Science.gov

Sample records for bound defect pairs

  1. Double phase slips and bound defect pairs in parametrically driven waves

    SciTech Connect

    Riecke, H.; Granzow, G.D.

    1997-12-31

    Spatio-temporal chaos in parametrically driven waves is investigated in one and two dimensions using numerical simulations of Ginzburg-Landau equations. A regime is identified in which in one dimension the dynamics are due to double phase slips. In very small systems they are found to arise through a Hopf bifurcation off a mixed mode. In large systems they can lead to a state of localized spatio-temporal chaos, which can be understood within the framework of phase dynamics. In two dimensions the double phase slips are replaced by bound defect pairs. Our simulations indicate the possibility of an unbinding transition of these pairs, which is associated with a transition from ordered to disordered defect chaos.

  2. Search for bound-state electron+positron pair decay

    NASA Astrophysics Data System (ADS)

    Bosch, F.; Hagmann, S.; Hillenbrand, P.-M.; Lane, G. J.; Litvinov, Yu. A.; Reed, M. W.; Sanjari, M. S.; Stöhlker, Th.; Torilov, S. Yu.; Tu, X. L.; Walke, P. M.

    2016-09-01

    The heavy ion storage rings coupled to in-flight radioactive-ion beam facilities, namely the ability to produce and store for extended periods of time radioactive nuclides in high atomic charge states, for the searchof yet unobserved decay mode - bound-state electron-positron pair decay.

  3. Approaching Tsirelson's Bound in a Photon Pair Experiment

    NASA Astrophysics Data System (ADS)

    Poh, Hou Shun; Joshi, Siddarth K.; Cerè, Alessandro; Cabello, Adán; Kurtsiefer, Christian

    2015-10-01

    We present an experimental test of the Clauser-Horne-Shimony-Holt Bell inequality on photon pairs in a maximally entangled state of polarization in which a value S =2.82759 ±0.00051 is observed. This value comes close to the Tsirelson bound of |S |≤2 √{2 } , with S -2 √{2 }=0.00084 ±0.00051 . It also violates the bound |S |≤2.82537 introduced by Grinbaum by 4.3 standard deviations. This violation allows us to exclude that quantum mechanics is only an effective description of a more fundamental theory.

  4. Synthesizing skyrmion bound pairs in Fe-Gd thin films

    NASA Astrophysics Data System (ADS)

    Lee, J. C. T.; Chess, J. J.; Montoya, S. A.; Shi, X.; Tamura, N.; Mishra, S. K.; Fischer, P.; McMorran, B. J.; Sinha, S. K.; Fullerton, E. E.; Kevan, S. D.; Roy, S.

    2016-07-01

    We show that properly engineered amorphous Fe-Gd alloy thin films with perpendicular magnetic anisotropy exhibit bound pairs of like-polarity, opposite helicity skyrmions at room temperature. Magnetic mirror symmetry planes present in the stripe phase, instead of chiral exchange, determine the internal skyrmion structure and the net achirality of the skyrmion phase. Our study shows that stripe domain engineering in amorphous alloy thin films may enable the creation of skyrmion phases with technologically desirable properties.

  5. Synthesizing skyrmion bound pairs in Fe-Gd thin films

    DOE PAGES

    Lee, J. C. T.; Chess, J. J.; Montoya, S. A.; ...

    2016-07-11

    Here, we show that properly engineered amorphous Fe-Gd alloy thin films with perpendicular magnetic anisotropy exhibit bound pairs of like-polarity, opposite helicity skyrmions at room temperature. Magnetic mirror symmetry planes present in the stripe phase, instead of chiral exchange, determine the internal skyrmion structure and the net achirality of the skyrmion phase. Our study shows that stripe domain engineering in amorphous alloy thin films may enable the creation of skyrmion phases with technologically desirable properties.

  6. Metastable Frenkel Pair Defect in Graphite: Source of Wigner Energy?

    NASA Astrophysics Data System (ADS)

    Ewels, C. P.; Telling, R. H.; El-Barbary, A. A.; Heggie, M. I.; Briddon, P. R.

    2003-07-01

    The atomic processes associated with energy storage and release in irradiated graphite have long been subject to untested speculation. We examine structures and recombination routes for interstitial-vacancy (I-V) pairs in graphite. Interaction results in the formation of a new metastable defect (an intimate I-V pair) or a Stone-Wales defect. The intimate I-V pair, although 2.9eV more stable than its isolated constituents, still has a formation energy of 10.8eV. The barrier to recombination to perfect graphite is calculated to be 1.3eV, consistent with the experimental first Wigner energy release peak at 1.38eV. We expect similar defects to form in carbon nanostructures such as nanotubes, nested fullerenes, and onions under irradiation.

  7. Defect pair in the elastic lattice of pancake vortices

    SciTech Connect

    Slutzky, M.; Mints, R.G.; Brandt, E.H.

    1997-07-01

    An additional pancake-antipancake vortex pair is considered in the vortex lattice of layered superconductors. Within linear elastic continuum theory, the relaxation of the background lattice screens the long-range logarithmic interaction of the defect pair, reducing the factor ln(r{sub 0}/{xi}) to ln(a/{xi}) where r{sub 0} is the pair spacing, {xi} the in-plane coherence length, and a the vortex spacing. The finite tilt modulus does not destroy this ideal two-dimensional screening, yielding a small correction {approximately}(a{sup 2}/8{pi}{lambda}{sup 2})ln(r{sub 0}/a), which in principle is of long range, but has a very small prefactor when the vortex spacing a is smaller than the in-plane penetration depth {lambda}. {copyright} {ital 1997} {ital The American Physical Society}

  8. Migration of point defects and a defect pair in zinc oxide using the dimer method

    SciTech Connect

    Chen, Dong; Gao, Fei; Dong, Mingdong; Liu, Bo

    2012-09-24

    The migration mechanism and the minimum energy path of vacancies, interstitials and an interstitial-vacancy pair in zinc oxide have been studied by the dimer method. The in-plane and out-of-plane migrations of zinc and oxygen vacancies are found to be anisotropic. The kick-out mechanism is energetically preferred to zinc and oxygen interstitials that can easily migrate through the ZnO crystal lattice. In addition, the migration process of an interstitial-vacancy pair as a complex of an octahedral oxygen interstitial and a zinc vacancy is dominated by an oxygen interstitial/zinc vacancy successive migration. The energy barriers indicate that the existence of oxygen interstitial in the defect pair can promote the mobility of zinc vacancy, whereas the migration of oxygen interstitial is slowed down due to the presence of zinc vacancy. In the end, we show a possible migration path of the interstitial-vacancy pair that can be dissociated through a set of displacement movements.

  9. Observation of bound and antibound states of cavity polariton pairs in a CuCl microcavity

    NASA Astrophysics Data System (ADS)

    Matsuura, S.; Mitsumori, Y.; Kosaka, H.; Edamatsu, K.; Miyazaki, K.; Kim, D.; Nakayama, M.; Oohata, G.; Oka, H.; Ajiki, H.; Ishihara, H.

    2014-01-01

    We observed the antibound state, as well as the bound state, for cavity polariton pairs in a planar CuCl microcavity by spectrally resolved four-wave mixing. We obtained dispersion curves of the bound and antibound states by changing the incident angle of the pump pulses corresponding to the cavity detuning. The dispersion curve for the bound state suggests that the bound state is mainly composed of a bare biexciton and is weakly coupled to the cavity photons. The dephasing time of the bound state was faster than that of a bare biexciton in a thin sample, supporting the hypothesis that the bound state is coupled to the cavity photons. On the other hand, the antibound state consists of two lower polaritons having the same spin. The clear observation of the antibound state can be qualitatively explained by the phase-space filling, which reduces the Rabi splitting.

  10. Defect structures in liquid crystals bounded by microwrinkles

    NASA Astrophysics Data System (ADS)

    Ohzono, Takuya

    2013-09-01

    Spatially confined liquid crystals (LCs) exhibit non-uniform alignment, often accompanied by self-organized topological defects of non-trivial shape in response to imposed boundary conditions and geometry. Here we show that a nematic LC, when confined in a sinusoidal microwrinkle groove, exhibits a new periodic arrangement of twist deformations and a zigzag line defect. This periodic ordering results from the inherent LC elastic anisotropy and the antagonistic boundary conditions at the top flat LC and the curved LC-groove interfaces. The effect of the LC thickness on the stability of the line defect is also shown.

  11. Defect pair separation as the controlling step in homogeneous ice melting.

    PubMed

    Mochizuki, Kenji; Matsumoto, Masakazu; Ohmine, Iwao

    2013-06-20

    On being heated, ice melts into liquid water. Although in practice this process tends to be heterogeneous, it can occur homogeneously inside bulk ice. The thermally induced homogeneous melting of solids is fairly well understood, and involves the formation and growth of melting nuclei. But in the case of water, resilient hydrogen bonds render ice melting more complex. We know that the first defects appearing during homogeneous ice melting are pairs of five- and seven-membered rings, which appear and disappear repeatedly and randomly in space and time in the crystalline ice structure. However, the accumulation of these defects to form an aggregate is nearly additive in energy, and results in a steep free energy increase that suppresses further growth. Here we report molecular dynamics simulations of homogeneous ice melting that identify as a crucial first step not the formation but rather the spatial separation of a defect pair. We find that once it is separated, the defect pair--either an interstitial (I) and a vacancy (V) defect pair (a Frenkel pair), or an L and a D defect pair (a Bjerrum pair)--is entropically stabilized, or 'entangled'. In this state, defects with threefold hydrogen-bond coordination persist and grow, and thereby prepare the system for subsequent rapid melting.

  12. Quantum information processing in the radical-pair mechanism: Haberkorn's theory violates the Ozawa entropy bound

    NASA Astrophysics Data System (ADS)

    Mouloudakis, K.; Kominis, I. K.

    2017-02-01

    Radical-ion-pair reactions, central for understanding the avian magnetic compass and spin transport in photosynthetic reaction centers, were recently shown to be a fruitful paradigm of the new synthesis of quantum information science with biological processes. We show here that the master equation so far constituting the theoretical foundation of spin chemistry violates fundamental bounds for the entropy of quantum systems, in particular the Ozawa bound. In contrast, a recently developed theory based on quantum measurements, quantum coherence measures, and quantum retrodiction, thus exemplifying the paradigm of quantum biology, satisfies the Ozawa bound as well as the Lanford-Robinson bound on information extraction. By considering Groenewold's information, the quantum information extracted during the reaction, we reproduce the known and unravel other magnetic-field effects not conveyed by reaction yields.

  13. Quantum information processing in the radical-pair mechanism: Haberkorn's theory violates the Ozawa entropy bound.

    PubMed

    Mouloudakis, K; Kominis, I K

    2017-02-01

    Radical-ion-pair reactions, central for understanding the avian magnetic compass and spin transport in photosynthetic reaction centers, were recently shown to be a fruitful paradigm of the new synthesis of quantum information science with biological processes. We show here that the master equation so far constituting the theoretical foundation of spin chemistry violates fundamental bounds for the entropy of quantum systems, in particular the Ozawa bound. In contrast, a recently developed theory based on quantum measurements, quantum coherence measures, and quantum retrodiction, thus exemplifying the paradigm of quantum biology, satisfies the Ozawa bound as well as the Lanford-Robinson bound on information extraction. By considering Groenewold's information, the quantum information extracted during the reaction, we reproduce the known and unravel other magnetic-field effects not conveyed by reaction yields.

  14. Pair creation induced by transitions between electronic and positronic bound states

    NASA Astrophysics Data System (ADS)

    Liu, Y.; Lv, Q. Z.; Li, Y. T.; Grobe, R.; Su, Q.

    2015-05-01

    We study the creation process of electron-positron pairs from the quantum electrodynamical vacuum under very strong electric fields by solving the quantum field theoretical Dirac equation on a space-time grid. We investigate the role of bound-bound state mixing in such a process, which can be studied if the external force can be modeled by a combination of a potential barrier and a potential well. By increasing the magnitude of the two potentials, discrete states that originate from the positive and negative energy continua can become quasidegenerate in the mass gap region (between -mc 2 and mc 2). We show that this bound-bound state mixing is quite different from the usual bound-continuum state mixing where the particles are created until the Pauli exclusion principle inhibits this process. In the case of bound-bound mixing the particle number exhibits a characteristic oscillatory behavior that in principle can last forever. These findings can be modeled by an effective two-state model.

  15. Bound-free electron-positron pair production in relativistic heavy-ion collisions

    NASA Astrophysics Data System (ADS)

    Şengül, M. Y.; Güçlü, M. C.; Fritzsche, S.

    2009-10-01

    The bound-free electron-positron pair production is considered for relativistic heavy ion collisions. In particular, cross sections are calculated for the pair production with the simultaneous capture of the electron into the 1s ground state of one of the ions and for energies that are relevant for the relativistic heavy ion collider and the large hadron colliders. In the framework of perturbation theory, we applied Monte Carlo integration techniques to compute the lowest-order Feynman diagrams amplitudes by using Darwin wave functions for the bound states of the electrons and Sommerfeld-Maue wave functions for the continuum states of the positrons. Calculations were performed especially for the collision of Au+Au at 100 GeV/nucleon and Pb+Pb at 3400 GeV/nucleon.

  16. Lowest optical excitations in molecular crystals: bound excitons versus free electron-hole pairs in anthracene.

    PubMed

    Hummer, Kerstin; Puschnig, Peter; Ambrosch-Draxl, Claudia

    2004-04-09

    By solving the Bethe-Salpeter equation for the electron-hole Green function for crystalline anthracene we find the lowest absorption peak generated by strongly bound excitons or by a free electron-hole pair, depending on the polarization direction being parallel to the short or the long molecular axis, respectively. Both excitations are shifted to lower energies by pressure. The physical difference of these excitations is apparent from the electron-hole wave functions. Our findings are a major contribution to solve the long-standing puzzle about the nature of the lowest optical excitations in organic materials.

  17. Long range coupling between defect centres in inorganic nanostructures: Valence alternation pairs in nanoscale silica

    NASA Astrophysics Data System (ADS)

    Zwijnenburg, M. A.; Illas, F.; Bromley, S. T.

    2012-10-01

    Valence alternation pair (VAP) states are formed by a closed-shell combination of two space- and charge-separated topological defect centres. These pairs of defects, although historically invoked to explain the electronic properties of bulk inorganic glassy materials (e.g., amorphous silicon dioxide) via the concept of negative-U defects, have more recently been found in a number of theoretical studies of silica surfaces and nanoscale silica clusters. Using density functional theory we systematically probe the structure and internal stability of VAPs in a number of silica nanoclusters with respect to the separation of the two constituent defect centres. We find that VAP states in nanosilica are strongly stabilised by the attractive electrostatic interaction between their separated oppositely charged component defects such that VAPs can persist up to an internal separation of a least 1.5 nanometres. Beyond this distance VAPs become unstable with respect to an open-shell combination of topological defects, virtually indistinguishable from two isolated open-shell defect centres. Finally, we theoretically analyse the possibility of experimental observation of VAP states through their infra-red vibrational spectra.

  18. Transport properties of paired Majorana bound states in a parallel junction

    NASA Astrophysics Data System (ADS)

    Jiang, Cui; Gong, W. J.; Zheng, Yi-Song

    2013-12-01

    The transport properties of a paired Majorana bound states (MBSs) in a parallel junction are theoretically investigated, by considering the influence of different MBS-lead coupling manners, i.e., left-right asymmetric coupling, upper-down asymmetric coupling, and left-right upper-down asymmetric coupling. The calculation results show that the MBS-lead coupling manners affect the transport properties in a substantial way. For the former two configurations, the shot noise Fano factor in the zero-bias limit is related to the value of the conductance maximum with F0=1+1/2Tmax (conductance G =e/2hT). When both the left-right and upper-down symmetries are broken, such a relation is modified into F0=1-12/T0. These results will be helpful for describing the transport characteristics of the junction with MBSs.

  19. Rare-earth defect pairs in GaN: LDA+U calculations

    NASA Astrophysics Data System (ADS)

    Sanna, Simone; Schmidt, W. G.; Frauenheim, Th.; Gerstmann, U.

    2009-09-01

    The structural and electronic properties of rare-earth (RE) (Eu, Er, and Tm) related defect pairs in GaN have been investigated theoretically. Based on LDA+U total-energy calculations, their possible role in the luminescence process is discussed. In all charge states, the lanthanides show a strong preference for the Ga-lattice site, either as isolated substitutional or complexed with intrinsic defects. With respect to the electronic valence, a proper description of correlation effects of the strongly localized 4f electrons is shown to be crucial, especially if the REGa is paired with donors like the Ga interstitial or the N vacancy. The pairs formed by REGa substitutionals and vacancies or interstitials lower the symmetry and are found to locally distort the environment. By this, they are quite effective in relaxing the selection rules for the luminescent intra- 4f -shell transitions. While for n -type GaN, the next-nearest-neighbor pair REGaVGa pair is energetically favored, for p -type GaN, the REGaVN pair provides the most stable configuration and introduces shallow levels close to the conduction band, which can act as assistant levels in the luminescence process.

  20. Possible s±-wave pairing evidenced by midgap surface bound states in Fe-pnictide superconductors

    NASA Astrophysics Data System (ADS)

    Liu, C. S.; Chang, J. Y.; Wu, W. C.; Mou, Chung-Yu

    2013-09-01

    A phenomenological theory of tunneling spectroscopy for Fe-pnictide superconductors is developed by taking into consideration asymmetric interface scattering between particle and holes. It is shown that, consistent with anti-phase s±-wave pairing, appreciable zero-energy surface bound states exist on the [100] surface of Fe-pnictide superconductors. However, in contrast to the [110] bound states in d-wave cuprate superconductors, these bound states arise as a result of non-conservation of momentum perpendicular to the interface for tunneling electrons and the s± pairing, and hence they can only exist in a small window (∼ ± 6∘) in the orientation of edges near the [100] direction. Our results explain why a zero-bias conductance peak is often observed in tunneling spectroscopy and why, when it disappears, two coherent peaks show up. These results provide unambiguous signals to test for possible s±-wave pairing in Fe-pnictide superconductors.

  1. Dark-polariton bound pairs in the modified Jaynes-Cummings-Hubbard model

    NASA Astrophysics Data System (ADS)

    Maggitti, A.; Radonjić, M.; Jelenković, B. M.

    2016-01-01

    We investigate a one-dimensional modified Jaynes-Cummings-Hubbard chain of N identical QED cavities with nearest-neighbor photon tunneling and periodic boundary conditions. Each cavity contains an embedded three-level atom which is coupled to a cavity mode and an external classical control field. In the case of two excitations and common large detuning of two Raman-resonant fields, we show the emergence of two different species of dark-polariton bound pairs (DPBPs) that are mutually localized in their relative spatial coordinates. Due to the high degree of controllability, we show the appearance of either one or two DPBPs, having the energies within the energy gaps between three bands of mutually delocalized eigenstates. Interestingly, in a different parameter regime with negatively detuned Raman fields, we find that the ground state of the system is a DPBP which can be utilized for the photon storage, retrieval, and controllable state preparation. Moreover, we propose an experimental realization of our model system.

  2. Research on dynamics and fault mechanism of spur gear pair with spalling defect

    NASA Astrophysics Data System (ADS)

    Ma, Rui; Chen, Yushu; Cao, Qingjie

    2012-04-01

    This study focuses on the nonlinear dynamic and vibration characteristics of spur gear pair with local spalling defect to explore the spalling mechanism. The dynamic model of the gear pair with spalling defect and time-variant mesh stiffness is established to investigate the effect of spalling defect on mesh stiffness and dynamic response. The analytical solutions of the system which is deduced into four different stages of the gear with the time-variant stiffness in a mesh period are obtained. The dynamic responses with the evolvement of sapll are analyzed by using time history, phase contrail, Poincaré section and spectrum analysis. The spalling characteristics are also evaluated by employing statistical techniques, which shows that the spalling failure is suitable to be detected under low velocity and small excitation. The gearbox with spalling defect is designed and the experiments are carried out to get the dynamic characteristics of the spalling vibration signals. The results obtained herein show the good agreement qualitatively with the theoretical analysis, which provides a theoretical basis to spalling fault diagnosis of gearbox.

  3. Excitons Bound to Nitrogen Pairs in GaAs as Seen by Photoluminescence of High Spectral and Spatial Resolution

    SciTech Connect

    Karaiskaj, D.; Mascarenhas, A.; Klem, J. F.; Volz, K.; Stolz, W.; Adamcyk, M.; Tiedje, T.

    2007-01-01

    High resolution photoluminescence (PL) spectroscopy was performed on high quality bulk GaAs, lightly doped with the nitrogen isoelectronic impurity. The shallowest nitrogen pair bound exciton center labeled as X{sub 1} revealed a total of six transitions. The photoluminescence lines from a small ensemble of nitrogen centers showed polarization dependent intensity. High spectral resolution PL spectroscopy was combined with confocal spectroscopy experiments performed on a GaAs:N/AlGaAs heterostructure. The high spatial resolution achieved by this technique enables us to localize and examine individual nitrogen bound excitons. Similar spectral structure and polarization dependence was observed for individual N-pair centers in GaAs. Both techniques support the C{sub 2v} symmetry of such isoelectronic impurity centers. The comparison between the PL spectra from an ensemble of nitrogen pairs and individual centers demonstrate the ability of the single impurity technique to lift the orientational degeneracy.

  4. Local structure investigation of oxide ion and proton defects in Ge-apatites by pair distribution function analysis.

    PubMed

    Malavasi, Lorenzo; Orera, Alodia; Slater, Peter R; Panchmatia, Pooja M; Islam, M Saiful; Siewenie, Joan

    2011-01-07

    In this communication we provide a direct insight into the local structure and defects of oxygen excess Ge-apatites, in both dry and deuterated states, by means of pair distribution function analysis.

  5. Simultaneous observation of free and defect-bound excitons in CH3NH3PbI3 using four-wave mixing spectroscopy

    PubMed Central

    March, Samuel A.; Clegg, Charlotte; Riley, Drew B.; Webber, Daniel; Hill, Ian G.; Hall, Kimberley C.

    2016-01-01

    Solar cells incorporating organic-inorganic perovskite, which may be fabricated using low-cost solution-based processing, have witnessed a dramatic rise in efficiencies yet their fundamental photophysical properties are not well understood. The exciton binding energy, central to the charge collection process, has been the subject of considerable controversy due to subtleties in extracting it from conventional linear spectroscopy techniques due to strong broadening tied to disorder. Here we report the simultaneous observation of free and defect-bound excitons in CH3NH3PbI3 films using four-wave mixing (FWM) spectroscopy. Due to the high sensitivity of FWM to excitons, tied to their longer coherence decay times than unbound electron- hole pairs, we show that the exciton resonance energies can be directly observed from the nonlinear optical spectra. Our results indicate low-temperature binding energies of 13 meV (29 meV) for the free (defect-bound) exciton, with the 16 meV localization energy for excitons attributed to binding to point defects. Our findings shed light on the wide range of binding energies (2–55 meV) reported in recent years. PMID:27974815

  6. Simultaneous observation of free and defect-bound excitons in CH3NH3PbI3 using four-wave mixing spectroscopy.

    PubMed

    March, Samuel A; Clegg, Charlotte; Riley, Drew B; Webber, Daniel; Hill, Ian G; Hall, Kimberley C

    2016-12-15

    Solar cells incorporating organic-inorganic perovskite, which may be fabricated using low-cost solution-based processing, have witnessed a dramatic rise in efficiencies yet their fundamental photophysical properties are not well understood. The exciton binding energy, central to the charge collection process, has been the subject of considerable controversy due to subtleties in extracting it from conventional linear spectroscopy techniques due to strong broadening tied to disorder. Here we report the simultaneous observation of free and defect-bound excitons in CH3NH3PbI3 films using four-wave mixing (FWM) spectroscopy. Due to the high sensitivity of FWM to excitons, tied to their longer coherence decay times than unbound electron- hole pairs, we show that the exciton resonance energies can be directly observed from the nonlinear optical spectra. Our results indicate low-temperature binding energies of 13 meV (29 meV) for the free (defect-bound) exciton, with the 16 meV localization energy for excitons attributed to binding to point defects. Our findings shed light on the wide range of binding energies (2-55 meV) reported in recent years.

  7. Simultaneous observation of free and defect-bound excitons in CH3NH3PbI3 using four-wave mixing spectroscopy

    NASA Astrophysics Data System (ADS)

    March, Samuel A.; Clegg, Charlotte; Riley, Drew B.; Webber, Daniel; Hill, Ian G.; Hall, Kimberley C.

    2016-12-01

    Solar cells incorporating organic-inorganic perovskite, which may be fabricated using low-cost solution-based processing, have witnessed a dramatic rise in efficiencies yet their fundamental photophysical properties are not well understood. The exciton binding energy, central to the charge collection process, has been the subject of considerable controversy due to subtleties in extracting it from conventional linear spectroscopy techniques due to strong broadening tied to disorder. Here we report the simultaneous observation of free and defect-bound excitons in CH3NH3PbI3 films using four-wave mixing (FWM) spectroscopy. Due to the high sensitivity of FWM to excitons, tied to their longer coherence decay times than unbound electron- hole pairs, we show that the exciton resonance energies can be directly observed from the nonlinear optical spectra. Our results indicate low-temperature binding energies of 13 meV (29 meV) for the free (defect-bound) exciton, with the 16 meV localization energy for excitons attributed to binding to point defects. Our findings shed light on the wide range of binding energies (2–55 meV) reported in recent years.

  8. Robust zero-energy bound states around a pair-density-wave vortex core in locally noncentrosymmetric superconductors

    NASA Astrophysics Data System (ADS)

    Higashi, Yoichi; Nagai, Yuki; Yoshida, Tomohiro; Masaki, Yusuke; Yanase, Youichi

    2016-03-01

    We numerically investigate the electronic structures around a vortex core in a bilayer superconducting system, with s -wave pairing, Rashba spin-orbit coupling, and Zeeman magnetic field, with the use of the quasiclassical Green's function method. The BCS phase and the so-called pair-density-wave (PDW) phase appear in the temperature-magnetic-field phase diagram in a bulk uniform system [T. Yoshida et al., Phys. Rev. B 86, 134514 (2012), 10.1103/PhysRevB.86.134514]. In the low magnetic field perpendicular to the layers, the zero-energy vortex bound states in the BCS phase are split by the Zeeman magnetic field. On the other hand, the PDW state appears in the high magnetic field, and the sign of the order parameter is opposite between the layers. We find that the vortex core suddenly shrinks and the zero-energy bound states appear by increasing the magnetic field through the BCS-PDW transition. We discuss the origin of the change in the vortex-core structure between the BCS and PDW states by clarifying the relation between the vortex bound states and the bulk energy spectra. In the high-magnetic-field region, the PDW state and vortex bound states are protected by the spin-orbit coupling. These characteristic behaviors in the PDW state can be observed by scanning tunneling microscopy/spectroscopy.

  9. Enhancement of electron-positron pair creation due to transient excitation of field-induced bound states

    NASA Astrophysics Data System (ADS)

    Jiang, M.; Lv, Q. Z.; Sheng, Z. M.; Grobe, R.; Su, Q.

    2013-04-01

    We study the creation of electron-positron pairs induced by two spatially separated electric fields that vary periodically in time. The results are based on large-scale computer simulations of the time-dependent Dirac equation in reduced spatial dimensions. When the separation of the fields is very large, the pair creation is caused by multiphoton transitions and mainly determined by the frequency of the fields. However, for small spatial separations a coherence effect can be observed that can enhance or reduce the particle yield compared to the case of two infinitely separated fields. If the travel time for a created electron or positron between both field locations becomes comparable to the period of the oscillating fields, we observe peaks in the energy spectrum which can be explained in terms of field-induced transient bound states.

  10. Fano effect and bound state in continuum in electron transport through an armchair graphene nanoribbon with line defect

    PubMed Central

    2013-01-01

    Electron transport properties in an armchair graphene nanoribbon are theoretically investigated by considering the presence of line defect. It is found that the line defect causes the abundant Fano effects and bound state in continuum (BIC) in the electron transport process, which are tightly dependent on the width of the nanoribbon. By plotting the spectra of the density of electron states of the line defect, we see that the line defect induces some localized quantum states around the Dirac point and that the different localizations of these states lead to these two kinds of transport results. Next, the Fano effect and BIC phenomenon are detailedly described via the analysis about the influence of the structure parameters. According to the numerical results, we propose such a structure to be a promising candidate for graphene nanoswitch. PACS 81.05.Uw, 71.55.-i, 73.23.-b, 73.25.+i PMID:23870061

  11. Fano effect and bound state in continuum in electron transport through an armchair graphene nanoribbon with line defect.

    PubMed

    Gong, Wei-Jiang; Sui, Xiao-Yan; Wang, Yan; Yu, Guo-Dong; Chen, Xiao-Hui

    2013-07-22

    : Electron transport properties in an armchair graphene nanoribbon are theoretically investigated by considering the presence of line defect. It is found that the line defect causes the abundant Fano effects and bound state in continuum (BIC) in the electron transport process, which are tightly dependent on the width of the nanoribbon. By plotting the spectra of the density of electron states of the line defect, we see that the line defect induces some localized quantum states around the Dirac point and that the different localizations of these states lead to these two kinds of transport results. Next, the Fano effect and BIC phenomenon are detailedly described via the analysis about the influence of the structure parameters. According to the numerical results, we propose such a structure to be a promising candidate for graphene nanoswitch. PACS: 81.05.Uw, 71.55.-i, 73.23.-b, 73.25.+i.

  12. Strain effects on the behavior of isolated and paired sulfur vacancy defects in monolayer MoS2

    NASA Astrophysics Data System (ADS)

    Sensoy, Mehmet Gokhan; Vinichenko, Dmitry; Chen, Wei; Friend, Cynthia M.; Kaxiras, Efthimios

    2017-01-01

    We investigate the behavior of sulfur vacancy defects, the most abundant type of intrinsic defect in monolayer MoS2, using first-principles calculations based on density functional theory. We consider the dependence of the isolated defect formation energy on the charge state and on uniaxial tensile and compressive strain up to 5%. We also consider the possibility of defect clustering by examining the formation energies of pairs of vacancies at various relative positions, and their dependence on charge state and strain. We find that there is no driving force for vacancy clustering, independent of strain in the material. The barrier for diffusion of S vacancies is larger than 1.9 eV in both charged and neutral states regardless of the presence of other nearby vacancies. We conclude that the formation of extended defects from S vacancies in planar monolayer MoS2 is hindered both thermodynamically and kinetically.

  13. Holes bound as small polarons to acceptor defects in oxide materials: why are their thermal ionization energies so high?

    NASA Astrophysics Data System (ADS)

    Schirmer, O. F.

    2011-08-01

    Holes bound to acceptor defects in oxide materials usually need comparatively high energies, of the order of 0.5-1.0 eV, to be ionized thermally to the valence band maximum. It is discussed that this has to be attributed to the stabilization of such holes by mainly short range interactions with the surrounding lattice, leading to the formation of small O - polarons. This is tantamount to the localization of the hole at only one of several equivalent oxygen ions next to the defect. The hole stabilizing energies can be determined experimentally from the related intense optical absorption bands. This paper exploits previous phenomenological studies of bound-hole small polarons in order to account for the large hole stabilization energies on this basis. A compilation demonstrates that bound-hole small polarons occur rather often in oxides and also in some related materials. The identification of such systems is based on EPR and optical studies and also on recent advanced electronic structure calculations.

  14. Towards building artificial light harvesting complexes: enhanced singlet-singlet energy transfer between donor and acceptor pairs bound to albumins.

    PubMed

    Kumar, Challa V; Duff, Michael R

    2008-12-01

    Specific donor and acceptor pairs have been assembled in bovine serum albumin (BSA), at neutral pH and room temperature, and these dye-protein complexes indicated efficient donor to acceptor singlet-singlet energy transfer. For example, pyrene-1-butyric acid served as the donor and Coumarin 540A served as the acceptor. Both the donor and the acceptor bind to BSA with affinity constants in excess of 2x10(5) M(-1), as measured in absorption and circular dichroism (CD) spectral titrations. Simultaneous binding of both the donor and the acceptor chromophores was supported by CD spectra and one chromophore did not displace the other from the protein host, even when limited concentrations of the host were used. For example, a 1:1:1 complex between the donor, acceptor and the host can be readily formed, and spectral data clearly show that the binding sites are mutually exclusive. The ternary complexes (two different ligands bound to the same protein molecule) provided opportunities to examine singlet-singlet energy transfer between the protein-bound chromophores. Donor emission was quenched by the addition of the acceptor, in the presence of limited amounts of BSA, while no energy transfer was observed in the absence of the protein host, under the same conditions. The excitation spectra of the donor-acceptor-host complexes clearly show the sensitization of acceptor emission by the donor. Protein denaturation, as induced by the addition of urea or increasing the temperature to 360 K, inhibited energy transfer, which indicate that protein structure plays an important role. Sensitization also proceeded at low temperature (77 K) and diffusion of the donor or the acceptor is not required for energy transfer. Stern-Volmer quenching plots show that the quenching constant is (3.1+/-0.2)x10(4) M(-1), at low acceptor concentrations (<35 microM). Other albumins such as human and porcine proteins also served as good hosts for the above experiments. For the first time, non

  15. Topological defect-phase soliton and the pairing symmetry of a two-band superconductor: role of the proximity effect.

    PubMed

    Vakaryuk, Victor; Stanev, Valentin; Lee, Wei-Cheng; Levchenko, Alex

    2012-11-30

    We suggest a mechanism which promotes the existence of a phase soliton--a topological defect formed in the relative phase of superconducting gaps of a two-band superconductor with s(+-) type of pairing. This mechanism exploits the proximity effect with a conventional s-wave superconductor which favors the alignment of the phases of the two-band superconductor which, in the case of s(+-) pairing, are π shifted in the absence of proximity. In the case of a strong proximity such an effect can be used to reduce the soliton's energy below the energy of a soliton-free state, thus making the soliton thermodynamically stable. Based on this observation we consider an experimental setup, applicable for both stable and metastable solitons, which can be used to distinguish between ss(+-) and s(++) types of pairing in the iron-based multiband superconductors.

  16. Dynamics of a ±1/2 defect pair in a confined geometry: A thin hybrid aligned nematic cell

    NASA Astrophysics Data System (ADS)

    Lu, Li-Xia; Zhang, Zhi-Dong

    2015-02-01

    Confined geometry can change the defect structure and its properties. In this paper, we investigate numerically the dynamics of a dipole of ±1/2 parallel wedge disclination lines in a confined geometry: a thin hybrid aligned nematic (HAN) cell, based on the Landau-de Gennes theory. When the cell gap d is larger than a critical value of 12ξ (where ξ is the characteristic length for order-parameter change), the pair annihilates. A pure HAN configuration without defect is formed in an equilibrium state. In the confined geometry of d ≤ 12ξ, the diffusion process is discovered for the first time and an eigenvalue exchange configuration is formed in an equilibrium state. The eigenvalue exchange configuration is induced by different essential reasons. When 10ξ < d ≤ 12ξ, the two defects coalesce and annihilate. The biaxial wall is created by the inhomogeneous distortion of the director, which results in the eigenvalue exchange configuration. When d ≤ 10ξ, the defects do not collide and the eigenvalue exchange configuration originates from the biaxial seeds concentrated at the defects. Project supported by the National Natural Science Foundation of China (Grant No. 11374087) and the Key Subject Construction Project of Hebei Province University.

  17. Application of the bounds-analysis approach to arsenic and gallium antisite defects in gallium arsenide

    DOE PAGES

    Wright, A. F.; Modine, N. A.

    2015-01-23

    The As antisite in GaAs (AsGa) has been the subject of numerous experimental and theoretical studies. Recent density-functional-theory (DFT) studies report results in good agreement with experimental data for the +2, +1, and 0 charge states of the stable EL2 structure, the 0 charge state of the metastable EL2* structure, and the activation energy to transform from EL2* to EL2 in the 0 charge state. However, these studies did not report results for EL2* in the -1 charge state. In this paper, we report new DFT results for the +2, +1, 0, and -1 charge states of AsGa, obtained usingmore » a semilocal exchange-correlation functional and interpreted using a bounds-analysis approach. In good agreement with experimental data, we find a -1/0 EL2* level 0.06 eV below the conduction-band edge and an activation energy of 0.05 eV to transform from EL2* to EL2 in the -1 charge state. While the Ga antisite in GaAs (GaAs) has not been studied as extensively as AsGa, experimental studies report three charge states (-2, -1, 0) and two levels (-2/-1, -1/0) close to the valence-band edge. Recent DFT studies report the same charge states, but the levels are found to be well-separated from the valence-band edge. To resolve this disagreement, we performed new DFT calculations for GaAs and interpreted them using a bounds analysis. The analysis identified the -1 and 0 charge states as hole states weakly bound to a highly-localized -2 charge state. Moreover, the -2/-1, -1/0 levels were found to be near the valence-band edge, in good agreement with the experimental data.« less

  18. Application of the bounds-analysis approach to arsenic and gallium antisite defects in gallium arsenide

    SciTech Connect

    Wright, A. F.; Modine, N. A.

    2015-01-23

    The As antisite in GaAs (AsGa) has been the subject of numerous experimental and theoretical studies. Recent density-functional-theory (DFT) studies report results in good agreement with experimental data for the +2, +1, and 0 charge states of the stable EL2 structure, the 0 charge state of the metastable EL2* structure, and the activation energy to transform from EL2* to EL2 in the 0 charge state. However, these studies did not report results for EL2* in the -1 charge state. In this paper, we report new DFT results for the +2, +1, 0, and -1 charge states of AsGa, obtained using a semilocal exchange-correlation functional and interpreted using a bounds-analysis approach. In good agreement with experimental data, we find a -1/0 EL2* level 0.06 eV below the conduction-band edge and an activation energy of 0.05 eV to transform from EL2* to EL2 in the -1 charge state. While the Ga antisite in GaAs (GaAs) has not been studied as extensively as AsGa, experimental studies report three charge states (-2, -1, 0) and two levels (-2/-1, -1/0) close to the valence-band edge. Recent DFT studies report the same charge states, but the levels are found to be well-separated from the valence-band edge. To resolve this disagreement, we performed new DFT calculations for GaAs and interpreted them using a bounds analysis. The analysis identified the -1 and 0 charge states as hole states weakly bound to a highly-localized -2 charge state. Moreover, the -2/-1, -1/0 levels were found to be near the valence-band edge, in good agreement with the experimental data.

  19. First-principles calculations of momentum distributions of annihilating electron-positron pairs in defects in UO2

    NASA Astrophysics Data System (ADS)

    Wiktor, Julia; Jomard, Gérald; Torrent, Marc; Bertolus, Marjorie

    2017-01-01

    We performed first-principles calculations of the momentum distributions of annihilating electron-positron pairs in vacancies in uranium dioxide. Full atomic relaxation effects (due to both electronic and positronic forces) were taken into account and self-consistent two-component density functional theory schemes were used. We present one-dimensional momentum distributions (Doppler-broadened annihilation radiation line shapes) along with line-shape parameters S and W. We studied the effect of the charge state of the defect on the Doppler spectra. The effect of krypton incorporation in the vacancy was also considered and it was shown that it should be possible to observe the fission gas incorporation in defects in UO2 using positron annihilation spectroscopy. We suggest that the Doppler broadening measurements can be especially useful for studying impurities and dopants in UO2 and of mixed actinide oxides.

  20. Quasiparticle Scattering off Defects and Possible Bound States in Charge-Ordered YBa2 Cu3 Oy

    NASA Astrophysics Data System (ADS)

    Zhou, R.; Hirata, M.; Wu, T.; Vinograd, I.; Mayaffre, H.; Krämer, S.; Horvatić, M.; Berthier, C.; Reyes, A. P.; Kuhns, P. L.; Liang, R.; Hardy, W. N.; Bonn, D. A.; Julien, M.-H.

    2017-01-01

    We report the NMR observation of a skewed distribution of 17O Knight shifts when a magnetic field quenches superconductivity and induces long-range charge-density-wave (CDW) order in YBa2Cu3Oy . This distribution is explained by an inhomogeneous pattern of the local density of states N (EF) arising from quasiparticle scattering off, yet unidentified, defects in the CDW state. We argue that the effect is most likely related to the formation of quasiparticle bound states, as is known to occur, under specific circumstances, in some metals and superconductors (but not in the CDW state, in general, except for very few cases in 1D materials). These observations should provide insight into the microscopic nature of the CDW, especially regarding the reconstructed band structure and the sensitivity to disorder.

  1. Fryns syndrome: a lethal mesoectodermal birth defect with variable expression in a pair of monozygotic twins.

    PubMed

    Pratap, A; Agrawal, A; Raja, S; Khaniya, S; Tiwari, A; Kumar, A

    2007-04-01

    We report a pair of twins with variable expressions of Fryns syndrome, both of whom died in the neonatal period. The syndrome is characterised by craniofacial dysmorphism, diaphragmatic hernia and distal limb hypoplasia. With this report, there are a total of 83 cases reported in the literature and this further serves to illustrate the clinical variability of this disorder.

  2. Base-pairing energies of proton-bound heterodimers of cytosine and modified cytosines: implications for the stability of DNA i-motif conformations.

    PubMed

    Yang, Bo; Rodgers, M T

    2014-01-08

    The DNA i-motif conformation was discovered in (CCG)•(CGG)n trinucleotide repeats, which are associated with fragile X syndrome, the most widespread inherited cause of mental retardation in humans. The DNA i-motif is a four-stranded structure whose strands are held together by proton-bound dimers of cytosine (C(+)•C). The stronger base-pairing interactions in C(+)•C proton-bound dimers as compared to Watson-Crick G•C base pairs are the major forces responsible for stabilization of i-motif conformations. Methylation of cytosine results in silencing of the FMR1 gene and causes fragile X syndrome. However, the influence of methylation or other modifications such as halogenation of cytosine on the base-pairing energies (BPEs) in the i-motif remains elusive. To address this, proton-bound heterodimers of cytosine and 5-methylcytosine, 5-fluorocytosine, 5-bromocytosine, and 5-iodocytosine are probed in detail. Experimentally, the BPEs of proton-bound heterodimers of cytosine and modified cytosines are determined using threshold collision-induced dissociation (TCID) techniques. All modifications at the 5-position of cytosine are found to lower the BPE and therefore would tend to destabilize DNA i-motif conformations. However, the BPEs in these proton-bound heterodimers still significantly exceed those of the Watson-Crick G•C and neutral C•C base pairs, suggesting that C(+)•C mismatches are still energetically favored such that i-motif conformations are preserved. Excellent agreement between TCID measured BPEs and B3LYP calculated values is found with the def2-TZVPPD and 6-311+G(2d,2p) basis sets, suggesting that calculations at these levels of theory can be employed to provide reliable energetic predictions for related systems.

  3. Evidence for a pairing anti-halo effect in the odd-even staggering in reaction cross sections of weakly bound nuclei

    SciTech Connect

    Hagino, K.; Sagawa, H.

    2011-07-15

    We investigate the spatial extension of weakly bound Ne and C isotopes by taking into account the pairing correlation with the Hartree-Fock-Bogoliubov (HFB) method and a three-body model, respectively. We show that the odd-even staggering in the reaction cross sections of {sup 30,31,32}Ne and {sup 14,15,16}C are successfully reproduced, and thus the staggering can be attributed to the pairing anti-halo effect. A correlation between a one-neutron separation energy and the anti-halo effect is demonstrated for s and p waves using the HFB wave functions.

  4. Quantum transport through a multi-quantum-dot-pair chain side-coupled with Majorana bound states

    NASA Astrophysics Data System (ADS)

    Zhao-Tan, Jiang; Cheng-Cheng, Zhong

    2016-06-01

    We investigate the quantum transport properties through a special kind of quantum dot (QD) system composed of a serially coupled multi-QD-pair (multi-QDP) chain and side-coupled Majorana bound states (MBSs) by using the Green functions method, where the conductance can be classified into two kinds: the electron tunneling (ET) conductance and the Andreev reflection (AR) one. First we find that for the nonzero MBS-QDP coupling a sharp AR-induced zero-bias conductance peak with the height of e 2/h is present (or absent) when the MBS is coupled to the far left (or the other) QDP. Moreover, the MBS-QDP coupling can suppress the ET conductance and strengthen the AR one, and further split into two sub-peaks each of the total conductance peaks of the isolated multi-QDPs, indicating that the MBS will make obvious influences on the competition between the ET and AR processes. Then we find that the tunneling rate Γ L is able to affect the conductances of leads L and R in different ways, demonstrating that there exists a Γ L-related competition between the AR and ET processes. Finally we consider the effect of the inter-MBS coupling on the conductances of the multi-QDP chains and it is shown that the inter-MBS coupling will split the zero-bias conductance peak with the height of e 2/h into two sub-peaks. As the inter-MBS coupling becomes stronger, the two sub-peaks are pushed away from each other and simultaneously become lower, which is opposite to that of the single QDP chain where the two sub-peaks with the height of about e 2/2h become higher. Also, the decay of the conductance sub-peaks with the increase of the MBS-QDP coupling becomes slower as the number of the QDPs becomes larger. This research should be an important extension in studying the transport properties in the kind of QD systems coupled with the side MBSs, which is helpful for understanding the nature of the MBSs, as well as the MBS-related QD transport properties. Project supported by the National Natural

  5. Investigating of the exclusive reaction of π⁺π⁻ pair electroproduction on a proton bound in a deuteron

    SciTech Connect

    Skorodumina, Yu. A.; Golovach, Evgeny N.; Gothe, Ralf W.; Ishkhanov, Boris S.; Isupov, Evgeny L.; Mokeev, Viktor I.; Fedotov, Gleb V.

    2015-04-01

    Preliminary results from analyzing π⁺π⁻ pair electroproduction on a proton bound in a deuteron are presented. Procedures for considering the Fermi motion of the initial proton in the deuteron and assessing the effects of interaction in the final states are developed. The yield of the reaction ep(n) → e'p'(n')π⁺π⁻ is obtained for the first time.

  6. Base-pairing energies of proton-bound homodimers determined by guided ion beam tandem mass spectrometry: application to cytosine and 5-substituted cytosines.

    PubMed

    Yang, Bo; Wu, R R; Rodgers, M T

    2013-11-19

    Base-pairing interactions in proton-bound dimers of cytosine (C(+)·C) are the major forces responsible for stabilization of DNA i-motif conformations. Permethylation of cytosine in extended (CCG)·(CGG)n trinucleotide repeats has been shown to cause fragile-X syndrome, the most widespread inherited cause of mental retardation in humans. Oligonucleotides containing 5-bromo- or 5-fluorocytosine can bind to proteins that selectively bind methylated DNA, suggesting that halogenated cytosine damage products can potentially mimic methylation signals. However, the influence of methylation or halogenation on the base-pairing energies (BPEs) of proton-bound dimers of cytosine and their impact on the stability of DNA i-motif conformations is presently unknown. To address this, proton-bound homodimers of cytosine and 5-methyl-, 5-fluoro-, 5-bromo-, and 5-iodocytosine are investigated in detail both experimentally and theoretically. The BPEs of proton-bound homodimers of cytosine and the modified cytosines are measured by threshold collision-induced dissociation (TCID) techniques. 5-Methylation of cytosine is found to increase the BPE and would therefore tend to stabilize DNA i-motif conformations. In contrast, 5-halogenation lowers the BPE. However, the BPEs of the proton-bound 5-halocytosine homodimers examined here still significantly exceed that of Watson-Crick G·C base pairs, such that DNA i-motif conformations should be preserved in the presence of these modifications. Excellent agreement between TCID measured and B3LYP calculated BPEs is found, suggesting that B3LYP calculations can be used to provide reliable energetic predictions for related systems.

  7. Calculating the mean time to capture for tethered ligands and its effect on the chemical equilibrium of bound ligand pairs.

    PubMed

    Shen, Lu; Decker, Caitlin G; Maynard, Heather D; Levine, Alex J

    2016-09-01

    We present here the calculation of the mean time to capture of a tethered ligand to the receptor. This calculation is then used to determine the shift in the partitioning between (1) free, (2) singly bound, and (3) doubly bound ligands in chemical equilibrium as a function of the length of the tether. These calculations are used in the research article Fibroblast Growth Factor 2 Dimer with Superagonist in vitro Activity Improves Granulation Tissue Formation During Wound Healing (Decker et al., in press [1]) to explain quantitatively how changes in polymeric linker length in the ligand dimers modifies the efficacy of these molecules relative to that of free ligands.

  8. Multichannel HSO4- recognition promoted by a bound cation within a ferrocene-based ion pair receptor.

    PubMed

    Alfonso, María; Espinosa, Arturo; Tárraga, Alberto; Molina, Pedro

    2012-07-11

    A ferrocene-based ion pair receptor is shown only to recognise HSO(4)(-) anions in the presence of a cobound Pb(2+) or Zn(2+) cation guest species through a perturbation of the redox potential of the ferrocene unit and a remarkable enhancement of the fluorescence.

  9. Competing rearrangement reactions in small gas-phase ionic complexes: The internal SN2 and nitro-nitrite rearrangements in nitroalkane proton-bound pairs

    NASA Astrophysics Data System (ADS)

    Poon, Clement; Mayer, Paul M.

    2006-09-01

    The dissociation of metastable proton-bound pairs, (R1NO2)(R2NO2)H+ (R1 and R2 = CH3, CH3CH2, (CH3)2CH and (CH3)3C) have been investigated by mass spectrometry and density functional theory calculations. The proton-bound pairs can dissociate via hydrogen-bond cleavage into protonated and neutral nitroalkanes. Methyl substitution of the nitroalkanes (R1 and R2 = (CH3)2CH, (CH3)3C) permits a rearrangement process to compete with the H-bond cleavage on the microsecond timescale. The rearrangement reaction results in an isomer that then loses nitrous acid and involves an internal SN2-type mechanism in which (R1NO2)(R2NO2)H+ isomerizes to R1NO2...R2NO2H+ via TS1 and then subsequently to R1NO2R2+...HONO via TS2 prior to dissociation. The process is favoured by stabilization of the charge in TS2 by methyl substitution. The stability of the t-butyl ion changes the mechanism in ((CH3)3CNO2)2H+ to one that involves a two-step alkyl cation transfer. An investigation of nitro-nitrite rearrangement in protonated nitroalkanes at the B3-LYP/6-31 + G(d) level of theory found that the rearrangement barrier is lowered to the point that (CH3)3CNO2H+ can easily interconvert into (CH3)3CO(H)NO+ in the gas phase and leads to the conclusion that the proton-bound pairs involving (CH3)3CNO2 are a mixture of nitro-nitro and nitro-nitrite proton-bound pairs. The nitrite isomer can dissociate into protonated t-butyl nitrite and neutral nitroalkane via a simple hydrogen-bond cleavage. A more favourable competing dissociation process leads to the loss of t-butanol to form the ((CH3)3CNO2)(NO)+ complex.

  10. The structure of the human tRNALys3 anticodon bound to the HIV genome is stabilized by modified nucleosides and adjacent mismatch base pairs.

    PubMed

    Bilbille, Yann; Vendeix, Franck A P; Guenther, Richard; Malkiewicz, Andrzej; Ariza, Xavier; Vilarrasa, Jaume; Agris, Paul F

    2009-06-01

    Replication of human immunodeficiency virus (HIV) requires base pairing of the reverse transcriptase primer, human tRNA(Lys3), to the viral RNA. Although the major complementary base pairing occurs between the HIV primer binding sequence (PBS) and the tRNA's 3'-terminus, an important discriminatory, secondary contact occurs between the viral A-rich Loop I, 5'-adjacent to the PBS, and the modified, U-rich anticodon domain of tRNA(Lys3). The importance of individual and combined anticodon modifications to the tRNA/HIV-1 Loop I RNA's interaction was determined. The thermal stabilities of variously modified tRNA anticodon region sequences bound to the Loop I of viral sub(sero)types G and B were analyzed and the structure of one duplex containing two modified nucleosides was determined using NMR spectroscopy and restrained molecular dynamics. The modifications 2-thiouridine, s(2)U(34), and pseudouridine, Psi(39), appreciably stabilized the interaction of the anticodon region with the viral subtype G and B RNAs. The structure of the duplex results in two coaxially stacked A-form RNA stems separated by two mismatched base pairs, U(162)*Psi(39) and G(163)*A(38), that maintained a reasonable A-form helix diameter. The tRNA's s(2)U(34) stabilized the interaction between the A-rich HIV Loop I sequence and the U-rich anticodon, whereas the tRNA's Psi(39) stabilized the adjacent mismatched pairs.

  11. Simultaneous Creation of Electron-Positron Pairs and Photons in Robertson-Walker Universes with Statically Bounded Expansion

    NASA Astrophysics Data System (ADS)

    Lotze, K.-H.

    We present, based upon quantum electrodynamics in Robertson-Walker flat universes, a thorough analysis of the creation of mutually interacting electron-positron pairs and photons from vacuum. Therefore we discuss at least qualitatively all processes contributing to the number densities of created particles up to the second order in the coupling constant. For two particular expansion laws with Minkowskian in respectively in and out regions, we obtain exact solutions to the Dirac equation and investigate in detail the process of simultaneous creation of electron-positron pairs and photons and the related attenuation effect for fermionic particles. This is done for electrons and positrons which have nonrelativistic momenta at Compton time in rapidly expanding universes. The results are compared with the zeroth-order creation of electron-positron pairs. Despite being smaller by a factor of roughly e02 /4π ≈ 1 /137, the interacting-particle creation is important mainly as a source of photons even in conformally flat universes.

  12. Crystallization and preliminary X-ray diffraction analysis of the Pax9 paired domain bound to a DC5 enhancer DNA element.

    PubMed

    Narasimhan, Kamesh; Hilbig, Antonia; Udayasuryan, Barath; Jayabal, Sriram; Kolatkar, Prasanna R; Jauch, Ralf

    2014-10-01

    Pax genes belong to a family of metazoan transcription factors that are known to play a critical role in eye, ear, kidney and neural development. The mammalian Pax family of transcription factors is characterized by a ∼128-amino-acid DNA-binding paired domain that makes sequence-specific contacts with DNA. The diversity in Pax gene activities emerges from complex modes of interaction with enhancer regions and heterodimerization with multiple interaction partners. Based on in vitro optimal binding-site selection studies and enhancer identification assays, it has been suggested that Pax proteins may recognize and bind their target DNA elements with different binding modes/topologies, however this hypothesis has not yet been structurally explored. One of the most extensively studied DNA target elements of the Pax6 paired domain is the eye-lens specific DC5 (δ-crystallin) enhancer element. In order to shed light on Pax6-DC5 DNA interactions, the related paired-domain prototype Pax9 was crystallized with the minimal δ-crystallin DC5 enhancer element and preliminary X-ray diffraction analysis was attempted. A 3.0 Å resolution native data set was collected at the National Synchrotron Light Source (NSLS), Brookhaven from crystals grown in a solution consisting of 10%(w/v) PEG 20K, 20%(v/v) PEG 550 MME, 0.03 M NaNO3, 0.03 M Na2HPO4, 0.03 M NH2SO4, 0.1 M MES/imidazole pH 6.5. The data set was indexed and merged in space group C2221, with unit-cell parameters a = 75.74, b = 165.59, c = 70.14 Å, α = β = γ = 90°. The solvent content in the unit cell is consistent with the presence of one Pax9 paired domain bound to duplex DNA in the asymmetric unit.

  13. Defects-assisted ferromagnetism due to bound magnetic polarons in Ce into Fe, Co:ZnO nanoparticles and first-principle calculations.

    PubMed

    Verma, Kuldeep Chand; Kotnala, R K

    2016-02-21

    Zn0.94TM0.03Ce0.03O [Zn0.94Fe0.03Ce0.03O (ZFCeO) and Zn0.94Co0.03Ce0.03O (ZCCeO)] nanoparticles were synthesized by a sol-gel process. Elemental analysis of these nanoparticles detects the weight percentage of Zn, Co, Fe, Ce and O in each sample. The Rietveld refinement of the X-ray diffraction pattern obtains the occupancy of dopant atoms, Wurtzite ZnO structure, crystallinity and lattice deformation with doping. The Ce doping into ZFO and ZCO form nanoparticles than nanorods was observed in pure ZnO, ZFO and ZCO samples that described due to chemical and ionic behavior of Ce, Fe, Co and Zn ions. The Raman active modes have peak broadening, intensity changes and peak shifts with metal doping that induces lattice defects. Photoluminescence spectra show blue-shifts at near-band edges and defects that influence broad visible emission with Ce doping. An enhancement in ferromagnetism in the magnetic hysteresis at 5 K is measured. The zero-field cooling and field cooling at H = 500 Oe and T = 300-5 K could confirm antiferromagnetic interactions mediated by defect carriers. The bound magnetic polaron at defect sites is responsible for the observed ferromagnetism. The ac magnetic susceptibility measurements determine the antiferromagnetic to ferromagnetic transition with some magnetic clustered growth in the samples and reveal a frequency independent peak that shows the Neel temperature. Weak room temperature ferromagnetism and optical quenching in ZFCeO are described by valance states of Fe and Ce ions, respectively. Using first-principle calculations, we studied the occupancy of Ce (replacing Zn atoms) in the Wurtzite structure.

  14. Zero-field optical detection of magnetic resonance on a metastable sulfur-pair-related defect in silicon: Evidence for a Cu constituent

    NASA Astrophysics Data System (ADS)

    Frens, A. M.; Bennebroek, M. T.; Schmidt, J.; Chen, W. M.; Monemar, B.

    1992-11-01

    A metastable complex defect in S-doped silicon has been studied with zero-field optically-detected magnetic-resonance (ODMR) spectroscopy. The defect shows two characteristic photoluminescence (PL) spectra SA and SB, corresponding to two different geometric configurations 1 and 2. The PL spectra in both cases originate from excited-state triplet bound excitons in the neutral charge state of the defect. Previous X-band ODMR studies for SA and SB show broad spectra with unresolved hyperfine interaction. In zero-field ODMR the linewidth is reduced to about 50 MHz for SA (100 MHz for SB), and the second-order hyperfine structure of an I=32 nucleus is resolved, partly with the help of a double-resonance technique. The zero-field splitting parameters of the triplet states (i.e., the principal D-tensor components) are determined as Dxx=-2905, Dyy=-705, and Dzz=3610 MHz for SA, and Dxx=-1295, Dyy=-180, and Dzz=1475 MHz for SB. The hyperfine splitting is determined as A=175 MHz for both SA and SB, whereas the quadrupole constant Pz'z' has a value 10-20 MHz for SA and a substantially larger value, 30-40 MHz for SB. The I=32 nucleus at the core of the defect is tentatively identified as Cu. The conclusion about the different quadrupole interaction for SA and SB from these data agrees with previous ODMR X-band data in a magnetic field, which also show a different configuration (of the Cu atom) in the excited triplet states of SA and SB. It is tentatively concluded from these data that the metastability of this defect is connected to a change of the site of the Cu atom with respect to its surroundings in the silicon lattice.

