Real-Time Dispatch of Petroleum Tank Trucks.

DTIC Science & Technology

1979-12-01

dispatches for each bulk terminal from which loads are hauled. The dispatchers, located at a central national order processing facility, must each...of an order processor and new capa- bilities to, for instance, trace orders. Also, uniform control of thef order processing function is desirable, if

40 CFR 63.11088 - What requirements must I meet for gasoline loading racks if my facility is a bulk gasoline...

Code of Federal Regulations, 2014 CFR

2014-07-01

... gasoline loading racks if my facility is a bulk gasoline terminal, pipeline breakout station, or pipeline... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline... § 63.11088 What requirements must I meet for gasoline loading racks if my facility is a bulk gasoline...

40 CFR 63.11087 - What requirements must I meet for gasoline storage tanks if my facility is a bulk gasoline...

Code of Federal Regulations, 2012 CFR

2012-07-01

... gasoline storage tanks if my facility is a bulk gasoline terminal, pipeline breakout station, or pipeline... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline... § 63.11087 What requirements must I meet for gasoline storage tanks if my facility is a bulk gasoline...

40 CFR 63.11087 - What requirements must I meet for gasoline storage tanks if my facility is a bulk gasoline...

Code of Federal Regulations, 2014 CFR

2014-07-01

... gasoline storage tanks if my facility is a bulk gasoline terminal, pipeline breakout station, or pipeline... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline... § 63.11087 What requirements must I meet for gasoline storage tanks if my facility is a bulk gasoline...

40 CFR 63.11087 - What requirements must I meet for gasoline storage tanks if my facility is a bulk gasoline...

Code of Federal Regulations, 2010 CFR

2010-07-01

... gasoline storage tanks if my facility is a bulk gasoline terminal, pipeline breakout station, or pipeline... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline... § 63.11087 What requirements must I meet for gasoline storage tanks if my facility is a bulk gasoline...

40 CFR 63.11088 - What requirements must I meet for gasoline loading racks if my facility is a bulk gasoline...

Code of Federal Regulations, 2010 CFR

2010-07-01

... gasoline loading racks if my facility is a bulk gasoline terminal, pipeline breakout station, or pipeline... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline... § 63.11088 What requirements must I meet for gasoline loading racks if my facility is a bulk gasoline...

40 CFR 63.11088 - What requirements must I meet for gasoline loading racks if my facility is a bulk gasoline...

Code of Federal Regulations, 2013 CFR

2013-07-01

... gasoline loading racks if my facility is a bulk gasoline terminal, pipeline breakout station, or pipeline... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline... § 63.11088 What requirements must I meet for gasoline loading racks if my facility is a bulk gasoline...

40 CFR 63.11087 - What requirements must I meet for gasoline storage tanks if my facility is a bulk gasoline...

Code of Federal Regulations, 2013 CFR

2013-07-01

... gasoline storage tanks if my facility is a bulk gasoline terminal, pipeline breakout station, or pipeline... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline... § 63.11087 What requirements must I meet for gasoline storage tanks if my facility is a bulk gasoline...

40 CFR 63.11088 - What requirements must I meet for gasoline loading racks if my facility is a bulk gasoline...

Code of Federal Regulations, 2011 CFR

2011-07-01

... gasoline loading racks if my facility is a bulk gasoline terminal, pipeline breakout station, or pipeline... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline... § 63.11088 What requirements must I meet for gasoline loading racks if my facility is a bulk gasoline...

40 CFR 63.11087 - What requirements must I meet for gasoline storage tanks if my facility is a bulk gasoline...

Code of Federal Regulations, 2011 CFR

2011-07-01

... gasoline storage tanks if my facility is a bulk gasoline terminal, pipeline breakout station, or pipeline... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline... § 63.11087 What requirements must I meet for gasoline storage tanks if my facility is a bulk gasoline...

40 CFR 63.11088 - What requirements must I meet for gasoline loading racks if my facility is a bulk gasoline...

Code of Federal Regulations, 2012 CFR

2012-07-01

... gasoline loading racks if my facility is a bulk gasoline terminal, pipeline breakout station, or pipeline... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Source Category: Gasoline... § 63.11088 What requirements must I meet for gasoline loading racks if my facility is a bulk gasoline...

40 CFR 63.11100 - What definitions apply to this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

... Distribution Bulk Terminals, Bulk Plants, and Pipeline Facilities Other Requirements and Information § 63.11100... authority to implement the provisions of this subpart). Bulk gasoline plant means any gasoline storage and distribution facility that receives gasoline by pipeline, ship or barge, or cargo tank and has a gasoline...

33 CFR 154.1210 - Purpose and applicability.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for Animal Fats and Vegetable Oils Facilities § 154.1210 Purpose and applicability. (a) The requirements of this... fats or vegetable oils including— (1) A fixed MTR facility capable of transferring oil in bulk, to or...

33 CFR 154.1210 - Purpose and applicability.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for Animal Fats and Vegetable Oils Facilities § 154.1210 Purpose and applicability. (a) The requirements of this... fats or vegetable oils including— (1) A fixed MTR facility capable of transferring oil in bulk, to or...

Bulk Enthalpy Calculations in the Arc Jet Facility at NASA ARC

NASA Technical Reports Server (NTRS)

Thompson, Corinna S.; Prabhu, Dinesh; Terrazas-Salinas, Imelda; Mach, Jeffrey J.

2011-01-01

The Arc Jet Facilities at NASA Ames Research Center generate test streams with enthalpies ranging from 5 MJ/kg to 25 MJ/kg. The present work describes a rigorous method, based on equilibrium thermodynamics, for calculating the bulk enthalpy of the flow produced in two of these facilities. The motivation for this work is to determine a dimensionally-correct formula for calculating the bulk enthalpy that is at least as accurate as the conventional formulas that are currently used. Unlike previous methods, the new method accounts for the amount of argon that is present in the flow. Comparisons are made with bulk enthalpies computed from an energy balance method. An analysis of primary facility operating parameters and their associated uncertainties is presented in order to further validate the enthalpy calculations reported herein.

40 CFR 60.500 - Applicability and designation of affected facility.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Performance for Bulk Gasoline Terminals § 60.500 Applicability and designation of affected facility. (a) The... bulk gasoline terminal which deliver liquid product into gasoline tank trucks. (b) Each facility under... technologies (BDT). The numerical emission limits in this standard are expressed in terms of total organic...

40 CFR 60.500 - Applicability and designation of affected facility.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Performance for Bulk Gasoline Terminals § 60.500 Applicability and designation of affected facility. (a) The... bulk gasoline terminal which deliver liquid product into gasoline tank trucks. (b) Each facility under... technologies (BDT). The numerical emission limits in this standard are expressed in terms of total organic...

21 CFR 226.30 - Equipment.

Code of Federal Regulations, 2010 CFR

2010-04-01

... CURRENT GOOD MANUFACTURING PRACTICE FOR TYPE A MEDICATED ARTICLES Construction and Maintenance of Facilities and Equipment § 226.30 Equipment. Equipment used for the manufacture, processing, packaging, bulk... maintained in a clean and orderly manner and shall be of suitable design, size, construction, and location to...

A robust, melting class bulk superhydrophobic material with heat-healing and self-cleaning properties

PubMed Central

Ramakrishna, S.; Santhosh Kumar, K. S.; Mathew, Dona; Reghunadhan Nair, C. P.

2015-01-01

Superhydrophobic (SH) materials are essential for a myriad of applications such as anti-icing and self-cleaning due to their extreme water repellency. A single, robust material simultaneously possessing melt-coatability, bulk water repellency, self-cleanability, self-healability, self-refreshability, and adhesiveness has been remaining an elusive goal. We demonstrate a unique class of melt-processable, bulk SH coating by grafting long alkyl chains on silica nanoparticle surface by a facile one-step method. The well-defined nanomaterial shows SH property in the bulk and is found to heal macro-cracks on gentle heating. It retains wettability characteristics even after abrading with a sand paper. The surface regenerates SH features (due to reversible self-assembly of nano structures) quickly at ambient temperature even after cyclic water impalement, boiling water treatment and multiple finger rubbing tests. It exhibits self-cleaning properties on both fresh and cut surfaces. This kind of coating, hitherto undisclosed, is expected to be a breakthrough in the field of melt-processable SH coatings. PMID:26679096

Appendix D - Sample Bulk Storage Facility Plan

EPA Pesticide Factsheets

This sample Spill Prevention, Control and Countermeasure (SPCC) Plan in Appendix D is intended to provide examples and illustrations of how a bulk storage facility could address a variety of scenarios in its SPCC Plan.

RELEASE OF DRIED RADIOACTIVE WASTE MATERIALS TECHNICAL BASIS DOCUMENT

DOE Office of Scientific and Technical Information (OSTI.GOV)

KOZLOWSKI, S.D.

2007-05-30

This technical basis document was developed to support RPP-23429, Preliminary Documented Safety Analysis for the Demonstration Bulk Vitrification System (PDSA) and RPP-23479, Preliminary Documented Safety Analysis for the Contact-Handled Transuranic Mixed (CH-TRUM) Waste Facility. The main document describes the risk binning process and the technical basis for assigning risk bins to the representative accidents involving the release of dried radioactive waste materials from the Demonstration Bulk Vitrification System (DBVS) and to the associated represented hazardous conditions. Appendices D through F provide the technical basis for assigning risk bins to the representative dried waste release accident and associated represented hazardous conditionsmore » for the Contact-Handled Transuranic Mixed (CH-TRUM) Waste Packaging Unit (WPU). The risk binning process uses an evaluation of the frequency and consequence of a given representative accident or represented hazardous condition to determine the need for safety structures, systems, and components (SSC) and technical safety requirement (TSR)-level controls. A representative accident or a represented hazardous condition is assigned to a risk bin based on the potential radiological and toxicological consequences to the public and the collocated worker. Note that the risk binning process is not applied to facility workers because credible hazardous conditions with the potential for significant facility worker consequences are considered for safety-significant SSCs and/or TSR-level controls regardless of their estimated frequency. The controls for protection of the facility workers are described in RPP-23429 and RPP-23479. Determination of the need for safety-class SSCs was performed in accordance with DOE-STD-3009-94, Preparation Guide for US. Department of Energy Nonreactor Nuclear Facility Documented Safety Analyses, as described below.« less

Development of a Bulk-Format System to Harvest, Handle, Store, and Deliver High-Tonnage Low-Moisture Switchgrass Feedstock

DOE Office of Scientific and Technical Information (OSTI.GOV)

Womac, Alvin; Groothuis, Mitch; Westover, Tyler

2013-09-24

This project evaluates and compares comprehensive feedstock logistics systems (FLS), where a FLS is defined to comprehensively span from biomass material standing in a field to conveyance of a uniform, industrial-milled product into the throat of a biomass conversion facility (BCF). Elements of the bulk-format FLS evaluated in this project include: field-standing switchgrass dry chopped into bulk format on the farm, hauled (either loose or bulk compacted) to storage, stored with confining overburden in a protective facility, reclaimed and conveyed to bulk-format discharge, bulk compacted into an ejector trailer, and conveyed as bulk flow into the BCF. In this FLSmore » evaluation, bulk storage bins served as a controlled and sensored proxy for large commercial stacks protected from moisture with a membrane cover.« less

A COMPREHENSIVE TECHNICAL REVIEW OF THE DEMONSTRATION BULK VITRIFICATION SYSTEM

DOE Office of Scientific and Technical Information (OSTI.GOV)

SCHAUS, P.S.

2006-09-29

In May 2006, CH2M Hill Hanford Group, Inc. chartered an Expert Review Panel (ERP) to review the current status of the Demonstration Bulk Vitrification System (DBVS). It is the consensus of the ERP that bulk vitrification is a technology that requires further development and evaluation to determine its potential for meeting the Hanford waste stabilization mission. No fatal flaws (issues that would jeopardize the overall DBVS mission that cannot be mitigated) were found, given the current state of the project. However, a number of technical issues were found that could significantly affect the project's ability to meet its overall missionmore » as stated in the project ''Justification of Mission Need'' document, if not satisfactorily resolved. The ERP recognizes that the project has changed from an accelerated schedule demonstration project to a formally chartered project that must be in full compliance with DOE 413.3 requirements. The perspective of the ERP presented herein, is measured against the formally chartered project as stated in the approved Justification of Mission Need document. A justification of Mission Need document was approved in July 2006 which defined the objectives for the DBVS Project. In this document, DOE concluded that bulk vitrification is a viable technology that requires additional development to determine its potential applicability to treatment of a portion of the Hanford low activity waste. The DBVS mission need statement now includes the following primary objectives: (1) process approximately 190,000 gallons of Tank S-109 waste into fifty 100 metric ton boxes of vitrified product; (2) store and dispose of these boxes at Hanford's Integrated Disposal Facility (IDF); (3) evaluate the waste form characteristics; (4) gather pilot plant operability data, and (5) develop the overall life cycle system performance of bulk vitrification and produce a comparison of the bulk vitrification process to building a second LAW Immobilization facility or other supplemental treatment alternatives as provided in M-62-08.« less

A combined arc-melting and tilt-casting furnace for the manufacture of high-purity bulk metallic glass materials.

PubMed

Soinila, E; Pihlajamäki, T; Bossuyt, S; Hänninen, H

2011-07-01

An arc-melting furnace which includes a tilt-casting facility was designed and built, for the purpose of producing bulk metallic glass specimens. Tilt-casting was chosen because reportedly, in combination with high-purity processing, it produces the best fatigue endurance in Zr-based bulk metallic glasses. Incorporating the alloying and casting facilities in a single piece of equipment reduces the amount of laboratory space and capital investment needed. Eliminating the sample transfer step from the production process also saves time and reduces sample contamination. This is important because the glass forming ability in many alloy systems, such as Zr-based glass-forming alloys, deteriorates rapidly with increasing oxygen content of the specimen. The challenge was to create a versatile instrument, in which high purity conditions can be maintained throughout the process, even when melting alloys with high affinity for oxygen. Therefore, the design provides a high-vacuum chamber to be filled with a low-oxygen inert atmosphere, and takes special care to keep the system hermetically sealed throughout the process. In particular, movements of the arc-melting electrode and sample manipulator arm are accommodated by deformable metal bellows, rather than sliding O-ring seals, and the whole furnace is tilted for tilt-casting. This performance of the furnace is demonstrated by alloying and casting Zr(55)Cu(30)Al(10)Ni(5) directly into rods up to ø 10 mm which are verified to be amorphous by x-ray diffraction and differential scanning calorimetry, and to exhibit locally ductile fracture at liquid nitrogen temperature.

Bulk heterojunction perovskite solar cells based on room temperature deposited hole-blocking layer: Suppressed hysteresis and flexible photovoltaic application

NASA Astrophysics Data System (ADS)

Chen, Zhiliang; Yang, Guang; Zheng, Xiaolu; Lei, Hongwei; Chen, Cong; Ma, Junjie; Wang, Hao; Fang, Guojia

2017-05-01

Perovskite solar cells have developed rapidly in recent years as the third generation solar cells. In spite of the great improvement achieved, there still exist some issues such as undesired hysteresis and indispensable high temperature process. In this work, bulk heterojunction perovskite-phenyl-C61-butyric acid methyl ester solar cells have been prepared to diminish hysteresis using a facile two step spin-coating method. Furthermore, high quality tin oxide films are fabricated using pulse laser deposition technique at room temperature without any annealing procedure. The as fabricated tin oxide film is successfully applied in bulk heterojunction perovskite solar cells as a hole blocking layer. Bulk heterojunction devices based on room temperature tin oxide exhibit almost hysteresis-free characteristics with power conversion efficiency of 17.29% and 14.0% on rigid and flexible substrates, respectively.

Comparison of mass balance, energy consumption and cost of composting facilities for different types of organic waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang Huijun; Matsuto, Toshihiko, E-mail: matsuto@eng.hokudai.ac.jp

2011-03-15

Mass balance, energy consumption and cost are basic pieces of information necessary for selecting a waste management technology. In this study, composting facilities that treat different types of organic waste were studied by questionnaire survey and via a chemical analysis of material collected at the facilities. The mass balance was calculated on a dry weight basis because the moisture content of organic waste was very high. Even though the ratio of bulking material to total input varied in the range 0-65% on a dry basis, the carbon and ash content, carbon/nitrogen ratio, heavy metal content and inorganic nutrients in themore » compost were clearly influenced by the different characteristics of the input waste. The use of bulking material was not correlated with ash or elemental content in the compost. The operating costs were categorised into two groups. There was some economy of scale for wages and maintenance cost, but the costs for electricity and fuel were proportional to the amount of waste. Differences in operating costs can be explained by differences in the process characteristics.« less

77 FR 5849 - Manufacturer of Controlled Substances; Notice of Registration

Federal Register 2010, 2011, 2012, 2013, 2014

2012-02-06

... (DEA) to be registered as a bulk manufacturer of Remifentanil (9739), the basic class of controlled substance in schedule II. The company plans to utilize this facility to manufacture small quantities of the... manufacturing facility in West Deptford, New Jersey. The controlled substances manufactured in bulk at this...

40 CFR 63.11095 - What are my reporting requirements?

Code of Federal Regulations, 2010 CFR

2010-07-01

... Distribution Bulk Terminals, Bulk Plants, and Pipeline Facilities Notifications, Records, and Reports § 63...) Each owner or operator of a bulk gasoline plant or a pipeline pumping station shall submit a semiannual...

NRL Review, 2008

DTIC Science & Technology

2008-01-01

submicron powders in situ. Facilities to process powder into bulk specimens by hot and cold isostatic pressing permit a variety of consolidation...two types of nanoparticles, (YxHo1–x)2O3 and Cu - Ba-Ho-Y (exact stoichiometry yet to be determined), are formed during the deposition process ... Properties by Tailor- ing Nanoparticles in Holmium-doped YBa 2 Cu 3 O 7-d Superconductors 187 Molecular Memory Circuits Using a Virus as a Template 189

Real time monitoring of powder blend bulk density for coupled feed-forward/feed-back control of a continuous direct compaction tablet manufacturing process.

PubMed

Singh, Ravendra; Román-Ospino, Andrés D; Romañach, Rodolfo J; Ierapetritou, Marianthi; Ramachandran, Rohit

2015-11-10

The pharmaceutical industry is strictly regulated, where precise and accurate control of the end product quality is necessary to ensure the effectiveness of the drug products. For such control, the process and raw materials variability ideally need to be fed-forward in real time into an automatic control system so that a proactive action can be taken before it can affect the end product quality. Variations in raw material properties (e.g., particle size), feeder hopper level, amount of lubrication, milling and blending action, applied shear in different processing stages can affect the blend density significantly and thereby tablet weight, hardness and dissolution. Therefore, real time monitoring of powder bulk density variability and its incorporation into the automatic control system so that its effect can be mitigated proactively and efficiently is highly desired. However, real time monitoring of powder bulk density is still a challenging task because of different level of complexities. In this work, powder bulk density which has a significant effect on the critical quality attributes (CQA's) has been monitored in real time in a pilot-plant facility, using a NIR sensor. The sensitivity of the powder bulk density on critical process parameters (CPP's) and CQA's has been analyzed and thereby feed-forward controller has been designed. The measured signal can be used for feed-forward control so that the corrective actions on the density variations can be taken before they can influence the product quality. The coupled feed-forward/feed-back control system demonstrates improved control performance and improvements in the final product quality in the presence of process and raw material variations. Copyright © 2015 Elsevier B.V. All rights reserved.

EnergySolution's Clive Disposal Facility Operational Research Model - 13475

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nissley, Paul; Berry, Joanne

2013-07-01

EnergySolutions owns and operates a licensed, commercial low-level radioactive waste disposal facility located in Clive, Utah. The Clive site receives low-level radioactive waste from various locations within the United States via bulk truck, containerised truck, enclosed truck, bulk rail-cars, rail boxcars, and rail inter-modals. Waste packages are unloaded, characterized, processed, and disposed of at the Clive site. Examples of low-level radioactive waste arriving at Clive include, but are not limited to, contaminated soil/debris, spent nuclear power plant components, and medical waste. Generators of low-level radioactive waste typically include nuclear power plants, hospitals, national laboratories, and various United States government operatedmore » waste sites. Over the past few years, poor economic conditions have significantly reduced the number of shipments to Clive. With less revenue coming in from processing shipments, Clive needed to keep its expenses down if it was going to maintain past levels of profitability. The Operational Research group of EnergySolutions were asked to develop a simulation model to help identify any improvement opportunities that would increase overall operating efficiency and reduce costs at the Clive Facility. The Clive operations research model simulates the receipt, movement, and processing requirements of shipments arriving at the facility. The model includes shipment schedules, processing times of various waste types, labor requirements, shift schedules, and site equipment availability. The Clive operations research model has been developed using the WITNESS{sup TM} process simulation software, which is developed by the Lanner Group. The major goals of this project were to: - identify processing bottlenecks that could reduce the turnaround time from shipment arrival to disposal; - evaluate the use (or idle time) of labor and equipment; - project future operational requirements under different forecasted scenarios. By identifying processing bottlenecks and unused equipment and/or labor, improvements to operating efficiency could be determined and appropriate cost saving measures implemented. Model runs forecasting various scenarios helped illustrate potential impacts of certain conditions (e.g. 20% decrease in shipments arrived), variables (e.g. 20% decrease in labor), or other possible situations. (authors)« less

Proceedings of the Goddard Space Flight Center Workshop on Robotics for Commercial Microelectronic Processes in Space

NASA Technical Reports Server (NTRS)

1987-01-01

Potential applications of robots for cost effective commercial microelectronic processes in space were studied and the associated robotic requirements were defined. Potential space application areas include advanced materials processing, bulk crystal growth, and epitaxial thin film growth and related processes. All possible automation of these processes was considered, along with energy and environmental requirements. Aspects of robot capabilities considered include system intelligence, ROM requirements, kinematic and dynamic specifications, sensor design and configuration, flexibility and maintainability. Support elements discussed included facilities, logistics, ground support, launch and recovery, and management systems.

Method for exfoliation of hexagonal boron nitride

NASA Technical Reports Server (NTRS)

Lin, Yi (Inventor); Connell, John W. (Inventor)

2012-01-01

A new method is disclosed for the exfoliation of hexagonal boron nitride into mono- and few-layered nanosheets (or nanoplatelets, nanomesh, nanoribbons). The method does not necessarily require high temperature or vacuum, but uses commercially available h-BN powders (or those derived from these materials, bulk crystals) and only requires wet chemical processing. The method is facile, cost efficient, and scalable. The resultant exfoliated h-BN is dispersible in an organic solvent or water thus amenable for solution processing for unique microelectronic or composite applications.

Mirror Technology

NASA Technical Reports Server (NTRS)

1992-01-01

Under a NASA contract, MI-CVD developed a process for producing bulk silicon carbide by means of a chemical vapor deposition process. The technology allows growth of a high purity material with superior mechanical/thermal properties and high polishability - ideal for mirror applications. The company employed the technology to develop three research mirrors for NASA Langley and is now marketing it as CVD SILICON CARBIDE. Its advantages include light weight, thermal stability and high reflectivity. The material has nuclear research facility applications and is of interest to industrial users of high power lasers.

33 CFR 127.313 - Bulk storage.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Bulk storage. 127.313 Section 127.313 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED... Waterfront Facilities Handling Liquefied Natural Gas Operations § 127.313 Bulk storage. (a) The operator...

33 CFR 127.313 - Bulk storage.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Bulk storage. 127.313 Section 127.313 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED... Waterfront Facilities Handling Liquefied Natural Gas Operations § 127.313 Bulk storage. (a) The operator...

33 CFR 127.313 - Bulk storage.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Bulk storage. 127.313 Section 127.313 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED... Waterfront Facilities Handling Liquefied Natural Gas Operations § 127.313 Bulk storage. (a) The operator...

33 CFR 127.313 - Bulk storage.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Bulk storage. 127.313 Section 127.313 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED... Waterfront Facilities Handling Liquefied Natural Gas Operations § 127.313 Bulk storage. (a) The operator...

33 CFR 127.313 - Bulk storage.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Bulk storage. 127.313 Section 127.313 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED... Waterfront Facilities Handling Liquefied Natural Gas Operations § 127.313 Bulk storage. (a) The operator...

A Batch Feeder for Inhomogeneous Bulk Materials

NASA Astrophysics Data System (ADS)

Vislov, I. S.; Kladiev, S. N.; Slobodyan, S. M.; Bogdan, A. M.

2016-04-01

The work includes the mechanical analysis of mechanical feeders and batchers that find application in various technological processes and industrial fields. Feeders are usually classified according to their design features into two groups: conveyor-type feeders and non-conveyor feeders. Batchers are used to batch solid bulk materials. Less frequently, they are used for liquids. In terms of a batching method, they are divided into volumetric and weighting batchers. Weighting batchers do not provide for sufficient batching accuracy. Automatic weighting batchers include a mass controlling sensor and systems for automatic material feed and automatic mass discharge control. In terms of operating principle, batchers are divided into gravitational batchers and batchers with forced feed of material using conveyors and pumps. Improved consumption of raw materials, decreased loss of materials, ease of use in automatic control systems of industrial facilities allows increasing the quality of technological processes and improve labor conditions. The batch feeder suggested by the authors is a volumetric batcher that has no comparable counterparts among conveyor-type feeders and allows solving the problem of targeted feeding of bulk material batches increasing reliability and hermeticity of the device.

Microbial communities in bulk fluids and biofilms of an oil facility have similar composition but different structure.

PubMed

Stevenson, Bradley S; Drilling, Heather S; Lawson, Paul A; Duncan, Kathleen E; Parisi, Victoria A; Suflita, Joseph M

2011-04-01

The oil-water-gas environments of oil production facilities harbour abundant and diverse microbial communities that can participate in deleterious processes such as biocorrosion. Several molecular methods, including pyrosequencing of 16S rRNA libraries, were used to characterize the microbial communities from an oil production facility on the Alaskan North Slope. The communities in produced water and a sample from a 'pig envelope' were compared in order to identify specific populations or communities associated with biocorrosion. The 'pigs' are used for physical mitigation of pipeline corrosion and fouling and the samples are enriched in surface-associated solids (i.e. paraffins, minerals and biofilm) and coincidentally, microorganisms (over 10(5) -fold). Throughout the oil production facility, bacteria were more abundant (10- to 150-fold) than archaea, with thermophilic members of the phyla Firmicutes (Thermoanaerobacter and Thermacetogenium) and Synergistes (Thermovirga) dominating the community. However, the structure (relative abundances of taxa) of the microbial community in the pig envelope was distinct due to the increased relative abundances of the genera Thermacetogenium and Thermovirga. The data presented here suggest that bulk fluid is representative of the biofilm communities associated with biocorrosion but that certain populations are more abundant in biofilms, which should be the focus of monitoring and mitigation strategies. © 2011 Society for Applied Microbiology and Blackwell Publishing Ltd.

33 CFR 154.120 - Facility examinations.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Facility examinations. 154.120...) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK General § 154.120 Facility examinations. (a) The facility operator shall allow the Coast Guard, at any time, to make any examination and shall...

40 CFR 63.11092 - What testing and monitoring requirements must I meet?

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 15 2013-07-01 2013-07-01 false What testing and monitoring... Distribution Bulk Terminals, Bulk Plants, and Pipeline Facilities Testing and Monitoring Requirements § 63.11092 What testing and monitoring requirements must I meet? (a) Each owner or operator of a bulk...

40 CFR 63.11092 - What testing and monitoring requirements must I meet?

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 15 2012-07-01 2012-07-01 false What testing and monitoring... Distribution Bulk Terminals, Bulk Plants, and Pipeline Facilities Testing and Monitoring Requirements § 63.11092 What testing and monitoring requirements must I meet? (a) Each owner or operator of a bulk...

40 CFR 63.11092 - What testing and monitoring requirements must I meet?

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 15 2014-07-01 2014-07-01 false What testing and monitoring... Distribution Bulk Terminals, Bulk Plants, and Pipeline Facilities Testing and Monitoring Requirements § 63.11092 What testing and monitoring requirements must I meet? (a) Each owner or operator of a bulk...

40 CFR 63.11092 - What testing and monitoring requirements must I meet?

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 14 2011-07-01 2011-07-01 false What testing and monitoring... Distribution Bulk Terminals, Bulk Plants, and Pipeline Facilities Testing and Monitoring Requirements § 63.11092 What testing and monitoring requirements must I meet? (a) Each owner or operator of a bulk...

Mass production of bulk artificial nacre with excellent mechanical properties.

PubMed

Gao, Huai-Ling; Chen, Si-Ming; Mao, Li-Bo; Song, Zhao-Qiang; Yao, Hong-Bin; Cölfen, Helmut; Luo, Xi-Sheng; Zhang, Fu; Pan, Zhao; Meng, Yu-Feng; Ni, Yong; Yu, Shu-Hong

2017-08-18

Various methods have been exploited to replicate nacre features into artificial structural materials with impressive structural and mechanical similarity. However, it is still very challenging to produce nacre-mimetics in three-dimensional bulk form, especially for further scale-up. Herein, we demonstrate that large-sized, three-dimensional bulk artificial nacre with comprehensive mimicry of the hierarchical structures and the toughening mechanisms of natural nacre can be facilely fabricated via a bottom-up assembly process based on laminating pre-fabricated two-dimensional nacre-mimetic films. By optimizing the hierarchical architecture from molecular level to macroscopic level, the mechanical performance of the artificial nacre is superior to that of natural nacre and many engineering materials. This bottom-up strategy has no size restriction or fundamental barrier for further scale-up, and can be easily extended to other material systems, opening an avenue for mass production of high-performance bulk nacre-mimetic structural materials in an efficient and cost-effective way for practical applications.Artificial materials that replicate the mechanical properties of nacre represent important structural materials, but are difficult to produce in bulk. Here, the authors exploit the bottom-up assembly of 2D nacre-mimetic films to fabricate 3D bulk artificial nacre with an optimized architecture and excellent mechanical properties.

TECHNICAL ASSESSMENT OF BULK VITRIFICATION PROCESS & PRODUCT FOR TANK WASTE TREATMENT AT THE DEPARTMENT OF ENERGY HANFORD SITE

DOE Office of Scientific and Technical Information (OSTI.GOV)

SCHAUS, P.S.

At the U.S. Department of Energy (DOE) Hanford Site, the Waste Treatment Plant (WTP) is being constructed to immobilize both high-level waste (IUW) for disposal in a national repository and low-activity waste (LAW) for onsite, near-surface disposal. The schedule-controlling step for the WTP Project is vitrification of the large volume of LAW, current capacity of the WTP (as planned) would require 50 years to treat the Hanford tank waste, if the entire LAW volume were to be processed through the WTP. To reduce the time and cost for treatment of Hanford Tank Waste, and as required by the Tank Wastemore » Remediation System Environmental Impact Statement Record of Decision and the Hanford Federal Facility Consent Agreement (Tn-Party Agreement), DOE plans to supplement the LAW treatment capacity of the WTP. Since 2002, DOE, in cooperation with the Environmental Protection Agency and State of Washington Department of Ecology has been evaluating technologies that could provide safe and effective supplemental treatment of LAW. Current efforts at Hanford are intended to provide additional information to aid a joint agency decision on which technology will be used to supplement the WTP. A Research, Development and Demonstration permit has been issued by the State of Washington to build and (for a limited time) operate a Demonstration Bulk Vitrification System (DBVS) facility to provide information for the decision on a supplemental treatment technology for up to 50% of the LAW. In the Bulk Vitrification (BV) process, LAW, soil, and glass-forming chemicals are mixed, dried, and placed in a refractory-lined box, Electric current, supplied through two graphite electrodes in the box, melts the waste feed, producing a durable glass waste-form. Although recent modifications to the process have resulted in significant improvements, there are continuing technical concerns.« less

Low Gravity venting of Refrigerant 11

NASA Technical Reports Server (NTRS)

Labus, T. L.; Aydelott, J. C.; Lacovic, R. F.

1972-01-01

An experimental investigation was conducted in a five-second zero gravity facility to examine the effects of venting initially saturated Refrigerant 11 from a cylindrical container (15-cm diameter) under reduced gravitational conditions. The system Bond numbers studied were 0 (weightlessness), 9 and 63; the liquid exhibited a nearly zero-degree contact angle on the container surface. During the venting process, both liquid-vapor interface and liquid bulk vaporization occurred. The temperature of the liquid in the immediate vicinity of the liquid-vapor interface was found to decrease during venting, while the liquid bulk temperature remained constant. Qualitative observations of the effects of system acceleration, vent rate, and vapor volume presented. Quantitative information concerning the ullage pressure decay during low gravity venting is also included.

40 CFR 63.11081 - Am I subject to the requirements in this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

... Distribution Bulk Terminals, Bulk Plants, and Pipeline Facilities What This Subpart Covers § 63.11081 Am I... gasoline plant identified in paragraphs (a)(1) through (4) of this section. You are subject to the... station. (4) A bulk gasoline plant. (b) If you are an owner or operator of affected sources, as defined in...

High saturation magnetization of γ-Fe2O3 nano-particles by a facile one-step synthesis approach

PubMed Central

Cao, Derang; Li, Hao; Pan, Lining; Li, Jianan; Wang, Xicheng; Jing, Panpan; Cheng, Xiaohong; Wang, Wenjie; Wang, Jianbo; Liu, Qingfang

2016-01-01

We have demonstrated the synthesis of γ-Fe2O3 nano-particles through a facile and novel calcination process in the air. There is no pH regulation, gas atmosphere, additive, centrifugation or other complicated procedures during the preparing process. A detailed formation process of the nano-particles is proposed, and DMF as a polar solvent may slower the reaction process of calcination. The structures, morphologies, and magnetic properties of γ-Fe2O3 nano-particles were investigated systematically, and the pure γ-Fe2O3 nano-particles obtained at 200 °C display uniform morphology good magnetic property. The saturation magnetization of obtained pure γ-Fe2O3 is about 74 emu/g, which is comparable with bulk material (76 emu/g) and larger than other results. In addition, the photocatalytic activity for degradation of methylene blue is also studied, which shows proper photocatalytic activity. PMID:27581732

DEVELOPMENT OF A TAMPER RESISTANT/INDICATING AEROSOL COLLECTION SYSTEM FOR ENVIRONMENTAL SAMPLING AT BULK HANDLING FACILITIES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sexton, L.

2012-06-06

Environmental sampling has become a key component of International Atomic Energy Agency (IAEA) safeguards approaches since its approval for use in 1996. Environmental sampling supports the IAEA's mission of drawing conclusions concerning the absence of undeclared nuclear material or nuclear activities in a Nation State. Swipe sampling is the most commonly used method for the collection of environmental samples from bulk handling facilities. However, augmenting swipe samples with an air monitoring system, which could continuously draw samples from the environment of bulk handling facilities, could improve the possibility of the detection of undeclared activities. Continuous sampling offers the opportunity tomore » collect airborne materials before they settle onto surfaces which can be decontaminated, taken into existing duct work, filtered by plant ventilation, or escape via alternate pathways (i.e. drains, doors). Researchers at the Savannah River National Laboratory and Oak Ridge National Laboratory have been working to further develop an aerosol collection technology that could be installed at IAEA safeguarded bulk handling facilities. The addition of this technology may reduce the number of IAEA inspector visits required to effectively collect samples. The principal sample collection device is a patented Aerosol Contaminant Extractor (ACE) which utilizes electrostatic precipitation principles to deposit particulates onto selected substrates. Recent work has focused on comparing traditional swipe sampling to samples collected via an ACE system, and incorporating tamper resistant and tamper indicating (TRI) technologies into the ACE system. Development of a TRI-ACE system would allow collection of samples at uranium/plutonium bulk handling facilities in a manner that ensures sample integrity and could be an important addition to the international nuclear safeguards inspector's toolkit. This work was supported by the Next Generation Safeguards Initiative (NGSI), Office of Nonproliferation and International Security (NIS), National Nuclear Security Administration (NNSA).« less

33 CFR 154.1240 - Specific requirements for animal fats and vegetable oils facilities that could reasonably be...

Code of Federal Regulations, 2011 CFR

2011-07-01

... fats and vegetable oils facilities that could reasonably be expected to cause substantial harm to the... SECURITY (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for Animal Fats and Vegetable Oils Facilities § 154.1240 Specific requirements for animal fats and vegetable...

Occurrence of heterotrophic and coliform bacteria in liquid hand soaps from bulk refillable dispensers in public facilities.

PubMed

Chattman, Marisa; Gerba, Sheri L; Maxwell, Charles P

2011-03-01

The goal of the study discussed in this article was to determine the occurrence of heterotrophic and coliform bacteria in liquid soap from bulk refillable dispensers, obtained from restrooms in a variety of public facilities. A total of 541 samples was collected from five U.S. cities. Liquid soap from dispensers in public areas was found to contain heterotrophic and coliform bacterial numbers averaging more than 106 CFU/mL in 24.8% of the dispensers.

Holographic data storage crystals for the LDEF. [long duration exposure facility

NASA Technical Reports Server (NTRS)

Callen, W. Russell; Gaylord, Thomas K.

1992-01-01

Lithium niobate is a significant electro-optic material, with potential applications in ultra high capacity storage and processing systems. Lithium niobate is the material of choice for many integrated optical devices and holographic mass memory systems. For crystals of lithium niobate were passively exposed to the space environment of the Long Duration Exposure Facility (LDEF). Three of these crystals contained volume holograms. Although the crystals suffered the surface damage characteristics of most of the other optical components on the Georgia Tech tray, the crystals were recovered intact. The holograms were severely degraded because of the lengthy exposure, but the bulk properties are being investigated to determine the spaceworthiness for space data storage and retrieval systems.

33 CFR 154.1220 - Response plan submission requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... SECURITY (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for Animal Fats and Vegetable Oils Facilities § 154.1220 Response plan submission requirements. (a) The owner...

33 CFR 154.1220 - Response plan submission requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... SECURITY (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for Animal Fats and Vegetable Oils Facilities § 154.1220 Response plan submission requirements. (a) The owner...

Superconducting NbTiN thin films for superconducting radio frequency accelerator cavity applications

DOE PAGES

Burton, Matthew C.; Beebe, Melissa R.; Yang, Kaida; ...

2016-02-12

Current superconducting radio frequency technology, used in various particle accelerator facilities across the world, is reliant upon bulk niobium superconducting cavities. Due to technological advancements in the processing of bulk Nb cavities, the facilities have reached accelerating fields very close to a material-dependent limit, which is close to 50 MV/m for bulk Nb. One possible solution to improve upon this fundamental limitation was proposed a few years ago by Gurevich [Appl. Phys. Lett. 88, 012511 (2006)], consisting of the deposition of alternating thin layers of superconducting and insulating materials on the interior surface of the cavities. The use of type-IImore » superconductors with Tc > Tc Nb and H c > HcNb, (e.g., Nb 3Sn, NbN, or NbTiN) could potentially greatly reduce the surface resistance (Rs) and enhance the accelerating field, if the onset of vortex penetration is increased above Hc Nb, thus enabling higher field gradients. Although Nb 3Sn may prove superior, it is not clear that it can be grown as a suitable thin film for the proposed multilayer approach, since very high temperature is typically required for its growth, hindering achieving smooth interfaces and/or surfaces. On the other hand, since NbTiN has a smaller lower critical field (H c1) and higher critical temperature (T c) than Nb and increased conductivity compared to NbN, it is a promising candidate material for this new scheme. Here, the authors present experimental results correlating filmmicrostructure with superconducting properties on NbTiN thin film coupon samples while also comparing filmsgrown with targets of different stoichiometry. In conclusion, it is worth mentioning that the authors have achieved thin films with bulk-like lattice parameter and transition temperature while also achieving H c1 values larger than bulk for films thinner than their London penetration depths.« less

33 CFR 154.1325 - Response plan development and evaluation criteria for facilities that handle, store, or transport...

Code of Federal Regulations, 2011 CFR

2011-07-01

... evaluation criteria for facilities that handle, store, or transport other non-petroleum oils. 154.1325...) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for Other Non-Petroleum..., store, or transport other non-petroleum oils. (a) An owner or operator of a facility that handles...

33 CFR 154.1325 - Response plan development and evaluation criteria for facilities that handle, store, or transport...

Code of Federal Regulations, 2010 CFR

2010-07-01

... evaluation criteria for facilities that handle, store, or transport other non-petroleum oils. 154.1325...) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for Other Non-Petroleum..., store, or transport other non-petroleum oils. (a) An owner or operator of a facility that handles...

33 CFR 154.1045 - Response plan development and evaluation criteria for facilities that handle, store, or transport...

Code of Federal Regulations, 2013 CFR

2013-07-01

... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Response plan development and... (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for Oil Facilities § 154.1045 Response plan development and evaluation criteria for facilities that handle, store, or...

33 CFR 154.1045 - Response plan development and evaluation criteria for facilities that handle, store, or transport...

Code of Federal Regulations, 2011 CFR

2011-07-01

... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Response plan development and... (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for Oil Facilities § 154.1045 Response plan development and evaluation criteria for facilities that handle, store, or...

33 CFR 154.1045 - Response plan development and evaluation criteria for facilities that handle, store, or transport...

Code of Federal Regulations, 2012 CFR

2012-07-01

... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Response plan development and... (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for Oil Facilities § 154.1045 Response plan development and evaluation criteria for facilities that handle, store, or...

33 CFR 154.1045 - Response plan development and evaluation criteria for facilities that handle, store, or transport...

Code of Federal Regulations, 2014 CFR

2014-07-01

... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Response plan development and... (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for Oil Facilities § 154.1045 Response plan development and evaluation criteria for facilities that handle, store, or...

33 CFR 154.1210 - Purpose and applicability.

Code of Federal Regulations, 2012 CFR

2012-07-01

... Fats and Vegetable Oils Facilities § 154.1210 Purpose and applicability. (a) The requirements of this... fats or vegetable oils including— (1) A fixed MTR facility capable of transferring oil in bulk, to or...

33 CFR 154.1210 - Purpose and applicability.

Code of Federal Regulations, 2013 CFR

2013-07-01

... Fats and Vegetable Oils Facilities § 154.1210 Purpose and applicability. (a) The requirements of this... fats or vegetable oils including— (1) A fixed MTR facility capable of transferring oil in bulk, to or...

33 CFR 154.1210 - Purpose and applicability.

Code of Federal Regulations, 2014 CFR

2014-07-01

... Fats and Vegetable Oils Facilities § 154.1210 Purpose and applicability. (a) The requirements of this... fats or vegetable oils including— (1) A fixed MTR facility capable of transferring oil in bulk, to or...

Perspective: Aerosol microphysics: From molecules to the chemical physics of aerosols

NASA Astrophysics Data System (ADS)

Bzdek, Bryan R.; Reid, Jonathan P.

2017-12-01

Aerosols are found in a wide diversity of contexts and applications, including the atmosphere, pharmaceutics, and industry. Aerosols are dispersions of particles in a gas, and the coupling of the two phases results in highly dynamic systems where chemical and physical properties like size, composition, phase, and refractive index change rapidly in response to environmental perturbations. Aerosol particles span a wide range of sizes from 1 nm to tens of micrometres or from small molecular clusters that may more closely resemble gas phase molecules to large particles that can have similar qualities to bulk materials. However, even large particles with finite volumes exhibit distinct properties from the bulk condensed phase, due in part to their higher surface-to-volume ratio and their ability to easily access supersaturated solute states inaccessible in the bulk. Aerosols represent a major challenge for study because of the facile coupling between the particle and gas, the small amounts of sample available for analysis, and the sheer breadth of operative processes. Time scales of aerosol processes can be as short as nanoseconds or as long as years. Despite their very different impacts and applications, fundamental chemical physics processes serve as a common theme that underpins our understanding of aerosols. This perspective article discusses challenges in the study of aerosols and highlights recent chemical physics advancements that have enabled improved understanding of these complex systems.

46 CFR 153.975 - Preparation for cargo transfer.

Code of Federal Regulations, 2013 CFR

2013-10-01

... Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SHIPS CARRYING BULK LIQUID, LIQUEFIED GAS, OR COMPRESSED GAS HAZARDOUS MATERIALS Operations Cargo Transfer... facility is made before the cargo transfer piping is joined. (c) Any supplemental inert gas supply...

46 CFR 153.975 - Preparation for cargo transfer.

Code of Federal Regulations, 2011 CFR

2011-10-01

... Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SHIPS CARRYING BULK LIQUID, LIQUEFIED GAS, OR COMPRESSED GAS HAZARDOUS MATERIALS Operations Cargo Transfer... facility is made before the cargo transfer piping is joined. (c) Any supplemental inert gas supply...

46 CFR 153.975 - Preparation for cargo transfer.

Code of Federal Regulations, 2012 CFR

2012-10-01

... Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SHIPS CARRYING BULK LIQUID, LIQUEFIED GAS, OR COMPRESSED GAS HAZARDOUS MATERIALS Operations Cargo Transfer... facility is made before the cargo transfer piping is joined. (c) Any supplemental inert gas supply...

46 CFR 153.975 - Preparation for cargo transfer.

Code of Federal Regulations, 2014 CFR

2014-10-01

... Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SHIPS CARRYING BULK LIQUID, LIQUEFIED GAS, OR COMPRESSED GAS HAZARDOUS MATERIALS Operations Cargo Transfer... facility is made before the cargo transfer piping is joined. (c) Any supplemental inert gas supply...

Characterization of airborne and bulk particulate from iron and steel manufacturing facilities.

PubMed

Machemer, Steven D

2004-01-15

Characterization of airborne and bulk particulate material from iron and steel manufacturing facilities, commonly referred to as kish, indicated graphite flakes and graphite flakes associated with spherical iron oxide particles were unique particle characteristics useful in identifying particle emissions from iron and steel manufacturing. Characterization of airborne particulate material collected in receptor areas was consistent with multiple atmospheric release events of kish particles from the local iron and steel facilities into neighboring residential areas. Kish particles deposited in nearby residential areas included an abundance of graphite flakes, tens of micrometers to millimeters in size, and spherical iron oxide particles, submicrometer to tens of micrometers in size. Bulk kish from local iron and steel facilities contained an abundance of similar particles. Approximately 60% of blast furnace kish by volume consisted of spherical iron oxide particles in the respirable size range. Basic oxygen furnace kish contained percent levels of strongly alkaline components such as calcium hydroxide. In addition, concentrations of respirable Mn in airborne particulate in residential areas and at local iron and steel facilities were approximately 1.6 and 53 times the inhalation reference concentration of 0.05 microg/m3 for chronic inhalation exposure of Mn, respectively. Thus, airborne release of kish may pose potential respirable particulate, corrosive, or toxic hazards for human health and/or a corrosive hazard for property and the environment.

A taxonomy of chemicals of emerging concern based on observed fate at water resource recovery facilities.

PubMed

Jones, Steven M; Chowdhury, Zaid K; Watts, Michael J

2017-03-01

As reuse of municipal water resource recovery facility (WRRF) effluent becomes vital to augment diminishing fresh drinking water resources, concern exists that conventional barriers may prove deficient, and the upcycling of chemicals of emerging concern (CECs) could prove harmful to human health and aquatic species if more effective and robust treatment barriers are not in place. A multiple month survey, of both primary and secondary effluents, from three (3) WRRFs, for 95 CECs was conducted in 2014 to classify CECs by their persistence through conventional water reclamation processes. By sampling the participating WRRF process trains at their peak performance (as determined by measured bulk organics and particulates removal), a short-list of recalcitrant CECs that warrant monitoring to assess treatment performance at advanced water reclamation and production facilities. The list of identified CECs for potable water reclamation (indirect or direct potable reuse) include a herbicide and its degradants, prescription pharmaceuticals and antibiotics, a female hormone, an artificial sweetener, and chlorinated flame retardants. Copyright © 2016 Elsevier Ltd. All rights reserved.

40 CFR 63.11085 - What are my general duties to minimize emissions?

Code of Federal Regulations, 2011 CFR

2011-07-01

... Distribution Bulk Terminals, Bulk Plants, and Pipeline Facilities Emission Limitations and Management Practices... control practices for minimizing emissions. Determination of whether such operation and maintenance... operation and maintenance records, and inspection of the source. (b) You must keep applicable records and...

40 CFR 63.11085 - What are my general duties to minimize emissions?

Code of Federal Regulations, 2012 CFR

2012-07-01

... Distribution Bulk Terminals, Bulk Plants, and Pipeline Facilities Emission Limitations and Management Practices... control practices for minimizing emissions. Determination of whether such operation and maintenance... operation and maintenance records, and inspection of the source. (b) You must keep applicable records and...

40 CFR 63.11085 - What are my general duties to minimize emissions?

Code of Federal Regulations, 2014 CFR

2014-07-01

... Distribution Bulk Terminals, Bulk Plants, and Pipeline Facilities Emission Limitations and Management Practices... control practices for minimizing emissions. Determination of whether such operation and maintenance... operation and maintenance records, and inspection of the source. (b) You must keep applicable records and...

