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Sample records for cavity-enhanced down-conversion high

  1. High-efficiency microwave photonic harmonic down-conversion with tunable and reconfigurable filtering.

    PubMed

    Liao, Jinxin; Zheng, Xiaoping; Li, Shangyuan; Zhang, Hanyi; Zhou, Bingkun

    2014-12-01

    A new optical-frequency comb-based microwave photonic harmonic down-convertor with tunable and reconfigurable filtering is proposed and experimentally demonstrated. The coherent evenly spaced optical carriers offer harmonic down-conversion for ultrahigh radio frequency signals with low-frequency local oscillator, and construct a tunable and reconfigurable bandpass filter for the intermediate-frequency (IF) signal combined with dispersion. This implementation features high conversion efficiency. Experimental results show the filtered output IF signal has a clean spectrum with high quality. Measured conversion loss is 8.3 dB without extra electrical amplification.

  2. High-speed Si resonant cavity enhanced photodetectors and arrays

    NASA Astrophysics Data System (ADS)

    Ünlü, M. S.; Emsley, M. K.; Dosunmu, O. I.; Muller, P.; Leblebici, Y.

    2004-05-01

    Over the past decade a new family of optoelectronic devices has emerged whose performance is enhanced by placing the active device structure inside a Fabry-Perot resonant microcavity [P. E. Green, IEEE Spectrum 13 (2002)]. The increased optical field allows photodetectors to be made thinner and therefore faster, while simultaneously increasing the quantum efficiency at the resonant wavelengths. We have demonstrated a variety of resonant cavity enhanced (RCE) photodetectors in compound semiconductors [B. Yang, J. D. Schaub, S. M. Csutak, D. J. Rogers, and J. C. Campbell, IEEE Photonics Technol. Lett. 15, 745 (2003)] and Si [M. K. Emsley, O. I. Dosunmu, and M. S. Ünlü, IEEE J. Selected Topics Quantum Electron. 8, 948 (2002)], operating at optical communication wavelengths ranging from 850 nm to 1550 nm. The focus of this article is on Si photodetectors and arrays. High bandwidth short distance communications standards are being developed based on parallel optical interconnect fiber arrays to meet the needs of increasing data rates of interchip communication in modern computer architecture. To ensure that this standard becomes an attractive option for computer systems, low cost components must be implemented on both the transmitting and receiving end of the fibers. To meet this low cost requirement silicon based receiver circuits are the most viable option, however, high speed, high efficiency silicon photodetectors present a technical challenge. Commercially reproducible silicon wafers with a high reflectance buried distributed Bragg reflector (DBR) have been designed and fabricated [M. K. Emsley, O. I. Dosunmu, and M. S. Ünlü, IEEE J. Selected Topics Quantum Electron. 8, 948 (2002)]. The substrates consist of a two-period, 90% reflecting, DBR fabricated using a double silicon-on-insulator (SOI) process. Resonant-cavity-enhanced (RCE) Si photodetectors have been fabricated with 40% quantum efficiency at 850 nm and a FWHM of 29 ps suitable for 10 Gbps data

  3. Orbital angular momentum modes of high-gain parametric down-conversion

    NASA Astrophysics Data System (ADS)

    Beltran, Lina; Frascella, Gaetano; Perez, Angela M.; Fickler, Robert; Sharapova, Polina R.; Manceau, Mathieu; Tikhonova, Olga V.; Boyd, Robert W.; Leuchs, Gerd; Chekhova, Maria V.

    2017-04-01

    Light beams with orbital angular momentum (OAM) are convenient carriers of quantum information. They can also be used for imparting rotational motion to particles and providing high resolution in imaging. Due to the conservation of OAM in parametric down-conversion (PDC), signal and idler photons generated at low gain have perfectly anti-correlated OAM values. It is interesting to study the OAM properties of high-gain PDC, where the same OAM modes can be populated with large, but correlated, numbers of photons. Here we investigate the OAM spectrum of high-gain PDC and show that the OAM mode content can be controlled by varying the pump power and the configuration of the source. In our experiment, we use a source consisting of two nonlinear crystals separated by an air gap. We discuss the OAM properties of PDC radiation emitted by this source and suggest possible modifications.

  4. High-Fidelity Down-Conversion Source for Secure Communications Using On-Demand Single Photons

    NASA Technical Reports Server (NTRS)

    Roberts, Tony

    2015-01-01

    AdvR, Inc., has built an efficient, fully integrated, waveguide-based source of spectrally uncorrelated photon pairs that will accelerate research and development (R&D) in the emerging field of quantum information science. Key to the innovation is the use of submicron periodically poled waveguides to produce counter propagating photon pairs, which is enabled by AdvR's patented segmented microelectrode poling technique. This novel device will provide a high brightness source of down-conversion pairs with enhanced spectral properties and low attenuation, and it will operate in the visible to the mid-infrared spectral region. A waveguide-based source of spectrally and spatially pure heralded photons will contribute to a wide range of NASA's advanced technology development efforts, including on-demand single photon sources for high-rate spaced-based secure communications.

  5. Type I parametric down conversion of highly focused Gaussian beams in finite length crystals

    NASA Astrophysics Data System (ADS)

    Jeronimo-Moreno, Yasser; Jáuregui, R.

    2014-06-01

    This paper presents a study of the correlations in wave vector space of photon pairs generated by type I spontaneous parametric down conversion using a Gaussian pump beam. The analysis covers both moderate focused and highly focused regimes, paying special attention to the angular spectrum and the conditional angular spectrum. Simple analytic expressions are derived that allow a detailed study of the dependence of these spectra on the waist of the source and the length of the nonlinear crystal. These expressions are in good agreement with numerical expectations and reported experimental results. They are used to make a systematic search of optimization parameters that improve the feasibility of using highly focused Gaussian beams to generate idler and signal photons with predetermined mean values and spread of their transverse wave vectors.

  6. High efficiency light source using solid-state emitter and down-conversion material

    DOEpatents

    Narendran, Nadarajah; Gu, Yimin; Freyssinier, Jean Paul

    2010-10-26

    A light emitting apparatus includes a source of light for emitting light; a down conversion material receiving the emitted light, and converting the emitted light into transmitted light and backward transmitted light; and an optic device configured to receive the backward transmitted light and transfer the backward transmitted light outside of the optic device. The source of light is a semiconductor light emitting diode, a laser diode (LD), or a resonant cavity light emitting diode (RCLED). The down conversion material includes one of phosphor or other material for absorbing light in one spectral region and emitting light in another spectral region. The optic device, or lens, includes light transmissive material.

  7. Producing high fidelity single photons with optimal brightness via waveguided parametric down-conversion.

    PubMed

    Laiho, K; Cassemiro, K N; Silberhorn, Ch

    2009-12-07

    Parametric down-conversion (PDC) offers the possibility to control the fabrication of non-Gaussian states such as Fock states. However, in conventional PDC sources energy and momentum conservation introduce strict frequency and photon number correlations, which impact the fidelity of the prepared state. In our work we optimize the preparation of single-photon Fock states from the emission of waveguided PDC via spectral filtering. We study the effect of correlations via photon number resolving detection and quantum interference. Our measurements show how the reduction of mixedness due to filtering can be evaluated. Interfering the prepared photon with a coherent state we establish an experimentally measured fidelity of the produced target state of 78%.

  8. Supercontinuum high-speed cavity-enhanced absorption spectroscopy for sensitive multispecies detection.

    PubMed

    Werblinski, Thomas; Lämmlein, Bastian; Huber, Franz J T; Zigan, Lars; Will, Stefan

    2016-05-15

    Cavity-enhanced absorption spectroscopy is promising for many applications requiring a very high concentration sensitivity but often accompanied by low temporal resolution. In this Letter, we demonstrate a broadband cavity-enhanced absorption spectrometer capable of detection rates of up to 50 kHz, based on a spatially coherent supercontinuum (SC) light source and an in-house-built, high-speed near-infrared spectrograph. The SC spectrometer allows for the simultaneous quantitative detection of CO2, C2H2, and H2O within a spectral range from 1420 to 1570 nm. Using cavity mirrors with a specified reflectivity of R=98.0±0.3% a minimal spectrally averaged absorption coefficient of αmin=1·10-5  cm-1 can be detected at a repetition rate of 50 kHz.

  9. Quantum-to-classical transition via fuzzy measurements on high-gain spontaneous parametric down-conversion

    SciTech Connect

    Vitelli, Chiara; Spagnolo, Nicolo; Toffoli, Lorenzo; Sciarrino, Fabio; De Martini, Francesco

    2010-03-15

    We consider the high-gain spontaneous parametric down-conversion in a noncollinear geometry as a paradigmatic scenario to investigate the quantum-to-classical transition by increasing the pump power, that is, the average number of generated photons. The possibility of observing quantum correlations in such a macroscopic quantum system through dichotomic measurement will be analyzed by addressing two different measurement schemes, based on different dichotomization processes. More specifically, we will investigate the persistence of nonlocality in an increasing size (n/2)-spin singlet state by studying the change in the correlations form as n increases, both in the ideal case and in presence of losses. We observe a fast decrease in the amount of Bell's inequality violation for increasing system size. This theoretical analysis is supported by the experimental observation of macro-macro correlations with an average number of photons of about 10{sup 3}. Our results shed light on the practical extreme difficulty of observing nonlocality by performing such a dichotomic fuzzy measurement.

  10. Theory of quantum frequency conversion and type-II parametric down-conversion in the high-gain regime

    NASA Astrophysics Data System (ADS)

    Christ, Andreas; Brecht, Benjamin; Mauerer, Wolfgang; Silberhorn, Christine

    2013-05-01

    Frequency conversion (FC) and type-II parametric down-conversion (PDC) processes serve as basic building blocks for the implementation of quantum optical experiments: type-II PDC enables the efficient creation of quantum states such as photon-number states and Einstein-Podolsky-Rosen (EPR)-states. FC gives rise to technologies enabling efficient atom-photon coupling, ultrafast pulse gates and enhanced detection schemes. However, despite their widespread deployment, their theoretical treatment remains challenging. Especially the multi-photon components in the high-gain regime as well as the explicit time-dependence of the involved Hamiltonians hamper an efficient theoretical description of these nonlinear optical processes. In this paper, we investigate these effects and put forward two models that enable a full description of FC and type-II PDC in the high-gain regime. We present a rigorous numerical model relying on the solution of coupled integro-differential equations that covers the complete dynamics of the process. As an alternative, we develop a simplified model that, at the expense of neglecting time-ordering effects, enables an analytical solution. While the simplified model approximates the correct solution with high fidelity in a broad parameter range, sufficient for many experimental situations, such as FC with low efficiency, entangled photon-pair generation and the heralding of single photons from type-II PDC, our investigations reveal that the rigorous model predicts a decreased performance for FC processes in quantum pulse gate applications and an enhanced EPR-state generation rate during type-II PDC, when EPR squeezing values above 12 dB are considered.

  11. A Lattice-Trapped and Cavity-Enhanced High-Quality Quantum Memory

    NASA Astrophysics Data System (ADS)

    Yang, Sheng-Jun; Wang, Xu-Jie; Bao, Xiao-Hui; Pan, Jian-Wei

    2015-05-01

    Quantum memory plays an increasing essential part in many applications of quantum information science. Currently, the intense research and crucial challenge is that integration of a full functional quantum memory with various high-performance properties in a single system. Storage lifetime and retrieval efficiency are the two most important qualities of quantum memory, especially indispensable for quantum repeater and long-distance quantum communication. Here based on techniques of magic optical lattice trap and ring cavity enhancement, we experimentally achieved a high-quality cold atom quantum memory. The initial intrinsic retrieval efficiency is up to 77(5)%, with an e-1-storage lifetime about 0.25 sec for the first time. Such high effective and long-lived quantum memory should be significantly important for quantum communication and cryptography, and would truly stimulate a first practical demonstration of long distance quantum repeaters in the near future.

  12. Scalable high-precision tuning of photonic resonators by resonant cavity-enhanced photoelectrochemical etching

    PubMed Central

    Gil-Santos, Eduardo; Baker, Christopher; Lemaître, Aristide; Gomez, Carmen; Leo, Giuseppe; Favero, Ivan

    2017-01-01

    Photonic lattices of mutually interacting indistinguishable cavities represent a cornerstone of collective phenomena in optics and could become important in advanced sensing or communication devices. The disorder induced by fabrication technologies has so far hindered the development of such resonant cavity architectures, while post-fabrication tuning methods have been limited by complexity and poor scalability. Here we present a new simple and scalable tuning method for ensembles of microphotonic and nanophotonic resonators, which enables their permanent collective spectral alignment. The method introduces an approach of cavity-enhanced photoelectrochemical etching in a fluid, a resonant process triggered by sub-bandgap light that allows for high selectivity and precision. The technique is presented on a gallium arsenide nanophotonic platform and illustrated by finely tuning one, two and up to five resonators. It opens the way to applications requiring large networks of identical resonators and their spectral referencing to external etalons. PMID:28117394

  13. Scalable high-precision tuning of photonic resonators by resonant cavity-enhanced photoelectrochemical etching

    NASA Astrophysics Data System (ADS)

    Gil-Santos, Eduardo; Baker, Christopher; Lemaître, Aristide; Gomez, Carmen; Leo, Giuseppe; Favero, Ivan

    2017-01-01

    Photonic lattices of mutually interacting indistinguishable cavities represent a cornerstone of collective phenomena in optics and could become important in advanced sensing or communication devices. The disorder induced by fabrication technologies has so far hindered the development of such resonant cavity architectures, while post-fabrication tuning methods have been limited by complexity and poor scalability. Here we present a new simple and scalable tuning method for ensembles of microphotonic and nanophotonic resonators, which enables their permanent collective spectral alignment. The method introduces an approach of cavity-enhanced photoelectrochemical etching in a fluid, a resonant process triggered by sub-bandgap light that allows for high selectivity and precision. The technique is presented on a gallium arsenide nanophotonic platform and illustrated by finely tuning one, two and up to five resonators. It opens the way to applications requiring large networks of identical resonators and their spectral referencing to external etalons.

  14. Tunable resonant-cavity-enhanced photodetector with double high-index-contrast grating mirrors

    NASA Astrophysics Data System (ADS)

    Learkthanakhachon, Supannee; Yvind, Kresten; Chung, Il-Sug

    2013-03-01

    In this paper, we propose a broadband-tunable resonant-cavity-enhanced photodetector (RCE-PD) structure with double high-index-contrast grating (HCG) mirrors and numerically investigate its characteristics. The detector is designed to operate at 1550-nm wavelength. The detector structure consists of a top InP HCG mirror, a p-i-n photodiode embedding multiple quantum wells, and a Si HCG mirror formed in the Si layer of a silicon-on-insulator wafer. The detection wavelength can be changed by moving the top InP HCG mirror suspended in the air. High reflectivity and small penetration length of HCGs lead to a narrow absorption linewidth of 0.38 nm and a broad tuning range of 111 nm. The peak absorption efficiency is 76-84% within the tuning range. This broadband-tunable and narrow-absorption-linewidth RCE-PD is desirable for applications where selective wavelength demultiplexing is required. Furthermore, the fact that it can be fabricated on a silicon platform offers us a possibility of integration with electronics.

  15. High-Speed Widely-Tunable 90% Quantum-Efficiency Resonant Cavity Enhanced p-i-n Photodiodes

    DTIC Science & Technology

    1998-12-01

    REPORT unclassified b . ABSTRACT unclassified c. THIS PAGE unclassified Standard Form 298 (Rev. 8-98) Prescribed by ANSI Std Z39-18 8:45am - 9...00am WB2 High-Speed Widely-Tunable >90% Quantum-Efficiency Resonant Cavity Enhanced p-i-n Photodiodes Necmi Biyiklia. Ibrahim Kimukinb. Orhan ...Bilkent, Ankara 06533, Turkey. b Department of Physics, Bilkent University, Bilkent, Ankara 06533, Turkey. c Department of Electrical and Computer

  16. High-fidelity frequency down-conversion of visible entangled photon pairs with superconducting single-photon detectors

    SciTech Connect

    Ikuta, Rikizo; Kato, Hiroshi; Kusaka, Yoshiaki; Yamamoto, Takashi; Imoto, Nobuyuki; Miki, Shigehito; Yamashita, Taro; Terai, Hirotaka; Wang, Zhen; Fujiwara, Mikio; Sasaki, Masahide; Koashi, Masato

    2014-12-04

    We experimentally demonstrate a high-fidelity visible-to-telecommunicationwavelength conversion of a photon by using a solid-state-based difference frequency generation. In the experiment, one half of a pico-second visible entangled photon pair at 780 nm is converted to a 1522-nm photon. Using superconducting single-photon detectors with low dark count rates and small timing jitters, we observed a fidelity of 0.93±0.04 after the wavelength conversion.

  17. Nanostructured organosilicon luminophores as a new concept of nanomaterials for highly efficient down-conversion of light

    NASA Astrophysics Data System (ADS)

    Ponomarenko, Sergey A.; Surin, Nikolay M.; Borshchev, Oleg V.; Skorotetcky, Maxim S.; Muzafarov, Aziz M.

    2015-10-01

    Nanostructured organosilicon luminophores (NOLs) are branched molecular structures having two types of covalently bonded via silicon atoms organic luminophores with efficient Förster energy transfer between them. They combine the best properties of organic luminophores and inorganic quantum dots: high absorption cross-section, excellent photoluminescence quantum yield, fast luminescence decay time, good processability and low toxicity. A smart choice of organic luminophores allowed us to design and synthesize a library of NOLs, absorbing from VUV to visible region and emitting at the desired wavelengths from 390 to 650 nm. They can be used as unique wavelength shifters in plastic scintillators and other applications.

  18. Approach to high-frequency, cavity-enhanced Faraday rotation in fluids.

    PubMed

    Pagliero, D; Li, Y; Fisher, S; Meriles, C A

    2011-02-10

    Recent work demonstrating detection of nuclear spin magnetization via Faraday rotation in transparent fluids promises novel opportunities for magnetic resonance imaging and spectroscopy. Unfortunately, low sensitivity is a serious concern. With this motivation in mind, we explore the use of an optical cavity to augment the Faraday rotation experienced by a linearly polarized beam traversing a sample fluid. Relying on a setup that affords reduced sample size and high-frequency modulation, we demonstrate amplification of regular (i.e., nonnuclear) Faraday rotation of order 20. Extensions of the present methodology that take into account the geometric constraints imposed by a high-field magnet may open the way to high-sensitivity, optically-detected magnetic resonance in the liquid state.

  19. Cavity-enhanced room-temperature high sensitivity optical Faraday magnetometry

    NASA Astrophysics Data System (ADS)

    Sun, Hui; Lei, Yaohua; Fan, Shuangli; Zhang, Qiaolin; Guo, Hong

    2017-01-01

    We propose a cavity QED system with two-photon Doppler-free configuration for weak magnetic field detection with high sensitivity at room temperature based on cavity electromagnetically induced transparency. Owing to the destructive interference induced by the control and driving fields, two transparency channels are opened. The Faraday rotation within two transparency channels can be used to detect weak magnetic field with high sensitivity at room temperature. The sensitivity with single photon and multiphoton probe inputs is analyzed. With single photon measurement, our numerical calculations demonstrate that the sensitivity with 3.8nT/√{Hz} and 6.4nT/√{Hz} could be achieved. When we measure the magnetic field with multiphoton input, the sensitivity can be improved to 7.7fT/√{Hz} and 25.6fT/√{Hz} under the realistic experimental conditions.

  20. Fast cavity-enhanced atom detection with low noise and high fidelity.

    PubMed

    Goldwin, J; Trupke, M; Kenner, J; Ratnapala, A; Hinds, E A

    2011-08-09

    Cavity quantum electrodynamics describes the fundamental interactions between light and matter, and how they can be controlled by shaping the local environment. For example, optical microcavities allow high-efficiency detection and manipulation of single atoms. In this regime, fluctuations of atom number are on the order of the mean number, which can lead to signal fluctuations in excess of the noise on the incident probe field. Here we demonstrate, however, that nonlinearities and multi-atom statistics can together serve to suppress the effects of atomic fluctuations when making local density measurements on clouds of cold atoms. We measure atom densities below 1 per cavity mode volume near the photon shot-noise limit. This is in direct contrast to previous experiments where fluctuations in atom number contribute significantly to the noise. Atom detection is shown to be fast and efficient, reaching fidelities in excess of 97% after 10 μs and 99.9% after 30 μs.

  1. Cavity enhanced atomic magnetometry.

    PubMed

    Crepaz, Herbert; Ley, Li Yuan; Dumke, Rainer

    2015-10-20

    Atom sensing based on Faraday rotation is an indispensable method for precision measurements, universally suitable for both hot and cold atomic systems. Here we demonstrate an all-optical magnetometer where the optical cell for Faraday rotation spectroscopy is augmented with a low finesse cavity. Unlike in previous experiments, where specifically designed multipass cells had been employed, our scheme allows to use conventional, spherical vapour cells. Spherical shaped cells have the advantage that they can be effectively coated inside with a spin relaxation suppressing layer providing long spin coherence times without addition of a buffer gas. Cavity enhancement shows in an increase in optical polarization rotation and sensitivity compared to single-pass configurations.

  2. Cavity enhanced atomic magnetometry

    PubMed Central

    Crepaz, Herbert; Ley, Li Yuan; Dumke, Rainer

    2015-01-01

    Atom sensing based on Faraday rotation is an indispensable method for precision measurements, universally suitable for both hot and cold atomic systems. Here we demonstrate an all-optical magnetometer where the optical cell for Faraday rotation spectroscopy is augmented with a low finesse cavity. Unlike in previous experiments, where specifically designed multipass cells had been employed, our scheme allows to use conventional, spherical vapour cells. Spherical shaped cells have the advantage that they can be effectively coated inside with a spin relaxation suppressing layer providing long spin coherence times without addition of a buffer gas. Cavity enhancement shows in an increase in optical polarization rotation and sensitivity compared to single-pass configurations. PMID:26481853

  3. High quantum efficiency N-structure type-II superlattice mid-wavelength infrared detector with resonant cavity enhanced design

    NASA Astrophysics Data System (ADS)

    Wu, Haoyue; Xu, Yun; Li, Jian; Jiang, Yu; Bai, Lin; Yu, Hailong; Fu, Dong; Zhu, Haijun; Song, Guofeng

    2017-05-01

    We propose a resonant cavity enhanced (RCE) N-structure type-II superlattice (T2SL) mid-wavelength infrared (MWIR) photodetector which can be used for the detection of methane gas at 3.3 μm. The theoretical analysis of quantum efficiency (QE) shows that the peak QE can be enhanced from 0.45 to 0.80 at 3.3 μm after 12 period AlAs0.09Sb0.91/GaSb DBR is introduced to the N-structure T2SL detector and QE exhibits the narrow bandwidth characteristic near the target wavelength. By analyzing the refractive indices of different materials and the reflectance of different DBRs, we also discuss how to determine the component materials of quarter-wavelength DBR reflectors.

  4. Cavity enhanced terahertz modulation

    SciTech Connect

    Born, N.; Scheller, M.; Moloney, J. V.; Koch, M.

    2014-03-10

    We present a versatile concept for all optical terahertz (THz) amplitude modulators based on a Fabry-Pérot semiconductor cavity design. Employing the high reflectivity of two parallel meta-surfaces allows for trapping selected THz photons within the cavity and thus only a weak optical modulation of the semiconductor absorbance is required to significantly damp the field within the cavity. The optical switching yields to modulation depths of more than 90% with insertion efficiencies of 80%.

  5. Interfacing a quantum dot with a spontaneous parametric down-conversion source

    NASA Astrophysics Data System (ADS)

    Huber, Tobias; Prilmüller, Maximilian; Sehner, Michael; Solomon, Glenn S.; Predojević, Ana; Weihs, Gregor

    2017-09-01

    Quantum networks require interfacing stationary and flying qubits. These flying qubits are usually nonclassical states of light. Here we consider two of the leading source technologies for nonclassical light, spontaneous parametric down-conversion and single semiconductor quantum dots. Down-conversion delivers high-grade entangled photon pairs, whereas quantum dots excel at producing single photons. We report on an experiment that joins these two technologies and investigates the conditions under which optimal interference between these dissimilar light sources may be achieved.

  6. Cavity-enhanced resonant photoacoustic spectroscopy with optical feedback cw diode lasers: A novel technique for ultratrace gas analysis and high-resolution spectroscopy.

    PubMed

    Hippler, Michael; Mohr, Christian; Keen, Katherine A; McNaghten, Edward D

    2010-07-28

    Cavity-enhanced resonant photoacoustic spectroscopy with optical feedback cw diode lasers (OF-CERPAS) is introduced as a novel technique for ultratrace gas analysis and high-resolution spectroscopy. In the scheme, a single-mode cw diode laser (3 mW, 635 nm) is coupled into a high-finesse linear cavity and stabilized to the cavity by optical feedback. Inside the cavity, a build-up of laser power to at least 2.5 W occurs. Absorbing gas phase species inside the cavity are detected with high sensitivity by the photoacoustic effect using a microphone embedded in the cavity. To increase sensitivity further, coupling into the cavity is modulated at a frequency corresponding to a longitudinal resonance of an organ pipe acoustic resonator (f=1.35 kHz and Q approximately 10). The technique has been characterized by measuring very weak water overtone transitions near 635 nm. Normalized noise-equivalent absorption coefficients are determined as alpha approximately 4.4x10(-9) cm(-1) s(1/2) (1 s integration time) and 2.6x10(-11) cm(-1) s(1/2) W (1 s integration time and 1 W laser power). These sensitivities compare favorably with existing state-of-the-art techniques. As an advantage, OF-CERPAS is a "zero-background" method which increases selectivity and sensitivity, and its sensitivity scales with laser power.

  7. Cavity-enhanced resonant photoacoustic spectroscopy with optical feedback cw diode lasers: A novel technique for ultratrace gas analysis and high-resolution spectroscopy

    NASA Astrophysics Data System (ADS)

    Hippler, Michael; Mohr, Christian; Keen, Katherine A.; McNaghten, Edward D.

    2010-07-01

    Cavity-enhanced resonant photoacoustic spectroscopy with optical feedback cw diode lasers (OF-CERPAS) is introduced as a novel technique for ultratrace gas analysis and high-resolution spectroscopy. In the scheme, a single-mode cw diode laser (3 mW, 635 nm) is coupled into a high-finesse linear cavity and stabilized to the cavity by optical feedback. Inside the cavity, a build-up of laser power to at least 2.5 W occurs. Absorbing gas phase species inside the cavity are detected with high sensitivity by the photoacoustic effect using a microphone embedded in the cavity. To increase sensitivity further, coupling into the cavity is modulated at a frequency corresponding to a longitudinal resonance of an organ pipe acoustic resonator (f =1.35 kHz and Q ≈10). The technique has been characterized by measuring very weak water overtone transitions near 635 nm. Normalized noise-equivalent absorption coefficients are determined as α ≈4.4×10-9 cm-1 s1/2 (1 s integration time) and 2.6×10-11 cm-1 s1/2 W (1 s integration time and 1 W laser power). These sensitivities compare favorably with existing state-of-the-art techniques. As an advantage, OF-CERPAS is a "zero-background" method which increases selectivity and sensitivity, and its sensitivity scales with laser power.

  8. Giant frequency down-conversion of the dancing acoustic bubble

    PubMed Central

    Deymier, P. A.; Keswani, M.; Jenkins, N.; Tang, C.; Runge, K.

    2016-01-01

    We have demonstrated experimentally the existence of a giant frequency down-conversion of the translational oscillatory motion of individual submillimeter acoustic bubbles in water in the presence of a high frequency (500 kHz) ultrasonic standing wave. The frequency of the translational oscillations (~170 Hz) is more than three orders of magnitude smaller than that of the driving acoustic wave. We elucidate the mechanism of this very slow oscillation with an analytical model leading to an equation of translational motion of a bubble taking the form of Mathieu’s equation. This equation illuminates the origin of the giant down conversion in frequency as arising from an unstable equilibrium. We also show that bubbles that form chains along the direction of the acoustic standing wave due to radiation interaction forces exhibit also translation oscillations that form a spectral band. This band extends approximately from 130 Hz up to nearly 370 Hz, a frequency range that is still at least three orders of magnitude lower than the frequency of the driving acoustic wave. PMID:27857217

  9. Giant frequency down-conversion of the dancing acoustic bubble

    NASA Astrophysics Data System (ADS)

    Deymier, P. A.; Keswani, M.; Jenkins, N.; Tang, C.; Runge, K.

    2016-11-01

    We have demonstrated experimentally the existence of a giant frequency down-conversion of the translational oscillatory motion of individual submillimeter acoustic bubbles in water in the presence of a high frequency (500 kHz) ultrasonic standing wave. The frequency of the translational oscillations (~170 Hz) is more than three orders of magnitude smaller than that of the driving acoustic wave. We elucidate the mechanism of this very slow oscillation with an analytical model leading to an equation of translational motion of a bubble taking the form of Mathieu’s equation. This equation illuminates the origin of the giant down conversion in frequency as arising from an unstable equilibrium. We also show that bubbles that form chains along the direction of the acoustic standing wave due to radiation interaction forces exhibit also translation oscillations that form a spectral band. This band extends approximately from 130 Hz up to nearly 370 Hz, a frequency range that is still at least three orders of magnitude lower than the frequency of the driving acoustic wave.

  10. Photon-added coherent states in parametric down-conversion

    SciTech Connect

    Sivakumar, S.

    2011-03-15

    Photon-added coherent states have been realized in optical parametric down-conversion by Zavatta et al. [Science 306, 660 (2004)]. In this report, it is established that the states generated in the process are ideal photon-added coherent states. It is shown that the scheme can generate higher-order photon-added coherent states. A comparative study of the down-conversion process and atom-cavity interaction in generating the photon-added coherent states is presented.

  11. Analysis of the possibility of analog detectors calibration by exploiting stimulated parametric down conversion.

    PubMed

    Brida, Giorgio; Chekhova, Maria; Genovese, Marco; Ruo-Berchera, Ivano

    2008-08-18

    Spontaneous parametric down conversion (SPDC) has been largely exploited as a tool for absolute calibration of photon-counting detectors, i.e detectors registering very small photon fluxes. In [J. Opt. Soc. Am. B 23, 2185 (2006)] we derived a method for absolute calibration of analog detectors using SPDC emission at higher photon fluxes, where the beam is seen as a continuum by the detector. Nevertheless intrinsic limitations appear when high-gain regime of SPDC is required to reach even larger photon fluxes. Here we show that stimulated parametric down conversion allow one to avoid this limitation, since stimulated photon fluxes are increased by the presence of the seed beam.

  12. Cavity Enhanced Velocity Modulation Spectroscopy

    NASA Astrophysics Data System (ADS)

    Siller, Brian; Mills, Andrew; Porambo, Michael; McCall, Benjamin

    2010-11-01

    Over the past several decades, velocity modulation spectroscopy has been used to study dozens of molecular ions of astronomical importance. This technique has been so productive because it provides the advantage of ion-neutral discrimination, which is critically important when interfering neutral molecules are many orders of magnitude more abundant, and when combined with heterodyne techniques, its sensitivity can approach the shot noise limit. Traditionally, velocity modulation experiments have utilized unidirectional multipass White cells to achieve up to about 8 passes through a positive column discharge cell. But by positioning the cell within an optical cavity, it is possible to obtain an effective path length orders of magnitude longer than was previously possible. We have demonstrated this novel technique using a Ti:Sapp laser in the near-IR to observe rovibronic transitions of N2+. By demodulating at twice the modulation frequency, 2nd derivative-like lineshapes are observed for ions that are velocity-modulated, while Gaussian lineshapes are observed for excited neutral that are concentration-modulated. The signals for N2+ and N2+* have been observed to be 78° out of phase with one another, so ion-neutral discrimination is retained. And due to the laser power enhancement and geometry of the optical cavity, Doppler-free saturation spectroscopy is now possible. Observed Lamb dips have widths of 50 MHz, and when combined with calibration by an optical frequency comb, this allows for determination of line centers to within 1 MHz. In our original demonstration of this technique, our sensitivity was limited by noise in the laser-cavity lock. Since then, we have integrated Noise Immune Cavity Enhanced Optical Heterodyne Molecular Spectroscopy (NICE-OHMS) by adding sidebands to the laser at an exact multiple of the cavity free spectral range, and demodulating at the sideband frequency before sending the signal to a lock-in amplifier for demodulating at twice the

  13. Cavity-enhanced spectroscopy in optical fibers.

    PubMed

    Gupta, Manish; Jiao, Hong; O'Keefe, Anthony

    2002-11-01

    Cavity-enhanced methods have been extended to fiber optics by use of fiber Bragg gratings (FBGs) as reflectors. High-finesse fiber cavities were fabricated from FBGs made in both germanium/boron-co-doped photosensitive fiber and hydrogen-loaded Corning SMF-28 fiber. Optical losses in these cavities were determined from the measured Fabry-Perot transmission spectra and cavity ring-down spectroscopy. For a 10-m-long single-mode fiber cavity, ring-down times in excess of 2 ms were observed at 1563.6 nm, and individual laser pulses were resolved. An evanescent-wave access block was produced within a fiber cavity, and an enhanced sensitivity to optical loss was observed as the external medium's refractive index was altered.

  14. Atmospheric Measurements by Cavity Enhanced Absorption Spectroscopy

    NASA Astrophysics Data System (ADS)

    Yi, Hongming; Wu, Tao; Coeur-Tourneur, Cécile; Fertein, Eric; Gao, Xiaoming; Zhao, Weixiong; Zhang, Weijun; Chen, Weidong

    2015-04-01

    Since the last decade, atmospheric environmental monitoring has benefited from the development of novel spectroscopic measurement techniques owing to the significant breakthroughs in photonic technology from the UV to the infrared spectral domain [1]. In this presentation, we will overview our recent development and applications of cavity enhanced absorption spectroscopy techniques for in situ optical monitoring of chemically reactive atmospheric species (such as HONO, NO3, NO2, N2O5) in intensive campaigns [2] and/or in smog chamber studies [3]. These field deployments demonstrated that modern photonic technologies (newly emergent light sources combined with high sensitivity spectroscopic techniques) can provide a useful tool to improve our understanding of tropospheric chemical processes which affect climate, air quality, and the spread of pollution. Experimental detail and preliminary results will be presented. Acknowledgements. The financial support from the French Agence Nationale de la Recherche (ANR) under the NexCILAS (ANR-11-NS09-0002) and the CaPPA (ANR-10-LABX-005) contracts is acknowledged. References [1] X. Cui, C. Lengignon, T. Wu, W. Zhao, G. Wysocki, E. Fertein, C. Coeur, A. Cassez,L. Croisé, W. Chen, et al., "Photonic Sensing of the Atmosphere by absorption spectroscopy", J. Quant. Spectrosc. Rad. Transfer 113 (2012) 1300-1316 [2] T. Wu, Q. Zha, W. Chen, Z. XU, T. Wang, X. He, "Development and deployment of a cavity enhanced UV-LED spectrometer for measurements of atmospheric HONO and NO2 in Hong Kong", Atmos. Environ. 95 (2014) 544-551 [3] T. Wu, C. Coeur-Tourneur, G. Dhont,A. Cassez, E. Fertein, X. He, W. Chen,"Application of IBBCEAS to kinetic study of NO3 radical formation from O3 + NO2 reaction in an atmospheric simulation chamber", J. Quant. Spectrosc. Rad. Transfer 133 (2014)199-205

  15. Generalized parametric down conversion, many particle interferometry, and Bell's theorem

    NASA Technical Reports Server (NTRS)

    Choi, Hyung Sup

    1992-01-01

    A new field of multi-particle interferometry is introduced using a nonlinear optical spontaneous parametric down conversion (SPDC) of a photon into more than two photons. The study of SPDC using a realistic Hamiltonian in a multi-mode shows that at least a low conversion rate limit is possible. The down converted field exhibits many stronger nonclassical phenomena than the usual two photon parametric down conversion. Application of the multi-particle interferometry to a recently proposed many particle Bell's theorem on the Einstein-Podolsky-Rosen problem is given.

  16. New Developments of Broadband Cavity Enhanced Spectroscopic Techniques

    NASA Astrophysics Data System (ADS)

    Walsh, A.; Zhao, D.; Linnartz, H.; Ubachs, W.

    2013-06-01

    In recent years, cavity enhanced spectroscopic techniques, such as cavity ring-down spectroscopy (CRDS), cavity enhanced absorption spectroscopy (CEAS), and broadband cavity enhanced absorption spectroscopy (BBCEAS), have been widely employed as ultra-sensitive methods for the measurement of weak absorptions and in the real-time detection of trace species. In this contribution, we introduce two new cavity enhanced spectroscopic concepts: a) Optomechanical shutter modulated BBCEAS, a variant of BBCEAS capable of measuring optical absorption in pulsed systems with typically low duty cycles. In conventional BBCEAS applications, the latter substantially reduces the signal-to-noise ratio (S/N), consequently also reducing the detection sensitivity. To overcome this, we incorporate a fast optomechanical shutter as a time gate, modulating the detection scheme of BBCEAS and increasing the effective duty cycle reaches a value close to unity. This extends the applications of BBCEAS into pulsed samples and also in time-resolved studies. b) Cavity enhanced self-absorption spectroscopy (CESAS), a new spectroscopic concept capable of studying light emitting matter (plasma, flames, combustion samples) simultaneously in absorption and emission. In CESAS, a sample (plasma, flame or combustion source) is located in an optically stable cavity consisting of two high reflectivity mirrors, and here it acts both as light source and absorbing medium. A high detection sensitivity of weak absorption is reached without the need of an external light source, such as a laser or broadband lamp. The performance is illustrated by the first CESAS result on a supersonically expanding hydrocarbon plasma. We expect CESAS to become a generally applicable analytical tool for real time and in situ diagnostics. A. Walsh, D. Zhao, W. Ubachs, H. Linnartz, J. Phys. Chem. A, {dx.doi.org/10.1021/jp310392n}, in press, 2013. A. Walsh, D. Zhao, H. Linnartz Rev. Sci. Instrum. {84}(2), 021608 2013. A. Walsh, D. Zhao

  17. Cavity-enhanced absorption spectroscopy with a ps-pulsed UV laser for sensitive, high-speed measurements in a shock tube.

    PubMed

    Wang, Shengkai; Sun, Kai; Davidson, David F; Jeffries, Jay B; Hanson, Ronald K

    2016-01-11

    We report the first application of cavity-enhanced absorption spectroscopy (CEAS) with a ps-pulsed UV laser for sensitive and rapid gaseous species time-history measurements in a transient environment (in this study, a shock tube). The broadband nature of the ps pulses enabled instantaneous coupling of the laser beam into roughly a thousand cavity modes, which grants excellent immunity to laser-cavity coupling noise in environments with heavy vibrations, even with an on-axis alignment. In this proof-of-concept experiment, we demonstrated an absorption gain of 49, which improved the minimum detectable absorbance by ~20 compared to the conventional single-pass strategy at similar experimental conditions. For absorption measurements behind reflected shock waves, an effective time-resolution of ~2 μs was achieved, which enabled time-resolved observations of transient phenomena, such as the vibrational relaxation of O(2) demonstrated here. The substantial improvement in detection sensitivity, together with microsecond measurement resolution implies excellent potential for studies of transient physical and chemical processes in nonequilibrium situations, particularly via measurements of weak absorptions of trace species in dilute reactive systems.

  18. Heralding Pure Single Photons Generated with Spontaneous Parametric Down Conversion

    NASA Astrophysics Data System (ADS)

    Liu, Xue-lin; Xiang, Tong; Chen, Xian-feng

    2017-09-01

    We investigate the possibility of generated heralding single photons via spontaneous parametric down conversion using periodically poled lithium niobate crystals with different phase-matching. We use the Schmidt decomposition to calculate the degree of entanglement of photon pairs We simulated the spectral purity, bandwidth, and the joint spectral intensity pictures of degenerate and non-degenerate photon pairs. At last, we obtain an ideal condition of the counter-propagating photons, which can be applied in the quantum communication.

  19. Heralding Pure Single Photons Generated with Spontaneous Parametric Down Conversion

    NASA Astrophysics Data System (ADS)

    Liu, Xue-lin; Xiang, Tong; Chen, Xian-feng

    2017-06-01

    We investigate the possibility of generated heralding single photons via spontaneous parametric down conversion using periodically poled lithium niobate crystals with different phase-matching. We use the Schmidt decomposition to calculate the degree of entanglement of photon pairs We simulated the spectral purity, bandwidth, and the joint spectral intensity pictures of degenerate and non-degenerate photon pairs. At last, we obtain an ideal condition of the counter-propagating photons, which can be applied in the quantum communication.

  20. The role of spatial and temporal modes in pulsed parametric down-conversion.

    PubMed

    Yorulmaz, S C; van Exter, M P; de Dood, M J A

    2014-03-10

    We explore spatial correlations created by stimulated pair emission in frequency degenerate parametric down-conversion from a periodically poled KTP crystal pumped by ∼2 ps duration laser pulses. The ratio of stimulated pairs over spontaneous pairs reaches as high 0.8 in the experiment. This ratio is a direct measure of the total number of modes relevant to the down-conversion process. We identify a universal curve for this ratio that accounts for the effect of the focused pump, introducing a coherence diameter r(0) related to the diffraction limited size of the pump beam in the far-field. Measurements of the spatial correlations of the PDC light for longer crystals and tight focusing conditions show that the description given in terms of a universal curve is surprisingly robust and breaks down only for a laser beam focussed to a waist smaller than 40 μm in a 2 mm long PPKTP crystal.

  1. Long Wave Infrared Cavity Enhanced Sensors

    SciTech Connect

    Taubman, Matthew S.; Scott, David C.; Cannon, Bret D.; Myers, Tanya L.; Bonebrake, Christopher A.; Aker, Pam M.; Wojcik, Michael D.; Munley, John T.; Nguyen, Vinh T.; Schultz, John F.

    2004-10-01

    The principal goal of Pacific Northwest National Laboratory's (PNNL's) long wave infrared (LWIR) cavity enhanced sensor (CES) project is to explore ultra-sensitive spectroscopic techniques and apply them to the development of LWIR chemical sensors needed for detecting weapons proliferation. This includes detecting not only the weapons of mass destruction (WMDs) themselves, but also signatures of their production and/or detonation. The LWIR CES project is concerned exclusively with developing point sensors; other portions of PNNL's IR Sensors program address stand off detection. PNNL's LWIR CES research is distinguished from that done by others by the use quantum cascade lasers (QCLs) as the light source. QCLs are novel devices, and a significant fraction of our research has been devoted to developing the procedures and hardware required to implement them most effectively for chemical sensing. This report details the progress we have made on our LWIR CES sensor development. During FY02, PNNL investigated three LWIR CES implementations beginning with the easiest to implement, direct cavity-enhanced detection (simple CES), including a technique of intermediate difficulty, cavity-dithered phase-sensitive detection (FM recovery CES) through to the most complex technique, that of resonant sideband cavity-enhanced detection also known as noise-immune cavity-enhanced optical heterodyne molecular spectroscopy, or NICE-OHMS.

  2. Analysis of a four-mirror-cavity enhanced Michelson interferometer.

    PubMed

    Thüring, André; Lück, Harald; Danzmann, Karsten

    2005-12-01

    We investigate the shot-noise-limited sensitivity of a four-mirror-cavity enhanced Michelson interferometer. The intention of this interferometer topology is the reduction of thermal lensing and the impact of the interferometers contrast although transmissive optics are used with high circulating powers. The analytical expressions describing the light fields and the frequency response are derived. Although the parameter space has 11 dimensions, a detailed analysis of the resonance feature gives boundary conditions allowing systematic parameter studies.

  3. Cavity Enhanced Velocity Modulation Spectroscopy

    NASA Astrophysics Data System (ADS)

    Siller, Brian; Mills, Andrew; McCall, Benjamin J.

    2010-06-01

    Velocity modulation spectroscopy has traditionally been used with a unidirectional multipass White cell to obtain several passes through a plasma in order to obtain strong signals from the absorption of ions, but the total number of passes allowed by this type of setup is limited to ˜8. By placing an optical cavity around an N_2^+ plasma and locking the cavity to a Ti:Sapphire laser, the effective number of passes has been increased to several hundred. Demodulating the signal from the transmitted light at twice the plasma frequency (due to the symmetric nature of the cavity) gives a 2nd derivative lineshape for ions and a Gaussian lineshape for excited neutrals. N_2^+ and N_2^* have been observed to be 78° out of phase with one another. The different lineshapes and phases allow for discrimination and separation of the ion and neutral signals. The high intensity laser light within the cavity causes the transitions to saturate, which allows for the observation of lamb dips; this opens the door to sub-Doppler spectroscopy, as well as to studies of ion-neutral collisional rate coefficients.

  4. Unity-Efficiency Parametric Down-Conversion via Amplitude Amplification

    NASA Astrophysics Data System (ADS)

    Niu, Murphy Yuezhen; Sanders, Barry C.; Wong, Franco N. C.; Shapiro, Jeffrey H.

    2017-03-01

    We propose an optical scheme, employing optical parametric down-converters interlaced with nonlinear sign gates (NSGs), that completely converts an n -photon Fock-state pump to n signal-idler photon pairs when the down-converters' crystal lengths are chosen appropriately. The proof of this assertion relies on amplitude amplification, analogous to that employed in Grover search, applied to the full quantum dynamics of single-mode parametric down-conversion. When we require that all Grover iterations use the same crystal, and account for potential experimental limitations on crystal-length precision, our optimized conversion efficiencies reach unity for 1 ≤n ≤5 , after which they decrease monotonically for n values up to 50, which is the upper limit of our numerical dynamics evaluations. Nevertheless, our conversion efficiencies remain higher than those for a conventional (no NSGs) down-converter.

  5. Silicon resonant cavity enhanced photodetector arrays for optical interconnects

    NASA Astrophysics Data System (ADS)

    Emsley, Matthew Kent

    High bandwidth short distance communications standards are being developed based on parallel optical interconnect fiber arrays to meet the needs of increasing data rates of inter-chip communication in modern computer architecture. To ensure that this standard becomes an attractive option for computer systems, low cost components must be implemented on both the transmitting and receiving end of the fibers. To meet this low cost requirement silicon based receiver circuits are the most viable option, however, manufacturing high speed, high efficiency silicon photodetectors presents a technical challenge. Resonant cavity enhanced photodetectors have been shown to provide the required bandwidth-efficiency product but have remained a challenge to reproduce through commercially available fabrication techniques. In this work, commercially reproducible silicon wafers with a high reflectance buried distributed Bragg reflector (DBR) have been designed and fabricated. The substrates consist of a two-period, 90% reflecting, DBR fabricated using a double silicon-on-insulator (SOI) process. Resonant-cavity-enhanced (RCE) Si photodetectors have been fabricated with 40% quantum efficiency at 860 nm, a FWHM of 25 ps, and a 3dB bandwidth in excess of 10 GHz. Si RCE 12 x 1 photodetector arrays have been fabricated and packaged with silicon based amplifiers to demonstrate the feasibility of a low cost monolithic silicon photoreceiver array.

  6. Long Wave Infrared Cavity Enhanced Sensors

    SciTech Connect

    Taubman, Matthew S.; Scott, David C.; Cannon, Bret D.; Myers, Tanya L.; Munley, John T.; Nguyen, Vinh T.; Schultz, John F.

    2005-12-01

    The principal goal of Pacific Northwest National Laboratory's (PNNL's) long wave infrared (LWIR) cavity enhanced sensor (CES) task is to explore ultra-sensitive spectroscopic chemical sensing techniques and apply them to detecting proliferation of weapons of mass destruction (WMD). Our primary application is detecting signatures of WMD production, but LWIR CES techniques are also capable of detecting chemical weapons. The LWIR CES task is concerned exclusively with developing novel point sensors; stand-off detection is addressed by other PNNL tasks and projects. PNNL's LWIR CES research is distinguished from that done by others by the use quantum cascade lasers (QCLs) as the light source. QCLs are novel devices, and a significant fraction of our research has been devoted to developing the procedures and hardware required to implement them most effectively for chemical sensing. This report details the progress we have made on LWIR CES sensor development.

  7. Pure down-conversion photons through sub-coherence-length domain engineering

    NASA Astrophysics Data System (ADS)

    Graffitti, Francesco; Kundys, Dmytro; Reid, Derryck T.; Brańczyk, Agata M.; Fedrizzi, Alessandro

    2017-09-01

    Photonic quantum technology relies on efficient sources of coherent single photons, the ideal carriers of quantum information. Heralded single photons from parametric down-conversion can approximate on-demand single photons to a desired degree, with high spectral purities achieved through group-velocity matching and tailored crystal nonlinearities. Here we propose crystal-nonlinearity-engineering techniques with sub-coherence-length domains. We first introduce a combination of two existing methods: a deterministic approach with coherence-length domains and probabilistic domain-width annealing. We then show how the same deterministic domain-flip approach can be implemented with sub-coherence-length domains. Both of these complementary techniques create highly pure photons, outperforming previous methods, in particular for short nonlinear crystals matched to femtosecond lasers.

  8. Cavity-enhanced ultrafast two-dimensional spectroscopy using higher order modes

    NASA Astrophysics Data System (ADS)

    Allison, Thomas K.

    2017-02-01

    We describe methods using frequency combs and optical resonators for recording two-dimensional (2D) ultrafast spectroscopy signals with high sensitivity. By coupling multiple frequency combs to higher-order modes of one or more optical cavities, background-free, cavity-enhanced 2D spectroscopy signals are naturally generated via phase cycling. As in cavity-enhanced ultrafast transient absorption spectroscopy, the signal to noise is enhanced by a factor proportional to the cavity finesse squared, so even using cavities of modest finesse, a very high sensitivity is expected, enabling ultrafast 2D spectroscopy experiments in dilute molecular beams.

  9. Characterization of periodically poled LiTaO3 crystals by means of spontaneous parametric down-conversion

    NASA Astrophysics Data System (ADS)

    Kuznetsov, K. A.; Guo, H. C.; Kitaeva, Gs. Kh.; Ezhov, A. A.; Muzychenko, D. A.; Penin, A. N.; Tang, S. H.

    2006-05-01

    We describe the observation of quasi-phase-matched spontaneous parametric down-conversion in eee-geometry in periodically poled LiTaO3 crystals. For scattered light, the two-dimensional angular-frequency intensity distribution was studied. Several detuning curves were recorded, corresponding to high orders m=-2, -3, -4, -5 of quasi-phase matching. The measured periods of domain gratings agree with the data obtained by atomic-force microscopy for the etched crystal surfaces. The presence of both odd and even orders indicates that the lengths of positive and negative domains are unequal. To determine the mean duty cycle for regular domain gratings we propose comparing of the intensities of spontaneous parametric down-conversion in different orders of quasi-phase-matching.

  10. Silicon coding-decoding photonic device by electron irradiation and light down conversion

    NASA Astrophysics Data System (ADS)

    Malyutenko, V. K.; Tykhonov, A. N.; Malyutenko, O. Yu.; Rohutskii, I. S.; Danilchenko, B. A.

    2012-10-01

    We propose and demonstrate a coding-decoding procedure as an important step to realize one more Si-based photonic device. Low-fluence (<1014 e/cm2) high-energy (1 MeV) electron irradiation of a bulk Si matrix is used to code an information by forming local regions with lower free carrier lifetime that are hidden under the surface and invisible to the eye. Short-wavelength (<1 μm) free carrier generation stands for multiple, remote, and nondestructive decoding process, which makes it easy to dynamically (ms range) visualize a code by capturing two-dimensional pattern of thermal emission in the longer-wavelength (3-12 μm) band (light down conversion).

  11. Multi-copy entanglement purification with practical spontaneous parametric down conversion sources

    NASA Astrophysics Data System (ADS)

    Zhang, Shuai-Shuai; Shu, Qi; Zhou, Lan; Sheng, Yu-Bo

    2017-06-01

    Entanglement purification is to distill the high quality entanglement from the low quality entanglement with local operations and classical communications. It is one of the key technologies in long-distance quantum communication. We discuss an entanglement purification protocol (EPP) with spontaneous parametric down conversion (SPDC) sources, in contrast to previous EPP with multi-copy mixed states, which requires ideal entanglement sources. We show that the SPDC source is not an obstacle for purification, but can benefit the fidelity of the purified mixed state. This EPP works for linear optics and is feasible in current experiment technology. Project supported by the National Natural Science Foundation of China (Grant Nos. 11474168 and 61401222), the Natural Science Foundation of Jiangsu Province, China (Grant No. BK20151502), the Qing Lan Project in Jiangsu Province, China, and a Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions, China.

  12. Parameter estimation with entangled photons produced by parametric down-conversion.

    PubMed

    Cable, Hugo; Durkin, Gabriel A

    2010-07-02

    We explore the advantages offered by twin light beams produced in parametric down-conversion for precision measurement. The symmetry of these bipartite quantum states, even under losses, suggests that monitoring correlations between the divergent beams permits a high-precision inference of any symmetry-breaking effect, e.g., fiber birefringence. We show that the quantity of entanglement is not the key feature for such an instrument. In a lossless setting, scaling of precision at the ultimate "Heisenberg" limit is possible with photon counting alone. Even as photon losses approach 100% the precision is shot-noise limited, and we identify the crossover point between quantum and classical precision as a function of detected flux. The predicted hypersensitivity is demonstrated with a Bayesian simulation.

  13. Parameter Estimation with Entangled Photons Produced by Parametric Down-Conversion

    NASA Technical Reports Server (NTRS)

    Cable, Hugo; Durkin, Gabriel A.

    2010-01-01

    We explore the advantages offered by twin light beams produced in parametric down-conversion for precision measurement. The symmetry of these bipartite quantum states, even under losses, suggests that monitoring correlations between the divergent beams permits a high-precision inference of any symmetry-breaking effect, e.g., fiber birefringence. We show that the quantity of entanglement is not the key feature for such an instrument. In a lossless setting, scaling of precision at the ultimate "Heisenberg" limit is possible with photon counting alone. Even as photon losses approach 100% the precision is shot-noise limited, and we identify the crossover point between quantum and classical precision as a function of detected flux. The predicted hypersensitivity is demonstrated with a Bayesian simulation.

  14. Parameter Estimation with Entangled Photons Produced by Parametric Down-Conversion

    SciTech Connect

    Cable, Hugo; Durkin, Gabriel A.

    2010-07-02

    We explore the advantages offered by twin light beams produced in parametric down-conversion for precision measurement. The symmetry of these bipartite quantum states, even under losses, suggests that monitoring correlations between the divergent beams permits a high-precision inference of any symmetry-breaking effect, e.g., fiber birefringence. We show that the quantity of entanglement is not the key feature for such an instrument. In a lossless setting, scaling of precision at the ultimate ''Heisenberg'' limit is possible with photon counting alone. Even as photon losses approach 100% the precision is shot-noise limited, and we identify the crossover point between quantum and classical precision as a function of detected flux. The predicted hypersensitivity is demonstrated with a Bayesian simulation.

  15. Optical down-conversion in doped ZnSe:Tb3+ nanocrystals.

    PubMed

    Das, Sandip; Mandal, Krishna C

    2013-02-07

    Rare earth (RE) Tb(3+)-doped high quality ZnSe nanocrystals (NCs) were synthesized by a facile chemical hot-injection method. ZnSe:Tb(3+) nanocrystals exhibited broadband absorption below the first excitonic absorption peak. Photoluminescence spectra showed Tb(3+) emission lines in the visible spectral window at room temperature when excited by UV radiation below the band-edge of the host ZnSe nanocrystals. Our experimental results indicate optical down-conversion in these Tb(3+)-doped Zn-chalcogenide nanocrystals via energy migration from host ZnSe to the Tb(3+) dopant. The host-dopant energy transfer mechanism for this ZnSe:Tb(3+) nanocrystal system is correlated with the emission spectra.

  16. Parameter Estimation with Entangled Photons Produced by Parametric Down-Conversion

    NASA Technical Reports Server (NTRS)

    Cable, Hugo; Durkin, Gabriel A.

    2010-01-01

    We explore the advantages offered by twin light beams produced in parametric down-conversion for precision measurement. The symmetry of these bipartite quantum states, even under losses, suggests that monitoring correlations between the divergent beams permits a high-precision inference of any symmetry-breaking effect, e.g., fiber birefringence. We show that the quantity of entanglement is not the key feature for such an instrument. In a lossless setting, scaling of precision at the ultimate "Heisenberg" limit is possible with photon counting alone. Even as photon losses approach 100% the precision is shot-noise limited, and we identify the crossover point between quantum and classical precision as a function of detected flux. The predicted hypersensitivity is demonstrated with a Bayesian simulation.

  17. Microwave down-conversion with an impedance-matched Λ system in driven circuit QED.

    PubMed

    Inomata, K; Koshino, K; Lin, Z R; Oliver, W D; Tsai, J S; Nakamura, Y; Yamamoto, T

    2014-08-08

    By driving a dispersively coupled qubit-resonator system, we realize an "impedance-matched" Λ system that has two identical radiative decay rates from the top level and interacts with a semi-infinite waveguide. It has been predicted that a photon input from the waveguide deterministically induces a Raman transition in the system and switches its electronic state. We confirm this through microwave response to a continuous probe field, observing near-perfect (99.7%) extinction of the reflection and highly efficient (74%) frequency down-conversion. These proof-of-principle results lead to deterministic quantum gates between material qubits and microwave photons and open the possibility for scalable quantum networks interconnected with waveguide photons.

  18. Cavity-enhanced resonant tunneling photodetector at telecommunication wavelengths

    SciTech Connect

    Pfenning, Andreas Hartmann, Fabian; Langer, Fabian; Höfling, Sven; Kamp, Martin; Worschech, Lukas

    2014-03-10

    An AlGaAs/GaAs double barrier resonant tunneling diode (RTD) with a nearby lattice-matched GaInNAs absorption layer was integrated into an optical cavity consisting of five and seven GaAs/AlAs layers to demonstrate cavity enhanced photodetection at the telecommunication wavelength 1.3 μm. The samples were grown by molecular beam epitaxy and RTD-mesas with ring-shaped contacts were fabricated. Electrical and optical properties were investigated at room temperature. The detector shows maximum photocurrent for the optical resonance at a wavelength of 1.29 μm. At resonance a high sensitivity of 3.1×10{sup 4} A/W and a response up to several pA per photon at room temperature were found.

  19. Cavity-enhanced Raman microscopy of individual carbon nanotubes.

    PubMed

    Hümmer, Thomas; Noe, Jonathan; Hofmann, Matthias S; Hänsch, Theodor W; Högele, Alexander; Hunger, David

    2016-07-12

    Raman spectroscopy reveals chemically specific information and provides label-free insight into the molecular world. However, the signals are intrinsically weak and call for enhancement techniques. Here, we demonstrate Purcell enhancement of Raman scattering in a tunable high-finesse microcavity, and utilize it for molecular diagnostics by combined Raman and absorption imaging. Studying individual single-wall carbon nanotubes, we identify crucial structural parameters such as nanotube radius, electronic structure and extinction cross-section. We observe a 320-times enhanced Raman scattering spectral density and an effective Purcell factor of 6.2, together with a collection efficiency of 60%. Potential for significantly higher enhancement, quantitative signals, inherent spectral filtering and absence of intrinsic background in cavity-vacuum stimulated Raman scattering render the technique a promising tool for molecular imaging. Furthermore, cavity-enhanced Raman transitions involving localized excitons could potentially be used for gaining quantum control over nanomechanical motion and open a route for molecular cavity optomechanics.

  20. Cavity-enhanced Raman microscopy of individual carbon nanotubes

    NASA Astrophysics Data System (ADS)

    Hümmer, Thomas; Noe, Jonathan; Hofmann, Matthias S.; Hänsch, Theodor W.; Högele, Alexander; Hunger, David

    2016-07-01

    Raman spectroscopy reveals chemically specific information and provides label-free insight into the molecular world. However, the signals are intrinsically weak and call for enhancement techniques. Here, we demonstrate Purcell enhancement of Raman scattering in a tunable high-finesse microcavity, and utilize it for molecular diagnostics by combined Raman and absorption imaging. Studying individual single-wall carbon nanotubes, we identify crucial structural parameters such as nanotube radius, electronic structure and extinction cross-section. We observe a 320-times enhanced Raman scattering spectral density and an effective Purcell factor of 6.2, together with a collection efficiency of 60%. Potential for significantly higher enhancement, quantitative signals, inherent spectral filtering and absence of intrinsic background in cavity-vacuum stimulated Raman scattering render the technique a promising tool for molecular imaging. Furthermore, cavity-enhanced Raman transitions involving localized excitons could potentially be used for gaining quantum control over nanomechanical motion and open a route for molecular cavity optomechanics.

  1. Cavity enhanced telecom heralded single photons for spin-wave solid state quantum memories

    NASA Astrophysics Data System (ADS)

    Rieländer, Daniel; Lenhard, Andreas; Mazzera, Margherita; de Riedmatten, Hugues

    2016-12-01

    We report on a source of heralded narrowband (≈ 3 MHz) single photons compatible with solid-state spin-wave quantum memories based on praseodymium doped crystals. Widely non-degenerate narrow-band photon pairs are generated using cavity enhanced down conversion. One photon from the pair is at telecom wavelengths and serves as heralding signal, while the heralded single photon is at 606 nm, resonant with an optical transition of Pr3+:Y2SiO5. The source offers a heralding efficiency of 28% and a generation rate exceeding 2000 pairs mW-1 in a single-mode. The single photon nature of the heralded field is confirmed by a direct antibunching measurement, with a measured antibunching parameter down to 0.010(4). Moreover, we investigate in detail photon cross- and autocorrelation functions proving non-classical correlations between the two photons. The results presented in this paper offer prospects for the demonstration of single photon spin-wave storage in an on-demand solid state quantum memory, heralded by a telecom photon.

  2. Low-noise quantum frequency down-conversion of indistinguishable photons (Conference Presentation)

    NASA Astrophysics Data System (ADS)

    Kambs, Benjamin; Kettler, Jan; Bock, Matthias; Becker, Jonas; Arend, Carsten; Jetter, Michael; Michler, Peter; Becher, Christoph

    2016-04-01

    Single-photon sources based on quantum dots have been shown to exhibit almost ideal properties such as high brightness and purity in terms of clear anti-bunching as well as high two-photon interference visibilities of the emitted photons, making them promising candidates for different quantum information applications such as quantum computing, quantum communication and quantum teleportation. However, as most single-photon sources also quantum dots typically emit light at wavelengths of electronic transitions within the visible or the near infrared range. In order to establish quantum networks with remote building blocks, low-loss single photons at telecom wavelengths are preferable, though. Despite recent progress on emitters of telecom-photons, the most efficient single-photon sources still work at shorter wavelengths. On that matter, quantum frequency down-conversion, being a nonlinear optical process, has been used in recent years to alter the wavelength of single photons to the telecom wavelength range while conserving their nonclassical properties. Characteristics such as lifetime, first-order coherence, anti-bunching and entanglement have been shown to be conserved or even improved due to background suppression during the conversion process, while the conservation of indistinguishability was yet to be shown. Here we present our experimental results on quantum frequency down-conversion of single photons emitted by an InAs/GaAs quantum dot at 903.6 nm following a pulsed excitation of a p-shell exciton at 884 nm. The emitted fluorescence photons are mixed with a strong pump-field at 2155 nm inside a periodically poled lithium niobate ridge waveguide and converted to 1557 nm. Common issues of a large background due to Raman-scattered pump-light photons spectrally overlapping with the converted single photons could largely be avoided, as the pump-wavelength was chosen to be fairly longer than the target wavelength. Additional narrowband spectral filtering at the

  3. Noise-Immune Cavity-Enhanced Optical Frequency Comb Spectroscopy

    NASA Astrophysics Data System (ADS)

    Rutkowski, Lucile; Khodabakhsh, Amir; Johanssson, Alexandra C.; Foltynowicz, Aleksandra

    2015-06-01

    We present noise-immune cavity-enhanced optical frequency comb spectroscopy (NICE-OFCS), a recently developed technique for sensitive, broadband, and high resolution spectroscopy. In NICE-OFCS an optical frequency comb (OFC) is locked to a high finesse cavity and phase-modulated at a frequency precisely equal to (a multiple of) the cavity free spectral range. Since each comb line and sideband is transmitted through a separate cavity mode in exactly the same way, any residual frequency noise on the OFC relative to the cavity affects each component in an identical manner. The transmitted intensity contains a beat signal at the modulation frequency that is immune to frequency-to-amplitude noise conversion by the cavity, in a way similar to continuous wave noise-immune cavity-enhanced optical heterodyne molecular spectroscopy (NICE-OHMS). The light transmitted through the cavity is detected with a fast-scanning Fourier-transform spectrometer (FTS) and the NICE-OFCS signal is obtained by fast Fourier transform of the synchronously demodulated interferogram. Our NICE-OFCS system is based on an Er:fiber femtosecond laser locked to a cavity with a finesse of ˜9000 and a fast-scanning FTS equipped with a high-bandwidth commercial detector. We measured NICE-OFCS signals from the 3νb{1}+νb{3} overtone band of CO_2 around 1.57 μm and achieved absorption sensitivity 6.4×10-11cm-1 Hz-1/2 per spectral element, corresponding to a minimum detectable CO_2 concentration of 25 ppb after 330 s integration time. We will describe the principles of the technique and its technical implementation, and discuss the spectral lineshapes of the NICE-OFCS signals. A. Khodabakhsh, C. Abd Alrahman, and A. Foltynowicz, Opt. Lett. 39, 5034-5037 (2014). J. Ye, L. S. Ma, and J. L. Hall, J. Opt. Soc. Am. B 15, 6-15 (1998). A. Khodabakhsh, A. C. Johansson, and A. Foltynowicz, Appl. Phys. B (2015) doi:10.1007/s00340-015-6010-7.

  4. Broadband Comb-Resolved Cavity Enhanced Spectrometer with Graphene Modulator

    NASA Astrophysics Data System (ADS)

    Lee, Kevin; Mohr, Christian; Jiang, Jie; Fermann, Martin; Lee, Chien-Chung; Schibli, Thomas R.; Kowzan, Grzegorz; Maslowski, Piotr

    2015-06-01

    Optical cavities enhance sensitivity in absorption spectroscopy. While this is commonly done with single wavelengths, broad bandwidths can be coupled into the cavity using frequency combs. The combination of cavity enhancement and broad bandwidth allows simultaneous measurement of tens of transitions with high signal-to-noise for even weak near-infrared transitions. This removes the need for time-consuming sequencing acquisition or long-term averaging, so any systematic errors from long-term drifts of the experimental setup or slow changes of sample composition are minimized. Resolving comb lines provides a high accuracy, absolute frequency axis. This is of great importance for gas metrology and data acquisition for future molecular lines databases, and can be applied to simultaneous trace-gas detection of gas mixtures. Coupling of a frequency comb into a cavity can be complex, so we introduce and demonstrate a simplification. The Pound-Drever-Hall method for locking a cavity and a frequency comb together requires a phase modulation of the laser output. We use the graphene modulator that is already in the Tm fiber laser cavity for controlling the carrier envelope offset of the frequency comb, rather than adding a lossy external modulator. The graphene modulator can operate at frequencies of over 1~ MHz, which is sufficient for controlling the laser cavity length actuator which operates below 100~kHz. We match the laser cavity length to fast variations of the enhancement cavity length. Slow variations are stabilized by comparison of the pulse repetition rate to a GPS reference. The carrier envelope offset is locked to a constant value chosen to optimize the transmitted spectrum. The transmitted pulse train is a stable frequency comb suitable for long measurements, including the acquisition of comb-resolved Fourier transform spectra with a minimum absorption coefficient of about 2×10-7 wn. For our 38 cm long enhancement cavity, the comb spacing is 394~MHz. With our

  5. Applications of Cavity-Enhanced Direct Frequency Comb Spectroscopy

    NASA Astrophysics Data System (ADS)

    Cossel, Kevin C.; Adler, Florian; Maslowski, Piotr; Ye, Jun

    2010-06-01

    Cavity-enhanced direct frequency comb spectroscopy (CE-DFCS) is a unique technique that provides broad bandwidth, high resolution, and ultra-high detection sensitivities. This is accomplished by combining a femtosecond laser based optical frequency comb with an enhancement cavity and a broadband, multichannel imaging system. These systems are capable of simultaneously recording many terahertz of spectral bandwidth with sub-gigahertz resolution and absorption sensitivities of 1×10-7 cm-1 Hz-1/2. In addition, the ultrashort pulses enable efficient nonlinear processes, which makes it possible to reach spectral regions that are difficult to access with conventional laser sources. We will present an application of CE-DFCS for trace impurity detection in the semiconductor processing gas arsine near 1.8 μm and the development of a high-power, mid-infrared frequency comb for breath analysis in the 2.8-4.8 μm region. M. J. Thorpe, K. D. Moll, R. J. Jones, B. Safdi, and J. Ye. Science 311, 1595-1599 (2006) F. Adler, M. J. Thorpe, K. C. Cossel, and J. Ye. Annu. Rev. Anal. Chem. 3, 175-205 (2010) F. Adler, K. C. Cossel, M. J. Thorpe, I. Hartl, M. E. Fermann, and J. Ye. Opt. Lett. 34, 1330-1332 (2009)

  6. Silicon resonant-cavity-enhanced photodetector arrays for optical interconnects

    NASA Astrophysics Data System (ADS)

    Emsley, Matthew K.; Dosunmu, Olufemi I.; Muller, Paul; Unlu, M. Selim; Leblebici, Yusuf

    2003-08-01

    High bandwidth short distance communications standards are being developed based on parallel optical interconnect fiber arrays to meet the needs of increasing data rates of inter-chip communication in modern computer architecture. To ensure that this standard becomes an attractive option for computer systems, low cost components must be implemented on both the transmitting and receiving end of the fibers. To meet this low cost requirement silicon based receiver circuits are the most viable option, however, manufacturing high speed, high efficiency silicon photodetectors presents a technical challenge. Resonant cavity enhanced (RCE) Si photodetectors have been shown to provide the required bandwidth-efficiency product and we have recently developed a method to reproduce them through commercially available fabrication techniques. In this work, commercially reproducible silicon wafers with a 90% reflectance buried distributed Bragg reflector (DBR) are used to create Si-RCE photodetector arrays for optical interconnects. The Si-RCE photodetectors have 40% quantum efficiency at 860 nm, a FWHM of 25 ps, and a 3dB bandwidth in excess of 10 GHz. We also demonstrate Si-RCE 12×1 photodetector arrays that have been fabricated and packaged with silicon based amplifiers to demonstrate the feasibility of a low cost monolithic silicon photoreceiver array.