  15. Association of Myopic Optic Disc Deformation with Visual Field Defects in Paired Eyes with Open-Angle Glaucoma: A Cross-Sectional Study

    PubMed Central

    Sawada, Yu; Hangai, Masanori; Ishikawa, Makoto; Yoshitomi, Takeshi

    2016-01-01

    Purpose To examine the association of myopia with the visual field (VF) defects in open-angle glaucoma (OAG) using paired eyes to eliminate the effect of unknown confounding factors that are diverse among individuals. Methods One hundred eighteen eyes of 59 subjects with myopia (spherical equivalent [SE] ≥ -2 diopter [D] and axial length ≥ 24.0 mm) whose intra-ocular pressure between paired eyes was similar and the mean deviation (MD) of the Humphrey VF test differed by more than 6 dB were included. Refractive errors (SE, axial length) and parameters associated with the papillary and parapapillary myopic deformation (tilt ratio, torsion angle, and β-zone parapapillary atrophy [PPA] area without Bruch’s membrane) were measured in each eye. The paired eyes were divided into worse and better eyes according to the MD of the VF, and parameters were compared between them. Further, multiple linear regression analysis was performed to examine the correlation of the difference in various parameters with the MD difference between paired eyes. Results The SE of all eyes was -6.39 ± 2.15 D (mean ± standard deviation) and axial length was 26.42 ± 1.07 mm. MD of the worse and better VF eyes were -13.56 ± 6.65 dB and -4.87 ± 5.32 dB, respectively. Eyes with worse VFs had significantly greater SE, axial length, tilt ratio, and PPA area without Bruch’s membrane than those with better VFs (all P < 0.05). In multiple linear regression analysis, the difference of the MD between paired eyes was significantly correlated with the difference in the tilt ratio and PPA area without Bruch’s membrane. Conclusion The myopic papillary and parapapillary deformations, but not refractive error itself, were related to the worse VF in paired eyes with OAG. This suggests that myopia influences the severity of the glaucomatous VF defects via structural deformation. PMID:27571303

  16. Defect properties of Sb- and Bi-doped CuInSe{sub 2}: The effect of the deep lone-pair s states

    SciTech Connect

    Park, Ji-Sang; Yang, Ji-Hui; Ramanathan, Kannan; Wei, Su-Huai

    2014-12-15

    Bi or Sb doping has been used to make better material properties of polycrystalline Cu{sub 2}(In,Ga)Se{sub 2} as solar cell absorbers, including the experimentally observed improved electrical properties. However, the mechanism is still not clear. Using first-principles method, we investigate the stability and electronic structure of Bi- and Sb-related defects in CuInSe{sub 2} and study their effects on the doping efficiency. Contrary to previous thinking that Bi or Sb substituted on the anion site, we find that under anion-rich conditions, the impurities can substitute on cation sites and are isovalent to In because of the formation of the impurity lone pair s states. When the impurities substitute for Cu, the defects act as shallow double donors and help remove the deep In{sub Cu} level, thus resulting in the improved carrier life time. On the other hand, under anion-poor conditions, impurities at the Se site create amphoteric deep levels that are detrimental to the device performance.

  17. Ab-initio studies on Li doping, Li-pairs, and complexes between Li and intrinsic defects in ZnO

    NASA Astrophysics Data System (ADS)

    Vidya, R.; Ravindran, P.; Fjellvâg, H.

    2012-06-01

    First-principles density functional calculations have been performed on Li-doped ZnO using all-electron projector augmented plane wave method. Li was considered at six different interstitial sites (Lii), including anti-bonding and bond-center sites and also in substitutional sites such as at Zn-site (Lizn) and at oxygen site (Lio) in the ZnO matrix. Stability of LiZn over Lii is shown to depend on synthetic condition, viz., LiZn is found to be more stable than Lii under O-rich conditions. Hybrid density functional calculations performed on LiZn indicate that it is a deep acceptor with (0/-) transition taking place at 0.74 eV above valence band maximum. The local vibrational frequencies for Li-dopants are calculated and compared with reported values. In addition, we considered the formation of Li-pair complexes and their role on electronic properties of ZnO. Present study suggests that at extreme oxygen-rich synthesis condition, a pair of acceptor type LiZn-complex is found to be stable over the compensating Lii + LiZn pair. The stability of complexes formed between Li impurities and various intrinsic defects is also investigated and their role on electronic properties of ZnO has been analyzed. We have shown that a complex between LiZn and oxygen vacancy has less formation energy and donor-type character and could compensate the holes generated by Li-doping in ZnO.

  18. Base-Pairing Energies of Proton-Bound Dimers and Proton Affinities of 1-Methyl-5-Halocytosines: Implications for the Effects of Halogenation on the Stability of the DNA i-Motif.

    PubMed

    Yang, Bo; Wu, R R; Rodgers, M T

    2015-09-01

    (CCG)(n)•(CGG)(n) trinucleotide repeats have been found to be associated with fragile X syndrome, the most widespread inherited cause of mental retardation in humans. The (CCG)(n)•(CGG)(n) repeats adopt i-motif conformations that are preferentially stabilized by base-pairing interactions of noncanonical proton-bound dimers of cytosine (C(+)•C). Halogenated cytosine residues are one form of DNA damage that may be important in altering the structure and stability of DNA or DNA-protein interactions and, hence, regulate gene expression. Previously, we investigated the effects of 5-halogenation and 1-methylation of cytosine on the base-pairing energies (BPEs) using threshold collision-induced dissociation (TCID) techniques. In the present study, we extend our work to include proton-bound homo- and heterodimers of cytosine, 1-methyl-5-fluorocytosine, and 1-methyl-5-bromocytosine. All modifications examined here are found to produce a decrease in the BPEs. However, the BPEs of all of the proton-bound dimers examined significantly exceed those of Watson-Crick G•C, neutral C•C base pairs, and various methylated variants such that DNA i-motif conformations should still be preserved in the presence of these modifications. The proton affinities (PAs) of the halogenated cytosines are also obtained from the experimental data by competitive analysis of the primary dissociation pathways that occur in parallel for the proton-bound heterodimers. 5-Halogenation leads to a decrease in the N3 PA of cytosine, whereas 1-methylation leads to an increase in the N3 PA. Thus, the 1-methyl-5-halocytosines exhibit PAs that are intermediate.

  19. Base-Pairing Energies of Proton-Bound Dimers and Proton Affinities of 1-Methyl-5-Halocytosines: Implications for the Effects of Halogenation on the Stability of the DNA i-Motif

    NASA Astrophysics Data System (ADS)

    Yang, Bo; Wu, R. R.; Rodgers, M. T.

    2015-09-01

    (CCG)n•(CGG)n trinucleotide repeats have been found to be associated with fragile X syndrome, the most widespread inherited cause of mental retardation in humans. The (CCG)n•(CGG)n repeats adopt i-motif conformations that are preferentially stabilized by base-pairing interactions of noncanonical proton-bound dimers of cytosine (C+•C). Halogenated cytosine residues are one form of DNA damage that may be important in altering the structure and stability of DNA or DNA-protein interactions and, hence, regulate gene expression. Previously, we investigated the effects of 5-halogenation and 1-methylation of cytosine on the base-pairing energies (BPEs) using threshold collision-induced dissociation (TCID) techniques. In the present study, we extend our work to include proton-bound homo- and heterodimers of cytosine, 1-methyl-5-fluorocytosine, and 1-methyl-5-bromocytosine. All modifications examined here are found to produce a decrease in the BPEs. However, the BPEs of all of the proton-bound dimers examined significantly exceed those of Watson-Crick G•C, neutral C•C base pairs, and various methylated variants such that DNA i-motif conformations should still be preserved in the presence of these modifications. The proton affinities (PAs) of the halogenated cytosines are also obtained from the experimental data by competitive analysis of the primary dissociation pathways that occur in parallel for the proton-bound heterodimers. 5-Halogenation leads to a decrease in the N3 PA of cytosine, whereas 1-methylation leads to an increase in the N3 PA. Thus, the 1-methyl-5-halocytosines exhibit PAs that are intermediate.

  20. Sequence-Dependent T:G Base Pair Opening in DNA Double Helix Bound by Cren7, a Chromatin Protein Conserved among Crenarchaea

    PubMed Central

    Tian, Lei; Zhang, Zhenfeng; Wang, Hanqian; Zhao, Mohan; Dong, Yuhui; Gong, Yong

    2016-01-01

    T:G base pair arising from spontaneous deamination of 5mC or polymerase errors is a great challenge for DNA repair of hyperthermophilic archaea, especially Crenarchaea. Most strains in this phylum lack the protein homologues responsible for the recognition of the mismatch in the DNA repair pathways. To investigate whether Cren7, a highly conserved chromatin protein in Crenarchaea, serves a role in the repair of T:G mispairs, the crystal structures of Cren7-GTAATTGC and Cren7-GTGATCGC complexes were solved at 2.0 Å and 2.1 Å. In our structures, binding of Cren7 to the AT-rich DNA duplex (GTAATTGC) induces opening of T2:G15 but not T10:G7 base pair. By contrast, both T:G mispairs in the GC-rich DNA duplex (GTGATCGC) retain the classic wobble type. Structural analysis also showed DNA helical changes of GTAATTGC, especially in the steps around the open T:G base pair, as compared to GTGATCGC or the matched DNAs. Surface plasmon resonance assays revealed a 4-fold lower binding affinity of Cren7 for GTAATTGC than that for GTGATCGC, which was dominantly contributed by the decrease of association rate. These results suggested that binding of Cren7 to DNA leads to T:G mispair opening in a sequence dependent manner, and therefore propose the potential roles of Cren7 in DNA repair. PMID:27685992

  1. Transfer of a weakly bound electron in collisions of Rydberg atoms with neutral particles. II. Ion-pair formation and resonant quenching of the Rb(nl) and Ne(nl) States by Ca, Sr, and Ba atoms

    SciTech Connect

    Narits, A. A.; Mironchuk, E. S.; Lebedev, V. S.

    2013-10-15

    Electron-transfer processes are studied in thermal collisions of Rydberg atoms with alkaline-earth Ca(4s{sup 2}), Sr(5s{sup 2}), and Ba(6s{sup 2}) atoms capable of forming negative ions with a weakly bound outermost p-electron. We consider the ion-pair formation and resonant quenching of highly excited atomic states caused by transitions between Rydberg covalent and ionic terms of a quasi-molecule produced in collisions of particles. The contributions of these reaction channels to the total depopulation cross section of Rydberg states of Rb(nl) and Ne(nl) atoms as functions of the principal quantum number n are compared for selectively excited nl-levels with l Much-Less-Than n and for states with large orbital quantum numbers l = n - 1, n - 2. It is shown that the contribution from resonant quenching dominates at small values of n, and the ion-pair formation process begins to dominate with increasing n. The values and positions of the maxima of cross sections for both processes strongly depend on the electron affinity of an alkaline-earth atom and on the orbital angular momentum l of a highly excited atom. It is shown that in the case of Rydberg atoms in states with large l {approx} n - 1, the rate constants of ion-pair formation and collisional quenching are considerably lower than those for nl-levels with l Much-Less-Than n.

  2. A FRET-based probe for epidermal growth factor receptor bound non-covalently to a pair of synthetic amphipathic helixes

    SciTech Connect

    Itoh, Reina E.; Kurokawa, Kazuo; Fujioka, Aki; Sharma, Alok; Mayer, Bruce J.; Matsuda, Michiyuki . E-mail: matsudam@biken.osaka-u.ac.jp

    2005-07-01

    Epidermal growth factor (EGF) receptor plays a pivotal role in a variety of cellular functions, such as proliferation, differentiation, and migration. To monitor the EGF receptor (EGFR) activity in living cells, we developed a probe for EGFR activity based on the principle of fluorescence resonance energy transfer (FRET). Previously, we developed a probe designated as Picchu (Phosphorylation indicator of the CrkII chimeric unit), which detects the tyrosine phosphorylation of the CrkII adaptor protein. We used a pair of synthetic amphipathic helixes, WinZipA2 and WinZipB1, to bind Picchu non-covalently to the carboxyl-terminus of the EGFR. Using this modified probe named Picchu-Z, the activity of EGFR was followed in EGF-stimulated Cos7 cells. We found that a high level of tyrosine phosphorylation of Picchu-Z probe remained after endocytosis until the point when the EGFR was translocated to the perinuclear region. These findings are in agreement with the previously reported 'signaling endosome' model. Furthermore, by pulse stimulation with EGF and by acute ablation of EGFR activity with AG1478, it was suggested that the phosphorylation of Picchu-Z probe, and probably the phosphorylation of EGFR also, underwent a rapid equilibrium ({tau} {sub 1/2} < 2 min) between the phosphorylated and dephosphorylated states in the presence of EGF.

  3. Ion pair receptors†

    PubMed Central

    Kim, Sung Kuk

    2010-01-01

    Compared with simple ion receptors, which are able to bind either a cation or an anion, ion pair receptors bearing both a cation and an anion recognition site offer the promise of binding ion pairs or pairs of ions strongly as the result of direct or indirect cooperative interactions between co-bound ions. This critical review focuses on the recent progress in the design of ion pair receptors and summarizes the various binding modes that have been used to accommodate ion pairs (110 references). PMID:20737073

  4. Defect identification in the AsGa family in GaAs

    NASA Astrophysics Data System (ADS)

    Overhof, H.; Spaeth, J.-M.

    2005-09-01

    Ab initio total-energy calculations are presented for intrinsic defects in GaAs with a particular emphasis on hyperfine interactions in order to clarify the atomic structure of the various AsGa -related defects. For the AsGa-X2 defect complex the interpretation as an AsGa-VAs antisite-vacancy pair as was considered so far is challenged. An AsGa-GaAs antistructure pair is the most likely identification. It is also unlikely that the AsGa-X1 defect can be identified as a distant antistructure pair as was considered from magnetic resonance experiments. The theoretical results obtained for the isolated AsGa point defect agree with the experimental data reported for the defect identified as isolated AsGa and, with the exception of a small broadening of the nearest-neighbor lines and of a moderate splitting in the fifth shell, for the EL2 as well. We speculate that at room temperature the EL2 will be an isolated AsGa defect which lowers its symmetry attracting some other mobile defect at the low temperatures required to perform magnetic resonance experiments. We have calculated the binding energies of antisites bound to a distant shallow acceptor and the influence of the pairing on the hyperfine interactions. We show that this mechanism could explain the broadening of the nearest-neighbor lines but not the splitting in the fifth shell.

  5. Cooper Pairs in Insulators?!

    ScienceCinema

    James Valles

    2016-07-12

    Nearly 50 years elapsed between the discovery of superconductivity and the emergence of the microscopic theory describing this zero resistance state. The explanation required a novel phase of matter in which conduction electrons joined in weakly bound pairs and condensed with other pairs into a single quantum state. Surprisingly, this Cooper pair formation has also been invoked to account for recently uncovered high-resistance or insulating phases of matter. To address this possibility, we have used nanotechnology to create an insulating system that we can probe directly for Cooper pairs. I will present the evidence that Cooper pairs exist and dominate the electrical transport in these insulators and I will discuss how these findings provide new insight into superconductor to insulator quantum phase transitions. 

  6. Electronic pairing in exotic superconductors

    SciTech Connect

    Cox, D.L. ); Maple, M.B. )

    1995-02-01

    Superconductivity in heavy-fermion materials and high T[sub c] cuprates may involve electronic pairing with unconventional symmetries and mechanisms. Although there has been no smoking-gun proof, numerous pieces of circumstantial evidence combined with heuristic theoretical arguments make a compelling case that these materials have pairs with exotic symmetry bound by nonphonon glue. 20 refs., 5 figs.

  7. Effect of intrinsic point defects on ferroelectric polarization behavior of SrTiO3

    NASA Astrophysics Data System (ADS)

    Klyukin, Konstantin; Alexandrov, Vitaly

    2017-01-01

    The effect of a variety of intrinsic defects and defect clusters in bulk and thin films of SrTiO3 on ferroelectric polarization and switching mechanisms is investigated by means of density-functional-theory based calculations and the Berry phase approach. Our results show that both the titanium TiSr•• and strontium SrTi'' antisite defects induce ferroelectric polarization in SrTiO3, with the TiSr•• defect causing a more pronounced spontaneous polarization and higher activation barriers of polarization reversal than SrTi''. The presence of oxygen vacancies bound to the antisite defects can either enhance or diminish polarization depending on the configuration of the defect pair, but it always leads to larger activation barriers of polarization switching as compared to the antisite defects with no oxygen vacancies. We also show that the magnitude of spontaneous polarization in SrTiO3 can be tuned by controlling the degree of Sr/Ti nonstroichiometry. Other intrinsic point defects such as Frenkel defect pairs and electron small polarons also contribute to the emergence of ferroelectric polarization in SrTiO3.

  8. Upward Bound

    ERIC Educational Resources Information Center

    Journal of Aerospace Education, 1976

    1976-01-01

    Describes an Upward Bound program at Embry-Riddle Aeronautical University designed to assist disadvantaged high school juniors and seniors in overcoming academic deficiencies in order to enter and succeed in college. The Saturday program centered on various aspects of aviation, including career opportunities. (MLH)

  9. Outward Bound.

    ERIC Educational Resources Information Center

    Outward Bound, Inc., Andover, MA.

    The Outward Bound concept was developed in Germany and Great Britain with the saving of human life as the ultimate goal. Courses are designed to help students discover their true physical and mental limits through development of skills including emergency medical aid, firefighting, search and rescue, mountaineering, and sailing. Five Outward Bound…

  10. Cooper Pair Insulators

    NASA Astrophysics Data System (ADS)

    Valles, James

    One of the recent advances in the field of the Superconductor to Insulator Transition (SIT) has been the discovery and characterization of the Cooper Pair Insulator phase. This bosonic insulator, which consists of localized Cooper pairs, exhibits activated transport and a giant magneto-resistance peak. These features differ markedly from the weakly localized transport that emerges as pairs break at a ``fermionic'' SIT. I will describe how our experiments on films nano-patterned with a nearly triangular array of holes have enabled us to 1) distinguish bosonic insulators from fermionic insulators, 2) show that Cooper pairs, rather than quasi-particles dominate the transport in the Cooper Pair insulator phase, 3) demonstrate that very weak, sub nano-meter thickness inhomogeneities control whether a bosonic or fermionic insulator forms at an SIT and 4) reveal that Cooper pairs disintegrate rather than becoming more tightly bound deep in the localized phase. We have also developed a method, using a magnetic field, to tune flux disorder reversibly in these films. I will present our latest results on the influence of magnetic flux disorder and random gauge fields on phenomena near bosonic SITs. This work was performed in collaboration with M. D. Stewart, Jr., Hung Q. Nguyen, Shawna M. Hollen, Jimmy Joy, Xue Zhang, Gustavo Fernandez, Jeffrey Shainline and Jimmy Xu. It was supported by NSF Grants DMR 1307290 and DMR-0907357.

  11. Pick a Pair. Pancake Pairs

    ERIC Educational Resources Information Center

    Miller, Pat

    2005-01-01

    Cold February weather and pancakes are a traditional pairing. Pancake Day began as a way to eat up the foods that were abstained from in Lent--traditionally meat, fat, eggs and dairy products. The best-known pancake event is The Pancake Day Race in Buckinghamshire, England, which has been run since 1445. This column describes pairs of books that…

  12. Error bounds in cascading regressions

    USGS Publications Warehouse

    Karlinger, M.R.; Troutman, B.M.

    1985-01-01

    Cascading regressions is a technique for predicting a value of a dependent variable when no paired measurements exist to perform a standard regression analysis. Biases in coefficients of a cascaded-regression line as well as error variance of points about the line are functions of the correlation coefficient between dependent and independent variables. Although this correlation cannot be computed because of the lack of paired data, bounds can be placed on errors through the required properties of the correlation coefficient. The potential meansquared error of a cascaded-regression prediction can be large, as illustrated through an example using geomorphologic data. ?? 1985 Plenum Publishing Corporation.

  13. Birth Defects

    MedlinePlus

    ... how the body looks, works or both. Some birth defects like cleft lip or neural tube defects are structural problems that can be easy to see. To find others, like heart defects, doctors use special tests. Birth defects can vary from mild to severe. Some ...

  14. Sequential detection of web defects

    DOEpatents

    Eichel, Paul H.; Sleefe, Gerard E.; Stalker, K. Terry; Yee, Amy A.

    2001-01-01

    A system for detecting defects on a moving web having a sequential series of identical frames uses an imaging device to form a real-time camera image of a frame and a comparitor to comparing elements of the camera image with corresponding elements of an image of an exemplar frame. The comparitor provides an acceptable indication if the pair of elements are determined to be statistically identical; and a defective indication if the pair of elements are determined to be statistically not identical. If the pair of elements is neither acceptable nor defective, the comparitor recursively compares the element of said exemplar frame with corresponding elements of other frames on said web until one of the acceptable or defective indications occur.

  15. Hamiltonian anomalies of bound states in QED

    SciTech Connect

    Shilin, V. I.; Pervushin, V. N.

    2013-10-15

    The Bound State in QED is described in systematic way by means of nonlocal irreducible representations of the nonhomogeneous Poincare group and Dirac's method of quantization. As an example of application of this method we calculate triangle diagram Para-Positronium {yields} {gamma}{gamma}. We show that the Hamiltonian approach to Bound State in QED leads to anomaly-type contribution to creation of pair of parapositronium by two photon.

  16. Ab-intitio Studies of Defects in Ferroelectrics

    NASA Astrophysics Data System (ADS)

    Poykko, Sami

    2000-03-01

    Defects, defect complexes and domain walls in PbTiO3 have been studied using a first-principles method. Platinum is a widely used electrode material for PZT. Due to relatively high deposition temperatures a large concentration of Pt atoms diffuse into PZT, where they occupy Ti-sites and act as acceptors. Platinum impurity is shown to form a tightly bond pair with oxygen vacancy. This complex can have a significant role in fatigue, since each of these strongly polar defect also pin a polarization of a surrounding lattice. This result implies that in order to increase fatigue resistance of PZT it is extremely important to minimize especially acceptor type impurities [1]. We have shown that oxygen and lead vacancies do not form strongly bound defect complexes in PZT and therefore their creation does not seem to be directly involved in fatigue or imprint. According to our calculations a formation of a oxygen-vacancy lead-vacancy pair (close or distant) becomes exothermic under certain conditions. Therefore large number of vacancies are produced to PZT leading to resistance degradation and overall crystal quality also becomes worse [2]. An 180 degree domain wall has been shown to have an energy density of 150 erg/cm^2 and is lead-centered (ie. symmetry plane goes along Pb-atoms). A minimum width of a domain is calculated to be 4 lattice constants, narrower domains are found to be thermodynamically unstable [3]. footnote[1]S. Poykko and D. J. Chadi, "Dipolar Defect Model for Fatigue in Ferroelectric Perovskites" Physical Review Letters 83, 1231 (1999). footnote[2]S. Poykko and D. J. Chadi, "First principles study of Pb-vacancies in PbTiO_3", Applied Physics Letters, in print (2000). footnote[3]S. Poykko and D. J. Chadi, "Ab initio study of 180 degree domain wall energy and structure in PbTiO_3" Applied Physics Letters, 75, 2830 (1999).

  17. Immunoglobulin K light chain deficiency: A rare, but probably underestimated, humoral immune defect.

    PubMed

    Sala, Pierguido; Colatutto, Antonio; Fabbro, Dora; Mariuzzi, Laura; Marzinotto, Stefania; Toffoletto, Barbara; Perosa, Anna R; Damante, Giuseppe

    2016-04-01

    Human immunoglobulin molecules are generated by a pair of identical heavy chains, which identify the immunoglobulin class, and a pair of identical light chains, Kappa or Lambda alternatively, which characterize the immunoglobulin type. In normal conditions, Kappa light chains represent approximately 2/3 of the light chains of total immunoglobulins, both circulating and lymphocyte surface bound. Very few cases of immunoglobulin Kappa or Lambda light chain defects have been reported. Furthermore, the genetic basis of this defect has been extensively explored only in a single case. We report a case of a patient suffering of serious recurrent bacterial infections, which was caused by a very rare form of immunoglobulin disorder, consisting of a pure defect of Kappa light chain. We evaluated major serum immunoglobulin concentrations, as well as total and free Kappa and Lambda light chain concentrations. Lymphocyte phenotyping was also performed and finally we tested the Kappa chain VJ rearrangement as well as the constant Kappa region sequence. Studies performed on VJ rearrangement showed a polyclonal genetic arrangement, whereas the gene sequencing for the constant region of Kappa chain showed a homozygous T to G substitution at the position 1288 (rs200765148). This mutation causes a substitution from Cys to Gly in the protein sequence and, therefore, determines the abnormal folding of the constant region of Kappa chain. We suggest that this defect could lead to an effective reduction of the variability of total antibody repertoire and a consequent defect of an apparently normal immunoglobulin response to common antigens.

  18. Pairing Learners in Pair Work Activity

    ERIC Educational Resources Information Center

    Storch, Neomy; Aldosari, Ali

    2013-01-01

    Although pair work is advocated by major theories of second language (L2) learning and research findings suggest that pair work facilitates L2 learning, what is unclear is how to best pair students in L2 classes of mixed L2 proficiency. This study investigated the nature of pair work in an English as a Foreign Language (EFL) class in a college in…

  19. HIM-8 binds to the X chromosome pairing center and mediateschromosome-specific meiotic synapsis

    SciTech Connect

    Phillips, Carolyn M.; Wong, Chihunt; Bhalla, Needhi; Carlton,Peter M.; Weiser, Pinky; Meneely, Philip M.; Dernburg, Abby F.

    2005-06-05

    The him-8 gene is essential for proper meiotic segregationof the X chromosomes in C. elegans. Herewe show that loss of him-8function causes profound X-chromosome-specific defects in homolog pairingand synapsis.him-8 encodes a C2H2 zinc finger protein that is expressedduring meiosis andconcentrates at a site on the X chromosome known as themeiotic Pairing Center (PC). A role for HIM-8 in PC function is supportedby genetic interactions between PC lesions and him-8 mutations.HIM-8-bound chromosome sites associate with the nuclear envelope (NE)throughout meiotic prophase. Surprisingly, a point mutation in him-8 thatretains both chromosome binding and NE localization fails to stabilizepairing or promote synapsis. These observations indicate thatstabilization of homolog pairing is an active process in which thetethering of chromosome sites to the NE may be necessary but is notsufficient.

  20. Locating Bound Structures in the Accelerating Universe

    NASA Astrophysics Data System (ADS)

    Pearson, David; Batuski, D. J.

    2013-01-01

    Given the overwhelming evidence of the universe’s accelerating expansion, the question of what structures are gravitationally bound becomes one of utmost interest. Dunner et al. 2006 (D06) and Busha et al. 2003 (B03) set out to answer this question analytically, and they arrived at fairly different answers owing to the differences in their assumptions of velocities at the present epoch. Applying their criteria to different superclusters, it’s possible to make predictions about what structures may be bound. We apply the criteria of D06 and B03 to the Aquarius, Microscopium, Corona Borealis, and Shapley superclusters to make predictions about what structures might be bound and compare with the results of simple N-body simulations to determine which method is a better predictor and to determine the likelihood that parts or all of the superclusters listed above are bound. We find that D06 tend to predict more structure to be bound than B03, and the results of the N-body simulations usually lie somewhere in between the two sets of predictions. Observational evidence, and simulation data suggests that pairs of clusters in Aquarius and Microscopium are gravitationally bound, and that Shapley contains a large complex of clusters that are bound, along with some additional bound pairs. The likelihood that any of the clusters in Corona Borealis are bound to one another is very small, contrary to the claims of Small et al. 1998, who claimed that the entire supercluster is likely gravitationally bound. Busha M. T., Adams F. C., Wechsler R. H., Evrard A. E., 2003, ApJ, 596, 713 Dunner R., Araya P. A., Meza A., Reisenegger A., 2006, MNRAS, 306, 803 Small T. A., Ma C., Sargent W. L. W., Hamilton D., 1998, ApJ, 492, 45

  1. Formation energy of point defects in free surfaces and grain boundaries in MgO

    SciTech Connect

    Wolf, D.

    1982-01-01

    The computer code developed in recent years at Argonne National Laboratory for the investigation of the energy and structure of interfaces in ionic crystals has been extended to permit the consideration of neutral intrinsic point defects in such interfaces. As examples, bound Schottky pairs as well as substitutional Fe/sup 2 +/ and Ca/sup 2 +/ impurities are considered in the (100) surface and surface region. The role of isovalent impurities in the free (110) surface region and in a coincident-site twist boundary are also investigated. Results are compared and found in agreement with results obtained by means of the HADES program.

  2. Bound states and the Bekenstein bound

    SciTech Connect

    Bousso, Raphael

    2003-10-16

    We explore the validity of the generalized Bekenstein bound, S<= pi M a. We define the entropy S as the logarithm of the number of states which have energy eigenvalue below M and are localized to a flat space region of width alpha. If boundary conditions that localize field modes are imposed by fiat, then the bound encounters well-known difficulties with negative Casimir energy and large species number, as well as novel problems arising only in the generalized form. In realistic systems, however, finite-size effects contribute additional energy. We study two different models for estimating such contributions. Our analysis suggests that the bound is both valid and nontrivial if interactions are properly included, so that the entropy S counts the bound states of interacting fields.

  3. Anyon pairing via phonon-mediated interaction

    NASA Astrophysics Data System (ADS)

    Kandemir, B. S.

    2006-08-01

    In this paper, we study the pairing of anyons subjected to an external uniform magnetic field and confined in a two-dimensional parabolic quantum dot within the framework of Fröhlich large bipolaron theory, motivated by the Wilczek’s prescription that treats anyons as composites having both charges and fictitious flux tubes. In this model, electrons bound to Aharanov-Bohm type flux tubes and surrounded by a cloud of virtual LO phonons interact with each other through the long range Coulomb and statistical potentials. In order to discuss the effects of both spatial confinement potential and external uniform magnetic field on the boundaries of the stability region of such a pairing in real space, we perform a self-consistent treatment of the ground-state energies of both an interacting anyon pair and two noninteracting anyons. Our results suggest that two interacting anyons can be bound into a condensate anyon pair through a phonon-mediated interaction.

  4. Bounded link prediction in very large networks

    NASA Astrophysics Data System (ADS)

    Cui, Wei; Pu, Cunlai; Xu, Zhongqi; Cai, Shimin; Yang, Jian; Michaelson, Andrew

    2016-09-01

    Evaluating link prediction methods is a hard task in very large complex networks due to the prohibitive computational cost. However, if we consider the lower bound of node pairs' similarity scores, this task can be greatly optimized. In this paper, we study CN index in the bounded link prediction framework, which is applicable to enormous heterogeneous networks. Specifically, we propose a fast algorithm based on the parallel computing scheme to obtain all node pairs with CN values larger than the lower bound. Furthermore, we propose a general measurement, called self-predictability, to quantify the performance of similarity indices in link prediction, which can also indicate the link predictability of networks with respect to given similarity indices.

  5. Superconductivity: The persistence of pairs

    SciTech Connect

    Edelman, Alex; Littlewood, Peter

    2015-05-20

    Superconductivity stems from a weak attraction between electrons that causes them to form bound pairs and behave much like bosons. These so-called Cooper pairs are phase coherent, which leads to the astonishing properties of zero electrical resistance and magnetic flux expulsion typical of superconducting materials. This coherent state may be qualitatively understood within the Bose–Einstein condensate (BEC) model, which predicts that a gas of interacting bosons will become unstable below a critical temperature and condense into a phase of matter with a macroscopic, coherent population in the lowest energy state, as happens in 4He or cold atomic gases. The successful theory proposed by Bardeen, Cooper and Schrieffer (BCS) predicts that at the superconducting transition temperature Tc, electrons simultaneously form pairs and condense, with no sign of pairing above Tc. Theorists have long surmised that the BCS and BEC models are opposite limits of a single theory and that strong interactions or low density can, in principle, drive the system to a paired state at a temperature Tpair higher than Tc, making the transition to the superconducting state BEC-like (Fig. 1). Yet most superconductors to date are reasonably well described by BCS theory or its extensions, and there has been scant evidence in electronic materials for the existence of pairing independent of the full superconducting state (though an active debate rages over the cuprate superconductors). Writing in Nature, Jeremy Levy and colleagues have now used ingenious nanostructured devices to provide evidence for electron pairing1. Perhaps surprisingly, the material they have studied is a venerable, yet enigmatic, low-temperature superconductor, SrTiO3.

  6. Coulomb Bound States of Strongly Interacting Photons

    NASA Astrophysics Data System (ADS)

    Maghrebi, M. F.; Gullans, M. J.; Bienias, P.; Choi, S.; Martin, I.; Firstenberg, O.; Lukin, M. D.; Büchler, H. P.; Gorshkov, A. V.

    2015-09-01

    We show that two photons coupled to Rydberg states via electromagnetically induced transparency can interact via an effective Coulomb potential. This interaction gives rise to a continuum of two-body bound states. Within the continuum, metastable bound states are distinguished in analogy with quasibound states tunneling through a potential barrier. We find multiple branches of metastable bound states whose energy spectrum is governed by the Coulomb potential, thus obtaining a photonic analogue of the hydrogen atom. Under certain conditions, the wave function resembles that of a diatomic molecule in which the two polaritons are separated by a finite "bond length." These states propagate with a negative group velocity in the medium, allowing for a simple preparation and detection scheme, before they slowly decay to pairs of bound Rydberg atoms.

  7. Physical Uncertainty Bounds (PUB)

    SciTech Connect

    Vaughan, Diane Elizabeth; Preston, Dean L.

    2015-03-19

    This paper introduces and motivates the need for a new methodology for determining upper bounds on the uncertainties in simulations of engineered systems due to limited fidelity in the composite continuum-level physics models needed to simulate the systems. We show that traditional uncertainty quantification methods provide, at best, a lower bound on this uncertainty. We propose to obtain bounds on the simulation uncertainties by first determining bounds on the physical quantities or processes relevant to system performance. By bounding these physics processes, as opposed to carrying out statistical analyses of the parameter sets of specific physics models or simply switching out the available physics models, one can obtain upper bounds on the uncertainties in simulated quantities of interest.

  8. Sculpture, perspective view looking to pair of lions positioned at ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Sculpture, perspective view looking to pair of lions positioned at top of stairs leading down into the Glen - National Park Seminary, Bounded by Capitol Beltway (I-495), Linden Lane, Woodstove Avenue, & Smith Drive, Silver Spring, Montgomery County, MD

  9. Antihistamine Use in Early Pregnancy and Risk of Birth Defects

    PubMed Central

    Li, Qian; Mitchell, Allen A.; Werler, Martha M.; Yau, Wai-Ping; Hernández-Díaz, Sonia

    2014-01-01

    Background Several studies have reported an association between use of specific antihistamines in early pregnancy and certain specific birth defects. Objective To test 16 previously-hypothesized associations between specific antihistamines and specific birth defects, and identify possible new associations. Methods We used 1998-2010 data from the Slone Epidemiology Center Birth Defects Study, a multicenter case-control surveillance program of birth defects in North America. Mothers were interviewed within six months of delivery about demographic, reproductive, medical, and behavioral factors, and details on use of prescription and non-prescription medications. We compared 1st trimester exposure to specific antihistamines between 13,213 infants with specific malformations and 6,982 non-malformed controls, using conditional logistic regression to estimate odds ratios (ORs) and 95% confidence intervals (CIs), with adjustment for potential confounders, including indication for use. Results Overall, 13.7% of controls were exposed to antihistamines during the 1st trimester. The most commonly-used medications were diphenhydramine (4.2%), loratadine (3.1%), doxylamine (1.9%), and chlorpheniramine (1.7%). Where estimates were stable, none supported the previously-hypothesized associations. Among over 100 exploratory comparisons of other specific antihistamine/defect pairs, 14 had ORs ≥1.5 of which 6 had 95% CI bounds excluding 1.0 before but not after adjustment for multiple comparisons. Conclusion Our findings do not provide meaningful support for previously-posited associations between antihistamines and major congenital anomalies; at the same time, we identified associations that had not been previously suggested. We suspect that previous associations may be chance findings in the context of multiple comparisons, a situation which may also apply to our new findings. PMID:24565715

  10. A Cramer-Rao Type Lower Bound for Essentially Unbiased Parameter Estimation

    DTIC Science & Technology

    1992-01-03

    should apply to the entire class of estimators with acceptably small bias. In this report a new CR-type lower bound is derived which takes into account a...unbiased CR bound. If an upper bound on the bias gradient ot tne estimator is specified, our lower bound on estimator variance can subsequently be applied ...multiple parameters. Finally, Section 8 applies the new bound to covariance estimation for a pair of HD Gaussian sequences. 2 2. PRELIMINARIES 2.1

  11. Bounding Species Distribution Models

    NASA Technical Reports Server (NTRS)

    Stohlgren, Thomas J.; Jarnevich, Cahterine S.; Morisette, Jeffrey T.; Esaias, Wayne E.

    2011-01-01

    Species distribution models are increasing in popularity for mapping suitable habitat for species of management concern. Many investigators now recognize that extrapolations of these models with geographic information systems (GIS) might be sensitive to the environmental bounds of the data used in their development, yet there is no recommended best practice for "clamping" model extrapolations. We relied on two commonly used modeling approaches: classification and regression tree (CART) and maximum entropy (Maxent) models, and we tested a simple alteration of the model extrapolations, bounding extrapolations to the maximum and minimum values of primary environmental predictors, to provide a more realistic map of suitable habitat of hybridized Africanized honey bees in the southwestern United States. Findings suggest that multiple models of bounding, and the most conservative bounding of species distribution models, like those presented here, should probably replace the unbounded or loosely bounded techniques currently used [Current Zoology 57 (5): 642-647, 2011].

  12. Causality and Tsirelson's bounds

    SciTech Connect

    Buhrman, H.; Massar, S.

    2005-11-15

    We study the properties of no-signaling correlations that cannot be reproduced by local measurements on entangled quantum states. We say that such correlations violate Tsirelson bounds. We show that if these correlations are obtained by some reversible unitary quantum evolution U, then U cannot be written in the product form U{sub A}xU{sub B}. This implies that U can be used for signaling and for entanglement generation. This result is completely general and in fact can be viewed as a characterization of Tsirelson bounds. We then show how this result can be used as a tool to study Tsirelson bounds and we illustrate this by rederiving the Tsirelson bound of 2{radical}(2) for the Clauser-Horn-Shimony-Holt inequality, and by deriving a new Tsirelson bound for qutrits.

  13. Bounding species distribution models

    USGS Publications Warehouse

    Stohlgren, T.J.; Jarnevich, C.S.; Esaias, W.E.; Morisette, J.T.

    2011-01-01

    Species distribution models are increasing in popularity for mapping suitable habitat for species of management concern. Many investigators now recognize that extrapolations of these models with geographic information systems (GIS) might be sensitive to the environmental bounds of the data used in their development, yet there is no recommended best practice for "clamping" model extrapolations. We relied on two commonly used modeling approaches: classification and regression tree (CART) and maximum entropy (Maxent) models, and we tested a simple alteration of the model extrapolations, bounding extrapolations to the maximum and minimum values of primary environmental predictors, to provide a more realistic map of suitable habitat of hybridized Africanized honey bees in the southwestern United States. Findings suggest that multiple models of bounding, and the most conservative bounding of species distribution models, like those presented here, should probably replace the unbounded or loosely bounded techniques currently used. ?? 2011 Current Zoology.

  14. Point Defects Quenched in Nickel Aluminide and Related Intermetallic Compounds

    NASA Astrophysics Data System (ADS)

    Fan, Jiawen

    Point defects in the highly ordered B2 compounds NiAl, CoAl and FeAl were studied using the perturbed gammagamma angular correlations (PAC) technique. Quadrupole interactions detected at dilute ^{111}In probes on Al sites in NiAl and CoAl were identified with complexes containing one or two vacancies in the first atomic shell. Measurements on rapidly quenched NiAl and CoAl exhibited increases in site fractions of vacancy-probe complexes caused by formation of thermal defects. Site fractions were analyzed using the law of mass action to obtain absolute vacancy concentrations. PAC is shown to be a powerful new technique for the quantitative study of equilibrium defects in solids. For NiAl, the vacancy concentration quenched-in from a given temperature was found to be independent of composition over the range 50.4 -53.5 at.% Ni, identifying the Schottky defect (vacancy pair) as the dominant equilibrium defect, and ruling out the so-called triple defect. Formation energies and entropies of Schottky pairs were determined to be 2.66(8) and 3.48(12) eV, and 12(1) and 17(2) k_{rm B}, respectively, for NiAl and CoAl. The entropies suggest huge vacancy concentrations, 13%, at the melting temperatures of NiAl and CoAl. Migration energies of Ni and Co vacancies were found to be 1.8(2) and 2.5(2) eV, respectively. FeAl exhibited complex behavior. A low-temperature regime was detected in NiAl and CoAl within which vacancies are mobile but do not anneal out, so that the vacancy concentration remains constant. In NiAl, this "bottleneck" regime extends from 350 to 700 ^circC. Vacancies were found to be bound to the In probes with an energy very close to 0.20 eV in NiAl and CoAl. An explanation of the bottleneck is proposed in terms of saturation of all lattice sinks. This annealing bottleneck should exist in a wide range of intermetallic compounds when there is a sufficiently high vacancy concentration.

  15. Malabsorption of protein bound vitamin B12.

    PubMed Central

    Dawson, D W; Sawers, A H; Sharma, R K

    1984-01-01

    Patients with subnormal serum vitamin B12 concentrations were tested for absorption of protein bound vitamin B12 and compared with controls. Absorption of the protein bound vitamin appeared to decrease with increasing age in healthy subjects. Differences between the result of this test and the result of the Schilling test in patients who had undergone gastric surgery were confirmed; such differences were also seen in some patients who had iron deficiency anaemia, an excessive alcohol intake, or folate deficiency. Defective absorption was also found in six patients with an adequate dietary intake of vitamin B12, normal Schilling test results, low serum vitamin concentrations, and tissue changes responding to treatment with vitamin B12. Malabsorption of the vitamin from protein bound sources, which is not detected by the Schilling test, may produce vitamin B12 deficiency of clinical importance. PMID:6421428

  16. Congenital Defects.

    ERIC Educational Resources Information Center

    Goldman, Allen S.; And Others

    There are two general categories (not necessarily mutually exclusive) of congenital defects: (1) abnormalities that have an hereditary basis, such as single and multiple genes, or chromosomal abberration; and (2) abnormalities that are caused by nonhereditary factors, such as malnutrition, maternal disease, radiation, infections, drugs, or…

  17. Asymmetric dark matter bound state

    NASA Astrophysics Data System (ADS)

    Bi, Xiao-Jun; Kang, Zhaofeng; Ko, P.; Li, Jinmian; Li, Tianjun

    2017-02-01

    We propose an interesting framework for asymmetric scalar dark matter (ADM), which has novel collider phenomenology in terms of an unstable ADM bound state (ADMonium) produced via Higgs portals. ADMonium is a natural consequence of the basic features of ADM: the (complex scalar) ADM is charged under a dark local U (1 )d symmetry which is broken at a low scale and provides a light gauge boson X . The dark gauge coupling is strong and then ADM can annihilate away into X -pair effectively. Therefore, the ADM can form a bound state due to its large self-interaction via X mediation. To explore the collider signature of ADMonium, we propose that ADM has a two-Higgs doublet portal. The ADMonium can have a sizable mixing with the heavier Higgs boson, which admits a large cross section of ADMonium production associated with b b ¯. The resulting signature at the LHC depends on the decays of X . In this paper we consider a case of particular interest: p p →b b ¯ +ADMonium followed by ADMonium→2 X →2 e+e- where the electrons are identified as (un)converted photons. It may provide a competitive explanation to heavy di-photon resonance searches at the LHC.

  18. Virial Expansion Bounds

    NASA Astrophysics Data System (ADS)

    Tate, Stephen James

    2013-10-01

    In the 1960s, the technique of using cluster expansion bounds in order to achieve bounds on the virial expansion was developed by Lebowitz and Penrose (J. Math. Phys. 5:841, 1964) and Ruelle (Statistical Mechanics: Rigorous Results. Benjamin, Elmsford, 1969). This technique is generalised to more recent cluster expansion bounds by Poghosyan and Ueltschi (J. Math. Phys. 50:053509, 2009), which are related to the work of Procacci (J. Stat. Phys. 129:171, 2007) and the tree-graph identity, detailed by Brydges (Phénomènes Critiques, Systèmes Aléatoires, Théories de Jauge. Les Houches 1984, pp. 129-183, 1986). The bounds achieved by Lebowitz and Penrose can also be sharpened by doing the actual optimisation and achieving expressions in terms of the Lambert W-function. The different bound from the cluster expansion shows some improvements for bounds on the convergence of the virial expansion in the case of positive potentials, which are allowed to have a hard core.

  19. Bosonic pair creation and the Schiff-Snyder-Weinberg effect

    NASA Astrophysics Data System (ADS)

    Lv, Q. Z.; Bauke, Heiko; Su, Q.; Keitel, C. H.; Grobe, R.

    2016-01-01

    Interactions between different bound states in bosonic systems can lead to pair creation. We study this process in detail by solving the Klein-Gordon equation on space-time grids in the framework of time-dependent quantum field theory. By choosing specific external field configurations, two bound states can become pseudodegenerate, which is commonly referred to as the Schiff-Snyder-Weinberg effect. These pseudodegenerate bound states, which have complex energy eigenvalues, are related to the pseudo-Hermiticity of the Klein-Gordon Hamiltonian. In this work, the influence of the Schiff-Snyder-Weinberg effect on pair production is studied. A generalized Schiff-Snyder-Weinberg effect, where several pairs of pseudodegenerate states appear, is found in combined electric and magnetic fields. The generalized Schiff-Snyder-Weinberg effect likewise triggers pair creation. The particle number in these situations obeys an exponential growth law in time enhancing the creation of bosons, which cannot be found in fermionic systems.

  20. Genetic sperm defects.

    PubMed

    Chenoweth, Peter J

    2005-08-01

    Genetic sperm defects are specific sperm defects, which have been shown to have a genetic mode of transmission. Such genetic linkage, either direct or indirect, has been associated with a number of sperm defects in different species, with this number increasing with improved diagnostic capabilities. A number of sperm defects, which have proven or suspected genetic modes of transmission are discussed herein, with particular emphasis on cattle. These include: 1. Acrosome defects (knobbed, ruffled and incomplete); 2. Head defects (abnormal condensation, decapitated, round head, rolled head, nuclear crest); 3. Midpiece abnormalities ("Dag" defect, "corkscrew" defect, "pseudo-droplet" defect); 4. Tail defects ("tail stump" defect, primary ciliary dyskinesia).

  1. Validation of EMP bounds

    SciTech Connect

    Warne, L.K.; Merewether, K.O.; Chen, K.C.; Jorgenson, R.E.; Morris, M.E.; Solberg, J.E.; Lewis, J.G.; Derr, W.

    1996-07-01

    Test data on canonical weapon-like fixtures are used to validate previously developed analytical bounding results. The test fixtures were constructed to simulate (but be slightly worse than) weapon ports of entry but have known geometries (and electrical points of contact). The exterior of the test fixtures exhibited exterior resonant enhancement of the incident fields at the ports of entry with magnitudes equal to those of weapon geometries. The interior consisted of loaded transmission lines adjusted to maximize received energy or voltage but incorporating practical weapon geometrical constraints. New analytical results are also presented for bounding the energies associated with multiple bolt joints and for bounding the exterior resonant enhancement of the exciting fields.

  2. Electron teleportation via Majorana bound states in a mesoscopic superconductor.

    PubMed

    Fu, Liang

    2010-02-05

    Zero-energy Majorana bound states in superconductors have been proposed to be potential building blocks of a topological quantum computer, because quantum information can be encoded nonlocally in the fermion occupation of a pair of spatially separated Majorana bound states. However, despite intensive efforts, nonlocal signatures of Majorana bound states have not been found in charge transport. In this work, we predict a striking nonlocal phase-coherent electron transfer process by virtue of tunneling in and out of a pair of Majorana bound states. This teleportation phenomenon only exists in a mesoscopic superconductor because of an all-important but previously overlooked charging energy. We propose an experimental setup to detect this phenomenon in a superconductor-quantum-spin-Hall-insulator-magnetic-insulator hybrid system.

  3. Matched-pair classification

    SciTech Connect

    Theiler, James P

    2009-01-01

    Following an analogous distinction in statistical hypothesis testing, we investigate variants of machine learning where the training set comes in matched pairs. We demonstrate that even conventional classifiers can exhibit improved performance when the input data has a matched-pair structure. Online algorithms, in particular, converge quicker when the data is presented in pairs. In some scenarios (such as the weak signal detection problem), matched pairs can be generated from independent samples, with the effect not only doubling the nominal size of the training set, but of providing the structure that leads to better learning. A family of 'dipole' algorithms is introduced that explicitly takes advantage of matched-pair structure in the input data and leads to further performance gains. Finally, we illustrate the application of matched-pair learning to chemical plume detection in hyperspectral imagery.

  4. Vortex pairs on surfaces

    SciTech Connect

    Koiller, Jair

    2009-05-06

    A pair of infinitesimally close opposite vortices moving on a curved surface moves along a geodesic, according to a conjecture by Kimura. We outline a proof. Numerical simulations are presented for a pair of opposite vortices at a close but nonzero distance on a surface of revolution, the catenoid. We conjecture that the vortex pair system on a triaxial ellipsoid is a KAM perturbation of Jacobi's geodesic problem. We outline some preliminary calculations required for this study. Finding the surfaces for which the vortex pair system is integrable is in order.

  5. Computing Graphical Confidence Bounds

    NASA Technical Reports Server (NTRS)

    Mezzacappa, M. A.

    1983-01-01

    Approximation for graphical confidence bounds is simple enough to run on programmable calculator. Approximation is used in lieu of numerical tables not always available, and exact calculations, which often require rather sizable computer resources. Approximation verified for collection of up to 50 data points. Method used to analyze tile-strength data on Space Shuttle thermal-protection system.

  6. Cooper pairs and bipolarons

    NASA Astrophysics Data System (ADS)

    Lakhno, Victor

    2016-11-01

    It is shown that Cooper pairs are a solution of the bipolaron problem for model Fröhlich Hamiltonian. The total energy of a pair for the initial Fröhlich Hamiltonian is found. Differences between the solutions for the model and initial two-particle problems are discussed.

  7. Formation of asteroid pairs by rotational fission.

    PubMed

    Pravec, P; Vokrouhlický, D; Polishook, D; Scheeres, D J; Harris, A W; Galád, A; Vaduvescu, O; Pozo, F; Barr, A; Longa, P; Vachier, F; Colas, F; Pray, D P; Pollock, J; Reichart, D; Ivarsen, K; Haislip, J; Lacluyze, A; Kusnirák, P; Henych, T; Marchis, F; Macomber, B; Jacobson, S A; Krugly, Yu N; Sergeev, A V; Leroy, A

    2010-08-26

    Pairs of asteroids sharing similar heliocentric orbits, but not bound together, were found recently. Backward integrations of their orbits indicated that they separated gently with low relative velocities, but did not provide additional insight into their formation mechanism. A previously hypothesized rotational fission process may explain their formation-critical predictions are that the mass ratios are less than about 0.2 and, as the mass ratio approaches this upper limit, the spin period of the larger body becomes long. Here we report photometric observations of a sample of asteroid pairs, revealing that the primaries of pairs with mass ratios much less than 0.2 rotate rapidly, near their critical fission frequency. As the mass ratio approaches 0.2, the primary period grows long. This occurs as the total energy of the system approaches zero, requiring the asteroid pair to extract an increasing fraction of energy from the primary's spin in order to escape. We do not find asteroid pairs with mass ratios larger than 0.2. Rotationally fissioned systems beyond this limit have insufficient energy to disrupt. We conclude that asteroid pairs are formed by the rotational fission of a parent asteroid into a proto-binary system, which subsequently disrupts under its own internal system dynamics soon after formation.

  8. 351 New Common Proper-Motion Pairs from the Sloan Digital Sky Survey

    NASA Astrophysics Data System (ADS)

    Caballero, Rafael

    2012-01-01

    This paper presents 351 previously uncataloged pairs with separation under 100 arcseconds and proper motion over 70 milliseconds of arc/year. These pairs are the result of an extensive study that started with 96,205 candidate pairs from the Sloan Digital Survey (SDSS). Different criteria explained in the paper are applied to increase the probability of a physical bound between the components.

  9. Petawatt laser absorption bounded

    PubMed Central

    Levy, Matthew C.; Wilks, Scott C.; Tabak, Max; Libby, Stephen B.; Baring, Matthew G.

    2014-01-01

    The interaction of petawatt (1015 W) lasers with solid matter forms the basis for advanced scientific applications such as table-top particle accelerators, ultrafast imaging systems and laser fusion. Key metrics for these applications relate to absorption, yet conditions in this regime are so nonlinear that it is often impossible to know the fraction of absorbed light f, and even the range of f is unknown. Here using a relativistic Rankine-Hugoniot-like analysis, we show for the first time that f exhibits a theoretical maximum and minimum. These bounds constrain nonlinear absorption mechanisms across the petawatt regime, forbidding high absorption values at low laser power and low absorption values at high laser power. For applications needing to circumvent the absorption bounds, these results will accelerate a shift from solid targets, towards structured and multilayer targets, and lead the development of new materials. PMID:24938656

  10. Quantum Phases of Fermionic Cold Atoms Through Pairing and Dissociation

    NASA Astrophysics Data System (ADS)

    Lopez, Nicolas; Tsai, Shan-Wen; Timmermans, E.; Lin, Chi-Yong

    2011-03-01

    Cold atom experiments have realized molecule creation consisting of paired fermions and dissociation of weakly bound molecules into correlated fermions by tuning of the interactions with external fields [1,2]. We study many-body correlations in such system where molecules are weakly bound and therefore pairs of fermionic atoms convert into and dissociate from the bound molecule state. This exchange mediates a long-range interaction between the fermions. We consider a simple many-body Hamiltonian that includes the destruction of fermionic atom pairs to form single bosonic molecules and vice versa. We employ a functional renormalization-group approach to search for instabilities from the disordered quantum liquid phase that may arise from a boson mediated fermion-fermion interaction. We calculate the renormalized frequency-dependent fermion interactions vertices and renormalized molecular binding energy.

  11. The Peak Pairs algorithm for strain mapping from HRTEM images.

    PubMed

    Galindo, Pedro L; Kret, Sławomir; Sanchez, Ana M; Laval, Jean-Yves; Yáñez, Andrés; Pizarro, Joaquín; Guerrero, Elisa; Ben, Teresa; Molina, Sergio I

    2007-11-01

    Strain mapping is defined as a numerical image-processing technique that measures the local shifts of image details around a crystal defect with respect to the ideal, defect-free, positions in the bulk. Algorithms to map elastic strains from high-resolution transmission electron microscopy (HRTEM) images may be classified into two categories: those based on the detection of peaks of intensity in real space and the Geometric Phase approach, calculated in Fourier space. In this paper, we discuss both categories and propose an alternative real space algorithm (Peak Pairs) based on the detection of pairs of intensity maxima in an affine transformed space dependent on the reference area. In spite of the fact that it is a real space approach, the Peak Pairs algorithm exhibits good behaviour at heavily distorted defect cores, e.g. interfaces and dislocations. Quantitative results are reported from experiments to determine local strain in different types of semiconductor heterostructures.

  12. Universal bounds on current fluctuations

    NASA Astrophysics Data System (ADS)

    Pietzonka, Patrick; Barato, Andre C.; Seifert, Udo

    2016-05-01

    For current fluctuations in nonequilibrium steady states of Markovian processes, we derive four different universal bounds valid beyond the Gaussian regime. Different variants of these bounds apply to either the entropy change or any individual current, e.g., the rate of substrate consumption in a chemical reaction or the electron current in an electronic device. The bounds vary with respect to their degree of universality and tightness. A universal parabolic bound on the generating function of an arbitrary current depends solely on the average entropy production. A second, stronger bound requires knowledge both of the thermodynamic forces that drive the system and of the topology of the network of states. These two bounds are conjectures based on extensive numerics. An exponential bound that depends only on the average entropy production and the average number of transitions per time is rigorously proved. This bound has no obvious relation to the parabolic bound but it is typically tighter further away from equilibrium. An asymptotic bound that depends on the specific transition rates and becomes tight for large fluctuations is also derived. This bound allows for the prediction of the asymptotic growth of the generating function. Even though our results are restricted to networks with a finite number of states, we show that the parabolic bound is also valid for three paradigmatic examples of driven diffusive systems for which the generating function can be calculated using the additivity principle. Our bounds provide a general class of constraints for nonequilibrium systems.

  13. Paired Straight Hearth Furnace

    SciTech Connect

    2009-04-01

    This factsheet describes a research project whose goals are to design, develop, and evaluate the scalability and commercial feasibility of the PSH Paired Straight Hearth Furnace alternative ironmaking process.

  14. Facts about Birth Defects

    MedlinePlus

    ... and Palate Clubfoot Craniosynostosis Down Syndrome Eye Defects Fetal Alcohol Syndrome Disorders Gastroschisis Heart Defects Coarctation of the Aorta ... grow and develop. For some birth defects, like fetal alcohol syndrome, we know the cause. But for most birth ...

  15. Atrial septal defect (ASD)

    MedlinePlus

    ... other heart defects of the ventricular septum and mitral valve . Secundum defects can be a single, small ... Sometimes, open-heart surgery may be needed to repair the defect. The type of surgery is more ...

  16. Single Ventricle Defects

    MedlinePlus

    ... Healthy Heart Function Common Types of Heart Defects - Aortic Valve Stenosis (AVS) - Atrial Septal Defect (ASD) - Coarctation of the Aorta (CoA) - Complete Atrioventricular Canal defect (CAVC) - d-Transposition ...

  17. Neural Tube Defects

    MedlinePlus

    Neural tube defects are birth defects of the brain, spine, or spinal cord. They happen in the first month ... she is pregnant. The two most common neural tube defects are spina bifida and anencephaly. In spina ...

  18. Noncompeting channel approach to pair creation in supercritical fields.

    PubMed

    Lv, Q Z; Liu, Y; Li, Y J; Grobe, R; Su, Q

    2013-11-01

    The Dirac and Klein-Gordon equations are solved on a space-time grid to study the strong-field induced pair creation process for bosons and fermions from the vacuum. If the external field is sufficiently strong to induce bound states that are embedded in the negative energy continuum, a complex scaling technique of the Hamiltonian can predict the longtime behavior of the dynamics. In the case of multiple bound states this technique predicts the occurrence of a new collective time scale. The longtime behavior of the pair creation is not determined by a single (most important) channel, but collectively by the sum of all individual widths of the embedded states.

  19. Isospin Mixing and the Continuum Coupling in Weakly Bound Nuclei

    SciTech Connect

    Michel, N.; Nazarewicz, Witold; Ploszajczak, M.

    2010-01-01

    We investigate the near-threshold behavior of one-nucleon spectroscopic factors in mirror nuclei using the Gamow Shell Model, which simultaneously takes into account many-body correlations and continuum effects. We demonstrate that for weakly bound or unbound systems, the mirror symmetry-breaking effects are appreciable, and they manifest in large differences of spectroscopic factors in a mirror pair.