75 FR 72909 - Revision to Electric Reliability Organization Definition of Bulk Electric System

Federal Register 2010, 2011, 2012, 2013, 2014

2010-11-26

...) Comments 135 (b) Commission Determination 139 6. Impact on Generation Owners and Operators 142 (a) Comments... Organization, the electrical generation resources, transmission lines, interconnections with neighboring... above that interconnect with registered generation facilities are excluded from NPCC's list of bulk...

Quantum junction solar cells.

PubMed

Tang, Jiang; Liu, Huan; Zhitomirsky, David; Hoogland, Sjoerd; Wang, Xihua; Furukawa, Melissa; Levina, Larissa; Sargent, Edward H

2012-09-12

Colloidal quantum dot solids combine convenient solution-processing with quantum size effect tuning, offering avenues to high-efficiency multijunction cells based on a single materials synthesis and processing platform. The highest-performing colloidal quantum dot rectifying devices reported to date have relied on a junction between a quantum-tuned absorber and a bulk material (e.g., TiO(2)); however, quantum tuning of the absorber then requires complete redesign of the bulk acceptor, compromising the benefits of facile quantum tuning. Here we report rectifying junctions constructed entirely using inherently band-aligned quantum-tuned materials. Realizing these quantum junction diodes relied upon the creation of an n-type quantum dot solid having a clean bandgap. We combine stable, chemically compatible, high-performance n-type and p-type materials to create the first quantum junction solar cells. We present a family of photovoltaic devices having widely tuned bandgaps of 0.6-1.6 eV that excel where conventional quantum-to-bulk devices fail to perform. Devices having optimal single-junction bandgaps exhibit certified AM1.5 solar power conversion efficiencies of 5.4%. Control over doping in quantum solids, and the successful integration of these materials to form stable quantum junctions, offers a powerful new degree of freedom to colloidal quantum dot optoelectronics.

Physical properties of five grain dust types.

PubMed Central

Parnell, C B; Jones, D D; Rutherford, R D; Goforth, K J

1986-01-01

Physical properties of grain dust derived from five grain types (soybean, rice, corn, wheat, and sorghum) were measured and reported. The grain dusts were obtained from dust collection systems of terminal grain handling facilities and were assumed to be representative of grain dust generated during the handling process. The physical properties reported were as follows: particle size distributions and surface area measurements using a Coulter Counter Model TAII; percent dust fractions less than 100 micron of whole dust; bulk density; particle density; and ash content. PMID:3709482

33 CFR 154.740 - Records.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Records. 154.740 Section 154.740... TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Facility Operations § 154.740 Records. Each facility operator... (e) and (g) except that marked on the hose; (e) The record of all examinations of the facility by the...

33 CFR 154.740 - Records.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Records. 154.740 Section 154.740... TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Facility Operations § 154.740 Records. Each facility operator... (e) and (g) except that marked on the hose; (e) The record of all examinations of the facility by the...

33 CFR 154.740 - Records.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Records. 154.740 Section 154.740... TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Facility Operations § 154.740 Records. Each facility operator... (e) and (g) except that marked on the hose; (e) The record of all examinations of the facility by the...

33 CFR 154.740 - Records.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Records. 154.740 Section 154.740... TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Facility Operations § 154.740 Records. Each facility operator... (e) and (g) except that marked on the hose; (e) The record of all examinations of the facility by the...

33 CFR 154.740 - Records.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Records. 154.740 Section 154.740... TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Facility Operations § 154.740 Records. Each facility operator... (e) and (g) except that marked on the hose; (e) The record of all examinations of the facility by the...

33 CFR 154.2103 - Facility requirements for vessel vapor overpressure and vacuum protection.

Code of Federal Regulations, 2014 CFR

2014-07-01

... HAZARDOUS MATERIAL IN BULK Marine Vapor Control Systems Transfer Facilities-Vcs Design and Installation... rate, unless there is experimental data for actual vapor growth for turbulent transferring under the... vapor growth. (b) A facility VCS must be designed to prevent the pressure in a vessel's cargo tanks from...

Processing lunar soils for oxygen and other materials

NASA Technical Reports Server (NTRS)

Knudsen, Christian W.; Gibson, Michael A.

1992-01-01

Two types of lunar materials are excellent candidates for lunar oxygen production: ilmenite and silicates such as anorthite. Both are lunar surface minable, occurring in soils, breccias, and basalts. Because silicates are considerably more abundant than ilmenite, they may be preferred as source materials. Depending on the processing method chosen for oxygen production and the feedstock material, various useful metals and bulk materials can be produced as byproducts. Available processing techniques include hydrogen reduction of ilmenite and electrochemical and chemical reductions of silicates. Processes in these categories are generally in preliminary development stages and need significant research and development support to carry them to practical deployment, particularly as a lunar-based operation. The goal of beginning lunar processing operations by 2010 requires that planning and research and development emphasize the simplest processing schemes. However, more complex schemes that now appear to present difficult technical challenges may offer more valuable metal byproducts later. While they require more time and effort to perfect, the more complex or difficult schemes may provide important processing and product improvements with which to extend and elaborate the initial lunar processing facilities. A balanced R&D program should take this into account. The following topics are discussed: (1) ilmenite--semi-continuous process; (2) ilmenite--continuous fluid-bed reduction; (3) utilization of spent ilmenite to produce bulk materials; (4) silicates--electrochemical reduction; and (5) silicates--chemical reduction.

Non-destructive automated sampling of mycotoxins in bulk food and feed - A new tool for required harmonization.

PubMed

Spanjer, M; Stroka, J; Patel, S; Buechler, S; Pittet, A; Barel, S

2001-06-01

Mycotoxins contamination is highly non-uniformly distributed as is well recog-nized by the EC, by not only setting legal limits in a series of commodities, but also schedule a sampling plan that takes this heterogeneity into account. In practice however, it turns out that it is very difficult to carry out this sampling plan in a harmonised way. Applying the sampling plan to a container filled with pallets of bags (i.e. with nuts or coffee beans) varies from very laborious to almost impossible. The presented non-destructive automated method to sample bulk food could help to overcome these practical problems and to enforcing of EC directives. It is derived from a tested and approved technology for detection of illicit substances in security applications. It has capability to collect and iden-tify ultra trace contaminants, i.e. from a fingerprint of chemical substance in a bulk of goods, a cargo pallet load (~ 1000 kg) with boxes and commodities.The technology, patented for explosives detection, uses physical and chemistry processes for excitation and remote rapid enhanced release of contaminant residues, vapours and particulate, of the inner/outer surfaces of inspected bulk and collect them on selective probes. The process is automated, takes only 10 minutes, is non-destructive and the bulk itself remains unharmed. The system design is based on applicable international regulations for shipped cargo hand-ling and transportation by road, sea and air. After this process the pallet can be loaded on a truck, ship or plane. Analysis can be carried out before the cargo leaves the place of shipping. The potent application of this technology for myco-toxins detection, has been demonstrated by preliminary feasibility experiments. Aflatoxins were detected in pistachios and ochratoxin A in green coffee beans bulk. Both commodities were naturally contaminated, priory found and confirm-ed by common methods as used at routine inspections. Once the contaminants are extracted from a bulk shipment, an appropriate existing analytical method, i.e. a CEN method, can be used to measure the mycotoxins.The system, routinely in use for explosives detection, was able to screen bulk food and feed for mycotoxins, through non-destructive automated sampling of a whole batch/lot/sublot of commodities. The opportunity to sample a whole bulk would provide more effective tools for inspection at seaports, production facili-ties and distri-bution points. It will advance the current process of myco-toxins check because: (i) Checks will be automated and harmonized, (ii) Checks will be non-destructive, (iii) Checks will be faster and allow a greater amount of bulk commodities to be inspected and (iv) The ability to check, with automated equipment, larger portions of lots of a shipment will increase the probability to detect the heterogeneous mycotoxins contamination in bulk foods. The poster provides some results of feasibility experiments indicating the capability of this technology for inspection of commodities bulks for the detection of mycotoxins, at legal limits, in naturally contaminated food.

33 CFR 126.27 - General permit for handling dangerous cargo.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) in bulk, portable tanks, containers, or packagings, at designated waterfront facilities, conditioned... bulk packaging; or Division 2.3 (Poison Gas) materials in excess of 72,800 kg (80 net tons) at any one... cargo in limited-quantity packaging. (e) Transport units and portable tanks containing dangerous cargo...

40 CFR 63.11092 - What testing and monitoring requirements must I meet?

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 14 2010-07-01 2010-07-01 false What testing and monitoring... Distribution Bulk Terminals, Bulk Plants, and Pipeline Facilities Testing and Monitoring Requirements § 63.11092 What testing and monitoring requirements must I meet? (a) Each owner or operator subject to the...

40 CFR 112.12 - Spill Prevention, Control, and Countermeasure Plan requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... equipment failure or human error at the facility. (c) Bulk storage containers. (1) Not use a container for... means of containment for the entire capacity of the largest single container and sufficient freeboard to... soil conditions. (6) Bulk storage container inspections. (i) Except for containers that meet the...

40 CFR 112.12 - Spill Prevention, Control, and Countermeasure Plan requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... equipment failure or human error at the facility. (c) Bulk storage containers. (1) Not use a container for... means of containment for the entire capacity of the largest single container and sufficient freeboard to... soil conditions. (6) Bulk storage container inspections. (i) Except for containers that meet the...

40 CFR 112.12 - Spill Prevention, Control, and Countermeasure Plan requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... equipment failure or human error at the facility. (c) Bulk storage containers. (1) Not use a container for... means of containment for the entire capacity of the largest single container and sufficient freeboard to... soil conditions. (6) Bulk storage container inspections. (i) Except for containers that meet the...

33 CFR 154.730 - Persons in charge: Evidence of designation.

Code of Federal Regulations, 2011 CFR

2011-07-01

... evidence is immediately available at the facility. (Sec. 311(j)(1)(C) of the Federal Water Pollution Control Act (86 Stat. 816, 868); 33 U.S.C. 1161(j)(1)(C); EO 11548, 3 CFR, 1966-1970 Comp., p. 949; 49 CFR... SECURITY (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Facility...

33 CFR 154.730 - Persons in charge: Evidence of designation.

Code of Federal Regulations, 2010 CFR

2010-07-01

... evidence is immediately available at the facility. (Sec. 311(j)(1)(C) of the Federal Water Pollution Control Act (86 Stat. 816, 868); 33 U.S.C. 1161(j)(1)(C); EO 11548, 3 CFR, 1966-1970 Comp., p. 949; 49 CFR... SECURITY (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Facility...

33 CFR 157.304 - Shore-based reception facility: standards.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Shore-based reception facility: standards. 157.304 Section 157.304 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND... CARRYING OIL IN BULK Exemption From § 157.10a or § 157.10c § 157.304 Shore-based reception facility...

33 CFR 157.304 - Shore-based reception facility: standards.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Shore-based reception facility: standards. 157.304 Section 157.304 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND... CARRYING OIL IN BULK Exemption From § 157.10a or § 157.10c § 157.304 Shore-based reception facility...

Models of Mass Transport During Microgravity Crystal Growth of Alloyed Semiconductors in a Magnetic Field

NASA Technical Reports Server (NTRS)

Ma, Nancy

2003-01-01

Alloyed semiconductor crystals, such as germanium-silicon (GeSi) and various II-VI alloyed crystals, are extremely important for optoelectronic devices. Currently, high-quality crystals of GeSi and of II-VI alloys can be grown by epitaxial processes, but the time required to grow a certain amount of single crystal is roughly 1,000 times longer than the time required for Bridgman growth from a melt. Recent rapid advances in optoelectronics have led to a great demand for more and larger crystals with fewer dislocations and other microdefects and with more uniform and controllable compositions. Currently, alloyed crystals grown by bulk methods have unacceptable levels of segregation in the composition of the crystal. Alloyed crystals are being grown by the Bridgman process in space in order to develop successful bulk-growth methods, with the hope that the technology will be equally successful on earth. Unfortunately some crystals grown in space still have unacceptable segregation, for example, due to residual accelerations. The application of a weak magnetic field during crystal growth in space may eliminate the undesirable segregation. Understanding and improving the bulk growth of alloyed semiconductors in microgravity is critically important. The purpose of this grant to to develop models of the unsteady species transport during the bulk growth of alloyed semiconductor crystals in the presence of a magnetic field in microgravity. The research supports experiments being conducted in the High Magnetic Field Solidification Facility at Marshall Space Flight Center (MSFC) and future experiments on the International Space Station.

19 CFR 11.6 - Distilled spirits, wines, and malt liquors in bulk.

Code of Federal Regulations, 2010 CFR

2010-04-01

..., and malt liquors in bulk. (a) The port director, in his discretion, may require marks, brands, stamps..., brands, stamps, labels, or similar devices required by Federal, State, or local statute or regulation may... measurement shall be done at a public store, warehouse, or other appropriate facility. (c) Marks, brands...

49 CFR 172.301 - General marking requirements for non-bulk packagings.

Code of Federal Regulations, 2012 CFR

2012-10-01

... container load, and the entire contents of the rail car, truck or freight container are shipped from one... quantities of a single hazardous material in non-bulk packages. A transport vehicle or freight container... loaded at one loading facility; (iv) The transport vehicle or freight container contains no other...

49 CFR 172.301 - General marking requirements for non-bulk packagings.

Code of Federal Regulations, 2011 CFR

2011-10-01

... container load, and the entire contents of the rail car, truck or freight container are shipped from one... quantities of a single hazardous material in non-bulk packages. A transport vehicle or freight container... loaded at one loading facility; (iv) The transport vehicle or freight container contains no other...

49 CFR 172.301 - General marking requirements for non-bulk packagings.

Code of Federal Regulations, 2010 CFR

2010-10-01

... container load, and the entire contents of the rail car, truck or freight container are shipped from one... or freight container containing only a single hazardous material in non-bulk packages must be marked... hazardous material is loaded at one loading facility; (iv) The transport vehicle or freight container...

Radiological considerations for bulk shielding calculations of national synchrotron light source-II

NASA Astrophysics Data System (ADS)

Job, Panakkal K.; Casey, William R.

2011-12-01

Brookhaven National Laboratory is designing a new electron synchrotron for scientific research using synchrotron radiation. This facility, called the “National Synchrotron Light Source II” (NSLS-II), will provide x-ray radiation of ultra-high brightness and exceptional spatial and energy resolution. It will also provide advanced insertion devices, optics, detectors and robotics, and a suite of scientific instruments designed to maximize the scientific output of the facility. The project scope includes the design, construction, installation, and commissioning of the following accelerators: a 200 MeV linac, a booster synchrotron operating from 200 MeV to 3.0 GeV, and the storage ring which stores a maximum of 500 mA current of electrons at an energy of 3.0 GeV. It is planned to operate the facility primarily in a top-off mode, thereby maintaining the maximum variation in stored beam current to <1%. Because of the very demanding requirements for beam emittance and synchrotron radiation brilliance, the beam life-time is expected to be quite low, on the order of 2 h. Analysis of the bulk shielding for operating this facility and the input parameters used for this analysis have been discussed in this paper. The characteristics of each of the accelerators and their operating modes have been summarized with the input assumptions for the bulk shielding analysis.

Gasoline Distribution Facilities (Bulk Gasoline Terminals and Pipeline Breakout Stations) Air Toxics Rule Fact Sheets

EPA Pesticide Factsheets

This page contains a November 1994 fact sheet for the final NESHAP for Gasoline Distribution Facilities. This page also contains a December fact sheet with information regarding the final amendments to the 2003 final rule for the NESHAP.

ZrCuAl Bulk Metallic Glass spall induced by laser shock

NASA Astrophysics Data System (ADS)

Jodar, Benjamin; Loison, Didier; Yokoyama, Yoshihiko; Lescoute, Emilien; Berthe, Laurent; Sangleboeuf, Jean-Christophe

2017-06-01

To face High Velocity Impacts, the aerospace industry is always seeking for innovative materials usable as debris shielding components. Bulk Metallic Glasses (BMG) revealed interesting mechanical properties in case of static and quasi-static loading conditions: high elasticity, high tenacity, low density and high fracture threshold... The department of Mechanics and Glass of the Institut of Physics Rennes conducted on the ELFIE facility, laser shock experiments to study the behavior of a ternary ZrCuAl BMG under high strain rate, up-to fragmentation process. On the one hand, in-situ diagnostics were used to measure ejection velocities with PDV and debris morphologies were observed by Shadowgraphy. On the other hand, spalled areas (dimensions and features) were characterized through post-mortem analysis (optical observations, profilometry and SEM). These results are compared to experimental and numerical data on the crystalline forms of the ZrCuAl basic compounds.

Bulk Preparation of Holey Graphene via Controlled Catalytic Oxidation

NASA Technical Reports Server (NTRS)

Connell, John (Inventor); Watson, Kent (Inventor); Ghose, Sayata (Inventor); Lin, Yi (Inventor)

2015-01-01

A scalable method allows preparation of bulk quantities of holey carbon allotropes with holes ranging from a few to over 100 nm in diameter. Carbon oxidation catalyst nanoparticles are first deposited onto a carbon allotrope surface in a facile, controllable, and solvent-free process. The catalyst-loaded carbons are then subjected to thermal treatment in air. The carbons in contact with the carbon oxidation catalyst nanoparticles are selectively oxidized into gaseous byproducts such as CO or CO.sub.2, leaving the surface with holes. The catalyst is then removed via refluxing in diluted nitric acid to obtain the final holey carbon allotropes. The average size of the holes correlates strongly with the size of the catalyst nanoparticles and is controlled by adjusting the catalyst precursor concentration. The temperature and time of the air oxidation step, and the catalyst removal treatment conditions, strongly affect the morphology of the holes.

A Facile in Situ and UV Printing Process for Bioinspired Self-Cleaning Surfaces

PubMed Central

González Lazo, Marina A.; Katrantzis, Ioannis; Dalle Vacche, Sara; Karasu, Feyza; Leterrier, Yves

2016-01-01

A facile in situ and UV printing process was demonstrated to create self-cleaning synthetic replica of natural petals and leaves. The process relied on the spontaneous migration of a fluorinated acrylate surfactant (PFUA) within a low-shrinkage acrylated hyperbranched polymer (HBP) and its chemical immobilization at the polymer-air interface. Dilute concentrations of 1 wt. % PFUA saturated the polymer-air interface within 30 min, leading to a ten-fold increase of fluorine concentration at the surface compared with the initial bulk concentration and a water contact angle (WCA) of 108°. A 200 ms flash of UV light was used to chemically crosslink the PFUA at the HBP surface prior to UV printing with a polydimethylsiloxane (PDMS) negative template of red and yellow rose petals and lotus leaves. This flash immobilization hindered the reverse migration of PFUA within the bulk HBP upon contacting the PDMS template, and enabled to produce texturized surfaces with WCA well above 108°. The synthetic red rose petal was hydrophobic (WCA of 125°) and exhibited the adhesive petal effect. It was not superhydrophobic due to insufficient concentration of fluorine at its surface, a result of the very large increase of the surface of the printed texture. The synthetic yellow rose petal was quasi-superhydrophobic (WCA of 143°, roll-off angle of 10°) and its self-cleaning ability was not good also due to lack of fluorine. The synthetic lotus leaf did not accurately replicate the intricate nanotubular crystal structures of the plant. In spite of this, the fluorine concentration at the surface was high enough and the leaf was superhydrophobic (WCA of 151°, roll-off angle below 5°) and also featured self-cleaning properties. PMID:28773860

The detection of formaldehyde using microelectromechanical acoustic resonator with multiwalled carbon nanotubes-polyethyleneimine composite coating

NASA Astrophysics Data System (ADS)

Wang, Jingjing; Zhan, Da; Wang, Ke; Hang, Weiwei

2018-01-01

A micro-scale gas sensor based on mass-sensitive film bulk acoustic resonator is demonstrated for the detection of trace formaldehyde at room temperature. The composites mixed with multiwalled carbon nanotubes and polyethyleneimine (MWNTs-PEI) were coated on the resonator surface as the sensitive layer to specifically absorb formaldehyde molecules using a facile spray process. The influence of spraying processes on the formaldehyde sensing properties were investigated. Different response behaviors were determined by both the chemical absorption between formaldehyde molecules and the amine functional groups on PEI and the increase of absorption surface came from the nanostructure. The combination of high frequency of the film bulk acoustic resonator (~4.3 GHz) and the specific absorbability of MWNTs-PEI composites provided a high sensitivity in the detections of trace formaldehyde. The obtained ultra-low limit of detection was as low as 60 ppb with linear response, quick response/recovery time, good reproducibility and selectivity. The proposed sensor shows potential as a portable and convenient gas-sensing system for monitoring the low-level concentration of indoor air pollution.

Scalable planar fabrication processes for chalcogenide-based topological insulators

NASA Astrophysics Data System (ADS)

Sharma, Peter; Henry, M. David; Douglas, Erica; Wiwi, Michael; Lima Sharma, Ana; Lewis, Rupert; Sugar, Joshua; Salehi, Maryam; Koirala, Nikesh; Oh, Seongshik

Surface currents in topological insulators are expected to have long spin diffusion lengths, which could lead to numerous applications. Experiments that show promising transport properties were conducted on exfoliated flakes from bulk material, thin films on substrates of limited dimensions, or bulk material, with limited yield. A planar thin film-based technology is needed to make topological insulator devices at scale and could also lead to new device designs. We address two problems related to fabricating chalcogenide-based topological insulator devices on 3'' wafers in the Sandia Microfabrication Facility using Bi2Te3 films. (2) Implantation damage and its subsequent mitigation through annealing is characterized. (2) The degradation in dielectric layers used to manipulate surface potential for elucidating topological surface state transport is characterized under different processing conditions. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under Contract No. DE-AC04-94AL85000. Funded by the Office of Naval Research (N0001416IP00098-0).

120. NORTH PLANT GB BULK STORAGE BUILDING AND AMMUNITION DEMOLITION ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

120. NORTH PLANT GB BULK STORAGE BUILDING AND AMMUNITION DEMOLITION FACILITY AT CENTER AND CASE FILLING PLANT/CLUSTER ASSEMBLY BUILDING (BUILDING 1601/1606) IN BACKGROUND, FROM GB MANUFACTURING PLANT. VIEW TO WEST. - Rocky Mountain Arsenal, Bounded by Ninety-sixth Avenue & Fifty-sixth Avenue, Buckley Road, Quebec Street & Colorado Highway 2, Commerce City, Adams County, CO

33 CFR 154.525 - Monitoring devices.

Code of Federal Regulations, 2013 CFR

2013-07-01

... monitoring devices at the facility would significantly limit the size of a discharge of oil or hazardous... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Monitoring devices. 154.525...) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Equipment Requirements § 154.525...

33 CFR 154.525 - Monitoring devices.

Code of Federal Regulations, 2011 CFR

2011-07-01

... monitoring devices at the facility would significantly limit the size of a discharge of oil or hazardous... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Monitoring devices. 154.525...) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Equipment Requirements § 154.525...

33 CFR 154.525 - Monitoring devices.

Code of Federal Regulations, 2014 CFR

2014-07-01

... monitoring devices at the facility would significantly limit the size of a discharge of oil or hazardous... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Monitoring devices. 154.525...) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Equipment Requirements § 154.525...

33 CFR 154.525 - Monitoring devices.

Code of Federal Regulations, 2012 CFR

2012-07-01

... monitoring devices at the facility would significantly limit the size of a discharge of oil or hazardous... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Monitoring devices. 154.525...) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Equipment Requirements § 154.525...

33 CFR 154.107 - Alternatives.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Alternatives. 154.107 Section 154... FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK General § 154.107 Alternatives. (a) The COTP may consider and approve alternative procedures, methods, or equipment standards to be used by a facility...

Hazardous Waste Cleanup: Kinder Morgan Liquid Terminals, LLC in Staten Island, New York

EPA Pesticide Factsheets

Exxon Mobil Port Mobil Terminal is a petroleum bulk storage and distribution facility which began operations in 1934 and continues today. The facility is located on the eastern shoreline of the Arthur Kill, Staten Island, City of New York, and is bounded

46 CFR 525.1 - Purpose and scope.

Code of Federal Regulations, 2012 CFR

2012-10-01

..., warehouse or other terminal facilities in connection with a common carrier, or in connection with a common...; common carriers who perform port terminal services; and warehousemen who operate port terminal facilities... storage spaces, cold storage plants, cranes, grain elevators and/or bulk cargo loading and/or unloading...

33 CFR 154.310 - Operations manual: Contents.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Operations Manual § 154.310..., maps, drawings, aerial photographs or diagrams, showing the boundaries of the facility subject to Coast... or chemical name; and (ii) The following cargo information: (a) The name of the cargo as listed under...

33 CFR 154.310 - Operations manual: Contents.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Operations Manual § 154.310..., maps, drawings, aerial photographs or diagrams, showing the boundaries of the facility subject to Coast... or chemical name; and (ii) The following cargo information: (a) The name of the cargo as listed under...

33 CFR 154.310 - Operations manual: Contents.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Operations Manual § 154.310..., maps, drawings, aerial photographs or diagrams, showing the boundaries of the facility subject to Coast... or chemical name; and (ii) The following cargo information: (a) The name of the cargo as listed under...

33 CFR 154.310 - Operations manual: Contents.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Operations Manual § 154.310..., maps, drawings, aerial photographs or diagrams, showing the boundaries of the facility subject to Coast... or chemical name; and (ii) The following cargo information: (a) The name of the cargo as listed under...

40 CFR 60.433 - Performance test and compliance provisions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... facilities routinely share the same raw ink storage/handling system with existing facilities, then temporary measurement procedures for segregating the raw inks, related coatings, VOC solvent, and water used at the... the purpose of measuring bulk storage tank quantities of each color of raw ink and each related...

40 CFR 60.433 - Performance test and compliance provisions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... facilities routinely share the same raw ink storage/handling system with existing facilities, then temporary measurement procedures for segregating the raw inks, related coatings, VOC solvent, and water used at the... the purpose of measuring bulk storage tank quantities of each color of raw ink and each related...

40 CFR 60.433 - Performance test and compliance provisions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... facilities routinely share the same raw ink storage/handling system with existing facilities, then temporary measurement procedures for segregating the raw inks, related coatings, VOC solvent, and water used at the... the purpose of measuring bulk storage tank quantities of each color of raw ink and each related...

40 CFR 264.71 - Use of manifest system.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) Within 30 days of delivery, send a copy of the manifest to the generator; and (v) Retain at the facility..., NW., Washington, DC 20460. (b) If a facility receives, from a rail or water (bulk shipment... on the manifest (excluding the EPA identification numbers, generator's certification, and signatures...

Hazardous Waste Cleanup: McKesson Envirosystems in Syracuse Falls, New York

EPA Pesticide Factsheets

The facility is approximately 8.2 acres in size and is located at 400 Bear Street West in the city of Syracuse, south of Onondaga Lake. The facility has been used since the 1930's as a bulk petroleum distribution terminal for gasoline, diesel fuel, heating

Evaluating Fuel Leak and Aging Infrastructure at Red Hill, Hawaii, the Largest Underground Fuel Storage Facility in the United States

EPA Pesticide Factsheets

Learn about how EPA Region 9, Hawaii’s Department of Health, U.S. Navy, and Defense Logistics Agency are working tprotect human health and the environment at the Red Hill Bulk Fuel Storage Facility in Hawaii.

33 CFR 154.1026 - Qualified individual and alternate qualified individual.

Code of Federal Regulations, 2013 CFR

2013-07-01

... BULK Response Plans for Oil Facilities § 154.1026 Qualified individual and alternate qualified individual. (a) The response plan must identify a qualified individual and at least one alternate who meet... implementation of the facility response plan; and (4) Be trained in the responsibilities of the qualified...

33 CFR 154.1060 - Submission and approval procedures.

Code of Federal Regulations, 2011 CFR

2011-07-01

... SECURITY (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for... to which this subpart applies shall submit one copy of a facility response plan meeting the... also required to prepare a response plan under 40 CFR part 112, if the COTP determines that the plan...

33 CFR 154.1026 - Qualified individual and alternate qualified individual.

Code of Federal Regulations, 2012 CFR

2012-07-01

... BULK Response Plans for Oil Facilities § 154.1026 Qualified individual and alternate qualified individual. (a) The response plan must identify a qualified individual and at least one alternate who meet... implementation of the facility response plan; and (4) Be trained in the responsibilities of the qualified...

33 CFR 154.1030 - General response plan contents.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false General response plan contents... (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for Oil Facilities § 154.1030 General response plan contents. (a) The plan must be written in English. (b) A response...

33 CFR 154.1060 - Submission and approval procedures.

Code of Federal Regulations, 2012 CFR

2012-07-01

... SECURITY (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for... to which this subpart applies shall submit one copy of a facility response plan meeting the... also required to prepare a response plan under 40 CFR part 112, if the COTP determines that the plan...

33 CFR 154.1060 - Submission and approval procedures.

Code of Federal Regulations, 2014 CFR

2014-07-01

... SECURITY (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for... to which this subpart applies shall submit one copy of a facility response plan meeting the... also required to prepare a response plan under 40 CFR part 112, if the COTP determines that the plan...

33 CFR 154.1060 - Submission and approval procedures.

Code of Federal Regulations, 2013 CFR

2013-07-01

... SECURITY (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for... to which this subpart applies shall submit one copy of a facility response plan meeting the... also required to prepare a response plan under 40 CFR part 112, if the COTP determines that the plan...

33 CFR 154.1030 - General response plan contents.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false General response plan contents... (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for Oil Facilities § 154.1030 General response plan contents. (a) The plan must be written in English. (b) A response...

33 CFR 154.1026 - Qualified individual and alternate qualified individual.

Code of Federal Regulations, 2011 CFR

2011-07-01

... BULK Response Plans for Oil Facilities § 154.1026 Qualified individual and alternate qualified individual. (a) The response plan must identify a qualified individual and at least one alternate who meet... implementation of the facility response plan; and (4) Be trained in the responsibilities of the qualified...

33 CFR 154.1026 - Qualified individual and alternate qualified individual.

Code of Federal Regulations, 2014 CFR

2014-07-01

... BULK Response Plans for Oil Facilities § 154.1026 Qualified individual and alternate qualified individual. (a) The response plan must identify a qualified individual and at least one alternate who meet... implementation of the facility response plan; and (4) Be trained in the responsibilities of the qualified...

33 CFR 154.1030 - General response plan contents.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false General response plan contents... (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for Oil Facilities § 154.1030 General response plan contents. (a) The plan must be written in English. (b) A response...

33 CFR 154.1060 - Submission and approval procedures.

Code of Federal Regulations, 2010 CFR

2010-07-01

... SECURITY (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for... to which this subpart applies shall submit one copy of a facility response plan meeting the... also required to prepare a response plan under 40 CFR part 112, if the COTP determines that the plan...

33 CFR 154.1030 - General response plan contents.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false General response plan contents... (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for Oil Facilities § 154.1030 General response plan contents. (a) The plan must be written in English. (b) A response...

33 CFR 154.1030 - General response plan contents.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false General response plan contents... (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for Oil Facilities § 154.1030 General response plan contents. (a) The plan must be written in English. (b) A response...

76 FR 39127 - Manufacturer of Controlled Substances; Notice of Application

Federal Register 2010, 2011, 2012, 2013, 2014

2011-07-05

... Administration (DEA) to be registered as a bulk manufacturer of Remifentanil (9739) the basic class of controlled substance in schedule II. The company plans to utilize this facility to manufacture small quantities of the... primary manufacturing facility in West Deptford, New Jersey. The controlled substances manufactured in...

Facilities Management Guide for Asbestos and Lead

DTIC Science & Technology

2004-11-01

equipment such as HEPA filtered power tools, portable welding exhaust systems, and paint removal equipment when work disturbs lead. Do not dry sweep ...sampling and analysis of [______] paint bulk and wipe samples by atomic absorption spectrophotometry (AA) or anodic stripping voltametry (ASV...analysis. e. All bulk (destructive) collected for lead shall be analyzed by atomic absorption spectrophotometry (AA) or anodic stripping voltametry

Shaping Crystal-Crystal Phase Transitions

NASA Astrophysics Data System (ADS)

Du, Xiyu; van Anders, Greg; Dshemuchadse, Julia; Glotzer, Sharon

Previous computational and experimental studies have shown self-assembled structure depends strongly on building block shape. New synthesis techniques have led to building blocks with reconfigurable shape and it has been demonstrated that building block reconfiguration can induce bulk structural reconfiguration. However, we do not understand systematically how this transition happens as a function of building block shape. Using a recently developed ``digital alchemy'' framework, we study the thermodynamics of shape-driven crystal-crystal transitions. We find examples of shape-driven bulk reconfiguration that are accompanied by first-order phase transitions, and bulk reconfiguration that occurs without any thermodynamic phase transition. Our results suggest that for well-chosen shapes and structures, there exist facile means of bulk reconfiguration, and that shape-driven bulk reconfiguration provides a viable mechanism for developing functional materials.

33 CFR 6.12-3 - Approval of facility for dangerous cargo.

Code of Federal Regulations, 2010 CFR

2010-07-01

... dangerous cargo. 6.12-3 Section 6.12-3 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND... Control of Explosives or Other Dangerous Cargo § 6.12-3 Approval of facility for dangerous cargo. The... discharging, explosives, inflammable or combustible liquids in bulk, or other dangerous articles or cargo...

33 CFR 6.12-3 - Approval of facility for dangerous cargo.

Code of Federal Regulations, 2013 CFR

2013-07-01

... dangerous cargo. 6.12-3 Section 6.12-3 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND... Control of Explosives or Other Dangerous Cargo § 6.12-3 Approval of facility for dangerous cargo. The... discharging, explosives, inflammable or combustible liquids in bulk, or other dangerous articles or cargo...

33 CFR 6.12-3 - Approval of facility for dangerous cargo.

Code of Federal Regulations, 2011 CFR

2011-07-01

... dangerous cargo. 6.12-3 Section 6.12-3 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND... Control of Explosives or Other Dangerous Cargo § 6.12-3 Approval of facility for dangerous cargo. The... discharging, explosives, inflammable or combustible liquids in bulk, or other dangerous articles or cargo...

33 CFR 6.12-3 - Approval of facility for dangerous cargo.

Code of Federal Regulations, 2014 CFR

2014-07-01

... dangerous cargo. 6.12-3 Section 6.12-3 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND... Control of Explosives or Other Dangerous Cargo § 6.12-3 Approval of facility for dangerous cargo. The... discharging, explosives, inflammable or combustible liquids in bulk, or other dangerous articles or cargo...

33 CFR 6.12-3 - Approval of facility for dangerous cargo.

Code of Federal Regulations, 2012 CFR

2012-07-01

... dangerous cargo. 6.12-3 Section 6.12-3 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND... Control of Explosives or Other Dangerous Cargo § 6.12-3 Approval of facility for dangerous cargo. The... discharging, explosives, inflammable or combustible liquids in bulk, or other dangerous articles or cargo...

7 CFR 1710.102 - Borrower eligibility for different types of loans.

Code of Federal Regulations, 2012 CFR

2012-01-01

... insured loan to finance any remaining portion of said facilities or for any future insured loan to finance... grid renewable energy systems. (See 7 CFR part 1712). These guarantees are normally used to finance bulk transmission and generation facilities, but they may also be used to finance distribution and...

7 CFR 1710.102 - Borrower eligibility for different types of loans.

Code of Federal Regulations, 2013 CFR

2013-01-01

... insured loan to finance any remaining portion of said facilities or for any future insured loan to finance... grid renewable energy systems. (See 7 CFR part 1712). These guarantees are normally used to finance bulk transmission and generation facilities, but they may also be used to finance distribution and...

Biodegradation of paint stripper solvents in a modified gas lift loop bioreactor.

PubMed

Vanderberg-Twary, L; Steenhoudt, K; Travis, B J; Hanners, J L; Foreman, T M; Brainard, J R

1997-07-05

Paint stripping wastes generated during the decontamination and decommissioning of former nuclear facilities contain paint stripping organics (dichloromethane, 2-propanol, and methanol) and bulk materials containing paint pigments. It is desirable to degrade the organic residues as part of an integrated chemical-biological treatment system. We have developed a modified gas lift loop bioreactor employing a defined consortium of Rhodococcus rhodochrous strain OFS and Hyphomicrobium sp. DM-2 that degrades paint stripper organics. Mass transfer coefficients and kinetic constants for biodegradation in the system were determined. It was found that transfer of organic substrates from surrogate waste into the air and further into the liquid medium in the bioreactor were rapid processes, occurring within minutes. Monod kinetics was employed to model the biodegradation of paint stripping organics. Analysis of the bioreactor process was accomplished with BIOLAB, a mathematical code that simulates coupled mass transfer and biodegradation processes. This code was used to fit experimental data to Monod kinetics and to determine kinetic parameters. The BIOLAB code was also employed to compare activities in the bioreactor of individual microbial cultures to the activities of combined cultures in the bioreactor. This code is of benefit for further optimization and scale-up of the bioreactor for treatment of paint stripping and other volatile organic wastes in bulk materials.

Elemental properties of copper slag and measured airborne exposures at a copper slag processing facility.

PubMed

Mugford, Christopher; Gibbs, Jenna L; Boylstein, Randy

2017-08-01

In 1974, the National Institute for Occupational Safety and Health recommended a ban on the use of abrasives containing >1% silica, giving rise to abrasive substitutes like copper slag. We present results from a National Institute for Occupational Safety and Health industrial hygiene survey at a copper slag processing facility that consisted of the collection of bulk samples for metals and silica; and full-shift area and personal air samples for dust, metals, and respirable silica. Carcinogens, suspect carcinogens, and other toxic elements were detected in all bulk samples, and area and personal air samples. Area air samples identified several areas with elevated levels of inhalable and respirable dust, and respirable silica: quality control check area (236 mg/m 3 inhalable; 10.3 mg/m 3 respirable; 0.430 mg/m 3 silica), inside the screen house (109 mg/m 3 inhalable; 13.8 mg/m 3 respirable; 0.686 mg/m 3 silica), under the conveyor belt leading to the screen house (19.8 mg/m 3 inhalable), and inside a conveyor access shack (11.4 mg/m 3 inhalable; 1.74 mg/m 3 respirable; 0.067 mg/m 3 silica). Overall, personal dust samples were lower than area dust samples and did not exceed published occupational exposure limits. Silica samples collected from a plant hand and a laborer exceeded the American Conference of Governmental Industrial Hygienist Threshold Limit Value of 0.025 µg/m 3 . All workers involved in copper slag processing (n = 5) approached or exceeded the Occupational Safety and Health Administration permissible exposure limit of 10 µg/m 3 for arsenic (range: 9.12-18.0 µg/m 3 ). Personal total dust levels were moderately correlated with personal arsenic levels (R s = 0.70) and personal respirable dust levels were strongly correlated with respirable silica levels (R s = 0.89). We identified multiple areas with elevated levels of dust, respirable silica, and metals that may have implications for personal exposure at other facilities if preventive measures are not taken. To our knowledge, this is the first attempt to characterize exposures associated with copper slag processing. More in-depth air monitoring and health surveillance is needed to understand occupational exposures and health outcomes in this industry.

Investigation on target normal sheath acceleration through measurements of ions energy distribution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tudisco, S., E-mail: tudisco@lns.infn.it; Cirrone, G. A. P.; Mascali, D.

2016-02-15

An experimental campaign aiming at investigating the ion acceleration mechanisms through laser-matter interaction in femtosecond domain has been carried out at the Intense Laser Irradiation Laboratory facility with a laser intensity of up to 2 × 10{sup 19} W/cm{sup 2}. A Thomson parabola spectrometer was used to obtain the spectra of the ions of the different species accelerated. Here, we show the energy spectra of light-ions and we discuss their dependence on structural characteristics of the target and the role of surface and target bulk in the acceleration process.

76 FR 16263 - Revision to Electric Reliability Organization Definition of Bulk Electric System

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-23

...'s Reliability Standards Development Process, to revise its definition of the term ``bulk electric... definition of ``bulk electric system'' through the NERC Standards Development Process to address the... undertake the process of revising the bulk electric system definition to address the Commission's concerns...

Facile Preparation of Light Emitting Organic Metal Halide Crystals with Near-Unity Quantum Efficiency

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhou, Chenkun; Worku, Michael; Neu, Jennifer

Here, we report the synthesis and characterization of (Ph 4P) 2SbCl 5, a novel ionically bonded organic metal halide hybrid with a zero-dimensional (0D) structure at the molecular level. By cocrystallization of tetraphenylphosphonium (Ph 4P +) and antimony (Sb 3+) chloride salts, (Ph 4P) 2SbCl 5 bulk single crystals can be prepared in high yield, which exhibit a highly efficient broadband red emission peaked at 648 nm with a photoluminescence quantum efficiency (PLQE) of around 87%. Density functional theory (DFT) calculations reveal the origin of emission as phosphorescence from the excitons localized at SbCl 5 2– with strong excited-state structuralmore » distortion. Interestingly, (Ph 4P) 2SbCl 5 bulk crystals with a PLQE of around 100% can be prepared via a rapid crystal growth process within minutes, followed by a spontaneous structural transformation. It was found that the rapid growth process yielded a yellow emitting kinetically favored metastable product containing solvent molecules, which turned into the red emitting thermodynamically stable product slowly at room temperature or quickly upon thermal treatment.« less

Facile Preparation of Light Emitting Organic Metal Halide Crystals with Near-Unity Quantum Efficiency

DOE PAGES

Zhou, Chenkun; Worku, Michael; Neu, Jennifer; ...

2018-03-12

Here, we report the synthesis and characterization of (Ph 4P) 2SbCl 5, a novel ionically bonded organic metal halide hybrid with a zero-dimensional (0D) structure at the molecular level. By cocrystallization of tetraphenylphosphonium (Ph 4P +) and antimony (Sb 3+) chloride salts, (Ph 4P) 2SbCl 5 bulk single crystals can be prepared in high yield, which exhibit a highly efficient broadband red emission peaked at 648 nm with a photoluminescence quantum efficiency (PLQE) of around 87%. Density functional theory (DFT) calculations reveal the origin of emission as phosphorescence from the excitons localized at SbCl 5 2– with strong excited-state structuralmore » distortion. Interestingly, (Ph 4P) 2SbCl 5 bulk crystals with a PLQE of around 100% can be prepared via a rapid crystal growth process within minutes, followed by a spontaneous structural transformation. It was found that the rapid growth process yielded a yellow emitting kinetically favored metastable product containing solvent molecules, which turned into the red emitting thermodynamically stable product slowly at room temperature or quickly upon thermal treatment.« less

76 FR 4155 - National Emission Standards for Hazardous Air Pollutants for Source Categories: Gasoline...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-01-24

...This action promulgates amendments to the National Emission Standards for Hazardous Air Pollutants for Source Categories: Gasoline Distribution Bulk Terminals, Bulk Plants, and Pipeline Facilities; and Gasoline Dispensing Facilities, which EPA promulgated on January 10, 2008, and amended on March 7, 2008. In this action, EPA is finalizing amendments and clarifications to certain definitions and applicability provisions of the final rules in response to some of the issues raised in the petitions for reconsideration. In addition, several other compliance-related questions posed by various individual stakeholders and State and local agency representatives are addressed in this action. We are also denying reconsideration on one issue raised in a petition for reconsideration received by the Agency on the final rules.

Bridgman Growth of Germanium

NASA Technical Reports Server (NTRS)

Szofran, F. R.; Volz, M. P.; Cobb, S. D.; Motakef, S.

1997-01-01

The high-magnetic-field crystal growth facility at the Marshall Space Flight Center will be briefly described. This facility has been used to grow bulk germanium by the Bridgman technique in magnetic fields up to 5 Tesla. The results of investigations of ampoule material on the interface shape and thermal field applied to the melt on stability against convection will be discussed.

33 CFR 154.1225 - Specific response plan development and evaluation criteria and other requirements for fixed...

Code of Federal Regulations, 2010 CFR

2010-07-01

... transport animal fats or vegetable oils. 154.1225 Section 154.1225 Navigation and Navigable Waters COAST... MATERIAL IN BULK Response Plans for Animal Fats and Vegetable Oils Facilities § 154.1225 Specific response..., or transport animal fats or vegetable oils. (a) The owner or operator of a fixed facility that...

33 CFR 154.1225 - Specific response plan development and evaluation criteria and other requirements for fixed...

Code of Federal Regulations, 2011 CFR

2011-07-01

... transport animal fats or vegetable oils. 154.1225 Section 154.1225 Navigation and Navigable Waters COAST... MATERIAL IN BULK Response Plans for Animal Fats and Vegetable Oils Facilities § 154.1225 Specific response..., or transport animal fats or vegetable oils. (a) The owner or operator of a fixed facility that...

33 CFR 154.1225 - Specific response plan development and evaluation criteria and other requirements for fixed...

Code of Federal Regulations, 2014 CFR

2014-07-01

... transport animal fats or vegetable oils. 154.1225 Section 154.1225 Navigation and Navigable Waters COAST... MATERIAL IN BULK Response Plans for Animal Fats and Vegetable Oils Facilities § 154.1225 Specific response..., or transport animal fats or vegetable oils. (a) The owner or operator of a fixed facility that...

33 CFR 154.1225 - Specific response plan development and evaluation criteria and other requirements for fixed...

Code of Federal Regulations, 2013 CFR

2013-07-01

... transport animal fats or vegetable oils. 154.1225 Section 154.1225 Navigation and Navigable Waters COAST... MATERIAL IN BULK Response Plans for Animal Fats and Vegetable Oils Facilities § 154.1225 Specific response..., or transport animal fats or vegetable oils. (a) The owner or operator of a fixed facility that...

33 CFR 154.1225 - Specific response plan development and evaluation criteria and other requirements for fixed...

Code of Federal Regulations, 2012 CFR

2012-07-01

... transport animal fats or vegetable oils. 154.1225 Section 154.1225 Navigation and Navigable Waters COAST... MATERIAL IN BULK Response Plans for Animal Fats and Vegetable Oils Facilities § 154.1225 Specific response..., or transport animal fats or vegetable oils. (a) The owner or operator of a fixed facility that...

A Structural Approach to Establishing a Platform Chemistry for the Tunable, Bulk Electron Beam Cross-Linking of Shape Memory Polymer Systems

PubMed Central

Hearon, Keith; Besset, Celine J.; Lonnecker, Alexander T.; Ware, Taylor; Voit, Walter E.; Wilson, Thomas S.; Wooley, Karen L.; Maitland, Duncan J.

2014-01-01

The synthetic design and thermomechanical characterization of shape memory polymers (SMPs) built from a new polyurethane chemistry that enables facile, bulk and tunable cross-linking of low-molecular weight thermoplastics by electron beam irradiation is reported in this study. SMPs exhibit stimuli-induced geometry changes and are being proposed for applications in numerous fields. We have previously reported a polyurethane SMP system that exhibits the complex processing capabilities of thermoplastic polymers and the mechanical robustness and tunability of thermomechanical properties that are often characteristic of thermoset materials. These previously reported polyurethanes suffer practically because the thermoplastic molecular weights needed to achieve target cross-link densities severely limit high-throughput thermoplastic processing and because thermally unstable radiation-sensitizing additives must be used to achieve high enough cross-link densities to enable desired tunable shape memory behavior. In this study, we demonstrate the ability to manipulate cross-link density in low-molecular weight aliphatic thermoplastic polyurethane SMPs (Mw as low as ~1.5 kDa) without radiation-sensitizing additives by incorporating specific structural motifs into the thermoplastic polymer side chains that we hypothesized would significantly enhance susceptibility to e-beam cross-linking. A custom diol monomer was first synthesized and then implemented in the synthesis of neat thermoplastic polyurethane SMPs that were irradiated at doses ranging from 1 to 500 kGy. Dynamic mechanical analysis (DMA) demonstrated rubbery moduli to be tailorable between 0.1 and 55 MPa, and both DMA and sol/gel analysis results provided fundamental insight into our hypothesized mechanism of electron beam cross-linking, which enables controllable bulk cross-linking to be achieved in highly processable, low-molecular weight thermoplastic shape memory polymers without sensitizing additives. PMID:25411511

The Boiling eXperiment Facility (BXF) for the Microgravity Science Glovebox (MSG)

NASA Technical Reports Server (NTRS)

McQuillen, John; Chao, David; Vergilii, Frank

2006-01-01

Boiling is an effective means of cooling by removing heat from surfaces through vaporization of a working fluid. It is also affected by both the magnitude and direction of gravity. By conducting pool boiling tests in microgravity, the effect of buoyancy n the overall boiling process and the relative magnitude of other phenomena can be assessed. The Boiling eXperiment Facility (BXF) is being built for the Microgravity Science Glovebox. This facility will conduct two pool boiling studies. The first study the Microheater Array Boiling Experiment (MABE) uses two 96 element microheater arrays, 2.7 mm and 7.0 mm in size, to measure localized hear fluxes while operating at a constant temperature. The other experiment, the Nucleate Pool Boiling eXperiment (NPBX) uses a 85 mm diameter heater wafer that has been "seeded" with five individually-controlled nucleation sites to study bubble nucleation, growth, coalescence and departure. The BXF uses normal-perfluorohexane as the test fluid and will operate between pressures of 60 to 244 Pa. and temperatures of 35 to 60 C. Both sets of experimental heaters are highly instrumented. Pressure and bulk fluid temperature measurements will be made with standard rate video. A high speed video system will be used to visualize the boiling process through the bottom of the MABE heater arrays. The BXF is currently scheduled to fly on Utilization Flight-13A.1 to the ISS with facility integration into the MSG and operation during Increment 15

Contamination control and assay results for the Majorana Demonstrator ultra clean components

NASA Astrophysics Data System (ADS)

Christofferson, C. D.; Abgrall, N.; Alvis, S. I.; Arnquist, I. J.; Avignone, F. T.; Barabash, A. S.; Barton, C. J.; Bertrand, F. E.; Bode, T.; Bradley, A. W.; Brudanin, V.; Busch, M.; Buuck, M.; Caldwell, T. S.; Chan, Y.-D.; Chu, P.-H.; Cuesta, C.; Detwiler, J. A.; Dunagan, C.; Efremenko, Yu.; Ejiri, H.; Elliott, S. R.; Gilliss, T.; Giovanetti, G. K.; Green, M. P.; Gruszko, J.; Guinn, I. S.; Guiseppe, V. E.; Haufe, C. R.; Hehn, L.; Henning, R.; Hoppe, E. W.; Howe, M. A.; Keeter, K. J.; Kidd, M. F.; Konovalov, S. I.; Kouzes, R. T.; Lopez, A. M.; Martin, R. D.; Massarczyk, R.; Meijer, S. J.; Mertens, S.; Myslik, J.; O'Shaughnessy, C.; Othman, G.; Poon, A. W. P.; Radford, D. C.; Rager, J.; Reine, A. L.; Rielage, K.; Robertson, R. G. H.; Rouf, N. W.; Shanks, B.; Shirchenko, M.; Suriano, A. M.; Tedeschi, D.; Trimble, J. E.; Varner, R. L.; Vasilyev, S.; Vetter, K.; Vorren, K.; White, B. R.; Wilkerson, J. F.; Wiseman, C.; Xu, W.; Yakushev, E.; Yu, C.-H.; Yumatov, V.; Zhitnikov, I.; Zhu, B. X.

