Engineering fluid flow using sequenced microstructures

NASA Astrophysics Data System (ADS)

Amini, Hamed; Sollier, Elodie; Masaeli, Mahdokht; Xie, Yu; Ganapathysubramanian, Baskar; Stone, Howard A.; di Carlo, Dino

2013-05-01

Controlling the shape of fluid streams is important across scales: from industrial processing to control of biomolecular interactions. Previous approaches to control fluid streams have focused mainly on creating chaotic flows to enhance mixing. Here we develop an approach to apply order using sequences of fluid transformations rather than enhancing chaos. We investigate the inertial flow deformations around a library of single cylindrical pillars within a microfluidic channel and assemble these net fluid transformations to engineer fluid streams. As these transformations provide a deterministic mapping of fluid elements from upstream to downstream of a pillar, we can sequentially arrange pillars to apply the associated nested maps and, therefore, create complex fluid structures without additional numerical simulation. To show the range of capabilities, we present sequences that sculpt the cross-sectional shape of a stream into complex geometries, move and split a fluid stream, perform solution exchange and achieve particle separation. A general strategy to engineer fluid streams into a broad class of defined configurations in which the complexity of the nonlinear equations of fluid motion are abstracted from the user is a first step to programming streams of any desired shape, which would be useful for biological, chemical and materials automation.

Characteristic electron variations across simple high-speed solar wind streams

NASA Technical Reports Server (NTRS)

Feldman, W. C.; Asbridge, J. R.; Bame, S. J.; Gosling, J. T.; Lemons, D. S.

1978-01-01

The paper deals with electron variations across simple high-speed streams. Comprehensive scans of the shapes of electron distributions measured at the highest bulk speeds confirm the results of Rosenbauer et al. (1976, 1977) and show that the electron velocity distributions can be broken down into a low-energy or core component and a high-energy strongly beamed component. The low-energy component displays many characteristics expected from a fluid: the internal particle coupling necessary to maintain this state must result from both binary Coulomb collisions and wave-particle interactions. The high-energy or halo component displays many characteristics expected to develop in the absence of collisions beyond a certain base radius. These electrons appear to evolve under the primary influence of static interplanetary magnetic and electric fields and, therefore, develop very anisotropic velocity distributions.

Vortex combustor for low NOX emissions when burning lean premixed high hydrogen content fuel

DOEpatents

Steele, Robert C; Edmonds, Ryan G; Williams, Joseph T; Baldwin, Stephen P

2012-11-20

A trapped vortex combustor. The trapped vortex combustor is configured for receiving a lean premixed gaseous fuel and oxidant stream, where the fuel includes hydrogen gas. The trapped vortex combustor is configured to receive the lean premixed fuel and oxidant stream at a velocity which significantly exceeds combustion flame speed in a selected lean premixed fuel and oxidant mixture. The combustor is configured to operate at relatively high bulk fluid velocities while maintaining stable combustion, and low NOx emissions. The combustor is useful in gas turbines in a process of burning synfuels, as it offers the opportunity to avoid use of diluent gas to reduce combustion temperatures. The combustor also offers the possibility of avoiding the use of selected catalytic reaction units for removal of oxides of nitrogen from combustion gases exiting a gas turbine.

Vortex combustor for low NOx emissions when burning lean premixed high hydrogen content fuel

DOEpatents

Steele, Robert C [Woodinville, WA; Edmonds, Ryan G [Renton, WA; Williams, Joseph T [Kirkland, WA; Baldwin, Stephen P [Winchester, MA

2009-10-20

A trapped vortex combustor. The trapped vortex combustor is configured for receiving a lean premixed gaseous fuel and oxidant stream, where the fuel includes hydrogen gas. The trapped vortex combustor is configured to receive the lean premixed fuel and oxidant stream at a velocity which significantly exceeds combustion flame speed in a selected lean premixed fuel and oxidant mixture. The combustor is configured to operate at relatively high bulk fluid velocities while maintaining stable combustion, and low NOx emissions. The combustor is useful in gas turbines in a process of burning synfuels, as it offers the opportunity to avoid use of diluent gas to reduce combustion temperatures. The combustor also offers the possibility of avoiding the use of selected catalytic reaction units for removal of oxides of nitrogen from combustion gases exiting a gas turbine.

Hyporheic less-mobile porosity and solute transport in porous media

NASA Astrophysics Data System (ADS)

MahmoodPoorDehkordy, F.; Briggs, M. A.; Day-Lewis, F. D.; Scruggs, C.; Singha, K.; Zarnetske, J. P.; Lane, J. W., Jr.; Bagtzoglou, A. C.

2017-12-01

Solute transport and reactive processes are strongly influenced by hydrodynamic exchange with the hyporheic zone. Contaminant transport and redox zonation in the hyporheic zone and near-stream aquifer can be impacted by the exchange between mobile and less-mobile porosity zones in heterogeneous porous media. Less-mobile porosity zones can be created by fine materials with tight pore throats (e.g. clay, organics) and in larger, well-connected pores down gradient of flow obstructions (e.g. sand behind cobbles). Whereas fluid sampling is primarily responsive to the more-mobile domain, tracking solute tracer dynamics by geoelectrical methods provides direct information about both more- and less-mobile zones. During tracer injection through porous media of varied pore connectivity, a lag between fluid and bulk electrical conductivity is observed, creating a hysteresis loop when plotted in conductivity space. Thus, the combination of simultaneous fluid and bulk electrical conductivity measurements enables a much improved quantification of less-mobile solute dynamics compared to traditional fluid-only sampling approaches. We have demonstrated the less-mobile porosity exchange in laboratory-scale column experiments verified by simulation models. The experimental approach has also been applied to streambed sediments in column and reach-scale field experiments and verified using numerical simulation. Properties of the resultant hysteresis loops can be used to estimate exchange parameters of less-mobile porosity. Our integrated approach combining field experiments, laboratory experiments, and numerical modeling provides new insights into the effect of less-mobile porosity on solute transport in the hyporheic zone.

Reduction of diffusional defocusing in hydrodynamically focused flows

DOEpatents

Affleck, Rhett L.; Demas, James N.; Goodwin, Peter M.; Keller, Richard; Wu, Ming

1998-01-01

An analyte fluid stream with first molecules having relatively low molecular weight and a corresponding high coefficient of diffusion has reduced diffusional defocusing out of an analyte fluid stream. The analyte fluid stream of first molecules is associated with second molecules of relatively high molecular weight having a relatively low coefficient of diffusion and a binding constant effective to associate with the first molecules. A focused analyte fluid stream is maintained since the combined molecular weight of the associated first and second molecules is effective to minimize diffusion of the first molecules out of the analyte fluid stream.

Reduction of diffusional defocusing in hydrodynamically focused flows

DOEpatents

Affleck, R.L.; Demas, J.N.; Goodwin, P.M.; Keller, R.; Wu, M.

1998-09-01

An analyte fluid stream with first molecules having relatively low molecular weight and a corresponding high coefficient of diffusion has reduced diffusional defocusing out of an analyte fluid stream. The analyte fluid stream of first molecules is associated with second molecules of relatively high molecular weight having a relatively low coefficient of diffusion and a binding constant effective to associate with the first molecules. A focused analyte fluid stream is maintained since the combined molecular weight of the associated first and second molecules is effective to minimize diffusion of the first molecules out of the analyte fluid stream. 6 figs.

High temperature methods for forming oxidizer fuel

DOEpatents

Bravo, Jose Luis [Houston, TX

2011-01-11

A method of treating a formation fluid includes providing formation fluid from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes carbon dioxide, hydrogen sulfide, hydrocarbons, hydrogen or mixtures thereof. Molecular oxygen is separated from air to form a molecular oxygen stream comprising molecular oxygen. The first gas stream is combined with the molecular oxygen stream to form a combined stream comprising molecular oxygen and the first gas stream. The combined stream is provided to one or more downhole burners.

Substantial reduction of the heat losses to ambient air by natural convection from horizontal in-tube flows: impact of an axial bundle of passive baffles

NASA Astrophysics Data System (ADS)

Campo, A.; Cortés, C.

This paper is concerned with a distinct and effective technique to insulate horizontal tubes carrying hot fluids without using the variety of insulating materials traditionally utilized in industry. The tubes transport hot fluids and are exposed to a natural convection environment of air at standard atmospheric temperature and pressure. Essentially, an ``equivalent quantity of insulation'' is provided by an envelope of straight symmetric baffles made from a low conductivity material that is affixed to the outer surface of the horizontal tubes. A simple 1-D lumped model of comparable precision to the customary 2-D differential model serves to regulate the thermal interaction between the two perpendicular fluid streams, one horizontal due to internal forced convection and the other vertical due to external natural convection in air. All computations are algebraic and lead to a rapid determination of the two quantities that are indispensable to design engineers: the mean bulk temperatures of the internal hot fluid moving either laminarly or turbulently, together with the degraded levels of heat transfer rates.

Energy Harvesting Systems and Methods of Assembling Same

NASA Technical Reports Server (NTRS)

Cepeda-Rizo, Juan (Inventor); Ganapathi, Gani B. (Inventor)

2013-01-01

A method of assembling an energy harvesting system is provided. The method includes coupling at least one energy storage device in flow communication with at least one apparatus that is configured to generate thermal energy and to transfer the thermal energy into at least one fluid stream. The energy storage device is configured to store the fluid stream. Moreover, the method includes coupling at least one fluid transfer device downstream from the energy storage device. The fluid transfer device receives the fluid stream from the energy storage device. A bladeless turbine is coupled in flow communication with the fluid transfer device, wherein the bladeless turbine receives the fluid stream to generate power.

Improved understanding of the relationship between hydraulic properties and streaming potentials

NASA Astrophysics Data System (ADS)

Cassiani, G.; Brovelli, A.

2009-12-01

Streaming potential (SP) measurements have been satisfactorily used in a number of recent studies as a non-invasive tool to monitor fluid movement in both the vadose and the saturated zone. SPs are generated from the coupling between two independent physical processes oc-curring at the pore-level, namely water flow and excess of ions at the negatively charged solid matrix-water interface. The intensity of the measured potentials depends on physical proper-ties of the medium, including the internal micro-geometry of the system, the charge density of the interface and the composition of the pore fluid, which affects its ionic strength, pH and redox potential. The goal of this work is to investigate whether a relationship between the intensity of the SPs and the saturated hydraulic conductivity can be identified. Both properties are - at least to some extent - dependent on the pore-size distribution and connectivity of the pores, and there-fore some degree of correlation is expected. We used a pore-scale numerical model previously developed to simulate both the bulk hydraulic conductivity and the intensity of the SPs gener-ated in a three-dimensional pore-network. The chemical-physical properties of both the inter-face (Zeta-potential) and of the aqueous phase are computed using an analytical, physically based model that has shown good agreement with experimental data. Modelling results were satisfactorily compared with experimental data, showing that the model, although simplified retains the key properties and mechanisms that control SP generation. A sensitivity analysis with respect to the key geometrical and chemical parameters was conducted to evaluate how the correlation between the two studied variables changes and to ascertain whether the bulk hydraulic conductivity can be estimated from SP measurements alone.

An experimental study of reactive turbulent mixing

NASA Technical Reports Server (NTRS)

Cooper, L. P.; Marek, C. J.; Strehlow, R. A.

1977-01-01

An experimental study of two coaxial gas streams, which react very rapidly, was performed to investigate the mixing characteristics of turbulent flow fields. The center stream consisted of a CO-N2 mixture and the outer annular stream consisted of air vitiated by H2 combustion. The streams were at equal velocity (50 m/sec) and temperature (1280 K). Turbulence measurements were obtained using hot film anemometry. A sampling probe was used to obtain time averaged gas compositions. Six different turbulence generators were placed in the annular passage to alter the flow field mixing characteristics. The turbulence generators affected the bulk mixing of the streams and the extent of CO conversion to different degrees. The effects can be related to the average eddy size (integral scale) and the bulk mixing. Higher extents of conversion of CO to CO2 were found be increasing the bulk mixing and decreasing the average eddy size.

Apparatus for measuring a sorbate dispersed in a fluid stream

NASA Technical Reports Server (NTRS)

Updike, O. L. (Inventor)

1977-01-01

A sensitive, miniature apparatus was designed for measuring low concentrations of a sorbate dispersed in a fluid stream. The device consists of an elongated body having a surface capable of sorbing an amount of the sorbate proportional to the concentration in the fluid stream and propagating acoustic energy along its length. The acoustic energy is converted to an electrical output signal corresponding to the concentration of sorbate in the fluid stream. The device can be designed to exhibit high sensitivity to extremely small amounts of sorbate dispersed in a fluid stream and to exhibit low sensitivity to large amounts of sorbate. Another advantage is that the apparatus may be formed in a microminiature size and at a low cost using bath microfabrication technology.

Method of aeration disinfecting and drying grain in bulk and pretreating seeds and a transverse blow silo grain dryer therefor

DOEpatents

Danchenko, Vitaliy G [Dnipropetrovsk, UA; Noyes, Ronald T [Stillwater, OK; Potapovych, Larysa P [Dnipropetrovsk, UA

2012-02-28

Aeration drying and disinfecting grain crops in bulk and pretreating seeds includes passing through a bulk of grain crops and seeds disinfecting and drying agents including an ozone and air mixture and surrounding air, subdividing the disinfecting and drying agents into a plurality of streams spaced from one another in a vertical direction, and passing the streams at different heights through levels located at corresponding heights of the bulk of grain crops and seeds transversely in a substantially horizontal direction.

Process for heating coal-oil slurries

DOEpatents

Braunlin, W.A.; Gorski, A.; Jaehnig, L.J.; Moskal, C.J.; Naylor, J.D.; Parimi, K.; Ward, J.V.

1984-01-03

Controlling gas to slurry volume ratio to achieve a gas holdup of about 0.4 when heating a flowing coal-oil slurry and a hydrogen containing gas stream allows operation with virtually any coal to solvent ratio and permits operation with efficient heat transfer and satisfactory pressure drops. The critical minimum gas flow rate for any given coal-oil slurry will depend on numerous factors such as coal concentration, coal particle size distribution, composition of the solvent (including recycle slurries), and type of coal. Further system efficiency can be achieved by operating with multiple heating zones to provide a high heat flux when the apparent viscosity of the gas saturated slurry is highest. Operation with gas flow rates below the critical minimum results in system instability indicated by temperature excursions in the fluid and at the tube wall, by a rapid increase and then decrease in overall pressure drop with decreasing gas flow rate, and by increased temperature differences between the temperature of the bulk fluid and the tube wall. At the temperatures and pressures used in coal liquefaction preheaters the coal-oil slurry and hydrogen containing gas stream behaves essentially as a Newtonian fluid at shear rates in excess of 150 sec[sup [minus]1]. The gas to slurry volume ratio should also be controlled to assure that the flow regime does not shift from homogeneous flow to non-homogeneous flow. Stable operations have been observed with a maximum gas holdup as high as 0.72. 29 figs.

Process for heating coal-oil slurries

DOEpatents

Braunlin, Walter A.; Gorski, Alan; Jaehnig, Leo J.; Moskal, Clifford J.; Naylor, Joseph D.; Parimi, Krishnia; Ward, John V.

1984-01-03

Controlling gas to slurry volume ratio to achieve a gas holdup of about 0.4 when heating a flowing coal-oil slurry and a hydrogen containing gas stream allows operation with virtually any coal to solvent ratio and permits operation with efficient heat transfer and satisfactory pressure drops. The critical minimum gas flow rate for any given coal-oil slurry will depend on numerous factors such as coal concentration, coal particle size distribution, composition of the solvent (including recycle slurries), and type of coal. Further system efficiency can be achieved by operating with multiple heating zones to provide a high heat flux when the apparent viscosity of the gas saturated slurry is highest. Operation with gas flow rates below the critical minimum results in system instability indicated by temperature excursions in the fluid and at the tube wall, by a rapid increase and then decrease in overall pressure drop with decreasing gas flow rate, and by increased temperature differences between the temperature of the bulk fluid and the tube wall. At the temperatures and pressures used in coal liquefaction preheaters the coal-oil slurry and hydrogen containing gas stream behaves essentially as a Newtonian fluid at shear rates in excess of 150 sec.sup. -1. The gas to slurry volume ratio should also be controlled to assure that the flow regime does not shift from homogeneous flow to non-homogeneous flow. Stable operations have been observed with a maximum gas holdup as high as 0.72.

Spectrometer for measuring the concentration of components in a fluid stream and method for using same

DOEpatents

Durham, Michael D.; Stedman, Donald H.; Ebner, Timothy G.; Burkhardt, Mark R.

1991-01-01

A device and method for measuring the concentrations of components of a fluid stream. Preferably, the fluid stream is an in situ gas stream, such as a fossil fuel fired flue gas in a smoke stack. The measurements are determined from the intensity of radiation over a selected range of radiation wavelengths using peak-to-trough calculations. The need for a reference intensity is eliminated.

Electron Fluid Description of Wave-Particle Interactions in Strong Buneman Turbulence

NASA Astrophysics Data System (ADS)

Che, Haihong

2013-10-01

To understand the nature of anomalous resistivity in magnetic reconnection, we investigate turbulence-induced momentum transport and energy dissipation associated with electron heating in Buneman instability. Using 3D particle-in-cell simulations, we find that the macroscopic effects generated by wave-particle interactions can be described by a set of electron fluid equations. These equations show that the energy dissipation and momentum transports in Buneman instability are locally quasi-static but globally non-static and irreversible. Turbulence drag dissipates both the bulk energy of electron streams and the associated magnetic energy. The decrease of magnetic field maintains an inductive electric field that re-accelerates electrons. The net loss of streaming energy is converted into electron heat and increases the electron Boltzmann entropy. The growth of self-sustained Buneman waves satisfies a Bernoulli-like equation which relates the turbulence-induced convective momentum transport and thermal momentum transport. Electron trapping and de-trapping drives local momentum transports, while phase mixing converts convective momentum into thermal momentum.These two local momentum transports sustain the Buneman waves and act as the micro-macro link in the anomalous heating process. This research is supported by the NASA Postdoctoral Program at NASA/GSFC administered by Oak Ridge Associated Universities through a contract with NASA.

Spectrometer for measuring the concentration of components in a fluid stream and method for using same

DOEpatents

Durham, M.D.; Stedman, D.H.; Ebner, T.G.; Burkhardt, M.R.

1991-12-03

A device and method are described for measuring the concentrations of components of a fluid stream. Preferably, the fluid stream is an in-situ gas stream, such as a fossil fuel fired flue gas in a smoke stack. The measurements are determined from the intensity of radiation over a selected range of radiation wavelengths using peak-to-trough calculations. The need for a reference intensity is eliminated. 15 figures.

Method for filtering solvent and tar sand mixtures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kelterborn, J. C.; Stone, R. A.

1985-09-03

A method for filtering spent tar sands from a bitumen and organic solvent solution comprises separating the solution into two streams wherein the bulk of the coarser spent tar sand is in a first stream and has an average particle size of about 10 to about 100 mesh and the bulk of the finer spent tar sand is in a second stream; producing a filter cake by filtering the coarser spent tar sand from the first stream; and filtering the finer spent tar sand from the second stream with the filter cake. The method is particularly useful for filtering solutionsmore » of bitumen extracted from bitumen containing diatomite, spent diatomite and organic solvent.« less

Apparatus and method for rapid separation and detection of hydrocarbon fractions in a fluid stream

DOEpatents

Sluder, Charles S.; Storey, John M.; Lewis, Sr., Samuel A.

2013-01-22

An apparatus and method for rapid fractionation of hydrocarbon phases in a sample fluid stream are disclosed. Examples of the disclosed apparatus and method include an assembly of elements in fluid communication with one another including one or more valves and at least one sorbent chamber for removing certain classifications of hydrocarbons and detecting the remaining fractions using a detector. The respective ratios of hydrocarbons are determined by comparison with a non separated fluid stream.

Dormancy and Recovery Testing for Biological Wastewater Processors

NASA Technical Reports Server (NTRS)

Hummerick, Mary E.; Coutts, Janelle L.; Lunn, Griffin M.; Spencer, LaShelle; Khodadad, Christina L.; Birmele, Michele N.; Frances, Someliz; Wheeler, Raymond

2015-01-01

Bioreactors, such as the aerated hollow fiber membrane type, have been proposed and studied for a number of years as an alternate approach for treating wastewater streams for space exploration. Several challenges remain to be resolved before these types of bioreactors can be used in space settings, including transporting the bioreactors with intact and active biofilms, whether that be to the International Space Station or beyond, or procedures for safing the systems and placing them into a dormant state for later start-up. Little information is available on such operations as it is not common practice for terrestrial systems. This study explored several dormancy processes for established bioreactors to determine optimal storage and recovery conditions. Procedures focused on complete isolation of the microbial communities from an operational standpoint and observing the effects of: 1) storage temperature, and 2) storage with or without the reactor bulk fluid. The first consideration was tested from a microbial integrity and power consumption standpoint; both ambient temperature (25 C) and cold (4 C) storage conditions were studied. The second consideration was explored; again, for microbial integrity as well as plausible real-world scenarios of how terrestrially established bioreactors would be transported to microgravity and stored for periods of time between operations. Biofilms were stored without the reactor bulk fluid to simulate transport of established biofilms into microgravity, while biofilms stored with the reactor bulk fluid simulated the most simplistic storage condition to implement operations for extended periods of nonuse. Dormancy condition did not have an influence on recovery in initial studies with immature biofilms (48 days old), however a lengthy recovery time was required (20+ days). Bioreactors with fully established biofilms (13 months) were able to recover from a 7-month dormancy period to steady state operation within 4 days (approx. 1 residence cycle). Results indicate a need for future testing on biofilm age and health and further exploration of dormancy length.

Dormancy and Recovery Testing for Biological Wastewater Processors

NASA Technical Reports Server (NTRS)

Hummerick, Mary E.; Coutts, Janelle L.; Lunn, Griffin M.; Spencer, LaShelle; Khodadad, Christina L.; Frances, Someliz; Wheller, Raymond

2015-01-01

Bioreactors, such as aerated membrane type bioreactors have been proposed and studied for a number of years as an alternate approach for treating wastewater streams for space exploration. Several challenges remain before these types of bioreactors can be used in space settings, including transporting the bioreactors with their microbial communities to space, whether that be the International Space Station or beyond, or procedures for safing the systems and placing them into dormant state for later start-up. Little information is available on such operations as it is not common practice for terrestrial systems. This study explored several dormancy processes for established bioreactors to determine optimal storage and recovery conditions. Procedures focused on complete isolation of the microbial communities from an operational standpoint and observing the effects of: 1) storage temperature, and 2) storage with or without the reactor bulk fluid. The first consideration was tested from a microbial integrity and power consumption standpoint; both room temperature (25 C) and cold (4 C) storage conditions were studied. The second consideration was explored; again, for microbial integrity as well as plausible real-world scenarios of how terrestrially established bioreactors would be transported to microgravity and stored for periods of time between operations. Biofilms were stored without the reactor bulk fluid to simulate transport of established biofilms into microgravity, while biofilms stored with the reactor bulk fluid simulated the most simplistic storage condition to implement operations for extended periods of nonuse. Dormancy condition did not have an influence on recovery in initial studies with immature biofilms (48 days old), however, a lengthy recovery time was required (20+ days). Bioreactors with fully established biofilms (13 months) were able to recover from a 7-month dormancy period to steady state operation within 4 days (approximately 1 residence cycle). Results indicate a need for future testing on biofilm age and health and further exploration of dormancy length.

Methods of hydrotreating a liquid stream to remove clogging compounds

DOEpatents

Minderhoud, Johannes Kornelis [Amsterdam, NL; Nelson, Richard Gene [Katy, TX; Roes, Augustinus Wilhelmus Maria [Houston, TX; Ryan, Robert Charles [Houston, TX; Nair, Vijay [Katy, TX

2009-09-22

A method includes producing formation fluid from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a gas stream. At least a portion of the liquid stream is provided to a hydrotreating unit. At least a portion of selected in situ heat treatment clogging compositions in the liquid stream are removed to produce a hydrotreated liquid stream by hydrotreating at least a portion of the liquid stream at conditions sufficient to remove the selected in situ heat treatment clogging compositions.

The fate of calcium carbonate nanoparticles administered by oral route: absorption and their interaction with biological matrices

PubMed Central

Lee, Jeong-A; Kim, Mi-Kyung; Kim, Hyoung-Mi; Lee, Jong Kwon; Jeong, Jayoung; Kim, Young-Rok; Oh, Jae-Min; Choi, Soo-Jin

2015-01-01

Background Orally administered particles rapidly interact with biological fluids containing proteins, enzymes, electrolytes, and other biomolecules to eventually form particles covered by a corona, and this corona potentially affects particle uptake, fate, absorption, distribution, and elimination in vivo. This study explored relationships between the biological interactions of calcium carbonate particles and their biokinetics. Methods We examined the effects of food grade calcium carbonates of different particle size (nano [N-Cal] and bulk [B-Cal]: specific surface areas of 15.8 and 0.83 m2/g, respectively) on biological interactions in in vitro simulated physiological fluids, ex vivo biofluids, and in vivo in gastrointestinal fluid. Moreover, absorption and tissue distribution of calcium carbonates were evaluated following a single dose oral administration to rats. Results N-Cal interacted more with biomatrices than bulk materials in vitro and ex vivo, as evidenced by high fluorescence quenching ratios, but it did not interact more actively with biomatrices in vivo. Analysis of coronas revealed that immunoglobulin, apolipoprotein, thrombin, and fibrinogen, were the major corona proteins, regardless of particle size. A biokinetic study revealed that orally delivered N-Cal was more rapidly absorbed into the blood stream than B-Cal, but no significant differences were observed between the two in terms of absorption efficiencies or tissue distributions. Both calcium carbonates were primarily present as particulate forms in gastrointestinal fluids but enter the circulatory system in dissolved Ca2+, although both types showed partial phase transformation to dicalcium phosphate dihydrate. Relatively low dissolution (about 4%), no remarkable protein–particle interaction, and the major particulate fate of calcium carbonate in vivo gastrointestinal fluids can explain its low oral absorption (about 4%) regardless of particle size. Conclusion We conclude that calcium carbonate nanoparticles can act more actively with biological matrices in vitro and ex vivo, but that in vivo, their biological interactions and biokinetics are not affected by particle size. PMID:25848250

The fate of calcium carbonate nanoparticles administered by oral route: absorption and their interaction with biological matrices.

PubMed

Lee, Jeong-A; Kim, Mi-Kyung; Kim, Hyoung-Mi; Lee, Jong Kwon; Jeong, Jayoung; Kim, Young-Rok; Oh, Jae-Min; Choi, Soo-Jin

2015-01-01

Orally administered particles rapidly interact with biological fluids containing proteins, enzymes, electrolytes, and other biomolecules to eventually form particles covered by a corona, and this corona potentially affects particle uptake, fate, absorption, distribution, and elimination in vivo. This study explored relationships between the biological interactions of calcium carbonate particles and their biokinetics. We examined the effects of food grade calcium carbonates of different particle size (nano [N-Cal] and bulk [B-Cal]: specific surface areas of 15.8 and 0.83 m(2)/g, respectively) on biological interactions in in vitro simulated physiological fluids, ex vivo biofluids, and in vivo in gastrointestinal fluid. Moreover, absorption and tissue distribution of calcium carbonates were evaluated following a single dose oral administration to rats. N-Cal interacted more with biomatrices than bulk materials in vitro and ex vivo, as evidenced by high fluorescence quenching ratios, but it did not interact more actively with biomatrices in vivo. Analysis of coronas revealed that immunoglobulin, apolipoprotein, thrombin, and fibrinogen, were the major corona proteins, regardless of particle size. A biokinetic study revealed that orally delivered N-Cal was more rapidly absorbed into the blood stream than B-Cal, but no significant differences were observed between the two in terms of absorption efficiencies or tissue distributions. Both calcium carbonates were primarily present as particulate forms in gastrointestinal fluids but enter the circulatory system in dissolved Ca(2+), although both types showed partial phase transformation to dicalcium phosphate dihydrate. Relatively low dissolution (about 4%), no remarkable protein-particle interaction, and the major particulate fate of calcium carbonate in vivo gastrointestinal fluids can explain its low oral absorption (about 4%) regardless of particle size. We conclude that calcium carbonate nanoparticles can act more actively with biological matrices in vitro and ex vivo, but that in vivo, their biological interactions and biokinetics are not affected by particle size.

Methods of producing alkylated hydrocarbons from an in situ heat treatment process liquid

DOEpatents

Roes, Augustinus Wilhelmus Maria [Houston, TX; Mo, Weijian [Sugar Land, TX; Muylle, Michel Serge Marie [Houston, TX; Mandema, Remco Hugo [Houston, TX; Nair, Vijay [Katy, TX

2009-09-01

A method for producing alkylated hydrocarbons is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce at least a second gas stream including hydrocarbons having a carbon number of at least 3. The first gas stream and the second gas stream are introduced into an alkylation unit to produce alkylated hydrocarbons. At least a portion of the olefins in the first gas stream enhance alkylation.

Experimental and numerical investigation of Acoustic streaming (Eckart streaming)

NASA Astrophysics Data System (ADS)

Dridi, Walid; Botton, Valery; Henry, Daniel; Ben Hadid, Hamda

The application of sound waves in the bulk of a fluid can generate steady or quasi-steady flows reffered to as Acoustic streaming flows. We can distinguish two kind of acoustic streaming: The Rayleigh Streaming is generated when a standing acoustic waves interfere with solid walls to give birth to an acoustic boundary layer. Steady recirculations are then driven out of the boundary layer and can be used in micro-gravity, where the free convection is too weak or absent, to enhance the convective heat or mass transfer and cooling the electronic devises [1]. The second kind is the Eckart streaming, which is a flow generated far from the solid boundaries, it can be used to mix a chemical solutions [2], and to drive a viscous liquids in channels [3-4], in micro-gravity area. Our study focuses on the Eckart streaming configuration, which is investigated both numerical and experimental means. The experimental configuration is restricted to the case of a cylindrical non-heated cavity full of water or of a water+glycerol mixture. At the middle of one side of the cavity, a plane ultrasonic transducer generates a 2MHz wave; an absorber is set at the opposite side of the cavity to avoid any reflections. The velocity field is measured with a standard PIV system. [1] P. Vainshtein, M. Fichman and C. Gutfinger, "Acoustic enhancement of heat transfer between two parallel plates", International Journal of Heat and Mass Transfert, 1995, 38(10), 1893. [2] C. Suri, K. Tekenaka, H. Yanagida, Y. Kojima and K. Koyama, "Chaotic mixing generated by acoustic streaming", Ultrasonics, 2002, 40, 393 [3] O.V. Rudenko and A.A. Sukhorukov, "Nonstationnary Eckart streaming and pumping of liquid in ultrasonic field", Acoustical Physics, 1998, 44, 653. [4] Kenneth D. Frampton, Shawn E. Martin and Keith Minor, "The scaling of acoustic streaming for application in micro-fluidic devices", Applied Acoustics, 2003, 64,681

Electrowinning apparatus and process

DOEpatents

Buschmann, Wayne E [Boulder, CO

2012-06-19

Apparatus and processes are disclosed for electrowinning metal from a fluid stream. A representative apparatus comprises at least one spouted bed reactor wherein each said reactor includes an anolyte chamber comprising an anode and configured for containing an anolyte, a catholyte chamber comprising a current collector and configured for containing a particulate cathode bed and a flowing stream of an electrically conductive metal-containing fluid, and a membrane separating said anolyte chamber and said catholyte chamber, an inlet for an electrically conductive metal-containing fluid stream; and a particle bed churning device configured for spouting particle bed particles in the catholyte chamber independently of the flow of said metal-containing fluid stream. In operation, reduced heavy metals or their oxides are recovered from the cathode particles.

Methods of making transportation fuel

DOEpatents

Roes, Augustinus Wilhelmus Maria [Houston, TX; Mo, Weijian [Sugar Land, TX; Muylle, Michel Serge Marie [Houston, TX; Mandema, Remco Hugo [Houston, TX; Nair, Vijay [Katy, TX

2012-04-10

A method for producing alkylated hydrocarbons is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce at least a second gas stream including hydrocarbons having a carbon number of at least 3. The first gas stream and the second gas stream are introduced into an alkylation unit to produce alkylated hydrocarbons. At least a portion of the olefins in the first gas stream enhance alkylation. The alkylated hydrocarbons may be blended with one or more components to produce transportation fuel.

Treatment of gas from an in situ conversion process

DOEpatents

Diaz, Zaida [Katy, TX; Del Paggio, Alan Anthony [Spring, TX; Nair, Vijay [Katy, TX; Roes, Augustinus Wilhelmus Maria [Houston, TX

2011-12-06

A method of producing methane is described. The method includes providing formation fluid from a subsurface in situ conversion process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. At least the olefins in the first gas stream are contacted with a hydrogen source in the presence of one or more catalysts and steam to produce a second gas stream. The second gas stream is contacted with a hydrogen source in the presence of one or more additional catalysts to produce a third gas stream. The third gas stream includes methane.

Rare but active taxa contribute to community dynamics of benthic biofilms in glacier-fed streams.

PubMed

Wilhelm, Linda; Besemer, Katharina; Fasching, Christina; Urich, Tim; Singer, Gabriel A; Quince, Christopher; Battin, Tom J

2014-08-01

Glaciers harbour diverse microorganisms, which upon ice melt can be released downstream. In glacier-fed streams microorganisms can attach to stones or sediments to form benthic biofilms. We used 454-pyrosequencing to explore the bulk (16S rDNA) and putatively active (16S rRNA) microbial communities of stone and sediment biofilms across 26 glacier-fed streams. We found differences in community composition between bulk and active communities among streams and a stronger congruence between biofilm types. Relative abundances of rRNA and rDNA were positively correlated across different taxa and taxonomic levels, but at lower taxonomic levels, the higher abundance in either the active or the bulk communities became more apparent. Here, environmental variables played a minor role in structuring active communities. However, we found a large number of rare taxa with higher relative abundances in rRNA compared with rDNA. This suggests that rare taxa contribute disproportionately to microbial community dynamics in glacier-fed streams. Our findings propose that high community turnover, where taxa repeatedly enter and leave the 'seed bank', contributes to the maintenance of microbial biodiversity in harsh ecosystems with continuous environmental perturbations, such as glacier-fed streams. © 2014 The Authors. Environmental Microbiology published by Society for Applied Microbiology and John Wiley & Sons Ltd.

Optofluidic fabrication for 3D-shaped particles

NASA Astrophysics Data System (ADS)

Paulsen, Kevin S.; di Carlo, Dino; Chung, Aram J.

2015-04-01

Complex three-dimensional (3D)-shaped particles could play unique roles in biotechnology, structural mechanics and self-assembly. Current methods of fabricating 3D-shaped particles such as 3D printing, injection moulding or photolithography are limited because of low-resolution, low-throughput or complicated/expensive procedures. Here, we present a novel method called optofluidic fabrication for the generation of complex 3D-shaped polymer particles based on two coupled processes: inertial flow shaping and ultraviolet (UV) light polymerization. Pillars within fluidic platforms are used to deterministically deform photosensitive precursor fluid streams. The channels are then illuminated with patterned UV light to polymerize the photosensitive fluid, creating particles with multi-scale 3D geometries. The fundamental advantages of optofluidic fabrication include high-resolution, multi-scalability, dynamic tunability, simple operation and great potential for bulk fabrication with full automation. Through different combinations of pillar configurations, flow rates and UV light patterns, an infinite set of 3D-shaped particles is available, and a variety are demonstrated.

Generation of Alfvenic Waves and Turbulence in Magnetic Reconnection Jets

NASA Astrophysics Data System (ADS)

Hoshino, M.

2014-12-01

The magneto-hydro-dynamic (MHD) linear stability for the plasma sheet with a localized bulk plasma flow parallel to the neutral sheet is investigated. We find three different unstable modes propagating parallel to the anti-parallel magnetic field line, and we call them as "streaming　tearing'', "streaming sausage'', and "streaming kink'' mode. The streaming tearing and sausage modes have the tearing mode-like structure with symmetric density fluctuation to the neutral sheet, and the streaming kink mode has the asymmetric fluctuation.　The growth rate of the streaming tearing mode decreases with increasing the magnetic Reynolds number, while those of the streaming　sausage and kink modes do not strongly depend on the Reynolds number. The wavelengths of these unstable modes are of the order of the thickness of plasma sheet, which behavior is almost same as the standard　tearing mode with no bulk flow. Roughly speaking the growth rates of　three modes become faster than the standard tearing mode. The situation of the plasma sheet with the bulk flow can be realized in the reconnection exhaust with the Alfvenic reconnection jet, and the unstable modes may be regarded as one of the generation processes of Alfvenic　turbulence in the plasma sheet during magnetic reconnection.

Development of ultrasonic electrostatic microjets for distributed propulsion and microflight

NASA Astrophysics Data System (ADS)

Amirparviz, Babak

This dissertation details the first attempt to design and fabricate a distributed micro propulsion system based on acoustic streaming. A novel micro propulsion method is suggested by combining Helmholtz resonance, acoustic streaming and flow entrainment and thrust augmentation. In this method, oscillatory motion of an electrostatically actuated diaphragm creates a high frequency acoustic field inside the cavity of a Helmholtz resonator. The initial fluid motion velocity is amplified by the Helmholtz resonator structure and creates a jet flow at the exit nozzle. Acoustic streaming is the phenomenon responsible for primary jet stream creation. Primary jets produced by a few resonators can be combined in an ejector configuration to induce flow entrainment and thrust augmentation. Basic governing equations for the electrostatic actuator, deformation of the diaphragm and the fluid flow inside the resonator are derived. These equations are linearized and used to derive an equivalent electrical circuit model for the operation of the device. Numerical solution of the governing equations and simulation of the circuit model are used to predict the performance of the experimental systems. Thrust values as high as 30.3muN are expected per resonator. A micro machined electrostatically-driven high frequency Helmholtz resonator prototype is designed and fabricated. A new micro fabrication technique is developed for bulk micromachining and in particular fabrication of the resonator. Geometric stops for wet anisotropic etching of silicon are introduced for the fist time for structure formation. Arrays of high frequency (>60kHz) micro Helmholtz resonators are fabricated. In one sample more than 1000 resonators cover the surface of a four-inch silicon wafer and in effect convert it to a distributed propulsion system. A high yield (>85%) micro fabrication process is presented for realization of this propulsion system taking advantage of newly developed deep glass micromachining and lithography on thin (15mum) silicon methods. Extensive test and characterization are performed on the micro jets using current frequency component analysis, laser interferometry, acoustic measurements, hot-wire anemometers, video particle imaging and load cells. The occurrence of acoustic streaming at jet nozzles is verified and flow velocities exceeding 1m/s are measured at the 15mum x 330mum jet exit nozzle.

Reducing or stopping the uncontrolled flow of fluid such as oil from a well

DOEpatents

Hermes, Robert E

2014-02-18

The uncontrolled flow of fluid from an oil or gas well may be reduced or stopped by injecting a composition including 2-cyanoacrylate ester monomer into the fluid stream. Injection of the monomer results in a rapid, perhaps instantaneous, polymerization of the monomer within the flow stream of the fluid. This polymerization results in formation of a solid plug that reduces or stops the flow of additional fluid from the well.

Method of measuring the mass flow rate of a substance entering a cocurrent fluid stream

DOEpatents

Cochran, Jr., Henry D.

1978-04-11

This invention relates to an improved method of monitoring the mass flow rate of a substance entering a cocurrent fluid stream. The method very basically consists of heating equal sections of the fluid stream above and below the point of entry of the substance to be monitored, and measuring and comparing the resulting change in temperature of the sections. Advantage is taken of the difference in thermal characteristics of the fluid and the substance to be measured to correlate temperature differences in the sections above and below the substance feed point for providing an indication of the mass flow rate of the substance.

Shielded fluid stream injector for particle bed reactor

DOEpatents

Notestein, John E.

1993-01-01

A shielded fluid-stream injector assembly is provided for particle bed reactors. The assembly includes a perforated pipe injector disposed across the particle bed region of the reactor and an inverted V-shaped shield placed over the pipe, overlapping it to prevent descending particles from coming into direct contact with the pipe. The pipe and shield are fixedly secured at one end to the reactor wall and slidably secured at the other end to compensate for thermal expansion. An axially extending housing aligned with the pipe and outside the reactor and an in-line reamer are provided for removing deposits from the inside of the pipe. The assembly enables fluid streams to be injected and distributed uniformly into the particle bed with minimized clogging of injector ports. The same design may also be used for extraction of fluid streams from particle bed reactors.

Selective evaporation of focusing fluid in two-fluid hydrodynamic print head.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Keicher, David M.; Cook, Adam W.

The work performed in this project has demonstrated the feasibility to use hydrodynamic focusing of two fluid steams to create a novel micro printing technology for electronics and other high performance applications. Initial efforts focused solely on selective evaporation of the sheath fluid from print stream provided insight in developing a unique print head geometry allowing excess sheath fluid to be separated from the print flow stream for recycling/reuse. Fluid flow models suggest that more than 81 percent of the sheath fluid can be removed without affecting the print stream. Further development and optimization is required to demonstrate this capabilitymore » in operation. Print results using two-fluid hydrodynamic focusing yielded a 30 micrometers wide by 0.5 micrometers tall line that suggests that the cross-section of the printed feature from the print head was approximately 2 micrometers in diameter. Printing results also demonstrated that complete removal of the sheath fluid is not necessary for all material systems. The two-fluid printing technology could enable printing of insulated conductors and clad optical interconnects. Further development of this concept should be pursued.« less

Utilizing chemo-mechanically functionalized oscillating fins to ``catch and release'' nanoparticles in binary flow

NASA Astrophysics Data System (ADS)

Liu, Ya; Ma, Yongting; Bhattacharya, Amitabh; Kuksenok, Olga; He, Ximin; Aizenberg, Joanna; Balazs, Anna

2013-11-01

In biomimetics, designing an effective ``catch and release'' device for the selective removal of target species from the surrounding solution is critical for developing autonomous sensors and sorters. Using computational simulation, we model an array of oscillating fins that are tethered on the floor of a microchannel and immersed in a binary-fluid stream. During the oscillation, the fins with the specific chemical wetting reach the upper fluid when they are upright and are entirely within the lower stream when they are tilted. We introduce specific adhesive interactions between the fins and particulates in the solution and determine conditions where the oscillating fins can selectively bind (``catch'') target nanoparticles within the upper fluid stream and then release these particles into the lower stream. We isolate the effects of chemical wetting on the fins (e.g., wetting contact angle between fins and fluid) and mechanical parameters (e.g., frequency of fins' oscillations) that lead to the efficient extraction of target species from the upper stream and placement into the lower fluid. Our understanding provides fundamental insights into the system's complex dynamics and mechanism for detection, separation, and purification of multi-component mixtures.

Utilizing Chemo-mechanically Functionalized Oscillating Fins to ``Catch and Release'' Nanoparticles in Binary Flow

NASA Astrophysics Data System (ADS)

Liu, Ya; Kuksenok, Olga; Bhattacharya, Amitabh; Ma, Yongting; He, Ximin; Aizenberg4, Joanna; Balazs, Anna

2014-03-01

In biomimetics, designing an effective ``catch and release'' device for the selective removal of target species from the surrounding solution is critical for developing autonomous sensors and sorters. Using computer simulations, we model an array of oscillating fins that are tethered on the floor of a microchannel and immersed in a mixture of binary fluid stream and binary nanoparticles. During the oscillation, the fins with the specific chemical wetting reach the upper fluid when they are upright and are entirely immersed within the lower stream when they are tilted. We introduce specific interaction between the fins and particulates in the solution and determine conditions where the oscillating fins can selectively ?catch? target nanoparticles within the upper fluid stream and then release these particles into the lower stream. We isolate the effects of wetting contact angle between fins and fluid and the mode of fins' oscillations that lead to the efficient extraction of target species from the upper stream and their placement into the lower fluid. These studies provide fundamental insights into the system's complex dynamics and mechanism for detection, separation, and purification of multi-component mixtures.

Apparatus for removing a contaminant from a fluid stream

DOEpatents

Brewster, M.D.; Posa, R.P.

1998-12-22

A device for removing a contaminant from a fluid stream flowing within a conduit is disclosed. The device includes a container and a barrier. The container has a first wall generated about an axis and a second wall generated about the same axis. The first wall defines a first volume therewithin, while the first and second walls define an annular second volume therebetween. Both the first and second volumes are sealed at one end of the device, while at the other end of the device the second volume only is sealed. A filter material occupies the second volume. The first and second walls are permeable to the fluid stream and are capable of retaining the filter material in the second volume. The barrier is impermeable to the fluid stream and creates a seal between the second wall and the conduit wall. The barrier is positioned adjacent the other end of the device such that when the other end of the device is the upstream end, the fluid stream must sequentially pass into the first volume, through the first wall, into the second volume and through the filter material, and through the second wall. 4 figs.

Investigation of particle lateral migration in sample-sheath flow of viscoelastic fluid and Newtonian fluid.

PubMed

Yuan, Dan; Zhang, Jun; Yan, Sheng; Peng, Gangrou; Zhao, Qianbin; Alici, Gursel; Du, Hejun; Li, Weihua

2016-08-01

In this work, particle lateral migration in sample-sheath flow of viscoelastic fluid and Newtonian fluid was experimentally investigated. The 4.8-μm micro-particles were dispersed in a polyethylene oxide (PEO) viscoelastic solution, and then the solution was injected into a straight rectangular channel with a deionised (DI) water Newtonian sheath flow. Micro-particles suspended in PEO solution migrated laterally to a DI water stream, but migration in the opposite direction from a DI water stream to a PEO solution stream or from one DI water stream to another DI water stream could not be achieved. The lateral migration of particles depends on the viscoelastic properties of the sample fluids. Furthermore, the effects of channel length, flow rate, and PEO concentration were studied. By using viscoelastic sample flow and Newtonian sheath flow, a selective particle lateral migration can be achieved in a simple straight channel, without any external force fields. This particle lateral migration technique could be potentially used in solution exchange fields such as automated cell staining and washing in microfluidic platforms, and holds numerous biomedical applications. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Apparatus for removing a contaminant from a fluid stream

DOEpatents

Brewster, Michael D.; Posa, Richard P.

1998-01-01

A device for removing a contaminant from a fluid stream flowing within a conduit is disclosed. The device includes a container and a barrier. The container has a first wall generated about an axis and a second wall generated about the same axis. The first wall defines a first volume therewithin, while the first and second walls define an annular second volume therebetween. Both the first and second volumes are sealed at one end of the device, while at the other end of the device the second volume only is sealed. A filter material occupies the second volume. The first and second walls are permeable to the fluid stream and are capable of retaining the filter material in the second volume. The barrier is impermeable to the fluid stream and creates a seal between the second wall and the conduit wall. The barrier is positioned adjacent the other end of the device such that when the other end of the device is the upstream end, the fluid stream must sequentially pass into the first volume, through the first wall, into the second volume and through the filter material, and through the second wall.

A molecular Debye-Huckel theory of solvation in polar fluids: An extension of the Born model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xiao, Tiejun; Song, Xueyu

A dielectric response theory of solvation beyond the conventional Born model for polar fluids is presented. The dielectric response of a polar fluid is described by a Born response mode and a linear combination of Debye-Hückel-like response modes that capture the nonlocal response of polar fluids. The Born mode is characterized by a bulk dielectric constant, while a Debye-Hückel mode is characterized by its corresponding Debye screening length. Both the bulk dielectric constant and the Debye screening lengths are determined from the bulk dielectric function of the polar fluid. The linear combination coefficients of the response modes are evaluated inmore » a self-consistent way and can be used to evaluate the electrostatic contribution to the thermodynamic properties of a polar fluid. In conclusion, our theory is applied to a dipolar hard sphere fluid as well as interaction site models of polar fluids such as water, where the electrostatic contribution to their thermodynamic properties can be obtained accurately.« less

A molecular Debye-Huckel theory of solvation in polar fluids: An extension of the Born model

DOE PAGES

Xiao, Tiejun; Song, Xueyu

2017-12-06

A dielectric response theory of solvation beyond the conventional Born model for polar fluids is presented. The dielectric response of a polar fluid is described by a Born response mode and a linear combination of Debye-Hückel-like response modes that capture the nonlocal response of polar fluids. The Born mode is characterized by a bulk dielectric constant, while a Debye-Hückel mode is characterized by its corresponding Debye screening length. Both the bulk dielectric constant and the Debye screening lengths are determined from the bulk dielectric function of the polar fluid. The linear combination coefficients of the response modes are evaluated inmore » a self-consistent way and can be used to evaluate the electrostatic contribution to the thermodynamic properties of a polar fluid. In conclusion, our theory is applied to a dipolar hard sphere fluid as well as interaction site models of polar fluids such as water, where the electrostatic contribution to their thermodynamic properties can be obtained accurately.« less

A molecular Debye-Hückel theory of solvation in polar fluids: An extension of the Born model

NASA Astrophysics Data System (ADS)

Xiao, Tiejun; Song, Xueyu

2017-12-01

A dielectric response theory of solvation beyond the conventional Born model for polar fluids is presented. The dielectric response of a polar fluid is described by a Born response mode and a linear combination of Debye-Hückel-like response modes that capture the nonlocal response of polar fluids. The Born mode is characterized by a bulk dielectric constant, while a Debye-Hückel mode is characterized by its corresponding Debye screening length. Both the bulk dielectric constant and the Debye screening lengths are determined from the bulk dielectric function of the polar fluid. The linear combination coefficients of the response modes are evaluated in a self-consistent way and can be used to evaluate the electrostatic contribution to the thermodynamic properties of a polar fluid. Our theory is applied to a dipolar hard sphere fluid as well as interaction site models of polar fluids such as water, where the electrostatic contribution to their thermodynamic properties can be obtained accurately.

A molecular Debye-Hückel theory of solvation in polar fluids: An extension of the Born model.

PubMed

Xiao, Tiejun; Song, Xueyu

2017-12-07

A dielectric response theory of solvation beyond the conventional Born model for polar fluids is presented. The dielectric response of a polar fluid is described by a Born response mode and a linear combination of Debye-Hückel-like response modes that capture the nonlocal response of polar fluids. The Born mode is characterized by a bulk dielectric constant, while a Debye-Hückel mode is characterized by its corresponding Debye screening length. Both the bulk dielectric constant and the Debye screening lengths are determined from the bulk dielectric function of the polar fluid. The linear combination coefficients of the response modes are evaluated in a self-consistent way and can be used to evaluate the electrostatic contribution to the thermodynamic properties of a polar fluid. Our theory is applied to a dipolar hard sphere fluid as well as interaction site models of polar fluids such as water, where the electrostatic contribution to their thermodynamic properties can be obtained accurately.

Numerical study of a confined slot impinging jet with nanofluids

PubMed Central

2011-01-01

Background Heat transfer enhancement technology concerns with the aim of developing more efficient systems to satisfy the increasing demands of many applications in the fields of automotive, aerospace, electronic and process industry. A solution for obtaining efficient cooling systems is represented by the use of confined or unconfined impinging jets. Moreover, the possibility of increasing the thermal performances of the working fluids can be taken into account, and the introduction of nanoparticles in a base fluid can be considered. Results In this article, a numerical investigation on confined impinging slot jet working with a mixture of water and Al2O3 nanoparticles is described. The flow is turbulent and a constant temperature is applied on the impinging. A single-phase model approach has been adopted. Different geometric ratios, particle volume concentrations and Reynolds number have been considered to study the behavior of the system in terms of average and local Nusselt number, convective heat transfer coefficient and required pumping power profiles, temperature fields and stream function contours. Conclusions The dimensionless stream function contours show that the intensity and size of the vortex structures depend on the confining effects, given by H/W ratio, Reynolds number and particle concentrations. Furthermore, for increasing concentrations, nanofluids realize increasing fluid bulk temperature, as a result of the elevated thermal conductivity of mixtures. The local Nusselt number profiles show the highest values at the stagnation point, and the lowest at the end of the heated plate. The average Nusselt number increases for increasing particle concentrations and Reynolds numbers; moreover, the highest values are observed for H/W = 10, and a maximum increase of 18% is detected at a concentration equal to 6%. The required pumping power as well as Reynolds number increases and particle concentrations grow, which is almost 4.8 times greater than the values calculated in the case of base fluid. List of symbols PMID:21711743

Fluid aspects of electron streaming instability in electron-ion plasmas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jao, C.-S.; Hau, L.-N.; Department of Physics, National Central University, Jhongli, Taiwan

2014-02-15

Electrons streaming in a background electron and ion plasma may lead to the formation of electrostatic solitary wave (ESW) and hole structure which have been observed in various space plasma environments. Past studies on the formation of ESW are mostly based on the particle simulations due to the necessity of incorporating particle's trapping effects. In this study, the fluid aspects and thermodynamics of streaming instabilities in electron-ion plasmas including bi-streaming and bump-on-tail instabilities are addressed based on the comparison between fluid theory and the results from particle-in-cell simulations. The energy closure adopted in the fluid model is the polytropic lawmore » of d(pρ{sup −γ})/dt=0 with γ being a free parameter. Two unstable modes are identified for the bump-on-tail instability and the growth rates as well as the dispersion relation of the streaming instabilities derived from the linear theory are found to be in good agreement with the particle simulations for both bi-streaming and bump-on-tail instabilities. At the nonlinear saturation, 70% of the electrons are trapped inside the potential well for the drift velocity being 20 times of the thermal velocity and the pρ{sup −γ} value is significantly increased. Effects of ion to electron mass ratio on the linear fluid theory and nonlinear simulations are also examined.« less

Dynamic bulk and shear moduli due to grain-scale local fluid flow in fluid-saturated cracked poroelastic rocks: Theoretical model

NASA Astrophysics Data System (ADS)

Song, Yongjia; Hu, Hengshan; Rudnicki, John W.

2016-07-01

Grain-scale local fluid flow is an important loss mechanism for attenuating waves in cracked fluid-saturated poroelastic rocks. In this study, a dynamic elastic modulus model is developed to quantify local flow effect on wave attenuation and velocity dispersion in porous isotropic rocks. The Eshelby transform technique, inclusion-based effective medium model (the Mori-Tanaka scheme), fluid dynamics and mass conservation principle are combined to analyze pore-fluid pressure relaxation and its influences on overall elastic properties. The derivation gives fully analytic, frequency-dependent effective bulk and shear moduli of a fluid-saturated porous rock. It is shown that the derived bulk and shear moduli rigorously satisfy the Biot-Gassmann relationship of poroelasticity in the low-frequency limit, while they are consistent with isolated-pore effective medium theory in the high-frequency limit. In particular, a simplified model is proposed to quantify the squirt-flow dispersion for frequencies lower than stiff-pore relaxation frequency. The main advantage of the proposed model over previous models is its ability to predict the dispersion due to squirt flow between pores and cracks with distributed aspect ratio instead of flow in a simply conceptual double-porosity structure. Independent input parameters include pore aspect ratio distribution, fluid bulk modulus and viscosity, and bulk and shear moduli of the solid grain. Physical assumptions made in this model include (1) pores are inter-connected and (2) crack thickness is smaller than the viscous skin depth. This study is restricted to linear elastic, well-consolidated granular rocks.

Sorption Phase of Supercritical CO2 in Silica Aerogel: Experiments and Mesoscale Computer Simulations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rother, Gernot; Vlcek, Lukas; Gruszkiewicz, Miroslaw

2014-01-01

Adsorption of supercritical CO2 in nanoporous silica aerogel was investigated by a combination of experiments and molecular-level computer modeling. High-pressure gravimetric and vibrating tube densimetry techniques were used to measure the mean pore fluid density and excess sorption at 35 C and 50 C and pressures of 0-200 bar. Densification of the pore fluid was observed at bulk fluid densities below 0.7 g/cm3. Far above the bulk fluid density, near-zero sorption or weak depletion effects were measured, while broad excess sorption maxima form in the vicinity of the bulk critical density region. The CO2 sorption properties are very similar formore » two aerogels with different bulk densities of 0.1 g/cm3 and 0.2 g/cm3, respectively. The spatial distribution of the confined supercritical fluid was analyzed in terms of sorption- and bulk-phase densities by means of the Adsorbed Phase Model (APM), which used data from gravimetric sorption and small-angle neutron scattering experiments. To gain more detailed insight into supercritical fluid sorption, large-scale lattice gas GCMC simulations were utilized and tuned to resemble the experimental excess sorption data. The computed three-dimensional pore fluid density distributions show that the observed maximum of the excess sorption near the critical density originates from large density fluctuations pinned to the pore walls. At this maximum, the size of these fluctuations is comparable to the prevailing pore sizes.« less

Probe systems for measuring static pressure and turbulence intensity in fluid streams

NASA Technical Reports Server (NTRS)

Rossow, Vernon J. (Inventor)

1993-01-01

A method and an apparatus for measuring time-averaged static or ambient pressure and turbulence intensity in a turbulent stream are discussed. The procedure involves placing a plurality of probes in the stream. Each probe responds in a different manner to characteristics of the fluid stream, preferably as a result of having varying cross sections. The responses from the probes are used to eliminate unwanted components in the measured quantities for accurate determination of selected characteristics.

Self-alignment of plasmonic gold nanorods in reconfigurable anisotropic fluids for tunable bulk metamaterial applications.

PubMed

Liu, Qingkun; Cui, Yanxia; Gardner, Dennis; Li, Xin; He, Sailing; Smalyukh, Ivan I

2010-04-14

We demonstrate the bulk self-alignment of dispersed gold nanorods imposed by the intrinsic cylindrical micelle self-assembly in nematic and hexagonal liquid crystalline phases of anisotropic fluids. External magnetic field and shearing allow for alignment and realignment of the liquid crystal matrix with the ensuing long-range orientational order of well-dispersed plasmonic nanorods. This results in a switchable polarization-sensitive plasmon resonance exhibiting stark differences from that of the same nanorods in isotropic fluids. The device-scale bulk nanoparticle alignment may enable optical metamaterial mass production and control of properties arising from combining the switchable nanoscale structure of anisotropic fluids with the surface plasmon resonance properties of the plasmonic nanorods.

Method and apparatus for separation of heavy and tritiated water

DOEpatents

Lee, Myung W.

2001-01-01

The present invention is a bi-thermal membrane process for separating and recovering hydrogen isotopes from a fluid containing hydrogen isotopes, such as water and hydrogen gas. The process in accordance with the present invention provides counter-current cold and hot streams of the fluid separated with a thermally insulating and chemically transparent proton exchange membrane (PEM). The two streams exchange hydrogen isotopes through the membrane: the heavier isotopes migrate into the cold stream, while the lighter isotopes migrate into the hot stream. The heavy and light isotopes are continuously withdrawn from the cold and hot streams respectively.

System for adding sulfur to a fuel cell stack system for improved fuel cell stability

DOEpatents

Mukerjee, Subhasish [Pittsford, NY; Haltiner, Jr., Karl J; Weissman, Jeffrey G [West Henrietta, NY

2012-03-06

A system for adding sulfur to a fuel cell stack, having a reformer adapted to reform a hydrocarbon fuel stream containing sulfur contaminants, thereby providing a reformate stream having sulfur; a sulfur trap fluidly coupled downstream of the reformer for removing sulfur from the reformate stream, thereby providing a desulfurized reformate stream; and a metering device in fluid communication with the reformate stream upstream of the sulfur trap and with the desulfurized reformate stream downstream of the sulfur trap. The metering device is adapted to bypass a portion of the reformate stream to mix with the desulfurized reformate stream, thereby producing a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

Noise reducing screen devices for in-flow pressure sensors

NASA Technical Reports Server (NTRS)

Schmitz, Fredric (Inventor); Liu, Sandy (Inventor); Jaeger, Stephen (Inventor); Horne, W. Clifton (Inventor)

1997-01-01

An acoustic sensor assembly is provided for sensing acoustic signals in a moving fluid such as high speed fluid stream. The assembly includes one or more acoustic sensors and a porous, acoustically transparent screen supported between the moving fluid stream and the sensor and having a major surface disposed so as to be tangent to the moving fluid. A layer of reduced velocity fluid separating the sensor from the porous screen. This reduced velocity fluid can comprise substantially still air. A foam filler material attenuates acoustic signals arriving at the assembly from other than a predetermined range of incident angles.

Cascaded recompression closed brayton cycle system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pasch, James J.

The present disclosure is directed to a cascaded recompression closed Brayton cycle (CRCBC) system and method of operation thereof, where the CRCBC system includes a compressor for compressing the system fluid, a separator for generating fluid feed streams for each of the system's turbines, and separate segments of a heater that heat the fluid feed streams to different feed temperatures for the system's turbines. Fluid exiting each turbine is used to preheat the fluid to the turbine. In an embodiment, the amount of heat extracted is determined by operational costs.

Gas powered fluid gun with recoil mitigation

DOEpatents

Grubelich, Mark C; Yonas, Gerold

2013-11-12

A gas powered fluid gun for propelling a stream or slug of a fluid at high velocity toward a target. Recoil mitigation is provided that reduces or eliminates the associated recoil forces, with minimal or no backwash. By launching a quantity of water in the opposite direction, net momentum forces are reduced or eliminated. Examples of recoil mitigation devices include a cone for making a conical fluid sheet, a device forming multiple impinging streams of fluid, a cavitating venturi, one or more spinning vanes, or an annular tangential entry/exit.

