Gasification of Simplex briquets: briquet production. Vol. 1. Final report
DOE Office of Scientific and Technical Information (OSTI.GOV)
Not Available
A 7-ton/hr briquetting plant was installed at International Briquetting in Baltimore, Maryland, and used to produce 360 tons of Simplex briquets from Pittsburgh No. 8 seam, Champion No. 1 mine caking coal and shredded, air-classified Baltimore County refuse. The production of these briquets was funded by the Department of Energy, through the US Bureau of Mines, and a consortium comprised of the New York State Energy Research and Development Authority and the Empire State Electric Energy Research Company. This report describes the briquetting plant and discusses the problems that were encountered in producing the briquets. The following modifications are recommendedmore » for future Simplex briquetting plants: drying equipment should be installed on the RDF feed system to ensure that the RDF moisture is below 18%; the crushed coal must be dried to less than 4% moisture to ensure its free flow in the bins; magnets should be installed above the coal and RDF feed conveyors to remove any tramp metal; a 3/4-inch screen should be installed over the coal feed bin to remove any oversize rocks or lump coal; the RDF handling system and turbulizer discharge to the press should all be enclosed for dust control (the enclosures should be vented to a baghouse); only heavy duty apron conveyors should be used where belt conveyors are needed; briquetts should be cured if they are going to be stored in containers where they might sweat; and a screen with 1 1/4-inch openings should be used to remove the fines from 2 1/4-inch briquets (this screen should be sufficiently large to prevent briquets from crowding together on the screen).« less
Federal Register 2010, 2011, 2012, 2013, 2014
2010-05-28
... DEPARTMENT OF LABOR Employment and Training Administration [TA-W-72,247] National Briquetting Corporation, a Subsidiary of Harsco, Also Known as Performix East Chicago, East Chicago, IN; Notice of... the TAA petition filed on behalf of workers at National Briquetting Corporation, a subsidiary of...
Justification of rational parameters of briquetting using mechanic activation techniques
NASA Astrophysics Data System (ADS)
Nikolaeva, L. A.; Burenina, O. N.
2017-12-01
The paper illustrates results of development of technology and compositions of briquetting substandard lignite waste with the use of tar as a binder, modified with mechanically activated organic-mineral fillers. The influence of highly disperse additives and technological briquetting regimes on the structure formation and the qualitative characteristics of fuel brown coal briquettes is considered.
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 30 2014-07-01 2014-07-01 false Applicability; description of the manufacture of char and charcoal briquets subcategory. 454.10 Section 454.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) GUM AND WOOD CHEMICALS...
Code of Federal Regulations, 2012 CFR
2012-07-01
... 40 Protection of Environment 31 2012-07-01 2012-07-01 false Applicability; description of the manufacture of char and charcoal briquets subcategory. 454.10 Section 454.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) GUM AND WOOD CHEMICALS...
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 31 2013-07-01 2013-07-01 false Applicability; description of the manufacture of char and charcoal briquets subcategory. 454.10 Section 454.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) GUM AND WOOD CHEMICALS...
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 30 2011-07-01 2011-07-01 false Applicability; description of the manufacture of char and charcoal briquets subcategory. 454.10 Section 454.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS GUM AND WOOD CHEMICALS...
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 29 2010-07-01 2010-07-01 false Applicability; description of the manufacture of char and charcoal briquets subcategory. 454.10 Section 454.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS GUM AND WOOD CHEMICALS...
Harbison, Justin E; Zazra, Dave; Henry, Marlon; Xamplas, Christopher; Kafensztok, Ruth
2015-09-01
Because it is often logistically impossible to monitor all catch basins within an operational area, local mosquito control programs will preemptively treat catch basins with larvicides each season. However, these larvicides can, ostensibly, be considered water quality pollutants. To experimentally reduce the use of larvicides toward improving water quality, 30 basins within a small 0.7-km(2) residential area were monitored weekly for the presence of larvae and pupae for 14 wk in the summer of 2013. Once a basin was found to reach a threshold of 12 mosquitoes per dip sample, it received a FourStar® Briquet (a 180-day briquet formulation of 6% Bacillus sphaericus and 1% B. thuringiensis israelensis). Each week a FourStar-treated basin surpassed this threshold, it was treated with an application of CocoBear™ oil (10% mineral oil). By the end of trials, all but one basin received a briquet and 13 required at least 4 treatments of CocoBear, suggesting that preemptive treatment is appropriate for the study area.
6. VIEW OF THE BRIQUETTING PRESS AND CHIP CLEANING HOOD. ...
6. VIEW OF THE BRIQUETTING PRESS AND CHIP CLEANING HOOD. SCRAPS OF ENRICHED URANIUM FROM MACHINING OPERATIONS WERE CLEANED IN A SOLVENT BATH, THEN PRESSED INTO BRIQUETTS. THE BRIQUETTS WERE USED AS FEED MATERIAL FOR THE FOUNDRY. (4/4/66) - Rocky Flats Plant, General Manufacturing, Support, Records-Central Computing, Southern portion of Plant, Golden, Jefferson County, CO
Sevda Alanya-Rosenbaum; Richard D. Bergman; Indroneil Ganguly; Francesca Pierobon
2018-01-01
Timber harvest activities in the western United States have resulted in large volumes of low- to no-value logging (forest) residues. Alternatives to pile-and-burning are needed to best utilize this material and to mitigate the resultant environmental impacts. Briquetting (densifying) forest residues near-woods is one such option and is the focus of this study. This...
An Experimental Study of Briquetting Process of Torrefied Rubber Seed Kernel and Palm Oil Shell.
Hamid, M Fadzli; Idroas, M Yusof; Ishak, M Zulfikar; Zainal Alauddin, Z Alimuddin; Miskam, M Azman; Abdullah, M Khalil
2016-01-01
Torrefaction process of biomass material is essential in converting them into biofuel with improved calorific value and physical strength. However, the production of torrefied biomass is loose, powdery, and nonuniform. One method of upgrading this material to improve their handling and combustion properties is by densification into briquettes of higher density than the original bulk density of the material. The effects of critical parameters of briquetting process that includes the type of biomass material used for torrefaction and briquetting, densification temperature, and composition of binder for torrefied biomass are studied and characterized. Starch is used as a binder in the study. The results showed that the briquette of torrefied rubber seed kernel (RSK) is better than torrefied palm oil shell (POS) in both calorific value and compressive strength. The best quality of briquettes is yielded from torrefied RSK at the ambient temperature of briquetting process with the composition of 60% water and 5% binder. The maximum compressive load for the briquettes of torrefied RSK is 141 N and the calorific value is 16 MJ/kg. Based on the economic evaluation analysis, the return of investment (ROI) for the mass production of both RSK and POS briquettes is estimated in 2-year period and the annual profit after payback was approximately 107,428.6 USD.
The properties of coke breeze briquettes produced by ram briquetting
NASA Astrophysics Data System (ADS)
Loginov, Yu. N.; Babailov, N. A.; Polyansky, L. I.
2017-12-01
The paper reports on the results of briquetting coke breeze with a binder in a closed cylindrical press-die. Liquid glass is used as a binder. Approximating curves for the "compaction ratio vs. compaction pressure" dependences are plotted from experimental data. The mechanical properties of the briquettes are determined, namely, drop damage resistance and breaking stress. The results are presented as approximating dependences in the form of a power function.
Li, Yang; Li, Xiaotong; Shen, Fei; Wang, Zhanghong; Yang, Gang; Lin, Lili; Zhang, Yanzong; Zeng, Yongmei; Deng, Shihuai
2014-01-01
Although lignocellulosic biomass has been extensively regarded as the most important resource for bioethanol, the wide application was seriously restricted by the high transportation cost of biomass. Currently, biomass densification is regarded as an acceptable solution to this issue. Herein, briquettes, pellets and their corresponding undensified biomass were pretreated by diluted-NaOH and hydrothermal method to investigate the responses of biomass densification to these typical water-involved pretreatments and subsequent enzymatic hydrolysis. The densified biomass auto-swelling was initially investigated before pretreatment. Results indicated pellets could be totally auto-swollen in an hour, while it took about 24 h for briquettes. When diluted-NaOH pretreatment was performed, biomass briquetting and pelleting improved sugar conversion rate by 20.1% and 5.5% comparing with their corresponding undensified biomass. Pelleting improved sugar conversion rate by 7.0% after hydrothermal pretreatment comparing with the undensified biomass. However, briquetting disturbed hydrothermal pretreatment resulting in the decrease of sugar conversion rate by 15.0%. Copyright © 2013 Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Zhao, W.; Wang, H. T.; Liu, Z. G.; Chu, M. S.; Ying, Z. W.; Tang, J.
2017-10-01
A new type of blast furnace burden, named VTM-CCB (vanadium titanomagnetite carbon composite hot briquette), is proposed and optimized in this paper. The preparation process of VTM-CCB includes two components, hot briquetting and heat treatment. The hot-briquetting and heat-treatment parameters are systematically optimized based on the Taguchi method and single-factor experiment. The optimized preparation parameters of VTM-CCB include a hot-briquetting temperature of 300°C, a coal particle size of <0.075 mm, a vanadium titanomagnetite particle size of <0.075 mm, a coal-added ratio of 28.52%, a heat-treatment temperature of 500°C and a heat-treatment time of 3 h. The compressive strength of VTM-CCB, based on the optimized parameters, reaches 2450 N, which meets the requirement of blast furnace ironmaking. These integrated parameters provide a theoretical basis for the production and application of a blast furnace smelting VTM-CCB.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Honaker, R. Q.; Taulbee, D.; Parekh, B. K.