  20. Blog life: Entropy Bound

    NASA Astrophysics Data System (ADS)

    Steinberg, Peter

    2008-06-01

    Who is the blog written by? Peter Steinberg is a nuclear physicist at the Brookhaven National Laboratory in New York, US. He is acting project manager of the PHOBOS experiment, which used Brookhaven's Relativistic Heavy Ion Collider (RHIC) to search for unusual events produced during collisions between gold nuclei. He is also involved with the PHENIX experiment, which seeks to discover a new state of matter known as the quark-gluon plasma. In addition to his own blog Entropy Bound, Steinberg is currently blogging on a website that was set up last year to publicize the involvement of US scientists with the Large Hadron Collider (LHC) at CERN.

  1. Defect complexes in semiconductors and insulators

    NASA Astrophysics Data System (ADS)

    Raebiger, Hannes

    2010-03-01

    The interaction of isolated defects and impurities (concentration upto ˜10^18 cm-3) is usually rationalized as that of point charges in a dielectric medium, but as defect concentrations are in the order of atomic percent (˜10^21 cm-3), the statistical probability for two or more defects to sit on neighboring sites, forming a cluster or complex, becomes significant [1]. The formation of such clusters changes the local chemical environment, which in turn affects the electronic (and optical and magnetic) properties of the constituent defects non-trivially. To understand these changes, I study a variety of bound defect complexes in wide-gap semiconductors, composed of both deep and shallow defects, focusing on the shifting of the gap levels caused by defect--defect chemical interactions. First the electronic structure is calculated from first principles calculations, and then I will outline a simple theory that describes the level shifts due to cluster formation qualitatively and semi-quantitatively in terms local atomic shielding constants derived from local charge self-regulation [2].[4pt] [1] R. Behringer, J. Chem. Phys. 29, 537 (1958).[0pt] [2] H. Raebiger, S. Lany, and A. Zunger, Nature 453, 763 (2008).

  2. Line defects and (framed) BPS quivers

    NASA Astrophysics Data System (ADS)

    Cirafici, Michele

    2013-11-01

    The BPS spectrum of certain = 2 supersymmetric field theories can be determined algebraically by studying the representation theory of BPS quivers. We introduce methods based on BPS quivers to study line defects. The presence of a line defect opens up a new BPS sector: framed BPS states can be bound to the defect. The defect can be geometrically described in terms of laminations on a curve. To a lamination we associate certain elements of the Leavitt path algebra of the BPS quiver and use them to compute the framed BPS spectrum. We also provide an alternative characterization of line defects by introducing framed BPS quivers. Using the theory of (quantum) cluster algebras, we derive an algorithm to compute the framed BPS spectra of new defects from known ones. Line defects are generated from a framed BPS quiver by applying certain sequences of mutation operations. Framed BPS quivers also behave nicely under a set of "cut and join" rules, which can be used to study how = 2 systems with defects couple to produce more complicated ones. We illustrate our formalism with several examples.

  3. Pair distribution functions of silicon/silicon nitride interfaces

    NASA Astrophysics Data System (ADS)

    Cao, Deng; Bachlechner, Martina E.

    2006-03-01

    Using molecular dynamics simulations, we investigate different mechanical and structural properties of the silicon/silicon nitride interface. One way to characterize the structure as tensile strain is applied parallel to the interface is to calculate pair distribution functions for specific atom types. The pair distribution function gives the probability of finding a pair of atoms a distance r apart, relative to the probability expected for a completely random distribution at the same density. The pair distribution functions for bulk silicon nitride reflect the fracture of the silicon nitride film at about 8 % and the fact that the centerpiece of the silicon nitride film returns to its original structure after fracture. The pair distribution functions for interface silicon atoms reveal the formation of bonds for originally unbound atom pairs, which is indicative of the interstitial-vacancy defect that causes failure in silicon.

  4. Multifunctions of bounded variation

    NASA Astrophysics Data System (ADS)

    Vinter, R. B.

    2016-02-01

    Consider control systems described by a differential equation with a control term or, more generally, by a differential inclusion with velocity set F (t , x). Certain properties of state trajectories can be derived when it is assumed that F (t , x) is merely measurable w.r.t. the time variable t. But sometimes a refined analysis requires the imposition of stronger hypotheses regarding the time dependence. Stronger forms of necessary conditions for minimizing state trajectories can be derived, for example, when F (t , x) is Lipschitz continuous w.r.t. time. It has recently become apparent that significant addition properties of state trajectories can still be derived, when the Lipschitz continuity hypothesis is replaced by the weaker requirement that F (t , x) has bounded variation w.r.t. time. This paper introduces a new concept of multifunctions F (t , x) that have bounded variation w.r.t. time near a given state trajectory, of special relevance to control. We provide an application to sensitivity analysis.

  5. Culture-bound syndromes.

    PubMed

    Levine, R E; Gaw, A C

    1995-09-01

    Since its inception, scholars have struggled with the concept of CBSs. This struggle is reflected in the continuing use of a term that is confusing and inaccurate. Most authors would agree that the term "culture-bound syndrome" was intended to describe forms of otherwise common mental illness that are rendered unusual because of the pathoplastic influence of culture. It was intended not only to describe specific syndromes, but also meanings of illness and non-Western notions of disease causation. The term has become an anachronism, for the word, "syndrome," implies specific disease entities, not illnesses of attribution of idioms of distress. Furthermore, the word "bound" implies that the entities described are restricted to a single culture. Close examination reveals that many of the so-called "culture-bound" syndromes are found in multiple cultures that have in common only that they are "non-Western." It may be unreasonable to expect one term to describe these different concepts. The most accurate of the designations offered might be "folk diagnostic categories." Perhaps the most difficult question remaining is "How can we understand (and classify) these phenomena in such a way that highlights their uniqueness but does not dismiss them as too rare and exotic to warrant attention?" The first step is to recognize that the CBSs are a heterogeneous group of conditions. We must next acknowledge that the concepts represented may be difficult for the average Western clinician to recognize but, in their respective cultures, are neither rare nor unusual. With 80% of our increasingly shrinking world coming from "non-Western" cultures, a familiarity with non-Western notions of disease causation is particularly important for modern clinicians. Many authors have recommended that those CBSs that are "true" syndromes be classified together with their Western counterparts. In order to do this, the folk labels need to be put aside and the fundamental components of each disorder

  6. Determination of the fermion pair size in a resonantly interacting superfluid.

    PubMed

    Schunck, Christian H; Shin, Yong-Il; Schirotzek, André; Ketterle, Wolfgang

    2008-08-07

    Fermionic superfluidity requires the formation of particle pairs, the size of which varies from the femtometre scale in neutron stars and nuclei to the micrometre scale in conventional superconductors. Many properties of the superfluid depend on the pair size relative to the interparticle spacing. This is expressed in 'BCS-BEC crossover' theories, describing the crossover from a Bardeen-Cooper-Schrieffer (BCS)-type superfluid of loosely bound, large Cooper pairs to Bose-Einstein condensates (BECs) of tightly bound molecules. Such a crossover superfluid has been realized in ultracold atomic gases where high-temperature superfluidity has been observed. The microscopic properties of the fermion pairs can be probed using radio-frequency spectroscopy. However, previous work was difficult to interpret owing to strong final-state interactions that were not well understood. Here we realize a superfluid spin mixture in which such interactions have negligible influence and present fermion pair dissociation spectra that reveal the underlying pairing correlations. This allows us to determine that the spectroscopic pair size in the resonantly interacting gas is 20 per cent smaller than the interparticle spacing. These are the smallest pairs so far observed in fermionic superfluids, highlighting the importance of small fermion pairs for superfluidity at high critical temperatures. We have also identified transitions from fermion pairs to bound molecular states and to many-body bound states in the case of strong final-state interactions.

  7. On Adiabatic Pair Creation

    NASA Astrophysics Data System (ADS)

    Pickl, Peter; Dürr, Detlef

    2008-08-01

    We give here a rigorous proof of the well known prediction of pair creation as it arises from the Dirac equation with an external time dependent potential. Pair creation happens with probability one if the potential changes adiabatically in time and becomes overcritical, which means that an eigenvalue curve (as a function of time) bridges the gap between the negative and positive spectral continuum. The potential can be thought of as being zero at large negative and large positive times. The rigorous treatment of this effect has been lacking since the pioneering work of Beck, Steinwedel and Süßmann [1] in 1963 and Gershtein and Zeldovich [8] in 1970.

  8. Physical Mechanism of Photon Pairing in a Kerr Nonlinear Medium

    NASA Astrophysics Data System (ADS)

    Cheng, Ze

    2017-01-01

    We establish that Cooper instability of the ground state of a normal blackbody triggers the attractive photons to form the pairs. We next find that however small the effective interphoton attraction V 0 is, Cooper pairs of photon always exist in the ground state of a Kerr nonlinear blackbody. It has been pointed out that there are the three fundamental properties of the Cooper pair of photon: the extremely large binding energy, the extremely small radius, and the extremely high critical temperature. These properties are reflected in the many-photon bound state described by the optical superfluid theory.

  9. Direct Cavity Detection of Majorana Pairs

    NASA Astrophysics Data System (ADS)

    Dartiailh, Matthieu C.; Kontos, Takis; Douçot, Benoit; Cottet, Audrey

    2017-03-01

    No experiment could directly test the particle-antiparticle duality of Majorana fermions, so far. However, this property represents a necessary ingredient towards the realization of topological quantum computing schemes. Here, we show how to complete this task by using microwave techniques. The direct coupling between a pair of overlapping Majorana bound states and the electric field from a microwave cavity is extremely difficult to detect due to the self-adjoint character of Majorana fermions which forbids direct energy exchanges with the cavity. We show theoretically how this problem can be circumvented by using photoassisted tunneling to fermionic reservoirs. The absence of a direct microwave transition inside the Majorana pair in spite of the light-Majorana coupling would represent a smoking gun for the Majorana self-adjoint character.

  10. Minimal Pairs: Minimal Importance?

    ERIC Educational Resources Information Center

    Brown, Adam

    1995-01-01

    This article argues that minimal pairs do not merit as much attention as they receive in pronunciation instruction. There are other aspects of pronunciation that are of greater importance, and there are other ways of teaching vowel and consonant pronunciation. (13 references) (VWL)

  11. Sculpture, view looking to pair of lions, positioned at top ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Sculpture, view looking to pair of lions, positioned at top of stairs leading down into the Glen from DeWitt Circle, just north of the American Bungalow (note: Windmill in background) - National Park Seminary, Bounded by Capitol Beltway (I-495), Linden Lane, Woodstove Avenue, & Smith Drive, Silver Spring, Montgomery County, MD

  12. Defect properties of ZnO nanowires

    NASA Astrophysics Data System (ADS)

    Stehr, J. E.; Devika, M.; Reddy, N. Koteeswara; Tu, C. W.; Chen, W. M.; Buyanova, I. A.

    2014-02-01

    In this work we examined optical and defect properties of as-grown and Ni-coated ZnO nanowires (NWs) grown by rapid thermal chemical vapor deposition by means of optically detected magnetic resonance (ODMR). Several grown-in defects are revealed by monitoring visible photoluminescence (PL) emissions and are attributed to Zn vacancies, O vacancies, a shallow (but not effective mass) donor and exchange-coupled pairs of a Zn vacancy and a Zn interstitial. It is also found that the same ODMR signals are detected in the as-grown and Ni-coated NWs, indicating that metal coatings does not significantly affect formation of the aforementioned defects and that the observed defects are located in the bulk of the NWs.

  13. Superrotations and black hole pair creation

    NASA Astrophysics Data System (ADS)

    Strominger, Andrew; Zhiboedov, Alexander

    2017-03-01

    Recent work has shown that the symmetries of classical gravitational scattering in asymptotically flat spacetimes include, at the linearized level, infinitesimal superrotations. These act like Virasoro generators on the celestial sphere at null infinity. However, due to the singularities in these generators, the physical status of finite superrotations has remained unclear. Here we address this issue in the context of the breaking of a cosmic string via quantum black hole pair nucleation. This process is described by a gravitational instanton known as the C-metric. After pair production, the black holes are pulled by the string to null infinity with a constant acceleration. At late times the string decays and the spacetime settles into a vacuum state. We show that the early and late spacetimes before and after string decay differ by a finite superrotation. This provides a physical interpretation of superrotations. They act on spacetimes which are asymptotically flat everywhere except at isolated singularities with cosmic string defects.

  14. Point defects quenched in NiAl and related intermetallic compounds

    NASA Astrophysics Data System (ADS)

    Fan, Jiawen

    1991-08-01

    Point defects in the highly ordered B2 compounds NiAl, CoAl and FeAl were studied using the perturbed gamma-gamma angular correlations (PAC) technique. Quadrupole interactions detected at dilute In-111 probes on Al sites in NiAl and CoAl were identified with complexes containing one or two vacancies in the first atomic shell. Measurements on rapidly quenched NiAl and CoAl exhibited increases in site fractions of vacancy-probe complexes caused by formation of thermal defects. Site fractions were analyzed using the law of mass action to obtain absolute vacancy concentrations. PAC is shown to be a powerful new technique for the quantitative study of equilibrium defects in solids. For NiAl, the vacancy concentration quenched-in from a given temperature was found to be independent of composition over the range 50.4 to 53.5 at. pct. Ni, identifying the Schottky defect (vacancy pair) as the dominant equilibrium defect, and ruling out the so-called triple defect. Formation energies and entropies of Schottky pairs were determined to be 2.66(8) and 3.48(12) eV, and 12(1) and 17(2) k sub B, respectively, for NiAl and CoAl. The entropies suggest huge vacancy concentrations, 13 pct. at the melting temperatures of NiAl and CoAl. Migration energies of Ni and Co vacancies were found to be 1.8(2) and 2.5(2) eV, respectively. FeAl exhibited complex behavior. A low temperature regime was detected in NiAl and CoAl within which vacancies are mobile but do not anneal out, so that the vacancy concentration remains constant. In NiAl, this 'bottleneck' regime extends from 350 to 700 C. Vacancies were found to be bound to the In probes with an energy very close to 0.20 eV in NiAl and CoAl. An explanation of the bottleneck is proposed in terms of saturation of all lattice sinks. This annealing bottleneck should exist in a wide range of intermetallic compounds when there is a sufficiently high vacancy concentration.

  15. Therapeutic drugs in early pregnancy and congenital defects.

    PubMed

    McDonald, A D

    1994-01-01

    In a study of occupation and pregnancy outcome, information was collected on certain non-occupational factors including therapeutic drugs taken in the first trimester, reported by some 17% of women. A case-referent analysis was made of data from pregnancies leading to 787 major (class 1) and 2386 miscellaneous minor (class 2) congenital defects compared with pregnancies without defects, matched for hospital, maternal age and educational level. In pairs discordant for one of seven drug groups, ratios of positive pairs (case with drug) to negative pairs (referent with drug) were for class 1 defects 164:148, relative risk (RR) 1.11 and for class 2 defects 433:383, RR 1.13. Only anti-infective drugs showed an increased RR: 1.70 (p = 0.06). This was mainly with nervous/sensory defects (10:2; RR 5.0, p = 0.04) but no one type of defect or type of drug was identified; the infections for which the drugs were given might have been responsible. For class 1 defects two pairs were positive for anti-convulsant drugs and two negative; no increase in risk was found for any specific drugs including doxylamine succinate (Bendectin).

  16. Bound Rationality and Organizational Learning.

    DTIC Science & Technology

    1989-09-23

    8217 . 90 0 8 0.. O 4 BOUNDED RATIONALITY AND ORGANIZATIONAL LEARNING Technical Report AlP - 107 Herbert A. Simon Department of Psychology Carnegie Mellon...ACCESSION No N/A N/A N/A N/A 1 1 TITLE (include Security Classificarnon) Bounded rationality and organizational learning 12 PERSONAL AUTHOR(S) HretA io 13a...organizations organizational psychology organizational learning bounded rationality cognitive psychology 𔄃 ABSTRACT (Continue on reverse if necessary

  17. Aerodynamics of intermittent bounds in flying birds

    NASA Astrophysics Data System (ADS)

    Tobalske, Bret W.; Hearn, Jason W. D.; Warrick, Douglas R.

    Flap-bounding is a common flight style in small birds in which flapping phases alternate with flexed-wing bounds. Body lift is predicted to be essential to making this flight style an aerodynamically attractive flight strategy. To elucidate the contributions of the body and tail to lift and drag during the flexed-wing bound phase, we used particle image velocimetry (PIV) and measured properties of the wake of zebra finch (Taeniopygia guttata, N = 5), flying at 6-10 m s- 1 in a variable speed wind tunnel as well as flow around taxidermically prepared specimens (N = 4) mounted on a sting instrumented with force transducers. For the specimens, we varied air velocity from 2 to 12 m s- 1 and body angle from -15∘ to 50∘. The wake of bounding birds and mounted specimens consisted of a pair of counterrotating vortices shed into the wake from the tail, with induced downwash in the sagittal plane and upwash in parasagittal planes lateral to the bird. This wake structure was present even when the tail was entirely removed. We observed good agreement between force measures derived from PIV and force transducers over the range of body angles typically used by zebra finch during forward flight. Body lift:drag (L:D) ratios averaged 1.4 in live birds and varied between 1 and 1.5 in specimens at body angles from 10∘ to 30∘. Peak (L:D) ratio was the same in live birds and specimens (1.5) and was exhibited in specimens at body angles of 15∘ or 20∘, consistent with the lower end of body angles utilized during bounds. Increasing flight velocity in live birds caused a decrease in CL and CD from maximum values of 1.19 and 0.95 during flight at 6 m s- 1 to minimum values of 0.70 and 0.54 during flight at 10 m s- 1. Consistent with delta-wing theory as applied to birds with a graduated-tail shape, trimming the tail to 0 and 50% of normal length reduced L:D ratios and extending tail length to 150% of normal increased L:D ratio. As downward induced velocity is present in the

  18. Aerodynamics of intermittent bounds in flying birds

    NASA Astrophysics Data System (ADS)

    Tobalske, Bret W.; Hearn, Jason W. D.; Warrick, Douglas R.

    2009-05-01

    Flap-bounding is a common flight style in small birds in which flapping phases alternate with flexed-wing bounds. Body lift is predicted to be essential to making this flight style an aerodynamically attractive flight strategy. To elucidate the contributions of the body and tail to lift and drag during the flexed-wing bound phase, we used particle image velocimetry (PIV) and measured properties of the wake of zebra finch ( Taeniopygia guttata, N = 5), flying at 6-10 m s-1 in a variable speed wind tunnel as well as flow around taxidermically prepared specimens ( N = 4) mounted on a sting instrumented with force transducers. For the specimens, we varied air velocity from 2 to 12 m s-1 and body angle from -15° to 50°. The wake of bounding birds and mounted specimens consisted of a pair of counter-rotating vortices shed into the wake from the tail, with induced downwash in the sagittal plane and upwash in parasagittal planes lateral to the bird. This wake structure was present even when the tail was entirely removed. We observed good agreement between force measures derived from PIV and force transducers over the range of body angles typically used by zebra finch during forward flight. Body lift:drag ( L: D) ratios averaged 1.4 in live birds and varied between 1 and 1.5 in specimens at body angles from 10° to 30°. Peak ( L: D) ratio was the same in live birds and specimens (1.5) and was exhibited in specimens at body angles of 15° or 20°, consistent with the lower end of body angles utilized during bounds. Increasing flight velocity in live birds caused a decrease in C L and C D from maximum values of 1.19 and 0.95 during flight at 6 m s-1 to minimum values of 0.70 and 0.54 during flight at 10 m s-1. Consistent with delta-wing theory as applied to birds with a graduated-tail shape, trimming the tail to 0 and 50% of normal length reduced L: D ratios and extending tail length to 150% of normal increased L: D ratio. As downward induced velocity is present in the

  19. Pumping Electron-Positron Pairs from a Well Potential

    PubMed Central

    Wang, Qiang; Liu, Jie; Fu, Li-bin

    2016-01-01

    In the presence of very deep well potential, electrons will spontaneously occupy the empty embedded bound states and electron-positron pairs are created by means of a non-perturbative tunneling process. In this work, by slowly oscillating the width or depth, the population transfer channels are opened and closed periodically. We find and clearly show that by the non-synchronous ejections of particles, the saturation of pair number in a static super-critical well can be broken, and electrons and positrons can be pumped inexhaustibly from vacuum with a constant production rate. In the adiabatic limit, final pair number after a single cycle has quantized values as a function of the upper boundary of the oscillating, and the critical upper boundaries indicate the diving points of the bound states. PMID:27125998

  20. Pumping Electron-Positron Pairs from a Well Potential

    NASA Astrophysics Data System (ADS)

    Wang, Qiang; Liu, Jie; Fu, Li-Bin

    2016-04-01

    In the presence of very deep well potential, electrons will spontaneously occupy the empty embedded bound states and electron-positron pairs are created by means of a non-perturbative tunneling process. In this work, by slowly oscillating the width or depth, the population transfer channels are opened and closed periodically. We find and clearly show that by the non-synchronous ejections of particles, the saturation of pair number in a static super-critical well can be broken, and electrons and positrons can be pumped inexhaustibly from vacuum with a constant production rate. In the adiabatic limit, final pair number after a single cycle has quantized values as a function of the upper boundary of the oscillating, and the critical upper boundaries indicate the diving points of the bound states.

  1. Defect coarsening in a biological system: the vascular cambium of cottonwood trees.

    PubMed

    Kramer, Eric M; Groves, Joseph V

    2003-04-01

    We present micrographic evidence for the annihilation of topological defect pairs and defect-mediated coarsening in the vascular cambium of cottonwood trees (Populus deltoides). We also show that a recently published mathematical model of cell orientation dynamics in the cambium reproduces many qualitative features of the defect coarsening process.

  2. Protected Flux Pairing Qubit

    NASA Astrophysics Data System (ADS)

    Bell, Matthew; Zhang, Wenyuan; Ioffe, Lev; Gershenson, Michael

    2014-03-01

    We have studied the coherent flux tunneling in a qubit containing two submicron Josephson junctions shunted by a superinductor (a dissipationless inductor with an impedance much greater than the resistance quantum). The two low energy quantum states of this device, 0 and 1, are represented by even and odd number of fluxes in the loop, respectively. This device is dual to the charge pairing Josephson rhombi qubit. The spectrum of the device, studied by microwave spectroscopy, reflects the interference between coherent quantum phase slips in the two junctions (the Aharonov-Casher effect). The time domain measurements demonstrate the suppression of the qubit's energy relaxation in the protected regime, which illustrates the potential of this flux pairing device as a protected quantum circuit. Templeton Foundation, NSF, and ARO.

  3. Junctionless Cooper pair transistor

    NASA Astrophysics Data System (ADS)

    Arutyunov, K. Yu.; Lehtinen, J. S.

    2017-02-01

    Quantum phase slip (QPS) is the topological singularity of the complex order parameter of a quasi-one-dimensional superconductor: momentary zeroing of the modulus and simultaneous 'slip' of the phase by ±2π. The QPS event(s) are the dynamic equivalent of tunneling through a conventional Josephson junction containing static in space and time weak link(s). Here we demonstrate the operation of a superconducting single electron transistor (Cooper pair transistor) without any tunnel junctions. Instead a pair of thin superconducting titanium wires in QPS regime was used. The current-voltage characteristics demonstrate the clear Coulomb blockade with magnitude of the Coulomb gap modulated by the gate potential. The Coulomb blockade disappears above the critical temperature, and at low temperatures can be suppressed by strong magnetic field.

  4. TOPICAL REVIEW: O- bound small polarons in oxide materials

    NASA Astrophysics Data System (ADS)

    Schirmer, O. F.

    2006-11-01

    Holes bound to acceptor defects in oxide crystals are often localized by lattice distortion at just one of the equivalent oxygen ligands of the defect. Such holes thus form small polarons in symmetric clusters of a few oxygen ions. An overview on mainly the optical manifestations of those clusters is given. The article is essentially divided into two parts: the first one covers the basic features of the phenomena and their explanations, exemplified by several paradigmatic defects; in the second part numerous oxide materials are presented which exhibit bound small polaron optical properties. The first part starts with summaries on the production of bound hole polarons and the identification of their structure. It is demonstrated why they show strong, wide absorption bands, usually visible, based on polaron stabilization energies of typically 1 eV. The basic absorption process is detailed with a fictitious two-well system. Clusters with four, six and twelve equivalent ions are realized in various oxide compounds. In these cases several degenerate optically excited polaron states occur, leading to characteristic final state resonance splittings. The peak energies of the absorption bands as well as the sign of the transfer energy depend on the topology of the clusters. A special section is devoted to the distinction between interpolaron and intrapolaron optical transitions. The latter are usually comparatively weak. The oxide compounds exhibiting bound hole small polaron absorptions include the alkaline earth oxides (e.g. MgO), BeO and ZnO, the perovskites BaTiO3 and KTaO3, quartz, the sillenites (e.g. Bi12TiO20), Al2O3, LiNbO3, topaz and various other materials. There are indications that the magnetic crystals NiO, doped with Li, and LaMnO3, doped with Sr, also show optical features caused by bound hole polarons. Beyond being elementary paradigms for the properties of small polarons in general, the defect species treated can be used to explain radiation and light

  5. Northwest Outward Bound Instructor's Manual.

    ERIC Educational Resources Information Center

    Northwest Outward Bound School, Portland, OR.

    Instructor responsibilities, procedures for completing activities safely, and instructional methods and techniques are outlined to assist instructors in the Northwest Outward Bound School (Portland, Oregon) as they strive for teaching excellence. Information is organized into six chapters addressing: history and philosophy of Outward Bound; course…

  6. Fractional diffusion on bounded domains

    DOE PAGES

    Defterli, Ozlem; D'Elia, Marta; Du, Qiang; ...

    2015-03-13

    We found that the mathematically correct specification of a fractional differential equation on a bounded domain requires specification of appropriate boundary conditions, or their fractional analogue. In this paper we discuss the application of nonlocal diffusion theory to specify well-posed fractional diffusion equations on bounded domains.

  7. Bounds for Asian basket options

    NASA Astrophysics Data System (ADS)

    Deelstra, Griselda; Diallo, Ibrahima; Vanmaele, Michèle

    2008-09-01

    In this paper we propose pricing bounds for European-style discrete arithmetic Asian basket options in a Black and Scholes framework. We start from methods used for basket options and Asian options. First, we use the general approach for deriving upper and lower bounds for stop-loss premia of sums of non-independent random variables as in Kaas et al. [Upper and lower bounds for sums of random variables, Insurance Math. Econom. 27 (2000) 151-168] or Dhaene et al. [The concept of comonotonicity in actuarial science and finance: theory, Insurance Math. Econom. 31(1) (2002) 3-33]. We generalize the methods in Deelstra et al. [Pricing of arithmetic basket options by conditioning, Insurance Math. Econom. 34 (2004) 55-57] and Vanmaele et al. [Bounds for the price of discrete sampled arithmetic Asian options, J. Comput. Appl. Math. 185(1) (2006) 51-90]. Afterwards we show how to derive an analytical closed-form expression for a lower bound in the non-comonotonic case. Finally, we derive upper bounds for Asian basket options by applying techniques as in Thompson [Fast narrow bounds on the value of Asian options, Working Paper, University of Cambridge, 1999] and Lord [Partially exact and bounded approximations for arithmetic Asian options, J. Comput. Finance 10 (2) (2006) 1-52]. Numerical results are included and on the basis of our numerical tests, we explain which method we recommend depending on moneyness and time-to-maturity.

  8. Atrioventricular Canal Defect

    MedlinePlus

    ... al. Clinical manifestations, pathophysiology, and diagnosis of atrioventricular (AV) canal defects. http://www.uptodate.com/home. Accessed ... CE, et al. Management and outcome of atrioventricular (AV) canal defects. http://www.uptodate.com/home. Accessed ...

  9. Birth Defects (For Parents)

    MedlinePlus

    ... to create energy. Examples of metabolic defects include Tay-Sachs disease , a fatal disease that affects the central nervous ... called recessive inheritance and includes conditions such as Tay-Sachs disease and cystic fibrosis . A disease or defect also ...

  10. Metabolism of organically bound tritium

    SciTech Connect

    Travis, C.C.

    1984-01-01

    The classic methodology for estimating dose to man from environmental tritium ignores the fact that organically bound tritium in foodstuffs may be directly assimilated in the bound compartment of tissues without previous oxidation. We propose a four-compartment model consisting of a free body water compartment, two organic compartments, and a small, rapidly metabolizing compartment. The utility of this model lies in the ability to input organically bound tritium in foodstuffs directly into the organic compartments of the model. We found that organically bound tritium in foodstuffs can increase cumulative total body dose by a factor of 1.7 to 4.5 times the free body water dose alone, depending on the bound-to-loose ratio of tritium in the diet. Model predictions are compared with empirical measurements of tritium in human urine and tissue samples, and appear to be in close agreement. 10 references, 4 figures, 3 tables.

  11. Pair of Craters

    NASA Technical Reports Server (NTRS)

    2005-01-01

    14 July 2005 This Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) image shows a 1.5 meters per pixel (5 ft/pixel) view of a pair of small meteor impact craters in the Arena Colles region of Mars, located north of Isidis Planitia.

    Location near: 22.7oN, 278.5oW Image width: width: 3 km (1.9 mi) Illumination from: lower left Season: Northern Autumn

  12. Donor-vacancy pairs in irradiated n-Ge: A searching look at the problem

    SciTech Connect

    Emtsev, Vadim; Oganesyan, Gagik

    2014-02-21

    The present situation concerning the identification of vacancy-donor pairs in irradiated n-Ge is discussed. The challenging points are the energy states of these defects deduced from DLTS spectra. Hall effect data seem to be at variance with some important conclusions drawn from DLTS measurements. Critical points of the radiation-produced defect modeling in n-Ge are highlighted.

  13. Defects in liquid crystal nematic shells

    NASA Astrophysics Data System (ADS)

    Fernandez-Nieves, A.; Utada, A. S.; Vitelli, V.; Link, D. R.; Nelson, D. R.; Weitz, D. A.

    2006-03-01

    We generate water/liquid crystal (LC)/water double emulsions via recent micro-capillary fluidic devices [A. S. Utada, et.al. Science 308, 537 (2005)]. The resultant objects are stabilized against coalescence by using surfactants or adequate polymers; these also fix the boundary conditions for the director field n. We use 4-pentyl-4-cyanobiphenyl (5CB) and impose tangential boundary conditions at both water/LC interfaces by having polyvinyl alcohol (PVA) dispersed in the inner and outer water phases. We confirm recent predictions [D. R. Nelson, NanoLetters 2, 1125 (2002)] and find that four strength s=+1/2 defects are present; this is in contrast to the two s=+1 defect bipolar configuration observed for bulk spheres [A. Fernandez-Nieves, et.al. Phys. Rev. Lett. 92, 105503 (2004)]. However, these defects do not lie in the vertices of a tetrahedron but are pushed towards each other until certain equilibration distance is reached. In addition to the four defect shells, we observe shells with two s=+1 defects and even with three defects, a s=+1 and two s=+1/2. We argue these configurations arise from nematic bulk distortions that become important as the shell thickness increases. Finally, by adding a different surfactant, sodium dodecyl sulphate (SDS), to the outer phase, we can change the director boundary conditions at the outermost interface from parallel to homeotropic, to induce coalescing of the two pair of defects in the four defect shell configuration to yield two defect bipolar shells.

  14. Swelling Mechanisms of UO2 Lattices with Defect Ingrowths

    PubMed Central

    Günay, Seçkin D.

    2015-01-01

    The swelling that occurs in uranium dioxide as a result of radiation-induced defect ingrowth is not fully understood. Experimental and theoretical groups have attempted to explain this phenomenon with various complex theories. In this study, experimental lattice expansion and lattice super saturation were accurately reproduced using a molecular dynamics simulation method. Based on their resemblance to experimental data, the simulation results presented here show that fission induces only oxygen Frenkel pairs while alpha particle irradiation results in both oxygen and uranium Frenkel pair defects. Moreover, in this work, defects are divided into two sub-groups, obstruction type defects and distortion type defects. It is shown that obstruction type Frenkel pairs are responsible for both fission- and alpha-particle-induced lattice swelling. Relative lattice expansion was found to vary linearly with the number of obstruction type uranium Frenkel defects. Additionally, at high concentrations, some of the obstruction type uranium Frenkel pairs formed diatomic and triatomic structures with oxygen ions in their octahedral cages, increasing the slope of the linear dependence. PMID:26244777

  15. Effects of QCD bound states on dark matter relic abundance

    NASA Astrophysics Data System (ADS)

    Liew, Seng Pei; Luo, Feng

    2017-02-01

    We study scenarios where there exists an exotic massive particle charged under QCD in the early Universe. We calculate the formation and dissociation rates of bound states formed by pairs of these particles, and apply the results in dark matter (DM) coannihilation scenarios, including also the Sommerfeld effect. We find that on top of the Sommerfeld enhancement, bound-state effects can further significantly increase the largest possible DM masses which can give the observed DM relic abundance, by ˜ 30-100% with respect to values obtained by considering the Sommerfeld effect only, for the color triplet or octet exotic particles we consider. In particular, it indicates that the Bino DM mass in the right-handed stop-Bino coannihilation scenario in the Minimal Supersymmetric extension of the Standard Model (MSSM) can reach ˜ 2.5 TeV, even though the potential between the stop and antistop prior to forming a bound state is repulsive. We also apply the bound-state effects in the calculations of relic abundance of long-lived or metastable massive colored particles, and discuss the implications on the BBN constraints and the abundance of a super-weakly interacting DM. The corrections for the bound-state effect when the exotic massive colored particles also carry electric charges, and the collider bounds are also discussed.

  16. Topological defect lasers

    NASA Astrophysics Data System (ADS)

    Knitter, Sebastian; Fatt Liew, Seng; Xiong, Wen; Guy, Mikhael I.; Solomon, Glenn S.; Cao, Hui

    2016-01-01

    We introduce a topological defect to a regular photonic crystal defect cavity with anisotropic unit cell. Spatially localized resonances are formed and have high quality factor. Unlike the regular photonic crystal defect states, the localized resonances in the topological defect structures support powerflow vortices. Experimentally we realize lasing in the topological defect cavities with optical pumping. This work shows that the spatially inhomogeneous variation of the unit cell orientation adds another degree of freedom to the control of lasing modes, enabling the manipulation of the field pattern and energy flow landscape.

  17. Congenital defects of sheep.

    PubMed

    Dennis, S M

    1993-03-01

    With increasing incrimination of viruses, plants, and drugs as causes of ovine congenital defects, concerted efforts are required to identify environmental teratogens. Expanding knowledge of congenital defects requires studying as many defective lambs as possible; recording and documenting; detailed diagnostic examinations; genetic analyses and chromosomal examinations, whenever possible; and field investigations. Adopting standardized classification, terminology, and diagnostic procedures should improve descriptions, diagnoses, and interdisciplinary exchange of information. That, in turn, should improve our knowledge of and diagnosis of congenital defects of sheep in the future. Finally, veterinary clinicians and diagnosticians are encouraged to take an interest in congenital defects and teratology.

  18. Defect production in ceramics

    SciTech Connect

    Zinkle, S.J.; Kinoshita, C.

    1997-08-01

    A review is given of several important defect production and accumulation parameters for irradiated ceramics. Materials covered in this review include alumina, magnesia, spinel silicon carbide, silicon nitride, aluminum nitride and diamond. Whereas threshold displacement energies for many ceramics are known within a reasonable level of uncertainty (with notable exceptions being AIN and Si{sub 3}N{sub 4}), relatively little information exists on the equally important parameters of surviving defect fraction (defect production efficiency) and point defect migration energies for most ceramics. Very little fundamental displacement damage information is available for nitride ceramics. The role of subthreshold irradiation on defect migration and microstructural evolution is also briefly discussed.

  19. Type III burst pair

    NASA Astrophysics Data System (ADS)

    Ning, Zongjun; Fu, Qijun; Lu, Quankang

    2000-05-01

    We present a special solar radio burst detected on 5 January 1994 using the multi-channel (50) spectrometer (1.0-2.0 GHz) of the Beijing Astronomical Observatory (BAO). Sadly, the whole event could not be recorded since it had a broader bandwidth than the limit range of the instrument. The important part was obtained, however. The event is composed of a normal drift type III burst on the lower frequency side and a reverse drift type III burst appearing almost simultaneously on the high side. We call the burst type III a burst pair. It is a typical characteristic of two type III bursts that they are morphologically symmetric about some frequency from 1.64 GHz to 1.78 GHz on the dynamic spectra records, which indicates that there are two different electron beams from the same acceleration region travelling simultaneously in opposite directions (upward and downward). A magnetic reconnection mode is a nice interpretation of type III burst pair since the plasma beta β~=0.01 is much less than 1 and the beams have velocity of about 1.07×10^8 cm s^-1 after leaving the reconnection region if we assume that the ambient magnetic field strength is about 100 G.

  20. Type III burst pair.

    NASA Astrophysics Data System (ADS)

    Zongjun, Ning; Fu, Qijun; Quankang, Lu

    2000-05-01

    Presents a special solar radio burst detected on 5 January 1994 using the multi-channel (50) spectrometer (1.0 - 2.0 GHz) of the Beijing Astronomical Observatory. Sadly, the whole event could not be recorded since it had a broader bandwidth than the limit range of the instrument. The important part was obtained, however. The event is composed of a normal drift type III burst on the lower frequency side and a reverse drift type III burst appearing almost simultaneously on the high side. The authors call the burst type III a burst pair. It is a typical characteristic of two type III bursts that they are morphologically symmetric about some frequency from 1.64 GHz to 1.78 GHz on the dynamic spectra records, which indicates that there are two different electron beams from the same acceleration region travelling simultaneously in opposite directions (upward and downward). A magnetic reconnection mode is an interpretation of type III burst pair.

  1. Nonuniversal BBN bounds on electromagnetically decaying particles

    NASA Astrophysics Data System (ADS)

    Poulin, Vivian; Serpico, Pasquale Dario

    2015-05-01

    In Poulin and Serpico [Phys. Rev. Lett. 114, 091101 (2015)] we recently argued that when the energy of a photon injected in the primordial plasma falls below the pair-production threshold the universality of the nonthermal photon spectrum from the standard theory of electromagnetic cascades onto a photon background breaks down. We showed that this could reopen or widen the parameter space for an exotic solution to the "lithium problem." Here we discuss another application, namely the impact that this has on nonthermal big bang nucleosynthesis constraints from He 4 , He 3 , and H 2 , using the parametric example of monochromatic photon injection of different energies. Typically, we find tighter bounds than those existing in the literature, up to more than 1 order of magnitude. As a consequence of the nonuniversality of the spectrum, the energy dependence of the photodissociation cross sections is important. We also compare the constraints obtained with current level and future reach of cosmic microwave background spectral distortion bounds.

  2. Restricted Defect Dynamics in Colloidal Peanut Crystals

    NASA Astrophysics Data System (ADS)

    Gerbode, Sharon; Lee, Stephanie; John, Bettina; Wolfgang, Angie; Liddell, Chekesha; Escobedo, Fernando; Cohen, Itai

    2008-03-01

    We report that monolayers of hard peanut-shaped colloidal particles consisting of two connected spherical lobes order into a crystalline phase at high area fractions. In this ``lobe-close-packed'' (LCP) crystal, the peanut particle lobes occupy triangular lattice sites, much like close-packed spheres, while the connections between lobe pairs are randomly oriented, uniformly populating the three crystalline directions of the underlying lattice. Using optical microscopy, we directly observe defect nucleation and dynamics in sheared LCP crystals. We find that many particle configurations form obstacles blocking dislocation glide. Consequently, in stark contrast to colloidal monolayers of close-packed spheres, single dislocation pair nucleation is not the only significant energetic barrier to relieving an imposed shear strain. Dislocation propagation beyond such obstructions can proceed only through additional mechanisms such as dislocation reactions. We discuss the implications of such restricted defect mobility for the plasticity of LCP crystals.

  3. Restricted Defect Dynamics in Colloidal Peanut Crystals

    NASA Astrophysics Data System (ADS)

    Gerbode, Sharon; Lee, Stephanie; John, Bettina; Wolfgang, Angie; Liddell, Chakesha; Escobedo, Fernando; Cohen, Itai

    2008-03-01

    We report that monolayers of hard peanut-shaped colloidal particles consisting of two connected spherical lobes order into a crystalline phase at high area fractions. In this ``lobe- close-packed'' (LCP) crystal, the peanut particle lobes occupy triangular lattice sites, much like close-packed spheres, while the connections between lobe pairs are randomly oriented, uniformly populating the three crystalline directions of the underlying lattice. Using optical microscopy, we directly observe defect nucleation and dynamics in sheared LCP crystals. We find that many particle configurations form obstacles blocking dislocation glide. Consequently, in stark contrast to colloidal monolayers of close-packed spheres, single dislocation pair nucleation is not the only significant energetic barrier to relieving an imposed shear strain. Dislocation propagation beyond such obstructions can proceed only through additional mechanisms such as dislocation reactions. We discuss the implications of such restricted defect mobility for the plasticity of LCP crystals.

  4. Postdevelopment defect evaluation

    NASA Astrophysics Data System (ADS)

    Miyahara, Osamu; Kiba, Yukio; Ono, Yuko

    2001-08-01

    Reduction of defects after development is a critical issue in photolithography. A special category of post development defects is the satellite defect which is located in large exposed areas generally in proximity to large unexposed regions of photoresist. We have investigated the formation of this defect type on ESCAP and ACETAL DUV resists with and without underlying organic BARCs, In this paper, we will present AFM and elemental analysis data to determine the origin of the satellite defect. Imaging was done on a full-field Nikon 248nm stepper and resist processing was completed on a TEL CLEAN TRACK ACT 8 track. Defect inspection and review were performed on a KLA-Tencor and Hitachi SEM respectively. Results indicate that the satellite defect is generated on both BARC and resist films and defect counts are dependent on the dark erosion. Elemental analysis indicates that the defects are composed of sulfur and nitrogen compounds. We suspect that the defect is formed as a result of a reaction between PAG, quencher and TMAH. This defect type is removed after a DIW re-rinse.

  5. Etravirine in CSF is highly protein bound

    PubMed Central

    Nguyen, Anh; Rossi, Steven; Croteau, David; Best, Brookie M.; Clifford, David; Collier, Ann C.; Gelman, Benjamin; Marra, Christina; McArthur, Justin; McCutchan, J. Allen; Morgello, Susan; Simpson, David; Ellis, Ronald J.; Grant, Igor; Capparelli, Edmund; Letendre, Scott; Ellis, Ronald J.; Letendre, Scott; Abramson, Ian; Al-Lozi, Muhammad; Atkinson, J. Hampton; Capparelli, Edmund; Clifford, David; Collier, Ann C.; Fennema-Notestine, Christine; Gamst, Anthony C.; Gelman, Benjamin; Heaton, Robert K.; Marcotte, Thomas D.; Marra, Christina; McCutchan, J. Allen; McArthur, Justin; Morgello, Susan; Simpson, David; Smith, Davey M.; Taylor, Michael J.; Theilmann, Rebecca; Vaida, Florin; Paul Woods, Steven; Cushman, Clint; Dawson, Matthew; Franklin, Donald; Jones, Trudy; Lewis, Kristen; Mintz, Letty; Teshome, Mengesha; Toperoff, Will

    2013-01-01

    Objectives Etravirine has high affinity for plasma drug-binding proteins, such as albumin and α1-acid glycoprotein, which limits the amount of unbound etravirine available to enter the CNS. The objective of this study was to compare total and unbound etravirine concentrations in CSF with plasma concentrations and the in vitro median inhibitory concentration (IC50) for wild-type HIV (0.9 ng/mL). Methods Total and bound etravirine concentrations were measured in 17 CSF and plasma pairs by isotope-dilution liquid chromatography tandem mass spectroscopy, radioligand displacement and ultracentrifugation. Unbound etravirine concentrations were calculated from the bound fraction. The dynamic range of the assay was 7.8–2000 (plasma) and 0.78–200 (CSF) ng/mL. Results Subjects were mostly middle-aged (median 43 years) white (78%) men (89%). All CSF etravirine concentrations were above the limit of quantification. Total and unbound median etravirine concentrations in CSF were 9.5 (IQR 6.4, 26.4) and 0.13 (IQR 0.08, 0.27) ng/mL, respectively. Etravirine was 96% (IQR 94.5, 97.2) protein bound in plasma and 98.4% (IQR 97.8, 98.8) in CSF. Total etravirine in CSF was 4.3% (IQR 3, 5.9) of total and 101% (IQR 76, 160) of unbound etravirine in plasma. There were no significant correlations between unbound etravirine concentrations and concentrations of albumin in plasma or CSF. Unbound etravirine concentrations in CSF did not reach the wild-type IC50 in any of the specimens. Conclusions Unbound etravirine may not achieve optimal concentrations to inhibit HIV replication in the CNS. PMID:23335197

  6. Octagonal Defects at Carbon Nanotube Junctions

    PubMed Central

    Jaskólski, W.; Pelc, M.; Chico, Leonor; Ayuela, A.

    2013-01-01

    We investigate knee-shaped junctions of semiconductor zigzag carbon nanotubes. Two dissimilar octagons appear at such junctions; one of them can reconstruct into a pair of pentagons. The junction with two octagons presents two degenerate localized states at Fermi energy (EF). The reconstructed junction has only one state near EF, indicating that these localized states are related to the octagonal defects. The inclusion of Coulomb interaction splits the localized states in the junction with two octagons, yielding an antiferromagnetic system. PMID:24089604

  7. Ventricular Septal Defect (For Parents)

    MedlinePlus

    ... Atrial Septal Defect Ventricular Septal Defect Heart and Circulatory System ECG (Electrocardiogram) Anesthesia - What to Expect Tetralogy of ... Atrial Septal Defect Ventricular Septal Defect Heart and Circulatory System Contact Us Print Resources Send to a friend ...

  8. Ventricular Septal Defect (For Parents)

    MedlinePlus

    ... Atrial Septal Defect Ventricular Septal Defect Heart and Circulatory System ECG (Electrocardiogram) Anesthesia - What to Expect Tetralogy of ... Atrial Septal Defect Ventricular Septal Defect Heart and Circulatory System Contact Us Print Resources Send to a Friend ...

  9. Finding Bounded Rational Equilibria. Part 1; Iterative Focusing

    NASA Technical Reports Server (NTRS)

    Wolpert, David H.

    2004-01-01

    A long-running difficulty with conventional game theory has been how to modify it to accommodate the bounded rationality characterizing all real-world players. A recurring issue in statistical physics is how best to approximate joint probability distributions with decoupled (and therefore far more tractable) distributions. It has recently been shown that the same information theoretic mathematical structure, known as Probability Collectives (PC) underlies both issues. This relationship between statistical physics and game theory allows techniques and insights from the one field to be applied to the other. In particular, PC provides a formal model-independent definition of the degree of rationality of a player and of bounded rationality equilibria. This pair of papers extends previous work on PC by introducing new computational approaches to effectively find bounded rationality equilibria of common-interest (team) games.

  10. Binaries and triples among asteroid pairs

    NASA Astrophysics Data System (ADS)

    Pravec, Petr; Scheirich, Peter; Kušnirák, Peter; Hornoch, Kamil; Galád, Adrián

    2015-08-01

    smaller (with one exception) than the bound orbiting secondaries. I will compare the observed properties of the paired binaries to predictions from theories of formation of asteroid binaries and pairs.

  11. Topology optimization of compliant mechanisms using pairs of curves

    NASA Astrophysics Data System (ADS)

    Wang, N. F.; Zhang, X. M.

    2015-11-01

    The structural topology optimization approach can be used to generate compliant mechanisms for some desired input-output requirements. The success of the optimization depends on the structural geometry representation scheme used. In this paper, a novel representation scheme is proposed. The representation scheme is characterized by pairs of curves that are used to connect Input/Ouput (I/O) regions of the structure. Each pair of curves includes a normal curve and a fat curve. The areas bounded by the pair of curves define the material distribution between them. All I/O regions are connected to one another (either directly or indirectly) by pairs of curves in order to form one single connected load-bearing structure. A genetic algorithm for constrained and multiobjective optimization is then applied with the representation scheme of the structure in the form of a graph. Simulation results from a displacement inverter and a displacement redirector indicate that the presented representation scheme is appropriate.

  12. Bound states in string nets

    NASA Astrophysics Data System (ADS)

    Schulz, Marc Daniel; Dusuel, Sébastien; Vidal, Julien

    2016-11-01

    We discuss the emergence of bound states in the low-energy spectrum of the string-net Hamiltonian in the presence of a string tension. In the ladder geometry, we show that a single bound state arises either for a finite tension or in the zero-tension limit depending on the theory considered. In the latter case, we perturbatively compute the binding energy as a function of the total quantum dimension. We also address this issue in the honeycomb lattice where the number of bound states in the topological phase depends on the total quantum dimension. Finally, the internal structure of these bound states is analyzed in the zero-tension limit.

  13. Mechanics of Miura-ori Origami Lattice Defects

    NASA Astrophysics Data System (ADS)

    Silverberg, Jesse; McLeod, Lauren; Evans, Arthur; Ginepro, Jessica; Santangelo, Christian; Hull, Thomas; Cohen, Itai

    2014-03-01

    The mechanical properties of origami-inspired materials show remarkable potential for responsive, tunable next-generation materials. For example, the Miura-ori fold is predicted to have negative Poisson ratio and anisotropic compressive properties. Using a custom mechanical testing device and 3D laser profilometry, we investigate the moduli and the role of curvature in setting these material properties. Because defects are known to dramatically alter the bulk properties in other periodic materials, we introduce defects into the folding pattern to investigate their effects on the macroscopic mechanical properties. Interestingly, we find that a single defect increases the overall material stiffness, but the introduction of a second defect in the opposite direction can cancel out the first, tending to restore the original material properties. Moreover, these defect pairs can be arranged to form edge dislocations, grain boundaries, and many other topological configurations familiar from the study of crystallographic lattice defects.

  14. Point Defects in Two-Dimensional Layered Semiconductors: Physics and Its Applications

    NASA Astrophysics Data System (ADS)

    Suh, Joonki

    thermoelectric materials are thoroughly investigated. Point defects can potentially beat the undesired coupling, often term "thermoelectric Bermuda triangle", among electrical conductivity, thermal conductivity and thermopower. The maximum thermoelectric performance is demonstrated with an intermediate density of defects when they beneficially and multi-functionally act as electron donors, as well as strongly energy-dependent electron and phonon scatterers. Therefore, this is a good example of how fundamental defect physics can be applied for practical devices toward renewable energy technology. Another interesting field of layered nanomaterials is on transition-metal dichalcogenides (TMDs), sensational candidates for 2D semiconductor physics and applications. At the reduced dimensionality of 2D where a far stronger correlation between point defects and charge carriers is expected, it is studied how chalcogen vacancies alter optical properties of monolayer TMDs. A new, sub-bandgap broad emission lines as well as increase in the overall photoluminescence intensity at low temperatures are reported as a result of high quantum efficiency of excitons, i.e., bound electron-hole pairs, localized at defect sites. On electrical transport, both n- and p-type materials are needed to form junctions and support bipolar carrier conduction while typically only one type of doping is stable for a particular TMD. For example, MoS2 is natively n-type, thus the lack of p-type doping hampers the development of charge-splitting p-n junctions of MoS2. To address this issue, we demonstrate stable p-type conduction in MoS2 by substitutional Nb doping up to the degenerate level. Proof-of-concept, van der Waals p-n homo-junctions based on vertically stacked MoS2 layers are also fabricated which enable gate-tuneable current rectification. Various electronic devices fabricated are stable in ambient air even without additional treatment such as capping layer protection, thanks to the substitutionality nature

  15. Effective response theory for zero-energy Majorana bound states in three spatial dimensions

    NASA Astrophysics Data System (ADS)

    Lopes, Pedro L. e. S.; Teo, Jeffrey C. Y.; Ryu, Shinsei

    2015-05-01

    We propose a gravitational response theory for point defects (hedgehogs) binding Majorana zero modes in (3 + 1)-dimensional superconductors. Starting in 4 + 1 dimensions, where the point defect is extended into a line, a coupling of the bulk defect texture with the gravitational field is introduced. Diffeomorphism invariance then leads to an S U (2) 2 Kac-Moody current running along the defect line. The S U (2) 2 Kac-Moody algebra accounts for the non-Abelian nature of the zero modes in 3 + 1 dimensions. It is then shown to also encode the angular momentum density which permeates throughout the bulk between hedgehog-antihedgehog pairs.

  16. Single-point position and transition defects in continuous time quantum walks

    PubMed Central

    Li, Z. J.; Wang, J. B.

    2015-01-01

    We present a detailed analysis of continuous time quantum walks (CTQW) with both position and transition defects defined at a single point in the line. Analytical solutions of both traveling waves and bound states are obtained, which provide valuable insight into the dynamics of CTQW. The number of bound states is found to be critically dependent on the defect parameters, and the localized probability peaks can be readily obtained by projecting the state vector of CTQW on to these bound states. The interference between two bound states are also observed in the case of a transition defect. The spreading of CTQW probability over the line can be finely tuned by varying the position and transition defect parameters, offering the possibility of precision quantum control of the system. PMID:26323855

  17. Multiprocessor switch with selective pairing

    DOEpatents

    Gara, Alan; Gschwind, Michael K; Salapura, Valentina

    2014-03-11

    System, method and computer program product for a multiprocessing system to offer selective pairing of processor cores for increased processing reliability. A selective pairing facility is provided that selectively connects, i.e., pairs, multiple microprocessor or processor cores to provide one highly reliable thread (or thread group). Each paired microprocessor or processor cores that provide one highly reliable thread for high-reliability connect with a system components such as a memory "nest" (or memory hierarchy), an optional system controller, and optional interrupt controller, optional I/O or peripheral devices, etc. The memory nest is attached to a selective pairing facility via a switch or a bus

  18. Upper bounds on the error probabilities and asymptotic error exponents in quantum multiple state discrimination

    SciTech Connect

    Audenaert, Koenraad M. R.; Mosonyi, Milán

    2014-10-01

    We consider the multiple hypothesis testing problem for symmetric quantum state discrimination between r given states σ₁, …, σ{sub r}. By splitting up the overall test into multiple binary tests in various ways we obtain a number of upper bounds on the optimal error probability in terms of the binary error probabilities. These upper bounds allow us to deduce various bounds on the asymptotic error rate, for which it has been hypothesized that it is given by the multi-hypothesis quantum Chernoff bound (or Chernoff divergence) C(σ₁, …, σ{sub r}), as recently introduced by Nussbaum and Szkoła in analogy with Salikhov's classical multi-hypothesis Chernoff bound. This quantity is defined as the minimum of the pairwise binary Chernoff divergences min{sub jbound is actually achieved. It was known to be achieved, in particular, when the state pair that is closest together in Chernoff divergence is more than 6 times closer than the next closest pair. Our results improve on this in two ways. First, we show that the optimal asymptotic rate must lie between C/2 and C. Second, we show that the Chernoff bound is already achieved when the closest state pair is more than 2 times closer than the next closest pair. We also show that the Chernoff bound is achieved when at least r - 2 of the states are pure, improving on a previous result by Nussbaum and Szkoła. Finally, we indicate a number of potential pathways along which a proof (or disproof) may eventually be found that the multi-hypothesis quantum Chernoff bound is always achieved.

  19. Stereo Pair, Pasadena, California

    NASA Technical Reports Server (NTRS)

    2000-01-01

    This stereoscopic image pair is a perspective view that shows the western part of the city of Pasadena, California, looking north toward the San Gabriel Mountains. Portions of the cities of Altadena and La Canada Flintridge are also shown. The cluster of large buildings left of center, at the base of the mountains, is the Jet Propulsion Laboratory. This image shows the power of combining data from different sources to create planning tools to study problems that affect large urban areas. In addition to the well-known earthquake hazards, Southern California is affected by a natural cycle of fire and mudflows. Data shown in this image can be used to predict both how wildfires spread over the terrain and how mudflows are channeled down the canyons.

    The image was created from three datasets: the Shuttle Radar Topography Mission (SRTM) supplied the elevation, U. S. Geological Survey digital aerial photography provided the image detail, and the Landsat Thematic Mapper provided the color. The United States Geological Survey's Earth Resources Observations Systems (EROS) Data Center, Sioux Falls, South Dakota, provided the Landsat data and the aerial photography. The image can be viewed in 3-D by viewing the left image with the right eye and the right image with the left eye (cross-eyed viewing), or by downloading and printing the image pair, and viewing them with a stereoscope.

    The Shuttle Radar Topography Mission (SRTM), launched on February 11, 2000, used the same radar instrument that comprised the Spaceborne Imaging Radar-C/X-Band Synthetic Aperture Radar (SIR-C/X-SAR) that flew twice on the Space Shuttle Endeavour in 1994. The mission was designed to collect three-dimensional measurements of the Earth's surface. To collect the 3-D data, engineers added a 60-meter-long (200-foot) mast, an additional C-band imaging antenna and improved tracking and navigation devices. The mission is a cooperative project between the National Aeronautics and Space Administration

  20. Observation of 3D defect mediated dust acoustic wave turbulence with fluctuating defects and amplitude hole filaments

    SciTech Connect

    Chang, Mei-Chu; Tsai, Ya-Yi; I, Lin

    2013-08-15

    We experimentally demonstrate the direct observation of defect mediated wave turbulence with fluctuating defects and low amplitude hole filaments, from a 3D self-excited plane dust acoustic wave in a dusty plasma by reducing dissipation. The waveform undulation is found to be the origin for the amplitude and the phase modulations of the local dust density oscillation, the broadening of the sharp peaks in the frequency spectrum, and the fluctuating defects. The corrugated wave crest surface also causes the observed high and low density patches in the transverse (xy) plane. Low oscillation amplitude spots (holes) share the same positions with the defects. Their trajectories in the xyt space appear in the form of chaotic filaments without long term predictability, through uncertain pair generation, propagation, and pair annihilation.

  1. Cooperon condensation and intravalley pairing states in honeycomb Dirac systems

    NASA Astrophysics Data System (ADS)

    Tsuchiya, Shunji; Goryo, Jun; Arahata, Emiko; Sigrist, Manfred

    2016-09-01

    Motivated by recent developments in the experimental study of superconducting graphene and transition metal dichalcogenides, we investigate superconductivity of the Kane-Mele (KM) model with short-range attractive interactions on the two-dimensional honeycomb lattice. We show that intravalley spin-triplet pairing arises from nearest-neighbor (NN) attractive interaction and the intrinsic spin-orbit coupling. We demonstrate this in two independent approaches: We study superconducting instability driven by condensation of Cooperons, which are in-gap bound states of two conduction electrons, within the T -matrix approximation and also study the superconducting ground state within the mean-field theory. We find that Cooperons with antiparallel spins condense at the K and K' points. This leads to the emergence of an intravalley spin-triplet pairing state belonging to the irreducible representation A1 of the point group C6 v. The fact that this pairing state has opposite chirality for K and K' identifies this state as a "helical" valley-triplet state, the valley analog to the 3He -B phase in two dimensions. Because of the finite center of mass momentum of Cooper pairs, the pair amplitude in NN bonds exhibits spatial modulation on the length scale of lattice constant, such that this pairing state may be viewed as a pair-density wave state. We find that the pair amplitude spontaneously breaks the translational symmetry and exhibits a p -Kekulé pattern. We also discuss the selection rule for pairing states focusing the characteristic band structure of the KM model and the Berry phase effects to the emergence of the intravalley pairing state.