Sampling device for withdrawing a representative sample from single and multi-phase flows

DOEpatents

Apley, Walter J.; Cliff, William C.; Creer, James M.

1984-01-01

A fluid stream sampling device has been developed for the purpose of obtaining a representative sample from a single or multi-phase fluid flow. This objective is carried out by means of a probe which may be inserted into the fluid stream. Individual samples are withdrawn from the fluid flow by sampling ports with particular spacings, and the sampling parts are coupled to various analytical systems for characterization of the physical, thermal, and chemical properties of the fluid flow as a whole and also individually.

Gas powered fluid gun with recoil mitigation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grubelich, Mark C.; Yonas, Gerold

A gas powered fluid gun for propelling a stream or slug of a fluid at high velocity toward a target. Recoil mitigation is provided that reduces or eliminates the associated recoil forces, with minimal or no backwash. By launching a quantity of water in the opposite direction, net momentum forces are reduced or eliminated. Examples of recoil mitigation devices include a cone for making a conical fluid sheet, a device forming multiple impinging streams of fluid, a cavitating venturi, one or more spinning vanes, or an annular tangential entry/exit.

Cascaded recompression closed Brayton cycle system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pasch, James Jay

The present disclosure is directed to a cascaded recompression closed Brayton cycle (CRCBC) system and method of operation thereof, where the CRCBC system includes a compressor for compressing the system fluid, a separator for generating fluid feed streams for each of the system's turbines, and separate segments of a heater that heat the fluid feed streams to different feed temperatures for the system's turbines. Fluid exiting each turbine is used to preheat the fluid to the turbine. In an embodiment, the amount of heat extracted is determined by operational costs.

Comparison of amine-selective properties of weak and strong cation-exchangers.

PubMed

Stenholm, Ake; Lindgren, Helena; Shaffie, Juliana

2006-09-22

The capacity of several weak and strong cation-exchangers to adsorb 2-diethylaminoethanol (DEAE) and (2,3-hydroxypropyl) trimethylammonium chloride (HPMAC) from sodium-containing process water streams, and the ease of subsequently eluting the amines and regenerating the exchangers, were investigated. (2,3-hydroxypropyl) trimethylammonium chloride was enriched 40-fold compared with the initial amine/sodium-ratio in the bulk fluid by Amberlite IRC-50. The highest selectivity for 2-diethylaminoethanol (26-fold) was provided by Imac HP336. Neither of the selected strong cation-exchangers showed any selectivity towards 2-diethylaminoethanol, but they enriched (2,3-hydroxypropyl) trimethylammonium chloride approximately three to four fold. These findings suggest that weak cation-exchangers (WCX) could be readily used for the selective removal of these or similar amines from sodium-containing process waters.

Relativistic thermal electron scale instabilities in sheared flow plasma

NASA Astrophysics Data System (ADS)

Miller, Evan D.; Rogers, Barrett N.

2016-04-01

> The linear dispersion relation obeyed by finite-temperature, non-magnetized, relativistic two-fluid plasmas is presented, in the special case of a discontinuous bulk velocity profile and parallel wave vectors. It is found that such flows become universally unstable at the collisionless electron skin-depth scale. Further analyses are performed in the limits of either free-streaming ions or ultra-hot plasmas. In these limits, the system is highly unstable in the parameter regimes associated with either the electron scale Kelvin-Helmholtz instability (ESKHI) or the relativistic electron scale sheared flow instability (RESI) recently highlighted by Gruzinov. Coupling between these modes provides further instability throughout the remaining parameter space, provided both shear flow and temperature are finite. An explicit parameter space bound on the highly unstable region is found.

Measurements of the streaming potential of clay soils from tropical and subtropical regions using self-made apparatus.

PubMed

Li, Zhong-Yi; Li, Jiu-Yu; Liu, Yuan; Xu, Ren-Kou

2014-09-01

The streaming potential has been wildly used in charged parallel plates, capillaries, and porous media. However, there have been few studies involving the ζ potential of clay soils based on streaming potential measurements. A laboratory apparatus was developed in this study to measure the streaming potential (ΔE) of bulk clay soils' coupling coefficient (C) and cell resistance (R) of saturated granular soil samples. Excellent linearity of ΔE versus liquid pressure (ΔP) ensured the validity of measurements. The obtained parameters of C and R can be used to calculate the ζ potential of bulk soils. The results indicated that the ζ potentials measured by streaming potential method were significantly correlated with the ζ potentials of soil colloids determined by electrophoresis (r (2) = 0.960**). Therefore, the streaming potential method can be used to study the ζ potentials of bulk clay soils. The absolute values of the ζ potentials of four soils followed the order: Ultisol from Jiangxi > Ultisol from Anhui > Oxisol from Guangdong > Oxisol from Hainan, and this was consistent with the cation exchange capacities of these soils. The type and concentration of electrolytes affected soil ζ potentials. The ζ potential became less negative with increased electrolyte concentration. The ζ potentials were more negative in monovalent than in divalent cationic electrolyte solutions because more divalent cations were distributed in the shear plane of the diffuse layer as counter-cations on the soil surfaces than monovalent cations at the same electrolyte concentration.

Boundary layer streaming in viscoelastic fluids

NASA Astrophysics Data System (ADS)

Bahrani, Seyed Amir; Costalanga, Maxime; Royon, Laurent; Brunet, Philippe; DSHE Team; Energy Team

2017-11-01

Oscillations of bodies immersed in fluids are known to generate secondary steady flows (streaming). These flows have strong similarities with acoustic streaming induced by sound and ultrasound waves. A typical situation, investigated here, is that of a cylinder oscillating perpendicular to its axis, generating two pairs of counter-rotating steady vortices due to the transfer of vorticity from an inner boundary layer. While most studies so far investigated the situation of newtonian fluids, here, we consider the situation of a viscoelastic fluid. By using Particle Image Velocimetry, we carry out an experimental study of the flow structure and magnitude over a range of amplitude (A up to 2.5 mm, nearly half the cylinder diameter) and frequency (f between 5 and 100 Hz). We observe unprecedented behaviors at higher frequency (f >50 Hz) : at high enough amplitude, the usual flow with 2 pairs of vortices is replaced by a more complex flow where 4 pairs of vortices are observed. At smaller frequency, we observe reversal large scale vortices that replace the usual inner and outer ones in Newtonian fluids. The main intention of this work is to understand the influence of the complex and nonlinear rheology on the mechanism of streaming flow. In this way, another source of purely rheological nonlinearity is expected, competing with hydrodynamic nonlinearity. We evidence the effect of elasticity in streaming.

Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream

DOEpatents

Kansa, Edward J.; Anderson, Brian L.; Wijesinghe, Ananda M.; Viani, Brian E.

1999-01-01

This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced.

Gassmann Theory Applies to Nanoporous Media

NASA Astrophysics Data System (ADS)

Gor, Gennady Y.; Gurevich, Boris

2018-01-01

Recent progress in extraction of unconventional hydrocarbon resources has ignited the interest in the studies of nanoporous media. Since many thermodynamic and mechanical properties of nanoscale solids and fluids differ from the analogous bulk materials, it is not obvious whether wave propagation in nanoporous media can be described using the same framework as in macroporous media. Here we test the validity of Gassmann equation using two published sets of ultrasonic measurements for a model nanoporous medium, Vycor glass, saturated with two different fluids, argon, and n-hexane. Predictions of the Gassmann theory depend on the bulk and shear moduli of the dry samples, which are known from ultrasonic measurements and the bulk moduli of the solid and fluid constituents. The solid bulk modulus can be estimated from adsorption-induced deformation or from elastic effective medium theory. The fluid modulus can be calculated according to the Tait-Murnaghan equation at the solvation pressure in the pore. Substitution of these parameters into the Gassmann equation provides predictions consistent with measured data. Our findings set up a theoretical framework for investigation of fluid-saturated nanoporous media using ultrasonic elastic wave propagation.

DE-1 observations of polar O(+) stream bulk parameters and comparison with a model of the centrifugally-accelerated polar wind

NASA Technical Reports Server (NTRS)

Ho, C. Wing; Horwitz, J. L.

1995-01-01

A survey of bulk parameters of analyzable O(+) outward streams in the mid-altitude (3-4.7 R(sub E) geocentric distance) polar cap magnetosphere is obtained from measurements by the Retarding Ion Mass Spectrometer (RIMS) aboard the Dynamics Explorer-1 (DE-1) spacecraft. There is wide scatter in the obtained densities, but they do display discernible trends: the average O(+) density in these streams decreases from about 60 ions/cc at 3.5 R(sub E) to about 1 ion/cc at 4.6 R(sub E). The streaming velocities are somewhat more defined, and their average increases from about 8 km/s at 3.5 R(sub E) to about 12 km/s at 4.6 R(sub E). The densities and bulk velocities are inversely correlated. We have further compared these observational trends with model profiles for the centrifugally-accelerated polar wind as recently described by Horwitz et al. (1994). The large outflow velocities observed can be understood in part as centrifugally-driven by convection with ionospheric electric field magnitudes of the order 50-70 mV/m, perhaps including plasma expansion effects.

Adjustable steam producing flexible orifice independent of fluid pressure

NASA Technical Reports Server (NTRS)

Morrison, Andrew D. (Inventor)

1992-01-01

A self-adjusting choke for a fluids nozzle includes a membrane constructed of a single piece of flexible or elastic material. This flexible material is shaped to fit into the outlet of a nozzle. The body of the membrane has at least two flow channels, from one face to the other, which directs two streams of water to cross at the opening of the nozzle or at some point beyond. The elasticity and thickness of the membrane is selected to match the range of expected pressures and fluid velocities. The choke may have more than two flow channels, as long as they are aligned adjacent to one another and directed towards each other at the exit face. In a three orifice embodiment, one is directed upward, one is directed downward, and the one in the middle is directed forward. In this embodiment all three fluid streams intersect at some point past the nozzle opening. Under increased pressure the membrane will deform causing the orifices to realign in a more forward direction, causing the streams to intersect at a smaller angle. This reduces the force with which the separate streams impact each other, still allowing the separate streams to unify into a single stable spiralling stream in spite of the increased pressure.

Unsteady Boundary-Layer Flow over Jerked Plate Moving in a Free Stream of Viscoelastic Fluid

PubMed Central

Mehmood, Ahmer; Ali, Asif; Saleem, Najma

2014-01-01

This study aims to investigate the unsteady boundary-layer flow of a viscoelastic non-Newtonian fluid over a flat surface. The plate is suddenly jerked to move with uniform velocity in a uniform stream of non-Newtonian fluid. Purely analytic solution to governing nonlinear equation is obtained. The solution is highly accurate and valid for all values of the dimensionless time 0 ≤ τ < ∞. Flow properties of the viscoelastic fluid are discussed through graphs. PMID:24892060

Capacitance probe for fluid flow and volume measurements

NASA Technical Reports Server (NTRS)

Arndt, G. Dickey (Inventor); Nguyen, Thanh X. (Inventor); Carl, James R. (Inventor)

1995-01-01

Method and apparatus for making measurements on fluids are disclosed, including the use of a capacitive probe for measuring the flow volume of a material within a flow stream. The capacitance probe has at least two elongate electrodes and, in a specific embodiment of the invention, has three parallel elongate electrodes with the center electrode being an extension of the center conductor of a co-axial cable. A conductance probe is also provided to provide more accurate flow volume data in response to conductivity of the material within the flow stream. A preferred embodiment of the present invention provides for a gas flow stream through a microgravity environment that allows for monitoring a flow volume of a fluid sample, such as a urine sample, that is entrained within the gas flow stream.

Capacitance Probe for Fluid Flow and Volume Measurements

NASA Technical Reports Server (NTRS)

Arndt, G. Dickey (Inventor); Nguyen, Thanh X. (Inventor); Carl, James R. (Inventor)

1997-01-01

Method and apparatus for making measurements on fluids are disclosed, including the use of a capacitive probe for measuring the flow volume of a material within a flow stream. The capacitance probe has at least two elongate electrodes and, in a specific embodiment of the invention, has three parallel elongate electrodes with the center electrode being an extension of the center conductor of a co-axial cable. A conductance probe is also provided to provide more accurate flow volume data in response to conductivity of the material within the flow stream. A preferred embodiment of the present invention provides for a gas flow stream through a micro-gravity environment that allows for monitoring a flow volume of a fluid sample, such as a urine sample, that is entrained within the gas flow stream.

Experimental and numerical investigations of resonant acoustic waves in near-critical carbon dioxide.

PubMed

Hasan, Nusair; Farouk, Bakhtier

2015-10-01

Flow and transport induced by resonant acoustic waves in a near-critical fluid filled cylindrical enclosure is investigated both experimentally and numerically. Supercritical carbon dioxide (near the critical or the pseudo-critical states) in a confined resonator is subjected to acoustic field created by an electro-mechanical acoustic transducer and the induced pressure waves are measured by a fast response pressure field microphone. The frequency of the acoustic transducer is chosen such that the lowest acoustic mode propagates along the enclosure. For numerical simulations, a real-fluid computational fluid dynamics model representing the thermo-physical and transport properties of the supercritical fluid is considered. The simulated acoustic field in the resonator is compared with measurements. The formation of acoustic streaming structures in the highly compressible medium is revealed by time-averaging the numerical solutions over a given period. Due to diverging thermo-physical properties of supercritical fluid near the critical point, large scale oscillations are generated even for small sound field intensity. The strength of the acoustic wave field is found to be in direct relation with the thermodynamic state of the fluid. The effects of near-critical property variations and the operating pressure on the formation process of the streaming structures are also investigated. Irregular streaming patterns with significantly higher streaming velocities are observed for near-pseudo-critical states at operating pressures close to the critical pressure. However, these structures quickly re-orient to the typical Rayleigh streaming patterns with the increase operating pressure.

Electrokinetic flow in a capillary with a charge-regulating surface polymer layer.

PubMed

Keh, Huan J; Ding, Jau M

2003-07-15

An analytical study of the steady electrokinetic flow in a long uniform capillary tube or slit is presented. The inside wall of the capillary is covered by a layer of adsorbed or covalently bound charge-regulating polymer in equilibrium with the ambient electrolyte solution. In this solvent-permeable and ion-penetrable surface polyelectrolyte layer, ionogenic functional groups and frictional segments are assumed to distribute at uniform densities. The electrical potential and space charge density distributions in the cross section of the capillary are obtained by solving the linearized Poisson-Boltzmann equation. The fluid velocity profile due to the application of an electric field and a pressure gradient through the capillary is obtained from the analytical solution of a modified Navier-Stokes/Brinkman equation. Explicit formulas for the electroosmotic velocity, the average fluid velocity and electric current density on the cross section, and the streaming potential in the capillary are also derived. The results demonstrate that the direction of the electroosmotic flow and the magnitudes of the fluid velocity and electric current density are dominated by the fixed charge density inside the surface polymer layer, which is determined by the regulation characteristics such as the dissociation equilibrium constants of the ionogenic functional groups in the surface layer and the concentration of the potential-determining ions in the bulk solution.

Microfluidic device and method for focusing, segmenting, and dispensing of a fluid stream

DOEpatents

Jacobson, Stephen C [Knoxville, TN; Ramsey, J Michael [Knoxville, TN

2008-09-09

A microfluidic device and method for forming and dispensing minute volume segments of a material are described. In accordance with the present invention, a microfluidic device and method are provided for spatially confining the material in a focusing element. The device is also adapted for segmenting the confined material into minute volume segments, and dispensing a volume segment to a waste or collection channel. The device further includes means for driving the respective streams of sample and focusing fluids through respective channels into a chamber, such that the focusing fluid streams spatially confine the sample material. The device may also include additional means for driving a minute volume segment of the spatially confined sample material into a collection channel in fluid communication with the waste reservoir.

Microfluidic device and method for focusing, segmenting, and dispensing of a fluid stream

DOEpatents

Jacobson, Stephen C.; Ramsey, J. Michael

2004-09-14

A microfluidic device for forming and/or dispensing minute volume segments of a material is described. In accordance with one aspect of the present invention, a microfluidic device and method is provided for spatially confining the material in a focusing element. The device is also capable of segmenting the confined material into minute volume segments, and dispensing a volume segment to a waste or collection channel. The device further includes means for driving the respective streams of sample and focusing fluids through respective channels into a chamber, such that the focusing fluid streams spatially confine the sample material. The device may also include additional means for driving a minute volume segment of the spatially confined sample material into a collection channel in fluid communication with the waste reservoir.

Apparatus for continuously referenced analysis of reactive components in solution

DOEpatents

Bostick, William D.; Denton, Mark S.; Dinsmore, Stanley R.

1981-01-01

A continuously referenced apparatus for measuring the concentration of a reactive chemical species in solution comprises in combination conduit means for introducing a sample solution, means for introducing one or more reactants into a sample solution, a reaction zone in fluid communication with said conduit means wherein a first chemical reaction occurs between said species and reactants, and a stream separator disposed within the conduit means for separating the sample solution into a sample stream and a reference stream. An enzymatic reactor is disposed in fluid communication with only the sample stream wherein a second reaction takes place between the said reactants, species, and reactor enzymes causing the consumption or production of an indicator species in just the sample stream. Measurement means such as a photometric system are disposed in communication with the sample and reference streams, and the outputs of the measurement means are compared to provide a blanked measurement of the concentration of indicator species. A peristaltic pump is provided to equalize flow through the apparatus by evacuation. The apparatus is particularly suitable for measurement of isoenzymes in body tissues or fluids.

Compton Scattering by Static and Moving Media. Part 1; The Transfer Equation and its Moments

NASA Technical Reports Server (NTRS)

Psaltis, Dimitrios; Lamb, Frederick K.

1997-01-01

Compton scattering of photons by nonrelativistic particles is thought to play an important role in forming the radiation spectrum of many astrophysical systems. Here we derive the time-dependent photon kinetic equation that describes spontaneous and induced Compton scattering, as well as absorption and emission by static and moving media, the corresponding radiative transfer equation, and their zeroth and first angular moments, both in the system frame and in the frame comoving with the medium. We show that it is necessary to use the correct relativistic differential scattering cross section in order to obtain a photon kinetic equation that is correct to first order in Epsilon/m(sub e), T(sub e)/m(sub e), and V, where Epsilon is the photon energy, T(sub e) and m(sub e) are the electron temperature and rest mass, and V is the electron bulk velocity in units of the speed of light. We also demonstrate that the terms in the radiative transfer equation that are second order in V should usually be retained, because if the radiation energy density is sufficiently large, compared to the radiation flux, the effects of bulk Comptonization described by the terms that are second order in V can be as important as the effects described by the terms that are first order in V, even when V is small. The system- and fluid-frame equations that we derive are correct to first order in Epsilon/m(sub e). Our system-frame equations, which are correct to second order in V, may be used when V is not too large. Our fluid-frame equations, which are exact in V, may be used when V approaches 1. Both sets of equations are valid for systems of arbitrary optical depth and can therefore be used in both the free-streaming and diffusion regimes. We demonstrate that Comptonization by the electron bulk motion occurs whether or not the radiation field is isotropic or the bulk flow converges and that it is more important than thermal Comptonization if V(sup 2) is greater than 3T(sub e)/m(sub e).

Position sensitive radioactivity detection for gas and liquid chromatography

DOEpatents

Cochran, Joseph L.; McCarthy, John F.; Palumbo, Anthony V.; Phelps, Tommy J.

2001-01-01

A method and apparatus are provided for the position sensitive detection of radioactivity in a fluid stream, particularly in the effluent fluid stream from a gas or liquid chromatographic instrument. The invention represents a significant advance in efficiency and cost reduction compared with current efforts.

Magnetic separator having a multilayer matrix, method and apparatus

DOEpatents

Kelland, David R.

1980-01-01

A magnetic separator having multiple staggered layers of porous magnetic material positioned to intercept a fluid stream carrying magnetic particles and so placed that a bypass of each layer is effected as the pores of the layer become filled with material extracted from the fluid stream.

Estimation of Dry Fracture Weakness, Porosity, and Fluid Modulus Using Observable Seismic Reflection Data in a Gas-Bearing Reservoir

NASA Astrophysics Data System (ADS)

Chen, Huaizhen; Zhang, Guangzhi

2017-05-01

Fracture detection and fluid identification are important tasks for a fractured reservoir characterization. Our goal is to demonstrate a direct approach to utilize azimuthal seismic data to estimate fluid bulk modulus, porosity, and dry fracture weaknesses, which decreases the uncertainty of fluid identification. Combining Gassmann's (Vier. der Natur. Gesellschaft Zürich 96:1-23, 1951) equations and linear-slip model, we first establish new simplified expressions of stiffness parameters for a gas-bearing saturated fractured rock with low porosity and small fracture density, and then we derive a novel PP-wave reflection coefficient in terms of dry background rock properties (P-wave and S-wave moduli, and density), fracture (dry fracture weaknesses), porosity, and fluid (fluid bulk modulus). A Bayesian Markov chain Monte Carlo nonlinear inversion method is proposed to estimate fluid bulk modulus, porosity, and fracture weaknesses directly from azimuthal seismic data. The inversion method yields reasonable estimates in the case of synthetic data containing a moderate noise and stable results on real data.

Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream

DOEpatents

Kansa, E.J.; Anderson, B.L.; Wijesinghe, A.M.; Viani, B.E.

1999-05-25

This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced. 3 figs.

Magnetic transit-time flowmeter

DOEpatents

Forster, George A.

1976-07-06

The flow rate of a conducting fluid in a stream is determined by disposing two permanent-magnet flowmeters in the stream, one downstream of the other. Flow of the conducting fluid causes the generation of both d-c and a-c electrical signals, the a-c comprising flow noise. Measurement of the time delay between similarities in the a-c signals by cross-correlation methods provides a measure of the rate of flow of the fluid.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hamilton, T.; Jones, H.; Wong, K.

The Marshall Islands Environmental Characterization and Dose Assessment Program has recently implemented waste minimization measures to reduce low level radioactive (LLW) and low level mixed (LLWMIXED) waste streams at the Lawrence Livermore National Laboratory (LLNL). Several thousand environmental samples are collected annually from former US nuclear test sites in the Marshall Islands, and returned to LLNL for processing and radiometric analysis. In the past, we analyzed coconut milk directly by gamma-spectrometry after adding formaldehyde (as preservative) and sealing the fluid in metal cans. This procedure was not only tedious and time consuming but generated storage and waste disposal problems. Wemore » have now reduced the number of coconut milk samples required for analysis from 1500 per year to approximately 250, and developed a new analytical procedure which essentially eliminates the associated mixed radioactive waste stream. Coconut milk samples are mixed with a few grams of ammonium-molydophosphate (AMP) which quantitatively scavenges the target radionuclide cesium 137 in an ion-exchange process. The AMP is then separated from the mixture and sealed in a plastic container. The bulk sample material can be disposed of as a non- radioactive non-hazardous waste, and the relatively small amount of AMP conveniently counted by gamma-spectrometry, packaged and stored for future use.« less

Numerical Modeling of Anaerobic Microzones Development in Bulk Oxic Porous Media: An Assessment of Different Microzone Formation Processes

NASA Astrophysics Data System (ADS)

Roy Chowdhury, S.; Zarnetske, J. P.; Briggs, M. A.; Day-Lewis, F. D.; Singha, K.

2017-12-01

Soil and groundwater research indicates that unique biogeochemical "microzones" commonly form within bulk soil masses. The formation of these microzones at the pore-scale has been attributed to a number of causes, including variability of in situ carbon or nutrient sources, intrinsic physical conditions that lead to dual-porosity and mass transfer conditions, or microbial bioclogging of the porous media. Each of these causes, while documented in different porous media systems, potentially can lead to the presence of anaerobic pores residing in a bulk oxic domain. The relative role of these causes operating independently or in conjunction with each other to form microzones is not known. Here, we use a single numerical modeling framework to assess the relative roles of each process in creating anaerobic microzones. Using a two-dimensional pore-network model, coupled with a microbial growth model based on Monod kinetics, simulations were performed to explore the development of these anoxic microzones and their fate under a range of hydrologic, nutrient, and microbial conditions. Initial results parameterized for a stream-groundwater exchange environment (i.e., a hyporheic zone) indicate that external forcing of fluid flux in the domain is a key soil characteristic to anaerobic microzone development as fluid flux governs the nutrient flux. The initial amount of biomass present in the system also plays a major role in the development of the microzones. In terms of dominant in situ causes, the intrinsic physical structure of the local pore space is found to play the key role in development of anaerobic sites by regulating fluxes to reaction sites. Acknowledging and understanding the drivers of these microzones will improve the ability of multiple disciplines to measure and model reactive mass transport in soils and assess if they play a significant role for particular biogeochemical processes and ecosystem functions, such as denitrification and greenhouse gas production.

Fuel cell membrane hydration and fluid metering

DOEpatents

Jones, Daniel O.; Walsh, Michael M.

1999-01-01

A hydration system includes fuel cell fluid flow plate(s) and injection port(s). Each plate has flow channel(s) with respective inlet(s) for receiving respective portion(s) of a given stream of reactant fluid for a fuel cell. Each injection port injects a portion of liquid water directly into its respective flow channel in order to mix its respective portion of liquid water with the corresponding portion of the stream. This serves to hydrate at least corresponding part(s) of a given membrane of the corresponding fuel cell(s). The hydration system may be augmented by a metering system including flow regulator(s). Each flow regulator meters an injecting at inlet(s) of each plate of respective portions of liquid into respective portion(s) of a given stream of fluid by corresponding injection port(s).

Composite media for ion processing

DOEpatents

Mann, Nick R [Blackfoot, ID; Wood, Donald J [Peshastin, WA; Todd, Terry A [Aberdeen, ID; Sebesta, Ferdinand [Prague, CZ

2009-12-08

Composite media, systems, and devices for substantially removing, or otherwise processing, one or more constituents of a fluid stream. The composite media comprise a plurality of beads, each having a matrix substantially comprising polyacrylonitrile (PAN) and supporting one or more active components which are effective in removing, by various mechanisms, one or more constituents from a fluid stream. Due to the porosity and large surface area of the beads, a high level of contact is achieved between composite media of the present invention and the fluid stream being processed. Further, the homogeneity of the beads facilitates use of the beads in high volume applications where it is desired to effectively process a large volume of flow per unit of time.

A novel passive micromixer based on unbalanced splits and collisions of fluid streams

NASA Astrophysics Data System (ADS)

Ansari, Mubashshir Ahmad; Kim, Kwang-Yong; Anwar, Khalid; Kim, Sun Min

2010-05-01

A new passive micromixer based on the concept of unbalanced splits and cross-collisions of fluid streams is designed and fabricated. Experimental and numerical studies have been carried out on the micromixer at Reynolds numbers ranging from 10 to 80. The three-dimensional Navier-Stokes equations have been used to analyze the mixing and flow behavior of the micromixer, which is composed of two sub-channels of unequal widths which repeatedly undergo splitting and recombination. The difference between the mass flow rates in the two sub-channels creates an unbalanced collision of the two fluid streams. Mixing is mainly due to the combined effect of unbalanced collisions of the fluid streams and Dean vortices. The micromixer shows interesting mixing behavior for different ratios of the widths of the two split sub-channels. The sub-channels wherein the major sub-channel is twice as wide as the minor sub-channel exhibit the highest mixing performance at Reynolds numbers larger than 40. The results show the lowest mixing performance for the case of uniform width, where balanced collisions occur.

Mass flow sensor utilizing a resistance bridge

NASA Technical Reports Server (NTRS)

Fralick, Gustave C. (Inventor); Hwang, Danny P. (Inventor); Wrbanek, John D. (Inventor)

2004-01-01

A mass flow sensor to be mounted within a duct and measures the mass flow of a fluid stream moving through the duct. The sensor is an elongated thin quartz substrate having a plurality of platinum strips extending in a parallel relationship on the strip, with certain of the strips being resistors connected to an excitation voltage. The resistors form the legs of a Wheatstone bridge. The resistors are spaced a sufficient distance inwardly from the leading and trailing edges of the substrate to lie within the velocity recovery region so that the measured flow is the same as the actual upstream flow. The resistor strips extend at least half-way through the fluid stream to include a substantial part of the velocity profile of the stream. Certain of the resistors detect a change in temperature as the fluid stream moves across the substrate to provide an output signal from the Wheatstone bridge which is representative of the fluid flow. A heater is located in the midst of the resistor array to heat the air as it passes over the array.

Evolution of water chemistry during Marcellus Shale gas development: A case study in West Virginia.

PubMed

Ziemkiewicz, Paul F; Thomas He, Y

2015-09-01

Hydraulic fracturing (HF) has been used with horizontal drilling to extract gas and natural gas liquids from source rock such as the Marcellus Shale in the Appalachian Basin. Horizontal drilling and HF generates large volumes of waste water known as flowback. While inorganic ion chemistry has been well characterized, and the general increase in concentration through the flowback is widely recognized, the literature contains little information relative to organic compounds and radionuclides. This study examined the chemical evolution of liquid process and waste streams (including makeup water, HF fluids, and flowback) in four Marcellus Shale gas well sites in north central West Virginia. Concentrations of organic and inorganic constituents and radioactive isotopes were measured to determine changes in waste water chemistry during shale gas development. We found that additives used in fracturing fluid may contribute to some of the constituents (e.g., Fe) found in flowback, but they appear to play a minor role. Time sequence samples collected during flowback indicated increasing concentrations of organic, inorganic and radioactive constituents. Nearly all constituents were found in much higher concentrations in flowback water than in injected HF fluids suggesting that the bulk of constituents originate in the Marcellus Shale formation rather than in the formulation of the injected HF fluids. Liquid wastes such as flowback and produced water, are largely recycled for subsequent fracturing operations. These practices limit environmental exposure to flowback. Copyright © 2015 Elsevier Ltd. All rights reserved.

Resonant Drag Instability of Grains Streaming in Fluids

NASA Astrophysics Data System (ADS)

Squire, J.; Hopkins, P. F.

2018-03-01

We show that grains streaming through a fluid are generically unstable if their velocity, projected along some direction, matches the phase velocity of a fluid wave (linear oscillation). This can occur whenever grains stream faster than any fluid wave. The wave itself can be quite general—sound waves, magnetosonic waves, epicyclic oscillations, and Brunt–Väisälä oscillations each generate instabilities, for example. We derive a simple expression for the growth rates of these “resonant drag instabilities” (RDI). This expression (i) illustrates why such instabilities are so virulent and generic and (ii) allows for simple analytic computation of RDI growth rates and properties for different fluids. As examples, we introduce several new instabilities, which could see application across a variety of physical systems from atmospheres to protoplanetary disks, the interstellar medium, and galactic outflows. The matrix-based resonance formalism we introduce can also be applied more generally in other (nonfluid) contexts, providing a simple means for calculating and understanding the stability properties of interacting systems.

Bulk viscosity of water in acoustic modal analysis and experiment

NASA Astrophysics Data System (ADS)

Kůrečka, Jan; Habán, Vladimír; Himr, Daniel

2018-06-01

Bulk viscosity is an important factor in the damping properties of fluid systems and exhibits frequency dependent behaviour. A comparison between modal analysis in ANSYS Acoustics, custom code and experimental data is presented in this paper. The measured system consists of closed ended water-filled steel pipes of different lengths. The influence of a pipe wall, flanges on both ends and longitudinal waves in the structural part were included in measurement evaluation. Therefore, the obtained values of sound speed and bulk viscosity are parameters of the fluid. A numerical simulation was carried out only using fluid volume in a range of bulk viscosity. Damping characteristics in this range were compared to measured values. The results show a significant influence of sound speed and subsequently, the use of sound speed value regressed from experimental data yields a better fit between the measurement and the computation.

Global and critical test of the perturbation density-functional theory based on extensive simulation of Lennard-Jones fluid near an interface and in confined systems.

PubMed

Zhou, Shiqi; Jamnik, Andrej

2005-09-22

The structure of a Lennard-Jones (LJ) fluid subjected to diverse external fields maintaining the equilibrium with the bulk LJ fluid is studied on the basis of the third-order+second-order perturbation density-functional approximation (DFA). The chosen density and potential parameters for the bulk fluid correspond to the conditions situated at "dangerous" regions of the phase diagram, i.e., near the critical temperature or close to the gas-liquid coexistence curve. The accuracy of DFA predictions is tested against the results of a grand canonical ensemble Monte Carlo simulation. It is found that the DFA theory presented in this work performs successfully for the nonuniform LJ fluid only on the condition of high accuracy of the required bulk second-order direct correlation function. The present report further indicates that the proposed perturbation DFA is efficient and suitable for both supercritical and subcritical temperatures.

Methods of cracking a crude product to produce additional crude products

DOEpatents

Mo, Weijian [Sugar Land, TX; Roes, Augustinus Wilhelmus Maria [Houston, TX; Nair, Vijay [Katy, TX

2009-09-08

A method for producing a crude product is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce one or more crude products. At least one of the crude products has a boiling range distribution from 38.degree. C. and 343.degree. C. as determined by ASTM Method D5307. The crude product having the boiling range distribution from 38.degree. C. and 343.degree. C. is catalytically cracked to produce one or more additional crude products. At least one of the additional crude products is a second gas stream. The second gas stream has a boiling point of at most 38.degree. C. at 0.101 MPa.

Gas venting system

DOEpatents

Khan, Amjad; Dreier, Ken Wayne; Moulthrop, Lawrence Clinton; White, Erik James

2010-06-29

A system to vent a moist gas stream is disclosed. The system includes an enclosure and an electrochemical cell disposed within the enclosure, the electrochemical cell productive of the moist gas stream. A first vent is in fluid communication with the electrochemical cell for venting the moist gas stream to an exterior of the enclosure, and a second vent is in fluid communication with an interior of the enclosure and in thermal communication with the first vent for discharging heated air to the exterior of the enclosure. At least a portion of the discharging heated air is for preventing freezing of the moist gas stream within the first vent.

Methods of producing transportation fuel

DOEpatents

Nair, Vijay [Katy, TX; Roes, Augustinus Wilhelmus Maria [Houston, TX; Cherrillo, Ralph Anthony [Houston, TX; Bauldreay, Joanna M [Chester, GB

2011-12-27

Systems, methods, and heaters for treating a subsurface formation are described herein. At least one method for producing transportation fuel is described herein. The method for producing transportation fuel may include providing formation fluid having a boiling range distribution between -5.degree. C. and 350.degree. C. from a subsurface in situ heat treatment process to a subsurface treatment facility. A liquid stream may be separated from the formation fluid. The separated liquid stream may be hydrotreated and then distilled to produce a distilled stream having a boiling range distribution between 150.degree. C. and 350.degree. C. The distilled liquid stream may be combined with one or more additives to produce transportation fuel.

Free-Stream Boundaries of Turbulent Flows

NASA Technical Reports Server (NTRS)

Corrsin, Stanley; Kistler, Alan L

1955-01-01

Report presents the results of an experimental and theoretical study made of the instantaneously sharp and irregular front which is always found to separate turbulent fluid from contiguous "nonturbulent" fluid at a free-stream boundary. This distinct demarcation is known to give an intermittent character to hot-wire signals in the boundary zone. The overall behavior of the front is described statistically in terms of its wrinkle-amplitude growth and its lateral propagation relative to the fluid as functions of downstream coordinate.

Investigation of soil properties for identifying recharge characteristics in the Lake Chad Basin

NASA Astrophysics Data System (ADS)

Banks, M. L.; Ndunguru, G. G.; Adisa, S. J.; Lee, J.; Adegoke, J. O.; Goni, I. B.; Grindley, J.; Mulugeta, V.

2009-12-01

Lake Chad was once labeled as one of the largest fresh water lakes in the world, providing water and livelihood to over 20 million people. The lake is shared by six different countries; Chad Nigeria, Niger, Cameroon, Central African Republic, and Sudan. Since the 1970 to date, a significant decrease in the size of the lake has been observed with the use of satellite imagery. This shrinking of the lake has been blamed on global warming, population increase and poor water management by the agriculture industry for farming purpose for both plants and animals. While these can be all valid reasons for the decrease of Lake Chad, we see the need to examine environmental and hydrological evidence around the Lake Chad basin. This study was carried out from upper stream to lower stream leading from Kano to the Damatru region which is one of several water bodies that supply Lake Chad. Over seventy six sites were sampled for soil texture, bulk density and other physical properties to investigate recharge capacity of the basin especially along the stream. Soils were collected using a soil core and properly stored at 4 degrees Celsius. Soils were weighed and put to dry at 105 degrees for twenty four hours. Dry weight was recorded and bulk density was calculated. The wet sieve method was used to determine the particle size analysis. Soils were weighed to 10 grams and hydrogen peroxide added to separate particles. Samples were washed with water and put to dry overnight. Soils were reweighed and sieved to separate as course sand, fine sand and silt and clay. The data revealed that in the upstream, coarse sand continuously decreased while silt and clay continuously increased down toward the lake. At mid stream silt and clay had significantly higher values when compared to coarse sand and fine sand. In the lower stream, bulk density clearly decreased compared to the upper and mid streams. Correlations will be carried out to investigate the particle size analysis and bulk density with recharge capacity of the lake Chad Basin.

Two fluid anisotropic dark energy models in a scale invariant theory

NASA Astrophysics Data System (ADS)

Tripathy, S. K.; Mishra, B.; Sahoo, P. K.

2017-09-01

Some anisotropic Bianchi V dark energy models are investigated in a scale invariant theory of gravity. We consider two non-interacting fluids such as dark energy and a bulk viscous fluid. Dark energy pressure is considered to be anisotropic in different spatial directions. A dynamically evolving pressure anisotropy is obtained from the models. The models favour phantom behaviour. It is observed that, in presence of dark energy, bulk viscosity has no appreciable effect on the cosmic dynamics.

A mean curvature model for capillary flows in asymmetric containers and conduits

NASA Astrophysics Data System (ADS)

Chen, Yongkang; Tavan, Noël; Weislogel, Mark M.

2012-08-01

Capillarity-driven flows resulting from critical geometric wetting criterion are observed to yield significant shifts of the bulk fluid from one side of the container to the other during "zero gravity" experiments. For wetting fluids, such bulk shift flows consist of advancing and receding menisci sometimes separated by secondary capillary flows such as rivulet-like flows along gaps. Here we study the mean curvature of an advancing meniscus in hopes of approximating a critical boundary condition for fluid dynamics solutions. It is found that the bulk shift flows behave as if the bulk menisci are either "connected" or "disconnected." For the connected case, an analytic method is developed to calculate the mean curvature of the advancing meniscus in an asymptotic sense. In contrast, for the disconnected case the method to calculate the mean curvature of the advancing and receding menisci uses a well-established procedure. Both disconnected and connected bulk shifts can occur as the first tier flow of more complex compound capillary flows. Preliminary comparisons between the analytic method and the results of drop tower experiments are encouraging.

Microgravity Transport Phenomena Experiment (MTPE) Overview

NASA Technical Reports Server (NTRS)

Mason, Larry W.

1999-01-01

The Microgravity Transport Phenomena Experiment (MTPE) is a fluids experiment supported by the Fundamentals in Biotechnology program in association with the Human Exploration and Development of Space (BEDS) initiative. The MTP Experiment will investigate fluid transport phenomena both in ground based experiments and in the microgravity environment. Many fluid transport processes are affected by gravity. Osmotic flux kinetics in planar membrane systems have been shown to be influenced by gravimetric orientation, either through convective mixing caused by unstably stratified fluid layers, or through a stable fluid boundary layer structure that forms in association with the membrane. Coupled transport phenomena also show gravity related effects. Coefficients associated with coupled transport processes are defined in terms of a steady state condition. Buoyancy (gravity) driven convection interferes with the attainment of steady state, and the measurement of coupled processes. The MTP Experiment measures the kinetics of molecular migration that occurs in fluids, in response to the application of various driving potentials. Three separate driving potentials may be applied to the MTP Experiment fluids, either singly or in combination. The driving potentials include chemical potential, thermal potential, and electrical potential. Two separate fluid arrangements are used to study membrane mediated and bulk fluid transport phenomena. Transport processes of interest in membrane mediated systems include diffusion, osmosis, and streaming potential. Bulk fluid processes of interest include coupled phenomena such as the Soret Effect, Dufour Effect, Donnan Effect, and thermal diffusion potential. MTP Experiments are performed in the Microgravity Transport Apparatus (MTA), an instrument that has been developed specifically for precision measurement of transport processes. Experiment fluids are contained within the MTA fluid cells, designed to create a one dimensional flow geometry of constant cross sectional area, and to facilitate fluid filling and draining operations in microgravity. The fluid cells may be used singly for bulk solutions, or in a Stokes diaphragm configuration to investigate membrane mediated phenomena. Thermal and electrical driving potentials are applied to the experiment fluids through boundary plates located at the ends of the fluid cells. In the ground based instrument, two constant temperature baths circulate through reservoirs adjacent to the boundary plates, and establish the thermal environment within the fluid cells. The boundary plates also serve as electrodes for measurement and application of electrical potentials. The Fluid Manipulation System associated with the MTA is a computer controlled system that enables storage and transfer of experiment fluids during on orbit operations. The system is used to automatically initiate experiments and manipulate fluids by orchestrating pump and valve operations through scripted sequences. Unique technologies are incorporated in the MTA for measurement of fluid properties. Volumetric Flow Sensors have been developed for precision measurement of total fluid volume contained within the fluid cells over time. This data is most useful for measuring the kinetics of osmosis, where fluid is transported from one fluid cell to another through a semipermeable membrane. The MicroSensor Array has been designed to perform in situ measurement of several important fluid parameters, providing simultaneous measurement of solution composition at multiple locations within the experiment fluids. Micromachined sensors and interface electronics have been developed to measure temperature, electrical conductivity, pH, cation activity, and anion activity. The Profile Refractometer uses a laser optical system to directly image the fluid Index of Refraction profile that exists along the MTA fluid cell axis. A video system acquires images of the RI profile over time, and records the transport kinetics that occur upon application of chemical, thermal, or electrical driving potentials. Image processing algorithms have been developed to analyze the refractometer images on a pixel by pixel basis, calibrating and scaling the measured Index of Refraction profile to correlated solution properties of interest such as density, concentration, and temperature. Additional software has been developed to compile the processed images into a three dimensional matrix that contains fluid composition data as a function of experiment time and position in the fluid cell. These data are combined with data from the other sensor systems, and analyzed in the context of transport coefficients associated with the various transport phenomena. Analysis protocols have been developed to measure the transient kinetics, and steady state distribution of fluid components that occur in response to the applied driving potentials. The results are expressed in terms of effective transport coefficients. Experiments have been performed using a variety of solutes, and results generated are that are in agreement with published transport coefficient values.

Streaming Potential Modeling to Understand the Identification of Hydraulically Active Fractures and Fracture-Matrix Fluid Interactions Using the Self-Potential Method

NASA Astrophysics Data System (ADS)

Jougnot, D.; Roubinet, D.; Linde, N.; Irving, J.

2016-12-01

Quantifying fluid flow in fractured media is a critical challenge in a wide variety of research fields and applications. To this end, geophysics offers a variety of tools that can provide important information on subsurface physical properties in a noninvasive manner. Most geophysical techniques infer fluid flow by data or model differencing in time or space (i.e., they are not directly sensitive to flow occurring at the time of the measurements). An exception is the self-potential (SP) method. When water flows in the subsurface, an excess of charge in the pore water that counterbalances electric charges at the mineral-pore water interface gives rise to a streaming current and an associated streaming potential. The latter can be measured with the SP technique, meaning that the method is directly sensitive to fluid flow. Whereas numerous field experiments suggest that the SP method may allow for the detection of hydraulically active fractures, suitable tools for numerically modeling streaming potentials in fractured media do not exist. Here, we present a highly efficient two-dimensional discrete-dual-porosity approach for solving the fluid-flow and associated self-potential problems in fractured domains. Our approach is specifically designed for complex fracture networks that cannot be investigated using standard numerical methods due to computational limitations. We then simulate SP signals associated with pumping conditions for a number of examples to show that (i) accounting for matrix fluid flow is essential for accurate SP modeling and (ii) the sensitivity of SP to hydraulically active fractures is intimately linked with fracture-matrix fluid interactions. This implies that fractures associated with strong SP amplitudes are likely to be hydraulically conductive, attracting fluid flow from the surrounding matrix.

Method and apparatus for continuously referenced analysis of reactive components in solution

DOEpatents

Bostick, W.D.; Denton, M.S.; Dinsmore, S.R.

1979-07-31

A continuously referenced apparatus for measuring the concentration of a reactive chemical species in solution comprises in combination conduit means for introducing a sample solution, means for introducing one or more reactants into a sample solution, and a stream separator disposed within the conduit means for separating the sample solution into a first sample stream and a second sample stream. A reactor is disposed in fluid communication with the first sample stream. A reaction takes place between the reactants introduced and the reactive chemical species of interest, causing the consumption or production of an indicator species in the first sample stream. Measurement means such as a photometric system are disposed in communication with the first and second sample streams, and the outputs of the measurement means are compared to provide a blanked measurement of the concentration of indicator species. The apparatus is particularly suitable for measurement of isoenzymes in body tissues or fluids.

Radiating gravitational collapse with shearing motion and bulk viscosity

NASA Astrophysics Data System (ADS)

Chan, R.

2001-03-01

A model is proposed of a collapsing radiating star consisting of a shearing fluid with bulk viscosity undergoing radial heat flow with outgoing radiation. The pressure of the star, at the beginning of the collapse, is isotropic but due to the presence of the bulk viscosity the pressure becomes more and more anisotropic. The behavior of the density, pressure, mass, luminosity, the effective adiabatic index and the Kretschmann scalar is analyzed. Our work is compared to the case of a collapsing shearing fluid of a previous model, for a star with 6 Msun.

The development of new, low-cost perfluoroalkylether fluids with excellent low and high-temperature properties

NASA Technical Reports Server (NTRS)

Bierschenk, Thomas R.; Kawa, Hajimu; Juhlke, Timothy J.; Lagow, Richard J.

1988-01-01

A series of perfluoroalkylether (PFAE) fluids were synthesized by direct fluorination. Viscosity-temperature properties, oxidation stabilities, oxidation-corrosion properties, and lubricity were determined. The fluids were tested in the presence of common elastomers to check for compatibility. The bulk modulus of each was measured to determine if any could be used as nonflammable aircraft hydraulic fluid. It was determined that as the carbon to oxygen ratio decreases, the viscometric properties improve, the fluids may become poor lubricants, the bulk modulus increases, the surface tension increases, and the fluid density increases. The presence of difluoromethylene oxide units in the polymer does not seriously lower the oxidation and oxidation-corrosion stabilities as long as the difluoromethylene oxide units are separated by other units.

Exploration of diffuse and discrete sources of acid mine drainage to a headwater mountain stream in Colorado, USA

USGS Publications Warehouse

Johnston, Allison; Runkel, Robert L.; Navarre-Sitchler, Alexis; Singha, Kamini

2017-01-01

We investigated the impact of acid mine drainage (AMD) contamination from the Minnesota Mine, an inactive gold and silver mine, on Lion Creek, a headwater mountain stream near Empire, Colorado. The objective was to map the sources of AMD contamination, including discrete sources visible at the surface and diffuse inputs that were not readily apparent. This was achieved using geochemical sampling, in-stream and in-seep fluid electrical conductivity (EC) logging, and electrical resistivity imaging (ERI) of the subsurface. The low pH of the AMD-impacted water correlated to high fluid EC values that served as a target for the ERI. From ERI, we identified two likely sources of diffuse contamination entering the stream: (1) the subsurface extent of two seepage faces visible on the surface, and (2) rainfall runoff washing salts deposited on the streambank and in a tailings pile on the east bank of Lion Creek. Additionally, rainfall leaching through the tailings pile is a potential diffuse source of contamination if the subsurface beneath the tailings pile is hydraulically connected with the stream. In-stream fluid EC was lowest when stream discharge was highest in early summer and then increased throughout the summer as stream discharge decreased, indicating that the concentration of dissolved solids in the stream is largely controlled by mixing of groundwater and snowmelt. Total dissolved solids (TDS) load is greatest in early summer and displays a large diel signal. Identification of diffuse sources and variability in TDS load through time should allow for more targeted remediation options.

Analyses and descriptions of geochemical samples from the Rich Mountain Roadless Area, Fannin and Gilmer counties, Georgia

USGS Publications Warehouse

Sears, C.M.; Foose, M.P.; Day, G.W.; Ericksen, M.S.

1983-01-01

Semi-quantitative spectrographic analyses for 31 elements on rock, soil, fine-grained stream sediment, bulk stream sediment, and panned stream sediment samples collected in the Rich Mountain Roadless Area, Fannin and Gilmer Counties, Georgia, are reported here. Atomic absorption analyses for gold and fluorometric analyses for uranium are also reported. Brief descriptions of all rock samples analyzed are included.

Temporal and spatial variation in porosity and compaction pressure for the viscoelastic slab

NASA Astrophysics Data System (ADS)

Morishige, M.; Van Keken, P. E.

2017-12-01

Fluid is considered to play key roles in subduction zones. It triggers various types of earthquakes by elevating pore-fluid pressure or forming hydrous minerals, and it also facilitates magma genesis by lowering the solidus temperatures of mantle and crustal rocks. Several previous numerical studies have worked on how fluid migrates and how porosity changes in time and space, but our knowledge of the fluid behavior remains limited. In this presentation, we demonstrate the detailed fluid behavior in the slab. The main features of this study are that (1) viscoelasticity is included, and that (2) fluid flow toward the inner part of the slab is also considered. We construct 2D and 3D finite element models for viscoelastic slab based on a theory of two-phase flow, which allows us to treat the movement of rock- and fluid- phases simultaneously. We solve the equations for porosity and compaction pressure which is defined as the pressure difference in between the two phases. Fluid source is fixed in time and space, and a uniform slab velocity is imposed for the whole model domain. There are several important parameters affecting the fluid behavior which includes bulk viscosity, bulk modulus, permeability, and fluid viscosity. Among these we fix bulk modulus and change the other parameters to investigate their effects on fluid migration. We find that when bulk viscosity is relatively high, elasticity is dominant and large amount of fluid is trapped in and around the fluid source. In addition, fluid migrates along the fluid source when relatively high ratio of permeability to fluid viscosity is assumed. Fluid generally moves with the slab when the ratio of permeability to fluid viscosity is low. One interesting feature is that in some cases porosity increases also in the deeper part of the fluid source due to the diffusion of compaction pressure. It suggests that the effects of resistance to volume change can be an alternative mechanism to effectively hydrate the inner part in the slab. In 3D, we find that fluid migrates in the maximum-dip direction of the slab. It leads to a fluid focusing where the slab bends away from the trench and it results in the increase in porosity and compaction pressure there. This finding may be useful to explain the observed along-arc variation in short-term slow slip events and the upper plane of double seismic zone.

Device for measuring the total concentration of oxygen in gases

DOEpatents

Isaacs, Hugh S.; Romano, Anthony J.

1977-01-01

This invention provides a CO equilibrium in a device for measuring the total concentration of oxygen impurities in a fluid stream. To this end, the CO equilibrium is produced in an electrochemical measuring cell by the interaction of a carbon element in the cell with the chemically combined and uncombined oxygen in the fluid stream at an elevated temperature.

Milestone Report #2: Direct Evaporator Leak and Flammability Analysis Modifications and Optimization of the Organic Rankine Cycle to Improve the Recovery of Waste Heat

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guillen, Donna Post

2013-09-01

The direct evaporator is a simplified heat exchange system for an Organic Rankine Cycle (ORC) that generates electricity from a gas turbine exhaust stream. Typically, the heat of the exhaust stream is transferred indirectly to the ORC by means of an intermediate thermal oil loop. In this project, the goal is to design a direct evaporator where the working fluid is evaporated in the exhaust gas heat exchanger. By eliminating one of the heat exchangers and the intermediate oil loop, the overall ORC system cost can be reduced by approximately 15%. However, placing a heat exchanger operating with a flammablemore » hydrocarbon working fluid directly in the hot exhaust gas stream presents potential safety risks. The purpose of the analyses presented in this report is to assess the flammability of the selected working fluid in the hot exhaust gas stream stemming from a potential leak in the evaporator. Ignition delay time for cyclopentane at temperatures and pressure corresponding to direct evaporator operation was obtained for several equivalence ratios. Results of a computational fluid dynamic analysis of a pinhole leak scenario are given.« less

Removal of common organic solvents from aqueous waste streams via supercritical C02 extraction: a potential green approach to sustainable waste management in the pharmaceutical industry.

PubMed

Leazer, Johnnie L; Gant, Sean; Houck, Anthony; Leonard, William; Welch, Christopher J

2009-03-15

Supercritical CO2 extraction of aqueous streams is a convenient and effective method to remove commonly used solvents of varying polarities from aqueous waste streams. The resulting aqueous layers can potentially be sewered; whereas the organic layer can be recovered for potential reuse. Supercritical fluid extraction (SFE) is a technology that is increasingly being used in commercial processes (1). Supercritical fluids are well suited for extraction of a variety of media, including solids, natural products, and liquid products. Many supercritical fluids have low critical temperatures, allowing for extractions to be done at modestly low temperatures, thus avoiding any potential thermal decomposition of the solutes under study (2). Furthermore, the CO2 solvent strength is easily tuned by adjusting the density of the supercritical fluid (The density is proportional to the pressure of the extraction process). Since many supercritical fluids are gases at ambient temperature, the extract can be concentrated by simply venting the reaction mixture to a cyclone collection vessel, using appropriate safety protocols.

Propulsion of a Two-Sphere Swimmer.

PubMed

Klotsa, Daphne; Baldwin, Kyle A; Hill, Richard J A; Bowley, R M; Swift, Michael R

2015-12-11

We describe experiments and simulations demonstrating the propulsion of a neutrally buoyant swimmer that consists of a pair of spheres attached by a spring, immersed in a vibrating fluid. The vibration of the fluid induces relative motion of the spheres which, for sufficiently large amplitudes, can lead to motion of the center of mass of the two spheres. We find that the swimming speed obtained from both experiment and simulation agree and collapse onto a single curve if plotted as a function of the streaming Reynolds number, suggesting that the propulsion is related to streaming flows. There appears to be a critical onset value of the streaming Reynolds number for swimming to occur. We observe a change in the streaming flows as the Reynolds number increases, from that generated by two independent oscillating spheres to a collective flow pattern around the swimmer as a whole. The mechanism for swimming is traced to a strengthening of a jet of fluid in the wake of the swimmer.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garn, Troy G; Law, Jack D; Greenhalgh, Mitchell R

A composite media including at least one crystalline aluminosilicate material in polyacrylonitrile. A method of forming a composite media is also disclosed. The method comprises dissolving polyacrylonitrile in an organic solvent to form a matrix solution. At least one crystalline aluminosilicate material is combined with the matrix solution to form a composite media solution. The organic solvent present in the composite media solution is diluted. The composite media solution is solidified. In addition, a method of processing a fluid stream is disclosed. The method comprises providing a beads of a composite media comprising at least one crystalline aluminosilicate material dispersedmore » in a polyacrylonitrile matrix. The beads of the composite media are contacted with a fluid stream comprising at least one constituent. The at least one constituent is substantially removed from the fluid stream.« less

Swimming using surface acoustic waves.

PubMed

Bourquin, Yannyk; Cooper, Jonathan M

2013-01-01

Microactuation of free standing objects in fluids is currently dominated by the rotary propeller, giving rise to a range of potential applications in the military, aeronautic and biomedical fields. Previously, surface acoustic waves (SAWs) have been shown to be of increasing interest in the field of microfluidics, where the refraction of a SAW into a drop of fluid creates a convective flow, a phenomenon generally known as SAW streaming. We now show how SAWs, generated at microelectronic devices, can be used as an efficient method of propulsion actuated by localised fluid streaming. The direction of the force arising from such streaming is optimal when the devices are maintained at the Rayleigh angle. The technique provides propulsion without any moving parts, and, due to the inherent design of the SAW transducer, enables simple control of the direction of travel.

Relationships between self-diffusivity, packing fraction, and excess entropy in simple bulk and confined fluids.

PubMed

Mittal, Jeetain; Errington, Jeffrey R; Truskett, Thomas M

2007-08-30

Static measures such as density and entropy, which are intimately connected to structure, have featured prominently in modern thinking about the dynamics of the liquid state. Here, we explore the connections between self-diffusivity, density, and excess entropy for two of the most widely used model "simple" liquids, the equilibrium Lennard-Jones and square-well fluids, in both bulk and confined environments. We find that the self-diffusivity data of the Lennard-Jones fluid can be approximately collapsed onto a single curve (i) versus effective packing fraction and (ii) in appropriately reduced form versus excess entropy, as suggested by two well-known scaling laws. Similar data collapse does not occur for the square-well fluid, a fact that can be understood on the basis of the nontrivial effects that temperature has on its static structure. Nonetheless, we show that the implications of confinement for the self-diffusivity of both of these model fluids, over a broad range of equilibrium conditions, can be predicted on the basis of knowledge of the bulk fluid behavior and either the effective packing fraction or the excess entropy of the confined fluid. Excess entropy is perhaps the most preferable route due to its superior predictive ability and because it is a standard, unambiguous thermodynamic quantity that can be readily predicted via classical density functional theories of inhomogeneous fluids.

Radionuclide detection devices and associated methods

DOEpatents

Mann, Nicholas R [Rigby, ID; Lister, Tedd E [Idaho Falls, ID; Tranter, Troy J [Idaho Falls, ID

2011-03-08

Radionuclide detection devices comprise a fluid cell comprising a flow channel for a fluid stream. A radionuclide collector is positioned within the flow channel and configured to concentrate one or more radionuclides from the fluid stream onto at least a portion of the radionuclide collector. A scintillator for generating scintillation pulses responsive to an occurrence of a decay event is positioned proximate at least a portion of the radionuclide collector and adjacent to a detection system for detecting the scintillation pulses. Methods of selectively detecting a radionuclide are also provided.

Method and turbine for extracting kinetic energy from a stream of two-phase fluid

NASA Technical Reports Server (NTRS)

Elliott, D. G. (Inventor)

1979-01-01

An axial flow separator turbine is described which includes a number of nozzles for delivering streams of a two-phase fluid along linear paths. A phase separator which responsively separates the vapor and liquid is characterized by concentrically related annuli supported for rotation within the paths. The separator has endless channels for confining the liquid under the influence of centrifugal forces. A vapor turbine fan extracts kinetic energy from the liquid. Angular momentum of both the liquid phase and the vapor phase of the fluid is converted to torque.

Kaluza-Klein Bulk Viscous Fluid Cosmological Models and the Validity of the Second Law of Thermodynamics in f(R, T) Gravity

NASA Astrophysics Data System (ADS)

Samanta, Gauranga Charan; Myrzakulov, Ratbay; Shah, Parth

2017-04-01

The authors considered the bulk viscous fluid in f(R, T) gravity within the framework of Kaluza-Klein space time. The bulk viscous coefficient (ξ) expressed as ξ = {ξ_0} + {ξ_1}{{\\dot a} \\over a} + {ξ_2}{{\\ddot a} \\over {\\dot a}}, where ξ0, ξ1, and ξ2 are positive constants. We take p=(γ-1)ρ, where 0≤γ≤2 as an equation of state for perfect fluid. The exact solutions to the corresponding field equations are given by assuming a particular model of the form of f(R, T)=R+2f(T), where f(T)=λT, λ is constant. We studied the cosmological model in two stages, in first stage: we studied the model with no viscosity, and in second stage: we studied the model involve with viscosity. The cosmological model involve with viscosity is studied by five possible scenarios for bulk viscous fluid coefficient (ξ). The total bulk viscous coefficient seems to be negative, when the bulk viscous coefficient is proportional to {ξ _2}{{\\ddot a} \\over {\\dot a}}, hence, the second law of thermodynamics is not valid; however, it is valid with the generalised second law of thermodynamics. The total bulk viscous coefficient seems to be positive, when the bulk viscous coefficient is proportional to ξ = {ξ _1}{{\\dot a} \\over a} + {ξ _2}{{\\ddot a} \\over {\\dot a}} and ξ = {ξ _0} + {ξ _1}{{\\dot a} \\over a} + {ξ _2}{{\\ddot a} \\over {\\dot a}}, so the second law of thermodynamics and the generalised second law of thermodynamics is satisfied throughout the evolution. We calculate statefinder parameters of the model and observed that it is different from the ∧CDM model. Finally, some physical and geometrical properties of the models are discussed.