  7. Cavity-enhanced continuous graphene plasmonic resonator for infrared sensing

    NASA Astrophysics Data System (ADS)

    Wei, Wei; Nong, Jinpeng; Zhu, Yong; Tang, Linlong; Zhang, Guiwen; Yang, Jun; Huang, Yu; Wei, Dapeng

    2017-07-01

    We propose a cavity-enhanced resonator based on graphene surface plasmonics for infrared sensing. In such a resonator, a continuous and non-patterned monolayer graphene serves as the sensing medium by exciting surface plasmons on its surface, which can preserve the excellent electronic property of graphene and avoid the interaction between biomolecules and dielectric substrate. To improve its sensing performance, an optical cavity is employed to enhance the coupling of the incident light with the resonator. Simulation results demonstrate that the reflection spectra of the resonator can be modified to be narrower and deeper to improve the figure of merit (FOM) of the device significantly by adjusting the structure parameters of the cavity and the Fermi energy level. The FOM can achieve a high value of up to 20.15 RIU-1, which is about twice larger than that of the traditional structure without a cavity. Furthermore, the resonator can work in a wide angle range of the incident light. Such a plasmonic resonator with excellent features may provide a strategy to engineer graphene-based SPR sensor with high detection accuracy.

  8. Beat note stabilization of a 10-60 GHz dual-polarization microlaser through optical down conversion.

    PubMed

    Rolland, A; Brunel, M; Loas, G; Frein, L; Vallet, M; Alouini, M

    2011-02-28

    Down-conversion of a high-frequency beat note to an intermediate frequency is realized by a Mach-Zehnder intensity modulator. Optically-carried microwave signals in the 10-60 GHz range are synthesized by using a two-frequency solid-state microchip laser as a voltage-controlled oscillator inside a digital phase-locked loop. We report an in-loop relative frequency stability better than 2.5×10⁻¹¹. The principle is applicable to beat notes in the millimeter-wave range.

  9. Real-time multiplexed digital cavity-enhanced spectroscopy

    SciTech Connect

    Boyson, Toby K.; Dagdigian, Paul J.; Pavey, Karl D.; Fitzgerald, Nicholas J.; Spence, Thomas G.; Moore, David S.; Harb, Charles C.

    2015-10-01

    Cavity-enhanced spectroscopy is a sensitive optical absorption technique but one where the practical applications have been limited to studying small wavelength ranges. In addition, this Letter shows that wideband operation can be achieved by combining techniques usually reserved for the communications community with that of cavity-enhanced spectroscopy, producing a multiplexed real-time cavity-enhanced spectrometer. We use multiple collinear laser sources operating asynchronously and simultaneously while being detected on a single photodetector. This is synonymous with radio frequency (RF) cellular systems in which signals are detected on a single antenna but decoded uniquely. Here, we demonstrate results with spectra of methyl salicylate and show parts-per-billion per root hertz sensitivity measured in real-time.

  10. Real-time multiplexed digital cavity-enhanced spectroscopy

    DOE PAGES

    Boyson, Toby K.; Dagdigian, Paul J.; Pavey, Karl D.; ...

    2015-10-01

    Cavity-enhanced spectroscopy is a sensitive optical absorption technique but one where the practical applications have been limited to studying small wavelength ranges. In addition, this Letter shows that wideband operation can be achieved by combining techniques usually reserved for the communications community with that of cavity-enhanced spectroscopy, producing a multiplexed real-time cavity-enhanced spectrometer. We use multiple collinear laser sources operating asynchronously and simultaneously while being detected on a single photodetector. This is synonymous with radio frequency (RF) cellular systems in which signals are detected on a single antenna but decoded uniquely. Here, we demonstrate results with spectra of methyl salicylatemore » and show parts-per-billion per root hertz sensitivity measured in real-time.« less

  11. Cavity-enhanced Raman microscopy of individual carbon nanotubes

    PubMed Central

    Hümmer, Thomas; Noe, Jonathan; Hofmann, Matthias S.; Hänsch, Theodor W.; Högele, Alexander; Hunger, David

    2016-01-01

    Raman spectroscopy reveals chemically specific information and provides label-free insight into the molecular world. However, the signals are intrinsically weak and call for enhancement techniques. Here, we demonstrate Purcell enhancement of Raman scattering in a tunable high-finesse microcavity, and utilize it for molecular diagnostics by combined Raman and absorption imaging. Studying individual single-wall carbon nanotubes, we identify crucial structural parameters such as nanotube radius, electronic structure and extinction cross-section. We observe a 320-times enhanced Raman scattering spectral density and an effective Purcell factor of 6.2, together with a collection efficiency of 60%. Potential for significantly higher enhancement, quantitative signals, inherent spectral filtering and absence of intrinsic background in cavity-vacuum stimulated Raman scattering render the technique a promising tool for molecular imaging. Furthermore, cavity-enhanced Raman transitions involving localized excitons could potentially be used for gaining quantum control over nanomechanical motion and open a route for molecular cavity optomechanics. PMID:27402165

  12. A versatile design for resonant guided-wave parametric down-conversion sources for quantum repeaters

    NASA Astrophysics Data System (ADS)

    Brecht, Benjamin; Luo, Kai-Hong; Herrmann, Harald; Silberhorn, Christine

    2016-05-01

    Quantum repeaters—fundamental building blocks for long-distance quantum communication—are based on the interaction between photons and quantum memories. The photons must fulfil stringent requirements on central frequency, spectral bandwidth and purity in order for this interaction to be efficient. We present a design scheme for monolithically integrated resonant photon-pair sources based on parametric down-conversion in nonlinear waveguides, which facilitate the generation of such photons. We investigate the impact of different design parameters on the performance of our source. The generated photon spectral bandwidths can be varied between several tens of MHz up to around 1 GHz, facilitating an efficient coupling to different memories. The central frequency of the generated photons can be coarsely tuned by adjusting the pump frequency, poling period and sample temperature, and we identify stability requirements on the pump laser and sample temperature that can be readily fulfilled with off-the-shelf components. We find that our source is capable of generating high-purity photons over a wide range of photon bandwidths. Finally, the PDC emission can be frequency fine-tuned over several GHz by simultaneously adjusting the sample temperature and pump frequency. We conclude our study with demonstrating the adaptability of our source to different quantum memories.

  13. New passive decoy-state quantum key distribution with thermal distributed parametric down-conversion source

    NASA Astrophysics Data System (ADS)

    Wei, Jie; Zhang, Chun-Hui; Wang, Qin

    2017-02-01

    We present a new scheme on implementing the passive quantum key distribution with thermal distributed parametric down-conversion source. In this scheme, only one-intensity decoy state is employed, but we can achieve very precise estimation on the single-photon-pulse contribution by utilizing those built-in decoy states. Moreover, we compare the new scheme with other practical methods, i.e., the standard three-intensity decoy-state BB84 protocol using either weak coherent states or parametric down-conversion source. Through numerical simulations, we demonstrate that our new scheme can drastically improve both the secure transmission distance and the key generation rate.

  14. Spatial Symmetry and Conservation of Orbital Angular Momentum in Spontaneous Parametric Down-Conversion

    SciTech Connect

    Feng Sheng; Kumar, Prem

    2008-10-17

    Directly contradictory arguments coexist regarding the conservation rule of orbital angular momentum in spontaneous parametric down-conversion. We analytically show how this rule is decided by spatial symmetry. We discover that the down-converted photon pairs can carry non-negligible extrinsic orbital angular momentum in the degrees of relative-movement freedom due to spatial symmetry breaking, leading to nonconservation of total orbital angular momentum in type-II down-conversion. Also, we demonstrate that the traditional technique does not measure the extrinsic orbital angular momentum.

  15. Optical extinction monitor using cw cavity enhanced detection.

    PubMed

    Kebabian, Paul L; Robinson, Wade A; Freedman, Andrew

    2007-06-01

    We present details of an apparatus capable of measuring optical extinction (i.e., scattering and/or absorption) with high precision and sensitivity. The apparatus employs one variant of cavity enhanced detection, specifically cavity attenuated phase shift spectroscopy, using a near-confocal arrangement of two high reflectivity (R approximately 0.9999) mirrors in tandem with an enclosed cell 26 cm in length, a light emitting diode (LED), and a vacuum photodiode detector. The square wave modulated light from the LED passes through the absorption cell and is detected as a distorted wave form which is characterized by a phase shift with respect to the initial modulation. The amount of that phase shift is a function of fixed instrument properties-cell length, mirror reflectivity, and modulation frequency-and of the presence of a scatterer or absorber (air, particles, trace gases, etc.) within the cell. The specific implementation reported here employs a blue LED; the wavelength and spectral bandpass of the measurement are defined by the use of an interference filter centered at 440 nm with a 20 nm wide bandpass. The monitor is enclosed within a standard 19 in. rack-mounted instrumentation box, weighs 10 kg, and uses 70 W of electrical power including a vacuum pump. Measurements of the phase shift induced by Rayleigh scattering from several gases (which range in extinction coefficient from 0.4-32 Mm(-1)) exhibit a highly linear dependence (r(2)=0.999 97) when plotted as the co-tangent of the phase shift versus the expected extinction. Using heterodyne demodulation techniques, we demonstrate a detection limit of 0.04 Mm(-1) (4 x 10(-10) cm(-1)) (2sigma) in 10 s integration time and a base line drift of less than +/-0.1 Mm(-1) over a 24 h period. Detection limits decrease as the square root of integration time out to approximately 150 s.

  16. Cavity Enhanced Ultrafast Transient Absorption Spectroscopy

    NASA Astrophysics Data System (ADS)

    Allison, Thomas K.; Reber, Melanie Roberts; Chen, Yuning

    2015-06-01

    Ultrafast spectroscopy on gas phase systems is typically restricted to techniques involving photoionization, whereas solution phase experiments utilize the detection of light. At Stony Brook, we are developing new techniques for performing femtosecond time-resolved spectroscopy using frequency combs and high-finesse optical resonators. A large detection sensitivity enhancement over traditional methods enables the extension of all-optical ultrafast spectroscopies, such as broad-band transient absorption spectroscopy (TAS) and 2D spectroscopy, to dilute gas phase samples produced in molecular beams. Here, gas phase data can be directly compared to solution phase data. Initial demonstration experiments are focusing on the photodissociation of iodine in small neutral argon clusters, where cluster size strongly influences the effects solvent-caging and geminate recombination. I will discuss these initial results, our high power home-built Yb:fiber laser systems, and also extensions of the methods to the mid-IR to study the vibrational dynamics of hydrogen bonded clusters.

  17. Warm white LED light by frequency down-conversion of mixed yellow and red Lumogen

    NASA Astrophysics Data System (ADS)

    Mosca, Mauro; Caruso, Fulvio; Zambito, Leandro; Seminara, Biagio; Macaluso, Roberto; Calı, Claudio; Feltin, Eric

    2013-05-01

    This work reports on the benefits and promising opportunities offered by white LED hybrid technology, based on a mixing perylene-based dyes in order to obtain a warm white light for frequency-down conversion. In a standard Ce:YAG-based white LED, the white light appears cold due to the weakness of red wavelength components in the emission spectrum. In order to obtain a warmer white, one possible solution is to add a red phosphor to the yellow one to move the chromatic coordinates properly, though the luminous efficiency drastically decreases due to the increased light absorption of the coating layer. It is generally believed that the low efficiency of warm white LEDs is the main issue today for LED-based lighting. Using photoluminescence of Lumogen® F Yellow 083, a perylene-based polymer dye commercialized by BASF, and adding a small quantity of another perylene-based dye, Lumogen® F Red 305 (BASF), we obtained high-efficiency warm white LEDs by yellow and red conversion from a standard 450 nm GaN/InGaN royal blue LED. Different weight proportions of dyes were dissolved in solutions with equal amounts of poly-methyl-methacrylate (PMMA) in ethyl acetate, then the LEDs were dip-coated in each solution and optically characterized. Record values of 8.03 lm of luminous flux and 116.11 lm/W of optical efficiency were achieved. Finally, the effects of both driving current, and pump wavelength on LED performances - such as chromatic coordinates, correlated color temperature, color rendering index (CRI), and optical efficiency - were investigated.

  18. Resonant cavity enhanced multi-analyte sensing

    NASA Astrophysics Data System (ADS)

    Bergstein, David Alan

    Biological research and medicine increasingly depend on interrogating binding interactions among small segments of DNA, RNA, protein, and bio-specific small molecules. Microarray technology, which senses the affinity for target molecules in solution for a multiplicity of capturing agents fixed to a surface, has been used in biological research for gene expression profiling and in medicine for molecular biomarker detection. Label-free affinity sensing is preferable as it avoids fluorescent labeling of the target molecules, reducing test cost and variability. The Resonant Cavity Imaging Biosensor (RCIB) is a label-free optical inference based technique introduced that scales readily to high throughput and employs an optical resonant cavity to enhance sensitivity by a factor of 100 or more. Near-infrared light centered at 1512.5 nm couples resonantly through a cavity constructed from Si/SiO2 Bragg reflectors, one of which serves as the binding surface. As the wavelength is swept 5 nm, an Indium-Gallium-Arsenide digital camera monitors cavity transmittance at each pixel with resolution 128 x 128. A wavelength shift in the local resonant response of the optical cavity indicates binding. Positioning the sensing surface with respect to the standing wave pattern of the electric field within the cavity, one can control the sensitivity of the measurement to the presence of bound molecules thereby enhancing or suppressing sensitivity where appropriate. Transmitted intensity at thousands of pixel locations are recorded simultaneously in a 10 s, 5 nm scan. An initial proof-of-principle setup was constructed. A sample was fabricated with 25, 100 mum wide square regions, each with a different density of 1 mum square depressions etched 12 nm into the S1O 2 surface. The average depth of each etched region was found with 0.05 nm RMS precision when the sample remains loaded in the setup and 0.3 nm RMS precision when the sample is removed and replaced. Selective binding of the protein

  19. Nanophotonics and nanochemistry: controlling the excitation dynamics for frequency up- and down-conversion in lanthanide-doped nanoparticles.

    PubMed

    Chen, Guanying; Yang, Chunhui; Prasad, Paras N

    2013-07-16

    Nanophotonics is an emerging science dealing with the interaction of light and matter on a nanometer scale and holds promise to produce new generation nanophosphors with highly efficient frequency conversion of infrared (IR) light. Scientists can control the excitation dynamics by using nanochemistry to produce hierarchically built nanostructures and tailor their interfaces. These nanophosphors can either perform frequency up-conversion from IR to visible or ultraviolet (UV) or down-conversion, which results in the IR light being further red shifted. Nanophotonics and nanochemistry open up numerous opportunities for these photon converters, including in high contrast bioimaging, photodynamic therapy, drug release and gene delivery, nanothermometry, and solar cells. Applications of these nanophosphors in these directions derive from three main stimuli. Light excitation and emission within the near-infrared (NIR) "optical transparency window" of tissues is ideal for high contrast in vitro and in vivo imaging. This is due to low natural florescence, reduced scattering background, and deep penetration in tissues. Secondly, the naked eye is highly sensitive in the visible range, but it has no response to IR light. Therefore, many scientists have interest in the frequency up-conversion of IR wavelengths for security and display applications. Lastly, frequency up-conversion can convert IR photons to higher energy photons, which can then readily be absorbed by solar materials. Current solar devices do not use abundant IR light that comprises almost half of solar energy. In this Account, we present our recent work on nanophotonic control of frequency up- and down-conversion in fluoride nanophosphors, and their biophotonic and nanophotonic applications. Through nanoscopic control of phonon dynamics, electronic energy transfer, local crystal field, and surface-induced non-radiative processes, we were able to produce new generation nanophosphors with highly efficient frequency

  20. Wave function for spontaneous parametric down-conversion with orbital angular momentum

    SciTech Connect

    Barbosa, Geraldo A.

    2009-12-15

    Several wave-function approximations describing spontaneous parametric down-conversion can be found in the literature. Basically all cases are derived from the standard Hamiltonian for parametric down-conversion. Most frequently, particular cases describing collinear or paraxial approximations are described. This work presents a wave function in compact form, valid for all cases of single photon-pair conversion (Type I or Type II), for all angles allowed by the phase-matching conditions and for all orbital angular momentum values l. Examples are given of coincidence structures to be expected for signal and idler photons. Partial transfer of orbital angular momentum from the pump laser to the photon pair is discussed. Some hypothesis for the decay channels of the nontransferred part of the orbital angular momentum is made.

  1. Three-photon frequency down-conversion as an event-ready source of entangled states

    SciTech Connect

    Hnilo, Alejandro A.

    2005-03-01

    An event-ready (or deterministic) source of entangled states is of interest in the practical implementation of schemes of quantum computation and cryptography as well as in the experiments aimed to elucidate the foundations of quantum mechanics. I study the phase matching geometry and detection conditions for the process of three-photon frequency down-conversion, which is a possible source of that kind. It is apparently free of some limitations of the schemes based on two-photon frequency down-conversion. The goal of the proposed setup is not the generation of an entangled state of three photons (in a GHZ-state sense), but of an entangled state of two photons with a 'trigger' signal. As an example, I estimate the values of the trios' flux and trigger's reliability for the particular case of crystal calcite illuminated by the fourth harmonic of a Nd:YAG mode-locked laser.

  2. Matching Solid-State to Solution-Phase Photoluminescence for Near-Unity Down-Conversion Efficiency Using Giant Quantum Dots.

    PubMed

    Hanson, Christina J; Buck, Matthew R; Acharya, Krishna; Torres, Joseph A; Kundu, Janardan; Ma, Xuedan; Bouquin, Sarah; Hamilton, Christopher E; Htoon, Han; Hollingsworth, Jennifer A

    2015-06-24

    Efficient, stable, and narrowband red-emitting fluorophores are needed as down-conversion materials for next-generation solid-state lighting that is both efficient and of high color quality. Semiconductor quantum dots (QDs) are nearly ideal color-shifting phosphors, but solution-phase efficiencies have not traditionally extended to the solid-state, with losses from both intrinsic and environmental effects. Here, we assess the impacts of temperature and flux on QD phosphor performance. By controlling QD core/shell structure, we realize near-unity down-conversion efficiency and enhanced operational stability. Furthermore, we show that a simple modification of the phosphor-coated light-emitting diode device-incorporation of a thin spacer layer-can afford reduced thermal or photon-flux quenching at high driving currents (>200 mA).

  3. Derivation of the density matrix of a single photon produced in parametric down-conversion

    SciTech Connect

    Kolenderski, Piotr; Wasilewski, Wojciech

    2009-07-15

    We discuss an effective numerical method of density matrix determination of fiber coupled single photon generated in process of spontaneous parametric down conversion in type I noncollinear configuration. The presented theory has been successfully applied in case of source utilized to demonstrate the experimental characterization of spectral state of single photon, what was reported in Wasilewski, Kolenderski, and Frankowski [Phys. Rev. Lett. 99, 123601 (2007)].

  4. Two-mode correlation of microwave quantum noise generated by parametric down-conversion.

    PubMed

    Bergeal, N; Schackert, F; Frunzio, L; Devoret, M H

    2012-03-23

    In this Letter, we report the observation of the correlation between two modes of microwave radiation resulting from the amplification of quantum noise by the Josephson parametric converter. This process, seen from the pump, can be viewed as parametric down-conversion. The correlation is measured by an interference experiment displaying a contrast better than 99% with a number of photons per mode greater than 250,000. Dispersive measurements of mesoscopic systems and quantum encryption can benefit from this development.

  5. Two-Photon Entanglement and EPR Experiments Using Type-2 Spontaneous Parametric Down Conversion

    NASA Technical Reports Server (NTRS)

    Sergienko, A. V.; Shih, Y. H.; Pittman, T. B.; Rubin, M. H.

    1996-01-01

    Simultaneous entanglement in spin and space-time of a two-photon quantum state generated in type-2 spontaneous parametric down-conversion is demonstrated by the observation of quantum interference with 98% visibility in a simple beam-splitter (Hanburry Brown-Twiss) anticorrelation experiment. The nonlocal cancellation of two-photon probability amplitudes as a result of this double entanglement allows us to demonstrate two different types of Bell's inequality violations in one experimental setup.

  6. InAs nanowire MOSFETs in three-transistor configurations: single balanced RF down-conversion mixers.

    PubMed

    Berg, Martin; Persson, Karl-Magnus; Wu, Jun; Lind, Erik; Sjöland, Henrik; Wernersson, Lars-Erik

    2014-12-05

    Integration of III-V semiconductors on Si substrates allows for the realization of high-performance, low power III-V electronics on the Si-platform. In this work, we demonstrate the implementation of single balanced down-conversion mixer circuits, fabricated using vertically aligned InAs nanowire devices on Si. A thin, highly doped InAs buffer layer has been introduced to reduce the access resistance and serve as a bottom electrode. Low-frequency voltage conversion gain is measured up to 7 dB for a supply voltage of 1.5V. Operation of these mixers extends into the GHz regime with a -3 dB cut-off frequency of 2 GHz, limited by the optical lithography system used. The circuit dc power consumption is measured at 3.9 mW.

  7. Measurement of SFDR and noise in EDF amplified analog RF links using all-optical down-conversion and balanced receivers

    NASA Astrophysics Data System (ADS)

    Middleton, Charles; Borbath, Michael; Wyatt, Jeff; DeSalvo, Richard

    2008-04-01

    Optical down-conversion techniques have become an increasingly popular architecture to realize Multi-band Enterprise Terminals (MET), Synthetic Aperture Radar (SAR), Optical Arbitrary Waveform Generation (OAWG), RF Channelizers and other technologies that need rapid frequency agile tunability in the microwave and millimeter RF bands. We describe recent SFDR, NF, Gain, and Noise modeling and measurements of Erbium-doped-fiber amplified analog RF optical links implementing all-optical down-conversion and balanced photodiode receivers. We describe measurements made on our newly designed extensive test-bed utilizing a wide array of high powered single and balanced photodiodes, polarization preserving output LN modulators, EAMs, LIMs, tunable lasers, EDFAs, RF Amplifiers, and other components to fully characterize direct and coherent detection techniques. Additionally, we compare these experimental results to our comprehensive MATLAB system modeling and optimization software tools.

  8. Entanglement and nonclassicality in four-mode Gaussian states generated via parametric down-conversion and frequency up-conversion

    PubMed Central

    Arkhipov, Ievgen I.; Peřina Jr., Jan; Haderka, Ondřej; Allevi, Alessia; Bondani, Maria

    2016-01-01

    Multipartite entanglement and nonclassicality of four-mode Gaussian states generated in two simultaneous nonlinear processes involving parametric down-conversion and frequency up-conversion are analyzed assuming the vacuum as the initial state. Suitable conditions for the generation of highly entangled states are found. Transfer of the entanglement from the down-converted modes into the up-converted ones is also suggested. The analysis of the whole set of states reveals that sub-shot-noise intensity correlations between the equally-populated down-converted modes, as well as the equally-populated up-converted modes, uniquely identify entangled states. They represent a powerful entanglement identifier also in other cases with arbitrarily populated modes. PMID:27658508

  9. Entanglement and nonclassicality in four-mode Gaussian states generated via parametric down-conversion and frequency up-conversion.

    PubMed

    Arkhipov, Ievgen I; Peřina, Jan; Haderka, Ondřej; Allevi, Alessia; Bondani, Maria

    2016-09-23

    Multipartite entanglement and nonclassicality of four-mode Gaussian states generated in two simultaneous nonlinear processes involving parametric down-conversion and frequency up-conversion are analyzed assuming the vacuum as the initial state. Suitable conditions for the generation of highly entangled states are found. Transfer of the entanglement from the down-converted modes into the up-converted ones is also suggested. The analysis of the whole set of states reveals that sub-shot-noise intensity correlations between the equally-populated down-converted modes, as well as the equally-populated up-converted modes, uniquely identify entangled states. They represent a powerful entanglement identifier also in other cases with arbitrarily populated modes.

  10. Cavity Enhanced Absorption Spectroscopy using a Prism Cavity and Supercontinuum Source

    NASA Astrophysics Data System (ADS)

    Lehmann, Kevin K.; Johnston, Paul S.

    2010-03-01

    The multiplex advantage of current cavity enhanced spectrometers is limited by the limited high reflectivity bandwidth of the dielectric mirrors used to construct the high finesse cavity. We report on our development of a spectrometer that uses Brewster's angle retroreflectors that is excited with supercontinuum radiation generated by a 1.06 μm pumped photonic crystal fiber, which covers the 500-1800 nm spectral range. Recent progress will be discussed including modeling of the prism cavity losses, alternative prism materials for use in the UV and mid-IR, and a new higher power source pumped by a mode-locked laser.

  11. Einstein-Podolsky-Rosen-Bohm experiment and Bell inequality violation using Type 2 parametric down conversion

    NASA Technical Reports Server (NTRS)

    Kiess, Thomas E.; Shih, Yan-Hua; Sergienko, A. V.; Alley, Carroll O.

    1994-01-01

    We report a new two-photon polarization correlation experiment for realizing the Einstein-Podolsky-Rosen-Bohm (EPRB) state and for testing Bell-type inequalities. We use the pair of orthogonally-polarized light quanta generated in Type 2 parametric down conversion. Using 1 nm interference filters in front of our detectors, we observe from the output of a 0.5mm beta - BaB2O4 (BBO) crystal the EPRB correlations in coincidence counts, and measure an associated Bell inequality violation of 22 standard deviations. The quantum state of the photon pair is a polarization analog of the spin-1/2 singlet state.

  12. Pump Spectral Bandwidth, Birefringence, and Entanglement in Type-II Parametric Down Conversion

    DOE PAGES

    Erenso, Daniel

    2009-01-01

    The twin photons produced by a type-II spontaneous parametric down conversion are well know as a potential source of photons for quantum teleportation due to the strong entanglement in polarization. This strong entanglement in polarization, however, depends on the spectral composition of the pump photon and the nature of optical isotropy of the crystal. By exact numerical calculation of the concurrence, we have shown that how pump photons spectral width and the birefringence nature of the crystal directly affect the degree of polarization entanglement of the twin photons.

  13. Interference of biphotons upon parametric down-conversion in the field of biharmonic pumping

    SciTech Connect

    Zolotoverkh, I I

    2014-04-28

    We report theoretical investigation of interference of biphotons emitted upon type-II collinear parametric down-conversion in the case of biharmonic pumping. Interference occurs when an optical or electronic shutter is used as an amplitude modulator in the experimental scheme. The phase of the interference is shown to depend on the time interval between the instant the shutter is opened and the instant corresponding to the maximum pump intensity. The main parameter affecting the visibility of the interference pattern is a time interval during which the shutter is open. (nonlinear optical phenomena)

  14. Generation of coherent waves by frequency up-conversion and down-conversion of incoherent light

    SciTech Connect

    Piskarskas, A.; Pyragaite, V.; Stabinis, A.

    2010-11-15

    It is revealed that the generation of a coherent wave by frequency conversion of incoherent waves is a characteristic feature of three-wave interaction in a nonlinear medium when angular dispersion of input waves is properly chosen. In this case the combining action of the pairs of spectral components of incoherent waves may result in the cumulative driving of a single plane monochromatic wave in up-conversion and down-conversion processes. As a fundamental result we point out an enhancement of the spectral radiance of the generated wave in comparison with incoherent waves.

  15. Simple performance evaluation of pulsed spontaneous parametric down-conversion sources for quantum communications.

    PubMed

    Smirr, Jean-Loup; Guilbaud, Sylvain; Ghalbouni, Joe; Frey, Robert; Diamanti, Eleni; Alléaume, Romain; Zaquine, Isabelle

    2011-01-17

    Fast characterization of pulsed spontaneous parametric down conversion (SPDC) sources is important for applications in quantum information processing and communications. We propose a simple method to perform this task, which only requires measuring the counts on the two output channels and the coincidences between them, as well as modeling the filter used to reduce the source bandwidth. The proposed method is experimentally tested and used for a complete evaluation of SPDC sources (pair emission probability, total losses, and fidelity) of various bandwidths. This method can find applications in the setting up of SPDC sources and in the continuous verification of the quality of quantum communication links.

  16. Nonlocalized Generation of Correlated Photon Pairs in Degenerate Down-Conversion

    NASA Astrophysics Data System (ADS)

    Forbes, Kayn A.; Ford, Jack S.; Andrews, David L.

    2017-03-01

    The achievement of optimum conversion efficiency in conventional spontaneous parametric down-conversion requires consideration of quantum processes that entail multisite electrodynamic coupling, actively taking place within the conversion material. The physical mechanism, which operates through virtual photon propagation, provides for photon pairs to be emitted from spatially separated sites of photon interaction; occasionally pairs are produced in which each photon emerges from a different point in space. The extent of such nonlocalized generation is influenced by individual variations in both distance and phase correlation. Mathematical analysis of the global contributions from this mechanism provides a quantitative measure for a degree of positional uncertainty in the origin of down-converted emission.

  17. Parametric down-conversion with optimized spectral properties in nonlinear photonic crystals

    SciTech Connect

    Corona, Maria; U'Ren, Alfred B.

    2007-10-15

    We study the joint spectral properties of photon pairs generated by spontaneous parametric down-conversion in a one-dimensional nonlinear photonic crystal in a collinear, degenerate, type-II geometry. We show that the photonic crystal properties may be exploited to compensate for material dispersion and obtain photon pairs that are nearly factorable, in principle, for arbitrary materials and spectral regions, limited by the ability to fabricate the nonlinear crystal with the required periodic variation in the refractive indices for the ordinary and extraordinary waves.

  18. Experiences on developing digital down conversion algorithms using Xilinx system generator

    NASA Astrophysics Data System (ADS)

    Xu, Chengfa; Yuan, Yuan; Zhao, Lizhi

    2013-07-01

    The Digital Down Conversion (DDC) algorithm is a classical signal processing method which is widely used in radar and communication systems. In this paper, the DDC function is implemented by Xilinx System Generator tool on FPGA. System Generator is an FPGA design tool provided by Xilinx Inc and MathWorks Inc. It is very convenient for programmers to manipulate the design and debug the function, especially for the complex algorithm. Through the developing process of DDC function based on System Generator, the results show that System Generator is a very fast and efficient tool for FPGA design.

  19. Full two-photon down-conversion of a single photon

    NASA Astrophysics Data System (ADS)

    Sánchez-Burillo, E.; Martín-Moreno, L.; García-Ripoll, J. J.; Zueco, D.

    2016-11-01

    We demonstrate, both numerically and analytically, that it is possible to deterministically generate two photons from one and only one photon. We characterize the output two-photon field and make our calculations close to reality by including losses. Our proposal relies on real or artificial three-level atoms with a cyclic transition strongly coupled to a one-dimensional waveguide. We show that almost perfect down-conversion, with efficiency over 99 % , is reachable using state-of-the-art waveguide QED architectures such as photonic crystals or superconducting circuits. In particular, we sketch an implementation in circuit QED, where the three-level atom is a transmon.

  20. A unified description of sum frequency generation, parametric down conversion and two-photon fluorescence

    PubMed Central

    Roslyak, Oleksiy; Mukamel, Shaul

    2010-01-01

    A superoperator non-equilibrium Green’s function formalism is presented for computing nonlinear optical processes involving any combination of classical and quantum optical modes. Closed correlation-function expressions based on superoperator time-ordering are derived for the combined effects of causal response and non-causal spontaneous fluctuations. Coherent three wave mixing (sum frequency generation and parametric down conversion) involving one and two quantum optical modes, respectively, are compared with their incoherent counterparts: two-photon-induced fluorescence and two-photon-emitted fluorescence. PMID:20607143

  1. [Near infrared Cavity enhanced absorption spectroscopy study of NO2O].

    PubMed

    Wu, Zhi-wei; Dong, Yan-ting; Zhou, Wei-dong

    2014-08-01

    Using a tunable near infrared external cavity diode laser and a 650 mm long high finesse optical cavity consisting of two highly reflective (R=99.97% at 6561.39 cm(-1)) plan-concave mirrors of curvature radius approximately 1000 mm, a cavity enhanced absorption spectroscopy (CEAS) system was made. The absorption spectra centered at 6561.39 cm(-1) of pure N2O gas and gas mixtures of N2O and N2 were recorded. According to the absorption of N2O at 6561.39 cm(-1) in the cavity, the measured effective absorption path was about 1460 km. The spectra line intensity and line-width of N2O centered at 6561.39 cm(-1) were carefully studied. The relationship between the line-width of absorption spectra and the gas pressure was derived. The pressure broadening parameter of N2 gas for NO2O line centered at 6 561. 39 cm(-1) was deduced and given a value of approximately (0.114 +/- 0.004) cm(-1) x atm(-1). The possibility to detect trace N2O gas in mixture using this CEAS system was investigated. By recording the ab- sorption spectra of N2O gas mixtures at different concentration, the relationship between the line intensity and gas concentration was derived. The minimum detectable absorption was found to be 2.34 x 10(-7) cm(-1) using this cavity enhanced absorption spectroscopy system. And te measurement precision in terms of relative standard deviation (RSD) for N2O is approximately 1.73%, indicating the possibility of using the cavity enhanced absorption spectroscopy system for micro gas N2O analysis in the future.

  2. Aerosol optical properties measurement by recently developed cavity-enhanced aerosol single scattering albedometer

    NASA Astrophysics Data System (ADS)

    Zhao, Weixiong; Xu, Xuezhe; Zhang, Qilei; Fang, Bo; Qian, Xiaodong; Chen, Weidong; Gao, Xiaoming; Zhang, Weijun

    2015-04-01

    Development of appropriate and well-adapted measurement technologies for real-time in-situ measurement of aerosol optical properties is an important step towards a more accurate and quantitative understanding of aerosol impacts on climate and the environment. Aerosol single scattering albedo (SSA, ω), the ratio between the scattering (αscat) and extinction (αext) coefficients, is an important optical parameter that governs the relative strength of the aerosol scattering and absorption capacity. Since the aerosol extinction coefficient is the sum of the absorption and scattering coefficients, a commonly used method for the determination of SSA is to separately measure two of the three optical parameters - absorption, scattering and extinction coefficients - with different instruments. However, as this method involves still different instruments for separate measurements of extinction and absorption coefficients under different sampling conditions, it might cause potential errors in the determination of SSA value, because aerosol optical properties are very sensitive to the sampling conditions such as temperature and relative humidity (RH). In this paper, we report on the development of a cavity-enhanced aerosol single scattering albedometer incorporating incoherent broad-band cavity-enhanced spectroscopy (IBBCEAS) and an integrating sphere (IS) for direct in-situ measurement of aerosol scattering and extinction coefficients on the exact same sample volume. The cavity-enhanced albedometer holds great promise for high-sensitivity and high-precision measurement of ambient aerosol scattering and extinction coefficients (hence absorption coefficient and SSA determination) and for absorbing trace gas concentration. In addition, simultaneous measurements of aerosol scattering and extinction coefficients enable a potential application for the retrieval of particle number size distribution and for faster retrieval of aerosols' complex RI. The albedometer was deployed to

  3. Time resolved imaging using non-collinear parametric down-conversion

    NASA Astrophysics Data System (ADS)

    Park, Jung-Rae

    In this thesis I present a method for measuring the time resolved spatial profile of a single laser pulse and its application to the semiconductor devices. In OMEGA laser system, spatial profile of a laser beam can change as a function of time due to spontaneous effects such as the B-integral or imposed effects such as smoothing by spectral dispersion. The method presented here uses a non-collinear parametric down-conversion process to multiply sample a single laser pulse. In the non-collinear parametric down-conversion process, an infrared laser beam at 1064 nm is mixed with an intense ultraviolet beam at 351 nm to generate the green signal beam at 524 nm. Calculations have been carried out to determine the threshold power of the infrared probe beam for generating a detectable signal beam. The generated green beam is captured by a cooled optical multichannel analyzer camera and the image of signal beam is analyzed. This temporal spatial measurement can also be applied to the dynamic image detection schemes of semiconductor devices.

  4. Development of digital sideband separating down-conversion for Yuan-Tseh Lee Array

    NASA Astrophysics Data System (ADS)

    Li, Chao-Te; Kubo, Derek; Cheng, Jen-Chieh; Kuroda, John; Srinivasan, Ranjani; Ho, Solomon; Guzzino, Kim; Chen, Ming-Tang

    2016-07-01

    This report presents a down-conversion method involving digital sideband separation for the Yuan-Tseh Lee Array (YTLA) to double the processing bandwidth. The receiver consists of a MMIC HEMT LNA front end operating at a wavelength of 3 mm, and sub-harmonic mixers that output signals at intermediate frequencies (IFs) of 2-18 GHz. The sideband separation scheme involves an analog 90° hybrid followed by two mixers that provide down-conversion of the IF signal to a pair of in-phase (I) and quadrature (Q) signals in baseband. The I and Q baseband signals are digitized using 5 Giga sample per second (Gsps) analog-to-digital converters (ADCs). A second hybrid is digitally implemented using field-programmable gate arrays (FPGAs) to produce two sidebands, each with a bandwidth of 1.6 GHz. The 2 x 1.6 GHz band can be tuned to cover any 3.6 GHz window within the aforementioned IF range of the array. Sideband rejection ratios (SRRs) above 20 dB can be obtained across the 3.6 GHz bandwidth by equalizing the power and delay between the I and Q baseband signals. Furthermore, SRRs above 30 dB can be achieved when calibration is applied.

  5. Time-Resolved Broadband Cavity-Enhanced Absorption Spectroscopy behind Shock Waves.

    PubMed

    Matsugi, Akira; Shiina, Hiroumi; Oguchi, Tatsuo; Takahashi, Kazuo

    2016-04-07

    A fast and sensitive broadband absorption technique for measurements of high-temperature chemical kinetics and spectroscopy has been developed by applying broadband cavity-enhanced absorption spectroscopy (BBCEAS) in a shock tube. The developed method has effective absorption path lengths of 60-200 cm, or cavity enhancement factors of 12-40, over a wavelength range of 280-420 nm, and is capable of simultaneously recording absorption time profiles over an ∼32 nm spectral bandpass in a single experiment with temporal and spectral resolutions of 5 μs and 2 nm, respectively. The accuracy of the kinetic and spectroscopic measurements was examined by investigating high-temperature reactions and absorption spectra of formaldehyde behind reflected shock waves using 1,3,5-trioxane as a precursor. The rate constants obtained for the thermal decomposition reactions of 1,3,5-trioxane (to three formaldehyde molecules) and formaldehyde (to HCO + H) agreed well with the literature data. High-temperature absorption cross sections of formaldehyde between 280 and 410 nm have been determined at the post-reflected-shock temperatures of 955, 1265, and 1708 K. The results demonstrate the applicability of the BBCEAS technique to time- and wavelength-resolved sensitive absorption measurements at high temperatures.

  6. Cavity enhanced ultra-thin aluminum plasmonic resonator for surface enhanced infrared absorption spectroscopy

    NASA Astrophysics Data System (ADS)

    Wei, Wei; Jiang, Xiao; Nong, Jinpeng; Chen, Na; Lan, Guilian; Tang, Linlong

    2016-11-01

    Owing to the advantages of natural abundance, low cost, and amenability to manufacturing processes, aluminum has recently been recognized as a highly promising plasmonic material that attracts extensive research interest. Here, we propose a cavity-enhanced ultra-thin plasmonic resonator for surface enhanced infrared absorption spectroscopy. The considered resonator consists of a patterned ultra-thin aluminum grating strips, a dielectric spacer layer and a reflective layer. In such structure, the resonance absorption is enhanced by the cavity formed between the patterned aluminum strips and the reflective layer. It is demonstrated that the spectral features of the resonator can be tuned by adjusting the structural parameters. Furthermore, in order to achieve a deep and broad spectral line shape, the spacer layer thickness should be properly designed to realize the simultaneous resonances for the electric and the magnetic excitations. The enhanced infrared absorption characteristics can be used for infrared sensing of the environment. When the resonator is covered with a molecular layer, the resonator can be used as a surface enhanced infrared absorption substrate to enhance the absorption signal of the molecules. A high enhanced factor of 1.15×105 can be achieved when the resonance wavelength of resonator is adjusted to match the desired vibrational mode of the molecules. Such a cavity-enhanced plasmonic resonator, which is easy for practical fabrication, is expected to have potential applications for infrared sensing with high-performance.

  7. Mid-Infrared Tunable Resonant Cavity Enhanced Detectors

    PubMed Central

    Quack, Niels; Blunier, Stefan; Dual, Jurg; Felder, Ferdinand; Arnold, Martin; Zogg, Hans

    2008-01-01

    Mid-infrared detectors that are sensitive only in a tunable narrow spectral band are presented. They are based on the Resonant Cavity Enhanced Detector (RCED) principle and employing a thin active region using IV-VI narrow gap semiconductor layers. A Fabry-Pérot cavity is formed by two mirrors. The active layer is grown onto one mirror, while the second mirror can be displaced. This changes the cavity length thus shifting the resonances where the detector is sensitive. Using electrostatically actuated MEMS micromirrors, a very compact tunable detector system has been fabricated. Mirror movements of more than 3 μm at 30V are obtained. With these mirrors, detectors with a wavelength tuning range of about 0.7 μm have been realized. Single detectors can be used in mid-infrared micro spectrometers, while a detector arrangement in an array makes it possible to realize Adaptive Focal Plane Arrays (AFPA). PMID:27873824

  8. Power build-up cavity enhanced Raman spectroscopy based on piezoelectric transducer for gas analysis

    NASA Astrophysics Data System (ADS)

    Zhang, Xiumei; Jiang, Shubo; Hu, Jialin

    2017-02-01

    In this paper, the Power Build-Up cavity enhanced Raman spectroscopy is introduced and the matching mode between the cavity length and wavelength is improved simultaneously. At the same time, the laser diode optical frequency modulation circuit is designed. Cavity length control system is built up to enhance the cavity power and experiments are also set up. The 532nm laser is coupled into an external linear optical cavity composed of two highly reflective mirrors. Since the light source is a solid laser, center light wavelength is a constant and line width is also known. Considered the distance between concave mirrors, the cavity length is squirmed slightly by the piezoelectric transducer. The light intensity measurement method is designed to record and analyze the performance of the cavity beam power and figure out the non-linear characteristic of system. In the premise of stable initial condition of enhanced system, the operating point is searched firstly which based on feedback control until the beam power is enhanced ultimately. The final experiment illustrates the feasibility of enhanced Raman effects with controlling cavity length and obtaining build-up optical power. The Power Build-Up cavity enhanced Raman spectroscopy has the potential to become a standard method for sensitive gas phase Raman spectroscopy.

  9. Entanglement, coherence, and redistribution of quantum resources in double spontaneous down-conversion processes

    NASA Astrophysics Data System (ADS)

    Bruschi, David Edward; Sabín, Carlos; Paraoanu, Gheorghe Sorin

    2017-06-01

    We study the properties of bisqueezed tripartite Gaussian states created by two spontaneous parametric down-conversion processes that share a common idler. We give a complete description of the quantum correlations across all partitions, as well as of the genuine multipartite entanglement, obtaining analytical expressions for most of the quantities of interest. We find that the state contains genuine tripartite entanglement, in addition to the bipartite entanglement among the modes that are directly squeezed. We also investigate the effect of homodyne detection of the photons in the common idler mode, and analyze the final reduced state of the remaining two signal modes. We find that this measurement leads to a conversion of the coherence of the two signal modes into entanglement, a phenomenon that can be regarded as a redistribution of quantum resources between the modes. The applications of these results to quantum optics and circuit quantum electrodynamics platforms are also discussed.

  10. Indistinguishability of orbital angular-momentum modes in spontaneous parametric down-conversion

    SciTech Connect

    Barbosa, Geraldo Alexandre

    2009-05-15

    Identification of light modes usually requires careful considerations of the collecting geometry. This is particularly true for states carrying orbital angular-momentum modes from spontaneous parametric down-conversion due to the entanglement of the signal and idler fields. A detailed understanding of the generated modes in a general case allows the design of efficient detection setups. This is true for distinct cases, e.g., when multiple samplings are performed by repeated state generation or in single-photon cryptography or quantum computation, where a photon state is generated within a short-time window and a single measurement is performed. Aspects of nonorthogonality of signal and idler modes and effects of restrictions on the collecting geometry are discussed in this work.

  11. Parametric down-conversion with nonideal and random quasi-phase-matching

    PubMed Central

    Yang, Chun-Yao; Lin, Chun; Liljestrand, Charlotte; Su, Wei-Min; Canalias, Carlota; Chuu, Chih-Sung

    2016-01-01

    Quasi-phase-matching (QPM) has enriched the capacity of parametric down-conversion (PDC) in generating biphotons for many fundamental tests and advanced applications. However, it is not clear how the nonidealities and randomness in the QPM grating of a parametric down-converter may affect the quantum properties of the biphotons. This paper intends to provide insights into the interplay between PDC and nonideal or random QPM structures. Using a periodically poled nonlinear crystal with short periodicity, we conduct experimental and theoretical studies of PDC subject to nonideal duty cycle and random errors in domain lengths. We report the observation of biphotons emerging through noncritical birefringent-phasematching, which is impossible to occur in PDC with an ideal QPM grating, and a biphoton spectrum determined by the details of nonidealities and randomness. We also observed QPM biphotons with a diminished strength. These features are both confirmed by our theory. Our work provides new perspectives for biphoton engineering with QPM. PMID:27173482

  12. Coordination polymer core/shell structures: Preparation and up/down-conversion luminescence.

    PubMed

    Li, Bingmei; Xu, Hualan; Xiao, Chen; Shuai, Min; Chen, Weimin; Zhong, Shengliang

    2016-10-01

    Coordination polymer (CP) core-shell nanoparticles with Gd-based CP (GdCP) as core and Eu-based CP (EuCP) as shell have been successfully prepared. Allantoin was employed as the organic building block without the assistance of any template. The composition, size and structure of the core-shell nanospheres were well characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray (EDX), powder X-ray diffraction (PXRD), Fourier transform infrared spectroscopy (FT-IR), thermo-gravimetric analysis (TG). Results show that the resultant cores are uniform nanospheres with diameter of approximately 45nm, while the diameters of the core-shell nanospheres are increased to approximately 60nm. The core-shell products show enhanced luminescence efficiency than the core under 980nm laser excitation and decreased down-conversion luminescence when excited at 394nm.

  13. Type-I spontaneous parametric down-conversion with a strongly focused pump

    SciTech Connect

    Di Lorenzo Pires, H.; Coppens, F. M. G. J.; Exter, M. P. van

    2011-03-15

    We experimentally study the spatial properties of the field generated by spontaneous parametric down-conversion (SPDC) when the pump laser beam is strongly focused in the nonlinear crystal. Special attention is paid to classical intensity measurements with a CCD camera. We introduce the concept of a classical equivalent source that replicates all the coherence properties of SPDC light and explains all our experimental results. We show that, in contrast with experiments with a well-collimated pump, here both the phase-matching conditions and the position of the focusing plane determine the measured intensity profiles in the image plane of the crystal. The transition from the near-field regime to the far field is investigated. Measurements of two-photon correlations under strong focusing are also presented and the special features thereof are discussed.

  14. Down-Conversion of Short-Wavelength Radiation in LBO Crystal

    NASA Astrophysics Data System (ADS)

    Kononova, N. G.; Kokh, A. E.; Kokh, K. A.; Lanskii, G. V.; Losev, V. F.; Svetlichnyi, V. A.; Andreev, Yu. M.

    2016-12-01

    Comparative model analysis of the possibilities of down-conversion into the terahertz (THz) frequency range of radiation of all-solid-state femtosecond Ti:Sapphire laser systems and hybrid systems based on the same type lasers and equipped with amplifiers on XeF(C-A) and XeCl(C-A) molecules of excimer gases with harmonic generators on nonlinear LBO crystals is performed. It is established that when the crystal is cooled to a temperature of 80 K, the coefficient of optical losses in the frequency range from 0.2 to 1.5 THz linearly decreases in the direction of the X axis by 5-6 times down to 0.1-0.2 cm-1. It is shown that the use of hybrid laser systems as pumping sources will allow the power of generated THz pulses to be increased from 3.5 to 20 times.

  15. Digitral Down Conversion Technology for Tevatron Beam Line Tuner at FNAL

    SciTech Connect

    Schappert, W.; Lorman, E.; Scarpine, V.; Ross, M.C.; Sebek, J.; Straumann, T.; /Fermilab /SLAC

    2008-03-17

    Fermilab is presently in Run II collider operations and is developing instrumentation to improve luminosity. Improving the orbit matching between accelerator components using a Beam Line Tuner (BLT) can improve the luminosity. Digital Down Conversion (DDC) has been proposed as a method for making more accurate beam position measurements. Fermilab has implemented a BLT system using a DDC technique to measure orbit oscillations during injections from the Main Injector to the Tevatron. The output of a fast ADC is downconverted and filtered in software. The system measures the x and y positions, the intensity, and the time of arrival for each proton or antiproton bunch, on a turn-by-turn basis, during the first 1024 turns immediately following injection. We present results showing position, intensity, and time of arrival for both injected and coasting beam. Initial results indicate a position resolution of {approx}20 to 40 microns and a phase resolution of {approx}25 ps.

  16. Lattice topology and spontaneous parametric down-conversion in quadratic nonlinear waveguide arrays

    NASA Astrophysics Data System (ADS)

    Leykam, Daniel; Solntsev, Alexander S.; Sukhorukov, Andrey A.; Desyatnikov, Anton S.

    2015-09-01

    We analyze spontaneous parametric down-conversion in various experimentally feasible one-dimensional quadratic nonlinear waveguide arrays, with emphasis on the relationship between the lattice's topological invariants and the biphoton correlations. Nontrivial topology results in a nontrivial "winding" of the array's Bloch waves, which introduces additional selection rules for the generation of biphotons, independent of existing control using the pump beam's spatial profile and phase-matching conditions. In finite lattices, nontrivial topology produces single-photon edge modes, resulting in "hybrid" biphoton edge modes, with one photon localized at the edge and the other propagating into the bulk. When the single-photon band gap is sufficiently large, these hybrid biphoton modes reside in a band gap of the bulk biphoton Bloch wave spectrum. Numerical simulations support our analytical results.

  17. High Sensitivity Planetary Composition Measurements Using Integrating Cavity Enhanced Spectroscopy

    NASA Astrophysics Data System (ADS)

    Moore, T. Z.; Retherford, K. D.; Davis, M. W.; Raut, U.; Mandt, K. E.; Mason, J. D.; Yakovlev, V. V.

    2016-10-01

    The desire to understand planetary atmospheres, terrestrial chemistry, or search for potential biological markers often involves optical spectroscopy. We present a new approach to planetary instrumentation based on a novel integrating cavity.

  18. Cavity Enhanced Absorption Spectroscopy Using a Broadband Prism Cavity and a Supercontinuum Source

    NASA Astrophysics Data System (ADS)

    Johnston, Paul S.; Lehmann, Kevin K.

    2009-06-01

    The multiplex advantage of current cavity enhanced spectrometers is limited by the high reflectivity bandwidth of the mirrors used to construct the high finesse cavity. Previously, we reported the design and construction of a new spectrometer that circumvents this limitation by utilizing Brewster^{,}s angle prism retroreflectors. The prisms, made from fused silica and combined with a supercontinuum source generated by pumping a highly nonlinear photonic crystal fiber, yields a spectral window ranging from 500 nm to 1750 nm. Recent progress in the instruments development will be discussed, including work on modeling the prism cavity losses, alternative prism material for use in the UV and mid-IR spectral regions, and a new high power supercontinuum source based on mode-locked picosecond laser.

  19. Noise Immune Cavity Enhanced Optical Heterodyne Velocity Modulation Spectroscopy

    NASA Astrophysics Data System (ADS)

    Siller, Brian; Mills, Andrew; Porambo, Michael; McCall, Benjamin

    2011-06-01

    The technique of Cavity Enhanced Velocity Modulation Spectroscopy (CEVMS) has recently been developed. By demodulating the detector signal at twice the plasma modulation frequency (2f), the velocity-modulated ionic absorption signal can be extracted. Although the concentration-modulated excited neutral molecules are also observed at 2f, the ion and neutral signals can be distinguished and separated with phase-sensitive demodulation. The optical cavity provides two major benefits. It increases both the optical path length and the intracavity laser power by a factor of 2×Finesse/π. The multipass advantage allows for much longer path length than was previously possible with unidirectional multipass White cells. The power enhancement combined with perfectly overlapped counterpropagating beams within the cavity allows for sub-Doppler spectroscopy. Although CEVMS showed much potential, its sensitivity was ultimately limited by electronic noise from the plasma interfering with the cavity-locking electronics. We have further improved upon CEVMS by combining it with Noise Immune Cavity Enhanced Optical Heterodyne Molecular Spectroscopy (NICE-OHMS). The laser is frequency modulated at precisely an integer multiple of the free spectral range of the optical cavity; this allows the heterodyne sidebands to be coupled into the optical cavity. Heterodyne detection of the cavity leak-out is immune to noise in the laser-cavity lock, and 2f demodulation further decreases electronic noise in the system and retains ion-neutral discrimination. The additional level of modulation beyond ordinary CEVMS has the added advantage of enabling the observation of both absorption and dispersion signals simultaneously by using two RF mixers, each driving its own lock-in amplifier. In a single scan, four distinct signals can be obtained: absorption and dispersion for ions and excited neutrals. The technique has been demonstrated in the near-IR for N_2^+. B. M. Siller, A. A. Mills and B. J. Mc

  20. Localization of one-photon state in space and Einstein-Podolsky-Rosen paradox in spontaneous parametric down conversion

    NASA Astrophysics Data System (ADS)

    Penin, A. N.; Reutova, T. A.; Sergienko, A. V.

    1992-02-01

    An experiment on one-photon state localization in space using a correlation technique in Spontaneous Parametric Down Conversion (SPDC) process is discussed. Results of measurements demonstrate an idea of the Einstein-Podolsky-Rosen (EPR) paradox for coordinate and momentum variables of photon states. Results of the experiment can be explained with the help of an advanced wave technique. The experiment is based on the idea that two-photon states of optical electromagnetic fields arising in the nonlinear process of the spontaneous parametric down conversion (spontaneous parametric light scattering) can be explained by quantum mechanical theory with the help of a single wave function.

  1. Localization of one-photon state in space and Einstein-Podolsky-Rosen paradox in spontaneous parametric down conversion

    NASA Technical Reports Server (NTRS)

    Penin, A. N.; Reutova, T. A.; Sergienko, A. V.

    1992-01-01

    An experiment on one-photon state localization in space using a correlation technique in Spontaneous Parametric Down Conversion (SPDC) process is discussed. Results of measurements demonstrate an idea of the Einstein-Podolsky-Rosen (EPR) paradox for coordinate and momentum variables of photon states. Results of the experiment can be explained with the help of an advanced wave technique. The experiment is based on the idea that two-photon states of optical electromagnetic fields arising in the nonlinear process of the spontaneous parametric down conversion (spontaneous parametric light scattering) can be explained by quantum mechanical theory with the help of a single wave function.

  2. Gas trace detection with cavity enhanced absorption spectroscopy: a review of its process in the field

    NASA Astrophysics Data System (ADS)

    Liu, Siqi; Luo, Zhifu; Tan, Zhongqi; Long, Xingwu

    2016-11-01

    Cavity-enhanced absorption spectroscopy (CEAS) is a technology in which the intracavity absorption is deduced from the intensity of light transmitted by the high finesse optical cavity. Then the samples' parameters, such as their species, concentration and absorption cross section, would be detection. It was first proposed and demonstrated by Engeln R. [1] and O'Keefe[2] in 1998. This technology has extraordinary detection sensitivity, high resolution and good practicability, so it is used in many fields , such as clinical medicine, gas detection and basic physics research. In this paper, we focus on the use of gas trace detection, including the advance of CEAS over the past twenty years, the newest research progresses, and the prediction of this technology's development direction in the future.

  3. Broadband cavity enhanced spectroscopy in the ultraviolet spectral region for measurements of nitrogen dioxide and formaldehyde

    NASA Astrophysics Data System (ADS)

    Washenfelder, R. A.; Attwood, A. R.; Flores, J. M.; Rudich, Y.; Brown, S. S.

    2015-09-01

    Formaldehyde (CH2O) is the most abundant aldehyde in the atmosphere, and strongly affects photochemistry through its photolysis. We describe simultaneous measurements of CH2O and nitrogen dioxide (NO2) using broadband cavity enhanced spectroscopy in the ultraviolet spectral region. The light source consists of a continuous-wave diode laser focused into a Xenon bulb to produce a plasma that emits high-intensity, broadband light. The plasma discharge is optically filtered and coupled into a 1 m optical cavity. The reflectivity of the cavity mirrors is 0.99933 ± 0.00003 (670 ppm loss) at 338 nm, as determined from the known Rayleigh scattering of He and zero air. This mirror reflectivity corresponds to an effective path length of 1.49 km within the 1 m cell. We measure the cavity output over the 315-350 nm spectral region using a grating monochromator and charge-coupled device (CCD) array detector. We use published reference spectra with spectral fitting software to simultaneously retrieve CH2O and NO2 concentrations. Independent measurements of NO2 standard additions by broadband cavity enhanced spectroscopy and cavity ringdown spectroscopy agree within 2 % (slope for linear fit = 0.98 ± 0.03 with r2 = 0.998). Standard additions of CH2O measured by broadband cavity enhanced spectroscopy and calculated based on flow dilution are also well-correlated, with r2 = 0.9998. During constant, mixed additions of NO2 and CH2O, the 30 s measurement precisions (1σ) of the current configuration were 140 and 210 pptv, respectively. The current 1-min detection limit for extinction measurements at 315-350 nm provides sufficient sensitivity for measurement of trace gases in laboratory experiments and ground-based field experiments. Additionally, the instrument provides highly accurate, spectroscopically-based trace gas detection that may complement higher precision techniques based on non-absolute detection methods. In addition to trace gases, this approach will be appropriate for

  4. Modeling and optimization of photon pair sources based on spontaneous parametric down-conversion

    SciTech Connect

    Kolenderski, Piotr; Banaszek, Konrad; Wasilewski, Wojciech

    2009-07-15

    We address the problem of efficient modeling of photon pairs generated in spontaneous parametric down-conversion and coupled into single-mode fibers. It is shown that when the range of relevant transverse wave vectors is restricted by the pump and fiber modes, the computational complexity can be reduced substantially with the help of the paraxial approximation, while retaining the full spectral characteristics of the source. This approach can serve as a basis for efficient numerical calculations or can be combined with analytically tractable approximations of the phase-matching function. We introduce here a cosine-Gaussian approximation of the phase-matching function that works for a broader range of parameters than the Gaussian model used previously. The developed modeling tools are used to evaluate characteristics of the photon pair sources such as the pair production rate and the spectral purity quantifying frequency correlations. Strategies to generate spectrally uncorrelated photons, necessary in multiphoton interference experiments, are analyzed with respect to trade-offs between parameters of the source.

  5. A small-form-factor piezoelectric vibration energy harvester using a resonant frequency-down conversion

    SciTech Connect

    Sun, Kyung Ho; Kim, Young-Cheol; Kim, Jae Eun

    2014-10-15

    While environmental vibrations are usually in the range of a few hundred Hertz, small-form-factor piezoelectric vibration energy harvesters will have higher resonant frequencies due to the structural size effect. To address this issue, we propose a resonant frequency-down conversion based on the theory of dynamic vibration absorber for the design of a small-form-factor piezoelectric vibration energy harvester. The proposed energy harvester consists of two frequency-tuned elastic components for lowering the first resonant frequency of an integrated system but is so configured that an energy harvesting beam component is inverted with respect to the other supporting beam component for a small form factor. Furthermore, in order to change the unwanted modal characteristic of small separation of resonant frequencies, as is the case with an inverted configuration, a proof mass on the supporting beam component is slightly shifted toward a second proof mass on the tip of the energy harvesting beam component. The proposed small-form-factor design capability was experimentally verified using a fabricated prototype with an occupation volume of 20 × 39 × 6.9 mm{sup 3}, which was designed for a target frequency of as low as 100 Hz.

  6. Robust Ghost Imaging Based on Degenerate Spontaneous Parametric Down-Conversion

    NASA Astrophysics Data System (ADS)

    Kong, Ling-Jun; Si, Yu; Liu, Rui; Wang, Zhou-Xiang; Qi, Wen-Rong; Tu, Chenghou; Li, Yongnan; Wang, Hui-Tian

    2017-05-01

    In traditional ghost imaging, the entangled photon pairs produced from the spontaneous parametric down conversion (SPDC) process are used. There is an intrinsic disadvantage that the utilization efficiency of the photon pairs is very low. Inasmuch as all the correlated photon pairs produced by the degenerate SPDC process can be used to record the image of an object, the ghost imaging scheme we present here has a higher utilization efficiency of the photon pairs. We also investigate the robustness of our experimental scheme. The experimental results show that, no matter whether the photon-pair source is two light cones or two beam-like spots, the clear image of the object can be obtained. The slight rotation of the nonlinear crystal has no influence on the imaging quality. Our experimental results also demonstrate that when the part of the photon-pair source in the signal path or the idler path is blocked by unwanted things, the clear ghost image of the object can still be recorded. Supported by the National Natural Science Foundation of China under Grant Nos 11534006, 11674184 and 11374166, the Natural Science Foundation of Tianjin under Grant No 16JCZDJC31300, and the Collaborative Innovation Center of Extreme Optics.

  7. Spontaneous Parametric Down-Conversion to Create a Quantum Key Distribution System

    NASA Astrophysics Data System (ADS)

    Salgado, Erik; Aragoneses, Andres, , Dr.

    Quantum Key Distribution (QKD) aims to share a secret key between two parties in a secure manner. It provides security benefits over classical communication systems. We have constructed a QKD system that uses quantum entanglement to ensure security against eavesdroppers. We use polarization to encode the binary information of an encryption key. This key is secure due to the quantum properties of light. We use the process of spontaneous parametric down-conversion (SPDC) to create entangled photon pairs. Experimentally, we fire pump (laser) photons through a nonlinear crystal, where there exists a probability of them being annihilated and spontaneously generating two entangled photons of lower energies. A coincidence measurement between two entangled photons indicates the successful transfer of one bit of information, and a coincidence measurement between two disparate photons indicates an error in data transfer. We aim to optimize data transfer rate and reduce error rate. The project is still in development and we look forward to collecting data in the near future.

  8. Down-conversion luminescence from (Ce, Yb) co-doped oxygen-rich silicon oxides

    SciTech Connect

    Heng, C. L. E-mail: terje.finstad@fys.uio.no; Wang, T.; Su, W. Y.; Wu, H. C.; Yin, P. G.; Finstad, T. G. E-mail: terje.finstad@fys.uio.no

    2016-03-28

    We have studied down-conversion photoluminescence (PL) from (Ce, Yb) co-doped “oxygen rich” silicon oxide films prepared by sputtering and annealing. The Ce{sup 3+} ∼510 nm PL is sensitive to the Ce concentration of the films and is much stronger for 3 at. % Ce than for 2 at. % Ce after annealing at 1200 °C. The PL emission and excitation spectroscopy results indicate that the excitation of Yb{sup 3+} is mainly through an energy transfer from Ce{sup 3+} to Yb{sup 3+}, oxide defects also play a role in the excitation of Yb{sup 3+} after lower temperature (∼800 °C) annealing. The Ce{sup 3+} 510 nm photon excites mostly only one Yb{sup 3+} 980 nm photon. Temperature-dependent PL measurements suggest that the energy transfer from Ce{sup 3+} to Yb{sup 3+} is partly thermally activated.

  9. A small-form-factor piezoelectric vibration energy harvester using a resonant frequency-down conversion

    NASA Astrophysics Data System (ADS)

    Sun, Kyung Ho; Kim, Young-Cheol; Kim, Jae Eun

    2014-10-01

    While environmental vibrations are usually in the range of a few hundred Hertz, small-form-factor piezoelectric vibration energy harvesters will have higher resonant frequencies due to the structural size effect. To address this issue, we propose a resonant frequency-down conversion based on the theory of dynamic vibration absorber for the design of a small-form-factor piezoelectric vibration energy harvester. The proposed energy harvester consists of two frequency-tuned elastic components for lowering the first resonant frequency of an integrated system but is so configured that an energy harvesting beam component is inverted with respect to the other supporting beam component for a small form factor. Furthermore, in order to change the unwanted modal characteristic of small separation of resonant frequencies, as is the case with an inverted configuration, a proof mass on the supporting beam component is slightly shifted toward a second proof mass on the tip of the energy harvesting beam component. The proposed small-form-factor design capability was experimentally verified using a fabricated prototype with an occupation volume of 20 × 39 × 6.9 mm3, which was designed for a target frequency of as low as 100 Hz.

  10. Aspects for efficient wide spectral band THz generation via CO2 laser down conversion

    NASA Astrophysics Data System (ADS)

    Panchenko, Yu. N.; Andreev, Yu. M.; Lanskii, G. V.; Losev, V. F.; Lubenko, D. M.

    2015-02-01

    Detailed model study of THz generation by CO2 laser down-conversion in pure and solid solution crystals GaSe1-xSx is carried out for the first time. Both forward and backward collinear interactions of common (eo-e, oe-e, oe-o, oo-e, ee-o) and original (ee-e, oo-o) types are considered. Possibility of realization, phase matching angles and figure of merits are estimated for line mixing within 9 μm and 10 μm emission bands, as well between them. Dispersion properties of o- and e-wave refractive indices and absorption coefficients for GaSe, GaS and GaSe1-xSx crystals were preliminary measured by THz-TDS, approximated in the equation form and then used in the study. Estimated results are presented in the form of 3-D figures that are suitable for rapid analyses of DFG parameters. The most efficient type of interaction is eo-o type. Optimally doped (x = 0.09-0.13) GaSe1-xSx crystals are from 4 to 5 times more efficient at limit pump intensity than not doped GaSe crystals.

  11. Simple scheme for generating four-photon polarization-entangled decoherence-free states using spontaneous parametric down-conversions

    SciTech Connect

    Zou Xubo; Shu Jing; Guo Guangcan

    2006-05-15

    We propose a simple scheme for the generation of four-photon polarization-entangled decoherence-free states by using a pair of spontaneous parametric down-conversions and one tunable beam splitter. The scheme is based on post-selection strategy and feasible by current experimental technology.

  12. Demonstration of a mid-infrared cavity enhanced absorption spectrometer for breath acetone detection.

    PubMed

    Ciaffoni, Luca; Hancock, Gus; Harrison, Jeremy J; van Helden, Jean-Pierre H; Langley, Cathryn E; Peverall, Robert; Ritchie, Grant A D; Wood, Simon

    2013-01-15

    A high-resolution absorption spectrum of gaseous acetone near 8.2 μm has been taken using both Fourier transform and quantum cascade laser (QCL)-based infrared spectrometers. Absolute absorption cross sections within the 1215-1222 cm(-1) range have been determined, and the spectral window around 1216.5 cm(-1) (σ = 3.4 × 10(-19) cm(2) molecule(-1)) has been chosen for monitoring trace acetone in exhaled breath. Acetone at sub parts-per-million (ppm) levels has been measured in a breath sample with a precision of 0.17 ppm (1σ) by utilizing a cavity enhanced absorption spectrometer constructed from the QCL source and a linear, low-volume, optical cavity. The use of a water vapor trap ensured the accuracy of the results, which have been corroborated by mass spectrometric measurements.

  13. Cavity-Enhanced Absorption Spectroscopy and Photoacoustic Spectroscopy for Human Breath Analysis

    NASA Astrophysics Data System (ADS)

    Wojtas, J.; Tittel, F. K.; Stacewicz, T.; Bielecki, Z.; Lewicki, R.; Mikolajczyk, J.; Nowakowski, M.; Szabra, D.; Stefanski, P.; Tarka, J.

    2014-12-01

    This paper describes two different optoelectronic detection techniques: cavity-enhanced absorption spectroscopy and photoacoustic spectroscopy. These techniques are designed to perform a sensitive analysis of trace gas species in exhaled human breath for medical applications. With such systems, the detection of pathogenic changes at the molecular level can be achieved. The presence of certain gases (biomarkers), at increased concentration levels, indicates numerous human diseases. Diagnosis of a disease in its early stage would significantly increase chances for effective therapy. Non-invasive, real-time measurements, and high sensitivity and selectivity, capable of minimum discomfort for patients, are the main advantages of human breath analysis. At present, monitoring of volatile biomarkers in breath is commonly useful for diagnostic screening, treatment for specific conditions, therapy monitoring, control of exogenous gases (such as bacterial and poisonous emissions), as well as for analysis of metabolic gases.

  14. Cavity-enhanced measurements for determining dielectric-membrane thickness and complex index of refraction.

    PubMed

    Stambaugh, Corey; Durand, Mathieu; Kemiktarak, Utku; Lawall, John

    2014-08-01

    The material properties of silicon nitride (SiN) play an important role in the performance of SiN membranes used in optomechanical applications. An optimum design of a subwavelength high-contrast grating requires accurate knowledge of the membrane thickness and index of refraction, and its performance is ultimately limited by material absorption. Here we describe a cavity-enhanced method to measure the thickness and complex index of refraction of dielectric membranes with small, but nonzero, absorption coefficients. By determining Brewster's angle and an angle at which reflection is minimized by means of destructive interference, both the real part of the index of refraction and the sample thickness can be measured. A comparison of the losses in the empty cavity and the cavity containing the dielectric sample provides a measurement of the absorption.