  2. Pygmy stars: first pair.

    PubMed

    Zwicky, F

    1966-07-01

    The binary LP 101-15/16 having the proper motion of 1.62 seconds of arc per year has been studied with the prime-focus spectrograph of the 200-inch (508 cm) telescope. Indications are that LP 101-15/16 is the first pair of pygmy stars ever discovered. One of its components, LP 101-16, is probably a blue pygmy star which is at least four magnitudes fainter than the ordinary white dwarfs. Also, two of the Balmer lines in absorption appear to be displaced toward the red by amounts which indicate the existence of an Einstein gravitational red shift corresponding to about 1000 km sec-1. On the other hand LP 101-15 is red and shows an entirely new type of spectrum, which suggests that it may be a first representative of a type of red pygmy star which is 2.5 magnitudes fainter than the M-type dwarf stars of the main sequence.

  3. Multiple focused EMAT designs for improved surface breaking defect characterization

    NASA Astrophysics Data System (ADS)

    Thring, C. B.; Fan, Y.; Edwards, R. S.

    2017-02-01

    Ultrasonic Rayleigh waves can be employed for the detection of surface breaking defects such as rolling contact fatigue and stress corrosion cracking. Electromagnetic Acoustic Transducers (EMATs) are well suited to this technique as they can directly generate Rayleigh waves within the sample without the requirement for wedges, and they are robust and inexpensive compared to laser ultrasonics. Three different EMAT coil types have been developed, and these are compared to assess their ability to detect and characterize small (down to 0.5 mm depth, 1 mm diameter) surface breaking defects in aluminium. These designs are: a pair of linear meander coils used in a pseudo-pulse-echo mode, a pair of focused meander coils also used in pseudo-pulse-echo mode, and a pair of focused racetrack coils used in pitch-catch mode. The linear meander coils are able to detect most of the defects tested, but have a much lower signal to noise ratio and give limited sizing information. The focused meander coils and the focused racetrack coils can detect all defects tested, but have the advantage that they can also characterize the defect sizes on the sample surface, and have a stronger sensitivity at their focal point. Measurements using all three EMAT designs are presented and compared for high resolution imaging of surface-breaking defects.

  4. Maximum common subgraph: some upper bound and lower bound results

    PubMed Central

    Huang, Xiuzhen; Lai, Jing; Jennings, Steven F

    2006-01-01

    Background Structure matching plays an important part in understanding the functional role of biological structures. Bioinformatics assists in this effort by reformulating this process into a problem of finding a maximum common subgraph between graphical representations of these structures. Among the many different variants of the maximum common subgraph problem, the maximum common induced subgraph of two graphs is of special interest. Results Based on current research in the area of parameterized computation, we derive a new lower bound for the exact algorithms of the maximum common induced subgraph of two graphs which is the best currently known. Then we investigate the upper bound and design techniques for approaching this problem, specifically, reducing it to one of finding a maximum clique in the product graph of the two given graphs. Considering the upper bound result, the derived lower bound result is asymptotically tight. Conclusion Parameterized computation is a viable approach with great potential for investigating many applications within bioinformatics, such as the maximum common subgraph problem studied in this paper. With an improved hardness result and the proposed approaches in this paper, future research can be focused on further exploration of efficient approaches for different variants of this problem within the constraints imposed by real applications. PMID:17217524

  5. Kink pair production and dislocation motion

    PubMed Central

    Fitzgerald, S. P.

    2016-01-01

    The motion of extended defects called dislocations controls the mechanical properties of crystalline materials such as strength and ductility. Under moderate applied loads, this motion proceeds via the thermal nucleation of kink pairs. The nucleation rate is known to be a highly nonlinear function of the applied load, and its calculation has long been a theoretical challenge. In this article, a stochastic path integral approach is used to derive a simple, general, and exact formula for the rate. The predictions are in excellent agreement with experimental and computational investigations, and unambiguously explain the origin of the observed extreme nonlinearity. The results can also be applied to other systems modelled by an elastic string interacting with a periodic potential, such as Josephson junctions in superconductors. PMID:28004834

  6. Kink pair production and dislocation motion

    NASA Astrophysics Data System (ADS)

    Fitzgerald, S. P.

    2016-12-01

    The motion of extended defects called dislocations controls the mechanical properties of crystalline materials such as strength and ductility. Under moderate applied loads, this motion proceeds via the thermal nucleation of kink pairs. The nucleation rate is known to be a highly nonlinear function of the applied load, and its calculation has long been a theoretical challenge. In this article, a stochastic path integral approach is used to derive a simple, general, and exact formula for the rate. The predictions are in excellent agreement with experimental and computational investigations, and unambiguously explain the origin of the observed extreme nonlinearity. The results can also be applied to other systems modelled by an elastic string interacting with a periodic potential, such as Josephson junctions in superconductors.

  7. SDSS DR2 Merging pairs

    NASA Astrophysics Data System (ADS)

    Allam, S. S.; Tucker, D. L.; SDSS Collaboration

    2004-05-01

    We present and analyze a catalog of 9,000 Merging pairs candidates to g=21 from the imaging data of the Sloan Digital Sky Survey (SDSS) Second Data Release (DR2). Candidates were selected using an automated algorithm (Allam et al. 2004) that is efficient in its selection of galaxy pairs. We highlight possible science applications of such a large photometric sample of merging pais and discuss future improvements, including incorporating magnitudes and pushing to higher redshifts and fainter pairs.

  8. Uncertainty bounds using sector theory

    NASA Technical Reports Server (NTRS)

    Waszak, Martin R.; Schmidt, David K.

    1989-01-01

    An approach based on sector-stability theory can furnish a description of the uncertainty associated with the frequency response of a model, given sector-bounds on the individual parameters of the model. The application of the sector-based approach to the formulation of useful uncertainty descriptions for linear, time-invariant multivariable systems is presently explored, and the approach is applied to two generic forms of parameter uncertainty in order to investigate its advantages and limitations. The results obtained show that sector-uncertainty bounds can be used to evaluate the impact of parameter uncertainties on the frequency response of the design model.

  9. Controversies in kidney paired donation.

    PubMed

    Gentry, Sommer E; Montgomery, Robert A; Segev, Dorry L

    2012-07-01

    Kidney paired donation represented 10% of living kidney donation in the United States in 2011. National registries around the world and several separate registries in the United States arrange paired donations, although with significant variations in their practices. Concerns about ethical considerations, clinical advisability, and the quantitative effectiveness of these approaches in paired donation result in these variations. For instance, although donor travel can be burdensome and might discourage paired donation, it was nearly universal until convincing analysis showed that living donor kidneys can sustain many hours of cold ischemia time without adverse consequences. Opinions also differ about whether the last donor in a chain of paired donation transplants initiated by a nondirected donor should donate immediately to someone on the deceased donor wait-list (a domino or closed chain) or should be asked to wait some length of time and donate to start another sequence of paired donations later (an open chain); some argue that asking the donor to donate later may be coercive, and others focus on balancing the probability that the waiting donor withdraws versus the number of additional transplants if the chain can be continued. Other controversies in paired donation include simultaneous versus nonsimultaneous donor operations, whether to enroll compatible pairs, and interactions with desensitization protocols. Efforts to expand public awareness of and participation in paired donation are needed to generate more transplant opportunities.

  10. Detection of oocyte perivitelline membrane-bound sperm: a tool for avian collection management.

    PubMed

    Croyle, Kaitlin E; Durrant, Barbara S; Jensen, Thomas

    2015-01-01

    The success and sustainability of an avian breeding programme depend on managing productive and unproductive pairs. Given that each breeding season can be of immeasurable importance, it is critical to resolve pair fertility issues quickly. Such problems are traditionally diagnosed through behavioural observations, egg lay history and hatch rates, with a decision to re-pair generally taking one or more breeding seasons. In pairs producing incubated eggs that show little or no signs of embryonic development, determining fertility is difficult. Incorporating a technique to assess sperm presence on the oocyte could, in conjunction with behaviour and other data, facilitate a more timely re-pair decision. Detection of perivitelline membrane-bound (PVM-bound) sperm verifies successful copulation, sperm production and sperm functionality. Alternatively, a lack of detectable sperm, at least in freshly laid eggs, suggests no mating, lack of sperm production/function or sperm-oviduct incompatibility. This study demonstrated PVM-bound sperm detection by Hoechst staining in fresh to 24-day-incubated exotic eggs from 39 species representing 13 orders. However, a rapid and significant time-dependent loss of detectable PVM-bound sperm was observed following incubation of chicken eggs. The PCR detection of sperm in seven species, including two bacterially infected eggs, demonstrated that this method was not as reliable as visual detection using Hoechst staining. The absence of amplicons in visually positive PVMs was presumably due to large PVM size and low sperm count, resulting in DNA concentrations too low for standard PCR detection. In summary, this study demonstrated the feasibility and limitations of using PVM-bound sperm detection as a management tool for exotic avian species. We verified that sperm presence or absence on fluorescence microscopy can aid in the differentiation of fertile from infertile eggs to assist breeding managers in making prompt decisions for pair

  11. Detection of oocyte perivitelline membrane-bound sperm: a tool for avian collection management

    PubMed Central

    Croyle, Kaitlin E.; Durrant, Barbara S.; Jensen, Thomas

    2015-01-01

    The success and sustainability of an avian breeding programme depend on managing productive and unproductive pairs. Given that each breeding season can be of immeasurable importance, it is critical to resolve pair fertility issues quickly. Such problems are traditionally diagnosed through behavioural observations, egg lay history and hatch rates, with a decision to re-pair generally taking one or more breeding seasons. In pairs producing incubated eggs that show little or no signs of embryonic development, determining fertility is difficult. Incorporating a technique to assess sperm presence on the oocyte could, in conjunction with behaviour and other data, facilitate a more timely re-pair decision. Detection of perivitelline membrane-bound (PVM-bound) sperm verifies successful copulation, sperm production and sperm functionality. Alternatively, a lack of detectable sperm, at least in freshly laid eggs, suggests no mating, lack of sperm production/function or sperm–oviduct incompatibility. This study demonstrated PVM-bound sperm detection by Hoechst staining in fresh to 24-day-incubated exotic eggs from 39 species representing 13 orders. However, a rapid and significant time-dependent loss of detectable PVM-bound sperm was observed following incubation of chicken eggs. The PCR detection of sperm in seven species, including two bacterially infected eggs, demonstrated that this method was not as reliable as visual detection using Hoechst staining. The absence of amplicons in visually positive PVMs was presumably due to large PVM size and low sperm count, resulting in DNA concentrations too low for standard PCR detection. In summary, this study demonstrated the feasibility and limitations of using PVM-bound sperm detection as a management tool for exotic avian species. We verified that sperm presence or absence on fluorescence microscopy can aid in the differentiation of fertile from infertile eggs to assist breeding managers in making prompt decisions for pair

  12. Loosely-Bound Diatomic Molecules.

    ERIC Educational Resources Information Center

    Balfour, W. J.

    1979-01-01

    Discusses concept of covalent bonding as related to homonuclear diatomic molecules. Article draws attention to the existence of bound rare gas and alkaline earth diatomic molecules. Summarizes their molecular parameters and offers spectroscopic data. Strength and variation with distance of interatomic attractive forces is given. (Author/SA)

  13. Variational Bounds for Creeping Composites

    NASA Astrophysics Data System (ADS)

    Procházka, Petr

    2010-05-01

    In the paper time dependent variational bounds are derived based on Extended Hashin-Shtrikman variational principles. Direct calculation leads to explicit formulas to be presented in the text. For various mechanical properties easy coding in Excel, say, can be used and verification of accuracy for numerical procedures is available using the derived formulas.

  14. Pieter Paul Rubens, "Prometheus Bound."

    ERIC Educational Resources Information Center

    Shoemaker, Marla K.

    1986-01-01

    Provides a full-color reproduction of Pieter Paul Rubens' painting, "Prometheus Bound," and a lesson plan for using it with students in grades 10 through 12. The goal of the lesson is to introduce students to the techniques of design and execution used by Rubens. (JDH)

  15. Teacher Education in Outward Bound.

    ERIC Educational Resources Information Center

    Robinson, Richard A.

    A series of Outward Bound programs and experiences was planned for El Paso County, Colorado, school teachers to increase their awareness of their personal characteristics, especially those that might enhance learning on the part of their students. Part of the planning for the program involved a survey of county high school teachers, counselors,…

  16. Wronskian Method for Bound States

    ERIC Educational Resources Information Center

    Fernandez, Francisco M.

    2011-01-01

    We propose a simple and straightforward method based on Wronskians for the calculation of bound-state energies and wavefunctions of one-dimensional quantum-mechanical problems. We explicitly discuss the asymptotic behaviour of the wavefunction and show that the allowed energies make the divergent part vanish. As illustrative examples we consider…

  17. Asymptotic behavior of impurity-induced bound states in low-dimensional topological superconductors

    NASA Astrophysics Data System (ADS)

    Kaladzhyan, V.; Bena, C.; Simon, P.

    2016-12-01

    We study theoretically the asymptotic behavior of the Shiba bound states associated with magnetic impurities embedded in both 2D and 1D anomalous superconductors. We calculate analytically the spatial dependence of the local density of states together with the spin polarization associated with the Shiba bound states. We show that the latter quantity exhibits drastic differences between s-wave and different types of p-wave superconductors. Such properties, which could be measured using spin-polarized STM, offer therefore a way to discriminate between singlet and triplet pairing in low-dimensional superconductors, as well as a way to estimate the amplitude of the triplet pairing in these systems.

  18. Optical binding of particle pairs in retro-reflected beam geometry

    NASA Astrophysics Data System (ADS)

    Damková, Jana; Chvátal, Lukáš; Brzobohatý, Oto; Zemánek, Pavel

    2016-12-01

    Optical binding of polystyrene microparticle pairs in retro-reflected wide Gaussian beam, called "tractor beam", is studied experimentally and the results are compared with the numerical calculations based on the multiple-particle Mie scattering theory. To investigate the dynamics of optically bound particle pairs in three dimensions we employ holographic video microscopy technique. We show that the particle pair motion is strongly dependent on the relative distances of the particles and the switching between applying pushing and pulling force on particle pairs can be achieved only by changing their configuration even though the "tractor-beam" parameters remain unchanged.

  19. Defects and Ion-Solid Interactions in Silicon Carbide

    SciTech Connect

    Weber, William J.; Gao, Fei; Devanathan, Ram; Jiang, Weilin; Zhang, Yanwen

    2005-01-03

    Atomic-level simulations are used to determine defect production, cascade-overlap effects, and defect migration energies in SiC. Energetic C and Si collision cascades primarily produce single interstitials, mono-vacancies, antisite defects, and small defect clusters, while amorphous clusters are produced within 25% of Au cascades. Cascade overlap results in defect stimulated cluster growth that produces amorphization. The good agreement of disordering behavior and changes in volume and elastic modulus obtained computationally and experimentally provides atomic-level interpretation of experimentally observed features. Simulations indicate that close-pair recombination activation energies range from 0.24 to 0.38 eV, and long-range migration energies for interstitials and vacancies have been determined.

  20. Titania bound sodium titanate ion exchanger

    DOEpatents

    DeFilippi, Irene C. G.; Yates, Stephen Frederic; Shen, Jian-Kun; Gaita, Romulus; Sedath, Robert Henry; Seminara, Gary Joseph; Straszewski, Michael Peter; Anderson, David Joseph

    1999-03-23

    This invention is method for preparing a titania bound ion exchange composition comprising admixing crystalline sodium titanate and a hydrolyzable titanium compound and, thereafter drying the titania bound crystalline sodium titanate and subjecting the dried titania bound ion exchange composition to optional compaction and calcination steps to improve the physical strength of the titania bound composition.

  1. Nuclear and bound nucleon structure studies using GlueX

    NASA Astrophysics Data System (ADS)

    Patsyuk, Maria; Hen, Or; Williams, Mike

    2016-09-01

    We propose extending the physics program of the GlueX detector at Jefferson Lab to study structure of bound nucleon and short range correlations (SRC) in nuclei. Many important properties of nuclear systems are significantly influenced by the existence of SRC-pairs, which are high- momentum nucleons in a nucleus with considerably overlapping wave functions. Using the new JLab high-energy high-intensity photon beam, we will study exclusive meson photo-production on the nucleon in nuclei from Deuterium to Lead. We will compare the branching ratio of these reactions on semi-free nucleons in deuterium, deeply bound nucleons in heavier nuclei, and nucleons belonging to SRC pairs (by tagging the spectator recoil nucleon in the GlueX Barrel Calorimeter) in order to learn about short range structure of nuclei and the possible modification of the internal structure of bound nucleons. In this talk, we will present a brief summary of the physics goals and a data-driven determination of the neutron-detection efficiency using the so-called tag and probe technique.

  2. Oxygen defects in GaAs: A hybrid functional study

    NASA Astrophysics Data System (ADS)

    Colleoni, Davide; Pasquarello, Alfredo

    2016-03-01

    Using hybrid density functional calculations, we address the structural properties, formation energies, and charge transition levels of a variety of oxygen defects in GaAs. The set of considered defects comprises the bridging O atom in a As-O-Ga configuration, interstitial O atoms in tetrahedral sites, and O atoms substitutional to either Ga (OGa) or As atoms (OAs). In addition, we consider an As vacancy containing two O atoms, for which the most stable configurations are found through the use of molecular dynamics simulations, and defect complexes involving a OAs defect bound to either one or two AsGa antisites, denoted AsGa-OAs and (AsGa)2-OAs , respectively. We find that the bridging O defect and the AsGa-OAs and (AsGa)2-OAs complexes are the most stable oxygen defects in GaAs. The actual occurrence of these defects is examined against two criteria. The first criterion concerns the stability against O dissociation and is evaluated via the calculation of dissociation energies. The second criterion involves the defect formation at thermodynamic equilibrium and is inferred from the comparison between the formation energy of the oxygen defect and that of its O-related dissociation product (bridging O defect). Both the AsGa-OAs and (AsGa)2-OAs complexes satisfy these criteria and are stable against O dissociation. Further analysis in cooled-down conditions leads us to dismiss the AsGa-OAs defect due to the more favorable bonding of two rather than one AsGa antisites. The conclusion that only the bridging O defect and the (AsGa)2-OAs complex are expected to occur is in accord with experimental observations.

  3. Homologous pairing and the role of pairing centers in meiosis.

    PubMed

    Tsai, Jui-He; McKee, Bruce D

    2011-06-15

    Homologous pairing establishes the foundation for accurate reductional segregation during meiosis I in sexual organisms. This Commentary summarizes recent progress in our understanding of homologous pairing in meiosis, and will focus on the characteristics and mechanisms of specialized chromosome sites, called pairing centers (PCs), in Caenorhabditis elegans and Drosophila melanogaster. In C. elegans, each chromosome contains a single PC that stabilizes chromosome pairing and initiates synapsis of homologous chromosomes. Specific zinc-finger proteins recruited to PCs link chromosomes to nuclear envelope proteins--and through them to the microtubule cytoskeleton--thereby stimulating chromosome movements in early prophase, which are thought to be important for homolog sorting. This mechanism appears to be a variant of the 'telomere bouquet' process, in which telomeres cluster on the nuclear envelope, connect chromosomes through nuclear envelope proteins to the cytoskeleton and lead chromosome movements that promote homologous synapsis. In Drosophila males, which undergo meiosis without recombination, pairing of the largely non-homologous X and Y chromosomes occurs at specific repetitive sequences in the ribosomal DNA. Although no other clear examples of PC-based pairing mechanisms have been described, there is evidence for special roles of telomeres and centromeres in aspects of chromosome pairing, synapsis and segregation; these roles are in some cases similar to those of PCs.

  4. Diabetes mellitus and birth defects

    PubMed Central

    Correa, Adolfo; Gilboa, Suzanne M.; Besser, Lilah M.; Botto, Lorenzo D.; Moore, Cynthia A.; Hobbs, Charlotte A.; Cleves, Mario A.; Riehle-Colarusso, Tiffany J.; Waller, D. Kim; Reece, E. Albert

    2016-01-01

    OBJECTIVE The purpose of this study was to examine associations between diabetes mellitus and 39 birth defects. STUDY DESIGN This was a multicenter case-control study of mothers of infants who were born with (n = 13,030) and without (n = 4895) birth defects in the National Birth Defects Prevention Study (1997–2003). RESULTS Pregestational diabetes mellitus (PGDM) was associated significantly with noncardiac defects (isolated, 7/23 defects; multiples, 13/23 defects) and cardiac defects (isolated, 11/16 defects; multiples, 8/16 defects). Adjusted odds ratios for PGDM and all isolated and multiple defects were 3.17 (95% CI, 2.20–4.99) and 8.62 (95% CI, 5.27–14.10), respectively. Gestational diabetes mellitus (GDM) was associated with fewer noncardiac defects (isolated, 3/23 defects; multiples, 3/23 defects) and cardiac defects (isolated, 3/16 defects; multiples, 2/16 defects). Odds ratios between GDM and all isolated and multiple defects were 1.42 (95% CI, 1.17–1.73) and 1.50 (95% CI, 1.13–2.00), respectively. These associations were limited generally to offspring of women with prepregnancy body mass index ≥25 kg/m2. CONCLUSION PGDM was associated with a wide range of birth defects; GDM was associated with a limited group of birth defects. PMID:18674752

  5. Transversely bounded DFB lasers. [bounded distributed-feedback lasers

    NASA Technical Reports Server (NTRS)

    Elachi, C.; Evans, G.; Yeh, C.

    1975-01-01

    Bounded distributed-feedback (DFB) lasers are studied in detail. Threshold gain and field distribution for a number of configurations are derived and analyzed. More specifically, the thin-film guide, fiber, diffusion guide, and hollow channel with inhomogeneous-cladding DFB lasers are considered. Optimum points exist and must be used in DFB laser design. Different-modes feedback and the effects of the transverse boundaries are included. A number of applications are also discussed.

  6. Base pairing and base mis-pairing in nucleic acids

    NASA Technical Reports Server (NTRS)

    Wang, A. H. J.; Rich, A.

    1986-01-01

    In recent years we have learned that DNA is conformationally active. It can exist in a number of different stable conformations including both right-handed and left-handed forms. Using single crystal X-ray diffraction analysis we are able to discover not only additional conformations of the nucleic acids but also different types of hydrogen bonded base-base interactions. Although Watson-Crick base pairings are the predominant type of interaction in double helical DNA, they are not the only types. Recently, we have been able to examine mismatching of guanine-thymine base pairs in left-handed Z-DNA at atomic resolution (1A). A minimum amount of distortion of the sugar phosphate backbone is found in the G x T pairing in which the bases are held together by two hydrogen bonds in the wobble pairing interaction. Because of the high resolution of the analysis we can visualize water molecules which fill in to accommodate the other hydrogen bonding positions in the bases which are not used in the base-base interactions. Studies on other DNA oligomers have revealed that other types of non-Watson-Crick hydrogen bonding interactions can occur. In the structure of a DNA octamer with the sequence d(GCGTACGC) complexed to an antibiotic triostin A, it was found that the two central AT base pairs are held together by Hoogsteen rather than Watson-Crick base pairs. Similarly, the G x C base pairs at the ends are also Hoogsteen rather than Watson-Crick pairing. Hoogsteen base pairs make a modified helix which is distinct from the Watson-Crick double helix.

  7. Stereo Pair, Patagonia, Argentina

    NASA Technical Reports Server (NTRS)

    2000-01-01

    This view of northern Patagonia, at Los Menucos, Argentina shows remnants of relatively young volcanoes built upon an eroded plain of much older and contorted volcanic, granitic, and sedimentary rocks. The large purple, brown, and green 'butterfly' pattern is a single volcano that has been deeply eroded. Large holes on the volcano's flanks indicate that they may have collapsed soon after eruption, as fluid molten rock drained out from under its cooled and solidified outer shell. At the upper left, a more recent eruption occurred and produced a small volcanic cone and a long stream of lava, which flowed down a gully. At the top of the image, volcanic intrusions permeated the older rocks resulting in a chain of small dark volcanic peaks. At the top center of the image, two halves of a tan ellipse pattern are offset from each other. This feature is an old igneous intrusion that has been split by a right-lateral fault. The apparent offset is about 6.6 kilometers (4 miles). Color, tonal, and topographic discontinuities reveal the fault trace as it extends across the image to the lower left. However, young unbroken basalt flows show that the fault has not been active recently.

    This cross-eyed stereoscopic image pair was generated using topographic data from the Shuttle Radar Topography Mission, combined with an enhanced Landsat 7satellite color image. The topography data are used to create two differing perspectives of a single image, one perspective for each eye. In doing so, each point in the image is shifted slightly, depending on its elevation. When stereoscopically merged, the result is a vertically exaggerated view of the Earth's surface in its full three dimensions.

    Landsat satellites have provided visible light and infrared images of the Earth continuously since 1972. SRTM topographic data match the 30-meter (99-foot) spatial resolution of most Landsat images and provide a valuable complement for studying the historic and growing Landsat data archive

  8. Stereo Pair: Patagonia, Argentina

    NASA Technical Reports Server (NTRS)

    2000-01-01

    This view of northern Patagonia, near El Cain, Argentina shows complexly eroded volcanic terrain, with basalt mesas, sinkholes, landslide debris, playas, and relatively few integrated drainage channels. Surrounding this site (but also extending far to the east) is a broad plateau capped by basalt, the Meseta de Somuncura. Here, near the western edge of the plateau, erosion has broken through the basalt cap in a variety of ways. On the mesas, water-filled sinkholes (lower left) are most likely the result of the collapse of old lava tubes. Along the edges of the mesas (several locations) the basalt seems to be sliding away from the plateau in a series of slices. Water erosion by overland flow is also evident, particularly in canyons where vegetation blankets the drainage channels (green patterns, bottom of image). However, overland water flow does not extend very far at any location. This entire site drains to local playas, some of which are seen here (blue). While the water can reach the playas and then evaporate, what becomes of the eroded rock debris? Wind might excavate some of the finer eroded debris, but the fate of much of the missing bedrock remains mysterious.

    This cross-eyed stereoscopic image pair was generated using topographic data from the Shuttle Radar Topography Mission, combined with an enhanced Landsat 7 satellite color image. The topography data are used to create two differing perspectives of a single image, one perspective for each eye. In doing so, each point in the image is shifted slightly, depending on its elevation. When stereoscopically merged, the result is a vertically exaggerated view of the Earth's surface in its full three dimensions.

    Landsat satellites have provided visible light and infrared images of the Earth continuously since 1972. SRTM topographic data match the 30-meter (99-foot) spatial resolution of most Landsat images and provide a valuable complement for studying the historic and growing Landsat data archive. The

  9. Performance Bounds on Two Concatenated, Interleaved Codes

    NASA Technical Reports Server (NTRS)

    Moision, Bruce; Dolinar, Samuel

    2010-01-01

    A method has been developed of computing bounds on the performance of a code comprised of two linear binary codes generated by two encoders serially concatenated through an interleaver. Originally intended for use in evaluating the performances of some codes proposed for deep-space communication links, the method can also be used in evaluating the performances of short-block-length codes in other applications. The method applies, more specifically, to a communication system in which following processes take place: At the transmitter, the original binary information that one seeks to transmit is first processed by an encoder into an outer code (Co) characterized by, among other things, a pair of numbers (n,k), where n (n > k)is the total number of code bits associated with k information bits and n k bits are used for correcting or at least detecting errors. Next, the outer code is processed through either a block or a convolutional interleaver. In the block interleaver, the words of the outer code are processed in blocks of I words. In the convolutional interleaver, the interleaving operation is performed bit-wise in N rows with delays that are multiples of B bits. The output of the interleaver is processed through a second encoder to obtain an inner code (Ci) characterized by (ni,ki). The output of the inner code is transmitted over an additive-white-Gaussian- noise channel characterized by a symbol signal-to-noise ratio (SNR) Es/No and a bit SNR Eb/No. At the receiver, an inner decoder generates estimates of bits. Depending on whether a block or a convolutional interleaver is used at the transmitter, the sequence of estimated bits is processed through a block or a convolutional de-interleaver, respectively, to obtain estimates of code words. Then the estimates of the code words are processed through an outer decoder, which generates estimates of the original information along with flags indicating which estimates are presumed to be correct and which are found to

  10. Defects in Calcite.

    DTIC Science & Technology

    1991-05-13

    AD-A245 645 A TRIDENT SCHOLAR PROJECT REPORT NO. 181 "DEFECTS IN CALCITE " DTTC %N FEB 5-1912 UNITED STATES NAVAL ACADEMY ANNAPOLIS, MARYLAND 92-02841...report; no. 181 (1991) "DEFECTS IN CALCITE " A Trident Scholar Project Report by Midshipman Anthony J. Kotarski, Class of 1991 U. S. Naval Academy Annapolis...REPORT TYPE AND DATES COVERED 13 May 1991 Final 1990/91 . TITLE AND SUBTITLE s. FUNDING NUMBERS DEFECTS IN CALCITE 6. AUTHOR(S) Anthony J. Kotarski 7

  11. Magnetic pair creation transparency in gamma-ray pulsars

    SciTech Connect

    Story, Sarah A.; Baring, Matthew G. E-mail: baring@rice.edu

    2014-07-20

    Magnetic pair creation, γ → e {sup +} e {sup –}, has been at the core of radio pulsar paradigms and central to polar cap models of gamma-ray pulsars for over three decades. The Fermi gamma-ray pulsar population now exceeds 140 sources and has defined an important part of Fermi's science legacy, providing rich information for the interpretation of young energetic pulsars and old millisecond pulsars. Among the population characteristics well established is the common occurrence of exponential turnovers in their spectra in the 1-10 GeV range. These turnovers are too gradual to arise from magnetic pair creation in the strong magnetic fields of pulsar inner magnetospheres. By demanding insignificant photon attenuation precipitated by such single-photon pair creation, the energies of these turnovers for Fermi pulsars can be used to compute lower bounds for the typical altitude of GeV band emission. This paper explores such pair transparency constraints below the turnover energy and updates earlier altitude bound determinations that have been deployed in various Fermi pulsar papers. For low altitude emission locales, general relativistic influences are found to be important, increasing cumulative opacity, shortening the photon attenuation lengths, and also reducing the maximum energy that permits escape of photons from a neutron star magnetosphere. Rotational aberration influences are also explored, and are found to be small at low altitudes, except near the magnetic pole. The analysis presented in this paper clearly demonstrates that including near-threshold physics in the pair creation rate is essential to deriving accurate attenuation lengths and escape energies. The altitude bounds are typically in the range of 2-7 stellar radii for the young Fermi pulsar population, and provide key information on the emission altitude in radio quiet pulsars that do not possess double-peaked pulse profiles. The bound for the Crab pulsar is at a much higher altitude, with the

  12. First-Principles Study of Defects in GaN

    DTIC Science & Technology

    2009-07-29

    energies and other properties of the Gai – VGa and Ni – VN Frenkel pairs in GaN. o Results on the binding energies and stabilities of Frenkel pairs as...Frenkel pair are interstitial Ga ( Gai ) and Ga vacancy (VGa). Gallium interstitial can occur in 3+, 2+, and 1+ charge states, depending on the Fermi...distance to the six Ga nearest neighbors are roughly the same (to within 0.15 Å). The defect level of Gai is found to lie in the upper part of the

  13. Role of Topological Defects in the Phase Transition of the Three-Dimensional Heisenberg Model.

    NASA Astrophysics Data System (ADS)

    Lau, Manhot

    The role of topological point defects (hedgehogs) in the phase transition of the classical Heisenberg model in three dimensions is investigated by using Monte Carlo simulations. Simulations of the behavior of the defects near the phase transition show that the number density of defects increases sharply and defect pairs with separations comparable to the sample size begin to appear as the temperature is increased through the transition temperature. In simulations in a restricted ensemble in which spin configurations containing defects are not allowed, the system appears to remain ordered at all temperatures. Simulations in which the spin-spin interaction is set equal to zero and the number density of defects is controlled by varying a 'chemical potential' term indicate that the system is ordered if the number density of defect pairs is sufficiently small. These results show that topological defects play a crucial role in the three-dimensional Heisenberg transition in the sense that configurations containing defect pairs are necessary for the transition from the ferromagnetic to paramagnetic phase to occur. Such a conclusion is also consistent with a Renormalization Group study of the O(n) model, which suggests that topological defects should be explicitly taken into account for a correct description of the critical behavior in models including the three-dimensional Heisenberg model.

  14. TOPICAL REVIEW: W = 0 pairing in Hubbard and related models of low-dimensional superconductors

    NASA Astrophysics Data System (ADS)

    Balzarotti, Adalberto; Cini, Michele; Perfetto, Enrico; Stefanucci, Gianluca

    2004-12-01

    Lattice Hamiltonians with on-site interaction W have W = 0 solutions, that is, many-body singlet eigenstates without double occupation. In particular, W = 0 pairs give a clue to understand the pairing force in repulsive Hubbard models. These eigenstates are found in systems with high enough symmetry, like the square, hexagonal or triangular lattices. By a general theorem, we propose a systematic way to construct all the W = 0 pairs of a given Hamiltonian. We also introduce a canonical transformation to calculate the effective interaction between the particles of such pairs. In geometries appropriate for the CuO2 planes of cuprate superconductors, armchair carbon nanotubes, or cobalt oxide planes, the dressed pair becomes a bound state in a physically relevant range of parameters. We also show that W = 0 pairs quantize the magnetic flux as superconducting pairs do. The pairing mechanism breaks down in the presence of strong distortions. The W = 0 pairs are also the building blocks for the antiferromagnetic ground state of the half-filled Hubbard model at weak coupling. Our analytical results for the 4 × 4 Hubbard square lattice, compared to available numerical data, demonstrate that the method, besides providing an intuitive grasp on pairing, also has quantitative predictive power. We also consider including phonon effects in this scenario. Preliminary calculations with small clusters indicate that vector phonons hinder pairing while half-breathing modes are synergic with the W = 0 pairing mechanism both at weak coupling and in the polaronic regime.

  15. Congenital Heart Defects

    MedlinePlus

    ... Treatment can include medicines, catheter procedures, surgery, and heart transplants. The treatment depends on the type of the defect, how severe it is, and a child's age, size, and general health. NIH: National Heart, Lung, and Blood Institute

  16. Ventricular Septal Defect (VSD)

    MedlinePlus

    ... specially sized mesh device to close the hole. Hybrid procedure. A hybrid procedure uses surgical and catheter-based techniques. Access ... clinicalkey.com. Accessed Sept. 15, 2014. Konetti NR. Hybrid muscular ventricular defect closure: Surgeon or physician. Indian ...

  17. Birth defects monitoring

    SciTech Connect

    Klingberg, M.A.; Papier, C.M.; Hart, J.

    1983-01-01

    Population monitoring of birth defects provides a means for detecting relative changes in their frequency. Many varied systems have been developed throughout the world since the thalidomide tragedy of the early 1960s. Although it is difficult to pinpoint specific teratogenic agents based on rises in rates of a particular defect or a constellation of defects, monitoring systems can provide clues for hypothesis testing in epidemiological investigations. International coordination of efforts in this area resulted in the founding of the International Clearinghouse for Birth Defects Monitoring Systems (ICBDMS) in 1974. In this paper we will describe the functions and basic requirements of monitoring systems in general, and look at the development and activities of the ICBDMS. A review of known and suspected environmental teratogenic agents (eg, chemical, habitual, biological, physical, and nutritional) is also presented.

  18. Defect Physics of Structural Materials under Extreme Conditions

    NASA Astrophysics Data System (ADS)

    Stocks, G. Malcolm

    2010-03-01

    ``Crystals are like people: it is the defects in them that make them interesting.'' This oft quoted quip of Sir Charles Frank speaks to the heart of structural alloys. Indeed, the extent to which the collective effects of defects can be manipulated and controlled determines the combination of structural materials properties that underpins modern energy and transportation technologies. Furthermore, the bounds on performance of current structural materials generally result from limitations in our understanding of defects, rather than insurmountable physical principles. I will describe research in the Center for Defect PhysicsfootnotetextThe CDP is an Energy Frontier Research Center (EFRC), DOE Office of Basic Energy Sciences. in three thrust areas: *Fundamental Physics of Defect Formation and Evolution during Irradiation *Fundamental Physics of Defect Interactions during Deformation *Quantum Theory of Defects and Interactions Specifically, I will described ongoing and planned research that is based on the realization that we are on the verge of a new era of ``quantitative measurement'' and ``direct quantum simulation'' of defects and their interactions enabled by major national facilities (APS, SNS, and LCLS) and the PFlop/s computing (NCCS and NERSC).

  19. Secure Key from Bound Entanglement

    NASA Astrophysics Data System (ADS)

    Horodecki, Karol; Horodecki, Michał; Horodecki, Paweł; Oppenheim, Jonathan

    2005-04-01

    We characterize the set of shared quantum states which contain a cryptographically private key. This allows us to recast the theory of privacy as a paradigm closely related to that used in entanglement manipulation. It is shown that one can distill an arbitrarily secure key from bound entangled states. There are also states that have less distillable private keys than the entanglement cost of the state. In general, the amount of distillable key is bounded from above by the relative entropy of entanglement. Relationships between distillability and distinguishability are found for a class of states which have Bell states correlated to separable hiding states. We also describe a technique for finding states exhibiting irreversibility in entanglement distillation.

  20. Lower Bounds on Paraclique Density.

    PubMed

    Hagan, Ronald D; Langston, Michael A; Wang, Kai

    2016-05-11

    The scientific literature teems with clique-centric clustering strategies. In this paper we analyze one such method, the paraclique algorithm. Paraclique has found practical utility in a variety of application domains, and has been successfully employed to reduce the effects of noise. Nevertheless, its formal analysis and worst-case guarantees have remained elusive. We address this issue by deriving a series of lower bounds on paraclique densities.

  1. Discrete family of dissipative soliton pairs in mode-locked fiber lasers

    SciTech Connect

    Zavyalov, Aleksandr; Iliew, Rumen; Egorov, Oleg; Lederer, Falk

    2009-05-15

    We numerically investigate the formation of soliton pairs (bound states) in mode-locked fiber ring lasers. In the distributed model (complex cubic-quintic Ginzburg-Landau equation) we observe a discrete family of soliton pairs with equidistantly increasing peak separation. This family was identified by two alternative numerical schemes and the bound state instability was disclosed by a linear stability analysis. Moreover, similar families of unstable bound state solutions have been found in a more realistic lumped laser model with an idealized saturable absorber (instantaneous response). We show that a stabilization of these bound states can be achieved when the finite relaxation time of the saturable absorber is taken into account. The domain of stability can be controlled by varying this relaxation time.

  2. 78 FR 18326 - Agency Information Collection Activities; Comment Request; Upward Bound and Upward Bound Math...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-03-26

    ... Agency Information Collection Activities; Comment Request; Upward Bound and Upward Bound Math Science... Upward Bound Math Science Annual Performance Report. OMB Control Number: 1840-NEW. Type of Review: New... under the regular Upward Bound (UB) and Upward Bound Math and Science (UBMS) Programs. The Department...

  3. Information bounds for Gaussian copulas

    PubMed Central

    Hoff, Peter D.; Niu, Xiaoyue; Wellner, Jon A.

    2013-01-01

    Often of primary interest in the analysis of multivariate data are the copula parameters describing the dependence among the variables, rather than the univariate marginal distributions. Since the ranks of a multivariate dataset are invariant to changes in the univariate marginal distributions, rank-based estimators are natural candidates for semiparametric copula estimation. Asymptotic information bounds for such estimators can be obtained from an asymptotic analysis of the rank likelihood, i.e. the probability of the multivariate ranks. In this article, we obtain limiting normal distributions of the rank likelihood for Gaussian copula models. Our results cover models with structured correlation matrices, such as exchangeable or circular correlation models, as well as unstructured correlation matrices. For all Gaussian copula models, the limiting distribution of the rank likelihood ratio is shown to be equal to that of a parametric likelihood ratio for an appropriately chosen multivariate normal model. This implies that the semiparametric information bounds for rank-based estimators are the same as the information bounds for estimators based on the full data, and that the multivariate normal distributions are least favorable. PMID:25313292

  4. Pairing Correlations at High Spins

    NASA Astrophysics Data System (ADS)

    Ma, Hai-Liang; Dong, Bao-Guo; Zhang, Yan; Fan, Ping; Yuan, Da-Qing; Zhu, Shen-Yun; Zhang, Huan-Qiao; Petrache, C. M.; Ragnarsson, I.; Carlsson, B. G.

    The pairing correcting energies at high spins in 161Lu and 138Nd are studied by comparing the results of the cranked-Nilsson-Strutinsky (CNS) and cranked-Nilsson-Strutinsky-Bogoliubov (CNSB) models. It is concluded that the Coriolis effect rather than the rotational alignment effect plays a major role in the reduction of the pairing correlations in the high spin region. Then we proposed an average pairing correction method which not only better reproduces the experimental data comparing with the CNS model but also enables a clean-cut tracing of the configurations thus the full-spin-range discussion on the various rotating bands.

  5. DNA as membrane-bound ligand-receptor pairs: duplex stability is tuned by intermembrane forces.

    PubMed

    Beales, Paul A; Vanderlick, T Kyle

    2009-02-18

    We use membrane-anchored DNA as model adhesion receptors between lipid vesicles. By studying the thermal stability of DNA duplex formation, which tethers the vesicles into superstructures, we show that the melting temperature of a 10-base DNA sequence is dependent on the lipid composition of the tethered vesicles. We propose a simple model that describes how the intermembrane interactions tilt the free energy landscape for DNA binding. From our model, we estimate the area per DNA in the binding sites between vesicles and also the total area of the adhesion plaques. We find that vesicles containing a small proportion of cationic lipid that are modified with membrane-anchored DNA can be reversibly tethered by specific DNA interactions and that the DNA also induces a small attraction between these membranes, which stabilizes the DNA duplex. By increasing the equilibrium intermembrane distance on binding, we show that intermembrane interactions become negligible for the binding thermodynamics of the DNA and hence the thermal stability of vesicle aggregates becomes independent of lipid composition at large enough intervesicle separations. We discuss the implications of our findings with regards to cell adhesion and fusion receptors, and the programmable self-assembly of nano-structured materials by DNA hybridization.

  6. Exchange of carbon-bound hydrogen atoms ortho to the hydroxyl group in tyrosine.

    PubMed

    Martin, R B; Morlino, V J

    1965-10-22

    The carbon-bound hydrogen atoms of tyrosine that exchange with solvent protons in strongly acid solutions at about 100 degrees C are not the methylene hydrogen atoms but a pair on the aromatic ring. Of the two pairs of protons on the aromatic ring, observed in the proton magnetic resonance spectra, the pair at higher field undergoes exchange in 2.4N DCI at 100 degrees C. Other hydrogen atoms, attached either to aliphatic or aromatic carbon atoms, exhibit no noticeable exchange under the same conditions. From a chemicalshift analysis the exchanging protons are assigned as those ortho to the hydroxyl group on the aromatic ring.

  7. Negative U-centers and defect superconductivity

    NASA Astrophysics Data System (ADS)

    Dzhumanov, S.; Yavidov, B.; Makhmudov, N. A.

    1997-04-01

    A connection between the formation of defect bipolarons (i.e. U-centers or U-bipolarons) and superconductivity in high-Tcsuperconductors (HTSC) is considered in two pairing limits of carriers in realr- andk-spaces. The irrelevance ofr-space U-bipolarons to superconductivity is motivated. It is shown that the formation ofk-space U-bipolarons and their subsequent attractive single particle and pair condensation lead to depressed (in comparison with lattice bipolarons) superconductivity due to a large mass of such U-bipolarons. It is argued that the coexistence ofk-space lattice bipolarons andr-space U-bipolarons leads to the shift of the maximum of the concentration dependenceTc(n)to higher carrier concentrations, in accordance with the observations in HTSC.

  8. Lower bounds for randomized Exclusive Write PRAMs

    SciTech Connect

    MacKenzie, P.D.

    1995-05-02

    In this paper we study the question: How useful is randomization in speeding up Exclusive Write PRAM computations? Our results give further evidence that randomization is of limited use in these types of computations. First we examine a compaction problem on both the CREW and EREW PRAM models, and we present randomized lower bounds which match the best deterministic lower bounds known. (For the CREW PRAM model, the lower bound is asymptotically optimal.) These are the first non-trivial randomized lower bounds known for the compaction problem on these models. We show that our lower bounds also apply to the problem of approximate compaction. Next we examine the problem of computing boolean functions on the CREW PRAM model, and we present a randomized lower bound, which improves on the previous best randomized lower bound for many boolean functions, including the OR function. (The previous lower bounds for these functions were asymptotically optimal, but we improve the constant multiplicative factor.) We also give an alternate proof for the randomized lower bound on PARITY, which was already optimal to within a constant additive factor. Lastly, we give a randomized lower bound for integer merging on an EREW PRAM which matches the best deterministic lower bound known. In all our proofs, we use the Random Adversary method, which has previously only been used for proving lower bounds on models with Concurrent Write capabilities. Thus this paper also serves to illustrate the power and generality of this method for proving parallel randomized lower bounds.

  9. Birth Defects. Matrix No. 2.

    ERIC Educational Resources Information Center

    Brent, Robert L.

    This report discusses the magnitude of the problem of birth defects, outlines advances in the birth defects field in the past decade, and identifies those areas where research is needed for the prevention, treatment, and management of birth defects. The problem of birth defects has consumed a greater portion of our health care resources because of…

  10. Relativistic description of pair production of doubly heavy baryons in e{sup +}e{sup −} annihilation

    SciTech Connect

    Martynenko, A. P.; Trunin, A. M.

    2015-05-15

    Relativistic corrections in the pair production of S-wave doubly heavy diquarks in electron-positron annihilation were calculated on the basis of perturbative QCD and the quark model. The relativistic corrections to the wave functions for quark bound states were taken into account with the aid of the Breit potential in QCD. Relativistic effects change substantially the nonrelativistic cross sections for pair diquark production. The yield of pairs of (ccq) doubly heavy baryons at B factories was estimated.

  11. Structural birth defects associated with neural tube defects in Hawai'i from 1986 until 2001.

    PubMed

    Forrester, Mathias B; Merz, Ruth D

    2007-09-01

    Using birth defects registry data, this study identified birth defects associated with anencephaly, spina bifida, and encephalocele. Musculoskeletal defects were associated with anencephaly; central nervous system defects, gastrointestinal atresia/stenosis, genitourinary system defects, and musculoskeletal system defects with spina bifida; and central nervous system defects, respiratory defects, oral clefts, genitourinary system defects, and musculoskeletal system defects with encephalocele.

  12. Numerical investigation of the role of topological defects in the three-dimensional Heisenberg transition

    NASA Astrophysics Data System (ADS)

    Lau, Man-Hot; Dasgupta, Chandan

    1989-04-01

    The role of topological point defects (hedgehogs) in the phase transition of the classical Heisenberg model in three dimensions is investigated by using Monte Carlo simulations. Simulations of the behavior of the defects near the phase transition show that the number density of defects increases sharply and defect pairs with separations comparable to the sample size begin to appear as the temperature is increased through the transition temperature. In simulations in a restricted ensemble in which spin configurations containing defects are not allowed, the system appears to remain ordered at all temperatures. Simulations in which the spin-spin interaction is set equal to zero and the number density of defects is controlled by varying a ``chemical potential'' term indicate that the system is ordered if the number density of defect pairs is sufficiently small. These results show that topological defects play a crucial role in the three-dimensional Heisenberg transition in the sense that configurations containing defect pairs are necessary for the transition from the ferromagnetic to the paramagnetic phase to occur.

  13. Self-confined particle pairs in complex plasmas

    NASA Astrophysics Data System (ADS)

    Lisina, I. I.; Lisin, E. A.; Vaulina, O. S.; Petrov, O. F.

    2017-01-01

    The liquid-crystal type of phase transition in complex plasmas has been observed repeatedly. However, more studies need to be done on the liquid-vapor transition in complex plasmas. In this paper, the phenomenon of coupling (condensation) of particles into self-confined particle pairs in an anisotropic plasma medium with ion flow is considered analytically and numerically using the Langevin molecular dynamics method. We obtain the stability conditions of the pair (bound) state depending on the interaction parameters and particle kinetic energy. It was shown that the breakup of the particle pair is very sensitive to the ratio of particle charges; for example, it is determined by the influence of the upper particle on the ion flow around the lower one. We also show that a self-confined pair of particles exists even if their total kinetic energy is much greater than the potential well depth for the pair state. This phenomenon occurs due to velocity correlation of particles, which arises with the nonreciprocity of interparticle interaction.

  14. Self-confined particle pairs in complex plasmas.

    PubMed

    Lisina, I I; Lisin, E A; Vaulina, O S; Petrov, O F

    2017-01-01

    The liquid-crystal type of phase transition in complex plasmas has been observed repeatedly. However, more studies need to be done on the liquid-vapor transition in complex plasmas. In this paper, the phenomenon of coupling (condensation) of particles into self-confined particle pairs in an anisotropic plasma medium with ion flow is considered analytically and numerically using the Langevin molecular dynamics method. We obtain the stability conditions of the pair (bound) state depending on the interaction parameters and particle kinetic energy. It was shown that the breakup of the particle pair is very sensitive to the ratio of particle charges; for example, it is determined by the influence of the upper particle on the ion flow around the lower one. We also show that a self-confined pair of particles exists even if their total kinetic energy is much greater than the potential well depth for the pair state. This phenomenon occurs due to velocity correlation of particles, which arises with the nonreciprocity of interparticle interaction.

  15. Defect behavior of polycrystalline solar cell silicon

    SciTech Connect

    Schroder, D.K.; Park, S.H.; Hwang, I.G.; Mohr, J.B.; Hanly, M.P.

    1993-05-01

    The major objective of this study, conducted from October 1988 to September 1991, was to gain an understanding of the behavior of impurities in polycrystalline silicon and the influence of these impurities on solar cell efficiency. The authors studied edge-defined film-fed growth (EFG) and cast poly-Si materials and solar cells. With EFG Si they concentrated on chromium-doped materials and cells to determine the role of Cr on solar cell performance. Cast poly-Si samples were not deliberately contaminated. Samples were characterized by cell efficiency, current-voltage, deep-level transient spectroscopy (DLTS), surface photovoltage (SPV), open-circuit voltage decay, secondary ion mass spectrometry, and Fourier transform infrared spectroscopy measurements. They find that Cr forms Cr-B pairs with boron at room temperature and these pairs dissociate into Cr{sub i}{sup +} and B{sup {minus}} during anneals at 210{degrees}C for 10 min. Following the anneal, Cr-B pairs reform at room temperature with a time constant of 230 h. Chromium forms CrSi{sub 2} precipitates in heavily contaminated regions and they find evidence of CrSi{sub 2} gettering, but a lack of chromium segregation or precipitation to grain boundaries and dislocations. Cr-B pairs have well defined DLTS peaks. However, DLTS spectra of other defects are not well defined, giving broad peaks indicative of defects with a range of energy levels in the band gap. In some high-stress, low-efficiency cast poly-Si they detect SiC precipitates, but not in low-stress, high-efficiency samples. SPV measurements result in nonlinear SPV curves in some materials that are likely due to varying optical absorption coefficients due to locally varying stress in the material.

  16. Resonances from QCD bound states and the 750 GeV diphoton excess

    NASA Astrophysics Data System (ADS)

    Kats, Yevgeny; Strassler, Matthew J.

    2016-05-01

    Pair production of colored particles is in general accompanied by production of QCD bound states (onia) slightly below the pair-production threshold. Bound state annihilation leads to resonant signals, which in some cases are easier to see than the decays of the pair-produced constituents. In a previous paper ( arXiv:1204.1119 ) we estimated the bound state signals, at leading order and in the Coulomb approximation, for particles with various spins, color representations and electric charges, and used 7 TeV ATLAS and CMS resonance searches to set rough limits. Here we update our results to include 8 and 13 TeV data. We find that the recently reported diphoton excesses near 750 GeV could indeed be due to a bound state of this kind. A narrow resonance of the correct size could be obtained for a color-triplet scalar with electric charge -4/3 and mass near 375GeV, if (as a recent lattice computation suggests) the wave function at the origin is somewhat larger than anticipated. Pair production of this particle could have evaded detection up to now. Other candidates may include a triplet scalar of charge 5/3, a triplet fermion of charge -4/3, and perhaps a sextet scalar of charge -2/3.

  17. Bound Anionic States of Aadenine

    SciTech Connect

    Haranczyk, Maciej; Gutowski, Maciej S.; Li, Xiang; Bowen, Kit H.

    2007-03-20

    The research described in this product was performed in part in the Environmental Molecular Sciences Laboratory, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory. Anionic states of nucleic acid bases are involved in DNA damage by low-energy electrons and in charge transfer through DNA. Previous gas phase studies of free, unsolvated nucleic acid base parent anions probed only dipole-bound states, which are not present in condensed phase environments, but did not observe valence anionic states, which for purine bases are thought to be adiabatically unbound. Contrary to this expectation,wehave demonstrated that some thus far ignored tautomers of adenine, which result from enamine-imine transformations, support valence anionic states with electron vertical detachment energies as large as 2.2 eV, and at least one of these anionic tautomers is adiabatically bound. Moreover, we predict that the new anionic tautomers should also dominate in solutions and should be characterized by larger values of electron vertical detachment energy than the canonical valence anion. All of the newfound anionic tautomers might be formed in the course of dissociative electron attachment followed by a hydrogen atom attachment to a carbon atom, and they might affect the structure and properties of DNA and RNA exposed to low-energy electrons. The new valence states observed here, unlike the dipole-bound state, could exist in condensed phases and might be relevant to radiobiological damage. The discovery of these valence anionic states of adenine was facilitated by the development of (i) an experimental method for preparing parent anions of nucleic acid bases for photoelectron experiments, and (ii) a combinatorial/quantum chemical approach for identification of the most stable tautomers of organic molecules.

  18. Bound Anionic States of Adenine

    SciTech Connect

    Haranczyk, Maciej; Gutowski, Maciej S.; Li, Xiang; Bowen, Kit H.

    2007-03-20

    The research described in this product was performed in part in the Environmental Molecular Sciences Laboratory, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory. Anionic states of nucleic acid bases are involved in DNA damage by low-energy electrons and in charge transfer through DNA. Previous gas phase studies of free, unsolvated nucleic acid base parent anions probed only dipole-bound states, which are not present in condensed phase environments, but did not observe valence anionic states, which for purine bases are thought to be adiabatically unbound. Contrary to this expectation, we have demonstrated that some thus far ignored tautomers of adenine, which result from enamine-imine transformations, support valence anionic states with electron vertical detachment energies as large as 2.2 eV, and at least one of these anionic tautomers is adiabatically bound. Moreover, we predict that the new anionic tautomers should also dominate in solutions and should be characterized by larger values of electron vertical detachment energy than the canonical valence anion. All of the newfound anionic tautomers might be formed in the course of dissociative electron attachment followed by a hydrogen atom attachment to a carbon atom, and they might affect the structure and properties of DNA and RNA exposed to low-energy electrons. The new valence states observed here, unlike the dipole-bound state, could exist in condensed phases and might be relevant to radiobiological damage. The discovery of these valence anionic states of adenine was facilitated by the development of (i) an experimental method for preparing parent anions of nucleic acid bases for photoelectron experiments, and (it) a combinatorial/quantum chemical approach for identification of the most stable tautomers of organic molecules.

  19. Wire insulation defect detector

    NASA Technical Reports Server (NTRS)

    Greulich, Owen R. (Inventor)

    2004-01-01

    Wiring defects are located by detecting a reflected signal that is developed when an arc occurs through the defect to a nearby ground. The time between the generation of the signal and the return of the reflected signal provides an indication of the distance of the arc (and therefore the defect) from the signal source. To ensure arcing, a signal is repeated at gradually increasing voltages while the wire being tested and a nearby ground are immersed in a conductive medium. In order to ensure that the arcing occurs at an identifiable time, the signal whose reflection is to be detected is always made to reach the highest potential yet seen by the system.

  20. Reconstruction of Mandibular Defects

    PubMed Central

    Chim, Harvey; Salgado, Christopher J.; Mardini, Samir; Chen, Hung-Chi

    2010-01-01

    Defects requiring reconstruction in the mandible are commonly encountered and may result from resection of benign or malignant lesions, trauma, or osteoradionecrosis. Mandibular defects can be classified according to location and extent, as well as involvement of mucosa, skin, and tongue. Vascularized bone flaps, in general, provide the best functional and aesthetic outcome, with the fibula flap remaining the gold standard for mandible reconstruction. In this review, we discuss classification and approach to reconstruction of mandibular defects. We also elaborate upon four commonly used free osteocutaneous flaps, inclusive of fibula, iliac crest, scapula, and radial forearm. Finally, we discuss indications and use of osseointegrated implants as well as recent advances in mandibular reconstruction. PMID:22550439

  1. Bounds on multipartite concurrence and tangle

    NASA Astrophysics Data System (ADS)

    Wang, Jing; Li, Ming; Li, Hongfang; Fei, Shao-Ming; Li-Jost, Xianqing

    2016-10-01

    We present an analytical lower bound of multipartite concurrence based on the generalized Bloch representations of density matrices. It is shown that the lower bound can be used as an effective entanglement witness of genuine multipartite entanglement. Tight lower and upper bounds for multipartite tangles are also derived. Since the lower bounds depend on just part of the correlation tensors, the result is experimentally feasible.

  2. Finite Element Output Bounds for Hyperbolic Problems

    SciTech Connect

    Machiels, L.

    2000-03-27

    We propose a Neumann-subproblem a posteriori finite element error bound technique for linear stationary scalar advection problems. The method is similar in many respects to the previous output bound technique developed for elliptic problems. In the new approach, however, the primal residual is enhanced with a streamline diffusion term. We first formulate the bound algorithm, with particular emphasis on the proof of the bounding properties; then, we provide numerical results for an illustrative example.

  3. Molecular Dynamics Simulation of Defect Production in Collision Cascades in Zircon

    SciTech Connect

    Devanathan, Ram; Corrales, Louis R.; Weber, William J.; Chartier, Alain; Meis, Constantin

    2005-01-01

    Defect production in collision cascades in zircon has been examined by molecular dynamics simulations using a partial charge model combined with the Ziegler-Biersack-Littmark potential. U, Zr, Si and O recoils with energies ranging from 250 eV to 5 keV were simulated in the NVE ensemble. To obtain good statistics, 5-10 cascades in randomly chosen directions were simulated for each ion and energy. The damage consists of mainly Si and O Frenkel pairs, a smaller number of Zr Frenkel pairs, and Zr on Si antisite defects. Defect production, interstitial clustering, ion beam mixing and Si-O-Si polymerization increase with PKA mass and energy.

  4. Polaron pair mediated triplet generation in polymer/fullerene blends

    PubMed Central

    Dimitrov, Stoichko D.; Wheeler, Scot; Niedzialek, Dorota; Schroeder, Bob C.; Utzat, Hendrik; Frost, Jarvist M.; Yao, Jizhong; Gillett, Alexander; Tuladhar, Pabitra S.; McCulloch, Iain; Nelson, Jenny; Durrant, James R.

