Pilot-scale road subbase made with granular material formulated with MSWI bottom ash and stabilized APC fly ash: environmental impact assessment.

PubMed

del Valle-Zermeño, R; Formosa, J; Prieto, M; Nadal, R; Niubó, M; Chimenos, J M

2014-02-15

A granular material (GM) to be used as road sub-base was formulated using 80% of weathered bottom ash (WBA) and 20% of mortar. The mortar was prepared separately and consisted in 50% APC and 50% of Portland cement. A pilot-scale study was carried on by constructing three roads in order to environmentally evaluate the performance of GM in a real scenario. By comparing the field results with those of the column experiments, the overestimations observed at laboratory scale can be explained by the potential mechanisms in which water enters into the road body and the pH of the media. An exception was observed in the case of Cu, whose concentration release at the test road was higher. The long-time of exposure at atmospheric conditions might have favoured oxidation of organic matter and therefore the leaching of this element. The results obtained showed that immobilization of all heavy metals and metalloids from APC is achieved by the pozzolanic effect of the cement mortar. This is, to the knowledge of the authors, the only pilot scale study that is considering reutilization of APC as a safe way to disposal. Copyright © 2013 Elsevier B.V. All rights reserved.

Aggregate material formulated with MSWI bottom ash and APC fly ash for use as secondary building material.

PubMed

del Valle-Zermeño, R; Formosa, J; Chimenos, J M; Martínez, M; Fernández, A I

2013-03-01

The main goal of this paper is to obtain a granular material formulated with Municipal Solid Waste Incineration (MSWI) bottom ash (BA) and air pollution control (APC) fly ash to be used as secondary building material. Previously, an optimum concrete mixture using both MSWI residues as aggregates was formulated. A compromise between the environmental behavior whilst maximizing the reuse of APC fly ash was considered and assessed. Unconfined compressive strength and abrasion resistance values were measured in order to evaluate the mechanical properties. From these results, the granular mixture was not suited for certain applications owing to the high BA/APC fly ash content and low cement percentages used to reduce the costs of the final product. Nevertheless, the leaching test performed showed that the concentrations of all heavy metals were below the limits established by the current Catalan legislation for their reutilization. Therefore, the material studied might be mainly used in embankments, where high mechanical properties are not needed and environmental safety is assured. Copyright © 2012 Elsevier Ltd. All rights reserved.

Characterization of the mechanical behavior of sea ice as a frictional material

NASA Astrophysics Data System (ADS)

Lade, Poul V.

2002-12-01

The mechanical properties of sea ice are determined by the formation process, and the consequent material behavior at the element scale exhibits viscoelastic behavior at the early loading stages, followed by brittle fracture or ductile, irrecoverable deformation that may be captured by hardening/softening plasticity models with nonassociated flow. Failure of sea ice under different loading conditions follows a pattern that demonstrates its highly cross-anisotropic nature as well as its behavior as a frictional material. The interactions between the floes in the pack ice resemble those observed in granular materials. These materials are frictional in nature, they exhibit both contractive and dilative volume changes, the plastic flow is nonassociated, and their stiffnesses and strengths increase with confining pressure, but they do not have any strength when unconfined. The overall behavior of the pack ice may be close to isotropic. Constitutive modeling of this behavior may be achieved by models used in geotechnical engineering. Formation of leads and subsequent freezing of the water results in cementation between the ice floes, and the pack ice becomes stronger. The behavior of the pack ice may now be compared with that observed in cemented soils or concrete. For these materials, increasing amounts of cementation result in increasing rates of dilation when sheared, and this accounts for the largest contribution to the increase in shear strength.

Relating monolithic and granular leaching from contaminated soil treated with different cementitious binders.

PubMed

Kogbara, Reginald B; Al-Tabbaa, Abir; Stegemann, Julia A

2013-01-01

This work employed a clayey, silty, sandy gravel contaminated with a mixture of metals (Cd, Cu, Pb, Ni and Zn) and diesel. The contaminated soil was treated with 5 and 10% dosages of different cementitious binders. The binders include Portland cement, cement-fly ash, cement-slag and lime-slag mixtures. Monolithic leaching from the treated soils was evaluated over a 64-day period alongside granular leachability of 49- and 84-day old samples. Surface wash-off was the predominant leaching mechanism for monolithic samples. In this condition, with data from different binders and curing ages combined, granular leachability as a function of monolithic leaching generally followed degrees 4 and 6 polynomial functions. The only exception was for Cu, which followed the multistage dose-response model. The relationship between both leaching tests varied with the type of metal, curing age/residence time of monolithic samples in the leachant, and binder formulation. The results provide useful design information on the relationship between leachability of metals from monolithic forms of S/S treated soils and the ultimate leachability in the eventual breakdown of the stabilized/solidified soil.

Properties of lightweight cement-based composites containing waste polypropylene

NASA Astrophysics Data System (ADS)

Záleská, Martina; Pavlíková, Milena; Pavlík, Zbyšek

2016-07-01

Improvement of buildings thermal stability represents an increasingly important trend of the construction industry. This work aims to study the possible use of two types of waste polypropylene (PP) for the development of lightweight cement-based composites with enhanced thermal insulation function. Crushed PP waste originating from the PP tubes production is used for the partial replacement of silica sand by 10, 20, 30, 40 and 50 mass%, whereas a reference mixture without plastic waste is studied as well. First, basic physical and thermal properties of granular PP random copolymer (PPR) and glass fiber reinforced PP (PPGF) aggregate are studied. For the developed composite mixtures, basic physical, mechanical, heat transport and storage properties are accessed. The obtained results show that the composites with incorporated PP aggregate exhibit an improved thermal insulation properties and acceptable mechanical resistivity. This new composite materials with enhanced thermal insulation function are found to be promising materials for buildings subsoil or floor structures.

Effect of citric acid on setting reaction and tissue response to β-TCP granular cement.

PubMed

Fukuda, Naoyuki; Tsuru, Kanji; Mori, Yoshihide; Ishikawa, Kunio

2017-02-24

We recently reported that when an acidic calcium phosphate solution is mixed with β-tricalcium phosphate (β-TCP) granules, the resulting dicalcium phosphate dihydrate (DCPD) crystals form bridges between the β-TCP granules, creating a set interconnected porous structure in approximately 1 min. Although this self-setting β-TCP granular cement (β-TCPGC) is useful for clinical applications, the short setting time is a key drawback for handling. In this study, the setting time of β-TCPGC was adjusted with the addition of citric acid, which is a known inhibiter of DCPD crystal growth. As the concentration of citric acid in the acidic calcium phosphate solution increased, the amount of DCPD formation in the set β-TCPGC decreased, and the crystal morphology of DCPD became elongated. β-TCPGC prepared with various citric acid concentrations were used as grafting material in rat calvarial bone defects to evaluate bone regeneration in vivo. Four weeks after implantation, no inflammatory reaction and approximately 20% new bone formation were observed, regardless of the presence or absence of citric acid in the liquid phase of β-TCPGC. We concluded, therefore, that citric acid might be a useful retarder of β-TCPGC setting times.

Tensile strength and fracture of cemented granular aggregates.

PubMed

Affes, R; Delenne, J-Y; Monerie, Y; Radjaï, F; Topin, V

2012-11-01

Cemented granular aggregates include a broad class of geomaterials such as sedimentary rocks and some biomaterials such as the wheat endosperm. We present a 3D lattice element method for the simulation of such materials, modeled as a jammed assembly of particles bound together by a matrix partially filling the interstitial space. From extensive simulation data, we analyze the mechanical properties of aggregates subjected to tensile loading as a function of matrix volume fraction and particle-matrix adhesion. We observe a linear elastic behavior followed by a brutal failure along a fracture surface. The effective stiffness before failure increases almost linearly with the matrix volume fraction. We show that the tensile strength of the aggregates increases with both the increasing tensile strength at the particle-matrix interface and decreasing stress concentration as a function of matrix volume fraction. The proportion of broken bonds in the particle phase reveals a range of values of the particle-matrix adhesion and matrix volume fraction for which the cracks bypass the particles and hence no particle damage occurs. This limit is shown to depend on the relative toughness of the particle-matrix interface with respect to the particles.

Reduction of Leaching Impacts by Applying Biomass Bottom Ash and Recycled Mixed Aggregates in Structural Layers of Roads

PubMed Central

Cabrera, Manuel; Galvin, Adela P.; Agrela, Francisco; Beltran, Manuel G.; Ayuso, Jesus

2016-01-01

This research is focused on analyzing the environmental pollution potential of biomass bottom ashes as individual materials, as mixtures manufactured with biomass bottom ashes and granular construction aggregates, and these mixtures treated with cement. For the environmental assessment of all of the samples and materials mentioned, the following leaching procedures have been performed: the compliance batch test of UNE-EN 12457-3:2003 for aggregates and bottom ashes; the column test according to NEN 7343:1994 for the mixtures prepared in the laboratory; and the tank test by EA NEN 7375:2004 for analyzing the behavior of mixtures after their solidification/stabilization with 5% cement. After the discussion of the data, the reduction of the pollution load of the most hazardous biomass bottom ashes after their combination with different aggregates can be confirmed, which implies their possible application in civil infrastructures, such as filler embankments and road construction layers, without negatively impacting the environment. In addition, the positive effect of the stabilization/solidification of the cement-treated mixtures with a reduction of the heavy metals that were released at the highest levels, namely As, Hg Cr, Ni, Cu, Se and Mo, was proven. PMID:28773352

Leaching behaviour of municipal solid waste incineration bottom ash: From granular material to monolithic concrete.

PubMed

Sorlini, Sabrina; Collivignarelli, Maria Cristina; Abbà, Alessandro

2017-09-01

The aim of this work was to assess the leaching behaviour of the bottom ash derived from municipal solid waste incineration (MSWI) used in concrete production. In particular, the release of pollutants was evaluated by the application of different leaching tests, both on granular materials and monolithic samples (concrete mixtures cast with bottom ash). The results confirmed that, according to Italian regulations, unwashed bottom ashes present critical issues for the use as alternative aggregates in the construction sector due to the excessive release of pollutants; instead, the leachate from washed bottom ashes was similar to natural aggregates. The concentration of pollutants in the leachate from concrete mixtures was lower than regulation limits for reuse. The crushing process significantly influenced the release of pollutants: this behaviour was due both to the increase in surface area and the release of contaminants from cement. Moreover, the increase in contact time (up to 64 days) involved more heavy metals to be released.

Detection and Analysis of the Magnetic Field Component of Electromagnetic Radiation Emission from Macroscopic Fracturing of Cement-Bound Granular Material

NASA Astrophysics Data System (ADS)

Maquiling, J. T.; Ceralde, P. I. B.

2016-12-01

Countries most prone to earthquake damage have been in pursuit of a possible earthquake precursor. This study aims to detect and measure the magnetic field component of the Electromagnetic Radiation (EMR) emitted by quasi-brittle materials that undergo macroscopic fracturing. Cement-Bound Granular Materials (CBGM) were prepared by mixing cement, sand and gravel in a beam mold. Additional aggregates in the form of saw dust were added to produce variable CBGM samples. A concrete beam holder was designed and fabricated such that induced cracks from impact loading would form at the center of the beam. Six Vernier software magnetic field sensors were used to detect the magnetic field (MF) component of the EMR emission. Initial calibration was done to minimize noise in the laboratory. The magnetic field sensors were set at a low amplification range (±6.4x10-3 T) setting with 0.0002 mT precision at 20-50 Hz. Sensor locations and orientations were specified and fixed throughout the experiment. The impact loading process was repeated until concrete failure. The time of drop was determined through the occurrence of peak sound levels (dB) induced by the collision noise using a sound level meter at fast time weighting. Magnetic field fluctuations manifesting near the occurrence of sound level impulses were recorded. Peak magnetic field values within ±200ms from the recorded time of impact were considered to be originating from the concrete fracture. Concrete samples consisting of cement, sand and gravel produced magnetic field emissions measuring 0.58-1.07 μT while the same concrete mixture added with dispersed fine sawdust released 0.55-1.28 μT. A more dispersed set of values of magnetic field emissions were observed for concrete with sawdust. Comparison between the average number of drops done before failure occurs between the two concrete mixtures also indicated that the addition of dispersed sawdust resulted to weaker CBGM samples. Upon increasing input energy from weight drop by 150%, magnetic field emissions from samples of the same concrete mixture showed significant increase with maximum magnitude of emission measured at 1.06 μT. A model of the magnetic field magnitudes with respect to sensor position was generated by non-linear data-fitting method using Microsoft Excel and SciLab.

Characteristics of acoustic emissions from shearing of granular media

NASA Astrophysics Data System (ADS)

Michlmayr, Gernot; Cohen, Denis; Or, Dani

2010-05-01

Deformation and abrupt formation of small failure cracks on hillslopes often precede sudden release of shallow landslides. The associated frictional sliding, breakage of cementing agents and rupture of embedded biological fibers or liquid bonds between grain contacts are associated with measurable acoustic emissions (AE). The aim of this study was to characterize small scale shear induced failure events (as models of precursors prior to a landslide) by capturing elastic body waves emitted from such events. We conducted a series of experiments with a specially-designed shear frame to measure and characterize high frequency (kHz range) acoustic emissions under different conditions using piezoelectric sensors. Tests were performed at different shear rates ranging from 0.01mm/sec to 2mm/sec with different dry and wet granular materials. In addition to acoustic emissions the setup allows to measure forces and deformations in both horizontal and vertical directions. Results provide means to define characteristic AE signature for different failure events. We observed an increase in AE activity during dilation of granular samples. In wet material AE signals were attributed to the snap-off of liquid bridges between single gains. Acoustic emissions clearly provide an experimental tool for exploring micro-mechanical processes in dry and wet material. Moreover, high sampling rates found in most AE systems coupled with waveguides to overcome signal attenuation offer a promise for field applications as an early warning method for observing the progressive development of slip planes prior to the onset of a landslide.

Erosion of a wet/dry granular interface

NASA Astrophysics Data System (ADS)

Jop, Pierre; Lefebvre, Gautier

2013-04-01

To model the dynamic of landslides, the evolution of the interface between the erodible ground and the flowing material is still studied experimentally or numerically (ie. Mangeney et al. 2010, Iverson 2012). In some cases, the basal material is more cohesive than the flowing one. Such situation arises for example due to cementation or humidity. What are the exchange rates between these phases? What is the coupling between the evolution of the interface and the flow? We studied the erosion phenomenon and performed laboratory experiments to focus on the interaction between a cohesive unsaturated granular material and a dry granular flow. Both materials were spherical grains, the cohesion being induced by adding a given mass of liquid to the grains. Two configurations were explored: a circular aggregate submitted to a dry flow in a rotating drum, and a granular flow eroding a wet granular pile. First, we focused on the influence of the cohesion, controlled by the liquid properties, such as the surface tension and the viscosity. Then the flow characteristics were modified by varying the grain size and density. These results allowed us to present a model for the erosion mechanisms, based on the flow and fluid properties. The main results are the need to take into account the whole probability distribution the stress applied on the wet grains and that both the surface tension and the viscosity are important since they play a different roles. The latter is mainly responsible of the time scale of the dynamic of a wet grain, while the former acts as a threshold on the force distribution. In the second configuration, we could also control the inclination of the slope. This system supported the previous model and moreover revealed an interface instability, leading the formation of steep steps, which is a reminiscence of the cyclic-steps observed during river-channel incision (Parker and Izumi 2000). We will present the dynamics of such granular steps. [1] Mangeney, A., O. Roche, O. Hungr, N. Mangold, G. Faccanoni, and A. Lucas (2010), Erosion and mobility in granular collapse over sloping beds, J. Geophys. Res., 115, F03040, doi:10.1029/2009JF001462. [2] Iverson, R. M. (2012), Elementary theory of bed-sediment entrainment by debris flows and avalanches, J. Geophys. Res., 117, F03006, doi:10.1029/2011JF002189. [3] Parker G.and Izumi N., Purely erosional cyclic and solitary steps created by flow over a cohesive bed, J. Fluid Mech. (2000), vol. 419, pp. 203-238.

40 CFR 278.1 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... THE MANAGEMENT OF GRANULAR MINE TAILINGS (CHAT) IN ASPHALT CONCRETE AND PORTLAND CEMENT CONCRETE IN... purposes, including reducing the stress applied to the sub grade layer and providing drainage for the...

40 CFR 278.1 - Definitions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... THE MANAGEMENT OF GRANULAR MINE TAILINGS (CHAT) IN ASPHALT CONCRETE AND PORTLAND CEMENT CONCRETE IN... purposes, including reducing the stress applied to the sub grade layer and providing drainage for the...

40 CFR 278.1 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... THE MANAGEMENT OF GRANULAR MINE TAILINGS (CHAT) IN ASPHALT CONCRETE AND PORTLAND CEMENT CONCRETE IN... purposes, including reducing the stress applied to the sub grade layer and providing drainage for the...

40 CFR 278.1 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... THE MANAGEMENT OF GRANULAR MINE TAILINGS (CHAT) IN ASPHALT CONCRETE AND PORTLAND CEMENT CONCRETE IN... purposes, including reducing the stress applied to the sub grade layer and providing drainage for the...

40 CFR 278.1 - Definitions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... THE MANAGEMENT OF GRANULAR MINE TAILINGS (CHAT) IN ASPHALT CONCRETE AND PORTLAND CEMENT CONCRETE IN... purposes, including reducing the stress applied to the sub grade layer and providing drainage for the...

40 CFR 278.4 - Certification and recordkeeping requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... WASTES (CONTINUED) CRITERIA FOR THE MANAGEMENT OF GRANULAR MINE TAILINGS (CHAT) IN ASPHALT CONCRETE AND PORTLAND CEMENT CONCRETE IN TRANSPORTATION CONSTRUCTION PROJECTS FUNDED IN WHOLE OR IN PART BY FEDERAL...

Textural evidence for jamming and dewatering of a sub-surface, fluid-saturated granular flow

NASA Astrophysics Data System (ADS)

Sherry, T. J.; Rowe, C. D.; Kirkpatrick, J. D.; Brodsky, E. E.

2011-12-01

Sand injectites are spectacular examples of large-scale granular flows involving migration of hundreds of cubic meters of sand slurry over hundreds of meters to kilometers in the sub-surface. By studying the macro- and microstructural textures of a kilometer-scale sand injectite, we interpret the fluid flow regimes during emplacement and define the timing of formation of specific textures in the injected material. Fluidized sand sourced from the Santa Margarita Fm., was injected upward into the Santa Cruz Mudstone, Santa Cruz County, California. The sand injectite exposed at Yellow Bank Beach records emplacement of both hydrocarbon and aqueous sand slurries. Elongate, angular mudstone clasts were ripped from the wall rock during sand migration, providing evidence for high velocity, turbid flow. However, clast long axis orientations are consistently sub-horizontal suggesting the slurry transitioned to a laminar flow as the flow velocity decreased in the sill-like intrusion. Millimeter to centimeter scale laminations are ubiquitous throughout the sand body and are locally parallel to the mudstone clast long axes. The laminations are distinct in exposure because alternating layers are preferentially cemented with limonite sourced from later groundwater infiltration. Quantitative microstructural analyses show that the laminations are defined by subtle oscillations in grain alignment between limonite and non-limonite stained layers. Grain packing, size and shape distributions do not vary. The presence of limonite in alternating layers results from differential infiltration of groundwater, indicating permeability changes between the layers despite minimal grain scale differences. Convolute dewatering structures deform the laminations. Dolomite-cemented sand, a signature of hydrocarbon saturation, forms irregular bodies that cross-cut the laminations and dewatering structures. Laminations are not formed in the dolomite-cemented sand. The relative viscosity difference between the hydrocarbon and aqueous sand slurries controls the the critical radius of the contacts between dolomite cemented and limonite cemented sand bodies. The cross-cutting relationships established in the field show that the laminations formed at the jamming transition in the aqueous sand slurry. We interpret the laminations as preserving evidence for dynamic permeability instabilities in the dewatering slurry. Relatively high permeability channels formed as pore fluid flow rearranged grains during initial dewatering. Once initiated, the flow localized further into the higher permeability channels resulting in a feedback that caused the permeability in the channels to increase.

Diagenetic history of late Oligocene-early Miocene carbonates in East Sabah, Malaysia

NASA Astrophysics Data System (ADS)

Zainal Abidin, N. S.; Raymond, R. R.; Bashah, N. S. I.

2017-10-01

Limestones are particularly susceptible to drastic early diagenesis modifications, mainly cementation and dissolution. During the early Miocene, a major tectonic deformation has caused a widespread of uplift in Sabah. This has resulted change in depositional environment from deep to shallow marine, which favours the deposition of Gomantong Limestone. This study aims to investigate the diagenetic history of Gomantong Limestone in East Sabah. Thorough understanding of the diagenetic processes may provide data to unravel the tectonic activities which affected the reservoir quality of the carbonates. Combining the data from comprehensive petrographic analysis, and Scanning Electron Microscopy (SEM) of 30 samples, two main cements type were identified. These are microcrystalline cement and Mg-calcite cement of granular and blocky mosaics which are dominantly seen in all samples. The sequence of diagenesis events are determined as (1) micritization; (2) grain scale compaction; (3) cementation (pore-filling); (4) mechanical compaction and cementation infilling fractures and (5) chemical compaction. These diagenetic events are interpreted as reflection of changes in diagenetic environment from shallow marine to deep burial. The massive cementation in the Gomantong Limestone has resulted into a poor reservoir quality.

Granular flow: Dry and wet

NASA Astrophysics Data System (ADS)

Mitarai, N.; Nakanishi, H.

2012-04-01

Granular material is a collection of macroscopic particles that are visible with naked eyes. The non-equilibrium nature of the granular materials makes their rheology quite different from that of molecular systems. In this minireview, we present the unique features of granular materials focusing on the shear flow of dry granular materials and granule-liquid mixture.

40 CFR 278.2 - Applicability.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 28 2013-07-01 2013-07-01 false Applicability. 278.2 Section 278.2 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) CRITERIA FOR THE MANAGEMENT OF GRANULAR MINE TAILINGS (CHAT) IN ASPHALT CONCRETE AND PORTLAND CEMENT CONCRETE IN...

40 CFR 278.2 - Applicability.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 28 2012-07-01 2012-07-01 false Applicability. 278.2 Section 278.2 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) CRITERIA FOR THE MANAGEMENT OF GRANULAR MINE TAILINGS (CHAT) IN ASPHALT CONCRETE AND PORTLAND CEMENT CONCRETE IN...

40 CFR 278.2 - Applicability.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 27 2014-07-01 2014-07-01 false Applicability. 278.2 Section 278.2 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) CRITERIA FOR THE MANAGEMENT OF GRANULAR MINE TAILINGS (CHAT) IN ASPHALT CONCRETE AND PORTLAND CEMENT CONCRETE IN...

40 CFR 278.2 - Applicability.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 27 2011-07-01 2011-07-01 false Applicability. 278.2 Section 278.2 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) CRITERIA FOR THE MANAGEMENT OF GRANULAR MINE TAILINGS (CHAT) IN ASPHALT CONCRETE AND PORTLAND CEMENT CONCRETE IN...

40 CFR 278.2 - Applicability.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Applicability. 278.2 Section 278.2 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) CRITERIA FOR THE MANAGEMENT OF GRANULAR MINE TAILINGS (CHAT) IN ASPHALT CONCRETE AND PORTLAND CEMENT CONCRETE IN...

Interrelationships among geotechnical and leaching properties of a cement-stabilized contaminated soil.

PubMed

Kogbara, Reginald B

2017-01-28

Relationships among selected performance properties have been established using experimental data from a cement-stabilized mixed contaminated soil. The sandy soil was spiked with 3,000 mg/kg each of Cd, Cu, Pb, Ni and Zn, and 10,000 mg/kg of diesel. It was then treated with 5%, 10%, 15%, and 20% dosages of Portland cement. Different water contents were considered for lower dosage mixes. Selected geotechnical and leaching properties were determined on 28-day old samples. These include unconfined compressive strength (UCS), bulk density, porosity, hydraulic conductivity, leachate pH and granular leachability of contaminants. Interrelationships among these properties were deduced using the most reasonable best fits determined by specialized curve fitting software. Strong quadratic and log-linear relationships exist between hydraulic conductivity and UCS, with increasing binder and water contents, respectively. However, the strength of interrelationships between hydraulic conductivity and porosity, UCS and porosity, and UCS and bulk density varies with binder and water contents. Leachate pH and granular leachability of contaminants are best related to UCS and hydraulic conductivity by a power law and an exponential function, respectively. These results suggest how the accuracy of not-easily-measurable performance properties may be constrained from simpler ones. Comparisons with some published performance properties data support this.

Impact Compaction of a Granular Material

NASA Astrophysics Data System (ADS)

Fenton, Gregg; Asay, Blaine; Todd, Steve; Grady, Dennis

2017-06-01

The dynamic behavior of granular materials has importance to a variety of engineering applications. Although, the mechanical behavior of granular materials have been studied extensively for several decades, the dynamic behavior of these materials remains poorly understood. High-quality experimental data are needed to improve our general understanding of granular material compaction physics. This paper describes how an instrumented plunger impact system can be used to measure the compaction process for granular materials at high and controlled strain rates and subsequently used for computational modelling. The experimental technique relies on a gas-gun driven plunger system to generate a compaction wave through a volume of granular material. This volume of material has been redundantly instrumented along the bed length to track the progression of the compaction wave, and the piston displacement is measured with Photon Doppler Velocimetry (PDV). Using the gathered experimental data along with the initial material tap density, a granular material equation of state can be determined.

Optimizing pavement base, subbase, and subgrade layers for cost and performance of local roads : [tech transfer summary].

DOT National Transportation Integrated Search

2014-12-01

It is common for local street and road pavements to be constructed using : portland cement concrete (PCC) directly supported on natural subgrade : without considering subgrade treatment or structural support layers such : as granular subbase. In orde...

Eco-friendly porous concrete using bottom ash aggregate for marine ranch application.

PubMed

Lee, Byung Jae; Prabhu, G Ganesh; Lee, Bong Chun; Kim, Yun Yong

2016-03-01

This article presents the test results of an investigation carried out on the reuse of coal bottom ash aggregate as a substitute material for coarse aggregate in porous concrete production for marine ranch applications. The experimental parameters were the rate of bottom ash aggregate substitution (30%, 50% and 100%) and the target void ratio (15%, 20% and 25%). The cement-coated granular fertiliser was substituted into a bottom ash aggregate concrete mixture to improve marine ranch applications. The results of leaching tests revealed that the bottom ash aggregate has only a negligible amount of the ten deleterious substances specified in the Ministry of Environment - Enforcement Regulation of the Waste Management Act of Republic Korea. The large amount of bubbles/air gaps in the bottom ash aggregate increased the voids of the concrete mixtures in all target void ratios, and decreased the compressive strength of the porous concrete mixture; however, the mixture substituted with 30% and 10% of bottom ash aggregate and granular fertiliser, respectively, showed an equal strength to the control mixture. The sea water resistibility of the bottom ash aggregate substituted mixture was relatively equal to that of the control mixture, and also showed a great deal of improvement in the degree of marine organism adhesion compared with the control mixture. No fatality of fish was observed in the fish toxicity test, which suggested that bottom ash aggregate was a harmless material and that the combination of bottom ash aggregate and granular fertiliser with substitution rates of 30% and 10%, respectively, can be effectively used in porous concrete production for marine ranch application. © The Author(s) 2015.

Contactor/filter improvements

DOEpatents

Stelman, David

1989-01-01

A contactor/filter arrangement for removing particulate contaminants from a gaseous stream includes a housing having a substantially vertically oriented granular material retention member with upstream and downstream faces, a substantially vertically oriented microporous gas filter element, wherein the retention member and the filter element are spaced apart to provide a zone for the passage of granular material therethrough. The housing further includes a gas inlet means, a gas outlet means, and means for moving a body of granular material through the zone. A gaseous stream containing particulate contaminants passes through the gas inlet means as well as through the upstream face of the granular material retention member, passing through the retention member, the body of granular material, the microporous gas filter element, exiting out of the gas outlet means. Disposed on the upstream face of the filter element is a cover screen which isolates the filter element from contact with the moving granular bed and collects a portion of the particulates so as to form a dust cake having openings small enough to exclude the granular material, yet large enough to receive the dust particles. In one embodiment, the granular material is comprised of prous alumina impregnated with CuO, with the cover screen cleaned by the action of the moving granular material as well as by backflow pressure pulses.

Spatio-structural granularity of biological material entities

PubMed Central

2010-01-01

Background With the continuously increasing demands on knowledge- and data-management that databases have to meet, ontologies and the theories of granularity they use become more and more important. Unfortunately, currently used theories and schemes of granularity unnecessarily limit the performance of ontologies due to two shortcomings: (i) they do not allow the integration of multiple granularity perspectives into one granularity framework; (ii) they are not applicable to cumulative-constitutively organized material entities, which cover most of the biomedical material entities. Results The above mentioned shortcomings are responsible for the major inconsistencies in currently used spatio-structural granularity schemes. By using the Basic Formal Ontology (BFO) as a top-level ontology and Keet's general theory of granularity, a granularity framework is presented that is applicable to cumulative-constitutively organized material entities. It provides a scheme for granulating complex material entities into their constitutive and regional parts by integrating various compositional and spatial granularity perspectives. Within a scale dependent resolution perspective, it even allows distinguishing different types of representations of the same material entity. Within other scale dependent perspectives, which are based on specific types of measurements (e.g. weight, volume, etc.), the possibility of organizing instances of material entities independent of their parthood relations and only according to increasing measures is provided as well. All granularity perspectives are connected to one another through overcrossing granularity levels, together forming an integrated whole that uses the compositional object perspective as an integrating backbone. This granularity framework allows to consistently assign structural granularity values to all different types of material entities. Conclusions The here presented framework provides a spatio-structural granularity framework for all domain reference ontologies that model cumulative-constitutively organized material entities. With its multi-perspectives approach it allows querying an ontology stored in a database at one's own desired different levels of detail: The contents of a database can be organized according to diverse granularity perspectives, which in their turn provide different views on its content (i.e. data, knowledge), each organized into different levels of detail. PMID:20509878

Contactor/filter improvements

DOEpatents

Stelman, D.

1988-06-30

A contactor/filter arrangement for removing particulate contaminants from a gaseous stream is described. The filter includes a housing having a substantially vertically oriented granular material retention member with upstream and downstream faces, a substantially vertically oriented microporous gas filter element, wherein the retention member and the filter element are spaced apart to provide a zone for the passage of granular material therethrough. A gaseous stream containing particulate contaminants passes through the gas inlet means as well as through the upstream face of the granular material retention member, passing through the retention member, the body of granular material, the microporous gas filter element, exiting out of the gas outlet means. A cover screen isolates the filter element from contact with the moving granular bed. In one embodiment, the granular material is comprised of porous alumina impregnated with CuO, with the cover screen cleaned by the action of the moving granular material as well as by backflow pressure pulses. 6 figs.

Amplitude of late Miocene sea-level fluctuations from karst development in reef-slope deposits (SE Spain)

NASA Astrophysics Data System (ADS)

Reolid, Jesús; Betzler, Christian; Braga, Juan Carlos

2016-11-01

A prograding late Miocene carbonate platform in southern Spain revealing different sea-level pinning points was analysed with the aim to increase the accuracy of reconstruction of past sea-level changes. These pinning points are distinct diagenetic zones (DZ) and the position of reef-framework deposits. DZ1 is defined by the dissolution of bioclastic components and DZ2 by calcitic cement precipitation in dissolution pores. Calcite cements are granular and radiaxial fibrous, and are of meteoric origin as deduced from cathodoluminescence, EDX spectroscopy, as well as from δ13C and δ18O isotope analyses. DZ3 has moldic porosity after aragonitic bioclasts with minor granular calcitic cements. DZ1 and DZ2 indicate karstification and the development of a coastal palaeoaquifer during a sea-level lowstand. DZ3 diagenetic features are related to the final subaerial exposure of the section during the Messinian Salinity Crisis. Facies and diagenetic data reveal a complete cycle of sea-level fall (23 ± 1 m) and rise (31 ± 1 m). A robust age model based on magneto- and cyclostratigraphy for these deposits places this cycle between 5.89 and 5.87 Ma. Therefore, for the first time, this work allows a direct comparison of an outcrop with a pelagic marine proxy record of a specific Neogene sea-level fluctuation.