  15. Optical re-injection in cavity-enhanced absorption spectroscopy

    PubMed Central

    Leen, J. Brian; O’Keefe, Anthony

    2014-01-01

    Non-mode-matched cavity-enhanced absorption spectrometry (e.g., cavity ringdown spectroscopy and integrated cavity output spectroscopy) is commonly used for the ultrasensitive detection of trace gases. These techniques are attractive for their simplicity and robustness, but their performance may be limited by the reflection of light from the front mirror and the resulting low optical transmission. Although this low transmitted power can sometimes be overcome with higher power lasers and lower noise detectors (e.g., in the near-infrared), many regimes exist where the available light intensity or photodetector sensitivity limits instrument performance (e.g., in the mid-infrared). In this article, we describe a method of repeatedly re-injecting light reflected off the front mirror of the optical cavity to boost the cavity's circulating power and deliver more light to the photodetector and thus increase the signal-to-noise ratio of the absorption measurement. We model and experimentally demonstrate the method's performance using off-axis cavity ringdown spectroscopy (OA-CRDS) with a broadly tunable external cavity quantum cascade laser. The power coupled through the cavity to the detector is increased by a factor of 22.5. The cavity loss is measured with a precision of 2 × 10−10 cm−1/\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{upgreek} \\usepackage{mathrsfs} \\setlength{\\oddsidemargin}{-69pt} \\begin{document} }{}$\\sqrt {{\\rm Hz;}}$\\end{document} Hz ; an increase of 12 times over the standard off-axis configuration without reinjection and comparable to the best reported sensitivities in the mid-infrared. Finally, the re-injected CRDS system is used to measure the spectrum of several volatile organic compounds, demonstrating the improved ability to resolve weakly absorbing spectroscopic features. PMID:25273701

  16. Optical re-injection in cavity-enhanced absorption spectroscopy.

    PubMed

    Leen, J Brian; O'Keefe, Anthony

    2014-09-01

    Non-mode-matched cavity-enhanced absorption spectrometry (e.g., cavity ringdown spectroscopy and integrated cavity output spectroscopy) is commonly used for the ultrasensitive detection of trace gases. These techniques are attractive for their simplicity and robustness, but their performance may be limited by the reflection of light from the front mirror and the resulting low optical transmission. Although this low transmitted power can sometimes be overcome with higher power lasers and lower noise detectors (e.g., in the near-infrared), many regimes exist where the available light intensity or photodetector sensitivity limits instrument performance (e.g., in the mid-infrared). In this article, we describe a method of repeatedly re-injecting light reflected off the front mirror of the optical cavity to boost the cavity's circulating power and deliver more light to the photodetector and thus increase the signal-to-noise ratio of the absorption measurement. We model and experimentally demonstrate the method's performance using off-axis cavity ringdown spectroscopy (OA-CRDS) with a broadly tunable external cavity quantum cascade laser. The power coupled through the cavity to the detector is increased by a factor of 22.5. The cavity loss is measured with a precision of 2 × 10(-10) cm(-1)/√Hz; an increase of 12 times over the standard off-axis configuration without reinjection and comparable to the best reported sensitivities in the mid-infrared. Finally, the re-injected CRDS system is used to measure the spectrum of several volatile organic compounds, demonstrating the improved ability to resolve weakly absorbing spectroscopic features.

  17. Optical re-injection in cavity-enhanced absorption spectroscopy

    SciTech Connect

    Leen, J. Brian O’Keefe, Anthony

    2014-09-15

    Non-mode-matched cavity-enhanced absorption spectrometry (e.g., cavity ringdown spectroscopy and integrated cavity output spectroscopy) is commonly used for the ultrasensitive detection of trace gases. These techniques are attractive for their simplicity and robustness, but their performance may be limited by the reflection of light from the front mirror and the resulting low optical transmission. Although this low transmitted power can sometimes be overcome with higher power lasers and lower noise detectors (e.g., in the near-infrared), many regimes exist where the available light intensity or photodetector sensitivity limits instrument performance (e.g., in the mid-infrared). In this article, we describe a method of repeatedly re-injecting light reflected off the front mirror of the optical cavity to boost the cavity's circulating power and deliver more light to the photodetector and thus increase the signal-to-noise ratio of the absorption measurement. We model and experimentally demonstrate the method's performance using off-axis cavity ringdown spectroscopy (OA-CRDS) with a broadly tunable external cavity quantum cascade laser. The power coupled through the cavity to the detector is increased by a factor of 22.5. The cavity loss is measured with a precision of 2 × 10{sup −10} cm{sup −1}/√(Hz;) an increase of 12 times over the standard off-axis configuration without reinjection and comparable to the best reported sensitivities in the mid-infrared. Finally, the re-injected CRDS system is used to measure the spectrum of several volatile organic compounds, demonstrating the improved ability to resolve weakly absorbing spectroscopic features.

  18. Hydrothermal synthesis, characterization and up/down-conversion luminescence of barium rare earth fluoride nanocrystals

    SciTech Connect

    Jia, Li-Ping; Zhang, Qiang; Yan, Bing

    2014-07-01

    Graphical abstract: Lanthanide ions doped bare earth rare earth fluoride nanocrystals are synthesized by hydrothermal technology and characterized. The down/up-conversion luminescence of them are discussed. - Highlights: • Mixed hydrothermal system H{sub 2}O–OA (EDA)–O-A(LO-A) is used for synthesis. • Barium rare earth fluoride nanocrystals are synthesized comprehensively. • Luminescence for down-conversion and up-conversion are obtained for these systems. - Abstract: Mixed hydrothermal system H{sub 2}O–OA (EDA)–O-A(LO-A) is developed to synthesize barium rare earth fluorides nanocrystals (OA = oleylamine, EDA = ethylenediamine, O-A = oleic acid and LO-A = linoleic acid). They are presented as BaREF{sub 5} (RE = Ce, Pr, Nd, Eu, Gd, Tb, Dy, Y, Tm, Lu) and Ba{sub 2}REF{sub 7} (RE = La, Sm, Ho, Er, Yb). The influence of reaction parameters (rare earth species, hydrothermal system and temperature) is checked on the phase and shape evolution of the fluoride nanocrystals. It is found that reaction time and temperature of these nanocrystals using EDA (180 °C, 6 h) is lower than those of them using OA (220 °C, 10 h). The photoluminescence properties of these fluorides activated by some rare earth ions (Nd{sup 3+}, Eu{sup 3+}, Tb{sup 3+}) are studied, and especially up-conversion luminescence of the four fluoride nanocrystal systems (Ba{sub 2}LaF{sub 7}:Yb, Tm(Er), Ba{sub 2}REF{sub 7}:Yb, Tm(Er) (RE = Gd, Y, Lu)) is observed.

  19. Full analysis of multi-photon pair effects in spontaneous parametric down conversion based photonic quantum information processing

    NASA Astrophysics Data System (ADS)

    Takeoka, Masahiro; Jin, Rui-Bo; Sasaki, Masahide

    2015-04-01

    In spontaneous parametric down conversion (SPDC) based quantum information processing (QIP) experiments, there is a tradeoff between the coincidence count rates (i.e. the pumping power of the SPDC), which limits the rate of the protocol, and the visibility of the quantum interference, which limits the quality of the protocol. This tradeoff is mainly caused by the multi-photon pair emissions from the SPDCs. In theory, the problem is how to model the experiments without truncating these multi-photon emissions while including practical imperfections. In this paper, we establish a method to theoretically simulate SPDC-based QIPs which fully incorporates the effect of multi-photon emissions and various practical imperfections. The key ingredient in our method is the application of the characteristic function formalism which has been used in continuous variable QIPs. We apply our method to three examples, the Hong-Ou-Mandel interference and the Einstein-Podolsky-Rosen interference experiments, and the concatenated entanglement swapping protocol. For the first two examples, we show that our theoretical results quantitatively agree with the recent experimental results. Also we provide the closed expressions for these interference visibilities with the full multi-photon components and various imperfections. For the last example, we provide the general theoretical form of the concatenated entanglement swapping protocol in our method and show the numerical results up to five concatenations. Our method requires only a small computational resource (a few minutes by a commercially available computer), which was not possible in the previous theoretical approach. Our method will have applications in a wide range of SPDC-based QIP protocols with high accuracy and a reasonable computational resource.

  20. Molecular-like Ag clusters sensitized near-infrared down-conversion luminescence in oxyfluoride glasses for broadband spectral modification

    NASA Astrophysics Data System (ADS)

    Lin, Hang; Chen, Daqin; Yu, Yunlong; Zhang, Rui; Wang, Yuansheng

    2013-08-01

    Molecular-like Ag clusters sized at 1-4 nm have been stabilized in Pb/Cd-free oxyfluoride glasses, showing broadband excitation/emission characteristics and unique wavelength-dependent luminescent performance with a maximal quantum yield of 26.9%. It was experimentally demonstrated that an energy transfer route of Ag clusters → Tb3+ → Yb3+ occurs in Ag+/Tb3+/Yb3+ tri-doped sample, wherein Ag clusters act as sensitizers for near-infrared down-conversion spectral modification. Hopefully, the proposed strategy that noble metal clusters being applied for harvesting solar radiation may potentially solve the sticky problems of the narrow excitation bandwidth and the low excitation efficiency in rare earth ions doped down-conversion materials.

  1. Molecular-like Ag clusters sensitized near-infrared down-conversion luminescence in oxyfluoride glasses for broadband spectral modification

    SciTech Connect

    Lin, Hang; Chen, Daqin; Yu, Yunlong; Zhang, Rui; Wang, Yuansheng

    2013-08-26

    Molecular-like Ag clusters sized at 1–4 nm have been stabilized in Pb/Cd-free oxyfluoride glasses, showing broadband excitation/emission characteristics and unique wavelength-dependent luminescent performance with a maximal quantum yield of 26.9%. It was experimentally demonstrated that an energy transfer route of Ag clusters → Tb{sup 3+} → Yb{sup 3+} occurs in Ag{sup +}/Tb{sup 3+}/Yb{sup 3+} tri-doped sample, wherein Ag clusters act as sensitizers for near-infrared down-conversion spectral modification. Hopefully, the proposed strategy that noble metal clusters being applied for harvesting solar radiation may potentially solve the sticky problems of the narrow excitation bandwidth and the low excitation efficiency in rare earth ions doped down-conversion materials.

  2. NO_2 Trace Measurements by Optical-Feedback Cavity-Enhanced Absorption Spectroscopy

    NASA Astrophysics Data System (ADS)

    Ventrillard-Courtillot, I.; Desbois, Th.; Foldes, T.; Romanini, D.

    2009-06-01

    In order to reach the sub-ppb NO_2 detection level required for environmental applications in remote areas, we develop a spectrometer based on a technique introduced a few years ago, named Optical-Feedback Cavity-Enhanced Absorption Spectroscopy (OF-CEAS) [1]. It allows very sensitive and selective measurements, together with the realization of compact and robust set-ups as was subsequently demonstrated during measurements campaigns in harsh environments [2]. OF-CEAS benefits from the optical feedback to efficiently inject a cw-laser in a V-shaped high finesse cavity (typically 10 000). Cavity-enhanced absorption spectra are acquired on a small spectral region (˜1 cm^{-1}) that enables selective and quantitative measurements at a fast acquisition rate with a detection limit of several 10^{-10} cm^{-1} as reported in this work. Spectra are obtained with high spectral definition (150 MHz highly precisely spaced data points) and are self calibrated by cavity rind-down measurements regularly performed (typically every second). NO_2 measurements are performed with a commercial extended cavity diode laser around 411 nm, spectral region where intense electronic transitions occur. We will describe the set-up developed for in-situ measurements allowing real time concentration measurements at typically 5 Hz; and then report on the measurements performed with calibrated NO_2 reference samples to evaluate the linearity of the apparatus. The minimum detectable absorption loss is estimated by considering the standard deviation of the residual of one spectrum. We achieved 2x10^{-10} cm^{-1} for a single spectrum recorded in less than 100 ms at 100 mbar. It leads to a potential detection limit of 3x10^8 molecules/cm^3, corresponding to about 150 pptv at this pressure. [1] J. Morville, S. Kassi, M. Chenevier, and D. Romanini, Appl. Phys. B, 80, 1027 (2005). [2] D. Romanini, M. Chenevrier, S. Kassi, M. Schmidt, C. Valant, M. Ramonet, J. Lopez, and H.-J. Jost, Appl. Phys. B, 83, 659

  3. Evidence of significant down-conversion in a Si-based solar cell using CuInS{sub 2}/ZnS core shell quantum dots

    SciTech Connect

    Gardelis, Spiros Nassiopoulou, Androula G.

    2014-05-05

    We report on the increase of up to 37.5% in conversion efficiency of a Si-based solar cell after deposition of light-emitting Cd-free, CuInS{sub 2}/ZnS core shell quantum dots on the active area of the cell due to the combined effect of down-conversion and the anti- reflecting property of the dots. We clearly distinguished the effect of down-conversion from anti-reflection and estimated an enhancement of up to 10.5% in the conversion efficiency due to down-conversion.

  4. Atmospheric HONO and NO2 measurement based on a broadband cavity enhanced UV-LED spectrometer

    NASA Astrophysics Data System (ADS)

    Wu, Tao; Zha, Qiaozhi; Chen, Weidong; Xu, Zheng; Wang, Tao; He, Xingdao

    2015-04-01

    Nitrous acid (HONO) is a key component in tropospheric oxidant chemistry due to its contribution to the cycles of nitrogen oxides (NOx) and hydrogen oxides (HOx). Though numerous laboratory, field, and modeling studies were performed to explain the observed HONO concentrations in the atmosphere, the knowledge of atmospheric HONO chemistry is still not well understood and sometimes controversial [1]. Accurate measurements of HONO and its precursors with high precision should aid in understanding the HONO chemistry. In this paper we report on the measurements of HONO and NO2 concentrations at a suburban site of Tung Chung in Hong Kong during a field intercomparison campaign using a broadband cavity enhanced UV-LED spectrometer. 1σ detection limits of 0.3 ppbv for HONO and 1 ppbv for NO2 were achieved with an optimum acquisition time of 120 s. The measured HONO and NO2 concentrations were compared with the data from commercial HONO (LOPAP) and NO2 (NOX-analyzer) measurement instrument. Typical diurnal pattern of HONO have been observed and the potential formation sources have been analyzed [2]. Acknowledgements The supported by National Natural Science Foundation of China (No. 41265011), Educational Commission of Jiangxi Province of China (No.GJJ14548) and Environment and Conservation Fund of the Hong Kong Special Administrative Region (No. 7/2009). The support of the IRENI program of the Région Nord-Pas de Calaisn, is acknowledged. References [1] W. Chen, R. Maamary, X. Cui, T. Wu, E. Fertein, D. Dewaele, F. Cazier, Q. Zha, Z. Xu, T. Wang, Y. Wang, W. Zhang, X. Gao, W. Liu, F. Dong, 'Photonic Sensing of Environmental Gaseous Nitrous Acid (HONO): Opportunities and Challenges' in The Wonder of Nanotechnology: Quantum Optoelectronic Devices and Applications, M. Razeghi. L. Esaki, and K. von Klitzing, Eds., SPIE Press, Bellingham, WA, 2013, pp. 693-737 [2] T. Wu, Q. Zha, W. Chen, Z. XU, T. Wang, X. He, 'Development and deployment of a cavity enhanced UV

  5. Cavity-enhanced absorption spectroscopy to characterize atmospheric pressure plasma jets

    NASA Astrophysics Data System (ADS)

    van Helden, Jean-Pierre; Nave, Andy; Reuter, Stephan; Roepcke, Juergen; Gianella, Michele; Ritchie, Grant

    2016-09-01

    Non-equilibrium atmospheric pressure plasma jets gain more and more interest as their technological applications increase in diverse fields such as material processing and plasma medicine. Hence, it is essential to diagnose the fluxes of the species generated by these plasma sources to identify relevant fundamental processes and to improve process efficiency. Especially for a comprehensive understanding of the kinetics of the transient species involved, high precision measurements of reactive molecular precursors, free radicals and to identify of any short lived species are of crucial importance. However, the detection of transient species in these type of plasmas poses a challenge for diagnostic techniques as the plasmas typically have small dimensions and high density gradients in space and time. We have overcome these limitations by using cavity-enhanced absorption spectroscopy (CEAS). In this contribution, the latest results concerning the detection of transient species in two types of plasma jets employing CEAS in the near- and mid-infrared spectral range will be presented. We will show that with these methods spatially resolved investigations of concentrations in the mm sized effluent of the plasma jet can be achieved.

  6. Lasic -Cavity-enhanced molecular iodine laser frequency stabilization for space projects

    NASA Astrophysics Data System (ADS)

    Turazza, Oscar; Acef, O.; Auger, G.; Halloin, H.; Duburck, F.; Plagnol, E.; Holleville, D.; Dimarcq, N.; Binetruy, P.; Brillet, A.; Lemonde, P.; Devismes, E.; Prat, P.; Lours, M.; Tuckey, P.; Argence, B.

    We present work in progress at SYRTE, APC and ARTEMIS aiming at stabilizing the frequency of a Nd:YAG laser using saturated absorption spectroscopy of molecular iodine 127I2. The novel design of the LASIC project allows for robustness and compacity while achieving high-performance phase noise suppression. The project is a follow-up of the laser stabilization work started at Artemis and continued at APC. The use of a low-finesse bow-tie optical cavity around the iodine absorber, combined with an adapted high-frequency modulation of the laser phase -NICE-OHMS technique-yields shot-noise limited saturated absorption signals with cavity-enhanced signal-to-noise ratios. Residual fractional frequency instability in terms of Allan Std. Deviation is expected below 10-14 @1s integration time and down to 10-15 over several hours. The compact iodine / cavity design, and performance well above LISA requirements make this project an interesting candidate for the space-based Gravitational Waves detector. We discuss the scientific background and outline of this project within the LISA framework, as well as its potential impact on other stringent technical requirements of the LISA project (e.g. U.S.O. clock-stability, arm-length measurements. . . ). We also present other possible applications for space projects involving interferometry, laser ranging or onboard ultrastable oscillators.

  7. Microwave cavity-enhanced transduction for plug and play nanomechanics at room temperature

    PubMed Central

    Faust, T.; Krenn, P.; Manus, S.; Kotthaus, J.P.; Weig, E.M.

    2012-01-01

    Following recent insights into energy storage and loss mechanisms in nanoelectromechanical systems (NEMS), nanomechanical resonators with increasingly high quality factors are possible. Consequently, efficient, non-dissipative transduction schemes are required to avoid the dominating influence of coupling losses. Here we present an integrated NEMS transducer based on a microwave cavity dielectrically coupled to an array of doubly clamped pre-stressed silicon nitride beam resonators. This cavity-enhanced detection scheme allows resolving of the resonators' Brownian motion at room temperature while preserving their high mechanical quality factor of 290,000 at 6.6 MHz. Furthermore, our approach constitutes an 'opto'-mechanical system in which backaction effects of the microwave field are employed to alter the effective damping of the resonators. In particular, cavity-pumped self-oscillation yields a linewidth of only 5 Hz. Thereby, an adjustement-free, all-integrated and self-driven nanoelectromechanical resonator array interfaced by just two microwave connectors is realised, which is potentially useful for applications in sensing and signal processing. PMID:22395619

  8. Continuous Vernier filtering of an optical frequency comb for broadband cavity-enhanced molecular spectroscopy

    NASA Astrophysics Data System (ADS)

    Rutkowski, Lucile; Morville, Jérôme

    2017-01-01

    We have recently introduced the Vernier-based Direct Frequency Comb Cavity-Enhanced Spectroscopy technique which allows us to record broadband spectra at high sensitivity and GHz resolution (Rutkowski and Morville, 2014) [1]. We discuss here the effect of Vernier filtering on the observed lineshapes in the 3 ν + δ band of water vapor and the entire A-band of oxygen around 800 nm in ambient air. We derive expressions for the absorption profiles resulting from the continuous Vernier filtering method, testing them on spectra covering more than 2000 cm-1 around 12,500 cm-1. With 31,300 independent spectral elements acquired at the second time scale, an absorption baseline noise of 2 ×10-8cm-1 is obtained, providing a figure of merit of 1.1×10-10 cm-1/√{ Hz } per spectral element with a cavity finesse of 3000 and a cavity round-trip length around 3.3 m.

  9. Aspects of the Application of Cavity Enhanced Spectroscopy to Nitrogen Oxides Detection

    PubMed Central

    Wojtas, Jacek; Mikolajczyk, Janusz; Bielecki, Zbigniew

    2013-01-01

    This article presents design issues of high-sensitive laser absorption spectroscopy systems for nitrogen oxides (NOx) detection. Examples of our systems and their investigation results are also described. The constructed systems use one of the most sensitive methods, cavity enhanced absorption spectroscopy (CEAS). They operate at different wavelength ranges using a blue—violet laser diode (410 nm) as well as quantum cascade lasers (5.27 μm and 4.53 μm). Each of them is configured as a one or two channel measurement device using, e.g., time division multiplexing and averaging. During the testing procedure, the main performance features such as detection limits and measurements uncertainties have been determined. The obtained results are 1 ppb NO2, 75 ppb NO and 45 ppb N2O. For all systems, the uncertainty of concentration measurements does not exceed a value of 13%. Some experiments with explosives are also discussed. A setup equipped with a concentrator of explosives vapours was used. The detection method is based either on the reaction of the sensors to the nitrogen oxides directly emitted by the explosives or on the reaction to the nitrogen oxides produced during thermal decomposition of explosive vapours. For TNT, PETN, RDX and HMX a detection limit better than 1 ng has been achieved. PMID:23752566

  10. Cavity-enhanced measurements of hydrogen peroxide absorption cross sections from 353 to 410 nm.

    PubMed

    Kahan, Tara F; Washenfelder, Rebecca A; Vaida, Veronica; Brown, Steven S

    2012-06-21

    We report near-ultraviolet and visible absorption cross sections of hydrogen peroxide (H(2)O(2)) using incoherent broad-band cavity-enhanced absorption spectroscopy (IBBCEAS), a recently developed, high-sensitivity technique. The measurements reported here span the range of 353-410 nm and extend published electronic absorption cross sections by 60 nm to absorption cross sections below 1 × 10(-23) cm(2) molecule(-1). We have calculated photolysis rate constants for H(2)O(2) in the lower troposphere at a range of solar zenith angles by combining the new measurements with previously reported data at wavelengths shorter than 350 nm. We predict that photolysis at wavelengths longer than those included in the current JPL recommendation may account for up to 28% of the total hydroxyl radical (OH) production from H(2)O(2) photolysis under some conditions. Loss of H(2)O(2) via photolysis may be of the same order of magnitude as reaction with OH and dry deposition in the lower atmosphere; these processes have very different impacts on HO(x) loss and regeneration.

  11. Aspects of the application of cavity enhanced spectroscopy to nitrogen oxides detection.

    PubMed

    Wojtas, Jacek; Mikolajczyk, Janusz; Bielecki, Zbigniew

    2013-06-10

    This article presents design issues of high-sensitive laser absorption spectroscopy systems for nitrogen oxides (NO(x)) detection. Examples of our systems and their investigation results are also described. The constructed systems use one of the most sensitive methods, cavity enhanced absorption spectroscopy (CEAS). They operate at different wavelength ranges using a blue--violet laser diode (410 nm) as well as quantum cascade lasers (5.27 µm and 4.53 µm). Each of them is configured as a one or two channel measurement device using, e.g., time division multiplexing and averaging. During the testing procedure, the main performance features such as detection limits and measurements uncertainties have been determined. The obtained results are 1 ppb NO(2), 75 ppb NO and 45 ppb N(2)O. For all systems, the uncertainty of concentration measurements does not exceed a value of 13%. Some experiments with explosives are also discussed. A setup equipped with a concentrator of explosives vapours was used. The detection method is based either on the reaction of the sensors to the nitrogen oxides directly emitted by the explosives or on the reaction to the nitrogen oxides produced during thermal decomposition of explosive vapours. For TNT, PETN, RDX and HMX a detection limit better than 1 ng has been achieved.

  12. Towards passive and active laser stabilization using cavity-enhanced atomic interaction

    NASA Astrophysics Data System (ADS)

    Schäffer, S. A.; Christensen, B. T. R.; Rathmann, S. M.; Appel, M. H.; Henriksen, M. R.; Thomsen, J. W.

    2017-02-01

    Ultra stable frequency references such as the ones used in optical atomic clocks and for quantum metrology may be obtained by stabilizing a laser to an optical cavity that is stable over time. State-of-the-art frequency references are constructed in this way, but their stabilities are currently limited by thermally induced length fluctuations in the reference cavity. Several alternative approaches using the potential for frequency discriminating of highly forbidden narrow atomic transitions have been proposed in, e.g., [1] and [2]. In this proceeding we will present some of the ongoing experimental efforts derived from these proposals, to use cavity-enhanced interaction with atomic 88Sr samples as a frequency reference for laser stabilization. Such systems can be realized using both passive and active approaches where either the atomic phase response is used as an error signal, or the narrow atomic transition itself is used as a source for a spectrally pure laser. Both approaches shows the promise of being able to compete with the current state of the art in stable lasers and have similar limitations on their ultimately achievable linewidths [1, 2].

  13. Applications of broadband cavity enhanced spectroscopy for measurements of trace gases and aerosols

    NASA Astrophysics Data System (ADS)

    Washenfelder, R. A.; Attwood, A. R.; Brock, C. A.; Brown, S. S.; Dube, W. P.; Flores, J. M.; Langford, A. O.; Min, K. E.; Rudich, Y.; Stutz, J.; Wagner, N.; Young, C.; Zarzana, K. J.

    2015-12-01

    Broadband cavity enhanced spectroscopy (BBCES) uses a broadband light source, optical cavity, and multichannel detector to measure light extinction with high sensitivity. This method differs from cavity ringdown spectroscopy, because it uses an inexpensive, incoherent light source and allows optical extinction to be determined simultaneously across a broad wavelength region.Spectral fitting methods can be used to retrieve multiple absorbers across the observed wavelength region. We have successfully used this method to measure glyoxal (CHOCHO), nitrous acid (HONO), and nitrogen dioxide (NO2) from ground-based and aircraft-based sampling platforms. The detection limit (2-sigma) in 5 s for retrievals of CHOCHO, HONO and NO2 is 32, 250 and 80 parts per trillion (pptv).Alternatively, gas-phase absorbers can be chemically removed to allow the accurate determination of aerosol extinction. In the laboratory, we have used the aerosol extinction measurements to determine scattering and absorption as a function of wavelength. We have deployed a ground-based field instrument to measure aerosol extinction, with a detection limit of approximately 0.2 Mm-1 in 1 min.BBCES methods are most widely used in the near-ultraviolet and visible spectral region. Recently, we have demonstrated measurements at 315-350 nm for formaldehyde (CH2O) and NO2. Extending the technique further into the ultraviolet spectral region will allow important additional measurements of trace gas species and aerosol extinction.

  14. Shock-Tube Measurement of Acetone Dissociation Using Cavity-Enhanced Absorption Spectroscopy of CO.

    PubMed

    Wang, Shengkai; Sun, Kai; Davidson, David F; Jeffries, Jay B; Hanson, Ronald K

    2015-07-16

    A direct measurement for the rate constant of the acetone dissociation reaction (CH3COCH3 = CH3CO + CH3) was conducted behind reflected shock wave, utilizing a sub-ppm sensitivity CO diagnostic achieved by cavity-enhanced absorption spectroscopy (CEAS). The current experiment eliminated the influence from secondary reactions and temperature change by investigating the clean pyrolysis of <20 ppm acetone in argon. For the first time, the acetone dissociation rate constant (k1) was directly measured over 5.5 orders of magnitude with a high degree of accuracy: k1 (1004-1494 K, 1.6 atm) = 4.39 × 10(55) T(-11.394) exp(-52 140K/T) ± 24% s(-1). This result was seen to agree with most previous studies and has bridged the gap between their temperature and pressure conditions. The current work also served as an example demonstration of the potential of using the CEAS technique in shock-tube kinetics studies.

  15. Shock-tube measurements of excited oxygen atoms using cavity-enhanced absorption spectroscopy.

    PubMed

    Nations, Marcel; Wang, Shengkai; Goldenstein, Christopher S; Sun, Kai; Davidson, David F; Jeffries, Jay B; Hanson, Ronald K

    2015-10-10

    We report the use of cavity-enhanced absorption spectroscopy (CEAS) using two distributed feedback diode lasers near 777.2 and 844.6 nm for sensitive, time-resolved, in situ measurements of excited-state populations of atomic oxygen in a shock tube. Here, a 1% O2/Ar mixture was shock-heated to 5400-8000 K behind reflected shock waves. The combined use of a low-finesse cavity, fast wavelength scanning of the lasers, and an off-axis alignment enabled measurements with 10 μs time response and low cavity noise. The CEAS absorption gain factors of 104 and 142 for the P35←S520 (777.2 nm) and P0,1,23←S310 (844.6 nm) atomic oxygen transitions, respectively, significantly improved the detection sensitivity over conventional single-pass measurements. This work demonstrates the potential of using CEAS to improve shock-tube studies of nonequilibrium electronic-excitation processes at high temperatures.

  16. Down-conversion photoluminescence sensitizing plasmonic silver nanoparticles on ZnO nanorods to generate hydrogen by water splitting photochemistry

    NASA Astrophysics Data System (ADS)

    Kung, Po-Yen; Huang, Li-Wen; Shen, Tin-Wei; Wang, Wen-Lin; Su, Yen-Hsun; Lin, Melody I.

    2015-01-01

    Silver nanoparticles fabricated onto the surface of the ZnO nanorods form the photoanode and generate photoelectric current due to surface plasmon resonance, which serves as anode electrodes in photoelectrochemical hydrogen production. In order to increase the absorption spectrum of photoanode, organic pigments were utilized as photo-sensitizers to generate down-conversion photoluminescence to excite surface plasmon resonances of silver nanoparticles. The way of using light to carry the energy in electronic scattering regime runs the system for the enhancement of solar water splitting efficiency. It was significantly tuned in environmentally sustainable applications for power generation and development of alternative energy.

  17. W-band OFDM Radio-over-Fiber system with power detector for vector signal down-conversion.

    PubMed

    Lin, Chun-Ting; Wu, Meng-Fan; Ho, Chun-Hung; Li, Che-Hao; Lin, Chi-Hsiang; Huang, Hou-Tzu

    2015-06-01

    This Letter proposes a W-band OFDM RoF system at 103.5 GHz employing power detector to support vector signal down-conversion. Additional RF tone is generated and transmitted from central office to replace the local oscillator at a wireless receiver. With a proper frequency gap and power ratio between the RF tone and the OFDM-modulated signal, the impact from signal-to-signal beating interference can be minimized. The data rate can achieve a 40 Gbps 16 QAM OFDM signal over 25 km fiber and 2 m wireless transmission.

  18. Optimization of two-photon wave function in parametric down conversion by adaptive optics control of the pump radiation.

    PubMed

    Minozzi, M; Bonora, S; Sergienko, A V; Vallone, G; Villoresi, P

    2013-02-15

    We present an efficient method for optimizing the spatial profile of entangled-photon wave function produced in a spontaneous parametric down conversion process. A deformable mirror that modifies a wavefront of a 404 nm CW diode laser pump interacting with a nonlinear β-barium borate type-I crystal effectively controls the profile of the joint biphoton function. The use of a feedback signal extracted from the biphoton coincidence rate is used to achieve the optimal wavefront shape. The optimization of the two-photon coupling into two, single spatial modes for correlated detection is used for a practical demonstration of this physical principle.

  19. Title: Development of Single photon Quantum Optical Experiments using Type-I and Type-II Spontaneous Parametric Down Conversion

    NASA Astrophysics Data System (ADS)

    Laugharn, Andrew; Maleki, Seyfollah

    We constructed a quantum optical apparatus to control and detect single photons. We generated these photons via Type-I and Type-II spontaneous parametric down conversion by pumping a GaN laser (405nm) incident on a BBO crystal. We detected the two down converted photons (810nm), denoted signal and idler, in coincidence so as to measure and control single photons. We implemented a coincidence counting unite onto an Altera DE2 board and used LabView for data acquisition. We used these photon pairs to demonstrate quantum entanglement and indistinguishability using multiple optical experiments.

  20. Down-conversion photoluminescence sensitizing plasmonic silver nanoparticles on ZnO nanorods to generate hydrogen by water splitting photochemistry

    SciTech Connect

    Kung, Po-Yen; Huang, Li-Wen; Shen, Tin-Wei; Wang, Wen-Lin; Su, Yen-Hsun; Lin, Melody I.

    2015-01-12

    Silver nanoparticles fabricated onto the surface of the ZnO nanorods form the photoanode and generate photoelectric current due to surface plasmon resonance, which serves as anode electrodes in photoelectrochemical hydrogen production. In order to increase the absorption spectrum of photoanode, organic pigments were utilized as photo-sensitizers to generate down-conversion photoluminescence to excite surface plasmon resonances of silver nanoparticles. The way of using light to carry the energy in electronic scattering regime runs the system for the enhancement of solar water splitting efficiency. It was significantly tuned in environmentally sustainable applications for power generation and development of alternative energy.

  1. Role of volume and surface spontaneous parametric down-conversion in the generation of photon pairs in layered media

    NASA Astrophysics Data System (ADS)

    Javůrek, D.; Peřina, J.

    2017-04-01

    A rigorous description of volume and surface spontaneous parametric down-conversion in one-dimensional nonlinear layered structures is developed considering exact continuity relations for the fields' amplitudes at the boundaries. The nonlinear process is described by the quantum momentum operator that provides the Heisenberg equations whose solution is continuous at the boundaries. The transfer-matrix formalism is applied. The volume and surface contributions are clearly identified. Numerical analysis of a structure composed of 20 alternating GaN/AlN layers is given as an example.

  2. Development of a broadband cavity enhanced UV-LED spectrometer for the detection of atmospheric HONO and NO2

    NASA Astrophysics Data System (ADS)

    Wu, Tao; Xia, Ruxiao; Chen, Weidong; He, Xingdao

    2016-10-01

    An incoherent broadband cavity enhanced UV-LED spectrometer (IBBCEAS) was developed to detect atmospheric HONO and NO2. Using a UV light emitting diode (LED) operating at 366 nm in combination with a high finesse optical cavity, HONO and NO2 were able to be simultaneously measured with high sensitivity. Detection limits (for SNR=1) of 0.3 ppbv for HONO and 1 ppbv for NO2 were achieved with an optimum acquisition time of 120 s. Stability of the developed cavity enhanced UV-LED spectrometer has been characterized by means of an Allan variance analysis. Daytime and nighttime concentrations of atmospheric HONO and NO2 were measured and compared with data from LOPAP for HONO and blue light converter-based NOx analyzer for NO2. The present work performed in a real atmospheric environment demonstrates the feasibility of using IBBCEAS technique for interference (chemical and spectral) free measurement of HONO. Experimental detail will be presented, the problems encountered during the real atmospheric measurement will be discussed.

  3. Tm{sup 3+}-sensitized up- and down-conversions in nano-structured oxyfluoride glass ceramics

    SciTech Connect

    Lin, Hang; Marqués-Hueso, José; Chen, Daqin; Wang, Yuansheng; Richards, Bryce S.

    2012-12-15

    Graphical abstract: Display Omitted Highlights: ► UC and DC are achieved in a single-ion sensitized phosphor for PV applications. ► The most intense fractions of AM 1.5G spectrum below/above c-Si bandgap are absorbed. ► The converted photons match the optimal spectral response of c-Si. -- Abstract: Tm{sup 3+}-sensitized up-conversion and down-conversion are studied in transparent glass ceramics embedded with β-YF{sub 3} nanocrystals. Upon excitation at 1220 nm, where crystalline silicon (c-Si) solar cells no longer absorb, the sub-bandgap photons could be converted to the higher-energy ones via up-conversion. In addition, under excitation at 468 nm (a wavelength close to the peak in the air-mass 1.5 global solar spectrum), one blue photon might be split in up to two near-infrared ones via down-conversion. In both cases, the frequency-converted photons match the spectral response of c-Si solar cell well. Hopefully, the investigated luminescent materials may act as the spectral conversion layers to reduce the sub-bandgap transmission and charge carrier thermalization losses of c-Si solar cells, and in turn, enhance the energy efficiency.

  4. Efficiency enhancement in dye-sensitized solar cells with down conversion material ZnO: Eu3+, Dy3+

    NASA Astrophysics Data System (ADS)

    Yao, Nannan; Huang, Jinzhao; Fu, Ke; Liu, Shiyou; E, Dong; Wang, Yanhao; Xu, Xijin; Zhu, Min; Cao, Bingqiang

    2014-12-01

    The down conversion (DC) material ZnO: Eu3+, Dy3+ are synthesized by precipitation method and used to prepare the photo anode of dye-sensitized solar cells (DSSCs). The effects of down conversion material on the photoelectric performance of the DSSC were characterized by the X-ray diffraction (XRD), photoluminescence (PL), scanning electron microscope (SEM), current-voltage (I-V) curve, incident-photon-to-current conversion efficiency (IPCE) and UV-vis-NIR absorption spectroscopy. In this paper, Eu3+, Dy3+ codoped ZnO excited by from UV to blue light converts blue to red light emission, corresponding to the absorption region of the dye (N719). At the concentration 1.75% of ZnO: Eu3+, Dy3+ (weight ratio of DC to TiO2), the short-circuit current density and conversion efficiency of the DSSCs reached to the optimal values: 8.92 mA cm-2 and 4.48%, about 212% and 245% higher than with pure TiO2 and about 91.4% and 105% higher than with TiO2/graphene (G) structure, respectively. The research result reveals that the application of DC material can improve the efficiency of DSSCs.

  5. Cavity enhanced 1.5μm LED with silicon as a hole injector

    NASA Astrophysics Data System (ADS)

    Liu, Dong; Xia, Zhenyang; Cho, SangJune; Zhao, Deyin; Zhang, Huilong; Chang, Tzu-Hsuan; Yin, Xin; Kim, Munho; Seo, Jung-Hun; Lee, Jaeseong; Wang, Xudong; Zhou, Weidong; Ma, Zhenqiang

    2016-03-01

    Here we report the demonstration of a Si/InAlGaAs/InP PIN cavity enhanced LED around 1.5 um by using membrane transfer method. The silicon layer is acting not only as the optical guiding layer but also the hole injection layer. The new hybrid integrated LED could be further developed as laser source for silicon photonics.

  6. Cavity Enhanced Spectrometer performance assessment for greenhouse gas dry mole fraction measurement in humid air.

    NASA Astrophysics Data System (ADS)

    Laurent, Olivier; Yver Kwok, Camille; Guemri, Ali; Philippon, Carole; Rivier, Leonard; Ramonet, Michel

    2017-04-01

    Due to the high variability of the water vapor content in the atmosphere, the mole fraction of trace gas such as greenhouse gas (GHG) in the atmosphere is usually presented as mole fraction in dry air. In consequence, the first technology used for GHG measurement, gas chromatography or non-dispersive infra-red spectroscopy, required to dry the air sample prior to analysis at a dew point lower than -50°C. The emergence of new GHG analyzers using infrared Enhanced Cavity Spectroscopy which measure the water vapor content in the air sample, allows providing the dry mole fraction of GHG without any drying system upstream by applying appropriate correction of the water vapor effects (dilution, pressure broadening…). In the framework of ICOS, a European research infrastructure aiming to provide harmonized high precision data for advanced research on carbon cycle and GHG budgets over Europe, the Metrology Lab of the Atmosphere Thematic Centre (ATC), located at LSCE in France, is mainly dedicated to elaborating measurement protocols and evaluating performance of GHG analyzers. Among the different tests conducted to characterize the metrological performance, the Metrology Lab focuses on the water vapor correction to apply on the GHG measurement. Most of the analyzers tested at the Metrology Lab are based on Cavity Enhanced Spectroscopy measuring the ICOS mandatory species, CO2, CH4 and CO. This presentation presents the results of the performance assessment of the manufacturer built-in water vapor correction and the possible improvement. Thanks to the large number of instrument tested, the presentation provides a performance overview of the GHG analyzers deployed in the ICOS atmospheric station network. Finally the performance of the water vapor correction will be discussed in regard of the performance obtained by using a drying system.

  7. High-efficiency WSi superconducting nanowire single-photon detectors for quantum state engineering in the near infrared

    NASA Astrophysics Data System (ADS)

    Le Jeannic, Hanna; Verma, Varun B.; Cavaillès, Adrien; Marsili, Francesco; Shaw, Matthew D.; Huang, Kun; Morin, Olivier; Nam, Sae Woo; Laurat, Julien

    2016-11-01

    We report on high-efficiency superconducting nanowire single-photon detectors based on amorphous WSi and optimized at 1064 nm. At an operating temperature of 1.8 K, we demonstrated a 93% system detection efficiency at this wavelength with a dark noise of a few counts per second. Combined with cavity-enhanced spontaneous parametric down-conversion, this fiber-coupled detector enabled us to generate narrowband single photons with a heralding efficiency greater than 90% and a high spectral brightness of $0.6\\times10^4$ photons/(s$\\cdot$mW$\\cdot$MHz). Beyond single-photon generation at large rate, such high-efficiency detectors open the path to efficient multiple-photon heralding and complex quantum state engineering.

  8. Cavity-Enhanced Ultrafast Spectroscopy: Ultrafast Meets Ultrasensitive

    NASA Astrophysics Data System (ADS)

    Allison, Thomas K.; Reber, Melanie Roberts; Chen, Yuning

    2016-06-01

    Ultrafast optical spectroscopy methods, such as transient absorption spectroscopy and 2D-spectroscopy, are widely used across many disciplines. However, these techniques are typically restricted to optically thick samples, such as solids and liquid solutions. Using a frequency comb laser and optical cavities, we present a new technique for performing ultrafast optical spectroscopy with high sensitivity, enabling work in dilute gas-phase molecular beams. Resonantly enhancing the probe pulses, we demonstrate transient absorption measurements with a detection limit of ΔOD = 2 × 10-10 (1 × 10-9/√{Hz}). Resonantly enhancing the pump pulses allows us to produce a high excitation fraction at high repetition-rate, so that signals can be recorded from samples with optical densities as low as OD ≈ 10-8, or column densities < 1010 molecules/cm^2. To our knowledge, this represents a 5,000-fold improvement of the state-of-the-art. oise performance of CE-TAS. (a), Transient absorption measurements taken with reduced gas flow and perpendicular polarizations. The red dots represent the average of 60 consecutive scans taken over a 1 hour period. Black curves are every 10th scan from the data set. Inset: Zoom-in around 0.8 ps delay. Error bars represent the uncertainty in the mean. (b), The green squares show the average of the Allan deviations obtained independently for each delay point. Error bars here are the standard deviation (not the uncertainty in the mean) of this ensemble, to represent the spread in the data. The blue diamond is the average of the error bars of (a), along with their standard deviation. The grey line has a slope of -1/2 on the log-log plot, the expected slope for white noise performance

  9. Development of a cavity enhanced absorption spectrometer for airborne measurements of CH4 and CO2

    NASA Astrophysics Data System (ADS)

    O'Shea, S. J.; Bauguitte, S. J.-B.; Gallagher, M. W.; Lowry, D.; Percival, C. J.

    2013-01-01

    High-resolution CH4 and CO2 measurements were made onboard the FAAM BAe 146 UK atmospheric research aircraft during a number of field campaigns. The system was based on an infrared spectrometer using the cavity enhanced absorption spectroscopy technique. Correction functions to convert the mole fractions retrieved from the spectroscopy to dry air mole fractions were derived using laboratory experiments and over a 3 month period showed good stability. Long-term performance of the system was monitored using WMO traceable calibration gases. During the first year of operation (29 flights) analysis of the system's in-flight calibrations suggest that its measurements are accurate to -0.07 ppbv (1 σ precision at 1 Hz = 2.48 ppbv) for CH4 and -0.06 ppmv (1 σ precision at 1 Hz = 0.66 ppmv) for CO2. The system was found to be very robust, no major motion or altitude dependency could be detected in the measurements. An inter-comparison between whole air samples that were analysed post-flight for CH4 and CO2 by cavity ring down spectroscopy showed a mean difference between the two techniques of -2.4 ppbv (1 σ = 2.3 ppbv) for CH4 and -0.22 ppmv (1 σ = 0.45 ppmv) for CO2. In September 2012, the system was used to sample biomass burning plumes in Brazil as part of the SAMBBA project (South American biomass burning analysis). From these and simultaneous CO measurements, emission factors for savannah fires were calculated. These were found to be 2.2 ± 0.2 g (kg dry matter)-1 for CH4 and 1710 ± 171 g (kg dry matter)-1 for CO2, which are in excellent agreement with previous estimates in the literature.

  10. Cavity-Enhanced Room-Temperature Broadband Raman Memory

    NASA Astrophysics Data System (ADS)

    Saunders, D. J.; Munns, J. H. D.; Champion, T. F. M.; Qiu, C.; Kaczmarek, K. T.; Poem, E.; Ledingham, P. M.; Walmsley, I. A.; Nunn, J.

    2016-03-01

    Broadband quantum memories hold great promise as multiplexing elements in future photonic quantum information protocols. Alkali-vapor Raman memories combine high-bandwidth storage, on-demand readout, and operation at room temperature without collisional fluorescence noise. However, previous implementations have required large control pulse energies and have suffered from four-wave-mixing noise. Here, we present a Raman memory where the storage interaction is enhanced by a low-finesse birefringent cavity tuned into simultaneous resonance with the signal and control fields, dramatically reducing the energy required to drive the memory. By engineering antiresonance for the anti-Stokes field, we also suppress the four-wave-mixing noise and report the lowest unconditional noise floor yet achieved in a Raman-type warm vapor memory, (15 ±2 )×10-3 photons per pulse, with a total efficiency of (9.5 ±0.5 )%.

  11. Fluorescent MoS2 Quantum Dots: Ultrasonic Preparation, Up-Conversion and Down-Conversion Bioimaging, and Photodynamic Therapy.

    PubMed

    Dong, Haifeng; Tang, Songsong; Hao, Yansong; Yu, Haizhu; Dai, Wenhao; Zhao, Guifeng; Cao, Yu; Lu, Huiting; Zhang, Xueji; Ju, Huangxian

    2016-02-10

    Small size molybdenum disulfide (MoS2) quantum dots (QDs) with desired optical properties were controllably synthesized by using tetrabutylammonium-assisted ultrasonication of multilayered MoS2 powder via OH-mediated chain-like Mo-S bond cleavage mode. The tunable up-bottom approach of precise fabrication of MoS2 QDs finally enables detailed experimental investigations of their optical properties. The synthesized MoS2 QDs present good down-conversion photoluminescence behaviors and exhibit remarkable up-conversion photoluminescence for bioimaging. The mechanism of the emerging photoluminescence was investigated. Furthermore, superior (1)O2 production ability of MoS2 QDs to commercial photosensitizer PpIX was demonstrated, which has great potential application for photodynamic therapy. These early affording results of tunable synthesis of MoS2 QDs with desired photo properties can lead to application in fields of biomedical and optoelectronics.

  12. Heralded quantum repeater based on the scattering of photons off single emitters using parametric down-conversion source

    PubMed Central

    Song, Guo-Zhu; Wu, Fang-Zhou; Zhang, Mei; Yang, Guo-Jian

    2016-01-01

    Quantum repeater is the key element in quantum communication and quantum information processing. Here, we investigate the possibility of achieving a heralded quantum repeater based on the scattering of photons off single emitters in one-dimensional waveguides. We design the compact quantum circuits for nonlocal entanglement generation, entanglement swapping, and entanglement purification, and discuss the feasibility of our protocols with current experimental technology. In our scheme, we use a parametric down-conversion source instead of ideal single-photon sources to realize the heralded quantum repeater. Moreover, our protocols can turn faulty events into the detection of photon polarization, and the fidelity can reach 100% in principle. Our scheme is attractive and scalable, since it can be realized with artificial solid-state quantum systems. With developed experimental technique on controlling emitter-waveguide systems, the repeater may be very useful in long-distance quantum communication. PMID:27350159

  13. Spontaneous parametric down conversion with a depleted pump as an analogue for black hole evaporation/particle production

    NASA Astrophysics Data System (ADS)

    Alsing, P. M.; Fanto, M. L.

    2016-05-01

    In this work we argue that black hole evaporation/particle production has a very close analogy to the laboratory process of spontaneous parametric down conversion, when the pump is allowed to deplete. We present an analytical formulation of the recent one-shot decoupling model that was numerically analyzed in Bradler and Adami Phys. Rev. Lett. 116, 101301 (2016) [arXiv:1505.0284]. We compute the resulting "Page Information" curves, which describe the rate at which information escapes form the black hole as it evaporates, for the reduced density matrices for the evaporating black hole internal degrees of freedom, and emitted Hawking radiation pairs entangled across the horizon. The present work reviews and attempts to elucidate the trilinear Hamiltonian models for black hole evaporation/particle production recently investigated by the authors in Class. Quant. Grav 32, 075010 (2015) [arXiv:1408.4491] and Class. Quant. Grav 33, 015005 (2016) [arXiv:1507.00429].

  14. Telecom-band two-photon Michelson interferometer using frequency entangled photon pairs generated by spontaneous parametric down-conversion

    NASA Astrophysics Data System (ADS)

    Yoshizawa, Akio; Fukuda, Daiji; Tsuchida, Hidemi

    2014-02-01

    We demonstrate a telecom-band fiber-optic two-photon Michelson interferometer using near-degenerate and collinear photon pairs with frequency entanglement. For spontaneous parametric down-conversion (SPDC), a continuous-wave laser diode pumps a periodically poled lithium niobate waveguide. Two threshold single-photon detectors record coincidence counts to observe two-photon interference and evaluate the correlation function. Multi-pair emission events are inevitable in SPDC and photon pairs without frequency entanglement are unintentionally registered as coincidence counts. In the demonstrated experiment, a mixture of photon pairs with and without frequency entanglement is present. The effects of such a mixed state on the correlation function are experimentally investigated. Two-photon interference of photon pairs without frequency entanglement is also measured for comparison.

  15. Third-order spontaneous parametric down-conversion in thin optical fibers as a photon-triplet source

    SciTech Connect

    Corona, Maria; Garay-Palmett, Karina; U'Ren, Alfred B.

    2011-09-15

    We study the third-order spontaneous parametric down-conversion (TOSPDC) process, as a means to generate entangled photon triplets. Specifically, we consider thin optical fibers as the nonlinear medium to be used as the basis for TOSPDC in configurations where phase matching is attained through the use of more than one fiber transverse modes. Our analysis in this paper, which follows from our earlier paper [Opt. Lett. 36, 190-192 (2011)], aims to supply experimentalists with the details required in order to design a TOSPDC photon-triplet source. Specifically, our analysis focuses on the photon triplet state, on the rate of emission, and on the TOSPDC phase-matching characteristics for the cases of frequency-degenerate and frequency nondegenerate TOSPDC.

  16. Effects of polarization mode dispersion on polarization-entangled photons generated via broadband pumped spontaneous parametric down-conversion

    NASA Astrophysics Data System (ADS)

    Lim, Hyang-Tag; Hong, Kang-Hee; Kim, Yoon-Ho

    2016-05-01

    An inexpensive and compact frequency multi-mode diode laser enables a compact two-photon polarization entanglement source via the continuous wave broadband pumped spontaneous parametric down-conversion (SPDC) process. Entanglement degradation caused by polarization mode dispersion (PMD) is one of the critical issues in optical fiber-based polarization entanglement distribution. We theoretically and experimentally investigate how the initial entanglement is degraded when the two-photon polarization entangled state undergoes PMD. We report an effect of PMD unique to broadband pumped SPDC, equally applicable to pulsed pumping as well as cw broadband pumping, which is that the amount of the entanglement degradation is asymmetrical to the PMD introduced to each quantum channel. We believe that our results have important applications in long-distance distribution of polarization entanglement via optical fiber channels.

  17. Angular and temperature dependence of photon pair rates in spontaneous parametric down-conversion from a periodically poled crystal

    NASA Astrophysics Data System (ADS)

    Jimenez, G. Daniel; Garces, Veneranda G.; O'Donnell, Kevin A.

    2017-08-01

    We present a theoretical and experimental study of the angular and temperature dependence of the photon pairs produced by spontaneous parametric down-conversion in a periodically poled KTP crystal. In the experiment, two detectors are placed at different angles in the emitted light, and the detected photon pair rate is measured as a function of one angle or of crystal temperature. In the theoretical work, exact results for the pair rates are obtained through importance-sampled numerical integration of the fourth-order coherence function over regions representing the experimental integration parameters. Conditions studied range from well-resolved results in which detector angular and filter bandwidth integration effects are negligible, to other cases in which such effects are large and pair rates exceed 105s-1 . Throughout these cases, good agreement is often seen between experimental and theoretical results, while some differences that are noted provide insight into the actual crystal quasi-phase-matching function.

  18. A broadband cavity enhanced absorption spectrometer for aircraft measurements of glyoxal, methylglyoxal, nitrous acid, nitrogen dioxide, and water vapor

    NASA Astrophysics Data System (ADS)

    Min, K.-E.; Washenfelder, R. A.; Dubé, W. P.; Langford, A. O.; Edwards, P. M.; Zarzana, K. J.; Stutz, J.; Lu, K.; Rohrer, F.; Zhang, Y.; Brown, S. S.

    2016-02-01

    We describe a two-channel broadband cavity enhanced absorption spectrometer (BBCEAS) for aircraft measurements of glyoxal (CHOCHO), methylglyoxal (CH3COCHO), nitrous acid (HONO), nitrogen dioxide (NO2), and water (H2O). The instrument spans 361-389 and 438-468 nm, using two light-emitting diodes (LEDs) and a single grating spectrometer with a charge-coupled device (CCD) detector. Robust performance is achieved using a custom optical mounting system, high-power LEDs with electronic on/off modulation, high-reflectivity cavity mirrors, and materials that minimize analyte surface losses. We have successfully deployed this instrument during two aircraft and two ground-based field campaigns to date. The demonstrated precision (2σ) for retrievals of CHOCHO, HONO and NO2 are 34, 350, and 80 parts per trillion (pptv) in 5 s. The accuracy is 5.8, 9.0, and 5.0 %, limited mainly by the available absorption cross sections.

  19. Broadband cavity-enhanced absorption spectroscopy in the ultraviolet spectral region for measurements of nitrogen dioxide and formaldehyde

    NASA Astrophysics Data System (ADS)

    Washenfelder, R. A.; Attwood, A. R.; Flores, J. M.; Zarzana, K. J.; Rudich, Y.; Brown, S. S.

    2016-01-01

    Formaldehyde (CH2O) is the most abundant aldehyde in the atmosphere, and it strongly affects photochemistry through its photolysis. We describe simultaneous measurements of CH2O and nitrogen dioxide (NO2) using broadband cavity-enhanced absorption spectroscopy in the ultraviolet spectral region. The light source consists of a continuous-wave diode laser focused into a Xenon bulb to produce a plasma that emits high-intensity, broadband light. The plasma discharge is optically filtered and coupled into a 1 m optical cavity. The reflectivity of the cavity mirrors is 0.99930 ± 0.00003 (1- reflectivity = 700 ppm loss) at 338 nm, as determined from the known Rayleigh scattering of He and zero air. This mirror reflectivity corresponds to an effective path length of 1.43 km within the 1 m cell. We measure the cavity output over the 315-350 nm spectral region using a grating monochromator and charge-coupled device array detector. We use published reference spectra with spectral fitting software to simultaneously retrieve CH2O and NO2 concentrations. Independent measurements of NO2 standard additions by broadband cavity-enhanced absorption spectroscopy and cavity ring-down spectroscopy agree within 2 % (slope for linear fit = 1.02 ± 0.03 with r2 = 0.998). Standard additions of CH2O measured by broadband cavity-enhanced absorption spectroscopy and calculated based on flow dilution are also well correlated, with r2 = 0.9998. During constant mixed additions of NO2 and CH2O, the 30 s measurement precisions (1σ) of the current configuration were 140 and 210 pptv, respectively. The current 1 min detection limit for extinction measurements at 315-350 nm provides sufficient sensitivity for measurement of trace gases in laboratory experiments and ground-based field experiments. Additionally, the instrument provides highly accurate, spectroscopically based trace gas detection that may complement higher precision techniques based on non

  20. The time-dependent emission of molecular iodine from Laminaria Digitata measured with incoherent broadband cavity-enhanced absorption spectroscopy

    NASA Astrophysics Data System (ADS)

    Dixneuf, S.

    2009-04-01

    The release of molecular iodine (I2) from the oceans into the atmosphere has been recognized to correlate strongly with ozone depletion events and aerosol formation in the Marine Boundary Layer (MBL), which affects in turn global radiative forcing. The detailed mechanisms and dominant sources leading to the observed concentrations of I2 in the marine troposphere are still under intense investigation. In a recent campaign on the Irish west coast at Mace Head Atmospheric Research Station [1], it was found that significant levels of molecular iodine correlated with times of low tide, suggesting that the emission of air-exposed macro-algae may be a prime source of molecular iodine in coastal areas [2]. To further investigate this hypothesis we tried to detect the I2 emission of the brown seaweed Laminaria digitata, one of the most efficient iodine accumulators among living systems, directly by means of highly sensitive incoherent broadband cavity-enhanced absorption spectroscopy (IBBCEAS) [3]. IBBCEAS combines a good temporal and spatial resolution with high molecule-specific detection limits [4] comparable to that of typical LP-DOAS. IBBCEAS thus complements LP-DOAS in the search for sources of tropospheric trace gases. In this presentation the first direct observation of the time dependence of molecular iodine emission from Laminaria digitata will be shown. Plants were studied under naturally occurring stress for quasi in situ conditions for many hours. Surprisingly, the release of I2 occurs in short, strong bursts with quasi-oscillatory behaviour, bearing similarities to well known "iodine clock reactions". References [1] Saiz-Lopez A. & Plane, J. M. C. Novel iodine chemistry in the marine boundary layer. Geophys. Res. Lett. 31, L04112 (2004) doi:10.1029/2003GL019215. [2] McFiggans, G., Coe, H., Burgess, R., Allan, J., Cubison, M., Alfarra, M. R., Saunders, R., Saiz-Lopez, A., Plane, J. M. C., Wevill, D. J., Carpenter, L. J., Rickard, A. R. & Monks, P. S. Direct

  1. Detection of nitrogen dioxide by CW cavity-enhanced spectroscopy

    NASA Astrophysics Data System (ADS)

    Jie, Guo; Han, Ye-Xing; Yu, Zhi-Wei; Tang, Huai-Wu

    2016-11-01

    In the paper, an accurate and sensitive system was used to monitor the ambient atmospheric NO2 concentrations. This system utilizes cavity attenuated phase shift spectroscopy(CAPS), a technology related to cavity ring down spectroscopy(CRDS). Advantages of the CAPS system include such as: (1) cheap and easy to control the light source, (2) high accuracy, and (3) low detection limit. The performance of the CAPS system was evaluated by measuring of the stability and response of the system. The minima ( 0.08 ppb NO2) in the Allan plots show the optimum average time( 100s) for optimum detection performance of the CAPS system. Over a 20-day-long period of the ambient atmospheric NO2 concentrations monitoring, a comparison of the CAPS system with an extremely accurate and precise chemiluminescence-based NOx analyzer showed that the CAPS system was able to reliably and quantitatively measure both large and small fluctuations in the ambient nitrogen dioxide concentration. The experimental results show that the measuring instrument results correlation is 0.95.

  2. Time-bin entangled photon pairs from spontaneous parametric down-conversion pumped by a cw multi-mode diode laser.

    PubMed

    Kwon, Osung; Park, Kwang-Kyoon; Ra, Young-Sik; Kim, Yong-Su; Kim, Yoon-Ho

    2013-10-21

    Generation of time-bin entangled photon pairs requires the use of the Franson interferometer which consists of two spatially separated unbalanced Mach-Zehnder interferometers through which the signal and idler photons from spontaneous parametric down-conversion (SPDC) are made to transmit individually. There have been two SPDC pumping regimes where the scheme works: the narrowband regime and the double-pulse regime. In the narrowband regime, the SPDC process is pumped by a narrowband cw laser with the coherence length much longer than the path length difference of the Franson interferometer. In the double-pulse regime, the longitudinal separation between the pulse pair is made equal to the path length difference of the Franson interferometer. In this paper, we propose another regime by which the generation of time-bin entanglement is possible and demonstrate the scheme experimentally. In our scheme, differently from the previous approaches, the SPDC process is pumped by a cw multi-mode (i.e., short coherence length) laser and makes use of the coherence revival property of such a laser. The high-visibility two-photon Franson interference demonstrates clearly that high-quality time-bin entanglement source can be developed using inexpensive cw multi-mode diode lasers for various quantum communication applications.

  3. Complementary cavity-enhanced spectrometers to investigate the OH + CH combination band in trans-formic acid.

    PubMed

    Golebiowski, D; Földes, T; Vanfleteren, T; Herman, M; Perrin, A

    2015-07-07

    We have used continuous-wave cavity ring-down and femto-Fourier transform-cavity-enhanced absorption spectrometers to record the spectrum of the OH-stretching + CH-stretching (ν1 + ν2) combination band in trans-formic acid, with origin close to 6507 cm(-1). They, respectively, allowed resolving and simplifying the rotational structure of the band near its origin under jet-cooled conditions (Trot = 10 K) and highlighting the overview of the band under room temperature conditions. The stronger B-type and weaker A-type subbands close to the band origin could be assigned, as well as the main B-type Q branches. The high-resolution analysis was hindered by numerous, severe perturbations. Rotational constants are reported with, however, limited physical meaning. The ν1 + ν2 transition moment is estimated from relative intensities to be 24° away from the principal b-axis of inertia.

  4. A broadband cavity enhanced absorption spectrometer for aircraft measurements of glyoxal, methylglyoxal, nitrous acid, nitrogen dioxide, and water vapor

    NASA Astrophysics Data System (ADS)

    Min, K.-E.; Washenfelder, R. A.; Dubé, W. P.; Langford, A. O.; Edwards, P. M.; Zarzana, K. J.; Stutz, J.; Lu, K.; Rohrer, F.; Zhang, Y.; Brown, S. S.

    2015-10-01

    We describe a two-channel broadband cavity enhanced absorption spectrometer (BBCEAS) for aircraft measurements of glyoxal (CHOCHO), methylglyoxal (CH3COCHO), nitrous acid (HONO), nitrogen dioxide (NO2), and water (H2O). The instrument spans 361-389 and 438-468 nm, using two light emitting diodes (LEDs) and a grating spectrometer with a charge-coupled device (CCD) detector. Robust performance is achieved using a custom optical mounting system, high power LEDs with electronic on/off modulation, state-of-the-art cavity mirrors, and materials that minimize analyte surface losses. We have successfully deployed this instrument during two aircraft and two ground-based field campaigns to date. The demonstrated precision (2σ) for retrievals of CHOCHO, HONO and NO2 are 34, 350 and 80 pptv in 5 s. The accuracy is 5.8, 9.0 and 5.0 % limited mainly by the available absorption cross sections.

  5. Spectral properties of three-photon entangled states generated via three-photon parametric down-conversion in a {chi}{sup (3)} medium

    SciTech Connect

    Chekhova, M.V.; Ivanova, O.A.; Berardi, V.; Garuccio, A.

    2005-08-15

    We consider the quantum state of light produced via direct parametric decay of pump photons into photon triples in a medium with cubic nonlinearity. For this state generated in the near-collinear frequency-degenerate regime, the third- and second-order Glauber's correlation functions are calculated and the intensity distribution over frequency and wave vector is found. It is shown that the number of photons generated into a single mode via the three-photon down-conversion is proportional to the width of the frequency-angular intensity distribution for the corresponding two-photon phase matching (spontaneous parametric down-conversion). The intensity of three-photon parametric down-conversion is shown to have an extremely broad frequency spectrum, even for a fixed angle of scattering.

  6. Design and simulation of resonant cavity enhanced corrugated quantum well infrared photodetectors.

    PubMed

    Kim, Jang Pyo; Sarangan, Andrew M

    2006-08-20

    The dipole selection rule limits the maximum achievable efficiency in corrugated quantum well infrared photodetectors (C-QWIPs) to 50%. We consider what is believed to be a novel design that utilizes a resonant cavity enhancement technique to increase the efficiency beyond 50% by rotating the photon polarization at each pass around the cavity. Simulation results show that the quantum efficiency of this device can be enhanced up to 38% compared to that of the standard C-QWIP device.

  7. Laser frequency down-conversion by means of a monochromatically driven two-level system

    NASA Astrophysics Data System (ADS)

    Soldatov, Andrey V.

    2016-09-01

    Conditions are found under which a simple two-level quantum system possessing dipole moment operator with permanent non-equal diagonal matrix elements and driven by external semiclassical monochromatic high-frequency EM (laser) field can radiate continuously at much lower frequency. Possible ways to experimental observation and practical implementation of the predicted effect for a wide range of applications are discussed.

  8. Optical and structural properties of down-conversion Bi doped Y2O3 films for potential application in solar cell

    NASA Astrophysics Data System (ADS)

    Meng, Lijian; Xu, Wei; Zhang, Qingyu

    2017-07-01

    The highly efficient antireflective down-conversion Bi-doped Y2O3 films have been deposited on the (100) oriented Si and quartz substrates by rf reactive magnetron sputtering using a metallic target. The effects of the Bi doping concentration on the optical and structural properties of the films were studied. The Bi/Y ratio in the films varied from 0.002 to 0.02. The undoped Y2O3 films show a cubic phase crystal structure with a preferred orientation along the (222) direction. Bi doping results in the appearance of the (111) oriented monoclinic phase crystal structure. The refractive index is increased and the optical band gap is decreased as the Bi concentration in the films is increased. The bright green photoluminescence of Bi ions was observed under ultraviolet light excitation for all the Bi-doped Y2O3 films and the luminescence intensity increases as the Bi/Y ratio is increased from 0.002 to 0.02. In addition, Bi-doped Y2O3 films show a much lower optical reflectance than the undoped Y2O3 films. These results make the Bi-doped Y2O3 films a potential application not only as a spectrum converting layer but also as an antireflective layer in crystalline Si solar cells.

  9. Design of diamond microcavities for single photon frequency down-conversion.

    PubMed

    Lin, Z; Johnson, S G; Rodriguez, A W; Loncar, M

    2015-09-21

    We propose monolithic diamond cavities that can be used to convert color-center Fock-state single photons from emission wavelengths to telecommunication bands. We present a detailed theoretical description of the conversion process, analyzing important practical concerns such as nonlinear phase shifts and frequency mismatch. Our analysis predicts sustainable power requirements (≲ 1 W) for a chipscale nonlinear device with high conversion efficiencies.

  10. Enhancing the Photovoltaic Performance of Perovskite Solar Cells with a Down-Conversion Eu-Complex.

    PubMed

    Jiang, Ling; Chen, Wangchao; Zheng, Jiawei; Zhu, Liangzheng; Mo, Li'e; Li, Zhaoqian; Hu, Linhua; Hayat, Tasawar; Alsaedi, Ahmed; Zhang, Changneng; Dai, Songyuan

    2017-08-16

    Organometal halide perovskite solar cells (PSCs) have shown high photovoltaic performance but poor utilization of ultraviolet (UV) irradiation. Lanthanide complexes have a wide absorption range in the UV region and they can down-convert the absorbed UV light into visible light, which provides a possibility for PSCs to utilize UV light for higher photocurrent, efficiency, and stability. In this study, we use a transparent luminescent down-converting layer (LDL) of Eu-4,7-diphenyl-1,10-phenanthroline (Eu-complex) to improve the light utilization efficiency of PSCs. Compared with the uncoated PSC, the PSC coated with Eu-complex LDL on the reverse of the fluorine-doped tin oxide glass displayed an enhancement of 11.8% in short-circuit current density (Jsc) and 15.3% in efficiency due to the Eu-complex LDL re-emitting UV light (300-380 nm) in the visible range. It is indicated that the Eu-complex LDL plays the role of enhancing the power conversion efficiency as well as reducing UV degradation for PSCs.

  11. Effect of annealing on down-conversion properties of monoclinic Gd2O3:Er3+ nanophosphors.

    PubMed

    Tamrakar, Raunak Kumar; Bisen, D P; Upadhyay, Kanchan

    2015-09-01

    Erbium-doped nano-sized Gd2O3 phosphor was prepared by a solution combustion method in the presence of urea as a fuel. The phosphor was characterized by X-ray diffractometry (XRD), Fourier transform infra-red spectroscopy, energy dispersive X-ray analysis (EDX) and transmission electron microscopy (TEM). The results of the XRD shows that the phosphor has a monoclinic phase, which was further confirmed by the TEM results. Particle size was calculated by the Debye-Scherrer formula. The erbium-doped Gd2O3 nanophosphor was revealed to have good down-conversion (DC) properties and the intensity of phosphor could be modified by annealing. The effects of annealing at 900°C on the particle size and luminescence properties were studied and compared with freshly prepared Gd2O3:Er(3+) nanoparticles. The average particle sizes were calculated as 8 and 20 nm for the freshly prepared samples and samples annealed at 900°C for 1 h, respectively. The results show that both freshly prepared and annealed Gd2O3:Er(3+) have monoclinic structure. Copyright © 2014 John Wiley & Sons, Ltd.

  12. Ultrasensitive detection of waste products in water using fluorescence emission cavity-enhanced spectroscopy.

    PubMed

    Bixler, Joel N; Cone, Michael T; Hokr, Brett H; Mason, John D; Figueroa, Eleonora; Fry, Edward S; Yakovlev, Vladislav V; Scully, Marlan O

    2014-05-20

    Clean water is paramount to human health. In this article, we present a technique for detection of trace amounts of human or animal waste products in water using fluorescence emission cavity-enhanced spectroscopy. The detection of femtomolar concentrations of urobilin, a metabolic byproduct of heme metabolism that is excreted in both human and animal waste in water, was achieved through the use of an integrating cavity. This technique could allow for real-time assessment of water quality without the need for expensive laboratory equipment.

  13. Studies of cavity enhanced absorption spectroscopy for weak absorption gas measurements

    NASA Astrophysics Data System (ADS)

    Li, Liucheng; Duo, Liping; Gong, Deyu; Ma, Yanhua; Zhang, Zhiguo; Wang, Yuanhu; Zhou, Dongjian; Jin, Yuqi

    2017-01-01

    In order to determine the concentrations of trace amount metastable species in chemical lasers, an off-axis cavity enhanced absorption spectrometer for the detection of weak absorption gases has been built with a noise equivalent absorption sensitivity of 1.6x10-8 cm-1. The absorption spectrum of trace amount gaseous ammonia and water vapor was obtained with a spectral resolution of about 78 MHz. A multiple-line absorption spectroscopic method to determine the temperature of gaseous ammonia has been developed by use of multiple lines of ammonia molecule absorption spectrum.