    2015-01-01

    Electron spin is a key consideration for the function of organic semiconductors in light-emitting diodes and solar cells, as well as spintronic applications relying on organic magnetoresistance. A mechanism for triplet excited state generation in such systems is by recombination of electron-hole pairs. However, the exact charge recombination mechanism, whether geminate or nongeminate and whether it involves spin-state mixing is not well understood. In this work, the dynamics of free charge separation competing with recombination to polymer triplet states is studied in two closely related polymer-fullerene blends with differing polymer fluorination and photovoltaic performance. Using time-resolved laser spectroscopic techniques and quantum chemical calculations, we show that lower charge separation in the fluorinated system is associated with the formation of bound electron-hole pairs, which undergo spin-state mixing on the nanosecond timescale and subsequent geminate recombination to triplet excitons. We find that these bound electron-hole pairs can be dissociated by electric fields. PMID:25735188

  5. The Acquisition of Bound and Free Anaphora.

    ERIC Educational Resources Information Center

    Koster, Jan; Koster, Charlotte

    Most linguists assume that bound anaphors such as "himself" are connected with their antecedents in a different way from free anaphors such as "him." Bound anaphora resolution is deterministic, based on Principle A of Chomsky's binding theory. Free anaphors, pronominals, cannot be bound in the domain of reflexives (principle…

  6. Some Educational Implications & Contributions of Outward Bound.

    ERIC Educational Resources Information Center

    Australian Outward Bound School, Sydney.

    The development of Outward Bound, from the early beginnings in Britain through expansion in over 30 locations throughout the world, is outlined, and Outward Bound educational aspects are analyzed in terms of the Australian Outward Bound School. The concepts of experiential education, lifelong education, and the broader Australian educational scene…

  7. Consistent Tolerance Bounds for Statistical Distributions

    NASA Technical Reports Server (NTRS)

    Mezzacappa, M. A.

    1983-01-01

    Assumption that sample comes from population with particular distribution is made with confidence C if data lie between certain bounds. These "confidence bounds" depend on C and assumption about distribution of sampling errors around regression line. Graphical test criteria using tolerance bounds are applied in industry where statistical analysis influences product development and use. Applied to evaluate equipment life.

  8. Unitary photoassociation: One-step production of ground-state bound molecules

    SciTech Connect

    Kallush, S.; Kosloff, R.

    2008-02-15

    Bound-state molecules can be photoassociated directly from ultracold free-atom pairs by excitation to a purely repulsive electronic state. The process is explained on the basis of quantum unitarity: the initially free-scattering state is transformed by an impulsive light pulse to a deformed superposition which contains bound-state components. For pulse durations which are short compared to the ultracold dynamics, the maximal rate of photoassociation was found to be determined by the initial stationary distribution of scattering states of the atom pairs. The process was simulated for an ultracold gas of {sup 87}Rb with a temperature of T=44 {mu}K and a density of {approx_equal}10{sup 11} cm{sup -3}. Transform-limited pulses maximize the photoassociation, yielding {approx}1 bound molecule per pulse. Coherent control calculated by a local control scheme can increase the photoassociation yield by two orders of magnitude.

  9. Supersymmetric k-defects

    NASA Astrophysics Data System (ADS)

    Koehn, Michael; Trodden, Mark

    2016-04-01

    In supersymmetric theories, topological defects can have nontrivial behaviors determined purely by whether or not supersymmetry is restored in the defect core. A well-known example of this is that some supersymmetric cosmic strings are automatically superconducting, leading to important cosmological effects and constraints. We investigate the impact of nontrivial kinetic interactions, present in a number of particle physics models of interest in cosmology, on the relationship between supersymmetry and supercurrents on strings. We find that in some cases it is possible for superconductivity to be disrupted by the extra interactions.

  10. Quantum correlations beyond Tsirelson's bound

    NASA Astrophysics Data System (ADS)

    Berry, Dominic; Ringbauer, Martin; Fedrizzi, Alessandro; White, Andrew

    2014-03-01

    Violations of Bell inequalities show that there are correlations that cannot explained by any classical theory. Further violation, beyond Tsirelson's bound, shows that there are correlations that are not explained by quantum mechanics. Such super-quantum correlations would enable violation of information causality, where communication of one bit provides more than one bit of information [Nature 461, 1101 (2009)]. An unavoidable feature of all realistic Bell inequality experiments is loss. If one postselects on successful measurements, unentangled states can violate Bell inequalities. On the other hand, loss can be used to enhance the violation of Bell inequalities for entangled states. This can improve the ability to distinguish between entangled and unentangled states, despite loss. Here we report an optical experiment providing maximal violation of the CHSH-Bell inequality with entangled states. Due to loss and postselection, Tsirelson's bound is also violated. This enables us to more easily distinguish between entangled and unentangled states. In addition, it provides violation of information causality for the postselected data.

  11. Endurance bounds of aerial systems

    NASA Astrophysics Data System (ADS)

    Harrington, Aaron M.; Kroninger, Christopher M.

    2014-06-01

    Within the past few years micro aerial vehicles (MAVs) have received much more attention and are starting to proliferate into military as well as civilian roles. However, one of the major drawbacks for this technology currently, has been their poor endurance, usually below 10 minutes. This is a direct result of the inefficiencies inherent in their design. Often times, designers do not consider the various components in the vehicle design and match their performance to the desired mission for the vehicle. These vehicles lack a prescribed set of design guidelines or empirically derived design equations which often limits their design to selection of commercial off-the-shelf components without proper consideration of their affect on vehicle performance. In the current study, the design space for different vehicle configurations has been examined including insect flapping, avian flapping, rotary wing, and fixed wing, and their performance bounds are established. The propulsion system typical of a rotary wing vehicle is analyzed to establish current baselines for efficiency of vehicles at this scale. The power draw from communications is analyzed to determine its impact on vehicle performance. Finally, a representative fixed wing MAV is examined and the effects of adaptive structures as a means for increasing vehicle endurance and range are examined. This paper seeks to establish the performance bounds for micro air vehicles and establish a path forward for future designs so that efficiency may be maximized.

  12. Pair extended coupled cluster doubles

    SciTech Connect

    Henderson, Thomas M.; Scuseria, Gustavo E.; Bulik, Ireneusz W.

    2015-06-07

    The accurate and efficient description of strongly correlated systems remains an important challenge for computational methods. Doubly occupied configuration interaction (DOCI), in which all electrons are paired and no correlations which break these pairs are permitted, can in many cases provide an accurate account of strong correlations, albeit at combinatorial computational cost. Recently, there has been significant interest in a method we refer to as pair coupled cluster doubles (pCCD), a variant of coupled cluster doubles in which the electrons are paired. This is simply because pCCD provides energies nearly identical to those of DOCI, but at mean-field computational cost (disregarding the cost of the two-electron integral transformation). Here, we introduce the more complete pair extended coupled cluster doubles (pECCD) approach which, like pCCD, has mean-field cost and reproduces DOCI energetically. We show that unlike pCCD, pECCD also reproduces the DOCI wave function with high accuracy. Moreover, pECCD yields sensible albeit inexact results even for attractive interactions where pCCD breaks down.

  13. Calculations of the free energy of dislocation defects in lamellae forming diblock copolymers using thermodynamic integration

    NASA Astrophysics Data System (ADS)

    Peters, Andrew J.; Lawson, Richard A.; Nation, Benjamin D.; Ludovice, Peter J.; Henderson, Clifford L.

    2016-04-01

    State-of-the-art directed self-assembly (DSA) of block copolymer (BCP) methods still yield defect densities orders of magnitude higher than is necessary in semiconductor fabrication. The defect free energy of a dislocation pair or jog defect, one of the most common defects found in BCP-DSA, is calculated via thermodynamic integration using a coarse-grained molecular dynamics model as a function of χ and the degree of polymerization (N). It is found that χN is not the best predictor of defect free energy and that a single χN value can yield vastly different free energies when χ and N are different. Defect free energy was highly dependent on defect location relative to the underlayer, and free energy differences ˜100 kT were found among the three possible defect locations on a 1:3 guiding pattern. It was found that increasing molar mass dispersity (Ð) significantly reduced defect free energy. Extrapolating from Ð up to 1.5 suggests that the defect will occur in equal proportions to the defect free state at a Ð of around 1.6 for this system. It was found that long chains tended to concentrate near the defect and stabilize the defect.

  14. Defect-Stabilized Phases in Extensile Active Nematics

    NASA Astrophysics Data System (ADS)

    Redner, Gabriel; Decamp, Stephen; Dogic, Zvonimir; Hagan, Michael

    2015-03-01

    Active nematics are liquid crystals which are driven out of equilibrium by energy-dissipating active stresses. The equilibrium nematic state is unstable in these materials, leading to beautiful and surprising behaviors including the spontaneous generation of topological defect pairs which stream through the system and later annihilate, yielding a complex, seemingly chaotic dynamical steady-state. In this talk, I will describe the emergence of order from this chaos in the form of previously unknown broken-symmetry phases in which the topological defects themselves undergo orientational ordering. We have identified these defect-ordered phases in two realizations of an active nematic: first, a suspension of extensile bundles of microtubules and molecular motor proteins, and second, a computational model of extending hard rods. I will describe the defect-stabilized phases that manifest in these systems, our current understanding of their origins, and discuss whether such phases may be a general feature of extensile active nematics.

  15. First-Principles Study of Defects in GaN, AlN and Their Alloys

    DTIC Science & Technology

    2010-08-31

    studied the similar type of pairs in GaN, i.e. Gai -VGa. These types of defect complexes are called Frenkel pairs which are believed to form when the...defects have been carried out.[17-21] In our previous program, we studied the GaGa i V− pairs in GaN. We found that Gai can occur in 3+, 2+, and 1...charge states, depending on the Fermi energy of the sample. VGa can occur in 3−, 2−, 1−, and neutral charge states. Because Gai and VGa have

  16. Reconstruction of complex abdominal wall defects.

    PubMed

    Leppäniemi, A; Tukiainen, E

    2013-01-01

    Complex abdominal wall defects refer to situations where simple ventral hernia repair is not feasible because the defect is very large, there is a concomitant infection or failed previous re-pair attempt, or if there is not enough original skin to cover the repair. Usually a complex abdominal wall repair is preceded by a period of temporary abdominal closure where the short-term aims include closure of the catabolic drain, protection of the viscera and preventing fistula formation, preventing bowel adherence to the abdominal wall, and enabling future fascial and skin closure. Currently the best way to achieve these goals is the vacuum- and mesh-mediated fascial traction method achieving close to 90% fascial closure rates. The long-term aims of an abdominal closure following a planned hernia strategy include intact skin cover, fascial closure at midline (if possible), good functional outcome with innervated abdominal musculature, no pain and good cosmetic result. The main methods of abdominal wall reconstruction include the use of prosthetic (mesh) or autologous material (tissue flaps). In patients with original skin cover over the fascial defect (simple ventral hernia), the most commonly used method is hernia repair with an artificial mesh. For more complex defects, our first choice of reconstruction is the component separation technique, sometimes combined with a mesh. In contaminated fields where component separation alone is not feasible, a combination with a biological mesh can be used. In large defects with grafted skin, a free TFL flap is the best option, sometimes reinforced with a mesh and enhanced with components separation.

  17. Pair-Starved Pulsar Magnetospheres

    NASA Technical Reports Server (NTRS)

    Muslimov, Alex G.; Harding, Alice K.

    2009-01-01

    We propose a simple analytic model for the innermost (within the light cylinder of canonical radius, approx. c/Omega) structure of open-magnetic-field lines of a rotating neutron star (NS) with relativistic outflow of charged particles (electrons/positrons) and arbitrary angle between the NS spin and magnetic axes. We present the self-consistent solution of Maxwell's equations for the magnetic field and electric current in the pair-starved regime where the density of electron-positron plasma generated above the pulsar polar cap is not sufficient to completely screen the accelerating electric field and thus establish thee E . B = 0 condition above the pair-formation front up to the very high altitudes within the light cylinder. The proposed mode1 may provide a theoretical framework for developing the refined model of the global pair-starved pulsar magnetosphere.

  18. Enhancing EUV mask blanks usability through smart shift and blank-design pairing optimization

    NASA Astrophysics Data System (ADS)

    Soni, Rakesh Kumar; Paninjath, Sankaranarayanan; Pereira, Mark; Buck, Peter; Thwaite, Peter

    2016-10-01

    EUV Defect avoidance techniques will play a vital role in extreme ultraviolet lithography (EUVL) photomask fabrication with the anticipation that defect free mask blanks won't be available and that cost effective techniques will not be available for defect repairing. In addition, mask shops may not have a large inventory of expensive EUV mask blanks. Given these facts, defect avoidance can be used as cost effective technique to optimize the mask blank and design data (mask data) pair selection across mask blank manufacturers and mask shops so that overall mask blank utilization can be enhanced. In previous work, it was determined that the pattern shift based solution increases the chance that a defective mask blank can be used that would otherwise be discarded [1]. In pattern shift, design data is shifted such that defects are either moved to isolated regions or hidden under the patterns that are written. However pattern shifts techniques don't perform well with masks with higher defect counts. Pattern shift techniques in this form assume all defects to be equally critical. In addition, a defect is critical or important only if it lands on the main pattern. A defect landing on fill, sub-resolution assist feature (SRAF) or fiducial areas may not be critical. In this paper we assess the performance of pattern shift techniques assuming defects that are not critical based upon size or type, as well as defects landing in non-critical areas (smart shift) can be ignored. In a production mask manufacturing environment it is necessary to co-optimize and prioritize blank-design pairing for multiple mask layouts in the queue with the available blanks. A blank-design pairing tool maximizes the utilization of blanks by finding the best pairing between blanks and design data so that the maximum number of mask blanks can be used. In this paper we also propose a novel process which would optimize the usage of costly EUV mask blanks across mask blank manufacturers and mask shops

  19. Creating multiphoton-polarization bound entangled states

    SciTech Connect

    Wei, Tzu-Chieh; Lavoie, Jonathan; Kaltenbaek, Rainer

    2011-03-15

    Bound entangled states are the exotic objects in the entangled world. They require entanglement to create them, but once they are formed, it is not possible to locally distill any free entanglement from them. It is only until recently that a few bound entangled states were realized in the laboratory. Motivated by these experiments, we propose schemes for creating various classes of bound entangled states with photon polarization. These include Acin-Bruss-Lewenstein-Sanpara states, Duer's states, Lee-Lee-Kim bound entangled states, and an unextendible-product-basis bound entangled state.

  20. Quantum computing with defects.

    PubMed

    Weber, J R; Koehl, W F; Varley, J B; Janotti, A; Buckley, B B; Van de Walle, C G; Awschalom, D D

    2010-05-11

    Identifying and designing physical systems for use as qubits, the basic units of quantum information, are critical steps in the development of a quantum computer. Among the possibilities in the solid state, a defect in diamond known as the nitrogen-vacancy (NV(-1)) center stands out for its robustness--its quantum state can be initialized, manipulated, and measured with high fidelity at room temperature. Here we describe how to systematically identify other deep center defects with similar quantum-mechanical properties. We present a list of physical criteria that these centers and their hosts should meet and explain how these requirements can be used in conjunction with electronic structure theory to intelligently sort through candidate defect systems. To illustrate these points in detail, we compare electronic structure calculations of the NV(-1) center in diamond with those of several deep centers in 4H silicon carbide (SiC). We then discuss the proposed criteria for similar defects in other tetrahedrally coordinated semiconductors.

  1. Defects in flexoelectric solids

    NASA Astrophysics Data System (ADS)

    Mao, Sheng; Purohit, Prashant K.

    2015-11-01

    A solid is said to be flexoelectric when it polarizes in proportion to strain gradients. Since strain gradients are large near defects, we expect the flexoelectric effect to be prominent there and decay away at distances much larger than a flexoelectric length scale. Here, we quantify this expectation by computing displacement, stress and polarization fields near defects in flexoelectric solids. For point defects we recover some well known results from strain gradient elasticity and non-local piezoelectric theories, but with different length scales in the final expressions. For edge dislocations we show that the electric potential is a maximum in the vicinity of the dislocation core. We also estimate the polarized line charge density of an edge dislocation in an isotropic flexoelectric solid which is in agreement with some measurements in ice. We perform an asymptotic analysis of the crack tip fields in flexoelectric solids and show that our results share some features from solutions in strain gradient elasticity and piezoelectricity. We also compute the energy release rate for cracks using simple crack face boundary conditions and use them in classical criteria for crack growth to make predictions. Our analysis can serve as a starting point for more sophisticated analytic and computational treatments of defects in flexoelectric solids which are gaining increasing prominence in the field of nanoscience and nanotechnology.

  2. Invisibly Sanitizable Signature without Pairings

    NASA Astrophysics Data System (ADS)

    Yum, Dae Hyun; Lee, Pil Joong

    Sanitizable signatures allow sanitizers to delete some pre-determined parts of a signed document without invalidating the signature. While ordinary sanitizable signatures allow verifiers to know how many subdocuments have been sanitized, invisibly sanitizable signatures do not leave any clue to the sanitized subdocuments; verifiers do not know whether or not sanitizing has been performed. Previous invisibly sanitizable signature scheme was constructed based on aggregate signature with pairings. In this article, we present the first invisibly sanitizable signature without using pairings. Our proposed scheme is secure under the RSA assumption.

  3. Annealing bounds to prevent further Charge Transfer Inefficiency increase of the Chandra X-ray CCDs

    NASA Astrophysics Data System (ADS)

    Monmeyran, Corentin; Patel, Neil S.; Bautz, Mark W.; Grant, Catherine E.; Prigozhin, Gregory Y.; Agarwal, Anuradha; Kimerling, Lionel C.

    2016-12-01

    After the front-illuminated CCDs on board the X-ray telescope Chandra were damaged by radiation after launch, it was decided to anneal them in an effort to remove the defects introduced by the irradiation. The annealing led to an unexpected increase of the Charge Transfer Inefficiency (CTI). The performance degradation is attributed to point defect interactions in the devices. Specifically, the annealing at 30 °C activated the diffusion of the main interstitial defect in the device, the carbon interstitial, which led to its association with a substitutional impurity, ultimately resulting in a stable and electrically active defect state. Because the formation reaction of this carbon interstitial and substitutional impurity associate is diffusion limited, we recommend a higher upper bound for the annealing temperature and duration of any future CCD anneals, that of -50 °C for one day or -60 °C for a week, to prevent further CTI increase.

  4. Bound states in the continuum

    NASA Astrophysics Data System (ADS)

    Hsu, Chia Wei; Zhen, Bo; Stone, A. Douglas; Joannopoulos, John D.; Soljačić, Marin

    2016-09-01

    Bound states in the continuum (BICs) are waves that remain localized even though they coexist with a continuous spectrum of radiating waves that can carry energy away. Their very existence defies conventional wisdom. Although BICs were first proposed in quantum mechanics, they are a general wave phenomenon and have since been identified in electromagnetic waves, acoustic waves in air, water waves and elastic waves in solids. These states have been studied in a wide range of material systems, such as piezoelectric materials, dielectric photonic crystals, optical waveguides and fibres, quantum dots, graphene and topological insulators. In this Review, we describe recent developments in this field with an emphasis on the physical mechanisms that lead to BICs across seemingly very different materials and types of waves. We also discuss experimental realizations, existing applications and directions for future work.

  5. Trace Impurities and Radiation Defects in Optical Materials

    NASA Astrophysics Data System (ADS)

    Malovichko, Galina; Grachev, Valentin; Meyer, Martin; Munro, Mark; Pankratov, Vladimir

    2007-05-01

    Trace impurities and radiation defects lead to inevitable performance degradation of devices based on optical materials. The results of the Electron Paramagnetic Resonance (EPR) study of defects in as grown and irradiated single crystals are reported. Among investigated optical materials are LiNbO3, Li2B4O7, KTiOPO4 etc. Crystals from different vendors or grown by different ways have different concentrations of non-controlled impurities and, as a result, different physical properties, including radiation resistance. Intrinsic defects (vacancies and antisites), usually present in congruent non-stoichiometric crystals like lithium niobate and tantalate. Many EPR lines of non-controlled impurities were found in KTiOPO4 crystals. We found that dominating types of defects formed under visible, UV and gamma photon irradiation are centers created by defects trapped electron or hole. The neutron and high energy electron irradiation creates stable Frenkel pairs - interstitial ions and vacancies. Computer simulation of observed spectra allowed us to determine spectroscopic characteristics and models for more than dozen trace impurities and radiation defects. Obtained data about atomic defects can be used for a selection of materials suitable for various applications. To cite this abstract, use the following reference: http://meetings.aps.org/link/BAPS.2007.NWS07.B1.2

  6. Relativistic and quantum electrodynamics effects in the helium pair potential.

    PubMed

    Przybytek, M; Cencek, W; Komasa, J; Łach, G; Jeziorski, B; Szalewicz, K

    2010-05-07

    The helium pair potential was computed including relativistic and quantum electrodynamics contributions as well as improved accuracy adiabatic ones. Accurate asymptotic expansions were used for large distances R. Error estimates show that the present potential is more accurate than any published to date. The computed dissociation energy and the average R for the (4)He(2) bound state are 1.62+/-0.03 mK and 47.1+/-0.5 A. These values can be compared with the measured ones: 1.1(-0.2)(+0.3) mK and 52+/-4 A [R. E. Grisenti, Phys. Rev. Lett. 85, 2284 (2000)].

  7. Rapid thermal co-annihilation through bound states in QCD

    NASA Astrophysics Data System (ADS)

    Kim, Seyong; Laine, M.

    2016-07-01

    The co-annihilation rate of heavy particles close to thermal equilibrium, which plays a role in many classic dark matter scenarios, can be "simulated" in QCD by considering the pair annihilation rate of a heavy quark and antiquark at a temperature of a few hundred MeV. We show that the so-called Sommerfeld factors, parameterizing the rate, can be defined and measured non-perturbatively within the NRQCD framework. Lattice measurements indicate a modest suppression in the octet channel, in reasonable agreement with perturbation theory, and a large enhancement in the singlet channel, much above the perturbative prediction. The additional enhancement is suggested to originate from bound state formation and subsequent decay. Making use of a Green's function based method to incorporate thermal corrections in perturbative co-annihilation rate computations, we show that qualitative agreement with lattice data can be found once thermally broadened bound states are accounted for. We suggest that our formalism may also be applicable to specific dark matter models which have complicated bound state structures.

  8. Watson-Crick pairing, the Heisenberg group and Milnor invariants.

    PubMed

    Gadgil, Siddhartha

    2009-07-01

    We study the secondary structure of RNA determined by Watson-Crick pairing without pseudo-knots using Milnor invariants of links. We focus on the first non-trivial invariant, which we call the Heisenberg invariant. The Heisenberg invariant, which is an integer, can be interpreted in terms of the Heisenberg group as well as in terms of lattice paths. We show that the Heisenberg invariant gives a lower bound on the number of unpaired bases in an RNA secondary structure. We also show that the Heisenberg invariant can predict allosteric structures for RNA. Namely, if the Heisenberg invariant is large, then there are widely separated local maxima (i.e., allosteric structures) for the number of Watson-Crick pairs found.

  9. Pairing symmetry and vortex zero mode for superconducting Dirac fermions

    SciTech Connect

    Lu, C.-K.; Herbut, Igor F.

    2010-10-01

    We study vortex zero-energy bound states in presence of pairing between low-energy Dirac fermions on the surface of a topological insulator. The pairing symmetries considered include the s-wave, p-wave, and, in particular, the mixed-parity symmetry, which arises in absence of the inversion symmetry on the surface. The zero mode is analyzed within the generalized Jackiw-Rossi-Dirac Hamiltonian that contains a momentum-dependent mass term, and includes the effects of the electromagnetic gauge field and the Zeeman coupling as well. At a finite chemical potential, as long as the spectrum without the vortex is fully gapped, the presence of a single Fermi surface with a definite helicity always leads to one Majorana zero mode, in which both electron's spin projections participate. In particular, the critical effects of the Zeeman coupling on the zero mode are discussed.

  10. Missing energies at pair creation

    NASA Technical Reports Server (NTRS)

    El-Ela, A. A.; Hassan, S.; Bagge, E. R.

    1985-01-01

    Wilson cloud chamber measurements of the separated spectra of positrons and electrons produced by gamma quanta of 6.14 MeV differ considerably from the theoretically predicted spectra by BETHE and HEITLER, but are in good agreement with those of a modified theory of pair creation.

  11. Pairing Linguistic and Music Intelligences

    ERIC Educational Resources Information Center

    DiEdwardo, MaryAnn Pasda

    2005-01-01

    This article describes how music in the language classroom setting can be a catalyst for developing reading, writing, and understanding skills. Studies suggest that pairing music and linguistic intelligences in the college classroom improves students' grades and abilities to compose theses statements for research papers in courses that emphasize…

  12. Pick a Pair. Being Bony

    ERIC Educational Resources Information Center

    Miller, Pat

    2004-01-01

    This column suggests pairings of fiction and nonfiction books to meet curricular needs and help students to compare/contrast the texts as they may be asked on state tests. The author of this paper focuses on activities surrounding Halloween. Since many schools are discouraged from teaching about Halloween, this can be a great time to investigate…

  13. Conjugate quasilinear Dirichlet and Neumann problems and a posteriori error bounds

    NASA Technical Reports Server (NTRS)

    Lavery, J. E.

    1976-01-01

    Quasilinear Dirichlet and Neumann problems on a rectangle D with boundary D prime are considered. Using these concepts, conjugate problems, that is, a pair of one Dirichlet and one Neumann problem, the minima of the energies of which add to zero, are introduced. From the concept of conjugate problems, two-sided bounds for the energy of the exact solution of any given Dirichlet or Neumann problem are constructed. These two-sided bounds for the energy at the exact solution are in turn used to obtain a posteriori error bounds for the norm of the difference of the approximate and exact solutions of the problem. These bounds do not involve the unknown exact solution and are easily constructed numerically.

  14. Scattering and bound states of fermions in a mixed vector–scalar smooth step potential

    SciTech Connect

    Castilho, W.M. Castro, A.S. de

    2014-07-15

    The scattering of a fermion in the background of a smooth step potential is considered with a general mixing of vector and scalar Lorentz structures with the scalar coupling stronger than or equal to the vector coupling. Charge-conjugation and chiral-conjugation transformations are discussed and it is shown that a finite set of intrinsically relativistic bound-state solutions appears as poles of the transmission amplitude. It is also shown that those bound solutions disappear asymptotically as one approaches the conditions for the realization of the so-called spin and pseudospin symmetries in a four-dimensional space–time. - Highlights: • Scattering and bound states of fermions in a kink-like potential. • No pair production despite the high localization. • No bounded solution under exact spin and pseudospin symmetries.

  15. Defect Tolerance in Methylammonium Lead Triiodide Perovskite

    SciTech Connect

    Steirer, K. Xerxes; Schulz, Philip; Teeter, Glenn; Stevanovic, Vladan; Yang, Mengjin; Zhu, Kai; Berry, Joseph J.

    2016-08-12

    Photovoltaic applications of perovskite semiconductor material systems have generated considerable interest in part because of predictions that primary defect energy levels reside outside the bandgap. We present experimental evidence that this enabling material property is present in the halide-lead perovskite, CH3NH3PbI3 (MAPbI3), consistent with theoretical predictions. By performing X-ray photoemission spectroscopy, we induce and track dynamic chemical and electronic transformations in the perovskite. These data show compositional changes that begin immediately with exposure to X-ray irradiation, whereas the predominant electronic structure of the thin film on compact TiO2 appears tolerant to the formation of compensating defect pairs of VI and VMA and for a large range of I/Pb ratios. Changing film composition is correlated with a shift of the valence-band maximum only as the halide-lead ratio drops below 2.5. This delay is attributed to the invariance of MAPbI3 electronic structure to distributed defects that can significantly transform the electronic density of states only when in high concentrations.

  16. Using tolerance bounds in scientific investigations

    SciTech Connect

    Wendelberger, J.R.

    1996-07-01

    Assessment of the variability in population values plays an important role in the analysis of scientific data. Analysis of scientific data often involves developing a bound on a proportion of a population. Sometimes simple probability bounds are obtained using formulas involving known mean and variance parameters and replacing the parameters by sample estimates. The resulting bounds are only approximate and fail to account for the variability in the estimated parameters. Tolerance bounds provide bounds on population proportions which account for the variation resulting from the estimated mean and variance parameters. A beta content, gamma confidence tolerance interval is constructed so that a proportion beta of the population lies within the region bounded by the interval with confidence gamma. An application involving corrosion measurements is used to illustrate the use of tolerance bounds for different situations. Extensions of standard tolerance intervals are applied to generate regression tolerance bounds, tolerance bounds for more general models of measurements collected over time, and tolerance intervals for varying precision data. Tolerance bounds also provide useful information for designing the collection of future data.

  17. Atrial Septal Defect (For Parents)

    MedlinePlus

    ... Defect Preparing Your Child for Surgery Heart and Circulatory System Anesthesia Basics Congenital Heart Defects Activity: The Heart ... EKG (Video) Going to the Hospital Your Heart & Circulatory System Quiz: Heart & Circulatory System EKG (Video) What's It ...

  18. Atrial Septal Defect (For Kids)

    MedlinePlus

    ... Dictionary of Medical Words En Español What Other Kids Are Reading Taking Care of Your Ears Taking ... an X-ray Atrial Septal Defect KidsHealth > For Kids > Atrial Septal Defect Print A A A What's ...

  19. Congenital heart defect - corrective surgery

    MedlinePlus

    ... repair; Tetralogy of Fallot repair; Coarctation of the aorta repair; Atrial septal defect repair; Ventricular septal defect ... the pulmonary valve and removing the thickened muscle (stenosis). Placing a patch on the right ventricle and ...

  20. Neural tube defects.

    PubMed

    Greene, Nicholas D E; Copp, Andrew J

    2014-01-01

    Neural tube defects (NTDs), including spina bifida and anencephaly, are severe birth defects of the central nervous system that originate during embryonic development when the neural tube fails to close completely. Human NTDs are multifactorial, with contributions from both genetic and environmental factors. The genetic basis is not yet well understood, but several nongenetic risk factors have been identified as have possibilities for prevention by maternal folic acid supplementation. Mechanisms underlying neural tube closure and NTDs may be informed by experimental models, which have revealed numerous genes whose abnormal function causes NTDs and have provided details of critical cellular and morphological events whose regulation is essential for closure. Such models also provide an opportunity to investigate potential risk factors and to develop novel preventive therapies.

  1. Controversies in Parotid Defect Reconstruction.

    PubMed

    Tamplen, Matthew; Knott, P Daniel; Fritz, Michael A; Seth, Rahul

    2016-08-01

    Reconstruction of the parotid defect is a complex topic that encompasses restoration of both facial form and function. The reconstructive surgeon must consider facial contour, avoidance of Frey syndrome, skin coverage, tumor surveillance, potential adjuvant therapy, and facial reanimation when addressing parotid defects. With each defect there are several options within the reconstructive ladder, creating controversies regarding optimal management. This article describes surgical approaches to reconstruction of parotid defects, highlighting areas of controversy.

  2. Molecular defects in the chondrodysplasias

    SciTech Connect

    Rimoin, D.L.

    1996-05-03

    There has been a recent explosion of knowledge concerning the biochemical and molecular defects in the skeletal dysplasia. Through both the candidate gene approach and positional cloning, specific gene defects that produce the skeletal dysplasia have been identified and may be classified into several general categories: (1) qualitative or quantitative abnormalities in the structural proteins of cartilage; (2) inborn errors of cartilage metabolism; (3) defects in local regulators of cartilage growth; and (4) systemic defects influencing cartilage development. 35 refs., 1 tab.

  3. Composite Defect Significance.

    DTIC Science & Technology

    1982-07-13

    A12i 299 COMPOSITE DEFECT SIGNIFICANCE(U) MATERIALS SCIENCES 1/1 \\ CORP SPRING HOUSE PA S N CHATTERJEE ET AL. 13 JUL 82 MSC/TFR/1288/il87 NADC-80848...Directorate 30 Sensors & Avionics Technology Directorate 40 Communication & Navigation Technology Directorate 50 Software Computer Directorate 60 Aircraft ...instructions concerning commercial products herein do not constitute an endorsement by the Government nor do they convey or imply the license or right to use

  4. Andreev bound state at a strongly correlated oxide interface

    NASA Astrophysics Data System (ADS)

    Cheng, Guanglei; Tomczyk, Michelle; Tacla, Alexandre; Daley, Andrew; Lu, Shicheng; Veazey, Josh; Huang, Mengchen; Irvin, Patrick; Ryu, Sangwoo; Lee, Hyungwoo; Eom, Chang-Beom; Pekker, David; Levy, Jeremy

    Strongly correlated electrons at oxide interfaces give rise to a set of novel physics phenomena including superconductivity and magnetism. At the LaAlO3/SrTiO3 (LAO/STO) interface, signatures of strong electron pairing persist even for conditions where superconductivity is suppressed. Meanwhile, an Andreev bound state (ABS) is a single quasiparticle excitation that mediates pair transport in confined superconductor-normal systems. Here we report a transition from pair resonant transport to ABS in sketched single electron transistors at the LAO/STO interface. This transition is consistent with a change of electron-electron interaction from attractive to repulsive, occurring at or near the Lifshitz transition. Such new electronically tunable electron-electron interaction may be useful for quantum simulation and engineering of novel quantum states in oxide materials. We gratefully acknowledge support from AFOSR FA9550-10-1-0524 (JL, CBE), AFOSR FA9550-12-1-0057 (JL, CBE, AD), NSF DMR-1104191 (JL), ONR N00014-15-1-2847 (JL).

  5. Bound anionic states of adenine

    SciTech Connect

    Haranczyk, Maciej; Gutowski, Maciej S; Li, Xiang; Bowen, Kit H

    2007-03-20

    Anionic states of nucleic acid bases are involved in DNA damage by low-energy electrons and in charge transfer through DNA. Previous gas phase studies of free, unsolvated nucleic acid base parent anions probed only dipole-bound states, which are not present in condensed phase environments, but did not observe valence anionic states, which for purine bases, are thought to be adiabatically unbound. Contrary to this expectation, we have demonstrated that some thus far ignored tautomers of adenine, which result from enamine-imine transformations, support valence anionic states with electron vertical detachment energies as large as 2.2 eV, and at least one of these anionic tautomers is adiabatically bound. Moreover, we predict that the new anionic tautomers should also dominate in solutions and should be characterized by larger values of electron vertical detachment energy than the canonical valence anion. All of the new-found anionic tautomers might be formed in the course of dissociative electron attachment followed by a hydrogen atom attachment to a carbon atom, and they might affect the structure and properties of DNA and RNA exposed to low-energy electrons. The discovery of these valence anionic states of adenine was facilitated by the development of: (i) a new experimental method for preparing parent anions of nucleic acid bases for photoelectron experiments, and (ii) a new combinatorial/ quantum chemical approach for identification of the most stable tautomers of organic molecules. The computational portion of this work was supported by the: (i) Polish State Committee for Scientific Research (KBN) Grants: DS/8000-4-0140-7 (M.G.) and N204 127 31/2963 (M.H.), (ii) European Social Funds (EFS) ZPORR/2.22/II/2.6/ARP/U/2/05 (M.H.), and (iii) US DOE Office of Biological and Environmental Research, Low Dose Radiation Research Program (M.G.). M.H. holds the Foundation for Polish Science (FNP) award for young scientists. The calculations were performed at the Academic

  6. Defect mapping system

    DOEpatents

    Sopori, Bhushan L.

    1995-01-01

    Apparatus for detecting and mapping defects in the surfaces of polycrystalline materials in a manner that distinguishes dislocation pits from grain boundaries includes a laser for illuminating a wide spot on the surface of the material, a light integrating sphere with apertures for capturing light scattered by etched dislocation pits in an intermediate range away from specular reflection while allowing light scattered by etched grain boundaries in a near range from specular reflection to pass through, and optical detection devices for detecting and measuring intensities of the respective intermediate scattered light and near specular scattered light. A center blocking aperture or filter can be used to screen out specular reflected light, which would be reflected by nondefect portions of the polycrystalline material surface. An X-Y translation stage for mounting the polycrystalline material and signal processing and computer equipment accommodate rastor mapping, recording, and displaying of respective dislocation and grain boundary defect densities. A special etch procedure is included, which prepares the polycrystalline material surface to produce distinguishable intermediate and near specular light scattering in patterns that have statistical relevance to the dislocation and grain boundary defect densities.

  7. Defect mapping system

    DOEpatents

    Sopori, B.L.

    1995-04-11

    Apparatus for detecting and mapping defects in the surfaces of polycrystalline materials in a manner that distinguishes dislocation pits from grain boundaries includes a laser for illuminating a wide spot on the surface of the material, a light integrating sphere with apertures for capturing light scattered by etched dislocation pits in an intermediate range away from specular reflection while allowing light scattered by etched grain boundaries in a near range from specular reflection to pass through, and optical detection devices for detecting and measuring intensities of the respective intermediate scattered light and near specular scattered light. A center blocking aperture or filter can be used to screen out specular reflected light, which would be reflected by nondefect portions of the polycrystalline material surface. An X-Y translation stage for mounting the polycrystalline material and signal processing and computer equipment accommodate rastor mapping, recording, and displaying of respective dislocation and grain boundary defect densities. A special etch procedure is included, which prepares the polycrystalline material surface to produce distinguishable intermediate and near specular light scattering in patterns that have statistical relevance to the dislocation and grain boundary defect densities. 20 figures.

  8. Defective pyrite (100) surface: An ab initio study

    SciTech Connect

    Stirling, Andras; Bernasconi, Marco; Parrinello, Michele

    2007-04-15

    The structural and electronic properties of sulfur monomeric defects at the FeS{sub 2}(100) surface have been studied by periodic density-functional calculations. We have shown that for a monomeric sulfur bound to an originally fivefold coordinated surface Fe site, the defect core features a triplet electronic ground state with unpaired spins localized on the exposed Fe-S unit. At this site, the iron and sulfur ions have oxidation states +4 and -2, respectively. This defect can be seen as produced via heterolytic bond breaking of the S-S sulfur dimer followed by a Fe-S redox reaction. The calculated sulfur 2p core-level shifts of the monomeric defects are in good agreement with experimental photoemission spectra, which allow a compelling assignment of the different spectroscopic features. The effect of water on the stability of the defective surface has also been studied, and it has been shown that the triplet state is stable against the wetting of the surface. The most important implications of the presence of the monomeric sulfur defect on the reactivity are also discussed.

  9. Study of lattice defect vibration

    NASA Technical Reports Server (NTRS)

    Elliott, R. J.

    1969-01-01

    Report on the vibrations of defects in crystals relates how defects, well localized in a crystal but interacting strongly with the other atoms, change the properties of a perfect crystal. The methods used to solve defect problems relate the properties of an imperfect lattice to the properties of a perfect lattice.

  10. Soliton-like defects in nematic liquid crystal thin layers

    NASA Astrophysics Data System (ADS)

    Chuvyrov, A. N.; Krekhov, A. P.; Lebedev, Yu. A.; Timirov, Yu. I.

    2016-11-01

    The nonsingular soliton-like defects in plane nematic liquid crystal (NLC) layers and spherical NLC drops are experimentally detected and studied when the interaction of NLC molecules with a bounding surface is varied. The dynamics and the annihilation of nonsingular defects of opposite signs on a plane surface are investigated. Periodic transformations of the soliton-like defects in NLC drops in an electric field are detected. The theory of elasticity is used to show that the surface energy taken into account in the total free energy of NLC in the case of weak anchoring leads to the possibility of nonsingular solutions of a director equilibrium equation. The calculated pictures of director distribution in a plane NLC layer and in a spherical NLC drop characterized by weak surface anchoring agree well with the results of polarized light optical observations.

  11. Collisions of Vortex Filament Pairs

    NASA Astrophysics Data System (ADS)

    Banica, Valeria; Faou, Erwan; Miot, Evelyne

    2014-12-01

    We consider the problem of collisions of vortex filaments for a model introduced by Klein et al. (J Fluid Mech 288:201-248, 1995) and Zakharov (Sov Phys Usp 31(7):672-674, 1988, Lect. Notes Phys 536:369-385, 1999) to describe the interaction of almost parallel vortex filaments in three-dimensional fluids. Since the results of Crow (AIAA J 8:2172-2179, 1970) examples of collisions are searched as perturbations of antiparallel translating pairs of filaments, with initial perturbations related to the unstable mode of the linearized problem; most results are numerical calculations. In this article, we first consider a related model for the evolution of pairs of filaments, and we display another type of initial perturbation leading to collision in finite time. Moreover, we give numerical evidence that it also leads to collision through the initial model. We finally study the self-similar solutions of the model.

  12. Stabilization of primary mobile radiation defects in MgF2 crystals

    NASA Astrophysics Data System (ADS)

    Lisitsyn, V. M.; Lisitsyna, L. A.; Popov, A. I.; Kotomin, E. A.; Abuova, F. U.; Akilbekov, A.; Maier, J.

    2016-05-01

    Non-radiative decay of the electronic excitations (excitons) into point defects (F-H pairs of Frenkel defects) is main radiation damage mechanism in many ionic (halide) solids. Typical time scale of the relaxation of the electronic excitation into a primary, short-lived defect pair is about 1-50 ps with the quantum yield up to 0.2-0.8. However, only a small fraction of these primary defects are spatially separated and survive after transformation into stable, long-lived defects. The survival probability (or stable defect accumulation efficiency) can differ by orders of magnitude, dependent on the material type; e.g. ∼10% in alkali halides with f.c.c. or b.c.c. structure, 0.1% in rutile MgF2 and <0.001% in fluorides MeF2 (Me: Ca, Sr, Ba). The key factor determining accumulation of stable radiation defects is stabilization of primary defects, first of all, highly mobile hole H centers, through their transformation into more complex immobile defects. In this talk, we present the results of theoretical calculations of the migration energies of the F and H centers in poorely studied MgF2 crystals with a focus on the H center stabilization in the form of the interstitial F2 molecules which is supported by presented experimental data.

  13. Asymmetric Ion-Pairing Catalysis

    PubMed Central

    Brak, Katrien

    2014-01-01

    Charged intermediates and reagents are ubiquitous in organic transformations. The interaction of these ionic species with chiral neutral, anionic, or cationic small molecules has emerged as a powerful strategy for catalytic, enantioselective synthesis. This review describes developments in the burgeoning field of asymmetric ion-pairing catalysis with an emphasis on the insights that have been gleaned into the structural and mechanistic features that contribute to high asymmetric induction. PMID:23192886

  14. Septin pairs, a complex choreography.

    PubMed

    Ewers, Helge

    2011-06-13

    Septins form a filamentous collar at the mother-bud neck in budding yeast. In cytokinesis, this collar splits into two rings and the septin complexes undergo a dramatic reorientation. Using fluorescence polarization microscopy, DeMay et al. (2011. J. Cell Biol. doi:10.1083/jcb.201012143) now demonstrate that septin complexes assemble as paired filaments in vivo and reveal new insights into septin organization during cytokinesis.

  15. Disclinations, dislocations, and continuous defects: A reappraisal

    NASA Astrophysics Data System (ADS)

    Kleman, M.; Friedel, J.

    2008-01-01

    Disclinations were first observed in mesomorphic phases. They were later found relevant to a number of ill-ordered condensed-matter media involving continuous symmetries or frustrated order. Disclinations also appear in polycrystals at the edges of grain boundaries; but they are of limited interest in solid single crystals, where they can move only by diffusion climb and, owing to their large elastic stresses, mostly appear in close pairs of opposite signs. The relaxation mechanisms associated with a disclination in its creation, motion, and change of shape involve an interplay with continuous or quantized dislocations and/or continuous disclinations. These are attached to the disclinations or are akin to Nye’s dislocation densities, which are particularly well suited for consideration here. The notion of an extended Volterra process is introduced, which takes these relaxation processes into account and covers different situations where this interplay takes place. These concepts are illustrated by a variety of applications in amorphous solids, mesomorphic phases, and frustrated media in their curved habit space. These often involve disclination networks with specific node conditions. The powerful topological theory of line defects considers only defects stable against any change of boundary conditions or relaxation processes compatible with the structure considered. It can be seen as a simplified case of the approach considered here, particularly suited for media of high plasticity or/and complex structures. It cannot analyze the dynamical properties of defects nor the elastic constants involved in their static properties; topological stability cannot guarantee energetic stability, and sometimes cannot distinguish finer details of the structure of defects.

  16. Impurity bound states in fully gapped d-wave superconductors with subdominant order parameters.

    PubMed

    Mashkoori, Mahdi; Björnson, Kristofer; Black-Schaffer, Annica M

    2017-03-10

    Impurities in superconductors and their induced bound states are important both for engineering novel states such as Majorana zero-energy modes and for probing bulk properties of the superconducting state. The high-temperature cuprates offer a clear advantage in a much larger superconducting order parameter, but the nodal energy spectrum of a pure d-wave superconductor only allows virtual bound states. Fully gapped d-wave superconducting states have, however, been proposed in several cuprate systems thanks to subdominant order parameters producing d + is- or d + id'-wave superconducting states. Here we study both magnetic and potential impurities in these fully gapped d-wave superconductors. Using analytical T-matrix and complementary numerical tight-binding lattice calculations, we show that magnetic and potential impurities behave fundamentally different in d + is- and d + id'-wave superconductors. In a d + is-wave superconductor, there are no bound states for potential impurities, while a magnetic impurity produces one pair of bound states, with a zero-energy level crossing at a finite scattering strength. On the other hand, a d + id'-wave symmetry always gives rise to two pairs of bound states and only produce a reachable zero-energy level crossing if the normal state has a strong particle-hole asymmetry.

  17. Impurity bound states in fully gapped d-wave superconductors with subdominant order parameters

    PubMed Central

    Mashkoori, Mahdi; Björnson, Kristofer; Black-Schaffer, Annica M.

    2017-01-01

    Impurities in superconductors and their induced bound states are important both for engineering novel states such as Majorana zero-energy modes and for probing bulk properties of the superconducting state. The high-temperature cuprates offer a clear advantage in a much larger superconducting order parameter, but the nodal energy spectrum of a pure d-wave superconductor only allows virtual bound states. Fully gapped d-wave superconducting states have, however, been proposed in several cuprate systems thanks to subdominant order parameters producing d + is- or d + id′-wave superconducting states. Here we study both magnetic and potential impurities in these fully gapped d-wave superconductors. Using analytical T-matrix and complementary numerical tight-binding lattice calculations, we show that magnetic and potential impurities behave fundamentally different in d + is- and d + id′-wave superconductors. In a d + is-wave superconductor, there are no bound states for potential impurities, while a magnetic impurity produces one pair of bound states, with a zero-energy level crossing at a finite scattering strength. On the other hand, a d + id′-wave symmetry always gives rise to two pairs of bound states and only produce a reachable zero-energy level crossing if the normal state has a strong particle-hole asymmetry. PMID:28281570

  18. Impurity bound states in fully gapped d-wave superconductors with subdominant order parameters

    NASA Astrophysics Data System (ADS)

    Mashkoori, Mahdi; Björnson, Kristofer; Black-Schaffer, Annica M.

    2017-03-01

    Impurities in superconductors and their induced bound states are important both for engineering novel states such as Majorana zero-energy modes and for probing bulk properties of the superconducting state. The high-temperature cuprates offer a clear advantage in a much larger superconducting order parameter, but the nodal energy spectrum of a pure d-wave superconductor only allows virtual bound states. Fully gapped d-wave superconducting states have, however, been proposed in several cuprate systems thanks to subdominant order parameters producing d + is- or d + id‧-wave superconducting states. Here we study both magnetic and potential impurities in these fully gapped d-wave superconductors. Using analytical T-matrix and complementary numerical tight-binding lattice calculations, we show that magnetic and potential impurities behave fundamentally different in d + is- and d + id‧-wave superconductors. In a d + is-wave superconductor, there are no bound states for potential impurities, while a magnetic impurity produces one pair of bound states, with a zero-energy level crossing at a finite scattering strength. On the other hand, a d + id‧-wave symmetry always gives rise to two pairs of bound states and only produce a reachable zero-energy level crossing if the normal state has a strong particle-hole asymmetry.

  19. Thermal properties of defective fullerene

    NASA Astrophysics Data System (ADS)

    Li, Jian; Zheng, Dong-Qin; Zhong, Wei-Rong

    2016-09-01

    We have investigated the thermal conductivity of defective fullerene (C60) by using the nonequilibrium molecular dynamics (MD) method. It is found that the thermal conductivity of C60 with one defect is lower than the thermal conductivity of perfect C60. However, double defects in C60 have either positive or negative influence on the thermal conductivity, which depends on the positions of the defects. The phonon spectra of perfect and defective C60 are also provided to give corresponding supports. Our results can be extended to long C60 chains, which is helpful for the thermal management of C60.

  20. Germination-defective mutant of Neurospora crassa that responds to siderophores

    NASA Technical Reports Server (NTRS)

    Charlang, G.; Williams, N. P.

    1977-01-01

    A conditionally germination-defective mutant of Neurospora crassa has been found to be partially curable by ferricrocin and other siderophores. The mutant conidia rapidly lose their membrane-bound siderophores when suspended in buffer or growth media. Germination is consequently delayed unless large numbers of conidia are present (positive population effect). This indicates that the mutant has a membrane defect involving the siderophore attachment site.

  1. Classification of two-dimensional topological crystalline superconductors and Majorana bound states at disclinations

    NASA Astrophysics Data System (ADS)

    Benalcazar, Wladimir A.; Teo, Jeffrey C. Y.; Hughes, Taylor L.

    2014-06-01

    We classify discrete-rotation symmetric topological crystalline superconductors (TCS) in two dimensions and provide the criteria for a zero-energy Majorana bound state (MBS) to be present at composite defects made from magnetic flux, dislocations, and disclinations. In addition to the Chern number that encodes chirality, discrete rotation symmetry further divides TCS into distinct stable topological classes according to the rotation eigenspectrum of Bogoliubov-de Gennes quasiparticles. Conical crystalline defects are shown to be able to accommodate robust MBS when a certain combination of these bulk topological invariants is nontrivial as dictated by the index theorems proved within. The number parity of MBS is counted by a Z2-valued index that solely depends on the disclination and the topological class of the TCS. We also discuss the implications for corner-bound Majorana modes on the boundary of topological crystalline superconductors.

  2. A lower bound for the QRQW PRAM

    SciTech Connect

    MacKenzie, P.D.

    1995-05-02

    The queue-read, queue-write (QRQW) parallel random access machine (PRAM) model is a shared memory model which allows concurrent reading and writing with a time cost proportional to the contention. This is designed to model currently available parallel machines more accurately than either the CRCW PRAM or EREW PRAM models. Many algorithmic results have been developed for the QRQW PRAM. However, the only lower bound results have been fairly simple reductions from lower bounds for other models, such as the EREW PRAM or the ``few-write`` CREW PRAM. Here we present a lower bound specific to the QRQW PRAM. This lower bound is on the problem of Linear Approximate Compaction (LAC), whose input consists of at most m marked items in an array of size n, and whose output consists of the rn marked items in an array of size 0(m). There is an O({radical}log n), expected time randomized algorithm for LAC on the QRQW PRAM. We prove a lower bound of {Omega}(log log log n) expected time for any randomized algorithm for LAC. This bound applies regardless of the number of processors and memory cells of the QRQW PRAM. The previous best lower bound was {Omega}(log* n) time, taken from the known lower bound for LAC on the CRCW PRAM.

  3. Outward Bound: An Innovative Patient Education Program.

    ERIC Educational Resources Information Center

    Stich, Thomas F.; Gaylor, Michael S.

    A 1975 Dartmouth Outward Bound Mental Health Project, begun with a pilot project for disturbed adolescents, has evolved into an ongoing treatment option in three separate clinical settings for psychiatric patients and recovering alcoholics. Outward Bound consists of a series of prescribed physical and social tasks where the presence of stress,…

  4. Generalized upper bound for inelastic diffraction

    NASA Astrophysics Data System (ADS)

    Troshin, S. M.; Tyurin, N. E.

    2017-01-01

    For inelastic diffraction, we obtain an upper bound valid for the whole range of the elastic scattering amplitude variation allowed by unitarity. We discuss the energy dependence of the inelastic diffractive cross-section on the base of this bound and recent Large Hadron Collider (LHC) data.

  5. THE HOPF BIFURCATION WITH BOUNDED NOISE

    PubMed Central

    Botts, Ryan T.; Homburg, Ale Jan; Young, Todd R.

    2012-01-01

    We study Hopf-Andronov bifurcations in a class of random differential equations (RDEs) with bounded noise. We observe that when an ordinary differential equation that undergoes a Hopf bifurcation is subjected to bounded noise then the bifurcation that occurs involves a discontinuous change in the Minimal Forward Invariant set. PMID:24748762

  6. Outward Bound: an Experience in Human Development

    ERIC Educational Resources Information Center

    Danenburg, William; Gaggi, Silvio

    1974-01-01

    Two authors describe how their participation in an outward bound program has helped them develop a greater degree of general self confidence, greater ease in dealing with complex and frustrating problems, and a greater appreciation of man's place in the natural environment. They also describe Outward Bound courses that have been especially…

  7. Rigorous bounds for optimal dynamical decoupling

    SciTech Connect

    Uhrig, Goetz S.; Lidar, Daniel A.

    2010-07-15

    We present rigorous performance bounds for the optimal dynamical decoupling pulse sequence protecting a quantum bit (qubit) against pure dephasing. Our bounds apply under the assumption of instantaneous pulses and of bounded perturbing environment and qubit-environment Hamiltonians such as those realized by baths of nuclear spins in quantum dots. We show that if the total sequence time is fixed the optimal sequence can be used to make the distance between the protected and unperturbed qubit states arbitrarily small in the number of applied pulses. If, on the other hand, the minimum pulse interval is fixed and the total sequence time is allowed to scale with the number of pulses, then longer sequences need not always be advantageous. The rigorous bound may serve as a testbed for approximate treatments of optimal decoupling in bounded models of decoherence.

  8. Phenomenology of transionospheric pulse pairs

    NASA Astrophysics Data System (ADS)

    Massey, R. S.; Holden, D. N.

    1995-09-01

    Recent observations of transient radio impulses by an Earth-orbiting satellite appear to be quite unlike any previously reported. They appear as pairs of brief (a few microseconds), noiselike bursts, separated by a few tens of microseconds, and are dispersed in a way that implies subionospheric origin. Over 300 of these events have now been observed. These "transionospheric pulse pairs" (TIPPs) have not yet been associated with any known source, although thunderstorms are suspected. The observations, made by the Blackbeard instrument on the ALEXIS satellite, are digitized records of the electric field in a passband from about 25 to 100 MHz. Ground-based observations of lightning in this band appear quite different, even accounting for ionospheric dispersion: bursts of short pulses last hundreds of microseconds and have much lower power (when propagated to the satellite) than TIPP events. Signals that resemble the ground-based data have been observed by Blackbeard but, being much weaker, are much less likely to trigger the instrument than are the strong pulse pair events. In this paper we analyze 97 of the early TIPP observations. We compute several parameters that describe the events: the location of the satellite at the time of reception, the energy in each pulse, the separation between pulses, the duration of each pulse, and the dispersion of each pulse. The statistical distributions of these parameters provide clues to and constraints on possible source mechanisms. The possibility that the pulses might be the direct and reflected signals from a high-altitude source is considered and cannot be rejected by the data.

  9. Point defects in thorium nitride: A first-principles study

    NASA Astrophysics Data System (ADS)

    Pérez Daroca, D.; Llois, A. M.; Mosca, H. O.

    2016-11-01

    Thorium and its compounds (carbides and nitrides) are being investigated as possible materials to be used as nuclear fuels for Generation-IV reactors. As a first step in the research of these materials under irradiation, we study the formation energies and stability of point defects in thorium nitride by means of first-principles calculations within the framework of density functional theory. We focus on vacancies, interstitials, Frenkel pairs and Schottky defects. We found that N and Th vacancies have almost the same formation energy and that the most energetically favorable defects of all studied in this work are N interstitials. These kind of results for ThN, to the best authors' knowledge, have not been obtained previously, neither experimentally, nor theoretically.

  10. Paired circularly polarized heterodyne ellipsometer

    SciTech Connect

    Yu, C.-J.; Lin, C.-E.; Yu, L.-P.; Chou, C

    2009-02-01

    We develop a paired circularly polarized heterodyne ellipsometer (PCPHE), in which a heterodyne interferometer based on a two-frequency circularly polarized laser beam is set up. It belongs to an amplitude-sensitive ellipsometer that is able to provide not only a wider dynamic range of polarization modulation frequency but also a higher detection sensitivity than that of a conventional photometric ellipsometer. A real-time and precise measurement of ellipsometric parameters, which demonstrated an accuracy of less than 1 nm on thickness measurement of SiO2 thin film deposited on silicon substrate, can be applied with the PCPHE.

  11. [Congenital defects and incapacity].

    PubMed

    Jouve de la Barreda, Nicolás

    2009-01-01

    As a whole the congenital defects constitute an important section of the medical attention affecting near 3% of the population. A 15% of spontaneous abortions take place of which the greater frequency corresponds to the chromosome anomalies (25%) and the monogenic mutations (20%) and in a lesser extent to the effects of teratogenic agents. Between the genetic causes determining the congenital defects the mutations that affect genes acting in the early stages of development occupy a main place. These alterations can affect to homeotic genes or monogenic systems that act during the critical phases of the organogenesis. It seems evident that an alteration in the expression of a necessary gene for the appearance of a morphogenetic change constitutes the angular stone to understand resurging of a malformation or discapacity. In the last years has been demonstrated the importance of the teratogenic or environmental agents on the delicate internal physiological balance during the critical stages of the development. In this context must be included the inductive environmental factors inducing epigenetic modifications in the early stage of the development of the embryos produced by fertilization in vitro.

  12. Dynamic nuclear polarization of membrane proteins: covalently bound spin-labels at protein-protein interfaces.

    PubMed

    Wylie, Benjamin J; Dzikovski, Boris G; Pawsey, Shane; Caporini, Marc; Rosay, Melanie; Freed, Jack H; McDermott, Ann E

    2015-04-01

    We demonstrate that dynamic nuclear polarization of membrane proteins in lipid bilayers may be achieved using a novel polarizing agent: pairs of spin labels covalently bound to a protein of interest interacting at an intermolecular interaction surface. For gramicidin A, nitroxide tags attached to the N-terminal intermolecular interface region become proximal only when bimolecular channels forms in the membrane. We obtained signal enhancements of sixfold for the dimeric protein. The enhancement effect was comparable to that of a doubly tagged sample of gramicidin C, with intramolecular spin pairs. This approach could be a powerful and selective means for signal enhancement in membrane proteins, and for recognizing intermolecular interfaces.

  13. Bound-free Spectra for Diatomic Molecules

    NASA Technical Reports Server (NTRS)

    Schwenke, David W.

