A Survey of Measurement, Mitigation, and Verification Field Technologies for Carbon Sequestration Geologic Storage

NASA Astrophysics Data System (ADS)

Cohen, K. K.; Klara, S. M.; Srivastava, R. D.

2004-12-01

The U.S. Department of Energy's (U.S. DOE's) Carbon Sequestration Program is developing state-of-the-science technologies for measurement, mitigation, and verification (MM&V) in field operations of geologic sequestration. MM&V of geologic carbon sequestration operations will play an integral role in the pre-injection, injection, and post-injection phases of carbon capture and storage projects to reduce anthropogenic greenhouse gas emissions. Effective MM&V is critical to the success of CO2 storage projects and will be used by operators, regulators, and stakeholders to ensure safe and permanent storage of CO2. In the U.S. DOE's Program, Carbon sequestration MM&V has numerous instrumental roles: Measurement of a site's characteristics and capability for sequestration; Monitoring of the site to ensure the storage integrity; Verification that the CO2 is safely stored; and Protection of ecosystems. Other drivers for MM&V technology development include cost-effectiveness, measurement precision, and frequency of measurements required. As sequestration operations are implemented in the future, it is anticipated that measurements over long time periods and at different scales will be required; this will present a significant challenge. MM&V sequestration technologies generally utilize one of the following approaches: below ground measurements; surface/near-surface measurements; aerial and satellite imagery; and modeling/simulations. Advanced subsurface geophysical technologies will play a primary role for MM&V. It is likely that successful MM&V programs will incorporate multiple technologies including but not limited to: reservoir modeling and simulations; geophysical techniques (a wide variety of seismic methods, microgravity, electrical, and electromagnetic techniques); subsurface fluid movement monitoring methods such as injection of tracers, borehole and wellhead pressure sensors, and tiltmeters; surface/near surface methods such as soil gas monitoring and infrared sensors and; aerial and satellite imagery. This abstract will describe results, similarities, and contrasts for funded studies from the U.S. DOE's Carbon Sequestration Program including examples from the Sleipner North Sea Project, the Canadian Weyburn Field/Dakota Gasification Plant Project, the Frio Formation Texas Project, and Yolo County Bioreactor Landfill Project. The abstract will also address the following: How are the terms ``measurement,'' ``mitigation''and ``verification'' defined in the Program? What is the U.S. DOE's Carbon Sequestration Program Roadmap and what are the Roadmap goals for MM&V? What is the current status of MM&V technologies?

Defect stability in thorium monocarbide: An ab initio study

NASA Astrophysics Data System (ADS)

Wang, Chang-Ying; Han, Han; Shao, Kuan; Cheng, Cheng; Huai, Ping

2015-09-01

The elastic properties and point defects of thorium monocarbide (ThC) have been studied by means of density functional theory based on the projector-augmented-wave method. The calculated electronic and elastic properties of ThC are in good agreement with experimental data and previous theoretical results. Five types of point defects have been considered in our study, including the vacancy defect, interstitial defect, antisite defect, schottky defect, and composition-conserving defect. Among these defects, the carbon vacancy defect has the lowest formation energy of 0.29 eV. The second most stable defect (0.49 eV) is one of composition-conserving defects in which one carbon is removed to another carbon site forming a C2 dimer. In addition, we also discuss several kinds of carbon interstitial defects, and predict that the carbon trimer configuration may be a transition state for a carbon dimer diffusion in ThC. Project supported by the International S&T Cooperation Program of China (Grant No. 2014DFG60230), the National Natural Science Foundation of China (Grant No. 91326105), the National Basic Research Program of China (Grant No. 2010CB934504), and the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDA02040104).

Molecular-level chemistry of model single-crystal oxide surfaces with model halogenated compounds

NASA Astrophysics Data System (ADS)

Adib, Kaveh

Synchrotron-based X-ray photoelectron spectroscopy (XPS), temperature-programmed desorption (TPD) and low energy electron diffraction (LEED) have been used to investigate, at a molecular level, the chemistry of different terminations of single crystal iron-oxide surfaces with probe molecules (CCl4 and D2O). Comparisons of the reactivity of these surfaces towards CCl4, indicate that the presence of an uncapped surface Fe cation (strong Lewis acid site) and an adjacent oxygen site capped by that cation can effect the C-Cl bond cleavage in CCl4, resulting in dissociatively adsorbed Cl-adatoms and carbon-containing fragments. If in addition to these sites, an uncapped surface oxygen (Lewis base) site is also available, the carbon-containing moiety can then move that site, coordinate itself with that uncapped oxygen, and stabilize itself. At a later step, the carbon-containing fragment may form a strong covalent bond with the uncapped oxygen and may even abstract that surface oxygen. On the other hand, if an uncapped oxygen is not available to stabilize the carbon-containing fragment, the surface coordination will not occur and upon the subsequent thermal annealing of the surface the Cl-adatoms and the carbon-containing fragments will recombine and desorb as CCl4. Finally, the presence of surface deuteroxyls blocking the strong Lewis acid and base sites of the reactive surface, passivates this surface. Such a deuteroxylated surface will be unreactive towards CCl 4. Such a molecular level understanding of the surface chemistry of metal-oxides will have applications in the areas of selective catalysis, including environmental catalysis, and chemical sensor technology.

Calcium isotope evidence for suppression of carbonate dissolution in carbonate-bearing organic-rich sediments

NASA Astrophysics Data System (ADS)

Turchyn, Alexandra V.; DePaolo, Donald J.

2011-11-01

Pore fluid calcium isotope, calcium concentration and strontium concentration data are used to measure the rates of diagenetic dissolution and precipitation of calcite in deep-sea sediments containing abundant clay and organic material. This type of study of deep-sea sediment diagenesis provides unique information about the ultra-slow chemical reactions that occur in natural marine sediments that affect global geochemical cycles and the preservation of paleo-environmental information in carbonate fossils. For this study, calcium isotope ratios (δ 44/40Ca) of pore fluid calcium from Ocean Drilling Program (ODP) Sites 984 (North Atlantic) and 1082 (off the coast of West Africa) were measured to augment available pore fluid measurements of calcium and strontium concentration. Both study sites have high sedimentation rates and support quantitative sulfate reduction, methanogenesis and anaerobic methane oxidation. The pattern of change of δ 44/40Ca of pore fluid calcium versus depth at Sites 984 and 1082 differs markedly from that of previously studied deep-sea Sites like 590B and 807, which are composed of nearly pure carbonate sediment. In the 984 and 1082 pore fluids, δ 44/40Ca remains elevated near seawater values deep in the sediments, rather than shifting rapidly toward the δ 44/40Ca of carbonate solids. This observation indicates that the rate of calcite dissolution is far lower than at previously studied carbonate-rich sites. The data are fit using a numerical model, as well as more approximate analytical models, to estimate the rates of carbonate dissolution and precipitation and the relationship of these rates to the abundance of clay and organic material. Our models give mutually consistent results and indicate that calcite dissolution rates at Sites 984 and 1082 are roughly two orders of magnitude lower than at previously studied carbonate-rich sites, and the rate correlates with the abundance of clay. Our calculated rates are conservative for these sites (the actual rates could be significantly slower) because other processes that impact the calcium isotope composition of sedimentary pore fluid have not been included. The results provide direct geochemical evidence for the anecdotal observation that the best-preserved carbonate fossils are often found in clay or organic-rich sedimentary horizons. The results also suggest that the presence of clay minerals has a strong passivating effect on the surfaces of biogenic carbonate minerals, slowing dissolution dramatically even in relation to the already-slow rates typical of carbonate-rich sediments.

ARM Airborne Carbon Measurements VI (ACME VI) Science Plan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Biraud, S

2015-12-01

From October 1 through September 30, 2016, the Atmospheric Radiation Measurement (ARM) Aerial Facility will deploy the Cessna 206 aircraft over the Southern Great Plains (SGP) site, collecting observations of trace-gas mixing ratios over the ARM’s SGP facility. The aircraft payload includes two Atmospheric Observing Systems, Inc., analyzers for continuous measurements of CO2 and a 12-flask sampler for analysis of carbon cycle gases (CO2, CO, CH4, N2O, 13CO2, 14CO2, carbonyl sulfide, and trace hydrocarbon species, including ethane). The aircraft payload also includes instrumentation for solar/infrared radiation measurements. This research is supported by the U.S. Department of Energy’s ARM Climate Researchmore » Facility and Terrestrial Ecosystem Science Program and builds upon previous ARM Airborne Carbon Measurements (ARM-ACME) missions. The goal of these measurements is to improve understanding of 1) the carbon exchange at the SGP site, 2) how CO2 and associated water and energy fluxes influence radiative forcing, convective processes and CO2 concentrations over the SGP site, and 3) how greenhouse gases are transported on continental scales.« less

The Fall River Long-Term Site Productivity study in coastal Washington: site characteristics, methods, and biomass and carbon and nitrogen stores before and after harvest.

Treesearch

Adrian Ares; Thomas A. Terry; Kathryn B. Piatek; Robert B. Harrison; Richard E. Miller; Barry L. Flaming; ChristopherW Licata; Brian D. Strahm; Constance A. Harrington; Rodney Meade; Harry W. Anderson; Leslie C. Brodie; Joseph M. Kraft

2007-01-01

The Fall River research site in coastal Washington is an affiliate installation of the North American Long-Term Soil Productivity (LTSP) network, which constitutes one of the world’s largest coordinated research programs addressing forest management impacts on sustained productivity. Overall goals of the Fall River study are to assess effects of biomass removals, soil...

MX Siting Investigation. Water Resources Program Progress Report.

DTIC Science & Technology

1981-02-13

avoided. o Limestones and dolomites (carbonates) of Devonian age appear to be the major regional aquifers which hydrologically con- nect many valleys...that of the aquifer itself. Carbonate Aquifer. A aquifer, contained in limestone or dolomite rock, which occurs beneath the unconsolidated valley-fill...sediments and in the mountain ranges. Flow is believed to be primarily through fracture and solution openings rather than through normal inter

Characterizing the performance of ecosystem models across time scales: A spectral analysis of the North American Carbon Program site-level synthesis

Treesearch

Michael C. Dietze; Rodrigo Vargas; Andrew D. Richardson; Paul C. Stoy; Alan G. Barr; Ryan S. Anderson; M. Altaf Arain; Ian T. Baker; T. Andrew Black; Jing M. Chen; Philippe Ciais; Lawrence B. Flanagan; Christopher M. Gough; Robert F. Grant; David Hollinger; R. Cesar Izaurralde; Christopher J. Kucharik; Peter Lafleur; Shugang Liu; Erandathie Lokupitiya; Yiqi Luo; J. William Munger; Changhui Peng; Benjamin Poulter; David T. Price; Daniel M. Ricciuto; William J. Riley; Alok Kumar Sahoo; Kevin Schaefer; Andrew E. Suyker; Hanqin Tian; Christina Tonitto; Hans Verbeeck; Shashi B. Verma; Weifeng Wang; Ensheng Weng

2011-01-01

Ecosystem models are important tools for diagnosing the carbon cycle and projecting its behavior across space and time. Despite the fact that ecosystems respond to drivers at multiple time scales, most assessments of model performance do not discriminate different time scales. Spectral methods, such as wavelet analyses, present an alternative approach that enables the...

The strength of strategically placed in situ networks: The Critical Zone Observatory Program (Invited)

NASA Astrophysics Data System (ADS)

Bauer, S.; Benisch, K.; Li, D.; Beyer, C.; Mitiku, A. B.; Graupner, B.

2011-12-01

The Critical Zone Observatory (CZO) program, initiated by the U.S. National Science Foundation in 2007 with 3 sites, was expanded to 6 sites in 2009 and is expected to grow to at least 8 sites in FY 2014. The CZO program is now maturing into a coordinated network that enables scientific research around terrestrial fluxes of water, carbon and nutrients and informs societal questions around resource management and adaptation to climate change. Individual CZOs have contributed to understanding of the influences of disturbances and of changes in climate on fluxes and stores in critical ecosystems, and to a better predictive ability. CZOs have enabled the disciplinary integration needed to consider controlling processes together, from bedrock to boundary layer, and over sub-daily to millennial or longer times. Together, the CZO network has shown the role of climate versus disturbance on rain, snowfall and snowmelt reaching the ground surface, and the influences of climate, disturbance and regolith properties on partitioning of infiltrated water into evapotranspiration versus streamflow. The influence of disturbance is manifest both through abiotic factors, e.g. boundary-layer meteorology and turbulence, and through biotic influences, e.g. changes in vegetation density due to fire or disease, and thus interception and evapotranspiration. Climatic influences are overlain on this, including i) changes in rain versus snowfall and thus snowpack and soil-water storage, and ii) growing season and thus evapotranspiration. Carbon and nutrient fluxes are closely linked to those of water. Thus rich data sets and improved models from the CZO sites together provide a better understanding of the bi-directional feedbacks between vegetation structure, regolith properties and climate. Going forward, the CZO network as a whole offers well-instrumented sites with many common measurements and multi-disciplinary data across gradient of climate, parent material, vegetation structure and regolith properties. Measurements are at scales that are sufficiently large for research involving water, carbon or nutrient balances. Results are relevant to help guide decisions around vegetation management, and to understand the water, carbon and nutrient implications of vegetation-management options. The CZO network is a community platform for research, with the common, long-term observations across the multiple sites a resource available to all for multi-disciplinary critical-zone science.

The strength of strategically placed in situ networks: The Critical Zone Observatory Program (Invited)

NASA Astrophysics Data System (ADS)

Bales, R. C.; Brooks, P. D.; Molotch, N. P.

2013-12-01

The Critical Zone Observatory (CZO) program, initiated by the U.S. National Science Foundation in 2007 with 3 sites, was expanded to 6 sites in 2009 and is expected to grow to at least 8 sites in FY 2014. The CZO program is now maturing into a coordinated network that enables scientific research around terrestrial fluxes of water, carbon and nutrients and informs societal questions around resource management and adaptation to climate change. Individual CZOs have contributed to understanding of the influences of disturbances and of changes in climate on fluxes and stores in critical ecosystems, and to a better predictive ability. CZOs have enabled the disciplinary integration needed to consider controlling processes together, from bedrock to boundary layer, and over sub-daily to millennial or longer times. Together, the CZO network has shown the role of climate versus disturbance on rain, snowfall and snowmelt reaching the ground surface, and the influences of climate, disturbance and regolith properties on partitioning of infiltrated water into evapotranspiration versus streamflow. The influence of disturbance is manifest both through abiotic factors, e.g. boundary-layer meteorology and turbulence, and through biotic influences, e.g. changes in vegetation density due to fire or disease, and thus interception and evapotranspiration. Climatic influences are overlain on this, including i) changes in rain versus snowfall and thus snowpack and soil-water storage, and ii) growing season and thus evapotranspiration. Carbon and nutrient fluxes are closely linked to those of water. Thus rich data sets and improved models from the CZO sites together provide a better understanding of the bi-directional feedbacks between vegetation structure, regolith properties and climate. Going forward, the CZO network as a whole offers well-instrumented sites with many common measurements and multi-disciplinary data across gradient of climate, parent material, vegetation structure and regolith properties. Measurements are at scales that are sufficiently large for research involving water, carbon or nutrient balances. Results are relevant to help guide decisions around vegetation management, and to understand the water, carbon and nutrient implications of vegetation-management options. The CZO network is a community platform for research, with the common, long-term observations across the multiple sites a resource available to all for multi-disciplinary critical-zone science.

A model-data comparison of gross primary productivity: Results from the North American Carbon Program site synthesis

Treesearch

Kevin Schaefer; Christopher R. Schwalm; Chris Williams; M. Altaf Arain; Alan Barr; Jing M. Chen; Kenneth J. Davis; Dimitre Dimitrov; Timothy W. Hilton; David Y. Hollinger; Elyn Humphreys; Benjamin Poulter; Brett M. Raczka; Andrew D. Richardson; Alok Sahoo; Peter Thornton; Rodrigo Vargas; Hans Verbeeck; Ryan Anderson; Ian Baker; T. Andrew Black; Paul Bolstad; Jiquan Chen; Peter S. Curtis; Ankur R. Desai; Michael Dietze; Danilo Dragoni; Christopher Gough; Robert F. Grant; Lianhong Gu; Atul Jain; Chris Kucharik; Beverly Law; Shuguang Liu; Erandathie Lokipitiya; Hank A. Margolis; Roser Matamala; J. Harry McCaughey; Russ Monson; J. William Munger; Walter Oechel; Changhui Peng; David T. Price; Dan Ricciuto; William J. Riley; Nigel Roulet; Hanqin Tian; Christina Tonitto; Margaret Torn; Ensheng Weng; Xiaolu Zhou

2012-01-01

Accurately simulating gross primary productivity (GPP) in terrestrial ecosystem models is critical because errors in simulated GPP propagate through the model to introduce additional errors in simulated biomass and other fluxes. We evaluated simulated, daily average GPP from 26 models against estimated GPP at 39 eddy covariance flux tower sites across the United States...

Reactivity of a Carbon-Supported Single-Site Molybdenum Dioxo Catalyst for Biodiesel Synthesis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mouat, Aidan R.; Lohr, Tracy L.; Wegener, Evan C.

2016-08-23

A single-site molybdenum dioxo catalyst, (O c) 2Mo(=O) 2@C, was prepared via direct grafting of MoO 2Cl 2(dme) (dme = 1,2-dimethoxyethane) on high-surface- area activated carbon. The physicochemical and chemical properties of this catalyst were fully characterized by N 2 physisorption, ICP-AES/OES, PXRD, STEM, XPS, XAS, temperature-programmed reduction with H 2 (TPR-H 2), and temperature-programmed NH 3 desorption (TPD-NH 3). The single-site nature of the Mo species is corroborated by XPS and TPR-H 2 data, and it exhibits the lowest reported MoO x Tmax of reduction reported to date, suggesting a highly reactive MoVI center. (O c) 2Mo(=O) 2@C catalyzesmore » the transesterification of a variety of esters and triglycerides with ethanol, exhibiting high activity at moderate temperatures (60-90 °C) and with negligible deactivation. (O c) 2Mo(=O) 2@C is resistant to water and can be recycled at least three times with no loss of activity. The transesterification reaction is determined experimentally to be first order in [ethanol] and first order in [Mo] with ΔH = 10.5(8) kcal mol -1 and ΔS = -32(2) eu. The low energy of activation is consistent with the moderate conditions needed to achieve rapid turnover. This highly active carbon-supported single-site molybdenum dioxo species is thus an efficient, robust, and lowcost catalyst with significant potential for transesterification processes.« less

The GLOBE Carbon Project: Integrating the Science of Carbon Cycling and Climate Change into K-12 Classrooms.

NASA Astrophysics Data System (ADS)

Ollinger, S. V.; Silverberg, S.; Albrechtova, J.; Freuder, R.; Gengarelly, L.; Martin, M.; Randolph, G.; Schloss, A.

2007-12-01

The global carbon cycle is a key regulator of the Earth's climate and is central to the normal function of ecological systems. Because rising atmospheric CO2 is the principal cause of climate change, understanding how ecosystems cycle and store carbon has become an extremely important issue. In recent years, the growing importance of the carbon cycle has brought it to the forefront of both science and environmental policy. The need for better scientific understanding has led to establishment of numerous research programs, such as the North American Carbon Program (NACP), which seeks to understand controls on carbon cycling under present and future conditions. Parallel efforts are greatly needed to integrate state-of-the-art science on the carbon cycle and its importance to climate with education and outreach efforts that help prepare society to make sound decisions on energy use, carbon management and climate change adaptation. Here, we present a new effort that joins carbon cycle scientists with the International GLOBE Education program to develop carbon cycle activities for K-12 classrooms. The GLOBE Carbon Cycle project is focused on bringing cutting edge research and research techniques in the field of terrestrial ecosystem carbon cycling into the classroom. Students will collect data about their school field site through existing protocols of phenology, land cover and soils as well as new protocols focused on leaf traits, and ecosystem growth and change. They will also participate in classroom activities to understand carbon cycling in terrestrial ecosystems, these will include plant- a-plant experiments, hands-on demonstrations of various concepts, and analysis of collected data. In addition to the traditional GLOBE experience, students will have the opportunity to integrate their data with emerging and expanding technologies including global and local carbon cycle models and remote sensing toolkits. This program design will allow students to explore research questions from local to global scales with both present and future environmental conditions.

Hydrogeologic framework of fractured sedimentary rock, Newark Basin, New Jersey

USGS Publications Warehouse

Lacombe, Pierre J.; Burton, William C.

2010-01-01

The hydrogeologic framework of fractured sedimentary bedrock at the former Naval Air Warfare Center (NAWC), Trenton, New Jersey, a trichloroethylene (TCE)-contaminated site in the Newark Basin, is developed using an understanding of the geologic history of the strata, gamma-ray logs, and rock cores. NAWC is the newest field research site established as part of the U.S. Geological Survey Toxic Substances Hydrology Program, Department of Defense (DoD) Strategic Environmental Research and Development Program, and DoD Environmental Security Technology Certification Program to investigate contaminant remediation in fractured rock. Sedimentary bedrock at the NAWC research site comprises the Skunk Hollow, Byram, and Ewing Creek Members of the Lockatong Formation and Raven Rock Member of the Stockton Formation. Muds of the Lockatong Formation that were deposited in Van Houten cycles during the Triassic have lithified to form the bedrock that is typical of much of the Newark Basin. Four lithotypes formed from the sediments include black, carbon-rich laminated mudstone, dark-gray laminated mudstone, light-gray massive mudstone, and red massive mudstone. Diagenesis, tectonic compression, off-loading, and weathering have altered the rocks to give some strata greater hydraulic conductivity than other strata. Each stratum in the Lockatong Formation is 0.3 to 8 m thick, strikes N65 degrees E, and dips 25 degrees to 70 degrees NW. The black, carbon-rich laminated mudstone tends to fracture easily, has a relatively high hydraulic conductivity and is associated with high natural gamma-ray count rates. The dark-gray laminated mudstone is less fractured and has a lower hydraulic conductivity than the black carbon-rich laminated mudstone. The light-gray and the red massive mudstones are highly indurated and tend to have the least fractures and a low hydraulic conductivity. The differences in gamma-ray count rates for different mudstones allow gamma-ray logs to be used to correlate and delineate the lithostratigraphy from multiple wells. Gamma-ray logs and rock cores were correlated to develop a 13-layer gamma-ray stratigraphy and 41-layer lithostratigraphy throughout the fractured sedimentary rock research site. Detailed hydrogeologic framework shows that black carbon-rich laminated mudstones are the most hydraulically conductive. Water-quality and aquifer-test data indicate that groundwater flow is greatest and TCE contamination is highest in the black, carbon- and clay-rich laminated mudstones. Large-scale groundwater flow at the NAWC research site can be modeled as highly anisotropic with the highest component of permeability occurring along bedding planes.

Impact of hydrological variations on modeling of peatland CO2 fluxes: Results from the North American Carbon Program site synthesis

NASA Astrophysics Data System (ADS)

Sulman, Benjamin N.; Desai, Ankur R.; Schroeder, Nicole M.; Ricciuto, Dan; Barr, Alan; Richardson, Andrew D.; Flanagan, Lawrence B.; Lafleur, Peter M.; Tian, Hanqin; Chen, Guangsheng; Grant, Robert F.; Poulter, Benjamin; Verbeeck, Hans; Ciais, Philippe; Ringeval, Bruno; Baker, Ian T.; Schaefer, Kevin; Luo, Yiqi; Weng, Ensheng

2012-03-01

Northern peatlands are likely to be important in future carbon cycle-climate feedbacks due to their large carbon pools and vulnerability to hydrological change. Use of non-peatland-specific models could lead to bias in modeling studies of peatland-rich regions. Here, seven ecosystem models were used to simulate CO2fluxes at three wetland sites in Canada and the northern United States, including two nutrient-rich fens and one nutrient-poor,sphagnum-dominated bog, over periods between 1999 and 2007. Models consistently overestimated mean annual gross ecosystem production (GEP) and ecosystem respiration (ER) at all three sites. Monthly flux residuals (simulated - observed) were correlated with measured water table for GEP and ER at the two fen sites, but were not consistently correlated with water table at the bog site. Models that inhibited soil respiration under saturated conditions had less mean bias than models that did not. Modeled diurnal cycles agreed well with eddy covariance measurements at fen sites, but overestimated fluxes at the bog site. Eddy covariance GEP and ER at fens were higher during dry periods than during wet periods, while models predicted either the opposite relationship or no significant difference. At the bog site, eddy covariance GEP did not depend on water table, while simulated GEP was higher during wet periods. Carbon cycle modeling in peatland-rich regions could be improved by incorporating wetland-specific hydrology and by inhibiting GEP and ER under saturated conditions. Bogs and fens likely require distinct plant and soil parameterizations in ecosystem models due to differences in nutrients, peat properties, and plant communities.

Toward a Mexican eddy covariance network for carbon cycle science

NASA Astrophysics Data System (ADS)

Vargas, Rodrigo; Yépez, Enrico A.

2011-09-01

First Annual MexFlux Principal Investigators Meeting; Hermosillo, Sonora, Mexico, 4-8 May 2011; The carbon cycle science community has organized a global network, called FLUXNET, to measure the exchange of energy, water, and carbon dioxide (CO2) between the ecosystems and the atmosphere using the eddy covariance technique. This network has provided unprecedented information for carbon cycle science and global climate change but is mostly represented by study sites in the United States and Europe. Thus, there is an important gap in measurements and understanding of ecosystem dynamics in other regions of the world that are seeing a rapid change in land use. Researchers met under the sponsorship of Red Temática de Ecosistemas and Consejo Nacional de Ciencia y Tecnologia (CONACYT) to discuss strategies to establish a Mexican eddy covariance network (MexFlux) by identifying researchers, study sites, and scientific goals. During the meeting, attendees noted that 10 study sites have been established in Mexico with more than 30 combined years of information. Study sites span from new sites installed during 2011 to others with 9 to 6 years of measurements. Sites with the longest span measurements are located in Baja California Sur (established by Walter Oechel in 2002) and Sonora (established by Christopher Watts in 2005); both are semiarid ecosystems. MexFlux sites represent a variety of ecosystem types, including Mediterranean and sarcocaulescent shrublands in Baja California; oak woodland, subtropical shrubland, tropical dry forest, and a grassland in Sonora; tropical dry forests in Jalisco and Yucatan; a managed grassland in San Luis Potosi; and a managed pine forest in Hidalgo. Sites are maintained with an individual researcher's funds from Mexican government agencies (e.g., CONACYT) and international collaborations, but no coordinated funding exists for a long-term program.

Environmental Assessment for Anti-Terrorism/Force Protection Upgrades at Beale Air Force Base, California

DTIC Science & Technology

2004-04-01

triple-awn grass, annual fescues, and foxtail barley . Intermixed with these dominant grasses are an assemblage of native and non-native forb species...as a wheat- stem rust (fungal disease) biological production test site. Chemicals associated with the wheat- stem rust program included freon, carbon...Carboxide treatment (using a solution of 10 percent ethylene oxide and 90 percent carbon dioxide) was used to destroy the rust fungus stocks. Residual

San Francisco Deep Ocean Dredged Material Disposal Site (SF-DODS) Monitoring Program. Physical, Chemical, and Benthic Community Monitoring

DTIC Science & Technology

2003-08-29

analyzed for total volatile solids, total organic carbon, oil and grease/total petroleum hydrocarbons , grain size distribution, metals, polycyclic...TBT Tri-Butyltin TOC Total Organic Carbon TPCB Total Polychlorinated Biphenyls TPH Total Petroleum Hydrocarbons USACE U.S. Army Corps of Engineers U.S...Health PQL Practical Quantitation Limit RCRA Resource Conservation and Recovery Act SIM Selected Ion Monitoring TPH Total Petroleum Hydrocarbons tr Trace

Geophysical Monitoring Methods Evaluation for the FutureGen 2.0 Project

DOE PAGES

Strickland, Chris E.; USA, Richland Washington; Vermeul, Vince R.; ...

2014-12-31

A comprehensive monitoring program will be needed in order to assess the effectiveness of carbon sequestration at the FutureGen 2.0 carbon capture and storage (CCS) field-site. Geophysical monitoring methods are sensitive to subsurface changes that result from injection of CO 2 and will be used for: (1) tracking the spatial extent of the free phase CO 2 plume, (2) monitoring advancement of the pressure front, (3) identifying or mapping areas where induced seismicity occurs, and (4) identifying and mapping regions of increased risk for brine or CO 2 leakage from the reservoir. Site-specific suitability and cost effectiveness were evaluated formore » a number of geophysical monitoring methods including: passive seismic monitoring, reflection seismic imaging, integrated surface deformation, time-lapse gravity, pulsed neutron capture logging, cross-borehole seismic, electrical resistivity tomography, magnetotellurics and controlled source electromagnetics. The results of this evaluation indicate that CO 2 injection monitoring using reflection seismic methods would likely be difficult at the FutureGen 2.0 site. Electrical methods also exhibited low sensitivity to the expected CO 2 saturation changes and would be affected by metallic infrastructure at the field site. Passive seismic, integrated surface deformation, time-lapse gravity, and pulsed neutron capture monitoring were selected for implementation as part of the FutureGen 2.0 storage site monitoring program.« less

Geophysical Monitoring Methods Evaluation for the FutureGen 2.0 Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Strickland, Chris E.; USA, Richland Washington; Vermeul, Vince R.

A comprehensive monitoring program will be needed in order to assess the effectiveness of carbon sequestration at the FutureGen 2.0 carbon capture and storage (CCS) field-site. Geophysical monitoring methods are sensitive to subsurface changes that result from injection of CO 2 and will be used for: (1) tracking the spatial extent of the free phase CO 2 plume, (2) monitoring advancement of the pressure front, (3) identifying or mapping areas where induced seismicity occurs, and (4) identifying and mapping regions of increased risk for brine or CO 2 leakage from the reservoir. Site-specific suitability and cost effectiveness were evaluated formore » a number of geophysical monitoring methods including: passive seismic monitoring, reflection seismic imaging, integrated surface deformation, time-lapse gravity, pulsed neutron capture logging, cross-borehole seismic, electrical resistivity tomography, magnetotellurics and controlled source electromagnetics. The results of this evaluation indicate that CO 2 injection monitoring using reflection seismic methods would likely be difficult at the FutureGen 2.0 site. Electrical methods also exhibited low sensitivity to the expected CO 2 saturation changes and would be affected by metallic infrastructure at the field site. Passive seismic, integrated surface deformation, time-lapse gravity, and pulsed neutron capture monitoring were selected for implementation as part of the FutureGen 2.0 storage site monitoring program.« less

Paleo-Productivity across the Paleocene-Eocene Thermal Maximum, Walvis Ridge Transect (ODP Sites 1262, 1263, and 1266)

NASA Astrophysics Data System (ADS)

Chun, C. O.; Delaney, M. L.; Zachos, J. C.

2005-12-01

Walvis Ridge transect (Ocean Drilling Program (ODP) Leg 208) provides the first high-resolution depth-transect of deep-sea sediments recovered from the south Atlantic across the P/E boundary. A geographically restricted depth transect (~ 2.2 km, water depths between 2500 and 4770 m) allows us to constrain the surface waters by assuming marine productivity conditions in the overlying water column are similar across all sites. The sediment record will reveal variations for processes that are water-depth dependent. We use the geochemical tracers; biogenic barium, phosphorus, calcium carbonate, and the redox sensitive trace elements manganese and uranium, to reconstruct nutrient burial, paleoproductivity, and bottom water redox chemistry across the Paleocene-Eocene Thermal Maximum (PETM). We calculate our concentrations on a calcium carbonate-free basis to account for dilution by non-carbonate sediments. Trace metal enrichment factors (EFs) are calculated relative to bulk crustal averages. We chose three sites from the depth transect: the shallowest (Site 1263, 2717 m water depth), an intermediate site (Site 1266, 3798 m water depth), and the deepest site (Site 1262, 4755 m water depth). We sampled each site at a sample resolution of ~ 1-2 kyr for 5 m.y. centered at 55 Ma. Uranium EFs at the shallow site exhibits values ~ 5 pre-event and drop to values near crustal averages during and after the carbon isotope excursion (CIE). No dramatic changes in U EFs across the P/E boundary are recorded at the deep and intermediate sites. Mn EFs range between 2.9 -8.6 prior to the event across all three sites, suggesting an oxygenated depositional environment. At the boundary, Mn EFs drop to crustal averages at all sites, then gradually return to pre-event values, indicating more reducing environments during the CIE, a possible explanation for the benthic extinction event (BEE) observed across this transect. Ba excess and reactive phosphorus exhibit decreased concentrations during the CIE with gradual return to pre-event values at the shallowest and deepest sites. We will compare the paleo-productivity and redox chemistry response at the Walvis Ridge sites across the PETM.

Monitoring the hydrothermal system in Long Valley caldera, California

USGS Publications Warehouse

Farrar, C.D.; Sorey, M.L.

1985-01-01

An ongoing program to monitor the hydrothermal system in Long Valley for changes caused by volcanic or tectonic processes has produced considerable data on the water chemistry and discharge of springs and fluid temperatures and pressures in wells. Chemical and isotopic data collected under this program have greatly expanded the knowledge of chemical variability both in space and time. Although no chemical or isotopic changes in hot spring waters can be attributed directly to volcanic or tectonic processes, changes in hot spring chemistry that have been recorded probably relate to interactions between and variations in the quantity of liquid and gas discharged. Stable carbon isotope data are consistent with a carbon source either perform the mantle or from metamorphosed carbonate rocks. Continuous and periodic measurements of hot spring discharge at several sites show significant co seismic and a seismic changes since 1980.

Water-quality data from lakes in the Yukon Flats, Alaska, 2010-2011

USGS Publications Warehouse

Halm, Douglas R.; Griffith, Brad

2014-01-01

Over a two-year period (2010–2011), in-place measurements were made and water-quality samples were collected from 122 lakes in the Yukon Flats, Alaska, during a U.S. Geological Survey lake biological diversity inventory. The U.S. Geological Survey National Research Program performed the chemical analyses on the retrieved water-quality samples. Results from the analyses of water samples for dissolved carbon gases and carbon isotopes, hydrogen and oxygen stable isotopes, dissolved organic carbon, and major cations and anions, along with supporting site data, are presented in this report.

Formation of carbonate concretions in deep-sea sediment below the CCD and above an active gas hydrate system

NASA Astrophysics Data System (ADS)

Dicus, C. M.; Snyder, G. T.; Dickens, G. R.

2004-12-01

Site 1230 of the Ocean Drilling Program targeted the chemistry and microbiology of an active deep-water gas hydrate system in the Peru Trench. The site is noteworthy because, at nearly 6000 m water depth, it lies well below the carbonate compensation depth and the sediments comprise mostly terrigenous clays and biogenic silica. Shipboard work at this site delineated a prominent sulfate-methane transition (SMT) at 8-10 m below seafloor (mbsf) as well as some carbonate horizons. In this study, we present calcium and strontium data for pore waters and sediments at this site, including across the SMT. Concentration profiles show that dissolved Ca2+ diffuses downward from the seafloor toward the SMT, where a sharp inflection indicates consumption of Ca2+ into an authigenic phase. Dissolved Sr2+, on the other hand, diffuses upward from depth toward the SMT. Again, however, a prominent inflection suggests removal of Sr2+ to sediment. The inferences from pore water profiles are borne out by sediment chemistry. Large peaks in the calcium and strontium content of sediment mark the SMT. The calcium and strontium fronts reach ˜2700 and ˜5 mmol/kg, respectively, at 9 mbsf, which are much greater than average background values of ˜10 and ˜1 mmol/kg. These authigenic fronts are primarily composed of carbonate minerals, as determined by acetic acid extractions and x-ray diffraction. Because the calcium and strontium fronts coincide with both the SMT and changes in dissolved chemistry, it is proposed that the carbonates are currently forming as follows: methane rising from the underlying gas hydrate system reacts with dissolved sulfate through anaerobic oxidation of methane which releases HCO3- and alkalinity and causes carbonate precipitation. The overall process has been observed elsewhere; the Peru Trench is interesting, however, because the process leads to carbonate in sediments otherwise devoid of carbonate.

Annual Radioactive Waste Tank Inspection Program 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

McNatt, F.G. Sr.

1995-04-01

Aqueous radioactive wastes from Savannah River Site (SRS) separations processes are contained in large underground carbon steel tanks. Inspections made during 1994 to evaluate these vessels and evaluations based on data accrued by inspections made since the tanks were constructed are the subject of this report.

The structure and function of supported molybdenum nitride and molybdenum carbide hydrotreating catalysts

NASA Astrophysics Data System (ADS)

Dolce, Gregory Martin

1997-11-01

A series of gamma-Alsb2Osb3 supported molybdenum nitrides and carbides were prepared by the temperature programmed reaction of supported molybdates with ammonia and methane/hydrogen mixtures, respectively. In the first part of this research, the effects of synthesis heating rates and molybdenum loading on the catalytic properties of the materials were examined. A significant amount of excess carbon was deposited on the surface of the carbides during synthesis. The materials consisted of small particles which were very highly dispersed. Oxygen chemisorption indicated that the nitride particles may have been two-dimensional. The dispersion of the carbides, however, appeared to decrease as the loading increased. The catalysts were evaluated for hydrodenitrogenation (HDN), hydrodesulfurization (HDS), and hydrodeoxygenation (HDO). The molybdenum loading had the largest effect on the activity of the materials. For the nitrides, the HDN and HDS activities were inverse functions of the loading. This suggested that the most active HDN and HDS sites were located at the perimeter of the two-dimensional particles. The HDN and HDS activities of the carbides followed the same trend as the oxygen uptake. This result suggested that oxygen titrated the active sites on the supported carbides. Selected catalysts were evaluated for methylcarbazole HDN, dibenzothiophene HDS, and dibenzofuran HDO. The activity and selectivity of the nitrides and carbides were competitive with a presulfided commercial catalyst. In the second part of this work, a series of supported nitrides and carbides were prepared using a wider range of loadings (5-30 wt% Mo). Thermogravimetric analysis was used to determine the temperature at which excess carbon was deposited on the carbides. By modifying the synthesis parameters, the deposition of excess carbon was effectively inhibited. The dispersions of the supported nitrides and carbides were constant and suggested that the materials consisted of two-dimensional raft-like particles. The HDN activity of the nitrides decreased as the loading increased, while that of the carbides was relatively constant. Carbon monoxide and methylamine adsorbed on the same types of sites on the nitrides and carbides. Infrared spectroscopy and temperature programmed desorption revealed that some methylamine underwent HDN on the nitrides and carbides. Carbon monoxide appeared to adsorb on two types of sites. One type of site adsorbed CO which desorbed upon heating while the other type of site adsorbed CO which dissociated when the material was heated. The relative amounts of desorbed CO and methylamine scaled with the activity of the nitrides suggesting that CO and methylamine titrated the active sites. It appeared that the active sites of the supported carbides were different from those on the supported nitrides. It was proposed that the active sites on the supported nitrides were at the perimeter of the two-dimensional particles while the active sites of the carbides were "on top" of the particles.

An initial examination of carbonate variability in the western equatorial Pacific: XRF results from the lower to middle Miocene of IODP Site U1490

NASA Astrophysics Data System (ADS)

Valerio, D. A.; Kulhanek, D. K.; Rosenthal, Y.; Holbourn, A. E.

2017-12-01

International Ocean Discovery Program (IODP) Expedition 363 sought to determine the nature of and driving forces behind climate variability in the Western Pacific Warm Pool (WPWP) region throughout the Neogene on millennial, orbital, and geologic timescales. Our research focuses on the Miocene (19-9 Ma) sediment record from IODP Site U1490 to examine changes in carbonate production and burial in the WPWP as a record of variations in the regional/global carbon cycle. This interval is of particular interest because it spans the Middle Miocene Climatic Optimum, the Middle Miocene Climate Transition, and the late Miocene carbonate crash. Site U1490 is located on the northern edge of Eauripik Rise at 05°58.95'N, 142°39.27'E in the northern part of the WPWP. At 2341 m water depth, today the site is bathed in Upper Circumpolar Deepwater. Miocene sediment at Site U1490 primarily consists of clay-bearing to clay-rich foraminifer-rich nannofossil ooze, although biogenic silica (primarily radiolaria) is a significant component in the lowermost part of the record. The sedimentation rate in the early to middle Miocene was very low (<1 cm/kyr), increasing to 1.6 cm/kyr in the late Miocene. Initial shipboard results show an average calcium carbonate content of 87 wt% throughout the site, with the most significant variations in the lower to middle Miocene, where contents range from 20 to 85 wt%. We collected X-ray fluorescence (XRF) data at 1 cm resolution along the composite stratigraphic section over the 19-9 Ma interval to obtain a qualitative measure of the bulk chemistry of the sediment. We will use the weight percent calcium carbonate of discrete samples to calibrate the XRF data to generate a high-resolution carbonate record. We observe cyclical variations in the Ca/Ba, which may reflect variations in productivity and/or dissolution through this interval, although additional work is needed to fully interpret these data. Ultimately our research will allow for comparison between records obtained from these cores located in the western equatorial Pacific to those obtained in the eastern and central Pacific, which will better elucidate the nature of the carbon system during the Miocene.

Early to middle Miocene climate evolution: New insights from IODP Sites U1335, U1337 and U1338 (eastern equatorial Pacific Ocean)

NASA Astrophysics Data System (ADS)

Kochhann, Karlos G. D.; Holbourn, Ann; Kuhnt, Wolfgang; Lyle, Mitch; Raffi, Isabella; Channell, James E.; Andersen, Nils

2015-04-01

The lower to middle Miocene (~20 to 13 Ma) carbonate-rich sedimentary successions recovered at Integrated Ocean Drilling Program (IODP) Sites U1335, U1337 and U1338 allow unsurpassed resolution over the Climatic Optimum (16.9-14.7 Ma) and the transition into a colder climate mode after 13.9 Ma with re-establishment of permanent Antarctic ice sheets. High-resolution (1-10 kyr) stable carbon (δ13C) and oxygen (δ18O) isotopes of well-preserved epibenthic foraminifera (Cibicidoides mundulus and Planulina wuellerstorfi) from these three sites show that the Climatic Optimum was characterized by high-amplitude climate variations and intense perturbations of the carbon cycle. Episodes of peak warmth coincided with transient shoaling of the carbonate compensation depth and enhanced carbonate dissolution in the deep ocean. The U1335 and U1337 records additionally reveal that the rapid global warming and/or polar ice melting event, marking the onset of the Climatic Optimum at ~16.9 Ma, was coupled to a massive increase in carbonate dissolution, indicated by sharp drops in carbonate percentages and accumulation rates and by the fragmentation or complete dissolution of planktonic foraminifers. After ~14.7 Ma, stepwise global cooling, culminating with extensive ice growth over Antarctica at ~13.8 Ma, coincide with enhanced opal and benthic foraminiferal accumulation rates, suggesting that increased siliceous productivity and organic carbon burial may have contributed to CO2 drawdown. Integration of age models derived from orbitally-tuned, high-resolution isotopes, biostratigraphic data and magnetic reversals allows further constraints on the temporal sequence of events and helps unravel the drivers of early to middle Miocene climate variations.

Factors influencing the rates, processes and magnitude of accumulation of carbon in desert soils

NASA Technical Reports Server (NTRS)

Mcfadden, Leslie D.

1994-01-01

This report summarizes research funded through NASA's Soil Landscape Climate Program which includes studies of the systematics of carbon storage and flux in the terrestrial environment, specifically terrestrial soils. Efforts focussed on the nature of carbon behavior in arid environments, where the majority of the carbon is present as inorganic carbon stored as pedogenic carbonate in desert calcic soils. Studies were supported of soils in two areas of western North America's major deserts: the Mojave Desert and the Chihuahuan Desert. Part 1 of this report summarizes the results of research conducted in the area of the Providence Mountains, California in the eastern Mojave Desert. Part 2 of this report summarizes the results of research in the Sevilleta Wildlife Refuge in central New Mexico, one of the sites of the UMN Biology Department's Long Term Ecological Research.

SOIL QUALITY RECOVERY IN PREVIOUSLY FARMED FIELDS SEEDED TO PERENNIAL WARM SEASON NATIVE GRASS

EPA Science Inventory

A study of twelve Conservation Reserve Program sites in northeastern Kansas was conducted to determine native grass species and selected soil textures influence on soil quality recovery.
Plant productivity, plant carbon and nitrogen concentrations, total soil nitrogen and car...

ANNUAL RADIOACTIVE WASTE TANK INSPECTION PROGRAM 2008

DOE Office of Scientific and Technical Information (OSTI.GOV)

West, B.; Waltz, R.

2009-06-11

Aqueous radioactive wastes from Savannah River Site (SRS) separations and vitrification processes are contained in large underground carbon steel tanks. Inspections made during 2008 to evaluate these vessels and other waste handling facilities along with evaluations based on data from previous inspections are the subject of this report.

MX Siting Investigation. Water Resources Program. Volume I. Preliminary Water Management Report.

DTIC Science & Technology

1981-09-28

ficantly less than that of the valley-fill aquifer. This well was not situated, however, in an area of extensive fracturing which has been demonstrated by...SEPT 81 TAOLE 4-41 E-TR-53 63 Section 4.2.1, although wells should be constructed in highly fractured areas for best yields. Carbonate aquifer...correspondingly limited pump capacity. Also, this well was not in a highly fractured area. It is recommended that wells tapping the re- gional carbonate

Repeated occurrences of methanogenic zones, diagenetic dolomite formation and linked silicate alteration in southern Bering Sea sediments (Bowers Ridge, IODP Exp. 323 Site U1341)

NASA Astrophysics Data System (ADS)

Wehrmann, L. M.; Ockert, C.; Mix, A. C.; Gussone, N.; Teichert, B. M. A.; Meister, P.

2016-03-01

Diagenetic precipitates, such as dolomite, and the chemistry of residual deeply buried porewater often represent the only traces of past biogeochemical activity in marine sediments. A 600 m thick sedimentary section, recently drilled at Integrated Ocean Drilling Program (IODP) Site U1341 on Bowers Ridge (southern Bering Sea), provides insight into such a 4.3 Ma old paleo-diagenetic archive. Hard-lithified calcite-dolomite layers, and laminae of disseminated carbonate, were recovered in diatom-rich sediments over a depth range of 400 m. Carbon isotope values of the diagenetic carbonates between -16.6 and -14.4‰ (VPDB) and strontium isotope ratios of dolomites close to past seawater values suggest carbonate precipitation induced by the production of dissolved inorganic carbon (DIC) during elevated rates of organic carbon mineralization, primarily via sulfate reduction, at shallow sediment depth below the paleo-seafloor. Diagenetic carbonates at 280-440 m below seafloor were likely also produced by the intermittent onset of sulfate reduction coupled to the anaerobic oxidation of methane (AOM) at sulfate-methane transition zones (SMTZ). These microbially mediated processes do not occur in the sediment at this site at present but were likely connected to the presence of a methanogenic zone at 2.58-2.51 Ma. A minimum in sulfate concentrations in modern porewaters and low sedimentary Ba/Al ratios resulting from former sulfate depletion are reminiscent of the presence of this large methanogenic zone. The minimum in sulfate concentrations is reflected in a minimum in magnesium concentrations, less radiogenic strontium and isotopically light calcium in the porewater. It is proposed that magnesium was removed from the porewater during carbonate precipitation and volcanic ash alteration which occurred in the former methanogenic zone and also released strontium with a less radiogenic isotope ratio and isotopically light calcium into the porewater. The isotopic composition of porewater calcium was also influenced by ammonium-calcium exchange on clay minerals and carbonate recrystallization. Our study elucidates the response of porewater element concentrations and isotopic profiles interlinked with the formation of diagenetic carbonates to changes in the deposition of organic carbon in sediments of deeper water sites (>2000 m water depth) over prolonged timescales. It shows that variations in biogeochemical processes in response to changes in oceanographic conditions and a dynamic subseafloor biogeochemical zonation have to also be taken into account at these deep water sites for a global assessment of organic carbon burial fluxes and remineralization.

Mechanism of SO2 removal by carbon

USGS Publications Warehouse

Lizzio, Anthony A.; DeBarr, Joseph A.

1997-01-01

The reaction of SO2 with carbon (C) in the presence of O2 and H2O involves a series of reactions that leads to the formation of sulfuric acid as the final product. The rate-determining step in the overall process is the oxidation of SO2 to SO3. Three SO2 oxidation reactions are possible. Adsorbed SO2 (C−SO2) can react either with gas phase O2 or with adsorbed oxygen (C−O complex) to form sulfur trioxide (SO3), or gas phase SO2 can react directly with the C−O complex. In optimizing the SO2 removal capabilities of carbon, most studies only assume a given mechanism for SO2 adsorption and conversion to H2SO4 to be operable. The appropriate SO2 oxidation step and role of the C−O complex in this mechanism remain to be determined. The ultimate goal of this study was to prepare activated char from Illinois coal with optimal properties for low-temperature (80−150°C) removal of sulfur dioxide from coal combustion flue gas. The SO2 adsorption capacity of activated char was found to be inversely proportional to the amount of oxygen adsorbed on its surface. A temperature-programmed desorption technique was developed to titrate those sites responsible for adsorption of SO2 and conversion to H2SO4. On the basis of these results, a mechanism for SO2 removal by carbon was proposed. The derived rate expression showed SO2 adsorption to be dependent only on the fundamental rate constant and concentration of carbon atoms designated as free sites. Recent studies indicate a similar relationship exists between the rate of carbon gasification (in CO2 or H2O) and the number of reactive sites as determined by transient kinetics experiments. Utilizing the concept of active or free sites, it was possible to produce a char from Illinois coal having an SO2 adsorption capacity surpassing that of a commercial catalytic activated carbon.

An initial examination of carbonate production in the western equatorial Pacific: XRF results from the Pliocene-Pleistocene of IODP Site U1490

NASA Astrophysics Data System (ADS)

Chapman, J.; Kulhanek, D. K.; Rosenthal, Y.; Holbourn, A. E.

2017-12-01

International Ocean Discovery Program (IODP) Expedition 363 sought to determine the nature of and driving forces behind climate variability in the Western Pacific Warm Pool (WPWP) region throughout the Neogene on millennial, orbital, and geologic timescales. Our research focuses on the Pliocene to recent (4-0 Ma) sediment record from IODP Site U1490 to examine changes in carbonate production and burial in the WPWP as a record of variations in the regional/global carbon cycle. This interval is of particular interest because it spans the Middle Pliocene Warm Period, the initiation of Northern Hemisphere Glaciation, and the Mid-Pleistocene Transition. Site U1490 is located on the northern edge of Eauripik Rise at 05°58.95'N, 142°39.27'E in the northern part of the WPWP. At 2341 m water depth, today the site is bathed in Upper Circumpolar Deepwater. Pliocene to recent sediment primarily consists of foraminifer-rich nannofossil ooze, with the sedimentation rate varying between 1.5 and 3 cm/kyr. Initial shipboard measurement of calcium carbonate content shows little variation at low resolution (1 sample every few meters), varying between 90 and 95 wt%. We collected X-ray fluorescence (XRF) data at 2 cm resolution along the composite stratigraphic section to obtain a qualitative measure of the bulk chemistry of the sediment. We will use the weight percent calcium carbonate of discrete samples to calibrate the XRF data to generate a high-resolution carbonate record. We observe cyclical variations in the Ca/Ba, which may reflect variations in productivity and/or dissolution through this interval, although additional work is needed to fully interpret these data. Ultimately our research will allow for comparison between records obtained from these cores located in the western equatorial Pacific to those obtained in the eastern and central Pacific, which will better elucidate the nature of the carbon system during the Plio-Pleistocene.

Carbonate substitution in the mineral component of bone: Discriminating the structural changes, simultaneously imposed by carbonate in A and B sites of apatite

NASA Astrophysics Data System (ADS)

Madupalli, Honey; Pavan, Barbara; Tecklenburg, Mary M. J.

2017-11-01

The mineral component of bone and other biological calcifications is primarily a carbonate substituted calcium apatite. Integration of carbonate into two sites, substitution for phosphate (B-type carbonate) and substitution for hydroxide (A-type carbonate), influences the crystal properties which relate to the functional properties of bone. In the present work, a series of AB-type carbonated apatites (AB-CAp) having varying A-type and B-type carbonate weight fractions were prepared and analyzed by Fourier transform infrared spectroscopy (FTIR), powder X-ray diffraction (XRD), and carbonate analysis. A detailed characterization of A-site and B-site carbonate assignment in the FTIR ν3 region is proposed. The mass fractions of carbonate in A-site and B-site of AB-CAp correlate differently with crystal axis length and crystallite domain size. In this series of samples reduction in crystal domain size correlates only with A-type carbonate which indicates that carbonate in the A-site is more disruptive to the apatite structure than carbonate in the B-site. High temperature methods were required to produce significant A-type carbonation of apatite, indicating a higher energy barrier for the formation of A-type carbonate than for B-type carbonate. This is consistent with the dominance of B-type carbonate substitution in low temperature synthetic and biological apatites.

78 FR 48639 - North Dakota Underground Injection Control Program Revision Application

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-09

... Dakota Industrial Commission, Oil and Gas Division 1016 East Calgary Avenue, Bismarck, North Dakota 58503... the North Dakota Industrial Commission (NDIC) to issue UIC permits for carbon geo-sequestration... protected through www.regulations.gov or email. The www.regulations.gov Web site is an ``anonymous access...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meyers, Tilden

This is the AmeriFlux version of the carbon flux data for the site US-Goo Goodwin Creek. Site Description - The Goodwin Creek site is located in the Bluff Hills, just east of the Mississippi River valley. In addition to being a core AmeriFlux site, Goodwin Creek is also affiliated with a multitude of other projects including SURFRAD, BSRN, and one of the twelve watersheds in the USDA Conservation Reserve Program. Natural disturbances are of minimal influence to the site. The immediate region is primarily used for grazing while infrequent logging activities occur in nearby forests. The grass surrounding the basemore » of the tower is mowed periodically to maintain a height consistent with the regional grasslands.« less

The path to a successful one-million tonne demonstration of geological sequestration: Characterization, cooperation, and collaboration

USGS Publications Warehouse

Finley, R.J.; Greenberg, S.E.; Frailey, S.M.; Krapac, I.G.; Leetaru, H.E.; Marsteller, S.

2011-01-01

The development of the Illinois Basin-Decatur USA test site for a 1 million tonne injection of CO2 into the Mount Simon Sandstone saline reservoir beginning in 2011 has been a multiphase process requiring a wide array of personnel and resources that began in 2003. The process of regional characterization took two years as part of a Phase I effort focused on the entire Illinois Basin, located in Illinois, Indiana, and Kentucky, USA. Seeking the cooperation of an industrial source of CO2 and site selection within the Basin took place during Phase II while most of the concurrent research emphasis was on a set of small-scale tests of Enhanced Oil Recovery (EOR) and CO2 injection into a coal seam. Phase III began the commitment to the 1 million-tonne test site development through the collaboration of the Archer Daniels Midland Company (ADM) who is providing a site, the CO2, and developing a compression facility, of Schlumberger Carbon Services who is providing expertise for operations, drilling, geophysics, risk assessment, and reservoir modelling, and of the Illinois State Geological Survey (ISGS) whose geologists and engineers lead the Midwest Geological Sequestration Consortium (MGSC). Communications and outreach has been a collaborative effort of ADM, ISGS and Schlumberger Carbon Services. The Consortium is one of the seven Regional Carbon Sequestration Partnerships, a carbon sequestration research program supported by the National Energy Technology Laboratory of the U.S. Department of Energy. ?? 2011 Published by Elsevier Ltd.

Quantifying climate change mitigation potential in Great Plains wetlands for three greenhouse gas emission scenarios

USGS Publications Warehouse

Byrd, Kristin B.; Ratliff, Jamie L.; Wein, Anne; Bliss, Norman B.; Sleeter, Benjamin M.; Sohl, Terry L.; Li, Zhengpeng

2015-01-01

We examined opportunities for avoided loss of wetland carbon stocks in the Great Plains of the United States in the context of future agricultural expansion through analysis of land-use land-cover (LULC) change scenarios, baseline carbon datasets and biogeochemical model outputs. A wetland map that classifies wetlands according to carbon pools was created to describe future patterns of carbon loss and potential carbon savings. Wetland avoided loss scenarios, superimposed upon LULC change scenarios, quantified carbon stocks preserved under criteria of carbon densities or land value plus cropland suitability. Up to 3420 km2 of wetlands may be lost in the region by 2050, mainly due to conversion of herbaceous wetlands in the Temperate Prairies where soil organic carbon (SOC) is highest. SOC loss would be approximately 0.20 ± 0.15 megagrams of carbon per hectare per year (MgC ha−1 yr−1), depending upon tillage practices on converted wetlands, and total ecosystem carbon loss in woody wetlands would be approximately 0.81 ± 0.41 MgC ha−1 yr−1, based on biogeochemical model results. Among wetlands vulnerable to conversion, wetlands in the Northern Glaciated Plains and Lake Agassiz Plains ecoregions exhibit very high mean SOC and on average, relatively low land values, potentially creating economically competitive opportunities for avoided carbon loss. This mitigation scenarios approach may be adapted by managers using their own preferred criteria to select sites that best meet their objectives. Results can help prioritize field-based assessments, where site-level investigations of carbon stocks, land value, and consideration of local priorities for climate change mitigation programs are needed.

76 FR 56982 - Announcement of Federal Underground Injection Control (UIC) Class VI Program for Carbon Dioxide (CO2

Federal Register 2010, 2011, 2012, 2013, 2014

2011-09-15

... and Administration priorities for developing and deploying CCS projects in the next few years as... VI rule finalized on December 10, 2010. Direct Federal implementation of the final Class VI... on the final Class VI rule, visit the Underground Injection Control Geologic Sequestration Web site...

Trace element evidence for abrupt changes in deep South Atlantic Ocean nutrient and carbonate chemistry across the Mid-Pleistocene Transition

NASA Astrophysics Data System (ADS)

Farmer, J. R.; Hoenisch, B.; Haynes, L.; Kroon, D.; Bell, D. B.; Jung, S.; Seguí, M. J.; Raymo, M. E.; Goldstein, S. L.; Pena, L. D.

2016-12-01

Pleistocene glaciations underwent a profound transition from lower amplitude 40 kyr cycles to high amplitude 100 kyr cycles between 1.2 and 0.8 Ma, an interval termed the Mid-Pleistocene Transition (MPT). While the underlying causes of the MPT are uncertain, previous studies show quasi-contemporaneous reductions in North Atlantic Deep Water (NADW) export1 and glacial atmospheric pCO22 around 0.9 Ma. Although this suggests a possible role for enhanced deep-ocean carbon storage in amplifying climate change across the MPT, few direct records of deep ocean carbonate chemistry exist for this interval to test this hypothesis. Here we present South Atlantic benthic foraminiferal B/Ca and Cd/Ca records from International Ocean Discovery Program Sites 1088, 1264 and 1267 (2.1 to 4.3 km water depth) as part of a larger study of Atlantic-wide changes in deep ocean chemistry and circulation spanning the MPT. Results show an abrupt 15-20% decrease in benthic B/Ca and 40-50% increase in Cd/Ca at 4.3 km depth (Site 1267) between 1.0 and 0.9 Ma. Site 1088, which at 2.1 km depth is sensitive to input of southern-sourced Upper Circumpolar Deep Water, shows a prolonged 25% decrease in B/Ca and 50% increase in Cd/Ca from 1.0 to 0.6 Ma. In contrast, at Site 1264 ( 2.5 km depth within the core of modern NADW) B/Ca and Cd/Ca changes across the MPT are more modest (-5% and +10%, respectively). These observations reflect on the accumulation of regenerated carbon and nutrients in the deep South Atlantic, and varying contributions of northern- and southern-sourced watermasses to each core site. Implications for deep-ocean carbon storage and forcing of the MPT will be discussed. 1Pena, L. and Goldstein, S. (2014), Science 345, 318 2Hönisch, B. et al. (2009), Science 324, 1551

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kammen, D.M.

Kenya is said to be an ideal site for projects that promote renewable energy sources since it devotes over forty percent of its GNP to the purchase of imported coal and oil. The author presents a chronology of solar oven projects in Kenya and suggests that success of the program will be measured by the number of people who move on to wind turbine use. He discusses the role of renewable energy technology in reducing greenhouse gases and closes by recommending that industrialized nations that produce large amounts of carbon dioxide provide aid to develop projects that reduce carbon dioxidemore » elsewhere in the world. At the same time they would receive credit towards their carbon dioxide quotas.« less

SITEHOUND-web: a server for ligand binding site identification in protein structures.

PubMed

Hernandez, Marylens; Ghersi, Dario; Sanchez, Roberto

2009-07-01

SITEHOUND-web (http://sitehound.sanchezlab.org) is a binding-site identification server powered by the SITEHOUND program. Given a protein structure in PDB format SITEHOUND-web will identify regions of the protein characterized by favorable interactions with a probe molecule. These regions correspond to putative ligand binding sites. Depending on the probe used in the calculation, sites with preference for different ligands will be identified. Currently, a carbon probe for identification of binding sites for drug-like molecules, and a phosphate probe for phosphorylated ligands (ATP, phoshopeptides, etc.) have been implemented. SITEHOUND-web will display the results in HTML pages including an interactive 3D representation of the protein structure and the putative sites using the Jmol java applet. Various downloadable data files are also provided for offline data analysis.

NACP Synthesis: Evaluating modeled carbon state and flux variables against multiple observational constraints (Invited)

NASA Astrophysics Data System (ADS)

Thornton, P. E.; Nacp Site Synthesis Participants

2010-12-01

The North American Carbon Program (NACP) synthesis effort includes an extensive intercomparison of modeled and observed ecosystem states and fluxes preformed with multiple models across multiple sites. The participating models span a range of complexity and intended application, while the participating sites cover a broad range of natural and managed ecosystems in North America, from the subtropics to arctic tundra, and coastal to interior climates. A unique characteristic of this collaborative effort is that multiple independent observations are available at all sites: fluxes are measured with the eddy covariance technique, and standard biometric and field sampling methods provide estimates of standing stock and annual production in multiple categories. In addition, multiple modeling approaches are employed to make predictions at each site, varying, for example, in the use of diagnostic vs. prognostic leaf area index. Given multiple independent observational constraints and multiple classes of model, we evaluate the internal consistency of observations at each site, and use this information to extend previously derived estimates of uncertainty in the flux observations. Model results are then compared with all available observations and models are ranked according to their consistency with each type of observation (high frequency flux measurement, carbon stock, annual production). We demonstrate a range of internal consistency across the sites, and show that some models which perform well against one observational metric perform poorly against others. We use this analysis to construct a hypothesis for combining eddy covariance, biometrics, and other standard physiological and ecological measurements which, as data collection proceeded over several years, would present an increasingly challenging target for next generation models.

CCS Activities Being Performed by the U.S. DOE

PubMed Central

Dressel, Brian; Deel, Dawn; Rodosta, Traci; Plasynski, Sean; Litynski, John; Myer, Larry

2011-01-01

The United States Department of Energy (DOE) is the lead federal agency for the development and deployment of carbon sequestration technologies. Its mission includes promoting scientific and technological innovations and transfer of knowledge for safe and permanent storage of CO2 in the subsurface. To accomplish its mission, DOE is characterizing and classifying potential geologic storage reservoirs in basins throughout the U.S. and Canada, and developing best practices for project developers, to help ensure the safety of future geologic storage projects. DOE’s Carbon Sequestration Program, Regional Carbon Sequestration Partnership (RCSP) Initiative, administered by the National Energy Technology Laboratory (NETL), is identifying, characterizing, and testing potential injection formations. The RCSP Initiative consists of collaborations among government, industry, universities, and international organizations. Through this collaborative effort, a series of integrated knowledge-based tools have been developed to help potential sequestration project developers. They are the Carbon Sequestration Atlas of the United States and Canada, National Carbon Sequestration Database and Geographic System (NATCARB), and best practice manuals for CCS including Depositional Reservoir Classification for CO2; Public Outreach and Education for Carbon Storage Projects; Monitoring, Verification, and Accounting of CO2 Stored in Deep Geologic Formation; Site Screening, Site Selection, and Initial Characterization of CO2 Storage in Deep Geologic Formations. DOE’s future research will help with refinement of these tools and additional best practice manuals (BPM) which focus on other technical aspects of project development. PMID:21556188

Evaluation of Five Sedimentary Rocks Other Than Salt for Geologic Repository Siting Purposes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Croff, A.G.; Lomenick, T.F.; Lowrie, R.S.

The US Department of Energy (DOE), in order to increase the diversity of rock types under consideration by the geologic disposal program, initiated the Sedimary ROck Program (SERP), whose immediate objectiv eis to evaluate five types of secimdnary rock - sandstone, chalk, carbonate rocks (limestone and dolostone), anhydrock, and shale - to determine the potential for siting a geologic repository. The evaluation of these five rock types, together with the ongoing salt studies, effectively results in the consideration of all types of relatively impermeable sedimentary rock for repository purposes. The results of this evaluation are expressed in terms of amore » ranking of the five rock types with respect to their potential to serve as a geologic repository host rock. This comparative evaluation was conducted on a non-site-specific basis, by use of generic information together with rock evaluation criteria (RECs) derived from the DOE siting guidelines for geologic repositories (CFR 1984). An information base relevant to rock evaluation using these RECs was developed in hydrology, geochemistry, rock characteristics (rock occurrences, thermal response, rock mechanics), natural resources, and rock dissolution. Evaluation against postclosure and preclosure RECs yielded a ranking of the five subject rocks with respect to their potential as repository host rocks. Shale was determined to be the most preferred of the five rock types, with sandstone a distant second, the carbonate rocks and anhydrock a more distant third, and chalk a relatively close fourth.« less

Removal of bulk dissolved organic carbon (DOC) and trace organic compounds by bank filtration and artificial recharge.

PubMed

Grünheid, Steffen; Amy, Gary; Jekel, Martin

2005-09-01

Bank filtration and artificial recharge provide an important drinking water source to the city of Berlin. Due to the practice of water recycling through a semi-closed urban water cycle, the introduction of effluent organic matter (EfOM) and persistent trace organic pollutants in the drinking water is of potential concern. In the work reported herein, the research objectives are to study the removal of bulk and trace organics at bank filtration and artificial recharge sites and to assess important factors of influence for the Berlin area. The monthly analytical program is comprised of dissolved organic carbon (DOC), UV absorbance (UVA254), liquid chromatography with organic carbon detection (LC-OCD), differentiated adsorbable organic halogens (AOX) and single organic compound analysis of a few model compounds. More than 1 year of monitoring was conducted on observation wells located along the flowpaths of the infiltrating water at two field sites that have different characteristics regarding redox conditions, travel time, and travel distance. Two transects are highlighted: one associated with a bank filtration site dominated by anoxic/anaerobic conditions with a travel time of up to 4-5 months, and another with an artificial recharge site dominated by aerobic conditions with a travel time of up to 50 days. It was found that redox conditions and travel time significantly influence the DOC degradation kinetics and the efficiency of AOX and trace compound removal.

Simulating the carbon, water, energy budgets and greenhouse gas emissions of arctic soils with the ISBA land surface model

NASA Astrophysics Data System (ADS)

Morel, Xavier; Decharme, Bertrand; Delire, Christine

2017-04-01

Permafrost soils and boreal wetlands represent an important challenge for future climate simulations. Our aim is to be able to correctly represent the most important thermal, hydrologic and carbon cycle related processes in boreal areas with our land surface model ISBA (Masson et al, 2013). This is particularly important since ISBA is part of the CNRM-CM Climate Model (Voldoire et al, 2012), that is used for projections of future climate changes. To achieve this goal, we replaced the one layer original soil carbon module based on the CENTURY model (Parton et al, 1987) by a multi-layer soil carbon module that represents C pools and fluxes (CO2 and CH4), organic matter decomposition, gas diffusion (Khvorostyanov et al., 2008), CH4 ebullition and plant-mediated transport, and cryoturbation (Koven et al., 2009). The carbon budget of the new model is closed. The soil carbon module is tightly coupled to the ISBA energy and water budget module that solves the one-dimensional Fourier law and the mixed-form of the Richards equation explicitly to calculate the time evolution of the soil energy and water budgets (Boone et al., 2000; Decharme et al. 2011). The carbon, energy and water modules are solved using the same vertical discretization. Snowpack processes are represented by a multi-layer snow model (Decharme et al, 2016). We test this new model on a pair of monitoring sites in Greenland, one in a permafrost area (Zackenberg Ecological Research Operations, Jensen et al, 2014) and the other in a region without permafrost (Nuuk Ecological Research Operations, Jensen et al, 2013); both sites are established within the GeoBasis part of the Greenland Ecosystem Monitoring (GEM) program. The site of Chokurdakh, in a permafrost area of Siberia is is our third studied site. We test the model's ability to represent the physical variables (soil temperature and water profiles, snow height), the energy and water fluxes as well as the carbon dioxyde and methane fluxes. We also test the model behaviour in the case of a flooded fen, hence giving a first insight of the sensitivity of greenhouse gas emissions with respect to surface hydrology. Comparing the model results on these three climatically distinct sites also gives a first insight on the model sensitivity to the forcing climate variables, and show that the model is generic enough to reasonably model methane and carbon dioxyde emission behaviour from different types of boreal ecosystems.

Geochemical constraints on the temperature and timing of carbonate formation and lithification in the Nankai Trough, NanTroSEIZE transect

NASA Astrophysics Data System (ADS)

Sample, James C.; Torres, Marta E.; Fisher, Andrew; Hong, Wei-Li; Destrigneville, Christine; Defliese, William F.; Tripati, Aradhna E.

2017-02-01

Information about diagenetic processes and temperatures during burial of sediments entering the subduction zone is important for understanding changes in physical properties and seismic behavior during deformation. The geochemistry of authigenic carbonates from accretionary prisms can serve as proxies for conditions during carbonate cementation and resultant lithification. We report results from the Nankai accretionary prism recovered from Integrated Ocean Drilling Program (IODP) sites C0011 and C0012 and we document continued cementation of deep sediment sections prior to subduction. Elemental and isotope data provide evidence for complex mixing of different isotopic reservoirs in pore waters contributing to carbonate chemical signatures. Carbon stable isotope values exhibit a broad range (δ13CV-PDB = +0.1‰ to -22.5‰) that corresponds to different stages of cement formation during burial. Carbonate formation temperatures from carbonate-clumped isotope geochemistry range from 16 °C to 63 °C at Site C0011 and 8.7 °C to 68 °C at Site C0012. The correspondence between the clumped-isotope temperatures and extrapolations of measured in situ temperatures indicate the carbonate is continuing to form at present. Calculated water isotopic compositions are in some cases enriched in 18O relative to measured interstitial waters suggesting a component of inherited seawater or input from clay-bound water. Low oxygen isotope values and the observed Ba/Ca ratios are also consistent with carbonate cementation at depth. Strontium isotopes of interstitial waters (87Sr/86Sr of 0.7059-0.7069) and carbonates (87Sr/86Sr of 0.70715-0.70891) support formation of carbonates from a mixture of strontium reservoirs including current interstitial waters and relic seawater contemporaneous with deposition. Collectively our data reflect mixed sources of dissolved inorganic carbon and cations that include authigenic phases driven by organic carbon and volcanic alteration reactions. Physical properties of input sediments continue to undergo modification by carbonate cementation at present. Due to ongoing recrystallization, temperatures from carbonate-clumped isotopes reflect the modern geothermal gradient and may serve as useful measures of geothermal gradients in other siliciclastic basins where carbonate cementation occurs. We conclude that clumped-isotope signatures in authigenic carbonates from accretionary prisms are important proxies for the timing and conditions of cementation in active margins. Our results highlight the importance of using multi-proxy approaches to elucidate the history of carbonate cementation, particularly to establish carbonate precipitation at depth and its potential impact on the physical and mechanical properties of the sediment prior to subduction.

Combining multiple ecosystem productivity measurements to constrain carbon uptake estimates in semiarid grasslands and shrublands

NASA Astrophysics Data System (ADS)

Maurer, G. E.; Krofcheck, D. J.; Collins, S. L.; Litvak, M. E.

2016-12-01

Recent observational and modeling studies have indicated that semiarid ecosystems are more dynamic contributors to the global carbon budget than once thought. Semiarid carbon fluxes, however, are generally small, with high interannual and spatial variability, which suggests that validating their global significance may depend on examining multiple productivity measures and their associated uncertainties and inconsistencies. We examined ecosystem productivity from eddy covariance (NEE), harvest (NPP), and terrestrial biome models (NEPm) at two very similar grassland sites and one creosote shrubland site in the Sevilleta National Wildlife Refuge of central New Mexico, USA. Our goal was to assess site and methodological correspondence in annual carbon uptake, patterns of interannual variability, and measurement uncertainty. One grassland site was a perennial carbon source losing 30 g C m-2 per year on average, while the other two sites were carbon sources or sinks depending on the year, with average net uptake of 5 and 25 g C m-2 per year at the grassland and shrubland site, respectively. Uncertainty values for cumulative annual NEE overlapped between the three sites in most years. When combined, aboveground and belowground annual NPP measurements were 15% higher than annual NEE values and did not confirm a loss of carbon at any site in any year. Despite differences in mean site carbon balance, year-to-year changes in cumulative annual NEE and NPP were similar at all sites with years 2010 and 2013 being favorable for carbon uptake and 2011 and 2012 being unfavorable at all sites. Modeled NEPm data for a number of nearby grid cells reproduced only a fraction of the observed range in carbon uptake and its interannual variability. These three sites are highly similar in location and climate and multiple carbon flux measurements confirm the high interannual variability in carbon flux. The exact magnitude of these fluxes, however, remains difficult to discern.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, L. M.

The Commodity Credit Corporation (CCC), an agency of the U.S. Department of Agriculture (USDA), formerly operated a grain storage facility approximately 1,100 ft north of Centralia (Figure 1.2). The CCC/USDA operated this facility from 1949 until 1971. None of the CCC/USDA structures remain. Two additional grain storage facilities currently exist in and near Centralia: the Nemaha County Co-op, approximately 4,000 ft south of the former CCC/USDA facility, and a private grain storage facility near the Don Morris residence, 3,500 ft north of the former CCC/USDA facility. Prior to 1986, commercial grain fumigants containing carbon tetrachloride were commonly used by themore » CCC/USDA and the grain storage industry to preserve grain. In April 1998, the Kansas Department of Health and Environment (KDHE) sampled the domestic well at the Don Morris residence near Centralia (Figure 1.2) as part of the CCC/USDA Private Well Sampling Program, which was initiated to determine whether carbon tetrachloride was present in domestic wells located near former CCC/USDA grain storage facilities in Kansas. Carbon tetrachloride was detected in the Morris well at 19.3 mg/L and confirmed at 25.4 mg/L, both concentrations above the maximum contaminant level (MCL) of 5 mg/L for carbon tetrachloride in drinking water. On the basis of the detection of carbon tetrachloride in the Morris well, the KDHE in August-September 1998 conducted preliminary investigations at the former CCC/USDA facility. For the details of previous investigations in the area and a summary of their findings, see the QuickSite{reg_sign} Phase I Work Plan for Centralia (Argonne 2002a). Because the KDHE found carbon tetrachloride at the former CCC/USDA facility at Centralia that might, in part, be linked to historical use of carbon tetrachloride-based grain fumigants at the facility, the CCC/USDA is conducting an environmental site investigation at Centralia. However, the KDHE established in 1998 that the probable groundwater flow direction at the former CCC/USDA facility is not toward the Morris well, and thus the former facility is not responsible for the carbon tetrachloride measured in that well. The town of Centralia and all residents near the former CCC/USDA facility currently obtain their water from Rural Water District No.3 (RWD 3). Therefore, these local residents are not drinking and using contaminated groundwater. The investigation at Centralia is being performed by the Environmental Research Division of Argonne National Laboratory. Argonne is a nonprofit, multidisciplinary research center operated by the University of Chicago for the U.S. Department of Energy (DOE). The CCC/USDA has entered into an interagency agreement with DOE, under which Argonne provides technical assistance to the CCC/USDA with environmental site characterization and remediation at its former grain storage facilities. At these facilities, Argonne is applying its QuickSite environmental site characterization methodology. QuickSite is Argonne's proprietary implementation system for the expedited site characterization (ESC) process. Argonne's Environmental Research Division developed the ESC process to optimize preremedial site characterization work at hazardous waste sites by obtaining and then applying a thorough understanding of a site's geology, hydrogeology, and hydrogeochemistry (e.g., Burton 1994). This approach is fundamental to successful site characterization because the geology and hydrogeology of a site largely govern the mobility and fate of contaminants there. Argonne's ESC process has been used successfully at a number of former CCC/USDA facilities in Kansas and Nebraska and has been adopted by the American Society for Testing and Materials (ASTM 1998) as standard practice for environmental site characterization. This report documents the findings of the Phase I activities at Centralia. Section 1 provides a brief history of the area and the QuickSite process, a summary of the geologic/hydrogeologic model, objectives of the Phase I investigation, and a brief description of the sections contained in this report. Section 2 describes the investigative methods used during the Phase I investigation. Section 3 presents all of the data obtained during the investigation. Section 4 describes the interpretation of the pertinent data used to meet the technical objectives of the investigation, including the contaminant migration pathways in soil and groundwater. A summary of the findings is also provided in Section 4. Section 5 presents the conclusions of the investigation relative to the technical objectives and outlines recommendations for Phase II. To streamline the reporting process, materials from the Work Plan (Argonne 2002a) and relevant sections of the Master Work Plan (Argonne 2002b) are not repeated in detail in this report. Consequently, these documents must also be consulted to obtain the complete details of the Phase I investigative program.« less

A connection to deep groundwater alters ecosystem carbon fluxes and budgets: Example from a Costa Rican rainforest

DOE Office of Scientific and Technical Information (OSTI.GOV)

Genereux, David P.; Nagy, Laura A.; Osburn, Christopher L.

Field studies of watershed carbon fluxes and budgets are critical for understanding the carbon cycle, but the role of deep regional groundwater is poorly known and field examples are lacking. Here we show that discharge of regional groundwater into a lowland Costa Rican rainforest has a major influence on ecosystem carbon fluxes. Furthermore, this influence is observable through chemical, isotopic, and flux signals in groundwater, surface water, and air. Not addressing the influence of regional groundwater in the field measurement program and data analysis would give a misleading impression of the overall carbon source or sink status of the rainforest.more » In quantifying a carbon budget with the traditional "small watershed" mass-balance approach, it would be critical at this site and likely many others to consider watershed inputs or losses associated with exchange between the ecosystem and the deeper hydrogeological system on which it sits.« less

A connection to deep groundwater alters ecosystem carbon fluxes and budgets: Example from a Costa Rican rainforest

DOE PAGES

Genereux, David P.; Nagy, Laura A.; Osburn, Christopher L.; ...

2013-05-28

Field studies of watershed carbon fluxes and budgets are critical for understanding the carbon cycle, but the role of deep regional groundwater is poorly known and field examples are lacking. Here we show that discharge of regional groundwater into a lowland Costa Rican rainforest has a major influence on ecosystem carbon fluxes. Furthermore, this influence is observable through chemical, isotopic, and flux signals in groundwater, surface water, and air. Not addressing the influence of regional groundwater in the field measurement program and data analysis would give a misleading impression of the overall carbon source or sink status of the rainforest.more » In quantifying a carbon budget with the traditional "small watershed" mass-balance approach, it would be critical at this site and likely many others to consider watershed inputs or losses associated with exchange between the ecosystem and the deeper hydrogeological system on which it sits.« less

Mechanisms of deep benzene oxidation on the Pt(1 1 1) surface using temperature-programmed reaction methods

NASA Astrophysics Data System (ADS)

Marsh, Anderson L.; Gland, John L.

2003-06-01

The catalytic oxidation of benzene on the Pt(1 1 1) surface has been characterized using temperature-programmed reaction spectroscopy (TPRS) over a wide range of benzene and oxygen coverages. Coadsorbed atomic oxygen and benzene are the primary reactants on the surface during the initial oxidation step. Benzene is oxidized over the 300-500 K range to produce carbon dioxide and water. Carbon-hydrogen and carbon-carbon bond activation are clearly rate-limiting steps for these reactions. Preferential oxidation causes depletion of bridge-bonded benzene, suggesting enhanced reactivity in this bonding configuration. When oxygen is in excess on the surface, all of the surface carbon and hydrogen is oxidized. When benzene is in excess on the surface, hydrogen produced by dehydrogenation is desorbed after all of the surface oxygen has been consumed. Repulsive interactions between benzene and molecular oxygen dominate at low temperatures. Preadsorption of oxygen inhibits adsorption of less reactive benzene in threefold hollow sites. The desorption temperature of this non-reactive chemisorbed benzene decreases and overlaps with the multilayer desorption peak with increasing oxygen exposure. The results presented here provide a clear picture of rate-limiting steps during deep oxidation of benzene on the Pt(1 1 1) surface.

Gas and aerosol carbon in California: comparison of ...

EPA Pesticide Factsheets

Co-located measurements of fine particulate matter (PM2.5) organic carbon (OC), elemental carbon, radiocarbon (14C), speciated volatile organic compounds (VOCs),and OH radicals during the CalNex field campaign provide a unique opportunity to evaluate the Community Multiscale Air Quality (CMAQ) model's representation of organic species from VOCs to particles. Episode average daily 23 h average 14C analysis indicates PM2.5 carbon at Pasadena and Bakersfield during the CalNex field campaign was evenly split between contemporary and fossil origins. CMAQ predicts a higher contemporary carbon fraction than indicated by the 14C analysis at both locations. The model underestimates measured PM2.5 organic carbon at both sites with very little (7% in Pasadena) of the modeled mass represented by secondary production, which contrasts with the ambient-based SOC/OC fraction of 63% at Pasadena. The National Exposure Research Laboratory’s (NERL’s) Human Exposure and Atmospheric Sciences Division (HEASD) conducts research in support of EPA’s mission to protect human health and the environment. HEASD’s research program supports Goal 1 (Clean Air) and Goal 4 (Healthy People) of EPA’s strategic plan. More specifically, our division conducts research to characterize the movement of pollutants from the source to contact with humans. Our multidisciplinary research program produces Methods, Measurements, and Models to identify relationships between and characterize processe

Soil carbon under perennial pastures; benchmarking the influence of pasture age and management

NASA Astrophysics Data System (ADS)

Orgill, Susan E.; Spoljaric, Nancy; Kelly, Georgina

2015-07-01

This paper reports baseline soil carbon stocks from a field survey of 19 sites; 8 pairs/triplet in the Monaro region of New South Wales. Site comparisons were selected by the Monaro Farming Systems group to demonstrate the influence of land management on soil carbon, and included: nutrient management, liming, pasture age and cropping history. Soil carbon stocks varied with parent material and with land management. The fertilised (phosphorus) native perennial pasture had a greater stock of soil carbon compared with the unfertilised site; 46.8 vs 40.4 Mg.C.ha to 0.50 m. However, the introduced perennial pasture which had been limed had a lower stock of soil carbon compared with the unlimed site; 62.8 vs 66.7 Mg.C.ha to 0.50 m. There was a greater stock of soil carbon under two of the three younger (<10 yr old) perennial pastures compared with older (>35 yr old) pastures. Cropped sites did not have lower soil carbon stocks at all sites; however, this survey was conducted after three years of above average annual rainfall and most sites had been cropped for less than three years. At all sites more than 20% of the total carbon stock to 0.50 m was in the 0.30 to 0.50 m soil layer highlighting the importance of considering this soil layer when investigating the implications of land management on soil carbon. Our baseline data indicates that nutrient management may increase soil carbon under perennial pastures and highlights the importance of perennial pastures for soil carbon sequestration regardless of age.

Long-Term, Autonomous Measurement of Atmospheric Carbon Dioxide Using an Ormosil Nanocomposite-Based Optical Sensor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kisholoy Goswami

2005-10-11

The goal of this project is to construct a prototype carbon dioxide sensor that can be commercialized to offer a low-cost, autonomous instrument for long-term, unattended measurements. Currently, a cost-effective CO2 sensor system is not available that can perform cross-platform measurements (ground-based or airborne platforms such as balloon and unmanned aerial vehicle (UAV)) for understanding the carbon sequestration phenomenon. The CO2 sensor would support the research objectives of DOE-sponsored programs such as AmeriFlux and the North American Carbon Program (NACP). Global energy consumption is projected to rise 60% over the next 20 years and use of oil is projected tomore » increase by approximately 40%. The combustion of coal, oil, and natural gas has increased carbon emissions globally from 1.6 billion tons in 1950 to 6.3 billion tons in 2000. This figure is expected to reach 10 billon tons by 2020. It is important to understand the fate of this excess CO2 in the global carbon cycle. The overall goal of the project is to develop an accurate and reliable optical sensor for monitoring carbon dioxide autonomously at least for one year at a point remote from the actual CO2 release site. In Phase I of this project, InnoSense LLC (ISL) demonstrated the feasibility of an ormosil-monolith based Autonomous Sensor for Atmospheric CO2 (ASAC) device. All of the Phase I objectives were successfully met.« less

Planktic foraminiferal response to early Eocene carbon cycle perturbations in the southeast Atlantic Ocean (ODP Site 1263)

NASA Astrophysics Data System (ADS)

Luciani, Valeria; D'Onofrio, Roberta; Dickens, Gerald R.; Wade, Bridget S.

2017-11-01

At low latitude locations in the northern hemisphere, striking changes in the relative abundances and diversity of the two dominant planktic foraminifera genera, Morozovella and Acarinina, are known to have occurred close to the Early Eocene Climatic Optimum (EECO; 49-53 Ma). Lower Eocene carbonate-rich sediments at Ocean Drilling Program (ODP) Site 1263 were deposited on a bathymetric high (Walvis Ridge) at 40° S, and afford an opportunity to examine such planktic foraminiferal assemblage changes in a temperate southern hemisphere setting. We present here quantified counts of early Eocene planktic foraminiferal assemblages from Hole 1263B, along with bulk sediment stable isotope analyses and proxy measurements for carbonate dissolution. The bulk sediment δ13C record at Site 1263 resembles similar records generated elsewhere, such that known and inferred hyperthermal events can be readily identified. Although some carbonate dissolution has occurred, the well-preserved planktic foraminiferal assemblages mostly represent primary changes in environmental conditions. Our results document the permanent decrease in Morozovella abundance and increase in Acarinina abundance at the beginning of the EECO, although this switch occurred 165 kyr after that at low-latitude northern hemisphere locations. This suggests that unfavourable environmental conditions for morozovellids at the start of the EECO, such as sustained passage of a temperature threshold or other changes in surface waters, occurred at lower latitudes first. The remarkable turnover from Morozovella to Acarinina was widely geographically widespread, although the causal mechanism remains elusive. In addition, at Site 1263, we document the virtual disappearance within the EECO of the biserial chiloguembelinids, commonly considered as inhabiting intermediate water depths, and a reduction in abundance of the thermocline-dwelling subbotinids. We interpret these changes as signals of subsurface water properties, perhaps warming, and the associated contraction of ecological niches.

Terrestrial biosphere models need better representation of vegetation phenology: results from the North American Carbon Program Site Synthesis

Treesearch

Andrew D. Richardson; Ryan S. Anderson; M. Altaf Arain; Alan G. Barr; Gil Bohrer; Guangsheng Chen; Jing M. Chen; Philippe Ciais; Kenneth J. David; Ankur R. Desai; Michael C. Dietze; Danilo Dragoni; Steven R. Garrity; Christopher M. Gough; Robert Grant; David Hollinger; Hank A. Margolis; Harry McCaughey; Mirco Migliavacca; Russel K. Monson; J. William Munger; Benjamin Poulter; Brett M. Raczka; Daniel M. Ricciuto; Alok K. Sahoo; Kevin Schaefer; Hanqin Tian; Rodrigo Vargas; Hans Verbeeck; Jingfeng Xiao; Yongkang Xue

2012-01-01

Phenology, by controlling the seasonal activity of vegetation on the land surface, plays a fundamental role in regulating photosynthesis and other ecosystem processes, as well as competitive interactions and feedbacks to the climate system. We conducted an analysis to evaluate the representation of phenology, and the associated seasonality of ecosystem-scale CO

Phase 2 Site Investigations Report. Volume 1 of 3: General Annex-Wide Information

DTIC Science & Technology

1994-09-01

completeness PCB Polychlorinated Biphenyl PCE Tetrachloroethene or Perchloroethene PHC Petroleum hydrocarbons PID Photoionization Detector POLs Petroleum , Oil...TEPS Total Environmental Program Support TIC Tentatively Identified Compound TOC Total Organic Carbon TPHC Total Petroleum Hydrocarbons TRC Technical... hydrocarbons were identified within some soil and sediment samples near the detection limit. These could result from urban runoff. No petroleum

Physico-chemical characterization of African urban aerosols (Abidjan in Cote d'Ivoire and Cotonou in Benin) and their toxic effects in human bronchial epithelial cells during the dry season 2016.

NASA Astrophysics Data System (ADS)

Adon, Jacques; Liousse, Cathy; Yoboue, Veronique; Baeza, Armelle; Akpo, Aristide; Bahino, Julien; Chiron, Christelle; Galy-Lacaux, Corinne; Keita, Sékou

2017-04-01

This study is a contribution to the WP2-DACCIWA program with the aim to characterize particulate pollution on domestic fire site, traffic sites and waste burning site of two West-African capitals (Abidjan, Cote d'Ivoire and Cotonou, Benin) and to study aerosol biological impacts on lung inflammation. Such an impact is still largely unknown, especially for the particles emitted by intense African traffic sources and domestic fires. In this context, fundamental research of this study is centered on the following key scientific question: what is the link between aerosol size differentiated composition and inflammation markers for the main combustion sources prevailing in South West Africa during dry and wet seasons? To tackle this question, intensive campaigns in Abidjan and Cotonou have been conducted in July 2015, January and July 2016, and January 2017. In this paper, we will present our first results for the campaign of January 2016. In terms of aerosol size differentiated composition, main aerosol components (mass, black carbon, organic carbon, water soluble particles ...) were measured. We may notice that PM measured for all the sites is generally higher than WHO norms. Organic carbon and dust particles are the two more important contributors for the ultra-fine and fine particle sizes with more organic carbon in Abidjan and dust particles in Cotonou respectively. In terms of in vitro biological studies on sampled aerosols on these sites, size-fractionated PM from the different sampling sites were compared for their ability to induce a proinflammatory response characterized by the release of the cytokine IL-6 by human bronchial epithelial cells. PM from waste burning site did not induce significant IL-6 release whatever the size fraction whereas PM from domestic fire were the most reactive especially the ultra-fine fraction. Ultra-fine particles from traffic (Abidjan and Cotonou) always induced a dose-dependent IL-6 release. A tentative cross-analysis between physico-chemical and toxicological results will be proposed.

Multiproxy record of the last interglacial (MIS 5e) off central and northern California, U.S.A., from Ocean Drilling Program sites 1018 and 1020

USGS Publications Warehouse

Poore, Richard Z.; Dowsett, H.J.; Barron, J.A.; Heusser, L.; Ravelo, A.C.; Mix, A.

2000-01-01

Environmental and climatic conditions during the last interglacial (about 125,000 years ago) along the Central and Northern California coastal region are interpreted from study of marine cores recovered by the Ocean Drilling Program at sites 1018 and 1020. Marine microfossil and pollen assemblages, oxygen isotopes in benthic foraminifers, physical properties, and calcium carbonate contents of cored sediments are proxies indicating strong links between the marine and terrestrial environments during marine isotope stage 5 (MIS 5). At the beginning of the last interglacial (MIS 5e), reduction in global ice volume, increase in surface temperature, and warming of air temperature along the Central and Northern California coast were synchronous within the resolution of our sampling record.

Carbon Sequestration in Reforested Areas in China Since 1970

NASA Astrophysics Data System (ADS)

Chen, J.; Liu, J.; Wang, S.; Sun, R.; Shi, X.; Tian, Q.; Xue, J.; Pan, J.; Kang, E.; Zhu, Q.; Zhou, Y.; Yang, L.; Liu, G.; Chen, M.; Thomas, S.; Bryan, R.; Yin, Y.; MacLaren, V.; Zhou, S.; Feng, X.; Wang, C.; Pan, J.

2004-05-01

Since July 2002, a 3-year Canada-China joint project was funded by the Canadian International Development Agency and the Chinese Academy of Sciences to assess the current status of China's forests and the impacts of forestry activities on carbon sequestration. From 1973 to 2001, China's total forested area increased from 122 Mha to 159 Mha, owing to large-scale reforestations for the main purpose of soil erosion control. In this project, four local forest sites in Changbaishan, Heihe, Liping and Xingguo in various regions are chosen for intensive assessments of forest and soil stocks. Ground-based measurements of leaf area index (LAI), net primary productivity (NPP), soil texture, vegetation and soil carbon stocks are used to calibrate models. High-resolution remote sensing images from ASTER and ETM are used to map LAI and NPP of these sites and for upscaling to the whole China based on MODIS and VEGETATION images. Remote sensing techniques and carbon cycle models (BEPS, InTEC) developed in Canada are being adapted to China's ecosystems. Preliminary results suggest that new reforested areas since 1970 are now actively sequester carbon, making the overall forested area as a carbon sink in the last few decades. Efforts are being made to reduce uncertainties in the estimation through incorporating new nation-wide datasets of forest age, soil texture and organic matter, nitrogen deposition, etc. At Changbaishan, Liping and Heihe, integrated assessments are being conducted to investigate the impacts of reforestation (Grain-to-Green) programs on the social and economic status of farmers as well as the ecological environment and land use options to maximize carbon sequestraton.