2018-01-01

The Majorana Demonstrator is a neutrinoless double beta decay experiment utilizing enriched Ge-76 detectors in 2 separate modules inside of a common solid shield at the Sanford Underground Research Facility. The Demonstrator has utilized world leading assay sensitivities to develop clean materials and processes for producing ultra-pure copper and plastic components. This experiment is now operating, and initial data provide new insights into the success of cleaning and processing. Post production copper assays after the completion of Module 1 showed an increase in U and Th contamination in finished parts compared to starting bulk material. A revised cleaning method and additional round of surface contamination studies prior to Module 2 construction have provided evidence that more rigorous process control can reduce surface contamination. This article describes the assay results and discuss further studies to take advantage of assay capabilities for the purpose of maintaining ultra clean fabrication and process design.

Modeling of Non-Homogeneous Containment Atmosphere in the ThAI Experimental Facility Using a CFD Code

DOE Office of Scientific and Technical Information (OSTI.GOV)

Babic, Miroslav; Kljenak, Ivo; Mavko, Borut

2006-07-01

The CFD code CFX4.4 was used to simulate an experiment in the ThAI facility, which was designed for investigation of thermal-hydraulic processes during a severe accident inside a Light Water Reactor containment. In the considered experiment, air was initially present in the vessel, and helium and steam were injected during different phases of the experiment at various mass flow rates and at different locations. The main purpose of the simulation was to reproduce the non-homogeneous temperature and species concentration distributions in the ThAI experimental facility. A three-dimensional model of the ThAI vessel for the CFX4.4 code was developed. The flowmore » in the simulation domain was modeled as single-phase. Steam condensation on vessel walls was modeled as a sink of mass and energy using a correlation that was originally developed for an integral approach. A simple model of bulk phase change was also introduced. The calculated time-dependent variables together with temperature and concentration distributions at the end of experiment phases are compared to experimental results. (authors)« less

MaRIE: Probing Dynamic Processes in Soft Materials Using Advanced Light Sources

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sykora, Milan; Kober, Edward Martin

Los Alamos National Laboratory has developed a concept for a new research facility, MaRIE: Matter-Radiation Interactions in Extremes. The key motivation for MaRIE is to develop new experimental capabilities needed to fill the existing gaps in our fundamental understanding of materials important for key National Nuclear Security Agency (NNSA) goals. MaRIE will bring two major new capabilities: (a) the ability to characterize the meso- and microstructure of materials in bulk as well as local dynamic response characteristics, and (b) the ability to characterize how this microstructure evolves under NNSA-relevant conditions and impacts the material’s performance in this regime.

Liquid phase electroepitaxial bulk growth of binary and ternary alloy semiconductors under external magnetic field

NASA Astrophysics Data System (ADS)

Sheibani, Hamdi

2002-01-01

Liquid Phase Electroepitaxy (LPEE) and is a relatively new, promising technique for producing high quality, thick compound semiconductors and their alloys. The main objectives are to reduce the adverse effect of natural convection and to determine the optimum growth conditions for reproducible desired crystals for the optoelectronic and electronic device industry. Among the available techniques for suppressing the adverse effect of natural convection, the application of an external magnetic field seems the most feasible one. The research work in this dissertation consists of two parts. The first part is focused on the design and development of a state of the art LPEE facility with a novel crucible design, that can produce bulk crystals of quality higher than those achieved by the existing LPEE system. A growth procedure was developed to take advantage of this novel crucible design. The research of the growth of InGaAs single crystals presented in this thesis will be a basis for the future LPEE growth of other important material and is an ideal vehicle for the development of a ternary crystal growth process. The second part of the research program is the experimental study of the LPEE growth process of high quality bulk single crystals of binary/ternary semiconductors under applied magnetic field. The compositional uniformity of grown crystals was measured by Electron Probe Micro-analysis (EPMA) and X-ray microanalysis. The state-of-the-art LPEE system developed at University of Victoria, because of its novel design features, has achieved a growth rate of about 4.5 mm/day (with the application of an external fixed magnetic field of 4.5 KGauss and 3 A/cm2 electric current density), and a growth rate of about 11 mm/day (with 4.5 KGauss magnetic field and 7 A/cm2 electric current density). This achievement is simply a breakthrough in LPEE, making this growth technique absolutely a bulk growth technique and putting it in competition with other bulk growth techniques. The growth rates achieved can even be higher for higher electric current and magnetic field intensities. (Abstract shortened by UMI.)

33 CFR 154.2108 - Vapor-moving devices.

Code of Federal Regulations, 2014 CFR

2014-07-01

...) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Marine Vapor Control Systems Transfer... vibration; (4) Low lube oil level; (5) Low lube oil pressure; and (6) Excessive shaft bearing temperature...

33 CFR 154.826 - Vapor compressors and blowers.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Vapor Control Systems § 154... chamber or cylinder; (2) Excessive cooling water temperature; (3) Excessive vibration; (4) Low lube oil...

33 CFR 154.826 - Vapor compressors and blowers.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Vapor Control Systems § 154... chamber or cylinder; (2) Excessive cooling water temperature; (3) Excessive vibration; (4) Low lube oil...

33 CFR 154.826 - Vapor compressors and blowers.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Vapor Control Systems § 154... chamber or cylinder; (2) Excessive cooling water temperature; (3) Excessive vibration; (4) Low lube oil...

Red Hill

EPA Pesticide Factsheets

Information about the Red Hill Bulk Fuel Storage Facility in Hawaii Administrative Order on Consent (AOC), an enforceable agreement of the Hawaii Department of Health, the Environmental Protection Agency, and the U.S. Navy -- Defense Logistics Agency.

Facile synthesis of biphasic calcium phosphate microspheres with engineered surface topography for controlled delivery of drugs and proteins.

PubMed

Zarkesh, Ibrahim; Ghanian, Mohammad Hossein; Azami, Mahmoud; Bagheri, Fatemeh; Baharvand, Hossein; Mohammadi, Javad; Eslaminejad, Mohamadreza Baghaban

2017-09-01

Biphasic calcium phosphate (BCP) microspheres are of great interest due to their high stability and osteoinductive properties at specific compositions. However, the need for optimal performance at a unique composition limits their flexibility for tuning drug release by modulation of bulk properties and presents the question of engineering surface topography as an alternative. It is necessary to have a facile method to control surface topography at a defined bulk composition. Here, we have produced BCP microspheres with different surface topographies that have the capability to be used as tunable drug release systems. We synthesized calcium deficient hydroxyapatite (CDHA) microparticles by precipitating calcium and phosphate ions onto ethylenediaminetetraacetic acid (EDTA) templates. The morphology and surface topography of CDHA microparticles were controlled using process parameters, which governed nucleation and growth. These parameters included template concentration, heat rate, and stirring speed. Under low heat rate and static conditions, we could obtain spherical microparticles with long and short nanosheets on their surfaces at low and high EDTA concentrations, respectively. These nanostructured microspheres were subsequently crystallized by thermal treatment to produce EDTA-free BCP microspheres with intact morphology. These biocompatible BCP microspheres were highly effective in loading and prolonged release of both small molecule [dexamethasone (Dex)] and protein [bovine serum albumin (BSA)] models. This strategy has enabled us to control the surface topography of BCP microspheres at defined compositions and holds tremendous promise for drug delivery and tissue engineering applications. Copyright © 2017 Elsevier B.V. All rights reserved.

7 CFR 70.15 - Equipment and facilities for graders.

Code of Federal Regulations, 2011 CFR

2011-01-01

... drill holes in frozen product for inserting the metal thermometer stem to determine temperature. (3... or less for weighing bulk containers of poultry and test weights for such scales. (b) Furnished...

Nanometrization of Lanthanide-Based Coordination Polymers.

PubMed

Neaime, Chrystelle; Daiguebonne, Carole; Calvez, Guillaume; Freslon, Stéphane; Bernot, Kevin; Grasset, Fabien; Cordier, Stéphane; Guillou, Olivier

2015-11-23

Heteronuclear lanthanide-based coordination polymers are microcrystalline powders, the luminescence properties of which can be precisely tuned by judicious choice of the rare-earth ions. In this study, we demonstrate that such materials can also be obtained as stable solutions of nanoparticles in non-toxic polyols. Bulk powders of the formula [Ln2-2x Ln'2x (bdc)3 ⋅4 H2 O]∞ (where H2 bdc denotes 1,4-benzene-dicarboxylic acid, 0≤x≤1, and Ln and Ln' denote lanthanide ions of the series La to Tm plus Y) afford nanoparticles that have been characterized by dynamic light-scattering (DLS) and transmission electron microscopy (TEM) measurements. Their luminescence properties are similar to those of the bulk materials. Stabilities versus time and versus dilution with another solvent have been studied. This study has revealed that it is possible to tune the size of the nanoparticles. This process offers a reliable means of synthesizing suspensions of nanoparticles with tunable luminescence properties and tunable size distributions in a green solvent (glycerol). The process is also extendable to other coordination polymers and other solvents (ethylene glycol, for example). It constitutes a new route for the facile solubilization of lanthanide-based coordination polymers. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Material Science Experiments on Mir

NASA Technical Reports Server (NTRS)

Kroes, Roger L.

1999-01-01

This paper describes the microgravity materials experiments carried out on the Shuttle/Mir program. There were six experiments, all of which investigated some aspect of diffusivity in liquid melts. The Liquid Metal Diffusion (LMD) experiment investigated the diffusivity of molten Indium samples at 185 C using a radioactive tracer, In-114m. By monitoring two different gamma ray energies (190 keV and 24 keV) emitted by the samples it was possible to measure independently the diffusion rates in the bulk and at the surface of the samples. The Queens University Experiment in Liquid Diffusion (QUELD) was the furnace facility used to process 213 samples for the five other experiments. These experiments investigated the diffusion, ripening, crystal growth, and glass formation in metal, semiconductor, and glass samples. This facility had the capability to process samples in an isothermal or gradient configuration for varying periods of time at temperatures up to 900 C. Both the LMD and the QUELD furnaces were mounted on the Microgravity Isolation Mount (MIM) which provided isolation from g-jitter. All the microgravity experiments were supported by the Space Acceleration Measurement System (SAMS); a three head three axes acceleration monitoring system which measured and recorded the acceleration environment.

A facile and green method towards coal-based fluorescent carbon dots with photocatalytic activity

NASA Astrophysics Data System (ADS)

Hu, Shengliang; Wei, Zhijia; Chang, Qing; Trinchi, Adrian; Yang, Jinlong

2016-08-01

One of the most widely used methods for exfoliating crystalline nanocarbon is via strong oxidizing acid treatment of bulk carbon sources, such as graphite, carbon black and coal. Not only is such method dangerous and accompanied by the liberation of toxic gases, it is also plagued by issues of purity, requiring the thorough and costly removal of the excess oxidizing acids and salts formed during the process. Herein we report a facile, green and inexpensive top-down strategy towards fluorescent carbon dots (CDs) from coal without incurring the burden of tedious or inefficient post-processing steps and facing the danger of highly toxic gas liberation. The presented approach shows a high yield and great potential for carbon dot production scale-up using coal, one of our most abundant and low-cost resources. The prepared CDs demonstrate photocatalytic behavior capable of rapidly degrading organic dyes under visible light. Our findings may lead to alternative uses of coal, particularly for applications including the treatment of environmental pollution, solar energy conversion or storage, and highlight coal's applicability in areas other than energy producing via burning of this great resource.

Measuring Device for Air Speed in Macroporous Media and Its Application Inside Apple Storage Bins.

PubMed

Geyer, Martin; Praeger, Ulrike; Truppel, Ingo; Scaar, Holger; Neuwald, Daniel A; Jedermann, Reiner; Gottschalk, Klaus

2018-02-13

In cold storage facilities of fruit and vegetables, airflow is necessary for heat removal. The design of storage facilities influences the air speed in the surrounding of the product. Therefore, knowledge about airflow next to the product is important to plan the layout of cold stores adapted to the requirements of the products. A new sensing device (ASL, Air speed logger) is developed for omnidirectional measurement of air speed between fruit or vegetables inside storage bins or in bulk. It consists of four interconnected plastic spheres with 80 mm diameter each, adapted to the size of apple fruit. In the free space between the spheres, silicon diodes are fixed for the airflow measurement based on a calorimetric principle. Battery and data logger are mounted inside the spheres. The device is calibrated in a wind tunnel in a measuring range of 0-1.3 m/s. Air speed measurements in fruit bulks on laboratory scale and in an industrial fruit store show air speeds in gaps between fruit with high stability at different airflow levels. Several devices can be placed between stored products for determination of the air speed distribution inside bulks or bin stacks in a storage room.

Red Hill Administrative Order on Consent

EPA Pesticide Factsheets

Orderequiring the Navy and DLA to take actions, subject to DOH and EPA approval, to address fuel releases and implement infrastructure improvements to protect human health and the environment Red Hill Bulk Fuel Storage Facility in Hawaii.

75 FR 8318 - Agency Information Collection Activities: Submission for OMB Review; Comment Request

Federal Register 2010, 2011, 2012, 2013, 2014

2010-02-24

... and disposition of crude oil, petroleum products, and natural gas liquids. The data are published by..., blending plants, bulk terminals, crude oil and product pipelines, natural gas plant facilities, tankers...

Thin Film Approaches to the SRF Cavity Problem: Fabrication and Characterization of Superconducting Thin Films

NASA Astrophysics Data System (ADS)

Beringer, Douglas B.

Superconducting Radio Frequency (SRF) cavities are responsible for the acceleration of charged particles to relativistic velocities in most modern linear accelerators, such as those employed at high-energy research facilities like Thomas Jefferson National Laboratory's CEBAF and the LHC at CERN. Recognizing SRF as primarily a surface phenomenon enables the possibility of applying thin films to the interior surface of SRF cavities, opening a formidable tool chest of opportunities by combining and designing materials that offer greater benefit. Thus, while improvements in radio frequency cavity design and refinements in cavity processing techniques have improved accelerator performance and efficiency - 1.5 GHz bulk niobium SRF cavities have achieved accelerating gradients in excess of 35 MV/m - there exist fundamental material bounds in bulk superconductors limiting the maximally sustained accelerating field gradient (approximately 45 MV/m for Niobium) where inevitable thermodynamic breakdown occurs. With state of the art niobium based cavity design fast approaching these theoretical limits, novel material innovations must be sought in order to realize next generation SRF cavities. One proposed method to improve SRF performance is to utilize thin film superconducting-insulating-superconducting (SIS) multilayer structures to effectively magnetically screen a bulk superconducting layer such that it can operate at higher field gradients before suffering critically detrimental SRF losses. This dissertation focuses on the production and characterization of thin film superconductors for such SIS layers for radio-frequency applications.

Tritium systems test assembly stabilization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jasen, W. G.; Michelotti, R. A.; Anast, K. R.

The Tritium Systems Test Assembly (TSTA) was a facility dedicated to tritium technology Research and Development (R&D) primarily for future fusion power reactors. The facility was conceived in mid 1970's, operations commenced in early 1980's, stabilization and deactivation began in 2000 and were completed in 2003. The facility will remain in a Surveillance and Maintenance (S&M) mode until the Department of Energy (DOE) funds demolition of the facility, tentatively in 2009. A safe and stable end state was achieved by the TSTA Facility Stabilization Project (TFSP) in anticipation of long term S&M. At the start of the stabilization project, withmore » an inventory of approximately 140 grams of tritium, the facility was designated a Hazard Category (HC) 2 Non-Reactor Nuclear facility as defined by US Department of Energy standard DOE-STD-1027-92 (1997). The TSTA facility comprises a laboratory area, supporting rooms, offices and associated laboratory space that included more than 20 major tritium handling systems. The project's focus was to reduce the tritium inventory by removing bulk tritium, tritiated water wastes, and tritium-contaminated high-inventory components. Any equipment that remained in the facility was stabilized in place. All of the gloveboxes and piping were rendered inoperative and vented to atmosphere. All equipment, and inventoried tritium contamination, remaining in the facility was left in a safe-and-stable state. The project used the End Points process as defined by the DOE Office of Environmental Management (web page http://www.em.doe.- gov/deact/epman.htmtlo) document and define the end state required for the stabilization of TSTA Facility. The End Points process added structure that was beneficial through virtually all phases of the project. At completion of the facility stabilization project the residual tritium inventory was approximately 3,000 curies, considerably less than the 1.6-gram threshold for a HC 3 facility. TSTA is now designated as a Radiological Facility. Innovative approaches were employed for characterization and removal of legacy wastes and high inventory components. Major accomplishments included: (1) Reduction of tritium inventory, elimination of chemical hazards, and identification and posting of remaining hazards. (2) Removal of legacy wastes. (3) Transferred equipment for reuse in other DOE projects, including some at other DOE facilities. (4) Transferred facility in a safe and stable condition to the S&M organization. The project successfully completed all project goals and the TSTA facility was transferred into S&M on August 1,2003. This project demonstrates the benefit of radiological inventory reduction and the removal of legacy wastes to achieve a safe and stable end state that protects workers and the environment pending eventual demolition of the facility.« less

Bioleached sludge composting drastically reducing ammonia volatilization as well as decreasing bulking agent dosage and improving compost quality: A case study.

PubMed

Hu, Weitong; Zheng, Guanyu; Fang, Di; Cui, Chunhong; Liang, Jianru; Zhou, Lixiang

2015-10-01

Sludge bioleaching technology with Acidithiobacillus species has been commercially adopted for improving advanced dewatering of sludge in China since 2010. However, up to now, little information on bioleached dewatered sludge (BS) composting is available. Here, we report the changes of physicochemical and biological properties in BS composting and evaluate compost product quality compared to conventional dewatered sludge (CS) composting in an engineering scale composting facility. The results showed that the amount of bulking agents required in BS composting was only about 10% of CS composting to obtain optimum moisture content, reducing about 700 kg bulking agents per ton fresh sludge. pH of BS composting mixture was slightly lower consistently by about 0.2-0.3 pH units than that in CS mixture in the first 30 days. Organic matter biodegradation in BS system mainly occurred in the first 9 days of composting. In spite of higher content of NH4(+)-N was found in BS mixture in related to CS mixture; unexpectedly the cumulative ammonia volatilization in the former was only 51% of the latter, indicating that BS composting drastically reduced nitrogen loss. Compared to CS composting system, the relative lower pH, the higher intensity of microbial assimilation, and the presence of water soluble Fe in BS system might jointly reduce ammonia volatilization. Consequently, BS compost product exhibited higher fertilizer values (N+P2O5+K2O=8.38%) as well as lower heavy metal levels due to the solubilization of sludge-borne heavy metals during bioleaching process. Therefore, composting of BS possesses more advantages over the CS composting process. Copyright © 2015 Elsevier Ltd. All rights reserved.

Radio Frequency Plasma Synthesis of Boron Nitride Nanotubes (BNNTs) for Structural Applications. Part II

NASA Technical Reports Server (NTRS)

Hales, Stephen J.; Alexa, Joel A.; Jensen, Brian J.

2016-01-01

Boron nitride nanotubes (BNNTs) are more thermally and chemically compatible with metal- and ceramic-matrix composites than carbon nanotubes (CNTs). The lack of an abundant supply of defect-free, high-aspect-ratio BNNTs has hindered development as reinforcing agents in structural materials. Recent activities at the National Research Council - Canada (NRC-C) and the University of California - Berkeley (UC-B) have resulted in bulk synthesis of few-walled, small diameter BNNTs. Both processes employ induction plasma technology to create boron vapor and highly reactive nitrogen species at temperatures in excess of 8000 K. Subsequent recombination under controlled cooling conditions results in the formation of BNNTs at a rate of 20 g/hr and 35 g/hr, respectively. The end product tends to consist of tangled masses of fibril-, sheet-, and cotton candy-like materials, which accumulate within the processing equipment. The radio frequency plasma spray (RFPS) facility at NASA Langley (LaRC), developed for metallic materials deposition, has been re-tooled for in-situ synthesis of BNNTs. The NRC-C and UC-B facilities comprise a 60 kW RF torch, a reactor with a stove pipe geometry, and a filtration system. In contrast, the LaRC facility has a 100 kW torch mounted atop an expansive reaction chamber coupled with a cyclone separator. The intent is to take advantage of both the extra power and the equipment configuration to simultaneously produce and gather BNNTs in a macroscopic form amenable to structural material applications.

Examining the freezing process of an intermediate bulk containing an industrially relevant protein

PubMed Central

Reinsch, Holger; Spadiut, Oliver; Heidingsfelder, Johannes; Herwig, Christoph

2015-01-01

Numerous biopharmaceuticals are produced in recombinant microorganisms in the controlled environment of a bioreactor, a process known as Upstream Process. To minimize product loss due to physico-chemical and enzymatic degradation, the Upstream Process should be directly followed by product purification, known as Downstream Process. However, the Downstream Process can be technologically complex and time-consuming which is why Upstream and Downstream Process usually have to be decoupled temporally and spatially. Consequently, the product obtained after the Upstream Process, known as intermediate bulk, has to be stored. In those circumstances, a freezing procedure is often performed to prevent product loss. However, the freezing process itself is inseparably linked to physico-chemical changes of the intermediate bulk which may in turn damage the product. The present study analysed the behaviour of a Tris-buffered intermediate bulk containing a biopharmaceutically relevant protein during a bottle freezing process. Major damaging mechanisms, like the spatiotemporal redistribution of ion concentrations and pH, and their influence on product stability were investigated. Summarizing, we show the complex events which happen in an intermediate bulk during freezing and explain the different causes for product loss. PMID:25765305

Enhancement of the inverted polymer solar cells via ZnO doped with CTAB

NASA Astrophysics Data System (ADS)

Sivashnamugan, Kundan; Guo, Tzung-Fang; Hsu, Yao-Jane; Wen, Ten-Chin

2018-02-01

A facile approach enhancing electron extraction in zinc oxide (ZnO) electron transfer interlayer and improving performance of bulk-heterojunction (BHJ) polymer solar cells (PSCs) by adding cetyltrimethylammonium bromide (CTAB) into sol-gel ZnO precursor solution was demonstrated in this work. The power conversion efficiency (PCE) has a 24.1% increment after modification. Our results show that CTAB can dramatically influence optical, electrical and morphological properties of ZnO electron transfer layer, and work as effective additive to enhance the performance of bulk- heterojunction polymer solar cells.

Mesoscopic Free Path of Nonthermalized Photogenerated Carriers in a Ferroelectric Insulator.

PubMed

Gu, Zongquan; Imbrenda, Dominic; Bennett-Jackson, Andrew L; Falmbigl, Matthias; Podpirka, Adrian; Parker, Thomas C; Shreiber, Daniel; Ivill, Mathew P; Fridkin, Vladimir M; Spanier, Jonathan E

2017-03-03

We show how finite-size scaling of a bulk photovoltaic effect-generated electric field in epitaxial ferroelectric insulating BaTiO_{3}(001) films and a photo-Hall response involving the bulk photovoltaic current reveal a large room-temperature mean free path of photogenerated nonthermalized electrons. Experimental determination of mesoscopic ballistic optically generated carrier transport opens a new paradigm for hot electron-based solar energy conversion, and for facile control of ballistic transport distinct from existing low-dimensional semiconductor interfaces, surfaces, layers, or other structures.

Moderate Bacterial Etching Allows Scalable and Clean Delamination of g-C3N4 with Enriched Unpaired Electrons for Highly Improved Photocatalytic Water Disinfection.

PubMed

Kang, Shifei; Huang, Wei; Zhang, Lu; He, Maofen; Xu, Suyun; Sun, Di; Jiang, Xia

2018-04-25

Delamination treatment is crucial in promoting the activity of bulk graphitic carbon nitride (g-C 3 N 4 ). However, most of the currently used methods of exfoliating bulk g-C 3 N 4 to achieve g-C 3 N 4 thin layers suffer from low yield and environmental pollution. Herein, we developed a facile bacterial etching approach for the preparation of high-quality g-C 3 N 4 nanosheets by exfoliating bulk g-C 3 N 4 under room temperature. Morphology and physicochemical characterizations show that the bacteria-treated g-C 3 N 4 (BT-CN) samples, especially BT-CN-2d, have a lamina-like two-dimensional (2D) in-plane porous structure, a significantly enlarged specific surface area (82.61 m 2 g -1 ), and a remarkable narrow band gap (2.11 eV). X-ray photoelectron spectroscopy and electron paramagnetic resonance spectra confirm the dramatic enrichment of unpaired electron in the BT-CN-2d g-C 3 N 4 nanosheets. EIS spectra and photocurrent tests indicate the fast electron transportation. As a result, the representative BT-CN-2d g-C 3 N 4 photocatalyst shows an optimal visible light-driven photocatalytic performance in water disinfection (fourfold higher than bulk g-C 3 N 4 ), as well as good cycle stability. This moderate and clean bacterial etching process can be realized in tens of gram scale in the laboratory and should be readily extended to kilogram scale. The present work provides fundamental knowledge about the scalable production of high-quality g-C 3 N 4 by bioengineering method, offering extendable availability for designing and fabricating other functional 2D materials.

Research activity at the shock tube facility at NASA Ames

NASA Astrophysics Data System (ADS)

Sharma, Surendra P.

1992-03-01

The real gas phenomena dominate the relaxation process occurring in the flow around hypersonic vehicles. The air flow around these vehicles undergoes vibrational excitation, chemical dissociation, and ionization. These chemical and kinetic phenomena absorb energy, change compressibility, cause temperature to fall, and density to rise. In high-altitude, low density environments, the characteristic thicknesses of the shock layers can be smaller than the relaxation distances required for the gas to attain chemical and thermodynamic equilibrium. To determine the effects of chemical nonequilibrium over a realistic hypersonic vehicle, it would be desirable to conduct an experiment in which all aspects of fluid flow are simulated. Such an experiment is extremely difficult to setup. The only practical alternative is to develop a theoretical model of the phenomena and to compute the flow around the vehicle including the chemical nonequilibrium, and compare the results with the experiments conducted in the facilities under conditions where only a portion of the flow phenomena is simulated. Three types of experimental data are needed to assist the aerospace community in this model development process: (1) data which will enhance our phenomenological understanding of the relaxation process, (2) data on rate reactions for the relevant reactions, and (3) data on bulk properties, such as spectral radiation emitted by the gas, for a given set of aerodynamic conditions. NASA Ames is in a process of collecting such data by simulating the required aerothermochemical conditions in an electric arc driven shock tube.

Koch Carbon LLC Response to Section 114 Information Request

EPA Pesticide Factsheets

Koch Carbon states objections to several of EPA's Dec. 30, 2013 requests, and asserts that its pet coke facilities do not fall within their scope. It does provide end user information for petroleum coke stored/handled by Detroit Bulk Storage.

Improving striping operations through system optimization - phase 2 : final report.

DOT National Transportation Integrated Search

2016-07-01

Striping operations generate a significant workload for MoDOT maintenance operations. The requirement for each striping crew : to replenish its stock of paint and other consumable items from a bulk storage facility, along with the necessity to make s...

High-Oriented Thermoelectric Nano-Bulk Fabricated from Thermoelectric Ink

NASA Astrophysics Data System (ADS)

Koyano, M.; Mizutani, S.; Hayashi, Y.; Nishino, S.; Miyata, M.; Tanaka, T.; Fukuda, K.

2017-05-01

Printing technology is expected to provide innovative and environmentally friendly processes for thermoelectric (TE) module fabrication. As described in this paper, we propose an orientation control process using plastic deformation at high temperatures and present high-oriented TE nano-bulks fabricated from bismuth telluride (Bi-Te) TE inks using this process. In the case of n-type Bi-Te, surface x-ray diffraction reveals that crystalline grains in the plastic-deformed nano-bulk demonstrate a c-plane orientation parallel to the pressed face. According to the high orientation, electrical resistivity ρ, thermal conductivity κ, and figure of merit ZT show anisotropic behavior. It is noteworthy that ( ZT)// almost reaches unity ( ZT)// ˜1 at 340 K, even at low temperatures of the plastic deformation process. In contrast, the ZT of plastic-deformed p-type nano-bulk indicates isotropic behavior. The difference in the process temperature dependence of ZT suggests that n-type and p-type nano-bulk orientation mechanisms mutually differ.

Technical issues of a high-Tc superconducting bulk magnet

NASA Astrophysics Data System (ADS)

Fujimoto, Hiroyuki

2000-06-01

Superconducting magnets made of high-Tc superconductors are promising for industrial applications. It is well known that REBa2Cu3O7-x superconductors prepared by melt processes have a high critical current density, Jc, at 77 K and high magnetic fields. The materials are very promising for high magnetic field applications as a superconducting permanent/bulk magnet with liquid-nitrogen refrigeration. Light rare-earth (LRE) BaCuO bulks, compared with REBaCuO bulks, exhibit a larger Jc in high magnetic fields and a much improved irreversibility field, Hirr, at 77 K. In this study, we discuss technical issues of a high-Tc superconducting bulk magnet, namely the aspects of the melt processing for bulk superconductors, their characteristic superconducting properties and mechanical properties, and trapped field properties of a superconducting bulk magnet. One of the possible applications is a superconducting bulk magnet for the magnetically levitated (Maglev) train in the future.

Quasi-one-dimensional arrangement of silver nanoparticles templated by cellulose microfibrils.

PubMed

Wu, Min; Kuga, Shigenori; Huang, Yong

2008-09-16

We demonstrate a simple, facile approach to the deposition of silver nanoparticles on the surface of cellulose microfibrils with a quasi-one-dimensional arrangement. The process involves the generation of aldehyde groups by oxidizing the surface of cellulose microfibrils and then the assembly of silver nanoparticles on the surface by means of the silver mirror reaction. The linear nature of the microfibrils and the relatively uniform surface chemical modification result in a uniform linear distribution of silver particles along the microfibrils. The effects of various reaction parameters, such as the reaction time for the reduction process and employed starting materials, have been investigated by transmission electron microscopy (TEM) and ultraviolet-visible spectroscopy. Additionally, the products were examined for their electric current-voltage characteristics, the results showing that these materials had an electric conductivity of approximately 5 S/cm, being different from either the oxidated cellulose or bulk silver materials by many orders of magnitude.

Microscale patterning of thermoplastic polymer surfaces by selective solvent swelling.

PubMed

Rahmanian, Omid; Chen, Chien-Fu; DeVoe, Don L

2012-09-04

A new method for the fabrication of microscale features in thermoplastic substrates is presented. Unlike traditional thermoplastic microfabrication techniques, in which bulk polymer is displaced from the substrate by machining or embossing, a unique process termed orogenic microfabrication has been developed in which selected regions of a thermoplastic surface are raised from the substrate by an irreversible solvent swelling mechanism. The orogenic technique allows thermoplastic surfaces to be patterned using a variety of masking methods, resulting in three-dimensional features that would be difficult to achieve through traditional microfabrication methods. Using cyclic olefin copolymer as a model thermoplastic material, several variations of this process are described to realize growth heights ranging from several nanometers to tens of micrometers, with patterning techniques include direct photoresist masking, patterned UV/ozone surface passivation, elastomeric stamping, and noncontact spotting. Orogenic microfabrication is also demonstrated by direct inkjet printing as a facile photolithography-free masking method for rapid desktop thermoplastic microfabrication.

Enhanced electrochemical performance of orientated VO2(B) raft-like nanobelt arrays through direct lithiation for lithium ion batteries.

PubMed

Liu, Liang; Liu, Qiang; Zhao, Wen; Li, Guochun; Wang, Limei; Shi, Weidong; Chen, Long

2017-02-10

Lithiation modification of VO 2 (B) has been carried out by a facile hydrothermal process, and the compact and locally ordered VO 2 (B) raft-like nanobelt arrays have been prepared. The synthesis route provides a new approach to elaborate a VO 2 (B) nanostructure under a mild environment condition. It is found that the growth mechanism of VO 2 (B) raft-like nanobelt arrays is different from the traditional nucleation-growth process. A novel chemical lithiating-exfoliating-splitting model is proposed. Compared with the bulk counterpart, the lithiated VO 2 (B) raft-like nanobelt arrays as cathodes exhibit a higher discharge capacity and an enhanced high-rate performance owing to their increased structural anisotropy and decreased polarization. This work indicates that VO 2 (B) raft-like nanobelt arrays have great potential applications as cathode materials for lithium ion batteries.

Enhanced electrochemical performance of orientated VO2(B) raft-like nanobelt arrays through direct lithiation for lithium ion batteries

NASA Astrophysics Data System (ADS)

Liu, Liang; Liu, Qiang; Zhao, Wen; Li, Guochun; Wang, Limei; Shi, Weidong; Chen, Long

2017-02-01

Lithiation modification of VO2(B) has been carried out by a facile hydrothermal process, and the compact and locally ordered VO2(B) raft-like nanobelt arrays have been prepared. The synthesis route provides a new approach to elaborate a VO2(B) nanostructure under a mild environment condition. It is found that the growth mechanism of VO2(B) raft-like nanobelt arrays is different from the traditional nucleation-growth process. A novel chemical lithiating-exfoliating-splitting model is proposed. Compared with the bulk counterpart, the lithiated VO2(B) raft-like nanobelt arrays as cathodes exhibit a higher discharge capacity and an enhanced high-rate performance owing to their increased structural anisotropy and decreased polarization. This work indicates that VO2(B) raft-like nanobelt arrays have great potential applications as cathode materials for lithium ion batteries.

Measuring Device for Air Speed in Macroporous Media and Its Application Inside Apple Storage Bins

PubMed Central

Geyer, Martin; Praeger, Ulrike; Scaar, Holger; Neuwald, Daniel A.; Gottschalk, Klaus

2018-01-01

In cold storage facilities of fruit and vegetables, airflow is necessary for heat removal. The design of storage facilities influences the air speed in the surrounding of the product. Therefore, knowledge about airflow next to the product is important to plan the layout of cold stores adapted to the requirements of the products. A new sensing device (ASL, Air speed logger) is developed for omnidirectional measurement of air speed between fruit or vegetables inside storage bins or in bulk. It consists of four interconnected plastic spheres with 80 mm diameter each, adapted to the size of apple fruit. In the free space between the spheres, silicon diodes are fixed for the airflow measurement based on a calorimetric principle. Battery and data logger are mounted inside the spheres. The device is calibrated in a wind tunnel in a measuring range of 0–1.3 m/s. Air speed measurements in fruit bulks on laboratory scale and in an industrial fruit store show air speeds in gaps between fruit with high stability at different airflow levels. Several devices can be placed between stored products for determination of the air speed distribution inside bulks or bin stacks in a storage room. PMID:29438339

Preliminary study of superconducting bulk magnets for Maglev

NASA Astrophysics Data System (ADS)

Fujimoto, Hiroyuki; Kamijo, Hiroki

Recent development shows that melt-processed YBaCuO (Y123) or Rare Earth (RE)123 superconductors have a high Jc at 77 K and high magnetic field, leading to high field application as a superconducting quasi-permanent bulk magnet with the liquid nitrogen refrigeration. One of the promising applications is a superconducting magnet for the magnetically levitated (Maglev) train. We discuss a superconducting bulk magnet for the Maglev train in the aspect of a preliminary design of the bulk magnet and also processing for (L)REBaCuO bulk superconductors and their characteristic superconducting properties.

Demonstration of a 1 MWe biomass power plant at USMC Base Camp Lejeune. Report for July 1994-May 1997

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cleland, J.; Purvis, C.R.

1998-06-01

The paper discusses a biomass energy conversion project being sponsored by EPA to demonstrate an enviromentally and economically sound electrical power option for government installations, industrial sites, rural cooperatives, small municipalities, and developing countries. Wood gasification combined with internal combustion engines was chosen because of (1) recent improvements in gas cleaning, (2) simple economical operation for units < 10 MW, and (3) the option of a clean cheap fuel for the many existing facilities generating expensive electricity from petroleum fuels with reciprocating engines. The plant incorporates a downdraft, moving-bed gasifier utilizing hogged waste wood from the Marine Corps Base atmore » Camp Lejeune, NC. A moving-bed bulk wood dryer and both spark ignition and diesel engines are included. Unique process design features are described briefly, relative to the gasifier, wood drying, tar separation, and process control. A test plan for process optimization and demonstration of reliability, economics, and environmental impact is outlined.« less

Managing Ammonia Emissions From Screwworm Larval Rearing Media.

PubMed

Sagel, Agustin; Phillips, Pamela; Chaudhury, Muhammad; Skoda, Steven

2016-02-01

Mass production, sterilization, and release of screwworms (Cochliomyia hominivorax (Coquerel)) that were competitive in the field significantly contributed to the successful application of the sterile insect technique for eradication of screwworms from continental North America. Metabolic byproducts resulting from protein-rich diets required for larval screwworms lead to ammonia liberation, sometimes at high levels, within the mass rearing facility. Until recently a sodium polyacrylate gel bulking agent was used for the larval media and adsorbed much of the ammonia. A need to replace the gel with an environmentally "friendly" bulking agent, while not increasing ammonia levels in the rearing facility, led to a series of experiments with the objective of developing procedures to reduce ammonia emissions from the larval media bulked with cellulose fiber. Additives of ammonia-converting bacteria, potassium permanganate, and Yucca schidigera Roezl ex Otrgies powder extract, previously reported to reduce ammonia levels in organic environments, were evaluated. Ammonia-converting bacteria did not have a positive effect. Addition of Y. schidigera powder extract (∼1% of total volume), potassium permanganate (∼250 ppm), and a combination of these two additives (at these same concentrations) kept ammonia at equivalent levels as when larval media was bulked with gel. Potassium permanganate also had sufficient antimicrobial properties that the use of formaldehyde in the diet was not necessary. Further testing is needed, at a mass rearing level, before full implementation into the screwworm eradication program. Published by Oxford University Press on behalf of Entomological Society of America 2015. This work is written by US Government employees and is in the public domain in the US.

Resuspension of soil as a source of airborne lead near industrial facilities and highways.

PubMed

Young, Thomas M; Heeraman, Deo A; Sirin, Gorkem; Ashbaugh, Lowell L

2002-06-01

Geologic materials are an important source of airborne particulate matter less than 10 microm aerodynamic diameter (PM10), but the contribution of contaminated soil to concentrations of Pb and other trace elements in air has not been documented. To examine the potential significance of this mechanism, surface soil samples with a range of bulk soil Pb concentrations were obtained near five industrial facilities and along roadsides and were resuspended in a specially designed laboratory chamber. The concentration of Pb and other trace elements was measured in the bulk soil, in soil size fractions, and in PM10 generated during resuspension of soils and fractions. Average yields of PM10 from dry soils ranged from 0.169 to 0.869 mg of PM10/g of soil. Yields declined approximately linearly with increasing geometric mean particle size of the bulk soil. The resulting PM10 had average Pb concentrations as high as 2283 mg/kg for samples from a secondary Pb smelter. Pb was enriched in PM10 by 5.36-88.7 times as compared with uncontaminated California soils. Total production of PM10 bound Pb from the soil samples varied between 0.012 and 1.2 mg of Pb/kg of bulk soil. During a relatively large erosion event, a contaminated site might contribute approximately 300 ng/m3 of PM10-bound Pb to air. Contribution of soil from contaminated sites to airborne element balances thus deserves consideration when constructing receptor models for source apportionment or attempting to control airborne Pb emissions.

Temporal Geophysical Signatures Due to Contaminant Mass Remediation

EPA Science Inventory

Geophysical surveys acquired over a ten year period are used to document changes in bulk electrical conductivity associated with the attenuation of hydrocarbon contaminants at the former fire training facility (FT-02) Wurtsmith Air Force base (WAFB), Oscoda, MI, USA. Initial inv...

BIOREMEDIATION FIELD INITIATIVE SITE PROFILE: ESCAMBIA WOOD PRESERVING SITE - BROOKHAVEN

EPA Science Inventory

The Escambia Wood Preserving Site—Brookhaven in Brookhaven, Mississippi, is a former wood preserving facility that used pentachlo- rophenol (PCP) and creosote to treat wooden poles. The site contains two pressure treatment cylinders, a wastewater treatment system, five bulk pr...

40 CFR 98.306 - Data reporting requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) Pounds of SF6 and PFC returned to facility after off-site recycling. (i) Pounds of SF6 and PFC in bulk...) Pounds of SF6 and PFC sent off-site for recycling. (l) Pounds of SF6 and PFC sent off-site for...

40 CFR 98.306 - Data reporting requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

...) Pounds of SF6 and PFC returned to facility after off-site recycling. (i) Pounds of SF6 and PFC in bulk...) Pounds of SF6 and PFC sent off-site for recycling. (l) Pounds of SF6 and PFC sent off-site for...

40 CFR 98.306 - Data reporting requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) Pounds of SF6 and PFC returned to facility after off-site recycling. (i) Pounds of SF6 and PFC in bulk...) Pounds of SF6 and PFC sent off-site for recycling. (l) Pounds of SF6 and PFC sent off-site for...

40 CFR 98.306 - Data reporting requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) Pounds of SF6 and PFC returned to facility after off-site recycling. (i) Pounds of SF6 and PFC in bulk...) Pounds of SF6 and PFC sent off-site for recycling. (l) Pounds of SF6 and PFC sent off-site for...

18 CFR 39.1 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-04-01

... Mexico. Cybersecurity Incident means a malicious act or suspicious event that disrupts, or was an attempt... includes requirements for the operation of existing Bulk-Power System facilities, including cybersecurity... failures of such system will not occur as a result of a sudden disturbance, including a Cybersecurity...

18 CFR 39.1 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-04-01

... Mexico. Cybersecurity Incident means a malicious act or suspicious event that disrupts, or was an attempt... includes requirements for the operation of existing Bulk-Power System facilities, including cybersecurity... failures of such system will not occur as a result of a sudden disturbance, including a Cybersecurity...

18 CFR 39.1 - Definitions.

Code of Federal Regulations, 2013 CFR

2013-04-01

... Mexico. Cybersecurity Incident means a malicious act or suspicious event that disrupts, or was an attempt... includes requirements for the operation of existing Bulk-Power System facilities, including cybersecurity... failures of such system will not occur as a result of a sudden disturbance, including a Cybersecurity...

18 CFR 39.1 - Definitions.

Code of Federal Regulations, 2014 CFR

2014-04-01

... Mexico. Cybersecurity Incident means a malicious act or suspicious event that disrupts, or was an attempt... includes requirements for the operation of existing Bulk-Power System facilities, including cybersecurity... failures of such system will not occur as a result of a sudden disturbance, including a Cybersecurity...

18 CFR 39.1 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-04-01

... Mexico. Cybersecurity Incident means a malicious act or suspicious event that disrupts, or was an attempt... includes requirements for the operation of existing Bulk-Power System facilities, including cybersecurity... failures of such system will not occur as a result of a sudden disturbance, including a Cybersecurity...

40 CFR 442.1 - General applicability.

Code of Federal Regulations, 2010 CFR

2010-07-01

... under a wide variety of Standard Industrial Classification (SIC) codes. Several of the most common SIC... industrial, commercial, or Publicly Owned Treatment Works (POTW) operations, provided that the cleaning is... drums, intermediate bulk containers, or closed-top hoppers. (3) Wastewater from a facility that...

Global Petroleum Corporation (MA0003425) | NPDES | New ...

EPA Pesticide Factsheets

2017-04-10

EPA and the Massachusetts Department of Environmental Protection (MADEP) have developed final National Pollutant Discharge Elimination System (NPDES) permits for seven bulk petroleum storage facilities located along Chelsea River (Creek) in Chelsea and Revere, Massachusetts to meet the requirements of the Clean Water Act.

Chelsea Sandwich, LLC (MA0003280) | Chelsea Creek ...

EPA Pesticide Factsheets

2017-04-10

EPA and the Massachusetts Department of Environmental Protection (MADEP) have developed final National Pollutant Discharge Elimination System (NPDES) permits for seven bulk petroleum storage facilities located along Chelsea River (Creek) in Chelsea and Revere, Massachusetts to meet the requirements of the Clean Water Act.

Intrinsic white-light emission from layered hybrid perovskites.

PubMed

Dohner, Emma R; Jaffe, Adam; Bradshaw, Liam R; Karunadasa, Hemamala I

2014-09-24

We report on the second family of layered perovskite white-light emitters with improved photoluminescence quantum efficiencies (PLQEs). Upon near-ultraviolet excitation, two new Pb-Cl and Pb-Br perovskites emit broadband "cold" and "warm" white light, respectively, with high color rendition. Emission from large, single crystals indicates an origin from the bulk material and not surface defect sites. The Pb-Br perovskite has a PLQE of 9%, which is undiminished after 3 months of continuous irradiation. Our mechanistic studies indicate that the emission has contributions from strong electron-phonon coupling in a deformable lattice and from a distribution of intrinsic trap states. These hybrids provide a tunable platform for combining the facile processability of organic materials with the structural definition of crystalline, inorganic solids.

A novel broadband impedance method for detection of cell-derived microparticles

PubMed Central

Lvovich, Vadim; Srikanthan, Sowmya; Silverstein, Roy L.

2010-01-01

A novel label-free method is presented to detect and quantify cell-derived microparticles (MPs) by the electrochemical potential-modulated electrochemical impedance spectroscopy (EIS). MPs are present in elevated concentrations during pathological conditions and play a major role in the establishment and pathogenesis of many diseases. Considering this, accurate detection and quantification of MPs is very important in clinical diagnostics and therapeutics. A combination of bulk solution electrokinetic sorting and interfacial impedance responses allows achieving detection limits as low as several MPs per µL. By fitting resulting EIS spectra with an equivalent electrical circuit, the bulk solution electrokinetic and interfacial impedance responses were characterized. In the bulk solution two major relaxations were prominent - β-relaxation in low MHz region due to the MP capacitive membrane bridging, and α-relaxation at ∼ 10 kHz due to counter ions diffusion. At low frequencies (10-0.1 Hz) at electrochemical potentials exceeding −100 mV, a facile interfacial Faradaic process of oxidation in MPs coupled with diffusion and non Faradaic double layer charging dominate, probably due to oxidation of phospholipids and/or proteins on the MP surface and MP lysis. Buffer influence on the MP detection demonstrated that that a relatively low conductivity Tyrode’s buffer background solution is preferential for the MP electrokinetic separation and characterization. This study also demonstrated that standard laboratory methods such as flow cytometry underestimate MP concentrations, especially those with smaller average sizes, by as much as a factor of 2 to 40. PMID:20729061

Low temperature reduction of free-standing graphene oxide papers with metal iodides for ultrahigh bulk conductivity.