  14. Parametric down conversion with a depleted pump as a model for classical information transmission capacity of quantum black holes

    NASA Astrophysics Data System (ADS)

    Alsing, Paul M.

    2015-04-01

    In this paper we extend the investigation of Adami and Ver Steeg (2014 Class. Quantum Grav. 31 075015) to treat the process of black hole (BH) particle emission effectively as the analogous quantum optical process of parametric down conversion with a dynamical (depleted versus non-depleted) ‘pump’ source mode which models the evaporating BH energy degree of freedom. We investigate both the short time (non-depleted pump) and long time (depleted pump) regimes of the quantum state and its impact on the Holevo channel capacity for commu.nicating information from the far past to the far future in the presence of Hawking radiation. The new feature introduced in this work is the coupling of the emitted Hawking radiation modes through the common BH ‘source pump’ mode which phenomenologically represents a quantized energy degree of freedom of the gravitational field. This (zero-dimensional) model serves as a simplified arena to explore BH particle production/evaporation and back-action effects under an explicitly unitary evolution that enforces quantized energy/particle conservation. Within our analogous quantum optical model we examine the entanglement between two emitted particle/anti-particle and anti-particle/particle pairs coupled via the BH evaporating ‘pump’ source. We also analytically and dynamically verify the ‘Page information time’ for our model, which refers to the conventionally held belief that the information in the BH radiation becomes significant after the BH has evaporated half its initial energy into the outgoing radiation. Lastly, we investigate the effect of BH particle production/evaporation on two modes in the exterior region of the BH event horizon that are initially maximally entangled, when one mode falls inward and interacts with the BH, and the other remains forever outside and non-interacting.

  15. Line-Parameter Measurements and Stringent Tests of Line-Shape Models Based on Cavity-Enhanced Absorption Spectroscopy

    NASA Astrophysics Data System (ADS)

    Bielska, Katarzyna; Fleisher, Adam J.; Hodges, Joseph T.; Lin, Hong; Long, David A.; Reed, Zachary D.; Sironneau, Vincent; Truong, Gar-Wing; Wójtewicz, Szymon

    2014-06-01

    Laser methods that are based on cavity-enhanced absorption spectroscopy (CEAS) are well-suited for measuring molecular line parameters under conditions of low optical density, and as such they are complementary to broadband Fourier-transform spectroscopy (FTS) techniques. Attributes of CEAS include relatively low detection limits, accurate and precise detuning axes and high fidelity measurements of line shape. In many cases these performance criteria are superior to those obtained using direct laser absorption spectroscopy and FTS-based systems. In this presentation we will survey several examples of frequency-stabilized cavity ring-down spectroscopy (FS-CRDS)1 measurements obtained with laser spectrometers developed at the National Institute of Standards and Technology (NIST) in Gaithersburg Maryland. These experiments, which are motivated by atmospheric monitoring and remote-sensing applications that require high-precision and accuracy, involve nearinfrared transitions of carbon dioxide, water, oxygen and methane. We discuss spectra with signal-to-noise ratios exceeding 106, frequency axes with absolute uncertainties in the 10 kHz to 100 kHz range and linked to a Cs clock, line parameters with relative uncertainties at the 0.2 % level and isotopic ratios measured with a precision of 0.03 %. We also present FS-CRDS measurements of CO2 line intensities which are measured at atmospheric concentration levels and linked to gravimetric standards for CO2 in air, and we quantify pressure-dependent deviations between various theoretical line profiles and measured line shapes. Finally we also present recent efforts to increase data throughput and spectral coverage in CEAS experiments. We describe three new high-bandwidth CEAS techniques including frequency-agile, rapid scanning spectroscopy (FARS)2, which enables continuous-wave measurements of cavity mode linewidth and acquisition of ringdown decays with no dead time during laser frequency tuning, heterodyne

  16. Cavity-Enhanced Raman Spectroscopy of Natural Gas with Optical Feedback cw-Diode Lasers.

    PubMed

    Hippler, Michael

    2015-08-04

    We report on improvements made on our previously introduced technique of cavity-enhanced Raman spectroscopy (CERS) with optical feedback cw-diode lasers in the gas phase, including a new mode-matching procedure which keeps the laser in resonance with the optical cavity without inducing long-term frequency shifts of the laser, and using a new CCD camera with improved noise performance. With 10 mW of 636.2 nm diode laser excitation and 30 s integration time, cavity enhancement achieves noise-equivalent detection limits below 1 mbar at 1 bar total pressure, depending on Raman cross sections. Detection limits can be easily improved using higher power diodes. We further demonstrate a relevant analytical application of CERS, the multicomponent analysis of natural gas samples. Several spectroscopic features have been identified and characterized. CERS with low power diode lasers is suitable for online monitoring of natural gas mixtures with sensitivity and spectroscopic selectivity, including monitoring H2, H2S, N2, CO2, and alkanes.

  17. NO2 trace measurements by optical-feedback cavity-enhanced absorption spectroscopy

    NASA Astrophysics Data System (ADS)

    Ventrillard-Courtillot, I.; Foldes, T.; Romanini, D.

    2009-04-01

    In order to reach the sub-ppb NO2 detection level required for environmental applications in remote areas, we are developing a spectrometer that exploits a technique that we introduced several years ago, named Optical-Feedback Cavity-Enhanced Absorption Spectroscopy (OF-CEAS) [1]. It allows very sensitive and selective measurements, together with the realization of compact and robust set-ups as was subsequently demonstrated during measurements campaigns in harsh environments [2,3]. OF-CEAS benefits from the optical feedback (OF) to efficiently inject a cw-laser in a high finesse cavity (typically F >10 000). Absorption spectra are acquired on a small spectral region (~1 cm-1) that enables selective and quantitative measurements at a fast acquisition rate (~10 Hz) with a detection limit of several 10-10 cm-1 as reported in this paper. Spectra are obtained with high spectral resolution (~150 MHz) and are self calibrated by cavity rind-down measurements regularly performed (typically every second). Therefore, OF-CEAS appears very attractive for NO2 trace detection. This work is performed in the blue spectral region where NO2 has intense electronic transitions. Our setup involves a commercial extended cavity diode laser (ECDL) working at room temperature around 411nm. A first setup was developed [4] to demonstrate that OF sensitivity of ECDL is fully consistent with this technique, initially introduced with distributed feedback diode lasers in the near infrared region. In this paper we will report on a new set-up developed for in-situ measurements with proper mechanical, acoustic and thermal insulation. Additionally, new data processing was implemented allowing real time concentration measurements. It is based on a reference spectra recorded under controlled conditions by OF-CEAS and used later to fit the observed spectra. We will present measurements performed with calibrated NO2 reference samples demonstrating a good linearity of the apparatus. The minimum detectable

  18. Laser-induced down-conversion and infrared phosphorescence emissivity of novel ligand-free perovskite nanomaterials

    NASA Astrophysics Data System (ADS)

    Ahmed, M. A.; Khafagy, Rasha M.; El-sayed, O.

    2014-03-01

    For the first time, standalone and ligand-free series of novel rare-earth-based perovskite nanomaterials are used as near infrared (NIR) and mid infrared (MIR) emitters. Nano-sized La0.7Sr0.3M0.1Fe0.9O3; where M = 0, Mn2+, Co2+ or Ni2+ were synthesized using the flash auto-combustion method and characterized using FTIR, FT-Raman, SEM and EDX. Photoluminescence spectra were spontaneously recorded during pumping the samples with 0.5 mW of green laser emitting continuously at 532 nm. La0.7Sr0.3FeO3 (where M = 0) did not result in any infrared emissivity, while intense near and mid infrared down-converted phosphorescence was released from the M-doped samples. The released phosphorescence greatly shifted among the infrared spectral region with changing the doping cation. Ni2+-doped perovskite emitted at the short-wavelength near-infrared region, while Mn2+ and Co2+-doped perovskites emitted at the mid-wavelength infrared region. The detected laser-induced spontaneous parametric down-conversion phosphorescence (SPDC) occurred through a two-photon process by emitting two NIR or MIR photons among a cooperative energy transfer between the La3+ cations and the M2+ cations. Combining SrFeO3 ceramic with both a rare earth cation (RE3+) and a transition metal cation (Mn2+, Co2+ or Ni2+), rather than introducing merely RE3+ cations, greatly improved and controlled the infrared emissivity properties of synthesized perovskites through destroying their crystal symmetry and giving rise to asymmetrical lattice vibration and the nonlinear optical character. The existence of SPDC in the M2+-doped samples verifies their nonlinear character after the absence of this character in La0.7Sr0.3FeO3. Obtained results verify that, for the first time, perovskite nanomaterials are considered as nonlinear optical crystals with intense infrared emissivity at low pumping power of visible wavelengths, which nominates them for photonic applications and requires further studies regarding their lasing

  19. FIFTH SEMINAR IN MEMORY OF D.N. KLYSHKO: Generation of triphotons upon spontaneous parametric down-conversion in a resonator

    NASA Astrophysics Data System (ADS)

    Kalachev, A. A.; Fattakhova, Yu Z.

    2007-12-01

    The possibility of generating correlated three-photon states of light (triphotons) during spontaneous parametric down-conversion of light in a cubic medium in a resonator is analysed. It is shown that the number of photons per mode of the three-photon field is proportional to the square of the resonator finesse and the number of longitudinal resonator modes satisfying the triple resonance condition.

  20. Cavity-enhanced optical frequency comb spectroscopy in the mid-infrared application to trace detection of hydrogen peroxide

    NASA Astrophysics Data System (ADS)

    Foltynowicz, A.; Masłowski, P.; Fleisher, A. J.; Bjork, B. J.; Ye, J.

    2013-02-01

    We demonstrate the first cavity-enhanced optical frequency comb spectroscopy in the mid-infrared wavelength region and report the sensitive real-time trace detection of hydrogen peroxide in the presence of a large amount of water. The experimental apparatus is based on a mid-infrared optical parametric oscillator synchronously pumped by a high-power Yb:fiber laser, a high-finesse broadband cavity, and a fast-scanning Fourier transform spectrometer with autobalancing detection. The comb spectrum with a bandwidth of 200 nm centered around 3.76 μm is simultaneously coupled to the cavity and both degrees of freedom of the comb, i.e. the repetition rate and carrier envelope offset frequency, are locked to the cavity to ensure stable transmission. The autobalancing detection scheme reduces the intensity noise by a factor of 300, and a sensitivity of 5.4×10-9 cm-1 Hz-1/2 with a resolution of 800 MHz is achieved (corresponding to 6.9×10-11 cm-1 Hz-1/2 per spectral element for 6000 resolved elements). This yields a noise equivalent detection limit for hydrogen peroxide of 8 parts-per-billion (ppb); in the presence of 2.8 % of water the detection limit is 130 ppb. Spectra of acetylene, methane, and nitrous oxide at atmospheric pressure are also presented, and a line-shape model is developed to simulate the experimental data.

  1. Facile microwave-assisted synthesis of Zn2GeO4:Mn2+, Yb3+ uniform nanorods and near-infrared down-conversion properties

    NASA Astrophysics Data System (ADS)

    Yang, Min; Deng, Guowei; Hou, Tianwu; Jia, Xiaopeng; Wang, Ying; Wang, Qihui; Li, Bingke; Liu, Jialei; Liu, Xiaoyang

    2017-02-01

    Germanates have potential applications in electroluminescent fields. Herein, we report a simple strategy for the rapid synthesis of near-infrared (NIR) down-conversion Zn1.96-xGeO4+1/2x:Mn0.04Ybx phosphors using the microwave-assisted hydrothermal method. This method is facile, rapid, surfactant-free and environmentally friendly. In the Zn2GeO4 lattice, intrinsic defect transitions and Mn2+ ions act as broadband spectral sensitizers by absorbing UV-Vis (280-500 nm) photons and transferring the absorbed energy to Yb3+ centers in a cooperative down-conversion process. Efficient energy transfer is reflected by a sharp decrease in the excited state lifetime and green photoluminescence (PL) from tetrahedrally coordinated Mn2+ with increasing Yb3+ concentration. The possible formation mechanism for Zn1.96-xGeO4+1/2x:Mn0.04Ybx nanorods has been presented. PL spectroscopic characterizations show that pure Zn2GeO4 sample shows a blue emission due to defects, while Zn2GeO4:Mn2+ phosphors exhibit a green emission corresponding to the characteristic transition of Mn2+ (4T1 → 6A1) under the excitation of UV. The Yb3+ acceptor is then the source of NIR emission at a wavelength of ∼1000 nm. These phosphors are promising for applications in solar spectral down-conversion.

  2. a New Broadband Cavity Enhanced Frequency Comb Spectroscopy Technique Using GHz Vernier Filtering.

    NASA Astrophysics Data System (ADS)

    Morville, Jérôme; Rutkowski, Lucile; Dobrev, Georgi; Crozet, Patrick

    2015-06-01

    We present a new approach to Cavity Enhanced - Direct Frequency Comb Spectroscopy where the full emission bandwidth of a Titanium:Sapphire laser is exploited at GHz resolution. The technique is based on a low-resolution Vernier filtering obtained with an appreciable -actively stabilized- mismatch between the cavity Free Spectral Range and the laser repetition rate, using a diffraction grating and a split-photodiode. This particular approach provides an immunity to frequency-amplitude noise conversion, reaching an absorption baseline noise in the 10-9 cm-1 range with a cavity finesse of only 3000. Spectra covering 1800 cm-1 (˜ 55 THz) are acquired in recording times of about 1 second, providing an absorption figure of merit of a few 10-11 cm-1/√{Hz}. Initially tested with ambient air, we report progress in using the Vernier frequency comb method with a discharge source of small radicals. Rutkowski et al, Opt. Lett., 39(23)2014

  3. Near-infrared broad-band cavity enhanced absorption spectroscopy using a superluminescent light emitting diode.

    PubMed

    Denzer, W; Hamilton, M L; Hancock, G; Islam, M; Langley, C E; Peverall, R; Ritchie, G A D

    2009-11-01

    A fibre coupled near-infrared superluminescent light emitting diode that emits approximately 10 mW of radiation between 1.62 and 1.7 microm is employed in combination with a broad-band cavity enhanced spectrometer consisting of a linear optical cavity with mirrors of reflectivity approximately 99.98% and either a dispersive near-infrared spectrometer or a Fourier transform interferometer. Results are presented on the absorption of 1,3-butadiene, and sensitivities are achieved of 6.1 x 10(-8) cm(-1) using the dispersive spectrometer in combination with phase-sensitive detection, and 1.5 x 10(-8) cm(-1) using the Fourier transform interferometer (expressed as a minimum detectable absorption coefficient) over several minutes of acquisition time.

  4. Cavity-enhanced eigenmode and angular hybrid multiplexing in holographic data storage systems.

    PubMed

    Miller, Bo E; Takashima, Yuzuru

    2016-12-26

    Resonant optical cavities have been demonstrated to improve energy efficiencies in Holographic Data Storage Systems (HDSS). The orthogonal reference beams supported as cavity eigenmodes can provide another multiplexing degree of freedom to push storage densities toward the limit of 3D optical data storage. While keeping the increased energy efficiency of a cavity enhanced reference arm, image bearing holograms are multiplexed by orthogonal phase code multiplexing via Hermite-Gaussian eigenmodes in a Fe:LiNbO3 medium with a 532 nm laser at two Bragg angles. We experimentally confirmed write rates are enhanced by an average factor of 1.1, and page crosstalk is about 2.5%. This hybrid multiplexing opens up a pathway to increase storage density while minimizing modification of current angular multiplexing HDSS.

  5. Ultra-Trace Chemical Sensing with Long-Wave Infrared Cavity-Enhanced Spectroscopic Sensors

    SciTech Connect

    Taubman, Matthew S.; Myers, Tanya L.; Cannon, Bret D.; Williams, Richard M.; Schultz, John F.

    2003-02-20

    The infrared sensors task of Pacific Northwest National Laboratory's (PNNL's) Remote Spectroscopy Project (Task B of Project PL211) is focused on the science and technology of remote and in-situ spectroscopic chemical sensors for detecting proliferation and coun-tering terrorism. Missions to be addressed by remote chemical sensor development in-clude detecting proliferation of nuclear or chemical weapons, and providing warning of terrorist use of chemical weapons. Missions to be addressed by in-situ chemical sensor development include countering terrorism by screening luggage, personnel, and shipping containers for explosives, firearms, narcotics, chemical weapons, or chemical weapons residues, and mapping contaminated areas. The science and technology is also relevant to chemical weapons defense, air operations support, monitoring emissions from chemi-cal weapons destruction or industrial activities, law enforcement, medical diagnostics, and other applications. Sensors for most of these missions will require extreme chemical sensitivity and selectiv-ity because the signature chemicals of importance are expected to be present in low con-centrations or have low vapor pressures, and the ambient air is likely to contain pollutants or other chemicals with interfering spectra. Cavity-enhanced chemical sensors (CES) that draw air samples into optical cavities for laser-based interrogation of their chemical content promise real-time, in-situ chemical detection with extreme sensitivity to specified target molecules and superb immunity to spectral interference and other sources of noise. PNNL is developing CES based on quantum cascade (QC) lasers that operate in the mid-wave infrared (MWIR - 3 to 5 microns) and long-wave infrared (LWIR - 8 to 14 mi-crons), and CES based on telecommunications lasers operating in the short-wave infrared (SWIR - 1 to 2 microns). All three spectral regions are promising because smaller mo-lecular absorption cross sections in the SWIR are offset

  6. Broadband cavity-enhanced molecular spectra from Vernier filtering of a complete frequency comb.

    PubMed

    Rutkowski, Lucile; Morville, Jérôme

    2014-12-01

    We present a new approach to cavity enhanced-direct frequency comb spectroscopy where the full emission bandwidth of a titanium:sapphire laser is exploited, currently at gigahertz resolution. The technique is based on low-resolution Vernier filtering obtained with an appreciable actively stabilized mismatch between the cavity-free spectral range and the laser repetition rate, using a diffraction grating and a split-photodiode. Spectra covering 1300  cm⁻¹ (40 THz) are acquired in less than 100 ms, and a baseline noise of 1.7×10⁻⁸ cm⁻¹ is reached with a cavity finesse of only 300, providing an absorption figure of merit M=6×10⁻¹¹ cm⁻¹·Hz(-1/2).

  7. Cavity-enhanced spontaneous emission rates for rhodamine 6-G in levitated microdroplets

    SciTech Connect

    Barnes, M.D.; Whitten, W.B.; Ramsey, J.M. ); Arnold, S. )

    1992-01-01

    Fluorescence decay kinetics of Rhodamine 6-G molecules in levitated glycerol microdroplets (4--20 microns in diameter) have been investigated to determine the effects of spherical cavity resonances on spontaneous emission rates. For droplet diameters greater than 10 microns, the fluorescence lifetime is essentially the same as in bulk glycerol. As the droplet diameter is decreased below 10 microns, bi-exponential decay behavior is observed with a slow component whose rate is similar to bulk glycerol, and a fast component whose rate is as much as a factor of 10 larger than the bulk decay rate. This fast component is attributed to cavity enhancement of the spontaneous emission rate and, within the weak coupling approximation, a value for the homogeneous linewidth at room temperature can be estimated from the fluorescence lifetime data.

  8. Cavity-enhanced spontaneous emission rates for rhodamine 6-G in levitated microdroplets

    SciTech Connect

    Barnes, M.D.; Whitten, W.B.; Ramsey, J.M.; Arnold, S.

    1992-11-01

    Fluorescence decay kinetics of Rhodamine 6-G molecules in levitated glycerol microdroplets (4--20 microns in diameter) have been investigated to determine the effects of spherical cavity resonances on spontaneous emission rates. For droplet diameters greater than 10 microns, the fluorescence lifetime is essentially the same as in bulk glycerol. As the droplet diameter is decreased below 10 microns, bi-exponential decay behavior is observed with a slow component whose rate is similar to bulk glycerol, and a fast component whose rate is as much as a factor of 10 larger than the bulk decay rate. This fast component is attributed to cavity enhancement of the spontaneous emission rate and, within the weak coupling approximation, a value for the homogeneous linewidth at room temperature can be estimated from the fluorescence lifetime data.

  9. Dual-recycled cavity-enhanced Michelson interferometer for gravitational-wave detection.

    PubMed

    Müller, Guido; Delker, Tom; Tanner, David B; Reitze, David

    2003-03-01

    The baseline design for an Advanced Laser Interferometer Gravitational-Wave Observatory (Advanced LIGO) is a dual-recycled Michelson interferometer with cavities in each of the Michelson interferometer arms. We describe one possible length-sensing and control scheme for such a dual-recycled, cavity-enhanced Michelson interferometer. We discuss the principles of this scheme and derive the first-order sensing signals. We also present a successful experimental verification of our length-sensing system using a prototype tabletop interferometer. Our results demonstrate the robustness of the scheme against deviations from the idealized design. We also identify potential weaknesses and discuss possible improvements. These results as well as other benchtop experiments that we present form the basis for a sensing and control scheme for Advanced LIGO.

  10. Cavity-enhanced Faraday rotation measurement with auto-balanced photodetection.

    PubMed

    Chang, Chia-Yu; Shy, Jow-Tsong

    2015-10-01

    Optical cavity enhancement for a tiny Faraday rotation is demonstrated with auto-balanced photodetection. This configuration is analyzed using the Jones matrix formalism. The resonant rotation signal is amplified, and thus, the angular sensitivity is improved. In the experiment, the air Faraday rotation is measured with an auto-balanced photoreceiver in single-pass and cavity geometries. The result shows that the measured Faraday rotation in the single-pass geometry is enhanced by a factor of 85 in the cavity geometry, and the sensitivity is improved to 7.54×10(-10)  rad Hz(-1/2), which agrees well with the Jones matrix analysis. With this verification, we propose an AC magnetic sensor whose magnetic sensitivity is expected to achieve 10  pT Hz(-1/2).

  11. Sensitive and rapid laser diagnostic for shock tube kinetics studies using cavity-enhanced absorption spectroscopy.

    PubMed

    Sun, Kai; Wang, Shengkai; Sur, Ritobrata; Chao, Xing; Jeffries, Jay B; Hanson, Ronald K

    2014-04-21

    We report the first application of cavity-enhanced absorption spectroscopy (CEAS) using a coherent light source for sensitive and rapid gaseous species time-history measurements in a shock tube. Off-axis alignment and fast scanning of the laser wavelength were used to minimize coupling noise in a low-finesse cavity. An absorption gain factor of 83 with a measurement time resolution of 20 µs was demonstrated for C2H2 detection using a near-infrared transition near 1537 nm, corresponding to a noise-equivalent detection limit of 20 ppm at 296 K and 76 ppm at 906 K at 50 kHz. This substantial gain in signal, relative to conventional single-pass absorption, will enable ultra-sensitive species detection in shock tube kinetics studies, particularly useful for measurements of minor species and for studies of dilute reactive systems.

  12. Time-resolved broadband cavity-enhanced absorption spectroscopy for chemical kinetics.

    SciTech Connect

    Sheps, Leonid; Chandler, David W.

    2013-04-01

    Experimental measurements of elementary reaction rate coefficients and product branching ratios are essential to our understanding of many fundamentally important processes in Combustion Chemistry. However, such measurements are often impossible because of a lack of adequate detection techniques. Some of the largest gaps in our knowledge concern some of the most important radical species, because their short lifetimes and low steady-state concentrations make them particularly difficult to detect. To address this challenge, we propose a novel general detection method for gas-phase chemical kinetics: time-resolved broadband cavity-enhanced absorption spectroscopy (TR-BB-CEAS). This all-optical, non-intrusive, multiplexed method enables sensitive direct probing of transient reaction intermediates in a simple, inexpensive, and robust experimental package.

  13. Optical-feedback cavity-enhanced absorption spectroscopy with an interband cascade laser: application to SO2 trace analysis

    NASA Astrophysics Data System (ADS)

    Richard, Lucile; Ventrillard, Irene; Chau, Guilmin; Jaulin, Kevin; Kerstel, Erik; Romanini, Daniele

    2016-09-01

    The combination of interband cascade lasers (ICL) with cavity-enhanced absorption spectroscopy (CEAS) offers new perspectives in trace analysis and isotope ratio measurements. ICLs cover a mid-infrared spectral window (3-4 µm), in between those covered by Ga(InAs)Sb diode lasers and quantum cascade lasers (QCL), where strong molecular transitions can be found. While ICLs have lower emission power than QCLs, their thermal dissipation is much closer to that of telecom diode lasers and their current tuning range larger, which are both major advantages for developing compact instruments. We present an OF-CEAS implementation with an ICL at 4.015 µm, in which optical feedback (OF) enables efficient injection into the high-finesse cavity. In this paper, we also discuss a procedure allowing to obtain an accurate measurement of the OF rate. With regard to performance, we obtain a rms noise-equivalent absorption of 7.7 × 10-9 cm-1 for one acquired spectrum (80 ms) with a cavity of finesse 3900, which translates to a normalized figure of merit of 2.2 × 10-9 cm-1/√Hz, allowing for SO2 trace analysis down to ppbv levels with a response time of seconds.

  14. Cavity-enhanced Raman spectroscopy with optical feedback cw diode lasers for gas phase analysis and spectroscopy.

    PubMed

    Salter, Robert; Chu, Johnny; Hippler, Michael

    2012-10-21

    A variant of cavity-enhanced Raman spectroscopy (CERS) is introduced, in which diode laser radiation at 635 nm is coupled into an external linear optical cavity composed of two highly reflective mirrors. Using optical feedback stabilisation, build-up of circulating laser power by 3 orders of magnitude occurs. Strong Raman signals are collected in forward scattering geometry. Gas phase CERS spectra of H(2), air, CH(4) and benzene are recorded to demonstrate the potential for analytical applications and fundamental molecular studies. Noise equivalent limits of detection in the ppm by volume range (1 bar sample) can be achieved with excellent linearity with a 10 mW excitation laser, with sensitivity increasing with laser power and integration time. The apparatus can be operated with battery powered components and can thus be very compact and portable. Possible applications include safety monitoring of hydrogen gas levels, isotope tracer studies (e.g., (14)N/(15)N ratios), observing isotopomers of hydrogen (e.g., radioactive tritium), and simultaneous multi-component gas analysis. CERS has the potential to become a standard method for sensitive gas phase Raman spectroscopy.

  15. Multispecies breath analysis faster than a single respiratory cycle by optical-feedback cavity-enhanced absorption spectroscopy

    NASA Astrophysics Data System (ADS)

    Ventrillard-Courtillot, Irene; Gonthiez, Thierry; Clerici, Christine; Romanini, Daniel

    2009-11-01

    We demonstrate a first application, of optical-feedback cavity-enhanced absorption spectroscopy (OF-CEAS) to breath analysis in a medical environment. Noninvasive monitoring of trace species in exhaled air was performed simultaneous to spirometric measurements on patients at Bichat Hospital (Paris). The high selectivity of the OF-CEAS spectrometer and a time response of 0.3 s (limited by sample flow rate) allowed following the evolution of carbon monoxide and methane concentrations during individual respiratory cycles, and resolving variations among different ventilatory patterns. The minimum detectable absorption on this time scale is about 3×10-10 cm-1. At the working wavelength of the instrument (2.326 μm), this translates to concentration detection limits of ~1 ppbv (45 picomolar, or ~1.25 μg/m3) for CO and 25 ppbv for CH4, well below concentration values found in exhaled air. This same instrument is also able to provide measurement of NH3 concentrations with a detection limit of ~10 ppbv however, at present, memory effects do not allow its measurement on fast time scales.

  16. Development of a Near-Ir Cavity Enhanced Absorption Spectrometer for the Detection of Atmospheric Oxidation Products and Organoamines

    NASA Astrophysics Data System (ADS)

    Eddingsaas, Nathan C.; Jewell, Breanna; Thurnherr, Emily

    2014-06-01

    An estimated 10,000 to 100,000 different compounds have been measured in the atmosphere, each one undergoes many oxidation reactions that may or may not degrade air quality. To date, the fate of even some of the most abundant hydrocarbons in the atmosphere is poorly understood. One difficulty is the detection of atmospheric oxidation products that are very labile and decompose during analysis. To study labile species under atmospheric conditions, a highly sensitive, non-destructive technique is needed. Here we describe a near-IR incoherent broadband cavity enhanced absorption spectroscopy (IBBCEAS) setup that we are developing to meet this end. We have chosen to utilize the near-IR, where vibrational overtone absorptions are observed, due to the clean spectral windows and better spectral separation of absorption features. In one spectral window we can simultaneously and continuously monitor the composition of alcohols, hydroperoxides, and carboxylic acids in an air mass. In addition, we have used our CEAS setup to detect organoamines. The long effective path length of CEAS allows for low detection limits, even of the overtone absorption features, at ppb and ppt levels.

  17. Beating the Standard Sensitivity-Bandwidth Limit of Cavity-Enhanced Interferometers with Internal Squeezed-Light Generation

    NASA Astrophysics Data System (ADS)

    Korobko, M.; Kleybolte, L.; Ast, S.; Miao, H.; Chen, Y.; Schnabel, R.

    2017-04-01

    The shot-noise limited peak sensitivity of cavity-enhanced interferometric measurement devices, such as gravitational-wave detectors, can be improved by increasing the cavity finesse, even when comparing fixed intracavity light powers. For a fixed light power inside the detector, this comes at the price of a proportional reduction in the detection bandwidth. High sensitivity over a large span of signal frequencies, however, is essential for astronomical observations. It is possible to overcome this standard sensitivity-bandwidth limit using nonclassical correlations in the light field. Here, we investigate the internal squeezing approach, where the parametric amplification process creates a nonclassical correlation directly inside the interferometer cavity. We theoretically analyze the limits of the approach and measure 36% increase in the sensitivity-bandwidth product compared to the classical case. To our knowledge, this is the first experimental demonstration of an improvement in the sensitivity-bandwidth product using internal squeezing, opening the way for a new class of optomechanical force sensing devices.

  18. Cavity enhanced spectroscopy for measurement of nitrogen oxides in the Anthropocene: results from the Seoul tower during MAPS 2015.

    PubMed

    Brown, Steven S; An, Hyunjin; Lee, Meehye; Park, Jeong-Hoo; Lee, Sang-Deok; Fibiger, Dorothy L; McDuffie, Erin E; Dubé, William P; Wagner, Nicholas L; Min, Kyung-Eun

    2017-08-24

    Cavity enhanced spectroscopy, CES, is a high sensitivity direct absorption method that has seen increasing utility in the last decade, a period also marked by increasing requirements for understanding human impacts on atmospheric composition. This paper describes the current NOAA six channel cavity ring-down spectrometer (CRDS, the most common form of CES) for measurement of nitrogen oxides and O3. It further describes the results from measurements from a tower 300 m above the urban area of Seoul in late spring of 2015. The campaign demonstrates the performance of the CRDS instrument and provides new data on both photochemistry and nighttime chemistry in a major Asian megacity. The instrument provided accurate, high time resolution data for N2O5, NO, NO2, NOy and O3, but suffered from large wall loss in the sampling of NO3, illustrating the requirement for calibration of the NO3 inlet transmission. Both the photochemistry and nighttime chemistry of nitrogen oxides and O3 were rapid in this megacity. Sustained average rates of O3 buildup of 10 ppbv h(-1) during recurring morning and early afternoon sea breezes led to a 50 ppbv average daily O3 rise. Nitrate radical production rates, P(NO3), averaged 3-4 ppbv h(-1) in late afternoon and early evening, much greater than contemporary data from Los Angeles, a comparable U. S. megacity. These P(NO3) were much smaller than historical data from Los Angeles, however. Nighttime data at 300 m above ground showed considerable variability in high time resolution nitrogen oxide and O3, likely resulting from sampling within gradients in the nighttime boundary layer structure. Apparent nighttime biogenic VOC oxidation rates of several ppbv h(-1) were also likely influenced by vertical gradients. Finally, daytime N2O5 mixing ratios of 3-35 pptv were associated with rapid daytime P(NO3) and agreed well with a photochemical steady state calculation.

  19. An instrument for measurements of BrO with LED-based Cavity-Enhanced Differential Optical Absorption Spectroscopy

    NASA Astrophysics Data System (ADS)

    Hoch, D. J.; Buxmann, J.; Sihler, H.; Pöhler, D.; Zetzsch, C.; Platt, U.

    2014-01-01

    The chemistry of the troposphere and specifically the global tropospheric ozone budget is affected by reactive halogen species such as bromine monoxide (BrO) or chlorine monoxide (ClO). Especially BrO plays an important role in the processes of ozone destruction, disturbance of NOx and HOx chemistry, oxidation of dimethyl sulfide (DMS), and the deposition of elementary mercury. In the troposphere BrO has been detected in polar regions, at salt lakes, in volcanic plumes, and in the marine boundary layer. For a better understanding of these processes, field measurements as well as reaction chamber studies are performed. In both cases instruments with high spatial resolution and high sensitivity are necessary. A Cavity-Enhanced Differential Optical Absorption Spectroscopy (CE-DOAS) instrument with an open path measurement cell was designed and applied. For the first time, a CE-DOAS instrument is presented using an UV LED in the 325-365 nm wavelength range. In laboratory studies, BrO as well as HONO, HCHO, O3, and O4 could be reliably determined at detection limits of 20 ppt for BrO, 9.1 ppb for HCHO, 970 ppt for HONO, and 91 ppb for O3, for five minutes integration time. The best detection limits were achieved for BrO (11 ppt), HCHO (5.1 ppb), HONO (490 ppt), and O3 (59 ppb) for integration times of 81 minutes or less. Comparison with established White system (WS) DOAS and O3 monitor measurements demonstrate the reliability of the instrument.

  20. [Measurement of Trace C2H6 Based on Optical-Feedback Cavity-Enhanced Absorption Spectroscopy].

    PubMed

    Wan, Fu; Chen, Wei-gen; Gu, Zhao-liang; Zou, Jing-xin; DU, Ling-Ling; Qi, Wei; Zhou, Qu

    2015-10-01

    Ethane is one of major fault characteristic gases dissolved in power transformer, the detection of Ethane with high accuracy and sensitivity is the key of dissolved gas analysis. In this paper, based on optical feedback theory and cavity-enhanced absorption spectroscopy, combined with quantum cascade laser, a detection system for dissolved gas C2 H6 in transformer oil was built up. Based on the symmetry of the individual cavity modes, the phase matching of returning light in resonance with the cavity was achieved through LabVIEW codes. The optical feedback effect that the emitted light return to the laser cavity after a small delay time and lock to the resonance frequency of cavity, even and odd modes effect that the higher modes and lower modes structure will build up alternatively, and threshold current lowering effect of about 1.2 mA were studied and achieved. By cavity ring-down spectroscopy, the effective reflectivity of 99.978% and cavity finesse of 7 138.4 is obtained respectively. The frequency selectivity is 0.005 2 cm(-1). With an acquisition time of 1s, this optical system allows detection for the PQ3 band of C2 H6 with high accuracy of 95.72% ± 0.17% and detection limit of (1.97 ± 0.06) x 10(-3) μL x L(-1) at atmospheric pressure and temperature of 20 degrees C, which lays a foundation for fault diagnose from dissolved gas analysis.

  1. Chemical Sensing Using Infrared Cavity Enhanced Spectroscopy: Short Wave Infrared Cavity Ring Down Spectroscopy (SWIR CRDS) Sensor

    SciTech Connect

    Williams, Richard M.; Harper, Warren W.; Aker, Pam M.; Thompson, Jason S.; Stewart, Timothy L.

    2003-10-01

    The principal goal of Pacific Northwest National Laboratory's (PNNL's) Remote Spectroscopy Project is to explore and develop the science and technology behind point and stand off infrared (IR) spectroscopic chemical sensors that are needed for detecting weapons proliferation activity and countering terrorism. Missions addressed include detecting chemical, biological, and nuclear weapons and their production; counter terrorism measures that involve screening luggage, personnel, and shipping containers for explosives, firearms, narcotics, chemical weapons and/or their residues; and mapping of contaminated areas. The science and technology developed in this program is dual use in that it additionally supports progress in a diverse set of agendas that include chemical weapons defense programs, air operations activities, emissions monitoring, law enforcement, and medical diagnostics. Sensors for these missions require extremely low limits of detection because many of the targeted signature species are either present in low concentrations or have extremely low vapor pressures. The sensors also need to be highly selective as the environments that they will be operated in will contain a variety of interferent species and false positive detection is not an option. PNNL has been working on developing a class of sensors that draw vapor into optical cavities and use laser-based spectroscopy to identify and quantify the vapor chemical content. The cavity enhanced spectroscopies (CES) afford extreme sensitivity, excellent selectivity, noise immunity, and rapid, real-time, in-situ chemical characterization. PNNL's CES program is currently focused on developing two types of sensors. The first one, which is based on cavity ring down spectroscopy (CRDS), uses short wave infrared (SWIR) lasers to interrogate species. The second sensor, which is based on noise immune cavity-enhanced optical heterodyne molecular spectroscopy (NICE OHMS), uses long wave infrared (LWIR) quantum cascade

  2. Cavity-Enhanced Near-Infrared Laser Absorption Spectrometer for the Measurement of Acetonitrile in Breath.

    PubMed

    Gianella, Michele; Ritchie, Grant A D

    2015-07-07

    Elevated concentrations of acetonitrile have been found in the exhaled breath of patients with cystic fibrosis1 and may indicate the severity of their condition or the presence of an accompanying bacterial infection of the airways. There is therefore interest in detecting acetonitrile in exhaled breath. For this purpose, a cavity-enhanced laser absorption spectrometer (λ = 1.65 μm) with a preconcentration stage was built and is described here. The spectrometer has a limit of detection of 72 ppbv and 114 ppbv of acetonitrile in nitrogen and breath, respectively, with a measurement duration of just under 5 min. The preconcentration stage, which employs a carbon molecular sieve and an adsorption/thermal desorption cycle, can increase the acetonitrile concentration by up to a factor 93, thus, lowering the overall limit of detection to approximately 1 ppbv. The suitability of the system for acetonitrile measurements in breath is demonstrated with breath samples taken from the authors, which yielded acetonitrile concentrations of 23 ± 3 ppbv and 29 ± 3 ppbv, respectively.

  3. Near infrared cavity enhanced absorption spectra of atmospherically relevant ether-1, 4-Dioxane

    NASA Astrophysics Data System (ADS)

    Chandran, Satheesh; Varma, Ravi

    2016-01-01

    1, 4-Dioxane (DX) is a commonly found ether in industrially polluted atmosphere. The near infrared absorption spectra of this compound has been recorded in the region 5900-8230 cm- 1 with a resolution of 0.08 cm- 1 using a novel Fourier transform incoherent broadband cavity-enhanced absorption spectrometer (FT-IBBCEAS). All recorded spectra were found to contain regions that are only weakly perturbed. The possible combinations of fundamental modes and their overtone bands corresponding to selected regions in the measured spectra are tabulated. Two interesting spectral regions were identified as 5900-6400 cm- 1 and 8100-8230 cm- 1. No significant spectral interference due to presence of water vapor was observed suggesting the suitability of these spectral signatures for spectroscopic in situ detection of DX. The technique employed here is much more sensitive than standard Fourier transform spectrometer measurements on account of long effective path length achieved. Hence significant enhancement of weaker absorption lines above the noise level was observed as demonstrated by comparison with an available measurement from database.

  4. Incoherent broadband cavity-enhanced total internal reflection spectroscopy of surface-adsorbed metallo-porphyrins.

    PubMed

    Ruth, Albert A; Lynch, Kieran T

    2008-12-21

    An improvement of conventional attenuated total reflection (ATR) spectroscopy is demonstrated by applying an incoherent broadband light source (short-arc Xe-lamp) in a cavity-enhanced evanescent-wave absorption method. With this novel approach the absorption spectra of several metallo-octaethyl porphyrins (palladium (PdOEP), platinum (PtOEP) and zinc (ZnOEP)) in thin acetone solution layers and on a fused silica (FS) surface are studied between approximately 390 and 625 nm. The time dependence of the evaporation process of the solution on the FS surface is described. The maximum sensitivity of the setup is estimated at approximately 2 x 10(-5) per pass, which translates into a minimal detectable surface density of less than 2 x 10(-3) monolayers for the porphyrins studied (based on the strong absorption in the Soret bands). Changes of surface and solution spectra are characterised and discussed on the basis of observed band broadenings and spectral shifts. For Pd- and PtOEP the changes of spectral feature can be interpreted with respect to J-aggregate formation supported by polarization dependent measurements. The reason for an observed blue-shift of ca. 10 nm for the Soret band in ZnOEP in combination with a large red-shift of the Q-bands (11 nm for Q1 and 18 nm for Q2) is discussed.

  5. Incoherent broadband cavity-enhanced total internal reflection spectroscopy of surface-adsorbed metallo-porphyrins

    NASA Astrophysics Data System (ADS)

    Ruth, A. A.; Glaczynski, G.; Lynch, K. T.

    2009-04-01

    An improvement of conventional attenuated total reflection (ATR) spectroscopy is demonstrated by applying an incoherent broadband light source (short-arc Xe-lamp) in a cavity-enhanced evanescent-wave absorption method. With this novel approach the absorption spectra of several metallo-octaethyl porphyrins (Palladium (PdOEP), Platinum (PtOEP) and Zinc- (ZnOEP)) in thin acetone solution layers and on a fused silica (FS) surface were studied between 390 and 625 nm. The time dependence of the evaporation process of the solution on the FS surface is described. The maximum sensitivity of the setup is estimated at approximately 2 Ã- 10-5 per pass, which translates into a minimal detectable surface density of less than 2 Ã- 10-3 monolayers for the porphyrins studied (based on absorption in the strong Soret bands). Changes of surface and solution spectra are characterised and discussed on basis of observed band broadenings and spectral shifts. This new approach is of relevance for investigations in atmopsheric and planetary sciences involving absorbers on surfaces and heterogeneous chemistry.

  6. Optical feedback cavity enhanced absorption spectroscopy: effective adjustment of the feedback-phase

    NASA Astrophysics Data System (ADS)

    Habig, J. C.; Nadolny, J.; Meinen, J.; Saathoff, H.; Leisner, T.

    2012-02-01

    Optical-feedback cavity enhanced absorption spectroscopy (OF-CEAS) is a very sensitive technique for the detection of trace amounts of gaseous absorbers. The most crucial parameter in an OF-CEAS setup is the optical phase of the light fed back into the laser source, which is usually controlled by the position of a piezo driven mirror. Various approaches for the analysis of the cavity transmitted light with respect to feedback-phase are presented, and tested on simulated phase and frequency dependent cavity transmission. Finally, we present the performance of a digital signal processor based regulator—employing one of these approaches—in a real OF-CEAS experiment. The results of the simulation show that several algorithms are well suited for the task of control signal generation. They confirm also that with the presented approach, a mode by mode correction of the feedback-phase is possible. Consequently, a regulatory bandwidth of 37 Hz was achieved. This maximum control frequency was limited by the piezo system.

  7. Interfacing whispering-gallery microresonators and free space light with cavity enhanced Rayleigh scattering

    PubMed Central

    Zhu, Jiangang; Özdemir, Şahin K.; Yilmaz, Huzeyfe; Peng, Bo; Dong, Mark; Tomes, Matthew; Carmon, Tal; Yang, Lan

    2014-01-01

    Whispering gallery mode resonators (WGMRs) take advantage of strong light confinement and long photon lifetime for applications in sensing, optomechanics, microlasers and quantum optics. However, their rotational symmetry and low radiation loss impede energy exchange between WGMs and the surrounding. As a result, free-space coupling of light into and from WGMRs is very challenging. In previous schemes, resonators are intentionally deformed to break circular symmetry to enable free-space coupling of carefully aligned focused light, which comes with bulky size and alignment issues that hinder the realization of compact WGMR applications. Here, we report a new class of nanocouplers based on cavity enhanced Rayleigh scattering from nano-scatterer(s) on resonator surface, and demonstrate whispering gallery microlaser by free-space optical pumping of an Ytterbium doped silica microtoroid via the scatterers. This new scheme will not only expand the range of applications enabled by WGMRs, but also provide a possible route to integrate them into solar powered green photonics. PMID:25227918

  8. Development of a cavity-enhanced absorption spectrometer for airborne measurements of CH4 and CO2

    NASA Astrophysics Data System (ADS)

    O'Shea, S. J.; Bauguitte, S. J.-B.; Gallagher, M. W.; Lowry, D.; Percival, C. J.

    2013-05-01

    High-resolution CH4 and CO2 measurements were made on board the FAAM BAe-146 UK (Facility for Airborne Atmospheric Measurements, British Aerospace-146) atmospheric research aircraft during a number of field campaigns. The system was based on an infrared spectrometer using the cavity-enhanced absorption spectroscopy technique. Correction functions to convert the mole fractions retrieved from the spectroscopy to dry-air mole fractions were derived using laboratory experiments and over a 3 month period showed good stability. Long-term performance of the system was monitored using WMO (World Meteorological Office) traceable calibration gases. During the first year of operation (29 flights) analysis of the system's in-flight calibrations suggest that its measurements are accurate to 1.28 ppb (1σ repeatability at 1 Hz = 2.48 ppb) for CH4 and 0.17 ppm (1σ repeatability at 1 Hz = 0.66 ppm) for CO2. The system was found to be robust, no major motion or altitude dependency could be detected in the measurements. An inter-comparison between whole-air samples that were analysed post-flight for CH4 and CO2 by cavity ring-down spectroscopy showed a mean difference between the two techniques of -2.4 ppb (1σ = 2.3 ppb) for CH4 and -0.22 ppm (1σ = 0.45 ppm) for CO2. In September 2012, the system was used to sample biomass-burning plumes in Brazil as part of the SAMBBA project (South AMerican Biomass Burning Analysis). From these and simultaneous CO measurements, emission factors for savannah fires were calculated. These were found to be 2.2 ± 0.2 g (kg dry matter)-1 for CH4 and 1710 ± 171 g (kg dry matter)-1 for CO2, which are in excellent agreement with previous estimates in the literature.

  9. QCL - Optical-Feedback Cavity Enhanced Absorption Spectroscopy For The Analysis Of Atmospheric 13CO2/12CO2 In Ice-Core Gas Bubbles

    NASA Astrophysics Data System (ADS)

    Gorrotxategi Carbajo, Paula; Romanini, Daniele; Maisons, Gregory; Carras, Mathieu; Chappellaz, Jerome; Kerstel, Erik

    2013-04-01

    In the context of a globally warming climate it is crucial to study the climate variability in the past and to understand the underlying mechanisms. The composition of gas stored in bubbles in polar ice presents a paleo-climate archive that provides a powerful means to study the exact mechanisms involved in the ~40% increase in the atmospheric CO2 concentration between glacial and interglacial climates. It is particularly important to understand such natural coupling between climate and the carbon cycle, as it will partly determine what natural feedback can be expected on the atmospheric CO2 concentration in a future warmer world. The source of the CO2 released into the atmosphere during previous deglaciations can be constrained from isotopic measurements by the fact that the different CO2 reservoirs (terrestrial biosphere, oceans) and associated mechanisms (biological or physical) have different isotopic signatures. Unfortunately, such isotope studies have been seriously hampered by the experimental difficulty of extracting the CO2 without contamination or fractionation, and measuring the isotope signal off-line on an isotope ratio mass spectrometer (IRMS). Here we present an alternative method that leverages the extreme sensitivity afforded by Optical Feedback Cavity Enhanced Absorption Spectroscopy (OF-CEAS) in the Mid-Infrared [1]. This region of the spectrum is accessed by a custom-developed Quantum Cascade Laser operating near 4.35 µm. The feedback to the laser of light that has been spectrally filtered by a high-finesse, V-shaped enhancement cavity has the effect of spectrally narrowing the laser emission and to auto-lock the laser frequency to one of the cavity's longitudinal modes, with clear advantages in terms of acquisition time and signal-to-noise ratio of the measurement. The line strengths in this region are about 5 orders of magnitude higher than in the more easily accessible NIR region near 1.6 µm and about 1000 times higher than at 2 µm. The

  10. Noise-immune cavity-enhanced analytical atomic spectrometry - NICE-AAS - A technique for detection of elements down to zeptogram amounts

    NASA Astrophysics Data System (ADS)

    Axner, Ove; Ehlers, Patrick; Hausmaninger, Thomas; Silander, Isak; Ma, Weiguang

    2014-10-01

    Noise-immune cavity-enhanced optical heterodyne molecular spectroscopy (NICE-OHMS) is a powerful technique for detection of molecular compounds in gas phase that is based on a combination of two important concepts: frequency modulation spectroscopy (FMS) for reduction of noise, and cavity enhancement, for prolongation of the interaction length between the light and the sample. Due to its unique properties, it has demonstrated unparalleled detection sensitivity when it comes to detection of molecular constituents in the gas phase. However, despite these, it has so far not been used for detection of atoms, i.e. for elemental analysis. The present work presents an assessment of the expected performance of Doppler-broadened (Db) NICE-OHMS for analytical atomic spectrometry, then referred to as noise-immune cavity-enhanced analytical atomic spectrometry (NICE-AAS). After a description of the basic principles of Db-NICE-OHMS, the modulation and detection conditions for optimum performance are identified. Based on a previous demonstrated detection sensitivity of Db-NICE-OHMS of 5 × 10- 12 cm- 1 Hz- 1/2 (corresponding to a single-pass absorbance of 7 × 10- 11 over 10 s), the expected limits of detection (LODs) of Hg and Na by NICE-AAS are estimated. Hg is assumed to be detected in gas phase directly while Na is considered to be atomized in a graphite furnace (GF) prior to detection. It is shown that in the absence of spectral interferences, contaminated sample compartments, and optical saturation, it should be feasible to detect Hg down to 10 zg/cm3 (10 fg/m3 or 10- 5 ng/m3), which corresponds to 25 atoms/cm3, and Na down to 0.5 zg (zg = zeptogram = 10- 21 g), representing 50 zg/mL (parts-per-sextillion, pps, 1:1021) in liquid solution (assuming a sample of 10 μL) or solely 15 atoms injected into the GF, respectively. These LODs are several orders of magnitude lower (better) than any previous laser-based absorption technique previously demonstrated under atmospheric

  11. Cavity-enhanced rotational Raman scattering in gases using a 20  mW near-infrared fiber laser.

    PubMed

    Friss, Adam J; Limbach, Christopher M; Yalin, Azer P

    2016-07-15

    A novel cavity-enhanced laser diagnostic has been developed to perform point measurements of spontaneous rotational Raman scattering. A narrow linewidth fiber laser source (1064 nm) is frequency locked to a high-finesse cavity containing the sample gas. Intracavity powers of 22 W are generated from 3.7 mW of incident laser power, corresponding to a buildup factor of 5900. A triple monochromator and a photomultiplier tube in counting mode are used to disperse and measure the scattering spectra. The system is demonstrated with rotational Raman spectra of nitrogen, oxygen, and carbon dioxide at atmospheric pressure. The approach will allow temporally and spatially resolved Raman measurements for combustion diagnostics and, by extending to higher power, Thomson scattering for diagnostics of low-density plasmas.

  12. Precision Cavity-Enhanced Dual-Comb Spectroscopy: Application to the Gas Metrology of CO_2, H_2O, and N_2O.

    NASA Astrophysics Data System (ADS)

    Fleisher, Adam J.; Long, David A.; Hodges, Joseph T.

    2017-06-01

    With inherent simplicity, mutual phase coherence, and a high degree of user control, electro-optic frequency combs are amenable to both dual-comb spectroscopy and cavity-enhanced comb spectroscopy. This combination of fast, multiplexed spectroscopy, with an effective absorption pathlength >1 km, is used here to perform line-by-line metrology of the gas-phase absorption spectra of CO_2, H_2O, and N_2O in the near-infrared. We report absolute transition frequency with precision better than 1 MHz in 1 s of spectral acquisition per transition using a comb with an instantaneous optical bandwidth of 6 GHz, tunable over the entire 6240-6370 \\wn range. A full model for the electric field transmitted through the enhancement cavity (even in the presence of strong molecular absorption and dispersion) will be discussed. I. Coddington et al., Optica 3, 414 (2016) B. Bernhardt et al., Nat. Photonics 4, 55 (2010)

  13. Cavity-enhanced AlGaAs/GaAs resonant tunneling photodetectors for telecommunication wavelength light detection at 1.3 μm

    NASA Astrophysics Data System (ADS)

    Pfenning, Andreas; Hartmann, Fabian; Langer, Fabian; Kamp, Martin; Höfling, Sven; Worschech, Lukas

    2015-09-01

    We demonstrate a cavity-enhanced photodetector at the telecommunication wavelength of λ = 1.3 μm based on a resonant tunneling diode (RTD). The cavity-enhanced RTD photodetector consists of three integral parts: First, a Ga0.89In0.11N0.04As0.96 absorption layer that can be grown lattice-matched on GaAs and which is light-active in the near infrared spectral region due to its reduced bandgap energy. Second, an Al0.6Ga0.4As/GaAs double barrier resonant tunneling structure (RTS) that serves as high gain internal amplifier of weak electric signals caused by photogenerated electron-hole pairs within the GaInNAs absorption layer. Third, an optical distributed Bragg reflector (DBR) cavity consisting of five top and seven bottom alternating GaAs/AlAs mirror pairs, which provides an enhanced quantum efficiency at the resonance wavelength. The samples were grown by molecular beam epitaxy. Electro-optical properties of the RTDs were studied at room temperature. From the reflection-spectrum the optical resonance at λ = 1.29 μm was extracted. The current-voltage characteristics were studied in the dark and under illumination and a wellpronounced photo-response was found and is attributed to accumulation of photogenerated holes in the vicinity of the RTS. The maximum photocurrent was found at the optical resonance of 1.29 μm. At resonance, a sensitivity of S = 3.97 × 104 A/W was observed. From the sensitivity, a noise equivalent power of NEP = 1.18 × 10-16 W/Hz1/2, and a specific detectivity of D∗ ≅ 6.74 × 1012 cm Hz1/2/W were calculated. For a single absorbed photon a photocurrent of ISP = 50 pA was determined.

  14. Rapid monitoring of intermediate states and mass balance of nitrogen during denitrification by means of cavity enhanced Raman multi-gas sensing.

    PubMed

    Keiner, Robert; Herrmann, Martina; Küsel, Kirsten; Popp, Jürgen; Frosch, Torsten

    2015-03-15

    The comprehensive investigation of changes in N cycling has been challenging so far due to difficulties with measuring gases such as N2 and N2O simultaneously. In this study we introduce cavity enhanced Raman gas spectroscopy as a new analytical methodology for tracing the stepwise reduction of (15)N-labelled nitrate by the denitrifying bacteria Pseudomonas stutzeri. The unique capabilities of Raman multi-gas analysis enabled real-time, continuous, and non-consumptive quantification of the relevant gases ((14)N2, (14)N2O, O2, and CO2) and to trace the fate of (15)N-labeled nitrate substrate ((15)N2, (15)N2O) added to a P. stutzeri culture with one single measurement. Using this new methodology, we could quantify the kinetics of the formation and degradation for all gaseous compounds (educts and products) and thus study the reaction orders. The gas quantification was complemented with the analysis of nitrate and nitrite concentrations for the online monitoring of the total nitrogen element budget. The simultaneous quantification of all gases also enabled the contactless and sterile online acquisition of the pH changes in the P. stutzeri culture by the stoichiometry of the redox reactions during denitrification and the CO2-bicarbonate equilibrium. Continuous pH monitoring - without the need to insert an electrode into solution - elucidated e.g. an increase in the slope of the pH value coinciding with an accumulation of nitrite, which in turn led to a temporary accumulation of N2O, due to an inhibition of nitrous oxide reductase. Cavity enhanced Raman gas spectroscopy has a high potential for the assessment of denitrification processes and can contribute substantially to our understanding of nitrogen cycling in both natural and agricultural systems. Copyright © 2015 Elsevier B.V. All rights reserved.

  15. Broadband down-conversion based near infrared quantum cutting in Eu{sup 2+}–Yb{sup 3+} co-doped SrAl{sub 2}O{sub 4} for crystalline silicon solar cells

    SciTech Connect

    Tai, Yuping; Zheng, Guojun; Wang, Hui; Bai, Jintao

    2015-03-15

    Near infrared (NIR) quantum cutting involving the down conversion of an absorbed visible photon to emission of two NIR photons was achieved in SrAl{sub 2}O{sub 4}:0.01Eu{sup 2+}, xYb{sup 3+} (x=0, 1, 2, 5, 10, 20, 30 mol%) samples. The photoluminescence properties of samples in visible and NIR regions were measured to verify the energy transfer (ET) from Eu{sup 2+} to Yb{sup 3+}. The results demonstrated that Eu{sup 2+} was an efficient sensitizer for Yb{sup 3+} in the SrAl{sub 2}O{sub 4} host lattice. According to Gaussian fitting analysis and temperature-dependent luminescence experiments, the conclusion was drawn that the cooperative energy transfer (CET) process dominated the ET process and the influence of charge transfer state (CTS) of Yb{sup 3+} could be negligible. As a result, the high energy transfer efficiency (ETE) and quantum yield (QY) have been acquired, the maximum value approached 73.68% and 147.36%, respectively. Therefore, this down-conversion material has potential application in crystalline silicon solar cells to improve conversion efficiency. - Graphical abstract: Near infrared quantum cutting was achieved in Eu{sup 2+}–Yb{sup 3+} co-doped SrAl{sub 2}O{sub 4} samples. The cooperative energy transfer process dominated energy transfer process and high energy transfer efficiency was acquired. - Highlights: • The absorption spectrum of Eu{sup 2+} ion is strong in intensity and broad in bandwidth. • The spectra of Eu{sup 2+} in SrAl{sub 2}O{sub 4} lies in the strongest region of solar spectrum. • The cooperative energy transfer (CET) dominated the energy transfer process. • The domination of CET is confirmed by experimental analysis. • SrAl{sub 2}O{sub 4}:Eu{sup 2+},Yb{sup 3+} show high energy transfer efficiency and long lifetime.

  16. Where are photons created in parametric down-conversion? On the control of the spatio-temporal properties of biphoton states

    NASA Astrophysics Data System (ADS)

    Büse, A.; Tischler, N.; Juan, M. L.; Molina-Terriza, G.

    2015-06-01

    In spontaneous parametric down-conversion, pairs of photons are known to be created coherently and with equal probability over the entire length of the crystal. Then, there is no particular position in the crystal where a photon pair is created. We make the seemingly contradictory observation that the time delay between the photons in the pair depends on the distance from the crystal to the collection lens, as if the photons were actually collected preferentially from a particular position in the crystal. We resolve this contradiction by showing that the spatio-temporal correlations critically affect the temporal properties of the pair of photons. The theoretical model we present matches all our experimental results. We expect this to have important implications for experiments that require indistinguishable photons.

  17. ELECTROMAGNETISM, OPTICS, ACOUSTICS, HEAT TRANSFER, CLASSICAL MECHANICS, AND FLUID DYNAMICS: Time Evolution and Squeezing of Degenerate and Non-degenerate Coupled Parametric Down-Conversion with Driving Term

    NASA Astrophysics Data System (ADS)

    Li, Jiang-Fan; Fang, Jia-Yuan; Xiao, Fu-Liang; Liu, Xin-Hai; Wang, Cheng-Zhi

    2009-03-01

    By properly selecting the time-dependent unitary transformation for the linear combination of the number operators, we construct a time-dependent invariant and derive the corresponding auxiliary equations for the degenerate and non-degenerate coupled parametric down-conversion system with driving term. By means of this invariant and the Lewis-Riesenfeld quantum invariant theory, we obtain closed formulae of the quantum state and the evolution operator of the system. We show that the time evolution of the quantum system directly leads to production of various generalized one- and two-mode combination squeezed states, and the squeezed effect is independent of the driving term of the Hamiltonian. In some special cases, the current solution can reduce to the results of the previous works.

  18. Frequency down-conversion of 637 nm light to the telecommunication band for non-classical light emitted from NV centers in diamond.

    PubMed

    Ikuta, Rikizo; Kobayashi, Toshiki; Yasui, Shuto; Miki, Shigehito; Yamashita, Taro; Terai, Hirotaka; Fujiwara, Mikio; Yamamoto, Takashi; Koashi, Masato; Sasaki, Masahide; Wang, Zhen; Imoto, Nobuyuki

    2014-05-05

    We demonstrate a low-noise frequency down-conversion of photons at 637 nm to the telecommunication band at 1587 nm by the difference frequency generation in a periodically-poled lithium niobate. An internal conversion efficiency of the converter is estimated to be 0.44 at the maximum which is achieved by a pump power of 0.43 W, whereas a rate of internal background photons caused by the strong cw pump laser is estimated to be 9 kHz/mW within a bandwidth of about 1 nm. By using the experimental values related to the intrinsic property of the converter, and using the intensity correlation and the average photon number of a 637 nm input light pulse, we derive the intensity correlation of a converted telecom light pulse. Then we discuss feasibility of a single-photon frequency conversion to the telecommunication band for a long-distance quantum communication based on NV centers in diamond.

  19. A new calibration system for lightweight, compact and mobile Cavity-Enhanced Differential Optical Absorption Spectroscopy instruments

    NASA Astrophysics Data System (ADS)

    Zielcke, Johannes; Horbanski, Martin; Pöhler, Denis; Frieß, Udo; Platt, Ulrich

    2013-04-01

    Absorption Spectroscopy has been employed for several decades now to study the earth's atmosphere. While the focus has been on remote sensing for a long time, lately there has been a renewed interest in in-situ methods, as point measurements allow an easier interpretation for highly inhomogeneous distributions of gases of interest compared to the integration approach of most remote sensing methods. One comparatively new method offering both advantages of in-situ measurements as well as being contactless is open-path Cavity-Enhanced Differential Optical Absorption Spectroscopy (CE-DOAS). Broadband open-path CE-DOAS instruments have been used for ten years now, and in the meantime allow the measurement of numerous atmospheric trace gases (e.g. NO2, NO3, IO, CHOCHO, HCHO). While those instruments were bulky and not very mobile at first, recent developments resulted in relatively lightweight (< 30 kg) instruments with a relatively low power consumption allowing mobile open-path measurements at remote field locations. An important operational issue has been the path length calibration in the field, necessary for the determination of the concentration of measured gases. Until now, often calibration gases were used with different scattering properties than air or known concentrations. However this methods has several major shortcomings, being rather inconvenient and cumbersome in the field with the need for compressed gas cylinders, as well as time consuming, preventing a quick check of the state of the instrument in the field after changing measurement locations. Here we present a new wavelength-resolved method for broadband CE-DOAS path length calibration. A small, custom made ring-down system is employed with a pulsed LED as light source. The wavelength is then resolved by tilting a narrow band interference filter. The system not only allows quick, automated path length calibrations without physical interaction on the instrument, but also saves weight, space and the

  20. Efficient THZ Source Based on Cascaded Optical Down-Conversion in Orientation-Patterned GaAs Structures

    DTIC Science & Technology

    2008-11-20

    techniques for generating THz radiation [5], none of them provides a THz source which is simultaneously ( i ) compact, (ii) highly efficient, (iii...are very attractive for QPM THz-wave generation because of several appealing properties, namely ( i ) small THz absorption coefficient (smaller by an...with periodically- inverted crystalline orientation were used for QPM THz generation: ( i ) diffusion-bonded GaAs (DB-GaAs) [49], produced by

  1. Using active resonator impedance matching for shot-noise limited, cavity enhanced amplitude modulated laser absorption spectroscopy.

    PubMed

    Chow, Jong H; Littler, Ian C M; Rabeling, David S; McClelland, David E; Gray, Malcolm B

    2008-05-26

    We introduce a closed-loop feedback technique to actively control the coupling condition of an optical cavity, by employing amplitude modulation of the interrogating laser. We show that active impedance matching of the cavity facilitates optimal shot-noise sensing performance in a cavity enhanced system, while its control error signal can be used for intra-cavity absorption or loss signal extraction. We present the first demonstration of this technique with a fiber ring cavity, and achieved shot-noise limited loss sensitivity. We also briefly discuss further use of impedance matching control as a tool for other applications.

  2. Higher-order spontaneous parametric down-conversion with back-propagating idler using a submicron poled KTP waveguide

    NASA Astrophysics Data System (ADS)

    Bashkansky, Mark; Pruessner, Marcel W.; Vurgaftman, Igor; Kim, Mijin; Reintjes, J.

    2016-05-01

    Spontaneous parametric downconversion (SPDC) using periodically poled nonlinear optical crystals under the quasiphase- matching condition has found wide use in quantum optics. High efficiencies and good coupling to single-mode fibers resulted from using channel waveguides in crystals. It is often desirable to have a very narrow bandwidth for the signal and idler photons, but under the typical operating conditions, phase matching dictates the bandwidth of the SPDC to be of the order of <1 nm. This occurs because the co-propagating signal and idler photons are entangled, and an increase of the signal wave-vector is compensated by a decrease of the idler wave-vector. One way to reduce the bandwidth is by forming either external or internal cavities. Additionally, bandwidth reduction is possible without cavities when the signal and idler are counter-propagating, and the changes in the wave-vector with frequency are additive. To accomplish this a domain inversion on the wavelength scale is required. In this work, we experimentally demonstrate SPDC in one-dimensional KTP-based waveguides with sub-micron poling for forward and backward interactions. Some of the spectral features of the generated light are accounted for by mode coupling theory in periodically poled waveguides but other features are as yet not explained.

  3. Trace measurement of BrO at the ppt level by a transportable mode-locked frequency-doubled cavity-enhanced spectrometer

    NASA Astrophysics Data System (ADS)

    Grilli, R.; Méjean, G.; Kassi, S.; Ventrillard, I.; Abd-Alrahman, C.; Fasci, E.; Romanini, D.

    2012-04-01

    Pptv levels of BrO radical have been detected around 338.5-nm wavelength probing a rotationally structured A←X (7,0) electronic transition using mode-locked cavity-enhanced spectroscopy (ML-CEAS). The spectrometer is composed by a widely tunable, broadband frequency-doubled Ti:Sa mode-locked frequency comb laser injected into a high-finesse optical cavity and a high-resolution spectrometer based on a high-order diffraction grating and a high-sensitivity back-thinned CCD camera. A typical minimum detectable absorption coefficient of 1×10-9 cm-1 in 30 s of acquisition has been achieved, leading to a detection limit of 1.7 parts per trillion of BrO at atmospheric pressure. The compact and robust ultrasensitive broadband UV spectrometer is intended to be employed for in situ long-term direct measurements of BrO and other halogenated radicals, thus responding to the lack of analytical techniques to monitor the concentrations of such highly chemically reactive species.

  4. Incoherent broad-band cavity-enhanced absorption spectroscopy of the marine boundary layer species I2, IO and OIO.

    PubMed

    Vaughan, Stewart; Gherman, Titus; Ruth, Albert A; Orphal, Johannes

    2008-08-14

    The novel combination of incoherent broad-band cavity-enhanced absorption spectroscopy (IBBCEAS) and a discharge-flow tube for the study of three key atmospheric trace species, I(2), IO and OIO, is reported. Absorption measurements of I(2) and OIO at lambda=525-555 nm and IO at lambda=420-460 nm were made using a compact cavity-enhanced spectrometer employing a 150 W short-arc Xenon lamp. The use of a flow system allowed the monitoring of the chemically short-lived radical species IO and OIO to be conducted over timescales of several seconds. We report detection limits of approximately 26 pmol mol(-1) for I(2) (L=81 cm, acquisition time 60 s), approximately 45 pmol mol(-1) for OIO (L=42.5 cm, acquisition time 5 s) and approximately 210 pmol mol(-1) for IO (L=70 cm, acquisition time 60 s), demonstrating the usefulness of this approach for monitoring these important species in both laboratory studies and field campaigns.

  5. Improved efficiency for nanopillar array of c-Si photovoltaic by down-conversion and anti-reflection of quantum dots

    NASA Astrophysics Data System (ADS)

    Lin, Chien-chung; Chen, Hsin-Chu; Han, Hau-Vei; Tsai, Yu-Lin; Chang, Chia-Hua; Tsai, Min-An; Kuo, Hao-Chung; Yu, Peichen

    2012-02-01

    Improvement of efficiency for crystalline silicon (c-Si) with nanopillar arrays (NPAs) solar cell was demonstrated by deployment of CdS quantum dots (QDs). The NPAs was fabricated by colloidal lithography of self-assembled polystyrene (PS) nanospheres with a 600 nm in size and reactive-ion etching techniques, and then a colloidal CdS QDs with a concentration of 5 mg/mL was spun on the surface of c-Si with NPAs solar cell. Under a simulated one-sun condition, the device with CdS QDs shows a 33% improvement of power conversion efficiency, compared with the one without QDs. Additionally, we also found that the device with CdS QDs shows a 32% reduction in electrical resistance, compared with the one without QDs solar cell, under an ultraviolet (UV) light of 355nm illumination. This reduced electrical resistance can directly contribute to our fill-factor (FF) enhancement. For further investigation, the excitation spectrum of photoluminescence (PL), absorbance spectrum, current-voltage (I-V) characteristics, reflectance and external quantum efficiency (EQE) of the device were measured and analyzed. Based on the spectral response and optical measurement, we believe that CdS QDs not only have the capability for photon down-conversion in ultraviolet region, but also provide extra antireflection capability.

