Novel Use of Ophthalmic pH Paper to Diagnose Malicious Caustic Ingestion in a Pediatric Patient

PubMed Central

Bruno, Eric C.

2018-01-01

Occult caustic ingestion in the pediatric population is a challenging diagnosis to make in the emergency department. Failure to suspect and diagnose a caustic ingestion can lead to potentially life-changing comorbidities. Historically, the diagnosis of caustic ingestion has been clinical without any suitable diagnostic tools to aid in the suspicion of occult cases. In this case, we describe a novel use of ophthalmic pH paper to diagnose caustic ingestion in a three-year-old.

Geometrical optics and optimal transport.

PubMed

Rubinstein, Jacob; Wolansky, Gershon

2017-10-01

The Fermat principle is generalized to a system of rays. It is shown that all the ray mappings that are compatible with two given intensities of a monochromatic wave, measured at two planes, are stationary points of a canonical functional, which is the weighted average of the actions of all the rays. It is further shown that there exist at least two stationary points for this functional, implying that in the geometrical optics regime the phase from intensity problem has inherently more than one solution. The caustic structures of all the possible ray mappings are analyzed. A number of simulations illustrate the theoretical considerations.

21 CFR 2.110 - Definition of ammonia under Federal Caustic Poison Act.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 21 Food and Drugs 1 2011-04-01 2011-04-01 false Definition of ammonia under Federal Caustic Poison... SERVICES GENERAL GENERAL ADMINISTRATIVE RULINGS AND DECISIONS Caustic Poisons § 2.110 Definition of ammonia under Federal Caustic Poison Act. For the purpose of determining whether an article containing ammonia...

21 CFR 2.110 - Definition of ammonia under Federal Caustic Poison Act.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 21 Food and Drugs 1 2013-04-01 2013-04-01 false Definition of ammonia under Federal Caustic Poison... SERVICES GENERAL GENERAL ADMINISTRATIVE RULINGS AND DECISIONS Caustic Poisons § 2.110 Definition of ammonia under Federal Caustic Poison Act. For the purpose of determining whether an article containing ammonia...

21 CFR 2.110 - Definition of ammonia under Federal Caustic Poison Act.

Code of Federal Regulations, 2012 CFR

2012-04-01

... 21 Food and Drugs 1 2012-04-01 2012-04-01 false Definition of ammonia under Federal Caustic Poison... SERVICES GENERAL GENERAL ADMINISTRATIVE RULINGS AND DECISIONS Caustic Poisons § 2.110 Definition of ammonia under Federal Caustic Poison Act. For the purpose of determining whether an article containing ammonia...

21 CFR 2.110 - Definition of ammonia under Federal Caustic Poison Act.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 21 Food and Drugs 1 2014-04-01 2014-04-01 false Definition of ammonia under Federal Caustic Poison... SERVICES GENERAL GENERAL ADMINISTRATIVE RULINGS AND DECISIONS Caustic Poisons § 2.110 Definition of ammonia under Federal Caustic Poison Act. For the purpose of determining whether an article containing ammonia...

21 CFR 2.110 - Definition of ammonia under Federal Caustic Poison Act.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 21 Food and Drugs 1 2010-04-01 2010-04-01 false Definition of ammonia under Federal Caustic Poison... SERVICES GENERAL GENERAL ADMINISTRATIVE RULINGS AND DECISIONS Caustic Poisons § 2.110 Definition of ammonia under Federal Caustic Poison Act. For the purpose of determining whether an article containing ammonia...

Mapping of bird distributions from point count surveys

USGS Publications Warehouse

Sauer, J.R.; Pendleton, G.W.; Orsillo, Sandra; Ralph, C.J.; Sauer, J.R.; Droege, S.

1995-01-01

Maps generated from bird survey data are used for a variety of scientific purposes, but little is known about their bias and precision. We review methods for preparing maps from point count data and appropriate sampling methods for maps based on point counts. Maps based on point counts can be affected by bias associated with incomplete counts, primarily due to changes in proportion counted as a function of observer or habitat differences. Large-scale surveys also generally suffer from regional and temporal variation in sampling intensity. A simulated surface is used to demonstrate sampling principles for maps.

Hazardous Waste Minimization Assessment: Fort Campbell, Kentucky

DTIC Science & Technology

1991-03-01

Used Oii - Better Operating Practices . Selective Segregation 97 Used Oil - Process Change - Fast Lube Oil Change System (FLOCS) 98 Caustic Wastes...Product Substitution 98 Caustic Wastes - Process Change - Hot Tank (Equipment) Modifications 98 Aqueous or Caustic Wastes - Process Change - Dry Ovens...Aqueous or Caustic Wastes - Equipment Leasiag 102 Dirty Rags/Uniforms • Onsite/Offsite Recycling - Laundry Service 103 Treatment 103 Used Oil - Onsite

Generation of Caustics and Rogue Waves from Nonlinear Instability.

PubMed

Safari, Akbar; Fickler, Robert; Padgett, Miles J; Boyd, Robert W

2017-11-17

Caustics are phenomena in which nature concentrates the energy of waves and may exhibit rogue-type behavior. Although they are known mostly in optics, caustics are intrinsic to all wave phenomena. As we demonstrate in this Letter, the formation of caustics and consequently rogue events in linear systems requires strong phase fluctuations. We show that nonlinear phase shifts can generate sharp caustics from even small fluctuations. Moreover, in that the wave amplitude increases dramatically in caustics, nonlinearity is usually inevitable. We perform an experiment in an optical system with Kerr nonlinearity, simulate the results based on the nonlinear Schrödinger equation, and achieve perfect agreement. As the same theoretical framework is used to describe other wave systems such as large-scale water waves, our results may also aid the understanding of ocean phenomena.

Generation of Caustics and Rogue Waves from Nonlinear Instability

NASA Astrophysics Data System (ADS)

Safari, Akbar; Fickler, Robert; Padgett, Miles J.; Boyd, Robert W.

2017-11-01

Caustics are phenomena in which nature concentrates the energy of waves and may exhibit rogue-type behavior. Although they are known mostly in optics, caustics are intrinsic to all wave phenomena. As we demonstrate in this Letter, the formation of caustics and consequently rogue events in linear systems requires strong phase fluctuations. We show that nonlinear phase shifts can generate sharp caustics from even small fluctuations. Moreover, in that the wave amplitude increases dramatically in caustics, nonlinearity is usually inevitable. We perform an experiment in an optical system with Kerr nonlinearity, simulate the results based on the nonlinear Schrödinger equation, and achieve perfect agreement. As the same theoretical framework is used to describe other wave systems such as large-scale water waves, our results may also aid the understanding of ocean phenomena.

Testing the Caustic Ring Dark Matter Halo Model Against Observations in the Milky Way

NASA Astrophysics Data System (ADS)

Dumas, Julie; Newberg, Heidi Jo; Niedzielski, Bethany; Susser, Adam; Thompson, Jeffery M.; Weiss, Jake; Lewis, Kim M.

2016-06-01

One prediction of axion dark matter models is they can form Bose-Einstein condensates and rigid caustic rings as a halo collapses in the non-linear regime. In this thesis, we undertake the first study of a caustic ring model for the Milky Way halo (Duffy & Sikivie 2008), paying particular attention to observational consequences. We first present the formalism for calculating the gravitational acceleration of a caustic ring halo. The caustic ring dark matter theory reproduces a roughly logarithmic halo, with large perturbations near the rings. We show that this halo can reasonably match the known Galactic rotation curve. We are not able to confirm or rule out an association between the positions of the caustic rings and oscillations in the observed rotation curve, due to insufficient rotation curve data. We explore the effects of dark matter caustic rings on dwarf galaxy tidal disruption with N-body simulations. Simulations of the Sagittarius (Sgr) dwarf galaxy in a caustic ring halo potential, with disk and bulge parameters that are tuned to match the Galactic rotation curve, match observations of the Sgr trailing tidal tails as far as 90 kpc from the Galactic center. Like the Navarro-Frenk-White (NFW) halo, they are, however, unable to match the leading tidal tail. None of the caustic, NFW, or triaxial logarithmic halos are able to simultaneously match observations of the leading and trailing arms of the Sagittarius stream. We further show that simulations of dwarf galaxies that move through caustic rings are qualitatively similar to those moving in a logarithmic halo. This research was funded by NSF grant AST 10-09670, the NASA-NY Space Grant, and the American Fellowship from AAUW.

A preliminary cost analysis of the biotreatment of refinery spent-sulfidic caustic.

PubMed

Sublette, K L

1997-01-01

Caustics are used in petroleum refining to remove hydrogen sulfide from various hydrocarbon streams. Spent-sulfidic caustics from three refineries have been successfully biotreated on the bench and pilot scale, resulting in neutralization and removal of active Sulfides. Sulfides were completely oxidized to sulfate by Thiobacillus denitrificans strain F. Microbial oxidation of sulfide produced acid, which at least partially neutralized the caustic. A commercial-scale treatment system has been designed that features a bioreactor with a suspended culture of flocculated T. denitrificans, a settler and acid and nutrient storage and delivery systems. A cost analysis has been performed for nine cases representing a range of spent caustic sulfide and hydroxide concentrations at a base treatment rate of 10 gpm. This analysis shows that refinery spent-sulfidic caustic can be biotreated for 4-8.3 cent/gal.

Structured caustic vector vortex optical field: manipulating optical angular momentum flux and polarization rotation.

PubMed

Chen, Rui-Pin; Chen, Zhaozhong; Chew, Khian-Hooi; Li, Pei-Gang; Yu, Zhongliang; Ding, Jianping; He, Sailing

2015-05-29

A caustic vector vortex optical field is experimentally generated and demonstrated by a caustic-based approach. The desired caustic with arbitrary acceleration trajectories, as well as the structured states of polarization (SoP) and vortex orders located in different positions in the field cross-section, is generated by imposing the corresponding spatial phase function in a vector vortex optical field. Our study reveals that different spin and orbital angular momentum flux distributions (including opposite directions) in different positions in the cross-section of a caustic vector vortex optical field can be dynamically managed during propagation by intentionally choosing the initial polarization and vortex topological charges, as a result of the modulation of the caustic phase. We find that the SoP in the field cross-section rotates during propagation due to the existence of the vortex. The unique structured feature of the caustic vector vortex optical field opens the possibility of multi-manipulation of optical angular momentum fluxes and SoP, leading to more complex manipulation of the optical field scenarios. Thus this approach further expands the functionality of an optical system.

68. INTERIOR VIEW LOOKING OF THE CAUSTIC SODA (SODIUM HYDROXIDE) ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

68. INTERIOR VIEW LOOKING OF THE CAUSTIC SODA (SODIUM HYDROXIDE) BUILDING, LOOKING AT CAUSTIC SODA MEASURING TANKS. (DATE UNKNOWN). - United States Nitrate Plant No. 2, Reservation Road, Muscle Shoals, Muscle Shoals, Colbert County, AL

Causticizing for Black Liquor Gasifiers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Scott Sinquefeld; James Cantrell; Xiaoyan Zeng

2009-01-07

The cost-benefit outlook of black liquor gasification (BLG) could be greatly improved if the smelt causticization step could be achieved in situ during the gasification step. Or, at a minimum, the increase in causticizing load associated with BLG could be mitigated. A number of chemistries have been proven successful during black liquor combustion. In this project, three in situ causticizing processes (titanate, manganate, and borate) were evaluated under conditions suitable for high temperature entrained flow BLG, and low temperature steam reforming of black liquor. The evaluation included both thermodynamic modeling and lab experimentation. Titanate and manganate were tested for completemore » direct causticizing (to thus eliminate the lime cycle), and borates were evaluated for partial causticizing (to mitigate the load increase associated with BLG). Criteria included high carbonate conversion, corresponding hydroxide recovery upon hydrolysis, non process element (NPE) removal, and economics. Of the six cases (three chemistries at two BLG conditions), only two were found to be industrially viable: titanates for complete causticizing during high temperature BLG, and borates for partial causticizing during high temperature BLG. These two cases were evaluated for integration into a gasification-based recovery island. The Larsen [28] BLG cost-benefit study was used as a reference case for economic forecasting (i.e. a 1500 tpd pulp mill using BLG and upgrading the lime cycle). By comparison, using the titanate direct causticizing process yielded a net present value (NPV) of $25M over the NPV of BLG with conventional lime cycle. Using the existing lime cycle plus borate autocausticizing for extra capacity yielded a NPV of $16M.« less

Evaluation and Management of Caustic Injuries from Ingestion of Acid or Alkaline Substances

PubMed Central

2014-01-01

Although the numbers have decreased compared with in the past, cases of patients who ingest caustic substances and visit the emergency room are not rare. However, well-summarized data about caustic injuries are insufficient. Therefore, in this article, I will discuss the etiologic causative agents, injury mechanism, and clinical characteristics, as well as the endoscopic evaluation of the degree of injury and proper management of the patient, in gastrointestinal caustic injury. PMID:25133115

Mid-Frequency Reverberation Measurements with Full Companion Environmental Support

DTIC Science & Technology

2014-12-30

it reaches a caustic . Beyond the caustic , it is only a saddle point [12]; there are distortions of the ray that give shorter travel times. Each of the...rays TBT, TB, and BT has at least one caustic . Thus, the argument must be modified. The following modified argument also uses Fermat’s prin- ciple...travel time decreased by about 1 ms. The presence of caustics invalidates a straightforward Fermat’s principle in- terpretation with a minimum travel

Optical caustics associated with the primary and the secondary rainbows of oblate droplets

NASA Astrophysics Data System (ADS)

Yu, Haitao; Shen, Jianqi; Tropea, Cameron

2014-08-01

The vector ray tracing (VRT) model is used to simulate the optical caustic structures near the primary and the secondary rainbow angles of oblate water droplets. The evolution process of the optical caustic structures in response to shape deformation of the water droplet is discussed. The dependence of the caustic structures on equatorial radius, refractive index and aspect ratio of the droplet are studied and the curvatures of the two rainbow fringes are calculated.

Dual behavior of caustic optical beams facing obstacles

NASA Astrophysics Data System (ADS)

Vaveliuk, Pablo; Martínez-Matos, Óscar; Ren, Yu-Xuan; Lu, Rong-De

2017-06-01

A full propagation analysis on both fold-type and cusp-type caustic optical beams under various setups of obstructions is theoretically and experimentally performed. It is demonstrated that the self-healing property of caustic optical beams that include the famous Airy beam is a quite relative property. In fact, fold-type and cusp-type beams cannot only behave as self-healing beams by blocking the main intensity peak, but also behave as self-breaking ones in a nonintuitive manner: by blocking a lateral side of the beam without touching the central intensity peak. The regeneration and rupture processes of caustic beams follow a nonlocal propagation dynamic unlike the other conventional beams. Moreover, deep differences between fold and cusp caustic beams are pointed out once facing certain obstructions. The cusp-caustic beam can be broken down by the obstacle placed in a dark zone outside the caustic region, while the fold-type one remains unaltered. This beam rupture confirms the key role of a hidden propagating field in the shadow region for cusp beams that coexist with the evanescent one. The obtained results cast down the established idea that the Airy beam is a robust self-healing beam since any caustic beam can behave in a dual manner depending on the obstruction location. These facts open up different perspectives for the applications in which the self-healing properties of the beam are relevant.

Caustics for spherical waves

DOE PAGES

de Rham, Claudia; Motohashi, Hayato

2017-03-07

We study the development of caustics in shift-symmetric scalar field theories by focusing on simple waves with an S O ( p ) -symmetry in an arbitrary number of space dimensions. We show that the pure Galileon, the DBI–Galileon, and the extreme-relativistic Galileon naturally emerge as the unique set of caustic-free theories, highlighting a link between the caustic-free condition for simple S O ( p ) -waves and the existence of either a global Galilean symmetry or a global (extreme-)relativistic Galilean symmetry.

Optical method of caustics applied in viscoelastic fracture analysis

NASA Astrophysics Data System (ADS)

Gao, Guiyun; Li, Zheng; Xu, Jie

2011-05-01

The optical method of caustics is developed here to study the fracture of viscoelastic materials. By adopting a distribution of viscoelastic stress fields near the crack tip, the method of caustics is used to determine the viscoelastic fracture parameters from the caustic patterns near the crack tip. Two viscoelastic materials are studied. These are PMMA and ternary composites of HDPE/POE-g-MA/CaCO 3. The transmitted and reflective methods of caustics are performed separately to investigate viscoelastic fracture behaviors. The stress intensity factors (SIFs) versus time is determined by a series of shadow spot patterns combined with viscoelastic parameters evaluated by creep tests. In order to understand the viscoelastic fracture mechanisms of HDPE/POE-g-MA/CaCO 3 composites, their fracture surfaces are observed by a Scanning Electron Microscope (SEM). The results indicate that the method of caustics can be used to characterize the fracture behaviors of viscoelastic materials and further to optimize the design of polymer composites.

Analysis of sonic boom measurements near shock wave extremities for flight near Mach 1.0 and for airplane accelerations

NASA Technical Reports Server (NTRS)

Haglund, G. T.; Kane, E. J.

1974-01-01

The analysis of the 14 low-altitude transonic flights showed that the prevailing meteorological consideration of the acoustic disturbances below the cutoff altitude during threshold Mach number flight has shown that a theoretical safe altitude appears to be valid over a wide range of meteorological conditions and provides a reasonable estimate of the airplane ground speed reduction to avoid sonic boom noise during threshold Mach number flight. Recent theoretical results for the acoustic pressure waves below the threshold Mach number caustic showed excellent agreement with observations near the caustic, but the predicted overpressure levels were significantly lower than those observed far from the caustic. The analysis of caustics produced by inadvertent low-magnitude accelerations during flight at Mach numbers slightly greater than the threshold Mach number showed that folds and associated caustics were produced by slight changes in the airplane ground speed. These caustic intensities ranged from 1 to 3 time the nominal steady, level flight intensity.

Underwater Rays

ERIC Educational Resources Information Center

Cepic, Mojca

2008-01-01

Light beams in wavy unclear water, also called underwater rays, and caustic networks of light formed at the bottom of shallow water are two faces of a single phenomenon. Derivation of the caustic using only simple geometry, Snell's law and simple derivatives accounts for observations such as the existence of the caustic network on vertical walls,…

21 CFR 1230.43 - Enforcement.

Code of Federal Regulations, 2011 CFR

2011-04-01

... CAUSTIC POISON ACT Imports § 1230.43 Enforcement. (a) Enforcement agency. The Federal Caustic Poison Act...) Enforcement of provisions. The enforcement of the provisions of the Federal Caustic Poison Act as they relate... Poison Act. (c) Chief of district as customs officer. The chief of district shall be deemed a customs...

21 CFR 1230.43 - Enforcement.

Code of Federal Regulations, 2014 CFR

2014-04-01

... CAUSTIC POISON ACT Imports § 1230.43 Enforcement. (a) Enforcement agency. The Federal Caustic Poison Act...) Enforcement of provisions. The enforcement of the provisions of the Federal Caustic Poison Act as they relate... Poison Act. (c) Chief of district as customs officer. The chief of district shall be deemed a customs...

21 CFR 1230.21 - Specific guaranty.

Code of Federal Regulations, 2012 CFR

2012-04-01

... FEDERAL CAUSTIC POISON ACT Guaranty § 1230.21 Specific guaranty. If a guaranty in respect to any specific... Caustic Poison Act. (Signature and address of guarantor) (b) Substances for other than household use (this... be misbranded within the meaning of the Federal Caustic Poison Act. (Name and address of manufacturer...

21 CFR 1230.21 - Specific guaranty.

Code of Federal Regulations, 2014 CFR

2014-04-01

... FEDERAL CAUSTIC POISON ACT Guaranty § 1230.21 Specific guaranty. If a guaranty in respect to any specific... Caustic Poison Act. (Signature and address of guarantor) (b) Substances for other than household use (this... be misbranded within the meaning of the Federal Caustic Poison Act. (Name and address of manufacturer...

21 CFR 1230.21 - Specific guaranty.

Code of Federal Regulations, 2010 CFR

2010-04-01

... FEDERAL CAUSTIC POISON ACT Guaranty § 1230.21 Specific guaranty. If a guaranty in respect to any specific... Caustic Poison Act. (Signature and address of guarantor) (b) Substances for other than household use (this... be misbranded within the meaning of the Federal Caustic Poison Act. (Name and address of manufacturer...

21 CFR 1230.43 - Enforcement.

Code of Federal Regulations, 2013 CFR

2013-04-01

... CAUSTIC POISON ACT Imports § 1230.43 Enforcement. (a) Enforcement agency. The Federal Caustic Poison Act...) Enforcement of provisions. The enforcement of the provisions of the Federal Caustic Poison Act as they relate... Poison Act. (c) Chief of district as customs officer. The chief of district shall be deemed a customs...

21 CFR 1230.21 - Specific guaranty.

Code of Federal Regulations, 2013 CFR

2013-04-01

... FEDERAL CAUSTIC POISON ACT Guaranty § 1230.21 Specific guaranty. If a guaranty in respect to any specific... Caustic Poison Act. (Signature and address of guarantor) (b) Substances for other than household use (this... be misbranded within the meaning of the Federal Caustic Poison Act. (Name and address of manufacturer...

21 CFR 1230.21 - Specific guaranty.

Code of Federal Regulations, 2011 CFR

2011-04-01

... FEDERAL CAUSTIC POISON ACT Guaranty § 1230.21 Specific guaranty. If a guaranty in respect to any specific... Caustic Poison Act. (Signature and address of guarantor) (b) Substances for other than household use (this... be misbranded within the meaning of the Federal Caustic Poison Act. (Name and address of manufacturer...

21 CFR 1230.43 - Enforcement.

Code of Federal Regulations, 2012 CFR

2012-04-01

... CAUSTIC POISON ACT Imports § 1230.43 Enforcement. (a) Enforcement agency. The Federal Caustic Poison Act...) Enforcement of provisions. The enforcement of the provisions of the Federal Caustic Poison Act as they relate... Poison Act. (c) Chief of district as customs officer. The chief of district shall be deemed a customs...

21 CFR 1230.43 - Enforcement.

Code of Federal Regulations, 2010 CFR

2010-04-01

... CAUSTIC POISON ACT Imports § 1230.43 Enforcement. (a) Enforcement agency. The Federal Caustic Poison Act...) Enforcement of provisions. The enforcement of the provisions of the Federal Caustic Poison Act as they relate... Poison Act. (c) Chief of district as customs officer. The chief of district shall be deemed a customs...

The internal caustic structure of illuminated liquid droplets

NASA Technical Reports Server (NTRS)

Lock, James A.; Hovenac, Edward A.

1991-01-01

The internal electric field of an illuminated liquid droplet is studied in detail using both wave theory and ray theory. The internal field obtains its maximum values on the caustics within the droplet. Ray theory is used to determine the equations of these caustics and the density of rays on them. The Debye series expansion of the interior field Mie amplitudes is used to calculate the wave theory version of these caustics. The physical interpretation of the sources of stimulated Raman scattering and fluorescence emission within a liquid droplet is then given.

46 CFR Appendix I to Part 150 - Exceptions to the Chart

Code of Federal Regulations, 2013 CFR

2013-10-01

...). Triethylenetetramine (7). Sodium cresylate as Cresylate spent caustic (5) Methyl alcohol (20). Sodium dichromate, 70... (0) N-Methyl-2-pyrrolidone (9) Caustic potash, 50% or less (5) Isobutyl alcohol (20)Ethyl alcohol (20) Ethylene glycol (20) Isopropyl alcohol (20) Methyl alcohol (20) iso-Octyl alcohol (20) Caustic soda, 50% or...

46 CFR Appendix I to Part 150 - Exceptions to the Chart

Code of Federal Regulations, 2014 CFR

2014-10-01

...). Triethylenetetramine (7). Sodium cresylate as Cresylate spent caustic (5) Methyl alcohol (20). Sodium dichromate, 70...-pyrrolidone (9) Caustic potash, 50% or less (5) Isobutyl alcohol (20)Ethyl alcohol (20) Ethylene glycol (20) Isopropyl alcohol (20) Methyl alcohol (20) iso-Octyl alcohol (20) Caustic soda, 50% or less (5) Butyl...

16 CFR 1500.129 - Substances named in the Federal Caustic Poison Act.

Code of Federal Regulations, 2014 CFR

2014-01-01

... Poison Act. 1500.129 Section 1500.129 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FEDERAL... REGULATIONS § 1500.129 Substances named in the Federal Caustic Poison Act. The Commission finds that for those substances covered by the Federal Caustic Poison Act (44 Stat. 1406), the requirements of section 2(p)(1) of...

16 CFR 1500.129 - Substances named in the Federal Caustic Poison Act.

Code of Federal Regulations, 2011 CFR

2011-01-01

... Poison Act. 1500.129 Section 1500.129 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FEDERAL... REGULATIONS § 1500.129 Substances named in the Federal Caustic Poison Act. The Commission finds that for those substances covered by the Federal Caustic Poison Act (44 Stat. 1406), the requirements of section 2(p)(1) of...

16 CFR 1500.129 - Substances named in the Federal Caustic Poison Act.

Code of Federal Regulations, 2012 CFR

2012-01-01

... Poison Act. 1500.129 Section 1500.129 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FEDERAL... REGULATIONS § 1500.129 Substances named in the Federal Caustic Poison Act. The Commission finds that for those substances covered by the Federal Caustic Poison Act (44 Stat. 1406), the requirements of section 2(p)(1) of...

16 CFR § 1500.129 - Substances named in the Federal Caustic Poison Act.

Code of Federal Regulations, 2013 CFR

2013-01-01

... Poison Act. § 1500.129 Section § 1500.129 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION... ENFORCEMENT REGULATIONS § 1500.129 Substances named in the Federal Caustic Poison Act. The Commission finds that for those substances covered by the Federal Caustic Poison Act (44 Stat. 1406), the requirements...

PEP Support: Laboratory Scale Leaching and Permeate Stability Tests

DOE Office of Scientific and Technical Information (OSTI.GOV)

Russell, Renee L.; Peterson, Reid A.; Rinehart, Donald E.

2010-05-21

This report documents results from a variety of activities requested by the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The activities related to caustic leaching, oxidative leaching, permeate precipitation behavior of waste as well as chromium (Cr) leaching are: • Model Input Boehmite Leaching Tests • Pretreatment Engineering Platform (PEP) Support Leaching Tests • PEP Parallel Leaching Tests • Precipitation Study Results • Cr Caustic and Oxidative Leaching Tests. Leaching test activities using the PEP simulant provided input to a boehmite dissolution model and determined the effect of temperature on mass loss during caustic leaching, the reaction rate constantmore » for the boehmite dissolution, and the effect of aeration in enhancing the chromium dissolution during caustic leaching. Other tests were performed in parallel with the PEP tests to support the development of scaling factors for caustic and oxidative leaching. Another study determined if precipitate formed in the wash solution after the caustic leach in the PEP. Finally, the leaching characteristics of different chromium compounds under different conditions were examined to determine the best one to use in further testing.« less

Microbial oxidation of mixtures of methylmercaptan and hydrogen sulfide.

PubMed

Subramaniyan, A; Kolhatkar, R; Sublette, K L; Beitle, R

1998-01-01

Refinery spent-sulfidic caustic, containing only inorganic sulfides, has previously been shown to be amenable to biotreatment with Thiobacillus denitrificans strain F with complete oxidation of sulfides to sulfate. However, many spent caustics contain mercaptans that cannot be metabolized by this strict autotroph. An aerobic enrichment culture was developed from mixed Thiobacilli and activated sludge that was capable of simultaneous oxidation of inorganic sulfide and mercaptans using hydrogen sulfide (H2S) and methylmercaptan (MeSH) gas feeds used to simulate the inorganic and organic sulfur of a spent-sulfidic caustic. The enrichment culture was also capable of biotreatment of an actual mercaptan-containing, spent-sulfidic caustic but at lower rates than predicted by operation on MeSH and H2S fed to the culture in the gas phase, indicating that the caustic contained other inhibitory components.

New astrophysical bounds on ultralight axionlike particles

DOE PAGES

Banik, Nilanjan; Christopherson, Adam J.; Sikivie, Pierre; ...

2017-02-15

Motivated by tension between the predictions of ordinary cold dark matter (CDM) and observations at galactic scales, ultralight axionlike particles (ULALPs) with mass of the order 10 -22 eV have been proposed as an alternative CDM candidate. We consider cold and collisionless ULALPs produced in the early Universe by the vacuum realignment mechanism and constituting most of CDM. The ULALP fluid is commonly described by classical field equations. However, we show that, like QCD axions, the ULALPs thermalize by gravitational self-interactions and form a Bose-Einstein condensate, a quantum phenomenon. ULALPs, like QCD axions, explain the observational evidence for caustic ringsmore » of dark matter because they thermalize and go to the lowest energy state available to them. This is one of rigid rotation on the turnaround sphere. Here, by studying the heating effect of infalling ULALPs on galactic disk stars and the thickness of the nearby caustic ring as observed from a triangular feature in the infrared astronomical satellite map of our galactic disk, we obtain lower-mass bounds on the ULALP mass of order 10 -23 and 10 -20 eV, respectively.« less

Hydrogen peroxide and caustic soda: Dancing with a dragon while bleaching

Treesearch

Peter W. Hart; Carl Houtman; Kolby Hirth

2013-01-01

When hydrogen peroxide is mixed with caustic soda, an auto-accelerating reaction can lead to generation of significant amounts of heat and oxygen. On the basis of experiments using typical pulp mill process concentration and temperatures, a relatively simple kinetic model has been developed. Evaluation of these model results reveals that hydrogen peroxide-caustic soda...

16 CFR 1500.129 - Substances named in the Federal Caustic Poison Act.

Code of Federal Regulations, 2010 CFR

2010-01-01

... Commission therefore finds that for the following substances, and at the following concentrations, the word... REGULATIONS § 1500.129 Substances named in the Federal Caustic Poison Act. The Commission finds that for those... Caustic Poison Act, were required to bear the signal word “poison.” The Commission concludes that the lack...

Evaluating point count efficiency relative to territory mapping in cropland birds

Treesearch

Andre Cyr; Denis Lepage; Kathryn Freemark

1995-01-01

Species richness, composition, and abundance of farmland birds were compared between point counts (50-m, 100-m, and 150-m radius half circles) and territory mapping on three 40-ha plots in Québec, Canada. Point counts of smaller radii tended to have larger density estimates than counts of larger radii. Territory mapping detected 10 species more than 150-m...

OGLE-2016-BLG-1003: First Resolved Caustic-crossing Binary-source Event Discovered by Second-generation Microlensing Surveys

NASA Astrophysics Data System (ADS)

Jung, Y. K.; Udalski, A.; Bond, I. A.; Yee, J. C.; Gould, A.; Han, C.; Albrow, M. D.; Lee, C.-U.; Kim, S.-L.; Hwang, K.-H.; Chung, S.-J.; Ryu, Y.-H.; Shin, I.-G.; Zhu, W.; Cha, S.-M.; Kim, D.-J.; Lee, Y.; Park, B.-G.; Kim, H.-W.; Pogge, R. W.; KMTNet Collaboration; Skowron, J.; Szymański, M. K.; Poleski, R.; Mróz, P.; Kozłowski, S.; Pietrukowicz, P.; Soszyński, I.; Ulaczyk, K.; Pawlak, M.; OGLE Collaboration; Abe, F.; Bennett, D. P.; Barry, R.; Sumi, T.; Asakura, Y.; Bhattacharya, A.; Donachie, M.; Fukui, A.; Hirao, Y.; Itow, Y.; Koshimoto, N.; Li, M. C. A.; Ling, C. H.; Masuda, K.; Matsubara, Y.; Muraki, Y.; Nagakane, M.; Rattenbury, N. J.; Evans, P.; Sharan, A.; Sullivan, D. J.; Suzuki, D.; Tristram, P. J.; Yamada, T.; Yamada, T.; Yonehara, A.; MOA Collaboration

2017-06-01

We report the analysis of the first resolved caustic-crossing binary-source microlensing event OGLE-2016-BLG-1003. The event is densely covered by round-the-clock observations of three surveys. The light curve is characterized by two nested caustic-crossing features, which is unusual for typical caustic-crossing perturbations. From the modeling of the light curve, we find that the anomaly is produced by a binary source passing over a caustic formed by a binary lens. The result proves the importance of high-cadence and continuous observations, and the capability of second-generation microlensing experiments to identify such complex perturbations that are previously unknown. However, the result also raises the issues of the limitations of current analysis techniques for understanding lens systems beyond two masses and of determining the appropriate multiband observing strategy of survey experiments.

Chemical Discovery as Belief Revision.

DTIC Science & Technology

1986-09-30

in order to explain conflicting experimental results. For example, Gay- Lussac and Thenard claimed that potassium con- sisted of caustic-potash and...hydrogen, while Davy observed that caustic-potash decomposed into potassium and oxygen. To support their view, Gay- Lussac and Thenard proposed that...Potash and Potassium We touched earlier on the disagreement between Davy and fellow chemists Gay- Lussac and Thenard concerning caustic-potash and

Test Results for Caustic Demand Measurements on Tank 241-AX-101 and Tank 241-AX-103 Archive Samples

DOE Office of Scientific and Technical Information (OSTI.GOV)

Doll, Stephanie R.; Bolling, Stacie D.

Caustic demand testing is used to determine the necessary amount of caustic required to neutralize species present in the Hanford tank waste and obtain a target molarity of free hydroxide for tank corrosion control. The presence and quantity of hydroxide-consuming analytes are just as important in determining the caustic demand as is the amount of free hydroxide present. No single data point can accurately predict whether a satisfactory hydroxide level is being met, as it is dependent on multiple factors (e.g., free hydroxide, buffers, amphoteric metal hydroxides, bicarbonate, etc.). This enclosure contains the caustic demand, scanning electron microscopy (SEM), polarizedmore » light microscopy (PLM), and X-ray diffraction (XRD) analysis for the tank 241-AX-101 (AX-101) and 241-AX-103 (AX-103) samples. The work was completed to fulfill a customer request outlined in the test plan, WRPS-1505529, “Test Plan and Procedure for Caustic Demand Testing on Tank 241-AX-101 and Tank 241-AX-103 Archive Samples.” The work results will provide a baseline to support planned retrieval of AX-101 and AX-103.« less

Caustic stress corrosion cracking of alloys 600 and 690 with NaOH concentrations

NASA Astrophysics Data System (ADS)

Park, In-Gyu; Lee, Chang-Soon; Hwang, Seong-Sik; Kim, Hong-Pyo; Kim, Joung-Soo

2005-10-01

In order to evaluate the stress corrosion cracking resistance for commercial alloys (C600MA, C600TT, C690TT) and Korean-made alloys (K600MA, K690TT), C-ring tests were performed in a caustic environment of 4, 10, 20, 30, and 50% NaOH solution at 315°C, for 480 h with an applied potential of 125 mV vs. OCP. Different stress corrosion cracking phenomena were observed according to the NaOH concentration. The rate of caustic IGSCC attack did not appear to increase monotonically with caustic concentrations, but peaked at a concentration between 4 and 50% caustic, or approximately 30% NaOH. Intergranular stress corrosion cracking was found for C600MA in 10, 20, and 30% NaOH solutions, while no cracking was observed in the 4 and 50% NaOH solutions. In 30% NaOH solution, transgrnular stress corrosion cracking was detected in C690TT, which may be related with the large amount of plastic strain (150% yield) and the applied potential (125 mV vs. OCP). The overall data clearly indicate that C600MA has the worst SCC resistance while K690TT offers the best resistance. There is also fairly good correlation between the caustic SCC susceptibility and some metallurgical parameters, particularly the grain size and the yield strength at room temperature. Specifically, materials having larger grain size and lower yield strength exhibited higher caustic SCC resistance.

Microlensing of Extremely Magnified Stars near Caustics of Galaxy Clusters

NASA Astrophysics Data System (ADS)

Venumadhav, Tejaswi; Dai, Liang; Miralda-Escudé, Jordi

2017-11-01

Recent observations of lensed galaxies at cosmological distances have detected individual stars that are extremely magnified when crossing the caustics of lensing clusters. In idealized cluster lenses with smooth mass distributions, two images of a star of radius R approaching a caustic brighten as {t}-1/2 and reach a peak magnification ˜ {10}6{(10{R}⊙ /R)}1/2 before merging on the critical curve. We show that a mass fraction ({κ }\\star ≳ {10}-4.5) in microlenses inevitably disrupts the smooth caustic into a network of corrugated microcaustics and produces light curves with numerous peaks. Using analytical calculations and numerical simulations, we derive the characteristic width of the network, caustic-crossing frequencies, and peak magnifications. For the lens parameters of a recent detection and a population of intracluster stars with {κ }\\star ˜ 0.01, we find a source-plane width of ˜ 20 {pc} for the caustic network, which spans 0.2 {arcsec} on the image plane. A source star takes ˜ 2× {10}4 years to cross this width, with a total of ˜ 6× {10}4 crossings, each one lasting for ˜ 5 {hr} (R/10 {R}⊙ ) with typical peak magnifications of ˜ {10}4 {(R/10{R}⊙ )}-1/2. The exquisite sensitivity of caustic-crossing events to the granularity of the lens-mass distribution makes them ideal probes of dark matter components, such as compact halo objects and ultralight axion dark matter.

Polymer Claw: Instant Underwater Adhesive

DTIC Science & Technology

2012-03-23

technology is the use of pressure sensitive microcapsules , which release reactive amine crosslinkers into an adhesive putty when pressed against the...PROIECT GOALS AND OBIECTIVES 2 2 KEY ACCOMPLISHMENTS 2 3.1 KICKOFF MEETING 3 3.2 AMINE MICROENCAPSULATION 3 3.3 CAUSTIC CLEANING AGENT 5 3.4...caustic, and the abrasive brush. We successfully synthesized amine-filled microcapsules and a dry mixture of caustic ingredients that only activate when

The point-characteristic function, wavefronts, and caustic of a spherical wave refracted by an arbitrary smooth surface.

PubMed

Marciano-Melchor, Magdalena; Navarro-Morales, Esperanza; Román-Hernández, Edwin; Santiago-Santiago, José Guadalupe; Silva-Ortigoza, Gilberto; Silva-Ortigoza, Ramón; Suárez-Xique, Román

2012-06-01

The aim of this paper is to obtain expressions for the k-function, the wavefront train, and the caustic associated with the light rays refracted by an arbitrary smooth surface after being emitted by a point light source located at an arbitrary position in a three-dimensional homogeneous optical medium. The general results are applied to a parabolic refracting surface. For this case, we find that when the point light source is off the optical axis, the caustic locally has singularities of the hyperbolic umbilic type, while the refracted wavefront, at the caustic region, locally has singularities of the cusp ridge and swallowtail types.

46 CFR Table 151.05 to Subpart 151... - Summary of Minimum Requirements

Code of Federal Regulations, 2011 CFR

2011-10-01

...% or more Phenol, see Phenol Cresylate spent caustic Atmos. Amb. III 1 i i 2 i Integral Gravity Open... spent caustic Crotonaldehyde Atmos. Amb. II 1 i i 2 i i Integral Gravity PV Restr. II G-1 NR Vent F Yes.... II G-2 NR Vent N Yes .50-73 NA NA G Caustic potash solution Atmos. Amb.Elev. III 1 i 2 i Integral...

46 CFR Table 151.05 to Subpart 151... - Summary of Minimum Requirements

Code of Federal Regulations, 2014 CFR

2014-10-01

...% or more Phenol, see Phenol Cresylate spent caustic Atmos. Amb. III 1 i i 2 i Integral Gravity Open... spent caustic Crotonaldehyde Atmos. Amb. II 1 i i 2 i i Integral Gravity PV Restr. II G-1 NR Vent F Yes.... II G-2 NR Vent N Yes .50-73 NA NA G Caustic potash solution Atmos. Amb.Elev. III 1 i 2 i Integral...

46 CFR Table 151.05 to Subpart 151... - Summary of Minimum Requirements

Code of Federal Regulations, 2013 CFR

2013-10-01

...% or more Phenol, see Phenol Cresylate spent caustic Atmos. Amb. III 1 i i 2 i Integral Gravity Open... spent caustic Crotonaldehyde Atmos. Amb. II 1 i i 2 i i Integral Gravity PV Restr. II G-1 NR Vent F Yes.... II G-2 NR Vent N Yes .50-73 NA NA G Caustic potash solution Atmos. Amb.Elev. III 1 i 2 i Integral...

46 CFR Table 151.05 to Subpart 151... - Summary of Minimum Requirements

Code of Federal Regulations, 2010 CFR

2010-10-01

..., see Phenol Cresylate spent caustic Atmos. Amb. III 1 i i 2 i Integral Gravity Open Open II G-1 NR Vent N No .50-73.55-1(b) NA NA G Cresylic acid, sodium salt solution, see Cresylate spent caustic.... II G-2 NR Vent N Yes .50-73 NA NA G Caustic potash solution Atmos. Amb.Elev. III 1 i 2 i Integral...

46 CFR Table 151.05 to Subpart 151... - Summary of Minimum Requirements

Code of Federal Regulations, 2012 CFR

2012-10-01

...% or more Phenol, see Phenol Cresylate spent caustic Atmos. Amb. III 1 i i 2 i Integral Gravity Open... spent caustic Crotonaldehyde Atmos. Amb. II 1 i i 2 i i Integral Gravity PV Restr. II G-1 NR Vent F Yes... G-2 NR Vent N Yes .50-73 NA NA G Caustic potash solution Atmos. Amb.Elev. III 1 i 2 i Integral...

Protective effects of dexpanthenol and y-27632 on stricture formation in a rat model of caustic esophageal injury.

PubMed

Ceylan, Haluk; Yapici, Sefa; Tutar, Ediz; Ceylan, Nurdan Ozlu; Tarakçıoğlu, Mehmet; Demiryurek, A Tuncay

2011-12-01

This experimental study was conducted to investigate the effect of dexpanthenol (converted in the body to pantothenic acid) and Y-27632 (a selective Rho-kinase inhibitor) on stricture formation after caustic (alkaline) esophageal injury in rats. Sixty male Wistar albino rats were randomly allocated into six groups. In group 1 (sham) the distal esophagus was isolated and cannulated but no caustic injury was induced. In all remaining groups, a caustic esophageal burn was induced with 50% sodium hydroxide solution for 90 s and drug treatment was given by daily intraperitoneal injection, beginning 24 h after injury and continuing for 21 d. In group 2 (controls), animals were treated with 0.9% saline; in groups 3 and 4, with 50 and 500 mg/kg/d of dexpanthenol, respectively; and in groups 5 and 6, with 0.3 and 3 mg/kg/d of Y-27632, respectively. Rats were sacrificed 22 d after caustic injury and the distal esophagus was isolated for histopathology and biochemical investigation. Stenosis index and collagen deposition scores were significantly lower in both the dexpanthenol and Y-27632 treated groups (P<0.05). Dexpanthenol and Y-27632 treatment markedly depressed esophageal tissue malondialdehyde and hydroxyproline levels. In this experimental model of caustic esophageal stricture, dexpanthenol and Y-27632 significantly attenuated esophageal stricture formation. These findings indicate that inhibition of Rho-kinase or dexpanthenol administration may offer novel therapeutic approaches in the treatment of caustic esophageal injury. Copyright © 2011 Elsevier Inc. All rights reserved.

A PLANETARY LENSING FEATURE IN CAUSTIC-CROSSING HIGH-MAGNIFICATION MICROLENSING EVENTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chung, Sun-Ju; Hwang, Kyu-Ha; Ryu, Yoon-Hyun

Current microlensing follow-up observations focus on high-magnification events because of the high efficiency of planet detection. However, central perturbations of high-magnification events caused by a planet can also be produced by a very close or a very wide binary companion, and the two kinds of central perturbations are not generally distinguished without time consuming detailed modeling (a planet-binary degeneracy). Hence, it is important to resolve the planet-binary degeneracy that occurs in high-magnification events. In this paper, we investigate caustic-crossing high-magnification events caused by a planet and a wide binary companion. From this investigation, we find that because of the differentmore » magnification excess patterns inside the central caustics induced by the planet and the binary companion, the light curves of the caustic-crossing planetary-lensing events exhibit a feature that is discriminated from those of the caustic-crossing binary-lensing events, and the feature can be used to immediately distinguish between the planetary and binary companions. The planetary-lensing feature appears in the interpeak region between the two peaks of the caustic-crossings. The structure of the interpeak region for the planetary-lensing events is smooth and convex or boxy, whereas the structure for the binary-lensing events is smooth and concave. We also investigate the effect of a finite background source star on the planetary-lensing feature in the caustic-crossing high-magnification events. From this, we find that the convex-shaped interpeak structure appears in a certain range that changes with the mass ratio of the planet to the planet-hosting star.« less

Oil refinery hazardous effluents minimization by membrane filtration: An on-site pilot plant study.

PubMed

Santos, Bruno; Crespo, João G; Santos, Maria António; Velizarov, Svetlozar

2016-10-01

Experiments for treating two different types of hazardous oil refinery effluents were performed in order to avoid/minimize their adverse impacts on the environment. First, refinery wastewater was subjected to ultrafiltration using a ceramic membrane, treatment, which did not provide an adequate reduction of the polar oil and grease content below the maximal contaminant level allowed. Therefore the option of reducing the polar oil and grease contamination at its main emission source point in the refinery - the spent caustic originating from the refinery kerosene caustic washing unit - using an alkaline-resistant nanofiltration polymeric membrane treatment was tested. It was found that at a constant operating pressure and temperature, 99.9% of the oil and grease and 97.7% of the COD content were rejected at this emission point. Moreover, no noticeable membrane fouling or permeate flux decrease were registered until a spent caustic volume concentration factor of 3. These results allow for a reuse of the purified permeate in the refinery operations, instead of a fresh caustic solution, which besides the improved safety and environmentally related benefits, can result in significant savings of 1.5 M€ per year at the current prices for the biggest Portuguese oil refinery. The capital investment needed for nanofiltration treatment of the spent caustic is estimated to be less than 10% of that associated with the conventional wet air oxidation treatment of the spent caustic that is greater than 9 M€. The payback period was estimated to be 1.1 years. The operating costs for the two treatment options are similar, but the reuse of the nanofiltration spent caustic concentrate for refinery pH control applications can further reduce the operating expenditures. Overall, the pilot plant results obtained and the process economics evaluation data indicate a safer, environmentally friendly and highly competitive solution offered by the proposed nanofiltration treatment, thus representing a promising alternative to the use of conventional spent caustic treatment units. Copyright © 2016 Elsevier Ltd. All rights reserved.

Extinction map of Chamaeleon I molecular cloud with DENIS star counts.

NASA Astrophysics Data System (ADS)

Cambresy, L.; Epchtein, N.; Copet, E.; de Batz, B.; Kimeswenger, S.; Le Bertre, T.; Rouan, D.; Tiphene, D.

1997-08-01

Massive, large scale star counts in the J (1.25μm) band provided by the Deep Near Infrared Survey of the Southern Sky (DENIS) are used for the first time to draw out an extinction map of the Chamaeleon I dark cloud. We derived a 2' resolution map of the cloud from J star counts within an area of 1.5°x3° around the centre of the cloud using an adaptive grid method and applying a wavelet decomposition. Possible contaminating young stellar objects within the cloud are removed, although they are shown to have a negligible effect on the counts. A comparison of our extinction map with the cold contribution of the IRAS 100μm emission shows an almost perfect matching. It is shown that J star counts supersede optical counts on Schmidt plate where A_V_>4.

Extreme Wave Statistics within the Mouth of the Columbia River

DTIC Science & Technology

2014-12-01

nearshore coastal environment. Because of his guidance, I was able to make the most of this challenging learning experience. I spent countless hours...the current field induces a refractive caustic along the principal current axis. Caustic focusing causes an increase of wave height to its maximum...the largest waves are found upstream of the caustic area (around x/Lo=25 in Figure 6). 10 Figure 6. Transformation of 0.1-Hz swell

Hazardous Waste Minimization Guide for Shipyards

DTIC Science & Technology

1994-01-01

any waste generation associated with spent sol- vent. Elimination can be achieved by utiliza- tion of non-solvent cleaning agents or elimi- nating the...alkali, citric, and caustic base, are often useful substitutes for solvents. There are many for- mulations that are suited for a variety of clean- ing...agents, such as caustic soda (NaOH), are often employed in place of meth- ylene chloride based strippers. Caustic solu- tions have the advantage of

A matrix-inversion method for gamma-source mapping from gamma-count data

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adsley, Ian; Burgess, Claire; Bull, Richard K

In a previous paper it was proposed that a simple matrix inversion method could be used to extract source distributions from gamma-count maps, using simple models to calculate the response matrix. The method was tested using numerically generated count maps. In the present work a 100 kBq Co{sup 60} source has been placed on a gridded surface and the count rate measured using a NaI scintillation detector. The resulting map of gamma counts was used as input to the matrix inversion procedure and the source position recovered. A multi-source array was simulated by superposition of several single-source count maps andmore » the source distribution was again recovered using matrix inversion. The measurements were performed for several detector heights. The effects of uncertainties in source-detector distances on the matrix inversion method are also examined. The results from this work give confidence in the application of the method to practical applications, such as the segregation of highly active objects amongst fuel-element debris. (authors)« less

Diffraction and Dissipation of Atmospheric Waves in the Vicinity of Caustics

NASA Astrophysics Data System (ADS)

Godin, O. A.

2015-12-01

A large and increasing number of ground-based and satellite-borne instruments has been demonstrated to reliably reveal ionospheric manifestations of natural hazards such as large earthquakes, strong tsunamis, and powerful tornadoes. To transition from detection of ionospheric manifestations of natural hazards to characterization of the hazards for the purposes of improving early warning systems and contributing to disaster recovery, it is necessary to relate quantitatively characteristics of the observed ionospheric disturbances and the underlying natural hazard and, in particular, accurately model propagation of atmospheric waves from the ground or ocean surface to the ionosphere. The ray theory has been used extensively to model propagation of atmospheric waves and proved to be very efficient in elucidating the effects of atmospheric variability on ionospheric signatures of natural hazards. However, the ray theory predicts unphysical, divergent values of the wave amplitude and needs to be modified in the vicinity of caustics. This paper presents an asymptotic theory that describes diffraction, focusing and increased dissipation of acoustic-gravity waves in the vicinity of caustics and turning points. Air temperature, viscosity, thermal conductivity, and wind velocity are assumed to vary gradually with height and horizontal coordinates, and slowness of these variations determines the large parameter of the problem. Uniform asymptotics of the wave field are expressed in terms of Airy functions and their derivatives. The geometrical, or Berry, phase, which arises in the consistent WKB approximation for acoustic-gravity waves, plays an important role in the caustic asymptotics. In addition to the wave field in the vicinity of the caustic, these asymptotics describe wave reflection from the caustic and the evanescent wave field beyond the caustic. The evanescent wave field is found to play an important role in ionospheric manifestations of tsunamis.

Archeological Survey and Testing Along Boone Creek, Louisiana Army Ammunition Plant, Webster Parish, Louisiana

DTIC Science & Technology

1989-01-01

ducks, partridges, cranes , quail, snakes, and fish. 8 CHAPTER 2: ENVIRONMENTAL SETTING Climate The modern climate of the project area is classified as... caustic materials. Large openings in their sides were cut by oil field workers, who then added water to the dry caustic material to make a caustic ...whiffletree hook and a harness ring were recovered, indicating that horses were used here. No automotive artifacts were recovered. This again reinforces the

Environmental Review Guide for Operations (ERGO) - A Compliance Assessment Manual for Use at All USACE Civil-Funded Projects and Facilities

DTIC Science & Technology

1994-03-01

other Pickling liquor and other corrosive alkalies corrosive acids Lime wastewater Spent acid Lime and water Spent mixed acid Spent caustic Spent ...acid Spent caustic Spent sulfuric acid Potential Consequences: heat generation; violent reaction. 4 - 161 Appendix 4-6 (continued) Group 2-A Group 2-B1...topical bleach (STB) Ordnance, ammunition, explosives & residues Battery acid & caustics (in unserviceable batteries) Some pharmaceuticals Petroleum, oil

United States Air Force Shale Oil to Fuels. Phase II.

DTIC Science & Technology

1981-11-01

and modified so that any off-gas from the LPS, stripper column, product drums, spent caustic drums, and sample ports would be sent to the caustic ...product, or in the spent caustic . After the desalted Paraho shale oil was processed in Production Run No. 2, the catalyst bed was flushed with light cycle...58 20 First-Stage Hydrotreating of Occidental Shale Oil -- Spent Catalyst Analysis - Run 1 ....... 59 21 First-Stage Hydrotreating of Occidental

Caustics of 1/r{sup n} binary gravitational lenses: from galactic haloes to exotic matter

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bozza, V.; Melchiorre, C., E-mail: valboz@physics.unisa.it, E-mail: cmelchiorre@unisa.it

2016-03-01

We investigate the caustic topologies for binary gravitational lenses made up of two objects whose gravitational potential declines as 1/r{sup n}. With n<1 this corresponds to power-law dust distributions like the singular isothermal sphere. The n>1 regime can be obtained with some violations of the energy conditions, one famous example being the Ellis wormhole. Gravitational lensing provides a natural arena to distinguish and identify such exotic objects in our Universe. We find that there are still three topologies for caustics as in the standard Schwarzschild binary lens, with the main novelty coming from the secondary caustics of the close topology,more » which become huge at higher n. After drawing caustics by numerical methods, we derive a large amount of analytical formulae in all limits that are useful to provide deeper insight in the mathematics of the problem. Our study is useful to better understand the phenomenology of galaxy lensing in clusters as well as the distinct signatures of exotic matter in complex systems.« less

Caustic Skeleton & Cosmic Web

NASA Astrophysics Data System (ADS)

Feldbrugge, Job; van de Weygaert, Rien; Hidding, Johan; Feldbrugge, Joost

2018-05-01

We present a general formalism for identifying the caustic structure of a dynamically evolving mass distribution, in an arbitrary dimensional space. The identification of caustics in fluids with Hamiltonian dynamics, viewed in Lagrangian space, corresponds to the classification of singularities in Lagrangian catastrophe theory. On the basis of this formalism we develop a theoretical framework for the dynamics of the formation of the cosmic web, and specifically those aspects that characterize its unique nature: its complex topological connectivity and multiscale spinal structure of sheetlike membranes, elongated filaments and compact cluster nodes. Given the collisionless nature of the gravitationally dominant dark matter component in the universe, the presented formalism entails an accurate description of the spatial organization of matter resulting from the gravitationally driven formation of cosmic structure. The present work represents a significant extension of the work by Arnol'd et al. [1], who classified the caustics that develop in one- and two-dimensional systems that evolve according to the Zel'dovich approximation. His seminal work established the defining role of emerging singularities in the formation of nonlinear structures in the universe. At the transition from the linear to nonlinear structure evolution, the first complex features emerge at locations where different fluid elements cross to establish multistream regions. Involving a complex folding of the 6-D sheetlike phase-space distribution, it manifests itself in the appearance of infinite density caustic features. The classification and characterization of these mass element foldings can be encapsulated in caustic conditions on the eigenvalue and eigenvector fields of the deformation tensor field. In this study we introduce an alternative and transparent proof for Lagrangian catastrophe theory. This facilitates the derivation of the caustic conditions for general Lagrangian fluids, with arbitrary dynamics. Most important in the present context is that it allows us to follow and describe the full three-dimensional geometric and topological complexity of the purely gravitationally evolving nonlinear cosmic matter field. While generic and statistical results can be based on the eigenvalue characteristics, one of our key findings is that of the significance of the eigenvector field of the deformation field for outlining the entire spatial structure of the caustic skeleton emerging from a primordial density field. In this paper we explicitly consider the caustic conditions for the three-dimensional Zel'dovich approximation, extending earlier work on those for one- and two-dimensional fluids towards the full spatial richness of the cosmic web. In an accompanying publication, we apply this towards a full three-dimensional study of caustics in the formation of the cosmic web and evaluate in how far it manages to outline and identify the intricate skeletal features in the corresponding N-body simulations.

Proceedings of the DICE THROW Symposium 21-23 June 1977. Volume 2

DTIC Science & Technology

1977-07-01

structure between 2.7 km and 4.3 km MSL that could cause distant blast focusing. Detailed acoustic ray calculations showed a caustic ring about 10 km...depending on just wheie the focus or caustic wave might strike. Propagation toward Truth or Consequences, MM, shown by Figure 14, was slightly ducted...layer. Thus there probably was no focus or caustic that struck any part of that small town. The recorded signal with 370-Pa amplitude was noisy

U S Navy Diving Manual. Volume 2. Mixed-Gas Diving. Revision 1.

DTIC Science & Technology

1981-07-01

has been soaked in a solution of portant aspects of underwater physics and physiology caustic potash. This chemical absorbed the carbon as they...between the diver’s breathing passages and the circuit must be of minimum volume minimum of caustic fumes. Water produced by the to preclude deadspace and...strongly react with water to pro- space around the absorbent bed to reduce the gas duce caustic fumes and cannot be used in UBA’s. flow distance. The

Modelling Bathymetric Control of Near Coastal Wave Climate. Report 2

DTIC Science & Technology

1990-04-01

given in Sub (1989), showing that the nonlinearity is important at the transects 4 and 5 where the wave has passed through the caustic cusp. Here we...pronounced, especially 22 I 3 on the right side of the caustic cusp. The overall shapes of the results of the parabolic model for 0, = 450 and 600 are...the positive z direction. The shift becomes severe with increasing angle of incidence, and it is more prominent on the right side of the caustic cusp

A Review of the Pollution Abatement Programs Relating to the Petroleum Refinery Industry in the Great Lakes Basin

DTIC Science & Technology

1982-11-01

of spent acids and caustics . The oil content of disposed wastes is 6,200 metric tons per year or approximately .01% of the average crude refinery rate...ALKYLATION "The major discharge from sulfuric acid alkylation are the spent caustics from the neutralization of hydrocarbon streams leaving the sulfuric... spent caustic waste stream. Any leaks or spills that involve loss of fluorides constitute a serious and difficult pollution problem. Formation of

21 CFR 1230.37 - Publication.

Code of Federal Regulations, 2010 CFR

2010-04-01

... CAUSTIC POISON ACT Administrative Procedures § 1230.37 Publication. (a) After judgment of the court in any proceeding under the Federal Caustic Poison Act, notice shall be given by publication. Such notice shall...

21 CFR 1230.37 - Publication.

Code of Federal Regulations, 2014 CFR

2014-04-01

... CAUSTIC POISON ACT Administrative Procedures § 1230.37 Publication. (a) After judgment of the court in any proceeding under the Federal Caustic Poison Act, notice shall be given by publication. Such notice shall...

21 CFR 1230.37 - Publication.

Code of Federal Regulations, 2012 CFR

2012-04-01

... CAUSTIC POISON ACT Administrative Procedures § 1230.37 Publication. (a) After judgment of the court in any proceeding under the Federal Caustic Poison Act, notice shall be given by publication. Such notice shall...

21 CFR 1230.37 - Publication.

Code of Federal Regulations, 2013 CFR

2013-04-01

... CAUSTIC POISON ACT Administrative Procedures § 1230.37 Publication. (a) After judgment of the court in any proceeding under the Federal Caustic Poison Act, notice shall be given by publication. Such notice shall...

21 CFR 1230.37 - Publication.

Code of Federal Regulations, 2011 CFR

2011-04-01

... CAUSTIC POISON ACT Administrative Procedures § 1230.37 Publication. (a) After judgment of the court in any proceeding under the Federal Caustic Poison Act, notice shall be given by publication. Such notice shall...

21 CFR 1230.48 - Relabeling of containers.

Code of Federal Regulations, 2012 CFR

2012-04-01

... FEDERAL CAUSTIC POISON ACT Imports § 1230.48 Relabeling of containers. (a) If containers are to be... requirements of the Federal Caustic Poison Act and all regulations and instructions issued thereunder. The...

21 CFR 1230.48 - Relabeling of containers.

Code of Federal Regulations, 2011 CFR

2011-04-01

... FEDERAL CAUSTIC POISON ACT Imports § 1230.48 Relabeling of containers. (a) If containers are to be... requirements of the Federal Caustic Poison Act and all regulations and instructions issued thereunder. The...

21 CFR 1230.48 - Relabeling of containers.

Code of Federal Regulations, 2013 CFR

2013-04-01

... FEDERAL CAUSTIC POISON ACT Imports § 1230.48 Relabeling of containers. (a) If containers are to be... requirements of the Federal Caustic Poison Act and all regulations and instructions issued thereunder. The...