Evidence for Biomass Burning from 14C and 13C/12C Measurements at T-0 and T-1 during MILAGRO.

NASA Astrophysics Data System (ADS)

Gaffney, J. S.; Marley, N. A.; Tackett, M. J.; Sturchio, N. C.; Heraty, L. J.; Martinez, N.; Hardy, K.; Guilderson, T.

2007-12-01

Both stable carbon isotopic and radiocarbon characterizations of aerosols can yield important information regarding the sources of carbonaceous aerosols in urban and regional environments. Biomass derived materials are labeled due to their recent photochemical activity in radiocarbon and vary depending upon the photochemical pathway (either C-4 or C-3) in stable carbon-13 content. C-4 being enriched over C-3. During the MILAGRO campaign, quartz filter samples were taken at 12 hour intervals from 5 am to 5 pm (day) and from 5 pm to 5 am (night) during the month of March 2006. These samples were taken at the two super-sites, T-0 (Instituto Mexicano de Petroleo in Mexico City) and T-1 (Universidad Technologica de Tecamac, State of Mexico). The total carbon content was analyzed for stable carbon isotopic composition as well as for radiocarbon. Stable isotope mass spectroscopy was used to determine the carbon-13 to carbon-12 isotopic ratios on carbon dioxide. The carbon dioxide was then converted to graphite for analysis by accelerator mass spectrometry at the Center for Accelerator Mass Spectrometry at Lawrence Livermore National Laboratory. Results are presented for the carbon-13 content relative to the PDB standard and radiocarbon is given relative to recent carbon. The results for total radiocarbon content show that the carbonaceous aerosol content in Mexico City has more than half of the carbon coming from biomass derived sources. These can include inflow of biomass burning aerosols into the T-0 site as well as the input from local burning of biofuels and trash containing biomass derived materials (paper, boxes, etc.). Data also indicate that at the T-1 site biomass burning of C-4 grasses appears to be significant in that the carbon-13 values observed are enriched. Also at T-1 the radiocarbon levels are also found to be slightly higher indicating regional biomass burning as a significant contributor to aerosol carbon in the 0.1 to 1.0 micron size fraction. Some day and night differences were observed that indicate secondary organic aerosols are contributing and that a significant fraction of these aerosols are biomass derived. Further analyses of organic carbon and elemental carbon fractions are underway. This work was performed as part of the Department of Energy's Megacity Aerosol Experiment - Mexico City (MAX- Mex) under the support of the Atmospheric Science Program. This research was supported by the Office of Science (BER), U.S. Department of Energy, Grant No. DE-FG02-07ER64328.

Providing Tobacco Treatment in a Community Mental Health Setting: A Pilot Study.

PubMed

Okoli, Chizimuzo T C; Mason, Dia A; Brumley-Shelton, Angela; Robertson, Heather

Individuals with mental illnesses (MIs) are disproportionately affected by tobacco-related disease burden because of higher tobacco use prevalence and poor tobacco treatment outcomes. This pilot study examines the outcomes of delivering an evidence-based tobacco treatment program (the Cooper-Clayton program) in a community mental health setting. A prospective nonequivalent group design was used to assess outcomes. This study included 47 participants, of which 19 were in a community mental health setting and 28 were from two non-mental-health settings. Information on sociodemographic (gender, age, educational level, and current life stressors) and medical, MI, substance use, and tobacco use and cessation histories were obtained. Program completion and smoking cessation at the end of treatment (verified with expired carbon monoxide monitoring) were assessed. The program consists of combining behavioral counseling with nicotine replacement therapy for 12 weeks. Participants from the mental health setting were significantly less educated, had greater medical comorbidities, had greater psychiatric and mental health histories, and had greater perceived secondhand tobacco smoke exposure as compared with those from the non-mental-health settings. Thirty-two percent of the participants (6/19) completed the program in the mental health site as compared with 68% (19/28) from the non-mental-health site. None of those from the mental health site achieved cessation as compared with 68% of those from non-mental-health sites. The differential outcomes of evidence-based tobacco treatment programs in non-mental-health versus mental health settings may suggest the need to modify existing tobacco treatment approaches for those with MIs in community settings.

Resource Conservation and Recovery Act, Part B permit application [of the Waste Isolation Pilot Plant (WIPP)]. Volume 11, Chapter D, Appendix D4--Chapter D, Appendix D17: Revision 3

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1993-03-01

This volume contains appendices D4 through D17 which cover the following: Waste Isolation Pilot Plant site environmental report; ecological monitoring program at the Waste Isolation Pilot Plant; site characterization; regional and site geology and hydrology; general geology; dissolution features; ground water hydrology; typical carbon sorption bed efficiency; VOC monitoring plan for bin-room tests; chemical compatibility analysis of waste forms and container materials; probable maximum precipitation; WHIP supplementary roof support system room 1, panel 1; and corrosion risk assessment of the Waste Isolation Pilot Plant ``humid`` test bins.

Carbon dynamics within agricultural and native sites in the loess region of Western lowa

USGS Publications Warehouse

Manies, K.L.; Harden, J.W.; Kramer, L.; Parton, W.J.

2001-01-01

In order to quantify the historical changes in carbon storage that result from agricultural conversion, this study compared the carbon dynamics of two sites in the loess region of Iowa: a native prairie and a cropland. Field data were obtained to determine present-day carbon storage and its variability within a landscape (a stable ridgetop vs. eroding upper-midslope vs. depositional lower slope). Models were used to recreate the historical carbon budget of these sites and determine the cropland's potential to be a net CO2 source or sink, relative to the atmosphere. Regardless of slope position, the cropland site contains approximately half the amount of carbon as prairie. Variability in soil carbon storage within a site as a consequence of slope position is as large or larger (variations of 200-300%) than temporal variation (???200% at all slope positions). The most extreme difference in soil carbon storage between the cropland and prairie sites is found in the soil at the upper-midslope, which is the area of greatest erosion. The models estimate that 93-172% of the carbon in the original topsoil has been lost from the cropland's eroding midslope. Much of this carbon is derived from deeper soil horizons. Either a small sink or strong source of carbon to the atmosphere is created, depending on the fate of the eroded sediment and its associated carbon.

Comparison of Forest Soil Carbon Dynamics at Five Sites Along a Latitudinal Gradient

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garten Jr, Charles T

2011-01-01

Carbon stocks, and C:N ratios, were measured in the forest floor, mineral soil, and two mineral soil fractions (particulate and mineral-associated organic matter, POM and MOM, respectively) at five forest sites, ranging from 60 to 100 years old, along a latitudinal gradient in the eastern United States. Sampling at four sites was replicated over two consecutive years. For many measurements (like forest floor carbon stocks, cumulative soil organic carbon stocks to 20 cm, and the fraction of whole soil carbon in POM), there was no significant difference between years at each site despite the use of somewhat different sampling methods.more » With one exception, forest floor and mineral soil carbon stocks increased from warm, southern, sites (with fine-textured soils) to northern, cool, sites (with more coarse-textured soils). The exception was a northern site, with less than 10% silt-clay content, that had a soil organic carbon stock similar to those measured at southern sites. Soil carbon at each site was partitioned into two pools (labile and stable) on the basis of carbon measured in the forest floor and POM and MOM fractions from the mineral soil. A two-compartment steady-state model, with randomly varying parameter values, was used in probabilistic calculations to estimate the turnover time of labile soil organic carbon (MRTU) and the annual transfer of labile carbon to stable carbon (k2) at each site in two different years. Based on empirical data, the turnover time of stable soil carbon (MRTS) was determined by mean annual temperature and increased from 30 to 100 years from south to north. Moving from south to north, MRTU increased from approximately 5 to 14 years. Consistent with prior studies, 13C enrichment factors ( ) from the Rayleigh equation, that describe the rate of change in 13C through the soil profile, were an indicator of soil carbon turnover times along the latitudinal gradient. Consistent with its role in stabilization of soil organic carbon, silt-clay content along the gradient was positively correlated (r = 0.91; P 0.001) with parameter k2. Mean annual temperature was indicated as the environmental factor most strongly associated with south to north differences in the storage and turnover of labile soil carbon. However, soil texture appeared to override the influence of temperature when there was too little silt-clay content to stabilize labile soil carbon and thereby protect it from decomposition. Irrespective of latitudinal differences in measured soil carbon stocks, each study site had a relatively high proportion of labile soil carbon (approximately 50% of whole soil carbon to a depth of 20 cm). Depending on unknown temperature sensitivities, large labile pools of forest soil carbon are potentially at risk of depletion by decomposition in a warming climate, and losses could be disproportionately higher from coarse textured forest soils.« less

Tropical Atlantic climate and ecosystem regime shifts during the Paleocene-Eocene Thermal Maximum

NASA Astrophysics Data System (ADS)

Frieling, Joost; Reichart, Gert-Jan; Middelburg, Jack J.; Röhl, Ursula; Westerhold, Thomas; Bohaty, Steven M.; Sluijs, Appy

2018-01-01

The Paleocene-Eocene Thermal Maximum (PETM, 56 Ma) was a phase of rapid global warming associated with massive carbon input into the ocean-atmosphere system from a 13C-depleted reservoir. Many midlatitude and high-latitude sections have been studied and document changes in salinity, hydrology and sedimentation, deoxygenation, biotic overturning, and migrations, but detailed records from tropical regions are lacking. Here, we study the PETM at Ocean Drilling Program (ODP) Site 959 in the equatorial Atlantic using a range of organic and inorganic proxies and couple these with dinoflagellate cyst (dinocyst) assemblage analysis. The PETM at Site 959 was previously found to be marked by a ˜ 3.8 ‰ negative carbon isotope excursion (CIE) and a ˜ 4 °C surface ocean warming from the uppermost Paleocene to peak PETM, of which ˜ 1 °C occurs before the onset of the CIE. We record upper Paleocene dinocyst assemblages that are similar to PETM assemblages as found in extratropical regions, confirming poleward migrations of ecosystems during the PETM. The early stages of the PETM are marked by a typical acme of the tropical genus Apectodinium, which reaches abundances of up to 95 %. Subsequently, dinocyst abundances diminish greatly, as do carbonate and pyritized silicate microfossils. The combined paleoenvironmental information from Site 959 and a close-by shelf site in Nigeria implies the general absence of eukaryotic surface-dwelling microplankton during peak PETM warmth in the eastern equatorial Atlantic, most likely caused by heat stress. We hypothesize, based on a literature survey, that heat stress might have reduced calcification in more tropical regions, potentially contributing to reduced deep sea carbonate accumulation rates, and, by buffering acidification, also to biological carbonate compensation of the injected carbon during the PETM. Crucially, abundant organic benthic foraminiferal linings imply sustained export production, likely driven by prokaryotes. In sharp contrast, the recovery of the CIE yields rapid (≪ 10 kyr) fluctuations in the abundance of several dinocyst groups, suggesting extreme ecosystem and environmental variability.

Utility of the Measurement of Carboxyhemoglobin Level at the Site of Acute Carbon Monoxide Poisoning in Rural Areas.

PubMed

Onodera, Makoto; Fujino, Yasuhisa; Kikuchi, Satoshi; Sato, Masayuki; Mori, Kiyofumi; Beppu, Takaaki; Inoue, Yoshihiro

2016-01-01

Objective. This study examined the hypothesis that correlations exist between the carbon monoxide exposure time and the carboxyhemoglobin concentration at the site of carbon monoxide poisoning, using a pulse carbon monoxide oximeter in rural areas or the carboxyhemoglobin concentration measured at a given medical institution. Background. In previous studies, no definitive relationships between the arterial blood carboxyhemoglobin level and the severity of carbon monoxide poisoning have been observed. Method. The subjects included patients treated for acute carbon monoxide poisoning in whom a medical emergency team was able to measure the carboxyhemoglobin level at the site of poisoning. We examined the relationship between the carboxyhemoglobin level at the site of poisoning and carbon monoxide exposure time and the relationships between the arterial blood carboxyhemoglobin level and carbon monoxide exposure time. Results. A total of 10 patients met the above criteria. The carboxyhemoglobin levels at the site of poisoning were significantly and positively correlated with the exposure time (rs = 0.710, p = 0.021), but the arterial blood carboxyhemoglobin levels were not correlated with the exposure time. Conclusion. In rural areas, the carboxyhemoglobin level measured at the site of carbon monoxide poisoning correlated with the exposure time.

Continuous Remote Measurements of Atmospheric O2 Concentrations in Relation to Interannual Variations in Biological Production and Carbon Cycling in the Oceans

NASA Technical Reports Server (NTRS)

Keeling, Ralph F.; Campbell, J. A. (Technical Monitor)

2002-01-01

We successfully initiated a program to obtain continuous time series of atmospheric O2 concentrations at a semi-remote coastal site, in Trinidad, California. The installation, which was completed in September 1999, consists of a commercially-available O2 and CO2 analyzers interfaced to a custom gas handling system and housed in a dedicated building at the Trinidad site. Ultimately, the data from this site are expected to provide constraints, complementing satellite data, on variations in ocean productivity and carbon exchange on annual and interannual time scales, in the context of human-induced changes in global climate and other perturbations. The existing time-series, of limited duration, have been used in support of studies of the O2/CO2 exchange from a wild fire (which fortuitously occurred nearby in October 1999) and to quantify air-sea N2O and O2 exchanges related to coastal upwelling events. More generally, the project demonstrates the feasibility of obtaining semi-continuous O2 time series at moderate cost from strategic locations globally.

A Carbon Flux Super Site. New Insights and Innovative Atmosphere-Terrestrial Carbon Exchange Measurements and Modeling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Leclerc, Monique Y.

2014-11-17

This final report presents the main activities and results of the project “A Carbon Flux Super Site: New Insights and Innovative Atmosphere-Terrestrial Carbon Exchange Measurements and Modeling” from 10/1/2006 to 9/30/2014. It describes the new AmeriFlux tower site (Aiken) at Savanna River Site (SC) and instrumentation, long term eddy-covariance, sodar, microbarograph, soil and other measurements at the site, and intensive field campaigns of tracer experiment at the Carbon Flux Super Site, SC, in 2009 and at ARM-CF site, Lamont, OK, and experiments in Plains, GA. The main results on tracer experiment and modeling, on low-level jet characteristics and their impactmore » on fluxes, on gravity waves and their influence on eddy fluxes, and other results are briefly described in the report.« less

Evaluating climatic response to external radiative forcing during the late Miocene to early Pliocene: New perspectives from eastern equatorial Pacific (IODP U1338) and North Atlantic (ODP 982) locations

NASA Astrophysics Data System (ADS)

Drury, Anna Joy; John, Cédric M.; Shevenell, Amelia E.

2016-01-01

Orbital-scale climate variability during the latest Miocene-early Pliocene is poorly understood due to a lack of high-resolution records spanning 8.0-3.5 Ma, which resolve all orbital cycles. Assessing this variability improves understanding of how Earth's system sensitivity to insolation evolves and provides insight into the factors driving the Messinian Salinity Crisis (MSC) and the Late Miocene Carbon Isotope Shift (LMCIS). New high-resolution benthic foraminiferal Cibicidoides mundulus δ18O and δ13C records from equatorial Pacific International Ocean Drilling Program Site U1338 are correlated to North Atlantic Ocean Drilling Program Site 982 to obtain a global perspective. Four long-term benthic δ18O variations are identified: the Tortonian-Messinian, Miocene-Pliocene, and Early-Pliocene Oxygen Isotope Lows (8-7, 5.9-4.9, and 4.8-3.5 Ma) and the Messinian Oxygen Isotope High (MOH; 7-5.9 Ma). Obliquity-paced variability dominates throughout, except during the MOH. Eleven new orbital-scale isotopic stages are identified between 7.4 and 7.1 Ma. Cryosphere and carbon cycle sensitivities, estimated from δ18O and δ13C variability, suggest a weak cryosphere-carbon cycle coupling. The MSC termination coincided with moderate cryosphere sensitivity and reduced global ice sheets. The LMCIS coincided with reduced carbon cycle sensitivity, suggesting a driving force independent of insolation changes. The response of the cryosphere and carbon cycle to obliquity forcing is established, defined as Earth System Response (ESR). Observations reveal that two late Miocene-early Pliocene climate states existed. The first is a prevailing dynamic state with moderate ESR and obliquity-driven Antarctic ice variations, associated with reduced global ice volumes. The second is a stable state, which occurred during the MOH, with reduced ESR and lower obliquity-driven variability, associated with expanded global ice volumes.

Transport properties for carbon chain sandwiched between heteroatom-doped carbon nanotubes with different doping sites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Wenjiang; Guizhou University of Finance and Economics, Guiyang 550025; Deng, Xiaoqing, E-mail: xq-deng@163.com, E-mail: caish@mail.gufe.edu.cn

The First-principles calculation is used to investigate the transport properties of a carbon chain connected with N-and/or B-doped caped carbon nanotube acting as electrodes. The I-V curves of the carbon chain are affected by the N/B doping sites, and rectifying behavior can be obtained distinctly when the carbon chain is just connected onto two doping atom sites (N- chain-B), and a weak rectification occurs when N (B) doping at other sites. Interestingly, the spin-filtering effects exist in the junction when it is doped at other sites, undoped system, or N-terminal carbon chains. However, no this behavior is found in N-chain-Bmore » and B-chain-B systems. The analysis on the transmission spectra, PDOS, LDOS, spin density, and the electron transmission pathways give an insight into the observed results for the system.« less

Variable effects of plant colonization on black slate uptake into microbial PLFAs

NASA Astrophysics Data System (ADS)

Seifert, Anne-Gret; Trumbore, Susan; Xu, Xiaomei; Zhang, Dachung; Gleixner, Gerd

2013-04-01

Microbial degradation of carbon derived from black shale and slate has been shown in vitro. However, in natural settings where other labile carbon sources are likely to exist, this has not been previously demonstrated. We investigated the uptake of ancient carbon derived from slate weathering and from recently photosynthesised organic matter by different groups of microorganisms. Therefore we isolated microbial biomarkers (phospholipid fatty acids, PLFAs) from black slates collected at a chronosequence of waste piles which differed in age and vegetation cover. We quantified the amount of PLFAs and performed stable isotope and radiocarbon measurements on individual or grouped PLFAs to quantify the fraction of slate derived carbon. We used black slate from a pile heaped in the 1950s with either uncovered black slate material (bare site) or material slightly colonized by small plants (greened site) and from a forested leaching pile (forested site) used for alum-mining in the 19th century. Colonization by plants influenced the amount and composition of the microbial community. Greater amounts of PLFAs (5410 ng PLFA/g dw) were extracted from slate sampled at the forested site as opposed to the bare site (960 ng PLFAs/g dw) or the greened (annual grasses and mosses) rock waste pile (1050 ng PLFAs/g dw). We found the highest proportion of PLFAs representing Gram-negative bacteria on the forested site and the highest proportion of PLFAs representing Gram-positive bacteria on the bare site. The fungal PLFA was most abundant at the greened site. Sites with less plant colonization (bare and greened site) tended to have more depleted δ13C values compared to the forested site. Radiocarbon measurements on PLFAs indicated that fungi and Gram-positive bacteria were best adapted to black slate carbon uptake. In the fungal PLFA (combined bare and greened waste pile sample) and in PLFAs of Gram-positive bacteria (greened site) we measured 39.7% and 28.9% ancient carbon uptake, respectively. Our results prove that black slate degradation followed by carbon uptake takes place in situ. Results imply that plant colonization might additionally affect this process. Slight colonization with few plants increased slate derived carbon uptake in PLFAs of Gram-positive bacteria. Evidently, Gram-positive bacteria represented by specific PLFAs from the greened site held more ancient carbon than from the bare site. In contrast, no black slate derived carbon was used by microorganisms at the forested site with 2-3 times greater carbon content. Results suggest that the use of ancient slate derived carbon dominates mainly in early stages of microbial colonization of surfaces and that with increasing ecosystem development recycling of plant derived carbon dominates.

Ground-water quality in the carbonate-rock aquifer of the Great Basin, Nevada and Utah, 2003

USGS Publications Warehouse

Schaefer, Donald H.; Thiros, Susan A.; Rosen, Michael R.

2005-01-01

The carbonate-rock aquifer of the Great Basin is named for the thick sequence of Paleozoic limestone and dolomite with lesser amounts of shale, sandstone, and quartzite. It lies primarily in the eastern half of the Great Basin and includes areas of eastern Nevada and western Utah as well as the Death Valley area of California and small parts of Arizona and Idaho. The carbonate-rock aquifer is contained within the Basin and Range Principal Aquifer, one of 16 principal aquifers selected for study by the U.S. Geological Survey’s National Water- Quality Assessment Program.Water samples from 30 ground-water sites (20 in Nevada and 10 in Utah) were collected in the summer of 2003 and analyzed for major anions and cations, nutrients, trace elements, dissolved organic carbon, volatile organic compounds (VOCs), pesticides, radon, and microbiology. Water samples from selected sites also were analyzed for the isotopes oxygen-18, deuterium, and tritium to determine recharge sources and the occurrence of water recharged since the early 1950s.Primary drinking-water standards were exceeded for several inorganic constituents in 30 water samples from the carbonate-rock aquifer. The maximum contaminant level was exceeded for concentrations of dissolved antimony (6 μg/L) in one sample, arsenic (10 μg/L) in eleven samples, and thallium (2 μg/L) in one sample. Secondary drinking-water regulations were exceeded for several inorganic constituents in water samples: chloride (250 mg/L) in five samples, fluoride (2 mg/L) in two samples, iron (0.3 mg/L) in four samples, manganese (0.05 mg/L) in one sample, sulfate (250 mg/L) in three samples, and total dissolved solids (500 mg/L) in seven samples.Six different pesticides or metabolites were detected at very low concentrations in the 30 water samples. The lack of VOC detections in water sampled from most of the sites is evidence thatVOCs are not common in the carbonate-rock aquifer. Arsenic values for water range from 0.7 to 45.7 μg/L, with a median value of 9.6 μg/L. Factors affecting arsenic concentration in the carbonate-rock aquifer in addition to geothermal heating are its natural occurrence in the aquifer material and time of travel along the flow path.Most of the chemical analyses, especially for VOCs and nutrients, indicate little, if any, effect of overlying land-use patterns on ground-water quality. The water quality in recharge areas for the aquifer where human activities are more intense may be affected by urban and/or agricultural land uses as evidenced by pesticide detections. The proximity of the carbonate-rock aquifer at these sites to the land surface and the potential for local recharge to occur through the fractured rock likely results in the occurrence of these and other land-surface related contaminants in the ground water. Water from sites sampled near outcrops of carbonate-rock aquifer likely has a much shorter residence time resulting in a potential for detection of anthropogenic or land-surface related compounds. Sites located in discharge areas of the flow systems or wells that are completed at a great depth below the land surface generally show no effects of land-use activities on water quality. Flow times within the carbonate-rock aquifer, away from recharge areas, are on the order of thousands of years, so any contaminants introduced at the land surface that will not degrade along the flow path have not reached the sampled sites in these areas.

The impact of single-tree selection and clearcut harvest on selected biochemical soil health indicators at the Missouri Forest Ecosystem Program and Long Term Soil Productivity sites in the Missouri Ozarks

USDA-ARS?s Scientific Manuscript database

The objective of this study was to evaluate carbon, nitrogen, sulfur and phosphorus (CNSP) cycling and to determine potential biochemical soil health indicators applicable to timber harvesting in the Missouri Ozarks. Soil samples were collected from the Missouri Forest Ecosystem Project (MOFEP) and ...

Aquifer Susceptibility in Virginia: Data on Chemical and Isotopic Composition, Recharge Temperature, and Apparent Age of Water from Wells and Springs, 1998-2000

USGS Publications Warehouse

Nelms, David L.; Harlow, George E.

2003-01-01

The determination of aquifer susceptibility to contamination from near-surface sources by the use of ground-water dating techniques is a critical part of Virginia's Source Water Assessment Program. As part of the Virginia Aquifer Susceptibility study, water samples were collected between 1998 and 2000 from 145 wells and 6 springs in various hydrogeologic settings across the Commonwealth. Samples were analyzed to determine water chemistry?including nitrate (NO3), dissolved organic carbon (DOC), and radon-222 (222Rn), major dissolved and noble gases?nitrogen (N2), argon (Ar), oxygen (O2), carbon dioxide (CO2), methane (CH4), helium (He), and neon (Ne), environmental tracers?chlorofluorocarbons (CFCs), sulfur hexafluoride (SF6), tritium (3H), and tritium/helium-3 (3H/3He), carbon isotopes?carbon-14 (14C) and carbon-13 (d13C), and stable isotopes of oxygen (d18O) and hydrogen (d2H). The chemical and isotopic composition, recharge temperatures, and apparent ages of these water samples are presented in this report. Data collected between 1999 and 2000 from 18 wells in Virginia as part of two other studies by the U.S. Geological Survey also are presented. Most of the sites sampled serve as public water supplies and are included in the comprehensive Source Water Assessment Program for the Commonwealth.

Scaling Properties of Turbulent Mixing for Scalars Measured at Arctic Terrestrial Sites

NASA Astrophysics Data System (ADS)

Grachev, A. A.; Uttal, T.; Persson, O. P. G.; Crepinsek, S.; Fairall, C. W.; Albee, R.; Makshtas, A.; Kustov, V. Y.; Repina, I.; Artamonov, A. Y.

2014-12-01

Measurements of atmospheric turbulence made at two different sites located near the coast of the Arctic Ocean at Eureka (Canadian territory of Nunavut) and Tiksi (East Siberia) are used to study turbulent fluxes, scaling laws for turbulent mixing, dissipation rates, and structure parameters of various scalars (temperature, water vapour, and carbon dioxide). Turbulent fluxes along with other turbulent statistics and mean meteorological data were measured continuously throughout the year and reported hourly at various levels on 10-m (Eureka) and 20-m (Tiksi) flux towers. According to our data, strong upward sensible and latent heat fluxes are observed throughout the summer months indicating unstable stratification on average. During the Polar winter and cold seasons when the air temperature falls below freezing, the near-surface environment is generally stably stratified (downward sensible but upward latent heat fluxes). It is found that observed temporal variability of the carbon dioxide vertical flux for both sites was generally in phase with Monin-Obukhov stability parameter, z/L (L is the Obukhov length scale). On average the turbulent flux of carbon dioxide was mostly negative (uptake by the surface) for z/L < 0 and vice versa. Our study also analyses the similarity between the turbulent mixing of sensible heat, water vapour, and carbon dioxide with a specific focus on the difference between the similarity functions for the dissipation rates. The work is supported by the NOAA Climate Program Office, the U.S. National Science Foundation (NSF) with award ARC 11-07428, and by the U.S. Civilian Research & Development Foundation (CRDF) with award RUG1-2976-ST-10.

Recovery of ponderosa pine ecosystem carbon and water fluxes from thinning and stand-replacing fire.

PubMed

Dore, Sabina; Montes-Helu, Mario; Hart, Stephen C; Hungate, Bruce A; Koch, George W; Moon, John B; Finkral, Alex J; Kolb, Thomas E

2012-10-01

Carbon uptake by forests is a major sink in the global carbon cycle, helping buffer the rising concentration of CO 2 in the atmosphere, yet the potential for future carbon uptake by forests is uncertain. Climate warming and drought can reduce forest carbon uptake by reducing photosynthesis, increasing respiration, and by increasing the frequency and intensity of wildfires, leading to large releases of stored carbon. Five years of eddy covariance measurements in a ponderosa pine (Pinus ponderosa)-dominated ecosystem in northern Arizona showed that an intense wildfire that converted forest into sparse grassland shifted site carbon balance from sink to source for at least 15 years after burning. In contrast, recovery of carbon sink strength after thinning, a management practice used to reduce the likelihood of intense wildfires, was rapid. Comparisons between an undisturbed-control site and an experimentally thinned site showed that thinning reduced carbon sink strength only for the first two posttreatment years. In the third and fourth posttreatment years, annual carbon sink strength of the thinned site was higher than the undisturbed site because thinning reduced aridity and drought limitation to carbon uptake. As a result, annual maximum gross primary production occurred when temperature was 3 °C higher at the thinned site compared with the undisturbed site. The severe fire consistently reduced annual evapotranspiration (range of 12-30%), whereas effects of thinning were smaller and transient, and could not be detected in the fourth year after thinning. Our results show large and persistent effects of intense fire and minor and short-lived effects of thinning on southwestern ponderosa pine ecosystem carbon and water exchanges. © 2012 Blackwell Publishing Ltd.

Influence of stocking, site quality, stand age, low-severity canopy disturbance, and forest composition on sub-boreal aspen mixedwood carbon stocks

USGS Publications Warehouse

Reinikainen, Michael; D’Amato, Anthony W.; Bradford, John B.; Fraver, Shawn

2014-01-01

Low-severity canopy disturbance presumably influences forest carbon dynamics during the course of stand development, yet the topic has received relatively little attention. This is surprising because of the frequent occurrence of such events and the potential for both the severity and frequency of disturbances to increase as a result of climate change. We investigated the impacts of low-severity canopy disturbance and average insect defoliation on forest carbon stocks and rates of carbon sequestration in mature aspen mixedwood forests of varying stand age (ranging from 61 to 85 years), overstory composition, stocking level, and site quality. Stocking level and site quality positively affected the average annual aboveground tree carbon increment (CAAI), while stocking level, site quality, and stand age positively affected tree carbon stocks (CTREE) and total ecosystem carbon stocks (CTOTAL). Cumulative canopy disturbance (DIST) was reconstructed using dendroecological methods over a 29-year period. DIST was negatively and significantly related to soil carbon (CSOIL), and it was negatively, albeit marginally, related to CTOTAL. Minima in the annual aboveground carbon increment of trees (CAI) occurred at sites during defoliation of aspen (Populus tremuloides Michx.) by forest tent caterpillar (Malacosoma disstria Hubner), and minima were more extreme at sites dominated by trembling aspen than sites mixed with conifers. At sites defoliated by forest tent caterpillar in the early 2000s, increased sequestration by the softwood component (Abies balsamea (L.) Mill. and Picea glauca (Moench) Voss) compensated for overall decreases in CAI by 17% on average. These results underscore the importance of accounting for low-severity canopy disturbance events when developing regional forest carbon models and argue for the restoration and maintenance of historically important conifer species within aspen mixedwoods to enhance stand-level resilience to disturbance agents and maintain site-level carbon stocks.

The biodiversity cost of carbon sequestration in tropical savanna.

PubMed

Abreu, Rodolfo C R; Hoffmann, William A; Vasconcelos, Heraldo L; Pilon, Natashi A; Rossatto, Davi R; Durigan, Giselda

2017-08-01

Tropical savannas have been increasingly viewed as an opportunity for carbon sequestration through fire suppression and afforestation, but insufficient attention has been given to the consequences for biodiversity. To evaluate the biodiversity costs of increasing carbon sequestration, we quantified changes in ecosystem carbon stocks and the associated changes in communities of plants and ants resulting from fire suppression in savannas of the Brazilian Cerrado, a global biodiversity hotspot. Fire suppression resulted in increased carbon stocks of 1.2 Mg ha -1 year -1 since 1986 but was associated with acute species loss. In sites fully encroached by forest, plant species richness declined by 27%, and ant richness declined by 35%. Richness of savanna specialists, the species most at risk of local extinction due to forest encroachment, declined by 67% for plants and 86% for ants. This loss highlights the important role of fire in maintaining biodiversity in tropical savannas, a role that is not reflected in current policies of fire suppression throughout the Brazilian Cerrado. In tropical grasslands and savannas throughout the tropics, carbon mitigation programs that promote forest cover cannot be assumed to provide net benefits for conservation.

Carbon and energy fluxes in cropland ecosystems: a model-data comparison

USGS Publications Warehouse

Lokupitiya, E.; Denning, A. Scott; Schaefer, K.; Ricciuto, D.; Anderson, R.; Arain, M. A.; Baker, I.; Barr, A. G.; Chen, G.; Chen, J.M.; Ciais, P.; Cook, D.R.; Dietze, M.C.; El Maayar, M.; Fischer, M.; Grant, R.; Hollinger, D.; Izaurralde, C.; Jain, A.; Kucharik, C.J.; Li, Z.; Liu, S.; Li, L.; Matamala, R.; Peylin, P.; Price, D.; Running, S. W.; Sahoo, A.; Sprintsin, M.; Suyker, A.E.; Tian, H.; Tonitto, Christina; Torn, M.S.; Verbeeck, Hans; Verma, S.B.; Xue, Y.

2016-01-01

Croplands are highly productive ecosystems that contribute to land–atmosphere exchange of carbon, energy, and water during their short growing seasons. We evaluated and compared net ecosystem exchange (NEE), latent heat flux (LE), and sensible heat flux (H) simulated by a suite of ecosystem models at five agricultural eddy covariance flux tower sites in the central United States as part of the North American Carbon Program Site Synthesis project. Most of the models overestimated H and underestimated LE during the growing season, leading to overall higher Bowen ratios compared to the observations. Most models systematically under predicted NEE, especially at rain-fed sites. Certain crop-specific models that were developed considering the high productivity and associated physiological changes in specific crops better predicted the NEE and LE at both rain-fed and irrigated sites. Models with specific parameterization for different crops better simulated the inter-annual variability of NEE for maize-soybean rotation compared to those models with a single generic crop type. Stratification according to basic model formulation and phenological methodology did not explain significant variation in model performance across these sites and crops. The under prediction of NEE and LE and over prediction of H by most of the models suggests that models developed and parameterized for natural ecosystems cannot accurately predict the more robust physiology of highly bred and intensively managed crop ecosystems. When coupled in Earth System Models, it is likely that the excessive physiological stress simulated in many land surface component models leads to overestimation of temperature and atmospheric boundary layer depth, and underestimation of humidity and CO2 seasonal uptake over agricultural regions.

Carbon and energy fluxes in cropland ecosystems: a model-data comparison

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lokupitiya, E.; Denning, A. S.; Schaefer, K.

2016-06-03

Croplands are highly productive ecosystems that contribute to land–atmosphere exchange of carbon, energy, and water during their short growing seasons. We evaluated and compared net ecosystem exchange (NEE), latent heat flux (LE), and sensible heat flux (H) simulated by a suite of ecosystem models at five agricultural eddy covariance flux tower sites in the central United States as part of the North American Carbon Program Site Synthesis project. Most of the models overestimated H and underestimated LE during the growing season, leading to overall higher Bowen ratios compared to the observations. Most models systematically under predicted NEE, especially at rain-fedmore » sites. Certain crop-specific models that were developed considering the high productivity and associated physiological changes in specific crops better predicted the NEE and LE at both rain-fed and irrigated sites. Models with specific parameterization for different crops better simulated the inter-annual variability of NEE for maize-soybean rotation compared to those models with a single generic crop type. Stratification according to basic model formulation and phenological methodology did not explain significant variation in model performance across these sites and crops. The under prediction of NEE and LE and over prediction of H by most of the models suggests that models developed and parameterized for natural ecosystems cannot accurately predict the more robust physiology of highly bred and intensively managed crop ecosystems. When coupled in Earth System Models, it is likely that the excessive physiological stress simulated in many land surface component models leads to overestimation of temperature and atmospheric boundary layer depth, and underestimation of humidity and CO 2 seasonal uptake over agricultural regions.« less

Mineralogical influences on porosity-depth trends of shelf deposits (Miocene-Pleistocene) along the northwest shelf of Australia (IODP Expedition 356)

NASA Astrophysics Data System (ADS)

Knierzinger, Wolfgang; Lee, Eun Young; Wagreich, Michael

2017-04-01

Porosity in sediments is influenced by various factors such as mineralogical composition, burial depth, connate fluids, and stratigraphic layering. This work focuses on processes underlying porosity anomalies in carbonate shelf deposits along the northwest shelf of Australia by using different techniques (polarization microscopy, electron microscopy, XRD, XRF). IODP expedition 356 recovered cored seven sites (U1458-U1464), covering a latitudinal range of 29°S-18°S on the northwest shelf. Strong negative deviations from general porosity-depth trends for these carbonate rich sediments are clear for samples with higher contents of dolomite, calcium sulfates, and non-skeletal calcite. No significant influence of aragonite on porosity values has yet been detected. However, it is likely that the occurrence of high amounts of aragonite is a crucial element with regard to porosity values in these carbonate rich deposits, since elongated aragonite needles commonly enhance interparticle porosity. Further insight might be gained through the application of electron microscopy. In general, sediments in the northern part of the study area (Sites U1462, U1463, U1464) tend to show slightly higher porosity values compared to sediments form the south (Sites U1459, U1460). This may reflect the influence of calcium sulfate, because mineralogical analyses show, calcium sulfate is relatively rare at the southern sites, whereas higher amounts of calcium sulfates occur in the north. The lack of detrital particles in calcium sulfate components indicates an evaporitic origin. Deposits at Site U 1461 differ from other analyzed sediments insofar as higher amounts of feldspars and micas are apparent. *This research is conducted within the frame of the 'International Ocean Discovery Program', funded by the Ministry of Oceans and Fisheries, Korea.

Coupled greenhouse warming and deep-sea acidification in the middle Eocene

NASA Astrophysics Data System (ADS)

Bohaty, Steven M.; Zachos, James C.; Florindo, Fabio; Delaney, Margaret L.

2009-06-01

The Middle Eocene Climatic Optimum (MECO) is an enigmatic warming event that represents an abrupt reversal in long-term cooling through the Eocene. In order to further assess the timing and nature of this event, we have assembled stable isotope and calcium carbonate concentration records from multiple Deep Sea Drilling Project and Ocean Drilling Program sites for the time interval between ˜43 and 38 Ma. Revised stratigraphy at several sites and compilation of δ18O records place peak warming during the MECO event at 40.0 Ma (Chron C18n.2n). The identification of the δ18O excursion at sites in different geographic regions indicates that the climatic effects of this event were globally extensive. The total duration of the MECO event is estimated at ˜500 ka, with peak warming lasting <100 ka. Assuming minimal glaciation in the late middle Eocene, ˜4°-6°C total warming of both surface and deep waters is estimated during the MECO at the study sites. The interval of peak warming at ˜40.0 Ma also coincided with a worldwide decline in carbonate accumulation at sites below 3000 m depth, reflecting a temporary shoaling of the calcite compensation depth. The synchroneity of deep-water acidification and globally extensive warming makes a persuasive argument that the MECO event was linked to a transient increase in atmospheric pCO2. The results of this study confirm previous reports of significant climatic instability during the middle Eocene. Furthermore, the direct link between warming and changes in the carbonate chemistry of the deep ocean provides strong evidence that changes in greenhouse gas concentrations exerted a primary control on short-term climate variability during this critical period of Eocene climate evolution.

A Regional Atmospheric Continuous CO2 Network In The Rocky Mountains (Rocky RACCOON)

NASA Astrophysics Data System (ADS)

Stephens, B.; de Wekker, S.; Watt, A.; Schimel, D.

2005-12-01

We have established a continuous CO2 observing network in the Rocky Mountains, building on technological and modeling advances made during the Carbon in the Mountains Experiment (CME), to improve our understanding of regional carbon fluxes and to fill key gaps in the North American Carbon Program (NACP). We will present a description of the Rocky RACCOON network and early results from the first three sites. There are strong scientific and societal motivations for determining CO2 exchanges on regional scales. NACP aims to address these concerns through a dramatic expansion in observations and modeling capabilities over North America. Mountain forests in particular represent a significant potential net CO2 sink in the U.S. and are highly sensitive to land-use practices and climate change. However, plans for new continuous CO2 observing sites have omitted the mountain west. This resulted from expensive instrumentation in the face of limited resources, and a perception that current atmospheric transport models are not sophisticated enough to interpret CO2 measurements made in complex terrain. Through our efforts in CME, we have a new autonomous, inexpensive, and robust CO2 analysis system and are developing mountain CO2 modeling tools that will help us to overcome these obstacles. Preliminary observational and modeling results give us confidence that continuous CO2 observations from mountain top observatories will provide useful constraints on regional carbon cycling and will be valuable in the continental inverse modeling efforts planned for NACP. We began at three Colorado sites in August 2005 and hope to add three to six sites in other western states in subsequent years, utilizing existing observatories to the maximum extent possible. The first three sites are at Niwot Ridge, allowing us to have an ongoing intercomparison with flask measurements made by NOAA CMDL; at Storm Peak Laboratory near Steamboat Springs, allowing us to investigate comparisons between these two relatively nearby sites; and at Fraser Experimental Forest, allowing us to investigate nocturnal respiration rates across a large intermountain valley. Our data are available to the public on the internet in near real time to support quality control, local science, and larger scale synthesis efforts.

U-tube based near-surface environmental monitoring in the Shenhua carbon dioxide capture and storage (CCS) project.

PubMed

Li, Qi; Song, Ranran; Shi, Hui; Ma, Jianli; Liu, Xuehao; Li, Xiaochun

2018-04-01

The CO 2 injected into deep formations during implementation of carbon dioxide (CO 2 ) capture and storage (CCS) technology may leak and migrate into shallow aquifers or ground surfaces through a variety of pathways over a long period. The leaked CO 2 can threaten shallow environments as well as human health. Therefore, almost all monitoring programs for CCS projects around the world contain near-surface monitoring. This paper presents a U-tube based near-surface monitoring technology focusing on its first application in the Shenhua CCS demonstration project, located in the Ordos Basin, Inner Mongolia, China. First, background information on the site monitoring program of the Shenhua CCS demonstration project was provided. Then, the principle of fluid sampling and the monitoring methods were summarized for the U-tube sampler system, and the monitoring data were analyzed in detail. The U-tube based monitoring results showed that the U-tube sampler system is accurate, flexible, and representative of the subsurface fluid sampling process. The monitoring indicators for the subsurface water and soil gas at the Shenhua CCS site indicate good stratification characteristics. The concentration level of each monitoring indicator decreases with increasing depth. Finally, the significance of this near-surface environmental monitoring technology for CO 2 leakage assessments was preliminarily confirmed at the Shenhua CCS site. The application potential of the U-tube based monitoring technology was also demonstrated during the subsurface environmental monitoring of other CCS projects.

Greenhouse Gas Fluxes at the Tablelands, NL, Canada: A Site of Active Serpentinization

NASA Astrophysics Data System (ADS)

Morrill, P. L.; Morrissey, L. S.; Cumming, E.

2016-12-01

Active sites of serpentinization have been proposed as sites for carbon capture and storage (CCS) projects. However, in addition to their ability to convert carbon dioxide to carbonate rock, sites of serpentinization also have the potential release methane, which is a more power greenhouse gas than carbon dioxide. Very little is known about the natural flux of carbon dioxide sequestered and methane released into the atmosphere from active sites of serpentinization. In this study we measured carbon dioxide, methane, and nitrous oxide gas fluxes at a pool of ultra-basic water discharging from serpentinized rock in Winterhouse Canyon, Gros Morne, Newfoundland. We found that the flux of methane released was 4.6 x 10-7 mol/m2/min and the carbon dioxide sequestered was 1.9 x 10-5 mol/m2/min, while the concentrations of nitrous oxide showed little change. Based on these fluxes we calculated predictive climate change parameters such as net radiative forcing and global warming potential which predicted that despite the methane being released the site still had an overall long-term atmospheric cooling effect based on the natural rate of carbon dioxide sequestration.

Towards a better understanding aquatic carbon losses from lowland peatlands across England and Wales

NASA Astrophysics Data System (ADS)

Grayson, Richard; Holden, Joseph; Chapman, Pippa; Evans, Chris

2017-04-01

Hydrological fluxes in lowland peatlands can be challenging to measure but they drive poorly understood aquatic carbon fluxes which may form an important part of the overall carbon budget for peatlands. In this study we examined 11 lowland peatland sites across some of the most important fen and raised bog complexes in England and Wales including agricultural peatlands, mining sites and restoration sites. These were intensively monitored between January 2013 and December 2015. The monitoring included continual hydrological measurements and regular sampling for dissolved organic and inorganic carbon (DOC and DIC), particulate organic carbon (POC) and dissolved carbon dioxide, methane and nitrous oxide. These data were used to calculate the amount of water flowing out of each site and the total aquatic carbon loss. In addition, the hydrological data were used to provide contextual data to explain carbon flux variations between sites and help explain and model variations in gaseous carbon fluxes. The hydrology of all these lowland peat sites is typically complex with most having been drained, which when combined with their relatively flat gradients results in most having no clear single outlet. In addition the drainage networks are often used to not only drain water during periods of excess rainfall but also to maintain raised water tables during summer months when rainfall totals are low. As a result, aquatic losses were determined using a mixture of water mass balance approaches (e.g. using flux tower evapotranspiration data) and groundwater flow monitoring. The hydrology of the 11 sites was found to vary considerably, even between co-located sites, however as might be expected given the west-east rainfall gradient observed in the UK, discharge was typically highest at the Anglesey Fens sites (western Wales) and lowest at the East Anglian Fens sites (eastern England). One influence on the observed differences in discharge was the impact of vegetation type on evapotranspiration rates, with sites with high ET having some of the lowest discharge. Compared to gaseous fluxes, aquatic carbon fluxes made a smaller but significant contribution to overall rates of carbon loss, with the 'reactive' aquatic C flux accounting for 2-26% of NEE. Dissolved organic carbon (DOC) made the largest contribution. Concentrations of DOC were generally high, with all sites having mean concentrations greater than 20 mg L-1. DOC fluxes ranged from just 4 g C m-2 yr-1 up to 67 g C m-2 yr-1 being more variable than concentrations due to the wide variation in discharge from the different sites. Fluxes were highest from the raised bog sites and lowest from the fen sites.

Carbon and water fluxes from ponderosa pine forests disturbed by wildfire and thinning.

PubMed

Dore, S; Kolb, T E; Montes-Helu, M; Eckert, S E; Sullivan, B W; Hungate, B A; Kaye, J P; Hart, S C; Koch, G W; Finkral, A

2010-04-01

Disturbances alter ecosystem carbon dynamics, often by reducing carbon uptake and stocks. We compared the impact of two types of disturbances that represent the most likely future conditions of currently dense ponderosa pine forests of the southwestern United States: (1) high-intensity fire and (2) thinning, designed to reduce fire intensity. High-severity fire had a larger impact on ecosystem carbon uptake and storage than thinning. Total ecosystem carbon was 42% lower at the intensely burned site, 10 years after burning, than at the undisturbed site. Eddy covariance measurements over two years showed that the burned site was a net annual source of carbon to the atmosphere whereas the undisturbed site was a sink. Net primary production (NPP), evapotranspiration (ET), and water use efficiency were lower at the burned site than at the undisturbed site. In contrast, thinning decreased total ecosystem carbon by 18%, and changed the site from a carbon sink to a source in the first posttreatment year. Thinning also decreased ET, reduced the limitation of drought on carbon uptake during summer, and did not change water use efficiency. Both disturbances reduced ecosystem carbon uptake by decreasing gross primary production (55% by burning, 30% by thinning) more than total ecosystem respiration (TER; 33-47% by burning, 18% by thinning), and increased the contribution of soil carbon dioxide efflux to TER. The relationship between TER and temperature was not affected by either disturbance. Efforts to accurately estimate regional carbon budgets should consider impacts on carbon dynamics of both large disturbances, such as high-intensity fire, and the partial disturbance of thinning that is often used to prevent intense burning. Our results show that thinned forests of ponderosa pine in the southwestern United States are a desirable alternative to intensively burned forests to maintain carbon stocks and primary production.

Early Paleogene variations in the calcite compensation depth: new constraints using old borehole sediments from across Ninetyeast Ridge, central Indian Ocean

NASA Astrophysics Data System (ADS)

Slotnick, B. S.; Lauretano, V.; Backman, J.; Dickens, G. R.; Sluijs, A.; Lourens, L.

2015-03-01

Major variations in global carbon cycling occurred between 62 and 48 Ma, and these very likely related to changes in the total carbon inventory of the ocean-atmosphere system. Based on carbon cycle theory, variations in the mass of the ocean carbon should be reflected in contemporaneous global ocean carbonate accumulation on the seafloor and, thereby, the depth of the calcite compensation depth (CCD). To better constrain the cause and magnitude of these changes, the community needs early Paleogene carbon isotope and carbonate accumulation records from widely separated deep-sea sediment sections, especially including the Indian Ocean. Several CCD reconstructions for this time interval have been generated using scientific drill sites in the Atlantic and Pacific oceans; however, corresponding information from the Indian Ocean has been extremely limited. To assess the depth of the CCD and the potential for renewed scientific drilling of Paleogene sequences in the Indian Ocean, we examine lithologic, nannofossil, carbon isotope, and carbonate content records for late Paleocene - early Eocene sediments recovered at three sites spanning Ninetyeast Ridge: Deep Sea Drilling Project (DSDP) Sites 213 (deep, east), 214 (shallow, central), and 215 (deep, west). The disturbed, discontinuous sediment sections are not ideal, because they were recovered in single holes using rotary coring methods, but remain the best Paleogene sediments available from the central Indian Ocean. The δ13C records at Sites 213 and 215 are similar to those generated at several locations in the Atlantic and Pacific, including the prominent high in δ13C across the Paleocene carbon isotope maximum (PCIM) at Site 215, and the prominent low in δ13C across the early Eocene Climatic Optimum (EECO) at both Site 213 and Site 215. The Paleocene-Eocene thermal maximum (PETM) and the K/X event are found at Site 213 but not at Site 215, presumably because of coring gaps. Carbonate content at both Sites 213 and 215 drops to <5% shortly after the first occurrence of Discoaster lodoensis and the early Eocene rise in δ13C (~52 Ma). This reflects a rapid shoaling of the CCD, and likely a major decrease in the net flux of 13C-depleted carbon to the ocean. Our results support ideas that major changes in net fluxes of organic carbon to and from the exogenic carbon cycle occurred during the early Paleogene. Moreover, we conclude that excellent early Paleogene carbonate accumulation records might be recovered from the central Indian Ocean with future scientific drilling.

Distribution and sources of organic matter in surface marine sediments across the North American Arctic margin

NASA Astrophysics Data System (ADS)

Goñi, Miguel A.; O'Connor, Alison E.; Kuzyk, Zou Zou; Yunker, Mark B.; Gobeil, Charles; Macdonald, Robie W.

2013-09-01

As part of the International Polar Year research program, we conducted a survey of surface marine sediments from box cores along a section extending from the Bering Sea to Davis Strait via the Canadian Archipelago. We used bulk elemental and isotopic compositions, together with biomarkers and principal components analysis, to elucidate the distribution of marine and terrestrial organic matter in different regions of the North American Arctic margin. Marked regional contrasts were observed in organic carbon loadings, with the highest values (≥1 mg C m-2 sediment) found in sites along Barrow Canyon and the Chukchi and Bering shelves, all of which were characterized by sediments with low oxygen exposure, as inferred from thin layers (<2 cm) of Mn oxihydroxides. We found strong regional differences in inorganic carbon concentrations, with sites from the Canadian Archipelago and Lancaster Sound displaying elevated values (2-7 wt %) and highly depleted 14C compositions consistent with inputs from bedrock carbonates. Organic carbon:nitrogen ratios, stable carbon isotopes, and terrigenous organic biomarkers (lignin phenols and cutin acids) all indicate marked regional differences in the proportions of marine and terrigenous organic matter present in surface sediments. Regions such as Barrow Canyon and the Mackenzie River shelf were characterized by the highest contributions of land-derived organic matter, with compositional characteristics that suggested distinct sources and provenance. In contrast, sediments from the Canadian Archipelago and Davis Strait had the smallest contributions of terrigenous organic matter and the lowest organic carbon loadings indicative of a high degree of post-depositional oxidation.

The Evolution of Deep Ocean Chemistry and Respired Carbon in the Eastern Equatorial Pacific Over the Last Deglaciation

NASA Astrophysics Data System (ADS)

de la Fuente, Maria; Calvo, Eva; Skinner, Luke; Pelejero, Carles; Evans, David; Müller, Wolfgang; Povea, Patricia; Cacho, Isabel

2017-12-01

It has been shown that the deep Eastern Equatorial Pacific (EEP) region was poorly ventilated during the Last Glacial Maximum (LGM) relative to Holocene values. This finding suggests a more efficient biological pump, which indirectly supports the idea of increased carbon storage in the deep ocean contributing to lower atmospheric CO2 during the last glacial. However, proxies related to respired carbon are needed in order to directly test this proposition. Here we present Cibicides wuellerstorfi B/Ca ratios from Ocean Drilling Program Site 1240 measured by laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) as a proxy for deep water carbonate saturation state (Δ[CO32-], and therefore [CO32-]), along with δ13C measurements. In addition, the U/Ca ratio in foraminiferal coatings has been analyzed as an indicator of oxygenation changes. Our results show lower [CO32-], δ13C, and [O2] values during the LGM, which would be consistent with higher respired carbon levels in the deep EEP driven, at least in part, by reduced deep water ventilation. However, the difference between LGM and Holocene [CO32-] observed at our site is relatively small, in accordance with other records from across the Pacific, suggesting that a "counteracting" mechanism, such as seafloor carbonate dissolution, also played a role. If so, this mechanism would have increased average ocean alkalinity, allowing even more atmospheric CO2 to be "sequestered" by the ocean. Therefore, the deep Pacific Ocean very likely stored a significant amount of atmospheric CO2 during the LGM, specifically due to a more efficient biological carbon pump and also an increase in average ocean alkalinity.

Soil organic matter stability as indicated by compound-specific radiocarbon analyses

NASA Astrophysics Data System (ADS)

van der Voort, Tessa Sophia; Zell, Claudia; Hagedorn, Frank; McIntyre, Cameron; Eglinton, Timothy Ian

2017-04-01

Carbon storage in soils is increasingly recognized as a key ecosystem function, and molecular-level analyses could be a valuable potential indicator of this storage potential. In this framework, radiocarbon constitutes a powerful tool for unraveling soil carbon dynamics on both decadal as well as centennial and millennial timescales. In this study, we look at the radiocarbon signature of specific compounds (fatty acids and n-alkanes) in two forested ecosystems (temperate and pre-alpine) with the aim of attaining a better understanding of soil organic carbon stability on a molecular level. Radiocarbon dating of the fatty acids and n-alkanes has been coupled to abundance data of these compounds and additionally lignin phenols. We hypothesize that potentially, these long-chain apolar compounds could be a representative indicator of the mineral-bound soil organic carbon pool. These well-studied sites are part of the Long-Term Forest Ecosystem Research (LWF) program of the Swiss Federal Institute for Forest, Snow and Landscape research (WSL). Therefore, a wide suite of ancillary climatic and textural data is available for these sites. Initial results show a wide range of ages in the specific compounds which constitute a much larger range than the ages indicated by the density fractions done on the same samples. Overall, this study explores the use of molecular-level indicators to study soil organic matter dynamics, which could help assess the overall potential vulnerability of soil carbon in various ecosystems.

Nevada National Security Site 2011 Data Report: Groundwater Monitoring Program Area 5 Radioactive Waste Management Site

DOE Office of Scientific and Technical Information (OSTI.GOV)

NSTec Environmental Management

2012-02-27

This report is a compilation of the groundwater sampling results from the Area 5 Radioactive Waste Management Site (RWMS). The data have been collected since 1993 and include calendar year 2011 results. During 2011, groundwater samples were collected and static water levels were measured at the three pilot wells surrounding the Area 5 RWMS. Samples were collected at UE5PW-1 on March 8, August 2, August 24, and October 19, 2011; at UE5PW-2 on March 8, August 2, August 23, and October 19, 2011; and at UE5PW-3 on March 8, August 2, August 23, and October 19, 2011. Static water levelsmore » were measured at each of the three pilot wells on March 1, June 7, August 1, and October 17, 2011. Groundwater samples were analyzed for the following indicators of contamination: pH, specific conductance, total organic carbon, total organic halides, and tritium. Indicators of general water chemistry (cations and anions) were also measured. Initial total organic carbon and total organic halides results for samples collected in August 2011 were above previous measurements and, in some cases, above the established investigation limits. However, after field sample pumps and tubing were disinfected with Clorox solution, the results returned to normal levels. Final results from samples collected in 2011 were within the limits established by agreement with the Nevada Division of Environmental Protection for each analyte. These data indicate that there has been no measurable impact to the uppermost aquifer from the Area 5 RWMS. There were no significant changes in measured groundwater parameters compared to previous years. The report contains an updated cumulative chronology for the Area 5 RWMS Groundwater Monitoring Program and a brief description of the site hydrogeology.« less

Fast synthesis of multilayer carbon nanotubes from camphor oil as an energy storage material.

PubMed

TermehYousefi, Amin; Bagheri, Samira; Shinji, Kawasaki; Rouhi, Jalal; Rusop Mahmood, Mohamad; Ikeda, Shoichiro

2014-01-01

Among the wide range of renewable energy sources, the ever-increasing demand for electricity storage represents an emerging challenge. Utilizing carbon nanotubes (CNTs) for energy storage is closely being scrutinized due to the promising performance on top of their extraordinary features. In this work, well-aligned multilayer carbon nanotubes were successfully synthesized on a porous silicon (PSi) substrate in a fast process using renewable natural essential oil via chemical vapor deposition (CVD). Considering the influx of vaporized multilayer vertical carbon nanotubes (MVCNTs) to the PSi, the diameter distribution increased as the flow rate decreased in the reactor. Raman spectroscopy results indicated that the crystalline quality of the carbon nanotubes structure exhibits no major variation despite changes in the flow rate. Fourier transform infrared (FT-IR) spectra confirmed the hexagonal structure of the carbon nanotubes because of the presence of a peak corresponding to the carbon double bond. Field emission scanning electron microscopy (FESEM) images showed multilayer nanotubes, each with different diameters with long and straight multiwall tubes. Moreover, the temperature programmed desorption (TPD) method has been used to analyze the hydrogen storage properties of MVCNTs, which indicates that hydrogen adsorption sites exist on the synthesized multilayer CNTs.

Fast Synthesis of Multilayer Carbon Nanotubes from Camphor Oil as an Energy Storage Material

PubMed Central

TermehYousefi, Amin; Bagheri, Samira; Shinji, Kawasaki; Rouhi, Jalal; Rusop Mahmood, Mohamad; Ikeda, Shoichiro

2014-01-01

Among the wide range of renewable energy sources, the ever-increasing demand for electricity storage represents an emerging challenge. Utilizing carbon nanotubes (CNTs) for energy storage is closely being scrutinized due to the promising performance on top of their extraordinary features. In this work, well-aligned multilayer carbon nanotubes were successfully synthesized on a porous silicon (PSi) substrate in a fast process using renewable natural essential oil via chemical vapor deposition (CVD). Considering the influx of vaporized multilayer vertical carbon nanotubes (MVCNTs) to the PSi, the diameter distribution increased as the flow rate decreased in the reactor. Raman spectroscopy results indicated that the crystalline quality of the carbon nanotubes structure exhibits no major variation despite changes in the flow rate. Fourier transform infrared (FT-IR) spectra confirmed the hexagonal structure of the carbon nanotubes because of the presence of a peak corresponding to the carbon double bond. Field emission scanning electron microscopy (FESEM) images showed multilayer nanotubes, each with different diameters with long and straight multiwall tubes. Moreover, the temperature programmed desorption (TPD) method has been used to analyze the hydrogen storage properties of MVCNTs, which indicates that hydrogen adsorption sites exist on the synthesized multilayer CNTs. PMID:25258714

Managing carbon sequestration and storage in northern hardwood forests

Treesearch

Eunice A. Padley; Deahn M. Donner; Karin S. Fassnacht; Ronald S. Zalesny; Bruce Birr; Karl J. Martin

2011-01-01

Carbon has an important role in sustainable forest management, contributing to functions that maintain site productivity, nutrient cycling, and soil physical properties. Forest management practices can alter ecosystem carbon allocation as well as the amount of total site carbon.

An optimization model for carbon capture & storage/utilization vs. carbon trading: A case study of fossil-fired power plants in Turkey.

PubMed

Ağralı, Semra; Üçtuğ, Fehmi Görkem; Türkmen, Burçin Atılgan

2018-06-01

We consider fossil-fired power plants that operate in an environment where a cap and trade system is in operation. These plants need to choose between carbon capture and storage (CCS), carbon capture and utilization (CCU), or carbon trading in order to obey emissions limits enforced by the government. We develop a mixed-integer programming model that decides on the capacities of carbon capture units, if it is optimal to install them, the transportation network that needs to be built for transporting the carbon captured, and the locations of storage sites, if they are decided to be built. Main restrictions on the system are the minimum and maximum capacities of the different parts of the pipeline network, the amount of carbon that can be sold to companies for utilization, and the capacities on the storage sites. Under these restrictions, the model aims to minimize the net present value of the sum of the costs associated with installation and operation of the carbon capture unit and the transportation of carbon, the storage cost in case of CCS, the cost (or revenue) that results from the emissions trading system, and finally the negative revenue of selling the carbon to other entities for utilization. We implement the model on General Algebraic Modeling System (GAMS) by using data associated with two coal-fired power plants located in different regions of Turkey. We choose enhanced oil recovery (EOR) as the process in which carbon would be utilized. The results show that CCU is preferable to CCS as long as there is sufficient demand in the EOR market. The distance between the location of emission and location of utilization/storage, and the capacity limits on the pipes are an important factor in deciding between carbon capture and carbon trading. At carbon prices over $15/ton, carbon capture becomes preferable to carbon trading. These results show that as far as Turkey is concerned, CCU should be prioritized as a means of reducing nation-wide carbon emissions in an environmentally and economically rewarding manner. The model developed in this study is generic, and it can be applied to any industry at any location, as long as the required inputs are available. Copyright © 2018 Elsevier Ltd. All rights reserved.

Evaluation of the Community Land Model simulated carbon and water fluxes against observations over ChinaFLUX sites

DOE PAGES

Zhang, Li; Mao, Jiafu; Shi, Xiaoying; ...

2016-07-15

The Community Land Model (CLM) is an advanced process-based land surface model that simulates carbon, nitrogen, water vapor and energy exchanges between terrestrial ecosystems and the atmosphere at various spatial and temporal scales. We use observed carbon and water fluxes from five representative Chinese Terrestrial Ecosystem Flux Research Network (ChinaFLUX) eddy covariance tower sites to systematically evaluate the new version CLM4.5 and old version CLM4.0, and to generate insights that may inform future model developments. CLM4.5 underestimates the annual carbon sink at three forest sites and one alpine grassland site but overestimates the carbon sink of a semi-arid grassland site.more » The annual carbon sink underestimation for the deciduous-dominated forest site results from underestimated daytime carbon sequestration during summer and overestimated nighttime carbon emission during spring and autumn. Compared to CLM4.0, the bias of annual gross primary production (GPP) is reduced by 24% and 28% in CLM4.5 at two subtropical forest sites. However, CLM4.5 still presents a large positive bias in annual GPP. The improvement in net ecosystem exchange (NEE) is limited, although soil respiration bias decreases by 16%–43% at three forest sites. CLM4.5 simulates lower soil water content in the dry season than CLM4.0 at two grassland sites. Drier soils produce a significant drop in the leaf area index and in GPP and an increase in respiration for CLM4.5. The new fire parameterization approach in CLM4.5 causes excessive burning at the Changbaishan forest site, resulting in an unexpected underestimation of NEE, vegetation carbon, and soil organic carbon by 46%, 95%, and 87%, respectively. Altogether, our study reveals significant improvements achieved by CLM4.5 compared to CLM4.0, and suggests further developments on the parameterization of seasonal GPP and respiration, which will require a more effective representation of seasonal water conditions and the partitioning of net radiation between sensible and heat fluxes.« less

Changes in Soil Carbon Storage in Industrial Forests of Western Oregon and Washington Following Modern Timber Harvesting Practices

NASA Astrophysics Data System (ADS)

Holub, S. M.; Hatten, J. A.

2016-12-01

Carbon in forest soils is often overlooked because it is less conspicuous than the live trees, downed wood, and forest floor layer that are easily visible when walking through a forest. However, the amount of carbon in forest soils to one meter depth is generally one to two times the amount of carbon we see above ground in mature forests, making soils an important carbon storage pool in forest ecosystems. Given the large quantity of carbon stored in soil, there is some concern that disturbances to forest ecosystems could push some soils out of steady state and lead to a release of carbon from the soil, potentially contributing to the already large amount of greenhouse gas emissions from the burning of fossil fuels for energy. This has implications for the carbon neutrality of timberlands. Thus, careful investigation of the carbon cycle in forest soils is a key component in deciphering the gains and losses of carbon from forests, and ultimately understanding the effects of forest soils on the global carbon cycle. The study objective was to measure pre-harvest soil carbon stores to 1 m depth with enough precision to detect a small change upon resampling post-harvest. The 9 sites examined ranged from 100 to 400 Mg C / ha before harvest with minimum detectible differences around 5%. Three and a half years post-harvest the average of all 9 sites showed a very modest increase in mineral soil carbon as a result of modern timber harvest. Mineral soil carbon did not change significantly at 6 of the 9 sites, individually (range -2% to +5%), while two sites gained soil carbon (+6% and +11%) and soil carbon decreased at one site (-6%).

Evaluation of forest structure, biomass and carbon sequestration in subtropical pristine forests of SW China.

PubMed

Nizami, Syed Moazzam; Yiping, Zhang; Zheng, Zheng; Zhiyun, Lu; Guoping, Yang; Liqing, Sha

2017-03-01

Very old natural forests comprising the species of Fagaceae (Lithocarpus xylocarpus, Castanopsis wattii, Lithocarpus hancei) have been prevailing since years in the Ailaoshan Mountain Nature Reserve (AMNR) SW China. Within these forest trees, density is quite variable. We studied the forest structure, stand dynamics and carbon density at two different sites to know the main factors which drives carbon sequestration process in old forests by considering the following questions: How much is the carbon density in these forest trees of different DBH (diameter at breast height)? How much carbon potential possessed by dominant species of these forests? How vegetation carbon is distributed in these forests? Which species shows high carbon sequestration? What are the physiochemical properties of soil in these forests? Five-year (2005-2010) tree growth data from permanently established plots in the AMNR was analysed for species composition, density, stem diameter (DBH), height and carbon (C) density both in aboveground and belowground vegetation biomass. Our study indicated that among two comparative sites, overall 54 species of 16 different families were present. The stem density, height, C density and soil properties varied significantly with time among the sites showing uneven distribution across the forests. Among the dominant species, L. xylocarpus represents 30% of the total carbon on site 1 while C. wattii represents 50% of the total carbon on site 2. The average C density ranged from 176.35 to 243.97 t C ha -1 . The study emphasized that there is generous degree to expand the carbon stocking in this AMNR through scientific management gearing towards conservation of old trees and planting of potentially high carbon sequestering species on good site quality areas.

Stimulation of Microbially Mediated Arsenic Release in Bangladesh Aquifers by Young Carbon Indicated by Radiocarbon Analysis of Sedimentary Bacterial Lipids.

PubMed

Whaley-Martin, K J; Mailloux, B J; van Geen, A; Bostick, B C; Silvern, R F; Kim, C; Ahmed, K M; Choudhury, I; Slater, G F

2016-07-19

The sources of reduced carbon driving the microbially mediated release of arsenic to shallow groundwater in Bangladesh remain poorly understood. Using radiocarbon analysis of phospholipid fatty acids (PLFAs) and potential carbon pools, the abundance and carbon sources of the active, sediment-associated, in situ bacterial communities inhabiting shallow aquifers (<30 m) at two sites in Araihazar, Bangladesh, were investigated. At both sites, sedimentary organic carbon (SOC) Δ(14)C signatures of -631 ± 54‰ (n = 12) were significantly depleted relative to dissolved inorganic carbon (DIC) of +24 ± 30‰ and dissolved organic carbon (DOC) of -230 ± 100‰. Sediment-associated PLFA Δ(14)C signatures (n = 10) at Site F (-167‰ to +20‰) and Site B (-163‰ to +21‰) were highly consistent and indicated utilization of carbon sources younger than the SOC, likely from the DOC pool. Sediment-associated PLFA Δ(14)C signatures were consistent with previously determined Δ(14)C signatures of microbial DNA sampled from groundwater at Site F indicating that the carbon source for these two components of the subsurface microbial community is consistent and is temporally stable over the two years between studies. These results demonstrate that the utilization of relatively young carbon sources by the subsurface microbial community occurs at sites with varying hydrology. Further they indicate that these young carbon sources drive the metabolism of the more abundant sediment-associated microbial communities that are presumably more capable of Fe reduction and associated release of As. This implies that an introduction of younger carbon to as of yet unaffected sediments (such as those comprising the deeper Pleistocene aquifer) could stimulate microbial communities and result in arsenic release.

Modeling carbon dynamics in vegetation and soil under the impact of soil erosion and deposition

NASA Astrophysics Data System (ADS)

Liu, Shuguang; Bliss, Norman; Sundquist, Eric; Huntington, Thomas G.

2003-06-01

Soil erosion and deposition may play important roles in balancing the global atmospheric carbon budget through their impacts on the net exchange of carbon between terrestrial ecosystems and the atmosphere. Few models and studies have been designed to assess these impacts. In this study, we developed a general ecosystem model, Erosion-Deposition-Carbon-Model (EDCM), to dynamically simulate the influences of rainfall-induced soil erosion and deposition on soil organic carbon (SOC) dynamics in soil profiles. EDCM was applied to several landscape positions in the Nelson Farm watershed in Mississippi, including ridge top (without erosion or deposition), eroding hillslopes, and depositional sites that had been converted from native forests to croplands in 1870. Erosion reduced the SOC storage at the eroding sites and deposition increased the SOC storage at the depositional areas compared with the site without erosion or deposition. Results indicated that soils were consistently carbon sources to the atmosphere at all landscape positions from 1870 to 1950, with lowest source strength at the eroding sites (13 to 24 gC m-2 yr-1), intermediate at the ridge top (34 gC m-2 yr-1), and highest at the depositional sites (42 to 49 gC m-2 yr-1). During this period, erosion reduced carbon emissions via dynamically replacing surface soil with subsurface soil that had lower SOC contents (quantity change) and higher passive SOC fractions (quality change). Soils at all landscape positions became carbon sinks from 1950 to 1997 due to changes in management practices (e.g., intensification of fertilization and crop genetic improvement). The sink strengths were highest at the eroding sites (42 to 44 gC m-2 yr-1), intermediate at the ridge top (35 gC m-2 yr-1), and lowest at the depositional sites (26 to 29 gC m-2 yr-1). During this period, erosion enhanced carbon uptake at the eroding sites by continuously taking away a fraction of SOC that can be replenished with enhanced plant residue input. Overall, soil erosion and deposition reduced CO2 emissions from the soil into the atmosphere by exposing low carbon-bearing soil at eroding sites and by burying SOC at depositional sites. The results suggest that failing to account for the impact of soil erosion and deposition may potentially contribute to an overestimation of both the total historical carbon released from soils owing to land use change and the contemporary carbon sequestration rates at the eroding sites.

Modeling carbon dynamics in vegetation and soil under the impact of soil erosion and deposition

USGS Publications Warehouse

Liu, S.; Bliss, N.; Sundquist, E.; Huntington, T.G.

2003-01-01

Soil erosion and deposition may play important roles in balancing the global atmospheric carbon budget through their impacts on the net exchange of carbon between terrestrial ecosystem and the atmosphere. Few models and studies have been designed to assess these impacts. In this study, we developed a general ecosystem model, Erosion-Deposition-Carbon-Model (EDCM), to dynamically simulate the influences of rainfall-induced soil erosion and deposition on soil organic carbon (SOC) dynamics in soil profiles. EDCM was applied to several landscape positions in the Nelson Farm watershed in Mississippi, including ridge top (without erosion or deposition), eroding hillslopes, and depositional sites that had been converted from native forests to croplands in 1870. Erosion reduced the SOC storage at the eroding sites and deposition increased the SOC storage at the depositional areas compared with the site without erosion or deposition. Results indicated that soils were consistently carbon sources to the atmosphere at all landscape positions from 1870 to 1950, with lowest source strength at the eroding sites (13 to 24 gC m-2 yr-1), intermediate at the ridge top (34 gC m-2 yr-1), and highest at the depositional sites (42 to 49 gC m-2 yr-1). During this period, erosion reduced carbon emissions via dynamically replacing surface soil with subsurface soil that had lower SOC contents (quantity change) and higher passive SOC fractions (quality change). Soils at all landscape positions became carbon sinks from 1950 to 1997 due to changes in management practices (e.g., intensification of fertilization and crop genetic improvement). The sink strengths were highest at the eroding sites (42 to 44 gC m-2 yr-1 , intermediate at the ridge top (35 gC m-2 yr-1), and lowest at the depositional sites (26 to 29 gC m-2 yr-1). During this period, erosion enhanced carbon uptake at the eroding sites by continuously taking away a fraction of SOC that can be replenished with enhanced plant residue input. Overall, soil erosion and deposition reduced CO2 emissions from the soil into the atmosphere by exposing low carbon-bearing soil at eroding sites and by burying SOC at depositional sites. The results suggest that failing to account for the impact of soil erosion and deposition may potentially contribute to an overestimation of both the total historical carbon released from soils owing to land use change and the contemporary carbon sequestration rates at the eroding sites.

Chemical and isotopic signature of bulk organic matter and hydrocarbon biomarkers within mid-slope accretionary sediments of the northern Cascadia margin gas hydrate system

USGS Publications Warehouse

Kaneko, Masanori; Shingai, Hiroshi; Pohlman, John W.; Naraoka, Hiroshi

2010-01-01

The chemical and isotopic compositions of sedimentary organic matter (SOM) from two mid-slope sites of the northern Cascadia margin were investigated during Integrated Ocean Drilling Program (IODP) Expedition 311 to elucidate the organic matter origins and identify potential microbial contributions to SOM. Gas hydrate is present at both locations (IODP Sites U1327 and U1328), with distinct patterns of near-seafloor structural accumulations at the cold seep Site U1328 and deeper stratigraphic accumulations at the slope-basin Site U1327. Source characterization and evidence that some components of the organic matter have been diagenetically altered are determined from the concentrations and isotopic compositions of hydrocarbon biomarkers, total organic carbon (TOC), total nitrogen (TN) and total sulfur (TS). The carbon isotopic compositions of TOC (δ13CTOC = −26 to −22‰) and long-chain n-alkanes (C27, C29 and C31, δ13C = −34 to − 29‰) suggest the organic matter at both sites is a mixture of 1) terrestrial plants that employ the C3 photosynthetic pathway and 2) marine algae. In contrast, the δ15NTN values of the bulk sediment (+ 4 to + 8‰) are consistent with a predominantly marine source, but these values most likely have been modified during microbial organic matter degradation. The δ13C values of archaeal biomarker pentamethylicosane (PMI) (− 46.4‰) and bacterial-sourced hopenes, diploptene and hop-21-ene (− 40.9 to − 34.7‰) indicate a partial contribution from methane carbon or a chemoautotrophic pathway. Our multi-isotope and biomarker-based conclusions are consistent with previous studies, based only on the elemental composition of bulk sediments, that suggested a mixed marine-terrestrial organic matter origin for these mid-slope sites of the northern Cascadia margin.

INTEGRATED GASIFICATION COMBINED CYCLE PROJECT 2 MW FUEL CELL DEMONSTRATION

DOE Office of Scientific and Technical Information (OSTI.GOV)

FuelCell Energy

2005-05-16

With about 50% of power generation in the United States derived from coal and projections indicating that coal will continue to be the primary fuel for power generation in the next two decades, the Department of Energy (DOE) Clean Coal Technology Demonstration Program (CCTDP) has been conducted since 1985 to develop innovative, environmentally friendly processes for the world energy market place. The 2 MW Fuel Cell Demonstration was part of the Kentucky Pioneer Energy (KPE) Integrated Gasification Combined Cycle (IGCC) project selected by DOE under Round Five of the Clean Coal Technology Demonstration Program. The participant in the CCTDP Vmore » Project was Kentucky Pioneer Energy for the IGCC plant. FuelCell Energy, Inc. (FCE), under subcontract to KPE, was responsible for the design, construction and operation of the 2 MW fuel cell power plant. Duke Fluor Daniel provided engineering design and procurement support for the balance-of-plant skids. Colt Engineering Corporation provided engineering design, fabrication and procurement of the syngas processing skids. Jacobs Applied Technology provided the fabrication of the fuel cell module vessels. Wabash River Energy Ltd (WREL) provided the test site. The 2 MW fuel cell power plant utilizes FuelCell Energy's Direct Fuel Cell (DFC) technology, which is based on the internally reforming carbonate fuel cell. This plant is capable of operating on coal-derived syngas as well as natural gas. Prior testing (1992) of a subscale 20 kW carbonate fuel cell stack at the Louisiana Gasification Technology Inc. (LGTI) site using the Dow/Destec gasification plant indicated that operation on coal derived gas provided normal performance and stable operation. Duke Fluor Daniel and FuelCell Energy developed a commercial plant design for the 2 MW fuel cell. The plant was designed to be modular, factory assembled and truck shippable to the site. Five balance-of-plant skids incorporating fuel processing, anode gas oxidation, heat recovery, water treatment/instrument air, and power conditioning/controls were built and shipped to the site. The two fuel cell modules, each rated at 1 MW on natural gas, were fabricated by FuelCell Energy in its Torrington, CT manufacturing facility. The fuel cell modules were conditioned and tested at FuelCell Energy in Danbury and shipped to the site. Installation of the power plant and connection to all required utilities and syngas was completed. Pre-operation checkout of the entire power plant was conducted and the plant was ready to operate in July 2004. However, fuel gas (natural gas or syngas) was not available at the WREL site due to technical difficulties with the gasifier and other issues. The fuel cell power plant was therefore not operated, and subsequently removed by October of 2005. The WREL fuel cell site was restored to the satisfaction of WREL. FuelCell Energy continues to market carbonate fuel cells for natural gas and digester gas applications. A fuel cell/turbine hybrid is being developed and tested that provides higher efficiency with potential to reach the DOE goal of 60% HHV on coal gas. A system study was conducted for a 40 MW direct fuel cell/turbine hybrid (DFC/T) with potential for future coal gas applications. In addition, FCE is developing Solid Oxide Fuel Cell (SOFC) power plants with Versa Power Systems (VPS) as part of the Solid State Energy Conversion Alliance (SECA) program and has an on-going program for co-production of hydrogen. Future development in these technologies can lead to future coal gas fuel cell applications.« less

Hadrontherapy - macrobenefit in cancer therapy?

NASA Astrophysics Data System (ADS)

Habrand, J. L.; Baron, E.; Bourhis, J.; Datchary, J.; Mazal, A.; Meflah, K.

2012-07-01

Hadrontherapy is one of the most promising radiotherapeutical innovations that deal with accelerated heavy charged particles, mainly proton and carbon ions. Their salient features include an original dose-distribution, based on the Bragg curve, and in some of them an increased RBE at the range-end. Approximately 100 000 patients have been treated so far in approximately 40 centers worldwide. Outstanding outcomes have been substantiated in rare neoplasms using protons, such as ocular melanomas, skull base sarcomas, and pediatric malignancies, while only promising evidences have emerged using carbons. Assessing their place in more common tumor-sites, such as lung, pancreas, prostate, esophagus remains to be determined, and justifies the expansion of future particle therapy programs.

Glacial/interglacial changes in subarctic north pacific stratification.

PubMed

Jaccard, S L; Haug, G H; Sigman, D M; Pedersen, T F; Thierstein, H R; Röhl, U

2005-05-13

Since the first evidence of low algal productivity during ice ages in the Antarctic Zone of the Southern Ocean was discovered, there has been debate as to whether it was associated with increased polar ocean stratification or with sea-ice cover, shortening the productive season. The sediment concentration of biogenic barium at Ocean Drilling Program site 882 indicates low algal productivity during ice ages in the Subarctic North Pacific as well. Site 882 is located southeast of the summer sea-ice extent even during glacial maxima, ruling out sea-ice-driven light limitation and supporting stratification as the explanation, with implications for the glacial cycles of atmospheric carbon dioxide concentration.

Exploring Research Contributions of the North American Carbon Program using Google Earth and Google Map

NASA Astrophysics Data System (ADS)

Griffith, P. C.; Wilcox, L. E.; Morrell, A.

2009-12-01

The central objective of the North American Carbon Program (NACP), a core element of the US Global Change Research Program, is to quantify the sources and sinks of carbon dioxide, carbon monoxide, and methane in North America and adjacent ocean regions. The NACP consists of a wide range of investigators at universities and federal research centers. Although many of these investigators have worked together in the past, many have had few prior interactions and may not know of similar work within knowledge domains, much less across the diversity of environments and scientific approaches in the Program. Coordinating interactions and sharing data are major challenges in conducting NACP. The Google Earth and Google Map Collections on the NACP website (www.nacarbon.org) provide a geographical view of the research products contributed by each core and affiliated NACP project. Other relevant data sources (e.g. AERONET, LVIS) can also be browsed in spatial context with NACP contributions. Each contribution links to project-oriented metadata, or “project profiles”, that provide a greater understanding of the scientific and social context of each dataset and are an important means of communicating within the NACP and to the larger carbon cycle science community. Project profiles store information such as a project's title, leaders, participants, an abstract, keywords, funding agencies, associated intensive campaigns, expected data products, data needs, publications, and URLs to associated data centers, datasets, and metadata. Data products are research contributions that include biometric inventories, flux tower estimates, remote sensing land cover products, tools, services, and model inputs / outputs. Project leaders have been asked to identify these contributions to the site level whenever possible, either through simple latitude/longitude pair, or by uploading a KML, KMZ, or shape file. Project leaders may select custom icons to graphically categorize their contributions; for example, a ship for oceanographic samples, a tower for tower measurements. After post-processing, research contributions are added to the NACP Google Earth and Google Map Collection to facilitate discovery and use in synthesis activities of the Program.

Sampling design and procedures for fixed surface-water sites in the Georgia-Florida coastal plain study unit, 1993

USGS Publications Warehouse

Hatzell, H.H.; Oaksford, E.T.; Asbury, C.E.

1995-01-01

The implementation of design guidelines for the National Water-Quality Assessment (NAWQA) Program has resulted in the development of new sampling procedures and the modification of existing procedures commonly used in the Water Resources Division of the U.S. Geological Survey. The Georgia-Florida Coastal Plain (GAFL) study unit began the intensive data collection phase of the program in October 1992. This report documents the implementation of the NAWQA guidelines by describing the sampling design and procedures for collecting surface-water samples in the GAFL study unit in 1993. This documentation is provided for agencies that use water-quality data and for future study units that will be entering the intensive phase of data collection. The sampling design is intended to account for large- and small-scale spatial variations, and temporal variations in water quality for the study area. Nine fixed sites were selected in drainage basins of different sizes and different land-use characteristics located in different land-resource provinces. Each of the nine fixed sites was sampled regularly for a combination of six constituent groups composed of physical and chemical constituents: field measurements, major ions and metals, nutrients, organic carbon, pesticides, and suspended sediments. Some sites were also sampled during high-flow conditions and storm events. Discussion of the sampling procedure is divided into three phases: sample collection, sample splitting, and sample processing. A cone splitter was used to split water samples for the analysis of the sampling constituent groups except organic carbon from approximately nine liters of stream water collected at four fixed sites that were sampled intensively. An example of the sample splitting schemes designed to provide the sample volumes required for each sample constituent group is described in detail. Information about onsite sample processing has been organized into a flowchart that describes a pathway for each of the constituent groups.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Li; Mao, Jiafu; Shi, Xiaoying

The Community Land Model (CLM) is an advanced process-based land surface model that simulates carbon, nitrogen, water vapor and energy exchanges between terrestrial ecosystems and the atmosphere at various spatial and temporal scales. We use observed carbon and water fluxes from five representative Chinese Terrestrial Ecosystem Flux Research Network (ChinaFLUX) eddy covariance tower sites to systematically evaluate the new version CLM4.5 and old version CLM4.0, and to generate insights that may inform future model developments. CLM4.5 underestimates the annual carbon sink at three forest sites and one alpine grassland site but overestimates the carbon sink of a semi-arid grassland site.more » The annual carbon sink underestimation for the deciduous-dominated forest site results from underestimated daytime carbon sequestration during summer and overestimated nighttime carbon emission during spring and autumn. Compared to CLM4.0, the bias of annual gross primary production (GPP) is reduced by 24% and 28% in CLM4.5 at two subtropical forest sites. However, CLM4.5 still presents a large positive bias in annual GPP. The improvement in net ecosystem exchange (NEE) is limited, although soil respiration bias decreases by 16%–43% at three forest sites. CLM4.5 simulates lower soil water content in the dry season than CLM4.0 at two grassland sites. Drier soils produce a significant drop in the leaf area index and in GPP and an increase in respiration for CLM4.5. The new fire parameterization approach in CLM4.5 causes excessive burning at the Changbaishan forest site, resulting in an unexpected underestimation of NEE, vegetation carbon, and soil organic carbon by 46%, 95%, and 87%, respectively. Altogether, our study reveals significant improvements achieved by CLM4.5 compared to CLM4.0, and suggests further developments on the parameterization of seasonal GPP and respiration, which will require a more effective representation of seasonal water conditions and the partitioning of net radiation between sensible and heat fluxes.« less

Carbon budgets of thirteen years at the FLUXNET cropland site Oensingen, Switzerland

NASA Astrophysics Data System (ADS)

Emmel, Carmen; Revill, Andrew; Hörtnagl, Lukas; Eugster, Werner

2017-04-01

The FLUXNET cropland site at Oensingen, Switzerland (CH-Oe2) is located on the Swiss Plateau, which is representative for the average domain of agricultural crop production in Switzerland. The site is managed under the low pesticide integrated production (IP) farming protocol and features a crop rotation focusing on winter wheat, but also includes winter barley, rapeseed, peas and potatoes as well as intermediate cover crops. Thirteen years of eddy covariance and meteorological measurements are available for the site. The carbon imports through manure applications and sowing, along with the exports through harvests, were quantified. In this study, we analyze the carbon budgets of all crop types and measurement years. These results will be compared to changes in soil carbon content. We will answer the questions: (1) Has the crop rotation and field management resulted in a net carbon source or sink? (2) To what extent are the different crop types linked to net carbon exchanges? (3) What are the climatic potential drivers for the interannual cropland carbon budget? (4) Is the carbon budget reflected in the changes in soil carbon content?

Hydrogeologic studies at the USGS Amargosa Desert Research Site

USGS Publications Warehouse

Andraski, Brian J.; Stonestrom, David A.; Taylor, Emily M.

1998-01-01

In 1976, the U.S. Geological Survey (USGS) began studies of unsaturated-zone hydrology in the Amargosa Desert in support of the USGS Low-Level Radioactive Waste Program. In 1983, agreements with the Bureau of Land Management and the State of Nevada established two field study areas: a 16-ha area adjacent to a waste-burial facility 17 km south of Beatty and a 0.1-ha area about 3 km farther south (fig. 1A). The study areas are collectively known as the Amargosa Desert Research Site (ADRS). Investigations at the ADRS have provided long-term benchmark information about hydraulic characteristics and soil-water movement for undisturbed conditions and for simulated waste-site conditions in arid environments. In 1995, as a result of unexpectedly finding high concentrations of tritium and carbon-14 in the unsaturated zone beneath the ADRS, the scope of research was broadened to include the study of processes affecting radionuclide transport. The ADRS was incorporated into the USGS Toxic Substances Hydrology Program in 1997. Research at the site is a multidisciplinary, collaborative effort that involves scientists from the USGS, universities, research institutes, and national laboratories. The overall objective for research at the site is to improve understanding of and methods for characterizing mechanisms that control subsurface migration and fate of contaminants in arid environments.

Deriving Multiple Benefits from Carbon Market-Based Savanna Fire Management: An Australian Example.

PubMed

Russell-Smith, Jeremy; Yates, Cameron P; Edwards, Andrew C; Whitehead, Peter J; Murphy, Brett P; Lawes, Michael J

2015-01-01

Carbon markets afford potentially useful opportunities for supporting socially and environmentally sustainable land management programs but, to date, have been little applied in globally significant fire-prone savanna settings. While fire is intrinsic to regulating the composition, structure and dynamics of savanna systems, in north Australian savannas frequent and extensive late dry season wildfires incur significant environmental, production and social impacts. Here we assess the potential of market-based savanna burning greenhouse gas emissions abatement and allied carbon biosequestration projects to deliver compatible environmental and broader socio-economic benefits in a highly biodiverse north Australian setting. Drawing on extensive regional ecological knowledge of fire regime effects on fire-vulnerable taxa and communities, we compare three fire regime metrics (seasonal fire frequency, proportion of long-unburnt vegetation, fire patch-size distribution) over a 15-year period for three national parks with an indigenously (Aboriginal) owned and managed market-based emissions abatement enterprise. Our assessment indicates improved fire management outcomes under the emissions abatement program, and mostly little change or declining outcomes on the parks. We attribute improved outcomes and putative biodiversity benefits under the abatement program to enhanced strategic management made possible by the market-based mitigation arrangement. For these same sites we estimate quanta of carbon credits that could be delivered under realistic enhanced fire management practice, using currently available and developing accredited Australian savanna burning accounting methods. We conclude that, in appropriate situations, market-based savanna burning activities can provide transformative climate change mitigation, ecosystem health, and community benefits in northern Australia, and, despite significant challenges, potentially in other fire-prone savanna settings.

Deriving Multiple Benefits from Carbon Market-Based Savanna Fire Management: An Australian Example

PubMed Central

Russell-Smith, Jeremy; Yates, Cameron P.; Edwards, Andrew C.; Whitehead, Peter J.; Murphy, Brett P.; Lawes, Michael J.

2015-01-01

Carbon markets afford potentially useful opportunities for supporting socially and environmentally sustainable land management programs but, to date, have been little applied in globally significant fire-prone savanna settings. While fire is intrinsic to regulating the composition, structure and dynamics of savanna systems, in north Australian savannas frequent and extensive late dry season wildfires incur significant environmental, production and social impacts. Here we assess the potential of market-based savanna burning greenhouse gas emissions abatement and allied carbon biosequestration projects to deliver compatible environmental and broader socio-economic benefits in a highly biodiverse north Australian setting. Drawing on extensive regional ecological knowledge of fire regime effects on fire-vulnerable taxa and communities, we compare three fire regime metrics (seasonal fire frequency, proportion of long-unburnt vegetation, fire patch-size distribution) over a 15-year period for three national parks with an indigenously (Aboriginal) owned and managed market-based emissions abatement enterprise. Our assessment indicates improved fire management outcomes under the emissions abatement program, and mostly little change or declining outcomes on the parks. We attribute improved outcomes and putative biodiversity benefits under the abatement program to enhanced strategic management made possible by the market-based mitigation arrangement. For these same sites we estimate quanta of carbon credits that could be delivered under realistic enhanced fire management practice, using currently available and developing accredited Australian savanna burning accounting methods. We conclude that, in appropriate situations, market-based savanna burning activities can provide transformative climate change mitigation, ecosystem health, and community benefits in northern Australia, and, despite significant challenges, potentially in other fire-prone savanna settings. PMID:26630453

Characterization of the Aerobic Oxidation of cis-Dichloroethene and Vinyl Chloride in Support of Bioremediation of Chloroethene-Contaminated Sites

DTIC Science & Technology

2004-11-05

perchloroethylene) PCR polymerase chain reaction SERDP Strategic Environmental Research and Development Program TCE trichloroethene VC vinyl chloride iv...from one of the enrichments, which was inoculated with activated carbon from a pump-and-treat plant (Dortmund, Germany) processing chloroethene...dependent enzyme activity in extracts from VC and ethene-grown cells 8 (Coleman and Spain, 2003a). PCR amplifications using primers targeted at

The Nature, Origin, and Importance of Carbonate-Bearing Samples at the Final Three Candidate Mars 2020 Landing Sites

NASA Astrophysics Data System (ADS)

Horgan, B.; Anderson, R. B.; Ruff, S. W.

2018-04-01

All three candidate Mars 2020 landing sites contain similar regional olivine/carbonate units, and a carbonate unit of possible lacustrine origin is also present at Jezero. Carbonates are critical for Mars Sample Return as records of climate and biosignatures.

Formation evaluation of gas hydrate-bearing marine sediments on the Blake Ridge with downhole geochemical log measurements

USGS Publications Warehouse

Collett, T.S.; Wendlandt, R.F.

2000-01-01

The analyses of downhole log data from Ocean Drilling Program (ODP) boreholes on the Blake Ridge at Sites 994, 995, and 997 indicate that the Schlumberger geochemical logging tool (GLT) may yield useful gas hydrate reservoir data. In neutron spectroscopy downhole logging, each element has a characteristic gamma ray that is emitted from a given neutron-element interaction. Specific elements can be identified by their characteristic gamma-ray signature, with the intensity of emission related to the atomic elemental concentration. By combining elemental yields from neutron spectroscopy logs, reservoir parameters including porosities, lithologies, formation fluid salinities, and hydrocarbon saturations (including gas hydrate) can be calculated. Carbon and oxygen elemental data from the GLT was used to determine gas hydrate saturations at all three sites (Sites 994, 995, and 997) drilled on the Blake Ridge during Leg 164. Detailed analyses of the carbon and oxygen content of various sediments and formation fluids were used to construct specialized carbon/oxygen ratio (COR) fan charts for a series of hypothetical gas hydrate accumulations. For more complex geologic systems, a modified version of the standard three-component COR hydrocarbon saturation equation was developed and used to calculate gas hydrate saturations on the Blake Ridge. The COR-calculated gas hydrate saturations (ranging from about 2% to 14% bulk volume gas hydrate) from the Blake Ridge compare favorably to the gas hydrate saturations derived from electrical resistivity log measurements.