Effective Elastic and Neutron Capture Cross Section Calculations Corresponding to Simulated Fluid Properties from CO2 Push-Pull Simulations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chugunov, Nikita; Altundas, Bilgin

The submission contains a .xls files consisting of 10 excel sheets, which contain combined list of pressure, saturation, salinity, temperature profiles from the simulation of CO2 push-pull using Brady reservoir model and the corresponding effective compressional and shear velocity, bulk density, and fluid and time-lapse neutron capture cross section profiles of rock at times 0 day (baseline) through 14 days. First 9 sheets (each named after the corresponding CO2 push-pull simulation time) contains simulated pressure, saturation, temperature, salinity profiles and the corresponding effective elastic and neutron capture cross section profiles of rock matrix at the time of CO2 injection. Eachmore » sheet contains two sets of effective compressional velocity profiles of the rock, one based on Gassmann and the other based on Patchy saturation model. Effective neutron capture cross section calculations are done using a proprietary neutron cross-section simulator (SNUPAR) whereas for the thermodynamic properties of CO2 and bulk density of rock matrix filled with fluid, a standalone fluid substitution tool by Schlumberger is used. Last sheet in the file contains the bulk modulus of solid rock, which is inverted from the rock properties (porosity, sound speed etc) based on Gassmann model. Bulk modulus of solid rock in turn is used in the fluid substitution.« less

Statistical mechanics of homogeneous partly pinned fluid systems.

PubMed

Krakoviack, Vincent

2010-12-01

The homogeneous partly pinned fluid systems are simple models of a fluid confined in a disordered porous matrix obtained by arresting randomly chosen particles in a one-component bulk fluid or one of the two components of a binary mixture. In this paper, their configurational properties are investigated. It is shown that a peculiar complementarity exists between the mobile and immobile phases, which originates from the fact that the solid is prepared in presence of and in equilibrium with the adsorbed fluid. Simple identities follow, which connect different types of configurational averages, either relative to the fluid-matrix system or to the bulk fluid from which it is prepared. Crucial simplifications result for the computation of important structural quantities, both in computer simulations and in theoretical approaches. Finally, possible applications of the model in the field of dynamics in confinement or in strongly asymmetric mixtures are suggested.

A density functional theory for association of fluid molecules with a functionalized surface: fluid-wall single and double bonding.

PubMed

Haghmoradi, Amin; Wang, Le; Chapman, Walter G

2017-02-01

In this manuscript we extend Wertheim's two-density formalism beyond its first order to model a system of fluid molecules with a single association site close to a planar hard wall with association sites on its surface in a density functional theory framework. The association sites of the fluid molecules are small enough that they can form only one bond, while the wall association sites are large enough to bond with more than one fluid molecule. The effects of temperature and of bulk fluid and wall site densities on the fluid density profile, extent of association, and competition between single and double bonding of fluid segments at the wall sites versus distance from the wall are presented. The theory predictions are compared with new Monte Carlo simulation results and they are in good agreement. The theory captures the surface coverage over wide ranges of temperature and bulk density by introducing the effect of steric hindrance in fluid association at a wall site.

Temporal trends of bulk precipitation and stream water chemistry (1977-1997) in a small forested area, Krusne hory, northern Bohemia, Czech Republic

USGS Publications Warehouse

Peters, N.E.; Cerny, J.; Havel, M.; Krejci, R.

1999-01-01

The Krusne hory (Erzgebirge or Ore Mountains) has been heavily affected by high atmospheric pollutant deposition caused by fossil fuel combustion in an adjacent Tertiary coal basin. Long-term routine sampling of bulk precipitation (1977-1996) and stream water (1977-1998) in a forested area on the south-eastern slope of the mountains were used to evaluate trends and patterns in solute concentration and flux with respect to controlling processes. From 1977 to 1996, the annual volume-weighted Ca2+ and SO42- concentrations decreased in bulk precipitation. However, after 1989, when a pronounced and continuous decrease occurred in coal production, annual volume-weighted concentrations decreased for most solutes, except H+. The concentration decreases were marked, with 1996 levels at or below 50% of those in 1989. The lack of a trend in H+ is attributed to similar decreases in both acid anions and neutralizing base cations. Stream water concentrations of most solutes, i.e. H+, Ca2+, Mg2+, SO42- and NO3-, were highest at the onset of sampling in 1977, decreased markedly from 1977 to 1983 and decreased more gradually from 1983 to 1998. The spruce forest die-back and removal reduced dry deposition of these solutes by reducing the filtering action, which was provided by the forest canopy. A notable decrease in stream water Ca2+ concentrations occurred after 1995 and may be due to the depletion of Ca2+, which was provided by catchment liming in 1986, 1988 and 1989. Solute flux trends in bulk atmospheric deposition and stream water generally were not significant and the lack of trend is attributed to the large interannual variability in precipitation quantity and runoff, respectively. All solutes except Na+ varied seasonally. The average seasonal concentrations varied between the solutes, but for most solutes were highest in winter and spring and lowest in summer, correlating with the seasonal trend and runoff. For Ca2+, Mg2+ and SO42-, the concentration minimum occurs in September and the maximum occurs in February or March, correlating with the seasonal baseflow. These solutes are primarily controlled by the contribution of soil water and groundwater to stream flow. During snowmelt, the meltwater generally causes concentrations to decrease as soil water and groundwater are diluted. For NO3, average minimum concentrations occur in August at the end of the growing season concurrent with the lowest stream flow, and the maximum occurs in February and March with high stream flow during snowmelt. Seasonal stream water NO3- concentration variations are large compared with the long-term decrease.The Krusne hory (Erzgebirge or Ore Mountains) has been heavily affected by high atmospheric pollutant deposition caused by fossil fuel combustion in an adjacent Tertiary coal basin. Long-term routine sampling of bulk precipitation (1977-1996) and stream water (1977-1998) in a forested area on the south-eastern slope of the mountains were used to evaluate trends and patterns in solute concentration and flux with respect to controlling processes. From 1977 to 1996, the annual volume-weighted Ca2+ and SO42- concentrations decreased in bulk precipitation. However, after 1989, when a pronounced and continuous decrease occurred in coal production, annual volume-weighted concentrations decreased for most solutes, except H+. The concentration decreases were marked, with 1996 levels at or below 50% of those in 1989. The lack of a trend in H+ is attributed to similar decreases in both acid anions and neutralizing base cations. Stream water concentrations of most solutes, i.e. H+, Ca2+, Mg2+, SO42- and NO3-, were highest at the onset of sampling in 1977, decreased markedly from 1977 to 1983 and decreased more gradually from 1983 to 1998. The spruce forest die-back and removal reduced dry deposition of these solutes by reducing the filtering action, which was provided by the forest canopy. A notable decrease in stream water Ca2+ concentrations occurred after 1995 an

Fuel cell membrane hydration and fluid metering

DOEpatents

Jones, Daniel O.; Walsh, Michael M.

2003-01-01

A hydration system includes fuel cell fluid flow plate(s) and injection port(s). Each plate has flow channel(s) with respective inlet(s) for receiving respective portion(s) of a given stream of reactant fluid for a fuel cell. Each injection port injects a portion of liquid water directly into its respective flow channel. This serves to hydrate at least corresponding part(s) of a given membrane of the corresponding fuel cell(s). The hydration system may be augmented by a metering system including flow regulator(s). Each flow regulator meters an injecting at inlet(s) of each plate of respective portions of liquid into respective portion(s) of a given stream of fluid by corresponding injection port(s).

Cosmological QCD phase transition in steady non-equilibrium dissipative Hořava–Lifshitz early universe

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khodadi, M., E-mail: M.Khodadi@sbu.ac.ir; Sepangi, H.R., E-mail: hr-sepangi@sbu.ac.ir

We study the phase transition from quark–gluon plasma to hadrons in the early universe in the context of non-equilibrium thermodynamics. According to the standard model of cosmology, a phase transition associated with chiral symmetry breaking after the electro-weak transition has occurred when the universe was about 1–10 μs old. We focus attention on such a phase transition in the presence of a viscous relativistic cosmological background fluid in the framework of non-detailed balance Hořava–Lifshitz cosmology within an effective model of QCD. We consider a flat Friedmann–Robertson–Walker universe filled with a non-causal and a causal bulk viscous cosmological fluid respectively and investigatemore » the effects of the running coupling constants of Hořava–Lifshitz gravity, λ, on the evolution of the physical quantities relevant to a description of the early universe, namely, the temperature T, scale factor a, deceleration parameter q and dimensionless ratio of the bulk viscosity coefficient to entropy density (ξ)/s . We assume that the bulk viscosity cosmological background fluid obeys the evolution equation of the steady truncated (Eckart) and full version of the Israel–Stewart fluid, respectively. -- Highlights: •In this paper we have studied quark–hadron phase transition in the early universe in the context of the Hořava–Lifshitz model. •We use a flat FRW universe with the bulk viscosity cosmological background fluid obeying the evolution equation of the steady truncated (Eckart) and full version of the Israel–Stewart fluid, respectively.« less

Ion processing element with composite media

DOEpatents

Mann, Nick R.; Tranter, Troy J.; Todd, Terry A.; Sebesta, Ferdinand

2003-02-04

An ion processing element employing composite media disposed in a porous substrate, for facilitating removal of selected chemical species from a fluid stream. The ion processing element includes a porous fibrous glass substrate impregnated by composite media having one or more active components supported by a matrix material of polyacrylonitrile. The active components are effective in removing, by various mechanisms, one or more constituents from a fluid stream passing through the ion processing element. Due to the porosity and large surface area of both the composite medium and the substrate in which it is disposed, a high degree of contact is achieved between the active component and the fluid stream being processed. Further, the porosity of the matrix material and the substrate facilitates use of the ion processing element in high volume applications where it is desired to effectively process a high volume flows.

Ion processing element with composite media

DOEpatents

Mann, Nick R [Blackfoot, ID; Tranter, Troy J [Idaho Falls, ID; Todd, Terry A [Aberdeen, ID; Sebesta, Ferdinand [Prague, CZ

2009-03-24

An ion processing element employing composite media disposed in a porous substrate, for facilitating removal of selected chemical species from a fluid stream. The ion processing element includes a porous fibrous glass substrate impregnated by composite media having one or more active components supported by a matrix material of polyacrylonitrile. The active components are effective in removing, by various mechanisms, one or more constituents from a fluid stream passing through the ion processing element. Due to the porosity and large surface area of both the composite medium and the substrate in which it is disposed, a high degree of contact is achieved between the active component and the fluid stream being processed. Further, the porosity of the matrix material and the substrate facilitates use of the ion processing element in high volume applications where it is desired to effectively process a high volume flows.

Swimming Using Surface Acoustic Waves

PubMed Central

Bourquin, Yannyk; Cooper, Jonathan M.

2013-01-01

Microactuation of free standing objects in fluids is currently dominated by the rotary propeller, giving rise to a range of potential applications in the military, aeronautic and biomedical fields. Previously, surface acoustic waves (SAWs) have been shown to be of increasing interest in the field of microfluidics, where the refraction of a SAW into a drop of fluid creates a convective flow, a phenomenon generally known as SAW streaming. We now show how SAWs, generated at microelectronic devices, can be used as an efficient method of propulsion actuated by localised fluid streaming. The direction of the force arising from such streaming is optimal when the devices are maintained at the Rayleigh angle. The technique provides propulsion without any moving parts, and, due to the inherent design of the SAW transducer, enables simple control of the direction of travel. PMID:23431358

Scaling laws and bulk-boundary decoupling in heat flow.

PubMed

del Pozo, Jesús J; Garrido, Pedro L; Hurtado, Pablo I

2015-03-01

When driven out of equilibrium by a temperature gradient, fluids respond by developing a nontrivial, inhomogeneous structure according to the governing macroscopic laws. Here we show that such structure obeys strikingly simple scaling laws arbitrarily far from equilibrium, provided that both macroscopic local equilibrium and Fourier's law hold. Extensive simulations of hard disk fluids confirm the scaling laws even under strong temperature gradients, implying that Fourier's law remains valid in this highly nonlinear regime, with putative corrections absorbed into a nonlinear conductivity functional. In addition, our results show that the scaling laws are robust in the presence of strong finite-size effects, hinting at a subtle bulk-boundary decoupling mechanism which enforces the macroscopic laws on the bulk of the finite-sized fluid. This allows one to measure the marginal anomaly of the heat conductivity predicted for hard disks.

Local equilibrium solutions in simple anisotropic cosmological models, as described by relativistic fluid dynamics

NASA Astrophysics Data System (ADS)

Shogin, Dmitry; Amund Amundsen, Per

2016-10-01

We test the physical relevance of the full and the truncated versions of the Israel-Stewart (IS) theory of irreversible thermodynamics in a cosmological setting. Using a dynamical systems method, we determine the asymptotic future of plane symmetric Bianchi type I spacetimes with a viscous mathematical fluid, keeping track of the magnitude of the relative dissipative fluxes, which determines the applicability of the IS theory. We consider the situations where the dissipative mechanisms of shear and bulk viscosity are involved separately and simultaneously. It is demonstrated that the only case in the given model when the fluid asymptotically approaches local thermal equilibrium, and the underlying assumptions of the IS theory are therefore not violated, is that of a dissipative fluid with vanishing bulk viscosity. The truncated IS equations for shear viscosity are found to produce solutions which manifest pathological dynamical features and, in addition, to be strongly sensitive to the choice of initial conditions. Since these features are observed already in the case of an oversimplified mathematical fluid model, we have no reason to assume that the truncation of the IS transport equations will produce relevant results for physically more realistic fluids. The possible role of bulk and shear viscosity in cosmological evolution is also discussed.

Apparatus for irradiating a continuously flowing stream of fluid. [For neutron activation analysis

DOEpatents

Speir, L.G.; Adams, E.L.

1982-05-13

An apparatus for irradiating a continuously flowing stream of fluid is disclosed. The apparatus consists of a housing having a spherical cavity and a spherical moderator containing a radiation source positioned within the spherical cavity. The spherical moderator is of lesser diameter than the spherical cavity so as to define a spherical annular volume around the moderator. The housing includes fluid intake and output conduits which open onto the spherical cavity at diametrically opposite positions. Fluid flows through the cavity around the spherical moderator and is uniformly irradiated due to the 4..pi.. radiation geometry. The irradiation source, for example a /sup 252/Cf neutron source, is removable from the spherical moderator through a radial bore which extends outwardly to an opening on the outside of the housing. The radiation source may be routinely removed without interrupting the flow of fluid or breaching the containment of the fluid.

Apparatus for irradiating a continuously flowing stream of fluid

DOEpatents

Speir, Leslie G.; Adams, Edwin L.

1984-01-01

An apparatus for irradiating a continuously flowing stream of fluid is diosed. The apparatus consists of a housing having a spherical cavity and a spherical moderator containing a radiation source positioned within the spherical cavity. The spherical moderator is of lesser diameter than the spherical cavity so as to define a spherical annular volume around the moderator. The housing includes fluid intake and output conduits which open onto the spherical cavity at diametrically opposite positions. Fluid flows through the cavity around the spherical moderator and is uniformly irradiated due to the 4.pi. radiation geometry. The irradiation source, for example a .sup.252 CF neutron source, is removable from the spherical moderator through a radial bore which extends outwardly to an opening on the outside of the housing. The radiation source may be routinely removed without interrupting the flow of fluid or breaching the containment of the fluid.

Ultrasonic-generated fluid velocity with Sovereign WhiteStar micropulse and continuous phacoemulsification.

PubMed

Steinert, Roger F; Schafer, Mark E

2006-02-01

To evaluate and compare ultrasonic turbulence created by conventional and micropulse ultrasound technology. Sonora Medical Systems, Longmont, Colorado, USA. A high-resolution digital ultrasound probe imaged the zone around a phacoemulsification tip. Doppler analysis allowed determination of flow. The fluid velocity was measured at 4 levels of ultrasound power at a constant flow, comparing the ultrasonic conditions of continuous energy to WhiteStar micropulses. In addition to the normal baseline irrigation and aspiration, fluid movement was detected directly below the phaco tip, produced by a nonlinear effect known as acoustic streaming. Acoustic streaming increased with increased phacoemulsification power for both conditions. At each of the 4 levels of power, fluid velocity away from the tip was less with micropulse technology than with continuous phacoemulsification. The demonstrated decrease in acoustic streaming flow away from the phaco tip with Sovereign WhiteStar micropulse technology compared to conventional ultrasound provides an objective explanation for clinical observations of increased stability of nuclear fragments at the tip and less turbulence in the anterior chamber during phacoemulsification. This methodology can be used to examine and compare fluid flow and turbulence under a variety of clinically relevant conditions.

Coaxial screen filter

DOEpatents

Schneider, William R.

1989-01-01

Methods and apparatus for removing a pollutant such as dust (33) from a fluid stream (34). A nested array of fibers (35) is provided in a substantially annular container (36) having openings in its inner (32) and outer (31) cylindrical sides of such size as to retain the fibers (35) within the container while permitting fluid (34) to pass through easily, and the pollutant-containing fluid stream (34) is passed through at least a substantial portion of the container (36) from a region (37) outside the outer side (31) to a region (38) inside the inner side (32). Thus a substantial fraction of the pollutant (33) is separated from the fluid stream (34) in a portion of the nested array (35) generally nearer to the outer side (31) of the container (36) than to the inner side (31). From time to time the container (36) is rotated about its axis to remove a substantial fraction of the separated pollutant (33) from the nested array (35), by tumbling action and by the force of gravity, through the openings in the outer side (31) of the container (36). To assist in this removal, purging fluid (41) may be directed back through the container (36) from the inner side (32) during the tumbling.

Direct Measurements of Pore Fluid Density by Vibrating Tube Densimetry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gruszkiewicz, Miroslaw S.; Rother, Gernot; Wesolowski, David J.

2012-02-27

The densities of pore-confined fluids were measured for the first time by means of a vibrating tube method. Isotherms of total adsorption capacity were measured directly making the method complementary to the conventional gravimetric or volumetric/piezometric adsorption techniques, which yield the excess adsorption (the Gibbsian surface excess). A custom-made high-pressure, high-temperature vibrating tube densimeter (VTD) was used to measure the densities of subcritical and supercritical propane (between 35 °C and 97 °C) and supercritical carbon dioxide (between 32 C and 50°C) saturating hydrophobic silica aerogel (0.2 g/cm 3, 90% porosity) synthesized inside Hastelloy U-tubes. Additionally, excess adsorption isotherms for supercriticalmore » CO 2 and the same porous solid were measured gravimetrically using a precise magnetically-coupled microbalance. Pore fluid densities and total adsorption isotherms increased monotonically with increasing density of the bulk fluid, in contrast to excess adsorption isotherms, which reached a maximum at a subcritical density of the bulk fluid, and then decreased towards zero or negative values at supercritical densities. Compression of the confined fluid significantly beyond the density of the bulk liquid at the same temperature was observed at subcritical temperatures. The features of the isotherms of confined fluid density are interpreted to elucidate the observed behavior of excess adsorption. The maxima of excess adsorption were found to occur below the critical density of the bulk fluid at the conditions corresponding to the beginning of the plateau of total adsorption, marking the end of the transition of pore fluid to a denser, liquid-like pore phase. The results for propane and carbon dioxide showed similarity in the sense of the principle of corresponding states. No measurable effect of pore confinement on the liquid-vapor critical point was found. Quantitative agreement was obtained between excess adsorption isotherms determined from VTD total adsorption results and those measured gravimetrically at the same temperature, confirming the validity of the vibrating tube measurements. Vibrating tube densimetry was demonstrated as a novel experimental approach capable of providing the average density of pore-confined fluids.« less

Influence of mixing conditions on the rheological properties and structure of capillary suspensions

PubMed Central

Bossler, Frank; Weyrauch, Lydia; Schmidt, Robert; Koos, Erin

2017-01-01

The rheological properties of a suspension can be dramatically altered by adding a small amount of a secondary fluid that is immiscible with the bulk liquid. These capillary suspensions exist either in the pendular state where the secondary fluid preferentially wets the particles or the capillary state where the bulk fluid is preferentially wetting. The yield stress, as well as storage and loss moduli, depends on the size and distribution of secondary phase droplets created during sample preparation. Enhanced droplet breakup leads to stronger sample structures. In capillary state systems, this can be achieved by increasing the mixing speed and time of turbulent mixing using a dissolver stirrer. In the pendular state, increased mixing speed also leads to better droplet breakup, but spherical agglomeration is favored at longer times decreasing the yield stress. Additional mixing with a ball mill is shown to be beneficial to sample strength. The influence of viscosity variance between the bulk and second fluid on the droplet breakup is excluded by performing experiments with viscosity-matched fluids. These experiments show that the capillary state competes with the formation of Pickering emulsion droplets and is often more difficult to achieve than the pendular state. PMID:28194044

Effects of CO2 injection and Kerogen Maturation on Low-Field Nuclear Magnetic Resonance Response

NASA Astrophysics Data System (ADS)

Prasad, M.; Livo, K.

2017-12-01

Low-field Nuclear Magnetic Resonance (NMR) is commonly used in petrophysical analysis of petroleum reservoir rocks. NMR experiments record the relaxation and polarization of in-situ hydrogen protons present in gaseous phases such as free-gas intervals and solution gas fluids, bulk fluid phases such as oil and aquifer intervals, and immovable fractions of kerogen and bitumen. Analysis of NMR relaxation spectra is performed to record how fluid composition, maturity, and viscosity change NMR experimental results. We present T1-T2 maps as thermal maturity of a water-saturated, sub-mature Woodford shale is increased at temperatures from 125 to 400 degrees Celsius. Experiments with applied fluid pressure in paraffinic mineral oil and DI water with varying fluid pH have been performed to mimic reservoir conditions in analysis of the relaxation of bulk fluid phases. We have recorded NMR spectra, T1-T2 maps, and fluid diffusion coefficients using a low-field (2 MHz) MagritekTM NMR. CO2 was injected at a pressure of 900 psi in an in house developed NMR pressure vessel made of torlon plastic. Observable 2D NMR shifts in immature kerogen formations as thermal maturity is increased show generation of lighter oils with increased maturity. CO2 injection leads to a decrease in bulk fluid relaxation time that is attributed to viscosity modification with gas presence. pH variation with increased CO2 presence were shown to not effect NMR spectra. From this, fluid properties have been shown to greatly affect NMR readings and must be taken into account for more accurate NMR reservoir characterization.

Near-Surface Transport Pathways in the North Atlantic Ocean: Looking for Throughput from the Subtropical to the Subpolar Gyre

NASA Astrophysics Data System (ADS)

Rypina, I. I.; Pratt, L. J.; Lozier, M.

2011-12-01

Motivated by discrepancies between Eulerian transport estimates and the behavior of Lagrangian surface drifters, near-surface transport pathways and processes in the North Atlantic are studied using a combination of data, altimetric surface heights, statistical analysis of trajectories, and dynamical systems techniques. Particular attention is paid to the issue of the subtropical-to-subpolar intergyre fluid exchange. The velocity field used in this study is composed of a steady drifter-derived background flow, upon which a time-dependent altimeter-based perturbation is superimposed. This analysis suggests that most of the fluid entering the subpolar gyre from the subtropical gyre within two years comes from a narrow region lying inshore of the Gulf Stream core, whereas fluid on the offshore side of the Gulf Stream is largely prevented from doing so by the Gulf Stream core, which acts as a strong transport barrier, in agreement with past studies. The transport barrier near the Gulf Stream core is robust and persistent from 1992 until 2008. The qualitative behavior is found to be largely independent of the Ekman drift.

Variation in chemistry of stream water and bulk deposition across the Hubbard Brook Valley, New Hampshire, USA

Treesearch

Gene E. Likens; Donald C. Buso; James W. Hornbeck

2002-01-01

Chemistry and volume of precipitation and stream water have been measured in south-facing watersheds of the Hubbard Brook Experimental Forest (HBEF), continuously for 37 years. These long-term data have provided important insights into the bio-geochemistry of these watershed ecosystems and the region (e.g. LIKENS & BORMANN 1995).

Active micromixer using surface acoustic wave streaming

DOEpatents

Branch,; Darren W. , Meyer; Grant D. , Craighead; Harold, G [Ithaca, NY

2011-05-17

An active micromixer uses a surface acoustic wave, preferably a Rayleigh wave, propagating on a piezoelectric substrate to induce acoustic streaming in a fluid in a microfluidic channel. The surface acoustic wave can be generated by applying an RF excitation signal to at least one interdigital transducer on the piezoelectric substrate. The active micromixer can rapidly mix quiescent fluids or laminar streams in low Reynolds number flows. The active micromixer has no moving parts (other than the SAW transducer) and is, therefore, more reliable, less damaging to sensitive fluids, and less susceptible to fouling and channel clogging than other types of active and passive micromixers. The active micromixer is adaptable to a wide range of geometries, can be easily fabricated, and can be integrated in a microfluidic system, reducing dead volume. Finally, the active micromixer has on-demand on/off mixing capability and can be operated at low power.

Removing sulphur oxides from a fluid stream

DOEpatents

Katz, Torsten; Riemann, Christian; Bartling, Karsten; Rigby, Sean Taylor; Coleman, Luke James Ivor; Lail, Marty Alan

2014-04-08

A process for removing sulphur oxides from a fluid stream, such as flue gas, comprising: providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the liquid being incompletely miscible with water; treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex; causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid whereby at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid; separating the aqueous liquid from the non-aqueous absorption liquid. The process mitigates absorbent degradation problems caused by sulphur dioxide and oxygen in flue gas.

Indications of Bulk-Fluid Motion in Direct-Drive Implosions

NASA Astrophysics Data System (ADS)

Mannion, O. M.; Anderson, K. S.; Forrest, C. J.; Glebov, V. Yu.; Goncharov, V. N.; Knauer, J. P.; Radha, P. B.; Regan, S. P.; Sangster, T. C.; Stoeckl, C.

2017-10-01

The neutron spectrum produced by a burning plasma encodes essential information about the fusion products and serves as an important diagnostic for inertial confinement fusion experiments. At the Omega Laser Facility, neutron time-of-flight measurements are used to interpret the first and second moment of the neutron spectrum. These moments have been shown to be directly related to properties of the plasma, such as bulk fluid motion and apparent ion temperature. New measurement devices allow for unprecedented accuracy in the measurement of these moments and will provide a better understanding of the performance of direct-drive implosions. We present measurements of the first moment of the DT and D2 peaks in DT implosions and show that variations in the first moment indicate bulk fluid motion of the plasma. This material is based upon work supported by the Department of Energy National Nuclear Security Administration under Award Number DE-NA0001944.

Direct observation of cerebrospinal fluid bulk flow in the brain

NASA Astrophysics Data System (ADS)

Mestre, Humberto; Tithof, Jeffrey; Thomas, John; Kelley, Douglas; Nedergaard, Maiken

2017-11-01

Cerebrospinal fluid (CSF) serves a vital role in normal brain function. Its adequate flow and exchange with interstitial fluid through perivascular spaces (PVS) has been shown to be important in the clearance of toxic metabolites like amyloid- β, and its disturbance can cause severe neurological diseases. It has long been suspected that bulk flow may transport CSF, but limitations in imaging techniques have prevented direct observation of such flows in the PVS. In this talk, we describe a novel approach using high speed two photon laser scanning microscopy which has allowed for the first ever direct observation of CSF flow in the PVS of a mouse brain. By performing particle tracking velocimetry, we quantify the CSF bulk flow speeds and PVS geometry. This technique enables future studies of CSF flow disturbances on a new scale and will pave the way for evaluating the role of these fluxes in neurodegenerative disease. R01NS100366 (to M.N.).

GUIDES TO POLLUTION PREVENTION: THE AUTO REPAIR INDUSTRY

EPA Science Inventory

Automotive maintenance and repair shops generate a variety of waste streams during activities such as replacing fluids (e.g., motor oil, radiator coolant, transmission fluid, brake fluid), replacing non-repairable parts (e.g., brake shoes/pads, shocks, batteries, belts, mufflers,...

Harnessing Active Fins to Segregate Nanoparticles from Binary Mixtures

NASA Astrophysics Data System (ADS)

Liu, Ya; Kuksenok, Olga; Bhattacharya, Amitabh; Ma, Yongting; He, Ximin; Aizenberg, Joanna; Balazs, Anna

2014-03-01

One of the challenges in creating high-performance polymeric nanocomposites for optoelectronic applications, such as bilayer solar cells, is establishing effective and facile routes for controlling the properties of interface and segregation of binary particles with hole conductor particles and electron conductor particles. We model nanocomposites that encompass binary particles and binary blends in a microchannel. An array of oscillating microfins is immersed in the fluid and tethered to the floor of the microchannel; the fluid containing mixture of nanoparticles is driven along the channel by an imposed pressure gradient. During the oscillations, the fins with the specific chemical wetting reach the upper fluid when they are upright and are entirely within the lower stream when they are tilted. We introduce specific interaction between the fins and particulates in the solution. Fins can selectively ``catch'' target nanoparticles within the upper fluid stream and then release them into the lower stream. We focus on different modes of fins motion to optimize selective segregation of particles within binary mixture. Our approach provides an effective means of tailoring the properties and ultimate performance of the composites.

Fluid-rock Interactions recorded in Serpentinites subducted to 60-80 km Depth

NASA Astrophysics Data System (ADS)

Peters, D.; John, T.; Scambelluri, M.; Pettke, D. T.

2016-12-01

The HP metamorphic serpentinised peridotites of Erro-Tobbio (ET, Italy) offer a unique possibility to study fluid-rock interactions in subducted ultrabasic rocks that reached 550-650°C at 2-2.5 GPa. They contain metamorphic olivine + Ti-clinohumite in both the serpentinite matrix and veins cutting the rock foliation, interpreted to represent partial serpentinite dehydration fluid pathways [1,2] being variably retrogressed as e.g., indicated by chrysotile/lizardite mesh textures in vein olivine in strongly altered samples. This study aims to constraining the origin of fluid(s) and the scale(s) of fluid-rock interaction based on major to trace element systematics employing detailed bulk rock (nanoparticulate pressed powder pellet LA-ICP-MS [3] and ion chromatography / liquid ICP-MS analysis), and in situ mineral analysis (work in progress). Bulk data show moderate fluid-mobile element (FME) enrichment for Cs, Rb, Ba, Pb, As, and Sb (up to 100 times primitive mantle (PM)), W (1000 PM), and B (10000 PM). Alkali over U ratios of compiled serpentinite data (n ˜ 620) reveal distinctive global FME enrichment trends for MOR vs. forearc (FA) serpentinisation. ET serpentinites fall into the latter, indicating both sediment-equilibrated fluids and the preservation of characteristic FME enrichment patterns in HP serpentinites. Petrography reveals a multiphase evolution of the HP veins including retrograde serpentinisation, whereas serpentinite hosts have remained largely unaffected by retrogression. Comparison of vein vs. wall rock bulk data indicate vein-forming fluids in equilibrium with wall rocks, however, without evidence for external fluid ingress. The preservation of multiple fluid-rock interaction episodes and the lack of external fluid ingress in the ET HP serpentinites indicate near-closed system behaviour throughout subduction and imprint of characteristic fluid signatures onto the mantle. [1] Scambelluri et al. (1995) Geology, 23, 459-462. [2] John et al. (2011) Earth Planet Sci Lett 308, 65-76. [3] Peters and Pettke (2016) GGR, DOI: 10.1111/ggr.12125.

Mechanochemical symmetric breaking in cell motility of slime mold

NASA Astrophysics Data System (ADS)

Guy, Robert; Zhang, Shun; Del Alamo, Juan Carlos

2016-11-01

The cytoplasm of the true slime mold Physarum polycephalum exhibits regular rhythmic periodic shuttle streaming though the cell in the direction of motion. The fluid motion is driven by the periodic contraction of an actin-myosin gel that is regulated by a calcium oscillation. When the organism is small (< 100 microns) there is no shuttle streaming, but beyond this size, regular back-and-forth streaming appears and the cell begins to migrate. In this talk we analyze a mechanochemical model of the cell which includes the intracellular fluid, the active contractile cytoskeleton, the adhesion to the substrate, and the dynamics of a chemical oscillator. We use this analysis along with experimental data to identify the instability related to the onset of streaming in order to bring insight into how contraction, flow, and adhesion are coordinated during locomotion.

A binomial modeling approach for upscaling colloid transport under unfavorable conditions: Emergent prediction of extended tailing

NASA Astrophysics Data System (ADS)

Hilpert, Markus; Rasmuson, Anna; Johnson, William P.

2017-07-01

Colloid transport in saturated porous media is significantly influenced by colloidal interactions with grain surfaces. Near-surface fluid domain colloids experience relatively low fluid drag and relatively strong colloidal forces that slow their downgradient translation relative to colloids in bulk fluid. Near-surface fluid domain colloids may reenter into the bulk fluid via diffusion (nanoparticles) or expulsion at rear flow stagnation zones, they may immobilize (attach) via primary minimum interactions, or they may move along a grain-to-grain contact to the near-surface fluid domain of an adjacent grain. We introduce a simple model that accounts for all possible permutations of mass transfer within a dual pore and grain network. The primary phenomena thereby represented in the model are mass transfer of colloids between the bulk and near-surface fluid domains and immobilization. Colloid movement is described by a Markov chain, i.e., a sequence of trials in a 1-D network of unit cells, which contain a pore and a grain. Using combinatorial analysis, which utilizes the binomial coefficient, we derive the residence time distribution, i.e., an inventory of the discrete colloid travel times through the network and of their probabilities to occur. To parameterize the network model, we performed mechanistic pore-scale simulations in a single unit cell that determined the likelihoods and timescales associated with the above colloid mass transfer processes. We found that intergrain transport of colloids in the near-surface fluid domain can cause extended tailing, which has traditionally been attributed to hydrodynamic dispersion emanating from flow tortuosity of solute trajectories.

Multiscale Models for the Two-Stream Instability

NASA Astrophysics Data System (ADS)

Joseph, Ilon; Dimits, Andris; Banks, Jeffrey; Berger, Richard; Brunner, Stephan; Chapman, Thomas

2017-10-01

Interpenetrating streams of plasma found in many important scenarios in nature and in the laboratory can develop kinetic two-stream instabilities that exchange momentum and energy between the streams. A quasilinear model for the electrostatic two-stream instability is under development as a component of a multiscale model that couples fluid simulations to kinetic theory. Parameters of the model will be validated with comparison to full kinetic simulations using LOKI and efficient strategies for numerical solution of the quasilinear model and for coupling to the fluid model will be discussed. Extending the kinetic models into the collisional regime requires an efficient treatment of the collision operator. Useful reductions of the collision operator relative to the full multi-species Landau-Fokker-Plank operator are being explored. These are further motivated both by careful consideration of the parameter orderings relevant to two-stream scenarios and by the particular 2D+2V phase space used in the LOKI code. Prepared for US DOE by LLNL under Contract DE-AC52-07NA27344 and LDRD project 17- ERD-081.

Bulk-Flow Analysis, part A

NASA Technical Reports Server (NTRS)

Childs, Dara W.

1993-01-01

The bulk-flow analysis results for this contract are incorporated in the following publications: 'Fluid-Structure Interaction Forces at Pump-Impeller Shroud Surfaces for Axial Vibration Analysis'; 'Centrifugal Acceleration Modes for Incompressible Fluid in the Leakage Annulus Between a Shrouded Pump Impeller and Its Housing'; 'Influence of Impeller Shroud Forces on Pump Rotordynamics'; 'Pressure Oscillation in the Leakage Annulus Between a Shrouded Impeller and Its Housing Due to Impeller-Discharge-Pressure Disturbances'; and 'Compressibility Effects on Rotor Forces in the Leakage Path Between a Shrouded Pump Impeller and Its Housing'. These publications are summarized and included in this final report. Computational Fluid Mechanics (CFD) results developed by Dr. Erian Baskharone are reported separately.

Physical and chemical properties of some new perfluoropolyalkylether lubricants prepared by direct fluorination

NASA Technical Reports Server (NTRS)

Jones, W. R., Jr.; Bierschenk, T. R.; Juhlke, T. J.; Kawa, H.; Lagow, R. J.

1993-01-01

A series of perfluoropolyalkylether (PFPAE) fluids was synthesized by direct fluorination. Viscosity-temperature properties, oxidation stabilities, oxidation-corrosion properties, bulk modulus, lubricity, surface tension and density were measured. It was shown that as the carbon to oxygen ratio in the polymer repeating unit decreases, the viscometric properties improve, the fluids may become poorer boundary lubricants, the bulk modulus increases, the surface tension increases and the fluid density increases. The presence of difluoromethylene oxide units in the polymer does not significantly lower the oxidation and oxidation-corrosion stabilities as long as the difluoromethylene oxide units are separated by other units.

Influences of a temperature gradient and fluid inertia on acoustic streaming in a standing wave.

PubMed

Thompson, Michael W; Atchley, Anthony A; Maccarone, Michael J

2005-04-01

Following the experimental method of Thompson and Atchley [J. Acoust. Soc. Am. 117, 1828-1838 (2005)] laser Doppler anemometry (LDA) is used to investigate the influences of a thermoacoustically induced axial temperature gradient and of fluid inertia on the acoustic streaming generated in a cylindrical standing-wave resonator filled with air driven sinusoidally at a frequency of 308 Hz. The axial component of Lagrangian streaming velocity is measured along the resonator axis and across the diameter at acoustic-velocity amplitudes of 2.7, 4.3, 6.1, and 8.6 m/s at the velocity antinodes. The magnitude of the axial temperature gradient along the resonator wall is varied between approximately 0 and 8 K/m by repeating measurements with the resonator either surrounded by a water jacket, suspended within an air-filled tank, or wrapped in foam insulation. A significant correlation is observed between the temperature gradient and the behavior of the streaming: as the magnitude of the temperature gradient increases, the magnitude of the streaming decreases and the shape of the streaming cell becomes increasingly distorted. The observed steady-state streaming velocities are not in agreement with any available theory.

Longitudinal and bulk viscosities of Lennard-Jones fluids

NASA Astrophysics Data System (ADS)

Tankeshwar, K.; Pathak, K. N.; Ranganathan, S.

1996-12-01

Expressions for the longitudinal and bulk viscosities have been derived using Green Kubo formulae involving the time integral of the longitudinal and bulk stress autocorrelation functions. The time evolution of stress autocorrelation functions are determined using the Mori formalism and a memory function which is obtained from the Mori equation of motion. The memory function is of hyperbolic secant form and involves two parameters which are related to the microscopic sum rules of the respective autocorrelation function. We have derived expressions for the zeroth-, second-and fourth- order sum rules of the longitudinal and bulk stress autocorrelation functions. These involve static correlation functions up to four particles. The final expressions for these have been put in a form suitable for numerical calculations using low- order decoupling approximations. The numerical results have been obtained for the sum rules of longitudinal and bulk stress autocorrelation functions. These have been used to calculate the longitudinal and bulk viscosities and time evolution of the longitudinal stress autocorrelation function of the Lennard-Jones fluids over wide ranges of densities and temperatures. We have compared our results with the available computer simulation data and found reasonable agreement.

Rock property measurements and analysis of selected igneous, sedimentary, and metamorphic rocks from worldwide localities

USGS Publications Warehouse

Johnson, Gordon R.

1983-01-01

Dry bulk density and grain density measurements were made on 182 samples of igneous, sedimentary, and metamorphic rocks from various world-wide localities. Total porosity values and both water-accessible and helium-accessible porosities were calculated from the density data. Magnetic susceptibility measurements were made on the solid samples and permeability and streaming potentials were concurrently measured on most samples. Dry bulk densities obtained using two methods of volume determination, namely direct measurement and Archlmedes principle, were nearly equivalent for most samples. Grain densities obtained on powdered samples were typically greater than grain densities obtained on solid samples, but differences were usually small. Sedimentary rocks had the highest percentage of occluded porosity per rock volume whereas metamorphic rocks had the highest percentage of occluded porosity per total porosity. There was no apparent direct relationship between permeability and streaming potential for most samples, although there were indications of such a relationship in the rock group consisting of granites, aplites, and syenites. Most rock types or groups of similar rock types of low permeability had, when averaged, comparable levels of streaming potential per unit of permeability. Three calcite samples had negative streaming potentials.

The role of penetrating gas streams in setting the dynamical state of galaxy clusters

NASA Astrophysics Data System (ADS)

Zinger, E.; Dekel, A.; Birnboim, Y.; Kravtsov, A.; Nagai, D.

2016-09-01

We utilize cosmological simulations of 16 galaxy clusters at redshifts z = 0 and z = 0.6 to study the effect of inflowing streams on the properties of the X-ray emitting intracluster medium. We find that the mass accretion occurs predominantly along streams that originate from the cosmic web and consist of heated gas. Clusters that are unrelaxed in terms of their X-ray morphology are characterized by higher mass inflow rates and deeper penetration of the streams, typically into the inner third of the virial radius. The penetrating streams generate elevated random motions, bulk flows and cold fronts. The degree of penetration of the streams may change over time such that clusters can switch from being unrelaxed to relaxed over a time-scale of several giga years.

Black hole acoustics in the minimal geometric deformation of a de Laval nozzle

NASA Astrophysics Data System (ADS)

da Rocha, Roldão

2017-05-01

The correspondence between sound waves, in a de Laval propelling nozzle, and quasinormal modes emitted by brane-world black holes deformed by a 5D bulk Weyl fluid are here explored and scrutinized. The analysis of sound waves patterns in a de Laval nozzle in the laboratory, reciprocally, is here shown to provide relevant data about the 5D bulk Weyl fluid and its on-brane projection, comprised by the minimal geometrically deformed compact stellar distribution on the brane. Acoustic perturbations of the gas fluid flow in the de Laval nozzle are proved to coincide with the quasinormal modes of black holes solutions deformed by the 5D Weyl fluid, in the geometric deformation procedure. Hence, in a phenomenological Eötvös-Friedmann fluid brane-world model, the realistic shape of a de Laval nozzle is derived and its consequences studied.

Transport and flow characteristics of an oscillating cylindrical fiber for total artificial lung application.

PubMed

Qamar, Adnan; Bull, Joseph L

2017-08-01

Mass transport and fluid dynamics characteristics in the vicinity of an oscillating cylindrical fiber with an imposed pulsatile inflow condition are computationally investigated in the present study. The work is motivated by a recently proposed design modification to the Total Artificial Lung (TAL) device, which is expected to provide better gas exchange. Navier-Stokes computations, coupled with convection-diffusion equation are performed to assess flow dynamics and mass transport behavior around the oscillating fiber. The oscillations and the pulsatile free stream velocity are represented by two sinusoidal functions. The resulting non-dimensional parameters are Keulegan-Carpenter number (KC), Schmidt number (Sc), Reynolds number (Re), pulsatile inflow amplitude ([Formula: see text]), and amplitude of cylinder oscillation ([Formula: see text]). Results are computed for [Formula: see text], Sc = 1000, Re = 5 and 10, [Formula: see text] and 0.7 and 0.25 [Formula: see text][Formula: see text][Formula: see text] 5.25. The pulsatile inflow parameters correspond to the flow velocities found in human pulmonary artery while matching the operating TAL Reynolds number. Mass transport from the surface of the cylinder to the bulk fluid is found to be primarily dependent on the size of surface vortices created by the movement of the cylinder. Time-averaged surface Sherwood number (Sh) is dependent on the amplitude and KC of cylinder oscillation. Compared to the fixed cylinder case, a significant gain up to 380% in Sh is achieved by oscillating the cylinder even at the small displacement amplitude (AD = 0.75D). Moreover, with decrease in KC the oscillating cylinder exhibits a lower drag amplitude compared with the fixed cylinder case. Inflow pulsation amplitude has minor effects on the mass transport characteristics. However, an increase in [Formula: see text] results in an increase in the amplitude of the periodic drag force on the cylinder. This rise in the drag amplitude is similar to that measured for the fixed cylinder case. Quantifications of shear stress distribution in the bulk fluid suggest that the physiological concerns of platelet activation and injury to red blood cells due to cylinder oscillation are negligible.

Scaled particle theory for bulk and confined fluids: A review

NASA Astrophysics Data System (ADS)

Dong, Wei; Chen, XiaoSong

2018-07-01

More than half a century after its first formulation by Reiss, Frisch and Lebowitz in 1959, scaled particle theory (SPT) has proven its immense usefulness and has become one of the most successful theories in liquid physics. In recent years, we have strived to extend SPT to fluids confined in a variety of random porous matrices. In this article, we present a timely review of these developments. We have endeavored to present a formulation that is pedagogically more accessible than those presented in various original papers, and we hope this benefits newcomers in their research work. We also use more consistent notations for different cases. In addition, we discuss issues that have been scarcely considered in the literature, e.g., the one-fluid structure of SPT due to the isomorphism between the equation of state for a multicomponent fluid and that for a one-component fluid or the pure-confinement scaling relation that provides a connection between a confined and a bulk fluid.

Methods and Apparatus for Deployable Swirl Vanes

NASA Technical Reports Server (NTRS)

Shah, Parthiv N. (Inventor)

2017-01-01

An aircraft control structure for drag management includes a nozzle structure configured to exhaust a swirling fluid stream. A plurality of swirl vanes are positioned within the nozzle structure, and an actuation subsystem is configured to cause the plurality of swirl vanes to move from a deployed state to a non-deployed state. In the non-deployed state, the plurality of swirl vanes are substantially flush with the inner surface of the nozzle structure. In the deployed state, the plurality of swirl vanes produce the swirling fluid stream.

The Gulf Stream and Density of Fluids

ERIC Educational Resources Information Center

Landstrom, Erich

2006-01-01

A few kilometers from the shores of Palm Beach County, Florida, is the Gulf Stream current--a remarkable "river" within an ocean. The current's journey across the Atlantic Ocean connects southeast Florida and southwest Great Britain as it streams steadily north at speeds of 97 km a day; moving 100 times as much water as all the rivers on…

Speciation in experimental C-O-H fluids produced by the thermal dissociation of oxalic acid dihydrate

NASA Astrophysics Data System (ADS)

Morgan, G. B., VI; Chou, I.-Ming; Pasteris, J. D.

1992-01-01

Fluid speciations and their related reaction pathways were studied in C-O-H-system fluids produced by the thermal dissociation of oxalic acid dihydrate (OAD: H 2C 2O 4 · 2H 2O) sealed in silica glass capsules. Experiments were conducted in the temperature range 230-750°C, with bulk fluid densities in the range 0.01-0.53 g/cm 3. Pressure was controlled by temperature and density in the isochoric systems. The quenched products of dissociation experiments were an aqueous liquid and one (supercritical fluid) or, rarely, two (vapor plus liquid) carbonic phase (s). In-situ Raman microanalyses were performed on the quenched carbonic phases at room temperature, at which fluid pressures ranged from about 50 to 340 bars. Bulk fluid speciations were reconstructed from the Raman analyses via mass balance constraints, and appear to monitor the true fluid speciations at run conditions. In experiments from the lowtemperature range (230-350°C), fluid speciations record the dissociation of OAD according to the reaction OAD = CO2 + CO + 3 H2O. A process of the form CO + H2O = CO2 + H2 is driven to the right with increasing temperature. The hydrogen gas produced tends to escape from the sample systems via diffusion into/through the silica glass capsules, shifting bulk compositions toward equimolar binary H 2O-CO 2 mixtures. The speciations of fluids in experiments with minimal hydrogen loss show poor agreement with speciations calculated for equilibrium fluids by the corresponding-states model of SAXENA and FEI (1988). Such disagreement suggests that the formations of CH 4 and graphite are metastably inhibited in the current experiments, which correlates with their absence or trivial abundances in experimental products. Moreover, calculations in which the stabilities of methane and graphite are suppressed suggest that such metastable equilibrium is approached only in experiments at temperatures greater than about 600-650°C. These results have applications to fluid processes in geological environments, in addition to considerations of using oxalate compounds as volatile sources in experimental studies. It is possible that disequilibrium or metastable fluids may be entrapped as inclusions; re-speciation (toward metastable or stable equilibrium) during P-T evolution of a given terrain would place the fluid inclusion on a new isochore that would not project through the original conditions of entrapment. Moreover, the disequilibrium to metastable nature of dissociation reactions, coupled with the diffusional mobility of hydrogen gas observed in the current experiments, suggests that the predominance of binary H 2O-CO 2 fluid mixtures in natural inclusions from medium- to high-grade metamorphic terrains may be more than a coincidence of similar initial bulk compositions.

Speciation in experimental C-O-H fluids produced by the thermal dissociation of oxalic acid dihydrate

USGS Publications Warehouse

Morgan, G.B.; Chou, I.-Ming; Pasteris, J.D.

1992-01-01

Fluid speciations and their related reaction pathways were studied in C-O-H-system fluids produced by the thermal dissociation of oxalic acid dihydrate (OAD: H2C2O4 ?? 2H2O) sealed in silica glass capsules. Experiments were conducted in the temperature range 230-750??C, with bulk fluid densities in the range 0.01-0.53 g/cm3. Pressure was controlled by temperature and density in the isochoric systems. The quenched products of dissociation experiments were an aqueous liquid and one (supercritical fluid) or, rarely, two (vapor plus liquid) carbonic phase (s). In-situ Raman microanalyses were performed on the quenched carbonic phases at room temperature, at which fluid pressures ranged from about 50 to 340 bars. Bulk fluid speciations were reconstructed from the Raman analyses via mass balance constraints, and appear to monitor the true fluid speciations at run conditions. In experiments from the lowtemperature range (230-350??C), fluid speciations record the dissociation of OAD according to the reaction OAD = CO2 + CO + 3H2O. A process of the form CO + H2O = CO2 + H2 is driven to the right with increasing temperature. The hydrogen gas produced tends to escape from the sample systems via diffusion into/through the silica glass capsules, shifting bulk compositions toward equimolar binary H2O-CO2 mixtures. The speciations of fluids in experiments with minimal hydrogen loss show poor agreement with speciations calculated for equilibrium fluids by the corresponding-states model of Saxena and Fei (1988). Such disagreement suggests that the formations of CH4 and graphite are metastably inhibited in the current experiments, which correlates with their absence or trivial abundances in experimental products. Moreover, calculations in which the stabilities of methane and graphite are suppressed suggest that such metastable equilibrium is approached only in experiments at temperatures greater than about 600-650??C. These results have applications to fluid processes in geological environments, in addition to considerations of using oxalate compounds as volatile sources in experimental studies. It is possible that disequilibrium or metastable fluids may be entrapped as inclusions; re-speciation (toward metastable or stable equilibrium) during P-T evolution of a given terrain would place the fluid inclusion on a new isochore that would not project through the original conditions of entrapment. Moreover, the disequilibrium to metastable nature of dissociation reactions, coupled with the diffusional mobility of hydrogen gas observed in the current experiments, suggests that the predominance of binary H2O-CO2 fluid mixtures in natural inclusions from medium- to high-grade metamorphic terrains may be more than a coincidence of similar initial bulk compositions. ?? 1992.

Trapping of Embolic Particles in a Vessel Phantom by Cavitation-Enhanced Acoustic Streaming

PubMed Central

Maxwell, Adam D.; Park, Simone; Vaughan, Benjamin L.; Cain, Charles A.; Grotberg, James B.; Xu, Zhen

2014-01-01

Cavitation clouds generated by short, high-amplitude, focused ultrasound pulses were previously observed to attract, trap, and erode thrombus fragments in a vessel phantom. This phenomenon may offer a noninvasive method to capture and eliminate embolic fragments flowing through the bloodstream during a cardiovascular intervention. In this article, the mechanism of embolus trapping was explored by particle image velocimetry (PIV). PIV was used to examine the fluid streaming patterns generated by ultrasound in a vessel phantom with and without crossflow of blood-mimicking fluid. Cavitation enhanced streaming, which generated fluid vortices adjacent to the focus. The focal streaming velocity, uf, was as high as 120 cm/s, while mean crossflow velocities, uc, were imposed up to 14 cm/s. When a solid particle 3-4 mm diameter was introduced into crossflow, it was trapped near the focus. Increasing uf promoted particle trapping while increasing uc promoted particle escape. The maximum crossflow Reynolds number at which particles could be trapped, Rec, was approximately linear with focal streaming number, Ref, i.e. Rec = 0.25Ref + 67.44 (R2=0.76) corresponding to dimensional velocities uc=0.084uf + 3.122 for 20 < uf < 120 cm/s. The fluidic pressure map was estimated from PIV and indicated a negative pressure gradient towards the focus, trapping the embolus near this location. PMID:25109407

The temporal evolution of magnesium isotope fractionation during hydromagnesite dissolution, precipitation, and at equilibrium

NASA Astrophysics Data System (ADS)

Oelkers, Eric H.; Berninger, Ulf-Niklas; Pérez-Fernàndez, Andrea; Chmeleff, Jérôme; Mavromatis, Vasileios

2018-04-01

This study provides experimental evidence of the resetting of the magnesium (Mg) isotope signatures of hydromagnesite in the presence of an aqueous fluid during its congruent dissolution, precipitation, and at equilibrium at ambient temperatures over month-long timescales. All experiments were performed in batch reactors in aqueous sodium carbonate buffer solutions having a pH from 7.8 to 9.2. The fluid phase in all experiments attained bulk chemical equilibrium within analytical uncertainty with hydromagnesite within several days, but the experiments were allowed to continue for up to 575 days. During congruent hydromagnesite dissolution, the fluid first became enriched in isotopically light Mg compared to the dissolving hydromagnesite, but this Mg isotope composition became heavier after the fluid attained chemical equilibrium with the mineral. The δ26Mg composition of the fluid was up to ∼0.35‰ heavier than the initial dissolving hydromagnesite at the end of the dissolution experiments. Hydromagnesite precipitation was provoked during one experiment by increasing the reaction temperature from 4 to 50 °C. The δ26Mg composition of the fluid increased as hydromagnesite precipitated and continued to increase after the fluid attained bulk equilibrium with this phase. These observations are consistent with the hypothesis that mineral-fluid equilibrium is dynamic (i.e. dissolution and precipitation occur at equal, non-zero rates at equilibrium). Moreover the results presented in this study confirm (1) that the transfer of material from the solid to the fluid phase may not be conservative during stoichiometric dissolution, and (2) that the isotopic compositions of carbonate minerals can evolve even when the mineral is in bulk chemical equilibrium with its coexisting fluid. This latter observation suggests that the preservation of isotopic signatures of carbonate minerals in the geological record may require a combination of the isolation of fluid-mineral system from external chemical input and/or the existence of a yet to be defined dissolution/precipitation inhibition mechanism.

Adsorption behaviors of supercritical Lennard-Jones fluid in slit-like pores.

PubMed

Li, Yingfeng; Cui, Mengqi; Peng, Bo; Qin, Mingde

2018-05-18

Understanding the adsorption behaviors of supercritical fluid in confined space is pivotal for coupling the supercritical technology and the membrane separation technology. Based on grand canonical Monte Carlo simulations, the adsorption behaviors of a Lennard-Jones (LJ) fluid in slit-like pores at reduced temperatures over the critical temperature, T c *  = 1.312, are investigated; and impacts of the wall-fluid interactions, the pore width, and the temperature are taken into account. It is found that even if under supercritical conditions, the LJ fluid can undergo a "vapor-liquid phase transition" in confined space, i.e., the adsorption density undergoes a sudden increase with the bulk density. A greater wall-fluid attractive potential, a smaller pore width, and a lower temperature will bring about a stronger confinement effect. Besides, the adsorption pressure reaches a local minimum when the bulk density equals to a certain value, independent of the wall-fluid potential or pore width. The insights in this work have both practical and theoretical significances. Copyright © 2018 Elsevier Inc. All rights reserved.

Future Roads Near Streams

EPA Pesticide Factsheets

Roads are a source of auto related pollutants (e.g. gasoline, oil and other engine fluids). When roads are near streams, rain can wash these pollutants directly into the stream, harming both water and habitat quality. This metric measured the length of roads within 30 meters of a stream. More information about these resources, including the variables used in this study, may be found here: https://edg.epa.gov/data/Public/ORD/NERL/ReVA/ReVA_Data.zip.

Roads Near Streams

EPA Pesticide Factsheets

Roads are a source of auto related pollutants (e.g. gasoline, oil and other engine fluids). When roads are near streams, rain can wash these pollutants directly into the stream, harming both water and habitat quality. This metric measured the length of roads within 30 meters of a stream. More information about these resources, including the variables used in this study, may be found here: https://edg.epa.gov/data/Public/ORD/NERL/ReVA/ReVA_Data.zip.

Estimates of olivine-basaltic melt electrical conductivity using a digital rock physics approach

NASA Astrophysics Data System (ADS)

Miller, Kevin J.; Montési, Laurent G. J.; Zhu, Wen-lu

2015-12-01

Estimates of melt content beneath fast-spreading mid-ocean ridges inferred from magnetotelluric tomography (MT) vary between 0.01 and 0.10. Much of this variation may stem from a lack of understanding of how the grain-scale melt geometry influences the bulk electrical conductivity of a partially molten rock, especially at low melt fraction. We compute bulk electrical conductivity of olivine-basalt aggregates over 0.02 to 0.20 melt fraction by simulating electric current in experimentally obtained partially molten geometries. Olivine-basalt aggregates were synthesized by hot-pressing San Carlos olivine and high-alumina basalt in a solid-medium piston-cylinder apparatus. Run conditions for experimental charges were 1.5 GPa and 1350 °C. Upon completion, charges were quenched and cored. Samples were imaged using synchrotron X-ray micro-computed tomography (μ-CT). The resulting high-resolution, 3-dimensional (3-D) image of the melt distribution constitutes a digital rock sample, on which numerical simulations were conducted to estimate material properties. To compute bulk electrical conductivity, we simulated a direct current measurement by solving the current continuity equation, assuming electrical conductivities for olivine and melt. An application of Ohm's Law yields the bulk electrical conductivity of the partially molten region. The bulk electrical conductivity values for nominally dry materials follow a power-law relationship σbulk = Cσmeltϕm with fit parameters m = 1.3 ± 0.3 and C = 0.66 ± 0.06. Laminar fluid flow simulations were conducted on the same partially molten geometries to obtain permeability, and the respective pathways for electrical current and fluid flow over the same melt geometry were compared. Our results indicate that the pathways for flow fluid are different from those for electric current. Electrical tortuosity is lower than fluid flow tortuosity. The simulation results are compared to existing experimental data, and the potential influence of volatiles and melt films on electrical conductivity of partially molten rocks is discussed.

X-Ray Absorption Spectroscopy of Electrochemically Generated Species

DTIC Science & Technology

1993-02-01

that is a modification of our previously reported design (17) with reticulated vitreous carbon (RVC) as the working electrode. A peristaltic pump...and a flowing analyte stream. A packed carbon -bed bulk electrolysis cell generates the desired metal oxidation state. Completa oxidation and...packed carbon -bed bulk electrolysis cell generates the desired metal oxidation state. The system consists of a closed loop of electrolyte solution

Variable flexure-based fluid filter

DOEpatents

Brown, Steve B.; Colston, Jr., Billy W.; Marshall, Graham; Wolcott, Duane

2007-03-13

An apparatus and method for filtering particles from a fluid comprises a fluid inlet, a fluid outlet, a variable size passage between the fluid inlet and the fluid outlet, and means for adjusting the size of the variable size passage for filtering the particles from the fluid. An inlet fluid flow stream is introduced to a fixture with a variable size passage. The size of the variable size passage is set so that the fluid passes through the variable size passage but the particles do not pass through the variable size passage.

Diagnostic system for measuring temperature, pressure, CO2 concentration and H2O concentration in a fluid stream

DOE Office of Scientific and Technical Information (OSTI.GOV)

Partridge, Jr., William P.; Jatana, Gurneesh Singh; Yoo, Ji-Hyung

A diagnostic system for measuring temperature, pressure, CO.sub.2 concentration and H.sub.2O concentration in a fluid stream is described. The system may include one or more probes that sample the fluid stream spatially, temporally and over ranges of pressure and temperature. Laser light sources are directed down pitch optical cables, through a lens and to a mirror, where the light sources are reflected back, through the lens to catch optical cables. The light travels through the catch optical cables to detectors, which provide electrical signals to a processer. The processer utilizes the signals to calculate CO.sub.2 concentration based on the temperaturesmore » derived from H.sub.2O vapor concentration. A probe for sampling CO.sub.2 and H.sub.2O vapor concentrations is also disclosed. Various mechanical features interact together to ensure the pitch and catch optical cables are properly aligned with the lens during assembly and use.« less

Diagnostic system for measuring temperature, pressure, CO.sub.2 concentration and H.sub.2O concentration in a fluid stream

DOE Office of Scientific and Technical Information (OSTI.GOV)

Partridge, Jr., William P.; Jatana, Gurneesh Singh; Yoo, Ji Hyung

A diagnostic system for measuring temperature, pressure, CO.sub.2 concentration and H.sub.2O concentration in a fluid stream is described. The system may include one or more probes that sample the fluid stream spatially, temporally and over ranges of pressure and temperature. Laser light sources are directed down pitch optical cables, through a lens and to a mirror, where the light sources are reflected back, through the lens to catch optical cables. The light travels through the catch optical cables to detectors, which provide electrical signals to a processer. The processer utilizes the signals to calculate CO.sub.2 concentration based on the temperaturesmore » derived from H.sub.2O vapor concentration. A probe for sampling CO.sub.2 and H.sub.2O vapor concentrations is also disclosed. Various mechanical features interact together to ensure the pitch and catch optical cables are properly aligned with the lens during assembly and use.« less

Actinide and lanthanide separation process (ALSEP)

DOEpatents

Guelis, Artem V.