Gas stream clean-up filter and method for forming same

DOEpatents

Mei, Joseph S.; DeVault, James; Halow, John S.

1993-01-01

A gas cleaning filter is formed in-situ within a vessel containing a fluidizable bed of granular material of a relatively large size fraction. A filter membrane provided by a porous metal or ceramic body or such a body supported a perforated screen on one side thereof is coated in-situ with a layer of the granular material from the fluidized bed by serially passing a bed-fluidizing gas stream through the bed of granular material and the membrane. The layer of granular material provides the filtering medium for the combined membrane-granular layer filter. The filter is not blinded by the granular material and provides for the removal of virtually all of the particulates from a process gas stream. The granular material can be at least partially provided by a material capable of chemically reacting with and removing sulfur compounds from the process gas stream. Low level radioactive waste containing organic material may be incinerated in a fluidized bed in communication with the described filter for removing particulates from the gaseous combustion products.

Hydrophobization of Concrete Using Granular Nanostructured Aggregate

NASA Astrophysics Data System (ADS)

Ogurtsova, Y. N.; Strokova, V. V.; Labuzova, M. V.

2017-11-01

The possibility of giving hydrophobical properties to the fine-grained concrete matrix by using a granular nanostructured aggregate (GNA) with a hydrophobizing additive is investigated in this work. GNA is obtained by granulating the silica raw material with an alkaline component. The introduction of a hydrophobizing additive into the raw mix of GNA allows to encapsulate it reducing the negative effect on hydration processes, the intensity of migration of moisture and efflorescence in concrete and, consequently, improving the performance characteristics of fine-grained concrete products. The hydrophobizing ability of a solution of sodium polysilicates formed in the core of GNA during concrete heat and moisture treatment is proved. The analysis of IR spectra after the impregnation of cement stone samples with a solution of sodium polysilicates showed an increase in the degree of hydration and the formation of framework water aluminosilicates. Atmospheric processes modelling showed that the use of GNA on the basis of gaize with calcium stearate and on the basis of fly ash with GKZh-11 makes it possible to increase the resistance of fine-grained concrete to the atmospheric effect of the medium, namely, the outwashing of readily soluble compounds.

Laboratory Investigation on the Effects of Natural Fine Aggregates and Recycled Waste Tire Rubber in Pervious Concrete to Develop More Sustainable Pavement Materials

NASA Astrophysics Data System (ADS)

Bonicelli, Alessandra; Fuentes, Luis G.; Khalil Dawd Bermejo, Ibrahim

2017-10-01

Pervious concrete pavement is a recognized sustainable solution for urban roads. To enhance mechanical properties of pervious concrete material, in order to allow wider use of this technology, a lot of studies are going on all over the world. The use of a little percentage of fine aggregates is proven to increase the material resistance without an excessive reduction of permeability. This study aimed to evaluate the effect of replacing the fine virgin aggregates with r cycled tire rubber. 14 different mixes were analysed in terms of indirect tensile strength resistance, void content and density. Two different dimensions of crumb rubber were studied, as well as two different dosages, which were applied to different no-fine control mixes. All results were compared with the same control mixes containing natural fine aggregate. The mixes had a fixed granulometric curve but varied in water/cement ratio; this in order to evaluate the effect of recycled rubber depending to w/c ratio of the mix. An image analysis was also conducted to verify the rubber distribution in the mixture and the cracking surfaces. The experimental analysis showed that a correct proportioning of fine sand significantly increased the strength of the material. Moreover, the use of recycled waste tire rubber, gave interesting improvements respect to the no-fine control mixes, even though the developed resistance was lower respect to mixes containing mineral sand. This result was expected because of the cementing property of mineral sand. Although, the important result was that it was possible to use waste tire rubber in pervious concrete, with an appropriate dosage and granular dimension, for increasing the performance of traditional mix design, in order to achieve pavement materials more and more sustainable.

Friction on a granular-continuum interface: Effects of granular media

NASA Astrophysics Data System (ADS)

Ecke, Robert; Geller, Drew

We consider the frictional interactions of two soft plates with interposed granular material subject to normal and shear forces. The plates are soft photo-elastic material, have length 50 cm, and are separated by a gap of variable width from 0 to 20 granular particle diameters. The granular materials are two-dimensional rods that are bi-dispersed in size to prevent crystallization. Different rod materials with frictional coefficients between 0 . 04 < μ < 0 . 5 are used to explore the effects of inter-granular friction on the effective friction of a granular medium. The gap is varied to test the dependence of the friction coefficient on the thickness of the granular layer. Because the soft plates absorb most of the displacement associated with the compressional normal force, the granular packing fractions are close to a jamming threshold, probably a shear jamming criterion. The overall shear and normal forces are measured using force sensors and the local strain tensor over a central portion of the gap is obtained using relative displacements of fiducial markers on the soft elastic material. These measurements provide a good characterization of the global and local forces giving rise to an effective friction coefficient. Funded by US DOE LDRD Program.

Nanogranular origin of concrete creep.

PubMed

Vandamme, Matthieu; Ulm, Franz-Josef

2009-06-30

Concrete, the solid that forms at room temperature from mixing Portland cement with water, sand, and aggregates, suffers from time-dependent deformation under load. This creep occurs at a rate that deteriorates the durability and truncates the lifespan of concrete structures. However, despite decades of research, the origin of concrete creep remains unknown. Here, we measure the in situ creep behavior of calcium-silicate-hydrates (C-S-H), the nano-meter sized particles that form the fundamental building block of Portland cement concrete. We show that C-S-H exhibits a logarithmic creep that depends only on the packing of 3 structurally distinct but compositionally similar C-S-H forms: low density, high density, ultra-high density. We demonstrate that the creep rate ( approximately 1/t) is likely due to the rearrangement of nanoscale particles around limit packing densities following the free-volume dynamics theory of granular physics. These findings could lead to a new basis for nanoengineering concrete materials and structures with minimal creep rates monitored by packing density distributions of nanoscale particles, and predicted by nanoscale creep measurements in some minute time, which are as exact as macroscopic creep tests carried out over years.

Nanogranular origin of concrete creep

PubMed Central

Vandamme, Matthieu; Ulm, Franz-Josef

2009-01-01

Concrete, the solid that forms at room temperature from mixing Portland cement with water, sand, and aggregates, suffers from time-dependent deformation under load. This creep occurs at a rate that deteriorates the durability and truncates the lifespan of concrete structures. However, despite decades of research, the origin of concrete creep remains unknown. Here, we measure the in situ creep behavior of calcium–silicate–hydrates (C–S–H), the nano-meter sized particles that form the fundamental building block of Portland cement concrete. We show that C–S–H exhibits a logarithmic creep that depends only on the packing of 3 structurally distinct but compositionally similar C–S–H forms: low density, high density, ultra-high density. We demonstrate that the creep rate (≈1/t) is likely due to the rearrangement of nanoscale particles around limit packing densities following the free-volume dynamics theory of granular physics. These findings could lead to a new basis for nanoengineering concrete materials and structures with minimal creep rates monitored by packing density distributions of nanoscale particles, and predicted by nanoscale creep measurements in some minute time, which are as exact as macroscopic creep tests carried out over years. PMID:19541652

A hydrodynamic model for granular material flows including segregation effects

NASA Astrophysics Data System (ADS)

Gilberg, Dominik; Klar, Axel; Steiner, Konrad

2017-06-01

The simulation of granular flows including segregation effects in large industrial processes using particle methods is accurate, but very time-consuming. To overcome the long computation times a macroscopic model is a natural choice. Therefore, we couple a mixture theory based segregation model to a hydrodynamic model of Navier-Stokes-type, describing the flow behavior of the granular material. The granular flow model is a hybrid model derived from kinetic theory and a soil mechanical approach to cover the regime of fast dilute flow, as well as slow dense flow, where the density of the granular material is close to the maximum packing density. Originally, the segregation model has been formulated by Thornton and Gray for idealized avalanches. It is modified and adapted to be in the preferred form for the coupling. In the final coupled model the segregation process depends on the local state of the granular system. On the other hand, the granular system changes as differently mixed regions of the granular material differ i.e. in the packing density. For the modeling process the focus lies on dry granular material flows of two particle types differing only in size but can be easily extended to arbitrary granular mixtures of different particle size and density. To solve the coupled system a finite volume approach is used. To test the model the rotational mixing of small and large particles in a tumbler is simulated.

Failure evolution in granular material retained by rigid wall in active mode

NASA Astrophysics Data System (ADS)

Pietrzak, Magdalena; Leśniewska, Danuta

2012-10-01

This paper presents a detailed study of a selected small scale model test, performed on a sample of surrogate granular material, retained by a rigid wall (typical geotechnical problem of earth thrust on a retaining wall). The experimental data presented in this paper show that the deformation of granular sample behind retaining wall can undergo some cyclic changes. The nature of these cycles is not clear - it is probably related to some micromechanical features of granular materials, which are recently extensively studied in many research centers in the world. Employing very precise DIC (PIV) method can help to relate micro and macro-scale behavior of granular materials.

Analysis and Modeling of Structure Formation in Granular and Fluid-Solid Flows

NASA Astrophysics Data System (ADS)

Murphy, Eric

Granular and multiphase flows are encountered in a number of industrial processes with particular emphasis in this manuscript given to the particular applications in cement pumping, pneumatic conveying, fluid catalytic cracking, CO2 capture, and fast pyrolysis of bio-materials. These processes are often modeled using averaged equations that may be simulated using computational fluid dynamics. Closure models are then required that describe the average forces that arise from both interparticle interactions, e.g. shear stress, and interphase interactions, such as mean drag. One of the biggest hurdles to this approach is the emergence of non-trivial spatio-temporal structures in the particulate phase, which can significantly modify the qualitative behavior of these forces and the resultant flow phenomenology. For example, the formation of large clusters in cohesive granular flows is responsible for a transition from solid-like to fluid-like rheology. Another example is found in gas-solid systems, where clustering at small scales is observed to significantly lower in the observed drag. Moreover, there remains the possibility that structure formation may occur at all scales, leading to a lack of scale separation required for traditional averaging approaches. In this context, several modeling problems are treated 1) first-principles based modeling of the rheology of cement slurries, 2) modeling the mean solid-solid drag experienced by polydisperse particles undergoing segregation, and 3) modeling clustering in homogeneous gas-solid flows. The first and third components are described in greater detail. In the study on the rheology of cements, several sub-problems are introduced, which systematically increase in the number and complexity of interparticle interactions. These interparticle interactions include inelasticity, friction, cohesion, and fluid interactions. In the first study, the interactions between cohesive inelastic particles was fully characterized for the first time. Next, kinetic theory was used to predict the cooling of a gas of such particles. DEM was then used to validate this approach. A study on the rheology of dry cohesive granules with and without friction was then carried out, where the physics of different flow phenomenology was exhaustively explored. Lastly, homogeneous cement slurry simulations were carried out, and compared with vane-rheometer experiments. Qualitative agreement between simulation and experiment were observed. Lastly, the physics of clustering in homogeneous gas-solid flows is explored in the hopes of gaining a mechanistic explanation of how particle-fluid interactions lead to clustering. Exact equations are derived, detailing the evolution of the two particle density, which may be closed using high-fidelity particle-resolved direct numerical simulation. Two canonical gas-solid flows are then addressed, the homogeneously cooling gas-solid flow (HCGSF) and sedimenting gas-solid flow (SGSF). A mechanism responsible for clustering in the HCGSF is identified. Clustering of plane-wave like structures is observed in the SGSF, and the exact terms are quantified. A method for modeling the dynamics of clustering in these systems is proposed, which may aid in the prediction of clustering and other correlation length-scales useful for less expensive computations.

Gravity and Granular Materials

NASA Technical Reports Server (NTRS)

Behringer, R. P.; Hovell, Daniel; Kondic, Lou; Tennakoon, Sarath; Veje, Christian

1999-01-01

We describe experiments that probe a number of different types of granular flow where either gravity is effectively eliminated or it is modulated in time. These experiments include the shaking of granular materials both vertically and horizontally, and the shearing of a 2D granular material. For the shaken system, we identify interesting dynamical phenomena and relate them to standard simple friction models. An interesting application of this set of experiments is to the mixing of dissimilar materials. For the sheared system we identify a new kind of dynamical phase transition.

Synthesis of Portland cement and calcium sulfoaluminate-belite cement for sustainable development and performance

NASA Astrophysics Data System (ADS)

Chen, Irvin Allen

Portland cement concrete, the most widely used manufactured material in the world, is made primarily from water, mineral aggregates, and portland cement. The production of portland cement is energy intensive, accounting for 2% of primary energy consumption and 5% of industrial energy consumption globally. Moreover, portland cement manufacturing contributes significantly to greenhouse gases and accounts for 5% of the global CO2 emissions resulting from human activity. The primary objective of this research was to explore methods of reducing the environmental impact of cement production while maintaining or improving current performance standards. Two approaches were taken, (1) incorporation of waste materials in portland cement synthesis, and (2) optimization of an alternative environmental friendly binder, calcium sulfoaluminate-belite cement. These approaches can lead to less energy consumption, less emission of CO2, and more reuse of industrial waste materials for cement manufacturing. In the portland cement part of the research, portland cement clinkers conforming to the compositional specifications in ASTM C 150 for Type I cement were successfully synthesized from reagent-grade chemicals with 0% to 40% fly ash and 0% to 60% slag incorporation (with 10% intervals), 72.5% limestone with 27.5% fly ash, and 65% limestone with 35% slag. The synthesized portland cements had similar early-age hydration behavior to commercial portland cement. However, waste materials significantly affected cement phase formation. The C3S--C2S ratio decreased with increasing amounts of waste materials incorporated. These differences could have implications on proportioning of raw materials for cement production when using waste materials. In the calcium sulfoaluminate-belite cement part of the research, three calcium sulfoaluminate-belite cement clinkers with a range of phase compositions were successfully synthesized from reagent-grade chemicals. The synthesized calcium sulfoaluminate-belite cement that contained medium C4A3 S¯ and C2S contents showed good dimensional stability, sulfate resistance, and compressive strength development and was considered the optimum phase composition for calcium sulfoaluminate-belite cement in terms of comparable performance characteristics to portland cement. Furthermore, two calcium sulfoaluminate-belite cement clinkers were successfully synthesized from natural and waste materials such as limestone, bauxite, flue gas desulfurization sludge, Class C fly ash, and fluidized bed ash proportioned to the optimum calcium sulfoaluminate-belite cement synthesized from reagent-grade chemicals. Waste materials composed 30% and 41% of the raw ingredients. The two calcium sulfoaluminate-belite cements synthesized from natural and waste materials showed good dimensional stability, sulfate resistance, and compressive strength development, comparable to commercial portland cement.

Developing a Magnetic Resonance Imaging measurement of the forces within 3D granular materials under external loads

NASA Astrophysics Data System (ADS)

Elrington, Stefan; Bertrand, Thibault; Frey, Merideth; Shattuck, Mark; O'Hern, Corey; Barrett, Sean

2014-03-01

Granular materials are comprised of an ensemble of discrete macroscopic grains that interact with each other via highly dissipative forces. These materials are ubiquitous in our everyday life ranging in scale from the granular media that forms the Earth's crust to that used in agricultural and pharmaceutical industries. Granular materials exhibit complex behaviors that are poorly understood and cannot be easily described by statistical mechanics. Under external loads individual grains are jammed into place by a network of force chains. These networks have been imaged in quasi two-dimensional and on the outer surface of three-dimensional granular materials. Our goal is to use magnetic resonance imaging (MRI) to detect contact forces deep within three-dimensional granular materials, using hydrogen-1 relaxation times as a reporter for changes in local stress and strain. To this end, we use a novel pulse sequence to narrow the line width of hydrogen-1 in rubber. Here we present our progress to date, and prospects for future improvements.

Time-resolved dynamics of granular matter by random laser emission

NASA Astrophysics Data System (ADS)

Folli, Viola; Ghofraniha, Neda; Puglisi, Andrea; Leuzzi, Luca; Conti, Claudio

2013-07-01

Because of the huge commercial importance of granular systems, the second-most used material in industry after water, intersecting the industry in multiple trades, like pharmacy and agriculture, fundamental research on grain-like materials has received an increasing amount of attention in the last decades. In photonics, the applications of granular materials have been only marginally investigated. We report the first phase-diagram of a granular as obtained by laser emission. The dynamics of vertically-oscillated granular in a liquid solution in a three-dimensional container is investigated by employing its random laser emission. The granular motion is function of the frequency and amplitude of the mechanical solicitation, we show how the laser emission allows to distinguish two phases in the granular and analyze its spectral distribution. This constitutes a fundamental step in the field of granulars and gives a clear evidence of the possible control on light-matter interaction achievable in grain-like system.

Effects of Coal Gangue on Cement Grouting Material Properties

NASA Astrophysics Data System (ADS)

Liu, J. Y.; Chen, H. X.

2018-05-01

The coal gangue is one of the most abundant industrial solid wastes and pollute source of air and water. The use of coal gangue in the production of cement grouting material comforms to the basic state policy of environment protection and the circular using of natural resources. Through coal gangue processing experiment, coal gangue cement grouting materials making test, properties detection of properties and theoretical analysis, the paper studied the effects of coal gangue on the properties of cement grouting materials. It is found that at the range of 600 to 700 °C, the fluidity and the compressive and flexural strengths of the cement grouting materials increase with the rising up of the calcination temperatures of coal gangue. The optimum calcination temperature is around 700 °C. The part substitution of cement by the calcined coal gangue in the cement grouting material will improve the mechanical properties of the cement grouting material, even thought it will decrease its fluidity. The best substitution amount of cement by coal gangue is about 30%. The fluidity and the long term strength of the ordinary silicate cement grouting material is obviously higher than that of the sulphoaluminate cement one as well as that of the silicate-sulphoaluminate complex cement one.

Numerical investigations on flow dynamics of prismatic granular materials using the discrete element method

NASA Astrophysics Data System (ADS)

Hancock, W.; Weatherley, D.; Wruck, B.; Chitombo, G. P.

2012-04-01

The flow dynamics of granular materials is of broad interest in both the geosciences (e.g. landslides, fault zone evolution, and brecchia pipe formation) and many engineering disciplines (e.g chemical engineering, food sciences, pharmaceuticals and materials science). At the interface between natural and human-induced granular media flow, current underground mass-mining methods are trending towards the induced failure and subsequent gravitational flow of large volumes of broken rock, a method known as cave mining. Cave mining relies upon the undercutting of a large ore body, inducement of fragmentation of the rock and subsequent extraction of ore from below, via hopper-like outlets. Design of such mines currently relies upon a simplified kinematic theory of granular flow in hoppers, known as the ellipsoid theory of mass movement. This theory assumes that the zone of moving material grows as an ellipsoid above the outlet of the silo. The boundary of the movement zone is a shear band and internal to the movement zone, the granular material is assumed to have a uniformly high bulk porosity compared with surrounding stagnant regions. There is however, increasing anecdotal evidence and field measurements suggesting this theory fails to capture the full complexity of granular material flow within cave mines. Given the practical challenges obstructing direct measurement of movement both in laboratory experiments and in-situ, the Discrete Element Method (DEM [1]) is a popular alternative to investigate granular media flow. Small-scale DEM studies (c.f. [3] and references therein) have confirmed that movement within DEM silo flow models matches that predicted by ellipsoid theory, at least for mono-disperse granular material freely outflowing at a constant rate. A major draw-back of these small-scale DEM studies is that the initial bulk porosity of the simulated granular material is significantly higher than that of broken, prismatic rock. In this investigation, more realistic granular material geometries are simulated using the ESyS-Particle [2] DEM simulation software on cluster supercomputers. Individual grains of the granular material are represented as convex polyhedra. Initially the polyhedra are packed in a low bulk porosity configuration prior to commencing silo flow simulations. The resultant flow dynamics are markedly different to that predicted by ellipsoid theory. Initially shearing occurs around the silo outlet however rapidly shear localization in a particular direction dominates other directions, causing preferential movement in that direction. Within the shear band itself, the granular material becomes hgihly dilated however elsewhere the bulk porosity remains low. The low porosity within these regions promotes entrainment whereby large volumes of granular material interlock and begin to rotate and translate as a single rigid body. In some cases, entrainment may result in complete overturning of a large volume of material. The consequences of preferential shear localization and in particular, entrainment, for granular media flow in cave mines and natural settings (such as brecchia pipes) is a topic of ongoing research to be presented at the meeting.

Introduction

NASA Astrophysics Data System (ADS)

Starosvetsky, Yuli; Jayaprakash, K. R.; Hasan, Md. Arif; Vakakis, Alexander F.

The study of mechanics of granular media dates back to the era of Coulomb. He was the first to postulate the yield condition for homogeneous solids and also conditions for failure in granular media [1-4]. In fact the ideal Coulomb material is the simplest granular material model wherein the shear stress along a plane is linearly proportional to the normal stress on that plane. This can be considered analogous to the Coulomb friction model in cohesion-free interfaces between solids. Initial research in this domain focused mainly on the statics of granular materials from a soil mechanics perspective. However, as the applications of granular materials broadened, the objectives of different research communities contradicted. For example, in geophysics or soil mechanics the objective is to regard granular media with properties of a solid in order to take considerable loads without yielding; on the other hand, in food grain or pharmaceutical industries the granular media is considered as fluids and their rheological properties are of interest. In fact granular media can exhibit both of these behaviors (and also the properties of a gas), and such unique features pave the way for their broad range applications...

Impact compaction of a granular material

DOE PAGES

Fenton, Gregg; Asay, Blaine; Dalton, Devon

2015-05-19

The dynamic behavior of granular materials has importance to a variety of engineering applications. Structural seismic coupling, planetary science, and earth penetration mechanics, are just a few of the application areas. Although the mechanical behavior of granular materials of various types have been studied extensively for several decades, the dynamic behavior of such materials remains poorly understood. High-quality experimental data are needed to improve our general understanding of granular material compaction physics. This study will describe how an instrumented plunger impact system can be used to measure pressure-density relationships for model materials at high and controlled strain rates and subsequentlymore » used for computational modeling.« less

MGM - MS Reilly holds a container used in the MGM experiment

NASA Image and Video Library

1998-03-04

S89-E-5328 (27 Jan 1998) --- This Electronic Still Camera (ESC) image shows astronaut James F. Reilly, mission specialist, holding the Mechanics of Granular Materials (MGM) experiment. The MGM experiment is aimed at understanding the behavior of granular materials, such as sand or salt, under very low confining pressure. This pressure is the force that keeps a granular material ?sticking together?. The experiment has applications in a wide range of fields, including earthquake engineering; coastal and off-shore engineering; mining; transportation of granular materials; soil erosion; the handling of granular materials such as grains and powders; off-road vehicles; geology of the Earth; and planetary geology and exploration. Findings from the experiment may lead to improved selection and preparation of building sites, better management of undeveloped land, and improved handling of materials in chemical, agricultural and other industries.

Educational Brief: Using Space for a Better Foundation on Earth Mechanics of Granular Materials

NASA Technical Reports Server (NTRS)

Dooling, Dave (Editor)

2002-01-01

Soils are three-phase composite materials that consist of soil, solid particles, and voids filled with water and/or air. Based on the particle-size distribution, they are generally classified as fine-grained (clays and plastic silts) and coarse-grained soils (nonplastic silts, sand, and gravel). Soil's resistance to external loadings is mainly derived from friction between particles and cohesion. Friction resistance is due to particles' surface-to-surface friction, interlocking, crushing, rearrangement, and dilation (or expansion) during shearing. Cohesion can be due to chemical cementation between particles, electrostatic and electromagnetic forces, and soil-water reaction and equilibrium. The basic factor responsible for the strength of coarse-grained soils is friction. Cohesion can be ignored. This educational brief focuses on measuring shear strength of sands (typical example of coarse-grained soils) where, for the same material, packing density is a main factor to be considered when one asks about the shear strength value. As the external load is applied, the soil's resistance is attained through shearing resistance, which causes the soil volume to increase (expand) or decrease (compress) depending on the initial packing density.

Cementing a wellbore using cementing material encapsulated in a shell

DOEpatents

Aines, Roger D.; Bourcier, William L.; Duoss, Eric B.; Spadaccini, Christopher M.; Cowan, Kenneth Michael

2016-08-16

A system for cementing a wellbore penetrating an earth formation into which a pipe extends. A cement material is positioned in the space between the wellbore and the pipe by circulated capsules containing the cement material through the pipe into the space between the wellbore and the pipe. The capsules contain the cementing material encapsulated in a shell. The capsules are added to a fluid and the fluid with capsules is circulated through the pipe into the space between the wellbore and the pipe. The shell is breached once the capsules contain the cementing material are in position in the space between the wellbore and the pipe.

Micro-scale investigation on the quasi-static behavior of granular material

NASA Astrophysics Data System (ADS)

Li, Xia

Granular material exhibits complex responses when subjected to various external loading. Fundamental mechanisms have not been well established so far, including that about the critical state, one of the most important concepts in the modern soil mechanics. With the recognition that granular material is discrete in nature, the basic understanding can only be obtained from the particle scale. The complexity in granular material behavior lies in the fact that the macroscopic behavior of granular material is determined by not only the interactions operating at contacts, but also how the particles become arranged in space to form an internal structure. This research is aimed to microscopically investigate the influence of the internal structure and the fundamental mechanism about the critical state. In view of the extensive laboratory test data already available in the literature, a numerical simulation method, DEM, is employed as the tool to conduct particle-scale investigations. The contact model for two in-contact circular disks is derived theoretically from the elasticity theory, and the result is a linear contact model with constant stiffness and lateral sliding. Based on the contact model, a systematic series of numerical tests has been implemented, and the results can successfully reproduce the main characteristics in the behavior of natural granular material, under various loading conditions. The macro-micro relationship is the link between the investigations at the two worlds. The key point is to describe the internal structure with the two dual cell systems, a particle cell system and a void cell system. Based on these two systems, the stress and strain in a uniform field are equivalently expressed in terms of the contact forces/relative displacements, and the micro-geometrical variables. With the microstructural definition of the stress tensor, the stress state of granular material is studied microscopically. The stress-fabric-force relation is derived, based on the variables describing the statistics of the contact forces and the contact vectors. By studying the evolution of the micro-quantities during shearing, how the internal structure affects the macro stress state under different loading condition is revealed. With the assumption that the influence of the local variance in stress is ignorable, the response of granular material can be investigated based on the void cell system. Starting from the behavior of a single void cell, the evolutions of the internal structure and its influence on the response of granular material are explained. The stress ratio and the dilatancy behavior of granular material are investigated. The influences of the void ratio, the mean normal stress and the drainage condition are discussed. The fundamental mechanism of the critical state is studied in the framework of thermodynamics with properly considering the influence of the internal structure. The normalized stress ratio tensor at critical state is associated with the critical void cell anisotropy, corresponding to the maximal energy dissipation. The (e, p) relationship at critical state is associated with the critical combination of the void cell size and the contact interactions, corresponding to the minimal free energy. The investigation on the influence of the internal structure anisotropy on the granular material behavior and the critical state is carried out. The results show that at small strain levels, the behavior of granular material is mainly affected by the initial fabric. As shearing continuous, the internal structure of granular material is gradually changed. The granular material approaches the critical state, which is irrespective with the initial internal structure. The critical state of granular material is not unique. With different loading modes, the critical state of granular material, including both the critical stress ratio and the critical (e, p) relations, are found to be different. A fabric tensor is defined based on the characteristics of the void cells. The laboratory method to quantify the fabric anisotropy is proposed by deviatoric shearing. 3D numerical simulations have been carried out to investigate the influence of the loading mode, which is found to be an important factor in the large strain behavior of granular material. With the obtained microscopic understanding, the influence of contact model on granular material behavior is investigated. A method to quantify the fabric anisotropy is proposed. And a simple discussion on the state variable used in the elasto-plastic constitutive model is given.

The influence of sugarcane bagasse ash as fly ash on cement quality

NASA Astrophysics Data System (ADS)

Rauf, N.; Damayanti, M. C.; Pratama, S. W. I.

2017-01-01

Fly ash often is used as the third material for cement. The fly ash from sugarcane bagasse is usually considered as industrial waste material that can be added to the base material of cement (clinker, trash, gypsum and lime stone) for economic and environment reason. The amount of fly ash usually up to 30 % of cement material, but in this research the percentage of sugarcane bagasse ash (SBA) is added to cement material is up to 15% total weight. Then the x-rays fluorescence (XRF) was used to determine its chemical composition of raw material and cement samples. The physical properties of cement such as fineness, setting time, expansion, and compressive strength were measured using Automatic Blaine, Vicat, Autoclave, respectively. The result show that the percentage of sugarcane bagasse ash influences the quality of cement and concrete, and this is confirmed with Indonesia National Standard (SNI). It is showed that the sugarcane bagasse ash could be use as material to improve the quality of cement and will solve the environment waste material

A road pavement full-scale test track containing stabilized bottom ashes.

PubMed

Toraldo, E; Saponaro, S

2015-01-01

This paper reports the results of a road pavement full-scale test track built by using stabilized bottom ash (SBA) from an Italian municipal solid waste incinerator as the aggregate in granular foundation, cement-bound mixes and asphalt concretes. The investigation focused on both the performance and the environmental compatibility of such mixes, especially with regard to the effects of mixing, laying and compaction. From the road construction point of view, the performance related to the effects of mixing, laying and compaction on constructability was assessed, as well as the volumetric and the mechanical properties. Environmental aspects were investigated by leaching tests. The results suggested that SBA meets the environmental Italian law for the reuse of non-hazardous waste and could be used as road material with the procedures, plants and equipment currently used for road construction.

QUANTIFYING THE MICROMECHANICAL EFFECTS OF VARIABLE CEMENT IN GRANULAR POROUS MEDIA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boutt, David F; Goodwin, Laurel B

2010-03-01

The mechanical and hydrologic behavior of clastic rocks and sediments is fundamentally controlled by variables such as grain size and shape, sorting, grain and cement mineralogy, porosity, and %cement - parameters that are not used directly in field-scale models of coupled flow and deformation. To improve our understanding of the relationship between these micromechanical properties and bulk behavior we focused on (1) relating detailed, quantitative characterization of the grain-pore systems to both hydrologic and mechanical properties of a suite of variably quartz-cemented quartz arenite samples and (2) the use of a combination of discrete element method (DEM) and poroelastic modelsmore » parameterized by data from the natural samples to isolate and compare the influence of changes in the mechanical and hydrologic properties of granular porous media due to changes in degree of cementation. Quartz overgrowths, the most common form of authigenic cements in sandstones, are responsible for significant porosity and permeability reduction. The distribution of quartz overgrowths is controlled by available pore space and the crystallographic orientations of individual quartz grains. Study of the St. Peter Sandstone allowed evaluation of the relative effects of quartz cementation and compaction on final grain and pore morphology, showing that progressive quartz cementation modifies the grain framework in consistent, predictable ways. Detailed microstructural characterization and multiple regression analyses show that with progressive diagenesis, the number and length of grain contacts increases as the number of pores increases, the number of large, well-connected pores decreases, and pores become rounder. These changes cause a decrease in pore size variability that leads to a decrease in bulk permeability and both stiffening and strengthening of the grain framework. The consistent nature of these changes allows us to predict variations in hydrologic and mechanical properties with progressive diagenesis, and explore the impact of these changes on aquifer behavior. Several examples of this predictive capability are offered. In one application, data from natural sandstones are used to calibrate the proportionality constant of the Kozeny- Carman relationship, improving the ability to predict permeability in quartz-cemented quartz arenites. In another, the bond-to-grain ratio (BGR) is used to parameterize a discrete element model with data acquired from sandstone samples. The DEM results provide input to poroelastic models used to explore the hydrologic, mechanical, and coupled hydrologic and mechanical response of the sandstone to pumping stresses. This modeling exercise shows that at the macroscale, changes in mechanical and hydrologic properties directly influence the magnitude and area of aquifer deformation. The significant difference in sensitivity of the system to the mechanical properties alone versus its sensitivity to coupled mechanical and hydrologic properties demonstrates the importance of including hydrologic properties that are adjusted for changes in cementation in fluid storage and deformation studies. The large magnitude of radial deformation compared to vertical deformation in these models emphasizes the importance of considering three dimensional deformation in fluid flow and deformation studies.« less

Multiscale Phenomena in the Solid-Liquid Transition State of a Granular Material: Analysis and Modelling of Dense Granular Materials

DTIC Science & Technology

2011-09-26

most challenging to characterize and model of the gamut of granular behaviour encountered in practice. In particular, it exhibits self-organized...is intrinsically multiscale and is arguably one of, if not, the most challenging to characterize and model of the gamut of granular behaviour...the most challenging to characterize and model of the gamut of granular behaviour encountered in practice. In particular, it exhibits self-organized

Using Space for a Better Foundation on Earth: Mechanics of Granular Materials. Educational Brief. Grades 5-8.