Declining Atmospheric pCO2 During the Late Miocene and Early Pliocene: New Insights from Paired Alkenone and Coccolith Stable Isotope Barometry

NASA Astrophysics Data System (ADS)

Phelps, S. R.; Polissar, P. J.; deMenocal, P. B.; Swann, J. P.; Guo, M. Y.; Stoll, H. M.

2015-12-01

The relationship between atmospheric CO2 concentrations and climate is broadly understood for the Cenozoic era: warmer periods are associated with higher atmospheric carbon dioxide. This understanding is supported by atmospheric samples of the past 800,000 years from ice cores, which suggest CO2 levels play a key role in regulating global climate on glacial interglacial timescales as well. In this context, the late Miocene poses a challenge: sea-surface temperatures indicate substantial global warmth, though existing data suggest atmospheric CO2 concentrations were lower than pre-industrial values. Recent work using the stable carbon and oxygen isotopic composition of coccolith calcite has demonstrated these organisms began actively diverting inorganic carbon away from calcification and to the site of photosynthesis during the late Miocene. This process occurs in culture experiments in response to low aqueous CO2 concentrations, and suggests decreasing atmospheric pCO2 values during the late Miocene. Here we present new data from ODP Site 806 in the western equatorial Pacific Ocean that supports declining atmospheric CO2 across the late Miocene. Carbon isotope values of coccolith calcite from Site 806 demonstrate carbon limitation and re-allocation of inorganic carbon to photosynthesis starting between ~8 and 6 Ma. The timing of this limitation at Site 806 precedes shifts at other ODP sites, reflecting the higher mixed layer temperature and resultant lower CO2 solubility at Site 806. New measurements of carbon isotope values from alkenones at Site 806 show an increase in photosynthetic carbon fractionation (ɛp) accompanied the carbon limitation evident from coccolith calcite stable isotope data. While higher ɛp is typically interpreted as higher CO2 concentrations, at Site 806, our data suggest it reflects enhancement of chloroplast CO2 from active carbon transport by the coccolithophore algae in response to lower CO2 concentrations. Our new data from ODP Site 806 combined with previous published measurements suggests atmospheric CO2 values declined across the late Miocene and early Pliocene. This decline is coincident with decreasing ocean temperatures suggesting the fundamental relationship between atmospheric CO2 and climate can qualitatively explain late Miocene warmth.

Factors Influencing NO2 Adsorption/Reduction on Microporous Activated Carbon: Porosity vs. Surface Chemistry

PubMed Central

Ghouma, Imen; Limousy, Lionel; Bennici, Simona

2018-01-01

The textural properties and surface chemistry of different activated carbons, prepared by the chemical activation of olive stones, have been investigated in order to gain insight on the NO2 adsorption mechanism. The parent chemical activated carbon was prepared by the impregnation of olive stones in phosphoric acid followed by thermal carbonization. Then, the textural properties and surface chemistry were modified by chemical treatments including nitric acid, sodium hydroxide and/or a thermal treatment at 900 °C. The main properties of the parent and modified activated carbons were analyzed by N2-adsorption, scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR) techniques, in order to enlighten the modifications issued from the chemical and thermal treatments. The NO2 adsorption capacities of the different activated carbons were measured in fixed bed experiments under 500 ppmv NO2 concentrations at room temperature. Temperature programmed desorption (TPD) was applied after adsorption tests in order to quantify the amount of the physisorbed and chemisorbed NO2. The obtained results showed that the development of microporosity, the presence of oxygen-free sites, and the presence of basic surface groups are key factors for the efficient adsorption of NO2. PMID:29670008

The biodiversity cost of carbon sequestration in tropical savanna

PubMed Central

Abreu, Rodolfo C. R.; Hoffmann, William A.; Vasconcelos, Heraldo L.; Pilon, Natashi A.; Rossatto, Davi R.; Durigan, Giselda

2017-01-01

Tropical savannas have been increasingly viewed as an opportunity for carbon sequestration through fire suppression and afforestation, but insufficient attention has been given to the consequences for biodiversity. To evaluate the biodiversity costs of increasing carbon sequestration, we quantified changes in ecosystem carbon stocks and the associated changes in communities of plants and ants resulting from fire suppression in savannas of the Brazilian Cerrado, a global biodiversity hotspot. Fire suppression resulted in increased carbon stocks of 1.2 Mg ha−1 year−1 since 1986 but was associated with acute species loss. In sites fully encroached by forest, plant species richness declined by 27%, and ant richness declined by 35%. Richness of savanna specialists, the species most at risk of local extinction due to forest encroachment, declined by 67% for plants and 86% for ants. This loss highlights the important role of fire in maintaining biodiversity in tropical savannas, a role that is not reflected in current policies of fire suppression throughout the Brazilian Cerrado. In tropical grasslands and savannas throughout the tropics, carbon mitigation programs that promote forest cover cannot be assumed to provide net benefits for conservation. PMID:28875172

X-ray fluorescence results from IODP Expedition 355 sediments in Laxmi Basin, eastern Arabian Sea: Insights into late Miocene and Pleistocene carbonate production and burial and possible variations in monsoon intensit

NASA Astrophysics Data System (ADS)

Bowen, M. G.; Kulhanek, D. K.; Lyle, M. W.; Hahn, A.

2017-12-01

Variations in CaCO3 accumulation on the seafloor depend on a number of factors, including productivity of carbonate-producing organisms in the overlying water column, input of siliciclastic material from nearby continents, and changes in ocean chemistry. These factors are affected by variations in tectonics and climate. Here we use X-ray fluorescence (XRF) core scanning data to develop high-resolution chemical profiles calibrated with discrete samples to examine changes in carbonate production and burial in the eastern Arabian Sea. International Ocean Discovery Program (IODP) Expedition 355 cored two sites in the Indus Fan in Laxmi Basin. We scanned the Pleistocene composite sections from both sites at 2 cm resolution ( 150-300 year sampling resolution) using the Avaatech XRF core scanner at the IODP Gulf Coast Repository. In addition, we scanned a hemipelagic interval dated to the late Miocene ( 8 to 6 Ma) that spans the late Miocene climate transition to drier conditions globally, as documented by an expansion in C4 plants. The 2 cm scanning resolution represents 500 years between samples for the upper Miocene section. We used carbonate measurements on discrete samples to calibrate the XRF data, supplemented by analysis using a quantitative benchtop XRF at the University of Bremen. We find large variability in carbonate content in the Pleistocene and upper Miocene, varying from 15-80 wt%, with higher carbonate content correlating with lighter colored sediment. The aluminosilicate composition varies in part because of carbonate dilution but also because of changes in the source of clays and turbidites through the section. We also explore the use of chemical ratios to better understand the variations through the section. Changes in Ca/Fe (biogenic/terrestrial component) and Rb/Zr (fine/coarse grained) match well with visual observation of sediment composition in the cores. We can combine these with the oxygen isotope-derived age model for the Pleistocene section to examine orbital-scale variations in carbonate production and terrigenous input at the sites. We also explore proxies for precipitation (Ti/Ca) and weathering (Fe/K and Al/K) to elucidate changes in monsoon strength during the Pleistocene, although these results are preliminary.

Modeling the impact of hydraulic redistribution on the carbon flux and storages using CLM4.5 at four AmeriFlux Sites

NASA Astrophysics Data System (ADS)

Fu, C.; Wang, G.; Cardon, Z. G.

2015-12-01

Effects of hydraulic redistribution (HR) on the hydrological cycle and ecosystem dynamics have been demonstrated in the field, but few modeling studies have compared HR's influences on the carbon cycle in different ecosystems and climate regions. The soil moisture changes associated with HR could influence plant carbon gain via two mechanisms: (1) improved plant water status supporting stomatal opening, and/or (2) enhanced nutrient availability to plants caused by enhanced soil microbial activity. In this study, using a modified version of the Community Land Model with Century-based soil carbon pool kinetics that includes the "Ryel et al. 2002" scheme for hydraulic redistribution (HR), the influence of HR on the carbon flux and storage is investigated at four Ameriflux sites where HR was detected from soil moisture measurements. The study sites include a Douglas-fir site (US-Wrc) in Washington State with a mediterranean climate, a savanna site (US-SRM) in Arizona with a semi-arid climate, an oak/pine forest site (US-SCf) in Southern California with a mediterranean climate, and an evergreen broadleaf forest site (BR-Sa1) with tropical monsoon climate. Simulations revealed that HR tended to enhance plant growth at all four sites, and incorporating HR into CLM4.5 reduces the temporal fluctuation of soil carbon storage at all four sites. Simulations with HR can capture the net carbon exchange between ecosystem and the atmosphere (NEE) at the US-Wrc, US-SRM, and BR-Sa1 sites over the annual cycle. Incorporation of HR into CLM4.5 clearly improved the weekly and sub-daily NEE simulation during dry periods at US-SCf and BR-Sa1 site. HR-induced increase in Net Primary Productivity (NPP) at the US-Wrc and US-SRM sites was driven approximately equally by the two distinct mechanisms we investigated: increased stomatal conductance and increased nutrient availability to plants.

Using Digital Repeat Photography to Link Vegetative Phenology and Carbon Fluxes to Biotic and Abiotic Drivers in Three Semi-arid Systems (New Mexico, USA)

NASA Astrophysics Data System (ADS)

Hallmark, A.; Litvak, M. E.; Collins, S. L.

2015-12-01

Arid and semi-arid ecosystems account for over 45% of global land cover. While mean annual carbon uptake in these ecosystems is relatively low, aridlands collectively store a significant amount of carbon. There is high inter- and intra-annual variability of plant growth in aridlands, depending largely on the timing and size of rainfall events. This variation is also of great significance, as the variation in annual semi-aridland carbon uptake accounts for ~39% of the inter-annual variability of the global terrestrial carbon sink, the largest percentage of any land cover type. Although arid and semi-arid ecosystems are of global importance, they are understudied. To better understand the drivers and variability of carbon uptake in these critical ecosystems, we utilize a six-year record of digital images (45,000+ images), carbon flux and meteorological data, soil water content, and associated ecological measurements from three eddy covariance tower sites in central New Mexico. These sites include a Chihuahuan Desert/short-grass Plains grassland site, and post-fire successional grassland site, and a creosote-encroached shrubland site, each of which have unique species compositions, carbon fluxes, and reactions to disturbance and resource addition. All images used are co-registered and corrected for radial lens distortions (when necessary) and greenness indices (2GRBi, gcc, and/or NDVI) are calculated for each scene's overall "canopy" and for individual species and plant functional types therein. At all three sites, camera-derived greenness is correlated to measured carbon uptake with fine resolution (R2 up to 0.8), capturing temporal and spatial variation usually not seen in satellite-based imagery. At sites with lower LAI, species-specific ROI's were more correlated to the site's measured carbon flux across shorter time scales. Understanding the biota comprising each image and its contribution to changing scene greenness at different times of year can lead to more accurate carbon flux predictions in semi-arid systems, with species-specific biotic constraints (maximum growth rate, lifespan, and seasonality), growth parameters (light availability, VPD, soil water content, and temperature) as well as community-wide abiotic drivers considered.

Carbon Emission from Forest Fires on Scots Pine Logging Sites in the Angara Region of Central Siberia

NASA Astrophysics Data System (ADS)

Ivanova, G. A.; Conard, S. G.; McRae, D. J.; Kukavskaya, E. A.; Bogorodskaya, A. V.; Kovaleva, N. M.

2010-12-01

Wildfire and large-scale forest harvesting are the two major disturbances in the Russian boreal forests. Non-recovered logged sites total about a million hectares in Siberia. Logged sites are characterized by higher fire hazard than forest sites due to the presence of generally untreated logging slash (i.e., available fuel) which dries out much more rapidly compared to understory fuels. Moreover, most logging sites can be easily accessed by local population; this increases the risk for fire ignition. Fire impacts on the overstory trees, subcanopy woody layer, and ground vegetation biomass were estimated on 14 logged and unlogged comparison sites in the Lower Angara Region in 2009-2010 as part of the NASA-funded NEESPI project, The Influence of Changing Forestry Practices on the Effects of Wildfire and on Interactions Between Fire and Changing Climate in Central Siberia. Based on calculated fuel consumption, we estimated carbon emission from fires on both logged and unlogged burned sites. Carbon emission from fires on logged sites appeared to be twice that on unlogged sites. Soil respiration decreased on both site types after fires. This reduction may partially offset fire-produced carbon emissions. Carbon emissions from fire and post-fire ecosystem damage on logged sites are expected to increase under changing climate conditions and as a result of anticipated increases in future forest harvesting in Siberia.

A Coupled Epipelagic-Meso/Bathypelagic Particle Flux Model for the Bermuda Atlantic Time-series Station (BATS)/Oceanic Flux Program (OFP) Site

NASA Astrophysics Data System (ADS)

Glover, D. M.; Conte, M.

2002-12-01

Of considerable scientific interest is the role remineralization plays in the global carbon cycle. It is the ``biological pump'' that fixes carbon in the upper water column and exports it for long time periods to the deep ocean. From a global carbon cycle point-of-view, it is the processes that govern remineralization in the mid- to deep-ocean waters that provide the feedback to the biogeochemical carbon cycle. In this study we construct an ecosystem model that serves as a mechanistic link between euphotic processes and mesopelagic and bathypelagic processes. We then use this prognostic model to further our understanding of the unparalleled time-series of deep-water sediment traps (21+ years) at the Oceanic Flux Program (OFP) and the euphotic zone measurements (10+ years) at the Bermuda Atlantic Time-series Site (BATS). At the core of this mechanistic ecosystem model of the mesopelagic zone is a model that consists of an active feeding habit zooplankton, a passive feeding habit zooplankton, large detritus (sinks), small detritus (non-sinking), and a nutrient pool. As the detritus, the primary source of food, moves through the water column it is fed upon by the active/passive zooplankton pair and undergoes bacterially mediated remineralization into nutrients. The large detritus pool at depth gains material from the formation of fecal pellets from the passive and active zooplankton. Sloppy feeding habits of the active zooplankton contribute to the small detrital pool. Zooplankton mortality (both classes) also contribute directly to the large detritus pool. Aggregation and disaggregation transform detrital particles from one pool to the other and back again. The nutrients at each depth will gain from detrital remineralization and zooplankton excretion. The equations that model the active zooplankton, passive zooplankton, large detritus, small detritus, and nutrients will be reviewed, results shown and future model modifications discussed.

Preparation of Metal Nanowire Decorated Carbon Allotropes

NASA Technical Reports Server (NTRS)

Southward, Robin E. (Inventor); Ghose, Sayata (Inventor); Connell, John W. (Inventor); Delozier, Donavon Mark (Inventor); Smith, Joseph G. (Inventor); Watson, Kent A. (Inventor)

2014-01-01

In the method of embodiments of the invention, the metal seeded carbon allotropes are reacted in solution forming zero valent metallic nanowires at the seeded sites. A polymeric passivating reagent, which selects for anisotropic growth is also used in the reaction to facilitate nanowire formation. The resulting structure resembles a porcupine, where carbon allotropes have metallic wires of nanometer dimensions that emanate from the seed sites on the carbon allotrope. These sites are populated by nanowires having approximately the same diameter as the starting nanoparticle diameter.

Preparation of Metal Nanowire Decorated Carbon Allotropes

NASA Technical Reports Server (NTRS)

Smith, Jr., Joseph G. (Inventor); Ghose, Sayata (Inventor); Connell, John W. (Inventor); Southward, Robin E. (Inventor); Delozier, Donavon Mark (Inventor); Watson, Kent A. (Inventor)

2016-01-01

In the method of embodiments of the invention, the metal seeded carbon allotropes are reacted in solution forming zero valent metallic nanowires at the seeded sites. A polymeric passivating reagent, which selects for anisotropic growth is also used in the reaction to facilitate nanowire formation. The resulting structure resembles a porcupine, where carbon allotropes have metallic wires of nanometer dimensions that emanate from the seed sites on the carbon allotrope. These sites are populated by nanowires having approximately the same diameter as the starting nanoparticle diameter.

Explaining the inter-annual variability in the ecosystem fluxes of the Brasschaat Scots pine forest: 20 years of eddy flux and pollution monitoring

NASA Astrophysics Data System (ADS)

Horemans, Joanna; Roland, Marilyn; Janssens, Ivan; Ceulemans, Reinhart

2017-04-01

Because of their ecological and recreational value, the health of forest ecosystems and their response to global change and pollution are of high importance. At a number of EuroFlux and ICOS ecosystem sites in Europe - as the Brasschaat forest site - the measurements of ecosystem fluxes of carbon and other gases are combined with vertical profiles of air pollution within the framework of the ICP-Forest monitoring program. The Brasschaat forest is dominated by 80-year old Scots pines (Pinus sylvestris L.), and has a total area of about 150 ha. It is situated near an urban area in the Campine region of Flanders, Belgium and is characterized by a mean annual temperature of 9.8 °C and an annual rainfall of 830 mm. In this contribution we report on a long-term analysis (1996-2016) of the ecosystem carbon and water fluxes, the energy exchanges and the pollutant concentrations (ozone, NOx, NH3, SO2). Particular interest goes to the inter-annual variation of the carbon fluxes and the carbon allocation patterns. The impact of the long-term (aggregated) and the short-term variability in both the meteorological drivers and in the main tropospheric pollutants on the carbon fluxes is examined, as well as their mutual interactive effects and their potential memory effect. The effect of variability in the drivers during the phenological phases (seasonality) on the inter-annual variability of the fluxes is also examined. Basic statistical techniques as well as spectral analyses and data mining techniques are being used.

Sequestration of Carbon in Mycorrhizal Fungi Under Nitrogen Fertilization

NASA Astrophysics Data System (ADS)

Treseder, K. K.; Turner, K. M.

2005-12-01

Mycorrhizal fungi are root symbionts that facilitate plant uptake of soil nutrients in exchange for plant carbohydrates. They grow in almost every terrestrial ecosystem on earth, form relationships with about 80% of plant species, and receive 10 to 20% of the carbon fixed by their host plants. As such, they could potentially sequester a significant amount of carbon in ecosystems. We hypothesized that nitrogen fertilization would decrease carbon storage in mycorrhizal fungi, because plants should reduce investment of carbon in mycorrhizal fungi when nitrogen availability is high. We measured the abundance of two major groups of mycorrhizal fungi, arbuscular mycorrhizal (AM) and ectomycorrhizal (ECM) fungi, in control and nitrogen-fertilized plots within three boreal ecosystems of inland Alaska. The ecosystems represented different recovery stages following severe fire, and comprised a young site dominated by AM fungi, an old site dominated by ECM fungi, and an intermediate site co-dominated by both groups. Pools of mycorrhizal carbon included root-associated AM and ECM structures, soil-associated AM hyphae, and soil-associated glomalin. Glomalin is a glycoprotein produced only by AM fungi. It is present in the cell walls of AM hyphae, and then is deposited in the soil as the hyphae senesce. Nitrogen significantly altered total mycorrhizal carbon pools, but its effect varied by site (site * N interaction, P = 0.05). Under nitrogen fertilization, mycorrhizal carbon was reduced from 99 to 50 g C m2 in the youngest site, was increased from 124 to 203 g C m2 in the intermediate-aged site, and remained at 35 g C m2 in the oldest site. The changes in total mycorrhizal carbon stocks were driven mostly by changes in glomalin (site * N interaction, P = 0.05), and glomalin stocks were strongly correlated with AM hyphal abundance (P < 0.01). Nevertheless, it is not clear why AM hyphae responded differently to nitrogen fertilization in the different sites. Carbon stocks within root-associated AM structures increased significantly with nitrogen fertilization across all sites (P = 0.001), as did root-associated ECM structures (P = 0.021). The amount of carbon sequestered within living mycorrhizal structures (0.013 to 0.21 g m2), however, was modest compared to that of glomalin (91 g m2). We conclude that allocation by AM fungi to hyphal growth influenced the size of glomalin stocks in the soil, and that nitrogen fertilization altered investment in hyphal growth, with potential consequences for soil carbon storage. However, the nitrogen response was inconsistent among boreal forest ecosystems. An understanding of the mechanisms underlying this variation would improve our ability to predict ecosystem feedbacks to global change.

Carbon diffusion in bulk hcp zirconium: A multi-scale approach

NASA Astrophysics Data System (ADS)

Xu, Y.; Roques, J.; Domain, C.; Simoni, E.

2016-05-01

In the framework of the geological repository of the used fuel claddings of pressurized water reactor, carbon behavior in bulk zirconium is studied by periodic Density Functional Theory calculations. The C interstitial sites were investigated and it was found that there are two possible carbon interstitial sites: a distorted basal tetragonal site and an octahedral site. There are four types of possible atomic jumps between them. After calculating the migration energies, the attempt frequencies and the jump probabilities for each possible migration path, kinetic Monte Carlo (KMC) simulations were performed to simulate carbon diffusion at the macroscopic scale. The results show that carbon diffusion in pure Zr bulk is extremely limited at the storage temperature (50 °C). Since there are defects in Zr bulk, in a second step, the effect of atomic vacancy was studied and it was proved that vacancies cannot increase carbon diffusion.

Using local research sites to engage undergraduates in environmental science research

NASA Astrophysics Data System (ADS)

Varner, R. K.

2016-12-01

For the first time in their undergraduate experience, students in the University of New Hampshire's Techniques in Environmental Science course are immersed in learning approaches to scientific investigation that they can implement as part of their senior capstone research experience or other REU type programs. The course begins with an understanding of the value of note taking in the field and working collaboratively in groups. The students then embark upon a series of field experiences that include using both simple and complex tools for mapping elevation, species composition and above ground biomass estimates in a forest and wetland, carbon cycling through measurement of greenhouse gas exchange at both a wetland and at an organic dairy farm, assessing hydrology and water quality through both ground and surface water measurements at locations on campus, and finally analysis of atmospheric chemistry data collected locally. Over the course of a semester the students learn how to describe their methodology and the importance of their work concisely. Eventually the students are given instrumentation and a field site and learn to ask their own research question and develop their approach to answering it. This course model provides a foundation for students to pursue their capstone research experiences but also for understanding complex environmental questions such as the impact of land use change on water and air quality and carbon cycling and its role in our climate system. Students are provided a unique opportunity to address questions at field sites that are local and are part of larger research programs which allows for a larger context to place their work. This course has also been a framework for the NSF funded REU program- Northern Ecosystems Research for Undergraduates (EAR#1063037). Sallie's Fen, a wetland research site, is used as an initial field setting for students to learn techniques, build their ability to ask research questions and to plan research approaches, all skills required for them to be successful in their research in northern Sweden where they spend the next four weeks studying the impact of climate change in a region of thawing permafrost.

Reforestation Effects on Carbon Stocks in the Northeast USA: Interactions among Earthworms, Land-Use History and Soil Properties

NASA Astrophysics Data System (ADS)

Ross, D. S.; Görres, J. H.; Knowles, M.; Cogbill, C. V.

2017-12-01

Reforestation has occurred in many areas of the northeastern USA that were cleared for agriculture in the 1700s and 1800s. Net gains in carbon have occurred but these gains may be affected by earthworm invasions. All earthworm species common to New England were introduced from either Europe or, more recently, Asia. We have been monitoring 18 managed forest stands in Vermont to be able to determine long-term changes in carbon stores. In addition to measuring carbon with depth into the C horizon, we have documented land use history dating back to colonial times, determined earthworm species and density, measured tree species and site metrics, and measured a suite of soil chemical parameters. We also determined carbon distribution in soil microaggregates in a subset of sites. Prior land use in the 18 monitored plots included cultivation, pasture, farm woodlot and possibly iron mining. Higher earthworm species diversity correlated with reduced forest floor depth, higher mineral soil carbon, and greater stability (microaggregate-protected) of that carbon. Sites with the highest worm density and species richness had a history of more intense agricultural land use (although not all former agricultural sites had earthworms). There were also positive interactions between exchangeable calcium pools and earthworm density, and between elevation and carbon in the forest floor. With only 18 sites, it is difficult to establish statistically robust relationships. The effect of reforestation on present-day carbon stores appears to be a complex interaction of land-use history, site location, earthworm history and soil chemistry.

Low-Cost Options for Moderate Levels of Mercury Control

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sharon Sjostrom

2006-03-31

On March 15, 2005, EPA issued the Clean Air Mercury Rule, requiring phased-in reductions of mercury emissions from electric power generators. ADA-ES, Inc., with support from DOE/NETL and industry partners, is conducting evaluations of EPRI's TOXECON II{trademark} process and of high-temperature reagents and sorbents to determine the capabilities of sorbent/reagent injection, including activated carbon, for mercury control on different coals and air emissions control equipment configurations. DOE/NETL targets for total mercury removal are {ge}55% (lignite), {ge}65% (subbituminous), and {ge}80% (bituminous). Based on work done to date at various scales, meeting the removal targets appears feasible. However, work needs to progressmore » to more thoroughly document and test these promising technologies at full scale. This is the final site report for tests conducted at MidAmerican's Louisa Station, one of three sites evaluated in this DOE/NETL program. The other two sites in the program are MidAmerican's Council Bluff Station and Entergy's Independence Station. MidAmerican's Louisa Station burns Powder River Basin (PRB) coal and employs hot-side electrostatic precipitators with flue gas conditioning for particulate control. This part of the testing program evaluated the effect of reagents used in the existing flue gas conditioning on mercury removal.« less

Energy Use and Carbon Dioxide Emissions from Cropland Production in the United States, 1990-2004

DOE Data Explorer

Nelson, R. G.; Hellwinckel, C. H.; Brandt, C. C.; West, T. O.; De La Torre Ugarte, D. G.; Marland, G.

2008-01-01

These data represent energy use and fossil-fuel CO2 emissions associated with cropland production in the U.S. Energy use and emissions occurring on the farm are referred to as on-site energy and on-site emissions. Energy use and emissions associated with cropland production that occur off the farm (e.g., use of electricity, energy and emissions associated with fertilizer and pesticide production) are referred to as off-site energy and off-site emissions. The combination of on-site and off-site energy and carbon is referred to as total energy and total carbon, respectively.

Late Paleocene-middle Eocene benthic foraminifera on a Pacific seamount (Allison Guyot, ODP Site 865): Greenhouse climate and superimposed hyperthermal events

NASA Astrophysics Data System (ADS)

Arreguín-Rodríguez, Gabriela J.; Alegret, Laia; Thomas, Ellen

2016-03-01

We investigated the response of late Paleocene-middle Eocene (~60-37.5 Ma) benthic foraminiferal assemblages to long-term climate change and hyperthermal events including the Paleocene-Eocene Thermal Maximum (PETM) at Ocean Drilling Program (ODP) Site 865 on Allison Guyot, a seamount in the Mid-Pacific Mountains. Seamounts are isolated deep-sea environments where enhanced current systems interrupt bentho-pelagic coupling, and fossil assemblages from such settings have been little evaluated. Assemblages at Site 865 are diverse and dominated by cylindrical calcareous taxa with complex apertures, an extinct group which probably lived infaunally. Dominance of an infaunal morphogroup is unexpected in a highly oligotrophic setting, but these forms may have been shallow infaunal suspension feeders, which were ecologically successful on the current-swept seamount. The magnitude of the PETM extinction at Site 865 was similar to other sites globally, but lower diversity postextinction faunas at this location were affected by ocean acidification as well as changes in current regime, which might have led to increased nutrient supply through trophic focusing. A minor hyperthermal saw less severe effects of changes in current regime, with no evidence for carbonate dissolution. Although the relative abundance of infaunal benthic foraminifera has been used as a proxy for surface productivity through bentho-pelagic coupling, we argue that this proxy can be used only in the absence of changes in carbonate saturation and current-driven biophysical linking.

IRIS Toxicological Review and Summary Documents for ...

EPA Pesticide Factsheets

Carbon tetrachloride is a volatile haloalkane with a wide range of industrial and chemical applications. It is produced commercially from chlorination of a variety of low molecular weight hydrocarbons such as carbon disulfide, methanol, methane, propane, and ethylene dichloride. It is also produced by thermal chlorination in the production of tetrachloroethylene. Major uses of carbon tetrachloride have been in the recovery of tin from tin plating waste, in formulation of petrol additives and refrigerants, in metal degreasing and agricultural fumigants, in chlorination of organic compounds, in the production of semiconductors, in the reduction of fire hazard, as a solvent for rubber cement, and as a catalyst in polymer technology. Its production has been decreasing and it is no longer permitted in products intended for home use. Despite this ban, carbon tetrachloride has been detected at 314 hazardous waste sites. EPA's assessment of noncancer health effects and carcinogenic potential of carbon tetrachloride was last prepared and added to the IRIS database in 1991. The IRIS program is preparing an assessment that will incorporate health effects information available for carbon tetrachloride, and current risk assessment methods. The IRIS assessment for carbon tetrachloride will consist of a Toxicological Review and IRIS Summary. The Toxicological Review is a critical review of the physiochemical and toxicokinetic properties of a chemical, and its toxicity

Assessing FPAR Source and Parameter Optimization Scheme in Application of a Diagnostic Carbon Flux Model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Turner, D P; Ritts, W D; Wharton, S

2009-02-26

The combination of satellite remote sensing and carbon cycle models provides an opportunity for regional to global scale monitoring of terrestrial gross primary production, ecosystem respiration, and net ecosystem production. FPAR (the fraction of photosynthetically active radiation absorbed by the plant canopy) is a critical input to diagnostic models, however little is known about the relative effectiveness of FPAR products from different satellite sensors nor about the sensitivity of flux estimates to different parameterization approaches. In this study, we used multiyear observations of carbon flux at four eddy covariance flux tower sites within the conifer biome to evaluate these factors.more » FPAR products from the MODIS and SeaWiFS sensors, and the effects of single site vs. cross-site parameter optimization were tested with the CFLUX model. The SeaWiFs FPAR product showed greater dynamic range across sites and resulted in slightly reduced flux estimation errors relative to the MODIS product when using cross-site optimization. With site-specific parameter optimization, the flux model was effective in capturing seasonal and interannual variation in the carbon fluxes at these sites. The cross-site prediction errors were lower when using parameters from a cross-site optimization compared to parameter sets from optimization at single sites. These results support the practice of multisite optimization within a biome for parameterization of diagnostic carbon flux models.« less

Treated carbon fibers with improved performance for electrochemical and chemical applications

DOEpatents

Chu, X.; Kinoshita, Kimio

1999-02-23

A treated mesophase carbon fiber is disclosed having a high density of exposed edges on the fiber surface, and a method is described for making such a treated fiber. A carbon electrode is also described which is constructed from such treated mesophase carbon fibers. The resulting electrode, formed from such treated flexible carbon fibers, is characterized by a high density of active sites formed from such exposed edges, low corrosion, and good mechanical strength, and may be fabricated into various shapes. The treated mesophase carbon fibers of the invention are formed by first loading the surface of the mesophase carbon fiber with catalytic metal particles to form catalytic etch sites on a hard carbon shell of the fiber. The carbon fiber is then subject to an etch step wherein portions of the hard carbon shell or skin are selectively removed adjacent the catalytic metal particles adhering to the carbon shell. This exposes the underlying radial edges of the graphite-like layers within the carbon shell of the mesophase carbon fiber, which exposed radial edges then act as active sites of a carbon electrode subsequently formed from the treated mesophase carbon fibers. 14 figs.

Treated carbon fibers with improved performance for electrochemical and chemical applications

DOEpatents

Chu, Xi; Kinoshita, Kimio

1999-01-01

A treated mesophase carbon fiber is disclosed having a high density of exposed edges on the fiber surface, and a method of making such a treated fiber. A carbon electrode is also described which is constructed from such treated mesophase carbon fibers. The resulting electrode, formed from such treated flexible carbon fibers, is characterized by a high density of active sites formed from such exposed edges, low corrosion, and good mechanical strength, and may be fabricated into various shapes. The treated mesophase carbon fibers of the invention are formed by first loading the surface of the mesophase carbon fiber with catalytic metal particles to form catalytic etch sites on a hard carbon shell of the fiber. The carbon fiber is then subject to an etch step wherein portions of the hard carbon shell or skin are selectively removed adjacent the catalytic metal particles adhering to the carbon shell. This exposes the underlying radial edges of the graphite-like layers within the carbon shell of the mesophase carbon fiber, which exposed radial edges then act as active sites of a carbon electrode subsequently formed from the treated mesophase carbon fibers.

Distributed Energy Resources On-Site Optimization for Commercial Buildings with Electric and Thermal Storage Technologies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lacommare, Kristina S H; Stadler, Michael; Aki, Hirohisa

The addition of storage technologies such as flow batteries, conventional batteries, and heat storage can improve the economic as well as environmental attractiveness of on-site generation (e.g., PV, fuel cells, reciprocating engines or microturbines operating with or without CHP) and contribute to enhanced demand response. In order to examine the impact of storage technologies on demand response and carbon emissions, a microgrid's distributed energy resources (DER) adoption problem is formulated as a mixed-integer linear program that has the minimization of annual energy costs as its objective function. By implementing this approach in the General Algebraic Modeling System (GAMS), the problemmore » is solved for a given test year at representative customer sites, such as schools and nursing homes, to obtain not only the level of technology investment, but also the optimal hourly operating schedules. This paper focuses on analysis of storage technologies in DER optimization on a building level, with example applications for commercial buildings. Preliminary analysis indicates that storage technologies respond effectively to time-varying electricity prices, i.e., by charging batteries during periods of low electricity prices and discharging them during peak hours. The results also indicate that storage technologies significantly alter the residual load profile, which can contribute to lower carbon emissions depending on the test site, its load profile, and its adopted DER technologies.« less

ANNUAL RADIOACTIVE WASTE TANK INSPECTION PROGRAM- 2007

DOE Office of Scientific and Technical Information (OSTI.GOV)

West, B; Ruel Waltz, R

2008-06-05

Aqueous radioactive wastes from Savannah River Site (SRS) separations and vitrification processes are contained in large underground carbon steel tanks. The 2007 inspection program revealed that the structural integrity and waste confinement capability of the Savannah River Site waste tanks were maintained. A very small amount of material had seeped from Tank 12 from a previously identified leaksite. The material observed had dried on the tank wall and did not reach the annulus floor. A total of 5945 photographs were made and 1221 visual and video inspections were performed during 2007. Additionally, ultrasonic testing was performed on four Waste Tanksmore » (15, 36, 37 and 38) in accordance with approved inspection plans that met the requirements of WSRC-TR-2002- 00061, Revision 2 'In-Service Inspection Program for High Level Waste Tanks'. The Ultrasonic Testing (UT) In-Service Inspections (ISI) are documented in a separate report that is prepared by the ISI programmatic Level III UT Analyst. Tanks 15, 36, 37 and 38 are documented in 'Tank Inspection NDE Results for Fiscal Year 2007'; WSRC-TR-2007-00064.« less

Deciphering Equatorial Pacific Deep Sea Sediment Transport Regimes by Core-Log-Seismic Integration

NASA Astrophysics Data System (ADS)

Ortiz, E.; Tominaga, M.; Marcantonio, F.

2017-12-01

Investigating deep-sea sediment transportation and deposition regimes is a key to accurately understand implications from geological information recorded by pelagic sediments, e.g. climate signals. However, except for physical oceanographic particle trap experiments, geochemical analyses of in situsediments, and theoretical modeling of the relation between the bottom currents and sediment particle flux, it has remained a challenging task to document the movement of deep sea sediments, that takes place over time. We utilized high-resolution, multichannel reflection seismic data from the eastern equatorial Pacific region with drilling and logging results from two Integrated Ocean Drilling Program (IODP) sites, the Pacific Equatorial Age Transect (PEAT) 7 (Site U1337) and 8 (Site U1338), to characterize sediment transportation regimes on 18-24 Ma oceanic crust. Site U1337, constructed by a series of distinct abyssal hills and abyssal basins; Site U1338, located 570 km SE from Site U1337 site and constructed by a series of ridges, seamounts, and abyssal hills. These sites are of particular interest due to their proximity to the equatorial productivity zone, areas with high sedimentation rates and preservation of carbonate-bearing sediment that provide invaluable insights on equatorial Pacific ecosystems and carbon cycle. We integrate downhole geophysical logging data as well as geochemistry and physical properties measurements on recovered cores from IODP Sites U1337 and U1338 to comprehensively examine the mobility of deep-sea sediments and sediment diagenesis over times in a quasi-3D manner. We also examine 1100 km of high resolution underway seismic surveys from site survey lines in between PEAT 7 and 8 in order to investigate changes in sediment transportation between both sites. Integrating detailed seismic interpretations, high resolution core data, and 230Th flux measurements we aim to create a detailed chronological sedimentation and sediment diagenesis history of this area.

Carbon-cycle effects of differences in soil moisture and soil extracellular enzyme activity at sites representing different land-use histories in high-elevation Ecuadorian páramo landscapes

NASA Astrophysics Data System (ADS)

McKnight, J.; Harden, C. P.; Schaeffer, S. M.

2016-12-01

Ecuadorian páramo grasslands are important regional soil carbon sinks. In the páramo of the Mazar Wildlife Reserve, differences in soil carbon content among different types of land use may reflect changes in soil carbon-acquisition related microbial enzyme activity after land cover and soil moisture are altered; however, this hypothesis has not been tested explicitly for Ecuadorian páramos. This study used a fluorescence enzyme assay to assess the activities of four different extracellular enzymes representing carbon acquisition: α-glucosidase, β-glucosidase, β-D-cellulobiohydrolase, and β-xylosidase in Andean páramo soils. Acquisition activities were also measured for nitrogen (N-acetyl-β-glucosidase and leucine aminopeptidase) and phosphorus (phosphatase) to assess stoichiometric differences between land-uses, which can affect soil microbial activity related to carbon acquisition. Soils were analyzed from four land uses: native forest, grass páramo, recently burned grass páramo, and non-native pine plantation. Carbon acquisition activity was highest at the pine site (678 nmol h-1 g-1) and lowest at the recently burned páramo site (252 nmol h-1 g-1), indicating the lowest and highest available soil carbon, respectively. Carbon-acquisition EE activity was significantly higher at the grass páramo site (595 nmol h-1 g-1) than at the recently burned páramo and native forest sites. At the grass páramo site, a history of burning as a management strategy and high carbon-acquisition EE activity could indicate the presence of pyrogenic soil organic matter, which is more resistant to microbial decomposition. Soils at the native forest and both grassland sites were phosphorus limited, and soil at the pine site had higher nitrogen-acquisition activity, indicative of a shift to nitrogen-limited soil stoichiometric conditions. To our knowledge these are the first data reported for soil extracellular enzyme activities for Ecuadorian páramos.

Height-related growth declines in ponderosa pine are not due to carbon limitation.

PubMed

Sala, Anna; Hoch, Günter

2009-01-01

Decreased gas exchange as trees grow tall has been proposed to explain age-related growth declines in trees. We examined changes of mobile carbon stores (starch, sugars and lipids) with tree height in ponderosa pine (Pinus ponderosa) at two sites differing in water availability, and tested the following hypotheses: (1) carbon supply does not become increasingly limited as trees grow tall; rather, the concentration of mobile carbon compounds increases with tree height reflecting greater reductions of carbon sink activities relative to carbon assimilation; and (2) increases of stored mobile carbon compounds with tree height are greater in drier sites. Height-related growth reductions were associated with significant increases of non-structural carbohydrates (NSC) and lipid concentrations in all tissues in the upper canopy and of NSC in the bole. Lipid concentrations in the bole decreased with tree height, but such decrease is not necessarily inconsistent with non-limiting carbon supply in tall trees. Furthermore, we found stronger increases of mobile carbon stores with tree height at the dry site relative to the moist site. Our results provide first direct evidence that carbon supply does not limit growth in tall trees and that decreases of water availability might negatively impact growth processes more than net-photosynthesis.

Tree- Rings Link Climate and Carbon Storage in a Northern Mixed Hardwood Forest

NASA Astrophysics Data System (ADS)

Chiriboga, A.

2007-12-01

The terrestrial biosphere is a variable sink for atmospheric carbon dioxide. It is important to understand how carbon storage in trees is affected by natural climate variability to better characterize the sink. Quantifying the sensitivity of forest carbon storage to climate will improve carbon budgets and have implications for forest management practices. Here we explore how climate variability affects the ability of a northern mixed hardwood forest in Michigan to sequester atmospheric carbon dioxide in woody tissues. This site is ideal for studies of carbon sequestration; The University of Michigan Biological Station is an Ameriflux site, and has detailed meteorological and biometric records, as well as CO2 flux data. We have produced an 82- year aspen (Populus grandidentata) tree-ring chronology for this site, and measured ring widths at several heights up the bole. These measurements were used to estimate annual wood volume, which represents carbon allocated to aboveground carbon stores. Standard dendroclimatological techniques are used to identify environmental factors (e.g. temperature or precipitation) that drive tree-ring increment variability in the past century, and therefore annual carbon storage in this forest. Preliminary results show that marker years within the tree- ring chronology correspond with years that have cold spring temperatures. This suggests that trees at this site are temperature sensitive.

Terrestrial Carbon Sequestration: Analysis of Terrestrial Carbon Sequestration at Three Contaminated Sites Remediated and Revitalized with Soil Amendments

EPA Pesticide Factsheets

This paper provides EPA's analysis of the data to determine carbon sequestration rates at three diverse sites that differ in geography/location, weather, soil properties, type of contamination, and age.

CARBON MONOXIDE FLUXES OF DIFFERENT SOIL LAYERS IN UPLAND CANADIAN BOREAL FORESTS

EPA Science Inventory

Dark or low-light carbon monoxide fluxes at upland Canadian boreal forest sites were measured on-site with static chambers and with a laboratory incubation technique using cores from different depths at the same sites. Three different upland black spruce sites, burned in 1987,199...

AmeriFlux US-Skr Shark River Slough (Tower SRS-6) Everglades

DOE Data Explorer

Barr, Jordan G. [Everglades National Park; Fuentes, Jose [Pennsylvania State University

2016-01-01

This is the AmeriFlux version of the carbon flux data for the site US-Skr Shark River Slough (Tower SRS-6) Everglades. Site Description - The Florida Everglades Shark River Slough Mangrove Forest site is located along the Shark River in the western region of Everglades National Park. Also referred to as site SRS6 of the Florida Coastal Everglades LTER program, freshwater in the mangrove riverine floods the forest floor under a meter of water twice per day. Transgressive discharge of freshwater from the Shark river follows annual rainfall distributions between the wet and dry seasons. Hurricane Wilma struck the site in October of 2005 causing significant damage. The tower was offline until the following October in order to continue temporally consistent measurements. In post-hurricane conditions, ecosystem respiration rates and solar irradiance transfer increased. 2007- 2008 measurements indicate that these factors led to an decline in both annual -NEE and daily NEE from pre-hurricane conditions in 2004-2005.

Desert Test Site Uniformity Analysis

NASA Technical Reports Server (NTRS)

Kerola, Dana X.; Bruegge, Carol J.

2009-01-01

Desert test sites such as Railroad Valley (RRV) Nevada, Egypt-1, and Libya-4 are commonly targeted to assess the on-orbit radiometric performance of sensors. Railroad Valley is used for vicarious calibration experiments, where a field-team makes ground measurements to produce accurate estimates of top-of-atmosphere (TOA) radiances. The Sahara desert test sites are not instrumented, but provide a stable target that can be used for sensor cross-comparisons, or for stability monitoring of a single sensor. These sites are of interest to NASA's Atmospheric Carbon Observation from Space (ACOS) and JAXA's Greenhouse Gas Observation SATellite (GOSAT) programs. This study assesses the utility of these three test sites to the ACOS and GOSAT calibration teams. To simulate errors in sensor-measured radiance with pointing errors, simulated data have been created using MODIS Aqua data. MODIS data are further utilized to validate the campaign data acquired from June 22 through July 5, 2009. The first GOSAT vicarious calibration experiment was conducted during this timeframe.

BOREAS TGB-12 Isotropic Carbon Dioxide Data over the NSA

NASA Technical Reports Server (NTRS)

Trumbore, Susan; Hall, Forrest G. (Editor); Sundquist, Eric; Winston, Greg; Conrad, Sara K. (Editor)

2000-01-01

The BOREAS TGB-12 team made measurements of soil carbon inventories, carbon concentration in soil gases, and rates of soil respiration at several sites to estimate the rates of carbon accumulation and turnover in each of the major vegetation types. This data set contains information on the carbon isotopic content of carbon dioxide sampled from soils in the NSA-OBS, NSA-YJP, and NSA-OJP sites. Data were collected from 14-Nov-1993 to 10-Oct-1996. The data are stored in tabular ASCII files.

Characteristics of gas hydrate-bearing sediments of the northern South China Sea: insight into past hydrate episodic dissociations and intensities of seepage

NASA Astrophysics Data System (ADS)

Chen, F.; Su, X.; Zhou, Y.; Zhang, G.; Zhuang, C.; Lu, H.

2016-12-01

In 2013 the second China's major gas hydrate expedition, GMGS2, cored and recovered abundant gas hydrates at five sites, which were located in the South China Sea.Site GMGS08 (95m long) contained two gas hydrate intervals and five authigenic carbonate intervals. We analyzed carbon and oxygen isotopes of authigenic carbonates and foraminifera shells in sediments recovered at this site, in order to understanding of features of hydrate-bearing sediments and timing of gas hydrate dissociation and methane seepage at this site. An age of younger than 0.27 Ma was estimated for the 95 m sedimentary sequences at Site GMGS08. A detailed age model was further established by employing of U/Th and AMS14C dating of authigenic carbonates and seep bivalve fragments. These carbonates are featured by 13C-depleted (with a range from -38.9‰ to 56.7‰ δ13C) and positive δ18O (from 2.94‰ to 5.66‰ δ18O) values. A further analysis indicated the formation of carbonates were correlated to methane seepages derived from gas hydrate dissociation. Subsequently, these five authigenic carbonates intervals were seen as five hydrate episodic dissociation events since last 0.27Ma at this site. The most significant event during the period of 0.11 Ma to 0.13 Ma were account for the formation of thick authigenic carbonate (with the lowest -56.8‰ δ13C value) platform on paleo-seafloor at this site. The upmost authigenic carbonates interval is just overlying on the top of the upper gas hydrate occurrence zone, and it represents the latest methane seepage event with an age of 26ka to 36ka. Well correlated to these five events, it existed five intervals with strongly 13C-depleted carbon (-15.85‰ PDB) of foraminifera shells both from benthic and planktonic. The anomalous δ13C depletion records of planktonic G. ruber shells should be caused by formation of secondary authigenic carbonates on the shells, which were derived from the anaerobic oxidation of methane (AOM). The analyses on carbonate samples indicated varied intensity of methane flux in each event. The most intensive methane venting flux occurred during the event of 0.11 Ma to 0.13 Ma, which is correlated to a warm and relative high sea level period of MIS stage 5. These records obtained at Site GMGS08 implied much complicated causes for formation of authigenic carbonates and gas hydrate episodic dissociation.

Diagenesis in tephra-rich sediments from the Lesser Antilles Volcanic Arc: Pore fluid constraints

NASA Astrophysics Data System (ADS)

Murray, Natalie A.; McManus, James; Palmer, Martin R.; Haley, Brian; Manners, Hayley

2018-05-01

We present sediment pore fluid and sediment solid phase results obtained during IODP Expedition 340 from seven sites located within the Grenada Basin of the southern Lesser Antilles Volcanic Arc region. These sites are generally characterized as being low in organic carbon content and rich in calcium carbonate and volcanogenic material. In addition to the typical reactions related to organic matter diagenesis, pore fluid chemistry indicates that the diagenetic reactions fall within two broad categories; (1) reactions related to chemical exchange with volcanogenic material and (2) reactions related to carbonate dissolution, precipitation, or recrystallization. For locations dominated by reaction with volcanogenic material, these sites exhibit increases in dissolved Ca with coeval decreases in Mg. We interpret this behavior as being driven by sediment-water exchange reactions from the alteration of volcanic material that is dispersed throughout the sediment package, which likely result in formation of Mg-rich secondary authigenic clays. In contrast to this behavior, sediment sequences that exhibit decreases in Ca, Mg, Mn, and Sr with depth suggest that carbonate precipitation is an active diagenetic process affecting solute distributions. The distributions of pore fluid 87Sr/86Sr reflect these competitive diagenetic reactions between volcanic material and carbonate, which are inferred by the major cation distributions. From one site where we have solid phase 87Sr/86Sr (site U1396), the carbonate fraction is found to be generally consistent with the contemporaneous seawater isotope values. However, the 87Sr/86Sr of the non-carbonate fraction ranges from 0.7074 to 0.7052, and these values likely represent a mixture of local arc volcanic sources and trans-Atlantic eolian sources. Even at this site where there is clear evidence for diagenesis of volcanogenic material, carbonate diagenesis appears to buffer pore fluid 87Sr/86Sr from the larger changes that might be expected given the high abundance of tephra in these sediments. Part of this carbonate buffering, at this site as well as throughout the region, derives from the fact that the Sr concentration in the non-carbonate fraction is generally low (<200 ppm), whereas the carbonate fraction has Sr concentrations approaching ∼1000 ppm.

Old and Not-So-Old: Examining Changes in Forest Ecosystem Carbon Exchange With Stand Age in the Upper Midwest U.S.

NASA Astrophysics Data System (ADS)

Desai, A. R.; Cook, B.; Davis, K. J.; Bolstad, P.; Carey, E.; Martin, J.; Kreller, L.; Wang, W.

2003-12-01

Forest stand age is an important determinant of ecosystem carbon uptake. Though there are biometric measurements and ecological models for forests of all ages, there are few stand-scale eddy-flux measurements of net carbon exchange in older forests, though the number is increasing. In order to scale carbon fluxes from sites to regions, where stands of multiple ages may exist, it is necessary to measure to the effect of stand age on carbon exchange. Measuring the effect of stand age on carbon exchange is also necessary when trying to predict future or past carbon exchange (scaling across time). Many researchers have noted that site disturbance history is the fundamental factor in determining carbon uptake by forests over time scales of decades to centuries. The 8,500 ha Sylvania Wilderness in the upper peninsula of Michigan is one of several large tracts of old-growth forest in the Midwest. Trees range from 0-350 years old. Primary species are sugar maple, eastern hemlock and yellow birch. Catastrophic disturbance is rare. A research plot near the wilderness was established in late 2001 to measure the net ecosystem exchange (NEE) of carbon and water using eddy-flux, component flux and biometric methods. This site is part of the Chequamegon Ecosystem Atmosphere Study (ChEAS, http://cheas.psu.edu), a loose affiliation of researchers conducting carbon and water research in northern Wisconsin and upper Michigan. Another similar research plot within ChEAS and not far from Sylvania is the Willow Creek mature uplands site. This forest is about 70 years old and the primary species are sugar maple, basswood and green ash. The site had presettlement old-growth vegetation similar to what is currently seen in the Sylvania Wilderness. Thus, the carbon exchange seen at Sylvania may be representative of carbon uptake at Willow Creek had it not been logged in the early 20th century, and may also represent the future (or past) carbon uptake for similar forests in northern Wisconsin/upper Michigan. Initial results from 2002 show that both Sylvania and Willow Creek were sinks of carbon, though the annual NEE of carbon at Sylvania was only -72 gC/m2/yr, while it was -447 gC/m2/yr at Willow Creek. The lack of carbon balance at the old-growth site may be caused by growth enhancement due to carbon/nutrient fertilization, climate warming, or recent local-scale disturbances. A standard moving-window Arrenhius-style temperature-nighttime NEE relationship was used to separate total ecosystem respiration from gross ecosystem production (GEP). Total annual respiration was much greater at Sylvania (965 gC/m2/yr) than Willow Creek (667 gC/m2/yr), while GEP at Sylvania (1045 gC/m2/yr) was only slightly smaller than Willow Creek (1136 gC/m2/yr). The largest differences in respiration between the two sites occurred in early summer, whereas the largest difference in GEP occurred in late summer. The observed differences between the two sites matches well with theory. Ecosystem respiration is expected to increase steadily with stand age while gross ecosystem production is expected to increase rapidly as new species are established, but eventually level off. Current ongoing component flux measurements will help determine the mechanisms for the observed differences in carbon uptake at the two sites and provide insight on the causes of declining carbon exchange with stand age.

Carbon and Water Exchanges in a Chronosequence of Temperate White Pine Forest

NASA Astrophysics Data System (ADS)

Arain, M.; Restrepo, N.; Pejam, M.; Khomik, M.

2003-12-01

Quantification of carbon sink or source strengths of temperate forest ecosystems, growing in northern mid-latitudes, is essential to resolve uncertainties in carbon balance of the world's terrestrial ecosystems. Long-term flux measurements are needed to quantify seasonal and annual variability of carbon and water exchanges from these ecosystems and to relate the variability to environmental and physiological factors. Such long-term measurements are of particular interest for different stand developmental stages. An understanding of environmental control factors is necessary to improve predictive capabilities of terrestrial carbon and water cycles. A long-term year-round measurement program has been initiated to observe energy, water vapour, and carbon dioxide fluxes in a chronosequence of white pine (Pinus Strobus) forests in southeastern Canada. White pine is an important species in the North American landscape because of its ability to adapt to dry environments. White pine efficiently grows on coarse and sandy soils, where other deciduous and conifer species cannot survive. Generally, it is the first woody species to flourish after disturbances such as fire and clearing. The climate at the study site is temperate, with a mean annual temperature of 8 degree C and a mean annual precipitation of about 800 mm. The growing season is one of the longest in Canada, with at least 150 frost-free days. Measurements at the site began in June 2002 and are continuing at present. Flux measurements at the 60 year old stand are being made using a close-path eddy covariance (EC) system, while fluxes at the three younger stands (30, 15 and 1 year old) are being measured over 10 to 20 day periods using a roving open-path EC system Soil respiration is being measured every 2-weeks across 50-m transects at all four sites using a mobile chamber system (LI-COR 6400). The mature stand was a sink of carbon with annual NEP value of 140 g C m-2 from June 2002 to May 2003. Gross ecosystem productivity (GEP) and ecosystem respiration (R) for 2002-03 were 1290 and 1150 g C m-2, respectively. A processed-based carbon simulation model was created by incorporating canopy physiology (photosynthesis - sunlit and shaded leaf, conductance), plant phenology (leaf out, senescence), and carbon balance (plant and soil respiration, ecosystem productivity) algorithms in the Canadian Land Surface Scheme. In this study, we compare observed and simulated energy, water vapour, and carbon dioxide fluxes of the mature stand with those of the younger stands. This comparison will help to resolve scaling issues for estimating water and carbon budgets from stands to regions.

Structural evidence for a copper-bound carbonate intermediate in the peroxidase and dismutase activities of superoxide dismutase.

PubMed

Strange, Richard W; Hough, Michael A; Antonyuk, Svetlana V; Hasnain, S Samar

2012-01-01

Copper-zinc superoxide dismutase (SOD) is of fundamental importance to our understanding of oxidative damage. Its primary function is catalysing the dismutation of superoxide to O(2) and H(2)O(2). SOD also reacts with H(2)O(2), leading to the formation of a strong copper-bound oxidant species that can either inactivate the enzyme or oxidise other substrates. In the presence of bicarbonate (or CO(2)) and H(2)O(2), this peroxidase activity is enhanced and produces the carbonate radical. This freely diffusible reactive oxygen species is proposed as the agent for oxidation of large substrates that are too bulky to enter the active site. Here, we provide direct structural evidence, from a 2.15 Å resolution crystal structure, of (bi)carbonate captured at the active site of reduced SOD, consistent with the view that a bound carbonate intermediate could be formed, producing a diffusible carbonate radical upon reoxidation of copper. The bound carbonate blocks direct access of substrates to Cu(I), suggesting that an adjunct to the accepted mechanism of SOD catalysed dismutation of superoxide operates, with Cu(I) oxidation by superoxide being driven via a proton-coupled electron transfer mechanism involving the bound carbonate rather than the solvent. Carbonate is captured in a different site when SOD is oxidised, being located in the active site channel adjacent to the catalytically important Arg143. This is the probable route of diffusion from the active site following reoxidation of the copper. In this position, the carbonate is poised for re-entry into the active site and binding to the reduced copper.

Structural Evidence for a Copper-Bound Carbonate Intermediate in the Peroxidase and Dismutase Activities of Superoxide Dismutase

PubMed Central

Strange, Richard W.; Hough, Michael A.; Antonyuk, Svetlana V.; Hasnain, S. Samar

2012-01-01

Copper-zinc superoxide dismutase (SOD) is of fundamental importance to our understanding of oxidative damage. Its primary function is catalysing the dismutation of superoxide to O2 and H2O2. SOD also reacts with H2O2, leading to the formation of a strong copper-bound oxidant species that can either inactivate the enzyme or oxidise other substrates. In the presence of bicarbonate (or CO2) and H2O2, this peroxidase activity is enhanced and produces the carbonate radical. This freely diffusible reactive oxygen species is proposed as the agent for oxidation of large substrates that are too bulky to enter the active site. Here, we provide direct structural evidence, from a 2.15 Å resolution crystal structure, of (bi)carbonate captured at the active site of reduced SOD, consistent with the view that a bound carbonate intermediate could be formed, producing a diffusible carbonate radical upon reoxidation of copper. The bound carbonate blocks direct access of substrates to Cu(I), suggesting that an adjunct to the accepted mechanism of SOD catalysed dismutation of superoxide operates, with Cu(I) oxidation by superoxide being driven via a proton-coupled electron transfer mechanism involving the bound carbonate rather than the solvent. Carbonate is captured in a different site when SOD is oxidised, being located in the active site channel adjacent to the catalytically important Arg143. This is the probable route of diffusion from the active site following reoxidation of the copper. In this position, the carbonate is poised for re-entry into the active site and binding to the reduced copper. PMID:22984565

Carbon and nitrogen isotope variations in tree-rings as records of perturbations in regional carbon and nitrogen cycles.

PubMed

Bukata, Andrew R; Kyser, T Kurtis

2007-02-15

Increasing anthropogenic pollution from urban centers and fossil fuel combustion can impact the carbon and nitrogen cycles in forests. To assess the impact of twentieth century anthropogenic pollution on forested system carbon and nitrogen cycles, variations in the carbon and nitrogen isotopic compositions of tree-rings were measured. Individual annual growth rings in trees from six sites across Ontario and one in New Brunswick, Canada were used to develop site chronologies of tree-ring delta 15N and delta 13C values. Tree-ring 615N values were approximately 0.5% per hundred higher and correlated with contemporaneous foliar samples from the same tree, but not with delta 15N values of soil samples. Temporal trends in carbon and nitrogen isotopic compositions of these tree-rings are consistent with increasing anthropogenic influence on both the carbon and nitrogen cycles since 1945. Tree-ring delta 13C values and delta 15N values are correlated at both remote and urban-proximal sites, with delta 15N values decreasing since 1945 and converging on 1% per hundred at urban-proximal sites and decreasing but not converging on a single delta 15N value in remote sites. These results indicate that temporal trends in tree-ring nitrogen and carbon isotopic compositions record the regional extent of pollution.

DOE Office of Scientific and Technical Information (OSTI.GOV)

B.E. Law; D. Turner; M. Goeckede

GOAL: To develop and apply an approach to quantify and understand the regional carbon balance of the west coast states for the North American Carbon Program. OBJECTIVE: As an element of NACP research, the proposed investigation is a two pronged approach that derives and evaluates a regional carbon (C) budget for Oregon, Washington, and California. Objectives are (1) Use multiple data sources, including AmeriFlux data, inventories, and multispectral remote sensing data to investigate trends in carbon storage and exchanges of CO2 and water with variation in climate and disturbance history; (2) Develop and apply regional modeling that relies on thesemore » multiple data sources to reduce uncertainty in spatial estimates of carbon storage and NEP, and relative contributions of terrestrial ecosystems and anthropogenic emissions to atmospheric CO2 in the region; (3) Model terrestrial carbon processes across the region, using the Biome-BGC terrestrial ecosystem model, and an atmospheric inverse modeling approach to estimate variation in rate and timing of terrestrial uptake and feedbacks to the atmosphere in response to climate and disturbance. APPROACH: In performing the regional analysis, the research plan for the bottom-up approach uses a nested hierarchy of observations that include AmeriFlux data (i.e., net ecosystem exchange (NEE) from eddy covariance and associated biometric data), intermediate intensity inventories from an extended plot array partially developed from the PI's previous research, Forest Service FIA and CVS inventory data, time since disturbance, disturbance type, and cover type from Landsat developed in this study, and productivity estimates from MODIS algorithms. The BIOME-BGC model is used to integrate information from these sources and quantify C balance across the region. The inverse modeling approach assimilates flux data from AmeriFlux sites, high precision CO2 concentration data from AmeriFlux towers and four new calibrated CO2 sites, reanalysis meteorology and various remote sensing products to generate statewide estimates of biosphere carbon exchange from the atmospheric point of view.« less

Re-evaluation of forest biomass carbon stocks and lessons from the world's most carbon-dense forests.

PubMed

Keith, Heather; Mackey, Brendan G; Lindenmayer, David B

2009-07-14

From analysis of published global site biomass data (n = 136) from primary forests, we discovered (i) the world's highest known total biomass carbon density (living plus dead) of 1,867 tonnes carbon per ha (average value from 13 sites) occurs in Australian temperate moist Eucalyptus regnans forests, and (ii) average values of the global site biomass data were higher for sampled temperate moist forests (n = 44) than for sampled tropical (n = 36) and boreal (n = 52) forests (n is number of sites per forest biome). Spatially averaged Intergovernmental Panel on Climate Change biome default values are lower than our average site values for temperate moist forests, because the temperate biome contains a diversity of forest ecosystem types that support a range of mature carbon stocks or have a long land-use history with reduced carbon stocks. We describe a framework for identifying forests important for carbon storage based on the factors that account for high biomass carbon densities, including (i) relatively cool temperatures and moderately high precipitation producing rates of fast growth but slow decomposition, and (ii) older forests that are often multiaged and multilayered and have experienced minimal human disturbance. Our results are relevant to negotiations under the United Nations Framework Convention on Climate Change regarding forest conservation, management, and restoration. Conserving forests with large stocks of biomass from deforestation and degradation avoids significant carbon emissions to the atmosphere, irrespective of the source country, and should be among allowable mitigation activities. Similarly, management that allows restoration of a forest's carbon sequestration potential also should be recognized.

Re-evaluation of forest biomass carbon stocks and lessons from the world's most carbon-dense forests

PubMed Central

Keith, Heather; Mackey, Brendan G.; Lindenmayer, David B.

2009-01-01

From analysis of published global site biomass data (n = 136) from primary forests, we discovered (i) the world's highest known total biomass carbon density (living plus dead) of 1,867 tonnes carbon per ha (average value from 13 sites) occurs in Australian temperate moist Eucalyptus regnans forests, and (ii) average values of the global site biomass data were higher for sampled temperate moist forests (n = 44) than for sampled tropical (n = 36) and boreal (n = 52) forests (n is number of sites per forest biome). Spatially averaged Intergovernmental Panel on Climate Change biome default values are lower than our average site values for temperate moist forests, because the temperate biome contains a diversity of forest ecosystem types that support a range of mature carbon stocks or have a long land-use history with reduced carbon stocks. We describe a framework for identifying forests important for carbon storage based on the factors that account for high biomass carbon densities, including (i) relatively cool temperatures and moderately high precipitation producing rates of fast growth but slow decomposition, and (ii) older forests that are often multiaged and multilayered and have experienced minimal human disturbance. Our results are relevant to negotiations under the United Nations Framework Convention on Climate Change regarding forest conservation, management, and restoration. Conserving forests with large stocks of biomass from deforestation and degradation avoids significant carbon emissions to the atmosphere, irrespective of the source country, and should be among allowable mitigation activities. Similarly, management that allows restoration of a forest's carbon sequestration potential also should be recognized. PMID:19553199

Water-quality, bed-sediment, and biological data (October 2015 through September 2016) and statistical summaries of data for streams in the Clark Fork Basin, Montana

USGS Publications Warehouse

Dodge, Kent A.; Hornberger, Michelle I.; Turner, Matthew A.

2018-03-30

Water, bed sediment, and biota were sampled in selected streams from Butte to near Missoula, Montana, as part of a monitoring program in the upper Clark Fork Basin of western Montana. The sampling program was led by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, to characterize aquatic resources in the Clark Fork Basin, with emphasis on trace elements associated with historic mining and smelting activities. Sampling sites were on the Clark Fork and selected tributaries. Water samples were collected periodically at 20 sites from October 2015 through September 2016. Bed-sediment and biota samples were collected once at 13 sites during August 2016.This report presents the analytical results and quality-assurance data for water-quality, bed-sediment, and biota samples collected at sites from October 2015 through September 2016. Water-quality data include concentrations of selected major ions, trace elements, and suspended sediment. Samples for analysis of turbidity were collected at 13 sites, whereas samples for analysis of dissolved organic carbon were collected at 10 sites. In addition, samples for analysis of nitrogen (nitrate plus nitrite) were collected at two sites. Daily values of mean suspended-sediment concentration and suspended-sediment discharge were determined for three sites. Seasonal daily values of turbidity were determined for five sites. Bed-sediment data include trace-element concentrations in the fine-grained (less than 0.063 millimeter) fraction. Biological data include trace-element concentrations in whole-body tissue of aquatic benthic insects. Statistical summaries of water-quality, bed-sediment, and biological data for sites in the upper Clark Fork Basin are provided for the period of record.

AmeriFlux US-Fmf Flagstaff - Managed Forest

DOE Data Explorer

Dor, Sabina [Northern Arizona Univ., Flagstaff, AZ (United States); Kolb, Thomas [Northern Arizona Univ., Flagstaff, AZ (United States)

2016-01-01

This is the AmeriFlux version of the carbon flux data for the site US-Fmf Flagstaff - Managed Forest. Site Description - Ponderosa pine forest subject to thinning in September 2006. Project webpage http://nau.edu/CEFNS/Forestry/Research/Carbon-Flux/Sites/

The C6 Program: Monitoring Climatic Changes in Canyons and Caves Involving Scientific Istitutions, Environmental NGOs and Mountain Sport Associations

NASA Astrophysics Data System (ADS)

di Pietro, R.; Casamento, G.; Interlandi, M.; Madonia, P.

2007-12-01

The acronym "C6" means "Climatic Changes and Carbon Cycle in Canyons and Caves". The project was born in 2005, joining under the scientific supervision of the Palermo branch of the Istituto Nazionale di Geofisica e Vulcanologia two different programs both active since 1999; the first was due to the initiative of the Italian Canyoning Association, a no-profit association aimed to the diffusion of the canyoning sport practise in Italy, the second one, developed by the NGO Legambiente Sicilia and funded by the Regione Siciliana-Assessorato Territorio e Ambiente (Sicilian Regional Government, Territorial and Environmental Department), managing the natural reserves of Santa Ninfa, Carburangeli and Sant'Angelo Muxaro caves (Sicily), was focused to verify the existence of a possible environmental negative feedback of human fruition. In 2005 the Royal Society for the Conservation of Nature of Jordan joined the program, and a new site was established inside the Shagher Daghleh Canyon in the Wadi Dana Reserve. In October 2006 the Caver Federation of Bosnia Herzegovina joined the C6 program and another observational site was instituted into a cave close to Sarajevo. Preliminary data acquired indicate how canyons play a very important role in biodiversity preservation in arid and semi-arid environments, whereas caves are extraordinary natural laboratories for the study of carbon dioxide partition between atmosphere and lithosphere, of the effect of rain dynamic on the underground aquifer recharge and, last but not least, of the monitoring of climatic changes. The success of the initiative is based on the very different nature of the co-participants. Caver and canyoning associations guarantee the safe accessibility to difficult environments, like canyons and caves. The selection as measuring sites of natural reserves managed by NGOs, whose activity is essentially based on volunteers, ensure on one hand their environmental stability on a long term perspective, on the other hand very low costs for the personnel involved in the operations. Both the factors are very important for long-term ecological researches, where continuity of data acquisition is fundamental. Finally, the huge numbers of non-scientific personnel involved in the program ensures a wide diffusion of a correct scientific approach to the themes of the climatic changes, very often presented to the public under a wrong dramatic and spectacular light.

Uses of Single Photon Lidar (SPL) in the Monitoring Reporting and Verification of afforestation and carbon offset projects

NASA Astrophysics Data System (ADS)

Dolan, K. A.; DeCola, P.; Dubayah, R.; Huang, W.; Hurtt, G. C.; Tang, H.; Whitehurst, A.

2017-12-01

As societies move towards increased valuation of carbon through markets, regulations, and voluntary agreements the need to develop comprehensive, traceable and continuous, carbon monitoring, reporting and verification (MRV) systems has risen in priority locally to globally. Future landuse decisions, to conserve, develop or reforest, rests on the perceived valuation of anthropogenic and ecological benefits, as well as our ability to measure, report, verify, and "project" those benefits. Two carbon markets in the US, the Regional Green House Gas Initiative (RGGI) and the California Cap and Trade, accept carbon credits or offsets from the forestry sector from avoided emissions through forest conservation, by the enhancement land carbon sequestration through improved forest management and through reforestation projects. These investments often go beyond state, and national boundaries. For example, Blue Source a leading investment firm in forest carbon credits invested in over 20,000 acres of Pennsylvania forests in collaboration with The Nature Conservatory (TNC) Forest Conservation Program. Further local to national governments are writing their own climate policies and regulations and are setting targets for forest carbon storage and sequestration as part of their climate action portfolios. Yet, often little resources or effort is left for monitoring the success of projects such as afforestation initiatives once they have been completed. While field data is critical to monitoring efforts, covering the vast areas needed and getting accurate structural information from field campaigns alone can be difficult and costly. The use of Lidar as a supplement to other developed forest monitoring techniques has advanced significantly over the last decade. Here we evaluate the use of single photon lidar (SPL) collected in the summer of 2015, developed for rapidly collecting high-density, three-dimensional data over a variety of terrain targets, to aid in carbon offset MRV on an 8 ha site reforested in 2002 in central Maryland, USA. With two previous comprehensive field inventories measuring every tree in 2004 and 2013, as well as two county-wide leaf off small footprint lidar campaigns (1pt/m2) in 2004 and 2011, this site represents an ideal candidate to research afforestation MRV capabilities and requirements.

Assimilation of aged organic carbon in a glacial river food web

NASA Astrophysics Data System (ADS)

Fellman, J.; Hood, E. W.; Raymond, P. A.; Bozeman, M.; Hudson, J.; Arimitsu, M.

2013-12-01

Identifying the key sources of organic carbon supporting fish and invertebrate consumers is fundamental to our understanding of stream ecosystems. Recent laboratory bioassays highlight that aged organic carbon from glacier environments is highly bioavailable to stream bacteria relative to carbon originating from ice-free areas. However, there is little evidence suggesting that this aged, bioavailable organic carbon is also a key basal carbon source for stream metazoa. We used natural abundance of Δ14C, δ13C, and δ15N to determine if fish and invertebrate consumers are subsidized by aged organic carbon in a glacial river in southeast Alaska. We collected biofilm, leaf litter, three different species of macroinvertebrates, and resident juvenile salmonids from a reference stream and two sites (one site is directly downstream of the glacial outflow and one site is upstream of the tidal estuary) on the heavily glaciated Herbert River. Key producers, fish, and invertebrate consumers in the reference stream had carbon isotope values that ranged from -26 to -30‰ for δ13C and from -12 to 53‰ for Δ14C, reflecting a food web sustained mainly on contemporary primary production. In contrast, biofilm in the two glacial sites was highly Δ14C depleted (-203 to -215‰) relative to the reference site. Although biofilm may consist of both bacteria and benthic algae utilizing carbon depleted in Δ14C, δ13C values for biofilm (-24.1‰), dissolved inorganic carbon (-5.9‰), and dissolved organic carbon (-24.0‰) suggest that biofilm consist of bacteria sustained in part by glacier-derived, aged organic carbon. Invertebrate consumers (mean Δ14C of -80.5, mean δ13C of -26.5) and fish (mean Δ14C of -63.3, mean δ13C of -25.7) in the two glacial sites had carbon isotope values similar to biofilm. These results similarly show that aged organic carbon is incorporated into the metazoan food web. Overall, our findings indicate that continued watershed deglaciation and subsequent decreases in glacier runoff may shift support of stream food web structure from mainly aged organic carbon to that of one sustained by contemporary primary production. This may have previously unrecognized effects on the productivity and biodiversity of glacier stream ecosystems.

Early atmospheric detection of carbon dioxide from carbon capture and storage sites.

PubMed

Pak, Nasrin Mostafavi; Rempillo, Ofelia; Norman, Ann-Lise; Layzell, David B

2016-08-01

The early atmospheric detection of carbon dioxide (CO2) leaks from carbon capture and storage (CCS) sites is important both to inform remediation efforts and to build and maintain public support for CCS in mitigating greenhouse gas emissions. A gas analysis system was developed to assess the origin of plumes of air enriched in CO2, as to whether CO2 is from a CCS site or from the oxidation of carbon compounds. The system measured CO2 and O2 concentrations for different plume samples relative to background air and calculated the gas differential concentration ratio (GDCR = -ΔO2/ΔCO2). The experimental results were in good agreement with theoretical calculations that placed GDCR values for a CO2 leak at 0.21, compared with GDCR values of 1-1.8 for the combustion of carbon compounds. Although some combustion plume samples deviated in GDCR from theoretical, the very low GDCR values associated with plumes from CO2 leaks provided confidence that this technology holds promise in providing a tool for the early detection of CO2 leaks from CCS sites. This work contributes to the development of a cost-effective technology for the early detection of leaks from sites where CO2 has been injected into the subsurface to enhance oil recovery or to permanently store the gas as a strategy for mitigating climate change. Such technology will be important in building public confidence regarding the safety and security of carbon capture and storage sites.

Abrupt turnover in calcareous-nannoplankton assemblages across the Paleocene/Eocene Thermal Maximum: implications for surface-water oligotrophy over the Kerguelen Plateau, Southern Indian Ocean

USGS Publications Warehouse

Jiang, Shijun; Wise, Sherwood W.

2007-01-01

Ocean Drilling Program (ODP) Core Section 183-1135A-25R-4 from the Kerguelen Plateau in the Indian Ocean sector of the Southern Ocean represents only the second complete, expanded sequence through the Paleocene/Eocene Thermal Maximum (PETM; ~55 Ma) recovered from Antarctic waters. Calcareous nannoplankton at this site underwent an abrupt, fundamental turnover across the PETM as defined by a carbon isotope excursion. Although Chiasmolithus, Discoaster, and Fasciculithus exponentially increase in abundance at the onset, the former abruptly drops but then rapidly recovers, whereas the latter two taxa show opposite trends due to surface-water oligotrophy. These observations confirm previous results from ODP Site 690 on Maud Rise. The elevated pCO2 that accompanied the PETM caused a shoaling of the lysocline and carbonate compensation depth, leading to intensive dissolution of susceptible holococcoliths and poor preservation of the assemblages. Similarities and contrasts between the results of this study and previous work from open-ocean sites and shelf margins further demonstrate that the response to the PETM was consistent in open-ocean environments, but could be localized on continental shelves where nutrient regimes depend on the local geologic setting and oceanographic conditions.

DESIGNING AN OPPORTUNITY FUEL WITH BIOMASS AND TIRE-DERIVED FUEL FOR COFIRING AT WILLOW ISLAND GENERATING STATION

DOE Office of Scientific and Technical Information (OSTI.GOV)

K. Payette; D. Tillman

During the period January 1, 2001-March 31, 2001, Allegheny Energy Supply Co., LLC (Allegheny) finalized the engineering of the Willow Island cofiring project, completed the fuel characterizations for both the Willow Island and Albright Generating Station projects, and initiated construction of both projects. Allegheny and its contractor, Foster Wheeler, selected appropriate fuel blends and issued purchase orders for all processing and mechanical equipment to be installed at both sites. This report summarizes the activities associated with the Designer Opportunity Fuel program, and demonstrations at Willow Island and Albright Generating Stations. The third quarter of the project involved completing the detailedmore » designs for the Willow Island Designer Fuel project. It also included complete characterization of the coal and biomass fuels being burned, focusing upon the following characteristics: proximate and ultimate analysis; higher heating value; carbon 13 nuclear magnetic resonance testing for aromaticity, number of aromatic carbons per cluster, and the structural characteristics of oxygen in the fuel; drop tube reactor testing for high temperature devolatilization kinetics and generation of fuel chars; thermogravimetric analyses (TGA) for char oxidation kinetics; and related testing. The construction at both sites commenced during this quarter, and was largely completed at the Albright Generating Station site.« less

AmeriFlux US-Fwf Flagstaff - Wildfire

DOE Data Explorer

Dor, Sabina [Northern Arizona Univ., Flagstaff, AZ (United States); Kolb, Thomas [Northern Arizona Univ., Flagstaff, AZ (United States)

2016-01-01

This is the AmeriFlux version of the carbon flux data for the site US-Fwf Flagstaff - Wildfire. Site Description - Ponderosa pine forest subject to high severity stand replacing wild fire in 1996. Project webpage http://nau.edu/CEFNS/Forestry/Research/Carbon-Flux/Sites/.

AmeriFlux US-Fuf Flagstaff - Unmanaged Forest

DOE Data Explorer

Dor, Sabina [Northern Arizona Univ., Flagstaff, AZ (United States); Kolb, Thomas [Northern Arizona Univ., Flagstaff, AZ (United States)

2016-01-01

This is the AmeriFlux version of the carbon flux data for the site US-Fuf Flagstaff - Unmanaged Forest. Site Description - Ponderosa pine forest not subject to disturbance in the last decades. Project webpage http://nau.edu/CEFNS/Forestry/Research/Carbon-Flux/Sites/.

Ecosystem carbon loss with woody plant invasion of grasslands.

PubMed

Jackson, Robert B; Banner, Jay L; Jobbágy, Esteban G; Pockman, William T; Wall, Diana H

2002-08-08

The invasion of woody vegetation into deserts, grasslands and savannas is generally thought to lead to an increase in the amount of carbon stored in those ecosystems. For this reason, shrub and forest expansion (for example, into grasslands) is also suggested to be a substantial, if uncertain, component of the terrestrial carbon sink. Here we investigate woody plant invasion along a precipitation gradient (200 to 1,100 mm yr(-1)) by comparing carbon and nitrogen budgets and soil delta(13)C profiles between six pairs of adjacent grasslands, in which one of each pair was invaded by woody species 30 to 100 years ago. We found a clear negative relationship between precipitation and changes in soil organic carbon and nitrogen content when grasslands were invaded by woody vegetation, with drier sites gaining, and wetter sites losing, soil organic carbon. Losses of soil organic carbon at the wetter sites were substantial enough to offset increases in plant biomass carbon, suggesting that current land-based assessments may overestimate carbon sinks. Assessments relying on carbon stored from woody plant invasions to balance emissions may therefore be incorrect.

Modern Timber Harvesting Practices Have Little Short-Term Effect on Soil Carbon Stores in Industrial Forests of Western Oregon and Washington, U.S.A.

NASA Astrophysics Data System (ADS)

Holub, S. M.; Hatten, J. A.

2017-12-01

Soil carbon represents a large, but slowly changing pool of carbon in forests and understanding its response to forest management, including harvesting, is critical for determining overall stand/landscape carbon balance. Past studies have observed mixed effects of harvesting on soil carbon possibly due, in part, to imprecise sampling methods and high variability within soils. Weyerhaeuser Company has led a major effort to examine the effect of conventional timber harvesting on long-term soil carbon stores in western Oregon and Washington Douglas-fir forests using a highly-replicated longitudinal study design that enables precise estimation of variability found in these systems. In 2010, we randomly selected nine harvest units from Weyerhaeuser's 2012 harvest plan. At each non-harvested unit, a uniform, non-rocky area of about 3-6 hectares was selected for the study. Pre-harvest soil samples were collected at 300 sample points from each unit on a fixed square grid, targeting an intensity that would allow detection of >5% change in soil carbon stores. We measured soil carbon concentration and soil bulk density in depth increments to 1 m to allow for the calculation of total soil carbon per hectare. Other ecosystem pools of carbon, such as trees and downed wood, also have been measured to complete the whole-site carbon budget. All units were harvested from late 2011 through mid-year 2012. In 2015, 3-3.5 years post-harvest, we resampled the same areas in an identical manner as the pre-harvest collection to evaluate changes in soil carbon following harvest. Across all sites combined, we estimated a +2% change (-2% to +6%, 95% confidence interval) in mineral soil carbon following harvest, which is consistent with small-to-no change. Individual sites varied in direction of response; only one site showed evidence of a slight decrease in soil carbon, while two sites showed slight gains. These early results indicate that Weyerhaeuser's conventional timber harvesting methods in the Pacific Northwest do not cause substantial short-term losses in soil carbon. Continued monitoring is necessary, however, to document the longer-term trajectory of soil carbon levels through stand development.

Contrasting impact of forestry-drainage on CO2 balance at two adjacent peatlands in Finland

NASA Astrophysics Data System (ADS)

Lohila, Annalea; Minkkinen, Kari; Penttilä, Timo; Launiainen, Samuli; Koskinen, Markku; Ojanen, Paavo; Laurila, Tuomas

2014-05-01

Fate of carbon in peatlands after drainage has been a subject of many studies, particularly at agriculturally managed sites, but also at sites prepared for forestry. In general, the drainage of peatlands has been considered to trigger the decomposition rate of peat and to cause carbon dioxide (CO2) emissions from the peat into the atmosphere. However, there is not yet full consensus on what are the main regulating factors of the carbon balances in forested peatlands, and do all the forested peatland even act as a source of carbon into the atmosphere. In this study we compare the CO2 exchange rates at two adjacent peatland sites in southern Finland, drained for forestry about 40 years earlier. The pair of sites with similar climatic conditions offer an excellent case for studying the mechanisms controlling the carbon balances of forestry-drained peatlands. The sites differ from each other only by fertility, which has an impact on, e.g., tree growth rate. At both sites, CO2 and energy fluxes have been measured with the eddy covariance method over the course of 4 years, but not simultaneously. We have also built at both sites an automatic system consisting of six transparent closed chambers which collect data on the CO2 exchange of the forest floor vegetation (including tree roots) and soil around the year. This enables us to quantify the carbon uptake potential of the ground layer and the peat decomposition rates and helps us to understand the differences between the sites. The results show that the pine and dwarf-shrub-dominated site (nutrient-poor) is a large CO2 sink. The site with a mixture of spruce, birch and pine and lesser ground vegetation (nutrient-rich), on the contrary, has a close-to-neutral CO2 balance, despite the much higher tree growth rate there. In this presentation we will compare the general dynamics and climatic responses of CO2 exchange at the sites, compare the magnitude and factors causing interannual variation, and discuss potential reasons for the different carbon balances.

Biogeochemical patterns of intermittent streams over space and time as surface flows decrease

NASA Astrophysics Data System (ADS)

MacNeille, R. B.; Lohse, K. A.; Godsey, S.; McCorkle, E. P.; Parsons, S.; Baxter, C.

2016-12-01

Climate change in the western United States is projected to lead to earlier snowmelt, increasing fire risk and potentially transitioning perennial streams to intermittent ones. Differences between perennial and intermittent streams, especially the temporal and spatial patterns of carbon and nutrient dynamics during periods of drying, are understudied. We examined spatial and temporal patterns in surface water biogeochemistry in southwest Idaho and hypothesized that as streams dry, carbon concentrations would increase due to evapoconcentration and/or increased in-stream production. Furthermore, we expected that biogeochemical patterns of streams would become increasingly spatially heterogeneous with drying. Finally, we expected that these patterns would vary in response to fire. To test these hypotheses, we collected water samples every 50 meters from two intermittent streams, one burned and one unburned, in April, May and June, 2016 to determine surface water biogeochemistry. Results showed average concentrations of dissolved inorganic carbon (DIC) and dissolved organic carbon (DOC) increased 3-fold from April to June in the burned site compared to the unburned site where concentrations remained relatively constant. Interestingly, average concentrations of total nitrogen (TN) dropped substantially for the burned site over these three months, but only decreased slightly for the unburned site over the same time period. We also assessed changes in spatial correlation between the burned and unburned site: carbon concentrations were less spatially correlated at the unburned site than at the burned site. Scatterplot matrices of DIC values indicated that at a lag distance of 300 m in April and June, the unburned site had r-values of 0.7416 and 0.5975, respectively, while the burned site had r-values of 0.9468 and 0.8783, respectively. These initial findings support our hypotheses that carbon concentrations and spatial heterogeneity increased over time.

Total Mercury, Methylmercury, and Carbon and Nitrogen Stable Isotope Data for Biota from Selected Streams in Oregon, Wisconsin, and Florida, 2002-04

USGS Publications Warehouse

Chasar, Lia C.; Scudder, Barbara C.; Bell, Amanda H.; Wentz, Dennis A.; Brigham, Mark E.

2008-01-01

The U.S. Geological Survey National Water-Quality Assessment Program conducted a multidisciplinary study to investigate the bioaccumulation of mercury from 2002 to 2004. Study areas were located in Oregon, Wisconsin, and Florida. Each study area included one urban site, and one or two nonurban sites that had the following attributes: high-percent wetland or low-percent wetland. Periphyton, macroinvertebrates, and forage fish were collected twice per year (during 2003 and 2004) to capture seasonality. Top predators, specifically largemouth bass (Micropterus salmoides), brown trout (Salmo trutta), and cutthroat trout (Oncorhynchus clarkii), were collected once per year (Oregon, Wisconsin, and Florida in 2003; Florida only in 2004). All biota were identified to the lowest possible taxonomic category and were analyzed for mercury and stable carbon and nitrogen isotopes. Periphyton and invertebrates were analyzed for total mercury and methylmercury; fish were analyzed for total mercury only. This report presents (1) methodology and data on mercury, methylmercury, stable isotopes, and (2) other ecologically relevant measurements in biological tissues of periphyton, invertebrates, forage fish, and predator fish.

Electron donor concentrations in sediments and sediment properties at the agricultural chemicals team research site near New Providence, Iowa, 2006-07

USGS Publications Warehouse

Maharjan, Bijesh; Korom, Scott F.; Smith, Erik A.

2013-01-01

The concentrations of electron donors in aquifer sediments are important to the understanding of the fate and transport of redox-sensitive constituents in groundwater, such as nitrate. For a study by the U.S. Geological Survey National Water-Quality Assessment Program, 50 sediment samples were collected from below the water table from 11 boreholes at the U.S. Geological Survey Agricultural Chemicals Team research site near New Providence, Iowa, during 2006-07. All samples were analyzed for gravel, sand (coarse, medium, and fine), silt, clay, Munsell soil color, inorganic carbon content, and for the following electron donors: organic carbon, ferrous iron, and inorganic sulfide. A subset of 14 sediment samples also was analyzed for organic sulfur, but all of these samples had concentrations less than the method detection limit; therefore, the presence of this potential electron donor was not considered further. X-ray diffraction analyses provided important semi-quantitative information of well-crystallized dominant minerals within the sediments that might be contributing electron donors.

The role of harvest residue in rotation cycle carbon balance in loblolly pine plantations

Treesearch

Asko Noormets; Steve G. Mcnulty; Jean-Christophe Domec; Michael Gavazzi; Ge Sun; John S. King

2012-01-01

Timber harvests remove a significant portion of ecosystem carbon. While some of the wood products moved off-site may last past the harvest cycle of the particular forest crop, the effect of the episodic disturbances on long-term on-site carbon sequestration is unclear. The current study presents a 25 year carbon budget estimate for a typical commercial loblolly pine...

Carbon and Metal Transformations Near the Continent-Ocean Margin Quantified with the ZAPS Instrument Package

DTIC Science & Technology

1999-09-30

Rudnicki M.D. and Klinkhammer G.P., (1999) A segment-scale survey of the Broken Spur hydrothermal plume , Deep-Sea Res. I, 46, 701-714. Guay C.K...We used our sled this year to explore the Bransfield Strait, Antarctica for hydrothermal vent sites (NSF -Office of Polar Programs; OPP-9725872). We...used the real time sensing capability to locate a vent field and map hydrothermal signals at several locations. We used the ZAPS package to investigate

Evaluating the agreement between measurements and models of net ecosystem exchange at different times and timescales using wavelet coherence: an example using data from the North American Carbon Program Site-Level Interim Synthesis

Treesearch

P.C. Stoy; M.C. Dietze; A.D. Richardson; R. Vargas; A.G. Barr; R.S. Anderson; M.A. Arain; I.T. Baker; T.A. Black; J.M. Chen; R.B. Cook; C.M. Gough; R.F. Grant; D.Y. Hollinger; R.C. Izaurralde; C.J. Kucharik; P. Lafleur; B.E. Law; S. Liu; E. Lokupitiya; Y. Luo; J. W. Munger; C. Peng; B. Poulter; D.T. Price; D. M. Ricciuto; W. J. Riley; A. K. Sahoo; K. Schaefer; C.R. Schwalm; H. Tian; H. Verbeeck; E. Weng

2013-01-01

Earth system processes exhibit complex patterns across time, as do the models that seek to replicate these processes. Model output may or may not be significantly related to observations at different times and on different frequencies. Conventional model diagnostics provide an aggregate view of model-data agreement, but usually do not identify the time and frequency...

Review of science issues, deployment strategy, and status for the ARM north slope of Alaska-Adjacent Arctic Ocean climate research site

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stamnes, K.; Ellingson, R.G.; Curry, J.A.

1999-01-01

Recent climate modeling results point to the Arctic as a region that is particularly sensitive to global climate change. The Arctic warming predicted by the models to result from the expected doubling of atmospheric carbon dioxide is two to three times the predicted mean global warming, and considerably greater than the warming predicted for the Antarctic. The North Slope of Alaska-Adjacent Arctic Ocean (NSA-AAO) Cloud and Radiation Testbed (CART) site of the Atmospheric Radiation Measurement (ARM) Program is designed to collect data on temperature-ice-albedo and water vapor-cloud-radiation feedbacks, which are believed to be important to the predicted enhanced warming inmore » the Arctic. The most important scientific issues of Arctic, as well as global, significance to be addressed at the NSA-AAO CART site are discussed, and a brief overview of the current approach toward, and status of, site development is provided. ARM radiometric and remote sensing instrumentation is already deployed and taking data in the perennial Arctic ice pack as part of the SHEBA (Surface Heat Budget of the Arctic ocean) experiment. In parallel with ARM`s participation in SHEBA, the NSA-AAO facility near Barrow was formally dedicated on 1 July 1997 and began routine data collection early in 1998. This schedule permits the US Department of Energy`s ARM Program, NASA`s Arctic Cloud program, and the SHEBA program (funded primarily by the National Science Foundation and the Office of Naval Research) to be mutually supportive. In addition, location of the NSA-AAO Barrow facility on National Oceanic and Atmospheric Administration land immediately adjacent to its Climate Monitoring and Diagnostic Laboratory Barrow Observatory includes NOAA in this major interagency Arctic collaboration.« less

Development and Testing of a Scanning Differential Absorption Lidar For Carbon Sequestration Site Monitoring

NASA Astrophysics Data System (ADS)

Soukup, B.; Johnson, W.; Repasky, K. S.; Carlsten, J. L.

2013-12-01

A scanning differential absorption lidar (DIAL) instrument for carbon sequestration site monitoring is under development and testing at Montana State University. The laser transmitter uses two tunable discrete mode laser diodes (DMLD) operating in the continuous wave (cw) mode with one locked to the on-line absorption wavelength at 1571.4067 nm and the second operating at the off-line wavelength at 1571.2585 nm. Two in-line fiber optic switches are used to switch between on-line and off-line operation. After the fiber optic switches, an acousto-optic modulator (AOM) is used to generate a pulse train used to injection seed an erbium doped fiber amplifier (EDFA) to produce eye-safe laser pulses with maximum pulse energies of 66 J and a pulse repetition frequency of 15 kHz. The DIAL receiver uses a 28 cm diameter Schmidt-Cassegrain telescope to collect that backscattered light, which is then monitored using a fiber coupled photo-multiplier tube (PMT) module operating in the photon counting mode. The PMT has a 3% quantum efficiency, a dark count rate of 90 kHz, and a maximum count rate of 1 MHz. Recently, a fiber coupled avalanche photodiode (APD) operating in the geiger mode has been incorporated into the DIAL receiver. The APD has a quantum efficiency of 10%, a dark count rate of 10 kHz, and a maximum count rate of 1 MHz and provides a much larger dynamic range than the PMT. Both the PMT and APD provide TTL logic pulses that are monitored using a multichannel scaler card used to count the return photons as a function of time of flight and are thus interchangeable. The DIAL instrument was developed at the 1.571 m wavelength to take advantage of commercial-off-the-shelf components. The instrument is operated using a custom Labview program that switches to the DMLD operating at the on-line wavelength, locks this laser to a user defined wavelength setting, and collects return signals for a user defined time. The control program switches to the DMLD operating at the off-line wavelength where data is again collected for a user defined time. The control program repeats this process until stopped by the operator. The DIAL instrument has been operated at the Zero Emission Research Technology (ZERT) field site located on the Montana State University campus and at the Big Sky Carbon Sequestration Partnership site located in north-central Montana. Data collected by the DIAL instrument at both field sites demonstrate that the DIAL is capable of retrieving night time CO2 number density profiles out to a range of 2.5 km with a 150 m range resolution. The DIAL retrievals are validated using a co-located Li-COR 820 gas analyzer placed along the DIAL optical path allowing comparison at a single range as a function of time.