PubMed

Liu, Chenyang; Hao, Feng; Zhao, Xiaochong; Zhao, Qiancheng; Luo, Songping; Lin, Hong

2014-02-05

Here we report a green and facile route for highly efficient reduction of free-standing graphene oxide (GO) papers with metal iodide aqueous solutions at low cost. The metal iodides (MgI2, AlI3, ZnI2, FeI2) were synthesized directly from metal and iodine powder with water as a catalyzer. An extremely high bulk conductivity of 55088 S/m for reduced graphene oxide (rGO) papers were obtained with FeI2 solution of which pH = 0 at 95°C for 6 hours. The catalytic effect of strong Lewis acid for the promotion of the nucleophilic substitution reaction is responsible for the greatly improved bulk conductivity. Furthermore, it was found that the layer-to-layer distance (dL) and the crystallinity of the rGO papers are regarded as two main factors affecting the bulk conductivity rather than C/O ratio and defect concentration.

Investigation of microstructure in additive manufactured Inconel 625 by spatially resolved neutron transmission spectroscopy

DOE PAGES

Tremsin, Anton S.; Gao, Yan; Dial, Laura C.; ...

2016-07-08

Non-destructive testing techniques based on neutron imaging and diffraction can provide information on the internal structure of relatively thick metal samples (up to several cm), which are opaque to other conventional non-destructive methods. Spatially resolved neutron transmission spectroscopy is an extension of traditional neutron radiography, where multiple images are acquired simultaneously, each corresponding to a narrow range of energy. The analysis of transmission spectra enables studies of bulk microstructures at the spatial resolution comparable to the detector pixel. In this study we demonstrate the possibility of imaging (with ~100 μm resolution) distribution of some microstructure properties, such as residual strain,more » texture, voids and impurities in Inconel 625 samples manufactured with an additive manufacturing method called direct metal laser melting (DMLM). Although this imaging technique can be implemented only in a few large-scale facilities, it can be a valuable tool for optimization of additive manufacturing techniques and materials and for correlating bulk microstructure properties to manufacturing process parameters. Additionally, the experimental strain distribution can help validate finite element models which many industries use to predict the residual stress distributions in additive manufactured components.« less

Investigation of microstructure in additive manufactured Inconel 625 by spatially resolved neutron transmission spectroscopy.

PubMed

Tremsin, Anton S; Gao, Yan; Dial, Laura C; Grazzi, Francesco; Shinohara, Takenao

2016-01-01

Non-destructive testing techniques based on neutron imaging and diffraction can provide information on the internal structure of relatively thick metal samples (up to several cm), which are opaque to other conventional non-destructive methods. Spatially resolved neutron transmission spectroscopy is an extension of traditional neutron radiography, where multiple images are acquired simultaneously, each corresponding to a narrow range of energy. The analysis of transmission spectra enables studies of bulk microstructures at the spatial resolution comparable to the detector pixel. In this study we demonstrate the possibility of imaging (with ~100 μm resolution) distribution of some microstructure properties, such as residual strain, texture, voids and impurities in Inconel 625 samples manufactured with an additive manufacturing method called direct metal laser melting (DMLM). Although this imaging technique can be implemented only in a few large-scale facilities, it can be a valuable tool for optimization of additive manufacturing techniques and materials and for correlating bulk microstructure properties to manufacturing process parameters. In addition, the experimental strain distribution can help validate finite element models which many industries use to predict the residual stress distributions in additive manufactured components.

Investigation of microstructure in additive manufactured Inconel 625 by spatially resolved neutron transmission spectroscopy

NASA Astrophysics Data System (ADS)

Tremsin, Anton S.; Gao, Yan; Dial, Laura C.; Grazzi, Francesco; Shinohara, Takenao

2016-01-01

Non-destructive testing techniques based on neutron imaging and diffraction can provide information on the internal structure of relatively thick metal samples (up to several cm), which are opaque to other conventional non-destructive methods. Spatially resolved neutron transmission spectroscopy is an extension of traditional neutron radiography, where multiple images are acquired simultaneously, each corresponding to a narrow range of energy. The analysis of transmission spectra enables studies of bulk microstructures at the spatial resolution comparable to the detector pixel. In this study we demonstrate the possibility of imaging (with 100 μm resolution) distribution of some microstructure properties, such as residual strain, texture, voids and impurities in Inconel 625 samples manufactured with an additive manufacturing method called direct metal laser melting (DMLM). Although this imaging technique can be implemented only in a few large-scale facilities, it can be a valuable tool for optimization of additive manufacturing techniques and materials and for correlating bulk microstructure properties to manufacturing process parameters. In addition, the experimental strain distribution can help validate finite element models which many industries use to predict the residual stress distributions in additive manufactured components.

Investigation of microstructure in additive manufactured Inconel 625 by spatially resolved neutron transmission spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tremsin, Anton S.; Gao, Yan; Dial, Laura C.

Non-destructive testing techniques based on neutron imaging and diffraction can provide information on the internal structure of relatively thick metal samples (up to several cm), which are opaque to other conventional non-destructive methods. Spatially resolved neutron transmission spectroscopy is an extension of traditional neutron radiography, where multiple images are acquired simultaneously, each corresponding to a narrow range of energy. The analysis of transmission spectra enables studies of bulk microstructures at the spatial resolution comparable to the detector pixel. In this study we demonstrate the possibility of imaging (with ~100 μm resolution) distribution of some microstructure properties, such as residual strain,more » texture, voids and impurities in Inconel 625 samples manufactured with an additive manufacturing method called direct metal laser melting (DMLM). Although this imaging technique can be implemented only in a few large-scale facilities, it can be a valuable tool for optimization of additive manufacturing techniques and materials and for correlating bulk microstructure properties to manufacturing process parameters. Additionally, the experimental strain distribution can help validate finite element models which many industries use to predict the residual stress distributions in additive manufactured components.« less

Investigation of microstructure in additive manufactured Inconel 625 by spatially resolved neutron transmission spectroscopy

PubMed Central

Tremsin, Anton S.; Gao, Yan; Dial, Laura C.; Grazzi, Francesco; Shinohara, Takenao

2016-01-01

Abstract Non-destructive testing techniques based on neutron imaging and diffraction can provide information on the internal structure of relatively thick metal samples (up to several cm), which are opaque to other conventional non-destructive methods. Spatially resolved neutron transmission spectroscopy is an extension of traditional neutron radiography, where multiple images are acquired simultaneously, each corresponding to a narrow range of energy. The analysis of transmission spectra enables studies of bulk microstructures at the spatial resolution comparable to the detector pixel. In this study we demonstrate the possibility of imaging (with ~100 μm resolution) distribution of some microstructure properties, such as residual strain, texture, voids and impurities in Inconel 625 samples manufactured with an additive manufacturing method called direct metal laser melting (DMLM). Although this imaging technique can be implemented only in a few large-scale facilities, it can be a valuable tool for optimization of additive manufacturing techniques and materials and for correlating bulk microstructure properties to manufacturing process parameters. In addition, the experimental strain distribution can help validate finite element models which many industries use to predict the residual stress distributions in additive manufactured components. PMID:27877885

33 CFR 154.802 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Vapor Control Systems § 154.802 Definitions. As used in this subpart: Certifying entity means an individual or organization accepted by the Commandant (CG-522) to review plans and calculations for vapor control system designs, and to conduct initial...

33 CFR 154.802 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Vapor Control Systems § 154.802 Definitions. As used in this subpart: Certifying entity means an individual or organization accepted by the Commandant (CG-522) to review plans and calculations for vapor control system designs, and to conduct initial...

33 CFR 154.1125 - Additional response plan requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Additional response plan... SECURITY (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Additional... Prince William Sound, Alaska § 154.1125 Additional response plan requirements. (a) The owner or operator...

33 CFR 154.300 - Operations manual: General.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Operations manual: General. 154.300 Section 154.300 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Operations Manual § 154.300...

33 CFR 154.300 - Operations manual: General.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Operations manual: General. 154.300 Section 154.300 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Operations Manual § 154.300...

"Wrapping Up" Your Construction Insurance.

ERIC Educational Resources Information Center

Ferraro, Mark

1998-01-01

School facility managers are beginning to use a special insurance-management technique called wrap-up. The project owner purchases a bulk construction insurance policy consisting of general liability, excess liability, workers' compensation, and builders' risk insurance. Wrap-ups ensure competitive pricing, safety incentives, lower claims costs,…

Gulf Oil Limited Partnership (MA0001091) | Chelsea Creek ...

EPA Pesticide Factsheets

2017-04-10

EPA and the Massachusetts Department of Environmental Protection (MADEP) have developed final National Pollutant Discharge Elimination System (NPDES) permits for seven bulk petroleum storage facilities located along Chelsea River (Creek) in Chelsea and Revere, Massachusetts to meet the requirements of the Clean Water Act.

Coastal Oil of New England, Inc. - Chelsea Terminal ...

EPA Pesticide Factsheets

2017-04-10

EPA and the Massachusetts Department of Environmental Protection (MADEP) have developed final National Pollutant Discharge Elimination System (NPDES) permits for seven bulk petroleum storage facilities located along Chelsea River (Creek) in Chelsea and Revere, Massachusetts to meet the requirements of the Clean Water Act.

Global South Terminal, LLC (MA0000825) | Chelsea Creek ...

EPA Pesticide Factsheets

2017-04-10

EPA and the Massachusetts Department of Environmental Protection (MADEP) have developed final National Pollutant Discharge Elimination System (NPDES) permits for seven bulk petroleum storage facilities located along Chelsea River (Creek) in Chelsea and Revere, Massachusetts to meet the requirements of the Clean Water Act.

Global REVCO Terminal, LLC (MA0003298) | Chelsea Creek ...

EPA Pesticide Factsheets

2017-04-10

EPA and the Massachusetts Department of Environmental Protection (MADEP) have developed final National Pollutant Discharge Elimination System (NPDES) permits for seven bulk petroleum storage facilities located along Chelsea River (Creek) in Chelsea and Revere, Massachusetts to meet the requirements of the Clean Water Act.

Irving Oil Terminal - Revere (MA0001929) | Chelsea Creek ...

EPA Pesticide Factsheets

2017-04-10

EPA and the Massachusetts Department of Environmental Protection (MADEP) have developed final National Pollutant Discharge Elimination System (NPDES) permits for seven bulk petroleum storage facilities located along Chelsea River (Creek) in Chelsea and Revere, Massachusetts to meet the requirements of the Clean Water Act.

POLLUTION PREVENTION OPPORTUNITY ASSESSMENT - U.S. POSTAL SERVICE BULK MAIL CENTER, DALLAS, TEXAS

EPA Science Inventory

The United States Postal Service (USPS) in cooperation with EPA’s National Risk Management Research Laboratory (NRMRL) is engaged in an effort to integrate waste prevention and recycling activities into the waste management programs at Postal facilities. This report describ...

Safeguardability of the vitrification option for disposal of plutonium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pillay, K.K.S.

1996-05-01

Safeguardability of the vitrification option for plutonium disposition is rather complex and there is no experience base in either domestic or international safeguards for this approach. In the present treaty regime between the US and the states of the former Soviet Union, bilaterial verifications are considered more likely with potential for a third-party verification of safeguards. There are serious technological limitations to applying conventional bulk handling facility safeguards techniques to achieve independent verification of plutonium in borosilicate glass. If vitrification is the final disposition option chosen, maintaining continuity of knowledge of plutonium in glass matrices, especially those containing boron andmore » those spike with high-level wastes or {sup 137}Cs, is beyond the capability of present-day safeguards technologies and nondestructive assay techniques. The alternative to quantitative measurement of fissile content is to maintain continuity of knowledge through a combination of containment and surveillance, which is not the international norm for bulk handling facilities.« less

Facile, Low-Cost, UV-Curing Approach to Prepare Highly Conductive Composites for Flexible Electronics Applications

NASA Astrophysics Data System (ADS)

Li, Fucheng; Chen, Shilong; Wei, Yong; Liu, Konghua; Lin, Yong; Liu, Lan

2016-07-01

We present a facile approach to prepare high-performance ultraviolet (UV)-curable polyurethane-acrylate-based flexible electrical conductive adhesive (PUA-FECA) for flexible electronics applications. PUA is employed as the polymer matrix so that the ECA is flexible and UV-curable at room temperature in just a few minutes. The effects of the PUA-FECA formulation and curing procedure on the electrical properties have been studied. Very low volume resistivity (5.08 × 10-4 Ω cm) is obtained by incorporating 70 wt.% microsized Ag-coated Cu flakes. Moreover, by simply standing the PUA-FECA paste for 4 h before exposure to UV light, the bulk resistivity of the PUA-FECA is dramatically decreased to 3.62 × 10-4 Ω cm. This can be attributed to rearrangement of Ag-coated Cu flakes in the matrix while standing. PUA-FECA also presents stable electrical conductivity during rolling and compression, excellent adhesion, and good processability, making it easily scalable to large-scale fabrication and enabling screen-printing on various low-cost flexible substrates such as office paper and polyethylene terephthalate film.

Lessons from Iowa : development of a 270 megawatt compressed air energy storage project in midwest Independent System Operator : a study for the DOE Energy Storage Systems Program.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Holst, Kent; Huff, Georgianne; Schulte, Robert H.

2012-01-01

The Iowa Stored Energy Park was an innovative, 270 Megawatt, $400 million compressed air energy storage (CAES) project proposed for in-service near Des Moines, Iowa, in 2015. After eight years in development the project was terminated because of site geological limitations. However, much was learned in the development process regarding what it takes to do a utility-scale, bulk energy storage facility and coordinate it with regional renewable wind energy resources in an Independent System Operator (ISO) marketplace. Lessons include the costs and long-term economics of a CAES facility compared to conventional natural gas-fired generation alternatives; market, legislative, and contract issuesmore » related to enabling energy storage in an ISO market; the importance of due diligence in project management; and community relations and marketing for siting of large energy projects. Although many of the lessons relate to CAES applications in particular, most of the lessons learned are independent of site location or geology, or even the particular energy storage technology involved.« less

Can a GIS toolbox assess the environmental risk of oil spills? Implementation for oil facilities in harbors.

PubMed

Valdor, Paloma F; Gómez, Aina G; Velarde, Víctor; Puente, Araceli

2016-04-01

Oil spills are one of the most widespread problems in port areas (loading/unloading of bulk liquid, fuel supply). Specific environmental risk analysis procedures for diffuse oil sources that are based on the evolution of oil in the marine environment are needed. Diffuse sources such as oil spills usually present a lack of information, which makes the use of numerical models an arduous and occasionally impossible task. For that reason, a tool that can assess the risk of oil spills in near-shore areas by using Geographical Information System (GIS) is presented. The SPILL Tool provides immediate results by automating the process without miscalculation errors. The tool was developed using the Python and ArcGIS scripting library to build a non-ambiguous geoprocessing workflow. The SPILL Tool was implemented for oil facilities at Tarragona Harbor (NE Spain) and validated showing a satisfactory correspondence (around 0.60 RSR error index) with the results obtained using a 2D calibrated oil transport numerical model. Copyright © 2016 Elsevier Ltd. All rights reserved.

33 CFR 154.510 - Loading arms.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Loading arms. 154.510 Section 154.510 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Equipment Requirements § 154.510 Loading arms. (a...

33 CFR 154.510 - Loading arms.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Loading arms. 154.510 Section 154.510 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Equipment Requirements § 154.510 Loading arms. (a...

46 CFR 153.968 - Cargo transfer conference.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 46 Shipping 5 2010-10-01 2010-10-01 false Cargo transfer conference. 153.968 Section 153.968 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SHIPS... the facility. (b) The person in charge of cargo transfer shall discuss the important aspects of the...

7 CFR 58.131 - Equipment and facilities.

Code of Federal Regulations, 2010 CFR

2010-01-01

... with 3-A Sanitary Standards for Stainless Steel Automotive Milk and Milk Products Transportation Tanks... be stainless steel and so constructed that it will not buckle, sag or prevent complete drainage. All... under sanitary conditions from farm bulk tanks through stainless steel piping or approved tubing. The...

7 CFR 58.131 - Equipment and facilities.

Code of Federal Regulations, 2013 CFR

2013-01-01

... with 3-A Sanitary Standards for Stainless Steel Automotive Milk and Milk Products Transportation Tanks... be stainless steel and so constructed that it will not buckle, sag or prevent complete drainage. All... under sanitary conditions from farm bulk tanks through stainless steel piping or approved tubing. The...

7 CFR 58.131 - Equipment and facilities.

Code of Federal Regulations, 2012 CFR

2012-01-01

... with 3-A Sanitary Standards for Stainless Steel Automotive Milk and Milk Products Transportation Tanks... be stainless steel and so constructed that it will not buckle, sag or prevent complete drainage. All... under sanitary conditions from farm bulk tanks through stainless steel piping or approved tubing. The...

7 CFR 58.131 - Equipment and facilities.

Code of Federal Regulations, 2011 CFR

2011-01-01

... with 3-A Sanitary Standards for Stainless Steel Automotive Milk and Milk Products Transportation Tanks... be stainless steel and so constructed that it will not buckle, sag or prevent complete drainage. All... under sanitary conditions from farm bulk tanks through stainless steel piping or approved tubing. The...

7 CFR 58.131 - Equipment and facilities.

Code of Federal Regulations, 2014 CFR

2014-01-01

... with 3-A Sanitary Standards for Stainless Steel Automotive Milk and Milk Products Transportation Tanks... be stainless steel and so constructed that it will not buckle, sag or prevent complete drainage. All... under sanitary conditions from farm bulk tanks through stainless steel piping or approved tubing. The...

40 CFR 265.1087 - Standards: Containers.

Code of Federal Regulations, 2013 CFR

2013-07-01

... integral part of the container structural design (e.g., a “portable tank” or bulk cargo container equipped... 40 Protection of Environment 27 2013-07-01 2013-07-01 false Standards: Containers. 265.1087... DISPOSAL FACILITIES Air Emission Standards for Tanks, Surface Impoundments, and Containers § 265.1087...

40 CFR 265.1087 - Standards: Containers.

Code of Federal Regulations, 2014 CFR

2014-07-01

... integral part of the container structural design (e.g., a “portable tank” or bulk cargo container equipped... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Standards: Containers. 265.1087... DISPOSAL FACILITIES Air Emission Standards for Tanks, Surface Impoundments, and Containers § 265.1087...

40 CFR 265.1087 - Standards: Containers.

Code of Federal Regulations, 2012 CFR

2012-07-01

... integral part of the container structural design (e.g., a “portable tank” or bulk cargo container equipped... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Standards: Containers. 265.1087... DISPOSAL FACILITIES Air Emission Standards for Tanks, Surface Impoundments, and Containers § 265.1087...

40 CFR 265.1087 - Standards: Containers.

Code of Federal Regulations, 2011 CFR

2011-07-01

... integral part of the container structural design (e.g., a “portable tank” or bulk cargo container equipped... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Standards: Containers. 265.1087... DISPOSAL FACILITIES Air Emission Standards for Tanks, Surface Impoundments, and Containers § 265.1087...

Environmental pollution with antimicrobial agents from bulk drug manufacturing industries in Hyderabad, South India, is associated with dissemination of extended-spectrum beta-lactamase and carbapenemase-producing pathogens.

PubMed

Lübbert, Christoph; Baars, Christian; Dayakar, Anil; Lippmann, Norman; Rodloff, Arne C; Kinzig, Martina; Sörgel, Fritz

2017-08-01

High antibiotic and antifungal concentrations in wastewater from anti-infective drug production may exert selection pressure for multidrug-resistant (MDR) pathogens. We investigated the environmental presence of active pharmaceutical ingredients and their association with MDR Gram-negative bacteria in Hyderabad, South India, a major production area for the global bulk drug market. From Nov 19 to 28, 2016, water samples were collected from the direct environment of bulk drug manufacturing facilities, the vicinity of two sewage treatment plants, the Musi River, and habitats in Hyderabad and nearby villages. Samples were analyzed for 25 anti-infective pharmaceuticals with liquid chromatography-tandem mass spectrometry and for MDR Gram-negative bacteria using chromogenic culture media. In addition, specimens were screened with PCR for bla VIM , bla KPC , bla NDM , bla IMP-1 , and bla OXA-48 resistance genes. All environmental specimens from 28 different sampling sites were contaminated with antimicrobials. High concentrations of moxifloxacin, voriconazole, and fluconazole (up to 694.1, 2500, and 236,950 µg/L, respectively) as well as increased concentrations of eight other antibiotics were found in sewers in the Patancheru-Bollaram industrial area. Corresponding microbiological analyses revealed an extensive presence of extended-spectrum beta-lactamase and carbapenemase-producing Enterobacteriaceae and non-fermenters (carrying mainly bla OXA-48 , bla NDM , and bla KPC ) in more than 95% of the samples. Insufficient wastewater management by bulk drug manufacturing facilities leads to unprecedented contamination of water resources with antimicrobial pharmaceuticals, which seems to be associated with the selection and dissemination of carbapenemase-producing pathogens. The development and global spread of antimicrobial resistance present a major challenge for pharmaceutical producers and regulatory agencies.

Bulk Extractor 1.4 User’s Manual

DTIC Science & Technology

2013-08-01

optimistically decompresses data in ZIP, GZIP, RAR, and Mi- crosoft’s Hibernation files. This has proven useful, for example, in recovering email...command line. Java 7 or above must be installed on the machine for the Bulk Extractor Viewer to run. Instructions on running bulk_extractor from the... Hibernation File Fragments (decompressed and processed, not carved) Subsection 4.6 winprefetch Windows Prefetch files, file fragments (processed

Materials process and applications of single grain (RE)-Ba-Cu-O bulk high-temperature superconductors

NASA Astrophysics Data System (ADS)

Li, Beizhan; Zhou, Difan; Xu, Kun; Hara, Shogo; Tsuzuki, Keita; Miki, Motohiro; Felder, Brice; Deng, Zigang; Izumi, Mitsuru

2012-11-01

This paper reviews recent advances in the melt process of (RE)-Ba-Cu-O [(RE)BCO, where RE represents a rare earth element] single grain high-temperature superconductors (HTSs), bulks and its applications. The efforts on the improvement of the magnetic flux pinning with employing the top-seeded melt-growth process technique and using a seeded infiltration and growth process are discussed. Which including various chemical doping strategies and controlled pushing effect based on the peritectic reaction of (RE)BCO. The typical experiment results, such as the largest single domain bulk, the clear TEM observations and the significant critical current density, are summarized together with the magnetization techniques. Finally, we highlight the recent prominent progress of HTS bulk applications, including Maglev, flywheel, power device, magnetic drug delivery system and magnetic resonance devices.

The role of exciton ionization processes in bulk heterojunction organic photovoltaic cells

NASA Astrophysics Data System (ADS)

Zou, Yunlong; Holmes, Russell

2015-03-01

Dissociating photogenerated excitons into their constituent charges is essential for efficient photoconversion in organic semiconductors. Organic photovoltaics cells (OPV) widely adopt a heterojunction architecture where dissociation is facilitated by charge transfer at a donor-acceptor (D-A) interface. Interestingly, recent work on MoOx/C60 Schottky OPVs has demonstrated that excitons in C60 may also undergo bulk-ionization to generate photocurrent, driven by the built-in field at the MoOx/C60 interface. Here, we show that bulk-ionization processes also contribute to the photocurrent in bulk heterojunction (BHJ) OPVs with fullerene-rich compositions. The short-circuit current density (JSC) in a MoOx/C60 Schottky OPVs shows almost no dependence on temperature down to 80 K. This characteristic of bulk-ionization allows the use of temperature-dependent measurements of JSC to distinguish dissociation by bulk-ionization from charge transfer at a D-A interface. For BHJ OPVs constructed using the D-A pairing of boron subphthalocyanine chloride (SubPc)-C60, bulk-ionization is found to contribute >10% of the total photocurrent and >30% of the photocurrent from C60. We further find that fullerene-rich SubPc-C60 BHJ OPVs show a larger open-circuit voltage (VOC) than evenly mixed BHJs due to the presence of bulk-ionization. This talk will examine the dependence of JSC and VOC on the relative fraction of dissociation by charge transfer and bulk-ionization processes.

An Automated Sample Divider for Farmers Stock Peanuts

USDA-ARS?s Scientific Manuscript database

In-shell peanuts are harvested, loaded into drying trailers, and delivered to a central facility where they are dried to a moisture content safe for long term storage, sampled, graded, then unloaded into bulk storage. Drying trailers have capacities ranging from five to twenty-five tons of dry farme...

An automated sample divider for farmers stock peanuts

USDA-ARS?s Scientific Manuscript database

In-shell peanuts are harvested, loaded into drying trailers, and delivered to a central facility where they are dried to a moisture content safe for long term storage, sampled, graded, then unloaded into bulk storage. Drying trailers have capacities ranging from five to twenty-five tons of dry farme...

40 CFR 265.71 - Use of manifest system.

Code of Federal Regulations, 2010 CFR

2010-07-01

... the manifest; (iv) Within 30 days of delivery, send a copy of the manifest to the generator; and (v... Pennsylvania Avenue, NW., Washington, DC 20460. (b) If a facility receives, from a rail or water (bulk shipment... on the manifest (excluding the EPA identification numbers, generator's certification, and signatures...

Hazardous Waste Management System - Identification and Listing of Hazardous Waste - Toxicity Characteristic - Hydrocarbon Recovery Operations - Federal Register Notice, October 5, 1990

EPA Pesticide Factsheets

The Agency is promulgating an interim final rule to extend the compliance date of the Toxicity Characteristic rule for petroleum refining facilities, marketing terminals and bulk plants engaged in the recovery and remediation operation for 120 days.

33 CFR 154.105 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK General § 154.105 Definitions. As used in this part... equipment in the marine transfer area are completely free of oil or hazardous materials, where these..., used or capable of being used to transfer oil or hazardous materials to or from a vessel or public...

33 CFR 154.105 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK General § 154.105 Definitions. As used in this part... equipment in the marine transfer area are completely free of oil or hazardous materials, where these..., used or capable of being used to transfer oil or hazardous materials to or from a vessel or public...

Alq3 nanorods: promising building blocks for optical devices.

PubMed

Chen, Wei; Peng, Qing; Li, Yadong

2008-07-17

Monodisperse Alq3 nanorods with hexagonal-prism-like morphology are produced via a facile, emulsion based synthesis route. The photoluminescence of individual nanorods differs from the bulk material. These nanorods are promising building blocks for novel optical devices. Copyright © 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Low Energy Building for High Energy People.

ERIC Educational Resources Information Center

American School and University, 1982

1982-01-01

The Huston Huffman Center at the University of Oklahoma's Norman campus has a jogging track as well as facilities for exercise and court games that are fully accessible to the handicapped. The building is set eight feet in the ground both to reduce its bulk and to conserve energy. (Author/MLF)

Short-Term Operations Plan for Collection of Bulk Quantity CBP Liquid in Support of a Pilot-Scale Treatabilty Evaluation with Water Recovery Inc

EPA Pesticide Factsheets

June 3, 2011 work plan for a pilot-scale treatability evaluation with a commercial wastewater treatment facility, Water Recovery Inc. (WRI) located in Jacksonville, Florida. Region ID: 04 DocID: 10749927, DocDate: 06-03-2011

33 CFR 154.510 - Loading arms.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Loading arms. 154.510 Section 154... FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Equipment Requirements § 154.510 Loading arms. (a) Each mechanical loading arm used for transferring oil or hazardous material and placed into service...

33 CFR 154.510 - Loading arms.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Loading arms. 154.510 Section 154... FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Equipment Requirements § 154.510 Loading arms. (a) Each mechanical loading arm used for transferring oil or hazardous material and placed into service...

33 CFR 154.510 - Loading arms.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Loading arms. 154.510 Section 154... FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Equipment Requirements § 154.510 Loading arms. (a) Each mechanical loading arm used for transferring oil or hazardous material and placed into service...

7 CFR 201.33 - Seed in bulk or large quantities; seed for cleaning or processing.

Code of Federal Regulations, 2014 CFR

2014-01-01

... quantities; seed for cleaning or processing. (a) In the case of seed in bulk, the information required under... seeds. (b) Seed consigned to a seed cleaning or processing establishment, for cleaning or processing for... pertaining to such seed show that it is “Seed for processing,” or, if the seed is in containers and in...

7 CFR 201.33 - Seed in bulk or large quantities; seed for cleaning or processing.

Code of Federal Regulations, 2012 CFR

2012-01-01

... quantities; seed for cleaning or processing. (a) In the case of seed in bulk, the information required under... seeds. (b) Seed consigned to a seed cleaning or processing establishment, for cleaning or processing for... pertaining to such seed show that it is “Seed for processing,” or, if the seed is in containers and in...

7 CFR 201.33 - Seed in bulk or large quantities; seed for cleaning or processing.

Code of Federal Regulations, 2011 CFR

2011-01-01

... quantities; seed for cleaning or processing. (a) In the case of seed in bulk, the information required under... seeds. (b) Seed consigned to a seed cleaning or processing establishment, for cleaning or processing for... pertaining to such seed show that it is “Seed for processing,” or, if the seed is in containers and in...

7 CFR 201.33 - Seed in bulk or large quantities; seed for cleaning or processing.

Code of Federal Regulations, 2010 CFR

2010-01-01

... quantities; seed for cleaning or processing. (a) In the case of seed in bulk, the information required under... seeds. (b) Seed consigned to a seed cleaning or processing establishment, for cleaning or processing for... pertaining to such seed show that it is “Seed for processing,” or, if the seed is in containers and in...

7 CFR 201.33 - Seed in bulk or large quantities; seed for cleaning or processing.

Code of Federal Regulations, 2013 CFR

2013-01-01

... quantities; seed for cleaning or processing. (a) In the case of seed in bulk, the information required under... seeds. (b) Seed consigned to a seed cleaning or processing establishment, for cleaning or processing for... pertaining to such seed show that it is “Seed for processing,” or, if the seed is in containers and in...

Fabrication of single domain GdBCO bulk superconductors by a new modified TSIG technique

NASA Astrophysics Data System (ADS)

Yang, W. M.; Zhi, X.; Chen, S. L.; Wang, M.; Li, J. W.; Ma, J.; Chao, X. X.

2014-01-01

Single domain GdBCO bulk superconductors have been fabricated with new and traditional solid phases by a top seeded infiltration and growth (TSIG) process technique. In the conventional TSIG process, three types of powders, such as Gd2BaCuO5, GdBa2Cu3O7-x and Ba3Cu5O8, must be prepared, but in our new modified TSIG technique, only BaCuO2 powders are required during the fabrication of the single domain GdBCO bulk superconductors. The solid phase used in the conventional process is Gd2BaCuO5 instead of the solid phase (Gd2O3 + BaCuO2) utilized in the new process. The liquid phase used in the conventional process is a mixture of (GdBa2Cu3O7-x + Ba3Cu5O8), and the liquid phase in the new process is a mixture of (Gd2O3 + 10BaCuO2 + 6CuO). Single domain GdBCO bulk superconductors have been fabricated with the new solid and liquid phases. The levitation force of the GdBCO bulk samples fabricated by the new solid phase is 28 N, which is slightly higher than that of the samples fabricated using the conventional solid phases (26 N). The microstructure and the levitation force of the samples indicate that this new method can greatly simplify the fabrication process, introduce nanometer-sized flux centers, improve the levitation force and working efficiency, and greatly reduce the cost of fabrication of single domain GdBCO bulk superconductors by the TSIG process.

A Remote Absorption Process for Disposal of Evaporate and Reverse Osmosis Concentrates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brunsell, D.A.

2008-07-01

Many commercial nuclear plants and DOE facilities generate secondary waste streams consisting of evaporator bottoms and reverse osmosis (RO) concentrate. Since liquids are not permitted in disposal facilities, these waste streams must be converted to dry solids, either by evaporation to dried solids or by solidification to liquid-free solids. Evaporation of the liquid wastes reduces their volume, but requires costly energy and capital equipment. In some cases, concentration of the contaminants during drying can cause the waste to exceed Class A waste for nuclear utilities or exceed DOE transuranic limits. This means that disposal costs will be increased, or that,more » when the Barnwell, SC disposal site closes to waste outside of the Atlantic Compact in July 2008, the waste will be precluded from disposal for the foreseeable future). Solidification with cement agents requires less energy and equipment than drying, but results in a volume increase of 50-100%. The doubling or tripling of waste weight, along with the increased volume, sharply increases shipping and disposal costs. Confronted with these unattractive alternatives, Diversified Technologies Services (DTS), in conjunction with selected nuclear utilities and D and D operations at Rocky Flats, undertook an exploratory effort to convert this liquid wastewater to a solid without using cement. This would avoid the bulking effect of cement, and permit the waste to be disposed of the Energy Solutions facility in Utah as well as some DOE facilities. To address the need for an attractive alternative to drying and cement solidification, a test program was developed using a polymer absorbent media to convert the concentrate streams to a liquid-free waste form that meets the waste acceptance criteria of the pertinent burial sites. Two approaches for mixing the polymer with the liquid were tested: mechanical mixing and in-situ incorporation. As part of this test program, a process control program (PCP) was developed that is 100% scalable from a concentrate test sample as small as 50 grams to full-scale processing of 100 cubic foot containers or larger. In summary: The absorption process offers utilities a viable and less costly alternative to on-site drying or solidification of concentrates. The absorption process can be completed by site personnel or by a vendor as a turnkey service. The process is suitable for multiple types of waste, including RO and evaporator concentrates, sludges, and other difficult to process waters and wet solids. (author)« less

Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream

DOEpatents

Kansa, Edward J.; Anderson, Brian L.; Wijesinghe, Ananda M.; Viani, Brian E.

1999-01-01

This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced.

The Portuguese gamma irradiation facility

NASA Astrophysics Data System (ADS)

Mendes, C. M.; Almeida, J. C.; Botelho, M. L.; Cavaco, M. C.; Almeida-Vara, E.; Andrade, M. E.

A Gamma Radiation Facility was built up in the National Laboratory of Industrial Technology and Engineering (LNETI), Lisbon, Portugal. This plant (UTR GAMA-Pi) is a Cobalt-60 dry storage continuous facility with a nominal capacity of 1.5X10 16 Bq. The initial activity is 1.1X10 16 Bq and the troughput capacity 10 3 ton/year for product with a bulk density of 0.2 g/cm 3 treated with a minimum absorbed dose of 25 kGy. Complementary control devices were installed: ventilation system, closed water refrigeration circuit, internal TV system, detection and extinction fire system and emergency power group. It must be emphasized that the best attention was given to the conception and efficiency of the interlock safety systems. This facility will be utilized mainly for radiosterilization of medical articles and decontamination of wine cork stoppers.

Thin Film Approaches to the SRF Cavity Problem Fabrication and Characterization of Superconducting Thin Films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Beringer, Douglas

Superconducting Radio Frequency (SRF) cavities are responsible for the acceleration of charged particles to relativistic velocities in most modern linear accelerators, such as those employed at high-energy research facilities like Thomas Jefferson National Laboratory’s CEBAF and the LHC at CERN. Recognizing SRF as primarily a surface phenomenon enables the possibility of applying thin films to the interior surface of SRF cavities, opening a formidable tool chest of opportunities by combining and designing materials that offer greater performance benefit. Thus, while improvements in radio frequency cavity design and refinements in cavity processing techniques have improved accelerator performance and efficiency – 1.5more » GHz bulk niobium SRF cavities have achieved accelerating gradients in excess of 35 MV/m – there exist fundamental material bounds in bulk superconductors limiting the maximally sustained accelerating field gradient (≈ 45 MV/m for Nb) where inevitable thermodynamic breakdown occurs. With state of the art Nb based cavity design fast approaching these theoretical limits, novel material innovations must be sought in order to realize next generation SRF cavities. One proposed method to improve SRF performance is to utilize thin film superconducting-insulating-superconducting (SIS) multilayer structures to effectively magnetically screen a bulk superconducting layer such that it can operate at higher field gradients before suffering critically detrimental SRF losses. This dissertation focuses on the production and characterization of thin film superconductors for such SIS layers for radio frequency applications. Correlated studies on structure, surface morphology and superconducting properties of epitaxial Nb and MgB2 thin films are presented.« less

A novel broadband impedance method for detection of cell-derived microparticles.

PubMed

Lvovich, Vadim; Srikanthan, Sowmya; Silverstein, Roy L

2010-10-15

A novel label-free method is presented to detect and quantify cell-derived microparticles (MPs) by the electrochemical potential-modulated electrochemical impedance spectroscopy (EIS). MPs are present in elevated concentrations during pathological conditions and play a major role in the establishment and pathogenesis of many diseases. Considering this, accurate detection and quantification of MPs is very important in clinical diagnostics and therapeutics. A combination of bulk solution electrokinetic sorting and interfacial impedance responses allows achieving detection limits as low as several MPs per μL. By fitting resulting EIS spectra with an equivalent electrical circuit, the bulk solution electrokinetic and interfacial impedance responses were characterized. In the bulk solution two major relaxations were prominent-β-relaxation in low MHz region due to the MP capacitive membrane bridging, and α-relaxation at ∼10 kHz due to counter ions diffusion. At low frequencies (10-0.1 Hz) at electrochemical potentials exceeding -100 mV, a facile interfacial Faradaic process of oxidation in MPs coupled with diffusion and non-Faradaic double layer charging dominate, probably due to oxidation of phospholipids and/or proteins on the MP surface and MP lysis. Buffer influence on the MP detection demonstrated that a relatively low conductivity Tyrode's buffer background solution is preferential for the MP electrokinetic separation and characterization. This study also demonstrated that standard laboratory methods such as flow cytometry underestimate MP concentrations, especially those with smaller average sizes, by as much as a factor of 2-40. Copyright © 2010 Elsevier B.V. All rights reserved.

Indications of Bulk-Fluid Motion in Direct-Drive Implosions

NASA Astrophysics Data System (ADS)

Mannion, O. M.; Anderson, K. S.; Forrest, C. J.; Glebov, V. Yu.; Goncharov, V. N.; Knauer, J. P.; Radha, P. B.; Regan, S. P.; Sangster, T. C.; Stoeckl, C.

2017-10-01

The neutron spectrum produced by a burning plasma encodes essential information about the fusion products and serves as an important diagnostic for inertial confinement fusion experiments. At the Omega Laser Facility, neutron time-of-flight measurements are used to interpret the first and second moment of the neutron spectrum. These moments have been shown to be directly related to properties of the plasma, such as bulk fluid motion and apparent ion temperature. New measurement devices allow for unprecedented accuracy in the measurement of these moments and will provide a better understanding of the performance of direct-drive implosions. We present measurements of the first moment of the DT and D2 peaks in DT implosions and show that variations in the first moment indicate bulk fluid motion of the plasma. This material is based upon work supported by the Department of Energy National Nuclear Security Administration under Award Number DE-NA0001944.

Changing the Rules on Fuel Export at Sellafield's First Fuel Storage Pond - 12065

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carlisle, Derek

2012-07-01

The Pile Fuel Storage Pond (PFSP) was built in 1949/50 to receive, store and de-can fuel and isotopes from the Windscale Piles. Following closure of the Piles in 1957, plant operations were scaled down until fuel processing eventually ceased in 1962. The facility has held an inventory of metal fuel both from the Piles and from other programmes since that time. The pond is currently undergoing remediation and removal of the fuel is a key step in that process, unfortunately the fuel export infrastructure on the plant is no longer functional and due to the size and limited lifting capability,more » the plant is not compatible with today's large volume heavy export flasks. The baseline scheme for the plant is to package fuel into a small capacity flask and transfer it to another facility for treatment and repackaging into a flask compatible with other facilities on site. Due to programme priorities the repackaging facility is not available to do this work for several years causing a delay to the work. In an effort accelerate the programme the Metal Fuel Pilot Project (MFPP) was initiated to challenge the norms for fuel transfer and develop a new methodology for transferring the fuel. In developing a transfer scheme the team had to overcome challenges associated with unknown fuel condition, transfers outside of bulk containment, pyro-phoricity and oxidisation hazards as well as developing remote control and recovery systems for equipment not designed for this purpose. A combination of novel engineering and enhanced operational controls were developed which resulted in the successful export of the first fuel to leave the Pile Fuel Storage Pond in over 40 years. The learning from the pilot project is now being considered by the main project team to see how the new methodology can be applied to the full inventory of the pond. (author)« less

27 CFR 19.401 - Inventories of wines and bulk spirits (except in packages) in processing account.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Inventories of wines and... DISTILLED SPIRITS PLANTS Processing Operations Other Than Denaturation and Manufacture of Articles Inventories § 19.401 Inventories of wines and bulk spirits (except in packages) in processing account. Each...

Soft chemical synthesis of silicon nanosheets and their applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nakano, Hideyuki; Ikuno, Takashi

2016-12-15

Two-dimensional silicon nanomaterials are expected to show different properties from those of bulk silicon materials by virtue of surface functionalization and quantum size effects. Since facile fabrication processes of large area silicon nanosheets (SiNSs) are required for practical applications, a development of soft chemical synthesis route without using conventional vacuum processes is a challenging issue. We have recently succeeded to prepare SiNSs with sub-nanometer thicknesses by exfoliating layered silicon compounds, and they are found to be composed of crystalline single-atom-thick silicon layers. In this review, we present the synthesis and modification methods of SiNSs. These SiNSs have atomically flat andmore » smooth surfaces due to dense coverage of organic moieties, and they are easily self-assembled in a concentrated state to form a regularly stacked structure. We have also characterized the electron transport properties and the electronic structures of SiNSs. Finally, the potential applications of these SiNSs and organic modified SiNSs are also reviewed.« less

Atomic oxygen erosion considerations for spacecraft materials selection

NASA Technical Reports Server (NTRS)

Whitaker, Ann F.; Kamenetzky, Rachel R.

1993-01-01

The Long Duration Exposure Facility (LDEF) satellite carried 57 experiments that were designed to define the low-Earth orbit (LEO) space environment and to evaluate the impact of this environment on potential engineering materials and material processes. Deployed by the Shuttle Challenger in April of 1984, LDEF made over 32,000 orbits before being retrieved nearly 6 years later by the Shuttle Columbia in January of 1990. The Solar Array Passive LDEF Experiment (SAMPLE) AO171 contained approximately 300 specimens, representing numerous material classes and material processes. AO171 was located on LDEF in position A8 at a yaw of 38.1 degrees from the ram direction and was subjected to an atomic oxygen (AO) fluence of 6.93 x 10(exp 21) atoms/sq cm. LDEF AO171 data, as well as short-term shuttle data, will be discussed in this paper as it applies to engineering design applications of composites, bulk and thin film polymers, glassy ceramics, thermal control paints, and metals subjected to AO erosion.

Material Science

NASA Image and Video Library

1992-01-22

This metal sample, which is approximately 1 cm in diameter, is typical of the metals that were studied using the German designed electromagnetic containerless processing facility. The series of experiments that use this device is known as TEMPUS which is the acronym that stands for the German Tiegelfreies Elektromanetisches Prozessieren Unter Schwerelosigkeit. Most of the TEMPUS experiments focused on various aspects of undercooling liquid metal and alloys. Undercooling is the process of melting a material and then cooling it to a temperature that is below its normal freezing or solidification point. The TEMPUS experiments that used the metal cages as shown in the photograph, often studied bulk metallic glass, a solid material with no crystalline structures. We study metals and alloys not only to build things in space, but to improve things that are made on Earth. Metals and alloys are everywhere around us; in our automobiles, in the engines of aircraft, in our power-plants, and elsewhere. Despite their presence in everyday life, there are many scientific aspects of metals that we do not understand.

Microscale Patterning of Thermoplastic Polymer Surfaces by Selective Solvent Swelling

PubMed Central

Rahmanian, Omid; Chen, Chien-Fu; DeVoe, Don L.

2012-01-01

A new method for the fabrication of microscale features in thermoplastic substrates is presented. Unlike traditional thermoplastic microfabrication techniques, in which bulk polymer is displaced from the substrate by machining or embossing, a unique process termed orogenic microfabrication has been developed in which selected regions of a thermoplastic surface are raised from the substrate by an irreversible solvent swelling mechanism. The orogenic technique allows thermoplastic surfaces to be patterned using a variety of masking methods, resulting in three-dimensional features that would be difficult to achieve through traditional microfabrication methods. Using cyclic olefin copolymer as a model thermoplastic material, several variations of this process are described to realize growth heights ranging from several nanometers to tens of microns, with patterning techniques include direct photoresist masking, patterned UV/ozone surface passivation, elastomeric stamping, and noncontact spotting. Orogenic microfabrication is also demonstrated by direct inkjet printing as a facile photolithography-free masking method for rapid desktop thermoplastic microfabrication. PMID:22900539

27 CFR 24.300 - General.

Code of Federal Regulations, 2010 CFR

2010-04-01

... record, copy, or reproduce records required by this part and may use any process which accurately... month, bulk wine produced by fermentation, sweetening, blending, amelioration or addition of wine... fermentation, sweetening, blending, amelioration or addition of wine spirits, bulk wine bottled, bulk and...

Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream

DOEpatents

Kansa, E.J.; Anderson, B.L.; Wijesinghe, A.M.; Viani, B.E.

1999-05-25

This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced. 3 figs.

77 FR 75701 - Landisville Railroad, LLC-Operation Exemption-Buckeye East Chicago Railroad LLC

Federal Register 2010, 2011, 2012, 2013, 2014

2012-12-21

... Railroad, LLC--Operation Exemption--Buckeye East Chicago Railroad LLC Landisville Railroad, LLC... operate approximately 7,065 feet (1.34 miles) of track,\\1\\ existing railroad right-of-way, and bulk liquid transloading facilities owned by Buckeye East Chicago Railroad, LLC, a Class III rail carrier, in East Chicago...

7 CFR 70.15 - Equipment and facilities for graders.

Code of Federal Regulations, 2010 CFR

2010-01-01

...) Scales graduated in tenths of a pound or less for weighing carcasses, parts, or products individually in containers up to 100 pounds, and test weights for such scales. (4) Scales graduated in one-pound graduation or less for weighing bulk containers of poultry and test weights for such scales. (b) Furnished...

A Plan for: A Consumer Conference for Older Adults.

ERIC Educational Resources Information Center

Zarakov, Selma

This document provides a step-by-step description of the planning and implementation of a two day consumer concerns conference for older adults held at Palomar Community College (California). The bulk of the document is made up of practical discussions of such planning phases as facility selection and decoration, conference publicity, snack and…

78 FR 54417 - Oil and Gas and Sulphur Operations on the Outer Continental Shelf-Oil and Gas Production Safety...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-09-04

... for subsurface related equipment installed in high safety valves (SSSVs) and pressure high temperature (HPHT) related equipment installed in environments. high pressure high temperature (HPHT) environments... flammable liquids (other than produced hydrocarbons) stored on the facility in containers other than bulk...

Quick-disconnect coupling/filter

NASA Technical Reports Server (NTRS)

Jankowski, F.

1977-01-01

Two-part coupling system for hose lines combines both connection and filter in one fitting. Flared fittings make coupling less prone to leakage, and reduced number of components speeds operation. These features may make coupler useful with liquid-bulk carriers, where materials (e.g., milk, cooking oil, and liquid sugar) must be transferred quickly from vehicle to storage facility.

40 CFR 112.8 - Spill Prevention, Control, and Countermeasure Plan requirements for onshore facilities (excluding...

Code of Federal Regulations, 2012 CFR

2012-07-01

...) Bulk storage containers. (1) Not use a container for the storage of oil unless its material and... of the largest single container and sufficient freeboard to contain precipitation. You must ensure... conditions. (6) Test or inspect each aboveground container for integrity on a regular schedule and whenever...

40 CFR 112.8 - Spill Prevention, Control, and Countermeasure Plan requirements for onshore facilities (excluding...

Code of Federal Regulations, 2013 CFR

2013-07-01

...) Bulk storage containers. (1) Not use a container for the storage of oil unless its material and... of the largest single container and sufficient freeboard to contain precipitation. You must ensure... conditions. (6) Test or inspect each aboveground container for integrity on a regular schedule and whenever...

40 CFR 112.8 - Spill Prevention, Control, and Countermeasure Plan requirements for onshore facilities (excluding...

Code of Federal Regulations, 2014 CFR

2014-07-01

...) Bulk storage containers. (1) Not use a container for the storage of oil unless its material and... of the largest single container and sufficient freeboard to contain precipitation. You must ensure... conditions. (6) Test or inspect each aboveground container for integrity on a regular schedule and whenever...

Material and Device Stability in Perovskite Solar Cells.

PubMed

Kim, Hui-Seon; Seo, Ja-Young; Park, Nam-Gyu

2016-09-22

Organic-inorganic halide perovskite solar cells have attracted great attention because of their superb efficiency reaching 22 % and low-cost, facile fabrication processing. Nevertheless, stability issues in perovskite solar cells seem to block further advancements toward commercialization. Thus, device stability is one of the important topics in perovskite solar cell research. In the beginning, the poor moisture resistivity of the perovskite layer was considered as a main problem that hindered further development of perovskite solar cells, which encouraged engineering of the perovskite or protection of the perovskite by a buffer layer. Soon after, other parameters affecting long-term stability were sequentially found and various attempts have been made to enhance intrinsic and extrinsic stability. Here we review the recent progresses addressing stability issues in perovskite solar cells. In this report, we investigated factors affecting stability from material and device points of view. To gain a better understanding of the stability of the bulk perovskite material, decomposition mechanisms were investigated in relation to moisture, photons, and heat. Stability of full device should also be carefully examined because its stability is dependent not only on bulk perovskite but also on the interfaces and selective contacts. In addition, ion migration and current-voltage hysteresis were found to be closely related to stability. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Volatility and leachability of heavy metals and radionuclides in thermally treated HEPA filter media generated from nuclear facilities.