ERIC Educational Resources Information Center

Alshibli, Khalid

This publication presents a science activity and instructional information on mechanics of granular materials, interparticle friction and geometric interlocking between particles which is a fundamental concept in many fields like earthquakes. The activity described in this document focuses on the principal strength of granular materials,…

Cementing a wellbore using cementing material encapsulated in a shell

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aines, Roger D.; Bourcier, William L.; Duoss, Eric B.

A system for cementing a wellbore penetrating an earth formation into which a pipe extends. A cement material is positioned in the space between the wellbore and the pipe by circulated capsules containing the cement material through the pipe into the space between the wellbore and the pipe. The capsules contain the cementing material encapsulated in a shell. The capsules are added to a fluid and the fluid with capsules is circulated through the pipe into the space between the wellbore and the pipe. The shell is breached once the capsules contain the cementing material are in position in themore » space between the wellbore and the pipe.« less

Crushed cement concrete substitution for construction aggregates; a materials flow analysis

USGS Publications Warehouse

Kelly, Thomas

1998-01-01

An analysis of the substitution of crushed cement concrete for natural construction aggregates is performed by using a materials flow diagram that tracks all material flows into and out of the cement concrete portion of the products made with cement concrete: highways, roads, and buildings. Crushed cement concrete is only one of the materials flowing into these products, and the amount of crushed cement concrete substituted influences the amount of other materials in the flow. Factors such as availability and transportation costs, as well as physical properties, that can affect stability and finishability, influence whether crushed cement concrete or construction aggregates should be used or predominate for a particular end use.

Microstructural characterization of catalysis product of nanocement based materials: A review

NASA Astrophysics Data System (ADS)

Sutan, Norsuzailina Mohamed; Izaitul Akma Ideris, Nur; Taib, Siti Noor Linda; Lee, Delsye Teo Ching; Hassan, Alsidqi; Kudnie Sahari, Siti; Mohamad Said, Khairul Anwar; Rahman Sobuz, Habibur

2018-03-01

Cement as an essential element for cement-based products contributed to negative environmental issues due to its high energy consumption and carbon dioxide emission during its production. These issues create the need to find alternative materials as partial cement replacement where studies on the potential of utilizing silica based materials as partial cement replacement come into picture. This review highlights the effectiveness of microstructural characterization techniques that have been used in the studies that focus on characterization of calcium hydroxide (CH) and calcium silicate hydrate (C-S-H) formation during hydration process of cement-based product incorporating nano reactive silica based materials as partial cement replacement. Understanding the effect of these materials as cement replacement in cement based product focusing on the microstructural development will lead to a higher confidence in the use of industrial waste as a new non-conventional material in construction industry that can catalyse rapid and innovative advances in green technology.

Using Space for a Better Foundation on Earth: Mechanics of Granular Materials. Educational Brief. Grades 9-12.

ERIC Educational Resources Information Center

Alshibli, Khalid

This publication presents a science activity and instructional information on the mechanics of granular materials, interparticle friction and geometric interlocking between particles which is a fundamental concept in many fields like in the study of earthquakes. This document describes the Mechanics of Granular Materials (MGM) experiments which…

Accelerated testing for studying pavement design and performance (FY 2001) : evaluation of the performance of permeable and semi-permeable unbound granular bases under Portland Cement Concrete Pavement (PCCP) slabs and alternate load transfer devices for

DOT National Transportation Integrated Search

2003-11-01

The objectives of this research are to determine the effect of unbound drainable base types on the performance of PCCP and the efficiency of fiber-reinforced polymer (FRP) dowels, compared to epoxy coated steel dowels, when retrofitted to re-establis...

Dynamics of Granular Materials

NASA Technical Reports Server (NTRS)

Behringer, Robert P.

1996-01-01

Granular materials exhibit a rich variety of dynamical behavior, much of which is poorly understood. Fractal-like stress chains, convection, a variety of wave dynamics, including waves which resemble capillary waves, l/f noise, and fractional Brownian motion provide examples. Work beginning at Duke will focus on gravity driven convection, mixing and gravitational collapse. Although granular materials consist of collections of interacting particles, there are important differences between the dynamics of a collections of grains and the dynamics of a collections of molecules. In particular, the ergodic hypothesis is generally invalid for granular materials, so that ordinary statistical physics does not apply. In the absence of a steady energy input, granular materials undergo a rapid collapse which is strongly influenced by the presence of gravity. Fluctuations on laboratory scales in such quantities as the stress can be very large-as much as an order of magnitude greater than the mean.

The effect of fly ash and coconut fibre ash as cement replacement materials on cement paste strength

NASA Astrophysics Data System (ADS)

Bayuaji, R.; Kurniawan, R. W.; Yasin, A. K.; Fatoni, H. AT; Lutfi, F. M. A.

2016-04-01

Concrete is the backbone material in the construction field. The main concept of the concrete material is composed of a binder and filler. Cement, concrete main binder highlighted by environmentalists as one of the industry are not environmentally friendly because of the burning of cement raw materials in the kiln requires energy up to a temperature of 1450° C and the output air waste CO2. On the other hand, the compound content of cement that can be utilized in innovation is Calcium Hydroxide (CaOH), this compound will react with pozzolan material and produces additional strength and durability of concrete, Calcium Silicate Hydrates (CSH). The objective of this research is to explore coconut fibers ash and fly ash. This material was used as cement replacement materials on cement paste. Experimental method was used in this study. SNI-03-1974-1990 is standard used to clarify the compressive strength of cement paste at the age of 7 days. The result of this study that the optimum composition of coconut fiber ash and fly ash to substitute 30% of cement with 25% and 5% for coconut fibers ash and fly ash with similar strength if to be compared normal cement paste.

Microstructural Properties of Cement Paste and Mortar Modified by Low Cost Nanoplatelets Sourced from Natural Materials.

PubMed

Huang, Piao; Lv, Liming; Liao, Wei; Lu, Chunhua; Xu, Zhongzi

2018-05-11

Nanomaterials have been widely used in cement-based materials. Graphene has excellent properties for improving the durability of cement-based materials. Given its high production budget, it has limited its wide potential for application in the field of engineering. Hence, it is very meaningful to obtain low cost nanoplatelets from natural materials that can replace graphene nanoplatelets (GNPs) The purpose of this paper is to improve the resistance to chloride ion penetration by optimizing the pore structure of cement-based materials, and another point is to reduce investment costs. The results illustrated that low cost CaCO₃ nanoplatelets (CCNPs) were successfully obtained under alkali treatment of seashell powder, and the chloride ion permeability of cement-based materials significantly decreased by 15.7% compared to that of the control samples when CCNPs were incorporated. Furthermore, the compressive strength of cement pastes at the age of 28 days increased by 37.9% than that of the plain sample. Improvement of performance of cement-based materials can be partly attributed to the refinement of the pore structure. In addition, AFM was employed to characterize the nanoplatelet thickness of CCNPs and the pore structures of the cement-based composites were analyzed by MIP, respectively. CCNPs composite cement best performance could lay the foundation for further study of the durability of cement-based materials and the application of decontaminated seashells.

Microstructural Properties of Cement Paste and Mortar Modified by Low Cost Nanoplatelets Sourced from Natural Materials

PubMed Central

Lv, Liming; Liao, Wei; Lu, Chunhua; Xu, Zhongzi

2018-01-01

Nanomaterials have been widely used in cement-based materials. Graphene has excellent properties for improving the durability of cement-based materials. Given its high production budget, it has limited its wide potential for application in the field of engineering. Hence, it is very meaningful to obtain low cost nanoplatelets from natural materials that can replace graphene nanoplatelets (GNPs) The purpose of this paper is to improve the resistance to chloride ion penetration by optimizing the pore structure of cement-based materials, and another point is to reduce investment costs. The results illustrated that low cost CaCO3 nanoplatelets (CCNPs) were successfully obtained under alkali treatment of seashell powder, and the chloride ion permeability of cement-based materials significantly decreased by 15.7% compared to that of the control samples when CCNPs were incorporated. Furthermore, the compressive strength of cement pastes at the age of 28 days increased by 37.9% than that of the plain sample. Improvement of performance of cement-based materials can be partly attributed to the refinement of the pore structure. In addition, AFM was employed to characterize the nanoplatelet thickness of CCNPs and the pore structures of the cement-based composites were analyzed by MIP, respectively. CCNPs composite cement best performance could lay the foundation for further study of the durability of cement-based materials and the application of decontaminated seashells. PMID:29751666

APC fly ashes stabilized with Portland cement for further development of road sub-base aggregates

NASA Astrophysics Data System (ADS)

Formosa, J.; Giro-Paloma, J.; Maldonado-Alameda, A.; Huete-Hernández, S.; Chimenos, J. M.

2017-10-01

Although waste-to-energy plants allow reducing the mass and volume of municipal solid waste (MSW) incinerated, an average around 30 % of the total content remains as bottom ash (BA) and air pollution control (APC) ashes at the end of combustion process. While weathered bottom ash (WBA) is considered a non-hazardous residue that can be revalorized as a secondary aggregate, APC fly ashes generated during the flue gas treatment are classified as hazardous waste and are handled in landfill disposal after stabilization, usually with Portland cement (OPC). However, taking into account the amount of APC residues produced and the disposing cost in landfill, their revalorization is an important issue that could be effectively addressed. As MSW can be incinerated producing bottom ashes (BA) or air pollutant control (APC) residues, the development of a mortar formulated with APC fly ash as secondary building material is a significant risk to the environment for their content of heavy metals. In this way, Design of Experiment (DoE) was used for the improvement of granular material (GM) formulation composed by APC and OPC for further uses as road sub-base aggregate. DoE analysis was successful in the modelling and optimization the formulation as function of the mechanical properties and APC amount. Consequently, an optimal mortar formulation (OMF) of around 50 wt.% APC and 50 wt.% OPC was considered. The OMF leachates and abrasion resistance have been analyzed. These results have demonstrated the viability of OMF as non-hazardous material feasible to be used as secondary aggregate. Moreover, it would be possible to consider the environmental assessment of a GM composed by ≈20 wt.% of OMF and ≈80 wt.% of WBA in order to improve mechanical properties and heavy metals stabilization.

Flowability of granular materials with industrial applications - An experimental approach

NASA Astrophysics Data System (ADS)

Torres-Serra, Joel; Romero, Enrique; Rodríguez-Ferran, Antonio; Caba, Joan; Arderiu, Xavier; Padullés, Josep-Manel; González, Juanjo

2017-06-01

Designing bulk material handling equipment requires a thorough understanding of the mechanical behaviour of powders and grains. Experimental characterization of granular materials is introduced focusing on flowability. A new prototype is presented which performs granular column collapse tests. The device consists of a channel whose design accounts for test inspection using visualization techniques and load measurements. A reservoir is attached where packing state of the granular material can be adjusted before run-off to simulate actual handling conditions by fluidisation and deaeration of the pile. Bulk materials on the market, with a wide range of particle sizes, can be tested with the prototype and the results used for classification in terms of flowability to improve industrial equipment selection processes.

Pressure regulator

DOEpatents

Ebeling, Jr., Robert W.; Weaver, Robert B.

1979-01-01

The pressure within a pressurized flow reactor operated under harsh environmental conditions is controlled by establishing and maintaining a fluidized bed of uniformly sized granular material of selected density by passing the gas from the reactor upwardly therethrough at a rate sufficient to fluidize the bed and varying the height of the bed by adding granular material thereto or removing granular material therefrom to adjust the backpressure on the flow reactor.

Resilient Modulus Characterization of Alaskan Granular Base Materials

DOT National Transportation Integrated Search

2010-08-01

Resilient modulus (MR) of base course material is an important material input for : pavement design. In Alaska, due to distinctiveness of local climate, material source, : fines content and groundwater level, resilient properties of D-1 granular base...

The Effect of the Kind of Sands and Additions on the Mechanical Behaviour of S.C.C

NASA Astrophysics Data System (ADS)

Zeghichi, L.; Benghazi, Z.; Baali, L.

The sand is an inert element essential in the composition of concrete; its use ensures granular continuity between the cement and gravel for better cohesion of concrete. This paper presents the results of a study that investigated the influence of sand quality on the properties of fresh and hardened self-compacting concrete (SCC). The dune sands are very fine materials characterized by a high intergranular porosity, high surface area and low fineness modulus; on the other hand crushed (manufactured) sand has a high rate into thin and irregular shapes which are influencing the workability of concrete. The amount of dune sand varies from (0% 50%, to 100%) by weight of fine aggregates. The effect of additions is also treated (blast furnace slag and lime stone) The results show that the rheological properties favour the use of dune sands; however the mechanical properties support the use of crushed sand.

Characterization and analyses of acid-extractable and leached trace elements in dental cements.

PubMed

Camilleri, J; Kralj, P; Veber, M; Sinagra, E

2012-08-01

Determination of the elemental constitution and investigation of the total and leachable arsenic, chromium and lead in Portland cement, pure tricalcium silicate, Biodentine, Bioaggregate and mineral trioxide aggregate (MTA) Angelus. The chemical composition of Portland cement, MTA Angelus, tricalcium silicate cement, Biodentine and Bioaggregate was determined using X-ray fluorescence (XRF). Measurements of arsenic, lead and chromium were taken with inductively coupled plasma-mass spectrometry (ICP-MS), following acid digestion on the hydrated material and on leachates of cements soaked in Hank's balanced salt solution (HBSS). All the cements investigated had a similar oxide composition with the main oxide being calcium and silicon oxide. Both the Portland cement and MTA Angelus had an additional aluminium oxide. The dental cements included a radiopacifying material. All the materials tested had higher acid-extractable arsenic content than the level set by ISO 9917-1 (2007) and an acceptable level of lead. Regardless these high levels of trace elements present in the materials, the leaching in HBSS was minimal for all the dental material tested in contrast to the high levels displayed by Portland cement. Dental materials based on tricalcium silicate cement and MTA Angelus release minimal quantities of trace elements when in contact with simulated body fluids. The results of acid extraction could be affected by nonspecific matrix effects by the cement. © 2012 International Endodontic Journal.

On Critical States, Rupture States and Interlocking Strength of Granular Materials.

PubMed

Szalwinski, Chris M

2017-07-27

The Mohr-Coulomb theory of strength identifies cohesion and internal friction as the two principal contributions to the shear strength of a granular material. The contribution of cohesion in over-compacted granular materials has been challenged and replacing cohesion with interlocking has been proposed. A theory of rupture strength that includes interlocking is derived herein. The physics-chemistry concept of critical state is elaborated to accommodate granular materials, based on empirical definitions established in the fields of soil mechanics and bulk solids' flow. A surface in state space, called the critical compaction surface, separates over-compacted states from lightly compacted states. The intersection of this surface with the Mohr-Coulomb envelope forms the critical state surface for a granular material. The rupture strength of an over-compacted granular material is expressed as the sum of cohesion, internal friction and interlocking strength. Interlocking strength is the shear strength contribution due to over-compaction and vanishes at critical state. The theory allows migrations from one critical state to another. Changes in specific volume during such migrations are related to changes in mean-normal effective stress and uncoupled from changes in shearing strain. The theory is reviewed with respect to two established research programs and underlying assumptions are identified.

Comparison of Novel Carboneous Structures to Treat Nitroaromatic Impacted Water

DTIC Science & Technology

2015-12-01

MS-15-D-047 Abstract Carboneous materials such as carbon nanotube (CNT), granular activated carbon (GAC), and biochar are promising materials...TECHNOLOGIES ...................................................49 A.3 GRANULAR ACTIVATED CARBON (GAC) ............................................50 A.4...GENERAL ISSUE In this study, we compared the adsorptive capacity of bituminous-coal based granular activated carbon (GAC) versus pristine novel

Experimental study on the signs of particulate structures formation in annular geometry of rapid granular shear flows

NASA Astrophysics Data System (ADS)

Ritvanen, J.; Jalali, P.

2009-06-01

Rapid granular shear flow is a classical example in granular materials which exhibits both fluid-like and solid-like behaviors. Another interesting feature of rapid granular shear flows is the formation of ordered structures upon shearing. Certain amount of granular material, with uniform size distribution, is required to be loaded in the container in order to shear it under stable conditions. This work concerns the experimental study of rapid granular shear flows in annular Couette geometry. The flow is induced by continuous rotation of the plate over the top of the granular bed in an annulus. The compressive pressure, driving torque, instantaneous bed height from three symmetric locations and rotational speed of the shearing plate are measured. The annulus has a capacity of up to 15 kg of spherical steel balls of 3 mm in diameter. Rapid shear flow experiments are performed in one compressive force and rotation rate. The sensitivity of fluctuations is then investigated by different means through monodisperse packing. In this work, we present the results of the experiments showing how the flow properties depend on the amount of loaded granular material which is varied by small amounts between different experiments. The flow can exist in stable (fixed behavior) and unstable (time-dependent behavior) regimes as a function of the loaded material. We present the characteristics of flow to detect the formation of any additional structured layer in the annulus. As a result, an evolution graph for the bed height has been obtained as material is gradually added. This graph shows how the bed height grows when material increases. Using these results, the structure inside the medium can be estimated at extreme stable and unstable conditions.

Granular materials interacting with thin flexible rods

NASA Astrophysics Data System (ADS)

Neto, Alfredo Gay; Campello, Eduardo M. B.

2017-04-01

In this work, we develop a computational model for the simulation of problems wherein granular materials interact with thin flexible rods. We treat granular materials as a collection of spherical particles following a discrete element method (DEM) approach, while flexible rods are described by a large deformation finite element (FEM) rod formulation. Grain-to-grain, grain-to-rod, and rod-to-rod contacts are fully permitted and resolved. A simple and efficient strategy is proposed for coupling the motion of the two types (discrete and continuum) of materials within an iterative time-stepping solution scheme. Implementation details are shown and discussed. Validity and applicability of the model are assessed by means of a few numerical examples. We believe that robust, efficiently coupled DEM-FEM schemes can be a useful tool to the simulation of problems wherein granular materials interact with thin flexible rods, such as (but not limited to) bombardment of grains on beam structures, flow of granular materials over surfaces covered by threads of hair in many biological processes, flow of grains through filters and strainers in various industrial segregation processes, and many others.

Hydration characteristics of zirconium oxide replaced Portland cement for use as a root-end filling material.

PubMed

Camilleri, J; Cutajar, A; Mallia, B

2011-08-01

Zirconium oxide can be added to dental materials rendering them sufficiently radiopaque. It can thus be used to replace the bismuth oxide in mineral trioxide aggregate (MTA). Replacement of Portland cement with 30% zirconium oxide mixed at a water/cement ratio of 0.3 resulted in a material with adequate physical properties. This study aimed at investigating the microstructure, pH and leaching in physiological solution of Portland cement replaced zirconium oxide at either water-powder or water-cement ratios of 0.3 for use as a root-end filling material. The hydration characteristics of the materials which exhibited optimal behavior were evaluated. Portland cement replaced by zirconium oxide in varying amounts ranging from 0 to 50% in increments of 10 was prepared and divided into two sets. One set was prepared at a constant water/cement ratio while the other set at a constant water/powder ratio of 0.3. Portland cement and MTA were used as controls. The materials were analyzed under the scanning electron microscope (SEM) and the hydration products were determined. X-ray energy dispersive analysis (EDX) was used to analyze the elemental composition of the hydration products. The pH and the amount of leachate in Hank's balanced salt solution (HBSS) were evaluated. A material that had optimal properties that satisfied set criteria and could replace MTA was selected. The microstructure of the prototype material and Portland cement used as a control was assessed after 30 days using SEM and atomic ratio diagrams of Al/Ca versus Si/Ca and S/Ca versus Al/Ca were plotted. The hydration products of Portland cement replaced with 30% zirconium oxide mixed at water/cement ratio of 0.3 were calcium silicate hydrate, calcium hydroxide and minimal amounts of ettringite and monosulphate. The calcium hydroxide leached in HBSS solution resulted in an increase in the pH value. The zirconium oxide acted as inert filler and exhibited no reaction with the hydration by-products of Portland cement. A prototype dental material composed of Portland cement replaced with 30% zirconium oxide as radiopacifier leached calcium ions on hydration which reacted with phosphates present in simulated tissue fluids. This resulted in bioactive cement that could prospectively be used as a root-end filling material. The zirconium oxide acted as inert filler and did not participate in the hydration reaction of the Portland cement. Copyright © 2011 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

Partial filling of a honeycomb structure by granular materials for vibration and noise reduction

NASA Astrophysics Data System (ADS)

Koch, Sebastian; Duvigneau, Fabian; Orszulik, Ryan; Gabbert, Ulrich; Woschke, Elmar

2017-04-01

In this paper, the damping effect of granular materials is explored to reduce the vibration and noise of mechanical structures. To this end, a honeycomb structure with high stiffness is used to contain a granular filling which presents the possiblity for the distribution of the granular material to be designed. As a particular application example, the oil pan bottom of a combustion engine is used to investigate the influence on the vibration behavior and the sound emission. The effect of the honeycomb structure along with the granular mass, distribution, and type on the vibration behaviour of the structure is investigated via laser scanning vibrometry. From this, an optimized filling is determined and then its noise suppression level validated on an engine test bench through measurements with an acoustic array.

Cement-based materials' characterization using ultrasonic attenuation

NASA Astrophysics Data System (ADS)

Punurai, Wonsiri

The quantitative nondestructive evaluation (NDE) of cement-based materials is a critical area of research that is leading to advances in the health monitoring and condition assessment of the civil infrastructure. Ultrasonic NDE has been implemented with varying levels of success to characterize cement-based materials with complex microstructure and damage. A major issue with the application of ultrasonic techniques to characterize cement-based materials is their inherent inhomogeneity at multiple length scales. Ultrasonic waves propagating in these materials exhibit a high degree of attenuation losses, making quantitative interpretations difficult. Physically, these attenuation losses are a combination of internal friction in a viscoelastic material (ultrasonic absorption), and the scattering losses due to the material heterogeneity. The objective of this research is to use ultrasonic attenuation to characterize the microstructure of heterogeneous cement-based materials. The study considers a real, but simplified cement-based material, cement paste---a common bonding matrix of all cement-based composites. Cement paste consists of Portland cement and water but does not include aggregates. First, this research presents the findings of a theoretical study that uses a set of existing acoustics models to quantify the scattered ultrasonic wavefield from a known distribution of entrained air voids. These attenuation results are then coupled with experimental measurements to develop an inversion procedure that directly predicts the size and volume fraction of entrained air voids in a cement paste specimen. Optical studies verify the accuracy of the proposed inversion scheme. These results demonstrate the effectiveness of using attenuation to measure the average size, volume fraction of entrained air voids and the existence of additional larger entrapped air voids in hardened cement paste. Finally, coherent and diffuse ultrasonic waves are used to develop a direct relationship between attenuation and water to cement (w/c) ratio. A phenomenological model based on the existence of fluid-filled capillary voids is used to help explain the experimentally observed behavior. Overall this research shows the potential of using ultrasonic attenuation to quantitatively characterize cement paste. The absorption and scattering losses can be related to the individual microstructural elements of hardened cement paste. By taking a fundamental, mechanics-based approach, it should be possible to add additional components such as scattering by aggregates or even microcracks in a systematic fashion and eventually build a realistic model for ultrasonic wave propagation study for concrete.

Improved method and composition for immobilization of waste in cement-based material

DOEpatents

Tallent, O.K.; Dodson, K.E.; McDaniel, E.W.

1987-10-01

A composition and method for fixation or immobilization of aqueous hazardous waste material in cement-based materials (grout) is disclosed. The amount of drainable water in the cured grout is reduced by the addition of an ionic aluminum compound to either the waste material or the mixture of waste material and dry-solid cement- based material. This reduction in drainable water in the cured grout obviates the need for large, expensive amounts of gelling clays in grout materials and also results in improved consistency and properties of these cement-based waste disposal materials.

Dental Cements for Luting and Bonding Restorations: Self-Adhesive Resin Cements.

PubMed

Manso, Adriana P; Carvalho, Ricardo M

2017-10-01

Self-adhesive resin cements combine easy application of conventional luting materials with improved mechanical properties and bonding capability of resin cements. The presence of functional acidic monomers, dual cure setting mechanism, and fillers capable of neutralizing the initial low pH of the cement are essential elements of the material and should be understood when selecting the ideal luting material for each clinical situation. This article addresses the most relevant aspects of self-adhesive resin cements and their potential impact on clinical performance. Although few clinical studies are available to establish solid clinical evidence, the information presented provides clinical guidance in the dynamic environment of material development. Copyright © 2017 Elsevier Inc. All rights reserved.

Effects of Leaching Behavior of Calcium Ions on Compression and Durability of Cement-Based Materials with Mineral Admixtures

PubMed Central

Cheng, An; Chao, Sao-Jeng; Lin, Wei-Ting

2013-01-01

Leaching of calcium ions increases the porosity of cement-based materials, consequently resulting in a negative effect on durability since it provides an entry for aggressive harmful ions, causing reinforcing steel corrosion. This study investigates the effects of leaching behavior of calcium ions on the compression and durability of cement-based materials. Since the parameters influencing the leaching behavior of cement-based materials are unclear and diverse, this paper focuses on the influence of added mineral admixtures (fly ash, slag and silica fume) on the leaching behavior of calcium ions regarding compression and durability of cemented-based materials. Ammonium nitrate solution was used to accelerate the leaching process in this study. Scanning electron microscopy, X-ray diffraction analysis, and thermogravimetric analysis were employed to analyze and compare the cement-based material compositions prior to and after calcium ion leaching. The experimental results show that the mineral admixtures reduce calcium hydroxide quantity and refine pore structure through pozzolanic reaction, thus enhancing the compressive strength and durability of cement-based materials. PMID:28809247

Discrete element modeling of free-standing wire-reinforced jammed granular columns

NASA Astrophysics Data System (ADS)

Iliev, Pavel S.; Wittel, Falk K.; Herrmann, Hans J.

2018-02-01

The use of fiber reinforcement in granular media is known to increase the cohesion and therefore the strength of the material. However, a new approach, based on layer-wise deployment of predetermined patterns of the fiber reinforcement has led self-confining and free-standing jammed structures to become viable. We have developed a novel model to simulate fiber-reinforced granular materials, which takes into account irregular particles and wire elasticity and apply it to study the stability of unconfined jammed granular columns.

Characterization of PCC Cement by Addition of Napa Soil from Subdistrict Sarilamak 50 Kota District as Alternative Additional Material for Semen Padang

NASA Astrophysics Data System (ADS)

Mawardi, M.; Deyundha, D.; Zainul, R.; Zalmi P, R.

2018-04-01

The study has been conducted to determine characteristics of the portland composite cement by the addition of napa soil from Sarilamak subdistrict, 50 Kota District as an alternative additional material at PT. Semen Padang. Napa soil is a natural material highly containing silica and alumina minerals so that it can be one of material in producing cement. This study aims to determine the effect of napa soil on the quality of portland composite cement. Napa soil used in the variation compositions 0%, 4%, 8%, 12% and 16%, for control of cement used 8 % of pozzolan and 0 % of napa soil. Determination of cement quality by testing cement characteristics include blaine test, sieving, lost of ignition or LOI, insoluble residue, normal consistency, setting time and compressive strength. Cement was characterized using XRF. Fineness of cement decreases with the addition of napa soil. Lost of Ignition of cement decreased, while the insoluble residue increased with the addition of napa soil. Normal consistency of cement increasing, so does initial setting time and final setting time of cement. While the resultant compressive strength decreases with the addition of napa soil on 28 days, 342, 325, 307, 306, and 300 kg / cm2.

Jetting and flooding of granular backfill materials : [summary].

DOT National Transportation Integrated Search

2015-03-01

Granular backfill materials on highway projects are often compacted by mechanical methods. : This requires the contractor to place backfill material into loose lifts of varying thickness : and use compaction equipment to reduce air voids and increase...

Effects of Noise and Vibration on the Solid to Liquid Fluidization Transition in Small Dense Granular Systems Under Shear

NASA Astrophysics Data System (ADS)

Melhus, Martin Frederic

2011-07-01

Granular materials exhibit bulk properties that are distinct from conventional solids, liq- uids, and gases, due to the dissipative nature of the inter-granular forces. Understanding the fundamentals of granular materials draws upon and gives insight into many fields at the current frontiers of physics, such as plasticity of solids, fracture and friction, com- plex systems such as colloids, foams and suspensions, and a variety of biological systems. Particulate flows are widespread in geophysics, and are also essential to many industries. Despite the importance of these phenomena, we lack a theoretical model that explains most behaviors of granular materials. Since granular assemblies are highly dissipative, they are often far from mechanical equilibrium, making most classical analyses inappli- cable. A theory for dilute granular systems exists, but for dense granular systems (by far the majority of granular systems in the real world) no comparable theory is accepted. We approach this problem by examining the fluidization, or transition from solid to liquid, in dense granular systems. In this study, the separate effects of random noise and vibration on the static to flowing transition of a dense granular assembly under planar shear is studied numerically using soft contact particle dynamics simulations in two dimensions. We focus on small systems in a thin planar Couette cell, examining the bistable region while increasing shear, with varying amounts of random noise or vibration, and determine the statistics of the shear required for the onset of flow. We find that the applied power is the key parameter in determining the magnitude of the effects of the noise or vibration, with vibration frequency also having an influence. Similarities and differences between noise and vibration are determined, and the results compare favorably with a two phase model for dense granular flow.

Granular flows in constrained geometries

NASA Astrophysics Data System (ADS)

Murthy, Tejas; Viswanathan, Koushik

Confined geometries are widespread in granular processing applications. The deformation and flow fields in such a geometry, with non-trivial boundary conditions, determine the resultant mechanical properties of the material (local porosity, density, residual stresses etc.). We present experimental studies of deformation and plastic flow of a prototypical granular medium in different nontrivial geometries- flat-punch compression, Couette-shear flow and a rigid body sliding past a granular half-space. These geometries represent simplified scaled-down versions of common industrial configurations such as compaction and dredging. The corresponding granular flows show a rich variety of flow features, representing the entire gamut of material types, from elastic solids (beam buckling) to fluids (vortex-formation, boundary layers) and even plastically deforming metals (dead material zone, pile-up). The effect of changing particle-level properties (e.g., shape, size, density) on the observed flows is also explicitly demonstrated. Non-smooth contact dynamics particle simulations are shown to reproduce some of the observed flow features quantitatively. These results showcase some central challenges facing continuum-scale constitutive theories for dynamic granular flows.

Wide-scale utilization of MSWI fly ashes in cement production and its impact on average heavy metal contents in cements: The case of Austria.