2005-12-05
The Commonwealth of Kentucky is one of the leading states in the production of both coal and timber. As a result of mining and processing coal, an estimated 3 million tons of fine coal are disposed annually to waste-slurry impoundments with an additional 500 million tons stored at a number of disposal sites around the state due to past practices. Likewise, the Kentucky timber industry discards nearly 35,000 tons of sawdust on the production site due to unfavorable economics of transporting the material to industrial boilers for use as a fuel. With an average heating value of 6,700 Btu/lb, themore » monetary value of the energy disposed in the form of sawdust is approximately $490,000 annually. Since the two industries are typically in close proximity, one promising avenue is to selectively recover and dewater the fine-coal particles and then briquette them with sawdust to produce a high-value fuel. The benefits are i) a premium fuel product that is low in moisture and can be handled, transported, and utilized in existing infrastructure, thereby avoiding significant additional capital investment and ii) a reduction in the amount of fine-waste material produced by the two industries that must now be disposed at a significant financial and environmental price. As such, the goal of this project was to evaluate the feasibility of producing a premium fuel with a heating value greater than 10,000 Btu/lb from waste materials generated by the coal and timber industries. Laboratory and pilot-scale testing of the briquetting process indicated that the goal was successfully achieved. Low-ash briquettes containing 5% to 10% sawdust were produced with energy values that were well in excess of 12,000 Btu/lb. A major economic hurdle associated with commercially briquetting coal is binder cost. Approximately fifty binder formulations, both with and without lime, were subjected to an extensive laboratory evaluation to assess their relative technical and economical effectiveness as binding agents for the briquetting of 90% coal and 10% sawdust blends. Guar gum, wheat starch, and a multi-component formulation were identified as most cost-effective for the production of briquettes targeted for the pulverized-coal market with costs being around $8 per ton of the coal-sawdust blend. REAX/lime and a second multi-component formulation were identified as the most cost-effective for the production of briquettes targeted for the stoker-coal market. Various sources of sawdust generated from different wood types were also investigated to determine their chemical properties and to evaluate their relative performance when briquetted with clean coal to form a premium fuel. The highest heating values, approaching 7,000 Btu/lb, were obtained from oak. Sawdusts from higher-density, red oak, white oak, hickory, and beech trees provided higher quality briquettes relative to their lower-density counterparts. In addition to sawdust type, a number of other parameters were evaluated to characterize their impact on briquette properties. The parameters that exhibited the greatest impact on briquette performance were binder concentration; sawdust concentration and particle size; cure temperature; and ash content. Parameters that had the least impact on briquette properties, at least over the ranges studied, were moisture content, briquetting force, and briquetting dwell time. The continuous production of briquettes from a blend of coal and sawdust was evaluated using a 200 lbs/hr Komarek Model B-100 briquetter. The heating values of briquettes produced by the unit exceeded the goal of the project by a large margin. A significant observation was the role of feed moisture on the stability of the mass flow rate through the briquetter and on briquette strength. Excessive feed moisture levels caused inconsistent or stoppage of material flow through the feed hopper and resulted in the production of variable-quality briquettes. Obviously, the limit on feed moisture content has a significant impact on the economics of coal-sawdust briquetting since it will ultimately dictate dewatering costs. Interestingly, the maximum feed moisture was found to be dependent to some extent on the binder type with molasses-containing blends being difficult to feed when the moisture content approached 12% while guar gum blends flowed consistently at moisture levels as high as 15% by weight. Due to the low ash and moisture contents of the coal-sawdust briquettes, a production increase of about 50 tons/hr would potentially be realized at a 1,400 ton/hr preparation plant. The overall capital cost of a 50 ton/hr flotation and briquetting addition was estimated to be around $8 million. Based on a conservative briquetting operating cost of $12/ton, the annual profit before taxes was approximated to be $4 million thereby indicating a return on investment in about 2 years. The internal rate of return based on a 10 year life was an attractive 43%.« less
NASA Astrophysics Data System (ADS)
Khorasgani, Nasrin B.; Karimibavani, Bahareh; Alamir, Mohammed; Alzahrani, Naif; McClain, Amy P.; Asmatulu, Ramazan
2017-04-01
One of the most environmental concerns is the climate change because of the greenhouse gasses, such as CO2, N2O, CH4, and fluorinated gases. The big majority of CO2 is coming from burning of fossil fuels to generate steam, heat and power. In order to address some of the major environmental concerns of fossil fuels, a number of different alternatives for renewable energy sources have been considered, including sunlight, wind, rain, tides and geothermal heat and biomass. In the present study, two different biomass products (three leaves and grasses) were collected from the local sources, cleaned, chopped, and mixed with corn starch as a binder prior to the briquetting process at different external loads in a metallic mold. A number of tests, including drop, ignition and mechanical compression were conducted on the prepared briquettes before and after stabilizations and carbonization processes at different conditions. The test results indicated that briquetting pressure and carbonizations are the primary factors to produce stable and durable briquettes for various industrial applications. Undergraduate students have been involved in every step of the project and observed all the details of the process during the laboratory studies, as well as data collection, analysis and presentation. This study will be useful for the future trainings of the undergraduate engineering students on the renewable energy and related technologies.
40 CFR 454.11 - Specialized definitions.
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 30 2011-07-01 2011-07-01 false Specialized definitions. 454.11 Section 454.11 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS GUM AND WOOD CHEMICALS MANUFACTURING POINT SOURCE CATEGORY Char and Charcoal Briquets...
40 CFR 454.11 - Specialized definitions.
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 29 2010-07-01 2010-07-01 false Specialized definitions. 454.11 Section 454.11 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS GUM AND WOOD CHEMICALS MANUFACTURING POINT SOURCE CATEGORY Char and Charcoal Briquets...
40 CFR 420.131 - Specialized definitions.
Code of Federal Regulations, 2012 CFR
2012-07-01
....131 Specialized definitions. As used in this subpart: (a) The term briquetting operations means a hot... gaseous (carbon monoxide-carbon dioxide, hydrogen) or solid reactants. (c) The term forging means the hot... of briquettes manufactured by hot or cold agglomeration processes. (e) For direct reduced iron (DRI...
40 CFR 420.131 - Specialized definitions.
Code of Federal Regulations, 2013 CFR
2013-07-01
....131 Specialized definitions. As used in this subpart: (a) The term briquetting operations means a hot... gaseous (carbon monoxide-carbon dioxide, hydrogen) or solid reactants. (c) The term forging means the hot... of briquettes manufactured by hot or cold agglomeration processes. (e) For direct reduced iron (DRI...
40 CFR 420.131 - Specialized definitions.
Code of Federal Regulations, 2011 CFR
2011-07-01
....131 Specialized definitions. As used in this subpart: (a) The term briquetting operations means a hot... gaseous (carbon monoxide-carbon dioxide, hydrogen) or solid reactants. (c) The term forging means the hot... of briquettes manufactured by hot or cold agglomeration processes. (e) For direct reduced iron (DRI...
40 CFR 420.131 - Specialized definitions.
Code of Federal Regulations, 2014 CFR
2014-07-01
....131 Specialized definitions. As used in this subpart: (a) The term briquetting operations means a hot... gaseous (carbon monoxide-carbon dioxide, hydrogen) or solid reactants. (c) The term forging means the hot... of briquettes manufactured by hot or cold agglomeration processes. (e) For direct reduced iron (DRI...
Charcoal as an alternative energy source. sub-project: briquetting of charcoal
DOE Office of Scientific and Technical Information (OSTI.GOV)
Enstad, G.G.
1982-02-02
Charcoal briquettes have been studied both theoretically and experimentally. It appears most realistic to use binders in solution. Binders of this kind have been examined and the briquettes' mechanical properties measured. Most promising are borresperse, gum arabic, dynolex, and wood tar.
Density equation of bio-coal briquettes and quantity of maize cob in Phitsanulok, Thailand
DOE Office of Scientific and Technical Information (OSTI.GOV)
Patomsok Wilaipon
One of the most important crops in Phitsanulok, a province in Northern Thailand, is maize. BaseD on the calculation, the quantity of maize cob produced in this region was approximately 220 kton year{sup -1}. The net heating value of maize cob was found to be 14.2 MJ kg{sup -1}. Therefore, the total energy over 874 TJ year-1 can be obtained from this agricultural waste. In the experiments, maize cob was utilized as the major ingredient for producing biomass-coal briquettes. The maize cob was treated with sodium hydroxide solution before mixing with coal fine. The ratios of coal:maize were 1:2 andmore » 1:3, respectively. The range of briquetting pressures was from 4-8 MPa. The result showed that the density was strongly affected by both parameters. Finally, the relationship between biomass ratio, briquetting pressures and briquette density was developed and validated by using regression technique. 13 refs., 2 figs.« less
Assessment of Biomass Pelletization Options for Greensburg, Kansas
DOE Office of Scientific and Technical Information (OSTI.GOV)
Haase, S.
2010-05-01
This report provides an overview of a technical report on an assessment NREL conducted in Greensburg, Kansas, to identify potential opportunities to develop a biomass pelletization or briquetting plant in the region. See NREL/TP-7A2-45843 for the Executive Summary of this report.
L. H. Reineke
1965-01-01
This report gives information on the preparation of wood fuel from wood residues and other wood raw materials. Types of wood fuel discussed are cordwood, stovewood, slabwood, kindling, chips, hogged fuel, sawdust and shavings, bark, charcoal, alcohol, and briquets. Related information is given on types of machinery for preparing wood fuel and on possible markets for...
Chen, Yingjun; Zhi, Guorui; Feng, Yanli; Chongguo Tian; Bi, Xinhui; Li, Jun; Zhang, Gan
2015-09-01
Both China and UNEP recommend replacing raw coal chunks with coal briquettes in household sector as clean coal technology (CCT), which has been confirmed by the decreased emissions of particulate matter and black carbon. However, the clean effect has never been systematically checked by other pollutants like polycyclic aromatic hydrocarbons (PAHs). In this study, 5 coals with different geological maturities were processed as both chunks and briquettes and burned in 3 typical coal stoves for the measurement of emission factors (EFs) of particle-bound PAHs. It was found that the EFs of 16 parent PAHs, 26 nitrated PAHs, 6 oxygenated PAHs, and 8 alkylated PAHs for coal briquettes were 6.90 ± 7.89, 0.04 ± 0.03, 0.65 ± 0.40, and 72.78 ± 18.23 mg/kg, respectively, which were approximately 3.1, 3.7, 1.9, and 171 times those for coal chunks, respectively. Such significant increases in PAH emissions increased human health risk and challenged the policy of CCT. Copyright © 2015 Elsevier Ltd. All rights reserved.
Hudziak, J J; Boffeli, T J; Kreisman, J J; Battaglia, M M; Stanger, C; Guze, S B; Kriesman, J J
1996-12-01
The criteria for borderline personality disorder seem to select patients with very high rates of Briquet's syndrome (hysteria), somatization disorder, antisocial personality disorder, and substance abuse disorders. This study was undertaken to determine whether systematic assessment of patients with borderline personality disorder would reveal characteristic features of that condition which would distinguish it from these other disorders. Eighty-seven white female patients (75 in St. Louis and 12 in Milan, Italy) who had borderline personality disorder according to both the DSM-III-R criteria and the Revised Diagnostic Interview for Borderlines were further examined with the DSM-III-R Checklist and the Perley-Guze Hysteria Checklist to determine their patterns of psychiatric comorbidity. Every patient had at least one additional DSM diagnosis. Patients in St. Louis and Milan averaged five and four additional diagnoses, respectively. Eighty-four percent of the patients in St. Louis met criteria for either somatization disorder, Briquet's syndrome, antisocial personality disorder, or substance abuse disorders. Patterns of comorbidity for panic (51%), generalized anxiety disorder (55%), and major depression (87%) in St. Louis were consistent with those in other studies. The data indicate that the boundaries for the borderline condition are not specific and identify a high percentage of patients with these other disorders. Furthermore, the comorbidity profiles closely resemble the psychiatric profiles of patients with these disorders. If the borderline syndrome is meant to include all of these disorders, its usefulness as a diagnosis is limited. Until the fundamental features of borderline personality disorder that distinguish it from the others are identified, it is recommended that clinicians carefully assess patients for these other diagnoses. Efforts should be made to change the borderline personality disorder criteria by shifting away from overlap with the criteria for the other disorders.
Drobíková, Klára; Plachá, Daniela; Motyka, Oldřich; Gabor, Roman; Kutláková, Kateřina Mamulová; Vallová, Silvie; Seidlerová, Jana
2016-02-01
Steel plants generate significant amounts of wastes such as sludge, slag, and dust. Blast furnace sludge is a fine-grained waste characterized as hazardous and affecting the environment negatively. Briquetting is one of the possible ways of recycling of this waste while the formed briquettes serve as a feed material to the blast furnace. Several binders, both organic and inorganic, had been assessed, however, only the solid product had been analysed. The aim of this study was to assess the possibilities of briquetting using commonly available laundry starch as a binder while evaluating the possible utilization of the waste gas originating from the thermal treatment of the briquettes. Briquettes (100g) were formed with the admixture of starch (UNIPRET) and their mechanical properties were analysed. Consequently, they were subjected to thermal treatment of 900, 1000 and 1100°C with retention period of 40min during which was the waste gas collected and its content analysed using gas chromatography. Dependency of the concentration of the compounds forming the waste gas on the temperature used was determined using Principal component analysis (PCA) and correlation matrix. Starch was found to be a very good binder and reduction agent, it was confirmed that metallic iron was formed during the thermal treatment. Approximately 20l of waste gas was obtained from the treatment of one briquette; main compounds were methane and hydrogen rendering the waste gas utilizable as a fuel while the greatest yield was during the lowest temperatures. Preparation of blast furnace sludge briquettes using starch as a binder and their thermal treatment represents a suitable method for recycling of this type of metallurgical waste. Moreover, the composition of the resulting gas is favourable for its use as a fuel. Copyright © 2015 Elsevier Ltd. All rights reserved.