21 CFR 1230.48 - Relabeling of containers.

Code of Federal Regulations, 2010 CFR

2010-04-01

... FEDERAL CAUSTIC POISON ACT Imports § 1230.48 Relabeling of containers. (a) If containers are to be... requirements of the Federal Caustic Poison Act and all regulations and instructions issued thereunder. The...

21 CFR 1230.48 - Relabeling of containers.

Code of Federal Regulations, 2014 CFR

2014-04-01

... FEDERAL CAUSTIC POISON ACT Imports § 1230.48 Relabeling of containers. (a) If containers are to be... requirements of the Federal Caustic Poison Act and all regulations and instructions issued thereunder. The...

27 CFR 21.63 - Formula No. 36.

Code of Federal Regulations, 2012 CFR

2012-04-01

... pounds of caustic soda, liquid grade, containing 50 percent sodium hydroxide by weight; or 12.0 pounds of caustic soda, liquid grade, containing 73 percent sodium hydroxide by weight. (b) Authorized uses. (1) As...

27 CFR 21.63 - Formula No. 36.

Code of Federal Regulations, 2014 CFR

2014-04-01

... pounds of caustic soda, liquid grade, containing 50 percent sodium hydroxide by weight; or 12.0 pounds of caustic soda, liquid grade, containing 73 percent sodium hydroxide by weight. (b) Authorized uses. (1) As...

27 CFR 21.63 - Formula No. 36.

Code of Federal Regulations, 2013 CFR

2013-04-01

... pounds of caustic soda, liquid grade, containing 50 percent sodium hydroxide by weight; or 12.0 pounds of caustic soda, liquid grade, containing 73 percent sodium hydroxide by weight. (b) Authorized uses. (1) As...

Using GC-FID to Quantify the Removal of 4-sec-Butylphenol from NGS Solvent by NaOH

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sloop, Jr., Frederick V.; Moyer, Bruce A.

2014-12-01

A caustic wash of the solvent used in the Next-Generation Caustic-Side Solvent Extraction (NG-CSSX) process was found to remove the modifier breakdown product 4-sec-butylphenol (SBP) with varying efficiency depending on the aqueous NaOH concentration. Recent efforts at ORNL have aimed at characterizing the flowsheet chemistry and reducing the technical uncertainties of the NG-CSSX process. One technical uncertainty has been the efficacy of caustic washing of the solvent for the removal of lipophilic anions, in particular, the efficient removal of SBP, an important degradation product of the solvent modifier, Cs-7SB. In order to make this determination, it was necessary to developmore » a sensitive and reliable analytical technique for the detection and quantitation of SBP. This report recounts the development of a GC-FID-based (Gas Chromatography Flame Ionization Detection) technique for analyzing SBP and the utilization of the technique to subsequently confirm the ability of the caustic wash to efficiently remove SBP from the Next Generation Solvent (NGS) used in NG-CSSX. In particular, the developed technique was used to monitor the amount of SBP removed from a simple solvent and the full NGS by contact with sodium hydroxide wash solutions over a range of concentrations. The results show that caustic washing removes SBP with effectively the same efficiency as it did in the original Caustic-Side Solvent Extraction (CSSX) process.« less

Results Of Routine Strip Effluent Hold Tank, Decontaminated Salt Solution Hold Tank, Caustic Wash Tank And Caustic Storage Tank Samples From Modular Caustic-Side Solvent Extraction Unit During Macrobatch 6 Operations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peters, T. B.

Strip Effluent Hold Tank (SEHT), Decontaminated Salt Solution Hold Tank (DSSHT), Caustic Wash Tank (CWT) and Caustic Storage Tank (CST) samples from the Interim Salt Disposition Project (ISDP) Salt Batch (“Macrobatch”) 6 have been analyzed for 238Pu, 90Sr, 137Cs, and by Inductively Coupled Plasma Emission Spectroscopy (ICPES). The Pu, Sr, and Cs results from the current Macrobatch 6 samples are similar to those from comparable samples in previous Macrobatch 5. In addition the SEHT and DSSHT heel samples (i.e. ‘preliminary’) have been analyzed and reported to meet NGS Demonstration Plan requirements. From a bulk chemical point of view, the ICPESmore » results do not vary considerably between this and the previous samples. The titanium results in the DSSHT samples continue to indicate the presence of Ti, when the feed material does not have detectable levels. This most likely indicates that leaching of Ti from MST has increased in ARP at the higher free hydroxide concentrations in the current feed.« less

Potentials of biological oxidation processes for the treatment of spent sulfidic caustics containing thiols.

PubMed

Sipma, Jan; Svitelskaya, Anna; van der Mark, Bart; Pol, Look W Hulshoff; Lettinga, Gatze; Buisman, Cees J N; Janssen, Albert J H

2004-12-01

This research focused on the biological treatment of sulfidic spent caustics from refineries, which contain mainly hydrogen sulfide, methanethiol (MT) and ethanethiol (ET). Also various organic compounds can be present such as BTEX. Biological oxidation of 2.5 mM MT in batch experiments occurred after MT was first auto-oxidized into dimethyldisulfide (DMDS) whereafter oxidation into sulfate was completed in 350 h. DMDS as sole substrate was completely oxidized within 40 h. Therefore, DMDS formation seems to play an important role in detoxification of MT. Biological oxidation of ET and buthanethiol was not successful in batch experiments. Complete oxidation of MT and ET was observed in flow-through reactor experiments. Simultaneous oxidation of sulfide and MT was achieved when treating a synthetic spent caustic, containing 10 mM sulfide and 2.5 mM MT, in a bubble column reactor with carrier material at a hydraulic retention time of 6 h. Addition of 7.5 mM phenol, a common pollutant of spent caustics, did not adversely affect the biological oxidation process and phenol was completely removed from the effluent. Finally, three different spent caustics solutions from refineries were successfully treated.

Caustic Recycling Pilot Unit to Separate Sodium from LLW at Hanford Site - 12279

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pendleton, Justin; Bhavaraju, Sai; Priday, George

As part of the Department of Energy (DOE) sponsored Advanced Remediation Technologies initiative, a scheme was developed to combine Continuous Sludge Leaching (CSL), Near-Tank Cesium Removal (NTCR), and Caustic Recycling Unit (CRU) using Ceramatec technology, into a single system known as the Pilot Near-Tank Treatment System (PNTTS). The Cesium (Cs) decontaminated effluent from the NTCR process will be sent to the caustic recycle process for recovery of the caustic which will be reused in another cycle of caustic leaching in the CSL process. Such an integrated mobile technology demonstration will give DOE the option to insert this process for sodiummore » management at various sites in Hanford, and will minimize the addition of further sodium into the waste tanks. This allows for recycling of the caustic used to remove aluminum during sludge washing as a pretreatment step in the vitrification of radioactive waste which will decrease the Low Level Waste (LLW) volume by as much as 39%. The CRU pilot process was designed to recycle sodium in the form of pure sodium hydroxide. The basis for the design of the 1/4 scale pilot caustic recycling unit was to demonstrate the efficient operation of a larger scale system to recycle caustic from the NTCR effluent stream from the Parsons process. The CRU was designed to process 0.28 liter/minute of NTCR effluent, and generate 10 M concentration of 'usable' sodium hydroxide. The proposed process operates at 40 deg. C to provide additional aluminum solubility and then recover the sodium hydroxide to the point where the aluminum is saturated at 40 deg. C. A system was developed to safely separate and vent the gases generated during operation of the CRU with the production of 10 M sodium hydroxide. Caustic was produced at a rate between 1.9 to 9.3 kg/hr. The CRU was located inside an ISO container to allow for moving of the unit close to tank locations to process the LLW stream. Actual tests were conducted with the NTCR effluent simulant from the Parsons process in the CRU. The modular CRU is easily scalable as a standalone system for caustic recycling, or for NTTS integration or for use as an In-Tank Treatment System to process sodium bearing waste to meet LLW processing needs at the Hanford site. The standalone pilot operation of the CRU to recycle sodium from NTCR effluent places the technology demonstration at TRL level 6. Multiple operations were performed with the CRU to process up to 500 gallons of the NTCR effluent and demonstrate an efficient separation of up to 70 % of the sodium without solids precipitation while producing 10 M caustic. Batch mode operation was conducted to study the effects of chemistry variation, establish the processing rate, and optimize the process operating conditions to recycle caustic from the NTCR effluent. The performance of the CRU was monitored by tracking the density parameter to control the concentration of caustic produced. Different levels of sodium were separated in tests from the effluent at a fixed operating current density and temperature. The voltage of the modules remained stable during the unit operation which demonstrated steady operation to separate sodium from the NTCR effluent. The sodium transfer current efficiency was measured in testing based on the concentration of caustic produced. Measurements showed a current efficiency of 99.8% for sodium transfer from the NTCR effluent to make sodium hydroxide. The sodium and hydroxide contents of the anolyte (NTCR feed) and catholyte (caustic product) were measured before and after each batch test. In two separate batch tests, samples were taken at different levels of sodium separation and analyzed to determine the stability of the NTCR effluent after sodium separation. The stability characteristics and changes in physical and chemical properties of the NTCR effluent chemistry after separation of sodium hydroxide as a function of storage time were evaluated. Parameters such as level of precipitated alumina, total alkalinity, analysis of Al, Na, K, Cs, Fe, OH, nitrate, nitrite, total dissolved and undissolved solids, viscosity, density, and other parameters of the NTCR effluent were measured. Changes in rheology and properties of NTCR stream to support downstream handling of the effluent after sodium separation was the basis for the analysis. The results show that the NTCR effluent is stable without the precipitation of aluminum hydroxide after 70% of the sodium was separated from the effluent. (authors)« less

21 CFR 1230.40 - Required label information.

Code of Federal Regulations, 2010 CFR

2010-04-01

... FEDERAL CAUSTIC POISON ACT Imports § 1230.40 Required label information. Containers which are offered for...) (1), (2), and (3) of the Federal Caustic Poison Act and the directions for treatment in the case of...

21 CFR 1230.40 - Required label information.

Code of Federal Regulations, 2012 CFR

2012-04-01

... FEDERAL CAUSTIC POISON ACT Imports § 1230.40 Required label information. Containers which are offered for...) (1), (2), and (3) of the Federal Caustic Poison Act and the directions for treatment in the case of...

21 CFR 1230.40 - Required label information.

Code of Federal Regulations, 2014 CFR

2014-04-01

... FEDERAL CAUSTIC POISON ACT Imports § 1230.40 Required label information. Containers which are offered for...) (1), (2), and (3) of the Federal Caustic Poison Act and the directions for treatment in the case of...

21 CFR 1230.40 - Required label information.

Code of Federal Regulations, 2011 CFR

2011-04-01

... FEDERAL CAUSTIC POISON ACT Imports § 1230.40 Required label information. Containers which are offered for...) (1), (2), and (3) of the Federal Caustic Poison Act and the directions for treatment in the case of...

21 CFR 1230.40 - Required label information.

Code of Federal Regulations, 2013 CFR

2013-04-01

... FEDERAL CAUSTIC POISON ACT Imports § 1230.40 Required label information. Containers which are offered for...) (1), (2), and (3) of the Federal Caustic Poison Act and the directions for treatment in the case of...

Observation of the enhanced backscattering of light by the end of a tilted dielectric cylinder owing to the caustic merging transition

NASA Astrophysics Data System (ADS)

Marston, Philip L.; Zhang, Yibing; Thiessen, David B.

2003-01-01

The scattering of light by obliquely illuminated circular dielectric cylinders was previously demonstrated to be enhanced by a merger of Airy caustics at a critical tilt angle. [Appl. Opt. 37, 1534 (1998)]. A related enhancement is demonstrated here for backward and near-backward scattering for cylinders cut with a flat end perpendicular to the cylinder's axis. It is expected that merged caustics will enhance the backscattering by clouds of randomly oriented circular cylinders that have appropriately flat ends.

A Technique for Evaluating the Uncertainties in Path Loss Predictions Caused by Sparsely Sampled Terrain Data

DTIC Science & Technology

2013-06-26

Diomedi, thank you for providing support in getting through the writing. To my parents and Suzanne’s, thank you for tolerating the time we’ve spent here...the caustic distance idea from geometric optics, and will be shown to slightly improve the results. Following those results, antenna patterns will be...change in the caustic in the 3rd dimension, while MOMI has already accounted for it in the x-z plane. In geometric optics, the caustic is the point of

Monitoring caustic injuries from emergency department databases using automatic keyword recognition software.

PubMed

Vignally, P; Fondi, G; Taggi, F; Pitidis, A

2011-03-31

In Italy the European Union Injury Database reports the involvement of chemical products in 0.9% of home and leisure accidents. The Emergency Department registry on domestic accidents in Italy and the Poison Control Centres record that 90% of cases of exposure to toxic substances occur in the home. It is not rare for the effects of chemical agents to be observed in hospitals, with a high potential risk of damage - the rate of this cause of hospital admission is double the domestic injury average. The aim of this study was to monitor the effects of injuries caused by caustic agents in Italy using automatic free-text recognition in Emergency Department medical databases. We created a Stata software program to automatically identify caustic or corrosive injury cases using an agent-specific list of keywords. We focused attention on the procedure's sensitivity and specificity. Ten hospitals in six regions of Italy participated in the study. The program identified 112 cases of injury by caustic or corrosive agents. Checking the cases by quality controls (based on manual reading of ED reports), we assessed 99 cases as true positive, i.e. 88.4% of the patients were automatically recognized by the software as being affected by caustic substances (99% CI: 80.6%- 96.2%), that is to say 0.59% (99% CI: 0.45%-0.76%) of the whole sample of home injuries, a value almost three times as high as that expected (p < 0.0001) from European codified information. False positives were 11.6% of the recognized cases (99% CI: 5.1%- 21.5%). Our automatic procedure for caustic agent identification proved to have excellent product recognition capacity with an acceptable level of excess sensitivity. Contrary to our a priori hypothesis, the automatic recognition system provided a level of identification of agents possessing caustic effects that was significantly much greater than was predictable on the basis of the values from current codifications reported in the European Database.

21 CFR 1230.36 - Hearings; when not provided for.

Code of Federal Regulations, 2011 CFR

2011-04-01

... FEDERAL CAUSTIC POISON ACT Administrative Procedures § 1230.36 Hearings; when not provided for. No hearing... Caustic Poison Act (44 Stat. 1409; 15 U.S.C. 408) in reporting a violation direct to the United States...

21 CFR 1230.36 - Hearings; when not provided for.

Code of Federal Regulations, 2013 CFR

2013-04-01

... FEDERAL CAUSTIC POISON ACT Administrative Procedures § 1230.36 Hearings; when not provided for. No hearing... Caustic Poison Act (44 Stat. 1409; 15 U.S.C. 408) in reporting a violation direct to the United States...

21 CFR 1230.36 - Hearings; when not provided for.

Code of Federal Regulations, 2010 CFR

2010-04-01

... FEDERAL CAUSTIC POISON ACT Administrative Procedures § 1230.36 Hearings; when not provided for. No hearing... Caustic Poison Act (44 Stat. 1409; 15 U.S.C. 408) in reporting a violation direct to the United States...

21 CFR 1230.36 - Hearings; when not provided for.

Code of Federal Regulations, 2014 CFR

2014-04-01

... FEDERAL CAUSTIC POISON ACT Administrative Procedures § 1230.36 Hearings; when not provided for. No hearing... Caustic Poison Act (44 Stat. 1409; 15 U.S.C. 408) in reporting a violation direct to the United States...

21 CFR 1230.36 - Hearings; when not provided for.

Code of Federal Regulations, 2012 CFR

2012-04-01

... FEDERAL CAUSTIC POISON ACT Administrative Procedures § 1230.36 Hearings; when not provided for. No hearing... Caustic Poison Act (44 Stat. 1409; 15 U.S.C. 408) in reporting a violation direct to the United States...

Microlensing as a possible probe of event-horizon structure in quasars

NASA Astrophysics Data System (ADS)

Tomozeiu, Mihai; Mohammed, Irshad; Rabold, Manuel; Saha, Prasenjit; Wambsganss, Joachim

2018-04-01

In quasars which are lensed by galaxies, the point-like images sometimes show sharp and uncorrelated brightness variations (microlensing). These brightness changes are associated with the innermost region of the quasar passing through a complicated pattern of caustics produced by the stars in the lensing galaxy. In this paper, we study whether the universal properties of optical caustics could enable extraction of shape information about the central engine of quasars. We present a toy model with a crescent-shaped source crossing a fold caustic. The silhouette of a black hole over an accretion disc tends to produce roughly crescent sources. When a crescent-shaped source crosses a fold caustic, the resulting light curve is noticeably different from the case of a circular luminosity profile or Gaussian source. With good enough monitoring data, the crescent parameters, apart from one degeneracy, can be recovered.

Microlensing as a Possible Probe of Event-Horizon Structure in Quasars

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tomozeiu, Mihai; Mohammed, Irshad; Rabold, Manuel

In quasars which are lensed by galaxies, the point-like images sometimes show sharp and uncorrelated brightness variations (microlensing). These brightness changes are associated with the innermost region of the quasar passing through a complicated pattern of caustics produced by the stars in the lensing galaxy. In this paper, we study whether the universal properties of optical caustics could enable extraction of shape information about the central engine of quasars. We present a toy model with a crescent-shaped source crossing a fold caustic. The silhouette of a black hole over an accretion disk tends to produce roughly crescent sources. When amore » crescent-shaped source crosses a fold caustic, the resulting light curve is noticeably different from the case of a circular luminosity profile or Gaussian source. With good enough monitoring data, the crescent parameters, apart from one degeneracy, can be recovered.« less

Microlensing as a Possible Probe of Event-Horizon Structure in Quasars

DOE PAGES

Tomozeiu, Mihai; Mohammed, Irshad; Rabold, Manuel; ...

2017-12-08

In quasars which are lensed by galaxies, the point-like images sometimes show sharp and uncorrelated brightness variations (microlensing). These brightness changes are associated with the innermost region of the quasar passing through a complicated pattern of caustics produced by the stars in the lensing galaxy. In this paper, we study whether the universal properties of optical caustics could enable extraction of shape information about the central engine of quasars. We present a toy model with a crescent-shaped source crossing a fold caustic. The silhouette of a black hole over an accretion disk tends to produce roughly crescent sources. When amore » crescent-shaped source crosses a fold caustic, the resulting light curve is noticeably different from the case of a circular luminosity profile or Gaussian source. With good enough monitoring data, the crescent parameters, apart from one degeneracy, can be recovered.« less

Heavy metal removal by caustic-treated yeast immobilized in alginate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lu, Y.; Wilkins, E.

1995-12-31

Saccharomyces cerevisiae yeast biomass was treated with hot alkali to increase its biosorption capacity for heavy metals and then was immobilized in alginate gel. Biosorption capacities for Cu{sup 2+}, Cd{sup 2+}, and Zn{sup 2+} on alginate gel, native yeast, native yeast immobilized in alginate gel, and caustic-treated yeast immobilized in alginate gel were all compared. Immobilized yeasts could be reactivated and reused in a manner similar to the ion exchange resins. Immobilized caustic-treated yeast has high heavy metal biosorption capacity and high metal removal efficiency in a rather wide acidic pH region. The biosorption isotherm of immobilized caustic-treated yeast wasmore » studied, and empirical equations were obtained. The initial pH of polluted water affected the metal removal efficiency significantly, and the equilibrium biosorption capacity seemed to be temperature independent at lower initial metal concentrations.« less

Prediction of sonic boom at a focus

NASA Technical Reports Server (NTRS)

Plotkin, K. J.; Cantril, J. M.

1976-01-01

The behavior of sonic boom at a focus has been reviewed for the purpose of extending present sonic boom computational methods to include focal zones. The geometry of a focal zone - whether a smooth caustic, a cusped caustic, or a perfect focus to a point - determines the character of focused signatures. The seeming contradiction of various experimental data can be resolved by noting these differences. A ray acoustic analysis has been developed for quantitative determination of caustic geometry. The only reliable theory presently available for signatures at a focus is for a smooth caustic. There has been some controversy between theoretical and experimental values of a constant in the scaling law for this case. It has been found that this discrepancy can be resolved by accounting for the finite thickness of real sonic boom shock waves. These findings have been incorporated into an existing sonic boom computer program.

Comparing census methods for the endangered Kirtland's Warbler

Treesearch

John R. Probst; Deahn M. Donner; Mike Worland; Jerry Weinrich; Phillip Huber; Kenneth R. Ennis

2005-01-01

We compared transect counts used for the annual official count of male Kirtland`s Warblers (Dendroica kirtlandii) to an observation-based mapping method of individually sighted males in 155 stands over 10 yrs. The annual census count almost tripled from 1990 to 1999. The transect and observation-based mapping method showed the same increasing trend...

Role of microstructure in caustic stress corrosion cracking of Alloy 690

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mertz, D.A.; Duda, P.T.; Pica, P.N.

1995-12-31

Alloy 690 has been selected for nuclear heat transport system tubing application in recent commercial reactor plants due to its resistance to multiple types of corrosion attack. Typical corn final heat treatments for this material are a mill-anneal (MA, approximately 1,070 C) to completely dissolve the carbides and develop the final grain structure plus a thermal treatment (TT, approximately 700 C) to precipitate carbides at the grain boundaries. Tubing with grain boundary carbides and no or few intragranular carbides has been found resistant to intergranular stress corrosion cracking (IGSCC) in caustic environments. In this work, first, Alloy 690 plate wasmore » subjected to a variety of MA and MA-TT heat treatments to create microstructures of carbide-decorated grain boundaries and undecorated boundaries. Caustic IGSCC test results were consistent with tubing data. Second, experiments were conducted to understand the mechanism by which caustic-corrosion resistance is imparted to Alloy 690 by grain boundary carbides. Tubing with a fully-developed MA-TT carbide microstructure was strained and heat-treated to create a mixed microstructure of new grain boundaries with no carbide precipitate decoration, intermixed with intragranular carbide strings from prior grain boundaries. Caustic SCC performance of this material was identical to that of material with the MA-TT carbide-decorated grain boundaries. This work suggests that the fundamental cause of good IGSCC resistance of MA-TT Alloy 690 in caustic does not derive solely from grain boundary carbides. It is suggested that matrix strength, as measured by yield stress, could be a controlling factor.« less

Laboratory scale Clean-In-Place (CIP) studies on the effectiveness of different caustic and acid wash steps on the removal of dairy biofilms.

PubMed

Bremer, Philip J; Fillery, Suzanne; McQuillan, A James

2006-02-15

A laboratory scale, bench top flow system was used to partially reproduce dairy plant conditions under which biofilms form and to quantify the effectiveness of caustic and acid wash steps in reducing the number of viable bacteria attached to stainless steel (SS) surfaces. Once bacteria attached to surfaces, a standard clean-in-place (CIP) regime (water rinse, 1% sodium hydroxide at 65 degrees C for 10 min, water rinse, 1.0% nitric acid at 65 degrees C for 10 min, water rinse) did not reproducibly ensure their removal. Standard CIP effectiveness was compared to alternative cleaning chemicals such as: caustic blends (Alkazolv 48, Ultrazolv 700, Concept C20, and Reflex B165); a caustic additive (Eliminator); acid blends (Nitroplus and Nitrobrite); and sanitizer (Perform). The addition of a caustic additive, Eliminator, enhanced biofilm removal compared to the standard CIP regime and further increases in cleaning efficiency occurred when nitric acid was substituted with Nitroplus. The combination of NaOH plus Eliminator and Nitroplus achieved a 3.8 log reduction in the number of cells recovered from the stainless steel surface. The incorporation of a sanitizer step into the CIP did not appear to enhance biofilm removal. This study has shown that the effectiveness of a "standard" CIP can possibly be enhanced through the testing and use of caustic and acid blends. There are many implications of these findings, including: the development of improved cleaning regimes and improved product quality, plant performance, and economic returns.

Intrinsic scatter of caustic masses and hydrostatic bias: An observational study

NASA Astrophysics Data System (ADS)

Andreon, S.; Trinchieri, G.; Moretti, A.; Wang, J.

2017-10-01

All estimates of cluster mass have some intrinsic scatter and perhaps some bias with true mass even in the absence of measurement errors for example caused by cluster triaxiality and large scale structure. Knowledge of the bias and scatter values is fundamental for both cluster cosmology and astrophysics. In this paper we show that the intrinsic scatter of a mass proxy can be constrained by measurements of the gas fraction because masses with higher values of intrinsic scatter with true mass produce more scattered gas fractions. Moreover, the relative bias of two mass estimates can be constrained by comparing the mean gas fraction at the same (nominal) cluster mass. Our observational study addresses the scatter between caustic (I.e., dynamically estimated) and true masses, and the relative bias of caustic and hydrostatic masses. For these purposes, we used the X-ray Unbiased Cluster Sample, a cluster sample selected independently from the intracluster medium content with reliable masses: 34 galaxy clusters in the nearby (0.050 < z < 0.135) Universe, mostly with 14 < log M500/M⊙ ≲ 14.5, and with caustic masses. We found a 35% scatter between caustic and true masses. Furthermore, we found that the relative bias between caustic and hydrostatic masses is small, 0.06 ± 0.05 dex, improving upon past measurements. The small scatter found confirms our previous measurements of a highly variable amount of feedback from cluster to cluster, which is the cause of the observed large variety of core-excised X-ray luminosities and gas masses.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Josephson, Gary B.; Geeting, John GH; Bredt, Ofelia P.

Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Waste Treatment Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed, and operated as part of a plan to respond to issue M12, "Undemonstrated Leaching Processes." The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEPmore » also includes non-prototypic ancillary equipment to support the core processing. Two operating scenarios are currently being evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario has caustic leaching performed in the UFP-2 ultrafiltration feed vessels (i.e., vessel UFP-VSL-T02A in the PEP; and vessels UFP-VSL-00002A and B in the WTP PTF). The second scenario has caustic leaching conducted in the UFP-1 ultrafiltration feed preparation vessels (i.e., vessels UFP-VSL-T01A and B in the PEP; vessels UFP-VSL-00001A and B in the WTP PTF). In both scenarios, 19-M sodium hydroxide solution (NaOH, caustic) is added to the waste slurry in the vessels to leach solid aluminum compounds (e.g., gibbsite, boehmite). Caustic addition is followed by a heating step that uses direct injection of steam to accelerate the leach process. Following the caustic leach, the vessel contents are cooled using vessel cooling jackets and/or external heat exchangers. The main difference between the two scenarios is that for leaching in UFP-1, the 19-M NaOH is added to un-concentrated waste slurry (3-8 wt% solids), while for leaching in UFP-2, the slurry is concentrated to nominally 20 wt% solids using cross-flow ultrafiltration before the addition of caustic. In both scenarios, following the caustic leach, the slurry was then concentrated to 17 wt% and washed with inhibited water to remove NaOH and other soluble salts. Next, the slurry was oxidatively leached using sodium permanganate to solubilize chrome. The slurry was then washed to remove the dissolved chrome and concentrated.« less

Stress corrosion cracking of duplex stainless steels in caustic solutions

NASA Astrophysics Data System (ADS)

Bhattacharya, Ananya

Duplex stainless steels (DSS) with roughly equal amount of austenite and ferrite phases are being used in industries such as petrochemical, nuclear, pulp and paper mills, de-salination plants, marine environments, and others. However, many DSS grades have been reported to undergo corrosion and stress corrosion cracking in some aggressive environments such as chlorides and sulfide-containing caustic solutions. Although stress corrosion cracking of duplex stainless steels in chloride solution has been investigated and well documented in the literature but the SCC mechanisms for DSS in caustic solutions were not known. Microstructural changes during fabrication processes affect the overall SCC susceptibility of these steels in caustic solutions. Other environmental factors, like pH of the solution, temperature, and resulting electrochemical potential also influence the SCC susceptibility of duplex stainless steels. In this study, the role of material and environmental parameters on corrosion and stress corrosion cracking of duplex stainless steels in caustic solutions were investigated. Changes in the DSS microstructure by different annealing and aging treatments were characterized in terms of changes in the ratio of austenite and ferrite phases, phase morphology and intermetallic precipitation using optical micrography, SEM, EDS, XRD, nano-indentation and microhardness methods. These samples were then tested for general and localized corrosion susceptibility and SCC to understand the underlying mechanisms of crack initiation and propagation in DSS in the above-mentioned environments. Results showed that the austenite phase in the DSS is more susceptible to crack initiation and propagation in caustic solutions, which is different from that in the low pH chloride environment where the ferrite phase is the more susceptible phase. This study also showed that microstructural changes in duplex stainless steels due to different heat treatments could affect their SCC susceptibility. Annealed and water quenched specimens were found to be immune to SCC in caustic environment. Aging treatment at 800°C gave rise to sigma and chi precipitates in the DSS. However, these sigma and chi precipitates, known to initiate cracking in DSS in chloride environment did not cause any cracking of DSS in caustic solutions. Aging of DSS at 475°C had resulted in '475°C embrittlement' and caused cracks to initiate in the ferrite phase. This was in contrast to the cracks initiating in the austenite phase in the as-received DSS. Alloy composition and microstructure of DSS as well as solution composition (dissolved ionic species) was also found to affect the electrochemical behavior and passivation of DSS which in turn plays a major role in stress corrosion crack initiation and propagation. Corrosion rates and SCC susceptibility of DSS was found to increase with addition of sulfide to caustic solutions. Corrosion films on DSS, characterized using XRD and X-ray photoelectron spectroscopy, indicated that the metal sulfide compounds were formed along with oxides at the metal surface in the presence of sulfide containing caustic environments. These metal sulfide containing passive films are unstable and hence breaks down under mechanical straining, leading to SCC initiations. The overall results from this study helped in understanding the mechanism of SCC in caustic solutions. Favorable slip systems in the austenite phase of DSS favors slip-induced local film damage thereby initiating a stress corrosion crack. Repeated film repassivation and breaking, followed by crack tip dissolution results in crack propagation in the austenite phase of DSS alloys. Result from this study will have a significant impact in terms of identifying the alloy compositions, fabrication processes, microstructures, and environmental conditions that may be avoided to mitigate corrosion and stress corrosion cracking of DSS in caustic solutions.

The Zel'dovich approximation: key to understanding cosmic web complexity

NASA Astrophysics Data System (ADS)

Hidding, Johan; Shandarin, Sergei F.; van de Weygaert, Rien

2014-02-01

We describe how the dynamics of cosmic structure formation defines the intricate geometric structure of the spine of the cosmic web. The Zel'dovich approximation is used to model the backbone of the cosmic web in terms of its singularity structure. The description by Arnold et al. in terms of catastrophe theory forms the basis of our analysis. This two-dimensional analysis involves a profound assessment of the Lagrangian and Eulerian projections of the gravitationally evolving four-dimensional phase-space manifold. It involves the identification of the complete family of singularity classes, and the corresponding caustics that we see emerging as structure in Eulerian space evolves. In particular, as it is instrumental in outlining the spatial network of the cosmic web, we investigate the nature of spatial connections between these singularities. The major finding of our study is that all singularities are located on a set of lines in Lagrangian space. All dynamical processes related to the caustics are concentrated near these lines. We demonstrate and discuss extensively how all 2D singularities are to be found on these lines. When mapping this spatial pattern of lines to Eulerian space, we find a growing connectedness between initially disjoint lines, resulting in a percolating network. In other words, the lines form the blueprint for the global geometric evolution of the cosmic web.

Salmonella

MedlinePlus

... Cereal en Español Recall and Advice to Consumers, Restaurants and Retailers Case Count Maps Epi Curves Signs & ... Eggs en Español Recalls and Advice to Consumers, Restaurants, and Retailers Case Count Maps Epi Curves Signs & ...

E. Coli

MedlinePlus

... to Romaine Lettuce en Español Advice to Consumers, Restaurants, Retailers, and Clinicians Case Count Maps Epi Curves ... Linked to Raw Clover Sprouts at Jimmy John’s Restaurants Advice to Consumers Case Count Maps Epi Curves ...

Salmonella Prevention

MedlinePlus

... Cereal en Español Recall and Advice to Consumers, Restaurants and Retailers Case Count Maps Epi Curves Signs & ... Eggs en Español Recalls and Advice to Consumers, Restaurants, and Retailers Case Count Maps Epi Curves Signs & ...

21 CFR 1230.35 - Hearings.

Code of Federal Regulations, 2013 CFR

2013-04-01

... POISON ACT Administrative Procedures § 1230.35 Hearings. Whenever it appears from the inspection, analysis, or test of any container that the provisions of section 3 or 6 of the Federal Caustic Poison Act... prosecution as a violation of the Federal Caustic Poison Act. ...

21 CFR 1230.35 - Hearings.

Code of Federal Regulations, 2012 CFR

2012-04-01

... POISON ACT Administrative Procedures § 1230.35 Hearings. Whenever it appears from the inspection, analysis, or test of any container that the provisions of section 3 or 6 of the Federal Caustic Poison Act... prosecution as a violation of the Federal Caustic Poison Act. ...

21 CFR 1230.35 - Hearings.

Code of Federal Regulations, 2010 CFR

2010-04-01

... POISON ACT Administrative Procedures § 1230.35 Hearings. Whenever it appears from the inspection, analysis, or test of any container that the provisions of section 3 or 6 of the Federal Caustic Poison Act... prosecution as a violation of the Federal Caustic Poison Act. ...

Caustic stress corrosion tests for the LLTR

DOE Office of Scientific and Technical Information (OSTI.GOV)

Indig, M.E.

1976-05-01

A series of tests have been performed in order to determine the effects of the caustic resulting from the Na/H/sub 2/O reaction on the materials used in the LLTR-MSG series of testing. Stainless steel, 2 /sup 1///sub 4/ Cr--1 Mo and carbon steel have been evaluated. Stress corrosion cracking susceptibility and general corrosion are reported. Over the range of temperature, caustic concentration and heating rate tested the stainless steel stressed to 90% of yield or above suffered cracking. Whereas, the 2-/sup 1///sub 4/ Cr--1 Mo and carbon steel were not cracked.

Mapping the layer count of few-layer hexagonal boron nitride at high lateral spatial resolutions

NASA Astrophysics Data System (ADS)

Mohsin, Ali; Cross, Nicholas G.; Liu, Lei; Watanabe, Kenji; Taniguchi, Takashi; Duscher, Gerd; Gu, Gong

2018-01-01

Layer count control and uniformity of two dimensional (2D) layered materials are critical to the investigation of their properties and to their electronic device applications, but methods to map 2D material layer count at nanometer-level lateral spatial resolutions have been lacking. Here, we demonstrate a method based on two complementary techniques widely available in transmission electron microscopes (TEMs) to map the layer count of multilayer hexagonal boron nitride (h-BN) films. The mass-thickness contrast in high-angle annular dark-field (HAADF) imaging in the scanning transmission electron microscope (STEM) mode allows for thickness determination in atomically clean regions with high spatial resolution (sub-nanometer), but is limited by surface contamination. To complement, another technique based on the boron K ionization edge in the electron energy loss spectroscopy spectrum (EELS) of h-BN is developed to quantify the layer count so that surface contamination does not cause an overestimate, albeit at a lower spatial resolution (nanometers). The two techniques agree remarkably well in atomically clean regions with discrepancies within  ±1 layer. For the first time, the layer count uniformity on the scale of nanometers is quantified for a 2D material. The methodology is applicable to layer count mapping of other 2D layered materials, paving the way toward the synthesis of multilayer 2D materials with homogeneous layer count.

Effect of vacuum and modified atmosphere packaging on microbiological properties of cold-smoked trout

NASA Astrophysics Data System (ADS)

Đorđević, J.; Pavlićević, N.; Bošković, M.; Janjić, J.; Glišić, M.; Starčević, M.; Baltić, M. Ž.

2017-09-01

Because of the importance of different packaging methods for the extension of fish shelf life, as a highly perishable food, the aim of the present study was to examine the effect of vacuum and modified atmosphere packaging on the total Enterobacteriaceae and lactic acid bacteria counts of cold-smoked Salmon trout (Oncorhynchus mykiss) stored at 3°C during six weeks. Trout fillets were vacuumed packaged (VP) or packaged in one of two different modified atmospheres, with gas ratio of 50%CO2/50%N2 (MAP1) and 90%CO2/10%N2 (MAP2) and analysed on days 0, 7, 14, 21, 28, 35 and 42. Both the total Enterobacteriaceae and total lactic acid bacteria counts increased in the trout fillets in all packaging types during storage. A significantly lower total Enterobacteriaceae count was determined in the MAP fish compared to the VP fish, with the weakest growth rate and lowest numbers attained in MAP2 fillets. The lactic acid bacteria count was higher in trout packaged in MAP compared to VP, with the highest number in the MAP with 90% CO2 (MAP2).

Salmonella Diagnosis and Treatment

MedlinePlus

... Cereal en Español Recall and Advice to Consumers, Restaurants and Retailers Case Count Maps Epi Curves Signs & ... Eggs en Español Recalls and Advice to Consumers, Restaurants, and Retailers Case Count Maps Epi Curves Signs & ...

METAL RECOVERY/REMOVAL USING NON-ELECTROLYTIC METAL RECOVERY

EPA Science Inventory

Radiator repair shops most commonly use hot caustic solutions to clean radiator sections prior to resoldering. he hot caustic, or "boil-out" solutions as they are cabled in the trade, become contaminated with dirt, rust flakes, paint flakes and miscellaneous particulate debris. n...

21 CFR 1230.20 - General guaranty.

Code of Federal Regulations, 2011 CFR

2011-04-01

... CAUSTIC POISON ACT Guaranty § 1230.20 General guaranty. In lieu of a particular guaranty for each lot of... to _____ are not misbranded within the meaning of the Federal Caustic Poison Act. (Date) (Signature... Poison Act. (Date) (Signature and address of manufacturer or wholesaler) ...

21 CFR 1230.20 - General guaranty.

Code of Federal Regulations, 2010 CFR

2010-04-01

... CAUSTIC POISON ACT Guaranty § 1230.20 General guaranty. In lieu of a particular guaranty for each lot of... to _____ are not misbranded within the meaning of the Federal Caustic Poison Act. (Date) (Signature... Poison Act. (Date) (Signature and address of manufacturer or wholesaler) ...

21 CFR 1230.20 - General guaranty.

Code of Federal Regulations, 2012 CFR

2012-04-01

... CAUSTIC POISON ACT Guaranty § 1230.20 General guaranty. In lieu of a particular guaranty for each lot of... to _____ are not misbranded within the meaning of the Federal Caustic Poison Act. (Date) (Signature... Poison Act. (Date) (Signature and address of manufacturer or wholesaler) ...

21 CFR 1230.20 - General guaranty.

Code of Federal Regulations, 2013 CFR

2013-04-01

... CAUSTIC POISON ACT Guaranty § 1230.20 General guaranty. In lieu of a particular guaranty for each lot of... to _____ are not misbranded within the meaning of the Federal Caustic Poison Act. (Date) (Signature... Poison Act. (Date) (Signature and address of manufacturer or wholesaler) ...

21 CFR 1230.20 - General guaranty.

Code of Federal Regulations, 2014 CFR

2014-04-01

... CAUSTIC POISON ACT Guaranty § 1230.20 General guaranty. In lieu of a particular guaranty for each lot of... to _____ are not misbranded within the meaning of the Federal Caustic Poison Act. (Date) (Signature... Poison Act. (Date) (Signature and address of manufacturer or wholesaler) ...

Electrochemical sulfide removal and caustic recovery from spent caustic streams.

PubMed

Vaiopoulou, Eleni; Provijn, Thomas; Prévoteau, Antonin; Pikaar, Ilje; Rabaey, Korneel

2016-04-01

Spent caustic streams (SCS) are produced during alkaline scrubbing of sulfide containing sour gases. Conventional methods mainly involve considerable chemical dosing or energy expenditures entailing high cost but limited benefits. Here we propose an electrochemical treatment approach involving anodic sulfide oxidation preferentially to sulfur coupled to cathodic caustic recovery using a two-compartment electrochemical system. Batch experiments showed sulfide removal efficiencies of 84 ± 4% with concomitant 57 ± 4% efficient caustic production in the catholyte at a final concentration of 6.4 ± 0.1 wt% NaOH (1.6 M) at an applied current density of 100 A m(-2). Subsequent long-term continuous experiments showed that stable cell voltages (i.e. 2.7 ± 0.1 V) as well as constant sulfide removal efficiencies of 67 ± 5% at a loading rate of 47 g(S) L(-1) h(-1) were achieved over a period of 77 days. Caustic was produced at industrially relevant strengths for scrubbing (i.e. 5.1 ± 0.9 wt% NaOH) at current efficiencies of 96 ± 2%. Current density between 0 and 200 A m(-2) and sulfide loading rates of 50-200 g(S) L(-1) d(-1) were tested. The higher the current density the more oxidized the sulfur species produced and the higher the sulfide oxidation. On the contrary, high loading rate resulted in a reduction of sulfide oxidation efficiency. The results obtained in this study together with engineering calculations show that the proposed process could represent a cost-effective approach for sodium and sulfur recovery from SCS. Copyright © 2016 Elsevier Ltd. All rights reserved.

The public health impact of pediatric caustic ingestion injuries.

PubMed

Johnson, Christopher M; Brigger, Matthew T

2012-12-01

To determine the current public health burden of injuries due to caustic ingestion in children. The 2009 Kids' Inpatient Database provides data on a sample of all pediatric hospital discharges in the United States during that year. Children with caustic ingestion injuries requiring hospitalization were identified by corresponding codes from the International Classification of Diseases, Ninth Revision. Database analysis generated national estimates of summary statistics. A national database. Representative sample of all hospital discharge data on patients 18 years or younger. Public health burden related to caustic injury, including potential factors related to admission outcome, the necessity of a procedure during the admission, admission length of stay, and total charges for the admission. We estimated the prevalence of pediatric caustic ingestion injuries requiring hospitalization in the United States in 2009 to be 807 (95% CI, 731-882) children. The annual economic burden was estimated at $22 900 000 (95% CI, $15 400 000-$30 400 000) in total hospital charges. The mean charge per patient was estimated at $28 860 (95% CI, $19 799-$37 922) with a median of $9848. The mean length of admission was 4.13 (95% CI, 3.22-5.03) days with a median of 2 days. Among the 807 patients, 45.3% underwent esophagoscopy, and those admitted to teaching hospitals were more likely to undergo a procedure during their stay (P = .02). Logistic regression models suggested significant median income (P < .001) and sex (P < .001) variations. The current public health burden of pediatric caustic ingestion injuries may be less than commonly cited. This finding supports the notion that legislative efforts have been successful. Despite these successes, these injuries continue to impose a significant burden on health care resources.

PEP Support Laboratory Leaching and Permeate Stability Tests

DOE Office of Scientific and Technical Information (OSTI.GOV)

Russell, Renee L.; Peterson, Reid A.; Rinehart, Donald E.

2009-09-25

Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed, and operated as part of a plan to respond to issue M12, "Undemonstrated Leaching Processes," of the External Flowsheet Review Team (EFRT) issue response plan.( ) The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes.more » The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. A simplified flow diagram of the PEP system is shown in Figure 1.1. Two operating scenarios are currently being evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario has caustic leaching performed in the UFP-2 ultrafiltration feed vessels (i.e., vessel UFP-VSL-T02A in the PEP and vessels UFP-VSL-00002A and B in the WTP PTF). The second scenario has caustic leaching conducted in the UFP-1 ultrafiltration feed preparation vessels (i.e., vessels UFP-VSL-T01A and B in the PEP and vessels UFP-VSL-00001A and B in the WTP PTF). In both scenarios, 19-M sodium hydroxide solution (NaOH, caustic) is added to the waste slurry in the vessels to leach solid aluminum compounds (e.g., gibbsite, boehmite). Caustic addition is followed by a heating step that uses direct injection of steam to accelerate the leach process. Following the caustic leach, the vessel contents are cooled using vessel cooling jackets and/or external heat exchangers. The main difference between the two scenarios is that for leaching in UFP-VSL-T01A and B, the 19-M NaOH is added to un-concentrated waste slurry (3 to 8 wt% solids), while for leaching in UFP-VSL-T02A, the slurry is concentrated to nominally 20 wt% solids using cross-flow ultrafiltration before adding caustic.« less

Process for the disposal of alkali metals

DOEpatents

Lewis, Leroy C.

1977-01-01

Large quantities of alkali metals may be safely reacted for ultimate disposal by contact with a hot concentrated caustic solution. The alkali metals react with water in the caustic solution in a controlled reaction while steam dilutes the hydrogen formed by the reaction to a safe level.

Treatment of olefin plant spent caustic by combination of neutralization and Fenton reaction.

PubMed

Sheu, S H; Weng, H S

2001-06-01

Spent caustic from olefin plants contains much H2S and some mercaptans, phenols and oil. A new treatment process of spent caustic by neutralization followed by oxidation with Fenton's reagent (Fe2+/H2O2) was successfully developed. Over 90% of dissolved H2S were converted to gas phase by neutralization at pH = 5 and T = 70 degrees, and the vent gas stream could be introduced to sulfur recovery plant. The neutralized liquid was oxidized with OH. free radical, which was provided by a Fenton's reagent. The residual sulfides in the neutralized spent caustic were oxidized to less than 0.1 mg/L. The total COD removal of spent caustic is over 99.5% and the final COD value of the effluent can be lower than 100 mg/L under the following oxidation conditions: reaction time = 50 min, T = 90 degrees, Fe2+ = 100 mg/L, and a stoichiometric H2O2/COD = 1.1. The value is better than the 800 mg/L value obtained by common WAO process. The optimum pH of the Fenton reaction is around 2 for this process, and the oxidation step can maintain a pH value in the range of 1.8-2.4. Moreover, the iron catalyst can be recycled without affecting process effectiveness thus preventing secondary pollution.

Results Of Routine Strip Effluent Hold Tank, Decontaminated Salt Solution Hold Tank, Caustic Wash Tank And Caustic Storage Tank Samples From Modular Caustic-Side Solvent Extraction Unit During Macrobatch 6 Operations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peters, T. B.

Strip Effluent Hold Tank (SEHT), Decontaminated Salt Solution Hold Tank (DSSHT), Caustic Wash Tank (CWT) and Caustic Storage Tank (CST) samples from several of the ''microbatches'' of Integrated Salt Disposition Project (ISDP) Salt Batch (''Macrobatch'') 6 have been analyzed for {sup 238}Pu, {sup 90}Sr, {sup 137}Cs, and by Inductively Coupled Plasma Emission Spectroscopy (ICPES). The results from the current microbatch samples are similar to those from comparable samples in Macrobatch 5. From a bulk chemical point of view, the ICPES results do not vary considerably between this and the previous macrobatch. The titanium results in the DSSHT samples continue tomore » indicate the presence of Ti, when the feed material does not have detectable levels. This most likely indicates that leaching of Ti from MST in ARP continues to occur. Both the CST and CWT samples indicate that the target Free OH value of 0.03 has been surpassed. While at this time there is no indication that this has caused an operational problem, the CST should be adjusted into specification. The {sup 137}Cs results from the SRNL as well as F/H lab data indicate a potential decline in cesium decontamination factor. Further samples will be carefully monitored to investigate this.« less

40 CFR 63.8184 - What parts of my plant does this subpart cover?

Code of Federal Regulations, 2014 CFR

2014-07-01

... in the manufacture of product chlorine, product caustic, and by-product hydrogen at a plant site. This subpart covers mercury emissions from by-product hydrogen streams, end box ventilation system vents, and fugitive emission sources associated with cell rooms, hydrogen systems, caustic systems, and...

40 CFR 63.8184 - What parts of my plant does this subpart cover?

Code of Federal Regulations, 2011 CFR

2011-07-01

... in the manufacture of product chlorine, product caustic, and by-product hydrogen at a plant site. This subpart covers mercury emissions from by-product hydrogen streams, end box ventilation system vents, and fugitive emission sources associated with cell rooms, hydrogen systems, caustic systems, and...

40 CFR 63.8184 - What parts of my plant does this subpart cover?

Code of Federal Regulations, 2012 CFR

2012-07-01

... in the manufacture of product chlorine, product caustic, and by-product hydrogen at a plant site. This subpart covers mercury emissions from by-product hydrogen streams, end box ventilation system vents, and fugitive emission sources associated with cell rooms, hydrogen systems, caustic systems, and...

40 CFR 63.8184 - What parts of my plant does this subpart cover?

Code of Federal Regulations, 2013 CFR

2013-07-01

... in the manufacture of product chlorine, product caustic, and by-product hydrogen at a plant site. This subpart covers mercury emissions from by-product hydrogen streams, end box ventilation system vents, and fugitive emission sources associated with cell rooms, hydrogen systems, caustic systems, and...

EFRT M12 Issue Resolution: Comparison of PEP and Bench-Scale Oxidative Leaching Results

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rapko, Brian M.; Brown, Christopher F.; Eslinger, Paul W.

2009-08-14

Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed and constructed and is to be operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes.” The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processesmore » using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing. Two operating scenarios are currently being evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario has caustic leaching performed in the UFP-2 ultrafiltration feed vessels (i.e., vessel UFP-VSL-T02A in the PEP; and vessels UFP-VSL-00002A and B in the WTP PTF). The second scenario has caustic leaching conducted in the UFP-1 ultrafiltration feed preparation vessels (i.e., vessels UFP-VSL-T01A and B in the PEP; vessels UFP-VSL-00001A and B in the WTP PTF). In both scenarios, 19-M sodium hydroxide solution (NaOH, caustic) is added to the waste slurry in the vessels to dissolve solid aluminum compounds (e.g., gibbsite, boehmite). Caustic addition is followed by a heating step that uses direct steam injection to accelerate the leaching process. Following the caustic leach, the vessel contents are cooled using vessel cooling jackets and/or external heat exchangers. The main difference between the two scenarios is that for leaching in UFP1, the 19-M NaOH is added to un-concentrated waste slurry (3 to 8 wt% solids), while for leaching in UFP2, the slurry is concentrated to nominally 20 wt% solids using cross-flow ultrafiltration before the addition of caustic. For wastes that have significantly high chromium content, the caustic leaching and slurry dewatering is followed by adding sodium permanganate to UFP-VSL-T02A, and the slurry is subjected to oxidative leaching at nominally ambient temperature. The purpose of the oxidative leaching is to selectively oxidize the poorly alkaline-soluble Cr(III) believed to be the insoluble form in Hanford tank sludge to the much more alkaline-soluble Cr(VI), e.g., chromate. The work described in this report provides the test results that are related to the efficiency of the oxidative leaching process to support process modeling based on tests performed with a Hanford waste simulant. The tests were completed both at the lab-bench scale and in the PEP. The purpose of this report is to summarize the results from both scales that are related to oxidative leaching chemistry to support a scale factor for the submodels to be used in the G2 model, which predicts WTP operating performance. Owing to schedule constraints, the PEP test data to be included in this report are limited to those from Integrated Tests A (T01 A/B caustic leaching) and B (T02A caustic leaching).« less

A comparison of spatial analysis methods for the construction of topographic maps of retinal cell density.

PubMed

Garza-Gisholt, Eduardo; Hemmi, Jan M; Hart, Nathan S; Collin, Shaun P

2014-01-01

Topographic maps that illustrate variations in the density of different neuronal sub-types across the retina are valuable tools for understanding the adaptive significance of retinal specialisations in different species of vertebrates. To date, such maps have been created from raw count data that have been subjected to only limited analysis (linear interpolation) and, in many cases, have been presented as iso-density contour maps with contour lines that have been smoothed 'by eye'. With the use of stereological approach to count neuronal distribution, a more rigorous approach to analysing the count data is warranted and potentially provides a more accurate representation of the neuron distribution pattern. Moreover, a formal spatial analysis of retinal topography permits a more robust comparison of topographic maps within and between species. In this paper, we present a new R-script for analysing the topography of retinal neurons and compare methods of interpolating and smoothing count data for the construction of topographic maps. We compare four methods for spatial analysis of cell count data: Akima interpolation, thin plate spline interpolation, thin plate spline smoothing and Gaussian kernel smoothing. The use of interpolation 'respects' the observed data and simply calculates the intermediate values required to create iso-density contour maps. Interpolation preserves more of the data but, consequently includes outliers, sampling errors and/or other experimental artefacts. In contrast, smoothing the data reduces the 'noise' caused by artefacts and permits a clearer representation of the dominant, 'real' distribution. This is particularly useful where cell density gradients are shallow and small variations in local density may dramatically influence the perceived spatial pattern of neuronal topography. The thin plate spline and the Gaussian kernel methods both produce similar retinal topography maps but the smoothing parameters used may affect the outcome.

Time delay of critical images of a point source near the gravitational lens fold-caustic

NASA Astrophysics Data System (ADS)

Alexandrov, A.; Zhdanov, V.

2016-06-01

Within the framework of the analytical theory of the gravitational lensing we derive asymptotic formula for the time delay of critical images of apoint source, which is situated near a fold-caustic. We found corrections of the first and second order in powers of a parameter, which describescloseness of the source to the caustic. Our formula modifies earlier result by Congdon, Keeton &Nordgren (MNRAS, 2008) obtained in zero-orderapproximation. We have proved the hypothesis put forward by these authors that the first-order correction to the relative time delay of two criticalmages is identically zero. The contribution of the corrections is illustrated in model example by comparison with exact expression.

A Medical Monitoring Program for the Marine Hazardous Chemical Worker. Volume 1

DTIC Science & Technology

1985-12-01

ri-CR ESOL CRL 0 O-CRESOL CSL 0 P-CRESOL CSO 0 C RE SOL S CRS 0 CRESYLATE SPENT CAUSTIC CSC 0 CROTONALDEH’YDE CTA -0 C UPINE cuml 0 CYCLOHEXANE CHX 0...BLACk BASE 0 CARBON DISULIFIDE CBS 0 CARBON MONOG IDE CARBON TETRACHLORIDE CST 0 CAUSTIC POTASH SOLUTION CPS a CAUSTIC SODA SOLUTION CSS 0 CETYL ALCOHOL...HXN D 1 -𔃾.AENE HXE Ci HEXYLENE *;i -COL HX(G 0 H, TrClCHL0 . ACID 14CL 13 H’vDPC-wLO’.. ACID. SPENT (15%. OP LESS) Hcs C) HYSý90F! tOJCQ AC 10 HFA 0 H

Comparison of point counts and territory mapping for detecting effects of forest management on songbirds

USGS Publications Warehouse

Newell, Felicity L.; Sheehan, James; Wood, Petra Bohall; Rodewald, Amanda D.; Buehler, David A.; Keyser, Patrick D.; Larkin, Jeffrey L.; Beachy, Tiffany A.; Bakermans, Marja H.; Boves, Than J.; Evans, Andrea; George, Gregory A.; McDermott, Molly E.; Perkins, Kelly A.; White, Matthew; Wigley, T. Bently

2013-01-01

Point counts are commonly used to assess changes in bird abundance, including analytical approaches such as distance sampling that estimate density. Point-count methods have come under increasing scrutiny because effects of detection probability and field error are difficult to quantify. For seven forest songbirds, we compared fixed-radii counts (50 m and 100 m) and density estimates obtained from distance sampling to known numbers of birds determined by territory mapping. We applied point-count analytic approaches to a typical forest management question and compared results to those obtained by territory mapping. We used a before–after control impact (BACI) analysis with a data set collected across seven study areas in the central Appalachians from 2006 to 2010. Using a 50-m fixed radius, variance in error was at least 1.5 times that of the other methods, whereas a 100-m fixed radius underestimated actual density by >3 territories per 10 ha for the most abundant species. Distance sampling improved accuracy and precision compared to fixed-radius counts, although estimates were affected by birds counted outside 10-ha units. In the BACI analysis, territory mapping detected an overall treatment effect for five of the seven species, and effects were generally consistent each year. In contrast, all point-count methods failed to detect two treatment effects due to variance and error in annual estimates. Overall, our results highlight the need for adequate sample sizes to reduce variance, and skilled observers to reduce the level of error in point-count data. Ultimately, the advantages and disadvantages of different survey methods should be considered in the context of overall study design and objectives, allowing for trade-offs among effort, accuracy, and power to detect treatment effects.

40 CFR 63.1082 - What definitions do I need to know?

Code of Federal Regulations, 2011 CFR

2011-07-01

... includes direct-contact cooling water. Spent caustic waste stream means the continuously flowing process... compounds from process streams, typically cracked gas. The spent caustic waste stream does not include spent..., and the C4 butadiene storage equipment; and spent wash water from the C4 crude butadiene carbonyl wash...

40 CFR 63.1082 - What definitions do I need to know?

Code of Federal Regulations, 2012 CFR

2012-07-01

... includes direct-contact cooling water. Spent caustic waste stream means the continuously flowing process... compounds from process streams, typically cracked gas. The spent caustic waste stream does not include spent..., and the C4 butadiene storage equipment; and spent wash water from the C4 crude butadiene carbonyl wash...

40 CFR 63.1082 - What definitions do I need to know?

Code of Federal Regulations, 2014 CFR

2014-07-01

... includes direct-contact cooling water. Spent caustic waste stream means the continuously flowing process... compounds from process streams, typically cracked gas. The spent caustic waste stream does not include spent..., and the C4 butadiene storage equipment; and spent wash water from the C4 crude butadiene carbonyl wash...

40 CFR 63.1082 - What definitions do I need to know?

Code of Federal Regulations, 2013 CFR

2013-07-01

... includes direct-contact cooling water. Spent caustic waste stream means the continuously flowing process... compounds from process streams, typically cracked gas. The spent caustic waste stream does not include spent..., and the C4 butadiene storage equipment; and spent wash water from the C4 crude butadiene carbonyl wash...

Evaluation of Military Field-Water Quality. Volume 3. Opportunity Poisons

DTIC Science & Technology

1987-12-01

Acidic chemical cleaners fluoric acid, nitric acid, perchloric Spent acid acid, sulfuric acid Alkalies Miscellaneous caustic products Ammonia, lime...calcium oxide), potassium Alkaline battery fluid hydroxide, sodium hydroxide, sodium Caustic wastewater silicate Cleaning solutions Lye Nonhalogenated...Laboratory chemicals chloride, polychlorinated biphenyls, zinc Paint and varnish removers naphthenate , copper naphthenate , dichloro- Capacitors and

21 CFR 184.1763 - Sodium hydroxide.

Code of Federal Regulations, 2012 CFR

2012-04-01

... 21 Food and Drugs 3 2012-04-01 2012-04-01 false Sodium hydroxide. 184.1763 Section 184.1763 Food... Specific Substances Affirmed as GRAS § 184.1763 Sodium hydroxide. (a) Sodium hydroxide (NaOH, CAS Reg. No. 1310-73-2) is also known as sodium hydrate, soda lye, caustic soda, white caustic, and lye. The...

21 CFR 184.1763 - Sodium hydroxide.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 21 Food and Drugs 3 2013-04-01 2013-04-01 false Sodium hydroxide. 184.1763 Section 184.1763 Food... Specific Substances Affirmed as GRAS § 184.1763 Sodium hydroxide. (a) Sodium hydroxide (NaOH, CAS Reg. No. 1310-73-2) is also known as sodium hydrate, soda lye, caustic soda, white caustic, and lye. The...

21 CFR 184.1763 - Sodium hydroxide.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Sodium hydroxide. 184.1763 Section 184.1763 Food... Specific Substances Affirmed as GRAS § 184.1763 Sodium hydroxide. (a) Sodium hydroxide (NaOH, CAS Reg. No. 1310-73-2) is also known as sodium hydrate, soda lye, caustic soda, white caustic, and lye. The...

21 CFR 184.1763 - Sodium hydroxide.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 21 Food and Drugs 3 2011-04-01 2011-04-01 false Sodium hydroxide. 184.1763 Section 184.1763 Food... Specific Substances Affirmed as GRAS § 184.1763 Sodium hydroxide. (a) Sodium hydroxide (NaOH, CAS Reg. No. 1310-73-2) is also known as sodium hydrate, soda lye, caustic soda, white caustic, and lye. The...

Letter from Galo Jackson, USEPA to Prashant Gupta, Honeywell, Inc. Subject: Caustic Brine Offsite Shipments: LCP Chemical National Priorities List Site, Brunswick, Glynn County, GA

EPA Pesticide Factsheets

Feb. 17, 2012 letter about suspending all shipments of caustic brine from the LCP Chemicals site to the Water Recovery, Inc. facility in Jacksonville, FL. Region ID: 04 DocID: 10843423, DocDate: 02-17-2012

Flight test measurements and analysis of sonic boom phenomena near the shock wave extremity

NASA Technical Reports Server (NTRS)

Haglund, G. T.; Kane, E. J.