PubMed

Lederer, Jakob; Trinkel, Verena; Fellner, Johann

2017-02-01

A number of studies present the utilization of fly ashes from municipal solid waste incineration (MSWI) in cement production as a recycling alternative to landfilling. While there is a lot of research on the impact of MSWI fly ashes utilization in cement production on the quality of concrete or the leaching of heavy metals, only a few studies have determined the resulting heavy metal content in cements caused by this MSWI fly ashes utilization. Making use of the case of Austria, this study (1) determines the total content of selected heavy metals in cements currently produced in the country, (2) designs a scenario and calculates the resulting heavy metal contents in cements assuming that all MSWI fly ashes from Austrian grate incinerators were used as secondary raw materials for Portland cement clinker production and (3) evaluates the legal recyclability of demolished concretes produced from MSWI fly ash amended cements based on their total heavy metal contents. To do so, data from literature and statistics are combined in a material flow analysis model to calculate the average total contents of heavy metals in cements and in the resulting concretes according to the above scenario. The resulting heavy metal contents are then compared (i) to their respective limit values for cements as defined in a new technical guideline in Austria (BMLFUW, 2016), and (ii) to their respective limit values for recycling materials from demolished concrete. Results show that MSWI fly ashes utilization increases the raw material input in cement production by only +0.9%, but the total contents of Cd by +310%, and Hg, Pb, and Zn by +70% to +170%. However these and other heavy metal contents are still below their respective limit values for Austrian cements. The same legal conformity counts for recycling material derived from concretes produced from the MSWI fly ash cements. However, if the MSWI fly ash ratio in all raw materials used for cement production were increased from 0.9% to 22%, which is suggested by some studies, the limit values for cements as defined by the BMLFUW (2016) will be exceeded. Furthermore, the concrete produced from this cement will not be recyclable anymore due to its high total heavy metal contents. This and the comparatively high contribution of MSWI fly ashes to total heavy metal contents in cements indicate their relatively low resource potential if compared to other secondary raw materials in the cement industry. Copyright © 2016 Elsevier Ltd. All rights reserved.

Low Temperature Regolith Bricks for In-Situ Structural Material

NASA Technical Reports Server (NTRS)

Grossman, Kevin; Sakthivel, Tamil S.; Mantovani, James; Seal, Sudipta

2016-01-01

Current technology for producing in-situ structural materials on future missions to Mars or the moon relies heavily on energy-intensive sintering processes to produce solid bricks from regolith. This process requires heating the material up to temperatures in excess of 1000 C and results in solid regolith pieces with compressive strengths in the range of 14000 to 28000 psi, but are heavily dependent on the porosity of the final material and are brittle. This method is currently preferred over a low temperature cementation process to prevent consumption of precious water and other non-renewable materials. A high strength structural material with low energy requirements is still needed for future colonization of other planets. To fulfill these requirements, a nano-functionalization process has been developed to produce structural bricks from regolith simulant and shows promising mechanical strength results. Functionalization of granular silicate particles into alkoxides using a simple low temperature chemical process produces a high surface area zeolite particles that are held together via inter-particle oxygen bonding. Addition of water in the resulting zeolite particles produces a sol-gel reaction called "inorganic polymerization" which gives a strong solid material after a curing process at 60 C. The aqueous solution by-product of the reaction is currently being investigated for its reusability; an essential component of any ISRU technology. For this study, two batches of regolith bricks are synthesized from JSC-1A; the first batch from fresh solvents and chemicals, the second batch made from the water solution by-product of the first batch. This is done to determine the feasibility of recycling necessary components of the synthesis process, mainly water. Characterization including BET surface area, SEM, and EDS has been done on the regolith bricks as well as the constituent particles,. The specific surface area of 17.53 sq m/g (average) of the granular regolith material was obtained from nitrogen adsorption isotherm measurement. The size, shape and textures of regolith from SEM shows that the particles are 25-50 micrometers in size and mostly irregular in shape (Figure 1a). The elemental composition of regolith was identified from EDS analysis showed the presence of Si, Al, Fe, Na, Mg, Ca, Ti, O and C (see figure 1b). Each set of cylindrical brick samples were prepared by low energy process, and cured for 21 and 28 days, respectively to compare their compressive strength. Figure 1c, and d shows the JSC-1A brick and the compressive strength measurements. The results from the 21 day cured bricks (2 bricks) have been done and yielded an aver-age strength of 3050 psi, considerably higher than Portland cement mortars (Type IV and V). This promising technology provides the benefits of construction material similar to concrete, with a low complexity, low energy synthesis process and the likelihood of complete reusability of precious resources. Compressive strength using this method can be improved by increasing the surface area of the particles, using bi-modal particle size distribution, and adding certain additives to increase inter-particle forces.

Physics of Granular Materials: Investigations in Support of Astrobiology

NASA Technical Reports Server (NTRS)

Marshall, John R.

2002-01-01

This publication list is submitted as a summary of the work conducted under Cooperative Agreement 1120. The goal of the 1120 research was to study granular materials within a planetary, astrophysical, and astrobiological context. This involved research on the physical, mechanical and electrostatic properties of granular systems, as well as the examination of these materials with atomic force microscopy and x-ray analysis. Instruments for analyzing said materials in planetary environments were developed, including the MECA (Mars Environment Compatibility Assessment) experiment for the MSP '01 lander, the ECHOS/MATADOR experiment for the MSP '03 lander, an ISRU experiment for the '03 lander, and MiniLEAP technology. Flight experiments for microgravity (Space Station and Shuttle) have also been developed for the study of granular materials. As expressed in the publications, work on 1120 encompassed laboratory research, theoretical modeling, field experiments, and flight experiments: a series of successful new models were developed for understanding the behavior of triboelectrostatically charged granular masses, and 4 separate instruments were selected for space flight. No inventions or patents were generated by the research under this Agreement.

The behavior of a macroscopic granular material in vortex flow

NASA Astrophysics Data System (ADS)

Nishikawa, Asami

A granular material is defined as a collection of discrete particles such as powder and grain. Granular materials display a large number of complex behaviors. In this project, the behavior of macroscopic granular materials under tornado-like vortex airflow, with varying airflow velocity, was observed and studied. The experimental system was composed of a 9.20-cm inner diameter acrylic pipe with a metal mesh bottom holding the particles, a PVC duct, and an airflow source controlled by a variable auto-transformer, and a power-meter. A fixed fan blade was attached to the duct's inner wall to create a tornado-like vortex airflow from straight flow. As the airflow velocity was increased gradually, the behavior of a set of same-diameter granular materials was observed. The observed behaviors were classified into six phases based on the macroscopic mechanical dynamics. Through this project, we gained insights on the significant parameters for a computer simulation of a similar system by Heath Rice [5]. Comparing computationally and experimentally observed phase diagrams, we can see similar structure. The experimental observations showed the effect of initial arrangement of particles on the phase transitions.

Shock Wave Propagation in Cementitious Materials at Micro/Meso Scales

DTIC Science & Technology

2015-08-31

ABSTRACT 16. SECURITY CLASSIFICATION OF: Shock wave response of heterogeneous materials like cement and concrete is greatly influenced by the...constituents and their statistical distributions. The microstructure of cement is complex due to the presence of unhydrated water, nano /micro pores, and other...heterogeneous materials like cement and concrete is greatly influenced by the constituents and their statistical distributions. The microstructure of cement

Physical characteristics, antimicrobial and odontogenesis potentials of calcium silicate cement containing hinokitiol.

PubMed

Huang, Ming-Hsien; Shen, Yu-Fang; Hsu, Tuan-Ti; Huang, Tsui-Hsien; Shie, Ming-You

2016-08-01

Hinokitiol is a natural material and it has antibacterial and anti-inflammatory effects. The purpose of this study was to evaluate the material characterization, cell viability, antibacterial and anti-inflammatory abilities of the hinokitiol-modified calcium silicate (CS) cement as a root end filling material. The setting times, diametral tensile strength (DTS) values and XRD patterns of CS cements with 0-10mM hinokitiol were examined. Then, the antibacterial effect and the expression levels of cyclooxygenase 2 (COX-2) and interleukin-1 (IL-1) of the hinokitiol-modified CS cements were evaluated. Furthermore, the cytocompatibility, the expression levels of the markers of odontoblastic differentiation, mineralized nodule formation and calcium deposition of human dental pulp cells (hDPCs) cultured on hinokitiol-modified CS cements were determined. The hinokitiol-modified CS cements had better antibacterial and anti-inflammatory abilities and cytocompatibility than non-modified CS cements. Otherwise, the hinokitiol-modified CS cements had suitable setting times and better odontoblastic potential of hDPCs. Previous report pointed out that the root-end filling materials may induce inflammatory cytokines reaction. In our study, hinokitiol-modified CS cements not only inhibited the expression level of inflammatory cytokines, but also had better cytocompatibility, antimicrobial properties and active ability of odontoblastic differentiation of hDPCs. Therefore, the hinokitiol-modified CS cement may be a potential root end filling material for clinic. Copyright © 2016 Elsevier B.V. All rights reserved.

Invited Article: Refractive index matched scanning of dense granular materials

NASA Astrophysics Data System (ADS)

Dijksman, Joshua A.; Rietz, Frank; Lőrincz, Kinga A.; van Hecke, Martin; Losert, Wolfgang

2012-01-01

We review an experimental method that allows to probe the time-dependent structure of fully three-dimensional densely packed granular materials and suspensions by means of particle recognition. The method relies on submersing a granular medium in a refractive index matched fluid. This makes the resulting suspension transparent. The granular medium is then visualized by exciting, layer by layer, the fluorescent dye in the fluid phase. We collect references and unreported experimental know-how to provide a solid background for future development of the technique, both for new and experienced users.

Using Advanced Computing in Applied Dynamics: From the Dynamics of Granular Material to the Motion of the Mars Rover

DTIC Science & Technology

2013-08-26

USING ADVANCED COMPUTING IN APPLIED DYNAMICS : FROM THE DYNAMICS OF GRANULAR MATERIAL TO THE MOTION OF THE MARS ROVER Dan Negrut NVIDIA CUDA...USING ADVANCED COMPUTING IN APPLIED DYNAMICS : FROM THE DYNAMICS OF GRANULAR MATERIAL TO THE MOTION OF THE MARS ROVER 5a. CONTRACT NUMBER W911NF-11-F...University of Parma, Italy • Drs. Paramsothy Jayakumar & David Lamb, US Army TARDEC • Mihai Anitescu, University of Chicago & Argonne National Lab

Comparative study on strength properties of cement mortar by partial replacement of cement with ceramic powder and silica fume

NASA Astrophysics Data System (ADS)

Himabindu, Ch.; Geethasri, Ch.; Hari, N.

2018-05-01

Cement mortar is a mixture of cement and sand. Usage of high amount of cement increases the consumption of natural resources and electric power. To overcome this problem we need to replace cement with some other material. Cement is replaced with many other materials like ceramic powder, silica fume, fly ash, granulated blast furnace slag, metakaolin etc.. In this research cement is replaced with ceramic powder and silica fume. Different combinations of ceramic powder and silica fume in cement were replaced. Cement mortar cubes of 1:3 grade were prepared. These cubes were cured under normal water for 7 days, 14days and 28 days. Compressive strength test was conducted for all mixes of cement mortar cubes.

Slide Conveying of Granular Materials-Thinking Out of the Glovebox

NASA Technical Reports Server (NTRS)

Goddard, J. D.; Didwania, A. K.; Nott, P. R.

2000-01-01

The vibratory conveyor, routinely employed for normal-gravity transport of granular materials, usually consists of a continuous open trough vibrated sinusoidally to induce axial movement of a granular material. Motivated in part by a hypothetical application in zero gravity, we propose a novel modification of the vibratory conveyor based on a closed 2d trough operating in a "slide-conveying" mode, with the granular mass remaining permanently in contact with the trough walls. We present a detailed analysis of the mechanics of transport, based on a rigid-slab model for the granular mass with frictional (Coulomb) slip at the upper and lower walls. The form of the vibration cycle plays a crucial role, and the optimal conveying cycle is not the commonly assumed rectilinear sinusoidal motion. The conveying efficiency for the novel slide conveyor will be presented for several simple vibration cycles, including one believed to represent the theoretical optimum.

Effects of granular charge on flow and mixing

NASA Astrophysics Data System (ADS)

Shinbrot, T.; Herrmann, H. J.

2008-12-01

Sandstorms in the desert have long been reported to produce sparks and other electrical disturbances - indeed as long ago as 1850, Faraday commented on the peculiarities of granular charging during desert sandstorms. Similarly, lightning strikes within volcanic dust plumes have been repeatedly reported for over half a century, but remain unexplained. The problem of granular charging has applied, as well as natural, implications, for charged particle clouds frequently generate spectacularly devastating dust explosions in granular processing plants, and sand becomes strongly electrified by helicopters traveling in desert environments. The issue even has implications for missions to the Moon and to Mars, where charged dust degrades solar cells viability and clings to spacesuits, limiting the lifetime of their joints. Despite the wide-ranging importance of granular charging, even the simplest aspects of its causes remain elusive. To take one example, sand grains in the desert manage to charge one another despite having only similar materials to rub against over expanses of many miles - thus existing theories of charging due to material differences fail entirely to account for the observed charging of desert sands. In this talk, we describe recent progress made in identifying underlying causes of granular charging, both in desert-like environments and in industrial applications, and we examine effects of granular charging on flow, mixing and separation of common granular materials. We find that charging of identical grains can occur under simple laboratory conditions, and we make new predictions for the effects of this charging on granular behaviours.

Evaluation of geofabric in undercut on MSE wall stability : executive summary report.

DOT National Transportation Integrated Search

2011-05-01

Compaction of granular base materials at sites with fine grained native soils often causes unwanted material loss due to penetration. In 2007, ODOT began placing geofabrics in the undercut of MSE walls at the soil/ granular material interface to faci...

DEM modeling of flexible structures against granular material avalanches

NASA Astrophysics Data System (ADS)

Lambert, Stéphane; Albaba, Adel; Nicot, François; Chareyre, Bruno

2016-04-01

This article presents the numerical modeling of flexible structures intended to contain avalanches of granular and coarse material (e.g. rock slide, a debris slide). The numerical model is based on a discrete element method (YADE-Dem). The DEM modeling of both the flowing granular material and the flexible structure are detailed before presenting some results. The flowing material consists of a dry polydisperse granular material accounting for the non-sphericity of real materials. The flexible structure consists in a metallic net hanged on main cables, connected to the ground via anchors, on both sides of the channel, including dissipators. All these components were modeled as flexible beams or wires, with mechanical parameters defined from literature data. The simulation results are presented with the aim of investigating the variability of the structure response depending on different parameters related to the structure (inclination of the fence, with/without brakes, mesh size opening), but also to the channel (inclination). Results are then compared with existing recommendations in similar fields.

Measurements of the frame acoustic properties of porous and granular materials

NASA Astrophysics Data System (ADS)

Park, Junhong

2005-12-01

For porous and granular materials, the dynamic characteristics of the solid component (frame) are important design factors that significantly affect the material's acoustic properties. The primary goal of this study was to present an experimental method for measuring the vibration characteristics of this frame. The experimental setup was designed to induce controlled vibration of the solid component while minimizing the influence from coupling between vibrations of the fluid and the solid component. The Biot theory was used to verify this assumption, taking the two dilatational wave propagations and interactions into account. The experimental method was applied to measure the dynamic properties of glass spheres, lightweight microspheres, acoustic foams, and fiberglass. A continuous variation of the frame vibration characteristics with frequency similar to that of typical viscoelastic materials was measured. The vibration amplitude had minimal effects on the dynamic characteristics of the porous material compared to those of the granular material. For the granular material, materials comprised of larger particles and those under larger vibration amplitudes exhibited lower frame wave speeds and larger decay rates.

Advances in the simulation and automated measurement of well-sorted granular material: 2. Direct measures of particle properties

USGS Publications Warehouse

Buscombe, Daniel D.; Rubin, David M.

2012-01-01

1. In this, the second of a pair of papers on the structure of well-sorted natural granular material (sediment), new methods are described for automated measurements from images of sediment, of: 1) particle-size standard deviation (arithmetic sorting) with and without apparent void fraction; and 2) mean particle size in material with void fraction. A variety of simulations of granular material are used for testing purposes, in addition to images of natural sediment. Simulations are also used to establish that the effects on automated particle sizing of grains visible through the interstices of the grains at the very surface of a granular material continue to a depth of approximately 4 grain diameters and that this is independent of mean particle size. Ensemble root-mean squared error between observed and estimated arithmetic sorting coefficients for 262 images of natural silts, sands and gravels (drawn from 8 populations) is 31%, which reduces to 27% if adjusted for bias (slope correction between observed and estimated values). These methods allow non-intrusive and fully automated measurements of surfaces of unconsolidated granular material. With no tunable parameters or empirically derived coefficients, they should be broadly universal in appropriate applications. However, empirical corrections may need to be applied for the most accurate results. Finally, analytical formulas are derived for the one-step pore-particle transition probability matrix, estimated from the image's autocorrelogram, from which void fraction of a section of granular material can be estimated directly. This model gives excellent predictions of bulk void fraction yet imperfect predictions of pore-particle transitions.

Advances in the simulation and automated measurement of well-sorted granular material: 2. Direct measures of particle properties

NASA Astrophysics Data System (ADS)

Buscombe, D.; Rubin, D. M.

2012-06-01

In this, the second of a pair of papers on the structure of well-sorted natural granular material (sediment), new methods are described for automated measurements from images of sediment, of: 1) particle-size standard deviation (arithmetic sorting) with and without apparent void fraction; and 2) mean particle size in material with void fraction. A variety of simulations of granular material are used for testing purposes, in addition to images of natural sediment. Simulations are also used to establish that the effects on automated particle sizing of grains visible through the interstices of the grains at the very surface of a granular material continue to a depth of approximately 4 grain diameters and that this is independent of mean particle size. Ensemble root-mean squared error between observed and estimated arithmetic sorting coefficients for 262 images of natural silts, sands and gravels (drawn from 8 populations) is 31%, which reduces to 27% if adjusted for bias (slope correction between observed and estimated values). These methods allow non-intrusive and fully automated measurements of surfaces of unconsolidated granular material. With no tunable parameters or empirically derived coefficients, they should be broadly universal in appropriate applications. However, empirical corrections may need to be applied for the most accurate results. Finally, analytical formulas are derived for the one-step pore-particle transition probability matrix, estimated from the image's autocorrelogram, from which void fraction of a section of granular material can be estimated directly. This model gives excellent predictions of bulk void fraction yet imperfect predictions of pore-particle transitions.

Experimental Investigation of Multi-mode Fiber Laser Cutting of Cement Mortar.

PubMed

Lee, Dongkyoung; Pyo, Sukhoon

2018-02-10

This study successfully applied multi-mode laser cutting with the variation of the laser cutting speed to cement mortar for the first time. The effects of the amount of silica sand in the cement mortar on laser cutting are tested and analyzed. The kerf width and penetration depth of the specimens after laser cutting are investigated. As the laser cutting speed increases, the penetration depth decreases for both cement paste and cement mortar, whereas the kerf width becomes saturated and increases, respectively, for cement paste and cement mortar. Cross sections of the specimens are compared with illustrations. Top-view images of the cement mortar with indicators of the physical characteristics, such as re-solidification, burning, and cracks are examined, and the possible causes of these characteristics are explained. The optical absorption rates of cement-based materials are quantified at wide ranges of wavelength to compare the absorption rates in accordance with the materials compositions. The chemical composition variation before and after laser cutting is also compared by EDX (Energy Dispersive X-Ray) analysis. In addition to these observations, material removal mechanisms for cement mortar are proposed.

Experimental Investigation of Multi-mode Fiber Laser Cutting of Cement Mortar

PubMed Central

2018-01-01

This study successfully applied multi-mode laser cutting with the variation of the laser cutting speed to cement mortar for the first time. The effects of the amount of silica sand in the cement mortar on laser cutting are tested and analyzed. The kerf width and penetration depth of the specimens after laser cutting are investigated. As the laser cutting speed increases, the penetration depth decreases for both cement paste and cement mortar, whereas the kerf width becomes saturated and increases, respectively, for cement paste and cement mortar. Cross sections of the specimens are compared with illustrations. Top-view images of the cement mortar with indicators of the physical characteristics, such as re-solidification, burning, and cracks are examined, and the possible causes of these characteristics are explained. The optical absorption rates of cement-based materials are quantified at wide ranges of wavelength to compare the absorption rates in accordance with the materials compositions. The chemical composition variation before and after laser cutting is also compared by EDX (Energy Dispersive X-Ray) analysis. In addition to these observations, material removal mechanisms for cement mortar are proposed. PMID:29439431

Compatibility improvement method of empty fruit bunch fibre as a replacement material in cement bonded boards: A review

NASA Astrophysics Data System (ADS)

Dullah, Hayana; Abidin Akasah, Zainal; Zaini Nik Soh, Nik Mohd; Mangi, Sajjad Ali

2017-11-01

The utilization of oil palm empty fruit bunch (OPEFB) fibre on bio-composite product has been introduced to replace current material mainly wood fibre. OPEFB is widely available as palm oil is one of the major agricultural crops in Malaysia. EFB fibre are lignocellulosic materials that could replace other natural fibre product especially cement bonded board. However, the contains of residual oil and sugar in EFB fibre has been detected to be the reason for incompatibility issue between EFB fibre and cement mixtures. Regarding on the issue, a study has been conducted widely on finding the suitable pre-treatment method for EFB fibre to remove carbohydrate contained in the said fibre that are known to inhibit cement hydration. Aside from that, cement accelerator was introduced to enhance the hydration of cement when it was mixed with natural fibre. Hence, this paper will summaries the previous findings and in-depth study on the use of EFB fibre as a replacement material in cement bonded fibre boards.

Rational Selection of Tailored Amendment Mixtures and Composites for In Situ Remediation of Contaminated Sediments

DTIC Science & Technology

2008-12-01

Certification Program GAC granular activated carbon HGR sulfur impregnated activated carbon MCA Menzie Cura and Associates MRM Minimum Required...determination of iodine number was followed. The materials tested were granular activated carbon (GAC), alumina powder, ATS, apatite, bentonite, barite...materials tested were granular activated carbon (GAC), alumina powder, ATS, apatite, bentonite, barite, ConSep 20 and 42%, and ATC. The Iodine Number

Mechanics of Granular Materials (MGM)

NASA Technical Reports Server (NTRS)

Alshibli, Khalid A.; Costes, Nicholas C.; Porter, Ronald F.

1996-01-01

The constitutive behavior of uncemented granular materials such as strength, stiffness, and localization of deformations are to a large extend derived from interparticle friction transmitted between solid particles and particle groups. Interparticle forces are highly dependent on gravitational body forces. At very low effective confining pressures, the true nature of the Mohr envelope, which defines the Mohr-Coulomb failure criterion for soils, as well as the relative contribution of each of non-frictional components to soil's shear strength cannot be evaluated in terrestrial laboratories. Because of the impossibility of eliminating gravitational body forces on earth, the weight of soil grains develops interparticle compressive stresses which mask true soil constitutive behavior even in the smallest samples of models. Therefore the microgravity environment induced by near-earth orbits of spacecraft provides unique experimental opportunities for testing theories related to the mechanical behavior of terrestrial granular materials. Such materials may include cohesionless soils, industrial powders, crushed coal, etc. This paper will describe the microgravity experiment, 'Mechanics of Granular Materials (MGM)', scheduled to be flown on Space Shuttle-MIR missions. The paper will describe the experiment's hardware, instrumentation, specimen preparation procedures, testing procedures in flight, as well as a brief summary of the post-mission analysis. It is expected that the experimental results will significantly improve the understanding of the behavior of granular materials under very low effective stress levels.

Granular Material Scoop and Near-Vertical Lifting Feeder/Conveyor

NASA Technical Reports Server (NTRS)

Walton, Otis (Inventor); Vollmer, Hubert J. (Inventor)

2017-01-01

An integrated granular-material scoop and near-vertical lifting feeder/conveyor includes special connections and skirts between a bullnose rotating scoop and an open-helical screw that provides the rotations and material lift and evacuation. A conical working-face of the bullnose rotating scoop has symmetrically distributed graters and vents to break loose and force-in granular material from natural deposits and cargo holds. The bullnose rotating scoop and the open-helical screw its attached to move the material into a continuous layer on the inside surface of an outer stationary sheathing. A motor drive attached to the open-helical screw above at the delivery end provides the lifting force necessary.

Granular crystals: Nonlinear dynamics meets materials engineering

DOE PAGES

Porter, Mason A.; Kevrekidis, Panayotis G.; Daraio, Chiara

2015-11-01

In this article, the freedom to choose the size, stiffness, and spatial distribution of macroscopic particles in a lattice makes granular crystals easily tailored building blocks for shock-absorbing materials, sound-focusing devices, acoustic switches, and other exotica.

Phosphate-bonded calcium aluminate cements

DOEpatents

Sugama, Toshifumi

1993-01-01

A method is described for making a rapid-setting phosphate-bonded cementitious material. A powdered aluminous cement is mixed with an aqueous solution of ammonium phosphate. The mixture is allowed to set to form an amorphous cementitious material which also may be hydrothermally treated at a temperature of from about 120.degree. C. to about 300.degree. C. to form a crystal-containing phosphate-bonded material. Also described are the cementitious products of this method and the cement composition which includes aluminous cement and ammonium polyphosphate.

Phosphate-bonded calcium aluminate cements

DOEpatents

Sugama, T.

1993-09-21

A method is described for making a rapid-setting phosphate-bonded cementitious material. A powdered aluminous cement is mixed with an aqueous solution of ammonium phosphate. The mixture is allowed to set to form an amorphous cementitious material which also may be hydrothermally treated at a temperature of from about 120 C to about 300 C to form a crystal-containing phosphate-bonded material. Also described are the cementitious products of this method and the cement composition which includes aluminous cement and ammonium polyphosphate. 10 figures.

Implicit continuum mechanics approach to heat conduction in granular materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Massoudi, M.; Mehrabadi, M.

In this paper, we derive a properly frame-invariant implicit constitutive relationship for the heat flux vector for a granular medium (or a density-gradient-type fluid). The heat flux vector is commonly modeled by Fourier’s law of heat conduction, and for complex materials such as nonlinear fluids, porous media, or granular materials, the coefficient of thermal conductivity is generalized by assuming that it would depend on a host of material and kinematic parameters such as temperature, shear rate, porosity, concentration, etc. In this paper, we extend the approach of Massoudi [Massoudi, M. Math. Methods Appl. Sci. 2006, 29, 1585; Massoudi, M. Math.more » Methods Appl. Sci. 2006, 29, 1599], who provided explicit constitutive relations for the heat flux vector for flowing granular materials; in order to do so, we use the implicit scheme suggested by Fox [Fox, N. Int. J. Eng. Sci. 1969, 7, 437], who obtained implicit relations in thermoelasticity.« less

The behavior of biogenic silica-rich rocks and volcanic tuffs as pozzolanic additives in cement

NASA Astrophysics Data System (ADS)

Fragoulis, Dimitris; Stamatakis, Michael; Anastasatou, Marianthi

2015-04-01

Cements currently produced, include a variety of pozzolanic materials, aiming for lower clinker addition and utilization of vast deposits of certain raw materials and/or mining wastes and byproducts. The major naturally occurring pozzolanic materials include glassy tuffs, zeolitic tuffs, diatomites and volcanic lavas rich in glassy phase, such as perlites. Therefore, based on the available raw materials in different locations, the cement composition might vary according to the accessibility of efficient pozzolanic materials. In the present investigation, the behavior of pozzolanic cements produced with representative samples of the aforementioned materials was studied, following the characterization of the implemented pozzolanas with respect to their chemical and mineralogical characteristics. Laboratory cements were produced by co-grinding 75% clinker, 5% gypsum and 20% pozzolana, for the same period of time (45 min). Regarding pozzolanic materials, four different types of pozzolanas were utilized namely, diatomite, perlite, zeolite tuff and glassy tuff. More specifically, two diatomite samples originated from Australia and Greece, with high and low reactive silica content respectively, two perlite samples originated from Turkey and from Milos Island, Greece, with different reactive silica contents, a zeolite tuff sample originated from Turkey and a glassy tuff sample originated from Milos Island, Greece. The above pozzolana samples, which were ground in the laboratory ball mill for cement production performed differently during grinding and that was reflected upon the specific surface area (cm2/gr) values. The perlites and the glassy tuff were the hardest to grind, whereas, the zeolite tuff and the Australian diatomite were the easiest ones. However, the exceedingly high specific surface area of the Australian diatomite renders cement difficult to transport and tricky to use for concrete manufacturing, due to the high water demand of the cement mixture. Regarding late compressive strength, the worst performing cement was the one with the lowest reactive silica content with biogenic opal-A as the only reactive pozzolana constituent. Cements produced with perlites, raw materials consisting mainly of a glassy phase, were characterized by higher strength and a rather ordinary specific surface area. Cements produced with Turkish zeolite tuff and Milos glassy tuff exhibited higher late compressive strength than those mentioned above. The highest strength was achieved by the implementation of Australian diatomite for cement production. Its 28 day strength exceeded that of the control mixture consisting of 95% clinker and 5% gypsum. That could be attributed to both, high specific surface of cement and reactive SiO2 of diatomite. Therefore, a preliminary assessment regarding late strength of pozzolanic cements could be obtained by the consideration of two main parameters, namely: specific surface area of cement and reactive silica content of pozzolana.

Utilization of Palm Oil Clinker as Cement Replacement Material

PubMed Central

Kanadasan, Jegathish; Abdul Razak, Hashim

2015-01-01

The utilization of waste materials from the palm oil industry provides immense benefit to various sectors of the construction industry. Palm oil clinker is a by-product from the processing stages of palm oil goods. Channelling this waste material into the building industry helps to promote sustainability besides overcoming waste disposal problems. Environmental pollution due to inappropriate waste management system can also be drastically reduced. In this study, cement was substituted with palm oil clinker powder as a binder material in self-compacting mortar. The fresh, hardened and microstructure properties were evaluated throughout this study. In addition, sustainability component analysis was also carried out to assess the environmental impact of introducing palm oil clinker powder as a replacement material for cement. It can be inferred that approximately 3.3% of cement production can be saved by substituting palm oil clinker powder with cement. Reducing the utilization of cement through a high substitution level of this waste material will also help to reduce carbon emissions by 52%. A cleaner environment free from pollutants can be created to ensure healthier living. Certain industries may benefit through the inclusion of this waste material as the cost and energy consumption of the product can be minimized. PMID:28793748

Utilization of Palm Oil Clinker as Cement Replacement Material.

PubMed

Kanadasan, Jegathish; Abdul Razak, Hashim

2015-12-16

The utilization of waste materials from the palm oil industry provides immense benefit to various sectors of the construction industry. Palm oil clinker is a by-product from the processing stages of palm oil goods. Channelling this waste material into the building industry helps to promote sustainability besides overcoming waste disposal problems. Environmental pollution due to inappropriate waste management system can also be drastically reduced. In this study, cement was substituted with palm oil clinker powder as a binder material in self-compacting mortar. The fresh, hardened and microstructure properties were evaluated throughout this study. In addition, sustainability component analysis was also carried out to assess the environmental impact of introducing palm oil clinker powder as a replacement material for cement. It can be inferred that approximately 3.3% of cement production can be saved by substituting palm oil clinker powder with cement. Reducing the utilization of cement through a high substitution level of this waste material will also help to reduce carbon emissions by 52%. A cleaner environment free from pollutants can be created to ensure healthier living. Certain industries may benefit through the inclusion of this waste material as the cost and energy consumption of the product can be minimized.

Consideration of reinforcement mechanism in the short fiber mixing granular materials by granular element simulations

NASA Astrophysics Data System (ADS)

Mori, Kentaro; Kaneko, Kenji; Hashizume, Yutaka

2017-06-01

The short fiber mixing method is well known as one of the method to improve the strength of gran- ular soils in geotechnical engineering. Mechanical properties of the short fiber mixing granular materials are influenced by many factors, such as the mixture ratio of the short fiber, the material of short fiber, the length, and the orientation. In particular, the mixture ratio of the short fibers is very important in mixture design. In the past study, we understood that the strength is reduced by too much short fiber mixing by a series of tri-axial compression experiments. Namely, there is "optimum mixture ratio" in the short fiber mixing granular soils. In this study, to consider the mechanism of occurrence of the optimum mixture ratio, we carried out the numerical experiments by granular element method. As the results, we can understand that the strength decrease when too much grain-fiber contact points exist, because a friction coefficient is smaller than the grain-grain contact points.

How mobile are protons in the structure of dental glass ionomer cements?

PubMed Central

Benetti, Ana R.; Jacobsen, Johan; Lehnhoff, Benedict; Momsen, Niels C. R.; Okhrimenko, Denis V.; Telling, Mark T. F.; Kardjilov, Nikolay; Strobl, Markus; Seydel, Tilo; Manke, Ingo; Bordallo, Heloisa N.