  6. Down-conversion phosphors as noble-metal-free co-catalyst in ZnO for efficient visible light photocatalysis

    NASA Astrophysics Data System (ADS)

    Chu, Haipeng; Liu, Xinjuan; Liu, Jiaqing; Lei, Wenyan; Li, Jinliang; Wu, Tianyang; Li, Ping; Li, Huili; Pan, Likun

    2017-01-01

    Exploring novel visible light responsive photocatalysts is one of greatly significant issues from the viewpoint of using solar energy. Here we report the yellow-orange emitting α-Si3N4-doped Lu3Al5O12:Ce3+ (Lu3Al5-xSixO12-xNx:Ce3+) phosphors as a noble-metal-free co-catalyst for enhanced visible light photocatalytic activity of ZnO. The results show that ZnO-Lu3Al5-xSixO12-xNx:Ce3+ hybrid photocatalysts using a fast microwave-assisted approach exhibits a 91% methylene blue (MB) degradation under visible light irradiation at 240 min, which evidence the synergistic effect of ZnO and Lu3Al5-xSixO12-xNx:Ce3+ that suppress the rate of charge recombination and increase the self-sensitized degradation of MB. ZnO-down conversion phosphors can be envisaged as potential candidate in environmental engineering and solar energy applications.

  7. Synthesis and down-conversion luminescence properties of Er3+/Yb3+ co-doped AlF3-PbF2-CaF2 powders

    NASA Astrophysics Data System (ADS)

    Liu, Fangchao; Han, Qun; Liu, Tiegen; Chen, Yaofei; Du, Yang; Yao, Yunzhi

    2015-08-01

    Er3+/Yb3+ co-doped oxy-fluoride powders with varying Er/Yb concentration were prepared by a melt quenching method at various sintering temperature. The effect of the Er/Yb doped concentration and sintering temperature were analyzed by using optical absorption and emission techniques. The Judd-Ofelt theory has been used to evaluate the three intensity parameters (Ωλ, where λ = 2, 4 and 6) and calculate the oscillator strengths (fc). Ultraviolet-to-visible emissions were observed under the excitation of a 325 nm CW laser. It was found that the down-conversion fluorescence intensity changes with the sintering temperature and Er/Yb content ratio, the results were explained with the level transitions in Er3+/Yb3+ co-doped systems. The intensity ratios (intensity of 437 nm as reference) of the luminescence spectra that the samples sintered at various temperature are relevant to Ω6 parameter which indicates the vibration amplitude of the Er-O distance. The sintering temperature also has an influence on the intensity ratios via affecting the thermalization of the excited 4I15/2 level.

  8. Theory of filtered type-II parametric down-conversion in the continuous-variable domain: Quantifying the impacts of filtering

    NASA Astrophysics Data System (ADS)

    Christ, Andreas; Lupo, Cosmo; Reichelt, Matthias; Meier, Torsten; Silberhorn, Christine

    2014-08-01

    Parametric down-conversion (PDC) forms one of the basic building blocks for quantum optical experiments. However, the intrinsic multimode spectral-temporal structure of pulsed PDC often poses a severe hindrance for the direct implementation of the heralding of pure single-photon states or, for example, continuous-variable entanglement distillation experiments. To get rid of multimode effects narrowband frequency filtering is frequently applied to achieve a single-mode behavior. A rigorous theoretical description to accurately describe the effects of filtering on PDC, however, is still missing. To date, the theoretical models of filtered PDC are rooted in the discrete-variable domain and only account for filtering in the low-gain regime, where only a few photon pairs are emitted at any single point in time. In this paper we extend these theoretical descriptions and put forward a simple model, which is able to accurately describe the effects of filtering on PDC in the continuous-variable domain. This developed straightforward theoretical framework enables us to accurately quantify the tradeoff between suppression of higher-order modes, reduced purity, and lowered Einstein-Podolsky-Rosen entanglement, when narrowband filters are applied to multimode type-II PDC.

  9. Double transverse wave-vector correlations in photon pairs generated by spontaneous parametric down-conversion pumped by Bessel-Gauss beams

    NASA Astrophysics Data System (ADS)

    Vicuña-Hernández, Verónica; Santiago, José T.; Jerónimo-Moreno, Yasser; Ramírez-Alarcón, Roberto; Cruz-Ramírez, Héctor; U'Ren, Alfred B.; Jáuregui-Renaud, Rocio

    2016-12-01

    We present an experimental and theoretical study of type I, frequency-degenerate spontaneous parametric down-conversion (SPDC) with a Bessel-Gauss pump in which we include both paraxial and nonparaxial pump beam configurations. We present measurements of the SPDC angular spectrum (AS), of the conditional angular spectrum (CAS) of signal-mode single photons as heralded by the detection of an idler photon, and of the transverse wave-vector signal-idler correlations (TWC). We show that as the pump is made increasingly nonparaxial, the AS acquires a nonconcentric double-cone structure, with the CAS shape depending on the azimuthal location of the heralding detector, while the signal-idler wave-vector correlation region splits into characteristic doublet stripes, representing as yet unexplored nontrivial, nonlocal quantum correlations between the signal and idler photons. Our work provides further understanding of SPDC with a particular class of structured pump beams, and we believe that the controlled presence of double wave-vector correlations represents an interesting resource for photon-pair quantum-state engineering.

  10. Improved Shock Tube Measurement of the CH4 + Ar = CH3 + H + Ar Rate Constant using UV Cavity-Enhanced Absorption Spectroscopy of CH3.

    PubMed

    Wang, Shengkai; Davidson, David F; Hanson, Ronald K

    2016-07-21

    We report an improved measurement for the rate constant of methane dissociation in argon (CH4 + Ar = CH3 + H + Ar) behind reflected shock waves. The experiment was conducted using a sub-parts per million sensitivity CH3 diagnostic recently developed in our laboratory based on ultraviolet cavity-enhanced absorption spectroscopy. The high sensitivity of this diagnostic allowed for measurements of quantitatively resolved CH3 time histories during the initial stage of CH4 pyrolysis, where the reaction system is clean and free from influences of secondary reactions and temperature change. This high sensitivity also allowed extension of our measurement range to much lower temperatures (<1500 K). The current-reflected shock measurements were performed at temperatures between 1487 and 1866 K and pressures near 1.7 atm, resulting in the following Arrhenius rate constant expression for the title reaction: k(1.7 atm) = 3.7 × 10(16) exp(-42 200 K/T) cm(3)/mol·s, with a 2σ uncertainty factor of 1.25. The current data are in good consensus with various theoretical and review studies, but at the low temperature end they suggest a slightly higher (up to 35%) rate constant compared to these previous results. A re-evaluation of previous and current experimental data in the falloff region was also performed, yielding updated expressions for both the low-pressure limit and the high-pressure limit rate constants and improved agreement with all existing data.

  11. Bromine Explosions In Smog Chamber Experiments: A comparison of Cavity-Enhanced (CE) and White-cell DOAS

    NASA Astrophysics Data System (ADS)

    Buxmann, J.; Hoch, D. J.; Sihler, H.; Pöhler, D.; Platt, U.; Bleicher, S.; Balzer, N.; Zetzsch, C.

    2011-12-01

    Reactive halogen species (RHS), such as Cl, Br or BrO, can significantly influence chemical processes in the troposphere, including the destruction of ozone, change in the chemical balance of hydrogen radicals (OH, HO2), increased deposition of toxic compounds (like mercury) with potential consequences for the global climate. Previous studies have shown that salt lakes can be significant sources for gaseous RHS. Environmental conditions such as salt composition, relative humidity (RH), pH, and temperature (T) can strongly influence reactive bromine levels, but are difficult to quantify in the field. Therefore, we conducted laboratory experiments by exposing NaCl salt containing 0.33% (by weight) NaBr to simulated sunlight in a Teflon smog-chamber under various conditions of RH and ozone concentrations. BrO levels were observed by a Differential-Optical-Absorption-Spectrometer (DOAS) in combination with a multi-reflection cell (White-cell). The concentrations of OH- and Cl- radicals were quantified by the radical clock method. We present the first direct observation of BrO from the "Bromine Explosion" (auto catalytic release of reactive bromine from salt surfaces - key to ozone destruction) in the laboratory above a simulated salt pan. The maximum BrO mixing ratio of 6419±71 ppt at 60% RH was observed to be one order of magnitude higher than at 37% RH and 2% RH. The release of RHS from the salt pan is possibly controlled by the thickness of the quasi liquid layer, covering the reactive surface of the halide crystals, as the layer thickness strongly depends on RH. Furthermore, a new cavity enhanced DOAS (CE-DOAS) instrument was designed and successfully used in chamber experiments. For the first time, such an instrument uses a spectral interval in the UV - wavelength range (325-365 nm) to identify BrO. We show a comparison of the CE-DOAS and White-cell DOAS instrument in a series of experiments, where e.g. a peak BrO mixing ratio up to 380 ppt within the first

  12. Comparison of optical-feedback cavity-enhanced absorption spectroscopy and gas chromatography for ground-based and airborne measurements of atmospheric CO concentration

    NASA Astrophysics Data System (ADS)

    Ventrillard, Irène; Xueref-Remy, Irène; Schmidt, Martina; Yver Kwok, Camille; Faïn, Xavier; Romanini, Daniele

    2017-05-01

    We present the first comparison of carbon monoxide (CO) measurements performed with a portable laser spectrometer that exploits the optical-feedback cavity-enhanced absorption spectroscopy (OF-CEAS) technique, against a high-performance automated gas chromatograph (GC) with a mercuric oxide reduction gas detector (RGD). First, measurements of atmospheric CO mole fraction were continuously collected in a Paris (France) suburb over 1 week. Both instruments showed an excellent agreement within typically 2 ppb (part per billion in volume), fulfilling the World Meteorological Organization (WMO) recommendation for CO inter-laboratory comparison. The compact size and robustness of the OF-CEAS instrument allowed its operation aboard a small aircraft employed for routine tropospheric air analysis over the French Orléans forest area. Direct OF-CEAS real-time CO measurements in tropospheric air were then compared with later analysis of flask samples by the gas chromatograph. Again, a very good agreement was observed. This work establishes that the OF-CEAS laser spectrometer can run unattended at a very high level of sensitivity ( < 1 ppb) and stability without any periodic calibration.

  13. Sub-Doppler resolution near-infrared spectroscopy at 128 μm with the noise-immune cavity-enhanced optical heterodyne molecular spectroscopy method

    NASA Astrophysics Data System (ADS)

    Chen, Tzu-Ling; Liu, Yi-Wei

    2017-07-01

    We report on the Doppler-free saturation spectroscopy of the nitrous oxide (N$_2$O) overtone transition at 1.28~$\\mu$m. This measurement is performed by the noise-immune cavity-enhanced optical heterodyne molecular spectroscopy (NICE-OHMS) technique based on the quantum-dot (QD) laser. A high intra-cavity power, up to 10~W, reaches the saturation limit of the overtone line using an optical cavity with a high finesse of 113,500. At a pressure of several mTorr, the saturation dip is observed with a full width at half-maximum of about 2~MHz and a signal-to-noise ratio of 71. To the best of our knowledge, this is the first saturation spectroscopy of molecular overtone transitions in 1.3~$\\mu$m region. The QD laser is then locked to this dispersion signal with a stability of 15 kHz at 1 sec integration time. We demonstrate the potential of the N$_2$O as markers because of its particularly rich spectrum at the vicinity of 1.28-1.30 $\\mu$m where lies several important forbidden transitions of atomic parity violation measurements and the 1.3 $\\mu$m O-band of optical communication.

  14. An off Axis Cavity Enhanced Absorption Spectrometer and a Rapid Scan Spectrometer with a Room-Temperature External Cavity Quantum Cascade Laser

    NASA Astrophysics Data System (ADS)

    Liu, Xunchen; Kang, Cheolhwa; Xu, Yunjie

    2009-06-01

    Quantum cascade laser (QCL) is a new type of mid-infrared tunable diode lasers with superior output power and mode quality. Recent developments, such as room temperature operation, wide frequency tunability, and narrow line width, make QCLs an ideal light source for high resolution spectroscopy. Two slit jet infrared spectrometers, namely an off-axis cavity enhanced absorption (CEA) spectrometer and a rapid scan spectrometer with an astigmatic multi-pass cell assembly, have been coupled with a newly purchased room temperature tunable mod-hop-free QCL with a frequency coverage from 1592 cm^{-1} to 1698 cm^{-1} and a scan rate of 0.1 cm^{-1}/ms. Our aim is to utilize these two sensitive spectrometers, that are equipped with a molecular jet expansion, to investigate the chiral molecules-(water)_n clusters. To demonstrate the resolution and sensitivity achieved, the rovibrational transitions of the static N_2O gas and the bending rovibrational transitions of the Ar-water complex, a test system, at 1634 cm^{-1} have been measured. D. Hofstetter and J. Faist in High performance quantum cascade lasers and their applications, Vol.89 Springer-Verlag Berlin & Heidelberg, 2003, pp. 61-98. Y. Xu, X. Liu, Z. Su, R. M. Kulkarni, W. S. Tam, C. Kang, I. Leonov and L. D'Agostino, Proc. Spie, 2009, 722208 (1-11). M. J. Weida and D. J. Nesbitt, J. Chem. Phys. 1997, 106, 3078-3089.

  15. Looking into the volcano with a Mid-IR DFB diode laser and Cavity Enhanced Absorption Spectroscopy.

    PubMed

    Kassi, S; Chenevier, M; Gianfrani, L; Salhi, A; Rouillard, Y; Ouvrard, A; Romanini, D

    2006-11-13

    We report on the first application of extended-wavelength DFB diode lasers to Cavity-Enhanced Absorption Spectroscopy in-situ trace measurements on geothermal gases. The emission from the most active fumarole at the Solfatara volcano near Naples (Italy) was probed for the presence of CO and CH(4). After passing through a gas dryer and cooler, the volcanic gas flow (98% CO(2)) was analysed in real time for the concentration of these species, whose relatively strong absorption lines could be monitored simultaneously by a single Distributed Feed-Back (DFB) GaSb-based diode laser emitting around 2.33 mum (4300 cm(-1)) at room temperature. The concentrations were found to be about 3 ppm and 75 ppm, respectively, while actual detection limits for these molecules are around 1 ppb. We discuss the possibility of detecting other species of interest for volcanic emission monitoring.

  16. A broadband cavity-enhanced spectrometer for measuring the extinction of aerosols at blue and near-UV wavelengths

    NASA Astrophysics Data System (ADS)

    Venables, Dean; Fullam, Donovan; Hoa Le, Phuoc; Chen, Jun; Böge, Olaf; Herrmann, Hartmut

    2016-04-01

    We describe a new broadband cavity-enhanced absorption spectrometer for sensitive extinction measurements of aerosols. The instrument is distinguished by its broad and continuous spectral coverage from the near-UV to blue wavelengths (ca. 320 to 450 nm). The short wavelength region has been little explored compared to visible wavelengths, but is important because (1) brown carbon (BrC) absorbs strongly in this wavelength region, and (2) absorption of near-UV radiation in the atmosphere alters the photolysis rate of the key atmospheric species O3, NO2, and HONO, with implications for air quality and atmospheric oxidation capacity. The instrument performance and the effect of a switchable in-line filter are characterised. Early results using the instrument in the TROPOS atmospheric simulation chamber are presented. These experiments include studies of secondary organic aerosol formation (SOA), and biomass burning experiments of rice and wheat straw, followed by experiments simulating particle aging under daytime and nighttime conditions.

  17. Noise-immune cavity-enhanced optical heterodyne detection of HO2 in the near-infrared range.

    PubMed

    Bell, Claire L; van Helden, Jean-Pierre H; Blaikie, Tom P J; Hancock, Gus; van Leeuwen, Nicola J; Peverall, Robert; Ritchie, Grant A D

    2012-05-31

    Accurate measurements of the absolute concentrations of radical species present in the atmosphere are invaluable for better understanding atmospheric processes and their impact on Earth systems. One of the most interesting species is HO(2), the hydroperoxyl radical, whose atmospheric daytime levels are on the order of 10 ppt and whose observation therefore requires very sensitive detection techniques. In this work, we demonstrate the first steps toward the application of external-cavity diode-laser-based noise-immune cavity-enhanced optical heterodyne molecular spectroscopy (NICE-OHMS) to the detection of the HO(2) radical in the near-infrared range. Measurements of stable species and of HO(2) were made in a laboratory setting, and the possibilities of extending the sensitivity of the technique to atmospheric conditions are discussed.

  18. Detection of HO2 in an atmospheric pressure plasma jet using optical feedback cavity-enhanced absorption spectroscopy

    NASA Astrophysics Data System (ADS)

    Gianella, Michele; Reuter, Stephan; Lawry Aguila, Ana; Ritchie, Grant A. D.; van Helden, Jean-Pierre H.

    2016-11-01

    Cold non-equilibrium atmospheric pressure plasma jets are increasingly applied in material processing and plasma medicine. However, their small dimensions make diagnosing the fluxes of generated species a challenge. Here we report on the detection of the hydroperoxyl radical, HO2, in the effluent of a plasma jet by the use of optical feedback cavity-enhanced absorption spectroscopy. The spectrometer has a minimum detectable absorption coefficient {α }\\min of 2.25× {10}-10 cm-1 with a 100 second acquisition, equivalent to 5.5× {10}12 {{cm}}-3 of HO2 (under ideal conditions). Concentrations in the range of (3.1-7.8) × 1013 cm-3 were inferred in the 4 mm wide effluent of the plasma jet.

  19. Influence of the cavity parameters on the output intensity in incoherent broadband cavity-enhanced absorption spectroscopy.

    PubMed

    Fiedler, Sven E; Hese, Achim; Heitmann, Uwe

    2007-07-01

    The incoherent broadband cavity-enhanced absorption spectroscopy is a technique in measuring small absorptions over a broad wavelength range. The setup consists of a conventional absorption spectrometer using an incoherent lamp and a charge coupled device detector, as well as a linear optical cavity placed around the absorbing sample, which enhances the effective path length through the sample. In this work the consequences of cavity length, mirror curvature, reflectivity, different light injection geometries, and spot size of the light source on the output intensity are studied and the implications to the signal-to-noise ratio of the absorption measurement are discussed. The symmetric confocal resonator configuration is identified as a special case with optimum imaging characteristics but with higher requirements for mechanical stability. Larger spot sizes of the light source were found to be favorable in order to reduce the negative effects of aberrations on the intensity.

  20. Part per trillion nitric oxide measurement by optical feedback cavity-enhanced absorption spectroscopy in the mid-infrared

    NASA Astrophysics Data System (ADS)

    Ventrillard, Irène; Gorrotxategi-Carbajo, Paula; Romanini, Daniele

    2017-06-01

    While nitric oxide (NO) is being monitored in various fields of application, there is still a lack of available instruments at a sub-ppb level of sensitivity. We report on the first application of Optical Feedback Cavity-Enhanced Absorption Spectroscopy (OF-CEAS) to NO trace gas analysis, with a room-temperature quantum-cascade laser at 5.26 µm (1900.5 cm^{-1}). A detection limit of 60 ppt is reached in a single measurement performed in 140 ms. The stability of the instrument allows to average for 10 s down to 8.3 ppt, limited by drift of etalon fringes in the spectra. This work opens the path towards new applications notably in breath analysis and environment sciences.

  1. Trace species detection in the near infrared using Fourier transform broadband cavity enhanced absorption spectroscopy: initial studies on potential breath analytes.

    PubMed

    Denzer, W; Hancock, G; Islam, M; Langley, C E; Peverall, R; Ritchie, G A D; Taylor, D

    2011-02-21

    Cavity enhanced absorption measurements have been made of several species that absorb light between 1.5 and 1.7 µm using both a supercontinuum source and superluminescent light emitting diodes. A system based upon an optical enhancement cavity of relatively high finesse, consisting of mirrors of reflectivity ∼99.98%, and a Fourier transform spectrometer, is demonstrated. Spectra are recorded of isoprene, butadiene, acetone and methane, highlighting problems with spectral interference and unambiguous concentration determinations. Initial results are presented of acetone within a breath-like matrix indicating ppm precision at <∼10 ppm acetone levels. Instrument sensitivities are sufficiently enhanced to enable the detection of atmospheric levels of methane. Higher detection sensitivities are achieved using the supercontinuum source, with a minimum detectable absorption coefficient of ∼4 × 10(-9) cm(-1) reported within a 4 min acquisition time. Finally, two superluminescent light emitting diodes are coupled together to increase the wavelength coverage, and measurements are made simultaneously on acetylene, CO(2), and butadiene. The absorption cross-sections for acetone and isoprene have been measured with an instrumental resolution of 4 cm(-1) and are found to be 1.3 ± 0.1 × 10(-21) cm(2) at a wavelength of 1671.9 nm and 3.6 ± 0.2 × 10(-21) cm(2) at 1624.7 nm, respectively.

  2. Application of Cavity Enhanced Absorption Spectroscopy to the Detection of Nitric Oxide, Carbonyl Sulphide, and Ethane--Breath Biomarkers of Serious Diseases.

    PubMed

    Wojtas, Jacek

    2015-06-17

    The paper presents one of the laser absorption spectroscopy techniques as an effective tool for sensitive analysis of trace gas species in human breath. Characterization of nitric oxide, carbonyl sulphide and ethane, and the selection of their absorption lines are described. Experiments with some biomarkers showed that detection of pathogenic changes at the molecular level is possible using this technique. Thanks to cavity enhanced spectroscopy application, detection limits at the ppb-level and short measurements time (<3 s) were achieved. Absorption lines of reference samples of the selected volatile biomarkers were probed using a distributed feedback quantum cascade laser and a tunable laser system consisting of an optical parametric oscillator and difference frequency generator. Setup using the first source provided a detection limit of 30 ppb for nitric oxide and 250 ppb for carbonyl sulphide. During experiments employing a second laser, detection limits of 0.9 ppb and 0.3 ppb were obtained for carbonyl sulphide and ethane, respectively. The conducted experiments show that this type of diagnosis would significantly increase chances for effective therapy of some diseases. Additionally, it offers non-invasive and real time measurements, high sensitivity and selectivity as well as minimizing discomfort for patients. For that reason, such sensors can be used in screening for early detection of serious diseases.

  3. Validation and application of cavity-enhanced, near-infrared tunable diode laser absorption spectrometry for measurements of methane carbon isotopes at ambient concentrations.

    PubMed

    Mortazavi, Behzad; Wilson, Benjamin J; Dong, Feng; Gupta, Manish; Baer, Doug

    2013-10-15

    Methane is an effective greenhouse gas but has a short residence time in the atmosphere, and therefore, reductions in emissions can alleviate its greenhouse gas warming effect within a decadal time frame. Continuous and high temporal resolution measurements of methane concentrations and carbon isotopic ratios (δ(13)CH4) can inform on mechanisms of formation, provide constraints on emissions sources, and guide future mitigation efforts. We describe the development, validation, and deployment of a cavity-enhanced, near-infrared tunable diode laser absorption spectrometry system capable of quantifying δ(13)CH4 at ambient methane concentrations. Laboratory validation and testing show that the instrument is capable of operating over a wide dynamic range of methane concentration and provides a measurement precision for δ(13)CH4 of better than ± 0.5 ‰ (1σ) over 1000 s of data averaging at ambient methane concentrations. The analyzer is accurate to better than ± 0.5 ‰, as demonstrated by measurements of characterized methane/air samples with minimal dependence (<1 ‰) of measured carbon isotope ratio on methane concentration. Deployment of the instrument at a marsh over multiple days demonstrated how methane fluxes varied by an order of magnitude over 2 day deployment periods, and showed a 17 ‰ variability in δ(13)CH4 of the emitted methane during the growing season.

  4. Development and deployment of a cavity enhanced UV-LED spectrometer for measurements of atmospheric HONO and NO2 in Hong Kong

    NASA Astrophysics Data System (ADS)

    Wu, Tao; Zha, Qiaozhi; Chen, Weidong; Xu, Zheng; Wang, Tao; He, Xingdao

    2014-10-01

    An optical analytical instrument based on light emitting diode (LED) incoherent broadband cavity enhanced absorption spectroscopy (LED-IBBCEAS) was developed for simultaneous measurements of HONO and NO2 in ambient air. Detection limits (for signal-to-noise ratio, SNR = 2) of 0.6 ppbv for HONO and 2 ppbv for NO2 were achieved with an optimum acquisition time of 120 s. Field intercomparison campaign at a suburban site of Tung Chung in Hong Kong was carried out. Daytime and nighttime concentrations of HONO and NO2 were recorded and compared with data from a long path absorption photometer (LOPAP) and a NOx analyzer equipped with a blue light converter. The test of such a LED-IBBCEAS setup by the measurement intercomparison with the well established HONO and NO2 measurement instruments, for the first time, in a real atmospheric environment, demonstrated the feasibility of the proposed technique for the measurement of environmental HONO and NO2 concentrations in a manner that is free of chemical and spectral interference. During the measurement period from 12:32 on May 12th to 12:32 on May 14th, 2012, the quantitative assessments from these techniques showed well agreed data. High temporal correlations of HONO with NOx and CO were observed, and possible formation sources of HONO are discussed. Occasional inconsistencies in the quantitative assessment of HONO were observed during the in-field campaign. The problems encountered by the IBBCEAS technique applied to field observation and the further improvements are discussed.

  5. Dilute nitride resonant cavity enhanced photodetector with internal gain for the λ ∼ 1.3 μm optical communications window

    NASA Astrophysics Data System (ADS)

    Balkan, N.; Erol, A.; Sarcan, F.; Al-Ghuraibawi, L. F. F.; Nordin, M. S.

    2015-10-01

    We report on a novel dilute nitride-based resonant cavity enhanced photodetector (RCEPD) operating at 1.286 μm. The RCEPD was fabricated using 21 pairs top and 24 pairs bottom GaAs/AlGaAs distributed Bragg reflectors for mirrors and 7 nm thick nine GaAs/Ga0.65In0.35N0.02 As0.98 quantum wells as the absorption region. For a 15 μm diameter window, the photocurrent at 1.286 μm is 27 μA and 42 μA, at V = 0 and -1 V, respectively, whereas the dark current is as low as 1.7 nA at -1 V. At the operating wavelength, an excellent wavelength selectivity with a full width at half maximum (FWHM) of 5 nm, and a high quantum efficiency of 43% are demonstrated. The device exhibits significant internal gain at very small reverse bias voltages of V ⩾ -2 V with an overall quantum efficiency of 67%. These are the best ever recorded values for a dilute nitride RCEPD.

  6. Application of Cavity Enhanced Absorption Spectroscopy to the Detection of Nitric Oxide, Carbonyl Sulphide, and Ethane—Breath Biomarkers of Serious Diseases

    PubMed Central

    Wojtas, Jacek

    2015-01-01

    The paper presents one of the laser absorption spectroscopy techniques as an effective tool for sensitive analysis of trace gas species in human breath. Characterization of nitric oxide, carbonyl sulphide and ethane, and the selection of their absorption lines are described. Experiments with some biomarkers showed that detection of pathogenic changes at the molecular level is possible using this technique. Thanks to cavity enhanced spectroscopy application, detection limits at the ppb-level and short measurements time (<3 s) were achieved. Absorption lines of reference samples of the selected volatile biomarkers were probed using a distributed feedback quantum cascade laser and a tunable laser system consisting of an optical parametric oscillator and difference frequency generator. Setup using the first source provided a detection limit of 30 ppb for nitric oxide and 250 ppb for carbonyl sulphide. During experiments employing a second laser, detection limits of 0.9 ppb and 0.3 ppb were obtained for carbonyl sulphide and ethane, respectively. The conducted experiments show that this type of diagnosis would significantly increase chances for effective therapy of some diseases. Additionally, it offers non-invasive and real time measurements, high sensitivity and selectivity as well as minimizing discomfort for patients. For that reason, such sensors can be used in screening for early detection of serious diseases. PMID:26091398

  7. Core-shell-like Y2O3:[(Tb3+-Yb3+), Li+]/CdZnS heterostructure synthesized by super-close-space sublimation for broadband down-conversion

    NASA Astrophysics Data System (ADS)

    Wu, Xiaojie; Zhang, Zhenzhong; Meng, Fanzhi; Yu, Yingning; Han, Lin; Liu, Xiaojuan; Meng, Jian

    2014-04-01

    Combination with semiconductors is a promising approach to the realization of broadband excitation of light conversion materials based on rare earth compounds, to boost the energy efficiency of silicon solar cells. Cd1-xZnxS is a wide bandgap semiconductor with large exciton binding energy. By changing its composition, the bandgap of Cd1-xZnxS can be tuned to match the absorption of trivalent lanthanide (Ln) ions, which makes it a competent energy donor for the Ln3+-Yb3+ couple. In this work, we designed a clean route to a broadband down-converter based on a core-shell-like Y2O3:[(Tb3+-Yb3+), Li+]/Cd0.81Zn0.19S (CdZnS) heterostructure. By hot-pressing and subsequent annealing of a Y2O3:[(Tb3+-Yb3+), Li+]/CdZnS mixture, highly pure CdZnS was sublimated and deposited on the Y2O3:[(Tb3+-Yb3+), Li+] grains while maintaining the original composition of the precursor. The CdZnS shell acted as a light absorber and energy donor for the Tb3+-Yb3+ quantum cutting couple. Because the use of solvents was avoided during the formation of the heterostructures, few impurities were incorporated into the samples, and the non-radiative transition was therefore markedly suppressed. The Y2O3:[(Tb3+-Yb3+), Li+]/CdZnS heterostructures possess strong near-infrared (NIR) luminescence from Yb3+. Broadband down-conversion to the Yb3+ NIR emission was obtained in a wide range of 250-650 nm.

  8. Core-shell-like Y2O3:[(Tb3+-Yb3+), Li+]/CdZnS heterostructure synthesized by super-close-space sublimation for broadband down-conversion.

    PubMed

    Wu, Xiaojie; Zhang, Zhenzhong; Meng, Fanzhi; Yu, Yingning; Han, Lin; Liu, Xiaojuan; Meng, Jian

    2014-05-07

    Combination with semiconductors is a promising approach to the realization of broadband excitation of light conversion materials based on rare earth compounds, to boost the energy efficiency of silicon solar cells. Cd(1-x)Zn(x)S is a wide bandgap semiconductor with large exciton binding energy. By changing its composition, the bandgap of Cd(1-x)Zn(x)S can be tuned to match the absorption of trivalent lanthanide (Ln) ions, which makes it a competent energy donor for the Ln(3+)-Yb(3+) couple. In this work, we designed a clean route to a broadband down-converter based on a core-shell-like Y2O3:[(Tb(3+)-Yb(3+)), Li(+)]/Cd0.81Zn0.19S (CdZnS) heterostructure. By hot-pressing and subsequent annealing of a Y2O3:[(Tb(3+)-Yb(3+)), Li(+)]/CdZnS mixture, highly pure CdZnS was sublimated and deposited on the Y2O3:[(Tb(3+)-Yb(3+)), Li(+)] grains while maintaining the original composition of the precursor. The CdZnS shell acted as a light absorber and energy donor for the Tb(3+)-Yb(3+) quantum cutting couple. Because the use of solvents was avoided during the formation of the heterostructures, few impurities were incorporated into the samples, and the non-radiative transition was therefore markedly suppressed. The Y2O3:[(Tb(3+)-Yb(3+)), Li(+)]/CdZnS heterostructures possess strong near-infrared (NIR) luminescence from Yb(3+). Broadband down-conversion to the Yb(3+) NIR emission was obtained in a wide range of 250-650 nm.

  9. SPECIES: a multi-channel infrared laser spectrometer with optical-feedback cavity-enhanced absorption for in-situ balloon-borne and airborne measurements

    NASA Astrophysics Data System (ADS)

    Jacquet, Patrick; Catoire, Valery; Chartier, Michel; Robert, Claude; Krysztofiak, Gisele; Huret, Nathalie; Romanini, Daniele

    2017-04-01

    Over the last decades, thanks to significant technological advances in measurement techniques, our understanding of the chemistry and dynamics of the upper troposphere and stratosphere has progressed significantly. However some key questions remain unsolved and new ones arise in the climate change context. The full recovery of the ozone layer in a period of halogens decrease and N2O increase (and the delay of this recovery), the impact of the climate change on the stratosphere and the role of this one as a feedback are very uncertain. To address these challenges, one needs instruments able to measure a wide variety of trace gases simultaneously with a wide vertical range, combined to chemical and dynamical modelling at different scales. LPC2E and LIPHY laboratories are developing a new balloon-borne and airborne instrument: SPECIES (SPECtromètre Infrarouge à lasErs in Situ). Based on the Optical Feedback Cavity Enhanced Spectroscopy (OF-CEAS) technique combined with mid-infrared quantum or interband cascade lasers (QCLs or ICLs), this instrument will offer unprecedented performances in terms of vertical extent of the measurements, from ground to the middle stratosphere, and number of molecular species simultaneously measured with sub-ppb detection limits (e.g. O3, N2O, HNO3, NH3, H2O2, HCl, HOCl,CF2O, CH4, CH2O, CO, CO2, OCS, SO2). Due to high frequency measurement (>0.5 Hz) it shall offer very high spatial resolution (a few meters).

  10. Rapid, online quantification of H2S in JP-8 fuel reformate using near-infrared cavity-enhanced laser absorption spectroscopy.

    PubMed

    Dong, Feng; Junaedi, Christian; Roychoudhury, Subir; Gupta, Manish

    2011-06-01

    One of the key challenges in reforming military fuels for use with fuel cells is their high sulfur content, which can poison the fuel cell anodes. Sulfur-tolerant fuel reformers can convert this sulfur into H(2)S and then use a desulfurizing bed to remove it prior to the fuel cell. In order to optimize and verify this desulfurization process, a gas-phase sulfur analyzer is required to measure H(2)S at low concentrations (<1 ppm(v)) in the presence of other reforming gases (e.g., 25-30% H(2), 10-15% H(2)O, 15% CO, 5% CO(2), 35-40% N(2), and trace amounts of light hydrocarbons). In this work, we utilize near-infrared cavity-enhanced optical absorption spectroscopy (off-axis ICOS) to quantify H(2)S in a JP-8 fuel reformer product stream. The sensor provides rapid (2 s), highly precise (±0.1 ppm(v)) measurements of H(2)S in reformate gases over a wide dynamic range (0-1000 ppm(v)) with a low detection limit (3σ = ±0.09 ppm(v) in 1 s) and minimal cross-interferences from other present species. It simultaneously quantifies CO(2) (±0.2%), CH(4) (±150 ppm(v)), C(2)H(4) (±30 ppm(v)), and H(2)O (±300 ppm(v)) in the reformed gas for a better characterization of the fuel reforming process. Other potential applications of this technology include measurement of coal syngas and H(2)S in natural gas. By including additional near-infrared, distributive feedback diode lasers, the instrument can also be extended to other reformate species, including CO and H(2).

  11. Magnetically Induced Optical Transparency on a Forbidden Transition in Strontium for Cavity-Enhanced Spectroscopy

    NASA Astrophysics Data System (ADS)

    Winchester, Matthew N.; Norcia, Matthew A.; Cline, Julia R. K.; Thompson, James K.

    2017-06-01

    In this Letter we realize a narrow spectroscopic feature using a technique that we refer to as magnetically induced optical transparency. A cold ensemble of 88Sr atoms interacts with a single mode of a high-finesse optical cavity via the 7.5 kHz linewidth, spin forbidden 1S0 to 3P1 transition. By applying a magnetic field that shifts two excited state Zeeman levels, we open a transmission window through the cavity where the collective vacuum Rabi splitting due to a single level would create destructive interference for probe transmission. The spectroscopic feature approaches the atomic transition linewidth, which is much narrower than the cavity linewidth, and is highly immune to the reference cavity length fluctuations that limit current state-of-the-art laser frequency stability.

  12. Performance scaling via passive pulse shaping in cavity-enhanced optical parametric chirped-pulse amplification.

    PubMed

    Siddiqui, Aleem M; Moses, Jeffrey; Hong, Kyung-Han; Lai, Chien-Jen; Kärtner, Franz X

    2010-06-15

    We show that an enhancement cavity seeded at the full repetition rate of the pump laser can automatically reshape small-signal gain across the interacting pulses in an optical parametric chirped-pulse amplifier for close-to-optimal operation, significantly increasing both the gain bandwidth and the conversion efficiency, in addition to boosting gain for high-repetition-rate amplification. Applied to a degenerate amplifier, the technique can provide an octave-spanning gain bandwidth.

  13. Interfacing Whispering-Gallery Microresonators and Free Space Light With Cavity Enhanced Rayleigh Scattering

    DTIC Science & Technology

    2014-09-17

    requires optical and mechanical systems with high angular and translational resolution. These unavoidably make the system bulky and difficult to move out...setup used in the experiments is depicted in Fig. 1b. It consists of a tunable external cavity laser and a fiber lens as the free-space light source...performance of the nanocoupler. Light from a tunable laser is sent through a fiber lens and incident onto the resonator. The distance between the

  14. Cavity-enhanced overtone spectroscopy of methanol in aprotic solvents: probing solute-solvent interactions and self-associative behavior.

    PubMed

    Kuen, Da-Sol; Feierabend, Karl J

    2014-04-24

    Methanol in aprotic solvents can serve as a case study for self-association via hydrogen-bonding, which is an important process in many biological and environmental systems. Incoherent broadband cavity-enhanced absorption spectroscopy (IBBCEAS), which provides enhanced sensitivity relative to conventional single-pass absorption techniques, has been used to characterize the third "free" O-H stretching overtone of methanol in four aprotic solvents (CCl4, CHCl3, CH2Cl2, and C6H6), including the transition wavenumber, bandwidth, and molar absorptivity. The absorption band characteristics indicate an increasing degree of nonspecific methanol-solvent interaction with increasing solvent dielectric constant, except in the case of benzene, which shows evidence of a specific, H-π interaction. Density functional theory with the polarizable continuum model was used to complement the results by assessing the accuracy of computational methods for calculating anharmonic O-H stretching frequencies. Finally, the self-association of methanol in these solvents at 298 K was also investigated using the concentration dependence of the overtone absorption intensity. The propensity for methanol's self-association in the solvents studied increases in the order: CH2Cl2 ∼ CHCl3 < C6H6 < CCl4.

  15. Microbial respiration and natural attenuation of benzene contaminated soils investigated by cavity enhanced Raman multi-gas spectroscopy.

    PubMed

    Jochum, Tobias; Michalzik, Beate; Bachmann, Anne; Popp, Jürgen; Frosch, Torsten

    2015-05-07

    Soil and groundwater contamination with benzene can cause serious environmental damage. However, many soil microorganisms are capable to adapt and are known to strongly control the fate of organic contamination. Innovative cavity enhanced Raman multi-gas spectroscopy (CERS) was applied to investigate the short-term response of the soil micro-flora to sudden surface contamination with benzene regarding the temporal variations of gas products and their exchange rates with the adjacent atmosphere. (13)C-labeled benzene was spiked on a silty-loamy soil column in order to track and separate the changes in heterotrophic soil respiration - involving (12)CO2 and O2- from the natural attenuation process of benzene degradation to ultimately form (13)CO2. The respiratory quotient (RQ) decreased from a value 0.98 to 0.46 directly after the spiking and increased again within 33 hours to a value of 0.72. This coincided with the maximum (13)CO2 concentration rate (0.63 μmol m(-2) s(-1)), indicating the highest benzene degradation at 33 hours after the spiking event. The diffusion of benzene in the headspace and the biodegradation into (13)CO2 were simultaneously monitored and 12 days after the benzene spiking no measurable degradation was detected anymore. The RQ finally returned to a value of 0.96 demonstrating the reestablished aerobic respiration.

  16. Optical feedback cavity-enhanced absorption spectroscopy with a 3.24 μm interband cascade laser

    SciTech Connect

    Manfred, K. M.; Ritchie, G. A. D.; Lang, N.; Röpcke, J.; Helden, J. H. van

    2015-06-01

    The development of interband cascade lasers (ICLs) has made the strong C-H transitions in the 3 μm spectral region increasingly accessible. We present the demonstration of a single mode distributed feedback ICL coupled to a V-shaped optical cavity in an optical feedback cavity-enhanced absorption spectroscopy (OF-CEAS) experiment. We achieved a minimum detectable absorption coefficient, α{sub min}, of (7.1±0.2)×10{sup −8} cm{sup −1} for a spectrum of CH{sub 4} at 3.24 μm with a two second acquisition time (100 scans averaged). This corresponds to a detection limit of 3 ppb CH{sub 4} at atmospheric pressure, which is comparable to previously reported OF-CEAS instruments with diode lasers or quantum cascade lasers. The ability to frequency lock an ICL source in the important 3 μm region to an optical cavity holds great promise for future spectroscopic applications.

  17. Airway extraction from 3D chest CT volumes based on iterative extension of VOI enhanced by cavity enhancement filter

    NASA Astrophysics Data System (ADS)

    Meng, Qier; Kitasaka, Takayuki; Oda, Masahiro; Mori, Kensaku

    2017-03-01

    Airway segmentation is an important step in analyzing chest CT volumes for computerized lung cancer detection, emphysema diagnosis, asthma diagnosis, and pre- and intra-operative bronchoscope navigation. However, obtaining an integrated 3-D airway tree structure from a CT volume is a quite challenging task. This paper presents a novel airway segmentation method based on intensity structure analysis and bronchi shape structure analysis in volume of interest (VOI). This method segments the bronchial regions by applying the cavity enhancement filter (CEF) to trace the bronchial tree structure from the trachea. It uses the CEF in each VOI to segment each branch and to predict the positions of VOIs which envelope the bronchial regions in next level. At the same time, a leakage detection is performed to avoid the leakage by analysing the pixel information and the shape information of airway candidate regions extracted in the VOI. Bronchial regions are finally obtained by unifying the extracted airway regions. The experiments results showed that the proposed method can extract most of the bronchial region in each VOI and led good results of the airway segmentation.

  18. RF noise induced laser perturbation for improving the performance of non-resonant cavity enhanced absorption spectroscopy.

    PubMed

    Ciaffoni, Luca; Couper, John; Hancock, Gus; Peverall, Robert; Robbins, Peter A; Ritchie, Grant A D

    2014-07-14

    We present a novel strategy for suppressing mode structure which often degrades off-axis cavity enhanced absorption spectra. This strategy relies on promoting small, random fluctuations in the optical frequency by perturbing the injection current of the diode laser source with radio frequency (RF) bandwidth-limited white noise. A fast and compact oxygen sensor, constructed from a 764 nm vertical-cavity surface-emitting laser (VCSEL) and an optical cavity with re-entrant configuration, is employed to demonstrate the potential of this scheme for improving the sensitivity and robustness of a field-deployable cavity spectrometer. The RF spectral density of the current noise injected into the VCSEL has been measured, and correlated to the effects on the optical spectral signal-to-noise ratio (SNR) and laser linewidth for a range of re-entrant geometries. A fourfold gain in the SNR has been achieved using the RF noise perturbation for the optimal off-axis alignment, which led to a minimum detectable absorption (MDA) predicted from an Allan variance study as low as 4.3 × 10(-5) at 1 s averaging. For the optically forbidden oxygen transition under investigation, a limit of detection (SNR = 1) of 810 ppm was achieved for a 10 ms acquisition time. This performance level paves the way for a fast, sensitive, in-line oxygen spectrometer that lends itself to a range of applications in respiratory medicine.

  19. REAL TIME CONTINUOUS MEASUREMENTS OF [CO2] AND δ13C AT MULTIPLE LOCATIONS USING CAVITY ENHANCED LASER ABSORPTION

    NASA Astrophysics Data System (ADS)

    McAlexander, W. I.; Rau, G. H.; Dobeck, L.; Spangler, L.

    2009-12-01

    A commercial instrument (Los Gatos Research, model 908-0003) utilizing Cavity Enhanced Laser Absorption Spectroscopy was deployed in 2009 at the ZERT carbon release site (Bozeman, MT) for real time measurement of above-ground CO2 concentration and isotope ratio (δ13C). An automated switching system sampled 13 different locations in the field, as well as two known references, over an 8 day period. Real-time Keeling plots were constructed showing distinct signatures of soil (-27.0 ‰) and fossil (-56.0 ‰) sources compared to background air (-8.2 ‰). Instrument performance gave 0.2 ‰ precision with only 100 seconds of averaging per inlet. Sequential sampling of the various inlets gave a temporal and physical mapping of the CO2 release plume that is difficult to obtain using more conventional techniques. The figures show the nature and quality of the data from one of the locations. Details concerning instrument performance, systematics, calibration, and data processing will be discussed. Fig1: Time chart of CO2 concentration and isotope ratio δ13C from one of 13 sample inlet locations at ZERT release field, July, 2009. Fig2: Keeling plot of data from Fig1 illustrating the two source mixing of soil (-27 ‰) and fossil (-56 ‰) CO2 with background air.

  20. Characteristic analysis of the optical delay in frequency response of resonant cavity enhanced (RCE) photodetectors

    NASA Astrophysics Data System (ADS)

    Guo, Jian-Chuan; Zuo, Yu-Hua; Zhang, Yun; Ding, Wu-Chang; Cheng, Bu-Wen; Yu, Jin-Zhong; Wang, Qi-Ming

    2009-06-01

    With consideration of the modulation frequency of the input lightwave itself, we present a new model to calculate the quantum efficiency of RCE p-i-n photodetectors (PD) by superimposition of multiple reflected lightwaves. For the first time, the optical delay, another important factor limiting the electrical bandwidth of RCE p-i-n PD excluding the transit time of the carriers and RCd response of the photodetector, is analyzed and discussed in detail. The optical delay dominates the bandwidth of RCE p-i-n PD when its active layer is thinner than several 10 nm. These three limiting factors must be considered exactly for design of ultra-high-speed RCE p-i-n PD.

  1. Cavity-Enhanced Single-Photon Source Based on the Silicon-Vacancy Center in Diamond

    NASA Astrophysics Data System (ADS)

    Benedikter, Julia; Kaupp, Hanno; Hümmer, Thomas; Liang, Yuejiang; Bommer, Alexander; Becher, Christoph; Krueger, Anke; Smith, Jason M.; Hänsch, Theodor W.; Hunger, David

    2017-02-01

    Single-photon sources are an integral part of various quantum technologies, and solid-state quantum emitters at room temperature appear to be a promising implementation. We couple the fluorescence of individual silicon-vacancy centers in nanodiamonds to a tunable optical microcavity to demonstrate a single-photon source with high efficiency, increased emission rate, and improved spectral purity compared to the intrinsic emitter properties. We use a fiber-based microcavity with a mode volume as small as 3.4 λ3 and a quality factor of 1.9 ×1 04 and observe an effective Purcell factor of up to 9.2. Furthermore, we study modifications of the internal rate dynamics and propose a rate model that closely agrees with the measurements. We observe lifetime changes of up to 31%, limited by the finite quantum efficiency of the emitters studied here. With improved materials, our achieved parameters predict single-photon rates beyond 1 GHz.

  2. Dynamics of bad-cavity-enhanced interaction with cold Sr atoms for laser stabilization

    NASA Astrophysics Data System (ADS)

    Schäffer, S. A.; Christensen, B. T. R.; Henriksen, M. R.; Thomsen, J. W.

    2017-07-01

    Hybrid systems of cold atoms and optical cavities are promising systems for increasing the stability of laser oscillators used in quantum metrology and atomic clocks. In this paper we map out the atom-cavity dynamics in such a system and demonstrate limitations as well as robustness of the approach. We investigate the phase response of an ensemble of cold 88Sr atoms inside an optical cavity for use as an error signal in laser frequency stabilization. With this system we realize a regime where the high atomic phase shift limits the dynamical locking range. The limitation is caused by the cavity transfer function relating input field to output field. The cavity dynamics is shown to have only little influence on the prospects for laser stabilization, making the system robust towards cavity fluctuations and ideal for the improvement of future narrow linewidth lasers.

  3. Long wave infrared cavity-enhanced sensors using quantum cascade lasers

    SciTech Connect

    Taubman, Matthew S.; Scott, David C.; Myers, Tanya L.; Cannon, Bret D.

    2005-12-30

    Quantum cascade lasers (QCLs) are becoming well known as convenient and stable semiconductor laser sources operating in the mid- to long-wave infrared, and are able to be fabricated to operate virtually anywhere in the 3.5 to 25 micron region. This makes them an ideal choice for infrared chemical sensing, a topic of great interest at present, spanning at least three critical areas: national security, environmental monitoring and protection, and the early diagnosis of disease through breath analysis. There are many different laser-based spectroscopic chemical sensor architectures in use today, from simple direct detection through to more complex and highly sensitive systems. Many current sensor needs can be met by combining QCLs and appropriate sensor architectures, those needs ranging from UAV-mounted surveillance systems, through to larger ultra-sensitive systems for airport security. In this paper we provide an overview of various laser-based spectroscopic sensing techniques, pointing out advantages and disadvantages of each. As part of this process, we include our own results and observations for techniques under development at PNNL. We also present the latest performance of our ultra-quiet QCL control electronics now being commercialized, and explore how using optimized supporting electronics enables increased sensor performance and decreased sensor footprint for given applications.

  4. Long wave infrared cavity-enhanced sensors using quantum cascade lasers

    NASA Astrophysics Data System (ADS)

    Taubman, Matthew S.; Scott, David C.; Myers, Tanya L.; Cannon, Bret D.

    2005-11-01

    Quantum cascade lasers (QCLs) are becoming well known as convenient and stable semiconductor laser sources operating in the mid- to long-wave infrared, and are able to be fabricated to operate virtually anywhere in the 3.5 to 25 micron region. This makes them an ideal choice for infrared chemical sensing, a topic of great interest at present, spanning at least three critical areas: national security, environmental monitoring and protection, and the early diagnosis of disease through breath analysis. There are many different laser-based spectroscopic chemical sensor architectures in use today, from simple direct detection through to more complex and highly sensitive systems. Many current sensor needs can be met by combining QCLs and appropriate sensor architectures, those needs ranging from UAV-mounted surveillance systems, through to larger ultra-sensitive systems for airport security. In this paper we provide an overview of various laser-based spectroscopic sensing techniques, pointing out advantages and disadvantages of each. As part of this process, we include our own results and observations for techniques under development at PNNL. We also present the latest performance of our ultra-quiet QCL control electronics now being commercialized, and explore how using optimized supporting electronics enables increased sensor performance and decreased sensor footprint for given applications.

  5. Cavity-enhanced single photons from a quantum dot (Invited Paper)

    NASA Astrophysics Data System (ADS)

    Vuckovic, Jelena; Fattal, David; Englund, Dirk; Waks, Edo; Santori, Charles; Solomon, Glenn; Yamamoto, Yoshihisa

    2005-04-01

    Single-photon sources rarely emit two or more photons in the same pulse, compared to a Poisson-distributed source of the same intensity, and have numerous applications in quantum information science. The quality of such a source is evaluated based on three criteria: high efficiency, small multi-photon probability, and quantum indistinguishability. We have demonstrated a single-photon source based on a quantum dot in a micropost microcavity that exhibits a large Purcell factor together with a small multi-photon probability. For a quantum dot on resonance with the cavity, the spontaneous emission rate has been increased by a factor of five, while the probability to emit two or more photons in the same pulse has been reduced to 2% compared to a Poisson-distributed source of the same intensity. The indistinguishability of emitted single photons from one of our devices has been tested through a Hong-Ou-Mandel-type two-photon interference experiment; consecutive photons emitted from such a source have been largely indistinguishable, with a mean wave-packet overlap as large as 0.81. We have also designed and demonstrated two-dimensional photonic crystal GaAs cavities containing InAs quantum dots that exhibit much higher quality factors together with much smaller mode volumes than microposts, and therefore present an ideal platform for construction of single photon sources of even higher quality.

  6. Time-resolved in situ detection of CO in a shock tube using cavity-enhanced absorption spectroscopy with a quantum-cascade laser near 4.6 µm.

    PubMed

    Sun, Kai; Wang, Shengkai; Sur, Ritobrata; Chao, Xing; Jeffries, Jay B; Hanson, Ronald K

    2014-10-06

    Cavity-enhanced absorption spectroscopy (CEAS) using a mid-infrared DFB quantum-cascade laser is reported for sensitive time-resolved (10 μs) in situ CO measurements in a shock tube. Off-axis alignment and fast scanning of the laser wavelength were used to minimize coupling noise in a low-finesse cavity. An absorption gain factor of 91 was demonstrated, which enabled sub-ppm detection sensitivity for gas temperatures of 1000-2100K in a 15 cm diameter shock tube. This substantial improvement in detection sensitivity compared to conventional single-pass absorption measurements, shows great potential for the study of reaction pathways of high-temperature combustion kinetics mechanisms in shock tubes.

  7. Using a fourth-generation cavity enhanced spectrometer to isotopically investigate nitrous oxide emissions from biochar amended soils.

    NASA Astrophysics Data System (ADS)

    Grabenhofer, Jutta; Dercon, Gerd; Heiling, Maria; Mayr, Leo; Resch, Christian; Hood-Nowotny, Rebecca

    2016-04-01

    Research into the impacts of biochar on key processes in the nitrogen cycle is important to understand biochar's potential role in sustainable agriculture. There is conflicting evidence that biochar can reduce globally significant greenhouse gas emissions, especially N2O, one of the most important greenhouse gases in agriculture. However to date there is little information on the mechanisms involved. The source of N2O is dependent on the physical, chemical and biological status of the soil at a microbial scale and we need to understand how biochar influences it. Using the 15N2O gas flux method combined with gross rate measurements of nitrification and modelling, it should be possible to determine the parameters which drive N2O emissions and to evaluate the specific impact of biochar on these important N loss processes. To date the scope of isotopic studies on nitrous oxide emissions have been limited, due in part to technical and infrastructural access to complex and expensive mass spectrometry. With the advent of laser based systems these logistical and analytical constraints could be overcome and allow for a deeper and geographically more representative, understanding and assessment of the role of biochar in reducing nitrous oxide emissions from soil. In this study we have developed a simple method for investigated nitrous oxide emissions from soils amended with biochar, employing state of the art stable isotope techniques, using a fourth-generation cavity enhanced absorption technique a variant of conventional Cavity Ringdown Spectroscopy (CRDS) for measurement of isotopes of nitrous oxide. We will present methodologies used and results from these experiments, techniques that should path the way for a greater global understand nitrous oxide emissions from soils.

  8. Tunable ultraviolet/visible to near-infrared down-conversion luminescence in the Er3+, Yb3+ co-doped (Y0.88La0.09Zr0.03)2O3 transparent ceramics

    NASA Astrophysics Data System (ADS)

    Hu, Yue; Shahid, Muhammad; Pan, Wei

    2017-10-01

    Herein, we report an efficient ultraviolet/visible to near-infrared (NIR) down-conversion luminescence phenomenon in transparent Er3+, Yb3+ co-doped (Y0.88La0.09Zr0.03)2O3 ceramics. Almost fully densified (Y0.88La0.09Zr0.03)2O3 transparent ceramic has been prepared by vacuum sintering at 1800 °C with different contents of Er3+ and Yb3+ elements. The intensity ratio of Yb3+: 2F5/2 → 2F7/2 emission (∼1000 nm) to the Er3+: 4I13/2 → 4I15/2 emission (∼1550 nm) has been tuned by adjusting the excitation wavelength. Phonon-assist quantum cutting from the 4G11/2 level of Er3+ with two energy transfer (ET) processes to Yb3+ has been determined, which enhances the Yb3+ emission around the wavelength of 1000 nm. It is found that when one photon around 379 nm is absorbed, two photons around 1000 nm will be emitted, and hence the quantum efficiency is estimated to be ∼182% in this transparent ceramics. The mechanism of the visible to near-infrared (NIR) down-conversion luminescence in the Er3+, Yb3+ co-doped (Y0.88La0.09Zr0.03)2O3 ceramics has been discussed.

  9. Walk-Off-Induced Modulation Instability, Temporal Pattern Formation, and Frequency Comb Generation in Cavity-Enhanced Second-Harmonic Generation.

    PubMed

    Leo, F; Hansson, T; Ricciardi, I; De Rosa, M; Coen, S; Wabnitz, S; Erkintalo, M

    2016-01-22

    We derive a time-domain mean-field equation to model the full temporal and spectral dynamics of light in singly resonant cavity-enhanced second-harmonic generation systems. We show that the temporal walk-off between the fundamental and the second-harmonic fields plays a decisive role under realistic conditions, giving rise to rich, previously unidentified nonlinear behavior. Through linear stability analysis and numerical simulations, we discover a new kind of quadratic modulation instability which leads to the formation of optical frequency combs and associated time-domain dissipative structures. Our numerical simulations show excellent agreement with recent experimental observations of frequency combs in quadratic nonlinear media [Phys. Rev. A 91, 063839 (2015)]. Thus, in addition to unveiling a new, experimentally accessible regime of nonlinear dynamics, our work enables predictive modeling of frequency comb generation in cavity-enhanced second-harmonic generation systems. We expect our findings to have wide impact on the study of temporal and spectral dynamics in a diverse range of dispersive, quadratically nonlinear resonators.

  10. Simultaneous clock recovery and dispersion, OSNR monitoring for 112-Gbit/s NRZ-DQPSK using frequency down-conversion electro-optical phase-locked loop.

    PubMed

    Wen, He; Cheng, Lin; Liao, Jinxin; Zheng, Xiaoping; Zhang, Hanyi; Guo, Yili; Zhou, Bingkun

    2011-12-12

    A cost effective clock recovery scheme simultaneously providing signal performance monitoring is proposed for high speed electrical time domain multiplexing (ETDM) transmission systems to release the bandwidth requirement on the involved electrical devices. In the scheme, we first convert the clock frequency down in the optical domain using electroptic modulation, and then extract the clock with a phase locked loop (PLL) after photo-detection. All the devices involved are operated at frequencies lower than half of the symbol rate. Furthermore, we use a quadrature phase detector in the PLL to create a monitor signal which characterizes the transmitted signal performance in terms of optical-to-noise ratio (OSNR) and accumulated chromatic dispersion (ACD). This scheme is applied to a 112-Gbit/s none-return-to-zero (NRZ) differential quadrature phase shift keying (DQPSK) system. Experimental results show that the clock can be recovered in a dispersion range of -40 to 40 ps/nm, and the evaluated OSNR, over a range of 18~36 dB, has a deviation smaller than 1 dB compared to the measured one based on the optical spectrum method. The bit error ratio remains below 10(-9) for 12 hours in the back-to-back case and 2 hours after transmission over 100-km standard single mode fiber (SSMF).

  11. Controllable synthesis and down-conversion properties of flower-like NaY(MoO{sub 4}){sub 2} microcrystals via polyvinylpyrrolidone-mediated

    SciTech Connect

    Lin, Han; Yan, Xiaohong; Wang, Xiangfu

    2013-08-15

    Double alkaline rare-earth molybdates NaY(MoO{sub 4}){sub 2} with multilayered flower-like architectures have been successfully synthesized via hydrothermal method in polyvinylpyrrolidone (PVP)-modified processes. The crystal structure and morphology of the obtained products were characterized by X-ray diffraction, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). It was found that reaction time and the amount of PVP have crucial influences on the morphology of the resulting novel microstructures. Under 450 nm excitation, Ho{sup 3+}/Yb{sup 3+} co-doped NaY(MoO{sub 4}){sub 2} samples exhibit 539 nm green emission and 960–1200 nm broadband near-infrared emission, corresponding to the characteristic lines of Ho{sup 3+} and Yb{sup 3+}, respectively. Moreover, increasing Yb{sup 3+} doping enhances the energy transfer efficiency from Ho{sup 3+} to Yb{sup 3+}. - Graphical abstract: Low and high-magnification SEM images demonstrate the perfect flower-like NaY(MoO{sub 4}){sub 2} prepared in the presence of PVP; Detailed TEM and HRTEM images further manifest the single-crystalline feature. Highlights: • NaY(MoO{sub 4}){sub 2} flower-like microstructures were synthesized by hydrothermal method using polyvinylpyrrolidone. • Polyvinylpyrrolidone induces the growth of the NaY(MoO{sub 4}){sub 2} to form multilayered architectures. • Flowerlike NaY(MoO{sub 4}){sub 2}: Ho{sup 3+}, Yb{sup 3+} phosphors were investigated as a downconversion layer candidate.

  12. Pumping-route-dependent concentration quenching and temperature effect of green up- and down-conversion luminescence in Er{sup 3+}/Yb{sup 3+} co-doped Gd{sub 2}(WO{sub 4}){sub 3} phosphors

    SciTech Connect

    Li, Jingjing; Sun, Jiashi; Liu, Jutao; Li, Xiangping; Zhang, Jinsu; Tian, Yue; Fu, Shaobo; Cheng, Lihong; Zhong, Haiyang; Xia, Haiping; Chen, Baojiu

    2013-06-01

    Graphical abstract: A comparative study on the concentration quenching behaviors of green down- and up-conversion emissions was carried out for the first time, and the different concentration quenching mechanisms were analyzed. Secondly, the thermal effect induced by 980 nm LD irradiation was investigated, it was observed that the equilibrium temperature of Gd{sub 2}(WO{sub 4}){sub 3}:Er{sup 3+}/Yb{sup 3+} sample was decided by both the excitation power and Er{sup 3+} doping concentration. Highlights: ► Gd{sub 2}(WO{sub 4}){sub 3}:Er/Yb phosphors were prepared via a co-precipitation reaction. ► Morphology and structure of the phosphors were characterized by XRD and SEM. ► Concentration quenching mechanisms for down and up emissions were studied. ► Thermal effect induced by laser irradiation was studied via temperature sensing tech. - Abstract: Gd{sub 2}(WO{sub 4}){sub 3} phosphors with various Er{sup 3+} concentrations and fixed Yb{sup 3+} concentration were synthesized via a co-precipitation method, and their crystal structure and morphology were characterized by using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The concentration quenching behaviors of green up- and down-conversion emissions of Er{sup 3+} were analyzed, and it was confirmed that the difference between quenching concentration for up- and down-conversion emissions resulted from the different population routes. The temperature sensing properties of the Gd{sub 2}(WO{sub 4}){sub 3}:Er{sup 3+}/Yb{sup 3+} phosphors were studied, and it was found that the Er{sup 3+} doping concentration slightly affected the sensitivity, and Gd{sub 2}(WO{sub 4}){sub 3}:Er{sup 3+}/Yb{sup 3+} phosphors could be used in a broad temperature region for detecting temperature. Finally, the thermal effect induced by 980 nm LD irradiation was investigated, it was observed that the equilibrium temperature of Gd{sub 2}(WO{sub 4}){sub 3}:Er{sup 3+}/Yb{sup 3+} sample was decided by both the excitation power

  13. Doppler-broadened mid-infrared noise-immune cavity-enhanced optical heterodyne molecular spectrometry based on an optical parametric oscillator for trace gas detection.

    PubMed

    Silander, Isak; Hausmaninger, Thomas; Ma, Weiguang; Harren, Frans J M; Axner, Ove

    2015-02-15

    An optical parametric oscillator based Doppler-broadened (Db) noise-immune cavity-enhanced optical heterodyne molecular spectrometry (NICE-OHMS) system suitable for addressing fundamental vibrational transitions in the 3.2-3.9 μm mid-infrared (MIR) region has been realized. An Allan-Werle analysis provides a detection sensitivity of methane of 1.5×10(-9)  cm(-1) with a 20 s integration time, which corresponds to 90 ppt of CH4 if detected at the strongest transition addressed at 40 Torr. This supersedes that of previous Db MIR NICE-OHMS demonstrations and suggests that the technique can be suitable for detection of both the environmentally important (13)CH(4) and CH3D isotopologues. It also opens up for detection of many other molecular species at ppt and sub-ppt concentration levels.

  14. Enhancing the sensitivity of mid-IR quantum cascade laser-based cavity-enhanced absorption spectroscopy using RF current perturbation.

    PubMed

    Manfred, Katherine M; Kirkbride, James M R; Ciaffoni, Luca; Peverall, Robert; Ritchie, Grant A D

    2014-12-15

    The sensitivity of mid-IR quantum cascade laser (QCL) off-axis cavity-enhanced absorption spectroscopy (CEAS), often limited by cavity mode structure and diffraction losses, was enhanced by applying a broadband RF noise to the laser current. A pump-probe measurement demonstrated that the addition of bandwidth-limited white noise effectively increased the laser linewidth, thereby reducing mode structure associated with CEAS. The broadband noise source offers a more sensitive, more robust alternative to applying single-frequency noise to the laser. Analysis of CEAS measurements of a CO(2) absorption feature at 1890  cm(-1) averaged over 100 ms yielded a minimum detectable absorption of 5.5×10(-3)  Hz(-1/2) in the presence of broadband RF perturbation, nearly a tenfold improvement over the unperturbed regime. The short acquisition time makes this technique suitable for breath applications requiring breath-by-breath gas concentration information.

  15. Development of a portable cavity-enhanced absorption spectrometer for the measurement of ambient NO3 and N2O5: experimental setup, lab characterizations, and field applications in a polluted urban environment

    NASA Astrophysics Data System (ADS)

    Wang, Haichao; Chen, Jun; Lu, Keding

    2017-04-01

    A small and portable incoherent broadband cavity-enhanced absorption spectrometer (IBBCEAS) for NO3 and N2O5 measurement has been developed. The instrument features a mechanically aligned non-adjustable optical mounting system, and the novel design of the optical mounting system enables a fast setup and stable operation in field applications. To remove the influence of the strong nonlinear absorption by water vapour, a dynamic reference spectrum through NO titration is used for the spectrum analysis. The wall loss effects of the sample system were extensively studied, and the total transmission efficiencies were determined to be 85 and 55 % for N2O5 and NO3, respectively, for our experimental setup. The limit of detection (LOD) was estimated to be 2.4 pptv (1σ) and 2.7 pptv (1σ) at 1 s intervals for NO3 and N2O5, respectively. The associated uncertainty of the field measurement was estimated to be 19 % for NO3 and 22-36 % for N2O5 measurements from the uncertainties of transmission efficiency, absorption cross section, effective cavity length, and mirror reflectivity. The instrument was successfully deployed in two comprehensive field campaigns conducted in the winter and summer of 2016 in Beijing. Up to 1.0 ppb NO3+N2O5 was observed with the presence of high aerosol loadings, which indicates an active night-time chemistry in Beijing.

  16. Noise-immune cavity-enhanced optical heterodyne molecular spectrometry on N₂O 1.283 μm transition based on a quantum-dot external-cavity diode laser.

    PubMed

    Chen, Tzu-Ling; Liu, Yi-Wei

    2015-09-15

    To access the wavelength within the 1.1-1.3 μm region, we have developed a quantum-dot (QD) laser with an external-cavity configuration and a linewidth of kilohertz at a 1 ms integration time. The residual electroluminescence, due to the inhomogeneous broadening of the QD gain medium, was observed and filtered out using a grating. While a fiber-coupled electro-optical modulator was employed, this laser system was locked to a high-finesse (F∼18,500) optical cavity, and noise-immune cavity-enhanced optical heterodyne molecular spectroscopy was used to observe weak transitions. The Doppler-broadened spectra of a weak N(2)O transition at 1.283 μm are obtained with a signal-to-noise ratio of 30 for a gas pressure of 54 mTorr. The minimum noise-equivalent absorption coefficient is 5.3×10(-10)  cm(-1) Hz(-1/2). This system can be a powerful and stable light source for atomic parity nonconservation measurements using thallium, ytterbium, lead, and iodine.

  17. Cavity-Enhanced Spectroscopy of Molecular Ions in the Mid-Infrared with Up-Conversion Detection and Brewster-Plate Spoilers

    NASA Astrophysics Data System (ADS)

    Markus, Charles R.; McCollum, Jefferson E.; Hodges, James Neil; Perry, Adam J.; McCall, Benjamin J.

    2017-06-01

    Molecular ions are challenging to study with conventional spectroscopic methods. Laboratory discharges produce ions in trace quantities which can be obscured by the abundant neutral molecules present. The technique Noise Immune Cavity Enhanced Optical Heterodyne Velocity Modulation Spectroscopy (NICE-OHVMS) overcomes these challenges by combining the ion-neutral discrimination of velocity modulation spectroscopy with the sensitivity of Noise-Immune Cavity-Enhanced Optical Heterodyne Molecular Spectroscopy (NICE-OHMS), and has been able to determine transition frequencies of molecular ions in the mid-infrared (mid-IR) with sub-MHz uncertainties when calibrated with an optical frequency comb. However, the extent of these studies was limited by the presence of fringes due to parasitic etalons and the speed and noise characteristics of mid-IR detectors. Recently, we have overcome these limitations by implementing up-conversion detection and dithered optics. We performed up-conversion using periodically poled lithium niobate to convert light from the mid-IR to the visible to be within the coverage of sensitive and fast silicon detectors while maintaining our heterodyne and velocity modulation signals. The parasitic etalons were removed by rapidly rotating CaF_2 windows with galvanometers, which is known as a Brewster-plate spoiler, which averaged out the fringes in detection. Together, these improved the sensitivity by more than an order of magnitude and have enabled extended spectroscopic surveys of molecular ions in the mid-IR. J. N. Hodges, A. J. Perry, P. A. Jenkins II, B. M. Siller, and B. J. McCall, J. Chem. Phys. (2013), 139, 164201. C. R. Webster, J. Opt. Soc. Am. B (1985), 2, 1464. C. R. Markus, A. J. Perry, J. N. Hodges, and B. J. McCall, Opt. Express (2017), 25, 3709-3721.

  18. The down-conversion and up-conversion photoluminescence properties of Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}:Yb{sup 3+}/Pr{sup 3+} ceramics

    SciTech Connect

    Huang, Yinpeng; Luo, Laihui Wang, Jia; Zuo, Qianghui; Yao, Yongjie; Li, Weiping

    2015-07-28

    Na{sub 0.5}Bi{sub 0.5−x−y}Yb{sub x}Pr{sub y}TiO{sub 3} (NBT:xYb/yPr) ceramics with different Yb and Pr contents are prepared. Both the down-conversion (DC) and up-conversion (UC) photoluminescence (PL) of the ceramics via 453 and 980 nm excitation, respectively, are investigated. The effect of Yb{sup 3+} and Pr{sup 3+} doping contents on the DC and UC PL is significantly different from each other. Furthermore, the UC PL of the ceramics as a function of temperatures is measured to investigate the UC process in detail. Based on energy level diagram of Pr{sup 3+} and Yb{sup 3+} ions and the DC and UC PL spectra, the DC and UC PL mechanisms of Pr{sup 3+} and Yb{sup 3+} ions are discussed. Especially, the UC PL mechanism is clarified, which is different from the previously reported literature. Also, the temperature sensing properties of the ceramics are studied based on the photoluminescence ratio technique, using the thermal coupling energy levels of Pr{sup 3+}.