2013-01-15

The process of the invention is the separation of minor actinides from lanthanides in a fluid mixture comprising, fission products, lanthanides, minor actinides, rare earth elements, nitric acid and water by addition of an organic chelating aid to the fluid; extracting the fluid with a solvent comprising a first extractant, a second extractant and an organic diluent to form an organic extractant stream and an aqueous raffinate. Scrubbing the organic stream with a dicarboxylic acid and a chelating agent to form a scrubber discharge. The scrubber discharge is stripped with a simple buffering agent and a second chelating agent in the pH range of 2.5 to 6.1 to produce actinide and lanthanide streams and spent organic diluents. The first extractant is selected from bis(2-ethylhexyl)hydrogen phosphate (HDEHP) and mono(2-ethylhexyl)2-ethylhexyl phosphonate (HEH(EHP)) and the second extractant is selected from N,N,N,N-tetra-2-ethylhexyl diglycol amide (TEHDGA) and N,N,N',N'-tetraoctyl-3-oxapentanediamide (TODGA).

Streaming Potential In Rocks Saturated With Water And Oil

NASA Astrophysics Data System (ADS)

Tarvin, J. A.; Caston, A.

2011-12-01

Fluids flowing through porous media generate electrical currents. These currents cause electric potentials, called "streaming potentials." Streaming potential amplitude depends on the applied pressure gradient, on rock and fluid properties, and on the interaction between rock and fluid. Streaming potential has been measured for rocks saturated with water (1) and with water-gas mixtures. (2) Few measurements (3) have been reported for rocks saturated with water-oil mixtures. We measured streaming potential for sandstone and limestone saturated with a mixture of brine and laboratory oil. Cylindrical samples were initially saturated with brine and submerged in oil. Saturation was changed by pumping oil from one end of a sample to the other and then through the sample in the opposite direction. Saturation was estimated from sample resistivity. The final saturation of each sample was determined by heating the sample in a closed container and measuring the pressure. Measurements were made by modulating the pressure difference (of oil) between the ends of a sample at multiple frequencies below 20 Hz. The observed streaming potential is a weak function of the saturation. Since sample conductivity decreases with increasing oil saturation, the electro-kinetic coupling coefficient (Pride's L (4)) decreases with increasing oil saturation. (1) David B. Pengra and Po-zen Wong, Colloids and Surfaces, vol., p. 159 283-292 (1999). (2) Eve S. Sprunt, Tony B. Mercer, and Nizar F. Djabbarah, Geophysics, vol. 59, p. 707-711 (1994). (3) Vinogradov, J., Jackson, M.D., Geophysical Res. L., Vol. 38, Article L01301 (2011). (4) Steve Pride, Phys. Rev. B, vol. 50, pp. 15678-15696 (1994).

Method for measuring particulate and gaseous metals in a fluid stream, device for measuring particulate and gaseous metals in a fluid stream

DOEpatents

Farber, Paul S.; Huang, Hann-Shen

2001-01-01

A method for analyzing metal in a fluid is provided comprising maintaining a first portion of a continuous filter media substrate at a temperature coinciding with the phase in which the metal is to be analyzed; contacting the fluid to a first portion of said substrate to retain the metal on the first portion of said substrate; preventing further contact of the fluid to the first portion of substrate; and contacting the fluid to a second portion of said substrate to retain metal on the second portion of the said substrate while simultaneously analyzing the first portion for metal. Also provided is a device for the simultaneous monitoring and analysis of metal in a fluid comprising a continuous filter media substrate; means for maintaining a first portion of said filter media substrate at a temperature coinciding with the phase in which the metal is to be analyzed; a means for contacting the fluid to the first portion of said substrate; a means for preventing further contact of the fluid to the first portion of substrate; a means for contacting the fluid to a second portion of said substrate to retain metal on the second portion of the said substrate; and means for analyzing the first portion for metal.

On the adsorption properties of magnetic fluids: Impact of bulk structure

NASA Astrophysics Data System (ADS)

Kubovcikova, Martina; Gapon, Igor V.; Zavisova, Vlasta; Koneracka, Martina; Petrenko, Viktor I.; Soltwedel, Olaf; Almasy, László; Avdeev, Mikhail V.; Kopcansky, Peter

2017-04-01

Adsorption of nanoparticles from magnetic fluids (MFs) on solid surface (crystalline silicon) was studied by neutron reflectometry (NR) and related to the bulk structural organization of MFs concluded from small-angle neutron scattering (SANS). The initial aqueous MF with nanomagnetite (co-precipitation reaction) stabilized by sodium oleate and MF modified by a biocompatible polymer, poly(ethylene glycol) (PEG), were considered. Regarding the bulk structure it was confirmed in the SANS experiment that comparatively small and compact (size 30 nm) aggregates of nanoparticle in the initial sample transfer to large and developed (size>130 nm, fractal dimension 2.7) associates in the PEG modified MF. This reorganization in the aggregates correlates with the changes in the neutron reflectivity that showed that a single adsorption layer of individual nanoparticles on the oxidized silicon surface for the initial MF disappears after the PEG modification. It is concluded that all particles in the modified fluid are in the aggregates that are not adsorbed by silicon.

The incompressible Rindler fluid versus the Schwarzschild-AdS fluid

NASA Astrophysics Data System (ADS)

Matsuo, Yoshinori; Natsuume, Makoto; Ohta, Masahiro; Okamura, Takashi

2013-02-01

We study the proposal by Bredberg et al. [J. High Energy Phys. 1103, 141 (2011)], where the fluid is defined by the Brown-York tensor on a timelike surface at r = rc in black hole backgrounds. We consider both Rindler space and the Schwarzschild-AdS (SAdS) black hole. The former describes an incompressible fluid, whereas the latter describes the vanishing bulk viscosity at arbitrary rc. Although the near-horizon limit of the SAdS black hole is Rindler space, these two results do not contradict each other. We also find an interesting "coincidence" with the black hole membrane paradigm that gives a negative bulk viscosity. In order to show these results, we rewrite the hydrodynamic stress tensor via metric perturbations using the conservation equation. The resulting expressions are suitable to compare with the Brown-York tensor.

A streaming birefringence study of the flow at the junction of the aorta and the renal arteries

NASA Astrophysics Data System (ADS)

Rankin, G. W.; Sabbah, H. N.; Stein, P. D.

1989-11-01

Streaming birefringence with an organic dye (Milling Yellow) was used to investigate the flow near the junction of the renal arteries and the descending aorta in a model of human vessels. The dye concentration was adjusted to give fluid rheological properties, typical of blood. Steady and pulsatile flow were investigated at branch-to-trunk flow ratios of 0.050 0.350. The flow ratio range over which flow separation and simple secondary flows were identified during systole near the renal ostia are reported. Streaming birefringence has the advantage of allowing visualization of the entire flow field. Also, the fluid rather than suspended particles are observed. An important disadvantage, however, is that three-dimensional flows make interpretation difficult.

Predicting the pKa and stability of organic acids and bases at an oil-water interface.

PubMed

Andersson, M P; Olsson, M H M; Stipp, S L S

2014-06-10

We have used density functional theory and the implicit solvent model, COSMO-RS, to investigate how the acidity constant, pKa, of organic acids and bases adsorbed at the organic compound-aqueous solution interface changes, compared to its value in the aqueous phase. The pKa determine the surface charge density of the molecules that accumulate at the fluid-fluid interface. We have estimated the pKa by comparing the stability of the protonated and unprotonated forms of a series of molecules in the bulk aqueous solution and at an interface where parts of each molecule reside in the hydrophobic phase and the rest remains in the hydrophilic phase. We found that the pKa for acids is shifted by ∼1 pH unit to higher values compared to the bulk water pKa, whereas they are shifted to lower values by a similar amount for bases. Because this pKa shift is similar in magnitude for each of the molecules studied, we propose that the pKa for molecules at a water-organic compound interface can easily be predicted by adding a small shift to the aqueous pKa. This shift is general and correlates with the functional group. We also found that the relative composition of molecules at the fluid-fluid interface is not the same as in the bulk. For example, species such as carboxylic acids are enriched at the interface, where they can dominate surface properties, even when they are a modest component in the bulk fluid. For high surface concentrations of carboxylic acid groups at an interface, such as a self-assembled monolayer, we have demonstrated that the pKa depends on the degree of deprotonation through direct hydrogen bonding between protonated and deprotonated acidic headgroups.

Analysis of Process Gases and Trace Contaminants in Membrane-Aerated Gaseous Effluent Streams.

NASA Technical Reports Server (NTRS)

Coutts, Janelle L.; Lunn, Griffin Michael; Meyer, Caitlin E.

2015-01-01

In membrane-aerated biofilm reactors (MABRs), hollow fibers are used to supply oxygen to the biofilms and bulk fluid. A pressure and concentration gradient between the inner volume of the fibers and the reactor reservoir drives oxygen mass transport across the fibers toward the bulk solution, providing the fiber-adhered biofilm with oxygen. Conversely, bacterial metabolic gases from the bulk liquid, as well as from the biofilm, move opposite to the flow of oxygen, entering the hollow fiber and out of the reactor. Metabolic gases are excellent indicators of biofilm vitality, and can aid in microbial identification. Certain gases can be indicative of system perturbations and control anomalies, or potentially unwanted biological processes occurring within the reactor. In confined environments, such as those found during spaceflight, it is important to understand what compounds are being stripped from the reactor and potentially released into the crew cabin to determine the appropriateness or the requirement for additional mitigation factors. Reactor effluent gas analysis focused on samples provided from Kennedy Space Center's sub-scale MABRs, as well as Johnson Space Center's full-scale MABRs, using infrared spectroscopy and gas chromatography techniques. Process gases, such as carbon dioxide, oxygen, nitrogen, nitrogen dioxide, and nitrous oxide, were quantified to monitor reactor operations. Solid Phase Microextraction (SPME) GC-MS analysis was used to identify trace volatile compounds. Compounds of interest were subsequently quantified. Reactor supply air was examined to establish target compound baseline concentrations. Concentration levels were compared to average ISS concentration values and/or Spacecraft Maximum Allowable Concentration (SMAC) levels where appropriate. Based on a review of to-date results, current trace contaminant control systems (TCCS) currently on board the ISS should be able to handle the added load from bioreactor systems without the need for secondary mitigation.

Low frequency vibration induced streaming in a Hele-Shaw cell

DOE Office of Scientific and Technical Information (OSTI.GOV)

Costalonga, M., E-mail: maxime.costalonga@univ-paris-diderot.fr; Laboratoire Matière et Systèmes Complexes, UMR CNRS 7057, Université Paris Diderot, 10 rue Alice Domon et Léonie Duquet, 75205 Paris cedex 13; Brunet, P.

When an acoustic wave propagates in a fluid, it can generate a second order flow whose characteristic time is much longer than the period of the wave. Within a range of frequency between ten and several hundred Hz, a relatively simple and versatile way to generate streaming flow is to put a vibrating object in the fluid. The flow develops vortices in the viscous boundary layer located in the vicinity of the source of vibrations, leading in turn to an outer irrotational streaming called Rayleigh streaming. Because the flow originates from non-linear time-irreversible terms of the Navier-Stokes equation, this phenomenonmore » can be used to generate efficient mixing at low Reynolds number, for instance in confined geometries. Here, we report on an experimental study of such streaming flow induced by a vibrating beam in a Hele-Shaw cell of 2 mm span using long exposure flow visualization and particle-image velocimetry measurements. Our study focuses especially on the effects of forcing frequency and amplitude on flow dynamics. It is shown that some features of this flow can be predicted by simple scaling arguments and that this vibration-induced streaming facilitates the generation of vortices.« less

Electrohydrodynamic and flow induced tip-streaming

NASA Astrophysics Data System (ADS)

Collins, Robert

2008-11-01

A liquid subjected to a strong electric field emits thin fluid jets from conical structures (Taylor cones) that form at its surface. Such behavior has both practical and fundamental implications, e.g. for raindrops in thunderclouds and in electrospray mass spectrometry. Theoretical analysis of the temporal development of such electrohydrodynamic (EHD) tip- streaming phenomena has been elusive given the large disparity in length scales between the macroscopic drops/films and the microscopic (nanoscopic) jets. Here, simulation and experiment are used to investigate the mechanisms of EHD tip-streaming from a film of finite conductivity. In the simulations, the full Taylor-Melcher leaky-dielectric model, which accounts for charge relaxation, is solved. Simulations show that tip- streaming does not occur for perfectly conducting or perfectly insulating liquids. Scaling laws for sizes of drops produced from the breakup of the thin jets is developed. Further, simulations demonstrate the critical role played by electrically induced surface shear stresses in the inception of tip-streaming. This invites a comparison to flow focusing, i.e. tip-streaming induced by co-flowing two fluids. The latter phenomenon is also investigated by simulation. In collaboration with Ronald Suryo, Exxon-Mobil; and Jeremy Jones, Michael Harris, and Osman Basaran, Purdue University.

Acoustic streaming induced by two orthogonal ultrasound standing waves in a microfluidic channel.

PubMed

Doinikov, Alexander A; Thibault, Pierre; Marmottant, Philippe

2018-07-01

A mathematical model is derived for acoustic streaming in a microfluidic channel confined between a solid wall and a rigid reflector. Acoustic streaming is produced by two orthogonal ultrasound standing waves of the same frequency that are created by two pairs of counter-propagating leaky surface waves induced in the solid wall. The magnitudes and phases of the standing waves are assumed to be different. Full analytical solutions are found for the equations of acoustic streaming. The obtained solutions are used in numerical simulations to reveal the structure of the acoustic streaming. It is shown that the interaction of two standing waves leads to the appearance of a cross term in the equations of acoustic streaming. If the phase lag between the standing waves is nonzero, the cross term brings about circular vortices with rotation axes perpendicular to the solid wall of the channel. The vortices make fluid particles rotate and move alternately up and down between the solid wall and the reflector. The obtained results are of immediate interest for acoustomicrofluidic applications such as the ultrasonic micromixing of fluids and the manipulation of microparticles. Copyright © 2018 Elsevier B.V. All rights reserved.

Methodologies for Reservoir Characterization Using Fluid Inclusion Gas Chemistry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dilley, Lorie M.

2015-04-13

The purpose of this project was to: 1) evaluate the relationship between geothermal fluid processes and the compositions of the fluid inclusion gases trapped in the reservoir rocks; and 2) develop methodologies for interpreting fluid inclusion gas data in terms of the chemical, thermal and hydrological properties of geothermal reservoirs. Phase 1 of this project was designed to conduct the following: 1) model the effects of boiling, condensation, conductive cooling and mixing on selected gaseous species; using fluid compositions obtained from geothermal wells, 2) evaluate, using quantitative analyses provided by New Mexico Tech (NMT), how these processes are recorded bymore » fluid inclusions trapped in individual crystals; and 3) determine if the results obtained on individual crystals can be applied to the bulk fluid inclusion analyses determined by Fluid Inclusion Technology (FIT). Our initial studies however, suggested that numerical modeling of the data would be premature. We observed that the gas compositions, determined on bulk and individual samples were not the same as those discharged by the geothermal wells. Gases discharged from geothermal wells are CO 2-rich and contain low concentrations of light gases (i.e. H 2, He, N, Ar, CH4). In contrast many of our samples displayed enrichments in these light gases. Efforts were initiated to evaluate the reasons for the observed gas distributions. As a first step, we examined the potential importance of different reservoir processes using a variety of commonly employed gas ratios (e.g. Giggenbach plots). The second technical target was the development of interpretational methodologies. We have develop methodologies for the interpretation of fluid inclusion gas data, based on the results of Phase 1, geologic interpretation of fluid inclusion data, and integration of the data. These methodologies can be used in conjunction with the relevant geological and hydrological information on the system to create fluid models for the system. The hope is that the methodologies developed will allow bulk fluid inclusion gas analysis to be a useful tool for estimating relative temperatures, identifying the sources and origins of the geothermal fluids, and developing conceptual models that can be used to help target areas of enhanced permeability.« less

The effect of artificial bulk viscosity in simulations of forced compressible turbulence

DOE Office of Scientific and Technical Information (OSTI.GOV)

Campos, A.; Morgan, B.

The use of an artificial bulk viscosity for shock stabilization is a common approach employed in turbulence simulations with high-order numerics. The effect of the artificial bulk viscosity is analyzed in the context of large eddy simulations by using as a test case simulations of linearly-forced compressible homogeneous turbulence (Petersen and Livescu, 2010 [12]). This case is unique in that it allows for the specification of a priori target values for total dissipation and ratio of solenoidal to dilatational dissipation. A comparison between these target values and the true predicted levels of dissipation is thus used to investigate the performancemore » of the artificial bulk viscosity. Results show that the artificial bulk viscosity is effective at achieving stable solutions, but also leads to large values of artificial dissipation that outweigh the physical dissipation caused by fluid viscosity. An alternate approach, which employs the artificial thermal conductivity only, shows that the dissipation of dilatational modes is entirely due to the fluid viscosity. However, this method leads to unwanted Gibbs oscillations around the shocklets. The use of shock sensors that further localize the artificial bulk viscosity did not reduce the amount of artificial dissipation introduced by the artificial bulk viscosity. Finally, an improved forcing function that explicitly accounts for the role of the artificial bulk viscosity in the budget of turbulent kinetic energy was explored.« less

The effect of artificial bulk viscosity in simulations of forced compressible turbulence

DOE PAGES

Campos, A.; Morgan, B.

2018-05-17

The use of an artificial bulk viscosity for shock stabilization is a common approach employed in turbulence simulations with high-order numerics. The effect of the artificial bulk viscosity is analyzed in the context of large eddy simulations by using as a test case simulations of linearly-forced compressible homogeneous turbulence (Petersen and Livescu, 2010 [12]). This case is unique in that it allows for the specification of a priori target values for total dissipation and ratio of solenoidal to dilatational dissipation. A comparison between these target values and the true predicted levels of dissipation is thus used to investigate the performancemore » of the artificial bulk viscosity. Results show that the artificial bulk viscosity is effective at achieving stable solutions, but also leads to large values of artificial dissipation that outweigh the physical dissipation caused by fluid viscosity. An alternate approach, which employs the artificial thermal conductivity only, shows that the dissipation of dilatational modes is entirely due to the fluid viscosity. However, this method leads to unwanted Gibbs oscillations around the shocklets. The use of shock sensors that further localize the artificial bulk viscosity did not reduce the amount of artificial dissipation introduced by the artificial bulk viscosity. Finally, an improved forcing function that explicitly accounts for the role of the artificial bulk viscosity in the budget of turbulent kinetic energy was explored.« less

Experimental constraints on the monazite-fluorapatite-allanite and xenotime-(Y,HREE)-rich fluorapatite-(Y,HREE)-rich epidote phase relations as a function of pressure, temperature, and Ca vs. Na activity in the fluid

NASA Astrophysics Data System (ADS)

Budzyń, Bartosz; Harlov, Daniel E.; Majka, Jarosław; Kozub, Gabriela A.

2014-05-01

Stability relations of monazite-fluorapatite-allanite and xenotime-(Y,HREE)-rich fluorapatite-(Y,HREE)-rich epidote are strongly dependent on pressure, temperature and fluid composition. The increased Ca bulk content expands stability field of allanite relative to monazite towards higher temperatures (Spear, 2010, Chem Geol 279, 55-62). It was also reported from amphibolite facies Alpine metapelites, that both temperature and bulk CaO/Na2O ratio control relative stabilities of allanite, monazite and xenotime (Janots et al., 2008, J Metam Geol 26, 5, 509-526). This study experimentally defines influence of pressure, temperature, high activity of Ca vs. Na in the fluid, and high vs. moderate bulk CaO/Na2O ratio on the relative stabilities of monazite-fluorapatite-allanite/REE-rich epidote and xenotime-(Y,HREE)-rich fluorapatite-(Y,HREE)-rich epidote. This work expands previous experimental study on monazite (Budzyń et al., 2011, Am Min 96, 1547-1567) to wide pressure-temperature range of 2-10 kbar and 450-750°C, utilizing most reactive fluids used in previous experiments. Experiments were performed using cold-seal autoclaves on a hydrothermal line (2-4 kbar runs) and piston-cylinder apparatus (6-10 kbar runs) over 4-16 days. Four sets of experiments, two for monazite and two for xenotime, were performed with 2M Ca(OH)2 and Na2Si2O5 + H2O fluids. The starting materials included inclusion-free crystals of monazite (pegmatite, Burnet County, TX, USA) or xenotime (pegmatite, Northwest Frontier Province, Pakistan) mixed with (1) labradorite (Ab37An60Kfs3) + K-feldspar + biotite + muscovite ± garnet + SiO2 + CaF2 + 2M Ca(OH)2 or (2) albite (Ab100) + K-feldspar + biotite + muscovite ± garnet + SiO2 + CaF2 + Na2Si2O5 + H2O. 20-35 mg of solids and 5 mg of fluid were loaded into 3x15 mm Au capsules and arc welded shut. The monazite alteration is observed in all runs. Newly formed REE-rich fluorapatite and/or britholite are stable in all experimental P-T range in the presence of both fluids. Alteration of monazite and subsequent formation of REE-rich epidote or allanite, REE-rich fluorapatite and britholite was promoted by high activity of Ca in the fluid, with high bulk CaO/Na2O ratio of ca. 11.5 in the system. In contrast, neither REE-rich epidote nor allanite does form in the presence of Na2Si2O5 + H2O fluid, with bulk CaO/Na2O ratio of ca. 1.0. Results indicating that stability field of allanite relative to monazite expands towards higher temperatures along with increased Ca bulk content are consistent with recent thermodynamic modeling of phase equilibria (Spear, 2010). Experiments also support natural observations from the amphibolite-facies Alpine metapelites regarding the influence of CaO/Na2O ratio in bulk content on the relative stabilities of monazite and REE-rich epidote (Janots et al., 2008). Alteration of xenotime is observed in all runs. (Y,HREE)-rich britholite or (Y,HREE)-rich fluorapatite always formed. In contrast to monazite experiments, (Y,HREE)-rich epidote formed only at 650°C and 8-10 kbar, in the presence of 2M Ca(OH)2. Results are partially consistent with natural observations showing that stability of (Y,HREE)-rich epidote is promoted by high Ca bulk content with high CaO/Na2O ratio (Janots et al., 2008). However, experimental results indicate that the relative stabilities of xenotime and (Y,HREE)-rich epidote are strongly controlled by pressure. Acknowledgements. The project was funded by the National Science Center of Poland, grant no. 2011/01/D/ST10/04588.

Performance of journal bearings with semi-compressible fluids

NASA Technical Reports Server (NTRS)

Carpino, M.; Peng, J.-P.

1991-01-01

Cryogenic fluids in isothermal rigid surface and foil type journal bearings can sometimes be treated as semicompressible fluids. In these applications, the fluid density is a function of the pressure. At low pressures, the fluids can change from a liquid to a saturated liquid-vapor phase. The performance of a rigid surface journal bearing with an idealized semicompressible fluid is discussed. Pressure solutions are based upon a Reynolds equation which includes the effects of a compressibility via the bulk modulus of the fluid. Results are contrasted with the performance of isothermal constant property incompressible fluids.

On the Induced Flow of an Electrically Conducting Liquid in a Rectangular Duct by Electric and Magnetic Fields of Finite Extent

NASA Technical Reports Server (NTRS)

Rossow, Vernon J.; Jones, William Prichard; Huerta, Robert H.

1961-01-01

Reported here are the results of a systematic study of a model of the direct-current electromagnetic pump. Of particular interest is the motion imparted to the electrically conducting fluid in the rectangular duct by the body forces that result from applied electric and magnetic fields. The purpose of the investigation is to associate the observed fluid motion with the characteristics of the electric and magnetic fields which cause them. The experiments were carried out with electromagnetic fields that moved a stream of copper sulphate solution through a clear plastic channel. Ink filaments injected into the stream ahead of the region where the fields were applied identify the motion of the fluid elements as they passed through the test channel. Several magnetic field configurations were employed with a two-dimensional electric current distribution in order to study and identify the magnitude of some of the effects on the fluid motion brought about by nonuniformities in the electromagnetic fields. A theoretical analysis was used to guide and evaluate the identification of the several fluid motions observed. The agreement of the experimental data with the theoretical predictions is satisfactory. It is found that sizable variations in the velocity profile and pressure head of the output stream are produced by the shape of the electric and magnetic fields.

Process for off-gas particulate removal and apparatus therefor

DOEpatents

Carl, D.E.

1997-10-21

In the event of a breach in the off-gas line of a melter operation requiring closure of the line, a secondary vessel vent line is provided with a particulate collector utilizing atomization for removal of large particulates from the off-gas. The collector receives the gas containing particulates and directs a portion of the gas through outer and inner annular channels. The collector further receives a fluid, such as water, which is directed through the outer channel together with a second portion of the particulate-laden gas. The outer and inner channels have respective ring-like termination apertures concentrically disposed adjacent one another on the outer edge of the downstream side of the particulate collector. Each of the outer and inner channels curves outwardly away from the collector`s centerline in proceeding toward the downstream side of the collector. Gas flow in the outer channel maintains the fluid on the channel`s wall in the form of a ``wavy film,`` while the gas stream from the inner channel shears the fluid film as it exits the outer channel in reducing the fluid to small droplets. Droplets formed by the collector capture particulates in the gas stream by one of three mechanisms: impaction, interception or Brownian diffusion in removing the particulates. The particulate-laden droplets are removed from the fluid stream by a vessel vent condenser or mist eliminator. 4 figs.

Cytoskeletal Dynamics and Fluid Flow in Drosophila Oocytes

NASA Astrophysics Data System (ADS)

de Canio, Gabriele; Goldstein, Raymond; Lauga, Eric

2015-11-01

The biological world includes a broad range of phenomena in which transport in a fluid plays a central role. Among these is the fundamental issue of cell polarity arising during development, studied historically using the model organism Drosophila melanogaster. The polarity of the oocyte is known to be induced by the translocation of mRNAs by kinesin motor proteins along a dense microtubule cytoskeleton, a process which also induces cytoplasmic streaming. Recent experimental observations have revealed the remarkable fluid-structure interactions that occur as the streaming flows back-react on the microtubules. In this work we use a combination of theory and simulations to address the interplay between the fluid flow and the configuration of cytoskeletal filaments leading to the directed motion inside the oocyte. We show in particular that the mechanical coupling between the fluid motion and the orientation of the microtubules can lead to a transition to coherent motion within the oocyte, as observed. Supported by EPSRC and ERC Advanced Investigator Grant 247333.

AqSo_NaCl: Computer program to calculate p-T-V-x properties in the H2O-NaCl fluid system applied to fluid inclusion research and pore fluid calculation

NASA Astrophysics Data System (ADS)

Bakker, Ronald J.

2018-06-01

The program AqSo_NaCl has been developed to calculate pressure - molar volume - temperature - composition (p-V-T-x) properties, enthalpy, and heat capacity of the binary H2O-NaCl system. The algorithms are designed in BASIC within the Xojo programming environment, and can be operated as stand-alone project with Macintosh-, Windows-, and Unix-based operating systems. A series of ten self-instructive interfaces (modules) are developed to calculate fluid inclusion properties and pore fluid properties. The modules may be used to calculate properties of pure NaCl, the halite-liquidus, the halite-vapourus, dew-point and bubble-point curves (liquid-vapour), critical point, and SLV solid-liquid-vapour curves at temperatures above 0.1 °C (with halite) and below 0.1 °C (with ice or hydrohalite). Isochores of homogeneous fluids and unmixed fluids in a closed system can be calculated and exported to a.txt file. Isochores calculated for fluid inclusions can be corrected according to the volumetric properties of quartz. Microthermometric data, i.e. dissolution temperatures and homogenization temperatures, can be used to calculated bulk fluid properties of fluid inclusions. Alternatively, in the absence of total homogenization temperature the volume fraction of the liquid phase in fluid inclusions can be used to obtain bulk properties.

40 CFR 63.166 - Standards: Sampling connection systems.

Code of Federal Regulations, 2012 CFR

2012-07-01

... fluid to a process; or (3) Be designed and operated to capture and transport the purged process fluid to a control device that complies with the requirements of § 63.172 of this subpart; or (4) Collect... of subpart G of this part applicable to group 1 wastewater streams. If the purged process fluid does...

40 CFR 63.166 - Standards: Sampling connection systems.

Code of Federal Regulations, 2014 CFR

2014-07-01

... fluid to a process; or (3) Be designed and operated to capture and transport the purged process fluid to a control device that complies with the requirements of § 63.172 of this subpart; or (4) Collect... of subpart G of this part applicable to group 1 wastewater streams. If the purged process fluid does...

Numerical study of fluid motion in bioreactor with two mixers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zheleva, I., E-mail: izheleva@uni-ruse.bg; Lecheva, A., E-mail: alecheva@uni-ruse.bg

2015-10-28

Numerical study of hydrodynamic laminar behavior of a viscous fluid in bioreactor with multiple mixers is provided in the present paper. The reactor is equipped with two disk impellers. The fluid motion is studied in stream function-vorticity formulation. The calculations are made by a computer program, written in MATLAB. The fluid structure is described and numerical results are graphically presented and commented.

Bulk properties and near-critical behaviour of SiO2 fluid

NASA Astrophysics Data System (ADS)

Green, Eleanor C. R.; Artacho, Emilio; Connolly, James A. D.

2018-06-01

Rocky planets and satellites form through impact and accretion processes that often involve silicate fluids at extreme temperatures. First-principles molecular dynamics (FPMD) simulations have been used to investigate the bulk thermodynamic properties of SiO2 fluid at high temperatures (4000-6000 K) and low densities (500-2240 kg m-3), conditions which are relevant to protoplanetary disc condensation. Liquid SiO2 is highly networked at the upper end of this density range, but depolymerises with increasing temperature and volume, in a process characterised by the formation of oxygen-oxygen (Odbnd O) pairs. The onset of vaporisation is closely associated with the depolymerisation process, and is likely to be non-stoichiometric at high temperature, initiated via the exsolution of O2 molecules to leave a Si-enriched fluid. By 6000 K the simulated fluid is supercritical. A large anomaly in the constant-volume heat capacity occurs near the critical temperature. We present tabulated thermodynamic properties for silica fluid that reconcile observations from FPMD simulations with current knowledge of the SiO2 melting curve and experimental Hugoniot curves.

Computational Fluid Dynamics (CFD) simulations of a Heisenberg Vortex Tube

NASA Astrophysics Data System (ADS)

Bunge, Carl; Sitaraman, Hariswaran; Leachman, Jake

2017-11-01

A 3D Computational Fluid Dynamics (CFD) simulation of a Heisenberg Vortex Tube (HVT) is performed to estimate cooling potential with cryogenic hydrogen. The main mechanism driving operation of the vortex tube is the use of fluid power for enthalpy streaming in a highly turbulent swirl in a dual-outlet tube. This enthalpy streaming creates a temperature separation between the outer and inner regions of the flow. Use of a catalyst on the peripheral wall of the centrifuge enables endothermic conversion of para-ortho hydrogen to aid primary cooling. A κ- ɛ turbulence model is used with a cryogenic, non-ideal equation of state, and para-orthohydrogen species evolution. The simulations are validated with experiments and strategies for parametric optimization of this device are presented.

A coin vibrational motor swimming at low Reynolds number

NASA Astrophysics Data System (ADS)

Quillen, Alice C.; Askari, Hesam; Kelley, Douglas H.; Friedmann, Tamar; Oakes, Patrick W.

2016-12-01

Low-cost coin vibrational motors, used in haptic feedback, exhibit rotational internal motion inside a rigid case. Because the motor case motion exhibits rotational symmetry, when placed into a fluid such as glycerin, the motor does not swim even though its oscillatory motions induce steady streaming in the fluid. However, a piece of rubber foam stuck to the curved case and giving the motor neutral buoyancy also breaks the rotational symmetry allowing it to swim. We measured a 1 cm diameter coin vibrational motor swimming in glycerin at a speed of a body length in 3 seconds or at 3 mm/s. The swim speed puts the vibrational motor in a low Reynolds number regime similar to bacterial motility, but because of the oscillations of the motor it is not analogous to biological organisms. Rather the swimming vibrational motor may inspire small inexpensive robotic swimmers that are robust as they contain no external moving parts. A time dependent Stokes equation planar sheet model suggests that the swim speed depends on a steady streaming velocity V stream Re s 1/2 U 0 where U 0 is the velocity of surface oscillations, and streaming Reynolds number Re s = U 0 2 /( ων) for motor angular frequency ω and fluid kinematic viscosity ν.

A perspective on stream-catchment connections

USGS Publications Warehouse

Bencala, Kenneth E.

1993-01-01

Ecological study of the hyporheic zone is leading to recognition of a need for additional hydrologic understanding. Some of this understanding can be obtained by viewing the hyporheic zone as a succession of isolated boxes adjacent to the stream. Further understanding, particularly relevant to catchment-scale ecology, may come from studies focussed on the fluid mechanics of the flow-path connections between streams and their catchments.

Dynamic behavior of microscale particles controlled by standing bulk acoustic waves

DOE Office of Scientific and Technical Information (OSTI.GOV)

Greenhall, J.; Raeymaekers, B., E-mail: bart.raeymaekers@utah.edu; Guevara Vasquez, F.

2014-10-06

We analyze the dynamic behavior of a spherical microparticle submerged in a fluid medium, driven to the node of a standing bulk acoustic wave created by two opposing transducers. We derive the dynamics of the fluid-particle system taking into account the acoustic radiation force and the time-dependent and time-independent drag force acting on the particle. Using this dynamic model, we characterize the transient and steady-state behavior of the fluid-particle system as a function of the particle and fluid properties and the transducer operating parameters. The results show that the settling time and percent overshoot of the particle trajectory are dependentmore » on the ratio of the acoustic radiation force and time-independent damping force. In addition, we show that the particle oscillates around the node of the standing wave with an amplitude that depends on the ratio of the time-dependent drag forces and the particle inertia.« less

The surface diffusion coefficient for an arbitrarily curved fluid-fluid interface. (I). General expression

NASA Astrophysics Data System (ADS)

M. C. Sagis, Leonard

2001-03-01

In this paper, we develop a theory for the calculation of the surface diffusion coefficient for an arbitrarily curved fluid-fluid interface. The theory is valid for systems in hydrodynamic equilibrium, with zero mass-averaged velocities in the bulk and interfacial regions. We restrict our attention to systems with isotropic bulk phases, and an interfacial region that is isotropic in the plane parallel to the dividing surface. The dividing surface is assumed to be a simple interface, without memory effects or yield stresses. We derive an expression for the surface diffusion coefficient in terms of two parameters of the interfacial region: the coefficient for plane-parallel diffusion D (AB)aa(ξ) , and the driving force d(B)I||(ξ) . This driving force is the parallel component of the driving force for diffusion in the interfacial region. We derive an expression for this driving force using the entropy balance.

Formulation and evaluation of C-Ether fluids as lubricants useful to 260 C. [air breathing engines

NASA Technical Reports Server (NTRS)

Clark, F. S.; Miller, D. R.

1980-01-01

Three base stocks were evaluated in bench and bearing tests to determine their suitability for use at bulk oil temperatures (BOT) from -40 C to +260 C. A polyol ester gave good bearing tests at a bulk temperature of 218 C, but only a partially successful run at 274 C. These results bracket the fluid's maximum operating temperature between these values. An extensive screening program selected lubrication additives for a C-ether (modified polyphenyl ether) base stock. One formulation lubricated a bearing for 111 hours at 274 C (BOT), but this fluid gave many deposit related problems. Other C-ether blends produced cage wear or fatigue failures. Studies of a third fluid, a C-ether/disiloxane blend, consisted of bench oxidation and lubrication tests. These showed that some additives react differently in the blend than in pure C-ethers.

Nonlinear viscosity in brane-world cosmology with a Gauss–Bonnet term

NASA Astrophysics Data System (ADS)

Debnath, P. S.; Beesham, A.; Paul, B. C.

2018-06-01

Cosmological solutions are obtained with nonlinear bulk viscous cosmological fluid in the Randall–Sundrum type II (RS) brane-world model with or without Gauss–Bonnet (GB) terms. To describe such a viscous fluid, we consider the nonlinear transport equation which may be used far from equilibrium during inflation or reheating. Cosmological models are explored for both (i) power law and (ii) exponential evolution of the early universe in the presence of an imperfect fluid described by the non-linear Israel and Stewart theory (nIS). We obtain analytic solutions and the complex field equations are also analyzed numerically to study the evolution of the universe. The stability analysis of the equilibrium points of the dynamical system associated with the evolution of the nonlinear bulk viscous fluid in the RS Brane in the presence (or absence) of a GB term are also studied.

Destabilizing effect of time-dependent oblique magnetic field on magnetic fluids streaming in porous media.

PubMed

El-Dib, Yusry O; Ghaly, Ahmed Y

2004-01-01

The present work studies Kelvin-Helmholtz waves propagating between two magnetic fluids. The system is composed of two semi-infinite magnetic fluids streaming throughout porous media. The system is influenced by an oblique magnetic field. The solution of the linearized equations of motion under the boundary conditions leads to deriving the Mathieu equation governing the interfacial displacement and having complex coefficients. The stability criteria are discussed theoretically and numerically, from which stability diagrams are obtained. Regions of stability and instability are identified for the magnetic fields versus the wavenumber. It is found that the increase of the fluid density ratio, the fluid velocity ratio, the upper viscosity, and the lower porous permeability play a stabilizing role in the stability behavior in the presence of an oscillating vertical magnetic field or in the presence of an oscillating tangential magnetic field. The increase of the fluid viscosity plays a stabilizing role and can be used to retard the destabilizing influence for the vertical magnetic field. Dual roles are observed for the fluid velocity in the stability criteria. It is found that the field frequency plays against the constant part for the magnetic field.

Inertial migration of elastic particles in a pressure-driven power-law fluid

NASA Astrophysics Data System (ADS)

Bowie, Samuel; Alexeev, Alexander

2016-11-01

Using three-dimensional computer simulations, we study the cross-stream migration of deformable particles in a channel filled with a non-Newtonian fluid driven by a pressure gradient. Our numerical approach integrates lattice Boltzmann method and lattice spring method in order to model fluid structural interactions of the elastic particle and the surrounding power fluid in the channel. The particles are modeled as elastic shells filled with a viscous fluid that are initially spherical. We focus on the regimes where the inertial effects cannot be neglected and cause cross-stream drift of particles. We probe the flow with different power law indexes including both the shear thickening and thinning fluids. We also examine migration of particles of with different elasticity and relative size. To isolate the non-Newtonian effects on particle migration, we compare the results with the inertial migration results found in the case where the channel is filled with a simple Newtonian fluid. The results can be useful for applications requiring high throughput separation, sorting, and focusing of both synthetic particles and biological cells in microfluidic devices. Financial support provided by National Science Foundation (NSF) Grant No. CMMI1538161.

Analysis of sources of bulk conductivity change in saturated silica sand after unbuffered TCE oxidation by permanganate.

PubMed

Hort, Ryan D; Revil, André; Munakata-Marr, Junko

2014-09-01

Time lapse resistivity surveys could potentially improve monitoring of permanganate-based in situ chemical oxidation (ISCO) of organic contaminants such as trichloroethene (TCE) by tracking changes in subsurface conductivity that result from injection of permanganate and oxidation of the contaminant. Bulk conductivity and pore fluid conductivity changes during unbuffered TCE oxidation using permanganate are examined through laboratory measurements and conductivity modeling using PHREEQC in fluid samples and porous media samples containing silica sand. In fluid samples, oxidation of one TCE molecule produces three chloride ions and one proton, resulting in an increase in fluid electrical conductivity despite the loss of two permanganate ions in the reaction. However, in saturated sand samples in which up to 8mM TCE was oxidized, at least 94% of the fluid conductivity associated with the presence of protons was removed within 3h of sand contact, most likely through protonation of silanol groups found on the surface of the sand grains. Minor conductivity effects most likely associated with pH-dependent reductive dissolution of manganese dioxide were also observed but not accounted for in pore-fluid conductivity modeling. Unaccounted conductivity effects resulted in an under-calculation of post-reaction pore fluid conductivity of 2.1% to 5.5%. Although small increases in the porous media formation factor resulting from precipitation of manganese dioxide were detected (about 3%), these increases could not be confirmed to be statistically significant. Both injection of permanganate and oxidation of TCE cause increases in bulk conductivity that would be detectable through time-lapse resistivity surveys in field conditions. Copyright © 2014 Elsevier B.V. All rights reserved.

Conductivity measurements on H 2O-bearing CO 2-rich fluids

DOE PAGES

Capobianco, Ryan M.; Miroslaw S. Gruszkiewicz; Bodnar, Robert J.; ...

2014-09-10

Recent studies report rapid corrosion of metals and carbonation of minerals in contact with carbon dioxide containing trace amounts of dissolved water. One explanation for this behavior is that addition of small amounts of H 2O to CO 2 leads to significant ionization within the fluid, thus promoting reactions at the fluid-solid interface analogous to corrosion associated with aqueous fluids. The extent of ionization in the bulk CO 2 fluid was determined using a flow-through conductivity cell capable of detecting very low conductivities. Experiments were conducted from 298 to 473 K and 7.39 to 20 MPa with H 2O concentrationsmore » up to ~1600 ppmw (xH 2O ≈ 3.9 x 10 -3), corresponding to the H 2O solubility limit in liquid CO 2 at ambient temperature. All solutions showed conductivities <10 nS/cm, indicating that the solutions were essentially ion-free. Furthermore, this observation suggests that the observed corrosion and carbonation reactions are not the result of ionization in CO 2-rich bulk phase, but does not preclude ionization in the fluid at the fluid-solid interface.« less

Linear nozzle with tailored gas plumes

DOEpatents

Leon, David D.; Kozarek, Robert L.; Mansour, Adel; Chigier, Norman

2001-01-01

There is claimed a method for depositing fluid material from a linear nozzle in a substantially uniform manner across and along a surface. The method includes directing gaseous medium through said nozzle to provide a gaseous stream at the nozzle exit that entrains fluid material supplied to the nozzle, said gaseous stream being provided with a velocity profile across the nozzle width that compensates for the gaseous medium's tendency to assume an axisymmetric configuration after leaving the nozzle and before reaching the surface. There is also claimed a nozzle divided into respective side-by-side zones, or preferably chambers, through which a gaseous stream can be delivered in various velocity profiles across the width of said nozzle to compensate for the tendency of this gaseous medium to assume an axisymmetric configuration.

Linear nozzle with tailored gas plumes and method

DOEpatents

Leon, David D.; Kozarek, Robert L.; Mansour, Adel; Chigier, Norman

1999-01-01

There is claimed a method for depositing fluid material from a linear nozzle in a substantially uniform manner across and along a surface. The method includes directing gaseous medium through said nozzle to provide a gaseous stream at the nozzle exit that entrains fluid material supplied to the nozzle, said gaseous stream being provided with a velocity profile across the nozzle width that compensates for the gaseous medium's tendency to assume an axisymmetric configuration after leaving the nozzle and before reaching the surface. There is also claimed a nozzle divided into respective side-by-side zones, or preferably chambers, through which a gaseous stream can be delivered in various velocity profiles across the width of said nozzle to compensate for the tendency of this gaseous medium to assume an axisymmetric configuration.

Linear nozzle with tailored gas plumes

DOEpatents

Kozarek, Robert L.; Straub, William D.; Fischer, Joern E.; Leon, David D.

2003-01-01

There is claimed a method for depositing fluid material from a linear nozzle in a substantially uniform manner across and along a surface. The method includes directing gaseous medium through said nozzle to provide a gaseous stream at the nozzle exit that entrains fluid material supplied to the nozzle, said gaseous stream being provided with a velocity profile across the nozzle width that compensates for the gaseous medium's tendency to assume an axisymmetric configuration after leaving the nozzle and before reaching the surface. There is also claimed a nozzle divided into respective side-by-side zones, or preferably chambers, through which a gaseous stream can be delivered in various velocity profiles across the width of said nozzle to compensate for the tendency of this gaseous medium to assume an axisymmetric configuration.

Young-Laplace equation for liquid crystal interfaces

NASA Astrophysics Data System (ADS)

Rey, Alejandro D.

2000-12-01

This letter uses the classical theories of liquid crystal physics to derive the Young-Laplace equation of capillary hydrostatics for interfaces between viscous isotropic (I) fluids and nematic liquid crystals (NLC's), and establishes the existence of four energy contributions to pressure jumps across these unusual anisotropic interfaces. It is shown that in addition to the usual curvature contribution, bulk and surface gradient elasticity, elastic stress, and anchoring energy contribute to pressure differentials across the interface. The magnitude of the effect is proportional to the elastic moduli of the NLC, and to the bulk and surface orientation gradients that may be present in the nematic phase. In contrast to the planar interface between isotropic fluids, flat liquid crystal interfaces support pressure jumps if elastic stresses, bulk and surface gradient energy, and/or anchoring energies are finite.

Apparatus and method for excluding gas from a liquid

DOEpatents

Murphy, Jr., Robert J.

1985-01-01

The present invention is directed to an apparatus and method for preventing diffusion of a gas under high pressure into the bulk of a liquid filling a substantially closed chamber. This apparatus and method is particularly useful in connection with test devices for testing fluid characteristics under harsh conditions of extremely high pressure and high temperature. These devices typically pressurize the liquid by placing the liquid in pressure and fluid communication with a high pressure inert gas. The apparatus and method of the present invention prevent diffusion of the pressurizing gas into the bulk of the test liquid by decreasing the chamber volume at a rate sufficient to maintain the bulk of the liquid free of absorbed or dissolved gas by expelling that portion of the liquid which is contaminated by the pressurizing gas.

Advanced computational multi-fluid dynamics: a new model for understanding electrokinetic phenomena in porous media

NASA Astrophysics Data System (ADS)

Gulamali, M. Y.; Saunders, J. H.; Jackson, M. D.; Pain, C. C.

2009-04-01

We present results from a new computational multi-fluid dynamics code, designed to model the transport of heat, mass and chemical species during flow of single or multiple immiscible fluid phases through porous media, including gravitational effects and compressibility. The model also captures the electrical phenomena which may arise through electrokinetic, electrochemical and electrothermal coupling. Building on the advanced computational technology of the Imperial College Ocean Model, this new development leads the way towards a complex multiphase code using arbitrary unstructured and adaptive meshes, and domains decomposed to run in parallel over a cluster of workstations or a dedicated parallel computer. These facilities will allow efficient and accurate modelling of multiphase flows which capture large- and small-scale transport phenomena, while preserving the important geology and/or surface topology to make the results physically meaningful and realistic. Applications include modelling of contaminant transport in aquifers, multiphase flow during hydrocarbon production, migration of carbon dioxide during sequestration, and evaluation of the design and safety of nuclear reactors. Simulations of the streaming potential resulting from multiphase flow in laboratory- and field-scale models demonstrate that streaming potential signals originate at fluid fronts, and at geologic boundaries where fluid saturation changes. This suggests that downhole measurements of streaming potential may be used to inform production strategies in oil and gas reservoirs. As water encroaches on an oil production well, the streaming-potential signal associated with the water front encompasses the well even when the front is up to 100 m away, so the potential measured at the well starts to change significantly relative to a distant reference electrode. Variations in the geometry of the encroaching water front could be characterized using an array of electrodes positioned along the well, but a good understanding of the local reservoir geology will be required to identify signals caused by the front. The streaming potential measured at a well will be maximized in low-permeability reservoirs produced at a high rate, and in thick reservoirs with low shale content.

Emergence of kinetic behavior in streaming ultracold neutral plasmas

DOE Office of Scientific and Technical Information (OSTI.GOV)

McQuillen, P.; Castro, J.; Bradshaw, S. J.

2015-04-15

We create streaming ultracold neutral plasmas by tailoring the photoionizing laser beam that creates the plasma. By varying the electron temperature, we control the relative velocity of the streaming populations, and, in conjunction with variation of the plasma density, this controls the ion collisionality of the colliding streams. Laser-induced fluorescence is used to map the spatially resolved density and velocity distribution function for the ions. We identify the lack of local thermal equilibrium and distinct populations of interpenetrating, counter-streaming ions as signatures of kinetic behavior. Experimental data are compared with results from a one-dimensional, two-fluid numerical simulation.

Supercritical (and Subcritical) Fluid Behavior and Modeling: Drops, Streams, Shear and Mixing Layers, Jets and Sprays

NASA Technical Reports Server (NTRS)

Bellan, J.

1999-01-01

A critical review of recent investigations in the real of supercritical (and subcritical) fluid behavior is presented with the goal of obtaining a perspective on the peculiarities of high pressure observations.

Isotope specific arbitrary material flow meter

DOEpatents

Barty, Christopher P. J.; Post, John C.; Jones, Edwin

2016-10-25

A laser-based mono-energetic gamma-ray source is used to provide non-destructive and non-intrusive, quantitative determination of the absolute amount of a specific isotope contained within pipe as part of a moving fluid or quasi-fluid material stream.

Method and apparatus for jet-assisted drilling or cutting

DOEpatents

Summers, David Archibold; Woelk, Klaus Hubert; Oglesby, Kenneth Doyle; Galecki, Grzegorz

2012-09-04

An abrasive cutting or drilling system, apparatus and method, which includes an upstream supercritical fluid and/or liquid carrier fluid, abrasive particles, a nozzle and a gaseous or low-density supercritical fluid exhaust abrasive stream. The nozzle includes a throat section and, optionally, a converging inlet section, a divergent discharge section, and a feed section.

Method and apparatus for jet-assisted drilling or cutting

DOEpatents

Summers, David Archibold; Woelk, Klaus Hubert; Oglesby, Kenneth Doyle; Galecki, Grzegorz

2013-07-02

An abrasive cutting or drilling system, apparatus and method, which includes an upstream supercritical fluid and/or liquid carrier fluid, abrasive particles, a nozzle and a gaseous or low-density supercritical fluid exhaust abrasive stream. The nozzle includes a throat section and, optionally, a converging inlet section, a divergent discharge section, and a feed section.

AN EXPERIMENTAL INVESTIGATION INTO THE EFFECT OF PROCESS CONDITIONS ON THE MASS CONCENTRATION OF CUTTING FLUID MIST IN TURNING. (R825370C057)

EPA Science Inventory

Cutting fluid mists that are generated during machining processes represent a significant waste stream as well as a health hazard to humans. Epidemiological studies have shown a link between worker exposure to cutting fluid mist and an increase in respiratory ailments and seve...

Gas powered fluid gun with recoil mitigation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grubelich, Mark C.; Yonas, Gerold

A gas powered fluid gun for propelling a stream or slug of a fluid at high velocity toward a target. Recoil mitigation is provided by a cavitating venturi that reduces or eliminates the associated recoil forces, with minimal or no backwash. By launching a quantity of water in the opposite direction, net momentum forces are reduced or eliminated.

Fluid property measurements study

NASA Technical Reports Server (NTRS)

Devaney, W. E.

1976-01-01

Fluid properties of refrigerant-21 were investigated at temperatures from the freezing point to 423 Kelvin and at pressures to 1.38 x 10 to the 8th power N/sq m (20,000 psia). The fluid properties included were: density, vapor pressure, viscosity, specific heat, thermal conductivity, thermal expansion coefficient, freezing point and bulk modulus. Tables of smooth values are reported.

Quantification of the multi-streaming effect in redshift space distortion

NASA Astrophysics Data System (ADS)

Zheng, Yi; Zhang, Pengjie; Oh, Minji

2017-05-01

Both multi-streaming (random motion) and bulk motion cause the Finger-of-God (FoG) effect in redshift space distortion (RSD). We apply a direct measurement of the multi-streaming effect in RSD from simulations, proving that it induces an additional, non-negligible FoG damping to the redshift space density power spectrum. We show that, including the multi-streaming effect, the RSD modelling is significantly improved. We also provide a theoretical explanation based on halo model for the measured effect, including a fitting formula with one to two free parameters. The improved understanding of FoG helps break the fσ8-σv degeneracy in RSD cosmology, and has the potential of significantly improving cosmological constraints.

Arsenic in rocks and stream sediments of the central Appalachian Basin, Kentucky

USGS Publications Warehouse

Tuttle, Michele L.W.; Goldhaber, Martin B.; Ruppert, Leslie F.; Hower, James C.

2002-01-01

Arsenic (As) enrichment in coal and stream sediments has been documented in the southern Appalachian basin (see Goldhaber and others, submitted) and is attributed to interaction of rocks and coal with metamorphic fluids generated during the Allegheny Orogeny (late Paleozoic). Similarly derived fluids are expected to affect the coal and in the Kentucky Appalachian Basin to the north as well. In addition, similar processes may have influenced the Devonian oil shale on the western margin of the basin. The major goals of this study are to determine the effect such fluids had on rocks in the Kentucky Appalachian basin (fig. 1), and to understand the geochemical processes that control trace-metal source, residence, and mobility within the basin. This report includes data presented in a poster at the USGS workshop on arsenic (February 21 and 22, 2001), new NURE stream sediment data3 , and field data from a trip in April 2001. Although data for major and minor elements and all detectable trace metals are reported in the Appendices, the narrative of this report primarily focuses on arsenic.

Pattern-formation under acoustic driving forces

NASA Astrophysics Data System (ADS)

Valverde, Jose Manuel

2015-07-01

Chemical and metallurgical processes enhanced by high intensity acoustic waves, thermoacoustic engines and refrigerators, fuel rods in nuclear reactors, heat exchanger tubes, offshore and vibrating structures, solar thermal collectors, acoustic levitators, microfluidic devices, cycling, musical acoustics, blood flow through veins/arteries, hearing in the mammalian ear, carbon nanotube loudspeakers, etc. The evolution of a myriad of processes involving the oscillation of viscous fluids in the presence of solid boundaries is up to a certain extent influenced by acoustic streaming. In addition to the sound field, viscous energy dissipation at the fluid-solid boundary causes a time-independent fluid circulation, which can lead to a significant enhancement of heat, mass and momentum transfer at large oscillation amplitudes. A particularly relevant phenomenon that can be notably affected by acoustic streaming is the promotion of sound waves by temperature gradients or viceversa (thermoacoustics), which is at the basis of potentially efficient and environmental friendly engines and refrigerators that have attracted a renewed interest in the last years. In the present manuscript, historical developments and the underlying basic physics behind acoustic streaming and thermoacoustics are reviewed from an unifying perspective.

The standard mean-field treatment of inter-particle attraction in classical DFT is better than one might expect

NASA Astrophysics Data System (ADS)

Archer, Andrew J.; Chacko, Blesson; Evans, Robert

2017-07-01

In classical density functional theory (DFT), the part of the Helmholtz free energy functional arising from attractive inter-particle interactions is often treated in a mean-field or van der Waals approximation. On the face of it, this is a somewhat crude treatment as the resulting functional generates the simple random phase approximation (RPA) for the bulk fluid pair direct correlation function. We explain why using standard mean-field DFT to describe inhomogeneous fluid structure and thermodynamics is more accurate than one might expect based on this observation. By considering the pair correlation function g(x) and structure factor S(k) of a one-dimensional model fluid, for which exact results are available, we show that the mean-field DFT, employed within the test-particle procedure, yields results much superior to those from the RPA closure of the bulk Ornstein-Zernike equation. We argue that one should not judge the quality of a DFT based solely on the approximation it generates for the bulk pair direct correlation function.

Annular recuperator design

DOEpatents

Kang, Yungmo

2005-10-04

An annular heat recuperator is formed with alternating hot and cold cells to separate counter-flowing hot and cold fluid streams. Each cold cell has a fluid inlet formed in the inner diameter of the recuperator near one axial end, and a fluid outlet formed in the outer diameter of the recuperator near the other axial end to evenly distribute fluid mass flow throughout the cell. Cold cells may be joined with the outlet of one cell fluidly connected to the inlet of an adjacent downstream cell to form multi-stage cells.

System for adding sulfur to a fuel cell stack system for improved fuel cell stability

DOEpatents

Mukerjee, Subhasish; Haltiner, Jr., Karl J; Weissman, Jeffrey G

2013-08-13

A system for adding sulfur to a reformate stream feeding a fuel cell stack, having a sulfur source for providing sulfur to the reformate stream and a metering device in fluid connection with the sulfur source and the reformate stream. The metering device injects sulfur from the sulfur source to the reformate stream at a predetermined rate, thereby providing a conditioned reformate stream to the fuel cell stack. The system provides a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

LABORATORY AND FIELD RESULTS LINKING HIGH BULK CONDUCTIVITIES TO THE MICROBIAL DEGRADATION OF PETROLEUM HYDROCARBONS

EPA Science Inventory

Diesel contaminated layer (i.e. 32-45 cm) was the most geoelectrically conductive and showed the peak microbial activity. Below the saturated zone microbial enhanced mineral weathering increases the ionic concentration of pore fluids, leading to increased bulk electrical conducit...

21 CFR 610.12 - Sterility.

Code of Federal Regulations, 2011 CFR

2011-04-01

... container material. (a) The test. Bulk material shall be tested separately from final container material and material from each final container shall be tested in individual test vessels as follows: (1) Using Fluid Thioglycollate Medium—(i) Bulk and final container material. The volume of product, as required by paragraph (d...

Fluid flow in solidifying monotectic alloys

NASA Technical Reports Server (NTRS)

Ecker, A.; Frazier, D. O.; Alexander, J. Iwan D.

1989-01-01

Use of a two-wavelength holographic technique results in a simultaneous determination of temperature and composition profiles during directional solidification in a system with a miscibility gap. The relationships among fluid flow, phase separation, and mass transport during the solidification of the monotectic alloy are discussed. The primary sources of fluid motion in this system are buoyancy and thermocapillary forces. These forces act together when phase separation results in the formation of droplets (this occurs at the solid-liquid interface and in the bulk melt). In the absence of phase separation, buoyancy results from density gradients related to temperature and compositional gradients in the single-phase bulk melt. The effects of buoyancy are especially evident in association with water- or ethanol-rich volumes created at the solid-liquid growth interface.

Thermodynamics of fluid conduction through hydrophobic channel of carbon nanotubes: The exciting force for filling of nanotubes with polar and nonpolar fluids

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sahu, Pooja; Ali, Sk. M., E-mail: musharaf@barc.gov.in; Shenoy, K. T.

2015-02-21

Thermodynamic properties of the fluid in the hydrophobic pores of nanotubes are known to be different not only from the bulk phase but also from other conventional confinements. Here, we use a recently developed theoretical scheme of “two phase thermodynamic (2PT)” model to understand the driving forces inclined to spontaneous filling of carbon nanotubes (CNTs) with polar (water) and nonpolar (methane) fluids. The CNT confinement is found to be energetically favorable for both water and methane, leading to their spontaneous filling inside CNT(6,6). For both the systems, the free energy of transfer from bulk to CNT confinement is favored bymore » the increased entropy (TΔS), i.e., increased translational entropy and increased rotational entropy, which were found to be sufficiently high to conquer the unfavorable increase in enthalpy (ΔE) when they are transferred inside CNT. To the best of our knowledge, this is the first time when it has been established that the increase in translational entropy during confinement in CNT(6,6) is not unique to water-like H bonding fluid but is also observed in case of nonpolar fluids such as methane. The thermodynamic results are explained in terms of density, structural rigidity, and transport of fluid molecules inside CNT. The faster diffusion of methane over water in bulk phase is found to be reversed during the confinement in CNT(6,6). Studies reveal that though hydrogen bonding plays an important role in transport of water through CNT, but it is not the solitary driving factor, as the nonpolar fluids, which do not have any hydrogen bond formation capacity can go inside CNT and also can flow through it. The associated driving force for filling and transport of water and methane is enhanced translational and rotational entropies, which are attributed mainly by the strong correlation between confined fluid molecules and availability of more free space for rotation of molecule, i.e., lower density of fluid inside CNT due to their single file-like arrangement. To the best of our information, this is perhaps the first study of nonpolar fluid within CNT using 2PT method. Furthermore, the fast flow of polar fluid (water) over nonpolar fluid (methane) has been captured for the first time using molecular dynamic simulations.« less

Lossless droplet transfer of droplet-based microfluidic analysis

DOEpatents

Kelly, Ryan T [West Richland, WA; Tang, Keqi [Richland, WA; Page, Jason S [Kennewick, WA; Smith, Richard D [Richland, WA

2011-11-22

A transfer structure for droplet-based microfluidic analysis is characterized by a first conduit containing a first stream having at least one immiscible droplet of aqueous material and a second conduit containing a second stream comprising an aqueous fluid. The interface between the first conduit and the second conduit can define a plurality of apertures, wherein the apertures are sized to prevent exchange of the first and second streams between conduits while allowing lossless transfer of droplets from the first conduit to the second conduit through contact between the first and second streams.

Accurate bulk density determination of irregularly shaped translucent and opaque aerogels

NASA Astrophysics Data System (ADS)

Petkov, M. P.; Jones, S. M.

2016-05-01

We present a volumetric method for accurate determination of bulk density of aerogels, calculated from extrapolated weight of the dry pure solid and volume estimates based on the Archimedes' principle of volume displacement, using packed 100 μm-sized monodispersed glass spheres as a "quasi-fluid" media. Hard particle packing theory is invoked to demonstrate the reproducibility of the apparent density of the quasi-fluid. Accuracy rivaling that of the refractive index method is demonstrated for both translucent and opaque aerogels with different absorptive properties, as well as for aerogels with regular and irregular shapes.

Vibratory pumping of a free fluid stream

DOEpatents

Merrigan, M.A.; Woloshun, K.A.