1973-01-01

The sonic boom flight test program conducted at Jackass Flats, Nevada, during the summer and fall of 1970 consisted of 121 sonic-boom-generating flights over the 1500 ft instrumented BREN tower. This test program was designed to provide information on several aspects of sonic boom, including caustics produced by longitudinal accelerations, caustics produced by steady flight near the threshold Mach number, sonic boom characteristics near lateral cutoff, and the vertical extent of shock waves attached to near-sonic airplanes. The measured test data, except for the near-sonic flight data, were analyzed in detail to determine sonic boom characteristics for these flight conditions and to determine the accuracy and the range of validity of linear sonic boom theory. The caustic phenomena observed during the threshold Mach number flights and during the transonic acceleration flights are documented and analyzed in detail. The theory of geometric acoustics is shown to be capable of predicting shock wave-ground intersections, and current methods for calculating sonic boom pressure signature away from caustics are shown to be reasonably accurate.

An Embodiment Perspective on Number-Space Mapping in 3.5-Year-Old Dutch Children.

PubMed

van 't Noordende, Jaccoline E; Volman, M Chiel J M; Leseman, Paul P M; Kroesbergen, Evelyn H

2017-01-01

Previous research suggests that block adding, subtracting and counting direction are early forms of number-space mapping. In this study, an embodiment perspective on these skills was taken. Embodiment theory assumes that cognition emerges through sensory-motor interaction with the environment. In line with this assumption, it was investigated if counting and adding/subtracting direction in young children is related to the hand they use during task performance. Forty-eight 3.5-year-old children completed a block adding, subtracting and counting task. They had to add and remove a block from a row of three blocks and count a row of five blocks. Adding, subtracting and counting direction were related to the hand the children used for task performance. Most children who used their right hand added, removed and started counting the blocks at the right side of the row. Most children who used their left hand added, removed and started counting the blocks at the left side of the row. It can be concluded that number-space mapping, as measured by direction of adding, subtracting and counting blocks, in young children is embodied: It is not fixed, but is related to the situation. © 2016 The Authors Infant and Child Development Published by John Wiley & Sons, Ltd.

Feasibility Study of an Optical Caustic Plasmonic Light Scattering Sensor for Human Serum Anti-Dengue Protein E Antibody Detection

PubMed Central

García, Antonio A.; Pirez-Gomez, Miguel A.; Pech-Pacheco, José L.; Mendez-Galvan, Jorge F.; Machain-Williams, Carlos; Talavera-Aguilar, Lourdes; Espinosa-Carrillo, José H.; Duarte-Villaseñor, Miriam M.; Be-Ortiz, Christian; Espinosa-de los Monteros, Luz E.; Castillo-Pacheco, Ariel; Garcia-Rejon, Julian E.

2017-01-01

Antibody detection and accurate diagnosis of tropical diseases is essential to help prevent the spread of disease. However, most detection methods lack cost-effectiveness and field portability, which are essential features for achieving diagnosis in a timely manner. To address this, 3D-printed oblate spheroid sample chambers were fabricated to measure green light scattering of gold nanoparticles using an optical caustic focus to detect antibodies. Scattering signals of 20–200 nm gold nanoparticles using a green laser were compared to green light emitting diode (LED) light source signals and to Mie theory. The change in signal from 60 to 120 nm decreased in the order of Mie Theory > optical caustic scattering > 90° scattering. These results suggested that conjugating 60 nm gold nanoparticles and using an optical caustic system to detect plasmonic light scattering, would result in a sensitive test for detecting human antibodies in serum. Therefore, we studied the light scattering response of conjugated gold nanoparticles exposed to different concentrations of anti-protein E antibody, and a feasibility study of 10 human serum samples using dot blot and a handheld optical caustic-based sensor device. The overall agreement between detection methods suggests that the new sensor concept shows promise to detect gold nanoparticle aggregation in a homogeneous assay. Further testing and protocol optimization is needed to draw conclusions on the positive and negative predictive values for this new testing system. PMID:28817080

Preverbal and verbal counting and computation.

PubMed

Gallistel, C R; Gelman, R

1992-08-01

We describe the preverbal system of counting and arithmetic reasoning revealed by experiments on numerical representations in animals. In this system, numerosities are represented by magnitudes, which are rapidly but inaccurately generated by the Meck and Church (1983) preverbal counting mechanism. We suggest the following. (1) The preverbal counting mechanism is the source of the implicit principles that guide the acquisition of verbal counting. (2) The preverbal system of arithmetic computation provides the framework for the assimilation of the verbal system. (3) Learning to count involves, in part, learning a mapping from the preverbal numerical magnitudes to the verbal and written number symbols and the inverse mappings from these symbols to the preverbal magnitudes. (4) Subitizing is the use of the preverbal counting process and the mapping from the resulting magnitudes to number words in order to generate rapidly the number words for small numerosities. (5) The retrieval of the number facts, which plays a central role in verbal computation, is mediated via the inverse mappings from verbal and written numbers to the preverbal magnitudes and the use of these magnitudes to find the appropriate cells in tabular arrangements of the answers. (6) This model of the fact retrieval process accounts for the salient features of the reaction time differences and error patterns revealed by experiments on mental arithmetic. (7) The application of verbal and written computational algorithms goes on in parallel with, and is to some extent guided by, preverbal computations, both in the child and in the adult.

Risk factors associated with refractoriness to esophageal dilatation for benign dysphagia.

PubMed

Rodrigues-Pinto, Eduardo; Pereira, Pedro; Ribeiro, Armando; Lopes, Susana; Moutinho-Ribeiro, Pedro; Silva, Marco; Peixoto, Armando; Gaspar, Rui; Macedo, Guilherme

2016-06-01

Benign esophageal strictures need repeated dilatations to relieve dysphagia. Literature is scarce on the risk factors for refractoriness of these strictures. This study aimed to assess the risk factors associated with refractory strictures. This is a retrospective study of patients with benign esophageal strictures who were referred for esophageal dilatation over a period of 3 years. A total of 327 esophageal dilatations were performed in 103 patients; 53% of the patients reported dysphagia for liquids. Clinical success was achieved in 77% of the patients. There was a need for further dilatations in 54% of patients, being more frequent in patients with dysphagia for liquids [78 vs. 64%, P=0.008, odds ratio (OR) 1.930], in those with caustic strictures (89 vs. 70%, P=0.007, OR 3.487), and in those with complex strictures (83 vs. 70%, P=0.047, OR 2.132). Caustic strictures, peptic strictures, and complex strictures showed statistical significance in the multivariate analysis. Time until subsequent dilatations was less in patients with dysphagia for liquids (49 vs. 182 days, P<0.001), in those with peptic strictures (49 vs. 98 days, P=0.004), in those with caustic strictures (49 vs. 78 days, P=0.005), and in patients with complex strictures (47 vs. 80 days P=0.009). In multivariate analysis, further dilatations occurred earlier in patients with dysphagia for liquids [hazard ratio (HR) 1.506, P=0.004], in those with peptic strictures (HR 1.644, P=0.002), in those with caustic strictures (HR 1.581, P=0.016), and in patients with complex strictures (HR 1.408, P=0.046). Caustic, peptic, and complex strictures were associated with a greater need for subsequent dilatations. Time until subsequent dilatations was less in patients with dysphagia for liquids and in those with caustic, peptic, and complex strictures.

A geochemical module for "AMDTreat" to compute caustic quantity, effluent quantity, and sludge volume

USGS Publications Warehouse

Cravotta, Charles A.; Parkhurst, David L.; Means, Brent P; McKenzie, Bob; Morris, Harry; Arthur, Bill

2010-01-01

Treatment with caustic chemicals typically is used to increase pH and decrease concentrations of dissolved aluminum, iron, and/or manganese in largevolume, metal-laden discharges from active coal mines. Generally, aluminum and iron can be removed effectively at near-neutral pH (6 to 8), whereas active manganese removal requires treatment to alkaline pH (~10). The treatment cost depends on the specific chemical used (NaOH, CaO, Ca(OH)2, Na2CO3, or NH3) and increases with the quantities of chemical added and sludge produced. The pH and metals concentrations do not change linearly with the amount of chemical added. Consequently, the amount of caustic chemical needed to achieve a target pH and the corresponding effluent composition and sludge volume can not be accurately determined without empirical titration data or the application of geochemical models to simulate the titration of the discharge water with caustic chemical(s). The AMDTreat computer program (http://amd.osmre.gov/ ) is widely used to compute costs for treatment of coal-mine drainage. Although AMDTreat can use results of empirical titration with industrial grade caustic chemicals to compute chemical costs for treatment of net-acidic or net-alkaline mine drainage, such data are rarely available. To improve the capability of AMDTreat to estimate (1) the quantity and cost of caustic chemicals to attain a target pH, (2) the concentrations of dissolved metals in treated effluent, and (3) the volume of sludge produced by the treatment, a titration simulation is being developed using the geochemical program PHREEQC (wwwbrr.cr.usgs.gov/projects/GWC_coupled/phreeqc/) that will be coupled as a module to AMDTreat. The simulated titration results can be compared with or used in place of empirical titration data to estimate chemical quantities and costs. This paper describes the development, evaluation, and potential utilization of the PHREEQC titration module for AMDTreat.

Backscattering of sound from targets in an Airy caustic formed by a curved reflecting surface

NASA Astrophysics Data System (ADS)

Dzikowicz, Benjamin Robert

The focusing of a caustic associated with the reflection of a locally curved sea floor or surface affects the scattering of sound by underwater targets. The most elementary caustic formed when sound reflects off a naturally curved surface is an Airy caustic. The case of a spherical target is examined here. With a point source acting also as a receiver, a point target lying in a shadow region returns only one echo directly from the target. When the target is on the Airy caustic, there are two echoes: one path is directly to the target and the other focuses off the curved surface. Echoes may be focused in both directions, the doubly focused case being the largest and the latest echo. With the target in the lit region, these different paths produce multiple echoes. For a finite sized sphere near an Airy caustic, all these echoes are manifest, but they occur at shifted target positions. Echoes of tone bursts reflecting only once overlap and interfere with each other, as do those reflecting twice. Catastrophe theory is used to analyze the echo amplitudes arising from these overlaps. The echo pressure for single reflections is shown to have a dependence on target position described by an Airy function for both a point and a finite target. With double focusing, this dependence is the square of an Airy function for a point target. With a finite sized target, (as in the experiment) this becomes a hyperbolic umbilic catastrophe integral with symmetric arguments. The arguments of each of these functions are derived from only the relative echo times of a transient pulse. Transient echo times are calculated using a numerical ray finding technique. Experiment confirms the predicted merging of transient echoes in the time domain, as well as the Airy and hyperbolic umbilic diffraction integral amplitudes for a tone burst. This method allows targets to be observed at greater distances in the presence of a focusing surface.

A uniform geometrical optics and an extended uniform geometrical theory of diffraction for evaluating high frequency EM fields near smooth caustics and composite shadow boundaries

NASA Technical Reports Server (NTRS)

Constantinides, E. D.; Marhefka, R. J.

1994-01-01

A uniform geometrical optics (UGO) and an extended uniform geometrical theory of diffraction (EUTD) are developed for evaluating high frequency electromagnetic (EM) fields within transition regions associated with a two and three dimensional smooth caustic of reflected rays and a composite shadow boundary formed by the caustic termination or the confluence of the caustic with the reflection shadow boundary (RSB). The UGO is a uniform version of the classic geometrical optics (GO). It retains the simple ray optical expressions of classic GO and employs a new set of uniform reflection coefficients. The UGO also includes a uniform version of the complex GO ray field that exists on the dark side of the smooth caustic. The EUTD is an extension of the classic uniform geometrical theory of diffraction (UTD) and accounts for the non-ray optical behavior of the UGO reflected field near caustics by using a two-variable transition function in the expressions for the edge diffraction coefficients. It also uniformly recovers the classic UTD behavior of the edge diffracted field outside the composite shadow boundary transition region. The approach employed for constructing the UGO/EUTD solution is based on a spatial domain physical optics (PO) radiation integral representation for the fields which is then reduced using uniform asymptotic procedures. The UGO/EUTD analysis is also employed to investigate the far-zone RCS problem of plane wave scattering from two and three dimensional polynomial defined surfaces, and uniform reflection, zero-curvature, and edge diffraction coefficients are derived. Numerical results for the scattering and diffraction from cubic and fourth order polynomial strips are also shown and the UGO/EUTD solution is validated by comparison to an independent moment method (MM) solution. The UGO/EUTD solution is also compared with the classic GO/UTD solution. The failure of the classic techniques near caustics and composite shadow boundaries is clearly demonstrated and it is shown that the UGO/EUTD results remain valid and uniformly reduce to the classic results away from the transition regions. Mathematical details on the asymptotic properties and efficient numerical evaluation of the canonical functions involved in the UGO/EUTD expressions are also provided.

Development of spatial preferences for counting and picture naming.

PubMed

Knudsen, Birgit; Fischer, Martin H; Aschersleben, Gisa

2015-11-01

The direction of object enumeration reflects children's enculturation but previous work on the development of such spatial preferences has been inconsistent. Therefore, we documented directional preferences in finger counting, object counting, and picture naming for children (4 groups from 3 to 6 years, N = 104) and adults (N = 56). We found a right-side preference for finger counting in 3- to 6-year-olds and a left-side preference for counting objects and naming pictures by 6 years of age. Children were consistent in their special preferences when comparing object counting and picture naming, but not in other task pairings. Finally, spatial preferences were not related to cardinality comprehension. These results, together with other recent work, suggest a gradual development of spatial-numerical associations from early non-directional mappings into culturally constrained directional mappings.

High-Sensitivity High-Speed X-ray Fluorescence Scanning Cadmium Telluride Detector for Deep-Portion Cancer Diagnosis Utilizing Tungsten-Kα-Excited Gadolinium Mapping

NASA Astrophysics Data System (ADS)

Yanbe, Yutaka; Sato, Eiichi; Chiba, Hiraku; Maeda, Tomoko; Matsushita, Ryo; Oda, Yasuyuki; Hagiwara, Osahiko; Matsukiyo, Hiroshi; Osawa, Akihiro; Enomoto, Toshiyuki; Watanabe, Manabu; Kusachi, Shinya; Sato, Shigehiro; Ogawa, Akira

2013-09-01

X-ray fluorescence (XRF) analysis is useful for mapping various atoms in objects. Bremsstrahlung X-rays with energies beyond tantalum (Ta) K-edge energy 67.4 keV are absorbed effectively using a 100-µm-thick Ta filter, and the filtered X-rays including tungsten (W) Kα rays are absorbed by gadolinium (Gd) atoms in objects. The Gd XRF is then produced from Gd atoms in the objects and is counted by a cadmium telluride (CdTe) detector. Gd Kα photons with a maximum count rate of 1 kilo counts per second are dispersed using a multichannel analyzer, and the number of photons is counted by a counter card. The distance between the CdTe detector and the object is minimized to 40 mm to increase the count rate. The object is scanned using an x-y stage with a velocity of 5.0 mm/s, and Gd mapping are shown on a computer monitor. The scan steps of the x- and y-axes were both 2.5 mm, and the photon-counting time per mapping point was 0.5 s. We obtained Gd XRF images at high contrast, and Gd Kα photons were easily detected from cancerous regions in a nude mouse placed behind a 20-mm-thick poly(methyl methacrylate) plate.

Chemical cleaning of coal by molten caustic leaching after pretreatment by low-temperature devolatilization

DOEpatents

Chriswell, Colin D.; Kaushik, Surender M.; Shah, Navin D.; Markuszewski, Richard

1989-08-22

Pretreatment of coal by devolatization at temperatures ranging from about 420.degree. C. to about 450.degree. C. for from about 10 minutes to about 30 minutes before leaching with molten caustic leads to a significant reduction in carbonate formation, greatly reducing the cost of cleaning coal on a per ton basis.

4. Photocopy of photograph, U.S. Army, ca. 1943 (original print ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. Photocopy of photograph, U.S. Army, ca. 1943 (original print located at Rocky Mountain Arsenal, Commerce City, Colorado). R.M.A. - 254 - CAUSTIC FUSION BLDG. LOOKING WEST. NORTH SIDE. - Rocky Mountain Arsenal, Caustic Fusion Building, 450 feet South of December Seventh Avenue; 900 feet West of D Street, Commerce City, Adams County, CO

3. Photocopy of photograph, U.S. Army, ca. 1943 (original print ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

3. Photocopy of photograph, U.S. Army, ca. 1943 (original print located at Rocky Mountain Arsenal, Commerce City, Colorado). R.M.A. - 254 - CAUSTIC FUSION BLDG. LOOKING N.W. - Rocky Mountain Arsenal, Caustic Fusion Building, 450 feet South of December Seventh Avenue; 900 feet West of D Street, Commerce City, Adams County, CO

21 CFR 184.1763 - Sodium hydroxide.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 21 Food and Drugs 3 2014-04-01 2014-04-01 false Sodium hydroxide. 184.1763 Section 184.1763 Food... GRAS § 184.1763 Sodium hydroxide. (a) Sodium hydroxide (NaOH, CAS Reg. No. 1310-73-2) is also known as sodium hydrate, soda lye, caustic soda, white caustic, and lye. The empirical formula is NaOH. Sodium...

Aspects of Motor Performance and Preacademic Learning.

ERIC Educational Resources Information Center

Feder, Katya; Kerr, Robert

1996-01-01

The Miller Assessment for Preschoolers (MAP) and a number/counting test were given to 50 4- and 5-year-olds. Low performance on counting was related to significantly slower average response time, overshoot movement time, and reaction time, indicating perceptual-motor difficulty. Low MAP scores indicated difficulty processing visual spatial…

Children's Mappings of Large Number Words to Numerosities

ERIC Educational Resources Information Center

Barth, Hilary; Starr, Ariel; Sullivan, Jessica

2009-01-01

Previous studies have suggested that children's learning of the relation between number words and approximate numerosities depends on their verbal counting ability, and that children exhibit no knowledge of mappings between number words and approximate numerical magnitudes for number words outside their productive verbal counting range. In the…

Detection of Mycobacterium avium subspecies paratuberculosis specific IS900 insertion sequences in bulk-tank milk samples obtained from different regions throughout Switzerland

PubMed Central

Corti, Sabrina; Stephan, Roger

2002-01-01

Background Since Mycobacterium avium subspecies paratuberculosis (MAP) was isolated from intestinal tissue of a human patient suffering Crohn's disease, a controversial discussion exists whether MAP have a role in the etiology of Crohn's disease or not. Raw milk may be a potential vehicle for the transmission of MAP to human population. In a previous paper, we have demonstrated that MAP are found in raw milk samples obtained from a defined region in Switzerland. The aim of this work is to collect data about the prevalence of MAP specific IS900 insertion sequence in bulk-tank milk samples in different regions of Switzerland. Furthermore, we examined eventual correlation between the presence of MAP and the somatic cell counts, the total colony counts and the presence of Enterobacteriaceae. Results 273 (19.7%) of the 1384 examined bulk-tank milk samples tested IS900 PCR-positive. The prevalence, however, in the different regions of Switzerland shows significant differences and ranged from 1.7% to 49.2%. Furthermore, there were no statistically significant (p >> 0.05) differences between the somatic cell counts and the total colony counts of PCR-positive and PCR-negative milk samples. Enterobacteriaceae occur as often in IS900 PCR-positive as in PCR-negative milk samples. Conclusion This is the first study, which investigates the prevalence of MAP in bulk-tank milk samples all over Switzerland and infers the herd-level prevalence of MAP infection in dairy herds. The prevalence of 19.7% IS900 PCR-positive bulk-milk samples shows a wide distribution of subclinical MAP-infections in dairy stock in Switzerland. MAP can therefore often be transmitted to humans by raw milk consumption. PMID:12097144

On the Observability of Individual Population III Stars and Their Stellar-mass Black Hole Accretion Disks through Cluster Caustic Transits

NASA Astrophysics Data System (ADS)

Windhorst, Rogier A.; Timmes, F. X.; Wyithe, J. Stuart B.; Alpaslan, Mehmet; Andrews, Stephen K.; Coe, Daniel; Diego, Jose M.; Dijkstra, Mark; Driver, Simon P.; Kelly, Patrick L.; Kim, Duho

2018-02-01

We summarize panchromatic Extragalactic Background Light data to place upper limits on the integrated near-infrared surface brightness (SB) that may come from Population III stars and possible accretion disks around their stellar-mass black holes (BHs) in the epoch of First Light, broadly taken from z ≃ 7–17. Theoretical predictions and recent near-infrared power spectra provide tighter constraints on their sky signal. We outline the physical properties of zero-metallicity Population III stars from MESA stellar evolution models through helium depletion and of BH accretion disks at z≳ 7. We assume that second-generation non-zero-metallicity stars can form at higher multiplicity, so that BH accretion disks may be fed by Roche-lobe overflow from lower-mass companions. We use these near-infrared SB constraints to calculate the number of caustic transits behind lensing clusters that the James Webb Space Telescope and the next-generation ground-based telescopes may observe for both Population III stars and their BH accretion disks. Typical caustic magnifications can be μ ≃ {10}4{--}{10}5, with rise times of hours and decline times of ≲ 1 year for cluster transverse velocities of {v}T≲ 1000 km s‑1. Microlensing by intracluster-medium objects can modify transit magnifications but lengthen visibility times. Depending on BH masses, accretion-disk radii, and feeding efficiencies, stellar-mass BH accretion-disk caustic transits could outnumber those from Population III stars. To observe Population III caustic transits directly may require monitoring 3–30 lensing clusters to {AB}≲ 29 mag over a decade.

Preliminary study of efficacy of hyaluronic acid on caustic esophageal burns in an experimental rat model.

PubMed

Cevik, Muazez; Demir, Tuncer; Karadag, Cetin Ali; Ketani, Muzaffer Aydin; Celik, Hakim; Kaplan, Davut Sinan; Boleken, Mehmet Emin

2013-04-01

The aim of this study was to investigate the effectiveness of hyaluronic acid on the prevention of esophageal damage and stricture formation after experimental caustic (alkaline) esophageal injury in rats. Twenty-one Wistar albino rats were randomly divided into three groups. A caustic esophageal burn was created following the Gehanno model: Group l (n=7) underwent operation, but no injury; Group 2 (n=7) was injured and left untreated; and Group 3 (n=7) was injured and treated with hyaluronic acid, first topically and then orally by gavage (2×0.3mL; 12.5mg/mL for 7days). The caustic esophageal burn was created by instilling 25% NaOH into the distal esophagus. All rats were euthanized on day 22 for evaluation. The efficacy of hyaluronic acid treatment was assessed histopathologically and biochemically via blood determination of the total antioxidant status (TAS), total oxidant status (TOS), oxidative stress index (OSI), and sulfhydryl group (SH) and lipid hydroperoxidase (LOOH) levels. Statistical analyses were performed. Weight gain was significantly lower in Group 2 than in the other two groups (P<0.05). The mean stenosis index, histopathologic damage score, TAS, TOS, OSI, and SH and LOOH levels were higher in Group 2 than in the other two groups. The mean stenosis index, inflammation, TAS, SH and OSI in Group 2 were significantly different than those in the other two groups (P<0.05). Hyaluronic acid treatment is effective in treating damage and preventing strictures after caustic esophageal burn in rats. Copyright © 2013 Elsevier Inc. All rights reserved.

Revealing stellar brightness profiles by means of microlensing fold caustics

NASA Astrophysics Data System (ADS)

Dominik, M.

2004-09-01

With a handful of measurements of limb-darkening coefficients, galactic microlensing has already proven to be a powerful technique for studying atmospheres of distant stars. Survey campaigns such as OGLE-III are capable of providing ~10 suitable target stars per year that undergo microlensing events involving passages over the caustic created by a binary lens, which last from a few hours to a few days and allow us to resolve the stellar atmosphere by frequent broad-band photometry. For a caustic exit lasting 12 h and a photometric precision of 1.5 per cent, a moderate sampling interval of 30 min (corresponding to ~25-30 data points) is sufficient for providing a reliable measurement of the linear limb-darkening coefficient Γ with an uncertainty of ~8 per cent, which reduces to ~3 per cent for a reduced sampling interval of 6 min for the surroundings of the end of the caustic exit. While some additional points over the remaining parts of the light curve are highly valuable, a denser sampling in these regions provides little improvement. Unless an accuracy of less than 5 per cent is desired, limb-darkening coefficients for several filters can be obtained or observing time can be spent on other targets during the same night. The adoption of an inappropriate stellar brightness profile as well as the effect of acceleration between source and caustic yield distinguishable characteristic systematics in the model residuals. Acceleration effects are unlikely to affect the light curve significantly for most events, although a free acceleration parameter blurs the limb-darkening measurement if the passage duration cannot be accurately determined.

Hematology of the Pascagoula map turtle (Graptemys gibbonsi) and the southeast Asian box turtle (Cuora amboinensis).

PubMed

Perpiñán, David; Hernandez-Divers, Sonia M; Latimer, Kenneth S; Akre, Thomas; Hagen, Chris; Buhlmann, Kurt A; Hernandez-Divers, Stephen J

2008-09-01

Turtle populations are decreasing dramatically due to habitat loss and collection for the food and pet market. This study sought to determine hematologic values in two species of turtles to help assess health status of captive and wild populations. Blood samples were collected from 12 individuals of the Pascagoula map turtle (Graptemys gibbonsi) and seven individuals of the southeast Asian box turtle (Cuora amboinensis) from the Savannah River Ecology Laboratory (South Carolina, USA). The hematologic data included hematocrit, total solids, erythrocyte count, leukocyte count, and differential and percentage leukocyte counts. Low hematocrit values and high basophil counts were found in both species. The basophil was the most abundant leukocyte in the Pascagoula map turtle (median = 0.80 x 10(9)/L), whereas in the Southeast Asian box turtle the most abundant leukocyte was the heterophil (median = 2.06 x 10(9)/L).

Worldwide Environmental Compliance Assessment System (ECAS)

DTIC Science & Technology

1993-03-01

and other Pickling liquor and other corrosive alkalies corrosive acids Lime wastewater Spent acid Lime and water Spent mixed acid Spent caustic Spent ...labeling. packag- ing. and spill response for hazardous materials? 4. Does the installation store: * a. acids? b. caustics ? c. flammables? d. combustibles...USEPA Hazardous Waste Hazard Waste Code No. FOOl The following spent halokenated solvents used in degreasing: tetra- (T) chloroethylene, trichloroethylene

A Comparison of Spatial Analysis Methods for the Construction of Topographic Maps of Retinal Cell Density

PubMed Central

Garza-Gisholt, Eduardo; Hemmi, Jan M.; Hart, Nathan S.; Collin, Shaun P.

2014-01-01

Topographic maps that illustrate variations in the density of different neuronal sub-types across the retina are valuable tools for understanding the adaptive significance of retinal specialisations in different species of vertebrates. To date, such maps have been created from raw count data that have been subjected to only limited analysis (linear interpolation) and, in many cases, have been presented as iso-density contour maps with contour lines that have been smoothed ‘by eye’. With the use of stereological approach to count neuronal distribution, a more rigorous approach to analysing the count data is warranted and potentially provides a more accurate representation of the neuron distribution pattern. Moreover, a formal spatial analysis of retinal topography permits a more robust comparison of topographic maps within and between species. In this paper, we present a new R-script for analysing the topography of retinal neurons and compare methods of interpolating and smoothing count data for the construction of topographic maps. We compare four methods for spatial analysis of cell count data: Akima interpolation, thin plate spline interpolation, thin plate spline smoothing and Gaussian kernel smoothing. The use of interpolation ‘respects’ the observed data and simply calculates the intermediate values required to create iso-density contour maps. Interpolation preserves more of the data but, consequently includes outliers, sampling errors and/or other experimental artefacts. In contrast, smoothing the data reduces the ‘noise’ caused by artefacts and permits a clearer representation of the dominant, ‘real’ distribution. This is particularly useful where cell density gradients are shallow and small variations in local density may dramatically influence the perceived spatial pattern of neuronal topography. The thin plate spline and the Gaussian kernel methods both produce similar retinal topography maps but the smoothing parameters used may affect the outcome. PMID:24747568

Alkaline flooding for enhanced oil recovery

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gittler, W.E.

1983-09-01

There are over 12 active projects of varying size using one of 3 major types of alkaline agents. These include sodium silicate, caustic soda, and soda ash. Among the largest pilots currently is the THUMS project in the Wilmington field, California. Plans called for the injection of a 4% weight concentration of sodium orthosilicate over a 60% PV. Through the first 3 yr, over 27 million bbl of chemicals have been injected. Gulf Oil is operating several alkaline floods, one of which is located off shore in the Quarantine Bay field, Louisiana. In this pilot, sodium hydroxide in a weightmore » concentration of 5 to 12% is being injected. Belco Petroleum Corp. has reported that their pilot operating in the Isenhour Unit in Wyoming is using a .5% weight concentration of soda ash in conjunction with a polymer. Other uses for alkaline agents in chemical flooding include the use of silicate as a preflush or sacrificial agent in micellar/polymer and surfactant recovery systems. In addition, caustic has been tested in the surface-mixed caustic emulsion process while orthosilicate has been tested in a recovery method known as mobility-controlled caustic floods.« less

Simulations of sonic boom ray tube area fluctuations for propagation through atmospheric turbulence including caustics via a Monte Carlo method

NASA Technical Reports Server (NTRS)

Sparrow, Victor W.; Pierce, Allan D.

1992-01-01

A theory which gives statistical predictions for how often sonic booms propagating through the earth's turbulent boundary layer will encounter caustics, given the spectral properties of the atmospheric turbulence, is outlined. The theory is simple but approximately accounts for the variation of ray tube areas along ray paths. This theory predicts that the variation of ray tube areas is determined by the product of two similar area factors, psi (x) and phi (x), each satisfying a generic harmonic oscillator equation. If an area factor increases the peak acoustic pressure decreases, and if the factor decreases the peak acoustic pressure increases. Additionally, if an area factor decreases to zero and becomes negative, the ray has propagated through a caustic, which contributes a phase change of 90 degrees to the wave. Thus, it is clear that the number of times that a sonic boom wave passes through a caustic should be related to the distorted boom waveform received on the ground. Examples are given based on a characterization of atmospheric turbulence due to the structure function of Tatarski as modified by Crow.

Caustics and Rogue Waves in an Optical Sea.

PubMed

Mathis, Amaury; Froehly, Luc; Toenger, Shanti; Dias, Frédéric; Genty, Goëry; Dudley, John M

2015-08-06

There are many examples in physics of systems showing rogue wave behaviour, the generation of high amplitude events at low probability. Although initially studied in oceanography, rogue waves have now been seen in many other domains, with particular recent interest in optics. Although most studies in optics have focussed on how nonlinearity can drive rogue wave emergence, purely linear effects have also been shown to induce extreme wave amplitudes. In this paper, we report a detailed experimental study of linear rogue waves in an optical system, using a spatial light modulator to impose random phase structure on a coherent optical field. After free space propagation, different random intensity patterns are generated, including partially-developed speckle, a broadband caustic network, and an intermediate pattern with characteristics of both speckle and caustic structures. Intensity peaks satisfying statistical criteria for rogue waves are seen especially in the case of the caustic network, and are associated with broader spatial spectra. In addition, the electric field statistics of the intermediate pattern shows properties of an "optical sea" with near-Gaussian statistics in elevation amplitude, and trough-to-crest statistics that are near-Rayleigh distributed but with an extended tail where a number of rogue wave events are observed.

Caustics and Rogue Waves in an Optical Sea

PubMed Central

Mathis, Amaury; Froehly, Luc; Toenger, Shanti; Dias, Frédéric; Genty, Goëry; Dudley, John M.

2015-01-01

There are many examples in physics of systems showing rogue wave behaviour, the generation of high amplitude events at low probability. Although initially studied in oceanography, rogue waves have now been seen in many other domains, with particular recent interest in optics. Although most studies in optics have focussed on how nonlinearity can drive rogue wave emergence, purely linear effects have also been shown to induce extreme wave amplitudes. In this paper, we report a detailed experimental study of linear rogue waves in an optical system, using a spatial light modulator to impose random phase structure on a coherent optical field. After free space propagation, different random intensity patterns are generated, including partially-developed speckle, a broadband caustic network, and an intermediate pattern with characteristics of both speckle and caustic structures. Intensity peaks satisfying statistical criteria for rogue waves are seen especially in the case of the caustic network, and are associated with broader spatial spectra. In addition, the electric field statistics of the intermediate pattern shows properties of an “optical sea” with near-Gaussian statistics in elevation amplitude, and trough-to-crest statistics that are near-Rayleigh distributed but with an extended tail where a number of rogue wave events are observed. PMID:26245864

Caustics and the growth of droplets

NASA Astrophysics Data System (ADS)

Govindarajan, Rama; Ravichandran, S.; Ray, Samriddhi; Deepu, P.

Caustics are formed when inertial particles of very different velocities collide in a flow, and are a consequence of the dissipative nature of particle motion in a suspension. Using a model vortex-dominated flow with heavy droplets in a saturated environment, we suggest that sling caustics form only within a neighbourhood around a vortex, the square of whose radius is proportional to the product of circulation and particle inertia. Droplets starting close to this critical radius congregate very close together, resulting in large spikes in (Lagrangian) number density. Allowing for merger when droplets collide, we show that droplets starting out close to the critical radius display a much more rapid growth in size than those starting elsewhere, and a large fraction of the large droplets are those that originate within the caustics-forming region. We test these predictions in a two-dimensional simulation of turbulent flow. We hope that our study will be of interest in long-standing problems of physical interest such as the mechanism of broadening of droplet spectra in a turbulent flow. Support from the Ministry of Earth Sciences, Government of India for the project Coupled physical processes in the Bay of Bengal and monsoon air-sea interaction under OMM is gratefully acknowledged.

Thermal degradation of the solvent employed in the next-generation caustic-side solvent extraction process and its effect on the extraction, scrubbing, and stripping of cesium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Roach, Benjamin D.; Williams, Neil J.; Moyer, Bruce A.

As part of the ongoing development of the Next-Generation Caustic-Side Solvent Extraction (NGS) process, the thermal stability of the process solvent was investigated and shown to be adequate for industrial application. The solvent was thermally treated at 35 C over a period of 13 months whilst in dynamic contact with each of the aqueous phases of the current NGS process, namely SRS 15 (a highly caustic waste simulant), sodium hydroxide scrub solution (0.025 M), and boric acid strip solution (0.01 M). The effect of thermal treatment was evaluated by assessing batch extract/scrub/strip performance as a function of time, by monitoringmore » the sodium extraction capacity of the solvent, and by analysis of the solvent using electrospray mass spectrometry. Current studies indicate that the NGS solvent should be thermally robust for a period of XXX months at the Modular Caustic-Side Solvent Extraction Unit (MCU) pilot plant located at Savannah River Site. Furthermore, the guanidine suppressor appears to be the solvent component most significantly impacted by thermal treatment of the solvent, showing significant degradation over time.« less

Thermal degradation of the solvent employed in the next-generation caustic-side solvent extraction process and its effect on the extraction, scrubbing, and stripping of cesium

DOE PAGES

Roach, Benjamin D.; Williams, Neil J.; Moyer, Bruce A.

2015-09-02

As part of the ongoing development of the Next-Generation Caustic-Side Solvent Extraction (NGS) process, the thermal stability of the process solvent was investigated and shown to be adequate for industrial application. The solvent was thermally treated at 35 C over a period of 13 months whilst in dynamic contact with each of the aqueous phases of the current NGS process, namely SRS 15 (a highly caustic waste simulant), sodium hydroxide scrub solution (0.025 M), and boric acid strip solution (0.01 M). The effect of thermal treatment was evaluated by assessing batch extract/scrub/strip performance as a function of time, by monitoringmore » the sodium extraction capacity of the solvent, and by analysis of the solvent using electrospray mass spectrometry. Current studies indicate that the NGS solvent should be thermally robust for a period of XXX months at the Modular Caustic-Side Solvent Extraction Unit (MCU) pilot plant located at Savannah River Site. Furthermore, the guanidine suppressor appears to be the solvent component most significantly impacted by thermal treatment of the solvent, showing significant degradation over time.« less

Backscattering from targets residing in caustics resulting from ocean boundary interactions

NASA Astrophysics Data System (ADS)

Dzikowicz, Benjamin R.; Marston, Philip L.

2005-04-01

Detection of targets by backscatter in shallow water can be enhanced by interactions with ocean boundaries. A laboratory experiment is performed where a spherical target passes through an Airy caustic formed by a curved surface. When the target resides in the insonified region of the caustic there are two sets of multi-path rays: two pairs reflecting once off the surface (either to or from the target), and three reflecting twice off the surface (to and from the target). When a target moves across the caustic the singly reflected rays merge, as do the doubly reflected. With a longer tone burst the rays in each set overlap and the backscatter is greatly enhanced as the target moves into the insonified region. For a point target the singly reflected backscatter scales as an Airy function [B. R. Dzikowicz and P. L. Marston, J. Acoust. Soc. Am. 116, 2751-2757 (2004)], and the doubly reflected as the square of an Airy function. For a finite target the doubly reflected backscatter unfolds into a hyperbolic umbilic function. The arguments of the Airy and Hyperbolic Umbilic functions are calculated using the relative echo times of transient pulses. [Work supported by ONR.

[Acquired caustic vagina stenosis: Surgical outcomes of 21 cases].

PubMed

Séni, K; Horo, A G; Koffi, A; Aka, K E; Fomba, M; Koné, M

2016-03-01

To document epidemiology, causes, anatomical varieties and surgical management outcomes of caustic acquired vagina stenosis. Retrospective study of 21 patients involved from 1996 to 2012 at the department of obstetrics and gynecology of Yopougon's teaching hospital in Abidjan, Côte d'Ivoire. Vaginal stenosis due to genital malformation, vaginal irradiation of pelvic tumours, repair of bladder and vaginal fistulae or intersexual disorders were excluded. The prevalence was 0.14/1000 admissions, mean age was 32.1 years, mean gravidity was 1.76 and mean parity was 1.1. Vaginal stenosis seat and extent were variable and 100 % had a caustic origin by use of traditional medicine vaginal pessaire. Of the patients, 95.2 % underwent surgical treatment followed by several dilations sessions with glass dilators. Successful surgical outcome allowing coitus was achieved in 47.6 % of cases with 52.4 % failure. Acquired caustic vagina stenosis are frequently occurring and are a public health problem related to ignorance. Health education and establishment of expert centers with exchange of experiences in West Africa should be able to improve surgical outcomes. Copyright © 2016. Published by Elsevier SAS.

Controlling Structure and Properties of High Surface Area Nonwoven Materials via Hydroentangling

NASA Astrophysics Data System (ADS)

Luzius, Dennis

Hydroentangling describes a technique using a series of high-velocity water jets to mechanically interlock and entangle fibers. Over the last decades researchers worked on a fundamental understanding of the process and the factors influencing the properties of the final nonwoven material. Recent studies discovered hydroentangling to be capable to create unique, knot-like structures characterized by high- and low density regions, which are believed to have interesting properties for filtration applications. However, just little is known about the impact of hydroentangling parameters on the properties of filtration media to this day. In this study we report on the effect of various hydroentangling parameters, such as jet spacing, manifold pressure, number of manifolds but also specific energy on the structure and properties of high surface area nonwoven materials. Latter was achieved by different bicomponent fiber technologies and subsequent treatments removing the sacrificial compound from the structure. The highest BET surface area was measured to be 3.5 m2 g-1 and the smallest mean fiber size about 0.5 mum. Hydroentangling with large jet spacing was found to be a parameter significantly enhancing the filtration properties of caustic-treated island-in-the-sea nonwoven materials. Moreover, improved capture efficiencies and reduced pressure drops were achieved by reducing the manifold pressure and therefore specific energy during hydroentangling. Jet spacing but not island count was found to be the dominant factor influencing the structure and properties of island-in-the-sea nonwovens. Contrary to our initial expectations increasing the island count and thus decreasing the fiber size did not result in better filtration properties. Mixed media nonwoven structures made from homocomponent and island-in-the-sea fibers were found to have lower densities, higher air permeabilities and better quality factors compared to island-in-the-sea structures hydroentangled under the exact same conditions. Study showed the specific energy to not be an adequate measure for describing the process-structure relationship in hydroentangling. Hydroentangling with same specific energy but different manifold pressures revealed the structure and properties to be different and the peak manifold pressure to be the dominant parameter. It was further shown that hydroentangling with multiple manifolds but same water pressure influences the structure and properties of mono- and bicomponent nonwoven materials. Hydroentangling with three manifolds having the same water pressure resulted in stronger, less permeable fabrics compared to two manifolds or one manifold with the same water pressure. Necessary hydroentangling intensity for winged and island-in-the-sea nonwoven materials was found to be different. Winged fiber nonwovens required higher manifold pressures and a different energy ratio than island-in-in-the-sea nonwovens. Hydroentangling winged fiber webs with jet spacing larger than 600 mum resulted in materials too weak to withstand the caustic-treatment. Study indicated the charging potential of winged fiber nonwovens to be superior compared to island-in-the-sea-structures. In contrast to winged fiber nonwovens, island-in-the-sea structures showed higher pressure drops after corona discharge. Loading winged fiber nonwovens with potassium chloride revealed caustic-treated, IPA discharged materials to show the highest loading capacity.

Direct Causticizing for Black Liquor Gasification in a Circulating Fluidized Bed

DOE Office of Scientific and Technical Information (OSTI.GOV)

Scott Sinquefield; Xiaoyan Zeng, Alan Ball

2010-03-02

Gasification of black liquor (BLG) has distinct advantages over direct combustion in Tomlinson recovery boilers. In this project we seek to resolve causticizing issues in order to make pressurized BLG even more efficient and cost-effective. One advantage of BLG is that the inherent partial separation of sulfur and sodium during gasification lends itself to the use of proven high yield variants to conventional kraft pulping which require just such a separation. Processes such as polysulfide, split sulfidity, ASAQ, and MSSAQ can increase pulp yield from 1% to 10% over conventional kraft but require varying degrees of sulfur/sodium separation, which requiresmore » additional [and costly] processing in a conventional Tomlinson recovery process. However during gasification, the sulfur is partitioned between the gas and smelt phases, while the sodium all leaves in the smelt; thus creating the opportunity to produce sulfur-rich and sulfur-lean white liquors for specialty pulping processes. A second major incentive of BLG is the production of a combustible product gas, rich in H2 and CO. This product gas (a.k.a. “syngas”) can be used in gas turbines for combined cycle power generation (which is twice as efficient as the steam cycle alone), or it can be used as a precursor to form liquid fuels, such as dimethyl ether or Fischer Tropsh diesel. There is drawback to BLG, which has the potential to become a third major incentive if this work is successful. The causticizing load is greater for gasification of black liquor than for combustion in a Tomlinson boiler. So implementing BLG in an existing mill would require costly increases to the causticizing capacity. In situ causticizing [within the gasifier] would handle the entire causticizing load and therefore eliminate the lime cycle entirely. Previous work by the author and others has shown that titanate direct causticizing (i.e. in situ) works quite well for high-temperature BLG (950°C), but was limited to pressures below about 5 bar. It is desirable however to operate BLG at 20-30 bar for efficiency reasons related to either firing the syngas in a turbine, or catalytically forming liquid fuels. This work focused on achieving high direct causticizing yields at 20 bars pressure. The titanate direct causticizing reactions are inhibited by CO2. Previous work has shown that the partial pressure of CO2 should be kept below about 0.5 bar in order for the process to work. This translates to a total reactor pressure limit of about 5 bar for airblown BLG, and only 2 bar for O2-blown BLG. In this work a process was developed in which the CO2 partial pressure could be manipulated to a level under 0.5 bar with the total system pressure at 10 bar during O2-blown BLG. This fell short of our 20 bar goal but still represents a substantial increase in the pressure limit. A material and energy balance was performed, as well as first-pass economics based on capital and utilities costs. Compared to a reference case of using BLG with a conventional lime cycle [Larson, 2003], the IRR and NVP were estimated for further replacing the lime kiln with direct causticizing. The economics are strongly dependent on the price of lime kiln fuel. At $6/mmBTU the lime cycle is the clear choice. At $8/mmBTU the NPV is $10M with IRR of 17%. At $12/mmBTU the NPV is $45M with IRR of 36%. To further increase the total allowable pressure, the CO2 could be further decreased by further decreasing the temperature. Testing should be done at 750C. Also a small pilot should be built.« less

Magnetoencephalographic Mapping of Epileptic Spike Population Using Distributed Source Analysis: Comparison With Intracranial Electroencephalographic Spikes.

PubMed

Tanaka, Naoaki; Papadelis, Christos; Tamilia, Eleonora; Madsen, Joseph R; Pearl, Phillip L; Stufflebeam, Steven M

2018-04-27

This study evaluates magnetoencephalographic (MEG) spike population as compared with intracranial electroencephalographic (IEEG) spikes using a quantitative method based on distributed source analysis. We retrospectively studied eight patients with medically intractable epilepsy who had an MEG and subsequent IEEG monitoring. Fifty MEG spikes were analyzed in each patient using minimum norm estimate. For individual spikes, each vertex in the source space was considered activated when its source amplitude at the peak latency was higher than a threshold, which was set at 50% of the maximum amplitude over all vertices. We mapped the total count of activation at each vertex. We also analyzed 50 IEEG spikes in the same manner over the intracranial electrodes and created the activation count map. The location of the electrodes was obtained in the MEG source space by coregistering postimplantation computed tomography to MRI. We estimated the MEG- and IEEG-active regions associated with the spike populations using the vertices/electrodes with a count over 25. The activation count maps of MEG spikes demonstrated the localization associated with the spike population by variable count values at each vertex. The MEG-active region overlapped with 65 to 85% of the IEEG-active region in our patient group. Mapping the MEG spike population is valid for demonstrating the trend of spikes clustering in patients with epilepsy. In addition, comparison of MEG and IEEG spikes quantitatively may be informative for understanding their relationship.

Removing Al and regenerating caustic soda from the spent washing liquor of Al etching

NASA Astrophysics Data System (ADS)

Barakat, M. A.; El-Sheikh, S. M.; Farghly, F. E.

2005-08-01

Spent liquor from washing of aluminum section materials after etching with caustic soda (NaOH) has been treated. Aluminum was removed from the liquor and caustic soda was regenerated by adding precipitating agents to hydrolyze sodium aluminate (Na2AlO2), separating the aluminumprecipitate, and concentrating free NaOH in the resulting solution for reuse in the etching process. Four systems were investigated: hydrated lime [Ca(OH)2], hydrogen peroxide (H2O2), H2O2/Ca(OH)2 mixture, and dry lime (CaO). Results revealed that CaO was more efficient in the removal of aluminum from the spent liquor with a higher hydrolyzing rate of Na2AlO2 than Ca(OH)2, H2O2, or their mixture.

When an Elected Official Fails to Play Nice: The Legal Implications and Lessons Learned from Associations with a Caustic School Board Member

ERIC Educational Resources Information Center

Weiler, Spencer C.

2015-01-01

In November of 2009 Mr. Sean Lyndon was elected to the Verde Mountain School Board and by February 2012 he resigned from this position. During his tumultuous tenure, Mr. Lyndon's antics proved divisive, caustic, and disruptive to the governance process. These actions included belittling and intimidating fellow school board members and school…

IDENTIFICATION OF MEMBERS IN THE CENTRAL AND OUTER REGIONS OF GALAXY CLUSTERS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Serra, Ana Laura; Diaferio, Antonaldo, E-mail: serra@ph.unito.it

2013-05-10

The caustic technique measures the mass of galaxy clusters in both their virial and infall regions and, as a byproduct, yields the list of cluster galaxy members. Here we use 100 galaxy clusters with mass M{sub 200} {>=} 10{sup 14} h {sup -1} M{sub Sun} extracted from a cosmological N-body simulation of a {Lambda}CDM universe to test the ability of the caustic technique to identify the cluster galaxy members. We identify the true three-dimensional members as the gravitationally bound galaxies. The caustic technique uses the caustic location in the redshift diagram to separate the cluster members from the interlopers. Wemore » apply the technique to mock catalogs containing 1000 galaxies in the field of view of 12 h {sup -1} Mpc on a side at the cluster location. On average, this sample size roughly corresponds to 180 real galaxy members within 3r{sub 200}, similar to recent redshift surveys of cluster regions. The caustic technique yields a completeness, the fraction of identified true members, f{sub c} = 0.95 {+-} 0.03, within 3r{sub 200}. The contamination, the fraction of interlopers in the observed catalog of members, increases from f{sub i}=0.020{sup +0.046}{sub -0.015} at r{sub 200} to f{sub i}=0.08{sup +0.11}{sub -0.05} at 3r{sub 200}. No other technique for the identification of the members of a galaxy cluster provides such large completeness and small contamination at these large radii. The caustic technique assumes spherical symmetry and the asphericity of the cluster is responsible for most of the spread of the completeness and the contamination. By applying the technique to an approximately spherical system obtained by stacking the individual clusters, the spreads decrease by at least a factor of two. We finally estimate the cluster mass within 3r{sub 200} after removing the interlopers: for individual clusters, the mass estimated with the virial theorem is unbiased and within 30% of the actual mass; this spread decreases to less than 10% for the spherically symmetric stacked cluster.« less

Biodegradable Stents for Caustic Esophageal Strictures: Do They Work?

PubMed

Kochhar, Rakesh; Samanta, Jayanta; Basha, Jahangeer; Verma, Abhai; Choudhuri, Gourdas; Lakhtakia, Sundeep; Reddy, D Nageshwar

2017-08-01

Biodegradable (BD) stents have been used for the management of various esophageal strictures (ES) but the experience of its use in caustic strictures is limited. The present study, aimed at evaluating efficacy of BD stents for the treatment of refractory caustic-induced ES, was a retrospective multi-center study conducted at three tertiary care centers in India wherein adult patients with refractory caustic induced strictures underwent placement of a BD stent. Patients were followed up for immediate complications and long term outcome. All 13 patients (39.3 ± 15.1 years) underwent successful BD stent placement. Retrosternal chest pain occurred in 2 patients and stent migration in 1 (7.6%) patient. At 3 months, restenosis with recurrence of dysphagia was seen in nine (69.2%) patients, at 6 months, 10 (77%) patients had dysphagia of whom three underwent surgery and the remaining seven patients required dilatations. At 1 year, one patient remained asymptomatic while nine had dysphagia. The requirement for dilatation was once in 3 months in seven patients & once in a month in two patients. At 2 years, the requirement of dilatations was further reduced to once in 4-6 months in all patients. Over a 3 year follow up three (23%) patients had undergone surgery, one was free of symptoms while nine patients continued to be on periodic dilatation although the requirement had reduced to once in 4-6 months. Efficacy of BD stents in patients with caustic-induced ES is limited and the short term radial force applied by the currently available BD stents is inadequate to provide long term relief in such patients.

Early endoscopic balloon dilation in caustic-induced gastric injury.

PubMed

Kochhar, Rakesh; Poornachandra, Kuchhangi Sureshchandra; Dutta, Usha; Agrawal, Amit; Singh, Kartar

2010-04-01

There are no reports on endoscopic balloon dilation (EBD) for caustic-induced gastric outlet obstruction (GOO) in the acute or subacute phase. To study the efficacy of early EBD in patients with caustic-induced gastric injury. Tertiary care center in India. Retrospective analysis of data. Out of 41 patients with caustic-induced GOO who reported to us in the subacute phase between January 2001 and December 2008, 31 were treated by EBD. All 31 had ingested an acid 14.39 +/- 4.65 days earlier. EBD was achieved by using wire-guided balloons under endoscopic guidance. The balloon was negotiated across the narrowed segment and inflated for 60 seconds using a pressure gun. Balloons of incremental diameter, up to a maximum of 3 sizes, were used in each sitting. Procedural success was defined as reaching the end point of dilation (15 mm) and absence of symptoms. All 31 patients (18 male, mean age 32.06 +/- 11.04 years) could be successfully dilated. All but 1 underwent successful dilations to achieve the end point of 15 mm, requiring a median of 9 (range 3-18) dilations over a period of 7 (range 1.5-16) weeks. Complications included self-limiting pain (n = 10), bleeding at the time of the procedure (n = 9), and perforation in 1 patient (3.2%) who required surgery. Thirty patients were followed up for a median of 21 (range 3-72) months with no recurrence. Early EBD by an expert endoscopist is a safe and effective treatment modality in the management of caustic-induced GOO. Copyright 2010 American Society for Gastrointestinal Endoscopy. Published by Mosby, Inc. All rights reserved.

Two-Pole Caustic Model for High-Energy Lightcurves of Pulsars

NASA Technical Reports Server (NTRS)

Dyks, J.; Rudak, B.

2003-01-01

We present a new model of high-energy lightcurves from rotation powered pulsars. The key ingredient of the model is the gap region (i.e. the region where particle acceleration is taking place and high-energy photons originate) which satisfies the following assumptions: i) the gap region extends from each polar cap to the light cylinder; ii) the gap is thin and confined to the surface of last open magnetic-field lines; iii) photon emissivity is uniform within the gap region. The model lightcurves are dominated by strong peaks (either double or single) of caustic origin. Unlike in other pulsar models with caustic effects, the double peaks arise due to crossing two caustics, each of which is associated with a different magnetic pole. The generic features of the lightcurves are consistent with the observed characteristics of pulsar lightcurves: 1) the most natural (in terms of probability) shape consists of two peaks (separated by 0.4 to 0.5 in phase for large viewing angles); 2) the peaks possess well developed wings; 3) there is a bridge (inter-peak) emission component; 4) there is a non-vanishing off-pulse emission level; 5) the radio pulse occurs before the leading high-energy peak. The model is well suited for four gamma-ray pulsars - Crab, Vela, Geminga and B1951+32 - with double-peak lightcurves exhibiting the peak separation of 0.4 to 0.5 in phase. Hereby, we apply the model to the Vela pulsar. Moreover, we indicate the limitation of the model in accurate reproducing of the lightcurves with single pulses and narrowly separated (about 0.2 in phase) pulse peaks. We also discuss the optical polarization properties for the Crab pulsar in the context of the two-pole caustic model.

Effects of Gas Composition in the Modified Atmosphere Packaging on the Shelf-life of Longissimus dorsi of Korean Native Black Pigs-Duroc Crossbred during Refrigerated Storage

PubMed Central

Muhlisin; Panjono; Kim, Dong Soo; Song, Yeong Rae; Lee, Sung-Jin; Lee, Jeong Koo; Lee, Sung Ki

2014-01-01

This study was conducted to observe the effects of gas composition in modified atmosphere packaging (MAP) on the shelf-life of Longissimus dorsi of Korean Native Black Pigs-Duroc Crossbred (KNP×D) during refrigerated storage. Muscle sample was obtained from the left side of carcass of seven months old of KNP×D barrow. The sample was sliced into 1 cm in thickness, placed on trays (two slices/tray) and filled with different gas composition, i.e. 0:20:80/O2:CO2:N2 (MAP1), 30:20:50/O2:CO2:N2 (MAP2) and 70:20:10/O2:CO2:N2 (MAP3). Other slices of sample were vacuum packed (VP) as a control. All packs were stored at 5±1°C. At 12 d of storage, pH value of MAP2 and MAP3 were higher (p<0.05) than that of MAP1 and pH value of MAP1 was higher (p<0.05) than that of VP. At 6 d of storage, redness (a*) value of MAP2 and MAP3 were higher (p<0.05) than that of VP and MAP1 and, at 9 and 12 d of storage, redness value of MAP3 was higher (p<0.05) than that of VP, MAP1, and MAP2. At 3, 6, 9, and 12 d of storage, the 2-thiobarbituric acid reactive substances (TBARS) value of MAP3 was higher than that of MAP2 and TBARS value of MAP2 was higher than that of VP and MAP1. At 3, 6, 9, and 12 d of storage, volatile basic nitrogen values of MAP2 and MAP3 were higher (p<0.05) than those of VP and MAP1. At 3 d of storage, total aerobic plate counts of MAP2 and MAP3 were higher (p<0.05) than those of VP and MAP1 and, at 6 d of storage, total aerobic plate counts of MAP3 was higher (p<0.05) than that of MAP1 and MAP2. However, there was no significant different total aerobic plate count among MAP1, MAP2, and MAP3 at 9 and 12 d of storage. There was no significant different total anaerobic plate count among MAP1, MAP2, and MAP3 during storage. It is concluded that the MAP containing 30:20:50/O2:CO2:N2 gas composition (MAP2) might be ideal for better meat quality for KNP×D meat. PMID:25083110

Evolution of velocity dispersion along cold collisionless flows

DOE PAGES

Banik, Nilanjan; Sikivie, Pierre

2016-05-01

We found that the infall of cold dark matter onto a galaxy produces cold collisionless flows and caustics in its halo. If a signal is found in the cavity detector of dark matter axions, the flows will be readily apparent as peaks in the energy spectrum of photons from axion conversion, allowing the densities, velocity vectors and velocity dispersions of the flows to be determined. We also discuss the evolution of velocity dispersion along cold collisionless flows in one and two dimensions. A technique is presented for obtaining the leading behaviour of the velocity dispersion near caustics. The results aremore » used to derive an upper limit on the energy dispersion of the Big Flow from the sharpness of its nearby caustic, and a prediction for the dispersions in its velocity components.« less

Conformal chemically resistant coatings for microflow devices

DOEpatents

Folta, James A.; Zdeblick, Mark

2003-05-13

A process for coating the inside surfaces of silicon microflow devices, such as electrophoresis microchannels, with a low-stress, conformal (uniform) silicon nitride film which has the ability to uniformly coat deeply-recessed cavities with, for example, aspect ratios of up to 40:1 or higher. The silicon nitride coating allows extended exposure to caustic solutions. The coating enables a microflow device fabricated in silicon to be resistant to all classes of chemicals: acids, bases, and solvents. The process involves low-pressure (vacuum) chemical vapor deposition. The ultra-low-stress silicon nitride deposition process allows 1-2 .mu.m thick films without cracks, and so enables extended chemical protection of a silicon microflow device against caustics for up to 1 year. Tests have demonstrated the resistance of the films to caustic solutions at both ambient and elevated temperatures to 65.degree. C.

Effect of packaging during storage time on retail display microbial population of beef strip loins from two different production systems.

PubMed

Luzardo, S; Woerner, D R; Geornaras, I; Hess, A M; Belk, K E

2016-06-01

Two studies were conducted to evaluate the influence of packaging during storage of strip loins (to simulate export shipment) from steers fattened on intensive grazing systems (Uruguay; UR) or on a high-concentrate diet (United States; US) on retail display life microbial growth. Four or 3 different packaging treatments were applied to UR and US strip loin roasts or steaks during 35 d of storage; treatments were applied 7 d following slaughter. After 35 d of storage, the samples were evaluated during simulated retail display for up to 6 d. In Exp. 1, the treatments were vacuum packaging (VP), low-oxygen modified atmosphere packaging (MAP) with N and CO (MAP/CO), low-oxygen MAP with N plus CO and CO, and VP plus an application of peroxyacetic acid (VP/PAA). In Exp. 2, block 1, the treatments were VP, MAP/CO, and VP with ethyl--lauroyl--arginate HCl incorporated into the film as an antimicrobial agent (VP/AM). In Exp. 2, block 2, the treatments were VP, MAP/CO, MAP/CO, and VP/AM. For retail display, VP treatments were sliced and repackaged in PVC overwrap, and MAP treatments were actually PVC overwrap trays that were removed from a master bag with the prescribed gas treatment. Regardless of production system and packaging treatment, mesophilic and psychrotrophic counts of 6.9 to 7.8 and 6.7 to 7.7 log10 CFU/cm, respectively, were obtained at the end of retail display, except for US samples in Exp. 2 (5.5 to 6.3 log CFU/cm). No differences ( > 0.05) were detected for spp. counts among packaging treatments in US steaks at the end of the display time in Exp.1, whereas, for UR steaks, both MAP treatments had lower ( < 0.05) spp. counts than VP treatments. spp. counts were lower ( < 0.05) in the MAP/CO treatment than in the other 3 treatments in US samples on d 6 of retail display for Exp. 2. At the end of display time and for Exp. 1, US steaks under MAP/CO had greater ( < 0.05) lactic acid bacteria (LAB) counts than samples in both VP treatments; no differences ( > 0.05) among packaging were detected for UR steaks. Both MAP and VP/AM treatments in the US samples for Exp. 2 had lower ( < 0.05) LAB counts on d 6 of display than the VP treatment, but no differences ( > 0.05) were found among packaging treatments for the UR samples. To maximize shelf life (storage and display life) of exported fresh beef, it is critical to minimize bacterial populations during processing and storage.

The economic pre-treatment of coal mine drainage water with caustic and ozone.