PubMed

Yoon, In-Ho; Choi, Wang-Kyu; Lee, Suk-Chol; Min, Byung-Youn; Yang, Hee-Chul; Lee, Kune-Woo

2012-06-15

The purpose of the present study was to apply thermal treatments to reduce the volume of HEPA filter media and to investigate the volatility and leachability of heavy metals and radionuclides during thermal treatment. HEPA filter media were transformed to glassy bulk material by thermal treatment at 900°C for 2h. The most abundant heavy metal in the HEPA filter media was Zn, followed by Sr, Pb and Cr, and the main radionuclide was Cs-137. The volatility tests showed that the heavy metals and radionuclides in radioactive HEPA filter media were not volatilized during the thermal treatment. PCT tests indicated that the leachability of heavy metals and radionuclides was relatively low compared to those of other glasses. XRD results showed that Zn and Cs reacted with HEPA filter media and were transformed into crystalline willemite (ZnO·SiO(2)) and pollucite (Cs(2)OAl(2)O(3)4SiO(2)), which are not volatile or leachable. The proposed technique for the volume reduction and transformation of radioactive HEPA filter media into glassy bulk material is a simple and energy efficient procedure without additives that can be performed at relatively low temperature compared with conventional vitrification process. Copyright © 2012 Elsevier B.V. All rights reserved.

Present Status and Future Prospects in Bulk Processing of HIGH-Tc Superconductors

NASA Astrophysics Data System (ADS)

Jin, S.; Chu, C. W.

The following sections are included: * INTRODUCTION * HIGH SUPERCONDUCTING TRANSITION TEMPERATURE * HIGH CRITICAL CURRENT DENSITY * Grain Boundary Weak Links * Nature of Weak Links * Possible Processing Approaches for Weak Link Problem * Processing Techniques for Texture Formation * Flux Creep in HTSC * Desirable Pinning Defects * Processing for Flux Pinning Enhancement * PROSPECTS FOR BULK APPLICATIONS * Magnetic Field Gener * Energy Storage * Magnetic Shielding * Other Applications * CONCLUDING REMARKS * ACKNOWLEDGMENT * REFERENCES

40 CFR 761.340 - Applicability.

Code of Federal Regulations, 2011 CFR

2011-07-01

... leaching characteristics for storage or disposal. (a) Existing accumulations of non-liquid, non-metal PCB bulk product waste. (b) Non-liquid, non-metal PCB bulk product waste from processes that continuously generate new waste. (c) Non-liquid PCB remediation waste from processes that continuously generate new...

Seals Research at Texas A/M University

NASA Technical Reports Server (NTRS)

Morrison, Gerald L.

1991-01-01

The Turbomachinery Laboratory at Texas A&M has been providing experimental data and computational codes for the design seals for many years. The program began with the development of a Halon based seal test rig. This facility provided information about the effective stiffness and damping in whirling seals. The Halon effectively simulated cryogenic fluids. Another test facility was developed (using air as the working fluid) where the stiffness and damping matrices can be determined. This data was used to develop bulk flow models of the seal's effect upon rotating machinery; in conjunction with this research, a bulk flow model for calculation of performance and rotordynamic coefficients of annular pressure seals of arbitrary non-uniform clearance for barotropic fluids such as LH2, LOX, LN2, and CH4 was developed. This program is very efficient (fast) and converges for very large eccentricities. Currently, work is being performed on a bulk flow analysis of the effects of the impeller-shroud interaction upon the stability of pumps. The data was used along with data from other researchers to develop an empirical leakage prediction code for MSFC. Presently, the flow field inside labyrinth and annular seals are being studied in detail. An advanced 3-D Doppler anemometer system is being used to measure the mean velocity and entire Reynolds stress tensor distribution throughout the seals. Concentric and statically eccentric seals were studied; presently, whirling seals are being studied. The data obtained are providing valuable information about the flow phenomena occurring inside the seals, as well as a data base for comparison with numerical predictions and for turbulence model development. A finite difference computer code was developed for solving the Reynolds averaged Navier Stokes equation inside labyrinth seals. A multi-scale k-epsilon turbulence model is currently being evaluated. A new seal geometry was designed and patented using a computer code. A large scale, 2-D seal flow visualization facility is also being developed.

EPA Enforcement and Compliance History Online

EPA Pesticide Factsheets

The Environmental Protection Agency's Enforcement and Compliance History Online (ECHO) website provides customizable and downloadable information about environmental inspections, violations, and enforcement actions for EPA-regulated facilities related to the Clean Air Act, Clean Water Act, Resource Conservation and Recovery Act, and Safe Drinking Water Act. These data are updated weekly as part of the ECHO data refresh, and ECHO offers many user-friendly options to explore data, including:? Facility Search: ECHO information is searchable by varied criteria, including location, facility type, and compliance status. Search results are customizable and downloadable.? Comparative Maps and State Dashboards: These tools offer aggregated information about facility compliance status, regulatory agency compliance monitoring, and enforcement activity at the national and state level.? Bulk Data Downloads: One of ECHO??s most popular features is the ability to work offline by downloading large data sets. Users can take advantage of the ECHO Exporter, which provides summary information about each facility in comma-separated values (csv) file format, or download data sets by program as zip files.

Production Guides for Vegetable Entrees, Soups, Desserts, Pastries and Salads Developed for Use in Central Food Preparation Facilities. Fort Lee, Interim Facility

DTIC Science & Technology

1974-09-01

mately l£ hours or until double in bulk. After fermentation, turn out dough onto a floured table. Divide and make up as desired. Cookies 1. When... cookies can be deposited on sheet pans by pastry bag. If a cookie depositer is used, the stiffness of the dough can be controlled by adjusting the...10 pieces, each weighing about 1 lb (1*53-6 g). Form each piece into a roll and cut into 20 slices. 3. Place cookie dough in rows 5 x 7 on greased

Laboratory Testing of Bulk Vitrified Low-Activity Waste Forms to Support the 2005 Integrated Disposal Facility Performance Assessment. Erratum

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, Gary L.

2016-09-06

This report refers to or contains K g values for glasses LAWA44, LAWB45 and LAWC22 affected by calculations errors as identified by Papathanassiu et al. (2011). The corrected K g values are reported in an erratum included in the revised version of the original report. The revised report can be referenced as follows: Pierce E. M. et al. (2004) Waste Form Release Data Package for the 2005 Integrated Disposal Facility Performance Assessment. PNNL-14805 Rev. 0 Erratum. Pacific Northwest National Laboratory, Richland, WA, USA.

Simulation of Containment Atmosphere Mixing and Stratification Experiment in the ThAI Facility with a CFD Code

DOE Office of Scientific and Technical Information (OSTI.GOV)

Babic, Miroslav; Kljenak, Ivo; Mavko, Borut

2006-07-01

The CFD code CFX4.4 was used to simulate an experiment in the ThAI facility, which was designed for investigation of thermal-hydraulic processes during a severe accident inside a Light Water Reactor containment. In the considered experiment, air was initially present in the vessel, and helium and steam were injected during different phases of the experiment at various mass flow rates and at different locations. The main purpose of the proposed work was to assess the capabilities of the CFD code to reproduce the atmosphere structure with a three-dimensional model, coupled with condensation models proposed by the authors. A three-dimensional modelmore » of the ThAI vessel for the CFX4.4 code was developed. The flow in the simulation domain was modeled as single-phase. Steam condensation on vessel walls was modeled as a sink of mass and energy using a correlation that was originally developed for an integral approach. A simple model of bulk phase change was also included. Calculated time-dependent variables together with temperature and volume fraction distributions at the end of different experiment phases are compared to experimental results. (authors)« less

Intellectual system of identification of Arabic graphics

NASA Astrophysics Data System (ADS)

Abdoullayeva, Gulchin G.; Aliyev, Telman A.; Gurbanova, Nazakat G.

2001-08-01

The studies made by using the domain of graphic images allowed creating facilities of the artificial intelligence for letters, letter combinations etc. for various graphics and prints. The work proposes a system of recognition and identification of symbols of the Arabic graphics, which has its own specificity as compared to Latin and Cyrillic ones. The starting stage of the recognition and the identification is coding with further entry of information into a computer. Here the problem of entry is one of the essentials. For entry of a large volume of information in the unit of time a scanner is usually employed. Along with the scanner the authors suggest their elaboration of technical facilities for effective input and coding of the information. For refinement of symbols not identified from the scanner mostly for a small bulk of information the developed coding devices are used directly in the process of writing. The functional design of the software is elaborated on the basis of the heuristic model of the creative activity of a researcher and experts in the description and estimation of states of the weakly formalizable systems on the strength of the methods of identification and of selection of geometric features.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Osmanlioglu, Ahmet Erdal

Available in abstract form only. Full text of publication follows: Naturally occurring radioactive material (NORM) in concentrated forms arises both in industry and in nature where natural radioisotopes accumulate at particular sites. Technically enhanced naturally occurring radioactive materials (TE-NORM) often occurs in an acidic environment where precipitates containing radionuclides plate out onto pipe walls, filters, tank linings, etc. Because of the radionuclides are selectively deposited at these sites, radioactivity concentration is extremely higher than the natural concentration. This paper presents characterization and related considerations of TE-NORM wastes in Turkey. Generally, accumulation conditions tend to favour the build-up of radium. Asmore » radium is highly radio-toxic, handling, treatment, storage and disposal of such material requires careful management. Turkey has the only low level waste processing and storage facility (WPSF) in Istanbul. This facility has interim storage buildings and storage area for storage of packaged radioactive waste which are containing artificial radioisotopes, but there is an increasing demand for the storage to accept bulk concentrated TE-NORM wastes from iron-steel and related industries. Most of these wastes generated from scrap metal piles which are imported from other countries. These wastes generally contain radium. (authors)« less

Centralized treatment of industrial wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saltzberg, E.R.

1982-08-01

A low-cost and effective alternative to on-site treatment of industrial wastes which can be used by firms in many areas of the country is described. Under the CWT approach, firms send their wastes to a common processing plant. In the right situations and with the proper kind of inexpensive retrofitting measures, CWT can drastically reduce the cost of treating industrial wastewater because of economies of scale. As well as saving money, CWT has several environmental advantages. First, these facilities are operated by professional waste handlers who should be able to treat and manage the waste more effectively than the generatingmore » firms. Second, the CWT can dramatically increase the potential for recovery of chemicals, which not only reduces the firm's wastewater costs but also the burdens of sludge handling and disposal. EPA, consultants, and local communities have been working on this concept for the last three years. During that time, they have been studying the feasibility of several CWT alternatives already in use in foreign countries for treating electroplating wastewater. In addition to waste treatment, CWT can also provide cogeneration of power, common laboratory facilities and, probably a bulk purchasing cooperative. 3 figures. (JMT)« less

Control of Y-211 content in bulk YBCO superconductors fabricated by a buffer-aided, top seeded infiltration and growth melt process

NASA Astrophysics Data System (ADS)

Namburi, Devendra K.; Shi, Yunhua; Palmer, Kysen G.; Dennis, Anthony R.; Durrell, John H.; Cardwell, David A.

2016-03-01

Bulk (RE)-Ba-Cu-O ((RE)BCO, where RE stands for rare-earth), single grain superconductors can trap magnetic fields of several tesla at low temperatures and therefore can function potentially as high field magnets. Although top seeded melt growth (TSMG) is an established process for fabricating relatively high quality single grains of (RE)BCO for high field applications, this technique suffers from inherent problems such as sample shrinkage, a large intrinsic porosity and the presence of (RE)2BaCuO5 (RE-211)-free regions in the single grain microstructure. Seeded infiltration and growth (SIG), therefore, has emerged as a practical alternative to TSMG that overcomes many of these problems. Until now, however, the superconducting properties of bulk materials processed by SIG have been inferior to those fabricated using the TSMG technique. In this study, we identify that the inferior properties of SIG processed bulk superconductors are related to the presence of a relatively large Y-211 content (˜41.8%) in the single grain microstructure. Controlling the RE-211 content in SIG bulk samples is particularly challenging because it is difficult to regulate the entry of the liquid phase into the solid RE-211 preform during the infiltration process. In an attempt to solve this issue, we have investigated the effect of careful control of both the infiltration temperature and the quantity of liquid phase powder present in the sample preforms prior to processing. We conclude that careful control of the infiltration temperature is the most promising of these two process variables. Using this knowledge, we have fabricated successfully a YBCO bulk single grain using the SIG process of diameter 25 mm that exhibits a trapped field of 0.69 T at 77 K, which is the largest value reported to date for a sample fabricated by the SIG technique.

Tax exemption: why not-for-profits deserve it.

PubMed

Annis, R; Kistner, W G

1988-04-01

Not-for-profit healthcare facilities' tax-exempt status is coming under attack, particularly in congressional hearings on the unrelated business income tax. Therefore tax-exempt providers must keep adequate records of all services and expenditures to demonstrate and preserve their exempt nature. A facility qualifies for tax exemption by demonstrating that it is legally organized to achieve its exempt purpose and that the bulk of its activities is directed toward that goal. The exemption indicates an agreement between the government and the facility: The government is willing to forgo collection of the tax due because the facility performs tasks that would otherwise befall the government, in particular, caring for the indigent. In addition to such care, other social goods flowing from tax-exempt healthcare facilities include their responsiveness to the needs of the nation, their desire to benefit the community, the medical training they provide, and their role as outlets for philanthropy. Before great changes are made in the unrelated business income tax, tax-exempt facilities must make legislatures and the public aware of the vital services they provide.

A molded surface-micromachining and bulk etching release (MOSBE) fabrication platform on (1 1 1) Si for MOEMS

NASA Astrophysics Data System (ADS)

Wu, Mingching; Fang, Weileun

2006-02-01

This work attempts to integrate poly-Si thin film and single-crystal-silicon (SCS) structures in a monolithic process. The process integrated multi-depth DRIE (deep reactive ion etching), trench-refilled molding, a two poly-Si MUMPs process and (1 1 1) Si bulk micromachining to accomplish multi-thickness and multi-depth structures for superior micro-optical devices. In application, a SCS scanning mirror driven by self-aligned vertical comb-drive actuators was demonstrated. The stiffness of the mirror was significantly increased by thick SCS structures. The thin poly-Si film served as flexible torsional springs and electrical routings. The depth difference of the vertical comb electrodes was tuned by DRIE to increase the devices' stroke. Finally, a large moving space was available after the bulk Si etching. In summary, the present fabrication process, named (1 1 1) MOSBE (molded surface-micromachining and bulk etching release on (1 1 1) Si substrate), can further integrate with the MUMPs devices to establish a more powerful platform.

Wastewater Biosolid Composting Optimization Based on UV-VNIR Spectroscopy Monitoring

PubMed Central

Temporal-Lara, Beatriz; Melendez-Pastor, Ignacio; Gómez, Ignacio; Navarro-Pedreño, Jose

2016-01-01

Conventional wastewater treatment generates large amounts of organic matter–rich sludge that requires adequate treatment to avoid public health and environmental problems. The mixture of wastewater sludge and some bulking agents produces a biosolid to be composted at adequate composting facilities. The composting process is chemically and microbiologically complex and requires an adequate aeration of the biosolid (e.g., with a turner machine) for proper maturation of the compost. Adequate (near) real-time monitoring of the compost maturity process is highly difficult and the operation of composting facilities is not as automatized as other industrial processes. Spectroscopic analysis of compost samples has been successfully employed for compost maturity assessment but the preparation of the solid compost samples is difficult and time-consuming. This manuscript presents a methodology based on a combination of a less time-consuming compost sample preparation and ultraviolet, visible and short-wave near-infrared spectroscopy. Spectroscopic measurements were performed with liquid compost extract instead of solid compost samples. Partial least square (PLS) models were developed to quantify chemical fractions commonly employed for compost maturity assessment. Effective regression models were obtained for total organic matter (residual predictive deviation—RPD = 2.68), humification ratio (RPD = 2.23), total exchangeable carbon (RPD = 2.07) and total organic carbon (RPD = 1.66) with a modular and cost-effective visible and near infrared (VNIR) spectroradiometer. This combination of a less time-consuming compost sample preparation with a versatile sensor system provides an easy-to-implement, efficient and cost-effective protocol for compost maturity assessment and near-real-time monitoring. PMID:27854280

Wastewater Biosolid Composting Optimization Based on UV-VNIR Spectroscopy Monitoring.

PubMed

Temporal-Lara, Beatriz; Melendez-Pastor, Ignacio; Gómez, Ignacio; Navarro-Pedreño, Jose

2016-11-15

Conventional wastewater treatment generates large amounts of organic matter-rich sludge that requires adequate treatment to avoid public health and environmental problems. The mixture of wastewater sludge and some bulking agents produces a biosolid to be composted at adequate composting facilities. The composting process is chemically and microbiologically complex and requires an adequate aeration of the biosolid (e.g., with a turner machine) for proper maturation of the compost. Adequate (near) real-time monitoring of the compost maturity process is highly difficult and the operation of composting facilities is not as automatized as other industrial processes. Spectroscopic analysis of compost samples has been successfully employed for compost maturity assessment but the preparation of the solid compost samples is difficult and time-consuming. This manuscript presents a methodology based on a combination of a less time-consuming compost sample preparation and ultraviolet, visible and short-wave near-infrared spectroscopy. Spectroscopic measurements were performed with liquid compost extract instead of solid compost samples. Partial least square (PLS) models were developed to quantify chemical fractions commonly employed for compost maturity assessment. Effective regression models were obtained for total organic matter (residual predictive deviation-RPD = 2.68), humification ratio (RPD = 2.23), total exchangeable carbon (RPD = 2.07) and total organic carbon (RPD = 1.66) with a modular and cost-effective visible and near infrared (VNIR) spectroradiometer. This combination of a less time-consuming compost sample preparation with a versatile sensor system provides an easy-to-implement, efficient and cost-effective protocol for compost maturity assessment and near-real-time monitoring.

Process-morphology scaling relations quantify self-organization in capillary densified nanofiber arrays.

PubMed

Kaiser, Ashley L; Stein, Itai Y; Cui, Kehang; Wardle, Brian L

2018-02-07

Capillary-mediated densification is an inexpensive and versatile approach to tune the application-specific properties and packing morphology of bulk nanofiber (NF) arrays, such as aligned carbon nanotubes. While NF length governs elasto-capillary self-assembly, the geometry of cellular patterns formed by capillary densified NFs cannot be precisely predicted by existing theories. This originates from the recently quantified orders of magnitude lower than expected NF array effective axial elastic modulus (E), and here we show via parametric experimentation and modeling that E determines the width, area, and wall thickness of the resulting cellular pattern. Both experiments and models show that further tuning of the cellular pattern is possible by altering the NF-substrate adhesion strength, which could enable the broad use of this facile approach to predictably pattern NF arrays for high value applications.

A method for aircraft afterburner combustion without flameholders

NASA Astrophysics Data System (ADS)

Birmaher, Shai

2009-12-01

State of the art aircraft afterburners employ spray bars to inject fuel and flameholders to stabilize the combustion process. Such afterburner designs significantly increase the length (and thus weight), pressure losses, and observability of the engine. This thesis presents a feasibility study of a compact 'prime and trigger' (PAT) afterburner concept that eliminates the fuel spray bars and flameholders and, thus, eliminates the above-mentioned problems. In this concept, afterburner fuel is injected just upstream or in between the turbine stages. As the fuel travels through the turbine stages, it evaporates, mixes with the bulk flow, and undergoes some chemical reactions without any significant heat release, a process referred to as 'priming'. Downstream of the turbine stages, combustion could take place through autoignition. However, if fuel autoignition does not occur or if autoignition does not produce a combustion zone that is stable and highly efficient, then a low power pilot, or 'trigger', can be used to control the combustion process. The envisioned trigger for the PAT concept is a jet of product gas from ultra-rich hydrocarbon/air combustion that is injected through the afterburner liner. This 'partial oxidation' (POx) gas, which consists mostly of H2, CO, and diluents, rapidly produces radicals and heat that accelerate the autoignition of the primed mixture and, thus, provide an anchor point for the afterburner combustion process. The objective of this research was to demonstrate the feasibility of the PAT concept by showing that (1) combustion of fuel injected within or upstream of turbine stages can occur only downstream of the turbine stages, and (2) the combustion zone is compact, stable and efficient. This was accomplished using two experimental facilities, a developed theoretical model, and Chemkin simulations. The first facility, termed the Afterburner Facility (AF), simulated the bulk flow temperature, velocity and O2 content through a turbojet combustor, turbine stage and afterburner. To model the PAT concept, Jet-A was injected upstream of the simulated turbine stage and a H2 jet was used to trigger the primed Jet-A combustion process downstream of the turbine stage. H2 was used because POx gas was not available for experiments. The second facility, termed the Propane Autoignition Combustor (PAC), was essentially a scaled-down, simplified version of the AF. The PAC experiments focused on the trigger stage of the PAT concept, using H 2 in lieu of POx gas and employing measurement techniques that were in some ways more detailed than in the AF experiments. The developed model simulated the physics of fuel priming in the AF and predicted the Jet-A autoignition location. It was used to predict and interpret the AF results and to study the feasibility of the PAT concept at pressures outside the AF operating range. Finally, the Chemkin simulations were used to examine the effect of several POx gas compositions on the Jet-A/vitiated-air autoignition process; to compare the POx and H2 triggers; and to explore several reasons for why POx gas and H2 are suitable trigger mechanisms. he experimental, theoretical, and numerical results obtained in this investigation indicated that the PAT concept provides a feasible approach to afterburner combustion. The experiments in the AF showed that the ignition delay of Jet-A is sufficiently long to allow fuel injection within turbine stages without significant heat release upstream of the afterburner. In the AF experiments without the H2 trigger, Jet-A combustion was achieved through autoignition; however, the autoignition combustion zone exhibited large axial fluctuations and low combustion efficiency. The H2 trigger was able to shift the combustion zone upstream, make it more compact, reduce fluctuations in its axial position, and raise the combustion efficiency to nearly 100%. The PAC experiments also showed that a H2 trigger can shift the combustion zone upstream, make it more compact, and increase the combustion efficiency. The PAC results were obtained with lower O 2 content and higher equivalence ratios than in the AF. Therefore, the combined AF and PAC results suggested that the PAT concept is feasible over a wide range of operating conditions. The developed model showed good agreement with the AF results. It also predicted that the PAT concept is feasible at bulk flow pressures outside the AF operating range. Finally, the Chemkin results showed that both the H2 and POx gas triggers can significantly reduce the ignition delay time of primed Jet-A/vitiated air mixtures. Thus, POx gas is a suitable trigger for the PAT concept and should be tested in future experimental investigations.

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

The High Ranking Facilities Deactivation Project (HRFDP), commissioned by the US Department of Energy Nuclear Materials and Facility Stabilization Program, is to place four primary high-risk surplus facilities with 28 associated ancillary facilities at Oak Ridge National Laboratory in a safe, stable, and environmentally sound condition as rapidly and economically as possible. The facilities will be deactivated and left in a condition suitable for an extended period of minimized surveillance and maintenance (S and M) prior to decontaminating and decommissioning (D and D). These four facilities include two reactor facilities containing spent fuel. One of these reactor facilities also containsmore » 55 tons of sodium with approximately 34 tons containing activated sodium-22, 2.5 tons of lithium hydride, approximately 100 tons of potentially contaminated lead, and several other hazardous materials as well as bulk quantities of contaminated scrap metals. The other two facilities to be transferred include a facility with a bank of hot cells containing high levels of transferable contamination and also a facility containing significant quantities of uranyl nitrate and quantities of transferable contamination. This work plan documents the objectives, technical requirements, and detailed work plans--including preliminary schedules, milestones, and conceptual FY 1996 cost estimates--for the Oak Ridge National Laboratory (ORNL). This plan has been developed by the Environmental Restoration (ER) Program of Lockheed Martin Energy Systems (Energy Systems) for the US Department of Energy (DOE) Oak Ridge Operations Office (ORO).« less

Nuclear Security: Quantifying Late Detection in MC&A

DOE Office of Scientific and Technical Information (OSTI.GOV)

Singh, Surinder Paul; Gibbs, Philip W.; Bultz, Garl A.

2014-03-01

The objectives of this presentation are to understand the concept of late detection; review the statistics used in MC&A; specify the Pd and timelines for Pd for MC&A elements for item inventories; review elements of process control as they relate to bulk processes; and specify the timelines and detection thresholds for Pd for MC&A elements for bulk or Processing Operations.

Environment and geographic distance differ in relative importance for determining fungal community of rhizosphere and bulk soil.

PubMed

Zhang, Kaoping; Adams, Jonathan M; Shi, Yu; Yang, Teng; Sun, Ruibo; He, Dan; Ni, Yingying; Chu, Haiyan

2017-09-01

Rhizospheric fungi play major roles in both natural and agricultural ecosystems. However, little is known about the determinants of their diversity and biogeographic patterns. Here, we compared fungal communities in rhizosphere and bulk soils of wheat fields in the North China Plain. The rhizosphere had a lower fungal diversity (observed OTUs and Chao1) than bulk soil, and a distinct fungal community structure in rhizosphere compared with bulk soil. The relative importance of environmental factors and geographic distance for fungal distribution differed between rhizosphere and bulk soil. Environmental factors were the primary cause of variations in total fungal community and major fungal phyla in bulk soil. By contrast, fungal communities in soils loosely attached to roots were predictable from both environmental factors and influences of geographic distance. Communities in soils tightly attached to roots were mainly determined by geographic distance. Our results suggest that both contemporary environment processes (present-day abiotic and biotic environment characters) and historical processes (spatial isolation, dispersal limitation occurred in the past) dominate variations of fungal communities in wheat fields, but their relative importance of all these processes depends on the proximity of fungal community to the plant roots. © 2017 Society for Applied Microbiology and John Wiley & Sons Ltd.

78 FR 29209 - Revisions to Electric Reliability Organization Definition of Bulk Electric System and Rules of...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-17

.../ or clarification of Order No. 773: NERC, American Public Power Association (APPA); American Wind... developed a list of facilities that have the potential to cause cascading problems on the system as well as... with particular tests and outlined general problems with the material impact tests used to determine...

Capabilities Report 2012, West Desert Test Center

DTIC Science & Technology

2012-03-12

132 FT- IR Spectrometer...electronic system files, paper logs, production batch records, QA/QC data, and PCR data generated during a test. Data analysts also track and QC raw data...Advantage +SL bench-top freeze dryers achieve shelf temperatures as low as -57°C and condenser temperatures to -67°C. The bulk milling facility produces

Selected Laws Relating to the Construction and Repair of Public School Facilities in North Carolina.

ERIC Educational Resources Information Center

North Carolina State Dept. of Public Instruction, Raleigh.

Schools in North Carolina are governed by numerous laws pertaining to construction and repair. A selection of these laws is presented. Financial concerns constitute the bulk of these statutes, covering areas such as bids (financial outlay, advertisement, rejecting bids, and withdrawing bids); sources of state funds; the selling or buying of school…

33 CFR 154.1228 - Methods of ensuring the availability of response resources by contract or other approved means.

Code of Federal Regulations, 2011 CFR

2011-07-01

... TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for Animal Fats and Vegetable Oils Facilities... following methods: (1) The identification of an oil spill removal organization with specified equipment and... personnel, equipment, and services capable of being provided by the oil spill removal organization within...

33 CFR 154.1228 - Methods of ensuring the availability of response resources by contract or other approved means.

Code of Federal Regulations, 2010 CFR

2010-07-01

... TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Response Plans for Animal Fats and Vegetable Oils Facilities... following methods: (1) The identification of an oil spill removal organization with specified equipment and... personnel, equipment, and services capable of being provided by the oil spill removal organization within...

EFFECT OF POLY (ETHYLENE GLYCOL) ON THE FORMATION OF NANOSTRUCTURES: A FACILE SUSTAINABLE APPROACH FOR THE SYNTHESIS OF SILVER NANORODS USING MICROWAVE IRRADIATION

EPA Science Inventory

Bulk synthesis of silver nanorods employing poly (ethylene glycol) (PEG) under microwave irradiation is reported. The formation of nanorods or particulate morphology is dependent on the PEG concentration. This greener method uses no surfactants or reducing agents and employs a b...

Molecular dynamics simulation of self-diffusion processes in titanium in bulk material, on grain junctions and on surface.

PubMed

Sushko, Gennady B; Verkhovtsev, Alexey V; Yakubovich, Alexander V; Schramm, Stefan; Solov'yov, Andrey V

2014-08-21

The process of self-diffusion of titanium atoms in a bulk material, on grain junctions and on surface is explored numerically in a broad temperature range by means of classical molecular dynamics simulation. The analysis is carried out for a nanoscale cylindrical sample consisting of three adjacent sectors and various junctions between nanocrystals. The calculated diffusion coefficient varies by several orders of magnitude for different regions of the sample. The calculated values of the bulk diffusion coefficient correspond reasonably well to the experimental data obtained for solid and molten states of titanium. Investigation of diffusion in the nanocrystalline titanium is of a significant importance because of its numerous technological applications. This paper aims to reduce the lack of data on diffusion in titanium and describe the processes occurring in bulk, at different interfaces and on surface of the crystalline titanium.

Determination of outer layer and bulk dehydration kinetics of trehalose dihydrate using atomic force microscopy, gravimetric vapour sorption and near infrared spectroscopy.

PubMed

Jones, Matthew D; Beezer, Anthony E; Buckton, Graham

2008-10-01

Knowledge of the kinetics of solid state reactions is important when considering the stability of many medicines. Potentially, such reactions could follow different kinetics on the surface of particles when compared with their interior, yet solid state processes are routinely followed using only bulk characterisation techniques. Atomic force microscopy (AFM) has previously been shown to be a suitable technique for the investigation of surface processes, but has not been combined with bulk techniques in order to analyse surface and bulk kinetics separately. This report therefore describes the investigation of the outer layer and bulk kinetics of the dehydration of trehalose dihydrate at ambient temperature and low humidity, using AFM, dynamic vapour sorption (DVS) and near infrared spectroscopy (NIR). The use of AFM enabled the dehydration kinetics of the outer layers to be determined both directly and from bulk data. There were no significant differences between the outer layer dehydration kinetics determined using these methods. AFM also enabled the bulk-only kinetics to be analysed from the DVS and NIR data. These results suggest that the combination of AFM and bulk characterisation techniques should enable a more complete understanding of the kinetics of certain solid state reactions to be achieved. (c) 2008 Wiley-Liss, Inc. and the American Pharmacists Association

Charging of Individual Micron-Size Interstellar/Planetary Dust Grains by Secondary Electron Emissions

NASA Technical Reports Server (NTRS)

Tankosic, D.; Abbas, M. M.

2012-01-01

Dust grains in various astrophysical environments are generally charged electrostatically by photoelectric emissions with UV/X-ray radiation, as well as by electron/ion impact. Knowledge of physical and optical properties of individual dust grains is required for understanding of the physical and dynamical processes in space environments and the role of dust in formation of stellar and planetary systems. In this paper, we discuss experimental results on dust charging by electron impact, where low energy electrons are scattered or stick to the dust grains, thereby charging the dust grains negatively, and at sufficiently high energies the incident electrons penetrate the grain leading to excitation and emission of electrons referred to as secondary electron emission (SEE). Currently, very limited experimental data are available for charging of individual micron-size dust grains, particularly by low energy electron impact. Available theoretical models based on the Sternglass equation (Sternglass, 1954) are applicable for neutral, planar, and bulk surfaces only. However, charging properties of individual micron-size dust grains are expected to be different from the values measured on bulk materials. Our recent experimental results on individual, positively charged, micron-size lunar dust grains levitated in an electrodynamic balance facility (at NASA-MSFC) indicate that the SEE by electron impact is a complex process. The electron impact may lead to charging or discharging of dust grains depending upon the grain size, surface potential, electron energy, electron flux, grain composition, and configuration (e.g. Abbas et al, 2010). Here we discuss the complex nature of SEE charging properties of individual micron-size lunar dust grains and silica microspheres.

Civil Penalty Policies

EPA Pesticide Factsheets

The Environmental Protection Agency's Enforcement and Compliance History Online (ECHO) website provides customizable and downloadable information about environmental inspections, violations, and enforcement actions for EPA-regulated facilities, like power plants and factories. ECHO advances public information by sharing data related to facility compliance with and regulatory agency activity related to air, hazardous waste, clean water, and drinking water regulations. ECHO offers many user-friendly options to explore data, including:1. Facility Search (http://echo.epa.gov/facilities/facility-search?mediaSelected=all): ECHO information is searchable by varied criteria, including location, facility type, and compliance status related to the Clean Air Act, Clean Water Act, Resource Conservation and Recovery Act, and Safe Drinking Water Act. Search results are customizable and downloadable.2. Comparative Maps (http://echo.epa.gov/maps/state-comparative-maps) and State Dashboards (http://echo.epa.gov/trends/comparative-maps-dashboards/state-air-dashboard): These tools offer aggregated information about facility compliance status and regulatory agency compliance monitoring and enforcement activity at the national and state level.3. Bulk Data Downloads (http://echo.epa.gov/resources/echo-data/data-downloads): One of ECHO's most popular features is the ability to work offline by downloading large data sets. Users can take advantage of the ECHO Exporter, which provides su

Spatial Variability of Soil Physical Properties Obtained with Laboratory Methods and Their Relation to Field Electrical Resistivity Measurements

NASA Astrophysics Data System (ADS)

Dathe, A.; Nemes, A.; Bloem, E.; Patterson, M.; Gimenez, D.; Angyal, A.; Koestel, J. K.; Jarvis, N.

2017-12-01

Soil spatial heterogeneity plays a critical role for describing water and solute transport processes in the unsaturated zone. Although we have a sound understanding of the physical properties underlying this heterogeneity (like macropores causing preferential water flow), their quantification in a spatial context is still a challenge. To improve existing knowledge and modelling approaches we established a field experiment on an agriculturally used silty clay loam (Stagnosol) in SE Norway. Centimeter to decimeter scale heterogeneities were investigated in the field using electrical resistivity tomography (ERT) in a quasi-3D and a real 3D approach. More than 100 undisturbed soil samples were taken in the 2x1x1 m3plot investigated with 3D ERT to determine soil water retention, saturated and unsaturated hydraulic conductivities and bulk density in the laboratory. A subset of these samples was scanned at the computer tomography (CT) facility at the Swedish University of Agricultural Sciences in Uppsala, Sweden, with special emphasis on characterizing macroporosity. Results show that the ERT measurements captured the spatial distribution of bulk densities and reflected soil water contents. However, ERT could not resolve the large variation observed in saturated hydraulic conductivities from the soil samples. Saturated hydraulic conductivity was clearly related to the macroporosity visible in the CT scans obtained from the respective soil cores. Hydraulic conductivities close to saturation mainly changed with depths in the soil profile and therefore with bulk density. In conclusion, to quantify the spatial heterogeneity of saturated hydraulic conductivities scanning methods with a resolution smaller than the size of macropores have to be used. This is feasible only when the information obtained from for example CT scans of soil cores would be upscaled in a meaningful way.

Elevated Air Humidity Changes Soil Bacterial Community Structure in the Silver Birch Stand.

PubMed

Truu, Marika; Ostonen, Ivika; Preem, Jens-Konrad; Lõhmus, Krista; Nõlvak, Hiie; Ligi, Teele; Rosenvald, Katrin; Parts, Kaarin; Kupper, Priit; Truu, Jaak

2017-01-01

Soil microbes play a fundamental role in forest ecosystems and respond rapidly to changes in the environment. Simultaneously with the temperature increase the climate change scenarios also predict an intensified hydrological cycle for the Baltic Sea runoff region. The aim of this study was to assess the effect of elevated air humidity on the top soil microbial community structure of a silver birch ( Betula pendula Roth.) stand by using a free air humidity manipulation facility (FAHM). The bacterial community structures of bulk soil and birch rhizosphere were analyzed using high-throughput sequencing of bacteria-specific16S rRNA gene fragments and quantification of denitrification related genes. The increased air humidity altered both bulk soil and rhizosphere bacterial community structures, and changes in the bacterial communities initiated by elevated air humidity were related to modified soil abiotic and biotic variables. Network analysis revealed that variation in soil bacterial community structural units is explained by altered abiotic conditions such as increased pH value in bulk soil, while in rhizosphere the change in absorptive root morphology had a higher effect. Among root morphological traits, the absorptive root diameter was strongest related to the bacterial community structure. The changes in bacterial community structures under elevated air humidity are associated with shifts in C, N, and P turnover as well as mineral weathering processes in soil. Increased air humidity decreased the nir and nosZ gene abundance in the rhizosphere bacterial community. The potential contribution of the denitrification to the N 2 O emission was not affected by the elevated air humidity in birch stand soil. In addition, the study revealed a strong link between the bacterial community structure, abundance of denitrification related genes, and birch absorptive root morphology in the ecosystem system adaptation to elevated air humidity.

Elevated Air Humidity Changes Soil Bacterial Community Structure in the Silver Birch Stand

PubMed Central

Truu, Marika; Ostonen, Ivika; Preem, Jens-Konrad; Lõhmus, Krista; Nõlvak, Hiie; Ligi, Teele; Rosenvald, Katrin; Parts, Kaarin; Kupper, Priit; Truu, Jaak

2017-01-01

Soil microbes play a fundamental role in forest ecosystems and respond rapidly to changes in the environment. Simultaneously with the temperature increase the climate change scenarios also predict an intensified hydrological cycle for the Baltic Sea runoff region. The aim of this study was to assess the effect of elevated air humidity on the top soil microbial community structure of a silver birch (Betula pendula Roth.) stand by using a free air humidity manipulation facility (FAHM). The bacterial community structures of bulk soil and birch rhizosphere were analyzed using high-throughput sequencing of bacteria-specific16S rRNA gene fragments and quantification of denitrification related genes. The increased air humidity altered both bulk soil and rhizosphere bacterial community structures, and changes in the bacterial communities initiated by elevated air humidity were related to modified soil abiotic and biotic variables. Network analysis revealed that variation in soil bacterial community structural units is explained by altered abiotic conditions such as increased pH value in bulk soil, while in rhizosphere the change in absorptive root morphology had a higher effect. Among root morphological traits, the absorptive root diameter was strongest related to the bacterial community structure. The changes in bacterial community structures under elevated air humidity are associated with shifts in C, N, and P turnover as well as mineral weathering processes in soil. Increased air humidity decreased the nir and nosZ gene abundance in the rhizosphere bacterial community. The potential contribution of the denitrification to the N2O emission was not affected by the elevated air humidity in birch stand soil. In addition, the study revealed a strong link between the bacterial community structure, abundance of denitrification related genes, and birch absorptive root morphology in the ecosystem system adaptation to elevated air humidity. PMID:28421053

Use of Ground Penetrating Radar at the FAA's National Airport Pavement Test Facility

NASA Astrophysics Data System (ADS)

Injun, Song

2015-04-01

The Federal Aviation Administration (FAA) in the United States has used a ground-coupled Ground Penetrating Radar (GPR) at the National Airport Pavement Test Facility (NAPTF) since 2005. One of the primary objectives of the testing at the facility is to provide full-scale pavement response and failure information for use in airplane landing gear design and configuration studies. During the traffic testing at the facility, a GSSI GPR system was used to develop new procedures for monitoring Hot Mix Asphalt (HMA) pavement density changes that is directly related to pavement failure. After reviewing current setups for data acquisition software and procedures for identifying different pavement layers, dielectric constant and pavement thickness were selected as dominant parameters controlling HMA properties provided by GPR. A new methodology showing HMA density changes in terms of dielectric constant variations, called dielectric sweep test, was developed and applied in full-scale pavement test. The dielectric constant changes were successfully monitored with increasing airplane traffic numbers. The changes were compared to pavement performance data (permanent deformation). The measured dielectric constants based on the known HMA thicknesses were also compared with computed dielectric constants using an equation from ASTM D4748-98 Standard Test Method for Determining the Thickness of Bound Pavement Layers Using Short-Pulse Radar. Six inches diameter cylindrical cores were taken after construction and traffic testing for the HMA layer bulk specific gravity. The measured bulk specific gravity was also compared to monitor HMA density changes caused by aircraft traffic conditions. Additionally this presentation will review the applications of the FAA's ground-coupled GPR on embedded rebar identification in concrete pavement, sewer pipes in soil, and gage identifications in 3D plots.

A wireless electronic monitoring system for securing milk from farm to processor

NASA Astrophysics Data System (ADS)

Womble, Phillip; Hopper, Lindsay; Thompson, Chris; Alexander, Suraj M.; Crist, William; Payne, Fred; Stombaugh, Tim; Paschal, Jon; Moore, Ryan; Luck, Brian; Tabayehnejab, Nasrin

2008-04-01

The Department of Homeland Security and the Department of Health and Human Services have targeted bulk food contamination as a focus for attention. The contamination of bulk food poses a high consequence threat to our society. Milk transport falls into three of the 17 targeted NIPP (National Infrastructure Protection Plan) sectors including agriculture-food, public health, and commercial facilities. Minimal security safeguards have been developed for bulk milk transport. The current manual methods of securing milk are paper intensive and prone to errors. The bulk milk transportation sector requires a security enhancement that will both reduce recording errors and enable normal transport activities to occur while providing security against unauthorized access. Milk transportation companies currently use voluntary seal programs that utilize plastic, numbered seals on milk transport tank openings. Our group has developed a Milk Transport Security System which is an electromechanical access control and communication system that assures the secure transport of milk, milk samples, milk data, and security data between locations and specifically between dairy farms, transfer stations, receiving stations, and milk plants. It includes a security monitoring system installed on the milk transport tank, a hand held device, optional printers, data server, and security evaluation software. The system operates automatically and requires minimal or no attention by the bulk milk hauler/sampler. The system is compatible with existing milk transport infrastructure, and has the support of the milk producers, milk transportation companies, milk marketing agencies, and dairy processors. The security protocol developed is applicable for transport of other bulk foods both nationally and internationally. This system adds significantly to the national security infrastructure for bulk food transport. We are currently demonstrating the system in central Kentucky and will report on the results of the demonstration.

Results From a Parametric Acoustic Liner Experiment Using P and W GEN1 HSR Mixer/Ejector Model

NASA Technical Reports Server (NTRS)

Boyd, Kathleen C.; Wolter, John D.

2004-01-01

This report documents the results of an acoustic liner test performed using a Gen 1 HSR mixer/ejector model installed on the Jet Exit Rig in the Nozzle Acoustic Test Rig in the Aeroacoustic Propulsion Laboratory or NASA Glenn Research Center. Acoustic liner effectiveness and single-component thrust performance results are discussed. Results from 26 different types of single-degree-of-freedom and bulk material liners are compared with each other and against a hardwall baseline. Design parameters involving all aspects of the facesheet, the backing cavity, and the type of bulk material were varied in order to study the effects of these design features on the acoustic impedance, acoustic effectiveness and on nozzle thrust performance. Overall, the bulk absorber liners are more effective at reducing the jet noise than the single-degree-of-freedom liners. Many of the design parameters had little effect on acoustic effectiveness, such as facesheeet hole diameter and honeycomb cell size. A relatively large variation in the impedance of the bulk absorber in a bulk liner is required to have a significant impact on the noise reduction. The thrust results exhibit a number of consistent trends, supporting the validity of this new addition to the facility. In general, the thrust results indicate that thrust performance benefits from increased facesheet thickness and decreased facesheet porosity.

A novel, two-step top seeded infiltration and growth process for the fabrication of single grain, bulk (RE)BCO superconductors

NASA Astrophysics Data System (ADS)

Namburi, Devendra K.; Shi, Yunhua; Palmer, Kysen G.; Dennis, Anthony R.; Durrell, John H.; Cardwell, David A.

2016-09-01

A fundamental requirement of the fabrication of high performing, (RE)-Ba-Cu-O bulk superconductors is achieving a single grain microstructure that exhibits good flux pinning properties. The top seeded melt growth (TSMG) process is a well-established technique for the fabrication of single grain (RE)BCO bulk samples and is now applied routinely by a number of research groups around the world. The introduction of a buffer layer to the TSMG process has been demonstrated recently to improve significantly the general reliability of the process. However, a number of growth-related defects, such as porosity and the formation of micro-cracks, remain inherent to the TSMG process, and are proving difficult to eliminate by varying the melt process parameters. The seeded infiltration and growth (SIG) process has been shown to yield single grain samples that exhibit significantly improved microstructures compared to the TSMG technique. Unfortunately, however, SIG leads to other processing challenges, such as the reliability of fabrication, optimisation of RE2BaCuO5 (RE-211) inclusions (size and content) in the sample microstructure, practical oxygenation of as processed samples and, hence, optimisation of the superconducting properties of the bulk single grain. In the present paper, we report the development of a near-net shaping technique based on a novel two-step, buffer-aided top seeded infiltration and growth (BA-TSIG) process, which has been demonstrated to improve greatly the reliability of the single grain growth process and has been used to fabricate successfully bulk, single grain (RE)BCO superconductors with improved microstructures and superconducting properties. A trapped field of ˜0.84 T and a zero field current density of 60 kA cm-2 have been measured at 77 K in a bulk, YBCO single grain sample of diameter 25 mm processed by this two-step BA-TSIG technique. To the best of our knowledge, this value of trapped field is the highest value ever reported for a sample fabricated by an infiltration and growth process. In this study we report the successful fabrication of 14 YBCO samples, with diameters of up to 32 mm, by this novel technique with a success rate of greater than 92%.

Highly Conductive and Reliable Copper-Filled Isotropically Conductive Adhesives Using Organic Acids for Oxidation Prevention

NASA Astrophysics Data System (ADS)

Chen, Wenjun; Deng, Dunying; Cheng, Yuanrong; Xiao, Fei

2015-07-01

The easy oxidation of copper is one critical obstacle to high-performance copper-filled isotropically conductive adhesives (ICAs). In this paper, a facile method to prepare highly reliable, highly conductive, and low-cost ICAs is reported. The copper fillers were treated by organic acids for oxidation prevention. Compared with ICA filled with untreated copper flakes, the ICA filled with copper flakes treated by different organic acids exhibited much lower bulk resistivity. The lowest bulk resistivity achieved was 4.5 × 10-5 Ω cm, which is comparable to that of commercially available Ag-filled ICA. After 500 h of 85°C/85% relative humidity (RH) aging, the treated ICAs showed quite stable bulk resistivity and relatively stable contact resistance. Through analyzing the results of x-ray diffraction, x-ray photoelectron spectroscopy, and thermogravimetric analysis, we found that, with the assistance of organic acids, the treated copper flakes exhibited resistance to oxidation, thus guaranteeing good performance.

Laboratory Evaluation of Remediation Alternatives for U.S. Coast Guard Small Arms Firing Ranges

DTIC Science & Technology

1999-11-01

S) is an immobilization process that involves the mixing of a contaminated soil with a binder material to enhance the physical and chemical...samples were shipped to WES for laboratory analysis. Phase III: Homogenization of the Bulk Samples. Each of the bulk samples was separately mixed to...produce uniform samples for testing. These mixed bulk soil samples were analyzed for metal content. Phase IV: Characterization of the Bulk Soils

Advanced bulk processing of lightweight materials for utilization in the transportation sector

NASA Astrophysics Data System (ADS)

Milner, Justin L.

The overall objective of this research is to develop the microstructure of metallic lightweight materials via multiple advanced processing techniques with potentials for industrial utilization on a large scale to meet the demands of the aerospace and automotive sectors. This work focused on (i) refining the grain structure to increase the strength, (ii) controlling the texture to increase formability and (iii) directly reducing processing/production cost of lightweight material components. Advanced processing is conducted on a bulk scale by several severe plastic deformation techniques including: accumulative roll bonding, isolated shear rolling and friction stir processing to achieve the multiple targets of this research. Development and validation of the processing techniques is achieved through wide-ranging experiments along with detailed mechanical and microstructural examination of the processed material. On a broad level, this research will make advancements in processing of bulk lightweight materials facilitating industrial-scale implementation. Where accumulative roll bonding and isolated shear rolling, currently feasible on an industrial scale, processes bulk sheet materials capable of replacing more expensive grades of alloys and enabling low-temperature and high-strain-rate formability. Furthermore, friction stir processing to manufacture lightweight tubes, made from magnesium alloys, has the potential to increase the utilization of these materials in the automotive and aerospace sectors for high strength - high formability applications. With the increased utilization of these advanced processing techniques will significantly reduce the cost associated with lightweight materials for many applications in the transportation sectors.

Development of property-transfer models for estimating the hydraulic properties of deep sediments at the Idaho National Engineering and Environmental Laboratory, Idaho

USGS Publications Warehouse

Winfield, Kari A.