1990-11-13

A vibratory fluid pump is described having a force generator for generating asymmetric periodic waves or oscillations connected to one end of one or more fluid conveyance means, such as filaments. The opposite ends of the filaments are connected to springs. Fluid introduced onto the filaments will traverse along the filaments according to the magnitude of the positive and negative excursions of the periodic waves or oscillations, and can be recovered from the filaments. 3 figs.

Bulk viscosity of molecular fluids

NASA Astrophysics Data System (ADS)

Jaeger, Frederike; Matar, Omar K.; Müller, Erich A.

2018-05-01

The bulk viscosity of molecular models of gases and liquids is determined by molecular simulations as a combination of a dilute gas contribution, arising due to the relaxation of internal degrees of freedom, and a configurational contribution, due to the presence of intermolecular interactions. The dilute gas contribution is evaluated using experimental data for the relaxation times of vibrational and rotational degrees of freedom. The configurational part is calculated using Green-Kubo relations for the fluctuations of the pressure tensor obtained from equilibrium microcanonical molecular dynamics simulations. As a benchmark, the Lennard-Jones fluid is studied. Both atomistic and coarse-grained force fields for water, CO2, and n-decane are considered and tested for their accuracy, and where possible, compared to experimental data. The dilute gas contribution to the bulk viscosity is seen to be significant only in the cases when intramolecular relaxation times are in the μs range, and for low vibrational wave numbers (<1000 cm-1); This explains the abnormally high values of bulk viscosity reported for CO2. In all other cases studied, the dilute gas contribution is negligible and the configurational contribution dominates the overall behavior. In particular, the configurational term is responsible for the enhancement of the bulk viscosity near the critical point.

Influence of a Large Free Stream Disturbance Level on Dynamics of a Jet in a Cross Flow

NASA Technical Reports Server (NTRS)

Foss, J. J.; Wark, C. E.

1983-01-01

An experiment to study the physical agents that are responsible for the jet turning into the streamwise direction, and the mixing of the jet and the cross stream fluid in the case of a jet in a cross flow is discussed.

Creation of high-energy electron tails by means of the modified two-stream instability

NASA Technical Reports Server (NTRS)

Tanaka, M.; Papadopoulos, K.

1983-01-01

Particle simulations of the modified two-stream instability demonstrate strong electron acceleration rather than bulk heating when the relative drift speed is below a critical speed Vc. A very interesting nonlinear mode transition and autoresonance acceleration process is observed which accelerates the electrons much above the phase speed of the linearly unstable modes. Simple criteria are presented that predict the value of Vc and the number density of the accelerated electrons.

Electrokinetic energy conversion efficiency of viscoelastic fluids in a polyelectrolyte-grafted nanochannel.

PubMed

Jian, Yongjun; Li, Fengqin; Liu, Yongbo; Chang, Long; Liu, Quansheng; Yang, Liangui

2017-08-01

In order to conduct extensive investigation of energy harvesting capabilities of nanofluidic devices, we provide analytical solutions for streaming potential and electrokinetic energy conversion (EKEC) efficiency through taking the combined consequences of soft nanochannel, a rigid nanochannel whose surface is covered by charged polyelectrolyte layer, and viscoelastic rheology into account. The viscoelasticity of the fluid is considered by employing the Maxwell constitutive model when the forcing frequency of an oscillatory driving pressure flow matches with the inverse of the relaxation time scale of a typical viscoelastic fluid. We compare the streaming potential and EKEC efficiency with those of a rigid nanochannel, having zeta potential equal to the electrostatic potential at the solid-polyelectrolyte interface of the soft nanochannels. Within the present selected parameter ranges, it is shown that the different peaks of maximal streaming potential and EKEC efficiency for the rigid nanochannel are larger than those for the soft nanochannel when forcing frequencies of the driving pressure gradient are close to resonating frequencies. However, more enhanced streaming potential and EKEC efficiency for a soft nanochannel can be found in most of the regions away from these resonant frequencies. Moreover, the influence of several dimensionless parameters on EKEC efficiency is discussed in detail. Finally, within the given parametric regions, the maximum efficiency at some resonant frequency obtained in present analysis is about 25%. Copyright © 2017 Elsevier B.V. All rights reserved.

Comparison of 74-MHz interplanetary scintillation and IMP 7 observations of the solar wind during 1973

NASA Technical Reports Server (NTRS)

Coles, W. A.; Harmon, J. K.; Lazarus, A. J.; Sullivan, J. D.

1978-01-01

Solar wind velocities measured by earth-orbiting spacecraft are compared with velocities determined from interplanetary scintillation (IPS) observations for 1973, a period when high-velocity streams were prevalent. The spacecraft and IPS velocities agree well in the mean and are highly correlated. No simple model for the distribution of enhanced turbulence within streams is sufficient to explain the velocity comparison results for the entire year. Although a simple proportionality between density fluctuation level and bulk density is consistent with IPS velocities for some periods, some streams appear to have enhanced turbulence in the high-velocity region, where the density is low.

Thermal analysis of turbulent flow of a supercritical fluid

NASA Technical Reports Server (NTRS)

Yamane, E.

1979-01-01

The influence of the large variation of thermodynamics and transport properties near the pseudocritical temperature on the heat transfer coefficient of supercritical fluid in turbulent flow was studied. The formation of the characteristics peak in the heat transfer coefficient vs. bulk temperature curve is described, and the necessity of the fluid element at pseudocritical temperature located in the buffer layer is discussed.

Molecular aspect ratio and anchoring strength effects in a confined Gay-Berne liquid crystal

NASA Astrophysics Data System (ADS)

Cañeda-Guzmán, E.; Moreno-Razo, J. A.; Díaz-Herrera, E.; Sambriski, E. J.

2014-04-01

Phase diagrams for Gay-Berne (GB) fluids were obtained from molecular dynamics simulations for GB(2, 5, 1, 2) (i.e. short mesogens) and GB(3, 5, 1, 2) (i.e. long mesogens), which yield isotropic, nematic, and smectic-B phases. The long-mesogen fluid also yields the smectic-A phase. Ordered phases of the long-mesogen fluid form at higher temperatures and lower densities when compared to those of the short-mesogen fluid. The effect of confinement under weak and strong substrate couplings in slab geometry was investigated. Compared to the bulk, the isotropic-nematic transition does not shift in temprature significantly for the weakly coupled substrate in either mesogen fluid. However, the strongly coupled substrate shifts the transition to lower temperature. Confinement induces marked stratification in the short-mesogen fluid. This effect diminishes with distance from the substrate, yielding bulk-like behaviour in the slab central region. Fluid stratification is very weak for the long-mesogen fluid, but the strongly coupled substrate induces 'smectisation', an ordering effect that decays with distance. Orientation of the fluid on the substrate depends on the mesogen. There is no preferred orientation in a plane parallel to the substrate for the weakly coupled case. In the strongly coupled case, the mesogen orientation mimics that of adjacent fluid layers. Planar anchoring is observed with a broad distribution of orientations in the weakly coupled case. In the strongly coupled case, the distribution leans toward planar orientations for the short-mesogen fluid, while a marginal preference for tilting persists in the long-mesogen fluid.

A three-dimensional model of co-rotating streams in the solar wind. 2: Hydrodynamic streams

NASA Technical Reports Server (NTRS)

Pizzo, V. J.

1979-01-01

Theoretical aspects of corotating solar wind dynamics on a global scale are explored by means of numerical simulations executed with a nonlinear, inviscid, adiabatic, single-fluid, three-dimensional (3-D) hydrodynamic formulation. A simple, hypothetical 3-D stream structure is defined on a source surface located at 35 solar radius and carefully documents its evolution to 1 AU under the influence of solar rotation. By manipulating the structure of this prototype configuration at the source surface, it is possible to elucidate the factors most strongly affecting stream evolution: (1) the intrinsic correlations among density, temperature, and velocity existing near the source; (2) the amplitude of the stream; (3) the longitudinal breadth of the stream; (4) the latitudinal breadth of the stream; and (5) the heliographic latitude of the centroid of the stream.

Role of dielectric constant in electrohydrodynamics of conducting fluids

NASA Technical Reports Server (NTRS)

Rhodes, Percy H.; Snyder, Robert S.; Roberts, Glyn O.

1992-01-01

Electrohydrodynamic (EHD) flows are driven by the interaction of an electric field with variations in electric conductivity or dielectric constant. In reported EHD experiments on the deformation of drops of immiscible dielectric fluids, the role of conductivity has tended to overshadow the role of dielectric constant. Often, large conductivity contrasts were convenient because the conductivities of the dielectric fluid were relatively uncertain. As a result, the observed effects were always qualitatively the same as if there had been no contrast in dielectric constant. Our early experiments studying the EHC deformations of cylindrical streams readily showed the conductivity effect but the dielectric constant effect was not discernible. We have modified our flow chamber and improved our method of observation and can now see an unequivocal dielectric constant effect which is in agreement with the prior theory. In this paper we first give a brief description of the physics of charge buildup at the interface of an immersed spherical drop or flowing cylindrical sample stream and then show how these charge distributions lead to interface distortions and accompanying viscous flows which constitute EHD. We next review theory and experiment describing the deformation of spherical drops. We show that in the reported drop deformation experiments, the contrast in dielectric constant was never sufficient to reverse the deformation due to the conductivity contrast. We review our work describing the deformation of a cylindrical stream of one fluid flowing in a parallel flow of another, and we compare the deformation equations with those for spherical drops. Finally, we show a definite experimental dielectric constant effect for cylindrical stream of aqueous polystyrene latex suspension. The dielectric constant varies with the frequency of the imposed electric field, and the associated EHD flow change is very apparent.

Active fluids at circular boundaries: swim pressure and anomalous droplet ripening.

PubMed

Jamali, Tayeb; Naji, Ali

2018-06-13

We investigate the swim pressure exerted by non-chiral and chiral active particles on convex or concave circular boundaries. Active particles are modeled as non-interacting and non-aligning self-propelled Brownian particles. The convex and concave circular boundaries are used to model a fixed inclusion immersed in an active bath and a cavity (or container) enclosing the active particles, respectively. We first present a detailed analysis of the role of convex versus concave boundary curvature and of the chirality of active particles in their spatial distribution, chirality-induced currents, and the swim pressure they exert on the bounding surfaces. The results will then be used to predict the mechanical equilibria of suspended fluid enclosures (generically referred to as 'droplets') in a bulk with active particles being present either inside the bulk fluid or within the suspended droplets. We show that, while droplets containing active particles behave in accordance with standard capillary paradigms when suspended in a normal bulk, those containing a normal fluid exhibit anomalous behaviors when suspended in an active bulk. In the latter case, the excess swim pressure results in non-monotonic dependence of the inside droplet pressure on the droplet radius; hence, revealing an anomalous regime of behavior beyond a threshold radius, in which the inside droplet pressure increases upon increasing the droplet size. Furthermore, for two interconnected droplets, mechanical equilibrium can occur also when the droplets have different sizes. We thus identify a regime of anomalous droplet ripening, where two unequal-sized droplets can reach a final state of equal size upon interconnection, in stark contrast with the standard Ostwald ripening phenomenon, implying shrinkage of the smaller droplet in favor of the larger one.

Apparatus for rapid measurement of aerosol bulk chemical composition

DOEpatents

Lee, Yin-Nan E.; Weber, Rodney J.

2003-01-01

An apparatus and method for continuous on-line measurement of chemical composition of aerosol particles with a fast time resolution are provided. The apparatus includes a modified particle size magnifier for producing activated aerosol particles and a collection device which collects the activated aerosol particles into a liquid stream for quantitative analysis by analytical methods. The method provided for on-line measurement of chemical composition of aerosol particles includes exposing aerosol carrying sample air to hot saturated steam thereby forming activated aerosol particles; collecting the activated aerosol particles by a collection device for delivery as a jet stream onto an impaction surface; flushing off the activated aerosol particles from the impaction surface into a liquid stream for delivery of the collected liquid stream to an analytical instrument for quantitative measurement.

Apparatus for rapid measurement of aerosol bulk chemical composition

DOEpatents

Lee, Yin-Nan E.; Weber, Rodney J.; Orsini, Douglas

2006-04-18

An apparatus for continuous on-line measurement of chemical composition of aerosol particles with a fast time resolution is provided. The apparatus includes an enhanced particle size magnifier for producing activated aerosol particles and an enhanced collection device which collects the activated aerosol particles into a liquid stream for quantitative analysis by analytical means. Methods for on-line measurement of chemical composition of aerosol particles are also provided, the method including exposing aerosol carrying sample air to hot saturated steam thereby forming activated aerosol particles; collecting the activated aerosol particles by a collection device for delivery as a jet stream onto an impaction surface; and flushing off the activated aerosol particles from the impaction surface into a liquid stream for delivery of the collected liquid stream to an analytical instrument for quantitative measurement.

Quantification of the multi-streaming effect in redshift space distortion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zheng, Yi; Oh, Minji; Zhang, Pengjie, E-mail: yizheng@kasi.re.kr, E-mail: zhangpj@sjtu.edu.cn, E-mail: minjioh@kasi.re.kr

Both multi-streaming (random motion) and bulk motion cause the Finger-of-God (FoG) effect in redshift space distortion (RSD). We apply a direct measurement of the multi-streaming effect in RSD from simulations, proving that it induces an additional, non-negligible FoG damping to the redshift space density power spectrum. We show that, including the multi-streaming effect, the RSD modelling is significantly improved. We also provide a theoretical explanation based on halo model for the measured effect, including a fitting formula with one to two free parameters. The improved understanding of FoG helps break the f σ{sub 8}−σ {sub v} degeneracy in RSD cosmology,more » and has the potential of significantly improving cosmological constraints.« less

Molecular Mechanism of Pancreatic and Salivary Glands Fluid and HCO3− Secretion

PubMed Central

Lee, Min Goo; Ohana, Ehud; Park, Hyun Woo; Yang, Dongki; Muallem, Shmuel

2013-01-01

Fluid and HCO3− secretion is a vital function of all epithelia and is required for the survival of the tissue. Aberrant fluid and HCO3− secretion is associated with many epithelial diseases, such as cystic fibrosis, pancreatitis, Sjögren’s syndrome and other epithelial inflammatory and autoimmune diseases. Significant progress has been made over the last 20 years in our understanding of epithelial fluid and HCO3− secretion, in particular by secretory glands. Fluid and HCO3− secretion by secretory glands is a two step process. Acinar cells secrete isotonic fluid in which the major salt is NaCl. Subsequently, the duct modifies the volume and electrolyte composition of the fluid to absorb the Cl− and secrete HCO3−. The relative volume secreted by acinar and duct cells and modification of electrolyte composition of the secreted fluids varies among secretory glands to meet their physiological functions. In the pancreas, acinar cells secrete small amount of NaCl-rich fluid, while the duct absorbs the Cl− and secretes HCO3− and the bulk of the fluid in the pancreatic juice. Fluid secretion appears to be driven by active HCO3− secretion. In the salivary glands, acinar cells secrete the bulk of the fluid in the saliva that contains high concentrations of Na+ and Cl− and fluid secretion is mediated by active Cl− secretion. The salivary glands duct absorbs both the Na+ and Cl− and secretes K+ and HCO3−. In this review, we focus on the molecular mechanism of fluid and HCO3− secretion by the pancreas and salivary glands, to highlight the similarities of the fundamental mechanisms of acinar and duct cell functions, and point the differences to meet glands specific secretions. PMID:22298651

Spreading of a ferrofluid core in three-stream micromixer channels

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Zhaomeng; Varma, V. B.; Ramanujan, R. V., E-mail: ramanujan@ntu.edu.sg

2015-05-15

Spreading of a water based ferrofluid core, cladded by a diamagnetic fluid, in three-stream micromixer channels was studied. This spreading, induced by an external magnetic field, is known as magnetofluidic spreading (MFS). MFS is useful for various novel applications where control of fluid-fluid interface is desired, such as micromixers or micro-chemical reactors. However, fundamental aspects of MFS are still unclear, and a model without correction factors is lacking. Hence, in this work, both experimental and numerical analyses were undertaken to study MFS. We show that MFS increased for higher applied magnetic fields, slower flow speed of both fluids, smaller flowmore » rate of ferrofluid relative to cladding, and higher initial magnetic particle concentration. Spreading, mainly due to connective diffusion, was observed mostly near the channel walls. Our multi-physics model, which combines magnetic and fluidic analyses, showed, for the first time, excellent agreement between theory and experiment. These results can be useful for lab-on-a-chip devices.« less

Spreading of a ferrofluid core in three-stream micromixer channels

NASA Astrophysics Data System (ADS)

Wang, Zhaomeng; Varma, V. B.; Xia, Huan Ming; Wang, Z. P.; Ramanujan, R. V.

2015-05-01

Spreading of a water based ferrofluid core, cladded by a diamagnetic fluid, in three-stream micromixer channels was studied. This spreading, induced by an external magnetic field, is known as magnetofluidic spreading (MFS). MFS is useful for various novel applications where control of fluid-fluid interface is desired, such as micromixers or micro-chemical reactors. However, fundamental aspects of MFS are still unclear, and a model without correction factors is lacking. Hence, in this work, both experimental and numerical analyses were undertaken to study MFS. We show that MFS increased for higher applied magnetic fields, slower flow speed of both fluids, smaller flow rate of ferrofluid relative to cladding, and higher initial magnetic particle concentration. Spreading, mainly due to connective diffusion, was observed mostly near the channel walls. Our multi-physics model, which combines magnetic and fluidic analyses, showed, for the first time, excellent agreement between theory and experiment. These results can be useful for lab-on-a-chip devices.

Bulk Enthalpy Calculations in the Arc Jet Facility at NASA ARC

NASA Technical Reports Server (NTRS)

Thompson, Corinna S.; Prabhu, Dinesh; Terrazas-Salinas, Imelda; Mach, Jeffrey J.

2011-01-01

The Arc Jet Facilities at NASA Ames Research Center generate test streams with enthalpies ranging from 5 MJ/kg to 25 MJ/kg. The present work describes a rigorous method, based on equilibrium thermodynamics, for calculating the bulk enthalpy of the flow produced in two of these facilities. The motivation for this work is to determine a dimensionally-correct formula for calculating the bulk enthalpy that is at least as accurate as the conventional formulas that are currently used. Unlike previous methods, the new method accounts for the amount of argon that is present in the flow. Comparisons are made with bulk enthalpies computed from an energy balance method. An analysis of primary facility operating parameters and their associated uncertainties is presented in order to further validate the enthalpy calculations reported herein.

BULK AND FILM CONTRIBUTIONS TO FLUID/FLUID INTERFACIAL AREA IN GRANULAR MEDIA. (R827116)

EPA Science Inventory

The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Concl...

Turbulent particle transport in streams: can exponential settling be reconciled with fluid mechanics?

PubMed

McNair, James N; Newbold, J Denis

2012-05-07

Most ecological studies of particle transport in streams that focus on fine particulate organic matter or benthic invertebrates use the Exponential Settling Model (ESM) to characterize the longitudinal pattern of particle settling on the bed. The ESM predicts that if particles are released into a stream, the proportion that have not yet settled will decline exponentially with transport time or distance and will be independent of the release elevation above the bed. To date, no credible basis in fluid mechanics has been established for this model, nor has it been rigorously tested against more-mechanistic alternative models. One alternative is the Local Exchange Model (LEM), which is a stochastic advection-diffusion model that includes both longitudinal and vertical spatial dimensions and is based on classical fluid mechanics. The LEM predicts that particle settling will be non-exponential in the near field but will become exponential in the far field, providing a new theoretical justification for far-field exponential settling that is based on plausible fluid mechanics. We review properties of the ESM and LEM and compare these with available empirical evidence. Most evidence supports the prediction of both models that settling will be exponential in the far field but contradicts the ESM's prediction that a single exponential distribution will hold for all transport times and distances. Copyright © 2012 Elsevier Ltd. All rights reserved.

Identification of the Viscous Superlayer on the Low-Speed Side of a Single-Stream Shear Layer

NASA Astrophysics Data System (ADS)

Foss, John; Peabody, Jason

2010-11-01

Image pairs (elevation/plan views) have been acquired of a smoke streakline originating in the irrotational region on the low-speed side of a high Re single-stream shear layer of Morris and Foss (2003). The viscous superlayer (VSL) is identified as the terminus of the streak; 1800 such images provide VSL position statistics. Hot-wire data acquired concurrently at the shear layer edge and interior are used to investigate the relationship between these velocity magnitudes and the large-scale motions. Distinctive features (plumes) along the streakline are tracked between images to provide discrete irrotational region velocity magnitudes and material trajectories. A non-diffusive marker, introduced in the separating (high speed) boundary layer and imaged at x/θo=352, has revealed an unexpected bias in the streak-defined VSL locations. The interpretation of this bias clarifies the induced flow patterns in the entrainment region. The observations are consistent with a conception of the large-scale shear layer motions as "billows" of vortical fluid separated by re-entrant "wedges" of irrotational fluid, per Phillips (1972). Morris, S.C. and Foss, J.F. (2003). "Turbulent Boundary Layer to Single Stream Shear Layer: The Transition Region." Journal of Fluid Mechanics. Vol. 494, pp. 187-221. Phillips, O. M. (1972). "The Entrainment Interface." Journal of Fluid Mechanics. Vol. 51, pp. 97-118.

Finite element analysis of acoustic streaming in a Kundt tube with bended wall

NASA Astrophysics Data System (ADS)

Wada, Yuji; Yuge, Kohei

2018-07-01

Acoustic streaming near artificially prescribed ridges is simulated and discussed to understand the mechanism of Kundt tube powder-ridge generation. A viscoacoustic harmonic finite element analysis (FEA) and a static-fluid FEA are coupled using an acoustic streaming driving force to derive acoustic streaming. The half-wavelength mode is excited in an acoustic tube where the calculation mesh is distorted to form a sinusoidal bottom stick wall. Consequently, intense Schlichting streaming is obtained when the height and interval of the ridge agree with those in the literature. The mechanism underlying the regular ridge interval is related to the conversion of mainstream particle velocity into ridge-localized velocity, which produces an inlet or outlet vertical streaming in ridge valleys.

The influence of free-stream turbulence on turbulent boundary layers with mild adverse pressure gradients

NASA Technical Reports Server (NTRS)

Hoffmann, Jon A.

1988-01-01

The influence of near isotropic free-stream turbulence on the shape factors and skin friction coefficients of turbulent bounday layers is presented for the cases of zero and mild adverse pressure gradients. With free-stream turbulence, improved fluid mixing occurs in boundary layers with adverse pressure gradients relative to the zero pressure gradient condition, with the same free-stream turbulence intensity and length scale. Stronger boundary layers with lower shape factors occur as a result of a lower ratio of the integral scale of turbulence to the boundary layer thickness, and to vortex stretching of the turbulent eddies in the free stream, both of which act to improve the transmission of momentum from the free stream to the boundary layers.

The influence of free-stream turbulence on turbulent boundary layers with mild adverse pressure gradients

NASA Technical Reports Server (NTRS)

Hoffmann, J. A.; Kassir, S. M.; Larwood, S. M.

1989-01-01

The influence of near isotropic free-stream turbulence on the shape factors and skin friction coefficients of turbulent boundary layers is presented for the cases of zero and mild adverse pressure gradients. With free-stream turbulence, improved fluid mixing occurs in boundary layers with adverse pressure gradients relative to the zero pressure gradient condition, with the same free-stream turbulence intensity and length scale. Stronger boundary layers with lower shape factors occur as a result of a lower ratio of the integral scale of turbulence to the boundary layer thickness, and to vortex stretching of the turbulent eddies in the free-stream, both of which act to improve the transmission of momentum from the free-stream to the boundary layers.

Shaped Recess Flow Control

NASA Technical Reports Server (NTRS)

Shyam, Vikram (Inventor); Poinsatte, Philip (Inventor); Thurman, Douglas (Inventor)

2017-01-01

One or more embodiments of techniques or systems for shaped recess flow control are provided herein. A shaped recess or cavity can be formed on a surface associated with fluid flow. The shaped recess can be configured to create or induce fluid effects, temperature effects, or shedding effects that interact with a free stream or other structures. The shaped recess can be formed at an angle to a free stream flow and may be substantially "V" shaped. The shaped recess can be coupled with a cooling channel, for example. The shaped recess can be upstream or downstream from a cooling channel and aligned in a variety of manners. Due to the fluid effects, shedding effects, and temperature effects created by a shaped recess, lift-off or separation of cooling jets of cooling channels can be mitigated, thereby enhancing film cooling effectiveness.

An experimental trace gas investigation of fluid transport and mixing in a circular-to-rectangular transition duct

NASA Technical Reports Server (NTRS)

Reichert, B. A.; Hingst, W. R.; Okiishi, T. H.

1991-01-01

An ethylene trace gas technique was used to map out fluid transport and mixing within a circular to rectangular transition duct. Ethylene gas was injected at several points in a cross stream plane upstream of the transition duct. Ethylene concentration contours were determined at several cross stream measurement planes spaced axially within the duct. The flow involved a uniform inlet flow at a Mach number level of 0.5. Statistical analyses were used to quantitatively interpret the trace gas results. Also, trace gas data were considered along with aerodynamic and surface flow visualization results to ascertain transition duct flow phenomena. Convection of wall boundary layer fluid by vortices produced regions of high total pressure loss in the duct. The physical extent of these high loss regions is governed by turbulent diffusion.

Surface acoustic wave actuated cell sorting (SAWACS).

PubMed

Franke, T; Braunmüller, S; Schmid, L; Wixforth, A; Weitz, D A

2010-03-21

We describe a novel microfluidic cell sorter which operates in continuous flow at high sorting rates. The device is based on a surface acoustic wave cell-sorting scheme and combines many advantages of fluorescence activated cell sorting (FACS) and fluorescence activated droplet sorting (FADS) in microfluidic channels. It is fully integrated on a PDMS device, and allows fast electronic control of cell diversion. We direct cells by acoustic streaming excited by a surface acoustic wave which deflects the fluid independently of the contrast in material properties of deflected objects and the continuous phase; thus the device underlying principle works without additional enhancement of the sorting by prior labelling of the cells with responsive markers such as magnetic or polarizable beads. Single cells are sorted directly from bulk media at rates as fast as several kHz without prior encapsulation into liquid droplet compartments as in traditional FACS. We have successfully directed HaCaT cells (human keratinocytes), fibroblasts from mice and MV3 melanoma cells. The low shear forces of this sorting method ensure that cells survive after sorting.

Evaluation of Innovative Volatile Organic Compound and Hazardous Air Pollutant Control Technologies for U.S. Air Force Paint Spray Booths

DTIC Science & Technology

1990-10-01

adsorption/incineration * Membrane vapor separation/condensation * Supercritical fluid oxidation • UV/ozone destruction * Molten salt combustion process...separation/ separate air stream contaminants 9 Oxygenated solvents condensation * Chlorinated hydrocarbons Supercritical fluid * Technology utilizing high...testing or full-scale unit capacity; they are: * Supercritical fluid oxidation • UV/ozone destruction * Molten salt incineration * Infrared incineration

Pressurized-Flat-Interface Heat Exchanger

NASA Technical Reports Server (NTRS)

Voss, F. E.; Howell, H. R.; Winkler, R. V.

1990-01-01

High thermal conductance obtained without leakage between loops. Heat-exchanger interface enables efficient transfer of heat between two working fluids without allowing fluids to intermingle. Interface thin, flat, and easy to integrate into thermal system. Possible application in chemical or pharmaceutical manufacturing when even trace contamination of process stream with water or other coolant ruins product. Reduces costs when highly corrosive fluids must be cooled or heated.

Fluid mechanics in crystal growth - The 1982 Freeman scholar lecture

NASA Technical Reports Server (NTRS)

Ostrach, S.

1983-01-01

An attempt is made to unify the current state of knowledge in crystal growth techniques and fluid mechanics. After identifying important fluid dynamic problems for such representative crystal growth processes as closed tube vapor transport, open reactor vapor deposition, and the Czochralski and floating zone melt growth techniques, research results obtained to date are presented. It is noted that the major effort to date has been directed to the description of the nature and extent of bulk transport under realistic conditions, where bulk flow determines the heat and solute transport which strongly influence the temperature and concentration fields in the vicinity of the growth interface. Proper treatment of near field, or interface, problems cannot be given until the far field, or global flow, involved in a given crystal growth technique has been adequately described.

Energy recovery system using an organic rankine cycle

DOEpatents

Ernst, Timothy C

2013-10-01

A thermodynamic system for waste heat recovery, using an organic rankine cycle is provided which employs a single organic heat transferring fluid to recover heat energy from two waste heat streams having differing waste heat temperatures. Separate high and low temperature boilers provide high and low pressure vapor streams that are routed into an integrated turbine assembly having dual turbines mounted on a common shaft. Each turbine is appropriately sized for the pressure ratio of each stream.

Nanoliter-droplet acoustic streaming via ultra high frequency surface acoustic waves.

PubMed

Shilton, Richie J; Travagliati, Marco; Beltram, Fabio; Cecchini, Marco

2014-08-06

The relevant length scales in sub-nanometer amplitude surface acoustic wave-driven acoustic streaming are demonstrated. We demonstrate the absence of any physical limitations preventing the downscaling of SAW-driven internal streaming to nanoliter microreactors and beyond by extending SAW microfluidics up to operating frequencies in the GHz range. This method is applied to nanoliter scale fluid mixing. © 2014 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Two-stream modeling of plasmaspheric refilling

NASA Technical Reports Server (NTRS)

Guiter, S. M.; Gombosi, T. I.; Rasmussen, C. E.

1995-01-01

Plasmaspheric refilling on an L = 4 flux tube was studied by using a time-dependent, hydrodynamic plasmaspheric flow model in which the ion streams from the two hemispheres are treated as distinct fluids. In the model the continuity, momentum, and energy equations of a two-ion (O(+) and H(+)), quasi-neutral, currentless plasma are solved along a closed geomagnetic field line; diffusive equilibrium is not assumed. collisions between all stream pairs and with neutral species are included. The model includes a corotating, tilted dipole magnetic field and neutral winds. Ionospheric sources and sinks are accounted for in a self-consistent manner. Electrons are assumed to be heated by photoelectrons. The model flux tube extends from a 200-km altitude in one hemisphere to a 200-km altitude in the other hemisphere. Initially, the upwelling streams pass through each other practically unimpeded. When the streams approach the boundary in the conjugate ionosphere, a shock develops there, which moves upward and dissipates slowly; at about the same time a reverse shock develops in the hemisphere of origin, which moves upward. After about 1 hour, large shocks develop in each stream near the equator; these shocks move toward the equator and downward after crossing the equator. However, these shocks are probably artificial, because counterstreaming flows occur in each H(+) fluid, which the model can only handle by creating shocks.

Super-alfvenic propagation of cosmic rays: The role of streaming modes

NASA Technical Reports Server (NTRS)

Morrison, P. J.; Scott, J. S.; Holman, G. D.; Ionson, J. A.

1980-01-01

Numerous cosmic ray propagation and acceleration problems require knowledge of the propagation speed of relativistic particles through an ambient plasma. Previous calculations indicated that self-generated turbulence scatters relativistic particles and reduces their bulk streaming velocity to the Alfven speed. This result was incorporated into all currently prominent theories of cosmic ray acceleration and propagation. It is demonstrated that super-Alfvenic propagation is indeed possible for a wide range of physical parameters. This fact dramatically affects the predictions of these models.

Ideal glass transitions in thin films: An energy landscape perspective

NASA Astrophysics Data System (ADS)

Truskett, Thomas M.; Ganesan, Venkat

2003-07-01

We introduce a mean-field model for the potential energy landscape of a thin fluid film confined between parallel substrates. The model predicts how the number of accessible basins on the energy landscape and, consequently, the film's ideal glass transition temperature depend on bulk pressure, film thickness, and the strength of the fluid-fluid and fluid-substrate interactions. The predictions are in qualitative agreement with the experimental trends for the kinetic glass transition temperature of thin films, suggesting the utility of landscape-based approaches for studying the behavior of confined fluids.

Acoustic streaming, fluid mixing, and particle transport by a Gaussian ultrasound beam in a cylindrical container

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marshall, Jeffrey S., E-mail: jeffm@cems.uvm.edu; Wu, Junru

A computational study is reported of the acoustic streaming flow field generated by a Gaussian ultrasound beam propagating normally toward the end wall of a cylindrical container. Particular focus is given to examining the effectiveness of the acoustic streaming flow for fluid mixing within the container, for deposition of particles in suspension onto the bottom surface, and for particle suspension from the bottom surface back into the flow field. The flow field is assumed to be axisymmetric with the ultrasound transducer oriented parallel to the cylinder axis and normal to the bottom surface of the container, which we refer tomore » as the impingement surface. Reflection of the sound from the impingement surface and sound absorption within the material at the container bottom are both accounted for in the computation. The computation also accounts for thermal buoyancy force due to ultrasonic heating of the impingement surface, but over the time period considered in the current simulations, the flow is found to be dominated by the acoustic streaming force, with only moderate effect of buoyancy force.« less

Acoustic streaming, fluid mixing, and particle transport by a Gaussian ultrasound beam in a cylindrical container

NASA Astrophysics Data System (ADS)

Marshall, Jeffrey S.; Wu, Junru

2015-10-01

A computational study is reported of the acoustic streaming flow field generated by a Gaussian ultrasound beam propagating normally toward the end wall of a cylindrical container. Particular focus is given to examining the effectiveness of the acoustic streaming flow for fluid mixing within the container, for deposition of particles in suspension onto the bottom surface, and for particle suspension from the bottom surface back into the flow field. The flow field is assumed to be axisymmetric with the ultrasound transducer oriented parallel to the cylinder axis and normal to the bottom surface of the container, which we refer to as the impingement surface. Reflection of the sound from the impingement surface and sound absorption within the material at the container bottom are both accounted for in the computation. The computation also accounts for thermal buoyancy force due to ultrasonic heating of the impingement surface, but over the time period considered in the current simulations, the flow is found to be dominated by the acoustic streaming force, with only moderate effect of buoyancy force.

Bulk viscous cosmology with causal transport theory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Piattella, Oliver F.; Fabris, Júlio C.; Zimdahl, Winfried, E-mail: oliver.piattella@gmail.com, E-mail: fabris@pq.cnpq.br, E-mail: winfried.zimdahl@pq.cnpq.br

2011-05-01

We consider cosmological scenarios originating from a single imperfect fluid with bulk viscosity and apply Eckart's and both the full and the truncated Müller-Israel-Stewart's theories as descriptions of the non-equilibrium processes. Our principal objective is to investigate if the dynamical properties of Dark Matter and Dark Energy can be described by a single viscous fluid and how such description changes when a causal theory (Müller-Israel-Stewart's, both in its full and truncated forms) is taken into account instead of Eckart's non-causal one. To this purpose, we find numerical solutions for the gravitational potential and compare its behaviour with the corresponding ΛCDMmore » case. Eckart's and the full causal theory seem to be disfavoured, whereas the truncated theory leads to results similar to those of the ΛCDM model for a bulk viscous speed in the interval 10{sup −11} || cb{sup 2} ∼< 10{sup −8}.« less

Combined free and forced convection heat transfer in magneto fluid mechanic pipe flow

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gardner, R.A.; Lo, Y.T.

1977-01-01

A study is made of fully developed, laminar, free-and-forced convection heat transfer in an electrically conducting fluid flowing in an electrically insulated, horizontal, circular pipe in a vertical transverse magnetic field. The normalized magnetofluidmechanic and energy equations are reduced to three coupled partial differential equations by the introduction of a stream function of the secondary flow. A perturbation solution is generated in inverse powers of the Lykoudis number, Ly = M/sup 2//..sqrt..Gr, which yields the influence of the magnetic field on the stream function of the secondary flow, axial velocity profiles, temperature profiles, and Nusselt number. 6 figures, 1 table.

A study analysis of cable-body systems totally immersed in a fluid stream

NASA Technical Reports Server (NTRS)

Delaurier, J. D.

1972-01-01

A general stability analysis of a cable-body system immersed in a fluid stream is presented. The analytical portion of this analysis treats the system as being essentially a cable problem, with the body dynamics giving the end conditions. The mathematical form of the analysis consists of partial differential wave equations, with the end and auxiliary conditions being determined from the body equations of motion. The equations uncouple to give a lateral problem and a longitudinal problem as in first order airplane dynamics. A series of tests on a tethered wind tunnel model provide a comparison of the theory with experiment.

Electro-osmosis of non-Newtonian fluids in porous media using lattice Poisson-Boltzmann method.

PubMed

Chen, Simeng; He, Xinting; Bertola, Volfango; Wang, Moran

2014-12-15

Electro-osmosis in porous media has many important applications in various areas such as oil and gas exploitation and biomedical detection. Very often, fluids relevant to these applications are non-Newtonian because of the shear-rate dependent viscosity. The purpose of this study was to investigate the behaviors and physical mechanism of electro-osmosis of non-Newtonian fluids in porous media. Model porous microstructures (granular, fibrous, and network) were created by a random generation-growth method. The nonlinear governing equations of electro-kinetic transport for a power-law fluid were solved by the lattice Poisson-Boltzmann method (LPBM). The model results indicate that: (i) the electro-osmosis of non-Newtonian fluids exhibits distinct nonlinear behaviors compared to that of Newtonian fluids; (ii) when the bulk ion concentration or zeta potential is high enough, shear-thinning fluids exhibit higher electro-osmotic permeability, while shear-thickening fluids lead to the higher electro-osmotic permeability for very low bulk ion concentration or zeta potential; (iii) the effect of the porous medium structure depends significantly on the constitutive parameters: for fluids with large constitutive coefficients strongly dependent on the power-law index, the network structure shows the highest electro-osmotic permeability while the granular structure exhibits the lowest permeability on the entire range of power law indices considered; when the dependence of the constitutive coefficient on the power law index is weaker, different behaviors can be observed especially in case of strong shear thinning. Copyright © 2014 Elsevier Inc. All rights reserved.

Recovering hydrocarbons from hydrocarbon-containing vapors

DOEpatents

Mirza, Zia I.; Knell, Everett W.; Winter, Bruce L.

1980-09-30

Values are recovered from a hydrocarbon-containing vapor by contacting the vapor with quench liquid consisting essentially of hydrocarbons to form a condensate and a vapor residue, the condensate and quench fluid forming a combined liquid stream. The combined liquid stream is mixed with a viscosity-lowering liquid to form a mixed liquid having a viscosity lower than the viscosity of the combined liquid stream to permit easy handling of the combined liquid stream. The quench liquid is a cooled portion of the mixed liquid. Viscosity-lowering liquid is separated from a portion of the mixed liquid and cycled to form additional mixed liquid.

Forced Convection and Sedimentation Past a Flat Plate

NASA Technical Reports Server (NTRS)

Pelekasis, Nikolaos A.; Acrivos, Andreas

1995-01-01

The steady laminar flow of a well-mixed suspension of monodisperse solid spheres, convected steadily past a horizontal flat plate and sedimenting under the action of gravity, is examined. It is shown that, in the limit as Re approaches infinity and epsilon approaches 0, where Re is the bulk Reynolds number and epsilon is the ratio of the particle radius a to the characteristic length scale L, the analysis for determining the particle concentration profile has several aspects in common with that of obtaining the temperature profile in forced-convection heat transfer from a wall to a fluid stream moving at high Reynolds and Prandtl numbers. Specifically, it is found that the particle concentration remains uniform throughout the O(Re(exp -1/2)) thick Blasius boundary layer except for two O(epsilon(exp 2/3)) thin regions on either side of the plate, where the concentration profile becomes non-uniform owing to the presence of shear-induced particle diffusion which balances the particle flux due to convection and sedimentation. The system of equations within this concentration boundary layer admits a similarity solution near the leading edge of the plate, according to which the particle concentration along the top surface of the plate increases from its value in the free stream by an amount proportional to X(exp 5/6), with X measuring the distance along the plate, and decreases in a similar fashion along the underside. But, unlike the case of gravity settling on an inclined plate in the absence of a bulk flow at infinity considered earlier, here the concentration profile remains continuous everywhere. For values of X beyond the region near the leading edge, the particle concentration profile is obtained through the numerical solution of the relevant equations. It is found that, as predicted from the similarity solution, there exists a value of X at which the particle concentration along the top side of the plate attains its maximum value phi(sub m) and that, beyond this point, a stagnant sediment layer will form that grows steadily in time. This critical value of X is computed as a function of phi(sub s), the particle volume fraction in the free stream. In contrast, but again in conformity with the similarity solution, for values of X sufficiently far removed from the leading edge along the underside of the plate, a particle-free region is predicted to form adjacent to the plate. This model, with minor modifications, can be used to describe particle migration in other shear flows, as, for example, in the case of crossflow microfiltration.

Dynamics of yield-stress droplets: Morphology of impact craters

NASA Astrophysics Data System (ADS)

Neufeld, Jerome; Sohr, David; Ferrari, Leo; Dalziel, Stuart

2017-11-01

Yield strength can play an important role for the dynamics of droplets impacting on surfaces, whether at the industrial or planetary scale, and can capture a zoo of impact crater morphologies, from simple parabolic craters, to more complex forms with forms with, for example, multiple rings, central peaks. Here we show that the morphology of planetary impact craters can be reproduced in the laboratory using carbopol, a transparent yield-stress fluid, as both impactor and bulk fluid. Using high-speed video photography, we characterise the universal, transient initial excavation stage of impact and show the dependence of the subsequent relaxation to final crater morphology on impactor size, impact speed and yield stress. To further interrogate our laboratory impacts, we dye our impactor to map its final distribution and use particle tracking to determine the flow fields during impact and the maximal extent of the yield surface. We characterise the flow-fields induced during impact, and the maximal extent of the yield surface, by tracking particles within the bulk fluid and map the distribution of impactor and bulk by tracing the final distribution of dyed impactor. The results of laboratory impact droplets are used to infer the properties of planetary impactors, and aid in inter.

Measurements of unjacketed moduli of porous rock

NASA Astrophysics Data System (ADS)

Tarokh, A.; Makhnenko, R. Y.; Labuz, J.

2017-12-01

Coupling of stress and pore pressure appears in a number of applications dealing with subsurface (sedimentary) rock, including petroleum exploration and waste storage. Poroelastic analyses consider the compressibility of the solid constituents forming the rock, and often times solid bulk modulus Ks is assumed to be the same as the dominant mineral bulk modulus. In fact, there are two different parameters describing solid compressibility of a porous rock: the unjacketed bulk modulus Ks' and the unjacketed pore modulus Ks". Experimental techniques are developed to measure the two poroelastic parameters of fluid-saturated porous rock under the unjacketed condition. In an unjacketed experiment, the rock without a membrane is loaded by the fluid in a pressure vessel. The confining fluid permeates the connected pore space throughout the interior of the rock. Therefore, changes in mean stress P will produce equal changes in pore pressure p, i.e. ΔP = Δp. The test can also be performed with a jacketed rock specimen by applying equal increments of mean stress and pore pressure. The unjacketed bulk modulus, Ks', is obtained by measuring the bulk strain with resistive strain gages. The unjacketed pore modulus, Ks", the pore volume counterpart to Ks', is a measure of the change in pore pressure per unit pore volume strain under the unjacketed condition. Several indirect estimates of Ks" have been reported but limitations of these approaches do not provide an accurate value. We present direct measurements of Ks" with detailed calibration on the system volumetric response. The results indicate that for Dunnville sandstone Ks' and Ks" are equal while for Berea sandstone, a difference between the two moduli exists, which is explained by the presence of non-connected pores. The experiments also strongly suggest that both Ks' and Ks" are independent of effective stress.

Computational fluid mechanics utilizing the variational principle of modeling damping seals

NASA Technical Reports Server (NTRS)

Abernathy, J. M.

1986-01-01

A computational fluid dynamics code for application to traditional incompressible flow problems has been developed. The method is actually a slight compressibility approach which takes advantage of the bulk modulus and finite sound speed of all real fluids. The finite element numerical analog uses a dynamic differencing scheme based, in part, on a variational principle for computational fluid dynamics. The code was developed in order to study the feasibility of damping seals for high speed turbomachinery. Preliminary seal analyses have been performed.

Unravelling the effects of melt depletion and secondary infiltration on mantle Re-Os isotopes beneath the French Massif Central

NASA Astrophysics Data System (ADS)

Harvey, J.; Gannoun, A.; Burton, K. W.; Schiano, P.; Rogers, N. W.; Alard, O.

2010-01-01

Spinel lherzolite xenoliths from Mont Briançon, French Massif Central, retain evidence for multiple episodes of melt depletion and melt/fluid infiltration (metasomatism). Evidence for primary melt depletion is still preserved in the co-variation of bulk-rock major elements (MgO 38.7-46.1 wt.%; CaO 0.9-3.6 wt.%), and many samples yield unradiogenic bulk-rock Os isotope ratios ( 187Os/ 188Os = 0.11541-0.12626). However, many individual xenoliths contain interstitial glasses and melt inclusions that are not in equilibrium with the major primary minerals. Incompatible trace element mass balance calculations demonstrate that metasomatic components comprise a significant proportion of the bulk-rock budget for these elements in some rocks, ranging to as much as 25% of Nd and 40% of Sr Critically, for Re-Os geochronology, melt/fluid infiltration is accompanied by the mobilisation of sulfide. Consequently, bulk-rock isotope measurements, whether using lithophile (e.g. Rb-Sr, Sm-Nd) or siderophile (Re-Os) based isotope systems, may only yield a perturbed and/or homogenised average of these multiple events. Osmium mass balance calculations demonstrate that bulk-rock Os in peridotite is dominated by contributions from two populations of sulfide grain: (i) interstitial, metasomatic sulfide with low [Os] and radiogenic 187Os/ 188Os, and (ii) primary sulfides with high [Os] and unradiogenic 187Os/ 188Os, which have been preserved within host silicate grains and shielded from interaction with transient melts and fluid. The latter can account for >97% of bulk-rock Os and preserve geochronological information of the melt from which they originally precipitated as an immiscible liquid. The Re-depletion model ages of individual primary sulfide grains preserve evidence for melt depletion beneath the Massif Central from at least 1.8 Gyr ago despite the more recent metasomatic event(s).

40 CFR 63.1012 - Compressor standards.

Code of Federal Regulations, 2012 CFR

2012-07-01

... in the referencing subpart. (b) Seal system standard. Each compressor shall be equipped with a seal..., except as provided in § 63.1002(b) and paragraphs (e) and (f) of this section. Each compressor seal...-loop system that purges the barrier fluid directly into a process stream. (c) Barrier fluid system. The...

40 CFR 63.1012 - Compressor standards.

Code of Federal Regulations, 2014 CFR

2014-07-01

... in the referencing subpart. (b) Seal system standard. Each compressor shall be equipped with a seal..., except as provided in § 63.1002(b) and paragraphs (e) and (f) of this section. Each compressor seal...-loop system that purges the barrier fluid directly into a process stream. (c) Barrier fluid system. The...

40 CFR 63.1012 - Compressor standards.

Code of Federal Regulations, 2013 CFR

2013-07-01

... in the referencing subpart. (b) Seal system standard. Each compressor shall be equipped with a seal..., except as provided in § 63.1002(b) and paragraphs (e) and (f) of this section. Each compressor seal...-loop system that purges the barrier fluid directly into a process stream. (c) Barrier fluid system. The...

Measuring the DC electrokinetic coupling coefficient of porous rock samples in the laboratory : a new apparatus

NASA Astrophysics Data System (ADS)

Walker, E.; Tardif, E.; Glover, P. W.; Ruel, J.; Hadjigeorgiou, J.

2009-12-01

Electro-kinetic properties of rocks allow the generation of an electric potential by the flow of an aqueous fluid through a porous media. The electrical potential is called the streaming potential, and the streaming potential coupling coefficient Cs is the ratio of the generated electric potential to the pressure difference that causes the fluid flow. The streaming potential coupling coefficient for rocks is described in the steady-state regime by the well known Helmholtz-Smoluchowski equation, and is supported by a relatively small body of experimental data. However, the electrokinetic coupling coefficient measurement is important for the further development of different area of expertise such as reservoir prospection and monitoring, volcano and earthquake monitoring and the underground sequestration of CO2. We have designed, constructed and tested a new experimental cell that is capable of measuring the DC streaming potential of consolidated and unconsolidated porous media. The new cell is made from stainless steel, perspex and other engineering polymers. Cylindrical samples of 25.4 mm can be placed in a deformable rubber sleeve and subjected to a radial confining pressure of compressed nitrogen up to 4.5 MPa. Actively degassed aqueous fluids can be flowed by an Agilent 1200 series binary pump (2 to 10 mL/min). A maximum input fluid pressure of 2.5 MPa can be applied, with a maximum exit pressure of 1 MPa to ensure sample saturation is stable and to reduce gas bubbles. The pressures each side of the sample are measured by high stability pressure transducers (Omega PX302-300GV), previously calibrated by a high precision differential pressure transducer Endress and Hauser Deltabar S PMD75. The streaming potentials are measured with Harvard Apparatus LF-1 and LF-2 Ag/AgCl non-polarising miniature electrodes. An axial pressure is applied (1 to 6.5 MPa) to counteract the radial pressure and provide additional axial load with a hydraulic piston. It is our intention to complete the testing of the cell and to use it to measure the electrokinetic properties of porous rocks in the DC regime in order to provide sufficient data to improve the theories and models of DC streaming potentials.

Measuring the DC electrokinetic coupling coefficient of porous rock samples in the laboratory : A new apparatus

NASA Astrophysics Data System (ADS)

Walker, Emilie; Tardif, Eric; Glover, Paul; Ruel, Jean; Lalande, Guillaume; Hadjigeorgiou, John

2010-05-01

Electro-kinetic properties of rocks allow the generation of an electric potential by the flow of an aqueous fluid through a porous media. The electrical potential is called the streaming potential, and the streaming potential coupling coefficient is the ratio of the generated electric potential to the pressure difference that causes the fluid flow. The streaming potential coupling coefficient for rocks is described in the steady-state regime by the well known Helmholtz-Smoluchowski equation, and is supported by a relatively small body of experimental data. However, the electrokinetic coupling coefficient measurement is important for the further development of different area of expertise such as reservoir prospection and monitoring, volcano and earthquake monitoring and the underground sequestration of carbon dioxide. We have designed, constructed and tested a new experimental cell that is capable of measuring the DC streaming potential of consolidated and unconsolidated porous media. The new cell is made from stainless steel, perspex and other engineering polymers. Cylindrical samples of 25.4 mm can be placed in a deformable rubber sleeve and subjected to a radial confining pressure of compressed nitrogen up to 4.5 MPa. Actively degassed aqueous fluids can be flowed by an Agilent 1200 series binary pump (2 to 10 mL/min). A maximum input fluid pressure of 2.5 MPa can be applied, with a maximum exit pressure of 1 MPa to ensure sample saturation is stable and to reduce gas bubbles. The pressures each side of the sample are measured by high stability pressure transducers (Omega PX302-300GV), previously calibrated by a high precision differential pressure transducer Endress and Hauser Deltabar S PMD75. The streaming potentials are measured with Harvard Apparatus LF-1 and LF-2 Ag/AgCl non-polarising miniature electrodes. An axial pressure is applied (1 to 6.5 MPa) to counteract the radial pressure and provide additional axial load with a hydraulic piston. It is our intention to complete the testing of the cell and to use it to measure the electrokinetic properties of porous rocks in the DC regime in order to provide sufficient data to improve the theories and models of DC streaming potentials.

Simultaneous measurement of acoustic and streaming velocities in a standing wave using laser Doppler anemometry.

PubMed

Thompson, Michael W; Atchley, Anthony A

2005-04-01

Laser Doppler anemometry (LDA) with burst spectrum analysis (BSA) is used to study the acoustic streaming generated in a cylindrical standing-wave resonator filled with air. The air column is driven sinusoidally at a frequency of approximately 310 Hz and the resultant acoustic-velocity amplitudes are less than 1.3 m/s at the velocity antinodes. The axial component of fluid velocity is measured along the resonator axis, across the diameter, and as a function of acoustic amplitude. The velocity signals are postprocessed using the Fourier averaging method [Sonnenberger et al., Exp. Fluids 28, 217-224 (2000)]. Equations are derived for determining the uncertainties in the resultant Fourier coefficients. The time-averaged velocity-signal components are seen to be contaminated by significant errors due to the LDA/BSA system. In order to avoid these errors, the Lagrangian streaming velocities are determined using the time-harmonic signal components and the arrival times of the velocity samples. The observed Lagrangian streaming velocities are consistent with Rott's theory [N. Rott, Z. Angew. Math. Phys. 25, 417-421 (1974)], indicating that the dependence of viscosity on temperature is important. The onset of streaming is observed to occur within approximately 5 s after switching on the acoustic field.

Do freshwater mussel shells record road-salt pollution?

NASA Astrophysics Data System (ADS)

O'Neil, Dane D.; Gillikin, David P.

2014-11-01

Road-salt pollution in streams in the Northeastern United States has become a major concern, but historical data are scarce. Freshwater bivalve shells have the ability to record past environmental information, and may act as archives of road-salt pollution. We sampled Elliptio complanata shells from four streams, as well as specimens collected in 1877. Average [Na/Ca]shell was highest in modern shells from the stream with the highest sodium concentrations, and low in shells collected from this same stream in 1877 as well as in the shells from other streams, suggesting that [Na/Ca]shell serves as a proxy for road-salt pollution. We expected higher [Na/Ca]shell in winter and spring. However, high-resolution [Na/Ca]shell analyses along the growth axis of one shell did not reveal any clear subannual patterns, which could be the result of shell growth cessation in winter and/or during periods of high stream sodium concentrations. Therefore, bulk [Na/Ca]shell analysis from multiple shells can be used as a proxy of large changes in stream sodium concentrations, but high-resolution variations in stream sodium concentrations do not seem to be recorded in the shells.

Do freshwater mussel shells record road-salt pollution?

PubMed Central

O'Neil, Dane D.; Gillikin, David P.

2014-01-01

Road-salt pollution in streams in the Northeastern United States has become a major concern, but historical data are scarce. Freshwater bivalve shells have the ability to record past environmental information, and may act as archives of road-salt pollution. We sampled Elliptio complanata shells from four streams, as well as specimens collected in 1877. Average [Na/Ca]shell was highest in modern shells from the stream with the highest sodium concentrations, and low in shells collected from this same stream in 1877 as well as in the shells from other streams, suggesting that [Na/Ca]shell serves as a proxy for road-salt pollution. We expected higher [Na/Ca]shell in winter and spring. However, high-resolution [Na/Ca]shell analyses along the growth axis of one shell did not reveal any clear subannual patterns, which could be the result of shell growth cessation in winter and/or during periods of high stream sodium concentrations. Therefore, bulk [Na/Ca]shell analysis from multiple shells can be used as a proxy of large changes in stream sodium concentrations, but high-resolution variations in stream sodium concentrations do not seem to be recorded in the shells. PMID:25418687

7 CFR 1032.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2013 CFR

2013-01-01

... the following information: (1) Product pounds, pounds of butterfat, pounds of protein, pounds of solids-not-fat other than protein (other solids), and the value of the somatic cell adjustment pursuant... of fluid milk products and bulk fluid cream products; (3) The utilization or disposition of all milk...

7 CFR 1033.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2014 CFR

2014-01-01

... the following information: (1) Product pounds, pounds of butterfat, pounds of protein, pounds of solids-not-fat other than protein (other solids), and the value of the somatic cell adjustment pursuant... of fluid milk products and bulk fluid cream products; (3) The utilization or disposition of all milk...

7 CFR 1032.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2011 CFR

2011-01-01

... the following information: (1) Product pounds, pounds of butterfat, pounds of protein, pounds of solids-not-fat other than protein (other solids), and the value of the somatic cell adjustment pursuant... of fluid milk products and bulk fluid cream products; (3) The utilization or disposition of all milk...

7 CFR 1033.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2012 CFR

2012-01-01

... the following information: (1) Product pounds, pounds of butterfat, pounds of protein, pounds of solids-not-fat other than protein (other solids), and the value of the somatic cell adjustment pursuant... of fluid milk products and bulk fluid cream products; (3) The utilization or disposition of all milk...

7 CFR 1032.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2014 CFR

2014-01-01

... the following information: (1) Product pounds, pounds of butterfat, pounds of protein, pounds of solids-not-fat other than protein (other solids), and the value of the somatic cell adjustment pursuant... of fluid milk products and bulk fluid cream products; (3) The utilization or disposition of all milk...

7 CFR 1033.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2010 CFR

2010-01-01

... the following information: (1) Product pounds, pounds of butterfat, pounds of protein, pounds of solids-not-fat other than protein (other solids), and the value of the somatic cell adjustment pursuant... of fluid milk products and bulk fluid cream products; (3) The utilization or disposition of all milk...

7 CFR 1126.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2010 CFR

2010-01-01

... pool plant operator shall report for each of its operations the following information: (1) Product pounds, pounds of butterfat, pounds of protein, pounds of nonfat solids other than protein (other solids...) Inventories at the beginning and end of the month of fluid milk products and bulk fluid cream products; (3...

7 CFR 1032.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2012 CFR

2012-01-01

... the following information: (1) Product pounds, pounds of butterfat, pounds of protein, pounds of solids-not-fat other than protein (other solids), and the value of the somatic cell adjustment pursuant... of fluid milk products and bulk fluid cream products; (3) The utilization or disposition of all milk...

7 CFR 1126.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2011 CFR

2011-01-01

... pool plant operator shall report for each of its operations the following information: (1) Product pounds, pounds of butterfat, pounds of protein, pounds of nonfat solids other than protein (other solids...) Inventories at the beginning and end of the month of fluid milk products and bulk fluid cream products; (3...

7 CFR 1124.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2011 CFR

2011-01-01

... the following information: (1) Product pounds, pounds of butterfat, pounds of protein, and pounds of solids-not-fat other than protein (other solids) contained in or represented by: (i) Receipts of producer... and end of the month of fluid milk products and bulk fluid cream products; (3) The utilization or...

7 CFR 1126.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2013 CFR

2013-01-01

... pool plant operator shall report for each of its operations the following information: (1) Product pounds, pounds of butterfat, pounds of protein, pounds of nonfat solids other than protein (other solids...) Inventories at the beginning and end of the month of fluid milk products and bulk fluid cream products; (3...

7 CFR 1124.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2013 CFR

2013-01-01

... the following information: (1) Product pounds, pounds of butterfat, pounds of protein, and pounds of solids-not-fat other than protein (other solids) contained in or represented by: (i) Receipts of producer... and end of the month of fluid milk products and bulk fluid cream products; (3) The utilization or...

7 CFR 1124.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2010 CFR

2010-01-01

... the following information: (1) Product pounds, pounds of butterfat, pounds of protein, and pounds of solids-not-fat other than protein (other solids) contained in or represented by: (i) Receipts of producer... and end of the month of fluid milk products and bulk fluid cream products; (3) The utilization or...

7 CFR 1126.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2012 CFR

2012-01-01

... pool plant operator shall report for each of its operations the following information: (1) Product pounds, pounds of butterfat, pounds of protein, pounds of nonfat solids other than protein (other solids...) Inventories at the beginning and end of the month of fluid milk products and bulk fluid cream products; (3...

7 CFR 1032.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2010 CFR

2010-01-01

... the following information: (1) Product pounds, pounds of butterfat, pounds of protein, pounds of solids-not-fat other than protein (other solids), and the value of the somatic cell adjustment pursuant... of fluid milk products and bulk fluid cream products; (3) The utilization or disposition of all milk...

7 CFR 1126.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2014 CFR

2014-01-01

... pool plant operator shall report for each of its operations the following information: (1) Product pounds, pounds of butterfat, pounds of protein, pounds of nonfat solids other than protein (other solids...) Inventories at the beginning and end of the month of fluid milk products and bulk fluid cream products; (3...

7 CFR 1033.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2013 CFR

2013-01-01

... the following information: (1) Product pounds, pounds of butterfat, pounds of protein, pounds of solids-not-fat other than protein (other solids), and the value of the somatic cell adjustment pursuant... of fluid milk products and bulk fluid cream products; (3) The utilization or disposition of all milk...

7 CFR 1033.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2011 CFR

2011-01-01

... the following information: (1) Product pounds, pounds of butterfat, pounds of protein, pounds of solids-not-fat other than protein (other solids), and the value of the somatic cell adjustment pursuant... of fluid milk products and bulk fluid cream products; (3) The utilization or disposition of all milk...

7 CFR 1124.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2012 CFR

2012-01-01

... the following information: (1) Product pounds, pounds of butterfat, pounds of protein, and pounds of solids-not-fat other than protein (other solids) contained in or represented by: (i) Receipts of producer... and end of the month of fluid milk products and bulk fluid cream products; (3) The utilization or...

7 CFR 1124.30 - Reports of receipts and utilization.

Code of Federal Regulations, 2014 CFR

2014-01-01

... the following information: (1) Product pounds, pounds of butterfat, pounds of protein, and pounds of solids-not-fat other than protein (other solids) contained in or represented by: (i) Receipts of producer... and end of the month of fluid milk products and bulk fluid cream products; (3) The utilization or...