PubMed

Boyden, B H; Nador, L; Addleman, S; Jeston, L

2017-09-01

Coal mine drainage waters are low in pH with varying amounts of iron and manganese and are generally brackish. The Austar Coal Mine in NSW, Australia, sought alternatives to their current lime dosing as the pre-treatment before the downstream reverse osmosis plant. Undesirable operating aspects of the current system include manganese and gypsum scaling/fouling, the need for anti-scalants and reduced water recovery. Thirteen processes for acid mine drainage were initially considered. The preferred process of caustic and ozone for Mn(II) oxidation was pilot tested at up to 0.74 kL/hr at the mine site. Under proper conditions and no aeration, about 81 per cent of the Fe could be removed (initially at 156 mg/L) as green rust. Supplemental aeration followed first-order kinetics and allowed 99.9 per cent Fe(II) oxidation and removal but only with a hydraulic residence time of about 47 minutes. The addition of supplemental Cu catalyst improved Fe removal. Ozone applied after caustic was effective in stoichiometrically oxidising recalcitrant Mn(II) and any remaining Fe(II). Control of the ozonation was achieved using the oxidation reduction potential during oxidation of the Mn(II) species. The use of caustic, followed by ozone, proved economically comparable to the current lime pre-treatment.

Reflective and refractive objects for mixed reality.

PubMed

Knecht, Martin; Traxler, Christoph; Winklhofer, Christoph; Wimmer, Michael

2013-04-01

In this paper, we present a novel rendering method which integrates reflective or refractive objects into a differential instant radiosity (DIR) framework usable for mixed-reality (MR) applications. This kind of objects are very special from the light interaction point of view, as they reflect and refract incident rays. Therefore they may cause high-frequency lighting effects known as caustics. Using instant-radiosity (IR) methods to approximate these high-frequency lighting effects would require a large amount of virtual point lights (VPLs) and is therefore not desirable due to real-time constraints. Instead, our approach combines differential instant radiosity with three other methods. One method handles more accurate reflections compared to simple cubemaps by using impostors. Another method is able to calculate two refractions in real-time, and the third method uses small quads to create caustic effects. Our proposed method replaces parts in light paths that belong to reflective or refractive objects using these three methods and thus tightly integrates into DIR. In contrast to previous methods which introduce reflective or refractive objects into MR scenarios, our method produces caustics that also emit additional indirect light. The method runs at real-time frame rates, and the results show that reflective and refractive objects with caustics improve the overall impression for MR scenarios.

Wavefronts, actions and caustics determined by the probability density of an Airy beam

NASA Astrophysics Data System (ADS)

Espíndola-Ramos, Ernesto; Silva-Ortigoza, Gilberto; Sosa-Sánchez, Citlalli Teresa; Julián-Macías, Israel; de Jesús Cabrera-Rosas, Omar; Ortega-Vidals, Paula; Alejandro Juárez-Reyes, Salvador; González-Juárez, Adriana; Silva-Ortigoza, Ramón

2018-07-01

The main contribution of the present work is to use the probability density of an Airy beam to identify its maxima with the family of caustics associated with the wavefronts determined by the level curves of a one-parameter family of solutions to the Hamilton–Jacobi equation with a given potential. To this end, we give a classical mechanics characterization of a solution of the one-dimensional Schrödinger equation in free space determined by a complete integral of the Hamilton–Jacobi and Laplace equations in free space. That is, with this type of solution, we associate a two-parameter family of wavefronts in the spacetime, which are the level curves of a one-parameter family of solutions to the Hamilton–Jacobi equation with a determined potential, and a one-parameter family of caustics. The general results are applied to an Airy beam to show that the maxima of its probability density provide a discrete set of: caustics, wavefronts and potentials. The results presented here are a natural generalization of those obtained by Berry and Balazs in 1979 for an Airy beam. Finally, we remark that, in a natural manner, each maxima of the probability density of an Airy beam determines a Hamiltonian system.

Comparison of ultrasound-assisted and traditional caustic leaching of spent cathode carbon (SCC) from aluminum electrolysis.

PubMed

Xiao, Jin; Yuan, Jie; Tian, Zhongliang; Yang, Kai; Yao, Zhen; Yu, Bailie; Zhang, Liuyun

2018-01-01

The spent cathode carbon (SCC) from aluminum electrolysis was subjected to caustic leaching to investigate the different effects of ultrasound-assisted and traditional methods on element fluorine (F) leaching rate and leaching residue carbon content. Sodium hydroxide (NaOH) dissolved in deionized water was used as the reaction system. Through single-factor experiments and a comparison of two leaching techniques, the optimum F leaching rate and residue carbon content for ultrasound-assisted leaching process were obtained at a temperature of 70°C, residue time of 40min, initial mass ratio of alkali to SCC (initial alkali-to-material ratio) of 0.6, liquid-to-solid ratio of 10mL/g, and ultrasonic power of 400W, respectively. Under the optimal conditions, the leaching residue carbon content was 94.72%, 2.19% larger than the carbon content of traditional leaching residue. Leaching wastewater was treated with calcium chloride (CaCl 2 ) and bleaching powder and the treated wastewater was recycled caustic solution. All in all, benefiting from advantage of the ultrasonication effects, ultrasound-assisted caustic leaching on spent cathode carbon had 55.6% shorter residue time than the traditional process with a higher impurity removal rate. Copyright © 2017 Elsevier B.V. All rights reserved.

An unconventional method for the recovery of caustic soda from spent Al-rich pickling solutions.

PubMed

Aprea, Paolo; de Gennaro, Bruno; Colella, Carmine

2011-07-01

This work presents an unconventional procedure for the recovery of spent Al-rich caustic soda solutions from the pickling of dies for the production of aluminium extrusions. Caustic soda was regenerated at roughly 70%, by precipitating aluminate, after addition of a silica source, in the form of zeolite A, a microporous material that is widely used in many technological sectors. It was shown that the process is reliable and can be repeated for several cycles, provided the concentration of the caustic soda solution is suitably restored. The by-product obtained, zeolite A, proved to be a high-grade material with performance as a cation exchanger and physical sorbent that is certainly comparable to that reported in literature (e.g., cation exchange capacity equal to 5.14 meq g(-1) vs. 5.48 meq g(-1) and water vapour adsorption capacity of 26.5% vs. 27.6% at 16 torr and 298 K). The economics of the process, although not examined yet, would appear generally favourable, considering that zeolite A is a valuable by-product which widely covers the costs for the recovery of the spent solutions. There are, therefore, significant prospects for the use of zeolite A, particularly as a builder in detergent formulation. Copyright © 2011 Elsevier Ltd. All rights reserved.

Effect of Non-Alignment/Alignment of Attenuation Map Without/With Emission Motion Correction in Cardiac SPECT/CT

NASA Astrophysics Data System (ADS)

Dey, Joyoni; Segars, W. Paul; Pretorius, P. Hendrik; King, Michael A.

2015-08-01

Purpose: We investigate the differences without/with respiratory motion correction in apparent imaging agent localization induced in reconstructed emission images when the attenuation maps used for attenuation correction (from CT) are misaligned with the patient anatomy during emission imaging due to differences in respiratory state. Methods: We investigated use of attenuation maps acquired at different states of a 2 cm amplitude respiratory cycle (at end-expiration, at end-inspiration, the center map, the average transmission map, and a large breath-hold beyond range of respiration during emission imaging) to correct for attenuation in MLEM reconstruction for several anatomical variants of the NCAT phantom which included both with and without non-rigid motion between heart and sub-diaphragmatic regions (such as liver, kidneys etc). We tested these cases with and without emission motion correction and attenuation map alignment/non-alignment. Results: For the NCAT default male anatomy the false count-reduction due to breathing was largely removed upon emission motion correction for the large majority of the cases. Exceptions (for the default male) were for the cases when using the large-breathhold end-inspiration map (TI_EXT), when we used the end-expiration (TE) map, and to a smaller extent, the end-inspiration map (TI). However moving the attenuation maps rigidly to align the heart region, reduced the remaining count-reduction artifacts. For the female patient count-reduction remained post motion correction using rigid map-alignment due to the breast soft-tissue misalignment. Quantitatively, after the transmission (rigid) alignment correction, the polar-map 17-segment RMS error with respect to the reference (motion-less case) reduced by 46.5% on average for the extreme breathhold case. The reductions were 40.8% for end-expiration map and 31.9% for end-inspiration cases on the average, comparable to the semi-ideal case where each state uses its own attenuation map for correction. Conclusions: Two main conclusions are that even rigid emission motion correction to rigidly align the heart region to the attenuation map helps in average cases to reduce the count-reduction artifacts and secondly, within the limits of the study (ex. rigid correction) when there is lung tissue inferior to the heart as with the NCAT phantom employed in this study end-expiration maps (TE) might best be avoided as they may create more artifacts than the end-inspiration (TI) maps.

Handbook of Thermal Insulation Applications.

DTIC Science & Technology

1983-01-01

today. Every $10 spent on conservation would save at least I barrel of oil - equivalent * to buying oil at $10 a barrel. In recent years, energy...there exists some point at which’more would be spent for an increment of insulation than could ever be saved by that increment. By adding the...TO ACIDS, CAUSTICS , AND SOLVENTS: The property of a material to resist decomposition by various acids, caustics and solvents to which it may be

Polymer Claw: Instant Underwater Adhesive

DTIC Science & Technology

2012-10-23

April to October. The biofilms included mostly algae with patches of barnacles. 3.1.1 Removal of Biofilm with Caustic Paste The caustic paste was...when the brush was rotated 360° while it was pressed downwards. Figure 3 shows that the thick algae biofilm was completely removed under these...413 TABLE OF CONTENTS 1 SUMMARY 1 2 PROIECT GOALS AND OBJECTIVES 3. 1 KEY ACCOMPLISHMENTS 3 3.1 BIOFILM REMOVAL 3 3.1.1 REMOVAL OF BIOFILM

First Responders Immersive Training Simulation Environment (FRITSE): Scenario Development and Support

DTIC Science & Technology

2014-07-30

consisted of three stages: a deliberate derailment of a train containing either methanol (flammable) or ammonia (caustic) cars at an overpass where...event would be the deliberate release of chemical agent from a van parked near the train derailment and the tertiary event would be a giant fertilizer ...political targets is highest. The derailment would cause a major leak of either caustic ( ammonia ) or highly flammable (methanol) material from derailed

A new approach on Brewer's spent grains treatment and potential use as lignocellulosic yeast cells carriers.

PubMed

Pires, Eduardo J; Ruiz, Héctor A; Teixeira, José A; Vicente, António A

2012-06-13

The major objective of this work is to improve the pretreatments of brewer's spent grains (BSG) aiming at their use as a source for lignocellulosic yeast carriers (LCYC) production. Therefore, several pretreatments of BSG have been designed aiming at obtaining various yeast carriers, differing on their physicochemical composition. Cellulose, hemicellulose, lignin, fat, protein, and ash content were determined for crude BSG and the LCYCs. The long chain fatty acids profile for the crude BSG was also analyzed. Chemical treatments successfully produced several different LCYC based on BSG. The highest cellulose content in LCYC was achieved upon application of caustic (NaOH) treatment during 40 min. Either caustic or combined acid-caustic treatments predominately generated hydrophobic, negatively charged LCYC. The feasibility of using BSG for LCYC production is strengthened by the fact that added-value byproduct can be extracted before the chemical treatments are applied.

Sodium to sodium carbonate conversion process

DOEpatents

Herrmann, Steven D.

1997-01-01

A method of converting radioactive alkali metal into a low level disposable solid waste material. The radioactive alkali metal is atomized and introduced into an aqueous caustic solution having caustic present in the range of from about 20 wt % to about 70 wt % to convert the radioactive alkali metal to a radioactive alkali metal hydroxide. The aqueous caustic containing radioactive alkali metal hydroxide and CO.sub.2 are introduced into a thin film evaporator with the CO.sub.2 present in an amount greater than required to convert the alkali metal hydroxide to a radioactive alkali metal carbonate, and thereafter the radioactive alkali metal carbonate is separated from the thin film evaporator as a dry powder. Hydroxide solutions containing toxic metal hydroxide including one or more metal ions of Sb, As, Ba, Be, Cd, Cr, Pb, Hg, Ni, Se, Ag and T1 can be converted into a low level non-hazardous waste using the thin film evaporator of the invention.

Reducing operating costs for struvite formation with a carbon dioxide stripper.

PubMed

Fattah, K P; Sabrina, N; Mavinic, D S; Koch, F A

2008-01-01

One of the major operational costs of phosphorus recovery as struvite is the cost of caustic chemical that is added to maintain a desired level of operative pH. A study was conducted at the Lulu Island Wastewater Treatment Plant (LIWWTP), Richmond, BC, using a struvite crystallizer and a cascade stripper designed at the University of British Columbia (UBC). The stripper was tested under different operating conditions to determine the effectiveness of CO(2) stripping in increasing the pH of the water matrix and thereby reducing caustic chemical use. This reduction is expected to reduce the operational costs of struvite production. Throughout the project, a high percentage (90%) of phosphorus removal was achieved under each condition. The cascade stripper was very effective in saving caustic usage, ranging from 35% to 86%, depending on the operating conditions. However, the stripper showed relatively poor performance regarding ammonia stripping. Copyright IWA Publishing 2008.

PEP Integrated Test D Run Report Caustic and Oxidative Leaching in UFP-VSL-T02A

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sevigny, Gary J.; Bredt, Ofelia P.; Burns, Carolyn A.

2009-12-11

Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed and operated as part of a plan to respond to issue M12, "Undemonstrated Leaching Processes" of the External Flowsheet Review Team (EFRT) issue response plan. The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. Themore » PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing. Two operating scenarios are currently being evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario (Test B and D) has caustic leaching performed in the UFP-2 ultrafiltration feed vessels (i.e., vessel UFP-VSL-T02A in the PEP and vessels UFP-VSL-00002A and B in the WTP PTF). The second scenario (Test A) has caustic leaching conducted in the UFP-1 ultrafiltration feed preparation vessels (i.e., vessels UFP-VSL-T01A and B in the PEP and vessels UFP VSL-00001A and B in the WTP PTF). In Test D, 19M sodium hydroxide (NaOH, caustic) was added to the waste slurry in the UFP VSL T02 vessel after the solids were concentrated to ~20% undissolved solids. The NaOH was added to leach solid aluminum compounds (e.g., gibbsite, boehmite). Caustic addition is followed by heating to 85°C using direct injection of steam to accelerate the leach process. The main difference of Test D compared to Test B is that the leach temperature is 85°C for 24 hrs as compared to 100°C for 12 hours. The other difference is the Test D simulant had Cr in the simulant from the start of processing and Test B had Cr added to adjust the simulant composition after aluminum leaching. Following the caustic leach, the UFP-VSL-T02A vessel contents are cooled using the vessel cooling jacket. The slurry was then concentrated to 17 wt% undissolved solids and washed with inhibited water to remove NaOH and other soluble salts. Next, the slurry was oxidatively leached using sodium permanganate to solubilize chrome. The slurry was then washed to remove the dissolved chrome and concentrated.« less

Proceedings of the Technology Transfer Seminar/Workshop on the Application of Pollution Abatement Technology to Local Governments

DTIC Science & Technology

1975-05-01

civil agencies through interage..:y agreements. One of the Navy field activities, the Naval Ammunition Depot at Crane , Indiana, has developed rather...chemical mixing compartment and chem- ical dosing tank assures adequate contact time. Solids and organics are hydrolyzed by the caustic , while the...The high caustic level of the treated waste water resulted in corrosion to various points in the system. Pumps required extensive weekly maintenance

Analysis of Deep Seafloor Arrivals Observed on NPAL04

DTIC Science & Technology

2012-12-03

transmission station to the scattering point (black line) to compute the time spent on the PE-predicted path to the scattering point. This time would...arrives at the OBSs at times corresponding to caustics of the PE predicted time fronts, there are large amplitude, late arrivals that occur between... caustics and even after the PE predicted coda. Similar analysis was done for T500 to T2300 with similar results and is discussed in Section 4 of

The Effects of Internal Tides on Acoustic Propagation in the Philippine Sea

DTIC Science & Technology

2013-09-01

understanding during the long days spent away from home while working on this thesis xvi THIS PAGE INTENTIONALLY LEFT BLANK 1 I. INTRODUCTION...sweeping by a vertical set of receivers at a fixed range. Each wavefront branch is seen as the line between caustics (acoustic focusing points where...the ray folds), and is composed of eigenrays with the same ID. The caustics farthest to the left of the timefront plot represent the rays with large

Hazardous Waste Minimization Initiation Decision Report. Volume 1

DTIC Science & Technology

1988-06-01

different treatment and disposal practices for spent caustic materials. In some cases, the material is placed in drums and sent to DRMO for disposal or to a...often available. As at some Navy facilities, waste caustic may be neutralized with spent acid at the process line with the effluent sent to the IWTP...3-111 PART II - Spent Battery Electrolyte .... 3-112 PART III- Battery Acid Sludges ........ 3-113 3.13.3 Disposal of Wastes from Battery Repair and

Commandant’s International Technical Series. Volume 9. International Regulations on the Prevention of Pollution from Ships Carrying Hazardous Chemicals in Bulk.

DTIC Science & Technology

1985-12-01

Styrene monomer 2055 B Sulphuric acid 1830 C " Sulphuric acid, spent 1832 C - Sulphurous acid 1633 (C) Sunflover oil D...anhydrides (e.g. formic, acetic); .3 halogenated carboxylic acids (e.g. chloracetic); .4 sulpnonic acids (e.g. benzene sulphonic); .5 caustic alkalis...acetic); (iii) halogenated carboxylic acids (e.g. cbloracetic); (iv) sulphonic acids (e.g. benzene sulphonic);II (v) caustic alkalis (e.g. sodium

Left colonic graft in esophageal reconstruction for caustic stricture: mortality and morbidity.

PubMed

Boukerrouche, A

2013-01-01

The adequacy of the blood supply to the left colon graft and its ability to transport food effectively from pharynx to stomach made it an esophageal substitute of choice, particularly in esophageal caustic stricture. From 1999 to 2009, 60 patients underwent colon interposition for esophageal caustic stricture (n= 57) and cancer (n= 3). An isoperistaltic colonic graft based on the left colonic artery could be used in all of these patients. The substernal route was used exclusively, and upper thoracic inlet was opened when necessary. The isoperistaltic left colonic graft interposed by substernal route represents the surgical procedure of choice in all operations performed for esophageal substitution during the study period. The operative mortality rate was 3.3%. A cervical fistula occurred in 10 patients (16.6%) and cervical anastomotic stricture in five patients (8.3%). Dilation was required in all the stricture of the esophageal colonic anastomosis with good response. The isoperistaltic left colic transplant supplied by the left colic pedicle is an excellent long-term replacement organ for the esophageal caustic stenosis. When performed by experienced surgeons, the left isoperistaltic esophagocoloplasty is a satisfactory surgical method for esophageal reconstruction with acceptable early morbidity and good long-term functional results. © 2012 Copyright the Authors. Journal compilation © 2012, Wiley Periodicals, Inc. and the International Society for Diseases of the Esophagus.

Quantitative holographic interferometry applied to combustion and compressible flow research

NASA Astrophysics Data System (ADS)

Bryanston-Cross, Peter J.; Towers, D. P.

1993-03-01

The application of holographic interferometry to phase object analysis is described. Emphasis has been given to a method of extracting quantitative information automatically from the interferometric fringe data. To achieve this a carrier frequency has been added to the holographic data. This has made it possible, firstly to form a phase map using a fast Fourier transform (FFT) algorithm. Then to `solve,' or unwrap, this image to give a contiguous density map using a minimum weight spanning tree (MST) noise immune algorithm, known as fringe analysis (FRAN). Applications of this work to a burner flame and a compressible flow are presented. In both cases the spatial frequency of the fringes exceed the resolvable limit of conventional digital framestores. Therefore, a flatbed scanner with a resolution of 3200 X 2400 pixels has been used to produce very high resolution digital images from photographs. This approach has allowed the processing of data despite the presence of caustics, generated by strong thermal gradients at the edge of the combustion field. A similar example is presented from the analysis of a compressible transonic flow in the shock wave and trailing edge regions.

One, two, three, four, nothing more: an investigation of the conceptual sources of the verbal counting principles.

PubMed

Le Corre, Mathieu; Carey, Susan

2007-11-01

Since the publication of [Gelman, R., & Gallistel, C. R. (1978). The child's understanding of number. Cambridge, MA: Harvard University Press.] seminal work on the development of verbal counting as a representation of number, the nature of the ontogenetic sources of the verbal counting principles has been intensely debated. The present experiments explore proposals according to which the verbal counting principles are acquired by mapping numerals in the count list onto systems of numerical representation for which there is evidence in infancy, namely, analog magnitudes, parallel individuation, and set-based quantification. By asking 3- and 4-year-olds to estimate the number of elements in sets without counting, we investigate whether the numerals that are assigned cardinal meaning as part of the acquisition process display the signatures of what we call "enriched parallel individuation" (which combines properties of parallel individuation and of set-based quantification) or analog magnitudes. Two experiments demonstrate that while "one" to "four" are mapped onto core representations of small sets prior to the acquisition of the counting principles, numerals beyond "four" are only mapped onto analog magnitudes about six months after the acquisition of the counting principles. Moreover, we show that children's numerical estimates of sets from 1 to 4 elements fail to show the signature of numeral use based on analog magnitudes - namely, scalar variability. We conclude that, while representations of small sets provided by parallel individuation, enriched by the resources of set-based quantification are recruited in the acquisition process to provide the first numerical meanings for "one" to "four", analog magnitudes play no role in this process.

Process for converting sodium nitrate-containing, caustic liquid radioactive wastes to solid insoluble products

DOEpatents

Barney, Gary S.; Brownell, Lloyd E.

1977-01-01

A method for converting sodium nitrate-containing, caustic, radioactive wastes to a solid, relatively insoluble, thermally stable form is provided and comprises the steps of reacting powdered aluminum silicate clay, e.g., kaolin, bentonite, dickite, halloysite, pyrophyllite, etc., with the sodium nitrate-containing radioactive wastes which have a caustic concentration of about 3 to 7 M at a temperature of 30.degree. C to 100.degree. C to thereby entrap the dissolved radioactive salts in the aluminosilicate matrix. In one embodiment the sodium nitrate-containing, caustic, radioactive liquid waste, such as neutralized Purex-type waste, or salts or oxide produced by evaporation or calcination of these liquid wastes (e.g., anhydrous salt cake) is converted at a temperature within the range of 30.degree. C to 100.degree. C to the solid mineral form-cancrinite having an approximate chemical formula 2(NaAlSiO.sub.4) .sup.. xSalt.sup.. y H.sub.2 O with x = 0.52 and y = 0.68 when the entrapped salt is NaNO.sub.3. In another embodiment the sodium nitrate-containing, caustic, radioactive liquid is reacted with the powdered aluminum silicate clay at a temperature within the range of 30.degree. C to 100.degree. C, the resulting reaction product is air dried eitheras loose powder or molded shapes (e.g., bricks) and then fired at a temperature of at least 600.degree. C to form the solid mineral form-nepheline which has the approximate chemical formula of NaAlSiO.sub.4. The leach rate of the entrapped radioactive salts with distilled water is reduced essentially to that of the aluminosilicate lattice which is very low, e.g., in the range of 10.sup.-.sup.2 to 10.sup.-.sup.4 g/cm.sup.2 -- day for cancrinite and 10.sup.-.sup.3 to 10.sup.-.sup.5 g/cm.sup.2 -- day for nepheline.

Sonic boom measurements from accelerating supersonic tracked sleds

NASA Technical Reports Server (NTRS)

Reed, J. W.

1974-01-01

Supersonic sled tests on the Sandia 1524-m (5000-ft) track generate sonic booms of sufficient intensity to allow some airblast measurements at distance scales not obtained from wind tunnel or flight tests. During acceleration, an emitted curved boom wave propagates to a caustic, or focus. Detailed measurements around these caustics may help to clarify the overpressure magnification which can occur from real aircraft operations. Six fixed pressure gages have been operated to document the general noise field, and a mobile array of twelve gages.

[Poisoning by household products].

PubMed

Lambert, H; Manel, J; Gabrion, I

2000-02-15

Caustic products are responsible for the most serious cases of poisoning, which are always emergency cases. Application of current intervention procedures has decreased both morbidity and mortality. Water-diluted bleach, the ingestion of which remains extremely frequent, is a moderate irritant rather than a caustic product. Emission of gas produced when mixing bleach with other agents can be responsible for choking gas poisoning. Anionic and nonionic detergents are mostly dangerous because of their foam-producing properties. Mercury vapours and methanol are other potentially hazardous products.

Wave Chaos and HPM Effects on Electronic Systems

DTIC Science & Technology

2013-08-13

if one examines these pas- sages, one will find that, as the orbit length approaches infinity, (i) the fraction of time spent by the orbit in the...as the orbits in a complete quarter circle billiard having the same radius R (see Fig. 3.2(a)). These orbits are tangent to a circular caustic 62 with...a radius Cr. If the caustic radius Cr > ρ0, (see Fig. 3.1) this orbit is trapped in the cap, and is integrable. There are also chaotic orbits that

Minutes of the Explosives Safety Seminar (25th) Held in Anaheim, California on 18-20 August 1992. Volume 1

DTIC Science & Technology

1992-08-20

project. There is no doubt that we would have otherwise spent many years in proving project feasibility and trialing the specific demilitarisation...SUCH ROCKET MOTORS AS THE ONE USED IN THE BULLPUP SYSTEM WERE CONSIDERED. A. DRAINING AND NEUTRALIZING THE OXIDIZER BY CAUSTIC SODA AND THEN SIMPLE...INHIBITED RED FUMING NITRIC ACID WAS DETECTED IN SMALL AMOUNTS. 482 CONSEQUENTLY. THE "EMPTY" CASES WERE PLACED INTO A TANK CONTAINING WATER AND CAUSTIC

Efficient statistical mapping of avian count data

USGS Publications Warehouse

Royle, J. Andrew; Wikle, C.K.

2005-01-01

We develop a spatial modeling framework for count data that is efficient to implement in high-dimensional prediction problems. We consider spectral parameterizations for the spatially varying mean of a Poisson model. The spectral parameterization of the spatial process is very computationally efficient, enabling effective estimation and prediction in large problems using Markov chain Monte Carlo techniques. We apply this model to creating avian relative abundance maps from North American Breeding Bird Survey (BBS) data. Variation in the ability of observers to count birds is modeled as spatially independent noise, resulting in over-dispersion relative to the Poisson assumption. This approach represents an improvement over existing approaches used for spatial modeling of BBS data which are either inefficient for continental scale modeling and prediction or fail to accommodate important distributional features of count data thus leading to inaccurate accounting of prediction uncertainty.

Arraycount, an algorithm for automatic cell counting in microwell arrays.

PubMed

Kachouie, Nezamoddin; Kang, Lifeng; Khademhosseini, Ali

2009-09-01

Microscale technologies have emerged as a powerful tool for studying and manipulating biological systems and miniaturizing experiments. However, the lack of software complementing these techniques has made it difficult to apply them for many high-throughput experiments. This work establishes Arraycount, an approach to automatically count cells in microwell arrays. The procedure consists of fluorescent microscope imaging of cells that are seeded in microwells of a microarray system and then analyzing images via computer to recognize the array and count cells inside each microwell. To start counting, green and red fluorescent images (representing live and dead cells, respectively) are extracted from the original image and processed separately. A template-matching algorithm is proposed in which pre-defined well and cell templates are matched against the red and green images to locate microwells and cells. Subsequently, local maxima in the correlation maps are determined and local maxima maps are thresholded. At the end, the software records the cell counts for each detected microwell on the original image in high-throughput. The automated counting was shown to be accurate compared with manual counting, with a difference of approximately 1-2 cells per microwell: based on cell concentration, the absolute difference between manual and automatic counting measurements was 2.5-13%.

Anaerobic degradation of renewable biomass for production of methane

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rajoka, M.I.; Tabassum, R.; Malik, K.A.

1996-12-31

Anaerobic degradation of renewable biomass namely kallar grass (KG) (Leptochloafusca L. Kunth), Atriplex sp, wheat straw, cotton stalk, cotton lint and molasses was carried out at 37{degrees}C in a 15 litre fermentor, using laboratory enriched co-culture of fermentative, acetogenic and methanogenic organisms. Maximum reduction of volatile solids (VS) was from causticized KG, and cotton lint, followed by causticized wheat straw and Atriplex sp. followed by causticized wheat straw and Atriplex sp. Maximum production of methane was obtained from NaOH-pretreated KG with a process product yield (Y{sub p/s}) of 0.9 m{sup 3}/kg VS with a volumetric productivity (Q{sub p}) of 4.24more » L/day after 19 days of fermentation. Maximum methane content in the gas mixture was 96% with average of 78.6{+-}21.6. The Y{sub p/s} in 1000 litre digestor was 0.7 m{sup 3}/kg VS from a 3% suspension of uncaustisized kallar grass.« less

Effect of magnetic starch on the clarification of hematite tailings wastewater

NASA Astrophysics Data System (ADS)

Yue, Tao; Wu, Xiqing

2018-02-01

The magnetic starch solution, synthesized by mixing the caustic starch, the Fe2+ solution (in some cases containing the Zn2+, Cu2+, Mn2+ or Mg2+ ions) and H2O2 solution, was used as the flocculant to investigate its clarification effect on hematite tailings wastewater. Based on the clarification tests and adsorption analysis it was demonstrated that the magnetic starch produced better clarification effect than the caustic starch, and the adsorption of magnetic starch onto hematite tailings particles was also stronger than the caustic starch. AFM found that the magnetic interaction between magnetic seeds and hematite is characteristic of long range force and greatly strengthens the adsorption of magnetic seeds onto fine hematite for agglomeration. FTIR indicates the starch adsorbed onto the surfaces of hematite and magnetic seeds, thus acting as the bridging between hematite particles and magnetic seeds, resulting in an intensified coverage of the starch onto hematite and positive action in the clarification.

Microbial Fuel Cell-driven caustic potash production from wastewater for carbon sequestration.

PubMed

Gajda, Iwona; Greenman, John; Melhuish, Chris; Santoro, Carlo; Ieropoulos, Ioannis

2016-09-01

This work reports on the novel formation of caustic potash (KOH) directly on the MFC cathode locking carbon dioxide into potassium bicarbonate salt (kalicinite) while producing, instead of consuming electrical power. Using potassium-rich wastewater as a fuel for microorganisms to generate electricity in the anode chamber, has resulted in the formation of caustic catholyte directly on the surface of the cathode electrode. Analysis of this liquid has shown to be highly alkaline (pH>13) and act as a CO2 sorbent. It has been later mineralised to kalicinite thus locking carbon dioxide into potassium bicarbonate salt. This work demonstrates an electricity generation method as a simple, cost-effective and environmentally friendly route towards CO2 sequestration that perhaps leads to a carbon negative economy. Moreover, it shows a potential application for both electricity production and nutrient recovery in the form of minerals from nutrient-rich wastewater streams such as urine for use as fertiliser in the future. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.

Sodium to sodium carbonate conversion process

DOEpatents

Herrmann, S.D.

1997-10-14

A method is described for converting radioactive alkali metal into a low level disposable solid waste material. The radioactive alkali metal is atomized and introduced into an aqueous caustic solution having caustic present in the range of from about 20 wt % to about 70 wt % to convert the radioactive alkali metal to a radioactive alkali metal hydroxide. The aqueous caustic containing radioactive alkali metal hydroxide and CO{sub 2} are introduced into a thin film evaporator with the CO{sub 2} present in an amount greater than required to convert the alkali metal hydroxide to a radioactive alkali metal carbonate, and thereafter the radioactive alkali metal carbonate is separated from the thin film evaporator as a dry powder. Hydroxide solutions containing toxic metal hydroxide including one or more metal ions of Sb, As, Ba, Be, Cd, Cr, Pb, Hg, Ni, Se, Ag and Tl can be converted into a low level non-hazardous waste using the thin film evaporator of the invention. 3 figs.

Effect of solvent addition sequence on lycopene extraction efficiency from membrane neutralized caustic peeled tomato waste.

PubMed

Phinney, David M; Frelka, John C; Cooperstone, Jessica L; Schwartz, Steven J; Heldman, Dennis R

2017-01-15

Lycopene is a high value nutraceutical and its isolation from waste streams is often desirable to maximize profits. This research investigated solvent addition order and composition on lycopene extraction efficiency from a commercial tomato waste stream (pH 12.5, solids ∼5%) that was neutralized using membrane filtration. Constant volume dilution (CVD) was used to desalinate the caustic salt to neutralize the waste. Acetone, ethanol and hexane were used as direct or blended additions. Extraction efficiency was defined as the amount of lycopene extracted divided by the total lycopene in the sample. The CVD operation reduced the active alkali of the waste from 0.66 to <0.01M and the moisture content of the pulp increased from 93% to 97% (wet basis), showing the removal of caustic salts from the waste. Extraction efficiency varied from 32.5% to 94.5%. This study demonstrates a lab scale feasibility to extract lycopene efficiently from tomato processing byproducts. Published by Elsevier Ltd.

Relativistic Effects and Polarization in Three High-Energy Pulsar Models

NASA Technical Reports Server (NTRS)

Dyks, J.; Harding, Alice K.; Rudak, B.

2004-01-01

We present the influence of the special relativistic effects of aberration and light travel time delay on pulsar high-energy lightcurves and polarization characteristics predicted by three models: the two-pole caustic model, the outer gap model, and the polar cap model. Position angle curves and degree of polarization are calculated for the models and compared with the optical data on the Crab pulsar. The relative positions of peaks in gamma-ray and radio lightcurves are discussed in detail for the models. We find that the two-pole caustic model can reproduce qualitatively the optical polarization characteristics of the Crab pulsar - fast swings of the position angle and minima in polarization degree associated with both peaks. The anticorrelation between the observed flux and the polarization degree (observed in the optical band also for B0656+14) naturally results from the caustic nature of the peaks which are produced in the model due to the superposition of radiation from many different altitudes, ie. polarized at different angles. The two-pole caustic model also provides an acceptable interpretation of the main features in the Crab's radio profile. Neither the outer gap model nor the polar cap model are able to reproduce the optical polarization data on the Crab. Although the outer gap model is very successful in reproducing the relative positions of gamma-ray and radio peaks in pulse profiles, it can reproduce the high-energy lightcurves only when photon emission from regions very close to the light cylinder is included.

U.S. Level III and IV Ecoregions (U.S. EPA)

EPA Pesticide Factsheets

This map service displays Level III and Level IV Ecoregions of the United States and was created from ecoregion data obtained from the U.S. Environmental Protection Agency Office of Research and Development's Western Ecology Division. The original ecoregion data was projected from Albers to Web Mercator for this map service. To download shapefiles of ecoregion data (in Albers), please go to: ftp://newftp.epa.gov/EPADataCommons/ORD/Ecoregions/. IMPORTANT NOTE ABOUT LEVEL IV POLYGON LEGEND DISPLAY IN ARCMAP: Due to the limitations of Graphical Device Interface (GDI) resources per application on Windows, ArcMap does not display the legend in the Table of Contents for the ArcGIS Server service layer if the legend has more than 100 items. As of December 2011, there are 968 unique legend items in the Level IV Ecoregion Polygon legend. Follow this link (http://support.esri.com/en/knowledgebase/techarticles/detail/33741) for instructions about how to increase the maximum number of ArcGIS Server service layer legend items allowed for display in ArcMap. Note the instructions at this link provide a slightly incorrect path to Maximum Legend Count. The correct path is HKEY_CURRENT_USER > Software > ESRI > ArcMap > Server > MapServerLayer > Maximum Legend Count. When editing the Maximum Legend Count, update the field, Value data to 1000. To download a PDF version of the Level IV ecoregion map and legend, go to ftp://newftp.epa.gov/EPADataCommons/ORD/Ecoregions/us/Eco_Level_IV

Seismic structures in the inner and outer core constrained by the PKP observations near the caustic distance range

NASA Astrophysics Data System (ADS)

Yu, W.; Wen, L.; Niu, F.

2002-05-01

We have extensively collected PKP waveforms around the PKP caustic distance range (141o - 147o) recorded in several dense regional arrays and the Global Seismic Network covering from 1990 to 2000. PKP observations at this distance range (141o - 147o) are usually purposely avoided in travel time analyses, because of the interference of various PKP branches. The observations there, however, will be extremely useful for constraining the seismic structures at both the top of the inner core and the bottom of the outer core. Moreover, because PKIKP phases sample a depth range of 100 km - 170 km below the inner-core boundary at this distant range, their observations fill the sampling depth gap between the PKiKP-PKIKP observations at the smaller distances and the PKPbc-PKIKP phases at the larger distances. Before the PKP caustics (141o - 145o), the diffracted PKP phases near the B caustics (PKPBdiff) and PKiKP phases are discernible in the long-period seismograms, and their differential travel times and waveforms could be used to constrain seismic structures at the bottom of the outer core and/or at the base of the mantle. The observed long-period PKiKP-PKPBdiff waveforms exhibit a hemispheric difference between those sampling the "eastern" and "western" hemispheres, with those sampling the "western" hemisphere showing larger time separations between the two phases. These observations can be explained by models with P velocity gradients of 0.0806 (km/s)/ 200 km for the "western" hemisphere and 0.114 (km/s)/200 km for the "eastern" hemisphere at the bottom of the outer core. Alternatively, these observations can also be explained by models with different velocity structures at the bottom 200 km of the mantle with P velocity variations in an order of 3 percent with respect to PREM. Broadband PKP observations after the PKP caustics (145o - 147o), on the other hand, provide high-quality constraints on the seismic structures at both the top of the inner core and the bottom of the outer core, as PKPbc phases can be used as excellent reference phases. We explore seismic models in both the bottom of the outer core and the top of the inner core, which can consistently explain the seismic observations at the caustic distance range (141o - 147o) and the PKiKP-PKIKP observations at the closer distances (Niu and Wen, Nature, 410, 1081-1084, 2001, Wen and Niu, JGR, submitted).

What Is the Role of Manual Preference in Hand-Digit Mapping During Finger Counting? A Study in a Large Sample of Right- and Left-Handers.

PubMed

Zago, Laure; Badets, Arnaud

2016-01-01

The goal of the present study was to test whether there is a relationship between manual preference and hand-digit mapping in 369 French adults with similar numbers of right- and left-handers. Manual laterality was evaluated with the finger tapping test to evaluate hand motor asymmetry, and the Edinburgh handedness inventory was used to assess manual preference strength (MPS) and direction. Participants were asked to spontaneously "count on their fingers from 1 to 10" without indications concerning the hand(s) to be used. The results indicated that both MPS and hand motor asymmetry affect the hand-starting preference for counting. Left-handers with a strong left-hand preference (sLH) or left-hand motor asymmetry largely started to count with their left hand (left-starter), while right-handers with a strong right-hand preference (sRH) or right-hand motor asymmetry largely started to count with their right hand (right-starter). Notably, individuals with weak MPS did not show a hand-starting preference. These findings demonstrated that manual laterality contributes to finger counting directionality. Lastly, the results showed a higher proportion of sLH left-starter individuals compared with sRH right-starters, indicating an asymmetric bias of MPS on hand-starting preference. We hypothesize that the higher proportion of sLH left-starters could be explained by the congruence between left-to-right hand-digit mapping and left-to-right mental number line representation that has been largely reported in the literature. Taken together, these results indicate that finger-counting habits integrate biological and cultural information. © The Author(s) 2015.

Solid immersion terahertz imaging with sub-wavelength resolution

NASA Astrophysics Data System (ADS)

Chernomyrdin, Nikita V.; Schadko, Aleksander O.; Lebedev, Sergey P.; Tolstoguzov, Viktor L.; Kurlov, Vladimir N.; Reshetov, Igor V.; Spektor, Igor E.; Skorobogatiy, Maksim; Yurchenko, Stanislav O.; Zaytsev, Kirill I.

2017-05-01

We have developed a method of solid immersion THz imaging—a non-contact technique employing the THz beam focused into evanescent-field volume and allowing strong reduction in the dimensions of THz caustic. We have combined numerical simulations and experimental studies to demonstrate a sub-wavelength 0.35λ0-resolution of the solid immersion THz imaging system compared to 0.85λ0-resolution of a standard imaging system, employing only an aspherical singlet. We have discussed the prospective of using the developed technique in various branches of THz science and technology, namely, for THz measurements of solid-state materials featuring sub-wavelength variations of physical properties, for highly accurate mapping of healthy and pathological tissues in THz medical diagnosis, for detection of sub-wavelength defects in THz non-destructive sensing, and for enhancement of THz nonlinear effects.

Tooele Army Depot - South Area Suspected Release Units. RCRA Facility Investigation - Phase 2, for SWMUs 1, 25, and 27

DTIC Science & Technology

1995-11-01

Thickener (25% naphthenic acids) (25% oleic acid) Source: NUS 1987, Departments of the Army and Air Force 1963 2-8 TOO/TBL0025 07/21/94 11:45 am bpw S-60...Assessment does not state whether incineration occurred at SWMU 1 or elsewhere. The AC containers were decontaminated at SWMU 1 by rinsing with caustic ... caustic decontaminating agents that may have been applied during disposal. Decontaminating agents used include DANC (a mixture of sodium hydroxide and

Experimental colitis is exacerbated by concomitant infection with Mycobacterium avium ssp. paratuberculosis.

PubMed

Suwandi, Abdulhadi; Bargen, Imke; Roy, Bishnudeo; Pils, Marina C; Krey, Martina; Zur Lage, Susanne; Basler, Tina; Rohde, Manfred; Falk, Christine S; Hornef, Mathias W; Goethe, Ralph; Weiss, Siegfried

2014-11-01

Crohn's disease (CD) is a chronic inflammatory disorder of the human gastrointestinal tract. Although genetic, immunological, environmental, and bacterial factors have been implicated, the pathogenesis is incompletely understood. The histopathological appearance of CD strikingly resembles Johne's disease, a ruminant inflammatory bowel disease, caused by Mycobacterium avium ssp. paratuberculosis (MAP), but a causative role of MAP in CD has not been established. In this work, we hypothesized that MAP might exacerbate an already existing intestinal disease. We combined dextran sulfate sodium (DSS)-induced colitis with MAP infection in mice and monitored the immune response and bacterial count in different organs. An increased size of liver and spleen was observed in DSS-treated and MAP-infected animals (DSS + MAP) as compared with DSS-treated uninfected (DSS + PBS) mice. Similarly, DSS treatment increased the number and size of MAP-induced liver granulomas and enhanced the MAP counts in enteric tissue. MAP infection in turn delayed the mucosal healing of DSS-induced tissue damage. Finally, high numbers of MAP were found in mesenteric fat tissue causing large granuloma and necrotic regions. Taken together, we present an in vivo model to study the role of MAP infection in CD. Our results confirm the hypothesis that MAP is able to exacerbate existing intestinal inflammation.

Mapping Mixed Methods Research: Methods, Measures, and Meaning

ERIC Educational Resources Information Center

Wheeldon, J.

2010-01-01

This article explores how concept maps and mind maps can be used as data collection tools in mixed methods research to combine the clarity of quantitative counts with the nuance of qualitative reflections. Based on more traditional mixed methods approaches, this article details how the use of pre/post concept maps can be used to design qualitative…

On the Observability of Individual Population III Stars and Their Stellar-mass Black Hole Accretion Disks through Cluster Caustic Transits

NASA Astrophysics Data System (ADS)

Windhorst, Rogier A.; Wyithe, Stuart; Alpaslan, Mehmet; Timmes, F. X.; Andrews, Stephen K.; Kim, Duho; Kelly, Patrick; Coe, Dan A.; Diego, Jose M.; Driver, Simon P.; Dijkstra, Mark

2018-06-01

We summarize panchromatic Extragalactic Background Light data to place upper limits on the integrated near-IR surface brightness (SB) that may come from Population III stars and possible accretion disks around their stellar-mass black holes (BHs) in the epoch of First Light, broadly taken from z=7-17.We outline the physical properties of zero-metallicity Population III stars from MESA stellar evolution models through helium depletion and of BH accretion disks at z>7. We assume that second-generation non-zero-metallicity stars can form at higher multiplicity, so that BH accretion disks may be fed by Roche-lobe overflow from lower-mass companions.We use these near-infrared SB constraints to calculate the number of caustic transits behind lensing clusters that the James Webb Space Telescope and the next-generation ground-based telescopes may observe for both Population III stars and their BH accretion disks. Typical caustic magnifications can be 10^4-10^5x, with rise times of hours and decline times of z~<1 year for cluster transverse velocities of v_T<~1000 km/s.Microlensing by intracluster-medium objects can modify transit magnifications but lengthen visibility times. Depending on BH masses, accretion-disk radii, and feeding efficiencies, stellar-mass BH accretion-disk caustic transits could outnumber those from Population III stars. To observe Population III caustic transits directly may require monitoring 3-30 lensing clusters to AB<29 mag over a decade (see Windhorst et al. 2018, ApJS, 234, 41; astro-ph/1801.03584).This work was supported by NASA JWST Interdisciplinary Scientist grants NAG5-12460, NX14AN10G, and 80NSSC18K0200, NASA Theoretical and Computational Astrophysics Networks grant NNX14AB53G, NSF Software Infrastructure for Sustained Innovation grant 1339600, NSF Physics Frontier Center JINA-CEE grant PHY-1430152, Australian Research Council projects AYA2015-64508-P, AYA2012-39475-C02-01, and Ministerio de Economia y Competitividad of Spain Consolider Project CSD2010-00064.

Non linear shock wave propagation in heterogeneous fluids: a numerical approach beyond the parabolic approximation with application to sonic boom.

NASA Astrophysics Data System (ADS)

Dagrau, Franck; Coulouvrat, François; Marchiano, Régis; Héron, Nicolas

2008-06-01

Dassault Aviation as a civil aircraft manufacturer is studying the feasibility of a supersonic business jet with the target of an "acceptable" sonic boom at the ground level, and in particular in case of focusing. A sonic boom computational process has been performed, that takes into account meteorological effects and aircraft manoeuvres. Turn manoeuvres and aircraft acceleration create zones of convergence of rays (caustics) which are the place of sound amplification. Therefore two elements have to be evaluated: firstly the geometrical position of the caustics, and secondly the noise level in the neighbourhood of the caustics. The modelling of the sonic boom propagation is based essentially on the assumptions of geometrical acoustics. Ray tracing is obtained according to Fermat's principle as paths that minimise the propagation time between the source (the aircraft) and the receiver. Wave amplitude and time waveform result from the solution of the inviscid Burgers' equation written along each individual ray. The "age variable" measuring the cumulative nonlinear effects is linked to the ray tube area. Caustics are located as the place where the ray tube area vanishes. Since geometrical acoustics does not take into account diffraction effects, it breaks down in the neighbourhood of caustics where it would predict unphysical infinite pressure amplitude. The aim of this study is to describe an original method for computing the focused noise level. The approach involves three main steps that can be summarised as follows. The propagation equation is solved by a forward marching procedure split into three successive steps: linear propagation in a homogeneous medium, linear perturbation due to the weak heterogeneity of the medium, and non-linear effects. The first step is solved using an "exact" angular spectrum algorithm. Parabolic approximation is applied only for the weak perturbation due to the heterogeneities. Finally, non linear effects are performed by solving the in-viscid Burgers' equation. As this one is valid for a plane wave, the direction of this last one is not prescribed a priori, but is computed in a self-adaptative way using an efficient numerical solver of the non-linear eikonal equation (Fast Marching Method).

Effects of Hydrated Potato Starch on the Quality of Low-fat Ttoekgalbi (Korean Traditional Patty) Packaged in Modified Atmosphere Conditions during Storage.

PubMed

Muhlisin, S M Kang; Choi, W H; Lee, K T; Cheong, S H; Lee, S K

2012-05-01

This study was carried out to investigate the effects of hydrated potato starch on the quality of low-fat ttoekgalbi (Korean traditional patty) packaged in modified atmosphere conditions during storage. The ttoekgalbi was prepared from 53.2% lean beef, 13.9% lean pork, 9.3% pork fat, and 23.6% other ingredients. Two low-fat ttoekgalbi treatments were prepared by substituting pork fat with hydrated potato starch; either by 50% fat replacement (50% FR) or 100% fat replacement (100% FR). Both 50% and 100% FR increased the moisture, crude protein, and decreased fat content, cooking loss, and hardness. For MAP studies, 200 g of ttoekgalbi were placed on the tray and filled with gas composed of 70% O2: 30% CO2 (70% O2-MAP) and 30% CO2: 70% N2 (70% N2-MAP), and were stored at 5°C for 12 d. During the storage time, both 50% and 100% FR showed higher protein deterioration, while no differences were found in CIE a*, CIE L*, lipid oxidation, and bacterial counts in comparison to control. The ttoekgalbi with 70% O2-MAP was more red, lighter in color, and showed higher TBARS values compared with 70% N2-MAP. The meat with 70% N2-MAP showed lower aerobic bacterial counts in control than those with 70% O2-MAP. The lower anaerobic bacterial counts were observed only in 50% FR and 100% FR packed with 70% N2-MAP in comparison with 70% O2-MAP. In conclusion, the fat replacement with hydrated potato starch showed no negative effects on the quality of low fat ttoekgalbi during storage and 70% N2-MAP was better than 70% O2-MAP for low-fat ttoekgalbi packaging.

POSTERIOR PREDICTIVE MODEL CHECKS FOR DISEASE MAPPING MODELS. (R827257)

EPA Science Inventory

Disease incidence or disease mortality rates for small areas are often displayed on maps. Maps of raw rates, disease counts divided by the total population at risk, have been criticized as unreliable due to non-constant variance associated with heterogeneity in base population si...

TOXIC EXPOSURES IN CHILDREN INVOLVING LEGALLY AND ILLEGALLY COMMERCIALIZED HOUSEHOLD SANITIZERS

PubMed Central

Campos, Alessandra Marcuz de Souza; Bucaretchi, Fábio; Fernandes, Luciane Cristina Rodrigues; Fernandes, Carla Borrasca; de Capitani, Eduardo Mello; Beck, Ana Raquel Medeiros

2017-01-01

ABSTRACT Objectives: To analyze and to compare clinical repercussions of accidents involving legally and illegally commercialized household sanitizers in children under 7 years of age. Methods: A descriptive cross-sectional design was used to collect data from electronic database of a regional Poison Control Center during one year. Data were analyzed by means of descriptive non-parametric statistics and association tests. Results: The sample had 737 reported cases. Most of the accidents occurred with children under 3 years of age (median: 1 year of age; interquartile interval: 1-3 years of age), at home (92.9%), by ingestion (97.2%). Products involved were cleaning products with low toxicity and no caustic effects (38.9%); caustics (24.1%); hydrocarbons (19.3%); pesticides/rodenticides (16.6%), and other products (1.1%). Seventy accidents were due to exposures to illegal products, mainly caustics (n=47) and rodenticides (n=15). Among the 337 children presenting post-exposure clinical manifestations, the most frequent were vomiting (n=125), oral burns (n=74), cough (n=35), drooling (n=26), and abdominal pain (n=25). Clinical manifestations were significantly more frequent after illegal products exposure (55/70 versus 282/667, p<0.01). Nineteen children had to be hospitalized (caustics, n=17; illegal products, n=12; median time of hospitalization: 2 days), 22 were submitted to esophagogastroduodenoscopy (sodium hydroxide, n=14; illegal products, n=14); and 12 cases had endoscopic alterations (severe in 2). No deaths occurred. Conclusion: Toxic exposures owing to illegal household sanitizer products are associated with greater morbidity when compared with legal ones. PMID:28977311

Patients Admitted to Three Spanish Intensive Care Units for Poisoning: Type of Poisoning, Mortality, and Functioning of Prognostic Scores Commonly Used

PubMed Central

Banderas-Bravo, María Esther; Arias-Verdú, Maria Dolores; Macías-Guarasa, Ines; Castillo-Lorente, Encarnación; Pérez-Costillas, Lucia; Gutierrez-Rodriguez, Raquel; Quesada-García, Guillermo; Rivera-Fernández, Ricardo

2017-01-01

Objectives. To evaluate the gravity and mortality of those patients admitted to the intensive care unit for poisoning. Also, the applicability and predicted capacity of prognostic scales most frequently used in ICU must be evaluated. Methods. Multicentre study between 2008 and 2013 on all patients admitted for poisoning. Results. The results are from 119 patients. The causes of poisoning were medication, 92 patients (77.3%), caustics, 11 (9.2%), and alcohol, 20 (16,8%). 78.3% attempted suicides. Mean age was 44.42 ± 13.85 years. 72.5% had a Glasgow Coma Scale (GCS) ≤8 points. The ICU mortality was 5.9% and the hospital mortality was 6.7%. The mortality from caustic poisoning was 54.5%, and it was 1.9% for noncaustic poisoning (p < 0.001). After adjusting for SAPS-3 (OR: 1.19 (1.02–1.39)) the mortality of patients who had ingested caustics was far higher than the rest (OR: 560.34 (11.64–26973.83)). There was considerable discrepancy between mortality predicted by SAPS-3 (26.8%) and observed (6.7%) (Hosmer-Lemeshow test: H = 35.10; p < 0.001). The APACHE-II (7,57%) and APACHE-III (8,15%) were no discrepancies. Conclusions. Admission to ICU for poisoning is rare in our country. Medication is the most frequent cause, but mortality of caustic poisoning is higher. APACHE-II and APACHE-III provide adequate predictions about mortality, while SAPS-3 tends to overestimate. PMID:28459061

AMDTreat 5.0+ with PHREEQC titration module to compute caustic chemical quantity, effluent quality, and sludge volume

USGS Publications Warehouse

Cravotta, Charles A.; Means, Brent P; Arthur, Willam; McKenzie, Robert M; Parkhurst, David L.

2015-01-01

Alkaline chemicals are commonly added to discharges from coal mines to increase pH and decrease concentrations of acidity and dissolved aluminum, iron, manganese, and associated metals. The annual cost of chemical treatment depends on the type and quantities of chemicals added and sludge produced. The AMDTreat computer program, initially developed in 2003, is widely used to compute such costs on the basis of the user-specified flow rate and water quality data for the untreated AMD. Although AMDTreat can use results of empirical titration of net-acidic or net-alkaline effluent with caustic chemicals to accurately estimate costs for treatment, such empirical data are rarely available. A titration simulation module using the geochemical program PHREEQC has been incorporated with AMDTreat 5.0+ to improve the capability of AMDTreat to estimate: (1) the quantity and cost of caustic chemicals to attain a target pH, (2) the chemical composition of the treated effluent, and (3) the volume of sludge produced by the treatment. The simulated titration results for selected caustic chemicals (NaOH, CaO, Ca(OH)2, Na2CO3, or NH3) without aeration or with pre-aeration can be compared with or used in place of empirical titration data to estimate chemical quantities, treated effluent composition, sludge volume (precipitated metals plus unreacted chemical), and associated treatment costs. This paper describes the development, evaluation, and potential utilization of the PHREEQC titration module with the new AMDTreat 5.0+ computer program available at http://www.amd.osmre.gov/.

Regeneration of iron-based adsorptive media used for removing arsenic from groundwater.

PubMed

Chen, Abraham S C; Sorg, Thomas J; Wang, Lili

2015-06-15

Adsorptive media technology is regarded as a simple, low cost method of removing arsenic from drinking water particularly for small systems. Currently, when the effluent of a treatment system reaches the USEPA maximum contaminant level (MCL) of 10 ug/L, the exhausted media is removed and replaced by new virgin media. Although the commonly used iron-based media products are reasonable in price, the replacement cost accounts for around 80% of the systems total operational costs. One option to media replacement is on-site regeneration and reuse of the exhausted media. To determine whether an iron based media can be successfully regenerated and reused, laboratory batch and column regeneration tests were conducted on six exhausted iron-based media products obtained from six full scale arsenic removal treatment systems. Batch tests conducted on three of the media products to evaluate the effectiveness of 1-6% caustic regenerant solutions found that arsenic desorption increased until around 4%. Using 4% caustic solutions, the columns tests on the six exhausted media products showed arsenic removals ranged from 25 to 90% with the best results obtained with the Severn Trent E33 media. Exposing the media to caustic (pH ≥ 13) and acid (pH ≤ 2) solutions found minimal media loss with the caustic solution, but significant media dissolution with a pH 2 acid solution. A six column pilot plant test at an Ohio test site with the lab regenerated media products found that the regenerated media could achieve arsenic removals somewhat similar to virgin media. Copyright © 2015 Elsevier Ltd. All rights reserved.

Inhibition of the acetoclastic methanogenic activity by phenol and alkyl phenols.

PubMed

Olguin-Lora, P; Puig-Grajales, L; Razo-Flores, E

2003-08-01

Chemical and petrochemical industries are important sources of aromatic pollutants. Petrochemical processes like caustic washing of middle distillates produce the spent caustic liquors highly concentrated in phenol and alkyl phenols. The anaerobic technology is considered a feasible strategy for petrochemical wastewater pre-treatment although high concentrations of phenol could limit its efficiency. The goal of this work was to determine the toxicity of both selected alkyl phenols and a synthetic "spent-caustic phenols mixture" on the acetoclastic Specific Methanogenic Activity (SMA) of unadapted and phenol-adapted granular sludge. Alkyl phenols were responsible for 50% (IC50) and 100% (IC100) inhibition of the SMA at concentrations ranging from 1.6 to 5.0 mM and from 4.1 to 27.5 mM, respectively, for un-adapted granular sludge. In the case of phenol-adapted granular sludge, the inhibitory concentrations ranged from 1.7 to 14.9 mM and from 4.0 to 83.0 for IC50 and IC100, respectively, highlighting the impact of sludge acclimation. The inhibition produced by 2-ethylphenol was more acute compared to phenol and was not reduced by the phenol acclimation process. The IC50 and IC100 values obtained for the synthetic "spent-caustic phenols mixture" were 9.5 mM and 88.4 mM, respectively. The inhibitory concentrations of phenol compounds were closely correlated with compound apolarity (log P), indicating that the lipophilic character of the tested compounds was responsible for their methanogenic toxicity. An inhibition model is confirmed to estimate the IC50 and IC100.

Modeling and mapping abundance of American Woodcock across the Midwestern and Northeastern United States

USGS Publications Warehouse

Thogmartin, W.E.; Sauer, J.R.; Knutson, M.G.

2007-01-01

We used an over-dispersed Poisson regression with fixed and random effects, fitted by Markov chain Monte Carlo methods, to model population spatial patterns of relative abundance of American woodcock (Scolopax minor) across its breeding range in the United States. We predicted North American woodcock Singing Ground Survey counts with a log-linear function of explanatory variables describing habitat, year effects, and observer effects. The model also included a conditional autoregressive term representing potential correlation between adjacent route counts. Categories of explanatory habitat variables in the model included land-cover composition, climate, terrain heterogeneity, and human influence. Woodcock counts were higher in landscapes with more forest, especially aspen (Populus tremuloides) and birch (Betula spp.) forest, and in locations with a high degree of interspersion among forest, shrubs, and grasslands. Woodcock counts were lower in landscapes with a high degree of human development. The most noteworthy practical application of this spatial modeling approach was the ability to map predicted relative abundance. Based on a map of predicted relative abundance derived from the posterior parameter estimates, we identified major concentrations of woodcock abundance in east-central Minnesota, USA, the intersection of Vermont, USA, New York, USA, and Ontario, Canada, the upper peninsula of Michigan, USA, and St. Lawrence County, New York. The functional relations we elucidated for the American woodcock provide a basis for the development of management programs and the model and map may serve to focus management and monitoring on areas and habitat features important to American woodcock.

Dual-contrast agent photon-counting computed tomography of the heart: initial experience.

PubMed

Symons, Rolf; Cork, Tyler E; Lakshmanan, Manu N; Evers, Robert; Davies-Venn, Cynthia; Rice, Kelly A; Thomas, Marvin L; Liu, Chia-Ying; Kappler, Steffen; Ulzheimer, Stefan; Sandfort, Veit; Bluemke, David A; Pourmorteza, Amir

2017-08-01

To determine the feasibility of dual-contrast agent imaging of the heart using photon-counting detector (PCD) computed tomography (CT) to simultaneously assess both first-pass and late enhancement of the myocardium. An occlusion-reperfusion canine model of myocardial infarction was used. Gadolinium-based contrast was injected 10 min prior to PCD CT. Iodinated contrast was infused immediately prior to PCD CT, thus capturing late gadolinium enhancement as well as first-pass iodine enhancement. Gadolinium and iodine maps were calculated using a linear material decomposition technique and compared to single-energy (conventional) images. PCD images were compared to in vivo and ex vivo magnetic resonance imaging (MRI) and histology. For infarct versus remote myocardium, contrast-to-noise ratio (CNR) was maximal on late enhancement gadolinium maps (CNR 9.0 ± 0.8, 6.6 ± 0.7, and 0.4 ± 0.4, p < 0.001 for gadolinium maps, single-energy images, and iodine maps, respectively). For infarct versus blood pool, CNR was maximum for iodine maps (CNR 11.8 ± 1.3, 3.8 ± 1.0, and 1.3 ± 0.4, p < 0.001 for iodine maps, gadolinium maps, and single-energy images, respectively). Combined first-pass iodine and late gadolinium maps allowed quantitative separation of blood pool, scar, and remote myocardium. MRI and histology analysis confirmed accurate PCD CT delineation of scar. Simultaneous multi-contrast agent cardiac imaging is feasible with photon-counting detector CT. These initial proof-of-concept results may provide incentives to develop new k-edge contrast agents, to investigate possible interactions between multiple simultaneously administered contrast agents, and to ultimately bring them to clinical practice.