2005-01-01

Because characterizing the unsaturated hydraulic properties of sediments over large areas or depths is costly and time consuming, development of models that predict these properties from more easily measured bulk-physical properties is desirable. At the Idaho National Engineering and Environmental Laboratory, the unsaturated zone is composed of thick basalt flow sequences interbedded with thinner sedimentary layers. Determining the unsaturated hydraulic properties of sedimentary layers is one step in understanding water flow and solute transport processes through this complex unsaturated system. Multiple linear regression was used to construct simple property-transfer models for estimating the water-retention curve and saturated hydraulic conductivity of deep sediments at the Idaho National Engineering and Environmental Laboratory. The regression models were developed from 109 core sample subsets with laboratory measurements of hydraulic and bulk-physical properties. The core samples were collected at depths of 9 to 175 meters at two facilities within the southwestern portion of the Idaho National Engineering and Environmental Laboratory-the Radioactive Waste Management Complex, and the Vadose Zone Research Park southwest of the Idaho Nuclear Technology and Engineering Center. Four regression models were developed using bulk-physical property measurements (bulk density, particle density, and particle size) as the potential explanatory variables. Three representations of the particle-size distribution were compared: (1) textural-class percentages (gravel, sand, silt, and clay), (2) geometric statistics (mean and standard deviation), and (3) graphical statistics (median and uniformity coefficient). The four response variables, estimated from linear combinations of the bulk-physical properties, included saturated hydraulic conductivity and three parameters that define the water-retention curve. For each core sample,values of each water-retention parameter were estimated from the appropriate regression equation and used to calculate an estimated water-retention curve. The degree to which the estimated curve approximated the measured curve was quantified using a goodness-of-fit indicator, the root-mean-square error. Comparison of the root-mean-square-error distributions for each alternative particle-size model showed that the estimated water-retention curves were insensitive to the way the particle-size distribution was represented. Bulk density, the median particle diameter, and the uniformity coefficient were chosen as input parameters for the final models. The property-transfer models developed in this study allow easy determination of hydraulic properties without need for their direct measurement. Additionally, the models provide the basis for development of theoretical models that rely on physical relationships between the pore-size distribution and the bulk-physical properties of the media. With this adaptation, the property-transfer models should have greater application throughout the Idaho National Engineering and Environmental Laboratory and other geographic locations.

Method of forming crystalline silicon devices on glass

DOEpatents

McCarthy, Anthony M.

1995-01-01

A method for fabricating single-crystal silicon microelectronic components on a silicon substrate and transferring same to a glass substrate. This is achieved by utilizing conventional silicon processing techniques for fabricating components of electronic circuits and devices on bulk silicon, wherein a bulk silicon surface is prepared with epitaxial layers prior to the conventional processing. The silicon substrate is bonded to a glass substrate and the bulk silicon is removed leaving the components intact on the glass substrate surface. Subsequent standard processing completes the device and circuit manufacturing. This invention is useful in applications requiring a transparent or insulating substrate, particularly for display manufacturing. Other applications include sensors, actuators, optoelectronics, radiation hard electronics, and high temperature electronics.

A methodology to identify stranded generation facilities and estimate stranded costs for Louisiana's electric utility industry

NASA Astrophysics Data System (ADS)

Cope, Robert Frank, III

1998-12-01

The electric utility industry in the United States is currently experiencing a new and different type of growing pain. It is the pain of having to restructure itself into a competitive business. Many industry experts are trying to explain how the nation as a whole, as well as individual states, will implement restructuring and handle its numerous "transition problems." One significant transition problem for federal and state regulators rests with determining a utility's stranded costs. Stranded generation facilities are assets which would be uneconomic in a competitive environment or costs for assets whose regulated book value is greater than market value. At issue is the methodology which will be used to estimate stranded costs. The two primary methods are known as "Top-Down" and "Bottom-Up." The "Top-Down" approach simply determines the present value of the losses in revenue as the market price for electricity changes over a period of time into the future. The problem with this approach is that it does not take into account technical issues associated with the generation and wheeling of electricity. The "Bottom-Up" approach computes the present value of specific strandable generation facilities and compares the resulting valuations with their historical costs. It is regarded as a detailed and difficult, but more precise, approach to identifying stranded assets and their associated costs. This dissertation develops a "Bottom-Up" quantitative, optimization-based approach to electric power wheeling within the state of Louisiana. It optimally evaluates all production capabilities and coordinates the movement of bulk power through transmission interconnections of competing companies in and around the state. Sensitivity analysis to this approach is performed by varying seasonal consumer demand, electric power imports, and transmission inter-connection cost parameters. Generation facility economic dispatch and transmission interconnection bulk power transfers, specific to each set of parameters, lead to the identification of stranded generation facilities. Stranded costs of non-dispatched and uneconomically dispatched generation facilities can then be estimated to indicate, arguably, the largest portion of restructuring transition costs as the industry is transformed from its present monopolistic structure to a competitive one.

Energy saving control strategies for Haliscomenobacter hydrossis filamentous sludge bulking in the A/O process treating real low carbon/nitrogen domestic wastewater.

PubMed

Jiao, Erlong; Gao, Chundi; Li, Renfei; Tian, Ye; Peng, Yongzhen

2017-07-16

The control strategies of energy saving for filamentous sludge bulking were investigated in the A/O process under low dissolved oxygen (DO) with low carbon/nitrogen (C/N) ratio, and the dominant filamentous bacteria were identified by using fluorescent in situ hybridization. Initially, the sludge volume index reached nearly 500 mL/g and serious bulking occurred when the DO value was 0.5 mg/L, with Haliscomenobacter hydrossis as the major filamentous bacteria in the bulking sludge. Later on, the compartment number increased in the aerobic zone, increasing by this way DO, to control serious bulking. Increasing DO to 1 mg/L based on the increase of compartment number in the aerobic zone was the favorable controlling method, which solved the sludge loss, improved the effluent quality to the national discharge standard and allowed for energy costs saving. As a result, the effective control method for H. hydrossis filamentous sludge bulking provided the economical, convenient and longstanding method for most municipal wastewater treatment plants treating real low C/N domestic wastewater.

Complex Behavior of Aqueous α-Cyclodextrin Solutions. Interfacial Morphologies Resulting from Bulk Aggregation.

PubMed

Hernandez-Pascacio, Jorge; Piñeiro, Ángel; Ruso, Juan M; Hassan, Natalia; Campbell, Richard A; Campos-Terán, José; Costas, Miguel

2016-07-05

The spontaneous aggregation of α-cyclodextrin (α-CD) molecules in the bulk aqueous solution and the interactions of the resulting aggregates at the liquid/air interface have been studied at 283 K using a battery of techniques: transmission electron microscopy, dynamic light scattering, dynamic surface tensiometry, Brewster angle microscopy, neutron reflectometry, and ellipsometry. We show that α-CD molecules spontaneously form aggregates in the bulk that grow in size with time. These aggregates adsorb to the liquid/air interface with their size in the bulk determining the adsorption rate. The material that reaches the interface coalesces laterally to form two-dimensional domains on the micrometer scale with a layer thickness on the nanometer scale. These processes are affected by the ages of both the bulk and the interface. The interfacial layer formed is not in fast dynamic equilibrium with the subphase as the resulting morphology is locked in a kinetically trapped state. These results reveal a surprising complexity of the parallel physical processes taking place in the bulk and at the interface of what might have seemed initially like a simple system.

Bulk contribution to magnetotransport properties of low-defect-density Bi2Te3 topological insulator thin films

NASA Astrophysics Data System (ADS)

Ngabonziza, P.; Wang, Y.; Brinkman, A.

2018-04-01

An important challenge in the field of topological materials is to carefully disentangle the electronic transport contribution of the topological surface states from that of the bulk. For Bi2Te3 topological insulator samples, bulk single crystals and thin films exposed to air during fabrication processes are known to be bulk conducting, with the chemical potential in the bulk conduction band. For Bi2Te3 thin films grown by molecular beam epitaxy, we combine structural characterization (transmission electron microscopy), chemical surface analysis as function of time (x-ray photoelectron spectroscopy) and magnetotransport analysis to understand the low defect density and record high bulk electron mobility once charge is doped into the bulk by surface degradation. Carrier densities and electronic mobilities extracted from the Hall effect and the quantum oscillations are consistent and reveal a large bulk carrier mobility. Because of the cylindrical shape of the bulk Fermi surface, the angle dependence of the bulk magnetoresistance oscillations is two dimensional in nature.

Characterization of Spatial Impact of Particles Emitted from a Cement Material Production Facility on Outdoor Particle Deposition in the Surrounding Community.

PubMed

Yu, Chang Ho; Fan, Zhihua Tina; McCandlish, Elizabeth; Stern, Alan H; Lioy, Paul J

2011-10-01

The objective of this study was to estimate the contribution of a facility that processes steel production slag into raw material for cement production to local outdoor particle deposition in Camden, NJ. A dry deposition sampler that can house four 37-mm quartz fiber filters was developed and used for the collection of atmospheric particle deposits. Two rounds of particle collection (3-4 weeks each) were conducted in 8-11 locations 200-800 m downwind of the facility. Background samples were concurrently collected in a remote area located ∼2 km upwind from the facility. In addition, duplicate surface wipe samples were collected side-by-side from each of the 13 locations within the same sampling area during the first deposition sampling period. One composite source material sample was also collected from a pile stored in the facility. Both the bulk of the source material and the <38 μm fraction subsample were analyzed to obtain the elemental source profile. The particle deposition flux in the study area was higher (24-83 mg/m 2 ·day) than at the background sites (13-17 mg/m 2 ·day). The concentration of Ca, a major element in the cement source production material, was found to exponentially decrease with increasing downwind distance from the facility (P < 0.05). The ratio of Ca/Al, an indicator of Ca enrichment due to anthropogenic sources in a given sample, showed a similar trend. These observations suggest a significant contribution of the facility to the local particle deposition. The contribution of the facility to outdoor deposited particle mass was further estimated by three independent models using the measurements obtained from this study. The estimated contributions to particle deposition in the study area were 1.8-7.4% from the regression analysis of the Ca concentration in particle deposition samples against the distance from the facility, 0-11% from the U.S. Environmental Protection Agency (EPA) Chemical Mass Balance (CMB) source-receptor model, and 7.6-13% from the EPA Industrial Source Complex Short Term (ISCST3) dispersion model using the particle-size-adjusted permit-based emissions estimates. [Box: see text].

Assessment of Performance of the Industrial Process of Bulk Vacuum Packaging of Raw Meat with Nondestructive Optical Oxygen Sensing Systems.

PubMed

Kelly, Caroline A; Cruz-Romero, Malco; Kerry, Joseph P; Papkovsky, Dmitri P

2018-05-02

The commercially-available optical oxygen-sensing system Optech-O₂ Platinum was applied to nondestructively assess the in situ performance of bulk, vacuum-packaged raw beef in three ~300 kg containers. Twenty sensors were attached to the inner surface of the standard bin-contained laminate bag (10 on the front and back sides), such that after filling with meat and sealing under vacuum, the sensors were accessible for optical interrogation with the external reader device. After filling and sealing each bag, the sensors were measured repetitively and nondestructively over a 15-day storage period at 1 °C, thus tracking residual oxygen distribution in the bag and changes during storage. The sensors revealed a number of unidentified meat quality and processing issues, and helped to improve the packaging process by pouring flakes of dry ice into the bag. Sensor utility in mapping the distribution of residual O₂ in sealed bulk containers and optimising and improving the packaging process, including handling and storage of bulk vacuum-packaged meat bins, was evident.

Trapped magnetic-field properties of prototype for Gd-Ba-Cu-O/MgB2 hybrid-type superconducting bulk magnet

NASA Astrophysics Data System (ADS)

Naito, Tomoyuki; Mochizuki, Hidehiko; Fujishiro, Hiroyuki; Teshima, Hidekazu

2016-03-01

We have studied experimentally and numerically the trapped magnetic-field properties of a hybrid-type superconducting bulk magnet, which comprised an inner Gd-Ba-Cu-O (GdBCO) disk-bulk and an outer MgB2 ring-bulk, under field-cooled magnetization (FCM) and pulsed-field magnetization (PFM). The trapped field by FCM at the center of the hybrid bulk was 4.5 T at 20 K, which was 0.2 T higher than that of the inner GdBCO disk-bulk without MgB2 ring-bulk. The experimental results by FCM were quantitatively reproduced by the numerical estimations for a model, which makes it possible to understand the trapped field properties of the hybrid bulk. The total magnetic flux by FCM, which was estimated numerically, was enhanced by about 1.7 times from 0.91 mWb of the single GdBCO bulk to 1.53 mWb of the hybrid bulk. We also succeeded in magnetizing the whole hybrid bulk by applying multi-pulsed-fields. The central trapped field of 1.88 T was not enhanced, but the total magnetic flux, which was obtained experimentally, was evidently increased by 2.5 times (0.25 \\to 0.62 mWb) for the hybrid bulk. The obtained results suggest that the hybridization is effective to enhance the total magnetic flux. To confirm the reinforcing effect of the MgB2 ring to the GdBCO disk during the cooling and magnetization processes, we have measured the thermal dilatation, {\\text{}}{dL}({\\text{}}T)/{\\text{}}L(300 K), of the GdBCO, MgB2 and stainless steel. As a result, the thermal dilatation of MgB2 was smaller than that of GdBCO. MgB2 ring-bulk shows no compression effect to resist the hoop stress of the GdBCO disk-bulk during the FCM process. The reinforcing material such as the stainless steel ring must be set outside the GdBCO disk-bulk.

Fabricating waveguide Bragg gratings (WBGs) in bulk materials using ultrashort laser pulses

NASA Astrophysics Data System (ADS)

Ams, Martin; Dekker, Peter; Gross, Simon; Withford, Michael J.

2017-01-01

Optical waveguide Bragg gratings (WBGs) can be created in transparent materials using femtosecond laser pulses. The technique is conducted without the need for lithography, ion-beam fabrication methods, or clean room facilities. This paper reviews the field of ultrafast laser-inscribed WBGs since its inception, with a particular focus on fabrication techniques, WBG characteristics, WBG types, and WBG applications.

33 CFR Appendix D to Part 154 - Training Elements for Oil Spill Response Plans

Code of Federal Regulations, 2010 CFR

2010-07-01

... Response Plans D Appendix D to Part 154 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Pt. 154, App. D Appendix D to Part 154—Training Elements for Oil Spill Response Plans 1. General 1.1The portion of the plan...

Delignified and Densified Cellulose Bulk Materials with Excellent Tensile Properties for Sustainable Engineering.

PubMed

Frey, Marion; Widner, Daniel; Segmehl, Jana S; Casdorff, Kirstin; Keplinger, Tobias; Burgert, Ingo

2018-02-07

Today's materials research aims at excellent mechanical performance in combination with advanced functionality. In this regard, great progress has been made in tailoring the materials by assembly processes in bottom-up approaches. In the field of wood-derived materials, nanocellulose research has gained increasing attention, and materials with advanced properties were developed. However, there are still unresolved issues concerning upscaling for large-scale applications. Alternatively, the sophisticated hierarchical scaffold of wood can be utilized in a top-down approach to upscale functionalization, and one can profit at the same time from its renewable nature, CO 2 storing capacity, light weight, and good mechanical performance. Nevertheless, for bulk wood materials, a wider multipurpose industrial use is so far impeded by concerns regarding durability, natural heterogeneity as well as limitations in terms of functionalization, processing, and shaping. Here, we present a novel cellulose bulk material concept based on delignification and densification of wood resulting in a high-performance material. A delignification process using hydrogen peroxide and acetic acid was optimized to delignify the entire bulk wooden blocks and to retain the highly beneficial structural directionality of wood. In a subsequent step, these cellulosic blocks were densified in a process combining compression and lateral shear to gain a very compact cellulosic material with entangled fibers while retaining unidirectional fiber orientation. The cellulose bulk materials obtained by different densification protocols were structurally, chemically, and mechanically characterized revealing superior tensile properties compared to native wood. Furthermore, after delignification, the cellulose bulk material can be easily formed into different shapes, and the delignification facilitates functionalization of the bioscaffold.

Get ready for the new asbestos standard

DOE Office of Scientific and Technical Information (OSTI.GOV)

Onderick, W.A.

On October 1, OSHA`s revised asbestos rules became law, and with them are many changes from the previous 1986 standard. The presumed asbestos-containing material (PACM) rule is one of the bigger changes in the revised standard. OSHA has declared that owners must presume that there are certain high-risk asbestos-containing materials (ACM) in facilities built prior to 1981, unless bulk sample results prove them to be nonasbestos. The impact of this provision forces companies to think carefully before presuming where asbestos is or where it is not. Companies must also heed the EPA Asbestos National Emission Standards for Hazardous Air Pollutantsmore » (NESHAP), which require inspections and bulk sampling to identify materials prior to renovation or demolition. Short and long term needs should be examined when analyzing how to comply with the PACM provision. There are four options available. Option 1: Ignore the standard and face potential enforcement fines. Option 2: Presume all materials in pre-1981 buildings contain asbestos and simply post additional warning signs. Option 3: Survey or resurvey the facilities to be in compliance with the PACM ruling. Option 4: Conduct more comprehensive surveys. Option 3 is discussed in some detail.« less

Idealized simulation of the Colorado hailstorm case: comparison of bulk and detailed microphysics

NASA Astrophysics Data System (ADS)

Geresdi, I.

One of the purposes of the Fourth Cloud Modeling Workshop was to compare different microphysical treatments. In this paper, the results of a widely used bulk treatment and five versions of a detailed microphysical model are presented. Sensitivity analysis was made to investigate the effect of bulk parametrization, ice initiation technique, CCN concentration and collision efficiency of rimed ice crystal-drop collision. The results show that: (i) The mixing ratios of different species of hydrometeors calculated by bulk and one of the detailed models show some similarity. However, the processes of hail/graupel formation are different in the bulk and the detailed models. (ii) Using different ice initiation in the detailed models' different processes became important in the hail and graupel formation. (iii) In the case of higher CCN concentration, the mixing ratio of liquid water, hail and graupel were more sensitive to the value of collision efficiency of rimed ice crystal-drop collision. (iv) The Bergeron-Findeisen process does not work in the updraft core of a convective cloud. The vapor content was always over water saturation; moreover, the supersaturation gradually increased after the appearance of precipitation ice particles.

"Bulk" Nanocrystalline Metals: Review of the Current State of the Art and Future Opportunities for Copper and Copper Alloys

NASA Astrophysics Data System (ADS)

Tschopp, M. A.; Murdoch, H. A.; Kecskes, L. J.; Darling, K. A.

2014-06-01

It is a new beginning for innovative fundamental and applied science in nanocrystalline materials. Many of the processing and consolidation challenges that have haunted nanocrystalline materials are now more fully understood, opening the doors for bulk nanocrystalline materials and parts to be produced. While challenges remain, recent advances in experimental, computational, and theoretical capability have allowed for bulk specimens that have heretofore been pursued only on a limited basis. This article discusses the methodology for synthesis and consolidation of bulk nanocrystalline materials using mechanical alloying, the alloy development and synthesis process for stabilizing these materials at elevated temperatures, and the physical and mechanical properties of nanocrystalline materials with a focus throughout on nanocrystalline copper and a nanocrystalline Cu-Ta system, consolidated via equal channel angular extrusion, with properties rivaling that of nanocrystalline pure Ta. Moreover, modeling and simulation approaches as well as experimental results for grain growth, grain boundary processes, and deformation mechanisms in nanocrystalline copper are briefly reviewed and discussed. Integrating experiments and computational materials science for synthesizing bulk nanocrystalline materials can bring about the next generation of ultrahigh strength materials for defense and energy applications.

Fatigue Life Variability in Large Aluminum Forgings with Residual Stress

DTIC Science & Technology

2011-07-01

been conducted. A detailed finite element analysis of the forge/ quench /coldwork/machine process was performed in order to predict the bulk residual...forge/ quench /coldwork/machine process was performed in order to predict the bulk residual stresses in a fictitious aluminum bulkhead. The residual...continues to develop the capability for computational simulation of the forge, quench , cold work and machining processes. In order to handle the

Just-In-Time Inventory Management; Application and Recommendations for Naval Hospital, Oakland.

DTIC Science & Technology

1992-12-01

108 c. Break Bulk on Stored Material .................. 110 d. Emphasize Continuous Quality Improvement ...... 111 4. Streamline Order Processing for...manpower. 4. Use of existing industry automation to expedite order processing to the prime vendor. The intent of this research is to present the JIT...34* Collection of baseline data. "* Break bulk on stored material. 85 • Emphasize continuous quality improvement. 4. Streamline order processing for PV

Design and fabrication of MEMS devices using the integration of MUMPs, trench-refilled molding, DRIE and bulk silicon etching processes

NASA Astrophysics Data System (ADS)

Wu, Mingching; Fang, Weileun

2005-03-01

This work integrates multi-depth DRIE etching, trench-refilled molding, two poly-Si layers MUMPs and bulk releasing to improve the variety and performance of MEMS devices. In summary, the present fabrication process, named MOSBE II, has three merits. First, this process can monolithically fabricate and integrate poly-Si thin-film structures with different thicknesses and stiffnesses, such as the flexible spring and the stiff mirror plate. Second, multi-depth structures, such as vertical comb electrodes, are available from the DRIE processes. Third, a cavity under the micromachined device is provided by the bulk silicon etching process, so that a large out-of-plane motion is allowed. In application, an optical scanner driven by the self-aligned vertical comb actuator was demonstrated. The poly-Si micromachined components fabricated by MOSBE II can further integrate with the MUMPs devices to establish a more powerful MOEMS platform.

Boiling of the interface between two immiscible liquids below the bulk boiling temperatures of both components.

PubMed

Pimenova, Anastasiya V; Goldobin, Denis S

2014-11-01

We consider the problem of boiling of the direct contact of two immiscible liquids. An intense vapour formation at such a direct contact is possible below the bulk boiling points of both components, meaning an effective decrease of the boiling temperature of the system. Although the phenomenon is known in science and widely employed in technology, the direct contact boiling process was thoroughly studied (both experimentally and theoretically) only for the case where one of liquids is becoming heated above its bulk boiling point. On the contrary, we address the case where both liquids remain below their bulk boiling points. In this paper we construct the theoretical description of the boiling process and discuss the actualisation of the case we consider for real systems.

Lightweight alumina refractory aggregate. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Swansiger, T.G.; Pearson, A.

1996-07-16

Objective was to develop a lightweight, high alumina refractory aggregate for use in various high performance insulating (low thermal conductivity) refractory applications (e.g., in the aluminium, glass, cement, and iron and steel industries). A new aggregate process was developed through bench and pilot-scale experiments involving extrusion of a blend of calcined and activated alumina powders and organic extrusion aids and binders. The aggregate, with a bulk density approaching 2.5 g/cc, exhibited reduced thermal conductivity and adequate fired strength compared to dense tabular aggregate. Refractory manufacturers were moderately enthusiastic over the results. Alcoa prepared an economic analysis for producing lightweight aggregate,more » based on a retrofit of this process into existing Alcoa production facilities. However, a new, competing lightweight aggregate material was developed by another company; this material (Plasmal{trademark})had a significantly more favorable cost base than the Alcoa/DOE material, due to cheap raw materials and fewer processing steps. In late 1995, Alcoa became a distributor of Plasmal. Alcoa estimated that {ge}75% of the market originally envisioned for the Alcoa/DOE aggregate would be taken by Plasmal. Hence, it was decided to terminate the contract without the full- scale demonstration.« less

Mercury Contamination - Amalgamate (contract with NFS and ADA). Demonstration of DeHg SM Process. Mixed Waste Focus Area. OST Reference Number 1675

DOE Office of Scientific and Technical Information (OSTI.GOV)

None, None

1999-09-01

Through efforts led by the Mixed Waste Focus Area (MWFA) and its Mercury Working Group (HgWG), the inventory of bulk elemental mercury contaminated with radionuclides stored at various U.S. Department of Energy (DOE) sites is thought to be approximately 16 m3 (Conley et al. 1998). At least 19 different DOE sites have this type of mixed low-level waste in their storage facilities. The U.S. Environmental Protection Agency (EPA) specifies amalgamation as the treatment method for radioactively contaminated elemental mercury. Although the chemistry of amalgamation is well known, the practical engineering of a sizable amalgamation process has not been tested (Tysonmore » 1993). To eliminate the existing DOE inventory in a reasonable timeframe, scalable equipment is needed that can produce waste forms that meet the EPA definition of amalgamation, produce waste forms that pass the EPA Toxicity Characteristic Leaching Procedure (TCLP) limit of 0.20 mg/L, limit mercury vapor concentrations during processing to below the Occupational Safety and Health Administration’s (OSHA) 8-h worker exposure limit (50 mg/m3) for mercury, and perform the above economically.« less

Tip-induced nanoreactor for silicate

NASA Astrophysics Data System (ADS)

Gao, Ming; Ma, Liran; Liang, Yong; Gao, Yuan; Luo, Jianbin

2015-09-01

Nanoscale scientific issues have attracted an increasing amount of research interest due to their specific size-effect and novel structure-property. From macro to nano, materials present some unique chemical reactivity that bulk materials do not own. Here we introduce a facile method to generate silicate with nanoscale control based on the establishment of a confined space between a meso/nanoscale tungsten tip and a smooth silica/silicon substrate. During the process, local water-like droplets deposition can be obviously observed in the confinement between the Si/SiO2 surfaces and the KOH-modified tungsten tip. By the combination of in-situ optical microscopy and Raman spectroscopy, we were able to take a deep insight of both the product composition and the underlying mechanism of such phenomena. It was indicated that such nanoreactor for silicate could be quite efficient as a result of the local capillarity and electric field effect, with implications at both nano and meso scales.

Tip-induced nanoreactor for silicate.

PubMed

Gao, Ming; Ma, Liran; Liang, Yong; Gao, Yuan; Luo, Jianbin

2015-09-14

Nanoscale scientific issues have attracted an increasing amount of research interest due to their specific size-effect and novel structure-property. From macro to nano, materials present some unique chemical reactivity that bulk materials do not own. Here we introduce a facile method to generate silicate with nanoscale control based on the establishment of a confined space between a meso/nanoscale tungsten tip and a smooth silica/silicon substrate. During the process, local water-like droplets deposition can be obviously observed in the confinement between the Si/SiO2 surfaces and the KOH-modified tungsten tip. By the combination of in-situ optical microscopy and Raman spectroscopy, we were able to take a deep insight of both the product composition and the underlying mechanism of such phenomena. It was indicated that such nanoreactor for silicate could be quite efficient as a result of the local capillarity and electric field effect, with implications at both nano and meso scales.

Crystallization in high level waste (HLW) glass melters: Savannah River Site operational experience

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fox, Kevin M.; Peeler, David K.; Kruger, Albert A.

2015-06-12

This paper provides a review of the scaled melter testing that was completed for design input to the Defense Waste Processing Facility (DWPF) melter. Testing with prototype melters provided the data to define the DWPF operating limits to avoid bulk (volume) crystallization in the un-agitated DWPF melter and provided the data to distinguish between spinels generated by refractory corrosion versus spinels that precipitated from the HLW glass melt pool. A review of the crystallization observed with the prototype melters and the full-scale DWPF melters (DWPF Melter 1 and DWPF Melter 2) is included. Examples of actual DWPF melter attainment withmore » Melter 2 are given. The intent is to provide an overview of lessons learned, including some example data, that can be used to advance the development and implementation of an empirical model and operating limit for crystal accumulation for a waste treatment and immobilization plant.« less

Heat flux sensor research and development: The cool film calorimeter

NASA Technical Reports Server (NTRS)

Abtahi, A.; Dean, P.

1990-01-01

The goal was to meet the measurement requirement of the NASP program for a gauge capable of measuring heat flux into a 'typical' structure in a 'typical' hypersonic flight environment. A device is conceptually described that has fast response times and is small enough to fit in leading edge or cowl lip structures. The device relies heavily on thin film technology. The main conclusion is the description of the limitations of thin film technology both in the art of fabrication and in the assumption that thin films have the same material properties as the original bulk material. Three gauges were designed and fabricated. Thin film deposition processes were evaluated. The effect of different thin film materials on the performance and fabrication of the gauge was studied. The gauges were tested in an arcjet facility. Survivability and accuracy were determined under various hostile environment conditions.

Tip-induced nanoreactor for silicate

PubMed Central

Gao, Ming; Ma, Liran; Liang, Yong; Gao, Yuan; Luo, Jianbin

2015-01-01

Nanoscale scientific issues have attracted an increasing amount of research interest due to their specific size-effect and novel structure-property. From macro to nano, materials present some unique chemical reactivity that bulk materials do not own. Here we introduce a facile method to generate silicate with nanoscale control based on the establishment of a confined space between a meso/nanoscale tungsten tip and a smooth silica/silicon substrate. During the process, local water-like droplets deposition can be obviously observed in the confinement between the Si/SiO2 surfaces and the KOH-modified tungsten tip. By the combination of in-situ optical microscopy and Raman spectroscopy, we were able to take a deep insight of both the product composition and the underlying mechanism of such phenomena. It was indicated that such nanoreactor for silicate could be quite efficient as a result of the local capillarity and electric field effect, with implications at both nano and meso scales. PMID:26364882

Parallel RNA extraction using magnetic beads and a droplet array.

PubMed

Shi, Xu; Chen, Chun-Hong; Gao, Weimin; Chao, Shih-Hui; Meldrum, Deirdre R

2015-02-21

Nucleic acid extraction is a necessary step for most genomic/transcriptomic analyses, but it often requires complicated mechanisms to be integrated into a lab-on-a-chip device. Here, we present a simple, effective configuration for rapidly obtaining purified RNA from low concentration cell medium. This Total RNA Extraction Droplet Array (TREDA) utilizes an array of surface-adhering droplets to facilitate the transportation of magnetic purification beads seamlessly through individual buffer solutions without solid structures. The fabrication of TREDA chips is rapid and does not require a microfabrication facility or expertise. The process takes less than 5 minutes. When purifying mRNA from bulk marine diatom samples, its repeatability and extraction efficiency are comparable to conventional tube-based operations. We demonstrate that TREDA can extract the total mRNA of about 10 marine diatom cells, indicating that the sensitivity of TREDA approaches single-digit cell numbers.

Parallel RNA extraction using magnetic beads and a droplet array

PubMed Central

Shi, Xu; Chen, Chun-Hong; Gao, Weimin; Meldrum, Deirdre R.

2015-01-01

Nucleic acid extraction is a necessary step for most genomic/transcriptomic analyses, but it often requires complicated mechanisms to be integrated into a lab-on-a-chip device. Here, we present a simple, effective configuration for rapidly obtaining purified RNA from low concentration cell medium. This Total RNA Extraction Droplet Array (TREDA) utilizes an array of surface-adhering droplets to facilitate the transportation of magnetic purification beads seamlessly through individual buffer solutions without solid structures. The fabrication of TREDA chips is rapid and does not require a microfabrication facility or expertise. The process takes less than 5 minutes. When purifying mRNA from bulk marine diatom samples, its repeatability and extraction efficiency are comparable to conventional tube-based operations. We demonstrate that TREDA can extract the total mRNA of about 10 marine diatom cells, indicating that the sensitivity of TREDA approaches single-digit cell numbers. PMID:25519439

Photon Doppler Velocimeter to Measure Entrained Additive Manufactured Bulk Metal Powders in Hot Subsonic and Supersonic Oxygen Gas

NASA Technical Reports Server (NTRS)

Tylka, Jonathan

2016-01-01

Parts produced by additive manufacturing, particularly selective laser melting (SLM), have been shown to silt metal particulate even after undergoing stringent precision aerospace cleaning processes (Lowrey 2016). As printed parts are used in oxygen systems with increased pressures, temperatures, and gas velocity, the risk of ignition by particle impact, the most common direct ignition source of metals in oxygen, substantially increases. The White Sands Test Facility (WSTF), in collaboration with Marshall Space Flight Center (MSFC), desires to test the ignitability of SLM metals by particle impact in heated oxygen. The existing test systems rely on gas velocity calculations to infer particle velocity in both subsonic and supersonic particle impact systems. Until now, it was not possible to directly measure particle velocity. To increase the fidelity of planned SLM ignition studies, it is necessary to validate that the Photon Doppler Velocimetry(PDV) test system can accurately measure particle velocity.

Waste Handling and Emplacement Options for Disposal of Radioactive Waste in Deep Boreholes.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cochran, John R.; Hardin, Ernest

2015-11-01

Traditional methods cannot be used to handle and emplace radioactive wastes in boreholes up to 16,400 feet (5 km) deep for disposal. This paper describes three systems that can be used for handling and emplacing waste packages in deep borehole: (1) a 2011 reference design that is based on a previous study by Woodward–Clyde in 1983 in which waste packages are assembled into “strings” and lowered using drill pipe; (2) an updated version of the 2011 reference design; and (3) a new concept in which individual waste packages would be lowered to depth using a wireline. Emplacement on coiled tubingmore » was also considered, but not developed in detail. The systems described here are currently designed for U.S. Department of Energy-owned high-level waste (HLW) including the Cesium- 137/Strontium-90 capsules from the Hanford Facility and bulk granular HLW from fuel processing in Idaho.« less

An airport cargo inspection system based on X-ray and thermal neutron analysis (TNA).

PubMed

Ipe, Nisy E; Akery, A; Ryge, P; Brown, D; Liu, F; Thieu, J; James, B

2005-01-01

A cargo inspection system incorporating a high-resolution X-ray imaging system with a material-specific detection system based on Ancore Corporation's patented thermal neutron analysis (TNA) technology can detect bulk quantities of explosives and drugs concealed in trucks or cargo containers. The TNA process utilises a 252Cf neutron source surrounded by a moderator. The neutron interactions with the inspected object result in strong and unique gamma-ray signals from nitrogen, which is a key ingredient in modern high explosives, and from chlorinated drugs. The TNA computer analyses the gamma-ray signals and automatically determines the presence of explosives or drugs. The radiation source terms and shielding design of the facility are described. For the X-ray generator, the primary beam, leakage radiation, and scattered primary and leakage radiation were considered. For the TNA, the primary neutrons and tunnel scattered neutrons as well as the neutron-capture gamma rays were considered.

Crystal nucleation and glass formation in metallic alloy melts

NASA Technical Reports Server (NTRS)

Spaepen, F.

1984-01-01

Homogeneous nucleation, containerless solidification, and bulk formation of metallic glasses are discussed. Homogeneous nucleation is not a limiting factor for metallic glass formation at slow cooling rates if the reduced glass transition temperature is high enough. Such glasses can be made in bulk if heterogeneous nucleants are removed. Containerless processing eleminates potential sources of nucleants, but as drop tube experiments on the Pd-Si alloys show, the free surface may still be a very effective heterogeneous nucleant. Combination of etching and heating in vacuum or fluxing can be effective for cleaning fairly large ingots of nucleants. Reduced gravity processing has a potentially useful role in the fluxing technique, for example to keep large metallic ingots surrounded by a low density, low fluidity flux if this proved difficult under ground conditions. For systems where heterogeneous nucleants in the bulk of the ingot need gravity to segregate to the flux-metal interface, reduced gravity processing may not be appropriate for bulk glass formation.

Technical Information on the Carbonation of the EBR-II Reactor, Summary Report Part 1: Laboratory Experiments and Application to EBR-II Secondary Sodium System

DOE Office of Scientific and Technical Information (OSTI.GOV)

Steven R. Sherman

Residual sodium is defined as sodium metal that remains behind in pipes, vessels, and tanks after the bulk sodium metal has been melted and drained from such components. The residual sodium has the same chemical properties as bulk sodium, and differs from bulk sodium only in the thickness of the sodium deposit. Typically, sodium is considered residual when the thickness of the deposit is less than 5-6 cm. This residual sodium must be removed or deactivated when a pipe, vessel, system, or entire reactor is permanently taken out of service, in order to make the component or system safer and/ormore » to comply with decommissioning regulations. As an alternative to the established residual sodium deactivation techniques (steam-and-nitrogen, wet vapor nitrogen, etc.), a technique involving the use of moisture and carbon dioxide has been developed. With this technique, sodium metal is converted into sodium bicarbonate by reacting it with humid carbon dioxide. Hydrogen is emitted as a by-product. This technique was first developed in the laboratory by exposing sodium samples to humidified carbon dioxide under controlled conditions, and then demonstrated on a larger scale by treating residual sodium within the Experimental Breeder Reactor II (EBR-II) secondary cooling system, followed by the primary cooling system, respectively. The EBR-II facility is located at the Idaho National Laboratory (INL) in southeastern Idaho, U.S.A. This report is Part 1 of a two-part report. It is divided into three sections. The first section describes the chemistry of carbon dioxide-water-sodium reactions. The second section covers the laboratory experiments that were conducted in order to develop the residual sodium deactivation process. The third section discusses the application of the deactivation process to the treatment of residual sodium within the EBR-II secondary sodium cooling system. Part 2 of the report, under separate cover, describes the application of the technique to residual sodium treatment within the EBR-II primary sodium cooling system and related systems.« less

Manufacture of bulk superconducting YBa2Cu3O(7-delta) by a continuous process

NASA Technical Reports Server (NTRS)

Meng, R. L.; Kinalidis, C.; Sun, Y. Y.; Gao, L.; Tao, Y. K.

1990-01-01

The development of a continuous process for fabricating large bulk superconductors with a predetermined grain orientation is reported. A bar of the 123 compound with dimensions 5 x 0.5 x about 0.3 cm with excellent grain alignment has been fabricated continuously. The bulk 123 thus obtained has magnetically determined J(c)s of about 30,000 and 12,000 A/sq cm at 0 and 1 T, respectively, and transport J(c)s of 20,000, 11,000, and 7500 A-sq cm at 0, 0.54, and 0.83 T.

Trapped magnetic field of a mini-bulk magnet using YBaCuO at 77 K

NASA Astrophysics Data System (ADS)

Fujimoto, Hiroyuki; Kamijo, Hiroki

2001-09-01

Melt-processed rare earth (RE)123 superconductors have a high Jc at 77 K and high magnetic field. Solidification processes for producing (L)RE123 superconductors and pinning centers in the (L)RE123 matrix are effective for obtaining high Jc, leading to high-field application as a superconducting quasi-permanent bulk magnet with the liquid nitrogen refrigeration. One of the promising applications is a superconducting magnet for the magnetically levitated train. We fabricated a mini-superconducting bulk magnet of 200×100 mm2, consisting of 18 bulks, which are a square 33 mm on a side and 10 mm in thickness, and magnetized the mini-magnet by field cooling. The mini-magnet showed the trapped magnetic field of larger than 0.1 T on the surface of the outer vessel of the magnet. The present preliminary study discusses trapped magnetic field properties of the mini-bulk magnet using YBaCuO superconductors at 77 K.

Low temperature diffusion process using rare earth-Cu eutectic alloys for hot-deformed Nd-Fe-B bulk magnets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Akiya, T., E-mail: akiya.takahiro@nims.go.jp; Sepehri-Amin, H.; Ohkubo, T.

2014-05-07

The low temperature grain boundary diffusion process using RE{sub 70}Cu{sub 30} (RE = Pr, Nd) eutectic alloy powders was applied to sintered and hot-deformed Nd-Fe-B bulk magnets. Although only marginal coercivity increase was observed in sintered magnets, a substantial enhancement in coercivity was observed when the process was applied to hot-deformed anisotropic bulk magnets. Using Pr{sub 70}Cu{sub 30} eutectic alloy as a diffusion source, the coercivity was enhanced from 1.65 T to 2.56 T. The hot-deformed sample expanded along c-axis direction only after the diffusion process as RE rich intergranular layers parallel to the broad surface of the Nd{sub 2}Fe{sub 14}B are thickened inmore » the c-axis direction.« less

Attrition resistant bulk iron catalysts and processes for preparing and using same

DOEpatents

Jothimurugesan, Kandaswamy [Ponca City, OK; Goodwin, Jr., James G.; Gangwal, Santosh K [Cary, NC

2007-08-21

An attrition resistant precipitated bulk iron catalyst is prepared from iron oxide precursor and a binder by spray drying. The catalysts are preferably used in carbon monoxide hydrogenation processes such as Fischer-Tropsch synthesis. These catalysts are suitable for use in fluidized-bed reactors, transport reactors and, especially, slurry bubble column reactors.

Method of forming crystalline silicon devices on glass

DOEpatents

McCarthy, A.M.

1995-03-21

A method is disclosed for fabricating single-crystal silicon microelectronic components on a silicon substrate and transferring same to a glass substrate. This is achieved by utilizing conventional silicon processing techniques for fabricating components of electronic circuits and devices on bulk silicon, wherein a bulk silicon surface is prepared with epitaxial layers prior to the conventional processing. The silicon substrate is bonded to a glass substrate and the bulk silicon is removed leaving the components intact on the glass substrate surface. Subsequent standard processing completes the device and circuit manufacturing. This invention is useful in applications requiring a transparent or insulating substrate, particularly for display manufacturing. Other applications include sensors, actuators, optoelectronics, radiation hard electronics, and high temperature electronics. 7 figures.

Novel configuration of processing bulk textured YB 2Cu 3O 7-x superconductor by seeded infiltration growth method

NASA Astrophysics Data System (ADS)

Cao, Haitao; Moutalbi, Nahed; Harnois, Christelle; Hu, Rui; Li, Jinshan; Zhou, Lian; Noudem, Jacques G.

2010-01-01

Mono-domain YBa 2Cu 3O 7-x (Y123) bulk superconductors have been processed using seeded infiltration growth technique (SIG). The combination of melt infiltrated liquid source (Ba 3Cu 5O 8) into the Y 2BaCuO 5 (Y211) pre-form and the nucleation of Y123 domain from SmBa 2Cu 3O 7 crystal seed has been investigated. The different configurations of SIG process were compared in this study. In addition, the effect of the starting Y211 particles size has been studied. The results reveal that, the Y211 particle size and different configurations strongly influence the properties of the final bulk superconductor sample.

Tritium plume dynamics in the shallow unsaturated zone in an arid environment

USGS Publications Warehouse

Maples, S.R.; Andraski, Brian J.; Stonestrom, David A.; Cooper, C.A.; Pohll, G.; Michel, R.L.

2014-01-01

The spatiotemporal variability of a tritium plume in the shallow unsaturated zone and the mechanisms controlling its transport were evaluated during a 10-yr study. Plume movement was minimal and its mass declined by 68%. Upward-directed diffusive-vapor tritium fluxes and radioactive decay accounted for most of the observed plume-mass declines.Effective isolation of tritium (3H) and other contaminants at waste-burial facilities requires improved understanding of transport processes and pathways. Previous studies documented an anomalously widespread (i.e., theoretically unexpected) distribution of 3H (>400 m from burial trenches) in a dry, sub-root-zone gravelly layer (1–2-m depth) adjacent to a low-level radioactive waste (LLRW) burial facility in the Amargosa Desert, Nevada, that closed in 1992. The objectives of this study were to: (i) characterize long-term, spatiotemporal variability of 3H plumes; and (ii) quantify the processes controlling 3H behavior in the sub-root-zone gravelly layer beneath native vegetation adjacent to the facility. Geostatistical methods, spatial moment analyses, and mass flux calculations were applied to a spatiotemporally comprehensive, 10-yr data set (2001–2011). Results showed minimal bulk-plume advancement during the study period and limited Fickian spreading of mass. Observed spreading rates were generally consistent with theoretical vapor-phase dispersion. The plume mass diminished more rapidly than would be expected from radioactive decay alone, indicating net efflux from the plume. Estimates of upward 3H efflux via diffusive-vapor movement were >10× greater than by dispersive-vapor or total-liquid movement. Total vertical fluxes were >20× greater than lateral diffusive-vapor fluxes, highlighting the importance of upward migration toward the land surface. Mass-balance calculations showed that radioactive decay and upward diffusive-vapor fluxes contributed the majority of plume loss. Results indicate that plume losses substantially exceeded any continuing 3H contribution to the plume from the LLRW facility during 2001 to 2011 and suggest that the widespread 3H distribution resulted from transport before 2001.

Advanced Land Imager Assessment System

NASA Technical Reports Server (NTRS)

Chander, Gyanesh; Choate, Mike; Christopherson, Jon; Hollaren, Doug; Morfitt, Ron; Nelson, Jim; Nelson, Shar; Storey, James; Helder, Dennis; Ruggles, Tim;

Enhanced bulk heterojunction devices prepared by thermal and solvent vapor annealing processes

DOEpatents

Forrest, Stephen R.; Thompson, Mark E.; Wei, Guodan; Wang, Siyi

2017-09-19

A method of preparing a bulk heterojunction organic photovoltaic cell through combinations of thermal and solvent vapor annealing are described. Bulk heterojunction films may prepared by known methods such as spin coating, and then exposed to one or more vaporized solvents and thermally annealed in an effort to enhance the crystalline nature of the photoactive materials.

The effects of changing deposition conditions on the similarity of sputter-deposited fluorocarbon thin films to bulk PTFE

NASA Astrophysics Data System (ADS)

Zandona, Philip

Solid lubrication of space-borne mechanical components is essential to their survival and the continued human exploration of space. Recent discoveries have shown that PTFE when blended with alumina nanofillers exhibits greatly improved physical performance properties, with wear rates being reduced by several orders of magnitude. The bulk processes used to produce the PTFE-alumina blends are limiting. Co-sputter deposition of PTFE and a filler material overcomes several of these limitations by enabling the reduction of particle size to the atomic level and also by allowing for the even coating of the solid lubricant on relatively large areas and components. The goal of this study was to establish a baseline performance of the sputtered PTFE films as compared to the bulk material, and to establish deposition conditions that would result in the most bulk-like film possible. In order to coax change in the structure of the sputtered films, sputtering power and deposition temperature were increased independently. Further, post-deposition annealing was applied to half of the deposited film in an attempt to affect change in the film structure. Complications in the characterization process due to increasing film thickness were also examined. Bulk-like metrics for characterization processes the included Fourier transform infrared spectroscopy (FTIR), X-ray spectroscopy (XPS), nanoindentation via atomic force microscopy, and contact angle of water on surface measurements were established. The results of the study revealed that increasing sputtering power and deposition temperature resulted in an increase in the similarity between the fluorocarbon films and the bulk PTFE, at a cost of affecting the potential of the film thicknesses, either by affecting the deposition process directly, or by decreasing the longevity of the sputtering targets.

Field observations of the developing legal recreational cannabis economy in Washington State.

PubMed

Jensen, Eric L; Roussell, Aaron

2016-07-01

Washington State legalized the sale of recreational cannabis in 2012. This paper describes the unfolding of the market regulatory regime in an eastern portion of the state, including field descriptions to illustrate the setting. We made observations and conducted interviews of the local supply chain comprising a producer/processor, analytic facility, and retail establishments as well as querying the state director of the regulatory board. Interviews and observations of facilities suggest an overwhelming concern for black market diversion drives state regulatory efforts. The ongoing dialogue between market actors and the state has resulted in a more equitable distribution of profits at different stages in the process. State safety regulations have thus far been shifted to independent laboratories. Banks and insurance companies have slowly begun making inroads into the industry, despite federal prohibition. The law was conceived as a social justice remedy, but the bulk of the legal and regulatory activity surrounds cannabis marketplace management. This has been characterized by concerns for black market diversion, producer/processor profits, and a hands-off approach to safety regulation. Minor cannabis violations as a pathway to criminal justice system involvement have been reduced substantially but disproportionate enforcement upon racial/ethnic minorities continues. Copyright © 2016 Elsevier B.V. All rights reserved.

An IAEA multi-technique X-ray spectrometry endstation at Elettra Sincrotrone Trieste: benchmarking results and interdisciplinary applications.

PubMed

Karydas, Andreas Germanos; Czyzycki, Mateusz; Leani, Juan José; Migliori, Alessandro; Osan, Janos; Bogovac, Mladen; Wrobel, Pawel; Vakula, Nikita; Padilla-Alvarez, Roman; Menk, Ralf Hendrik; Gol, Maryam Ghahremani; Antonelli, Matias; Tiwari, Manoj K; Caliri, Claudia; Vogel-Mikuš, Katarina; Darby, Iain; Kaiser, Ralf Bernd

2018-01-01

The International Atomic Energy Agency (IAEA) jointly with the Elettra Sincrotrone Trieste (EST) operates a multipurpose X-ray spectrometry endstation at the X-ray Fluorescence beamline (10.1L). The facility has been available to external users since the beginning of 2015 through the peer-review process of EST. Using this collaboration framework, the IAEA supports and promotes synchrotron-radiation-based research and training activities for various research groups from the IAEA Member States, especially those who have limited previous experience and resources to access a synchrotron radiation facility. This paper aims to provide a broad overview about various analytical capabilities, intrinsic features and performance figures of the IAEA X-ray spectrometry endstation through the measured results. The IAEA-EST endstation works with monochromatic X-rays in the energy range 3.7-14 keV for the Elettra storage ring operating at 2.0 or 2.4 GeV electron energy. It offers a combination of different advanced analytical probes, e.g. X-ray reflectivity, X-ray absorption fine-structure measurements, grazing-incidence X-ray fluorescence measurements, using different excitation and detection geometries, and thereby supports a comprehensive characterization for different kinds of nanostructured and bulk materials.