Adult Uca panacea were distributed randomly (250 females, 100 males per pond) into six estuarine ponds to determine the effects of field applications of methoprene (AltosidO XR briquets) on female growth and reproduction. Duplicate reference ponds, low-dose ponds, and high-dose p...
Process for converting coal into liquid fuel and metallurgical coke
Wolfe, Richard A.; Im, Chang J.; Wright, Robert E.
1994-01-01
A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.
PREPARATION OF URANIUM HEXAFLUORIDE
Lawroski, S.; Jonke, A.A.; Steunenberg, R.K.
1959-10-01
A process is described for preparing uranium hexafluoride from carbonate- leach uranium ore concentrate. The briquetted, crushed, and screened concentrate is reacted with hydrogen fluoride in a fluidized bed, and the uranium tetrafluoride formed is mixed with a solid diluent, such as calcium fluoride. This mixture is fluorinated with fluorine and an inert diluent gas, also in a fluidized bed, and the uranium hexafluoride obtained is finally purified by fractional distillation.
NASA Astrophysics Data System (ADS)
Sun, Jianzhong; Zhi, Guorui; Hitzenberger, Regina; Chen, Yingjun; Tian, Chongguo; Zhang, Yayun; Feng, Yanli; Cheng, Miaomiao; Zhang, Yuzhe; Cai, Jing; Chen, Feng; Qiu, Yiqin; Jiang, Zhiming; Li, Jun; Zhang, Gan; Mo, Yangzhi
2017-04-01
Brown carbon (BrC) draws increasing attention due to its effects on climate and other environmental factors. In China, household coal burned for heating and cooking purposes releases huge amounts of carbonaceous particles every year; however, BrC emissions have rarely been estimated in a persuasive manner due to the unavailable emission characteristics. Here, seven coals jointly covering geological maturity from low to high were burned in four typical stoves as both chunk and briquette styles. The optical integrating sphere (IS) method was applied to measure the emission factors (EFs) of BrC and black carbon (BC) via an iterative process using the different spectral dependence of light absorption for BrC and BC and using humic acid sodium salt (HASS) and carbon black (CarB) as reference materials. The following results have been found: (i) the average EFs of BrC for anthracite coal chunks and briquettes are 1.08 ± 0.80 and 1.52 ± 0.16 g kg-1, respectively, and those for bituminous coal chunks and briquettes are 8.59 ± 2.70 and 4.01 ± 2.19 g kg-1, respectively, reflecting a more significant decline in BrC EFs for bituminous coals than for anthracites due to briquetting. (ii) The BrC EF peaks at the middle of coal's geological maturity, displaying a bell-shaped curve between EF and volatile matter (Vdaf). (iii) The calculated BrC emissions from China's residential coal burning amounted to 592 Gg (1 Gg = 109 g) in 2013, which is nearly half of China's total BC emissions. (iv) The absorption Ångström exponents (AAEs) of all coal briquettes are higher than those of coal chunks, indicating that the measure of coal briquetting increases the BrC / BC emission ratio and thus offsets some of the climate cooling effect of briquetting. (v) In the scenario of current household coal burning in China, solar light absorption by BrC (350-850 nm in this study) accounts for more than a quarter (0.265) of the total absorption. This implies the significance of BrC to climate modeling.
The environmental problems in urban communities and the protection of the environment in Korea.
Kim, I K
1994-07-01
Korea's urban environmental problems, specifically air and water pollution, government environmental policies, and the role of nongovernmental organizations (NGOs) in protecting the environment are described and discussed. Korea's rapid industrialization and urbanization between 1961 and 1985 led to an increased volume of waste and air pollution. Automobiles increased in number from 29,234 in 1961 to 1,113,430 in 1985. In the same period, the number of factories with at least five employees rose from 15,204 to 44,037. The volume of chemical materials and agricultural chemicals dramatically increased. Household wastes in urban areas increased from 26,831 tons per day in 1978 to 61,072 tons per day in 1985. Industrial waste rose from 13,130 to 33,349 tons per day in 1985. Respiratory diseases are precipitated by exposure to sulphur dioxide, which is produced during cooking and heating with coal briquets; to nitrogen dioxide from automobile exhaust; and to carbon monoxide from coal briquets. Indoor air pollution from particles such as radon, asbestos, cigarette smoke, fungus, and bacteria also impacts on health. Tolerance limits have been reached or surpassed in many cities, particularly in Seoul. Air pollution is worse during the winter. The poor are particularly affected because of the continued use of coal briquets for heating. Industry contributes to water pollution. The volume of industrial waste water quadrupled between 1980 and 1990. In Seoul, however, population size directly contributes to 64.3% of water pollution, and the remaining 35.2% is from factories. Although livestock contributes to only 0.5% of water pollution, livestock drainage contributes to 36.3% of chemical materials in polluted water. Biological oxygen demand has also exceeded tolerance limits. Water reservoirs contain toxic chemicals such as lead, copper, mercury, arsenic, phenol, phosphorus, and nitrogen, which take a longer time to affect health. The Anti-Pollution Law of 1963 and the Environmental Protection Law of 1977 were adopted, but public participation was problematic, and funding for assessment was limited. NGOs have been active in environmental programs since democratization in 1987.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Demirbas, A.; Simsek, T.
In this work, the utilization of aniline (C{sub 6}H{sub 7}N) formaldehyde (HCHO) resins as a binding agent of coke briquetting was investigated. Aniline (AN) formaldehyde (F) resins are a family of thermoplastics synthesized by condensing AN and F in an acid solution exhibiting high dielectric strength. The tensile strength sharply increases as the ratio of F to AN from 0.5 to 1.6, and it reaches the highest values between 1.6 and 2.2 F/AN ratio; it then slightly decreases. The highest tensile strength of F-AN resin-coke briquette (23.66 MN/m{sup 2}) was obtained from the run with 1.5 of F/AN ratio bymore » using (NH4){sub 2}S{sub 2}O{sub 8} catalyst at 310 K briquetting temperature. The tensile strength of F-AN resin-coke briquette slightly decreased with increasing the catalyst percent to 0.10%, and then it sharply decreased to zero with increasing the catalyst percent to 0.2%. The effect of pH on the tensile strength is irregular. As the pH of the mixture increases from 9.0 to 9.2, the tensile strength shows a sharp increase, and the curve reaches a plateau value between pH 9.3 and 9.9; then the tensile strength shows a slight increase after pH = 9.9.« less
Military and Private Sector Commodity Outlets: A Retail Price Comparison
1985-02-01
II where it is noted that some PXs carry only the glass bowl Sunbeam Mixmaser, at $69.95, while off-base outlets such as K-Mart carry the steel bowl...by comparing Table Bl with Tables B2 through B6. 11. The only difference between the two models is that the higher priced model included a glass ...Arrow Charcoal Briquets, 10 lb. Bag 9. Atra Shaving Cartridges, Pack of 10 10. Westinghouse Softlite Lightbulbs , 60 W, pack of 4 11. Kiwi Black Shoe
Sternberg, Morgan; Grue, Christian; Conquest, Loveday; Grassley, James; King, Kerensa
2012-01-01
We investigated the efficacy, fate, and potential for direct effects on salmonids of 4 common mosquito larvicides (Mosquito Dunks® and Bits® (AI: Bacillis thuringiensis var. israelensis, [Bti]), VectoLex® WSP (AI: Bacillus sphaericus [Bs], VectoLex CG [AI: Bs], and Altosid® Briquets [AI: s-methoprene]) in Seattle, WA, during 3 summers. During efficacy trials in 2006, all treatments resulted in a rapid reduction in number of mosquito pupae (Mosquito Dunks and Bits and VectoLex WSP) or emergence success (Altosid Briquets). VectoLex CG was chosen for city-wide application in 2007 and 2008. The average counts of pupae within round-top basins remained significantly below the control average for 11 wk in 2007, whereas efficacy in grated-top basins was short-lived. In 2008 the average counts of pupae within grated-top basins remained significantly below the control average for 10 wk. Altosid XR was also effective in reducing adult emergence within grated basins in 2008. In 2007 and 2008, frequent precipitation events made the evaluation of efficacy difficult due to reductions in pupae across control and treated basins. Four separate analyses of VectoLex products revealed that the product was a combination of Bs and Bti. Both Bs and Bti were detected in 3 urban creeks connected to treated basins in 2007 and 2008. Laboratory toxicity test results suggest that concentrations of Bs and Bti detected in each of the watersheds pose little direct hazard to juvenile salmonids.
Gasification: An alternative solution for energy recovery and utilization of vegetable market waste.
Narnaware, Sunil L; Srivastava, Nsl; Vahora, Samir
2017-03-01
Vegetables waste is generally utilized through a bioconversion process or disposed of at municipal landfills, dumping sites or dumped on open land, emitting a foul odor and causing health hazards. The presents study deals with an alternative way to utilize solid vegetable waste through a thermochemical route such as briquetting and gasification for its energy recovery and subsequent power generation. Briquettes of 50 mm diameter were produced from four different types of vegetable waste. The bulk density of briquettes produced was increased 10 to 15 times higher than the density of the dried vegetable waste in loose form. The lower heating value (LHV) of the briquettes ranged from 10.26 MJ kg -1 to 16.60 MJ kg -1 depending on the type of vegetable waste. The gasification of the briquettes was carried out in an open core downdraft gasifier, which resulted in syngas with a calorific value of 4.71 MJ Nm -3 at the gasification temperature between 889°C and 1011°C. A spark ignition, internal combustion engine was run on syngas and could generate a maximum load up to 10 kW e . The cold gas efficiency and the hot gas efficiency of the gasifier were measured at 74.11% and 79.87%, respectively. Energy recovery from the organic vegetable waste was possible through a thermochemical conversion route such as briquetting and subsequent gasification and recovery of the fuel for small-scale power generation.
Effective Processing of the Iron Ores
NASA Astrophysics Data System (ADS)
Kuskov, Vadim; Kuskova, Yana; Udovitsky, Vladimir
2017-11-01
Effective technology for a complex wasteless processing of the iron ores has been designed and includes three main components (plats): comminution plant, briquette plant, pigment plant. The comminution is done per energy effective technology. Using of briquetting for ores clotting enables the costs cut and brings to a higher level of environmental safety of the process. Briquette formation can be done as a regular pressing, as an extrusion. Developed technology allows to produce high quality competitively products for metallurgy industry and red iron oxide pigments. The whole production line impacts the environment in a minimal manner.