Energy conversion performance of black liquor gasification to hydrogen production using direct causticization with CO(2) capture.

PubMed

Naqvi, M; Yan, J; Dahlquist, E

2012-04-01

This paper estimates potential hydrogen production via dry black liquor gasification system with direct causticization integrated with a reference pulp mill. The advantage of using direct causticization is elimination of energy intensive lime kiln. Pressure swing adsorption is integrated in the carbon capture process for hydrogen upgrading. The energy conversion performance of the integrated system is compared with other bio-fuel alternatives and evaluated based on system performance indicators. The results indicated a significant hydrogen production potential (about 141MW) with an energy ratio of about 0.74 from the reference black liquor capacity (about 243.5MW) and extra biomass import (about 50MW) to compensate total energy deficit. About 867,000tonnes of CO(2) abatement per year is estimated i.e. combining CO(2) capture and CO(2) offset from hydrogen replacing motor gasoline. The hydrogen production offers a substantial motor fuel replacement especially in regions with large pulp and paper industry e.g. about 63% of domestic gasoline replacement in Sweden. Copyright © 2012 Elsevier Ltd. All rights reserved.

Spent caustic oxidation using electro-generated Fenton's reagent in a batch reactor.

PubMed

Rodriguez, Nicolas; Hansen, Henrik K; Nunez, Patricio; Guzman, Jaime

2008-07-01

This work shows the results of four Electro-Fenton laboratory tests to reduce the chemical oxygen demand (COD) in spent caustic solutions. The treatment consisted of (i) a pH reduction followed by (ii) an Electro-Fenton process, which was analyzed in this work. The Fenton's reagent was produced in a specially designed reactor, where the waste stream flowed through a labyrinth made by ferrous plates. These plates acted as sacrificial anodes-releasing Fe(2 +) cations to the solution, where H(2)O(2) was also added. The Electro-Fenton process was analyzed varying the ferrous ion concentration ([Fe(+ 2)]), the spent caustic's initial temperature and the initial pH. Close to 95% removal of COD (from 8800 mg L(- 1)) was achieved at a pH of 4, a temperature of 40 degrees C and 100 mg L(- 1) of Fe(+ 2) (applying 1 A). Two models were considered to simulate the behavior of the reactor considering (i) axial dispersion and (ii) kinetic rate, respectively. The model that was based on kinetics, proved to be the slightly closest fit to the experimental values.

Investigation of transient forms of sulfur during biological treatment of spent caustic.

PubMed

Kalantari, Hamed; Nosrati, Mohsen; Shojaosadati, Seyed Abbas; Shavandi, Mahmoud

2018-06-01

In the present study, the production of various transient forms of sulfur during biological oxidation of sulfidic spent caustics under haloalkaline conditions in a stirred tank bioreactor is investigated. Also, the effects of abiotic aeration (chemical oxidation), dissolved oxygen (DO) concentration and sodium concentration on forms of sulfur during biological treatment are demonstrated. Thioalkalivibrio versutus strain was used for sulfide oxidation in spent caustic (SC). The aeration had an important effect on sulfide oxidation and its final products. At DO concentrations above 2 mg l -1 , majority of sulfide was oxidized to sulfate. Maximum sulfide removal efficiency (%R) and yield of sulfate production [Formula: see text] was obtained in Na + concentration ranging from 0.6 to 2 M. Abiotic aeration, which is the most important factor of production of thiosulfate, resulted in the formation of an undesired product-polysulfide. However, abiotic aeration can be used as a pretreatment to biological treatment. In the bioreactor the removal efficiency was obtained as 82.7% and various forms of sulfur such as polysulfide, biosulfur, thiosulfate and sulfate was observed during biological treatment of SC.

F-Area Acid/Caustic Basin groundwater monitoring report: Third quarter 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1994-12-01

During third quarter 1994, samples from the FAC monitoring wells at the F-Area Acid/Caustic Basin were collected and analyzed for herbicides/pesticides, indicator parameters, metals, nitrate, radionuclide indicators, volatile organic compounds, and other constituents. Piezometer FAC 5P and monitoring well FAC 6 were dry and could not be sampled. New monitoring wells FAC 9C, 10C, 11C, and 12C were sampled for the first time during third quarter. Analytical results that exceeded final Primary Drinking Water Standards (PDWS), other Savannah River Site (SRS) Flag 2 criteria, or the SRS turbidity standard of 50 NTU during the quarter were as follows: gross alphamore » exceeded the final PDWS and aluminum, iron, manganese, and total alpha-emitting radium exceeded the SRS Flag 2 criteria in one or more of the FAC wells. Turbidity exceeded the SRS standard in wells FAC 3 and 10C. Groundwater flow direction and rate in the water table beneath the F-Area Acid/Caustic Basin were similar to past quarters.« less

Performance of 3DOSEM and MAP algorithms for reconstructing low count SPECT acquisitions.

PubMed

Grootjans, Willem; Meeuwis, Antoi P W; Slump, Cornelis H; de Geus-Oei, Lioe-Fee; Gotthardt, Martin; Visser, Eric P

2016-12-01

Low count single photon emission computed tomography (SPECT) is becoming more important in view of whole body SPECT and reduction of radiation dose. In this study, we investigated the performance of several 3D ordered subset expectation maximization (3DOSEM) and maximum a posteriori (MAP) algorithms for reconstructing low count SPECT images. Phantom experiments were conducted using the National Electrical Manufacturers Association (NEMA) NU2 image quality (IQ) phantom. The background compartment of the phantom was filled with varying concentrations of pertechnetate and indiumchloride, simulating various clinical imaging conditions. Images were acquired using a hybrid SPECT/CT scanner and reconstructed with 3DOSEM and MAP reconstruction algorithms implemented in Siemens Syngo MI.SPECT (Flash3D) and Hermes Hybrid Recon Oncology (Hyrid Recon 3DOSEM and MAP). Image analysis was performed by calculating the contrast recovery coefficient (CRC),percentage background variability (N%), and contrast-to-noise ratio (CNR), defined as the ratio between CRC and N%. Furthermore, image distortion is characterized by calculating the aspect ratio (AR) of ellipses fitted to the hot spheres. Additionally, the performance of these algorithms to reconstruct clinical images was investigated. Images reconstructed with 3DOSEM algorithms demonstrated superior image quality in terms of contrast and resolution recovery when compared to images reconstructed with filtered-back-projection (FBP), OSEM and 2DOSEM. However, occurrence of correlated noise patterns and image distortions significantly deteriorated the quality of 3DOSEM reconstructed images. The mean AR for the 37, 28, 22, and 17mm spheres was 1.3, 1.3, 1.6, and 1.7 respectively. The mean N% increase in high and low count Flash3D and Hybrid Recon 3DOSEM from 5.9% and 4.0% to 11.1% and 9.0%, respectively. Similarly, the mean CNR decreased in high and low count Flash3D and Hybrid Recon 3DOSEM from 8.7 and 8.8 to 3.6 and 4.2, respectively. Regularization with smoothing priors could suppress these noise patterns at the cost of reduced image contrast. The mean N% was 6.4% and 6.8% for low count QSP and MRP MAP reconstructed images. Alternatively, regularization with an anatomical Bowhser prior resulted in sharp images with high contrast, limited image distortion, and low N% of 8.3% in low count images, although some image artifacts did occur. Analysis of clinical images suggested that the same effects occur in clinical imaging. Image quality of low count SPECT acquisitions reconstructed with modern 3DOSEM algorithms is deteriorated by the occurrence of correlated noise patterns and image distortions. The artifacts observed in the phantom experiments can also occur in clinical imaging. Copyright © 2015. Published by Elsevier GmbH.

Interactive Dynamic Volume Illumination with Refraction and Caustics.

PubMed

Magnus, Jens G; Bruckner, Stefan

2018-01-01

In recent years, significant progress has been made in developing high-quality interactive methods for realistic volume illumination. However, refraction - despite being an important aspect of light propagation in participating media - has so far only received little attention. In this paper, we present a novel approach for refractive volume illumination including caustics capable of interactive frame rates. By interleaving light and viewing ray propagation, our technique avoids memory-intensive storage of illumination information and does not require any precomputation. It is fully dynamic and all parameters such as light position and transfer function can be modified interactively without a performance penalty.

Acute colitis caused by caustic products.

PubMed

da Fonseca, J; Brito, M J; Freitas, J; Leal, C

1998-12-01

We report two cases of acute proctocolitis caused by rectal application of caustic products of domestic use. One 61-yr-old woman applied an ammonia solution enema; the other patient, a 63-yr-old woman, accidentally applied an enema containing lye. Both patients presented with intense anal pain, but the first patient also had abdominal pain with guarding, hematochezia, and leucocytosis. An acute proctocolitis was found at sigmoidoscopy in both patients. Only conservative and symptomatic measures were prescribed in both cases, and a clinical and endoscopic recovery was seen. In spite of persistent fibrosis in the lamina propria, no signs of stenosis were found.

Heat resistant substrates and battery separators made therefrom

NASA Technical Reports Server (NTRS)

Langer, Alois (Inventor); Scala, Luciano C. (Inventor); Ruffing, Charles R. (Inventor)

1976-01-01

A flexible substrate having a caustic resistant support and at least one membrane comprising a solid polymeric matrix containing a network of interconnected pores and interdispersed inorganic filler particles with a ratio of filler: polymer in the polymeric matrix of between about 1:1 to 5:1, is made by coating at least one side of the support with a filler:coating formulation mixture of inorganic filler particles and a caustic resistant, water insoluble polymer dissolved in an organic solvent, and removing the solvent from the mixture to provide a porous network within the polymeric matrix.

Laboratory study of sonic booms and their scaling laws. [ballistic range simulation

NASA Technical Reports Server (NTRS)

Toong, T. Y.

1974-01-01

This program undertook to seek a basic understanding of non-linear effects associated with caustics, through laboratory simulation experiments of sonic booms in a ballistic range and a coordinated theoretical study of scaling laws. Two cases of superbooms or enhanced sonic booms at caustics have been studied. The first case, referred to as acceleration superbooms, is related to the enhanced sonic booms generated during the acceleration maneuvers of supersonic aircrafts. The second case, referred to as refraction superbooms, involves the superbooms that are generated as a result of atmospheric refraction. Important theoretical and experimental results are briefly reported.

Generation of three-dimensional optical cusp beams with ultrathin metasurfaces.

PubMed

Liu, Weiwei; Zhang, Yuchao; Gao, Jie; Yang, Xiaodong

2018-06-22

Cusp beams are one type of complex structured beams with unique multiple self-accelerating channels and needle-like field structures owning great potentials to advance applications such as particle micromanipulation and super-resolution imaging. The traditional method to generate optical catastrophe is based on cumbrous reflective diffraction optical elements, which makes optical system complicated and hinders the nanophotonics integration. Here we design geometric phase based ultrathin plasmonic metasurfaces made of nanoslit antennas to produce three-dimensional (3D) optical cusp beams with variable numbers of self-accelerating channels in a broadband wavelength range. The entire beam propagation profiles of the cusp beams generated from the metasurfaces are mapped theoretically and experimentally. The special self-accelerating behavior and caustics concentration property of the cups beams are also demonstrated. Our results provide great potentials for promoting metasurface-enabled compact photonic devices used in wide applications of light-matter interactions.

Comparison of a new GIS-based technique and a manual method for determining sinkhole density: An example from Illinois' sinkhole plain

USGS Publications Warehouse

Angel, J.C.; Nelson, D.O.; Panno, S.V.

2004-01-01

A new Geographic Information System (GIS) method was developed as an alternative to the hand-counting of sinkholes on topographic maps for density and distribution studies. Sinkhole counts were prepared by hand and compared to those generated from USGS DLG data using ArcView 3.2 and the ArcInfo Workstation component of ArcGIS 8.1 software. The study area for this investigation, chosen for its great density of sinkholes, included the 42 public land survey sections that reside entirely within the Renault Quadrangle in southwestern Illinois. Differences between the sinkhole counts derived from the two methods for the Renault Quadrangle study area were negligible. Although the initial development and refinement of the GIS method required considerably more time than counting sinkholes by hand, the flexibility of the GIS method is expected to provide significant long-term benefits and time savings when mapping larger areas and expanding research efforts. ?? 2004 by The National Speleological Society.

4D light-field sensing system for people counting

NASA Astrophysics Data System (ADS)

Hou, Guangqi; Zhang, Chi; Wang, Yunlong; Sun, Zhenan

2016-03-01

Counting the number of people is still an important task in social security applications, and a few methods based on video surveillance have been proposed in recent years. In this paper, we design a novel optical sensing system to directly acquire the depth map of the scene from one light-field camera. The light-field sensing system can count the number of people crossing the passageway, and record the direction and intensity of rays at a snapshot without any assistant light devices. Depth maps are extracted from the raw light-ray sensing data. Our smart sensing system is equipped with a passive imaging sensor, which is able to naturally discern the depth difference between the head and shoulders for each person. Then a human model is built. Through detecting the human model from light-field images, the number of people passing the scene can be counted rapidly. We verify the feasibility of the sensing system as well as the accuracy by capturing real-world scenes passing single and multiple people under natural illumination.

Asphalt Artisans: Creating a Community Eco-Map on the Playground.

ERIC Educational Resources Information Center

Fieldhouse, Paul; Bunkowsky, Lisa

2002-01-01

Describes an "eco-count" project that led to the creation of a community map and educational game being painted on an elementary school playground. The multidisciplinary project involved students, teachers, parents, and other community members and the resulting map includes sections related to the local "green environment", "built environment",…

A new endoscopic technique for suspension of esophageal prosthesis for refractory caustic esophageal strictures.

PubMed

Ancona, E; Guido, E; Cutrone, C; Bocus, P; Rampado, S; Vecchiato, M; Salvador, R; Donach, M; Battaglia, G

2008-01-01

There is no clear consensus concerning the best endoscopic treatment of benign refractory esophageal strictures due to caustic ingestion. Different procedures are currently used: frequent multiple dilations, retrievable self-expanding stent, nasogastric intubation and surgery. We describe a new technique to fix a suspended esophageal silicone prosthesis to the neck in benign esophageal strictures; this permits us to avoid the frequent risk of migration of the expandable metallic or plastic stents. Under general anesthesia a rigid esophagoscope was placed in the patient's hypopharynx. Using transillumination from the optical device, the patient's neck was pierced with a needle. A n.0 monofilament surgical wire was pushed into the needle, grasped by a standard foreign body forceps through the esophagoscope and pulled out of the mouth (as in percutaneous endoscopic gastrostomy procedure). After tying the proximal end of the silicone prosthesis with the wire, it was placed through the strictures under endoscopic view. This procedure was successfully utilized in four patients suffering from benign refractory esophageal strictures due to caustic ingestion. The prosthesis and its suspension from the neck were well-tolerated until removal (mean duration 4 months). A postoperative transitory myositis was diagnosed in only one patient. One of the most frequent complications of esophageal prostheses in refractory esophageal strictures due to caustic ingestion is distal migration. Different solutions were proposed. For example the suspension of a wire coming from the nose and then fixed behind the ear. This solution is not considered optimal because of patient complaints and moreover the aesthetic aspect is compromised. The procedure we utilized in four patients utilized the setting of a silicone tube hanging from the neck in a way similar to that of endoscopic pharyngostomy. This solution is a valid alternative both for quality of life and for functional results.

Is side-viewing endoscope assisted balloon dilatation better for corrosive gastric outlet obstruction?

PubMed

Katiyar, Prashant; Nijhawan, Sandeep; Saradava, Vimal; Nagaich, Neeraj; Gupta, Gaurav; Mathur, Amit; Nepalia, Subhash

2013-11-01

Endoscopic balloon dilatation (EBD) is an effective therapy for caustic-induced gastric outlet obstruction (GOO). Gaining access to the stricture site is the most important step. It is sometimes difficult to negotiate a balloon through the stricture with a front-viewing endoscope due to deformed anatomy of stomach. To overcome this technical difficulty, a side-viewing endoscope can be used. There is limited data regarding the use of side-viewing endoscopes in EBD. We here report on the short-term efficacy and safety of EBD in caustic-induced GOO. In technically difficult cases, a side-viewing endoscope was used for EBD and its efficacy and safety were assessed. The study included 25 patients with caustic-induced GOO. Patients underwent EBD using a through-the-scope balloon. Initial balloon dilatation was performed with a front-viewing endoscope. A side-viewing endoscope was used where negotiation across the stricture failed with a front-viewing endoscope. Dilatation was started at 8 mm diameter and was performed at 1-week intervals. The end point of dilatation was 15 mm diameter. In 18 patients successful balloon dilatation was possible with a front-viewing endoscope. A side-viewing endoscope was used in six patients as negotiation across the stricture was not possible with a front-viewing endoscope. In all six patients negotiation across the stricture followed by successful dilatation was successful with a side-viewing endoscope. Of the 25 patients included in this study, 24 (96%) achieved procedural success (18 with a front-viewing endoscope and 6 with a side-viewing endoscope) in 3-9 sessions. Our results show that EBD is a safe and effective option for caustic-induced GOO and in difficult cases a side-viewing endoscope can be used to achieve technical success.

Hotspot detection in pancreatic neuroendocrine tumors: density approximation by α-shape maps

NASA Astrophysics Data System (ADS)

Niazi, M. K. K.; Hartman, Douglas J.; Pantanowitz, Liron; Gurcan, Metin N.

2016-03-01

The grading of neuroendocrine tumors of the digestive system is dependent on accurate and reproducible assessment of the proliferation with the tumor, either by counting mitotic figures or counting Ki-67 positive nuclei. At the moment, most pathologists manually identify the hotspots, a practice which is tedious and irreproducible. To better help pathologists, we present an automatic method to detect all potential hotspots in neuroendocrine tumors of the digestive system. The method starts by segmenting Ki-67 positive nuclei by entropy based thresholding, followed by detection of centroids for all Ki-67 positive nuclei. Based on geodesic distance, approximated by the nuclei centroids, we compute two maps: an amoeba map and a weighted amoeba map. These maps are later combined to generate the heat map, the segmentation of which results in the hotspots. The method was trained on three and tested on nine whole slide images of neuroendocrine tumors. When evaluated by two expert pathologists, the method reached an accuracy of 92.6%. The current method does not discriminate between tumor, stromal and inflammatory nuclei. The results show that α-shape maps may represent how hotspots are perceived.

The Distribution of Non-Volatile Elements on Mars: Mars Odyssey GRS Results

NASA Technical Reports Server (NTRS)

Boynton, W.; Janes, D.; Kerry, K.; Kim, K.; Reedy, R.; Evans, L.; Starr, R.; Drake, D.; Taylor, J.; Waenke, H.

2004-01-01

The major scientific objective of the Gamma-Ray Spectrometer (GRS) on the 2001 Mars Odyssey Mission is to determine the distribution of elements in the near-surface of Mars. Mars Odyssey has been in its mapping orbit since February, 2002, and the GRS boom, which removes the instrument from the gamma-ray background of the spacecraft, was erected in June, 2002. In the 580 days since boom erection, we have accumulated 453 days of mapping data. The difference is due mostly to two times when Odyssey went into safe mode and the instrument warmed up forcing us to anneal out radiation damage that manifests itself after warming. Other data losses are due to simple transmitter data gaps and to intense solar particle events. The data from the GRS is statistical in nature. We have a very low count rate and a very low signal-to-noise ratio. With the exception of K, the most easily mapped elements have a signal/noise ratio on the order of 0.1 (0.5 for K) and the counting rates are on the order of 0.3 to 0.7 counts/min (4 cpm for K). In order to map the distribution of an element, we have to divide the total signal from Mars up into many cells that define the map s spatial resolution (unless the statistics are good enough that the intrinsic spatial resolution of the instrument, about 550 km diameter, dominates). The data for several elements have now achieved a statistical precision that permits us to make meaningful maps.

AzTEC half square degree survey of the SHADES fields - I. Maps, catalogues and source counts

NASA Astrophysics Data System (ADS)

Austermann, J. E.; Dunlop, J. S.; Perera, T. A.; Scott, K. S.; Wilson, G. W.; Aretxaga, I.; Hughes, D. H.; Almaini, O.; Chapin, E. L.; Chapman, S. C.; Cirasuolo, M.; Clements, D. L.; Coppin, K. E. K.; Dunne, L.; Dye, S.; Eales, S. A.; Egami, E.; Farrah, D.; Ferrusca, D.; Flynn, S.; Haig, D.; Halpern, M.; Ibar, E.; Ivison, R. J.; van Kampen, E.; Kang, Y.; Kim, S.; Lacey, C.; Lowenthal, J. D.; Mauskopf, P. D.; McLure, R. J.; Mortier, A. M. J.; Negrello, M.; Oliver, S.; Peacock, J. A.; Pope, A.; Rawlings, S.; Rieke, G.; Roseboom, I.; Rowan-Robinson, M.; Scott, D.; Serjeant, S.; Smail, I.; Swinbank, A. M.; Stevens, J. A.; Velazquez, M.; Wagg, J.; Yun, M. S.

2010-01-01

We present the first results from the largest deep extragalactic mm-wavelength survey undertaken to date. These results are derived from maps covering over 0.7deg2, made at λ = 1.1mm, using the AzTEC continuum camera mounted on the James Clerk Maxwell Telescope. The maps were made in the two fields originally targeted at λ = 850μm with the Submillimetre Common-User Bolometer Array (SCUBA) in the SCUBA Half-Degree Extragalactic Survey (SHADES) project, namely the Lockman Hole East (mapped to a depth of 0.9-1.3 mJy rms) and the Subaru/XMM-Newton Deep Field (mapped to a depth of 1.0-1.7 mJy rms). The wealth of existing and forthcoming deep multifrequency data in these two fields will allow the bright mm source population revealed by these new wide-area 1.1mm images to be explored in detail in subsequent papers. Here, we present the maps themselves, a catalogue of 114 high-significance submillimetre galaxy detections, and a thorough statistical analysis leading to the most robust determination to date of the 1.1mm source number counts. These new maps, covering an area nearly three times greater than the SCUBA SHADES maps, currently provide the largest sample of cosmological volumes of the high-redshift Universe in the mm or sub-mm. Through careful comparison, we find that both the Cosmic Evolution Survey (COSMOS) and the Great Observatories Origins Deep Survey (GOODS) North fields, also imaged with AzTEC, contain an excess of mm sources over the new 1.1mm source-count baseline established here. In particular, our new AzTEC/SHADES results indicate that very luminous high-redshift dust enshrouded starbursts (S1.1mm > 3mJy) are 25-50 per cent less common than would have been inferred from these smaller surveys, thus highlighting the potential roles of cosmic variance and clustering in such measurements. We compare number count predictions from recent models of the evolving mm/sub-mm source population to these sub-mm bright galaxy surveys, which provide important constraints for the ongoing refinement of semi-analytic and hydrodynamical models of galaxy formation, and find that all available models overpredict the number of bright submillimetre galaxies found in this survey.

A study of Propfan propagation noise

NASA Technical Reports Server (NTRS)

Sim, Ben W.-C.; George, A. R.

1993-01-01

A study of Propfan far-field noise is carried out based on geometrical acoustics theory. The analysis traces the acoustic rays and ray tube areas carrying the acoustic disturbances to the far-field. Sound attenuation due to nonlinear steepening, atmospheric absorption and turbulence scattering are also investigated. A comparison of our prediction methodology with experimental acoustics measurement shows good agreement. Geometrical decay and atmospheric absorption are identified as the primary noise attenuating mechanisms. Nonlinear effects are negligible. It is determined that the acoustic footprints of advanced propellers are dominated by caustics. Details of the formation of these caustics may provide a basis for future noise minimization efforts.

Radiolytic Treatment of the Next-Generation Caustic-Side Solvent Extraction (NGS) Solvent and its Effect on the NGS Process

DOE PAGES

Roach, Benjamin D.; Williams, Neil J.; Duncan, Nathan C.; ...

2014-12-01

We show in this work that the solvent used in the Next Generation Caustic-Side Solvent Extraction (NGS) process can withstand a radiation dose well in excess of the dose it would receive in multiple years of treating legacy salt waste at the US Department of Energy Savannah River Site. The solvent was subjected to a maximum of 50 kGy of gamma radiation while in dynamic contact with each of the aqueous phases of the current NGS process, namely SRS-15 (a highly caustic waste simulant), sodium hydroxide scrub solution (0.025 M), and boric acid strip solution (0.01 M). Bench-top testing ofmore » irradiated solvent confirmed that irradiation has inconsequential impact on the extraction, scrubbing, and stripping performance of the solvent up to 13 times the estimated 0.73 kGy/y annual absorbed dose. Lastly, stripping performance is the most sensitive step to radiation, deteriorating more due to buildup of p-sec-butylphenol (SBP) and possibly other proton-ionizable products than to degradation of the guanidine suppressor, as shown by chemical analyses.« less

Extraction of caustic potash from spent tea for biodiesel Production

NASA Astrophysics Data System (ADS)

Sulaiman, Sarina; Faiz Che Fisol, Ahmad; Sharikh, Atikah Mohamed; Noraini Jimat, Dzun; Jamal, Parveen

2018-01-01

Biodiesel is an alternative to non-renewable fossil fuels due to its low gas emission and economical value. This study aims to extract caustic potash (KOH) from spent tea and to optimize the transesterfication process based on parameters such as amount of catalyst, reaction temperature and methanol to oil ratio. The spent tea was first dried at 60°C prior to calcination at 600°C for two hours. Caustic Potash were extracted from the calcined spent tea. The transesterification process was done based on Design of Experiments (DOE) to study the effects of amount of catalyst ranging from 0.5 wt % to 2.5 wt %, reaction temperature from 55°C to 65°C and methanol to oil ratio from 6:1 to 12:1 at a constant agitation rate of 300 rpm for three hours. The calcined spent tea produced was recorded the highest at 54.3 wt % and the extracted catalyst was 2.4 wt %. The optimized biodiesel yield recorded was 56.95% at the optimal conditions of 2.5 wt % amount of catalyst, 65°C reaction temperature and 9:1 methanol to oil ratio.

Co-treatment of spent cathode carbon in caustic and acid leaching process under ultrasonic assisted for preparation of SiC.

PubMed

Yuan, Jie; Xiao, Jin; Li, Fachuang; Wang, Bingjie; Yao, Zhen; Yu, Bailie; Zhang, Liuyun

2018-03-01

Spent cathode carbon (SCC) from aluminum electrolysis has been treated in ultrasonic-assisted caustic leaching and acid leaching process, and purified SCC used as carbon source to synthesize silicon carbide (SiC) was investigated. Chemical and mineralogical properties have been characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy (SEM), and thermogravimetry and differential scanning calorimetry (TGA-DSC). Various experimental factors temperature, time, liquid-solid ratio, ultrasonic power, and initial concentration of alkali or acid affecting on SCC leaching result were studied. After co-treatment with ultrasonic-assisted caustic leaching and acid leaching, carbon content of leaching residue was 97.53%. SiC power was synthesized by carbothermal reduction at 1600 °C, as a result of yield of 76.43%, and specific surface area of 4378 cm 2 /g. This is the first report of using purified SCC and gangue to prepare SiC. The two industrial wastes have been used newly as secondary sources. Furthermore, ultrasonic showed significant effect in SCC leaching process. Copyright © 2017 Elsevier B.V. All rights reserved.

Results Of Routine Strip Effluent Hold Tank, Decontaminated Salt Solution Hold Tank, And Caustic Wash Tank Samples From Modular Caustic-Side Solvent Extraction Unit During Macrobatch 4 Operations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peters, T. B.; Fink, S. D.

Strip Effluent Hold Tank (SEHT), Decontaminated Salt Solution Hold Tank (DSSHT), and Caustic Wash Tank (CWT) samples from several of the ?microbatches? of Integrated Salt Disposition Project (ISDP) Salt Batch (?Macrobatch?) 4 have been analyzed for {sup 238}Pu, {sup 90}Sr, {sup 137}Cs, and by inductively-coupled plasma emission spectroscopy (ICPES). Furthermore, samples from the CWT have been analyzed by a variety of methods to investigate a decline in the decontamination factor (DF) of the cesium observed at MCU. The results indicate good decontamination performance within process design expectations. While the data set is sparse, the results of this set and themore » previous set of results for Macrobatch 3 samples indicate generally consistent operations. There is no indication of a disruption in plutonium and strontium removal. The average cesium DF and concentration factor (CF) for samples obtained from Macrobatch 4 are slightly lower than for Macrobatch 3, but still well within operating parameters. The DSSHT samples show continued presence of titanium, likely from leaching of the monosodium titanate in Actinide Removal Process (ARP).« less

Radiolytic Treatment of the Next-Generation Caustic-Side Solvent Extraction (NGS) Solvent and its Effect on the NGS Process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Roach, Benjamin D.; Williams, Neil J.; Duncan, Nathan C.

We show in this work that the solvent used in the Next Generation Caustic-Side Solvent Extraction (NGS) process can withstand a radiation dose well in excess of the dose it would receive in multiple years of treating legacy salt waste at the US Department of Energy Savannah River Site. The solvent was subjected to a maximum of 50 kGy of gamma radiation while in dynamic contact with each of the aqueous phases of the current NGS process, namely SRS-15 (a highly caustic waste simulant), sodium hydroxide scrub solution (0.025 M), and boric acid strip solution (0.01 M). Bench-top testing ofmore » irradiated solvent confirmed that irradiation has inconsequential impact on the extraction, scrubbing, and stripping performance of the solvent up to 13 times the estimated 0.73 kGy/y annual absorbed dose. Lastly, stripping performance is the most sensitive step to radiation, deteriorating more due to buildup of p-sec-butylphenol (SBP) and possibly other proton-ionizable products than to degradation of the guanidine suppressor, as shown by chemical analyses.« less

Biotreatment of refinery spent-sulfidic caustic using an enrichment culture immobilized in a novel support matrix.

PubMed

Conner, J A; Beitle, R R; Duncan, K; Kolhatkar, R; Sublette, K L

2000-01-01

Sodium hydroxide solutions are used in petroleum refining to remove hydrogen sulfide (H2S) and mercaptans from various hydrocarbon streams. The resulting sulfide-laden waste stream is called spent-sulfidic caustic. An aerobic enrichment culture was previously developed using a gas mixture of H2S and methyl-mercaptan (MeSH) as the sole energy source. This culture has now been immobilized in a novel support matrix, DuPont BIO-SEP beads, and is used to bio-treat a refinery spent-sulfidic caustic containing both inorganic sulfide and mercaptans in a continuous flow, fluidized-bed column bioreactor. Complete oxidation of both inorganic and organic sulfur to sulfate was observed with no breakthrough of H2S and < 2 ppmv of MeSH produced in the bioreactor outlet gas. Excessive buildup of sulfate (> 12 g/L) in the bioreactor medium resulted in an upset condition evidenced by excessive MeSH breakthrough. Therefore, bioreactor performance was limited by the steady-state sulfate concentration. Further improvement in volumetric productivity of a bioreactor system based on this enrichment culture will be dependent on maintenance of sulfate concentrations below inhibitory levels.

Interaction of aerodynamic noise with laminar boundary layers in supersonic wind tunnels

NASA Technical Reports Server (NTRS)

Schopper, M. R.

1984-01-01

The interaction between incoming aerodynamic noise and the supersonic laminar boundary layer is studied. The noise field is modeled as a Mach wave radiation field consisting of discrete waves emanating from coherent turbulent entities moving downstream within the supersonic turbulent boundary layer. The individual disturbances are likened to miniature sonic booms and the laminar boundary layer is staffed by the waves as the sources move downstream. The mean, autocorrelation, and power spectral density of the field are expressed in terms of the wave shapes and their average arrival rates. Some consideration is given to the possible appreciable thickness of the weak shock fronts. The emphasis in the interaction analysis is on the behavior of the shocklets in the noise field. The shocklets are shown to be focused by the laminar boundary layer in its outer region. Borrowing wave propagation terminology, this region is termed the caustic region. Using scaling laws from sonic boom work, focus factors at the caustic are estimated to vary from 2 to 6 for incoming shocklet strengths of 1 to .01 percent of the free stream pressure level. The situation regarding experimental evidence of the caustic region is reviewed.

F-Area Acid/Caustic Basin groundwater monitoring report. First quarter 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1995-06-01

During first quarter 1995, samples from the FAC monitoring wells at the F-Area Acid/Caustic Basin were collected and analyzed for herbicides/pesticides, indicator parameters, metals, nitrate, radionuclide indicators, volatile organic compounds, and other constituents. Piezometer FAC 5P and monitoring well FAC 6 were dry and could not be sampled. New monitoring wells FAC 9C, 10C, 11C, and 12C were completed in the Barnwell/McBean aquifer and were sampled for the first time during third quarter 1994 (first quarter 1995 is the third of four quarters of data required to support the closure of the basin). Analytical results that exceeded final Primary Drinkingmore » Water Standards (PDWS), other Savannah River Site (SRS) Flag 2 criteria, or the SRS turbidity standard of 50 NTU during the quarter were as follows: gross alpha exceeded the final PDWS and aluminum, iron, manganese, and total alpha-emitting radium exceeded the SRS Flag 2 criteria in one or more of the FAC wells. Turbidity exceeded the SRS standard (50 NTU) in wells FAC 3 and 11C. Groundwater flow direction and rate in the water table beneath the F-Area Acid/Caustic Basin were similar to past quarters.« less

The Effect of Modified Atmosphere Packaging and Addition of Rosemary Extract, Sodium Acetate and Calcium Lactate Mixture on the Quality of Pre-cooked Hamburger Patties during Refrigerated Storage

PubMed Central

Muhlisin; Kang, Sun Moon; Choi, Won Hee; Lee, Keun Taik; Cheong, Sung Hee; Lee, Sung Ki

2013-01-01

The effect of modified atmosphere packaging (MAP; 30% CO2+70% N2 or 100% N2) and an additive mixture (500 ppm rosemary extract, 3,000 ppm sodium acetate and 1,500 ppm calcium lactate) on the quality of pre-cooked hamburger patties during storage at 5°C for 14 d was evaluated. The addition of the additive mixture reduced aerobic and anaerobic bacteria counts in both 30% CO2-MAP (30% CO2+70% N2) and 100% N2-MAP (p<0.05). The 30% CO2-MAP was more effective to suppress the microbial growth than 100% N2-MAP, moreover the 30% CO2-MAP combined with additive mixture resulted in the lowest bacterial counts. The hamburger patties with additive mixture showed lower CIE L* and CIE a*, and higher CIE b* than those with no additive mixture. The 30% CO2-MAP tended to decrease the TBARS during storage regardless of the addition of additives. The use of 30% CO2-MAP in combination with additives mixture was effective for maintaining the quality and extending the shelf-life of pre-cooked hamburger patties. PMID:25049716

Trace Element Mapping of a Biological Specimen by a Full-Field X-ray Fluorescence Imaging Microscope with a Wolter Mirror

NASA Astrophysics Data System (ADS)

Hoshino, Masato; Yamada, Norimitsu; Ishino, Toyoaki; Namiki, Takashi; Watanabe, Norio; Aoki, Sadao

2007-01-01

A full-field X-ray fluorescence imaging microscope with a Wolter mirror was applied to the element mapping of alfalfa seeds. The X-ray fluorescence microscope was built at the Photon Factory BL3C2 (KEK). X-ray fluorescence images of several growing stages of the alfalfa seeds were obtained. X-ray fluorescence energy spectra were measured with either a solid state detector or a CCD photon counting method. The element distributions of iron and zinc which were included in the seeds were obtained using a photon counting method.

Use of miniroutes and Breeding Bird Survey data to estimate abundance

USGS Publications Warehouse

Robbins, C.S.; Dowell, B.A.

1986-01-01

1. Information on relative abundance is easily obtained and adds greatly to the value of an atlas project. 2. The Breeding Bird Survey (BBS) provides annual counts (birds per 50 roadside stops) that can be used to: (1) map relative abundance by physiographic region within a state or province, (2) map relative abundance on a more local scale by using results from individual routes, or (3) compute estimates of total state populations of a species. Where BBS coverage is too scanty to permit mapping, extra temporary routes may be established to provide additional information for the atlas. Or, if continuing coverage is anticipated, additional permanent random routes can be assigned by the U. S. Fish and Wildlife Service. 3. Miniroutes of 15 or more stops can be established in individual atlas blocks to serve the dual purposes of providing efficient uniform coverage and providing information on relative abundance. Miniroutes can also be extracted from BBS routes to supplement special atlas coverage, or vice versa; but the data from the BBS will not be confined to individual atlas blocks. 4. Advantages of 15- or 20-stop Miniroutes over 25-stop Miniroutes are several: the ability to do two per morning and the lower variability among M1niroute results. Also, many 5-km atlas blocks do not have enough secondary roads to accommodate 25 stops at one-half mile intervals. Disadvantages of 15-stop Miniroutes starting at sunrise are the smaller numbers of birds recorded, missing of the very productive dawn chorus period (Robbins 1981), and missing crepuscular species (rails, woodcock, owls, and goatsuckers). 5. Advantages of recording counts of individuals rather than checking only species presence at Miniroute stops are that: (1) relative abundance can be mapped rather than frequency only (a measure of frequency is already available in the number of blocks recording each species); (2) population change can be measured over a period of years when the next atlas is made; and (3) comparative abundance data are available for habitat correlations and other statistical applications (Luis et ale 1983). Disadvantages of recording counts are that: (1) many observers do not feel they can make accurate counts of individuals; and (2) a few species may be missed while observers are counting (an hypothesis that will be field-tested this summer). While counts of individuals may be more subject to observer differences than are frequency counts, both the numbers of birds and their frequencies are available when birds are counted. 6. Roadside counts produce slightly larger samples and more species than off-road counts. The main advantage of off-road coverage is to sample habitats that cannot be sampled from roadsides. 7. Miniroutes can be recommended to individual atlasers as an efficient means of detecting species and upgrading them from Possible to Probable, even when there is no statewide Miniroute program.

The usefulness of GPS bicycle tracking data for evaluating the impact of infrastructure change on cycling behaviour.

PubMed

Heesch, Kristiann C; Langdon, Michael

2016-02-01

Issue addressed A key strategy to increase active travel is the construction of bicycle infrastructure. Tools to evaluate this strategy are limited. This study assessed the usefulness of a smartphone GPS tracking system for evaluating the impact of this strategy on cycling behaviour. Methods Cycling usage data were collected from Queenslanders who used a GPS tracking app on their smartphone from 2013-2014. 'Heat' and volume maps of the data were reviewed, and GPS bicycle counts were compared with surveillance data and bicycle counts from automatic traffic-monitoring devices. Results Heat maps broadly indicated that changes in cycling occurred near infrastructure improvements. Volume maps provided changes in counts of cyclists due to these improvements although errors were noted in geographic information system (GIS) geo-coding of some GPS data. Large variations were evident in the number of cyclists using the app in different locations. These variations limited the usefulness of GPS data for assessing differences in cycling across locations. Conclusion Smartphone GPS data are useful in evaluating the impact of improved bicycle infrastructure in one location. Using GPS data to evaluate differential changes in cycling across multiple locations is problematic when there is insufficient traffic-monitoring devices available to triangulate GPS data with bicycle traffic count data. So what? The use of smartphone GPS data with other data sources is recommended for assessing how infrastructure improvements influence cycling behaviour.

Turbulence Scales, Rise Times, Caustics, and the Simulation of Sonic Boom Propagation

NASA Technical Reports Server (NTRS)

Pierce, Allan D.

1996-01-01

The general topic of atmospheric turbulence effects on sonic boom propagation is addressed with especial emphasis on taking proper and efficient account of the contributions of the portion oi the turbulence that is associated with extremely high wavenumber components. The recent work reported by Bart Lipkens in his doctoral thesis is reexamined to determine whether the good agreement between his measured rise times with the 1971 theory of the author is fortuitous. It is argued that Lipken's estimate of the distance to the first caustic was a gross overestimate because of the use of a sound speed correlation function shaped like a gaussian curve. In particular, it is argued that the expected distance to the first caustic varies with the kinematic viscosity nu and the energy epsilon dissipated per unit mass per unit time, and the sound speed c as : d(sub first caustic) = nu(exp 7/12) c(exp 2/3)/ epsilon(exp 5/12)(nu x epsilon/c(exp 4))(exp a), where the exponent a is greater than -7/12 and can be argued to be either O or 1/24. In any event, the surprising aspect of the relationship is that it actually goes to zero as the viscosity goes to zero with s held constant. It is argued that the apparent overabundance of caustics can be grossly reduced by a general computational and analytical perspective that partitions the turbulence into two parts, divided by a wavenumber k(sub c). Wavenumbers higher than kc correspond to small-scale turbulence, and the associated turbulence can be taken into account by a renormalization of the ambient sound speed so that the result has a small frequency dependence that results from a spatial averaging over of the smaller-scale turbulent fluctuations. Selection of k(sub c). can be made so large that only a very small number of caustics are encountered if one adopts the premise that the frequency dispersion of pulses is caused by that part of the turbulence spectrum which lies in the inertial range originally predicted by Kolmogoroff. The acoustic propagating wave's dispersion relation has the acoustic wavenumber being of the form k = (omega/c) + F(omega), where c is a spatially averaged sound speed and where, for mechanical turbulence, the extra term F(omega) must depend on only the angular frequency omega, the sound speed c, and the turbulent energy dissipation epsilon per unit fluid mass and per unit time. If the turbulence is weak, then the quantity F(omega) has to be of second order in the portions of the turbulent fluid velocity in the inertial range, so, following Kolmogoroff's reasoning, it must vary with epsilon as epsilon(exp 2/3). Simple dimensional analysis then reveals that F(omega) is K epsilon(exp 2/3) c(exp -7/3) omega(exp l/3), K being a universal dimensionless complex constant.

Relationship of students' conceptual representations and problem-solving abilities in acid-base chemistry

NASA Astrophysics Data System (ADS)

Powers, Angela R.

2000-10-01

This study explored the relationship between secondary chemistry students' conceptual representations of acid-base chemistry, as shown in student-constructed concept maps, and their ability to solve acid-base problems, represented by their score on an 18-item paper and pencil test, the Acid-Base Concept Assessment (ABCA). The ABCA, consisting of both multiple-choice and short-answer items, was originally designed using a question-type by subtopic matrix, validated by a panel of experts, and refined through pilot studies and factor analysis to create the final instrument. The concept map task included a short introduction to concept mapping, a prototype concept map, a practice concept-mapping activity, and the instructions for the acid-base concept map task. The instruments were administered to chemistry students at two high schools; 108 subjects completed both instruments for this study. Factor analysis of ABCA results indicated that the test was unifactorial for these students, despite the intention to create an instrument with multiple "question-type" scales. Concept maps were scored both holistically and by counting valid concepts. The two approaches were highly correlated (r = 0.75). The correlation between ABCA score and concept-map score was 0.29 for holistically-scored concept maps and 0.33 for counted-concept maps. Although both correlations were significant, they accounted for only 8.8 and 10.2% of variance in ABCA scores, respectively. However, when the reliability of the instruments used is considered, more than 20% of the variance in ABCA scores may be explained by concept map scores. MANOVAs for ABCA and concept map scores by instructor, student gender, and year in school showed significant differences for both holistic and counted concept-map scores. Discriminant analysis revealed that the source of these differences was the instruction variable. Significant differences between classes receiving different instruction were found in the frequency of concepts listed by students for 9 of 10 concepts evaluated. Mean ABCA scores did not differ significantly between the two instruction groups. The results of this study failed to provide evidence of conceptual distinctions among different "types" of problem-solving items. The results suggested that several factors influence success in chemistry problem solving, including concept knowledge and organization. Further research into the nature of chemistry problems and problem solving is recommended.

Effects of dark storage and retail display on beef chuck and round muscles enhanced with ammonium hydroxide, salt, and carbon monoxide.

PubMed

Hamling, A E; Jenschke, B E; Calkins, C R

2008-04-01

The objective of this study was to determine the retail shelf stability of beef chuck and round muscles enhanced with ammonium hydroxide, salt, and carbon monoxide. A split plot design was used for each of 3 muscles [triceps brachii (TB), biceps femoris (BF), and rectus femoris (RF)] with 2 treatments (0 and 20% pump), 3 dark storage periods (1, 2, and 3 wk), and 3 replications in the whole plot and retail display period as the split plot. There were a total of 12 subprimals per treatment per dark storage period (n = 72 each). Individual steaks were cut to a thickness of 2.54 cm and packaged in a modified-atmosphere package (MAP). The TB was packaged in a high-oxygen MAP (80% oxygen, 20% carbon dioxide). The BF and RF were packaged in a low-oxygen MAP (100% carbon dioxide). At the completion of each dark storage period, steaks were subjected to 7 d of simulated retail display. Steaks were used for objective and subjective color measurements, total plate counts, and determination of retail purge and oxidation. For all muscles, total plate counts were always numerically greater in injected steaks. Triceps brachii steaks held in dark storage for 3 wk and displayed at retail for 4 or more days all exceeded 10(7) log of cfu/cm(2) for aerobic plate count. Biceps femoris and RF steaks packaged in a low-oxygen MAP had much lower bacterial counts, with levels below 4.2 log of cfu/cm(2), even after 7 d of retail display. Oxidation values for the TB were extremely high (ranging from 12.3 to 26.6), whereas the BF and RF had values that were much lower (< or =1.0 mg of malonaldehyde/kg of muscle), likely due to the oxidation occurring in a high-oxygen MAP for the TB. Enhanced TB steaks proved to have greater color stability (less discoloration) than nonenhanced TB steaks. In addition, the BF and RF (low-oxygen MAP) steaks had better color stability (more stable redness values) than TB (high-oxygen MAP) steaks, although TB steaks initially exhibited a brighter red color. Retail display life was enhanced by packaging in 100% carbon dioxide, and enhanced steaks exhibited greater color stability in retail display than control steaks.

Cancer diagnosis using a conventional x-ray fluorescence camera with a cadmium-telluride detector

NASA Astrophysics Data System (ADS)

Sato, Eiichi; Enomoto, Toshiyuki; Hagiwara, Osahiko; Abudurexiti, Abulajiang; Sato, Koetsu; Sato, Shigehiro; Ogawa, Akira; Onagawa, Jun

2011-10-01

X-ray fluorescence (XRF) analysis is useful for mapping various atoms in objects. Bremsstrahlung X-rays are selected using a 3.0 mm-thick aluminum filter, and these rays are absorbed by indium, cerium and gadolinium atoms in objects. Then XRF is produced from the objects, and photons are detected by a cadmium-telluride detector. The Kα photons are discriminated using a multichannel analyzer, and the number of photons is counted by a counter card. The objects are moved and scanned by an x-y stage in conjunction with a two-stage controller, and X-ray images obtained by atomic mapping are shown on a personal computer monitor. The scan steps of the x and y axes were both 2.5 mm, and the photon-counting time per mapping point was 0.5 s. We carried out atomic mapping using the X-ray camera, and Kα photons from cerium and gadolinium atoms were produced from cancerous regions in nude mice.

Conventional X-ray fluorescence camera with a cadmium-telluride detector and its application to cancer diagnosis

NASA Astrophysics Data System (ADS)

Enomoto, Toshiyuki; Sato, Eiichi; Abderyim, Purkhet; Abudurexiti, Abulajiang; Hagiwara, Osahiko; Matsukiyo, Hiroshi; Osawa, Akihiro; Watanabe, Manabu; Nagao, Jiro; Sato, Shigehiro; Ogawa, Akira; Onagawa, Jun

2011-04-01

X-ray fluorescence (XRF) analysis is useful for mapping various molecules in objects. Bremsstrahlung X-rays are selected using a 3.0-mm-thick aluminum filter, and these rays are absorbed by iodine, cerium, and gadolinium molecules in objects. Next, XRF is produced from the objects, and photons are detected by a cadmium-telluride detector. The Kα photons are discriminated using a multichannel analyzer, and the number of photons is counted by a counter card. The objects are moved and scanned by an x- y stage in conjunction with a two-stage controller, and X-ray images obtained by molecular mapping are shown on a personal computer monitor. The scan steps of x and y axes were both 2.5 mm, and the photon-counting time per mapping point was 0.5 s. We carried out molecular mapping using the X-ray camera, and Kα photons from cerium and gadolinium molecules were produced from cancerous regions in nude mice.

A scanning defect mapping system for semiconductor characterization

NASA Technical Reports Server (NTRS)

Sopori, Bushnan L.

1994-01-01

We have developed an optical scanning system that generates maps of the spatial distributions of defects in single and polycrystalline silicon wafers. This instrument, called Scanning Defect Mapping System, utilizes differences in the scattering characteristics of dislocation etch pits and grain boundaries from a defect-etched sample to identify and count them. This system simultaneously operates in the dislocation mode and the grain boundary (GB) mode. In the 'dislocation mode,' the optical scattering from the etch pits is used to statistically count dislocations, while ignoring the GB's. Likewise, in the 'grain boundary mode' the system only recognizes the local scattering from the GB's to generate grain boundary distributions. The information generated by this instrument is valuable for material quality control, identifying mechanisms of defect generation and the nature of thermal stresses during the crystal growth, and the solar cell process design.

Simulation of Mirror Electron Microscopy Caustic Images in Three-Dimensions

NASA Astrophysics Data System (ADS)

Kennedy, S. M.; Zheng, C. X.; Jesson, D. E.

A full, three-dimensional (3D) ray tracing approach is developed to simulate the caustics visible in mirror electron microscopy (MEM). The method reproduces MEM image contrast resulting from 3D surface relief. To illustrate the potential of the simulation methods, we study the evolution of crater contrast associated with a movie of GaAs structures generated by the droplet epitaxy technique. Specifically, we simulate the image contrast resulting from both a precursor stage and the final crater morphology which is consistent with an inverted pyramid consisting of (111) facet walls. The method therefore facilities the study of how self-assembled quantum structures evolve with time and, in particular, the development of anisotropic features including faceting.

Why is number word learning hard? Evidence from bilingual learners.

PubMed

Wagner, Katie; Kimura, Katherine; Cheung, Pierina; Barner, David

2015-12-01

Young children typically take between 18 months and 2 years to learn the meanings of number words. In the present study, we investigated this developmental trajectory in bilingual preschoolers to examine the relative contributions of two factors in number word learning: (1) the construction of numerical concepts, and (2) the mapping of language specific words onto these concepts. We found that children learn the meanings of small number words (i.e., one, two, and three) independently in each language, indicating that observed delays in learning these words are attributable to difficulties in mapping words to concepts. In contrast, children generally learned to accurately count larger sets (i.e., five or greater) simultaneously in their two languages, suggesting that the difficulty in learning to count is not tied to a specific language. We also replicated previous studies that found that children learn the counting procedure before they learn its logic - i.e., that for any natural number, n, the successor of n in the count list denotes the cardinality n+1. Consistent with past studies, we found that children's knowledge of successors is first acquired incrementally. In bilinguals, we found that this knowledge exhibits item-specific transfer between languages, suggesting that the logic of the positive integers may not be stored in a language-specific format. We conclude that delays in learning the meanings of small number words are mainly due to language-specific processes of mapping words to concepts, whereas the logic and procedures of counting appear to be learned in a format that is independent of a particular language and thus transfers rapidly from one language to the other in development. Copyright © 2015. Published by Elsevier Inc.

Mapping QTL influencing gastrointestinal nematode burden in Dutch Holstein-Friesian dairy cattle

PubMed Central

Coppieters, Wouter; Mes, Ted HM; Druet, Tom; Farnir, Frédéric; Tamma, Nico; Schrooten, Chris; Cornelissen, Albert WCA; Georges, Michel; Ploeger, Harm W

2009-01-01

Background Parasitic gastroenteritis caused by nematodes is only second to mastitis in terms of health costs to dairy farmers in developed countries. Sustainable control strategies complementing anthelmintics are desired, including selective breeding for enhanced resistance. Results and Conclusion To quantify and characterize the genetic contribution to variation in resistance to gastro-intestinal parasites, we measured the heritability of faecal egg and larval counts in the Dutch Holstein-Friesian dairy cattle population. The heritability of faecal egg counts ranged from 7 to 21% and was generally higher than for larval counts. We performed a whole genome scan in 12 paternal half-daughter groups for a total of 768 cows, corresponding to the ~10% most and least infected daughters within each family (selective genotyping). Two genome-wide significant QTL were identified in an across-family analysis, respectively on chromosomes 9 and 19, coinciding with previous findings in orthologous chromosomal regions in sheep. We identified six more suggestive QTL by within-family analysis. An additional 73 informative SNPs were genotyped on chromosome 19 and the ensuing high density map used in a variance component approach to simultaneously exploit linkage and linkage disequilibrium in an initial inconclusive attempt to refine the QTL map position. PMID:19254385

Decomposition of banten ilmenite by caustic fusion process for TiO2 photocatalytic applications

NASA Astrophysics Data System (ADS)

Aristanti, Y.; Supriyatna, Y. I.; Masduki, N. P.; Soepriyanto, S.

2018-01-01

Decomposition of Banten ilmenite by caustic fusion process for TiO2 photocatalytic applications has been done. Caustic fusion process using NaOH to obtain sodium titanate compound which is soluble in sulfuric acid (H2SO4) to produces TiOSO4 as a precursor. Synthesis of TiO2 from TiOSO4 precursors by variations of pH hydrolysis are 1.0 (TiO2 A), 1.5 (TiO2 B) and 2.0 (TiO2 C). XRD pattern identified TiO2 structures crystals are anatase phase and traces α-Fe2O3 as an impurity. Presence of Fe2O3 as an impurities give positive effect on TiO2 photocatalytic activity that is to narrower the band gap energy thus facilitates of electrons excitation from valence band to conduction band and enlarge the specific surface area thus reaction between Rhodamin B solution and TiO2 surface can be faster. TiO2 A, TiO2 B and TiO2 C was compared to TiO2 M (commercial TiO2) in Rhodamin B solution for the photocatalytic activity where the maximum TiO2 degradation efficiency was obtained at TiO2 C 80.0 % while TiO2 M 59.8 %.

[Endoscopic contribution in the dilatation of caustic esophagus stenosis].

PubMed

Seydou, Togo; Abdoulaye, Ouattara Moussa; Xing, Li; Zi, Sanogo Zimogo; Sekou, Koumaré; Wen, Yang Shang; Ibrahim, Sankare; Sekou, Toure Cheik Ahmed; Boubacar, Maiga Ibrahim; Saye, Jacque; Jerome, Dakouo Dodino; Dantoumé, Toure Ousmane; Sadio, Yena

2016-01-01

The aim of this work was to present the contribution of the endoscopy in the management of esophageal dilatation for caustic esophageal stenosis (CES). This was a descriptive and prospective study in the thoracic surgery department at the Hospital of Mali. A total of 46 cases of CES is recorded and divided into 4 groups according to the topography of the esophageal lesions. For the different methods of dilatation the number of performed endoscopic support was determined to understand the contribution of endoscopic means in the success of dilatation for CES. The outcome, complications and mortality in the two methods were compared. Fibroscopy was used in 41.30% of patients with Savary Guillard dilators and in 47.82% of patients with Lerut dilators. Video laryngoscopy was used in 58.69% of patients who underwent dilatation with Lerut dilators. The passage of the guide wire was performed in 39.13% under video laryngoscopy and 58.68% under fibroscopy. In comparison of the two methods, there is a significant difference in the occurrence of complications (p=0.04075), general anesthesia (p=0.02287), accessibility (p=0.04805) and mortality (p=0.00402). The CES is a serious disease and under evaluated in Mali. The endoscopies contribute significantly to the success of esophageal dilatation for caustic stenosis in the different methods we used.

Galaxies as High-resolution Telescopes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barnacka, Anna, E-mail: abarnacka@cfa.harvard.edu

Recent observations show a population of active galaxies with milliarcsecond offsets between optical and radio emission. Such offsets can be an indication of extreme phenomena associated with supermassive black holes including relativistic jets, binary supermassive black holes, or even recoiling supermassive black holes. However, the multi-wavelength structure of active galaxies at a few milliarcseconds cannot be resolved with direct observations. We propose using strong gravitational lensing to elucidate the multi-wavelength structure of sources. When sources are located close to the caustic of a lensing galaxy, even a small offset in the position of the sources results in a drastic differencemore » in the position and magnification of mirage images. We show that the angular offset in the position of the sources can be amplified more than 50 times in the observed position of mirage images. We find that at least 8% of the observed gravitationally lensed quasars will be in the caustic configuration. The synergy between SKA and Euclid will provide an ideal set of observations for thousands of gravitationally lensed sources in the caustic configuration, which will allow us to resolve the multi-wavelength structure for a large ensemble of sources and to study the physical origin of radio emissions, their connection to supermassive black holes, and their cosmic evolution.« less

CHARACTERIZATION AND EVALUATION OF CAUSTIC WASH TANK AND SOLVENT HOLD TANK SAMPLES FROM MCU FROM AUGUST TO SEPTEMBER 2011

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fondeur, F.; Fink, S.

2012-08-01

During processing of Salt Batches 3 and 4 in the Modular Caustic-Side Solvent Extraction Unit (MCU), the decontamination efficiency for cesium declined from historical values and from expectations based on laboratory testing. This report documents efforts to analyze samples of solvent and process solutions from MCU in an attempt to understand the cause of the reduced performance and to recommend mitigations. CWT Solutions from MCU from the time period of variable decontamination factor (DF) performance which covers from April 2011 to September 2011 (during processing of Salt Batch 4) were examined for impurities using chromatography and spectroscopy. The results indicatemore » that impurities were found to be of two types: aromatic containing impurities most likely from Modifier degradation and aliphatic type impurities most likely from Isopar{reg_sign} L and tri-n-octylamine (TOA) degradation. Caustic washing the Solvent Hold Tank (SHT) solution with 1M NaOH improved its extraction ability as determined from {sup 22}Na uptake tests. Evidence from this work showed that pH variance in the aqueous solutions within the range of 1M nitric acid to 1.91M NaOH that contacted the solvent samples does not influence the analytical determination of the TOA concentration by GC-MS.« less

Detailed Analysis of the Intra-Ejecta Dark Plains of Caloris Basin, Mercury

NASA Astrophysics Data System (ADS)

Buczkowski, D.; Seelos, K. D.

2010-12-01

The Caloris basin on Mercury is floored by light-toned plains and surrounded by an annulus of dark-toned material interpreted to be ejecta blocks and smooth, dark, ridged plains. Strangely, preliminary crater-counts indicate that these intra-ejecta dark plains are younger than the light-toned plains within the Caloris basin. This would imply a second, younger plains emplacement event, possibly involving lower albedo material volcanics, which resurfaced the original ejecta deposit. On the other hand, the dark plains may be pre-Caloris light plains covered by a thin layer of dark ejecta. Another alternative to the hypothesis of young, dark volcanism is the possibility that previous crater-counts have not thoroughly distinguished between superposed craters (fresh) and partly-buried craters (old) and therefore have not accurately determined the ages of the Caloris units. We here outline the tasks associated with a new mapping project of the Caloris basin, intended to improve our knowledge of the geology and geologic history of the basin, and thus facilitate an understanding of the thermal evolution of this region of Mercury. We will 1) classify craters based on geomorphology and infilling, 2) create a high-resolution map of the intra-ejecta dark plains, 3) perform crater counts of the intra-ejecta dark plains, the ejecta, and the Caloris floor light plains and 4) refine the stratigraphy of Caloris basin units. We will use new high resolution (200-300 m/p) imaging data from the MDIS instrument to create a new geomorphic map of the dark annulus around the Caloris basin. Known Caloris group formations will be mapped where identified and any new units will be defined and mapped as necessary. Specifically, we will delineate hummocks and smooth plains within the Odin formation and map them separately. We will look for unequivocal evidence of volcanic activity within the dark annulus and the Odin Formation, such as vents and flow lobes. The location of any filled craters will be especially noted, to be incorporated into a new crater classification scheme that includes both degradation state and level and type of infilling. We will also distinguish between craters infilled with 1) lava, 2) impact melt and 3) ejecta, based on our interpretation of the MDIS images. We will then determine the crater size-frequency distribution of each geomorphic unit. We will analyze the crater density of the Caloris floor plains unit, the Odin Formation ejecta and the Odin Formation intra-ejecta dark plains. We will do a second count of Caloris floor craters that includes filled craters, to attempt to get a minimum age for the underlying dark basement. Crater counting on any additional geologic units will depend upon results of the geomorphic mapping. Finally, we will refine the stratigraphy of the Caloris basin units. We start in the region where MESSENGER data over-laps Mariner 10 images. By comparing the Caloris group formations mapped in the Tolstoj and Shakespeare quadrangles to the overlapping MDIS images, we determine the distinctive geomorphology of each of these units in the high resolution MESSENGER data. We will then use this as diagnostic criteria as we map the rest of the basin.