2015-01-01

The development of dental materials with improved properties and increased longevity can save costs and minimize discomfort for patients. Due to their good biocompatibility, glass ionomer cements are an interesting restorative option. However, these cements have limited mechanical strength to survive in the challenging oral environment. Therefore, a better understanding of the structure and hydration process of these cements can bring the necessary understanding to further developments. Neutrons and X-rays have been used to investigate the highly complex pore structure, as well as to assess the hydrogen mobility within these cements. Our findings suggest that the lower mechanical strength in glass ionomer cements results not only from the presence of pores, but also from the increased hydrogen mobility within the material. The relationship between microstructure, hydrogen mobility and strength brings insights into the material's durability, also demonstrating the need and opening the possibility for further research in these dental cements. PMID:25754555

The effect of different surfactants/plastisizers on the electrical behavior of CNT nano-modified cement mortars

NASA Astrophysics Data System (ADS)

Dalla, P. T.; Alafogianni, P.; Tragazikis, I. K.; Exarchos, D. A.; Dassios, K.; Barkoula, N.-M.; Matikas, T. E.

2015-03-01

Cement-based materials have in general low electrical conductivity. Electrical conductivity is the measure of the ability of the material to resist the passage of electrical current. The addition of a conductive admixture such as Multi-Walled Carbon Nanotubes (MWCNTs) in a cement-based material increases the conductivity of the structure. This research aims to characterize nano-modified cement mortars with MWCNT reinforcements. Such nano-composites would possess smartness and multi-functionality. Multifunctional properties include electrical, thermal and piezo-electric characteristics. One of these properties, the electrical conductivity, was measured using a custom made apparatus that allows application of known D.C. voltage on the nano-composite. In this study, the influence of different surfactants/plasticizers on CNT nano-modified cement mortar specimens with various concentrations of CNTs (0.2% wt. cement CNTs - 0.8% wt. cement CNTs) on the electrical conductivity is assessed.

How mobile are protons in the structure of dental glass ionomer cements?

NASA Astrophysics Data System (ADS)

Benetti, Ana R.; Jacobsen, Johan; Lehnhoff, Benedict; Momsen, Niels C. R.; Okhrimenko, Denis V.; Telling, Mark T. F.; Kardjilov, Nikolay; Strobl, Markus; Seydel, Tilo; Manke, Ingo; Bordallo, Heloisa N.

2015-03-01

The development of dental materials with improved properties and increased longevity can save costs and minimize discomfort for patients. Due to their good biocompatibility, glass ionomer cements are an interesting restorative option. However, these cements have limited mechanical strength to survive in the challenging oral environment. Therefore, a better understanding of the structure and hydration process of these cements can bring the necessary understanding to further developments. Neutrons and X-rays have been used to investigate the highly complex pore structure, as well as to assess the hydrogen mobility within these cements. Our findings suggest that the lower mechanical strength in glass ionomer cements results not only from the presence of pores, but also from the increased hydrogen mobility within the material. The relationship between microstructure, hydrogen mobility and strength brings insights into the material's durability, also demonstrating the need and opening the possibility for further research in these dental cements.

An in vitro atomic force microscopic study of commercially available dental luting materials.

PubMed

Djordje, Antonijevic; Denis, Brajkovic; Nenadovic, Milos; Petar, Milovanovic; Marija, Djuric; Zlatko, Rakocevic

2013-09-01

The aim of this in vitro study was to compare the surface roughness parameters of four different types of dental luting agents used for cementation of implant restorations. Five specimens (8 mm high and 1 mm thick) of each cement were made using metal ring steelless molds. Atomic Force Microscope was employed to analyze different surface texture parameters of the materials. Bearing ratio analysis was used to calculate the potential microgap size between the cement and implant material and to calculate the depth of the valleys on the cement surface, while power spectral density (PSD) measurements were performed to measure the percentage of the surface prone to bacterial adhesion. Glass ionomer cement showed significantly lower value of average surface roughness then the other groups of the materials (P < 0.05) which was in line with the results of Bearing ratio analysis. On the other side, PSD analysis showed that zinc phosphate cement experience the lowest percentage of the surface which promote bacterial colonization. Glas ionomer cements present the surface roughness parameters that are less favorable for bacterial adhesion than that of zinc phosphate, resin-modified glass ionomer and resin cements. Copyright © 2013 Wiley Periodicals, Inc.

Thermophysical and Mechanical Properties of Hardened Cement Paste with Microencapsulated Phase Change Materials for Energy Storage.

PubMed

Cui, Hongzhi; Liao, Wenyu; Memon, Shazim Ali; Dong, Biqin; Tang, Waiching

2014-12-16

In this research, structural-functional integrated cement-based materials were prepared by employing cement paste and a microencapsulated phase change material (MPCM) manufactured using urea-formaldehyde resin as the shell and paraffin as the core material. The encapsulation ratio of the MPCM could reach up to 91.21 wt%. Thermal energy storage cement pastes (TESCPs) incorporated with different MPCM contents (5%, 10%, 15%, 20% and 25% by weight of cement) were developed, and their thermal and mechanical properties were studied. The results showed that the total energy storage capacity of the hardened cement specimens with MPCM increased by up to 3.9-times compared with that of the control cement paste. The thermal conductivity at different temperature levels (35-36 °C, 55-56 °C and 72-74 °C) decreased with the increase of MPCM content, and the decrease was the highest when the temperature level was 55-56 °C. Moreover, the compressive strength, flexural strength and density of hardened cement paste decreased with the increase in MPCM content linearly. Among the evaluated properties, the compressive strength of TESCPs had a larger and faster degradation with the increase of MPCM content.

Color change of CAD-CAM materials and composite resin cements after thermocycling.

PubMed

Gürdal, Isil; Atay, Ayse; Eichberger, Marlis; Cal, Ebru; Üsümez, Aslihan; Stawarczyk, Bogna

2018-04-24

The color of resin cements and computer-aided-design and computer-aided-manufacturing (CAD-CAM) restorations may change with aging. The purpose of this in vitro study was to analyze the influence of thermocycling on the color of CAD-CAM materials with underlying resin cement. Seven different CAD-CAM materials, composite resins and glass-ceramics were cut into 0.7-mm and 1.2-mm thicknesses (n=10) and cemented with a dual-polymerizing resin cement, a light-polymerizing resin cement, and a preheated composite resin (N=420). Color values were measured by using spectrophotometry. Specimens were subjected to thermocycling (5°C and 55°C; 5000 cycles). The measured color difference (ΔE) data were analyzed by using descriptive statistics. Normality of data distribution was tested by using the Kolmogorov-Smirnov test. Three-way and 1-way ANOVA followed by the Scheffé post-hoc test and unpaired 2-sample Student t test were computed to determine the significant differences among the tested parameters (α=.05). ΔE values were significantly influenced by the CAD-CAM material (η p 2 =0.85, P<.001) and the resin composite cement (η P 2 =0.03, P=.003) but were not influenced by thickness (P=.179). Significant interactions were present among thickness, cement, and CAD-CAM materials (P<.001). Vita Suprinity and GC Cerasmart showed significantly the lowest ΔE values (P<.001). The highest ΔE values were observed for IPS Empress CAD. The dual-polymerizing resin cement showed significantly lower ΔE values than the preheated composite resin (P=.003). Restoration materials and composite resin cement types used for cementation influence the amount of color change due to aging. Copyright © 2018 Editorial Council for the Journal of Prosthetic Dentistry. Published by Elsevier Inc. All rights reserved.

Force Transmission Modes of Non-Cohesive and Cohesive Materials at the Critical State.

PubMed

Wang, Ji-Peng

2017-08-31

This paper investigates the force transmission modes, mainly described by probability density distributions, in non-cohesive dry and cohesive wet granular materials by discrete element modeling. The critical state force transmission patterns are focused on with the contact model effect being analyzed. By shearing relatively dense and loose dry specimens to the critical state in the conventional triaxial loading path, it is observed that there is a unique critical state force transmission mode. There is a universe critical state force distribution pattern for both the normal contact forces and tangential contact forces. Furthermore, it is found that using either the linear Hooke or the non-linear Hertz model does not affect the universe force transmission mode, and it is only related to the grain size distribution. Wet granular materials are also simulated by incorporating a water bridge model. Dense and loose wet granular materials are tested, and the critical state behavior for the wet material is also observed. The critical state strength and void ratio of wet granular materials are higher than those of a non-cohesive material. The critical state inter-particle distribution is altered from that of a non-cohesive material with higher probability in relatively weak forces. Grains in non-cohesive materials are under compressive stresses, and their principal directions are mainly in the axial loading direction. However, for cohesive wet granular materials, some particles are in tension, and the tensile stresses are in the horizontal direction on which the confinement is applied. The additional confinement by the tensile stress explains the macro strength and dilatancy increase in wet samples.

Force Transmission Modes of Non-Cohesive and Cohesive Materials at the Critical State

PubMed Central

2017-01-01

This paper investigates the force transmission modes, mainly described by probability density distributions, in non-cohesive dry and cohesive wet granular materials by discrete element modeling. The critical state force transmission patterns are focused on with the contact model effect being analyzed. By shearing relatively dense and loose dry specimens to the critical state in the conventional triaxial loading path, it is observed that there is a unique critical state force transmission mode. There is a universe critical state force distribution pattern for both the normal contact forces and tangential contact forces. Furthermore, it is found that using either the linear Hooke or the non-linear Hertz model does not affect the universe force transmission mode, and it is only related to the grain size distribution. Wet granular materials are also simulated by incorporating a water bridge model. Dense and loose wet granular materials are tested, and the critical state behavior for the wet material is also observed. The critical state strength and void ratio of wet granular materials are higher than those of a non-cohesive material. The critical state inter-particle distribution is altered from that of a non-cohesive material with higher probability in relatively weak forces. Grains in non-cohesive materials are under compressive stresses, and their principal directions are mainly in the axial loading direction. However, for cohesive wet granular materials, some particles are in tension, and the tensile stresses are in the horizontal direction on which the confinement is applied. The additional confinement by the tensile stress explains the macro strength and dilatancy increase in wet samples. PMID:28858238

Terminal velocity of liquids and granular materials dispersed by a high explosive

NASA Astrophysics Data System (ADS)

Loiseau, J.; Pontalier, Q.; Milne, A. M.; Goroshin, S.; Frost, D. L.

2018-05-01

The explosive dispersal of a layer of solid particles or a layer of liquid surrounding a spherical high-explosive charge generates a turbulent, multiphase flow. Shock compression of the material layer during the initial acceleration may partially consolidate the material, leading to the formation of jet-like structures when the layer fragments and sheds particles upon release. Similarly, release of a shock-compressed liquid shell causes the nucleation of cavitation sites, leading to the radial breakup of the shell and the formation of jets upon expansion. In the current study, a wide variety of granular materials and liquids were explosively dispersed. The maximum terminal jet tip or shell velocity was measured using high-speed videography. Charges were constructed using thin-walled glass bulbs of various diameters and contained a central C-4 charge surrounded by the material to be dispersed. This permitted variation of the ratio of material mass to charge mass ( M/ C) from 4 to 300. Results indicated that material velocity broadly correlates with predictions of the Gurney model. For liquids, the terminal velocity was accurately predicted by the Gurney model. For granular materials, Gurney over-predicted the terminal velocity by 25-60%, depending on the M/ C ratio, with larger M/ C values exhibiting larger deficits. These deficits are explained by energy dissipation during the collapse of voids in the granular material bed. Velocity deficits were insensitive to the degree of jetting and granular material properties. Empirical corrections to the Gurney model are presented with improved agreement with the dry powder experimental velocities.

Terminal velocity of liquids and granular materials dispersed by a high explosive

NASA Astrophysics Data System (ADS)

Loiseau, J.; Pontalier, Q.; Milne, A. M.; Goroshin, S.; Frost, D. L.

2018-04-01

The explosive dispersal of a layer of solid particles or a layer of liquid surrounding a spherical high-explosive charge generates a turbulent, multiphase flow. Shock compression of the material layer during the initial acceleration may partially consolidate the material, leading to the formation of jet-like structures when the layer fragments and sheds particles upon release. Similarly, release of a shock-compressed liquid shell causes the nucleation of cavitation sites, leading to the radial breakup of the shell and the formation of jets upon expansion. In the current study, a wide variety of granular materials and liquids were explosively dispersed. The maximum terminal jet tip or shell velocity was measured using high-speed videography. Charges were constructed using thin-walled glass bulbs of various diameters and contained a central C-4 charge surrounded by the material to be dispersed. This permitted variation of the ratio of material mass to charge mass (M/C) from 4 to 300. Results indicated that material velocity broadly correlates with predictions of the Gurney model. For liquids, the terminal velocity was accurately predicted by the Gurney model. For granular materials, Gurney over-predicted the terminal velocity by 25-60%, depending on the M/C ratio, with larger M/C values exhibiting larger deficits. These deficits are explained by energy dissipation during the collapse of voids in the granular material bed. Velocity deficits were insensitive to the degree of jetting and granular material properties. Empirical corrections to the Gurney model are presented with improved agreement with the dry powder experimental velocities.

Studies of elasticity, sound propagation and attenuation of acoustic modes in granular media: final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Makse, Hernan A.; Johnson, David L.

2014-09-03

This is the final report describing the results of DOE Grant # DE-FG02-03ER15458 with original termination date of April 31, 2013, which has been extended to April 31, 2014. The goal of this project is to develop a theoretical and experimental understanding of sound propagation, elasticity and dissipation in granular materials. The topic is relevant for the efficient production of hydrocarbon and for identifying and characterizing the underground formation for storage of either CO 2 or nuclear waste material. Furthermore, understanding the basic properties of acoustic propagation in granular media is of importance not only to the energy industry, butmore » also to the pharmaceutical, chemical and agricultural industries. We employ a set of experimental, theoretical and computational tools to develop a study of acoustics and dissipation in granular media. These include the concept effective mass of granular media, normal modes analysis, statistical mechanics frameworks and numerical simulations based on Discrete Element Methods. Effective mass measurements allow us to study the mechanisms of the elastic response and attenuation of acoustic modes in granular media. We perform experiments and simulations under varying conditions, including humidity and vacuum, and different interparticle force-laws to develop a fundamental understanding of the mechanisms of damping and acoustic propagation in granular media. A theoretical statistical approach studies the necessary phase space of configurations in pressure, volume fraction to classify granular materials.« less

Granular materials flow like complex fluids

NASA Astrophysics Data System (ADS)

Kou, Binquan; Cao, Yixin; Li, Jindong; Xia, Chengjie; Li, Zhifeng; Dong, Haipeng; Zhang, Ang; Zhang, Jie; Kob, Walter; Wang, Yujie

2017-11-01

Granular materials such as sand, powders and foams are ubiquitous in daily life and in industrial and geotechnical applications. These disordered systems form stable structures when unperturbed, but in the presence of external influences such as tapping or shear they `relax', becoming fluid in nature. It is often assumed that the relaxation dynamics of granular systems is similar to that of thermal glass-forming systems. However, so far it has not been possible to determine experimentally the dynamic properties of three-dimensional granular systems at the particle level. This lack of experimental data, combined with the fact that the motion of granular particles involves friction (whereas the motion of particles in thermal glass-forming systems does not), means that an accurate description of the relaxation dynamics of granular materials is lacking. Here we use X-ray tomography to determine the microscale relaxation dynamics of hard granular ellipsoids subject to an oscillatory shear. We find that the distribution of the displacements of the ellipsoids is well described by a Gumbel law (which is similar to a Gaussian distribution for small displacements but has a heavier tail for larger displacements), with a shape parameter that is independent of the amplitude of the shear strain and of the time. Despite this universality, the mean squared displacement of an individual ellipsoid follows a power law as a function of time, with an exponent that does depend on the strain amplitude and time. We argue that these results are related to microscale relaxation mechanisms that involve friction and memory effects (whereby the motion of an ellipsoid at a given point in time depends on its previous motion). Our observations demonstrate that, at the particle level, the dynamic behaviour of granular systems is qualitatively different from that of thermal glass-forming systems, and is instead more similar to that of complex fluids. We conclude that granular materials can relax even when the driving strain is weak.

Substantial global carbon uptake by cement carbonation

NASA Astrophysics Data System (ADS)

Xi, Fengming; Davis, Steven J.; Ciais, Philippe; Crawford-Brown, Douglas; Guan, Dabo; Pade, Claus; Shi, Tiemao; Syddall, Mark; Lv, Jie; Ji, Lanzhu; Bing, Longfei; Wang, Jiaoyue; Wei, Wei; Yang, Keun-Hyeok; Lagerblad, Björn; Galan, Isabel; Andrade, Carmen; Zhang, Ying; Liu, Zhu

2016-12-01

Calcination of carbonate rocks during the manufacture of cement produced 5% of global CO2 emissions from all industrial process and fossil-fuel combustion in 2013. Considerable attention has been paid to quantifying these industrial process emissions from cement production, but the natural reversal of the process--carbonation--has received little attention in carbon cycle studies. Here, we use new and existing data on cement materials during cement service life, demolition, and secondary use of concrete waste to estimate regional and global CO2 uptake between 1930 and 2013 using an analytical model describing carbonation chemistry. We find that carbonation of cement materials over their life cycle represents a large and growing net sink of CO2, increasing from 0.10 GtC yr-1 in 1998 to 0.25 GtC yr-1 in 2013. In total, we estimate that a cumulative amount of 4.5 GtC has been sequestered in carbonating cement materials from 1930 to 2013, offsetting 43% of the CO2 emissions from production of cement over the same period, not including emissions associated with fossil use during cement production. We conclude that carbonation of cement products represents a substantial carbon sink that is not currently considered in emissions inventories.

Apatite formation on bioactive calcium-silicate cements for dentistry affects surface topography and human marrow stromal cells proliferation.

PubMed

Gandolfi, Maria Giovanna; Ciapetti, Gabriela; Taddei, Paola; Perut, Francesca; Tinti, Anna; Cardoso, Marcio Vivan; Van Meerbeek, Bart; Prati, Carlo

2010-10-01

The effect of ageing in phosphate-containing solution of bioactive calcium-silicate cements on the chemistry, morphology and topography of the surface, as well as on in vitro human marrow stromal cells viability and proliferation was investigated. A calcium-silicate cement (wTC) mainly based on dicalcium-silicate and tricalcium-silicate was prepared. Alpha-TCP was added to wTC to obtain wTC-TCP. Bismuth oxide was inserted in wTC to prepare a radiopaque cement (wTC-Bi). A commercial calcium-silicate cement (ProRoot MTA) was tested as control. Cement disks were aged in DPBS for 5 h ('fresh samples'), 14 and 28 days, and analyzed by ESEM/EDX, SEM/EDX, ATR-FTIR, micro-Raman techniques and scanning white-light interferometry. Proliferation, LDH release, ALP activity and collagen production of human marrow stromal cells (MSC) seeded for 1-28 days on the cements were evaluated. Fresh samples exposed a surface mainly composed of calcium-silicate hydrates CSH (from the hydration of belite and alite), calcium hydroxide, calcium carbonate, and ettringite. Apatite nano-spherulites rapidly precipitated on cement surfaces within 5 h. On wTC-TCP the Ca-P deposits appeared thicker than on the other cements. Aged cements showed an irregular porous calcium-phosphate (Ca-P) coating, formed by aggregated apatite spherulites with interspersed calcite crystals. All the experimental cements exerted no acute toxicity in the cell assay system and allowed cell growth. Using biochemical results, the scores were: fresh cements>aged cements for cell proliferation and ALP activity (except for wTC-Bi), whereas fresh cements

Simulating Regoliths in a Microgravity Environment

NASA Astrophysics Data System (ADS)

Murdoch, N.; Rozitis, B.; Green, S. F.; Michel, P.; Losert, W.; de Lophem, T. L.

2011-10-01

The dynamics of granular materials are involved in the evolution of solid planets and small bodies in our Solar System, whose surfaces are generally covered with regolith. An understanding of granular dynamics appears also to be critical for the design and/or operations of landers, sampling devices and rovers to be included in space missions. The AstEx experiment uses a microgravity modified Taylor-Couette shear cell to investigate granular motion caused by shear and shear reversal forces under the microgravity conditions of parabolic flight. The results will lead to a greater understanding of the mechanical response of granular materials subject to external forces in varying gravitational environments.

Cemented Volcanic Soils, Martian Spectra and Implications for the Martian Climate

NASA Technical Reports Server (NTRS)

Bishop, J. L.; Schiffman, P.; Drief, A.; Southard, R. J.

2004-01-01

Cemented soils formed via reactions with salts are studied here and provide information about the climate when they formed. Spectroscopic and microprobe studies have been performed on cemented volcanic crusts in order to learn about the composition of these materials, how they formed, and what they can tell us about climatic interactions with surface material on Mars to form cemented soils. These crusts include carbonate, sulfate and opaline components that may all be present in cemented soil units on Mars.

[Research on bond durability among different core materials and zirconia ceramic cemented by self-adhesive resin cements].

PubMed

Xinyu, Luo; Xiangfeng, Meng

2017-02-01

This research estimated shear bond durability of zirconia and different substrates cemented by two self-adhesive resin cements (Clearfil SA Luting and RelyX U100) before and after aging conditioning. Machined zirconia ceramic discs were cemented with four kinds of core material (cobalt-chromium alloy, flowable composite resin core material, packable composite resin, and dentin) with two self-adhesive resin cements (Clearfil SA Luting and RelyX U100). All specimens were divided into eight test groups, and each test group was divided into two subgroups. Each subgroup was subjected to shear test before and after 10 000 thermal cycles. All factors (core materials, cements, and thermal cycle) significantly influenced bond durability of zirconia ceramic (P<0.00 1). After 10 000 thermal cycles, significant decrease was not observed in shear bond strength of cobalt-chromium alloy luted with Clearfil SA Luting (P>0.05); observed shear bond strength was significantly higher than those of other substrates (P<0.05). Significantly higher shear bond strength was noted in Clearfil SA Luting luted with cobalt-chromium alloy, flowable composite resin core material, and packable composite resin than that of RelyX U100 (P<0.05). However, significant difference was not observed in shear bond strength of dentin luted with Clearfil SA Luting and RelyX U100 (P>0.05). Different core materials and self-adhesive resin cements can significantly affect bond durability of zirconia ceramic. 
.

Use of reinforced inorganic cement materials for spark wire and drift chamber wire frames

NASA Technical Reports Server (NTRS)

1987-01-01

The results of a survey, materials test, and analysis study directed toward the development of an inorganic glass-fiber reinforced cement material for use in the construction of space qualified spark wire frames and drift chamber frames are presented. The purpose for this research was to evaluate the feasibility of using glass fiber reinforced cement (GFRC) for large dimensioned structural frames for supporting a number of precisely located spark wires in multiple planes. A survey of the current state of the art in fiber reinforced cement materials was made; material sample mixes were made and tested to determine their laboratory performances. Tests conducted on sample materials showed that compressive and flexural strengths of this material could approach values which would enable fabrication of structural spark wire frames.

Resilient moduli of typical Missouri soils and unbound granular base materials.

DOT National Transportation Integrated Search

2009-01-01

The objective of this project was to determine the resilient moduli for common Missouri subgrade soils and typical unbound granular base materials in accordance with the AASHTO T 307 test method. The results allow Missouri Department of Transportatio...

Noise Propagation and Uncertainty Quantification in Hybrid Multiphysics Models: Initiation and Reaction Propagation in Energetic Materials

DTIC Science & Technology

2016-05-23

general model for heterogeneous granular media under compaction and (ii) the lack of a reliable multiscale discrete -to-continuum framework for...dynamics. These include a continuum- discrete model of heat dissipation/diffusion and a continuum- discrete model of compaction of a granular material with...the lack of a general model for het- erogeneous granular media under compac- tion and (ii) the lack of a reliable multi- scale discrete -to-continuum

The effect of cement on hip stem fixation: a biomechanical study.

PubMed

Çelik, Talip; Mutlu, İbrahim; Özkan, Arif; Kişioğlu, Yasin

2017-06-01

This study presents the numerical analysis of stem fixation in hip surgery using with/without cement methods since the use of cement is still controversial based on the clinical studies in the literature. Many different factors such as stress shielding, aseptic loosening, material properties of the stem, surgeon experiences etc. play an important role in the failure of the stem fixations. The stem fixation methods, cemented and uncemented, were evaluated in terms of mechanical failure aspects using computerized finite element method. For the modeling processes, three dimensional (3D) femur model was generated from computerized tomography (CT) images taken from a patient using the MIMICS Software. The design of the stem was also generated as 3D CAD model using the design parameters taken from the manufacturer catalogue. These 3D CAD models were generated and combined with/without cement considering the surgical procedure using SolidWorks program and then imported into ANSYS Workbench Software. Two different material properties, CoCrMo and Ti6Al4V, for the stem model and Poly Methyl Methacrylate (PMMA) for the cement were assigned. The material properties of the femur were described according to a density calculated from the CT images. Body weight and muscle forces were applied on the femur and the distal femur was fixed for the boundary conditions. The calculations of the stress distributions of the models including cement and relative movements of the contacts examined to evaluate the effects of the cement and different stem material usage on the failure of stem fixation. According to the results, the use of cement for the stem fixation reduces the stress shielding but increases the aseptic loosening depending on the cement crack formations. Additionally, using the stiffer material for the stem reduces the cement stress but increases the stress shielding. Based on the results obtained in the study, even when taking the disadvantages into account, the cement usage is more suitable for the hip fixations.

USE OF GRANULAR GRAPHITE FOR ELECTROLYTIC DECHLORINATION OF TRICHLOROETHYLENE

EPA Science Inventory

Granular graphite is a potential electrode material for the electrochemical remediation of refractory chlorinated organic compounds such as trichloroethylene (TCE). However, the use of granular graphite can complicate the experimental results. On one hand, up to 99% of TCE was re...

Particle size effect on strength, failure, and shock behavior in polytetrafluoroethylene-Al-W granular composite materials

NASA Astrophysics Data System (ADS)

Herbold, E. B.; Nesterenko, V. F.; Benson, D. J.; Cai, J.; Vecchio, K. S.; Jiang, F.; Addiss, J. W.; Walley, S. M.; Proud, W. G.

2008-11-01

The variation of metallic particle size and sample porosity significantly alters the dynamic mechanical properties of high density granular composite materials processed using a cold isostatically pressed mixture of polytetrafluoroethylene (PTFE), aluminum (Al), and tungsten (W) powders. Quasistatic and dynamic experiments are performed with identical constituent mass fractions with variations in the size of the W particles and pressing conditions. The relatively weak polymer matrix allows the strength and fracture modes of this material to be governed by the granular type behavior of agglomerated metal particles. A higher ultimate compressive strength was observed in relatively high porosity samples with small W particles compared to those with coarse W particles in all experiments. Mesoscale granular force chains of the metallic particles explain this unusual phenomenon as observed in hydrocode simulations of a drop-weight test. Macrocracks forming below the critical failure strain for the matrix and unusual behavior due to a competition between densification and fracture in dynamic tests of porous samples were also observed. Numerical modeling of shock loading of this granular composite material demonstrated that the internal energy, specifically thermal energy, of the soft PTFE matrix can be tailored by the W particle size distribution.

An alternative method for the treatment of waste produced at a dye and a metal-plating industry using natural and/or waste materials.

PubMed

Fatta, Despo; Papadopoulos, Achilleas; Stefanakis, Nikos; Loizidou, Maria; Savvides, Chrysanthos

2004-08-01

The aim of this study was to develop cost-effective, appropriate solidification technologies for treating hazardous industrial wastes that are currently disposed of in ways that may threaten the quality of local groundwater. One major objective was to use materials other than cement, and preferably materials that are themselves wastes, as the solidification additives, namely using wastes to treat wastes or locally available natural material. This research examines the cement-based and lime-based stabilization/solidification (S/S) techniques applied for waste generated at a metal-plating industry and a dye industry. For the lime-based S/S process the following binder mixtures were used: cement kiln dust/ lime, bentonite/lime and gypsum/lime. For the cement-based S/S process three binder mixtures were used: cement kiln dust/cement, bentonite/cement and gypsum/cement. The leachability of the wastes was evaluated using the toxicity characteristic leaching procedure. The applicability and optimum weight ratio of the binder mixtures were estimated using the unconfined compressive strength test. The optimum ratio mixtures were mixed with waste samples in different ratios and cured for 28 days in order to find the S/S products with the highest strength and lowest leachability at the same time. The results of this work showed that the cement-and lime-based S/S process, using cement kiln dust and bentonite as additives can be effectively used in order to treat industrial waste.

Piezoresistivity, mechanisms and model of cement-based materials with CNT/NCB composite fillers

NASA Astrophysics Data System (ADS)

Zhang, Liqing; Ding, Siqi; Dong, Sufen; Li, Zhen; Ouyang, Jian; Yu, Xun; Han, Baoguo

2017-12-01

The use of conductive cement-based materials as sensors has attracted intense interest over past decades. In this paper, carbon nanotube (CNT)/nano carbon black (NCB) composite fillers made by electrostatic self-assembly are used to fabricate conductive cement-based materials. Electrical and piezoresistive properties of the fabricated cement-based materials are investigated. Effect of filler content, load amplitudes and rate on piezoresistive property within elastic regime and piezoresistive behaviors during compressive loading to destruction are explored. Finally, a model describing piezoresistive property of cement-based materials with CNT/NCB composite fillers is established based on the effective conductive path and tunneling effect theory. The research results demonstrate that filler content and load amplitudes have obvious effect on piezoresistive property of the composites materials, while load rate has little influence on piezoresistive property. During compressive loading to destruction, the composites also show sensitive piezoresistive property. Therefore, the cement-based composites can be used to monitor the health state of structures during their whole life. The built model can well describe the piezoresistive property of the composites during compressive loading to destruction. The good match between the model and experiment data indicates that tunneling effect actually contributes to piezoresistive phenomenon.

High-volume use of self-cementing spray dry absorber material for structural applications

NASA Astrophysics Data System (ADS)

Riley, Charles E.

Spray dry absorber (SDA) material, or spray dryer ash, is a byproduct of energy generation by coal combustion and sulfur emissions controls. Like any resource, it ought to be used to its fullest potential offsetting as many of the negative environmental impacts of coal combustion as possible throughout its lifecycle. Its cementitious and pozzolanic properties suggest it be used to augment or replace another energy and emissions intensive product: Portland cement. There is excellent potential for spray dryer ash to be used beneficially in structural applications, which will offset CO2 emissions due to Portland cement production, divert landfill waste by further utilizing a plentiful coal combustion by-product, and create more durable and sustainable structures. The research into beneficial use applications for SDA material is relatively undeveloped and the material is highly underutilized. This dissertation explored a specific self-cementing spray dryer ash for use as a binder in structural materials. Strength and stiffness properties of hydrated spray dryer ash mortars were improved by chemical activation with Portland cement and reinforcement with polymer fibers from automobile tire recycling. Portland cement at additions of five percent of the cementitious material was found to function effectively as an activating agent for spray dryer ash and had a significant impact on the hardened properties. The recycled polymer fibers improved the ductility and toughness of the material in all cases and increased the compressive strength of weak matrix materials like the pure hydrated ash. The resulting hardened materials exhibited useful properties that were sufficient to suggest that they be used in structural applications such as concrete, masonry block, or as a hydraulic cement binder. While the long-term performance characteristics remain to be investigated, from an embodied-energy and carbon emissions standpoint the material investigated here is far superior to Portland cement.

Resilient moduli of typical Missouri soils and unbound granular base materials

DOT National Transportation Integrated Search

2008-03-01

The objective of this project is to accurately determine the resilient moduli for common Missouri subgrade soils and unbound granular base materials in accordance with the AASHTO T 307 test method. The test results included moduli data from 27 common...

Preparation and Characterization of Injectable Brushite Filled-Poly (Methyl Methacrylate) Bone Cement

PubMed Central

Rodriguez, Lucas C.; Chari, Jonathan; Aghyarian, Shant; Gindri, Izabelle M.; Kosmopoulos, Victor; Rodrigues, Danieli C.