Liu, Chanchan; Srividya, Narayanan; Parrish, Amber N; Yue, Wei; Shan, Mingqiu; Wu, Qinan; Lange, B Markus
2018-06-01
Schizonepeta tenuifolia Briquet, commonly known as Japanese catnip, is used for the treatment of colds, headaches, fevers, and skin rashes in traditional Asian medicine (China, Japan and Korea). The volatile oil and its constituents have various demonstrated biological activities, but there is currently limited information regarding the site of biosynthesis. Light microscopy and scanning electron microscopy indicated the presence of three distinct glandular trichome types which, based on their morphological features, are referred to as peltate, capitate and digitiform glandular trichomes. Laser scanning microscopy and 3D reconstruction demonstrated that terpenoid-producing peltate glandular trichomes contain a disk of twelve secretory cells. The oil of peltate glandular trichomes, collected by laser microdissection or using custom-made micropipettes, was demonstrated to contain (-)-pulegone, (+)-menthone and (+)-limonene as major constituents. Digitiform and capitate glandular trichomes did not contain appreciable levels of terpenoid volatiles. The yield of distilled oil from spikes was significantly (44%) higher than that from leaves, while the composition of oils was very similar. Oils collected directly from leaf peltate glandular trichomes over the course of a growing season contained primarily (-)-pulegone (>80% at 32 days after germination) in young plants, while (+)-menthone began to accumulate later (>75% at 80 days after germination), at the expense of (-)-pulegone (the levels of (+)-limonene remained fairly stable at 3-5%). The current study establishes the morphological and chemical characteristics of glandular trichome types of S. tenuifolia, and also provides the basis for unraveling the biosynthesis of essential oil in this popular medicinal plant. Copyright © 2018 Elsevier Ltd. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Karmis, Michael; Luttrell, Gerald; Ripepi, Nino
The research activities presented in this report are intended to address the most critical technical challenges pertaining to coal-biomass briquette feedstocks. Several detailed investigations were conducted using a variety of coal and biomass feedstocks on the topics of (1) coal-biomass briquette production and characterization, (2) gasification of coal-biomass mixtures and briquettes, (3) combustion of coal-biomass mixtures and briquettes, and (4) conceptual engineering design and economic feasibility of briquette production. The briquette production studies indicate that strong and durable co-firing feedstocks can be produced by co-briquetting coal and biomass resources commonly available in the United States. It is demonstrated that binderlessmore » coal-biomass briquettes produced at optimized conditions exhibit very high strength and durability, which indicates that such briquettes would remain competent in the presence of forces encountered in handling, storage and transportation. The gasification studies conducted demonstrate that coal-biomass mixtures and briquettes are exceptional gasification feedstocks, particularly with regard to the synergistic effects realized during devolatilization of the blended materials. The mixture combustion studies indicate that coal-biomass mixtures are exceptional combustion feedstocks, while the briquette combustion study indicates that the use of blended briquettes reduces NO x, CO 2, and CO emissions, and requires the least amount of changes in the operating conditions of an existing coal-fired power plant. Similar results were obtained for the physical durability of the pilot-scale briquettes compared to the bench-scale tests. Finally, the conceptual engineering and feasibility analysis study for a commercial-scale briquetting production facility provides preliminary flowsheet and cost simulations to evaluate the various feedstocks, equipment selection and operating parameters.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Jaya Shankar Tumuluru
2011-08-01
Effect of process variables on the quality attributes of briquettes from wheat, oat, canola and barley straw Jaya Shankar Tumuluru*, L. G. Tabil, Y. Song, K. L. Iroba and V. Meda Biomass is a renewable energy source and environmentally friendly substitute for fossil fuels such as coal and petroleum products. Major limitation of biomass for successful energy application is its low bulk density, which makes it very difficult and costly to transport and handle. To overcome this limitation, biomass has to be densified. The commonly used technologies for densification of biomass are pelletization and briquetting. Briquetting offers many advantages atmore » it can densify larger particles sizes of biomass at higher moisture contents. Briquetting is influenced by a number of feedstock and process variables such as moisture content, particle size distribution, and some operating variables such as temperature and densification pressure. In the present study, experiments were designed and conducted based on Box-Behnken design to produce briquettes using barley, wheat, canola and barley straws. A laboratory scale hydraulic briquette press was used for the present study. The experimental process variables and their levels used in the present study were pressure levels (7.5, 10, 12.5 MPa), three levels of temperature (90, 110, 130 C), at three moisture content levels (9, 12, 15% w.b.), and three levels of particle size (19.1, 25.04, 31.75 mm). The quality variables studied includes moisture content, initial density and final briquette density after two weeks of storage, size distribution index and durability. The raw biomass was initially chopped and size reduced using a hammer mill. The ground biomass was conditioned at different moisture contents and was further densified using laboratory hydraulic press. For each treatment combination, ten briquettes were manufactured at a residence time of about 30 s after compression pressure setpoint was achieved. After compression, the initial dimensions and the final dimensions after 2 weeks of storage in controlled environment of all the samples were measured. Durability, dimensional stability, and moisture content tests were conducted after two weeks of storage of the briquettes produced. Initial results indicated that moisture content played a significant role on briquettes durability, stability, and density. Low moisture content of the straws (7-12%) gave more durable briquettes. Briquette density increased with increasing pressure depending on the moisture content value. The axial expansion was more significant than the lateral expansion, which in some cases tended to be nil depending on the material and operating variables. Further data analysis is in progress in order to understand the significance of the process variables based on ANOVA. Regression models were developed to predict the changes in quality of briquettes with respect of the process variables under study. Keywords: Herbaceous biomass, densification, briquettes, density, durability, dimensional stability, ANOVA and regression equations« less
Determination of thorium by fluorescent x-ray spectrometry
Adler, I.; Axelrod, J.M.
1955-01-01
A fluorescent x-ray spectrographic method for the determination of thoria in rock samples uses thallium as an internal standard. Measurements are made with a two-channel spectrometer equipped with quartz (d = 1.817 A.) analyzing crystals. Particle-size effects are minimized by grinding the sample components with a mixture of silicon carbide and aluminum and then briquetting. Analyses of 17 samples showed that for the 16 samples containing over 0.7% thoria the average error, based on chemical results, is 4.7% and the maximum error, 9.5%. Because of limitations of instrumentation, 0.2% thoria is considered the lower limit of detection. An analysis can be made in about an hour.
History of physical and 'moral' treatment of hysteria.
Broussolle, Emmanuel; Gobert, Florent; Danaila, Teodor; Thobois, Stéphane; Walusinski, Olivier; Bogousslavsky, Julien
2014-01-01
This historical review presents the advances made mostly during the last 200 years on the description, concepts, theories, and (more specifically) cure of patients suffering from hysteria, a still obscure entity. The denomination of the syndrome has changed over time, from hysteria (reinvestigated by Paul Briquet and Jean-Martin Charcot) to pithiatism (Joseph Babinski), then to conversion neurosis (Sigmund Freud), and today functional neurological disorders according to the 2013 American Neurological Association DSM-5 classification. The treatment was renewed in the second half of the 19th century in Paris by Paul Briquet and then by Jean-Martin Charcot. Hysterical women, who represented the great majority of cases, were cured by physical therapy (notably physio-, hydro-, and electrotherapy, and in some cases ovary compression) and 'moral' therapies (general, causal therapy, rest, isolation, hypnosis, and suggestion). At the turn of the 19th and 20th centuries, psychotherapy, psychoanalysis, and persuasion were established respectively by Pierre Janet, Sigmund Freud, and Joseph Babinski. During World War I, military forces faced a large number of posttrauma neurosis cases among soldiers (named the 'Babinski-Froment war neurosis' and Myers 'shell shock', in the French and English literature, respectively). This led to the use of more brutal therapies in military hospitals, combining electrical shock and persuasion, particularly in France with Clovis Vincent and Gustave Roussy, but also in Great Britain and Germany. After World War I, this method was abandoned and there was a marked decrease in interest in hysteria for a long period of time. Today, the current treatment comprises (if possible intensive) physiotherapy, together with psychotherapy, and in some cases psychoanalysis. Antidepressants and anxiolytics may be required, and more recently cognitive and behavioral therapy. Repetitive transcranial magnetic stimulation is a new technique under investigation which may be promising in patients presenting with motor conversion syndrome (motor deficit or movement disorder). Functional neurological disorders remain a difficult problem to manage with frequent failures and chronic handicapping evolution. This emphasizes the need for therapeutic innovations in the future.
Use of cold-bonded, waste oxide briquettes at U.S. Steel Mon Valley BOP shop
DOE Office of Scientific and Technical Information (OSTI.GOV)
DiCaprio, V.; Howell, K.; Harris, R.
1995-09-01
In attempts to avoid the escalated costs and environmental concerns associated with taking waste oxide materials to a landfill, National Recovery Systems Inc., in conjunction with US Steel, built a waste oxide briquetting facility at the USS Mon Valley works (Edgar Thomson plant) to recycle various sludges and scales. The waste oxide briquette is currently a blend of BOP classifier sludge, BOP filter drum sludge, casterscale and hot strip mill scale. In addition to the landfill cost avoidance, the waste oxide briquette is also a low cast, steel scrap supplement. This paper describes the production of the waste oxide briquettemore » and the use of the recycled material at the Edgar Thomson BOP shop.« less
NASA Astrophysics Data System (ADS)
Anikin, A. E.; Galevsky, G. V.; Nozdrin, E. V.; Rudneva, V. V.; Galevsky, S. G.
2016-09-01
The research of the metallization process of the roll scale and sludge after gas treatment in the BOF production with the use of brown coal semicoke mined in Berezovsky field of the Kansk-Achinsk Basin was carried out. A flow diagram of “cold” briquetting using a water-soluble binder was offered. The reduction of iron from its oxide Fe2O3 with brown coal semicoke in the laboratory electric-tube furnace in the argon atmosphere was studied. The mathematical models of dependence of the metallization degree on variable factors were developed. The optimal values of technological factors and essential characteristics of the obtained metallized products were revealed.
Beneficiation of Turkish lignites by thermal treatment and magnetic separation
DOE Office of Scientific and Technical Information (OSTI.GOV)
Onal, G.; Renda, D.; Mustafaev, I.
1999-07-01
In this paper, the improvement of Turkish lignites by semi-coking and REMS magnetic separation, in two stages, is discussed. The oxidation and decomposition of pyrite through the thermal treatment result in the formation of iron oxide and pyrrhotite on the surface. In addition to pyrite, part of the organic sulfur is also removed. After thermal treatment of lignites at temperatures ranging from 370 to 650 C, the application of REMS magnetic separator produces a product higher in calorific value and lower in sulfur content. The product can be utilized after briquetting. The volatile gases can also be used after sulfurmore » removal. This process appears to be feasible as a clean coal manufacture from the point of energy efficiency. A short economic analysis is also presented.« less
A neurological bias in the history of hysteria: from the womb to the nervous system and Charcot.
Mota Gomes, Marleide da; Engelhardt, Eliasz
2014-12-01
Hysteria conceptions, from ancient Egypt until the 19th century Parisian hospital based studies, are presented from gynaecological and demonological theories to neurological ones. The hysteria protean behavioral disorders based on nervous origin was proposed at the beginning, mainly in Great Britain, by the "enlightenment nerve doctors". The following personages are highlighted: Galen, William, Sydenham, Cullen, Briquet, and Charcot with his School. Charcot who had hysteria and hypnotism probably as his most important long term work, developed his conceptions, initially, based on the same methodology he applied to studies of other neurological disorder. Some of his associates followed him in his hysteria theories, mainly Paul Richer and Gilles de La Tourette who produced, with the master's support, expressive books on Salpêtrière School view on hysteria.
Enhanced bioremediation of BTEX using immobilized nutrients: Field demonstration and monitoring
DOE Office of Scientific and Technical Information (OSTI.GOV)
Borden, R.C.; Goin, R.T.; Kao, C.M.
1996-12-01
A permeable barrier system was developed for controlling the migration of dissolved contaminant plumes in ground water. The barrier system consisted of a line of closely spaced wells installed perpendicular to the contaminant plume. Each well contained concrete briquets that released oxygen and nitrate at a controlled rate, enhancing the aerobic biodegradation of dissolved hydrocarbons in the downgradient aquifer. A full scale permeable barrier system was constructed at a gasoline-spill site near Leland, NC. Initially, increased dissolved oxygen and decreased benzene, toluene, ethylbenzene, and xylene isomer (BTEX) concentrations in the downgradient aquifer indicated that oxygen released from the remediation wellsmore » was enhancing biodegradation. Field tracer tests and soil analyses performed at the conclusion of the project indicated that the aquifer in the vicinity of the remediation wells was being clogged by precipitation from iron minerals.« less
Physiochemical Characterization of Briquettes Made from Different Feedstocks
Karunanithy, C.; Wang, Y.; Muthukumarappan, K.; Pugalendhi, S.