A Facile Method to Fabricate Anisotropic Hydrogels with Perfectly Aligned Hierarchical Fibrous Structures.

PubMed

Mredha, Md Tariful Islam; Guo, Yun Zhou; Nonoyama, Takayuki; Nakajima, Tasuku; Kurokawa, Takayuki; Gong, Jian Ping

2018-03-01

Natural structural materials (such as tendons and ligaments) are comprised of multiscale hierarchical architectures, with dimensions ranging from nano- to macroscale, which are difficult to mimic synthetically. Here a bioinspired, facile method to fabricate anisotropic hydrogels with perfectly aligned multiscale hierarchical fibrous structures similar to those of tendons and ligaments is reported. The method includes drying a diluted physical hydrogel in air by confining its length direction. During this process, sufficiently high tensile stress is built along the length direction to align the polymer chains and multiscale fibrous structures (from nano- to submicro- to microscale) are spontaneously formed in the bulk material, which are well-retained in the reswollen gel. The method is useful for relatively rigid polymers (such as alginate and cellulose), which are susceptible to mechanical signal. By controlling the drying with or without prestretching, the degree of alignment, size of superstructures, and the strength of supramolecular interactions can be tuned, which sensitively influence the strength and toughness of the hydrogels. The mechanical properties are comparable with those of natural ligaments. This study provides a general strategy for designing hydrogels with highly ordered hierarchical structures, which opens routes for the development of many functional biomimetic materials for biomedical applications. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bulk shielding facility quarterly report, October, November, and December 1976

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hurt, III, S. S.; Lance, E. D.; Thomas, J. R.

1977-08-01

The BSR operated at an average power level of 1,836 kw for 78.01 percent of the time during October, November, and December. Water-quality control in both the reactor primary and secondary cooling systems was satisfactory. The PCA was used in training programs and was operated on two occasions when the University of Kentucky students actively participated in training laboratories.

Bulk Fuel Storage Facility Cape Canaveral Air Force Station, Florida. Environmental Assessment

DTIC Science & Technology

2006-11-01

Potential DESC Fuel Depot Locations............................................2-7 Figure 2-5: Proposed Action Area Soils Map ... Area (FSA) #4, as the location is required to provide secure office space. 4) Maintain fuel operations in compliance with federal, state, and local...at the CCAFS fueling station(s) to Aboveground Storage Tanks (ASTs). Six alternative sites (five locations in the CCAFS Industrial Area and one

Recent developments in melt processed Gd-123 and MgB2 materials at RTRI

NASA Astrophysics Data System (ADS)

Muralidhar, M.; Fukumoto, Y.; Ishihara, A.; Suzuki, K.; Tomita, M.; Koblischka, M. R.; Yamamoto, A.; Kishio, K.

2014-01-01

In this contribution we will report on the current status, recent developments in GdBa2Cu3Oy "Gd-123" and MgB2 material processing, characterization, and applications at the Railway Technical Research Institute (RTRI). Batch-processing of Gd-123 bulk material grown in air was performed using novel thin film Nd-123 seeds grown on MgO crystals. In this way, we are able to fabricate materials with good quality, and uniform performance. We examined the technology of the uniform performance of the large 45 mm diameter, single grain Gd-123 bulks for use in application of NMR. For this purpose, four 5 mm thick pieces are cut vertically from a single grain Gd-123 material and the magnetic field distribution is measured using a scanning hall sensor. We found that all four pieces are single domain and exhibit a quite uniform field distribution. Furthermore, the batch-processed bulk materials are used for the construction of a chilled Maglev vehicle. On the other hand, to optimize the trapped field performance of bulk MgB2 material, several samples were prepared by solid state reaction at different temperatures ranging from 750 to 950 °C in pure argon atmosphere. X-ray diffraction results indicated that single phase and homogenous MgB2 bulks are produced when sintering them around 775 °C. Further, atomic force microscopy (AFM) and scanning electron microscopy (SEM) indicated that an uniform grain size results by controlling the processing temperature. So, higher trapped fields can be achieved in sintered MgB2 material.

Ductile Damage and Fatigue Behavior of Semi-Finished Tailored Blanks for Sheet-Bulk Metal Forming Processes

NASA Astrophysics Data System (ADS)

Besserer, Hans-Bernward; Hildenbrand, Philipp; Gerstein, Gregory; Rodman, Dmytro; Nürnberger, Florian; Merklein, Marion; Maier, Hans Jürgen

2016-03-01

To produce parts from sheet metal with thickened functional elements, bulk forming operations can be employed. For this new process class, the term sheet-bulk metal forming has been established recently. Since sheet-bulk metal forming processes such as orbital forming generates triaxial stress and strain states, ductile damage is induced in the form of voids in the microstructure. Typical parts will experience cyclic loads during service, and thus, the influence of ductile damage on the fatigue life of parts manufactured by orbital forming is of interest. Both the formation and growth of voids were characterized following this forming process and then compared to the as-received condition of the ferritic deep drawing steel DC04 chosen for this study. Subsequent to the forming operation, the specimens were fatigued and the evolution of ductile damage and the rearrangement of the dislocation networks occurring during cyclic loading were determined. It was shown, that despite an increased ductile damage due to the forming process, the induced strain hardening has a positive effect on the fatigue life of the material. However, by analyzing the fatigued specimens a development of the ductile damage by an increasing number of voids and a change in the void shape were detected.

Magnetic Signals of High-Temperature Superconductor Bulk During the Levitation Force Measurement Process

NASA Astrophysics Data System (ADS)

Huang, Huan; Zheng, Jun; Qian, Nan; Che, Tong; Zheng, Botian; Jin, Liwei; Deng, Zigang

2017-05-01

In order to study the commonly neglected magnetic field information in the course of levitation force measurement process in a superconducting maglev system, a multipoint magnetic field measurement platform was employed to acquire magnetic signals of a bulk high-Tc superconductor on both the top and the bottom surface. Working conditions including field cooling (FC) and zero field cooling were investigated for these vertical down and up motions above a permanent magnet guideway performed on a HTS maglev measurement system. We have discussed the magnetic flux variation process based on the Bean model. A magnetic hysteresis effect similar to the levitation force hysteresis loop of the bulk superconductor was displayed and analyzed in this paper. What is more valuable, there exists some available magnetic flux on the top surface of the bulk superconductor, and the proportion is as high as 62.42% in the FC condition, which provides an experimental hint to design the superconductor bulk and the applied field for practical use in a more efficient way. In particular, this work reveals real-time magnetic flux variation of the bulk superconductor in the levitation application, which is the other important information in contrast to the macroscopic levitation and guidance force investigations in previous studies, and it enriches the existing research methods. The results are significant for understanding the magnetic characteristic of superconductors, and they can contribute to optimize the present HTS maglev system design.

Experimental Investigations of the Physical and Optical Properties of Individual Micron/Submicron-Size Dust Grains in Astrophysical Environments

NASA Technical Reports Server (NTRS)

Abbas, M. M.; Tankosic, D.; LeClair, A.

2014-01-01

Dust grains constitute a significant component of matter in the universe, and play an important and crucial role in the formation and evolution of the stellar/planetary systems in interstellar dust clouds. Knowledge of physical and optical properties of dust grains is required for understanding of a variety of processes in astrophysical and planetary environments. The currently available and generally employed data on the properties of dust grains is based on bulk materials, with analytical models employed to deduce the corresponding values for individual small micron/submicron-size dust grains. However, it has been well-recognized over a long period, that the properties of individual smallsize dust grains may be very different from those deduced from bulk materials. This has been validated by a series of experimental investigations carried out over the last few years, on a laboratory facility based on an Electrodynamic Balance at NASA, which permits levitation of single small-size dust grains of desired composition and size, in vacuum, in simulated space environments. In this paper, we present a brief review of the results of a series of selected investigations carried out on the analogs of interstellar and planetary dust grains, as well as dust grains obtained by Apollo-l1-17 lunar missions. The selected investigations, with analytical results and discussions, include: (a) Direct measurements of radiation on individual dust grains (b) Rotation and alignments of dust grains by radiative torque (c) Charging properties of dust grains by: (i) UV Photo-electric emissions (ii) Electron Impact. The results from these experiments are examined in the light of the current theories of the processes involved.

Study of the Effects of the Electric Field on Charging Measurements on Individual Micron-size Dust Grains by Secondary Electron Emissions

NASA Technical Reports Server (NTRS)

Tankosic, D.; Abbas, M. M.

2013-01-01

The dust charging by electron impact is an important dust charging process in Astrophysical, Planetary, and the Lunar environments. Low energy electrons are reflected or stick to the grains charging the dust grains negatively. At sufficiently high energies electrons penetrate the grain leading to excitation and emission of electrons referred to as secondary electron emission (SEE). Available theoretical models for the calculation of SEE yield applicable for neutral, planar or bulk surfaces are generally based on Sternglass Equation. However, viable models for charging of individual dust grains do not exist at the present time. Therefore, the SEE yields have to be obtained by some experimental methods at the present time. We have conducted experimental studies on charging of individual micron size dust grains in simulated space environments using an electrodynamic balance (EDB) facility at NASA-MSFC. The results of our extensive laboratory study of charging of individual micron-size dust grains by low energy electron impact indicate that the SEE by electron impact is a very complex process expected to be substantially different from the bulk materials. It was found that the incident electrons may lead to positive or negative charging of dust grains depending upon the grain size, surface potential, electron energy, electron flux, grain composition, and configuration. In this paper we give a more elaborate discussion about the possible effects of the AC field in the EDB on dust charging measurements by comparing the secondary electron emission time-period (tau (sub em) (s/e)) with the time-period (tau (sub ac) (ms)) of the AC field cycle in the EDB that we have briefly addressed in our previous publication.

Spherical nitroguanidine process

DOEpatents

Sanchez, John A.; Roemer, Edward L.; Stretz, Lawrence A.

1990-01-01

A process of preparing spherical high bulk density nitroguanidine by dissing low bulk density nitroguanidine in N-methyl pyrrolidone at elevated temperatures and then cooling the solution to lower temperatures as a liquid characterized as a nonsolvent for the nitroguanidine is provided. The process is enhanced by inclusion in the solution of from about 1 ppm up to about 250 ppm of a metal salt such as nickel nitrate, zinc nitrate or chromium nitrate, preferably from about 20 to about 50 ppm.

Process parameters, orientation, and functional properties of melt-processed bulk Y-Ba-Cu-O superconductors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zakharchenko, I.V.; Terryll, K.M.; Rao, K.V.

1995-03-01

This study compared the microstructure, texturing, and functional properties (critical currents) of YBa{sub 2}Cu{sub 3}O{sub 7{minus}x}-based bulk pellets that were prepared by the quench-melt-growth-process (QMGP), melt-textured growth (MTG), and conventional solid-state reaction (SSR) approaches. Using two X-ray diffraction (XRD) methods, {theta}-2{theta}, and rocking curves, the authors found that the individual grains of two melt-processed pellets exhibited remarkable preferred orientational alignment (best rocking curve width = 3.2{degree}). However, the direction of the preferred orientation among the grains was random. Among the three types of bulk materials studied, the QMGP sample was found to have the best J{sub c} values, {approx} 4,500more » A/cm{sup 2} at 77 K in a field of 2 kG, as determined from SQUID magnetic data.« less

Economic impact of storage and handling regulations on retail fertilizer and pesticide firms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Akridge, J.T.; Rogers, D.S.

1994-12-31

A budgeting model was developed to estimate the cost of retailing dry bulk fertilizer, liquid bulk fertilizer, anhydrous ammonia, and pesticides for three sizes of facilities. Estimates were obtained of the cost to upgrade each of the model plants to comply with Indiana`s recently enacted regulations on the handling and storage of fertilizers and pesticides. In addition, various strategies (increasing price and increasing volume) that dealers might employ to rationalize these investments were assessed. Results suggest that there are significant scale economies associated with the regulations and that smaller plants will have a more difficult time rationalizing the investment thanmore » larger plants. Dealers will need to consider a range of strategies to offset the increase in annual operating costs resulting from these environmental investments.« less

Thermal conductivity measurements of epoxy systems at low temperature

NASA Astrophysics Data System (ADS)

Rondeaux, F.; Bredy, Ph.; Rey, J. M.

2002-05-01

We have developed a specific thermal conductivity measurement facility for solid materials at low temperature (LHe and LN2). At present, the Measurement of Thermal Conductivity of Insulators (MECTI) facility performs measurements on epoxy resin, as well as on bulk materials such as aluminum alloy and on insulators developed at Saclay. Thermal conductivity measurements on pre-impregnated fiber-glass epoxy composite are presented in the temperature range of 4.2 K to 14 K for different thicknesses in order to extract the thermal boundary resistance. We also present results obtained on four different bonding glues (Stycast 2850 FT, Poxycomet F, DP190, Eccobond 285) in the temperature range of 4.2 K to 10 K.

Vorticity in heavy-ion collisions at the JINR Nuclotron-based Ion Collider fAcility

NASA Astrophysics Data System (ADS)

Ivanov, Yu. B.; Soldatov, A. A.

2017-05-01

Vorticity of matter generated in noncentral heavy-ion collisions at energies of the Nuclotron-based Ion Collider fAcility (NICA) at the Joint Institute for Nuclear Research (JINR) in Dubna is studied. Simulations are performed within the model of the three-fluid dynamics (3FD) which reproduces the major part of bulk observables at these energies. Comparison with earlier calculations is done. The qualitative pattern of the vorticity evolution is analyzed. It is demonstrated that the vorticity is mainly located at the border between participants and spectators. In particular, this implies that the relative Λ -hyperon polarization should be stronger at rapidities of the fragmentation regions than that in the midrapidity region.

Processing of Bulk YBa2Cu3O(7-x) High Temperature Superconductor Materials for Gravity Modification Experiments and Performance Under AC Levitation

NASA Technical Reports Server (NTRS)

Koczor, Ronald; Noever, David; Hiser, Robert

1999-01-01

We have previously reported results using a high precision gravimeter to probe local gravity changes in the neighborhood of bulk-processed high temperature superconductor disks. Others have indicated that large annular disks (on the order of 25cm diameter) and AC levitation fields play an essential role in their observed experiments. We report experiments in processing such large bulk superconductors. Successful results depend on material mechanical characteristics, and pressure and heat treat protocols. Annular disks having rough dimensions of 30cm O.D., 7cm I.D. and 1 cm thickness have been routinely fabricated and tested under AC levitation fields ranging from 45 to 300OHz. Implications for space transportation initiatives and power storage flywheel technology will be discussed.

Predictive Simulation of Process Windows for Powder Bed Fusion Additive Manufacturing: Influence of the Powder Bulk Density.

PubMed

Rausch, Alexander M; Küng, Vera E; Pobel, Christoph; Markl, Matthias; Körner, Carolin

2017-09-22

The resulting properties of parts fabricated by powder bed fusion additive manufacturing processes are determined by their porosity, local composition, and microstructure. The objective of this work is to examine the influence of the stochastic powder bed on the process window for dense parts by means of numerical simulation. The investigations demonstrate the unique capability of simulating macroscopic domains in the range of millimeters with a mesoscopic approach, which resolves the powder bed and the hydrodynamics of the melt pool. A simulated process window reveals the influence of the stochastic powder layer. The numerical results are verified with an experimental process window for selective electron beam-melted Ti-6Al-4V. Furthermore, the influence of the powder bulk density is investigated numerically. The simulations predict an increase in porosity and surface roughness for samples produced with lower powder bulk densities. Due to its higher probability for unfavorable powder arrangements, the process stability is also decreased. This shrinks the actual parameter range in a process window for producing dense parts.

Predictive Simulation of Process Windows for Powder Bed Fusion Additive Manufacturing: Influence of the Powder Bulk Density

PubMed Central

Rausch, Alexander M.; Küng, Vera E.; Pobel, Christoph; Körner, Carolin

2017-01-01

The resulting properties of parts fabricated by powder bed fusion additive manufacturing processes are determined by their porosity, local composition, and microstructure. The objective of this work is to examine the influence of the stochastic powder bed on the process window for dense parts by means of numerical simulation. The investigations demonstrate the unique capability of simulating macroscopic domains in the range of millimeters with a mesoscopic approach, which resolves the powder bed and the hydrodynamics of the melt pool. A simulated process window reveals the influence of the stochastic powder layer. The numerical results are verified with an experimental process window for selective electron beam-melted Ti-6Al-4V. Furthermore, the influence of the powder bulk density is investigated numerically. The simulations predict an increase in porosity and surface roughness for samples produced with lower powder bulk densities. Due to its higher probability for unfavorable powder arrangements, the process stability is also decreased. This shrinks the actual parameter range in a process window for producing dense parts. PMID:28937633

Facile One-Step Synthesis of Hybrid Graphitic Carbon Nitride and Carbon Composites as High-Performance Catalysts for CO2 Photocatalytic Conversion.

PubMed

Wang, Yangang; Bai, Xia; Qin, Hengfei; Wang, Fei; Li, Yaguang; Li, Xi; Kang, Shifei; Zuo, Yuanhui; Cui, Lifeng

2016-07-13

Utilizing and reducing carbon dioxide is a key target in the fight against global warming. The photocatalytic performance of bulk graphitic carbon nitride (g-C3N4) is usually limited by its low surface area and rapid charge carrier recombination. To develop g-C3N4 more suitable for photocatalysis, researchers have to enlarge its surface area and accelerate the charge carrier separation. In this work, novel hybrid graphitic carbon nitride and carbon (H-g-C3N4/C) composites with various carbon contents have been developed for the first time by a facile one-step pyrolysis method using melamine and natural soybean oil as precursors. The effect of carbon content on the structure of H-g-C3N4/C composites and the catalytic activity for the photoreduction of CO2 with H2O were investigated. The results indicated that the introduction of carbon component can effectively improve the textural properties and electronic conductivity of the composites, which exhibited imporved photocatalytic activity for the reduction of CO2 with H2O in comparison with bulk g-C3N4. The highest CO and CH4 yield of 22.60 μmol/g-cat. and 12.5 μmol/g-cat., respectively, were acquired on the H-g-C3N4/C-6 catalyst with the carbon content of 3.77 wt % under 9 h simulated solar irradiation, which were more than twice as high as that of bulk g-C3N4. The remarkably increased photocatalytic performance arises from the synergistic effect of hybrid carbon and g-C3N4.

The effect of refrigerated and frozen storage on butter flavor and texture.

PubMed

Krause, A J; Miracle, R E; Sanders, T H; Dean, L L; Drake, M A

2008-02-01

Butter is often stored for extended periods of time; therefore, it is important for manufacturers to know the refrigerated and frozen shelf life. The objectives of this study were to characterize the effect of refrigerated and frozen storage on the sensory and physical characteristics of butter. Fresh butter was obtained on 2 occasions from 2 facilities in 113-g sticks and 4-kg bulk blocks (2 facilities, 2 package forms). Butters were placed into both frozen (-20 degrees C) and refrigerated storage (5 degrees C). Frozen butters were sampled after 0, 6, 12, 15, and 24 mo; refrigerated butters were sampled after 0, 3, 6, 9, 12, 15, and 18 mo. Every 3 mo, oxidative stability index (OSI) and descriptive sensory analysis (texture, flavor, and color) were conducted. Every 6 mo, peroxide value (PV), free fatty acid value (FFV), fatty acid profiling, vane, instrumental color, and oil turbidity were examined. A mixed-model ANOVA was conducted to characterize the effects of storage time, temperature, and package type. Storage time, temperature, and package type affected butter flavor, OSI, PV, and FFV. Refrigerated butter quarters exhibited refrigerator/stale off-flavors concurrent with increased levels of oxidation (lower oxidative stability and higher PV and FFV) within 6 mo of refrigerated storage, and similar trends were observed for refrigerated bulk butter after 9 mo. Off-flavors were not evident in frozen butters until 12 or 18 mo for quarters and bulk butters, respectively. Off-flavors in frozen butters were not correlated with instrumental oxidation measurements. Because butter is such a desirable fat source in terms of flavor and textural properties, it is important that manufacturers understand how long their product can be stored before negative attributes develop.

The successful incorporation of Ag into single grain, Y-Ba-Cu-O bulk superconductors

NASA Astrophysics Data System (ADS)

Congreve, Jasmin V. J.; Shi, Yunhua; Dennis, Anthony R.; Durrell, John H.; Cardwell, David A.

2018-07-01

The use of RE-Ba-Cu-O [(RE)BCO] bulk superconductors, where RE = Y, Gd, Sm, in practical applications is, at least in part, limited by their mechanical properties and brittle nature, in particular. Alloying these materials with silver, however, produces a significant improvement in strength without any detrimental impact on their superconducting properties. Unfortunately, the top seeded melt growth technique, used routinely to process bulk (RE)BCO superconductors in the form of large, single grains required for practical applications, is complex and has a large number of inter-related variables, so the addition of silver increases the complexity of the growth process even further. This can make successful growth of this system extremely challenging. Here we report measurements of the growth rate of YBCO-Ag fabricated using a new growth technique consisting of continuous cooling and isothermal hold process. The resulting data form the basis of a model that has been used to derive suitable heating profiles for the successful single grain growth of YBCO-Ag bulk superconductors of up to 26 mm in diameter. The microstructure and distribution of silver within these samples have been studied in detail. The maximum trapped field at the top surface of the bulk YBCO-Ag samples has been found to be comparable to that of standard YBCO processed without Ag. The YBCO-Ag samples also exhibit a much more uniform trapped field profile compared to that of YBCO.

The performance of spinel bulk-like oxygen-deficient CoGa2O4 as an air-cathode catalyst in microbial fuel cell

NASA Astrophysics Data System (ADS)

Liu, Di; Mo, Xiaoping; Li, Kexun; Liu, Yi; Wang, Junjie; Yang, Tingting

2017-08-01

Nano spinel bulk-like CoGa2O4 prepared via a facile hydrothermal method is used as a high efficient electrochemical catalyst in activated carbon (AC) air-cathode microbial fuel cell (MFC). The maximum power density of the modified MFC is 1911 ± 49 mW m-2, 147% higher than the MFC of untreated AC cathode. Transmission electron microscope (TEM) and X-ray diffraction (XRD) exhibit the morphology and crystal structure of CoGa2O4. Rotating disk electrode (RDE) confirms the four-electron pathway at the cathode during the oxygen reduction reaction (ORR). Thermogravimetric analysis (TGA) and X-ray photoelectron spectroscopy (XPS) illustrate that the high rate oxygen vacancy exist in the CoGa2O4. The oxygen vacancy of CoGa2O4 plays an important role in catalytic activity. In a word, the prepared nano spinel bulk-like CoGa2O4 provides an alternative to the costly Pt in air-cathode for power output.

Effects of Small Polar Molecules (MA+ and H2O) on Degradation Processes of Perovskite Solar Cells.

PubMed

Ma, Chunqing; Shen, Dong; Qing, Jian; Thachoth Chandran, Hrisheekesh; Lo, Ming-Fai; Lee, Chun-Sing

2017-05-03

Degradation mechanisms of methylammonium lead halide perovskite solar cells (PSCs) have drawn much attention recently. Herein, the bulk and surface degradation processes of the perovskite were differentiated for the first time by employing combinational studies using electrochemical impedance spectroscopy (EIS), capacitance frequency (CF), and X-ray diffraction (XRD) studies with particular attention on the roles of small polar molecules (MA + and H 2 O). CF study shows that short-circuit current density of the PSCs is increased by H 2 O at the beginning of the degradation process coupled with an increased surface capacitance. On the basis of EIS and XRD analysis, we show that the bulk degradation of PSCs involves a lattice expansion process, which facilitates MA + ion diffusion by creating more efficient channels. These results provide a better understanding of the roles of small polar molecules on degradation processes in the bulk and on the surface of the perovskite film.

Disconnecting structure and dynamics in glassy thin films

PubMed Central

Sussman, Daniel M.; Cubuk, Ekin D.; Liu, Andrea J.

2017-01-01

Nanometrically thin glassy films depart strikingly from the behavior of their bulk counterparts. We investigate whether the dynamical differences between a bulk and thin film polymeric glass former can be understood by differences in local microscopic structure. Machine learning methods have shown that local structure can serve as the foundation for successful, predictive models of particle rearrangement dynamics in bulk systems. By contrast, in thin glassy films, we find that particles at the center of the film and those near the surface are structurally indistinguishable despite exhibiting very different dynamics. Next, we show that structure-independent processes, already present in bulk systems and demonstrably different from simple facilitated dynamics, are crucial for understanding glassy dynamics in thin films. Our analysis suggests a picture of glassy dynamics in which two dynamical processes coexist, with relative strengths that depend on the distance from an interface. One of these processes depends on local structure and is unchanged throughout most of the film, while the other is purely Arrhenius, does not depend on local structure, and is strongly enhanced near the free surface of a film. PMID:28928147

Effect of temperature on anoxic sulfide oxidation and denitrification in the bulk wastewater phase of sewer networks.

PubMed

Mathioudakis, V L; Aivasidis, A

2009-01-01

Artificial dosage of nitrate in sewer networks is considered as one of the most effective methods for odor and corrosion control. However, there is limited knowledge on the effect of temperature on the transformations that takes place during anoxic conditions. Thus, two groups of batch experiments were conducted to gain insight in the involved processes in bulk phase of a septic municipal wastewater. It can be concluded that sewer denitrification, in bulk phase, can be simplified in three stages. According to the experimental results, nitrate or nitrite is utilized for autotrophic denitrification with sulfide, while heterotrophic utilization is initiated after the completion of anoxic sulfide oxidation. Moreover, temperature is proved to have a significant impact on sewer denitrification kinetic profile, as it determines the extent of temporal nitrite accumulation. The temperature coefficient of each anoxic process, including sulfide oxidation, nitrate utilization and denitrification/nitrite utilization is experimentally calculated and temperature dependent equations are developed, providing the rate of all anoxic processes in bulk phase of sewer wastewater, in any given temperature.

Bulk tank somatic cell counts analyzed by statistical process control tools to identify and monitor subclinical mastitis incidence.

PubMed

Lukas, J M; Hawkins, D M; Kinsel, M L; Reneau, J K

2005-11-01

The objective of this study was to examine the relationship between monthly Dairy Herd Improvement (DHI) subclinical mastitis and new infection rate estimates and daily bulk tank somatic cell count (SCC) summarized by statistical process control tools. Dairy Herd Improvement Association test-day subclinical mastitis and new infection rate estimates along with daily or every other day bulk tank SCC data were collected for 12 mo of 2003 from 275 Upper Midwest dairy herds. Herds were divided into 5 herd production categories. A linear score [LNS = ln(BTSCC/100,000)/0.693147 + 3] was calculated for each individual bulk tank SCC. For both the raw SCC and the transformed data, the mean and sigma were calculated using the statistical quality control individual measurement and moving range chart procedure of Statistical Analysis System. One hundred eighty-three herds of the 275 herds from the study data set were then randomly selected and the raw (method 1) and transformed (method 2) bulk tank SCC mean and sigma were used to develop models for predicting subclinical mastitis and new infection rate estimates. Herd production category was also included in all models as 5 dummy variables. Models were validated by calculating estimates of subclinical mastitis and new infection rates for the remaining 92 herds and plotting them against observed values of each of the dependents. Only herd production category and bulk tank SCC mean were significant and remained in the final models. High R2 values (0.83 and 0.81 for methods 1 and 2, respectively) indicated a strong correlation between the bulk tank SCC and herd's subclinical mastitis prevalence. The standard errors of the estimate were 4.02 and 4.28% for methods 1 and 2, respectively, and decreased with increasing herd production. As a case study, Shewhart Individual Measurement Charts were plotted from the bulk tank SCC to identify shifts in mastitis incidence. Four of 5 charts examined signaled a change in bulk tank SCC before the DHI test day identified the change in subclinical mastitis prevalence. It can be concluded that applying statistical process control tools to daily bulk tank SCC can be used to estimate subclinical mastitis prevalence in the herd and observe for change in the subclinical mastitis status. Single DHI test day estimates of new infection rate were insufficient to accurately describe its dynamics.

Increasing strength and conductivity of Cu alloy through abnormal plastic deformation of an intermetallic compound

PubMed Central

Han, Seung Zeon; Lim, Sung Hwan; Kim, Sangshik; Lee, Jehyun; Goto, Masahiro; Kim, Hyung Giun; Han, Byungchan; Kim, Kwang Ho

2016-01-01

The precipitation strengthening of Cu alloys inevitably accompanies lowering of their electric conductivity and ductility. We produced bulk Cu alloys arrayed with nanofibers of stiff intermetallic compound through a precipitation mechanism using conventional casting and heat treatment processes. We then successfully elongated these arrays of nanofibers in the bulk Cu alloys to 400% of original length without breakage at room temperature using conventional rolling process. By inducing such an one-directional array of nanofibers of intermetallic compound from the uniform distribution of fine precipitates in the bulk Cu alloys, the trade-off between strength and conductivity and between strength and ductility could be significantly reduced. We observed a simultaneous increase in electrical conductivity by 1.3 times and also tensile strength by 1.3 times in this Cu alloy bulk compared to the conventional Cu alloys. PMID:27488621

Probing topological Fermi-Arcs and bulk boundary correspondence in the Weyl semimetal TaAs

NASA Astrophysics Data System (ADS)

Batabyal, Rajib; Morali, Noam; Avraham, Nurit; Sun, Yan; Schmidt, Marcus; Felser, Claudia; Stern, Ady; Yan, Binghai; Beidenkopf, Haim

The relation between surface Fermi-arcs and bulk Weyl cones in a Weyl semimetal, uniquely allows to study the notion of bulk to surface correspondence. We visualize these topological Fermi arc states on the surface of the Weyl semi-metal tantalum arsenide using scanning tunneling spectroscopy. Its surface hosts 12 Fermi arcs amongst several other surface bands of non-topological origin. We detect the possible scattering processes of surface bands in which Fermi arcs are involved including intra- and inter arc scatterings and arc-trivial scatterings. Each of the measured scattering processes entails additional information on the unique nature of Fermi arcs in tantalum arsenide: their contour, their energy-momentum dispersion and its relation with the bulk Weyl nodes. We further identify a sharp distinction between the wave function's spatial distribution of topological versus trivial bands. The non-topological surface bands, which are derived from the arsenic dangling bonds, are tightly bound to the arsenic termination layer. In contrast, the Fermi-arc bands reside on the deeper tantalum layer, penetrating into the bulk, which is predominantly derived from tantalum orbitals.

Processing and properties of carbon nanofibers reinforced epoxy powder composites

NASA Astrophysics Data System (ADS)

Palencia, C.; Mazo, M. A.; Nistal, A.; Rubio, F.; Rubio, J.; Oteo, J. L.

2011-11-01

Commercially available CNFs (diameter 30-300 nm) have been used to develop both bulk and coating epoxy nanocomposites by using a solvent-free epoxy matrix powder. Processing of both types of materials has been carried out by a double-step process consisting in an initial physical premix of all components followed by three consecutive extrusions. The extruded pellets were grinded into powder and sieved. Carbon nanofibers powder coatings were obtained by electrostatic painting of the extruded powder followed by a curing process based in a thermal treatment at 200 °C for 25 min. On the other hand, for obtaining bulk carbon nanofibers epoxy composites, a thermal curing process involving several steps was needed. Gloss and mechanical properties of both nanocomposite coatings and bulk nanocomposites were improved as a result of the processing process. FE-SEM fracture surface microphotographs corroborate these results. It has been assessed the key role played by the dispersion of CNFs in the matrix, and the highly important step that is the processing and curing of the nanocomposites. A processing stage consisted in three consecutive extrusions has reached to nanocomposites free of entanglements neither agglomerates. This process leads to nanocomposite coatings of enhanced properties, as it has been evidenced through gloss and mechanical properties. A dispersion limit of 1% has been determined for the studied system in which a given dispersion has been achieved, as the bending mechanical properties have been increased around 25% compared with the pristine epoxy resin. It has been also demonstrated the importance of the thickness in the nanocomposite, as it involves the curing stage. The complex curing treatment carried out in the case of bulk nanocomposites has reached to reagglomeration of CNFs.

Improvements in Certain District of Columbia Public Schools' Administrative Operations. Report to the Superintendent of the District of Columbia Public Schools.

ERIC Educational Resources Information Center

General Accounting Office, Washington, DC.

The District of Columbia Public Schools system has taken action to ensure that supply items will be obtained at the most competitive prices. Because lack of storage facilities prevented bulk purchase of emergency items at competitive rates, the Division of Buildings and Grounds has remodeled a building as a warehouse to store large quantities of…

Foundation for California Community Colleges (F.C.C.C.) Facility Program: Saving Community California Community Colleges $$$ on Assessments and Bulk Purchasing.

ERIC Educational Resources Information Center

Chen, Spencer; Toy, Larry

The Foundation for California Community Colleges (FCCC) is a non-profit foundation whose mission is to support the California Community College (CCC) system and to save the CCC money. FCCC is the official auxiliary to the Board of Governors, the Chancellor's office, and the system of 108 colleges of the CCC. This document provides details on the…

Evaluation of residual uranium contamination in the dirt floor of an abandoned metal rolling mill.

PubMed

Glassford, Eric; Spitz, Henry; Lobaugh, Megan; Spitler, Grant; Succop, Paul; Rice, Carol

2013-02-01

A single, large, bulk sample of uranium-contaminated material from the dirt floor of an abandoned metal rolling mill was separated into different types and sizes of aliquots to simulate samples that would be collected during site remediation. The facility rolled approximately 11,000 tons of hot-forged ingots of uranium metal approximately 60 y ago, and it has not been used since that time. Thirty small mass (≈ 0.7 g) and 15 large mass (≈ 70 g) samples were prepared from the heterogeneously contaminated bulk material to determine how measurements of the uranium contamination vary with sample size. Aliquots of bulk material were also resuspended in an exposure chamber to produce six samples of respirable particles that were obtained using a cascade impactor. Samples of removable surface contamination were collected by wiping 100 cm of the interior surfaces of the exposure chamber with 47-mm-diameter fiber filters. Uranium contamination in each of the samples was measured directly using high-resolution gamma ray spectrometry. As expected, results for isotopic uranium (i.e., U and U) measured with the large-mass and small-mass samples are significantly different (p < 0.001), and the coefficient of variation (COV) for the small-mass samples was greater than for the large-mass samples. The uranium isotopic concentrations measured in the air and on the wipe samples were not significantly different and were also not significantly different (p > 0.05) from results for the large- or small-mass samples. Large-mass samples are more reliable for characterizing heterogeneously distributed radiological contamination than small-mass samples since they exhibit the least variation compared to the mean. Thus, samples should be sufficiently large in mass to insure that the results are truly representative of the heterogeneously distributed uranium contamination present at the facility. Monitoring exposure of workers and the public as a result of uranium contamination resuspended during site remediation should be evaluated using samples of sufficient size and type to accommodate the heterogeneous distribution of uranium in the bulk material.

Control of Listeria species food safety at a poultry food production facility.

PubMed

Fox, Edward M; Wall, Patrick G; Fanning, Séamus

2015-10-01

Surveillance and control of food-borne human pathogens, such as Listeria monocytogenes, is a critical aspect of modern food safety programs at food production facilities. This study evaluated contamination patterns of Listeria species at a poultry food production facility, and evaluated the efficacy of procedures to control the contamination and transfer of the bacteria throughout the plant. The presence of Listeria species was studied along the production chain, including raw ingredients, food-contact, non-food-contact surfaces, and finished product. All isolates were sub-typed by pulsed-field gel electrophoresis (PFGE) to identify possible entry points for Listeria species into the production chain, as well as identifying possible transfer routes through the facility. The efficacy of selected in-house sanitizers against a sub-set of the isolates was evaluated. Of the 77 different PFGE-types identified, 10 were found among two or more of the five categories/areas (ingredients, food preparation, cooking and packing, bulk packing, and product), indicating potential transfer routes at the facility. One of the six sanitizers used was identified as unsuitable for control of Listeria species. Combining PFGE data, together with information on isolate location and timeframe, facilitated identification of a persistent Listeria species contamination that had colonized the facility, along with others that were transient. Copyright © 2015 Elsevier Ltd. All rights reserved.

Hopper apparatuses for processing a bulk solid, and related systems and methods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Westover, Tyler Lott; Ryan, John Chadron Benjamin; Matthews, Austin Colter

A hopper apparatus comprises a movable wall comprising opposing walls movably connected to a support assembly and oriented at acute angles relative to a central vertical axis of the support assembly, and movement control devices configured and positioned to move the opposing walls along the support assembly to control dimensions of a discharge outlet at least partially defined by converging ends of the opposing walls; a liner assembly comprising liner structures at least partially overlying inner surfaces of the opposing walls and configured to remain at least partially stationary relative to the opposing walls during movement of the opposing walls;more » and pressure sensors between the inner surfaces of opposing walls and portions of the liner structures thereover. A bulk solids processing system and a method of processing a bulk solid are also described.« less

Shear and bulk viscosity of high-temperature gluon plasma

NASA Astrophysics Data System (ADS)

Zhang, Le; Hou, De-Fu

2018-05-01

We calculate the shear viscosity (η) and bulk viscosity (ζ) to entropy density (s) ratios η/s and ζ/s of a gluon plasma system in kinetic theory, including both the elastic {gg}≤ftrightarrow {gg} forward scattering and the inelastic soft gluon bremsstrahlung {gg}≤ftrightarrow {ggg} processes. Due to the suppressed contribution to η and ζ in the {gg}≤ftrightarrow {gg} forward scattering and the effective g≤ftrightarrow {gg} gluon splitting, Arnold, Moore and Yaffe (AMY) and Arnold, Dogan and Moore (ADM) have got the leading order computations for η and ζ in high-temperature QCD matter. In this paper, we calculate the correction to η and ζ in the soft gluon bremsstrahlung {gg}≤ftrightarrow {ggg} process with an analytic method. We find that the contribution of the collision term from the {gg}≤ftrightarrow {ggg} soft gluon bremsstrahlung process is just a small perturbation to the {gg}≤ftrightarrow {gg} scattering process and that the correction is at ∼5% level. Then, we obtain the bulk viscosity of the gluon plasma for the number-changing process. Furthermore, our leading-order result for bulk viscosity is the formula \\zeta \\propto \\tfrac{{α }s2{T}3}{ln}{α }s-1} in high-temperature gluon plasma. Supported by Ministry of Science and Technology of China (MSTC) under the “973” Project (2015CB856904(4)) and National Natural Science Foundation of China (11735007, 11521064)

Non-equilibrium condensation process in holographic superconductor with nonlinear electrodynamics

NASA Astrophysics Data System (ADS)

Liu, Yunqi; Gong, Yungui; Wang, Bin

2016-02-01

We study the non-equilibrium condensation process in a holographic superconductor with nonlinear corrections to the U (1) gauge field. We start with an asymptotic Anti-de-Sitter (AdS) black hole against a complex scalar perturbation at the initial time, and solve the dynamics of the gravitational systems in the bulk. When the black hole temperature T is smaller than a critical value T c , the scalar perturbation grows exponentially till saturation, the final state of spacetime approaches to a hairy black hole. In the bulk theory, we find the clue of the influence of nonlinear corrections in the gauge filed on the process of the scalar field condensation. We show that the bulk dynamics in the non-equilibrium process is completely consistent with the observations on the boundary order parameter. Furthermore we examine the time evolution of horizons in the bulk non-equilibrium transformation process from the bald AdS black hole to the AdS hairy hole. Both the evolution of apparent and event horizons show that the original AdS black hole configuration requires more time to finish the transformation to become a hairy black hole if there is nonlinear correction to the electromagnetic field. We generalize our non-equilibrium discussions to the holographic entanglement entropy and find that the holographic entanglement entropy can give us further understanding of the influence of the nonlinearity in the gauge field on the scalar condensation.

The Effect of Aqueous Alteration in Antarctic Carbonaceous Chondrites from Comparative ICP-MS Bulk Chemistry

NASA Technical Reports Server (NTRS)

Alonso-Azcarate, J.; Trigo-Rodriguez, J. M.; Moyano-Cambero, C. E.; Zolensky, M.

2014-01-01

Terrestrial ages of Antarctic carbonaceous chondrites (CC) indicate that these meteorites have been preserved in or on ice for, at least, tens of thousands of years. Due to the porous structure of these chondrites formed by the aggregation of silicate-rich chondrules, refractory inclusions, metal grains, and fine-grained matrix materials, the effect of pervasive terrestrial water is relevant. Our community defends that pristine CC matrices are representing samples of scarcely processed protoplanetary disk materials as they contain stellar grains, but they might also trace parent body processes. It is important to study the effects of terrestrial aqueous alteration in promoting bulk chemistry changes, and creating distinctive alteration minerals. Particularly because it is thought that aqueous alteration has particularly played a key role in some CC groups in modifying primordial bulk chemistry, and homogenizing the isotopic content of fine-grained matrix materials. Fortunately, the mineralogy produced by parent-body and terrestrial aqueous alteration processes is distinctive. With the goal to learn more about terrestrial alteration in Antarctica we are obtaining reflectance spectra of CCs, but also performing ICP-MS bulk chemistry of the different CC groups. A direct comparison with the mean bulk elemental composition of recovered falls might inform us on the effects of terrestrial alteration in finds. With such a goal, in the current work we have analyzed some members representative of CO and CM chondrite groups.

Processing of MnBi bulk magnets with enhanced energy product

DOE PAGES

Poudyal, Narayan; Liu, Xubo; Wang, Wei; ...

2016-02-23

Here, we report magnetic properties and microstructure of high energy-product MnBi bulk magnets fabricated by low-temperature ball-milling and warm compaction technique. A maximum energy product (BH) max of 8.4 MGOe and a coercivity of 6.2 kOe were obtained in the bulk MnBi magnet at room temperature. Magnetic characterization at elevated temperatures showed an increase in coercivity to 16.2 kOe while (BH) max value decreased to 6.8 MGOe at 400 K. Microstructure characterization revealed that the bulk magnets consist of oriented uniform nanoscale grains with average size about 50 nm.

Large area bulk superconductors

DOEpatents

Miller, Dean J.; Field, Michael B.

2002-01-01

A bulk superconductor having a thickness of not less than about 100 microns is carried by a polycrystalline textured substrate having misorientation angles at the surface thereof not greater than about 15.degree.; the bulk superconductor may have a thickness of not less than about 100 microns and a surface area of not less than about 50 cm.sup.2. The textured substrate may have a thickness not less than about 10 microns and misorientation angles at the surface thereof not greater than about 15.degree.. Also disclosed is a process of manufacturing the bulk superconductor and the polycrystalline biaxially textured substrate material.

Guided evolution of bulk metallic glass nanostructures: A platform for designing three-dimensional electrocatalytic surfaces

DOE PAGES

Doubek, Gustavo; Sekol, Ryan C.; Li, Jinyang; ...

2015-12-22

Precise control over catalyst surface composition and structure is necessary to improve the function of electrochemical systems. To that end, bulk metallic glass (BMG) alloys with atomically dispersed elements provide a highly processable, nanoscale platform for electrocatalysis and surface modification. Here we report on nanostructures of Pt-based BMGs that are modified with various subtractive and additive processes to improve their electrochemical performance.

Dynamics of Hyperbranched Polymers under Confinement

NASA Astrophysics Data System (ADS)

Androulaki, Krystallenia; Chrissopoulou, Kiriaki; Anastasiadis, Spiros H.; Prevosto, Daniele; Labardi, Massimiliano

2015-03-01

The effect of severe confinement on the dynamics of three different generations of hyperbranched polyesters (Boltorns) is investigated by Dielectric Spectroscopy. The polymers are intercalated within the galleries of natural Na+-MMT, thus, forming 1nm polymer films confined between solid walls. The Tg's of the polymers determined by DSC show a clear dependence on the generation whereas the transition is completely suppressed when all the polymer chains are intercalated. The dynamic investigation of the bulk polymers reveals two sub-Tg processes, with similar behavior for the three polymers with the segmental relaxation observed above the Tg of each. For the nanocomposites, where all polymers are severely confined, the dynamics show significant differences compared to that of the bulk polymers. The sub-Tg processes are similar for the three generations but significantly faster and with weaker temperature dependence than those in the bulk. The segmental process appears at temperatures below the bulk polymer Tg, it exhibits an Arrhenius temperature dependence and shows differences for the three generations. A slow process that appears at higher temperatures is due to interfacial polarization. Co-financed by the EU and Greek funds through the Operational Program ``Education and Lifelong Learning'' of the NSRF-Research Funding Program: THALES-Investing in knowledge society through the Eur. Social Fund (MIS 377278) and COST Action MP0902-COINAPO.

Safeguards Approaches for Black Box Processes or Facilities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Diaz-Marcano, Helly; Gitau, Ernest TN; Hockert, John

2013-09-25

The objective of this study is to determine whether a safeguards approach can be developed for “black box” processes or facilities. These are facilities where a State or operator may limit IAEA access to specific processes or portions of a facility; in other cases, the IAEA may be prohibited access to the entire facility. The determination of whether a black box process or facility is safeguardable is dependent upon the details of the process type, design, and layout; the specific limitations on inspector access; and the restrictions placed upon the design information that can be provided to the IAEA. Thismore » analysis identified the necessary conditions for safeguardability of black box processes and facilities.« less

Rat animal model for preclinical testing of microparticle urethral bulking agents.

PubMed

Mann-Gow, Travis K; Blaivas, Jerry G; King, Benjamin J; El-Ghannam, Ahmed; Knabe, Christine; Lam, Michael K; Kida, Masatoshi; Sikavi, Cameron S; Plante, Mark K; Krhut, Jan; Zvara, Peter

2015-04-01

To develop an economic, practical and readily available animal model for preclinical testing of urethral bulking therapies, as well as to establish feasible experimental methods that allow for complete analysis of hard microparticle bulking agents. Alumina ceramic beads suspended in hyaluronic acid were injected into the proximal urethra of 15 female rats under an operating microscope. We assessed overall lower urinary tract function, bulking material intraurethral integrity and local host tissue response over time. Microphotographs were taken during injection and again 6 months postoperatively, before urethral harvest. Urinary flow rate and voiding frequency were assessed before and after injection. At 6 months, the urethra was removed and embedded in resin. Hard tissue sections were cut using a sawing microtome, and processed for histological analysis using scanning electron microscopy, light microscopy and immunohistochemistry. Microphotographs of the urethra showed complete volume retention of the bulking agent at 6 months. There was no significant difference between average urinary frequency and mean urinary flow rate at 1 and 3 months postinjection as compared with baseline. Scanning electron microscopy proved suitable for evaluation of microparticle size and integrity, as well as local tissue remodeling. Light microscopy and immunohistochemistry allowed for evaluation of an inflammatory host tissue reaction to the bulking agent. The microsurgical injection technique, in vivo physiology and novel hard tissue processing for histology, described in the present study, will allow for future comprehensive preclinical testing of urethral bulking therapy agents containing microparticles made of a hard material. © 2015 The Japanese Urological Association.

Grout Isolation and Stabilization of Structures and Materials within Nuclear Facilities at the U.S. Department of Energy, Hanford Site, Summary - 12309

DOE Office of Scientific and Technical Information (OSTI.GOV)

Phillips, S.J.; Phillips, M.; Etheridge, D.

2012-07-01

Per regulatory agreement and facility closure design, U.S. Department of Energy Hanford Site nuclear fuel cycle structures and materials require in situ isolation in perpetuity and/or interim physicochemical stabilization as a part of final disposal or interim waste removal, respectively. To this end, grout materials are being used to encase facilities structures or are being incorporated within structures containing hazardous and radioactive contaminants. Facilities where grout materials have been recently used for isolation and stabilization include: (1) spent fuel separations, (2) uranium trioxide calcining, (3) reactor fuel storage basin, (4) reactor fuel cooling basin transport rail tanker cars and casks,more » (5) cold vacuum drying and reactor fuel load-out, and (6) plutonium fuel metal finishing. Grout components primarily include: (1) portland cement, (2) fly ash, (3) aggregate, and (4) chemical admixtures. Mix designs for these typically include aggregate and non aggregate slurries and bulk powders. Placement equipment includes: (1) concrete piston line pump or boom pump truck for grout slurry, (2) progressive cavity and shearing vortex pump systems, and (3) extendable boom fork lift for bulk powder dry grout mix. Grout slurries placed within the interior of facilities were typically conveyed utilizing large diameter slick line and the equivalent diameter flexible high pressure concrete conveyance hose. Other facilities requirements dictated use of much smaller diameter flexible grout conveyance hose. Placement required direct operator location within facilities structures in most cases, whereas due to radiological dose concerns, placement has also been completed remotely with significant standoff distances. Grout performance during placement and subsequent to placement often required unique design. For example, grout placed in fuel basin structures to serve as interim stabilization materials required sufficient bearing i.e., unconfined compressive strength, to sustain heavy equipment yet, low breakout force to permit efficient removal by track hoe bucket or equivalent construction equipment. Further, flow of slurries through small orifice geometries of moderate head pressures was another typical design requirement. Phase separation of less than 1 percent was a typical design requirement for slurries. On the order of 30,000 cubic meters of cementitious grout have recently been placed in the above noted U.S. Department of Energy Hanford Site facilities or structures. Each has presented a unique challenge in mix design, equipment, grout injection or placement, and ultimate facility or structure performance. Unconfined compressive and shear strength, flow, density, mass attenuation coefficient, phase separation, air content, wash-out, parameters and others, unique to each facility or structure, dictate the grout mix design for each. Each mix design was tested under laboratory and scaled field conditions as a precursor to field deployment. Further, after injection or placement of each grout formulation, the material was field inspected either by standard laboratory testing protocols, direct physical evaluation, or both. (authors)« less

Antineoplastic Activity Comparison of Bovine Serum Albumin--Conjugated Sulfides Semiconductor Nanomaterials.