    2012-01-01

    It is now recognized that prediction of radiative heating of entering space craft requires explicit treatment of the radiation field from the infrared (IR) to the vacuum ultra violet (VUV). While at low temperatures and longer wavelengths, molecular radiation is well described by bound-bound transitions, in the short wavelength, high temperature regime, bound-free transitions can play an important role. In this work we describe first principles calculations we have carried out for bound-bound and bound-free transitions in N2, O2, C2, CO, CN, NO, and N2+. Compared to bound ]bound transitions, bound-free transitions have several particularities that make them different to deal with. These include more complicated line shapes and a dependence of emission intensity on both bound state diatomic and atomic concentrations. These will be discussed in detail below. The general procedure we used was the same for all species. The first step is to generate potential energy curves, transition moments, and coupling matrix elements by carrying out ab initio electronic structure calculations. These calculations are expensive, and thus approximations need to be made in order to make the calculations tractable. The only practical method we have to carry out these calculations is the internally contracted multi-reference configuration interaction (icMRCI) method as implemented in the program suite Molpro. This is a widely used method for these kinds of calculations, and is capable of generating very accurate results. With this method, we must first of choose which electrons to correlate, the one-electron basis to use, and then how to generate the molecular orbitals.

  14. Protein packing defects "heat up" interfacial water.

    PubMed

    Sierra, María Belén; Accordino, Sebastián R; Rodriguez-Fris, J Ariel; Morini, Marcela A; Appignanesi, Gustavo A; Fernández Stigliano, Ariel

    2013-06-01

    Ligands must displace water molecules from their corresponding protein surface binding site during association. Thus, protein binding sites are expected to be surrounded by non-tightly-bound, easily removable water molecules. In turn, the existence of packing defects at protein binding sites has been also established. At such structural motifs, named dehydrons, the protein backbone is exposed to the solvent since the intramolecular interactions are incompletely wrapped by non-polar groups. Hence, dehydrons are sticky since they depend on additional intermolecular wrapping in order to properly protect the structure from water attack. Thus, a picture of protein binding is emerging wherein binding sites should be both dehydrons rich and surrounded by easily removable water. In this work we shall indeed confirm such a link between structure and dynamics by showing the existence of a firm correlation between the degree of underwrapping of the protein chain and the mobility of the corresponding hydration water molecules. In other words, we shall show that protein packing defects promote their local dehydration, thus producing a region of "hot" interfacial water which might be easily removed by a ligand upon association.

  15. Interaction of sine-Gordon kinks and breathers with a parity-time-symmetric defect

    NASA Astrophysics Data System (ADS)

    Saadatmand, Danial; Dmitriev, Sergey V.; Borisov, Denis I.; Kevrekidis, Panayotis G.

    2014-11-01

    The scattering of kinks and low-frequency breathers of the nonlinear sine-Gordon (SG) equation on a spatially localized parity-time-symmetric perturbation (defect) with a balanced gain and loss is investigated numerically. It is demonstrated that if a kink passes the defect, it always restores its initial momentum and energy, and the only effect of the interaction with the defect is a phase shift of the kink. A kink approaching the defect from the gain side always passes, while in the opposite case it must have sufficiently large initial momentum to pass through the defect instead of being trapped in the loss region. The kink phase shift and critical velocity are calculated by means of the collective variable method. Kink-kink (kink-antikink) collisions at the defect are also briefly considered, showing how their pairwise repulsive (respectively, attractive) interaction can modify the collisional outcome of a single kink within the pair with the defect. For the breather, the result of its interaction with the defect depends strongly on the breather parameters (velocity, frequency, and initial phase) and on the defect parameters. The breather can gain some energy from the defect and as a result potentially even split into a kink-antikink pair, or it can lose a part of its energy. Interestingly, the breather translational mode is very weakly affected by the dissipative perturbation, so that a breather penetrates more easily through the defect when it comes from the lossy side, than a kink. In all studied soliton-defect interactions, the energy loss to radiation of small-amplitude extended waves is negligible.

  16. Theoretical study of transition-metal ions bound to benzene

    NASA Technical Reports Server (NTRS)

    Bauschlicher, Charles W., Jr.; Partridge, Harry; Langhoff, Stephen R.

    1992-01-01

    Theoretical binding energies are reported for all first-row and selected second-row transition metal ions (M+) bound to benzene. The calculations employ basis sets of at least double-zeta plus polarization quality and account for electron correlation using the modified coupled-pair functional method. While the bending is predominantly electrostatic, the binding energies are significantly increased by electron correlation, because the donation from the metal d orbitals to the benzene pi* orbitals is not well described at the self-consistent-field level. The uncertainties in the computed binding energies are estimated to be about 5 kcal/mol. Although the calculated and experimental binding energies generally agree to within their combined uncertainties, it is likely that the true binding energies lie in the lower portion of the experimental range. This is supported by the very good agreement between the theoretical and recent experimental binding energies for AgC6H6(+).

  17. Bound {mu}{sup +}{mu}{sup {minus}} system

    SciTech Connect

    Jentschura, U.D.; Soff, G.; Ivanov, V.G.; Karshenboim, S.G.

    1997-12-01

    We consider the hyperfine structure, the atomic spectrum, and the decay channels of the bound {mu}{sup +}{mu}{sup {minus}} system (dimuonium). The annihilation lifetimes of low-lying atomic states of the system lie in the 10{sup {minus}12} s range. The decay rates could be measured by detection of the decay products (high-energy photons or electron-positron pairs). The hyperfine-structure splitting of the dimuonic system and its decay rate are influenced by electronic vacuum polarization effects in the far timelike asymptotic region. This constitutes a previously unexplored kinematic regime. We evaluate next-to-leading-order radiative corrections to the decay rate of low-lying atomic states. We also obtain order {alpha}{sup 5}m{sub {mu}} corrections to the hyperfine splitting of the 1S and 2S levels. {copyright} {ital 1997} {ital The American Physical Society}

  18. Odd-frequency pairing and Ising spin susceptibility in time-reversal-invariant superfluids and superconductors

    NASA Astrophysics Data System (ADS)

    Mizushima, Takeshi

    2014-11-01

    We here illustrate the relation between odd-frequency spin-triplet even-parity (OTE) Cooper pairs and anomalous surface magnetic response in time-reversal-invariant (TRI) spin-triplet superfluids and superconductors. The spin susceptibility generally consists of two contributions: even-frequency odd-parity pair amplitudes and odd-frequency even-parity pair amplitudes. The OTE pair amplitudes are absent in the bulk region, but ubiquitously exist in the surface and interface region as Andreev bound states. We here clarify that additional discrete symmetries, originating from the internal symmetry and point-group symmetry, impose strong constraint on the OTE pair amplitudes emergent in the surface of TRI superfluids and superconductors. As a result of the symmetry constraint, the magnetic response of the OTE pairs yields Ising-like anisotropy. For the topological phase of the 3He -B in a restricted geometry, the coupling of the OTE pair amplitudes to an applied field is prohibited by an additional discrete symmetry. Once the discrete symmetry is broken, however, the OTE pairs start to couple to the applied field, which anomalously enhances surface spin susceptibility. Furthermore, we extend this theory to TRI superconductors, where the corresponding discrete symmetry is the mirror reflection symmetry.

  19. Influence of pairing correlations on the radius of neutron-rich nuclei

    NASA Astrophysics Data System (ADS)

    Zhang, Ying; Chen, Ying; Meng, Jie; Ring, Peter

    2017-01-01

    The influence of pairing correlations on the neutron root mean square (rms) radius of nuclei is investigated in the framework of self-consistent Skyrme Hartree-Fock-Bogoliubov calculations. The continuum is treated appropriately by the Green's function techniques. As an example the nucleus 124Zr is treated for a varying strength of pairing correlations. We find that, as the pairing strength increases, the neutron rms radius first shrinks, reaches a minimum, and beyond this point it expands again. The shrinkage is due to the the so-called pairing antihalo effect, i.e., due to the decrease of the asymptotic density distribution with increasing pairing. However, in some cases, increasing pairing correlations can also lead to an expansion of the nucleus due to a growing occupation of so-called halo orbits, i.e., weakly bound states and resonances in the continuum with low-ℓ values. In this case, the neutron radii are extended just by the influence of pairing correlations, since these halo orbits cannot be occupied without pairing. The term "antihalo effect" is not justified in such cases. For a full understanding of this complicated interplay, self-consistent calculations are necessary.

  20. Rashba Splitting of Cooper Pairs

    NASA Astrophysics Data System (ADS)

    Shekhter, R. I.; Entin-Wohlman, O.; Jonson, M.; Aharony, A.

    2016-05-01

    We investigate theoretically the properties of a weak link between two superconducting leads, which has the form of a nonsuperconducting nanowire with a strong Rashba spin-orbit coupling caused by an electric field. In the Coulomb-blockade regime of single-electron tunneling, we find that such a weak link acts as a "spin splitter" of the spin states of Cooper pairs tunneling through the link, to an extent that depends on the direction of the electric field. We show that the Josephson current is sensitive to interference between the resulting two transmission channels, one where the spins of both members of a Cooper pair are preserved and one where they are both flipped. As a result, the current is a periodic function of the strength of the spin-orbit interaction and of the bending angle of the nanowire (when mechanically bent); an identical effect appears due to strain-induced spin-orbit coupling. In contrast, no spin-orbit induced interference effect can influence the current through a single weak link connecting two normal metals.

  1. Sloan Low-mass Wide Pairs of Kinematically Equivalent Stars (SLoWPoKES): A Catalog of Very Wide, Low-mass Pairs

    NASA Astrophysics Data System (ADS)

    Dhital, Saurav; West, Andrew A.; Stassun, Keivan G.; Bochanski, John J.

    2010-06-01

    We present the Sloan Low-mass Wide Pairs of Kinematically Equivalent Stars (SLoWPoKES), a catalog of 1342 very-wide (projected separation gsim500 AU), low-mass (at least one mid-K to mid-M dwarf component) common proper motion pairs identified from astrometry, photometry, and proper motions in the Sloan Digital Sky Survey. A Monte Carlo-based Galactic model is constructed to assess the probability of chance alignment for each pair; only pairs with a probability of chance alignment <=0.05 are included in the catalog. The overall fidelity of the catalog is expected to be 98.35%. The selection algorithm is purposely exclusive to ensure that the resulting catalog is efficient for follow-up studies of low-mass pairs. The SLoWPoKES catalog is the largest sample of wide, low-mass pairs to date and is intended as an ongoing community resource for detailed study of bona fide systems. Here, we summarize the general characteristics of the SLoWPoKES sample and present preliminary results describing the properties of wide, low-mass pairs. While the majority of the identified pairs are disk dwarfs, there are 70 halo subdwarf (SD) pairs and 21 white dwarf-disk dwarf pairs, as well as four triples. Most SLoWPoKES pairs violate the previously defined empirical limits for maximum angular separation or binding energies. However, they are well within the theoretical limits and should prove very useful in putting firm constraints on the maximum size of binary systems and on different formation scenarios. We find a lower limit to the wide binary frequency (WBF) for the mid-K to mid-M spectral types that constitute our sample to be 1.1%. This frequency decreases as a function of Galactic height, indicating a time evolution of the WBF. In addition, the semi-major axes of the SLoWPoKES systems exhibit a distinctly bimodal distribution, with a break at separations around 0.1 pc that is also manifested in the system binding energy. Compared with theoretical predictions for the disruption of

  2. Bounded global Hopf branches for stage-structured differential equations with unimodal feedback

    NASA Astrophysics Data System (ADS)

    Shu, Hongying; Wang, Lin; Wu, Jianhong

    2017-03-01

    We consider a class of stage-structured differential equations with unimodal feedback. By using the time delay as a bifurcation parameter, we show that the number of local Hopf bifurcation values is finite. Furthermore, we analytically prove that these local Hopf bifurcation values are neatly paired, and each pair is jointed by a bounded global Hopf branch. We use the well-known Mackey-Glass equation with a stage structure as an illustrative example to demonstrate that bounded global Hopf branches can induce interesting and rich dynamics. As the delay increases over a finite interval, the stage-structured Mackey-Glass equation exhibits certain symmetric dynamic patterns: the solutions evolve from a stable equilibrium to sustained stable periodic oscillations, to chaotic-like aperiodic oscillations and back to sustained stable periodic oscillations, to a stable equilibrium.

  3. Optical conductivity from pair density waves

    NASA Astrophysics Data System (ADS)

    Dai, Zhehao; Lee, Patrick A.

    2017-01-01

    We present a theory of optical conductivity in systems with finite-momentum Cooper pairs. In contrast to the BCS pairing where ac conductivity is purely imaginary in the clean limit, there is nonzero ac absorption across the superconducting gap for finite-momentum pairing if we break the Galilean symmetry explicitly in the electronic Hamiltonian. Vertex correction is crucial for maintaining the gauge invariance in the mean-field formalism and dramatically changes the optical conductivity in the direction of the pairing momentum. We carried out a self-consistent calculation and gave an explicit formula for optical conductivity in a simple case. This result applies to the Fulde-Ferrell-Larkin-Ovchinnikov state and candidates with pair density waves proposed for high-Tc cuprates. It may help detect pair density waves and determine the pairing gap as well as the direction of the pairing momentum in experiments.

  4. Detection of Majorana Kramers Pairs Using a Quantum Point Contact

    NASA Astrophysics Data System (ADS)

    Li, Jian; Pan, Wei; Bernevig, B. Andrei; Lutchyn, Roman M.

    2016-07-01

    We propose a setup that integrates a quantum point contact (QPC) and a Josephson junction on a quantum spin Hall sample, experimentally realizable in InAs/GaSb quantum wells. The confinement due to both the QPC and the superconductor results in a Kramers pair of Majorana zero-energy bound states when the superconducting phases in the two arms differ by an odd multiple of π across the Josephson junction. We investigate the detection of these Majorana pairs with the integrated QPC, and find a robust switching from normal to Andreev scattering across the edges due to the presence of Majorana Kramers pairs. Such a switching of the current represents a qualitative signature where multiterminal differential conductances oscillate with alternating signs when the external magnetic field is tuned. We show that this qualitative signature is also present in current cross-correlations. Thus, the change of the backscattering current nature affects both conductance and shot noise, the measurement of which offers a significant advantage over quantitative signatures such as conductance quantization in realistic measurements.

  5. Topological defects in extended inflation

    NASA Technical Reports Server (NTRS)

    Copeland, Edmund J.; Kolb, Edward W.; Liddle, Andrew R.

    1990-01-01

    The production of topological defects, especially cosmic strings, in extended inflation models was considered. In extended inflation, the Universe passes through a first-order phase transition via bubble percolation, which naturally allows defects to form at the end of inflation. The correlation length, which determines the number density of the defects, is related to the mean size of bubbles when they collide. This mechanism allows a natural combination of inflation and large scale structure via cosmic strings.

  6. Match-bounded String Rewriting Systems

    NASA Technical Reports Server (NTRS)

    Geser, Alfons; Hofbauer, Dieter; Waldmann, Johannes

    2003-01-01

    We introduce a new class of automated proof methods for the termination of rewriting systems on strings. The basis of all these methods is to show that rewriting preserves regular languages. To this end, letters are annotated with natural numbers, called match heights. If the minimal height of all positions in a redex is h+1 then every position in the reduct will get height h+1. In a match-bounded system, match heights are globally bounded. Using recent results on deleting systems, we prove that rewriting by a match-bounded system preserves regular languages. Hence it is decidable whether a given rewriting system has a given match bound. We also provide a sufficient criterion for the abence of a match-bound. The problem of existence of a match-bound is still open. Match-boundedness for all strings can be used as an automated criterion for termination, for match-bounded systems are terminating. This criterion can be strengthened by requiring match-boundedness only for a restricted set of strings, for instance the set of right hand sides of forward closures.

  7. Who named the quantum defect?

    SciTech Connect

    Rau, A.R.P.; Inokuti, M.

    1997-08-01

    The notion of the quantum defect is important in atomic and molecular spectroscopy and also in unifying spectroscopy with collision theory. In the latter context, the quantum defect may be viewed as an ancestor of the phase shift. However, the origin of the term quantum defect does not seem to be explained in standard textbooks. It occurred in a 1921 paper by Schroedinger, preceding quantum mechanics, yet giving the correct meaning as an index of the short-range interactions with the core of an atom. The authors present the early history of the quantum-defect idea, and sketch its recent developments.

  8. Radar/sonar signal design for bounded Doppler shifts

    NASA Astrophysics Data System (ADS)

    Altes, R. A.

    1982-07-01

    In many detection and estimation problems, Doppler frequency shifts are bounded. For clutter or multipath that is uniformly distributed in range and symmetrically distributed in Doppler shift relative to the signal, detectability of a point target or a communication signal is improved by minimizing the weighted volume of the magnitude-squared autoambiguity function. When clutter Doppler shifts are bounded, this volume is in a strip containing the range axis on the range-Doppler plane. For scattering function estimation, e.g., for weather radar, Doppler flow meters, and distributed target classifiers, it is again relevant to minimize ambiguity volume in a strip. Strip volume is minimized by using a pulse train, but such a signal has unacceptably large range sidelobe for most applications. Other waveforms that have relatively small sidelobe level within a strip on the range-Doppler plane, as well as small ambiguity volume in the strip, are obtained. The waveforms are composed of pulse pairs that are phase modulated with Golay complementary codes.

  9. Existence and consequences of Coulomb pairing of electrons in a solid

    SciTech Connect

    Mahajan, S.M.; Thyagaraja, A.

    1996-11-01

    It is shown from first principles that, in the periodic potential of a crystalline solid, short-range (i.e., screened) binary Coulomb interactions can lead to a two-electron bound state. It is further suggested that these composite bosonic states (charge -2e, and typically spin zero) could mediate an effectively attractive interaction between pairs of conduction electrons close to the Fermi level. This necessarily short range attractive interaction, which is crucially dependent on the band structure of the solid, and is complementary to the phonon-mediated one, may provide a source for the existence and properties of short correlation-length electron pairs (analogous to but distinct from Cooper pairs) needed to understand high temperature superconductivity. Several distinctive and observable characteristics of the proposed pairing scheme are discussed.

  10. Reproducing pairs and the continuous nonstationary Gabor transform on LCA groups

    NASA Astrophysics Data System (ADS)

    Speckbacher, Michael; Balazs, Peter

    2015-10-01

    In this paper we introduce and investigate the concept of reproducing pairs as a generalization of continuous frames. Reproducing pairs yield a bounded analysis and synthesis process while the frame condition can be omitted at both stages. Moreover, we will investigate certain continuous frames (resp. reproducing pairs) on LCA groups, which can be described as a continuous version of nonstationary Gabor systems and state sufficient conditions for these systems to form a continuous frame (resp. reproducing pair). As a byproduct we identify the structure of the frame operator (resp. resolution operator). We will apply our results to systems generated by a unitary action of a subset of the affine Weyl-Heisenberg group in {L}2({{R}}). This setup will also serve as a nontrivial example of a system for which, whereas continuous frames exist, no dual system with the same structure exists even if we drop the frame property.

  11. Studying dissociative electron attachment through formation of heavy-Rydberg ion-pair states

    NASA Astrophysics Data System (ADS)

    Kelley, Michael; Buathong, Sitti; Dunning, F. Barry

    2016-05-01

    Following dissociative electron transfer in collisions between Rydberg atoms and electron-attaching targets, it is possible for the resulting pair of ions to remain electrostatically bound, forming heavy-Rydberg ion-pair states. Precise measurement of the velocity distributions of such ion-pair states provides information concerning the dissociation dynamics of the excited intermediates initially created by electron transfer. Here, electric-field-induced dissociation is used to detect the product ion pairs and observe their velocity distributions. These distributions are analyzed with the aid of a Monte Carlo collision code that models the electron transfer. Measurements with a number of different target species show that through this analysis, dissociation energetics, the branching ratios into different dissociation products, and the lifetimes of the excited intermediates can be examined. Research supported by the Robert A. Welch Foundation.

  12. Homolog pairing and segregation in Drosophila meiosis.

    PubMed

    McKee, B D

    2009-01-01

    Pairing of homologous chromosomes is fundamental to their reliable segregation during meiosis I and thus underlies sexual reproduction. In most eukaryotes homolog pairing is confined to prophase of meiosis I and is accompanied by frequent exchanges, known as crossovers, between homologous chromatids. Crossovers give rise to chiasmata, stable interhomolog connectors that are required for bipolar orientation (orientation to opposite poles) of homologs during meiosis I. Drosophila is unique among model eukaryotes in exhibiting regular homolog pairing in mitotic as well as meiotic cells. I review the results of recent molecular studies of pairing in both mitosis and meiosis in Drosophila. These studies show that homolog pairing is continuous between pre-meiotic mitosis and meiosis but that pairing frequencies and patterns are altered during the mitotic-meiotic transition. They also show that, with the exception of X-Y pairing in male meiosis, which is mediated specifically by the 240-bp rDNA spacer repeats, chromosome pairing is not restricted to specific sites in either mitosis or meiosis. Instead, virtually all chromosome regions, both heterochromatic and euchromatic, exhibit autonomous pairing capacity. Mutations that reduce the frequencies of both mitotic and meiotic pairing have been recently described, but no mutations that abolish pairing completely have been discovered, and the genetic control of pairing in Drosophila remains to be elucidated.

  13. Bounds on dark matter in solar orbit

    SciTech Connect

    Anderson, J.D.; Lau, E.L.; Taylor, A.H.; Dicus, D.A.; Teplitz, D.C.; Texas Univ., Austin; Maryland Univ., College Park )

    1989-07-01

    The possibility is considered that a spherical distribution of dark matter (DM), matter not visible with current instruments, is trapped in the sun's gravitational field. Bounds are placed from the motion of Uranus and Neptune, on the amount of DM that could be so trapped within the radius of those planets' orbits, as follows: from the Voyager 2, Uranus-flyby data new, more accurate ephemeris values are generated. Trapped DM mass is bounded by noting that such a distribution would increase the effective mass of the sun as seen by the outer planets and by using the new ephemeris values to bound such an increase. 34 refs.

  14. Lightweight Distance Bounding Protocol against Relay Attacks

    NASA Astrophysics Data System (ADS)

    Kim, Jin Seok; Cho, Kookrae; Yum, Dae Hyun; Hong, Sung Je; Lee, Pil Joong

    Traditional authentication protocols are based on cryptographic techniques to achieve identity verification. Distance bounding protocols are an enhanced type of authentication protocol built upon both signal traversal time measurement and cryptographic techniques to accomplish distance verification as well as identity verification. A distance bounding protocol is usually designed to defend against the relay attack and the distance fraud attack. As there are applications to which the distance fraud attack is not a serious threat, we propose a streamlined distance bounding protocol that focuses on the relay attack. The proposed protocol is more efficient than previous protocols and has a low false acceptance rate under the relay attack.

  15. Pattern Search Algorithms for Bound Constrained Minimization

    NASA Technical Reports Server (NTRS)

    Lewis, Robert Michael; Torczon, Virginia

    1996-01-01

    We present a convergence theory for pattern search methods for solving bound constrained nonlinear programs. The analysis relies on the abstract structure of pattern search methods and an understanding of how the pattern interacts with the bound constraints. This analysis makes it possible to develop pattern search methods for bound constrained problems while only slightly restricting the flexibility present in pattern search methods for unconstrained problems. We prove global convergence despite the fact that pattern search methods do not have explicit information concerning the gradient and its projection onto the feasible region and consequently are unable to enforce explicitly a notion of sufficient feasible decrease.

  16. Sound Velocity Bound and Neutron Stars

    SciTech Connect

    Bedaque, Paulo; Steiner, Andrew W.

    2015-01-21

    A conjecture that the velocity of sound in any medium is smaller than the velocity of light in vacuum divided by sqrt(3). Simple arguments support this bound in nonrelativistic and/or weakly coupled theories. Moreover, the bound has been demonstrated in several classes of strongly coupled theories with gravity duals and is saturated only in conformal theories. Here, we point out that the existence of neutron stars with masses around two solar masses combined with the knowledge of the equation of state of hadronic matter at low densities is in strong tension with this bound.

  17. Excitation spectra and wave functions of quasiparticle bound states in bilayer Rashba superconductors

    NASA Astrophysics Data System (ADS)

    Higashi, Yoichi; Nagai, Yuki; Yoshida, Tomohiro; Kato, Masaru; Yanase, Youichi

    2015-11-01

    We study the excitation spectra and the wave functions of quasiparticle bound states at a vortex and an edge in bilayer Rashba superconductors under a magnetic field. In particular, we focus on the quasiparticle states at the zero energy in the pair-density wave state in a topologically non-trivial phase. We numerically demonstrate that the quasiparticle wave functions with zero energy are localized at both the edge and the vortex core if the magnetic field exceeds the critical value.

  18. A Transformer Coupling Method for Imaging Defects in Concentrically Arranged Steel Tubes

    SciTech Connect

    Miller, G.; Hussin, H.; Fernandes, B.; Zaid, M.; Gaydecki, P.; El-Madaani, F.

    2006-03-06

    This paper describes the development of a system that uses a transformer coupling method for imaging defects in the outer tube of a concentric steel tube pair. Transformer coupling is employed where a receiver is mounted opposite to the transmitter. Magnetic field coupling is used, in which the field propagates through the inner steel tube towards the outer steel tube. Defects in the outer section distort the field and the change is detected by the receiver.

  19. Nitrogen-related point defect in 4H and 6H SiC

    NASA Astrophysics Data System (ADS)

    Zvanut, M. E.; van Tol, J.

    2007-12-01

    A nitrogen-related pair defect is studied as a function of doping density in 4H and 6H SiC. Electron paramagnetic resonance measurements verify that one nucleus in the pair is nitrogen, but the second part of the pair remains uncertain. The pair concentration varies monotonically with nitrogen concentration in samples with doping density 10 18-10 16 cm -3 and the boron concentration is an order of magnitude less than that of nitrogen. The pair center is not observed in the dark or under ultraviolet illumination when the nitrogen and boron concentrations are similar. We conclude that the pair is generated in all nitrogen-doped samples, but like the isolated nitrogen impurity, may be compensated by boron.

  20. Localized states and their stability in an anharmonic medium with a nonlinear defect

    SciTech Connect

    Gerasimchuk, I. V.

    2015-10-15

    A comprehensive analysis of soliton states localized near a plane defect (a defect layer) possessing nonlinear properties is carried out within a quasiclassical approach for different signs of nonlinearity of the medium and different characters of interaction of elementary excitations of the medium with the defect. A quantum interpretation is given to these nonlinear localized modes as a bound state of a large number of elementary excitations. The domains of existence of such states are determined, and their properties are analyzed as a function of the character of interaction of elementary excitations between each other and with the defect. A full analysis of the stability of all the localized states with respect to small perturbations of amplitude and phase is carried out analytically, and the frequency of small oscillations of the state localized on the defect is determined.

  1. Finding Bounded Rational Equilibria. Part 2; Alternative Lagrangians and Uncountable Move Spaces

    NASA Technical Reports Server (NTRS)

    Wolpert, David H.

    2004-01-01

    A long-running difficulty with conventional game theory has been how to modify it to accommodate the bounded rationality characterizing all real-world players. A recurring issue in statistical physics is how best to approximate joint probability distributions with decoupled (and therefore far more tractable) distributions. It has recently been shown that the same information theoretic mathematical structure, known as Probability Collectives (PC) underlies both issues. This relationship between statistical physics and game theory allows techniques and insights &om the one field to be applied to the other. In particular, PC provides a formal model-independent definition of the degree of rationality of a player and of bounded rationality equilibria. This pair of papers extends previous work on PC by introducing new computational approaches to effectively find bounded rationality equilibria of common-interest (team) games.

  2. A neural network for bounded linear programming

    SciTech Connect

    Culioli, J.C.; Protopopescu, V.; Britton, C.; Ericson, N. )

    1989-01-01

    The purpose of this paper is to describe a neural network implementation of an algorithm recently designed at ORNL to solve the Transportation and the Assignment Problems, and, more generally, any explicitly bounded linear program. 9 refs.

  3. Family of nonlocal bound entangled states

    NASA Astrophysics Data System (ADS)

    Yu, Sixia; Oh, C. H.

    2017-03-01

    Bound entanglement, being entangled yet not distillable, is essential to our understanding of the relations between nonlocality and entanglement besides its applications in certain quantum information tasks. Recently, bound entangled states that violate a Bell inequality have been constructed for a two-qutrit system, disproving a conjecture by Peres that bound entanglement is local. Here we construct this kind of nonlocal bound entangled state for all finite dimensions larger than two, making possible their experimental demonstration in most general systems. We propose a Bell inequality, based on a Hardy-type argument for nonlocality, and a steering inequality to identify their nonlocality. We also provide a family of entanglement witnesses to detect their entanglement beyond the Bell inequality and the steering inequality.

  4. Molecular Andreev bound states and Majorana modes in a double dot system

    NASA Astrophysics Data System (ADS)

    Vernek, Edson; Silva, Joelson F.

    Nanostructured systems such as quantum dots (QD) connected to superconductors has attracted a lot of attention in the recent years. One of the well known phenomena in such a system is the formation of a pair of bound called Andreev bound states (ABS). Recently, it have been shown that when a QD is coupled to a topological superconductor wire, a Majorana bound state (MBS) leaks from the end of the wire into the dot. The character of these bound states is much reacher in structures like molecules and is far from being completely understood. In this work we study a system composed by a two inter-connected QDs in which one of then is coupled to a normal superconductor and to a normal lead while the other is coupled to a topological superconductor and to a distinct normal metallic lead. We show that in the atomic limit (for small interdot coupling), one of the dot has a pair of ABS whereas the other has a single a MBS. More interestingly, in the molecular regime (large inter-dot coupling) we observe a localized Majorana mode coexisting with a delocalized molecular ABS. We would like to thank financial support from the Brazilian agencies CNPq, CAPES and FAPEMIG.

  5. Bound states in the Higgs model

    NASA Astrophysics Data System (ADS)

    di Leo, Leo; Darewych, Jurij W.

    1994-02-01

    We derive relativistic wave equations for the bound states of two Higgs bosons within the Higgs sector of the minimal standard model. The variational method and the Hamiltonian formalism of QFT are used to obtain the equations using a simple ||hh>+||hhh> Fock-space ansatz. We present approximate solutions of these equations for a range of Higgs boson masses, and explore the parameter space which corresponds to the existence of two-Higgs-boson bound states.

  6. Performance bound for real OTEC heat engines

    SciTech Connect

    Wu, C.

    1987-01-01

    Maximum power and efficiency at the maximum power of an irreversible OTEC heat engine are treated. When time is explicitly considered in the energy exchanges between the heat engine and its surroundings, it is found that there is a bound on the efficiency of the real OTEC heat engine at the maximum power condition. This bound can guide the evaluation of existing OTEC systems or influence design of future OTEC heat engines.

  7. Elastic scattering with weakly bound projectiles

    SciTech Connect

    Figueira, J. M.; Abriola, D.; Arazi, A.; Capurro, O. A.; Marti, G. V.; Martinez Heinmann, D.; Pacheco, A. J.; Testoni, J. E.; Barbara, E. de; Fernandez Niello, J. O.; Padron, I.; Gomes, P. R. S.; Lubian, J.

    2007-02-12

    Possible effects of the break-up channel on the elastic scattering threshold anomaly has been investigated. We used the weakly bound 6,7Li nuclei, which is known to undergo break-up, as projectiles in order to study the elastic scattering on a 27Al target. In this contribution we present preliminary results of these experiments, which were analyzed in terms of the Optical Model and compared with other elastic scattering data using weakly bound nuclei as projectile.

  8. Point defect states in Sb-doped germanium

    SciTech Connect

    Patel, Neil S. Monmeyran, Corentin; Agarwal, Anuradha; Kimerling, Lionel C.

    2015-10-21

    Defect states in n-type Sb-doped germanium were investigated by deep-level transient spectroscopy. Cobalt-60 gamma rays were used to generate isolated vacancies and interstitials which diffuse and react with impurities in the material to form four defect states (E{sub 37}, E{sub 30}, E{sub 22}, and E{sub 21}) in the upper half of the bandgap. Irradiations at 77 K and 300 K as well as isothermal anneals were performed to characterize the relationships between the four observable defects. E{sub 37} is assigned to the Sb donor-vacancy associate (E-center) and is the only vacancy containing defect giving an estimate of 2 × 10{sup 11 }cm{sup −3} Mrad{sup −1} for the uncorrelated vacancy-interstitial pair introduction rate. The remaining three defect states are interstitial associates and transform among one another. Conversion ratios between E{sub 22}, E{sub 21}, and E{sub 30} indicate that E{sub 22} likely contains two interstitials.

  9. Facts about Ventricular Septal Defect

    MedlinePlus

    ... Living With Heart Defects Data & Statistics Tracking & Research Articles & Key Findings Free Materials Multimedia and Tools Links to Other Websites Information For... Media Policy Makers Facts about Ventricular Septal Defect Language: English Español (Spanish) Recommend on Facebook Tweet Share Compartir ...

  10. Congenital Heart Defects (For Parents)

    MedlinePlus

    ... of the heart or its surrounding structures, include: Aortic Stenosis In aortic stenosis, the aortic valve is stiffened and has a narrowed opening. ... actually a combination of four heart defects: pulmonary stenosis; a thickened ... septal defect); and an aorta that can receive blood from both the left ...

  11. Holographic Chern-Simons defects

    DOE PAGES

    Fujita, Mitsutoshi; Melby-Thompson, Charles M.; Meyer, René; ...

    2016-06-28

    Here, we study SU(N ) Yang-Mills-Chern-Simons theory in the presence of defects that shift the Chern-Simons level from a holographic point of view by embedding the system in string theory. The model is a D3-D7 system in Type IIB string theory, whose gravity dual is given by the AdS soliton background with probe D7 branes attaching to the AdS boundary along the defects. We holographically renormalize the free energy of the defect system with sources, from which we obtain the correlation functions for certain operators naturally associated to these defects. We find interesting phase transitions when the separation of themore » defects as well as the temperature are varied. We also discuss some implications for the Fractional Quantum Hall Effect and for 2-dimensional QCD.« less

  12. Global topological k-defects

    SciTech Connect

    Babichev, E.

    2006-10-15

    We consider global topological defects in symmetry-breaking models with a noncanonical kinetic term. Apart from a mass parameter entering the potential, one additional dimensional parameter arises in such models - a kinetic mass. The properties of defects in these models are quite different from standard global domain walls, vortices, and monopoles, if their kinetic mass scale is smaller than their symmetry-breaking scale. In particular, depending on the concrete form of the kinetic term, the typical size of such a defect can be either much larger or much smaller than the size of a standard defect with the same potential term. The characteristic mass of a nonstandard defect, which might have been formed during a phase transition in the early universe, depends on both the temperature of a phase transition and the kinetic mass.

  13. Holographic Chern-Simons defects

    NASA Astrophysics Data System (ADS)

    Fujita, Mitsutoshi; Melby-Thompson, Charles M.; Meyer, René; Sugimoto, Shigeki

    2016-06-01

    We study SU( N ) Yang-Mills-Chern-Simons theory in the presence of defects that shift the Chern-Simons level from a holographic point of view by embedding the system in string theory. The model is a D3-D7 system in Type IIB string theory, whose gravity dual is given by the AdS soliton background with probe D7 branes attaching to the AdS boundary along the defects. We holographically renormalize the free energy of the defect system with sources, from which we obtain the correlation functions for certain operators naturally associated to these defects. We find interesting phase transitions when the separation of the defects as well as the temperature are varied. We also discuss some implications for the Fractional Quantum Hall Effect and for 2-dimensional QCD.

  14. Holographic Chern-Simons defects

    SciTech Connect

    Fujita, Mitsutoshi; Melby-Thompson, Charles M.; Meyer, René; Sugimoto, Shigeki

    2016-06-28

    Here, we study SU(N ) Yang-Mills-Chern-Simons theory in the presence of defects that shift the Chern-Simons level from a holographic point of view by embedding the system in string theory. The model is a D3-D7 system in Type IIB string theory, whose gravity dual is given by the AdS soliton background with probe D7 branes attaching to the AdS boundary along the defects. We holographically renormalize the free energy of the defect system with sources, from which we obtain the correlation functions for certain operators naturally associated to these defects. We find interesting phase transitions when the separation of the defects as well as the temperature are varied. We also discuss some implications for the Fractional Quantum Hall Effect and for 2-dimensional QCD.

  15. Toward Intelligent Software Defect Detection

    NASA Technical Reports Server (NTRS)

    Benson, Markland J.

    2011-01-01

    Source code level software defect detection has gone from state of the art to a software engineering best practice. Automated code analysis tools streamline many of the aspects of formal code inspections but have the drawback of being difficult to construct and either prone to false positives or severely limited in the set of defects that can be detected. Machine learning technology provides the promise of learning software defects by example, easing construction of detectors and broadening the range of defects that can be found. Pinpointing software defects with the same level of granularity as prominent source code analysis tools distinguishes this research from past efforts, which focused on analyzing software engineering metrics data with granularity limited to that of a particular function rather than a line of code.

  16. Antisite defects at oxide interfaces

    NASA Astrophysics Data System (ADS)

    Chen, Hanghui; Millis, Andrew

    We use ab initio calculations to estimate formation energies of cation (transition metal) antisite defects at oxide interfaces and to understand the basic physical effects that drive or suppress the formation of these defects. We find that antisite defects are favored in systems with substantial charge transfer across the interface, while Jahn-Teller distortions and itinerant ferromagnetism can prevent antisite defects and help stabilize atomically sharp interfaces. Our results enable identification of classes of systems that are more and less susceptible to the formation of antisite defects and motivate a range of experimental studies and further theoretical calculations to further explicate the oxide interface systems. This research was supported by National Science Foundation under Grant No. DMR-1120296 (H. Chen) and DOE-ER-046169 (A. J. Millis).

  17. Displacement cascades and defects annealing in tungsten, Part I: Defect database from molecular dynamics simulations

    SciTech Connect

    Setyawan, Wahyu; Nandipati, Giridhar; Roche, Kenneth J.; Heinisch, Howard L.; Wirth, Brian D.; Kurtz, Richard J.

    2015-07-01

    Molecular dynamics simulations have been used to generate a comprehensive database of surviving defects due to displacement cascades in bulk tungsten. Twenty-one data points of primary knock-on atom (PKA) energies ranging from 100 eV (sub-threshold energy) to 100 keV (~780×Ed, where Ed = 128 eV is the average displacement threshold energy) have been completed at 300 K, 1025 K and 2050 K. Within this range of PKA energies, two regimes of power-law energy-dependence of the defect production are observed. A distinct power-law exponent characterizes the number of Frenkel pairs produced within each regime. The two regimes intersect at a transition energy which occurs at approximately 250×Ed. The transition energy also marks the onset of the formation of large self-interstitial atom (SIA) clusters (size 14 or more). The observed defect clustering behavior is asymmetric, with SIA clustering increasing with temperature, while the vacancy clustering decreases. This asymmetry increases with temperature such that at 2050 K (~0.5Tm) practically no large vacancy clusters are formed, meanwhile large SIA clusters appear in all simulations. The implication of such asymmetry on the long-term defect survival and damage accumulation is discussed. In addition, <100> {110} SIA loops are observed to form directly in the highest energy cascades, while vacancy <100> loops are observed to form at the lowest temperature and highest PKA energies, although the appearance of both the vacancy and SIA loops with Burgers vector of <100> type is relatively rare.

  18. Holographic Experiments on Defects

    NASA Astrophysics Data System (ADS)

    Wapler, Matthias C.

    Using the AdS/CFT correspondence, we study the anisotropic charge transport properties of both supersymmetric and nonsupersymmetric matter fields on (2+1)-dimensional defects coupled to a (3+1)-dimensional { N} = 4 SYM "heat bath." We focus on the cases of a finite external background magnetic field, finite net charge density and finite mass and their combinations. In this context, we also discuss the limitations due to operator mixing that appears in a few situations and that we ignore in our analysis. At high frequencies, we discover a spectrum of quasiparticle resonances due to the magnetic field and finite density and at small frequencies, we perform a Drude-like expansion around the DC limit. Both of these regimes display many generic features and some features that we attribute to strong coupling, such as a minimum DC conductivity and an unusual behavior of the "cyclotron" and plasmon frequencies, which become related to the resonances found in the conformal case in an earlier paper. We further study the hydrodynamic regime and the relaxation properties, from which the system displays a set of different possible transitions to the collisionless regime. The mass dependence can be cast in two regimes: a generic relativistic behavior dominated by the UV and a nonlinear hydrodynamic behavior dominated by the IR. In the massless case, we furthermore extend earlier results from the literature to find an interesting selfduality under a transformation of the conductivity and the exchange of density and magnetic field.

  19. Theory of surface Andreev bound states and tunneling spectroscopy in three-dimensional chiral superconductors

    NASA Astrophysics Data System (ADS)

    Tamura, Shun; Kobayashi, Shingo; Bo, Lu; Tanaka, Yukio

    2017-03-01

    We study the surface Andreev bound states (SABSs) and quasiparticle tunneling spectroscopy of three-dimensional (3D) chiral superconductors by changing their surface (interface) misorientation angles. We obtain an analytical formula for the SABS energy dispersion of a general pair potential, for which an original 4 ×4 BdG Hamiltonian can be reduced to two 2 ×2 blocks. The resulting SABS for 3D chiral superconductors with a pair potential given by kz(kx+i ky) ν (ν =1 ,2 ) has a complicated energy dispersion owing to the coexistence of both point and line nodes. We focus on the tunneling spectroscopy of this pairing in the presence of an applied magnetic field, which induces a Doppler shift in the quasiparticle spectra. In contrast to the previously known Doppler effect in unconventional superconductors, a zero-bias conductance dip can change into a zero-bias conductance peak owing to an external magnetic field. We also study SABSs and tunneling spectroscopy for possible pairing symmetries of UPt3. For this purpose, we extend a standard formula for the tunneling conductance of unconventional superconductor junctions to treat spin-triplet nonunitary pairings. Magnetotunneling spectroscopy, i.e., tunneling spectroscopy in the presence of a magnetic field, can serve as a guide to determine the pairing symmetry of this material.

  20. Differential refractive index sensor based on photonic molecules and defect cavities.

    PubMed

    Andueza, Ángel; Pérez-Conde, Jesús; Sevilla, Joaquín

    2016-08-08

    We present a novel differential refractive index sensor prototype based on a matrix of photonic molecules (PM) of soda-lime glass cylinders (εc = 4.5) and two defect cavities. The measured and simulated spectra in the microwave range (8-12 GHz) show a wide photonic stop band with two localized states: the reference state, bound to a decagonal ring of cylinders and the sensing state, bound to the defect cavities. The defect mode is very sensitive to the permittivity of the material inserted in the cavity while the state in the PM remains unperturbed. We find that the response of the sensor is linear. These results can be extrapolated to the visible range due to scale invariance of Maxwell equations.

  1. Investigations of EPR parameters for the trigonal Ti3+-Ti3+ pair in beryl crystal.

    PubMed

    Wang, Fang; Zheng, Wen-Chen

    2007-08-01

    By using the complete diagonalization of energy matrix of 3d1 ions in trigonal symmetry, the EPR parameters (g factors g( parallel), g( perpendicular) and zero-field splitting D) of the trigonal Ti3+-Ti3+ pair in beryl crystal are calculated. In the calculations, the exchange interaction in the Ti3+-Ti3+ pair is taken as the perturbation and the local trigonal distortion in the defect center is considered. The results (which are in agreement with the experimental values) are discussed.

  2. Slow light enhanced correlated photon pair generation in photonic-crystal coupled-resonator optical waveguides.

    PubMed

    Matsuda, Nobuyuki; Takesue, Hiroki; Shimizu, Kaoru; Tokura, Yasuhiro; Kuramochi, Eiichi; Notomi, Masaya

    2013-04-08

    We demonstrate the generation of quantum-correlated photon pairs from a Si photonic-crystal coupled-resonator optical waveguide. A slow-light supermode realized by the collective resonance of high-Q and small-mode-volume photonic-crystal cavities successfully enhanced the efficiency of the spontaneous four-wave mixing process. The generation rate of photon pairs was improved by two orders of magnitude compared with that of a photonic-crystal line defect waveguide without a slow-light effect.

  3. Report on Pairing-based Cryptography

    PubMed Central

    Moody, Dustin; Peralta, Rene; Perlner, Ray; Regenscheid, Andrew; Roginsky, Allen; Chen, Lily

    2015-01-01

    This report summarizes study results on pairing-based cryptography. The main purpose of the study is to form NIST’s position on standardizing and recommending pairing-based cryptography schemes currently published in research literature and standardized in other standard bodies. The report reviews the mathematical background of pairings. This includes topics such as pairing-friendly elliptic curves and how to compute various pairings. It includes a brief introduction to existing identity-based encryption (IBE) schemes and other cryptographic schemes using pairing technology. The report provides a complete study of the current status of standard activities on pairing-based cryptographic schemes. It explores different application scenarios for pairing-based cryptography schemes. As an important aspect of adopting pairing-based schemes, the report also considers the challenges inherent in validation testing of cryptographic algorithms and modules. Based on the study, the report suggests an approach for including pairing-based cryptography schemes in the NIST cryptographic toolkit. The report also outlines several questions that will require further study if this approach is followed. PMID:26958435

  4. FIR statistics of paired galaxies

    NASA Technical Reports Server (NTRS)

    Sulentic, Jack W.

    1990-01-01

    Much progress has been made in understanding the effects of interaction on galaxies (see reviews in this volume by Heckman and Kennicutt). Evidence for enhanced emission from galaxies in pairs first emerged in the radio (Sulentic 1976) and optical (Larson and Tinsley 1978) domains. Results in the far infrared (FIR) lagged behind until the advent of the Infrared Astronomy Satellite (IRAS). The last five years have seen numerous FIR studies of optical and IR selected samples of interacting galaxies (e.g., Cutri and McAlary 1985; Joseph and Wright 1985; Kennicutt et al. 1987; Haynes and Herter 1988). Despite all of this work, there are still contradictory ideas about the level and, even, the reality of an FIR enhancement in interacting galaxies. Much of the confusion originates in differences between the galaxy samples that were studied (i.e., optical morphology and redshift coverage). Here, the authors report on a study of the FIR detection properties for a large sample of interacting galaxies and a matching control sample. They focus on the distance independent detection fraction (DF) statistics of the sample. The results prove useful in interpreting the previously published work. A clarification of the phenomenology provides valuable clues about the physics of the FIR enhancement in galaxies.

  5. Pulsational Pair-instability Supernovae

    NASA Astrophysics Data System (ADS)

    Woosley, S. E.

    2017-02-01

    The final evolution of stars in the mass range 70–140 {\\text{}}{M}ȯ is explored. Depending upon their mass loss history and rotation rates, these stars will end their lives as pulsational pair-instability supernovae (PPISN) producing a great variety of observational transients with total durations ranging from weeks to millennia and luminosities from 1041 to over 1044 erg s‑1. No nonrotating model radiates more than 5× {10}50 erg of light or has a kinetic energy exceeding 5× {10}51 erg, but greater energies are possible, in principle, in magnetar-powered explosions, which are explored. Many events resemble SNe Ibn, SNe Icn, and SNe IIn, and some potential observational counterparts are mentioned. Some PPISN can exist in a dormant state for extended periods, producing explosions millennia after their first violent pulse. These dormant supernovae contain bright Wolf–Rayet stars, possibly embedded in bright X-ray and radio sources. The relevance of PPISN to supernova impostors like Eta Carinae, to superluminous supernovae, and to sources of gravitational radiation is discussed. No black holes between 52 and 133 {\\text{}}{M}ȯ are expected from stellar evolution in close binaries.

  6. Error bounds from extra precise iterative refinement

    SciTech Connect

    Demmel, James; Hida, Yozo; Kahan, William; Li, Xiaoye S.; Mukherjee, Soni; Riedy, E. Jason

    2005-02-07

    We present the design and testing of an algorithm for iterative refinement of the solution of linear equations, where the residual is computed with extra precision. This algorithm was originally proposed in the 1960s [6, 22] as a means to compute very accurate solutions to all but the most ill-conditioned linear systems of equations. However two obstacles have until now prevented its adoption in standard subroutine libraries like LAPACK: (1) There was no standard way to access the higher precision arithmetic needed to compute residuals, and (2) it was unclear how to compute a reliable error bound for the computed solution. The completion of the new BLAS Technical Forum Standard [5] has recently removed the first obstacle. To overcome the second obstacle, we show how a single application of iterative refinement can be used to compute an error bound in any norm at small cost, and use this to compute both an error bound in the usual infinity norm, and a componentwise relative error bound. We report extensive test results on over 6.2 million matrices of dimension 5, 10, 100, and 1000. As long as a normwise (resp. componentwise) condition number computed by the algorithm is less than 1/max{l_brace}10,{radical}n{r_brace} {var_epsilon}{sub w}, the computed normwise (resp. componentwise) error bound is at most 2 max{l_brace}10,{radical}n{r_brace} {center_dot} {var_epsilon}{sub w}, and indeed bounds the true error. Here, n is the matrix dimension and w is single precision roundoff error. For worse conditioned problems, we get similarly small correct error bounds in over 89.4% of cases.

  7. Energetics of intrinsic point defects in ZrSiO{sub 4}

    SciTech Connect

    Pruneda, J.M.; Artacho, Emilio

    2005-03-01

    Using first principles calculations we have studied the formation energies, electron and hole affinities, and electronic levels of intrinsic point defects in zircon. The atomic structures of charged interstitials, vacancies, Frenkel pairs, and antisite defects are obtained. The limit of high concentration of point defects, relevant for the use of this material in nuclear waste immobilization, was studied with a variable lattice relaxation that can simulate the swelling induced by radiation damage. The limit of low concentration of defects is simulated with larger cells and fixed lattice parameters. Using known band offset values at the interface of zircon with silicon, we analyze the foreseeable effect of the defects on the electronic properties of zircon used as gate in metal-oxide-semiconductor devices.

  8. Model of defect reactions and the influence of clustering in pulse-neutron-irradiated Si

    SciTech Connect

    Myers, S. M.; Cooper, P. J.; Wampler, W. R.

    2008-08-15

    Transient reactions among irradiation defects, dopants, impurities, and carriers in pulse-neutron-irradiated Si were modeled taking into account the clustering of the primal defects in recoil cascades. Continuum equations describing the diffusion, field drift, and reactions of relevant species were numerically solved for a submicrometer spherical volume, within which the starting radial distributions of defects could be varied in accord with the degree of clustering. The radial profiles corresponding to neutron irradiation were chosen through pair-correlation-function analysis of vacancy and interstitial distributions obtained from the binary-collision code MARLOWE, using a spectrum of primary recoil energies computed for a fast-burst fission reactor. Model predictions of transient behavior were compared with a variety of experimental results from irradiated bulk Si, solar cells, and bipolar-junction transistors. The influence of defect clustering during neutron bombardment was further distinguished through contrast with electron irradiation, where the primal point defects are more uniformly dispersed.

  9. Upper bounds on superpartner masses from upper bounds on the Higgs boson mass.

    PubMed

    Cabrera, M E; Casas, J A; Delgado, A

    2012-01-13

    The LHC is putting bounds on the Higgs boson mass. In this Letter we use those bounds to constrain the minimal supersymmetric standard model (MSSM) parameter space using the fact that, in supersymmetry, the Higgs mass is a function of the masses of sparticles, and therefore an upper bound on the Higgs mass translates into an upper bound for the masses for superpartners. We show that, although current bounds do not constrain the MSSM parameter space from above, once the Higgs mass bound improves big regions of this parameter space will be excluded, putting upper bounds on supersymmetry (SUSY) masses. On the other hand, for the case of split-SUSY we show that, for moderate or large tanβ, the present bounds on the Higgs mass imply that the common mass for scalars cannot be greater than 10(11)  GeV. We show how these bounds will evolve as LHC continues to improve the limits on the Higgs mass.

  10. Variational derivation of equation for generalized pair correlation function

    NASA Technical Reports Server (NTRS)

    Malik, F. Bary

    1992-01-01

    The wavefunction of a system is explicitly written down in a fully anti-symmetric way between a fermion pair and a medium, and the equations for each one of them are derived from the variation of total energy for bound systems and by forming appropriate scalar products for continuum states. High-energy particles, such as protons, electrons, and nuclei impinging upon spacecraft, produce secondary radiations. In order to protect the internal environment of spacecraft from these radiations, their intensities are determined in many instances theoretically, and an appropriate program has been developed in the High Energy Science Branch. The purpose of this research is to investigate the problem of indistinguishability of an incident projectile with one of the same in a target.

  11. Defect studies in low-temperature-grown GaAs

    SciTech Connect

    Bliss, D.E.

    1992-11-01

    High content of excess As is incorporated in GaAs grown by low-temperature molecular-beam-epitaxy (LTMBE). The excess As exists primarily as As antisite defects AsGa and a lesser extent of gallium vacancies V{sub Ga}. The neutral AsGa-related defects were measured by infrared absorption at 1{mu}m. Gallium vacancies, V{sub Ga}, was investigated by slow positron annihilation. Dependence of defect contents on doping was studied by Si and Be dopants. No free carriers are generated by n-type or p-type doping up to 10{sup 19} cm{sup {minus}3} Si or Be. Raman data indicate Be occupies Ga substitutional sites but Si atom is not substitutional. Si induces more As{sub Ga} in the layer. As As{sub Ga} increases, photoquenchable As{sub Ga} decreases. Fraction of photoquenchable defects correlates to defects within 3 nearest neighbor separations disrupting the metastability. Annealing reduces neutral As{sub Ga} content around 500C, similar to irradiation damaged and plastically deformed Ga{sub As}, as opposed to bulk grown GaAs in which As{sub Ga}-related defects are stable up to 1100C. The lower temperature defect removal is due to V{sub Ga} enhanced diffusion of As{sub Ga} to As precipitates. The supersaturated V{sub GA} and also decreases during annealing. Annealing kinetics for As{sub Ga}-related defects gives 2.0 {plus_minus} 0.3 eV and 1.5 {plus_minus} 0.3 eV migration enthalpies for the As{sub Ga} and V{sub Ga}. This represents the difference between Ga and As atoms hopping into the vacancy. The non-photoquenchable As{sub Ga}-related defects anneal with an activation energy of 1.1 {plus_minus} 0.3eV. Be acceptors can be activated by 800C annealing. Temperature difference between defect annealing and Be activation formation of As{sub Ga}-Be{sub Ga} pairs. Si donors can only be partially activated.

  12. Defect studies in low-temperature-grown GaAs

    SciTech Connect

    Bliss, D.E.

    1992-11-01

    High content of excess As is incorporated in GaAs grown by low-temperature molecular-beam-epitaxy (LTMBE). The excess As exists primarily as As antisite defects AsGa and a lesser extent of gallium vacancies V[sub Ga]. The neutral AsGa-related defects were measured by infrared absorption at 1[mu]m. Gallium vacancies, V[sub Ga], was investigated by slow positron annihilation. Dependence of defect contents on doping was studied by Si and Be dopants. No free carriers are generated by n-type or p-type doping up to 10[sup 19] cm[sup [minus]3] Si or Be. Raman data indicate Be occupies Ga substitutional sites but Si atom is not substitutional. Si induces more As[sub Ga] in the layer. As As[sub Ga] increases, photoquenchable As[sub Ga] decreases. Fraction of photoquenchable defects correlates to defects within 3 nearest neighbor separations disrupting the metastability. Annealing reduces neutral As[sub Ga] content around 500C, similar to irradiation damaged and plastically deformed Ga[sub As], as opposed to bulk grown GaAs in which As[sub Ga]-related defects are stable up to 1100C. The lower temperature defect removal is due to V[sub Ga] enhanced diffusion of As[sub Ga] to As precipitates. The supersaturated V[sub GA] and also decreases during annealing. Annealing kinetics for As[sub Ga]-related defects gives 2.0 [plus minus] 0.3 eV and 1.5 [plus minus] 0.3 eV migration enthalpies for the As[sub Ga] and V[sub Ga]. This represents the difference between Ga and As atoms hopping into the vacancy. The non-photoquenchable As[sub Ga]-related defects anneal with an activation energy of 1.1 [plus minus] 0.3eV. Be acceptors can be activated by 800C annealing. Temperature difference between defect annealing and Be activation formation of As[sub Ga]-Be[sub Ga] pairs. Si donors can only be partially activated.

  13. Biomaterials in periodontal osseous defects

    PubMed Central

    Lal, Nand; Dixit, Jaya

    2012-01-01

    Introduction Osseous defects in periodontal diseases require osseous grafts and guided tissue regeneration (GTR) using barrier membranes. The present study was undertaken with the objectives to clinically evaluate the osteogenic potential of hydroxyapatite (HA), cissus quadrangularis (CQ), and oxidized cellulose membrane (OCM) and compare with normal bone healing. Materials and Methods Twenty subjects with periodontitis in the age group ranging from 20 years to 40 years were selected from our outpatient department on the basis of presence of deep periodontal pockets, clinical probing depth ≥5 mm, vertical osseous defects obvious on radiograph and two- or three-walled involvement seen on surgical exposure. Infrabony defects were randomly divided into four groups on the basis of treatment to be executed, such that each group comprised 5 defects. Group I was control, II received HA, III received CQ and IV received OCM. Probing depth and attachment level were measured at regular months after surgery. Defects were re-exposed using crevicular incisions at 6 months. Results There was gradual reduction in the mean probing pocket depth in all groups, but highly significant in the site treated with HA. Gain in attachment level was higher in sites treated with HA, 3.2 mm at 6 months. Conclusion Hydroxyapatite and OCM showed good reduction in pocket depth, attachment level gain and osseous defect fill. Further study should be conducted by using a combination of HA and OCM in periodontal osseous defects with growth factors and stem cells. PMID:25756030

  14. Secretory Defect and Cytotoxicity

    PubMed Central

    Li, Songhua; Yang, Zhihui; Hu, Jane; Gordon, William C.; Bazan, Nicolas G.; Haas, Arthur L.; Bok, Dean; Jin, Minghao

    2013-01-01

    Interphotoreceptor retinoid-binding protein (IRBP) secreted by photoreceptors plays a pivotal role in photoreceptor survival and function. Recently, a D1080N mutation in IRBP was found in patients with retinitis pigmentosa, a frequent cause of retinal degeneration. The molecular and cellular bases for pathogenicity of the mutation are unknown. Here, we show that the mutation abolishes secretion of IRBP and results in formation of insoluble high molecular weight complexes via disulfide bonds. Co-expression of protein disulfide isomerase A2 that regulates disulfide bond formation or introduction of double Cys-to-Ala substitutions at positions 304 and 1175 in D1080N IRBP promoted secretion of the mutated IRBP. D1080N IRBP was not transported to the Golgi apparatus, but accumulated in the endoplasmic reticulum (ER), bound with the ER-resident chaperone proteins such as BiP, protein disulfide isomerase, and heat shock proteins. Splicing of X-box-binding protein-1 mRNA, expression of activating transcription factor 4 (ATF4), and cleavage of ATF6 were significantly increased in cells expressing D1080N IRBP. Moreover, D1080N IRBP induced up-regulation and nuclear translocation of the C/EBP homologous protein, a proapoptotic transcription factor associated with the unfolded protein response. These results indicate that loss of normal function (nonsecretion) and gain of cytotoxic function (ER stress) are involved in the disease mechanisms of D1080N IRBP. Chemical chaperones and low temperature, which help proper folding of many mutated proteins, significantly rescued secretion of D1080N IRBP, suggesting that misfolding is the molecular basis for pathogenicity of D1080N substitution and that chemical chaperones are therapeutic candidates for the mutation-caused blinding disease. PMID:23486466

  15. Transport-reaction model for defect and carrier behavior within displacement cascades in gallium arsenide

    SciTech Connect

    Wampler, William R.; Myers, Samuel M.