Methods and apparatus for carbon dioxide removal from a fluid stream

DOEpatents

Wei, Wei; Ruud, James Anthony; Ku, Anthony Yu-Chung; Ramaswamy, Vidya; Liu, Ke

2010-01-19

An apparatus for producing hydrogen gas wherein the apparatus includes a reactor. In one embodiment, the reactor includes at least two conversion-removal portions. Each conversion-removal portion comprises a catalyst section configured to convert CO in the stream to CO.sub.2 and a membrane section located downstream of and in flow communication with the catalyst section. The membrane section is configured to selectively remove the CO.sub.2 from the stream and to be in flow communication with a sweep gas.

A simulation of streaming flows associated with acoustic levitators

NASA Astrophysics Data System (ADS)

Rednikov, A.; Riley, N.

2002-04-01

Steady-state acoustic streaming flow patterns have been observed by Trinh and Robey [Phys. Fluids 6, 3567 (1994)], during the operation of a variety of single axis ultrasonic levitators in a gaseous environment. Microstreaming around levitated samples is superimposed on the streaming flow which is observed in the levitator even in the absence of any particle therein. In this paper, by physical arguments, numerical and analytical simulations we provide entirely satisfactory interpretations of the observed flow patterns in both isothermal and nonisothermal situations.

PREFACE: Ionic fluids Ionic fluids

NASA Astrophysics Data System (ADS)

Levin, Yan; Kornyshev, Alexei; Barbosa, Marcia C.

2009-10-01

In spite of its apparent simplicity Coulomb law, when applied to many body systems, leads to an amazingly rich mathematical structure. The simple idea that two similarly charged objects always repel, is not necessarily true in a colloidal suspension or a dusty plasma. Neither can one simply predict the direction of the electrophoretic motion of a polyion from only knowing its chemical charge. Strong Coulomb correlations in ionic fluids result in instabilities very similar to the gas--liquid phase separation observed in atomic fluids. It is fair to say that bulk behavior of simple aqueous monovalent electrolytes is now very well understood. Unfortunately this is not the case for multivalent electrolytes or molten salts. In these systems cation-anion association leads to strong non-linear effects which manifest themselves in formations of tightly bound ionic clusters. In spite of the tremendous effort invested over the years, our understanding of these systems remains qualitative. In this special issue we have collected articles from some of the biggest experts working on ionic fluids. The papers are both experimental and theoretical. They range from simple electrolytes in the bulk and near interfaces, to polyelectrolytes, colloids, and molten salts. The special issue, covers a wide spectrum of the ongoing research on ionic fluids. All readers should find something of interest here.

A numerically efficient damping model for acoustic resonances in microfluidic cavities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hahn, P., E-mail: hahnp@ethz.ch; Dual, J.

Bulk acoustic wave devices are typically operated in a resonant state to achieve enhanced acoustic amplitudes and high acoustofluidic forces for the manipulation of microparticles. Among other loss mechanisms related to the structural parts of acoustofluidic devices, damping in the fluidic cavity is a crucial factor that limits the attainable acoustic amplitudes. In the analytical part of this study, we quantify all relevant loss mechanisms related to the fluid inside acoustofluidic micro-devices. Subsequently, a numerical analysis of the time-harmonic visco-acoustic and thermo-visco-acoustic equations is carried out to verify the analytical results for 2D and 3D examples. The damping results aremore » fitted into the framework of classical linear acoustics to set up a numerically efficient device model. For this purpose, all damping effects are combined into an acoustofluidic loss factor. Since some components of the acoustofluidic loss factor depend on the acoustic mode shape in the fluid cavity, we propose a two-step simulation procedure. In the first step, the loss factors are deduced from the simulated mode shape. Subsequently, a second simulation is invoked, taking all losses into account. Owing to its computational efficiency, the presented numerical device model is of great relevance for the simulation of acoustofluidic particle manipulation by means of acoustic radiation forces or acoustic streaming. For the first time, accurate 3D simulations of realistic micro-devices for the quantitative prediction of pressure amplitudes and the related acoustofluidic forces become feasible.« less

Oil Based Drilling Fluid Waste: An Overview on Environmentally Persistent Pollutants

NASA Astrophysics Data System (ADS)

Siddique, Shohel; Kwoffie, Lorraine; Addae-Afoakwa, Kofi; Yates, Kyari; Njuguna, James

2017-05-01

Operational discharges of spent drilling fluid, produced water, and accumulated drill cuttings from oil and gas industry are a continuous point source of environmental pollution. To meet the strict environmental standard for waste disposal, oil and gas industry is facing a numerous challenges in technological development to ensure a clean and safe environment. Oil and gas industry generates a large amount of spent drilling fluid, produced water, and drill cuttings, which are very different in every drilling operation in terms of composition and characterisation. This review article highlights the knowledge gap in identifying the different sources of waste streams in combined drilling waste. This paper also emphasises how different chemicals turn into environmentally significant pollutants after serving great performance in oil and gas drilling operations. For instance, oil based drilling fluid performs excellent in deeper drilling and drilling in the harsh geological conditions, but ended with (produces) a significant amount of persistent toxic pollutants in the environment. This review paper provides an overview on the basic concepts of drilling fluids and their functions, sources and characterisation of drilling wastes, and highlights some environmentally significant elements including different minerals present in drilling waste stream.

Bulk data transfer distributer: a high performance multicast model in ALMA ACS

NASA Astrophysics Data System (ADS)

Cirami, R.; Di Marcantonio, P.; Chiozzi, G.; Jeram, B.

2006-06-01

A high performance multicast model for the bulk data transfer mechanism in the ALMA (Atacama Large Millimeter Array) Common Software (ACS) is presented. The ALMA astronomical interferometer will consist of at least 50 12-m antennas operating at millimeter wavelength. The whole software infrastructure for ALMA is based on ACS, which is a set of application frameworks built on top of CORBA. To cope with the very strong requirements for the amount of data that needs to be transported by the software communication channels of the ALMA subsystems (a typical output data rate expected from the Correlator is of the order of 64 MB per second) and with the potential CORBA bottleneck due to parameter marshalling/de-marshalling, usage of IIOP protocol, etc., a transfer mechanism based on the ACE/TAO CORBA Audio/Video (A/V) Streaming Service has been developed. The ACS Bulk Data Transfer architecture bypasses the CORBA protocol with an out-of-bound connection for the data streams (transmitting data directly in TCP or UDP format), using at the same time CORBA for handshaking and leveraging the benefits of ACS middleware. Such a mechanism has proven to be capable of high performances, of the order of 800 Mbits per second on a 1Gbit Ethernet network. Besides a point-to-point communication model, the ACS Bulk Data Transfer provides a multicast model. Since the TCP protocol does not support multicasting and all the data must be correctly delivered to all ALMA subsystems, a distributer mechanism has been developed. This paper focuses on the ACS Bulk Data Distributer, which mimics a multicast behaviour managing data dispatching to all receivers willing to get data from the same sender.

Microfluidic Devices for Analysis of Spatial Orientation Behaviors in Semi-Restrained Caenorhabditis elegans

PubMed Central

McCormick, Kathryn E.; Gaertner, Bryn E.; Sottile, Matthew; Phillips, Patrick C.; Lockery, Shawn R.

2011-01-01

This article describes the fabrication and use of microfluidic devices for investigating spatial orientation behaviors in nematode worms (Caenorhabditis elegans). Until now, spatial orientation has been studied in freely moving nematodes in which the frequency and nature of encounters with the gradient are uncontrolled experimental variables. In the new devices, the nematode is held in place by a restraint that aligns the longitudinal axis of the body with the border between two laminar fluid streams, leaving the animal's head and tail free to move. The content of the fluid streams can be manipulated to deliver step gradients in space or time. We demonstrate the utility of the device by identifying previously uncharacterized aspects of the behavioral mechanisms underlying chemotaxis, osmotic avoidance, and thermotaxis in this organism. The new devices are readily adaptable to behavioral and imaging studies involving fluid borne stimuli in a wide range of sensory modalities. PMID:22022437

The Boundary Layer Flows of a Rivlin-Ericksen Fluid

NASA Astrophysics Data System (ADS)

Sadeghy, K.; Khabazi, N.; Taghavi, S. M.

The present work deals with the two-dimensional incompressible, laminar, steady-state boundary layer equations. First, we determine a family of velocity distributions outside the boundary layer such that these problems may have similarity solutions. We study the Falkner-Skan flow of a viscoelastic fluid governed by second order model, as the Reynolds number Re→ ∞. We obtain an ordinary forth order differential equation to obtain the stream function, velocity profile and the stress. The stream function is then governed by a generalized Falkner-Skan equation. In comparison with Newtonian Falkner-Skan equation that has two coefficients this new one has four coefficients that two of them represent elastic properties of the fluid. The effects of the elastic parameter on the velocity filed have been discussed. As it is shown in the figure there is a good agreement between numerical results and previous special cases confirm the validity of the presented algorithm.

Mixing high-viscosity fluids via acoustically driven bubbles

NASA Astrophysics Data System (ADS)

Orbay, Sinem; Ozcelik, Adem; Lata, James; Kaynak, Murat; Wu, Mengxi; Huang, Tony Jun

2017-01-01

We present an acoustofluidic micromixer which can perform rapid and homogeneous mixing of highly viscous fluids in the presence of an acoustic field. In this device, two high-viscosity polyethylene glycol (PEG) solutions were co-injected into a three-inlet PDMS microchannel with the center inlet containing a constant stream of nitrogen flow which forms bubbles in the device. When these bubbles were excited by an acoustic field generated via a piezoelectric transducer, the two solutions mixed homogenously due to the combination of acoustic streaming, droplet ejection, and bubble eruption effects. The mixing efficiency of this acoustofluidic device was evaluated using PEG-700 solutions which are ~106 times more viscous than deionized (DI) water. Our results indicate homogenous mixing of the PEG-700 solutions with a ~0.93 mixing index. The acoustofluidic micromixer is compact, inexpensive, easy to operate, and has the capacity to mix highly viscous fluids within 50 ms.

Streaming and particle motion in acoustically-actuated leaky systems

NASA Astrophysics Data System (ADS)

Nama, Nitesh; Barnkob, Rune; Jun Huang, Tony; Kahler, Christian; Costanzo, Francesco

2017-11-01

The integration of acoustics with microfluidics has shown great promise for applications within biology, chemistry, and medicine. A commonly employed system to achieve this integration consists of a fluid-filled, polymer-walled microchannel that is acoustically actuated via standing surface acoustic waves. However, despite significant experimental advancements, the precise physical understanding of such systems remains a work in progress. In this work, we investigate the nature of acoustic fields that are setup inside the microchannel as well as the fundamental driving mechanism governing the fluid and particle motion in these systems. We provide an experimental benchmark using state-of-art 3D measurements of fluid and particle motion and present a Lagrangian velocity based temporal multiscale numerical framework to explain the experimental observations. Following verification and validation, we employ our numerical model to reveal the presence of a pseudo-standing acoustic wave that drives the acoustic streaming and particle motion in these systems.

High energy power-law tail in X-ray binaries and bulk Comptonization due to an outflow from a disk

NASA Astrophysics Data System (ADS)

Kumar, Nagendra

2018-02-01

We study the high energy power-law tail emission of X-ray binaries (XRBs) by a bulk Comptonization process which is usually observed in the very high soft (VHS) state of black hole (BH) XRBs and the high soft (HS) state of the neutron star (NS) and BH XRBs. Earlier, to generate the power-law tail in bulk Comptonization framework, a free-fall converging flow into BH or NS had been considered as a bulk region. In this work, for a bulk region we consider mainly an outflow geometry from the accretion disk which is bounded by a torus surrounding the compact object. We have two choices for an outflow geometry: (i) collimated flow and (ii) conical flow of opening angle θ _b and the axis is perpendicular to the disk. We also consider an azimuthal velocity of the torus fluids as a bulk motion where the fluids are rotating around the compact object (a torus flow). We find that the power-law tail can be generated in a torus flow having large optical depth and bulk speed (>0.75 c), and in conical flow with θ _b > ˜ 30° for a low value of Comptonizing medium temperature. Particularly, in conical flow the low opening angle is more favourable to generate the power-law tail in both the HS state and the VHS state. We notice that when the outflow is collimated, then the emergent spectrum does not have power-law component for a low Comptonizing medium temperature.

Molecular modeling the microstructure and phase behavior of bulk and inhomogeneous complex fluids

NASA Astrophysics Data System (ADS)

Bymaster, Adam

Accurate prediction of the thermodynamics and microstructure of complex fluids is contingent upon a model's ability to capture the molecular architecture and the specific intermolecular and intramolecular interactions that govern fluid behavior. This dissertation makes key contributions to improving the understanding and molecular modeling of complex bulk and inhomogeneous fluids, with an emphasis on associating and macromolecular molecules (water, hydrocarbons, polymers, surfactants, and colloids). Such developments apply broadly to fields ranging from biology and medicine, to high performance soft materials and energy. In the bulk, the perturbed-chain statistical associating fluid theory (PC-SAFT), an equation of state based on Wertheim's thermodynamic perturbation theory (TPT1), is extended to include a crossover correction that significantly improves the predicted phase behavior in the critical region. In addition, PC-SAFT is used to investigate the vapor-liquid equilibrium of sour gas mixtures, to improve the understanding of mercaptan/sulfide removal via gas treating. For inhomogeneous fluids, a density functional theory (DFT) based on TPT1 is extended to problems that exhibit radially symmetric inhomogeneities. First, the influence of model solutes on the structure and interfacial properties of water are investigated. The DFT successfully describes the hydrophobic phenomena on microscopic and macroscopic length scales, capturing structural changes as a function of solute size and temperature. The DFT is used to investigate the structure and effective forces in nonadsorbing polymer-colloid mixtures. A comprehensive study is conducted characterizing the role of polymer concentration and particle/polymer size ratio on the structure, polymer induced depletion forces, and tendency towards colloidal aggregation. The inhomogeneous form of the association functional is used, for the first time, to extend the DFT to associating polymer systems, applicable to any association scheme. Theoretical results elucidate how reversible bonding governs the structure of a fluid near a surface and in confined environments, the molecular connectivity (formation of supramolecules, star polymers, etc.) and the phase behavior of the system. Finally, the DFT is extended to predict the inter- and intramolecular correlation functions of polymeric fluids. A theory capable of providing such local structure is important to understanding how local chemistry, branching, and bond flexibility affect the thermodynamic properties of polymers.

Application of wave mechanics theory to fluid dynamics problems: Boundary layer on a circular cylinder including turbulence

NASA Technical Reports Server (NTRS)

Krzywoblocki, M. Z. V.

1974-01-01

The application of the elements of quantum (wave) mechanics to some special problems in the field of macroscopic fluid dynamics is discussed. Emphasis is placed on the flow of a viscous, incompressible fluid around a circular cylinder. The following subjects are considered: (1) the flow of a nonviscous fluid around a circular cylinder, (2) the restrictions imposed the stream function by the number of dimensions of space, and (3) the flow past three dimensional bodies in a viscous fluid, particularly past a circular cylinder in the symmetrical case.

Dissolved rainfall inputs and streamwater outputs in an undisturbed watershed on highly weathered soils in the Brazilian cerrado

NASA Astrophysics Data System (ADS)

Markewitz, Daniel; Resende, Julio C. F.; Parron, Lucilia; Bustamante, Mercedes; Klink, Carlos A.; Figueiredo, Ricardo De O.; Davidson, Eric A.

2006-08-01

The cerrados of Brazil cover 2 million km2. Despite the extent of these seasonally dry ecosystems, little watershed research has been focused in this region, particularly relative to the watersheds of the Amazon Basin. The cerrado shares pedogenic characteristics with the Amazon Basin in draining portions of the Brazilian shield and in possessing Oxisols over much of the landscape. The objective of this research was to quantify the stream water geochemical relationships of an undisturbed 1200 ha cerrado watershed for comparison to river geochemistry in the Amazon. Furthermore, this undisturbed watershed was used to evaluate stream discharge versus dissolved ion concentration relationships. This research was conducted in the Córrego Roncador watershed of the Reserva Ecológica do Roncador (RECOR) of the Instituto Brasileiro Geografia e Estatística (IBGE) near Brasilia, Brazil. Bulk precipitation and stream water chemistry were analysed between May 1998 and May 2000. The upland soils of this watershed are nutrient poor possessing total stocks of exchangeable elements in the upper 1 m of 81 +/- 13, 77 +/- 4, 25 +/- 3, and 1 +/- 1 kg ha-1 of K, Ca, Mg, and P, respectively. Bulk precipitation inputs of dissolved nutrients for this watershed are low and consistent with previous estimates. The nutrient-poor soils of this watershed, however, increase the relative importance of precipitation for nutrient replenishment to vegetation during episodes of ecosystem disturbance. Stream water dissolved loads were extremely dilute with conductivities ranging from 4 to 10 μS cm-1 during periods of high- and low-flow, respectively. Despite the low concentrations in this stream, geochemical relationships were similar to other Amazonian streams draining shield geologies. Discharge-concentration relationships for Ca and Mg in these highly weathered soils developed from igneous rocks of the Brazilian shield demonstrated a significant negative relationship indicating a continued predominance of groundwater baseflow contributions these cationic elements.

Filling in the Gaps: Xenoliths in Meteorites are Samples of "Missing" Asteroid Lithologies

NASA Technical Reports Server (NTRS)

Zolensky, Mike

2016-01-01

We know that the stones that fall to earth as meteorites are not representative of the full diversity of small solar system bodies, because of the peculiarities of the dynamical processes that send material into Earth-crossing paths [1] which result in severe selection biases. Thus, the bulk of the meteorites that fall are insufficient to understand the full range of early solar system processes. However, the situation is different for pebble- and smaller-sized objects that stream past the giant planets and asteroid belts into the inner solar system in a representative manner. Thus, micrometeorites and interplanetary dust particles have been exploited to permit study of objects that do not provide meteorites to earth. However, there is another population of materials that sample a larger range of small solar system bodies, but which have received little attention - pebble-sized foreign clasts in meteorites (also called xenoliths, dark inclusions, clasts, etc.). Unfortunately, most previous studies of these clasts have been misleading, in that these objects have simply been identified as pieces of CM or CI chondrites. In our work we have found this to be generally erroneous, and that CM and especially CI clasts are actually rather rare. We therefore test the hypothesis that these clasts sample the full range of small solar system bodies. We have located and obtained samples of clasts in 81 different meteorites, and have begun a thorough characterization of the bulk compositions, mineralogies, petrographies, and organic compositions of this unique sample set. In addition to the standard e-beam analyses, recent advances in technology now permit us to measure bulk O isotopic compositions, and major- though trace-element compositions of the sub-mm-sized discrete clasts. Detailed characterization of these clasts permit us to explore the full range of mineralogical and petrologic processes in the early solar system, including the nature of fluids in the Kuiper belt and the outer main asteroid belt, as revealed by the mineralogy of secondary phases.

The composition-explicit distillation curve technique: Relating chemical analysis and physical properties of complex fluids.

PubMed

Bruno, Thomas J; Ott, Lisa S; Lovestead, Tara M; Huber, Marcia L

2010-04-16

The analysis of complex fluids such as crude oils, fuels, vegetable oils and mixed waste streams poses significant challenges arising primarily from the multiplicity of components, the different properties of the components (polarity, polarizability, etc.) and matrix properties. We have recently introduced an analytical strategy that simplifies many of these analyses, and provides the added potential of linking compositional information with physical property information. This aspect can be used to facilitate equation of state development for the complex fluids. In addition to chemical characterization, the approach provides the ability to calculate thermodynamic properties for such complex heterogeneous streams. The technique is based on the advanced distillation curve (ADC) metrology, which separates a complex fluid by distillation into fractions that are sampled, and for which thermodynamically consistent temperatures are measured at atmospheric pressure. The collected sample fractions can be analyzed by any method that is appropriate. The analytical methods we have applied include gas chromatography (with flame ionization, mass spectrometric and sulfur chemiluminescence detection), thin layer chromatography, FTIR, corrosivity analysis, neutron activation analysis and cold neutron prompt gamma activation analysis. By far, the most widely used analytical technique we have used with the ADC is gas chromatography. This has enabled us to study finished fuels (gasoline, diesel fuels, aviation fuels, rocket propellants), crude oils (including a crude oil made from swine manure) and waste oils streams (used automotive and transformer oils). In this special issue of the Journal of Chromatography, specifically dedicated to extraction technologies, we describe the essential features of the advanced distillation curve metrology as an analytical strategy for complex fluids. Published by Elsevier B.V.

Molten salt destruction of energetic waste materials

DOEpatents

Brummond, W.A.; Upadhye, R.S.; Pruneda, C.O.

1995-07-18

A molten salt destruction process is used to treat and destroy energetic waste materials such as high explosives, propellants, and rocket fuels. The energetic material is pre-blended with a solid or fluid diluent in safe proportions to form a fluid fuel mixture. The fuel mixture is rapidly introduced into a high temperature molten salt bath. A stream of molten salt is removed from the vessel and may be recycled as diluent. Additionally, the molten salt stream may be pumped from the reactor, circulated outside the reactor for further processing, and delivered back into the reactor or cooled and circulated to the feed delivery system to further dilute the fuel mixture entering the reactor. 4 figs.

Molten salt destruction of energetic waste materials

DOEpatents

Brummond, William A.; Upadhye, Ravindra S.; Pruneda, Cesar O.

1995-01-01

A molten salt destruction process is used to treat and destroy energetic waste materials such as high explosives, propellants, and rocket fuels. The energetic material is pre-blended with a solid or fluid diluent in safe proportions to form a fluid fuel mixture. The fuel mixture is rapidly introduced into a high temperature molten salt bath. A stream of molten salt is removed from the vessel and may be recycled as diluent. Additionally, the molten salt stream may be pumped from the reactor, circulated outside the reactor for further processing, and delivered back into the reactor or cooled and circulated to the feed delivery system to further dilute the fuel mixture entering the reactor.

Hybrid biological, electron beam and zero-valent nano iron treatment of recalcitrant metalworking fluids.

PubMed

Thill, Patrick G; Ager, Duane K; Vojnovic, Borivoj; Tesh, Sarah J; Scott, Thomas B; Thompson, Ian P

2016-04-15

Hybrid approaches for the remediation and detoxification of toxic recalcitrant industrial wastewater were investigated. The focus was waste metalworking fluid, which was selected as a representative model of other waste streams that are toxic, recalcitrant and that require more sustainable routes of safe disposal. The hybrid approaches included biodegradation, electron beam irradiation and zero-valent nano iron advanced oxidation processes that were employed individually and in sequence employing a factorial design. To compare process performance operationally exhausted and pristine metalworking fluid were compared. Sequential hybrid electron beam irradiation, biological, nanoscale zero-valent iron and biological treatment lead to synergistic detoxification and degradation of both recalcitrant streams, as determined by complementary surrogates and lead to overall improved COD removal of 92.8 ± 1.4% up from 85.9 ± 3.4% for the pristine metalworking fluid. Electron beam pre-treatment enabled more effective biotreatment, achieving 69.5 ± 8% (p = 0.005) and 24.6 ± 4.8% (p = 0.044) COD reductions. Copyright © 2016. Published by Elsevier Ltd.

Streaming potential modeling in fractured rock: Insights into the identification of hydraulically active fractures

NASA Astrophysics Data System (ADS)

Roubinet, D.; Linde, N.; Jougnot, D.; Irving, J.

2016-05-01

Numerous field experiments suggest that the self-potential (SP) geophysical method may allow for the detection of hydraulically active fractures and provide information about fracture properties. However, a lack of suitable numerical tools for modeling streaming potentials in fractured media prevents quantitative interpretation and limits our understanding of how the SP method can be used in this regard. To address this issue, we present a highly efficient two-dimensional discrete-dual-porosity approach for solving the fluid flow and associated self-potential problems in fractured rock. Our approach is specifically designed for complex fracture networks that cannot be investigated using standard numerical methods. We then simulate SP signals associated with pumping conditions for a number of examples to show that (i) accounting for matrix fluid flow is essential for accurate SP modeling and (ii) the sensitivity of SP to hydraulically active fractures is intimately linked with fracture-matrix fluid interactions. This implies that fractures associated with strong SP amplitudes are likely to be hydraulically conductive, attracting fluid flow from the surrounding matrix.

DOE Waste Treatability Group Guidance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kirkpatrick, T.D.

1995-01-01

This guidance presents a method and definitions for aggregating U.S. Department of Energy (DOE) waste into streams and treatability groups based on characteristic parameters that influence waste management technology needs. Adaptable to all DOE waste types (i.e., radioactive waste, hazardous waste, mixed waste, sanitary waste), the guidance establishes categories and definitions that reflect variations within the radiological, matrix (e.g., bulk physical/chemical form), and regulated contaminant characteristics of DOE waste. Beginning at the waste container level, the guidance presents a logical approach to implementing the characteristic parameter categories as part of the basis for defining waste streams and as the solemore » basis for assigning streams to treatability groups. Implementation of this guidance at each DOE site will facilitate the development of technically defined, site-specific waste stream data sets to support waste management planning and reporting activities. Consistent implementation at all of the sites will enable aggregation of the site-specific waste stream data sets into comparable national data sets to support these activities at a DOE complex-wide level.« less

Progress Toward Quality Assurance Standards for Advanced Hydrocarbon Fuels Based on Thermal Performance Testing and Chemometric Modeling

DTIC Science & Technology

2015-12-15

axial direction; v – fluid velocity; Twc – wall temperature; Tb – fuel bulk temperature; q″ – heat flux ; ρ – fluid density. INTRODUCTION In...and cyclic paraffins ] and distribution are not. Chromatograms demonstrating RP compositional variability are shown in Fig. 2 alongside aviation

Venous compliance and fluid shift measurements on Spacelab IML-1

NASA Technical Reports Server (NTRS)

Leiski, D.; Thirsk, R. B.; Charles, J. B.; Bennett, B.

1992-01-01

During the first few hours of a human spaceflight mission, a headward fluid shift out of the abdomen, pelvis, and legs initiates a number of adaptive cardiovascular responses, including a loss of intravascular and extravascular fluid volume. On return to earth, these cardiovascular changes may lead to debilitating symptoms of orthostatic intolerance in an unprotected astronaut. To test the hypothesis that an inflight increase in compliance of the leg veins may contribute to this condition, measurements of lower leg fluid shift and bulk venous compliance were collected from crew members during the eight-day First International Microgravity Laboratory shuttle mission. An ultrasonic limb plethysmograph, in conjunction with two compression cuffs encircling the calf and thigh, was used to determine bulk compliance of the underlying veins over a range of negative and positive transmural pressures. The data from inflight experiment sessions were compared to preflight and postflight sessions. The preliminary results indicate that the volume of the lower leg decreased by over 10 percent by the sixth day of flight, but there was no apparent change in venous compliance.

Smectite diagenesis, pore-water freshening, and fluid flow at the toe of the Nankai wedge

USGS Publications Warehouse

Brown, K.M.; Saffer, D.M.; Bekins, B.A.

2001-01-01

The presence of low-chloride fluids in the lowermost sediments drilled at Ocean Drilling Program Site 808, at the Nankai accretionary wedge, has been considered as prime evidence for long-distance, lateral fluid flow from depth. Here, we re-evaluate the potential role of in situ reaction of smectite (S) to illite (I) in the genesis of this low chloride anomaly. This reaction is known to be occurring at Site 808, with both the S content and S to I ratio in the mixed layer clays decreasing substantially with depth. We show that the bulk of the chloride anomaly can generate by in situ clay dehydration, particularly if pre-reaction smectite abundances (Ai) approach ?? 10-15% of the bulk sediment. The Ai values, however, are not well constrained. At Ai values < 10-15%, an additional source of low-Cl fluid centered close to the de??collement could be required. Thus, there remains the important possibility that the observed low-Cl anomaly is a compound effect of both lateral flow and in situ smectite dehydration. ?? 2001 Elsevier Science B.V. All rights reserved.

Tritium release from SS316 under vacuum condition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Torikai, Y.; Penzhorn, R.D.

The plasma facing surface of the ITER vacuum vessel, partly made of low carbon austenitic stainless steel type 316L, will incorporate tritium during machine operation. In this paper the kinetics of tritium release from stainless steel type 316 into vacuum and into a noble gas stream are compared and modelled. Type 316 stainless steel specimens loaded with tritium either by exposure to 1.2 kPa HT at 573 K or submersion into liquid HTO at 298 K showed characteristic thin surface layers trapping tritium in concentrations far higher than those determined in the bulk. The evolution of the tritium depth profilemore » in the bulk during heating under vacuum was non-discernible from that of tritium liberated into a stream of argon. Only the relative amount of the two released tritium-species, i.e. HT or HTO, was different. Temperature-dependent depth profiles could be predicted with a one-dimensional diffusion model. Diffusion coefficients derived from fitting of the tritium release into an evacuated vessel or a stream of argon were found to be (1.4 ± 1.0)*10{sup -7} and (1.3 ± 0.9)*10{sup -9} cm{sup 2}/s at 573 and 423 K, respectively. Polished surfaces on type SS316 stainless steel inhibit considerably the thermal release rate of tritium.« less

Quantification of CO2-FLUID-ROCK Reactions Using Reactive and Non-Reactive Tracers

NASA Astrophysics Data System (ADS)

Matter, J.; Stute, M.; Hall, J. L.; Mesfin, K. G.; Gislason, S. R.; Oelkers, E. H.; Sigfússon, B.; Gunnarsson, I.; Aradottir, E. S.; Alfredsson, H. A.; Gunnlaugsson, E.; Broecker, W. S.

2013-12-01

Carbon dioxide mineralization via fluid-rock reactions provides the most effective and long-term storage option for geologic carbon storage. Injection of CO2 in geologic formations induces CO2 -fluid-rock reactions that may enhance or decrease the storage permanence and thus the long-term safety of geologic carbon storage. Hence, quantitative characterization of critical CO2 -fluid-rock interactions is essential to assess the storage efficiency and safety of geologic carbon storage. In an attempt to quantify in-situ fluid-rock reactions and CO2 transport relevant for geologic carbon storage, we are testing reactive (14C, 13C) and non-reactive (sodium fluorescein, amidorhodamine G, SF5CF3, and SF6) tracers in an ongoing CO2 injection in a basaltic storage reservoir at the CARBFIX pilot injection site in Iceland. At the injection site, CO2 is dissolved in groundwater and injected into a permeable basalt formation located 500-800 m below the surface [1]. The injected CO2 is labeled with 14C by dynamically adding calibrated amounts of H14CO3-solution into the injection stream in addition to the non-reactive tracers. Chemical and isotopic analyses of fluid samples collected in a monitoring well, reveal fast fluid-rock reactions. Maximum SF6 concentration in the monitoring well indicates the bulk arrival of the injected CO2 solution but dissolved inorganic carbon (DIC) concentration and pH values close to background, and a potentially lower 14C to SF6 ratio than the injection ratio suggest that most of the injected CO2 has reacted with the basaltic rocks. This is supported by δ13CDIC, which shows a drop from values close to the δ 13C of the injected CO2 gas (-3‰ VPDB) during breakthrough of the CO2 plume to subsequent more depleted values (-11.25‰ VPDB), indicating precipitation of carbonate minerals. Preliminary mass balance calculations using mixing relationships between the background water in the storage formation and the injected solution, suggest that approximately 85% of the injected CO2 must have reacted along the flow path from the injection well to the monitoring well within less than one year. Monitoring is still going on and we will extend the time series and the mass balance accordingly. Our study demonstrates that by combining reactive and non-reactive tracers, we are able to quantify CO2-fluid-rock interactions on a reservoir scale. [1] Gislason et al. (2010), Int. J. Greenh. Gas Con. 4, 537-545.

Reductant injection and mixing system

DOEpatents

Reeves, Matt; Henry, Cary A.; Ruth, Michael J.

2016-02-16

A gaseous reductant injection and mixing system is described herein. The system includes an injector for injecting a gaseous reductant into an exhaust gas stream, and a mixer attached to a surface of the injector. The injector includes a plurality of apertures through which the gaseous reductant is injected into an exhaust gas stream. The mixer includes a plurality of fluid deflecting elements.

Static analysis of a sonar dome rubber window

NASA Technical Reports Server (NTRS)

Lai, J. L.

1978-01-01

The application of NASTRAN (level 16.0.1) to the static analysis of a sonar dome rubber window (SDRW) was demonstrated. The assessment of the conventional model (neglecting the enclosed fluid) for the stress analysis of the SDRW was made by comparing its results to those based on a sophisticated model (including the enclosed fluid). The fluid was modeled with isoparametric linear hexahedron elements with approximate material properties whose shear modulus was much smaller than its bulk modulus. The effect of the chosen material property for the fluid is discussed.

Fluid Dynamics for Physicists

NASA Astrophysics Data System (ADS)

Faber, T. E.

1995-08-01

This textbook provides an accessible and comprehensive account of fluid dynamics that emphasizes fundamental physical principles and stresses connections with other branches of physics. Beginning with a basic introduction, the book goes on to cover many topics not typically treated in texts, such as compressible flow and shock waves, sound attenuation and bulk viscosity, solitary waves and ship waves, thermal convection, instabilities, turbulence, and the behavior of anisotropic, non-Newtonian and quantum fluids. Undergraduate or graduate students in physics or engineering who are taking courses in fluid dynamics will find this book invaluable.

On the structure of the two-stream instability–complex G-Hamiltonian structure and Krein collisions between positive- and negative-action modes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Ruili; Liu, Jian; Xiao, Jianyuan

2016-07-15

The two-stream instability is probably the most important elementary example of collective instabilities in plasma physics and beam-plasma systems. For a warm plasma with two charged particle species, the instability diagram of the two-stream instability based on a 1D warm-fluid model exhibits an interesting band structure that has not been explained. We show that the band structure for this instability is the consequence of the Hamiltonian nature of the warm two-fluid system. Interestingly, the Hamiltonian nature manifests as a complex G-Hamiltonian structure in wave-number space, which directly determines the instability diagram. Specifically, it is shown that the boundaries between themore » stable and unstable regions are locations for Krein collisions between eigenmodes with different Krein signatures. In terms of physics, this rigorously implies that the system is destabilized when a positive-action mode resonates with a negative-action mode, and that this is the only mechanism by which the system can be destabilized. It is anticipated that this physical mechanism of destabilization is valid for other collective instabilities in conservative systems in plasma physics, accelerator physics, and fluid dynamics systems, which admit infinite-dimensional Hamiltonian structures.« less

An analytical approach to fluid ratcheting in oscillatory boundary layer

NASA Astrophysics Data System (ADS)

Yu, Jie

2013-11-01

It is well known that oscillatory flows close to a rigid or flexible boundary induces a steady streaming due to viscosity. Under progressive motions, this becomes a unidirectional streaming near the boundary (e.g. mass transport or peristaltic pumping in water waves). This mechanism is shared by the phenomenon of ratcheting fluid in a narrow channel by vibrating the channel walls that are lined with asymmetric corrugations (shown by a recent experiment BAPS.2010.DFD.HC.3). A theory is presented here to describe the ratcheting effects in such a channel. A conformal transformation method, developed for waves over arbitrary periodic topographies (Yu & Howard, J. Fluid Mech. 2012), is adapted to deal with large corrugations of the channel walls. Under the assumption that the wall oscillations are of small amplitude, the vorticity dynamics can be analyzed in the mapped plane, obtaining the solution that describes the steady streaming field due to nonlinear convective inertia. The results are discussed, regarding the dependency of the pumping direction on the oscillation frequency of the walls and the effects of the end position relative to the phase of corrugations in the case of a finite length channel. Preliminary experimental data will be presented if time permits. Support by NFS (Grant CBET-0845957) during the period of this work is gratefully acknowledged.

A framework for estimating potential fluid flow from digital imagery

NASA Astrophysics Data System (ADS)

Luttman, Aaron; Bollt, Erik M.; Basnayake, Ranil; Kramer, Sean; Tufillaro, Nicholas B.

2013-09-01

Given image data of a fluid flow, the flow field, ⟨u,v⟩, governing the evolution of the system can be estimated using a variational approach to optical flow. Assuming that the flow field governing the advection is the symplectic gradient of a stream function or the gradient of a potential function—both falling under the category of a potential flow—it is natural to re-frame the optical flow problem to reconstruct the stream or potential function directly rather than the components of the flow individually. There are several advantages to this framework. Minimizing a functional based on the stream or potential function rather than based on the components of the flow will ensure that the computed flow is a potential flow. Next, this approach allows a more natural method for imposing scientific priors on the computed flow, via regularization of the optical flow functional. Also, this paradigm shift gives a framework—rather than an algorithm—and can be applied to nearly any existing variational optical flow technique. In this work, we develop the mathematical formulation of the potential optical flow framework and demonstrate the technique on synthetic flows that represent important dynamics for mass transport in fluid flows, as well as a flow generated by a satellite data-verified ocean model of temperature transport.

Aluminum in Precipitation, Streams, and Shallow Groundwater in the New Jersey Pine Barrens

NASA Astrophysics Data System (ADS)

Budd, W. W.; Johnson, A. H.; Huss, J. B.; Turner, R. S.

1981-08-01

Total (acid reactive) aluminum deposited in bulk precipitation in the McDonalds Branch (New Jersey) basin was 140 mg m-2 yr-1 for the period May 1978-May 1980. Stream and groundwater outputs for the same period were 149 and 110 mg m-2 yr-1, respectively. Aluminum inputs and outputs were highest during summer months because of elevated concentrations coupled with increased precipitation and streamflow. Median acid reactive Al concentrations in precipitation, stream water, and groundwater were 100, 350, and 230 μg 1-1, respectively. In streams, acid reactive Al concentration is correlated with dissolved organic matter concentration, suggesting that Al is transported as an organometallic complex. Shallow groundwater Al concentration is apparently controlled by gibbsite solubility in mineral soils and thus is pH dependent. The relatively high Al concentrations are attributable to acid conditions and mobile organic matter.

Prediction of the rate of the rise of an air bubble in nanofluids in a vertical tube.

PubMed

Cho, Heon Ki; Nikolov, Alex D; Wasan, Darsh T

2018-04-19

Our recent experiments have demonstrated that when a bubble rises through a nanofluid (a liquid containing dispersed nanoparticles) in a vertical tube, a nanofluidic film with several particle layers is formed between the gas bubble and the glass tube wall, which significantly changes the bubble velocity due to the nanoparticle layering phenomenon in the film. We calculated the structural nanofilm viscosity as a function of the number of particle layers confined in it and found that the film viscosity increases rather steeply when the film contains only one or two particle layers. The nanofilm viscosity was found to be several times higher than the bulk viscosity of the fluid. Consequently, the Bretherton equation cannot accurately predict the rate of the rise of a slow-moving long bubble in a vertical tube in a nanofluid because it is valid only for very thick films and uses the bulk viscosity of the fluid. However, in this brief note, we demonstrate that the Bretherton equation can indeed be used for predicting the rate of the rise of a long single bubble through a vertical tube filled with a nanofluid by simply replacing the bulk viscosity with the proper structural nanofilm viscosity of the fluid. Copyright © 2018. Published by Elsevier Inc.

The role of bulk viscosity on the decay of compressible, homogeneous, isotropic turbulence

NASA Astrophysics Data System (ADS)

Johnsen, Eric; Pan, Shaowu

2016-11-01

The practice of neglecting bulk viscosity in studies of compressible turbulence is widespread. While exact for monatomic gases and unlikely to strongly affect the dynamics of fluids whose bulk-to-shear viscosity ratio is small and/or of weakly compressible turbulence, this assumption is not justifiable for compressible, turbulent flows of gases whose bulk viscosity is orders of magnitude larger than their shear viscosities (e.g., CO2). To understand the mechanisms by which bulk viscosity and the associated phenomena affect compressible turbulence, we conduct DNS of freely decaying compressible, homogeneous, isotropic turbulence for ratios of bulk-to-shear viscosity ranging from 0-1000. Our simulations demonstrate that bulk viscosity increases the decay rate of turbulent kinetic energy; while enstrophy exhibits little sensitivity to bulk viscosity, dilatation is reduced by an order of magnitude within the two eddy turnover time. Via a Helmholtz decomposition of the flow, we determined that bulk viscosity damps the dilatational velocity and reduces dilatational-solenoidal exchanges, as well as pressure-dilatation coupling. In short, bulk viscosity renders compressible turbulence incompressible by reducing energy transfer between translational and internal modes.

Bulk Viscosity of Bubbly Magmas and the Amplification of Pressure Waves

NASA Astrophysics Data System (ADS)

Navon, O.; Lensky, N. G.; Neuberg, J. W.; Lyakhovsky, V.

2001-12-01

The bulk viscosity of magma is needed in order to describe the dynamics of a compressible bubbly magma flowing in conduits and to follow the attenuation of pressure waves travelling through a compressible magma. We developed a model for the bulk viscosity of a suspension of gas bubbles in an incompressible Newtonian liquid that exsolves volatiles (e.g. magma). The suspension is modeled as a close pack of spherical cells, consisting of gas bubbles centered in spherical shells of a volatile-bearing liquid. Following a drop in the ambient pressure the resulting dilatational motion and driving pressure are obtained in terms of the two-phase cell parameters, i.e. bubble radius and gas pressure. By definition, the bulk viscosity of a fluid is the relation between changes of the driving pressure with respect to changes in the resulted expansion strain-rate. Thus, we can use the two-phase solution to define the bulk viscosity of a hypothetical cell, composed of a homogeneously compressible, one-phase, continuous fluid. The resulted bulk viscosity is highly non-linear. At the beginning of the expansion process, when gas exsolution is efficient, the expansion rate grows exponentially while the driving pressure decreases slightly. That means that bulk viscosity is formally negative. The negative value reflects the release of the energy stored in the supersaturated liquid (melt) and its conversion to mechanical work during exsolution. Later, when bubbles are large enough and the gas influx decreases significantly, the strain rate decelerates and the bulk viscosity becomes positive as expected in a dissipative system. We demonstrate that amplification of seismic wave travelling through a volcanic conduit filled with a volatile saturated magma may be attributed to the negative bulk viscosity of the compressible magma. Amplification of an expansion wave may, at some level in the conduit, damage the conduit walls and initiate opening of new pathways for magma to erupt.

Fluid Mechanics and Heat Transfer in Transitional Boundary Layers

NASA Technical Reports Server (NTRS)

Wang, Ting

2007-01-01

Experiments have been performed to investigate the effects of elevated free-stream turbulence and streamwise acceleration on flow and thermal structures in transitional boundary layers. The free-stream turbulence ranges from 0.5 to 6.4% and the streamwise acceleration ranges from K = 0 to 0.8 x 10(exp -6). The onset of transition, transition length and the turbulent spot formation rate are determined. The statistical results and conditionally sampled results of th streamwise and cross-stream velocity fluctuations, temperature fluctuations, Reynolds stress and Reynolds heat fluxes are presented.

Electrokinetically induced alterations in dynamic response of viscoelastic fluids in narrow confinements.

PubMed

Bandopadhyay, Aditya; Chakraborty, Suman

2012-05-01

We investigate a dynamical interplay between interfacial electrokinetics and a combined dissipative and elastic behavior of flow through narrow confinements, in analogy with spatiotemporal hydrodynamics of porous media. In particular, we investigate the effects of streaming potential on the pertinent dynamic responses, by choosing a Maxwell fluid model for representing the consequent electro-hydrodynamic characteristics. We transform the pertinent governing equation to the frequency domain, so that a dynamic generalization of Darcy's law in the presence of streaming potential effects can be effectively realized. We show that the frequencies corresponding to local maxima in the dynamic permeability also correspond to local maxima in the induced streaming potential. We also bring out the effects of Stern layer conductivity on the dynamic permeability. Our analytical estimates do reveal that serious overestimations in the commonly portrayed notion of massive amplifications of dynamic permeability at resonating frequencies may be possible, if interactions between spontaneous electrochemical interfacial phenomena and pulsating pressure-gradient-driven viscoelastic transport are trivially ignored.

Lightweight moving radiators for heat rejection in space

NASA Technical Reports Server (NTRS)

Knapp, K.

1981-01-01

Low temperature droplet stream radiators, using nonmetallic fluids, can be used to radiate large amounts of waste heat from large space facilities. Moving belt radiators are suitable for use on a smaller scale, radiating as few as 10 kW from shuttle related operations. If appropriate seal technology can be developed, moving belt radiators may prove to be important for high temperature systems as well. Droplet stream radiators suitable for operation at peak temperatures near 300 K and 1000 K were studied using both freezing and nonfreezing droplets. Moving belt radiators were also investigated for operation in both temperature ranges. The potential mass and performance characteristics of both concepts were estimated on the basis of parametric variations of analytical point designs. These analyses included all consideration of the equipment required to operate the moving radiator system and take into account the mass of fluid lost by evaporation during mission lifetimes. Preliminary results indicate that low temperature droplet stream radiator appears to offer the greatest potential for improvement over conventional flat plate radiators.

Formation and Control of Fluidic Species

NASA Technical Reports Server (NTRS)

Link, Darren Roy (Inventor); Marquez-Sanchez, Manuel (Inventor); Cheng, Zhengdong (Inventor); Weitz, David A. (Inventor)

2015-01-01

This invention generally relates to systems and methods for the formation and/or control of fluidic species, and articles produced by such systems and methods. In some cases, the invention involves unique fluid channels, systems, controls, and/or restrictions, and combinations thereof. In certain embodiments, the invention allows fluidic streams (which can be continuous or discontinuous, i.e., droplets) to be formed and/or combined, at a variety of scales, including microfluidic scales. In one set of embodiments, a fluidic stream may be produced from a channel, where a cross-sectional dimension of the fluidic stream is smaller than that of the channel, for example, through the use of structural elements, other fluids, and/or applied external fields, etc. In some cases, a Taylor cone may be produced. In another set of embodiments, a fluidic stream may be manipulated in some fashion, for example, to create tubes (which may be hollow or solid), droplets, nested tubes or droplets, arrays of tubes or droplets, meshes of tubes, etc. In some cases, droplets produced using certain embodiments of the invention may be charged or substantially charged, which may allow their further manipulation, for instance, using applied external fields. Non-limiting examples of such manipulations include producing charged droplets, coalescing droplets (especially at the microscale), synchronizing droplet formation, aligning molecules within the droplet, etc. In some cases, the droplets and/or the fluidic streams may include colloids, cells, therapeutic agents, and the like.

Thermo-hydro-mechanical coupling in long-term sedimentary rock response

NASA Astrophysics Data System (ADS)

Makhnenko, R. Y.; Podladchikov, Y.

2017-12-01

Storage of nuclear waste or CO2 affects the state of stress and pore pressure in the subsurface and may induce large thermal gradients in the rock formations. In general, the associated coupled thermo-hydro-mechanical effect on long-term rock deformation and fluid flow have to be studied. Principles behind mathematical models for poroviscoelastic response are reviewed, and poroviscous model parameter, the bulk viscosity, is included in the constitutive equations. Time-dependent response (creep) of fluid-filled sedimentary rocks is experimentally quantified at isotropic stress states. Three poroelastic parameters are measured by drained, undrained, and unjacketed geomechanical tests for quartz-rich Berea sandstone, calcite-rich Apulian limestone, and clay-rich Jurassic shale. The bulk viscosity is calculated from the measurements of pore pressure growth under undrained conditions, which requires time scales 104 s. The bulk viscosity is reported to be on the order of 1015 Pa•s for the sandstone, limestone, and shale. It is found to be decreasing with the increase of pore pressure despite corresponding decrease in the effective stress. Additionally, increase of temperature (from 24 ºC to 40 ºC) enhances creep, where the most pronounced effect is reported for the shale with bulk viscosity decrease by a factor of 3. Viscous compaction of fluid-filled porous media allows a generation of a special type of fluid flow instability that leads to formation of high-porosity, high-permeability domains that are able to self-propagate upwards due to interplay between buoyancy and viscous resistance of the deforming porous matrix. This instability is known as "porosity wave" and its formation is possible under conditions applicable to deep CO2 storage in reservoirs and explains creation of high-porosity channels and chimneys. The reported experiments show that the formation of high-permeability pathways is most likely to occur in low-permeable clay-rich materials (caprock representatives) at elevated temperatures.

Heat recirculating cooler for fluid stream pollutant removal

DOEpatents

Richards, George A.; Berry, David A.

2008-10-28

A process by which heat is removed from a reactant fluid to reach the operating temperature of a known pollutant removal method and said heat is recirculated to raise the temperature of the product fluid. The process can be utilized whenever an intermediate step reaction requires a lower reaction temperature than the prior and next steps. The benefits of a heat-recirculating cooler include the ability to use known pollutant removal methods and increased thermal efficiency of the system.

Geothermal Produced Fluids: Characteristics, Treatment Technologies, and Management Options

DOE Office of Scientific and Technical Information (OSTI.GOV)

Finster, Molly; Clark, Corrie; Schroeder, Jenna

2015-10-01

Geothermal power plants use geothermal fluids as a resource and create waste residuals as part of the power generation process. Both the geofluid resource and the waste stream are considered produced fluids. The chemical and physical nature of produced fluids can have a major impact on the geothermal power industry and can influence the feasibility of geothermal power development, exploration approaches, power plant design, operating practices, and the reuse or disposal of residuals. In general, produced fluids include anything that comes out of a geothermal field and that subsequently must be managed on the surface. These fluids vary greatly dependingmore » on the geothermal reservoir being harnessed, power plant design, and the life cycle stage in which the fluid exists, but generally include water and fluids used to drill geothermal wells, fluids used to stimulate wells in enhanced geothermal systems, and makeup and/or cooling water used during operation of a geothermal power plant. Additional geothermal-related produced fluids include many substances that are similar to waste streams from the oil and gas industry, such as scale, flash tank solids, precipitated solids from brine treatment, hydrogen sulfide, and cooling-tower-related waste. This review paper aims to provide baseline knowledge on specific technologies and technology areas associated with geothermal power production. Specifically, this research focused on the management techniques related to fluids produced and used during the operational stage of a geothermal power plant; the vast majority of which are employed in the generation of electricity. The general characteristics of produced fluids are discussed. Constituents of interest that tend to drive the selection of treatment technologies are described, including total dissolved solids, noncondensable gases, scale and corrosion, silicon dioxide, metal sulfides, calcium carbonate, corrosion, metals, and naturally occurring radioactive material. Management options for produced fluids that require additional treatment for these constituents are also discussed, including surface disposal, reuse and recycle, agricultural industrial and domestic uses, mineral extraction and recovery, and solid waste handling.« less

Poly-N-acetylglucosamine matrix polysaccharide impedes fluid convection and transport of the cationic surfactant cetylpyridinium chloride through bacterial biofilms.

PubMed

Ganeshnarayan, Krishnaraj; Shah, Suhagi M; Libera, Matthew R; Santostefano, Anthony; Kaplan, Jeffrey B

2009-03-01

Biofilms are composed of bacterial cells encased in a self-synthesized, extracellular polymeric matrix. Poly-beta(1,6)-N-acetyl-d-glucosamine (PNAG) is a major biofilm matrix component in phylogenetically diverse bacteria. In this study we investigated the physical and chemical properties of the PNAG matrix in biofilms produced in vitro by the gram-negative porcine respiratory pathogen Actinobacillus pleuropneumoniae and the gram-positive device-associated pathogen Staphylococcus epidermidis. The effect of PNAG on bulk fluid flow was determined by measuring the rate of fluid convection through biofilms cultured in centrifugal filter devices. The rate of fluid convection was significantly higher in biofilms cultured in the presence of the PNAG-degrading enzyme dispersin B than in biofilms cultured without the enzyme, indicating that PNAG decreases bulk fluid flow. PNAG also blocked transport of the quaternary ammonium compound cetylpyridinium chloride (CPC) through the biofilms. Binding of CPC to biofilms further impeded fluid convection and blocked transport of the azo dye Allura red. Bioactive CPC was efficiently eluted from biofilms by treatment with 1 M sodium chloride. Taken together, these findings suggest that CPC reacts directly with the PNAG matrix and alters its physical and chemical properties. Our results indicate that PNAG plays an important role in controlling the physiological state of biofilms and may contribute to additional biofilm-associated processes such as biocide resistance.

Charging Effects on Fluid Stream Droplets for Momentum Exchange Between Spacecraft

DTIC Science & Technology

2009-01-01

DC705 have similar density; 1070 kg/m 3 for DC704 and 1097 kg/m 3 for DC705. The fluids differ chemically by a single methyl group, which is replaced...measured as a function of photon energy. The relative light intensity was monitored by the fluorescence of Sodium Salicylate . Division of the current by

Electrokinetic micro-fluid mixer

DOEpatents

Paul, Phillip H.; Rakestraw, David J.

2000-01-01

A method and apparatus for efficiently and rapidly mixing liquids in a system operating in the creeping flow regime such as would be encountered in capillary-based systems. By applying an electric field to each liquid, the present invention is capable of mixing together fluid streams in capillary-based systems, where mechanical or turbulent stirring cannot be used, to produce a homogeneous liquid.

Device for cooling and humidifying reformate

DOEpatents

Zhao, Jian Lian; Northrop, William F.

2008-04-08

Devices for cooling and humidifying a reformate stream from a reforming reactor as well as related methods, modules and systems includes a heat exchanger and a sprayer. The heat exchanger has an inlet, an outlet, and a conduit between the inlet and the outlet. The heat exchanger is adapted to allow a flow of a first fluid (e.g. water) inside the conduit and to establish a heat exchange relationship between the first fluid and a second fluid (e.g. reformate from a reforming reactor) flowing outside the conduit. The sprayer is coupled to the outlet of the heat exchanger for spraying the first fluid exiting the heat exchanger into the second fluid.

Ultrasonic Recovery and Modification of Food Ingredients

NASA Astrophysics Data System (ADS)

Vilkhu, Kamaljit; Manasseh, Richard; Mawson, Raymond; Ashokkumar, Muthupandian

There are two general classes of effects that sound, and ultrasound in particular, can have on a fluid. First, very significant modifications to the nature of food and food ingredients can be due to the phenomena of bubble acoustics and cavitation. The applied sound oscillates bubbles in the fluid, creating intense forces at microscopic scales thus driving chemical changes. Second, the sound itself can cause the fluid to flow vigorously, both on a large scale and on a microscopic scale; furthermore, the sound can cause particles in the fluid to move relative to the fluid. These streaming phenomena can redistribute materials within food and food ingredients at both microscopic and macroscopic scales.

Ion Streaming Instabilities in Pair Ion Plasma and Localized Structure with Non-Thermal Electrons

NASA Astrophysics Data System (ADS)

Nasir Khattak, M.; Mushtaq, A.; Qamar, A.

2015-12-01

Pair ion plasma with a fraction of non-thermal electrons is considered. We investigate the effects of the streaming motion of ions on linear and nonlinear properties of unmagnetized, collisionless plasma by using the fluid model. A dispersion relation is derived, and the growth rate of streaming instabilities with effect of streaming motion of ions and non-thermal electrons is calculated. A qausi-potential approach is adopted to study the characteristics of ion acoustic solitons. An energy integral equation involving Sagdeev potential is derived during this process. The presence of the streaming term in the energy integral equation affects the structure of the solitary waves significantly along with non-thermal electrons. Possible application of the work to the space and laboratory plasmas are highlighted.

Synthesis of ordered L10-type FeNi nanoparticles

DOEpatents

Pinkerton, Frederick E.

2015-09-22

Particles of iron and nickel are added to a flowing plasma stream which does not chemically alter the iron or nickel. The iron and nickel are heated and vaporized in the stream, and then a cryogenic fluid is added to the stream to rapidly cause the formation of nanometer size particles of iron and nickel. The particles are separated from the stream. The particles are preferably formed as single crystals in which the iron and nickel atoms are organized in a tetragonal L1.sub.0 crystal structure which displays magnetic anisotropy. A minor portion of an additive, such as titanium, vanadium, aluminum, boron, carbon, phosphorous, or sulfur, may be added to the plasma stream with the iron and nickel to enhance formation of the desired crystal structure.

Calculation of Macrosegregation in an Ingot

NASA Technical Reports Server (NTRS)

Poirier, D. R.; Maples, A. L.

1986-01-01

Report describes both two-dimensional theoretical model of macrosegregation (separating into regions of discrete composition) in solidification of binary alloy in chilled rectangular mold and interactive computer program embodying model. Model evolved from previous ones limited to calculating effects of interdendritic fluid flow on final macrosegregation for given input temperature field under assumption of no fluid in bulk melt.

7 CFR 1000.42 - Classification of transfers and diversions.

Code of Federal Regulations, 2011 CFR

2011-01-01

.... (a) Transfers and diversions to pool plants. Skim milk or butterfat transferred or diverted in the form of a fluid milk product or transferred in the form of a bulk fluid cream product from a pool plant... corresponding step of § 1000.44(b); (2) If the transferring plant received during the month other source milk to...

Highly resolved fluid flows: "liquid plasmas" at the kinetic level.

PubMed

Morfill, Gregor E; Rubin-Zuzic, Milenko; Rothermel, Hermann; Ivlev, Alexei V; Klumov, Boris A; Thomas, Hubertus M; Konopka, Uwe; Steinberg, Victor

2004-04-30

Fluid flow around an obstacle was observed at the kinetic (individual particle) level using "complex (dusty) plasmas" in their liquid state. These "liquid plasmas" have bulk properties similar to water (e.g., viscosity), and a comparison in terms of similarity parameters suggests that they can provide a unique tool to model classical fluids. This allows us to study "nanofluidics" at the most elementary-the particle-level, including the transition from fluid behavior to purely kinetic transport. In this (first) experimental investigation we describe the kinetic flow topology, discuss our observations in terms of fluid theories, and follow this up with numerical simulations.

Electrokinetics of diffuse soft interfaces. 1. Limit of low Donnan potentials.

PubMed

Duval, Jérôme F L; van Leeuwen, Herman P

2004-11-09

The current theoretical approaches to electrokinetics of gels or polyelectrolyte layers are based on the assumption that the position of the very interface between the aqueous medium and the gel phase is well defined. Within this assumption, spatial profiles for the volume fraction of polymer segments (phi), the density of fixed charges in the porous layer (rho fix), and the coefficient modeling the friction to hydrodynamic flow (k) follow a step-function. In reality, the "fuzzy" nature of the charged soft layer is intrinsically incompatible with the concept of a sharp interface and therefore necessarily calls for more detailed spatial representations for phi, rho fix, and k. In this paper, the notion of diffuse interface is introduced. For the sake of illustration, linear spatial distributions for phi and rho fix are considered in the interfacial zone between the bulk of the porous charged layer and the bulk electrolyte solution. The corresponding distribution for k is inferred from the Brinkman equation, which for low phi reduces to Stokes' equation. Linear electrostatics, hydrodynamics, and electroosmosis issues are analytically solved within the context of streaming current and streaming potential of charged surface layers in a thin-layer cell. The hydrodynamic analysis clearly demonstrates the physical incorrectness of the concept of a discrete slip plane for diffuse interfaces. For moderate to low electrolyte concentrations and nanoscale spatial transition of phi from zero (bulk electrolyte) to phi o (bulk gel), the electrokinetic properties of the soft layer as predicted by the theory considerably deviate from those calculated on the basis of the discontinuous approximation by Ohshima.

Computational fluid dynamics study of viscous fingering in supercritical fluid chromatography.

PubMed

Subraveti, Sai Gokul; Nikrityuk, Petr; Rajendran, Arvind

2018-01-26

Axi-symmetric numerical simulations are carried out to study the dynamics of a plug introduced through a mixed-stream injection in supercritical fluid chromatographic columns. The computational fluid dynamics model developed in this work takes into account both the hydrodynamics and adsorption equilibria to describe the phenomena of viscous fingering and plug effect that contribute to peak distortions in mixed-stream injections. The model was implemented into commercial computational fluid dynamics software using user-defined functions. The simulations describe the propagation of both the solute and modifier highlighting the interplay between the hydrodynamics and plug effect. The simulated peaks showed good agreement with experimental data published in the literature involving different injection volumes (5 μL, 50 μL, 1 mL and 2 mL) of flurbiprofen on Chiralpak AD-H column using a mobile phase of CO 2 and methanol. The study demonstrates that while viscous fingering is the main source of peak distortions for large-volume injections (1 mL and 2 mL) it has negligible impact on small-volume injections (5 μL and 50 μL). Band broadening in small-volume injections arise mainly due to the plug effect. Crown Copyright © 2017. Published by Elsevier B.V. All rights reserved.

Hydrodynamic enhanced dielectrophoretic particle trapping

DOEpatents

Miles, Robin R.

2003-12-09

Hydrodynamic enhanced dielectrophoretic particle trapping carried out by introducing a side stream into the main stream to squeeze the fluid containing particles close to the electrodes producing the dielelectrophoretic forces. The region of most effective or the strongest forces in the manipulating fields of the electrodes producing the dielectrophoretic forces is close to the electrodes, within 100 .mu.m from the electrodes. The particle trapping arrangement uses a series of electrodes with an AC field placed between pairs of electrodes, which causes trapping of particles along the edges of the electrodes. By forcing an incoming flow stream containing cells and DNA, for example, close to the electrodes using another flow stream improves the efficiency of the DNA trapping.