2012-01-01
Densification of biomass can address handling, transportation, and storage problems and also lend itself to an automated loading and unloading of transport vehicles and storage systems. The purpose of this study is to compare the physicochemical properties of briquettes made from different feedstocks. Feedstocks such as corn stover, switchgrass, prairie cord grass, sawdust, pigeon pea grass, and cotton stalk were densified using a briquetting system. Physical characterization includes particle size distribution, geometrical mean diameter (GMD), densities (bulk and true), porosity, and glass transition temperature. The compositional analysis of control and briquettes was also performed. Statistical analyses confirmed the existence of significant differences in these physical properties and chemical composition of control and briquettes. Correlation analysis confirms the contribution of lignin to bulk density and durability. Among the feedstocks tested, cotton stalk had the highest bulk density of 964 kg/m3 which is an elevenfold increase compared to control cotton stalk. Corn stover and pigeon pea grass had the highest (96.6%) and lowest (61%) durability. PMID:22792471
On the behavior and stability of a liquid metal in quasi-planar electric contacts
NASA Astrophysics Data System (ADS)
Samuilov, S. D.
2016-06-01
The contacts between conductors formed under relatively low pressures can be treated as quasi-planar. Melting of the material of such contacts upon the passage of electric current is used in some technological processes, but the behavior of liquid in these conditions has not been analyzed. In this study, such an estimate was obtained for specific conditions appearing under electric-pulse compacting (briquetting) of metal shavings. Analysis of derived relations shows that this estimate is valid for any quasi-2D contacts upon passage of a pulsed current of duration from microseconds to milliseconds. It is shown that the spacing between contact surfaces decreases, the liquid metal is extruded in the lateral directions, and the area of the contact and its conductivity increase. Sausage-type magnetohydrodynamic (MHD) instability and overheating instability do not evolve in these conditions because the instability wavelength is larger than the rated thickness of the molten layer; screw MHD instability can appear in slower processes.
Progress of fossil fuel science
DOE Office of Scientific and Technical Information (OSTI.GOV)
Demirbas, M.F.
2007-07-01
Coal is the most abundant and widely distributed fossil fuel. More than 45% of the world's electricity is generated from coal, and it is the major fuel for generating electricity worldwide. The known coal reserves in the world are enough for more than 215 years of consumption, while the known oil reserves are only about 39 times of the world's consumption and the known natural gas reserves are about 63 times of the world's consumption level in 1998. In recent years, there have been effective scientific investigations on Turkish fossil fuels, which are considerable focused on coal resources. Coal ismore » a major fossil fuel source for Turkey. Turkish coal consumption has been stable over the past decade and currently accounts for about 24% of the country's total energy consumption. Lignite coal has had the biggest share in total fossil fuel production, at 43%, in Turkey. Turkish researchers may investigate ten broad pathways of coal species upgrading, such as desulfurization and oxydesulfurization, pyrolysis and hydropyrolysis, liquefaction and hydroliquefaction, extraction and supercritical fluid extraction, gasification, oxidation, briquetting, flotation, and structure identification.« less
NASA Astrophysics Data System (ADS)
Shevelev, L. N.
2017-12-01
Estimates were given of economical and energy efficiency of breakthrough energy-saving technologies, which increase competitive advantages and provide energy efficiency of production while reducing negative impact on the environment through reduction of emissions of harmful substances and greenhouse gases in the atmosphere. Among these technologies, preference is given to the following: pulverized coal fuel, blast-furnace gas recycling, gasification of non-coking coal in bubble-type gas-generators, iron-ore concentrate briquetting with steam coal with further use of ore-coal briquettes in electric furnace steel making. Implementation of these technologies at iron and steel works will significantly reduce the energy intensity of production through reduction of expensive coking coal consumption by means of their substitution by less expensive non-coking (steam) coal, and natural gas substitution by own secondary energy resource, which is the reducing gas. As the result, plants will get an opportunity to become self-sufficient in energy-resources and free themselves entirely from expensive purchased energy resources (natural gas, electric power, and partially coking coals), and cross over to low-carbon development.
NASA Astrophysics Data System (ADS)
Zima, W.; Kolenberg, K.; Briquet, M.; Breger, M.
2004-06-01
We have carried out a Hare-and-Hound test to determine the reliability of the Moment Method (Briquet & Aerts 2003) and the Pixel-by-Pixel Method (Mantegazza 2000) for the identification of pulsation modes in Delta Scuti stars. For this purpose we calculated synthetic line profiles, exhibiting six pulsation modes of low degree and with input parameters initially unknown to us. The aim was to test and increase the quality of the mode identification by applying both methods independently and by using a combined technique. Our results show that, whereas the azimuthal order m and its sign can be fixed by both methods, the degree l is not determined unambiguously. Both identification methods show a better reliability if multiple modes are fitted simultaneously. In particular, the inclination angle is better determined. We have to emphasize that the outcome of this test is only meaningful for stars having pulsational velocities below 0.2 vsini. This is the first part of a series of articles, in which we will test these spectroscopic identification methods.
Sheng, Kui-Chuan; Shen, Ying-Ying; Yang, Hai-Qing; Wang, Wen-Jin; Luo, Wei-Qiang
2012-10-01
Rapid determination of biomass feedstock properties is of value for the production of biomass densification briquetting fuel with high quality. In the present study, visible and near-infrared (Vis-NIR) spectroscopy was employed to build prediction models of componential contents, i. e. moisture, ash, volatile matter and fixed-carbon, and calorific value of three selected species of agricultural biomass feedstock, i. e. pine wood, cedar wood, and cotton stalk. The partial least squares (PLS) cross validation results showed that compared with original reflection spectra, PLS regression models developed for first derivative spectra produced higher prediction accuracy with coefficients of determination (R2) of 0.97, 0.94 and 0.90, and residual prediction deviation (RPD) of 6.57, 4.00 and 3.01 for ash, volatile matter and moisture, respectively. Good prediction accuracy was achieved with R2 of 0.85 and RPD of 2.55 for fixed carbon, and R2 of 0.87 and RPD of 2.73 for calorific value. It is concluded that the Vis-NIR spectroscopy is promising as an alternative of traditional proximate analysis for rapid determination of componential contents and calorific value of agricultural biomass feedstock
DOE Office of Scientific and Technical Information (OSTI.GOV)
Perlack, R.D.; Stevenson, G.G.; Shelton, R.B.
1986-02-01
Fuelwood shortages and potential shortages are widespread throughout the developing world, and are becoming increasingly more prevalent because of the clearing of land for subsistence and plantation agriculture, excessive and inefficient commercial timber harvesting for domestic and export construction, and charcoal production to meet rising urban demands. Further, the environmental and socioeconomic consequences of the resulting deforestation are both pervasive and complex. This report focuses on the substitution of coal briquettes for fuelwood. Although substantial adverse health effects could be expected from burning non-anthracite coal or coal briquettes, a well-developed technique, carbonization, exists to convert coal to a safer formmore » for combustion. The costs associated with briquetting and carbonizing coal indicate that ''smokeless'' coal briquettes can be produced at costs competitive with fuelwood and charcoal. The US Agency for International Development (USAID) is working on implementing this energy option in Haiti and Pakistan by (1) evaluating resources, (2) assessing markets, (3) analyzing technologies, (4) studying government policy and planning, and (5) packaging the idea for the private sector to implement. 26 refs., 2 figs., 12 tabs.« less
Newete, Solomon W; Byrne, Marcus J
2016-06-01
The actual amount of fresh water readily accessible for use is <1 % of the total amount of water on earth, and is expected to shrink further due to the projected growth of the population by a third in 2050. Worse yet are the major issues of water pollution, including mining and industrial waste which account for the bulk of contamination sources. The use of aquatic macrophytes as a cost-effective and eco-friendly tool for phytoremediation is well documented. However, little is known about the fate of those plants after phytoremediation. This paper reviews the options for safe disposal of waste plant biomass after phytoremediation. Among the few mentioned in the literature are briquetting, incineration and biogasification. The economic viability of such processes and the safety of their economic products for domestic use are however, not yet established. Over half of the nations in the world are involved in mining of precious metals, and tailings dams are the widespread legacy of such activities. Thus, the disposal of polluted plant biomass onto mine storage facilities such as tailing dams could be an interim solution. There, the material can act as mulch for the establishment of stabilizing vegetation and suppress dust. Plant decomposition might liberate its contaminants, but in a site where containment is a priority.
Majuste, Daniel; Mansur, Marcelo Borges
2008-05-01
The argon oxygen decarburization with lance (AOD-L) sludge generated by the stainless steelmaking industry is a hazardous waste due to the presence of chromium. While its coarse fraction is usually recycled into the own industrial process, the fine fraction is normally disposed in landfills. Techniques such as briquetting or magnetic separation were found to be inadequate to treat it for reuse purposes. So, in this work, the fine fraction of the AOD-L sludge was characterized aiming to find alternative methods to treat it. This sludge consists of a fine powder (mean diameter of 1 microm) containing 34 +/- 2% (w/w) of iron, 10.2 +/- 0.9% (w/w) of chromium and 1.4 +/- 0.1% (w/w) of nickel. The main crystalline phases identified in this study were chromite (FeCr(2)O(4)), magnetite (Fe(3)O(4)), hematite (Fe(2)O(3)) and calcite (CaCO(3)). In the digestion tests, the addition of HClO(4) has favored the dissolution of chromite which is a very stable oxide in aqueous media. Nickel was found in very fine particles, probably in the metallic form or associated with iron and oxygen. The sludge was classified as hazardous waste, so its disposal in landfills should be avoided.
Frequency of DEA 1 antigen in 1037 mongrel and PUREBREED dogs in ITALY.
Carli, E; Carminato, A; Ravagnan, S; Capello, K; Antognoni, M T; Miglio, A; Furlanello, T; Proverbio, D; Spada, E; Stefani, A; Mutinelli, F; Vascellari, M
2017-11-29
The prevalence of dog erythrocyte antigen (DEA 1) in canine population is approximately 40-60%. Often data are limited to a small number of breeds and/or dogs. The aims of this study were to evaluate frequency of DEA 1 in a large population of purebred and mongrel dogs including Italian native breeds and to recognize a possible association between DEA 1 and breed, sex, and genetic and phenotypical/functional classifications of breeds. Frequencies of DEA 1 blood group collected from screened/enrolled blood donors and from healthy and sick dogs were retrospectively evaluated. The breed and the sex were recorded when available. DEA 1 blood typing was assessed by immunocromatographic test on K3EDTA blood samples. The prevalence of DEA 1 antigen was statistically related to breed, gender, Fédération Cynologique Internationale (FCI) and genotypic grouping. Sixty-two per cent dogs resulted DEA 1+ and 38% DEA 1-. DEA 1- was statistically associated with Dogo Argentino, Dobermann, German Shepherd, Boxer, Corso dogs, the molossian dogs, the FCI group 1, 2 and 3 and the genetic groups "working dogs" and "mastiff". DEA 1+ was statistically associated with Rottweiler, Briquet Griffon Vendéen, Bernese mountain dog, Golden Retriever, the hunting breeds, the FCI group 4, 6, 7 and 8 and the genetic groups "scent hounds" and "retrievers". No gender association was observed. Data obtained by this work may be clinically useful to drive blood donor enrollment and selection among different breeds.