Effects of Climatic Conditions and Management Practices on Agricultural Carbon and Water Budgets in the Inland Pacific Northwest USA

NASA Astrophysics Data System (ADS)

Chi, Jinshu; Waldo, Sarah; Pressley, Shelley N.; Russell, Eric S.; O'Keeffe, Patrick T.; Pan, William L.; Huggins, David R.; Stöckle, Claudio O.; Brooks, Erin S.; Lamb, Brian K.

2017-12-01

Cropland is an important land cover influencing global carbon and water cycles. Variability of agricultural carbon and water fluxes depends on crop species, management practices, soil characteristics, and climatic conditions. In the context of climate change, it is critical to quantify the long-term effects of these environmental drivers and farming activities on carbon and water dynamics. Twenty site-years of carbon and water fluxes covering a large precipitation gradient and a variety of crop species and management practices were measured in the inland Pacific Northwest using the eddy covariance method. The rain-fed fields were net carbon sinks, while the irrigated site was close to carbon neutral during the winter wheat crop years. Sites growing spring crops were either carbon sinks, sources, or neutral, varying with crops, rainfall zones, and tillage practices. Fluxes were more sensitive to variability in precipitation than temperature: annual carbon and water fluxes increased with the increasing precipitation while only respiration increased with temperature in the high-rainfall area. Compared to a nearby rain-fed site, irrigation improved winter wheat production but resulted in large losses of carbon and water to the atmosphere. Compared to conventional tillage, no-till had significantly lower respiration but resulted in slightly lower yields and water use efficiency over 4 years. Under future climate change, it is expected that more carbon fixation by crops and evapotranspiration would occur in a warmer and wetter environment.

NON-DESTRUCTIVE SOIL CARBON ANALYZER.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wielopolski, Lucian; Hendrey, G.; Orion, I.

2004-02-01

This report describes the feasibility, calibration, and safety considerations of a non-destructive, in situ, quantitative, volumetric soil carbon analytical method based on inelastic neutron scattering (INS). The method can quantify values as low as 0.018 gC/cc, or about 1.2% carbon by weight with high precision under the instrument's configuration and operating conditions reported here. INS is safe and easy to use, residual soil activation declines to background values in under an hour, and no radiological requirements are needed for transporting the instrument. The labor required to obtain soil-carbon data is about 10-fold less than with other methods, and the instrumentmore » offers a nearly instantaneous rate of output of carbon-content values. Furthermore, it has the potential to quantify other elements, particularly nitrogen. New instrumentation was developed in response to a research solicitation from the U.S. Department of Energy (DOE LAB 00-09 Carbon Sequestration Research Program) supporting the Terrestrial Carbon Processes (TCP) program of the Office of Science, Biological and Environmental Research (BER). The solicitation called for developing and demonstrating novel techniques for quantitatively measuring changes in soil carbon. The report includes raw data and analyses of a set of proof-of-concept, double-blind studies to evaluate the INS approach in the first phase of developing the instrument. Managing soils so that they sequester massive amounts of carbon was suggested as a means to mitigate the atmospheric buildup of anthropogenic CO{sub 2}. Quantifying changes in the soils' carbon stocks will be essential to evaluating such schemes and documenting their performance. Current methods for quantifying carbon in soil by excavation and core sampling are invasive, slow, labor-intensive and locally destroy the system being observed. Newly emerging technologies, such as Laser Induced Breakdown Spectroscopy and Near-Infrared Spectroscopy, offer soil-carbon analysis; however, these also are invasive and destructive techniques. The INS approach permits quantification in a relatively large volume of soil without disrupting the measurement site. The technique is very fast and provides nearly instantaneous results thereby reducing the cost, and speeding up the rate of analysis. It also has the potential to cover large areas in a mobile scanning mode. These capabilities will significantly advance the tracking carbon sequestration and offer a tool for research in agronomy, forestry, soil ecology and biogeochemistry.« less

The adsorption of NO, NH3, N2 on carbon surface: a density functional theory study.

PubMed

Wang, Jiayong; Yang, Mo; Deng, Debing; Qiu, Shuxia

2017-08-11

To explore the adsorption mechanism of NO, NH 3 , N 2 on a carbon surface, and the effect of basic and acidic functional groups, density functional theory was employed to investigate the interactions between these molecules and carbon surfaces. Molecular electrostatic potential, Mulliken population analyses, reduced density gradient, and Mayer bond order analyses were used to clarify the adsorption mechanism. The results indicate that van der Waals interactions are responsible for N 2 physisorption, and N 2 is the least likely to adsorb on a carbon surface. Modification of carbon materials to decorate basic or acidic functional groups could enhance the NH 3 physisorption because of hydrogen bonding or electrostatic interactions, however, NO physisorption on a carbon surface is poor. Zig-zag sites are more reactive than armchair sites when these gas molecules absorb on the edge sites of carbon surface. Graphical abstract NH 3 , N 2 , NO adsortion on carbon surface.

Constraining Sources of Subducted and Recycled Carbon Along the Sunda Arc

NASA Astrophysics Data System (ADS)

House, B. M.; Bebout, G. E.; Hilton, D. R.; Rodriguez, B.; Plank, T. A.

2014-12-01

From sediment subduction rates and C contents at ODP/DSDP sites 765 and 211, we estimate the rate of C subduction along ~2000 km of the East Sunda Arc to be ~0.4 Tg C yr-1, representing a significant source of subducted volatiles [1]. However volatile recycling efficiency and the provenance of recycled volatiles in this region remain poorly understood. With new δ13C measurements of both carbonate and organic carbon from sites 211 and 765, we present the most detailed study yet of the spatial variability of subducted C and recycled CO2 provenance along the strike of the arc. Furthermore we demonstrate the importance of oceanic crustal carbonate as a C source in a subduction zone that is otherwise carbonate starved. Carbonate content throughout the sediment column decreases dramatically between site 765, approximately 250 km from the Australian continental margin, and site 211, approximately 300 km southwest of the trench and outboard of the Sunda Strait between Sumatra and Java. Continental and shelf carbonate input from the Australian margin dominates shallow deposits at site 765, but underlying pelagic sediments are thought to contribute the majority of inorganic C to the arc. The paucity of carbonate in sediments at site 211 suggests that along this segment essentially all carbonate subducted is derived from altered ocean crust, presenting an opportunity to study the effects of crustal carbonate input. While previous C provenance studies relied on globally-averaged δ13C values for organic and inorganic C in subducted sediments, we present new estimates based on measured δ13CVPDB of carbonate (average of ~2‰ in subducted sediments) and organic carbon (-22.5 to -23‰ average) along with previously published efflux data [2]. These estimates suggest that the arc-averaged ratio of carbonate to organic C subducted along the East Sunda Arc is nearly identical to the inorganic to organic C ratio represented in volcanic and hydrothermal CO2 output, suggesting that differential devolatilization of carbonate and organic C is limited. Our calculated CO2 recycling efficiency of 10 to 20% - which does not include fore-arc outgassing - agrees with geochemical models predicting up to 80% of subducted C may be carried into the deep mantle [3]. [1] Hilton et al., 2002; [2] Halldórsson et al., 2013; [3] Cook-Kollars et al., 2014

Comparisons of a Quantum Annealing and Classical Computer Neural Net Approach for Inferring Global Annual CO2 Fluxes over Land

NASA Astrophysics Data System (ADS)

Halem, M.; Radov, A.; Singh, D.

2017-12-01

Investigations of mid to high latitude atmospheric CO2 show growing amplitudes in seasonal variations over the past several decades. Recent high-resolution satellite measurements of CO2 concentration are now available for three years from the Orbiting Carbon Observatory-2. The Atmospheric Radiation Measurement (ARM) program of DOE has been making long-term CO2-flux measurements (in addition to CO2 concentration and an array of other meteorological quantities) at several towers and mobile sites located around the globe at half-hour frequencies. Recent papers have shown CO2 fluxes inferred by assimilating CO2 observations into ecosystem models are largely inconsistent with station observations. An investigation of how the biosphere has reacted to changes in atmospheric CO2 is essential to our understanding of potential climate-vegetation feedbacks. Thus, new approaches for calculating CO2-flux for assimilation into land surface models are necessary for improving the prediction of annual carbon uptake. In this study, we calculate and compare the predicted CO2 fluxes results employing a Feed Forward Backward Propagation Neural Network model on two architectures, (i) an IBM Minsky Computer node and (ii) a hybrid version of the ARC D-Wave quantum annealing computer. We compare the neural net results of predictions of CO2 flux from ARM station data for three different DOE ecosystem sites; an arid plains near Oklahoma City, a northern arctic site at Barrows AL, and a tropical rainforest site in the Amazon. Training times and predictive results for the calculating annual CO2 flux for the two architectures for each of the three sites are presented. Comparative results of predictions as measured by RMSE and MAE are discussed. Plots and correlations of observed vs predicted CO2 flux are also presented for all three sites. We show the estimated training times for quantum and classical calculations when extended to calculating global annual Carbon Uptake over land. We also examine the efficiency, dependability and resilience of the quantum neural net approach relative to classical computer systems in predicting annual CO2 flux globally.

Water-quality, bed-sediment, and biological data (October 2014 through September 2015) and statistical summaries of data for streams in the Clark Fork Basin, Montana

USGS Publications Warehouse

Dodge, Kent A.; Hornberger, Michelle I.; Turner, Matthew A.

2017-01-19

Water, bed sediment, and biota were sampled in selected streams from Butte to near Missoula, Montana, as part of a monitoring program in the upper Clark Fork Basin of western Montana. The sampling program was led by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, to characterize aquatic resources in the Clark Fork Basin, with emphasis on trace elements associated with historic mining and smelting activities. Sampling sites were located on the Clark Fork and selected tributaries. Water samples were collected periodically at 20 sites from October 2014 through September 2015. Bed-sediment and biota samples were collected once at 13 sites during August 2015.This report presents the analytical results and quality-assurance data for water-quality, bed-sediment, and biota samples collected at sites from October 2014 through September 2015. Water-quality data include concentrations of selected major ions, trace elements, and suspended sediment. At 12 sites, samples for analysis of dissolved organic carbon and turbidity were collected. In addition, samples for analysis of nitrogen (nitrate plus nitrite) were collected at two sites. Daily values of mean suspended-sediment concentration and suspended-sediment discharge were determined for three sites. Seasonal daily values of turbidity were determined for four sites. Bed-sediment data include trace-element concentrations in the fine-grained fraction. Biological data include trace-element concentrations in whole-body tissue of aquatic benthic insects. Statistical summaries of water-quality, bed-sediment, and biological data for sites in the upper Clark Fork Basin are provided for the period of record.

Quantifying Fast and Slow Responses of Terrestrial Carbon Exchange across a Water Availability Gradient in North American Flux Sites

NASA Astrophysics Data System (ADS)

Biederman, J. A.; Scott, R. L.; Goulden, M.

2014-12-01

Climate change is predicted to increase the frequency and severity of water limitation, altering terrestrial ecosystems and their carbon exchange with the atmosphere. Here we compare site-level temporal sensitivity of annual carbon fluxes to interannual variations in water availability against cross-site spatial patterns over a network of 19 eddy covariance flux sites. This network represents one order of magnitude in mean annual productivity and includes western North American desert shrublands and grasslands, savannahs, woodlands, and forests with continuous records of 4 to 12 years. Our analysis reveals site-specific patterns not identifiable in prior syntheses that pooled sites. We interpret temporal variability as an indicator of ecosystem response to annual water availability due to fast-changing factors such as leaf stomatal response and microbial activity, while cross-site spatial patterns are used to infer ecosystem adjustment to climatic water availability through slow-changing factors such as plant community and organic carbon pools. Using variance decomposition, we directly quantify how terrestrial carbon balance depends on slow- and fast-changing components of gross ecosystem production (GEP) and total ecosystem respiration (TER). Slow factors explain the majority of variance in annual net ecosystem production (NEP) across the dataset, and their relative importance is greater at wetter, forest sites than desert ecosystems. Site-specific offsets from spatial patterns of GEP and TER explain one third of NEP variance, likely due to slow-changing factors not directly linked to water, such as disturbance. TER and GEP are correlated across sites as previously shown, but our site-level analysis reveals surprisingly consistent linear relationships between these fluxes in deserts and savannahs, indicating fast coupling of TER and GEP in more arid ecosystems. Based on the uncertainty associated with slow and fast factors, we suggest a framework for improved prediction of terrestrial carbon balance. We will also present results of ongoing work to quantify fast and slow contributions to the relationship between evapotranspiration and precipitation across a precipitation gradient.

CarbonTracker-Lagrange: A Framework for Greenhouse Gas Flux Estimation at Regional to Continental Scales

NASA Astrophysics Data System (ADS)

Andrews, A. E.

2016-12-01

CarbonTracker-Lagrange (CT-L) is a flexible modeling framework developed to take advantage of newly available atmospheric data for CO2 and other long-lived gases such as CH4 and N2O. The North American atmospheric CO2 measurement network has grown from three sites in 2004 to >100 sites in 2015. The US network includes tall tower, mountaintop, surface, and aircraft sites in the NOAA Global Greenhouse Gas Reference Network along with sites maintained by university, government and private sector researchers. The Canadian network is operated by Environment and Climate Change Canada. This unprecedented dataset can provide spatially and temporally resolved CO2 emissions and uptake flux estimates and quantitative information about drivers of variability, such as drought and temperature. CT-L is a platform for systematic comparison of data assimilation techniques and evaluation of assumed prior, model and observation errors. A novel feature of CT-L is the optimization of boundary values along with surface fluxes, leveraging vertically resolved data available from NOAA's aircraft sampling program. CT-L uses observation footprints (influence functions) from the Weather Research and Forecasting/Stochastic Time-Inverted Lagrangian Transport (WRF-STILT) modeling system to relate atmospheric measurements to upwind fluxes and boundary values. Footprints are pre-computed and the optimization algorithms are efficient, so many variants of the calculation can be performed. Fluxes are adjusted using Bayesian or Geostatistical methods to provide optimal agreement with observations. Satellite measurements of CO2 and CH4 from GOSAT are available starting in July 2009 and from OCO-2 since September 2014. With support from the NASA Carbon Monitoring System, we are developing flux estimation strategies that use remote sensing and in situ data together, including geostatistical inversions using satellite retrievals of solar-induced chlorophyll fluorescence. CT-L enables quantitative investigation of what new measurements would best complement the existing carbon observing system. We are also working to implement multi-species inversions for CO2 flux estimation using CO2 data along with CO, δ13CO2, COS and radiocarbon observations and for CH4 flux estimation using data for various hydrocarbons.

Authigenic Carbonate Formation on the Peru Margin; New Insights from IODP Site 1230

NASA Astrophysics Data System (ADS)

Abdullajintakam, S.; Naehr, T. H.

2015-12-01

Fluid seepage of reduced organic compounds such as methane impacts the geology and biology of the seabed by inducing complex, microbially mediated biogeochemical processes. Authigenic carbonates serve as one of the few permanent records of these of dynamic biogeochemical interactions that involve methanogenesis, methanotrophy, sulfate reduction and carbonate precipitation. Meister et al. (2007) investigated deep-sea dolomite formation at Sites 1227-1229 on the Peru margin, where dolomite precipitation occurs in association with organic carbon-rich continental margin sediments. Geochemical and petrographic studies indicated episodic dolomite precipitation at a dynamic sulfate methane transition zone (SMTZ). Variations in δ13C values of these dolomites between +15‰ and -15‰ were attributed to non-steady state conditions as a result of the upward and downward migration of the SMTZ. Our study aims to better understand the biogeochemical processes associated with authigenic carbonate precipitation in this dynamic deep-sea setting. We focused our efforts on IODP Site 1230, which is a gas-hydrate-bearing site that shows sulphate consumption within the uppermost 10 m below the seafloor as well as high methane production. Using a multi proxy approach, we combined X-ray diffraction, stable isotope geochemistry, and trace metal analysis of authigenic carbonates to elucidate conditions for authigenic carbonate formation. Results from Site 1230 are compared to Sites 1227 and 1229, which lacks gas hydrates and is characterized by high pore water sulfate and low methane concentrations. This study contributes to a more comprehensive understanding of authigenic carbonate formation and associated biogeochemical processes in continental margin sediments. Meister, P., Mckenzie, J. A., Vasconcelos, C., Bernasconi, S., Frank, M., Gutjhar, M. and SCHRAG, D. P. (2007), Dolomite formation in the dynamic deep biosphere: results from the Peru Margin. Sedimentology, 54: 1007-1032.

A multi-site analysis of the association between black carbon concentrations and vehicular idling, traffic, background pollution, and meteorology during school dismissals.

PubMed

Richmond-Bryant, J; Bukiewicz, L; Kalin, R; Galarraga, C; Mirer, F

2011-05-01

A study was performed to assess the relationship between black carbon (BC), passing traffic, and vehicular idling outside New York City (NYC) schools during student dismissal. Monitoring was performed at three school sites in East Harlem, the Bronx, and Brooklyn for 1month per year over a two-year period from November 2006-October 2008. Monitoring at each site was conducted before and after the Asthma Free School Zone (AFSZ) asthma reduction education program was administered. Real-time equipment with a one-minute averaging interval was used to obtain the BC data, while volume counts of idling and passing school busses, trucks, and automobiles were collected each minute by study staff. These data were matched to ambient PM(2.5) and meteorology data obtained from the New York State Department of Environmental Conservation. A generalized additive model (GAM) model was run to examine the relationship between BC concentration and each variable while accounting for site-to-site differences. F-tests were employed to assess the significance of each of the predictor variables. The model results suggested that variability in ambient PM(2.5) concentration contributed 24% of the variability in transformed BC concentration, while variability in the number of idling busses and trucks on the street during dismissal contributed 20% of the variability in transformed BC concentration. The results of this study suggest that a combination of urban scale and local traffic control approaches in combination with cessation of school bus idling will produce improved local BC concentration outside schools. Published by Elsevier B.V.

Comparison of snowpack and winter wet-deposition chemistry in the Rocky Mountains, USA: Implications for winter dry deposition

USGS Publications Warehouse

Clow, David W.; Ingersoll, George P.; Mast, M. Alisa; Turk, John T.; Campbell, Donald H.

2002-01-01

Depth-integrated snowpack chemistry was measured just prior to maximum snowpack depth during the winters of 1992-1999 at 12 sites co-located with National Atmospheric Deposition Program/National Trend Network (NADP/NTN) sites in the central and southern Rocky Mountains, USA. Winter volume-weighted mean wet-deposition concentrations were calculated for the NADP/NTN sites, and the data were compared to snowpack concentrations using the paired t-test and the Wilcoxon signed-rank test. No statistically significant differences were indicated in concentrations of SO42- or NO3- (p>0.1). Small, but statistically significant differences (p???0.03) were indicated for all other solutes analyzed. Differences were largest for Ca2+ concentrations, which on average were 2.3??eql-1 (43%) higher in the snowpack than in winter NADP/NTN samples. Eolian carbonate dust appeared to influence snowpack chemistry through both wet and dry deposition, and the effect increased from north to south. Dry deposition of eolian carbonates was estimated to have neutralized an average of 6.9??eql-1 and a maximum of 12??eql-1 of snowpack acidity at the southernmost sites. The good agreement between snowpack and winter NADP/NTN SO42- and NO3- concentrations indicates that for those solutes the two data sets can be combined to increase data density in high-elevation areas, where few NADP/NTN sites exist. This combination of data sets will allow for better estimates of atmospheric deposition of SO42- and NO3- across the Rocky Mountain region.

Comparison of snowpack and winter wet-deposition chemistry in the Rocky Mountains, USA: implications for winter dry deposition

NASA Astrophysics Data System (ADS)

Clow, David W.; Ingersoll, George P.; Mast, M. Alisa; Turk, John T.; Campbell, Donald H.

Depth-integrated snowpack chemistry was measured just prior to maximum snowpack depth during the winters of 1992-1999 at 12 sites co-located with National Atmospheric Deposition Program/National Trend Network (NADP/NTN) sites in the central and southern Rocky Mountains, USA. Winter volume-weighted mean wet-deposition concentrations were calculated for the NADP/NTN sites, and the data were compared to snowpack concentrations using the paired t-test and the Wilcoxon signed-rank test. No statistically significant differences were indicated in concentrations of SO 42- or NO 3- ( p>0.1). Small, but statistically significant differences ( p⩽0.03) were indicated for all other solutes analyzed. Differences were largest for Ca 2+ concentrations, which on average were 2.3 μeq l -1 (43%) higher in the snowpack than in winter NADP/NTN samples. Eolian carbonate dust appeared to influence snowpack chemistry through both wet and dry deposition, and the effect increased from north to south. Dry deposition of eolian carbonates was estimated to have neutralized an average of 6.9 μeq l -1 and a maximum of 12 μeq l -1 of snowpack acidity at the southernmost sites. The good agreement between snowpack and winter NADP/NTN SO 42- and NO 3- concentrations indicates that for those solutes the two data sets can be combined to increase data density in high-elevation areas, where few NADP/NTN sites exist. This combination of data sets will allow for better estimates of atmospheric deposition of SO 42- and NO 3- across the Rocky Mountain region.

Final work plan : Phase I investigation of potential contamination at the former CCC/USDA grain storage facility in Savannah, Missouri.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, L. M.; Environmental Science Division

From approximately 1949 until 1970, the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) operated a grain storage facility on federally owned property approximately 0.25 mi northwest of Savannah, Missouri. During this time, commercial grain fumigants containing carbon tetrachloride were commonly used by the CCC/USDA and the private grain storage industry to preserve grain in their facilities. In November 1998, carbon tetrachloride was detected in a private well (Morgan) roughly 50 ft south of the former CCC/USDA facility, as a result of state-wide screening of private wells near former CCC/USDA facilities, conducted in Missouri by the U.S. Environmentalmore » Protection Agency (EPA 1999). The 1998 and subsequent investigations by the EPA and the Missouri Department of Natural Resources (MoDNR) confirmed the presence of carbon tetrachloride in the Morgan well, as well as in a second well (on property currently occupied by the Missouri Department of Transportation [MoDOT]), approximately 400 ft east of the former CCC/USDA facility. Carbon tetrachloride concentrations in the Morgan well have ranged from the initial value of 29 {micro}g/L in 1998, up to a maximum of 61 {micro}g/L in 1999, and back down to 22 {micro}g/L in 2005. The carbon tetrachloride concentration in the MoDOT well in 2000 (the only time it was sampled) was 321 {micro}g/L. The concentrations for the two wells are above the EPA maximum contaminant level (MCL) of 5 {micro}g/L for carbon tetrachloride (EPA 1999; MoDNR 2000a,b). Because the observed contamination in the Morgan and MoDOT wells might be linked to the past use of carbon tetrachloride-based grain fumigants at its former grain storage facility, the CCC/USDA will conduct investigations to (1) characterize the source(s), extent, and factors controlling the subsurface distribution and movement of carbon tetrachloride at Savannah and (2) evaluate the health and environmental threats potentially posed by the contamination. This work will be performed in accord with the Intergovernmental Agreement established between the Farm Service Agency of the USDA and MoDNR, to address carbon tetrachloride contamination potentially associated with a number of former CCC/USDA grain storage facilities in Missouri. The investigative activities at Savannah will be conducted on behalf of the CCC/USDA by the Environmental Science Division of Argonne National Laboratory. Argonne is a nonprofit, multidisciplinary research center operated by UChicago Argonne, LLC, for the U.S. Department of Energy (DOE). The CCC/USDA has entered into an agreement with the DOE, under which Argonne provides technical assistance to the CCC/USDA with environmental site characterization and remediation at its former grain storage facilities. The site characterization at Savannah will take place in phases. This approach is recommended by the CCC/USDA and Argonne, so that information obtained and interpretations developed during each incremental stage of the investigation can be used most effectively to guide subsequent phases of the program. This site-specific Work Plan outlines the specific technical objectives and scope of work proposed for Phase I of the Savannah investigation. This Work Plan also includes the community relations plan to be followed throughout the CCC/USDA program at the Savannah site. Argonne is developing a Master Work Plan specific to operations in the state of Missouri. In the meantime, Argonne will issue a Provisional Master Work Plan (PMWP; Argonne 2007) that will be submitted to the MoDNR for review and approval. The agency has already reviewed and approved (with minor changes) the present Master Work Plan (Argonne 2002) under which Argonne currently operates in Kansas. The PMWP (Argonne 2007) will provide detailed information and guidance on the investigative technologies, analytical methodologies, quality assurance-quality control measures, and general health and safety policies to be employed by Argonne for all investigations at former CCC/USDA grain storage facilities in Missouri. Both the PMWP and this site-specific Work Plan must therefore be consulted for a complete description of the planned Phase I work at the former CCC/USDA facility at Savannah.« less

Spatial and monthly trends in speciated fine particle concentration in the United States

NASA Astrophysics Data System (ADS)

Malm, William C.; Schichtel, Bret A.; Pitchford, Marc L.; Ashbaugh, Lowell L.; Eldred, Robert A.

2004-02-01

In the spring of 1985 an interagency consortium of federal land management agencies and the Environmental Protection Agency established the Interagency Monitoring of Protected Visual Environments (IMPROVE) network to assess visibility and aerosol monitoring for the purpose of tracking spatial and temporal trends of visibility and visibility-impairing particles in rural areas. The program was initiated with 20 monitoring sites and was expanded to 165 sites between 2000 and 2003. This paper reports on fine aerosol data collected in the year 2001 at 143 sites. The major fine (dp < 2.5 μm) particle aerosol species, sulfates, nitrates, organics, light-absorbing carbon, and wind-blown dust, and coarse gravimetric mass are monitored, and at some sites, light scattering and/or extinction are measured. Sulfates, carbon, and crustal material are responsible for most of the fine mass at the majority of locations throughout the United States, while at sites in southern California and the midwestern United States, nitrates can contribute significantly. In the eastern United States, sulfates contribute between 50 and 60% of the fine mass. Sulfate concentrations tend to be highest in the summer months while organic concentrations can be high in the spring, summer, or fall seasons, depending upon fire-related emissions. However, at the two urban sites, Phoenix, Arizona, and Puget Sound, Washington, organics peak during the winter months. Nitrate concentrations also tend to be highest during the winter months. During the spring months in many areas of the western United States, fine soil can contribute as much as 40% of fine mass. The temporal changes in soil concentration that occur simultaneously over much of the western United States including the Rocky Mountain region suggest a large source region, possibly long-range transport of Asian dust.

Soils at the hyperarid margin: The isotopic composition of soil carbonate from the Atacama Desert, Northern Chile

USGS Publications Warehouse

Quade, Jay; Rech, Jason A.; Latorre, Claudio; Betancourt, Julio L.; Gleeson, Erin; Kalin, Mary T.K.

2007-01-01

We evaluate the impact of exceptionally sparse plant cover (0–20%) and rainfall (2–114 mm/yr) on the stable carbon and oxygen composition of soil carbonate along elevation transects in what is among the driest places on the planet, the Atacama Desert in northern Chile. δ13C and δ18O values of carbonates from the Atacama are the highest of any desert in the world. δ13C (VPDB) values from soil carbonate range from -8.2% at the wettest sites to +7.9% at the driest. We measured plant composition and modeled respiration rates required to form these carbonate isotopic values using a modified version of the soil diffusion model of [Cerling (1984) Earth Planet. Sci. Lett.71, 229–240], in which we assumed an exponential form of the soil CO2 production function, and relatively shallow (20–30 cm) average production depths. Overall, we find that respiration rates are the main predictor of the δ13C value of soil carbonate in the Atacama, whereas the fraction C3 to C4 biomass at individual sites has a subordinate influence. The high average δ13C value (+4.1%) of carbonate from the driest study sites indicates it formed&mdahs;perhaps abiotically—in the presence of pure atmospheric CO2. δ18O (VPDB) values from soil carbonate range from -5.9% at the wettest sites to +7.3% at the driest and show much less regular variation with elevation change than δ13C values. δ18O values for soil carbonate predicted from local temperature and δ18O values of rainfall values suggest that extreme (>80% in some cases) soil dewatering by evaporation occurs at most sites prior to carbonate formation. The effects of evaporation compromise the use of δ18O values from ancient soil carbonate to reconstruct paleoelevation in such arid settings.

Carbon-14 analyses reveal fine structure of the urban carbon dioxide dome in the Salt Lake Valley, Utah, USA

NASA Astrophysics Data System (ADS)

Ehleringer, J. R.; Hopkins, F. M.; Xu, X.; Barnette, J.; Randerson, J. T.; Bush, S.; Lai, C.

2013-12-01

Carbon-14 analyses of mature deciduous tree leaves (aspen and cottonwood) were used to measure the increases in atmospheric carbon dioxide within the expansive urbanizing Salt Lake Valley, Utah, USA associated with fossil fuel combustion. Our objectives were twofold: to understand the fine scale spatial structure of elevated carbon dioxide levels in this urban environment and to relate these observations to actual carbon dioxide observations collected using both long-term monitoring sites and a mobile measurement vehicle. Paired observations of aspen and cottonwood at sites across the valley showed that there was no significant difference in carbon-14 values, allowing spatial pattern evaluations at sites where one but not the other species was present. Statistically significant patterns were observed over a two-year measurement period, with elevated carbon dioxide levels associated with carbon-14 depleted leaves, particularly in regions with higher vehicle travel. Carbon-14 content of leaves was significantly lower on 4-lane roads than on nearby 2-lane roads in both residential and commercial zones, consistent with atmospheric carbon dioxide observations. The analysis of spatial patterns in the carbon-14 in leaves was then used to evaluate how well these observations compared to instantaneous and long-term observations of carbon dioxide using traditional infrared gas analyzer approaches.

Perturbations and gradients as fundamental tests for modeling the soil carbon cycle

NASA Astrophysics Data System (ADS)

Bond-Lamberty, B. P.; Bailey, V. L.; Becker, K.; Fansler, S.; Hinkle, C.; Liu, C.

2013-12-01

An important step in matching process-level knowledge to larger-scale measurements and model results is to challenge those models with site-specific perturbations and/or changing environmental conditions. Here we subject modified versions of an ecosystem process model to two stringent tests: replicating a long-term climate change dryland experiment (Rattlesnake Mountain) and partitioning the carbon fluxes of a soil drainage gradient in the northern Everglades (Disney Wilderness Preserve). For both sites, on-site measurements were supplemented by laboratory incubations of soil columns. We used a parameter-space search algorithm to optimize, within observational limits, the model's influential inputs, so that the spun-up carbon stocks and fluxes matched observed values. Modeled carbon fluxes (net primary production and net ecosystem exchange) agreed with measured values, within observational error limits, but the model's partitioning of soil fluxes (autotrophic versus heterotrophic), did not match laboratory measurements from either site. Accounting for site heterogeneity at DWP, modeled carbon exchange was reasonably consistent with values from eddy covariance. We discuss the implications of this work for ecosystem- to global scale modeling of ecosystems in a changing climate.

Interannual and Seasonal Patterns of Carbon Dioxide, Water, and Energy Fluxes From Ecotonal and Thermokarst-Impacted Ecosystems on Carbon-Rich Permafrost Soils in Northeastern Siberia

NASA Astrophysics Data System (ADS)

Euskirchen, Eugénie S.; Edgar, Colin W.; Syndonia Bret-Harte, M.; Kade, Anja; Zimov, Nikita; Zimov, Sergey

2017-10-01

Eastern Siberia Russia is currently experiencing a distinct and unprecedented rate of warming. This change is particularly important given the large amounts of carbon stored in the yedoma permafrost soils that become vulnerable to thaw and release under warming. Data from this region pertaining to year-round carbon, water, and energy fluxes are scarce, particularly in sensitive ecotonal ecosystems near latitudinal treeline, as well as those already impacted by permafrost thaw. Here we investigated the interannual and seasonal carbon dioxide, water, and energy dynamics at an ecotonal forested site and a disturbed thermokarst-impacted site. The ecotonal site was approximately neutral in terms of CO2 uptake/release, while the disturbed site was either a source or neutral. Our data suggest that high rates of plant productivity during the growing season at the disturbed site may, in part, counterbalance higher rates of respiration during the cold season compared to the ecotonal site. We also found that the ecotonal site was sensitive to the timing of the freezeup of the soil active layer in fall, releasing more CO2 when freezeup occurred later. Both sites showed a negative water balance, although the ecotonal site appeared more sensitive to dry conditions. Water use efficiency at the ecotonal site was lower during warmer summers. Overall, these Siberian measurements indicate ecosystem sensitivity to warmer conditions during the fall and to drier conditions during the growing season and provide a better understanding of ecosystem response to climate in a part of the circumpolar Arctic where current knowledge is weakest.

Site productivity and forest carbon stocks in the United States: Analysis and implications for forest offset project planning

Treesearch

Coeli M. Hoover; James E. Smith

2012-01-01

The documented role of United States forests in sequestering carbon, the relatively low cost of forest-based mitigation, and the many co-benefits of increasing forest carbon stocks all contribute to the ongoing trend in the establishment of forest-based carbon offset projects. We present a broad analysis of forest inventory data using site quality indicators to provide...

Control of odor and VOC emissions at wastewater treatment plants: Boston Harbor case study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Getter, R.; Breen, C.; Laquidara, M.

1994-12-31

Siting of the new wastewater treatment plant (WWTP) for the Massachusetts Water Resources Authority (MWRA) in Boston was based on an assumption of mitigation of total reduced sulfur (TRS) and volatile organic compound (VOC) emissions. Collection and treatment of exhaust streams from potential emission sources was recommended. Best Available Control Technology (BACT) for VOC control was conservatively suggested to consist of wet by carbon adsorption based on initial sampling performed in 1988 during facilities planning, which estimated uncontrolled VOC emissions in excess of 1,000 tons per year. This concept was carried forward to the design phase in 1990, concurrent withmore » an extensive air emissions testing and pilot treatment program at the NMRA`s existing primary treatment plant. Results of the pilot program, however, indicated source VOC concentrations well below what was expected as a result of the initial sampling study. Use of the 1990 pilot data in a top-down BACT analysis led to a recommendation to reconsider VOC control with carbon adsorption on the basis of prohibitive cost. This paper summarizes the background and permitting approach for five new odor control facilities on Deer Island for the Boston Harbor Project, with emphasis on the new primary treatment facilities. The paper also presents results from the 1990 emissions characterization and pilot program, providing generally applicable ideas for solving the difficulties of characterizing and estimating emissions for WWTPS. Results from operation of the pilot facilities illustrate the effectiveness of met scrubbing and carbon adsorption in removing TRS and VOCs from wastewater treatment exhaust air streams. In addition, pilot program results indicate the importance of flexibility in design of odor control systems to accommodate variations in concentrations of TRS and VOCS.« less

Development of a 1 x N Fiber Optic Sensor Array for Carbon Sequestration Site Monitoring

DOE Office of Scientific and Technical Information (OSTI.GOV)

Repasky, Kevin

2014-02-01

A fiber sensor array for sub-surface CO 2 concentrations measurements was developed for monitoring geologic carbon sequestration sites. The fiber sensor array uses a single temperature tunable distributed feedback (DFB) laser operating with a nominal wavelength of 2.004 μm. Light from this DFB laser is direct to one of the 4 probes via an in-line 1 x 4 fiber optic switch. Each of the 4 probes are buried and allow the sub-surface CO 2 to enter the probe through Millipore filters that allow the soil gas to enter the probe but keeps out the soil and water. Light from themore » DFB laser interacts with the CO 2 before it is directed back through the in-line fiber optic switch. The DFB laser is tuned across two CO 2 absorption features where a transmission measurement is made allowing the CO 2 concentration to be retrieved. The fiber optic switch then directs the light to the next probe where this process is repeated allowing sub-surface CO 2 concentration measurements at each of the probes to be made as a function of time. The fiber sensor array was deployed for fifty-eight days beginning June 19, 2012 at the Zero Emission Research Technology (ZERT) field site where sub-surface CO 2 concentrations were monitored. Background measurements indicate the fiber sensor array can monitor background levels as low as 1,000 parts per million (ppm). A thirty four day sub-surface release of 0.15 tones CO 2/day began on July 10, 2012. The elevated subsurface CO 2 concentration was easily detected by each of the four probes with values ranging to over 60,000 ppm, a factor of greater than 6 higher than background measurements. The fiber sensor array was also deploy at the Big Sky Carbon Sequestration Partnership (BSCSP) site in north-central Montana between July 9th and August 7th, 2013 where background measurements were made in a remote sequestration site with minimal infrastructure. The project provided opportunities for two graduate students to participate in research directly related to geologic carbon sequestration. Furthermore, commercialization of the technology developed is being pursued with five different companies via the Department of energy SBIR/STTR program« less

Extreme late-summer drought causes neutral annual carbon balance in southwestern ponderosa pine forests and grasslands

NASA Astrophysics Data System (ADS)

Kolb, Thomas; Dore, Sabina; Montes-Helu, Mario

2013-03-01

We assessed the impacts of extreme late-summer drought on carbon balance in a semi-arid forest region in Arizona. To understand drought impacts over extremes of forest cover, we measured net ecosystem production (NEP), gross primary production (GPP), and total ecosystem respiration (TER) with eddy covariance over five years (2006-10) at an undisturbed ponderosa pine (Pinus ponderosa) forest and at a former forest converted to grassland by intense burning. Drought shifted annual NEP from a weak source of carbon to the atmosphere to a neutral carbon balance at the burned site and from a carbon sink to neutral at the undisturbed site. Carbon fluxes were particularly sensitive to drought in August. Drought shifted August NEP at the undisturbed site from sink to source because the reduction of GPP (70%) exceeded the reduction of TER (35%). At the burned site drought shifted August NEP from weak source to neutral because the reduction of TER (40%) exceeded the reduction of GPP (20%). These results show that the lack of forest recovery after burning and the exposure of undisturbed forests to late-summer drought reduce carbon sink strength and illustrate the high vulnerability of forest carbon sink strength in the southwest US to predicted increases in intense burning and precipitation variability.

Integrated bio-magnetostratigraphy of ODP Site 709 (equatorial Indian Ocean).

NASA Astrophysics Data System (ADS)

Villa, Giuliana; Fioroni, Chiara; Florindo, Fabio

2015-04-01

Over the last decade, calcareous nannofossil biostratigraphy of the lower Eocene-Oligocene sediments has shown great potential, through identification of several new nannofossil species and bioevents (e.g. Fornaciari et al., 2010; Bown and Dunkley Jones, 2012; Toffanin et al., 2013). These studies formed the basis for higher biostratigraphic resolution leading to definition of a new nannofossil biozonation (Agnini et al., 2014). In this study, we investigate the middle Eocene-lower Oligocene sediments from ODP Hole 709C (ODP Leg 115) by means of calcareous nannofossils and magnetostratigraphy. Ocean Drilling Program (ODP) Site 709 was located in the equatorial Indian Ocean and biostratigraphy has been investigated in the nineties (Okada, 1990; Fornaciari et al., 1990) while paleomagnetic data from the Initial Report provided only a poorly constrained magnetostratigraphic interpretation, thus the cored succession was dated only by means of biostratigraphy. Our goal is to test the reliability in the Indian Ocean of the biohorizons recently identified at Site 711 (Fioroni et al., in press), by means of high resolution sampling, new taxonomic updates, quantitative analyses on calcareous nannofossils allowed to increase the number of useful bioevents and to compare their reliability and synchroneity. The new magnetostratigraphic analyses and integrated stratigraphy allow also to achieve an accurate biochronology of the time interval spanning Chrons C20 (middle Eocene) and C12 (early Oligocene). In addition, this equatorial site represents an opportunity to study the carbonate accumulation history and the large fluctuations of the carbonate compensation depth (CCD) during the Eocene (e.g. Pälike et al., 2012). The investigated interval encompasses the Middle Eocene Climatic Optimum (MECO), and the long cooling trend that leads to the Oligocene glacial state. By means of our new bio-magnetostratigraphic data and paleoecological results we provide further insights on nannofossil assemblage response to the paleoclimatic changes that led to the Oligocene glacial state. References Agnini, C., Fornaciari, E., Raffi, I., Catanzariti, R., Pälike, H., Backman, J., Rio, D., 2014. Biozonation and biochronology of Paleogene calcareous nannofossils from low and middle latitudes. Newsletters on Stratigraphy, doi:10.1127/0078-0421/2014/0042. Bown, P. R., Dunkley Jones, T., 2012. Calcareous nannofossils from the Paleogene equatorial Pacific (IODP Expedition 320 Sites U1331-1334). Journal of Nannoplankton Research 32(2), 3-51. Fioroni, C., Villa, G., Persico, D., Jovane L. (in press). Middle Eocene-lower Oligocene Calcareous Nannofossil biostratigraphy and paleoceanographic implications from Site 711(equatorial Indian Ocean). Mar. Micropal. Fornaciari, E., Raffi, I., Rio, D., Villa, G., Backman, J., Olaffson, G., 1990. Quantitative distribution patterns of Oligocene and Miocene calcareous nannofossils from the western equatorial Indian Ocean. In: Duncan, R. A., Backman, J., Peterson, L. C., Proceedings of the Ocean Drilling Program, Scientific Resuls, 115, 237-254. Fornaciari, E., Agnini, C., Catanzariti, R., Rio, D., Bolla, E.M. , Valvasoni, E. 2010. Mid-latitude calcareous nannofossil biostratigraphy, biochronology and evolution across the middle to late Eocene transition. Stratigraphy 7, 229-264. Okada, H., 1990. Quaternary and Paleogene calcareous nannofossils, Leg 115. In Duncan, R.A., Backman, J., Peterson, L.C., et al., (Eds), Proceedings ODP, Scientific Results 115, 129-174. College Station, TX: Ocean Drilling Program. Pälike, H. et al., 2012. A Cenozoic record of the equatorial Pacific carbonate compensation depth. Nature 488, 609-615, doi:10.1038/nature11360. Toffanin, F., Agnini, C., Rio, D., Acton, G., Westerhold, T., 2013. Middle Eocene to early Oligocene calcareous nannofossil biostratigraphy at IODP Site U1333(equatorial Pacific). Micropaleontology 59(1), 69-82.

40 CFR 63.704 - Compliance and monitoring requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... nonregenerative carbon adsorber is used to comply with § 63.703(c)(1), the site-specific operating parameter value... compliance with § 63.703(c), (e)(1)(i), or (f)(1)(i), as appropriate. (5) For each nonregenerative carbon... site-specific operating parameter the carbon replacement time interval, as determined by the maximum...

40 CFR 63.704 - Compliance and monitoring requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... nonregenerative carbon adsorber is used to comply with § 63.703(c)(1), the site-specific operating parameter value... compliance with § 63.703(c), (e)(1)(i), or (f)(1)(i), as appropriate. (5) For each nonregenerative carbon... site-specific operating parameter the carbon replacement time interval, as determined by the maximum...

40 CFR 63.704 - Compliance and monitoring requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... nonregenerative carbon adsorber is used to comply with § 63.703(c)(1), the site-specific operating parameter value... compliance with § 63.703(c), (e)(1)(i), or (f)(1)(i), as appropriate. (5) For each nonregenerative carbon... site-specific operating parameter the carbon replacement time interval, as determined by the maximum...

40 CFR 63.704 - Compliance and monitoring requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... nonregenerative carbon adsorber is used to comply with § 63.703(c)(1), the site-specific operating parameter value... compliance with § 63.703(c), (e)(1)(i), or (f)(1)(i), as appropriate. (5) For each nonregenerative carbon... site-specific operating parameter the carbon replacement time interval, as determined by the maximum...

40 CFR 63.704 - Compliance and monitoring requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... nonregenerative carbon adsorber is used to comply with § 63.703(c)(1), the site-specific operating parameter value... compliance with § 63.703(c), (e)(1)(i), or (f)(1)(i), as appropriate. (5) For each nonregenerative carbon... site-specific operating parameter the carbon replacement time interval, as determined by the maximum...

A comparative study of authigenic carbonates from mussel and tubeworm environments: Implications for discriminating the effects of tubeworms

NASA Astrophysics Data System (ADS)

Feng, Dong; Cordes, Erik E.; Roberts, Harry H.; Fisher, Charles R.

2013-05-01

The Gulf of Mexico hydrocarbon seeps are often populated by dense mussel beds and tubeworm aggregations, as well as exposed authigenic carbonate outcrops. Previous studies suggest the activity of mussels and tubeworms could influence the sediment geochemistry of their habitats, resulting in variations in the stable carbon isotopes of the associated carbonates. However, this conclusion was based on the analyses of samples from a single site. To better understand whether there are consistent differences in the geochemical environments of mussels and tubeworms, mineralogical and stable isotopic compositions of authigenic carbonates from mussel and tubeworm environments from four seep sites were analyzed. The studied sites span a depth range of 1200 m to 2800 m on the northern Gulf of Mexico continental slope. We found that carbonate samples from tubeworm environments were more prone to contain aragonite whereas carbonates from mussel environments were more likely to have calcite. This finding supports the hypothesis that vestimentiferans release sulfate across their roots into the pore waters of the surrounding sediments, a process that could generate a locally sulfate-enriched environment that favors the precipitation of aragonite instead of calcite. Moreover, the δ13C values of tubeworm carbonates are generally lighter than that of mussel carbonates from the same site, which is consistent with the fact that tubeworms are fueling extra subsurface methane oxidation through the release of sulfate into the sediment. Such a process, consequently, enriches the subsurface dissolved inorganic carbon pool with light carbon derived from the seeping hydrocarbons. Taken together, our data suggest that tubeworms could produce a carbon isotope shift that is sufficient to influence the sediment geochemistry of their immediate area, and that this impact is reflected in the associated authigenic carbonates.

Planktonic food web structure at a coastal time-series site: II. Spatiotemporal variability of microbial trophic activities

NASA Astrophysics Data System (ADS)

Connell, Paige E.; Campbell, Victoria; Gellene, Alyssa G.; Hu, Sarah K.; Caron, David A.

2017-03-01

The grazing activities of phagotrophic protists on various microbial assemblages play key roles in determining the amount of carbon available for higher trophic levels and for export out of the photic zone. However, comparisons of the proportion of carbon consumed from the phytoplankton (cyanobacteria+photosynthetic eukaryotes) and heterotrophic bacteria (bacteria+archaea, excluding cyanobacteria) are rare. In this study, microbial community composition, phytoplankton growth and mortality rates (total chlorophyll a, Synechococcus, Prochlorococcus, and photosynthetic picoeukaryotes), and bacterial mortality rates were measured seasonally from 2012 to 2014 in the surface waters of three environmentally distinct sites in the San Pedro Channel, off the coast of southern CA, USA. Higher nutrient concentrations at the nearshore site supported community standing stocks that were 1.3-4.5x those found offshore, yet average growth and grazing rates of the phytoplankton and bacterial assemblages were generally similar between sites and across seasons. Thus, the amount of carbon consumed by the grazer assemblage was largely dictated by prey standing stocks. Heterotrophic bacteria constituted an important source of carbon for microbial consumers, particularly at the two offshore sites where bacterial carbon consumed was roughly equivalent to the amount of phytoplankton carbon consumed. Carbon removal by grazers at the nearshore station was predominantly from the diatoms, which were the primary component of the photosynthetic community at that site. This study highlights the significant contribution of protistan-bacterial trophic interactions to planktonic food webs and provides unique community composition and turnover data to inform biogeochemical models.

Early atmospheric detection of carbon dioxide from carbon capture and storage sites

PubMed Central

Pak, Nasrin Mostafavi; Rempillo, Ofelia; Norman, Ann-Lise; Layzell, David B.

2016-01-01

ABSTRACT The early atmospheric detection of carbon dioxide (CO2) leaks from carbon capture and storage (CCS) sites is important both to inform remediation efforts and to build and maintain public support for CCS in mitigating greenhouse gas emissions. A gas analysis system was developed to assess the origin of plumes of air enriched in CO2, as to whether CO2 is from a CCS site or from the oxidation of carbon compounds. The system measured CO2 and O2 concentrations for different plume samples relative to background air and calculated the gas differential concentration ratio (GDCR = −ΔO2/ΔCO2). The experimental results were in good agreement with theoretical calculations that placed GDCR values for a CO2 leak at 0.21, compared with GDCR values of 1–1.8 for the combustion of carbon compounds. Although some combustion plume samples deviated in GDCR from theoretical, the very low GDCR values associated with plumes from CO2 leaks provided confidence that this technology holds promise in providing a tool for the early detection of CO2 leaks from CCS sites.  Implications: This work contributes to the development of a cost-effective technology for the early detection of leaks from sites where CO2 has been injected into the subsurface to enhance oil recovery or to permanently store the gas as a strategy for mitigating climate change. Such technology will be important in building public confidence regarding the safety and security of carbon capture and storage sites. PMID:27111469

Rocky Mountain snowpack physical and chemical data for selected sites, 2009

USGS Publications Warehouse

Ingersoll, George P.; Mast, M. Alisa; Swank, James M.; Campbell, Chelsea D.

2010-01-01

The Rocky Mountain Snowpack program established a network of snowpack-sampling sites in the Rocky Mountain region from New Mexico to Montana to monitor the chemical content of snow and to understand the effects of regional atmospheric deposition. The U.S. Geological Survey, in cooperation with the National Park Service; the U.S. Department of Agriculture Forest Service; the Colorado Department of Public Health and Environment; Teton County, Wyoming; and others, collected and analyzed snowpack samples annually for 48 or more sites in the Rocky Mountain region during 1993-2009. Sixty-three snowpack-sampling sites were sampled once each in 2009 and data are presented in this report. Data include acid-neutralization capacity, specific conductance, pH, hydrogen ion concentrations, dissolved concentrations of major constituents (calcium, magnesium, sodium, potassium, ammonium, chloride, sulfate, and nitrate), dissolved organic carbon concentrations, snow-water equivalent, snow depth, total mercury concentrations, and ionic charge balance. Quality-assurance data for field and laboratory blanks and field replicates for 2009 also are included.

Shifts in vegetation affect organic carbon quality in a coastal marsh along the Hudson River Estuary

NASA Astrophysics Data System (ADS)

Zhang, A. H.; Corbett, J. E.; Tfaily, M. M.; Martin, I.; Ho, L.; Sun, E.; Sevilla, L.; Vincent, S.; Newton, R.; Peteet, D. M.

2015-12-01

To better understand carbon storage in coastal salt marshes, samples were collected from Piermont Marsh, NY (40 ̊00' N, 73 ̊55'W) located within the Hudson River Estuary. Porewater from three different vegetation sites was analyzed to compare the quality of the dissolved organic carbon. Sites contained either native or invasive vegetation with variations in live plant root depth. Porewater was taken from 0-3m in 50cm intervals, and sites were dominated either by invasive Phragmites australis, native Eleocharis , or native mixed vegetation (Spartina patens, Scirpus, and Typha angustifolia). Sites dominated by invasive Phragmites australis were found to have lower dissolved organic carbon (DOC) concentrations, lower cDOM absorption values, and more labile organic carbon compounds. The molecular composition of the DOC was determined with Fourier Transform Ion Cyclotron Mass Spectrometry (FT-ICR-MS). Labile DOC components were defined as proteins, carbohydrates, and amino sugars while recalcitrant DOC components were defined as lipids, unsaturated hydrocarbons, lignins, tannins, and condensed hydrocarbons. For the Phragmites, Eleocharis, and mixed vegetation sites, average DOC concentrations with depth were found to be 1.71 ± 1.06, 4.64 ± 1.73, and 4.62 ± 3.5 (mM), respectively and cDOM absorption values with depth were found to be 13.22 ± 4.81, 49.42 ± 10.8, and 35.74 ± 17.49 (m-1). Additionally, DOC concentrations increased with depth in the mixed vegetation and Eleocharis sites, but remained relatively constant in the Phragmites site. The percent of labile compounds in the surface samples were found to be 19.02, 14.64, and 14.07% for the Phragmites, Eleocharis, and mixed vegetation sites, respectively. These findings suggest that sites dominated by Phragmites may have more reactive DOC substrates than sites dominated by native vegetation. These results indicate that the carbon storage in marshes invaded by Phragmites would be expected to decrease over time.

Final work plan : phase I investigation of potential contamination at the former CCC/USDA grain storage facility in Montgomery City, Missouri.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, L. M.; Environmental Science Division

From September 1949 until September 1966, the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) leased property at the southeastern end of Montgomery City, Missouri, for the operation of a grain storage facility. During this time, commercial grain fumigants containing carbon tetrachloride were commonly used by the CCC/USDA and the private grain storage industry to preserve grain in their facilities. In January 2000, carbon tetrachloride was detected in a soil sample (220 {micro}g/kg) and two soil gas samples (58 {micro}g/m{sup 3} and 550 {micro}g/m{sup 3}) collected at the former CCC/USDA facility, as a result of a pre-CERCLIS sitemore » screening investigation (SSI) performed by TN & Associates, Inc., on behalf of the U.S. Environmental Protection Agency (EPA), Region VII (MoDNR 2001). In June 2001, the Missouri Department of Natural Resources (MoDNR) conducted further sampling of the soils and groundwater at the former CCC/USDA facility as part of a preliminary assessment/site inspection (PA/SI). The MoDNR confirmed the presence of carbon tetrachloride (at a maximum identified concentration of 2,810 {micro}g/kg) and chloroform (maximum 82 {micro}g/kg) in the soils and also detected carbon tetrachloride and chloroform (42.2 {micro}g/L and 58.4 {micro}g/L, respectively) in a groundwater sample collected at the former facility (MoDNR 2001). The carbon tetrachloride levels identified in the soils and groundwater are above the default target level (DTL) values established by the MoDNR for this contaminant in soils of all types (79.6 {micro}g/kg) and in groundwater (5.0 {micro}g/L), as outlined in Missouri Risk-Based Corrective Action (MRBCA): Departmental Technical Guidance (MoDNR 2006a). The corresponding MRBCA DTL values for chloroform are 76.6 {micro}g/kg in soils of all types and 80 {micro}g/L in groundwater. Because the observed contamination at Montgomery City might be linked to the past use of carbon tetrachloride-based fumigants at its former grain storage facility, the CCC/USDA will conduct investigations to (1) characterize the source(s), extent, and factors controlling the possible subsurface distribution and movement of carbon tetrachloride at the Montgomery City site and (2) evaluate the health and environmental threats potentially represented by the contamination. This work will be performed in accord with the Intergovernmental Agreement established between the Farm Service Agency of the USDA and the MoDNR, to address carbon tetrachloride contamination potentially associated with a number of former CCC/USDA grain storage facilities in Missouri. The investigations at Montgomery City will be conducted on behalf of the CCC/USDA by the Environmental Science Division of Argonne National Laboratory. Argonne is a nonprofit, multidisciplinary research center operated by UChicago Argonne, LLC, for the U.S. Department of Energy (DOE). The CCC/USDA has entered into an agreement with DOE, under which Argonne provides technical assistance to the CCC/USDA with environmental site characterization and remediation at its former grain storage facilities. The site characterization at Montgomery City will take place in phases. This approach is recommended by the CCC/USDA and Argonne, so that information obtained and interpretations developed during each incremental stage of the investigation can be used most effectively to guide subsequent phases of the program. This site-specific Work Plan outlines the specific technical objectives and scope of work proposed for Phase I of the Montgomery City investigation. This Work Plan also includes the community relations plan to be followed throughout the CCC/USDA program at the Montgomery City site. Argonne is developing a Master Work Plan specific to operations in the state of Missouri. In the meantime, Argonne has issued a Provisional Master Work Plan (PMWP; Argonne 2007) that has been reviewed and approved by the MoDNR for current use. The PMWP (Argonne 2007) provides detailed information and guidance on the investigative technologies, analytical methodologies, quality assurance-quality control measures, and general health and safety policies to be employed by Argonne for all investigations at former CCC/USDA grain storage facilities in Missouri. Both the PMWP and this site-specific Work Plan must therefore be consulted for a complete description of the planned Phase I work at the former CCC/USDA facility at Montgomery City.« less

Self-Organization of Amorphous Carbon Nanocapsules into Diamond Nanocrystals Driven by Self-Nanoscopic Excessive Pressure under Moderate Electron Irradiation without External Heating.

PubMed

Wang, Chengbing; Ling, San; Yang, Jin; Rao, Dewei; Guo, Zhiguang

2018-01-01

Phase transformation between carbon allotropes usually requires high pressures and high temperatures. Thus, the development of low-temperature phase transition approaches between carbon allotropes is highly desired. Herein, novel amorphous carbon nanocapsules are successfully synthesized by pulsed plasma glow discharge. These nanocapsules are comprised of highly strained carbon clusters encapsulated in a fullerene-like carbon matrix, with the formers serving as nucleation sites. These nucleation sites favored the formation of a diamond unit cell driven by the self-nanoscopic local excessive pressure, thereby significantly decreasing the temperature required for its transformation into a diamond nanocrystal. Under moderate electron beam irradiation (10-20 A cm -2 ) without external heating, self-organization of the energetic carbon clusters into diamond nanocrystals is achieved, whereas the surrounding fullerene-like carbon matrix remains nearly unchanged. Molecular dynamics simulations demonstrate that the defective rings as the active sites dominate the phase transition of amorphous carbon to diamond nanocrystal. The findings may open a promising route to realize phase transformation between carbon allotropes at a lower temperature. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Final Monitoring Plan for Site Closure at Inman, Kansas

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, Lorraine M.

Inman, Kansas, is a rural town located in southwest McPherson County, in sections 8, 9, 16, and 17, Township 21 South, Range 4 West (Figure 1.1). There are 1,377 people in 513 households, as of the census of 2010. The Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA), operated a grain storage facility at the southern edge of the city of Inman, Kansas, from 1954 to 1965. During this time, commercial grain fumigants containing carbon tetrachloride were in common use by the grain storage industry to preserve grain in their facilities. In 1997, trace to low levels ofmore » carbon tetrachloride (below the maximum contamination level [MCL] of 5.0 μg/L) were detected in three private wells near the former grain storage facility at Inman, as part of a statewide USDA private well sampling program that was implemented by the Kansas Department of Health and Environment (KDHE) near former CCC/USDA facilities. No public water supply wells were identified within 1 mi of the town by the KDHE in 1998. Carbon tetrachloride is the contaminant of primary concern at sites associated with grain storage operations. To determine whether the former CCC/USDA facility at Inman is a potential contaminant source and its possible relationship to the carbon tetrachloride contamination in groundwater, the CCC/USDA agreed to conduct a multi-phase investigation at Inman. The investigation was performed by the Environmental Science Division of Argonne National Laboratory in accordance with the Intergovernmental Agreement between the KDHE and the Farm Service Agency of the USDA.« less

Mineralogical Controls on Carbon Cycling in a Floodplain Environment

NASA Astrophysics Data System (ADS)

Arora, B.; Dwivedi, D.; Steefel, C. I.; Spycher, N.; Fox, P. M.; Nico, P. S.

2016-12-01

With the overarching goal of understanding mineral-organic-microbe interactions on carbon and nutrient cycles, we are developing a reactive transport model that includes carbon (C) pools and transformations, a realistic treatment of protected C pools, multiple decomposition pathways, and radiocarbon (14C) dynamics. The objective of the modeling is to understand the impact of mineralogy on carbon turnover and residence times in a floodplain site in Rifle, CO. Previous studies have identified naturally reduced zones (NRZs) in the saturated zone of the Rifle site to be C hotspots and regions characterized by diffusion-limited transport and high rates of microbially-mediated biogeochemical reactions. Detailed characterization of the soil organic matter in both the NRZ and non-NRZ sediments at the Rifle site including radiocarbon dating, and extraction and chemical characterization of mineral-bound pool of organic matter, is used to inform the modeling. In this study, we describe the development of a coupled unsaturated-saturated flow and biogeochemical reactive transport model of the Rifle site along a two-dimensional cross-section (parallel to groundwater flow). The biogeochemical reaction network includes representations of bacterial and fungal activity, archetypal polymer and monomer carbon substrate groups, kinetic and equilibrium mineral precipitation and dissolution reactions, and aqueous and surface complexation. We use this model to explore fungal and bacterial community emergence at the site and compare organo-mineral interactions across NRZ and non-NRZ regions. Observed 14C profiles suggest that sediment-associated carbon in NRZ locations is much older than both the depositional age of the floodplain sediments and dissolved organic carbon in the groundwater. Model simulations were able to capture the observed soil organic matter (SOM) and Δ14C profiles across the Rifle site. Modeling results show higher lignin content in the NRZ sediments and greater Fe-associated organic carbon as compared to non-NRZ locations. Results therefore suggest that soil mineralogy constitutes a dominant control over organic carbon stocks and residence times. A mechanistic representation of soil mineral-organic-microbe interactions is necessary to reproduce SOM profiles at the site.

Effects of long-term (10 years) exposure to elevated CO2 and O3 on trembling Aspen carbon and nitrogen metabolism at the aspen FACE (Free-Air Carbon Dioxide Enrichment) study site [Abstract

Treesearch

R. Minocha; S. Long; S. Minocha; P Marquardt; M. Kubiske

2010-01-01

The objective of the present study was to evaluate the long-term (10 years) effects of elevated CO2 and O3 on the carbon and nitrogen metabolism of aspen trees. The study was conducted at the Aspen Free-Air Carbon Dioxide Enrichment (FACE) experimental site, Rhinelander, WI, (USA).

Carbon, fire, and fuels: The importance of fuels and fuel characterization and the status of wildland fire fuels data for the United States

NASA Astrophysics Data System (ADS)

French, N. H. F.; Prichard, S.; McKenzie, D.; Kennedy, M. C.; Billmire, M.; Ottmar, R. D.; Kasischke, E. S.

2016-12-01

Quantification of emissions of carbon during combustion relies on knowing three general variables: how much landscape is impacted by fire (burn area), how much carbon is in that landscape (fuel loading), and fuel properties that determine the fraction that is consumed (fuel condition). These variables also determine how much carbon remains at the site in the form of unburned organic material or char, and therefore drive post-fire carbon dynamics and pools. In this presentation we review the importance of understanding fuel type, fuel loading, and fuel condition for quantifying carbon dynamics properly during burning and for measuring and mapping fuels across landscapes, regions, and continents. Variability in fuels has been shown to be a major driver of uncertainty in fire emissions, but has had little attention until recently. We review the current state of fuel characterization for fire management and carbon accounting, and present a new approach to quantifying fuel loading for use in fire-emissions mapping and for improving fire-effects assessment. The latest results of a study funded by the Joint Fire Science Program (JFSP) are presented, where a fuel loading database is being built to quantify variation in fuel loadings, as represented in the Fuel Characteristic Classification System (FCCS), across the conterminous US and Alaska. Statistical assessments of these data at multiple spatial scales will improve tools used by fire managers and scientists to quantify fire's impact on the land, atmosphere, and carbon cycle.

Testing Urey's carbonate-silicate cycle using the calcium isotopic composition of sedimentary carbonates

NASA Astrophysics Data System (ADS)

Blättler, Clara L.; Higgins, John A.

2017-12-01

Carbonate minerals constitute a major component of the sedimentary geological record and an archive of a fraction of the carbon and calcium cycled through the Earth's surface reservoirs for over three billion years. For calcium, carbonate minerals constitute the ultimate sink for almost all calcium liberated during continental and submarine weathering of silicate minerals. This study presents >500 stable isotope ratios of calcium in Precambrian carbonate sediments, both limestones and dolomites, in an attempt to characterize the isotope mass balance of the sedimentary carbonate reservoir through time. The mean of the dataset is indistinguishable from estimates of the calcium isotope ratio of bulk silicate Earth, consistent with the Urey cycle being the dominant mechanism exchanging calcium among surface reservoirs. The variability in bulk sediment calcium isotope ratios within each geological unit does not reflect changes in the global calcium cycle, but rather highlights the importance of local mineralogical and/or diagenetic effects in the carbonate record. This dataset demonstrates the potential for calcium isotope ratios to help assess these local effects, such as the former presence of aragonite, even in rocks with a history of neomorphism and recrystallization. Additionally, 29 calcium isotope measurements are presented from ODP (Ocean Drilling Program) Site 801 that contribute to the characterization of altered oceanic crust as an additional sink for calcium, and whose distinct isotopic signature places a limit on the importance of this subduction flux over Earth history.

The Use of a Mesoscale Climate Model to Validate the Nocturnal Carbon Flux over a Forested Site

NASA Astrophysics Data System (ADS)

Werth, D.; Parker, M.; Kurzeja, R.; Leclerc, M.; Watson, T.

2007-12-01

The Savannah River National Laboratory is initiating a comprehensive carbon dioxide monitoring and modeling program in collaboration with the University of Georgia and the Brookhaven National Laboratory. One of the primary goals is to study the dynamics of carbon dioxide in the stable nocturnal boundary layer (NBL) over a forested area of the Savannah River Site in southwest South Carolina. In the nocturnal boundary layer (NBL), eddy flux correlation is less effective in determining the release of CO2 due to respiration. Theoretically, however, the flux can be inferred by measuring the build up of CO2 in the stable layer throughout the night. This method of monitoring the flux will be validated and studied in more detail with both observations and the results of a high-resolution regional climate model. The experiment will involve two phases. First, an artificial tracer will be released into the forest boundary layer and observed through an array of sensors and at a flux tower. The event will be simulated with the RAMS climate model run at very high resolution. Ideally, the tracer will remain trapped within the stable layer and accumulate at rates which will allow us to infer the release rate, and this should compare well to the actual release rate. If an unknown mechanism allows the tracer to escape, the model simulation would be used to reveal it. In the second phase, carbon fluxes will be measured overnight through accumulation in the overlying layer. The RAMS model will be coupled with the SiB carbon model to simulate the nocturnal cycle of carbon dynamics, and this will be compared to the data collected during the night. As with the tracer study, the NBL method of flux measurement will be validated against the model. The RAMS-SiB coupled model has been run over the SRS at high-resolution to simulate the NBL, and results from simulations of both phases of the project will be presented.

Tropical forest response to a drier future: Measurement and modeling of soil organic matter stocks and turnover

NASA Astrophysics Data System (ADS)

Finstad, K. M.; Campbell, A.; Pett-Ridge, J.; Zhang, N.; McFarlane, K. J.

2017-12-01

Tropical forests account for over 50% of the global terrestrial carbon sink and 29% of global soil carbon, but the stability of carbon in these ecosystems under a changing climate is unknown. Recent work suggests moisture may be more important than temperature in driving soil carbon storage and emissions in the tropics. However, data on belowground carbon cycling in the tropics is sparse, and the role of moisture on soil carbon dynamics is underrepresented in current land surface models limiting our ability to extrapolate from field experiments to the entire region. We measured radiocarbon (14C) and calculated turnover rates of organic matter from 37 soil profiles from the Neotropics including sites in Mexico, Brazil, Costa Rica, Puerto Rico, and Peru. Our sites represent a large range of moisture, spanning 710 to 4200 mm of mean annual precipitation, and include Andisols, Oxisols, Inceptisols, and Ultisols. We found a large range in soil 14C profiles between sites, and in some locations, we also found a large spatial variation within a site. We compared measured soil C stocks and 14C profiles to data generated from the Community Land Model (CLM) v.4.5 and have begun to generate data from the ACME Land Model (ALM) v.1. We found that the CLM consistently overestimated carbon stocks and the mean age of soil carbon at the surface (upper 50 cm), and underestimated the mean age of deep soil carbon. Additionally, the CLM did not capture the variation in 14C and C stock profiles that exists between and within the sites across the Neotropics. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. LLNL-ABS-736060.

Ambient concentrations and insights on organic and elemental carbon dynamics in São Paulo, Brazil

NASA Astrophysics Data System (ADS)

Monteiro dos Santos, Djacinto A.; Brito, Joel F.; Godoy, José Marcus; Artaxo, Paulo

2016-11-01

The São Paulo Metropolitan Area (SPMA) is a megacity with about 20 million people and about 8 million vehicles, most of which are fueled with a significant fraction of ethanol - making it a unique case worldwide. This study presents organic and elemental carbon measurements using thermal-optical analysis from quartz filters collected in four sampling sites within the SPMA. Overall Organic Carbon (OC) concentration was comparable at all sites, where Street Canyon had the highest concentration (3.37 μg m-3) and Park site the lowest (2.65 μg m-3). Elemental Carbon (EC), emitted as result of incomplete combustion, has been significantly higher at the Street Canyon site (6.11 μg m-3) in contrast to all other three sites, ranging from 2.25 μg m-3 (Downtown) to 1.50 μg m-3 (Park). For all sampling sites, the average OC:EC ratio are found on the lower bound (<2) of what is usually observed for other megacities, highlighting the significant contribution of EC in Sao Paulo. At the Street Canyon site, average OC:EC ratio was 0.56, to our knowledge the lowest value ever observed for any urban site. An approach for apportionment between primary and secondary organic carbon based on primary OC:EC ratio was evaluated. The secondary OC was estimated to be 30-40% of total OC concentrations throughout the various sampling sites. The organic carbon dynamics has been further studied using each of the thermally-derived organic carbon fractions. Each of these has been studied regarding their correlation with EC and the correlation between different sites. The analyses have identified that the OC3 and OC4, i.e., the carbon fraction which evolves from the filter at temperatures above 450 °C, presents a regional behavior, with high correlation among all sites. Conversely, OC1, the first fraction to evolve, has depicted a more local characteristic. Furthermore, the fraction of OC which becomes char during the temperature increase under inert atmosphere (the Pyrolytic Carbon-PC) has been the only fraction not to present a significant correlation with EC. Since that EC is assumed to be a primary emission marker, it indicates that PC is not significant in traffic emissions. This study provided innovative insights of the organic aerosol content associated with air pollution dynamics in a megacity impacted by a unique vehicular fleet. It also shows the need of implementation of EURO VI technology and to improve mass transport systems such a metro and more bus corridors to allow better transport for 19 million people in the SPMA.

INTEX-NA: Intercontinental Chemical Transport Experiment - North America

NASA Technical Reports Server (NTRS)

Singh, Hanwant B.; Jacob, D.; Pfister, L.; Hipskind, R. Stephen (Technical Monitor)

2002-01-01

INTEX-NA is an integrated atmospheric chemistry field experiment to be performed over North America using the NASA DC-8 and P-3B aircraft as its primary platforms. It seeks to understand the exchange of chemicals and aerosols between continents and the global troposphere. The constituents of interest are ozone and its precursors (hydrocarbons, NOX and HOX), aerosols, and the major greenhouse gases (CO2, CH4, N2O). INTEX-NA will provide the observational database needed to quantify inflow, outflow, and transformations of chemicals over North America. INTEX-NA is to be performed in two phases. Phase A will take place during the period of May-August 2004 and Phase B during March-June 2006. Phase A is in summer when photochemistry is most intense and climatic issues involving aerosols and carbon cycle are most pressing, and Phase B is in spring when Asian transport to North America is at its peak. INTEX-NA will coordinate its activities with concurrent measurement programs including satellites (e. g. Terra, Aura, Envisat), field activities undertaken by the North American Carbon Program (NACP), and other U.S. and international partners. However, it is being designed as a 'stand alone' mission such that its successful execution is not contingent on other programs. Synthesis of the ensemble of observation from surface, airborne, and space platforms, with the help of global/regional models is an important It is anticipated that approximately 175 flight hours for each of the aircraft (DC-8 and P-3B) will be required for each Phase. Principal operational sites are tentatively selected to be Bangor, ME; Wallops Island, VA; Seattle, WA; Rhinelander, WI; Lancaster, CA; and New Orleans, LA. These coastal and continental sites can support large missions and are suitable for INTEX-NA objectives. The experiment will be supported by forecasts from meteorological and chemical models, satellite observations, surface networks, and enhanced O3,-sonde releases. In addition to characterizing Atlantic-outflow and Pacific-inflow, INTEX-NA will characterize air masses transported between the U.S., Canada, and Mexico. INTEX-NA will be the first continental scale inflow, outflow, and transformation experiment to be performed over North America. It will provide the most comprehensive observational data set to date to understand the O3/NOX/HOX/aerosol photochemical system and the carbon cycle. One of the critical needs of the carbon cycle research is to obtain large-scale vertical and horizontal concentration gradients of CO2, throughout the troposphere over continental source/sink regions. INTEX-NA is ideally suited to perform this role. Coastal and continental operational sites will allow us to develop a curtain profile of greenhouse gases (e. g. CO2,) and other key pollutants across North America. Such information is central to our quantitative understanding of chemical budgets on the continental scale. We expect to provide a number of satellite under-flights over land and water to test and validate observations from the appropriate satellite platform (e. g. Aura). We plan to develop strong collaborations with other national and international observational programs. Results from INTEX-NA should directly benefit the development of environmental policy for air quality and climate change.

Impacts of intensive forestry on early rotation trends in site carbon pools in the southeastern US

Treesearch

Raija Laiho; Felipe Sanchez; Allan Tiarks; Phillip M. Dougherty; Carl C. Trettin

2003-01-01

The effects of different silvicultural practices on site, especially soil, carbon (C) pools are still poorly known. We studied changes in site C pools during the first 5 years following harvesting and conversion of two extensively managed pine-hardwood stands to intensively managed loblolly pine plantations. One study site was located on the lower Atlantic Coastal...

Human impacts on soil carbon dynamics of deep-rooted Amazonian forests and effect of land use change on the carbon cycle in Amazon soils

NASA Technical Reports Server (NTRS)

Nepstad, Daniel; Stone, Thomas; Davidson, Eric; Trumbore, Susan E.

1992-01-01

The main objective of these NASA-funded projects is to improve our understanding of land-use impacts on soil carbon dynamics in the Amazon Basin. Soil contains approximately one half of tropical forest carbon stocks, yet the fate of this carbon following forest impoverishment is poorly studied. Our mechanistics approach draws on numerous techniques for measuring soil carbon outputs, inputs, and turnover time in the soils of adjacent forest and pasture ecosystems at our research site in Paragominas, state of Para, Brazil. We are scaling up from this site-specific work by analyzing Basin-wide patterns in rooting depth and rainfall seasonality, the two factors that we believe should explain much of the variation in tropical soil carbons dynamics. In this report, we summarize ongoing measurements at our Paragominas study site, progress in employing new field data to understand soil C dynamics, and some surprising results from our regional, scale-up work.

The effect of diagenesis and fluid migration on rare earth element distribution in pore fluids of the northern Cascadia accretionary margin

USGS Publications Warehouse

Kim, Ji-Hoon; Torres, Marta E.; Haley, Brian A.; Kastner, Miriam; Pohlman, John W.; Riedel, Michael; Lee, Young-Joo

2012-01-01

Analytical challenges in obtaining high quality measurements of rare earth elements (REEs) from small pore fluid volumes have limited the application of REEs as deep fluid geochemical tracers. Using a recently developed analytical technique, we analyzed REEs from pore fluids collected from Sites U1325 and U1329, drilled on the northern Cascadia margin during the Integrated Ocean Drilling Program (IODP) Expedition 311, to investigate the REE behavior during diagenesis and their utility as tracers of deep fluid migration. These sites were selected because they represent contrasting settings on an accretionary margin: a ponded basin at the toe of the margin, and the landward Tofino Basin near the shelf's edge. REE concentrations of pore fluid in the methanogenic zone at Sites U1325 and U1329 correlate positively with concentrations of dissolved organic carbon (DOC) and alkalinity. Fractionations across the REE series are driven by preferential complexation of the heavy REEs. Simultaneous enrichment of diagenetic indicators (DOC and alkalinity) and of REEs (in particular the heavy elements Ho to Lu), suggests that the heavy REEs are released during particulate organic carbon (POC) degradation and are subsequently chelated by DOC. REE concentrations are greater at Site U1325, a site where shorter residence times of POC in sulfate-bearing redox zones may enhance REE burial efficiency within sulfidic and methanogenic sediment zones where REE release ensues. Cross-plots of La concentrations versus Cl, Li and Sr delineate a distinct field for the deep fluids (z > 75 mbsf) at Site U1329, and indicate the presence of a fluid not observed at the other sites drilled on the Cascadia margin. Changes in REE patterns, the presence of a positive Eu anomaly, and other available geochemical data for this site suggest a complex hydrology and possible interaction with the igneous Crescent Terrane, located east of the drilled transect.

Final work plan : phase II investigation of potential contamination at the former CCC/USDA grain storage facility in Savannah, Missouri.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, L. M.; Environmental Science Division

From approximately 1949 until 1970, the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) operated a grain storage facility on federally owned property approximately 0.25 mi northwest of Savannah, Missouri (Figure 1.1). During this time, commercial grain fumigants containing carbon tetrachloride were commonly used by the CCC/USDA and the private grain storage industry to preserve grain in their facilities. In November 1998, carbon tetrachloride was detected in a private well (Morgan) roughly 50 ft south of the former CCC/USDA facility, as a result of statewide screening of private wells near former CCC/USDA facilities, conducted in Missouri by themore » U.S. Environmental Protection Agency (EPA 1999). The 1998 and subsequent investigations by the EPA and the Missouri Department of Natural Resources (MoDNR) confirmed the presence of carbon tetrachloride in the Morgan well, as well as in a second well (on property currently occupied by the Missouri Department of Transportation [MoDOT]) described as being approximately 400 ft east of the former CCC/USDA facility. The identified concentrations in these two wells were above the EPA maximum contaminant level (MCL) and the Missouri risk-based corrective action default target level (MRBCA DTL) values of 5.0 {micro}g/L for carbon tetrachloride in water used for domestic purposes (EPA 1999; MoDNR 2000a,b, 2006). Because the observed contamination in the Morgan and MoDOT wells might be linked to the past use of carbon tetrachloride-based fumigants at its former grain storage facility, the CCC/USDA is conducting an investigation to (1) characterize the source(s), extent, and factors controlling the subsurface distribution and movement of carbon tetrachloride at Savannah and (2) evaluate the potential risks to human health, public welfare, and the environment posed by the contamination. This work is being performed in accord with the Intergovernmental Agreement established between the Farm Service Agency of the USDA and the MoDNR, to address carbon tetrachloride contamination potentially associated with a number of former CCC/USDA grain storage facilities in Missouri. The site characterization at Savannah is being conducted on behalf of the CCC/USDA by the Environmental Science Division of Argonne National Laboratory. The investigation at Savannah is being conducted in phases. This approach is being used by the CCC/USDA and Argonne, with the approval of the MoDNR, so that information obtained and interpretations developed during each incremental stage of the investigation can be used most effectively to guide subsequent phases of the program. Phase I of the Savannah program was conducted in October-November 2007 and January 2008 (Argonne 2007a, 2008). This site-specific Work Plan provides a brief summary of the Phase I findings and the results of groundwater level monitoring that has been ongoing since completion of the Phase I study and also outlines technical objectives, investigation tasks, and investigation methods for Phase II of the site characterization at Savannah.« less

Yucca Mountain Area Saturated Zone Dissolved Organic Carbon Isotopic Data

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thomas, James; Decker, David; Patterson, Gary

2007-06-25

Groundwater samples in the Yucca Mountain area were collected for chemical and isotopic analyses and measurements of water temperature, pH, specific conductivity, and alkalinity were obtained at the well or spring at the time of sampling. For this project, groundwater samples were analyzed for major-ion chemistry, deuterium, oxygen-18, and carbon isotopes of dissolved inorganic carbon (DIC) and dissolved organic carbon (DOC). The U.S. Geological Survey (USGS) performed all the fieldwork on this project including measurement of water chemistry field parameters and sample collection. The major ions dissolved in the groundwater, deuterium, oxygen-18, and carbon isotopes of dissolved inorganic carbon (DIC)more » were analyzed by the USGS. All preparation and processing of samples for DOC carbon isotopic analyses and geochemical modeling were performed by the Desert Research Institute (DRI). Analysis of the DOC carbon dioxide gas produced at DRI to obtain carbon-13 and carbon-14 values was conducted at the University of Arizona Accelerator Facility (a NSHE Yucca Mountain project QA qualified contract facility). The major-ion chemistry, deuterium, oxygen-18, and carbon isotopes of DIC were used in geochemical modeling (NETPATH) to determine groundwater sources, flow paths, mixing, and ages. The carbon isotopes of DOC were used to calculate groundwater ages that are independent of DIC model corrected carbon-14 ages. The DIC model corrected carbon-14 calculated ages were used to evaluate groundwater travel times for mixtures of water including water beneath Yucca Mountain. When possible, groundwater travel times were calculated for groundwater flow from beneath Yucca Mountain to down gradient sample sites. DOC carbon-14 groundwater ages were also calculated for groundwaters in the Yucca Mountain area. When possible, groundwater travel times were estimated for groundwater flow from beneath Yucca Mountain to down gradient groundwater sample sites using the DOC calculated groundwater ages. The DIC calculated groundwater ages were compared with DOC calculated groundwater ages and both of these ages were compared to travel times developed in ground-water flow and transport models. If nuclear waste is stored in Yucca Mountain, the saturated zone is the final barrier against the release of radionuclides to the environment. The most recent rendition of the TSPA takes little credit for the presence of the saturated zone and is a testament to the inadequate understanding of this important barrier. If radionuclides reach the saturated zone beneath Yucca Mountain, then there is a travel time before they would leave the Yucca Mountain area and flow down gradient to the Amargosa Valley area. Knowing how long it takes groundwater in the saturated zone to flow from beneath Yucca Mountain to down gradient areas is critical information for potential radionuclide transport. Radionuclide transport in groundwater may be the quickest pathway for radionuclides in the proposed Yucca Mountain repository to reach land surface by way of groundwater pumped in Amargosa Valley. An alternative approach to ground-water flow and transport models to determine the travel time of radionuclides from beneath Yucca Mountain to down gradient areas in the saturated zone is by carbon-14 dating of both inorganic and organic carbon dissolved in the groundwater. A standard method of determining ground-water ages is to measure the carbon-13 and carbon-14 of DIC in the groundwater and then correct the measured carbon-14 along a flow path for geochemical reactions that involve carbon containing phases. These geochemical reactions are constrained by carbon-13 and isotopic fractionations. Without correcting for geochemical reactions, the ground-water ages calculated from only the differences in carbon-14 measured along a flow path (assuming the decrease in carbon-14 is due strictly to radioactive decay) could be tens of thousands of years too old. The computer program NETPATH, developed by the USGS, is the best geochemical program for correcting carbon-14 activities for geochemical reactions. The DIC carbon-14 corrected ages can be further constrained by measuring the carbon isotopes of DOC. Because the only source of organic carbon in aquifers is almost always greater than 40,000 years old, any organic carbon that may be added to the groundwater would contain no carbon-14. Thus, ground-water ages determined by carbon isotopes of DOC should be maximum ages that can be used to constrain DIC corrected ages.« less

Method of CO and/or CO.sub.2 hydrogenation to higher hydrocarbons using doped mixed-metal oxides

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shekhawat, Dushyant; Berry, David A.; Haynes, Daniel J.

2017-03-21

A method of hydrogenation utilizing a reactant gas mixture comprising a carbon oxide and a hydrogen agent, and a hydrogenation catalyst comprising a mixed-metal oxide containing metal sites supported and/or incorporated into the lattice. The mixed-metal oxide comprises a pyrochlore, a brownmillerite, or mixtures thereof doped at the A-site or the B-site. The metal site may comprise a deposited metal, where the deposited metal is a transition metal, an alkali metal, an alkaline earth metal, or mixtures thereof. Contact between the carbon oxide, hydrogen agent, and hydrogenation catalyst under appropriate conditions of temperature, pressure and gas flow rate generate amore » hydrogenation reaction and produce a hydrogenated product made up of carbon from the carbon oxide and some portion of the hydrogen agent. The carbon oxide may be CO, CO.sub.2, or mixtures thereof and the hydrogen agent may be H.sub.2. In a particular embodiment, the hydrogenated product comprises olefins, paraffins, or mixtures thereof.« less

Carbon and nitrogen distribution in oak-hickory forests distributed along a productivity gradient

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reber, R.T.; Kaczmarek, D.J.; Pope, P.E.

1993-12-31

Biomass, carbon and nitrogen pools were determined for oak-hickory forests of varying productivity. Little information of this type is available for the central hardwood region. Six oak-hickory dominated forests were chosen to represent a range in potential site productivity as influenced by soil type, amount of recyclable nutrients and available water. Biomass, carbon and nitrogen storage were determined for the following components: above ground standing biomass, fine root biomass, forest floor organic layers and litterfall. As site sequestered at each site was dependent more on the amount of living biomass at each site Litterfall, to some extent, increased with increasingmore » site productivity. As potential site productivity decreased, total fine root biomass increased. The data suggest that as site quality decreased fine root production and turnover may become as important in nutrient cycling as annual litterfall.« less

BOREAS TE-5 Leaf Carbon Isotope Data

NASA Technical Reports Server (NTRS)

Hall, Forrest G. (Editor); Curd, Shelaine (Editor); Ehleriinger, Jim; Brooks, J. Renee; Flanagan, Larry

2000-01-01

The BOREAS TE-5 team collected measurements in the NSA and SSA on gas exchange, gas composition, and tree growth. This documentation describes leaf carbon isotope data that were collected in 1993 and 1994 at the NSA and SSA OJP sites, the SSA OBS site, and the NSA UBS site. In addition, leaf carbon isotope data were collected in 1994 only at the NSA and SSA OA sites. These data was collected to provide seasonal integrated physiological information for 10 to 15 common species at these 6 BOREAS sites. The data are stored in tabular ASCII files. The data files are available on a CD-ROM (see document number 20010000884), or from the Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC).

The impact of biosolids application on organic carbon and carbon dioxide fluxes in soil.

PubMed

Wijesekara, Hasintha; Bolan, Nanthi S; Thangavel, Ramesh; Seshadri, Balaji; Surapaneni, Aravind; Saint, Christopher; Hetherington, Chris; Matthews, Peter; Vithanage, Meththika

2017-12-01

A field study was conducted on two texturally different soils to determine the influences of biosolids application on selected soil chemical properties and carbon dioxide fluxes. Two sites, located in Manildra (clay loam) and Grenfell (sandy loam), in Australia, were treated at a single level of 70 Mg ha -1 biosolids. Soil samples were analyzed for SOC fractions, including total organic carbon (TOC), labile, and non-labile carbon contents. The natural abundances of soil δ 13 C and δ 15 N were measured as isotopic tracers to fingerprint carbon derived from biosolids. An automated soil respirometer was used to measure in-situ diurnal CO 2 fluxes, soil moisture, and temperature. Application of biosolids increased the surface (0-15 cm) soil TOC by > 45% at both sites, which was attributed to the direct contribution from residual carbon in the biosolids and also from the increased biomass production. At both sites application of biosolids increased the non-labile carbon fraction that is stable against microbial decomposition, which indicated the soil carbon sequestration potential of biosolids. Soils amended with biosolids showed depleted δ 13 C, and enriched δ 15 N indicating the accumulation of biosolids residual carbon in soils. The in-situ respirometer data demonstrated enhanced CO 2 fluxes at the sites treated with biosolids, indicating limited carbon sequestration potential. However, addition of biosolids on both the clay loam and sandy loam soils found to be effective in building SOC than reducing it. Soil temperature and CO 2 fluxes, indicating that temperature was more important for microbial degradation of carbon in biosolids than soil moisture. Copyright © 2017 Elsevier Ltd. All rights reserved.

Aspects of Carbon and Sulfur Transformations in MOFEP Surface Soils

Treesearch

Henry G. Spratt

1997-01-01

Carbon and sulfur transformations were studied in surface soils from plots in MOFEP sites from August 1993 to May 1996 and in plots in watersheds ofMOFEP sites 1, 3, and 4 from May 1995 to May 1996. Element pools measured included total carbon, total sulfur, sulfate, and organic sulfur. Transformations quantified included lignocellulose mineralization and organic...

Effects of acidic deposition on the erosion of carbonate stone — experimental results from the U.S. National Acid Precipitation Assessment Program (NAPAP)

NASA Astrophysics Data System (ADS)

Baedecker, Philip A.; Reddy, Michael M.; Reimann, Karl J.; Sciammarella, Cesar A.

One of the goals of NAPAP-sponsored research on the effects of acidic deposition on carbonate stone has been to quantify the incremental effects of wet and dry deposition of hydrogen ion, sulfur dioxide and nitrogen oxides on stone erosion. Test briquettes and slabs of freshly quarried Indiana limestone and Vermont marble have been exposed to ambient environmental conditions in a long-term exposure program. Physical measurements of the recession of test stones exposed to ambient conditions at an angle of 30° to horizontal at the five NAPAP materials exposure sites range from ˜ 15 to ˜ 30 μm yr -1 for marble, and from ˜ 25 to ˜ 45 μm yr -1 for limestone, and are approximately double the recession estimates based on the observed calcium content of run-off solutions from test slabs. The difference between the physical and chemical recession measurements is attributed to the loss of mineral grains from the stone surfaces that are not measured in the run-off experiments. The erosion due to grain loss does not appear to be influenced by rainfall acidity, however, preliminary evidence suggests that grain loss may be influenced by dry deposition of sulfur dioxide between rainfall events. Chemical analyses of the run-off solutions and associated rainfall blanks suggest that ˜ 30% of erosion by dissolution can be attributed to the wet deposition of hydrogen ion and the dry deposition of sulfur dioxide and nitric acid between rain events. The remaining ˜ 70% of erosion by dissolution is accounted for by the solubility of carbonate stone in rain that is in equilibrium with atmospheric carbon dioxide ("clean rain"). These results are for marble and limestone slabs exposed at an angle of 30° from horizontal. The relative contribution of sulfur dioxide to chemical erosion is significantly enhanced for stone slabs having an inclination of 60° or 85°. The dry deposition of alkaline particulate material has a mitigating effect at the two urban field exposure sites at Washington, DC, and Steubenville, OH.

Effects of acidic deposition on the erosion of carbonate stone - experimental results from the U.S. National Acid Precipitation Assessment Program (NAPAP)

USGS Publications Warehouse

Baedecker, P.A.; Reddy, M.M.; Reimann, K.J.; Sciammarella, C.A.

1992-01-01

One of the goals of NAPAP-sponsored research on the effects of acidic deposition on carbonate stone has been to quantify the incremental effects of wet and dry deposition of hydrogen ion, sulfur dioxide and nitrogen oxides on stone erosion. Test briquettes and slabs of freshly quarried Indiana limestone and Vermont marble have been exposed to ambient environmental conditions in a long-term exposure program. Physical measurements of the recession of test stones exposed to ambient conditions at an angle of 30?? to horizontal at the five NAPAP materials exposure sites range from ~15 to ~30?? ??m yr-1 for marble, and from ~25 to ~45 ??m yr -1 for limestone, and are approximately double the recession estimates based on the observed calcium content of run-off solutions from test slabs. The difference between the physical and chemical recession measurements is attributed to the loss of mineral grains from the stone surfaces that are not measured in the run-off experiments. The erosion due to grain loss does not appear to be influenced by rainfall acidity, however, preliminary evidence suggests that grain loss may be influenced by dry deposition of sulfur dioxide between rainfall events. Chemical analyses of the run-off solutions and associated rainfall blanks suggest that ~30% of erosion by dissolution can be attributed to the wet deposition of hydrogen ion and the dry deposition of sulfur dioxide and nitric acid between rain events. The remaining ~70% of erosion by dissolution is accounted for by the solubility of carbonate stone in rain that is in equilibrium with atmospheric carbon dioxide ('clean rain'). These results are for marble and limestone slabs exposed at an angle of 30?? from horizontal. The relative contribution of sulfur dioxide to chemical erosion is significantly enhanced for stone slabs having an inclination of 60?? or 85??. The dry deposition of alkaline particulate material has a mitigating effect at the two urban field exposure sites at Washington, DC, and Steubenville, OH.

Automated Sensor Tuning for Seismic Event Detection at a Carbon Capture, Utilization, and Storage Site, Farnsworth Unit, Ochiltree County, Texas

NASA Astrophysics Data System (ADS)

Ziegler, A.; Balch, R. S.; Knox, H. A.; Van Wijk, J. W.; Draelos, T.; Peterson, M. G.

2016-12-01

We present results (e.g. seismic detections and STA/LTA detection parameters) from a continuous downhole seismic array in the Farnsworth Field, an oil field in Northern Texas that hosts an ongoing carbon capture, utilization, and storage project. Specifically, we evaluate data from a passive vertical monitoring array consisting of 16 levels of 3-component 15Hz geophones installed in the field and continuously recording since January 2014. This detection database is directly compared to ancillary data (i.e. wellbore pressure) to determine if there is any relationship between seismic observables and CO2 injection and pressure maintenance in the field. Of particular interest is detection of relatively low-amplitude signals constituting long-period long-duration (LPLD) events that may be associated with slow shear-slip analogous to low frequency tectonic tremor. While this category of seismic event provides great insight into dynamic behavior of the pressurized subsurface, it is inherently difficult to detect. To automatically detect seismic events using effective data processing parameters, an automated sensor tuning (AST) algorithm developed by Sandia National Laboratories is being utilized. AST exploits ideas from neuro-dynamic programming (reinforcement learning) to automatically self-tune and determine optimal detection parameter settings. AST adapts in near real-time to changing conditions and automatically self-tune a signal detector to identify (detect) only signals from events of interest, leading to a reduction in the number of missed legitimate event detections and the number of false event detections. Funding for this project is provided by the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL) through the Southwest Regional Partnership on Carbon Sequestration (SWP) under Award No. DE-FC26-05NT42591. Additional support has been provided by site operator Chaparral Energy, L.L.C. and Schlumberger Carbon Services. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

Springtime carbon episodes at Gosan background site revealed by total carbon, stable carbon isotopic composition, and thermal characteristics of carbonaceous particles

NASA Astrophysics Data System (ADS)

Jung, J.; Kawamura, K.