    2014-02-01

    A model is presented for recombination of charge carriers at displacement damage in gallium arsenide, which includes clustering of the defects in atomic displacement cascades produced by neutron or ion irradiation. The carrier recombination model is based on an atomistic description of capture and emission of carriers by the defects with time evolution resulting from the migration and reaction of the defects. The physics and equations on which the model is based are presented, along with details of the numerical methods used for their solution. The model uses a continuum description of diffusion, field-drift and reaction of carriers and defects within a representative spherically symmetric cluster. The initial radial defect profiles within the cluster were chosen through pair-correlation-function analysis of the spatial distribution of defects obtained from the binary-collision code MARLOWE, using recoil energies for fission neutrons. Charging of the defects can produce high electric fields within the cluster which may influence transport and reaction of carriers and defects, and which may enhance carrier recombination through band-to-trap tunneling. Properties of the defects are discussed and values for their parameters are given, many of which were obtained from density functional theory. The model provides a basis for predicting the transient response of III-V heterojunction bipolar transistors to pulsed neutron irradiation.

  16. Microtubule defects & Neurodegeneration.

    PubMed

    Baird, Fiona J; Bennett, Craig L

    2013-12-06

    One of the major challenges facing the long term survival of neurons is their requirement to maintain efficient axonal transport over long distances. In humans as large, long-lived vertebrates, the machinery maintaining neuronal transport must remain efficient despite the slow accumulation of cell damage during aging. Mutations in genes encoding proteins which function in the transport system feature prominently in neurologic disorders. Genes known to cause such disorders and showing traditional Mendelian inheritance have been more readily identified. It has been more difficult, however, to isolate factors underlying the complex genetics contributing to the more common idiopathic forms of neurodegenerative disease. At the heart of neuronal transport is the rail network or scaffolding provided by neuron specific microtubules (MTs). The importance of MT dynamics and stability is underscored by the critical role tau protein plays in MT-associated stabilization versus the dysfunction seen in Alzheimer's disease, frontotemporal dementia and other tauopathies. Another example of the requirement for tight regulation of MT dynamics is the need to maintain balanced levels of post-translational modification of key MT building-blocks such as α-tubulin. Tubulins require extensive polyglutamylation at their carboxyl-terminus as part of a novel post-translational modification mechanism to signal MT growth versus destabilization. Dramatically, knock-out of a gene encoding a deglutamylation family member causes an extremely rapid cell death of Purkinje cells in the ataxic mouse model, pcd. This review will examine a range of neurodegenerative conditions where current molecular understanding points to defects in the stability of MTs and axonal transport to emphasize the central role of MTs in neuron survival.

  17. Ordered pairing in liquid metallic hydrogen

    NASA Technical Reports Server (NTRS)

    Carlsson, A. E.; Ashcroft, N. W.

    1983-01-01

    We study two possible types of pairing involving the protons of a proposed low-temperature liquid phase metallic hydrogen. Electron-proton pairing, which can result in an insulating phase, is investigated by using an approximate solution of an Eliashberg-type equation for the anomalous self-energy. A very low estimate of the transition temperature is obtained by including proton correlations in the effective interaction. For proton-proton pairing, we derive a new proton pair potential based on the Abrikosov wave function. This potential includes the electron-proton interaction to all orders and has a much larger well depth than is obtained with linear screening methods. This suggests the possibility of either a superfluid paired phase analogous to that in He-3, or alternatively a phase with true molecular pairing.

  18. Ensemble treatments of thermal pairing in nuclei

    NASA Astrophysics Data System (ADS)

    Hung, Nguyen Quang; Dang, Nguyen Dinh

    2009-10-01

    A systematic comparison is conducted for pairing properties of finite systems at nonzero temperature as predicted by the exact solutions of the pairing problem embedded in three principal statistical ensembles, namely the grandcanonical ensemble, canonical ensemble and microcanonical ensemble, as well as the unprojected (FTBCS1+SCQRPA) and Lipkin-Nogami projected (FTLN1+SCQRPA) theories that include the quasiparticle number fluctuation and coupling to pair vibrations within the self-consistent quasiparticle random-phase approximation. The numerical calculations are performed for the pairing gap, total energy, heat capacity, entropy, and microcanonical temperature within the doubly-folded equidistant multilevel pairing model. The FTLN1+SCQRPA predictions are found to agree best with the exact grand-canonical results. In general, all approaches clearly show that the superfluid-normal phase transition is smoothed out in finite systems. A novel formula is suggested for extracting the empirical pairing gap in reasonable agreement with the exact canonical results.

  19. Thermalization Time Bounds for Pauli Stabilizer Hamiltonians

    NASA Astrophysics Data System (ADS)

    Temme, Kristan

    2017-03-01

    We prove a general lower bound to the spectral gap of the Davies generator for Hamiltonians that can be written as the sum of commuting Pauli operators. These Hamiltonians, defined on the Hilbert space of N-qubits, serve as one of the most frequently considered candidates for a self-correcting quantum memory. A spectral gap bound on the Davies generator establishes an upper limit on the life time of such a quantum memory and can be used to estimate the time until the system relaxes to thermal equilibrium when brought into contact with a thermal heat bath. The bound can be shown to behave as {λ ≥ O(N^{-1} exp(-2β overline{ɛ}))}, where {overline{ɛ}} is a generalization of the well known energy barrier for logical operators. Particularly in the low temperature regime we expect this bound to provide the correct asymptotic scaling of the gap with the system size up to a factor of N -1. Furthermore, we discuss conditions and provide scenarios where this factor can be removed and a constant lower bound can be proven.

  20. Care and Treatment for Congenital Heart Defects

    MedlinePlus

    ... Physical Activity Recommendations for Heart Health • Tools & Resources Web Booklets on Congenital Heart Defects These online publications ... to you or your child’s defect and concerns. Web Booklet: Adults With Congenital Heart Defects Web Booklet: ...

  1. Reproduction and Survival After Cardiac Defect Repair

    ClinicalTrials.gov

    2016-02-17

    Cardiovascular Diseases; Heart Diseases; Defect, Congenital Heart; Aortic Valve Stenosis; Transposition of Great Vessels; Ductus Arteriosus, Patent; Heart Septal Defects, Atrial; Heart Septal Defects, Ventricular; Down Syndrome; Tetralogy of Fallot; Pulmonic Stenosis; Coarctation of Aorta

  2. Dynamical evolution of comet pairs

    NASA Astrophysics Data System (ADS)

    Sosa, Andrea; Fernández, Julio A.

    2016-10-01

    Some Jupiter family comets in near-Earth orbits (thereafter NEJFCs) show a remarkable similarity in their present orbits, like for instance 169P/NEAT and P/2003 T12 (SOHO), or 252P/LINEAR and P/2016 BA14 (PANSTARRS). By means of numerical integrations we studied the dynamical evolution of these objects. In particular, for each pair of presumably related objects, we are interested in assessing the stability of the orbital parameters for several thousand years, and to find a minimum of their relative spatial distance, coincident with a low value of their relative velocity. For those cases for which we find a well defined minimum of their relative orbital separation, we are trying to reproduce the actual orbit of the hypothetical fragment by modeling a fragmentation of the parent body. Some model parameters are the relative ejection velocity (a few m/s), the orbital point at which the fragmentation could have happened (e.g. perihelion), and the elapsed time since fragmentation. In addition, some possible fragmentation mechanisms, like thermal stress, rotational instability, or collisions, could be explored. According to Fernández J.A and Sosa A. 2015 (Planetary and Space Science 118,pp.14-24), some NEJFCs might come from the outer asteroid belt, and then they would have a more consolidated structure and a higher mineral content than that of comets coming from the trans-Neptunian belt or the Oort cloud. Therefore, such objects would have a much longer physical lifetime in the near-Earth region, and could become potential candidates to produce visible meteor showers (as for example 169P/NEAT which has been identified as the parent body of the alpha-Capricornid meteoroid stream, according to Jenniskens, P., Vaubaillon, J., 2010 (Astron. J. 139), and Kasuga, T., Balam, D.D., Wiegert, P.A., 2010 (Astron. J. 139).

  3. Neutral versus charged defect patterns in curved crystals.

    PubMed

    Azadi, Amir; Grason, Gregory M

    2016-07-01

    Characterizing the complex spectrum of topological defects in ground states of curved crystals is a long-standing problem with wide implications, from the mathematical Thomson problem to diverse physical realizations, including fullerenes and particle-coated droplets. While the excess number of "topologically charged" fivefold disclinations in a closed, spherical crystal is fixed, here we study the elementary transition from defect-free, flat crystals to curved crystals possessing an excess of "charged" disclinations in their bulk. Specifically, we consider the impact of topologically neutral patterns of defects-in the form of multidislocation chains or "scars" stable for small lattice spacing-on the transition from neutral to charged ground-state patterns of a crystalline cap bound to a spherical surface. Based on the asymptotic theory of caps in continuum limit of vanishing lattice spacing, we derive the morphological phase diagram of ground-state defect patterns, spanned by surface coverage of the sphere and forces at the cap edge. For the singular limit of zero edge forces, we find that scars reduce (by half) the threshold surface coverage for excess disclinations. Even more significant, scars flatten the geometric dependence of excess disinclination number on Gaussian curvature, leading to a transition between stable "charged" and "neutral" patterns that is, instead, critically sensitive to the compressive vs tensile nature of boundary forces on the cap.

  4. Lax pairs for deformed Minkowski spacetimes

    NASA Astrophysics Data System (ADS)

    Kyono, Hideki; Sakamoto, Jun-ichi; Yoshida, Kentaroh

    2016-01-01

    We proceed to study Yang-Baxter deformations of 4D Minkowski spacetime based on a conformal embedding. We first revisit a Melvin background and argue a Lax pair by adopting a simple replacement law invented in 1509.00173. This argument enables us to deduce a general expression of Lax pair. Then the anticipated Lax pair is shown to work for arbitrary classical r-matrices with Poincaré generators. As other examples, we present Lax pairs for pp-wave backgrounds, the Hashimoto-Sethi background, the Spradlin-Takayanagi-Volovich background.

  5. Dual origin of pairing in nuclei

    NASA Astrophysics Data System (ADS)

    Idini, A.; Potel, G.; Barranco, F.; Vigezzi, E.; Broglia, R. A.

    2016-11-01

    The pairing correlations of the nucleus 120Sn are calculated by solving the Nambu-Gor'kov equations, including medium polarization effects resulting from the interweaving of quasiparticles, spin and density vibrations, taking into account, within the framework of nuclear field theory (NFT), processes leading to self-energy and vertex corrections and to the induced pairing interaction. From these results one can not only demonstrate the inevitability of the dual origin of pairing in nuclei, but also extract information which can be used at profit to quantitatively disentangle the contributions to the pairing gap Δ arising from the bare and from the induced pairing interaction. The first is the strong 1 S 0 short-range NN potential resulting from meson exchange between nucleons moving in time reversal states within an energy range of hundreds of MeV from the Fermi energy. The second results from the exchange of vibrational modes between nucleons moving within few MeV from the Fermi energy. Short- ( v p bare) and long-range ( v p ind) pairing interactions contribute essentially equally to nuclear Cooper pair stability. That is to the breaking of gauge invariance in open-shell superfluid nuclei and thus to the order parameter, namely to the ground state expectation value of the pair creation operator. In other words, to the emergent property of generalized rigidity in gauge space, and associated rotational bands and Cooper pair tunneling between members of these bands.

  6. Majorana fermions and exotic surface Andreev bound states in topological superconductors: application to Cu(x)Bi2Se3.

    PubMed

    Hsieh, Timothy H; Fu, Liang

    2012-03-09

    The recently discovered superconductor Cu(x)Bi2Se3 is a candidate for three-dimensional time-reversal-invariant topological superconductors, which are predicted to have robust surface Andreev bound states hosting massless Majorana fermions. In this work, we analytically and numerically find the linearly dispersing Majorana fermions at k=0, which smoothly evolve into a new branch of gapless surface Andreev bound states near the Fermi momentum. The latter is a new type of Andreev bound states resulting from both the nontrivial band structure and the odd-parity pairing symmetry. The tunneling spectra of these surface Andreev bound states agree well with a recent point-contact spectroscopy experiment [S. Sasaki et al., Phys. Rev. Lett. 107, 217001 (2011)] and yield additional predictions for low temperature tunneling and photoemission experiments.

  7. Convex Lower Bounds for Free Energy Minimization

    NASA Astrophysics Data System (ADS)

    Moussa, Jonathan

    We construct lower bounds on free energy with convex relaxations from the nonlinear minimization over probabilities to linear programs over expectation values. Finite-temperature expectation values are further resolved into distributions over energy. A superset of valid expectation values is delineated by an incomplete set of linear constraints. Free energy bounds can be improved systematically by adding constraints, which also increases their computational cost. We compute several free energy bounds of increasing accuracy for the triangular-lattice Ising model to assess the utility of this method. This work was supported by the Laboratory Directed Research and Development program at Sandia National Laboratories. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under Contract DE-AC04-94AL85000.

  8. Bounds on Neutrino Non-Standard Interactions

    SciTech Connect

    Fernandez-Martinez, Enrique

    2010-03-30

    We review the present model independent bounds on neutrino non-standard interactions both at neutrino production and detection and in its interactions with matter. For matter non-standard interactions the direct bounds are rather weak. However, matter non-standard interactions are related by gauge invariance to the production and detection ones as well as to flavour changing processes involving charged leptons. Taking into account these relations much stronger bounds of at least O(10{sup -2}) can be derived unless significant fine tunings are implemented. Testing non-standard interactions at this level at future neutrino oscillation facilities is challenging but still feasible at very ambitious proposals such as the Neutrino Factory.

  9. Narrow deeply bound K- atomic states

    NASA Astrophysics Data System (ADS)

    Friedman, E.; Gal, A.

    1999-07-01

    Using optical potentials fitted to a comprehensive set of strong interaction level shifts and widths in K- atoms, we predict that the K- atomic levels which are inaccessible in the atomic cascade process are generally narrow, spanning a range of widths about 50-1500 keV over the entire periodic table. The mechanism for this narrowing is different from the mechanism for narrowing of pionic atom levels. Examples of such `deeply bound' K- atomic states are given, showing that in many cases these states should be reasonably well resolved. Several reactions which could be used to form these `deeply bound' states are mentioned. Narrow deeply bound states are expected also in overlinep atoms.

  10. η-nuclear bound states revisited

    NASA Astrophysics Data System (ADS)

    Friedman, E.; Gal, A.; Mareš, J.

    2013-10-01

    The strong energy dependence of the s-wave ηN scattering amplitude at and below threshold, as evident in coupled-channels K-matrix fits and chiral models that incorporate the S11N* (1535) resonance, is included self-consistently in η-nuclear bound-state calculations. This approach, applied recently in calculations of kaonic atoms and Kbar-nuclear bound states, is found to impose stronger constraints than ever on the onset of η-nuclear binding, with a minimum value of ReaηN ≈ 0.9 fm required to accommodate an η-4He bound state. Binding energies and widths of η-nuclear states are calculated within several underlying ηN models for nuclei across the periodic table, including Mg25η for which some evidence was proposed in a recent COSY experiment.

  11. Bounds on tensor wave and twisted inflation

    SciTech Connect

    Panda, Sudhakar; Sami, M.; Ward, John

    2010-11-15

    We study the bounds on tensor wave in a class of twisted inflation models, where D(4+2k)-branes are wrapped on cycles in the compact manifold and wrap the Kaluza-Klein direction in the corresponding effective field theory. While the lower bound is found to be analogous to that in type IIB models of brane inflation, the upper bound turns out to be significantly different. This is argued for a range of values for the parameter g{sub s}M satisfying the self-consistency relation and the WMAP data. Further, we observe that the wrapped D8-brane appears to be the most attractive from a cosmological perspective.

  12. Mass dependence of quantum energy inequality bounds

    SciTech Connect

    Eveson, Simon P.; Fewster, Christopher J.

    2007-09-15

    In a recent paper [C. J. Fewster and M. J. Pfenning, J. Math. Phys. 47, 082303 (2006)], quantum energy inequalities were used to place simple geometrical bounds on the energy densities of quantum fields in Minkowskian space-time regions. Here, we refine this analysis for massive fields, obtaining more stringent bounds which decay exponentially in the mass. At the technical level, this involves the determination of the asymptotic behavior of the lowest eigenvalue of a family of polyharmonic differential equations, a result which may be of independent interest. We compare our resulting bounds with the known energy density of the ground state on a cylinder space-time. In addition, we generalize some of our technical results to general L{sup p} spaces and draw comparisons with a similar result in the literature.

  13. Bound water in Kevlar 49 fibers

    SciTech Connect

    Garza, R.G.; Pruneda, C.O.; Morgan, R.J.

    1981-04-01

    From elemental analyses, thermogravimetric-mass spectroscopy studies and re-evaluation of previous water diffusion studies in Kevlar 49 fibers it is concluded that these fibers can contain two types of sorbed moisture. The fibers can absorb up to approx. 6 wt % loosely bound water with an activation energy for outgassing by desorption of 6 kcal/mole. This loosely bound water is a direct result of the presence of Na/sub 2/SO/sub 4/ impurities and the perturbations they induce on the packing of the rod-like poly (p-phenylene terephthalamide) macromolecules. Kevlar 49 fibers also inherently contain up to 30 wt % additional water which is tightly bound within the crystal lattice. This water exhibits an activation energy for outgassing by diffusion of approx. 40 kcal/mole and is only evolved from the fiber in significant quantities at t > 350/sup 0/C over a period of hours.

  14. Carbon related donor bound exciton transitions in ZnO nanowires

    SciTech Connect

    Mohammadbeigi, F.; Kumar, E. Senthil; Alagha, S.; Anderson, I.; Watkins, S. P.

    2014-08-07

    Several shallow donor bound exciton photoluminescence (PL) transitions are reported in ZnO nanowires doped with carbon. The emission energies are in the range of 3360.8–3361.9 meV, close to previously reported emission lines due to excitons bound to donor point defects, such as Ga, Al, In, and H. The addition of small amounts of hydrogen during growth results in a strong enhancement of the PL of these carbon related emission lines, yet PL and annealing measurements indicate no appreciable bulk hydrogen. The observation of two electron satellites for these emission lines enables the determination of the donor binding energies. The dependence of exciton localization energy on donor binding energy departs somewhat from the usual linear relationship observed for group III donors, indicating a qualitatively different central cell potential, as one would expect for a complex. Emission lines due to excitons bound to ionized donors associated with these defects are also observed. The dependence of the PL emission intensities on temperature and growth conditions demonstrates that the lines are due to distinct complexes and not merely excited states of each other.

  15. OUTWARD BOUND IN THE MAINSTREAM OF AMERICAN EDUCATION, A SYNOPSIS OF SIX OUTWARD BOUND MAINSTREAM PROJECTS.

    ERIC Educational Resources Information Center

    Outward Bound, Inc., Andover, MA.

    A SYNOPSIS IS OFFERED OF SIX DIFFERENT OUTWARD-BOUND PROGRAMS, EACH OF WHICH IS AN ADAPTATION OF THE BASIC OUTWARD-BOUND PHILOSOPHY OF HAVING YOUNG PEOPLE RECOGNIZE FOR THEMSELVES THEIR PHYSICAL, EMOTIONAL, AND SPIRITUAL CAPABILITIES SO THAT THEY WILL DEVELOP A STRONG SENSE OF SELF-RELIANCE AND INNER STRENGTH. THE ADAMS COUNTY, COLORADO,…

  16. Low quantum defect laser performance

    NASA Astrophysics Data System (ADS)

    Bowman, Steven R.

    2017-01-01

    Low quantum defect lasers are possible using near-resonant optical pumping. This paper examines the laser material performance as the quantum defect of the laser is reduced. A steady-state model is developed, which incorporates the relevant physical processes in these materials and predicts extraction efficiency and waste heat generation. As the laser quantum defect is reduced below a few percent, the impact of fluorescence cooling must be included in the analysis. The special case of a net zero quantum defect laser is examined in detail. This condition, referred to as the radiation balance laser (RBL), is shown to provide two orders of magnitude lower heat generation at the cost of roughly 10% loss in extraction efficiency. Numerical examples are presented with the host materials Yb:YAG and Yb:Silica. The general conditions, which yield optimal laser efficiency, are derived and explored.

  17. Congenital Heart Defects (For Parents)

    MedlinePlus

    ... heart, lungs, and blood vessels make up the circulatory system . The heart is the central pump of this ... Heart Defects Getting an EKG (Video) Your Heart & Circulatory System Heart Murmurs Mitral Valve Prolapse Movie: Heart & Circulatory ...

  18. Atrial Septal Defect (For Teens)

    MedlinePlus

    ... septal defect (pronounced: AY-tree-ul SEP-tul DEE-fekt), or ASD for short, is sometimes referred ... can be treated with cardiac catheterization (pronounced: CAR-dee-ack cath-uh-turr-ih-ZAY-shun), in ...

  19. Atrial Septal Defect (For Kids)

    MedlinePlus

    ... wall called the septum that normally separates the blue and red blood. In a person with an atrial septal defect, there's an opening in that wall. This hole in the wall lets oxygen-rich blood from ...

  20. Bound states in the Higgs model

    SciTech Connect

    Di Leo, L.; Darewych, J.W. )

    1994-02-01

    We derive relativistic wave equations for the bound states of two Higgs bosons within the Higgs sector of the minimal standard model. The variational method and the Hamiltonian formalism of QFT are used to obtain the equations using a simple [vert bar][ital hh][r angle]+[vert bar][ital hhh][r angle] Fock-space ansatz. We present approximate solutions of these equations for a range of Higgs boson masses, and explore the parameter space which corresponds to the existence of two-Higgs-boson bound states.

  1. The Lovasz bound and some generalizations

    NASA Technical Reports Server (NTRS)

    Mceliece, R. J.; Rodemich, E. R.; Rumsey, H. C., Jr.

    1978-01-01

    The zero error capacity of a discrete memoryless channel is defined as the largest rate at which information can be transmitted over the channel with zero error probability. One channel with five inputs and outputs whose zero capacity remained unsolved until very recently is considered. An extremely powerful and general technique phased in terms of graph theory, for studying combinatorial packing problems is presented. In particular, Delsarte's linear programming bound for cliques in association schemes appears as a special case of the Lovasz bound.

  2. Quantum Kolmogorov complexity and bounded quantum memory

    SciTech Connect

    Miyadera, Takayuki

    2011-04-15

    The effect of bounded quantum memory in a primitive information protocol has been examined using the quantum Kolmogorov complexity as a measure of information. We employed a toy two-party protocol in which Bob, by using a bounded quantum memory and an unbounded classical memory, estimates a message that was encoded in qubits by Alice in one of the bases X or Z. Our theorem gave a nontrivial effect of the memory boundedness. In addition, a generalization of the uncertainty principle in the presence of quantum memory has been obtained.

  3. Stable line defects in silicene

    NASA Astrophysics Data System (ADS)

    Ghosh, Dibyajyoti; Parida, Prakash; Pati, Swapan K.

    2015-11-01

    Line defects in two-dimensional (2D) materials greatly modulate various properties of their pristine form. Using ab initio molecular dynamics (AIMD) simulations, we investigate the structural reconstructions of different kinds of grain boundaries in the silicene sheets. It is evident that depending upon the presence of silicon adatoms and edge shape of grain boundaries (i.e., armchair or zigzag), stable extended line defects (ELDs) can be introduced in a controlled way. Further studies show the stability of these line-defects in silicene, grown on Ag(111) surface at room-temperature. Importantly, unlike most of the 2D sheet materials such as graphene and hexagonal boron nitride, 5-5-8 line defects modify the nonmagnetic semimetallic pristine silicene sheet to spin-polarized metal. As ferromagnetically ordered magnetic moments remain strongly localized at the line defect, a one-dimensional spin channel gets created in silicene. Interestingly, these spin channels are quite stable because, unlike the edge of nanoribbons, structural reconstruction or contamination cannot destroy the ordering of magnetic moments here. Zigzag silicene nanoribbons with a 5-5-8 line defect also exhibit various interesting electronic and magnetic properties depending upon their width as well as the nature of the magnetic coupling between edge and defect spin states. Upon incorporation of other ELDs, such as 4-4-4 and 4-8 defects, 2D sheets and nanoribbons of silicene show a nonmagnetic metallic or semiconducting ground state. Highlighting the controlled formation of ELDs and consequent emergence of technologically important properties in silicene, we propose new routes to realize silicene-based nanoelectronic and spintronic devices.

  4. Thermodynamic properties of the specific binding between Ag+ ions and C:C mismatched base pairs in duplex DNA.

    PubMed

    Torigoe, Hidetaka; Miyakawa, Yukako; Ono, Akira; Kozasa, Tetsuo

    2011-02-01

    Metal-mediated base pairs formed by the interaction between metal ions and artificial bases in oligonucleotides have been developed for potential applications in nanotechnology. We recently found that a natural C:C mismatched base pair bound to an Ag(+) ion to generate a novel metal-mediated base pair in duplex DNA. Preparation of the novel C-Ag-C base pair involving natural bases is more convenient than that of metal-mediated base pairs involving artificial bases because time-consuming base synthesis is not required. Here, we examined the thermodynamic properties of the binding between the Ag(+) ion and each of single and double C:C mismatched base pair in duplex DNA by isothermal titration calorimetry. The Ag(+) ion specifically bound to the C:C mismatched base pair at a 1:1 molar ratio with 10(6) M(-1) binding constant, which was significantly larger than those for nonspecific metal ion-DNA interactions. The specific binding between the Ag(+) ion and the single C:C mismatched base pair was mainly driven by the positive dehydration entropy change and the negative binding enthalpy change. In the interaction between the Ag(+) ion and each of the consecutive and interrupted double C:C mismatched base pairs, stoichiometric binding at a 1:1 molar ratio was achieved in each step of the first and second Ag(+) binding. The binding affinity for the second Ag(+) binding was similar to that for the first Ag(+) binding. Stoichiometric binding without interference and negative cooperativity may be favorable for aligning multiple Ag(+) ions in duplex DNA for applications of the metal-mediated base pairs in nanotechnology.

  5. Observation of self-excited acoustic vortices in defect-mediated dust acoustic wave turbulence.

    PubMed

    Tsai, Ya-Yi; I, Lin

    2014-07-01

    Using the self-excited dust acoustic wave as a platform, we demonstrate experimental observation of self-excited fluctuating acoustic vortex pairs with ± 1 topological charges through spontaneous waveform undulation in defect-mediated turbulence for three-dimensional traveling nonlinear longitudinal waves. The acoustic vortex pair has helical waveforms with opposite chirality around the low-density hole filament pair in xyt space (the xy plane is the plane normal to the wave propagation direction). It is generated through ruptures of sequential crest surfaces and reconnections with their trailing ruptured crest surfaces. The initial rupture is originated from the amplitude reduction induced by the formation of the kinked wave crest strip with strong stretching through the undulation instability. Increasing rupture causes the separation of the acoustic vortex pair after generation. A similar reverse process is followed for the acoustic vortex annihilating with the opposite-charged acoustic vortex from the same or another pair generation.

  6. Vector-like pairs and Brill-Noether theory

    NASA Astrophysics Data System (ADS)

    Watari, Taizan

    2016-11-01

    How likely is it that there are particles in a vector-like pair of representations in low-energy spectrum, when neither symmetry nor anomaly consideration motivates their presence? We address this question in the context of supersymmetric and geometric phase compactification of F-theory and Heterotic dual. Quantisation of the number of generations (or net chiralities in more general term) is also discussed along the way. Self-dual nature of the fourth cohomology of Calabi-Yau fourfolds is essential for the latter issue, while we employ Brill-Noether theory to set upper bounds on the number ℓ of vector-like pairs of chiral multiplets in the SU (5)GUT (5 + 5 bar) representations. For typical topological choices of geometry for F-theory compactification for SU(5) unification, the range of 0 ≤ ℓ ≲ 4 for perturbative unification is not in immediate conflict with what is already understood about F-theory compactification at this moment.

  7. Pair-potential approximations for many-body plasma physics

    NASA Astrophysics Data System (ADS)

    Marciante, M.; Stanton, L. G.; Murillo, M. S.

    2016-10-01

    Predicting properties of dense plasmas across wide parameters regimes requires the numerical solution of a many-body dynamical system whose properties depend on various underlying quantum processes. For this reason, high fidelity physics codes (e.g. DFT (orbital-free or Kohn-Sham), classical-map HNC and path integral MC) yield accurate information about the microphysical properties of dense matter. However, their computational cost restricts the simulations to a few tens to few hundreds of ions. To simulate larger systems while retaining an accurate kinetic description of ions, classical MD simulations make use of quantum-effective pair-potentials between the ions. Such potentials involve a small set of parameters, whose values are obtained from DFT calculations, and allow to simulate multi-species systems at much lower computational cost. In these models, bound electrons are usually approximated by an effective charge and free electrons are described as a continuous density. We have undertaken a detailed comparison of our DFT-informed pair-potentials, with results from higher-fidelity physics codes, including g(r), VACF Z(t), and interdiffusion coefficients, in order to determine the physical regimes in which the simpler accurate and very large-scale simulations are possible. Contract DE-AC52-06NA25396.

  8. Intrauterine infections and birth defects.

    PubMed

    Zheng, Xiao-Ying; Zhang, Ting; Wang, Yi-Fei; Xu, Chen; Chen, Gong; Xin, Ruo-Lei; Chen, Jia-Peng; Hu, Xu-Mei; Yang, Qing; Song, Xin-Ming; Pang, Li-Hua; Ji, Ying; Sun, Hong-Mei; Zhang, Lei; Liu, Ju-Fen; Guo, Yan-Ling; Zhang, Yan

    2004-12-01

    Intrauterine infection is an important cause of some birth defects worldwide. The most common pathogens include rubella virus, cytomegaloviurs, ureaplasma urealyticum, toxoplasma, etc. General information about these pathogens in epidemiology, consequence of birth defects, and the possible mechanisms in the progress of birth defects, and the interventions to prevent or treat these pathogens' infections are described. The infections caused by rubella virus, cytomegaloviurs, ureaplasma urealyticum, toxoplasma, etc. are common, yet they are proved to be fatal during the pregnant period, especially during the first trimester. These infections may cause sterility, abortion, stillbirth, low birth weight, and affect multiple organs that may induce loss of hearing and vision, even fetal deformity and the long-term effects. These pathogens' infections may influence the microenvironment of placenta, including levels of enzymes and cytokines, and affect chondriosome that may induce the progress of birth defect. Early diagnosis of infections during pregnancy should be strengthened. There are still many things to be settled, such as the molecular mechanisms of birth defects, the effective vaccines to certain pathogens. Birth defect researches in terms of etiology and the development of applicable and sensitive pathogen detection technology and methods are imperative.

  9. Topological defects from the multiverse

    SciTech Connect

    Zhang, Jun; Blanco-Pillado, Jose J.; Garriga, Jaume; Vilenkin, Alexander

    2015-05-28

    Many theories of the early universe predict the existence of a multiverse where bubbles continuously nucleate giving rise to observers in their interior. In this paper, we point out that topological defects of several dimensionalities will also be produced in de Sitter like regions of the multiverse. In particular, defects could be spontaneously nucleated in our parent vacuum. We study the evolution of these defects as they collide with and propagate inside of our bubble. We estimate the present distribution of defects in the observable part of the universe. The expected number of such nearby defects turns out to be quite small, even for the highest nucleation rate. We also study collisions of strings and domain walls with our bubble in our past light cone. We obtain simulated full-sky maps of the loci of such collisions, and find their angular size distribution. Similarly to what happens in the case of bubble collisions, the prospect of detecting any collisions of our bubble with ambient defects is greatly enhanced in the case where the cosmological constant of our parent vacuum is much higher than the vacuum energy density during inflation in our bubble.

  10. Topological defects from the multiverse

    SciTech Connect

    Zhang, Jun; Vilenkin, Alexander; Blanco-Pillado, Jose J.

    2015-05-01

    Many theories of the early universe predict the existence of a multiverse where bubbles continuously nucleate giving rise to observers in their interior. In this paper, we point out that topological defects of several dimensionalities will also be produced in de Sitter like regions of the multiverse. In particular, defects could be spontaneously nucleated in our parent vacuum. We study the evolution of these defects as they collide with and propagate inside of our bubble. We estimate the present distribution of defects in the observable part of the universe. The expected number of such nearby defects turns out to be quite small, even for the highest nucleation rate. We also study collisions of strings and domain walls with our bubble in our past light cone. We obtain simulated full-sky maps of the loci of such collisions, and find their angular size distribution. Similarly to what happens in the case of bubble collisions, the prospect of detecting any collisions of our bubble with ambient defects is greatly enhanced in the case where the cosmological constant of our parent vacuum is much higher than the vacuum energy density during inflation in our bubble.

  11. Microscopic resolution of the interplay of Kondo screening and superconducting pairing: Mn-phthalocyanine molecules adsorbed on superconducting Pb(111)

    NASA Astrophysics Data System (ADS)

    Bauer, Johannes; Pascual, Jose I.; Franke, Katharina J.

    2013-02-01

    Magnetic molecules adsorbed on a superconductor give rise to a local competition of Cooper pair and Kondo singlet formation inducing subgap bound states. For manganese-phthalocyanine molecules on a Pb(111) substrate, scanning tunneling spectroscopy resolves pairs of subgap bound states and two Kondo screening channels. We show in a combined approach of scaling and numerical renormalization group calculations that the intriguing relation between Kondo screening and superconducting pairing is solely determined by the hybridization strength with the substrate. We demonstrate that an effective one-channel Anderson impurity model with a sizable particle-hole asymmetry captures universal and nonuniversal observations in the system quantitatively. The model parameters and disentanglement of the two screening channels are elucidated by scaling arguments.

  12. Impact of iron-site defects on superconductivity in LiFeAs

    NASA Astrophysics Data System (ADS)

    Chi, Shun; Aluru, Ramakrishna; Singh, Udai Raj; Liang, Ruixing; Hardy, Walter N.; Bonn, D. A.; Kreisel, A.; Andersen, Brian M.; Nelson, R.; Berlijn, T.; Ku, W.; Hirschfeld, P. J.; Wahl, Peter

    2016-10-01

    In conventional s -wave superconductors, only magnetic impurities exhibit impurity bound states, whereas for an s± order parameter they can occur for both magnetic and nonmagnetic impurities. Impurity bound states in superconductors can thus provide important insight into the order parameter. Here, we present a combined experimental and theoretical study of native and engineered iron-site defects in LiFeAs. A detailed comparison of tunneling spectra measured on impurities with spin-fluctuation theory reveals a continuous evolution from negligible impurity-bound-state features for weaker scattering potential to clearly detectable states for somewhat stronger scattering potentials. All bound states for these intermediate strength potentials are pinned at or close to the gap edge of the smaller gap, a phenomenon that we explain and ascribe to multiorbital physics.

  13. Pairing, pseudogap and Fermi arcs in cuprates

    SciTech Connect

    Kaminski, Adam; Kondo, Takeshi; Takeuchi, Tsunehiro; Gu, Genda

    2014-04-29

    We use Angle Resolved Photoemission Spectroscopy (ARPES) to study the relationship between the pseudogap, pairing and Fermi arcs in cuprates. High quality data measured over a wide range of dopings reveals a consistent picture of Fermiology and pairing in these materials. The pseudogap is due to an ordered state that competes with superconductivity rather than preformed pairs. Pairing does occur below Tpair ~ 150K and significantly above Tc, but well below T* and the doping dependence of this temperature scale is distinct from that of the pseudogap. The d-wave gap is present below Tpair, and its interplay with strong scattering creates “artificial” Fermi arcs for Tc ≤ T ≤ Tpair. However, above Tpair, the pseudogap exists only at the antipodal region. This leads to presence of real, gapless Fermi arcs close to the node. The length of these arcs remains constant up to T*, where the full Fermi surface is recovered. As a result, we demonstrate that these findings resolve a number of seemingly contradictory scenarios.

  14. Pair condensation in a finite Fermi system

    SciTech Connect

    Sambataro, M.

    2007-05-15

    The lowest seniority-zero eigenstates of an exactly solvable multilevel pairing Hamiltonian for a finite Fermi system are examined at different pairing regimes. After briefly reviewing the form of the eigenstates in the Richardson formalism, we discuss a different representation of these states in terms of the collective pairs resulting from the diagonalization of the Hamiltonian in a space of two degenerate time-reversed fermions. We perform a two-fold analysis by working both in the fermionic space of these collective pairs and in a space of corresponding elementary bosons. On the fermionic side, we monitor the variations which occur, with increasing the pairing strength, in the structure of both these collective pairs and the lowest eigenstates. On the bosonic side, after reviewing a fermion-boson mapping procedure, we construct exact images of the fermion eigenstates and study their wave function. The analysis allows a close examination of the phenomenon of pair condensation in a finite Fermi system and gives new insights into the evolution of the lowest (seniority-zero) excited states of a pairing Hamiltonian from the unperturbed regime up to a strongly interacting one.

  15. Exploring Pair Programming Benefits for MIS Majors

    ERIC Educational Resources Information Center

    Dongo, Tendai; Reed, April H.; O'Hara, Margaret

    2016-01-01

    Pair programming is a collaborative programming practice that places participants in dyads, working in tandem at one computer to complete programming assignments. Pair programming studies with Computer Science (CS) and Software Engineering (SE) majors have identified benefits such as technical productivity, program/design quality, academic…

  16. 22 CFR 62.31 - Au pairs.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... pair participant with child development and child safety instruction, as follows: (1) Prior to... development instruction of which no less than 4 shall be devoted to specific training for children under the... and participate directly in the home life of the host family. All au pair participants provide...

  17. 22 CFR 62.31 - Au pairs.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... pair participant with child development and child safety instruction, as follows: (1) Prior to... development instruction of which no less than 4 shall be devoted to specific training for children under the... and participate directly in the home life of the host family. All au pair participants provide...

  18. 22 CFR 62.31 - Au pairs.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... pair participant with child development and child safety instruction, as follows: (1) Prior to... development instruction of which no less than 4 shall be devoted to specific training for children under the... and participate directly in the home life of the host family. All au pair participants provide...

  19. 22 CFR 62.31 - Au pairs.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... pair participant with child development and child safety instruction, as follows: (1) Prior to... development instruction of which no less than 4 shall be devoted to specific training for children under the... and participate directly in the home life of the host family. All au pair participants provide...

  20. 22 CFR 62.31 - Au pairs.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... pair participant with child development and child safety instruction, as follows: (1) Prior to... development instruction of which no less than 4 shall be devoted to specific training for children under the... and participate directly in the home life of the host family. All au pair participants provide...

  1. Top Quark Pair Production at the Tevatron

    SciTech Connect

    Nielsen, Jason

    2005-05-17

    The measurement of the top quark pair production crosssection inproton-antiproton collisions at 1.96 TeV is a test ofquantumchromodynamics and could potentially be sensitive to newphysics beyondthe standard model. I report on the latest t-tbarcross section resultsfrom the CDF and DZero experiments in various finalstate topologies whicharise from decays of top quark pairs.

  2. The role of point defects in PbS, PbSe and PbTe: a first principles study.

    PubMed

    Li, Wun-Fan; Fang, Chang-Ming; Dijkstra, Marjolein; van Huis, Marijn A

    2015-09-09

    Intrinsic defects are of central importance to many physical and chemical processes taking place in compound nanomaterials, such as photoluminescence, accommodation of off-stoichiometry and cation exchange. Here, the role of intrinsic defects in the above mentioned processes inside rock salt (RS) lead chalcogenide systems PbS, PbSe and PbTe (PbX) was studied systematically using first principles density functional theory. Vacancy, interstitial, Schottky and Frenkel defects were considered. Rock salt PbO was included for comparison. The studied physical properties include defect formation energy, local geometry relaxation, Bader charge analysis, and electronic structure. The defect formation energies show that monovacancy defects and Schottky defects are favoured over interstitial and Frenkel defects. Schottky dimers, where the cation vacancy and anion vacancy are adjacent to each other, have the lowest defect formation energies at 1.27 eV, 1.29 eV and 1.21 eV for PbS, PbSe and PbTe, respectively. Our results predict that a Pb monovacancy gives rise to a shallow acceptor state, while an X vacancy generates a deep donor state, and Schottky defects create donor-acceptor pairs inside the band gap. The surprisingly low formation energy of Schottky dimers suggests that they may play an important role in cation exchange processes, in contrast to the current notion that only single point defects migrate during cation exchange.

  3. First-principles study of point defects in thorium carbide

    NASA Astrophysics Data System (ADS)

    Pérez Daroca, D.; Jaroszewicz, S.; Llois, A. M.; Mosca, H. O.

    2014-11-01

    Thorium-based materials are currently being investigated in relation with their potential utilization in Generation-IV reactors as nuclear fuels. One of the most important issues to be studied is their behavior under irradiation. A first approach to this goal is the study of point defects. By means of first-principles calculations within the framework of density functional theory, we study the stability and formation energies of vacancies, interstitials and Frenkel pairs in thorium carbide. We find that C isolated vacancies are the most likely defects, while C interstitials are energetically favored as compared to Th ones. These kind of results for ThC, to the best authors' knowledge, have not been obtained previously, neither experimentally, nor theoretically. For this reason, we compare with results on other compounds with the same NaCl-type structure.

  4. Bioactivity of albumins bound to silver nanoparticles.

    PubMed

    Mariam, Jessy; Sivakami, S; Kothari, D C; Dongre, P M

    2014-06-01

    The last decade has witnessed a tremendous rise in the proposed applications of nanomaterials in the field of medicine due to their very attractive physiochemical properties and novel actions such as the ability to reach previously inaccessible targets such as brain. However biological activity of functional molecules bound to nanoparticles and its physiological consequences is still unclear and hence this area requires immediate attention. The functional properties of Human Serum Albumin (HSA) and Bovine Serum Albumin (BSA) bound to silver nanoparticles (~60 nm) have been studied under physiological environment. Esterase activity, binding of drugs (warfarin and ibuprofen), antioxidant activity and copper binding by albumins was evaluated. The catalytic efficiencies of HSA and BSA diminished upon binding to silver nanoparticles. Perturbation in binding of warfarin and ibuprofen, loss of free sulphydryls, antioxidant activity and enhancement of copper binding were observed in albumins bound to nanoparticles. These alterations in functional activity of nanoparticle bound albumins which will have important consequences should be taken into consideration while using nanoparticles for diagnostic and therapeutic purposes.

  5. Outward Bound as an Adjunct to Therapy.

    ERIC Educational Resources Information Center

    Chase, Nelson K.

    The Colorado Outward Bound School (COBS) provides successful adjunct programs for special populations undergoing therapy at the Adventure Home (Boulder, CO), the Juvenile Justice Program and the St. Luke's Hospital Alcoholism Recovery Unit (Denver, CO), and the Dartmouth-Hitchcock Medical Center Department of Psychiatry (Hanover, NH). The goals of…

  6. Lifetime of a Chemically Bound Helium Compound

    NASA Technical Reports Server (NTRS)

    Chaban, Galina M.; Lundell, Jan; Gerber, R. Benny; Kwak, Dochan (Technical Monitor)

    2001-01-01

    The rare-gas atoms are chemically inert, to an extent unique among all elements. This is due to the stable electronic structure of the atoms. Stable molecules with chemically bound rare-gas atoms are, however, known. A first such compound, XePtF6, W2S prepared in 1962 and since then a range of molecules containing radon, xenon and krypton have been obtained. Most recently, a first stable chemically bound compound of argon was prepared, leaving neon and helium as the only elements for which stable chemically bound molecules are not yet known. Electronic structure calculations predict that a metastable species HHeF exists, but significance of the result depends on the unknown lifetime. Here we report quantum dynamics calculations of the lifetime of HHeF, using accurate interactions computed from electronic structure theory. HHeF is shown to disintegrate by tunneling through energy barriers into He + HF and H + He + F the first channel greatly dominating. The lifetime of HHeF is more than 120 picoseconds, that of DHeF is 14 nanoseconds. The relatively long lifetimes are encouraging for the preparation prospects of this first chemically bound helium compound.

  7. College Bound Seniors, 1974-75.

    ERIC Educational Resources Information Center

    College Entrance Examination Board, New York, NY.

    Some one million college bound students, who were high school seniors during 1974-75 previously participated in the College Board's Admissions Testing Program (ATP), which included the Scholarship Aptitude Test (SAT), the Test of Standard Written English, the Student Descriptive Questionnaire, and the ATP Achievement Tests. These tests created a…

  8. Mean shift is a bound optimization.

    PubMed

    Fashing, Mark; Tomasi, Carlo

    2005-03-01

    We build on the current understanding of mean shift as an optimization procedure. We demonstrate that, in the case of piecewise constant kernels, mean shift is equivalent to Newton's method. Further, we prove that, for all kernels, the mean shift procedure is a quadratic bound maximization.

  9. Bounds on transverse momentum dependent distribution functions

    NASA Astrophysics Data System (ADS)

    Henneman, A.

    2001-01-01

    When more than one hadron takes part in a hard process, an extended set of quark distribution and fragmentation functions becomes relevant. In this talk, the derivation of Soffer-like bounds for these functions, in the case of a spin-1/2 target [1], is sketched and some of their aspects are discussed.

  10. Mentoring College Bound High School Seniors.

    ERIC Educational Resources Information Center

    Mowrer-Popiel, Elizabeth

    This article examines causes of the high rate of attrition of college freshmen during the first few weeks of school and describes a plan for mentorships between successful college students and college-bound secondary seniors prior to entrance into college. In discussing the challenges facing freshmen, the article suggests that they suffer stress…

  11. Bounded relative motion under zonal harmonics perturbations

    NASA Astrophysics Data System (ADS)

    Baresi, Nicola; Scheeres, Daniel J.

    2017-04-01

    The problem of finding natural bounded relative trajectories between the different units of a distributed space system is of great interest to the astrodynamics community. This is because most popular initialization methods still fail to establish long-term bounded relative motion when gravitational perturbations are involved. Recent numerical searches based on dynamical systems theory and ergodic maps have demonstrated that bounded relative trajectories not only exist but may extend up to hundreds of kilometers, i.e., well beyond the reach of currently available techniques. To remedy this, we introduce a novel approach that relies on neither linearized equations nor mean-to-osculating orbit element mappings. The proposed algorithm applies to rotationally symmetric bodies and is based on a numerical method for computing quasi-periodic invariant tori via stroboscopic maps, including extra constraints to fix the average of the nodal period and RAAN drift between two consecutive equatorial plane crossings of the quasi-periodic solutions. In this way, bounded relative trajectories of arbitrary size can be found with great accuracy as long as these are allowed by the natural dynamics and the physical constraints of the system (e.g., the surface of the gravitational attractor). This holds under any number of zonal harmonics perturbations and for arbitrary time intervals as demonstrated by numerical simulations about an Earth-like planet and the highly oblate primary of the binary asteroid (66391) 1999 KW4.

  12. Colorado Outward Bound School River Rafters' Manual.

    ERIC Educational Resources Information Center

    Leachman, Mark

    Instructional sequences, safety rules, duties of crew members, and procedures for Colorado Outward Bound School river rafting trips are summarized in this manual. Designed to acquaint instructors with the duties expected of them on the trips, the information in the manual is presented in outline form and is intended for those with prior river…

  13. Colorado Outward Bound School Rafting Manual.

    ERIC Educational Resources Information Center

    Brown, Al

    River rafting trips at the Colorado Outward Bound School (COBS) present participants with an opportunity for developing self-confidence, self-awareness, and concern for others through challenging and adventuresome group effort, combined with a program of instruction in rafting skills, safety consciousness, and awareness of the natural environment.…

  14. Bound Indoleacetic Acid in Avena Coleoptiles 1

    PubMed Central

    Winter, Alan; Thimann, Kenneth V.

    1966-01-01

    When C14 carboxyl indoleacetic acid (IAA) is transported through Avena coleoptile sections a fraction of the activity becomes bound. The nature of this bound IAA has been investigated. Upon extraction with solvents and chromatography a substance having the RF of IAA in 4 solvents was detected. No evidence could be found for the formation of indoleacetyl conjugates. In pea stem sections subjected to a similar experimental regime good evidence was obtained for the occurrence of conjugates. When IAA was supplied exogenously to coleoptile sections floating in solutions the occurrence of conjugates was shown to be dependent on the presence of the primary leaf. In its absence no conjugates could be detected. On grinding coleoptile sections and subsequent centrifugation at 240 × g the radioactivity was found to be in the tissue fraction as opposed to the supernatant. The radioactivity cannot be removed from the tissue by extraction with water, buffer solution or treatment with ribonuclease. It is readily removed by 10% urea, crystalline trypsin and chymotrypsin. It is therefore concluded that IAA becomes bound to a protein. Bound IAA does not appear to be able to cause growth in Avena coleoptile sections. PMID:16656259

  15. Towards a New Generation of Outward Bound.

    ERIC Educational Resources Information Center

    Martin, Andrew

    2000-01-01

    Outward Bound Czech Republic developed a course for international participants in which everybody is simultaneously an actor and viewer in a 2-week theater play. A five-stage process of developing "dramaturgy" allows instructors to adapt the scenario to participant needs and thus enhance the likelihood of challenge and transfer of…

  16. Pairing in a dry Fermi sea

    NASA Astrophysics Data System (ADS)

    Maier, T. A.; Staar, P.; Mishra, V.; Chatterjee, U.; Campuzano, J. C.; Scalapino, D. J.

    2016-06-01

    In the traditional Bardeen-Cooper-Schrieffer theory of superconductivity, the amplitude for the propagation of a pair of electrons with momentum k and -k has a log singularity as the temperature decreases. This so-called Cooper instability arises from the presence of an electron Fermi sea. It means that an attractive interaction, no matter how weak, will eventually lead to a pairing instability. However, in the pseudogap regime of the cuprate superconductors, where parts of the Fermi surface are destroyed, this log singularity is suppressed, raising the question of how pairing occurs in the absence of a Fermi sea. Here we report Hubbard model numerical results and the analysis of angular-resolved photoemission experiments on a cuprate superconductor. In contrast to the traditional theory, we find that in the pseudogap regime the pairing instability arises from an increase in the strength of the spin-fluctuation pairing interaction as the temperature decreases rather than the Cooper log instability.

  17. PAIR: the predicted Arabidopsis interactome resource.

    PubMed

    Lin, Mingzhi; Shen, Xueling; Chen, Xin

    2011-01-01

    The predicted Arabidopsis interactome resource (PAIR, http://www.cls.zju.edu.cn/pair/), comprised of 5990 experimentally reported molecular interactions in Arabidopsis thaliana together with 145,494 predicted interactions, is currently the most comprehensive data set of the Arabidopsis interactome with high reliability. PAIR predicts interactions by a fine-tuned support vector machine model that integrates indirect evidences for interaction, such as gene co-expressions, domain interactions, shared GO annotations, co-localizations, phylogenetic profile similarities and homologous interactions in other organisms (interologs). These predictions were expected to cover 24% of the entire Arabidopsis interactome, and their reliability was estimated to be 44%. Two independent example data sets were used to rigorously validate the prediction accuracy. PAIR features a user-friendly query interface, providing rich annotation on the relationships between two proteins. A graphical interaction network browser has also been integrated into the PAIR web interface to facilitate mining of specific pathways.

  18. New concept for the pairing anti-halo effect as a localized wave packet of quasiparticles

    NASA Astrophysics Data System (ADS)

    Hagino, K.; Sagawa, H.

    2017-02-01

    The pairing anti-halo effect is a phenomenon that a pairing correlation suppresses a divergence of nuclear radius, which happens for single-particle states with orbital angular momenta of l =0 and 1 in the limit of vanishing binding energy. While this effect has mainly been discussed in terms of Hartree-Fock-Bogoliubov (HFB) theory, we here use a three-body model and provide its new intuitive concept as a localized wave packet for a quasiparticle, that is, a coherent superposition of a weakly bound and continuum wave functions due to a pairing interaction. We show that the one-particle density in the three-body model can be directly expressed with such quasiparticle wave functions, which have a close analog to wave functions in the HFB approximation.

  19. Defects formation and wave emitting from defects in excitable media

    NASA Astrophysics Data System (ADS)

    Ma, Jun; Xu, Ying; Tang, Jun; Wang, Chunni

    2016-05-01

    Abnormal electrical activities in neuronal system could be associated with some neuronal diseases. Indeed, external forcing can cause breakdown even collapse in nervous system under appropriate condition. The excitable media sometimes could be described by neuronal network with different topologies. The collective behaviors of neurons can show complex spatiotemporal dynamical properties and spatial distribution for electrical activities due to self-organization even from the regulating from central nervous system. Defects in the nervous system can emit continuous waves or pulses, and pacemaker-like source is generated to perturb the normal signal propagation in nervous system. How these defects are developed? In this paper, a network of neurons is designed in two-dimensional square array with nearest-neighbor connection type; the formation mechanism of defects is investigated by detecting the wave propagation induced by external forcing. It is found that defects could be induced under external periodical forcing under the boundary, and then the wave emitted from the defects can keep balance with the waves excited from external forcing.

  20. SRTM Stereo Pair: Fiji Islands

    NASA Technical Reports Server (NTRS)

    2000-01-01

    image pair and viewing them with a stereoscope. When stereoscopically merged, the result is a vertically exaggerated view of the Earth's surface in its full three dimensions.

    This image was acquired by SRTM aboard the Space Shuttle Endeavour, launched on February 11, 2000. SRTM used the same radar instrument that comprised the Spaceborne Imaging Radar-C/X-Band Synthetic Aperture Radar (SIR-C/X-SAR) that flew twice on the Space Shuttle Endeavour in 1994. SRTM was designed to collect three-dimensional measurements of the Earth's surface. To collect the 3-D data, engineers added a 60-meter-long (about 200 feet) mast, installed additional C-band and X-band antennas, and improved tracking and navigation devices. The mission is a cooperative project between the National Aeronautics and Space Administration (NASA), the National Imagery and Mapping Agency (NIMA) of the U.S. Department of Defense (DoD), and the German and Italian space agencies. It is managed by NASA's Jet Propulsion Laboratory, Pasadena, CA, for NASA's Earth Science Enterprise, Washington, DC.

    Size: 192 km (119 miles) x 142 km (88 miles) Location: 17.8 deg. South lat., 178.0 deg. East lon. Orientation: North at top Date Acquired: February 19, 2000 Image: NASA/JPL/NIMA

  1. Amorphous carbon film growth on Si: Correlation between stress and generation of defects into the substrate

    SciTech Connect

    Brusa, R.S.; Macchi, C.; Mariazzi, S.; Karwasz, G.P.; Laidani, N.; Bartali, R.; Anderle, M.

    2005-05-30

    Amorphous carbon films of several thicknesses were prepared by graphite sputtering on crystalline silicon substrate. The samples were depth profiled with positron annihilation spectroscopy for open-volume measurements and characterized for their residual internal stress. It was found that after film growth the substrate presents vacancy-like defects decorated by oxygen in a layer extending in the substrate by several tens of nanometers beyond the film/Si interface. The width of the defected layer and the decoration of vacancy-like defects are directly and inversely proportional to the measured intensity of the residual stress, respectively. These findings indicate the existence of a relaxation mechanism of the stress in the films that involves deeply the substrate. The decorated vacancy-like defects are suggested to be bounded to dislocations induced in the substrate by the stress relaxation.

  2. Going beyond "no-pair relativistic quantum chemistry".

    PubMed

    Liu, Wenjian; Lindgren, Ingvar

    2013-07-07

    The current field of relativistic quantum chemistry (RQC) has been built upon the no-pair and no-retardation approximations. While retardation effects must be treated in a time-dependent manner through quantum electrodynamics (QED) and are hence outside RQC, the no-pair approximation (NPA) has to be removed from RQC for it has some fundamental defects. Both configuration space and Fock space formulations have been proposed in the literature to do this. However, the former is simply wrong, whereas the latter is still incomplete. To resolve the old problems pertinent to the NPA itself and new problems beyond the NPA, we propose here an effective many-body (EMB) QED approach that is in full accordance with standard methodologies of electronic structure. As a first application, the full second order energy E2 of a closed-shell many-electron system subject to the instantaneous Coulomb-Breit interaction is derived, both algebraically and diagrammatically. It is shown that the same E2 can be obtained by means of 3 Goldstone-like diagrams through the standard many-body perturbation theory or 28 Feynman diagrams through the S-matrix technique. The NPA arises naturally by retaining only the terms involving the positive energy states. The potential dependence of the NPA can be removed by adding in the QED one-body counter terms involving the negative energy states, thereby leading to a "potential-independent no-pair approximation" (PI-NPA). The NPA, PI-NPA, EMB-QED, and full QED then span a continuous spectrum of relativistic molecular quantum mechanics.

  3. Going beyond ``no-pair relativistic quantum chemistry''

    NASA Astrophysics Data System (ADS)

    Liu, Wenjian; Lindgren, Ingvar

    2013-07-01

    The current field of relativistic quantum chemistry (RQC) has been built upon the no-pair and no-retardation approximations. While retardation effects must be treated in a time-dependent manner through quantum electrodynamics (QED) and are hence outside RQC, the no-pair approximation (NPA) has to be removed from RQC for it has some fundamental defects. Both configuration space and Fock space formulations have been proposed in the literature to do this. However, the former is simply wrong, whereas the latter is still incomplete. To resolve the old problems pertinent to the NPA itself and new problems beyond the NPA, we propose here an effective many-body (EMB) QED approach that is in full accordance with standard methodologies of electronic structure. As a first application, the full second order energy E2 of a closed-shell many-electron system subject to the instantaneous Coulomb-Breit interaction is derived, both algebraically and diagrammatically. It is shown that the same E2 can be obtained by means of 3 Goldstone-like diagrams through the standard many-body perturbation theory or 28 Feynman diagrams through the S-matrix technique. The NPA arises naturally by retaining only the terms involving the positive energy states. The potential dependence of the NPA can be removed by adding in the QED one-body counter terms involving the negative energy states, thereby leading to a "potential-independent no-pair approximation" (PI-NPA). The NPA, PI-NPA, EMB-QED, and full QED then span a continuous spectrum of relativistic molecular quantum mechanics.

  4. Solubilization and fractionation of paired helical filaments.

    PubMed

    González, P J; Correas, I; Avila, J

    1992-09-01

    Paired helical filaments isolated from brains of two different patients with Alzheimer's disease were extensively treated with the ionic detergent, sodium dodecyl sulphate. Filaments were solubilized at different extents, depending on the brain examined, thus suggesting the existence of two types of paired helical filaments: sodium dodecyl sulphate-soluble and insoluble filaments. In the first case, the number of structures resembling paired helical filaments greatly decreased after the detergent treatment, as observed by electron microscopy. Simultaneously, a decrease in the amount of sedimentable protein was also observed upon centrifugation of the sodium dodecyl sulfate-treated paired helical filaments. A sodium dodecyl sulphate-soluble fraction was isolated as a supernatant after low-speed centrifugation of the sodium dodecyl sulphate-treated paired helical filaments. The addition of the non-ionic detergent Nonidet-P40 to this fraction resulted in the formation of paired helical filament-like structures. When the sodium dodecyl sulphate-soluble fraction was further fractionated by high-speed centrifugation, three subfractions were observed: a supernatant, a pellet and a thin layer between these two subfractions. No paired helical filaments were observed in any of these subfractions, even after addition of Nonidet P-40. However, when they were mixed back together, the treatment with Nonidet P-40 resulted in the visualization of paired helical filament-like structures. These results suggest that at least two different components are needed for the reconstitution of paired helical filaments as determined by electron microscopy. The method described here may allow the study of the components involved in the formation of paired helical filaments and the identification of possible factors capable of blocking this process.