Concentrations and bioaccessibilities of trace elements in barbecue charcoals.
Sharp, Annabel; Turner, Andrew
2013-11-15
Total and bioaccessible concentrations of trace elements (Al, As, Cd, Cu, Fe, Hg, Mn, Ni, Pb and Zn) have been measured in charcoals from 15 barbecue products available from UK retailers. Total concentrations (available to boiling aqua regia) were greater in briquetted products (with mean concentrations ranging from 0.16 μg g(-1) for Cd to 3240 μg g(-1) for Al) than in lumpwoods (0.007 μg g(-1) for Cd to 28 μg g(-1) for Fe), presumably because of the use of additives and secondary constituents (e.g. coal) in the former. On ashing, and with the exception of Hg, elemental concentrations increased by factors ranging from about 1.5 to 50, an effect attributed to the combustion of organic components and offset to varying extents by the different volatilities of the elements. Concentrations in the ashed products that were bioaccessible, or available to a physiologically based extraction test (PBET) that simulates, successively, the chemical conditions in the human stomach and intestine, exhibited considerable variation among the elements studied. Overall, however, bioaccessible concentrations relative to corresponding total concentrations were greatest for As, Cu and Ni (attaining 100% in either or both simulated PBET phases in some cases) and lowest for Pb (generally <1% in both phases). A comparison of bioaccessible concentrations in ashed charcoals with estimates of daily dietary intake suggest that Al and As are the trace elements of greatest concern to human health from barbecuing. Copyright © 2013 Elsevier B.V. All rights reserved.
Bio-electricity Generation using Jatropha Oil Seed Cake.
Raheman, Hifjur; Padhee, Debasish
2016-01-01
The review of patents reveals that Handling of Jatropha seed cake after extraction of oil is essential as it contains toxic materials which create environmental pollution. The goal of this work is complete utilisation of Jatropha seeds. For this purpose, Jatropha oil was used for producing biodiesel and the byproduct Jatropha seed cake was gasified to obtain producer gas. Both biodiesel and producer gas were used to generate electricity. To achieve this, a system comprising gasifier, briquetting machine, diesel engine and generator was developed. Biodiesel was produced successfully using the method patented for biodiesel production and briquettes of Jatropha seed cake were made using a vertical extruding machine. Producer gas was obtained by gasifying these briquettes in a downdraft gasifier. A diesel engine was then run in dual fuel mode with biodiesel and producer gas instead of only diesel. Electricity was generated by coupling it to a generator. The cost of producing kilowatthour of electricity with biodiesel and diesel in dual fuel mode with producer gas was found to be 0.84 $ and 0.75 $, respectively as compared to 0.69 $ and 0.5 $ for the same fuels in single fuel mode resulting in up to 48 % saving of pilot fuel. Compared to singlefuel mode, there was 25-32 % reduction in system and brake thermal efficiency along with significantly lower NOx, higher CO and CO2 emissions when the bio-electricity generating system was operated in dual fuel mode. Overall, the developed system could produce electricity successfully by completely uti- lising Jatropha seeds without leaving any seed cake to cause environmental pollution.
Self-Scrubbing Coal -- an integrated approach to clean air
DOE Office of Scientific and Technical Information (OSTI.GOV)
Harrison, K.E.
1997-12-31
Carefree Coal is coal cleaned in a proprietary dense-media cyclone circuit, using ultrafine magnetite slurries, to remove noncombustible material, including up to 90% of the pyritic sulfur. Deep cleaning alone, however, cannot produce a compliance fuel from coals with high organic sulfur contents. In these cases, Self-Scrubbing Coal will be produced. Self-Scrubbing Coal is produced in the same manner as Carefree Coal except that the finest fraction of product from the cleaning circuit is mixed with limestone-based additives and briquetted. The reduced ash content of the deeply-cleaned coal will permit the addition of relatively large amounts of sorbent without exceedingmore » boiler ash specifications or overloading electrostatic precipitators. This additive reacts with sulfur dioxide (SO{sub 2}) during combustion of the coal to remove most of the remaining sulfur. Overall, sulfur reductions in the range of 80--90% are achieved. After nearly 5 years of research and development of a proprietary coal cleaning technology coupled with pilot-scale validation studies of this technology and pilot-scale combustion testing of Self-Scrubbing Coal, Custom Coals Corporation organized a team of experts to prepare a proposal in response to DOE`s Round IV Program Opportunity Notice for its Clean Coal Technology Program under Public Law 101-121 and Public Law 101-512. The main objective of the demonstration project is the production of a coal fuel that will result in up to 90% reduction in sulfur emissions from coal-fired boilers at a cost competitive advantage over other technologies designed to accomplish the same sulfur emissions and over naturally occurring low sulfur coals.« less
de Oliveira, Ricardo Sonsim; Palácio, Soraya Moreno; da Silva, Edson Antonio; Mariani, Filipe Quadros; Reinehr, Thiago Olinek
2017-04-01
This study evaluated the feasibility of production of briquettes using fine charcoal, sewage sludge, and mixtures thereof for use in energy production. The briquettes of 7-8 cm diameter and 20 cm length were produced in the conical press extruder type, mixing sewage sludge to charcoal fines in different ratios: 0:100, 25:75, 50:50, 75:25, and 100:0, with the addition of a binder (glue flour) in a ratio of 8 mass% prepared for briquetting. After air drying (temperatures between 24 and 30°C) for 48 h, the mechanical, thermal, and morphological characterizations were performed. The morphological properties of the briquettes were evaluated by scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) spectroscopy. The briquettes produced had mechanical strength, with values between 210 and 420 kgf, and densities between 0.75 and 0.91 g cm -3 . The calorific value of briquettes was in the range from 13.21 to 23.10 MJ kg -1 , in which there was an increase with the increase of concentration of charcoal fines in the mixture. Thermogravimetric analysis showed mass losses that occurred in the temperature range between 150 and 740 °C. The results of the mechanical and thermal properties showed the feasibility of using fine charcoal briquettes from sewage sludge as well as mixtures thereof, for the production of energy. The fine charcoal briquette was the one with the highest calorific value, but not showed the highest resistance to mechanical shock.
Development of briquette fuel from cashew shells and rice husk mixture
NASA Astrophysics Data System (ADS)
Yohana, Eflita; Arijanto, Kalyana, Ivan Edgar; Lazuardi, Andy
2017-01-01
In Indonesia, a large amount of biomasses are available from cashew plantations and rice fields and constitute one of the raw material sources for thermal energy. Annually, 130.052 tons of whole cashews can produce cashew shells with a total energy content of 4,933x109 kcal. In addition, 49 million tons of rice is produced annually in Indonesia. From this sum, 7.5-10 million tons of rice husks are obtained with a total energy content of 2.64x1013 kcal. The purpose of this research is to review the briquette of biomass made from a mixture of cashew shells and rice husks with polyvinyl acetate (PVA) as the adhesive. The mixture ratio of cashew shells and rice husks is varied with a range of 75:25, 50:50, and 25:75 % weight. Briquettes are made in a cylinder mold and pressed using a hydraulic press machine. The pressing pressure varies from 2.500, 5.000, and 7.500 kg/m2. Results show that a briquette with a mixture ratio of 75:25 % shows good pressure tenacity. A model is used to relate density with briquetting pressure. This model shows that the briquette has low compressibility at 0.13. Enhancement of the heating value for the briquettes is also carried out using the torrefaction treatment. The torrefaction process produces biomass briquettes made from a mixture of cashew shells and rice husks with a heating value on par to sub-bituminous coal according to the ASTM D 388 standard classification with a heating value of 6.712 kcal/kg.
A review on biomass classification and composition, cofiring issues and pretreatment methods
DOE Office of Scientific and Technical Information (OSTI.GOV)
Jaya Shankar Tumuluru; Shahab Sokhansanj; Christopher T. Wright
Presently around the globe there is a significant interest in using biomass for power generation as power generation from coal continues to raise environmental concerns. Biomass alone can be used for generation of power which can bring lot of environmental benefits. However the constraints of using biomass alone can include high investments costs for biomass feed systems and also uncertainty in the security of the feedstock supply due to seasonal variations and in most of the countries biomass is dispersed and the infrastructure for biomass supply is not well established. Alternatively cofiring biomass along with coal offer advantages like (a)more » reducing the issues related to biomass quality and buffers the system when there is insufficient feedstock quantity and (b) costs of adapting the existing coal power plants will be lower than building new systems dedicated only to biomass. However with the above said advantages there exists some technical constrains including low heating and energy density values, low bulk density, lower grindability index, higher moisture and ash content to successfully cofire biomass with coal. In order to successfully cofire biomass with coal, biomass feedstock specifications need to be established to direct pretreatment options that may include increasing the energy density, bulk density, stability during storage and grindability. Impacts on particle transport systems, flame stability, pollutant formation and boiler tube fouling/corrosion must also be minimized by setting feedstock specifications including composition and blend ratios if necessary. Some of these limitations can be overcome by using pretreatment methods. This paper discusses the impact of feedstock pretreatment methods like sizing, baling, pelletizing, briquetting, washing/leaching, torrefaction, torrefaction and pelletization and steam explosion in attainment of optimum feedstock characteristics to successfully cofire biomass with coal.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Jaya Shankar Tumuluru; J Richard Hess; Richard D. Boardman
2012-06-01
There is a growing interest internationally to use more biomass for power generation, given the potential for significant environmental benefits and long-term fuel sustainability. However, the use of biomass alone for power generation is subject to serious challenges, such as feedstock supply reliability, quality, and stability, as well as comparative cost, except in situations in which biomass is locally sourced. In most countries, only a limited biomass supply infrastructure exists. Alternatively, co-firing biomass alongwith coal offers several advantages; these include reducing challenges related to biomass quality, buffering the system against insufficient feedstock quantity, and mitigating the costs of adapting existingmore » coal power plants to feed biomass exclusively. There are some technical constraints, such as low heating values, low bulk density, and grindability or size-reduction challenges, as well as higher moisture, volatiles, and ash content, which limit the co-firing ratios in direct and indirect co-firing. To achieve successful co-firing of biomass with coal, biomass feedstock specifications must be established to direct pretreatment options in order to modify biomass materials into a format that is more compatible with coal co-firing. The impacts on particle transport systems, flame stability, pollutant formation, and boiler-tube fouling/corrosion must also be minimized by setting feedstock specifications, which may include developing new feedstock composition by formulation or blending. Some of the issues, like feeding, co-milling, and fouling, can be overcome by pretreatment methods including washing/leaching, steam explosion, hydrothermal carbonization, and torrefaction, and densification methods such as pelletizing and briquetting. Integrating formulation, pretreatment, and densification will help to overcome issues related to physical and chemical composition, storage, and logistics to successfully co-fire higher percentages of biomass ( > 40%) with coal.« less
Comparative study of different waste biomass for energy application.