Reclamation of potable water from mixed gas streams

DOEpatents

Judkins, Roddie R.; Bischoff, Brian L.; Debusk, Melanie Moses; Narula, Chaitanya

2016-07-19

An apparatus for separating a liquid from a mixed gas stream can include a wall, a mixed gas stream passageway, and a liquid collection assembly. The wall can include a first surface, a second surface, and a plurality of capillary condensation pores. The capillary condensation pores extend through the wall, and have a first opening on the first surface of the wall, and a second opening on the second surface of the wall. The pore size of the pores can be between about 2 nm to about 100 nm. The mixed gas stream passageway can be in fluid communication with the first opening. The liquid collection assembly can collect liquid from the plurality of pores.

Reclamation of potable water from mixed gas streams

DOEpatents

Judkins, Roddie R; Bischoff, Brian L; Debusk, Melanie Moses; Narula, Chaitanya

2013-08-20

An apparatus for separating a liquid from a mixed gas stream can include a wall, a mixed gas stream passageway, and a liquid collection assembly. The wall can include a first surface, a second surface, and a plurality of capillary condensation pores. The capillary condensation pores extend through the wall, and have a first opening on the first surface of the wall, and a second opening on the second surface of the wall. The pore size of the pores can be between about 2 nm to about 100 nm. The mixed gas stream passageway can be in fluid communication with the first opening. The liquid collection assembly can collect liquid from the plurality of pores.

Free stream capturing in fluid conservation law for moving coordinates in three dimensions

NASA Technical Reports Server (NTRS)

Obayashi, Shigeru

1991-01-01

The free-stream capturing technique for both the finite-volume (FV) and finite-difference (FD) framework is summarized. For an arbitrary motion of the grid, the FV analysis shows that volumes swept by all six surfaces of the cell have to be computed correctly. This means that the free-stream capturing time-metric terms should be calculated not only from a surface vector of a cell at a single time level, but also from a volume swept by the cell surface in space and time. The FV free-stream capturing formulation is applicable to the FD formulation by proper translation from an FV cell to an FD mesh.

Variable Geometry Aircraft Pylon Structure and Related Operation Techniques

NASA Technical Reports Server (NTRS)

Shah, Parthiv N. (Inventor)

2014-01-01

An aircraft control structure can be utilized for purposes of drag management, noise control, or aircraft flight maneuvering. The control structure includes a high pressure engine nozzle, such as a bypass nozzle or a core nozzle of a turbofan engine. The nozzle exhausts a high pressure fluid stream, which can be swirled using a deployable swirl vane architecture. The control structure also includes a variable geometry pylon configured to be coupled between the nozzle and the aircraft. The variable geometry pylon has a moveable pylon section that can be deployed into a deflected state to maintain or alter a swirling fluid stream (when the swirl vane architecture is deployed) for drag management purposes, or to assist in the performance of aircraft flight maneuvers.

Analytical and numerical performance models of a Heisenberg Vortex Tube

NASA Astrophysics Data System (ADS)

Bunge, C. D.; Cavender, K. A.; Matveev, K. I.; Leachman, J. W.

2017-12-01

Analytical and numerical investigations of a Heisenberg Vortex Tube (HVT) are performed to estimate the cooling potential with cryogenic hydrogen. The Ranque-Hilsch Vortex Tube (RHVT) is a device that tangentially injects a compressed fluid stream into a cylindrical geometry to promote enthalpy streaming and temperature separation between inner and outer flows. The HVT is the result of lining the inside of a RHVT with a hydrogen catalyst. This is the first concept to utilize the endothermic heat of para-orthohydrogen conversion to aid primary cooling. A review of 1st order vortex tube models available in the literature is presented and adapted to accommodate cryogenic hydrogen properties. These first order model predictions are compared with 2-D axisymmetric Computational Fluid Dynamics (CFD) simulations.

An Interpretation of the Laminar-Turbulent Transition Startup against the Consideration of the Transverse Viscosity Factor

NASA Astrophysics Data System (ADS)

Kolodezhnov, V. N.

2018-03-01

This paper proposes a rheological model of a fluid having the Newtonian model applicability limit and a potential for further “addition” of the transverse viscosity factor. The dynamic equations for a fluid that has such rheological model are discussed, the analysis of which demonstrates the possibility of “generating” the cross stream velocity components. The transition to the dimensionless notation introduces four dimensionless complexes of local characterization for the transition conditions in the neighborhood of the flow region point in question. Based on such dimensionless complexes and using the known experimental data, the empiric conditions of “generating” the cross stream velocity components and starting the laminar-turbulent transition are proposed.

Pyrolysis process for producing condensed stabilized hydrocarbons utilizing a beneficially reactive gas

DOEpatents

Durai-Swamy, Kandaswamy

1982-01-01

In a process for recovery of values contained in solid carbonaceous material, the solid carbonaceous material is comminuted and then subjected to pyrolysis, in the presence of a carbon containing solid particulate source of heat and a beneficially reactive transport gas in a transport flash pyrolysis reactor, to form a pyrolysis product stream. The pyrolysis product stream contains a gaseous mixture and particulate solids. The solids are separated from the gaseous mixture to form a substantially solids-free gaseous stream which comprises volatilized hydrocarbon free radicals newly formed by pyrolysis. Preferably the solid particulate source of heat is formed by oxidizing part of the separated particulate solids. The beneficially reactive transport gas inhibits the reactivity of the char product and the carbon-containing solid particulate source of heat. Condensed stabilized hydrocarbons are obtained by quenching the gaseous mixture stream with a quench fluid which contains a capping agent for stabilizing and terminating newly formed volatilized hydrocarbon free radicals. The capping agent is partially depleted of hydrogen by the stabilization and termination reaction. Hydrocarbons of four or more carbon atoms in the gaseous mixture stream are condensed. A liquid stream containing the stabilized liquid product is then treated or separated into various fractions. A liquid containing the hydrogen depleted capping agent is hydrogenated to form a regenerated capping agent. At least a portion of the regenerated capping agent is recycled to the quench zone as the quench fluid. In another embodiment capping agent is produced by the process, separated from the liquid product mixture, and recycled.

Volume-energy parameters for heat transfer to supercritical fluids

NASA Technical Reports Server (NTRS)

Kumakawa, A.; Niino, M.; Hendricks, R. C.; Giarratano, P. J.; Arp, V. D.

1986-01-01

Reduced Nusselt numbers of supercritical fluids from different sources were grouped by several volume-energy parameters. A modified bulk expansion parameter was introduced based on a comparative analysis of data scatter. Heat transfer experiments on liquefied methane were conducted under near-critical conditions in order to confirm the usefulness of the parameters. It was experimentally revealed that heat transfer characteristics of near-critical methane are similar to those of hydrogen. It was shown that the modified bulk expansion parameter and the Gibbs-energy parameter grouped the heat transfer data of hydrogen, oxygen and methane including the present data on near-critical methane. It was also indicated that the effects of surface roughness on heat transfer were very important in grouping the data of high Reynolds numbers.

Mathematical Development of the Spill Assessment Model (SAM) for Hydrazine and Similar Acting Materials in Water Bodies.

DTIC Science & Technology

1980-02-01

migration of the chemical mass in the fluid volume according to two entirely different means, yet governed by the same form of the equation: molecular ...pressure or temperature gradients, gravitational or other body forces, or bulk fluid motion, is observed as molecular diffusion. In general, the...need be made at this stage as to whether the diffusion of a released mass in the fluid is molecular or turbulent in nature. The general form of the one

Microvolume index of refraction determinations by interferometric backscatter

NASA Astrophysics Data System (ADS)

Bornhop, Darryl J.

1995-06-01

A new method has been applied to the determination of fluid bulk properties in small detection volumes. Through the use of an unfocused He-Ne laser beam and a cylindrical tube of capillary dimensions, relative refractive-index measurements are possible. The backscattered light from the illumination of a tube of capillary dimensions produces an interference pattern that is spatially defined and that contains information related to the bulk properties of the fluid contained in the tube. Positional changes in the intensity-modulated beam profile (interference fringes) are directly related to the refractive index of the fluid in the tube. The determination of dn/n at the 10-7 level is possible in probe volumes of 350 pL. The technique has been applied to tubes as small as 75 mu m inner diameter and as large as 1.0 mm inner diameter. No modification of the simple optical bench is required for facilitating the determination of refractive index for the complete range of tube diameters.

High bulk modulus of ionic liquid and effects on performance of hydraulic system.

PubMed

Kambic, Milan; Kalb, Roland; Tasner, Tadej; Lovrec, Darko

2014-01-01

Over recent years ionic liquids have gained in importance, causing a growing number of scientists and engineers to investigate possible applications for these liquids because of their unique physical and chemical properties. Their outstanding advantages such as nonflammable liquid within a broad liquid range, high thermal, mechanical, and chemical stabilities, low solubility for gases, attractive tribological properties (lubrication), and very low compressibility, and so forth, make them more interesting for applications in mechanical engineering, offering great potential for new innovative processes, and also as a novel hydraulic fluid. This paper focuses on the outstanding compressibility properties of ionic liquid EMIM-EtSO4, a very important physical chemically property when IL is used as a hydraulic fluid. This very low compressibility (respectively, very high Bulk modulus), compared to the classical hydraulic mineral oils or the non-flammable HFDU type of hydraulic fluids, opens up new possibilities regarding its usage within hydraulic systems with increased dynamics, respectively, systems' dynamic responses.

Local shear stress and its correlation with local volume fraction in concentrated non-Brownian suspensions: Lattice Boltzmann simulation

NASA Astrophysics Data System (ADS)

Lee, Young Ki; Ahn, Kyung Hyun; Lee, Seung Jong

2014-12-01

The local shear stress of non-Brownian suspensions was investigated using the lattice Boltzmann method coupled with the smoothed profile method. Previous studies have only focused on the bulk rheology of complex fluids because the local rheology of complex fluids was not accessible due to technical limitations. In this study, the local shear stress of two-dimensional solid particle suspensions in Couette flow was investigated with the method of planes to correlate non-Newtonian fluid behavior with the structural evolution of concentrated particle suspensions. Shear thickening was successfully captured for highly concentrated suspensions at high particle Reynolds number, and both the local rheology and local structure of the suspensions were analyzed. It was also found that the linear correlation between the local particle stress and local particle volume fraction was dramatically reduced during shear thickening. These results clearly show how the change in local structure of suspensions influences the local and bulk rheology of the suspensions.

Cerebrospinal fluid bulk flow is driven by the cardiac cycle

NASA Astrophysics Data System (ADS)

Tithof, Jeffrey; Mestre, Humberto; Thomas, John; Nedergaard, Maiken; Kelley, Douglas

2017-11-01

Recent discoveries have uncovered a cerebrospinal fluid (CSF) transport system in the perivascular spaces (PVS) of the mammalian brain which clears excess extracellular fluid and protein waste products. The oscillatory pattern of CSF flow has long been attributed to arterial pulsations due to cardiac contractility but limitations in imaging techniques have impeded quantitative measurement of flow rates within the PVS. In this talk, we describe quantitative measurements from the first ever direct imaging of CSF flow in the PVS of a mouse brain. We perform particle tracking velocimetry to obtain time-resolved velocity measurements. To identify the cardiac and/or respiratory dependence of the flow, while imaging, we simultaneously record the mouse's electrocardiogram and respiration. Our measurements conclusively indicate that CSF pulsatility in the arterial PVS is directly driven by the cardiac cycle and not by the respiratory cycle or cerebral vasomotion. These results offer a substantial step forward in understanding bulk flow of CSF in the mammalian brain and may have important implications related to neurodegenerative diseases.

Bulk viscosity and relaxation time of causal dissipative relativistic fluid dynamics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huang Xuguang; Rischke, Dirk H.; Institut fuer Theoretische Physik, J.W. Goethe-Universitaet, D-60438 Frankfurt am Main

2011-02-15

The microscopic formulas of the bulk viscosity {zeta} and the corresponding relaxation time {tau}{sub {Pi}} in causal dissipative relativistic fluid dynamics are derived by using the projection operator method. In applying these formulas to the pionic fluid, we find that the renormalizable energy-momentum tensor should be employed to obtain consistent results. In the leading-order approximation in the chiral perturbation theory, the relaxation time is enhanced near the QCD phase transition, and {tau}{sub {Pi}} and {zeta} are related as {tau}{sub {Pi}={zeta}}/[{beta}{l_brace}(1/3-c{sub s}{sup 2})({epsilon}+P)-2({epsilon}-3P)/9{r_brace}], where {epsilon}, P, and c{sub s} are the energy density, pressure, and velocity of sound, respectively. The predictedmore » {zeta} and {tau}{sub {Pi}} should satisfy the so-called causality condition. We compare our result with the results of the kinetic calculation by Israel and Stewart and the string theory, and confirm that all three approaches are consistent with the causality condition.« less

Manufacturing Solid Dosage Forms from Bulk Liquids Using the Fluid-bed Drying Technology.

PubMed

Qi, Jianping; Lu, Y I; Wu, Wei

2015-01-01

Solid dosage forms are better than liquid dosage forms in many ways, such as improved physical and chemical stability, ease of storage and transportation, improved handling properties, and patient compliance. Therefore, it is required to transform dosage forms of liquid origins into solid dosage forms. The functional approaches are to absorb the liquids by solid excipients or through drying. The conventional drying technologies for this purpose include drying by heating, vacuum-, freeze- and spray-drying, etc. Among these drying technologies, fluidbed drying emerges as a new technology that possesses unique advantages. Fluid-bed drying or coating is highly efficient in solvent removal, can be performed at relatively low temperatures, and is a one-step process to manufacture formulations in pellet forms. In this article, the status of the art of manufacturing solid dosage forms from bulk liquids by fluid-bed drying technology was reviewed emphasizing on its application in solid dispersion, inclusion complexes, self-microemulsifying systems, and various nanoscale drug delivery systems.

Anatomy and pathophysiology of the pleura and pleural space.

PubMed

Yalcin, Nilay Gamze; Choong, Cliff K C; Eizenberg, Norman

2013-02-01

Pleural effusions are most often secondary to an underlying condition and may be the first sign of the underlying pathologic condition. The balance between the hydrostatic and oncotic forces dictates pleural fluid homeostasis. The parietal pleura has a more significant role in pleural fluid homeostasis. Its vessels are closer to the pleural space compared with its visceral counterpart; it contains lymphatic stomata, absent on visceral pleura, which are responsible for a bulk clearance of fluid. The diagnosis and successful treatment of pleural effusions requires a mixture of imaging techniques and pleural fluid analysis. Copyright © 2013. Published by Elsevier Inc.

How animals drink and swim in fluids

NASA Astrophysics Data System (ADS)

Jung, Sunghwan

2011-10-01

Fluids are essential for most living organisms to maintain a healthy body and also serve as a medium in which they locomote. The fluid bulk or interfaces actively interact with biological structures, which produces highly nonlinear, interesting, and complicated dynamical problems. We studied the lapping of cats and the swimming of Paramecia in various fluidic environments. The problem of the cat drinking can be simplified as the competition between inertia and gravity whereas the problem of Paramecium swimming in viscous fluids results from the competition between viscous drag and thrust. The underlying mechanisms are discussed and understood through laboratory experiments utilizing high-speed photography.

Fluid Dynamics Applied to Streams. Physical Processes in Terrestrial and Aquatic Ecosystems, Transport Processes.

ERIC Educational Resources Information Center

Cowan, Christina E.

This module is part of a series designed to be used by life science students for instruction in the application of physical theory to ecosystem operation. Most modules contain computer programs which are built around a particular application of a physical process. This module deals specifically with concepts that are basic to fluid flow and…

Droplet monitoring probe

NASA Technical Reports Server (NTRS)

Baughman, J. R.; Thys, P. C.

1973-01-01

A droplet monitoring system is disclosed for analysis of mixed-phase fluid flow in development of gas turbines. The system uses a probe comprising two electrical wires spaced a known distance apart and connected at one end to means for establishing a dc potential between the wires. A drop in the fluid stream momentarily contacting both wires simultaneously causes and electrical signal which is amplified, detected and counted.

Supercritical fluid regeneration of adsorbents

NASA Astrophysics Data System (ADS)

Defilippi, R. P.; Robey, R. J.

1983-05-01

The results of a program to perform studies supercritical (fluid) carbon dioxide (SCF CO2) regeneration of adsorbents, using samples of industrial wastewaters from manufacturing pesticides and synthetic solution, and to estimate the economics of the specific wastewater treatment regenerations, based on test data are given. Processing costs for regenerating granular activated carbon GAC) for treating industrial wastewaters depend on stream properties and regeneration throughput.

Dynamical Systems Analysis Of Transport In Flows Defined As Data Sets: Contaminant Control On The Coast Of Florida And Criteria For Warm Rings In The North Atlantic

NASA Astrophysics Data System (ADS)

Lekien, F.; Coulliette, C.

In this talk we will briefly describe the dynamical systems framework for Lagrangian transport. In particular, we will show how dynamical systems theory can now be uti- lized in the context of "real" problems, such as those derived from remote sensing observations or the input of a large scale numerical model. We will illustrate these ideas by two examples. Study of fluid transport near the Atlantic coast of Florida us- ing a velocity field observed experimentally from high frequency radar measurements reveals that dynamical systems theory can be used to reduce contaminant density in coastal areas. We also study intergyre transport in a quasigeostrophic model of the North Atlantic. We investigate the structure of eddies detaching from the Gulf Stream and prove that in a double gyre structure cyclonic rings cannot contain fluid from the other gyre. Only anticyclonic rings can contain "foreign" fluid coming from another gyre. This explains many phenomenons, such as why counter-clockwise rings South of the Gulf Stream contain colder fluid advected directly from the northern gyre, which has been illustrated in many observational studies.

Falkner-Skan Boundary Layer Flow of a Sisko Fluid

NASA Astrophysics Data System (ADS)

Khan, Masood; Shahzad, Azeem

2012-09-01

In this paper, we investigate the steady boundary layer flow of a non-Newtonian fluid, represented by a Sisko fluid, over a wedge in a moving fluid. The equations of motion are derived for boundary layer flow of an incompressible Sisko fluid using appropriate similarity variables. The governing equations are reduced to a single third-order highly nonlinear ordinary differential equation in the dimensionless stream function, which is then solved analytically using the homotopy analysis method. Some important parameters have been discussed by this study, which include the power law index n, the material parameter A, the wedge shape factor b, and the skin friction coefficient Cf. A comprehensive study is made between the results of the Sisko and the power-law fluids.

Impact of Reservoir Fluid Saturation on Seismic Parameters: Endrod Gas Field, Hungary

NASA Astrophysics Data System (ADS)

El Sayed, Abdel Moktader A.; El Sayed, Nahla A.

2017-12-01

Outlining the reservoir fluid types and saturation is the main object of the present research work. 37 core samples were collected from three different gas bearing zones in the Endrod gas field in Hungary. These samples are belonging to the Miocene and the Upper - Lower Pliocene. These samples were prepared and laboratory measurements were conducted. Compression and shear wave velocity were measured using the Sonic Viewer-170-OYO. The sonic velocities were measured at the frequencies of 63 and 33 kHz for compressional and shear wave respectively. All samples were subjected to complete petrophysical investigations. Sonic velocities and mechanical parameters such as young’s modulus, rigidity, and bulk modulus were measured when samples were saturated by 100%-75%-0% brine water. Several plots have been performed to show the relationship between seismic parameters and saturation percentages. Robust relationships were obtained, showing the impact of fluid saturation on seismic parameters. Seismic velocity, Poisson’s ratio, bulk modulus and rigidity prove to be applicable during hydrocarbon exploration or production stages. Relationships among the measured seismic parameters in gas/water fully and partially saturated samples are useful to outline the fluid type and saturation percentage especially in gas/water transitional zones.

Method for separating disparate components in a fluid stream

DOEpatents

Meikrantz, David H.

1990-01-01

The invention provides a method of separating a mixed component waste stream in a centrifugal separator. The mixed component waste stream is introduced into the separator and is centrifugally separated within a spinning rotor. A dual vortex separation occurs due to the phase density differences, with the phases exiting the rotor distinct from one another. In a preferred embodiment, aqueous solutions of organics can be separated with up to 100% efficiency. The relatively more dense water phase is centrifugally separated through a radially outer aperture in the separator, while the relatively less dense organic phase is separated through a radially inner aperture.

A millisecond micromixer via single-bubble-based acoustic streaming.

PubMed

Ahmed, Daniel; Mao, Xiaole; Shi, Jinjie; Juluri, Bala Krishna; Huang, Tony Jun

2009-09-21

We present ultra-fast homogeneous mixing inside a microfluidic channel via single-bubble-based acoustic streaming. The device operates by trapping an air bubble within a "horse-shoe" structure located between two laminar flows inside a microchannel. Acoustic waves excite the trapped air bubble at its resonance frequency, resulting in acoustic streaming, which disrupts the laminar flows and triggers the two fluids to mix. Due to this technique's simple design, excellent mixing performance, and fast mixing speed (a few milliseconds), our single-bubble-based acoustic micromixer may prove useful for many biochemical studies and applications.

Connection between the two branches of the quantum two-stream instability across the k space

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bret, A.; Haas, F.

2010-05-15

The stability of two quantum counterstreaming electron beams is investigated within the quantum plasma fluid equations for arbitrarily oriented wave vectors k. The analysis reveals that the two quantum two-stream unstable branches are indeed connected by a continuum of unstable modes with oblique wave vectors. Using the longitudinal approximation, the stability domain for any k is analytically explained, together with the growth rate.

Computational Analyses of Offset Stream Nozzles for Noise Reduction

NASA Technical Reports Server (NTRS)

Dippold, Vance, III; Foster, Lancert; Wiese,Michael

2007-01-01

The Wind computational fluid dynamics code was used to perform a series of simulations on two offset stream nozzle concepts for jet noise reduction. The first concept used an S-duct to direct the secondary stream to the lower side of the nozzle. The second concept used vanes to turn the secondary flow downward. The analyses were completed in preparation of tests conducted in the NASA Glenn Research Center Aeroacoustic Propulsion Laboratory. The offset stream nozzles demonstrated good performance and reduced the amount of turbulence on the lower side of the jet plume. The computer analyses proved instrumental in guiding the development of the final test configurations and giving insight into the flow mechanics of offset stream nozzles. The computational predictions were compared with flowfield results from the jet rig testing and showed excellent agreement.

Multistream hydrodynamic modeling of interhemispheric plasma flow

NASA Technical Reports Server (NTRS)

Rasmussen, C. E.; Schunk, R. W.

1988-01-01

Interhemispheric plasma flow was simulated using one-stream and two-stream hydrodymic models in order to test the suggestion of Banks et al. (1971) and others that the collision of high-speed flows originating from the conjugate hemispheres will cause the formation of a pair of shocks. The single-fluid hydrodynamic equations were modified to include multiple ion streams, allowing for the possibility of counterstreaming flow. It was found that a counterstreaming of ion streams from conjugate hemispheres does occur during the early stages of the refilling of plamaspheric flux tubes, and that a pair of reverse shocks does form. These shocks form away from the equator, and their subsequent motion creates conditions similar to those predicted by the single-stream hydrodynamic models. The findings support the conclusion of earlier studies that the refilling of the plasmasphere occurs from the equatorial region downward.

Efficient bulk-loading of gridfiles

NASA Technical Reports Server (NTRS)

Leutenegger, Scott T.; Nicol, David M.

1994-01-01

This paper considers the problem of bulk-loading large data sets for the gridfile multiattribute indexing technique. We propose a rectilinear partitioning algorithm that heuristically seeks to minimize the size of the gridfile needed to ensure no bucket overflows. Empirical studies on both synthetic data sets and on data sets drawn from computational fluid dynamics applications demonstrate that our algorithm is very efficient, and is able to handle large data sets. In addition, we present an algorithm for bulk-loading data sets too large to fit in main memory. Utilizing a sort of the entire data set it creates a gridfile without incurring any overflows.

Live Soap: Stability, Order, and Fluctuations in Apolar Active Smectics

NASA Astrophysics Data System (ADS)

Adhyapak, Tapan Chandra; Ramaswamy, Sriram; Toner, John

2013-03-01

We construct a hydrodynamic theory of noisy, apolar active smectics in bulk suspension or on a substrate. Unlike purely orientationally ordered active fluids, active apolar smectics can be dynamically stable in Stokesian bulk suspensions. Smectic order in these systems is quasilong ranged in dimension d=2 and long ranged in d=3. We predict reentrant Kosterlitz-Thouless melting to an active nematic in our simplest model in d=2, a nonzero second-sound speed parallel to the layers in bulk suspensions, and that there are no giant number fluctuations in either case. We also briefly discuss possible instabilities in these systems.

Supercritical-fluid extraction and chromatography-mass spectrometry for analysis of mycotoxins

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, R.D.; Udseth, H.R.

1982-07-01

The use of direct supercritical-fluid injection-mass spectrometry for the rapid analysis of mycotoxins of the tricothecene group is demonstrated. A solution containing diacetoxyscirpenol or T-2 toxin is injected into a fluid consisting primarily of pentane or carbon dioxide and is rapidly brought to supercritical conditions. Direct injection of the fluid stream into a chemical ionization source allows thermally labile compounds to be analyzed. Under these conditions trichothecene mass spectra showing significant (M + 1)/sup +/ ions and distinctive fragmentation patterns are obtained. Detection limits are in the subnanogram range. Direct analysis from complex substrates using selective supercritical-fluid extraction is proposed.more » 4 figures.« less

Curved film cooling admission tube

NASA Astrophysics Data System (ADS)

Graham, R. W.; Papell, S. S.

1980-10-01

Effective film cooling to protect a wall surface from a hot fluid which impinges on or flows along the surface is provided. A film of cooling fluid having increased area is provided by changing the direction of a stream of cooling fluid through an angle of from 135 deg. to 165 deg. before injecting it through the wall into the hot flowing gas. The 1, cooling fluid is injected from an orifice through a wall into a hot flowing gas at an angle to form a cooling fluid film. Cooling fluid is supplied to the orifice from a cooling fluid source via a turbulence control passageway having a curved portion between two straight portions. The angle through which the direction of the cooling fluid is turned results in less mixing of the cooling fluid with the hot gas, thereby substantially increasing the length of the film in a downstream direction.

Curved film cooling admission tube

NASA Technical Reports Server (NTRS)

Graham, R. W.; Papell, S. S. (Inventor)

1980-01-01

Effective film cooling to protect a wall surface from a hot fluid which impinges on or flows along the surface is provided. A film of cooling fluid having increased area is provided by changing the direction of a stream of cooling fluid through an angle of from 135 deg. to 165 deg. before injecting it through the wall into the hot flowing gas. The 1, cooling fluid is injected from an orifice through a wall into a hot flowing gas at an angle to form a cooling fluid film. Cooling fluid is supplied to the orifice from a cooling fluid source via a turbulence control passageway having a curved portion between two straight portions. The angle through which the direction of the cooling fluid is turned results in less mixing of the cooling fluid with the hot gas, thereby substantially increasing the length of the film in a downstream direction.

Measuring and modeling the flux of fecal bacteria across the sediment-water interface in a turbulent stream

NASA Astrophysics Data System (ADS)

Grant, Stanley B.; Litton-Mueller, Rachel M.; Ahn, Jong H.

2011-05-01

Sediments are a pervasive source of fecal indicator bacteria (FIB) in rivers, lakes, estuaries, and oceans and may constitute a long-term reservoir of human disease. Previous attempts to quantify the flux of FIB across the sediment-water interface (SWI) are limited to extreme flow events, for which the primary mechanism of bacterial release is disruption and/or erosion of the sediment substrate. Here we report measurements of FIB flux across the SWI in a turbulent stream that is not undergoing significant erosion. The stream is formed by the steady discharge of bacteria-free disinfected and highly treated wastewater effluent to an earthen channel harboring high concentrations of FIB in the sediment from in situ growth. The flux j″ of FIB across the SWI, estimated from mass balance on FIB measurements in the water column, scales linearly with the concentration of bacteria in sediment pore fluids Cpore over a 3 decade change in both variables: ? The magnitude of the observed mass transfer velocity (? m s-1) is significantly larger than values predicted for either the diffusion of bacteria across a concentration boundary layer (? m s-1) or sweep and eject fluid motions at the SWI (? m s-1) but is similar to the flux of water between the stream and its hyporheic zone estimated from dye injection experiments. These results support the hypothesis that hyporheic exchange controls the trafficking of bacteria, and perhaps other types of particulate organic matter, across the SWI in turbulent streams.

Stream-wise distribution of skin-friction drag reduction on a flat plate with bubble injection

NASA Astrophysics Data System (ADS)

Qin, Shijie; Chu, Ning; Yao, Yan; Liu, Jingting; Huang, Bin; Wu, Dazhuan

2017-03-01

To investigate the stream-wise distribution of skin-friction drag reduction on a flat plate with bubble injection, both experiments and simulations of bubble drag reduction (BDR) have been conducted in this paper. Drag reductions at various flow speeds and air injection rates have been tested in cavitation tunnel experiments. Visualization of bubble flow pattern is implemented synchronously. The computational fluid dynamics (CFD) method, in the framework of Eulerian-Eulerian two fluid modeling, coupled with population balance model (PBM) is used to simulate the bubbly flow along the flat plate. A wide range of bubble sizes considering bubble breakup and coalescence is modeled based on experimental bubble distribution images. Drag and lift forces are fully modeled based on applicable closure models. Both predicted drag reductions and bubble distributions are in reasonable concordance with experimental results. Stream-wise distribution of BDR is revealed based on CFD-PBM numerical results. In particular, four distinct regions with different BDR characteristics are first identified and discussed in this study. Thresholds between regions are extracted and discussed. And it is highly necessary to fully understand the stream-wise distribution of BDR in order to establish a universal scaling law. Moreover, mechanism of stream-wise distribution of BDR is analysed based on the near-wall flow parameters. The local drag reduction is a direct result of near-wall max void fraction. And the near-wall velocity gradient modified by the presence of bubbles is considered as another important factor for bubble drag reduction.

Relation Between Pore Size and the Compressibility of a Confined Fluid

PubMed Central

Gor, Gennady Y.; Siderius, Daniel W.; Rasmussen, Christopher J.; Krekelberg, William P.; Shen, Vincent K.; Bernstein, Noam

2015-01-01

When a fluid is confined to a nanopore, its thermodynamic properties differ from the properties of a bulk fluid, so measuring such properties of the confined fluid can provide information about the pore sizes. Here we report a simple relation between the pore size and isothermal compressibility of argon confined in these pores. Compressibility is calculated from the fluctuations of the number of particles in the grand canonical ensemble using two different simulation techniques: conventional grand-canonical Monte Carlo and grand-canonical ensemble transition-matrix Monte Carlo. Our results provide a theoretical framework for extracting the information on the pore sizes of fluid-saturated samples by measuring the compressibility from ultrasonic experiments. PMID:26590541

New views of granular mass flows

USGS Publications Warehouse

Iverson, R.M.; Vallance, J.W.

2001-01-01

Concentrated grain-fluid mixtures in rock avalanches, debris flows, and pyroclastic flows do not behave as simple materials with fixed rheologies. Instead, rheology evolves as mixture agitation, grain concentration, and fluid-pressure change during flow initiation, transit, and deposition. Throughout a flow, however, normal forces on planes parallel to the free upper surface approximately balance the weight of the superincumbent mixture, and the Coulomb friction rule describes bulk intergranular shear stresses on such planes. Pore-fluid pressure can temporarily or locally enhance mixture mobility by reducing Coulomb friction and transferring shear stress to the fluid phase. Initial conditions, boundary conditions, and grain comminution and sorting can influence pore-fluid pressures and cause variations in flow dynamics and deposits.

4D ERT-based calibration and prediction of biostimulant induced changes in fluid conductivity

NASA Astrophysics Data System (ADS)

Johnson, T. C.; Versteeg, R. J.; Day-Lewis, F. D.; Major, W. R.; Wright, K. E.

2008-12-01

In-situ bioremediation is an emerging and cost-effective method of removing organic contaminants from groundwater. The performance of bioremedial systems depends on the adequate delivery and distribution of biostimulants to contaminated zones. Monitoring the distribution of biostimulants using monitoring wells is expensive, time consuming, and provides inadequate information between sampling wells. We discuss a Hydrogeophysical Performance Monitoring System (HPMS) deployed to monitor bioremediation efforts at a TCE-contaminated Superfund site in Brandywine MD. The HPMS enables autonomous electrical geophysical data acquisition, processing, quality-assurance/quality-control, and inversion. Our objective is to demonstrate the feasibility and cost effectiveness of the HPMS to provide near real-time information on the spatiotemporal behavior of injected biostimulants. As a first step, we use time-lapse electrical resistivity tomography (ERT) to estimate changes in bulk conductivity caused by the injectate. We demonstrate how ERT-based bulk conductivity estimates can be calibrated with a small number of fluid conductivity measurements to produce ERT-based estimates of fluid conductivity. The calibration procedure addresses the spatially variable resolution of the ERT tomograms. To test the validity of these estimates, we used the ERT results to predict the fluid conductivity at tens of points prior to field sampling of fluid conductivity at the same points. The comparison of ERT-predicted vs. observed fluid conductivity displays a high degree of correlation (correlation coefficient over 0.8), and demonstrates the ability of the HPMS to estimate the four-dimensional (4D) distribution of fluid conductivity caused by the biostimulant injection.

Electrical conductivity of the plagioclase-NaCl-water system and its implication for the high conductivity anomalies in the mid-lower crust of Tibet Plateau

NASA Astrophysics Data System (ADS)

Li, Ping; Guo, Xinzhuan; Chen, Sibo; Wang, Chao; Yang, Junlong; Zhou, Xingfan

2018-02-01

In order to investigate the origin of the high conductivity anomalies geophysically observed in the mid-lower crust of Tibet Plateau, the electrical conductivity of plagioclase-NaCl-water system was measured at 1.2 GPa and 400-900 K. The relationship between electrical conductivity and temperature follows the Arrhenius law. The bulk conductivity increases with the fluid fraction and salinity, but is almost independent of temperature (activation enthalpy less than 0.1 eV). The conductivity of plagioclase-NaCl-water system is much lower than that of albite-NaCl-water system with similar fluid fraction and salinity, indicating a strong effect of the major mineral phase on the bulk conductivity of the brine-bearing system. The high conductivity anomalies of 10-1 and 100 S/m observed in the mid-lower crust of Tibet Plateau can be explained by the aqueous fluid with a volume fraction of 1 and 9%, respectively, if the fluid salinity is 25%. The anomaly value of 10-1 S/m can be explained by the aqueous fluid with a volume fraction of 6% if the salinity is 10%. In case of Southern Tibet where the heat flow is high, the model of a thin layer of brine-bearing aqueous fluid with a high salinity overlying a thick layer of partial melt is most likely to prevail.

Chlorine isotope constraints on fluid-rock interactions during subduction and exhumation of the Zermatt-Saas ophiolite

NASA Astrophysics Data System (ADS)

Selverstone, J.; Sharp, Z. D.

2013-10-01

Chlorine isotope compositions of high-pressure (˜2.3 GPa) serpentinite, rodingite, and hydrothermally altered oceanic crust (AOC) differ significantly from high- and ultrahigh-pressure (> 3.2 GPa) metasedimentary rocks in the Aosta region, Italy. Texturally early serpentinites, rodingites, and AOC have bulk δ37Cl values indistinguishable from those of modern seafloor analogues (δ37Cl = -1.0 to +1.0‰). In contrast, serpentinites and AOC samples that recrystallized during exhumation have low δ37Cl values (-2.7 to -0.5‰); 37Cl depletion correlates with progressive changes in bulk chemistry. HP/UHP metasediments have low δ37Cl values (median = -2.5‰) that differ statistically from modern marine sediments (median = -0.6‰). Cl in metasedimentary rocks is concentrated in texturally early minerals, indicating modification of seafloor compositions early in the subduction history. The data constrain fluid sources during both subduction and exhumation-related phases of fluid-rock interaction: (1) marine sediments at the top of the downgoing plate likely interacted with isotopically light pore fluids from the accretionary wedge in the early stages of subduction. (2) No pervasive interaction with externally derived fluid occurred during subsequent subduction to the maximum depths of burial. (3) Localized mixing between serpentinites and fluids released by previously isotopically modified metasediments occurred during exhumation in the subduction channel. Most samples, however, preserved protolith signatures during subduction to near-arc depths.

Connection between encounter volume and diffusivity in geophysical flows

NASA Astrophysics Data System (ADS)

Rypina, Irina I.; Smith, Stefan G. Llewellyn; Pratt, Larry J.

2018-04-01

Trajectory encounter volume - the volume of fluid that passes close to a reference fluid parcel over some time interval - has been recently introduced as a measure of mixing potential of a flow. Diffusivity is the most commonly used characteristic of turbulent diffusion. We derive the analytical relationship between the encounter volume and diffusivity under the assumption of an isotropic random walk, i.e., diffusive motion, in one and two dimensions. We apply the derived formulas to produce maps of encounter volume and the corresponding diffusivity in the Gulf Stream region of the North Atlantic based on satellite altimetry, and discuss the mixing properties of Gulf Stream rings. Advantages offered by the derived formula for estimating diffusivity from oceanographic data are discussed, as well as applications to other disciplines.

Passive micromixer using by convection and surface tension effects with air-liquid interface.

PubMed

Ju, Jongil; Warrick, Jay

2013-12-01

This article describes a passive micromixer that utilizes an air-liquid interface and surface tension effects to enhance fluid mixing via convection and Marangoni effects. Performance of the microfluidic component is tested within a passive-pumping-based device that consists of three microchannels connected in succession using passive micro-mixers. Mixing was quantified at 5 key points along the length of the device using microscope images of patterned streams of Alexa 488 fluorescent-dyed water and pure DI water flowing through the device. The passive micro-mixer mixed fluid 15-20 times more effectively than diffusion between laminar flow streams alone and is a novel micro-mixer embodiment that provides an additional strategy for removing external components from microscale devices for simpler, autonomous operation.

Passive micromixer using by convection and surface tension effects with air-liquid interface

PubMed Central

Ju, Jongil; Warrick, Jay

2014-01-01

This article describes a passive micromixer that utilizes an air-liquid interface and surface tension effects to enhance fluid mixing via convection and Marangoni effects. Performance of the microfluidic component is tested within a passive-pumping-based device that consists of three microchannels connected in succession using passive micro-mixers. Mixing was quantified at 5 key points along the length of the device using microscope images of patterned streams of Alexa 488 fluorescent-dyed water and pure DI water flowing through the device. The passive micro-mixer mixed fluid 15–20 times more effectively than diffusion between laminar flow streams alone and is a novel micro-mixer embodiment that provides an additional strategy for removing external components from microscale devices for simpler, autonomous operation. PMID:25104979

Droplet-Based Segregation and Extraction of Concentrated Samples

DOE Office of Scientific and Technical Information (OSTI.GOV)

Buie, C R; Buckley, P; Hamilton, J

2007-02-23

Microfluidic analysis often requires sample concentration and separation techniques to isolate and detect analytes of interest. Complex or scarce samples may also require an orthogonal separation and detection method or off-chip analysis to confirm results. To perform these additional steps, the concentrated sample plug must be extracted from the primary microfluidic channel with minimal sample loss and dilution. We investigated two extraction techniques; injection of immiscible fluid droplets into the sample stream (''capping'''') and injection of the sample into an immiscible fluid stream (''extraction''). From our results we conclude that capping is the more effective partitioning technique. Furthermore, this functionalitymore » enables additional off-chip post-processing procedures such as DNA/RNA microarray analysis, realtime polymerase chain reaction (RT-PCR), and culture growth to validate chip performance.« less

Fuel leak detection apparatus for gas cooled nuclear reactors

DOEpatents

Burnette, Richard D.

1977-01-01

Apparatus is disclosed for detecting nuclear fuel leaks within nuclear power system reactors, such as high temperature gas cooled reactors. The apparatus includes a probe assembly that is inserted into the high temperature reactor coolant gaseous stream. The probe has an aperture adapted to communicate gaseous fluid between its inside and outside surfaces and also contains an inner tube for sampling gaseous fluid present near the aperture. A high pressure supply of noncontaminated gas is provided to selectively balance the pressure of the stream being sampled to prevent gas from entering the probe through the aperture. The apparatus includes valves that are operable to cause various directional flows and pressures, which valves are located outside of the reactor walls to permit maintenance work and the like to be performed without shutting down the reactor.

Solid oxide fuel cell power plant with an anode recycle loop turbocharger

DOEpatents

Saito, Kazuo; Skiba, Tommy; Patel, Kirtikumar H.

2015-07-14

An anode exhaust recycle turbocharger (100) has a turbocharger turbine (102) secured in fluid communication with a compressed oxidant stream within an oxidant inlet line (218) downstream from a compressed oxidant supply (104), and the anode exhaust recycle turbocharger (100) also includes a turbocharger compressor (106) mechanically linked to the turbocharger turbine (102) and secured in fluid communication with a flow of anode exhaust passing through an anode exhaust recycle loop (238) of the solid oxide fuel cell power plant (200). All or a portion of compressed oxidant within an oxidant inlet line (218) drives the turbocharger turbine (102) to thereby compress the anode exhaust stream in the recycle loop (238). A high-temperature, automotive-type turbocharger (100) replaces a recycle loop blower-compressor (52).

Solid oxide fuel cell power plant with an anode recycle loop turbocharger

DOEpatents

Saito, Kazuo; Skiba, Tommy; Patel, Kirtikumar H.

2016-09-27

An anode exhaust recycle turbocharger (100) has a turbocharger turbine (102) secured in fluid communication with a compressed oxidant stream within an oxidant inlet line (218) downstream from a compressed oxidant supply (104), and the anode exhaust recycle turbocharger (100) also includes a turbocharger compressor (106) mechanically linked to the turbocharger turbine (102) and secured in fluid communication with a flow of anode exhaust passing through an anode exhaust recycle loop (238) of the solid oxide fuel cell power plant (200). All or a portion of compressed oxidant within an oxidant inlet line (218) drives the turbocharger turbine (102) to thereby compress the anode exhaust stream in the recycle loop (238). A high-temperature, automotive-type turbocharger (100) replaces a recycle loop blower-compressor (52).

Electrohydrodynamic distortion of sample streams in continuous flow electrophoresis

NASA Technical Reports Server (NTRS)

Rhodes, Percy H.; Snyder, Robert S.; Roberts, Glyn O.

1989-01-01

Continuous flow electrophoresis experiments were carried out, using an electrolyte and a sample both made of aqueous solutions of phosphate buffer (with polystyrene latex added for visibility), to investigate causes of the sample spreading in this procedure. It is shown theoretically that an electric field perpendicular to a circular filament of conducting fluid surrounded by a fluid of different conductivity produces an electrohydrodynamic flow, which distorts the filament into an ellipse. Experimental results were found to be fully consistent with theretical predictions. It was found that the rate of distortion of the sample stream into a ribbon was proportional to the square of the applied voltage gradient. Furthermore, the orientation of the ribbon depends on the ratios of dielectric constant and electrical conductivity between the buffer and the sample.

From flying wheel to square flow: Dynamics of a flow driven by acoustic forcing

NASA Astrophysics Data System (ADS)

Cambonie, Tristan; Moudjed, Brahim; Botton, Valéry; Henry, Daniel; Ben Hadid, Hamda

2017-12-01

Acoustic streaming designates the ability to drive quasisteady flows by acoustic propagation in dissipative fluids and results from an acoustohydrodynamics coupling. It is a noninvasive way of putting a fluid into motion using the volumetric acoustic force and can be used for different applications such as mixing purposes. We present an experimental investigation of a kind of square flow driven by acoustic streaming, with the use of beam reflections, in a water tank. Time-resolved experiments using particle image velocimetry have been performed to investigate the velocity field in the reference plane of the experiments for six powers: 0.5, 1, 2, 4, 6, and 8 W. The evolution of the flow regime from almost steady to strongly unsteady states is characterized using different tools: the plot of time-averaged and instantaneous velocity fields, the calculation of presence density maps for vortex positions and for the maximal velocity and vorticity crest lines, and the use of spatiotemporal maps of the waving observed on the jets created by acoustic streaming. A transition is observed between two regimes at moderate and high acoustic forcing.

Multiple capillary biochemical analyzer with barrier member

DOEpatents

Dovichi, N.J.; Zhang, J.Z.

1996-10-22

A multiple capillary biochemical analyzer is disclosed for sequencing DNA and performing other analyses, in which a set of capillaries extends from wells in a microtiter plate into a cuvette. In the cuvette the capillaries are held on fixed closely spaced centers by passing through a sandwich construction having a pair of metal shims which squeeze between them a rubber gasket, forming a leak proof seal for an interior chamber in which the capillary ends are positioned. Sheath fluid enters the chamber and entrains filament sample streams from the capillaries. The filament sample streams, and sheath fluid, flow through aligned holes in a barrier member spaced close to the capillary ends, into a collection chamber having a lower glass window. The filament streams are illuminated above the barrier member by a laser, causing them to fluoresce. The fluorescence is viewed end-on by a CCD camera chip located below the glass window. The arrangement ensures an equal optical path length from all fluorescing spots to the CCD chip and also blocks scattered fluorescence illumination, providing more uniform results and an improved signal-to-noise ratio. 12 figs.

Multiple capillary biochemical analyzer with barrier member

DOEpatents

Dovichi, Norman J.; Zhang, Jian Z.

1996-01-01

A multiple capillary biochemical analyzer for sequencing DNA and performing other analyses, in which a set of capillaries extends from wells in a microtiter plate into a cuvette. In the cuvette the capillaries are held on fixed closely spaced centers by passing through a sandwich construction having a pair of metal shims which squeeze between them a rubber gasket, forming a leak proof seal for an interior chamber in which the capillary ends are positioned. Sheath fluid enters the chamber and entrains filament sample streams from the capillaries. The filament sample streams, and sheath fluid, flow through aligned holes in a barrier member spaced close to the capillary ends, into a collection chamber having a lower glass window. The filament streams are illuminated above the barrier member by a laser, causing them to fluoresce. The fluorescence is viewed end-on by a CCD camera chip located below the glass window. The arrangement ensures an equal optical path length from all fluorescing spots to the CCD chip and also blocks scattered fluorescence illumination, providing more uniform results and an improved signal to noise ratio.

Fluid-Structure Interaction Study on a Pre-Buckled Deformable Flat Ribbon

NASA Astrophysics Data System (ADS)

Fovargue, Lauren; Shams, Ehsan; Watterson, Amy; Corson, Dave; Filardo, Benjamin; Zimmerman, Daniel; Shan, Bob; Oberai, Assad

2015-11-01

A Fluid-Structure Interaction study is conducted for the flow over a deformable flat ribbon. This mechanism, which is called ribbon frond, maybe used as a device for pumping water and/or harvesting energy in rivers. We use a lower dimensional mathematical model, which represents the ribbon as a pre-buckled structure. The surface forces from the fluid flow, dictate the deformation of the ribbon, and the ribbon in turn imposes boundary conditions for the incompressible Navier-Stokes equations. The mesh motion is handled using an Arbitrary Lagrangian-Eulerian (ALE) scheme and the fluid-structure coupling is handled by iterating over the staggered governing equations for the structure, the fluid and the mesh. Simulations are conducted at three different free stream velocities. The results, including the frequency of oscillations, show agreement with experimental data. The vortical structures near the surface of the ribbon and its deformation are highly correlated. It is observed that the ribbon motion exhibits deviation from a harmonic motion, especially at lower free stream velocities. The behavior of the ribbon is compared to swimming animals, such as eels, in order to better understand its performance. The authors acknowledge support from ONR SBIR Phase II, contract No. N0001412C0604 and USDA, NIFA SBIR Phase I, contract No. 2013-33610-20836 and NYSERDA PON 2569, contract No. 30364.

Electrochemical treatment of water containing Microcystis aeruginosa in a fixed bed reactor with three-dimensional conductive diamond anodes.

PubMed

Mascia, Michele; Monasterio, Sara; Vacca, Annalisa; Palmas, Simonetta

2016-12-05

An electrochemical treatment was investigated to remove Microcystis aeruginosa from water. A fixed bed reactor in flow was tested, which was equipped with electrodes constituted by stacks of grids electrically connected in parallel, with the electric field parallel to the fluid flow. Conductive diamond were used as anodes, platinised Ti as cathode. Electrolyses were performed in continuous and in batch recirculated mode with flow rates corresponding to Re from 10 to 160, current densities in the range 10-60Am(-2) and Cl(-) concentrations up to 600gm(-3). The absorbance of chlorophyll-a pigment and the concentration of products and by-products of electrolysis were measured. In continuous experiments without algae in the inlet stream, total oxidants concentrations as equivalent Cl2, of about 0.7gCl2m(-3) were measured; the maximum values were obtained at Re=10 and i=25Am(-2), with values strongly dependent on the concentration of Cl(-). The highest algae inactivation was obtained under the operative conditions of maximum generation of oxidants; in the presence of microalgae the oxidants concentrations were generally below the detection limit. Results indicated that most of the bulk oxidants electrogenerated is constituted by active chlorine. The prevailing mechanism of M. aeruginosa inactivation is the disinfection by bulk oxidants. The experimental data were quantitatively interpreted through a simple plug flow model, in which the axial dispersion accounts for the non-ideal flow behaviour of the system; the model was successfully used to simulate the performances of the reactor in the single-stack configuration used for the experiments and in multi-stack configurations. Copyright © 2016 Elsevier B.V. All rights reserved.

Optimum free energy in the reference functional approach for the integral equations theory

NASA Astrophysics Data System (ADS)

Ayadim, A.; Oettel, M.; Amokrane, S.

2009-03-01

We investigate the question of determining the bulk properties of liquids, required as input for practical applications of the density functional theory of inhomogeneous systems, using density functional theory itself. By considering the reference functional approach in the test particle limit, we derive an expression of the bulk free energy that is consistent with the closure of the Ornstein-Zernike equations in which the bridge functions are obtained from the reference system bridge functional. By examining the connection between the free energy functional and the formally exact bulk free energy, we obtain an improved expression of the corresponding non-local term in the standard reference hypernetted chain theory derived by Lado. In this way, we also clarify the meaning of the recently proposed criterion for determining the optimum hard-sphere diameter in the reference system. This leads to a theory in which the sole input is the reference system bridge functional both for the homogeneous system and the inhomogeneous one. The accuracy of this method is illustrated with the standard case of the Lennard-Jones fluid and with a Yukawa fluid with very short range attraction.

Surfactant effects on the dynamics of an intravascular bubble

NASA Astrophysics Data System (ADS)

Zhang, Jie; Eckmann, David; Ayyaswamy, P. S.

2004-11-01

The effects of a surfactant on the dynamics of gas bubble behavior in the arteriolar vasculature are numerically investigated. The equations for momentum in the bulk fluid (blood) and the bubble, and the convection-diffusion equations for mass transport both in the bulk fluid and on the gas-liquid interface are numerically solved using a front tracking method. Both soluble and insoluble surfactants are considered. The adsorption/desorption dynamics of the soluble surfactant is accurately resolved. For a nearly occluded bubble, a faster rate of depletion of the surfactant from the region adjacent to the wall of the vessel is observed. In several cases studied here, the bulk medium is treated as non-Newtonian (power law, Casson), although the majority of cases treat blood as Newtonian. Results show that the adsorbed surfactant serves to prevent blood proteins and other macromolecules from occupying the interface. This prevents clotting or adhesion of the bubble to the vessel wall. The results obtained have significance in the study of intravascular gas embolism. Supported by NIH R01 HL67986

Tribological characterisation of Zr-based bulk metallic glass in simulated physiological media

NASA Astrophysics Data System (ADS)

Chen, Q.; Chan, K. C.; Liu, L.

2011-10-01

Due to their excellent wear resistant properties and high strength, as well as a low Young's modulus, Zr-based bulk metallic glasses (BMGs) are potentially suitable biomaterials for low-friction arthroplasty. The wear characteristics of the Zr60.14Cu22.31Fe4.85Al9.7Ag3 bulk amorphous alloy against ultra-high-molecular-weight polyethylene (UHMWPE) compared to a CoCrMo/UHMWPE combination were investigated in two different wear screening test devices, reciprocating and unidirectional. Hank's solution and sterile calf bovine serum were selected as the lubricant fluid media. It was found that different fluid media had insignificant effect on polyethylene wear against BMG counterfaces. The wear behaviour obtained on both test devices demonstrated that Zr-based BMG achieved UHMWPE counterface wear rates superior to conventional cast CoCrMo alloy, where the wear rate of UHMWPE is decreased by over 20 times. The tribological performance of these joints is superior to that of conventional metal-on-polymer designs. Contact angle measurements suggested that the advantage of BMG over a CoCrMo alloy counterface is attributed to its highly hydrophilic surfaces.

The dissolution of calcite in CO2-saturated solutions at 25°C and 1 atmosphere total pressure

USGS Publications Warehouse

Plummer, Niel; Wigley, T.M.L.

1976-01-01

The dissolution of Iceland spar in CO2-saturated solutions at 25°C and 1 atm total pressure has been followed by measurement of pH as a function of time. Surface concentrations of reactant and product species have been calculated from bulk fluid data using mass transport theory and a model that accounts for homogeneous reactions in the bulk fluid. The surface concentrations are found to be close to bulk solution values. This indicates that calcite dissolution under the experimental conditions is controlled by the kinetics of surface reaction. The rate of calcite dissolution follows an empirical second order relation with respect to calcium and hydrogen ion from near the initial condition (pH 3.91) to approximately pH 5.9. Beyond pH 5.9 the rate of surface reaction is greatly reduced and higher reaction orders are observed. Calculations show that the rate of calcite dissolution in natural environments may be influenced by both transport and surface-reaction processes. In the absence of inhibition, relatively short times should be sufficient to establish equilibrium.

Bianchi VI cosmological models representing perfect fluid and radiation with electric-type free gravitational fields

NASA Astrophysics Data System (ADS)

Roy, S. R.; Banerjee, S. K.

1992-11-01

A homogeneous Bianchi type VIh cosmological model filled with perfect fluid, null electromagnetic field and streaming neutrinos is obtained for which the free gravitational field is of the electric type. The barotropic equation of statep = (γ-1)ɛ is imposed in the particular case of Bianchi VI0 string models. Various physical and kinematical properties of the models are discussed.

Northwest Africa 5738: Multistage fluid-driven secondary alteration in an extraordinarily evolved eucrite

NASA Astrophysics Data System (ADS)

Warren, Paul H.; Rubin, Alan E.; Isa, Junko; Gessler, Nicholas; Ahn, Insu; Choi, Byeon-Gak

2014-09-01

The Northwest Africa 5738 eucrite contains a record of unprecedented geochemical complexity for a sample from the HED asteroid. It originated with a uniquely evolved (Stannern Trend) primary igneous composition, combining ultra-high bulk incompatible element and Na2O concentrations with a relatively low mg. Its bulk oxygen-isotopic composition (Δ‧17O = -0.27‰), as well as its trace element composition (e.g., Ga/Al), confirm other evidence for classification as a eucrite. Pyroxene mg equilibration, exsolution and ;cloudy; inclusions, all reflect a typical eucritic degree of thermal metamorphism. The rock contains an unprecedented array of microscopic fluid-metasomatic vein deposits. Most common are curvy microveins within pyroxene, which consist dominantly of Ca-plagioclase (typically An95, in stark contrast with the rock's An68-78 primary-igneous plagioclase), with Fe-olivine (Fo14) and Cr-spinel as additional major constituents. Likely related to these microveins are small masses of intergrown Ca-plagioclase (again roughly An95) and silica (or high-Si glass). Analyses of the microvein Cr-spinels show stoichiometry implying a significant Fe3+ content (Fe2O3 0.7-2.3 wt.%), and fO2 up to roughly IW+3; clearly elevated in comparison to the normal HED fO2 of about IW-1. The fO2 results show an anticorrelation with equilibration T (and with Mg/Fe), which suggests the parent fluid system became more oxidizing as it cooled. NWA 5738 also contains apparent secondary iron metal. The Fe-metals are very pure, with Ni consistently below an EPMA detection limit of ∼0.01 wt.%. The vein-like shapes of roughly 1/3 of the largest Fe-metals suggest origin by deposition from a fluid. The role of pyroxene exsolution as template for a denticular (sawtooth) Fe-metal edge shape, and the survival of Fo14 olivine in a rock with abundant silica and a far higher bulk mg, suggest that the most intense thermal metamorphism occurred no later than the secondary alteration. Near-complete lack of spatial association suggests that the Fe-metals formed during a distinct time period from the curvy microveins. The immediate cause of Fe-metal deposition was most plausibly (or anyway, least implausibly) an abrupt downshift in the fluid fO2. Considering the extremely evolved bulk composition, the fluid(s) may have been largely deuteric. However, more likely the main source of fluid was a nearby buried mass of volatile-rich impactor matter, such as carbonaceous chondrite, that hit the asteroid at low enough velocity to remain mostly intact. We further speculate that the abrupt drop in fluid fO2 may have been caused by a process of carbon-fueled ;smelting; (cf. ureilites), triggered by an impact-effected shift of the carbonaceous material to a changed environment, with higher T and/or lower P. These and other recent eucrite results point to a need for greater scrutiny regarding the absence of comparable alteration-veining in rocks from the lunar highland crust, a mysterious lack in view of recent evidence for abundant lunar water.

Bulk-Flow Analysis of Hybrid Thrust Bearings for Advanced Cryogenic Turbopumps

NASA Technical Reports Server (NTRS)

SanAndres, Luis

1998-01-01

A bulk-flow analysis and computer program for prediction of the static load performance and dynamic force coefficients of angled injection, orifice-compensated hydrostatic/hydrodynamic thrust bearings have been completed. The product of the research is an efficient computational tool for the design of high-speed thrust bearings for cryogenic fluid turbopumps. The study addresses the needs of a growing technology that requires of reliable fluid film bearings to provide the maximum operating life with optimum controllable rotordynamic characteristics at the lowest cost. The motion of a cryogenic fluid on the thin film lands of a thrust bearing is governed by a set of bulk-flow mass and momentum conservation and energy transport equations. Mass flow conservation and a simple model for momentum transport within the hydrostatic bearing recesses are also accounted for. The bulk-flow model includes flow turbulence with fluid inertia advection, Coriolis and centrifugal acceleration effects on the bearing recesses and film lands. The cryogenic fluid properties are obtained from realistic thermophysical equations of state. Turbulent bulk-flow shear parameters are based on Hirs' model with Moody's friction factor equations allowing a simple simulation for machined bearing surface roughness. A perturbation analysis leads to zeroth-order nonlinear equations governing the fluid flow for the thrust bearing operating at a static equilibrium position, and first-order linear equations describing the perturbed fluid flow for small amplitude shaft motions in the axial direction. Numerical solution to the zeroth-order flow field equations renders the bearing flow rate, thrust load, drag torque and power dissipation. Solution to the first-order equations determines the axial stiffness, damping and inertia force coefficients. The computational method uses well established algorithms and generic subprograms available from prior developments. The Fortran9O computer program hydrothrust runs on a Windows 95/NT personal computer. The program, help files and examples are licensed by Texas A&M University Technology License Office. The study of the static and dynamic performance of two hydrostatic/hydrodynamic bearings demonstrates the importance of centrifugal and advection fluid inertia effects for operation at high rotational speeds. The first example considers a conceptual hydrostatic thrust bearing for an advanced liquid hydrogen turbopump operating at 170,000 rpm. The large axial stiffness and damping coefficients of the bearing should provide accurate control and axial positioning of the turbopump and also allow for unshrouded impellers, therefore increasing the overall pump efficiency. The second bearing uses a refrigerant R134a, and its application in oil-free air conditioning compressors is of great technological importance and commercial value. The computed predictions reveal that the LH2 bearing load capacity and flow rate increase with the recess pressure (i.e. increasing orifice diameters). The bearing axial stiffness has a maximum for a recess pressure rati of approx. 0.55. while the axial damping coefficient decreases as the recess pressure ratio increases. The computer results from three flow models are compared. These models are a) inertialess, b) fluid inertia at recess edges only, and c) full fluid inertia at both recess edges and film lands. The full inertia model shows the lowest flow rates, axial load capacity and stiffness coefficient but on the other hand renders the largest damping coefficients and inertia coefficients. The most important findings are related to the reduction of the outflow through the inner radius and the appearance of subambient pressures. The performance of the refrigerant hybrid thrust bearing is evaluated at two operating speeds and pressure drops. The computed results are presented in dimensionless form to evidence consistent trends in the bearing performance characteristics. As the applied axial load increases, the bearing film thickness and flow rate decrease while the recess pressure increases. The axial stiffness coefficient shows a maximum for a certain intermediate load while the damping coefficient steadily increases. The computed results evidence the paramount of centrifugal fluid inertia at low recess pressures (i.e. low loads), and where there is actually an inflow through the bearing inner diameter, accompanied by subambient pressures just downstream of the bearing recess edge. These results are solely due to centrifugal fluid inertia and advection transport effects. Recommendations include the extension of the computer program to handle flexure pivot tilting pad hybrid bearings and the ability to calculate moment coefficients for shaft angular misalignments.

Turbidity threshold sampling: Methods and instrumentation

Treesearch

Rand Eads; Jack Lewis

2001-01-01

Traditional methods for determining the frequency of suspended sediment sample collection often rely on measurements, such as water discharge, that are not well correlated to sediment concentration. Stream power is generally not a good predictor of sediment concentration for rivers that transport the bulk of their load as fines, due to the highly variable routing of...