2011-05-01

In order to investigate the carbon episodes at Gosan background super-site (33.17° N, 126.10° E) in East Asia during spring of 2007 and 2008, total suspended particles (TSP) were collected and analyzed for particulate organic carbon, elemental carbon, total carbon (TC), total nitrogen (TN), and stable carbon isotopic composition (δ13C) of TC. The carbon episodes at the Gosan site were categorized as long-range transported anthropogenic pollutant (LTP) from Asian continent, Asian dust (AD) accompanying with LTP, and local pollen episodes. The stable carbon isotopic composition of TC (δ13CTC) was found to be lowest during the pollen episodes (range: -26.2 ‰ to -23.5 ‰, avg.: -25.2 ± 0.9 ‰), followed by the LTP episodes (range: -23.5 ‰ to -23.0 ‰, avg.: -23.3 ± 0.3 ‰) and the AD episodes (range: -23.3 to -20.4 %, avg.: -21.8 ± 2.0 ‰). The δ13CTC of the airborne pollens (-28.0 ‰) collected at the Gosan site showed value similar to that of tangerine fruit (-28.1 ‰) produced from Jeju Island. Based on the carbon isotope mass balance equation and the TN and TC regression approach, we found that ∼40-45 % of TC in the TSP samples during the pollen episodes was attributed to airborne pollens from Japanese cedar trees planted around tangerine farms in Jeju Island. The δ13C of citric acid in the airborne pollens (-26.3 ‰) collected at the Gosan site was similar to that in tangerine fruit (-27.4 ‰). The negative correlation between the citric acid-carbon/TC ratios and δ13CTC were obtained during the pollen episodes. These results suggest that citric acid emitted from tangerine fruit may be adsorbed on the airborne pollens and then transported to the Gosan site. Based on the thermal evolution pattern of organic aerosols during the carbon episodes, we found that organic aerosols originated from East China are more volatile on heating and are more likely to form pyrolized organic carbon than the pollen-enriched organic aerosols and organic aerosols originated from Northeast China. Since thermal evolution patterns of organic aerosols are highly influenced by their molecular weight, they can be used as additional information on the formation of secondary organic aerosols during the long-range atmospheric transport and the source regions of organics.

Assessment of Provisional MODIS-derived Surfaces Related to the Global Carbon Cycle

NASA Astrophysics Data System (ADS)

Cohen, W. B.; Maiersperger, T. K.; Turner, D. P.; Gower, S. T.; Kennedy, R. E.; Running, S. W.

2002-12-01

The global carbon cycle is one of the most important foci of an emerging global biosphere monitoring system. A key component of such a system is the MODIS sensor, onboard the Terra satellite platform. Biosphere monitoring requires an integrated program of satellite observations, Earth-system models, and in situ data. Related to the carbon cycle, MODIS science teams routinely develop a variety of global surfaces such as land cover, leaf area index, and net primary production using MODIS data and functional algorithms. The quality of these surfaces must be evaluated to determine their effectiveness for global biosphere monitoring. A project called BigFoot (http://www.fsl.orst.edu/larse/bigfoot/) is an organized effort across nine biomes to assess the quality of the abovementioned surfaces: (1) Arctic tundra; (2) boreal evergreen needle-leaved forest; temperate (3) cropland, (4) grassland, (5) evergreen needle-leaved forest, and (6) deciduous broad-leaved forest; desert (7) grassland and (8) shrubland; and (9) tropical evergreen broad-leaved forest. Each biome is represented by a site that has an eddy-covariance flux tower that measures water vapor and CO2 fluxes. Flux tower footprints are relatively small-approximately 1 km2. BigFoot characterizes 25 km2 around each tower, using field data, Landsat ETM+ image data, and ecosystem process models. Our innovative field sampling design incorporates a nested spatial series to facilitate geostatistical analyses, samples the ecological variability at a site, and is logistically efficient. Field data are used both to develop site-specific algorithms for mapping/modeling the variables of interest and to characterize the errors in derived BigFoot surfaces. Direct comparisons of BigFoot- and MODIS-derived surfaces are made to help understand the sources of error in MODIS-derived surfaces and to facilitate improvements to MODIS algorithms. Results from four BigFoot sites will be presented.

Remote Sensing of Ecosystem Light Use Efficiency Using MODIS

NASA Astrophysics Data System (ADS)

Huemmrich, K. F.; Middleton, E.; Landis, D.; Black, T. A.; Barr, A. G.; McCaughey, J. H.; Hall, F.

2009-12-01

Understanding the dynamics of the global carbon cycle requires an accurate determination of the spatial and temporal distribution of photosynthetic CO2 uptake by terrestrial vegetation. Optimal photosynthetic function is negatively affected by stress factors that cause down-regulation (i.e., reduced rate of photosynthesis). Present modeling approaches to determine ecosystem carbon exchange rely on meteorological data as inputs to models that predict the relative photosynthetic function in response to environmental conditions inducing stress (e.g., drought, high/low temperatures). This study examines the determination of ecosystem photosynthetic light use efficiency (LUE) from remote sensing, through measurement of vegetation spectral reflectance changes associated with physiologic stress responses exhibited by photosynthetic pigments. This approach uses the Moderate-Resolution Spectroradiometer (MODIS) on Aqua and Terra to provide frequent, narrow-band measurements. The reflective ocean MODIS bands were used to calculate the Photochemical Reflectance Index (PRI), an index that is sensitive to reflectance changes near 531nm associated with vegetation stress responses exhibited by photosynthetic pigments in the xanthophyll cycle. MODIS PRI values were compared with LUE calculated from CO2 flux measured at four Canadian forest sites: A mature Douglas fir site in British Columbia, mature aspen and black spruce sites in Saskatchewan, and a mixed forest site in Ontario, all part of the Canadian Carbon Program network. The relationships between LUE and MODIS PRI were different among forest types, with clear differences in the slopes of the relationships for conifer and deciduous forests. The MODIS based LUE measurements provide a more accurate estimation of observed LUE than the values calculated in the MODIS GPP model. This suggests the possibility of a GPP model that uses MODIS LUE instead of modeled LUE. This type of model may provide a useful contrast to existing models driven by meteorological data. The main impediment to developing such a model is the lack of a MODIS product that provides surface reflectance for the MODIS ocean bands over land.

Simulating dissolved organic carbon dynamics at the swedish integrated monitoring sites with the integrated catchments model for carbon, INCA-C.

PubMed

Futter, M N; Löfgren, S; Köhler, S J; Lundin, L; Moldan, F; Bringmark, L

2011-12-01

Surface water concentrations of dissolved organic carbon ([DOC]) are changing throughout the northern hemisphere due to changes in climate, land use and acid deposition. However, the relative importance of these drivers is unclear. Here, we use the Integrated Catchments model for Carbon (INCA-C) to simulate long-term (1996-2008) streamwater [DOC] at the four Swedish integrated monitoring (IM) sites. These are unmanaged headwater catchments with old-growth forests and no major changes in land use. Daily, seasonal and long-term variations in streamwater [DOC] driven by runoff, seasonal temperature and atmospheric sulfate (SO₄(2-)) deposition were observed at all sites. Using INCA-C, it was possible to reproduce observed patterns of variability in streamwater [DOC] at the four IM sites. Runoff was found to be the main short-term control on [DOC]. Seasonal patterns in [DOC] were controlled primarily by soil temperature. Measured SO₄(2-) deposition explained some of the long-term [DOC] variability at all sites.

FInal Report: Site Investigation Results, 2009-2011, at Inman, Kansas

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, Lorraine M.

The Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) operated a grain storage facility at the southern edge of the city of Inman, Kansas, from 1954 to 1965. During this time, commercial grain fumigants containing carbon tetrachloride were in common use by the grain storage industry to preserve grain in their facilities. In 1997, trace to low levels of carbon tetrachloride (below the maximum contamination level [MCL] of 5.0 μg/L) were detected in three private wells near the former grain storage facility at Inman, as part of a statewide USDA private well sampling program that was implemented bymore » the Kansas Department of Health and Environment (KDHE) near former CCC/USDA facilities. No public water supply wells were identified in 1998 by the KDHE within 1 mi of the town. Carbon tetrachloride is the contaminant of primary concern at sites associated with grain storage operations. To determine whether the former CCC/USDA facility at Inman is a potential contaminant source and its possible relationship to the contamination in groundwater, the CCC/USDA agreed to conduct investigations at Inman. The investigations were performed by the Environmental Science Division of Argonne National Laboratory in accordance with the Intergovernmental Agreement between the KDHE and the Farm Service Agency of the USDA. Argonne, on behalf of the CCC/USDA, developed a Work Plan (Argonne 2007) and subsequently a Summary of Investigation Results and Proposed Work Plan (Appendix A) for a phased site investigation. The proposed work was approved by the KDHE (2007, 2011). The investigations were conducted from November 2009 to September 2011, as proposed in the two work plans. This report presents the findings of the 2009-2011 investigations at Inman.« less

A Carbon Source Apportionment Shift in Mexico City Atmospheric Particles During 2003-2004 as Determined with Stable Carbon Isotopes

NASA Astrophysics Data System (ADS)

Lopez-Veneroni, D. G.; Vega, E.

2013-05-01

The stable carbon isotope composition of atmospheric particles (PM2.5) was measured at La Merced (MER), a commercial site in the eastern sector, and at Xalostoc (XAL) an industrial site in the NE sector of Mexico City, during three sampling periods in autumn 2003, and spring and autumn 2004. At each site and sampling campaign particle samples were collected daily with minivol samplers during two week periods. Ancillary data included organic and elemental carbon, trace elements and ionic species. This data base was complement with air quality data from the RAMA (Automatic Atmospheric Monitoring Network). In general, particle concentrations, ionic species and some air quality species showed higher concentrations in autumn and lowest values in spring. Moreover, the concentrations of these chemical species were highest at XAL compared to MER. The stable carbon isotope composition of PM2.5 during autumn 2003 and spring 2004 had and average value of -26.04 (± 1.54) ‰ vs. PDB. Differences in the isotopic composition between the two sites were non significant. The average δ13C during these seasons were 1 ‰ lighter relative to data collected previously at these sites during 2000 and 2001, and is consistent with a predominant source of hydrocarbon combustion. In autumn 2004, however, average δ13C at XAL and MER increased to -22.8 (± 0.9) and -20.6 (± 3.1) ‰, respectively. Organic carbon concentrations during this period increased concomitantly at these sites. The shift in the isotopic composition in ambient particles suggests a predominance of soil-derived carbon during this period. The possible causes and implications of this are discussed.

Insights into soil carbon dynamics across climatic gradients from carbon-pool specific radiocarbon analyses

NASA Astrophysics Data System (ADS)

van der Voort, Tessa Sophia; Hagedorn, Frank; McIntyre, Cameron; Zell, Claudia; Eglinton, Timothy Ian

2017-04-01

Soil carbon constitutes the largest terrestrial reservoir of organic carbon, and therefore understanding the mechanisms and drivers of carbon stabilization is crucial, especially in the framework of climate change. The understanding of the dependence of soil organic turnover in specific carbon pools as related to e.g. climate, soil texture and mineralogy is limited. In this framework, radiocarbon constitutes a uniquely powerful tool that help to unravel carbon dynamics from decadal to millennial timescales. This project combines bulk and pool-specific radiocarbon analyses in the top and deep soil on a wide range of forested soils that span a large climatic gradient (MAT 1.3-9.2°C, MAP 600 to 2100 mm m-2y-1). These well-studies sites are part of the Long-Term Forest Ecosystem Research (LWF) program of the Swiss Federal Institute for Forest, Snow and Landscape research (WSL). This study aims to combine the insights gained from bulk and pool-specific turnover to environmental conditions and molecular composition of soil carbon. The pools investigated span the mineral-associated (occluded and heavy fractions from density fractionation) and potentially water-soluble (free light fractions from density fractionation and water extractable organic carbon) organic carbon fractions. Pool-specific radiocarbon work is augmented by the measurement of abundance of compounds such as alkanes, fatty acids and lignin phenols on a subset of samples. Initial results show disparate patterns depending on soil type and in particular soil texture, which could be indicative of various stabilization mechanisms in different soils. Overall, this study provides new insights into the controls of soil organic matter dynamics as related to environmental conditions, in particular in specific sub-pools of carbon.

Indicators of carbon storage in U.S. ecosystems: baseline for terrestrial carbon accounting.

PubMed

Negra, Christine; Sweedo, Caroline Cremer; Cavender-Bares, Kent; O'Malley, Robin

2008-01-01

Policymakers, program managers, and landowners need information about net terrestrial carbon sequestration in forests, croplands, grasslands, and shrublands to understand the cumulative effects of carbon trading programs, expanding biofuels production, and changing environmental conditions in addition to agricultural and forestry uses. Objective information systems that establish credible baselines and track changes in carbon storage can provide the accountability needed for carbon trading programs to achieve durable carbon sequestration and for biofuels initiatives to reduce net greenhouse gas emissions. A multi-sector stakeholder design process was used to produce a new indicator for the 2008 State of the Nation's Ecosystems report that presents metrics of carbon storage for major ecosystem types, specifically change in the amount of carbon gained or lost over time and the amount of carbon stored per unit area (carbon density). These metrics have been developed for national scale use, but are suitable for adaptation to multiple scales such as individual farm and forest parcels, carbon offset markets and integrated national and international assessments. To acquire the data necessary for a complete understanding of how much, and where, carbon is gained or lost by U.S. ecosystems, expansion and integration of monitoring programs will be required.

Springtime carbon emission episodes at the Gosan background site revealed by total carbon, stable carbon isotopic composition, and thermal characteristics of carbonaceous particles

NASA Astrophysics Data System (ADS)

Jung, J.; Kawamura, K.

2011-11-01

In order to investigate the emission of carbonaceous aerosols at the Gosan background super-site (33.17° N, 126.10° E) in East Asia, total suspended particles (TSP) were collected during spring of 2007 and 2008 and analyzed for particulate organic carbon, elemental carbon, total carbon (TC), total nitrogen (TN), and stable carbon isotopic composition (δ13C) of TC. The stable carbon isotopic composition of TC (δ13CTC) was found to be lowest during pollen emission episodes (range: -26.2‰ to -23.5‰, avg. -25.2 ± 0.9‰), approaching those of the airborne pollen (-28.0‰) collected at the Gosan site. Based on a carbon isotope mass balance equation, we found that ~42% of TC in the TSP samples during the pollen episodes was attributed to airborne pollen from Japanese cedar trees planted around tangerine farms in Jeju Island. A negative correlation between the citric acid-carbon/TC ratios and δ13CTC was obtained during the pollen episodes. These results suggest that citric acid emitted from tangerine fruit may be adsorbed on the airborne pollen and then transported to the Gosan site. Thermal evolution patterns of organic carbon during the pollen episodes were characterized by high OC evolution in the OC2 temperature step (450 °C). Since thermal evolution patterns of organic aerosols are highly influenced by their molecular weight, they can be used as additional information on the formation of secondary organic aerosols and the effect of aging of organic aerosols during the long-range atmospheric transport and sources of organic aerosols.

The stable carbon isotope biogeochemistry of acetate and other dissolved carbon species in deep subseafloor sediments at the northern Cascadia Margin

USGS Publications Warehouse

Heuer, Verena B.; Pohlman, John W.; Torres, Marta E.; Elvert, Marcus; Hinrichs, Kai-Uwe

2009-01-01

Ocean drilling has revealed the existence of vast microbial populations in the deep subseafloor, but to date little is known about their metabolic activities. To better understand the biogeochemical processes in the deep biosphere, we investigate the stable carbon isotope chemistry of acetate and other carbon-bearing metabolites in sediment pore-waters. Acetate is a key metabolite in the cycling of carbon in anoxic sediments. Its stable carbon isotopic composition provides information on the metabolic processes dominating acetate turnover in situ. This study reports our findings for a methane-rich site at the northern Cascadia Margin (NE Pacific) where Expedition 311 of the Integrated Ocean Drilling Program (IODP) sampled the upper 190 m of sediment. At Site U1329, δ13C values of acetate span a wide range from −46.0‰ to −11.0‰ vs. VPDB and change systematically with sediment depth. In contrast, δ13C values of both the bulk dissolved organic carbon (DOC) (−21.6 ± 1.3‰ vs. VPDB) and the low-molecular-weight compound lactate (−20.9 ± 1.8‰ vs. VPDB) show little variability. These species are interpreted to represent the carbon isotopic composition of fermentation products. Relative to DOC, acetate is up to 23.1‰ depleted and up to 9.1‰ enriched in 13C. Broadly, 13C-depletions of acetate relative to DOC indicate flux of carbon from acetogenesis into the acetate pool while 13C-enrichments of pore-water acetate relative to DOC suggest consumption of acetate by acetoclastic methanogenesis. Isotopic relationships between acetate and lactate or DOC provide new information on the carbon flow and the presence and activity of specific functional microbial communities in distinct biogeochemical horizons of the sediment. In particular, they suggest that acetogenic CO2-reduction can coexist with methanogenic CO2-reduction, a notion contrary to the hypothesis that hydrogen levels are controlled by the thermodynamically most favorable electron-accepting process. Further, the isotopic relationship suggests a relative increase in acetate flow to acetoclastic methanogenesis with depth although its contribution to total methanogenesis is probably small. Our study demonstrates how the stable carbon isotope biogeochemistry of acetate can be used to identify pathways of microbial carbon turnover in subsurface environments. Our observations also raise new questions regarding the factors controlling acetate turnover in marine sediments.

Belowground carbon distribution in a pinon-juniper / short grass prairie site

Treesearch

John Harrington

2008-01-01

Pinon-juniper woodlands encompass over 22.5 million hectares in the Western United States. However, little is known about the ability of these ecosystems to sequester carbon. This paper presents the preliminary results of an investigation on the belowground carbon distribution in a pinon-juniper/short grass prarie site in north-central New Mexico. Using a systematic...

Wintertime Correlation Between Black Carbon and Particle Size in a Street and Rural Site in Santiago de Chile

NASA Astrophysics Data System (ADS)

Gramsch, E. V.; Reyes, F.; Oyola, P.

2013-05-01

We have studied the correlation between black carbon and particle size in three sites in the Metropolitan area of Santiago de Chile in the winter of 2009 and performed a detailed comparison. Two of the sites are located near busy streets in Santiago de Chile. The other site was located in a rural area about 30 km upwind from downtown with little influence from vehicles, but large influence from wood burning. The particle size distribution was measured with a DMPS (Whalin, 2001) in the range from 10 to 700 nm. Simultaneously, black carbon was measured with an optical monitor developed at the University of Santiago (Gramsch, 2004). It is well known that the smaller particles (~ 10 - 40 nm ) are emitted directly by the engines of vehicles, which later condensate or coagulate in the atmosphere to form larger particles. In our measurements, the street site is mostly influenced by diesel vehicles which emit large amounts of black carbon. We have divided the particle size measurements in four groups (10 - 40 nm, 41- 69 nm, 79 - 157 nm and 190 - 700 nm) in order to compare with the carbon monitor. The highest correlation (0.98) in the site near the street between black carbon and the particles was obtained with the 190 - 700 nm. The correlation with the 79 - 157 nm group was slightly less (0.93). A comparison between the hourly average curves for black carbon and the 190 - 700 nm group show a similar shape during the whole day. In the rural site, the number of particles in the 10 - 40 nm group was 10 times lower than in the street, but the number of particles in the 190 - 700 nm group was only two times smaller. This fact is an indication that wood burning does not generate particles smaller than ~ 80 - 100 nm. The best correlation in the rural site between the black carbon and the particles was also with the 190 - 700 nm group. However, the correlation was lower (0.86) than in the street site. The hourly average curves for black carbon and the 190 - 700 nm group show a similar shape during the night (10 PM - 6 AM), but differ during the day. These measurements indicate that black carbon measurements may be more sensitive to emission from diesel vehicles than wood burning. This work was supported by the University of Santiago (Dicyt), the National Commission for the Environment (CONAMA) and the Regional Government of the Metropolitan Region (GORE).. Gramsch, E., Cereceda-Balic, F., Ormeño, I., Palma, G., Oyola, P., 2004. Use of the light absorption coefficient to monitor elemental carbon and PM2.5. Example of Santiago de Chile. Journal of the Air and Waste Management Association 54, 799-808 Wahlin, P., Palmgren, F., Van Dingenen, R., 2001. Experimental studies of ultrafine particles in streets and the relationship to traffic. Atmospheric Environment 35 (Suppl. 1), 63-69..

Carbon and greenhouse gas balance of the FR-GRI crop site from 2005 to 2014

NASA Astrophysics Data System (ADS)

Loubet, Benjamin; Chammakhi, Manel; Mascher, Nicolas; Durand, Brigitte; Gueudet, Jean-Christophe; Decuq, Céline; Lecuyer, Vanessa; Laville, Patricia; Buysse, Pauline; Cellier, Pierre

2017-04-01

The carbon and greenhouse gas balance of the ICOS FR-GRI site from 2005 to 2014 is presented. The site is a wheat-barley-maize rotation with the introduction of oil-seed rape in 2012. The site receives large amounts of organic fertilization, but is shown to be a strong source of carbon to the atmosphere, especially due to the increase in the exportations of residues during the period. The exportations have increased from around 4 to around 8 t C ha-1 year-1 over the period on average except for maize for which it remained constant. In the meantime the carbon importations have increased from around 1 to around 2 t C ha-1 year-1 during the same period. Overall the field was losing around 2 t C ha-1 year-1 over the whole period but largely driven by last years (2012-2014). This would represent 17% loss of the soil carbon content in the 0-60 cm in the 2005-2014 period. The discussion focuses on explanations of these losses and possible drawbacks in the methodology. The effect of the winter intermediate crops on the carbon balance is also discussed.

Soil organic carbon dynamics following afforestation in the Loess Plateau of China

NASA Astrophysics Data System (ADS)

Lu, N.; Liski, J.; Chang, R. Y.; Akujärvi, A.; Wu, X.; Jin, T. T.; Wang, Y. F.; Fu, B. J.

2013-07-01

Soil organic carbon (SOC) is the largest terrestrial carbon pool and sensitive to land use and cover change; its dynamics is critical for carbon cycling in terrestrial ecosystems and the atmosphere. In this study, we combined a modeling approach and field measurements to examine the temporal dynamics of SOC following afforestation of former arable land at six sites under different climatic conditions in the Loess Plateau during 1980-2010. The results showed that the measured mean SOC increased to levels higher than before afforestation when taking the last measurements (i.e., at age 25 to 30 yr), although it decreased in the first few years at the wetter sites. The accumulation rates of SOC were 1.58 to 6.22% yr-1 in the upper 20 cm and 1.62 to 5.15% yr-1 in the upper 40 cm of soil. The simulations reproduced the basic characteristics of measured SOC dynamics, suggesting that litter input and climatic factors (temperature and precipitation) were the major causes for SOC dynamics and the differences among the sites. They explained 88-96, 48-86 and 57-74% of the variations in annual SOC changes at the soil depths of 0-20, 0-40, and 0-100 cm, respectively. Notably, the simulated SOC decreased during the first few years at all the sites, although the magnitudes of decreases were small at the drier sites. This suggested that the modeling may be advantageous in capturing SOC changes at finer time scale. The discrepancy between the simulation and measurement was a result of uncertainties in model structure, data input, and sampling design. Our findings indicated that afforestation promoted soil carbon sequestration at the study sites, which is favorable for further restoration of the vegetation and environment. Afforestation activities should decrease soil disturbances to reduce carbon release in the early stage. The long-term strategy for carbon fixation capability of the plantations should also consider the climate and site conditions, species adaptability, and successional stage of recovery.

Net ecosystem carbon dioxide exchange in tropical rainforests - sensitivity to environmental drivers and flux measurement methodology

NASA Astrophysics Data System (ADS)

Fu, Z.; Stoy, P. C.

2017-12-01

Tropical rainforests play a central role in the Earth system services of carbon metabolism, climate regulation, biodiversity maintenance, and more. They are under threat by direct anthropogenic effects including deforestation and indirect anthropogenic effects including climate change. A synthesis of the factors that determine the net ecosystem exchange of carbon dioxide (NEE) across multiple time scales in different tropical rainforests has not been undertaken to date. Here, we study NEE and its components, gross primary productivity (GPP) and ecosystem respiration (RE), across thirteen tropical rainforest research sites with 63 total site-years of eddy covariance data. Results reveal that the five ecosystems that have greater carbon uptakes (with the magnitude of GPP greater than 3000 g C m-2 y-1) sequester less carbon - or even lose it - on an annual basis at the ecosystem scale. This counterintuitive result is because high GPP is compensated by similar magnitudes of RE. Sites that provided subcanopy CO2 storage observations had higher average magnitudes of GPP and RE and consequently lower NEE, highlighting the importance of measurement methodology for understanding carbon dynamics in tropical rainforests. Vapor pressure deficit (VPD) constrained GPP at all sites, but to differing degrees. Many environmental variables are significantly related to NEE at time scales greater than one year, and NEE at a rainforest in Malaysia is significantly related to soil moisture variability at seasonal time scales. Climate projections from 13 general circulation models (CMIP5) under representative concentration pathway (RCP) 8.5 suggest that many current tropical rainforest sites on the cooler end of the current temperature range are likely to reach a climate space similar to present-day warmer sites by the year 2050, and warmer sites will reach a climate space not currently experienced. Results demonstrate the need to quantify if mature tropical trees acclimate to heat and VPD, and to further develop flux-partitioning and gap-filling algorithms for defensible estimates of carbon exchange in tropical rainforests.

75 FR 77229 - Federal Requirements Under the Underground Injection Control (UIC) Program for Carbon Dioxide (CO2

Federal Register 2010, 2011, 2012, 2013, 2014

2010-12-10

...This action finalizes minimum Federal requirements under the Safe Drinking Water Act (SDWA) for underground injection of carbon dioxide (CO2) for the purpose of geologic sequestration (GS). GS is one of a portfolio of options that could be deployed to reduce CO2 emissions to the atmosphere and help to mitigate climate change. This final rule applies to owners or operators of wells that will be used to inject CO2 into the subsurface for the purpose of long-term storage. It establishes a new class of well, Class VI, and sets minimum technical criteria for the permitting, geologic site characterization, area of review (AoR) and corrective action, financial responsibility, well construction, operation, mechanical integrity testing (MIT), monitoring, well plugging, post-injection site care (PISC), and site closure of Class VI wells for the purposes of protecting underground sources of drinking water (USDWs). The elements of this rulemaking are based on the existing Underground Injection Control (UIC) regulatory framework, with modifications to address the unique nature of CO2 injection for GS. This rule will help ensure consistency in permitting underground injection of CO2 at GS operations across the United States and provide requirements to prevent endangerment of USDWs in anticipation of the eventual use of GS to reduce CO2 emissions to the atmosphere and to mitigate climate change.

Using Biomass to Improve Site Quality and Carbon Sequestration

Treesearch

Bryce J. Stokes; Felipe G. Sanchez; Emily A. Carter

1998-01-01

The future demands on forest lands are a concern because of reduced productivity, especially on inherently poor sites, sites with long-depleted soils, or those soils that bear repeated, intensive short rotations. Forests are also an important carbon sink and, when well managed, can make even more significant contributions to sequestration and to reduction of greenhouse...

Seasonal and spatial trends in the sources of fine particle organic carbon in Israel, Jordan, and Palestine

NASA Astrophysics Data System (ADS)

von Schneidemesser, Erika; Zhou, Jiabin; Stone, Elizabeth A.; Schauer, James J.; Qasrawi, Radwan; Abdeen, Ziad; Shpund, Jacob; Vanger, Arye; Sharf, Geula; Moise, Tamar; Brenner, Shmuel; Nassar, Khaled; Saleh, Rami; Al-Mahasneh, Qusai M.; Sarnat, Jeremy A.

2010-09-01

A study of carbonaceous particulate matter (PM) was conducted in the Middle East at sites in Israel, Jordan, and Palestine. The sources and seasonal variation of organic carbon, as well as the contribution to fine aerosol (PM 2.5) mass, were determined. Of the 11 sites studied, Nablus had the highest contribution of organic carbon (OC), 29%, and elemental carbon (EC), 19%, to total PM 2.5 mass. The lowest concentrations of PM 2.5 mass, OC, and EC were measured at southern desert sites, located in Aqaba, Eilat, and Rachma. The OC contribution to PM 2.5 mass at these sites ranged between 9.4% and 16%, with mean annual PM 2.5 mass concentrations ranging from 21 to 25 ug m -3. These sites were also observed to have the highest OC to EC ratios (4.1-5.0), indicative of smaller contributions from primary combustion sources and/or a higher contribution of secondary organic aerosol. Biomass burning and vehicular emissions were found to be important sources of carbonaceous PM in this region at the non-southern desert sites, which together accounted for 30%-55% of the fine particle organic carbon at these sites. The fraction of measured OC unapportioned to primary sources (1.4 μgC m -3 to 4.9 μgC m -3; 30%-74%), which has been shown to be largely from secondary organic aerosol, is relatively constant at the sites examined in this study. This suggests that secondary organic aerosol is important in the Middle East during all seasons of the year.

The use of amino acid indices for assessing organic matter quality and microbial abundance in deep-sea Antarctic sediments of IODP Expedition 318

USGS Publications Warehouse

Carr, Stephanie A; Mills, Christopher T.; Mandernack, Kevin W

2016-01-01

The Adélie Basin, located offshore of the Wilkes Land margin, experiences unusually high sedimentation rates (~ 2 cm yr− 1) for the Antarctic coast. This study sought to compare depthwise changes in organic matter (OM) quantity and quality with changes in microbial biomass with depth at this high-deposition site and an offshore continental margin site. Sediments from both sites were collected during the International Ocean Drilling (IODP) Program Expedition 318. Viable microbial biomass was estimated from concentrations of bacterial-derived phospholipid fatty acids, while OM quality was assessed using four different amino acid degradation proxies. Concentrations of total hydrolysable amino acids (THAA) measured from the continental margin suggest an oligotrophic environment, with THAA concentrations representing only 2% of total organic carbon with relative proportions of non-protein amino acids β-alanine and γ-aminobutyric acid as high as 40%. In contrast, THAA concentrations from the near-shore Adélie Basin represent 40%–60% of total organic carbon. Concentrations of β-alanine and γ-aminobutyric acid were often below the detection limit and suggest that the OM of the basin as labile. DI values in surface sediments at the Adélie and margin sites were measured to be + 0.78 and − 0.76, reflecting labile and more recalcitrant OM, respectively. Greater DI values in deeper and more anoxic portions of both cores correlated positively with increased relative concentrations of phenylalanine plus tyrosine and may represent a change of redox conditions, rather than OM quality. This suggests that DI values calculated along chemical profiles should be interpreted with caution. THAA concentrations, the percentage of organic carbon (CAA%) and total nitrogen (NAA%) represented by amino acids at both sites demonstrated a significant positive correlation with bacterial abundance estimates. These data suggest that the selective degradation of amino acids, as indicated by THAA concentrations, CAA% or NAA% values may be a better proxy for describing the general changes in sedimentary bacterial abundances than total organic matter or bulk sedimentation rates.

Selectivity of adsorption of gases on doped graphene

NASA Astrophysics Data System (ADS)

Nnabugwu, Jordan; Maiga, Sidi; Gatica, Silvina

We report our results on the selectivity of carbon dioxide being adsorbed onto doped graphene. Using the Ideal Adsorption Solution theory (IAST) we calculate the selectivity using the uptake pressures of pure gases. We focus on the adsorption of atmospheric gases such as carbon dioxide (CO2) , Nitrogen (N2) , and Methane (CH4) on a pure and doped monolayer graphene slab placed at the bottom of a simulation cell. Grand Canonical Monte Carlo (GCMC) simulations allow us to calculate the amount of gases adsorbed at a given temperature and pressure of the system. We found that including impurities of varying strength and concentration can increase significantly the selectivity at room temperature. Financial support from the National Science Foundation Research Experiences for Undergraduates Program for the REU Site in Physics at Howard University (NSF Award No. PHY-1358727) is gratefully acknowledged.

Geological Setting of Diamond Drilling for the Archean Biosphere Drilling Project, Pilbara Craton, Western Australia

NASA Astrophysics Data System (ADS)

Hickman, A.

2004-12-01

The Archean Biosphere Drilling Project (ABDP) is a collaborative international research project conducting systematic (bio)geochemical investigations to improve our understanding of the biosphere of the early Earth. The Pilbara Craton of Western Australia, which includes exceptionally well preserved 3.52 to 2.70 Ga sedimentary sequences, was selected for an innovative sampling program commencing in 2003. To avoid near-surface alteration and contamination effects, sampling was by diamond drilling to depths of between 150 and 300 m, and was located at sites where the target lithologies were least deformed and had lowest metamorphic grade (below 300°C). The first of five successful drilling sites (Jasper Deposit) targeted red, white and black chert in the 3.46 Ga Marble Bar Chert Member. This chert marks the top of a thick mafic-felsic volcanic cycle, the third of four such cycles formed by mantle plumes between 3.52 and 3.43 Ga. The geological setting was a volcanic plateau founded on 3.72 to 3.60 Ga sialic crust (isotopic evidence). The second hole (Salgash) was sited on the basal section of the fourth cycle, and sampled sulfidic (Cu-Zn-Fe), carbon-rich shale and sandstone units separated by flows of peridotite. The third hole (Eastern Creek) was sited on the margin of a moderately deep-water rift basin, the 2.95 to 2.91 Ga Mosquito Creek Basin. This is dominated by turbidites, but the sandstones and carbon-rich shales intersected at the drilling site were deposited in shallower water. The fourth and fifth holes, located 300 km apart, sampled 2.77 to 2.76 Ga continental formations of the Fortescue Group; both holes included black shales.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grigg, Reid; McPherson, Brian; Lee, Rober

The Southwest Regional Partnership on Carbon Sequestration (SWP) one of seven regional partnerships sponsored by the U.S. Department of Energy (USDOE) carried out five field pilot tests in its Phase II Carbon Sequestration Demonstration effort, to validate the most promising sequestration technologies and infrastructure concepts, including three geologic pilot tests and two terrestrial pilot programs. This field testing demonstrated the efficacy of proposed sequestration technologies to reduce or offset greenhouse gas emissions in the region. Risk mitigation, optimization of monitoring, verification, and accounting (MVA) protocols, and effective outreach and communication were additional critical goals of these field validation tests. Themore » program included geologic pilot tests located in Utah, New Mexico, Texas, and a region-wide terrestrial analysis. Each geologic sequestration test site was intended to include injection of a minimum of ~75,000 tons/year CO{sub 2}, with minimum injection duration of one year. These pilots represent medium- scale validation tests in sinks that host capacity for possible larger-scale sequestration operations in the future. These validation tests also demonstrated a broad variety of carbon sink targets and multiple value-added benefits, including testing of enhanced oil recovery and sequestration, enhanced coalbed methane production and a geologic sequestration test combined with a local terrestrial sequestration pilot. A regional terrestrial sequestration demonstration was also carried out, with a focus on improved terrestrial MVA methods and reporting approaches specific for the Southwest region.« less

Relationship of subseafloor microbial diversity to sediment age and organic carbon content

NASA Astrophysics Data System (ADS)

Walsh, E. A.; Kirkpatrick, J. B.; Sogin, M. L.; D'Hondt, S. L.

2013-12-01

Our tag pyrosequencing investigation of four globally distant sites reveals sediment age and total organic carbon content to be significant components in understanding subseafloor diversity. Our sampling locations include two sites from high-productivity regions (Indian Ocean and Bering Sea) and two from moderate-productivity (eastern and central equatorial Pacific Ocean). Sediment from the high-productivity sites has much higher TOC than sediment from the moderate-productivity equatorial sites. We applied a high-resolution 16S V4-V6 tag pyrosequencing approach to 24 bacterial and 17 archaeal samples, totaling 602,502 reads. We identified1,291 archaeal and 15,910 bacterial OTUs (97%) from these reads. We analyzed bacterial samples from all four sites in addition to archaeal samples from our high productivity sites. These high productivity, high TOC sites have a pronounced methane-rich sulfate-free zone at depth from which archaea have been previously considered to dominate (Biddle et al., 2006). At all four locations, microbial diversity is highest near the seafloor and drops rapidly to low but stable values with increasing sediment depth. The depth at which diversity stabilizes varies greatly from site to site, but the age at which it stabilizes is relatively constant. At all four sites, diversity reaches low stable values a few hundred thousand years after sediment deposition. The sites with high total organic carbon (high productivity sites) generally exhibit higher diversity at each sediment age than the sites with lower total organic carbon (moderate-productivity sites). Archaeal diversity is lower than bacterial diversity at every sampled depth. Biddle, J.F., Lipp, J.S., Lever, M.A., Lloyd, K.G., Sørensen, K.B., Anderson, R. et al. (2006) Heterotrophic Archaea dominate sedimentary subsurface ecosystems off Peru. PNAS 103: 3846-3851.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, L. M.

The Commodity Credit Corporation (CCC), an agency of the U.S. Department of Agriculture (USDA), operated grain storage facilities at two different locations at Everest, Kansas (Figure 1.1). One facility (referred to in this report as the Everest facility) was at the western edge of the city of Everest. The CCC/USDA operated this facility from 1950 until the early 1970s. The second facility (referred to in this report as Everest East) was about 0.5 mi northeast of the town. The CCC/USDA operated this facility from 1954 until the early 1970s. While these two former CCC/USDA grain storage facilities were in operation,more » commercial grain fumigants containing carbon tetrachloride were in common use by the CCC/USDA and the private grain storage industry to preserve grain. In 1997, the Kansas Department of Health and Environment (KDHE) sampled several domestic drinking water and nondrinking water wells in the Everest area. The KDHE sampling was part of the CCC/USDA Private Well Sampling Program, which was initiated to determine whether carbon tetrachloride was present in domestic wells near former CCC/USDA grain storage facilities in Kansas. All of the sampled domestic drinking water wells were located outside the Everest city boundaries. As a result of this sampling, carbon tetrachloride contamination was identified at a single domestic drinking water well (the Nigh well; DW06) approximately 3/8 mi northwest of the former Everest CCC/USDA grain storage facility. The CCC/USDA subsequently connected the Nigh residence to the Everest municipal water system. As a result of the detection of carbon tetrachloride in this well, the KDHE conducted preliminary investigations to further evaluate the existence of contamination and its potential effect on public health and the environment. The KDHE concluded that carbon tetrachloride in groundwater at Everest might, in part, be linked to historical use of carbon tetrachloride-based grain fumigants at the former CCC/USDA facilities. For this reason, the CCC/USDA is conducting an environmental site investigation to determine the source(s) and extent of the carbon tetrachloride contamination at Everest and to assess whether the contamination requires remedial action. The investigation at Everest is being performed by the Environmental Research Division of Argonne National Laboratory. Argonne is a nonprofit, multidisciplinary research center operated by the University of Chicago for the U.S. Department of Energy (DOE). The CCC/USDA has entered into an interagency agreement with DOE, under which Argonne provides technical assistance to the CCC/USDA with environmental site characterization and remediation at its former grain storage facilities. At these facilities, Argonne is applying its QuickSite{reg_sign} environmental site characterization methodology. This methodology has been applied successfully at a number of former CCC/USDA facilities in Kansas and Nebraska and has been adopted by the American Society for Testing and Materials (ASTM 1998) as standard practice for environmental site characterization. Phase I of the QuickSite{reg_sign} investigation examined the key geologic, hydrogeologic, and hydrogeochemical relationships that define potential contaminant migration pathways at Everest (Argonne 2001). Phase II of the QuickSite{reg_sign} investigation at Everest was undertaken with the primary goal of delineating and improving understanding of the distribution of carbon tetrachloride contamination in groundwater at this site and the potential source area(s) that might have contributed to this contamination. To address this goal, four specific technical objectives were developed to guide the Phase II field studies. Sampling of near-surface soils at the former Everest CCC/USDA facility that was originally planned for Phase I had to be postponed until October 2000 because of access restrictions. Viable vegetation was not available for sampling then. This period is termed the first session of Phase II field work at Everest. The main session of field work for the Phase II QuickSite{reg_sign} investigation of the Everest site began on March 6, 2001. Work was suspended at the site on April 6, 2001, (1) because of access limitations to key properties, located north and west of the former CCC/USDA facility, imposed by the private owners at the onset of the spring planting season and (2) to permit further documentation by Argonne, at the request of the CCC/USDA, of the land use and ownership history of the Nigh property as a precursor to completion of the field work. This period is termed the second session of Phase II field work at Everest. Investigation of the Nigh property history was prompted by groundwater contamination evidence obtained during the second session of Phase II field activities (discussed in Section 3.7).« less

Impacts of ocean acidification on coral calcification: experimental results from a field study around submarine springs

NASA Astrophysics Data System (ADS)

Paytan, A.; Martínez Fernández, A.; Varona, N.

2017-12-01

Reef building corals are facing the effects of ocean acidification on calcification. Atmospheric carbon dioxide dissolves into the oceans and decreases the pH and the availability of carbonate ions in seawater. Carbonate ions are used by calcifying corals to create their calcium carbonate exoskeletons in the form of aragonite. As carbon dioxide emissions increase, corals may have problems precipitating their aragonite skeleton in low carbonate saturation seawater. Natural submarine groundwater springs discharge low pH seawater into the Caribbean Sea, in the Yucatan Peninsula (Mexico). These submarine springs serve as a natural laboratory to study the effects of low aragonite saturation water on coral growth. Here we show the skeletal growth parameters of three coral species under an in situ ocean acidification experiment. Nubbins of Porites porites, Porites astreoides and Siderastrea radians were collected at low pH springs and control sites and reciprocally transplanted into a low pH discharge site and into a control site not impacted by discharge. After two years, the nubbins were collected and linear extension, density and calcification rates were analyzed. Preliminary results show that coral skeleton density is significantly lower in corals transplanted into the low pH than in corals transplanted in control sites. Infaunal bioerosion is present in corals deployed at low pH sites. In contrast, linear extension and hence calcification rates do not seem to show a significant difference among sites. However, the coral species show diverse calcification responses under ocean acidification conditions, suggesting some species may be more vulnerable than others to a change in water chemistry.

Carbon sequestration pilot program : estimated land available for carbon sequestration in the national highway system

DOT National Transportation Integrated Search

2010-05-01

The Federal Highway Administration (FHWA) established the Carbon Sequestration Pilot Program (CSPP) in 2008 to assess whether a roadside carbon sequestration effort through modified maintenance and management practices is appropriate and feasible for...

Water-quality assessment of the Ozark Plateaus study unit, Arkansas, Kansas, Missouri, and Oklahoma; nutrients, bacteria, organic carbon, and suspended sediment in surface water, 1993-95

USGS Publications Warehouse

Davis, Jerri V.; Bell, Richard W.

1998-01-01

Nutrient, bacteria, organic carbon, and suspended- sediment samples were collected from 1993-95 at 43 surface-water-quality sampling sites within the Ozark Plateaus National Water- Quality Assessment Program study unit. Most surface-water-quality sites have small or medium drainage basins, near-homogenous land uses (primarily agricultural or forest), and are located predominantly in the Springfield and Salem Plateaus. The water-quality data were analyzed using selected descriptive and statistical methods to determine factors affecting occurrence in streams in the study unit. Nitrogen and phosphorus fertilizer use increased in the Ozark Plateaus study unit for the period 1965-85, but the application rates are well below the national median. Fertilizer use differed substantially among the major river basins and physiographic areas in the study unit. Livestock and poultry waste is a major source of nutrient loading in parts of the study unit. The quantity of nitrogen and phosphorus from livestock and poultry wastes differed substantially among the river basins of the study unit's sampling network. Eighty six municipal sewage-treatment plants in the study unit have effluents of 0.5 million gallons per day or more (for the years 1985-91). Statistically significant differences existed in surface-water quality that can be attributed to land use, physiography, and drainage basin size. Dissolved nitrite plus nitrate, total phosphorus, fecal coliform bacteria, and dissolved organic carbon concentrations generally were larger at sites associated with agricultural basins than at sites associated with forested basins. A large difference in dissolved nitrite plus nitrate concentrations occurred between streams draining basins with agricultural land use in the Springfield and Salem Plateaus. Streams draining both small and medium agricultural basins in the Springfield Plateau had much larger concentrations than their counterparts in the Salem Plateau. Drainage basin size was not a significant factor in affecting total phosphorus, fecal coliform bacteria, or dissolved organic carbon concentrations. Suspended-sediment concentrations generally were small and indicative of the clear water in streams in the Ozark Plateaus. A comparison of the dissolved nitrite plus nitrate, total phosphorus, and fecal coliform data collected at the fixed and synoptic sites indicates that generally the data for streams draining basins of similar physiography, land-use setting, and drainage basin size group together. Many of the variations are most likely the result of differences in percent agricultural land use between the sites being compared or are discharge related. The relation of dissolved nitrite plus nitrate, total phosphorus, and fecal coliform concentration to percent agricultural land use has a strong positive 2 Water-Quality Assessment-Nutrients, Bacteria, Organic Carbon, and Suspended Sediment in Surface Water, 1993-95 correlation, with percent agricultural land use accounting for between 42 and 60 percent of the variation in the observed concentrations.

Cyclic occurrence of fire and its role in carbon dynamics along an edaphic moisture gradient in longleaf pine ecosystems.

PubMed

Whelan, Andrew; Mitchell, Robert; Staudhammer, Christina; Starr, Gregory

2013-01-01

Fire regulates the structure and function of savanna ecosystems, yet we lack understanding of how cyclic fire affects savanna carbon dynamics. Furthermore, it is largely unknown how predicted changes in climate may impact the interaction between fire and carbon cycling in these ecosystems. This study utilizes a novel combination of prescribed fire, eddy covariance (EC) and statistical techniques to investigate carbon dynamics in frequently burned longleaf pine savannas along a gradient of soil moisture availability (mesic, intermediate and xeric). This research approach allowed us to investigate the complex interactions between carbon exchange and cyclic fire along the ecological amplitude of longleaf pine. Over three years of EC measurement of net ecosystem exchange (NEE) show that the mesic site was a net carbon sink (NEE = -2.48 tonnes C ha(-1)), while intermediate and xeric sites were net carbon sources (NEE = 1.57 and 1.46 tonnes C ha(-1), respectively), but when carbon losses due to fuel consumption were taken into account, all three sites were carbon sources (10.78, 7.95 and 9.69 tonnes C ha(-1) at the mesic, intermediate and xeric sites, respectively). Nonetheless, rates of NEE returned to pre-fire levels 1-2 months following fire. Consumption of leaf area by prescribed fire was associated with reduction in NEE post-fire, and the system quickly recovered its carbon uptake capacity 30-60 days post fire. While losses due to fire affected carbon balances on short time scales (instantaneous to a few months), drought conditions over the final two years of the study were a more important driver of net carbon loss on yearly to multi-year time scales. However, longer-term observations over greater environmental variability and additional fire cycles would help to more precisely examine interactions between fire and climate and make future predictions about carbon dynamics in these systems.

Cyclic Occurrence of Fire and Its Role in Carbon Dynamics along an Edaphic Moisture Gradient in Longleaf Pine Ecosystems

PubMed Central

Whelan, Andrew; Mitchell, Robert; Staudhammer, Christina; Starr, Gregory

2013-01-01

Fire regulates the structure and function of savanna ecosystems, yet we lack understanding of how cyclic fire affects savanna carbon dynamics. Furthermore, it is largely unknown how predicted changes in climate may impact the interaction between fire and carbon cycling in these ecosystems. This study utilizes a novel combination of prescribed fire, eddy covariance (EC) and statistical techniques to investigate carbon dynamics in frequently burned longleaf pine savannas along a gradient of soil moisture availability (mesic, intermediate and xeric). This research approach allowed us to investigate the complex interactions between carbon exchange and cyclic fire along the ecological amplitude of longleaf pine. Over three years of EC measurement of net ecosystem exchange (NEE) show that the mesic site was a net carbon sink (NEE = −2.48 tonnes C ha−1), while intermediate and xeric sites were net carbon sources (NEE = 1.57 and 1.46 tonnes C ha−1, respectively), but when carbon losses due to fuel consumption were taken into account, all three sites were carbon sources (10.78, 7.95 and 9.69 tonnes C ha−1 at the mesic, intermediate and xeric sites, respectively). Nonetheless, rates of NEE returned to pre-fire levels 1–2 months following fire. Consumption of leaf area by prescribed fire was associated with reduction in NEE post-fire, and the system quickly recovered its carbon uptake capacity 30–60 days post fire. While losses due to fire affected carbon balances on short time scales (instantaneous to a few months), drought conditions over the final two years of the study were a more important driver of net carbon loss on yearly to multi-year time scales. However, longer-term observations over greater environmental variability and additional fire cycles would help to more precisely examine interactions between fire and climate and make future predictions about carbon dynamics in these systems. PMID:23335986

Designing a Dynamic Data Driven Application System for Estimating Real-Time Load of DOC in a River

NASA Astrophysics Data System (ADS)

Ouyang, Y.; None

2011-12-01

Understanding the dynamics of naturally occurring dissolved organic carbon (DOC) in a river is central to estimating surface water quality, aquatic carbon cycling, and climate change. Currently, determination of DOC in surface water is primarily accomplished by manually collecting samples for laboratory analysis, which requires at least 24 hours. In other words, no effort has been devoted to monitoring real-time variations of DOC in a river due to the lack of suitable and/or cost-effective wireless sensors. However, when considering human health, carbon footprints, and effects of urbanization, industry, and agriculture on water resource supply, timely DOC information may be critical. We have developed here a new paradigm, a dynamic data driven application system (DDDAS), for estimating the real-time load of DOC into a river. This DDDAS consisted of the following four components: (1) a Visual Basic (VB) program for downloading US Geological Survey real-time chlorophyll and discharge data; (2) a STELLA model for evaluating real-time DOC load based on the relationship between chlorophyll a, DOC, and river discharge; (3) a batch file for linking the VB program and STELLA model; and (4) a Microsoft Windows Scheduled Tasks wizard for executing the model and displaying output on a computer screen at selected times. Results show that the real-time load of DOC into the St. Johns River basin near Satsuma, Putnam County, Florida, USA varied over a range from -13,143 to 29,248 kg/h at the selected site in Florida, USA. The negative loads occurred because of the back flow in the estuarine reach of the river. The cumulative load of DOC in the river for the selected site at the end of the simulation (178 hours) was about 1.2 tons. Our results support the utility of the DDDAS developed in this study for estimating the real-time variations of DOC in river ecosystems.

Tectonic control of the crustal organic carbon reservoir during the Precambrian

NASA Technical Reports Server (NTRS)

Des Marais, D. J.

1994-01-01

Carbon isotopic trends indicate that the crustal reservoir of reduced, organic carbon increased during the Proterozoic, particularly during periods of widespread continental rifting and orogeny. No long-term trends are apparent in the concentration of organic carbon in shales, cherts and carbonates. The age distribution of 261 sample site localities sampled for well-preserved sedimentary rocks revealed a 500-700-Ma periodicity which coincided with tectonic cycles. It is assumed that the numbers of sites are a proxy for mass of sediments. A substantial increase in the number of sites in the late Archean correlates with the first appearance between 2.9 and 2.5 Ga of extensive continental platforms and their associated sedimentation. It is proposed that the size of the Proterozoic crustal organic carbon reservoir has been modulated by tectonic control of the volume of sediments deposited in environments favorable for the burial and preservation of organic matter. Stepwise increases in this reservoir would have caused the oxidation state of the Proterozoic environment to increase in a stepwise fashion.

The impact of different management techniques on carbon balance of a pine stand after windthrow

NASA Astrophysics Data System (ADS)

Ziemblinska, Klaudia; Urbaniak, Marek; Merbold, Lutz; Chojnicki, Bogdan H.; Olejnik, Janusz

2015-04-01

Forest ecosystems cover approximately 1/3 of the global land area (and 29.8% in Poland). Since forests are constantly exposed to various types of disturbances - both natural and anthropogenic such as fires, wind, insects outbreaks or clear cuts - it is important to investigate the impact of such damages on the carbon dynamics. This becomes even more important due to the fact that future climate change will most likely result in a higher frequency and intensity of extreme climatic events. Even though wind damages cause large disturbances to forests only few places in the world exist where continuous measurements of carbon exchange (CO2) in windthrown sites are carried out. Besides the opportunity to assess the carbon dynamics following wind disturbance, there is an additional possibility of evaluating differences in post windthrow forest management practices. To fill this knowledge gap we set up two measuring stations in north-western Poland in the 500ha area of pine forest damaged by tornado in July 2012, to assess the impact of such disturbance on CO2 and H2O exchange by use of Eddy Covariance (EC) technique (Tlen I and Tlen II). Both sites are characterized by similar climatic as well as soil conditions and are located 3km from each other. While at the site Tlen I all biomass (coarse and fine woody debris were collected together with stumps) was removed and ploughed thereafter, at Tlen II only trunks and main branches were taken out from the site without ploughing. Total harvested biomass per hectare, as derived from local forest inventory, were almost 18 % higher at Tlen I than Tlen II site (where uprooted stumps were left to decompose). First analysis of the eddy covariance data shows that both sites are significant carbon sources. Emissions of carbon dioxide from the non-ploughed site (Tlen II) are higher than from the ploughed site (Tlen I). Both sites released more than 8.1 t of CO2 per ha during a three month time period (mid July to mid August 2014) after being prepared for reforestation as described above . Future analysis and continuation of the measurements will help to answer the following remaining questions: How does the carbon flux change in time at both sites? When does either system reach a compensation point (NEP0)? How large are the differences in CO2 loss between both sites? Which management technique appears to be more "carbon friendly" (less CO2 released to the atmosphere per decade). If these questions are answered they will allow to adapt current post-windthrow management activities and provide potential mitigation abilities in disturbed forest ecosystems.

Ecosystem Carbon Storage in Alpine Grassland on the Qinghai Plateau

PubMed Central

Liu, Shuli; Zhang, Fawei; Du, Yangong; Guo, Xiaowei; Lin, Li; Li, Yikang; Li, Qian; Cao, Guangmin

2016-01-01

The alpine grassland ecosystem can sequester a large quantity of carbon, yet its significance remains controversial owing to large uncertainties in the relative contributions of climate factors and grazing intensity. In this study we surveyed 115 sites to measure ecosystem carbon storage (both biomass and soil) in alpine grassland over the Qinghai Plateau during the peak growing season in 2011 and 2012. Our results revealed three key findings. (1) Total biomass carbon density ranged from 0.04 for alpine steppe to 2.80 kg C m-2 for alpine meadow. Median soil organic carbon (SOC) density was estimated to be 16.43 kg C m-2 in alpine grassland. Total ecosystem carbon density varied across sites and grassland types, from 1.95 to 28.56 kg C m-2. (2) Based on the median estimate, the total carbon storage of alpine grassland on the Qinghai Plateau was 5.14 Pg, of which 94% (4.85 Pg) was soil organic carbon. (3) Overall, we found that ecosystem carbon density was affected by both climate and grazing, but to different extents. Temperature and precipitation interaction significantly affected AGB carbon density in winter pasture, BGB carbon density in alpine meadow, and SOC density in alpine steppe. On the other hand, grazing intensity affected AGB carbon density in summer pasture, SOC density in alpine meadow and ecosystem carbon density in alpine grassland. Our results indicate that grazing intensity was the primary contributing factor controlling carbon storage at the sites tested and should be the primary consideration when accurately estimating the carbon storage in alpine grassland. PMID:27494253

Ecosystem Carbon Storage in Alpine Grassland on the Qinghai Plateau.

PubMed

Liu, Shuli; Zhang, Fawei; Du, Yangong; Guo, Xiaowei; Lin, Li; Li, Yikang; Li, Qian; Cao, Guangmin

2016-01-01

The alpine grassland ecosystem can sequester a large quantity of carbon, yet its significance remains controversial owing to large uncertainties in the relative contributions of climate factors and grazing intensity. In this study we surveyed 115 sites to measure ecosystem carbon storage (both biomass and soil) in alpine grassland over the Qinghai Plateau during the peak growing season in 2011 and 2012. Our results revealed three key findings. (1) Total biomass carbon density ranged from 0.04 for alpine steppe to 2.80 kg C m-2 for alpine meadow. Median soil organic carbon (SOC) density was estimated to be 16.43 kg C m-2 in alpine grassland. Total ecosystem carbon density varied across sites and grassland types, from 1.95 to 28.56 kg C m-2. (2) Based on the median estimate, the total carbon storage of alpine grassland on the Qinghai Plateau was 5.14 Pg, of which 94% (4.85 Pg) was soil organic carbon. (3) Overall, we found that ecosystem carbon density was affected by both climate and grazing, but to different extents. Temperature and precipitation interaction significantly affected AGB carbon density in winter pasture, BGB carbon density in alpine meadow, and SOC density in alpine steppe. On the other hand, grazing intensity affected AGB carbon density in summer pasture, SOC density in alpine meadow and ecosystem carbon density in alpine grassland. Our results indicate that grazing intensity was the primary contributing factor controlling carbon storage at the sites tested and should be the primary consideration when accurately estimating the carbon storage in alpine grassland.

Placing barrier-island transgression in a blue-carbon context

NASA Astrophysics Data System (ADS)

Theuerkauf, Ethan J.; Rodriguez, Antonio B.

2017-07-01

Backbarrier saltmarshes are considered carbon sinks; however, barrier island transgression and the associated processes of erosion and overwash are typically not included in coastal carbon budgets. Here, we present a carbon-budget model for transgressive barrier islands that includes a dynamic carbon-storage term, driven by backbarrier-marsh width, and a carbon-export term, driven by ocean and backbarrier shoreline erosion. To examine the impacts of storms, human disturbances and the backbarrier setting of a transgressive barrier island on carbon budgets and reservoirs, the model was applied to sites at Core Banks and Onslow Beach, NC, USA. Results show that shoreline erosion and burial of backbarrier marsh from washover deposition and dredge-spoil disposal temporarily transitioned each site into a net exporter (source) of carbon. The magnitude of the carbon reservoir was linked to the backbarrier setting of an island. Carbon reservoirs of study sites separated from the mainland by only backbarrier marsh (no lagoon) decreased for over a decade because carbon storage could not keep pace with erosion. With progressive narrowing of the backbarrier marsh, these barriers will begin to function more persistently as carbon sources until the reservoir is depleted at the point where the barrier welds with the mainland. Undeveloped barrier islands with wide lagoons are carbon sources briefly during erosive periods; however, at century time scales are net carbon importers (sinks) because new marsh habitat can form during barrier rollover. Human development on backbarrier saltmarsh serves to reduce the carbon storage capacity and can hasten the transition of an island from a sink to a source.

Soil organic carbon dynamics of black locust plantations in the middle Loess Plateau area of China

NASA Astrophysics Data System (ADS)

Lu, N.; Liski, J.; Chang, R. Y.; Akujärvi, A.; Wu, X.; Jin, T. T.; Wang, Y. F.; Fu, B. J.

2013-11-01

Soil organic carbon (SOC) is the largest terrestrial carbon pool and sensitive to land use and cover change; its dynamics are critical for carbon cycling in terrestrial ecosystems and the atmosphere. In this study, we combined a modeling approach and field measurements to examine the temporal dynamics of SOC following afforestation (Robinia pseudoacacia) of former arable land at six sites under different climatic conditions in the Loess Plateau during 1980-2010, where the annual mean precipitation ranging from 450 mm to 600 mm. The results showed that the measured mean SOC increased to levels higher than before afforestation when taking the last measurements (i.e., at age 25 to 30 yr) at all the sites, although it decreased at the wetter sites in the first few years. The accumulation rates of SOC were 1.58 to 6.22% yr-1 in the upper 20 cm and 1.62 to 5.15% yr-1in the upper 40 cm of soil. The simulations reproduced the basic characteristics of measured SOC dynamics, suggesting that litter input and climatic factors (temperature and precipitation) were the major causes for SOC dynamics and the differences among the sites. They explained 88-96, 48-86 and 57-74% of the variations in annual SOC changes at the soil depths of 0-20, 0-40, and 0-100 cm, respectively. Notably, the simulated SOC decreased during the first few years at all the sites, although the magnitudes of decreases were smaller at the drier sites. This suggested that the modeling may be advantageous in capturing SOC changes at finer timescale. The discrepancy between the simulation and measurement was a result of uncertainties in model structure, data input, and sampling design. Our findings indicated that afforestation promoted soil carbon sequestration at the study sites during 1980-2010. Afforestation activities should decrease soil disturbances to reduce carbon release in the early stage. The long-term strategy for carbon fixation capability of the plantations should also consider the climate and site conditions, species adaptability, and successional stage of recovery.

Position-specific 13C distributions within propane from experiments and natural gas samples

NASA Astrophysics Data System (ADS)

Piasecki, Alison; Sessions, Alex; Lawson, Michael; Ferreira, A. A.; Santos Neto, E. V.; Ellis, Geoffrey S.; Lewan, Michael D.; Eiler, John M.

2018-01-01

Site-specific carbon isotope measurements of organic compounds potentially recover information that is lost in a conventional, 'bulk' isotopic analysis. Such measurements are useful because isotopically fractionating processes may have distinct effects at different molecular sites, and thermodynamically equilibrated populations of molecules tend to concentrate heavy isotopes in one molecular site versus another. Most recent studies of site-specific 13C in organics use specialized Nuclear Magnetic Resonance (NMR) techniques or complex chemical degradations prior to mass spectrometric measurements. Herein we present the first application of a new mass spectrometric technique that reconstructs the site-specific carbon isotope composition of propane based on measurements of the 13C/12C ratios of two or more fragment ions that sample different proportions of the terminal and central carbon sites. We apply this method to propane from laboratory experiments and natural gas samples to explore the relationships between site-specific carbon isotope composition, full-molecular δ13C, thermal maturity, and variation in organic matter precursors. Our goal is to advance the understanding of the sources and histories of short-chain alkanes within geologic systems. Our findings suggest that propane varies in its site-specific carbon isotope structure, which is correlated with increasing thermal maturity, first increasing in terminal position δ13C and then increasing in both center and terminal position δ13C. This pattern is observed in both experimental and natural samples, and is plausibly explained by a combination of site-specific, temperature-dependent isotope effects associated with conversion of different precursor molecules (kerogen, bitumen, and/or oil) to propane, differences in site-specific isotopic contents of those precursors, and possibly distillation of reactive components of those precursors with increasing maturity. We hypothesize that the largest changes in site-specific isotopic content of propane occur when bitumen and/or oil replace kerogen as the dominant precursors. If correct, this phenomenon could have significant utility for understanding gas generation in thermogenic petroleum systems.

Position-specific 13C distributions within propane from experiments and natural gas samples

USGS Publications Warehouse

Piasecki, Alison; Sessions, Alex L.; Lawson, Michael; Ferreira, A.A.; Santos Neto, E. V.; Ellis, Geoffrey S.; Lewan, Michael; Eilers, J.M.

2018-01-01

Site-specific carbon isotope measurements of organic compounds potentially recover information that is lost in a conventional, ‘bulk’ isotopic analysis. Such measurements are useful because isotopically fractionating processes may have distinct effects at different molecular sites, and thermodynamically equilibrated populations of molecules tend to concentrate heavy isotopes in one molecular site versus another. Most recent studies of site-specific 13C in organics use specialized Nuclear Magnetic Resonance (NMR) techniques or complex chemical degradations prior to mass spectrometric measurements. Herein we present the first application of a new mass spectrometric technique that reconstructs the site-specific carbon isotope composition of propane based on measurements of the 13C/12C ratios of two or more fragment ions that sample different proportions of the terminal and central carbon sites. We apply this method to propane from laboratory experiments and natural gas samples to explore the relationships between site-specific carbon isotope composition, full-molecular δ13C, thermal maturity, and variation in organic matter precursors. Our goal is to advance the understanding of the sources and histories of short-chain alkanes within geologic systems. Our findings suggest that propane varies in its site-specific carbon isotope structure, which is correlated with increasing thermal maturity, first increasing in terminal position δ13C and then increasing in both center and terminal position δ13C. This pattern is observed in both experimental and natural samples, and is plausibly explained by a combination of site-specific, temperature-dependent isotope effects associated with conversion of different precursor molecules (kerogen, bitumen, and/or oil) to propane, differences in site-specific isotopic contents of those precursors, and possibly distillation of reactive components of those precursors with increasing maturity. We hypothesize that the largest changes in site-specific isotopic content of propane occur when bitumen and/or oil replace kerogen as the dominant precursors. If correct, this phenomenon could have significant utility for understanding gas generation in thermogenic petroleum systems.

Deep-sea Benthic Foraminifera in the SE Atlantic across Eocene Hyperthermal Events

NASA Astrophysics Data System (ADS)

Thomas, E.

2016-12-01

Short-term episodes of global warming (hyperthermal events) were superimposed on the warming trend into the Early Eocene Climate Optimum (EECO). The Paleocene-Eocene Thermal Maximum (PETM; 56 Ma) was the most extreme, followed by Eocene Thermal Maximum-2 and -3 (ETM2: 1.8 myr, ETM3: 3.1 myr post-PETM). Hyperthermals are characterized by negative carbon isotope excursions (CIEs, emission of isotopically light carbon in the ocean-atmosphere), negative oxygen isotope excursions (global warming) and carbonate dissolution (ocean acidification). Sensitivity of biota to environmental changes due to carbon emissions can be evaluated by studying their response to hyperthermals of different magnitude. Deep-sea benthic foraminiferal records across PETM, ETM2 and -3 are available for Site 1262 (3600 m) and 1263 (1500m) on SE Atlantic Walvis Ridge. Benthic foraminifera (carbonate and agglutinated) are absent in the carbonate-free PETM clay-layer (Site 1262: 65 kyr; Site1263: 10 kyr). Deep-sea benthic foraminifera suffered extinction and diversity loss at the start of the PETM, as they did globally, with diversity recovering only partially. Stable isotope records show a larger PETM-CIE and amount of warming at Site 1263 than global average (McCarren et al., 2008), and warming was more pronounced at Site 1263 than at 1262 during ETM2 (Jennions et al., 2015) and ETM3 (Roehl et al., 2005). During ETM2 and -3, carbonate dissolution affected the sites, both remaining between CCD and lysocline. Assemblages were more severely affected (larger drop in benthic foraminiferal accumulation rates, BFAR) at the shallower site, opposite to expected if caused mainly by carbonate corrosivity. The large decrease in BFAR indicates a decline in food arrival at the sea floor, more pronounced at the shallower site, as supported by changes in relative and absolute abundance of species, and more pronounced at ETM2 than at ETM3. Greater warming at intermediate depths could have been caused by ocean circulation changes, with the greater warming more severely affecting metabolic rates of benthic foraminifera, thus patterns of effective food supply, species and diversity change. Roehl et al. 2005 GSA Abstr. 37: 264. McCarren et al. 2008 G3, 9 (10): Q10008. Jennions et al. 2015 Paleoceanogr. 30: 1059-1077

BOREAS TGB-12 Soil Carbon Data over the NSA

NASA Technical Reports Server (NTRS)

Trumbore, Susan; Hall, Forrest G. (Editor); Conrad, Sara K. (Editor); Harden, Jennifer; Sundquist, Eric; Winston, Greg

2000-01-01

The BOREAS TGB-12 team made measurements of soil carbon inventories, carbon concentration in soil gases, and rates of soil respiration at several sites to estimate the rates of carbon accumulation and turnover in each of the major vegetation types. TGB-12 data sets include soil properties at tower and selected auxiliary sites in the BOREAS NSA and data on the seasonal variations in the radiocarbon content of CO2 in the soil atmosphere at NSA tower sites. The sampling strategies for soils were designed to take advantage of local fire chronosequences, so that the accumulation of C in areas of moss regrowth could be determined. These data are used to calculate the inventory of C and N in moss and mineral soil layers at NSA sites and to determine the rates of input and turnover (using both accumulation since the last stand-killing fire and radiocarbon data). This data set includes physical parameters needed to determine carbon and nitrogen inventory in soils. The data were collected discontinuously from August 1993 to July 1996. The data are stored in tabular ASCII files.

The impact of climate and reservoirs on longitudinal riverine carbon fluxes from two major watersheds in the Central and Intermontane West

USGS Publications Warehouse

Stackpoole, Sarah M.; Stets, Edward G.; Striegl, Robert G.

2014-01-01

A nested sampling network on the Colorado (CR) and Missouri Rivers (MR) provided data to assess impacts of large-scale reservoir systems and climate on carbon export. The Load Estimator (LOADEST) model was used to estimate both dissolved inorganic and organic carbon (DIC and DOC) fluxes for a total of 22 sites along the main stems of the CR and MR. Both the upper CR and MR DIC and DOC fluxes increased longitudinally, but the lower CR fluxes decreased while the lower MRs continued to increase. We examined multiple factors through space and time that help explain these flux patterns. Seasonal variability in precipitation and temperature, along with site-level concentration versus discharge relationships proved to be significant factors explaining much of the difference among sites located below reservoirs as compared to sites located in more free-flowing segments of the river. The characterization of variability in carbon exports over space and time provides a basis for understanding carbon cycling and transport within river basins affected by large reservoir systems, particular in arid-to semi-arid ecosystems.

Method of CO and/or CO.sub.2 hydrogenation using doped mixed-metal oxides

DOEpatents

Shekhawat, Dushyant; Berry, David A.; Haynes, Daniel J.; Abdelsayed, Victor; Smith, Mark W.; Spivey, James J.

2015-10-06

A method of hydrogenation utilizing a reactant gas mixture comprising a carbon oxide and a hydrogen agent, and a hydrogenation catalyst comprising a mixed-metal oxide containing metal sites supported and/or incorporated into the lattice. The mixed-metal oxide comprises a perovskite, a pyrochlore, a fluorite, a brownmillerite, or mixtures thereof doped at the A-site or the B-site. The metal site may comprise a deposited metal, where the deposited metal is a transition metal, an alkali metal, an alkaline earth metal, or mixtures thereof. Contact between the carbon oxide, hydrogen agent, and hydrogenation catalyst under appropriate conditions of temperature, pressure and gas flow rate generate a hydrogenation reaction and produce a hydrogenated product made up of carbon from the carbon oxide and some portion of the hydrogen agent. The carbon oxide may be CO, CO.sub.2, or mixtures thereof and the hydrogen agent may be H.sub.2. In a particular embodiment, the hydrogenated product comprises an alcohol, an olefin, an aldehyde, a ketone, an ester, an oxo-product, or mixtures thereof.

Feasibility Study of Carbon Sequestration Through Reforestation in the Chesapeake Bay Watershed of Virginia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Andy Lacatell; David Shoch; Bill Stanley

The Chesapeake Rivers conservation area encompasses approximately 2,000 square miles of agricultural and forest lands in four Virginia watersheds that drain to the Chesapeake Bay. Consulting a time series of classified Landsat imagery for the Chesapeake Rivers conservation area, the project team developed a GIS-based protocol for identifying agricultural lands that could be reforested, specifically agricultural lands that had been without forest since 1990. Subsequent filters were applied to the initial candidate reforestation sites, including individual sites > 100 acres and sites falling within TNC priority conservation areas. The same data were also used to produce an analysis of baselinemore » changes in forest cover within the study period. The Nature Conservancy and the Virginia Department of Forestry identified three reforestation/management models: (1) hardwood planting to establish old-growth forest, (2) loblolly pine planting to establish working forest buffer with hardwood planting to establish an old-growth core, and (3) loblolly pine planting to establish a working forest. To assess the relative carbon sequestration potential of these different strategies, an accounting of carbon and total project costs was completed for each model. Reforestation/management models produced from 151 to 171 tons carbon dioxide equivalent per acre over 100 years, with present value costs of from $2.61 to $13.28 per ton carbon dioxide equivalent. The outcome of the financial analysis was especially sensitive to the land acquisition/conservation easement cost, which represented the most significant, and also most highly variable, single cost involved. The reforestation/management models explored all require a substantial upfront investment prior to the generation of carbon benefits. Specifically, high land values represent a significant barrier to reforestation projects in the study area, and it is precisely these economic constraints that demonstrate the economic additionality of any carbon benefits produced via reforestation--these are outcomes over and above what is currently possible given existing market opportunities. This is reflected and further substantiated in the results of the forest cover change analysis, which demonstrated a decline in area of land in forest use in the study area for the 1987/88-2001 period. The project team collected data necessary to identify sites for reforestation in the study area, environmental data for the determining site suitability for a range of reforestation alternatives and has identified and addressed potential leakage and additionality issues associated with implementing a carbon sequestration project in the Chesapeake Rivers Conservation Area. Furthermore, carbon emissions reductions generated would have strong potential for recognition in existing reporting systems such as the U.S. Department of Energy 1605(b) voluntary reporting requirements and the Chicago Climate Exchange. The study identified 384,398 acres on which reforestation activities could potentially be sited. Of these candidate sites, sites totaling 26,105 acres are an appropriate size for management (> 100 acres) and located in priority conservation areas identified by The Nature Conservancy. Total carbon sequestration potential of reforestation in the study area, realized over a 100 year timeframe, ranges from 58 to 66 million tons of carbon dioxide equivalent, and on the priority sites alone, potential for carbon sequestration approaches or exceeds 4 million tons of carbon dioxide equivalent. In the absence of concerted reforestation efforts, coupled with policy strategies, the region will likely face continued declines in forest land.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Blystone, P.G.; Goltz, H.R.; Springer, J. Jr.

The reduction of volatile organic compound (VOC) emissions is a significant goal of the 1990 Clean Air Act. Industrial operations relating to surface preparation, surface coating and paint striping operations constitute one of the largest industrial sources of VOC emissions. This paper describes a new emission control system offered by Purus, Inc. which captures and recovers VOCs from paint stripping operations. The system is based on an on-site adsorption-desorption process which utilizes a specialized polymeric resin adsorbent. Adsorbent beds are regenerated through a computer controlled pressure-temperature swing process (PTSA). The adsorbent resin offers significant operational advantages over conventional activated carbonmore » adsorbents with respect to treating air laden with methyl ethyl ketone (MEK) vapors. Treatment of MEK with activated carbon can be problematic due to reactivity (degradation) and high heats of adsorption of ketones with carbon. The Purus process was successfully demonstrated at Tinker Air Force Base in or under the EPA`s Waste Reduction Evaluation at Federal Sites program. MEK emissions from a paint stripping booth vent were controlled at greater than 95% reduction levels. The recovered solvent was returned to depainting process and reused with no loss in paint stripping efficiency.« less

Carbon and nitrogen balances for six shrublands across Europe

NASA Astrophysics Data System (ADS)

Beier, Claus; Emmett, Bridget A.; Tietema, Albert; Schmidt, Inger K.; PeñUelas, Josep; LáNg, Edit KováCs; Duce, Pierpaolo; de Angelis, Paolo; Gorissen, Antonie; Estiarte, Marc; de Dato, Giovanbattista D.; Sowerby, Alwyn; KröEl-Dulay, GyöRgy; Lellei-KováCs, Eszter; Kull, Olevi; Mand, Pille; Petersen, Henning; Gjelstrup, Peter; Spano, Donatella

2009-12-01

Shrublands constitute significant and important parts of European landscapes providing a large number of important ecosystem services. Biogeochemical cycles in these ecosystems have gained little attention relative to forests and grassland systems, but data on such cycles are required for developing and testing ecosystem models. As climate change progresses, the potential feedback from terrestrial ecosystems to the atmosphere through changes in carbon stocks, carbon sequestration, and general knowledge on biogeochemical cycles becomes increasingly important. Here we present carbon and nitrogen balances of six shrublands along a climatic gradient across the European continent. The aim of the study was to provide a basis for assessing the range and variability in carbon storage in European shrublands. Across the sites the net carbon storage in the systems ranged from 1,163 g C m-2 to 18,546 g C m-2, and the systems ranged from being net sinks (126 g C m-2 a-1) to being net sources (-536 g C m-2 a-1) of carbon with the largest storage and sink of carbon at wet and cold climatic conditions. The soil carbon store dominates the carbon budget at all sites and in particular at the site with a cold and wet climate where soil C constitutes 95% of the total carbon in the ecosystem. Respiration of carbon from the soil organic matter pool dominated the carbon loss at all sites while carbon loss from aboveground litter decomposition appeared less important. Total belowground carbon allocation was more than 5 times aboveground litterfall carbon which is significantly greater than the factor of 2 reported in a global analysis of forest data. Nitrogen storage was also dominated by the soil pools generally showing small losses except when atmospheric N input was high. The study shows that in the future a climate-driven land cover change between grasslands and shrublands in Europe will likely lead to increased ecosystem C where shrublands are promoted and less where grasses are promoted. However, it also emphasizes that if feedbacks on the global carbon cycle are to be predicted it is critically important to quantify and understand belowground carbon allocation and processes as well as soil carbon pools, particularly on wet organic soils, rather than plant functional change as the soil stores dominate the overall budget and fluxes of carbon.

Terrestrial Contributions to the Aquatic Food Web in the Middle Yangtze River

PubMed Central

Wang, Jianzhu; Gu, Binhe; Huang, Jianhui; Han, Xingguo; Lin, Guanghui; Zheng, Fawen; Li, Yuncong

2014-01-01

Understanding the carbon sources supporting aquatic consumers in large rivers is essential for the protection of ecological integrity and for wildlife management. The relative importance of terrestrial and algal carbon to the aquatic food webs is still under intensive debate. The Yangtze River is the largest river in China and the third longest river in the world. The completion of the Three Gorges Dam (TGD) in 2003 has significantly altered the hydrological regime of the middle Yangtze River, but its immediate impact on carbon sources supporting the river food web is unknown. In this study, potential production sources from riparian and the main river channel, and selected aquatic consumers (invertebrates and fish) at an upstream constricted-channel site (Luoqi), a midstream estuarine site (Huanghua) and a near dam limnetic site (Maoping) of the TGD were collected for stable isotope (δ13C and δ15N) and IsoSource analyses. Model estimates indicated that terrestrial plants were the dominant carbon sources supporting the consumer taxa at the three study sites. Algal production appeared to play a supplemental role in supporting consumer production. The contribution from C4 plants was more important than that of C3 plants at the upstream site while C3 plants were the more important carbon source to the consumers at the two impacted sites (Huanghua and Maoping), particularly at the midstream site. There was no trend of increase in the contribution of autochthonous production from the upstream to the downstream sites as the flow rate decreased dramatically along the main river channel due to the construction of TGD. Our findings, along with recent studies in rivers and lakes, are contradictory to studies that demonstrate the importance of algal carbon in the aquatic food web. Differences in system geomorphology, hydrology, habitat heterogeneity, and land use may account for these contradictory findings reported in various studies. PMID:25047656

Terrestrial contributions to the aquatic food web in the middle Yangtze River.

PubMed

Wang, Jianzhu; Gu, Binhe; Huang, Jianhui; Han, Xingguo; Lin, Guanghui; Zheng, Fawen; Li, Yuncong

2014-01-01

Understanding the carbon sources supporting aquatic consumers in large rivers is essential for the protection of ecological integrity and for wildlife management. The relative importance of terrestrial and algal carbon to the aquatic food webs is still under intensive debate. The Yangtze River is the largest river in China and the third longest river in the world. The completion of the Three Gorges Dam (TGD) in 2003 has significantly altered the hydrological regime of the middle Yangtze River, but its immediate impact on carbon sources supporting the river food web is unknown. In this study, potential production sources from riparian and the main river channel, and selected aquatic consumers (invertebrates and fish) at an upstream constricted-channel site (Luoqi), a midstream estuarine site (Huanghua) and a near dam limnetic site (Maoping) of the TGD were collected for stable isotope (δ13C and δ15N) and IsoSource analyses. Model estimates indicated that terrestrial plants were the dominant carbon sources supporting the consumer taxa at the three study sites. Algal production appeared to play a supplemental role in supporting consumer production. The contribution from C4 plants was more important than that of C3 plants at the upstream site while C3 plants were the more important carbon source to the consumers at the two impacted sites (Huanghua and Maoping), particularly at the midstream site. There was no trend of increase in the contribution of autochthonous production from the upstream to the downstream sites as the flow rate decreased dramatically along the main river channel due to the construction of TGD. Our findings, along with recent studies in rivers and lakes, are contradictory to studies that demonstrate the importance of algal carbon in the aquatic food web. Differences in system geomorphology, hydrology, habitat heterogeneity, and land use may account for these contradictory findings reported in various studies.

Physically-based Canopy Reflectance Model Inversion of Vegetation Biophysical-Structural Information from Terra-MODIS Imagery in Boreal and Mountainous Terrain for Ecosystem, Climate and Carbon Models using the BIOPHYS-MFM Algorithm

NASA Astrophysics Data System (ADS)

Peddle, D. R.; Hall, F.

2009-12-01

The BIOPHYS algorithm provides innovative and flexible methods for the inversion of canopy reflectance models (CRM) to derive essential biophysical structural information (BSI) for quantifying vegetation state and disturbance, and for input to ecosystem, climate and carbon models. Based on spectral, angular, temporal and scene geometry inputs that can be provided or automatically derived, the BIOPHYS Multiple-Forward Mode (MFM) approach generates look-up tables (LUTs) that comprise reflectance data, structural inputs over specified or computed ranges, and the associated CRM output from forward mode runs. Image pixel and model LUT spectral values are then matched. The corresponding BSI retrieved from the LUT matches is output as the BSI results. BIOPHYS-MFM has been extensively used with agencies in Canada and the USA over the past decade (Peddle et al 2000-09; Soenen et al 2005-09; Gamon et al 2004; Cihlar et al 2003), such as CCRS, CFS, AICWR, NASA LEDAPS, BOREAS and MODIS Science Teams, and for the North American Carbon Program. The algorithm generates BSI products such as land cover, biomass, stand volume, stem density, height, crown closure, leaf area index (LAI) and branch area, crown dimension, productivity, topographic correction, structural change from harvest, forest fires and mountain pine beetle damage, and water / hydrology applications. BIOPHYS-MFM has been applied in different locations in Canada (six provinces from Newfoundland to British Columbia) and USA (NASA COVER, MODIS and LEDAPS sites) using 7 different CRM models and a variety of imagery (e.g. MODIS, Landsat, SPOT, IKONOS, airborne MSV, MMR, casi, Probe-1, AISA). In this paper we summarise the BIOPHYS-MFM algorithm and results from Terra-MODIS imagery from MODIS validation sites at Kananaskis Alberta in the Canadian Rocky Mountains, and from the Boreal Ecosystem Atmosphere Study (BOREAS) in Saskatchewan Canada. At the montane Rocky Mountain site, BIOPHYS-MFM density estimates were within ±380 stems/hectare (ha), with horizontal crown radius (HCR) ±0.4m, vertical crown radius (VCR) ±0.6m, and height (HGT) ±0.8m. At the BOREAS site, analysis of single-date MODIS imagery yielded density estimates within ±210 stems/ha, HCR ±0.3m, VCR ±0.5m, and HGT ±0.9m. Higher accuracies at BOREAS compared to the Rocky Mountain site were attributed primarily to the more complex terrain in the mountains, for which good results were obtained given the steep environmental, ecosystem, terrain and biophysical gradients. Further analysis of multiple BOREAS MODIS scenes with different view zenith angles provided convergence of BSI results, with improvements found for density (±42 stems/ha) and HCR (±0.2m). We concluded that good results from MODIS were obtained for both boreal and montane ecosystems. From this and other studies, BIOPHYS-MFM is well suited for large-area, multi-temporal applications involving multiple image sets and mosaics for assessing vegetation disturbance and quantifying vegetation dynamics for carbon and other models. It is also suitable for integration with forest inventory, monitoring and update needs, and other programs.

Seasonal variability of the carbonate system and coccolithophore Emiliania huxleyi at a Scottish Coastal Observatory monitoring site

NASA Astrophysics Data System (ADS)

León, Pablo; Walsham, Pam; Bresnan, Eileen; Hartman, Susan E.; Hughes, Sarah; Mackenzie, Kevin; Webster, Lynda

2018-03-01

Lack of information about carbonate chemistry in inshore waters is a 'knowledge gap' in assessing the impacts of changing carbonate chemistry on the marine environment. Assessing the response of calcifying phytoplankton to this changing carbonate chemistry requires a greater understanding of temporal variation. This study provides a description of the variability of carbonate parameters at a monitoring site in the eastern coast of Scotland. Four-years of monthly data were analysed to assess the diversity, abundance and morphometrics of coccolithophores in relation to carbonate chemistry and environmental variables. The seasonality in carbonate parameters reflected the seasonal cycle in phytoplankton activity, with higher total alkalinity concentrations and pH and lower dissolved inorganic carbon concentrations during the growing season. The dominant coccolithophore at the site was Emiliania huxleyi which showed a clear seasonal pattern, being more abundant in mid-summer when warmer and nutrient-depleted conditions restricted the annual diatom bloom. This study revealed the presence of three morphotypes of E. huxleyi, type A, type A overcalcified (type AO) and type B, which were seasonally distributed throughout the year. The less calcified form was mainly observed in spring while heavily calcified morphotypes overlapped during summer. Autumn and winter months were dominated by the most calcified form (type AO). These results indicate that the seasonal pattern of E. huxleyi morphotypes was not related to the carbonate concentration at the site. This study reflects the strong interannual variability in carbonate chemistry and the complexity associated with coccolithophore calcification, and highlights the need of long-term data to understand the potential impact of ocean acidification on calcifying phytoplankton.

Changes in deep-sea carbonate-hosted microbial communities associated with high and low methane flux

NASA Astrophysics Data System (ADS)

Case, D. H.; Steele, J. A.; Chadwick, G.; Mendoza, G. F.; Levin, L. A.; Orphan, V. J.

2012-12-01

Methane seeps on continental shelves are rich in authigenic carbonates built of methane-derived carbon. These authigenic carbonates are home to micro- and macroscopic communities whose compositions are thus far poorly constrained but are known to broadly depend on local methane flux. The formation of authigenic carbonates is itself a result of microbial metabolic activity, as associations of anaerobic methane oxidizing archaea (ANME) and sulfate reducing bacteria (SRB) in the sediment subsurface increase both dissolved inorganic carbon (DIC) and alkalinity in pore waters. This 1:1 increase in DIC and alkalinity promotes the precipitation of authigenic carbonates. In this study, we performed in situ manipulations to test the response of micro- and macrofaunal communities to a change in methane flux. Methane-derived authigenic carbonates from two locations at Hydrate Ridge, OR, USA (depth range 595-604 mbsl), were transplanted from "active" cold seep sites (high methane flux) to "inactive" background sites (low methane flux), and vise versa, for one year. Community diversity surveys using T-RFLP and 16S rRNA clone libraries revealed how both bacterial and archaeal assemblages respond to this change in local environment, specifically demonstrating reproducible shifts in different ANME groups (ANME-1 vs. ANME-2). Animal assemblage composition also shifted during transplantation; gastropod representation increased (relative to control rocks) when substrates were moved from inactive to active sites and polychaete, crustacean and echinoderm representation increased when substrates were moved from active to inactive sites. Combined with organic and inorganic carbon δ13C measurements and mineralogy, this unique in situ experiment demonstrates that authigenic carbonates are viable habitats, hosting microbial and macrofaunal communities capable of responding to changes in external environment over relatively short time periods.

Mesoscale carbon sequestration site screening and CCS infrastructure analysis.

PubMed

Keating, Gordon N; Middleton, Richard S; Stauffer, Philip H; Viswanathan, Hari S; Letellier, Bruce C; Pasqualini, Donatella; Pawar, Rajesh J; Wolfsberg, Andrew V

2011-01-01

We explore carbon capture and sequestration (CCS) at the meso-scale, a level of study between regional carbon accounting and highly detailed reservoir models for individual sites. We develop an approach to CO(2) sequestration site screening for industries or energy development policies that involves identification of appropriate sequestration basin, analysis of geologic formations, definition of surface sites, design of infrastructure, and analysis of CO(2) transport and storage costs. Our case study involves carbon management for potential oil shale development in the Piceance-Uinta Basin, CO and UT. This study uses new capabilities of the CO(2)-PENS model for site screening, including reservoir capacity, injectivity, and cost calculations for simple reservoirs at multiple sites. We couple this with a model of optimized source-sink-network infrastructure (SimCCS) to design pipeline networks and minimize CCS cost for a given industry or region. The CLEAR(uff) dynamical assessment model calculates the CO(2) source term for various oil production levels. Nine sites in a 13,300 km(2) area have the capacity to store 6.5 GtCO(2), corresponding to shale-oil production of 1.3 Mbbl/day for 50 years (about 1/4 of U.S. crude oil production). Our results highlight the complex, nonlinear relationship between the spatial deployment of CCS infrastructure and the oil-shale production rate.

Spatial variability of carbonaceous aerosol concentrations in East and West Jerusalem.

PubMed

von Schneidemesser, Erika; Zhou, Iiabin; Stone, Elizabeth A; Schauer, James I; Shpund, Jacob; Brenner, Shmuel; Qasrawi, Radwan; Abdeen, Ziad; Sarnat, Jeremy A

2010-03-15

Carbonaceous aerosol concentrations and sources were compared during a year long study at two sites in East and West Jerusalem that were separated by a distance of approximately 4 km. One in six day 24-h PM(2.5) elemental and organic carbon concentrations were measured, along with monthly average concentrations of particle-phase organic compound tracers for primary and secondary organic aerosol sources.Tracer compounds were used in a chemical mass balance ICMB) model to determine primary and secondary source contributions to organic carbon. The East Jerusalem sampling site at Al Quds University experienced higher concentrations of organic carbon (OC) and elemental carbon (EC) compared to the West Jerusalem site at Hebrew University. The annual average concentrations of OC and EC at the East Jerusalem site were 5.20 and 2.19 μg m(-3), respectively, and at the West Jerusalem site were 4.03 and 1.14 μg m(-3), respectively. Concentrations and trends of secondary organic aerosol and vegetative detritus were similar at both sites, but large differences were observed in the concentrations of organic aerosol from fossil fuel combustion and biomass burning, which was the cause of the large differences in OC and EC concentrations observed at the two sites.

Institutional Context of Carbon Cycle Science Research in the U.S. and North America - A SOCCR perspective

NASA Astrophysics Data System (ADS)

Shrestha, G.; Cavallaro, N.; Ste-Marie, C.

2016-12-01

Carbon cycle science has been a research priority in the U.S. for decades. Interagency coordination interests and research needs in U.S. carbon cycle science led to the establishment of the U.S. Carbon Cycle Science Program, the North American Carbon Program (NACP), the Ocean Carbon and Biogeochemistry Program (OCB) and other intergovernmental collaboration platforms such as CarboNA, involving the U.S., Mexico and Canada. This presentation highlights some of these activities, and the historical context, the institutional frameworks and the operational mechanisms that have helped to facilitate and advance large scale collaborative research in carbon cycle in the U.S. and North America.

Stepped Single Crystals as Improved Model for Supported Catalysts: Ethylene, Methanol and Assorted Molecules on PLATINUM(511) and PLATINUM(331)

NASA Astrophysics Data System (ADS)

Spaendonk, Vincent Van

Past research has shown unusual activity of the (1 x 1)Pt(110) surface to break carbon-carbon and carbon -oxygen bonds. Methane formation from ethylene or ethane has been reported for supported platinum catalysts. A model for the methane formation on (1 x 1)Pt(110), was proposed by Yagasaki. In this study, the mechanism of methane formation has been further investigated, and Yagasaki's model tested, by studying the decomposition of ethylene and methanol on the stepped surfaces Pt(511) and Pt(331) with Temperature Programmed Desorption. The experiments have been carried out in a Ultra High Vacuum system, equipped with a mass spectrometer, LEED and AES. Hydrogen and carbon monoxide desorption show that on Pt(511) different adsorption sites are available than on Pt(331). Ethylene decomposition on Pt(511) leads to small amounts of methane formation compared to (1 x 1)Pt(110). The metastable (1 x 1) phase of Pt(511) is 2-3 times more active than the stable (hex) phase. When ^{13}C_2H _4 is used, ^{13 }CH_4 is not detected. Methane formation is not seen on the Pt(331) surface. Arguments are given why Pt(511) is a superior model for supported catalysts compared to (1 x 1)Pt(110). The carbon-oxygen bond of methanol is not broken on either Pt(511) or Pt(331), whether the surface is clean or covered with oxygen. Hydrogen saturating the surface, prevents the chemisorption of ethylene and the formation of methane. Postadsorption of hydrogen does not lead to an increase in methane formation. Coadsorption of ethylene with carbon monoxide shows a maximum methane formation at 0.3 L carbon monoxide exposure. Poison experiments with 'oxide' and carbon indicate that the active site for methane formation is located at the step. The amount of carbon deposited during ethylene decomposition, increases in the order (1 x 1)Pt(511) to (hex)Pt(511) to Pt(331). This is also the order for decreasing methane activity. In a new model, it is proposed that in order to be active for methane formation, a surface has to prevent the polymerization of single carbon species to inactive graphite. The model predicts that surfaces with large enough (111) terraces have higher diffusion rates and allow the single carbon species to convert to graphite before the species can be hydrogenated.