PubMed

Wang, Hua-Jie; Huang, Jing-Chun; Wu, Sha-Sha; Wang, Cai-Feng; Yu, Xue-Hong; Cao, Ying

2015-04-01

Although tumor is one of the most frequently occurring diseases and a leading cause of death, nanotechnology, one of the frontier sciences, is exhibiting its great potential to tumor treatments. The aim of this study was to design a facile and environmentally-friendly method to prepare bovine serum albumin-conjugated heavy metal sulfides nano-materials, including Ag2S, PbS and CdS. Here, bovine serum albumin was introduced in order to direct the synthesis of nano-materials by using its template effect and supply more sites for further modification in future. The crystal structure and morphology were analyzed by XRD and TEM, respectively. Additionally, the antineoplastic activity of nano-materials was compared by cell viability analysis, optical and electron microscopy observation after exposure of the human hepatoma cell line. The results showed that the inhibition effect of heavy metal sulfides on tumor cells was in the order of nano-PbS > bulk CdS > nano-Ag2S > nano-CdS > bulk PbS > bulk Ag2S. It could be concluded that heavy metal sulfides had significantly negative impact on human hepatoma cells growth but it could not be obviously generalized that nano-particles were always more effective to kill tumor cells than bulk materials. The size and surface reactivity might be the important factors causing the difference.

Bulk Bismuth as a High-Capacity and Ultralong Cycle-Life Anode for Sodium-Ion Batteries by Coupling with Glyme-Based Electrolytes.

PubMed

Wang, Chenchen; Wang, Liubin; Li, Fujun; Cheng, Fangyi; Chen, Jun

2017-09-01

Sodium-ion batteries (SIBs) have attracted great interest for large-scale electric energy storage in recent years. However, anodes with long cycle life and large reversible capacities are still lacking and therefore limiting the development of SIBs. Here, a bulk Bi anode with surprisingly high Na storage performance in combination with glyme-based electrolytes is reported. This study shows that the bulk Bi electrode is gradually developed into a porous integrity during initial cycling, which is totally different from that in carbonate-based electrolytes and ensures facile Na + transport and structural stability. The achievable capacity of bulk Bi in the NaPF 6 -diglyme electrolyte is high up to 400 mAh g -1 , and the capacity retention is 94.4% after 2000 cycles, corresponding to a capacity loss of 0.0028% per cycle. It exhibits two flat discharge/charge plateaus at 0.67/0.77 and 0.46/0.64 V, ascribed to the typical two-phase reactions of Bi ↔ NaBi and NaBi ↔ Na 3 Bi, respectively. The excellent performance is attributed to the unique porous integrity, stable solid electrolyte interface, and good electrode wettability of glymes. This interplay between electrolyte and electrode to boost Na storage performance will pave a new pathway for high-performance SIBs. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Commandant's international technical series. Volume 9. International regulations on the prevention of pollution from ships carrying hazardous chemicals in bulk. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1985-12-01

MARPOL was developed to minimize accidental and operational pollution from ships carrying noxious liquid substances in bulk. Accidental pollution could result from a collision, a grounding, or an overflow of a cargo tank. Operational pollution results from the disposal of cargo tank washings. Major amendments were made to the original Annex II by the International Maritime Organization. The United States and other States party to MARPOL will implement Annex II, as amended, on April 7, 1987. Implementation will affect seagoing ships transporting noxious liquid substances to and from such ships. The attached documents contain internationally agreed requirements, interpretations, and guidelinesmore » necessary for the implementation of Annex II. The documents attached include: (1) MARPOL Annex II as amended by amendments adopted by the twenty-second session of the IMO Marine Environment Protection Committee; (2) Unified Interpretations of Annex II; (3) Standards for the Procedures and Arrangements for the Discharge of Noxious Liquid Substances; (4) Ammendments to the Bulk Chemical Code and the International Bulk Chemical Code to include marine pollution concerns; (5) Guidelines on the Provision of Adequate Reception Facilities in Ports, Part II (Noxious Liquid Substances). The contents of these documents are being placed in regulations. The purpose of this document is to give members of the interested public advance notification of impending regulations.« less

Solution processing of chalcogenide materials using thiol-amine "alkahest" solvent systems.

PubMed

McCarthy, Carrie L; Brutchey, Richard L

2017-05-02

Macroelectronics is a major focus in electronics research and is driven by large area applications such as flat panel displays and thin film solar cells. Innovations for these technologies, such as flexible substrates and mass production, will require efficient and affordable semiconductor processing. Low-temperature solution processing offers mild deposition methods, inexpensive processing equipment, and the possibility of high-throughput processing. In recent years, the discovery that binary "alkahest" mixtures of ethylenediamine and short chain thiols possess the ability to dissolve bulk inorganic materials to yield molecular inks has lead to the wide study of such systems and the straightforward recovery of phase pure crystalline chalcogenide thin films upon solution processing and mild annealing of the inks. In this review, we recount the work that has been done toward elucidating the scope of this method for the solution processing of inorganic materials for use in applications such as photovoltaic devices, electrocatalysts, photodetectors, thermoelectrics, and nanocrystal ligand exchange. We also take stock of the wide range of bulk materials that can be used as soluble precursors, and discuss the work that has been done to reveal the nature of the dissolved species. This method has provided a vast toolbox of over 65 bulk precursors, which can be utilized to develop new routes to functional chalcogenide materials. Future studies in this area should work toward a better understanding of the mechanisms involved in the dissolution and recovery of bulk materials, as well as broadening the scope of soluble precursors and recoverable functional materials for innovative applications.

Sintered tantalum carbide coatings on graphite substrates: Highly reliable protective coatings for bulk and epitaxial growth

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nakamura, Daisuke; Suzumura, Akitoshi; Shigetoh, Keisuke

2015-02-23

Highly reliable low-cost protective coatings have been sought after for use in crucibles and susceptors for bulk and epitaxial film growth processes involving wide bandgap materials. Here, we propose a production technique for ultra-thick (50–200 μmt) tantalum carbide (TaC) protective coatings on graphite substrates, which consists of TaC slurry application and subsequent sintering processes, i.e., a wet ceramic process. Structural analysis of the sintered TaC layers indicated that they have a dense granular structure containing coarse grain with sizes of 10–50 μm. Furthermore, no cracks or pinholes penetrated through the layers, i.e., the TaC layers are highly reliable protective coatings. The analysismore » also indicated that no plastic deformation occurred during the production process, and the non-textured crystalline orientation of the TaC layers is the origin of their high reliability and durability. The TaC-coated graphite crucibles were tested in an aluminum nitride (AlN) sublimation growth process, which involves extremely corrosive conditions, and demonstrated their practical reliability and durability in the AlN growth process as a TaC-coated graphite. The application of the TaC-coated graphite materials to crucibles and susceptors for use in bulk AlN single crystal growth, bulk silicon carbide (SiC) single crystal growth, chemical vapor deposition of epitaxial SiC films, and metal-organic vapor phase epitaxy of group-III nitrides will lead to further improvements in crystal quality and reduced processing costs.« less

40 CFR 52.279 - Food processing facilities.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 3 2012-07-01 2012-07-01 false Food processing facilities. 52.279... (CONTINUED) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS California § 52.279 Food processing facilities... emissions from food processing facilities without any accompanying analyses demonstrating that these...

40 CFR 52.279 - Food processing facilities.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 3 2014-07-01 2014-07-01 false Food processing facilities. 52.279... (CONTINUED) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS California § 52.279 Food processing facilities... emissions from food processing facilities without any accompanying analyses demonstrating that these...

40 CFR 52.279 - Food processing facilities.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 3 2011-07-01 2011-07-01 false Food processing facilities. 52.279... (CONTINUED) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS California § 52.279 Food processing facilities... emissions from food processing facilities without any accompanying analyses demonstrating that these...

40 CFR 52.279 - Food processing facilities.

Code of Federal Regulations, 2013 CFR

2013-07-01

... emissions from food processing facilities without any accompanying analyses demonstrating that these... 40 Protection of Environment 3 2013-07-01 2013-07-01 false Food processing facilities. 52.279... (CONTINUED) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS California § 52.279 Food processing facilities...

Accretion geometry in the persistent Be/X-ray binary RXJ0440.9+4431

NASA Astrophysics Data System (ADS)

Ferrigno, C.; Farinelli, R.; Bozzo, E.; Pottschmidt, K.; Klochkov, D.; Kretschmar, P.

2014-01-01

The persistent Be/X-ray binary RXJ0440.9+4431 flared in 2010 and 2011 and has been followed by various X-ray facilities (Swift, RXTE, XMM-Newton, and INTEGRAL). We studied the source timing and spectral properties as a function of its X-ray luminosity to investigate the transition from normal to flaring activity. The source spectrum can always be described by a bulk-motion Comptonization model of black body seed photons attenuated by a moderate photoelectric absorption. At the highest luminosity, we measured a curvature of the spectrum, which we attribute to a significant contribution of the radiation pressure in the accretion process. This allows us to estimate that the transition from a bulk-motion-dominated flow to a radiatively dominated one happens at a luminosity of ~ 2 × 1036 erg s-1. The luminosity dependency of the size of the black body emission region is found to be rBB ∝ LX0.39±0.02. This suggests that either matter accreting onto the neutron star hosted in RXJ0440.9+4431 penetrates through closed magnetic field lines at the border of the compact object magnetosphere or that the size of the black-body emitting hotspot is larger than the footprint of the accretion column. This phenomenon can be due to illumination of the surface by a growing column or by a a structure of the neutron star magnetic field more complicated than a simple dipole at least close to the surface.

Direct Comparison of Surface and Bulk Relaxation of PS - A Temperature Dependent Study

NASA Astrophysics Data System (ADS)

Wu, Wen-Li; Sambasivan, Sharadha; Wang, Chia-Ying; Genzer, Jan; Fischer, Daniel A.

2005-03-01

Near-edge X-ray absorption fine structure (NEXAFS) spectroscopy was used to measure simultaneously the relaxation rates of polystyrene (PS) molecules at the free surface and in the bulk. The samples were uniaxially oriented at room temperature via a modified cold rolling process. The density of the oriented samples as determined by liquid immersion technique is identical to that of bulk PS. At temperatures below its bulk glass transition temperature the rate of surface and bulk chain relaxation was monitored by measuring the partial-electron yield (PEY) and the fluorescence NEXAFS yields (FS), respectively, both parallel and perpendicular to the stretching direction. The decay rate of the dichroic ratios from both PEY and FY at various temperatures was taken as a measure of the relaxation rate of surface and bulk molecules respectively. In addition, the decay rate of the optical birefringence was also measured to provide an independent measure of the bulk relaxation. Relaxation of PS chains was found to occur faster on the surface relative to the bulk. The magnitude of the surface glass transition temperature suppression over the bulk was estimated to be 18 C based on the measured temperature dependence of the relaxation rates.

Evaluation Of Sludge Heel Dissolution Efficiency With Oxalic Acid Cleaning At Savannah River Site

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sudduth, Christie; Vitali, Jason; Keefer, Mark

The chemical cleaning process baseline strategy at the Savannah River Site was revised to improve efficiency during future execution of the process based on lessons learned during previous bulk oxalic acid cleaning activities and to account for operational constraints imposed by safety basis requirements. These improvements were also intended to transcend the difficulties that arise from waste removal in higher rheological yield stress sludge tanks. Tank 12 implemented this improved strategy and the bulk oxalic acid cleaning efforts concluded in July 2013. The Tank 12 radiological removal results were similar to previous bulk oxalic acid cleaning campaigns despite the factmore » that Tank 12 contained higher rheological yield stress sludge that would make removal more difficult than the sludge treated in previous cleaning campaigns. No appreciable oxalate precipitation occurred during the cleaning process in Tank 12 compared to previous campaigns, which aided in the net volume reduction of 75-80%. Overall, the controls established for Tank 12 provide a template for an improved cleaning process.« less

Sintering Process and Mechanical Property of MWCNTs/HDPE Bulk Composite.

PubMed

Ming-Wen, Wang; Tze-Chi, Hsu; Jie-Ren, Zheng

2009-08-01

Studies have proved that increasing polymer matrices by carbon nanotubes to form structural reinforcement and electrical conductivity have significantly improved mechanical and electrical properties at very low carbon nanotubes loading. In other words, increasing polymer matrices by carbon nanotubes to form structural reinforcement can reduce friction coefficient and enhance anti-wear property. However, producing traditional MWCNTs in polymeric materix is an extremely complicated process. Using melt-mixing process or in situ polymerization leads to better dispersion effect on composite materials. In this study, therefore, to simplify MWCNTs /HDPE composite process and increase dispersion, powder was used directly to replace pellet to mix and sinter with MWCNTs. The composite bulks with 0, 0.5, 1, 2 and 4% nanotube content by weight was analyzed under SEM to observe nanotubes dispersion. At this rate, a MWCNTs/HDPE composite bulk with uniformly dispersed MWCNTs was achieved, and through the wear bench (Pin-on-Disk), the wear experiment has accomplished. Accordingly, the result suggests the sintered MWCNTs/HDPE composites amplify the hardness and wear-resist property.

Quarantine and protocol

NASA Technical Reports Server (NTRS)

1981-01-01

The purpose of the Orbiting Quarantine Facility is to provide maximum protection of the terrestrial biosphere by ensuring that the returned Martian samples are safe to bring to Earth. The protocol designed to detect the presence of biologically active agents in the Martian soil is described. The protocol determines one of two things about the sample: (1) that it is free from nonterrestrial life forms and can be sent to a terrestrial containment facility where extensive chemical, biochemical, geological, and physical investigations can be conducted; or (2) that it exhibits "biological effects" of the type that dictate second order testing. The quarantine protocol is designed to be conducted on a small portion of the returned sample, leaving the bulk of the sample undisturbed for study on Earth.

MagLev Cobra: Test Facilities and Operational Experiments

NASA Astrophysics Data System (ADS)

Sotelo, G. G.; Dias, D. H. J. N.; de Oliveira, R. A. H.; Ferreira, A. C.; De Andrade, R., Jr.; Stephan, R. M.

2014-05-01

The superconducting MagLev technology for transportation systems is becoming mature due to the research and developing effort of recent years. The Brazilian project, named MagLev-Cobra, started in 1998. It has the goal of developing a superconducting levitation vehicle for urban areas. The adopted levitation technology is based on the diamagnetic and the flux pinning properties of YBa2Cu3O7-δ (YBCO) bulk blocks in the interaction with Nd-Fe-B permanent magnets. A laboratory test facility with permanent magnet guideway, linear induction motor and one vehicle module is been built to investigate its operation. The MagLev-Cobra project state of the art is presented in the present paper, describing some construction details of the new test line with 200 m.

Chemical technology for the toxic gas flow control through process water system.

PubMed

Broussard, G; Bramanti, O; Salvatore, A; Marchese, F M

2001-01-01

The aim of this work is focused on the safety and toxicological aspects due to under-pressure industrial plant management, above all in the case which the gas is very dangerous for human health and environment. Here is illustrated the safe method of control of risks through specific choices of engineering devices and chemical process: in this way we have shown the mathematical calculation regarding the case of ammonia flow gas running in the piping and plant under-pressure. In this paper the Authors show the assessment of the technological solution for falling down of a toxic gas as NH3, which lets off from safety values facilities. The under pressure industrial plants with ammonia are protected through the safety valves, settled at 20 bar pressure. The out-let gas flow is capted by a tank of a water bulk of five time theoretical water amount necessary to the complete absorption of gas. In order to prevent any health risk and carry out a safety management, it needs to verify two basic aspects, with connected specific techniques: 1. The safety valves technology through the mathematical calculation of operating device; 2. The absorption process of the toxic agent for controlling of dangerous runaway of gas.

Ultraviolet-ozone surface modification for non-wetting hole transport materials based inverted planar perovskite solar cells with efficiency exceeding 18%

NASA Astrophysics Data System (ADS)

Xu, Xiuwen; Ma, Chunqing; Cheng, Yuanhang; Xie, Yue-Min; Yi, Xueping; Gautam, Bhoj; Chen, Shengmei; Li, Ho-Wa; Lee, Chun-Sing; So, Franky; Tsang, Sai-Wing

2017-08-01

Non-wetting hole transport materials (HTMs) have great potential in facilitating large-sized perovskite crystal growth and enhancing device stability by opposing moisture ingress, However, the severe non-wetting issue limits the wide application of these materials in low-temperature solution-processed inverted planar perovskite solar cells (PVSCs), and corresponding devices are rarely reported. Here, a facile ultraviolet-ozone (UVO) modification method is demonstrated to overcome this issue. By carefully controlling the UVO modification time, the surface wettability of poly-TPD can be tuned without affecting the bulk properties of the film, hence perovskite films with desired grain size and excellent coverage can be deposited via a one-step spin-coating method. Benefiting from the high-quality perovskite, well-matched energy level alignment and hydrophobic property of poly-TPD, the resulting PVSCs show a champion power conversion efficiency of 18.19% with significantly enhanced stability as compared to the PEDOT:PSS counterparts. Moreover, the UVO modification approach also demonstrates its validity when being extended to other hydrophobic HTMs. This work not only provides a general strategy to broaden the selection pool of HTMs for solution-processed inverted planar PVSCs, but also may triggers the exploration of more advanced strategies to make non-wetting HTMs applicable in solution-processed inverted planar PVSCs.

The effect of high energy concentration source irradiation on structure and properties of Fe-based bulk metallic glass

NASA Astrophysics Data System (ADS)

Pilarczyk, Wirginia

2016-06-01

Metallic glasses exhibit metastable structure and maintain this relatively stable amorphous state within certain temperature range. High intensity laser beam was used for the surface irradiation of Fe-Co-B-Si-Nb bulk metallic glasses. The variable parameter was laser beam pulse energy. For the analysis of structure and properties of bulk metallic glasses and their surface after laser remelting the X-ray analysis, microscopic observation and test of mechanical properties were carried out. Examination of the nanostructure of amorphous materials obtained by high pressure copper mold casting method and the irradiated with the use of TITAN 80-300 HRTEM was carried out. Nanohardness and reduced Young's modulus of particular amorphous and amorphous-crystalline material zone of the laser beam were examined with the use of Hysitron TI950 Triboindenter nanoindenter and with the use of Berkovich's indenter. The XRD and microscopic analysis showed that the test material is amorphous in its structure before irradiation. Microstructure observation with electron transmission microscopy gave information about alloy crystallization in the irradiated process. Identification of given crystal phases allows to determine the kind of crystal phases created in the first place and also further changes of phase composition of alloy. The main value of the nanohardness of the surface prepared by laser beam has the order of magnitude similar to bulk metallic glasses formed by casting process irrespective of the laser beam energy used. Research results analysis showed that the area between parent material and fusion zone is characterized by extraordinarily interesting structure which is and will be the subject of further analysis in the scope of bulk metallic glasses amorphous structure and high energy concentration source. The main goal of this work is the results' presentation of structure and chosen properties of the selected bulk metallic glasses after casting process and after irradiation process employing the high energy concentration sources.

Formation and Stability of Bulk Nanobubbles Generated by Ethanol-Water Exchange.

PubMed

Qiu, Jie; Zou, Zhenglei; Wang, Shuo; Wang, Xingya; Wang, Lei; Dong, Yaming; Zhao, Hongwei; Zhang, Lijuan; Hu, Jun

2017-05-19

Bulk nanobubbles have unique properties and find potential applications in many important processes. However, their stability or long lifetime still needs to be understood and has attracted much attention from researchers. Bulk nanobubbles are generated based on ethanol-water exchange, a method that is generally used in the study of surface nanobubbles. Their formation and stability is further studied by using a new type of dynamic light scattering known as NanoSight. The results show that the concentration of the bulk nanobubbles produced by this method is about five times greater than that in the degassed group, which indicates the existence of bulk gas nanobubbles. The effects of ethanol/water ratios and temperature on the stability of the bulk nanobubbles have also been studied and their numbers reach a maximum at a ratio of about 1:10 (v/v). © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Physical science receives stimulus boost

NASA Astrophysics Data System (ADS)

Gwynne, Peter

2009-03-01

Science fared well in the 787bn package to stimulate the US economy that President Barack Obama signed into law last month. The "recovery and reinvestment bill" includes 21.5bn for research and development (R&D), the bulk of which - some 18bn - will go directly to researchers. The remaining 3.5bn is allocated for facilities and equipment. Politicians had been bickering over the bill since it was first unveiled on 15 January.

Assessing the Operational Resilience of Electrical Distribution Systems

DTIC Science & Technology

2017-09-01

as solar, hydro, wind , nuclear, or gas turbine power plants, produce electricity. Transmission systems move electricity in bulk from the originating...us. As I continue in my career I will consistently seek to emulate your attention to detail and ability to quickly frame and solve a problem . Thank...generation facility can cause problems (Knaus, 2017). Disruptions to transmission systems, either from the loss of a high-voltage line or a substation, can

Bulk Shielding Facility quarterly report, April, May and June 1984

DOE Office of Scientific and Technical Information (OSTI.GOV)

Corbett, B.L.; Lance, E.D.

1984-12-01

The BSR operated at an average power level of 1310 kW for 3.8% of the time during April, May, and June. Water-quality control in both the reactor primary and secondary cooling systems was satisfactory. The PCA was used in training startups and was operated on five occasions for the NBS and HEDL recheck of a previous experiment run on the LWR pressure vessel surveillance dosimetry improvement program.

Dynamics of Photoexcitation and Photocatalysis at Nanostructured Carbon Interfaces

DTIC Science & Technology

2015-07-14

nanotubes with a sacrificial polymer and eliminating the polymer using a critical point drying process. This process creates aerogel structures that...Bindl DJ, Jacobberger RM, Wu M-Y, Singha Roy S, Arnold MS, Semiconducting Carbon Nanotube Aerogel Bulk Heterojunction Solar Cells, Small 10 (16), pp...ACS Nano 2015, 9 (1), 564-572. Ye Y, Bindl DJ, Jacobberger RM, Wu M-Y, Singha Roy S, Arnold MS, Semiconducting Carbon Nanotube Aerogel Bulk

Novel pre-alloyed powder processing of modified alnico 8: Correlation of microstructure and magnetic properties

DOE PAGES

Anderson, I. E.; Kassen, A. G.; White, E. M. H.; ...

2015-04-13

Progress is reviewed on development of an improved near-final bulk magnet fabrication process for alnico 8, as a non-rare earth permanent magnet with promise for sufficient energy density and coercivity for electric drive motors. This study showed that alnico bulk magnets in near-final shape can be made by simple compression molding from spherical high purity gas atomized pre-alloyed powder. Dwell time at peak sintering temperature (1250°C) greatly affected grain size of the resulting magnet alloys. This microstructure transformation was demonstrated to be useful for gaining partially aligned magnetic properties and boosting energy product. Furthermore, while a route to increased coercivitymore » was not identified by these experiments, manufacturability of bulk alnico magnet alloys in near-final shapes was demonstrated, permitting further processing and alloy modification experiments that can target higher coercivity and better control of grain anisotropy during grain growth.« less

15 CFR 923.13 - Energy facility planning process.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 15 Commerce and Foreign Trade 3 2010-01-01 2010-01-01 false Energy facility planning process. 923... RESOURCE MANAGEMENT COASTAL ZONE MANAGEMENT PROGRAM REGULATIONS Uses Subject to Management § 923.13 Energy facility planning process. The management program must contain a planning process for energy facilities...

15 CFR 923.13 - Energy facility planning process.

Code of Federal Regulations, 2012 CFR

2012-01-01

... 15 Commerce and Foreign Trade 3 2012-01-01 2012-01-01 false Energy facility planning process. 923... RESOURCE MANAGEMENT COASTAL ZONE MANAGEMENT PROGRAM REGULATIONS Uses Subject to Management § 923.13 Energy facility planning process. The management program must contain a planning process for energy facilities...

15 CFR 923.13 - Energy facility planning process.

Code of Federal Regulations, 2013 CFR

2013-01-01

... 15 Commerce and Foreign Trade 3 2013-01-01 2013-01-01 false Energy facility planning process. 923... RESOURCE MANAGEMENT COASTAL ZONE MANAGEMENT PROGRAM REGULATIONS Uses Subject to Management § 923.13 Energy facility planning process. The management program must contain a planning process for energy facilities...

15 CFR 923.13 - Energy facility planning process.

Code of Federal Regulations, 2011 CFR

2011-01-01

... 15 Commerce and Foreign Trade 3 2011-01-01 2011-01-01 false Energy facility planning process. 923... RESOURCE MANAGEMENT COASTAL ZONE MANAGEMENT PROGRAM REGULATIONS Uses Subject to Management § 923.13 Energy facility planning process. The management program must contain a planning process for energy facilities...

15 CFR 923.13 - Energy facility planning process.

Code of Federal Regulations, 2014 CFR

2014-01-01

... 15 Commerce and Foreign Trade 3 2014-01-01 2014-01-01 false Energy facility planning process. 923... RESOURCE MANAGEMENT COASTAL ZONE MANAGEMENT PROGRAM REGULATIONS Uses Subject to Management § 923.13 Energy facility planning process. The management program must contain a planning process for energy facilities...

The nature, fabrication, and applications of photosensitive, bulk, germano-silicate glass

NASA Astrophysics Data System (ADS)

Heaney, Alan Douglas

2000-08-01

The photosensitive nature of germano-silicate glass is widely used to create fiber-optic devices. This thesis examines the cause of photosensitivity in germano- silicate glass. The results of this research elucidate the role that germanium oxygen deficient defects play in the photosensitivity of hydrogen-loaded, germano-silicate glass. We find that defects are not vital to the photosensitivity of hydrogen-loaded, germano-silicate glass but they do enhance the effect. Quantitative measurements show that germanium oxygen deficient defects promote the formation of OH, GeH, and GeH2 when hydrogen-loaded, germano-silicate glass is exposed to ultraviolet light. A sol-gel process for fabricating germano-silicate glass in bulk samples has been developed. The sol-gel process produces high-quality, germano-silicate glass which can be tailored to contain defects or be relatively free of defects. Control over the glass defect concentration allows us to use sol-gel derived glass for comparative studies of the photosensitive process and for device applications. The unique properties of germano-silicate glass make it a likely choice for use in optical applications. To prove the feasibility of bulk devices, chirped-pulse amplification is demonstrated using gratings written in bulk germano-silicate glass.

Heavy ion linear accelerator for radiation damage studies of materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kutsaev, Sergey V.; Mustapha, Brahim; Ostroumov, Peter N.

A new eXtreme MATerial (XMAT) research facility is being proposed at Argonne National Laboratory to enable rapid in situ mesoscale bulk analysis of ion radiation damage in advanced materials and nuclear fuels. This facility combines a new heavy-ion accelerator with the existing high-energy X-ray analysis capability of the Argonne Advanced Photon Source. The heavy-ion accelerator and target complex will enable experimenters to emulate the environment of a nuclear reactor making possible the study of fission fragment damage in materials. Material scientists will be able to use the measured material parameters to validate computer simulation codes and extrapolate the response ofmore » the material in a nuclear reactor environment. Utilizing a new heavy-ion accelerator will provide the appropriate energies and intensities to study these effects with beam intensities which allow experiments to run over hours or days instead of years. The XMAT facility will use a CW heavy-ion accelerator capable of providing beams of any stable isotope with adjustable energy up to 1.2 MeV/u for U-238(50+) and 1.7 MeV for protons. This energy is crucial to the design since it well mimics fission fragments that provide the major portion of the damage in nuclear fuels. The energy also allows damage to be created far from the surface of the material allowing bulk radiation damage effects to be investigated. The XMAT ion linac includes an electron cyclotron resonance ion source, a normal-conducting radio-frequency quadrupole and four normal-conducting multi-gap quarter-wave resonators operating at 60.625 MHz. This paper presents the 3D multi-physics design and analysis of the accelerating structures and beam dynamics studies of the linac.« less

Heavy ion linear accelerator for radiation damage studies of materials

NASA Astrophysics Data System (ADS)

Kutsaev, Sergey V.; Mustapha, Brahim; Ostroumov, Peter N.; Nolen, Jerry; Barcikowski, Albert; Pellin, Michael; Yacout, Abdellatif

2017-03-01

A new eXtreme MATerial (XMAT) research facility is being proposed at Argonne National Laboratory to enable rapid in situ mesoscale bulk analysis of ion radiation damage in advanced materials and nuclear fuels. This facility combines a new heavy-ion accelerator with the existing high-energy X-ray analysis capability of the Argonne Advanced Photon Source. The heavy-ion accelerator and target complex will enable experimenters to emulate the environment of a nuclear reactor making possible the study of fission fragment damage in materials. Material scientists will be able to use the measured material parameters to validate computer simulation codes and extrapolate the response of the material in a nuclear reactor environment. Utilizing a new heavy-ion accelerator will provide the appropriate energies and intensities to study these effects with beam intensities which allow experiments to run over hours or days instead of years. The XMAT facility will use a CW heavy-ion accelerator capable of providing beams of any stable isotope with adjustable energy up to 1.2 MeV/u for 238U50+ and 1.7 MeV for protons. This energy is crucial to the design since it well mimics fission fragments that provide the major portion of the damage in nuclear fuels. The energy also allows damage to be created far from the surface of the material allowing bulk radiation damage effects to be investigated. The XMAT ion linac includes an electron cyclotron resonance ion source, a normal-conducting radio-frequency quadrupole and four normal-conducting multi-gap quarter-wave resonators operating at 60.625 MHz. This paper presents the 3D multi-physics design and analysis of the accelerating structures and beam dynamics studies of the linac.

Promising Thermoelectric Bulk Materials with 2D Structures.

PubMed

Zhou, Yiming; Zhao, Li-Dong

2017-12-01

Given that more than two thirds of all energy is lost, mostly as waste heat, in utilization processes worldwide, thermoelectric materials, which can directly convert waste heat to electricity, provide an alternative option for optimizing energy utilization processes. After the prediction that superlattices may show high thermoelectric performance, various methods based on quantum effects and superlattice theory have been adopted to analyze bulk materials, leading to the rapid development of thermoelectric materials. Bulk materials with two-dimensional (2D) structures show outstanding properties, and their high performance originates from both their low thermal conductivity and high Seebeck coefficient due to their strong anisotropic features. Here, the advantages of superlattices for enhancing the thermoelectric performance, the transport mechanism in bulk materials with 2D structures, and optimization methods are discussed. The phenomenological transport mechanism in these materials indicates that thermal conductivities are reduced in 2D materials with intrinsically short mean free paths. Recent progress in the transport mechanisms of Bi 2 Te 3 -, SnSe-, and BiCuSeO-based systems is summarized. Finally, possible research directions to enhance the thermoelectric performance of bulk materials with 2D structures are briefly considered. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Spectroscopic Visualization of Inversion and Time-Reversal Symmetry Breaking Weyl Semi-metals

NASA Astrophysics Data System (ADS)

Beidenkopf, Haim

A defining property of a topological material is the existence of surface bands that cannot be realized but as the termination of a topological bulk. In a Weyl semi-metal these surface states are in the form of Fermi-arcs. Their open-contour Fermi-surface curves between pairs of surface projections of bulk Weyl cones. Such Dirac-like bulk bands, as opposed to the gapped bulk of topological insulators, land a unique opportunity to examine the deep notion of bulk to surface correspondence. We study the intricate properties both of inversion symmetry broken and of time-reversal symmetry broken Weyl semimetals using scanning tunneling spectroscopy. We visualize the Fermi arc states on the surface of the non-centrosymmetric Weyl semi-metal TaAs. Using the distinct structure and spatial distribution of the wavefunctions associated with the different topological and trivial bands we detect the scattering processes that involve Fermi arcs. Each of these imaged scattering processes entails information on the unique nature of Fermi arcs and their correspondence to the topological bulk. We further visualize the magnetic response of the candidate magnetic Weyl semimetal GdPtBi in which the magnetic order parameter is coupled to the topological classification. European Research Council (ERC-StG no. 678702, TOPO-NW\\x9D), the Israel Science Foundation (ISF), and the United States-Israel Binational Science Foundation (BSF).

Simulation study of the discharge characteristics of silos with cohesive particles

NASA Astrophysics Data System (ADS)

Hund, David; Weis, Dominik; Hesse, Robert; Antonyuk, Sergiy

2017-06-01

In many industrial applications the silo for bulk materials is an important part of an overall process. Silos are used for instance to buffer intermediate products to ensure a continuous supply for the next process step. This study deals with the discharging behaviour of silos containing cohesive bulk solids with particle sizes in the range of 100-500 μm. In this contribution the TOMAS [1,2] model developed for stationary and non-stationary discharging of a convergent hopper is verified with experiments and simulations using the Discrete Element Method. Moreover the influence of the cohesion of the bulk solids on the discharge behaviour is analysed by the simulation. The simulation results showed a qualitative agreement with the analytical model of TOMAS.

Direct measurement of the propagation velocity of defects using coherent X-rays

DOE PAGES

Ulbrandt, Jeffrey G.; Rainville, Meliha G.; Wagenbach, Christa; ...

2016-03-28

The properties of artificially grown thin films are often strongly affected by the dynamic relationships between surface growth processes and subsurface structure. Coherent mixing of X-ray signals promises to provide an approach to better understand such processes. Here, we demonstrate the continuously variable mixing of surface and bulk scattering signals during realtime studies of sputter deposition of a-Si and a-WSi2 films by controlling the X-ray penetration and escape depths in coherent grazing-incidence small-angle X-ray scattering. Under conditions where the X-ray signal comes from both the growth surface and the thin film bulk, oscillations in temporal correlations arise from coherent interferencemore » between scattering from stationary bulk features and from the advancing surface. We also observe evidence that elongated bulk features propagate upwards at the same velocity as the surface. Moreover, a highly surface-sensitive mode is demonstrated that can access the surface dynamics independently of the subsurface structure.« less

Transient Cooperative Processes in Dewetting Polymer Melts.

PubMed

Chandran, Sivasurender; Reiter, Günter

2016-02-26

We compare the high velocity dewetting behavior, at elevated temperatures, of atactic polystyrene (aPS) and isotactic polystyrene (iPS) films, with the zero shear bulk viscosity (η_{bulk}) of aPS being approximately ten times larger than iPS. As expected, for aPS the apparent viscosity of the films (η_{f}) derived from high-shear dewetting is less than η_{bulk}, displaying a shear thinning behavior. Surprisingly, for iPS films, η_{f} is always larger than η_{bulk}, even at about 50 °C above the melting point, with η_{f}/η_{bulk} following an Arrhenius behavior. The corresponding activation energy of ∼160±10  kJ/mol for iPS films suggests a cooperative motion of segments which are aligned and agglomerated by fast dewetting.

Surface flux density distribution characteristics of bulk high- Tc superconductor in external magnetic field

NASA Astrophysics Data System (ADS)

Torii, S.; Yuasa, K.

2004-10-01

Various magnetic levitation systems using oxide superconductors are developed as strong pinning forces are obtained in melt-processed bulk. However, the trapped flux of superconductor is moved by flux creep and fluctuating magnetic field. Therefore, to examine the internal condition of superconductor, the authors measure the dynamic surface flux density distribution of YBCO bulk. Flux density measurement system has a structure with the air-core coil and the Hall sensors. Ten Hall sensors are arranged in series. The YBCO bulk, which has 25 mm diameter and 13 mm thickness, is field cooled by liquid nitrogen. After that, magnetic field is changed by the air-core coil. This paper describes about the measured results of flux density distribution of YBCO bulk in the various frequencies of air-core coils currents.

Evaluation of risk and benefit in thermal effusivity sensor for monitoring lubrication process in pharmaceutical product manufacturing.

PubMed

Uchiyama, Jumpei; Kato, Yoshiteru; Uemoto, Yoshifumi

2014-08-01

In the process design of tablet manufacturing, understanding and control of the lubrication process is important from various viewpoints. A detailed analysis of thermal effusivity data in the lubrication process was conducted in this study. In addition, we evaluated the risk and benefit in the lubrication process by a detailed investigation. It was found that monitoring of thermal effusivity detected mainly the physical change of bulk density, which was changed by dispersal of the lubricant and the coating powder particle by the lubricant. The monitoring of thermal effusivity was almost the monitoring of bulk density, thermal effusivity could have a high correlation with tablet hardness. Moreover, as thermal effusivity sensor could detect not only the change of the conventional bulk density but also the fractional change of thermal conductivity and thermal capacity, two-phase progress of lubrication process could be revealed. However, each contribution of density, thermal conductivity, or heat capacity to thermal effusivity has the risk of fluctuation by formulation. After carefully considering the change factor with the risk to be changed by formulation, thermal effusivity sensor can be a useful tool for monitoring as process analytical technology, estimating tablet hardness and investigating the detailed mechanism of the lubrication process.

Facile synthesis of high surface area molybdenum nitride and carbide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Roy, Aaron; Serov, Alexey; Artyushkova, Kateryna

2015-08-15

The synthesis of high surface area γ-Mo{sub 2}N and α-Mo{sub 2}C is reported (116 and 120 m{sup 2}/g) without the temperature programmed reduction of MoO{sub 3}. γ-Mo{sub 2}N was prepared in an NH{sub 3}-free synthesis using forming gas (7 at% H{sub 2}, N{sub 2}-balance) as the reactive atmosphere. Three precursors were studied ((NH{sub 4}){sub 6}Mo{sub 7}O{sub 24}·4H{sub 2}O, (NH{sub 4}){sub 2} Mg(MoO{sub 4}){sub 2}, and MgMoO{sub 4}) along with the sacrificial support method (SSM) as a means of reducing the particle size of Mo{sub 2}N and Mo{sub 2}C. In situ X-ray diffraction (XRD) studies were carried out to identify reactionmore » intermediates, the temperature at which various intermediates form, and the average domain size of the Mo{sub 2}N products. Materials were synthesized in bulk and further characterized by XRD, HRTEM, XPS, and BET. - Highlights: • Facile synthesis of γ-Mo2N and α-Mo2C with surface area exceeding 100 m{sup 2}/g. • Sacrificial support method was used to achieve these high surface areas. • Materials can serve as catalysts or supports in (electro)chemical processes.« less

Facile bottom-up synthesis of partially oxidized black phosphorus nanosheets as metal-free photocatalyst for hydrogen evolution

PubMed Central

Tian, Bin; Tian, Bining; Smith, Bethany; Scott, M. C.; Lei, Qin; Hua, Ruinian; Liu, Yi

2018-01-01

Few-layer black phosphorus (BP) nanosheets were first reported as a 2D material for the application of field-effect transistors in 2014 and have stimulated intense activity among physicists, chemists, and material and biomedical scientists, driving research into novel synthetic techniques to produce BP nanosheets. At present, exfoliation is the main route toward few-layer BP nanosheets via employing bulk BP as raw material. However, this is a complicated and time-consuming process, which is difficult for the large-scale synthesis of BP nanosheets. Moreover, BP degrades rapidly when exfoliated to nanoscale dimensions, resulting in the rapid loss of semiconducting properties. Here, we report the direct wet-chemical synthesis of few-layer BP nanosheets in gram-scale quantities in a bottom-up approach based on common laboratory reagents at low temperature, showing excellent stability due to partial oxidation of surface. Solvent and temperature are two critical factors, controlling not only the formation of BP nanosheets but also the thickness. The as-prepared BP nanosheets can extract hydrogen from pure water (pH = 6.8), exhibiting more than 24-fold higher activity than the well-known C3N4 nanosheets. Our results reporting the ability to prepare few-layer BP nanosheets with a facile, scalable, low-cost approach take us a step closer to real-world applications of phosphorene including next-generation metal-free photocatalysts for photosynthesis. PMID:29563225

Facile and Green Production of Impurity-Free Aqueous Solutions of WS2 Nanosheets by Direct Exfoliation in Water.

PubMed

Pan, Long; Liu, Yi-Tao; Xie, Xu-Ming; Ye, Xiong-Ying

2016-12-01

To obtain 2D materials with large quantity, low cost, and little pollution, liquid-phase exfoliation of their bulk form in water is a particularly fascinating concept. However, the current strategies for water-borne exfoliation exclusively employ stabilizers, such as surfactants, polymers, or inorganic salts, to minimize the extremely high surface energy of these nanosheets and stabilize them by steric repulsion. It is worth noting, however, that the remaining impurities inevitably bring about adverse effects to the ultimate performances of 2D materials. Here, a facile and green route to large-scale production of impurity-free aqueous solutions of WS 2 nanosheets is reported by direct exfoliation in water. Crucial parameters such as initial concentration, sonication time, centrifugation speed, and centrifugation time are systematically evaluated to screen out an optimized condition for scaling up. Statistics based on morphological characterization prove that substantial fraction (66%) of the obtained WS 2 nanosheets are one to five layers. X-ray diffraction and Raman characterizations reveal a high quality with few, if any, structural distortions. The water-borne exfoliation route opens up new opportunities for easy, clean processing of WS 2 -based film devices that may shine in the fields of, e.g., energy storage and functional nanocomposites owing to their excellent electrochemical, mechanical, and thermal properties. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

The Role of Planetary Dust and Regolith Mechanics in Technology Developments at NASA

NASA Technical Reports Server (NTRS)

Agui, Juan H.

2011-01-01

One of NASA's long term goals continues to be the exploration of other planets and orbital bodies in our solar system. Our sustained presence through the installation of stations or bases on these planetary surfaces will depend on developing properly designed habitation modules, mobility systems and supporting infrastructure. NASA Glenn Research Center is involved in several technology developments in support of this overarching goal. Two key developments are in the area of advanced filtration and excavation systems. The first addresses the issues posed by the accumulation of particulate matter over long duration missions and the intrusion of planetary dust into spacecraft and habitat pressurized cabins. The latter supports the operation and infrastructure of insitu resource utilization (ISRU) processes to derive consumables and construction materials from the planetary regolith. These two developments require a basic understanding of the lunar regolith at the micro (particle) to macro (bulk) level. Investigation of the relevant properties of the lunar regolith and characterization of the standard simulant materials used in. testing were important first steps in these developments. The fundamentals and operational concepts of these technologies as well as descriptions of new NASA facilities, including the Particulate Filtration Testing and the NASA Excavation and Traction Testing facilities, and their capabilities for testing and advancing these technologies will be presented. The test data also serves to validate and anchor computational simulation models.

Effect of interfacial turbulence and accommodation coefficient on CFD predictions of pressurization and pressure control in cryogenic storage tank

NASA Astrophysics Data System (ADS)

Kassemi, Mohammad; Kartuzova, Olga

2016-03-01

Pressurization and pressure control in cryogenic storage tanks are to a large extent affected by heat and mass transport across the liquid-vapor interface. These mechanisms are, in turn, controlled by the kinetics of the phase change process and the dynamics of the turbulent recirculating flows in the liquid and vapor phases. In this paper, the effects of accommodation coefficient and interfacial turbulence on tank pressurization and pressure control simulations are examined. Comparison between numerical predictions and ground-based measurements in two large liquid hydrogen tank experiments, performed in the K-site facility at NASA Glenn Research Center (GRC) and the Multi-purpose Hydrogen Test Bed (MHTB) facility at NASA Marshall Space Flight Center (MSFC), are used to show the impact of accommodation coefficient and interfacial and vapor phase turbulence on evolution of pressure and temperatures in the cryogenic storage tanks. In particular, the self-pressurization comparisons indicate that: (1) numerical predictions are essentially independent of the magnitude of the accommodation coefficient; and (2) surprisingly, laminar models sometimes provide results that are in better agreement with experimental self-pressurization rates, even in parametric ranges where the bulk flow is deemed fully turbulent. In this light, shortcomings of the present CFD models, especially, numerical treatments of interfacial mass transfer and turbulence, as coupled to the Volume-of-Fluid (VOF) interface capturing scheme, are underscored and discussed.

Mercury contamination - Amalgamate (contract with NFS and ADA). Stabilize Elemental Mercury Wastes. Mixed Waste Focus Area. OST Reference Number 1675

DOE Office of Scientific and Technical Information (OSTI.GOV)

None, None

1999-09-01

Through efforts led by the Mixed Waste Focus Area (MWFA) and its Mercury Working Group (HgWG), the inventory of bulk elemental mercury contaminated with radionuclides stored at various U. S. Department of Energy (DOE) sites is thought to be approximately 16 m3 (Conley et al. 1998). At least 19 different DOE sites have this type of mixed low-level waste in their storage facilities. The U. S. Environmental Protection Agency (EPA) specifies amalgamation as the treatment method for radioactively contaminated elemental mercury. Although the chemistry of amalgamation is well known, the practical engineering of a sizable amalgamation process has not beenmore » tested (Tyson 1993). To eliminate the existing DOE inventory in a reasonable timeframe, scaleable equipment is needed that can: produce waste forms that meet the EPA definition of amalgamation, produce waste forms that pass the EPA Toxicity Characteristic Leaching Procedure (TCLP) limit of 0.20 mg/L, limit mercury vapor concentrations during processing to below the Occupational Safety and Health Administration’s (OSHA) 8-hour worker exposure limit (50 mg/m3) for mercury, and perform the above economically.« less

40 CFR 122.3 - Exclusions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... an energy or mining facility, a storage facility or a seafood processing facility, or when secured to a storage facility or a seafood processing facility, or when secured to the bed of the ocean...

40 CFR 122.3 - Exclusions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... an energy or mining facility, a storage facility or a seafood processing facility, or when secured to a storage facility or a seafood processing facility, or when secured to the bed of the ocean...

40 CFR 122.3 - Exclusions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... an energy or mining facility, a storage facility or a seafood processing facility, or when secured to a storage facility or a seafood processing facility, or when secured to the bed of the ocean...

40 CFR 122.3 - Exclusions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... an energy or mining facility, a storage facility or a seafood processing facility, or when secured to a storage facility or a seafood processing facility, or when secured to the bed of the ocean...

40 CFR 122.3 - Exclusions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... an energy or mining facility, a storage facility or a seafood processing facility, or when secured to a storage facility or a seafood processing facility, or when secured to the bed of the ocean...

Sequential structural and optical evolution of MoS2 by chemical synthesis and exfoliation

NASA Astrophysics Data System (ADS)

Kim, Ju Hwan; Kim, Jungkil; Oh, Si Duck; Kim, Sung; Choi, Suk-Ho

2015-06-01

Various types of MoS2 structures are successfully obtained by using economical and facile sequential synthesis and exfoliation methods. Spherically-shaped lumps of multilayer (ML) MoS2 are prepared by using a conventional hydrothermal method and were subsequently 1st-exfoliated in hydrazine while being kept in autoclave to be unrolled and separated into five-to-six-layer MoS2 pieces of several-hundred nm in size. The MoS2 MLs are 2nd-exfoliated in sodium naphthalenide under an Ar ambient to finally produce bilayer MoS2 crystals of ~100 nm. The sequential exfoliation processes downsize MoS2 laterally and reduce its number of layers. The three types of MoS2 allotropes exhibit particular optical properties corresponding to their structural differences. These results suggest that two-dimensional MoS2 crystals can be prepared by employing only chemical techniques without starting from high-pressure-synthesized bulk MoS2 crystals.

Facile preparation of antibacterial, highly elastic silvered polyurethane nanofiber fabrics using silver carbamate and their dermal wound healing properties.

PubMed

Hong, Suk-Min; Kim, Jong-Wan; Knowles, Jonathan C; Gong, Myoung-Seon

2017-02-01

In this study, polycarbonate diol/isosorbide-based antibacterial polyurethane nanofiber fabrics containing Ag nanoparticles were prepared by electrospinning process. Bio-based highly elastic polyurethane was prepared from hexamethylene diisocyanate and isosorbide/polycarbonate diol (8/2) by a simple one-shot bulk polymerization. Ag nanoparticles were formed using simple thermal reduction of silver 2-ethylhexylcarbamate at 120℃. The structural and morphological properties of polyurethane/Ag nanofibers were characterized by X-ray diffraction and scanning electron microscopy. The polyurethane nanofiber fabrics were flexible, with breaking strains from 355% to 950% under 7.28 to 23.1 MPa tensile stress. The antibacterial effects of the treated polyurethane/Ag fabrics against Staphylococcus aureus and methicillin resistant Staphylococcus aureus were examined and found to be excellent. Cell proliferation using the immortalized human keratinocyte HaCaT cell line was performed in order to determine cell viability in the presence of polyurethane and polyurethane/Ag fabrics, showing cytocompatiblility and a lack of toxicity.