2014-01-01

Powder-liquid poly (methyl methacrylate) (PMMA) bone cements are widely utilized for augmentation of bone fractures and fixation of orthopedic implants. These cements typically have an abundance of beneficial qualities, however their lack of bioactivity allows for continued development. To enhance osseointegration and bioactivity, calcium phosphate cements prepared with hydroxyapatite, brushite or tricalcium phosphates have been introduced with rather unsuccessful results due to increased cement viscosity, poor handling and reduced mechanical performance. This has limited the use of such cements in applications requiring delivery through small cannulas and in load bearing. The goal of this study is to design an alternative cement system that can better accommodate calcium-phosphate additives while preserving cement rheological properties and performance. In the present work, a number of brushite-filled two-solution bone cements were prepared and characterized by studying their complex viscosity-versus-test frequency, extrusion stress, clumping tendency during injection through a syringe, extent of fill of a machined void in cortical bone analog specimens, and compressive strength. The addition of brushite into the two-solution cement formulations investigated did not affect the pseudoplastic behavior and handling properties of the materials as demonstrated by rheological experiments. Extrusion stress was observed to vary with brushite concentration with values lower or in the range of control PMMA-based cements. The materials were observed to completely fill pre-formed voids in bone analog specimens. Cement compressive strength was observed to decrease with increasing concentration of fillers; however, the materials exhibited high enough strength for consideration in load bearing applications. The results indicated that partially substituting the PMMA phase of the two-solution cement with brushite at a 40% by mass concentration provided the best combination of the properties investigated. This alternative material may find applications in systems requiring highly injectable and viscous cements such as in the treatment of spinal fractures and bone defects. PMID:28788212

The effects of combined supplementary cementitious materials on physical properties of Kansas concrete pavements.

DOT National Transportation Integrated Search

2013-12-01

This study evaluated the effects of combining varying proportions of slag cement and Class C fly ash : with Type I/II cement in concrete pavement. Three different ternary cementitious material combinations : containing slag cement and Class C fly ash...

Origin of Granular Capillarity Revealed by Particle-Based Simulations

NASA Astrophysics Data System (ADS)

Fan, Fengxian; Parteli, Eric J. R.; Pöschel, Thorsten

2017-05-01

When a thin tube is dipped into water, the water will ascend to a certain height, against the action of gravity. While this effect, termed capillarity, is well known, recent experiments have shown that agitated granular matter reveals a similar behavior. Namely, when a vertical tube is inserted into a container filled with granular material and is then set into vertical vibration, the particles rise up along the tube. In the present Letter, we investigate the effect of granular capillarity by means of numerical simulations and show that the effect is caused by convection of the granular material in the container. Moreover, we identify two regimes of behavior for the capillary height Hc∞ depending on the tube-to-particle-diameter ratio, D /d . For large D /d , a scaling of Hc∞ with the inverse of the tube diameter, which is reminiscent of liquids, is observed. However, when D /d decreases down to values smaller than a few particle sizes, a uniquely granular behavior is observed where Hc∞ increases linearly with the tube diameter.

Investigation of 4-year-old stabilised/solidified and accelerated carbonated contaminated soil.

PubMed

Antemir, A; Hills, C D; Carey, P J; Magnié, M-C; Polettini, A

2010-09-15

The investigation of the pilot-scale application of two different stabilisation/solidification (S/S) techniques was carried out at a former fireworks and low explosives manufacturing site in SE England. Cores and granular samples were recovered from uncovered accelerated carbonated (ACT) and cement-treated soils (S/S) after 4 years to evaluate field-performance with time. Samples were prepared for microstructural examination and leaching testing. The results indicated that the cement-treated soil was progressively carbonated over time, whereas the mineralogy of the carbonated soil remained essentially unchanged. Distinct microstructures were developed in the two soils. Although Pb, Zn and Cu leached less from the carbonated soil, these metals were adequately immobilised by both treatments. Geochemical modeling of pH-dependent leaching data suggested that the retention of trace metals resulted from different immobilisation mechanisms operating in the two soils examined. Copyright 2010 Elsevier B.V. All rights reserved.

Thermophysical and Mechanical Properties of Hardened Cement Paste with Microencapsulated Phase Change Materials for Energy Storage

PubMed Central

Cui, Hongzhi; Liao, Wenyu; Memon, Shazim Ali; Dong, Biqin; Tang, Waiching

2014-01-01

In this research, structural-functional integrated cement-based materials were prepared by employing cement paste and a microencapsulated phase change material (MPCM) manufactured using urea-formaldehyde resin as the shell and paraffin as the core material. The encapsulation ratio of the MPCM could reach up to 91.21 wt%. Thermal energy storage cement pastes (TESCPs) incorporated with different MPCM contents (5%, 10%, 15%, 20% and 25% by weight of cement) were developed, and their thermal and mechanical properties were studied. The results showed that the total energy storage capacity of the hardened cement specimens with MPCM increased by up to 3.9-times compared with that of the control cement paste. The thermal conductivity at different temperature levels (35–36 °C, 55–56 °C and 72–74 °C) decreased with the increase of MPCM content, and the decrease was the highest when the temperature level was 55–56 °C. Moreover, the compressive strength, flexural strength and density of hardened cement paste decreased with the increase in MPCM content linearly. Among the evaluated properties, the compressive strength of TESCPs had a larger and faster degradation with the increase of MPCM content. PMID:28788291

Revealing the influence of water-cement ratio on the pore size distribution in hydrated cement paste by using cyclohexane

NASA Astrophysics Data System (ADS)

Bede, Andrea; Ardelean, Ioan

2017-12-01

Varying the amount of water in a concrete mix will influence its final properties considerably due to the changes in the capillary porosity. That is why a non-destructive technique is necessary for revealing the capillary pore distribution inside hydrated cement based materials and linking the capillary porosity with the macroscopic properties of these materials. In the present work, we demonstrate a simple approach for revealing the differences in capillary pore size distributions introduced by the preparation of cement paste with different water-to-cement ratios. The approach relies on monitoring the nuclear magnetic resonance transverse relaxation distribution of cyclohexane molecules confined inside the cement paste pores. The technique reveals the whole spectrum of pores inside the hydrated cement pastes, allowing a qualitative and quantitative analysis of different pore sizes. The cement pastes with higher water-to-cement ratios show an increase in capillary porosity, while for all the samples the intra-C-S-H and inter-C-S-H pores (also known as gel pores) remain unchanged. The technique can be applied to various porous materials with internal mineral surfaces.

Modeling of Abrasion and Crushing of Unbound Granular Materials During Compaction

NASA Astrophysics Data System (ADS)

Ocampo, Manuel S.; Caicedo, Bernardo

2009-06-01

Unbound compacted granular materials are commonly used in engineering structures as layers in road pavements, railroad beds, highway embankments, and foundations. These structures are generally subjected to dynamic loading by construction operations, traffic and wheel loads. These repeated or cyclic loads cause abrasion and crushing of the granular materials. Abrasion changes a particle's shape, and crushing divides the particle into a mixture of many small particles of varying sizes. Particle breakage is important because the mechanical and hydraulic properties of these materials depend upon their grain size distribution. Therefore, it is important to evaluate the evolution of the grain size distribution of these materials. In this paper an analytical model for unbound granular materials is proposed in order to evaluate particle crushing of gravels and soils subjected to cyclic loads. The model is based on a Markov chain which describes the development of grading changes in the material as a function of stress levels. In the model proposed, each particle size is a state in the system, and the evolution of the material is the movement of particles from one state to another in n steps. Each step is a load cycle, and movement between states is possible with a transition probability. The crushing of particles depends on the mechanical properties of each grain and the packing density of the granular material. The transition probability was calculated using both the survival probability defined by Weibull and the compressible packing model developed by De Larrard. Material mechanical properties are considered using the Weibull probability theory. The size and shape of the grains, as well as the method of processing the packing density are considered using De Larrard's model. Results of the proposed analytical model show a good agreement with the experimental tests carried out using the gyratory compaction test.

Formulation of portland composite cement using waste glass as a supplementary cementitious material

NASA Astrophysics Data System (ADS)

Manullang, Ria Julyana; Samadhi, Tjokorde Walmiki; Purbasari, Aprilina

2017-09-01

Utilization of waste glass in cement is an attractive options because of its pozzolanic behaviour and the market of glass-composite cement is potentially available. The objective of this research is to evaluate the formulation of waste glass as supplementary cementitious material (SCM) by an extreme vertices mixture experiment, in which clinker, waste glass and gypsum proportions are chosen as experimental variables. The composite cements were synthesized by mixing all of powder materials in jar mill. The compressive strength of the composite cement mortars after being cured for 28 days ranges between 229 to 268 kg/cm2. Composite cement mortars exhibit lower compressive strength than ordinary Portland cement (OPC) mortars but is still capable of meeting the SNI 15-7064-2004 standards. The highest compressive strength is obtained by shifting the cement blend composition to the direction of increasing clinker and gypsum proportions as well as reducing glass proportion. The lower compressive strength of composite cement is caused by expansion due to ettringite and ASR gel. Based on the experimental result, the composite cement containing 80% clinker, 15% glass and 5% gypsum has the highest compressive strength. As such, the preliminary technical feasibility of reuse of waste glass as SCM has been confirmed.

Mechanical, material, and antimicrobial properties of acrylic bone cement impregnated with silver nanoparticles.

PubMed

Slane, Josh; Vivanco, Juan; Rose, Warren; Ploeg, Heidi-Lynn; Squire, Matthew

2015-03-01

Prosthetic joint infection is one of the most serious complications that can lead to failure of a total joint replacement. Recently, the rise of multidrug resistant bacteria has substantially reduced the efficacy of antibiotics that are typically incorporated into acrylic bone cement. Silver nanoparticles (AgNPs) are an attractive alternative to traditional antibiotics resulting from their broad-spectrum antimicrobial activity and low bacterial resistance. The purpose of this study, therefore, was to incorporate metallic silver nanoparticles into acrylic bone cement and quantify the effects on the cement's mechanical, material and antimicrobial properties. AgNPs at three loading ratios (0.25, 0.5, and 1.0% wt/wt) were incorporated into a commercial bone cement using a probe sonication technique. The resulting cements demonstrated mechanical and material properties that were not substantially different from the standard cement. Testing against Staphylococcus aureus and Staphylococcus epidermidis using Kirby-Bauer and time-kill assays demonstrated no antimicrobial activity against planktonic bacteria. In contrast, cements modified with AgNPs significantly reduced biofilm formation on the surface of the cement. These results indicate that AgNP-loaded cement is of high potential for use in primary arthroplasty where prevention of bacterial surface colonization is vital. Copyright © 2014 Elsevier B.V. All rights reserved.

Analysis of the cement clinker produced with incorporation of petroleum sludge

NASA Astrophysics Data System (ADS)

Benlamoudi, A.; Kadir, A. Abdul; Khodja, M.; Nuruddin, M. F.

2018-04-01

Very limited researches have been conducted on the incorporation of petroleum sludge waste into cement clinker production even though this waste may contain similar components to those of clinker raw materials. In this research, petroleum sludge was integrated into cement plant as raw material to produce the cement clinker. As results, incorporation of 5% of this waste was able to produce an acceptable quality of cement. Despite the use of petroleum sludge has decreased the properties of the produced clinker, but it still fit the requirements.

Cements and adhesives for all-ceramic restorations.

PubMed

Manso, Adriana P; Silva, Nelson R F A; Bonfante, Estevam A; Pegoraro, Thiago A; Dias, Renata A; Carvalho, Ricardo M

2011-04-01

Dental cements are designed to retain restorations, prefabricated or cast posts and cores, and appliances in a stable, and long-lasting position in the oral environment. Resin-based cements were developed to overcome drawbacks of nonresinous materials, including low strength, high solubility, and opacity. Successful cementation of esthetic restorations depends on appropriate treatment to the tooth substrate and intaglio surface of the restoration, which in turn, depends on the ceramic characteristics. A reliable resin cementation procedure can only be achieved if the operator is aware of the mechanisms involved to perform the cementation and material properties. This article addresses current knowledge of resin cementation concepts, exploring the bonding mechanisms that influence long-term clinical success of all-ceramic systems. Copyright © 2011 Elsevier Inc. All rights reserved.

Chaos emerging in soil failure patterns observed during tillage: Normalized deterministic nonlinear prediction (NDNP) and its application.

PubMed

Sakai, Kenshi; Upadhyaya, Shrinivasa K; Andrade-Sanchez, Pedro; Sviridova, Nina V

2017-03-01

Real-world processes are often combinations of deterministic and stochastic processes. Soil failure observed during farm tillage is one example of this phenomenon. In this paper, we investigated the nonlinear features of soil failure patterns in a farm tillage process. We demonstrate emerging determinism in soil failure patterns from stochastic processes under specific soil conditions. We normalized the deterministic nonlinear prediction considering autocorrelation and propose it as a robust way of extracting a nonlinear dynamical system from noise contaminated motion. Soil is a typical granular material. The results obtained here are expected to be applicable to granular materials in general. From a global scale to nano scale, the granular material is featured in seismology, geotechnology, soil mechanics, and particle technology. The results and discussions presented here are applicable in these wide research areas. The proposed method and our findings are useful with respect to the application of nonlinear dynamics to investigate complex motions generated from granular materials.

A new perspective of particle adsorption: Dispersed oil and granular materials interactions in simulated coastal environment.

PubMed

Meng, Long; Bao, Mutai; Sun, Peiyan

2017-09-15

This study, adsorption behaviors of dispersed oil in seawaters by granular materials were explored in simulation environment. We quantitatively demonstrated the dispersed oil adsorbed by granular materials were both dissolved petroleum hydrocarbons (DPHs) and oil droplets. Furthermore, DPHs were accounted for 42.5%, 63.4%, and 85.2% (35.5% was emulsion adsorption) in the adsorption of dispersed oil by coastal rocks, sediments, and bacterial strain particles respectively. Effects of controlling parameters, such as temperature, particle size and concentration on adsorption of petroleum hydrocarbons were described in detail. Most strikingly, adsorption concentration was followed a decreasing order of bacterial strain (0.5-2μm)>sediments (0.005-0.625mm)>coastal rocks (0.2-1cm). With particle concentration or temperature increased, adsorption concentration increased for coastal rocks particle but decreased for sediments particle. Besides, particle adsorption rate of petroleum hydrocarbons (n-alkanes and PAHs) was different among granular materials during 60 days. Copyright © 2017 Elsevier Ltd. All rights reserved.

Installing Mechanics of Granular Materials (MGM) Experiment Test Cell

NASA Technical Reports Server (NTRS)

1996-01-01

Astronaut Carl Walz installs Mechanics of Granular Materials (MGM) test cell on STS-79. Sand and soil grains have faces that can cause friction as they roll and slide against each other, or even cause sticking and form small voids between grains. This complex behavior can cause soil to behave like a liquid under certain conditions such as earthquakes or when powders are handled in industrial processes. Mechanics of Granular Materials (MGM) experiments aboard the Space Shuttle use the microgravity of space to simulate this behavior under conditons that carnot be achieved in laboratory tests on Earth. MGM is shedding light on the behavior of fine-grain materials under low effective stresses. Applications include earthquake engineering, granular flow technologies (such as powder feed systems for pharmaceuticals and fertilizers), and terrestrial and planetary geology. Nine MGM specimens have flown on two Space Shuttle flights. Another three are scheduled to fly on STS-107. The principal investigator is Stein Sture of the University of Colorado at Boulder. Credit: NASA/John Space Center

Mechanical analysis and force chain determination in granular materials using digital image correlation.

PubMed

Chen, Fanxiu; Zhuang, Qi; Zhang, Huixin

2016-06-20

The mechanical behaviors of granular materials are governed by the grain properties and microstructure of the materials. We conducted experiments to study the force transmission in granular materials using plane strain tests. The large amount of nearly continuous displacement data provided by the advanced noncontact experimental technique of digital image correlation (DIC) has provided a means to quantify local displacements and strains at the particle level. The average strain of each particle could be calculated based on the DIC method, and the average stress could be obtained using Hooke's law. The relationship between the stress and particle force could be obtained based on basic Newtonian mechanics and the balance of linear momentum at the particle level. This methodology is introduced and validated. In the testing procedure, the system is tested in real 2D particle cases, and the contact forces and force chain are obtained and analyzed. The system has great potential for analyzing a real granular system and measuring the contact forces and force chain.

Dynamic compaction of granular materials

PubMed Central

Favrie, N.; Gavrilyuk, S.

2013-01-01

An Eulerian hyperbolic multiphase flow model for dynamic and irreversible compaction of granular materials is constructed. The reversible model is first constructed on the basis of the classical Hertz theory. The irreversible model is then derived in accordance with the following two basic principles. First, the entropy inequality is satisfied by the model. Second, the corresponding ‘intergranular stress’ coming from elastic energy owing to contact between grains decreases in time (the granular media behave as Maxwell-type materials). The irreversible model admits an equilibrium state corresponding to von Mises-type yield limit. The yield limit depends on the volume fraction of the solid. The sound velocity at the yield surface is smaller than that in the reversible model. The last one is smaller than the sound velocity in the irreversible model. Such an embedded model structure assures a thermodynamically correct formulation of the model of granular materials. The model is validated on quasi-static experiments on loading–unloading cycles. The experimentally observed hysteresis phenomena were numerically confirmed with a good accuracy by the proposed model. PMID:24353466

Dynamic Effective Mass of Granular Media

NASA Astrophysics Data System (ADS)

Hsu, Chaur-Jian; Johnson, David L.; Ingale, Rohit A.; Valenza, John J.; Gland, Nicolas; Makse, Hernán A.

2009-02-01

We develop the concept of frequency dependent effective mass, Mtilde (ω), of jammed granular materials which occupy a rigid cavity to a filling fraction of 48%, the remaining volume being air of normal room condition or controlled humidity. The dominant features of Mtilde (ω) provide signatures of the dissipation of acoustic modes, elasticity, and aging effects in the granular medium. We perform humidity controlled experiments and interpret the data in terms of a continuum model and a “trap” model of thermally activated capillary bridges at the contact points. The results suggest that attenuation of acoustic waves in granular materials can be influenced significantly by the kinetics of capillary condensation between the asperities at the contacts.

On Characterizing Particle Shape

NASA Technical Reports Server (NTRS)

Ennis, Bryan J.; Rickman, Douglas; Rollins, A. Brent; Ennis, Brandon

2014-01-01

It is well known that particle shape affects flow characteristics of granular materials, as well as a variety of other solids processing issues such as compaction, rheology, filtration and other two-phase flow problems. The impact of shape crosses many diverse and commercially important applications, including pharmaceuticals, civil engineering, metallurgy, health, and food processing. Two applications studied here include the dry solids flow of lunar simulants (e.g. JSC-1, NU-LHT-2M, OB-1), and the flow properties of wet concrete, including final compressive strength. A multi-dimensional generalized, engineering method to quantitatively characterize particle shapes has been developed, applicable to both single particle orientation and multi-particle assemblies. The two-dimension, three dimension inversion problem is also treated, and the application of these methods to DEM model particles will be discussed. In the case of lunar simulants, flow properties of six lunar simulants have been measured, and the impact of particle shape on flowability - as characterized by the shape method developed here -- is discussed, especially in the context of three simulants of similar size range. In the context of concrete processing, concrete construction is a major contributor to greenhouse gas production, of which the major contributor is cement binding loading. Any optimization in concrete rheology and packing that can reduce cement loading and improve strength loading can also reduce currently required construction safety factors. The characterization approach here is also demonstrated for the impact of rock aggregate shape on concrete slump rheology and dry compressive strength.

N-acetyl cysteine (NAC)-mediated detoxification and functionalization of poly(methyl methacrylate) bone cement.

PubMed

Tsukimura, Naoki; Yamada, Masahiro; Aita, Hideki; Hori, Norio; Yoshino, Fumihiko; Chang-Il Lee, Masaichi; Kimoto, Katsuhiko; Jewett, Anahid; Ogawa, Takahiro

2009-07-01

Currently used poly(methyl methacrylate) (PMMA)-based bone cement lacks osteoconductivity and induces osteolysis and implant loosening due to its cellular and tissue-toxicity. A high percentage of revision surgery following the use of bone cement has become a significant universal problem. This study determined whether incorporation of the amino acid derivative N-acetyl cysteine (NAC) in bone cement reduces its cytotoxicity and adds osteoconductivity to the material. Biocompatibility and bioactivity of PMMA-based bone cement with or without 25mm NAC incorporation was examined using rat bone marrow-derived osteoblastic cells. Osteoconductive potential of NAC-incorporated bone cement was determined by microCT bone morphometry and implant biomechanical test in the rat model. Generation of free radicals within the polymerizing bone cement was examined using electron spin resonance spectroscopy. Severely compromised viability and completely suppressed phenotypes of osteoblasts on untreated bone cement were restored to the normal level by NAC incorporation. Bone volume formed around 25mm NAC-incorporated bone cement was threefold greater than that around control bone cement. The strength of bone-bone cement integration was 2.2 times greater for NAC-incorporated bone cement. For NAC-incorporated bone cement, the spike of free radical generation ended within 12h, whereas for control bone cement, a peak level lasted for 6 days and a level greater than half the level of the peak was sustained for 20 days. NAC also increased the level of antioxidant glutathione in osteoblasts. These results suggest that incorporation of NAC in PMMA bone cement detoxifies the material by immediate and effective in situ scavenging of free radicals and increasing intracellular antioxidant reserves, and consequently adds osteoconductivity to the material.

Sounds of Failure: Passive Acoustic Measurements of Excited Vibrational Modes

NASA Astrophysics Data System (ADS)

Brzinski, Theodore A.; Daniels, Karen E.

2018-05-01

Granular materials can fail through spontaneous events like earthquakes or brittle fracture. However, measurements and analytic models which forecast failure in this class of materials, while of both fundamental and practical interest, remain elusive. Materials including numerical packings of spheres, colloidal glasses, and granular materials have been known to develop an excess of low-frequency vibrational modes as the confining pressure is reduced. Here, we report experiments on sheared granular materials in which we monitor the evolving density of excited modes via passive monitoring of acoustic emissions. We observe a broadening of the distribution of excited modes coincident with both bulk and local plasticity, and evolution in the shape of the distribution before and after bulk failure. These results provide a new interpretation of the changing state of the material on its approach to stick-slip failure.

Sounds of Failure: Passive Acoustic Measurements of Excited Vibrational Modes.

PubMed

Brzinski, Theodore A; Daniels, Karen E

2018-05-25

Granular materials can fail through spontaneous events like earthquakes or brittle fracture. However, measurements and analytic models which forecast failure in this class of materials, while of both fundamental and practical interest, remain elusive. Materials including numerical packings of spheres, colloidal glasses, and granular materials have been known to develop an excess of low-frequency vibrational modes as the confining pressure is reduced. Here, we report experiments on sheared granular materials in which we monitor the evolving density of excited modes via passive monitoring of acoustic emissions. We observe a broadening of the distribution of excited modes coincident with both bulk and local plasticity, and evolution in the shape of the distribution before and after bulk failure. These results provide a new interpretation of the changing state of the material on its approach to stick-slip failure.

In vitro wear rates of materials under different loads and varying pH.

PubMed

Shabanian, Mitra; Richards, Lindsay C

2002-06-01

Despite the need for information about the wear characteristics of restorative materials, there have been few systemic studies of the factors that influence the rate of material wear. This study compared the wear rates of enamel and 3 tooth-colored restorative materials under different loads (0, 3.2, 6.7, and 9.95 kg) and pH levels (1.2, 3.3, and 7.0). An electromechanical tooth wear machine was used so that standard restorations representing 3 materials could be worn by opposing enamel under controlled conditions. The wear rates of enamel, composite (Z100), a conventional glass ionomer cement (Fuji IX), and a resin-modified glass ionomer cement (Fuji II LC) were compared at a range of loads (0 to 9.95 kg) and pH levels (1.2 to 7.0) and also at different sites across each restoration. Ten specimens were randomly assigned to each experimental group. Wear assessment was performed with a modified light microscope to quantify the height changes at defined points across wear facets. Four-way analysis of variance was used to compare wear rates among materials, pH levels, loads, and sites. Post-hoc t tests identified significant differences between specific pairs of experimental conditions (P<.05). The wear rates of enamel and the other test materials varied significantly with pH (P<.0001), load (P<.0001), and type of material (P<.0001). Enamel wear was influenced most by varied pH, whereas the composite was least affected by acid. The conventional glass ionomer cement was more susceptible than the composite to the effects of varied pH; the acid susceptibility of the resin-modified glass ionomer cement was generally between that of the composite and conventional glass ionomer cement. Enamel and the conventional glass ionomer cement were affected similarly by load. The composite was more resistant than the conventional glass ionomer cement to wear at higher loads; the resin-modified glass ionomer cement exhibited intermediate load resistance. Within the limitations of this study, the 3 test materials were more resistant than enamel to acid, with the composite demonstrating the lowest susceptibility to acid. The acid- and load-resistance of the resin-modified glass ionomer cement was consistently less than that of the composite and greater than that of the conventional glass ionomer cement.

In vitro shear bond strength of cementing agents to fixed prosthodontic restorative materials.

PubMed

Piwowarczyk, Andree; Lauer, Hans-Christoph; Sorensen, John A

2004-09-01

Durable bonding to fixed prosthodontic restorations is desirable; however, little information is available on the strength of the bond between different cements and fixed prosthodontic restorative materials. This study determined the shear-bond strength of cementing agents to high-gold-content alloy castings and different dental ceramics: high-strength aluminum oxide (Procera AllCeram), leucite-reinforced (IPS Empress), and lithium disilicate glass-ceramic (IPS Empress 2). Prepolymerized resin composite cylinders (5.5 mm internal diameter, n=20) were bonded to the pretreated surfaces of prosthodontic materials. High-gold-content alloy and high-strength aluminum oxide surfaces were airborne-particle-abraded, and pressable ceramics were hydrofluoric acid-etched and silanized prior to cementing. The cementing agents tested were a zinc-phosphate cement (Fleck's zinc cement), glass ionomer cements (Fuji I, Ketac-Cem), resin-modified glass ionomer cements (Fuji Plus, Fuji Cem, RelyX Luting), resin cements (RelyX ARC, Panavia F, Variolink II, Compolute), and a self-adhesive universal resin cement (RelyX Unicem). Half the specimens (n=10) were tested after 30 minutes; the other half (n=10) were stored in distilled water at 37 degrees C for 14 days and then thermal cycled 1000 times between 5 degrees C and 55 degrees C prior to testing. Shear-bond strength tests were performed using a universal testing machine at a constant crosshead speed of 0.5 mm/min. Statistical analysis was performed by multifactorial analysis of variance taking interactions between effects into account. For multiple paired comparisons, the Tukey method was used (alpha=.05). In a 3-way ANOVA model, the main factors substrate, cement, time, and all corresponding interactions were statistically significant (all P <.0001). In subsequent separate 1-way or 2-way ANOVA models for each substrate type, significant differences between cement types and polymerizing modes were found (all P <.001). None of the cement types provided the highest bonding values with all substrate types. After 14 days of water storage followed by thermal cycling, only the self-adhesive universal resin cement (RelyX Unicem) and 2 of the resin cements (Panavia F and Compolute) exhibited strong bond strengths to specific prosthodontic materials. In contrast, zinc-phosphate, glass ionomer, and resin-modified glass ionomer cements showed the lowest values of all tested cementing agents after 14 days of water storage followed by thermal cycling.

A Twofold Comparison between Dual Cure Resin Modified Cement and Glass Ionomer Cement for Orthodontic Band Cementation

PubMed Central

Attar, Hanaa El; Elhiny, Omnia; Salem, Ghada; Abdelrahman, Ahmed; Attia, Mazen

2016-01-01

AIM: To test the solubility of dual cure resin modified resin cement in a food simulating solution and the shear bond strength compared to conventional Glass ionomer cement. MATERIALS AND METHOD: The materials tested were self-adhesive dual cure resin modified cement and Glass Ionomer (GIC). Twenty Teflon moulds were divided into two groups of tens. The first group was injected and packed with the modified resin cement, the second group was packed with GIC. To test the solubility, each mould was weighed before and after being placed in an analytical reagent for 30 days. The solubility was measured as the difference between the initial and final drying mass. To measure the Shear bond strength, 20 freshly extracted wisdom teeth were equally divided into two groups and embedded in self-cure acrylic resin. Four mm sections of stainless steel bands were cemented to the exposed buccal surfaces of teeth under a constant load of 500 g. Shear bond strength was measured using a computer controlled materials testing machine and the load required to deband the samples was recorded in Newtons. RESULTS: GIC showed significantly higher mean weight loss and an insignificant lower Shear bond strength, compared to dual cure resin Cement. CONCLUSION: It was found that dual cure resin modified cement was less soluble than glass ionomer cement and of comparable bond strength rendering it more useful clinically for orthodontic band cementation. PMID:28028417

Reduction of intergranular exchange coupling and grain size for high Ku CoPt-based granular media: Metal-oxide buffer layer and multiple oxide boundary materials

NASA Astrophysics Data System (ADS)

Tham, Kim Kong; Kushibiki, Ryosuke; Kamada, Tomonari; Hinata, Shintaro; Saito, Shin

2018-05-01

Investigation of magnetic properties and microstructure of granular media with various multiple oxides as the grain boundary material is reported. Saturation magnetization (Ms), uniaxial magnetocrystalline anisotropy (Ku), and magnetic grain diameter (GD) of the granular media show linear correlation with volume weighted average for melting point (Tm) of each oxides (Tmave). Ku of magnetic grains (Kugrain) shows a trade-off relation with GD that it is a big challenge to satisfy both high Kugrain and small GD by only controlling Tmave. To obtain a granular medium with appropriate Kugrain, GD, and low degree of intergranular exchange coupling, the combination of Tmave control of grain boundary material by mixing oxides and employment of a buffer layer are required. Here the degree of intergranular exchange coupling is estimated from the slope of M-H loop at around coercivity (α). By applying this technique, a typical granular medium with Kugrain of 1.0×107 erg/cm3, GD of 5.1 nm, and α of 1.2 is realized.

The comparison of properties and cost of material use of natural rubber and sand in manufacturing cement mortar for construction sub-base layer

NASA Astrophysics Data System (ADS)

Rahman, R.; Nemmang, M. S.; Hazurina, Nor; Shahidan, S.; Khairul Tajuddin Jemain, Raden; Abdullah, M. E.; Hassan, M. F.

2017-11-01

The main issue related to this research was to examine the feasibility of natural rubber SMR 20 in the manufacturing of cement mortar for sub-base layer construction. Subbase layers have certain functions that need to be fulfilled in order to assure strong and adequate permeability of pavement performance. In a pavement structure, sub-base is below the base and serves as the foundation for the overall pavement structure, transmitting traffic loads to the sub-grade and providing drainage. Based on this research, the natural rubber, SMR 20 was with the percentages of 0%, 5%, 10% and 15% to mix with sand in the manufacture of the cement mortar. This research describes some of the properties and cost of the materials for the natural rubber and sand in cement mortar manufacturing by laboratory testing. Effects of the natural rubber replacement on mechanical properties of mortar were investigated by laboratory testing such as compressive strength test and density. This study obtained the 5% of natural rubber replaced in sand can achieved the strength of normal mortar after 7 days and 28 days. The strength of cement mortar depends on the density of cement mortar. According to the cost of both materials, sand shows the lower cost in material for the cement mortar manufacturing than the uses of natural rubber. Thus, the convectional cement mortar which used sand need lower cost than the modified rubber cement mortar and the most economical to apply in industrial. As conclusion, the percentage of 5% natural rubber in the cement mortar would have the same with normal cement mortar in terms of the strength. However, in terms of the cost of the construction, it will increase higher than cost of normal cement mortar production. So that, this modified cement mortar is not economical for the road sub-base construction.

A two-phase flow model for submarine granular flows: With an application to collapse of deeply-submerged granular columns

NASA Astrophysics Data System (ADS)

Lee, Cheng-Hsien; Huang, Zhenhua

2018-05-01

The collapse process of a submerged granular column is strongly affected by its initial packing. Previous models for particle response time, which is used to quantify the drag force between the solid and liquid phases in rheology-based two-phase flow models, have difficulty in simulating the collapse process of granular columns with different initial concentrations (initial packing conditions). This study introduces a new model for particle response time, which enables us to satisfactorily model the drag force between the two phases for a wide range of volume concentration. The present model can give satisfactory results for both loose and dense packing conditions. The numerical results have shown that (i) the initial packing affects the occurrence of contractancy/diltancy behavior during the collapse process, (ii) the general buoyancy and drag force are strongly affected by the initial packing through contractancy and diltancy, and (iii) the general buoyancy and drag force can destabilize the granular material in loose packing condition but stabilize the granular material in dense packing condition. The results have shown that the collapse process of a densely-packed granular column is more sensitive to particle response time than that of a loosely-packed granular column.