Surface Wave Propagation on a Laterally Heterogeneous Earth

NASA Astrophysics Data System (ADS)

Tromp, Jeroen

1992-01-01

Love and Rayleigh waves propagating on the surface of the Earth exhibit path, phase and amplitude anomalies as a result of the lateral heterogeneity of the mantle. In the JWKB approximation, these anomalies can be determined by tracing surface wave trajectories, and calculating phase and amplitude anomalies along them. A time- or frequency -domain JWKB analysis yields local eigenfunctions, local dispersion relations, and conservation laws for the surface wave energy. The local dispersion relations determine the surface wave trajectories, and the energy equations determine the surface wave amplitudes. On an anisotrophic Earth model the local dispersion relation and the local vertical eigenfunctions depend explicitly on the direction of the local wavevector. Apart from the usual dynamical phase, which is the integral of the local wavevector along a raypath, there is an additional variation is phase. This additional phase, which is an analogue of the Berry phase in adiabatic quantum mechanics, vanishes in a waveguide with a local vertical two-fold symmetry axis or a local horizontal mirror plane. JWKB theory breaks down in the vicinity of caustics, where neighboring rays merge and the surface wave amplitude diverges. Based upon a potential representation of the surface wave field, a uniformly valid Maslov theory can be obtained. Surface wave trajectories are determined by a system of four ordinary differential equations which define a three-dimensional manifold in four-dimensional phase space (theta,phi,k_theta,k _phi), where theta is colatitude, phi is longitude, and k_theta and k _phi are the covariant components of the wavevector. There are no caustics in phase space; it is only when the rays in phase space are projected onto configuration space (theta,phi), the mixed spaces (k_theta,phi ) and (theta,k_phi), or onto momentum space (k_theta,k _phi), that caustics occur. The essential strategy is to employ a mixed or momentum space representation of the wavefield in the vicinity of a configuration space caustic.

Disentangling the Cosmic Web with Lagrangian Submanifold

NASA Astrophysics Data System (ADS)

Shandarin, Sergei F.; Medvedev, Mikhail V.

2016-10-01

The Cosmic Web is a complicated highly-entangled geometrical object. Remarkably it has formed from practically Gaussian initial conditions, which may be regarded as the simplest departure from exactly uniform universe in purely deterministic mapping. The full complexity of the web is revealed neither in configuration no velocity spaces considered separately. It can be fully appreciated only in six-dimensional (6D) phase space. However, studies of the phase space is complicated by the fact that every projection of it on a three-dimensional (3D) space is multivalued and contained caustics. In addition phase space is not a metric space that complicates studies of geometry. We suggest to use Lagrangian submanifold i.e., x = x(q), where both x and q are 3D vectors instead of the phase space for studies the complexity of cosmic web in cosmological N-body dark matter simulations. Being fully equivalent in dynamical sense to the phase space it has an advantage of being a single valued and also metric space.

Surface waves with high angular momentum: leakage from remote caustics, and tightly coiled streamlines

NASA Astrophysics Data System (ADS)

Berry, M. V.

2018-07-01

Outgoing cylindrical waves scattered by a disk, or emerging from a source inside it, are represented by Hankel functions of order m. For large m, these waves decay rapidly outside the disk and resemble radially evanescent surface waves travelling around it. But they eventually leak weakly away, in a manner described accurately by the asymptotics of the Hankel function. The transition occurs at radial distance ∣m∣ (in wavelength units), which constitutes a circular caustic from which the radiation leaking out, described by the streamlines, appears to issue tangentially. In the evanescent region, the streamlines form spirals, whose windings get exponentially closer nearer the disk. These insights are intended to help graduate students demystify mathematics associated with scattering theory.

Carbonation of metal silicates for long-term CO2 sequestration

DOEpatents

Blencoe, James G; Palmer, Donald A; Anovitz, Lawrence M; Beard, James S

2014-03-18

In a preferred embodiment, the invention relates to a process of sequestering carbon dioxide. The process comprises the steps of: (a) reacting a metal silicate with a caustic alkali-metal hydroxide to produce a hydroxide of the metal formerly contained in the silicate; (b) reacting carbon dioxide with at least one of a caustic alkali-metal hydroxide and an alkali-metal silicate to produce at least one of an alkali-metal carbonate and an alkali-metal bicarbonate; and (c) reacting the metal hydroxide product of step (a) with at least one of the alkali-metal carbonate and the alkali-metal bicarbonate produced in step (b) to produce a carbonate of the metal formerly contained in the metal silicate of step (a).

Carbonation of metal silicates for long-term CO.sub.2 sequestration

DOEpatents

Blencoe, James G [Harriman, TN; Palmer, Donald A [Oliver Springs, TN; Anovitz, Lawrence M [Knoxville, TN; Beard, James S [Martinsville, VA

2012-02-14

In a preferred embodiment, the invention relates to a process of sequestering carbon dioxide. The process comprises the steps of: (a) reacting a metal silicate with a caustic alkali-metal hydroxide to produce a hydroxide of the metal formerly contained in the silicate; (b) reacting carbon dioxide with at least one of a caustic alkali-metal hydroxide and an alkali-metal silicate to produce at least one of an alkali-metal carbonate and an alkali-metal bicarbonate; and (c) reacting the metal hydroxide product of step (a) with at least one of the alkali-metal carbonate and the alkali-metal bicarbonate produced in step (b) to produce a carbonate of the metal formerly contained in the metal silicate of step (a).

Viable Mycobacterium avium ssp. paratuberculosis isolated from calf milk replacer.

PubMed

Grant, Irene R; Foddai, Antonio C G; Tarrant, James C; Kunkel, Brenna; Hartmann, Faye A; McGuirk, Sheila; Hansen, Chungyi; Talaat, Adel M; Collins, Michael T

2017-12-01

When advising farmers on how to control Johne's disease in an infected herd, one of the main recommendations is to avoid feeding waste milk to calves and instead feed calf milk replacer (CMR). This advice is based on the assumption that CMR is free of viable Mycobacterium avium ssp. paratuberculosis (MAP) cells, an assumption that has not previously been challenged. We tested commercial CMR products (n = 83) obtained from dairy farms around the United States by the peptide-mediated magnetic separation (PMS)-phage assay, PMS followed by liquid culture (PMS-culture), and direct IS900 quantitative PCR (qPCR). Conventional microbiological analyses for total mesophilic bacterial counts, coliforms, Salmonella, coagulase-negative staphylococci, streptococci, nonhemolytic Corynebacterium spp., and Bacillus spp. were also performed to assess the overall microbiological quality of the CMR. Twenty-six (31.3%) of the 83 CMR samples showed evidence of the presence of MAP. Seventeen (20.5%) tested positive for viable MAP by the PMS-phage assay, with plaque counts ranging from 6 to 1,212 pfu/50 mL of reconstituted CMR (average 248.5 pfu/50 mL). Twelve (14.5%) CMR samples tested positive for viable MAP by PMS-culture; isolates from all 12 of these samples were subsequently confirmed by whole-genome sequencing to be different cattle strains of MAP. Seven (8.4%) CMR samples tested positive for MAP DNA by IS900 qPCR. Four CMR samples tested positive by both PMS-based tests and 5 CMR samples tested positive by IS900 qPCR plus one or other of the PMS-based tests, but only one CMR sample tested positive by all 3 MAP detection tests applied. All conventional microbiology results were within current standards for whole milk powders. A significant association existed between higher total bacterial counts and presence of viable MAP indicated by either of the PMS-based assays. This represents the first published report of the isolation of viable MAP from CMR. Our findings raise concerns about the potential ability of MAP to survive manufacture of dried milk-based products. The Authors. Published by the Federation of Animal Science Societies and Elsevier Inc. on behalf of the American Dairy Science Association®. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/3.0/).

Ammonium hydroxide poisoning

MedlinePlus

Ammonium hydroxide is a colorless liquid chemical solution. It is in a class of substances called caustics. Ammonium hydroxide forms when ammonia dissolves in water. This article discusses poisoning from ...

Counting the Nouns: Simple Structural Cues to Verb Meaning

ERIC Educational Resources Information Center

Yuan, Sylvia; Fisher, Cynthia; Snedeker, Jesse

2012-01-01

Two-year-olds use the sentence structures verbs appear in--"subcategorization frames"--to guide verb learning. This is syntactic bootstrapping. This study probed the developmental origins of this ability. The structure-mapping account proposes that children begin with a bias toward one-to-one mapping between nouns in sentences and participant…

Effect of packaging technology on microbiological and sensory quality of a cooked blood sausage, Morcela de Arroz, from Monchique region of Portugal.

PubMed

Pereira, J A; Dionísio, L; Patarata, L; Matos, T J S

2015-03-01

Morcela de Arroz (MA), a popular Portuguese blood sausage, with high pH and water activity (aw), is traditionally commercialized without preservatives and unpacked. This study evaluated the best packaging solution to extend MA shelf life stored at 4±1°C for 44days: without packaging (WP), vacuum (VP) and modified atmosphere packaging (MAP) (80% CO2; 20% N2). Mesophilic (MTVC), psychrotrophic (PTVC), lactic acid bacteria (LAB), pseudomonads, molds and yeasts, Enterobacteriaceae, Listeria monocytogenes, Salmonella spp., Bacillus cereus, Clostridium perfringens, sensory properties, pH, moisture and aw were studied. Moisture and aw decreased (p<0.05) in WP. pH decreased in WP and MAP during storage. MTVC and PTVC counts increased to values around 7logCFU/g at 44days of storage. LAB and Enterobacteriaceae counts were higher (p<0.05) in VP. Pseudomonads were inhibited (p<0.05) by MAP after 8days of storage. Sensory parameters were affected (p<0.05) by packaging and storage time. Globally, MAP performed better. Copyright © 2014 Elsevier Ltd. All rights reserved.

Mobile mapping of sporting event spectators using bluetooth sensors: tour of flanders 2011.

PubMed

Versichele, Mathias; Neutens, Tijs; Goudeseune, Stephanie; van Bossche, Frederik; van de Weghe, Nico

2012-10-22

Accurate spatiotemporal information on crowds is a necessity for a better management in general and for the mitigation of potential security risks. The large numbers of individuals involved and their mobility, however, make generation of this information non-trivial. This paper proposes a novel methodology to estimate and map crowd sizes using mobile Bluetooth sensors and examines to what extent this methodology represents a valuable alternative to existing traditional crowd density estimation methods. The proposed methodology is applied in a unique case study that uses Bluetooth technology for the mobile mapping of spectators of the Tour of Flanders 2011 road cycling race. The locations of nearly 16,000 cell phones of spectators along the race course were registered and detailed views of the spatiotemporal distribution of the crowd were generated. Comparison with visual head counts from camera footage delivered a detection ratio of 13.0 ± 2.3%, making it possible to estimate the crowd size. To our knowledge, this is the first study that uses mobile Bluetooth sensors to count and map a crowd over space and time.

Mobile Mapping of Sporting Event Spectators Using Bluetooth Sensors: Tour of Flanders 2011

PubMed Central

Versichele, Mathias; Neutens, Tijs; Goudeseune, Stephanie; van Bossche, Frederik; van de Weghe, Nico

2012-01-01

Accurate spatiotemporal information on crowds is a necessity for a better management in general and for the mitigation of potential security risks. The large numbers of individuals involved and their mobility, however, make generation of this information non-trivial. This paper proposes a novel methodology to estimate and map crowd sizes using mobile Bluetooth sensors and examines to what extent this methodology represents a valuable alternative to existing traditional crowd density estimation methods. The proposed methodology is applied in a unique case study that uses Bluetooth technology for the mobile mapping of spectators of the Tour of Flanders 2011 road cycling race. The locations of nearly 16,000 cell phones of spectators along the race course were registered and detailed views of the spatiotemporal distribution of the crowd were generated. Comparison with visual head counts from camera footage delivered a detection ratio of 13.0 ± 2.3%, making it possible to estimate the crowd size. To our knowledge, this is the first study that uses mobile Bluetooth sensors to count and map a crowd over space and time. PMID:23202044

Radio Source Contributions to the Microwave Sky

NASA Astrophysics Data System (ADS)

Boughn, S. P.; Partridge, R. B.

2008-03-01

Cross-correlations of the Wilkinson Microwave Anisotropy Probe (WMAP) full sky K-, Ka-, Q-, V-, and W-band maps with the 1.4 GHz NVSS source count map and the HEAO I A2 2-10 keV full sky X-ray flux map are used to constrain rms fluctuations due to unresolved microwave sources in the WMAP frequency range. In the Q band (40.7 GHz), a lower limit, taking account of only those fluctuations correlated with the 1.4 GHz radio source counts and X-ray flux, corresponds to an rms Rayleigh-Jeans temperature of ˜2 μK for a solid angle of 1 deg2 assuming that the cross-correlations are dominated by clustering, and ˜1 μK if dominated by Poisson fluctuations. The correlated fluctuations at the other bands are consistent with a β = -2.1 ± 0.4 frequency spectrum. If microwave sources are distributed similarly in redshift to the radio and X-ray sources and are similarly clustered, then the implied total rms microwave fluctuations correspond to ˜5 μK. While this value should be considered no more than a plausible estimate, it is similar to that implied by the excess, small angular scale fluctuations observed in the Q band by WMAP and is consistent with estimates made by extrapolating low-frequency source counts.

Botulism challenge studies of a modified atmosphere package for fresh mussels: inoculated pack studies.

PubMed

Newell, C R; Ma, Li; Doyle, Michael

2012-06-01

A series of botulism challenge studies were performed to determine the possibility of production of botulinum toxin in mussels (Mytilus edulis) held under a commercial high-oxygen (60 to 65% O(2)), modified atmosphere packaging (MAP) condition. Spore mixtures of six strains of nonproteolytic Clostridium botulinum were introduced into mussel MAP packages receiving different packaging buffers with or without the addition of lactic acid bacteria. Dye studies and package flipping trials were conducted to ensure internalization of spores by packed mussels. Inoculated mussel packages were stored at normal (4°C) and abusive (12°C) temperatures for 21 and 13 days, respectively, which were beyond the packaged mussels' intended shelf life. Microbiological and chemical analyses were conducted at predetermined intervals (a total of five sampling times at each temperature), including total aerobic plate counts, C. botulinum counts, lactic acid bacterial counts, package headspace gas composition, pH of packaging buffer and mussel meat, and botulinum toxin assays of packaging buffer and mussel meat. Results revealed that C. botulinum inoculated in fresh mussels packed under MAP packaging did not produce toxin, even at an abusive storage temperature and when held beyond their shelf life. No evidence was found that packaging buffers or gas composition influenced the lack of botulinum toxin production in packed mussels.

Results of Characterization and Retrieval Testing on Tank 241-C-109 Heel Solids

DOE Office of Scientific and Technical Information (OSTI.GOV)

Callaway, William S.

Eight samples of heel solids from tank 241-C-109 were delivered to the 222-S Laboratory for characterization and dissolution testing. After being drained thoroughly, one-half to two-thirds of the solids were off-white to tan solids that, visually, were fairly evenly graded in size from coarse silt (30-60 μm) to medium pebbles (8-16 mm). The remaining solids were mostly strongly cemented aggregates ranging from coarse pebbles (16-32 mm) to fine cobbles (6-15 cm) in size. Solid phase characterization and chemical analysis indicated that the air-dry heel solids contained ≈58 wt% gibbsite [Al(OH){sub 3}] and ≈37 wt% natrophosphate [Na{sub 7}F(PO{sub 4}){sub 2}·19H{sub 2}O].more » The strongly cemented aggregates were mostly fine-grained gibbsite cemented with additional gibbsite. Dissolution testing was performed on two test samples. One set of tests was performed on large pieces of aggregate solids removed from the heel solids samples. The other set of dissolution tests was performed on a composite sample prepared from well-drained, air-dry heel solids that were crushed to pass a 1/4-in. sieve. The bulk density of the composite sample was 2.04 g/mL. The dissolution tests included water dissolution followed by caustic dissolution testing. In each step of the three-step water dissolution tests, a volume of water approximately equal to 3 times the initial volume of the test solids was added. In each step, the test samples were gently but thoroughly mixed for approximately 2 days at an average ambient temperature of 25 °C. The caustic dissolution tests began with the addition of sufficient 49.6 wt% NaOH to the water dissolution residues to provide ≈3.1 moles of OH for each mole of Al estimated to have been present in the starting composite sample and ≈2.6 moles of OH for each mole of Al potentially present in the starting aggregate sample. Metathesis of gibbsite to sodium aluminate was then allowed to proceed over 10 days of gentle mixing of the test samples at temperatures ranging from 26-30 °C. The metathesized sodium aluminate was then dissolved by addition of volumes of water approximately equal to 1.3 times the volumes of caustic added to the test slurries. Aluminate dissolution was allowed to proceed for 2 days at ambient temperatures of ≈29 °C. Overall, the sequential water and caustic dissolution tests dissolved and removed 80.0 wt% of the tank 241-C-109 crushed heel solids composite test sample. The 20 wt% of solids remaining after the dissolution tests were 85-88 wt% gibbsite. If the density of the residual solids was approximately equal to that of gibbsite, they represented ≈17 vol% of the initial crushed solids composite test sample. In the water dissolution tests, addition of a volume of water ≈6.9 times the initial volume of the crushed solids composite was sufficient to dissolve and recover essentially all of the natrophosphate present. The ratio of the weight of water required to dissolve the natrophosphate solids to the estimated weight of natrophosphate present was 8.51. The Environmental Simulation Program (OLI Systems, Inc., Morris Plains, New Jersey) predicts that an 8.36 w/w ratio would be required to dissolve the estimated weight of natrophosphate present in the absence of other components of the heel solids. Only minor amounts of Al-bearing solids were removed from the composite solids in the water dissolution tests. The caustic metathesis/aluminate dissolution test sequence, executed at temperatures ranging from 27-30 °C, dissolved and recovered ≈69 wt% of the gibbsite estimated to have been present in the initial crushed heel solids composite. This level of gibbsite recovery is consistent with that measured in previous scoping tests on the dissolution of gibbsite in strong caustic solutions. Overall, the sequential water and caustic dissolution tests dissolved and removed 80.3 wt% of the tank 241-C-109 aggregate solids test sample. The residual solids were 92-95 wt% gibbsite. Only a minor portion (≈4.5 wt%) of the aggregate solids was dissolved and recovered in the water dissolution test. Other than some smoothing caused by continuous mixing, the aggregates were essentially unaffected by the water dissolution tests. During the caustic metathesis/aluminate dissolution test sequence, ≈81 wt% of the gibbsite estimated to have been present in the aggregate solids was dissolved and recovered. The pieces of aggregate were significantly reduced in size but persisted as distinct pieces of solids. The increased level of gibbsite recovery, as compared to that for the crushed heel solids composite, suggests that the way the gibbsite solids and caustic solution are mixed is a key determinant of the overall efficiency of gibbsite dissolution and recovery. The liquids recovered after the caustic dissolution tests on the crushed solids composite and the aggregate solids were observed for 170 days. No precipitation of gibbsite was observed. The distribution of particle sizes in the residual solids recovered following the dissolution tests on the crushed heel solids composite was characterized. Wet sieving indicated that 21.4 wt% of the residual solids were >710 μm in size, and laser light scattering indicated that the median equivalent spherical diameter in the <710-μm solids was 35 μm. The settling behavior of the residual solids following the large-scale dissolution tests was also studied. When dispersed at a concentration of ≈1 vol% in water, ≈24 wt% of the residual solids settled at a rate >0.43 in./s; ≈68 wt% settled at rates between 0.02 and 0.43 in./s; and ≈7 wt% settled slower than 0.02 in./s.« less

A comparative study of RNA-Seq and microarray data analysis on the two examples of rectal-cancer patients and Burkitt Lymphoma cells.

PubMed

Wolff, Alexander; Bayerlová, Michaela; Gaedcke, Jochen; Kube, Dieter; Beißbarth, Tim

2018-01-01

Pipeline comparisons for gene expression data are highly valuable for applied real data analyses, as they enable the selection of suitable analysis strategies for the dataset at hand. Such pipelines for RNA-Seq data should include mapping of reads, counting and differential gene expression analysis or preprocessing, normalization and differential gene expression in case of microarray analysis, in order to give a global insight into pipeline performances. Four commonly used RNA-Seq pipelines (STAR/HTSeq-Count/edgeR, STAR/RSEM/edgeR, Sailfish/edgeR, TopHat2/Cufflinks/CuffDiff)) were investigated on multiple levels (alignment and counting) and cross-compared with the microarray counterpart on the level of gene expression and gene ontology enrichment. For these comparisons we generated two matched microarray and RNA-Seq datasets: Burkitt Lymphoma cell line data and rectal cancer patient data. The overall mapping rate of STAR was 98.98% for the cell line dataset and 98.49% for the patient dataset. Tophat's overall mapping rate was 97.02% and 96.73%, respectively, while Sailfish had only an overall mapping rate of 84.81% and 54.44%. The correlation of gene expression in microarray and RNA-Seq data was moderately worse for the patient dataset (ρ = 0.67-0.69) than for the cell line dataset (ρ = 0.87-0.88). An exception were the correlation results of Cufflinks, which were substantially lower (ρ = 0.21-0.29 and 0.34-0.53). For both datasets we identified very low numbers of differentially expressed genes using the microarray platform. For RNA-Seq we checked the agreement of differentially expressed genes identified in the different pipelines and of GO-term enrichment results. In conclusion the combination of STAR aligner with HTSeq-Count followed by STAR aligner with RSEM and Sailfish generated differentially expressed genes best suited for the dataset at hand and in agreement with most of the other transcriptomics pipelines.

Leaching Characteristics of Hanford Ferrocyanide Wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Edwards, Matthew K.; Fiskum, Sandra K.; Peterson, Reid A.

2009-12-21

A series of leach tests were performed on actual Hanford Site tank wastes in support of the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The samples were targeted composite slurries of high-level tank waste materials representing major complex, radioactive, tank waste mixtures at the Hanford Site. Using a filtration/leaching apparatus, sample solids were concentrated, caustic leached, and washed under conditions representative of those planned for the Pretreatment Facility in the WTP. Caustic leaching was performed to assess the mobilization of aluminum (as gibbsite, Al[OH]3, and boehmite AlO[OH]), phosphates [PO43-], chromium [Cr3+] and, to a lesser extent, oxalates [C2O42-]). Ferrocyanidemore » waste released the solid phase 137Cs during caustic leaching; this was antithetical to the other Hanford waste types studied. Previous testing on ferrocyanide tank waste focused on the aging of the ferrocyanide salt complex and its thermal compatibilities with nitrites and nitrates. Few studies, however, examined cesium mobilization in the waste. Careful consideration should be given to the pretreatment of ferrocyanide wastes in light of this new observed behavior, given the fact that previous testing on simulants indicates a vastly different cesium mobility in this waste form. The discourse of this work will address the overall ferrocyanide leaching characteristics as well as the behavior of the 137Cs during leaching.« less

Catastrophe Optics Method to Determine the Micro-Nano Size Profiles at TPL of Liquid Films on a Solid Surface

NASA Technical Reports Server (NTRS)

Chao, David F.; McQuillen, J. B.; Sankovic, J. M.; Zhang, Nengli

2009-01-01

As discovered by recent studies, what directly affects the wetting and spreading is curvature in micro-region rather than the macroscopic contact angle. Measuring the profile of the micro-region becomes an important research topic. Recently, catastrophe optics has been applied to this kind of measurements. Optical catastrophe occurring in far field of waves of liquid-refracted laser beam implies a wealth of information about the liquid spreading not only for liquid drops but also for films. When a parallel laser beam passes through a liquid film on a slide glass at three-phase-line (TPL), very interesting optical image patterns occur on a screen far from the film. An analysis based on catastrophe optics discloses and interprets the formation of these optical image patterns. The analysis reveals that the caustic line manifested as the bright-thick line on the screen implies the lowest hierarchy of optical catastrophes, called fold caustic. This optical catastrophe is produced by the inflexion line on liquid surface at the liquid foot, which is formed not only in the spreading of drops but also in spreading of films. The generalized catastrophe optics method enables to identify the edge profiles and determine the edge foot height of liquid films. Keywords: Crossover region, Inflexion line, liquid edge foot, Catastrophe optics, Caustic and diffraction

Mechanism of Phosphorus Removal from Hanford Tank Sludge by Caustic Leaching

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lumetta, Gregg J.

Two experiments were conducted to explore the mechanism by which phosphorus is removed from Hanford tank sludge by caustic leaching. In the first experiment, a series of phosphate salts were treated with 3 M NaOH under conditions prototypic of the actual leaching process to be performed in the Waste Treatment and Immobilization Plant (WTP). The phosphates used were aluminum phosphate, bismuth phosphate, chromium(III) phosphate, and β-tri-calcium phosphate; all of these phases have previously been determined to exist in Hanford tank sludge. The leachate solution was sampled at selected time intervals and analyzed for the specific metal ion involved (Al, Bi,more » Ca, or Cr) and for P (total and as phosphate). The solids remaining after completion of the caustic leaching step were analyzed to determine the reaction product. In the second experiment, the dependence of P removal from bismuth phosphate was examined as a function of the hydroxide ion concentration. It was anticipated that a plot of log[phosphate] versus log[hydroxide] would provide insight into the phosphorus-removal mechanism. This report describes the test activities outlined in Section 6.3.2.1, Preliminary Investigation of Phosphate Dissolution, in Test Plan TP-RPP-WTP-467, Rev.1. The objectives, success criteria, and test conditions of Section 6.3.2.1 are summarized here.« less

A Systematic Analysis of Caustic Methods for Galaxy Cluster Masses

NASA Astrophysics Data System (ADS)

Gifford, Daniel; Miller, Christopher; Kern, Nicholas

2013-08-01

We quantify the expected observed statistical and systematic uncertainties of the escape velocity as a measure of the gravitational potential and total mass of galaxy clusters. We focus our attention on low redshift (z <=0.15) clusters, where large and deep spectroscopic datasets currently exist. Utilizing a suite of Millennium Simulation semi-analytic galaxy catalogs, we find that the dynamical mass, as traced by either the virial relation or the escape velocity, is robust to variations in how dynamical friction is applied to "orphan" galaxies in the mock catalogs (i.e., those galaxies whose dark matter halos have fallen below the resolution limit). We find that the caustic technique recovers the known halo masses (M 200) with a third less scatter compared to the virial masses. The bias we measure increases quickly as the number of galaxies used decreases. For N gal > 25, the scatter in the escape velocity mass is dominated by projections along the line-of-sight. Algorithmic uncertainties from the determination of the projected escape velocity profile are negligible. We quantify how target selection based on magnitude, color, and projected radial separation can induce small additional biases into the escape velocity masses. Using N gal = 150 (25), the caustic technique has a per cluster scatter in ln (M|M 200) of 0.3 (0.5) and bias 1% ± 3} (16% ± 5}) for clusters with masses >1014 M ⊙ at z < 0.15.

Laboratory Tests on Post-Filtration Precipitation in the WTP Pretreatment Process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Russell, Renee L.; Peterson, Reid A.; Rinehart, Donald E.

Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed, and operated as part of a plan to respond to issue M12, "Undemonstrated Leaching Processes," of the External Flowsheet Review Team (EFRT) issue response plan (Barnes et al. 2006). The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, andmore » slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. A simplified flow diagram of the PEP system is shown in Figure 1.1. Two operating scenarios are currently being evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario has caustic leaching performed in the UFP-2 ultrafiltration feed vessels (i.e., vessel UFP-VSL-T02A in the PEP; and vessels UFP-VSL-00002A and B in the WTP PTF). The second scenario has caustic leaching conducted in the UFP-1 ultrafiltration feed preparation vessels (i.e., vessels UFP-VSL-T01A and B in the PEP; vessels UFP-VSL-00001A and B in the WTP PTF).« less

F-Area Acid/Caustic Basin groundwater monitoring report. Second quarter 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1995-09-01

During second quarter 1995, samples from the FAC monitoring wells at the F-Area Acid/Caustic Basin were collected and analyzed for herbicides/pesticides, indicator parameters, metals, nitrate, radionuclide indicators, volatile organic compounds, and other constituents. Piezometer FAC 5P and monitoring well FAC 6 were dry and could not be sampled. New monitoring wells FAC 9C, 10C, 11C, and 12C were completed in the Barnwell/McBean aquifer and were sampled for the first time during third quarter 1994 (second quarter 1995 is the fourth of four quarters of data required to support the closure of the basin). Analytical results that exceeded final Primary Drinkingmore » Water Standards (PDWS) or Savannah River Site (SRS) Flag 2 criteria such as the SRS turbidity standard of 50 NTU during the quarter were as follows: gross alpha exceeded the final PDWS and aluminum, iron, manganese, and radium-226 exceeded the SRS Flag 2 criteria in one or more of the FAC wells. Turbidity exceeded the SRS standard (50 NTU) in well FAC 3. Groundwater flow direction in the water table beneath the F-Area Acid/Caustic Basin was to the west at a rate of 1300 feet per year. Groundwater flow in the Barnwell/McBean was to the northeast at a rate of 50 feet per year.« less

Production report: enhanced recovery. [Combustion, steam, soak steam drive, polymer and caustic, micellar/surfactant miscible hydrocarbons and CO/sub 2/

DOE Office of Scientific and Technical Information (OSTI.GOV)

Noran, D.

Schemes for producing additional oil using enhanced-recovery (ER) methods are under way throughout the world. The extent and intensity of ER activity is highest in the U.S. with 156 projects, about two-thirds of which are thermal. Venezuela has a strong ER commitment with at least 70 active projects, with a major thrust on steam soak. Significant projects, but limited in number, are under way in Canada, North Africa, Southeast Asia, and elsewhere in Latin America. A breakdown of active U.S. ER projects for 1970, 1973, and 1975 is tabulated for combustion, steam soak, steam drive, polymer and caustic, micellar/surfactant, misciblemore » hydrocarbon, and CO/sub 2/ methods. This Oil and Gas Journal Survey includes seven articles; the first six were prepared by David Noran, Journal Production Editor. The final article on Venezuelan activity was written by Alvaro Franco, Editor and Publisher, Petroleo Internacional. The articles are entitled: U.S. Thermal Recovery Activity Growing Steadily; Operators Accelerate Testing of Micellar/Surfactant Potential; Polymer and Caustic Methods on Rebound; Gas Miscible Projects Move at Slow Pace; Canadian Enhanced-Recovery Activity Moderate, Centers on Thermal Projects; Other Global Enhanced-Recovery Work Sparse; and Thermal Work Humming in Venezuela. Detailed information on each method is tabulated for each article. (MCW)« less

Direct anodic hydrochloric acid and cathodic caustic production during water electrolysis

NASA Astrophysics Data System (ADS)

Lin, Hui-Wen; Cejudo-Marín, Rocío; Jeremiasse, Adriaan W.; Rabaey, Korneel; Yuan, Zhiguo; Pikaar, Ilje

2016-02-01

Hydrochloric acid (HCl) and caustic (NaOH) are among the most widely used chemicals by the water industry. Direct anodic electrochemical HCl production by water electrolysis has not been successful as current commercially available electrodes are prone to chlorine formation. This study presents an innovative technology simultaneously generating HCl and NaOH from NaCl using a Mn0.84Mo0.16O2.23 oxygen evolution electrode during water electrolysis. The results showed that protons could be anodically generated at a high Coulombic efficiency (i.e. ≥ 95%) with chlorine formation accounting for 3 ~ 5% of the charge supplied. HCl was anodically produced at moderate strengths at a CE of 65 ± 4% together with a CE of 89 ± 1% for cathodic caustic production. The reduction in CE for HCl generation was caused by proton cross-over from the anode to the middle compartment. Overall, this study showed the potential of simultaneous HCl and NaOH generation from NaCl and represents a major step forward for the water industry towards on-site production of HCl and NaOH. In this study, artificial brine was used as a source of sodium and chloride ions. In theory, artificial brine could be replaced by saline waste streams such as Reverse Osmosis Concentrate (ROC), turning ROC into a valuable resource.

Distribution and density of bird species hazardous to aircraft

USGS Publications Warehouse

Robbins, C.S.; Gauthreaux, Sidney A.

1975-01-01

Only in the past 5 years has it become feasible to map the relative abundance of North American birds. Two programs presently under way and a third that is in the experimental phase are making possible the up-to-date mapping of abundance as well as distribution. A fourth program that has been used successfully in Europe and on a small scale in parts of North America yields detailed information on breeding distribution. The Breeding Bird Survey, sponsored by the U.S. Bureau of Sport Fisheries and Wildlife and the Canadian Wildlife Service, involves 2,000 randomly distributed roadside counts that are conducted during the height of the breeding season in all U.S. States and Canadian Provinces. Observations of approximately 1.4 million birds per year are entered on magnetic tape and subsequently used both for statistical analysis of population trends and for computer mapping of distribution and abundance. The National Audubon Society's Christmas Bird Count is conducted in about 1,000 circles, each 15 miles (24 km) in diameter, in the latter half of December. Raw data for past years have been published in voluminous reports, but not in a form for ready analysis. Under a contract between the U.S. Air Force and the U. S. Bureau of Sport Fisheries and Wildlife (in cooperation with the National Audubon Society), preliminary maps showing distribution and abundance of selected species that are potential hazards to aircraft are presently being mapped and prepared for publication. The Winter Bird Survey, which is in its fifth season of experimental study in a limited area in Central Maryland, may ultimately replace the Christmas Bird Count source. This Survey consists of a standardized 8-kilometer (5-mile) route covered uniformly once a year during midwinter. Bird Atlas programs, which map distribution but not abundance, are well established in Europe and are gaining interest in America

IMPROVED ANTIFOAM AGENT STUDY END OF YEAR REPORT, EM PROJECT 3.2.3

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lambert, D.; Koopman, D.; Newell, J.

2011-09-30

Antifoam 747 is added to minimize foam produced by process gases and water vapor during chemical processing of sludge in the Defense Waste Processing Facility (DWPF). This allows DWPF to maximize acid addition and evaporation rates to minimize the cycle time in the Chemical Processing Cell (CPC). Improvements in DWPF melt rate due to the addition of bubblers in the melter have resulted in the need for further reductions in cycle time in the CPC. This can only be accomplished with an effective antifoam agent. DWPF production was suspended on March 22, 2011 as the result of a Flammable Gasmore » New Information/(NI) Potential Inadequacy in the Safety Analysis (PISA). The issue was that the DWPF melter offgas flammability strategy did not take into account the H and C in the antifoam, potentially flammable components, in the melter feed. It was also determined the DWPF was using much more antifoam than anticipated due to a combination of longer processing in the CPC due to high Hg, longer processing due to Actinide Removal Process (ARP)/Modular Caustic Side Solvent Extraction Unit (MCU) additions, and adding more antifoam than recommended. The resolution to the PISA involved and assessment of the impact of the antifoam on melter flammability and the implementation of a strategy to control additions within acceptable levels. This led to the need to minimize the use of Antifoam 747 in processing beginning in May 2011. DWPF has had limited success in using Antifoam 747 in caustic processing. Since starting up the ARP facility, the ARP product (similar chemically to caustic sludge) is added to the Sludge Receipt and Adjustment Tank (SRAT) at boiling and evaporated to maintain a constant SRAT volume. Although there is very little offgas generated during caustic boiling, there is a large volume of water vapor produced which can lead to foaming. High additions and more frequent use of antifoam are used to mitigate the foaming during caustic boiling. The result of these three issues above is that DWPF had three antifoam needs in FY2011: (1) Determine the cause of the poor Antifoam 747 performance during caustic boiling; (2) Determine the decomposition products of Antifoam 747 during CPC processing; and (3) Improve the effectiveness of Antifoam 747, in order to minimize the amount used. Testing was completed by Illinois Institute of Technology (IIT) and Savannah River National Laboratory (SRNL) researchers to address these questions. The testing results reported were funded by both DWPF and DOE/EM 31. Both sets of results are reported in this document for completeness. The results of this research are summarized: (1) The cause for the poor Antifoam 747 performance during caustic boiling was the high hydrolysis rate, cleaving the antifoam molecule in two, leading to poor antifoam performance. In testing with pH solutions from 1 to 13, the antifoam degraded quickly at a pH < 4 and pH > 10. As the antifoam decomposed it lost its spreading ability (wetting agent performance), which is crucial to its antifoaming performance. During testing of a caustic sludge simulants, there was more foam in tests with added Antifoam 747 than in tests without added antifoam. (2) Analyses were completed to determine the composition of the two antifoam components and Antifoam 747. In addition, the decomposition products of Antifoam 747 were determined during CPC processing of sludge simulants. The main decomposition products were identified primarily as Long Chain Siloxanes, boiling point > 400 C. Total antifoam recovery was 33% by mass. In a subsequent study, various compounds potentially related to antifoam were found using semi-volatile organic analysis and volatile organic analysis on the hexane extractions and hexane rinses. These included siloxanes, trimethyl silanol, methoxy trimethyl silane, hexamethyl disiloxane, aliphatic hydrocarbons, dioctyl phthalate, and emulsifiers. Cumulatively, these species amounted to less than 3% of the antifoam mass. The majority of the antifoam was identified using carbon analysis of the SRAT product (40-80% by mass) and silicon analysis (23-83% by mass) of the condensate. Both studies recommended a better solvent for antifoam and more specific tests for antifoam degradation products than the Si and C analyses used. (3) The DWPF Antifoam 747 Purchase Specification was revised in Month, 2011 with a goal of increasing the quality of Antifoam 747. The purchase specification was changed to specify the manufacturer and product for both components that are blended by Siovation to produce Antifoam 747 for DWPF. Testing of Antifoam produced using both the old and new antifoam specifications perform very similarly in testing. Since the change in purchase specification has not improved antifoam performance, an improved antifoam agent is required.« less

A hierarchical spatial model of avian abundance with application to Cerulean Warblers

USGS Publications Warehouse

Thogmartin, Wayne E.; Sauer, John R.; Knutson, Melinda G.

2004-01-01

Surveys collecting count data are the primary means by which abundance is indexed for birds. These counts are confounded, however, by nuisance effects including observer effects and spatial correlation between counts. Current methods poorly accommodate both observer and spatial effects because modeling these spatially autocorrelated counts within a hierarchical framework is not practical using standard statistical approaches. We propose a Bayesian approach to this problem and provide as an example of its implementation a spatial model of predicted abundance for the Cerulean Warbler (Dendroica cerulea) in the Prairie-Hardwood Transition of the upper midwestern United States. We used an overdispersed Poisson regression with fixed and random effects, fitted by Markov chain Monte Carlo methods. We used 21 years of North American Breeding Bird Survey counts as the response in a loglinear function of explanatory variables describing habitat, spatial relatedness, year effects, and observer effects. The model included a conditional autoregressive term representing potential correlation between adjacent route counts. Categories of explanatory habitat variables in the model included land cover composition and configuration, climate, terrain heterogeneity, and human influence. The inherent hierarchy in the model was from counts occurring, in part, as a function of observers within survey routes within years. We found that the percentage of forested wetlands, an index of wetness potential, and an interaction between mean annual precipitation and deciduous forest patch size best described Cerulean Warbler abundance. Based on a map of relative abundance derived from the posterior parameter estimates, we estimated that only 15% of the species' population occurred on federal land, necessitating active engagement of public landowners and state agencies in the conservation of the breeding habitat for this species. Models of this type can be applied to any data in which the response is counts, such as animal counts, activity (e.g.,nest) counts, or species richness. The most noteworthy practical application of this spatial modeling approach is the ability to map relative species abundance. The functional relationships that we elucidated for the Cerulean Warbler provide a basis for the development of management programs and may serve to focus management and monitoring on areas and habitat variables important to Cerulean Warblers.

Carbonation of metal silicates for long-term CO.sub.2 sequestration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Blencoe, James G.; Palmer, Donald A.; Anovitz, Lawrence M.

In a preferred embodiment, the invention relates to a process of sequestering carbon dioxide. The process comprises the steps of: (a) reacting a metal silicate with a caustic alkali-metal hydroxide to produce a hydroxide of the metal formerly contained in the silicate; (b) reacting carbon dioxide with at least one of a caustic alkali-metal hydroxide and an alkali-metal silicate to produce at least one of an alkali-metal carbonate and an alkali-metal bicarbonate; and (c) reacting the metal hydroxide product of step (a) with at least one of the alkali-metal carbonate and the alkali-metal bicarbonate produced in step (b) to producemore » a carbonate of the metal formerly contained in the metal silicate of step (a).« less

Effect of heat stable salts on MDEA solution corrosivity: Part 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rooney, P.C.; DuPart, M.S.; Bacon, T.R.

1997-04-01

A comprehensive coupon corrosion testing program was undertaken to address the effect of various heat stable salts on methyldiethanolamine (MDEA) corrosivity to carbon steel and various stainless steels. Corrosion rates of carbon steel, 304SS, 316SS and 410SS liquid and vapor coupons towards MDEA, and MDEA containing various anions, at 180 F and 250 F, were measured in a reactor. Corrosion results of two refinery plant solutions before and after caustic neutralization were also performed. Based on these results, guidelines were determined for heat stable amine salt (HSAS) levels of oxalates, sulfates, formates, acetates and thiosulfates. In addition, caustic neutralization guidelinesmore » for MDEA heat stable salts were determined. Ongoing results include MDEA corrosivity with succinates, and malonates, glycolates, SO{sub 2} and ammonia.« less

A comparative study of the treatment of ethylene plant spent caustic by neutralization and classical and advanced oxidation.

PubMed

Hawari, Alaa; Ramadan, Hasanat; Abu-Reesh, Ibrahim; Ouederni, Mabrouk

2015-03-15

The treatment of spent caustic produced from an ethylene plant was investigated. In the case of neutralization alone it was found that the maximum removal of sulfide was at pH values below 5.5. The higher percentage removal of sulfides (99% at pH = 1.5) was accompanied with the highest COD removal (88%). For classical oxidation using H2O2 the maximum COD removal percentage reached 89% at pH = 2.5 and at a hydrogen peroxide concentration of 19 mM/L. For the advanced oxidation using Fenton's process it was found that the maximum COD removal of 96.5% was achieved at a hydrogen peroxide/ferrous sulfate ratio of (7:1). Copyright © 2014 Elsevier Ltd. All rights reserved.

Bench-Scale Filtration Testing in Support of the Pretreatment Engineering Platform (PEP)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Billing, Justin M.; Daniel, Richard C.; Kurath, Dean E.

Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed and operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes.” The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP testing program specifies that bench-scale testing is to bemore » performed in support of specific operations, including filtration, caustic leaching, and oxidative leaching.« less

The Influence of Glass Leachate on the Hydraulic, Physical, Mineralogical and Sorptive Properties of Hanford Sediment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kaplan, Daniel I.; Serne, R. Jeffrey; Schaef, Herbert T.

2003-08-26

The Immobilized Low Activity Waste (ILAW) generated from the Hanford Site will be disposed of in a vitrified form. It is expected that leachate from the vitrified waste will have a high pH and high ionic strength. The objective of this study was to determine the influence of glass leachate on the hydraulic, physical, mineralogical, and sorptive properties of Hanford sediments. Our approach was to put solutions of NaOH, a simplified surrogate for glass leachate, in contact with quartz sand, a simplified surrogate for the Hanford subsurface sediment, and Warden soil, an actual Hanford sediment. Following contact with three differentmore » concentrations of sodium hydroxide solutions, changes in hydraulic conductivity, porosity, moisture retention, mineralogy, aqueous chemistry, and soil-radionuclide distribution coefficients were determined. Under chemical conditions approaching the most caustic glass leachate conditions predicted in the near-field of the ILAW disposal site, approximated by 0.3 M NaOH, significant changes in mineralogy were observed. The clay minerals of the Hanford sediment evidenced the greatest dissolution thereby increasing the relative proportions of the more resistant minerals, e.g., quartz, feldspar, and calcite, in the remaining mass. Some re-precipitation of solids (mostly amorphous gels) was observed after caustic contact with both solids; these precipitates increased the moisture retention in both sediments, likely because of water retained within the gel coatings. The hydraulic conductivities were slightly lower but, because of experimental artifacts, these reductions should not be considered significant. Thus, there does not seem to be large differences in the hydraulic properties of the quartz sand or Warden silt loam soil after 192 days of contact with caustic fluids similar to glass leachate. The long term projected impact of the increased moisture retention has not been evaluated but likely will not make past simplified performance projections invalid. Despite the fact that some clay minerals, smectites and kaolinite, almost totally dissolved within a year of contact with 3.0 M NaOH (and by inference after longer time frames for 0.3 M NaOH, a more realistic surrogate for ILAW glass leachate) other sorbing minerals such as illite and chlorite do not appreciably react. The net result on sorption of common and risk relevant mobile radionuclides is not expected to be significant. Specifically, little change in Cs-Kd values and a significant increase in Sr-Kd values were measured in the simulated glass leachates versus natural groundwater. The difference in the sorptive responses of the radionuclides was attributed to differences in sorption mechanisms (Cs sorbs strongly to high-energy sites, whereas Sr sorbs primarily by cation exchange but also is sensitive to pH mediated precipitation reactions). Caustic treated sediments contacted with NaOH solutions radiotraced with Sr exhibited high Kd’s likely because of precipitation with CaCO3. In caustic solutions there was no appreciable adsorption for the three anions I-, SeO42-, or TcO4-. In the “far field” vadose zone in past performance projections, some sorption has been allowed for selenate. Even if the caustic glass leachate completely dominates the entire vadose zone below the repository, such that there will be no sorption of selenate, the dilution and pH neutralization that will occur in the upper unconfined aquifer will allow selenate adsorption to occur onto the aquifer sediments. It is recommended that a future performance assessment sensitivity run be performed to address this point.« less

An accurate derivation of the air dose-rate and the deposition concentration distribution by aerial monitoring in a low level contaminated area

NASA Astrophysics Data System (ADS)

Nishizawa, Yukiyasu; Sugita, Takeshi; Sanada, Yukihisa; Torii, Tatsuo

2015-04-01

Since 2011, MEXT (Ministry of Education, Culture, Sports, Science and Technology, Japan) have been conducting aerial monitoring to investigate the distribution of radioactive cesium dispersed into the atmosphere after the accident at the Fukushima Dai-ichi Nuclear Power Plant (FDNPP), Tokyo Electric Power Company. Distribution maps of the air dose-rate at 1 m above the ground and the radioactive cesium deposition concentration on the ground are prepared using spectrum obtained by aerial monitoring. The radioactive cesium deposition is derived from its dose rate, which is calculated by excluding the dose rate of the background radiation due to natural radionuclides from the air dose-rate at 1 m above the ground. The first step of the current method of calculating the dose rate due to natural radionuclides is calculate the ratio of the total count rate of areas where no radioactive cesium is detected and the count rate of regions with energy levels of 1,400 keV or higher (BG-Index). Next, calculate the air dose rate of radioactive cesium by multiplying the BG-Index and the integrated count rate of 1,400 keV or higher for the area where the radioactive cesium is distributed. In high dose-rate areas, however, the count rate of the 1,365-keV peak of Cs-134, though small, is included in the integrated count rate of 1,400 keV or higher, which could cause an overestimation of the air dose rate of natural radionuclides. We developed a method for accurately evaluating the distribution maps of natural air dose-rate by excluding the effect of radioactive cesium, even in contaminated areas, and obtained the accurate air dose-rate map attributed the radioactive cesium deposition on the ground. Furthermore, the natural dose-rate distribution throughout Japan has been obtained by this method.

An Embodiment Perspective on Number-Space Mapping in 3.5-year-old Dutch Children

ERIC Educational Resources Information Center

Noordende, Jaccoline E.; Volman, M(Chiel). J. M.; Leseman, Paul P. M.; Kroesbergen, Evelyn H.

2017-01-01

Previous research suggests that block adding, subtracting and counting direction are early forms of number-space mapping. In this study, an embodiment perspective on these skills was taken. Embodiment theory assumes that cognition emerges through sensory-motor interaction with the environment. In line with this assumption, it was investigated if…

The Precision of Mapping Between Number Words and the Approximate Number System Predicts Children’s Formal Math Abilities

PubMed Central

Libertus, Melissa E.; Odic, Darko; Feigenson, Lisa; Halberda, Justin

2016-01-01

Children can represent number in at least two ways: by using their non-verbal, intuitive Approximate Number System (ANS), and by using words and symbols to count and represent numbers exactly. Further, by the time they are five years old, children can map between the ANS and number words, as evidenced by their ability to verbally estimate numbers of items without counting. How does the quality of the mapping between approximate and exact numbers relate to children’s math abilities? The role of the ANS-number word mapping in math competence remains controversial for at least two reasons. First, previous work has not examined the relation between verbal estimation and distinct subtypes of math abilities. Second, previous work has not addressed how distinct components of verbal estimation – mapping accuracy and variability – might each relate to math performance. Here, we address these gaps by measuring individual differences in ANS precision, verbal number estimation, and formal and informal math abilities in 5- to 7-year-old children. We found that verbal estimation variability, but not estimation accuracy, predicted formal math abilities even when controlling for age, expressive vocabulary, and ANS precision, and that it mediated the link between ANS precision and overall math ability. These findings suggest that variability in the ANS-number word mapping may be especially important for formal math abilities. PMID:27348475

The precision of mapping between number words and the approximate number system predicts children's formal math abilities.

PubMed

Libertus, Melissa E; Odic, Darko; Feigenson, Lisa; Halberda, Justin

2016-10-01

Children can represent number in at least two ways: by using their non-verbal, intuitive approximate number system (ANS) and by using words and symbols to count and represent numbers exactly. Furthermore, by the time they are 5years old, children can map between the ANS and number words, as evidenced by their ability to verbally estimate numbers of items without counting. How does the quality of the mapping between approximate and exact numbers relate to children's math abilities? The role of the ANS-number word mapping in math competence remains controversial for at least two reasons. First, previous work has not examined the relation between verbal estimation and distinct subtypes of math abilities. Second, previous work has not addressed how distinct components of verbal estimation-mapping accuracy and variability-might each relate to math performance. Here, we addressed these gaps by measuring individual differences in ANS precision, verbal number estimation, and formal and informal math abilities in 5- to 7-year-old children. We found that verbal estimation variability, but not estimation accuracy, predicted formal math abilities, even when controlling for age, expressive vocabulary, and ANS precision, and that it mediated the link between ANS precision and overall math ability. These findings suggest that variability in the ANS-number word mapping may be especially important for formal math abilities. Copyright © 2016 Elsevier Inc. All rights reserved.

40 CFR 442.26 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2010 CFR

2010-07-01

... treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior...-treatment of segregated wastewaters (including heels, prerinse/pre-steam wastes, spent cleaning solutions...

40 CFR 442.26 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2011 CFR

2011-07-01

... treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior...-treatment of segregated wastewaters (including heels, prerinse/pre-steam wastes, spent cleaning solutions...

Sodium hydroxide poisoning

MedlinePlus

Sodium hydroxide is a very strong chemical. It is also known as lye and caustic soda. This ... poisoning from touching, breathing in (inhaling), or swallowing sodium hydroxide. This article is for information only. Do ...

The growth of Listeria monocytogenes in cheese packed under a modified atmosphere.

PubMed

Whitley, E; Muir, D; Waites, W M

2000-01-01

The effect of modified atmosphere Packaging (MAP) on the growth of Listeria monocytogenes in mould ripened cheeses was studied at refrigeration temperatures (2-8.3 degrees C) over a storage period of 6 weeks. Control experiments in cling film with no atmospheric modification produced a lag time before growth of up to 1 week and rapid subsequent growth. MAP with a CO2 concentration of less than 20% allowed growth to occur but when O2 was incorporated; the lag time was reduced from 3 to 2 weeks and subsequent growth was also faster, producing an increase in cell numbers of 1.4 log cycles over the incubation period. N2-MAP in the absence of O2 increased the lag time to 3 weeks and slowed growth, while the inclusion of CO2 extended the lag to 3 weeks and slowed subsequent growth even more. In MAP with 80:10:10 (v/v/v) N2:CO2:O2, there was a lag period of 2-3 weeks before growth of L. monocytogenes occurred, while the total viable aerobic count (TVAC) decreased by 2-3 log cycles and the total Lactobacillus count showed little change. It was concluded that MAP was not suitable for preventing the growth of L. monocytogenes in such cheeses.

Investigation of contrast-enhanced subtracted breast CT images with MAP-EM based on projection-based weighting imaging.

PubMed

Zhou, Zhengdong; Guan, Shaolin; Xin, Runchao; Li, Jianbo

2018-06-01

Contrast-enhanced subtracted breast computer tomography (CESBCT) images acquired using energy-resolved photon counting detector can be helpful to enhance the visibility of breast tumors. In such technology, one challenge is the limited number of photons in each energy bin, thereby possibly leading to high noise in separate images from each energy bin, the projection-based weighted image, and the subtracted image. In conventional low-dose CT imaging, iterative image reconstruction provides a superior signal-to-noise compared with the filtered back projection (FBP) algorithm. In this paper, maximum a posteriori expectation maximization (MAP-EM) based on projection-based weighting imaging for reconstruction of CESBCT images acquired using an energy-resolving photon counting detector is proposed, and its performance was investigated in terms of contrast-to-noise ratio (CNR). The simulation study shows that MAP-EM based on projection-based weighting imaging can improve the CNR in CESBCT images by 117.7%-121.2% compared with FBP based on projection-based weighting imaging method. When compared with the energy-integrating imaging that uses the MAP-EM algorithm, projection-based weighting imaging that uses the MAP-EM algorithm can improve the CNR of CESBCT images by 10.5%-13.3%. In conclusion, MAP-EM based on projection-based weighting imaging shows significant improvement the CNR of the CESBCT image compared with FBP based on projection-based weighting imaging, and MAP-EM based on projection-based weighting imaging outperforms MAP-EM based on energy-integrating imaging for CESBCT imaging.

Adsorptive conversion of nitrogen dioxide from etching vent gases over activated carbon.

PubMed

Fang, Mei-Ling; Wu, Ching-Yi; Chou, Ming-Shean

2018-04-13

Some metal etching operations emit limited flow rates of waste gases with reddish-brown NO 2 fume, which may cause visual and acidic-odor complaints, as well as negative health effects. In this study, tests were performed by passing caustic-treated waste gases vented from Al-etching operations through columns packed either with virgin or regenerated granular activated carbon (GAC) to test their adsorptive conversion performance of NO 2 in the gases. The gases contained 5-55 ppm NO 2 and acetic and nitric acids of below 3 ppm. Exhausted carbon was regenerated by scrubbing it with caustic solution and water, and dried for further adsorption tests. Results indicate that with an (empty bed residence time (EBRT) of 0.15 sec for the gas through the GAC-packed space, around 60% of the influent NO 2 of 54 ppm could be removed, and 47% of the removed NO 2 was converted by and desorbed from the carbon as NO. GAC used in the present study could be regenerated at least twice to restore its capacity for NO 2 adsorption. Within EBRTs of 0.076-0.18 sec, the adsorptive conversion capacity was linearly varied with EBRT. In practice, with an EBRT of 0.20 sec, a conversion capacity of 0.80 kg NO 2 (kg GAC) -1 with an influent NO 2 of 40 ppm can be used as a basis for system design. Some metal etching operations emit waste gases with reddish-brown (yellow when diluted) NO 2 fume which may cause visual and acidic-odor complaints, as well as negative health effects. This study provides a simple process for the adsorptive conversion of NO 2 in caustic-treated waste gases vented from metal-etching operations through a GAC column. With an EBRT of 0.20 sec, a conversion capacity of 0.80 kg NO 2 (kg GAC) -1 with an influent NO 2 of 40 ppm can be used as a basis for system design. Saturated GAC can be regenerated at least twice by simply scrubbing it with aqueous caustic solution.

[Conservative treatment of benign esophageal strictures using dilation. Analysis of 500 cases].

PubMed

Andreollo, N A; Lopes, L R; Inogutti, R; Brandalise, N A; Leonardi, L S

2001-01-01

The benign esophageal stenoses (BES) are common complications owing to many etiologies: gastroesophageal reflux, ingestion of corrosive agents, esophageal surgery, radiotherapy, postendoscopic variceal sclerotherapy, drug ingestion, prolonged nasogastric intubation, extrinsic compression and esophageal webs. Esophageal dilatations are worldwide recommended to treat this complication, employing dilators of many types and diameters and facilitating the food ingestion. Evaluation of the results and advantages of the conservative treatment of the BES using esophageal dilatations, in outpatient service of upper digestive endoscopy. During the period from 1981 to 1999, 500 patients with BES were treated and followed up at the Gastrocenter - UNICAMP, in an individually Program of Esophageal Dilatation for each case. The highest number of cases was under ages from 31 to 60 years old (52,8%), and males (59,2%). The most predominant etiologies were: peptic stenosis (30,4%), caustic ingestion (23,6%), anastomosis (23,2%), megaesophagus (8,0%) and prolonged nasogastric ingestion entubation (6,4%), totalizing 91,6% of the BES. Most of patients (94,2%) were submitted to the maximum of 25 dilations. Dilators from 10,5 to 16 mm were employed in 95,6% of the cases. The duration of the treatment was 24 months in 76,2% of the BES. Esophageal perforations occurred in 6 patients (1,2%), without mortality. Were considered excellent, good and bad results, respectively in 76,2%, 18,2% and 5,6% of the cases. On the other hand, excellent results were recorded in 81,0% of the peptic stenosis, 66,1% of the caustic stenosis and 82,7% of the anastomotic stenosis. The conservative treatment failed in 9,3% of the caustic stenosis, 4,3% of the anastomotic stenosis and 3,9% of the peptic stenosis. Thus, the caustic stenosis were unsuccessfull in the highest percentage of unsuccessful. The conservative treatment using guidewire dilators (Savary-Gilliard and Eder-Puestow) is the first choice in the BES, is effective for long time, with short complications and the surgical treatment is indicated only when the dilatations failed.

Modeling Phase-Aligned Gamma-Ray And Radio Millisecond Pulsar Light Curves

DOE PAGES

Venter, C.; Johnson, T. J.; Harding, A. K.

2011-12-12

The gamma-ray population of millisecond pulsars (MSPs) detected by the Fermi Large Area Telescope (LAT) has been steadily increasing. A number of the more recent detections, including PSR J0034-0534, PSR J1939+2134 (B1937+21; the first MSP ever discovered), PSR J1959+2048 (B1957+20; the first black widow system), and PSR J2214+3000, exhibit an unusual phenomenon: nearly phase-aligned radio and gamma- ray light curves (LCs). To account for the phase alignment, we explore geometric models where both the radio and gamma-ray emission originate either in the outer magnetosphere near the light cylinder (R LC) or near the polar caps (PCs). We obtain reasonable fitsmore » for the first three of these MSPs in the context of “altitude- limited” outer gap (alOG) and two-pole caustic (alTPC) geometries. The outer magnetosphere phase-aligned models differ from the standard outer gap (OG) / two-pole caustic (TPC) models in two respects: first, the radio emission originates in caustics at relatively high altitudes compared to the usual low-altitude conal radio beams; second, we allow the maximum altitude of the gamma-ray emission region as well as both the minimum and maximum altitudes of the radio emission region to vary within a limited range. Alternatively, there also exist phase-aligned LC solutions for emission originating near the stellar surface in a slot gap (SG) scenario (“low-altitude slot gap” (laSG) models). We find best-fit LCs using a Markov chain Monte Carlo (MCMC) max- imum likelihood approach [30]. Our fits imply that the phase-aligned LCs are likely of caustic origin, produced in the outer magnetosphere, and that the radio emission may come from close to R LC. We lastly constrain the emission altitudes with typical uncertainties of ~ 0.3RLC. Our results describe a third gamma-ray MSP subclass, in addition to the two (with non-aligned LCs) previously found [50]: those with LCs fit by standard OG / TPC models, and those with LCs fit by pair-starved polar cap (PSPC) models.« less

Discovery and Characterization of a Caustic Crossing Microlensing Event in the Small Magellanic Cloud

NASA Astrophysics Data System (ADS)

Alcock, C.; Allsman, R. A.; Alves, D.; Axelrod, T. S.; Becker, A. C.; Bennett, D. P.; Cook, K. H.; Drake, A. J.; Freeman, K. C.; Griest, K.; King, L. J.; Lehner, M. J.; Marshall, S. L.; Minniti, D.; Peterson, B. A.; Pratt, M. R.; Quinn, P. J.; Rhie, S. H.; Rodgers, A. W.; Stetson, P. B.; Stubbs, C. W.; Sutherland, W.; Tomaney, A.; Vandehei, T.