Motghare, Kalyani A; Rathod, Ajit P; Wasewar, Kailas L; Labhsetwar, Nitin K
2016-01-01
Biomass is available in many varieties, consisting of crops as well as its residues from agriculture, forestry, and the agro-industry. These different biomass find their way as freely available fuel in rural areas but are also responsible for air pollution. Emissions from such solid fuel combustion to indoor, regional and global air pollution largely depend on fuel types, combustion device, fuel properties, fuel moisture, amount of air supply for combustion and also on climatic conditions. In both economic and environment point of view, gasification constitutes an attractive alternative for the use of biomass as a fuel, than the combustion process. A large number of studies have been reported on a variety of biomass and agriculture residues for their possible use as renewable fuels. Considering the area specific agriculture residues and biomass availability and related transportation cost, it is important to explore various local biomass for their suitability as a fuel. Maharashtra (India) is the mainstay for the agriculture and therefore, produces a significant amount of waste biomass. The aim of the present research work is to analyze different local biomass wastes for their proximate analysis and calorific value to assess their potential as fuel. The biomass explored include cotton waste, leaf, soybean waste, wheat straw, rice straw, coconut coir, forest residues, etc. mainly due to their abundance. The calorific value and the proximate analysis of the different components of the biomass helped in assessing its potential for utilization in different industries. It is observed that ash content of these biomass species is quite low, while the volatile matter content is high as compared to Indian Coal. This may be appropriate for briquetting and thus can be used as a domestic fuel in biomass based gasifier cook stoves. Utilizing these biomass species as fuel in improved cook-stove and domestic gasifier cook-stoves would be a perspective step in the rural energy and environmental sectors. This is important considering that the cleaner fuel like LPG is still not available in rural areas of many parts of the world. Copyright © 2015 Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Sun, Jian; Shen, Zhenxing; Cao, Junji; Zhang, Leiming; Wu, Tingting; Zhang, Qian; Yin, Xiuli; Lei, Yali; Huang, Yu; Huang, R.-J.; Liu, Suixin; Han, Yongming; Xu, Hongmei; Zheng, Chunli; Liu, Pingping
2017-02-01
Maize straw smoldering in "Heated Kang" is the traditional way for heating in winter in rural areas of Guanzhong Plain. This smolder procedure produced large quantities of pollutants and got more and more concern from both public and researchers. In this study, on-site measurements of straw smoldering in a residence with a Chinese 'Heated Kang' (Scenario 1) were done to determine the emissions factors (EFs) for pollutants. Moreover, EFs of pollutants from an advanced stove fired with maize straw (Scenario 2) and maize-straw pellet (Scenario 3) had been conducted in a laboratory to find the new measure to reduce the pollution emissions. The results showed that the EFs of PM2.5 for three scenarios were 38.26 ± 13.94 g·kg- 1, 17.50 ± 8.29 g·kg- 1 and 2.95 ± 0.71 g·kg- 1, respectively. Comparing EFs of pollutants from 3 scenarios indicates that both briquetting of straw and advanced stove with air distribution system could efficiently reduce pollutants emission especially for Scenario 3. In detail, EFs of PM2.5, OC, EC and water soluble ions all have over 90% reduction between Scenarios 1 and 3. All particle-size distributions were unimodal, and all peaked in particle sizes < 0.47 μm. The EFs for K+ and Cl- were the highest of cations and anions for the majority of size groups. Converting to pellets and advanced stoves for residential heating could reduce PM2.5 emission from 48.3 Gg to 3.59 Gg, OC from 19.0 Gg to 0.91 Gg, EC from 1.7 Gg to 0.17 Gg and over 90% reduction on total water soluble ions in the whole region. A box model simulation for the Guanzhong Plain indicated that this conversion would lead to a 7.7% reduction in PM2.5 (from 130 to 120 μg·m- 3) in normal conditions and a 14.2% reduction (from 350 to 300 μg·m- 3) in hazy conditions. The results highlighted that the straw pellets burning in advanced stove can effectively reduce pollutants emitted and improve the energy use efficiency in comparison with maize straw smoldering in "Heated Kang". The study supplies an effective measure to reduce the rural biomass burning emission, and this method can be used in not only Guanzhong Plain but also other undeveloped areas in the future.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Gug, JeongIn, E-mail: Jeongin_gug@student.uml.edu; Cacciola, David, E-mail: david_cacciola@student.uml.edu; Sobkowicz, Margaret J., E-mail: Margaret_sobkowiczkline@uml.edu
Highlights: • Briquetting was used to produce solid fuels from municipal solid waste and recycled plastics. • Optimal drying, processing temperature and pressure were found to produce stable briquettes. • Addition of waste plastics yielded heating values comparable with typical coal feedstocks. • This processing method improves utilization of paper and plastic diverted from landfills. - Abstract: Diversion of waste streams such as plastics, woods, papers and other solid trash from municipal landfills and extraction of useful materials from landfills is an area of increasing interest especially in densely populated areas. One promising technology for recycling municipal solid waste (MSW)more » is to burn the high-energy-content components in standard coal power plant. This research aims to reform wastes into briquettes that are compatible with typical coal combustion processes. In order to comply with the standards of coal-fired power plants, the feedstock must be mechanically robust, free of hazardous contaminants, and moisture resistant, while retaining high fuel value. This study aims to investigate the effects of processing conditions and added recyclable plastics on the properties of MSW solid fuels. A well-sorted waste stream high in paper and fiber content was combined with controlled levels of recyclable plastics PE, PP, PET and PS and formed into briquettes using a compression molding technique. The effect of added plastics and moisture content on binding attraction and energy efficiency were investigated. The stability of the briquettes to moisture exposure, the fuel composition by proximate analysis, briquette mechanical strength, and burning efficiency were evaluated. It was found that high processing temperature ensures better properties of the product addition of milled mixed plastic waste leads to better encapsulation as well as to greater calorific value. Also some moisture removal (but not complete) improves the compacting process and results in higher heating value. Analysis of the post-processing water uptake and compressive strength showed a correlation between density and stability to both mechanical stress and humid environment. Proximate analysis indicated heating values comparable to coal. The results showed that mechanical and moisture uptake stability were improved when the moisture and air contents were optimized. Moreover, the briquette sample composition was similar to biomass fuels but had significant advantages due to addition of waste plastics that have high energy content compared to other waste types. Addition of PP and HDPE presented better benefits than addition of PET due to lower softening temperature and lower oxygen content. It should be noted that while harmful emissions such as dioxins, furans and mercury can result from burning plastics, WTE facilities have been able to control these emissions to meet US EPA standards. This research provides a drop-in coal replacement that reduces demand on landfill space and replaces a significant fraction of fossil-derived fuel with a renewable alternative.« less
Biomass energy: Sustainable solution for greenhouse gas emission
NASA Astrophysics Data System (ADS)
Sadrul Islam, A. K. M.; Ahiduzzaman, M.
2012-06-01
Biomass is part of the carbon cycle. Carbon dioxide is produced after combustion of biomass. Over a relatively short timescale, carbon dioxide is renewed from atmosphere during next generation of new growth of green vegetation. Contribution of renewable energy including hydropower, solar, biomass and biofuel in total primary energy consumption in world is about 19%. Traditional biomass alone contributes about 13% of total primary energy consumption in the world. The number of traditional biomass energy users expected to rise from 2.5 billion in 2004 to 2.6 billion in 2015 and to 2.7 billion in 2030 for cooking in developing countries. Residential biomass demand in developing countries is projected to rise from 771 Mtoe in 2004 to 818 Mtoe in 2030. The main sources of biomass are wood residues, bagasse, rice husk, agro-residues, animal manure, municipal and industrial waste etc. Dedicated energy crops such as short-rotation coppice, grasses, sugar crops, starch crops and oil crops are gaining importance and market share as source of biomass energy. Global trade in biomass feedstocks and processed bioenergy carriers are growing rapidly. There are some drawbacks of biomass energy utilization compared to fossil fuels viz: heterogeneous and uneven composition, lower calorific value and quality deterioration due to uncontrolled biodegradation. Loose biomass also is not viable for transportation. Pelletization, briquetting, liquefaction and gasification of biomass energy are some options to solve these problems. Wood fuel production is very much steady and little bit increase in trend, however, the forest land is decreasing, means the deforestation is progressive. There is a big challenge for sustainability of biomass resource and environment. Biomass energy can be used to reduce greenhouse emissions. Woody biomass such as briquette and pellet from un-organized biomass waste and residues could be used for alternative to wood fuel, as a result, forest will be saved and sustainable carbon sink will be developed. Clean energy production from biomass (such as ethanol, biodiesel, producer gas, bio-methane) could be viable option to reduce fossil fuel consumption. Electricity generation from biomass is increasing throughout the world. Co-firing of biomass with coal and biomass combustion in power plant and CHP would be a viable option for clean energy development. Biomass can produce less emission in the range of 14% to 90% compared to emission from fossil for electricity generation. Therefore, biomass could play a vital role for generation of clean energy by reducing fossil energy to reduce greenhouse gas emissions. The main barriers to expansion of power generation from biomass are cost, low conversion efficiency and availability of feedstock. Internationalization of external cost in power generation and effective policies to improve energy security and carbon dioxide reduction is important to boost up the bio-power. In the long run, bio-power will depend on technological development and on competition for feedstock with food production and arable land use.
[Personality and somatic disorders].
Darves-Bornoz, J-M
2018-06-08
In the title of this text, by somatic disorders we mean those physical illnesses clearly related to a non-psychiatric medical field, frequently termed psychosomatic illnesses and somatoform disorders. For forty years, a trend of thought has focused with pertinence on the psychological peculiarities in patients with severe somatic diseases. Moreover, causality was often supposed in the regularly mentioned association between personality features and somatoform disorders. However, the revival of the study of the earlier field of relationships between mind and body by Briquet, Charcot, Janet and Freud in his first period has led to the reassessment of the meaning of these observations. This reexamination is marked out by several assertions. Two of them work as preliminaries to argumentation: 1. existential wounds may produce long-lasting personality alterations; 2. existential wounds may produce somatoform disorders. These phenomena have been rediscovered over the last few years among assaulted subjects as well as war veterans in whom a frequent occurrence of somatizations has been, in addition, closely linked to the incidence of behavior or personality disorders. Two theses then emerge: 1. somatic diseases may produce long-lasting personality alterations; 2. until now no premorbid personality univocally predisposing to somatic diseases could be found. Indeed, during the 1980s a growing body of negative results coming from retrospective and prospective studies as well as anatomical comparisons have accumulated upon the potential role of certain personality factors in the incidence of somatic illnesses. This dialectic leads to the connection of two corollary assertions: 1. "pensée opératoire" and "alexithymia" in patients with somatic diseases may represent only an effect of the announcement or chronicity of the organic disease; 2. the old "dissociative hysteria" with somatic manifestations finds its substratum in existential wounds and not in pre-trauma personality. Indeed, on the one hand, recent publications do not allow the assertion to be confirmed that alexithymia and "pensée opératoire" predispose to somatizations. On the other hand, personality disorders in subjects with "dissociative hysteria" as well as their somatoform symptoms appear mainly as an effect of an existential wound and express in fact the Janetian concept of "a drop in Psychological Tension". Then, in spite of their differences, conversion and psychosomatic symptoms share the property of being a primitive response to existential wounds in which the subject cannot produce any appropriate psychic or behavioral response to his distress. Light is shed on these phenomena when put alongside the field of "fixed ideas" thought of by Pierre Janet as the recourse to archaic automatisms. Indeed, the experience which contradicts the vision of existence provokes an "unspeakable terror". It is mentally unrepresented or represented in too slight a way. In such cases, no previous personality prevails, but the resulting personality often appears modified, including when the breakdown of vision of the existence results from the diagnosis of an illness or its protracted course. Copyright © 2018 L'Encéphale, Paris. Published by Elsevier Masson SAS. All rights reserved.
NASA Astrophysics Data System (ADS)
Kapko, Vitaliy; Zhao, Zuofeng; Matyushov, Dmitry V.; Austen Angell, C.