  19. Nanoscale resonant-cavity-enhanced germanium photodetectors with lithographically defined spectral response for improved performance at telecommunications wavelengths.

    PubMed

    Balram, Krishna C; Audet, Ross M; Miller, David A B

    2013-04-22

    We demonstrate the use of a subwavelength planar metal-dielectric resonant cavity to enhance the absorption of germanium photodetectors at wavelengths beyond the material's direct absorption edge, enabling high responsivity across the entire telecommunications C and L bands. The resonant wavelength of the detectors can be tuned linearly by varying the width of the Ge fin, allowing multiple detectors, each resonant at a different wavelength, to be fabricated in a single-step process. This approach is promising for the development of CMOS-compatible devices suitable for integrated, high-speed, and energy-efficient photodetection at telecommunications wavelengths.

  20. Determination of nitrous acid emission factors from a gasoline vehicle using a chassis dynamometer combined with incoherent broadband cavity-enhanced absorption spectroscopy.

    PubMed

    Nakashima, Yoshihiro; Kajii, Yoshizumi

    2017-01-01

    Nitrous acid (HONO) is a well-known source of hydroxyl radicals in the troposphere. Vehicle exhaust is considered to be one of the primary emission sources of HONO. In this study, measurements of HONO in gasoline vehicle exhaust were carried out using a chassis dynamometer combined with incoherent broadband cavity-enhanced absorption spectroscopy. When catalysts were warm, concentrations of HONO were higher than those prior to catalysts warming. Other species, such as CO, and total hydrocarbons (THCs), showed the opposite pattern. There were no correlations evident between HONO and other trace species concentrations immediately after emission. The HONO/NOx ratio, a good proxy for the formation of HONO in atmosphere, ranged from 1.1 to 6.8×10(-3), which was consistent with previous studies. HONO emission factors (EFs) were calculated to be 0.01-3.6mgkg(-1) fuel, which was different from the vehicle's specifications and those reported under different driving cycles. Annual HONO emissions in Japan were estimated using the calculated EFs and other statistical data.

  1. Mid-infrared concentration-modulated noise-immune cavity-enhanced optical heterodyne molecular spectroscopy of a continuous supersonic expansion discharge source

    NASA Astrophysics Data System (ADS)

    Talicska, Courtney N.; Porambo, Michael W.; Perry, Adam J.; McCall, Benjamin J.

    2016-06-01

    Concentration-modulated noise-immune cavity-enhanced optical heterodyne molecular spectroscopy (NICE-OHMS) is implemented for the first time on a continuous gas-flow pinhole supersonic expansion discharge source for the study of cooled molecular ions. The instrument utilizes a continuous-wave optical parametric oscillator easily tunable from 2.5 to 3.9 μm and demonstrates a noise equivalent absorption of ˜1 × 10-9 cm-1. The effectiveness of concentration-modulated NICE-OHMS is tested through the acquisition of transitions in the ν1 fundamental band of HN2+ centered near 3234 cm-1, with a signal-to-noise of ˜40 obtained for the strongest transitions. The technique is used to characterize the cooling abilities of the supersonic expansion discharge source itself, and a Boltzmann analysis determines a rotational temperature of ˜29 K for low rotational states of HN2+. Further improvements are discussed that will enable concentration-modulated NICE-OHMS to reach its full potential for the detection of molecular ions formed in supersonic expansion discharges.

  2. Mid-infrared concentration-modulated noise-immune cavity-enhanced optical heterodyne molecular spectroscopy of a continuous supersonic expansion discharge source.

    PubMed

    Talicska, Courtney N; Porambo, Michael W; Perry, Adam J; McCall, Benjamin J

    2016-06-01

    Concentration-modulated noise-immune cavity-enhanced optical heterodyne molecular spectroscopy (NICE-OHMS) is implemented for the first time on a continuous gas-flow pinhole supersonic expansion discharge source for the study of cooled molecular ions. The instrument utilizes a continuous-wave optical parametric oscillator easily tunable from 2.5 to 3.9 μm and demonstrates a noise equivalent absorption of ∼1 × 10(-9) cm(-1). The effectiveness of concentration-modulated NICE-OHMS is tested through the acquisition of transitions in the ν1 fundamental band of HN2 (+) centered near 3234 cm(-1), with a signal-to-noise of ∼40 obtained for the strongest transitions. The technique is used to characterize the cooling abilities of the supersonic expansion discharge source itself, and a Boltzmann analysis determines a rotational temperature of ∼29 K for low rotational states of HN2 (+). Further improvements are discussed that will enable concentration-modulated NICE-OHMS to reach its full potential for the detection of molecular ions formed in supersonic expansion discharges.

  3. Ultrasensitive, real-time analysis of biomarkers in breath using tunable external cavity laser and off-axis cavity-enhanced absorption spectroscopy

    NASA Astrophysics Data System (ADS)

    Bayrakli, Ismail; Akman, Hatice

    2015-03-01

    A robust biomedical sensor for ultrasensitive detection of biomarkers in breath based on a tunable external cavity laser (ECL) and an off-axis cavity-enhanced absorption spectroscopy (OA-CEAS) using an amplitude stabilizer is developed. A single-mode, narrow-linewidth, tunable ECL is demonstrated. A broadly coarse wavelength tuning range of 720 cm-1 for the spectral range between 6890 and 6170 cm-1 is achieved by rotating the diffraction grating forming a Littrow-type external-cavity configuration. A mode-hop-free tuning range of 1.85 cm-1 is obtained. The linewidths below 140 kHz are recorded. The ECL is combined with an OA-CEAS to perform laser chemical sensing. Our system is able to detect any molecule in breath at concentrations to the ppbv range that have absorption lines in the spectral range between 1450 and 1620 nm. Ammonia is selected as target molecule to evaluate the performance of the sensor. Using the absorption line of ammonia at 6528.76 cm-1, a minimum detectable absorption coefficient of approximately 1×10-8 cm-1 is demonstrated for 256 averages. This is achieved for a 1.4-km absorption path length and a 2-s data-acquisition time. These results yield a detection sensitivity of approximately 8.6×10-10 cm-1 Hz-1/2. Ammonia in exhaled breath is analyzed and found in a concentration of 870 ppb for our example.

  4. Cavity-enhanced optical Hall effect in two-dimensional free charge carrier gases detected at terahertz frequencies.

    PubMed

    Knight, S; Schöche, S; Darakchieva, V; Kühne, P; Carlin, J-F; Grandjean, N; Herzinger, C M; Schubert, M; Hofmann, T

    2015-06-15

    The effect of a tunable, externally coupled Fabry-Perot cavity to resonantly enhance the optical Hall effect signatures at terahertz frequencies produced by a traditional Drude-like two-dimensional electron gas is shown and discussed in this Letter. As a result, the detection of optical Hall effect signatures at conveniently obtainable magnetic fields, for example, by neodymium permanent magnets, is demonstrated. An AlInN/GaN-based high-electron mobility transistor structure grown on a sapphire substrate is used for the experiment. The optical Hall effect signatures and their dispersions, which are governed by the frequency and the reflectance minima and maxima of the externally coupled Fabry-Perot cavity, are presented and discussed. Tuning the externally coupled Fabry-Perot cavity strongly modifies the optical Hall effect signatures, which provides a new degree of freedom for optical Hall effect experiments in addition to frequency, angle of incidence, and magnetic field direction and strength.

  5. Homodyne tomography of a single photon retrieved on demand from a cavity-enhanced cold atom memory.

    PubMed

    Bimbard, Erwan; Boddeda, Rajiv; Vitrant, Nicolas; Grankin, Andrey; Parigi, Valentina; Stanojevic, Jovica; Ourjoumtsev, Alexei; Grangier, Philippe

    2014-01-24

    We experimentally demonstrate that a nonclassical state prepared in an atomic memory can be efficiently transferred to a single mode of free-propagating light. By retrieving on demand a single excitation from a cold atomic gas, we realize an efficient source of single photons prepared in a pure, fully controlled quantum state. We characterize this source using two detection methods, one based on photon-counting analysis and the second using homodyne tomography to reconstruct the density matrix and Wigner function of the state. The latter technique allows us to completely determine the mode of the retrieved photon in its fine phase and amplitude details and demonstrate its nonclassical field statistics by observing a negative Wigner function. We measure a photon retrieval efficiency up to 82% and an atomic memory coherence time of 900  ns. This setup is very well suited to study interactions between atomic excitations and use them in order to create and manipulate more sophisticated quantum states of light with a high degree of experimental control.

  6. Online investigation of respiratory quotients in Pinus sylvestris and Picea abies during drought and shading by means of cavity-enhanced Raman multi-gas spectrometry.

    PubMed

    Hanf, Stefan; Fischer, Sarah; Hartmann, Henrik; Keiner, Robert; Trumbore, Susan; Popp, Jürgen; Frosch, Torsten

    2015-07-07

    Photosynthesis and respiration are major components of the plant carbon balance. During stress, like drought, carbohydrate supply from photosynthesis is reduced and the Krebs cycle respiration must be fueled with other stored carbon compounds. However, the dynamics of storage use are still unknown. The respiratory quotient (RQ, CO2 released per O2 consumed during respiration) is an excellent indicator of the nature of the respiration substrate. In plant science, however, online RQ measurements have been challenging or even impossible so far due to very small gas exchange fluxes during respiration. Here we apply cavity-enhanced multi-gas Raman spectrometry (CERS) for online in situ RQ measurements in drought-tolerant pine (Pinus sylvestris [L.]) and drought-intolerant spruce (Picea abies [L. H. Karst]). Two different treatments, drought and shading, were applied to reduce photosynthesis and force dependency on stored substrates. Changes in respiration rates and RQ values were continuously monitored over periods of several days with low levels of variance. The results show that both species switched from COH-dominated respiration (RQ = 1.0) to a mixture of substrates during shading (RQ = 0.77-0.81), while during drought only pine did so (RQ = 0.75). The gas phase measurements were complemented by concentration measurements of non-structural carbohydrates and lipids. These first results suggest a physiological explanation for greater drought tolerance in pine. CERS was proven as powerful technique for non-consumptive and precise real-time monitoring of respiration rates and respirational quotients for the investigation of plant metabolism under drought stress conditions that are predicted to increase with future climate change.

  7. Ambient measurements of the concentration of nitrous acid by incoherent cavity enhanced absorption spectroscopy during the winter season in 2016 in urban area of Tokyo.

    NASA Astrophysics Data System (ADS)

    Nakashima, Y.; Sadanaga, Y.; Saito, S.; Hoshi, J.; Ueno, H.

    2016-12-01

    Nitrous acid (HONO) plays an important role in the source of the hydroxyl radial (OH) by the photolysis. Since HONO decomposes easily even under the weak sun light condition, the photolysis of HONO would be the important source of OH in the morning. The main sources of HONO are (i) homogeneous reaction of NO with OH and (ii) heterogeneous reaction of NO2. However, many new primary or secondary source of HONO has been suggested. In addition, the existence of HONO in the daytime in the troposphere has been reported. To investigate the ambient concentration, difference of the seasonal conditions, and contribution of the primary and secondary source of HONO, the measurements of concentration of HONO have been begun at Tokyo Metropolitan Research Institute (TMRI), located in urban central Tokyo. In this time, the results of the measurements of HONO at TMRI during the winter season (January 21st - February 12th) in 2016 will be presented. For the measurements of HONO, the incoherent cavity enhanced absorption spectroscopy were applied. Gaseous trace species such as ozone, nitrogen oxides etc..., size and components of particles such as nitrate, sulfate, water soluble organic carbon and black carbon etc..., and meteorological conditions were also measured. During the measurement period, the average of the concentrations of NO2 and HONO were 26.2 ± 13.6 and 1.5 ± 1.1 ppbv, respectively. The concentration variation of HONO was similar with that of NO2, and the moderate correlation between the concentration of HONO and NO2 (R2 = 0.6) was observed. The ratio of the concentration of HONO to that of NO2 ([HONO] / [NO2]) were 0.058, which is comparable with that reported previously. These results imply that the source of HONO in urban area in Tokyo is the heterogeneous reaction of NO2. The analysis of the correlation between the components of aerosol and HONO have been performed and the results will be presented.

  8. Cavity-Enhanced Raman Spectroscopy in the Biosciences: In Situ, Multicomponent, and Isotope Selective Gas Measurements To Study Hydrogen Production and Consumption by Escherichia coli.

    PubMed

    Smith, Thomas W; Hippler, Michael

    2017-02-07

    Recently we introduced cavity-enhanced Raman spectroscopy (CERS) with optical feedback cw-diode lasers as a sensitive analytical tool. Here we report improvements made on the technique and its first application in the biosciences for in situ, multicomponent, and isotope selective gas measurements to study hydrogen production and consumption by Escherichia coli. Under anaerobic conditions, cultures grown on rich media supplemented with d-glucose or glycerol produce H2 and simultaneously consume some of it. By introducing D2 in the headspace, hydrogen production and consumption could be separated due to the distinct spectroscopic signatures of isotopomers. Different phases with distinctly different kinetic regimes of H2 and CO2 production and D2 consumption were identified. Some of the D2 consumed is converted back to H2 via H/D exchange with the solvent. HD was formed only as a minor component. This reflects either that H/D exchange at hydrogenase active sites is rapid compared to the rate of recombination, rapid recapture of HD occurs after the molecule is formed, or that the active sites where D2 oxidation and proton reduction occur are physically separated. Whereas in glucose supplemented cultures, addition of D2 led to an increase in H2 produced, while the yield of CO2 remained unchanged; with glycerol, addition of D2 led not only to increased yields of H2, but also significantly increased CO2 production, reflecting an impact on fermentation pathways. Addition of CO was found to completely inhibit H2 production and significantly reduce D2 oxidation, indicating at least some role for O2-tolerant Hyd-1 in D2 consumption.

  9. Simultaneous generation of 40, 80 and 120 GHz optical millimeter-wave from one Mach-Zehnder modulator and demonstration of millimeter-wave transmission and down-conversion

    NASA Astrophysics Data System (ADS)

    Zhou, Wen; Qin, Chaoyi

    2017-09-01

    We demonstrate multi-frequency QPSK millimeter-wave (mm-wave) vector signal generation enabled by MZM-based optical carrier suppression (OCS) modulation and in-phase/quadrature (I/Q) modulation. We numerically simulate the generation of 40-, 80- and 120-GHz vector signal. Here, the three different signals carry the same QPSK modulation information. We also experimentally realize 11Gbaud/s QPSK vector signal transmission over 20 km fiber, and the generation of the vector signals at 40-GHz, 80-GHz and 120-GHz. The experimental results show that the bit-error-rate (BER) for all the three different signals can reach the forward-error-correction (FEC) threshold of 3.8×10-3. The advantage of the proposed system is that provide high-speed, high-bandwidth and high-capacity seamless access of TDM and wireless network. These features indicate the important application prospect in wireless access networks for WiMax, Wi-Fi and 5G/LTE.

  10. Cooperative down-conversion of UV light in disordered scheelitelike Yb-doped NaGd(MoO4)2 and NaLa(MoO4)2 crystals

    NASA Astrophysics Data System (ADS)

    Subbotin, K. A.; Osipova, Yu. N.; Lis, D. A.; Smirnov, V. A.; Zharikov, E. V.; Shcherbakov, I. A.

    2017-07-01

    Concentration series of disordered scheelitelike Yb:NaGd(MoO4)2 and Yb:NaLa(MoO4)2 single crystals are grown by the Czochralski method. The actual concentrations of Yb3+ ions in the crystals are determined by optical-absorption spectroscopy. The luminescence of Yb3+ ions in these crystals in the region of 1 μm is studied under UV and IR excitation. In the case of UV excitation, this luminescence appears as a result of nonradiative excited state energy transfer from donor centers of unknown nature to ytterbium. The character of the concentration dependence of Yb3+ luminescence indicates that the energy transfer at high Yb concentrations occurs with active participation of a cooperative mechanism, according to which the excitation energy of one donor center is transferred simultaneously to two Yb3+ ions. In other words, the quantum yield of this transfer exceeds unity, which can be used to increase the efficiency of crystalline silicon (c-Si) solar cells.

  11. Water isotope ratio (δ2H and δ18O) measurements in atmospheric moisture using an optical feedback cavity enhanced absorption laser spectrometer

    NASA Astrophysics Data System (ADS)

    Iannone, Rosario Q.; Romanini, Daniele; Cattani, Olivier; Meijer, Harro A. J.; Kerstel, Erik R. Th.

    2010-05-01

    Water vapor isotopes represent an innovative and excellent tool for understanding complex mechanisms in the atmospheric water cycle over different time scales, and they can be used for a variety of applications in the fields of paleoclimatology, hydrology, oceanography, and ecology. We use an ultrasensitive near-infrared spectrometer, originally designed for use on airborne platforms in the upper troposphere and lower stratosphere, to measure the water deuterium and oxygen-18 isotope ratios in situ, in ground-level tropospheric moisture, with a high temporal resolution (from 300 s down to less than 1 s). We present some examples of continuous monitoring of near-surface atmospheric moisture, demonstrating that our infrared laser spectrometer could be used successfully to record high-concentration atmospheric water vapor mixing ratios in continuous time series, with a data coverage of ˜90%, interrupted only for daily calibration to two isotope ratio mass spectrometry-calibrated local water standards. The atmospheric data show that the water vapor isotopic composition exhibits a high variability that can be related to weather conditions, especially to changes in relative humidity. Besides, the results suggest that observed spatial and temporal variations of the stable isotope content of atmospheric water vapor are strongly related to water vapor transport in the atmosphere.

  12. Vacuum effects on interference in two-photon down conversion

    NASA Astrophysics Data System (ADS)

    Ou, Z. Y.; Wang, L. J.; Mandel, L.

    1989-08-01

    A proposed experiment is analyzed theoretically. In the proposed experiment two coherent pump waves fall on two identical nonlinear crystals, down-converted signal and idler beams from the two crystals are mixed by two beam splitters, and the coincidence counting rate for photons leaving the beam splitters is measured. We show that this counting rate depends on the phase difference between the two coherent pump waves, and results from the interference of the vacuum with the down-converted photons. The experiment could be used to look for locality violations along the lines recently proposed by Grangier, Potasek, and Yurke [Phys. Rev. A 38, 3132 (1988)], but without the need for a coherent reference beam for homodyning.

  13. Opto-Microwave Signal Processing: Up and Down Conversion Techniques

    DTIC Science & Technology

    2003-04-01

    introduces the concepts of opto-microwave signal processing used in several communication systems today. Emphasis is placed on optical-microwave up- and...wave optical-wireless local multipoint distribution systems (LMDS), computer or CATV networks. The right answer for all of these challenges is the...division multiple access) system . In a TDMA system the transmitters of the stations are operated on a time sharing basis. In the receivers direct

  14. On the Advanced Wave Model of Parametric Down-Conversion

    NASA Astrophysics Data System (ADS)

    Lvovsky, A. I.; Aichele, T.

    The spatiotemporal optical mode of the single-photon Fock state prepared by conditional measurements on a biphoton is investigated and found to be identical to that of a classical wave due to a nonlinear interaction of the pump wave and Klyshko's advanced wave. We discuss the applicability of this identity in various experimental settings.

  15. Feasibility Study of Using Breath Ammonia Analysis Based on Off-Axis Cavity-Enhanced Absorption Spectroscopy with External Cavity Diode Laser for Noninvasive Real-Time Diagnosis of Helicobacter Pylori.

    PubMed

    Bayrakli, Ismail; Turkmen, Aysenur; Cem Kockar, Muhammet

    2016-08-01

    The purpose of this study is to assess the feasibility of using breath ammonia analysis based on off-axis cavity-enhanced absorption spectroscopy (OA-CEAS) with an external-cavity diode laser (ECL) for noninvasive, real-time diagnosis of Helicobacter pylori (HP) infection. Analyses are performed for the breath of 15 healthy volunteers, and eight children and 19 adults with HP infection. The range of ammonia levels for healthy participants is determined to be between 178 and 610 ppb, whereas the ranges for child and adult patients with HP infection are measured to be 457-2470 ppb and 450-2990 ppb, respectively. The ammonia concentrations for patients with HP infection are significantly higher than the concentrations for healthy volunteers. However, no sharp boundary between the ammonia concentrations in the breath of patients with HP infection and healthy volunteers is observed. No correlation between breath ammonia and either body mass index (BMI) or age is found. The reported results suggest that our breath ammonia measurement system has the potential for future use in easy, noninvasive diagnosis of HP infection. © The Author(s) 2016.

  16. Frequency-feedback cavity enhanced spectrometer

    SciTech Connect

    Hovde, David Christian; Gomez, Anthony

    2015-08-18

    A spectrometer comprising an optical cavity, a light source capable of producing light at one or more wavelengths transmitted by the cavity and with the light directed at the cavity, a detector and optics positioned to collect light transmitted by the cavity, feedback electronics causing oscillation of amplitude of the optical signal on the detector at a frequency that depends on cavity losses, and a sensor measuring the oscillation frequency to determine the cavity losses.

  17. Nonlocality of high-dimensional two-photon orbital angular momentum states

    SciTech Connect

    Aiello, A.; Oemrawsingh, S. S. R.; Eliel, E. R.; Woerdman, J. P.

    2005-11-15

    We propose an interferometric method to investigate the nonlocality of high-dimensional two-photon orbital angular momentum states generated by spontaneous parametric down conversion. We incorporate two half-integer spiral phase plates and a variable-reflectivity output beam splitter into a Mach-Zehnder interferometer to build an orbital angular momentum analyzer. This setup enables testing the nonlocality of high-dimensional two-photon states by repeated use of the Clauser-Horne-Shimony-Holt inequality.

  18. Highly efficient heralding of entangled single photons.

    PubMed

    Ramelow, Sven; Mech, Alexandra; Giustina, Marissa; Gröblacher, Simon; Wieczorek, Witlef; Beyer, Jörn; Lita, Adriana; Calkins, Brice; Gerrits, Thomas; Nam, Sae Woo; Zeilinger, Anton; Ursin, Rupert

    2013-03-25

    Single photons are an important prerequisite for a broad spectrum of quantum optical applications. We experimentally demonstrate a heralded single-photon source based on spontaneous parametric down-conversion in collinear bulk optics, and fiber-coupled bolometric transition-edge sensors. Without correcting for background, losses, or detection inefficiencies, we measure an overall heralding efficiency of 83%. By violating a Bell inequality, we confirm the single-photon character and high-quality entanglement of our heralded single photons which, in combination with the high heralding efficiency, are a necessary ingredient for advanced quantum communication protocols such as one-sided device-independent quantum key distribution.

  19. Narrowing of the linewidth of an optical parametric oscillator by an acousto-optic modulator for the realization of mid-IR noise-immune cavity-enhanced optical heterodyne molecular spectrometry down to 10⁻¹⁰ cm⁻¹ Hz⁻¹/².

    PubMed

    Hausmaninger, Thomas; Silander, Isak; Axner, Ove

    2015-12-28

    The linewidth of a singly resonant optical parametric oscillator (OPO) has been narrowed with respect to an external cavity by the use of an acousto-optic modulator (AOM). This made possible an improvement of the sensitivity of a previously realized OPO-based noise-immune cavity-enhanced optical heterodyne molecular spectrometry instrument for the 3.2 - 3.9 µm mid-infrared region by one order of magnitude. The resulting system shows a detection sensitivity for methane of 2.4 × 10(-10) cm(-1) Hz(-1∕2) and 1.3 × 10(-10) cm(-1) at 20 s, which allows for detection of both the environmentally important (13)CH(4) and CH(3)D isotopologues in atmospheric samples.

  20. Experimental demonstration of four-photon entanglement and high-fidelity teleportation.

    PubMed

    Pan, J W; Daniell, M; Gasparoni, S; Weihs, G; Zeilinger, A

    2001-05-14

    We experimentally demonstrate observation of highly pure four-photon GHZ entanglement produced by parametric down-conversion and a projective measurement. At the same time this also demonstrates teleportation of entanglement with very high purity. Not only does the achieved high visibility enable various novel tests of quantum nonlocality, it also opens the possibility to experimentally investigate various quantum computation and communication schemes with linear optics. Our technique can, in principle, be used to produce entanglement of arbitrarily high order or, equivalently, teleportation and entanglement swapping over multiple stages.

  1. Artificial cavities enhance breeding bird densities in managed cottonwood forests

    USGS Publications Warehouse

    Twedt, D.J.; Henne-Kerr, J.L.

    2001-01-01

    The paucity of natural cavities within short-rotation hardwood agroforests restricts occupancy by cavity-nesting birds. However, providing 1.6 artificial nesting cavities (nest boxes)/ha within 3- to 10-year-old managed cottonwood forests in the Mississippi Alluvial Valley increased territory density of cavity-nesting birds. Differences in territory densities between forests with and without nest boxes increased as stands aged. Seven bird species initiated 38 nests in 173 boxes during 1997 and 39 nests in 172 boxes during 1998. Prothonotary warblers (Protonotaria citrea) and eastern bluebirds (Sialia sialis) accounted for 67% of nests; nearly all warbler nests were in 1.8-L, plastic-coated cardboard (paper) boxes, whereas bluebird nests were divided between paper boxes and 3.5-L wooden boxes. Larger-volume (16.5-L) wooden nest boxes were used by eastern screech owls (Otus asio) and great crested flycatchers (Myiarchus crinitus), but this box type often was usurped by honey bees (Apis mellifera). To enhance territory densities of cavity-nesting birds in cottonwood agroforests, we recommend placement of plastic-coated paper nest boxes, at a density of 0.5/ha, after trees are >4 years old but at least 2 years before anticipated timber harvest.

  2. Cavity-enhanced coherent light scattering from a quantum dot

    PubMed Central

    Bennett, Anthony J.; Lee, James P.; Ellis, David J. P.; Meany, Thomas; Murray, Eoin; Floether, Frederik F.; Griffths, Jonathan P.; Farrer, Ian; Ritchie, David A.; Shields, Andrew J.

    2016-01-01

    The generation of coherent and indistinguishable single photons is a critical step for photonic quantum technologies in information processing and metrology. A promising system is the resonant optical excitation of solid-state emitters embedded in wavelength-scale three-dimensional cavities. However, the challenge here is to reject the unwanted excitation to a level below the quantum signal. We demonstrate this using coherent photon scattering from a quantum dot in a micropillar. The cavity is shown to enhance the fraction of light that is resonantly scattered toward unity, generating antibunched indistinguishable photons that are 16 times narrower than the time-bandwidth limit, even when the transition is near saturation. Finally, deterministic excitation is used to create two-photon N00N states with which we make superresolving phase measurements in a photonic circuit. PMID:27152337

  3. Isotopic gas analysis through Purcell cavity enhanced Raman scattering

    SciTech Connect

    Petrak, B.; Konthasinghe, K.; Peiris, M.; Muller, A.; Cooper, J.; Hopkins, A. J.; Djeu, N.

    2016-02-29

    Purcell enhanced Raman scattering (PERS) by means of a doubly resonant Fabry-Perot microcavity (mode volume ≈ 100 μm{sup 3} and finesse ≈ 30 000) has been investigated as a technique for isotopic ratio gas analysis. At the pump frequency, the resonant cavity supports a buildup of circulating power while simultaneously enabling Purcell spontaneous emission rate enhancement at the resonant Stokes frequency. The three most common isotopologues of CO{sub 2} gas were quantified, and a signal was obtained from {sup 13}C{sup 16}O{sub 2} down to a partial pressure of 2 Torr. Due to its small size and low pump power needed (∼10 mW) PERS lends itself to miniaturization. Furthermore, since the cavity is resonant with the emission frequency, future improvements could allow it to serve as its own spectral analyzer and no separate spectroscopic device would be needed.

  4. Cavity-enhanced coherent light scattering from a quantum dot.

    PubMed

    Bennett, Anthony J; Lee, James P; Ellis, David J P; Meany, Thomas; Murray, Eoin; Floether, Frederik F; Griffths, Jonathan P; Farrer, Ian; Ritchie, David A; Shields, Andrew J

    2016-04-01

    The generation of coherent and indistinguishable single photons is a critical step for photonic quantum technologies in information processing and metrology. A promising system is the resonant optical excitation of solid-state emitters embedded in wavelength-scale three-dimensional cavities. However, the challenge here is to reject the unwanted excitation to a level below the quantum signal. We demonstrate this using coherent photon scattering from a quantum dot in a micropillar. The cavity is shown to enhance the fraction of light that is resonantly scattered toward unity, generating antibunched indistinguishable photons that are 16 times narrower than the time-bandwidth limit, even when the transition is near saturation. Finally, deterministic excitation is used to create two-photon N00N states with which we make superresolving phase measurements in a photonic circuit.

  5. Cavity-Enhanced Measurements of Defect Spins in Silicon Carbide

    NASA Astrophysics Data System (ADS)

    Calusine, Greg; Politi, Alberto; Awschalom, David D.

    2016-07-01

    The identification of new solid-state defect-qubit candidates in widely used semiconductors has the potential to enable the use of nanofabricated devices for enhanced qubit measurement and control operations. In particular, the recent discovery of optically active spin states in silicon carbide thin films offers a scalable route for incorporating defect qubits into on-chip photonic devices. Here, we demonstrate the use of 3C silicon carbide photonic crystal cavities for enhanced excitation of color-center defect spin ensembles in order to increase measured photoluminescence signal count rates, optically detected magnetic-resonance signal intensities, and optical spin initialization rates. We observe an up to a factor of 30 increase in the photoluminescence and optically detected magnetic-resonance signals from Ky5 color centers excited by cavity-resonant excitation and increase the rate of ground-state spin initialization by approximately a factor of 2. Furthermore, we show that the 705-fold reduction in excitation mode volume and enhanced excitation and collection efficiencies provided by the structures can be used to overcome inhomogenous broadening in order to facilitate the study of defect-qubit subensemble properties. These results highlight some of the benefits that nanofabricated devices offer for engineering the local photonic environment of color-center defect qubits to enable applications in quantum information and sensing.

  6. Measurement of aerosol optical properties by cw cavity enhanced spectroscopy

    NASA Astrophysics Data System (ADS)

    Jie, Guo; Ye, Shan-Shan; Yang, Xiao; Han, Ye-Xing; Tang, Huai-Wu; Yu, Zhi-Wei

    2016-10-01

    The CAPS (Cavity Attenuated Phase shift Spectroscopy) system, which detects the extinction coefficients within a 10 nm bandpass centered at 532 nm, comprises a green LED with center wavelength in 532nm, a resonant optical cavity (36 cm length), a Photo Multiplier Tube detector, and a lock in amplifier. The square wave modulated light from the LED passes through the optical cavity and is detected as a distorted waveform which is characterized by a phase shift with respect to the initial modulation. Extinction coefficients are determined from changes in the phase shift of the distorted waveform of the square wave modulated LED light that is transmitted through the optical cavity. The performance of the CAPS system was evaluated by using measurements of the stability and response of the system. The minima ( 0.1 Mm-1) in the Allan plots show the optimum average time ( 100s) for optimum detection performance of the CAPS system. In the paper, it illustrates that extinction coefficient was correlated with PM2.5 mass (0.91). These figures indicate that this method has the potential to become one of the most sensitive on-line analytical techniques for extinction coefficient detection. This work aims to provide an initial validation of the CAPS extinction monitor in laboratory and field environments. Our initial results presented in this paper show that the CAPS extinction monitor is capable of providing state-of-the-art performance while dramatically reducing the complexity of optical instrumentation for directly measuring the extinction coefficients.

  7. Purcell enhancement of fast-dephasing spontaneous emission from electron-hole droplets in high-Q silicon photonic crystal nanocavities

    NASA Astrophysics Data System (ADS)

    Sumikura, Hisashi; Kuramochi, Eiichi; Taniyama, Hideaki; Notomi, Masaya

    2016-11-01

    We have observed electron-hole droplet emission enhanced by silicon photonic crystal nanocavities with different Q values and simulated their Purcell effect using a semiclassical theory considering the temporal dephasing of the emission. When the photon loss rate of the nanocavities is smaller than the dephasing rate of the emission, the cavity-enhanced integrated photoluminescence (PL) intensity is unchanged by the cavity Q value. This is because the Purcell enhancement of the spontaneous emission rate is saturated in a high-Q region. In contrast, the peak intensity of the cavity-enhanced PL is proportional to the cavity Q value without saturation. These results suggest that a high-Q nanocavity is suitable for fabricating bright narrowband light emitting devices that concentrate the broadband emission energy of fast-dephasing emitters in a narrowband cavity resonance.

  8. Intracavity Spontaneous Parametric Down-Conversion in Bragg Reflection Waveguide Edge Emitting Diode

    NASA Astrophysics Data System (ADS)

    Wei, Si-Hang; Shang, Xiang-Jun; Ma, Ben; Chen, Ze-Sheng; Liao, Yong-Ping; Ni, Hai-Qiao; Niu, Zhi-Chuan

    2017-07-01

    Not Available Supported by the National Key Basic Research Program of China under Grant Nos 2013CB933304 and 2014CB643904, the National Natural Science Foundation of China under Grant Nos 61435012 and 61274125, and the Strategic Priority Research Program (B) of Chinese Academy of Sciences under Grant No XDB01010200.

  9. Theoretical Efficiency of 3rd Generation Solar Cells: Comparison between Carrier Multiplication and Down-Conversion

    DTIC Science & Technology

    2012-01-01

    isolate the chemical potential using the Ruppel and Würfel photon flux method [19], which is a rephrasing of Kirchh- off’s law of radiation [16] using...circuit conditions, using the Ruppel and Würfel relation [19], the outgoing emission equals the incoming absorption (Kirchhoff’s law of radiation...ary that the Ruppel –Würfel photon flux method [19] uses must be Z.R. Abrams et al. / Solar Energy Materials & Solar Cells ] (

  10. Qutrits and ququarts in spontaneous parametric down-conversion, correlations and entanglement

    SciTech Connect

    Fedorov, M. V. Volkov, P. A.; Milhailova, J. M.

    2012-07-15

    We investigate features of biphoton qutrits and ququarts with the symmetry of biphoton wavefunctions fully taken into account. Entanglement quantifiers of such states are found as functions of qutrit and ququart parameters. For biphoton qutrits, a general relation between degrees of entanglement and polarization is established. In the case of biphoton ququarts, photon frequencies are considered as variables independent of polarization variables, with both polarization and frequency degrees of freedom equally contributing to the total ququart entanglement. Averaging over one of these two degrees of freedom is shown to reduce pure ququart states to mixed two-qubit states. The degree of polarization and degrees of correlations in mixed polarization states are investigated.

  11. Multipli-Entangled Photons from a Spontaneous Parametric Down-Conversion Source

    DTIC Science & Technology

    2011-01-01

    Alsing, Corey J. Peters (AFRL/RITA); Enrique J. Galvez ( Colgate University, Hamilton, NY) 5d. PROJECT NUMBER QIS0 5e. TASK NUMBER PR 5f...and Enrique J. Galvez Colgate University, Hamilton, NY (USA) 1. ABSTRACT In this work, we discuss a novel compact source that generates six

  12. Radio-Frequency Down-Conversion via Sampled Analog Optical Links

    DTIC Science & Technology

    2010-08-09

    derived from one arm of the MZM. Note, the complementary nature of the modulation between the outputs allows the use of balanced detection for noise...photodiode. The first term in (6) represents the spectral contribution arising solely from photodetection of the optical carrier. The spectrum of the...from an optical amplifier). Note, this contribution to the RF spectrum is common-mode to both outputs and, therefore, may be suppressed via balanced

  13. Optoelectronic Components and Integrated Circuits Including Up and Down Conversion Technique and Hybrid Integration Technology

    DTIC Science & Technology

    2003-04-01

    solutions are also possible with (commercially available) DFB laser integrated with an electroabsorption modulator. 1-14 Another monolithic possible solution...discuss the monolithic integration of optoelectronic or photonic devices, recalling that the industrial way is based on hybrid technology on silicon...the integration (hybrid versus monolithic ) of components and circuits. 2. Emitters There is a lot of techniques to generate a microwave or millimetre

  14. Measurement of precision oscillator phase noise using the two-oscillator coherent down-conversion technique

    NASA Technical Reports Server (NTRS)

    Pagnanelli, Christopher J.; Cashin, William F.

    1992-01-01

    The characterization of precision frequency standard phase noise and spurious outputs is addressed, using the two-oscillator coherent downconversion technique. Focus is on techniques for making accurate measurements of phase noise and spurious outputs within 100 KHz of a carrier. Significant sources of measurement error related to hardware design problems and inadequate measurement procedures are discussed: measurement errors resulting from system noise sources, phase-locked loop effects, and system bandwidth limitations. In addition, methods and design considerations for minimizing the effects of such errors are presented. Analytic discussions and results are supplemented with actual test data and measurements made using measurement hardware developed at the Ball Corporation, Efratom Division.

  15. Photonic RF-IF wideband down conversion using optical injection locking

    NASA Astrophysics Data System (ADS)

    Adleman, James R.; Lin, Chunyan L.; Jester, Shai B.; Pascoguin, B. M.; Evans, Douglass C.; Jacobs, Everett W.

    2015-05-01

    We describe the implementation of a self-heterodyne, tunable down converting RF-IF photonic link as a key component of a wideband microwave signal search and intercept system covering S to Ka bands. The presented architecture uses photomixing of two distributed feedback lasers injection locked to a master external cavity laser, allowing low phase to amplitude noise conversion and improved sensitivity. Coherent detection of the intermediate frequency allows unambiguous recovery of full time-domain information. The practical implementation of a packaged prototype system will be discussed, with emphasis on the system stabilization strategy and performance requirements.

  16. Ultra-broadband microwave frequency down-conversion based on optical frequency comb.

    PubMed

    Fang, Xiao; Bai, Ming; Ye, Xiuzhu; Miao, Jungang; Zheng, Zheng

    2015-06-29

    Based on optical frequency comb (OFC), a photonic-assisted ultra-broadband microwave signal down-converting method is proposed. In the proposed scheme, microwave signal at 2~20GHz can be down-converted to 0~1GHz intermediate frequency (IF) signals by an OFC of 2GHz frequency space at different order of comb lines. By slightly switching the frequency space of OFC, the frequency of the signal to be measured can be retrieved through the frequency shift of the down-converted IF signal. The validity of this proposed unknown signal detection method is verified by the experiments. The proposed method is proven to be flexible, low-cost and easily implemented, which requires only a low-frequency tunable microwave source while provides ultra-broadband down-converting frequency range.

  17. Highly efficient CdS-quantum-dot-sensitized GaAs solar cells.

    PubMed

    Lin, Chien-Chung; Chen, Hsin-Chu; Tsai, Yu Lin; Han, Hau-Vei; Shih, Huai-Shiang; Chang, Yi-An; Kuo, Hao-Chung; Yu, Peichen

    2012-03-12

    We demonstrate a hybrid design of traditional GaAs-based solar cell combined with colloidal CdS quantum dots. With anti-reflective feature at long wavelength and down-conversion at UV regime, the CdS quantum dot effectively enhance the overall power conversion efficiency by as high as 18.9% compared to traditional GaAs-based device. A more detailed study showed an increase of surface photoconductivity due to UV presence, and the fill factor of the solar cell can be improved accordingly.

  18. A high-brightness source of polarization-entangled photons optimized for applications in free space.

    PubMed

    Steinlechner, Fabian; Trojek, Pavel; Jofre, Marc; Weier, Henning; Perez, Daniel; Jennewein, Thomas; Ursin, Rupert; Rarity, John; Mitchell, Morgan W; Torres, Juan P; Weinfurter, Harald; Pruneri, Valerio

    2012-04-23

    We present a simple but highly efficient source of polarization-entangled photons based on spontaneous parametric down-conversion (SPDC) in bulk periodically poled potassium titanyl phosphate crystals (PPKTP) pumped by a 405 nm laser diode. Utilizing one of the highest available nonlinear coefficients in a non-degenerate, collinear type-0 phase-matching configuration, we generate polarization entanglement via the crossed-crystal scheme and detect 0.64 million photon pair events/s/mW, while maintaining an overlap fidelity with the ideal Bell state of 0.98 at a pump power of 0.025 mW.

  19. High speed readout electronics development for frequency-multiplexed kinetic inductance detector design optimization

    NASA Astrophysics Data System (ADS)

    Bourrion, O.; Vescovi, C.; Catalano, A.; Calvo, M.; D'Addabbo, A.; Goupy, J.; Boudou, N.; Macias-Perez, J. F.; Monfardini, A.

    2013-12-01

    Microwave Kinetic Inductance Detectors (MKID) are a promising solution for space-borne mm-wave astronomy. To optimize their design and make them insensitive to the ballistic phonons created by cosmic-ray interactions in the substrate, the phonon propagation in silicon must be studied. A dedicated fast readout electronics, using channelized Digital Down Conversion for monitoring up to 12 MKIDs over a 100 MHz bandwidth was developed. Thanks to the fast ADC sampling and steep digital filtering, In-phase and Quadrature samples, having a high dynamic range, are provided at ~ 2 Msps. This paper describes the technical solution chosen and the results obtained.

  20. Method to generate high efficient devices which emit high quality light for illumination

    DOEpatents

    Krummacher, Benjamin C.; Mathai, Mathew; Choong, Vi-En; Choulis, Stelios A.

    2009-06-30

    An electroluminescent apparatus includes an OLED device emitting light in the blue and green spectrums, and at least one down conversion layer. The down conversion layer absorbs at least part of the green spectrum light and emits light in at least one of the orange spectra and red spectra.

  1. Maintaining high-Q in an optical microresonator coated with high-aspect-ratio gold nanorods

    NASA Astrophysics Data System (ADS)

    Ganta, D.; Dale, E. B.; Rosenberger, A. T.

    2013-10-01

    We report methods to coat fused-silica microresonators with solution-grown high-aspect-ratio (AR) gold nanorods (NRs). Microresonators coated using our method maintain an optical quality factor (Q) greater than 107 after coating. The more successful method involves silanization of the surface of the microresonator with 3-mercaptopropylmethyldimethoxysilane (MPMDMS), to enable the adhesion of gold NRs. The high-AR NR-coated microresonator combines the field enhancement of localized surface plasmon resonances with the cavity-enhanced evanescent components of high-Q whispering-gallery modes, making it useful for plasmonic sensing applications in the infrared. By coating with NRs having a different aspect ratio, the enhancement regime can be selected within a wide range of wavelengths.

  2. High-dimensional quantum nature of ghost angular Young's diffraction

    SciTech Connect

    Chen Lixiang; Leach, Jonathan; Jack, Barry; Padgett, Miles J.; Franke-Arnold, Sonja; She Weilong

    2010-09-15

    We propose a technique to characterize the dimensionality of entangled sources affected by any environment, including phase and amplitude masks or atmospheric turbulence. We illustrate this technique on the example of angular ghost diffraction using the orbital angular momentum (OAM) spectrum generated by a nonlocal double slit. We realize a nonlocal angular double slit by placing single angular slits in the paths of the signal and idler modes of the entangled light field generated by parametric down-conversion. Based on the observed OAM spectrum and the measured Shannon dimensionality spectrum of the possible quantum channels that contribute to Young's ghost diffraction, we calculate the associated dimensionality D{sub total}. The measured D{sub total} ranges between 1 and 2.74 depending on the opening angle of the angular slits. The ability to quantify the nature of high-dimensional entanglement is vital when considering quantum information protocols.

  3. Low Noise and Highly Linear Wideband CMOS RF Front-End for DVB-H Direct-Conversion Receiver

    NASA Astrophysics Data System (ADS)

    Nam, Ilku; Moon, Hyunwon; Woo, Doo Hyung

    In this paper, a wideband CMOS radio frequency (RF) front-end for digital video broadcasting-handheld (DVB-H) receiver is proposed. The RF front-end circuit is composed of a single-ended resistive feedback low noise amplifier (LNA), a single-to-differential amplifier, an I/Q down-conversion mixer with linearized transconductors employing third order intermodulation distortion cancellation, and a divide-by-two circuit with LO buffers. By employing a third order intermodulation (IMD3) cancellation technique and vertical NPN bipolar junction transistor (BJT) switching pair for an I/Q down-conversion mixer, the proposed RF front-end circuit has high linearity and low low-frequency noise performance. It is fabricated in a 0.18µm deep n-well CMOS technology and draws 12mA from a 1.8V supply voltage. It shows a voltage gain of 31dB, a noise figure (NF) lower than 2.6dB, and an IIP3 of -8dBm from 470MHz to 862MHz.

  4. Towards Quantum Teleportation Between a Photonic Qubit and a Quantum Dot Spin State

    NASA Astrophysics Data System (ADS)

    Wong, Jia Jun; Yang, Jian; Kwiat, Paul

    2015-05-01

    Quantum teleportation plays a vital role in quantum computation and communication, as it provides an interface between dissimilar qubits, allowing the possibility to exploit experimental advantages presented in different quantum systems. For example, a quantum dot spin qubit can be used for long storage time while a telecom wavelength photonic qubit can be used for robust information transfer between distant parties. Here we are developing a narrowband single-photon source with the aim of demonstrating quantum teleportation of a photonic state to a quantum dot spin state. To ensure high indistinguishability between the photon sources, cavity-enhanced spontaneous parametric down-conversion is used to generate narrowband photons of 200 MHz, matching the entangled spin-photon state emitted from the quantum dot. The source cavity mainly consists of three optical components in sequence, type-II nonlinear crystal (PPKTP), a KTP crystal for double-resonance tuning and a concave output coupler. By placing a polarizing beam splitter after the source, a single photon can be heralded at an expected rate of 13 kHz. To achieve high fidelity, an electro-optic modulator can be used to match the frequencies of the down-conversion and quantum dot photons.

  5. High power narrowband 589 nm frequency doubled fibre laser source.

    PubMed

    Taylor, Luke; Feng, Yan; Calia, Domenico Bonaccini

    2009-08-17

    We demonstrate high-power high-efficiency cavity-enhanced second harmonic generation of an in-house built ultra-high spectral density (SBS-suppressed) 1178 nm narrowband Raman fibre amplifier. Up to 14.5 W 589 nm CW emission is achieved with linewidth Delta nu(589) < 7 MHz in a diffraction-limited beam, with peak external conversion efficiency of 86%. The inherently high spectral and spatial qualities of the 589 nm source are particularly suited to both spectroscopic and Laser Guide Star applications, given the seed laser can be easily frequency-locked to the Na D(2a) emission line. Further, we expect the technology to be extendable, at similar or higher powers, to wavelengths limited only by the seed-pump-pair availability. (c) 2009 Optical Society of America

  6. A 2-GHz Low-Power Down-Conversion Mixer in 0.18-μm CMOS Technology

    NASA Astrophysics Data System (ADS)

    Chen, Jun-Da; Lin, Zhi-Ming; Row, Jeen-Sheen

    A low-voltage and low-power RF mixer for WCDMA applications is presented. The paper presents a novel topology mixer that leads to a better performance in terms of isolation and power consumption for low supply voltage. The measuring results of the proposed mixer achieve: 7dB power conversion gain, 10.4dB double side band (DSB) noise figure, -2dBm input third-order intercept point (IIP3), and the total dc power consumption of this mixer including output buffers is 2.2mW from a 1V supply voltage. The current output buffer is about 1.96mW, the excellent LO-RF, LO-IF and RF-IF isolation achieved up to 49dB, 39.5dB and 57.3dB, respectively.

  7. Introduction to the transverse spatial correlations in spontaneous parametric down-conversion through the biphoton birth zone

    NASA Astrophysics Data System (ADS)

    Schneeloch, James; Howell, John C.

    2016-05-01

    As a tutorial to the spatial aspects of spontaneous parametric downconversion (SPDC), we present a detailed first-principles derivation of the transverse correlation width of photon pairs in degenerate collinear SPDC. This width defines the size of a biphoton birth zone, the region where the signal and idler photons are likely to be found when conditioning on the position of the destroyed pump photon. Along the way, we discuss the quantum-optical calculation of the amplitude for the SPDC process, as well as its simplified form for nearly collinear degenerate phase matching. Following this, we show how this biphoton amplitude can be approximated with a double-Gaussian wavefunction, and give a brief discussion of the measurement statistics (and subsequent convenience) of such double-Gaussian wavefunctions. Next, we use this approximation to get a simplified estimation of the transverse correlation width, and compare it to more accurate calculations as well as experimental results. We then conclude with a discussion of the concept of a biphoton birth zone, using it to develop intuition for the tradeoff between the first-order spatial coherence and bipohoton correlations in SPDC.

  8. Generating Periodic Terahertz Structures in a Relativistic Electron Beam through Frequency Down-Conversion of Optical Lasers

    SciTech Connect

    Dunning, Michael

    2012-07-19

    We report generation of density modulation at terahertz (THz) frequencies in a relativistic electron beam through laser modulation of the beam longitudinal phase space. We show that by modulating the energy distribution of the beam with two lasers, density modulation at the difference frequency of the two lasers can be generated after the beam passes through a chicane. In this experiment, density modulation around 10 THz was generated by down-converting the frequencies of an 800 nm laser and a 1550 nm laser. The central frequency of the density modulation can be tuned by varying the laser wavelengths, beam energy chirp, or momentum compaction of the chicane. This technique can be applied to accelerator-based light sources for generation of coherent THz radiation and marks a significant advance toward tunable narrow-band THz sources.

  9. Time-Resolved Down-Conversion of 2-Aminopurine in a DNA Hairpin: Fluorescence Anisotropy and Solvent Effects

    NASA Astrophysics Data System (ADS)

    Tourón Touceda, Patricia; Gelot, Thomas; Crégut, Olivier; Léonard, Jérémie; Haacke, Stefan

    2013-03-01

    Femtosecond fluorescence anisotropy decay measured by type II difference frequency generation provides new insight into the local structural dynamics of ΔP(-)PBS fragments of the HIV- 1 DNA primary binding sequence, labeled with 2-aminopurine.

  10. On the Measurement of Two-Photon Single-Mode Coupling Efficiency in Parametric Down-Conversion Photon Sources

    DTIC Science & Technology

    2004-04-01

    could be used to differentiate between the two models. Acknowledgments This work was supported in part by DARPA/ QUIST , ARDA and ARO and partially by...Oberparleiter M and Weinfurter H 2001 Phys. Rev. A 6402 023802 [23] Bovino F A, Varisco P, Colla A M, Castagnoli G, Di Giuseppe G and Sergienko A V 2003

  11. Constructing Interfacial Energy Transfer for Photon Up- and Down-Conversion from Lanthanides in a Core-Shell Nanostructure.

    PubMed

    Zhou, Bo; Tao, Lili; Chai, Yang; Lau, Shu Ping; Zhang, Qinyuan; Tsang, Yuen Hong

    2016-09-26

    We report a new mechanistic strategy for controlling and modifying the photon emission of lanthanides in a core-shell nanostructure by using interfacial energy transfer. By taking advantage of this mechanism with Gd(3+) as the energy donor, we have realized efficient up- and down-converted emissions from a series of lanthanide emitters (Eu(3+) , Tb(3+) , Dy(3+) , and Sm(3+) ) in these core-shell nanoparticles, which do not need a migratory host sublattice. Moreover, we have demonstrated that the Gd(3+) -mediated interfacial energy transfer, in contrast to energy migration, is the leading process contributing to the photon emission of lanthanide dopants for the NaGdF4 @NaGdF4 core-shell system. Our finding suggests a new direction for research into better control of energy transfer at the nanometer length scale, which would help to stimulate new concepts for designing and improving photon emission of the lanthanide-based luminescent materials. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Efficient THz Source Based on Cascaded Optical Down-Conversion in Orientation-Patterned GaAs Structures

    DTIC Science & Technology

    2006-12-29

    With an optimized OPO cavity we expect to generate 8 cascades and beat Manley-Rowe limit by about the same factor . TRAINING OF GRADUATE STUDENTS: At...and (ii) orientation-patterned GaAs (OP-GaAs). N = LIA grating periods N THz periods A T THz THz Vf- Vph (THZ) , optical I __ _ _v 2=vg/opt) L Fig.5...both peaks are comparable. Efficiency reduction (1/32) 9 due to the 3 rd order QPM is offset by the VT1 1 z 2 factor which appears in the expression

  13. Twin photon pairs in a high-Q silicon microresonator

    NASA Astrophysics Data System (ADS)

    Rogers, Steven; Lu, Xiyuan; Jiang, Wei C.; Lin, Qiang

    2015-07-01

    We report the generation of high-purity twin photon pairs through cavity-enhanced non-degenerate four-wave mixing (FWM) in a high-Q silicon microdisk resonator. Twin photon pairs are created within the same cavity mode and are consequently expected to be identical in all degrees of freedom. The device is able to produce twin photons at telecommunication wavelengths with a pair generation rate as large as (3.96 ± 0.03) × 105 pairs/s, within a narrow bandwidth of 0.72 GHz. A coincidence-to-accidental ratio of 660 ± 62 was measured, the highest value reported to date for twin photon pairs, at a pair generation rate of (2.47 ± 0.04) × 104 pairs/s. Through careful engineering of the dispersion matching window, we have reduced the ratio of photons resulting from degenerate FWM to non-degenerate FWM to less than 0.15.

  14. High visibility Hong-Ou-Mandel interference via a time-resolved coincidence measurement

    NASA Astrophysics Data System (ADS)

    Tsujimoto, Yoshiaki; Sugiura, Yukihiro; Tanaka, Motoki; Ikuta, Rikizo; Miki, Shigehito; Yamashita, Taro; Terai, Hirotaka; Fujiwara, Mikio; Yamamoto, Takashi; Koashi, Masato; Sasaki, Masahide; Imoto, Nobuyuki

    2017-05-01

    We report on the observation of a high visibility Hong-Ou-Mandel interference of two heralded photons emitted from a spontaneous parametric down conversion~(SPDC) pumped by continuous-wave~(cw) light. A non-degenerate photon pair at 1541~nm and 1580~nm is generated by cw-pumped SPDC through a periodically poled lithium niobate waveguide. The heralded single photon at 1541~nm is prepared by the detection of the photon at 1580~nm. We performed the experiment of the Hong-Ou-Mandel interference between heralded single photons in separated time bins and observed a high visibility interference. All detectors we used are superconducting nanowire single-photon detectors and an overall temporal resolution of the photon detection is estimated as 85 ps, which is sufficiently shorter than the coherence time of the heralded photons.

  15. High-resolution multi-heterodyne spectroscopy based on Fabry-Perot quantum cascade lasers

    SciTech Connect

    Wang, Yin; Wang, Wen; Wysocki, Gerard; Soskind, Michael G.

    2014-01-20

    In this Letter, we present a method of performing broadband mid-infrared spectroscopy with conventional, free-running, continuous wave Fabry-Perot quantum cascade lasers (FP-QCLs). The measurement method is based on multi-heterodyne down-conversion of optical signals. The sample transmission spectrum probed by one multi-mode FP-QCL is down-converted to the radio-frequency domain through an optical multi-heterodyne process using a second FP-QCL as the local oscillator. Both a broadband multi-mode spectral measurement as well as high-resolution (∼15 MHz) spectroscopy of molecular absorption are demonstrated and show great potential for development of high performance FP-laser-based spectrometers for chemical sensing.

  16. High-capacity quantum key distribution using Chebyshev-map values corresponding to Lucas numbers coding

    NASA Astrophysics Data System (ADS)

    Lai, Hong; Orgun, Mehmet A.; Pieprzyk, Josef; Li, Jing; Luo, Mingxing; Xiao, Jinghua; Xiao, Fuyuan

    2016-11-01

    We propose an approach that achieves high-capacity quantum key distribution using Chebyshev-map values corresponding to Lucas numbers coding. In particular, we encode a key with the Chebyshev-map values corresponding to Lucas numbers and then use k-Chebyshev maps to achieve consecutive and flexible key expansion and apply the pre-shared classical information between Alice and Bob and fountain codes for privacy amplification to solve the security of the exchange of classical information via the classical channel. Consequently, our high-capacity protocol does not have the limitations imposed by orbital angular momentum and down-conversion bandwidths, and it meets the requirements for longer distances and lower error rates simultaneously.

  17. High-dimensional quantum key distribution with the entangled single-photon-added coherent state

    NASA Astrophysics Data System (ADS)

    Wang, Yang; Bao, Wan-Su; Bao, Hai-Ze; Zhou, Chun; Jiang, Mu-Sheng; Li, Hong-Wei

    2017-04-01

    High-dimensional quantum key distribution (HD-QKD) can generate more secure bits for one detection event so that it can achieve long distance key distribution with a high secret key capacity. In this Letter, we present a decoy state HD-QKD scheme with the entangled single-photon-added coherent state (ESPACS) source. We present two tight formulas to estimate the single-photon fraction of postselected events and Eve's Holevo information and derive lower bounds on the secret key capacity and the secret key rate of our protocol. We also present finite-key analysis for our protocol by using the Chernoff bound. Our numerical results show that our protocol using one decoy state can perform better than that of previous HD-QKD protocol with the spontaneous parametric down conversion (SPDC) using two decoy states. Moreover, when considering finite resources, the advantage is more obvious.

  18. Experimental Investigation of a Broadband High-Temperature Superconducting Terahertz Mixer Operating at Temperatures Between 40 and 77 K

    NASA Astrophysics Data System (ADS)

    Gao, Xiang; Du, Jia; Zhang, Ting; Jay Guo, Y.; Foley, Cathy P.

    2017-07-01

    This paper presents a systematic investigation of a broadband thin-film antenna-coupled high-temperature superconducting (HTS) terahertz (THz) harmonic mixer at relatively high operating temperature from 40 to 77 K. The mixer device chip was fabricated using the CSIRO established step-edge YBa2Cu3O7-x (YBCO) Josephson junction technology, packaged in a well-designed module and cooled in a temperature adjustable cryocooler. Detailed experimental characterizations were carried out for the broadband HTS mixer at both the 200 and 600 GHz bands in harmonic mixing mode. The DC current-voltage characteristics (IVCs), bias current condition, local oscillator (LO) power requirement, frequency response, as well as conversion efficiency under different bath temperatures were thoroughly investigated for demonstrating the frequency down-conversion performance.

  19. A wideband terahertz high-T c superconducting Josephson-junction mixer: electromagnetic design, analysis and characterization

    NASA Astrophysics Data System (ADS)

    Gao, Xiang; Zhang, Ting; Du, Jia; Weily, Andrew R.; Guo, Yingjie Jay; Foley, Cathy P.

    2017-09-01

    This paper presents a wideband terahertz (THz) mixer based on a thin-film antenna-coupled high-temperature superconducting (HTS) YBa2Cu3O7-x (YBCO) step-edge Josephson junction. The HTS mixer enables the flexible harmonic mixing operation at multiple THz bands with the same microwave local oscillator (LO) source, and features very wide intermediate-frequency or instantaneous bandwidth. In order to optimize the frequency down-conversion performance of the mixer, systematic electromagnetic design and analysis have been carried out to improve the power coupling of THz radiation as well as wideband transmission of microwave signals. Experimental characterization of a fabricated device prototype has demonstrated that the mixer exhibits good performance at both the 200 GHz and 600 GHz bands. Detailed measurement results including the DC characteristics, LO pumping requirement, frequency response, mixing linearity and conversion gain are presented in this paper.

  20. Realization and characterization of single-frequency tunable 637.2 nm high-power laser

    NASA Astrophysics Data System (ADS)

    Wang, Jieying; Bai, Jiandong; He, Jun; Wang, Junmin

    2016-07-01

    We report the preparation of narrow-linewidth 637.2 nm laser device by single-pass sum-frequency generation (SFG) of two infrared lasers at 1560.5 nm and 1076.9 nm in PPMgO:LN crystal. Over 8.75 W of single-frequency continuously tunable 637.2 nm laser is realized, and corresponding optical-optical conversion efficiency is 38.0%. We study the behavior of crystals with different poling periods. The detailed experiments show that the output red lasers have very good power stability and beam quality. This high-performance 637.2 nm laser is significant for the realization of high power ultra-violet (UV) 318.6 nm laser via cavity-enhanced frequency doubling. Narrow-linewidth 318.6 nm laser is important for Rydberg excitation of cesium atoms via single-photon transition.

  1. Bessel-Gauss beam enhancement cavities for high-intensity applications.

    PubMed

    Putnam, William P; Schimpf, Damian N; Abram, Gilberto; Kärtner, Franz X

    2012-10-22

    We introduce Bessel-Gauss beam enhancement cavities that may circumvent the major obstacles to more efficient cavity-enhanced high-field physics such as high-harmonic generation. The basic properties of Bessel-Gauss beams are reviewed and their transformation properties through simple optical systems (consisting of spherical and conical elements) are presented. A general Bessel-Gauss cavity design strategy is outlined, and a particular geometry, the confocal Bessel-Gauss cavity, is analyzed in detail. We numerically simulate the confocal Bessel-Gauss cavity and present an example cavity with 300 MHz repetition rate supporting an effective waist of 33 μm at the focus and an intensity ratio from the focus to the cavity mirror surfaces of 1.5 × 10(4).

  2. Quantum noise limits in white-light-cavity-enhanced gravitational wave detectors

    NASA Astrophysics Data System (ADS)

    Zhou, Minchuan; Zhou, Zifan; Shahriar, Selim M.

    2015-10-01

    Previously, we had proposed a gravitational wave detector that incorporates the white-light-cavity (WLC) effect using a compound cavity for signal recycling (CC-SR). Here, we first use an idealized model for the negative dispersion medium (NDM) and use the so-called Caves model for a phase-insensitive linear amplifier to account for the quantum noise (QN) contributed by the NDM, in order to determine the upper bound of the enhancement in the sensitivity-bandwidth product. We calculate the quantum noise limited sensitivity curves for the CC-SR design, and find that the broadening of sensitivity predicted by the classical analysis is also present in these curves, but is somewhat reduced. Furthermore, we find that the curves always stay above the standard quantum limit. To circumvent this limitation, we modify the dispersion to compensate the nonlinear phase variation produced by the optomechanical resonance effects. We find that the upper bound of the factor by which the sensitivity-bandwidth product is increased, compared to the highest-sensitivity result predicted by Bunanno and Chen [Phys. Rev. D 64, 042006 (2001)], is ˜14 . We also present a simpler scheme (WLC-SR), where a dispersion medium is inserted into the SR cavity. For this scheme, we found the upper bound of the enhancement factor to be ˜18 . We then consider an explicit system for realizing the NDM, which makes use of five energy levels in M configuration to produce gain, accompanied by electromagnetically induced transparency (the GEIT system). For this explicit system, we employ the rigorous approach based on Master Equation to compute the QN contributed by the NDM, thus enabling us to determine the enhancement in the sensitivity-bandwidth product definitively rather than the upper bound thereof. Specifically, we identify a set of parameters for which the sensitivity-bandwidth product is enhanced by a factor of 17.66.

  3. PCF-Based Cavity Enhanced Spectroscopic Sensors for Simultaneous Multicomponent Trace Gas Analysis

    PubMed Central

    Nakaema, Walter M.; Hao, Zuo-Qiang; Rohwetter, Philipp; Wöste, Ludger; Stelmaszczyk, Kamil

    2011-01-01

    A multiwavelength, multicomponent CRDS gas sensor operating on the basis of a compact photonic crystal fibre supercontinuum light source has been constructed. It features a simple design encompassing one radiation source, one cavity and one detection unit (a spectrograph with a fitted ICCD camera) that are common for all wavelengths. Multicomponent detection capability of the device is demonstrated by simultaneous measurements of the absorption spectra of molecular oxygen (spin-forbidden b-X branch) and water vapor (polyads 4v, 4v + δ) in ambient atmospheric air. Issues related to multimodal cavity excitation, as well as to obtaining the best signal-to-noise ratio are discussed together with methods for their practical resolution based on operating the cavity in a “quasi continuum” mode and setting long camera gate widths, respectively. A comprehensive review of multiwavelength CRDS techniques is also given. PMID:22319372

  4. Metrology with PT-Symmetric Cavities: Enhanced Sensitivity near the PT-Phase Transition.

    PubMed

    Liu, Zhong-Peng; Zhang, Jing; Özdemir, Şahin Kaya; Peng, Bo; Jing, Hui; Lü, Xin-You; Li, Chun-Wen; Yang, Lan; Nori, Franco; Liu, Yu-Xi

    2016-09-09

    We propose and analyze a new approach based on parity-time (PT) symmetric microcavities with balanced gain and loss to enhance the performance of cavity-assisted metrology. We identify the conditions under which PT-symmetric microcavities allow us to improve sensitivity beyond what is achievable in loss-only systems. We discuss the application of PT-symmetric microcavities to the detection of mechanical motion, and show that the sensitivity is significantly enhanced near the transition point from unbroken- to broken-PT regimes. Our results open a new direction for PT-symmetric physical systems and it may find use in ultrahigh precision metrology and sensing.

  5. NIR resonant-cavity-enhanced InP/InGaAs strained quantum well interband photodetector

    NASA Astrophysics Data System (ADS)

    Jourba, Serguei; Besland, Marie-Paule; Gendry, Michel; Garrigues, Michel; Leclercq, Jean L.; Rojo-Romeo, Pedro; Viktorovitch, Pierre; Cortial, Sebastein; Hugon, Xavier; Pautet, Christophe

    1999-04-01

    We demonstrate NIR (1.8 micrometer - 2.3 micrometer) resonant photo-detectors based on inter-band (Ecl- Ehhl) absorption in strain compensated, indium rich, InGaAs quantum wells (QW). Extremely low room temperature dark current densities are achieved by reduction of the active layer thickness combined with low defect density of the pseudomorphic strain compensated QWs. The weak absorption of the QW is enhanced by embedding the quantum well into a vertical resonant cavity. We present the experimental results for a demonstrator designed for a wavelength of 2 micrometer. The device, based on a single In(subscript 0.83)Ga(subscript 0.17)As quantum well and tensile strained barriers for strain compensation, exhibits a selectivity of 9 nm and 18% quantum efficiency. InP/InGaAs and Si/SiO(subscript 2) material systems are used for the bottom and top distributed Bragg reflectors (DBR) of the cavity, with 20 pairs and 2 pairs respectively. The semiconductor structure is grown by MOCVD. The top Si/SiO(subscript 2) DBR is deposited after fabrication of p-i-n planar photodiodes. Typical dark current densities are lower than 10(superscript -7) A/cm(superscript 2) at -2 V bias. Conditions for extension of the operating wavelength up to 2.3 micrometer have been obtained experimentally using InAs/GaAs superlattice deposition to increase the thickness of the strained QW. A prospective tunable detector based on an actuable micro-machined air cavity and air/InP bottom DBR is proposed.

  6. Cavity-enhanced optical trapping of bacteria using a silicon photonic crystal.

    PubMed

    van Leest, Thijs; Caro, Jacob

    2013-11-21

    On-chip optical trapping and manipulation of cells based on the evanescent field of photonic structures is emerging as a promising technique, both in research and for applications in broader context. Relying on mass fabrication techniques, the involved integration of photonics and microfluidics allows control of both the flow of light and water on the scale of interest in single cell microbiology. In this paper, we demonstrate for the first time optical trapping of single bacteria (B. subtilis and E. coli) using photonic crystal cavities for local enhancement of the evanescent field, as opposed to the synthetic particles used so far. Three types of cavities (H0, H1 and L3) are studied, embedded in a planar photonic crystal and optimized for coupling to two collinear photonic crystal waveguides. The photonic crystals are fabricated on a silicon-on-insulator chip, onto which a fluidic channel is created as well. For each of the cavities, when pumped at the resonance wavelength (around 1550 nm), we clearly demonstrate optical trapping of bacteria, in spite of their low index contrast w.r.t. water. By tracking the confined Brownian motion of B. subtilis spores in the traps using recorded microscope observations, we derive strong in-plane trap stiffnesses of about 7.6 pN nm(-1) W(-1). The values found agree very well with calculations based on the Maxwell stress tensor for the force and finite-difference time-domain simulations of the fields for the fabricated cavity geometries. We envision that our lab-on-a-chip with photonic crystal traps opens up new application directions, e.g. immobilization of single bio-objects such as mammalian cells and bacteria under controlled conditions for optical microscopy studies.

  7. Liquid Phase Supercontinuum Fiber-Loop Cavity Enhanced Absorption Spectroscopy for H_{2}O in Organics

    NASA Astrophysics Data System (ADS)

    Li, Mingyun; Lehmann, Kevin

    2017-06-01

    Last year we presented a way of liquid phase sensing for H_{2}O and D_{2}O samples using a side-polished-fiber (SPF) sensor. It is a setup to combine the advantages of Supercontinuum light source with fiber-loop sensing method to make liquid phase CEAS sensing easier and more reliable. After some calculation we found out that with a SPF sensor we could only make use of less than 0.2% of the light from Supercontinuum source, so we decided to make changes on sensors in order to make more light usable. Instead of a SPF or similar evanescent wave sensors, if the light can be guided through a sample directly in free space, we can get almost 100% of the light to be used. So we replaced our sensor by using a mirror and two fibers placed vertical to it side-by-side. The mirror reflects light from one fiber to the other. The free space coupling can make the most of our Supercontinuum source, and a much stronger signal is observed so far. We are now able to use our setup to monitor very low H_{2}O concentrations such as saturated H_{2}O solution in organics like CCl_{4}. Hopefully we can make our system more reliable in the future to make it use in more samples and lower concentrations.

  8. Silicon photonic crystal cavity enhanced second-harmonic generation from monolayer WSe2

    NASA Astrophysics Data System (ADS)

    Fryett, Taylor K.; Seyler, Kyle L.; Zheng, Jiajiu; Liu, Chang-Hua; Xu, Xiaodong; Majumdar, Arka

    2017-03-01

    Nano-resonators integrated with two-dimensional materials (e.g. transition metal dichalcogenides) have recently emerged as a promising nano-optoelectronic platform. Here we demonstrate resonator-enhanced second-harmonic generation (SHG) in tungsten diselenide using a silicon photonic crystal cavity. By pumping the device with ultrafast laser pulses near the cavity mode at the telecommunication wavelength, we observe a near visible SHG with a narrow linewidth and near unity linear polarization, originated from the coupling of the pump photon to the cavity mode. The observed SHG is enhanced by factor of ∼200 compared to a bare monolayer on silicon. Our results imply the efficacy of cavity integrated monolayer materials for nonlinear optics and the potential of building a silicon-compatible second-order nonlinear integrated photonic platform.