Separating Autotrophic and Heterotrophic Respiration in Streams and the Importance for Carbon Cycling: a Preliminary Study

NASA Astrophysics Data System (ADS)

Bozeman, M.; Raymond, P.

2005-05-01

Autotrophic and heterotrophic organisms confer different effects on nutrient cycling, especially on carbon (C). In stream ecosystems, net ecosystem production determines the amount and form of C exported; however any transformation due to different respiratory (R) mechanisms are not separated. These mechanisms highly influence the form and lability of the C transported. To understand the current state of knowledge and estimate the importance of autotrophic versus heterotrophic R, we obtained a range of respiratory rates from the literature and modeled effects of different balances of rates on bulk dissolved inorganic and organic C chemistry. Preliminary results show that a wide range of estimates of autotrophic R exist and that these can effect bulk properties of exported C. While specific effects are highly dependent upon physical structure of the study watershed, we offer that separating R mechanisms provides further insight into ecosystem C cycling. We also propose a method to measure autotrophic and heterotrophic R at the ecosystem scale and obtain watershed-level estimates of the importance of these processes on C cycling.

Bulk Group-III Nitride Crystal Growth in Supercritical Ammonia-Sodium Solutions

NASA Astrophysics Data System (ADS)

Griffiths, Steven Herbert

Gallium nitride (GaN) and its alloys with indium nitride (InGaN) and aluminum nitride (AlGaN), collectively referred to as Group-III Nitride semiconductors, have enabled white solid-state lighting (SSL) sources and power electronic devices. While these technologies have already made a lasting, positive impact on society, improvements in design and efficiency are anticipated by shifting from heteroepitaxial growth on foreign substrates (such as sapphire, Si, SiC, etc.) to homoepitaxial growth on native, bulk GaN substrates. Bulk GaN has not supplanted foreign substrate materials due to the extreme conditions required to achieve a stoichiometric GaN melt (temperatures and pressures in excess of 2200°C and 6 GPa, respectively). The only method used to produce bulk GaN on an industrial scale is hydride vapor phase epitaxy (HVPE), but the high cost of gaseous precursors and relatively poor crystal quality have limited the adoption of this technology. A solution growth technique known as the ammonothermal method has attracted interest from academia and industry alike for its ability to produce bulk GaN boules of exceedingly high crystal quality. The ammonothermal method employs supercritical ammonia (NH3) solutions to dissolve, transport, and crystallize GaN. However, ammonothermal growth pressures are still relatively high (˜200 MPa), which has thus far prevented the acquisition of fundamental crystal growth knowledge needed to efficiently (i.e. through data-driven approaches) advance the field. This dissertation focused on addressing the gaps in the literature through two studies employing in situ fluid temperature analysis. The first study focused on identifying the solubility of GaN in supercritical NH3-Na solutions. The design and utilization of in situ and ex situ monitoring equipment enabled the first reports of the two-phase nature of supercritical NH3-Na solutions, and of Ga-alloying of Ni-containing autoclave components. The effects of these error sources on the gravimetric determination of GaN solubility were explored in detail. The second study was aimed at correlating autoclave dissolution and growth zone fluid temperatures with bulk GaN crystal growth kinetics, crystal quality, and impurity incorporation. The insights resulting from this analysis include the identification of the barrier between mass transport and surface integration-limited GaN growth regimes, GaN crystal shape evolution with fluid temperature, the sensitivity of (0001)-orientation crystal quality with fluid temperature, and impurity-specific incorporation activated from the dissolution and growth zones of the autoclave. The results of the aforementioned studies motivated a paradigm-shift in ammonothermal growth. To address this need, a fundamentally different crystal growth approach involving isothermal solutions and tailor-made Group-III alloy source materials was developed/demonstrated. This growth method enabled impurity incorporation reduction compared to traditional ammonothermal GaN growth, and the realization of bulk, ternary Group-III Nitride crystals.

Infrared emission spectra from operating elastohydrodynamic sliding contacts

NASA Technical Reports Server (NTRS)

Lauer, J. L.

1976-01-01

Infrared emission spectra from an operating EHD sliding contact were obtained through a diamond window for an aromatic polymer solute present in equal concentration in four different fluids. Three different temperature ranges, three different loads, and three different speeds for every load were examined. Very sensitive Fourier spectrophotometric (Interferometric) techniques were employed. Band Intensities and band intensity ratios found to depend both on the operating parameters and on the fluid. Fluid film and metal surface temperatures were calculated from the spectra and their dependence on the mechanical parameters plotted. The difference between these temperatures could be plotted against shear rate on one curve for all fluids. However, at the same shear rate the difference between bulk fluid temperature and diamond window temperature was much higher for one of the fluids, a traction fluid, than for the others.

Fully-Coupled Fluid/Structure Vibration Analysis Using MSC/NASTRAN

NASA Technical Reports Server (NTRS)

Fernholz, Christian M.; Robinson, Jay H.

1996-01-01

MSC/NASTRAN's performance in the solution of fully-coupled fluid/structure problems is evaluated. NASTRAN is used to perform normal modes (SOL 103) and forced-response analyses (SOL 108, 111) on cylindrical and cubic fluid/structure models. Bulk data file cards unique to the specification of a fluid element are discussed and analytic partially-coupled solutions are derived for each type of problem. These solutions are used to evaluate NASTRAN's solutions for accuracy. Appendices to this work include NASTRAN data presented in fringe plot form, FORTRAN source code listings written in support of this work, and NASTRAN data file usage requirements for each analysis.

Analog geometry in an expanding fluid from AdS/CFT perspective

NASA Astrophysics Data System (ADS)

Bilić, Neven; Domazet, Silvije; Tolić, Dijana

2015-04-01

The dynamics of an expanding hadron fluid at temperatures below the chiral transition is studied in the framework of AdS/CFT correspondence. We establish a correspondence between the asymptotic AdS geometry in the 4 + 1 dimensional bulk with the analog spacetime geometry on its 3 + 1 dimensional boundary with the background fluid undergoing a spherical Bjorken type expansion. The analog metric tensor on the boundary depends locally on the soft pion dispersion relation and the four-velocity of the fluid. The AdS/CFT correspondence provides a relation between the pion velocity and the critical temperature of the chiral phase transition.

Holographic anyonic superfluidity

NASA Astrophysics Data System (ADS)

Jokela, Niko; Lifschytz, Gilad; Lippert, Matthew

2013-10-01

Starting with a holographic construction for a fractional quantum Hall state based on the D3-D7' system, we explore alternative quantization conditions for the bulk gauge fields. This gives a description of a quantum Hall state with various filling fractions. For a particular alternative quantization of the bulk gauge fields, we obtain a holographic anyon fluid in a vanishing background magnetic field. We show that this system is a superfluid, exhibiting the relevant gapless excitation.

Fast inertial particle manipulation in oscillating flows

NASA Astrophysics Data System (ADS)

Thameem, Raqeeb; Rallabandi, Bhargav; Hilgenfeldt, Sascha

2017-05-01

It is demonstrated that micron-sized particles suspended in fluid near oscillating interfaces experience strong inertial displacements above and beyond the fluid streaming. Experiments with oscillating bubbles show rectified particle lift over extraordinarily short (millisecond) times. A quantitative model on both the oscillatory and the steady time scales describes the particle displacement relative to the fluid motion. The formalism yields analytical predictions confirming the observed scaling behavior with particle size and experimental control parameters. It applies to a large class of oscillatory flows with applications from particle trapping to size sorting.

Microfluidic ultrasonic particle separators with engineered node locations and geometries

DOEpatents

Rose, Klint A.; Fisher, Karl A.; Wajda, Douglas A.; Mariella, Jr., Raymond P.; Bailey, Christopher; Dehlinger, Dietrich; Shusteff, Maxim; Jung, Byoungsok; Ness, Kevin D.

2016-04-26

An ultrasonic microfluidic system includes a separation channel for conveying a sample fluid containing small particles and large particles, flowing substantially parallel, adjacent to a recovery fluid, with which it is in contact. An acoustic transducer produces an ultrasound standing wave, that generates a pressure field having at least one node of minimum pressure amplitude. An acoustic extension structure is located proximate to said separation channel for positioning said acoustic node off center in said acoustic area and concentrating the large particles in said recovery fluid stream.

Microfluidic ultrasonic particle separators with engineered node locations and geometries

DOEpatents

Rose, Klint A; Fisher, Karl A; Wajda, Douglas A; Mariella, Jr., Raymond P; Bailey, Christopher; Dehlinger, Dietrich; Shusteff, Maxim; Jung, Byoungsok; Ness, Kevin D

2015-03-31

An ultrasonic microfluidic system includes a separation channel for conveying a sample fluid containing small particles and large particles, flowing substantially parallel, adjacent to a recovery fluid, with which it is in contact. An acoustic transducer produces an ultrasound standing wave, that generates a pressure field having at least one node of minimum, pressure amplitude. An acoustic extension structure is located proximate to said separation channel for positioning said acoustic node off center in said acoustic area and concentrating the large particles in said recovery fluid stream.

Microfluidic ultrasonic particle separators with engineered node locations and geometries

DOEpatents

Rose, Klint A; Fisher, Karl A; Wajda, Douglas A; Mariella, Jr., Raymond P; Bailey, Christoppher; Dehlinger, Dietrich; Shusteff, Maxim; Jung, Byoungsok; Ness, Kevin D

2014-05-20

An ultrasonic microfluidic system includes a separation channel for conveying a sample fluid containing small particles and large particles, flowing substantially parallel, adjacent to a recovery fluid, with which it is in contact. An acoustic transducer produces an ultrasound standing wave, that generates a pressure field having at least one node of minimum pressure amplitude. An acoustic extension structure is located proximate to said separation channel for positioning said acoustic node off center in said acoustic area and concentrating the large particles in said recovery fluid stream.

Experimental investigation of the flow dynamics and rheology of complex fluids in pipe flow by hybrid multi-scale velocimetry

NASA Astrophysics Data System (ADS)

Haavisto, Sanna; Cardona, Maria J.; Salmela, Juha; Powell, Robert L.; McCarthy, Michael J.; Kataja, Markku; Koponen, Antti I.

2017-11-01

A hybrid multi-scale velocimetry method utilizing Doppler optical coherence tomography in combination with either magnetic resonance imaging or ultrasound velocity profiling is used to investigate pipe flow of four rheologically different working fluids under varying flow regimes. These fluids include water, an aqueous xanthan gum solution, a softwood fiber suspension, and a microfibrillated cellulose suspension. The measurement setup enables not only the analysis of the rheological (bulk) behavior of a studied fluid but gives simultaneously information on their wall layer dynamics, both of which are needed for analyzing and solving practical fluid flow-related problems. Preliminary novel results on rheological and boundary layer flow properties of the working fluids are reported and the potential of the hybrid measurement setup is demonstrated.

A Streaming Language Implementation of the Discontinuous Galerkin Method

NASA Technical Reports Server (NTRS)

Barth, Timothy; Knight, Timothy

2005-01-01

We present a Brook streaming language implementation of the 3-D discontinuous Galerkin method for compressible fluid flow on tetrahedral meshes. Efficient implementation of the discontinuous Galerkin method using the streaming model of computation introduces several algorithmic design challenges. Using a cycle-accurate simulator, performance characteristics have been obtained for the Stanford Merrimac stream processor. The current Merrimac design achieves 128 Gflops per chip and the desktop board is populated with 16 chips yielding a peak performance of 2 Teraflops. Total parts cost for the desktop board is less than $20K. Current cycle-accurate simulations for discretizations of the 3-D compressible flow equations yield approximately 40-50% of the peak performance of the Merrimac streaming processor chip. Ongoing work includes the assessment of the performance of the same algorithm on the 2 Teraflop desktop board with a target goal of achieving 1 Teraflop performance.

Opto-mechano-fluidic viscometer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Han, Kewen, E-mail: khan56@illinois.edu; Zhu, Kaiyuan; Bahl, Gaurav, E-mail: bahl@illinois.edu

2014-07-07

The recent development of opto-mechano-fluidic resonators has provided—by harnessing photon radiation pressure—a microfluidics platform for the optical sensing of fluid density and bulk modulus. Here, we show that fluid viscosity can also be determined through optomechanical measurement of the vibrational noise spectrum of the resonator mechanical modes. A linear relationship between the spectral linewidth and root-viscosity is predicted and experimentally verified in the low viscosity regime. Our result is a step towards multi-frequency measurement of viscoelasticity of arbitrary fluids, without sample contamination, using highly sensitive optomechanics techniques.

Kinetic multi-layer model of the epithelial lining fluid (KM-ELF): Reactions of ozone and OH with antioxidants and surfactant molecules

NASA Astrophysics Data System (ADS)

Lakey, Pascale; Pöschl, Ulrich; Shiraiwa, Manabu

2015-04-01

Oxidants cause damage to biosurfaces such as the lung epithelium unless they are effectively scavenged. The respiratory tract is covered in a thin layer of fluid which extends from the nasal cavity to the alveoli and contain species that scavenge ozone and other incoming oxidants. The kinetic multi-layer model of the epithelial lining fluid (KM-ELF) has been developed in order to investigate the reactions of ozone and OH with antioxidants (ascorbate, uric acid, glutathione and α-tocopherol) and surfactant lipids and proteins within the epithelial lining fluid (ELF). The model incorporates different processes: gas phase diffusion, adsorption and desorption from the surface, bulk phase diffusion and known reactions at the surface and in the bulk. The ELF is split into many layers: a sorption layer, a surfactant layer, a near surface bulk layer and several bulk layers. Initial results using KM-ELF indicate that at ELF thicknesses of 80 nm and 1 × 10-4cm the ELF would become rapidly saturated with ozone with saturation occurring in less than a second. However, at an ELF thickness of 1 × 10-3cm concentration gradients were observed throughout the ELF and the presence of antioxidants reduced the O3 reaching the lung cells and tissues by 40% after 1 hour of exposure. In contrast, the antioxidants were efficient scavengers of OH radicals, although the large rate constants of OH reacting with the antioxidants resulted in the antioxidants decaying away rapidly. The chemical half-lives of the antioxidants and surface species were also calculated using KM-ELF as a function of O3 and OH concentration and ELF thickness. Finally, the pH dependence of the products of reactions between antioxidants and O3 were investigated. The KM-ELF model predicted that a harmful ascorbate ozonide product would increase from 1.4 × 1011cm-3at pH 7.4 to 1.1 × 1014 cm-3 at pH 4after 1 hour although a uric acid ozonide product would decrease from 2.0 × 1015cm-3to 5.9 × 1012cm-3.

The Effects of Ultra Thin Films on Dynamic Wetting

NASA Astrophysics Data System (ADS)

Chen, Xia; Garoff, Stephen; Rame, Enrique

2002-11-01

Dynamic wetting, the displacement of one fluid by another immiscible fluid on a surface, controls many natural and technological phenomena, such as coating, printing, spray painting and lubricating. Particularly in coating and spraying applications, contact lines advance across pre-existing fluid films. Most previous work has focused on contact lines advancing across films sufficiently thick that they behave as simple Newtonian fluids. Ultrathin films, where the film thickness may impinge on fundamental length scales in the fluid, have received less attention. In this talk, we will discuss the effects of ultrathin polymer films on dynamic wetting. We measure the interface shape within microns of moving contact lines advancing across preexisting films and compare the measurements to existing models of viscous bending for interfaces advancing across dry surfaces and 'thick' (in the sense that they behave as liquids) films. In the experiments, we advance a contact line of 10-poise and 1-poise polydimethylsiloxane (silicone oil) across pre-coated films of the same fluid with thickness from a single chain thickness (approx. 10 A) through a couple of radii of gyration (100-200 A) to films so thick they are likely bulk in behavior (103 A). All films are physisorbed, i.e. they readily rinse from the surface. Thus, molecules in the film are not anchored to the surface and can move within the film if the hydrodynamics dictate such motion. For films of the thickness of a single chain (approx. 10 A), our experiments indicate that the advancing fluid behaves just as it would if it advanced over a dry surface. For the thicker films (103 A), we find behavior indicating that the molecules in the film are acting as a fluid with the bulk properties. In this regime, results for the two different fluids are identical when the experiments are performed at the same pre-existing film thickness and advancing capillary number, Ca. For film of thickness of a few radii of gyration (approx. 100-200 A), the behavior depends on Ca of the advancing meniscus. At low Ca, the viscous bending of the interface near the contact line does not behave as it would on a dry surface. It has a lower curvature than expected. However, at higher Ca, the viscous bending is described by the model for spreading over a dry surface. These results show that the fluid flow in the film does behave differently than bulk as the film thickness becomes comparable to molecular length scale. But even more intriguing is the unusual velocity dependence of that behavior where the film behaves more solid-like at higher contact line speeds. We will discuss these results in terms of the properties of confined polymer melts.

The Effects of Ultra Thin Films on Dynamic Wetting

NASA Technical Reports Server (NTRS)

Chen, Xia; Garoff, Stephen; Rame, Enrique

2002-01-01

Dynamic wetting, the displacement of one fluid by another immiscible fluid on a surface, controls many natural and technological phenomena, such as coating, printing, spray painting and lubricating. Particularly in coating and spraying applications, contact lines advance across pre-existing fluid films. Most previous work has focused on contact lines advancing across films sufficiently thick that they behave as simple Newtonian fluids. Ultrathin films, where the film thickness may impinge on fundamental length scales in the fluid, have received less attention. In this talk, we will discuss the effects of ultrathin polymer films on dynamic wetting. We measure the interface shape within microns of moving contact lines advancing across preexisting films and compare the measurements to existing models of viscous bending for interfaces advancing across dry surfaces and 'thick' (in the sense that they behave as liquids) films. In the experiments, we advance a contact line of 10-poise and 1-poise polydimethylsiloxane (silicone oil) across pre-coated films of the same fluid with thickness from a single chain thickness (approx. 10 A) through a couple of radii of gyration (100-200 A) to films so thick they are likely bulk in behavior (10(exp 3) A). All films are physisorbed, i.e. they readily rinse from the surface. Thus, molecules in the film are not anchored to the surface and can move within the film if the hydrodynamics dictate such motion. For films of the thickness of a single chain (approx. 10 A), our experiments indicate that the advancing fluid behaves just as it would if it advanced over a dry surface. For the thicker films (10(exp 3) A), we find behavior indicating that the molecules in the film are acting as a fluid with the bulk properties. In this regime, results for the two different fluids are identical when the experiments are performed at the same pre-existing film thickness and advancing capillary number, Ca. For film of thickness of a few radii of gyration (approx. 100-200 A), the behavior depends on Ca of the advancing meniscus. At low Ca, the viscous bending of the interface near the contact line does not behave as it would on a dry surface. It has a lower curvature than expected. However, at higher Ca, the viscous bending is described by the model for spreading over a dry surface. These results show that the fluid flow in the film does behave differently than bulk as the film thickness becomes comparable to molecular length scale. But even more intriguing is the unusual velocity dependence of that behavior where the film behaves more solid-like at higher contact line speeds. We will discuss these results in terms of the properties of confined polymer melts.

Air Quality Monitor

NASA Technical Reports Server (NTRS)

1996-01-01

The Stak-Tracker CEM (Continuous Emission Monitor) Gas Analyzer is an air quality monitor capable of separating the various gases in a bulk exhaust stream and determining the amounts of individual gases present within the stream. The monitor is produced by GE Reuter- Stokes, a subsidiary of GE Corporate Research & Development Center. The Stak-Tracker uses a Langley Research Center software package which measures the concentration of a target gas by determining the degree to which molecules of that gas absorb an infrared beam. The system is environmental-friendly, fast and has relatively low installation and maintenance costs. It is applicable to gas turbines and various industries including glass, paper and cement.

Maxon and roton measurements in nanoconfined 4He

NASA Astrophysics Data System (ADS)

Bryan, M. S.; Sokol, P. E.

2018-05-01

We investigate the behavior of the collective excitations of adsorbed 4He in an ordered hexagonal mesopore, examining the crossover from a thin film to a confined fluid. Here, we present the inelastic scattering results as a function of filling at constant temperature. We find a monotonic transition of the maxon excitation as a function of filling. This has been interpreted as corresponding to an increasing density of the adsorbed helium, which approaches the bulk value as filling increases. The roton minimum exhibits a more complicated behavior that does not monotonically approach bulk values as filling increases. The full pore scattering resembles the bulk liquid accompanied by a layer mode. The maxon and roton scattering, taken together, at intermediate fillings does not correspond to a single bulk liquid dispersion at negative, low, or high pressure.

Simple, robust storage of drops and fluids in a microfluidic device.

PubMed

Boukellal, Hakim; Selimović, Seila; Jia, Yanwei; Cristobal, Galder; Fraden, Seth

2009-01-21

We describe a single microfluidic device and two methods for the passive storage of aqueous drops in a continuous stream of oil without any external control but hydrodynamic flow. Advantages of this device are that it is simple to manufacture, robust under operation, and drops never come into contact with each other, making it unnecessary to stabilize drops against coalescence. In one method the device can be used to store drops that are created upstream from the storage zone. In the second method the same device can be used to simultaneously create and store drops from a single large continuous fluid stream without resorting to the usual flow focusing or T-junction drop generation processes. Additionally, this device stores all the fluid introduced, including the first amount, with zero waste. Transport of drops in this device depends, however, on whether or not the aqueous drops wet the device walls. Analysis of drop transport in these two cases is presented. Finally, a method for extraction of the drops from the device is also presented, which works best when drops do not wet the walls of the chip.

Determination of the thermodynamic correction factor of fluids confined in nano-metric slit pores from molecular simulation

NASA Astrophysics Data System (ADS)

Collell, Julien; Galliero, Guillaume

2014-05-01

The multi-component diffusive mass transport is generally quantified by means of the Maxwell-Stefan diffusion coefficients when using molecular simulations. These coefficients can be related to the Fick diffusion coefficients using the thermodynamic correction factor matrix, which requires to run several simulations to estimate all the elements of the matrix. In a recent work, Schnell et al. ["Thermodynamics of small systems embedded in a reservoir: A detailed analysis of finite size effects," Mol. Phys. 110, 1069-1079 (2012)] developed an approach to determine the full matrix of thermodynamic factors from a single simulation in bulk. This approach relies on finite size effects of small systems on the density fluctuations. We present here an extension of their work for inhomogeneous Lennard Jones fluids confined in slit pores. We first verified this extension by cross validating the results obtained from this approach with the results obtained from the simulated adsorption isotherms, which allows to determine the thermodynamic factor in porous medium. We then studied the effects of the pore width (from 1 to 15 molecular sizes), of the solid-fluid interaction potential (Lennard Jones 9-3, hard wall potential) and of the reduced fluid density (from 0.1 to 0.7 at a reduced temperature T* = 2) on the thermodynamic factor. The deviation of the thermodynamic factor compared to its equivalent bulk value decreases when increasing the pore width and becomes insignificant for reduced pore width above 15. We also found that the thermodynamic factor is sensitive to the magnitude of the fluid-fluid and solid-fluid interactions, which softens or exacerbates the density fluctuations.

Determination of the thermodynamic correction factor of fluids confined in nano-metric slit pores from molecular simulation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Collell, Julien; Galliero, Guillaume, E-mail: guillaume.galliero@univ-pau.fr

2014-05-21

The multi-component diffusive mass transport is generally quantified by means of the Maxwell-Stefan diffusion coefficients when using molecular simulations. These coefficients can be related to the Fick diffusion coefficients using the thermodynamic correction factor matrix, which requires to run several simulations to estimate all the elements of the matrix. In a recent work, Schnell et al. [“Thermodynamics of small systems embedded in a reservoir: A detailed analysis of finite size effects,” Mol. Phys. 110, 1069–1079 (2012)] developed an approach to determine the full matrix of thermodynamic factors from a single simulation in bulk. This approach relies on finite size effectsmore » of small systems on the density fluctuations. We present here an extension of their work for inhomogeneous Lennard Jones fluids confined in slit pores. We first verified this extension by cross validating the results obtained from this approach with the results obtained from the simulated adsorption isotherms, which allows to determine the thermodynamic factor in porous medium. We then studied the effects of the pore width (from 1 to 15 molecular sizes), of the solid-fluid interaction potential (Lennard Jones 9-3, hard wall potential) and of the reduced fluid density (from 0.1 to 0.7 at a reduced temperature T* = 2) on the thermodynamic factor. The deviation of the thermodynamic factor compared to its equivalent bulk value decreases when increasing the pore width and becomes insignificant for reduced pore width above 15. We also found that the thermodynamic factor is sensitive to the magnitude of the fluid-fluid and solid-fluid interactions, which softens or exacerbates the density fluctuations.« less

Could the Coanda Effect Be Called the Young Effect? The Understanding of Fluid Dynamics of a Legendary Polymath

ERIC Educational Resources Information Center

Lopez-Arias, T.

2012-01-01

We discuss a brief part of a famous paper on sound and light written by Thomas Young in 1800. We show that the proverbial intuition of this famous polymath leads to the discussion of several important and complex fluid dynamics phenomena regarding the behaviour of streams of air. In particular, we show that Young had already explained the adhesion…

Heat of capillary condensation in nanopores: new insights from the equation of state.

PubMed

Tan, Sugata P; Piri, Mohammad

2017-02-15

Perturbed-Chain Statistical Associating Fluid Theory (PC-SAFT) coupled with the Young-Laplace equation is a recently developed equation of state (EOS) that successfully presents not only the capillary condensation but also the pore critical phenomena. The development of this new EOS allows further investigation of the heats involved in condensation. Compared to the conventional approaches, the EOS calculations present the temperature-dependent behavior of the heat of capillary condensation as well as that of the contributing effects. The confinement effect was found to be the strongest at the pore critical point. Therefore, contrary to the bulk heat condensation that vanishes at the critical point, the heat of capillary condensation in small pores shows a minimum and then increases with temperature when approaching the pore critical temperature. Strong support for the existence of the pore critical point is also discussed as the volume expansivity of the condensed phase in confinement was found to increase dramatically near the pore critical temperature. At high reduced temperatures, the Clausius-Clapeyron equation was found to apply better for confined fluids than it does for bulk fluids.

Edge-Induced Shear Banding in Entangled Polymeric Fluids

NASA Astrophysics Data System (ADS)

Hemingway, Ewan J.; Fielding, Suzanne M.

2018-03-01

Despite decades of research, the question of whether solutions and melts of highly entangled polymers exhibit shear banding as their steady state response to a steadily imposed shear flow remains controversial. From a theoretical viewpoint, an important unanswered question is whether the underlying constitutive curve of shear stress σ as a function of shear rate γ ˙ (for states of homogeneous shear) is monotonic, or has a region of negative slope, d σ /d γ ˙ <0 , which would trigger banding. Attempts to settle the question experimentally via velocimetry of the flow field inside the fluid are often confounded by an instability of the free surface where the sample meets the outside air, known as "edge fracture." Here we show by numerical simulation that in fact even only very modest edge disturbances—which are the precursor of full edge fracture but might well, in themselves, go unnoticed experimentally—can cause strong secondary flows in the form of shear bands that invade deep into the fluid bulk. Crucially, this is true even when the underlying constitutive curve is monotonically increasing, precluding true bulk shear banding in the absence of edge effects.

The relationship of metals, bifenthrin, physical habitat metrics, grain size, total organic carbon, dissolved oxygen and conductivity to Hyalella sp. abundance in urban California streams.

PubMed

Hall, Lenwood W; Anderson, Ronald D

2013-01-01

The objectives of this study were to determine the relationship between Hyalella sp. abundance in four urban California streams and the following parameters: (1) 8 bulk metals (As, Cd, Cr, Cu, Pb, Hg, Ni, and Zn) and their associated sediment Threshold Effect Levels (TELs); (2) bifenthrin sediment concentrations; (3) 10 habitat metrics and total score; (4) grain size (% sand, silt and clay); (5) Total Organic Carbon (TOC); (6) dissolved oxygen; and (7) conductivity. California stream data used for this study were collected from Kirker Creek (2006 and 2007), Pleasant Grove Creek (2006, 2007 and 2008), Salinas streams (2009 and 2010) and Arcade Creek (2009 and 2010). Hyalella abundance in the four California streams generally declined when metals concentrations were elevated beyond the TELs. There was also a statistically significant negative relationship between Hyalella abundance and % silt for these 4 California streams as Hyalella were generally not present in silt areas. No statistically significant relationships were reported between Hyalella abundance and metals concentrations, bifenthrin concentrations, habitat metrics, % sand, % clay, TOC, dissolved oxygen and conductivity. The results from this study highlight the complexity of assessing which factors are responsible for determining the abundance of amphipods, such as Hyalella sp., in the natural environment.

Method for treating a nuclear process off-gas stream

DOEpatents

Pence, Dallas T.; Chou, Chun-Chao

1984-01-01

Disclosed is a method for selectively removing and recovering the noble gas and other gaseous components typically emitted during nuclear process operations. The method is adaptable and useful for treating dissolver off-gas effluents released during reprocessing of spent nuclear fuels whereby to permit radioactive contaminant recovery prior to releasing the remaining off-gases to the atmosphere. Briefly, the method sequentially comprises treating the off-gas stream to preliminarily remove NO.sub.x, hydrogen and carbon-containing organic compounds, and semivolatile fission product metal oxide components therefrom; adsorbing iodine components on silver-exchanged mordenite; removing water vapor carried by said stream by means of a molecular sieve; selectively removing the carbon dioxide components of said off-gas stream by means of a molecular sieve; selectively removing xenon in gas phase by passing said stream through a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from oxygen by means of a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from the bulk nitrogen stream using a molecular sieve comprising silver-exchanged mordenite cooled to about -140.degree. to -160.degree. C.; concentrating the desorbed krypton upon a molecular sieve comprising silver-exchange mordenite cooled to about -140.degree. to -160.degree. C.; and further cryogenically concentrating, and the recovering for storage, the desorbed krypton.

Three-dimensional microbubble streaming flows

NASA Astrophysics Data System (ADS)

Rallabandi, Bhargav; Marin, Alvaro; Rossi, Massimiliano; Kaehler, Christian; Hilgenfeldt, Sascha

2014-11-01

Streaming due to acoustically excited bubbles has been used successfully for applications such as size-sorting, trapping and focusing of particles, as well as fluid mixing. Many of these applications involve the precise control of particle trajectories, typically achieved using cylindrical bubbles, which establish planar flows. Using astigmatic particle tracking velocimetry (APTV), we show that, while this two-dimensional picture is a useful description of the flow over short times, a systematic three-dimensional flow structure is evident over long time scales. We demonstrate that this long-time three-dimensional fluid motion can be understood through asymptotic theory, superimposing secondary axial flows (induced by boundary conditions at the device walls) onto the two-dimensional description. This leads to a general framework that describes three-dimensional flows in confined microstreaming systems, guiding the design of applications that profit from minimizing or maximizing these effects.

Oscillatory fluid flow in deformable tubes: Implications for pore-scale hydromechanics from comparing experimental observations with theoretical predictions.

PubMed

Kurzeja, Patrick; Steeb, Holger; Strutz, Marc A; Renner, Jörg

2016-12-01

Oscillatory flow of four fluids (air, water, two aqueous sodium-tungstate solutions) was excited at frequencies up to 250 Hz in tubes of two materials (steel, silicone) covering a wide range in length, diameter, and thickness. The hydrodynamical response was characterized by phase shift and amplitude ratio between pressures in an upstream (pressure excitation) and a downstream reservoir connected by the tubes. The resulting standing flow waves reflect viscosity-controlled diffusive behavior and inertia-controlled wave behavior for oscillation frequencies relatively low and high compared to Biot's critical frequency, respectively. Rigid-tube theories correspond well with the experimental results for steel tubes filled with air or water. The wave modes observed for silicone tubes filled with the rather incompressible liquids or air, however, require accounting for the solid's shear and bulk modulus to correctly predict speed of pressure propagation and deformation mode. The shear mode may be responsible for significant macroscopic attenuation in porous materials with effective frame-shear moduli lower than the bulk modulus of the pore fluid. Despite notable effects of the ratio of densities and of acoustic and shear velocity of fluid and solid, Biot's frequency remains an approximate indicator of the transition from the viscosity to the inertia controlled regime.

Mean-field density functional theory of a nanoconfined classical, three-dimensional Heisenberg fluid. I. The role of molecular anchoring

NASA Astrophysics Data System (ADS)

Cattes, Stefanie M.; Gubbins, Keith E.; Schoen, Martin

2016-05-01

In this work, we employ classical density functional theory (DFT) to investigate for the first time equilibrium properties of a Heisenberg fluid confined to nanoscopic slit pores of variable width. Within DFT pair correlations are treated at modified mean-field level. We consider three types of walls: hard ones, where the fluid-wall potential becomes infinite upon molecular contact but vanishes otherwise, and hard walls with superimposed short-range attraction with and without explicit orientation dependence. To model the distance dependence of the attractions, we employ a Yukawa potential. The orientation dependence is realized through anchoring of molecules at the substrates, i.e., an energetic discrimination of specific molecular orientations. If the walls are hard or attractive without specific anchoring, the results are "quasi-bulk"-like in that they can be linked to a confinement-induced reduction of the bulk mean field. In these cases, the precise nature of the walls is completely irrelevant at coexistence. Only for specific anchoring nontrivial features arise, because then the fluid-wall interaction potential affects the orientation distribution function in a nontrivial way and thus appears explicitly in the Euler-Lagrange equations to be solved for minima of the grand potential of coexisting phases.

The Influence of Hydrofoil Oscillation on Boundary Layer Transition and Cavitation Noise.

DTIC Science & Technology

1981-04-01

p., and V. are fluid density, reference free-stream AVERAGED static pressure and reference free-stream velocity, respec- ORSPL3. Lair tively. S3.1...of cavitation on a propeller in both uni- ly, the location of boundary layer transition with the foil in form and nonuniform flow. He concluded that...the presence of oscillation must be determined either theoretically or ex- sheet and bubble cavitation in nonuniform flow can be perimentally. Thirdly

Acoustic streaming in the cochlea under compressive bone conduction excitation

NASA Astrophysics Data System (ADS)

Aho, Katherine; Sunny, Megha; Nabat, Taoufik; Au, Jenny; Thompson, Charles

2012-02-01

This work examines the acoustic streaming in the cochlea. A model will be developed to examine the steady flow over a flexible boundary that is induced by compressive excitation of the cochlear capsule. A stokeslet based analysis of oscillatory flows was used to model fluid motion. The influence of evanescent modes on the pressure field is considered as the limit of the aspect ratio epsilon approaches zero. We will show a uniformly valid solution in space.

Electrokinetic instability micromixing.

PubMed

Oddy, M H; Santiago, J G; Mikkelsen, J C

2001-12-15

We have developed an electrokinetic process to rapidly stir micro- and nanoliter volume solutions for microfluidic bioanalytical applications. We rapidly stir microflow streams by initiating a flow instability, which we have observed in sinusoidally oscillating, electroosmotic channel flows. As the effect occurs within an oscillating electroosmotic flow, we refer to it here as an electrokinetic instability (EKI). The rapid stretching and folding of material lines associated with this instability can be used to stir fluid streams with Reynolds numbers of order unity, based on channel depth and rms electroosmotic velocity. This paper presents a preliminary description of the EKI and the design and fabrication of two micromixing devices capable of rapidly stirring two fluid streams using this flow phenomenon. A high-resolution CCD camera is used to record the stirring and diffusion of fluorescein from an initially unmixed configuration. Integration of fluorescence intensity over measurement volumes (voxels) provides a measure of the degree to which two streams are mixed to within the length scales of the voxels. Ensemble-averaged probability density functions and power spectra of the instantaneous spatial intensity profiles are used to quantify the mixing processes. Two-dimensional spectral bandwidths of the mixing images are initially anisotropic for the unmixed configuration, broaden as the stirring associated with the EKI rapidly stretches and folds material lines (adding high spatial frequencies to the concentration field), and then narrow to a relatively isotropic spectrum at the well-mixed conditions.

Characterization and timing of the different types of fluids present in the barren and ore-veins of the W-Sn deposit of Panasqueira, Central Portugal

NASA Astrophysics Data System (ADS)

Noronha, F.; Doria, A.; Dubessy, J.; Charoy, B.

1992-01-01

The Panasqueira W-Sn deposit is the largest quartz-vein type deposit of the Iberian Peninsula and the most important wolframite deposit in Western Europe. The ore-veins are almost exclusively sub-horizontal. Besides ore-bearing sub-horizontal veins, the Panasqueira mine also contains barren quartz veins. There are essentially two generations of barren quartz: quartz, contemporaneous with the earliest regional metamorphism (QI), and recrystallized quartz, contemporaneous with the thermal metamorphism related to the granite intrusion (QII). Fluid inclusion studies (microthermometry and Raman) were undertaken in order to distinguish fluids contemporaneous with the barren quartz from those contemporaneous with the ore-bearing quartz (QIII). Fluid inclusion data indicate that the barren and ore-bearing quartz fluids are dominantly aqueous (93 to 98 mol% H2O), with a nearly constant bulk salinity (8 to 12 wt% eq. NaCl), with the quantity of volatile component (determined by Raman spectrometry) higher in QIII, but never greater than 5 mol%. However, the CO2/CH4 + N2 ratio is different for each type of quartz. Volatiles are dominated by CH4 (10 to 96 mol% ZCH4 and/or N2 (3 to 87 mol% ZN2) in the barren quartz and by CO2 (60 to 73 mol% ZCO2) in ore-bearing quartz. The bulk chemical composition of the fluids in QIII is comparable to that found commonly in hydrothermal fluids associated with wolframite mineralization, where Na>K>Ca and HCO3>Cl>SO4. A dispersion in TH (226 to 350 °C) found in QIII, together with a variation in the degree of filling (0.5 to 0.7) and with the consequent variation of fluid densities (0.70 to 0.79), may result from changes in the fluid pressure regime below lithostatic pressure, suggesting vein filling related to tectonic events.

46 CFR 153.434 - Heat transfer coils within a tank.

Code of Federal Regulations, 2012 CFR

2012-10-01

... SHIPS CARRYING BULK LIQUID, LIQUEFIED GAS, OR COMPRESSED GAS HAZARDOUS MATERIALS Design and Equipment... the heat transfer fluid at a pressure greater than the pressure exerted on the heating or cooling...

Lagrangian transport properties of pulmonary interfacial flows

PubMed Central

Smith, Bradford J.; Lukens, Sarah; Yamaguchi, Eiichiro; Gaver, Donald P.

2012-01-01

Disease states characterized by airway fluid occlusion and pulmonary surfactant insufficiency, such as respiratory distress syndrome, have a high mortality rate. Understanding the mechanics of airway reopening, particularly involving surfactant transport, may provide an avenue to increase patient survival via optimized mechanical ventilation waveforms. We model the occluded airway as a liquid-filled rigid tube with the fluid phase displaced by a finger of air that propagates with both mean and sinusoidal velocity components. Finite-time Lyapunov exponent (FTLE) fields are employed to analyse the convective transport characteristics, taking note of Lagrangian coherent structures (LCSs) and their effects on transport. The Lagrangian perspective of these techniques reveals flow characteristics that are not readily apparent by observing Eulerian measures. These analysis techniques are applied to surfactant-free velocity fields determined computationally, with the boundary element method, and measured experimentally with micro particle image velocimetry (μ-PIV). We find that the LCS divides the fluid into two regimes, one advected upstream (into the thin residual film) and the other downstream ahead of the advancing bubble. At higher oscillatory frequencies particles originating immediately inside the LCS experience long residence times at the air–liquid interface, which may be conducive to surfactant transport. At high frequencies a well-mixed attractor region is identified; this volume of fluid cyclically travels along the interface and into the bulk fluid. The Lagrangian analysis is applied to velocity data measured with 0.01 mg ml−1 of the clinical pulmonary surfactant Infasurf in the bulk fluid, demonstrating flow field modifications with respect to the surfactant-free system that were not visible in the Eulerian frame. PMID:23049141

A qualitative view of cryogenic fluid injection into high speed flows

NASA Technical Reports Server (NTRS)

Hendricks, R. C.; Schlumberger, J.; Proctor, M.

1991-01-01

The injection of supercritical pressure, subcritical temperature fluids, into a 2-D, ambient, static temperature and static pressure supersonic tunnel and free jet supersonic nitrogen flow field was observed. Observed patterns with fluid air were the same as those observed for fluid nitrogen injected into the tunnel at 90 deg to the supersonic flow. The nominal injection pressure was of 6.9 MPa and tunnel Mach number was 2.7. When injected directly into and opposing the tunnel exhaust flow, the observed patterns with fluid air were similar to those observed for fluid nitrogen but appeared more diffusive. Cryogenic injection creates a high density region within the bow shock wake but the standoff distance remains unchanged from the gaseous value. However, as the temperature reaches a critical value, the shock faded and advanced into the supersonic stream. For both fluids, nitrogen and air, the phenomena was completely reversible.

Questionable inheritance: What Processes on Planetesimals Mean for the Bulk Composition of the Earth

NASA Astrophysics Data System (ADS)

Elkins-Tanton, L. T.

2015-12-01

Interrogating Earth's interior is limited to indirect means, such as seismic or magnetic fields, and relies heavily on modeling. A large body of literature either attempts to constrain the composition of the deep mantle by mass balancing the Earth with a chondritic composition, or to demonstrate that the Earth does not have a chondritic composition. These models provide predictions for the composition and density of the ultra-low shear wave provinces and for the D" layer, among others, and compare their results to structures resulting from seismic studies. The bulk composition of the Earth, however, remains an open question. We now know that the planets accreted from embryos that were already differentiated. The complexity of processes that occurred on planetesimals and planetary embryos are just beginning to come to light. Heating by radiogenic 26Al likely produced waves of hydration and dehydration in planetesimals. These free fluids may have carried a wide range of volatiles, moving them from the interior to the lid, or even losing them to space. Simultaneously, the first free fluids may have reacted with metals, producing oxides or sulfides. Further heating is required to reduce these to metals and made core formation possible; or perhaps the earliest cores are not fully metallic. These planetesimals and the embryos they were growing into were subjected to a series of impacts. As the work of Asphaug and his group have demonstrated, some of these are accretionary impacts, and some are hit-and-run, or destructive impacts. These destructive impacts may have reduced the thickness of Mercury's mantle, and stripped the mantle off the metal asteroid Psyche. Where, then would the shattered silicates from such collisions go? Asphuag suggests that at least in part they are added to the growing terrestrial planets. If the planetesimals and planetary embryos were compositionally heterogeneous because of interior fluid and magma movement, then the silicates blown off them by impacts would not have a bulk chondritic composition. The growing planets would not then have a bulk chondritic composition. This talk will discuss the possible ramifications of this model and its application to bulk Earth models.

Systems, compositions, and methods for fluid purification

DOEpatents

Ho, W.S. Winston; Verweij, Hendrik; Shqau, Krenar; Ramasubranian, Kartik

2015-12-22

Disclosed herein are membranes comprising a substrate, a support layer, and a selective layer. In some embodiments the membrane may further comprise a permeable layer. Methods of forming membranes are also disclosed comprising forming a support layer on a substrate, removing adsorbed species from the support layer, preparing a solution containing inorganic materials of a selective layer, contacting the support layer with the solution, drying the membrane, and exposing the membrane to rapid thermal processing. Also disclosed are methods of fluid purification comprising providing a membrane having a feed side and a permeable side, passing a fluid mixture across the feed side of the membrane, providing a driving force for transmembrane permeation, removing from the permeate side a permeate stream enriched in a purified fluid, and withdrawing from the feed side a fluid that is depleted in a purified fluid.

Generation of energy

DOEpatents

Kalina, Alexander I.

1984-01-01

A method of generating energy which comprises utilizing relatively lower temperature available heat to effect partial distillation of at least portion of a multicomponent working fluid stream at an intermediate pressure to generate working fluid fractions of differing compositions. The fractions are used to produce at least one main rich solution which is relatively enriched with respect to the lower boiling component, and to produce at least one lean solution which is relatively improverished with respect to the lower boiling component. The pressure of the main rich solution is increased whereafter it is evaporated to produce a charged gaseous main working fluid. The main working fluid is expanded to a low pressure level to release energy. The spent low pressure level working fluid is condensed in a main absorption stage by dissolving with cooling in the lean solution to regenerate an initial working fluid for reuse.

Electrically rechargeable REDOX flow cell

NASA Technical Reports Server (NTRS)

Thaller, L. H. (Inventor)

1976-01-01

A bulk energy storage system is designed with an electrically rechargeable reduction-oxidation (REDOX) cell divided into two compartments by a membrane, each compartment containing an electrode. An anode fluid is directed through the first compartment at the same time that a cathode fluid is directed through the second compartment. Means are provided for circulating the anode and cathode fluids, and the electrodes are connected to an intermittent or non-continuous electrical source, which when operating, supplies current to a load as well as to the cell to recharge it. Ancillary circuitry is provided for disconnecting the intermittent source from the cell at prescribed times and for circulating the anode and cathode fluids according to desired parameters and conditions.

Chlorine Isotope Evidence for Syn-Subduction Modification of Serpentinites by Interaction with Sediment-Derived Fluid

NASA Astrophysics Data System (ADS)

Selverstone, J.; Sharp, Z. D.

2012-12-01

High-pressure serpentinites and rodingites and high- to ultrahigh-pressure metasedimentary rocks from the Aosta region, Italy, preserve strikingly different chlorine isotope compositions that can be used to constrain the nature of fluid-rock interactions during subduction. Serpentinites and rodingitized gabbroic dikes subducted to 70-80 km have bulk δ37Cl values between -1.6 and +0.9‰ (median= -0.5‰, n=26 plus 5 replicates; one amphibole-vein outlier at -2.9‰). Serpentinite δ37Cl values are positively correlated with Cr ± Cl contents (r2= 0.97 and 0.58) and negatively correlated with CaO (r2=0.72). BSE imaging and X-ray mapping reveal up to three generations of compositionally distinct serpentine and chlorite in single samples. The youngest generation, which is most abundant, has the lowest chlorine content. Three rodingite samples contain abundant texturally early fluid inclusions. These samples were finely crushed and leached in 18 MΩ H2O to extract water-soluble chlorides. The leachates, which are assumed to record the compositions of the fluid inclusions, have δ37Cl values that are 0.7-1.5‰ lower than the corresponding bulk rock values. Leachate from the outlier amph-magnesite vein is indistinguishable from the bulk value at -2.7‰. There is almost no overlap between the Cl isotope compositions of HP serp/rod samples and associated HP/UHP metasedimentary rocks. Calcmica schists, diamond-bearing Mn nodules, and impure marbles subducted to >130 km and calcmica schists and Mn crusts transported to 70-80 km have δ37Cl values between -4.5 and -1.5‰ (median= -2.7‰, n=25 plus 7 replicates; two outlier points at -0.5‰). Primary fluid inclusions in the diamondiferous samples contain carbonate- and silicate-bearing aqueous fluids with very low chloride contents (Frezzotti et al., 2011, Nature Geosci). Taken together, these data record a history of progressive modification of serpentinites and rodingites by mixing with low-δ37Cl, low-Cl, high-Ca fluids during subduction and metamorphism. Serpentinites with the highest Cr contents have Cl isotopic compositions identical to those of modern seafloor serpentinites (δ37Cl=0.2-0.6‰), consistent with primary serpentinization by seawater (e.g., Barnes et al. 2009, Lithos). Low-Cr serpentinites record significant interaction with a Ca-rich fluid that shifted the rocks to lower δ37Cl values and diluted the original Cr and Cl contents. The fluid was likely derived from continuous devolatilization reactions in associated low-δ37Cl, calcareous metasedimentary rocks. These data have important implications for models of subduction mass transfer associated with antigorite breakdown. If serpentinites are commonly modified by interaction with metasedimentary fluids prior to antigorite dehydration, chemical signatures imparted during deserpentinization will reflect the integrated history of fluid-rock interaction in the subduction channel rather than an endmember "serpentinite signature". The data further suggest that Cl may be hydrophobic in HP/UHP carbonate-bearing aqueous fluids, resulting in generation of low-Cl fluid during metamorphic devolatilization.

Sustainable Fracturing Rationale to Reach Well Objectives: the Impact of Uncertainties and Complexities on Compliance Assurances

EPA Pesticide Factsheets

The presentation will discuss lessons learned; extract best practices and guidelines applied to injection of fluids and slurries during fracturing and exploration and production associated streams disposal.

Bound acoustic modes in the radiation continuum in isotropic layered systems without periodic structures

NASA Astrophysics Data System (ADS)

Maznev, A. A.; Every, A. G.

2018-01-01

We study the existence of guided acoustic modes in layered structures whose phase velocity is higher than that of bulk waves in a solid substrate or an adjacent fluid half space, which belong to the class of bound states in the radiation continuum (BICs). We demonstrate that in contrast to the electromagnetic case, non-symmetry-protected BICs exist in isotropic layered systems without periodic structures. Two systems supporting non-symmetry-protected sagittally polarized BICs have been identified: (i) a supported solid layer yields BICs whose phase velocity is higher than the transverse velocity of the substrate but lower than the longitudinal velocity; (ii) a supported solid layer loaded by a fluid half space supports BICs whose velocity is higher that the bulk velocity of the fluid but lower than acoustic velocities of the substrate. The latter case is a unique example of BICs in the sense that it does not involve an evanescent field in the fluid half space providing the radiation continuum. In either case, BICs are represented by isolated points in the dispersion relations located within "leaky" branches. We show that these BICs are robust with respect to small perturbations of the system parameters. Numerical results are provided for realistic materials combinations. We also show that no BICs exist in all-fluid layered structures, whereas in solid layered structures there are no shear horizontal BICs and no sagittally polarized BICs whose velocity exceeds the longitudinal velocity of the substrate.

Pore diameter effects on phase behavior of a gas condensate in graphitic one-and two-dimensional nanopores.

PubMed

Welch, William R W; Piri, Mohammad

2016-01-01

Molecular dynamics (MD) simulations were performed on a hydrocarbon mixture representing a typical gas condensate composed mostly of methane and other small molecules with small fractions of heavier hydrocarbons, representative of mixtures found in tight shale reservoirs. The fluid was examined both in bulk and confined to graphitic nano-scale slits and pores. Numerous widths and diameters of slits and pores respectively were examined under variable pressures at 300 K in order to find conditions in which the fluid at the center of the apertures would not be affected by capillary condensation due to the oil-wet walls. For the bulk fluid, retrograde phase behavior was verified by liquid volumes obtained from Voronoi tessellations. In cases of both one and two-dimensional confinement, for the smallest apertures, heavy molecules aggregated inside the pore space and compression of the gas outside the solid structure lead to decreases in density of the confined fluid. Normal density/pressure relationships were observed for slits having gaps of above 3 nm and pores having diameters above 6 nm. At 70 bar, the minimum gap width at which the fluid could pass through the center of slits without condensation effects was predicted to be 6 nm and the corresponding diameter in pores was predicted to be 8 nm. The models suggest that in nanoscale networks involving pores smaller than these limiting dimensions, capillary condensation should significantly impede transmission of natural gases with similar composition.

Waving of filaments induced by molecular motors

NASA Astrophysics Data System (ADS)

de Canio, Gabriele; Lauga, Eric; Goldstein, Raymond E.

2017-11-01

In many cellular phenomena, for example cytoplasmic streaming, molecular motors translocate along microtubules carrying cargoes which entrain fluid. The piconewton forces that motors produce can be sufficient to bend or buckle the filaments. When large numbers of such forced filaments interact through the surrounding fluid, as in particular stages of oocyte development in Drosophila melanogaster, complex dynamics are observed, but the mechanism underlying them has remained unclear. By using a combination of theory and numerical simulations, we study a simplified microtubules-molecular motor system in a viscous fluid and show that it can capture the wave-like filament motion dynamics observed in experiments.

Laser Soap Fountain

NASA Astrophysics Data System (ADS)

Foley, Tyler; Pegram, Matthew; Jenkins, Zachary; Hester, Brooke C.; Burris, Jennifer L.

2015-01-01

We have developed an eye-catching demonstration that showcases a variety of physics topics from total internal reflection to electrostatics to non-Newtonian fluid dynamics, including the Kaye effect. The essential components of the demonstration include a vertical stream of liquid soap in which a laser pointer is internally reflected, and which subsequently hits an inclined plane. As the liquid soap, a non-Newtonian fluid, begins to accumulate into a pile, its shear properties change and the incoming fluid rebounds from the pile, forming striking parabolic arcs. We present here a readily reproducible and inexpensive version of a laser soap fountain.

Viscous streaming for locomotion and transport

NASA Astrophysics Data System (ADS)

Gazzola, Mattia; Parthasarathy, Tejaswin

2017-11-01

Rectified and oscillatory flows associated with vibrating boundaries have been employed in a variety of tasks, especially in microfluidics. The associated fluid mechanics is well known in the case of simple geometries, cylinders in particular, yet little is known in the case of active, complex systems. Motivated by potential applications in swimming mini-bots, we established an accurate and robust computational framework to investigate the flow behavior associated with oscillations of multiple and deforming shapes with an emphasis on streaming assisted locomotion and transport systems.

Beyond single-stream with the Schrödinger method

NASA Astrophysics Data System (ADS)

Uhlemann, Cora; Kopp, Michael

2016-10-01

We investigate large scale structure formation of collisionless dark matter in the phase space description based on the Vlasov-Poisson equation. We present the Schrödinger method, originally proposed by \\cite{WK93} as numerical technique based on the Schrödinger Poisson equation, as an analytical tool which is superior to the common standard pressureless fluid model. Whereas the dust model fails and develops singularities at shell crossing the Schrödinger method encompasses multi-streaming and even virialization.

Molecular orientation in a dielectric liquid-vapor interphase

NASA Astrophysics Data System (ADS)

Chacón, E.; Mederos, L.; Navascués, G.; Tarazona, P.

1985-04-01

The density functional theory of Chacón et al. is used to study the molecular orientation in an interphase of a weak dipolar fluid. Explicit expressions are obtained using standard perturbation techniques. Molecular orientation, local susceptibility, and the Gibbsean surface susceptibility are evaluated for a Stockmayer model of dipolar fluid. The effect of the surface structure on the bulk ferroelectric transition is discussed in the light of the present theory and the numerical results.

A computational modeling approach of the jet-like acoustic streaming and heat generation induced by low frequency high power ultrasonic horn reactors.

PubMed

Trujillo, Francisco Javier; Knoerzer, Kai

2011-11-01

High power ultrasound reactors have gained a lot of interest in the food industry given the effects that can arise from ultrasonic-induced cavitation in liquid foods. However, most of the new food processing developments have been based on empirical approaches. Thus, there is a need for mathematical models which help to understand, optimize, and scale up ultrasonic reactors. In this work, a computational fluid dynamics (CFD) model was developed to predict the acoustic streaming and induced heat generated by an ultrasonic horn reactor. In the model it is assumed that the horn tip is a fluid inlet, where a turbulent jet flow is injected into the vessel. The hydrodynamic momentum rate of the incoming jet is assumed to be equal to the total acoustic momentum rate emitted by the acoustic power source. CFD velocity predictions show excellent agreement with the experimental data for power densities higher than W(0)/V ≥ 25kWm(-3). This model successfully describes hydrodynamic fields (streaming) generated by low-frequency-high-power ultrasound. Crown Copyright © 2011. Published by Elsevier B.V. All rights reserved.

Nature and origin of fluids in granulite facies metamorphism

NASA Technical Reports Server (NTRS)

Newton, R. C.

1988-01-01

The various models for the nature and origin of fluids in granulite facies metamorphism were summarized. Field and petrologic evidence exists for both fluid-absent and fluid-present deep crustal metamorphism. The South Indian granulite province is often cited as a fluid-rich example. The fluids must have been low in H2O and thus high in CO2. Deep crustal and subcrustal sources of CO2 are as yet unproven possibilities. There is much recent discussion of the possible ways in which deep crustal melts and fluids could have interacted in granulite metamorphism. Possible explanations for the characteristically low activity of H2O associated with granulite terranes were discussed. Granulites of the Adirondacks, New York, show evidence for vapor-absent conditions, and thus appear different from those of South India, for which CO2 streaming was proposed. Several features, such as the presence of high-density CO2 fluid inclusions, that may be misleading as evidence for CO2-saturated conditions during metamorphism, were discussed.

Nanopore Confinement of C-O-H Fluids Relevant to Subsurface Energy Systems

NASA Astrophysics Data System (ADS)

Cole, D. R.

2016-12-01

Complex intermolecular interactions of C-O-H fluids (e.g., H2O, CO2, CH4) result in their unique thermophysical properties, including large deviations in the volumetric properties from ideality, vapor-liquid equilibria, and critical phenomena as these fluids encounter different pressure-temperature-pore network conditions in the crust. Development of a comprehensive understanding of the structures, dynamics, and reactivity at multiple length scales (molecular to macroscopic) over wide ranges of state conditions and composition is foundational to advances in quantifying geochemical processes involving mineral-fluid interfaces. The size, distribution and connectivity of these confined geometries dictate how fluids migrate into and through these micro- and nano-environments, wet and react with the solid. This presentation will provide an overview of the application of state-of-the-art experimental, analytical and computational tools to assess key features of the fluid-matrix interaction. The multidisciplinary approaches highlighted will include neutron scattering and NMR experiments, thermodynamic measurements and molecular-level simulations to quantitatively assess molecular properties of different mixtures of C-O-H fluids in nanpores. Key results include: (1) The addition of a second carbon-bearing phase or water has a profound effect on the competition for sorption sites, phase chemistry and the dynamical properties of all phases present in the pore. (2) Low solubility phases such as methane may exhibit profound increases in concentration in nanopores in the presence of water at elevated pressures and ambient temperature compared to bulk values. (3) Methane permeability through the hydrated pores is strongly dependent on the solid substrate and local properties of confined water, including its structure and, more importantly, evolution of solvation free energy and hydrogen bond structure. (4) Under certain conditions preferential adsorption of the fluids in the narrow pores can produce a shift in the equilibrium distribution of mixed volatiles present in adjoining fractures (aka the bulk portion of the system).

Size Control of Sessile Microbubbles for Reproducibly Driven Acoustic Streaming

NASA Astrophysics Data System (ADS)

Volk, Andreas; Kähler, Christian J.

2018-05-01

Acoustically actuated bubbles are receiving growing interest in microfluidic applications, as they induce a streaming field that can be used for particle sorting and fluid mixing. An essential but often unspoken challenge in such applications is to maintain a constant bubble size to achieve reproducible conditions. We present an automatized system for the size control of a cylindrical bubble that is formed at a blind side pit of a polydimethylsiloxane microchannel. Using a pressure control system, we adapt the protrusion depth of the bubble into the microchannel to a precision of approximately 0.5 μ m on a timescale of seconds. By comparing the streaming field generated by bubbles of width 80 μ m with a protrusion depth between -12 and 60 μ m , we find that the mean velocity of the induced streaming fields varies by more than a factor of 4. We also find a qualitative change of the topology of the streaming field. Both observations confirm the importance of the bubble size control system in order to achieve reproducible and reliable bubble-driven streaming experiments.

Optimized open-flow mixing: insights from microbubble streaming

NASA Astrophysics Data System (ADS)

Rallabandi, Bhargav; Wang, Cheng; Guo, Lin; Hilgenfeldt, Sascha

2015-11-01

Microbubble streaming has been developed into a robust and powerful flow actuation technique in microfluidics. Here, we study it as a paradigmatic system for microfluidic mixing under a continuous throughput of fluid (open-flow mixing), providing a systematic optimization of the device parameters in this practically important situation. Focusing on two-dimensional advective stirring (neglecting diffusion), we show through numerical simulation and analytical theory that mixing in steady streaming vortices becomes ineffective beyond a characteristic time scale, necessitating the introduction of unsteadiness. By duty cycling the streaming, such unsteadiness is introduced in a controlled fashion, leading to exponential refinement of the advection structures. The rate of refinement is then optimized for particular parameters of the time modulation, i.e. a particular combination of times for which the streaming is turned ``on'' and ``off''. The optimized protocol can be understood theoretically using the properties of the streaming vortices and the throughput Poiseuille flow. We can thus infer simple design principles for practical open flow micromixing applications, consistent with experiments. Current Address: Mechanical and Aerospace Engineering, Princeton University.

Method For Chemical Sensing Using A Microfabricated Teeter-Totter Resonator

DOEpatents

Adkins, Douglas Ray; Heller, Edwin J.; Shul, Randy J.

2004-11-30

A method for sensing a chemical analyte in a fluid stream comprises providing a microfabricated teeter-totter resonator that relies upon a Lorentz force to cause oscillation in a paddle, applying a static magnetic field substantially aligned in-plane with the paddle, energizing a current conductor line on a surface of the paddle with an alternating electrical current to generate the Lorentz force, exposing the resonator to the analyte, and detecting the response of the oscillatory motion of the paddle to the chemical analyte. Preferably, a chemically sensitive coating is disposed on at least one surface of the paddle to enhance the sorption of the analyte by the paddle. The concentration of the analyte in a fluid stream can be determined by measuring the change in the resonant frequency or phase of the teeter-totter resonator as the chemical analyte is added to or removed from the paddle.