Thermal Properties of Cement-Based Composites for Geothermal Energy Applications.

PubMed

Bao, Xiaohua; Memon, Shazim Ali; Yang, Haibin; Dong, Zhijun; Cui, Hongzhi

2017-04-27

Geothermal energy piles are a quite recent renewable energy technique where geothermal energy in the foundation of a building is used to transport and store geothermal energy. In this paper, a structural-functional integrated cement-based composite, which can be used for energy piles, was developed using expanded graphite and graphite nanoplatelet-based composite phase change materials (CPCMs). Its mechanical properties, thermal-regulatory performance, and heat of hydration were evaluated. Test results showed that the compressive strength of GNP-Paraffin cement-based composites at 28 days was more than 25 MPa. The flexural strength and density of thermal energy storage cement paste composite decreased with increases in the percentage of CPCM in the cement paste. The infrared thermal image analysis results showed superior thermal control capability of cement based materials with CPCMs. Hence, the carbon-based CPCMs are promising thermal energy storage materials and can be used to improve the durability of energy piles.

Thermal Properties of Cement-Based Composites for Geothermal Energy Applications

PubMed Central

Bao, Xiaohua; Memon, Shazim Ali; Yang, Haibin; Dong, Zhijun; Cui, Hongzhi

2017-01-01

Geothermal energy piles are a quite recent renewable energy technique where geothermal energy in the foundation of a building is used to transport and store geothermal energy. In this paper, a structural–functional integrated cement-based composite, which can be used for energy piles, was developed using expanded graphite and graphite nanoplatelet-based composite phase change materials (CPCMs). Its mechanical properties, thermal-regulatory performance, and heat of hydration were evaluated. Test results showed that the compressive strength of GNP-Paraffin cement-based composites at 28 days was more than 25 MPa. The flexural strength and density of thermal energy storage cement paste composite decreased with increases in the percentage of CPCM in the cement paste. The infrared thermal image analysis results showed superior thermal control capability of cement based materials with CPCMs. Hence, the carbon-based CPCMs are promising thermal energy storage materials and can be used to improve the durability of energy piles. PMID:28772823

Development of multi-walled carbon nanotubes reinforced monetite bionanocomposite cements for orthopedic applications.

PubMed

Boroujeni, Nariman Mansoori; Zhou, Huan; Luchini, Timothy J F; Bhaduri, Sarit B

2013-10-01

In this study, we present results of our research on biodegradable monetite (DCPA, CaHPO4) cement with surface-modified multi-walled carbon nanotubes (mMWCNTs) as potential bone defect repair material. The cement pastes showed desirable handling properties and possessed a suitable setting time for use in surgical setting. The incorporation of mMWCNTs shortened the setting time of DCPA and increased the compressive strength of DCPA cement from 11.09±1.85 MPa to 21.56±2.47 MPa. The cytocompatibility of the materials was investigated in vitro using the preosteoblast cell line MC3T3-E1. An increase of cell numbers was observed on both DCPA and DCPA-mMWCNTs. Scanning electron microscopy (SEM) results also revealed an obvious cell growth on the surface of the cements. Based on these results, DCPA-mMWCNTs composite cements can be considered as potential bone defect repair materials. © 2013.

Dental Resin Cements-The Influence of Water Sorption on Contraction Stress Changes and Hydroscopic Expansion.

PubMed

Sokolowski, Grzegorz; Szczesio, Agata; Bociong, Kinga; Kaluzinska, Karolina; Lapinska, Barbara; Sokolowski, Jerzy; Domarecka, Monika; Lukomska-Szymanska, Monika

2018-06-08

Resin matrix dental materials undergo contraction and expansion changes due to polymerization and water absorption. Both phenomena deform resin-dentin bonding and influence the stress state in restored tooth structure in two opposite directions. The study tested three composite resin cements (Cement-It, NX3, Variolink Esthetic DC), three adhesive resin cements (Estecem, Multilink Automix, Panavia 2.0), and seven self-adhesive resin cements (Breeze, Calibra Universal, MaxCem Elite Chroma, Panavia SA Cement Plus, RelyX U200, SmartCem 2, and SpeedCEM Plus). The stress generated at the restoration-tooth interface during water immersion was evaluated. The shrinkage stress was measured immediately after curing and after 0.5 h, 24 h, 72 h, 96 h, 168 h, 240 h, 336 h, 504 h, 672 h, and 1344 h by means of photoelastic study. Water sorption and solubility were also studied. All tested materials during polymerization generated shrinkage stress ranging from 4.8 MPa up to 15.1 MPa. The decrease in shrinkage strain (not less than 57%) was observed after water storage (56 days). Self-adhesive cements, i.e., MaxCem Elite Chroma, SpeedCem Plus, Panavia SA Plus, and Breeze exhibited high values of water expansion stress (from 0 up to almost 7 MPa). Among other tested materials only composite resin cement Cement It and adhesive resin cement Panavia 2.0 showed water expansion stress (1.6 and 4.8, respectively). The changes in stress value (decrease in contraction stress or built up of hydroscopic expansion) in time were material-dependent.

Some exact velocity profiles for granular flow in converging hoppers

NASA Astrophysics Data System (ADS)

Cox, Grant M.; Hill, James M.

2005-01-01

Gravity flow of granular materials through hoppers occurs in many industrial processes. For an ideal cohesionless granular material, which satisfies the Coulomb-Mohr yield condition, the number of known analytical solutions is limited. However, for the special case of the angle of internal friction δ equal to ninety degrees, there exist exact parametric solutions for the governing coupled ordinary differential equations for both two-dimensional wedges and three-dimensional cones, both of which involve two arbitrary constants of integration. These solutions are the only known analytical solutions of this generality. Here, we utilize the double-shearing theory of granular materials to determine the velocity field corresponding to these exact parametric solutions for the two problems of gravity flow through converging wedge and conical hoppers. An independent numerical solution for other angles of internal friction is shown to coincide with the analytical solution.

Effect of Anisotropy on the Resilient Behaviour of a Granular Material in Low Traffic Pavement

PubMed Central

Jing, Peng; Nowamooz, Hossein; Chazallon, Cyrille

2017-01-01

Granular materials are often used in pavement structures. The influence of anisotropy on the mechanical behaviour of granular materials is very important. The coupled effects of water content and fine content usually lead to more complex anisotropic behaviour. With a repeated load triaxial test (RLTT), it is possible to measure the anisotropic deformation behaviour of granular materials. This article initially presents an experimental study of the resilient repeated load response of a compacted clayey natural sand with three fine contents and different water contents. Based on anisotropic behaviour, the non-linear resilient model (Boyce model) is improved by the radial anisotropy coefficient γ3 instead of the axial anisotropy coefficient γ1. The results from both approaches (γ1 and γ3) are compared with the measured volumetric and deviatoric responses. These results confirm the capacity of the improved model to capture the general trend of the experiments. Finally, finite element calculations are performed with CAST3M in order to validate the improvement of the modified Boyce model (from γ1 to γ3). The modelling results indicate that the modified Boyce model with γ3 is more widely available in different water contents and different fine contents for this granular material. Besides, based on the results, the coupled effects of water content and fine content on the deflection of the structures can also be observed. PMID:29207504

Effect of Anisotropy on the Resilient Behaviour of a Granular Material in Low Traffic Pavement.

PubMed

Jing, Peng; Nowamooz, Hossein; Chazallon, Cyrille

2017-12-03

Granular materials are often used in pavement structures. The influence of anisotropy on the mechanical behaviour of granular materials is very important. The coupled effects of water content and fine content usually lead to more complex anisotropic behaviour. With a repeated load triaxial test (RLTT), it is possible to measure the anisotropic deformation behaviour of granular materials. This article initially presents an experimental study of the resilient repeated load response of a compacted clayey natural sand with three fine contents and different water contents. Based on anisotropic behaviour, the non-linear resilient model (Boyce model) is improved by the radial anisotropy coefficient γ ₃ instead of the axial anisotropy coefficient γ ₁. The results from both approaches ( γ ₁ and γ ₃) are compared with the measured volumetric and deviatoric responses. These results confirm the capacity of the improved model to capture the general trend of the experiments. Finally, finite element calculations are performed with CAST3M in order to validate the improvement of the modified Boyce model (from γ ₁ to γ ₃). The modelling results indicate that the modified Boyce model with γ ₃ is more widely available in different water contents and different fine contents for this granular material. Besides, based on the results, the coupled effects of water content and fine content on the deflection of the structures can also be observed.

77 FR 59979 - Pure Magnesium (Granular) From China

Federal Register 2010, 2011, 2012, 2013, 2014

2012-10-01

... (Granular) From China Determination On the basis of the record \\1\\ developed in the subject five-year review... magnesium (granular) from China would be likely to lead to continuation or recurrence of material injury to... China: Investigation No.731-TA- 895 (Second Review). Issued: September 25, 2012. By order of the...

[Comparative investigation of compressive resistance of glass-cermet cements used as a core material in post-core systems].

PubMed

Ersoy, E; Cetiner, S; Koçak, F

1989-09-01

In post-core applications, addition to the cast designs restorations that are performed on fabrication posts with restorative materials are being used. To improve the physical properties of glass-ionomer cements that are popular today, glass-cermet cements have been introduced and those materials have been proposed to be an alternative restorative material in post-core applications. In this study, the compressive resistance of Ketac-Silver as a core material was investigated comparatively with amalgam and composite resins.

Relationship between electrical conductivity anisotropy and fabric anisotropy in granular materials during drained triaxial compressive tests: a numerical approach

NASA Astrophysics Data System (ADS)

Niu, Qifei; Revil, André; Li, Zhaofeng; Wang, Yu-Hsing

2017-07-01

The anisotropy of granular media and its evolution during shearing are important aspects required in developing physics-based constitutive models in Earth sciences. The development of relationships between geoelectrical properties and the deformation of porous media has applications to the monitoring of faulting and landslides. However, such relationships are still poorly understood. In this study, we first investigate the definition of the electrical conductivity anisotropy tensor of granular materials in presence of surface conductivity of the grains. Fabric anisotropy is related to the components of the fabric tensor. We define an electrical anisotropy factor based on the Archie's exponent second-order symmetric tensor m of granular materials. We use numerical simulations to confirm a relationship between the evolution of electrical and fabric anisotropy factors during shearing. To realize the simulations, we build a virtual laboratory in which we can easily perform synthetic experiments. We first simulate drained compressive triaxial tests of loose and dense granular materials (porosity 0.45 and 0.38, respectively) using the discrete element method. Then, the electrical conductivity tensor of a set of deformed synthetic samples is computed using the finite-difference method. The numerical results show that shear strains are responsible for a measurable anisotropy in the bulk conductivity of granular media. The observed electrical anisotropy response, during shearing, is distinct for dense and loose synthetic samples. Electrical and fabric anisotropy factors exhibit however a unique linear correlation, regardless of the shear strain and the initial state (porosity) of the synthetic samples. The practical implication of this finding confirms the usefulness of the electrical conductivity method in studying the fabric tensor of granular media. This result opens the door in using time-lapse electrical resistivity to study non-intrusively the evolution of anisotropy of soils and granular rocks during deformation, for instance during landslides, and to use the evolution of the conductivity tensor to monitor mechanical properties.

On the finite length-scale of compressible shock-waves formed in free-surface flows of dry granular materials down a slope

NASA Astrophysics Data System (ADS)

Faug, Thierry

2017-04-01

The Rankine-Hugoniot jump conditions traditionally describe the theoretical relationship between the equilibrium state on both sides of a shock-wave. They are based on the crucial assumption that the length-scale needed to adjust the equilibrium state upstream of the shock to downstream of it is too small to be of significance to the problem. They are often used with success to describe the shock-waves in a number of applications found in both fluid and solid mechanics. However, the relations based on jump conditions at singular surfaces may fail to capture some features of the shock-waves formed in complex materials, such as granular matter. This study addresses the particular problem of compressible shock-waves formed in flows of dry granular materials down a slope. This problem is for instance relevant to full-scale geophysical granular flows in interaction with natural obstacles or man-made structures, such as topographical obstacles or mitigation dams respectively. Steady-state jumps formed in granular flows and travelling shock-waves produced at the impact of a granular avalanche-flow with a rigid wall are considered. For both situations, new analytical relations which do not consider that the granular shock-wave shrinks into a singular surface are derived, by using balance equations in their depth-averaged forms for mass and momentum. However, these relations need additional inputs that are closure relations for the size and the shape of the shock-wave, and a relevant constitutive friction law. Small-scale laboratory tests and numerical simulations based on the discrete element method are shortly presented and used to infer crucial information needed for the closure relations. This allows testing some predictive aspects of the simple analytical approach proposed for both steady-state and travelling shock-waves formed in free-surface flows of dry granular materials down a slope.

Characterising fabric, force distributions and porosity evolution in sheared granular media

NASA Astrophysics Data System (ADS)

Mair, Karen; Abe, Steffen; Jettestuen, Espen

2014-05-01

Active faults, landslides, subglacial tills and poorly or unconsolidated sands essentially contain accumulations of granular debris that evolve under load. Both the macroscopic motions and the bulk fluid flow characteristics that result are determined by the particular grain scale processes operating in this deformed or transformed granular material. A relevant question is how the local behavior at the individual granular contacts actually sums up, and in particular how the load bearing skeleton (an important expression of connected load) and spatial distribution of pore space (and hence fluid pathways) are linked. Here we investigate the spatial distribution of porosity with granular rearrangements (specifically contact force network characteristics) produced in 3D discrete element models of granular layers under shear. We use percolation measures to identify, characterize, compare and track the evolution of strongly connected contact force networks. We show that specific topological measures used in describing the networks, such as number of contacts and coordination number, are sensitive to grain size distribution of the material as well as loading conditions. In addition we probe the 3D spatial distribution of porosity as a function of increasing strain. Two cases will be considered. The first, a non-fracture regime where configurational changes occur during shear but grain size distribution remains constant. This would be expected for a soil or granular material under relatively low normal loading. Secondly we consider a fragmentation regime where the grain size distributions of the granular material evolve with accumulated strain. This mirrors the scenario for faults or basal shear zones of slides under higher normal stress where comminution is typically a mark of increasing maturity and plays a major role in the poro-perm evolution of the system. We will present the correlated and anti-correlated features appearing in our simulations as well as discussing the triggers and relative persistence of fluid pathway creation versus destruction mechanisms. We will also demonstrate how the individual grain interactions are manifested in the macroscopic sliding behavior we observe.

Self-Structuring of Granular material under Capillary Bulldozing

NASA Astrophysics Data System (ADS)

Dumazer, Guillaume; Sandnes, Bjørnar; Ayaz, Monem; Måløy, Knut Jørgen; Flekkøy, Eirik

2017-06-01

An experimental observation of the structuring of a granular suspension under the progress of a gas/liquid meniscus in a narrow tube is reported here. The granular material is moved and compactifies as a growing accumulation front. The frictional interaction with the confining walls increases until the pore capillary entry pressure is reached. The gas then penetrates the clogged granular packing and a further accumulation front is formed at the far side of the plug. This cyclic process continues until the gas/liquid interface reaches the tube's outlet, leaving a trail of plugs in the tube. Such 1D pattern formation belongs to a larger family of patterning dynamics observed in 2D Hele-Shaw geometry. The cylindrical geometry considered here provides an ideal case for a theoretical modelling for forced granular matter oscillating between a long frictional phase and a sudden viscous fluidization.

Effect of Luting Cements On the Bond Strength to Turkom-Cera All-Ceramic Material

PubMed Central

Al–Makramani, Bandar M. A.; Razak, Abdul A. A.; Abu–Hassan, Mohamed I.; Al–Sanabani, Fuad A.; Albakri, Fahad M.

2018-01-01

BACKGROUND: The selection of the appropriate luting cement is a key factor for achieving a strong bond between prepared teeth and dental restorations. AIM: To evaluate the shear bond strength of Zinc phosphate cement Elite, glass ionomer cement Fuji I, resin-modified glass ionomer cement Fuji Plus and resin luting cement Panavia-F to Turkom-Cera all-ceramic material. MATERIALS AND METHODS: Turkom-Cera was used to form discs 10mm in diameter and 3 mm in thickness (n = 40). The ceramic discs were wet ground, air - particle abraded with 50 - μm aluminium oxide particles and randomly divided into four groups (n = 10). The luting cement was bonded to Turkom-Cera discs as per manufacturer instructions. The shear bond strengths were determined using the universal testing machine at a crosshead speed of 0.5 mm/min. The data were analysed using the tests One Way ANOVA, the nonparametric Kruskal - Wallis test and Mann - Whitney Post hoc test. RESULTS: The shear bond strength of the Elite, Fuji I, Fuji Plus and Panavia F groups were: 0.92 ± 0.42, 2.04 ± 0.78, 4.37 ± 1.18, and 16.42 ± 3.38 MPa, respectively. There was the statistically significant difference between the four luting cement tested (p < 0.05). CONCLUSION: the phosphate-containing resin cement Panavia-F exhibited shear bond strength value significantly higher than all materials tested. PMID:29610618

New Concept Study for Repair of Bomb-Damaged Runways. Volume I. Concept Identification.

DTIC Science & Technology

1979-09-01

Expanded polystyrene beads would be pneumatically mixed with the cement to form a low density material. Initially, the ratio of foam to cement would...the combinations are presented with this concept. PRIMARY MATERIALS 0 Expanded polystyrene foam beads * Graded aggregate * Quick setting cement 61 E-4...probability of success - high ALTERNATE MATERIALS * Expanded polystyrene foam beads * Organic binders Furan Methyl Methacrylate Epoxy Aminos * Graded

Strength and Stiffness Development in Soft Soils: A FESEM aided Soil Microstructure Viewpoint

NASA Astrophysics Data System (ADS)

Wijeyesekera, D. C.; Ho, M. H.; Bai, X.; Bakar, I.

2016-07-01

This paper opens with an overview of the debatable definition of soft soil that goes beyond a (CH) organic / inorganic clay and OH peat to include weakly cemented periglacial deposits of loess and alike. It then outlines the findings obtained from stiffness test on cement-stabilised soft clay. The findings are complemented with a microstructure viewpoint obtained using field emission scanning electron microscope (FESEM). Research also comprised of making cylindrical stabilised clay samples, prepared in the laboratory with various rubber chips contents and cement, and then aged for 28 days. The samples were then subjected to unconfined compressive strength (UCS) test and observations were also made of its microstructure using the FESEM. The impact of the soil microstructure on the stiffness result was studied both with the stabilized soil and also of some of the natural undisturbed loess soils. Sustainability aspect and the potential of the use of rubber chips and sand as additives to cement stabilisation are also discussed. The overall test results indicated that rubber chips and sand contributed to the improvement in unconfined compressive strength (qu). The derogatory influence of moisture on the stiffness of the stabilised clay was studied simultaneously. SEM micrographs are presented that show bonding of cement, rubber chips/ sand and soft clay, granular units and aggregated / agglomerated units in loess. The paper concludes with observations on the dependence of soil microstructure on the soil strength and deformability and even collapsibility of the loess. Current practices adopted as engineering solutions to these challenging soils are outlined.

Surface instabilities in shock loaded granular media

NASA Astrophysics Data System (ADS)

Kandan, K.; Khaderi, S. N.; Wadley, H. N. G.; Deshpande, V. S.

2017-12-01

The initiation and growth of instabilities in granular materials loaded by air shock waves are investigated via shock-tube experiments and numerical calculations. Three types of granular media, dry sand, water-saturated sand and a granular solid comprising PTFE spheres were experimentally investigated by air shock loading slugs of these materials in a transparent shock tube. Under all shock pressures considered here, the free-standing dry sand slugs remained stable while the shock loaded surface of the water-saturated sand slug became unstable resulting in mixing of the shocked air and the granular material. By contrast, the PTFE slugs were stable at low pressures but displayed instabilities similar to the water-saturated sand slugs at higher shock pressures. The distal surfaces of the slugs remained stable under all conditions considered here. Eulerian fluid/solid interaction calculations, with the granular material modelled as a Drucker-Prager solid, reproduced the onset of the instabilities as seen in the experiments to a high level of accuracy. These calculations showed that the shock pressures to initiate instabilities increased with increasing material friction and decreasing yield strain. Moreover, the high Atwood number for this problem implied that fluid/solid interaction effects were small, and the initiation of the instability is adequately captured by directly applying a pressure on the slug surface. Lagrangian calculations with the directly applied pressures demonstrated that the instability was caused by spatial pressure gradients created by initial surface perturbations. Surface instabilities are also shown to exist in shock loaded rear-supported granular slugs: these experiments and calculations are used to infer the velocity that free-standing slugs need to acquire to initiate instabilities on their front surfaces. The results presented here, while in an idealised one-dimensional setting, provide physical understanding of the conditions required to initiate instabilities in a range of situations involving the explosive dispersion of particles.

Dental Glass Ionomer Cements as Permanent Filling Materials? —Properties, Limitations Future Trends

PubMed Central

Lohbauer, Ulrich

2009-01-01

Glass ionomer cements (GICs) are clinically attractive dental materials that have certain unique properties that make them useful as restorative and luting materials. This includes adhesion to moist tooth structures and base metals, anticariogenic properties due to release of fluoride, thermal compatibility with tooth enamel, biocompatibility and low toxicity. The use of GICs in a mechanically loaded situation, however, has been hampered by their low mechanical performance. Poor mechanical properties, such as low fracture strength, toughness and wear, limit their extensive use in dentistry as a filling material in stress-bearing applications. In the posterior dental region, glass ionomer cements are mostly used as a temporary filling material. The requirement to strengthen those cements has lead to an ever increasing research effort into reinforcement or strengthening concepts.

Utilization of flotation wastes of copper slag as raw material in cement production.

PubMed

Alp, I; Deveci, H; Süngün, H

2008-11-30

Copper slag wastes, even if treated via processes such as flotation for metal recovery, still contain heavy metals with hazardous properties posing environmental risks for disposal. This study reports the potential use of flotation waste of a copper slag (FWCS) as iron source in the production of Portland cement clinker. The FWCS appears a suitable raw material as iron source containing >59% Fe(2)O(3) mainly in the form of fayalite (Fe(2)SiO(4)) and magnetite (Fe(3)O(4)). The clinker products obtained using the FWCS from the industrial scale trial operations over a 4-month period were characterised for the conformity of its chemical composition and the physico-mechanical performance of the resultant cement products was evaluated. The data collected for the clinker products produced using an iron ore, which is currently used as the cement raw material were also included for comparison. The results have shown that the chemical compositions of all the clinker products including those of FWCS are typical of a Portland cement clinker. The mechanical performance of the standard mortars prepared from the FWCS clinkers were found to be similar to those from the iron ore clinkers with the desired specifications for the industrial cements e.g. CEM I type cements. Furthermore, the leachability tests (TCLP and SPLP) have revealed that the mortar samples obtained from the FWCS clinkers present no environmental problems while the FWCS could act as the potential source of heavy metal contamination. These findings suggest that flotation wastes of copper slag (FWCS) can be readily utilised as cement raw material due to its availability in large quantities at low cost with the further significant benefits for waste management/environmental practices of the FWCS and the reduced production and processing costs for cement raw materials.

Influence of ferrite phase in alite-calcium sulfoaluminate cements

NASA Astrophysics Data System (ADS)

Duvallet, Tristana Yvonne Francoise

Since the energy crisis in 1970's, research on low energy cements with low CO2- emissions has been increasing. Numerous solutions have been investigated, and the goal of this original research is to create a viable hybrid cement with the components of both Ordinary Portland cement (OPC) and calcium sulfoaluminate cement (CSAC), by forming a material that contains both alite and calcium sulfoaluminate clinker phases. Furthermore, this research focuses on keeping the cost of this material reasonable by reducing aluminum requirements through its substitution with iron. The aim of this work would produce a cement that can use large amounts of red mud, which is a plentiful waste material, in place of bauxite known as an expensive raw material. Modified Bogue equations were established and tested to formulate this novel cement with different amounts of ferrite, from 5% to 45% by weight. This was followed by the production of cement from reagent chemicals, and from industrial by-products as feedstocks (fly ash, red mud and slag). Hydration processes, as well as the mechanical properties, of these clinker compositions were studied, along with the addition of gypsum and the impact of a ferric iron complexing additive triisopropanolamine (TIPA). To summarize this research, the influence of the addition of 5-45% by weight of ferrite phase, was examined with the goal of introducing as much red mud as possible in the process without negatively attenuate the cement properties. Based on this PhD dissertation, the production of high-iron alite-calcium sulfoaluminateferrite cements was proven possible from the two sources of raw materials. The hydration processes and the mechanical properties seemed negatively affected by the addition of ferrite, as this phase was not hydrated entirely, even after 6 months of curing. The usage of TIPA counteracted this decline in strength by improving the ferrite hydration and increasing the optimum amount of gypsum required in each composition. The mechanical data were equivalent to OPC strengths for some compositions with 25% ferrite. This preliminary work constitutes the first research phase of this novel cement and requires additional research for its improvement. Topics for additional research are identified in this dissertation. KEYWORDS: alite, calcium sulfoaluminate, ferrite, low-energy cement, triisopropanolamine.

Mineral resource of the month: hydraulic cement

USGS Publications Warehouse

van Oss, Hendrik G.

2012-01-01

Hydraulic cements are the binders in concrete and most mortars and stuccos. Concrete, particularly the reinforced variety, is the most versatile of all construction materials, and most of the hydraulic cement produced worldwide is portland cement or similar cements that have portland cement as a basis, such as blended cements and masonry cements. Cement typically makes up less than 15 percent of the concrete mix; most of the rest is aggregates. Not counting the weight of reinforcing media, 1 ton of cement will typically yield about 8 tons of concrete.

Granular giant magnetoresistive materials and their ferromagnetic resonances

NASA Astrophysics Data System (ADS)

Rubinstein, M.; Das, B. N.; Koon, N. C.; Chrisey, D. B.; Horwitz, J.

1994-11-01

Ferromagnetic resonance (FMR) can reveal important information on the size and shape of the ferromagnetic particles which are dispersed in granular giant magnetoresistive (GMR) materials. We have investigated the FMR spectra of three different types of granular GMR material, each with different properties: (1) melt-spun ribbons of Fe5Co15Cu80 and Co20Cu80, (2) thin films of Co20Cu80 produced by pulsed laser deposition, and (3) a granular multilayer film of (Cu(50 A)/Fe(10 A)) x 50. We interpret the linewidth of these materials in as simple a manner as possible, as a 'powder pattern' of noninteracting ferromagnetic particles. The linewidth of the melt-spun ribbons is caused by a completely random distribution of crystalline anisotropy axes. The linewidth of these samples is strongly dependent upon the annealing temperature: the linewidth of the as-spun sample is 2.5 kOe (appropriate for single-domain particles) while the linewidth of a melt-spun sample annealed at 900 C for 15 min is 3.8 kOe (appropriate for larger, multidomain particles). The linewidth of the granular multilayer is attributed to a restricted distribution of shape anisotropies, as expected from a discontinuous multilayer, and is only 0.98 kOe with the magnetic field in the plane of the film.

Ferromagnetic-resonance studies of granular giant-magnetoresistive materials

NASA Astrophysics Data System (ADS)

Rubinstein, M.; Das, B. N.; Koon, N. C.; Chrisey, D. B.; Horwitz, J.

1994-07-01

Ferromagnetic resonance (FMR) can reveal important information on the size and shape of the ferromagnetic particles which are dispersed in granular giant magnetoresistive (GMR) materials. We have investigated the FMR spectra of three different types of granular GMR material, each with different properties: (1) melt-spun ribbons of Fe5Co15Cu80 and Co20Cu80, (2) thin films of Co20Cu80 produced by pulsed laser deposition, and (3) a granular multilayer film of [Cu(50 Å)/Fe(10 Å)]×50. We interpret the linewidth of these materials in as simple a manner as possible, as a ``powder pattern'' of noninteracting ferromagnetic particles. The linewidth of the melt-spun ribbons is caused by a completely random distribution of crystalline anisotropy axes. The linewidth of these samples is strongly dependent upon the annealing temperature: the linewidth of the as-spun sample is 2.5 kOe (appropriate for single-domain particles) while the linewidth of a melt-spun sample annealed at 900 °C for 15 min is 4.5 kOe (appropriate for larger, multidomain particles). The linewidth of the granular multilayer is attributed to a restricted distribution of shape anisotropies, as expected from a discontinuous multilayer, and is only 0.98 kOe when the applied magnetic field is in the plane of the film.

The influence of shrinkage-cracking on the drying behaviour of White Portland cement using Single-Point Imaging (SPI).

PubMed

Beyea, S D; Balcom, B J; Bremner, T W; Prado, P J; Cross, A R; Armstrong, R L; Grattan-Bellew, P E

1998-11-01

The removal of water from pores in hardened cement paste smaller than 50 nm results in cracking of the cement matrix due to the tensile stresses induced by drying shrinkage. Cracks in the matrix fundamentally alter the permeability of the material, and therefore directly affect the drying behaviour. Using Single-Point Imaging (SPI), we obtain one-dimensional moisture profiles of hydrated White Portland cement cylinders as a function of drying time. The drying behaviour of White Portland cement, is distinctly different from the drying behaviour of related concrete materials containing aggregates.

Recycled materials in Portland cement concrete

DOT National Transportation Integrated Search

2000-06-01

This report pertains to a comprehensive study involving the use of recycled materials in Portland cement concrete. Three different materials were studied including crushed glass (CG), street sweepings (SS), and recycled concrete (RC). Blast furnace s...

Cement Thickness of Inlay Restorations Made of Lithium Disilicate, Polymer-Infiltrated Ceramic and Nano-Ceramic CAD/CAM Materials Evaluated Using 3D X-Ray Micro-Computed Tomography.

PubMed

Uzgur, Recep; Ercan, Ertuğrul; Uzgur, Zeynep; Çolak, Hakan; Yalçın, Muhammet; Özcan, Mutlu

2016-08-12

To evaluate the marginal and internal cement thicknesses of inlay restorations made of various CAD/CAM materials using 3D X-ray micro-computed tomography (micro-CT) technique. Caries-free extracted mandibular molars (N = 30) with similar size were randomly assigned to three groups (N = 10 per group). Mesio-occlusal-distal (MOD) cavities were prepared, and inlay restorations were obtained by milling out CAD/CAM materials namely, (a) IPS: monolithic lithium disilicate (control), (b) VE: polymer-infiltrated ceramic, and (c) CS: nano-ceramic using a CAM unit. Marginal and internal cement thicknesses were measured using 3D micro-CT. Data were analyzed using 1-way ANOVA and Tukey's tests (alpha = 0.05). The mean marginal and internal cement thickness were not significant in all inlay materials (p > 0.05). Mean marginal cement thickness (μm) was the lowest for the IPS group (67.54 ± 10.16) followed by VE (84.09 ± 3.94) and CS (95.18 ± 10.58) (p > 0.05). The internal cement thickness (μm) was the lowest in the CS group (54.85 ± 6.94) followed by IPS (60.58 ± 9.22) and VE (77.53 ± 12.13) (p > 0.05). Marginal and internal cement thicknesses of MOD inlays made of monolithic lithium disilicate, polymer-infiltrated ceramic, and nano-ceramic CAD/CAM materials were similar and all less than 100 μm, which could be considered clinically acceptable. MOD inlays made of different CAD/CAM materials presented similar cement thickness, less than 100 μm. © 2016 by the American College of Prosthodontists.

Cytotoxicity of a calcium aluminate cement in comparison with other dental cements and resin-based materials.