2013-03-01
The ability of some liquids to vitrify during supercooling is usually seen as a consequence of the rates of crystal nucleation (and/or crystal growth) becoming small [D. R. Uhlmann, J. Non-Cryst. Solids 7, 337 (1972), 10.1016/0022-3093(72)90269-4] - and thus a matter of kinetics. However, there is evidence dating back to the empirics of coal briquetting for maximum trucking efficiency [D. Frenkel, Physics 3, 37 (2010), 10.1103/Physics.3.37] that some object shapes find little advantage in self-assembly to ordered structures - meaning random packings prevail. Noting that key studies of non-spherical object packing have never been followed from hard ellipsoids [A. Donev, F. H. Stillinger, P. M. Chaikin, and S. Torquato, Phys. Rev. Lett. 92, 255506 (2004), 10.1103/PhysRevLett.92.255506; A. Donev, I. Cisse, D. Sachs, E. A. Variano, F. H. Stillinger, R. Connelly, S. Torquato, and P. M. Chaikin, Science 303, 990 (2004), 10.1126/science.1093010] or spherocylinders [S. R. Williams and A. P. Philipse, Phys. Rev. E 67, 051301 (2003), 10.1103/PhysRevE.67.051301] (diatomics excepted [S.-H. Chong, A. J. Moreno, F. Sciortino, and W. Kob, Phys. Rev. Lett. 94, 215701 (2005), 10.1103/PhysRevLett.94.215701] into the world of molecules with attractive forces, we have made a molecular dynamics study of crystal melting and glass formation on the Gay-Berne (G-B) model of ellipsoidal objects [J. G. Gay and B. J. Berne, J. Chem. Phys. 74, 3316 (1981), 10.1063/1.441483] across the aspect ratio range of the hard ellipsoid studies. Here, we report that in the aspect ratio range of maximum ellipsoid packing efficiency, various G-B crystalline states that cannot be obtained directly from the liquid, disorder spontaneously near 0 K and transform to liquids without any detectable enthalpy of fusion. Without claiming to have proved the existence of single component examples, we use the present observations, together with our knowledge of non-ideal mixing effects, to discuss the probable existence of "ideal glassformers" - single or multicomponent liquids that vitrify before ever becoming metastable with respect to crystals. We find evidence that "ideal glassformer" systems might also be highly fragile systems, approaching the "ideal glass" condition. We link this to the high "volume fragility" behavior observed in recent hard dumbbell studies at similar length/diameter ratios [R. Zhang and K. S. Schweitzer, J. Chem. Phys. 133, 104902 (2010), 10.1063/1.3483601]. The discussion suggests some unusual systems for laboratory study. Using differential scanning calorimetry detection of fusion points Tm, liquidus temperatures Tl, and glass transition temperatures Tg, we describe a system that would seem incapable of crystallizing before glass transition, i.e., an "ideal glassformer." The existence of crystal-free routes to the glassy state will eliminate precrystalline fluctuations as a source of the dynamic heterogeneities that are generally considered important in the discussion of the "glassy state problem [P. W. Anderson, Science 267, 1615 (1995), 10.1126/science.267.5204.1615-e]."
A Complex Use of the Materials Extracted from an Open-Cast Lignite Mine
NASA Astrophysics Data System (ADS)
Buryan, Petr; Bučko, Zdeněk; Mika, Petr
2014-12-01
The company Sokolovská uhelná, was the largest producer of city gas in the Czech Republic. After its substitution by natural gas the gasification technology became the basis of the production of electricity in the combine cycle power plant with total output 400 MW. For the possibility of gasification of liquid by- -products forming during the coal gasification a entrained-flow gasifier capable to process also alternative liquid fuels has been in installed. The concentrated waste gas with these sulphur compounds is conducted to the desulphurisation where the highly desired, pure, 96 % H2SO4 is produced. Briquettable brown coal is crushed, milled and dried and then it is passed into briquetting presses where briquettes, used mainly as a fuel in households, are pressed without binder in the punch under the pressure of 175 MPa. Fine brown coal dust (multidust) is commercially used for heat production in pulverized-coal burners. It forms not only during coal drying after separation on electrostatic separators, but it is also acquired by milling of dried coal in a vibratory bar mill. Slag from boilers of classical power plant, cinder form generators and ashes deposited at the dump are dehydrated and they are used as a quality bedding material during construction of communications in the mines of SUAS. Fly ash is used in building industry for partial substitution of cement in concrete. Flue gases after separation of fly ash are desulphurized by wet limestone method, where the main product is gypsum used, among others, in the building industry. Expanded clays from overburdens of coal seams, that are raw material for the production of "Liapor" artificial aggregate, are used heavily. This artificial aggregate is characterized by outstanding thermal and acoustic insulating properties. Przedsiębiorstwo Sokolovska uhelna jest największym producentem gazu miejskiego w Republice Czeskiej. Po jego zastąpieniu przez gaz ziemny, technologia gazyfikacji stała się podstawą do produkcji elektryczności w elektrowni o cyklu mieszanym o całkowitej mocy wyjściowej 400 MW. W celu umożliwienia gazyfikacji ciekłych produktów ubocznych gazyfikacji węgla, zainstalowano na drodze przepływu generator gazu, umożliwiający przetwarzanie alternatywnych paliw ciekłych. Skoncentrowany gaz odlotowy zawierający związki siarki odprowadzany jest do instalacji odsiarczającej, gdzie produkowany jest cenny produkt H2SO4, o wysokim stopniu czystości (96%). Węgiel brunatny nadający się do produkcji brykietów jest kruszony, mielony i suszony, następnie przechodzi przez proces brykietowania w odpowiednich prasach, gdzie formowane są brykiety, poprzez ich sprasowanie pod ciśnieniem 175 MPa. Brykiety takie wykorzystywane są powszechnie jako paliwo w gospodarstwach domowych. Drobnoziarniste pyły węgla brunatnego (paliwa pyłowe) wykorzystywane są na skalę komercyjną do produkcji ciepła w paleniskach pyłowych. Pyły węglowe powstają nie tylko w trakcie suszenia węgla po procesie oddzielania w separatorach elektrostatycznych, lecz także w procesie mielenia suszonego węgla w młynach wibracyjnych. Żużel z kotłów w konwencjonalnej elektrowni, popioły z generatorów oraz te osadzające się w instalacji podlegają wysuszeniu, następnie wykorzystywane są jako wysokiej jakości materiał na podłoże w różnorodnych instalacjach. Popioły lotne wykorzystywane są przemyśle budowlanym jako częściowe zamienniki cementu. Po oddzieleni popiołu lotnego, gazy wylotowe kierowane są do instalacji odsiarczania z wykorzystaniem technologii wilgotnego wapienia, w wyniku tego procesu powstaje gips, wykorzystywany, miedzy innymi, w przemyśle budowlanym. Glinki z warstw nadkładu nad pokładami węgla wykorzystywane są powszechnie jako surowiec do produkcji sztucznego kruszywa "Liapor', wykazującego wyjątkowe właściwości termiczne i dźwiękoizolacyjne.
Twenty-Sixth Annual Report of the Director of the United States Geological Survey, 1904-1905
Walcott, Charles D.
1905-01-01
IntroductionRemarks on the work of the yearBranches of workThe United States Geological Survey was created in 1879 for the purpose—as its name implies—of examining and reporting on the geologic structure and mineral resources and products of the national domain. To the adequate description of geologic formations and structure cartography is essential, and Congress early recognized this fact by making appropriations for the preparation of a geologic map of the United States. The topographic base map, in order to show with sufficient precision the relations of the geologic formations and the intricacies of the structure, must have a rather large scale and present considerable detail. No such map of this country existed in 1879, and its preparation was immediately begun. The waters of the country are of vast importance, and in a broad sense may be regarded as one of its greatest mineral resources. Hence, in the evolution of the work of the Survey, and especially in view of the great importance of the subject to the irrigation interests, Congress early began making appropriations for ascertaining the amount and quality of the surface and underground waters and when, in 1902, the service for the reclamation of arid lands was organized, that work naturally was placed in the hands of the Secretary of the Interior and by him intrusted to the Director of the Survey.The three great branches of work carried on by the Geological Survey are, therefore, the geologic, the topographic, and the hydrographic, and with these, more especially the latter, is conjoined the Reclamation Service ; publication and administration constitute necessary auxiliary branches. Along these great lines the work of the Survey has progressed without essential variation for many years. The changes made have been due to normal expansion rather than to radical departure in object or plan.State cooperationDuring the last fiscal year, State cooperation, as explained in previous reports, continued. Arrangements for cooperation in geologic work were made with five States, the total amount contributed by them being about \\$8,000, and arrangements for cooperative topographic surveys were made with eleven States, the amount available for such surveys being thus increased by more than \\$100,000.Reclamation serviceThe work of the Reclamation Service during the last fiscal year was advanced as rapidly as was thought consistent with thoroughness and accuracy. Actual construction is now in progress on eight projects, as follows : Salt River, Arizona; Truckee-Carson, Nevada; Hondo, New Mexico ; Uncompahgre Valley, Colorado; Minidoka, Idaho; Belle Fourche, South Dakota ; North Platte, Wyoming and Nebraska ; and Shoshone, Wyoming. Proposals were received for work on the Laguna dam, Yuma project, California and Arizona; Huntley project, Montana, and the Fort Buford project, North Dakota and Montana. In several other States operations are at a point where advertisements for bids only await the removal of certain legal obstacles, the settlement of international difficulties, or the termination of delays on the part of local organizations or individuals.The organization of the body of men constituting the personnel of the Reclamation Service, whose field of operations covers so large a territory, though necessarily difficult, has been satisfactorily accomplished, and precedents have been established along approved lines. The general allotment of funds has been made with a view to the greatest benefit to the greatest number, and from the broad standpoint of the welfare of the country as a whole.One of the important features in the evolution of the irrigation work is the development of power, which the numerous dams and, drops in canals make possible. Plans were made to transmit the power being developed in many sections of the arid regions, by means of electricity, to points more or less distant, there to be used for raising underground waters, pumping waters lying above the line of gravity canals, or for various other purposes, and attention was also given to the character of the soils and of the water to be used upon them, the materials used in the construction of the works, and numerous other details incident to reclamation by irrigation.Coal-testing plantUnder two special appropriations of \\$30,000 each, carried by the urgent deficiency bill approved February 18, 1904, and the general deficiency bill approved April 27, 1904, the Director of the Geological Survey was authorized to construct and operate at the Louisiana Purchase Exposition a plant for testing the coals and lignites of the United States, in order to determine their fuel values and the most economic method of their utilization for different purposes, it being provided that all testing machinery and all coals and lignites to be tested 'should be contributed free of charge to the Government. For carrying out the provisions of these acts the Director appointed a committee, consisting of Edward W. Parker, Joseph A. Holmes, and Marius R. Campbell, to direct the construction and operation of the plant. This committee received the heartiest cooperation from the manufacturers of such equipment as was needed for the installation of the plant, from the railroad companies in freight concessions and transportation for the experts and their assistants, and from the coal operators in the furnishing of coal in carload lots for testing purposes. Although the utmost expedition was used in the construction of the plant, it was not until the first of September that the testing work actually began. Between the first of September and the close of the exposition 65 carload samples of coal for testing purposes were received, and the results of the investigation were published in a preliminary report issued as Geological Survey Bulletin No. 261. The coals tested were received from 17 States and Territories, and much valuable information regarding the best uses to which the different coals may be put was obtained.One of the most important facts developed during this investigation is the possibility of utilizing the vast lignite resources of the West in the manufacture of producer gas, it having been shown that a higher grade of this gas can be obtained from lignite than from ordinary bituminous and anthracite coal. The investigation also showed that the slack or fine coal produced at the dry, noncoking bituminous coal mines of the middle West, large quantities of which are now being wasted, can be profitably utilized by briquetting.