  5. Sample Complexity Bounds for Differentially Private Learning

    PubMed Central

    Chaudhuri, Kamalika; Hsu, Daniel

    2013-01-01

    This work studies the problem of privacy-preserving classification – namely, learning a classifier from sensitive data while preserving the privacy of individuals in the training set. In particular, the learning algorithm is required in this problem to guarantee differential privacy, a very strong notion of privacy that has gained significant attention in recent years. A natural question to ask is: what is the sample requirement of a learning algorithm that guarantees a certain level of privacy and accuracy? We address this question in the context of learning with infinite hypothesis classes when the data is drawn from a continuous distribution. We first show that even for very simple hypothesis classes, any algorithm that uses a finite number of examples and guarantees differential privacy must fail to return an accurate classifier for at least some unlabeled data distributions. This result is unlike the case with either finite hypothesis classes or discrete data domains, in which distribution-free private learning is possible, as previously shown by Kasiviswanathan et al. (2008). We then consider two approaches to differentially private learning that get around this lower bound. The first approach is to use prior knowledge about the unlabeled data distribution in the form of a reference distribution chosen independently of the sensitive data. Given such a reference , we provide an upper bound on the sample requirement that depends (among other things) on a measure of closeness between and the unlabeled data distribution. Our upper bound applies to the non-realizable as well as the realizable case. The second approach is to relax the privacy requirement, by requiring only label-privacy – namely, that the only labels (and not the unlabeled parts of the examples) be considered sensitive information. An upper bound on the sample requirement of learning with label privacy was shown by Chaudhuri et al. (2006); in this work, we show a lower bound. PMID:25285183

  6. Rapid defect detections of bonded wafer using near infrared polariscope

    NASA Astrophysics Data System (ADS)

    Ng, Chi Seng; Asundi, Anand K.

    2011-10-01

    In modern field of microelectronics and MEMS, wafer bonding has emerged as an important processing step in wide range of manufacturing applications. During the manufacturing process, even in the modern clean room, small defects result from trapped particles and gas bubbles exist at bonded interface. Defects and trapped particles may exist on the top and bottom of the wafers, or at the interface of bonded wafer pair. These inclusions will generate high stress around debond region at the wafers bonded interface. In this paper, inspection at the bonded interface will be the interest of investigation. Since silicon wafer is opaque to visible light, defect detection at the bonded interface of silicon wafer is not possible. Due to the fact that silicon wafer is transparent to wavelength greater than 1150nm, an Near Infrared Polariscope which has showed some promises on residual stress measurement on silicon devices has been adapted and developed. This method is based on the well known photoelastic principles, where the stress variations are measured based on the changes of light propagation velocity in birefringence material. The results are compared and contrast with conventional Infrared Transmission Imaging tool (IRT) which is widely used to inspect the bonded silicon wafer. In this research, the trapped particles that are not visible via conventional infrared transmission method are identified via the generated residual stress pattern. The magnitude of the residual stress fields associated with each defect is examined qualitatively and quantitatively. The stress field generated at the wafers bonded interface will looks like a 'butterfly' pattern. Wafer pairs Pyrex-Si and Si-Si bonded interface will be examined.

  7. Detecting a preformed pair phase: Response to a pairing forcing field

    NASA Astrophysics Data System (ADS)

    Tagliavini, A.; Capone, M.; Toschi, A.

    2016-10-01

    The normal state of strongly coupled superconductors is characterized by the presence of "preformed" Cooper pairs well above the superconducting critical temperature. In this regime, the electrons are paired, but they lack the phase coherence necessary for superconductivity. The existence of preformed pairs implies the existence of a characteristic energy scale associated with a pseudogap. Preformed pairs are often invoked to interpret systems where some signatures of pairing are present without actual superconductivity, but an unambiguous theoretical characterization of a preformed-pair system is still lacking. To fill this gap, we consider the response to an external pairing field of an attractive Hubbard model, which hosts one of the cleanest realizations of a preformed pair phase, and a repulsive model where s -wave superconductivity cannot be realized. Using dynamical mean-field theory to study this response, we identify the characteristic features which distinguish the reaction of a preformed pair state from a normal metal without any precursor of pairing. The theoretical detection of preformed pairs is associated with the behavior of the second derivative of the order parameter with respect to the external field, as confirmed by analytic calculations in limiting cases. Our findings provide a solid test bed for the interpretation of state-of-the-art calculations for the normal state of the doped Hubbard model in terms of d -wave preformed pairs and, in perspective, of nonequilibrium experiments in high-temperature superconductors.

  8. Ab initio study of dopant-defect interactions in graphene sheets and graphene nano-ribbons

    NASA Astrophysics Data System (ADS)

    Tawalbeh, Tarek

    Theoretical studies of nanostructured systems, such as doped, defective and pristine graphene and graphene nanoribbons, present a major challenge to conventional computational methods. This thesis presents ab initio calculations based on density functional theory (DFT) to study the structural and electronic properties of doped and defective graphene and graphene 'nanoribbons. Our calculations are carried-out using density-functional pseudopotential approximations combined with the generalized gradient approximation (GGA) for the exchange-correlation functional. Structural optimizations are executed by iterative force minimization using the conjugate gradient algorithm. We investigate the effect of dopants and point defects on graphene and graphene nanoribbons and study the interactions between the two. Binding energies, equilibrium geometries, charge transfer, and exchange-splitting-induced magnetism are calculated. The dependence of dopant-defect separation distance on interaction energy and interaction energy is examined in detail. We find that the interaction energy for on-defect dopant sites is dominated by how well defect geometry accommodates the dopant-carbon interatomic distance. Depending on the site dopant-defect interaction is either attractive or repulsive. Stone-Wales defect-nitrogen pairing was found to induce exchange splitting and magnetism in certain configurations. Nitrogen was also found to passivate single-vacancy dangling bonds and eliminate exchange-splitting induced magnetism; vacancy-nitrogen interactions were found to be mostly attractive. Boron-vacancy pairing can result in a favorable symmetric sp3 configuration, this is the only vacancy-boron pairing were dangling bonds are passivated and magnetism is eliminated; other favorable boron-vacancy pairings maintain exchange splitting and can in some cases enhance it. We found that the effect of dopant-defect separation distance follows a simple inverse power law. Our results indicate that

  9. Breatherlike defects and their dynamics in the one-dimensional roll structure of twisted nematics

    SciTech Connect

    Skaldin, O. A.; Delev, V. A. Shikhovtseva, E. S.; Lebedev, Yu. A.; Batyrshin, E. S.

    2015-12-15

    The dynamics of the nonsingular defects in the periodic structures of the rolls that appear in π/2-twisted nematic liquid crystals during electroconvection is studied experimentally and theoretically. The roll structures in twisted nematics are characterized by the presence of an axial component of the hydrodynamic flow velocity with opposite directions in neighboring rolls. The critical oscillation frequency of structural defects is quantitatively estimated using a nonlinear equation of motion for roll displacements. It is found that a pair of edge dislocations with topological charges of +1 and–1 nucleates and annihilates periodically during the oscillations of a defect with a nonsingular core. Oscillating defects with a zero topological charge is shown to correspond to the solution of the sine-Gordon equation in the form of standing breathers. Asymmetry is detected in the full oscillation cycle of a breather defect, and it is related to the twist symmetry of a twist nematic. This asymmetry is taken into account as effective anisotropic friction. The behavior of a breather on a trap, namely, a classical defect (dislocation), is investigated. Dislocation motion is shown to be anisotropic in the oscillation cycle: in one direction, a dislocation moves regularly; in the second phase, the transition into the initial state proceeds via the decay of the breather into a dipole pair of dislocations of opposite signs followed by their annihilation.

  10. Model for transport and reaction of defects and carriers within displacement cascades in gallium arsenide

    SciTech Connect

    Wampler, William R. Myers, Samuel M.

    2015-01-28

    A model is presented for recombination of charge carriers at evolving displacement damage in gallium arsenide, which includes clustering of the defects in atomic displacement cascades produced by neutron or ion irradiation. The carrier recombination model is based on an atomistic description of capture and emission of carriers by the defects with time evolution resulting from the migration and reaction of the defects. The physics and equations on which the model is based are presented, along with the details of the numerical methods used for their solution. The model uses a continuum description of diffusion, field-drift and reaction of carriers, and defects within a representative spherically symmetric cluster of defects. The initial radial defect profiles within the cluster were determined through pair-correlation-function analysis of the spatial distribution of defects obtained from the binary-collision code MARLOWE, using recoil energies for fission neutrons. Properties of the defects are discussed and values for their parameters are given, many of which were obtained from density functional theory. The model provides a basis for predicting the transient response of III-V heterojunction bipolar transistors to displacement damage from energetic particle irradiation.

  11. Model for transport and reaction of defects and carriers within displacement cascades in gallium arsenide

    NASA Astrophysics Data System (ADS)

    Wampler, William R.; Myers, Samuel M.

    2015-01-01

    A model is presented for recombination of charge carriers at evolving displacement damage in gallium arsenide, which includes clustering of the defects in atomic displacement cascades produced by neutron or ion irradiation. The carrier recombination model is based on an atomistic description of capture and emission of carriers by the defects with time evolution resulting from the migration and reaction of the defects. The physics and equations on which the model is based are presented, along with the details of the numerical methods used for their solution. The model uses a continuum description of diffusion, field-drift and reaction of carriers, and defects within a representative spherically symmetric cluster of defects. The initial radial defect profiles within the cluster were determined through pair-correlation-function analysis of the spatial distribution of defects obtained from the binary-collision code MARLOWE, using recoil energies for fission neutrons. Properties of the defects are discussed and values for their parameters are given, many of which were obtained from density functional theory. The model provides a basis for predicting the transient response of III-V heterojunction bipolar transistors to displacement damage from energetic particle irradiation.

  12. Topological repulsion between domain walls in magnetic nanowires leading to the formation of bound states.

    PubMed

    Thomas, Luc; Hayashi, Masamitsu; Moriya, Rai; Rettner, Charles; Parkin, Stuart

    2012-05-01

    Head-to-head and tail-to-tail magnetic domain walls in nanowires behave as free magnetic monopoles carrying a single magnetic charge. Since adjacent walls always carry opposite charges, they attract one another. In most cases this long-range attractive interaction leads to annihilation of the two domain walls. Here, we show that, in some cases, a short-range repulsive interaction suppresses annihilation of the walls, even though the lowest energy state is without any domain walls. This repulsive interaction is a consequence of topological edge defects that have the same winding number. We show that the competition between the attractive and repulsive interactions leads to the formation of metastable bound states made up of two or more domain walls. We have created bound states formed from up to eight domain walls, corresponding to the magnetization winding up over four complete 360° rotations.

  13. Effective actions for bosonic topological defects

    NASA Technical Reports Server (NTRS)

    Gregory, Ruth

    1990-01-01

    A gauge field theory is considered which admits p-dimensional topological defects, expanding the equations of motion in powers of the defect thickness. In this way an effective action and effective equation of motion is derived for the defect in terms of the coordinates of the p-dimensional worldsurface defined by the history of the core of the defect.

  14. Photo-induced Defects in Semiconductors

    NASA Astrophysics Data System (ADS)

    Redfield, David; Bube, Richard H.

    2006-03-01

    1. Introduction: metastable defects; 2. III-V compounds: DX2 and EL2 centers; 3. Other crystalline materials; 4. Hydrogenated amorphous silicon: properties of defects; 5. Hydrogenated amorphous silicon: photo-induced defect kinetics and processes; 6. Other amorphous semiconductors; 7. Photo-induced defect effects in devices; References; Index.

  15. A Curious Pair of Galaxies

    NASA Astrophysics Data System (ADS)

    2009-03-01

    The ESO Very Large Telescope has taken the best image ever of a strange and chaotic duo of interwoven galaxies. The images also contain some surprises -- interlopers both far and near. ESO PR Photo 11a/09 A Curious Pair of Galaxies ESO PR Video 11a/09 Arp 261 zoom in ESO PR Video 11b/09 Pan over Arp 261 Sometimes objects in the sky that appear strange, or different from normal, have a story to tell and prove scientifically very rewarding. This was the idea behind Halton Arp's catalogue of Peculiar Galaxies that appeared in the 1960s. One of the oddballs listed there is Arp 261, which has now been imaged in more detail than ever before using the FORS2 instrument on ESO's Very Large Telescope. The image proves to contain several surprises. Arp 261 lies about 70 million light-years distant in the constellation of Libra, the Scales. Its chaotic and very unusual structure is created by the interaction of two galaxies that are engaged in a slow motion, but highly disruptive close encounter. Although individual stars are very unlikely to collide in such an event, the huge clouds of gas and dust certainly do crash into each other at high speed, leading to the formation of bright new clusters of very hot stars that are clearly seen in the picture. The paths of the existing stars in the galaxies are also dramatically disrupted, creating the faint swirls extending to the upper left and lower right of the image. Both interacting galaxies were probably dwarfs not unlike the Magellanic Clouds orbiting our own galaxy. The images used to create this picture were not actually taken to study the interacting galaxies at all, but to investigate the properties of the inconspicuous object just to the right of the brightest part of Arp 261 and close to the centre of the image. This is an unusual exploding star, called SN 1995N, that is thought to be the result of the final collapse of a massive star at the end of its life, a so-called core collapse supernova. SN 1995N is unusual because

  16. Weird Stellar Pair Puzzles Scientists

    NASA Astrophysics Data System (ADS)

    2008-05-01

    Astronomers have discovered a speedy spinning pulsar in an elongated orbit around an apparent Sun-like star, a combination never seen before, and one that has them puzzled about how the strange system developed. Orbital Comparison Comparing Orbits of Pulsar and Its Companion to our Solar System. CREDIT: Bill Saxton, NRAO/AUI/NSF Click on image for full caption information and available graphics. "Our ideas about how the fastest-spinning pulsars are produced do not predict either the kind of orbit or the type of companion star this one has," said David Champion of the Australia Telescope National Facility. "We have to come up with some new scenarios to explain this weird pair," he added. Astronomers first detected the pulsar, called J1903+0327, as part of a long-term survey using the National Science Foundation's Arecibo radio telescope in Puerto Rico. They made the discovery in 2006 doing data analysis at McGill University, where Champion worked at the time. They followed up the discovery with detailed studies using the Arecibo telescope, the NSF's Robert C. Byrd Green Bank Telescope (GBT) in West Virginia, the Westerbork radio telescope in the Netherlands, and the Gemini North optical telescope in Hawaii. The pulsar, a city-sized superdense stellar corpse left over after a massive star exploded as a supernova, is spinning on its axis 465 times every second. Nearly 21,000 light-years from Earth, it is in a highly-elongated orbit that takes it around its companion star once every 95 days. An infrared image made with the Gemini North telescope in Hawaii shows a Sun-like star at the pulsar's position. If this is an orbital companion to the pulsar, it is unlike any companions of other rapidly rotating pulsars. The pulsar, a neutron star, also is unusually massive for its type. "This combination of properties is unprecedented. Not only does it require us to figure out how this system was produced, but the large mass may help us understand how matter behaves at extremely

  17. 34 CFR 645.12 - What services may regular Upward Bound and Upward Bound Math-Science projects provide?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 34 Education 3 2011-07-01 2011-07-01 false What services may regular Upward Bound and Upward Bound Math-Science projects provide? 645.12 Section 645.12 Education Regulations of the Offices of the... services may regular Upward Bound and Upward Bound Math-Science projects provide? Any project...

  18. 34 CFR 645.12 - What services may regular Upward Bound and Upward Bound Math-Science projects provide?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 34 Education 3 2012-07-01 2012-07-01 false What services may regular Upward Bound and Upward Bound Math-Science projects provide? 645.12 Section 645.12 Education Regulations of the Offices of the... services may regular Upward Bound and Upward Bound Math-Science projects provide? Any project...

  19. 34 CFR 645.12 - What services may regular Upward Bound and Upward Bound Math-Science projects provide?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 34 Education 3 2013-07-01 2013-07-01 false What services may regular Upward Bound and Upward Bound Math-Science projects provide? 645.12 Section 645.12 Education Regulations of the Offices of the... services may regular Upward Bound and Upward Bound Math-Science projects provide? Any project...

  20. 34 CFR 645.12 - What services may regular Upward Bound and Upward Bound Math-Science projects provide?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 34 Education 3 2014-07-01 2014-07-01 false What services may regular Upward Bound and Upward Bound Math-Science projects provide? 645.12 Section 645.12 Education Regulations of the Offices of the... services may regular Upward Bound and Upward Bound Math-Science projects provide? Any project...

  1. Pure Pairing Modes in Trapped Fermion Systems

    NASA Astrophysics Data System (ADS)

    Capuzzi, P.; Hernández, E. S.; Szybisz, L.

    2013-05-01

    We present numerical predictions for the shape of the pairing fluctuations in harmonically trapped atomic 6Li with two spin projections, based on the fluiddynamical description of cold fermions with pairing interactions. In previous works it has been shown that when the equilibrium of a symmetric mixture is perturbed, the linearized fluiddynamic equations decouple into two sets, one containing the sound mode of fermion superfluids and the other the pairing mode. The latter corresponds to oscillations of the modulus of the complex gap and is driven by the kinetic energy densities of the particles and of the pairs. Assuming proportionality between the heat flux and the energy gradient, the particle kinetic energy undergoes a diffusive behavior and the diffusion parameter is the key parameter for the relaxation time scale. We examine a possible range of values for this parameter and find that the shape of the pairing oscillation is rather insensitive to the precise value of the transport coefficient. Moreover, the pairing fluctuation is largely confined to the center of the trap, and the energy of the pairing mode is consistent with the magnitude of the equilibrium gap.

  2. Pair supersolid with atom-pair hopping on the state-dependent triangular lattice

    NASA Astrophysics Data System (ADS)

    Zhang, Wanzhou; Yin, Ruoxi; Wang, Yancheng

    2013-11-01

    We systematically study an extended Bose-Hubbard model with atom hopping and atom-pair hopping in the presence of a three-body constraint on the triangular lattice. By means of large-scale quantum Monte Carlo simulations, the ground-state phase diagram is studied. We find a first-order transition between the atomic superfluid phase and the pair superfluid phase when the ratio of the atomic hopping and the atom-pair hopping is adapted. The first-order transition remains unchanged under various conditions. We then focus on the interplay among the atom-pair hopping, the on-site repulsion, and the nearest-neighbor repulsion. With on-site repulsion present, we observe first-order transitions between the Mott insulators and pair superfluid driven by the pair hopping. With the nearest-neighbor repulsion turning on, three typical solid phases with 2/3, 1, and 4/3 filling emerge at small atom-pair hopping region. A stable pair supersolid phase is found at small on-site repulsion. This is due to the three-body constraint and the pair hopping, which essentially make the model a quasihardcore boson system. Thus the pair supersolid state emerges basing on the order-by-disorder mechanism, by which hardcore bosons avoid classical frustration on the triangular lattice. Without on-site repulsion, the transitions between the pair supersolid and the atom superfluid or pair superfluid are first order, except for the particle-hole symmetric point. With weak on-site repulsion and atom hopping turning on, the transition between the pair supersolid and pair superfluid phase becomes continuous. The transition between solid and pair supersolid is three-dimensional XY university, with dynamical exponent z=1 and correlation exponent ν=0.67155. The thermal melting of pair supersolid belongs to the two-dimensional Ising university. We check both energetic and mechanical balance of pair supersolid phase. Lowering the three-body constraint, no pair supersolid is found due to the absence of

  3. Atomistic Simulations on the Thermal Stability of the Antisite Pair in 3C- and 4H-SiC

    SciTech Connect

    Posselt, Matthias; Gao, Fei; Weber, William J.

    2006-03-31

    The thermal stability of the first-neighbor antisite pair configurations in 3C- and 4H-SiC is investigated by a comprehensive atomistic study. At first the structure and energetics of these defects is determined in order to check the accuracy of the Gao-Weber interatomic potential used. The results are comparable with literature data obtained by the density-functional theory. Then, the lifetime of the antisite pair configurations is calculated for temperatures between 800 and 2500 K. Both in 3C- and 4H-SiC the thermal stability of the antisite pairs is rather low. In contrast to previous theoretical interpretations, the antisite pair can be therefore not correlated with the DI photoluminescence center that is stable to above 2000 K. The atomic mechanisms during the recombination of the antisite pair in 3C-SiC and of three antisite pair configurations in 4H-SiC is a modified concerted exchange. Due to the different sizes of the silicon and the carbon atoms, this process is not identical with the concerted exchange in Si. Two intermediate metastable configurations found during the recombination are similar to the bond defect in Si. Since the SiC lattice contains two types of atoms, there are also two different types of bond defects. The two bond defects can be considered as the result of the incomplete recombination of a carbon vacancy and a neighboring mixed dumbbell interstitial. For selected temperatures the thermal stability of the antisite pair in 3C-SiC is investigated by molecular dynamics simulations that are based on the density-functional theory. Their results are very similar to those of the atomistic study, i.e. the Gao-Weber potential describes the antisite pair and its recombination reasonably well. The antisite pair in 4H-SiC with the two atoms on hexagonal sites has a slightly different formation energy than the other three antisite pair configurations in 4H-SiC. Its lifetime shows another dependence on the temperature, and its recombination is

  4. Pair creation in heavy ion channeling

    NASA Astrophysics Data System (ADS)

    Belov, N. A.; Harman, Z.

    2016-04-01

    Heavy ions channeled through crystals with multi-GeV kinetic energies can create electron-positron pairs. In the framework of the ion, the energy of virtual photons arising from the periodic crystal potential may exceed the threshold 2mec2. The repeated periodic collisions with the crystal ions yield high pair production rates. When the virtual photon frequency matches a nuclear transition in the ion, the production rate can be resonantly increased. In this two-step excitation-pair conversion scheme, the excitation rates are coherently enhanced, and scale approximately quadratically with the number of crystal sites along the channel.

  5. Pair Creation at Large Inherent Angles

    SciTech Connect

    Chen, P.; Tauchi, T.; Schroeder, D.V.; /SLAC

    2007-04-25

    In the next-generation linear colliders, the low-energy e{sup +}e{sup -} pairs created during the collision of high-energy e{sup +}e{sup -} beams would cause potential deleterious background problems to the detectors. At low collider energies, the pairs are made essentially by the incoherent process, where the pair is created by the interaction of beamstrahlung photons on the individual particles in the oncoming beam. This problem was first identified by Zolotarev, et al[1]. At energies where the beamstrahlung parameter {Upsilon} lies approximately in the range 0.6 {approx}< {Upsilon} {approx}< 100, pair creation from the beamstrahlung photons is dominated by a coherent process, first noted by Chen[2]. The seriousness of this pair creation problem lies in the transverse momenta that the pair particles carry when leaving the interaction point (IP) with large angles. One source of transverse momentum is from the kick by the field of the oncoming beam which results in an outcoming angle {theta} {proportional_to} 1/{radical}x, where x is the fractional energy of the particle relative to the initial beam particle energy[2,3]. As was shown in Ref. 131, there in fact exists an energy threshold for the coherent pairs, where x{sub th} {approx}> 1/2{Upsilon}. Thus within a tolerable exiting angle, there exists an upper limit for {Upsilon} where all coherent pairs would leave the detector through the exhaust port[4]. A somewhat different analysis has been done by Schroeder[5]. In the next generation of linear colliders, as it occurs, the coherent pairs can be exponentially suppressed[2] by properly choosing the {Upsilon}({approx}< 0.6). When this is achieved, the incoherent pairs becomes dominant. Since the central issue is the transverse momentum for particles with large angles, we notice that there is another source for it. Namely, when the pair particles are created at low energies, the intrinsic angles of these pairs when produced may already be large. This issue was

  6. Critical criterion for axial models of defects in as-grown n-type GaAs

    SciTech Connect

    Nolte, D.D.; Walukiewicz, W.; Haller, E.E.

    1987-12-15

    Using the recently determined band-edge hydrostatic deformation potentials of GaAs we provide for the first time values for the change in the strength of the isotropic strain coupling of several defects upon electron emission. We further present uniaxial stress deep level transient spectroscopy data on EL2 and EL6 in as-grown n-type GaAs and obtain upper bounds for the axial deformation potentials. The ratio of the change in the isotropic strain-coupling strength to the change in the axial strain coupling for these defects is a critical criterion which must be satisfied by theoretical models that successfully describe axial defects.

  7. Congenital heart defects and medical imaging.

    PubMed

    Gehin, Connie; Ragsdale, Lisa

    2013-01-01

    Radiologic technologists perform imaging studies that are useful in the diagnosis of congenital heart defects in infants and adults. These studies also help to monitor congenital heart defect repairs in adults. This article describes the development and functional anatomy of the heart, along with the epidemiology and anatomy of congenital heart defects. It also discusses the increasing population of adults who have congenital heart defects and the most effective modalities for diagnosing, evaluating, and monitoring congenital heart defects.

  8. Environmental causes of enamel defects.

    PubMed

    Brook, A H; Fearne, J M; Smith, J M

    1997-01-01

    A large number of causes of enamel defects, both environmental and genetic, have been described. However, many of these are derived from case histories and studies of individual conditions. What is needed now is a systematic investigation of the problem. The first requirement in exploring the aetiology further is the standardization of both the clinical diagnosis and the descriptive terminology. This has been provided by the Fédération Dentaire Internationale Developmental Defects of Enamel Index. Comparing studies using standardized methods, including this index, has highlighted areas for closer investigation. The total prevalence of enamel defects in a population needs to be established as a baseline for studies on aetiology. Sixty-eight per cent of 1518 school children in London have enamel defects in the permanent dentition, with 10.5% having 10 or more teeth affected and 14.6% having hypoplasia, i.e. missing enamel. These findings are in contrast to the 37% with hypoplasia found in a group of third to fifth century Romano-Britons from Dorset, England, suggesting further consideration of possible environmental and genetic differences between the two populations. An overall long-term study of dental development in low birth weight children has shown significantly more (P < 0.001) enamel defects related to major health problems during the neonatal period. By using standardized, reproducible criteria in prevalence studies to gain an overview of the problem and then studying specific groups or conditions, it is possible to identify general and specific factors in the aetiology of enamel defects and investigate further the varying role of genetic and environmental effects.

  9. Probing the Dark Sector with Dark Matter Bound States.

    PubMed

    An, Haipeng; Echenard, Bertrand; Pospelov, Maxim; Zhang, Yue

    2016-04-15

    A model of the dark sector where O(few  GeV) mass dark matter particles χ couple to a lighter dark force mediator V, m_{V}≪m_{χ}, is motivated by the recently discovered mismatch between simulated and observed shapes of galactic halos. Such models, in general, provide a challenge for direct detection efforts and collider searches. We show that for a large range of coupling constants and masses, the production and decay of the bound states of χ, such as 0^{-+} and 1^{--} states, η_{D} and ϒ_{D}, is an important search channel. We show that e^{+}e^{-}→η_{D}+V or ϒ_{D}+γ production at B factories for α_{D}>0.1 is sufficiently strong to result in multiple pairs of charged leptons and pions via η_{D}→2V→2(l^{+}l^{-}) and ϒ_{D}→3V→3(l^{+}l^{-}) (l=e,μ,π). The absence of such final states in the existing searches performed at BABAR and Belle sets new constraints on the parameter space of the model. We also show that a search for multiple bremsstrahlung of dark force mediators, e^{+}e^{-}→χχ[over ¯]+nV, resulting in missing energy and multiple leptons, will further improve the sensitivity to self-interacting dark matter.

  10. Conformation of sulfoquinovosyldiacylglycerol bound to a magnetically oriented membrane system.

    PubMed Central

    Howard, K P; Prestegard, J H

    1996-01-01

    The conformation of uniformly 13C-labeled sulfoquinovosyldiacylglycerol (SQDG) is studied in both membrane and solution environments using NMR spectroscopy. Analysis in a membrane-like environment is based on the measurement of dipolar interactions between 13C-13C and 1H-13C spin pairs and on the measurement of 13C chemical shift anisotropy offsets, which appear in magnetically oriented phospholipid-based membrane fragments. Potential energy maps for glycosidic torsions, phi, psi and theta 1, are calculated with a membrane interaction energy and are used in the interpretation of experimental data. The membrane-bound description for SQDG is most consistent with a set of low-energy conformations that extends the headgroup of SQDG away from the membrane surface. Analysis of the conformation of SQDG in CD3OD solution is based on measured 3JCH scalar couplings. The description of the solution conformation is modeled as a mixture of low-energy conformers predicted in the absence of a membrane interaction term and involves more extensive motional averaging than the model for SQDG embedded in the lipid matrix. Images FIGURE 1 FIGURE 6 PMID:8913595

  11. Probing the Dark Sector with Dark Matter Bound States

    NASA Astrophysics Data System (ADS)

    An, Haipeng; Echenard, Bertrand; Pospelov, Maxim; Zhang, Yue

    2016-04-01

    A model of the dark sector where O (few GeV ) mass dark matter particles χ couple to a lighter dark force mediator V , mV≪mχ, is motivated by the recently discovered mismatch between simulated and observed shapes of galactic halos. Such models, in general, provide a challenge for direct detection efforts and collider searches. We show that for a large range of coupling constants and masses, the production and decay of the bound states of χ , such as 0-+ and 1-- states, ηD and ϒD, is an important search channel. We show that e+e-→ηD+V or ϒD+γ production at B factories for αD>0.1 is sufficiently strong to result in multiple pairs of charged leptons and pions via ηD→2 V →2 (l+l-) and ϒD→3 V →3 (l+l-) (l =e ,μ ,π ). The absence of such final states in the existing searches performed at BABAR and Belle sets new constraints on the parameter space of the model. We also show that a search for multiple bremsstrahlung of dark force mediators, e+e-→χ χ ¯+n V , resulting in missing energy and multiple leptons, will further improve the sensitivity to self-interacting dark matter.

  12. Scalable problems and memory bounded speedup

    NASA Technical Reports Server (NTRS)

    Sun, Xian-He; Ni, Lionel M.

    1992-01-01

    In this paper three models of parallel speedup are studied. They are fixed-size speedup, fixed-time speedup and memory-bounded speedup. The latter two consider the relationship between speedup and problem scalability. Two sets of speedup formulations are derived for these three models. One set considers uneven workload allocation and communication overhead and gives more accurate estimation. Another set considers a simplified case and provides a clear picture on the impact of the sequential portion of an application on the possible performance gain from parallel processing. The simplified fixed-size speedup is Amdahl's law. The simplified fixed-time speedup is Gustafson's scaled speedup. The simplified memory-bounded speedup contains both Amdahl's law and Gustafson's scaled speedup as special cases. This study leads to a better understanding of parallel processing.

  13. On generalized quasi-convex bounded sequences

    NASA Astrophysics Data System (ADS)

    Karakuş, Mahmut

    2016-08-01

    The space of all sequences a = (ak) for which ‖a ‖q= ∑k k |Δ2ak | +supk|ak | <∞ is denoted by q. Here, Δak = ak - ak+1 and Δmak = Δ(Δm-1ak) = Δm-1ak - Δm-1ak+1 with Δ0ak = ak, m ≥ 1. If a = (ak) ∈q then kΔak → 0 (k → ∞) and q ⊂ bv, the space of all sequences of bounded-variation, since ∑k | Δ ak | ≤ ∑k k | Δ2ak | In this study, we give a generalization of quasi-convex bounded sequences.

  14. Mutual Information Rate and Bounds for It

    PubMed Central

    Baptista, Murilo S.; Rubinger, Rero M.; Viana, Emilson R.; Sartorelli, José C.; Parlitz, Ulrich; Grebogi, Celso

    2012-01-01

    The amount of information exchanged per unit of time between two nodes in a dynamical network or between two data sets is a powerful concept for analysing complex systems. This quantity, known as the mutual information rate (MIR), is calculated from the mutual information, which is rigorously defined only for random systems. Moreover, the definition of mutual information is based on probabilities of significant events. This work offers a simple alternative way to calculate the MIR in dynamical (deterministic) networks or between two time series (not fully deterministic), and to calculate its upper and lower bounds without having to calculate probabilities, but rather in terms of well known and well defined quantities in dynamical systems. As possible applications of our bounds, we study the relationship between synchronisation and the exchange of information in a system of two coupled maps and in experimental networks of coupled oscillators. PMID:23112809

  15. Bounded excursion stable gravastars and black holes

    SciTech Connect

    Rocha, P; Da Silva, M F; Wang, Anzhong; Santos, N O E-mail: yasuda@on.br E-mail: mfasnic@gmail.com E-mail: anzhong_wang@baylor.edu

    2008-06-15

    Dynamical models of prototype gravastars were constructed in order to study their stability. The models are the Visser-Wiltshire three-layer gravastars, in which an infinitely thin spherical shell of stiff fluid divides the whole spacetime into two regions, where the internal region is de Sitter, and the external one is Schwarzschild. It is found that in some cases the models represent the 'bounded excursion' stable gravastars, where the thin shell is oscillating between two finite radii, while in other cases they collapse until the formation of black holes occurs. In the phase space, the region for the 'bounded excursion' gravastars is very small in comparison to that of black holes, but not empty. Therefore, although the possibility of the existence of gravastars cannot be excluded from such dynamical models, our results indicate that, even if gravastars do indeed exist, that does not exclude the possibility of the existence of black holes.

  16. Is Fusion Inhibited for Weakly Bound Nuclei?

    SciTech Connect

    Takahashi, J.; Munhoz, M.; Szanto, E.M.; Carlin, N.; Added, N.; Suaide, A.A.; de Moura, M.M.; Liguori Neto, R.; Szanto de Toledo, A.; Canto, L.F.

    1997-01-01

    Complete fusion of light radioactive nuclei is predicted to be hindered at near-barrier energies. This feature is investigated in the case of the least bound stable nuclei. Evaporation residues resulting from the {sup 6,7}Li+{sup 9}Be and {sup 6,7}Li+{sup 12}C fusion reactions have been measured in order to study common features in reactions involving light weakly bound nuclei. The experimental excitation functions revealed that the fusion cross section is significantly smaller than the total reaction cross section and also smaller than the fusion cross section expected from the available systematics. A clear correlation between the fusion probability and nucleon (cluster) separation energy has been established.The results suggest that the breakup process has a strong influence on the hindrance of the fusion cross section. {copyright} {ital 1996} {ital The American Physical Society}

  17. Performance bound for quantum absorption refrigerators

    NASA Astrophysics Data System (ADS)

    Correa, Luis A.; Palao, José P.; Adesso, Gerardo; Alonso, Daniel

    2013-04-01

    An implementation of quantum absorption chillers with three qubits has been recently proposed that is ideally able to reach the Carnot performance regime. Here we study the working efficiency of such self-contained refrigerators, adopting a consistent treatment of dissipation effects. We demonstrate that the coefficient of performance at maximum cooling power is upper bounded by 3/4 of the Carnot performance. The result is independent of the details of the system and the equilibrium temperatures of the external baths. We provide design prescriptions that saturate the bound in the limit of a large difference between the operating temperatures. Our study suggests that delocalized dissipation, which must be taken into account for a proper modeling of the machine-baths interaction, is a fundamental source of irreversibility which prevents the refrigerator from approaching the Carnot performance arbitrarily closely in practice. The potential role of quantum correlations in the operation of these machines is also investigated.

  18. Extremum seeking with bounded update rates

    SciTech Connect

    Scheinker, Alexander; Krstić, Miroslav

    2013-11-16

    In this work, we present a form of extremum seeking (ES) in which the unknown function being minimized enters the system’s dynamics as the argument of a cosine or sine term, thereby guaranteeing known bounds on update rates and control efforts. We present general n-dimensional optimization and stabilization results as well as 2D vehicle control, with bounded velocity and control efforts. For application to autonomous vehicles, tracking a source in a GPS denied environment with unknown orientation, this ES approach allows for smooth heading angle actuation, with constant velocity, and in application to a unicycle-type vehicle results in control ability as if the vehicle is fully actuated. Our stability analysis is made possible by the classic results of Kurzweil, Jarnik, Sussmann, and Liu, regarding systems with highly oscillatory terms. In our stability analysis, we combine the averaging results with a semi-global practical stability result under small parametric perturbations developed by Moreau and Aeyels.

  19. Tsirelson's bound and supersymmetric entangled states

    PubMed Central

    Borsten, L.; Brádler, K.; Duff, M. J.

    2014-01-01

    A superqubit, belonging to a (2|1)-dimensional super-Hilbert space, constitutes the minimal supersymmetric extension of the conventional qubit. In order to see whether superqubits are more non-local than ordinary qubits, we construct a class of two-superqubit entangled states as a non-local resource in the CHSH game. Since super Hilbert space amplitudes are Grassmann numbers, the result depends on how we extract real probabilities and we examine three choices of map: (1) DeWitt (2) Trigonometric and (3) Modified Rogers. In cases (1) and (2), the winning probability reaches the Tsirelson bound pwin=cos2π/8≃0.8536 of standard quantum mechanics. Case (3) crosses Tsirelson's bound with pwin≃0.9265. Although all states used in the game involve probabilities lying between 0 and 1, case (3) permits other changes of basis inducing negative transition probabilities. PMID:25294964

  20. Reinforcement Learning with Bounded Information Loss

    NASA Astrophysics Data System (ADS)

    Peters, Jan; Mülling, Katharina; Seldin, Yevgeny; Altun, Yasemin

    2011-03-01

    Policy search is a successful approach to reinforcement learning. However, policy improvements often result in the loss of information. Hence, it has been marred by premature convergence and implausible solutions. As first suggested in the context of covariant or natural policy gradients, many of these problems may be addressed by constraining the information loss. In this paper, we continue this path of reasoning and suggest two reinforcement learning methods, i.e., a model-based and a model free algorithm that bound the loss in relative entropy while maximizing their return. The resulting methods differ significantly from previous policy gradient approaches and yields an exact update step. It works well on typical reinforcement learning benchmark problems as well as novel evaluations in robotics. We also show a Bayesian bound motivation of this new approach [8].

  1. Interface effects on calculated defect levels for oxide defects

    NASA Astrophysics Data System (ADS)

    Edwards, Arthur; Barnaby, Hugh; Schultz, Peter; Pineda, Andrew

    2014-03-01

    Density functional theory (DFT) has had impressive recent success predicting defect levels in insulators and semiconductors [Schultz and von Lillienfeld, 2009]. Such success requires care in accounting for long-range electrostatic effects. Recently, Komsa and Pasquarello have started to address this problem in systems with interfaces. We report a multiscale technique for calculating electrostatic energies for charged defects in oxide of the metal-oxide-silicon (MOS) system, but where account is taken of substrate doping density, oxide thickness, and gate bias. We use device modeling to calculate electric fields for a point charge a fixed distance from the interface, and used the field to numerically calculate the long-range electrostatic interactions. We find, for example, that defect levels in the oxide do depend on both the magnitude and the polarity the substrate doping density. Furthermore, below 20 Å, oxide thickness also has significant effects. So, transferring results directly from bulk calculations leads to inaccuracies up to 0.5 eV- half of the silicon band gap. We will present trends in defect levels as a function of device parameters. We show that these results explain previous experimental results, and we comment on their potential impact on models for NBTI. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the United States Department of Energy's National Nuclear Security Administration under co.

  2. Carbon related defects in irradiated silicon revisited

    PubMed Central

    Wang, H.; Chroneos, A.; Londos, C. A.; Sgourou, E. N.; Schwingenschlögl, U.

    2014-01-01

    Electronic structure calculations employing hybrid functionals are used to gain insight into the interaction of carbon (C) atoms, oxygen (O) interstitials, and self-interstitials in silicon (Si). We calculate the formation energies of the C related defects Ci(SiI), CiOi, CiCs, and CiOi(SiI) with respect to the Fermi energy for all possible charge states. The Ci(SiI)2+ state dominates in almost the whole Fermi energy range. The unpaired electron in the CiOi+ state is mainly localized on the C interstitial so that spin polarization is able to lower the total energy. The three known atomic configurations of the CiCs pair are reproduced and it is demonstrated that hybrid functionals yield an improved energetic order for both the A and B-types as compared to previous theoretical studies. Different structures of the CiOi(SiI) cluster result for positive charge states in dramatically distinct electronic states around the Fermi energy and formation energies. PMID:24809804

  3. A bound particle coupled to two thermostats

    NASA Astrophysics Data System (ADS)

    Fogedby, Hans C.; Imparato, Alberto

    2011-05-01

    We consider a harmonically bound Brownian particle coupled to two distinct heat reservoirs at different temperatures. We show that the presence of a harmonic trap does not change the large deviation function from the case of a free Brownian particle discussed by Derrida and Brunet and Visco. Likewise, the Gallavotti-Cohen fluctuation theorem related to the entropy production at the heat sources remains in force. We support the analytical results with numerical simulations.

  4. Multipartite secret key distillation and bound entanglement

    SciTech Connect

    Augusiak, Remigiusz; Horodecki, Pawel

    2009-10-15

    Recently it has been shown that quantum cryptography beyond pure entanglement distillation is possible and a paradigm for the associated protocols has been established. Here we systematically generalize the whole paradigm to the multipartite scenario. We provide constructions of new classes of multipartite bound entangled states, i.e., those with underlying twisted Greenberger-Horne-Zeilinger (GHZ) structure and nonzero distillable cryptographic key. We quantitatively estimate the key from below with the help of the privacy squeezing technique.

  5. Improvement of cosmological neutrino mass bounds

    NASA Astrophysics Data System (ADS)

    Giusarma, Elena; Gerbino, Martina; Mena, Olga; Vagnozzi, Sunny; Ho, Shirley; Freese, Katherine

    2016-10-01

    The most recent measurements of the temperature and low-multipole polarization anisotropies of the cosmic microwave background from the Planck satellite, when combined with galaxy clustering data from the Baryon Oscillation Spectroscopic Survey in the form of the full shape of the power spectrum, and with baryon acoustic oscillation measurements, provide a 95% confidence level (C.L.) upper bound on the sum of the three active neutrinos ∑mν<0.183 eV , among the tightest neutrino mass bounds in the literature, to date, when the same data sets are taken into account. This very same data combination is able to set, at ˜70 % C.L., an upper limit on ∑mν of 0.0968 eV, a value that approximately corresponds to the minimal mass expected in the inverted neutrino mass hierarchy scenario. If high-multipole polarization data from Planck is also considered, the 95% C.L. upper bound is tightened to ∑mν<0.176 eV . Further improvements are obtained by considering recent measurements of the Hubble parameter. These limits are obtained assuming a specific nondegenerate neutrino mass spectrum; they slightly worsen when considering other degenerate neutrino mass schemes. Low-redshift quantities, such as the Hubble constant or the reionization optical depth, play a very important role when setting the neutrino mass constraints. We also comment on the eventual shifts in the cosmological bounds on ∑mν when possible variations in the former two quantities are addressed.

  6. Efficiency bounds for nonequilibrium heat engines

    SciTech Connect

    Mehta, Pankaj; Polkovnikov, Anatoli

    2013-05-15

    We analyze the efficiency of thermal engines (either quantum or classical) working with a single heat reservoir like an atmosphere. The engine first gets an energy intake, which can be done in an arbitrary nonequilibrium way e.g. combustion of fuel. Then the engine performs the work and returns to the initial state. We distinguish two general classes of engines where the working body first equilibrates within itself and then performs the work (ergodic engine) or when it performs the work before equilibrating (non-ergodic engine). We show that in both cases the second law of thermodynamics limits their efficiency. For ergodic engines we find a rigorous upper bound for the efficiency, which is strictly smaller than the equivalent Carnot efficiency. I.e. the Carnot efficiency can be never achieved in single reservoir heat engines. For non-ergodic engines the efficiency can be higher and can exceed the equilibrium Carnot bound. By extending the fundamental thermodynamic relation to nonequilibrium processes, we find a rigorous thermodynamic bound for the efficiency of both ergodic and non-ergodic engines and show that it is given by the relative entropy of the nonequilibrium and initial equilibrium distributions. These results suggest a new general strategy for designing more efficient engines. We illustrate our ideas by using simple examples. -- Highlights: ► Derived efficiency bounds for heat engines working with a single reservoir. ► Analyzed both ergodic and non-ergodic engines. ► Showed that non-ergodic engines can be more efficient. ► Extended fundamental thermodynamic relation to arbitrary nonequilibrium processes.

  7. Bounds on universal extra dimension from LHC run I and II data

    NASA Astrophysics Data System (ADS)

    Choudhury, Debajyoti; Ghosh, Kirtiman

    2016-12-01

    We discuss the collider bounds on minimal Universal Extra Dimension (mUED) model from LHC Run-I and II data. The phenomenology of mUED is determined by only two parameters namely, the compactification scale (R-1) of the extra dimension and cutoff scale (Λ) of the theory. The characteristic feature of mUED is the occurrence of nearly degenerate mass spectrum for the Kaluza-Klein (KK) particles and hence, soft leptons, soft jets at the collider experiments. The degree of degeneracy of KK-mass spectrum crucially depends on Λ. The strongest direct bound on R-1 (∼ 950GeV for large Λ) arises from a search for a pair of soft dimuons at the Large Hadron Collider (LHC) experiment with 8 TeV center-of-mass energy and 20 fb-1 integrated luminosity. However, for small Λ and hence, small splitting within the first KK-level, the bounds from the dimuon channel are rather weak. On the other hand, the discovery of 126 GeV Higgs boson demands small Λ to prevent the scalar potential form being unbounded from below. We discuss LHC monojet searches as a probe of low Λ region of mUED parameter space. We also compute bounds on the mUED parameter space from 13 TeV multijets results.

  8. Electron correlation within the relativistic no-pair approximation

    NASA Astrophysics Data System (ADS)

    Almoukhalalati, Adel; Knecht, Stefan; Jensen, Hans Jørgen Aa.; Dyall, Kenneth G.; Saue, Trond

    2016-08-01

    This paper addresses the definition of correlation energy within 4-component relativistic atomic and molecular calculations. In the nonrelativistic domain the correlation energy is defined as the difference between the exact eigenvalue of the electronic Hamiltonian and the Hartree-Fock energy. In practice, what is reported is the basis set correlation energy, where the "exact" value is provided by a full Configuration Interaction (CI) calculation with some specified one-particle basis. The extension of this definition to the relativistic domain is not straightforward since the corresponding electronic Hamiltonian, the Dirac-Coulomb Hamiltonian, has no bound solutions. Present-day relativistic calculations are carried out within the no-pair approximation, where the Dirac-Coulomb Hamiltonian is embedded by projectors eliminating the troublesome negative-energy solutions. Hartree-Fock calculations are carried out with the implicit use of such projectors and only positive-energy orbitals are retained at the correlated level, meaning that the Hartree-Fock projectors are frozen at the correlated level. We argue that the projection operators should be optimized also at the correlated level and that this is possible by full Multiconfigurational Self-Consistent Field (MCSCF) calculations, that is, MCSCF calculations using a no-pair full CI expansion, but including orbital relaxation from the negative-energy orbitals. We show by variational perturbation theory that the MCSCF correlation energy is a pure MP2-like correlation expression, whereas the corresponding CI correlation energy contains an additional relaxation term. We explore numerically our theoretical analysis by carrying out variational and perturbative calculations on the two-electron rare gas atoms with specially tailored basis sets. In particular, we show that the correlation energy obtained by the suggested MCSCF procedure is smaller than the no-pair full CI correlation energy, in accordance with the underlying

  9. Electron correlation within the relativistic no-pair approximation.

    PubMed

    Almoukhalalati, Adel; Knecht, Stefan; Jensen, Hans Jørgen Aa; Dyall, Kenneth G; Saue, Trond

    2016-08-21

    This paper addresses the definition of correlation energy within 4-component relativistic atomic and molecular calculations. In the nonrelativistic domain the correlation energy is defined as the difference between the exact eigenvalue of the electronic Hamiltonian and the Hartree-Fock energy. In practice, what is reported is the basis set correlation energy, where the "exact" value is provided by a full Configuration Interaction (CI) calculation with some specified one-particle basis. The extension of this definition to the relativistic domain is not straightforward since the corresponding electronic Hamiltonian, the Dirac-Coulomb Hamiltonian, has no bound solutions. Present-day relativistic calculations are carried out within the no-pair approximation, where the Dirac-Coulomb Hamiltonian is embedded by projectors eliminating the troublesome negative-energy solutions. Hartree-Fock calculations are carried out with the implicit use of such projectors and only positive-energy orbitals are retained at the correlated level, meaning that the Hartree-Fock projectors are frozen at the correlated level. We argue that the projection operators should be optimized also at the correlated level and that this is possible by full Multiconfigurational Self-Consistent Field (MCSCF) calculations, that is, MCSCF calculations using a no-pair full CI expansion, but including orbital relaxation from the negative-energy orbitals. We show by variational perturbation theory that the MCSCF correlation energy is a pure MP2-like correlation expression, whereas the corresponding CI correlation energy contains an additional relaxation term. We explore numerically our theoretical analysis by carrying out variational and perturbative calculations on the two-electron rare gas atoms with specially tailored basis sets. In particular, we show that the correlation energy obtained by the suggested MCSCF procedure is smaller than the no-pair full CI correlation energy, in accordance with the underlying

  10. Of Models and Machines: Implementing Bounded Rationality.

    PubMed

    Dick, Stephanie

    2015-09-01

    This essay explores the early history of Herbert Simon's principle of bounded rationality in the context of his Artificial Intelligence research in the mid 1950s. It focuses in particular on how Simon and his colleagues at the RAND Corporation translated a model of human reasoning into a computer program, the Logic Theory Machine. They were motivated by a belief that computers and minds were the same kind of thing--namely, information-processing systems. The Logic Theory Machine program was a model of how people solved problems in elementary mathematical logic. However, in making this model actually run on their 1950s computer, the JOHNNIAC, Simon and his colleagues had to navigate many obstacles and material constraints quite foreign to the human experience of logic. They crafted new tools and engaged in new practices that accommodated the affordances of their machine, rather than reflecting the character of human cognition and its bounds. The essay argues that tracking this implementation effort shows that "internal" cognitive practices and "external" tools and materials are not so easily separated as they are in Simon's principle of bounded rationality--the latter often shaping the dynamics of the former.

  11. Classical calculation of the equilibrium constants for true bound dimers using complete potential energy surface.

    PubMed

    Buryak, Ilya; Vigasin, Andrey A

    2015-12-21

    The present paper aims at deriving classical expressions which permit calculation of the equilibrium constant for weakly interacting molecular pairs using a complete multidimensional potential energy surface. The latter is often available nowadays as a result of the more and more sophisticated and accurate ab initio calculations. The water dimer formation is considered as an example. It is shown that even in case of a rather strongly bound dimer the suggested expression permits obtaining quite reliable estimate for the equilibrium constant. The reliability of our obtained water dimer equilibrium constant is briefly discussed by comparison with the available data based on experimental observations, quantum calculations, and the use of RRHO approximation, provided the latter is restricted to formation of true bound states only.

  12. Classical calculation of the equilibrium constants for true bound dimers using complete potential energy surface

    SciTech Connect

    Buryak, Ilya; Vigasin, Andrey A.

    2015-12-21

    The present paper aims at deriving classical expressions which permit calculation of the equilibrium constant for weakly interacting molecular pairs using a complete multidimensional potential energy surface. The latter is often available nowadays as a result of the more and more sophisticated and accurate ab initio calculations. The water dimer formation is considered as an example. It is shown that even in case of a rather strongly bound dimer the suggested expression permits obtaining quite reliable estimate for the equilibrium constant. The reliability of our obtained water dimer equilibrium constant is briefly discussed by comparison with the available data based on experimental observations, quantum calculations, and the use of RRHO approximation, provided the latter is restricted to formation of true bound states only.

  13. Primitive potentials and bounded solutions of the KdV equation

    NASA Astrophysics Data System (ADS)

    Dyachenko, S.; Zakharov, D.; Zakharov, V.

    2016-10-01

    We construct a broad class of bounded potentials of the one-dimensional Schrödinger operator that have the same spectral structure as periodic finite-gap potentials, but that are neither periodic nor quasi-periodic. Such potentials, which we call primitive, are non-uniquely parametrized by a pair of positive Hölder continuous functions defined on the allowed bands. Primitive potentials are constructed as solutions of a system of singular integral equations, which can be efficiently solved numerically. Simulations show that these potentials can have a disordered structure. Primitive potentials generate a broad class of bounded non-vanishing solutions of the KdV hierarchy, and we interpret them as an example of integrable turbulence in the framework of the KdV equation.

  14. Molecular Dynamics Simulation of Point Defect Accumulation in 3C-SiC

    SciTech Connect

    Devanathan, Ram; Gao, Fei; Weber, William J.

    2004-04-05

    Defect accumulation in silicon carbide has been simulated by molecular dynamics using a Brenner-type potential connected smoothly to the Ziegler-Biersack-Littmark potential. Displacement damage in 3C-SiC, which is known to consist of point defects, vacancy and interstitial clusters and anti-site defects, was modelled by introducing random displacements in the Si or C sublattice. SiC was amorphized by Si displacements at a damage level corresponding to 0.15 displacements per atom (dpa) and by C displacements at 0.25 dpa. In both cases, the damage consists of Si and C Frenkel pairs as well as anti-site defects. The results provide evidence that SiC can be amorphized by displacing C atoms exclusively and suggest that short-range disorder provides the driving force for amorphization of SiC.

  15. Correlated Defect Nano-Regions in a Metal–Organic Framework

    PubMed Central

    Cliffe, Matthew J.; Wan, Wei; Zou, Xiaodong; Chater, Philip A.; Kleppe, Annette K.; Tucker, Matthew G.; Wilhelm, Heribert; Funnell, Nicholas P.; Coudert, François-Xavier; Goodwin, Andrew L.

    2016-01-01

    Throughout much of condensed matter science, correlated disorder is key to material function. While structural and compositional defects are known to exist within a variety of metal–organic frameworks, the prevailing understanding is that these defects are only ever included in a random manner. Here we show—using a combination of diffuse scattering, electron microscopy, anomalous X-ray scattering, and pair distribution function measurements—that correlations between defects can in fact be introduced and controlled within a hafnium terephthalate metal–organic framework. The nanoscale defect structures that emerge are an analogue of correlated Schottky vacancies in rocksalt-structured transition metal monoxides and have implications for storage, transport, optical and mechanical responses. Our results suggest how the diffraction behaviour of some metal–organic frameworks might be reinterpreted, and establish a strategy of exploiting correlated nanoscale disorder as a targetable and desirable motif in metal–organic framework design. PMID:24946837

  16. Investigating the Defect Structures in Transparent Conducting Oxides Using X-ray and Neutron Scattering Techniques

    SciTech Connect

    González, Gabriela B.

    2012-10-23

    Transparent conducting oxide (TCO) materials are implemented into a wide variety of commercial devices because they possess a unique combination of high optical transparency and high electrical conductivity. Created during the processing of the TCOs, defects within the atomic-scale structure are responsible for their desirable optical and electrical properties. Therefore, studying the defect structure is essential to a better understanding of the behavior of transparent conductors. X-ray and neutron scattering techniques are powerful tools to investigate the atomic lattice structural defects in these materials. This review paper presents some of the current developments in the study of structural defects in n-type TCOs using x-ray diffraction (XRD), neutron diffraction, extended x-ray absorption fine structure (EXAFS), pair distribution functions (PDFs), and x-ray fluorescence (XRF).

  17. Temporal Multimode Storage of Entangled Photon Pairs

    NASA Astrophysics Data System (ADS)

    Tiranov, Alexey; Strassmann, Peter C.; Lavoie, Jonathan; Brunner, Nicolas; Huber, Marcus; Verma, Varun B.; Nam, Sae Woo; Mirin, Richard P.; Lita, Adriana E.; Marsili, Francesco; Afzelius, Mikael; Bussières, Félix; Gisin, Nicolas

    2016-12-01

    Multiplexed quantum memories capable of storing and processing entangled photons are essential for the development of quantum networks. In this context, we demonstrate and certify the simultaneous storage and retrieval of two entangled photons inside a solid-state quantum memory and measure a temporal multimode capacity of ten modes. This is achieved by producing two polarization-entangled pairs from parametric down-conversion and mapping one photon of each pair onto a rare-earth-ion-doped (REID) crystal using the atomic frequency comb (AFC) protocol. We develop a concept of indirect entanglement witnesses, which can be used as Schmidt number witnesses, and we use it to experimentally certify the presence of more than one entangled pair retrieved from the quantum memory. Our work puts forward REID-AFC as a platform compatible with temporal multiplexing of several entangled photon pairs along with a new entanglement certification method, useful for the characterization of multiplexed quantum memories.

  18. Spectra from pair-equilibrium plasmas

    NASA Technical Reports Server (NTRS)

    Zdziarski, A. A.

    1984-01-01

    A numerical model of relativistic nonmagnetized plasma with uniform temperature and electron density distributions is considered, and spectra from plasma in pair equilibrium are studied. A range of dimensionless temperature (T) greater than about 0.2 is considered. The spectra from low pair density plasmas in pair equilibrium vary from un-Comptonized bremsstrahlung spectra at Thomson cross section tau(N) much less than one to Comptonized bremsstrahlung spectra with tau(N) over one. For high pair density plasmas the spectra are flat for T greater than about one, and have broad intensity peaks at energy roughly equal to 3T for T less than one. In the latter region the total luminosity is approximately twice the annihilation luminosity. All spectra are flat in the X-ray region, in contradiction to observed AGN spectra. For dimensionless luminosity greater than about 100, the cooling time becomes shorter than the Thomson time.

  19. Alloy solution hardening with solute pairs

    DOEpatents

    Mitchell, John W.

    1976-08-24

    Solution hardened alloys are formed by using at least two solutes which form associated solute pairs in the solvent metal lattice. Copper containing equal atomic percentages of aluminum and palladium is an example.

  20. Mixed parity pairing in a dipolar gas

    NASA Astrophysics Data System (ADS)

    Bruun, G. M.; Hainzl, C.; Laux, M.

    2016-10-01

    We show that fermionic dipoles in a two-layer geometry form Cooper pairs with both singlet and triplet components when they are tilted with respect to the normal of the planes. The mixed parity pairing arises because the interaction between dipoles in the two different layers is not inversion symmetric. We use an efficient eigenvalue approach to calculate the zero-temperature phase diagram of the system as a function of the dipole orientation and the layer distance. The phase diagram contains purely triplet as well as mixed singlet and triplet superfluid phases. We show in detail how the pair wave function for dipoles residing in different layers smoothly changes from singlet to triplet symmetry as the orientation of the dipoles is changed. Our results indicate that dipolar quantum gases can be used to unambiguously observe mixed parity pairing.