1999-06-01

We present photometric observations and analysis of the second microlensing event detected toward the Small Magellanic Cloud (SMC), MACHO Alert 98-SMC-1. This event was detected early enough to allow intensive observation of the light curve. These observations revealed 98-SMC-1 to be the first caustic crossing binary microlensing event toward the Magellanic Clouds to be discovered in progress. Frequent coverage of the evolving light curve allowed an accurate prediction for the date of the source crossing out of the lens caustic structure. The caustic crossing temporal width, along with the angular size of the source star, measures the proper motion of the lens with respect to the source and thus allows an estimate of the location of the lens. Lenses located in the Galactic halo would have a velocity projected to the SMC of v̂~1500 kms-1, while an SMC lens would typically have v̂~60 kms-1. The event light curve allows us to obtain a unique fit to the parameters of the binary lens and to estimate the proper motion of the lensing system. We have performed a joint fit to the MACHO/GMAN data presented here, including recent EROS data of this event from Afonso and collaborators. These joint data are sufficient to constrain the time t* for the lens to move an angle equal to the source angular radius: t*=0.116+/-0.010 days. We estimate a radius for the lensed source of R*=1.1+/-0.1 Rsolar from its unblended color and magnitude. This yields a projected velocity of v̂=76+/-10 kms-1. Only 0.12% of halo lenses would be expected to have a v̂ value at least as small as this, while 38% of SMC lenses would be expected to have v̂ as large as this. This implies that the lensing system is more likely to reside in the SMC than in the Galactic halo. Similar observations of future Magellanic Cloud microlensing events will help to determine the contribution of MACHOS to the Galaxy's dark halo.

Assessing double counting of carbon emissions between forest land cover change and forest wildfires: a case study in the United States, 1992-2006

Treesearch

Daolan Zheng; Linda S. Heath; Mark J. Ducey; Brad Quayle

2013-01-01

The relative contributions of double counting of carbon emissions between forest-to-nonforest cover change (FNCC) and forest wildfires are an unknown in estimating net forest carbon exchanges at large scales. This study employed land-cover change maps and forest fire data in the four representative states (Arkansas, California, Minnesota, and Washington) of the US for...

Combined effects of gamma-irradiation and modified atmosphere packaging on quality of some spices.

PubMed

Kirkin, Celale; Mitrevski, Blagoj; Gunes, Gurbuz; Marriott, Philip J

2014-07-01

Thyme (Thymus vidgaris L.), rosemary (Rosmarinus officinalis L.), black pepper (Piper nigrum L.) and cumin (Cuminum cyminum L.) in ground form were packaged in either air or 100% N2 and γ-irradiated at 3 different irradiation levels (7kGy, 12kGy, 17kGy). Total viable bacterial count, yeast and mould count, colour, essential oil yield and essential oil composition were determined. Microbial load was not detectable after 12kGy irradiation of all samples. Irradiation resulted in significant changes in colour values of rosemary and black pepper. The discolouration of the irradiated black pepper was lower in modified atmosphere packaging (MAP) compared to air packaging. Essential oil yield of irradiated black pepper and cumin was lower in air packaging compared to MAP. Gamma-irradiation generally decreased monoterpenes and increased oxygenated compounds, but the effect was lower in MAP. Overall, spices should be irradiated under an O2-free atmosphere to minimise quality deterioration. Copyright © 2014 Elsevier Ltd. All rights reserved.

Where can pixel counting area estimates meet user-defined accuracy requirements?

NASA Astrophysics Data System (ADS)

Waldner, François; Defourny, Pierre

2017-08-01

Pixel counting is probably the most popular way to estimate class areas from satellite-derived maps. It involves determining the number of pixels allocated to a specific thematic class and multiplying it by the pixel area. In the presence of asymmetric classification errors, the pixel counting estimator is biased. The overarching objective of this article is to define the applicability conditions of pixel counting so that the estimates are below a user-defined accuracy target. By reasoning in terms of landscape fragmentation and spatial resolution, the proposed framework decouples the resolution bias and the classifier bias from the overall classification bias. The consequence is that prior to any classification, part of the tolerated bias is already committed due to the choice of the spatial resolution of the imagery. How much classification bias is affordable depends on the joint interaction of spatial resolution and fragmentation. The method was implemented over South Africa for cropland mapping, demonstrating its operational applicability. Particular attention was paid to modeling a realistic sensor's spatial response by explicitly accounting for the effect of its point spread function. The diagnostic capabilities offered by this framework have multiple potential domains of application such as guiding users in their choice of imagery and providing guidelines for space agencies to elaborate the design specifications of future instruments.

Choropleth map legend design for visualizing community health disparities.

PubMed

Cromley, Robert G; Cromley, Ellen K

2009-09-24

Disparities in health outcomes across communities are a central concern in public health and epidemiology. Health disparities research often links differences in health outcomes to other social factors like income. Choropleth maps of health outcome rates show the geographical distribution of health outcomes. This paper illustrates the use of cumulative frequency map legends for visualizing how the health events are distributed in relation to social characteristics of community populations. The approach uses two graphs in the cumulative frequency legend to highlight the difference between the raw count of the health events and the raw count of the social characteristic like low income in the geographical areas of the map. The approach is applied to mapping publicly available data on low birth weight by town in Connecticut and Lyme disease incidence by town in Connecticut in relation to income. The steps involved in creating these legends are described in detail so that health analysts can adopt this approach. The different health problems, low birth weight and Lyme disease, have different cumulative frequency signatures. Graphing poverty population on the cumulative frequency legends revealed that the poverty population is distributed differently with respect to the two different health problems mapped here. Cumulative frequency legends can be useful supplements for choropleth maps. These legends can be constructed using readily available software. They contain all of the information found in standard choropleth map legends, and they can be used with any choropleth map classification scheme. Cumulative frequency legends effectively communicate the proportion of areas, the proportion of health events, and/or the proportion of the denominator population in which the health events occurred that falls within each class interval. They illuminate the context of disease through graphing associations with other variables.

Complete blood count - slideshow

MedlinePlus

... Duplication for commercial use must be authorized in writing by ADAM Health Solutions. About MedlinePlus Site Map FAQs Customer Support Get email updates Subscribe to RSS Follow us Disclaimers Copyright ...

Statistical mapping of count survey data

USGS Publications Warehouse

Royle, J. Andrew; Link, W.A.; Sauer, J.R.; Scott, J. Michael; Heglund, Patricia J.; Morrison, Michael L.; Haufler, Jonathan B.; Wall, William A.

2002-01-01

We apply a Poisson mixed model to the problem of mapping (or predicting) bird relative abundance from counts collected from the North American Breeding Bird Survey (BBS). The model expresses the logarithm of the Poisson mean as a sum of a fixed term (which may depend on habitat variables) and a random effect which accounts for remaining unexplained variation. The random effect is assumed to be spatially correlated, thus providing a more general model than the traditional Poisson regression approach. Consequently, the model is capable of improved prediction when data are autocorrelated. Moreover, formulation of the mapping problem in terms of a statistical model facilitates a wide variety of inference problems which are cumbersome or even impossible using standard methods of mapping. For example, assessment of prediction uncertainty, including the formal comparison of predictions at different locations, or through time, using the model-based prediction variance is straightforward under the Poisson model (not so with many nominally model-free methods). Also, ecologists may generally be interested in quantifying the response of a species to particular habitat covariates or other landscape attributes. Proper accounting for the uncertainty in these estimated effects is crucially dependent on specification of a meaningful statistical model. Finally, the model may be used to aid in sampling design, by modifying the existing sampling plan in a manner which minimizes some variance-based criterion. Model fitting under this model is carried out using a simulation technique known as Markov Chain Monte Carlo. Application of the model is illustrated using Mourning Dove (Zenaida macroura) counts from Pennsylvania BBS routes. We produce both a model-based map depicting relative abundance, and the corresponding map of prediction uncertainty. We briefly address the issue of spatial sampling design under this model. Finally, we close with some discussion of mapping in relation to habitat structure. Although our models were fit in the absence of habitat information, the resulting predictions show a strong inverse relation with a map of forest cover in the state, as expected. Consequently, the results suggest that the correlated random effect in the model is broadly representing ecological variation, and that BBS data may be generally useful for studying bird-habitat relationships, even in the presence of observer errors and other widely recognized deficiencies of the BBS.

X-ray fluorescence camera for imaging of iodine media in vivo.

PubMed

Matsukiyo, Hiroshi; Watanabe, Manabu; Sato, Eiichi; Osawa, Akihiro; Enomoto, Toshiyuki; Nagao, Jiro; Abderyim, Purkhet; Aizawa, Katsuo; Tanaka, Etsuro; Mori, Hidezo; Kawai, Toshiaki; Ehara, Shigeru; Sato, Shigehiro; Ogawa, Akira; Onagawa, Jun

2009-01-01

X-ray fluorescence (XRF) analysis is useful for measuring density distributions of contrast media in vivo. An XRF camera was developed for carrying out mapping for iodine-based contrast media used in medical angiography. Objects are exposed by an X-ray beam from a cerium target. Cerium K-series X-rays are absorbed effectively by iodine media in objects, and iodine fluorescence is produced from the objects. Next, iodine Kalpha fluorescence is selected out by use of a 58-microm-thick stannum filter and is detected by a cadmium telluride (CdTe) detector. The Kalpha rays are discriminated out by a multichannel analyzer, and the number of photons is counted by a counter card. The objects are moved and scanned by an x-y stage in conjunction with a two-stage controller, and X-ray images obtained by iodine mapping are shown on a personal computer monitor. The scan pitch of the x and y axes was 2.5 mm, and the photon counting time per mapping point was 2.0 s. We carried out iodine mapping of non-living animals (phantoms), and iodine Kalpha fluorescence was produced from weakly remaining iodine elements in a rabbit skin cancer.

21 CFR 1230.49 - Penalties.

Code of Federal Regulations, 2013 CFR

2013-04-01

... POISON ACT Imports § 1230.49 Penalties. (a) In case of failure to comply with the instructions or... conditions imposed in order to comply with the provisions of the Federal Caustic Poison Act coming directly...

21 CFR 1230.49 - Penalties.

Code of Federal Regulations, 2012 CFR

2012-04-01

... POISON ACT Imports § 1230.49 Penalties. (a) In case of failure to comply with the instructions or... conditions imposed in order to comply with the provisions of the Federal Caustic Poison Act coming directly...

21 CFR 1230.49 - Penalties.

Code of Federal Regulations, 2010 CFR

2010-04-01

... POISON ACT Imports § 1230.49 Penalties. (a) In case of failure to comply with the instructions or... conditions imposed in order to comply with the provisions of the Federal Caustic Poison Act coming directly...

21 CFR 1230.49 - Penalties.

Code of Federal Regulations, 2014 CFR

2014-04-01

... POISON ACT Imports § 1230.49 Penalties. (a) In case of failure to comply with the instructions or... conditions imposed in order to comply with the provisions of the Federal Caustic Poison Act coming directly...

21 CFR 1230.49 - Penalties.

Code of Federal Regulations, 2011 CFR

2011-04-01

... POISON ACT Imports § 1230.49 Penalties. (a) In case of failure to comply with the instructions or... conditions imposed in order to comply with the provisions of the Federal Caustic Poison Act coming directly...

Mapping the acquisition of the number word sequence in the first year of school

NASA Astrophysics Data System (ADS)

Gould, Peter

2017-03-01

Learning to count and to produce the correct sequence of number words in English is not a simple process. In NSW government schools taking part in Early Action for Success, over 800 students in each of the first 3 years of school were assessed every 5 weeks over the school year to determine the highest correct oral count they could produce. Rather than displaying a steady increase in the accurate sequence of the number words produced, the kindergarten data reported here identified clear, substantial hurdles in the acquisition of the counting sequence. The large-scale, longitudinal data also provided evidence of learning to count through the teens being facilitated by the semi-regular structure of the number words in English. Instead of occurring as hurdles to starting the next counting sequence, number words corresponding to some multiples of ten (10, 20 and 100) acted as if they were rest points. These rest points appear to be artefacts of how the counting sequence is acquired.

Wild bearded capuchins process cashew nuts without contacting caustic compounds.

PubMed

Sirianni, Giulia; Visalberghi, Elisabetta

2013-04-01

Complex and flexible food processing was a key element for the evolutionary success of hominins, enlarging the range of exploitable foods while enabling occupation of new habitats. Only a few primate species crack open encased food by using percussive tools and/or avoid physical contact with irritant compounds by removing the structures containing them. We describe, for the first time, how a population of bearded capuchin monkeys (Sapajus libidinosus) accesses the nutritious kernel of cashew nuts avoiding the caustic chemicals protecting it. Two processing strategies, namely rubbing/piercing and stone tool use, are used according to maturity of the nuts. The frequency of cashew nuts processing increases with capuchin age, and the same set of processing strategies appears to be absent in other capuchin populations, making cashew nuts processing an excellent candidate for social transmission. © 2013 Wiley Periodicals, Inc.

Extraction, scrub, and strip test results for the salt waste processing facility caustic side solvent extraction solvent example

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peters, T. B.

An Extraction, Scrub, and Strip (ESS) test was performed on a sample of Salt Waste Processing Facility (SWPF) Caustic-Side Solvent Extraction (CSSX) solvent and salt simulant to determine cesium distribution ratios (D(Cs)), and cesium concentration in the strip effluent (SE) and decontaminated salt solution (DSS) streams; this data will be used by Parsons to help determine if the solvent is qualified for use at the SWPF. The ESS test showed acceptable performance of the solvent for extraction, scrub, and strip operations. The extraction D(Cs) measured 12.9, exceeding the required value of 8. This value is consistent with results from previousmore » ESS tests using similar solvent formulations. Similarly, scrub and strip cesium distribution ratios fell within acceptable ranges.« less

Bauxite Mining and Alumina Refining

PubMed Central

Frisch, Neale; Olney, David

2014-01-01

Objective: To describe bauxite mining and alumina refining processes and to outline the relevant physical, chemical, biological, ergonomic, and psychosocial health risks. Methods: Review article. Results: The most important risks relate to noise, ergonomics, trauma, and caustic soda splashes of the skin/eyes. Other risks of note relate to fatigue, heat, and solar ultraviolet and for some operations tropical diseases, venomous/dangerous animals, and remote locations. Exposures to bauxite dust, alumina dust, and caustic mist in contemporary best-practice bauxite mining and alumina refining operations have not been demonstrated to be associated with clinically significant decrements in lung function. Exposures to bauxite dust and alumina dust at such operations are also not associated with the incidence of cancer. Conclusions: A range of occupational health risks in bauxite mining and alumina refining require the maintenance of effective control measures. PMID:24806720

Bauxite mining and alumina refining: process description and occupational health risks.

PubMed

Donoghue, A Michael; Frisch, Neale; Olney, David

2014-05-01

To describe bauxite mining and alumina refining processes and to outline the relevant physical, chemical, biological, ergonomic, and psychosocial health risks. Review article. The most important risks relate to noise, ergonomics, trauma, and caustic soda splashes of the skin/eyes. Other risks of note relate to fatigue, heat, and solar ultraviolet and for some operations tropical diseases, venomous/dangerous animals, and remote locations. Exposures to bauxite dust, alumina dust, and caustic mist in contemporary best-practice bauxite mining and alumina refining operations have not been demonstrated to be associated with clinically significant decrements in lung function. Exposures to bauxite dust and alumina dust at such operations are also not associated with the incidence of cancer. A range of occupational health risks in bauxite mining and alumina refining require the maintenance of effective control measures.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wei, Shao-Wen; Liu, Yu-Xiao; Fu, Chun-E

In this paper, we study numerically the quasi-equatorial lensing by the stationary, axially-symmetric black hole in Kerr-Taub-NUT spacetime in the strong field limit. The deflection angle of light ray and other strong deflection limit coefficients are obtained numerically and they are found to be closely dependent on the NUT charge n and spin a. We also compute the magnification and the positions of the relativistic images. The caustics are studied and the results show that these caustics drift away from the optical axis, which is quite different from the Schwarzschild black hole case. Moreover, the intersections of the critical curvesmore » on the equatorial plane are obtained and it is shown that they increase with the NUT charge. These results show that there is a significant effect of the NUT charge on the strong gravitational lensing.« less

Characterization of solids deposited on the modular caustic-side solvent extraction unit (MCU) coalescer media removed in May and October 2014

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fondeur, F. F.

During routine maintenance, the coalescers utilized in the Modular Caustic-Side Solvent Extraction Unit (MCU) processing of Salt Batch 6 and a portion of Salt Batch 7 were sampled and submitted to the Savannah River National Laboratory (SRNL) for characterization, for the purpose of identifying solid phase constituents that may be accumulating in these coalescers. Specifically, two samples were received and characterized: A decontaminated salt solution (DSS) coalescer sample and a strip effluent (SE) coalescer sample. Aliquots of the samples were analyzed by XRD, Fourier Transform Infrared (FTIR) Spectroscopy, SEM, and EDS. Other aliquots of the samples were leached in acidmore » solution, and the leachates were analyzed by ICP-AES. In addition, modeling was performed to provide a basis for comparison of the analytical results.« less

Total gastrectomy due to ferric chloride intoxication.

PubMed

Menéndez, A Mesut; Abramson, Leonardo; Vera, Raúl A; Duza, Guillermo E; Palermo, Mariano

2015-09-01

The ferric chloride intoxication is frequently caused by accident. Its toxicity is generally underrated, which can lead to fatal evolution or irreversible consequences. In this case, the caustic condition of the substance is related to the toxic properties of iron. A 36-year-old male patient arrives by ambulance indicating sensory deterioration. He presents erosive injuries in the buccal cavity and in the oropharynx, brownish teeth and metabolic acidosis. Toxicology tests and ferritin blood dosage are requested, which show a result from 1400 mg/dl. The symptoms are interpreted as acute iron intoxication. Due to the unfavorable evolution of his condition, an abdominal and pelvic CT scan are performed, which show extensive pneumoperitoneum and free fluid in the abdominal cavity. An exploratory laparotomy, a total gastrectomy with esophagostomy and feeding jejunostomy, washing and drainage due to perforated gastric necrosis caused by caustic ingestion are performed. In our country, there is a high rate of intoxication caused by iron compounds, although it is not statistically measured. Nevertheless, the ferric chloride intoxication is extremely infrequent. The ingestion of this product leads to complications, which are associated with the iron concentration and its condition as a caustic agent. The surgical indications in the presence of intoxication caused by iron compounds are: stomach evacuation of iron, gastric necrosis, perforation or peritonitis and stenosis. Early or prophylactic gastrectomy is contraindicated. However, if complications that require immediate surgical intervention arise, there should be no hesitation and the corresponding procedure should be performed.

A drop in the pond: the effect of rapid mass-loss on the dynamics and interaction rate of collisionless particles

NASA Astrophysics Data System (ADS)

Penoyre, Zephyr; Haiman, Zoltán

2018-01-01

In symmetric gravitating systems experiencing rapid mass-loss, particle orbits change almost instantaneously, which can lead to the development of a sharply contoured density profile, including singular caustics for collisionless systems. This framework can be used to model a variety of dynamical systems, such as accretion discs following a massive black hole merger and dwarf galaxies following violent early star formation feedback. Particle interactions in the high-density peaks seem a promising source of observable signatures of these mass-loss events (i.e. a possible EM counterpart for black hole mergers or strong gamma-ray emission from dark matter annihilation around young galaxies), because the interaction rate depends on the square of the density. We study post-mass-loss density profiles, both analytic and numerical, in idealized cases and present arguments and methods to extend to any general system. An analytic derivation is presented for particles on Keplerian orbits responding to a drop in the central mass. We argue that this case, with initially circular orbits, gives the most sharply contoured profile possible. We find that despite the presence of a set of singular caustics, the total particle interaction rate is reduced compared to the unperturbed system; this is a result of the overall expansion of the system dominating over the steep caustics. Finally, we argue that this result holds more generally, and the loss of central mass decreases the particle interaction rate in any physical system.

A SYSTEMATIC ANALYSIS OF CAUSTIC METHODS FOR GALAXY CLUSTER MASSES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gifford, Daniel; Miller, Christopher; Kern, Nicholas

We quantify the expected observed statistical and systematic uncertainties of the escape velocity as a measure of the gravitational potential and total mass of galaxy clusters. We focus our attention on low redshift (z {<=}0.15) clusters, where large and deep spectroscopic datasets currently exist. Utilizing a suite of Millennium Simulation semi-analytic galaxy catalogs, we find that the dynamical mass, as traced by either the virial relation or the escape velocity, is robust to variations in how dynamical friction is applied to ''orphan'' galaxies in the mock catalogs (i.e., those galaxies whose dark matter halos have fallen below the resolution limit).more » We find that the caustic technique recovers the known halo masses (M{sub 200}) with a third less scatter compared to the virial masses. The bias we measure increases quickly as the number of galaxies used decreases. For N{sub gal} > 25, the scatter in the escape velocity mass is dominated by projections along the line-of-sight. Algorithmic uncertainties from the determination of the projected escape velocity profile are negligible. We quantify how target selection based on magnitude, color, and projected radial separation can induce small additional biases into the escape velocity masses. Using N{sub gal} = 150 (25), the caustic technique has a per cluster scatter in ln (M|M{sub 200}) of 0.3 (0.5) and bias 1% {+-} 3{r_brace} (16% {+-} 5{r_brace}) for clusters with masses >10{sup 14} M{sub Sun} at z < 0.15.« less

SCAMP: Rapid Focused Sonic Boom Waypoint Flight Planning Methods, Execution, and Results

NASA Technical Reports Server (NTRS)

Haering, Edward A., Jr.; Cliatt, Larry J., II; Delaney, Michael M., Jr.; Plotkin, Kenneth J.; Maglieri, Domenic J.; Brown, Jacob C.

2012-01-01

Successful execution of the flight phase of the Superboom Caustic Analysis and Measurement Project (SCAMP) required accurate placement of focused sonic booms on an array of prepositioned ground sensors. While the array was spread over a 10,000-ft-long area, this is a relatively small region when considering the speed of a supersonic aircraft and sonic boom ray path variability due to shifting atmospheric conditions and aircraft trajectories. Another requirement of the project was to determine the proper position for a microphone-equipped motorized glider to intercept the sonic boom caustic, adding critical timing to the constraints. Variability in several inputs to these calculations caused some shifts of the focus away from the optimal location. Reports of the sonic booms heard by persons positioned amongst the array were used to shift the focus closer to the optimal location for subsequent passes. This paper describes the methods and computations used to place the focused sonic boom on the SCAMP array and gives recommendations for their accurate placement by future quiet supersonic aircraft. For the SCAMP flights, 67% of the foci were placed on the ground array with measured positions within a few thousand feet of computed positions. Among those foci with large caustic elevation angles, 96% of foci were placed on the array, and measured positions were within a few hundred feet of computed positions. The motorized glider captured sonic booms on 59% of the passes when the instrumentation was operating properly.

Dark Matter under the Microscope: Constraining Compact Dark Matter with Caustic Crossing Events

NASA Astrophysics Data System (ADS)

Diego, Jose M.; Kaiser, Nick; Broadhurst, Tom; Kelly, Patrick L.; Rodney, Steve; Morishita, Takahiro; Oguri, Masamune; Ross, Timothy W.; Zitrin, Adi; Jauzac, Mathilde; Richard, Johan; Williams, Liliya; Vega-Ferrero, Jesus; Frye, Brenda; Filippenko, Alexei V.

2018-04-01

A galaxy cluster acts as a cosmic telescope over background galaxies but also as a cosmic microscope magnifying the imperfections of the lens. The diverging magnification of lensing caustics enhances the microlensing effect of substructure present within the lensing mass. Fine-scale structure can be accessed as a moving background source brightens and disappears when crossing these caustics. The recent discovery of a distant lensed star near the Einstein radius of the galaxy cluster MACSJ1149.5+2223 allows a rare opportunity to reach subsolar-mass microlensing through a supercritical column of cluster matter. Here we compare these observations with high-resolution ray-tracing simulations that include stellar microlensing set by the observed intracluster starlight and also primordial black holes that may be responsible for the recently observed LIGO events. We explore different scenarios with microlenses from the intracluster medium and black holes, including primordial ones, and examine strategies to exploit these unique alignments. We find that the best constraints on the fraction of compact dark matter (DM) in the small-mass regime can be obtained in regions of the cluster where the intracluster medium plays a negligible role. This new lensing phenomenon should be widespread and can be detected within modest-redshift lensed galaxies so that the luminosity distance is not prohibitive for detecting individual magnified stars. High-cadence Hubble Space Telescope monitoring of several such optimal arcs will be rewarded by an unprecedented mass spectrum of compact objects that can contribute to uncovering the nature of DM.

Binary Microlensing Events from the MACHO Project

NASA Astrophysics Data System (ADS)

Alcock, C.; Allsman, R. A.; Alves, D.; Axelrod, T. S.; Baines, D.; Becker, A. C.; Bennett, D. P.; Bourke, A.; Brakel, A.; Cook, K. H.; Crook, B.; Crouch, A.; Dan, J.; Drake, A. J.; Fragile, P. C.; Freeman, K. C.; Gal-Yam, A.; Geha, M.; Gray, J.; Griest, K.; Gurtierrez, A.; Heller, A.; Howard, J.; Johnson, B. R.; Kaspi, S.; Keane, M.; Kovo, O.; Leach, C.; Leach, T.; Leibowitz, E. M.; Lehner, M. J.; Lipkin, Y.; Maoz, D.; Marshall, S. L.; McDowell, D.; McKeown, S.; Mendelson, H.; Messenger, B.; Minniti, D.; Nelson, C.; Peterson, B. A.; Popowski, P.; Pozza, E.; Purcell, P.; Pratt, M. R.; Quinn, J.; Quinn, P. J.; Rhie, S. H.; Rodgers, A. W.; Salmon, A.; Shemmer, O.; Stetson, P.; Stubbs, C. W.; Sutherland, W.; Thomson, S.; Tomaney, A.; Vandehei, T.; Walker, A.; Ward, K.; Wyper, G.

2000-09-01

We present the light curves of 21 gravitational microlensing events from the first six years of the MACHO Project gravitational microlensing survey that are likely examples of lensing by binary systems. These events were manually selected from a total sample of ~350 candidate microlensing events that were either detected by the MACHO Alert System or discovered through retrospective analyses of the MACHO database. At least 14 of these 21 events exhibit strong (caustic) features, and four of the events are well fit with lensing by large mass ratio (brown dwarf or planetary) systems, although these fits are not necessarily unique. The total binary event rate is roughly consistent with predictions based upon our knowledge of the properties of binary stars, but a precise comparison cannot be made without a determination of our binary lens event detection efficiency. Toward the Galactic bulge, we find a ratio of caustic crossing to noncaustic crossing binary lensing events of 12:4, excluding one event for which we present two fits. This suggests significant incompleteness in our ability to detect and characterize noncaustic crossing binary lensing. The distribution of mass ratios, N(q), for these binary lenses appears relatively flat. We are also able to reliably measure source-face crossing times in four of the bulge caustic crossing events, and recover from them a distribution of lens proper motions, masses, and distances consistent with a population of Galactic bulge lenses at a distance of 7+/-1 kpc. This analysis yields two systems with companions of ~0.05 Msolar.

A redshift survey of the strong-lensing cluster ABELL 383

DOE Office of Scientific and Technical Information (OSTI.GOV)

Geller, Margaret J.; Hwang, Ho Seong; Kurtz, Michael J.

2014-03-01

Abell 383 is a famous rich cluster (z = 0.1887) imaged extensively as a basis for intensive strong- and weak-lensing studies. Nonetheless, there are few spectroscopic observations. We enable dynamical analyses by measuring 2360 new redshifts for galaxies with r {sub Petro} ≤ 20.5 and within 50' of the Brightest Cluster Galaxy (BCG; R.A.{sub 2000} = 42.°014125, decl.{sub 2000} = –03.°529228). We apply the caustic technique to identify 275 cluster members within 7 h {sup –1} Mpc of the hierarchical cluster center. The BCG lies within –11 ± 110 km s{sup –1} and 21 ± 56 h {sup –1} kpcmore » of the hierarchical cluster center; the velocity dispersion profile of the BCG appears to be an extension of the velocity dispersion profile based on cluster members. The distribution of cluster members on the sky corresponds impressively with the weak-lensing contours of Okabe et al. especially when the impact of foreground and background structure is included. The values of R {sub 200} = 1.22 ± 0.01 h {sup –1} Mpc and M {sub 200} = (5.07 ± 0.09) × 10{sup 14} h {sup –1} M {sub ☉} obtained by application of the caustic technique agree well with recent completely independent lensing measures. The caustic estimate extends direct measurement of the cluster mass profile to a radius of ∼5 h {sup –1} Mpc.« less

A Method for Counting Moving People in Video Surveillance Videos

NASA Astrophysics Data System (ADS)

Conte, Donatello; Foggia, Pasquale; Percannella, Gennaro; Tufano, Francesco; Vento, Mario

2010-12-01

People counting is an important problem in video surveillance applications. This problem has been faced either by trying to detect people in the scene and then counting them or by establishing a mapping between some scene feature and the number of people (avoiding the complex detection problem). This paper presents a novel method, following this second approach, that is based on the use of SURF features and of an [InlineEquation not available: see fulltext.]-SVR regressor provide an estimate of this count. The algorithm takes specifically into account problems due to partial occlusions and to perspective. In the experimental evaluation, the proposed method has been compared with the algorithm by Albiol et al., winner of the PETS 2009 contest on people counting, using the same PETS 2009 database. The provided results confirm that the proposed method yields an improved accuracy, while retaining the robustness of Albiol's algorithm.

How well do we know the polar hydrogen distribution on the Moon?

NASA Astrophysics Data System (ADS)

Teodoro, L. F. A.; Eke, V. R.; Elphic, R. C.; Feldman, W. C.; Lawrence, D. J.

2014-03-01

A detailed comparison is made of results from the Lunar Prospector Neutron Spectrometer (LPNS) and the Lunar Exploration Neutron Detector Collimated Sensors for Epithermal Neutrons (LEND CSETN). Using the autocorrelation function and power spectrum of the polar count rate maps produced by these experiments, it is shown that the LEND CSETN has a footprint that is at least as big as would be expected for an omnidirectional detector at an orbital altitude of 50 km. The collimated flux into the field of view of the collimator is negligible. A dip in the count rate in Shoemaker crater is found to be consistent with being a statistical fluctuation superimposed on a significant, larger-scale decrease in the count rate, providing no evidence for high spatial resolution of the LEND CSETN. The maps of lunar polar hydrogen with the highest contrast, i.e., spatial resolution, are those resulting from pixon image reconstructions of the LPNS data. These typically provide weight percentages of water-equivalent hydrogen that are accurate to 30% within the polar craters.

Remodeling census population with spatial information from Landsat TM imagery

USGS Publications Warehouse

Yuan, Y.; Smith, R.M.; Limp, W.F.

1997-01-01

In geographic information systems (GIS) studies there has been some difficulty integrating socioeconomic and physiogeographic data. One important type of socioeconomic data, census data, offers a wide range of socioeconomic information, but is aggregated within arbitrary enumeration districts (EDs). Values reflect either raw counts or, when standardized, the mean densities in the EDs. On the other hand, remote sensing imagery, an important type of physiogeographic data, provides large quantities of information with more spatial details than census data. Based on the dasymetric mapping principle, this study applies multivariable regression to examine the correlation between population counts from census and land cover types. The land cover map is classified from LandSat TM imagery. The correlation is high. Census population counts are remodeled to a GIS raster layer based on the discovered correlations coupled with scaling techniques, which offset influences from other than land cover types. The GIS raster layer depicts the population distribution with much more spatial detail than census data offer. The resulting GIS raster layer is ready to be analyzed or integrated with other GIS data. ?? 1998 Elsevier Science Ltd. All rights reserved.

Mars: Stratigraphy of Western Highlands and Polar Regions

NASA Technical Reports Server (NTRS)

Tanaka, K. L.; Scott, D. H.; Tuesink, M. F.

1985-01-01

Geologic mapping and stratigraphic studies of Mars based on Viking images improved knowledge of the relative age and occurrence of geologic units on a global scale. Densities of geologic units or features during the Noarchian, Hesperian, and Amazonian periods are indicated for the North and South polar regions as well as the equatorial region of Mars. Cumulative counts of crater size frequencies for craters larger than 2 km in diameter on plateau units mapped in the western region of Mars counts indicate that the plateau terrain as a whole was thinly resurfaced during the Hesperian Period, and a large proportion of pre-existing craters less than 10 to 15 km in diameter was buried. The formation of northern plains, subpolar highlands, and both polar regions is also described.

Preschool children use space, rather than counting, to infer the numerical magnitude of digits: Evidence for a spatial mapping principle.

PubMed

Sella, Francesco; Berteletti, Ilaria; Lucangeli, Daniela; Zorzi, Marco

2017-01-01

A milestone in numerical development is the acquisition of counting principles which allow children to exactly determine the numerosity of a given set. Moreover, a canonical left-to-right spatial layout for representing numbers also emerges during preschool. These foundational aspects of numerical competence have been extensively studied, but there is sparse knowledge about the interplay between the acquisition of the cardinality principle and spatial mapping of numbers in early numerical development. The present study investigated how these skills concurrently develop before formal schooling. Preschool children were classified according to their performance in Give-a-Number and Number-to-position tasks. Experiment 1 revealed three qualitatively different groups: (i) children who did not master the cardinality principle and lacked any consistent spatial mapping for digits, (ii) children who mastered the cardinality principle and yet failed in spatial mapping, and (iii) children who mastered the cardinality principle and displayed consistent spatial mapping. This suggests that mastery of the cardinality principle does not entail the emergence of spatial mapping. Experiment 2 confirmed the presence of these three developmental stages and investigated their relation with a digit comparison task. Crucially, only children who displayed a consistent spatial mapping of numbers showed the ability to compare digits by numerical magnitude. A congruent (i.e., numerically ordered) positioning of numbers onto a visual line as well as the concept that moving rightwards (in Western cultures) conveys an increase in numerical magnitude mark the mastery of a spatial mapping principle. Children seem to rely on this spatial organization to achieve a full understanding of the magnitude relations between digits. Copyright © 2016 Elsevier B.V. All rights reserved.

21 CFR 1230.14 - Directions for treatment.

Code of Federal Regulations, 2011 CFR

2011-04-01

... FEDERAL CAUSTIC POISON ACT Labeling § 1230.14 Directions for treatment. Except as provided in § 1230.16... word “Poison,” directions for treatment in the case of internal personal injury; in addition, if the...

21 CFR 1230.14 - Directions for treatment.

Code of Federal Regulations, 2014 CFR

2014-04-01

... FEDERAL CAUSTIC POISON ACT Labeling § 1230.14 Directions for treatment. Except as provided in § 1230.16... word “Poison,” directions for treatment in the case of internal personal injury; in addition, if the...

21 CFR 1230.14 - Directions for treatment.

Code of Federal Regulations, 2012 CFR

2012-04-01

... FEDERAL CAUSTIC POISON ACT Labeling § 1230.14 Directions for treatment. Except as provided in § 1230.16... word “Poison,” directions for treatment in the case of internal personal injury; in addition, if the...

21 CFR 1230.14 - Directions for treatment.

Code of Federal Regulations, 2013 CFR

2013-04-01

... FEDERAL CAUSTIC POISON ACT Labeling § 1230.14 Directions for treatment. Except as provided in § 1230.16... word “Poison,” directions for treatment in the case of internal personal injury; in addition, if the...

40 CFR 63.8184 - What parts of my plant does this subpart cover?

Code of Federal Regulations, 2010 CFR

2010-07-01

... in the manufacture of product chlorine, product caustic, and by-product hydrogen at a plant site. This subpart covers mercury emissions from by-product hydrogen streams, end box ventilation system...

Farm Mapping to Assist, Protect, and Prepare Emergency Responders: Farm MAPPER.

PubMed

Reyes, Iris; Rollins, Tami; Mahnke, Andrea; Kadolph, Christopher; Minor, Gerald; Keifer, Matthew

2014-01-01

Responders such as firefighters and emergency medical technicians who respond to farm emergencies often face complex and unknown environments. They may encounter hazards such as fuels, solvents, pesticides, caustics, and exploding gas storage cylinders. Responders may be unaware of dirt roads within the farm that can expedite their arrival at critical sites or snow-covered manure pits that act as hidden hazards. A response to a farm, unless guided by someone familiar with the operation, may present a risk to responders and post a challenge in locating the victim. This project explored the use of a Web-based farm-mapping application optimized for tablets and accessible via easily accessible on-site matrix barcodes, or quick response codes (QR codes), to provide emergency responders with hazard and resource information to agricultural operations. Secured portals were developed for both farmers and responders, allowing both parties to populate and customize farm maps with icons. Data were stored online and linked to QR codes attached to mailbox posts where emergency responders may read them with a mobile device. Mock responses were conducted on dairy farms to test QR code linking efficacy, Web site security, and field usability. Findings from farmer usability tests showed willingness to enter data as well as ease of Web site navigation and data entry even with farmers who had limited computer knowledge. Usability tests with emergency responders showed ease of QR code connectivity to the farm maps and ease of Web site navigation. Further research is needed to improve data security as well as assess the program's applicability to nonfarm environments and integration with existing emergency response systems. The next phases of this project will expand the program for regional and national use, develop QR code-linked, Web-based extrication guidance for farm machinery for victim entrapment rescue, and create QR code-linked online training videos and materials for limited English proficient immigrant farm workers.

Scanning Defect Mapping | Photovoltaic Research | NREL

Science.gov Websites

SDMS moves the treated wafer across a stationary laser beam and maps the defects for each location on the wafer. The amount of light reflected from an area is proportional to the dislocation density for that area and provides a direct statistical count of the number of dislocations. PV Research Other

The Gaussian Plasma Lens in Astrophysics: Refraction

NASA Astrophysics Data System (ADS)

Clegg, Andrew W.; Fey, Alan L.; Lazio, T. Joseph W.

1998-03-01

We present the geometrical optics for refraction of a distant background radio source by an interstellar plasma lens, with specific application to a lens with a Gaussian profile of free-electron column density. The refractive properties of the lens are specified completely by a dimensionless parameter α, which is a function of the wavelength of observation, the free-electron column density through the lens, the lens-observer distance, and the diameter of the lens transverse to the line of sight. A lens passing between the observer and a background source, due to the relative motions of the observer, lens, and source, produces modulations in the light curve of the background source. Because plasma lenses are diverging, the light curve displays a minimum in the background source's flux density, formed when the lens is on-axis, surrounded by enhancements above the nominal (unlensed) flux density. The exact form of the light curve depends only upon the parameter α and the relative angular sizes of the source and lens as seen by the observer. Other effects due to lensing include the following: (1) the formation of caustic surfaces, upon which the apparent brightness of the background source becomes very large; (2) the possible creation of multiple images of the background source; and (3) angular position wander of the background source. If caustics are formed, the separation of the outer caustics can be used to constrain α, while the separation of the inner caustics can constrain the size of the lens. We apply our analysis to two sources, which have undergone extreme scattering events: (1) 0954+658, a source for which we can identify multiple caustics in its light curve, and (2) 1741-038, for which polarization observations were obtained during and after the scattering event. We find general agreement between modeled and observed light curves at 2.25 GHz, but poor agreement at 8.1 GHz. The discrepancies between the modeled and observed light curves may result from some combination of substructure within the lens, an anisotropic lens shape, a lens which only grazes the source rather than passing completely over it, or unresolved substructure within the extragalactic sources. Our analysis also allows us to place constraints on the physical characteristics of the lens. The inferred properties of the lens responsible for the scattering event toward 0954+658 (1741-038) are that it was 0.38 AU (0.065 AU) in diameter with a peak column density of 0.24 pc cm-3 (10-4 pc cm-3), an electron density within the lens of 105 cm-3 (300 cm-3), and a mass of 6.5 × 10-14 M⊙ (10-18 M⊙). The angular position wander caused by the lens was 250 mas (0.4 mas) at 2.25 GHz. In the case of 1741-038, we can place an upper limit of only 100 mG on the magnetic field within the lens.

Entire Sky

NASA Image and Video Library

1999-12-01

Aitoff projection of the three-color composite JHKs source count map of the entire sky, based on 95,851,173 stars with Ks 13.5. What appears most prominently are the Galactic plane and the Galactic bulge.

Chemical milling solution produces smooth surface finish on aluminum

NASA Technical Reports Server (NTRS)

Lorenzen, H. C.

1966-01-01

Elementary sulfur mixed into a solution of caustic soda and salts produces an etchant which will chemically mill end-grain surfaces on aluminum plate. This composition results in the least amount of thickness variation and pitting.

2. EAST AND NORTH SIDES OF BUILDING 254. VIEW TO ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. EAST AND NORTH SIDES OF BUILDING 254. VIEW TO SOUTHWEST. - Rocky Mountain Arsenal, Caustic Fusion Building, 450 feet South of December Seventh Avenue; 900 feet West of D Street, Commerce City, Adams County, CO

1. SOUTH AND WEST SIDES OF BUILDING 254. VIEW TO ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. SOUTH AND WEST SIDES OF BUILDING 254. VIEW TO NORTHEAST. - Rocky Mountain Arsenal, Caustic Fusion Building, 450 feet South of December Seventh Avenue; 900 feet West of D Street, Commerce City, Adams County, CO

21 CFR 1230.13 - Labeling of “poison”.

Code of Federal Regulations, 2013 CFR

2013-04-01

... FEDERAL CAUSTIC POISON ACT Labeling § 1230.13 Labeling of “poison”. The following are styles of...-point size are required on a label in stating the word “poison” they must not be smaller than those...

21 CFR 1230.13 - Labeling of “poison”.

Code of Federal Regulations, 2012 CFR

2012-04-01

... FEDERAL CAUSTIC POISON ACT Labeling § 1230.13 Labeling of “poison”. The following are styles of...-point size are required on a label in stating the word “poison” they must not be smaller than those...

21 CFR 1230.13 - Labeling of “poison”.

Code of Federal Regulations, 2014 CFR

2014-04-01

... FEDERAL CAUSTIC POISON ACT Labeling § 1230.13 Labeling of “poison”. The following are styles of...-point size are required on a label in stating the word “poison” they must not be smaller than those...

21 CFR 1230.13 - Labeling of “poison”.

Code of Federal Regulations, 2011 CFR

2011-04-01

... FEDERAL CAUSTIC POISON ACT Labeling § 1230.13 Labeling of “poison”. The following are styles of...-point size are required on a label in stating the word “poison” they must not be smaller than those...

21 CFR 1230.13 - Labeling of “poison”.

Code of Federal Regulations, 2010 CFR

2010-04-01

... FEDERAL CAUSTIC POISON ACT Labeling § 1230.13 Labeling of “poison”. The following are styles of...-point size are required on a label in stating the word “poison” they must not be smaller than those...

PEP Run Report for Integrated Test A, Caustic Leaching in UFP-VSL-T01A, Oxidative Leaching in UFP-VSL-T02A

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guzman-Leong, Consuelo E.; Bredt, Ofelia P.; Burns, Carolyn A.

2009-12-04

Pacific Northwest National Laboratory (PNNL) was tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed and constructed and operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes.”(a) The PEP, located in the Process Engineering Laboratory-West (PDLW) located in Richland, Washington, is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes.more » The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing.« less

Quantum caustics in resonance-fluorescence trajectories

NASA Astrophysics Data System (ADS)

Naghiloo, M.; Tan, D.; Harrington, P. M.; Lewalle, P.; Jordan, A. N.; Murch, K. W.

2017-11-01

We employ phase-sensitive amplification to perform homodyne detection of the resonance fluorescence from a driven superconducting artificial atom. Entanglement between the emitter and its fluorescence allows us to track the individual quantum state trajectories of the emitter conditioned on the outcomes of the field measurements. We analyze the ensemble properties of these trajectories by considering trajectories that connect specific initial and final states. By applying the stochastic path-integral formalism, we calculate equations of motion for the most-likely path between two quantum states and compare these predicted paths to experimental data. Drawing on the mathematical similarity between the action formalism of the most-likely quantum paths and ray optics, we study the emergence of caustics in quantum trajectories: places where multiple extrema in the stochastic action occur. We observe such multiple most-likely paths in experimental data and find these paths to be in reasonable quantitative agreement with theoretical calculations.

Foreign bodies and caustic lesions.

PubMed

Dray, Xavier; Cattan, Pierre

2013-10-01

Foreign body ingestions, food bolus impactions, and caustic agent injuries are frequent but specific situations. Although most foreign bodies will naturally pass through the digestive tract, practitioners should recognize specific situations were endoscopic management is required. In such cases, timing and adequate equipment are critical. Endoscopic treatment is successful in about 95% of patients. Severe complications (including oesophageal perforations) are rare. Underlying diseases (including eosinophilic oesophagitis) must be investigated after food bolus impaction. Accidental or suicidal ingestion of corrosive agents may result in severe upper gastrointestinal tract injuries requiring a multidisciplinary approach including gastroenterologists, surgeons, otorhynolaryngologists, anaesthesiologists and psychiatrists. Treatment includes conservative management of patients with mild injuries, while patients with severe injuries undergo emergency surgical exploration. At distance of the ingestion episode, oesophageal reconstruction is required in patients who underwent oesophageal resection and in patients who developed oesophageal strictures that failed dilatation. Copyright © 2013. Published by Elsevier Ltd.

Current-horn suppression for reduced coherent-synchrotron-radiation-induced emittance growth in strong bunch compression

NASA Astrophysics Data System (ADS)

Charles, T. K.; Paganin, D. M.; Latina, A.; Boland, M. J.; Dowd, R. T.

2017-03-01

Control of coherent synchrotron radiation (CSR)-induced emittance growth is essential in linear accelerators designed to deliver very high brightness electron beams. Extreme current values at the head and tail of the electron bunch, resulting from strong bunch compression, are responsible for large CSR production leading to significant transverse projected emittance growth. The Linac Coherent Light Source (LCLS) truncates the head and tail current spikes which greatly improves free electron laser (FEL) performance. Here we consider the underlying dynamics that lead to formation of current spikes (also referred to as current horns), which has been identified as caustics forming in electron trajectories. We present a method to analytically determine conditions required to avoid the caustic formation and therefore prevent the current spikes from forming. These required conditions can be easily met, without increasing the transverse slice emittance, through inclusion of an octupole magnet in the middle of a bunch compressor.

Endoscopic mucosal autograft for treating esophageal caustic strictures: preliminary human experience.

PubMed

He, Kexin; Zhao, Lili; Bu, Shoushan; Liu, Li; Wang, Xiang; Wang, Min; Fan, Zhining

2018-06-11

 Esophageal caustic stricture is a stubborn disease and postoperative restenosis limits the clinical efficacy of endoscopic dilation. Autologous mucosal grafts have been successfully applied in the treatment of urethral stricture and in the prevention of stricture after extensive mucosal resection. We aimed to use mucosal autografting performed endoscopically to treat refractory esophageal stricture. METHODS : Three patients with intractable corrosive esophageal stricture were treated endoscopically by combining dilation with autologous mucosal transplantation. RESULTS : All procedures were successful with no severe complications. Mucosal regeneration was shown at the transplanted segments. One patient was able to maintain a normal diet with complete remission after 1 year of follow-up. Intraluminal stenosis and dysphagia were significantly improved in another two patients. CONCLUSIONS : Mucosal autografting can achieve esophageal re-epithelialization, inhibit undesired fibrosis, prevent restenosis, and promote functional regeneration. © Georg Thieme Verlag KG Stuttgart · New York.

Aluminum Target Dissolution in Support of the Pu-238 Program

DOE Office of Scientific and Technical Information (OSTI.GOV)

McFarlane, Joanna; Benker, Dennis; DePaoli, David W

2014-09-01

Selection of an aluminum alloy for target cladding affects post-irradiation target dissolution and separations. Recent tests with aluminum alloy 6061 yielded greater than expected precipitation in the caustic dissolution step, forming up to 10 wt.% solids of aluminum hydroxides and aluminosilicates. We present a study to maximize dissolution of aluminum metal alloy, along with silicon, magnesium, and copper impurities, through control of temperature, the rate of reagent addition, and incubation time. Aluminum phase transformations have been identified as a function of time and temperature, using X-ray diffraction. Solutions have been analyzed using wet chemical methods and X-ray fluorescence. These datamore » have been compared with published calculations of aluminum phase diagrams. Temperature logging during the transients has been investigated as a means to generate kinetic and mass transport data on the dissolution process. Approaches are given to enhance the dissolution of aluminum and aluminosilicate phases in caustic solution.« less

Washing and caustic leaching of Hanford tank sludges: results of FY 1996 studies. Revision

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lumetta, G.J.; Rapko, B.M.; Wagner, M.J.

During the past few years, the primary mission at the US Department of Energy`s Hanford Site has changed from producing plutonium to restoring the environment. Large volumes of high-level radioactive wastes (HLW), generated during past Pu production and other operations, are stored in underground tanks on site. The current plan for remediating the Hanford tank farms consists of waste retrieval, pretreatment, treatment (immobilization), and disposal. The HLW will be immobilized in a borosilicate glass matrix and then disposed of in a geologic repository. Because of the expected high cost of HLW vitrification and geologic disposal, pretreatment processes will be implementedmore » to reduce the volume of borosilicate glass produced in disposing of the tank wastes. On this basis, a pretreatment plan is being developed. This report describes the sludge washing and caustic leaching test conducted to create a Hanford tank sludge pretreatment flowsheet.« less

Biological treatment of toxic petroleum spent caustic in fluidized bed bioreactor using immobilized cells of Thiobacillus RAI01.

PubMed

Potumarthi, Ravichandra; Mugeraya, Gopal; Jetty, Annapurna

2008-12-01

In the present studies, newly isolated Thiobacillus sp was used for the treatment of synthetic spent sulfide caustic in a laboratory-scale fluidized bed bioreactor. The sulfide oxidation was tested using Ca-alginate immobilized Thiobacillus sp. Initially, response surface methodology was applied for the optimization of four parameters to check the sulfide oxidation efficiency in batch mode. Further, reactor was operated in continuous mode for 51 days at different sulfide loading rates and retention times to test the sulfide oxidation and sulfate and thiosulfate formation. Sulfide conversions in the range of 90-98% were obtained at almost all sulfide loading rates and hydraulic retention times. However, increased loading rates resulted in lower sulfide oxidation capacity. All the experiments were conducted at constant pH of around 6 and temperature of 30 +/- 5 degrees C.

[Skin burns, necrosis and ulcers caused by wet cement, ready-mixed concrete and lime. 8 cases].

PubMed

Koch, P

1996-01-01

Skin burns and caustic ulcers caused by wet cement, due to calcium hydroxyde, are rarely reported in the literature. They occur mostly among amateur cement users. We report seven cases of skin burns, necrosis and ulcerations after use of wet cement and ready-mixed concrete, and one case of caustic ulcers induced by wet lime. Even short skin contacts to wet cement or concrete may induce extensive lesions in some cases. However, we were not able to incriminate with certainty any special concrete additives which could increase skin penetration of calcium hydroxyde. Warning notices about the danger of skin contact should be prominent on sacked cement. When ready-mixed concrete is delivered, the purchaser should be handed a note explaining the risk of kneeling in wet concrete and the importance of protective measures. This may probably contribute to reduce the frequency of those accidents.

Resonant inelastic soft x-ray scattering of CdS: a two-dimensional electronic structure map approach

DOE Office of Scientific and Technical Information (OSTI.GOV)

Weinhardt, L.; Fuchs, O.; Fleszar, A.

2008-09-24

Resonant inelastic x-ray scattering (RIXS) with soft x-rays is uniquely suited to study the elec-tronic structure of a variety of materials, but is currently limited by low (fluorescence yield) count rates. This limitation is overcome with a new high-transmission spectrometer that allows to measure soft x-ray RIXS"maps." The S L2,3 RIXS map of CdS is discussed and compared with density functional calculations. The map allows the extraction of decay channel-specific"absorp-tion spectra," giving detailed insight into the wave functions of occupied and unoccupied elec-tronic states.

Simulating the component counts of combinatorial structures.

PubMed

Arratia, Richard; Barbour, A D; Ewens, W J; Tavaré, Simon

2018-02-09

This article describes and compares methods for simulating the component counts of random logarithmic combinatorial structures such as permutations and mappings. We exploit the Feller coupling for simulating permutations to provide a very fast method for simulating logarithmic assemblies more generally. For logarithmic multisets and selections, this approach is replaced by an acceptance/rejection method based on a particular conditioning relationship that represents the distribution of the combinatorial structure as that of independent random variables conditioned on a weighted sum. We show how to improve its acceptance rate. We illustrate the method by estimating the probability that a random mapping has no repeated component sizes, and establish the asymptotic distribution of the difference between the number of components and the number of distinct component sizes for a very general class of logarithmic structures. Copyright © 2018. Published by Elsevier Inc.

Constraining the geometry and kinematics of the quasar broad emission line region using gravitational microlensing. I. Models and simulations

NASA Astrophysics Data System (ADS)

Braibant, L.; Hutsemékers, D.; Sluse, D.; Goosmann, R.

2017-11-01

Recent studies have shown that line profile distortions are commonly observed in gravitationally lensed quasar spectra. Often attributed to microlensing differential magnification, line profile distortions can provide information on the geometry and kinematics of the broad emission line region (BLR) in quasars. We investigate the effect of gravitational microlensing on quasar broad emission line profiles and their underlying continuum, combining the emission from simple representative BLR models with generic microlensing magnification maps. Specifically, we considered Keplerian disk, polar, and equatorial wind BLR models of various sizes. The effect of microlensing has been quantified with four observables: μBLR, the total magnification of the broad emission line; μcont, the magnification of the underlying continuum; as well as red/blue, RBI and wings/core, WCI, indices that characterize the line profile distortions. The simulations showed that distortions of line profiles, such as those recently observed in lensed quasars, can indeed be reproduced and attributed to the differential effect of microlensing on spatially separated regions of the BLR. While the magnification of the emission line μBLR sets an upper limit on the BLR size and, similarly, the magnification of the continuum μcont sets an upper limit on the size of the continuum source, the line profile distortions mainly depend on the BLR geometry and kinematics. We thus built (WCI,RBI) diagrams that can serve as diagnostic diagrams to discriminate between the various BLR models on the basis of quantitative measurements. It appears that a strong microlensing effect puts important constraints on the size of the BLR and on its distance to the high-magnification caustic. In that case, BLR models with different geometries and kinematics are more prone to produce distinctive line profile distortions for a limited number of caustic configurations, which facilitates their discrimination. When the microlensing effect is weak, there is a larger overlap between the characteristics of the line profile distortions produced by the different models, and constraints can only be derived on a statistical basis.

Chemical Quantification of Atomic-Scale EDS Maps under Thin Specimen Conditions

DOE PAGES

Lu, Ping; Romero, Eric; Lee, Shinbuhm; ...

2014-10-13

We report our effort to quantify atomic-scale chemical maps obtained by collecting energy-dispersive X-ray spectra (EDS) using scanning transmission electron microscopy (STEM) (STEM-EDS). Under a thin specimen condition and when the EDS scattering potential is localized, the X-ray counts from atomic columns can be properly counted by fitting Gaussian peaks at the atomic columns, and can then be used for site-by-site chemical quantification. The effects of specimen thickness and X-ray energy on the Gaussian peak-width are investigated by using SrTiO 3 (STO) as a model specimen. The relationship between the peak-width and spatial-resolution of an EDS map is also studied.more » Furthermore, the method developed by this work is applied to study a Sm-doped STO thin film and antiphase boundaries present within the STO film. We find that Sm atoms occupy both Sr and Ti sites but preferably the Sr sites, and Sm atoms are relatively depleted at the antiphase boundaries likely due to the effect of strain.« less

A simulator for airborne laser swath mapping via photon counting

NASA Astrophysics Data System (ADS)

Slatton, K. C.; Carter, W. E.; Shrestha, R.

2005-06-01

Commercially marketed airborne laser swath mapping (ALSM) instruments currently use laser rangers with sufficient energy per pulse to work with return signals of thousands of photons per shot. The resulting high signal to noise level virtually eliminates spurious range values caused by noise, such as background solar radiation and sensor thermal noise. However, the high signal level approach requires laser repetition rates of hundreds of thousands of pulses per second to obtain contiguous coverage of the terrain at sub-meter spatial resolution, and with currently available technology, affords little scalability for significantly downsizing the hardware, or reducing the costs. A photon-counting ALSM sensor has been designed by the University of Florida and Sigma Space, Inc. for improved topographic mapping with lower power requirements and weight than traditional ALSM sensors. Major elements of the sensor design are presented along with preliminary simulation results. The simulator is being developed so that data phenomenology and target detection potential can be investigated before the system is completed. Early simulations suggest that precise estimates of terrain elevation and target detection will be possible with the sensor design.

Exploratory studies on some electrochemical cell systems

NASA Astrophysics Data System (ADS)

Chaudhuri, Srikumar; Guha, D.

Exploratory studies were conducted on cell systems with different metal anodes, and iodine and sulphur mixed with graphite powder in a polymer matrix as cathodes, using different electrolytes in non-aqueous and aqueous media as ionic charge carriers. The electrical conductance of the electrolyte solutions in aqueous and non-aqueous solvents, the open circuit voltage (OCV) and short circuit current (SCC) for the different cell systems were measured. To date, the non-aqueous solvents used in our studies were dimethylformamide, formamide, dioxan, and nitrobenzene, and the electrolytes used were potassium iodide, caustic potash, cetyltrimethylammonium bromide (CTAB), sodium lauryl sulphate (SLS) and calcium chloride. These electrolytes were used in both non-aqueous and aqueous media. In general, aqueous electrolyte solutions gave a better performance than non-aqueous electrolyte solutions. Of the aqueous electrolytes, the highest conductance was shown by potassium chloride solution in water (conductance=0.0334 mho). However, the best OCV and SCC were shown by aluminium as anode and iodine as cathode with a saturated solution of caustic potash in water. The OCV was 1.85 V and the SCC was 290 mA cm -2. The highest conductance among the non-aqueous systems was shown by caustic potash in formamide. (Conductance=0.013 mho.) The best OCV and SCC, however, were shown by a zinc anode and iodine cathode with saturated potassium chloride in formamide, having an OCV of 1.55 V and an SCC of 150 mA cm -2. Further studies are in progress to obtain detailed performance data and recharging characteristics of some of the more promising systems reported here.

Wet air oxidation of cresylic spent caustic - A model compound study over graphene oxide (GO) and ruthenium/GO catalysts.

PubMed

Barge, Aditti S; Vaidya, Prakash D

2018-04-15

Wet air oxidation (WAO) is a candidate technique for the effective treatment of spent caustic wastewater. In this work, cresols were chosen as model compounds to represent cresylic spent caustic wash. Graphene oxide (GO) is a promising catalyst as well as support for the wet oxidation process, due to its unique structure and properties. For the first time, GO and ruthenium supported on graphene oxide (Ru/GO) were employed for WAO of cresylic isomers. The aforesaid materials were synthesized by modified Hummer's method and characterized using scanning electron microscopy (SEM), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD) and Brunauer-Emmett-Teller (BET) analysis. The performance of the investigated materials for WAO of cresols was studied in a slurry reactor. The best reaction conditions for GO were 175 °C and 0.69 MPa O 2 pressure. Total organic carbon (TOC) degradation achieved at these conditions was 54.9, 48.9 and 61.2% for o-cresol, m-cresol and p-cresol, respectively. The amount of TOC degradation obtained by using Ru/GO at the same reaction conditions was 66.4, 53.4 and 73.9% for o-cresol, m-cresol and p-cresol, respectively. It was found that the order of reactivity for cresols was p-cresol > o-cresol > m-cresol. Finally, kinetics of TOC destruction during CWAO of p-cresol over GO was described using a two-step power law model. Copyright © 2018 Elsevier Ltd. All rights reserved.