Chemical compositions and precipitation timing of basement carbonate vein from fossil spreading ridge of South China Sea

NASA Astrophysics Data System (ADS)

Ding, W.; Chen, Y.

2016-12-01

Eighteen calcium carbonate veins within the igneous basement recovered close to the fossil spreading ridge of the South China Sea during the Integrated Ocean Drilling Program (IODP) Expedition 349 were investigated. These carbonates are of primarily either calcite or aragonite, or some mixed aragonite and calcite, with rarely ankerite. The chemical (Ca, Mg, Sr, Mn, Fe) contents and isotopic (87Sr/86Sr, δ18O, δ18C) compositions of the veins were determined to study the evolving chemistry of hydrothermal fluids and to constrain the timing of vein formation. The carbonate δ18O values range from -5.0 to -0.2 ‰ PDB, indicating these are typical low temperature basement carbonates. Chemical analyses show distinct Mg/Ca and Sr/Ca ratios for aragonite and calcite. 87Sr/86Sr ratios show negative correlations with both the depth and δ18O-calculated formation temperature, and are independent of mineralogy with both aragonite and calcite, indicating more geochemically evolved carbonated have precipitated from warmer fluids. The hightest 87Sr/86Sr ratios of vein samples at each drill site are believed to reflect the contemporaneous seawater compositions when carbonates precipitated. No unambiguous precipitation ages can be constrained by correlating 87Sr/86Sr ratios with the global seawater Sr isotope evolution. However, based on correlations of vein chemical composition with depth and formation temperature, as well as the Neogene post-spreading magmatism, we hypothesize 10 Ma is a particular time favoring the formation of carbonate veins in our study area.

Enhanced terrestrial weathering/runoff and surface ocean carbonate production during the recovery stages of the Paleocene-Eocene thermal maximum

NASA Astrophysics Data System (ADS)

Kelly, D. Clay; Zachos, James C.; Bralower, Timothy J.; Schellenberg, Stephen A.

2005-12-01

The carbonate saturation profile of the oceans shoaled markedly during a transient global warming event known as the Paleocene-Eocene thermal maximum (PETM) (circa 55 Ma). The rapid release of large quantities of carbon into the ocean-atmosphere system is believed to have triggered this intense episode of dissolution along with a negative carbon isotope excursion (CIE). The brevity (120-220 kyr) of the PETM reflects the rapid enhancement of negative feedback mechanisms within Earth's exogenic carbon cycle that served the dual function of buffering ocean pH and reducing atmospheric greenhouse gas levels. Detailed study of the PETM stratigraphy from Ocean Drilling Program Site 690 (Weddell Sea) reveals that the CIE recovery period, which postdates the CIE onset by ˜80 kyr, is represented by an expanded (˜2.5 m thick) interval containing a unique planktic foraminiferal assemblage strongly diluted by coccolithophore carbonate. Collectively, the micropaleontological and sedimentological changes preserved within the CIE recovery interval reflect a transient state when ocean-atmosphere chemistry fostered prolific coccolithophore blooms that suppressed the local lysocline to relatively deeper depths. A prominent peak in the abundance of the clay mineral kaolinite is associated with the CIE recovery interval, indicating that continental weathering/runoff intensified at this time as well (Robert and Kennett, 1994). Such parallel stratigraphic changes are generally consonant with the hypothesis that enhanced continental weathering/runoff and carbonate precipitation helped sequester carbon during the PETM recovery period (e.g., Dickens et al., 1997; Zachos et al., 2005).

Geologic datasets for weights-of-evidence analysis in northeast Washington: 2. Mineral databases

USGS Publications Warehouse

Boleneus, D.E.

1999-01-01

Digital mineral databases are necessary to carry out weights-of-evidence modeling of mineral resources for epithermal gold and carbonate-hosted lead-zinc deposits in northeast Washington. This report describes spreadsheet tables consisting of: 1) training sites for epithermal gold, 2) placer gold sites, 3) training sites for carbonate-hosted lead-zinc, and 4) small lead-zinc mines and prospects. A fifth table provides location data about sites in the four tables.

A Probabilistic Method of Assessing Carbon Accumulation Rate at Imnavait Creek Peatland, Arctic Long Term Ecological Research Station, Alaska

NASA Technical Reports Server (NTRS)

Nichols, Jonathan E.; Peteet, Dorothy M.; Frolking, Steve; Karavias, John

2017-01-01

Arctic peatlands are an important part of the global carbon cycle, accumulating atmospheric carbon as organic matter since the Late glacial. Current methods for understanding the changing efficiency of the peatland carbon sink rely on peatlands with an undisturbed stratigraphy. Here we present a method of estimating primary carbon accumulation rate from a site where permafrost processes have either vertically or horizontally translocated nearby carbon-rich sediment out of stratigraphic order. Briefly, our new algorithm estimates the probability of the age of deposition of a random increment of sediment in the core. The method assumes that if sediment age is measured at even depth increments, dates are more likely to occur during intervals of higher accumulation rate and vice versa. Multiplying estimated sedimentation rate by measured carbon density yields carbon accumulation rate. We perform this analysis at the Imnavait Creek Peatland, near the Arctic Long Term Ecological Research network site at Toolik Lake, Alaska. Using classical radiocarbon age modeling, we find unreasonably high rates of carbon accumulation at various Holocene intervals. With our new method, we find accumulation rate changes that are in improved agreement within the context of other sites throughout Alaska and the rest of the Circum-Arctic region.

Carbon Storage Patterns of Caragana korshinskii in Areas of Reduced Environmental Moisture on the Loess Plateau, China.

PubMed

Gong, Chunmei; Bai, Juan; Wang, Junhui; Zhou, Yulu; Kang, Tai; Wang, Jiajia; Hu, Congxia; Guo, Hongbo; Chen, Peilei; Xie, Pei; Li, Yuanfeng

2016-07-14

Precipitation patterns are influenced by climate change and profoundly alter the carbon sequestration potential of ecosystems. Carbon uptake by shrubbery alone accounts for approximately one-third of the total carbon sink; however, whether such uptake is altered by reduced precipitation is unclear. In this study, five experimental sites characterised by gradual reductions in precipitation from south to north across the Loess Plateau were used to evaluate the Caragana korshinskii's functional and physiological features, particularly its carbon fixation capacity, as well as the relationships among these features. We found the improved net CO2 assimilation rates and inhibited transpiration at the north leaf were caused by lower canopy stomatal conductance, which enhanced the instantaneous water use efficiency and promoted plant biomass as well as carbon accumulation. Regional-scale precipitation reductions over a certain range triggered a distinct increase in the shrub's organic carbon storage with an inevitable decrease in the soil's organic carbon storage. Our results confirm C. korshinskii is the optimal dominant species for the reconstruction of fragile dryland ecosystems. The patterns of organic carbon storage associated with this shrub occurred mostly in the soil at wetter sites, and in the branches and leaves at drier sites across the arid and semi-arid region.

Quantitative geochemical modeling along a transect off Peru: Carbon cycling in time and space, and the triggering factors for carbon loss and storage

NASA Astrophysics Data System (ADS)

Arning, Esther T.; van Berk, Wolfgang; Schulz, Hans-Martin

2012-12-01

Early diagenetic processes in Peruvian shelf and slope sediments are numerically reproduced by applying chemical thermodynamics in a complex, universal approach using the PHREEQC (version 2) computer code. The reaction kinetics of organic carbon remineralization are integrated into a set of equilibrium reactions by defining the type and the amount of converted organic matter in a certain time step. We calculate the most intense remineralization of organic carbon for present-day shelf sites, and the final carbon pool is dominated by secondary carbonates. This serves to highlight the influence of organic matter degradation and anaerobic oxidation of methane (AOM) on diagenetic mineral formation. The enrichment of aqueous methane and the formation of methane hydrate only takes place in slope sediments with high sedimentation rates that prevent diffusive loss of methane (e.g., Sites 682 and 688). Moreover, AOM prevents the diffusion of dissolved methane into overlying seawater. Throughout the Miocene period, these sites were located on a former shelf and the total carbon loss from the sediments was significantly higher in comparison with the present-day. Compared with the present-day shelf site, organic matter remineralization is high, and methane is produced but not stored within the sediments. Our model calculations rule out the possibility of present-day and former shelf site sediments off the coast of Peru as methane reservoirs. Remineralized TOC has to be considered, particularly in older sediments, when interpreting TOC profiles and calculating mass accumulation rates of total organic carbon (MARTOC). The more organic matter has been remineralized during the depositional history, the larger the difference between MARTOC calculated from measured TOC data, and from the sum of modeled and measured TOC data. Consequently, most reliable primary productivity calculations are based on the sum of measured relict TOC and the amount of remineralized organic carbon determined by modeling.

Site-specific equilibrium isotopic fractionation of oxygen, carbon and calcium in apatite

NASA Astrophysics Data System (ADS)

Aufort, Julie; Ségalen, Loïc; Gervais, Christel; Paulatto, Lorenzo; Blanchard, Marc; Balan, Etienne

2017-12-01

The stable isotope composition of biogenic apatite is an important geochemical marker that can record environmental parameters and is widely used to infer past climates, biomineralization processes, dietary preferences and habitat of vertebrates. In this study, theoretical equilibrium isotopic fractionation of oxygen, carbon and calcium in hydroxyapatite and carbonate-bearing hydroxyapatite is investigated using first-principles methods based on density-functional theory and compared to the theoretical isotopic fractionation properties of calcite, CO2 and H2O. Considering the variability of apatite crystal-chemistry, special attention is given to specific contributions of crystal sites to isotopic fractionation. Significant internal fractionation is calculated for oxygen and carbon isotopes in CO3 between the different structural sites occupied by carbonate groups in apatite (typically 7‰ for both 18O/16O and 13C/12C fractionation at 37 °C). Compared with calcite-water oxygen isotope fractionation, occurrence of A-type substitution in apatite structure, in addition to the main B-type substitution, could explain the larger temperature dependence of oxygen isotope fractionation measured at low temperature between carbonate in apatite and water. Theoretical internal fractionation of oxygen isotopes between carbonate and phosphate in B-type carbonated apatite (∼8‰ at 37 °C) is consistent with experimental values obtained from modern and well-preserved fossil bio-apatites. Concerning calcium, theoretical results suggest a small fractionation between apatite and calcite (-0.17‰ at 37 °C). Internal fractionation reaching 0.8‰ at 37 °C occurs between the two Ca sites in hydroxyapatite. Furthermore, the Ca isotopic fractionation properties of apatite are affected by the occurrence of carbonate groups, which could contribute to the variability observed on natural samples. Owing to the complexity of apatite crystal-chemistry and in light of the theoretical results, measurements of site-specific isotopic fractionation properties could improve our understanding and the interpretation of isotopic records in apatites.

BOREAS TGB-5 Dissolved Organic Carbon Data from NSA Beaver Ponds

NASA Technical Reports Server (NTRS)

Bourbonniere, Rick; Hall, Forrest G. (Editor); Conrad, Sara K. (Editor)

2000-01-01

The BOReal Ecosystem-Atmosphere Study Trace Gas Biogeochemistry (BOREAS TGB-5) team collected several data sets related to carbon and trace gas fluxes and concentrations in the Northern Study Area (NSA). This data set contains concentrations of dissolved organic and inorganic carbon species from water samples collected at various NSA sites. In particular, this set covers the NSA Tower Beaver Pond Site and the NSA Gillam Road Beaver Pond Site, including data from all visits to open water sampling locations during the BOREAS field campaigns from April to September 1994. The data are provided in tabular ASCII files.

Final Technical Report: The effects of climate, forest age, and disturbance history on carbon and water processes at AmeriFlux sites across gradients in Pacific Northwest forests

DOE Office of Scientific and Technical Information (OSTI.GOV)

Law, Beverly E.

Investigate the effects of disturbance and climate variables on processes controlling carbon and water processes at AmeriFlux cluster sites in semi-arid and mesic forests in Oregon. The observations were made at three existing and productive AmeriFlux research sites that represent climate and disturbance gradients as a natural experiment of the influence of climatic and hydrologic variability on carbon sequestration and resulting atmospheric CO 2 feedback that includes anomalies during the warm/ dry phase of the Pacific Decadal Oscillation.

Sorption of trivalent lanthanides and actinides onto montmorillonite: Macroscopic, thermodynamic and structural evidence for ternary hydroxo and carbonato surface complexes on multiple sorption sites.

PubMed

Fernandes, M Marques; Scheinost, A C; Baeyens, B

2016-08-01

The credibility of long-term safety assessments of radioactive waste repositories may be greatly enhanced by a molecular level understanding of the sorption processes onto individual minerals present in the near- and far-fields. In this study we couple macroscopic sorption experiments to surface complexation modelling and spectroscopic investigations, including extended X-ray absorption fine structure (EXAFS) and time-resolved laser fluorescence spectroscopies (TRLFS), to elucidate the uptake mechanism of trivalent lanthanides and actinides (Ln/An(III)) by montmorillonite in the absence and presence of dissolved carbonate. Based on the experimental sorption isotherms for the carbonate-free system, the previously developed 2 site protolysis non electrostatic surface complexation and cation exchange (2SPNE SC/CE) model needed to be complemented with an additional surface complexation reaction onto weak sites. The fitting of sorption isotherms in the presence of carbonate required refinement of the previously published model by reducing the strong site capacity and by adding the formation of Ln/An(III)-carbonato complexes both on strong and weak sites. EXAFS spectra of selected Am samples and TRLFS spectra of selected Cm samples corroborate the model assumptions by showing the existence of different surface complexation sites and evidencing the formation of Ln/An(III) carbonate surface complexes. In the absence of carbonate and at low loadings, Ln/An(III) form strong inner-sphere complexes through binding to three Al(O,OH)6 octahedra, most likely by occupying vacant sites in the octahedral layers of montmorillonite, which are exposed on {010} and {110} edge faces. At higher loadings, Ln/An(III) binds to only one Al octahedron, forming a weaker, edge-sharing surface complex. In the presence of carbonate, we identified a ternary mono- or dicarbonato Ln/An(III) complex binding directly to one Al(O,OH)6 octahedron, revealing that type-A ternary complexes form with the one or two carbonate groups pointing away from the surface into the solution phase. Within the spectroscopically observable concentration range these complexes could only be identified on the weak sites, in line with the small strong site capacity suggested by the refined sorption model. When the solubility of carbonates was exceeded, formation of an Am carbonate hydroxide could be identified. The excellent agreement between the thermodynamic model parameters obtained by fitting the macroscopic data, and the spectroscopically identified mechanisms, demonstrates the mature state of the 2SPNE SC/CE model for predicting and quantifying the retention of Ln/An(III) elements by montmorillonite-rich clay rocks. Copyright © 2016 Elsevier Ltd. All rights reserved.

RESTORING SUSTAINABLE FORESTS ON APPALACHIAN MINED LANDS FOR WOOD PRODUCTS, RENEWABLE ENERGY, CARBON SEQUESTRATION, AND OTHER ECOSYSTEM SERVICES

DOE Office of Scientific and Technical Information (OSTI.GOV)

James A. Burger; J. Galbraith; T. Fox

2005-06-08

The overall purpose of this project is to evaluate the biological and economic feasibility of restoring high-quality forests on mined land, and to measure carbon sequestration and wood production benefits that would be achieved from forest restoration procedures. We are currently estimating the acreage of lands in VA, WV, KY, OH, and PA mined under SMCRA and reclaimed to non-forested post-mining land uses that are not currently under active management, and therefore can be considered as available for carbon sequestration. To determine actual sequestration under different forest management scenarios, a field study was installed as a 3 x 3 factorialmore » in a random complete block design with three replications at each of three locations, Ohio, West Virginia, and Virginia. The treatments included three forest types (white pine, hybrid poplar, mixed hardwood) and three silvicultural regimes (competition control, competition control plus tillage, competition control plus tillage plus fertilization). Each individual treatment plot is 0.5 acres. Each block of nine plots is 4.5 acres, and the complete installation at each site is 13.5 acres. During the reporting period we compiled and evaluated all soil properties measured on the study sites. Statistical analysis of the properties was conducted, and first year survival and growth of white pine, hybrid poplars, and native hardwoods was assessed. Hardwood species survived better at all sites than white pine or hybrid poplar. Hardwood survival across treatments was 80%, 85%, and 50% for sites in Virginia, West Virginia, and Ohio, respectively, while white pine survival was 27%, 41%, and 58%, and hybrid poplar survival was 37%, 41%, and 72% for the same sites, respectively. Hybrid poplar height and diameter growth were superior to those of the other species tested, with the height growth of this species reaching 126.6cm after one year in the most intensive treatment at the site in Virginia. To determine carbon in soils on these sites, we developed a cost-effective method for partitioning total soil carbon to pedogenic carbon and geogenic carbon in mine soils. We are in the process of evaluating the accuracy and precision of the proposed carbon partitioning technique for which we are designing an experiment with carefully constructed mine soil samples. In a second effort, as part of a mined land reforestation project for carbon sequestration in southwestern Virginia we implemented the first phase of the carbon monitoring protocol that was recently delivered to DOE.« less

Carbon balance of South Asia constrained by passenger aircraft CO2 measurements

NASA Astrophysics Data System (ADS)

Patra, P. K.; Niwa, Y.; Schuck, T. J.; Brenninkmeijer, C. A.; Machida, T.; Matsueda, H.; Sawa, Y.

2011-12-01

Quantifying the fluxes of carbon dioxide (CO2) between the atmosphere and terrestrial ecosystems in all their diversity, across the continents, is important and urgent for implementing effective mitigating policies. Whereas much is known for Europe and North America for instance, in comparison, South Asia, with 1.6 billion inhabitants and considerable CO2 fluxes, remained terra incognita in this respect. The sole measurement site at Cape Rama does not constrain CO2 fluxes during the summer monsoon season. We use regional measurements of atmospheric CO2 aboard a Lufthansa passenger aircraft between Frankfurt (Germany) and Chennai (India) at cruise altitude, in addition to the existing network sites for 2008, to estimate monthly fluxes for 64-regions using Bayesian inversion and ACTM transport model simulations. The applicability of the model's transport parameterization is confirmed using multi-tracer (SF6, CH4, N2O) simulations for the CARIBIC datasets. The annual carbon flux obtained by including the aircraft data is twice as large as the fluxes simulated by a terrestrial ecosystem model that was applied to prescribe the fluxes used in the inversions. It is shown that South Asia sequestered carbon at a rate of 0.37±0.20 Pg C yr-1 for the years 2007 and 2008, primarily during the summer monsoon season when the water limitation for this tropical ecosystem is relaxed. The seasonality and the strength of the calculated monthly fluxes are successfully validated using independent measurements of vertical CO2 profiles over Delhi and spatial variations at cruising altitude by the CONTRAIL program over Asia aboard Japan Airlines passenger aircraft (Patra et al., 2011). Major challenges remain the verification of the inverse model flux seasonality and annual totals by bottom-up estimations using field measurements and terrestrial ecosystem models.

Carbon storage in subalpine forests and meadows of the Olympic Mountains, Washington

DOE Office of Scientific and Technical Information (OSTI.GOV)

Prichard, S.J.; Peterson, D.L.

1995-06-01

We investigated carbon storage in high elevation ecosystems of the Olympic Mountains. A sharp precipitation gradient created by the Olympic mountain range allows for comparison of carbon storage in different climatic regimes and vegetation types. Carbon in soils, vegetation, and woody debris was examined in subalpine forests and meadows of the northeast (dry) and southwest (wet) Olympics. Soil carbon storage in high elevation sites appears to be considerably greater than most low elevation forests. Above-ground carbon storage is generally greater in southwest sites. Meadow soils contained high carbon concentrations in upper horizons, while forests also stored a substantial amount ofmore » carbon in lower horizons. Information gained from this study will provide a better understanding of soil-vegetation relationships in subalpine ecosystems, especially with respect to potential climatic change impacts.« less

Potential biodiversity benefits from international programs to reduce carbon emissions from deforestation.

PubMed

Siikamäki, Juha; Newbold, Stephen C

2012-01-01

Deforestation is the second largest anthropogenic source of carbon dioxide emissions and options for its reduction are integral to climate policy. In addition to providing potentially low cost and near-term options for reducing global carbon emissions, reducing deforestation also could support biodiversity conservation. However, current understanding of the potential benefits to biodiversity from forest carbon offset programs is limited. We compile spatial data on global forest carbon, biodiversity, deforestation rates, and the opportunity cost of land to examine biodiversity conservation benefits from an international program to reduce carbon emissions from deforestation. Our results indicate limited geographic overlap between the least-cost areas for retaining forest carbon and protecting biodiversity. Therefore, carbon-focused policies will likely generate substantially lower benefits to biodiversity than a more biodiversity-focused policy could achieve. These results highlight the need to systematically consider co-benefits, such as biodiversity in the design and implementation of forest conservation programs to support international climate policy.

Black carbon at a roadside site in Beijing: Temporal variations and relationships with carbon monoxide and particle number size distribution

NASA Astrophysics Data System (ADS)

Song, Shaojie; Wu, Ye; Xu, Jiayu; Ohara, Toshimasa; Hasegawa, Shuichi; Li, Jiaqi; Yang, Liu; Hao, Jiming

2013-10-01

Black carbon (BC), carbon monoxide (CO), and particle number size distribution were measured near a major urban expressway of Beijing during summer and winter field campaigns in 2009. BC was also observed at urban and rural sites. The temporal variations of BC and its relationships with CO and particle number size distribution were analyzed. The average BC concentrations at the roadside site were 12.3 and 17.9 μg m-3 during the summer and winter campaigns, respectively. BC concentrations ranked in the order of roadside > urban > rural. A general diurnal pattern at all sites showed that the higher BC levels were observed at night. The diurnal pattern of summertime BC at the roadside site followed the variations of heavy-duty diesel vehicles (HDDVs). The increased proportion of HDDVs at night contributed to high ΔBC/ΔCO ratios. This study suggests that HDDVs are an important contributor to nighttime BC and particle number concentrations of both Aitken and accumulation modes near major roadways in Beijing, especially in summer.

Applicability of NASQAN data for ecosystem assessments on the Missouri River

USGS Publications Warehouse

Blevins, Dale W.; Fairchild, James

2001-01-01

The effectiveness of ecological restoration efforts on large developed rivers is often unknown because comprehensive ecological monitoring programs are often absent. Although Eulerian water-quality monitoring programs, such as the National Stream Quality Accounting Network (NASQAN) program, are more common, they are usually not designed for ecological assessment. Therefore, this paper addresses the value of NASQAN for ecological assessments on the Missouri River and identifies potential program additions and modifications to assess certain ecological changes in physical habitat, biological structure and function, and ecotoxicity. Five additional sites: The analysis of chlorophyll, mercury, ATP, potential endocrine disruptors, total trace elements, and selected total hydrophobic organics; and the hourly measurement of dissolved oxygen, turbidity, and temperature are recommended. Hourly measurements would require an entirely new operational aspect to NASQAN. However, the presence of data loggers and satellite transmitters in the gauging stations at all NASQAN sites substantially improves the feasibility of continuous water-quality monitoring. The use of semipermeable membrane devices (SPMDs) to monitor dissolved bioaccumulating organics and trace elements, identification and enumeration of zooplankton, and characterization of the bioavailability of organic matter are also recommended. The effect of biological processes on the conservative assumptions that are used in flux and source determinations of NASQAN constituents are also evaluated. Organic carbon, organic nitrogen, dissolved phosphate, and dissolved inorganic nitrogen are the NASQAN constituents most vulnerable to biological processes and thus violation of conservative assumptions.

Statistical Assessment of a Paired-site Approach for Verification of Carbon and Nitrogen Sequestration on CRP Land

NASA Astrophysics Data System (ADS)

Kucharik, C.; Roth, J.

2002-12-01

The threat of global climate change has provoked policy-makers to consider plausible strategies to slow the accumulation of greenhouse gases, especially carbon dioxide, in the atmosphere. One such idea involves the sequestration of atmospheric carbon (C) in degraded agricultural soils as part of the Conservation Reserve Program (CRP). While the potential for significant C sequestration in CRP grassland ecosystems has been demonstrated, the paired-site sampling approach traditionally used to quantify soil C changes has not been evaluated with robust statistical analysis. In this study, 14 paired CRP (> 8 years old) and cropland sites in Dane County, Wisconsin (WI) were used to assess whether a paired-site sampling design could detect statistically significant differences (ANOVA) in mean soil organic C and total nitrogen (N) storage. We compared surface (0 to 10 cm) bulk density, and sampled soils (0 to 5, 5 to 10, and 10 to 25 cm) for textural differences and chemical analysis of organic matter (OM), soil organic C (SOC), total N, and pH. The CRP contributed to lowering soil bulk density by 13% (p < 0.0001) and increased SOC and OM storage (kg m-2) by 13 to 17% in the 0 to 5 cm layer (p = 0.1). We tested the statistical power associated with ANOVA for measured soil properties, and calculated minimum detectable differences (MDD). We concluded that 40 to 65 paired sites and soil sampling in 5 cm increments near the surface were needed to achieve an 80% confidence level (α = 0.05; β = 0.20) in soil C and N sequestration rates. Because soil C and total N storage was highly variable among these sites (CVs > 20%), only a 23 to 29% change in existing total organic C and N pools could be reliably detected. While C and N sequestration (247 kg C ha{-1 } yr-1 and 17 kg N ha-1 yr-1) may be occurring and confined to the surface 5 cm as part of the WI CRP, our sampling design did not statistically support the desired 80% confidence level. We conclude that usage of statistical power analysis is essential to insure a high level of confidence in soil C and N sequestration rates that are quantified using paired plots.

NASA's Beachside Corrosion Test Site and Current Environmentally Friendly Corrosion Control Initiatives

NASA Technical Reports Server (NTRS)

Russell, Richard W.; Calle, Luz Marina; Johnston, Frederick; Montgomery, Eliza L.; Curran, Jerome P.; Kolody, Mark R.

2013-01-01

NASA began corrosion studies at the Kennedy Space Center (KSC) in 1966 during the Gemini/Apollo Programs with the evaluation of long-term corrosion protective coatings for carbon steel. KSC's Beachside Corrosion Test Site (BCTS), which has been documented by the American Society of Materials (ASM) as one of the most corrosive, naturally occurring, environments in the world, was established at that time. With the introduction of the Space Shuttle in 1981, the already highly corrosive conditions at the launch pad were rendered even more severe by the acid ic exhaust from the solid rocket boosters. In the years that followed, numerous studies have identified materials, coatings, and maintenance procedures for launch hardware and equipment exposed to the highly corrosive environment at the launch pad. This paper presents a historical overview of over 45 years of corrosion and coating evaluation studies and a description of the BCTS's current capabilities. Additionally, current research and testing programs involving chromium free coatings, environmentally friendly corrosion preventative compounds, and alternates to nitric acid passivation will be discussed.

CO2–rock–brine interactions in Lower Tuscaloosa Formation at Cranfield CO2 sequestration site, Mississippi, U.S.A.

USGS Publications Warehouse

Lu, Jiemin; Kharaka, Yousif K.; Thordsen, James J.; Horita, Juske; Karamalidis, Athanasios; Griffith, Craig; Hakala, J. Alexandra; Ambats, Gil; Cole, David R.; Phelps, Tommy J.; Manning, Michael A.; Cook, Paul J.; Hovorka, Susan D.

2012-01-01

A highly integrated geochemical program was conducted at the Cranfield CO2-enhanced oil recovery (EOR) and sequestration site, Mississippi, U.S.A.. The program included extensive field geochemical monitoring, a detailed petrographic study, and an autoclave experiment under in situ reservoir conditions. Results show that mineral reactions in the Lower Tuscaloosa reservoir were minor during CO2 injection. Brine chemistry remained largely unchanged, which contrasts with significant changes observed in other field tests. Field fluid sampling and laboratory experiments show consistently slow reactions. Carbon isotopic composition and CO2 content in the gas phase reveal simple two-end-member mixing between injected and original formation gas. We conclude that the reservoir rock, which is composed mainly of minerals with low reactivity (average quartz 79.4%, chlorite 11.8%, kaolinite 3.1%, illite 1.3%, concretionary calcite and dolomite 1.5%, and feldspar 0.2%), is relatively unreactive to CO2. The significance of low reactivity is both positive, in that the reservoir is not impacted, and negative, in that mineral trapping is insignificant.

The aqueous electrochemistry of carbon-based surfaces-investigation by scanning tunneling microscopy

NASA Astrophysics Data System (ADS)

Mühl, T.; Myhra, S.

2007-04-01

Electro-oxidation of carbon-based materials will lead to conversion of the solid to CO2/CO at the anode, with H2 being produced at the cathode. Recent voltammetric investigations of carbon nano-tubes and single crystal graphite have shown that only edge sites and other defect sites are electrochemically active. Local oxidation of diamond-like carbon films (DLC) by an STM tip in moist air followed by imaging allows correlation of topographical change with electro-chemical conditions and surface reactivity. The results may have implications for lithographic processing of carbon surfaces, and may have relevance for electrochemical H2 production.

Rational approaches for engineering novel functionalities in carbon-carbon bond forming enzymes

PubMed Central

Baker, Perrin; Seah, Stephen Y. K.

2012-01-01

Enzymes that catalyze carbon-carbon bond formation can be exploited as biocatalyst for synthetic organic chemistry. However, natural enzymes frequently do not possess the required properties or specificities to catalyze industrially useful transformations. This mini-review describes recent work using knowledge-guided site-specific mutagenesis of key active site residues to alter substrate specificity, stereospecificity and reaction specificity of these enzymes. In addition, examples of de novo designed enzymes that catalyze C-C bond reactions not found in nature will be discussed. PMID:24688644

Carbon fiber reinforcements for sheet molding composites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ozcan, Soydan; Paulauskas, Felix L.

A method of processing a carbon fiber tow includes the steps of providing a carbon fiber tow made of a plurality of carbon filaments, depositing a sizing composition at spaced-apart sizing sites along a length of the tow, leaving unsized interstitial regions of the tow, and cross-cutting the tow into a plurality of segments. Each segment includes at least a portion of one of the sizing sites and at least a portion of at least one of the unsized regions of the tow, the unsized region including and end portion of the segment.

Amorphous Carbon-Boron Nitride Nanotube Hybrids

NASA Technical Reports Server (NTRS)

Kim, Jae Woo (Inventor); Siochi, Emilie J. (Inventor); Wise, Kristopher E. (Inventor); Lin, Yi (Inventor); Connell, John (Inventor)

2016-01-01

A method for joining or repairing boron nitride nanotubes (BNNTs). In joining BNNTs, the nanotube structure is modified with amorphous carbon deposited by controlled electron beam irradiation to form well bonded hybrid a-C/BNNT structures. In repairing BNNTs, the damaged site of the nanotube structure is modified with amorphous carbon deposited by controlled electron beam irradiation to form well bonded hybrid a-C/BNNT structures at the damage site.

Comparing Soil Carbon of Short Rotation Poplar Plantations with Agricultural Crops and Woodlots in North Central United States

Treesearch

Mark D. Coleman; J.G. Isebrands; David N. Tolsted; Virginia R. Tolbert

2004-01-01

We collected soil samples from 27 study sites across North Central United States to compare the soil carbon of short rotation poplar plantations to adjacent agricultural crops and woodlots. Soil organic carbon (SOC) ranged from 20 to more than 160 Mg/ha across the sampled sites. Lowest SOC levels were found in uplands and highest levels in riparian soils. We attributed...

Systematically variable planktonic carbon metabolism along a land-to-lake gradient in a Great Lakes coastal zone.

PubMed

Weinke, Anthony D; Kendall, Scott T; Kroll, Daniel J; Strickler, Eric A; Weinert, Maggie E; Holcomb, Thomas M; Defore, Angela A; Dila, Deborah K; Snider, Michael J; Gereaux, Leon C; Biddanda, Bopaiah A

2014-11-01

During the summers of 2002-2013, we measured rates of carbon metabolism in surface waters of six sites across a land-to-lake gradient from the upstream end of drowned river-mouth Muskegon Lake (ML) (freshwater estuary) to 19 km offshore in Lake Michigan (LM) (a Great Lake). Despite considerable inter-year variability, the average rates of gross production (GP), respiration (R) and net production (NP) across ML (604 ± 58, 222 ± 22 and 381 ± 52 µg C L -1 day -1 , respectively) decreased steeply in the furthest offshore LM site (22 ± 3, 55 ± 17 and -33 ± 15 µg C L -1 day -1 , respectively). Along this land-to-lake gradient, GP decreased by 96 ± 1%, whereas R only decreased by 75 ± 9%, variably influencing the carbon balance along this coastal zone. All ML sites were consistently net autotrophic (mean GP:R = 2.7), while the furthest offshore LM site was net heterotrophic (mean GP:R = 0.4). Our study suggests that pelagic waters of this Great Lakes coastal estuary are net carbon sinks that transition into net carbon sources offshore. Reactive and dynamic estuarine coastal zones everywhere may contribute similarly to regional and global carbon cycles.

Soil carbon dynamics beneath switchgrass as indicated by stable isotope analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garten, C.T. Jr.; Wullschleger, S.D.

2000-04-01

Surface (0--40 cm) soil organic carbon (SOC) dynamics were studied beneath four switchgrass (Panicum virgatum L.) field trails in the southeastern US. Soil organic carbon was partitioned into particulate organic matter (POM) and mineral-associated organic matter (MOM). Most (75--90%) of the SOC at each study site was affiliated with MOM (<0.053 mm). Changes in stable carbon isotope ratios were used to derive carbon inputs to and losses from POM and MOM at each site. Inventories of existing SOC and new C{sub 4}-derived SOC beneath switchgrass decreased with increasing soil depth. Approximately 5 yr after establishment, 19 to 31% of themore » existing SOC inventories beneath switchgrass had been derived from new C{sub 4}-carbon inputs. Calculated turnover times of POM and MOM ranged from 2.4 to 4.3 yr and 26 to 40 yr, respectively. The turnover time of SOC in the POM fraction increased with decreasing mean annual temperature. A simple, two-compartment model was parameterized to predict the potential for soil carbon sequestration under switchgrass. An example calculation with the model indicated a measurable and verifiable recovery of soil carbon (=12% increase) on degraded lands through one decade of switchgrass production. The potential to sequester carbon through switchgrass cultivation will depend on initial soil carbon inventories, prevailing climate, soil types and site management.« less

Soil carbon dynamics beneath switchgrass as indicated by stable isotope analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garten Jr, Charles T; Wullschleger, Stan D

2000-04-01

Surface (0-40 cm) soil organic carbon (SOC) dynamics were studied beneath four switchgrass (Panicum virgatum L.) field trials in the southeastern United States. Soil organic carbon was partitioned into particulate organic matter (POM) and mineral-associated organic matter (MOM). Most (75-90%) of the SOC at each study site was affiliated with MOM (<0.053 mm). Changes in stable carbon isotope ratios were used to derive carbon inputs to and losses from POM and MOM at each site. Inventories of existing SOC and new C4-derived SOC beneath switchgrass decreased with increasing soil depth. Approximately 5 yr after establishment, 19 to 31% of themore » existing SOC inventories beneath switchgrass had been derived from new C{sub 4}-carbon inputs. Calculated turnover times of POM and MOM ranged from 2.4 to 4.3 yr and 26 to 40 yr, respectively. The turnover time of SOC in the POM fraction increased with decreasing mean annual temperature. A simple, two-compartment model was parameterized to predict the potential for soil carbon sequestration under switchgrass. An example calculation with the model indicated a measurable and verifiable recovery of soil carbon ({approx}12% increase) on degraded lands through one decade of switchgrass production. The potential to sequester carbon through switchgrass cultivation will depend on initial soil carbon inventories, prevailing climate, soil type, and site management.« less

Measurements of OC and EC in coarse particulate matter in the southeastern United States

DOE Office of Scientific and Technical Information (OSTI.GOV)

Edgerton, E.S.; Casuccio, G.S.; Saylor, R.D.

The organic carbon (OC) and elemental carbon (EC) content of filter-based, 24-hr integrated particulate matter with aerodynamic diameters between 2.5 and 10 {mu}m (PM10-2.5) was measured at two urban and two rural locations in the southeastern United States. On average, total carbon (OC + EC) comprised approximately 30% of PM10-2.5 mass at these four sites. Carbonate carbon was measured on a subset of samples from three sites and was found to be undetectable at a rural site in central Alabama, less than 2% of PM10-2.5 at an urban site in Georgia, and less than 10% of PM10-2.5 at an urban-industrialmore » site in Alabama. Manual scanning electron microscopy (SEM) and computer-controlled SEM (CCSEM) along with energy dispersive X-ray spectroscopy (EDS) were used to identify individual carbonaceous particles in a selected subset of samples collected at one rural site and one urban-industrial site in Alabama. CCSEM results showed that biological material (e.g., fungal spores, pollen, and vegetative detritus) accounted for 60-70% of the carbonaceous mass in PM10-2.5 samples with concentrations in the range of 2-16 {mu}g/m{sup 3}. Samples with higher PM10-2.5 concentrations (25-42 {mu}g/m{sup 3}) at the urban-industrial site were found by manual SEM to have significant amounts of unidentified carbonaceous material, likely originating from local industrial activities. Both filter-based OC and EC concentrations and SEM-identified biological material tended to have higher concentrations during warmer months. Upper limits for organic mass (OM) to OC ratios (OM/OC) are estimated for PM10-2.5 samples at 2.1 for urban sites and 2.6-2.7 for rural sites. 40 refs., 12 figs., 5 tabs.« less

Site-Specific Carbon Isotopes in Organics

NASA Astrophysics Data System (ADS)

Piasecki, A.; Eiler, J. M.

2012-12-01

Natural organic molecules exhibit a wide range of internal site-specific isotope variation (i.e., molecules with same isotopic substitution type but different site). Such variations are generally unconstrained by bulk isotopic measurements. If known, site-specific variations might constrain temperatures of equilibrium, mechanisms of formation or consumption reactions, and possibly other details. For example, lipids can exhibit carbon isotope differences of up to 30‰ between adjacent carbon sites as a result of fractionations arising during decarboxylation of pyruvate and other steps in lipid biosynthesis(1). We present a method for site-specific carbon isotope analysis of propane, based on high-resolution, multi-collector gas source mass spectrometry, using a novel prototype instrument - the Thermo MAT 253 Ultra. This machine has an inlet system and electron bombardment ion source resembling those in conventional stable isotope gas source mass spectrometers, and the energy filter, magnet, and detector array resembling those in multi-collector ICPMS and TIMS. The detector array has 7 detector positions, 6 of which are movable, and each of which can collect ions with either a faraday cup (read through amplifiers ranging from 107-1012 ohms) or an SEM. High mass resolving power (up to 27,000, MRP = M/dM definition) is achieved through a narrow entrance slit, adjustable from 250 to 5 μm. Such resolution can cleanly separate isobaric interferences between isotopologues of organic molecules having the same cardinal mass (e.g., 13CH3 and 12CH2D). We use this technology to analyze the isotopologues and fragments of propane, and use such data to solve for the site-specific carbon isotope fractionation. By measuring isotopologues of both the one-carbon (13CH3) and the two-carbon (13C12CH4) fragment ion, we can solve for both bulk δ13C and the difference in δ13C between the terminal and central carbon position. We tested this method by analyzing mixtures between natural propane and labeled propane (13CH3-12CH2-12CH3). Results are consistent with the expected relative fractionations between the two fragments, indicating limited 'scrambling' of carbon positions of less than 2% in the source. The limits of precision of this method are currently ~0.5 ‰, sufficient to resolve known or suspected position-specific isotope effects in propane. We have explored the expected temperature-dependent equilibrium isotopic distributions of propane using density functional theory and quantum mechanical models of vibrational isotope effects. These models predict the homogeneous isotope exchange equilibria among the various isotopologues of propane, which include several of a wide range of effects that should be measurable by our methods. At 300 K we predict that the central carbon site is 15‰ higher in δ13C and 95 ‰ higher in δD than the terminal carbon site; similarly the molecule containing both a 13C and D in the central site is enriched by ~120 ‰ relative to a random isotopic distribution at 300 K. These predictions present targets for future experimental and empirical studies of the temperature dependence of isotopic ordering in propane. More generally, the methods we are developing for the study of intramolecular isotopic distributions in propane will serve as a model for future study of similar effects in other organic compounds. [1]DeNiro, Epstein (1977) Science Volume 197, 261-263.

Structuring economic incentives to reduce emissions from deforestation within Indonesia.

PubMed

Busch, Jonah; Lubowski, Ruben N; Godoy, Fabiano; Steininger, Marc; Yusuf, Arief A; Austin, Kemen; Hewson, Jenny; Juhn, Daniel; Farid, Muhammad; Boltz, Frederick

2012-01-24

We estimate and map the impacts that alternative national and subnational economic incentive structures for reducing emissions from deforestation (REDD+) in Indonesia would have had on greenhouse gas emissions and national and local revenue if they had been in place from 2000 to 2005. The impact of carbon payments on deforestation is calibrated econometrically from the pattern of observed deforestation and spatial variation in the benefits and costs of converting land to agriculture over that time period. We estimate that at an international carbon price of $10/tCO(2)e, a "mandatory incentive structure," such as a cap-and-trade or symmetric tax-and-subsidy program, would have reduced emissions by 163-247 MtCO(2)e/y (20-31% below the without-REDD+ reference scenario), while generating a programmatic budget surplus. In contrast, a "basic voluntary incentive structure" modeled after a standard payment-for-environmental-services program would have reduced emissions nationally by only 45-76 MtCO(2)e/y (6-9%), while generating a programmatic budget shortfall. By making four policy improvements--paying for net emission reductions at the scale of an entire district rather than site-by-site; paying for reductions relative to reference levels that match business-as-usual levels; sharing a portion of district-level revenues with the national government; and sharing a portion of the national government's responsibility for costs with districts--an "improved voluntary incentive structure" would have been nearly as effective as a mandatory incentive structure, reducing emissions by 136-207 MtCO(2)e/y (17-26%) and generating a programmatic budget surplus.

MaGa, a web-based collaborative database for gas emissions: a tool to improve the knowledge on Earth degassing

NASA Astrophysics Data System (ADS)

Frigeri, A.; Cardellini, C.; Chiodini, G.; Frondini, F.; Bagnato, E.; Aiuppa, A.; Fischer, T. P.; Lehnert, K. A.

2014-12-01

The study of the main pathways of carbon flux from the deep Earth requires the analysis of a large quantity and variety of data on volcanic and non-volcanic gas emissions. Hence, there is need for common frameworks to aggregate available data and insert new observations. Since 2010 we have been developing the Mapping Gas emissions (MaGa) web-based database to collect data on carbon degassing form volcanic and non-volcanic environments. MaGa uses an Object-relational model, translating the experience of field surveyors into the database schema. The current web interface of MaGa allows users to browse the data in tabular format or by browsing an interactive web-map. Enabled users can insert information as measurement methods, instrument details as well as the actual values collected in the field. Measurements found in the literature can be inserted as well as direct field observations made by human-operated instruments. Currently the database includes fluxes and gas compositions from active craters degassing, diffuse soil degassing and fumaroles both from dormant volcanoes and open-vent volcanoes from literature survey and data about non-volcanic emission of the Italian territory. Currently, MaGa holds more than 1000 volcanic plume degassing fluxes, data from 30 sites of diffuse soil degassing from italian volcanoes, and about 60 measurements from fumarolic and non volcanic emission sites. For each gas emission site, the MaGa holds data, pictures, descriptions on gas sampling, analysis and measurement methods, together with bibliographic references and contacts to researchers having experience on each site. From 2012, MaGa developments started to be focused towards the framework of the Deep Earth Carbon Degassing research initiative of the Deep Carbon Observatory. Whithin the DECADE initiative, there are others data systems, as EarthChem and the Smithsonian Institution's Global Volcanism Program. An interoperable interaction between the DECADE data systems is being planned. MaGa is showing good potentials to improve the knowledge on Earth degassing firstly by making data more accessible and encouraging participation among researchers, and secondly by allowing to observe and explore, for the first time, a gas emission dataset with spatial and temporal extents never analyzed before.

Payments for carbon sequestration to alleviate development pressure in a rapidly urbanizing region

USGS Publications Warehouse

Smith, Jordan W.; Dorning, Monica; Shoemaker, Douglas A.; Méley, Andréanne; Dupey, Lauren; Meentemeyer, Ross K.

2017-01-01

The purpose of this study was to determine individuals' willingness to enroll in voluntary payments for carbon sequestration programs through the use of a discrete choice experiment delivered to forest owners living in the rapidly urbanizing region surrounding Charlotte, North Carolina. We examined forest owners' willingness to enroll in payments for carbon sequestration policies under different levels of financial incentives (annual revenue), different contract lengths, and different program administrators (e.g., private companies versus a state or federal agency). We also examined the influence forest owners' sense of place had on their willingness to enroll in hypothetical programs. Our results showed a high level of ambivalence toward participating in payments for carbon sequestration programs. However, both financial incentives and contract lengths significantly influenced forest owners' intent to enroll. Neither program administration nor forest owners' sense of place influenced intent to enroll. Although our analyses indicated that payments from carbon sequestration programs are not currently competitive with the monetary returns expected from timber harvest or property sales, certain forest owners might see payments for carbon sequestration programs as a viable option for offsetting increasing tax costs as development encroaches and property values rise.

The Origin of DIRT (Detrital Input and Removal Treatments): the Legacy of Dr. Francis D. Hole

NASA Astrophysics Data System (ADS)

Townsend, K. L.; Lajtha, K.; Caldwell, B.; Sollins, P.

2007-12-01

Soil organic matter (SOM) plays a key role in the cycling and retention of nitrogen and carbon within soil. Both above and belowground detrital inputs determine the nature and quantity of SOM. Studies on detrital impacts on SOM dynamics are underway at several LTER, ILTER and LTER-affiliated sites using a common experimental design, Detrital Input and Removal Treatments (DIRT). The concept for DIRT was originally based on experimental plots established at the University of Wisconsin Arboretum by Dr. Francis D. Hole in 1956 to study the effects of detrital inputs on pedogenesis. These plots are located on two forested sites and two prairie sites within the arboretum. Manipulations of the forested sites include double litter, no litter and removal of the O and A horizons. Manipulations of the prairie sites include harvest, mulch, bare and burn. These original treatments have largely been maintained since 1956. After 40 years of maintenance, there were significant differences in soil carbon between the double and no litter plots. The double litter plots had increased by nearly 30% while the no litter plots had decreased over 50%. The original DIRT plots are now 50 years old and have been re-sampled, where possible, for total carbon and nitrogen, labile and recalcitrant carbon fractions, net and gross nitrogen mineralization rates, and SOM bioavailability through CO2 respiration. The soils were fractionated by density to examine the role of carbon in each density fraction. The mean age of carbon in each fraction was determined by radiocarbon dating. This sampling and analysis is of special significance because it provides a glimpse into the future SOM trajectories for the new DIRT sites: Harvard Forest (MA), Bousson (PA), Andrews Experimental Forest (OR) and Sikfokut (Hungary).

Carbon Isotopic Measurements and Aerosol Optical Determinations during CARES: Indications of the Importance of Background Biogenic Aerosols

NASA Astrophysics Data System (ADS)

Gaffney, J. S.; Marley, N. A.; Begum, M.; Sturchio, N. C.; Guilderson, T. P.

2011-12-01

High volume size-fractionated aerosol samples were obtained in Cool, CA during the Carbonaceous Aerosol and Radiative Effects Study (CARES) in June of 2010. This site was chosen to study the regional impacts of carbonaceous aerosols originating from the Sacramento area. Samples were collected for 6 to 24 hour time periods on quartz fiber filters by using slotted impactors to allow for collection of sample size cuts above and below one micron. Both total carbon content and carbon isotopic composition, including 13C/12C and 14C, were determined on the samples. In addition, Ångstrom absorption exponents (AAEs) were determined for the region of 300-900 nm on the sub-micron size cut by using state of the art diffuse reflectance UV-visible spectroscopy with integrating sphere technology. The overall carbonaceous aerosol loadings were found to be quite low and relatively constant during the study, suggesting that most of the aerosols at the site were locally formed background aerosols. The 14C data is consistent with a substantial fraction (~80 %) being from modern carbon sources and 13C/12C results indicate that the carbon source was from C-3 plants. This is consistent with a significant fraction of the aerosols in the area arising from secondary formation from biogenic precursor emissions from trees, most likely mono- and sesquiterpenes. These results are compared to past results obtained in Mexico City and discussed in terms of the potential importance of biogenic emissions to UV absorbing aerosols as these are anticipated to increase with climate change. This work was supported by the Office of Science (BER), U.S. Department of Energy, Grant No. DE-FG02-07ER64328 and Grant No. DE-FG02-07-ER64329 as part of the Atmospheric Systems Research program.

Climate Controls on Carbon Sequestration in Eastern North America

NASA Technical Reports Server (NTRS)

Peteet, D. M.; Renik, B.; Maenza-Gmeich, T.; Kurdyla, D.; Guilderson, T.

2002-01-01

Mid-latitude forest ecosystems have been proposed as a "missing sink" today. The role of soils (including wetlands) in this proposed sink is a very important unknown. In order to make estimates of future climate change effects on carbon storage, we can examine past wetland carbon sequestration. How did past climate change affect net wetland carbon storage? We present long-term data from existing wetland sites used for paleoclimate reconstruction to assess the net carbon storage in wetland over the last 15000 years. During times of colder and wetter climate, many mid-latitude sites show increases in carbon storage, while past warmer, drier climates produced decreases in storage. Comparison among bog, fen, swamp, and tidal marsh are demonstrated for the Hudson Valley region.

Fossil and contemporary sources of organic and elemental carbon at a rural and an urban site in the Netherlands

NASA Astrophysics Data System (ADS)

Dusek, U.; Monaco, M.; Weijers, E.; Röckmann, T.

2012-04-01

Measurement of the radioactive carbon isotope 14C in aerosols can provide a direct estimate of the contribution of fossil fuel sources to aerosol carbon. In aerosol science, measurements of 14C/12C ratios are usually reported as fraction modern (fm), relative to an oxalic acid standard that, by definition, has fm=1. The radiocarbon signature gives a clear distinction between 'modern' carbon sources (fm around 1.1-1.2 for biomass burning and around 1.05 for biogenic secondary organic aerosol) and 'fossil' carbon sources (fm =0 for primary and secondary formation from fossil fuel combustion). High volume filter samples have been collected since February 2011 at Cabauw, a rural location in the Netherlands, and additionally in May and June at two suburban locations around Rotterdam. We report measurements of fm for total carbon (TC), organic carbon (OC), water insoluble OC (WIOC) and thermally refractory carbon (RC) as a proxy for elemental carbon. The carbon fractions are isolated by combusting TC at 650 °C, OC and WIOC at 360 °C. Refractory carbon is defined as the carbon remaining on the filter after water extraction, combustion at 360 °C for 15 min and at 450 °C for 2 minutes. The method has been tested with test substances and real aerosol filters and shows little charring for water-extracted filters. First results of 7 filter samples taken from February - Mai 2011 show fm(OC) generally larger than 0.86 at the rural site, except for one case, when a strongly polluted air mass originating in Eastern Europe reached the site. This indicates a strong contribution of natural sources to OC, even in the Netherlands, a very densely populated country with one of the highest levels of aerosol pollution in Western Europe. In particular, WSOC in the rural springtime aerosol seems to originate almost entirely from contemporary sources. Refractory carbon also showed relatively high fm, generally between 0.3-0.5, except in two cases, when marine air masses reached the site from the West and fm(RC) dropped to around 0.1. This could mean that biomass combustion plays a significant role around the Netherlands even in springtime. It is also possible that there exists a biogenic, organic component of the aerosol that evolves at such high temperatures that it is virtually inseparable from elemental carbon. Both hypotheses are consistent with low fM(RC) in marine aerosol. One urban sample was taken concurrently with one of the samples analyzed so far from the rural site. For both OC and RC, fM values were roughly 10-15% lower in the urban area than at the rural sites, which shows only a moderate influence of the urban fossil emissions on fm. A more detailed comparison between the rural and urban location as well as fm values in other seasons will be presented, as more samples from the rural site become available.

Rocky Mountain snowpack physical and chemical data for selected sites, 2010

USGS Publications Warehouse

Ingersoll, George P.; Mast, M. Alisa; Swank, James M.; Campbell, Chelsea D.

2010-01-01

The Rocky Mountain Snowpack program established a network of snowpack-sampling sites in the Rocky Mountain region, from New Mexico to Montana, to monitor the chemical content of snow and to understand the effects of regional atmospheric deposition on freshwater systems. Scientists with the U.S. Geological Survey, in cooperation with the National Park Service; the U.S. Department of Agriculture Forest Service; the Colorado Department of Public Health and Environment; Teton County, Wyoming; and others, annually collected and analyzed snow-pack samples at 48 or more sites in the Rocky Mountain region during 1993-2010. Sixty-three snowpack-sampling sites were each sampled once in 2010, and those data are presented in this report. Data include acid-neutralization capacity, specific conductance, pH, hydrogen ion concentrations, dissolved concentrations of major constituents (calcium, magnesium, sodium, potassium, ammonium, chloride, sulfate, and nitrate), dissolved organic carbon concentrations, snow-water equivalent, snow depth, total mercury concentrations, and ionic charge balance. Quality-assurance data for field and laboratory blanks and field replicates for 2010 also are included.

Rocky Mountain Snowpack Physical and Chemical Data for Selected Sites, 1993-2008

USGS Publications Warehouse

Ingersoll, George P.; Mast, M. Alisa; Campbell, Donald H.; Clow, David W.; Nanus, Leora; Turk, John T.

2009-01-01

The Rocky Mountain Snowpack program established a network of snowpack-sampling sites in the Rocky Mountain region from New Mexico to Montana to monitor the chemical content of snow to help in the understanding of the effects of atmospheric deposition to this region. The U.S. Geological Survey, in cooperation with the National Park Service, the USDA Forest Service, Teton County in Wyoming, Rio Blanco County in Colorado, Pitkin County in Colorado, and others, collected and analyzed snowpack samples annually for 48 or more sites in the Rocky Mountain region during 1993-2008. Forty-eight of the 162 snow-sampling sites have been sampled annually since 1993. Data include acid-neutralization capacity, specific conductance, pH, hydrogen ion concentrations, dissolved concentrations of major constituents (calcium, magnesium, sodium, potassium, ammonium, chloride, sulfate, and nitrate), dissolved organic carbon concentrations, snow/ water equivalent, snow depth, stable sulfur isotope ratios, total mercury concentrations (beginning in 2001), and ionic charge balance. Quality-assurance data for field and laboratory blanks and field replicates for individual years (1993-2008) also are included.

77 FR 6727 - Approval and Promulgation of Implementation Plans and Designation of Areas for Air Quality...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-02-09

... for Redesignation of Ozone and Carbon Monoxide Nonattainment Areas,'' Memorandum from G.T. Helms... Carbon Monoxide (CO) Redesignations,'' Memorandum from G.T. Helms, Chief, Ozone/Carbon Monoxide Programs...,'' Memorandum from G.T. Helms, Chief, Ozone/Carbon Monoxide Programs Branch, August 17, 1993; ``State...

Measuring priming using 14C of respired CO2: effects on respiration source pools and interactions with warming

NASA Astrophysics Data System (ADS)

Hopkins, F. M.; Trumbore, S.

2011-12-01

The role of substrate availability on soil carbon turnover is a critical unknown in predicting future soil carbon stocks. Substrate composition and availability can be altered by land cover change, warming, and nitrogen deposition, which can in turn affect soil carbon stocks through the priming effect. In particular, little is understood about the interaction between warming and changing substrate concentration. We examined the interactions between global change factors and the priming effect using sucrose addition to incubations of soils from two forest Free Air CO2 Enrichment (FACE) sites (Duke and Aspen). In addition to the in situ global change manipulations conducted at these sites, the CO2 fertilization procedure over the decade-long experiment labeled soil carbon pools with fossil-derived carbon (depleted in 14C relative to the background isotope content of soil carbon), allowing us to determine the effect of priming on respiration of soil carbon substrates of different ages. Thus, we used the carbon-13 signature of sucrose-derived CO2 to account for losses of substrate C, and the carbon-14 signature to partition fluxes of soil-derived CO2 between pre-FACE (> 10 y) and FACE derived (< 10 y) carbon sources. At both sites, we observed a positive priming effect-an increase in the rate of soil carbon derived respiration due to sucrose addition. However, the effect of substrate addition on respiratory source pools, as measured by 14C of respiration, varied greatly. At Duke FACE, we observed an increase in 14C content of CO2 of primed soil carbon, whereas at Aspen, we observed no difference. The amount of CO2 released by priming increased with temperature, but was proportionally similar to the amount of increase in basal respiration rates (no differences in Q10). At Duke, both warming and priming served to increase the 14C of respiration, whereas only warming changed 14C of respiration at Aspen. Despite similar overall carbon stocks, differences in the source of the priming effect between the two sites may be due to inherent differences in the relative role of stabilization factors within the soil carbon stock.

Trace Metals in Groundwater and Vadose Zone Calcite: In Situ Containment and Stabilization of Stronthium-90 and Other Divalent Metals and Radionuclides at Arid Western DOE Sites: Final Report for Award Number DE-FG07-02ER63486 to the University of Idaho (RW Smith) Environmental Management Science Program Project Number 87016

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, Robert W.; Fujita, Yoshiko

2007-11-07

Radionuclide and metal contaminants are present in the vadose zone and groundwater throughout the U.S. Department of Energy (DOE) energy research and weapons complex. In situ containment and stabilization of these contaminants represents a cost-effective treatment strategy that minimizes workers’ exposure to hazardous substances, does not require removal or transport of contaminants, and generally does not generate a secondary waste stream. We have investigated an in situ bioremediation approach that immobilizes radionuclides or contaminant metals (e.g., strontium-90) by their microbially facilitated co-precipitation with calcium carbonate in groundwater and vadose zone systems. Calcite, a common mineral in many aquifers and vadosemore » zones in the arid west, can incorporate divalent metals such as strontium, cadmium, lead, and cobalt into its crystal structure by the formation of a solid solution. Collaborative research undertaken by the Idaho National Laboratory (INL), University of Idaho, and University of Toronto as part of this Environmental Management Science Program project has focused on in situ microbially-catalyzed urea hydrolysis, which results in an increase in pH, carbonate alkalinity, ammonium, calcite precipitation, and co-precipitation of divalent cations. In calcite-saturated aquifers, microbially facilitated co-precipitation with calcium carbonate represents a potential long-term contaminant sequestration mechanism. Key results of the project include: **Demonstrating the linkage between urea hydrolysis and calcite precipitation in field and laboratory experiments **Observing strontium incorporation into calcite precipitate by urea hydrolyzers with higher distribution coefficient than in abiotic **Developing and applying molecular methods for characterizing microbial urease activity in groundwater including a quantitative PCR method for enumerating ureolytic bacteria **Applying the suite of developed molecular methods to assess the feasibility of the proposed bioremediation technique at a contaminated site located within the 100-N area of the Hanford, Washington site **Assessing the role of nitrification on the persistence of precipitated calcite by modifying primers for identification of the amoA gene region of various ammonia oxidizing bacteria (AOB) for characterizing AOB in the field« less

Towards TCCON Tropics: Assessment and Measurements of Carbon and its Climate Impacts in Southeast Asia (T3AM C2lImA)

NASA Astrophysics Data System (ADS)

Morino, I.; Velazco, V. A.; Schwandner, F. M.; Macatangay, R. C.; Griffith, D. W. T.

2015-12-01

TCCON (Total Carbon Column Observing Network) measurements of CO2 and CH4 have been and are currently used extensively and globally for satellite validation, for comparison with atmospheric chemistry models and to study atmosphere-biosphere exchanges of carbon. With the global effort to cap greenhouse gas emissions, TCCON has become vital for validating satellite-based greenhouse gas data from past, current and future missions like Japanese GOSAT (Greenhouse Gas Observing SATellite) and GOSAT-2, NASA's OCO-2 (Orbiting Carbon Observatory-2) and OCO-3, ESA's Carbon Monitoring Satellite (CarbonSat), Chinese TanSat, and others. The lack of reliable validation data for the satellite-based greenhouse gas observing missions in the tropical regions is a common limitation in global carbon-cycle modeling studies that have a tropical component. The international CO2 modeling community have specified a requirement for "expansion of the CO2 observation network within the tropics" to reduce uncertainties in regional estimates of CO2 sources and sinks using atmospheric transport models. A TCCON site in the western tropical Pacific is a logical next step in obtaining additional knowledge that would greatly contribute to the understanding of the Earth's atmosphere and better constraining a major tropical region experiencing tremendous economic and population growth. Here, we present a complete site assessment for a possible TCCON site in the Philippines and our decision on the site where a new TCCON FTS will be installed. This site assessment was conducted in cooperation with the Energy Development Corporation (EDC, Philippines), National Institute for Environmental Studies (NIES, Japan), University of Wollongong (UoW, Australia), NASA's Jet Propulsion Laboratory (JPL), the University of the Philippines (UP-IESM), the TCCON science team, and the GOSAT-2 science team.

Carbonate clumped isotopes and in situ temperature monitoring for Holocene soils in the San Luis Valley, USA indicate springtime carbonate formation

NASA Astrophysics Data System (ADS)

Hudson, A. M.; Paces, J. B.; Ruleman, C.

2017-12-01

Pedogenic carbonate horizons are abundant in semi-arid and arid regions worldwide and within the geologic record. They present a widely distributed archive of past environmental conditions, driven by global climate or tectonically-controlled elevation changes. Oxygen and carbon isotopes in calcite-rich nodules and clast rinds are widely-applied indicators of past soil water and CO2 composition linked to changing precipitation and plant communities. The temperature of carbonate formation, however, provides key constraint on past water/CO2 values and elucidate why they may have changed in the past. Clumped isotope thermometry can provide this constraint and additional climate information, given the carbonate forming system is well understood. We present preliminary clumped isotope (Δ47) temperatures for Holocene soil carbonates, constrained by 14C and U-Th disequilibrium dating, compared with two years of in situ soil temperature data to better understand the mechanism and seasonality of carbonate formation in the San Luis Valley region of the southern Rocky Mountains. Five temperature-monitoring sites ranging in elevation (1940-2450 m) and latitude (36.2-37.9°N) were installed in a variety of settings (range front, valley center, and canyon). The resulting records show indistinguishable seasonal temperature variations at >60 cm depth. This suggests Δ47 temperatures should be comparable at sites across the region. Temperatures based on Δ47 measurements of Holocene (>1.8 to 11.0 ka BP) carbonates at these sites yield consistent inter-site temperatures of 10±4°C, which are similar to modern springtime soil temperatures at depth. This seasonality matches previous results of isotopic modeling at sites further south along the Rio Grande corridor. Temperatures during March to May show multiple, abrupt warming and cooling cycles on weekly timescales caused by wetting and drying of the soil during spring precipitation events. This may drive carbonate precipitation under low pCO2 conditions before increased plant respiration increases soil pCO2 later in the season.

Spatiotemporal heterogeneity in carbon exchange at a restored peatland in Alberta, Canada

NASA Astrophysics Data System (ADS)

MacDonald, Scott; Strachan, Ian; Strack, Maria

2017-04-01

Boreal peatlands store a substantial portion of Earth's soil carbon, but the commercial peat extraction process upsets this carbon-sink dynamic. A best-practices restoration process has been developed that aims to return the vegetation and ecosystem functions of post-extraction peatlands. This includes the blocking and infilling of ditches, leveling of the peatland surface and re-introduction of vegetation through the moss layer transfer technique. The dynamics of carbon gas exchange in these restored peatlands are still poorly understood. We investigated ecosystem-scale and microscale carbon flux in a recently restored, post-extraction peatland near Seba Beach, Alberta, Canada. Two eddy covariance (EC) towers continuously measured CO2 and CH4 fluxes in hydrologically distinct parts of the peatland site. Here, we report on growing season measurements made during the fourth year following extraction. Regular static chamber measurements during June-August 2016 were also taken to study gas fluxes across an infilled drainage ditch on the site. Results suggest that if the peatland restoration process successfully returns high water table position, strong carbon uptake may be attained within several years of restoration. However, differences in peatland topography resulted spatial heterogeneity in carbon dynamics at this restored site. A gradient of revegetation success and attendant carbon-flux dynamics were observed, with much stronger net uptake of CO2 and substantial CH4 efflux measured at the tower with higher vegetation cover. Revegetation elsewhere was much sparser, and thus low CO2 uptake rates persisted at much of the peatland, though these conditions conversely inhibited substantial CH4 efflux. More broadly, the contrast in flux data between our two EC towers at the site suggests that attention be made to the selection of representative carbon flux values in similar restored peatlands.

Study on multimodal transport route under low carbon background

NASA Astrophysics Data System (ADS)

Liu, Lele; Liu, Jie

2018-06-01

Low-carbon environmental protection is the focus of attention around the world, scientists are constantly researching on production of carbon emissions and living carbon emissions. However, there is little literature about multimodal transportation based on carbon emission at home and abroad. Firstly, this paper introduces the theory of multimodal transportation, the multimodal transport models that didn't consider carbon emissions and consider carbon emissions are analyzed. On this basis, a multi-objective programming 0-1 programming model with minimum total transportation cost and minimum total carbon emission is proposed. The idea of weight is applied to Ideal point method for solving problem, multi-objective programming is transformed into a single objective function. The optimal solution of carbon emission to transportation cost under different weights is determined by a single objective function with variable weights. Based on the model and algorithm, an example is given and the results are analyzed.

Spatial optimization of carbon-stocking projects across Africa integrating stocking potential with co-benefits and feasibility.

PubMed

Greve, Michelle; Reyers, Belinda; Mette Lykke, Anne; Svenning, Jens-Christian

2013-01-01

Carbon offset projects through forestation are employed within the emissions trading framework to store carbon. Yet, information about the potential of landscapes to stock carbon, essential to the design of offset projects, is often lacking. Here, based on data on vegetation carbon, climate and soil, we quantify the potential for carbon storage in woody vegetation across tropical Africa. The ability of offset projects to produce co-benefits for ecosystems and people is then quantified. When co-benefits such as biodiversity conservation are considered, the top-ranked sites are sometimes different to sites selected purely for their carbon-stocking potential, although they still possess up to 92% of the latter carbon-stocking potential. This work provides the first continental-scale assessment of which areas may provide the greatest direct and indirect benefits from carbon storage reforestation projects at the smallest costs and risks, providing crucial information for prioritization of investments in carbon storage projects.

Shelf and open-ocean calcareous phytoplankton assemblages across the Paleocene-Eocene thermal maximum: Implications for global productivity gradients

USGS Publications Warehouse

Gibbs, S.J.; Bralower, T.J.; Bown, Paul R.; Zachos, J.C.; Bybell, L.M.

2006-01-01

Abrupt global warming and profound perturbation of the carbon cycle during the Paleocene-Eocene Thermal Maximum (PETM, ca. 55 Ma) have been linked to a massive release of carbon into the ocean-atmosphere system. Increased phytoplankton productivity has been invoked to cause subsequent CO2 drawdown, cooling, and environmental recovery. However, interpretations of geochemical and biotic data differ on when and where this increased productivity occurred. Here we present high-resolution nannofossil assemblage data from a shelf section (the U.S. Geological Survey [USGS] drill hole at Wilson Lake, New Jersey) and an open-ocean location (Ocean Drilling Program [ODP] Site 1209, paleoequatorial Pacific). These data combined with published biotic records indicate a transient steepening of shelf-offshelf trophic gradients across the PETM onset and peak, with a decrease in open-ocean productivity coeval with increased nutrient availability in shelf areas. Productivity levels recovered in the open ocean during the later stages of the event, which, coupled with intensified continental weathering rates, may have played an important role in carbon sequestration and CO2 drawdown. ?? 2006 Geological Society of America.

The United States Department of Energy's Regional Carbon Sequestration Partnerships program: a collaborative approach to carbon management.

PubMed

Litynski, John T; Klara, Scott M; McIlvried, Howard G; Srivastava, Rameshwar D

2006-01-01

This paper reviews the Regional Carbon Sequestration Partnerships (RCSP) concept, which is a first attempt to bring the U.S. Department of Energy's (DOE) carbon sequestration program activities into the "real world" by using a geographically-disposed-system type approach for the U.S. Each regional partnership is unique and covers a unique section of the U.S. and is tasked with determining how the research and development activities of DOE's carbon sequestration program can best be implemented in their region of the country. Although there is no universal agreement on the cause, it is generally understood that global warming is occurring, and many climate scientists believe that this is due, in part, to the buildup of carbon dioxide (CO(2)) in the atmosphere. This is evident from the finding presented in the National Academy of Science Report to the President on Climate Change which stated "Greenhouse gases are accumulating in Earth's atmosphere as a result of human activities, causing surface air temperatures and subsurface ocean temperatures to rise. Temperatures are, in fact, rising. The changes observed over the last several decades are likely mostly due to human activities, ...". In the United States, emissions of CO(2) originate mainly from the combustion of fossil fuels for energy production, transportation, and other industrial processes. Roughly one third of U.S. anthropogenic CO(2) emissions come from power plants. Reduction of CO(2) emissions through sequestration of carbon either in geologic formations or in terrestrial ecosystems can be part of the solution to the problem of global warming. However, a number of steps must be accomplished before sequestration can become a reality. Cost effective capture and separation technology must be developed, tested, and demonstrated; a database of potential sequestration sites must be established; and techniques must be developed to measure, monitor, and verify the sequestered CO(2). Geographical differences in fossil fuel use, the industries present, and potential sequestration sinks across the United States dictate the use of a regional approach to address the sequestration of CO(2). To accommodate these differences, the DOE has created a nationwide network of seven Regional Carbon Sequestration Partnerships (RCSP) to help determine and implement the carbon sequestration technologies, infrastructure, and regulations most appropriate to promote CO(2) sequestration in different regions of the nation. These partnerships currently represent 40 states, three Indian Nations, four Canadian Provinces, and over 200 organizations, including academic institutions, research institutions, coal companies, utilities, equipment manufacturers, forestry and agricultural representatives, state and local governments, non-governmental organizations, and national laboratories. These partnerships are dedicated to developing the necessary infrastructure and validating the carbon sequestration technologies that have emerged from DOE's core R&D and other programs to mitigate emissions of CO(2), a potent greenhouse gas. The partnerships provide a critical link to DOE's plans for FutureGen, a highly efficient and technologically sophisticated coal-fired power plant that will produce both hydrogen and electricity with near-zero emissions. Though limited to the situation in the U.S., the paper describes for the international scientific community the approach being taken by the U.S. to prepare for carbon sequestration, should that become necessary.

Variability of carbon and water fluxes following climate extremes over a tropical forest in southwestern Amazonia.

PubMed

Zeri, Marcelo; Sá, Leonardo D A; Manzi, Antônio O; Araújo, Alessandro C; Aguiar, Renata G; von Randow, Celso; Sampaio, Gilvan; Cardoso, Fernando L; Nobre, Carlos A

2014-01-01

The carbon and water cycles for a southwestern Amazonian forest site were investigated using the longest time series of fluxes of CO2 and water vapor ever reported for this site. The period from 2004 to 2010 included two severe droughts (2005 and 2010) and a flooding year (2009). The effects of such climate extremes were detected in annual sums of fluxes as well as in other components of the carbon and water cycles, such as gross primary production and water use efficiency. Gap-filling and flux-partitioning were applied in order to fill gaps due to missing data, and errors analysis made it possible to infer the uncertainty on the carbon balance. Overall, the site was found to have a net carbon uptake of ≈5 t C ha(-1) year(-1), but the effects of the drought of 2005 were still noticed in 2006, when the climate disturbance caused the site to become a net source of carbon to the atmosphere. Different regions of the Amazon forest might respond differently to climate extremes due to differences in dry season length, annual precipitation, species compositions, albedo and soil type. Longer time series of fluxes measured over several locations are required to better characterize the effects of climate anomalies on the carbon and water balances for the whole Amazon region. Such valuable datasets can also be used to calibrate biogeochemical models and infer on future scenarios of the Amazon forest carbon balance under the influence of climate change.

Fuel treatment impacts on estimated wildfire carbon loss from forests in Montana, Oregon, California, and Arizona

USGS Publications Warehouse

Stephens, Scott L.; Boerner, Ralph E.J.; Maghaddas, Jason J.; Maghaddas, Emily E.Y.; Collins, Brandon M.; Dow, Christopher B.; Edminster, Carl; Fiedler, Carl E.; Fry, Danny L.; Hartsough, Bruce R.; Keeley, Jon E.; Knapp, Eric E.; McIver, James D.; Skinner, Carl N.; Youngblood, Andrew P.

2012-01-01

Using forests to sequester carbon in response to anthropogenically induced climate change is being considered across the globe. A recent U.S. executive order mandated that all federal agencies account for sequestration and emissions of greenhouse gases, highlighting the importance of understanding how forest carbon stocks are influenced by wildfire. This paper reports the effects of the most common forest fuel reduction treatments on carbon pools composed of live and dead biomass as well as potential wildfire emissions from six different sites in four western U.S. states. Additionally, we predict the median forest product life spans and uses of materials removed during mechanical treatments. Carbon loss from modeled wildfire-induced tree mortality was lowest in the mechanical plus prescribed fire treatments, followed by the prescribed fire-only treatments. Wildfire emissions varied from 10–80 Mg/ha and were lowest in the prescribed fire and mechanical followed by prescribed fire treatments at most sites. Mean biomass removals per site ranged from approximately 30–60 dry Mg/ha; the median lives of products in first use varied considerably (from <10 to >50 years). Our research suggests most of the benefits of increased fire resistance can be achieved with relatively small reductions in current carbon stocks. Retaining or growing larger trees also reduced the vulnerability of carbon loss from wildfire. In addition, modeled vulnerabilities to carbon losses and median forest product life spans varied considerably across our study sites, which could be used to help prioritize treatment implementation.

Variability of Carbon and Water Fluxes Following Climate Extremes over a Tropical Forest in Southwestern Amazonia

PubMed Central

Zeri, Marcelo; Sá, Leonardo D. A.; Manzi, Antônio O.; Araújo, Alessandro C.; Aguiar, Renata G.; von Randow, Celso; Sampaio, Gilvan; Cardoso, Fernando L.; Nobre, Carlos A.

2014-01-01

The carbon and water cycles for a southwestern Amazonian forest site were investigated using the longest time series of fluxes of CO2 and water vapor ever reported for this site. The period from 2004 to 2010 included two severe droughts (2005 and 2010) and a flooding year (2009). The effects of such climate extremes were detected in annual sums of fluxes as well as in other components of the carbon and water cycles, such as gross primary production and water use efficiency. Gap-filling and flux-partitioning were applied in order to fill gaps due to missing data, and errors analysis made it possible to infer the uncertainty on the carbon balance. Overall, the site was found to have a net carbon uptake of ≈5 t C ha−1 year−1, but the effects of the drought of 2005 were still noticed in 2006, when the climate disturbance caused the site to become a net source of carbon to the atmosphere. Different regions of the Amazon forest might respond differently to climate extremes due to differences in dry season length, annual precipitation, species compositions, albedo and soil type. Longer time series of fluxes measured over several locations are required to better characterize the effects of climate anomalies on the carbon and water balances for the whole Amazon region. Such valuable datasets can also be used to calibrate biogeochemical models and infer on future scenarios of the Amazon forest carbon balance under the influence of climate change. PMID:24558378

Influence of dietary carbon on mercury bioaccumulation in streams of the Adirondack Mountains of New York and the Coastal Plain of South Carolina, USA

USGS Publications Warehouse

Riva-Murray, Karen; Bradley, Paul M.; Chasar, Lia C.; Button, Daniel T.; Brigham, Mark E.; Eikenberry, Barbara C. Scudder; Journey, Celeste A.; Lutz, Michelle A.

2013-01-01

We studied lower food webs in streams of two mercury-sensitive regions to determine whether variations in consumer foraging strategy and resultant dietary carbon signatures accounted for observed within-site and among-site variations in consumer mercury concentration. We collected macroinvertebrates (primary consumers and predators) and selected forage fishes from three sites in the Adirondack Mountains of New York, and three sites in the Coastal Plain of South Carolina, for analysis of mercury (Hg) and stable isotopes of carbon (δ13C) and nitrogen (δ15N). Among primary consumers, scrapers and filterers had higher MeHg and more depleted δ13C than shredders from the same site. Variation in δ13C accounted for up to 34 % of within-site variation in MeHg among primary consumers, beyond that explained by δ15N, an indicator of trophic position. Consumer δ13C accounted for 10 % of the variation in Hg among predatory macroinvertebrates and forage fishes across these six sites, after accounting for environmental aqueous methylmercury (MeHg, 5 % of variation) and base-N adjusted consumer trophic position (Δδ15N, 22 % of variation). The δ13C spatial pattern within consumer taxa groups corresponded to differences in benthic habitat shading among sites. Consumers from relatively more-shaded sites had more enriched δ13C that was more similar to typical detrital δ13C, while those from the relatively more-open sites had more depleted δ13C. Although we could not clearly attribute these differences strictly to differences in assimilation of carbon from terrestrial or in-channel sources, greater potential for benthic primary production at more open sites might play a role. We found significant variation among consumers within and among sites in carbon source; this may be related to within-site differences in diet and foraging habitat, and to among-site differences in environmental conditions that influence primary production. These observations suggest that different foraging strategies and habitats influence MeHg bioaccumulation in streams, even at relatively small spatial scales. Such influence must be considered when selecting lower trophic level consumers as sentinels of MeHg bioaccumulation for comparison within and among sites.

Influence of forest stands on soil and ecosystem carbon stocks in the conditions of the European part of Russia

NASA Astrophysics Data System (ADS)

Kaganov, Vladimir

2016-04-01

Forest stands are one of the most important components of ecosystems, both in Russia and around the world and at the same time forest vegetation is able to provide environment-modifying effect on the occupied landscape and, in particular, on the soil cover. Currently, due to the large interest in the carbon cycle, there is a question about the influence of forest vegetation on carbon stocks in ecosystems and in particular in the soil cover. To perform the study we selected 9 objects located in the European part of Russia from the area of the southern taiga to the semi-desert zone: Novgorod region, Kostroma region, Moscow region (2 objects), Penza region, Voronezh region, Volgograd region (2 objects) and Astrakhan region. For studying the influence of forest vegetation on the soil`s carbon, we organized the following experiment scheme: in each of the objects two key sites were selected, so that they originally were in the same soil conditions and the difference between them was only in a course development of vegetation - forest or grass. One part of the experimental sites, presenting forest vegetation, were the restored forests on abandoned lands with the age of 70-200 years. The second part of the experimental sites were artificial forest plantations aged from 60 to 112 years planted on the originally treeless forest-steppe or steppe landscapes. Perennial hayfields, perennial abandoned agricultural landscapes and virgin steppe areas were used as reference sites with grass vegetation. For each forest site we estimated the major carbon pools: phytomass, mortmass (dead wood, dry grass), debris, litter and soil. All data were recalculated using the conversion factors in carbon stocks in t C ha-1. We collected soil samples every 10 cm until the depth of 50 cm, and then at 50-75 and 75-100 cm soil layers. Bulk density and total organic carbon were determined by CHN analyzer. As a result, the soil`s carbon was also calculated into t C ha-1. We found out that the total carbon stocks were higher for the forestry vegetation than for the reference plots for all studied sites. Maximal values of carbon stocks (779±2 t C ha-1) were observed in forest sites of the forest-steppe zone (Voronezh region). These values decreased while moving both north and south and amounted for 236±1 t C ha-1 in south taiga (Novgorod region) and 104,5±7,4 t C ha-1 in semi-desert areas (Astrakhan region). The stock of total soil carbon significantly increased in 0-10 cm soil layer and decreased in 50-100 cm layer in the forest stands compared to the grass vegetation (T-test at significance level of 0.05). However, when considering the entire 100-cm layer of soil, there is no statistically significant difference in total carbon stock between forest and grass vegetation.

Sea change: Charting the course for biogeochemical ocean time-series research in a new millennium

NASA Astrophysics Data System (ADS)

Church, Matthew J.; Lomas, Michael W.; Muller-Karger, Frank

2013-09-01

Ocean time-series provide vital information needed for assessing ecosystem change. This paper summarizes the historical context, major program objectives, and future research priorities for three contemporary ocean time-series programs: The Hawaii Ocean Time-series (HOT), the Bermuda Atlantic Time-series Study (BATS), and the CARIACO Ocean Time-Series. These three programs operate in physically and biogeochemically distinct regions of the world's oceans, with HOT and BATS located in the open-ocean waters of the subtropical North Pacific and North Atlantic, respectively, and CARIACO situated in the anoxic Cariaco Basin of the tropical Atlantic. All three programs sustain near-monthly shipboard occupations of their field sampling sites, with HOT and BATS beginning in 1988, and CARIACO initiated in 1996. The resulting data provide some of the only multi-disciplinary, decadal-scale determinations of time-varying ecosystem change in the global ocean. Facilitated by a scoping workshop (September 2010) sponsored by the Ocean Carbon Biogeochemistry (OCB) program, leaders of these time-series programs sought community input on existing program strengths and for future research directions. Themes that emerged from these discussions included: 1. Shipboard time-series programs are key to informing our understanding of the connectivity between changes in ocean-climate and biogeochemistry 2. The scientific and logistical support provided by shipboard time-series programs forms the backbone for numerous research and education programs. Future studies should be encouraged that seek mechanistic understanding of ecological interactions underlying the biogeochemical dynamics at these sites. 3. Detecting time-varying trends in ocean properties and processes requires consistent, high-quality measurements. Time-series must carefully document analytical procedures and, where possible, trace the accuracy of analyses to certified standards and internal reference materials. 4. Leveraged implementation, testing, and validation of autonomous and remote observing technologies at time-series sites provide new insights into spatiotemporal variability underlying ecosystem changes. 5. The value of existing time-series data for formulating and validating ecosystem models should be promoted. In summary, the scientific underpinnings of ocean time-series programs remain as strong and important today as when these programs were initiated. The emerging data inform our knowledge of the ocean's biogeochemistry and ecology, and improve our predictive capacity about planetary change.

Boron isotope fractionation in magma via crustal carbonate dissolution

PubMed Central

Deegan, Frances M.; Troll, Valentin R.; Whitehouse, Martin J.; Jolis, Ester M.; Freda, Carmela

2016-01-01

Carbon dioxide released by arc volcanoes is widely considered to originate from the mantle and from subducted sediments. Fluids released from upper arc carbonates, however, have recently been proposed to help modulate arc CO2 fluxes. Here we use boron as a tracer, which substitutes for carbon in limestone, to further investigate crustal carbonate degassing in volcanic arcs. We performed laboratory experiments replicating limestone assimilation into magma at crustal pressure-temperature conditions and analysed boron isotope ratios in the resulting experimental glasses. Limestone dissolution and assimilation generates CaO-enriched glass near the reaction site and a CO2-dominated vapour phase. The CaO-rich glasses have extremely low δ11B values down to −41.5‰, reflecting preferential partitioning of 10B into the assimilating melt. Loss of 11B from the reaction site occurs via the CO2 vapour phase generated during carbonate dissolution, which transports 11B away from the reaction site as a boron-rich fluid phase. Our results demonstrate the efficacy of boron isotope fractionation during crustal carbonate assimilation and suggest that low δ11B melt values in arc magmas could flag shallow-level additions to the subduction cycle. PMID:27488228

Boron isotope fractionation in magma via crustal carbonate dissolution

NASA Astrophysics Data System (ADS)

Deegan, Frances M.; Troll, Valentin R.; Whitehouse, Martin J.; Jolis, Ester M.; Freda, Carmela

2016-08-01

Carbon dioxide released by arc volcanoes is widely considered to originate from the mantle and from subducted sediments. Fluids released from upper arc carbonates, however, have recently been proposed to help modulate arc CO2 fluxes. Here we use boron as a tracer, which substitutes for carbon in limestone, to further investigate crustal carbonate degassing in volcanic arcs. We performed laboratory experiments replicating limestone assimilation into magma at crustal pressure-temperature conditions and analysed boron isotope ratios in the resulting experimental glasses. Limestone dissolution and assimilation generates CaO-enriched glass near the reaction site and a CO2-dominated vapour phase. The CaO-rich glasses have extremely low δ11B values down to -41.5‰, reflecting preferential partitioning of 10B into the assimilating melt. Loss of 11B from the reaction site occurs via the CO2 vapour phase generated during carbonate dissolution, which transports 11B away from the reaction site as a boron-rich fluid phase. Our results demonstrate the efficacy of boron isotope fractionation during crustal carbonate assimilation and suggest that low δ11B melt values in arc magmas could flag shallow-level additions to the subduction cycle.

Boron isotope fractionation in magma via crustal carbonate dissolution.

PubMed

Deegan, Frances M; Troll, Valentin R; Whitehouse, Martin J; Jolis, Ester M; Freda, Carmela

2016-08-04

Carbon dioxide released by arc volcanoes is widely considered to originate from the mantle and from subducted sediments. Fluids released from upper arc carbonates, however, have recently been proposed to help modulate arc CO2 fluxes. Here we use boron as a tracer, which substitutes for carbon in limestone, to further investigate crustal carbonate degassing in volcanic arcs. We performed laboratory experiments replicating limestone assimilation into magma at crustal pressure-temperature conditions and analysed boron isotope ratios in the resulting experimental glasses. Limestone dissolution and assimilation generates CaO-enriched glass near the reaction site and a CO2-dominated vapour phase. The CaO-rich glasses have extremely low δ(11)B values down to -41.5‰, reflecting preferential partitioning of (10)B into the assimilating melt. Loss of (11)B from the reaction site occurs via the CO2 vapour phase generated during carbonate dissolution, which transports (11)B away from the reaction site as a boron-rich fluid phase. Our results demonstrate the efficacy of boron isotope fractionation during crustal carbonate assimilation and suggest that low δ(11)B melt values in arc magmas could flag shallow-level additions to the subduction cycle.

The Hyperarid Core of the Atacama Desert, an Extremely Dry and Carbon Deprived Habitat of Potential Interest for the Field of Carbon Science.

PubMed

Azua-Bustos, Armando; González-Silva, Carlos; Corsini, Gino

2017-01-01

The Atacama Desert in Chile is the driest and oldest desert on Earth, also considered one of the best Mars analog models. Here, several heterotrophic microbial communities have been discovered in its driest regions, with the ones present in the soil subsurface being one of the most interesting due to its existence in a habitat with almost no water available and almost undetectable organic carbon sources. Our recent discovery of the driest site of the Atacama known to date (and the heterotrophic microbial species that are able to survive in this site) reaffirms the opportunity to better characterize the physiological and molecular mechanisms that these species use to detect, mobilize, incorporate and use carbon under these extremely harsh conditions. Here we summarize what has been reported up to date on the organic carbon concentrations in different sites of the hyperarid core of the Atacama Desert, proposing that due to the meager amounts of carbon and extremely dry conditions, the microbial communities of the hyperarid core of the Atacama Desert may be of interest for the field of carbon science.

Effects of long-term (10 years) exposure to elevated CO2 and O3 on trembling Aspen carbon and nitrogen metabolism at the aspen FACE (Free-Air Carbon Dioxide Enrichment) study site

Treesearch

Rakesh Minocha; Stephanie Long; Subhash Minocha; Paula Marquardt; Neil Nelson; Mark. Kubiske

2010-01-01

This study was conducted at the Aspen Free-Air Carbon Dioxide Enrichment (FACE) experimental site, Rhinelander, WI, (USA). Since 1998, 12 experimental rings planted in 1997 underwent four different treatments: control; elevated CO2 (560 ppm); elevated O3 (1.5X ambient) and elevated CO2 (560 ppm) + O...

Nematode feeding strategies and the fate of dissolved organic matter carbon in different deep-sea sedimentary environments

NASA Astrophysics Data System (ADS)

Pape, Ellen; van Oevelen, Dick; Moodley, Leon; Soetaert, Karline; Vanreusel, Ann

2013-10-01

Sediments sampled from the Galicia Bank seamount and the adjacent slope (northeast Atlantic), and from a western Mediterranean slope site, were injected onboard with 13C-enriched dissolved organic matter (DOM) to evaluate nematode feeding strategies and the fate of DOM carbon in different benthic environments. We hypothesized that nematode 13C label assimilation resulted from either direct DOM uptake or feeding on 13C labeled bacteria. Slope sediments were injected with glucose ("simple" DOM) or "complex" diatom-derived DOM to investigate the influence of DOM composition on carbon assimilation. The time-series (1, 7 and 14 days) experiment at the seamount site was the first study to reveal a higher 13C enrichment of nematodes than bacteria and sediments after 7 days. Although isotope dynamics indicated that both DOM and bacteria were plausible candidate food sources, the contribution to nematode secondary production and metabolic requirements (estimated from biomass-dependent respiration rates) was higher for bacteria than for DOM at all sites. The seamount nematode community showed higher carbon assimilation rates than the slope assemblages, which may reflect an adaptation to the food-poor environment. Our results suggested that the trophic importance of bacteria did not depend on the amount of labile sedimentary organic matter. Furthermore, there was a discrepancy between carbon assimilation rates observed in the experiments and the feeding type classification, based on buccal morphology. Sites with a similar feeding type composition (i.e. the northeast Atlantic sites) showed large differences in uptake, whilst the nematode assemblages at the two slope sites, which had a differing trophic structure, took up similar amounts of the DOM associated carbon. Our results did not indicate substantial differences in carbon processing related to the complexity of the DOM substrate. The quantity of processed carbon (5-42% of added DOM) was determined by the bacteria, and was primarily respired. The bulk of the added 13C-DOM was not ingested by the benthic biota under study, and a considerable fraction was possibly adsorbed onto the sediment grains.

Effects of Surface Oxygen on the Performance of Carbon as an Anode in Lithium-Ion Batteries

NASA Technical Reports Server (NTRS)

Hung, Ching-Cheh; Clark, Gregory W.

2001-01-01

Carbon materials with similar bulk structure but different surface oxygen were compared for their performance as anodes in lithium-ion battery. The bulk structure was such that the graphene planes were perpendicular to the surface. Three types of surfaces were examined: surface containing C=O type oxygen. surface containing -O-C type oxygen, and surface containing high concentration of active sites. The test involved cycles of lithium insertion into and release from the carbon materials, which was in the half cells of carbon/saturated LiI-50/50 (vol %) EC and DMC/lithium. During the first cycle of lithium insertion, the presence of adsorbed oxygen, -O-C type oxygen, active carbon sites, and C=O type oxygen resulted in the formation of solid-electrolyte interface (SEI) when the carbon's voltage relative to lithium metal was >1.35, 1 to 1.35, 0.5 to 1, and 0.67 to 0.7 V, respectively. An optimum -O-C type oxygen and a minimum C=O type oxygen was found to increase the reversible and decrease the irreversible capacity of carbon. Active sites on the carbon surface result in a large irreversible capacity and a second lithium insertion-release mechanism. However, this new mechanism has a short cycle life.

Modeling Fluid Flow and Microbial Reactions in the Peru Accretionary Complex

NASA Astrophysics Data System (ADS)

Bekins, B. A.; Matmon, D.

2002-12-01

Accretionary complexes are sites where sediment compaction and deeper reactions drive large-scale flow systems that can affect global solute budgets. Extensive modeling and drilling studies have elucidated the origin of the fluids, pore pressures, duration of flow, and major flow paths in these settings. An important research goal is to quantify the effect of these flow systems on global chemical budgets of reactive solutes such as carbon. The Peru margin represents an end member setting that can serve as a basis to extend the results to other margins. The sediments are relatively high in organic carbon with an average value of 2.6%. The subduction rate at ~9 cm/yr and taper angle at 14-17° are among the largest in the world. Recent microbial studies on Ocean Drilling Program Leg 201 at the Peru accretionary margin provide many key elements needed to quantify the processes affecting organic carbon in an accretionary complex. Pore water chemistry data from Site 1230 located in the Peru accretionary prism indicate that sulfate reduction is important in the top 8 mbsf. Below this depth, methanogenesis is the dominant process and methane concentrations are among the highest measured at any site on Leg 201. The presence of high methane concentrations at shallow depths suggests that methane is transported upward in the prism by fluid flow. Measurements of in-situ pore pressures and temperatures also support the presence of upward fluid flow. A single in-situ pressure measurement at ~100 mbsf indicated an overpressure of 0.14 MPa. For a reasonable formation permeability of ~ 10-16 m2, the measured overpressure is adequate to produce flow at a rate of ~5 mm/yr. This rate is comparable to previous model estimates for flow rates in the Peru accretionary prism. In addition, curvature in the downhole temperature profile can best be explained by upward fluid flow of 1-10 mm/yr. These data are used to constrain a two-dimensional coupled fluid flow and reactive transport model focusing on the fate of organic carbon entering in the Peru accretionary complex. The proposed work is the first attempt at a quantitative estimate of the processes affecting the fate of organic carbon entering a subduction zone.

Geological Development of the Izu-Bonin Forearc Since the Eocene Based on Biostratigraphic, Rock Magnetic, and Sediment Provenance Observations from IODP Expedition 352 Drill Cores

NASA Astrophysics Data System (ADS)

Petronotis, K. E.; Robertson, A.; Kutterolf, S.; Avery, A.; Baxter, A.; Schindlbeck, J. C.; Wang, K. L.; Acton, G.