  9. PCF-based cavity enhanced spectroscopic sensors for simultaneous multicomponent trace gas analysis.

    PubMed

    Nakaema, Walter M; Hao, Zuo-Qiang; Rohwetter, Philipp; Wöste, Ludger; Stelmaszczyk, Kamil

    2011-01-01

    A multiwavelength, multicomponent CRDS gas sensor operating on the basis of a compact photonic crystal fibre supercontinuum light source has been constructed. It features a simple design encompassing one radiation source, one cavity and one detection unit (a spectrograph with a fitted ICCD camera) that are common for all wavelengths. Multicomponent detection capability of the device is demonstrated by simultaneous measurements of the absorption spectra of molecular oxygen (spin-forbidden b-X branch) and water vapor (polyads 4v, 4v + δ) in ambient atmospheric air. Issues related to multimodal cavity excitation, as well as to obtaining the best signal-to-noise ratio are discussed together with methods for their practical resolution based on operating the cavity in a "quasi continuum" mode and setting long camera gate widths, respectively. A comprehensive review of multiwavelength CRDS techniques is also given.

  10. An electrically driven cavity-enhanced source of indistinguishable photons with 61% overall efficiency

    NASA Astrophysics Data System (ADS)

    Schlehahn, A.; Thoma, A.; Munnelly, P.; Kamp, M.; Höfling, S.; Heindel, T.; Schneider, C.; Reitzenstein, S.

    2016-04-01

    We report on an electrically driven efficient source of indistinguishable photons operated at pulse-repetition rates f up to 1.2 GHz. The quantum light source is based on a p-i-n-doped micropillar cavity with integrated self-organized quantum dots, which exploits cavity quantum electrodynamics effects in the weak coupling regime to enhance the emission of a single quantum emitter coupled to the cavity mode. We achieve an overall single-photon extraction efficiency of (61 ± 11) % for a device triggered electrically at f = 625 MHz. Analyzing the suppression of multi-photon emission events as a function of excitation repetition rate, we observe single-photon emission associated with g(2)HBT(0) values between 0.076 and 0.227 for f ranging from 373 MHz to 1.2 GHz. Hong-Ou-Mandel-type two-photon interference experiments under pulsed current injection at 487 MHz reveal a photon-indistinguishability of (41.1 ± 9.5) % at a single-photon emission rate of (92 ± 23) MHz.

  11. High-efficiency WSi superconducting nanowire single-photon detectors for quantum state engineering in the near infrared.

    PubMed

    Le Jeannic, Hanna; Verma, Varun B; Cavaillès, Adrien; Marsili, Francesco; Shaw, Matthew D; Huang, Kun; Morin, Olivier; Nam, Sae Woo; Laurat, Julien

    2016-11-15

    We report on high-efficiency superconducting nanowire single-photon detectors based on amorphous tungsten silicide and optimized at 1064 nm. At an operating temperature of 1.8 K, we demonstrated a 93% system detection efficiency at this wavelength with a dark noise of a few counts per second. Combined with cavity-enhanced spontaneous parametric downconversion, this fiber-coupled detector enabled us to generate narrowband single photons with a heralding efficiency greater than 90% and a high spectral brightness of 0.6×104 photons/(s·mW·MHz). Beyond single-photon generation at large rate, such high-efficiency detectors open the path to efficient multiple-photon heralding and complex quantum state engineering.

  12. Integrated high-speed DFB light source and narrow-bandwidth RCE photodetector for WDM fiber communication network application

    NASA Astrophysics Data System (ADS)

    Wang, Qiming; Li, Cheng; Pan, Zhong; Luo, Yi

    2000-10-01

    Electroabsorption (EA) modulator integrated with partially gain coupling distributed feedback (DFB) lasers have been fabricated and shown high single mode yield and wavelength stability. The small signal bandwidth is about 7.5 GHz. Strained Si1-xGex/Si multiple quantum well (MQW) resonant-cavity enhanced (RCE) photodetectors with SiO2/Si distributed Bragg reflector (DBR) as the mirrors have been fabricated and shown a clear narrow bandwidth response. The external quantum efficiency at 1.3 micrometer is measured to be about 3.5% under reverse bias of 16 V. A novel GaInNAs/GaAs MQW RCE p-i-n photodetector with high reflectance GaAs/AlAs DBR mirrors has also been demonstrated and shown the selectively detecting function with the FWHM of peak response of 12 nm.

  13. Elucidating the Complex Lineshapes Resulting from the Highly Sensitive, Ion Selective, Technique Nice-Ohvms

    NASA Astrophysics Data System (ADS)

    Hodges, James N.; Siller, Brian; McCall, Benjamin J.

    2015-06-01

    The technique Noise Immune Cavity Enhanced Optical Heterodyne Velocity Modulation Spectroscopy, or NICE-OHVMS, has been used to great effect to precisely and accurately measure a variety of molecular ion transitions from species such as H_3^+, CH_5^+, HeH^+, and HCO^+, achieving MHz or in some cases sub-MHz uncertainty. It is a powerful technique, but a complete theoretical understanding of the complex NICE-OHVMS lineshape is needed to fully unlock its potential. NICE-OHVMS is the direct result of the combination of the highly sensitive spectroscopic technique Noise Immune Cavity Enhanced Optical Heterodyne Molecular Spectroscopy(NICE-OHMS) with Velocity Modulation Spectroscopy(VMS), applying the most sensitive optical detection method with ion species selectivity. The theoretical underpinnings of NICE-OHMS lineshapes are well established, as are those of VMS. This presentation is the logical extension of those two preceding bodies of work. Simulations of NICE-OHVMS lineshapes under a variety of conditions and fits of experimental data to the model are presented. The significance and accuracy of the various inferred parameters, along with the prospect of using them to extract additional information from observed transitions, are discussed. J.~N. Hodges, et al. J. Chem. Phys. (2013), 139, 164201. A.~J. Perry, et al. J. Chem. Phys. (2014), 141, 101101. K.~N. Crabtree, et al. Chem. Phys. Lett. (2012), 551, 1-6. F.~M. Schmidt, et al. J. Opt. Soc. Amer. A (2008), 24, 1392--1405. J.~W. Farley, J. Chem. Phys. (1991), 95, 5590--5602.

  14. High Precision Rovibrational Spectroscopy of OH+

    NASA Astrophysics Data System (ADS)

    Markus, Charles R.; Hodges, James N.; Perry, Adam J.; Kocheril, G. Stephen; Müller, Holger S. P.; McCall, Benjamin J.

    2016-02-01

    The molecular ion OH+ has long been known to be an important component of the interstellar medium. Its relative abundance can be used to indirectly measure cosmic ray ionization rates of hydrogen, and it is the first intermediate in the interstellar formation of water. To date, only a limited number of pure rotational transitions have been observed in the laboratory making it necessary to indirectly calculate rotational levels from high-precision rovibrational spectroscopy. We have remeasured 30 transitions in the fundamental band with MHz-level precision, in order to enable the prediction of a THz spectrum of OH+. The ions were produced in a water cooled discharge of O2, H2, and He, and the rovibrational transitions were measured with the technique Noise Immune Cavity Enhanced Optical Heterodyne Velocity Modulation Spectroscopy. These values have been included in a global fit of field free data to a 3Σ- linear molecule effective Hamiltonian to determine improved spectroscopic parameters which were used to predict the pure rotational transition frequencies.

  15. On the use of a small-scale two-phase thermosiphon to cool high-power electronics

    NASA Astrophysics Data System (ADS)

    Schrage, D. S.

    1990-01-01

    An experimental and analytical investigation of the steady-state thermal-hydraulic operating characteristics of a small-scale two-phase thermosiphon cooling actual power electronics are presented. Boiling heat transfer coefficients and circulation mass velocities were measured while varying heat load and pressure. Both a plain and augmented riser structure, utilizing micro-fins and reentrant cavities, were simultaneously tested. The boiling heat transfer coefficients increased with both increasing heat load and pressure. The mass velocity increased with increasing pressure while both increasing and then decreasing with increasing heat load. The reentrant cavity enhancement factor, a ratio of the augmented-to-plain riser nucleate boiling heat transfer coefficients, ranged from 1 to 1.4. High-speed photography revealed bubbly, slug, churn, wispy-annular and annular flow patterns. The experimental mass velocity and heat transfer coefficient data were compared to an analytical model with average absolute deviations of 16.3 and 26.3 percent, respectively.

  16. Multi-wavelength Erbium-doped fiber laser based on four-wave-mixing effect in single mode fiber and high nonlinear fiber.

    PubMed

    Wang, Pinghe; Weng, Danmei; Li, Kun; Liu, Yong; Yu, Xuecai; Zhou, Xiaojun

    2013-05-20

    A multi-wavelength Erbium-doped fiber (EDF) laser based on four-wave-mixing is proposed and experimentally demonstrated. The 5 km single mode fiber in the cavity enhances the four-wave-mixing to suppress the homogenous broadening of the erbium-doped fiber and get the stable multi-wavelength comb. The lasing stability is investigated. When the pump power is 300 mW, the fiber laser has 5-lasing lines and the maximum fluctuation of the output power is about 3.18 dB. At the same time, a laser with 110 m high nonlinear fiber (HNFL) is demonstrated. When the pump power is 300 mW, it has 7-lasing lines (above -30 dBm) and the maximum fluctuation is 0.18dB.

  17. The energy-time uncertainty principle and the EPR paradox: Experiments involving correlated two-photon emission in parametric down-conversion

    NASA Technical Reports Server (NTRS)

    Chiao, Raymond Y.; Kwiat, Paul G.; Steinberg, Aephraim M.

    1992-01-01

    The energy-time uncertainty principle is on a different footing than the momentum position uncertainty principle: in contrast to position, time is a c-number parameter, and not an operator. As Aharonov and Bohm have pointed out, this leads to different interpretations of the two uncertainty principles. In particular, one must distinguish between an inner and an outer time in the definition of the spread in time, delta t. It is the inner time which enters the energy-time uncertainty principle. We have checked this by means of a correlated two-photon light source in which the individual energies of the two photons are broad in spectra, but in which their sum is sharp. In other words, the pair of photons is in an entangled state of energy. By passing one member of the photon pair through a filter with width delta E, it is observed that the other member's wave packet collapses upon coincidence detection to a duration delta t, such that delta E(delta t) is approximately equal to planks constant/2 pi, where this duration delta t is an inner time, in the sense of Aharonov and Bohm. We have measured delta t by means of a Michelson interferometer by monitoring the visibility of the fringes seen in coincidence detection. This is a nonlocal effect, in the sense that the two photons are far away from each other when the collapse occurs. We have excluded classical-wave explanations of this effect by means of triple coincidence measurements in conjunction with a beam splitter which follows the Michelson interferometer. Since Bell's inequalities are known to be violated, we believe that it is also incorrect to interpret this experimental outcome as if energy were a local hidden variable, i.e., as if each photon, viewed as a particle, possessed some definite but unknown energy before its detection.

  18. Cognitive Radio Low-Energy Signal Analysis Sensor Integrated Circuits (CLASIC): A Broadband Mixed-Signal Iterative Down Conversion Spectrum Analyzer for Signal Recognition Applications

    DTIC Science & Technology

    2015-12-01

    AFRL-RY-WP-TR-2015-0144 COGNITIVE RADIO LOW-ENERGY SIGNAL ANALYSIS SENSOR INTEGRATED CIRCUITS (CLASIC) A Broadband Mixed-Signal Iterative Down...June 2015 4. TITLE AND SUBTITLE COGNITIVE RADIO LOW-ENERGY SIGNAL ANALYSIS SENSOR INTEGRATED CIRCUITS (CLASIC) A Broadband Mixed-Signal Iterative...Texas & Columbia University development project funded under the DARPA Cognitive radio Low-energy signal Analysis Sensor Integrated Circuits

  19. Enhanced generation of twin single-photon states via quantum interference in parametric down-conversion: Application to two-photon quantum photolithography

    SciTech Connect

    Gerry, Christopher C.

    2003-04-01

    Two-photon interferometric quantum photon lithography for light of wavelength {lambda} is capable of beating the Rayleigh diffraction limit of resolution {lambda}/4 to the level of {lambda}/8. The required twin single-photon states |1>{sub a}|1>{sub b}, which are converted into maximally entangled states by a 50:50 beam splitter, can be generated from a nondegenerate parametric amplifier initially in vacuum states and with a weak pump field. Increasing the pump strength can slightly increase the production rate of the desired state and it will also increase the production of the twin two-photon states |2>{sub a}|2>{sub b}, which leads to an unwanted background term. In this paper we show that, assuming a weak pair coherent state as input to the amplifier, quantum interference can be used to quench the production of the |2>{sub a}|2>{sub b} state and to enhance the production of the |1>{sub a}|1>{sub b} state by almost sixfold.

  20. Frequency down-conversion of 1 μm laser radiation to the mid-IR using non-oxide nonlinear crystals in a cascaded intracavity configuration

    NASA Astrophysics Data System (ADS)

    Petrov, Valentin; Boyko, Andrey A.; Kostyukova, Nadezhda Y.; Marchev, Georgi M.; Pasiskevicius, Valdas; Kolker, Dmitry B.; Badikov, Valeriy; Badikov, Dmitrii; Shevyrdyaeva, Galina; Zukauskas, Andrius; Panyutin, Vladimir

    2017-02-01

    A singly-resonant OPO (SRO) based on AgGaSe2 (AGSe) intracavity pumped at 1.85 μm by the signal pulses of a Rb:PPKTP doubly-resonant OPO (DRO) provided extremely broad tuning (5.8 to 18 μm) for the non-resonated idler. In a similar set-up with the same nonlinear crystals, we studied intracavity difference-frequency generation (DFG). Both AGSe and the new monoclinic crystal BaGa4Se7 (BGSe) generated single pulse energies of 0.7 mJ near 7 μm at an overall conversion efficiency from the 1.064 μm pump of 1.2%. The main advantage of BGSe is its damage resistivity up to the maximum pump levels applied at 100 Hz.

  1. Up/down conversion switching by adjusting the pulse width of red laser beams in LaF₃:Tm³⁺ nanocrystals.

    PubMed

    Gao, Dangli; Tian, Dongping; Xiao, Guoqing; Chong, Bo; Yu, Genghua; Pang, Qing

    2015-08-01

    We demonstrate a versatile approach to fine-tuning the ratio of blue to near-infrared emission intensity from Tm3+ ions in LaF3 nanocrystals by adjusting the pulse widths and excitation wavelengths of red laser beams. The mechanism of color-tunable Tm3+ emission by pulse widths is explored, and a mechanism based on promoting the population of some luminescence levels and cutting off the population of others by suitably adjusting pulse duration is proposed. The underlying reason of excitation wavelength-modulated emission is ascribed to tuning absorption probability ratio of ground state absorption to excited state absorption by tuning the matching degree between the energies of excitation wavelength and ground (excited) state absorption of Tm3+. The ability of our LaF3:Tm3+ nanocrystals to emit variable emissions on demand in response to pulse width and excitation wavelength provides keen insights into controlling the population processes of luminescent levels and offers a versatile approach for tuning the spectral output.

  2. Efficient near-infrared emission in Eu3+-Yb3+-Y3+ tri-doped cubic ZrO2 via down-conversion for silicon solar cells

    NASA Astrophysics Data System (ADS)

    Liao, Jinsheng; Zhou, Dan; Liu, Shaohua; Wen, He-Rui; Qiu, Xin; Chen, Jinglin

    2014-03-01

    Eu3+-Yb3+-Y3+ tri-doped cubic ZrO2 (abbreviated as YSZ:Eu,Yb) phosphors with different doping concentrations of Yb3+ can be synthesized via the Pechini sol-gel method. Efficient near-infrared (NIR) emission in YSZ:Eu,Yb phosphors was demonstrated. The dependence of the intensities of visible and NIR emissions, decay lifetimes and energy-transfer efficiencies on the Yb3+ doping concentration was investigated in detail. It is found that Eu3+, acting as a sensitizer, can efficiently transfer its energy to Yb3+ activator ions in YSZ:Eu,Yb phosphors.

  3. Temperature-controlled down-conversion luminescence behavior of Eu(3)(+) -doped transparent MF2 (M = Ba, Ca, Sr) glass ceramics.

    PubMed

    Zhou, B; E, C Q; Bu, Y Y; Meng, L; Yan, X H; Wang, X F

    2017-03-01

    Eu(3)(+) -doped transparent glass ceramics containing MF2 (M = Ba, Ca, Sr) nanocrystals were fabricated using a melt-quenching method, and the resulting structures were studied using X-ray diffraction. Levels (5) D1 and (5) D0 of Eu(3)(+) ions were verified as thermally coupled levels using the fluorescence intensity ratio method. The fluorescence intensity ratios, optical temperature sensitivity and thermal quenching ratios of the transparent glass ceramics were studied as a function of temperature. With an increase in temperature, the relative sensitivity (SR ) decreased sharply at first, then slowly increased, before finally decreasing. The minimum SR values of GCBaF2 (GCB), GCCaF2 (GCC) and GCSrF2 (GCS) were 2.8 × 10(-4) , 0.8 × 10(-4) and 1.9 × 10(-)(4)  K(-1) at 360, 269 and 319 K, respectively. Glass ceramics with an intense emission intensity can be used to convert the measured spectrum into temperature and may have an important role in temperature detectors.

  4. High visibility Hong-Ou-Mandel interference via a time-resolved coincidence measurement.

    PubMed

    Tsujimoto, Yoshiaki; Sugiura, Yukihiro; Tanaka, Motoki; Ikuta, Rikizo; Miki, Shigehito; Yamashita, Taro; Terai, Hirotaka; Fujiwara, Mikio; Yamamoto, Takashi; Koashi, Masato; Sasaki, Masahide; Imoto, Nobuyuki

    2017-05-29

    A high visibility Hong-Ou-Mandel (HOM) interference between two independently prepared photons plays an important role in various photonic quantum information processing. In a standard HOM experiment using photons generated by pulse-pumped spontaneous parametric down conversion (SPDC), larger detection time windows than the coherence time of photons have been employed for measuring the HOM visibility and/or drawing the HOM dip. If large amounts of stray photons continuously exist within the detection time windows, employing small detection time windows is favorable for reducing the effect of background noises. Especially, such a setup is helpful for the HOM experiment using continuous wave (cw)-pumped SPDC and the time-resolved coincidence measurement. Here we argue that the method for determining the HOM visibility used in the previous cw experiments tends to suffer from distortion arising from biased contribution of the background noises. We then present a new method with unbiased treatment of the cw backgrounds. By using this method, we experimentally demonstrate a high visibility HOM interference of two heralded telecom photons independently generated by SPDC with employing cw pump light. An observed HOM visibility is 0.87 ± 0.04, which is as high as those observed by using pulse-pumped SPDC photons.

  5. Twin photon pairs in a high-Q silicon microresonator

    SciTech Connect

    Rogers, Steven; Lu, Xiyuan; Jiang, Wei C.; Lin, Qiang

    2015-07-27

    We report the generation of high-purity twin photon pairs through cavity-enhanced non-degenerate four-wave mixing (FWM) in a high-Q silicon microdisk resonator. Twin photon pairs are created within the same cavity mode and are consequently expected to be identical in all degrees of freedom. The device is able to produce twin photons at telecommunication wavelengths with a pair generation rate as large as (3.96 ± 0.03) × 10{sup 5} pairs/s, within a narrow bandwidth of 0.72 GHz. A coincidence-to-accidental ratio of 660 ± 62 was measured, the highest value reported to date for twin photon pairs, at a pair generation rate of (2.47 ± 0.04) × 10{sup 4} pairs/s. Through careful engineering of the dispersion matching window, we have reduced the ratio of photons resulting from degenerate FWM to non-degenerate FWM to less than 0.15.

  6. HIGH PRECISION ROVIBRATIONAL SPECTROSCOPY OF OH{sup +}

    SciTech Connect

    Markus, Charles R.; Hodges, James N.; Perry, Adam J.; Kocheril, G. Stephen; McCall, Benjamin J.; Müller, Holger S. P.

    2016-02-01

    The molecular ion OH{sup +} has long been known to be an important component of the interstellar medium. Its relative abundance can be used to indirectly measure cosmic ray ionization rates of hydrogen, and it is the first intermediate in the interstellar formation of water. To date, only a limited number of pure rotational transitions have been observed in the laboratory making it necessary to indirectly calculate rotational levels from high-precision rovibrational spectroscopy. We have remeasured 30 transitions in the fundamental band with MHz-level precision, in order to enable the prediction of a THz spectrum of OH{sup +}. The ions were produced in a water cooled discharge of O{sub 2}, H{sub 2}, and He, and the rovibrational transitions were measured with the technique Noise Immune Cavity Enhanced Optical Heterodyne Velocity Modulation Spectroscopy. These values have been included in a global fit of field free data to a {sup 3}Σ{sup −} linear molecule effective Hamiltonian to determine improved spectroscopic parameters which were used to predict the pure rotational transition frequencies.

  7. Ultra-Low Phase Noise, High Resolution Spectrometer Using Comb-Assisted Quantum Cascade Lasers

    NASA Astrophysics Data System (ADS)

    Mills, Andrew A.; Mohr, Christian; Jiang, Jie; Gatti, Davide; Marangoni, Marco; Gianfrani, Livio; Hartl, Ingmar; Fermann, Martin

    2013-06-01

    In recent years, optical frequency combs have been used extensively to stabilize solid state cw lasers for high resolution spectroscopy, enabling the acquisition of absorption profiles of a gas sample with an absolutely calibrated, repeatable and linear frequency axis. This uniquely defined and repeatable frequency axis allows for the retrieval of highly accurate and traceable spectroscopic parameters and the ability to obtain physical insights regarding the influence of collisional processes on the absorption line shapes. The highly accurate frequency axis has can be used in precision spectroscopy applications such as resolving hyperfine transitions or cavity enhanced spectroscopy for trace gas detection. To simplify such precision spectroscopy systems in the future, the use of quantum cascade lasers (QCL) as a spectroscopic tool is highly desired. Here we report on the precision phase locking of a 9 μm QCL to a 2 μm low-noise thulium frequency comb. Utilizing a coherent lock with a MHz-level feedback bandwidth, we line narrow a QCL with a 1 MHz linewidth and achieve an in-loop beatnote measurement with 70 dB S/N at 1 Hz RBW. As an application, we demonstrate the interrogation of sub-Doppler features of ammonia spectra at 9 μm. It is expected that the system is further compatible with line narrowing of widely tunable external cavity QCL's, opening new measurement avenues in precision spectroscopy.

  8. Quantum non-Gaussianity of frequency up-converted single photons.

    PubMed

    Baune, Christoph; Schönbeck, Axel; Samblowski, Aiko; Fiurášek, Jaromír; Schnabel, Roman

    2014-09-22

    Nonclassical states of light are an important resource in today's quantum communication and metrology protocols. Quantum up-conversion of nonclassical states is a promising approach to overcome frequency differences between disparate subsystems within a quantum information network. Here, we present the generation of heralded narrowband single photons at 1550 nm via cavity enhanced spontaneous parametric down-conversion (SPDC) and their subsequent up-conversion to 532 nm. Quantum non-Gaussianity (QNG), which is an important feature for applications in quantum information science, was experimentally certified for the first time in frequency up-converted states.

  9. Travelling-wave resonant four-wave mixing breaks the limits of cavity-enhanced all-optical wavelength conversion

    PubMed Central

    Morichetti, Francesco; Canciamilla, Antonio; Ferrari, Carlo; Samarelli, Antonio; Sorel, Marc; Melloni, Andrea

    2011-01-01

    Wave mixing inside optical resonators, while experiencing a large enhancement of the nonlinear interaction efficiency, suffers from strong bandwidth constraints, preventing its practical exploitation for processing broad-band signals. Here we show that such limits are overcome by the new concept of travelling-wave resonant four-wave mixing (FWM). This approach combines the efficiency enhancement provided by resonant propagation with a wide-band conversion process. Compared with conventional FWM in bare waveguides, it exhibits higher robustness against chromatic dispersion and propagation loss, while preserving transparency to modulation formats. Travelling-wave resonant FWM has been demonstrated in silicon-coupled ring resonators and was exploited to realize a 630-μm-long wavelength converter operating over a wavelength range wider than 60 nm and with 28-dB gain with respect to a bare waveguide of the same physical length. Full compatibility of the travelling-wave resonant FWM with optical signal processing applications has been demonstrated through signal retiming and reshaping at 10 Gb s−1 PMID:21540838

  10. Resonant Cavity Enhanced On-Chip Raman Spectrometer Array with Precisely Positioned Metallic Nano-Gaps for Single Molecule Detection

    DTIC Science & Technology

    2011-03-22

    fabricated multi-segment gold nanowires with different diameters using electroplating, and formed nanogaps from 5nm to 50nm by sacrificial chemical etching...electroplating, and formed nanogaps from 5nm to 50nm by sacrificial chemical etching. Surface enhanced Raman scattering (SERS) characterization using these...nanowires with different diameters using electroplating, and formed nanogaps from 5nm to 50nm by sacrificial chemical etching. Surface enhanced Raman

  11. Ultrafast XUV Pulses at High Repetition Rate for Time Resolved Photoelectron Spectroscopy of Surface Dynamics

    NASA Astrophysics Data System (ADS)

    Corder, Christopher; Zhao, Peng; Li, Xinlong; Muraca, Amanda R.; Kershis, Matthew D.; White, Michael G.; Allison, Thomas K.

    2016-05-01

    Ultrafast photoelectron studies of surface dynamics are often limited by low repetition rates. At Stony Brook we have built a cavity-enhanced high-harmonic generation XUV source that delivers ultrafast pulses to a surface science apparatus for photoelectron spectroscopy. We begin with a Ytterbium fiber laser at a repetition rate of 78 MHz and up to 90 W of average power. After compression the pulses have μJ's of energy with < 180 fs pulse width. We then use an enhancement cavity with a finesse of a few hundred to build up to the peak intensity required for high harmonic generation. The enhancement cavity is a six mirror double folded bow-tie geometry with a focus of 15 μm at a Krypton gas jet, followed by a Sapphire crystal at Brewster's angle for the fundamental to allow outcoupling of the harmonics. A single harmonic is selected using a time-preserving monochromator to maintain the short pulses, and is sent to an ultra high vacuum chamber with sample preparation and diagnostic tools as well as an electron energy spectrometer. This allows us to study the electronic dynamics of semiconductor surfaces and their interfaces with adsorbed molecules which enable various charge transfer effects. Supported by AFOSR.

  12. Wavelength tunable parametric mid-IR source pumped by a high power picosecond thin-disk laser

    NASA Astrophysics Data System (ADS)

    Vyvlečka, Michal; Novák, Ondřej; Smrž, Martin; Endo, Akira; Mocek, Tomáš

    2017-05-01

    High average power wavelength tunable picosecond mid-IR source based on parametric down-conversion is being developed. The conversion system is pumped by a Yb:YAG thin-disk laser delivering 100 W of average power at 100 kHz repetition rate, 1030 nm wavelength, and 3 ps pulse width. First, part of the beam pumps an optical parametric generator (OPG) consisting of a PPLN crystal. The generated wavelength is determined by PPLN's poling period and temperature. Signal beam covered wavelength range between 1.46 mμ and 1.95 mμ. The corresponding idler wavelengths are 3.5 mμ and 2.18 mμ, respectively. Signal beam of about 20 mW was generated at 2 W pumping and double pass arrangement of the OPG stage. The signal pulse energy is further boosted in an optical parametric amplifier (OPA) consisting of two KTP crystals. The signal beam was amplified to 2 W at pumping of 38 W. The idler beam is taken out of the OPA stage as well. Wavelength tuning by KTP crystals' phase-matching angle change was achieved in ranges and 1.7 - 1.95 μm and 2.18 - 2.62 mμ for signal and idler beam, respectively.

  13. A high-field magnetic resonance imaging spectrometer using an oven-controlled crystal oscillator as the local oscillator of its radio frequency transceiver.

    PubMed

    Liang, Xiao; Tang, Xin; Tang, Weinan; Gao, Jia-Hong

    2014-09-01

    A home-made high-field magnetic resonance imaging (MRI) spectrometer with multiple receiving channels is described. The radio frequency (RF) transceiver of the spectrometer consists of digital intermediate frequency (IF) circuits and corresponding mixing circuits. A direct digital synthesis device is employed to generate the IF pulse; the IF signal from a down-conversion circuit is sampled and followed by digital quadrature detection. Both the IF generation and the IF sampling use a 50 MHz clock. An oven-controlled crystal oscillator, which has outstanding spectral purity and a compact circuit, is used as the local oscillator of the RF transceiver. A digital signal processor works as the pulse programmer of the spectrometer, as a result, 32 control lines can be generated simultaneously while an event is triggered. Field programmable gate array devices are utilized as the auxiliary controllers of the IF generation, IF receiving, and gradient control. High performance, including 1 μs time resolution of the soft pulse, 1 MHz receiving bandwidth, and 1 μs time resolution of the gradient waveform, is achieved. High-quality images on a 1.5 T MRI system using the spectrometer are obtained.

  14. Highly tunable hybrid metamaterials employing split-ring resonators strongly coupled to graphene surface plasmons.

    PubMed

    Liu, Peter Q; Luxmoore, Isaac J; Mikhailov, Sergey A; Savostianova, Nadja A; Valmorra, Federico; Faist, Jérôme; Nash, Geoffrey R

    2015-11-20

    Metamaterials and plasmonics are powerful tools for unconventional manipulation and harnessing of light. Metamaterials can be engineered to possess intriguing properties lacking in natural materials, such as negative refractive index. Plasmonics offers capabilities of confining light in subwavelength dimensions and enhancing light-matter interactions. Recently, the technological potential of graphene-based plasmonics has been recognized as the latter features large tunability, higher field-confinement and lower loss compared with metal-based plasmonics. Here, we introduce hybrid structures comprising graphene plasmonic resonators coupled to conventional split-ring resonators, thus demonstrating a type of highly tunable metamaterial, where the interaction between the two resonances reaches the strong-coupling regime. Such hybrid metamaterials are employed as high-speed THz modulators, exhibiting ∼60% transmission modulation and operating speed in excess of 40 MHz. This device concept also provides a platform for exploring cavity-enhanced light-matter interactions and optical processes in graphene plasmonic structures for applications including sensing, photo-detection and nonlinear frequency generation.

  15. Highly tunable hybrid metamaterials employing split-ring resonators strongly coupled to graphene surface plasmons

    PubMed Central

    Liu, Peter Q.; Luxmoore, Isaac J.; Mikhailov, Sergey A.; Savostianova, Nadja A.; Valmorra, Federico; Faist, Jérôme; Nash, Geoffrey R.

    2015-01-01

    Metamaterials and plasmonics are powerful tools for unconventional manipulation and harnessing of light. Metamaterials can be engineered to possess intriguing properties lacking in natural materials, such as negative refractive index. Plasmonics offers capabilities of confining light in subwavelength dimensions and enhancing light–matter interactions. Recently, the technological potential of graphene-based plasmonics has been recognized as the latter features large tunability, higher field-confinement and lower loss compared with metal-based plasmonics. Here, we introduce hybrid structures comprising graphene plasmonic resonators coupled to conventional split-ring resonators, thus demonstrating a type of highly tunable metamaterial, where the interaction between the two resonances reaches the strong-coupling regime. Such hybrid metamaterials are employed as high-speed THz modulators, exhibiting ∼60% transmission modulation and operating speed in excess of 40 MHz. This device concept also provides a platform for exploring cavity-enhanced light–matter interactions and optical processes in graphene plasmonic structures for applications including sensing, photo-detection and nonlinear frequency generation. PMID:26584781

  16. Highly tunable hybrid metamaterials employing split-ring resonators strongly coupled to graphene surface plasmons

    NASA Astrophysics Data System (ADS)

    Liu, Peter Q.; Luxmoore, Isaac J.; Mikhailov, Sergey A.; Savostianova, Nadja A.; Valmorra, Federico; Faist, Jérôme; Nash, Geoffrey R.

    2015-11-01

    Metamaterials and plasmonics are powerful tools for unconventional manipulation and harnessing of light. Metamaterials can be engineered to possess intriguing properties lacking in natural materials, such as negative refractive index. Plasmonics offers capabilities of confining light in subwavelength dimensions and enhancing light-matter interactions. Recently, the technological potential of graphene-based plasmonics has been recognized as the latter features large tunability, higher field-confinement and lower loss compared with metal-based plasmonics. Here, we introduce hybrid structures comprising graphene plasmonic resonators coupled to conventional split-ring resonators, thus demonstrating a type of highly tunable metamaterial, where the interaction between the two resonances reaches the strong-coupling regime. Such hybrid metamaterials are employed as high-speed THz modulators, exhibiting ~60% transmission modulation and operating speed in excess of 40 MHz. This device concept also provides a platform for exploring cavity-enhanced light-matter interactions and optical processes in graphene plasmonic structures for applications including sensing, photo-detection and nonlinear frequency generation.

  17. Highly efficient single-pass blue-light generation at 488 nm using a PPKTP waveguide crystal and high-brightness diode lasers

    NASA Astrophysics Data System (ADS)

    Jechow, Andreas; McNeil, Shirley; Kaleva, Christopher; Skoczowsky, Danilo; Menzel, Ralf

    2009-02-01

    The combination of high brightness laser diodes and periodically poled (PP) waveguide crystals for the generation of blue light at the technically interesting wavelength of 488 nm is promising. Although PPKTP has a lower nonlinear coefficient compared to PPLN it is of interest for the use in such devices. Because of its higher photorefractive damage threshold, it is well suited for operation at room temperature. In this work, a DFB laser as well as a tunable external cavity enhanced broad area diode laser (ECDL) are used for second harmonic generation using a waveguide PPKTP crystal. Both lasers yield several hundred Miliwatts of diffraction limited light around a center wavelength of 976 nm with excellent spectral properties. The ECDL system is further tunable over a broad range of 40 nm. The PPKTP crystal has a length of 12 mm and the 4 μm x 8 μm waveguides are manufactured by ion exchange followed by a patented submount poling technique. By using a DFB laser diode as pump source a laser to waveguide coupling efficiency of more than 55% could be achieved. A maximum output power of 66.7 mW could be generated out of 220 mW infrared light inside the waveguide channel at room temperature. This results in a conversion efficiency of more than 260%/W.

  18. High Resolution Rovibrational Spectroscopy of Large Molecules Using Infrared Frequency Combs and Buffer Gas Cooling

    NASA Astrophysics Data System (ADS)

    Changala, Bryan; Spaun, Ben; Patterson, David; Bjork, Bryce J.; Heckl, Oliver H.; Doyle, John M.; Ye, Jun

    2016-06-01

    We have recently demonstrated the integration of cavity-enhanced direct frequency comb spectroscopy with buffer gas cooling to acquire high resolution infrared spectra of translationally and rotationally cold (˜10 K) gas-phase molecules. Here, we extend this method to significantly larger systems, including naphthalene (C10H_8), a prototypical polyaromatic hydrocarbon, and adamantane (C10H_{16}), the fundamental building block of diamonoids. To the authors' knowledge, the latter molecule represents the largest system for which rotationally resolved spectra in the CH stretch region (3 μm) have been obtained. In addition to the measured spectra, we present several details of our experimental methods. These include introducing non-volatile species into the cold buffer gas cell and obtaining broadband spectra with single comb mode resolution. We also discuss recent modifications to the apparatus to improve its absorption sensitivity and time resolution, which facilitate the study of both larger molecular systems and cold chemical dynamics. B. Spaun, et al. Probing buffer-gas cooled molecules with direct frequency comb spectroscopy in the mid-infrared, WF02, 70th International Symposium on Molecular Spectroscopy, Champaign-Urbana, IL, 2015.

  19. Highly Sensitive Tunable Diode Laser Spectrometers for In Situ Planetary Exploration

    NASA Technical Reports Server (NTRS)

    Vasudev, Ram; Mansour, Kamjou; Webster, Christopher R.

    2013-01-01

    This paper describes highly sensitive tunable diode laser spectrometers suitable for in situ planetary exploration. The technology developed at JPL is based on wavelength modulated cavity enhanced absorption spectroscopy. It is capable of sensitively detecting chemical signatures of life through the abundance of biogenic molecules and their isotopic composition, and chemicals such as water necessary for habitats of life. The technology would be suitable for searching for biomarkers, extinct life, potential habitats of extant life, and signatures of ancient climates on Mars; and for detecting biomarkers, prebiotic chemicals and habitats of life in the outer Solar System. It would be useful for prospecting for water on the Moon and asteroids, and characterizing its isotopic composition. Deployment on the Moon could provide ground truth to the recent remote measurements and help to uncover precious records of the early bombardment history of the inner Solar System buried at the shadowed poles, and elucidate the mechanism for the generation of near-surface water in the illuminated regions. The technology would also be useful for detecting other volatile molecules in planetary atmospheres and subsurface reservoirs, isotopic characterization of planetary materials, and searching for signatures of extinct life preserved in solid matrices.

  20. Highly Sensitive Tunable Diode Laser Spectrometers for In Situ Planetary Exploration

    NASA Technical Reports Server (NTRS)

    Vasudev, Ram; Mansour, Kamjou; Webster, Christopher R.

    2013-01-01

    This paper describes highly sensitive tunable diode laser spectrometers suitable for in situ planetary exploration. The technology developed at JPL is based on wavelength modulated cavity enhanced absorption spectroscopy. It is capable of sensitively detecting chemical signatures of life through the abundance of biogenic molecules and their isotopic composition, and chemicals such as water necessary for habitats of life. The technology would be suitable for searching for biomarkers, extinct life, potential habitats of extant life, and signatures of ancient climates on Mars; and for detecting biomarkers, prebiotic chemicals and habitats of life in the outer Solar System. It would be useful for prospecting for water on the Moon and asteroids, and characterizing its isotopic composition. Deployment on the Moon could provide ground truth to the recent remote measurements and help to uncover precious records of the early bombardment history of the inner Solar System buried at the shadowed poles, and elucidate the mechanism for the generation of near-surface water in the illuminated regions. The technology would also be useful for detecting other volatile molecules in planetary atmospheres and subsurface reservoirs, isotopic characterization of planetary materials, and searching for signatures of extinct life preserved in solid matrices.

  1. High-power ultrafast Yb:fiber laser frequency combs using commercially available components and basic fiber tools

    NASA Astrophysics Data System (ADS)

    Li, Xinlong; Reber, Melanie A. R.; Corder, Christopher; Chen, Yuning; Zhao, Peng; Allison, Thomas K.

    2016-09-01

    We present a detailed description of the design, construction, and performance of high-power ultrafast Yb:fiber laser frequency combs in operation in our laboratory. We discuss two such laser systems: an 87 MHz, 9 W, 85 fs laser operating at 1060 nm and an 87 MHz, 80 W, 155 fs laser operating at 1035 nm. Both are constructed using low-cost, commercially available components, and can be assembled using only basic tools for cleaving and splicing single-mode fibers. We describe practical methods for achieving and characterizing low-noise single-pulse operation and long-term stability from Yb:fiber oscillators based on nonlinear polarization evolution. Stabilization of the combs using a variety of transducers, including a new method for tuning the carrier-envelope offset frequency, is discussed. High average power is achieved through chirped-pulse amplification in simple fiber amplifiers based on double-clad photonic crystal fibers. We describe the use of these combs in several applications, including ultrasensitive femtosecond time-resolved spectroscopy and cavity-enhanced high-order harmonic generation.

  2. High-power ultrafast Yb:fiber laser frequency combs using commercially available components and basic fiber tools.

    PubMed

    Li, Xinlong; Reber, Melanie A R; Corder, Christopher; Chen, Yuning; Zhao, Peng; Allison, Thomas K

    2016-09-01

    We present a detailed description of the design, construction, and performance of high-power ultrafast Yb:fiber laser frequency combs in operation in our laboratory. We discuss two such laser systems: an 87 MHz, 9 W, 85 fs laser operating at 1060 nm and an 87 MHz, 80 W, 155 fs laser operating at 1035 nm. Both are constructed using low-cost, commercially available components, and can be assembled using only basic tools for cleaving and splicing single-mode fibers. We describe practical methods for achieving and characterizing low-noise single-pulse operation and long-term stability from Yb:fiber oscillators based on nonlinear polarization evolution. Stabilization of the combs using a variety of transducers, including a new method for tuning the carrier-envelope offset frequency, is discussed. High average power is achieved through chirped-pulse amplification in simple fiber amplifiers based on double-clad photonic crystal fibers. We describe the use of these combs in several applications, including ultrasensitive femtosecond time-resolved spectroscopy and cavity-enhanced high-order harmonic generation.

  3. High spatial resolution upgrade of the electron cyclotron emission radiometer for the DIII-D tokamak

    DOE PAGES

    Truong, D. D.; Austin, M. E.

    2014-11-01

    The 40-channel DIII-D electron cyclotron emission (ECE) radiometer provides measurements of Te(r,t) at the tokamak midplane from optically thick, second harmonic X-mode emission over a frequency range of 83-130 GHz. Heterodyning divides this frequency range into three 2-18 GHz intermediate frequency (IF) bands. The frequency spacing of the radiometer’s channels results in a spatial resolution of ~1-3 cm, depending on local magnetic field and electron temperature. A new high resolution subsystem has been added to the DIII-D ECE radiometer to make sub-centimeter (0.6-0.8 cm) resolution Te measurements. The high resolution subsystem branches off from the regular channels’ IF bands andmore » consists of a microwave switch to toggle between IF bands, a switched filter bank for frequency selectivity, an adjustable local oscillator and mixer for further frequency down-conversion, and a set of eight microwave filters in the 2-4 GHz range. We achieved a higher spatial resolution through the use of a narrower (200 MHz) filter bandwidth and closer spacing between the filters’ center frequencies (250 MHz). This configuration allows for full coverage of the 83-130 GHz frequency range in 2 GHz bands. Depending on the local magnetic field, this translates into a “zoomed-in” analysis of a ~2-4 cm radial region. These high resolution channels will be most useful in the low-field side edge region where modest Te values (1-2 keV) result in a minimum of relativistic broadening. Some expected uses of these channels include mapping the spatial dependence of Alfven eigenmodes, geodesic acoustic modes, and externally applied magnetic perturbations. Initial Te measurements, which demonstrate that the desired resolution is achieved, is presented.« less

  4. High spatial resolution upgrade of the electron cyclotron emission radiometer for the DIII-D tokamak

    SciTech Connect

    Truong, D. D.; Austin, M. E.

    2014-11-01

    The 40-channel DIII-D electron cyclotron emission (ECE) radiometer provides measurements of Te(r,t) at the tokamak midplane from optically thick, second harmonic X-mode emission over a frequency range of 83-130 GHz. Heterodyning divides this frequency range into three 2-18 GHz intermediate frequency (IF) bands. The frequency spacing of the radiometer’s channels results in a spatial resolution of ~1-3 cm, depending on local magnetic field and electron temperature. A new high resolution subsystem has been added to the DIII-D ECE radiometer to make sub-centimeter (0.6-0.8 cm) resolution Te measurements. The high resolution subsystem branches off from the regular channels’ IF bands and consists of a microwave switch to toggle between IF bands, a switched filter bank for frequency selectivity, an adjustable local oscillator and mixer for further frequency down-conversion, and a set of eight microwave filters in the 2-4 GHz range. We achieved a higher spatial resolution through the use of a narrower (200 MHz) filter bandwidth and closer spacing between the filters’ center frequencies (250 MHz). This configuration allows for full coverage of the 83-130 GHz frequency range in 2 GHz bands. Depending on the local magnetic field, this translates into a “zoomed-in” analysis of a ~2-4 cm radial region. These high resolution channels will be most useful in the low-field side edge region where modest Te values (1-2 keV) result in a minimum of relativistic broadening. Some expected uses of these channels include mapping the spatial dependence of Alfven eigenmodes, geodesic acoustic modes, and externally applied magnetic perturbations. Initial Te measurements, which demonstrate that the desired resolution is achieved, is presented.

  5. High flux circularly polarized gamma beam factory: coupling a Fabry-Perot optical cavity with an electron storage ring

    PubMed Central

    Chaikovska, I.; Cassou, K.; Chiche, R.; Cizeron, R.; Cornebise, P.; Delerue, N.; Jehanno, D.; Labaye, F.; Marie, R.; Martens, A.; Peinaud, Y.; Soskov, V.; Variola, A.; Zomer, F.; Cormier, E.; Lhermite, J.; Dolique, V.; Flaminio, R.; Michel, C.; Pinard, L.; Sassolas, B.; Akagi, T.; Araki, S.; Honda, Y.; Omori, T.; Terunuma, N.; Urakawa, J.; Miyoshi, S.; Takahashi, T.; Yoshitama, H.

    2016-01-01

    We report and discuss high-flux generation of circularly polarized γ-rays by means of Compton scattering. The γ-ray beam results from the collision of an external-cavity-enhanced infrared laser beam and a low emittance relativistic electron beam. By operating a non-planar bow-tie high-finesse optical Fabry-Perot cavity coupled to a storage ring, we have recorded a flux of up to (3.5 ± 0.3) × 108 photons per second with a mean measured energy of 24 MeV. The γ-ray flux has been sustained for several hours. In particular, we were able to measure a record value of up to 400 γ-rays per collision in a full bandwidth. Moreover, the impact of Compton scattering on the electron beam dynamics could be observed resulting in a reduction of the electron beam lifetime correlated to the laser power stored in the Fabry-Perot cavity. We demonstrate that the electron beam lifetime provides an independent and consistent determination of the γ-ray flux. Furthermore, a reduction of the γ-ray flux due to intrabeam scattering has clearly been identified. These results, obtained on an accelerator test facility, warrant potential scaling and revealed both expected and yet unobserved effects. They set the baseline for further scaling of the future Compton sources under development around the world. PMID:27857146

  6. High flux circularly polarized gamma beam factory: coupling a Fabry-Perot optical cavity with an electron storage ring

    NASA Astrophysics Data System (ADS)

    Chaikovska, I.; Cassou, K.; Chiche, R.; Cizeron, R.; Cornebise, P.; Delerue, N.; Jehanno, D.; Labaye, F.; Marie, R.; Martens, A.; Peinaud, Y.; Soskov, V.; Variola, A.; Zomer, F.; Cormier, E.; Lhermite, J.; Dolique, V.; Flaminio, R.; Michel, C.; Pinard, L.; Sassolas, B.; Akagi, T.; Araki, S.; Honda, Y.; Omori, T.; Terunuma, N.; Urakawa, J.; Miyoshi, S.; Takahashi, T.; Yoshitama, H.

    2016-11-01

    We report and discuss high-flux generation of circularly polarized γ-rays by means of Compton scattering. The γ-ray beam results from the collision of an external-cavity-enhanced infrared laser beam and a low emittance relativistic electron beam. By operating a non-planar bow-tie high-finesse optical Fabry-Perot cavity coupled to a storage ring, we have recorded a flux of up to (3.5 ± 0.3) × 108 photons per second with a mean measured energy of 24 MeV. The γ-ray flux has been sustained for several hours. In particular, we were able to measure a record value of up to 400 γ-rays per collision in a full bandwidth. Moreover, the impact of Compton scattering on the electron beam dynamics could be observed resulting in a reduction of the electron beam lifetime correlated to the laser power stored in the Fabry-Perot cavity. We demonstrate that the electron beam lifetime provides an independent and consistent determination of the γ-ray flux. Furthermore, a reduction of the γ-ray flux due to intrabeam scattering has clearly been identified. These results, obtained on an accelerator test facility, warrant potential scaling and revealed both expected and yet unobserved effects. They set the baseline for further scaling of the future Compton sources under development around the world.

  7. High spatial resolution upgrade of the electron cyclotron emission radiometer for the DIII-D tokamak

    SciTech Connect

    Truong, D. D.; Austin, M. E.

    2014-11-15

    The 40-channel DIII-D electron cyclotron emission (ECE) radiometer provides measurements of T{sub e}(r,t) at the tokamak midplane from optically thick, second harmonic X-mode emission over a frequency range of 83–130 GHz. The frequency spacing of the radiometer's channels results in a spatial resolution of ∼1–3 cm, depending on local magnetic field and electron temperature. A new high resolution subsystem has been added to the DIII-D ECE radiometer to make sub-centimeter (0.6–0.8 cm) resolution T{sub e} measurements. The high resolution subsystem branches off from the regular channels’ IF bands and consists of a microwave switch to toggle between IF bands, a switched filter bank for frequency selectivity, an adjustable local oscillator and mixer for further frequency down-conversion, and a set of eight microwave filters in the 2–4 GHz range. Higher spatial resolution is achieved through the use of a narrower (200 MHz) filter bandwidth and closer spacing between the filters’ center frequencies (250 MHz). This configuration allows for full coverage of the 83–130 GHz frequency range in 2 GHz bands. Depending on the local magnetic field, this translates into a “zoomed-in” analysis of a ∼2–4 cm radial region. Expected uses of these channels include mapping the spatial dependence of Alfven eigenmodes, geodesic acoustic modes, and externally applied magnetic perturbations. Initial T{sub e} measurements, which demonstrate that the desired resolution is achieved, are presented.

  8. A high linearity current mode second IF CMOS mixer for a DRM/DAB receiver

    NASA Astrophysics Data System (ADS)

    Jian, Xu; Zheng, Zhou; Yiqiang, Wu; Zhigong, Wang; Jianping, Chen

    2015-05-01

    A passive current switch mixer was designed for the second IF down-conversion in a DRM/DAB receiver. The circuit consists of an input transconductance stage, a passive current switching stage, and a current amplifier stage. The input transconductance stage employs a self-biasing current reusing technique, with a resistor shunt feedback to increase the gain and output impedance. A dynamic bias technique is used in the switching stage to ensure the stability of the overdrive voltage versus the PVT variations. A current shunt feedback is introduced to the conventional low-voltage second-generation fully balanced multi-output current converter (FBMOCCII), which provides very low input impedance and high output impedance. With the circuit working in current mode, the linearity is effectively improved with low supply voltages. Especially, the transimpedance stage can be removed, which simplifies the design considerably. The design is verified with a SMIC 0.18 μm RF CMOS process. The measurement results show that the voltage conversation gain is 1.407 dB, the NF is 16.22 dB, and the IIP3 is 4.5 dBm, respectively. The current consumption is 9.30 mA with a supply voltage of 1.8 V. This exhibits a good compromise among the gain, noise, and linearity for the second IF mixer in DRM/DAB receivers. Project supported by the National Natural Science Foundation of China (No. 61306069), and the National High Technology Research and Development Program of China (No. 2011AA010301).

  9. Emission from quantum-dot high-β microcavities: transition from spontaneous emission to lasing and the effects of superradiant emitter coupling

    DOE PAGES

    Kreinberg, Sören; Chow, Weng W.; Wolters, Janik; ...

    2017-02-28

    Measured and calculated results are presented for the emission properties of a new class of emitters operating in the cavity quantum electrodynamics regime. The structures are based on high-finesse GaAs/AlAs micropillar cavities, each with an active medium consisting of a layer of InGaAs quantum dots (QDs) and the distinguishing feature of having a substantial fraction of spontaneous emission channeled into one cavity mode (high β-factor). This paper demonstrates that the usual criterion for lasing with a conventional (low β-factor) cavity, that is, a sharp non-linearity in the input–output curve accompanied by noticeable linewidth narrowing, has to be reinforced by themore » equal-time second-order photon autocorrelation function to confirm lasing. The article also shows that the equal-time second-order photon autocorrelation function is useful for recognizing superradiance, a manifestation of the correlations possible in high-β microcavities operating with QDs. In terms of consolidating the collected data and identifying the physics underlying laser action, both theory and experiment suggest a sole dependence on intracavity photon number. Evidence for this assertion comes from all our measured and calculated data on emission coherence and fluctuation, for devices ranging from light-emitting diodes (LEDs) and cavity-enhanced LEDs to lasers, lying on the same two curves: one for linewidth narrowing versus intracavity photon number and the other for g(2)(0) versus intracavity photon number.« less

  10. High Resolution Direct Frequency Comb Spectroscopy of Vinyl Bromide (C_2H_3Br) and Nitromethane (CH_3NO_2) in the CH Stretch Region

    NASA Astrophysics Data System (ADS)

    Changala, Bryan; Spaun, Ben; Patterson, David; Ye, Jun

    2016-06-01

    We present high resolution rovibrational spectra of buffer gas cooled vinyl bromide (C_2H_3Br) and nitromethane (CH_3NO_2) in the 3 μm CH stretch region, acquired via cavity-enhanced direct frequency comb absorption spectroscopy. The ˜10 K translational and rotational temperatures of the molecular gas, as well as the narrow linewidth of the frequency comb, yield well resolved rotational structure, isotope shifts, and nuclear hyperfine splittings. Given the wide bandwidth of the light source and the long path length of the enhancement cavity, we measure entire vibrational bands in a single shot with high signal-to-noise ratios. We discuss spectra of the entire fundamental CH stretch manifolds of both C_2H_3Br and CH_3NO_2, which provide contrasting examples of rovibrational structure of rigid and non-rigid systems. C_2H_3Br is a relatively normal asymmetric top, exhibiting local perturbations to its rotational structure. Conversely, CH_3NO_2 contains an essentially unhindered methyl rotor. Of particular interest are its quasi-degenerate asymmetric CH stretch modes. Here, one must consider multiple couplings between torsional, rotational, and vibrational angular momentum, leading to qualitatively new level patterns and structure.

  11. Intermediate frequency band digitized high dynamic range radiometer system for plasma diagnostics and real-time Tokamak control

    SciTech Connect

    Bongers, W. A.; Beveren, V. van; Westerhof, E.; Goede, A. P. H.; Krijger, B.; Berg, M. A. van den; Graswinckel, M. F.; Schueller, F. C.; Thoen, D. J.; Nuij, P. J. W. M.; Baar, M. R. de; Donne, A. J. H.; Hennen, B. A.; Kantor, M.

    2011-06-15

    An intermediate frequency (IF) band digitizing radiometer system in the 100-200 GHz frequency range has been developed for Tokamak diagnostics and control, and other fields of research which require a high flexibility in frequency resolution combined with a large bandwidth and the retrieval of the full wave information of the mm-wave signals under investigation. The system is based on directly digitizing the IF band after down conversion. The enabling technology consists of a fast multi-giga sample analog to digital converter that has recently become available. Field programmable gate arrays (FPGA) are implemented to accomplish versatile real-time data analysis. A prototype system has been developed and tested and its performance has been compared with conventional electron cyclotron emission (ECE) spectrometer systems. On the TEXTOR Tokamak a proof of principle shows that ECE, together with high power injected and scattered radiation, becomes amenable to measurement by this device. In particular, its capability to measure the phase of coherent signals in the spectrum offers important advantages in diagnostics and control. One case developed in detail employs the FPGA in real-time fast Fourier transform (FFT) and additional signal processing. The major benefit of such a FFT-based system is the real-time trade-off that can be made between frequency and time resolution. For ECE diagnostics this corresponds to a flexible spatial resolution in the plasma, with potential application in smart sensing of plasma instabilities such as the neoclassical tearing mode (NTM) and sawtooth instabilities. The flexible resolution would allow for the measurement of the full mode content of plasma instabilities contained within the system bandwidth.

  12. Intermediate frequency band digitized high dynamic range radiometer system for plasma diagnostics and real-time Tokamak control.

    PubMed

    Bongers, W A; van Beveren, V; Thoen, D J; Nuij, P J W M; de Baar, M R; Donné, A J H; Westerhof, E; Goede, A P H; Krijger, B; van den Berg, M A; Kantor, M; Graswinckel, M F; Hennen, B A; Schüller, F C

    2011-06-01

    An intermediate frequency (IF) band digitizing radiometer system in the 100-200 GHz frequency range has been developed for Tokamak diagnostics and control, and other fields of research which require a high flexibility in frequency resolution combined with a large bandwidth and the retrieval of the full wave information of the mm-wave signals under investigation. The system is based on directly digitizing the IF band after down conversion. The enabling technology consists of a fast multi-giga sample analog to digital converter that has recently become available. Field programmable gate arrays (FPGA) are implemented to accomplish versatile real-time data analysis. A prototype system has been developed and tested and its performance has been compared with conventional electron cyclotron emission (ECE) spectrometer systems. On the TEXTOR Tokamak a proof of principle shows that ECE, together with high power injected and scattered radiation, becomes amenable to measurement by this device. In particular, its capability to measure the phase of coherent signals in the spectrum offers important advantages in diagnostics and control. One case developed in detail employs the FPGA in real-time fast Fourier transform (FFT) and additional signal processing. The major benefit of such a FFT-based system is the real-time trade-off that can be made between frequency and time resolution. For ECE diagnostics this corresponds to a flexible spatial resolution in the plasma, with potential application in smart sensing of plasma instabilities such as the neoclassical tearing mode (NTM) and sawtooth instabilities. The flexible resolution would allow for the measurement of the full mode content of plasma instabilities contained within the system bandwidth.

  13. Progress Towards a High-Precision Infrared Spectroscopic Survey of the H_3^+ Ion

    NASA Astrophysics Data System (ADS)

    Perry, Adam J.; Hodges, James N.; Markus, Charles R.; Kocheril, G. Stephen; Jenkins, Paul A., II; McCall, Benjamin J.

    2015-06-01

    The trihydrogen cation, H_3^+, represents one of the most important and fundamental molecular systems. Having only two electrons and three nuclei, H_3^+ is the simplest polyatomic system and is a key testing ground for the development of new techniques for calculating potential energy surfaces and predicting molecular spectra. Corrections that go beyond the Born-Oppenheimer approximation, including adiabatic, non-adiabatic, relativistic, and quantum electrodynamic corrections are becoming more feasible to calculate. As a result, experimental measurements performed on the H_3^+ ion serve as important benchmarks which are used to test the predictive power of new computational methods. By measuring many infrared transitions with precision at the sub-MHz level it is possible to construct a list of the most highly precise experimental rovibrational energy levels for this molecule. Until recently, only a select handful of infrared transitions of this molecule have been measured with high precision (˜ 1 MHz). Using the technique of Noise Immune Cavity Enhanced Optical Heterodyne Velocity Modulation Spectroscopy, we are aiming to produce the largest high-precision spectroscopic dataset for this molecule to date. Presented here are the current results from our survey along with a discussion of the combination differences analysis used to extract the experimentally determined rovibrational energy levels. O. Polyansky, et al., Phil. Trans. R. Soc. A (2012), 370, 5014. M. Pavanello, et al., J. Chem. Phys. (2012), 136, 184303. L. Diniz, et al., Phys. Rev. A (2013), 88, 032506. L. Lodi, et al., Phys. Rev. A (2014), 89, 032505. J. Hodges, et al., J. Chem. Phys (2013), 139, 164201.

  14. High Speed, Ultrasensitive Trace Gas Sensing

    NASA Astrophysics Data System (ADS)

    Long, David A.; Fleisher, Adam J.; Plusquellic, David F.; Hodges, Joseph

    2014-06-01

    I will describe a variety of cavity-enhanced spectroscopic techniques, including frequency-agile rapid scanning spectroscopy (FARS) and heterodyne-detected cavity ring-down spectroscopy (HD-CRDS), which we have recently developed for rapid, ultrasensitive absorption measurements. Scanning rates that are limited only by the cavity response time itself as well as noise-equivalent detection limits as low as 6×10-14 cm-1 Hz-1/2 have been achieved. I will discuss the application of these techniques to current problems in atmospheric science including recent infrared measurements of analytes which are present at ultra-trace concentrations.

  15. High Precision NO2 and NO measurements with the ICAD instrument during s-b-s campaign Hohenpeißenberg 2016

    NASA Astrophysics Data System (ADS)

    Pöhler, Denis; Lutz, Erik; Horbanski, Martin; Lampel, Johannes; Platt, Ulrich

    2017-04-01

    Nitrogen Oxides (NOx = NO2 + NO) play a major role in air pollution and atmospheric chemistry. Beside health effects they influence e.g. acid rain, ozone and oxidation capacity. But precise NO2 and NO measurements are still difficult. State of the art NO2 / NO instruments show significant interferences e.g. to H2O and HONO, problems of zero point and calibration drifts, temperature and also vibration influences. Other systems, especially low cost sensors, feature significant problems in terms of measurement accuracy and reliability. To overcome these problems we developed a direct spectroscopic NO2 / NOx ICAD instrument (Iterative Cavity Enhanced DOAS). It feature high accuracy, is relatively small, mobile and requires only low power consumption. During a side by side (s-b-s) inter-comparison campaign at the Meteorological Observatory Hohenpeißenberg (DWD) 2016 the performance of different instruments for NO2, NO and NOx were investigated under natural and artificial conditions. The concentration ranged from few ppt up to 100ppb. The inter-comparison demonstrates excellent performance of our ICAD in terms of accuracy and drift. In comparison to other techniques it features no interferences to different humidity's, temperatures and interfering gases. Also the zero point and calibration is absolutely stable. As the instrument is also much simpler and easier to operate, it has many advantages in comparison to other instruments. The characteristics of the instruments and results of the campaign will be presented.

  16. High-Precision Sub-Doppler Infrared Spectroscopy of HeH^+

    NASA Astrophysics Data System (ADS)

    Perry, Adam J.; Hodges, James N.; Markus, Charles; Kocheril, G. Stephen; Jenkins, Paul A., II; McCall, Benjamin J.

    2014-06-01

    The helium hydride ion, HeH^+, is the simplest heteronuclear diatomic, and is composed of the two most abundant elements in the universe. It is widely believed that this ion was among the first molecules to be formed; thus it has been of great interest to scientists studying the chemistry of the early universe. HeH^+ is also isoelectronic to H_2 which makes it a great target ion for theorists to include adiabatic and non-adiabatic corrections to its Born-Oppenheimer potential energy surface. The accuracy of such calculations is further improved by incorporating electron relativistic and quantum electrodynamic effects. Using the highly sensitive spectroscopic technique of Noise Immune Cavity Enhanced Optical Heterodyne Velocity Modulation Spectroscopy (NICE-OHVMS) we are able to perform sub-Doppler spectroscopy on ions of interest. When combined with frequency calibration from an optical frequency comb we fit line centers with sub-MHz precision as has previously been shown for the H3^+, HCO+, and CH5+ ions. Here we report a list of the most precisely measured rovibrational transitions of HeH^+ to date. These measurements should allow theorists to continue to push the boundaries of ab initio calculations in order to further study this important fundamental species. S. Lepp, P. C. Stancil, A. Dalgarno J. Phys. B (2002), 35, R57. S. Lepp, Astrophys. Space Sci. (2003), 285, 737. K. Pachucki, J. Komasa, J. Chem. Phys (2012), 137, 204314. J. N. Hodges, A. J. Perry, P. A. Jenkins II, B. M. Siller, B. J. McCall J. Chem. Phys. (2013), 139, 164201.

  17. Up/down conversion luminescence and charge compensation investigation of Ca0.5Y1-x(WO4)2:xLn3+ (Ln = Pr, Sm, Eu, Tb, Dy, Yb/Er) phosphors

    NASA Astrophysics Data System (ADS)

    Mahalingam, Venkatakrishnan; Thirumalai, Jagannathan; Krishnan, Rajagopalan; Mantha, Srinivas

    2016-01-01

    Microstructures of Ca0.5Y(1-x)(WO4)2:xLn3+ (Ln = Pr, Sm, Eu, Tb, Dy, Yb/Er) phosphors were prepared via the solid-state reaction method. X-ray diffraction, scanning electron microscopy and photoluminescence were used to characterize the prepared phosphor samples. The results reveal that the phosphor samples have single phase scheelite structures with tetragonal symmetry of I41/a. The down/up conversion photoluminescence of the Ca0.5Y(1-x)(WO4)2:xLn3+ (Ln = Pr, Sm, Eu, Tb, Dy, Yb/Er) phosphors properties reveal characteristic visible emissions. The energy transfer process, fluorescence lifetime and color coordinates are discussed in detail. Furthermore, the phosphor Ca0.5Y(1-x)(WO4)2:xPr3+ co-doped with alkali chlorides shows the enhancement of luminescence, which was found in the sodium chloride co-doped powder phosphor. The photometric characteristics indicate the suitability of the inorganic powder phosphors for solid-state lighting and display applications.

  18. Synthesis of Sr(1-x-y)Al4O7:Eux 2+,Lny 3+ (Ln = Dy, Y, Pr) nanophosphors using rapid gel combustion process and their down conversion characteristics

    NASA Astrophysics Data System (ADS)

    Singh, Devender; Tanwar, Vijeta; Samantilleke, Anura Priyajith; Mari, Bernabe; Bhagwan, Shri; Singh, Krishan Chander; Kadyan, Pratap Singh; Singh, Ishwar

    2017-05-01

    Eu2+ and Eu2++Ln3+ doped SrAl4O7 nanophosphors were synthesized by rapid gel combustion process. The morphology of prepared phosphors was examined with scanning and transmission electron microscopy. The phase identification and the crystal structures of nanophosphors were studied using X-ray powder diffraction techniques. Luminescence characteristics of the prepared nanophosphors were analyzed on account of excitation, emission and phosphorescence decay analysis. The emission spectra demonstrated the broad green emission attributed to 4f65d1→ 4f7 transition of the Eu2+ ions. The effect of codoping of some trivalent lanthanide (Dy3+, Pr3+ and Y3+) ions were investigated for improving the emission intensity and phosphorescence decay time of the basic lattice of SrAl4O7:Eu2+ phosphors. The synthesized materials had enhanced bright luminescent properties that could suitably be applied for display as well as photovoltaic applications. [Figure not available: see fulltext.

  19. Synthesis of Sr(1-x-y)Al4O7:Eu{x/2+},Ln{y/3+} (Ln = Dy, Y, Pr) nanophosphors using rapid gel combustion process and their down conversion characteristics

    NASA Astrophysics Data System (ADS)

    Singh, Devender; Tanwar, Vijeta; Samantilleke, Anura Priyajith; Mari, Bernabe; Bhagwan, Shri; Singh, Krishan Chander; Kadyan, Pratap Singh; Singh, Ishwar

    2017-03-01

    Eu2+ and Eu2++Ln3+ doped SrAl4O7 nanophosphors were synthesized by rapid gel combustion process. The morphology of prepared phosphors was examined with scanning and transmission electron microscopy. The phase identification and the crystal structures of nanophosphors were studied using X-ray powder diffraction techniques. Luminescence characteristics of the prepared nanophosphors were analyzed on account of excitation, emission and phosphorescence decay analysis. The emission spectra demonstrated the broad green emission attributed to 4f65d1→ 4f7 transition of the Eu2+ ions. The effect of codoping of some trivalent lanthanide (Dy3+, Pr3+ and Y3+) ions were investigated for improving the emission intensity and phosphorescence decay time of the basic lattice of SrAl4O7:Eu2+ phosphors. The synthesized materials had enhanced bright luminescent properties that could suitably be applied for display as well as photovoltaic applications. [Figure not available: see fulltext.

  20. Applications of High-Q Microresonators in Cavity Optomechanics and Nonlinear Photonics

    NASA Astrophysics Data System (ADS)

    Jiang, Wei C.

    Optical microresonators confining light to small volumes are indispensable for a great variety of studies and applications. This thesis is devoted to a study of cavity optomechanical and nonlinear optical phenomena in high-Q microresonators with different materials and structures. Based on that, it proposes and demonstrates several novel schemes and device platforms that exhibit great potential for various applications ranging from frequency metrology and quantum photonics, to information processing and sensing. The thesis starts with a demonstration of a high-frequency (above 1 GHz) regenerative optomechanical oscillator based on a 2-mum-radius high-Q silicon microdisk resonator in the silicon-on-insulator platform with an ultra-low threshold pump power at room temperature and atmosphere. It then continues to explore the cavity optomechanics in single-crystal lithium niobate. A compact lithium niobate microdisk optomechanical resonator with high optical and mechanical qualities, large optomechanical coupling, and high mechanical frequency is achieved, enabling the demonstration of regenerative oscillation in the ambience. Meanwhile, I propose and investigate a novel approach for single molecule detection that utilizes the optical spring effect in a high-Q coherent optomechanical oscillator to dramatically enhance the sensing resolution by orders of magnitude compared with conventional resonator-based approaches. In particular, a high-Q silica microsphere is employed to experimentally demonstrate the detection of single Bovine Serum Albumin proteins with a molecular weight of 66 kDalton at a signal-to-noise ratio of 16.8. On the other hand, the thesis focuses on the theoretical and experimental investigation of the generation of high-purity bright photon pairs in a silicon microdisk based on the cavity enhanced four-wave mixing. The device is able to produce multiple photon pairs at different wavelengths in the telecom band with a high spectral brightness of 6.24 x

  1. Airborne measurements of CO2 and CH4 onboard the UK FAAM research aircraft using a, Los Gatos Research Inc, cavity enhanced absorption spectrometer

    NASA Astrophysics Data System (ADS)

    O'Shea, S.; Bauguitte, S.; Muller, J. B.; Le Breton, M.; Gallagher, M. W.; Allen, G.; Percival, C. J.

    2012-12-01

    Airborne measurements of CO2 and CH4 have been made using the UK Facility for Airborne Atmospheric Measurements (FAAM) BAe-146 research aircraft since spring 2011.The measurement system uses a commercially available analyser, based on the off-axis integrated cavity output spectroscopy technique, from Los Gatos Research Inc (FGGA, Model RMT-200). During the first year of operation (29 flights), 1 Hz measurements were found to be accurate to 0.07 ± 2.48ppbv for CH4 and -0.06± 0.66ppmv for CO2. In summer 2011, as part of the BORTAS project (Quantifying the impact of BOReal forest fires on Tropospheric oxidants over the Atlantic using Aircraft and Satellites), outflow from boreal forest fires was measured in Eastern Canada. A number of fresh and photochemically-aged plumes were identified using simultaneous HCN measurements, a widely used tracer for biomass burning. In the freshest plumes, strong relationships were found between CH4, CO2 and other tracers for biomass burning. From this we were able to estimate that 6.9±0.8 g of CH4 and 1551±213 g of CO2 were released into the atmosphere per kg of dry matter burnt. These emission factors are in good agreement with estimates from previous studies in boreal regions. However for aged plumes the correlations between CH4 and other biomass burning tracers were not as robust, most likely due to mixing from other CH4 emission sources, such as the wetland regions. The role of additional emission sources will be investigated using the UK Met Office NAME atmospheric dispersion model and the HYSPLIT trajectory model. Using tailored back trajectory analysis, we will present an interpretation of this new dataset in the context of air mass/fire origin, relating this to MODIS fire maps and source strength.