Response to comment on "Hydrogen mapping of the lunar South Pole using the LRO neutron detector experiment LEND".

PubMed

Mitrofanov, I G; Boynton, W V; Litvak, M L; Sanin, A B; Starr, R D

2011-11-25

Critical comments from Lawrence et al. are considered on the capability of the collimated neutron telescope Lunar Exploration Neutron Detector (LEND) on NASA's Lunar Reconnaissance Orbiter (LRO) for mapping lunar epithermal neutrons, as presented in our paper. We present two different analyses to show that our previous estimated count rates are valid and support the conclusions of that paper.

Inverting ion images without Abel inversion: maximum entropy reconstruction of velocity maps.

PubMed

Dick, Bernhard

2014-01-14

A new method for the reconstruction of velocity maps from ion images is presented, which is based on the maximum entropy concept. In contrast to other methods used for Abel inversion the new method never applies an inversion or smoothing to the data. Instead, it iteratively finds the map which is the most likely cause for the observed data, using the correct likelihood criterion for data sampled from a Poissonian distribution. The entropy criterion minimizes the information content in this map, which hence contains no information for which there is no evidence in the data. Two implementations are proposed, and their performance is demonstrated with simulated and experimental data: Maximum Entropy Velocity Image Reconstruction (MEVIR) obtains a two-dimensional slice through the velocity distribution and can be compared directly to Abel inversion. Maximum Entropy Velocity Legendre Reconstruction (MEVELER) finds one-dimensional distribution functions Q(l)(v) in an expansion of the velocity distribution in Legendre polynomials P((cos θ) for the angular dependence. Both MEVIR and MEVELER can be used for the analysis of ion images with intensities as low as 0.01 counts per pixel, with MEVELER performing significantly better than MEVIR for images with low intensity. Both methods perform better than pBASEX, in particular for images with less than one average count per pixel.

A Matter of Distance: Rachel DeWoskin Remembers Kenneth Koch.

ERIC Educational Resources Information Center

DeWoskin, Rachel

2002-01-01

Eulogizes poet and teacher Kenneth Koch. Notes that Koch was a renowned poet, a pioneer of the poets-in-the-school movement, and mentor to generations of Columbia students. Describes his often caustic teaching style. (PM)

Decreasing incidence of cutaneous chemical burns in a resource limited burn centre: is this a positive effect of modernization?

PubMed

Nnabuko, R E E; Okoye, C P; Ogbonnaya, I S; Isiwele, Egi

2017-01-01

Burns present a devastating injury to patients. Burns caused by chemical agents, present a worse scenario. In a resource limited country like Nigeria, readily available sources of these corrosive agents are mainly from lead-acid battery vendors and to some extent local small scale soap manufacturers who use caustic soda. We hypothesized that with the reduction in small scale soap manufacturing and increasing trend towards modernization in the use of dry cell batteries, chemical burns may be on the decline, and we sought to investigate this. The records of all acute burn patients seen at the Burns and Plastic Department of the National Orthopaedic Hospital Enugu Nigeria between January 2011 and December 2014 were retrospectively reviewed. The results were compared to similar studies carried out at the same centre. A questionnaire was administered to corrosive chemical (sulphuric and caustic soda) vendors to assess the trends in product sales and use in recent times. A total of 624 acute burn cases were treated during the period; among which, 12 cases (1.9%) were chemical burns. When compared with previous studies at the centre, Chemical burn cases were  recorded as the lowest rate. The median age of patients was 24 years. There were eight males and four females. Interpersonal assault was the commonest mechanism of injury with sulphuric acid suspected to be the commonest agent in 83.3% of the cases, while 16.7% of the cases were from accidental use of caustic soda. The head and neck as well as the upper limbs were the most affected (30%). Twenty-six questionnaires to lead-acid vendors were analyzed and revealed that all respondents noticed a marked downward trend in the sale of either sulphuric acid or caustic soda, and they attributed this to the ready availability of imported alternatives to locally manufactured soap or wet lead-acid batteries. Ease of use, durability and convenience of the dry cell batteries were cited as principal reasons. There appears to be a downward trend in the prevalence of chemical burns in our study compared to previous studies in the centre which may be due to reduced availability and access of corrosive chemicals to the general public. Further prospective multicentre studies to confirm this are recommended.

Developing Process Maps as a Tool for a Surgical Infection Prevention Quality Improvement Initiative in Resource-Constrained Settings.

PubMed

Forrester, Jared A; Koritsanszky, Luca A; Amenu, Demisew; Haynes, Alex B; Berry, William R; Alemu, Seifu; Jiru, Fekadu; Weiser, Thomas G

2018-06-01

Surgical infections cause substantial morbidity and mortality in low-and middle-income countries (LMICs). To improve adherence to critical perioperative infection prevention standards, we developed Clean Cut, a checklist-based quality improvement program to improve compliance with best practices. We hypothesized that process mapping infection prevention activities can help clinicians identify strategies for improving surgical safety. We introduced Clean Cut at a tertiary hospital in Ethiopia. Infection prevention standards included skin antisepsis, ensuring a sterile field, instrument decontamination/sterilization, prophylactic antibiotic administration, routine swab/gauze counting, and use of a surgical safety checklist. Processes were mapped by a visiting surgical fellow and local operating theater staff to facilitate the development of contextually relevant solutions; processes were reassessed for improvements. Process mapping helped identify barriers to using alcohol-based hand solution due to skin irritation, inconsistent administration of prophylactic antibiotics due to variable delivery outside of the operating theater, inefficiencies in assuring sterility of surgical instruments through lack of confirmatory measures, and occurrences of retained surgical items through inappropriate guidelines, staffing, and training in proper routine gauze counting. Compliance with most processes improved significantly following organizational changes to align tasks with specific process goals. Enumerating the steps involved in surgical infection prevention using a process mapping technique helped identify opportunities for improving adherence and plotting contextually relevant solutions, resulting in superior compliance with antiseptic standards. Simplifying these process maps into an adaptable tool could be a powerful strategy for improving safe surgery delivery in LMICs. Copyright © 2018 American College of Surgeons. Published by Elsevier Inc. All rights reserved.

Variations in neutrophil count in preterm infants with respiratory distress syndrome who subsequently developed chronic lung disease.

PubMed

Kohelet, D; Arbel, E; Ballin, A; Goldberg, M

2000-01-01

Neutrophil counts were studied in 62 preterm infants receiving mechanical ventilation for neonatal respiratory distress syndrome (NRDS). Exploratory analysis indicated that the severity of NRDS, as demonstrated by fractional inspired oxygen (FiO2), mean airway pressure (MAP), arterial-alveolar PO2 ratio (a/APO2) and oxygenation index (OI), was correlated with percentage change of neutrophil counts during the first 5 days of life. Further analysis demonstrated that infants with NRDS who subsequently developed chronic lung disease (CLD) (n = 21) had statistically significant differences in variation of neutrophil counts when compared with the remainder (n = 41) without CLD (-35.0% +/- 4.3 vs. -16.9% +/- 5.8, p < 0.02). It is concluded that significant variations in neutrophil counts during the first 5 days of life may be found in infants with NRDS who subsequently develop CLD and that these changes may have predictive value regarding the development of CLD.

Mapping species abundance by a spatial zero-inflated Poisson model: a case study in the Wadden Sea, the Netherlands.

PubMed

Lyashevska, Olga; Brus, Dick J; van der Meer, Jaap

2016-01-01

The objective of the study was to provide a general procedure for mapping species abundance when data are zero-inflated and spatially correlated counts. The bivalve species Macoma balthica was observed on a 500×500 m grid in the Dutch part of the Wadden Sea. In total, 66% of the 3451 counts were zeros. A zero-inflated Poisson mixture model was used to relate counts to environmental covariates. Two models were considered, one with relatively fewer covariates (model "small") than the other (model "large"). The models contained two processes: a Bernoulli (species prevalence) and a Poisson (species intensity, when the Bernoulli process predicts presence). The model was used to make predictions for sites where only environmental data are available. Predicted prevalences and intensities show that the model "small" predicts lower mean prevalence and higher mean intensity, than the model "large". Yet, the product of prevalence and intensity, which might be called the unconditional intensity, is very similar. Cross-validation showed that the model "small" performed slightly better, but the difference was small. The proposed methodology might be generally applicable, but is computer intensive.

Experimental results of use of triple-energy X-ray beam with K-edge filter in multi-energy imaging

NASA Astrophysics Data System (ADS)

Kim, D.; Lee, S.; Jeon, P.-H.

2016-04-01

Multi-energy imaging is useful for contrast enhancement of lesions, quantitative analysis of specific materials and material separation in the human body. Generally, dual-energy methods are applied to discriminating two materials, but this method cannot discriminate more than two materials. Photon-counting detectors provide spectral information from polyenergetic X-rays using multiple energy bins. In this work, we developed triple-energy X-ray beams using a filter with K-edge energy and applied them experimentally. The energy spectra of triple-energy X-ray beams were assessed by using a spectrometer. The designed triple-energy X-ray beams were validated by measuring quantitative evaluations with mean energy ratio (MER), contrast variation ratio (CVR) and exposure efficiency (EE). Then, triple-energy X-ray beams were used to extract density map of three materials, iodine (I), aluminum (Al) and polymethyl methacrylate (PMMA). The results of the thickness density maps obtained with the developed triple-energy X-ray beams were compared to those acquired using the photon-counting method. As a result, it was found experimentally that the proposed triple-energy X-ray beam technique can separate the three materials as well as the photon-counting method.

Chlor-Alkali Technology.

ERIC Educational Resources Information Center

Venkatesh, S.; Tilak, B. V.

1983-01-01

Chlor-alkali technology is one of the largest electrochemical industries in the world, the main products being chlorine and caustic soda (sodium hydroxide) generated simultaneously by the electrolysis of sodium chloride. This technology is reviewed in terms of electrochemical principles and manufacturing processes involved. (Author/JN)

40 CFR 63.9035 - How do I monitor and collect data to demonstrate continuous compliance?

Code of Federal Regulations, 2012 CFR

2012-07-01

... caustic scrubber or a water scrubber/absorber to meet the emission limits in Table 1 to this subpart, you... (including, as applicable, calibration checks and required zero and span adjustments), you must monitor...

40 CFR 63.9035 - How do I monitor and collect data to demonstrate continuous compliance?

Code of Federal Regulations, 2014 CFR

2014-07-01

... caustic scrubber or a water scrubber/absorber to meet the emission limits in Table 1 to this subpart, you... (including, as applicable, calibration checks and required zero and span adjustments), you must monitor...

40 CFR 63.9035 - How do I monitor and collect data to demonstrate continuous compliance?

Code of Federal Regulations, 2013 CFR

2013-07-01

... caustic scrubber or a water scrubber/absorber to meet the emission limits in Table 1 to this subpart, you... (including, as applicable, calibration checks and required zero and span adjustments), you must monitor...

Acoustic emission data assisted process monitoring.

PubMed

Yen, Gary G; Lu, Haiming

2002-07-01

Gas-liquid two-phase flows are widely used in the chemical industry. Accurate measurements of flow parameters, such as flow regimes, are the key of operating efficiency. Due to the interface complexity of a two-phase flow, it is very difficult to monitor and distinguish flow regimes on-line and real time. In this paper we propose a cost-effective and computation-efficient acoustic emission (AE) detection system combined with artificial neural network technology to recognize four major patterns in an air-water vertical two-phase flow column. Several crucial AE parameters are explored and validated, and we found that the density of acoustic emission events and ring-down counts are two excellent indicators for the flow pattern recognition problems. Instead of the traditional Fair map, a hit-count map is developed and a multilayer Perceptron neural network is designed as a decision maker to describe an approximate transmission stage of a given two-phase flow system.

Predicting fecal indicator organism contamination in Oregon coastal streams.

PubMed

Pettus, Paul; Foster, Eugene; Pan, Yangdong

2015-12-01

In this study, we used publicly available GIS layers and statistical tree-based modeling (CART and Random Forest) to predict pathogen indicator counts at a regional scale using 88 spatially explicit landscape predictors and 6657 samples from non-estuarine streams in the Oregon Coast Range. A total of 532 frequently sampled sites were parsed down to 93 pathogen sampling sites to control for spatial and temporal biases. This model's 56.5% explanation of variance, was comparable to other regional models, while still including a large number of variables. Analysis showed the most important predictors on bacteria counts to be: forest and natural riparian zones, cattle related activities, and urban land uses. This research confirmed linkages to anthropogenic activities, with the research prediction mapping showing increased bacteria counts in agricultural and urban land use areas and lower counts with more natural riparian conditions. Copyright © 2015 Elsevier Ltd. All rights reserved.

An Automated Statistical Technique for Counting Distinct Multiple Sclerosis Lesions.

PubMed

Dworkin, J D; Linn, K A; Oguz, I; Fleishman, G M; Bakshi, R; Nair, G; Calabresi, P A; Henry, R G; Oh, J; Papinutto, N; Pelletier, D; Rooney, W; Stern, W; Sicotte, N L; Reich, D S; Shinohara, R T

2018-04-01

Lesion load is a common biomarker in multiple sclerosis, yet it has historically shown modest association with clinical outcome. Lesion count, which encapsulates the natural history of lesion formation and is thought to provide complementary information, is difficult to assess in patients with confluent (ie, spatially overlapping) lesions. We introduce a statistical technique for cross-sectionally counting pathologically distinct lesions. MR imaging was used to assess the probability of a lesion at each location. The texture of this map was quantified using a novel technique, and clusters resembling the center of a lesion were counted. Validity compared with a criterion standard count was demonstrated in 60 subjects observed longitudinally, and reliability was determined using 14 scans of a clinically stable subject acquired at 7 sites. The proposed count and the criterion standard count were highly correlated ( r = 0.97, P < .001) and not significantly different (t 59 = -.83, P = .41), and the variability of the proposed count across repeat scans was equivalent to that of lesion load. After accounting for lesion load and age, lesion count was negatively associated ( t 58 = -2.73, P < .01) with the Expanded Disability Status Scale. Average lesion size had a higher association with the Expanded Disability Status Scale ( r = 0.35, P < .01) than lesion load ( r = 0.10, P = .44) or lesion count ( r = -.12, P = .36) alone. This study introduces a novel technique for counting pathologically distinct lesions using cross-sectional data and demonstrates its ability to recover obscured longitudinal information. The proposed count allows more accurate estimation of lesion size, which correlated more closely with disability scores than either lesion load or lesion count alone. © 2018 by American Journal of Neuroradiology.

The SCUBA-2 Cosmology Legacy Survey: 850 μm maps, catalogues and number counts

NASA Astrophysics Data System (ADS)

Geach, J. E.; Dunlop, J. S.; Halpern, M.; Smail, Ian; van der Werf, P.; Alexander, D. M.; Almaini, O.; Aretxaga, I.; Arumugam, V.; Asboth, V.; Banerji, M.; Beanlands, J.; Best, P. N.; Blain, A. W.; Birkinshaw, M.; Chapin, E. L.; Chapman, S. C.; Chen, C.-C.; Chrysostomou, A.; Clarke, C.; Clements, D. L.; Conselice, C.; Coppin, K. E. K.; Cowley, W. I.; Danielson, A. L. R.; Eales, S.; Edge, A. C.; Farrah, D.; Gibb, A.; Harrison, C. M.; Hine, N. K.; Hughes, D.; Ivison, R. J.; Jarvis, M.; Jenness, T.; Jones, S. F.; Karim, A.; Koprowski, M.; Knudsen, K. K.; Lacey, C. G.; Mackenzie, T.; Marsden, G.; McAlpine, K.; McMahon, R.; Meijerink, R.; Michałowski, M. J.; Oliver, S. J.; Page, M. J.; Peacock, J. A.; Rigopoulou, D.; Robson, E. I.; Roseboom, I.; Rotermund, K.; Scott, Douglas; Serjeant, S.; Simpson, C.; Simpson, J. M.; Smith, D. J. B.; Spaans, M.; Stanley, F.; Stevens, J. A.; Swinbank, A. M.; Targett, T.; Thomson, A. P.; Valiante, E.; Wake, D. A.; Webb, T. M. A.; Willott, C.; Zavala, J. A.; Zemcov, M.

2017-02-01

We present a catalogue of ˜3000 submillimetre sources detected (≥3.5σ) at 850 μm over ˜5 deg2 surveyed as part of the James Clerk Maxwell Telescope (JCMT) SCUBA-2 Cosmology Legacy Survey (S2CLS). This is the largest survey of its kind at 850 μm, increasing the sample size of 850 μm selected submillimetre galaxies by an order of magnitude. The wide 850 μm survey component of S2CLS covers the extragalactic fields: UKIDSS-UDS, COSMOS, Akari-NEP, Extended Groth Strip, Lockman Hole North, SSA22 and GOODS-North. The average 1σ depth of S2CLS is 1.2 mJy beam-1, approaching the SCUBA-2 850 μm confusion limit, which we determine to be σc ≈ 0.8 mJy beam-1. We measure the 850 μm number counts, reducing the Poisson errors on the differential counts to approximately 4 per cent at S850 ≈ 3 mJy. With several independent fields, we investigate field-to-field variance, finding that the number counts on 0.5°-1° scales are generally within 50 per cent of the S2CLS mean for S850 > 3 mJy, with scatter consistent with the Poisson and estimated cosmic variance uncertainties, although there is a marginal (2σ) density enhancement in GOODS-North. The observed counts are in reasonable agreement with recent phenomenological and semi-analytic models, although determining the shape of the faint-end slope (S850 < 3 mJy) remains a key test. The large solid angle of S2CLS allows us to measure the bright-end counts: at S850 > 10 mJy there are approximately 10 sources per square degree, and we detect the distinctive up-turn in the number counts indicative of the detection of local sources of 850 μm emission, and strongly lensed high-redshift galaxies. All calibrated maps and the catalogue are made publicly available.

CO2 Sparging Work Plan, LCP Chemicals

EPA Pesticide Factsheets

April 24, 2013 plan prepared by Mutch Associates, LLC for implementation of full-scale CO2 sparging of the subsurface caustic brine pool (CBP) at the LCP Chemicals site in Brunswick, Georgia. Region ID: 04 DocID: 10941341, DocDate: 04-24-2013

CATALYTIC ENZYME-BASED METHODS FOR WATER TREATMENT AND WATER DISTRIBUTION SYSTEM DECONTAMINATION

EPA Science Inventory

Current chemistry-based decontaminants for chemical or biological warfare agents and related toxic materials are caustic and have the potential for causing material and environmental damage. In addition, most are bulk liquids that require significant logistics and storage capabil...

Hazardous Waste Cleanup: Olin Corporation in Niagara Falls, New York

EPA Pesticide Factsheets

The Olin Niagara Falls Plant (the Plant), comprised of two separate lots, is located south of Buffalo Avenue in Niagara Falls, approximately 1,000 feet north of the Upper Niagara River. Historically, Olin produced chlorine and caustic soda from rock salt

40 CFR 442.15 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2011 CFR

2011-07-01

... be incompatible with treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior presolve washes, interior detergent washes, interior acid washes, and exterior... effective pre-treatment of segregated wastewaters (including heels, prerinse/pre-steam wastes, spent...

40 CFR 442.16 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2010 CFR

2010-07-01

... be incompatible with treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior presolve washes, interior detergent washes, interior acid washes, and exterior... effective pre-treatment of segregated wastewaters (including heels, prerinse/pre-steam wastes, spent...

40 CFR 442.25 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2010 CFR

2010-07-01

... be incompatible with treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior presolve washes, interior detergent washes, interior acid washes, and exterior... effective pre-treatment of segregated wastewaters (including heels, prerinse/pre-steam wastes, spent...

40 CFR 442.16 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2014 CFR

2014-07-01

... be incompatible with treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior presolve washes, interior detergent washes, interior acid washes, and exterior... effective pre-treatment of segregated wastewaters (including heels, prerinse/pre-steam wastes, spent...

40 CFR 442.15 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2010 CFR

2010-07-01

... be incompatible with treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior presolve washes, interior detergent washes, interior acid washes, and exterior... effective pre-treatment of segregated wastewaters (including heels, prerinse/pre-steam wastes, spent...

40 CFR 442.16 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2012 CFR

2012-07-01

... be incompatible with treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior presolve washes, interior detergent washes, interior acid washes, and exterior... effective pre-treatment of segregated wastewaters (including heels, prerinse/pre-steam wastes, spent...

40 CFR 442.26 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2012 CFR

2012-07-01

... be incompatible with treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior presolve washes, interior detergent washes, interior acid washes, and exterior... effective pre-treatment of segregated wastewaters (including heels, prerinse/pre-steam wastes, spent...

40 CFR 442.16 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2011 CFR

2011-07-01

... be incompatible with treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior presolve washes, interior detergent washes, interior acid washes, and exterior... effective pre-treatment of segregated wastewaters (including heels, prerinse/pre-steam wastes, spent...

40 CFR 442.16 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2013 CFR

2013-07-01

... be incompatible with treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior presolve washes, interior detergent washes, interior acid washes, and exterior... effective pre-treatment of segregated wastewaters (including heels, prerinse/pre-steam wastes, spent...

40 CFR 442.25 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2011 CFR

2011-07-01

... be incompatible with treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior presolve washes, interior detergent washes, interior acid washes, and exterior... effective pre-treatment of segregated wastewaters (including heels, prerinse/pre-steam wastes, spent...

40 CFR 442.26 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2013 CFR

2013-07-01

... be incompatible with treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior presolve washes, interior detergent washes, interior acid washes, and exterior... effective pre-treatment of segregated wastewaters (including heels, prerinse/pre-steam wastes, spent...

40 CFR 442.26 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2014 CFR

2014-07-01

... be incompatible with treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior presolve washes, interior detergent washes, interior acid washes, and exterior... effective pre-treatment of segregated wastewaters (including heels, prerinse/pre-steam wastes, spent...

Deep 1.1mm-wavelength imaging of the GOODS-S field by AzTEC/ASTE - I. Source catalogue and number counts

NASA Astrophysics Data System (ADS)

Scott, K. S.; Yun, M. S.; Wilson, G. W.; Austermann, J. E.; Aguilar, E.; Aretxaga, I.; Ezawa, H.; Ferrusca, D.; Hatsukade, B.; Hughes, D. H.; Iono, D.; Giavalisco, M.; Kawabe, R.; Kohno, K.; Mauskopf, P. D.; Oshima, T.; Perera, T. A.; Rand, J.; Tamura, Y.; Tosaki, T.; Velazquez, M.; Williams, C. C.; Zeballos, M.

2010-07-01

We present the first results from a confusion-limited map of the Great Observatories Origins Deep Survey-South (GOODS-S) taken with the AzTEC camera on the Atacama Submillimeter Telescope Experiment. We imaged a field to a 1σ depth of 0.48-0.73 mJybeam-1, making this one of the deepest blank-field surveys at mm-wavelengths ever achieved. Although by traditional standards our GOODS-S map is extremely confused due to a sea of faint underlying sources, we demonstrate through simulations that our source identification and number counts analyses are robust, and the techniques discussed in this paper are relevant for other deeply confused surveys. We find a total of 41 dusty starburst galaxies with signal-to-noise ratios S/N >= 3. 5 within this uniformly covered region, where only two are expected to be false detections, and an additional seven robust source candidates located in the noisier (1σ ~ 1 mJybeam-1) outer region of the map. We derive the 1.1 mm number counts from this field using two different methods: a fluctuation or ``P(d)'' analysis and a semi-Bayesian technique and find that both methods give consistent results. Our data are well fit by a Schechter function model with . Given the depth of this survey, we put the first tight constraints on the 1.1 mm number counts at S1.1mm = 0.5 mJy, and we find evidence that the faint end of the number counts at from various SCUBA surveys towards lensing clusters are biased high. In contrast to the 870μm survey of this field with the LABOCA camera, we find no apparent underdensity of sources compared to previous surveys at 1.1mm the estimates of the number counts of SMGs at flux densities >1mJy determined here are consistent with those measured from the AzTEC/SHADES survey. Additionally, we find a significant number of SMGs not identified in the LABOCA catalogue. We find that in contrast to observations at λ <= 500μm, MIPS 24μm sources do not resolve the total energy density in the cosmic infrared background at 1.1 mm, demonstrating that a population of z >~ 3 dust-obscured galaxies that are unaccounted for at these shorter wavelengths potentially contribute to a large fraction (~2/3) of the infrared background at 1.1 mm.

Spatial representation and cognitive modulation of response variability in the lateral intraparietal area priority map.

PubMed

Falkner, Annegret L; Goldberg, Michael E; Krishna, B Suresh

2013-10-09

The lateral intraparietal area (LIP) in the macaque contains a priority-based representation of the visual scene. We previously showed that the mean spike rate of LIP neurons is strongly influenced by spatially wide-ranging surround suppression in a manner that effectively sharpens the priority map. Reducing response variability can also improve the precision of LIP's priority map. We show that when a monkey plans a visually guided delayed saccade with an intervening distractor, variability (measured by the Fano factor) decreases both for neurons representing the saccade goal and for neurons representing the broad spatial surround. The reduction in Fano factor is maximal for neurons representing the saccade goal and steadily decreases for neurons representing more distant locations. LIP Fano factor changes are behaviorally significant: increasing expected reward leads to lower variability for the LIP representation of both the target and distractor locations, and trials with shorter latency saccades are associated with lower Fano factors in neurons representing the surround. Thus, the LIP Fano factor reflects both stimulus and behavioral engagement. Quantitative modeling shows that the interaction between mean spike count and target-receptive field (RF) distance in the surround during the predistractor epoch is multiplicative: the Fano factor increases more steeply with mean spike count further away from the RF. A negative-binomial model for LIP spike counts captures these findings quantitatively, suggests underlying mechanisms based on trial-by-trial variations in mean spike rate or burst-firing patterns, and potentially provides a principled framework to account simultaneously for the previously observed unsystematic relationships between spike rate and variability in different brain areas.

First Self-Consistent, Two-Layer Model of Near-Surface Water-Equivalent-Hydrogen on Mars

NASA Astrophysics Data System (ADS)

Feldman, W. C.; Pathare, A.; Prettyman, T. H.; Maurice, S.

2015-12-01

This study uses 9.5 years of Mars Odyssey Neutron Spectrometer (MONS) data [1]. We have used the epithermal and fast neutron count rates to determine the water-equivalent-hydrogen (WEH) content of an upper layer, Wup, having thickness D. The "crossover" technique we utilized is an improvement over previous work [2,3]. We then used Monte Carlo simulated grids of epithermal and thermal count rates spanning Wup = 1% to 15% [4] to determine the WEH content, Wdn, of a semi-infinite lower layer buried at depth, D. We also advance upon previous work by using improved deconvolution methods to reduce spatial blurring in fast and epithermal maps [5]. The resultant count-rates were digitized into a 2°x2°cylindrical grid for all WEH computations. Two sets of WEH maps will be shown. The first uses the one-layer model developed initially by Feldman et al. [6]. Comparison of the undeconvolved and deconvolved versions clearly illustrates the improvement obtained by deconvolution. We will also present the full two layer maps of Wup, Wdn, and D for the deconvolved data sets, which show: 1) contrary to our previous preliminary mapping [3], the fresh icy mid-latitude craters identified by [7] are NOT exclusively found in regions with average Wdn values that exceed the pore-filling threshold for regolith ice; 2) a maximum Wdn of about 80% by weight at the Phoenix site; 3) an isolated Wdn maximum just east of Gale crater that is centered on Aeolis Mensae; 4) a resolved Wdn maximum that overlays the Orsen Wells crater on Xanthe Terra; 5) Wdn local maxima that hug the western flanks of Olympus Mons and Elysium Mons, and 6) several Wdn maxima that cover Arabia Terra. We will present and interpret regional maps of all of these features. Refs: [1] Maurice et al. JGR, 2011; [2] Feldman et al. JGR, 2011; [3] Pathare et al. 8th Mars Conf., 2014; [4] Prettyman et al. JGR, 2004 [5] Prettyman et al. JGR, 2009; [6] Feldman et al. JGR, 2004; [7] Dundas et al. JGR, 2014.

Optimized tomography of continuous variable systems using excitation counting

NASA Astrophysics Data System (ADS)

Shen, Chao; Heeres, Reinier W.; Reinhold, Philip; Jiang, Luyao; Liu, Yi-Kai; Schoelkopf, Robert J.; Jiang, Liang

2016-11-01

We propose a systematic procedure to optimize quantum state tomography protocols for continuous variable systems based on excitation counting preceded by a displacement operation. Compared with conventional tomography based on Husimi or Wigner function measurement, the excitation counting approach can significantly reduce the number of measurement settings. We investigate both informational completeness and robustness, and provide a bound of reconstruction error involving the condition number of the sensing map. We also identify the measurement settings that optimize this error bound, and demonstrate that the improved reconstruction robustness can lead to an order-of-magnitude reduction of estimation error with given resources. This optimization procedure is general and can incorporate prior information of the unknown state to further simplify the protocol.

[Ingestion of caustic substances: An analysis of the safety and benefit of a less aggressive protocol].

PubMed

Ripoll Trujillo, Noelia; Martínez Sánchez, Lidia; Habimana Jordana, Anna; Trenchs Sainz de La Maza, Victoria; Vila Miravet, Víctor; Luaces Cubells, Carles

2018-04-14

The ingestion of a caustic agent is the most common cause of admission after being in contact with a domestic product. A group of patients could be considered low risk and not require aggressive procedures such a corticosteroid administration and endoscopy, especially in the paediatric population. To evaluate the safety and benefit of a less aggressive protocol for patients defined as low risk. An analytical-observational study conducted on patients who consulted for caustic ingestion between January 2011 and December 2015. Two periods were differentiated according to the current protocol. Period-1: usual protocol (which included admission and parenteral corticosteroid and antibiotic administration) and Period-2: less aggressive protocol for the low risk patients (oral intake test after 6hours and discharged if they remained asymptomatic). Low risk patients were considered as those who met the following criteria: unintentional intake, absence of symptoms and oral lesions. In the rest of the patients the usual protocol was performed. Re-admission with a diagnosis of digestive lesions was considered as a complication. Forty-eight patients were included in period 1, and 35 in period 2. In period 2, thirteen patients met low risk criteria. The adherence to the less aggressive protocol was 100%. None of the low risk patients required admission or endoscopy after discharge. In period 1 the adherence to the usual protocol was 60.4%. Six patients would have benefited from the application of the less aggressive protocol. Adopting a more conservative attitude in low risk patients is safe. These patients benefit from clinical observation, without performing more aggressive measures with their possible iatrogenic adverse effects. Copyright © 2018. Publicado por Elsevier España, S.L.U.

Next Generation Solvent Performance in the Modular Caustic Side Solvent Extraction Process - 15495

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, Tara E.; Scherman, Carl; Martin, David

Changes to the Modular Caustic Side Solvent Extraction Unit (MCU) flow-sheet were implemented in the facility. Implementation included changing the scrub and strip chemicals and concentrations, modifying the O/A ratios for the strip, scrub, and extraction contactor banks, and blending the current BoBCalixC6 extractant-based solvent in MCU with clean MaxCalix extractant-based solvent. During the successful demonstration period, the MCU process was subject to rigorous oversight to ensure hydraulic stability and chemical/radionuclide analysis of the key process tanks (caustic wash tank, solvent hold tank, strip effluent hold tank, and decontaminated salt solution hold tank) to evaluate solvent carryover to downstream facilitiesmore » and the effectiveness of cesium removal from the liquid salt waste. Results indicated the extraction of cesium was significantly more effective with an average Decontamination Factor (DF) of 1,129 (range was 107 to 1,824) and that stripping was effective. The contactor hydraulic performance was stable and satisfactory, as indicated by contactor vibration, contactor rotational speed, and flow stability; all of which remained at or near target values. Furthermore, the Solvent Hold Tank (SHT) level and specific gravity was as expected, indicating that solvent integrity and organic hydraulic stability were maintained. The coalescer performances were in the range of processing results under the BOBCalixC6 flow sheet, indicating negligible adverse impact of NGS deployment. After the Demonstration period, MCU began processing via routine operations. Results to date reiterate the enhanced cesium extraction and stripping capability of the Next Generation Solvent (NGS) flow sheet. This paper presents process performance results of the NGS Demonstration and continued operations of MCU utilizing the blended BobCalixC6-MaxCalix solvent under the NGS flowsheet.« less

Next Generation Solvent (NGS): Development for Caustic-Side Solvent Extraction of Cesium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moyer, Bruce A.; Birdwell, Jr, Joseph F.; Bonnesen, Peter V.

This report summarizes the FY 2010 and 2011 accomplishments at Oak Ridge National Laboratory (ORNL) in developing the Next Generation Caustic-Side Solvent Extraction (NG-CSSX) process, referred to commonly as the Next Generation Solvent (NGS), under funding from the U.S. Department of Energy, Office of Environmental Management (DOE-EM), Office of Technology Innovation and Development. The primary product of this effort is a process solvent and preliminary flowsheet capable of meeting a target decontamination factor (DF) of 40,000 for worst-case Savannah River Site (SRS) waste with a concentration factor of 15 or higher in the 18-stage equipment configuration of the SRS Modularmore » Caustic-Side Solvent Extraction Unit (MCU). In addition, the NG-CSSX process may be readily adapted for use in the SRS Salt Waste Processing Facility (SWPF) or in supplemental tank-waste treatment at Hanford upon appropriate solvent or flowsheet modifications. Efforts in FY 2010 focused on developing a solvent composition and process flowsheet for MCU implementation. In FY 2011 accomplishments at ORNL involved a wide array of chemical-development activities and testing up through single-stage hydraulic and mass-transfer tests in 5-cm centrifugal contactors. Under subcontract from ORNL, Argonne National Laboratory (ANL) designed a preliminary flowsheet using ORNL cesium distribution data, and Tennessee Technological University confirmed a chemical model for cesium distribution ratios (DCs) as a function of feed composition. Interlaboratory efforts were coordinated with complementary engineering tests carried out (and reported separately) by personnel at Savannah River National Laboratory (SRNL) and Savannah River Remediation (SRR) with helpful advice by Parsons Engineering and General Atomics on aspects of possible SWPF implementation.« less

Next Generation Solvent Development for Caustic-Side Solvent Extraction of Cesium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moyer, Bruce A.; Birdwell, Joseph F.; Bonnesen, Peter V.

This report summarizes the FY 2010 and 2011 accomplishments at Oak Ridge National Laboratory (ORNL) in developing the Next Generation Caustic-Side Solvent Extraction (NG-CSSX) process, referred to commonly as the Next Generation Solvent (NGS), under funding from the U.S. Department of Energy, Office of Environmental Management (DOE-EM), Office of Technology Innovation and Development. The primary product of this effort is a process solvent and preliminary flowsheet capable of meeting a target decontamination factor (DF) of 40,000 for worst-case Savannah River Site (SRS) waste with a concentration factor of 15 or higher in the 18-stage equipment configuration of the SRS Modularmore » Caustic-Side Solvent Extraction Unit (MCU). In addition, the NG-CSSX process may be readily adapted for use in the SRS Salt Waste Processing Facility (SWPF) or in supplemental tank-waste treatment at Hanford upon appropriate solvent or flowsheet modifications. Efforts in FY 2010 focused on developing a solvent composition and process flowsheet for MCU implementation. In FY 2011 accomplishments at ORNL involved a wide array of chemical-development activities and testing up through single-stage hydraulic and mass-transfer tests in 5-cm centrifugal contactors. Under subcontract from ORNL, Argonne National Laboratory (ANL) designed a preliminary flowsheet using ORNL cesium distribution data, and Tennessee Technological University confirmed a chemical model for cesium distribution ratios (DCs) as a function of feed composition. Inter laboratory efforts were coordinated with complementary engineering tests carried out (and reported separately) by personnel at Savannah River National Laboratory (SRNL) and Savannah River Remediation (SRR) with helpful advice by Parsons Engineering and General Atomics on aspects of possible SWPF implementation.« less

Can Cr( iii ) substitute for Al( iii ) in the structure of boehmite?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chatterjee, Sayandev; Conroy, Michele A.; Smith, Frances N.

2016-01-01

The dissolution of boehmite is a technical issue for the Al industry because of its recalcitrant nature. In fact, a similar problem exists with boehmite in nuclear waste sludge at the Hanford site in eastern Washington State, USA. Dissolution of Al phases is required to reduce the waste loadings in the final borosilicate glass waste form. Although not the most common Al-bearing species in the sludge, boehmite may become a rate limiting step in the processing of the wastes. Hanford boehmite is an order of magnitude more resistant to dissolution in hot caustic solutions than expected from surface-normalized rates. Wemore » are exploring potential intrinsic and extrinsic effects that may limit boehmite reactivity; one clue comes from microstructural analyses that indicate an association of Cr with Al in the Hanford nuclear waste. Hence, in this first paper, we investigated the potential role of chromium on the reactivity of boehmite in caustic solution. An important finding was that irrespective of the synthesis pathway, amount of Cr(III), or the resultant morphology, there was no evidence for Cr incorporation in the bulk structure, in agreement with QM calculations. In fact, electron microscopic (EM) and spectroscopic analyses showed that Cr was enriched at the (101) edges of the boehmite. However, Cr had no measurable effect on the morphology during the synthesis step. In contrast, comparison of the morphologies of the synthetic Cr-doped and pure boehmite samples after exposure to caustic solutions provided evidence that Cr inhibited the corrosion. TEM showed that Cr was not homogeneously distributed at the surface. Consequently, Cr may have partially passivated the surface by blocking discrete energetic sites on the lateral surfaces of boehmite.« less

LUGOL'S IODINE CHROMOENDOSCOPY VERSUS NARROW BAND IMAGE ENHANCED ENDOSCOPY FOR THE DETECTION OF ESOPHAGEAL CANCER IN PATIENTS WITH STENOSIS SECONDARY TO CAUSTIC/CORROSIVE AGENT INGESTION.

PubMed

Pennachi, Caterina Maria Pia Simoni; Moura, Diogo Turiani Hourneaux de; Amorim, Renato Bastos Pimenta; Guedes, Hugo Gonçalo; Kumbhari, Vivek; Moura, Eduardo Guimarães Hourneaux de

2017-01-01

The diagnosis of corrosion cancer should be suspected in patients with corrosive ingestion if after a latent period of negligible symptoms there is development of dysphagia, or poor response to dilatation, or if respiratory symptoms develop in an otherwise stable patient of esophageal stenosis. Narrow Band Imaging detects superficial squamous cell carcinoma more frequently than white-light imaging, and has significantly higher sensitivity and accuracy compared with white-light. To determinate the clinical applicability of Narrow Band Imaging versus Lugol´s solution chromendoscopy for detection of early esophageal cancer in patients with caustic/corrosive agent stenosis. Thirty-eight patients, aged between 28-84 were enrolled and examined by both Narrow Band Imaging and Lugol´s solution chromendoscopy. A 4.9mm diameter endoscope was used facilitating examination of a stenotic area without dilation. Narrow Band Imaging was performed and any lesion detected was marked for later biopsy. Then, Lugol´s solution chromoendoscopy was performed and biopsies were taken at suspicious areas. Patients who had abnormal findings at the routine, Narrow Band Imaging or Lugol´s solution chromoscopy exam had their stenotic ring biopsied. We detected nine suspicious lesions with Narrow Band Imaging and 14 with Lugol´s solution chromendoscopy. The sensitivity and specificity of the Narrow Band Imaging was 100% and 80.6%, and with Lugol´s chromoscopy 100% and 66.67%, respectively. Five (13%) suspicious lesions were detected both with Narrow Band Imaging and Lugol's chromoscopy, two (40%) of these lesions were confirmed carcinoma on histopathological examination. Narrow Band Imaging is an applicable option to detect and evaluate cancer in patients with caustic /corrosive stenosis compared to the Lugol´s solution chromoscopy.

Combined chitosan-thyme treatments with modified atmosphere packaging on a ready-to-cook poultry product.

PubMed

Giatrakou, V; Ntzimani, A; Savvaidis, I N

2010-04-01

In the present study, natural antimicrobials chitosan and thyme, and their combination, were evaluated for their effect on the shelf life of a ready-to-cook (RTC) chicken-pepper kebab (skewer) stored under modified atmosphere packaging (MAP) conditions at 4 +/- 0.5 degrees C for 14 days. The following treatments were examined: control samples stored under aerobic packaging (A), samples stored under MAP (M), samples treated with 1.5% chitosan (vol/wt) and stored under MAP (M-CH), samples treated with 0.2% thyme essential oil (vol/wt) (M-T), and samples treated with 1.5% chitosan (vol/wt) and 0.2% thyme essential oil (vol/wt) and stored under MAP (M-CH-T). Treatment M-CH-T significantly affected aerobic plate counts and counts of lactic acid bacteria, Pseudomonas spp., Brochothrix thermosphacta, Enterobacteriaceae, and yeasts and molds during the entire storage period. Similarly, lipid oxidation of the RTC product was retarded (M-CH-T treatment) during storage, whereas redness was maintained in M-T, M-CH, and M-CH-T samples. Based primarily on sensory data (taste attribute), M-CH and M-T treatments extended RTC product shelf life by 6 days, whereas M-CH-T treatment resulted in a product with a shelf life of 14 days that maintained acceptable sensory characteristics (shelf life of the control was 6 days).

The Herschel-ATLAS: Extragalatic Number Counts from 250 to 500 Microns

NASA Technical Reports Server (NTRS)

Clements, D. L.; Rigby, E.; Maddox, S.; Dunne, L.; Mortier, A.; Amblard, A.; Auld, R.; Bonfield, D.; Cooray, A.; Dariush, A.;

Frequency Count Attribute Oriented Induction of Corporate Network Data for Mapping Business Activity

NASA Astrophysics Data System (ADS)

Tanutama, Lukas

2014-03-01

Companies increasingly rely on Internet for effective and efficient business communication. As Information Technology infrastructure backbone for business activities, corporate network connects the company to Internet and enables its activities globally. It carries data packets generated by the activities of the users performing their business tasks. Traditionally, infrastructure operations mainly maintain data carrying capacity and network devices performance. It would be advantageous if a company knows what activities are running in its network. The research provides a simple method of mapping the business activity reflected by the network data. To map corporate users' activities, a slightly modified Attribute Oriented Induction (AOI) approach to mine the network data was applied. The frequency of each protocol invoked were counted to show what the user intended to do. The collected data was samples taken within a certain sampling period. Samples were taken due to the enormous data packets generated. Protocols of interest are only Internet related while intranet protocols are ignored. It can be concluded that the method could provide the management a general overview of the usage of its infrastructure and lead to efficient, effective and secure ICT infrastructure.

Data indexing techniques for the EUVE all-sky survey

NASA Technical Reports Server (NTRS)

Lewis, J.; Saba, V.; Dobson, C.

1992-01-01

This poster describes techniques developed for manipulating large full-sky data sets for the Extreme Ultraviolet Explorer project. The authors have adapted the quatrilateralized cubic sphere indexing algorithm to allow us to efficiently store and process several types of large data sets, such as full-sky maps of photon counts, exposure time, and count rates. A variation of this scheme is used to index sparser data such as individual photon events and viewing times for selected areas of the sky, which are eventually used to create EUVE source catalogs.

IF ECOLOGICAL RISK ASSESSMENT IS THE ANSWER, WHAT IS THE QUESTION?

EPA Science Inventory

Ecological risk assessment has become a commonly used tool in policy analysis, but its use is controversial. Opinions are diverse; they range from enthusiastic support to caustic dismissal. Much of the controversy with using risk assessment in ecological policy analysis revolves ...

CO2 Sparging Proof of Concept Test Report, Revision 1, LCP Chemicals Site, Brunswick, Georgia

EPA Pesticide Factsheets

April 2013 report to evaluate the feasibility of CO2 sparging to remediate a sub-surface caustic brine pool (CBP) at the LCP Chemicals Superfund Site, GA. Region ID : 04, DocID: 10940639 , DocDate: 2013-04-01

40 CFR 442.25 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2014 CFR

2014-07-01

... contribute to a discharge that would be incompatible with treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior presolve washes, interior detergent washes, interior..., prerinse/pre-steam wastes, spent cleaning solutions); (ix) Information on the volumes, content, and...

APL - North Pacific Acoustic Laboratory

DTIC Science & Technology

2015-03-04

PhilSea10 cruise were spent in a series of upgrades and associated tests of the TCTD system. Electronic upgrades in conjunction with the manufacturers, ADM...amplitude at positions sufficiently removed from caustics . Mr. White computed eigenrays to all tracked upper array hydrophone positions relative to each

40 CFR 442.15 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2012 CFR

2012-07-01

... contribute to a discharge that would be incompatible with treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior presolve washes, interior detergent washes, interior..., prerinse/pre-steam wastes, spent cleaning solutions); (ix) Information on the volumes, content, and...

40 CFR 442.15 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2013 CFR

2013-07-01

... contribute to a discharge that would be incompatible with treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior presolve washes, interior detergent washes, interior..., prerinse/pre-steam wastes, spent cleaning solutions); (ix) Information on the volumes, content, and...

40 CFR 442.25 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2012 CFR

2012-07-01

... contribute to a discharge that would be incompatible with treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior presolve washes, interior detergent washes, interior..., prerinse/pre-steam wastes, spent cleaning solutions); (ix) Information on the volumes, content, and...

40 CFR 442.15 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2014 CFR

2014-07-01

... contribute to a discharge that would be incompatible with treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior presolve washes, interior detergent washes, interior..., prerinse/pre-steam wastes, spent cleaning solutions); (ix) Information on the volumes, content, and...

40 CFR 442.25 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2013 CFR

2013-07-01

... contribute to a discharge that would be incompatible with treatment at the POTW; (iv) All spent cleaning solutions, including interior caustic washes, interior presolve washes, interior detergent washes, interior..., prerinse/pre-steam wastes, spent cleaning solutions); (ix) Information on the volumes, content, and...

TRENDS IN THE U.S. WATER MARKET SHAPING TECHNOLOGY INNOVATION

EPA Science Inventory

The US water market—and the new technologies that will increasingly define its growth—are entering a new era. Increased scarcity, new regulatory imperatives, public discontent over caustic treatments and practices, and the decline of the design-bid-build model (through which maj...

40 CFR 63.191 - Definitions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... polycarbonate. Methylene chloride is used as a solvent in this polymerization reaction. Polysulfide rubber means... product of reaction of butadiene with excess furfural in a liquid phase reactor. R-11 is usually used as... is not limited to, the reaction of tetrahydrophthalimide and perchloromethyl mercaptan with caustic...

40 CFR 63.191 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... polycarbonate. Methylene chloride is used as a solvent in this polymerization reaction. Polysulfide rubber means... product of reaction of butadiene with excess furfural in a liquid phase reactor. R-11 is usually used as... is not limited to, the reaction of tetrahydrophthalimide and perchloromethyl mercaptan with caustic...

40 CFR 63.191 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... polycarbonate. Methylene chloride is used as a solvent in this polymerization reaction. Polysulfide rubber means... product of reaction of butadiene with excess furfural in a liquid phase reactor. R-11 is usually used as... is not limited to, the reaction of tetrahydrophthalimide and perchloromethyl mercaptan with caustic...

40 CFR 63.191 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... polycarbonate. Methylene chloride is used as a solvent in this polymerization reaction. Polysulfide rubber means... product of reaction of butadiene with excess furfural in a liquid phase reactor. R-11 is usually used as... is not limited to, the reaction of tetrahydrophthalimide and perchloromethyl mercaptan with caustic...

40 CFR 63.191 - Definitions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... polycarbonate. Methylene chloride is used as a solvent in this polymerization reaction. Polysulfide rubber means... product of reaction of butadiene with excess furfural in a liquid phase reactor. R-11 is usually used as... is not limited to, the reaction of tetrahydrophthalimide and perchloromethyl mercaptan with caustic...

Thermal stability study of a new guanidine suppressor for the next-generation caustic-side solvent extraction process

DOE PAGES

Hill, Talon G.; Ensor, Dale D.; Delmau, Lætitia Helene; ...

2016-02-06

Cesium stripping performance of thermally stressed solvent degrades slowly over time in batch tests of the Next Generation Caustic-Side Solvent Extraction (NGS) process. NGS is currently used at pilot scale at the Savannah River Site for the selective removal of cesium from high-level salt waste. Recently a new guanidine, N,N',N" -tris(3,7-dimethyloctyl)guanidine (TiDG), was chosen for use as the suppressor, a lipophilic organic base needed for stripping, and the present study was undertaken to address the question of its stability. The NGS process solvent was evaluated for a period of three months under a variety of temperature and storage conditions. Themore » performance of the solvent was tested at 30-day increments using a standard extraction, scrub, strip, and extraction (ES 2S 3E) sequence. Lastly, the results provide insight on the effects of storage and process conditions, the stripping behavior of TiDG, and the stability of the new solvent composition.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marra, Valerio; Kolb, Edward W.; Matarrese, Sabino

Photon geodesics are calculated in a Swiss-cheese model, where the cheese is made of the usual Friedmann-Robertson-Walker (FRW) solution and the holes are constructed from a Lemaitre-Tolman-Bondi solution of Einstein's equations. The observables on which we focus are the changes in the redshift, in the angular-diameter-distance relation, in the luminosity-distance-redshift relation, and in the corresponding distance modulus. We find that redshift effects are suppressed when the hole is small because of a compensation effect acting on the scale of half a hole resulting from the special case of spherical symmetry. However, we find interesting effects in the calculation of themore » angular distance: strong evolution of the inhomogeneities (as in the approach to caustic formation) causes the photon path to deviate from that of the FRW case. Therefore, the inhomogeneities are able to partly mimic the effects of a dark-energy component. Our results also suggest that the nonlinear effects of caustic formation in cold dark matter models may lead to interesting effects on photon trajectories.« less

The varieties of symmetric stellar rings and radial caustics in galaxy disks

NASA Technical Reports Server (NTRS)

Struck-Marcell, Curtis; Lotan, Pnina

1990-01-01

Numerical, restricted three-body and analytic calculations are used to study the formation and propagation of cylindrically symmetric stellar ring waves in galaxy disks. It is shown that such waves can evolve in a variety of ways, depending on the amplitude of the perturbation and the potential of the target galaxy. Rings can thicken as they propagate outward, remain at a nearly constant width, or be pinched off at large radii. Multiple, closely spaced rings can result from a low-amplitude collision, while an outer ring can appear well-separated from overlapping inner rings or an apparent lens structure in halo-dominated potentials. All the single-encounter rings consist of paired fold caustics. The simple, impulsive, kinematic oscillation equations appear to provide a remarkably accurate model of the numerical simulations. Simple analytic approximations to these equations permit very good estimates of oscillation periods and amplitudes, the evolution of ring widths, and ring birth and propagation characteristics.

Thermal stability study of a new guanidine suppressor for the next-generation caustic-side solvent extraction process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hill, Talon G.; Ensor, Dale D.; Delmau, Lætitia Helene

Cesium stripping performance of thermally stressed solvent degrades slowly over time in batch tests of the Next Generation Caustic-Side Solvent Extraction (NGS) process. NGS is currently used at pilot scale at the Savannah River Site for the selective removal of cesium from high-level salt waste. Recently a new guanidine, N,N',N" -tris(3,7-dimethyloctyl)guanidine (TiDG), was chosen for use as the suppressor, a lipophilic organic base needed for stripping, and the present study was undertaken to address the question of its stability. The NGS process solvent was evaluated for a period of three months under a variety of temperature and storage conditions. Themore » performance of the solvent was tested at 30-day increments using a standard extraction, scrub, strip, and extraction (ES 2S 3E) sequence. Lastly, the results provide insight on the effects of storage and process conditions, the stripping behavior of TiDG, and the stability of the new solvent composition.« less

Method for sequestering CO.sub.2 and SO.sub.2 utilizing a plurality of waste streams

DOEpatents

Soong, Yee [Monroeville, PA; Allen, Douglas E [Salem, MA; Zhu, Chen [Monroe County, IN

2011-04-12

A neutralization/sequestration process is provided for concomitantly addressing capture and sequestration of both CO.sub.2 and SO.sub.2 from industrial gas byproduct streams. The invented process concomitantly treats and minimizes bauxite residues from aluminum production processes and brine wastewater from oil/gas production processes. The benefits of this integrated approach to coincidental treatment of multiple industrial waste byproduct streams include neutralization of caustic byproduct such as bauxite residue, thereby decreasing the risk associated with the long-term storage and potential environmental of storing caustic materials, decreasing or obviating the need for costly treatment of byproduct brines, thereby eliminating the need to purchase CaO or similar scrubber reagents typically required for SO.sub.2 treatment of such gasses, and directly using CO.sub.2 from flue gas to neutralize bauxite residue/brine mixtures, without the need for costly separation of CO.sub.2 from the industrial byproduct gas stream by processes such as liquid amine-based scrubbers.

Extraction, Scrub, and Strip Test Results for the Salt Waste Processing Facility Caustic Side Solvent Extraction Solvent Sample

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peters, T. B.

An Extraction, Scrub, and Strip (ESS) test was performed on a sample of Salt Waste Processing Facility (SWPF) Caustic-Side Solvent Extraction (CSSX) solvent and salt simulant to determine cesium distribution ratios (D( Cs)), and cesium concentration in the strip effluent (SE) and decontaminated salt solution (DSS) streams; this data will be used by Parsons to help determine if the solvent is qualified for use at the SWPF. The ESS test showed acceptable performance of the solvent for extraction, scrub, and strip operations. The extraction D( Cs) measured 12.5, exceeding the required value of 8. This value is consistent with resultsmore » from previous ESS tests using similar solvent formulations. Similarly, scrub and strip cesium distribution ratios fell within acceptable ranges. This revision was created to correct an error. The previous revision used an incorrect set of temperature correction coefficients which resulted in slight deviations from the correct D( Cs) results.« less

Biological treatment of refinery spent caustics under halo-alkaline conditions.

PubMed

de Graaff, Marco; Bijmans, Martijn F M; Abbas, Ben; Euverink, Gert-J W; Muyzer, Gerard; Janssen, Albert J H

2011-08-01

The present research demonstrates the biological treatment of refinery sulfidic spent caustics in a continuously fed system under halo-alkaline conditions (i.e. pH 9.5; Na(+)= 0.8M). Experiments were performed in identical gas-lift bioreactors operated under aerobic conditions (80-90% saturation) at 35°C. Sulfide loading rates up to 27 mmol L(-1)day(-1) were successfully applied at a HRT of 3.5 days. Sulfide was completely converted into sulfate by the haloalkaliphilic sulfide-oxidizing bacteria belonging to the genus Thioalkalivibrio. Influent benzene concentrations ranged from 100 to 600 μM. At steady state, benzene was removed by 93% due to high stripping efficiencies and biodegradation. Microbial community analysis revealed the presence of haloalkaliphilic heterotrophic bacteria belonging to the genera Marinobacter, Halomonas and Idiomarina which might have been involved in the observed benzene removal. The work shows the potential of halo-alkaliphilic bacteria in mitigating environmental problems caused by alkaline waste. Copyright © 2011 Elsevier Ltd. All rights reserved.

Bayesian analysis of caustic-crossing microlensing events

NASA Astrophysics Data System (ADS)

Cassan, A.; Horne, K.; Kains, N.; Tsapras, Y.; Browne, P.

2010-06-01

Aims: Caustic-crossing binary-lens microlensing events are important anomalous events because they are capable of detecting an extrasolar planet companion orbiting the lens star. Fast and robust modelling methods are thus of prime interest in helping to decide whether a planet is detected by an event. Cassan introduced a new set of parameters to model binary-lens events, which are closely related to properties of the light curve. In this work, we explain how Bayesian priors can be added to this framework, and investigate on interesting options. Methods: We develop a mathematical formulation that allows us to compute analytically the priors on the new parameters, given some previous knowledge about other physical quantities. We explicitly compute the priors for a number of interesting cases, and show how this can be implemented in a fully Bayesian, Markov chain Monte Carlo algorithm. Results: Using Bayesian priors can accelerate microlens fitting codes by reducing the time spent considering physically implausible models, and helps us to discriminate between alternative models based on the physical plausibility of their parameters.

Application of a 2-step process for the biological treatment of sulfidic spent caustics.

PubMed

de Graaff, Marco; Klok, Johannes B M; Bijmans, Martijn F M; Muyzer, Gerard; Janssen, Albert J H

2012-03-01

This research demonstrates the feasibility and advantages of a 2-step process for the biological treatment of sulfidic spent caustics under halo-alkaline conditions (i.e. pH 9.5; Na(+) = 0.8 M). Experiments with synthetically prepared solutions were performed in a continuously fed system consisting of two gas-lift reactors in series operated at aerobic conditions at 35 °C. The detoxification of sulfide to thiosulfate in the first step allowed the successful biological treatment of total-S loading rates up to 33 mmol L(-1) day(-1). In the second, biological step, the remaining sulfide and thiosulfate was completely converted to sulfate by haloalkaliphilic sulfide oxidizing bacteria. Mathematical modeling of the 2-step process shows that under the prevailing conditions an optimal reactor configuration consists of 40% 'abiotic' and 60% 'biological' volume, whilst the total reactor volume is 22% smaller than for the 1-step process. Copyright © 2011 Elsevier Ltd. All rights reserved.

Microbial community structure and dynamics in a mixotrophic nitrogen removal process using recycled spent caustic under different loading conditions.

PubMed

Park, Sora; Yu, Jaecheul; Byun, Imgyu; Cho, Sunja; Park, Taejoo; Lee, Taeho

2011-08-01

A laboratory-scale Bardenpho process was established to investigate the proper nitrogen loading rate (NLR) when modified spent caustic (MSC) is applied as electron donor and alkalinity source for denitrification. MSC injection induced autotrophic nitrogen removal with sulfur as electron donor and heterotrophic denitrification. The nitrogen removal rate (NRR) did not increase proportionally to NLR. Based on the total nitrogen concentration in the effluent observed in the trials with MSC, the NLR in the influent should not exceed 0.15 kg N/m(3)d in order to satisfy water quality regulations. Microbial communities in the anoxic reactors were characterized by pyrosequencing of 16S rRNA gene sequences amplified by the polymerase chain reaction of DNA extracted from sludge samples. Microbial diversity was lower as MSC dosage was increased, and the injection of MSC caused an increase in SOB belonging to the genus Thiobacillus which is responsible for denitrification using sulfur. Copyright © 2011 Elsevier Ltd. All rights reserved.

Effect of a nano-silver coating on the quality of fresh turkey meat during storage after modified atmosphere or vacuum packaging.

PubMed

Deus, D; Kehrenberg, C; Schaudien, D; Klein, G; Krischek, C

2017-02-01

Nano-silver is used in consumer products due to its antibacterial properties. The aim of this study was to evaluate the effect of a nano-silver-coated film on the quality of turkey meat during vacuum-sealed and modified atmosphere packaging up to 12 days of storage. In the first part of the experiment, turkey breasts were packaged using either vacuum packaging or modified atmosphere packages (MAPs) and contained films with or without a nano-silver coating (control film). Parameters such as pH, electrical conductivity, color (lightness L*, redness a*), myoglobin redox forms, thiobarbituric acid-reactive substances (TBARS), biogenic amines (BAs), total viable bacterial counts, Pseudomonas species counts, and Enterobacteriaceae species counts were evaluated on storage days 4, 8, and 12. In the second part of the study, the antimicrobial effect of a nano-silver-coated film on turkey breast was evaluated after inoculation with Escherichia coli (E. coli). Turkey meat packaged with the nano-silver film exhibited lower a* values on days 1 (3.15 ± 0.62), 4 (3.90 ± 0.68), and 8 (4.27 ± 0.76) compared to the packaged meat with the control film (3.41 ± 0.73, 4.35 ± 0.94, 4.85 ± 0.89, respectively), indicating special optical properties of nanoparticles. Concerning the BAs, silver packaged meat showed higher values of tyramine on day 12 (1274 ± 392 ng/g meat) and cadaverine on day 4 (1224 ± 435 ng/g meat) compared to the normal packaged products (647 ± 576 and 508 ± 314 ng/g meat, respectively). MAP meat revealed higher L* and TBARS values and lower microbial counts than the vacuum packaged products on all days. The MAP meat also showed lower a* results on days 4 and 8 and higher metmyoglobin (metMb) values on days 8 and 12 compared to th E: vacuum products. In the inoculation study, the microbial counts of the turkey meat were comparable between the two film types. The study showed that the nano-silver coating did not exhibit any advantageous effects on the quality and microbiological parameters of the turkey meat. © 2016 Poultry Science Association Inc.