2016-12-01

International Ocean Discovery Program (IODP) Expedition 352 recovered early Oligocene to recent sediments above Eocene igneous basement at 4 sites in the Izu-Bonin Forearc. The sites were selected to investigate the forearc region since subduction initiation in the Eocene, with Sites U1439 and U1442 being cored into the upper trench slope and Sites U1440 and U1441 into the lower trench slope. Postcruise studies of biostratigraphy, sediment chemistry, tephra composition and chronology and magnetic properties, along with observations from prior coring help constrain the regional geological development. Volcanic activity in the area, as inferred from its influence on sediment composition, has varied between long periods of activity and quiescence. Combined whole-rock sediment chemistry and tephra compositions suggest that during the Oligocene to earliest Miocene ( 30-22 Ma) tuffaceous input of predominantly dacitic composition was mainly derived from the intra-oceanic Izu-Bonin Arc. The early Miocene interval ( 22-15 Ma) lacks tuffaceous input, as supported by rock magnetic data. During this period, the forearc subsided beneath the carbonate compensation depth (CCD), as evidenced by radiolarian-bearing mud and metal-rich silty clay. This was followed by input of tephra with bimodal felsic and mafic compositions from the Izu-Bonin Arc from 15 to 5 Ma. Middle Miocene to Quaternary time was characterized by increased carbonate preservation, coupled with abundant, predominantly felsic tephra input, which is chemically indicative of a Japan continental arc source (Honshu), with additional chemically distinctive input from the Izu-Bonin Arc. Extending back to 32 Ma, tephra layers can be correlated between the upper-slope sites, extrapolated to the less well-dated lower-slope sites, and further correlated with onland Japanese tephra (Kutterolf et al., 2016; Goldschmidt Conference). Overall, the new results provide an improved understanding of the regional tectonic evolution.

Density controlled carbon nanotube array electrodes

DOEpatents

Ren, Zhifeng F [Newton, MA; Tu, Yi [Belmont, MA

2008-12-16

CNT materials comprising aligned carbon nanotubes (CNTs) with pre-determined site densities, catalyst substrate materials for obtaining them and methods for forming aligned CNTs with controllable densities on such catalyst substrate materials are described. The fabrication of films comprising site-density controlled vertically aligned CNT arrays of the invention with variable field emission characteristics, whereby the field emission properties of the films are controlled by independently varying the length of CNTs in the aligned array within the film or by independently varying inter-tubule spacing of the CNTs within the array (site density) are disclosed. The fabrication of microelectrode arrays (MEAs) formed utilizing the carbon nanotube material of the invention is also described.

BOREAS RSS-8 BIOME-BGC Model Simulations at Tower Flux Sites in 1994

NASA Technical Reports Server (NTRS)

Hall, Forrest G. (Editor); Nickeson, Jaime (Editor); Kimball, John

2000-01-01

BIOME-BGC is a general ecosystem process model designed to simulate biogeochemical and hydrologic processes across multiple scales (Running and Hunt, 1993). In this investigation, BIOME-BGC was used to estimate daily water and carbon budgets for the BOREAS tower flux sites for 1994. Carbon variables estimated by the model include gross primary production (i.e., net photosynthesis), maintenance and heterotrophic respiration, net primary production, and net ecosystem carbon exchange. Hydrologic variables estimated by the model include snowcover, evaporation, transpiration, evapotranspiration, soil moisture, and outflow. The information provided by the investigation includes input initialization and model output files for various sites in tabular ASCII format.

Gas adsorption capacity in an all carbon nanomaterial composed of carbon nanohorns and vertically aligned carbon nanotubes.

PubMed

Puthusseri, Divya; Babu, Deepu J; Okeil, Sherif; Schneider, Jörg J

2017-10-04

Whereas vertically aligned carbon nanotubes (VACNTs) typically show a promising adsorption behavior at high pressures, carbon nanohorns (CNHs) exhibit superior gas adsorption properties in the low pressure regime due to their inherent microporosity. These adsorption characteristics are further enhanced when both materials are opened at their tips. The so prepared composite material allows one to investigate the effect of physical entrapment of CO 2 molecules within the specific adsorption sites of VACNTs composed of opened double walled carbon nanotubes (CNTs) and in specific adsorption sites created by spherically aggregated opened single walled carbon nanohorns. Combining 50 wt% of tip opened CNTs with tip opened CNHs increases the CO 2 adsorption capacity of this material by ∼24% at 30 bar and 298 K compared to opened CNHs alone.

AmeriFlux US-UMd UMBS Disturbance

DOE Data Explorer

Curtis, Peter [Ohio State University; Gough, Christopher [Virginia Commonwealth University

2016-01-01

This is the AmeriFlux version of the carbon flux data for the site US-UMd UMBS Disturbance. Site Description - The UMBS Disturbance site is an artificial disturbance site that has recently been created as part of the Forest Accelerate Succession ExperimenT (FASET). In Spring 2008, every aspen and birch tree (>6,700, ~35% canopy LAI), the dominant early successional trees, were girdled over 39 ha of the FASET treatment plot to stimulate a disturbance that will move the forest into a later successional stage, dominated by maples, oaks, and white pine. This treatment caused aspen and birch mortality within 2 - 3 years. As a result of the changed canopy structure, there is a divergence in net ecosystem exchange between the control plot (enhanced carbon uptake) and the treatment plot (reduced carbon uptake).

CARBON STORAGE AND FLUXES IN PONDEROSA PINE AT DIFFERENT SUCCESSIONAL STAGES

EPA Science Inventory

We compared carbon storage and fluxes in young and old ponderosa pine stands in Oregon, including plant and soil storage, net primary productivity, respiration fluxes, and eddy flux estimates of net ecosystem exchange. The young site (Y site) was previously an old-growth pondero...

Carbon Storage in US Wetlands. | Science Inventory | US EPA

EPA Pesticide Factsheets

Background/Question/Methods Wetland soils contain some of the highest stores of soil carbon in the biosphere. However, there is little understanding of the quantity and distribution of carbon stored in US wetlands or of the potential effects of human disturbance on these stocks. We provide unbiased estimates of soil carbon stocks for wetlands at regional and national scales and describe how soil carbon stocks vary by anthropogenic disturbance to the wetland. To estimate the quantity and distribution of carbon stocks in wetlands of the conterminous US, we used data gathered in the field as part of the 2011 National Wetland Condition Assessment (NWCA) conducted by USEPA. During the growing season, field crews collected soil samples by horizon from 120-cm deep soil pits at 967 randomly selected wetland sites. Soil samples were analyzed for bulk density and organic carbon. We applied site carbon stock averages by soil depth back to the national population of wetlands and to several subpopulations, including five geographic areas and anthropogenic disturbance level. Disturbance levels were categorized by the NWCA as least, intermediately, or most disturbed using a priori defined physical, chemical, and biological indicators that were observable at the time of the site visit.Results/Conclusions We find that wetlands in the conterminous US store a total of 11.52 PgC – roughly equivalent to four years of annual carbon emissions by the US, with the greatest soil ca

Eelgrass Blue Carbon-Quantification of Carbon Stocks and Sequestration Rates in Zostera Marina Beds in the Salish Sea

NASA Astrophysics Data System (ADS)

Lutz, M. D.; Rybczyk, J.; Poppe, K.; Johnson, C.; Kaminsky, M.; Lanphear, M.

2017-12-01

Seagrass meadows provide more than habitat, biodiversity support, wave abatement, and water quality improvement; they help mitigate climate change by taking up and storing (sequestering) carbon (C), reportedly at rates only surpassed worldwide by salt marsh and mangrove ecosystems. Now that their climate mitigation capacity has earned seagrass ecosystems a place in the Verified Carbon Standard voluntary greenhouse gas program, accurate ecosystem carbon accounting is essential. Though seagrasses vary in carbon storage and accumulation greatly across species and geography, the bulk of data included in calculating global averages involves tropical and subtropical seagrasses. We know little regarding carbon stocks nor sequestration rates for eelgrass (Zostera marina) meadows in the Pacific Northwest. The intent of our study was to quantify carbon stocks and sequestration rates in the central Salish Sea of Washington State. We gathered sediment cores over three bays, as close to 1 m in depth as possible, both on foot and while scuba diving. We measured bulk density, carbon concentration, carbon stock, grain size, and carbon accumulation rate with depth. Results from our study show lower estimated Corg concentration (mean = 0.39% C, SE=0.01, range=0.11-1.75, SE=0.01), Corg stock (mean=24.46 Mg ha-1, SE=0.00, range=16.31-49.99.70), and C sequestration rates (mean=33.96 g m-2yr-1, range=11.4-49.5) than those reported in published studies from most other locations. Zostera marina is highly productive, yet does not seem to have the capacity to store C in its sediments like seagrasses in warmer climes. These data have implications in carbon market trading, when determining appropriate seagrass restoration site dimensions to offset emissions from transportation, industry, and seagrass habitat disturbance. Awareness of lower rates could prevent underestimating the area appropriate for mitigation or restoration.

Geological and geomechanical properties of the carbonate rocks at the eastern Black Sea Region (NE Turkey)

NASA Astrophysics Data System (ADS)

Ersoy, Hakan; Yalçinalp, Bülent; Arslan, Mehmet; Babacan, Ali Erden; Çetiner, Gözde

2016-11-01

Turkey located in the Alpine-Himalayan Mountain Belt has 35% of the natural stone reserves of the world and has good quality marble, limestone, travertine and onyx reserves especially in the western regions of the country. The eastern Black Sea Region with a 1.4 million meters cubes reserve has a little role on the natural stone production in the country. For this reason, this paper deals with investigation on the potential of carbonate stone in the region and determination of the geological and geo-mechanical properties of these rocks in order to provide economic contribution to the national economy. While the study sites are selected among the all carbonate rock sites, the importance as well as the representative of the sites were carefully considered for the region. After representative samples were analyzed for major oxide and trace element compositions to find out petrochemical variations, the experimental program conducted on rock samples for determination of both physical and strength properties of the carbonate rocks. The results of the tests showed that there are significant variations in the geo-mechanical properties of the studied rock groups. The density values vary from 2.48 to 2.70 gr/cm3, water absorption by weight values range from 0.07 to 1.15% and the apparent porosity of the carbonate rocks are between 0.19 and 3.29%. However, the values of the UCS shows variation from 36 to 80 MPa. Tensile and bending strength values range from 3.2 to 7.5 MPa and 6.0-9.2 MPa respectively. Although the onyx samples have the lowest values of apparent porosity and water absorption by weight, these samples do not have the highest values of UCS values owing to occurrence of the micro-cracks. The UCS values of the rock samples were also found after cycling tests However, the limestone samples have less than 5% deterioration after freezing-thawing and wetting-drying tests, but travertine and onyx samples have more than 15% deterioration. Exception of the apparent porosity values of travertine samples, all geo-mechanical properties of the studied carbonate rocks were determined in the acceptance values given by Turkish Standards Institute (TSE) for using as a natural dimension stone. After these investigations, it is anticipated that in the near future the number of quarries and factories will increase and more types of natural stones will be discovered in the eastern Black Sea Region and thus this will provide economic contribution to the economy of the country.

Four-electron deoxygenative reductive coupling of carbon monoxide at a single metal site

NASA Astrophysics Data System (ADS)

Buss, Joshua A.; Agapie, Theodor

2016-01-01

Carbon dioxide is the ultimate source of the fossil fuels that are both central to modern life and problematic: their use increases atmospheric levels of greenhouse gases, and their availability is geopolitically constrained. Using carbon dioxide as a feedstock to produce synthetic fuels might, in principle, alleviate these concerns. Although many homogeneous and heterogeneous catalysts convert carbon dioxide to carbon monoxide, further deoxygenative coupling of carbon monoxide to generate useful multicarbon products is challenging. Molybdenum and vanadium nitrogenases are capable of converting carbon monoxide into hydrocarbons under mild conditions, using discrete electron and proton sources. Electrocatalytic reduction of carbon monoxide on copper catalysts also uses a combination of electrons and protons, while the industrial Fischer-Tropsch process uses dihydrogen as a combined source of electrons and electrophiles for carbon monoxide coupling at high temperatures and pressures. However, these enzymatic and heterogeneous systems are difficult to probe mechanistically. Molecular catalysts have been studied extensively to investigate the elementary steps by which carbon monoxide is deoxygenated and coupled, but a single metal site that can efficiently induce the required scission of carbon-oxygen bonds and generate carbon-carbon bonds has not yet been documented. Here we describe a molybdenum compound, supported by a terphenyl-diphosphine ligand, that activates and cleaves the strong carbon-oxygen bond of carbon monoxide, enacts carbon-carbon coupling, and spontaneously dissociates the resulting fragment. This complex four-electron transformation is enabled by the terphenyl-diphosphine ligand, which acts as an electron reservoir and exhibits the coordinative flexibility needed to stabilize the different intermediates involved in the overall reaction sequence. We anticipate that these design elements might help in the development of efficient catalysts for converting carbon monoxide to chemical fuels, and should prove useful in the broader context of performing complex multi-electron transformations at a single metal site.

A Smoking Gun for Methane Hydrate Release During the Paleocene-Eocene Thermal Maximum

NASA Astrophysics Data System (ADS)

Frieling, J.; Peterse, F.; Lunt, D. J.; Bohaty, S. M.; S Sinninghe Damsté, J.; Reichart, G. J.; Sluijs, A.

2016-12-01

The Paleocene-Eocene Thermal Maximum (PETM; 56 Ma) was a period of rapid 4-5ºC global warming and a global negative carbon isotope excursion (CIE) of 3-4.5‰, signaling the input of at least 1500 Gt of δ13C-depleted carbon into the ocean-atmosphere system. Methane from submarine hydrates has long been proposed as a carbon source, but direct and indirect evidence is lacking. We generated a new high-resolution TEX86 and δ13C record from Ocean Drilling Program Site 959 in the eastern tropical Atlantic and find that initial warming preceded the PETM CIE by 10 kyr. Moreover, time-shifted cross-correlations on these new and published temperature-δ13C data imply that substantial (2-3 °C) warming lead 13C-depleted carbon injection by an average of 2-3 kyr globally. Finally, a data compilation shows that global burial fluxes of biogenic Ba approximately doubled across all depths of the ocean studied, which on PETM time scales can only be explained by significant Ba addition to the oceans. Submarine hydrates are Ba-rich and require warming to dissociate. The simplest explanation for the temperature lead and Ba addition to the ocean is that methane hydrate dissociated as a response to initial warming and acted as a positive carbon cycle feedback during the PETM.

Woodland carbon code: building an evidence base for the "4 per mil" initiative in land converted to forestry.

NASA Astrophysics Data System (ADS)

Hannam, Jacqueline; Vanguelova, Elena; West, Vicky

2017-04-01

The Woodland Carbon Code is a voluntary standard for woodland creation projects in the UK. Carbon sequestration resulting from certified projects will contribute directly to the UK's national targets for reducing emissions of greenhouse gases (GHG). Whilst this is concerned primarily with above ground capture there is little empirical evidence of the longer term carbon sequestration potential of soils under this land use change in the UK. We present preliminary results from a resurvey of 20 sites originally sampled as part of the soil survey of England and Wales. It includes soil carbon stocks assessed within the soil profile (up to 1m depth) where sites have been converted to forestry in the last 40 years. The small number of sites (n=20) and high variability in soil type, forest type and original land use prevented detailed analysis between these different factors, but overall there was an increase in carbon concentration in the whole profile, driven primarily by an increase the surface organic layers. For all sites combined there was no significant difference in the C stocks between the two survey periods. The increase in carbon stock in the surface organic horizons tended to be offset by a decrease in the mineral subsoils (specifically in Brown Earth soils) primarily as a result of bulk density changes. There are presently insufficient measured data from a range of UK climate, land-use and soil type conditions to quantify with confidence soil C changes during afforestation. This is partly because of the difficulties of detecting relatively slow changes in spatially heterogeneous soils and also obtaining good examples of sites that have undergone documented land use change. Reviewing results from all ongoing afforestation projects in the UK will provide better quantification of the C sequestration potential of forest soils to be accounted for in the Woodland Carbon Code's overall GHG mitigation potential.

Mass absorption efficiency of elemental carbon over Van Vihar National Park, Bhopal, India: Temporal variability and implications to estimates of black carbon radiative forcing

NASA Astrophysics Data System (ADS)

Samiksha, S.; Raman, R. S.; Singh, A.

2016-12-01

It is now well recognized that black carbon (a component of aerosols that is similar but not identical to elemental carbon) is an important contributor to global warming, second only to CO2.However, the most popular methods for estimation of black carbon rely on accurate estimates of its mass absorption efficiency (MAE) to convert optical attenuation measurements to black carbon concentrations. Often a constant manufacturer specified MAE is used for this purposes. Recent literature has unequivocally established that MAE shows large spatio-temporal heterogeneities. This is so because MAE depends on emission sources, chemical composition, and mixing state of aerosols. In this study, ambient PM2.5 samples were collected over an ecologically sensitive zone (Van Vihar National Park) in Bhopal, Central India for two years (01 January, 2012 to 31 December, 2013). Samples were collected on Teflon, Nylon, and Tissue quartz filter substrates. Punches of quartz fibre filter were analysed for organic and elemental carbon (OC/EC) by a thermal-optical-transmittance/reflectance (TOT-TOR) analyser operating with a 632 nm laser diode. Teflon filters were also used to interdependently measure PM2.5 attenuation (at 370 nm and 800 nm) by transmissometry. Site-specific mass absorption efficiency (MAE) for elemental carbon over the study site will be derived using a combination of measurements from the TOT/TOR analyser and transmissometer. An assessment of site-specific MAE values, its temporal variability and implications to black carbon radiative forcing will be discussed. It is now well recognized that black carbon (a component of aerosols that is similar but not identical to elemental carbon) is an important contributor to global warming, second only to CO2. However, the most popular methods for estimation of black carbon rely on accurate estimates of its mass absorption efficiency (MAE) to convert optical attenuation measurements to black carbon concentrations. Often a constant manufacturer specified MAE is used for this purposes. Recent literature has unequivocally established that MAE shows large spatio-temporal heterogeneities. This is so because MAE depends on emission sources, chemical composition, and mixing state of aerosols. In this study, ambient PM2.5 samples were collected over an ecologically sensitive zone (Van Vihar National Park) in Bhopal, Central India for two years (01 January, 2012 to 31 December, 2013). Samples were collected on Teflon, Nylon, and Tissue quartz filter substrates. Punches of quartz fibre filter were analysed for organic and elemental carbon (OC/EC) by a thermal-optical-transmittance/reflectance (TOT-TOR) analyser operating with a 632 nm laser diode. Teflon filters were also used to interdependently measure PM2.5 attenuation (at 370 nm and 800 nm) by transmissometry. Site-specific mass absorption efficiency (MAE) for elemental carbon over the study site will be derived using a combination of measurements from the TOT/TOR analyser and transmissometer. An assessment of site-specific MAE values, its temporal variability and implications to black carbon radiative forcing will be discussed.

Klamath River Water Quality Data from Link River Dam to Keno Dam, Oregon, 2008

USGS Publications Warehouse

Sullivan, Annett B.; Deas, Michael L.; Asbill, Jessica; Kirshtein, Julie D.; Butler, Kenna D.; Vaughn, Jennifer

2009-01-01

This report documents sampling and analytical methods and presents field data from a second year of an ongoing study on the Klamath River from Link River Dam to Keno Dam in south central Oregon; this dataset will form the basis of a hydrodynamic and water quality model. Water quality was sampled weekly at six mainstem and two tributary sites from early April through early November, 2008. Constituents reported herein include field-measured water-column parameters (water temperature, pH, dissolved oxygen concentration, specific conductance); total nitrogen and phosphorus; particulate carbon and nitrogen; total iron; filtered orthophosphate, nitrite, nitrite plus nitrate, ammonia, organic carbon, and iron; specific UV absorbance at 254 nanometers; chlorophyll a; phytoplankton and zooplankton enumeration and species identification; and bacterial abundance and morphological subgroups. Sampling program results indicated: *Most nutrient and carbon concentrations were lowest in spring, increased starting in mid-June, remained elevated in the summer, and decreased in fall. Dissolved nitrite plus nitrate had a different seasonal cycle and was below detection or at low concentration in summer. *Although total nitrogen and total phosphorus concentrations did not show large differences from upstream to downstream, filtered ammonia and orthophosphate concentrations increased in the downstream direction and particulate carbon and particulate nitrogen generally decreased in the downstream direction. *Large bacterial cells made up most of the bacteria biovolume, though cocci were the most numerous bacteria type. Cocci, with diameters of 0.1 to 0.2 micrometers, were smaller than the filter pore sizes used to separate dissolved from particulate matter. *Phytoplankton biovolumes were dominated by diatoms in spring and by the blue-green alga Aphanizomenon flos-aquae after mid-June. Another blue-green, Anabaena flos-aquae, was noted in samples from late May to late June. Phytoplankton biovolumes generally were highest at the upstream Link River and Railroad Bridge sites and decreased in the downstream direction. *Zooplankton densities were largest in late April. Populations were dominated by rotifers and copepods in early spring, and by rotifers and cladocerans in summer, with cladocerans most common at the most upstream site.

A Preliminary Assessment of Orbiting Carbon Observatory-2 (OCO-2) Measurements Using TCCON Data

NASA Astrophysics Data System (ADS)

Wennberg, P. O.; Fisher, B.; Roehl, C. M.; Wunch, D.; Osterman, G. B.; Eldering, A.; Naylor, B. J.; Nguyen, H.; Mandrake, L.; O'Dell, C.; Frankenberg, C.; Natraj, V.; Taylor, T.; Smyth, M.; Crisp, D.; Pollock, H. R.; Payne, V.; Gunson, M. R.; Salawitch, R. J.

2014-12-01

The NASA Orbiting Carbon Observatory-2 (OCO-2) successfully launched from Vandenberg Air Force Base in California on July 2, 2014. The mission provides remotely-sensed measurements of the column-averaged dry air mole fraction of carbon dioxide from space. In order to insure the quality of the space-based observations, a detailed validation program was developed for the original OCO mission. During the time period between the original OCO launch failure and the successful launch of OCO-2, that validation methodology was tested and refined using data from the Japanese Greenhouse gases Observing SATellite (GOSAT) as part of the NASA Atmospheric CO2 Observations from Space (ACOS) project. At the core of the OCO-2 validation plan are comparisons of the satellite data to observations from Total Carbon Column Observation Network (TCCON), a network of ground based Fourier Transform Spectrometers. The TCCON instruments provide "ground truth", allowing for determination of bias in the space-based observations. The TCCON observations are, in turn, traceable to the World Meteorological Organization (WMO) standards through aircraft and balloon-borne profile observations at the TCCON locations. OCO-2 is capable of making measurements in three observation modes: nadir; glint; and target. The initial operational mode for OCO-2 alternates between nadir and glint mode every 16 days with target mode observations initiated by commanding the spacecraft to point to specific surface location. Of the 19 locations that can be observed by OCO-2 in target mode, 18 are TCCON sites. The decision to target a specific TCCON site is based on a variety of criteria, including the local weather forecast, the operational status of the station, and the time since previous observation of that site. In addition, the coincidence criteria to utilize in comparison between the satellite and TCCON measurements have been refined during the ACOS project and will be utilized to compare OCO-2 nadir and glint observations with TCCON data. In this presentation, we will show preliminary comparisons between OCO-2 and TCCON, using data from all satellite observing modes.

Astronomical tunings of the Oligocene-Miocene transition from Pacific Ocean Site U1334 and implications for the carbon cycle

NASA Astrophysics Data System (ADS)

Beddow, Helen M.; Liebrand, Diederik; Wilson, Douglas S.; Hilgen, Frits J.; Sluijs, Appy; Wade, Bridget S.; Lourens, Lucas J.

2018-03-01

Astronomical tuning of sediment sequences requires both unambiguous cycle pattern recognition in climate proxy records and astronomical solutions, as well as independent information about the phase relationship between these two. Here we present two different astronomically tuned age models for the Oligocene-Miocene transition (OMT) from Integrated Ocean Drilling Program Site U1334 (equatorial Pacific Ocean) to assess the effect tuning has on astronomically calibrated ages and the geologic timescale. These alternative age models (roughly from ˜ 22 to ˜ 24 Ma) are based on different tunings between proxy records and eccentricity: the first age model is based on an aligning CaCO3 weight (wt%) to Earth's orbital eccentricity, and the second age model is based on a direct age calibration of benthic foraminiferal stable carbon isotope ratios (δ13C) to eccentricity. To independently test which tuned age model and associated tuning assumptions are in best agreement with independent ages based on tectonic plate-pair spreading rates, we assign the tuned ages to magnetostratigraphic reversals identified in deep-marine magnetic anomaly profiles. Subsequently, we compute tectonic plate-pair spreading rates based on the tuned ages. The resultant alternative spreading-rate histories indicate that the CaCO3 tuned age model is most consistent with a conservative assumption of constant, or linearly changing, spreading rates. The CaCO3 tuned age model thus provides robust ages and durations for polarity chrons C6Bn.1n-C7n.1r, which are not based on astronomical tuning in the latest iteration of the geologic timescale. Furthermore, it provides independent evidence that the relatively large (several 10 000 years) time lags documented in the benthic foraminiferal isotope records relative to orbital eccentricity constitute a real feature of the Oligocene-Miocene climate system and carbon cycle. The age constraints from Site U1334 thus indicate that the delayed responses of the Oligocene-Miocene climate-cryosphere system and (marine) carbon cycle resulted from highly non-linear feedbacks to astronomical forcing.

Carbon Dioxide and CO2 Isotopes at Three Spatial Scales Over the Rocky Mountains

NASA Astrophysics Data System (ADS)

Bowling, D. R.; Schaeffer, S. M.; Miller, J. B.; Stephens, B. B.

2006-12-01

Recent studies highlight the importance of western mountain regions to the North American carbon sink, suggesting 25 to 50 percent of the U.S. sink can be attributed to montane ecosystems. Isotopes of CO2 provide insight into ecosystem carbon cycling, plant physiological processes, and atmospheric boundary-layer dynamics, and are useful in integration of processes over multiple scales. CO2 isotopes have played a central role in our understanding of the magnitude and inter-annual dynamics of the terrestrial carbon sink at a variety of spatial and temporal scales, and will be crucial to understanding the carbon balance and carbon accounting of the North American continent. In 2005, we began a long-term study examining biosphere- atmosphere exchange of CO2 and its stable isotopes over the Rocky Mountains in Colorado. Measurements are made at 3 sites representing 3 different spatial scales. These include a subalpine forest site (3050 m elevation, the Niwot Ridge AmeriFlux site), a tundra site 3 km away (3520 m, representing the overlying forest air), and an aircraft site 125 km to the northeast over the plains (vertical profiles from ground level at 1740 m to 8000 m, representing the regional convective boundary layer and the free troposphere). The tundra (NWR) and aircraft (CAR) sites have been part of NOAA/CCGG Cooperative Air Sampling Network for many years. Observed CO2 and δ13C showed seasonal variation (> 10 ppm and >0.5 permil) and strong local variation at all sites (>100 ppm and >5 permil at the forest site). The forest exerted a strong respiratory influence on the overlying air during the fall and winter. Measurements 10m above the top of the forest canopy in winter were always higher in CO2 (~ 3 ppm) and more negative in δ13C of CO2 ~ 0.3 permil) than those at the tundra site. Summer data are still being analyzed, but we expect this to shift in the other direction during the growing season. Substantial synoptic variation in CO2 and δ13C was observed at all three sites, sometimes with simultaneous changes at all sites, sometimes not. The diurnal and seasonal patterns of CO2 and δ13C at the three sites will be discussed, and these data will be used to assess the local variability of the long-term CO2 (since 1968) and δ13C (since 1990) record at Niwot Ridge.

Estimation of Community Land Model parameters for an improved assessment of net carbon fluxes at European sites

NASA Astrophysics Data System (ADS)

Post, Hanna; Vrugt, Jasper A.; Fox, Andrew; Vereecken, Harry; Hendricks Franssen, Harrie-Jan

2017-03-01

The Community Land Model (CLM) contains many parameters whose values are uncertain and thus require careful estimation for model application at individual sites. Here we used Bayesian inference with the DiffeRential Evolution Adaptive Metropolis (DREAM(zs)) algorithm to estimate eight CLM v.4.5 ecosystem parameters using 1 year records of half-hourly net ecosystem CO2 exchange (NEE) observations of four central European sites with different plant functional types (PFTs). The posterior CLM parameter distributions of each site were estimated per individual season and on a yearly basis. These estimates were then evaluated using NEE data from an independent evaluation period and data from "nearby" FLUXNET sites at 600 km distance to the original sites. Latent variables (multipliers) were used to treat explicitly uncertainty in the initial carbon-nitrogen pools. The posterior parameter estimates were superior to their default values in their ability to track and explain the measured NEE data of each site. The seasonal parameter values reduced with more than 50% (averaged over all sites) the bias in the simulated NEE values. The most consistent performance of CLM during the evaluation period was found for the posterior parameter values of the forest PFTs, and contrary to the C3-grass and C3-crop sites, the latent variables of the initial pools further enhanced the quality-of-fit. The carbon sink function of the forest PFTs significantly increased with the posterior parameter estimates. We thus conclude that land surface model predictions of carbon stocks and fluxes require careful consideration of uncertain ecological parameters and initial states.

Clay mineral continental amplifier for marine carbon sequestration in a greenhouse ocean.

PubMed

Kennedy, Martin J; Wagner, Thomas

2011-06-14

The majority of carbon sequestration at the Earth's surface occurs in marine continental margin settings within fine-grained sediments whose mineral properties are a function of continental climatic conditions. We report very high mineral surface area (MSA) values of 300 and 570 m(2) g in Late Cretaceous black shales from Ocean Drilling Program site 959 of the Deep Ivorian Basin that vary on subcentennial time scales corresponding with abrupt increases from approximately 3 to approximately 18% total organic carbon (TOC). The observed MSA changes with TOC across multiple scales of variability and on a sample-by-sample basis (centimeter scale), provides a rigorous test of a hypothesized influence on organic carbon burial by detrital clay mineral controlled MSA. Changes in TOC also correspond with geochemical and sedimentological evidence for water column anoxia. Bioturbated intervals show a lower organic carbon loading on mineral surface area of 0.1 mg-OC m(-2) when compared to 0.4 mg-OC m(-2) for laminated and sulfidic sediments. Although either anoxia or mineral surface protection may be capable of producing TOC of < 5%, when brought together they produced the very high TOC (10-18%) apparent in these sediments. This nonlinear response in carbon burial resulted from minor precession-driven changes of continental climate influencing clay mineral properties and runoff from the African continent. This study identifies a previously unrecognized land-sea connection among continental weathering, clay mineral production, and anoxia and a nonlinear effect on marine carbon sequestration during the Coniacian-Santonian Oceanic Anoxic Event 3 in the tropical eastern Atlantic.

Soil data for a vegetation gradient located at Bonanza Creek Long Term Ecological Research Site, interior Alaska

USGS Publications Warehouse

Manies, Kristen L.; Harden, Jennifer W.; Fuller, Christopher C.; Xu, Xiaomei; McGeehin, John P.

2016-07-28

Boreal soils play an important role in the global carbon cycle owing to the large amount of carbon stored within this northern region. To understand how carbon and nitrogen storage varied among different ecosystems, a vegetation gradient was established in the Bonanza Creek Long Term Ecological Research (LTER) site, located in interior Alaska. The ecosystems represented are a black spruce (Picea mariana)–feather moss (for example, Hylocomium sp.) forest ecosystem, a shrub-dominated ecosystem, a tussock-grass-dominated ecosystem, a sedge-dominated ecosystem, and a rich fen ecosystem. Here, we report the physical, chemical, and descriptive properties for the soil cores collected at these sites. These data have been used to calculate carbon and nitrogen accumulation rates on a long-term (decadal and century) basis (Manies and others, in press).

BOREAS TGB-12 Rn-222 Flux Data over the NSA

NASA Technical Reports Server (NTRS)

Hall, Forrest G. (Editor); Conrad, Sara K.; Trumbore, Susan; Sundquist, Eric; Winston, Greg

2000-01-01

The BOREAS TGB-12 team made measurements of soil carbon inventories, carbon concentration in soil gases, and rates of soil respiration at several sites to estimate the rates of carbon accumulation and turnover in each of the major vegetation types. Sampling strategies for soils were designed to take advantage of local fire chronosequences, so that the accumulation of carbon in new moss growth could be determined. All the data are used to 1) calculate the inventory of carbon and nitrogen in moss and mineral soil layers at NSA sites, 2) determine the rates of input and turnover (using both accumulation since the last stand-killing fire and radiocarbon data), and 3) link changes in soil respiration rate to shifts in the C-14 content of soil CO2 to determine the average "age" respired CO2. These Rn-222 flux data were collected from 15-Nov-1993 to 16-Aug-1994 over the NSA sites. The data in this data set are stored in tabular ASCII files.

The effects of land use on fluvial sediment chemistry for the conterminous U.S. - Results from the first cycle of the NAWQA Program: Trace and major elements, phosphorus, carbon, and sulfur

USGS Publications Warehouse

Horowitz, A.J.; Stephens, V.C.

2008-01-01

In 1991, the U.S. Geological Survey (USGS) began the first cycle of its National Water Quality Assessment (NAWQA) Program. The Program encompassed 51 river basins that collectively accounted for more than 70% of the total water use (excluding power generation), and 50% of the drinking water supply in the U.S. The basins represented a variety of hydrologic settings, rock types (geology), land-use categories, and population densities. One aspect of the first cycle included bed sediment sampling; sites were chosen to represent baseline and important land-use categories (e.g., agriculture, urban) in each basin. In total, over 1200 bed sediment samples were collected. All samples were size-limited (< 63????m) to facilitate spatial and/or temporal comparisons, and subsequently analyzed for a variety of chemical constituents including major (e.g., Fe, Al,) and trace elements (e.g., Cu, Zn, Cd), nutrients (e.g., P), and carbon. The analyses yielded total (??? 95% of the concentrations present), rather than total-recoverable chemical data. Land-use percentages, upstream underlying geology, and population density were determined for each site and evaluated to asses their relative influence on sediment chemistry. Baseline concentrations for the entire U.S. also were generated from a subset of all the samples, and are based on material collected from low population (??? 27??p km- 2) density, low percent urban (??? 5%), agricultural or undeveloped areas. The NAWQA baseline values are similar to those found in other national and global datasets. Further, it appears that upstream/underlying rock type has only a limited effect (mostly major elements) on sediment chemistry. The only land-use category that appears to substantially affect sediment chemistry is percent urban, and this result is mirrored by population density; in fact, the latter appears more consistent than the former.

A method for quantifying bioavailable organic carbon in aquifer sediments

USGS Publications Warehouse

Rectanus, H.V.; Widdowson, M.; Novak, J.; Chapelle, F.

2005-01-01

The fact that naturally occurring microorganisms can biodegrade PCE and TCE allows the use of monitored natural attenuation (MNA) as a remediation strategy at chlorinated solvent-contaminated sites. Research at numerous chlorinated solvent sites indicates an active dechlorinating microbial population coupled with an ample supply of organic carbon are conditions needed to sustain reductive dechlorination. A series of extraction experiments was used to compare the ability of the different extractants to remove organic carbon from aquifer sediments. The different extractants included pyrophosphate, sodium hydroxide, and polished water. Pyrophosphate served as a mild extractant that minimally alters the organic structure of the extracted material. Three concentrations (0.1, 0.5, and 1%) of pyrophosphate extracted 18.8, 24.9, and 30.8% of sediment organic carbon, respectively. Under alkali conditions (0.5 N NaOH), which provided the harshest extractant, 30.7% of the sediment organic carbon was recovered. Amorphous organic carbon, measured by potassium persulfate oxidization, consisted of 44.6% of the sediment organic carbon and served as a baseline control for maximum carbon removal. Conversely, highly purified water provided a minimal extraction control and extracted 5.7% of the sediment organic carbon. The removal of organic carbon was quantified by aqueous TOC in the extract and residual sediment organic carbon content. Characterization of the organic carbon extracts by compositional analysis prior and after exposure to the mixed culture might indicate the type organic carbon and functional groups used and/or generated by the organisms. This is an abstract of a paper presented at the 8th International In Situ and On-Site Bioremediation Symposium (Baltimore, MD 6/6-9/2005).

The Degradation of 14C-Glutamic Acid by L-Glutamic Acid Decarboxylase.

ERIC Educational Resources Information Center

Dougherty, Charles M; Dayan, Jean

1982-01-01

Describes procedures and semi-micro reaction apparatus (carbon dioxide trap) to demonstrate how a particular enzyme (L-Glutamic acid decarboxylase) may be used to determine the site or sites of labeling in its substrate (carbon-14 labeled glutamic acid). Includes calculations, solutions, and reagents used. (Author/SK)

Seasonal variation of organic aerosol in PM2.5 at Anmyeondo, a background site in Korea

NASA Astrophysics Data System (ADS)

Lee, J.; Kim, E. S.; Kim, Y. P.; Jung, C. H.; Lee, J.

2016-12-01

Routine measurements of PM2.5 and chemical speciation for 100 individual organic compounds were carried out to understand seasonal variation of organic compounds at a background area in Korea between 2015 and 2016. Organic compounds analyzed in this study were classified into five groups, n-alkanes, polycyclic aromatic hydrocarbons (PAHs), fatty acids (FA), dicarboxylic acids (DCAs), and sugar. Further, organic carbon (OC), elemental carbon (EC), water-soluble organic carbon (WSOC) and Humic Like Substance-Carbon (HULIS-C) in PM2.5 were simultaneously analyzed to make mass balance of carbonaceous aerosol in PM2.5 at a background site in Korea. PAHs concentrations at this site was lower than that at Seoul, a representative urban site in Korea. PAHs and n-Alkanes concentrations showed clear seasonal variation with summer minimum and winter maximum, while, seasonal variation of DCAs and Sugars were different with PAHs and n-Alkanes.WSOC concentrations were highly correlated with SOC (Secondary Organic Carbon) concentrations which were estimated by the EC tracer method. The results indicate the formation of secondary organic aerosol (SOA) is major factor for the determination of WSOC concentrations in this region. HULIS-C as known one of brown carbon was major component of WSOC which accounts for 39 to 99% in WSOC. The average concentrations of HULIS-C was 2.02±1.42 and the highest concentration was observed in fall.

A modern soil carbon stock baseline for the conterminous United States

NASA Astrophysics Data System (ADS)

Loecke, T.; Wills, S. A.; Teachman, G.; Sequeira, C.; West, L.; Wijewardane, N.; Ge, Y.

2016-12-01

The Rapid Carbon Assessment Project was undertaken to ascertain the soil carbon stocks across the conterminous US at one point in time. Sample locations were chosen randomly from the NRI (National Resource Inventory) sampling framework and cover all areas in CONUS with SSURGO certified maps as of Dec 2010. The project was regionalized into 17 areas for logistical reasons. Within each region, soils were grouped by official series description properties. Sites were selected by soil groups and land use/cover as indicated by NRI or NLCD (USGS National Land Cover Dataset) class so that more extensive soils groups and/or land use/covers received more points and less extensive fewer points (with a minimum of 5 sites). Each region had 375 - 400 sites, for a total of approximately 6,400 sites. At each site, basic information about land use, vegetation and management were collected as appropriate and available. Samples were collected from 5 pedons (a central and 4 satellites) per site to a depth of 1m, at 0 - 5cm and by genetic horizon. A volumetric sample was collected for horizons above 50 cm to determine bulk density. For horizons below 50cm (or when a volumetric sample could not be obtained) bulk density was modeled from morphological information. All samples were air dried and crushed to <2mm. The central pedon was analyzed for total and organic carbon at the Kellogg Soil Science Laboratory in Lincoln, NE. A visible near-infrared (VNIR) spectrophotometer was used to predict organic and inorganic carbon contents for all satellites samples. A Hierarchical Bayesian statistical approach was used to estimate C stocks, concentrations, and uncertainty for each sampling level (i.e., CONUS, region, soil group, landuse and site). Carbon concentration and stocks were summarized by surface horizon and depth increments for sites, soil groups, and land use/groups and mapped by linking the values to a raster of SSURGO (Jan 2012) that includes map unit and NLCD classification. This modern soil C stock baseline data set will be useful for many application in climate science and biogeochemistry.

Modelling past, present and future peatland carbon accumulation across the pan-Arctic region

NASA Astrophysics Data System (ADS)

Chaudhary, Nitin; Miller, Paul A.; Smith, Benjamin

2017-09-01

Most northern peatlands developed during the Holocene, sequestering large amounts of carbon in terrestrial ecosystems. However, recent syntheses have highlighted the gaps in our understanding of peatland carbon accumulation. Assessments of the long-term carbon accumulation rate and possible warming-driven changes in these accumulation rates can therefore benefit from process-based modelling studies. We employed an individual-based dynamic global ecosystem model with dynamic peatland and permafrost functionalities and patch-based vegetation dynamics to quantify long-term carbon accumulation rates and to assess the effects of historical and projected climate change on peatland carbon balances across the pan-Arctic region. Our results are broadly consistent with published regional and global carbon accumulation estimates. A majority of modelled peatland sites in Scandinavia, Europe, Russia and central and eastern Canada change from carbon sinks through the Holocene to potential carbon sources in the coming century. In contrast, the carbon sink capacity of modelled sites in Siberia, far eastern Russia, Alaska and western and northern Canada was predicted to increase in the coming century. The greatest changes were evident in eastern Siberia, north-western Canada and in Alaska, where peat production hampered by permafrost and low productivity due the cold climate in these regions in the past was simulated to increase greatly due to warming, a wetter climate and higher CO2 levels by the year 2100. In contrast, our model predicts that sites that are expected to experience reduced precipitation rates and are currently permafrost free will lose more carbon in the future.

Century-long acidification reveals possible consequences of coral reef sediment dissolution

NASA Astrophysics Data System (ADS)

Fink, A.; Hassenrueck, C.; Guilini, K.; Lichtschlag, A.; Borisov, S.; Fabricius, K.; de Beer, D.

2016-02-01

Coarse permeable carbonate sediments play a key role as biocatalytical filters in element cycling on coral reefs, but are subjected to increased dissolution due to ocean acidification (OA). We investigated coral reef sediment properties and remineralization rates along a pH gradient in an area of volcanic CO2 seeping within a fringing coral reef (Papua New Guinea). In coarse carbonate-rich sediments of the reference site (water column pHT = 8.1) in-situ microprofiles showed a buffered porewater pH of 7.7 to 7.9. In contrast, sites with diffuse CO2 seeping (water column pHT 8.0 to 7.7) experienced porewater pH of less than 6 to 7. At the seep sites, the sediments were almost free of carbonates and were dominated by silicates. We found that this resulted in reduced grain sizes leading to decreased permeability and oxygen penetration into the sediment. Areal oxygen consumption and sulfate reduction rates declined at the seep sites. The pattern in oxygen consumption could be explained by oxygen limitation due to lower permeability. However, sulfate reduction was never limited by electron acceptor, indicating that the seep site sediments were limited in electron donors. In line with lower process rates, abundances of microorganisms and meiofauna declined at the seep sites. Our findings suggest that an enhanced dissolution of carbonate sediments due to OA could impact their biocatalytical filtration function. This could slow down the intense element cycling in coral reefs and other coastal carbonate environments, with consequences for ecosystem productivity and functioning.

Carbon Cycling Dynamics in Response to Pine Beetle Infection and Climate Variation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Monson, Russell K.

2015-01-26

We originally proposed to study and discover the changes that have occurred in soil carbon pools, as a result of tree mortality due to beetle infection, and the ease by which those pools release CO2 to the atmosphere in mountain forests in the Western US. We studied forest plots at two sites – the Niwot Ridge AmeriFlux site and the Fraser Experimental Forest site, both in Colorado.

Carbon dioxide effluxes and their environmental controls in sagebrush steppe ecosystems along an elevation gradient in the Reynolds Creek Critical Zone Observatory

NASA Astrophysics Data System (ADS)

Lohse, K. A.; Fellows, A.; Flerchinger, G. N.; Seyfried, M. S.

2017-12-01

The spatial and temporal variation of carbon dioxide effluxes and their environmental controls are poorly constrained in cold shrub steppe ecosystems. The objectives of this study were to 1) analyze environmental parameters in determining soil CO2 efflux, 2) assess the level of agreement between manual chambers and force diffusion (FD) soil CO2 efflux chambers, when both measurements are extrapolated across the growing season, and lastly to compare respiration fluxes to modeled ecosystem respiration fluxes. We installed FD chambers at four sites co-located with eddy covariance (EC) towers and soil moisture and temperature sensors along an elevation gradient in the Reynolds Creek Critical Zone Observatory in SW Idaho. FD chamber fluxes were collected continuously at 15-minute intervals. We sampled soil CO2 efflux with manual chambers at plant and interplant spaces in five plots at each site biweekly to monthly during the growing season. The sites included a Wyoming big sagebrush site, a low sagebrush site, a post-fire mountain big sagebrush site, and a mountain big sagebrush site located at elevations of 1425, 1680, 1808 and 2111 m. Climate variation followed the montane elevation gradient; mean annual precipitation (MAP) at the sites is 290, 337, 425, and 795 mm, respectively, and mean annual temperature is 8.9, 8.4, 6.1, 5.4°C. Automated force diffusion chambers detected large differences in carbon dioxide pulse dynamics along the elevation gradient. Growing season carbon dioxide fluxes were 3 times higher at the 425 mm MAP site compared than the lowest elevation sites at 290 and 337 MAP sites and >1.5 higher than the 795 mm MAP site over the same period. Manual fluxes showed similar seasonal patterns as FD chamber fluxes but often higher and greater spatial variability in fluxes than FD chamber fluxes. Plant and interplant flux differences were surprisingly similar, especially at higher elevations. Soil respiration ranged from 0.2-0.48 of ecosystem respiration suggesting that aboveground maintenance costs were relatively high at all of these sites. We conclude that coupled FD chamber, EC tower, and manual estimates hold promise in helping to partition and scale carbon fluxes from the plot to landscape scale.

Design of Zeolitic Imidazolate Framework Derived Nitrogen-Doped Nanoporous Carbons Containing Metal Species for Carbon Dioxide Fixation Reactions.

PubMed

Toyao, Takashi; Fujiwaki, Mika; Miyahara, Kenta; Kim, Tae-Ho; Horiuchi, Yu; Matsuoka, Masaya

2015-11-01

Various N-doped nanoporous carbons containing metal species were prepared by direct thermal conversion of zeolitic imidazolate frameworks (ZIFs; ZIF-7, -8, -9, and -67) at different temperatures (600, 800, and 1000 °C). These materials were utilized as bifunctional acid-base catalysts to promote the reaction of CO2 with epoxides to form cyclic carbonates under 0.6 MPa of CO2 at 80 °C. The catalyst generated by thermal conversion of ZIF-9 at 600 °C (C600-ZIF-9) was found to exhibit a higher catalytic activity than the other ZIFs, other conventional catalysts, and other metal-organic framework catalysts. The results of various characterization techniques including elemental analysis, X-ray diffraction, X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, and transmission electron microscopy show that C600-ZIF-9 contains partly oxidized Co nanoparticles and N species. Temperature-programmed desorption measurements by using CO2 and NH3 as probe molecules revealed that C600-ZIF-9 has both Lewis acid and Lewis base catalytic sites. Finally, the substrate scope was extended to seven other kinds of epoxides. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

One-Pot synthesis of phosphorylated mesoporous carbon heterogeneous catalysts with tailored surface acidity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fulvio, Pasquale F; Mahurin, Shannon Mark; Mayes, Richard T

2012-01-01

Soft-templated phosphorylated mesoporous carbons with homogeneous distributions of phosphate groups were prepared by a 'one-pot' synthesis method using mixtures of phosphoric acid with hydrochloric, or nitric acids in the presence of Pluronic F127 triblock copolymer. Adjusting the various ratios of phosphoric acid used in these mixtures resulted in carbons with distinct adsorption, structural and surface acidity properties. The pore size distributions (PSDs) from nitrogen adsorption at -196 C showed that mesoporous carbons exhibit specific surface areas as high as 551 m{sup 2}/g and mesopores as large as 13 nm. Both structural ordering of the mesopores and the final phosphate contentsmore » were strongly dependent on the ratios of H{sub 3}PO{sub 4} in the synthesis gels, as shown by transmission electron microscopy (TEM), X-ray photoelectron (XPS) and energy dispersive X-ray spectroscopy (EDS). The number of surface acid sites determined from temperature programmed desorption of ammonia (NH{sub 3}-TPD) were in the range of 0.3-1.5 mmol/g while the active surface areas are estimated to comprise 5-54% of the total surface areas. Finally, the conversion temperatures for the isopropanol dehydration were lowered by as much as 100 C by transitioning from the least acidic to the most acidic catalysts surface.« less

AmeriFlux US-MRf Mary's River (Fir) site

DOE Office of Scientific and Technical Information (OSTI.GOV)

Law, Bev

This is the AmeriFlux version of the carbon flux data for the site US-MRf Mary's River (Fir) site. Site Description - The Marys River Fir site is part of the "Synthesis of Remote Sensing and Field Observations to Model and Understand Disturbance and Climate Effects on the Carbon Balance of Oregon and Northern California (ORCA)". Located in the western region of Oregon the Marys River site represents the western extent of the climate gradient that spans eastward into the semi-arid basin of central Oregon. The sites that make up the eastern extent of the ORCA climate gradient is the Metoliusmore » site network (US-Me1, US-ME2, US-ME4, US-Me5) all of which are part of the TERRA PNW project at Oregon State University.« less

Aboveground carbon sequestration in dry temperate forests varies with climate not fire regime.

PubMed

Gordon, Christopher E; Bendall, Eli R; Stares, Mitchell G; Collins, Luke; Bradstock, Ross A

2018-06-01

The storage of carbon in plant tissues and debris has been proposed as a method to offset anthropogenic increases in atmospheric [CO 2 ]. Temperate forests represent significant above-ground carbon (AGC) "sinks" because their relatively fast growth and slow decay rates optimise carbon assimilation. Fire is a common disturbance event in temperate forests globally that should strongly influence AGC because: discrete fires consume above-ground biomass releasing carbon to the atmosphere, and the long-term application of different fire-regimes select for specific plant communities that sequester carbon at different rates. We investigated the latter process by quantifying AGC storage at 104 sites in the Sydney Basin Bioregion, Australia, relative to differences in components of the fire regime: frequency, severity and interfire interval. To predict the potential impacts of future climate change on fire/AGC interactions, we stratified our field sites across gradients of mean annual temperature and precipitation and quantified within- and between-factor interactions between the fire and climate variables. In agreement with previous studies, large trees were the primary AGC sink, accounting for ~70% of carbon at sites. Generalised additive models showed that mean annual temperature was the strongest predictor of AGC storage, with a 54% near-linear decrease predicted across the 6.1°C temperature range experienced at sites. Mean annual precipitation, fire frequency, fire severity and interfire interval were consistently poor predictors of total above-ground storage, although there were some significant relationships with component stocks. Our results show resilience of AGC to frequent and severe wildfire and suggest temperature mediated decreases in forest carbon storage under future climate change predictions. © 2018 John Wiley & Sons Ltd.

Determination of total carbonates in soil archaeometry using a new pressure method with temperature compensation

NASA Astrophysics Data System (ADS)

Barouchas, Pantelis; Koulos, Vasilios; Melfos, Vasilios

2017-04-01

For the determination of total carbonates in soil archaeometry a new technique was applied using a multi-sensor philosophy, which combines simultaneous measurement of pressure and temperature. This technology is innovative and complies with EN ISO 10693:2013, ASTM D4373-02(2007) and Soil Science Society of America standard test methods for calcium carbonate content in soils and sediments. The total carbonates analysis is based on a pressure method that utilizes the FOGII Digital Soil CalcimeterTM, which is a portable apparatus. The total carbonate content determined by treating a 1.000 g (+/- 0.001 g) dried sample specimens with 6N hydrochloric acid (HCL) reagent grade, in an enclosed reaction vessel. Carbon dioxide gas evolved during the reaction between the acid and carbonate fraction of the specimen, was measured by the resulting pressure generated, taking in account the temperature conditions during the reaction. Prior to analysis the procedure was validated with Sand/Soil mixtures from BIPEA proficiency testing program with soils of different origins. For applying this new method in archaeometry a total number of ten samples were used from various rocks which are related with cultural constructions and implements in Greece. They represent a large range of periods since the Neolithic times, and were selected because there was an uncertainty about their accurate mineralogical composition especially regarding the presence of carbonate minerals. The results were compared to the results from ELTRA CS580 inorganic carbon analyzer using an infrared cell. The determination of total carbonates for 10 samples from different ancient sites indicated a very good correlation (R2 >0.97) between the pressure method with temperature compensation and the infrared method. The proposed method is quickly and accurate in archaeometry and can replace easily other techniques for total carbonates testing. The FOGII Digital Soil CalcimeterTM is portable and easily can be carried for field work in archaeology.

Final Report: Results of Environmental Site Investigation at Sylvan Grove, Kansas

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, Lorraine M

Sylvan Grove is located in western Lincoln County, approximately 60 mi west of Salina, Kansas (Figure 1.1). From 1954 to 1966, the Commodity Credit Corporation (CCC), an agency of the U.S. Department of Agriculture (USDA), operated a grain storage facility at the northeastern edge of Sylvan Grove. During this time, commercial grain fumigants containing carbon tetrachloride were in common use to preserve grain in storage. In 1998, the Kansas Department of Health and Environment (KDHE) found carbon tetrachloride above the maximum contaminant level (MCL) of 5 μg/L in groundwater from one private well used for livestock and lawn and gardenmore » watering. The 1998 KDHE sampling at Sylvan Grove was conducted under the USDA private well sampling program. To determine whether the former CCC/USDA facility at Sylvan Grove is a potential contaminant source and its possible relationship to the contamination in groundwater, the CCC/USDA proposed to conduct an environmental site investigation, in accordance with the Intergovernmental Agreement between the KDHE and the Farm Service Agency (FSA) of the USDA. Argonne National Laboratory, on behalf of the CCC/USDA, developed a work plan (Argonne 2012) for the site investigation and a supplemental work plan for indoor and ambient air sampling (Appendix A). The proposed work was approved by the KDHE (2012a, 2013). The investigations were performed by the Environmental Science Division of Argonne National Laboratory, on behalf of the CCC/USDA. The main activities for the site investigation were conducted in June 2012, and indoor and ambient air sampling was performed in February 2013. This report presents the findings of the investigations at Sylvan Grove.« less

Site Development, Operations, and Closure Plan Topical Report 5 An Assessment of Geologic Carbon Sequestration Options in the Illinois Basin. Phase III

DOE Office of Scientific and Technical Information (OSTI.GOV)

Finley, Robert; Payne, William; Kirksey, Jim

2015-06-01

The Midwest Geological Sequestration Consortium (MGSC) has partnered with Archer Daniels Midland Company (ADM) and Schlumberger Carbon Services to conduct a large-volume, saline reservoir storage project at ADM’s agricultural products processing complex in Decatur, Illinois. The Development Phase project, named the Illinois Basin Decatur Project (IBDP) involves the injection of 1 million tonnes of carbon dioxide (CO 2) into a deep saline formation of the Illinois Basin over a three-year period. This report focuses on objectives, execution, and lessons learned/unanticipated results from the site development (relating specifically to surface equipment), operations, and the site closure plan.

Long term aerosol and trace gas measurements in Central Amazonia

NASA Astrophysics Data System (ADS)

Artaxo, Paulo; Barbosa, Henrique M. J.; Ferreira de Brito, Joel; Carbone, Samara; Rizzo, Luciana V.; Andreae, Meinrat O.; Martin, Scot T.

2016-04-01

The central region of the Amazonian forest is a pristine region in terms of aerosol and trace gases concentrations. In the wet season, Amazonia is actually one of the cleanest continental region we can observe on Earth. A long term observational program started 20 years ago, and show important features of this pristine region. Several sites were used, between then ATTO (Amazon Tall Tower Observatory) and ZF2 ecological research site, both 70-150 Km North of Manaus, receiving air masses that traveled over 1500 km of pristine tropical forests. The sites are GAW regional monitoring stations. Aerosol chemical composition (OC/EC and trace elements) is being analysed using filters for fine (PM2.5) and coarse mode aerosol as well as Aerodyne ACSM (Aerosol Chemical Speciation Monitors). VOCs are measured using PTR-MS, while CO, O3 and CO2 are routinely measured. Aerosol absorption is being studied with AE33 aethalometers and MAAP (Multi Angle Absorption Photometers). Aerosol light scattering are being measured at several wavelengths using TSI and Ecotech nephelometers. Aerosol size distribution is determined using scanning mobility particle sizer at each site. Lidars measure the aerosol column up to 12 Km providing the vertical profile of aerosol extinction. The aerosol column is measures using AERONET sun photometers. In the wet season, organic aerosol comprises 75-85% of fine aerosol, and sulfate and nitrate concentrations are very low (1-3 percent). Aerosols are dominated by biogenic primary particles as well as SOA from biogenic precursors. Black carbon in the wet season accounts for 5-9% of fine mode aerosol. Ozone in the wet season peaks at 10-12 ppb at the middle of the day, while carbon monoxide averages at 50-80 ppb. Aerosol optical thickness (AOT) is a low 0.05 to 0.1 at 550 nm in the wet season. Sahara dust transport events sporadically enhance the concentration of soil dust aerosols and black carbon. In the dry season (August-December), long range transported biomass burning alters atmospheric composition very significantly. AOT can reach values as high as 2-3 at 550 nm, and concentrations of aerosol species and trace gases are strongly enriched.

Active chemisorption sites in functionalized ionic liquids for carbon capture.

PubMed

Cui, Guokai; Wang, Jianji; Zhang, Suojiang

2016-07-25

Development of novel technologies for the efficient and reversible capture of CO2 is highly desired. In the last decade, CO2 capture using ionic liquids has attracted intensive attention from both academia and industry, and has been recognized as a very promising technology. Recently, a new approach has been developed for highly efficient capture of CO2 by site-containing ionic liquids through chemical interaction. This perspective review focuses on the recent advances in the chemical absorption of CO2 using site-containing ionic liquids, such as amino-based ionic liquids, azolate ionic liquids, phenolate ionic liquids, dual-functionalized ionic liquids, pyridine-containing ionic liquids and so on. Other site-containing liquid absorbents such as amine-based solutions, switchable solvents, and functionalized ionic liquid-amine blends are also investigated. Strategies have been discussed for how to activate the existent reactive sites and develop novel reactive sites by physical and chemical methods to enhance CO2 absorption capacity and reduce absorption enthalpy. The carbon capture mechanisms of these site-containing liquid absorbents are also presented. Particular attention has been paid to the latest progress in CO2 capture in multiple-site interactions by amino-free anion-functionalized ionic liquids. In the last section, future directions and prospects for carbon capture by site-containing ionic liquids are outlined.

Phenological and physiological mechanisms underlying interannual variability of terrestrial net ecosystem production

NASA Astrophysics Data System (ADS)

Niu, S.; Luo, Y.; Hui, D.; Chen, J.

2013-12-01

The interannual variability (IAV) of atmospheric CO2 concentration varies substantial and is largely ascribed to IAV of terrestrial ecosystem carbon fluxes. However, we have limited understanding on the mechanisms that control the IAV on the carbon flux of terrestrial ecosystems. Here, we hypothesized that physiological and phonological processes regulate IAV significantly in terrestrial carbon uptake (i.e., net ecosystem production, NEP). To test this hypothesis, we analyzed eddy-covariance data from 24 sites with more than 8 years data in deciduous broadleaf forests (DBF), evergreen forests (EF), and grasslands (GRA) in the northern hemisphere. Ecosystem physiology is represented by the maximum carbon uptake capacity (NEPmax) in one year whereas phonology is represented by carbon uptake period (CUP). We found that yearly anomalies of CUP and NEPmax accounted for 40% and 60% separately, and 73% in combination, of the anomalies in annual NEP across all the 253 site-years, with their relative contributions varying among the sites. The IAV of CUP was determined by the anomalies of spring and autumn carbon uptake phenology, both of which were sensitive to climate changes but controlled by different environmental factors in different biomes. IAV of NEPmax was determined by summer precipitation anomalies in DBF and GRA. The results suggest that IAV of NEP is consistently co-determined by CUP and NEPmax anomalies among sites in the northern hemisphere. Overall, the mechanisms revealed by our study on NEP anomalies through changing in phenology and physiology contribute to predictive understanding of temporal dynamics of terrestrial carbon uptake.

Investigation of vertical distribution and morphology of indigenous organic matter at Sleeping Bear site, Michigan

NASA Astrophysics Data System (ADS)

West, C. C.; Lyon, W. G.; Ross, D. L.; Pennington, L. K.

1994-11-01

This study evaluates the nature and origin of particulate organic carbon and organic coatings on aquifer sands upgradient from a fuel spill site near the Sleeping Bear Dunes National Lakeshore in Michigan. The distribution of carbon was found to be highly complex due to the occurrence of high organic carbon horizons, bounded above and below by high carbonate sediments. The organic coatings on the sands were examined using white light and fluorescence microscopy and by scanning electron microscopy. Core samples were analyzed for organic and inorganic carbon, solution pH, humic/fulvic acid ratios, and insoluble organic matter content (that is, humin) as a function of depth from the ground surface. The organic geochemistry of the soil profile at this site was found to be significantly influenced by the carbonates producing a sharp boundary of precipitated organic matter. This boundary was followed by coatings of predominantly fulvic acid salts on mineral grains deeper in the soil column. The coatings extended into the aquifer. The existence of native organic films on sand grains is well documented in the soils literature. The study reported here was greatly aided by this information and provides the framework for future studies concerning the influence of carbon distribution, chemical identity, and morphology on contaminant fate and transport processes.

A Dynamic Programming Model for Optimizing Frequency of Time-Lapse Seismic Monitoring in Geological CO2 Storage

NASA Astrophysics Data System (ADS)

Bhattacharjya, D.; Mukerji, T.; Mascarenhas, O.; Weyant, J.

2005-12-01

Designing a cost-effective and reliable monitoring program is crucial to the success of any geological CO2 storage project. Effective design entails determining both, the optimal measurement modality, as well as the frequency of monitoring the site. Time-lapse seismic provides the best spatial coverage and resolution for reservoir monitoring. Initial results from Sleipner (Norway) have demonstrated effective monitoring of CO2 plume movement. However, time-lapse seismic is an expensive monitoring technique especially over the long term life of a storage project and should be used judiciously. We present a mathematical model based on dynamic programming that can be used to estimate site-specific optimal frequency of time-lapse surveys. The dynamics of the CO2 sequestration process are simplified and modeled as a four state Markov process with transition probabilities. The states are M: injected CO2 safely migrating within the target zone; L: leakage from the target zone to the adjacent geosphere; R: safe migration after recovery from leakage state; and S: seepage from geosphere to the biosphere. The states are observed only when a monitoring survey is performed. We assume that the system may go to state S only from state L. We also assume that once observed to be in state L, remedial measures are always taken to bring it back to state R. Remediation benefits are captured by calculating the expected penalty if CO2 seeped into the biosphere. There is a trade-off between the conflicting objectives of minimum discounted costs of performing the next time-lapse survey and minimum risk of seepage and its associated costly consequences. A survey performed earlier would spot the leakage earlier. Remediation methods would have been utilized earlier, resulting in savings in costs attributed to excessive seepage. On the other hand, there are also costs for the survey and remedial measures. The problem is solved numerically using Bellman's optimality principal of dynamic programming to optimize over the entire finite time horizon. We use a Monte Carlo approach to explore trade-offs between survey costs, remediation costs, and survey frequency and to analyze the sensitivity to leakage probabilities, and carbon tax. The model can be useful in determining a monitoring regime appropriate to a specific site's risk and set of remediation options, rather than a generic one based on a maximum downside risk threshold for CO2 storage as a whole. This may have implications on the overall costs associated with deploying Carbon capture and storage on a large scale.

Radionuclide solubility and speciation studies for the Yucca Mountain site characterization project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nitsche, H.; Roberts, K.; Prussin, T.

1992-12-01

Yucca Mountain, Nevada, USA, is being investigated for its suitability as a potential site for a geologic nuclear waste repository. As part of the site characterization studies, actinide solubilities and speciations were studied at pH 6, 7, and 8.5 at 25{degrees}C in two different groundwaters from the vicinity of Yucca Mountain. The groundwaters differ substantially in total dissolved carbonate concentration, and to a lesser extent in ionic strength. In the waters with higher carbonate content, the solubilities of neptunium(V) decreased, whereas those americium(III) increased at 25{degrees}KC and decreased at 60{degrees}C. The solids formed were sodium neptunium carbonates and americium hydroxycarbonates.more » Plutonium solubilities did not significantly change with changing water composition because the solubility-controlling solids were mostly amorphous Pu(IV) polymers that contained only small amounts of carbonate.« less

Radionuclide solubility and speciation studies for the Yucca Mountain site characterization project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nitsche, H.; Roberts, K.; Prussin, T.

1993-12-31

Yucca Mountain, Nevada, U.S.A., is being investigated for its suitability as a potential site for a geologic nuclear waste repository. As part of the site characterization studies, actinide solubilities and speciations were studied at pH 6, 7, and 8.5 at 25{degrees} and 60{degrees}C in two different groundwaters from the vicinity of Yucca Mountain. The groundwaters differ substantially in total dissolved carbonate concentration, and to a lesser extent in ionic strength. In the waters with higher carbonate content, the solubilities of neptunium(V) decreased, whereas those of americium (III) increased at 25{degrees}C and decreased at 60{degrees}C. The solids formed were sodium neptuniummore » carbonates and americium hydroxycarbonates. Plutonium solubilities did not significantly change with changing water composition because the solubility-controlling solids were mostly amorphous Pu(IV) polymers that contained only small amounts of carbonate.« less

FINE PARTICULATE MATTER SOURCE ATTRIBUTION FOR SOUTHEAST TEXAS USING 14C/13C RATIOS

EPA Science Inventory

Radiocarbon analyses of fine particulate matter samples collected during the summer of 2000 in southeast Texas indicate that a substantial fraction of the aerosol carbon at an urban/suburban site (27% to 73%) and at a rural, forested site (44% to 77%) was modern carbon. Data fr...

78 FR 15048 - SGL Carbon, LLC Including Leased On-Site Worker of Reflex Staffing Services and Manpower, St...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-03-08

... DEPARTMENT OF LABOR Employment and Training Administration [TA-W-82,113] SGL Carbon, LLC Including Leased On-Site Worker of Reflex Staffing Services and Manpower, St. Marys, Pennsylvania; Notice of... of graphite parts. The initial investigation resulted in a negative determination based on the...

INVESTIGATION OF VERTICAL DISTRIUBTION AND MORPHO- LOGY OF INDIGENOUS ORGANIC MATTER AT SLEEPING BEAR SITE, MICHIGAN

EPA Science Inventory

This study evaluates the nature and origin of particulate organic carbon and organic coatings on aquifer sands upgradient from a fuel spill site near the Sleeping Bear Dunes National Lakeshore in Michigan. The distribution of carbon was found to be highly complex due to the occur...

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory; determination of pesticides in water by Carbopak-B solid-phase extraction and high-preformance liquid chromatography

USGS Publications Warehouse

Werner, Stephen L.; Burkhardt, Mark R.; DeRusseau, Sabrina N.

1996-01-01

In accordance with the needs of the National Water-Quality Assessment Program (NAWQA), the U.S. Geological Survey has developed and implemented a graphitized carbon-based solid-phase extraction and high-performance liquid chromatographic analytical method. The method is used to determine 41 pesticides and pesticide metabolites that are not readily amenable to gas chromatography or other high-temperature analytical techniques. Pesticides are extracted from filtered environmental water samples using a 0.5-gram graphitized carbon-based solid-phase cartridge, eluted from the cartridge into two analytical fractions, and analyzed using high-performance liquid chromatography with photodiode-array detection. The upper concentration limit is 1.6 micrograms per liter (=B5g/L) for most compounds. Single-operator method detection limits in organic-free water samples ranged from 0.006 to 0.032 =B5g/L= Recoveries in organic-free water samples ranged from 37 to 88 percent. Recoveries in ground- and surface-water samples ranged from 29 to 94 percent. An optional on-site extraction procedure allows for samples to be collected and processed at remote sites where it is difficult to ship samples to the laboratory within the recommended pre-extraction holding time of 7 days.

Conversion of 1,2-Propylene Glycol on Rutile TiO2(110)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Long; Li, Zhenjun; Smith, R. Scott

2014-07-17

We have studied the reactions of 1,2-propylene glycol (1,2-PG), DOCH(CH3)CH2OD, on partially reduced, hydroxylated and oxidized TiO2(110) surfaces using temperature programmed desorption. On reduced TiO2(110), propylene, propanal, and acetone are identified as primary carbon-containing products. While the propylene formation channel dominates at low 1,2-PG coverages, all of the above-mentioned products are observed at high coverages. The carbon-containing products are accompanied by the formation of D2O and D2. The observation of only deuterated products shows that the source of hydrogen (D) is from the 1,2-PG hydroxyls. The role of bridging oxygen vacancy (VO) sites was further investigated by titrating them viamore » hydroxylation and oxidation. The results show that hydroxylation does not change the reactivity because the VO sites are regenerated at 500 K, which is a temperature lower than the 1,2-PG product formation temperature. In contrast, surface oxidation causes significant changes in the product distribution, with increased acetone and propanal formation and decreased propylene formation. Additionally D2 is completely eliminated as an observed product at the expense of D2O formation.« less

The effect of Sn on the reactions of n-hexane and cyclohexane over polycrystalline Pt foils

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fujikawa, T.; Ribeiro, F.H.; Somorjai, G.A.

The modification of the catalytic properties of a polycrystalline platinum foil by the addition of tin was studied by the reactions of n-hexane and cyclohexane in excess H{sub 2}. The reactions were studied at 13.3 kPa of n-hexane, 450 kPa of H{sub 2} and 740 K, and 6.7 kPa of cyclohexane, 450 kPa of H{sub 2} and 573 K. The Pt-Sn catalyst was characterized by Auger electron spectroscopy and by temperature-programmed desorption of CO before and after the reactions. The sites that bind CO most strongly on the Pt foil also have the highest initial turnover rate and are themore » first ones to be poisoned by carbon deposits from hydrocarbon reactions or by sulfur when a sulfur-containing compound (thiophene) is present in the feed. The addition of tin can block these sites preferentially, thus decreasing the undesirable high initial hydrogenolysis rate of platinum catalysts in reforming reactions and eliminating the need for presulfiding the catalyst. Also, tin suppressed the hydrogenolysis reaction preferentially to the isomerization and cyclization reactions thus increasing the selectivities to isomerization and cyclization. The amount of carbon deposited was smaller on tin containing platinum catalysts during the dehydrogenation of cyclohexane and n-hexane.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Maiti, Debtanu; Daza, Yolanda A.; Yung, Matthew M.

Density functional theory (DFT) based investigation of two parameters of prime interest -- oxygen vacancy and surface terminations along (100) and (110) planes -- has been conducted for La (1-x)Sr xFe(1-y)Co yO (3-more » $$\\delta$$) perovskite oxides in view of their application towards thermochemical carbon dioxide conversion reactions. The bulk oxygen vacancy formation energies for these mixed perovskite oxides are found to increase with increasing lanthanum and iron contents in the 'A' site and 'B' site, respectively. Surface terminations along (100) and (110) crystal planes are studied to probe their stability and their capabilities to accommodate surface oxygen vacancies. Amongst the various terminations, the oxygen-rich (110) surface and strontium-rich (100) surface are the most stable, while transition metal-rich terminations along (100) revealed preference towards the production of oxygen vacancies. The carbon dioxide adsorption strength, a key descriptor for CO 2 conversion reactions, is found to increase on oxygen vacant surfaces thus establishing the importance of oxygen vacancies in CO 2 conversion reactions. Amongst all the surface terminations, the lanthanum-oxygen terminated surface exhibited the strongest CO 2 adsorption strength. Finally, the theoretical prediction of the oxygen vacancy trends and the stability of the samples were corroborated by the temperature-programmed reduction and oxidation reactions and in situ XRD crystallography.« less

Age depth model construction of the upper section of ICDP Dead Sea Deep Drilling Project based on the high-resolution 14C dating

NASA Astrophysics Data System (ADS)

Kitagawa, H.; Nakamura, T.; Neugebauer, I.; Schwab, M. J.; Brauer, A.; Goldstein, S. L.; Stein, M.

2014-12-01

To reconstruct environmental, climatic and tectonic histories of the Levant, a deep drilling has been accomplished in the northern basin of the Dead Sea during the fall winter of 2010-2011 by the Dead Sea Deep Drilling Project (DSDDP) in the framework of the ICDP program. The sediment cores from site 5017-1 (water depth of ~300 m) recorded the paleoenvironmental and paleohydrological changes in the Dead Sea and the Levant during the last two glacial-interglacial cycles (Neugebauer et al., QSR in press). To provide precise timing of sedimentological - limnological events in the lake and its watershed, and more critically the relative timing of these events, radiocarbon dating of >70 well-preserved terrestrial plants and some carbonate deposits from the upper 150 m long section of the sediment core were performed. Based on the high-resolution radiocarbon dating, a statistical age-depth model was constructed with assumptions on the deposition condition and the radiocarbon age offset of carbonate samples. We discuss the practicality and the limitation of the age-depth model toward interpreting the high-resolution records of environmental, climatic and tectonic events recorded in the long sediment cores from site 5017-1.

Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst

NASA Astrophysics Data System (ADS)

Chung, Hoon T.; Cullen, David A.; Higgins, Drew; Sneed, Brian T.; Holby, Edward F.; More, Karren L.; Zelenay, Piotr

2017-08-01

Platinum group metal-free (PGM-free) metal-nitrogen-carbon catalysts have emerged as a promising alternative to their costly platinum (Pt)-based counterparts in polymer electrolyte fuel cells (PEFCs) but still face some major challenges, including (i) the identification of the most relevant catalytic site for the oxygen reduction reaction (ORR) and (ii) demonstration of competitive PEFC performance under automotive-application conditions in the hydrogen (H2)-air fuel cell. Herein, we demonstrate H2-air performance gains achieved with an iron-nitrogen-carbon catalyst synthesized with two nitrogen precursors that developed hierarchical porosity. Current densities recorded in the kinetic region of cathode operation, at fuel cell voltages greater than ~0.75 V, were the same as those obtained with a Pt cathode at a loading of 0.1 milligram of Pt per centimeter squared. The proposed catalytic active site, carbon-embedded nitrogen-coordinated iron (FeN4), was directly visualized with aberration-corrected scanning transmission electron microscopy, and the contributions of these active sites associated with specific lattice-level carbon structures were explored computationally.

Delta-Flux: An eddy covariance network for a climate-smart Lower Mississippi Basin

USGS Publications Warehouse

Runkle, Benjamin R. K.; Rigby, James R.; Reba, Michele L.; Anapalli, Saseendran S.; Bhattacharjee, Joydeep; Krauss, Ken W.; Liang, Lu; Locke, Martin A.; Novick, Kimberly A.; Sui, Ruixiu; Suvočarev, Kosana; White, Paul M.

2017-01-01

Networks of remotely monitored research sites are increasingly the tool used to study regional agricultural impacts on carbon and water fluxes. However, key national networks such as the National Ecological Observatory Network and AmeriFlux lack contributions from the Lower Mississippi River Basin (LMRB), a highly productive agricultural area with opportunities for soil carbon sequestration through conservation practices. The authors describe the rationale to create the new Delta-Flux network, which will coordinate efforts to quantify carbon and water budgets at seventeen eddy covariance flux tower sites in the LMRB. The network structure will facilitate climate-smart management strategies based on production-scale and continuous measurements of carbon and water fluxes from the landscape to the atmosphere under different soil and water management conditions. The seventeen instrumented field sites are expected to monitor fluxes within the most characteristic landscapes of the target area: row-crop fields, pasture, grasslands, forests, and marshes. The network participants are committed to open collaboration and efficient regionalization of site-level findings to support sustainable agricultural and forestry management and conservation of natural resources.

Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst

DOE PAGES

Chung, Hoon T.; Cullen, David A.; Higgins, Drew; ...

2017-08-04

Platinum group metal–free (PGM-free) metal-nitrogen-carbon catalysts have emerged as a promising alternative to their costly platinum (Pt)–based counterparts in polymer electrolyte fuel cells (PEFCs) but still face some major challenges, including (i) the identification of the most relevant catalytic site for the oxygen reduction reaction (ORR) and (ii) demonstration of competitive PEFC performance under automotive-application conditions in the hydrogen (H 2)–air fuel cell. We demonstrate H 2-air performance gains achieved with an iron-nitrogen-carbon catalyst synthesized with two nitrogen precursors that developed hierarchical porosity. In current densities recorded in the kinetic region of cathode operation, at fuel cell voltages greater thanmore » ~0.75 V, were the same as those obtained with a Pt cathode at a loading of 0.1 milligram of Pt per centimeter squared. The catalytic active site we proposed, carbon-embedded nitrogen-coordinated iron (FeN 4), was directly visualized with aberration-corrected scanning transmission electron microscopy, and the contributions of these active sites associated with specific lattice-level carbon structures were explored computationally.« less

Materials property definition and generation for carbon-carbon and carbon phenolic materials

NASA Technical Reports Server (NTRS)

Canfield, A. R.; Mathis, J. R.; Starrett, H. S.; Koenig, J. R.

1987-01-01

A data base program to generate statistically significant material-property data for carbon-carbon and carbon phenolic materials to be used in designs of Space Shuttle is described. The program, which will provide data necessary for thermal and stress modeling of Shuttle nozzle and exit cone structures, includes evaluation of tension, compression, shear strength, shear modulus, thermal expansion, thermal conductivity, permeability, and emittance for both materials; the testing of carbon phenolic materials also includes CTE, off-gassing, pyrolysis, and RTG. Materials to be tested will be excised from Space Shuttle inlet, throat, and exit cone billets and modified involute carbon-carbon exit cones; coprocessed blocks, panels, and cylinders will also be tested.

Multi-element compound specific stable isotope analysis of chlorinated aliphatic contaminants derived from chlorinated pitches.

PubMed

Filippini, Maria; Nijenhuis, Ivonne; Kümmel, Steffen; Chiarini, Veronica; Crosta, Giovanni; Richnow, Hans H; Gargini, Alessandro

2018-05-30

Tetrachloroethene and trichloroethene are typical by-products of the industrial production of chloromethanes. These by-products are known as "chlorinated pitches" and were often dumped in un-contained waste disposal sites causing groundwater contaminations. Previous research showed that a strongly depleted stable carbon isotope signature characterizes chlorinated compounds associated with chlorinated pitches whereas manufactured commercial compounds have more enriched carbon isotope ratios. The findings were restricted to a single case study and one element (i.e. carbon). This paper presents a multi-element Compound-Specific Stable Isotope Analysis (CSIA, including carbon, chlorine and hydrogen) of chlorinated aliphatic contaminants originated from chlorinated pitches at two sites with different hydrogeology and different producers of chloromethanes. The results show strongly depleted carbon signatures at both sites whereas the chlorine and the hydrogen signatures are comparable to those presented in the literature for manufactured commercial compounds. Multi-element CSIA allowed the identification of sources and site-specific processes affecting chloroethene transformation in groundwater as a result of emergency remediation measures. CSIA turned out to be an effective forensic tool to address the liability for the contamination, leading to a conviction for the crimes of unintentional aggravated public water supply poisoning and environmental disaster. Copyright © 2018 Elsevier B.V. All rights reserved.

Legacy of Topography and Land Use on Erosion and Soil Organic Carbon Burial

NASA Astrophysics Data System (ADS)

Nater, E. A.; Dalzell, B. J.; Fissore, C.; Wu, A.; Yoo, K.; Ginakes, P.

2012-12-01

There is a growing body of evidence to suggest that soil erosion in agricultural landscapes can function as a net carbon (C) sink due to burial of carbon-rich topsoil at depositional sites. It has been argued, however, that soil organic carbon (SOC) degradation during erosion may represent an important source of C to the atmosphere and weaken the overall strength of the erosion-induced C sink. In this study we compare SOC in the top 1.5 m of soil in grassland and cropland landscapes and employ 137Cs (from atmospheric testing of thermonuclear bombs) as a proxy for soil movement over the past half-century. Using soil depth and terrain attributes calculated from LiDAR-derived digital elevation models, we are able to account for 82 and 83% of the variability observed in SOC and 137Cs content from grassland sites. For cropland sites, we are able to explain 78 and 50% of SOC and 137Cs variability, respectively. For cropland sites, slope steepness and curvature play a stronger predictive role than in grassland sites. Comparing SOC and 137Cs content between grassland and agricultural sites shows that there is not preferential SOC depletion in eroded soils. This suggests that, for the soils studied here, erosion functions to redistribute SOC around the landscape but does not accelerate SOC decomposition beyond what can be replaced by primary productivity.

Summary of Carbon Storage Incentives and Potential Legislation: East Sub-Basin Project Task 3.1 Business and Financial Case Study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Trabucchi, Chiara

The CarbonSAFE Illinois – East Sub-Basin project is conducting a pre-feasibility assessment for commercial-scale CO2 geological storage complexes. The project aims to identify sites capable of storing more than 50 million tons of industrially-sourced CO2. To support the business development assessment of the economic viability of potential sites in the East Sub-Basin and explore conditions under which a carbon capture and storage (CCS) project therein might be revenue positive, this document provides a summary of carbon storage incentives and legislation of potential relevance to the project.

The impact of including incentives and competition in a workplace smoking cessation program on quit rates.

PubMed

Koffman, D M; Lee, J W; Hopp, J W; Emont, S L

1998-01-01

To determine the effectiveness of a multicomponent smoking cessation program supplemented by incentives and team competition. A quasi-experimental design was employed to compare the effectiveness of three different smoking cessation programs, each assigned to separate worksite. The study was conducted from 1990 to 1991 at three aerospace industry worksites in California. All employees who were current, regular tobacco users were eligible to participate in the program offered at their site. The multicomponent program included a self-help package, telephone counseling, and other elements. The incentive-competition program included the multicomponent program plus cash incentives and team competition for the first 5 months of the program. The traditional program offered a standard smoking cessation program. Self-reported questionnaires and carbon monoxide tests of tobacco use or abstinence were used over a 12-month period. The incentive-competition program had an abstinence rate of 41% at 6 months (n = 68), which was significantly better than the multicomponent program (23%, n = 81) or the traditional program (8%, n = 36). At 12 months, the quit rates for the incentive and multicomponent-programs were statistically indistinguishable (37% vs. 30%), but remained higher than the traditional program (11%). Chi-square tests, t-tests, and logistic regression were used to compare smoking abstinence across the three programs. Offering a multicomponent program with telephone counseling may be just as effective for long-term smoking cessation as such a program plus incentives and competition, and more effective than a traditional program.

Complex terrain influences ecosystem carbon responses to temperature and precipitation

NASA Astrophysics Data System (ADS)

Reyes, W. M.; Epstein, H. E.; Li, X.; McGlynn, B. L.; Riveros-Iregui, D. A.; Emanuel, R. E.

2017-08-01

Terrestrial ecosystem responses to temperature and precipitation have major implications for the global carbon cycle. Case studies demonstrate that complex terrain, which accounts for more than 50% of Earth's land surface, can affect ecological processes associated with land-atmosphere carbon fluxes. However, no studies have addressed the role of complex terrain in mediating ecophysiological responses of land-atmosphere carbon fluxes to climate variables. We synthesized data from AmeriFlux towers and found that for sites in complex terrain, responses of ecosystem CO2 fluxes to temperature and precipitation are organized according to terrain slope and drainage area, variables associated with water and energy availability. Specifically, we found that for tower sites in complex terrain, mean topographic slope and drainage area surrounding the tower explained between 51% and 78% of site-to-site variation in the response of CO2 fluxes to temperature and precipitation depending on the time scale. We found no such organization among sites in flat terrain, even though their flux responses exhibited similar ranges. These results challenge prevailing conceptual framework in terrestrial ecosystem modeling that assumes that CO2 fluxes derive from vertical soil-plant-climate interactions. We conclude that the terrain in which ecosystems are situated can also have important influences on CO2 responses to temperature and precipitation. This work has implications for about 14% of the total land area of the conterminous U.S. This area is considered topographically complex and contributes to approximately 15% of gross ecosystem carbon production in the conterminous U.S.

National Institute for Global Environmental Change. Final Technical Report 1990-2007

DOE Office of Scientific and Technical Information (OSTI.GOV)

Athanasios Toulopoulos

Research conducted by the six NIGEC Regional Centers during recent years is reported. An overview of the NIGEC program from its beginnings provides a description and evaluation of the program's vision, strategy and major accomplishments. The program's purpose was to support academic research on environmental change in regions of the country that had historically received relatively little federal funding. The overall vision of NIGEC may be stated as the performance of academic research on the regional interactions between ecosystems and climate. NIGEC's research presents important evidence on the impacts of climate variability and change, and in some cases adaptability, formore » a broad range of both managed and unmanaged ecosystems, and has thereby documented significant regional issues on the environmental responses to climate change. NIGEC's research has demonstrated large regional differences in the atmospheric carbon exchange budgets of croplands and forests, that there are significant variations of this exchange on diurnal, synoptic, seasonal and interannual time scales due to atmospheric variability (including temperature, precipitation and cloudiness), and that management practices and past history have predominant effects in grasslands and croplands. It is the mid-latitude forests, however, that have received more attention in NIGEC than any other specific ecosystem, and NIGEC's initiation of and participation in the AmeriFlux program, network of carbon flux measurement sites in North American old-growth forests, is generally considered to be its most significant single accomplishment. By including appendices with complete listings of NIGEC publications, principal investigators and participating institutions, this report may also serve as a useful comprehensive documentation of NIGEC.« less

Carbon Fiber Manufacturing Facility Siting and Policy Considerations: International Comparison

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cook, Jeffrey J.; Booth, Samuel

Carbon fiber is increasingly used in a wide variety of applications due largely to its superior material properties such as high strength-to-weight ratio. The current global carbon fiber manufacturing industry is predominately located in China, Europe, Japan, and the United States. The carbon fiber market is expected to expand significantly through 2024 and to require additional manufacturing capacity to meet demand. Carbon fiber manufacturing facilities can offer significant economic development and employment opportunities as exemplified by the $1 billion investment and 500 jobs expected at a new Toray plant in Moore, South Carolina. Though the market is expected to expand,more » it is unclear where new manufacturing facilities will locate to meet demand. This uncertainty stems from the lack of research evaluating how different nations with significant carbon fiber manufacturing capacity compare as it relates to certain manufacturing facility siting factors such as costs of labor and energy as well as policy directed at supporting carbon fiber development, domestic deployment, and exports. This report fills these gaps by evaluating the top carbon fiber manufacturing countries, including China, European Union countries, Japan, Mexico, South Korea, Taiwan, and the United States. The report documents how the United States compares to these countries based on a range of manufacturing siting considerations and existing policies related to carbon fiber. It concludes with a discussion of various policy options the United States could adopt to both (1) increase the competitiveness of the United States as it relates to attracting new carbon fiber manufacturing and (2) foster broader end-use markets for deployment.« less

Limits on carbon sequestration in arid blue carbon ecosystems.

PubMed

Schile, Lisa M; Kauffman, J Boone; Crooks, Stephen; Fourqurean, James W; Glavan, Jane; Megonigal, J Patrick

2017-04-01

Coastal ecosystems produce and sequester significant amounts of carbon ("blue carbon"), which has been well documented in humid and semi-humid regions of temperate and tropical climates but less so in arid regions where mangroves, marshes, and seagrasses exist near the limit of their tolerance for extreme temperature and salinity. To better understand these unique systems, we measured whole-ecosystem carbon stocks in 58 sites across the United Arab Emirates (UAE) in natural and planted mangroves, salt marshes, seagrass beds, microbial mats, and coastal sabkha (inter- and supratidal unvegetated salt flats). Natural mangroves held significantly more carbon in above- and belowground biomass than other vegetated ecosystems. Planted mangrove carbon stocks increased with age, but there were large differences for sites of similar age. Soil carbon varied widely across sites (2-367 Mg C/ha), with ecosystem averages that ranged from 49 to 156 Mg C/ha. For the first time, microbial mats were documented to contain soil carbon pools comparable to vascular plant-dominated ecosystems, and could arguably be recognized as a unique blue carbon ecosystem. Total ecosystem carbon stocks ranged widely from 2 to 515 Mg C/ha (seagrass bed and mangrove, respectively). Seagrass beds had the lowest carbon stock per unit area, but the largest stock per total area due to their large spatial coverage. Compared to similar ecosystems globally, mangroves and marshes in the UAE have lower plant and soil carbon stocks; however, the difference in soil stocks is far larger than with plant stocks. This incongruent difference between stocks is likely due to poor carbon preservation under conditions of weakly reduced soils (200-350 mV), coarse-grained sediments, and active shoreline migration. This work represents the first attempt to produce a country-wide coastal ecosystem carbon accounting using a uniform sampling protocol, and was motivated by specific policy goals identified by the Abu Dhabi Global Environmental Data Initiative. These carbon stock data supported two objectives: to quantify carbon stocks and infer sequestration capacity in arid blue carbon ecosystems, and to explore the potential to incorporate blue carbon science into national reporting and planning documents. © 2016 by the Ecological Society of America.

Insights from a network of long-term measurements of biosphere-atmospheric exchanges of water vapor and carbon dioxide in a water-limited semiarid region

NASA Astrophysics Data System (ADS)

Scott, Russell; Biederman, Joel

2017-04-01

Around one-third of Earth's land surface is classified as semiarid, and carbon dioxide exchange in these regions has been shown to be an important regulator of both the trend and interannual variability of the terrestrial carbon sink. Fifteen years ago, when we began making measurements of biosphere-atmospheric exchanges of energy, water vapor, and carbon dioxide using eddy covariance in southern Arizona USA, there was paucity of semiarid observations in flux networks like AmeriFlux and EuroFlux. We started by establishing riparian sites across a woody plant encroachment gradient to quantify the productivity and consumptive plant water use along a iconic and ecologically important desert river. Soon thereafter, we added semiarid grassland, shrubland, and savanna sites that do not have access to groundwater in order to better understand how water limitation and changes in vegetation structure affect ecosystem productivity. Here, we highlight the value of multiyear, multisite flux data for addressing regional to global scale problems associated with groundwater pumping, land cover change, drought, and climate change. For the riparian sites, we find that ecosystem water availability is altered by vegetation structure such that ecosystems with more deeply rooted trees have higher productivity but at a cost of greater groundwater use. For the non-riparian sites, precipitation strongly controls ecosystem water availability and the resultant productivity, but differences in ecosystem structure impact water use efficiency due to the partitioning of evapotranspiration into its component sources. Also, the productivity at sites with more grass, and less woody, plants responds more quickly to precipitation fluctuations including long-term drought conditions. In semiarid regions, variability in water and carbon fluxes is much larger than in more mesic climes. Across our riparian and non-riparian sites, access to more stable groundwater reserves reduces variability in water and carbon fluxes and can decouple ecosystem productivity from precipitation. Finally, we show that the 8% increase in carbon dioxide concentrations over the period of our measurements may be altering ecosystem water use efficiency, a result that is expected and has been reported for northeastern US forests.

Insights from a network of long-term measurements of biosphere-atmospheric exchanges of water vapor and carbon dioxide in southern Arizona

NASA Astrophysics Data System (ADS)

Scott, R. L.; Barron-Gafford, G.; Biederman, J. A.

2016-12-01

Around one-third of Earth's land surface is classified as semiarid, and carbon dioxide exchange in these regions has been shown to be an important regulator of both the trend and interannual variability of the terrestrial carbon sink. Fifteen years ago, when we began making measurements of biosphere-atmospheric exchanges of energy, water vapor, and carbon dioxide using eddy covariance in southern Arizona USA, there was paucity of semiarid observations in flux networks like Ameriflux. We started by establishing riparian sites across a woody plant encroachment gradient to quantify the productivity and consumptive plant water use along a iconic and ecologically important desert river. Soon thereafter, we added semiarid grassland, shrubland, and savanna sites that do not have access to groundwater in order to better understand how water limitation and changes in vegetation structure affect ecosystem productivity. Here, we highlight the value of multiyear, multisite flux data for addressing regional to global scale problems associated with groundwater pumping, land cover change, drought, and climate change. For the riparian sites, we find that ecosystem water availability is altered by vegetation structure such that ecosystems with more deeply rooted trees have higher productivity but at a cost of greater groundwater use. For the non-riparian sites, precipitation strongly controls ecosystem water availability and the resultant productivity, but differences in ecosystem structure impact water use efficiency due to the partitioning of evapotranspiration into its component sources. Also, the productivity at sites with more grass, and less woody, plants responds more quickly to precipitation fluctuations including long-term drought conditions. In semiarid regions, variability in water and carbon fluxes is much larger than in more mesic climes. Across our riparian and non-riparian sites, access to more stable groundwater reserves reduces variability in water and carbon fluxes and can decouple ecosystem productivity from precipitation. Finally, we show that the 8% increase in carbon dioxide concentrations over the period of our measurements has not resulted in any apparent changes in ecosystem water use efficiency that is expected and has been reported for northeastern US forests.

Tropospheric ozone reduces carbon assimilation in trees: estimates from analysis of continuous flux measurements.