  2. High-accurate nonlocal timing and positioning using entangled photon pairs

    NASA Astrophysics Data System (ADS)

    Valencia Gonzalez, Alejandra C.

    One of the most surprising consequences of quantum mechanics is the concept of entanglement. This concept has intrigued the scientific community since it was first proposed by Einstein, Podolsky and Rosen in 1935 because of its connection to fundamental aspects regarding our conception of the universe. Nowadays, there are still open questions about the fundamental issues of quantum mechanics. Nevertheless, the unique characteristics of entanglement have been proposed for practical applications in the last years. Spontaneous Parametric Down Conversion (SPDC) has been recognized as a convenient source of entangled photon pairs. SPDC is a nonlinear optical process in which a pump laser beam is shone into a nonlinear crystal and occasionally one pump photon is down-converted to a pair of lower frequency photons that are entangled. Two photons in an entangled state are characterized by a single two-photon effective wavefunction, or Biphoton. They cannot be considered as the simple juxtaposition of two individual systems. This is a consequence of the quantum correlations between the two photons and implies that a measurement in one of the subsystems affects the total state of the composite system and, therefore, affects the output of a measurement performed in the other photon. The purpose of this dissertation is to show the potential of entangled photon pairs for high-accurate timing and positioning measurements. The entangled nature of the two-photon states allows, in principle, precise space-time correlation measurements to the femtosecond level, providing the physical foundations for high-accurate nonlocal distant clock synchronization. In this dissertation, the proof-of-principle demonstration of a "one-way" distant clock synchronization protocol is presented. The novel method is based on the measurements of the second order correlation function of entangled photon pairs. An experimental study of the behavior of the Biphoton when it travels through a dispersive

  3. Quantum storage of heralded single photons in a praseodymium-doped crystal.

    PubMed

    Rieländer, Daniel; Kutluer, Kutlu; Ledingham, Patrick M; Gündoğan, Mustafa; Fekete, Julia; Mazzera, Margherita; de Riedmatten, Hugues

    2014-01-31

    We report on experiments demonstrating the reversible mapping of heralded single photons to long-lived collective optical atomic excitations stored in a Pr3+:Y2SiO5 crystal. A cavity-enhanced spontaneous down-conversion source is employed to produce widely nondegenerate narrow-band (≈2  MHz) photon pairs. The idler photons, whose frequency is compatible with telecommunication optical fibers, are used to herald the creation of the signal photons, compatible with the Pr3+ transition. The signal photons are stored and retrieved using the atomic frequency comb protocol. We demonstrate storage times up to 4.5  μs while preserving nonclassical correlations between the heralding and the retrieved photon. This is more than 20 times longer than in previous realizations in solid state devices, and implemented in a system ideally suited for the extension to spin-wave storage.

  4. Dismantling the "Red Wall" of Colloidal Perovskites: Highly Luminescent Formamidinium and Formamidinium-Cesium Lead Iodide Nanocrystals.

    PubMed

    Protesescu, Loredana; Yakunin, Sergii; Kumar, Sudhir; Bär, Janine; Bertolotti, Federica; Masciocchi, Norberto; Guagliardi, Antonietta; Grotevent, Matthias; Shorubalko, Ivan; Bodnarchuk, Maryna I; Shih, Chih-Jen; Kovalenko, Maksym V

    2017-03-28

    Colloidal nanocrystals (NCs) of APbX3-type lead halide perovskites [A = Cs(+), CH3NH3(+) (methylammonium or MA(+)) or CH(NH2)2(+) (formamidinium or FA(+)); X = Cl(-), Br(-), I(-)] have recently emerged as highly versatile photonic sources for applications ranging from simple photoluminescence down-conversion (e.g., for display backlighting) to light-emitting diodes. From the perspective of spectral coverage, a formidable challenge facing the use of these materials is how to obtain stable emissions in the red and infrared spectral regions covered by the iodide-based compositions. So far, red-emissive CsPbI3 NCs have been shown to suffer from a delayed phase transformation into a nonluminescent, wide-band-gap 1D polymorph, and MAPbI3 exhibits very limited chemical durability. In this work, we report a facile colloidal synthesis method for obtaining FAPbI3 and FA-doped CsPbI3 NCs that are uniform in size (10-15 nm) and nearly cubic in shape and exhibit drastically higher robustness than their MA- or Cs-only cousins with similar sizes and morphologies. Detailed structural analysis indicated that the FAPbI3 NCs had a cubic crystal structure, while the FA0.1Cs0.9PbI3 NCs had a 3D orthorhombic structure that was isostructural to the structure of CsPbBr3 NCs. Bright photoluminescence (PL) with high quantum yield (QY > 70%) spanning red (690 nm, FA0.1Cs0.9PbI3 NCs) and near-infrared (near-IR, ca. 780 nm, FAPbI3 NCs) regions was sustained for several months or more in both the colloidal state and in films. The peak PL wavelengths can be fine-tuned by using postsynthetic cation- and anion-exchange reactions. Amplified spontaneous emissions with low thresholds of 28 and 7.5 μJ cm(-2) were obtained from the films deposited from FA0.1Cs0.9PbI3 and FAPbI3 NCs, respectively. Furthermore, light-emitting diodes with a high external quantum efficiency of 2.3% were obtained by using FAPbI3 NCs.

  5. Highly uniform and monodisperse beta-NaYF(4):Ln(3+) (Ln = Eu, Tb, Yb/Er, and Yb/Tm) hexagonal microprism crystals: hydrothermal synthesis and luminescent properties.

    PubMed

    Li, Chunxia; Quan, Zewei; Yang, Jun; Yang, Piaoping; Lin, Jun

    2007-08-06

    beta-NaYF4:Ln3+ (Ln = Eu, Tb, Yb/Er, and Yb/Tm) hexagonal microprisms with remarkably uniform morphology and size have been synthesized via a facile hydrothermal route. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), and photoluminescence (PL) spectra as well as kinetic decays were used to characterize the samples. It is found that sodium citrate as a shape modifier introduced into the reaction system plays a critical role in the shape evolution of the final products. Furthermore, the shape and size of the products can be further manipulated by adjusting the molar ratio of citrate/RE3+ (RE represents the total amount of Y3+ and the doped rare earth elements such as Eu3+, Tb3+, Yb3+/Er3+, or Yb3+/Tm3+). Under the excitation of 397 nm ultraviolet light, NaYF4:xEu3+ (x = 1.5, 5%) shows the emission lines of Eu3+ corresponding to 5D0-3 --> 7FJ (J = 0-4) transitions from 400 to 700 nm (whole visible spectral region) with different intensity, resulting in yellow and red down-conversion (DC) light emissions, respectively. When doped with 5% Tb3+ ions, the strong DC fluorescence corresponding to 5D4 --> 7FJ (J = 6, 5, 4, 3) transitions with 5D4 --> 7F5 (green emission at 544 nm) being the most prominent group that has been observed. In addition, under 980 nm laser excitation, the Yb3+/Er3+- and Yb3+/Tm3+-codoped beta-NaYF4 samples exhibit bright green and whitish blue up-conversion (UC) luminescence, respectively. The luminescence mechanisms for the doped lanthanide ions were thoroughly analyzed.

  6. High Frequency Measurements of Methane Concentrations and Carbon Isotopes at a Marsh and Landfill

    NASA Astrophysics Data System (ADS)

    Mortazavi, B.; Wilson, B.; Chanton, J.; Eller, K.; Dong, F.; Baer, D. S.; Gupta, M.; Dzwonkowski, B.

    2012-12-01

    High frequency measurements of methane concentrations and carbon isotopes can help constrain the source strengths of methane emitted to the atmosphere. We report here methane concentrations and 13C values measured at 0.5 Hz with cavity enhanced laser absorption spectrometers (Los Gatos Research) deployed at a saltmarsh in Alabama and a landfill in Florida. Methane concentrations and 13C at the saltmarsh were monitored over a 2.5 day time period at 2 m, 0.5 m above the ground as well as from the outflow of a flow-through (2 L) chamber placed on the Spartina alterniflora dominated marsh. A typical measurement cycle included regular samples from two tanks of known methane concentrations and isotopic values and from ambient air samples. Over the 2.5-day measurement period methane concentrations and isotopic ratios at 2 m averaged 1.85 ppm and -43.57‰ (±0.34, 1 SE), respectively. The concentration and isotopic values from the chamber outflow varied from 1.92 to 5.81 ppm and -38.5 to -59.3‰, respectively. Methane flux from the marsh ranged from undetectable to 3.6 mgC m-2hr-1, with high fluxes measured during low tide. The 13δCH4 of the emitted CH4 from the marsh, determined from a mass balance equation using the chamber inflow and outflow concentration and isotopic values ranged from -62.1 to -93.9‰ and averaged -77‰ (±1.25, 1SE). At the landfill ambient methane concentrations and 13C ratios measured over multiple days varied from 4.25 to 11.91 ppm and from -58.81 to -45.12‰, respectively. At higher methane concentrations the δ13C of CH4 was more depleted consistent with previously observed relationship at this site made by more traditional techniques. Over a 30-minute measurement period CH4 concentrations at the landfill could vary by as much as 15 ppm. The high frequency continuous optical measurements with field-deployed instruments provide us with an unprecedented temporal resolution of CH4 concentrations and isotopic ratios. These measurements will

  7. Optoelectronics for high-speed, wavelength-division- multiplexed optical communications networks

    NASA Astrophysics Data System (ADS)

    Hudgings, Janice Anne

    1999-11-01

    All-optical wavelength division multiplexed (WDM) communications networks have the potential to revolutionize future high-speed communications. All- optical networks offer enormous bandwidth capacity on the order of 25 THz, which is orders of magnitude greater than the capacity of radio or copper coaxial cable. In addition, wavelength division multiplexing offers a natural method of supporting with a single network multiple simultaneous applications with widely varying bandwidth requirements, modulation formats, and quality of service requirements. However, future implementation of all-optical WDM networks relies on further development of optical device technology. We present an experimental demonstration of a step- tunable, all-optical wavelength converter using cavity- enhanced four wave mixing (FWM) in a semiconductor laser. The converter is modulation format transparent, has a high conversion efficiency (> -10 dB), and is step- tunable over a large conversion range (> 2.5 THz). In addition, we derive a mathematical model of the wavelength converter, which is used to simulate step- tuning and to examine the relationship between the conversion efficiency and information bandwidth of the device. Likewise, the development of appropriate optical sources is critical to the success of all-optical communications networks. Vertical-cavity surface-emitting lasers (VCSELs) are rapidly emerging as strong competitors to the conventional edge-emitting semiconductor lasers. We have developed a novel three-contact VCSEL with an intracavity quantum-well absorber. The three-contact design of this structure enables independent control of the gain and absorber regions. If the VCSEL is designed such that the lasing wavelength is shorter than the bandedge of the intracavity absorber, the laser exhibits broad negative differential resistance, due to changes in the cavity photon density as the relative absorption is varied. With this design, the device is useful as an integrated

  8. Reduced erbium-doped ceria nanoparticles: one nano-host applicable for simultaneous optical down- and up-conversions.

    PubMed

    Shehata, Nader; Meehan, Kathleen; Hassounah, Ibrahim; Hudait, Mantu; Jain, Nikhil; Clavel, Michael; Elhelw, Sarah; Madi, Nabil

    2014-01-01

    This paper introduces a new synthesis procedure to form erbium-doped ceria nanoparticles (EDC NPs) that can act as an optical medium for both up-conversion and down-conversion in the same time. This synthesis process results qualitatively in a high concentration of Ce(3+) ions required to obtain high fluorescence efficiency in the down-conversion process. Simultaneously, the synthesized nanoparticles contain the molecular energy levels of erbium that are required for up-conversion. Therefore, the synthesized EDC NPs can emit visible light when excited with either UV or IR photons. This opens new opportunities for applications where emission of light via both up- and down-conversions from a single nanomaterial is desired such as solar cells and bio-imaging.

  9. High resolution measurements of carbon monoxide along a late Holocene Greenland ice core: evidence for in situ production

    NASA Astrophysics Data System (ADS)

    Faïn, X.; Chappellaz, J.; Rhodes, R. H.; Stowasser, C.; Blunier, T.; McConnell, J. R.; Brook, E. J.; Preunkert, S.; Legrand, M.; Debois, T.; Romanini, D.

    2014-05-01

    We present high-resolution measurements of carbon monoxide (CO) concentrations from a shallow ice core of the North Greenland Eemian Ice Drilling project (NEEM-2011-S1). An optical-feedback cavity-enhanced absorption spectrometer (OF-CEAS) coupled to a continuous melter system performed continuous, online analysis during a four-week measurement campaign. This analytical setup generated stable measurements of CO concentrations with an external precision of 7.8 ppbv (1σ), based on repeated analyses of equivalent ice core sections. However, this first application of this measurement technique suffered from a poorly constrained procedural blank of 48 ± 25 ppbv and poor accuracy because an absolute calibration was not possible. The NEEM-2011-S1 CO record spans 1800 yr and the long-term trends within the most recent section of this record (i.e., post 1700 AD) resemble the existing discrete CO measurements from the Eurocore ice core. However, the CO concentration is highly variable (75-1327 ppbv range) throughout the ice core with high frequency (annual scale), high amplitude spikes characterizing the record. These CO signals are too abrupt and rapid to reflect atmospheric variability and their prevalence largely prevents interpretation of the record in terms of atmospheric CO variation. The abrupt CO spikes are likely the result of in situ production occurring within the ice itself, although the unlikely possibility of CO production driven by non-photolytic, fast kinetic processes within the continuous melter system cannot be excluded. We observe that 68% of the CO spikes are observed in ice layers enriched with pyrogenic aerosols. Such aerosols, originating from boreal biomass burning emissions, contain organic compounds, which may be oxidized or photodissociated to produce CO within the ice. However, the NEEM-2011-S1 record displays an increase of ~0.05 ppbv yr-1 in baseline CO level prior to 1700 AD (129 m depth) and the concentration remains elevated, even for ice

  10. Imaging high-dimensional spatial entanglement with a camera.

    PubMed

    Edgar, M P; Tasca, D S; Izdebski, F; Warburton, R E; Leach, J; Agnew, M; Buller, G S; Boyd, R W; Padgett, M J

    2012-01-01

    The light produced by parametric down-conversion shows strong spatial entanglement that leads to violations of EPR criteria for separability. Historically, such studies have been performed by scanning a single-element, single-photon detector across a detection plane. Here we show that modern electron-multiplying charge-coupled device cameras can measure correlations in both position and momentum across a multi-pixel field of view. This capability allows us to observe entanglement of around 2,500 spatial states and demonstrate Einstein-Podolsky-Rosen type correlations by more than two orders of magnitude. More generally, our work shows that cameras can lead to important new capabilities in quantum optics and quantum information science.

  11. High-efficiency frequency upconversion of 1.5 μm laser based on a doubly resonant external ring cavity with a low finesse for signal field

    NASA Astrophysics Data System (ADS)

    Tan, Wei; Qiu, Xiaodong; Zhao, Gang; Jia, Mengyuan; Ma, Weiguang; Yan, Xiaojuan; Dong, Lei; Zhang, Lei; Tong, Zhaomin; Yin, Wangbao; Feng, Xiaoxia; Xiao, Liantuan; Axner, Ove; Jia, Suotang

    2017-02-01

    A doubly resonant external ring cavity with a low finesse for the signal field is used to improve the frequency upconversion efficiency of a weak 1583 nm signal laser to 636 nm by mixing with a resonance power enhanced 1064 nm pump laser in a 25 mm periodically poled lithium niobate crystal. The process of frequency upconversion is described and optimized by the doubly resonant cavity-enhanced sum frequency generation theory under the condition of undepleted pump approximation. By selecting the suitable reflectivity of the signal input mirror and the incident pump power, a cavity-enhanced frequency conversion efficiency of 94.6% was obtained for signal powers up to 25 mW with an input pump power of 780 mW.

  12. Department of Energy Office of Energy Efficiency and Renewable Energy Solid State Lighting Core Technologies

    SciTech Connect

    Franky So; Paul Holloway; Jiangeng Xue

    2009-08-06

    The project objective is to demonstrate high efficiency white emitting OLED devices with a target luminous efficiency between 100 1m/W and 150 1m/W with integrated microcavity structure and down conversion phosphors. The main focus of this work will be on three areas: (1) demonstration of a 2X reduction in OLED device operating voltage by employing the appropriate dopants in the carrier transporting layers; (2) demonstration of a 3X light out-coupling efficiency enhancement by incorporating microcavity structure in the OLED devices; and (3) demonstration of a 2X down-conversion efficiency enhancement (from blue to white) using phosphors.

  13. Photon recycling across a ultraviolet-blocking layer by luminescence in polymer solar cells

    NASA Astrophysics Data System (ADS)

    Engmann, Sebastian; Machalett, Marie; Turkovic, Vida; Rösch, Roland; Rädlein, Edda; Gobsch, Gerhard; Hoppe, Harald

    2012-08-01

    UV-blocking layers can increase the long term stability of organic solar cell devices; however, they limit the amount of light that can be utilized for energy conversion. We present photon recycling and down-conversion via a luminescent layer across a UV-blocking TiO2 layer. Our results show that the use of an additional UV-blocking layer does not necessarily reduce the overall efficiency of organic solar cells, since the loss in photocurrent due to the UV-absorption loss can be partially compensated using high energy photon down-conversion via luminescence layers.

  14. Monolithically integrated optoelectronic down-converter (MIOD)

    NASA Astrophysics Data System (ADS)

    Portnoi, Efrim L.; Venus, G. B.; Khazan, A. A.; Gorfinkel, Vera B.; Kompa, Guenter; Avrutin, Evgenii A.; Thayne, Iain G.; Barrow, David A.; Marsh, John H.

    1995-06-01

    Optoelectronic down-conversion of very high-frequency amplitude-modulated signals using a semiconductor laser simultaneously as a local oscillator and a mixer is proposed. Three possible constructions of a monolithically integrated down-converter are considered theoretically: a four-terminal semiconductor laser with dual pumping current/modal gain control, and both a passively mode-locked and a passively Q-switched semiconductor laser monolithically integrated with an electroabsorption or pumping current modulator. Experimental verification of the feasibility of the concept of down conversion in a laser diode is presented.

  15. Spectral correlation and interference in non-degenerate photon pairs at telecom wavelengths.

    PubMed

    Kuo, Paulina S; Gerrits, Thomas; Verma, Varun B; Nam, Sae Woo

    2016-11-01

    We characterize an entangled-photon-pair source that produces signal and idler photons at 1533 nm and 1567 nm using fiber-assisted signal-photon spectroscopy. By erasing the polarization distinguishability, we observe interference between the two down-conversion paths. The observed interference signature is closely related to the spectral correlations between photons in a Hong-Ou-Mandel interferometer. These measurements suggest good indistinguishability between the two down-conversion paths, which is required for high entanglement visibility.

  16. Continuous Supersonic Expansion Discharge Source for High-Precision Mid-Infrared Spectroscopy of Cold Molecular Ions

    NASA Astrophysics Data System (ADS)

    Talicska, Courtney; Porambo, Michael; McCall, Benjamin J.

    2015-06-01

    The low temperatures and pressures of the interstellar medium provide an ideal environment for gas phase ion-neutral reactions that play an essential role in the chemistry of the universe. High-precision laboratory spectra of molecular ions are necessary to facilitate new astronomical discoveries and provide a deeper understanding of interstellar chemistry, but forming ions in measurable quantities in the laboratory has proved challenging. Even when cryogenically cooled, the high temperatures and pressures of typical discharge cells lead to diluted and congested spectra from which extracting chemical information is difficult. Here we overcome this challenge by coupling an electric discharge to a continuous supersonic expansion source to form ions cooled to low temperatures. The ion production abilities of the source have been demonstrated previously as ion densities on the order of 1010-1012 cm-3 have been observed for H3+.a With a smaller rotational constant and the expectation that it will be formed with comparable densities, HN2+ is used as a reliable measure of the cooling abilities of the source. Ions are probed through the use of a widely tunable mid-infrared (3-5 μm) spectrometer based on light formed by difference frequency generation and noise-immune cavity-enhanced optical heterodyne molecular spectroscopy (NICE-OHMS).b To improve the sensitivity of the instrument the discharge is electrically modulated and the signal is fed into a lock-in amplifier before being recorded by a custom data acquisition program. Rovibrational transitions of H3+ and HN2+ have been recorded, giving rotational temperatures of 80-120 K and 35-40 K, respectively. With verification that the source is producing rotationally cold ions, we move toward the study of primary ions of more astronomical significance, including H2CO+. aK. N. Crabtree, C. A. Kaufman, and B. J. McCall, Rev. Sci. Instrum. 81, 086103 (2010). bM. W. Porambo, B. M. Siller, J. M. Pearson, and B. J. McCall, Opt

  17. Planning High-Tech High.

    ERIC Educational Resources Information Center

    Hymon, Steve

    1997-01-01

    Examines the planning process for developing a high-tech high school using the example of one such school in Florida's Collier County school district. Addresses budget figures, planning objectives, organizational considerations, pilot program creation, and planning tips. (GR)

  18. High PRF high current switch

    DOEpatents

    Moran, Stuart L.; Hutcherson, R. Kenneth

    1990-03-27

    A triggerable, high voltage, high current, spark gap switch for use in pu power systems. The device comprises a pair of electrodes in a high pressure hydrogen environment that is triggered by introducing an arc between one electrode and a trigger pin. Unusually high repetition rates may be obtained by undervolting the switch, i.e., operating the trigger at voltages much below the self-breakdown voltage of the device.

  19. High Schools.

    ERIC Educational Resources Information Center

    Educational Facility Planner, 2002

    2002-01-01

    Describes the building designs of 28 high schools, including their educational contexts and design goals. Includes information on size, construction costs, architects, and contractors. Also includes floor plans and photographs. (EV)

  20. High arch

    MedlinePlus

    ... condition can make it difficult to fit into shoes. People who have high arches most often need ... Symptoms include: Shortened foot length Difficulty fitting shoes Foot pain with walking, standing, and running (not everyone has this symptom)

  1. Ultrasensitive, High Accuracy Measurements of Trace Gas Species

    NASA Astrophysics Data System (ADS)

    Long, David A.; Fleisher, Adam J.; Plusquellic, David F.; Hodges, Joseph

    2015-06-01

    Our laboratory seeks to apply novel cavity-enhanced spectroscopic techniques to present problems in atmospheric and physical chemistry. Primarily we use cavity ring-down spectroscopy in which the passive decay of optical power within a Fabry-Pérot resonator is utilized to extract an absorption signal. With this technique we have demonstrated quantum (shot) noise limited sensitivities in both the near-infrared and mid-infrared spectral regions. Both commercial and home-built optical frequency combs are employed either to serve as absolute frequency references for molecular spectra or in a multiheterodyne approach for multiplexed sensing. I will discuss this novel instrumentation as well as measurements we have made of atmospherically relevant species such as CO2, H2O, O2, CH4, and CO with implications for in situ and remote (i.e. satellite-based) sensing. I will conclude by discussing future directions and plans for challenging measurements in the mid-infrared.

  2. Multisite high resolution measurements of carbon monoxide along Greenland ice cores: evidence for in-situ production and potential for atmospheric reconstruction

    NASA Astrophysics Data System (ADS)

    Faïn, Xavier; Chappellaz, Jérôme; Rhodes, Rachael; Stowasser, Christopher; Blunier, Thomas; McConnell, Joseph; Brook, Edward; Desbois, Thibault; Romanini, Daniele

    2014-05-01

    Carbon monoxide (CO) is the principal sink for hydroxyl radicals (OH) in the troposphere. Consequently, changes in atmospheric CO levels can considerably perturb the oxidizing capacity of the atmosphere, affecting mixing ratios of a host of chemical species oxidized by OH, including methane. In addition, CO variations (and changes in its stable isotopic composition) are expected to be good tracers of changes in biomass burning emissions. Investigating past mixing ratios of carbon monoxide is thus a promising approach towards reducing uncertainty related to the past oxidative capacity of the atmosphere and biogeochemical cycling of methane. Recent developments in optical spectrometry (Optical Feedback Cavity Enhanced Absorption Spectrometry, OFCEAS), combined with continuous flow analysis (CFA) systems, allow efficient, precise measurements of CO concentrations in ice cores. Coupling our OFCEAS spectrometer with the CFA melter operated at DRI (Reno, USA) provided the first continuous CO measurements along the NEEM (Greenland) core covering the last 1800 yr at an unprecedented resolution. Although the most recent section of this record (i.e., since 1700 AD) agreed with existing discrete CO measurements from the Eurocore ice core and the deep NEEM firn, it was difficult to interpret in terms of atmospheric CO variation due to high frequency, high amplitudes spikes related to in-situ production (Faïn et al., Climate of the Past Discussion). During a recent 8-week analytical campaign, three different ice archives from Greenland were melted on the DRI CFA and analyzed continuously for CO with the OFCEAS spectrometer: (i) the D4 core (spanning the last 170 yr), (ii) the NEEM core (extending the existing record from 200 AD to 800 BC), and (iii) the Tunu core (spanning the last 1800 yr). Although in-situ production of CO is observed at all sites, these new records reveal different CO patterns and trends. This multisite approach allows us to better characterize the

  3. High Class

    ERIC Educational Resources Information Center

    Waldecker, Mark

    2005-01-01

    Education administrators make buying decisions for furniture based on many factors. Cost, durability, functionality, safety and aesthetics represent just a few. Those issues always will be important, but gaining greater recognition in recent years has been the role furniture plays in creating positive, high-performance learning environments. The…

  4. High Stakes

    ERIC Educational Resources Information Center

    Elgin, Catherine Z.

    2004-01-01

    I discuss the contributions of Harvey Siegel, Francis Schrag and Randall Curren to this volume. Their articles cast in bold relief the relation of High Stakes Testing to the goals of education, the nature of mind and the demands of justice. I argue that the connections are deep, but that the considerations these authors raise do not show that High…

  5. Fast time resolution measurements of high concentrations of iodine above a Laminaria Digitata seaweed bed

    NASA Astrophysics Data System (ADS)

    Ball, Stephen; Adams, Thomas; Leblanc, Catherine; Potin, Philippe

    2013-04-01

    We report observations of extremely large concentrations of molecular iodine (I2) measured in situ above a seaweed bed composed of laminaria digitata (90%) and laminaria hyperborea (10%) growing in its natural habitat. Measurements were made off the coast of Roscoff in Brittany, France, during day-time low tides on several days in September and November 2012 with the greatest tidal amplitudes. Iodine was quantified using a portable, battery-powered broadband cavity enhanced absorption spectrometer (BBCEAS) deployed from the in-shore research vessel "Aurelia" operated by the Station Biologique de Roscoff. For the 5 second integration times used here, the BBCEAS instrument has a detection limit for iodine of 12 pptv (parts per trillion by volume). The boat was anchored above the seaweed bed before it was exposed to air by the ebbing tide; the boat was grounded on the seaweed bed around the tidal minimum, and then refloated as the incoming tide covered the seaweed. I2 concentrations were strongly anti-correlated with water depth. Initially little I2 was seen above background levels whilst the blades of the seaweed plants were floating on the water surface. However several hundred pptv of I2 was observed within a few minutes of the plants' stipes breaking the surface and first blades coming to rest on rocks out of the water. Iodine concentrations increased further as the tide ebbed, typically peaking around 1500 pptv around the tidal minimum (by which time the seaweed had been exposed for 45 minutes). I2 concentrations decreased rapidly back to background levels as the returning tide submerged the seaweeds. The concentration profiles showed a lot of high frequency structure, with I2 concentrations commonly varying by a factor 2 (or more) within 60 seconds. Additionally the profiles of I2 emitted from the seaweeds immediately below the instrument's inlet typically sat on a smoothly-varying background of approximately 100 pptv, which we attribute to I2 from other more

  6. The absorption spectrum of water vapor in the 2.2 μm transparency window: High sensitivity measurements and spectroscopic database

    NASA Astrophysics Data System (ADS)

    Campargue, A.; Mikhailenko, S. N.; Vasilchenko, S.; Reynaud, C.; Béguier, S.; Čermák, P.; Mondelain, D.; Kassi, S.; Romanini, D.

    2017-03-01

    The weak absorption spectrum of water vapor in the important 2.2 μm transparency window is investigated with very high sensitivity. Overall, about 400 absorption lines were measured by Cavity Ring Down Spectroscopy (CRDS) and Optical-Feedback-Cavity Enhanced Laser Spectroscopy (OF-CEAS) in five spectral intervals: 4248.2-4257.3, 4298.4-4302.6, 4336.8.5-4367.5, 4422.4-4441.2 and 4514.6-4533.7 cm-1. The achieved sensitivity of the recordings (noise equivalent absorption, αmin, on the order of 2×10-10 cm-1) allowed detecting transitions with intensity values down to 1×10-28 cm/molecule, more than one order of magnitude better than previous studies by Fourier Transform spectroscopy. The rovibrational assignment was performed on the basis of variational calculations and of previously determined empirical energy values. Most of the newly assigned lines correspond to transitions of the ν1, ν3 and 3ν2 bands of H217O in natural isotopic abundance. Fourteen energy levels of H217O, H218O and HD18O are newly determined. An accurate and complete spectroscopic database is constructed for natural water in the 4190-4550 cm-1 region (2.39-2.20 μm). The list includes about 4500 transitions with intensity greater than 1×10-29 cm/molecule, for the six most abundant isotopologues in natural isotopic abundance. Line positions were obtained by difference of empirical energy values determined from literature data and complemented with the present CRDS results. The list is made mostly complete by including weak transitions not yet detected, with positions calculated from empirical levels and variational intensities. The variational intensities computed by a collaboration between the University College London and the Institute of Applied Physics in Nizhny Novgorod are found to improve significantly previous results by Schwenke and Partridge. Examples of comparison of the constructed line list to CRDS spectra and to simulations based on the HITRAN2012 list illustrate the advantages

  7. A novel approach for using polyphase filter bank in directly digital RF conversion from RF to baseband

    NASA Astrophysics Data System (ADS)

    Zhang, Deying; Jiang, Qin; Ahmed, Mohiuddin

    2012-05-01

    Software defined radio (SDR) hardware platform is in high demand for ultra-wideband digital EW receiver to carry out different mission requirements. Due to the limitations of current Analog-to-Digital conversion (ADC) techniques, the ideal receiver structure of SDR, with digital RF frequency conversion, cannot be achieved. In this article, a new channelization technique called ADC polyphase fast Fourier transformation (ADC PFFT) filter bank channelization is demonstrated. The key concept is to separate the speed at which the two functional units of an ADC - the sample and hold and the quantizer - operate. The sample and hold unit operates at the sampling frequency fs and the quantizer (the speed limiting factor in ADCs) can operate at a much slower rate, fs/M, where M is the decimation factor for digital filter bank. By integrated this ADC PFFT technique in ultra-wideband digital channelized EW receivers, directly digital RF down conversion can be achieved. With the ADC PFFT channelization for RF down conversion and polyphase FFT channelization for IF down conversion, 2-18 GHz frequency coverage can be accomplished in such ultra-wideband digital channelized EW receivers without the requirement of EW receivers being time-shared among outputs from many subbands due to bandwidth limitation in digital IF channelized EW receivers. Because the frequency down conversion from RF to BB are all processed digitally, issues such as image rejection and I/Q imbalance due to analog mixing will be eliminated in the ultrawideband digital channelized EW receivers.

  8. Ultrasensitive high resolution laser spectroscopy and its application to optical frequency standards

    NASA Astrophysics Data System (ADS)

    Ye, Jun

    1997-09-01

    Advanced laser stabilization techniques now enable one to lock laser frequencies onto line centers of natural atomic/molecular resonances with unprecedented precision and accuracy. In this dissertation we discuss our effort in utilizing these techniques to establish visible optical frequency standards. By summarizing our earlier results on frequency measurements of the 87Rb D2 line at 780 nm 127I2 hyperfine transitions at 532 nm, we show the advantage of using a higher quality reference line, usually characterized by its narrower linewidth, higher attainable signal-to-noise ratio and lower sensitivity toward external perturbations. We then present a novel approach of cavity-enhanced frequency modulation spectroscopy for ultra-sensitive detections. The powerful utility of this new technique in the field of frequency standards is demonstrated by probing saturated molecular overtone transitions in the visible and near infrared. Weakly-absorbing gases such as C2H2 and C2HD are placed inside an external high-finesse resonator to enhance their detection sensitivities. A frequency modulation technique is employed to achieve a shot noise limited signal-to- noise ratio. The rf modulation frequency is chosen to match the cavity's free spectral range in order to avoid the cavity-induced conversion of laser frequency noise into amplitude noise. The molecular saturated dispersion signal is directly recovered after demodulation of the cavity transmitted light. A record high integrated absorption sensitivity of 5× 10-13/ (1× 10-14/cm) (at 1 second averaging time) has been obtained. Systematic studies on this new technique are presented on topics of detection sensitivity, signal line shape, signal size and slope, and pressure dependent linewidth broadening and linecenter shift. A Nd:YAG laser is stabilized on the P(5) transition in the (ν2+3/ ν3) overtone band of C2HD at 1.064 μm. Its absolute frequency is established. The excellent signal- to-noise ratio produces a frequency

  9. High efficiency in Mode Selective Frequency Conversion for Optical Quantum Information Processing

    NASA Astrophysics Data System (ADS)

    Quesada, Nicolas; Sipe, J. E.

    Mode selective Frequency conversion (FC) is an enabling process in many quantum information protocols. Recently, it has been observed that upconversion efficiencies in single-photon, mode-selective FC are limited to around 80%. In this contribution we show that these limits can be understood as time ordering corrections (TOCs) that modify the joint conversion amplitude of the process. Furthermore we show, using a simple scaling argument, that recently proposed cascaded FC protocols that overcome the aforementioned limitations act as ``attenuators'' of the TOCs. This observation allows us to argue that very similar cascaded architectures can be used to attenuate TOCs in photon generation via spontaneous parametric down-conversion. Finally, by using the Magnus expansion, we argue that the TOCs, which are usually considered detrimental for FC efficiency, can also be used to increase the efficiency of conversion in partially mode selective FC.

  10. Widely tunable single photon source with high purity at telecom wavelength.

    PubMed

    Jin, Rui-Bo; Shimizu, Ryosuke; Wakui, Kentaro; Benichi, Hugo; Sasaki, Masahide

    2013-05-06

    We theoretically and experimentally investigate the spectral tunability and purity of photon pairs generated from spontaneous parametric down conversion in periodically poled KTiOPO(4) crystal with group-velocity matching condition. The numerical simulation predicts that the spectral purity can be kept higher than 0.81 when the wavelength is tuned from 1460 nm to 1675 nm, which covers the S-, C-, L-, and U-band in telecommunication wavelengths. We also experimentally measured the joint spectral intensity at 1565 nm, 1584 nm and 1565 nm, yielding Schmidt numbers of 1.01, 1.02 and 1.04, respectively. Such a photon source is useful for quantum information and communication systems.

  11. Experimental generation of a high-fidelity four-photon linear cluster state

    NASA Astrophysics Data System (ADS)

    Zhang, Chao; Huang, Yun-Feng; Liu, Bi-Heng; Li, Chuan-Feng; Guo, Guang-Can

    2016-06-01

    Cluster state plays a crucial role in one-way quantum computation. Here, we propose and experimentally demonstrate a scheme to prepare an ultrahigh-fidelity four-photon linear cluster state via a spontaneous parametric down-conversion process. The state fidelity is measured to be 0.9517 ±0.0027 . Our scheme can be directly extended to more photons to generate an N -qubit linear cluster state. Furthermore, our scheme is optimal for generating photonic linear cluster states in the sense of achieving the maximal success probability and having the simplest strategy. The key idea is that the photon pairs are prepared in some special nonmaximally entangled states instead of the normal Bell states. To generate a 2 N -qubit linear cluster state from N pairs of entangled photons, only (N -1 ) Hong-Ou-Mandel interferences are needed and a success probability of (1/4) N -1 is achieved.

  12. A low-noise high dynamic-range time-domain EMI measurement system for CISPR Band E

    NASA Astrophysics Data System (ADS)

    Hoffmann, C.; Russer, P.

    2011-08-01

    In this paper, a broadband time-domain EMI measurement system for measurements from 9 kHz to 18 GHz is presented that allows for compliant EMI measurements in CISPR Band E. Combining ultra-fast analog-to-digital-conversion and real-time digital signal processing on a field-programmable-gate-array (FPGA) with ultra-broadband multi-stage down-conversion, scan times can be reduced by several orders of magnitude in comparison to a traditional heterodyne EMI-receiver. The ultra-low system noise floor of 6-8 dB and the real-time spectrogram allow for the characterisation of the time-behaviour of EMI near the noise floor. EMI measurements of electronic consumer devices and electric household appliances are presented.

  13. Applications of high-dimensional photonic entaglement

    NASA Astrophysics Data System (ADS)

    Broadbent, Curtis J.

    This thesis presents the results of four experiments related to applications of higher dimensional photonic entanglement. (1) We use energy-time entangled biphotons from spontaneous parametric down-conversion (SPDC) to implement a large-alphabet quantum key distribution (QKD) system which securely transmits up to 10 bits of the random key per photon. An advantage over binary alphabet QKD is demonstrated for quantum channels with a single-photon transmission-rate ceiling. The security of the QKD system is based on the measurable reduction of entanglement in the presence of eavesdropping. (2) We demonstrate the preservation of energy-time entanglement in a tunable slow-light medium. The fine-structure resonances of a hot Rubidium vapor are used to slow one photon from an energy-time entangled biphoton generated with non-degenerate SPDC. The slow-light medium is placed in one arm of a Franson interferometer. The observed Franson fringes witness the presence of entanglement and quantify a delay of 1.3 biphoton correlation lengths. (3) We utilize holograms to discriminate between two spatially-coherent single-photon images. Heralded single photons are created with degenerate SPDC and sent through one of two transmission masks to make single-photon images with no spatial overlap. The single-photon images are sent through a previously prepared holographic filter. The filter discriminates the single-photon images with an average confidence level of 95%. (4) We employ polarization entangled biphotons generated from non-collinear SPDC to violate a generalized Leggett-Garg inequality with non-local weak measurements. The weak measurement is implemented with Fresnel reflection of a microscope coverslip on one member of the entangled biphoton. Projective measurement with computer-controlled polarizers on the entangled state after the weak measurement yields a joint probability with three degrees of freedom. Contextual values are then used to determine statistical averages of

  14. Project Georgia High School/High Tech

    NASA Technical Reports Server (NTRS)

    2000-01-01

    Georgia High School/High Tech has been developing a suggested curriculum for use in its programs. The purpose of this instructional material is to provide a basic curriculum format for teachers of High School/High Tech students. The curriculum is designed to implement QCC classroom instruction that encourages career development in technological fields through post-secondary education, paid summer internships, and exposure to experiences in high technology.

  15. Quantum Correlations between Single Telecom Photons and a Multimode On-Demand Solid-State Quantum Memory

    NASA Astrophysics Data System (ADS)

    Seri, Alessandro; Lenhard, Andreas; Rieländer, Daniel; Gündoǧan, Mustafa; Ledingham, Patrick M.; Mazzera, Margherita; de Riedmatten, Hugues

    2017-04-01

    Quantum correlations between long-lived quantum memories and telecom photons that can propagate with low loss in optical fibers are an essential resource for the realization of large-scale quantum information networks. Significant progress has been realized in this direction with atomic and solid-state systems. Here, we demonstrate quantum correlations between a telecom photon and a multimode on-demand solid state quantum memory. This is achieved by mapping a correlated single photon onto a spin collective excitation in a Pr3 +:Y2SiO5 crystal for a controllable time. The stored single photons are generated by cavity-enhanced spontaneous parametric down-conversion and heralded by their partner photons at telecom wavelength. These results represent the first demonstration of a multimode on-demand solid state quantum memory for external quantum states of light. They provide an important resource for quantum repeaters and pave the way for the implementation of quantum information networks with distant solid state quantum nodes.

  16. Generation of Nondegenerate Narrow-Band Photon Pairs for a Hybrid Quantum Network

    NASA Astrophysics Data System (ADS)

    Wang, Jian; Lv, Peng-YinJie; Cui, Jin-Ming; Liu, Bi-Heng; Tang, Jian-Shun; Huang, Yun-Feng; Li, Chuan-Feng; Guo, Guang-Can

    2015-12-01

    In a hybrid quantum network, the linking of two types of quantum nodes through photonic channels requires excellent matching of the central frequency and bandwidth between both nodes and their interfacing photons. However, preexisting photon sources cannot fulfill this requirement. Using a novel conjoined double-cavity strategy, we report the generation of nondegenerate narrow-band photon pairs by cavity-enhanced spontaneous parametric down-conversion. The central frequencies and bandwidths of the signal and idler photons are independently set to match with trapped ions and solid-state quantum memories. With this source we achieve the bandwidths and central wavelengths of 4 MHz at 935 nm and 5 MHz at 880 nm for the signal and idler photons, respectively, with a normalized spectral brightness of 4.9 photon pairs /(s MHz mW ) . Because of its ability to be independently locked to two different wavelengths, the conjoined double cavity is universally suitable for a hybrid quantum network consisting of various quantum nodes.

  17. Generation of nondegenerate narrow-band photon pairs for hybrid quantum network

    NASA Astrophysics Data System (ADS)

    Wang, Jian; Lv, Pengyinjie; Cui, Jinming; Liu, Biheng; Tang, Jianshun; Huang, Yunfeng; Li, Chuanfeng; Guo, Guangcan

    In a hybrid quantum network, the linking two types of quantum nodes through photonic channels requires excellent matching of the central frequency and bandwidth between both nodes and their interfacing photons. However, pre-existing photon sources cannot fulfill this requirement. Using a novel conjoined double-cavity strategy, we report the generation of nondegenerate narrow-band photon pairs by cavity-enhanced spontaneous parametric down-conversion. The central frequencies and bandwidths of the signal and idler photons are independently set to match with trapped ions and solid-state quantum memories. With this source we achieve the bandwidths and central frequencies of 4 MHz at 935 nm and 5 MHz at 880 nm for the signal and idler photons, respectively, with a normalized spectral brightness of 4.9/s/MHz/mW. Due to its ability to be independently locked to two different wavelengths, the conjoined double-cavity is universally suitable for a hybrid quantum network consisting of various quantum nodes.

  18. High power, high frequency component test facility

    NASA Technical Reports Server (NTRS)

    Roth, Mary Ellen; Krawczonek, Walter

    1990-01-01

    The NASA Lewis Research Center has available a high frequency, high power laboratory facility for testing various components of aerospace and/or terrestrial power systems. This facility is described here. All of its capabilities and potential applications are detailed.

  19. Engineering the Frequency Spectrum of Bright Squeezed Vacuum via Group Velocity Dispersion in an SU(1,1) Interferometer

    NASA Astrophysics Data System (ADS)

    Lemieux, Samuel; Manceau, Mathieu; Sharapova, Polina R.; Tikhonova, Olga V.; Boyd, Robert W.; Leuchs, Gerd; Chekhova, Maria V.

    2016-10-01

    Bright squeezed vacuum, a promising tool for quantum information, can be generated by high-gain parametric down-conversion. However, its frequency and angular spectra are typically quite broad, which is undesirable for applications requiring single-mode radiation. We tailor the frequency spectrum of high-gain parametric down-conversion using an SU(1,1) interferometer consisting of two nonlinear crystals with a dispersive medium separating them. The dispersive medium allows us to select a narrow band of the frequency spectrum to be exponentially amplified by high-gain parametric amplification. The frequency spectrum is thereby narrowed from (56.5 ±0.1 ) to (1.22 ±0.02 ) THz and, in doing so, the number of frequency modes is reduced from approximately 50 to 1.82 ±0.02 . Moreover, this method provides control and flexibility over the spectrum of the generated light through the timing of the pump.

  20. Engineering the Frequency Spectrum of Bright Squeezed Vacuum via Group Velocity Dispersion in an SU(1,1) Interferometer.

    PubMed

    Lemieux, Samuel; Manceau, Mathieu; Sharapova, Polina R; Tikhonova, Olga V; Boyd, Robert W; Leuchs, Gerd; Chekhova, Maria V

    2016-10-28

    Bright squeezed vacuum, a promising tool for quantum information, can be generated by high-gain parametric down-conversion. However, its frequency and angular spectra are typically quite broad, which is undesirable for applications requiring single-mode radiation. We tailor the frequency spectrum of high-gain parametric down-conversion using an SU(1,1) interferometer consisting of two nonlinear crystals with a dispersive medium separating them. The dispersive medium allows us to select a narrow band of the frequency spectrum to be exponentially amplified by high-gain parametric amplification. The frequency spectrum is thereby narrowed from (56.5±0.1) to (1.22±0.02)  THz and, in doing so, the number of frequency modes is reduced from approximately 50 to 1.82±0.02. Moreover, this method provides control and flexibility over the spectrum of the generated light through the timing of the pump.

  1. Project Georgia High School/High Tech

    NASA Technical Reports Server (NTRS)

    2000-01-01

    The High School/High Tech initiative of the President's Committee on Employment of Disabilities, Georgia's application of the collaborative "Georgia Model" and NASA's commitment of funding have shown that opportunities for High School/High Tech students are unlimited. In Georgia, the partnership approach to meeting the needs of this program has opened doors previously closed. As the program grows and develops, reflecting the needs of our students and the marketplace, more opportunities will be available. Our collaboratives are there to provide these opportunities and meet the challenge of matching our students with appropriate education and career goals. Summing up the activities and outcomes of Project Georgia High School/High Tech is not difficult. Significant outcomes have already occurred in the Savannah area as a result of NASA's grant. The support of NASA has enabled Georgia Committee to "grow" High School/High Tech throughout the region-and, by example, the state. The success of the Columbus pilot project has fostered the proliferation of projects, resulting in more than 30 Georgia High School High Tech programs-with eight in the Savannah area.

  2. High Blood Pressure

    MedlinePlus

    ... version of this page please turn Javascript on. High Blood Pressure What Is High Blood Pressure? High blood pressure is a common disease in ... the heart, kidneys, brain, and eyes. Types of High Blood Pressure There are two main types of high blood ...

  3. High Blood Pressure

    MedlinePlus

    ... normal blood pressure 140/90 or higher is high blood pressure Between 120 and 139 for the top number, ... prehypertension. Prehypertension means you may end up with high blood pressure, unless you take steps to prevent it. High ...

  4. High Blood Pressure (Hypertension)

    MedlinePlus

    ... Print Page Text Size: A A A Listen High Blood Pressure (Hypertension) Nearly 1 in 3 American adults has ... weight. How Will I Know if I Have High Blood Pressure? High blood pressure is a silent problem — you ...

  5. Quantum interference of highly-dispersive surface plasmons (Conference Presentation)

    NASA Astrophysics Data System (ADS)

    Tokpanov, Yury S.; Fakonas, James S.; Atwater, Harry A.

    2016-09-01

    Previous experiments have shown that surface plasmon polaritons (SPPs) preserve their entangled state and do not cause measurable decoherence. However, essentially all of them were done using SPPs whose dispersion was in the linear "photon-like" regime. We report in this presentation on experiments showing how transition to "true-plasmon" non-linear dispersion regime, which occurs near SPP resonance frequency, will affect quantum coherent properties of light. To generate a polarization-entangled state we utilize type-I parametric down-conversion, occurring in a pair of non-linear crystals (BiBO), glued together and rotated by 90 degrees with respect to each other. For state projection measurements, we use a pair of polarizers and single-photon avalanche diode coincidence count detectors. We interpose a plasmonic hole array in the path of down-converted light before the polarizer. Without the hole array, we measure visibility V=99-100% and Bell's number S=2.81±0.03. To study geometrical effects we fabricated plasmonic hole arrays (gold on optically polished glass) with elliptical holes (axes are 190nm and 240nm) using focused ion beam. When we put this sample in our system we measured the reduction of visibility V=86±5% using entangled light. However, measurement using classical light gave exactly the same visibility; hence, this reduction is caused only by the difference in transmission coefficients of different polarizations. As samples with non-linear dispersion we fabricated two-layer (a-Si - Au) and three-layer (a-Si - Au - a-Si) structures on optically polished glass with different pitches and circular holes. The results of measurements with these samples will be discussed along with the theoretical investigations.

  6. High strength high modulus ceramic fiber

    NASA Technical Reports Server (NTRS)

    Fetterolf, R. N.

    1972-01-01

    Low cost method was developed for producing high strength, high modulus, continuous ceramic oxide fibers. Process transforms inexpensive metallic salts into syrup-like liquids that can be fiberized at room temperatures. Resulting salt fibers are then converted to oxides by calcination at relatively low temperatures.

  7. High-Flying High-Poverty Schools

    ERIC Educational Resources Information Center

    American Educator, 2013

    2013-01-01

    In discussing socioeconomic integration before audiences, the author is frequently asked: What about high-poverty schools that do work? Don't they suggest that economic segregation isn't much of a problem after all? High-poverty public schools that beat the odds paint a heartening story that often attracts considerable media attention. In 2000,…

  8. Bringing the High Court to High School.

    ERIC Educational Resources Information Center

    Raskin, Jamin B.

    2002-01-01

    Describes the Marshall-Brennan Fellowship constitutional literacy project wherein 30 pairs of law students at the Washington College of Law teach a constitutional rights and responsibilities course to high school students in Washington, D.C., and Maryland public high schools. Students are also taken to hear oral arguments at the Supreme Court.…

  9. High speed, high current pulsed driver circuit

    DOEpatents

    Carlen, Christopher R.

    2017-03-21

    Various technologies presented herein relate to driving a LED such that the LED emits short duration pulses of light. This is accomplished by driving the LED with short duration, high amplitude current pulses. When the LED is driven by short duration, high amplitude current pulses, the LED emits light at a greater amplitude compared to when the LED is driven by continuous wave current.

  10. High Performance Networks for High Impact Science

    SciTech Connect

    Scott, Mary A.; Bair, Raymond A.

    2003-02-13

    This workshop was the first major activity in developing a strategic plan for high-performance networking in the Office of Science. Held August 13 through 15, 2002, it brought together a selection of end users, especially representing the emerging, high-visibility initiatives, and network visionaries to identify opportunities and begin defining the path forward.

  11. Franson Interference Generated by a Two-Level System

    NASA Astrophysics Data System (ADS)

    Peiris, M.; Konthasinghe, K.; Muller, A.

    2017-01-01

    We report a Franson interferometry experiment based on correlated photon pairs generated via frequency-filtered scattered light from a near-resonantly driven two-level semiconductor quantum dot. In contrast to spontaneous parametric down-conversion and four-wave mixing, this approach can produce single pairs of correlated photons. We have measured a Franson visibility as high as 66%, which goes beyond the classical limit of 50% and approaches the limit of violation of Bell's inequalities (70.7%).

  12. Development of high strength, high temperature ceramics

    NASA Technical Reports Server (NTRS)

    Hall, W. B.

    1982-01-01

    Improvement in the high-pressure turbopumps, both fuel and oxidizer, in the Space Shuttle main engine were considered. The operation of these pumps is limited by temperature restrictions of the metallic components used in these pumps. Ceramic materials that retain strength at high temperatures and appear to be promising candidates for use as turbine blades and impellers are discussed. These high strength materials are sensitive to many related processing parameters such as impurities, sintering aids, reaction aids, particle size, processing temperature, and post thermal treatment. The specific objectives of the study were to: (1) identify and define the processing parameters that affect the properties of Si3N4 ceramic materials, (2) design and assembly equipment required for processing high strength ceramics, (3) design and assemble test apparatus for evaluating the high temperature properties of Si3N4, and (4) conduct a research program of manufacturing and evaluating Si3N4 materials as applicable to rocket engine applications.

  13. High pressure, high current, low inductance, high reliability sealed terminals

    DOEpatents

    Hsu, John S [Oak Ridge, TN; McKeever, John W [Oak Ridge, TN

    2010-03-23

    The invention is a terminal assembly having a casing with at least one delivery tapered-cone conductor and at least one return tapered-cone conductor routed there-through. The delivery and return tapered-cone conductors are electrically isolated from each other and positioned in the annuluses of ordered concentric cones at an off-normal angle. The tapered cone conductor service can be AC phase conductors and DC link conductors. The center core has at least one service conduit of gate signal leads, diagnostic signal wires, and refrigerant tubing routed there-through. A seal material is in direct contact with the casing inner surface, the tapered-cone conductors, and the service conduits thereby hermetically filling the interstitial space in the casing interior core and center core. The assembly provides simultaneous high-current, high-pressure, low-inductance, and high-reliability service.

  14. High-field/high-pressure ESR

    NASA Astrophysics Data System (ADS)

    Sakurai, T.; Okubo, S.; Ohta, H.

    2017-07-01

    We present a historical review of high-pressure ESR systems with emphasis on our recent development of a high-pressure, high-field, multi-frequency ESR system. Until 2000, the X-band system was almost established using a resonator filled with dielectric materials or a combination of the anvil cell and dielectric resonators. Recent developments have shifted from that in the low-frequency region, such as X-band, to that in multi-frequency region. High-pressure, high-field, multi-frequency ESR systems are classified into two types. First are the systems that use a vector network analyzer or a quasi-optical bridge, which have high sensitivity but a limited frequency region; the second are like our system, which has a very broad frequency region covering the THz region, but lower sensitivity. We will demonstrate the usefulness of our high-pressure ESR system, in addition to its experimental limitations. We also discuss the recent progress of our system and future plans.

  15. Propagation of transverse intensity correlations of a two-photon state

    NASA Astrophysics Data System (ADS)

    Tasca, D. S.; Walborn, S. P.; Souto Ribeiro, P. H.; Toscano, F.; Pellat-Finet, P.

    2009-03-01

    The propagation of transverse spatial correlations of photon pairs through arbitrary first-order linear optical systems is studied experimentally and theoretically using the fractional Fourier transform. Highly correlated photon pairs in an Einstein-Podolsky-Rosen-like state are produced by spontaneous parametric down-conversion and subject to optical fractional Fourier transform systems. It is shown that the joint detection probability can display either correlation, anticorrelation, or no correlation, depending on the sum of the orders α and β of the transforms of the down-converted photons. We present analytical results for the propagation of the perfectly correlated EPR state and numerical results for the propagation of the two-photon state produced from parametric down-conversion. We find good agreement between the theory and experiment.

  16. Flexible RF filter using a nonuniform SCISSOR.

    PubMed

    Zhuang, Leimeng

    2016-03-15

    This work presents a flexible radiofrequency (RF) filter using an integrated microwave photonic circuit that comprises a nonuniform side-coupled integrated spaced sequence of resonators (N-SCISSOR). The filter passband can be reconfigured by varying the N-SCISSOR parameters. When employing a dual-parallel Mach-Zechnder modulator, the filter is also able to perform frequency down-conversion. In the experiment, various filter response shapes are shown, ranging from a flat-top band-pass filter to a total opposite high-rejection (>40  dB) notch filter, with a frequency coverage of greater than two octaves. The frequency down-conversion function is also demonstrated.

  17. Wide-band quantum interface for visible-to-telecommunication wavelength conversion.

    PubMed

    Ikuta, Rikizo; Kusaka, Yoshiaki; Kitano, Tsuyoshi; Kato, Hiroshi; Yamamoto, Takashi; Koashi, Masato; Imoto, Nobuyuki

    2011-11-15

    Although near-infrared photons in telecommunication bands are required for long-distance quantum communication, various quantum information tasks have been performed by using visible photons for the past two decades. Recently, such visible photons from diverse media including atomic quantum memories have also been studied. Optical frequency down-conversion from visible to telecommunication bands while keeping the quantum states is thus required for bridging such wavelength gaps. Here we report demonstration of a quantum interface of frequency down-conversion from visible to telecommunication bands by using a nonlinear crystal, which has a potential to work over wide bandwidths, leading to a high-speed interface of frequency conversion. We achieved the conversion of a picosecond visible photon at 780  nm to a 1,522-nm photon, and observed that the conversion process retained entanglement between the down-converted photon and another photon.

  18. Giant narrowband twin-beam generation along the pump-energy propagation direction

    NASA Astrophysics Data System (ADS)

    Pérez, Angela M.; Spasibko, Kirill Yu; Sharapova, Polina R.; Tikhonova, Olga V.; Leuchs, Gerd; Chekhova, Maria V.

    2015-07-01

    Walk-off effects, originating from the difference between the group and phase velocities, limit the efficiency of nonlinear optical interactions. While transverse walk-off can be eliminated by proper medium engineering, longitudinal walk-off is harder to avoid. In particular, ultrafast twin-beam generation via pulsed parametric down-conversion and four-wave mixing is only possible in short crystals or fibres. Here we show that in high-gain parametric down-conversion, one can overcome the destructive role of both effects and even turn them into useful tools for shaping the emission. In our experiment, one of the twin beams is emitted along the pump Poynting vector or its group velocity matches that of the pump. The result is markedly enhanced generation of both twin beams, with the simultaneous narrowing of angular and frequency spectrum. The effect will enable efficient generation of ultrafast twin photons and beams in cavities, waveguides and whispering-gallery mode resonators.

  19. Enhanced 1G 4 emission in NaLaF 4: Pr 3+, Yb 3+ and charge transfer in NaLaF 4: Ce 3+, Yb 3+ studied by fourier transform luminescence spectroscopy

    NASA Astrophysics Data System (ADS)

    van der Kolk, E.; Ten Kate, O. M.; Wiegman, J. W.; Biner, D.; Krämer, K. W.

    2011-05-01

    A high resolution luminescence study of NaLaF 4: 1%Pr 3+, 5%Yb 3+ and NaLaF 4: 1%Ce 3+, 5%Yb 3+ in the UV to NIR spectral range using a InGaAs detector and a fourier transform interferometer is reported. Although the Pr 3+( 3P 0 → 1G 4), Yb 3+( 2F 7/2 → 2F 5/2) energy transfer step takes place, significant Pr 3+1G 4 emission around 993, 1330 and 1850 nm is observed. No experimental proof for the second energy transfer step in the down-conversion process between Pr 3+ and Yb 3+ can be given. In the case of NaLaF 4: Ce 3+, Yb 3+ it is concluded that the observed Yb 3+ emission upon Ce 3+ 5d excitation is the result of a charge transfer process instead of down-conversion.

  20. High speed high dynamic range high accuracy measurement system

    SciTech Connect

    Deibele, Craig E.; Curry, Douglas E.; Dickson, Richard W.; Xie, Zaipeng

    2016-11-29

    A measuring system includes an input that emulates a bandpass filter with no signal reflections. A directional coupler connected to the input passes the filtered input to electrically isolated measuring circuits. Each of the measuring circuits includes an amplifier that amplifies the signal through logarithmic functions. The output of the measuring system is an accurate high dynamic range measurement.

  1. Bumball: Highly Engaging, Highly Inclusive, and Highly Entertaining

    ERIC Educational Resources Information Center

    Hall, Amber; Barney, David; Wilkinson, Carol

    2014-01-01

    Physical educators are always looking for new and exciting games and activities in which students can participate. This article describes Bumball, a high-intensity game that provides the opportunity for students to use many common game skills, such as hand-eye coordination, passing to a target, running, playing defense, and getting to an open…

  2. Bumball: Highly Engaging, Highly Inclusive, and Highly Entertaining

    ERIC Educational Resources Information Center

    Hall, Amber; Barney, David; Wilkinson, Carol

    2014-01-01

    Physical educators are always looking for new and exciting games and activities in which students can participate. This article describes Bumball, a high-intensity game that provides the opportunity for students to use many common game skills, such as hand-eye coordination, passing to a target, running, playing defense, and getting to an open…

  3. Hypertension (High Blood Pressure)

    MedlinePlus

    ... Loss Surgery? A Week of Healthy Breakfasts Shyness Hypertension (High Blood Pressure) KidsHealth > For Teens > Hypertension (High Blood Pressure) A ... rest temperature diet emotions posture medicines Why Is High Blood Pressure Bad? High blood pressure means a person's heart ...

  4. High Schools with Character.

    ERIC Educational Resources Information Center

    Hill, Paul T.; And Others

    This study compares zoned high schools, special public magnet schools, and Catholic high schools to identify features that motivate low-income students. Ten days of observations, interviews, and reviews of student records were conducted at eight New York City schools. Of the eight, three were Catholic high schools, two were zoned high schools, and…

  5. High-current, high-frequency capacitors

    NASA Astrophysics Data System (ADS)

    Renz, D. D.

    1983-06-01

    The NASA Lewis high-current, high-frequency capacitor development program was conducted under a contract with Maxwell Laboratories, Inc., San Diego, California. The program was started to develop power components for space power systems. One of the components lacking was a high-power, high-frequency capacitor. Some of the technology developed in this program may be directly usable in an all-electric airplane. The materials used in the capacitor included the following: the film is polypropylene, the impregnant is monoisopropyl biphenyl, the conductive epoxy is Emerson and Cuming Stycast 2850 KT, the foil is aluminum, the case is stainless steel (304), and the electrode is a modified copper-ceramic.

  6. High-current, high-frequency capacitors

    NASA Technical Reports Server (NTRS)

    Renz, D. D.

    1983-01-01

    The NASA Lewis high-current, high-frequency capacitor development program was conducted under a contract with Maxwell Laboratories, Inc., San Diego, California. The program was started to develop power components for space power systems. One of the components lacking was a high-power, high-frequency capacitor. Some of the technology developed in this program may be directly usable in an all-electric airplane. The materials used in the capacitor included the following: the film is polypropylene, the impregnant is monoisopropyl biphenyl, the conductive epoxy is Emerson and Cuming Stycast 2850 KT, the foil is aluminum, the case is stainless steel (304), and the electrode is a modified copper-ceramic.

  7. High strength and high toughness steel

    DOEpatents

    Parker, Earl R.; Zackay, Victor F.

    1979-01-01

    A structural steel which possess both high strength and high toughness and has particular application of cryogenic uses. The steel is produced by the utilization of thermally induced phase transformation following heating in a three-phase field in iron-rich alloys of the Fe-Ni-Ti system, with a preferred composition of 12% nickel, 0.5% titanium, the remainder being iron.

  8. High strength, high ductility low carbon steel

    DOEpatents

    Koo, Jayoung; Thomas, Gareth

    1978-01-01

    A high strength, high ductility low carbon steel consisting essentially of iron, 0.05-0.15 wt% carbon, and 1-3 wt% silicon. Minor amounts of other constituents may be present. The steel is characterized by a duplex ferrite-martensite microstructure in a fibrous morphology. The microstructure is developed by heat treatment consisting of initial austenitizing treatment followed by annealing in the (.alpha. + .gamma.) range with intermediate quenching.

  9. Space Based Infrared System High (SBIRS High)

    DTIC Science & Technology

    2015-12-01

    mission areas: Missile Warning, Missile Defense, Technical Intelligence and Battlespace Awareness. The constellation architecture for SBIRS High...2015. A formal test on December 10-18, 2015 proved the Block 10.3 system has the ability to control the full constellation (GEO/HEO and DSP) of...on the full SBIRS constellation and Ground Segment. SBIRS High December 2015 SAR March 23, 2016 11:24:26 UNCLASSIFIED 14 Block Buy (GEO 5-6) No

  10. High-power, high-efficiency FELs

    SciTech Connect

    Sessler, A.M.

    1989-04-01

    High power, high efficiency FELs require tapering, as the particles loose energy, so as to maintain resonance between the electromagnetic wave and the particles. They also require focusing of the particles (usually done with curved pole faces) and focusing of the electromagnetic wave (i.e. optical guiding). In addition, one must avoid transverse beam instabilities (primarily resistive wall) and longitudinal instabilities (i.e sidebands). 18 refs., 7 figs., 3 tabs.

  11. High temperature, high power piezoelectric composite transducers.

    PubMed

    Lee, Hyeong Jae; Zhang, Shujun; Bar-Cohen, Yoseph; Sherrit, Stewart

    2014-08-08

    Piezoelectric composites are a class of functional materials consisting of piezoelectric active materials and non-piezoelectric passive polymers, mechanically attached together to form different connectivities. These composites have several advantages compared to conventional piezoelectric ceramics and polymers, including improved electromechanical properties, mechanical flexibility and the ability to tailor properties by using several different connectivity patterns. These advantages have led to the improvement of overall transducer performance, such as transducer sensitivity and bandwidth, resulting in rapid implementation of piezoelectric composites in medical imaging ultrasounds and other acoustic transducers. Recently, new piezoelectric composite transducers have been developed with optimized composite components that have improved thermal stability and mechanical quality factors, making them promising candidates for high temperature, high power transducer applications, such as therapeutic ultrasound, high power ultrasonic wirebonding, high temperature non-destructive testing, and downhole energy harvesting. This paper will present recent developments of piezoelectric composite technology for high temperature and high power applications. The concerns and limitations of using piezoelectric composites will also be discussed, and the expected future research directions will be outlined.

  12. High Temperature, High Power Piezoelectric Composite Transducers

    PubMed Central

    Lee, Hyeong Jae; Zhang, Shujun; Bar-Cohen, Yoseph; Sherrit, StewarT.

    2014-01-01

    Piezoelectric composites are a class of functional materials consisting of piezoelectric active materials and non-piezoelectric passive polymers, mechanically attached together to form different connectivities. These composites have several advantages compared to conventional piezoelectric ceramics and polymers, including improved electromechanical properties, mechanical flexibility and the ability to tailor properties by using several different connectivity patterns. These advantages have led to the improvement of overall transducer performance, such as transducer sensitivity and bandwidth, resulting in rapid implementation of piezoelectric composites in medical imaging ultrasounds and other acoustic transducers. Recently, new piezoelectric composite transducers have been developed with optimized composite components that have improved thermal stability and mechanical quality factors, making them promising candidates for high temperature, high power transducer applications, such as therapeutic ultrasound, high power ultrasonic wirebonding, high temperature non-destructive testing, and downhole energy harvesting. This paper will present recent developments of piezoelectric composite technology for high temperature and high power applications. The concerns and limitations of using piezoelectric composites will also be discussed, and the expected future research directions will be outlined. PMID:25111242

  13. High assurance SPIRAL

    NASA Astrophysics Data System (ADS)

    Franchetti, Franz; Sandryhaila, Aliaksei; Johnson, Jeremy R.

    2014-06-01

    In this paper we introduce High Assurance SPIRAL to solve the last mile problem for the synthesis of high assurance implementations of controllers for vehicular systems that are executed in today's and future embedded and high performance embedded system processors. High Assurance SPIRAL is a scalable methodology to translate a high level specification of a high assurance controller into a highly resource-efficient, platform-adapted, verified control software implementation for a given platform in a language like C or C++. High Assurance SPIRAL proves that the implementation is equivalent to the specification written in the control engineer's domain language. Our approach scales to problems involving floating-point calculations and provides highly optimized synthesized code. It is possible to estimate the available headroom to enable assurance/performance trade-offs under real-time constraints, and enables the synthesis of multiple implementation variants to make attacks harder. At the core of High Assurance SPIRAL is the Hybrid Control Operator Language (HCOL) that leverages advanced mathematical constructs expressing the controller specification to provide high quality translation capabilities. Combined with a verified/certified compiler, High Assurance SPIRAL provides a comprehensive complete solution to the efficient synthesis of verifiable high assurance controllers. We demonstrate High Assurance SPIRALs capability by co-synthesizing proofs and implementations for attack detection and sensor spoofing algorithms and deploy the code as ROS nodes on the Landshark unmanned ground vehicle and on a Synthetic Car in a real-time simulator.

  14. Causes of High Cholesterol

    MedlinePlus

    ... Venous Thromboembolism Aortic Aneurysm More Causes of High Cholesterol Updated:Jul 5,2017 If you have high ... and procedures related to heart disease and stroke. Cholesterol • Home • About Cholesterol • HDL, LDL, and Triglycerides • Causes ...

  15. High blood pressure - infants

    MedlinePlus

    ... this page: //medlineplus.gov/ency/article/007329.htm High blood pressure - infants To use the sharing features on this page, please enable JavaScript. High blood pressure (hypertension) is an increase in the force of ...

  16. High Blood Pressure Prevention

    MedlinePlus

    ... version of this page please turn Javascript on. High Blood Pressure Prevention Steps You Can Take You can take steps to prevent high blood pressure by adopting these healthy lifestyle habits. Follow a ...

  17. High blood pressure

    MedlinePlus

    ... this page: //medlineplus.gov/ency/article/000468.htm High blood pressure To use the sharing features on this page, ... body. Hypertension is the term used to describe high blood pressure. Blood pressure readings are given as two numbers. ...

  18. Hypertension (High Blood Pressure)

    MedlinePlus

    ... Visitor Information RePORT NIH Fact Sheets Home > Hypertension (High Blood Pressure) Small Text Medium Text Large Text Hypertension (High Blood Pressure) YESTERDAY Hypertension is a silent killer because it ...

  19. High power microwave generator

    DOEpatents

    Ekdahl, Carl A.

    1986-01-01

    A microwave generator efficiently converts the energy of an intense relativistic electron beam (REB) into a high-power microwave emission using the Smith-Purcell effect which is related to Cerenkov radiation. Feedback for efficient beam bunching and high gain is obtained by placing a cylindrical Smith-Purcell transmission grating on the axis of a toroidal resonator. High efficiency results from the use of a thin cold annular highly-magnetized REB that is closely coupled to the resonant structure.

  20. High power microwave generator

    DOEpatents

    Ekdahl, C.A.

    1983-12-29

    A microwave generator efficiently converts the energy of an intense relativistic electron beam (REB) into a high-power microwave emission using the Smith-Purcell effect which is related to Cerenkov radiation. Feedback for efficient beam bunching and high gain is obtained by placing a cylindrical Smith-Purcell transmission grating on the axis of a toroidal resonator. High efficiency results from the use of a thin cold annular highly-magnetized REB that is closely coupled to the resonant structure.