PubMed

Fares, Silvano; Vargas, Rodrigo; Detto, Matteo; Goldstein, Allen H; Karlik, John; Paoletti, Elena; Vitale, Marcello

2013-08-01

High ground-level ozone concentrations are typical of Mediterranean climates. Plant exposure to this oxidant is known to reduce carbon assimilation. Ozone damage has been traditionally measured through manipulative experiments that do not consider long-term exposure and propagate large uncertainty by up-scaling leaf-level observations to ecosystem-level interpretations. We analyzed long-term continuous measurements (>9 site-years at 30 min resolution) of environmental and eco-physiological parameters at three Mediterranean ecosystems: (i) forest site dominated by Pinus ponderosa in the Sierra Mountains in California, USA; (ii) forest site composed of a mixture of Quercus spp. and P. pinea in the Tyrrhenian sea coast near Rome, Italy; and (iii) orchard site of Citrus sinensis cultivated in the California Central Valley, USA. We hypothesized that higher levels of ozone concentration in the atmosphere result in a decrease in carbon assimilation by trees under field conditions. This hypothesis was tested using time series analysis such as wavelet coherence and spectral Granger causality, and complemented with multivariate linear and nonlinear statistical analyses. We found that reduction in carbon assimilation was more related to stomatal ozone deposition than to ozone concentration. The negative effects of ozone occurred within a day of exposure/uptake. Decoupling between carbon assimilation and stomatal aperture increased with the amount of ozone pollution. Up to 12-19% of the carbon assimilation reduction in P. ponderosa and in the Citrus plantation was explained by higher stomatal ozone deposition. In contrast, the Italian site did not show reductions in gross primary productivity either by ozone concentration or stomatal ozone deposition, mainly due to the lower ozone concentrations in the periurban site over the shorter period of investigation. These results highlight the importance of plant adaptation/sensitivity under field conditions, and the importance of continuous long-term measurements to explain ozone damage to real-world forests and calculate metrics for ozone-risk assessment. © 2013 John Wiley & Sons Ltd.

Integrating remotely sensed fires for predicting deforestation for REDD.

PubMed

Armenteras, Dolors; Gibbes, Cerian; Anaya, Jesús A; Dávalos, Liliana M

2017-06-01

Fire is an important tool in tropical forest management, as it alters forest composition, structure, and the carbon budget. The United Nations program on Reducing Emissions from Deforestation and Forest Degradation (REDD+) aims to sustainably manage forests, as well as to conserve and enhance their carbon stocks. Despite the crucial role of fire management, decision-making on REDD+ interventions fails to systematically include fires. Here, we address this critical knowledge gap in two ways. First, we review REDD+ projects and programs to assess the inclusion of fires in monitoring, reporting, and verification (MRV) systems. Second, we model the relationship between fire and forest for a pilot site in Colombia using near-real-time (NRT) fire monitoring data derived from the Moderate Resolution Imaging Spectroradiometer (MODIS). The literature review revealed fire remains to be incorporated as a key component of MRV systems. Spatially explicit modeling of land use change showed the probability of deforestation declined sharply with increasing distance to the nearest fire the preceding year (multi-year model area under the curve [AUC] 0.82). Deforestation predictions based on the model performed better than the official REDD early-warning system. The model AUC for 2013 and 2014 was 0.81, compared to 0.52 for the early-warning system in 2013 and 0.68 in 2014. This demonstrates NRT fire monitoring is a powerful tool to predict sites of forest deforestation. Applying new, publicly available, and open-access NRT fire data should be an essential element of early-warning systems to detect and prevent deforestation. Our results provide tools for improving both the current MRV systems, and the deforestation early-warning system in Colombia. © 2017 by the Ecological Society of America.

Characterization of the wintertime particulate (PM1) pollution at an urban background site of Nicosia, Cyprus

NASA Astrophysics Data System (ADS)

Pikridas, Michael; Sciare, Jean; Vrekoussis, Mihalis; Oikonomou, Konstantina; Merabet, Hamza; Mihalopoulos, Nikos; Yassaa, Nouredine; Savvides, Chrysanthos

2016-04-01

As part of MISTRALS-ChArMEx (Chemistry-Aerosol Mediterranean Experiment, http://charmex.lsce.ipsl.fr/), and MISTRALS-ENVI-Med "CyAr" (Cyprus Aerosols and gas precursors) programs, a 1-month intensive field campaign has been performed in December 2014 at an urban background site of Nicosia (Cyprus) - a typical European city of the Eastern Mediterranean - with the objective to document the major (local versus imported) sources responsible for wintertime particulate (PM1) pollution. Several near real-time analyzers were deployed for that purpose (TEOM 1400, OPC Grimm 1.108, Q-ACSM, Aethalometer AE31) allowing to investigate in near-real time the major chemical components of submicron aerosols (Black Carbon, Organics, Sulphate, Nitrate, Ammonium). Quality control of Q-ACSM and Aethalometer datasets was performed through closure studies (using co-located TEOM / OPC Grimm). Comparisons were also performed with other on-line / off-line measurements performed by the local Air quality network (DLI) at other locations in Nicosia with the objective to check the consistency and representativeness of our observations. Very high levels of Black Carbon and OA were systematically observed every night (with maximum concentrations around 22:00 local time) pointing to local combustion sources most probably related to domestic heating. Source apportionment of organic aerosols (OA) was performed using the SourceFinder software (SoFi, http://www.psi.ch/acsm-stations/me-2) allowing the distinction between various primary/secondary OA sources and helped us to better characterize the combustion sources being responsible for the observed elevated nighttime PM1 levels. Acknowledgements: This campaign has been funded by MISTRALS (ChArMEx et ENVI-Med CyAr programs), CNRS-INSU, CEA, CyI, DLI, CDER and ECPL.

Structuring economic incentives to reduce emissions from deforestation within Indonesia

PubMed Central

Busch, Jonah; Lubowski, Ruben N.; Godoy, Fabiano; Steininger, Marc; Yusuf, Arief A.; Austin, Kemen; Hewson, Jenny; Juhn, Daniel; Farid, Muhammad; Boltz, Frederick

2012-01-01

We estimate and map the impacts that alternative national and subnational economic incentive structures for reducing emissions from deforestation (REDD+) in Indonesia would have had on greenhouse gas emissions and national and local revenue if they had been in place from 2000 to 2005. The impact of carbon payments on deforestation is calibrated econometrically from the pattern of observed deforestation and spatial variation in the benefits and costs of converting land to agriculture over that time period. We estimate that at an international carbon price of $10/tCO2e, a “mandatory incentive structure,” such as a cap-and-trade or symmetric tax-and-subsidy program, would have reduced emissions by 163–247 MtCO2e/y (20–31% below the without-REDD+ reference scenario), while generating a programmatic budget surplus. In contrast, a “basic voluntary incentive structure” modeled after a standard payment-for-environmental-services program would have reduced emissions nationally by only 45–76 MtCO2e/y (6–9%), while generating a programmatic budget shortfall. By making four policy improvements—paying for net emission reductions at the scale of an entire district rather than site-by-site; paying for reductions relative to reference levels that match business-as-usual levels; sharing a portion of district-level revenues with the national government; and sharing a portion of the national government's responsibility for costs with districts—an “improved voluntary incentive structure” would have been nearly as effective as a mandatory incentive structure, reducing emissions by 136–207 MtCO2e/y (17–26%) and generating a programmatic budget surplus. PMID:22232665

Cenozoic variations in the South Atlantic carbonate saturation profile: Insights from the Walvis depth-transect (ODP Leg 208)

NASA Astrophysics Data System (ADS)

Schellenberg, S. A.; Nielsen, J. L.

2004-12-01

Ocean Drilling Program Leg 208 Science Party (D. Kroon, J. C. Zachos, P. Blum, J. Bowles, P. Gaillot, T. Hasegawa, E. C. Hawthorne, D. A. Hodell, D. C. Kelly, J. Jung, S. M. Keller, Y. Lee, D. C. Leuschner, Z. Liu, K. C. Lohmann, L. Lourens, S. Monechi, M. Nicolo, I. Raffi, C. Riesselman, U. Röhl, D. Schmidt, A. Sluijs, D. Thomas, E. Thomas, H. Vallius) Carbonate saturation profiles are complex and dynamic products of processes operating on temporospatial scales from the "short-term local" (e.g. carbonate export production) to the "long-term global" (e.g. carbonate-silicate weathering, shelf:basin carbonate partitioning). Established, if admittedly crude, proxies for reconstructing carbonate saturation from sediments include wt% carbonate, where values of 0-20% are typically attributed to deposition below the carbonate compensation depth (CCD), and planktonic foraminifer fragmentation, where enhanced fragmentation is typically attributed to deposition below the lysocline. Ocean Drilling Program Leg 208 successfully drilled a six-site Walvis Ridge depth-transect spanning modern water depths from 2,717 to 4,755 m. Exceptional core recovery, well-constrained biomagnetostratigraphy, and standard crustal subsidence corrections provide a working age-depth framework for contouring ship-board wt% carbonate determinations and identifying the following first-order features of the regional CCD: (1) >3.5 km position from 60-48 Ma punctuated by a major transient shoaling to <2 km during the Paleocene-Eocene Thermal Maximum at ˜55 Ma; (2) shoaling to ˜2.75 km from 48 to 44 Ma; (3) subsequent deepening to >4.25 km from 37 to 28 Ma; (4) marked high amplitude fluctuations from 28 to 20 Ma followed by deepening to >4.75 km; (5) transient shoaling to ˜4 km around 15 Ma followed by deepening to >4.75 km by ˜12 Ma. These first-order features are broadly congruent with classic Atlantic CCD reconstructions by van Andel (1975) and Berger and Roth (1975). A wealth of higher frequency variation in carbonate saturation is clearly preserved within the Leg 208 depth-transect. Ongoing shore-based analyses aim to transform cm-scale variations in core physical properties (i.e. magnetic susceptibility, color reflectance) into synthetic records of wt% carbonate. These data, combined with other proxies (e.g., planktonic foraminifer fragmentation, stable isotopes) and placed within the evolving post-cruise biomagnetostratigraphic and cyclostratigraphic age-model, will provide valuable constraints on cyclic and secular fluctuations in the South Atlantic carbonate saturation profile and their relation to other major components of the earth system (e.g. pCO2, eustacy).

Interannual variation of carbon fluxes from three contrasting evergreen forests: the role of forest dynamics and climate.

PubMed

Sierra, Carlos A; Loescher, Henry W; Harmon, Mark E; Richardson, Andrew D; Hollinger, David Y; Perakis, Steven S

2009-10-01

Interannual variation of carbon fluxes can be attributed to a number of biotic and abiotic controls that operate at different spatial and temporal scales. Type and frequency of disturbance, forest dynamics, and climate regimes are important sources of variability. Assessing the variability of carbon fluxes from these specific sources can enhance the interpretation of past and current observations. Being able to separate the variability caused by forest dynamics from that induced by climate will also give us the ability to determine if the current observed carbon fluxes are within an expected range or whether the ecosystem is undergoing unexpected change. Sources of interannual variation in ecosystem carbon fluxes from three evergreen ecosystems, a tropical, a temperate coniferous, and a boreal forest, were explored using the simulation model STANDCARB. We identified key processes that introduced variation in annual fluxes, but their relative importance differed among the ecosystems studied. In the tropical site, intrinsic forest dynamics contributed approximately 30% of the total variation in annual carbon fluxes. In the temperate and boreal sites, where many forest processes occur over longer temporal scales than those at the tropical site, climate controlled more of the variation among annual fluxes. These results suggest that climate-related variability affects the rates of carbon exchange differently among sites. Simulations in which temperature, precipitation, and radiation varied from year to year (based on historical records of climate variation) had less net carbon stores than simulations in which these variables were held constant (based on historical records of monthly average climate), a result caused by the functional relationship between temperature and respiration. This suggests that, under a more variable temperature regime, large respiratory pulses may become more frequent and high enough to cause a reduction in ecosystem carbon stores. Our results also show that the variation of annual carbon fluxes poses an important challenge in our ability to determine whether an ecosystem is a source, a sink, or is neutral in regard to CO2 at longer timescales. In simulations where climate change negatively affected ecosystem carbon stores, there was a 20% chance of committing Type II error, even with 20 years of sequential data.

Assessing NIR & MIR Spectral Analysis as a Method for Soil C Estimation Across a Network of Sampling Sites

NASA Astrophysics Data System (ADS)

Spencer, S.; Ogle, S.; Borch, T.; Rock, B.

2008-12-01

Monitoring soil C stocks is critical to assess the impact of future climate and land use change on carbon sinks and sources in agricultural lands. A benchmark network for soil carbon monitoring of stock changes is being designed for US agricultural lands with 3000-5000 sites anticipated and re-sampling on a 5- to10-year basis. Approximately 1000 sites would be sampled per year producing around 15,000 soil samples to be processed for total, organic, and inorganic carbon, as well as bulk density and nitrogen. Laboratory processing of soil samples is cost and time intensive, therefore we are testing the efficacy of using near-infrared (NIR) and mid-infrared (MIR) spectral methods for estimating soil carbon. As part of an initial implementation of national soil carbon monitoring, we collected over 1800 soil samples from 45 cropland sites in the mid-continental region of the U.S. Samples were processed using standard laboratory methods to determine the variables above. Carbon and nitrogen were determined by dry combustion and inorganic carbon was estimated with an acid-pressure test. 600 samples are being scanned using a bench- top NIR reflectance spectrometer (30 g of 2 mm oven-dried soil and 30 g of 8 mm air-dried soil) and 500 samples using a MIR Fourier-Transform Infrared Spectrometer (FTIR) with a DRIFT reflectance accessory (0.2 g oven-dried ground soil). Lab-measured carbon will be compared to spectrally-estimated carbon contents using Partial Least Squares (PLS) multivariate statistical approach. PLS attempts to develop a soil C predictive model that can then be used to estimate C in soil samples not lab-processed. The spectral analysis of soil samples either whole or partially processed can potentially save both funding resources and time to process samples. This is particularly relevant for the implementation of a national monitoring network for soil carbon. This poster will discuss our methods, initial results and potential for using NIR and MIR spectral approaches to either replace or augment traditional lab-based carbon analyses of soils.

Soil Biogeochemistry in the Ent DGVM

NASA Astrophysics Data System (ADS)

Kharecha, P. A.; Kiang, N. Y.; Aleinov, I.; Moorcroft, P.; Koster, R.

2007-12-01

As the global climate continues to warm in the 21st century, it will be vital to assess the degree of carbon cycle feedbacks from the terrestrial biosphere, particularly the soil. Global soil carbon stocks, which amount to approximately double the carbon stored in vegetation, could provide either positive or negative climate feedbacks, depending on a given ecosystem's response to warming. To predict changes in net terrestrial CO2 fluxes and belowground organic carbon storage, we have developed and evaluated a soil biogeochemistry submodel for the Ent dynamic global vegetation model currently being tested within the GISS GCM. It is a modified version of the soil submodel in the CASA biosphere model (Potter et al., Glob. Biogeoch. Cyc. 7, 1993). We have enhanced it to allow for explicit depth structure (2 soil layers, 0-30 cm and 30-100 cm), first-order inter-layer (vertical) soil organic carbon transport, and a variable-Q10 temperature dependence for soil microbial respiration. We have tested the soil model in numerous offline runs. To spin up the simulated carbon pools offline, we conducted multi-century runs using meteorological and ecological data from various FLUXNET field sites that represent 7 of the 8 GISS GCM plant functional types: tundra, grassland, shrubland, savanna, deciduous forest, evergreen needleleaf forest, and tropical rainforest (the eighth, cropland, will be dealt with in a separate study). We then compare the magnitudes of the simulated spun-up soil pools to soil carbon stock data from these field sites as well as the biome-aggregated data from Post et al. (Nature 317, 1985). Net ecosystem CO2 fluxes and soil respiration are also compared to site-specific measurements where available. Preliminary results suggest that simulated fluxes are reasonably close to measured values, but simulated carbon storage tends to be lower than the measurements. In addition to site-specific comparisons, we discuss the broader implications of our results, e.g., the effects of including explicit depth structure and inter-layer soil carbon transport on simulated soil respiration, carbon storage, and estimation of the global carbon budget.

Decrypting the Formation Conditions of the Basement Carbonate-Bearing Rocks at Nili Fossae

NASA Astrophysics Data System (ADS)

Brown, A. J.

2015-12-01

The Nili Fossae region is the site of a number of proposed Landing Sites for the Mars 2020 Rover. A distinguishing feature of many of these sites is the access to large exposures of carbonate (Ehlmann et al. 2008). Serpentinization has been proposed as a formation mechanism of these carbonates, including carbonated (Brown et al. 2010, Viviano, et al. 2013) and low temperature, near surface serpentinization. The potential for carbonated serpentization at Nili Fossae links the region to Earth analogs in terrestrial greenstone belts such as the Pilbara in Western Australia, where talc-carbonate bearing komatiite cumulate units of the Dresser Formation overlie the siliceous, stromatolite-bearing Strelley Pool Chert unit (Van Kranendonk and Pirajno, 2004). If a similar relationship exists on Mars, investigations of rocks stratigraphically beneath the carbonate-bearing units at Nili Fossae ("the basement rocks") may provide the best chance to examine well preserved organic material from the Noachian. This hypothesis is testable by Mars 2020. In preparation for the the Mars 2020 landing site, we are examining the thermodynamic relationships that favor formation of serpentine and talc-carbonate and different pressures and temperatures in the crust (Barnes 2007). This will allow us to constrain the low grade metamorphism required to replicate the proposed models of serpentinisation and help us understand the regional metamophic gradient that is critical to furthering our knowledge of the ancient rocks of Nili Fossae. Refs:Barnes, S. J. "Komatiites: Petrology, Volcanology, Metamorphism, and Geochemistry." S.E.G. 13 (2007): 13. Brown, A. J., et al.. "Hydrothermal Formation of Clay-Carbonate Alteration Assemblages in the Nili Fossae Region of Mars." EPSL 297 (2010): 174-82. Ehlmann, B. L. et al. "Orbital Identification of Carbonate-Bearing Rocks on Mars." Science 322, no. 5909 1828-32. Van Kranendonk, M.J., and F. Pirajno. "Geochemistry of Metabasalts and Hydrothermal Alteration Zones Associated with Ca. 3.45 Ga Chert+/- Barite Deposits" GEEA 4, no. 3 (2004): 253-78. Viviano, C. E., et al. "Implications for Early Hydrothermal Environments on Mars through the Spectral Evidence for Carbonation and Chloritization Reactions in the Nili Fossae Region." JGR 118, no. 9 (2013): 1858-72.

AmeriFlux US-Bo2 Bondville (companion site)

DOE Data Explorer

Bernacchi, Carl [University of Illinois, Urbana-Champaign

2016-01-01

This is the AmeriFlux version of the carbon flux data for the site US-Bo2 Bondville (companion site). Site Description - Located 400m north of Tilden Meyer's site and planted with opposite crop in corn/soybean rotation

Natural-abundance stable carbon isotopes of small-subunit ribosomal RNA (SSU rRNA) from Guaymas Basin (Mexico)

NASA Astrophysics Data System (ADS)

MacGregor, B. J.; Mendlovitz, H.; Albert, D.; Teske, A. P.

2012-12-01

Small-subunit ribosomal RNA (SSU rRNA) is a phylogenetically informative molecule found in all species. Because it is poorly preserved in most environments, it is a useful marker for active microbial populations. We are using the natural-abundance stable carbon isotopic composition of specific microbial groups to help identify the carbon substrates contributing to microbial biomass in a variety of marine environments. At Guaymas Basin, hydrothermal fluids interact with abundant sedimentary organic carbon to produce natural gas and petroleum. Where this reaches the sediment surface, it can support dense patches of seafloor life, including Beggiatoa mats. We report here on the stable carbon isotopic composition of SSU rRNA from a Beggiatoa mat transect, a cold background site, a warm site with high oil concentration, and a second Beggiatoa mat. The central part of the transect mat overlay the steepest temperature gradient, and was visually dominated by orange Beggiatoa. This was fringed by white Beggiatoa mat and bare, but still warm, sediment. Methane concentrations were saturating beneath the orange and white mats and at the oily site, lower beneath bare sediment, and below detection at the background site. Our initial hypotheses were that rRNA isotopic composition would be strongly influenced by methane supply, and that archaeal rRNA might be lighter than bacterial due to contributions from methanogens and anaerobic methane oxidizers. We used biotin-labeled oligonucleotides to capture Bacterial and Archaeal SSU rRNA for isotopic determination. Background-site rRNA was isotopically heaviest, and bacterial RNA from below 2 cm at the oily site was lightest, consistent with control by methane. Within the transect mat, however, the pattern was more complicated; at some sediment depths, rRNA from the mat periphery was isotopically lightest. Part of this may be due to the spatially and temporally variable paths followed by hydrothermal fluid, which can include horizontal flow. There was no consistent isotopic difference between rRNAs captured by the two probes, although RNA recoveries were too low for isotopic determinations at depths where methanogens and methane oxidizers are expected. Our prediction that rRNA stable carbon isotopic composition would correlate with methane supply was borne out by the comparison between background and mat sediments, but may be an oversimplification for sites within hydrothermal features. Future work will include the isotopic characterization of other potential carbon substrates, such as acetate. We are also investigating cold-seep sediments and brine pools in the Gulf of Mexico, where methane is significantly more 13C-depleted than at Guaymas Basin and may therefore leave a stronger imprint on microbial biomass.table carbon isotopes of rRNA captured with Bacterial and Archaeal probes at mat transect and background sites.

Carbon Dioxide and Methane Flux Related to Forest Type and Managed and Unmanaged Conditions in the Great Dismal Swamp, USA

NASA Astrophysics Data System (ADS)

Gutenberg, L. W.; Krauss, K.; Qu, J. J.; Hogan, D. M.; Zhu, Z.; Xu, C.

2017-12-01

The Great Dismal Swamp in Virginia and North Carolina, USA, has been greatly impacted by human use and management for the last few hundred years through logging, ditching, and draining. Today, the once dominant cedar, cypress and pocosin forest types are fragmented due to logging and environmental change. Maple-gum forest has taken over more than half the remaining area of the swamp ecosystem, which is now a National Wildlife Refuge and State Park. The peat soils and biomass store a vast quantity of carbon compared with the size of the refuge, but this store is threatened by fire and drying. This study looks at three of the main forest types in the GDS— maple-sweet gum, tall pine pocosin, and Atlantic white cedar— in terms of their carbon dioxide and methane soil flux. Using static chambers to sample soil gas flux in locally representative sites, we found that cedar sites showed a higher carbon dioxide flux rate as the soil temperature increased than maple sites, and the rate of carbon dioxide flux decreased as soil moisture increased faster in cedar sites than in maple sites. Methane flux increased as temperature increased for pocosin, but decreased with temperature for cedar and maple. All of the methane fluxes increased as soil moisture increased. Cedar average carbon dioxide flux was statistically significantly different from both maple and pocosin. These results show that soil carbon gas flux depends on soil moisture and temperature, which are factors that are changing due to human actions, as well as on forest type, which is also the result of human activity. Some of these variables may be adjustable by the managers of the land. Variables other than forest type, temperature and soil moisture/inundation may also play a role in influencing soil flux, such as stand age, tree height, composition of the peat and nutrient availability, and source of moisture as some sites are more influenced by groundwater from ditches and some more by rainfall depending on the direction of groundwater lateral flow. Increasing temperatures and changes in precipitation and soil moisture may impact the carbon storage and health of this ecosystem, although it is already strongly influenced by anthropogenic activities such as past logging and water level management.

Determining contributions of biomass burning and other sources to fine particle contemporary carbon in the western United States

NASA Astrophysics Data System (ADS)

Holden, Amanda S.; Sullivan, Amy P.; Munchak, Leigh A.; Kreidenweis, Sonia M.; Schichtel, Bret A.; Malm, William C.; Collett, Jeffrey L., Jr.

2011-02-01

Six-day integrated fine particle samples were collected at urban and rural sampling sites using Hi-Volume samplers during winter and summer 2004-2005 as part of the IMPROVE (Interagency Monitoring of PROtected Visual Environments) Radiocarbon Study. Filter samples from six sites (Grand Canyon, Mount Rainier, Phoenix, Puget Sound, Rocky Mountain National Park, and Tonto National Monument) were analyzed for levoglucosan, a tracer for biomass combustion, and other species by High-Performance Anion-Exchange Chromatography with Pulsed Amperometric Detection (HPAEC-PAD). Contemporary carbon concentrations were available from previous carbon isotope measurements at Lawrence Livermore National Laboratory. Primary contributions of biomass burning to measured fine particle contemporary carbon were estimated for residential wood burning (winter) and wild/prescribed fires (summer). Calculated contributions ranged from below detection limit to more than 100% and were typically higher at rural sites and during winter. Mannitol, a sugar alcohol emitted by fungal spores, was analyzed and used to determine contributions of fungal spores to fine particle contemporary carbon. Contributions reached up to 13% in summer samples, with higher contributions at rural sites. Concentrations of methyltetrols, oxidation products of isoprene, were also measured by HPAEC-PAD. Secondary organic aerosol (SOA) from isoprene oxidation was estimated to contribute up to 22% of measured contemporary carbon. For each sampling site, a substantial portion of the contemporary carbon was unexplained by primary biomass combustion, fungal spores, or SOA from isoprene oxidation. This unexplained fraction likely contains contributions from other SOA sources, including oxidation products of primary smoke emissions and plant emissions other than isoprene, as well as other primary particle emissions from meat cooking, plant debris, other biological aerosol particles, bio-diesel combustion, and other sources. Loss of levoglucosan during atmospheric aging of biomass burning emissions likely also results in an underestimate of apportioned primary smoke contributions.

Global Sea Surface Temperature and Ecosystem Change Across the Mid-Miocene Climatic Optimum

NASA Astrophysics Data System (ADS)

Veenstra, T. J. T.; Bakker, V. B.; Sangiorgi, F.; Peterse, F.; Schouten, S.; Sluijs, A.

2016-12-01

Even though the term Mid-Miocene Climatic Optimum (MMCO; ca. 17 to 14 Ma) has been widely used in the literature since the early 1990's, almost no early-middle Miocene sea surface temperature (SST) proxy records have been published that support climate warming across its onset. Benthic (and diagenetically altered planktic) foram δ18O records show a decrease, suggesting (deep) ocean warming and/or Antarctic ice sheet melting. However, reliable absolute SST proxy records are absent from the tropics and very scarce in temperate and polar regions. This leaves the question if the warmth of the MMCO was truly global and how its onset relates to the widely recorded positive (Monterey) carbon isotope excursion and volcanism. Finally, it remains uncertain how marine ecosystems responded to this hypothesized warming. We present organic biomarker SST proxy records (Uk'37 and TEX86) spanning the MMCO for several locations in the Atlantic and Pacific Ocean along a pole-to-pole transect, including Ocean Drilling Program Site 959 in the eastern Tropical Atlantic, ODP Site 643 in the Norwegian Sea, ODP Site 1007 on the Great Bahama Bank and Integrated Ocean Drilling Program Site U1352 off New Zealand. Additionally, we use marine palynology (mostly dinoflagellate cysts) to assess ecosystem change at these locations. The resulting spatial reconstruction of SST change shows that Middle Miocene warming was global. Nevertheless, the records also show distinct regional variability, including relatively large warming in the Norwegian Sea and a damped signal in the southern hemisphere, suggesting pronounced changes in ocean circulation. The onset of the MMCO was marked by prominent changes in ecological and depositional setting at the studied sites, likely also related to ocean circulation changes.

One ligand, two regulators and three binding sites: How KDPG controls primary carbon metabolism in Pseudomonas

PubMed Central

Fung, Rowena K. Y.; Grenga, Lucia; Trampari, Eleftheria; Pepe, Simona

2017-01-01

Effective regulation of primary carbon metabolism is critically important for bacteria to successfully adapt to different environments. We have identified an uncharacterised transcriptional regulator; RccR, that controls this process in response to carbon source availability. Disruption of rccR in the plant-associated microbe Pseudomonas fluorescens inhibits growth in defined media, and compromises its ability to colonise the wheat rhizosphere. Structurally, RccR is almost identical to the Entner-Doudoroff (ED) pathway regulator HexR, and both proteins are controlled by the same ED-intermediate; 2-keto-3-deoxy-6-phosphogluconate (KDPG). Despite these similarities, HexR and RccR control entirely different aspects of primary metabolism, with RccR regulating pyruvate metabolism (aceEF), the glyoxylate shunt (aceA, glcB, pntAA) and gluconeogenesis (pckA, gap). RccR displays complex and unusual regulatory behaviour; switching repression between the pyruvate metabolism and glyoxylate shunt/gluconeogenesis loci depending on the available carbon source. This regulatory complexity is enabled by two distinct pseudo-palindromic binding sites, differing only in the length of their linker regions, with KDPG binding increasing affinity for the 28 bp aceA binding site but decreasing affinity for the 15 bp aceE site. Thus, RccR is able to simultaneously suppress and activate gene expression in response to carbon source availability. Together, the RccR and HexR regulators enable the rapid coordination of multiple aspects of primary carbon metabolism, in response to levels of a single key intermediate. PMID:28658302

Impact of fire disturbance on soil thermal and carbon dynamics in Alaskan Tundra and Boreal forest ecosystems

NASA Astrophysics Data System (ADS)

Jiang, Y.; Rastetter, E.; Shaver, G. R.; Rocha, A. V.

2012-12-01

In Alaska, fire disturbance is a major component influencing the soil water and energy balance in both tundra and boreal forest ecosystems. Fire-caused changes in soil environment further affect both above- and below-ground carbon cycles depending on different fire severities. Understanding the effects of fire disturbance on soil thermal change requires implicit modeling work on the post-fire soil thawing and freezing processes. In this study, we model the soil temperature profiles in multiple burned and non-burned sites using a well-developed soil thermal model which fully couples soil water and heat transport. The subsequent change in carbon dynamics is analyzed based on site level observations and simulations from the Multiple Element Limitation (MEL) model. With comparison between burned and non-burned sites, we compare and contrast fire effects on soil thermal and carbon dynamics in continuous permafrost (Anaktuvik fire in north slope), discontinuous permafrost (Erickson Creek fire at Hess Creek) and non-permafrost zone (Delta Junction fire in interior Alaska). Then we check the post-fire recovery of soil temperature profiles at sites with different fire severities in both tundra and boreal forest fire areas. We further project the future changes in soil thermal and carbon dynamics using projected climate data from Scenarios Network for Alaska & Arctic Planning (SNAP). This study provides information to improve the understanding of fire disturbance on soil thermal and carbon dynamics and the consequent response under a warming climate.

No evidence for depletion of carbohydrate pools in Scots pine (Pinus sylvestris L.) under drought stress.

PubMed

Gruber, A; Pirkebner, D; Florian, C; Oberhuber, W

2012-01-01

The physiological mechanisms leading to Scots pine (Pinus sylvestris L.) decline in the dry inner alpine valleys are still unknown. Testing the carbon starvation hypothesis, we analysed the seasonal course of mobile carbohydrate pools (NSC) of Scots pine growing at a xeric and a dry-mesic site within an inner alpine dry valley (750 m a.s.l., Tyrol, Austria) during 2009, which was characterised by exceptional soil dryness. Although, soil moisture content dropped to ca. 10% at both sites during the growing season, NSC concentrations rose in all tissues (branch, stem, root) until the end of July, except in needles, where maxima were reached around bud break. NSC concentrations were not significantly different in the analysed tissues at the xeric and the dry-mesic site. At the dry-mesic site, NSC concentrations in the aboveground tree biomass were significantly higher during the period of radial growth. An accumulation of NSC in roots at the end of July indicates a change in carbon allocation after an early cessation in aboveground growth, possibly due to elevated belowground carbon demand. In conclusion, our results revealed that extensive soil dryness during the growing season did not lead to carbon depletion. However, even though carbon reserves were not exhausted, sequestration of carbohydrate pools during drought periods might lead to deficits in carbon supply that weaken tree vigour and drive tree mortality. © 2011 German Botanical Society and The Royal Botanical Society of the Netherlands.

Upscaling Our Approach to Peatland Carbon Sequestration: Remote Sensing as a Tool for Carbon Flux Estimation.

NASA Astrophysics Data System (ADS)

Lees, K.; Khomik, M.; Clark, J. M.; Quaife, T. L.; Artz, R.

2017-12-01

Peatlands are an important part of the Earth's carbon cycle, comprising approximately a third of the global terrestrial carbon store. However, peatlands are sensitive to climatic change and human mismanagement, and many are now degraded and acting as carbon sources. Restoration work is being undertaken at many sites around the world, but monitoring the success of these schemes can be difficult and costly using traditional methods. A landscape-scale alternative is to use satellite data in order to assess the condition of peatlands and estimate carbon fluxes. This work focuses on study sites in Northern Scotland, where parts of the largest blanket bog in Europe are being restored from forest plantations. A combination of laboratory and fieldwork has been used to assess the Net Ecosystem Exchange (NEE), Gross Primary Productivity (GPP) and respiration of peatland sites in different conditions, and the climatic vulnerability of key peat-forming Sphagnum species. The results from these studies have been compared with spectral data in order to evaluate the extent to which remote sensing can function as a source of information for peatland health and carbon flux models. This work considers particularly the effects of scale in calculating peatland carbon flux. Flux data includes chamber and eddy covariance measurements of carbon dioxide, and radiometric observations include both handheld spectroradiometer results and satellite images. Results suggest that despite the small-scale heterogeneity and unique ecosystem factors in blanket bogs, remote sensing can be a useful tool in monitoring peatland health and carbon sequestration. In particular, this study gives unique insights into the relationships between peatland vegetation, carbon flux and spectral reflectance.

The interactions between tree-herb layer diversity and soil properties in the oriental beech (Fagus orientalis Lipsky) stands in Hyrcanian forest.

PubMed

Bakhshandeh-Navroud, Behzad; Abrari Vajari, Kambiz; Pilehvar, Babak; Kooch, Yahya

2018-06-26

This study investigated the interactions between tree-herb layer diversity and some physico-chemical and eco-physiological characteristics of soil in natural oriental beech stand in western Guilan, Iran. The data were collected from nine research sites (50 m × 50 m) which were described as a gradient from pure oriental beech (Fagus orientalis Lipsky) stands to mixed stands with up to nine deciduous tree species (n = 27) in Hyrcanian forest. Herbaceous plants were sampled within ten 1 m × 1 m sub-plots in two plots of 400 m 2 which were installed randomly in each research site. Composite soil samples were taken at five positions in each research site. We found that the increase in tree diversity in mature oriental beech stands brought about an increase in microbial biomass carbon, soil carbon content, and the ratio of microbial biomass carbon to the organic carbon (C mic /C org ). Increased soil organic carbon raised microbial biomass carbon through creating suitable environment for microorganisms. The findings also indicated that the ratio of microbial biomass carbon to the organic carbon (C mic /C org ) increased as a quantitative indicator of soil carbon dynamics that finally benefits soil fertility of mixed oriental beech stands compared to pure oriental beech stands. The results showed that humus layer and litter thickness were negatively correlated with tree layer richness. Generally, it can be stated that maintaining a mixture of tree layer species in natural oriental beech stands results in an increase in richness and diversity values of herb plants as well as carbon content and microbial biomass carbon of soil.

78 FR 16247 - Approval for Export-Only Manufacturing Authority, Foreign-Trade Zone 203, SGL Automotive Carbon...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-03-14

... Manufacturing Authority, Foreign-Trade Zone 203, SGL Automotive Carbon Fibers, LLC, (Carbon Fiber Manufacturing... SGL Automotive Carbon Fibers, LLC, within FTZ 203-Site 3, in Moses Lake, Washington (FTZ Docket 4-2011... Carbon Fibers, LLC, as described in the application and Federal Register notice, is approved, subject to...

Defining a landscape-scale monitoring tier for the North American Carbon Program. Chapter 1

Treesearch

David Y. Hollinger

2008-01-01

Better knowledge of carbon stocks and fluxes is needed to understand the current state of the carbon cycle and how it might evolve with changing land uses and climatic conditions. For Canada, the United States, and Mexico, the North American Carbon Program (NACP) has been devised to measure and understand the sources and sinks of CO2, CH

Binding of dinitrogen to an iron-sulfur-carbon site

NASA Astrophysics Data System (ADS)

Čorić, Ilija; Mercado, Brandon Q.; Bill, Eckhard; Vinyard, David J.; Holland, Patrick L.

2015-10-01

Nitrogenases are the enzymes by which certain microorganisms convert atmospheric dinitrogen (N2) to ammonia, thereby providing essential nitrogen atoms for higher organisms. The most common nitrogenases reduce atmospheric N2 at the FeMo cofactor, a sulfur-rich iron-molybdenum cluster (FeMoco). The central iron sites that are coordinated to sulfur and carbon atoms in FeMoco have been proposed to be the substrate binding sites, on the basis of kinetic and spectroscopic studies. In the resting state, the central iron sites each have bonds to three sulfur atoms and one carbon atom. Addition of electrons to the resting state causes the FeMoco to react with N2, but the geometry and bonding environment of N2-bound species remain unknown. Here we describe a synthetic complex with a sulfur-rich coordination sphere that, upon reduction, breaks an Fe-S bond and binds N2. The product is the first synthetic Fe-N2 complex in which iron has bonds to sulfur and carbon atoms, providing a model for N2 coordination in the FeMoco. Our results demonstrate that breaking an Fe-S bond is a chemically reasonable route to N2 binding in the FeMoco, and show structural and spectroscopic details for weakened N2 on a sulfur-rich iron site.

Variability in carbon dioxide fluxes for dense urban, suburban and woodland environments in southern England

NASA Astrophysics Data System (ADS)

Ward, Helen; Kotthaus, Simone; Grimmond, C. Sue; Bjorkegren, Alex; Wilkinson, Matt; Morrison, Will; Evans, Jon; Morison, James; Christen, Andreas

2014-05-01

The net exchange of carbon dioxide between the surface and atmosphere can be measured using the eddy covariance technique. Fluxes from a dense urban environment (central London), a suburban landscape (Swindon) and a woodland ecosystem (Alice Holt) are compared. All sites are located in southern England and experience similar climatic and meteorological conditions, yet have very different land cover. The signatures of anthropogenic and biogenic processes are explored at various (daily, seasonal and annual) timescales. Particular emphasis is placed on identifying the mixture of controls that determine the flux. In summer, there are clear similarities between the suburban and woodland sites, as the diurnal behaviour is dominated by photosynthetic uptake. In winter, however, vegetation is largely dormant and human activity determines the pattern of fluxes at the urban and suburban sites. Emissions from building heating augment the net release of carbon dioxide in cold months. Road use is a major contributor to the total emissions, and the diurnal cycle in the observed fluxes reflects this: in central London roads are busy throughout the day, whereas in Swindon a double-peaked rush-hour signal is evident. The net exchange of carbon dioxide is estimated for each site and set in context with other studies around the world. Central London has the smallest proportion of vegetation and largest emissions amongst study sites in the literature to date. Although Swindon's appreciable vegetation fraction helps to offset the anthropogenic emissions, even in summertime the 24h total flux is usually positive, indicating carbon release. Comparison of these three sites in a similar region demonstrates the effects of increasing urban density and changing land use on the atmosphere. Findings are relevant in terms of characterising the behaviour of urban surfaces and for quantifying the impact of anthropogenic activities.

Seasonal variations of dissolved organic carbon in precipitation over urban and forest sites in central Poland.

PubMed

Siudek, Patrycja; Frankowski, Marcin; Siepak, Jerzy

2015-07-01

Spatial and temporal variability of carbon species in rainwater (bulk deposition) was studied for the first time at two sites located in urban area of Poznań City and protected woodland area (Jeziory), in central Poland, between April and December 2013. The mean concentration of total carbon (TC) for the first site was 5.86 mg L(-1), whereas for the second, 5.21 mg L(-1). Dissolved organic carbon (DOC) concentration accounted for, on average, 87 and 91 % of total carbon in precipitation at urban and non-urban sites, respectively. Significant changes in TC concentrations in rainwater were observed at both sites, indicating that atmospheric transformation, transport, and removal mechanisms of carbonaceous particles were affected by seasonal fluctuations in biogenic/anthropogenic emission and meteorological conditions (i.e., precipitation height and type, atmospheric transport). During the warm season, the DOC concentration in rainwater was mostly influenced by mixed natural and anthropogenic sources. In contrast, during the cold season, the DOC concentration significantly increased mainly as a result of anthropogenic activities, i.e., intensive coal combustion, domestic wood burning, high-temperature processes, etc. In addition, during the winter measurements, significant differences in mean DOC concentration (Kruskal-Wallis test, p < 0.05) were determined for rain, mixed rain-snow, and snow samples. It was found that rainwater TOC concentration measured in Poznań and Jeziory reflected a combination of local, regional, and distant sources. Backward trajectory analysis showed that air masses advected from polluted regions in western Europe largely affect the DOC amount in rainwater, both at urban and non-urban sites. These data imply that carbonaceous compounds are of crucial importance in atmospheric chemistry and should be considered as an important parameter while considering wet deposition, reactions with different substances, especially over polluted environments.

Fluvial carbon export from a lowland Amazonian rainforest in relation to atmospheric fluxes

NASA Astrophysics Data System (ADS)

Vihermaa, Leena E.; Waldron, Susan; Domingues, Tomas; Grace, John; Cosio, Eric G.; Limonchi, Fabian; Hopkinson, Chris; da Rocha, Humberto Ribeiro; Gloor, Emanuel

2016-12-01

We constructed a whole carbon budget for a catchment in the Western Amazon Basin, combining drainage water analyses with eddy covariance (EC) measured terrestrial CO2 fluxes. As fluvial C export can represent permanent C export it must be included in assessments of whole site C balance, but it is rarely done. The footprint area of the flux tower is drained by two small streams ( 5-7 km2) from which we measured the dissolved inorganic carbon (DIC), dissolved organic carbon (DOC), particulate organic carbon (POC) export, and CO2 efflux. The EC measurements showed the site C balance to be +0.7 ± 9.7 Mg C ha-1 yr-1 (a source to the atmosphere) and fluvial export was 0.3 ± 0.04 Mg C ha-1 yr-1. Of the total fluvial loss 34% was DIC, 37% DOC, and 29% POC. The wet season was most important for fluvial C export. There was a large uncertainty associated with the EC results and with previous biomass plot studies (-0.5 ± 4.1 Mg C ha-1 yr-1); hence, it cannot be concluded with certainty whether the site is C sink or source. The fluvial export corresponds to only 3-7% of the uncertainty related to the site C balance; thus, other factors need to be considered to reduce the uncertainty and refine the estimated C balance. However, stream C export is significant, especially for almost neutral sites where fluvial loss may determine the direction of the site C balance. The fate of C downstream then dictates the overall climate impact of fluvial export.

Tundra shrub effects on growing season energy and carbon dioxide exchange

NASA Astrophysics Data System (ADS)

Lafleur, Peter M.; Humphreys, Elyn R.

2018-05-01

Increased shrub cover on the Arctic tundra is expected to impact ecosystem-atmosphere exchanges of carbon and energy resulting in feedbacks to the climate system, yet few direct measurements of shrub tundra-atmosphere exchanges are available to corroborate expectations. Here we present energy and carbon dioxide (CO2) fluxes measured using the eddy covariance technique over six growing seasons at three closely located tundra sites in Canada’s Low Arctic. The sites are dominated by the tundra shrub Betula glandulosa, but percent cover varies from 17%–60% and average shrub height ranges from 18–59 cm among sites. The site with greatest percent cover and height had greater snow accumulation, but contrary to some expectations, it had similar late-winter albedo and snow melt dates compared to the other two sites. Immediately after snowmelt latent heat fluxes increased more slowly at this site compared to the others. Yet by the end of the growing season there was little difference in cumulative latent heat flux among the sites, suggesting evapotranspiration was not increased with greater shrub cover. In contrast, lower albedo and less soil thaw contributed to greater summer sensible heat flux at the site with greatest shrub cover, resulting in greater total atmospheric heating. Net ecosystem exchange of CO2 revealed the potential for enhanced carbon cycling rates under greater shrub cover. Spring CO2 emissions were greatest at the site with greatest percent cover of shrubs, as was summer net uptake of CO2. The seasonal net sink for CO2 was ~2 times larger at the site with the greatest shrub cover compared to the site with the least shrub cover. These results largely agree with expectations that the growing season feedback to the atmosphere arising from shrub expansion in the Arctic has the potential to be negative for CO2 fluxes but positive for turbulent energy fluxes.

BOREAS TGB-12 Rn-222 Activity Data over the NSA

NASA Technical Reports Server (NTRS)

Trumbore, Susan; Hall, Forrest G. (Editor); Conrad, Sara K. (Editor); Sundquist, Eric; Winston, Greg

2000-01-01

The BOREAS TGB-12 team made measurements of soil carbon inventories, carbon concentration in soil gases, and rates of soil respiration at several sites to estimate the rates of carbon accumulation and turnover in each of the major vegetation types. Sampling strategies for soils were designed to take advantage of local fire chronosequences, so that the accumulation of carbon in regrowing mosses could be determined. All the data are used to: (1) calculate the inventory of carbon and nitrogen in moss and mineral soil layers at NSA sites, (2) determine the rates of input and turnover (using both accumulation since the last stand-killing fire and radiocarbon data), and (3) link changes in soil respiration rate to shifts in the C-14 content of soil CO2 to determine the average "age" respired CO2 . These Rn-222 activity data were collected from 15-Nov-1993 to 16-Aug-1994 over the NSA sites. They are useful for determining the rate of gas exchange between soil and the overlying atmosphere. The data in this data set are stored in tabular ASCII files.

Evaluating Ambient Concentrations and Local Emissions of Greenhouse Gases (GHGs) in the San Francisco Bay Area of California Using a Comprehensive Fixed-site and Mobile Monitoring Network

NASA Astrophysics Data System (ADS)

Guha, A.; Bower, J. P.; Martien, P. T.; Randall, S.; Young, A.; Hilken, H.; Stevenson, E.

2015-12-01

The Bay Area Air Quality Management District (hence the Air District) is the greater San Francisco Bay metropolitan region's chief air quality regulatory agency. Aligning itself with Executive Order S-3-05, the Air District has set a goal to reduce the region's GHG emissions by 80% below 1990 levels by the year 2050. The Air District's 10-point Climate Action Work Program lays out the agency's priorities, actions and coordination with regional stakeholders. The Program has three core objectives: (1) to develop a technical and monitoring program to document the region's GHG sources and related emissions, (2) to implement a policy and rule-based approach to control and regulate GHG emissions, and finally, (3) to utilize local governance, incentives and partnerships to encourage GHG emissions reductions.As part of the technical program, the Air District has set up a long term, ambient GHG monitoring network at four sites. The first site is located north and upwind of the urban core at Bodega Bay by the Pacific Coast. It mostly receives clean marine inflow and serves as the regional background site. The other three sites are strategically located at regional exit points for Bay Area plumes that presumably contain GHG enhancements from local sources. These stations are at San Martin, located south of the San Jose metropolitan area; at Patterson Pass at the cross section with California's Central Valley; and at Bethel Island at the mouth of the Sacramento-San Joaquin Delta. At all sites, carbon dioxide (CO2) and methane (CH4) are being measured continuously, along with combustion tracer CO and other air pollutants. The GHG measurements are performed with high precision and fast laser instruments (Picarro Inc). In the longer term, the network will allow the Air District to monitor ambient concentrations of GHGs and thus evaluate the effectiveness of its policy, regulation and enforcement efforts. We present data from the sites in their first few months of operation and demonstrate the efficacy and utility of this monitoring network. We also present our progress on the design and fabrication of a dedicated mobile GHG measurement platform (a research van) equipped with state of the art analyzers capable of measuring isotopic methane (13C - CH4), CH4, CO2 and also nitrous oxide (N2O) in ambient air at fast temporal rates.

A comparison of coupled biogeophysical and biogeochemical dynamics across a precipitation gradient in Oregon using data assimilation

NASA Astrophysics Data System (ADS)

Pettijohn, J. C.; Law, B. E.; Williams, M. D.; Stoekli, R.; Thornton, P. E.; Thomas, C. K.; Hudiburg, T. W.; Martin, J.

2010-12-01

We present results from our coupled biophysical - biochemical model data fusion (MDF) analysis across a climatic gradient in Oregon, USA, using data from a coast-range Douglas-fir (US-Fir; 2006-2008) and a semi-arid ponderosa pine (US-Me2; 2002-2008) AmeriFlux site. Our MDF scheme couples the Ensemble Kalman Filter (EnKF) with the National Center for Atmospheric Research (NCAR) Community Land Model with Carbon-Nitrogen coupling (CLM-CN, version 3.5). Assimilated data includes continuous eddy covariance measurements of forest-atmosphere CO2 (NEE, net ecosystem exchange) and water vapor fluxes (λE, latent heat flux), chamber-based soil respiratory flux, soil moisture and temperature, snow depth (US-Me2), MODIS-derived 8 day LAI, and carbon and nitrogen pools. We quantify the ecosystem carbon and nitrogen budgets, partition NEE and λE fluxes, and thus increase confidence in multi-scale controls on CO2 and water vapor exchange. The MDF did a better job predicting NEE than λE at both sites (r2 = 0.86 for NEE at both sites; λE r2 = 0.65 and 0.63 at the US-ME2 and US-Fir sites, respectively) partly due to a weighting scheme we prescribed for NEE. The distribution of carbon and nitrogen differed significantly between sites, with total ecosystem carbon (vegetation, detritus, soil) of the US-Fir site being about 1.4 times higher than the US-Me2 site (35 kg C m-2 vs. 25 kg C m-2). Mean NEE over overlapping water years ‘07-‘08 was -495 gC m-2 at the US-Me2 site as opposed to -809 gC m-2 at the US-Fir site, nearly a two-fold difference in C uptake across this precipitation gradient. Average GPP and ecosystem respiration (Re) over these two water years were both ~1.7x greater at the US-Fir site, with 1712 gC m^-2 and 1217 gC m-2, respectively, at the US-Me2 site vs. 2841 gC m-2 and 2032 gC m-2 at the US-Fir. Autotrophic respiration contributed 79% and 72% to the Re flux at the US-Me2 and US-Fir sites, respectively, with total soil respiration contributing 53% and 58% to Re. While a comparison of observed and MDF environmental response functions suggests both root-zone soil moisture and leaf-to-air VPD photosynthetic controls at both sites, the MDF did not impose CLM-CN’s soil stress upon photosynthesis at the US-Fir site, suggesting the apparent soil moisture response arises from correlations with other driving variables such as VPD. In summary, we demonstrate that MDF analysis can help constrain coupled ecosystem carbon and water dynamics by combining long-term ecosystem measurements by incorporating necessary measurement and model uncertainties.

Water-quality assessment of the eastern Iowa basins- nitrogen, phosphorus, suspended sediment, and organic carbon in surface water, 1996-98

USGS Publications Warehouse

Becher, Kent D.; Kalkhoff, Stephen J.; Schnoebelen, Douglas J.; Barnes, Kimberlee K.; Miller, Von E.

2001-01-01

Synoptic samples collected during low and high base flow had nitrogen, phosphorus, and organic-carbon concentrations that varied spatially and seasonally. Comparisons of water-quality data from six basic-fixed sampling sites and 19 other synoptic sites suggest that the water-quality data from basic-fixed sampling sites were representative of the entire study unit during periods of low and high base flow when most streamflow originates from ground water.

Crystal growth of carbonate apatite using a CaCO3 flux.

PubMed

Suetsugu, Y; Tanaka, J

1999-09-01

Single crystals of carbonate apatite were grown using a CaCO3 flux under an Ar gas pressure of 55 MPa. The crystals obtained were observed by scanning electron microscopy, optical microscopy and X-ray diffraction. Electron probe microanalyses and thermal analyses were performed. CO3 ions in planar triangle form replaced both OH sites and PO4 tetrahedral sites in the apatite structure: in particular, the OH sites were perfectly substituted by CO3 ions using this method.

Complexation of copper by aquatic humic substances from different environments

USGS Publications Warehouse

McKnight, Diane M.; Feder, Gerald L.; Thurman, E. Michael; Wershaw, Robert L.

1983-01-01

The copper-complexing properties of aquatic humic substances isolated from eighteen different environments were characterized by potentiometric titration, using a cupric ion selective electrode. Potentiometric data were analyzed using FITEQL, a computer program for the determination of chemical equilibrium constants from experimental data. All the aquatic humic substances could be modelled as having two types of Cu(II)-binding sites: one with K equal to about 106 and a concentration of 1.0 ± 0.4 × 10−6 M(mg C)−1 and another with K equal to about 108 and a concentration of 2.6 ± 1.6 × 10−7 M(mg C)−1.A method is described for estimating the Cu(II)-binding sites associated with dissolved humic substances in natural water based on a measurement of dissolved organic carbon, which may be helpful in evaluating chemical processes controlling speciation of Cu and bioavailability of Cu to aquatic organisms.

Climate and Health Co-Benefits in Low-Income Countries: A Case Study of Carbon Financed Water Filters in Kenya and a Call for Independent Monitoring

PubMed Central

Pickering, Amy J.; Arnold, Benjamin F.; Dentz, Holly N.; Colford, John M.; Null, Clair

2016-01-01

Background: The recent global climate agreement in Paris aims to mitigate greenhouse gas emissions while fostering sustainable development and establishes an international trading mechanism to meet this goal. Currently, carbon offset program implementers are allowed to collect their own monitoring data to determine the number of carbon credits to be awarded. Objectives: We summarize reasons for mandating independent monitoring of greenhouse gas emission reduction projects. In support of our policy recommendations, we describe a case study of a program designed to earn carbon credits by distributing almost one million drinking water filters in rural Kenya to avert the use of fuel for boiling water. We compare results from an assessment conducted by our research team in the program area among households with pregnant women or caregivers in rural villages with low piped water access with the reported program monitoring data and discuss the implications. Discussion: Our assessment in Kenya found lower levels of household water filter usage than the internal program monitoring reported estimates used to determine carbon credits; we found 19% (n = 4,041) of households reported filter usage 2–3 years after filter distribution compared to the program stated usage rate of 81% (n = 14,988) 2.7 years after filter distribution. Although carbon financing could be a financially sustainable approach to scale up water treatment and improve health in low-income settings, these results suggest program effectiveness will remain uncertain in the absence of requiring monitoring data be collected by third-party organizations. Conclusion: Independent monitoring should be a key requirement for carbon credit verification in future international carbon trading mechanisms to ensure programs achieve benefits in line with sustainable development goals. Citation: Pickering AJ, Arnold BF, Dentz HN, Colford JM Jr., Null C. 2017. Climate and health co-benefits in low-income countries: a case study of carbon financed water filters in Kenya and a call for independent monitoring. Environ Health Perspect 125:278–283; http://dx.doi.org/10.1289/EHP342 PMID:27634098

Climate and Health Co-Benefits in Low-Income Countries: A Case Study of Carbon Financed Water Filters in Kenya and a Call for Independent Monitoring.

PubMed

Pickering, Amy J; Arnold, Benjamin F; Dentz, Holly N; Colford, John M; Null, Clair

2017-03-01

The recent global climate agreement in Paris aims to mitigate greenhouse gas emissions while fostering sustainable development and establishes an international trading mechanism to meet this goal. Currently, carbon offset program implementers are allowed to collect their own monitoring data to determine the number of carbon credits to be awarded. We summarize reasons for mandating independent monitoring of greenhouse gas emission reduction projects. In support of our policy recommendations, we describe a case study of a program designed to earn carbon credits by distributing almost one million drinking water filters in rural Kenya to avert the use of fuel for boiling water. We compare results from an assessment conducted by our research team in the program area among households with pregnant women or caregivers in rural villages with low piped water access with the reported program monitoring data and discuss the implications. Our assessment in Kenya found lower levels of household water filter usage than the internal program monitoring reported estimates used to determine carbon credits; we found 19% ( n = 4,041) of households reported filter usage 2-3 years after filter distribution compared to the program stated usage rate of 81% ( n = 14,988) 2.7 years after filter distribution. Although carbon financing could be a financially sustainable approach to scale up water treatment and improve health in low-income settings, these results suggest program effectiveness will remain uncertain in the absence of requiring monitoring data be collected by third-party organizations. Independent monitoring should be a key requirement for carbon credit verification in future international carbon trading mechanisms to ensure programs achieve benefits in line with sustainable development goals. Citation: Pickering AJ, Arnold BF, Dentz HN, Colford JM Jr., Null C. 2017. Climate and health co-benefits in low-income countries: a case study of carbon financed water filters in Kenya and a call for independent monitoring. Environ Health Perspect 125:278-283; http://dx.doi.org/10.1289/EHP342.

MM III/Mk 12A Reentry Vehicle Carbon/Carbon Nosetip Production Program.

DTIC Science & Technology

1980-05-28

MI IlI/MIK 12A REENTRY VEHICLE CARBON/CARBON NOSETIP PRODUCTION PROGRAM CRITICAL ITEM CONI.<OL PLN 1.0 INTRODUCTION 1. 1 PURPOS’ The purpose of...the basis of its proven technological and pruduction capability in Fine-Weave Pierced Fabric (FWPF) Carbon/Carbocn Nosetips. Avco in turn has awarded...are inspected prior to the acceptanicc of the part. Each operator and/or inspector assig ;ned to do a specific task has all the required infornmation

Soil data for a thermokarst bog and the surrounding permafrost plateau forest, located at Bonanza Creek Long Term Ecological Research Site, Interior Alaska

USGS Publications Warehouse

Manies, Kristen L.; Fuller, Christopher C.; Jones, Miriam C.; Waldrop, Mark P.; McGeehin, John P.

2017-01-19

Peatlands play an important role in boreal ecosystems, storing a large amount of soil organic carbon. In northern ecosystems, collapse-scar bogs (also known as thermokarst bogs) often form as the result of ground subsidence following permafrost thaw. To examine how ecosystem carbon balance changes with the loss of permafrost, we measured carbon and nitrogen storage within a thermokarst bog and the surrounding forest, which continues to have permafrost. These sites are a part of the Bonanza Creek Long Term Ecological Research (LTER) site and are located within Interior Alaska. Here, we report on methods used for core collection analysis as well as the cores’ physical, chemical, and descriptive properties.

Comparing Stream Discharge, Dissolved Organic Carbon, and Selected MODIS Indices in Freshwater Basins

NASA Astrophysics Data System (ADS)

Shaver, W. T.; Wollheim, W. M.

2009-12-01

In a preliminary study of the Ipswich Basin in Massachusetts, a good correlation was found to exist between the MODIS (Moderate Resolution Imaging Spectroradiometer) Enhanced Vegetation Index and stream dissolved organic carbon (DOC). Further study was warranted to determine the utility of MODIS indices in predicting temporal stream DOC. Stream discharge rates and DOC data were obtained from the USGS National Water Quality Assessment Program (NAWQA) database. Twelve NAWQA monitoring sites were selected for evaluation based on the criteria of having drainage basin sizes less than 600 km2 with relatively continuous, long-term DOC and discharge data. MODIS indices were selected based on their connections with terrestrial DOC and were obtained for each site's catchment area. These included the Normalized Vegetation Index (NDVI), the Enhanced Vegetation Index (EVI), the Daily Photosynthesis (PSN) and the Leaf Area Index (LAI). Regression analysis was used to evaluate the relationships between DOC, discharge and MODIS products. Data analysis revealed several important trends. Sites with strong positive correlation coefficients (r values ranging from 0.462 to 0.831) between DOC and discharge displayed weak correlations with all of the MODIS indices (r values ranging from 0 to 0.322). For sites where the DOC/discharge correlation was weak or negative, MODIS indices were moderately correlated, with r values ranging from 0.35 to 0.647, all of which were significant at less than 1 percent. Some sites that had weak positive correlations with MODIS indices displayed a lag time, that is, the MODIS index rose and fell shortly before the DOC concentration rose and fell. Shifting the MODIS data forward in time by roughly one month significantly increased the DOC/MODIS r values by about 10%. NDVI and EVI displayed the strongest correlations with temporal DOC variability (r values ranging from 0.471 to 0.647), and therefore these indices are the most promising for being incorporated into a model for remotely sensing terrestrial DOC.

Simulating carbon and water cycles of larch forests in East Asia by the BIOME-BGC model with AsiaFlux data

NASA Astrophysics Data System (ADS)

Ueyama, M.; Ichii, K.; Hirata, R.; Takagi, K.; Asanuma, J.; Machimura, T.; Nakai, Y.; Ohta, T.; Saigusa, N.; Takahashi, Y.; Hirano, T.

2010-03-01

Larch forests are widely distributed across many cool-temperate and boreal regions, and they are expected to play an important role in global carbon and water cycles. Model parameterizations for larch forests still contain large uncertainties owing to a lack of validation. In this study, a process-based terrestrial biosphere model, BIOME-BGC, was tested for larch forests at six AsiaFlux sites and used to identify important environmental factors that affect the carbon and water cycles at both temporal and spatial scales. The model simulation performed with the default deciduous conifer parameters produced results that had large differences from the observed net ecosystem exchange (NEE), gross primary productivity (GPP), ecosystem respiration (RE), and evapotranspiration (ET). Therefore, we adjusted several model parameters in order to reproduce the observed rates of carbon and water cycle processes. This model calibration, performed using the AsiaFlux data, substantially improved the model performance. The simulated annual GPP, RE, NEE, and ET from the calibrated model were highly consistent with observed values. The observed and simulated GPP and RE across the six sites were positively correlated with the annual mean air temperature and annual total precipitation. On the other hand, the simulated carbon budget was partly explained by the stand disturbance history in addition to the climate. The sensitivity study indicated that spring warming enhanced the carbon sink, whereas summer warming decreased it across the larch forests. The summer radiation was the most important factor that controlled the carbon fluxes in the temperate site, but the VPD and water conditions were the limiting factors in the boreal sites. One model parameter, the allocation ratio of carbon between belowground and aboveground, was site-specific, and it was negatively correlated with the annual climate of annual mean air temperature and total precipitation. Although this study substantially improved the model performance, the uncertainties that remained in terms of the sensitivity to water conditions should be examined in ongoing and long-term observations.

Simulating carbon and water cycles of larch forests in East Asia by the BIOME-BGC model with AsiaFlux data

NASA Astrophysics Data System (ADS)

Ueyama, M.; Ichii, K.; Hirata, R.; Takagi, K.; Asanuma, J.; Machimura, T.; Nakai, Y.; Ohta, T.; Saigusa, N.; Takahashi, Y.; Hirano, T.

2009-08-01

Larch forests are widely distributed across many cool-temperate and boreal regions, and they are expected to play an important role in global carbon and water cycles. Model parameterizations for larch forests still contain large uncertainties owing to a lack of validation. In this study, a process-based terrestrial biosphere model, BIOME-BGC, was tested for larch forests at six AsiaFlux sites and used to identify important environmental factors that affect the carbon and water cycles at both temporal and spatial scales. The model simulation performed with the default deciduous conifer parameters produced results that had large differences from the observed net ecosystem exchange (NEE), gross primary productivity (GPP), ecosystem respiration (RE), and evapotranspiration (ET). Therefore, we adjusted several model parameters in order to reproduce the observed rates of carbon and water cycle processes. This model calibration, performed using the AsiaFlux data, significantly improved the model performance. The simulated annual GPP, RE, NEE, and ET from the calibrated model were highly consistent with observed values. The observed and simulated GPP and RE across the six sites are positively correlated with the annual mean air temperature and annual total precipitation. On the other hand, the simulated carbon budget is partly explained by the stand disturbance history in addition to the climate. The sensitivity study indicates that spring warming enhances the carbon sink, whereas summer warming decreases it across the larch forests. The summer radiation is the most important factor that controls the carbon fluxes in the temperate site, but the VPD and water conditions are the limiting factors in the boreal sites. One model parameter, the allocation ratio of carbon between aboveground and belowground, is site-specific, and it is negatively correlated with the annual climate of annual mean air temperature and total precipitation. Although this study significantly improves the model performance, the uncertainties that remain in terms of the sensitivity to water conditions should be examined in ongoing and long-term observations.

Insights into soil carbon dynamics across climatic and geologic gradients from time-series and fraction-specific radiocarbon analysis

NASA Astrophysics Data System (ADS)

van der Voort, Tessa Sophia; Hagedorn, Frank; Zell, Claudia; McIntyre, Cameron; Eglinton, Tim

2016-04-01

Understanding the interaction between soil organic matter (SOM) and climatic, geologic and ecological factors is essential for the understanding of potential susceptibility and vulnerability to climate and land use change. Radiocarbon constitutes a powerful tool for unraveling SOM dynamics and is increasingly used in studies of carbon turnover. The complex and inherently heterogeneous nature of SOM renders it challenging to assess the processes that govern SOM stability by solely looking at the bulk signature on a plot-scale level. This project combines bulk radiocarbon measurements on a regional-scale spanning wide climatic and geologic gradients with a more in-depth approach for a subset of locations. For this subset, time-series and carbon pool-specific radiocarbon data has been acquired for both topsoil and deeper soils. These well-studied sites are part of the Long-Term Forest Ecosystem Research (LWF) program of the Swiss Federal Institute for Forest, Snow and Landscape research (WSL). Statistical analysis was performed to examine relationships of radiocarbon signatures with variables such as temperature, precipitation and elevation. Bomb-curve modeling was applied determine carbon turnover using time-series data. Results indicate that (1) there is no significant correlation between Δ14C signature and environmental conditions except a weak positive correlation with mean annual temperature, (2) vertical gradients in Δ14C signatures in surface and deeper soils are highly similar despite covering disparate soil-types and climatic systems, and (3) radiocarbon signatures vary significantly between time-series samples and carbon pools. Overall, this study provides a uniquely comprehensive dataset that allows for a better understanding of links between carbon dynamics and environmental settings, as well as for pool-specific and long-term trends in carbon (de)stabilization.

Clay mineral continental amplifier for marine carbon sequestration in a greenhouse ocean

PubMed Central

Kennedy, Martin J.; Wagner, Thomas

2011-01-01

The majority of carbon sequestration at the Earth’s surface occurs in marine continental margin settings within fine-grained sediments whose mineral properties are a function of continental climatic conditions. We report very high mineral surface area (MSA) values of 300 and 570 m2 g in Late Cretaceous black shales from Ocean Drilling Program site 959 of the Deep Ivorian Basin that vary on subcentennial time scales corresponding with abrupt increases from approximately 3 to approximately 18% total organic carbon (TOC). The observed MSA changes with TOC across multiple scales of variability and on a sample-by-sample basis (centimeter scale), provides a rigorous test of a hypothesized influence on organic carbon burial by detrital clay mineral controlled MSA. Changes in TOC also correspond with geochemical and sedimentological evidence for water column anoxia. Bioturbated intervals show a lower organic carbon loading on mineral surface area of 0.1 mg-OC m-2 when compared to 0.4 mg-OC m-2 for laminated and sulfidic sediments. Although either anoxia or mineral surface protection may be capable of producing TOC of < 5%, when brought together they produced the very high TOC (10–18%) apparent in these sediments. This nonlinear response in carbon burial resulted from minor precession-driven changes of continental climate influencing clay mineral properties and runoff from the African continent. This study identifies a previously unrecognized land–sea connection among continental weathering, clay mineral production, and anoxia and a nonlinear effect on marine carbon sequestration during the Coniacian-Santonian Oceanic Anoxic Event 3 in the tropical eastern Atlantic. PMID:21576498

Understanding the Organo-Carbonate Associations in Carbonaceous Chondrites with the Use of Micro-Raman Analysis

NASA Technical Reports Server (NTRS)

Chan, Q. H. S.; Zolensky, M. E.

2015-01-01

Carbonates can potentially provide sites for organic materials to accrue and develop into complex macromolecules. This study examines the organics associated with carbonates in carbonaceous chondrites using micron-Raman imaging.

Understanding the Organo-Carbonate Associations in Carbonaceous Chondrites with the Use of Micro-Raman Analysis

NASA Technical Reports Server (NTRS)

Chan, Q. H. S.; Zolensky, M. E.

2015-01-01

Carbonates can potentially provide sites for organic materials to accrue and develop into complex macromolecules. This study examines the organics associated with carbonates in carbonaceous chondrites using µ-Raman imaging.

Quantifying the effect of nighttime interactions between roots and canopy physiology and their control of water and carbon cycling on feedbacks between soil moisture and terrestrial climatology under variable environmental conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Domec, Jean-Christophe; Palmroth, Sari; Oren, Ram

The primary objective of this project is to characterize and quantify how the temporal variability of hydraulic redistribution (HR) and its physiological regulation in unmanaged and complex forests is affecting current water and carbon exchange and predict how future climate scenarios will affect these relationships and potentially feed back to the climate. Specifically, a detailed study of ecosystem water uptake and carbon exchange in relation to root functioning was proposed in order to quantify the mechanisms controlling temporal variability of soil moisture dynamic and HR in three active AmeriFlux sites, and to use published data of two other inactive AmeriFluxmore » sites. Furthermore, data collected by our research group at the Duke Free Air CO2 enrichment (FACE) site was also being utilized to further improve our ability to forecast future environmental impacts of elevated CO2 concentration on soil moisture dynamic and its effect on carbon sequestration and terrestrial climatology. The overarching objective being to forecast, using a soil:plant:atmosphere model coupled with a biosphere:atmosphere model, the impact of root functioning on land surface climatology. By comparing unmanaged sites to plantations, we also proposed to determine the effect of land use change on terrestrial carbon sequestration and climatology through its effect on soil moisture dynamic and HR. Our simulations of HR by roots indicated that in some systems HR is an important mechanism that buffers soil water deficit, affects energy and carbon cycling; thus having significant implications for seasonal climate. HR maintained roots alive and below 70% loss of conductivity and our simulations also showed that the increased vapor pressure deficit at night under future conditions was sufficient to drive significant nighttime transpiration at all sites, which reduced HR. This predicted reduction in HR under future climate conditions played an important regulatory role in land atmosphere interactions by affecting whole ecosystem carbon and water balance. Under future climatic scenarios, HR was reduced thus affecting negatively plant water use and carbon assimilation. The discrepancy between the predicted and actual surface warming and atmospheric water vapor caused by the persistence of evapotranspiration during the dry season, increasing energy transfer in the form of latent heat. Under those simulations, we also evaluated how the hydraulic properties of soil and xylem limited the rate of carbon uptake, and carbon net ecosystem exchange. The multilayered hydraulically driven soil vegetation atmosphere carbon and water transfer model was designed to represent processes common to vascular plants, so that ecosystem atmosphere exchange could be captured by the same processes at different sites. Those models shown to be well suited for investigating the impact of drought on forest ecosystems because of its explicit treatment of water transport to leaves. This modeling work also confirmed that unmanaged, mixed hardwood site are more resilient to climatic variations than an adjacent pine plantation, but that future climatic conditions will reverse this trends.« less

CCHDO: Data Management for US and International GO-SHIP and Related Programs

NASA Astrophysics Data System (ADS)

Diggs, S. C.

2016-02-01

An ever-expanding universe of oceanographic data that includes ship-based measurements (CTD, Nutrients, CFCs, etc.) - as well as the data collected from floats, drifters, gliders and moorings - are continuously gathered, scrutinized, documented and disseminated by the CLIVAR and Carbon Hydrographic Data Office (CCHDO) at Scripps Institution of Oceanography. As the official data assembly center for US GO-SHIP (a decadal global hydrography program) the CCHDO is involved in setting and promoting standards of modern data exchange - from observations at sea to final archive. Established in 1996, the CCHDO has a solid history of curating the highest quality full-depth hydrographic data and associated documentation, metadata and DOIs on an API-based web site that provides data in multiple formats and platforms that have been specifically requested by the hydrographic research community. The CCHDO's website, programming platforms, and documentation standards constantly evolve, based on the feedback we receive from the hydrographic community. Technical convergence and collaboration with organizations that include CDIAC, Princeton, NOAA/NCEI, Argo, OceanSITES, BCO-DMO and GO-SHIP is central to our success. We were early adopters of small crowd-sourcing for quality control, and by being involved in all aspects of data use we reintegrate suggested changes to the data, flags and documentation supplied by the most highly recognized and regarded hydrography researchers and institutions in the world.

ANNUAL RADIOACTIVE WASTE TANK INSPECTION PROGRAM - 2011

DOE Office of Scientific and Technical Information (OSTI.GOV)

West, B.; Waltz, R.

2012-06-21

Aqueous radioactive wastes from Savannah River Site (SRS) separations and vitrification processes are contained in large underground carbon steel tanks. Inspections made during 2011 to evaluate these vessels and other waste handling facilities along with evaluations based on data from previous inspections are the subject of this report. The 2011 inspection program revealed that the structural integrity and waste confinement capability of the Savannah River Site waste tanks were maintained. All inspections scheduled per SRR-LWE-2011-00026, HLW Tank Farm Inspection Plan for 2011, were completed. Ultrasonic measurements (UT) performed in 2011 met the requirements of C-ESR-G-00006, In-Service Inspection Program for Highmore » Level Waste Tanks, Rev. 3, and WSRC-TR-2002-00061, Rev.6. UT inspections were performed on Tanks 25, 26 and 34 and the findings are documented in SRNL-STI-2011-00495, Tank Inspection NDE Results for Fiscal Year 2011, Waste Tanks 25, 26, 34 and 41. A total of 5813 photographs were made and 835 visual and video inspections were performed during 2011. A potential leaksite was discovered at Tank 4 during routine annual inspections performed in 2011. The new crack, which is above the allowable fill level, resulted in no release to the environment or tank annulus. The location of the crack is documented in C-ESR-G-00003, SRS High Level Waste Tank Leaksite Information, Rev.6.« less

Holocene records of geomagnetic field behavior from a north-south transect along the western Antarctic Peninsula

NASA Astrophysics Data System (ADS)

Brachfeld, S. A.; Shah, D. P.; St-Onge, M.; St-Onge, G.

2013-12-01

Geochronology is inherently difficult when working with Antarctic margin sediments. Radiocarbon dating and oxygen isotope stratigraphy are challenging or impossible in sites with poor preservation of biogenic calcite. Radiocarbon dating of the acid insoluble organic matter (AIOM) is further complicated by organically lean sediment and the presence of reworked organic carbon or detrital carbon from sedimentary rocks. These complications limit the ability to interpret a paleoclimate record. Geomagnetic paleointensity dating is a proven 'tuning' technique that has been successfully applied in several studies around the Antarctic margin. However, the reference curves to which these sites were tuned were constructed primarily from Northern Hemisphere data. Here we present paleomagnetic secular variation (PSV) and relative paleointensity (RPI) data from three Antarctic Peninsula sites that possess independent chronologies and which have moderate to ultra-high sedimentation rates (40 - 700 cm/ka). Maxwell Bay, located in the volcanic South Shetland Islands, is an ultra-high-resolution site with strongly magnetic sediments from which the Shallow Drilling (SHALDRIL) program recovered a 108-m record spanning the last 14 ka. Outer Barilari Bay and Hugo Island Trough, which lie to the South along the western Antarctic Peninsula, are moderate resolution sites with a high proportion of biogenic silica. Maxwell Bay and Bariliari Bay are unique in that they possess homogenous sediment and uniform magnetic mineral assemblages, while also preserving biogenic calcite, a rare combination on the Antarctic margin. All three sites preserve strong, stable remanent magnetizations with an easily isolated characteristic component and MAD values generally < 2°, with the exception of turbidites, intervals with abundant dropstones, and biosiliceous ooze intervals. Inclination values fluctuate between the present-day value at the cores sites (-58°) and the geomagnetic axial dipole inclination (-77°) values for each site, with a temporal wavelength of approximately 1000 years. The Holocene intensity of the geomagnetic field in this region was highest during the last 3000 years, broadly similar to patterns observed in the Northern Hemisphere. The records will be stacked in order to generate a regional reference curve for the Antarctic Peninsula. Moreover, these sites have the potential to fill a spatial gap in the distribution of paleomagnetic records that are used in geomagnetic field models.

Insights into soil carbon dynamics across climatic and geologic gradients from temporally-resolved radiocarbon measurements

NASA Astrophysics Data System (ADS)

van der Voort, T. S.; Hagedorn, F.; Mannu, U.; Walthert, L.; McIntyre, C.; Eglinton, T. I.

2016-12-01

Soil carbon constitutes the largest terrestrial reservoir of organic carbon, and therefore quantifying soil organic matter dynamics (carbon turnover, stocks and fluxes) across spatial gradients is essential for an understanding of the carbon cycle and the impacts of global change. In particular, links between soil carbon dynamics and different climatic and compositional factors remains poorly understood. Radiocarbon constitutes a powerful tool for unraveling soil carbon dynamics. Temporally-resolved radiocarbon measurements, which take advantage of "bomb-radiocarbon"-driven changes in atmospheric 14C, enable further constraints to be placed on C turnover times. These in turn can yield more precise flux estimates for both upper and deeper soil horizons. This project combines bulk radiocarbon measurements on a suite of soil profiles spanning strong climatic (MAT 1.3-9.2°C, MAP 600 to 2100 mm m-2y-1) and geologic gradients with a more in-depth approach for a subset of locations. For this subset, temporal and carbon-fraction specific radiocarbon data has been acquired for both topsoil and deeper soils. These well-studied sites are part of the Long-Term Forest Ecosystem Research (LWF) program of the Swiss Federal Institute for Forest, Snow and Landscape research (WSL). Resulting temporally-resolved turnover estimates are coupled to carbon stocks, fluxes across this wide range of forest ecosystems and are examined in the context of environmental drivers (temperature, precipitation, primary production and soil moisture) as well as composition (sand, silt and clay content). Statistical analysis on the region-scale - correlating radiocarbon signature with climatic variables such as temperature, precipitation, primary production and elevation - indicates that composition rather than climate is a key driver of ­­Δ14C signatures. Estimates of carbon turnover, stocks and fluxes derived from temporally-resolved measurements highlight the pivotal role of soil moisture as a key driver of soil carbon turnover and associated fluxes. Overall, this study has afforded a uniquely comprehensive dataset that improves our understanding of controls on carbon dynamics across spatial and temporal scales, as well as the pool-specific and long-term trends in soil carbon (de)stabilization and vulnerability.

Nanostructured nonprecious metal catalysts for oxygen reduction reaction.

PubMed

Wu, Gang; Zelenay, Piotr

2013-08-20

Platinum-based catalysts represent a state of the art in the electrocatalysis of oxygen reduction reaction (ORR) from the point of view of their activity and durability in harnessing the chemical energy via direct electrochemical conversion. However, because platinum is both expensive and scarce, its widespread implementation in such clean energy applications is limited. Recent breakthroughs in the synthesis of high-performance nonprecious metal catalysts (NPMCs) make replacement of Pt in ORR electrocatalysts with earth-abundant elements, such as Fe, Co, N, and C, a realistic possibility. In this Account, we discuss how we can obtain highly promising M-N-C (M: Fe and/or Co) catalysts by simultaneously heat-treating precursors of nitrogen, carbon, and transition metals at 800-1000 °C. The activity and durability of resulting catalysts depend greatly on the selection of precursors and synthesis chemistry. In addition, they correlate quite well with the catalyst nanostructure. While chemists have presented no conclusive description of the active catalytic site for this class of NPMCs, they have developed a designed approach to making active and durable materials, focusing on the catalyst nanostructure. The approach consists of nitrogen doping, in situ carbon graphitization, and the usage of graphitic structures (possibly graphene and graphene oxides) as carbon precursors. Various forms of nitrogen, particularly pyridinic and quaternary, can act as n-type carbon dopants in the M-N-C catalysts, assisting in the formation of disordered carbon nanostructures and donating electrons to the carbon. The CNx structures are likely a crucial part of the ORR active site(s). Noteworthy, the ORR activity is not necessarily governed by the amount of nitrogen, but by how the nitrogen is incorporated into the nanostructures. Apart from the possibility of a direct participation in the active site, the transition metal often plays an important role in the in situ formation of various carbon nanostructures by catalyzing the decomposition of the nitrogen/carbon precursor. We can control the formation of different nanostructures during the synthesis of M-N-C catalysts. For example, in situ formed nitrogen-doped graphene-sheets can only be derived from polyaniline (PANI), probably due to structural similarities between the aromatic structures of PANI and graphene. Highly-graphitized carbon nanostructures may serve as a matrix for the formation of ORR-active groups with improved catalytic activity and durability, containing nitrogen and most probably also metal atoms. In the future, we will likely focus NPMC synthesis approaches on precise control of interactions between precursors of the metal and carbon/nitrogen during the heat treatment. The main purposes will be to maximize the number of active sites, optimize nitrogen doping levels, and generate morphologies capable of hosting active and stable ORR sites.

Can hydrocarbons entrapped in seep carbonates serve as gas geochemistry recorder?

NASA Astrophysics Data System (ADS)

Blumenberg, Martin; Pape, Thomas; Seifert, Richard; Bohrmann, Gerhard; Schlömer, Stefan

2018-04-01

The geochemistry of seep gases is useful for an understanding of the local petroleum system. Here it was tested whether individual light hydrocarbons in seep gases are representatively entrapped in authigenic carbonates that formed near active seep sites. If applicable, it would be possible to extract geochemical information not only on the origin but also on the thermal maturity of the hydrocarbon source rocks from the gases entrapped in carbonates in the past. Respective data could be used for a better understanding of paleoenvironments and might directly serve as calibration point for, amongst others, petroleum system modeling. For this approach, (sub)-recent seep carbonates from the Black Sea (Paleodnjepr region and Batumi seep area), two sites of the Campeche Knoll region in the Gulf of Mexico, and the Venere mud volcano (Mediterranean Sea) were selected. These seep carbonates derive from sites for which geochemical data on the currently seeping gases exist. During treatment with phosphoric acid, methane and higher hydrocarbons were released from all carbonates, but in low concentrations. Compositional studies demonstrate that the ratio of methane to the sum of higher hydrocarbons (C1/(C2+C3)) is (partly strongly) positively biased in the entrapped gas fraction. δ13C values of C1 were determined for all samples and, for the samples from the Gulf of Mexico and the Mediterranean Sea, also of C2 and C3. The present dataset from six seep sites indicates that information on the seeped methane can be—although with a scatter of several permil—recorded in seep carbonate matrices, but other valuable information like the composition and δ13C of ethane and propane appears to be modified or lost during, for example, enclosure or at an early stage of diagenesis.

Diurnal and Seasonal Variations of Eddy-Covariance Carbon Dioxide Fluxes Above an Urban Wetland, Partitioned by Vegetation Cover

NASA Astrophysics Data System (ADS)

Schafer, K. V.; Duman, T.

2017-12-01

The New Jersey Meadowlands are an urban brackish marsh with a long history of human activity causing disturbances and alterations. Carbon emissions were measured from two sites in the Meadowlands, a natural site and a restored site, using eddy-covariance (EC) from 2014 to 2016. At each site, the EC towers were placed at the interface of two vegetation covers, allowing capturing this aspect of the wetland's heterogeneity. Using footprint modeling and light response curves we were able to partition measured fluxes between vegetation cover types and compare CO2 fluxes from patches of invasive versus native wetland vegetation communities. We show that further separating the data into seasonal and diurnal fluxes reveals patterns in CO2 fluxes that allow determining the nature of each vegetation cover as a source or sink for CO2. Our results also show that CO2 emissions from the restored wetland are significantly higher than the natural wetland. Areas of invasive Phragmites australis at the natural site had the lowest CO2 release rates during winter. These were consistently lower in magnitude than summer daytime uptake, therefore making this part of the wetland a CO2 sink. Areas planted with native Spartina alterniflora at the restored site had the largest uptake during daytime, therefore seemingly justifying restoration activities. However, they also had the highest emission rates during summer nighttime, and therefore the daily summer net uptake was not the highest compared with other vegetation covers. Furthermore, emissions from the restored site during winter were larger compared to the natural site, indicating that restoration activities might have led to a significant increase of carbon release from the wetland. Thus, during the study period the restored wetland acted as a carbon source.

Limited Carbonate Dissolution by Boring Microflora at Two Volcanically Acidified Temperate Sites: Ischia (Italy, Mediterranean Sea) and Faial (Azores, NE Atlantic Ocean)

NASA Astrophysics Data System (ADS)

Tribollet, A.; Grange, J. S.; Parra, H.; Rodolfo-Metalpa, R.; Carreiro-Silva, M.

2018-01-01

In situ effects of ocean acidification on carbonate dissolution by microboring flora, also called biogenic dissolution, have only been studied once in tropical environments. Naturally acidified seawaters due to CO2 vents offer a perfect setting to study these effects in temperate systems. Three sites were selected at Ischia (Italy, Mediterranean Sea) with one experiencing ambient pH and the two others a mean pHT of 7.2 and 7.5. At Faial (Azores, NE Atlantic), one site with ambient pH and one acidified site with a mean pHT of 7.4 were selected. Experiments were carried out during 1.5 months and 6 months in Azores and Ischia, respectively, to determine the effects of OA on microboring communities in various carbonate substrates. Low pH influenced negatively boring microflora development by limiting their depth of penetration and abundance in substrates. Biogenic dissolution was thus reduced by a factor 3 to 7 depending on sites and substrate types. At sites with ambient pH in Faial, biogenic dissolution contributed up to 23% to the total weight loss, while it contributed less than 1% to the total weight loss of substrates at the acidified sites. Most of the dissolution at these sites was due to chemical dissolution (often Ω ≤ 1). Such conditions maintained microboring communities at a pioneer stage with a limited depth of penetration in substrates. Our results, together with previous findings that showed an increase of biogenic dissolution at pH > 7.7, suggest that there is a pH tipping point below which microborer development and thus carbonate biogenic dissolution is strongly limited.

Engineering of High-Toughness Carbon Nanotubes Hierarchically Laminated Composites

DTIC Science & Technology

2012-01-27

REPORT TYPE Final 3. DATES COVERED (From - To) Jul-10 - Jul-11 4. TITLE AND SUBTITLE Program Title: ENGINEERING OF HIGH-TOUGHNESS CARBON NANOTUBES ...LIMITATION OF ABSTRACT 18. NUMBER OF PAGES 19a. NAME OF RESPONSIBLE PERSON Program Title: ENGINEERING OF HIGH-TOUGHNESS CARBON NANOTUBES ...Ashby plots can be attained (Fig. 2B). 5. New doping method of carbon nanotubes was developed. Funding Profile: (Give the fiscal year funding

The role of fossil organic matter in the ecosystem development of post-mining sites revealed by isotope analyses

NASA Astrophysics Data System (ADS)

Jandova, Katerina; Hyodo, Fujio; Vindušková, Olga; Moradi, Jabbar; Frouz, Jan

2017-04-01

Sediments rich in kerogen ( 19 Ma old, 14C-free) are present in the overburden at post-mining area in Western Bohemia, near Sokolov city, the Czech Republic. There are two successional chronosequences, an alder reclamation and spontaneous succession, consisting of sites that differ in time since heaping. Both chronosequences accumulate recent organic matter over time, although the process is initially faster at reclamation. We hypothesized that (i) radiocarbon age of soil organic matter would be decreasing with time since spoil heaping; (ii) the detrital food web would show the assimilation of fossil carbon by heterotrophic organisms in the initial stages of succession when fossil organic matter is the predominant source of carbon; (iii) the isotopic track of fossil organic matter in the detrital food web would be more prominent at sites with lower vegetation cover and litter production. Nitrogen isotopic ratios of soils were high at the young sites and the decrease in δ15N was correlated with the increase in content of recent organic carbon. Nitrogen isotopic ratios of soil detritivores equalled to that of tree leaves at reclamation but were higher at successional sites. Possibly, other food sources were used apart from tree leaves litter at the latter. Interestingly, soil animals but not primary producers were 14C depleted in the youngest relative to the oldest sites. The depletion in 14C of detritivores relative to primary producers was likely due to the geophagy behaviour of the millipedes at the young sites where fossil organic matter is the largest carbon pool.

Early Eocene to Late Miocene Variations in the South Atlantic CCD: Constraints from the Walvis Ridge Depth-Transect (ODP Leg 208)

NASA Astrophysics Data System (ADS)

Lindsey, M. M.; Schellenberg, S. A.

2006-12-01

Carbonate saturation profiles are complex and dynamic products of processes operating on spatiotemporal scales from the "short-term local" (e.g. carbonate export production, carbonate ion concentration) to the "long- term global" (e.g. carbonate-silicate weathering, shelf:basin carbonate partitioning). Thus, a refined history of carbonate saturation may provide insight on global carbon-cycle dynamics. An established, if crude, proxy for reconstructing carbonate saturation is the wt% carbonate content of pelagic sediments, where <20 wt% is ascribed to deposition below the carbonate compensation depth (CCD). A number of now classic works (e.g. Berger and Roth, 1975; van Andel, 1977) established first-order and presumably global Cenozoic CCD fluctuations. The Walvis Ridge depth-transect of ODP Leg 208 represents an excellent opportunity to refine our understanding of the South Atlantic Cenozoic CCD. Wt% carbonate determinations (n = 299) through the Early Eocene to Late Miocene section at Site 1267 are significantly correlated with associated natural gamma ray values (r2 = 0.92). This relationship was used to produce a cm-scale synthetic wt% carbonate record ordinated in the time-domain via the ship-board age-model and in the paleodepth-domain via Sclater and Parsons (1977) crustal age-depth relationship. The Site 1267 record shows good general agreement with previous low-resolution (>10^{5-6} yr) CCD reconstructions and correlates relatively well with estimates of eustatic sea level fluctuations. Ongoing research expands this general approach to shallower and deeper ODP Leg 208 sites to provide greater constraints on the history of the South Atlantic CCD. These data, combined with other proxies (e.g. planktonic foraminifer fragmentation, stable isotopes) and placed within evolving Leg 208 age-models, will provide valuable constraints on cyclic and secular fluctuations in the South Atlantic carbonate saturation profile and their relation to various components of the earth system (e.g. pCO2, sea level, tectonics).

DOE Office of Scientific and Technical Information (OSTI.GOV)

Burton, J. C.; Environmental Research

The Commodity Credit Corporation (CCC) of the U.S. Department of Agriculture (USDA) has entered into an interagency agreement with the U.S. Department of Energy (DOE) under which Argonne National Laboratory provides technical assistance for hazardous waste site characterization and remediation for the CCC/USDA. Carbon tetrachloride is the contaminant of primary concern at sites in Kansas where former CCC/USDA grain storage facilities were located. Argonne applies its QuickSite(reg sign) Expedited Site Characterization (ESC) approach to these former facilities. The QuickSite environmental site characterization methodology is Argonne's proprietary implementation of the ESC process (ASTM 1998). Argonne has used this approach at severalmore » former CCC/USDA facilities in Kansas, including Agenda, Agra, Everest, and Frankfort. The Argonne ESC approach revolves around a multidisciplinary, team-oriented approach to problem solving. The basic features and steps of the QuickSite methodology are as follows: (1) A team of scientists with diverse expertise and strong field experience is required to make the process work. The Argonne team is composed of geologists, geochemists, geophysicists, hydrogeologists, chemists, biologists, engineers, computer scientists, health and safety personnel, and regulatory staff, as well as technical support staff. Most of the staff scientists are at the Ph.D. level; each has on average, more than 15 years of experience. The technical team works together throughout the process. In other words, the team that plans the program also implements the program in the field and writes the reports. More experienced scientists do not remain in the office while individuals with lesser degrees or experience carry out the field work. (2) The technical team reviews, evaluates, and interprets existing data for the site and the contaminants there to determine which data sets are technically valid and can be used in initially designing the field program. A basic mistake sometimes made in the site characterization process is failure to use technically sound available data to form working hypotheses on hydrogeology, contaminant distribution, etc. for initial testing. (3) After assembling and interpreting existing data for the site, the entire technical team visits the site to identify as a group the site characteristics that might prohibit or enhance any particular technological approach. Logistic and community constraints are also identified at this point. (4) After the field visit, the team selects a suite of technologies appropriate to the problem and completes the design of the field program. No one technique works well at all sites, and a suite of techniques is necessary to delineate site features fully. In addition, multiple technologies are employed to increase confidence in conclusions about site features. Noninvasive and minimally invasive technologies are emphasized to minimize risk to the environment, the community, and the staff. In no case is the traditional approach of installing a massive number of monitoring wells followed. A dynamic work plan that outlines the program is produced for the sponsoring and regulatory agencies. The word ''dynamic'' is emphasized because the work plan is viewed as a guide, subject to modification, for the site characterization activity, rather than a document that is absolute and unchangeable. Therefore, the health and safety plan and the quality assurance/quality control plan must be broad and encompass all possible alterations to the plan. The cooperation of the regulating agency is essential in successful implementation of this process. The sponsoring and regulatory agencies are notified if significant changes to the site-specific work plan are necessary. (5) The entire team participates in the technical field program. Several technical activities are undertaken simultaneously. These may range from different surface geophysics investigations to vegetation sampling. Data from the various activities are reduced and interpreted each day by the technical staff. Various computer programs are used to visualize and integrate the data. However, people do the data interpretation and integration, not the computers, which are just one more tool at the site. At the end of the day, the staff members meet, review results, and modify the next day's program as necessary to optimize activities that are generating overlapping or confirming site details. Data are not arbitrarily discarded -- each finding must be explained and understood. Anomalous readings may be due to equipment malfunctions, laboratory error, or the inability of a technique to work in a given setting. The suite of selected technologies is adjusted in the field if necessary. (6) The end result of this process is the optimization of the field activity to produce a high-quality technical product that is cost and time effective.« less