PubMed

Franz, Alexander; Konradsson, Katarina; König, Franz; Van Dijken, Jan W V; Schedle, Andreas

2006-02-01

The objective of this study was to compare the cytotoxic effects of a calcium aluminate cement with several currently used direct restorative materials. Specimens of three composites (QuiXfil, Tetric Ceram, Filtek Supreme), one zinc phosphate cement (Harvard Cement), one glass ionomer cement (Ketac Molar), and one calcium aluminate cement (DoxaDent), were used fresh or after 7-days' preincubation in cell culture medium at 37 degrees C, pH 7.2. PVC strips for ISO 10993-5 cytotoxicity test were used as positive control and glass specimens as negative control. L-929 fibroblasts (5-ml aliquots, containing 3 x 10(4) cells/ml), cultivated in DMEM with 10% FCS, 1% glutamine, and 1% penicillin/streptomycin at 37 degrees C/5% CO2 and trypsinized, were exposed to the specimens for 72 h. The cells were harvested, centrifuged, and resuspended in 500 microl DMEM and then counted in 500 microl DMEM for 30 s with a flow cytometer at 488 nm. The analysis of variance comparing the six materials showed different influences on L-929 fibroblast cytotoxicity (p <0.0001). The cytotoxicity of all specimens diminished with increasing preincubation time (p <0.0001). Fresh DoxaDent exhibited the lowest cytotoxicity, followed by QuiXfil. Ketac Molar showed the highest cytotoxicity. After 7 days of preincubation, Harvard Cement and Filtek Supreme demonstrated more cytotoxicity than the other materials (p <0.005).

Effect of ultrasonic agitation on push-out bond strength and adaptation of root-end filling materials

PubMed Central

2018-01-01

Objectives This study evaluated the effect of ultrasonic agitation of mineral trioxide aggregate (MTA), calcium silicate-based cement (CSC), and Sealer 26 (S26) on adaptation at the cement/dentin interface and push-out bond strength. Materials and Methods Sixty maxillary canines were divided into 6 groups (n = 10): MTA, S26, and CSC, with or without ultrasonic activation (US). After obturation, the apical portions of the teeth were sectioned, and retrograde cavities were prepared and filled with cement by hand condensation. In the US groups, the cement was activated for 60 seconds: 30 seconds in the mesio-distal direction and 30 seconds in the buccal-lingual direction, using a mini Irrisonic insert coupled with the ultrasound transducer. After the materials set, 1.5-mm thick sections were obtained from the apexes. The presence of gaps and the bond between cement and dentin were analyzed using low-vacuum scanning electron microscopy. Push-out bond strength was measured using a universal testing machine. Results Ultrasonic agitation increased the interfacial adaptation of the cements. The S26 US group showed a higher adaptation value than MTA (p < 0.05). US improved the push-out bond strength for all the cements (p < 0.05). Conclusions The US of retrograde filling cements enhanced the bond to the dentin wall of the root-end filling materials tested. PMID:29765903

Impedance methodology: A new way to characterize the setting reaction of dental cements.

PubMed

Villat, Cyril; Tran, Xuan-Vinh; Tran, V X; Pradelle-Plasse, Nelly; Ponthiaux, Pierre; Wenger, François; Grosgogeat, Brigitte; Colon, Pierre

2010-12-01

Impedance spectroscopy is a non-destructive, quantitative method, commonly used nowadays for industrial research on cement and concrete. The aim of this study is to investigate the interest of impedance spectroscopy in the characterization of setting process of dental cements. Two types of dental cements are used in this experiment: a new Calcium Silicate cement Biodentine™ (Septodont, Saint Maur-des Fossés, France) and a glass ionomer cement resin modified or not (Fuji II(®) LC Improved Capsules and Fuji IX(®) GP Fast set Capsules, GC Corp., Tokyo, Japan). The conductivity of the dental cements was determined by impedance spectroscopy measurements carried out on dental cement samples immersed in a 0.1M potassium chloride solution (KCl) in a "like-permeation" cell connected to a potentiostat and a Frequency Response Analyzer. The temperature of the solution is 37°C. From the moment of mixing of powder and liquid, the experiments lasted 2 weeks. The results obtained for each material are relevant of the setting process. For GIC, impedance values are stabilized after 5 days while at least 14 days are necessary for the calcium silicate based cement. In accordance with the literature regarding studies of cements and concrete, impedance spectroscopy can characterize ion mobility, porosity and hardening process of dental hydrogel materials. Copyright © 2010 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

Measurements of Acoustic Properties of Porous and Granular Materials and Application to Vibration Control

NASA Technical Reports Server (NTRS)

Park, Junhong; Palumbo, Daniel L.

2004-01-01

For application of porous and granular materials to vibro-acoustic controls, a finite dynamic strength of the solid component (frame) is an important design factor. The primary goal of this study was to investigate structural vibration damping through this frame wave propagation for various poroelastic materials. A measurement method to investigate the vibration characteristics of the frame was proposed. The measured properties were found to follow closely the characteristics of the viscoelastic materials - the dynamic modulus increased with frequency and the degree of the frequency dependence was determined by its loss factor. The dynamic stiffness of hollow cylindrical beams containing porous and granular materials as damping treatment was measured also. The data were used to extract the damping materials characteristics using the Rayleigh-Ritz method. The results suggested that the acoustic structure interaction between the frame and the structure enhances the dissipation of the vibration energy significantly.

The influence of silanized nano-SiO{sub 2} on the hydration of cement paste: NMR investigations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bede, A., E-mail: Andrea.Bede@phys.utcluj.ro; Pop, A.; Ardelean, I.

2015-12-23

It is known that by adding a small amount of nanoparticles to the cement-based materials a strong influence on the workability, strength and durability is obtained. These characteristics of the material are fundamentally determined by the hydration process taking place after mixing the cement grains with water. In the present study the influence introduced by the addition of nano-silica with silanized surfaces on the hydration process was investigated using low-field nuclear magnetic resonance (NMR) relaxometry. The cement samples were prepared using gray cement at a water-to-cement ratio of 0.4 and a 5% addition of nanosilica. The surface of the nanoparticlesmore » was modified using a coating of Silane A174. The cement pastes were monitored during their standard curing time of 28 days. It was established that, by using unmodified nanosilica particles, an acceleration of the hydration process takes place as compared with the pure cement paste. On the other side, by adding silanized nanoparticles, the dormancy stage significantly extends and the hydration process is slower. This slowing down process could enhance the mechanical strength of cement based materials as a result of a better compaction of the hydrated samples.« less

Open problems in active chaotic flows: Competition between chaos and order in granular materials.

PubMed

Ottino, J. M.; Khakhar, D. V.

2002-06-01

There are many systems where interaction among the elementary building blocks-no matter how well understood-does not even give a glimpse of the behavior of the global system itself. Characteristic for these systems is the ability to display structure without any external organizing principle being applied. They self-organize as a consequence of synthesis and collective phenomena and the behavior cannot be understood in terms of the systems' constitutive elements alone. A simple example is flowing granular materials, i.e., systems composed of particles or grains. How the grains interact with each other is reasonably well understood; as to how particles move, the governing law is Newton's second law. There are no surprises at this level. However, when the particles are many and the material is vibrated or tumbled, surprising behavior emerges. Systems self-organize in complex patterns that cannot be deduced from the behavior of the particles alone. Self-organization is often the result of competing effects; flowing granular matter displays both mixing and segregation. Small differences in either size or density lead to flow-induced segregation and order; similar to fluids, noncohesive granular materials can display chaotic mixing and disorder. Competition gives rise to a wealth of experimental outcomes. Equilibrium structures, obtained experimentally in quasi-two-dimensional systems, display organization in the presence of disorder, and are captured by a continuum flow model incorporating collisional diffusion and density-driven segregation. Several open issues remain to be addressed. These include analysis of segregating chaotic systems from a dynamical systems viewpoint, and understanding three-dimensional systems and wet granular systems (slurries). General aspects of the competition between chaos-enhanced mixing and properties-induced de-mixing go beyond granular materials and may offer a paradigm for other kinds of physical systems. (c) 2002 American Institute of Physics.

Spectroscopy of Loose and Cemented Sulfate-Bearing Soils: Implications for Duricrust on Mars

NASA Astrophysics Data System (ADS)

Cooper, Christopher D.; Mustard, John F.

2002-07-01

The goal of this work is to determine the spectroscopic properties of sulfate in martian soil analogs over the wavelength range 0.3 to 25 μm (which is relevant to existing and planned remotely sensed data sets for Mars). Sulfate is an abundant component of martian soil (up to 9% SO 3 by weight) and apparently exists as a particulate in the soil but also as a cement. Although previous studies have addressed the spectroscopic identity of sulfates on Mars, none have used laboratory mixtures of materials with sulfates at the abundances measured by landed spacecraft, nor have any works considered the effect of salt-cementation on spectral properties of soil materials. For this work we created mixtures of a palagonitic soil (JSC Mars-1) and sulfates (MgSO 4 and CaSO 4·2H 2O). The effects of cementation were determined and separated from the effects of packing and hydration by measuring the samples as loose powders, packed powders, cemented materials, and disaggregated materials. The results show that the presence of particulate sulfate is best observed in the 4-5 μm region. Soils cemented with sulfate exhibit a pronounced restrahlen band between 8 and 9 μm as well as well-defined absorptions in the 4-5 μm region. Cementation effects are distinct from packing effects and disaggregation of cemented samples rapidly diminishes the strength of the restrahlen bands. The results of this study show that sulfate in loose materials is more detectable in the near infrared (4-5 μm) than in the thermal infrared (8-9 μm). However, cemented materials are easily distinguished from loose mixtures in the thermal infrared because of the high values of their absorption coefficient in this region. Together these results suggest that both wavelength regions are important for determining the spatial extent and physical form of sulfates on the surface of Mars.

Delayed photo-activation and addition of thio-urethane: Impact on polymerization kinetics and stress of dual-cured resin cements.

PubMed

Faria-E-Silva, André L; Pfeifer, Carmem S

2017-10-01

1) to determine the moment during the redox polymerization reaction of dual cure cements at which to photo-activate the material in order to reduce the polymerization stress, and 2) to evaluate possible synergistic effects between adding chain transfer agents and delayed photo-activation. The two pastes of an experimental dual-cure material were mixed, and the polymerization kinetics of the redox phase was followed. The moment when the material reached its maximum rate of redox polymerization (MRRP) of cement was determined. The degree of conversion (DC) and maximum rates of polymerization (Rp max ) were assessed for materials where: the photoactivation immediately followed material mixing, at MRRP, 1min before and 1min after MRRP. Thio-urethane (TU) additives were synthesized and added to the cement (20% wt), which was then cured under the same conditions. The polymerization kinetics was evaluated for both cements photo-activated immediately or at MRRP, followed by measurements of polymerization stress, flexural strength (FS) and elastic modulus (EM). Knoop hardness was measured before and after ethanol storage. Photo-activating the cement at or after MRRP reduced the Rp max and the polymerization stress. Addition of TU promoted additional and more significant reduction, while not affecting the Rp max . Greater hardness loss was observed for cements with TU, but the final hardness was similar for all experimental conditions. Addition of TU slightly reduced the EM and did not affect the FS. Delayed photo-activation and addition of TU significantly reduce the polymerization stress of dual-cured cements. Copyright © 2017 Elsevier Ltd. All rights reserved.

Laboratory strength of glass ionomer and zinc phosphate cements.

PubMed

Piwowarczyk, A; Ottl, P; Lauer, H C

2001-09-01

The present in vitro study examined 3 mechanical properties, namely compressive, flexural, and diametral tensile strength, of various commercially available cements and core materials as a function of time after mixing. The examined materials were 2 cermet cements (Ketac Silver [ESPE, Seefeld, Germany] and Chelon Silver [ESPE]), 1 metal-reinforced glass ionomer cement (Miracle Mix [GC Dental Industrial Corp, Tokyo, Japan]), 2 conventional glass ionomer cements (Ketac Bond [ESPE] and Ketac Cem [ESPE]), 1 standard cure zinc phosphate cement (Harvard Cement [Richter and Hoffmann, Berlin, Germany]), and 1 zinc phosphate cement with the addition of 30% silver amalgam alloy powder (Harvard Cement 70% with Dispersalloy 30% [Richter and Hoffmann/Johnson and Johnson, East Windsor, NJ]). Properties were measured using a universal testing machine at 15 minutes, 1 hour, and 24 hours after first mixing. Compressive strengths varied widely between the 3 times of measurement from 5.8 +/- 6.6 MPa for Ketac Cem to 144.3 +/- 10.2 MPa for Ketac Silver. Twenty-four hours after mixing, the Bonferroni test showed significant (p

The Use of Empirical Methods for Testing Granular Materials in Analogue Modelling

PubMed Central

Montanari, Domenico; Agostini, Andrea; Bonini, Marco; Corti, Giacomo; Del Ventisette, Chiara

2017-01-01

The behaviour of a granular material is mainly dependent on its frictional properties, angle of internal friction, and cohesion, which, together with material density, are the key factors to be considered during the scaling procedure of analogue models. The frictional properties of a granular material are usually investigated by means of technical instruments such as a Hubbert-type apparatus and ring shear testers, which allow for investigating the response of the tested material to a wide range of applied stresses. Here we explore the possibility to determine material properties by means of different empirical methods applied to mixtures of quartz and K-feldspar sand. Empirical methods exhibit the great advantage of measuring the properties of a certain analogue material under the experimental conditions, which are strongly sensitive to the handling techniques. Finally, the results obtained from the empirical methods have been compared with ring shear tests carried out on the same materials, which show a satisfactory agreement with those determined empirically. PMID:28772993

3D FEA of cemented glass fiber and cast posts with various dental cements in a maxillary central incisor.

PubMed

Madfa, Ahmed A; Al-Hamzi, Mohsen A; Al-Sanabani, Fadhel A; Al-Qudaimi, Nasr H; Yue, Xiao-Guang

2015-01-01

This study aimed to analyse and compare the stability of two dental posts cemented with four different luting agents by examining their shear stress transfer through the FEM. Eight three-dimensional finite element models of a maxillary central incisor restored with glass fiber and Ni-Cr alloy cast dental posts. Each dental post was luted with zinc phosphate, Panavia resin, super bond C&B resin and glass ionomer materials. Finite element models were constructed and oblique loading of 100 N was applied. The distribution of shear stress was investigated at posts and cement/dentine interfaces using ABAQUS/CAE software. The peak shear stress for glass fiber post models minimized approximately three to four times of those for Ni-Cr alloy cast post models. There was negligible difference in peak of shear stress when various cements were compared, irrespective of post materials. The shear stress had same trend for all cement materials. This study found that the glass fiber dental post reduced the shear stress concentration at interfacial of post and cement/dentine compared to Ni-Cr alloy cast dental post.

Compaction Behavior of Granular Materials

NASA Astrophysics Data System (ADS)

Endicott, Mark R.; Kenkre, V. M.; Glass, S. Jill; Hurd, Alan J.

1996-03-01

We report the results of our recent study of compaction of granular materials. A theoretical model is developed for the description of the compaction of granular materials exemplified by granulated ceramic powders. Its predictions are compared to observations of uniaxial compaction tests of ceramic granules of PMN-PT, spray dried alumina and rutile. The theoretical model employs a volume-based statistical mechanics treatment and an activation analogy. Results of a computer simulation of random packing of discs in two dimensions are also reported. The effect of type of particle size distribution and other parameters of that distribution on the calculated quantities are discussed. We examine the implications of the results of the simulation for the theoretical model.

Microwave processing of cement and concrete materials – towards an industrial reality?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Buttress, Adam, E-mail: adam.buttress@nottingham.ac.uk; Jones, Aled; Kingman, Sam

2015-02-15

Each year a substantial body of literature is published on the use of microwave to process cement and concrete materials. Yet to date, very few if any have lead the realisation of a commercial scale industrial system and is the context under which this review has been undertaken. The state-of the–art is evaluated for opportunities, and the key barriers to the development of new microwave-based processing techniques to enhance production, processing and recycling of cement and concrete materials. Applications reviewed include pyro-processing of cement clinker; accelerated curing, non-destructive testing and evaluation (NDT&E), and end-of-life processing including radionuclide decontamination.

Healing in Unconsolidated Granular Earth Materials: a Mechanistic Theory

NASA Astrophysics Data System (ADS)

Lieou, C.; Daub, E. G.; Ecke, R. E.; Johnson, P. A.

2017-12-01

Abstract: Rock materials often display long-time relaxation, commonly termed aging or ``slow dynamics'', after the cessation of acoustic perturbations. In this presentation, we focus on unconsolidated rock materials and propose to explain such nonlinear relaxation through the Shear-Transformation-Zone (STZ) theory of granular media, adapted for small stresses and strains. The theory attributes the observed relaxation to the slow change of positions of constituent grains, and posits that the aging process can be described in three stages: fast recovery before some characteristic time associated with the fast nonlinear plasticity carriers, log-linear recovery of the elastic modulus at intermediate times, and gradual turnover to equilibrium steady-state behavior at long times. We demonstrate good agreement with experiments on aging in granular materials such as simulated fault gouge after an external disturbance.

Cermet cements.

PubMed

McLean, J W

1990-01-01

Cermet ionomer cements are sintered metal/glass powders, which can be made to react with poly(acids). These new cements are significantly more resistant to abrasion than regular glass ionomer cements and are widely accepted as core build-up materials and lining cements. They can strengthen teeth and provide the clinician with an opportunity to treat early dental caries.

40 CFR 60.541 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... facility (parts per million by volume) Dc=density of cement or spray material (grams per liter (lb per... which the tire is mounted. Bead cementing operation means the system that is used to apply cement to the... consists of a cement application station, such as a dip tank, spray booth and nozzles, cement trough and...

Waiting time for coronal preparation and the influence of different cements on tensile strength of metal posts.

PubMed

Oliveira, Ilione Kruschewsky Costa Sousa; Arsati, Ynara Bosco de Oliveira Lima; Basting, Roberta Tarkany; França, Fabiana Mantovani Gomes

2012-01-01

This study aimed to assess the effect of post-cementation waiting time for core preparation of cemented cast posts and cores had on retention in the root canal, using two different luting materials. Sixty extracted human canines were sectioned 16 mm from the root apex. After cast nickel-chromium metal posts and cores were fabricated and luted with zinc phosphate (ZP) cement or resin cement (RC), the specimens were divided into 3 groups (n = 10) according to the waiting time for core preparation: no preparation (control), 15 minutes, or 1 week after the core cementation. At the appropriate time, the specimens were subjected to a tensile load test (0.5 mm/min) until failure. Two-way ANOVA (time versus cement) and the Tukey tests (P < 0.05) showed significantly higher (P < 0.05) tensile strength values for the ZP cement groups than for the RC groups. Core preparation and post-cementation waiting time for core recontouring did not influence the retention strength. ZP was the best material for intraradicular metal post cementation.

Preparation of fly ash-granulated blast furnace slag-carbide slag binder and application in total tailings paste backfill

NASA Astrophysics Data System (ADS)

Li, Chao; Hao, Ya-fei; Zhao, Feng-qing

2018-03-01

Based on activation and synergistic effect among various materials, a low-cost mine backfill cementing material, FGC binder, was prepared by using fly ash, granulated blast-furnace slag (GBFS), carbide slag and composite activator. The proper proportioning of FGC binder is obtained by response surface experiment optimization method: fly ash 62 %, GBFS 20 %, carbide slag 8 % and compound activators 10 %. Adjusting the material ratio obtains different cementing material which could satisfy requirements of different mined-out areas. With the mass ratio of cementing material and tailings 1:4∼1:8, the concentration of total solid 70 %, the compressive strength values of total tailings filling body at 28 d reaches 1.64∼4.14 MPa, and the backfilling cost is 20 % lower than using OPC cement.

A Comparative Evaluation of Sorption, Solubility, and Compressive Strength of Three Different Glass Ionomer Cements in Artificial Saliva: An in vitro Study

PubMed Central

Bhatia, Hind P; Sood, Shveta; Sharma, Naresh

2017-01-01

Aim To evaluate and compare the sorption, solubility, and compressive strength of three different glass ionomer cements in artificial saliva - type IX glass ionomer cement, silver-reinforced glass ionomer cement, and zirconia-reinforced glass ionomer cement, so as to determine the material of choice for stress-bearing areas. Materials and methods A total of 90 cylindrical specimens (4 mm diameter and 6 mm height) were prepared for each material following the manufacturer’s instructions. After subjecting the specimens to thermocycling, 45 specimens were immersed in artificial saliva for 24 hours for compressive strength testing under a universal testing machine, and the other 45 were evaluated for sorption and solubility, by first weighing them by a precision weighing scale (W1), then immersing them in artificial saliva for 28 days and weighing them (W2), and finally dehydrating in an oven for 24 hours and weighing them (W3). Results Group III (zirconomer) shows the highest compressive strength followed by group II (Miracle Mix) and least compressive strength is seen in group I (glass ionomer cement type IX-Extra) with statistically significant differences between the groups. The sorption and solubility values in artificial saliva were highest for glass ionomer cement type IX - Extra-GC (group I) followed by zirconomer-Shofu (group III), and the least value was seen for Miracle Mix-GC (group II). Conclusion Zirconia-reinforced glass ionomer cement is a promising dental material and can be used as a restoration in stress-bearing areas due to its high strength and low solubility and sorption rate. It may be a substitute for silver-reinforced glass ionomer cement due to the added advantage of esthetics. Clinical significance This study provides vital information to pediatric dental surgeons on relatively new restorative materials as physical and mechanical properties of the new material are compared with conventional materials to determine the best suited material in terms of durability, strength and dimensional stability. This study will boost confidence among dental surgeons in terms of handling characteristics, cost effectiveness and success rate. This study will help clinically and scientifically; pediatric dental surgeons to use this material in stress-bearing areas in pediatric patients. How to cite this article Bhatia HP, Singh S, Sood S, Sharma N. A Comparative Evaluation of Sorption, Solubility, and Com-pressive Strength of Three Different Glass Ionomer Cements in Artificial Saliva: An in vitro Study. Int J Clin Pediatr Dent 2017;10(1):49-54. PMID:28377656

Porcelain thickness and cement shade effects on the colour and translucency of porcelain veneering materials.

PubMed

Kürklü, Duygu; Azer, Shereen S; Yilmaz, Burak; Johnston, William M

2013-11-01

Purposes of this in vitro study include evaluating colour changes in combinations of feldspathic porcelain and cement resulting from different thicknesses of porcelain and different shades of composite luting agent, and evaluating relative translucency parameter (RTP) values. Porcelain discs of shade A1 at nominal thicknesses of 0.5 and 1.0mm were bonded to cements of three shades in a factorial design. Colours were calculated for CIE D65 Illuminant and Standard Human Observer on black, grey and white backings. A colour difference (CD) was calculated of each possible pair of different porcelain thickness values for the same cement shade and each possible pair of different cement shades for the same porcelain thickness. RTP was analyzed by ANOVA and selected pairwise comparisons. All mean CDs studied were perceptible and most were at or greater than the clinical acceptability threshold, with the notable exception that the mean CDs and their confidence limits were below the clinical acceptability threshold for a change in porcelain thickness when utilizing the Clear cement shade. Variation in the shade of the resin luting cement will result in CDs which are near or beyond clinical acceptability. A decrease in porcelain thickness did significantly increase RTP when bonded to the resin cement shades studied. Changes in porcelain thickness or cement shade may adversely affect basic aesthetic properties of these materials. Development of methods for analyzing aesthetic effects over greater ranges of thickness for these materials would improve the prognosis for using these materials. Copyright © 2013 Elsevier Ltd. All rights reserved.

Cement manufacture and the environment - Part I: Chemistry and technology

USGS Publications Warehouse

Van Oss, H. G.; Padovani, A.C.

2002-01-01

Hydraulic (chiefly portland) cement is the binding agent in concrete and mortar and thus a key component of a country's construction sector. Concrete is arguably the most abundant of all manufactured solid materials. Portland cement is made primarily from finely ground clinker, which itself is composed dominantly of hydraulically active calcium silicate minerals formed through high-temperature burning of limestone and other materials in a kiln. This process requires approximately 1.7 tons of raw materials perton of clinker produced and yields about 1 ton of carbon dioxide (CO2) emissions, of which calcination of limestone and the combustion of fuels each contribute about half. The overall level of CO2 output makes the cement industry one of the top two manufacturing industry sources of greenhouse gases; however, in many countries, the cement industry's contribution is a small fraction of that from fossil fuel combustion by power plants and motor vehicles. The nature of clinker and the enormous heat requirements of its manufacture allow the cement industry to consume a wide variety of waste raw materials and fuels, thus providing the opportunity to apply key concepts of industrial ecology, most notably the closing of loops through the use of by-products of other industries (industrial symbiosis). In this article, the chemistry and technology of cement manufacture are summarized. In a forthcoming companion article (part II), some of the environmental challenges and opportunities facing the cement industry are described. Because of the size and scope of the U.S. cement industry, the analysis relies primarily on data and practices from the United States.

Analyses of heavy metals in mineral trioxide aggregate and Portland cement.

PubMed

Schembri, Matthew; Peplow, George; Camilleri, Josette

2010-07-01

Portland cement is used in the construction industry as a binder in concrete. It is manufactured from chalk, limestone, and clay, which are clinkered at very high temperatures and ground with gypsum to form Portland cement. The raw materials and the manufacturing process can result in the inclusion of heavy metals in Portland cement. Portland cement with a four to one addition of bismuth oxide is marketed as mineral trioxide aggregate (MTA), which is used mainly as a dental material. Heavy metal inclusion can be of concern because MTA is in contact with hard and soft tissues. Measurements of arsenic, lead, and chromium in hydrated gray and white Portland cement, ProRoot MTA, and MTA Angelus were conducted with graphite furnace atomic absorption spectrophotometry after acid digestion on the hydrated material. The leaching of the metal ions from the solid material in water and simulated body fluid (SBF) was also determined. All cement types showed high relative values of leached chromium compared with arsenic and lead in both the total metal content and leached species. The gray Portland cement showed the highest total amount of metal. The white Portland and both MTAs had lower values for all the leached metal ions. Both MTAs released more arsenic than the amount specified in ISO 9917-1 (2007). Portland cements and MTAs showed evidence of heavy metals in the acid-soluble form as well as leaching in deionized water and SBF. MTA contained levels of arsenic higher than the safe limit specified by the ISO 9917-1 (2007). Copyright 2010 American Association of Endodontists. Published by Elsevier Inc. All rights reserved.

Methods and compositions using calcium carbonate

DOEpatents

Constantz, Brent R [Portola Valley, CA; Farsad, Kasra [San Jose, CA; Camire, Chris [San Jose, CA; Patterson, Joshua [Freedom, CA; Ginder-Vogel, Matthew [Los Gatos, CA; Yaccato, Karin [San Jose, CA; Stagnaro, John [Santa Clara, CA; Devenney, Martin [Mountain View, CA; Ries, Justin [Chapel Hill, NC

2012-03-20

Provided herein are compositions and methods including hydraulic cement, supplementary cementitious material, and/or self-cementing material. Methods for making the compositions and using the compositions are provided.

Methods and compositions using calcium carbonate

DOEpatents

Constantz, Brent R [Portola Valley, CA; Farsad, Kasra [San Jose, CA; Camire, Chris [San Jose, CA; Patterson, Joshua [Freedom, CA; Fernandez, Miguel [San Jose, CA; Yaccato, Karin [San Jose, CA; Thatcher, Ryan [Sunnyvale, CA; Stagnaro, John [Santa Clara, CA; Chen, Irvin [Santa Clara, CA; Omelon, Sidney [Willowdale, CA; Hodson, Keith [Palo Alto, CA; Clodic, Laurence [Sunnyvale, CA; Geramita, Katharine [Seattle, CA; Holland, Terence C [Auburn Township, OH; Ries, Justin [Chapel Hill, NC

2012-02-14

Provided herein are compositions and methods including hydraulic cement, supplementary cementitious material, and/or self-cementing material. Methods for making the compositions and using the compositions are provided.

Methods and compositions using calcium carbonate

DOEpatents

Constantz, Brent R [Portola Valley, CA; Farsad, Kasra [San Jose, CA; Camire, Chris [San Jose, CA; Chen, Irvin [San Jose, CA

2011-04-12

Provided herein are compositions and methods including hydraulic cement, supplementary cementitious material, and/or self-cementing material. Methods for making the compositions and using the compositions are provided.

Methods and compositions using calcium carbonate

DOEpatents

Constantz, Brent R [Portola Valley, CA; Farsad, Kasra [San Jose, CA; Camire, Chris [San Jose, CA; Chen, Irvin [Santa Clara, CA; Ginder-Vogel, Matthew [Los Gatos, CA; Fernandez, Miguel [San Jose, CA

2012-05-15

Provided herein are compositions and methods including hydraulic cement, supplementary cementitious material, and/or self-cementing material. Methods for making the compositions and using the compositions are provided.

Methods and compositions using calcium carbonate

DOEpatents

Constantz, Brent R [Portola Valley, CA; Farsad, Kasra [San Jose, CA; Camire, Chris [San Jose, CA; Patterson, Joshua [Freedom, CA; Ginder-Vogel, Matthew [Los Gatos, CA; Yaccato, Karin [San Jose, CA; Stagnaro, John [Santa Clara, CA; Devenney, Martin [Mountain View, CA; Ries, Justin [Chapel Hill, NC

2011-11-22

Provided herein are compositions and methods including hydraulic cement, supplementary cementitious material, and/or self-cementing material. Methods for making the compositions and using the compositions are provided.

Methods and compositions using calcium carbonate

DOEpatents

Chen, Irvin; Fernandez, Miguel; Patterson, Joshua; Devenney, Martin

2015-01-13

Provided herein are compositions and methods including hydraulic cement, supplementary cementitious material, and/or self-cementing material. Methods for making the compositions and using the compositions are provided.

Methods and compositions using calcium carbonate

DOEpatents

Chen, Irvin; Fernandez, Miguel; Patterson, Joshua; Devenney, Martin

2015-06-16

Provided herein are compositions and methods including hydraulic cement, supplementary cementitious material, and/or self-cementing material. Methods for making the compositions and using the compositions are provided.

An Experimental Investigation on the Generation of a Stable Arch in Granular Materials Using a Developed Trapdoor Apparatus

NASA Astrophysics Data System (ADS)

Ahmadi, Ali; Seyedi Hosseininia, Ehsan

2017-06-01

This paper discusses the formation of stable arches in granular materials by using a series of laboratory tests. To this aim, a developed trapdoor apparatus is designed to find dimensions of arches formed over the door in cohesionless aggregates. This setup has two new important applications. In order to investigate the maximum width of the opening generated exactly on the verge of failure, the door can be open to an arbitrary size. In addition, the box containing granular materials (or base angle) is able to be set on optional angles from zero to 90 degrees with respect to the horizontal. Therefore, it is possible to understand the effect of different levels of gravity accelerations on the formed arches. It is observed that for all tested granular materials, increasing the door size and decreasing the base angle, both cause to increase the width and height of the arch. Moreover, the shape of all arches is governed by a parabola. Furthermore, the maximum door width is approximately five to 8.6 times the particle size, depending on the internal friction angle of materials and the base angle.

Mechanics of Granular Materials-3 (MGM-3)

NASA Technical Reports Server (NTRS)

Sture, Stein; Alshibi, Khalid; Guynes, Buddy (Technical Monitor)

2002-01-01

Scientists are going to space to understand how earthquakes and other forces disturb grains of soil and sand. They will examine how the particle arrangement and structure of soils, grains and powders are changed by external forces and gain knowledge about the strength, stiffness and volume changes properties of granular materials at low pressures. The Mechanics of Granular Materials (MGM) experiment uses the microgravity of orbit to test sand columns under conditions that cannot be obtained in experiments on Earth. Research can only go so far on Earth because gravity-induced stresses complicate the analysis and change loads too quickly for detailed analysis. This new knowledge will be applied to improving foundations for buildings, managing undeveloped land, and handling powdered and granular materials in chemical, agricultural, and other industries. NASA wants to understand the way soil behaves under different gravity levels so that crews can safely build habitats on Mars and the Moon. Future MGM experiments will benefit from extended tests aboard the International Space Station, including experiments under simulated lunar and Martian gravity in the science centrifuge.

Visualizing Perturbation Decay in Shocked Granular Materials

NASA Astrophysics Data System (ADS)

Cooper, Marcia; Vogler, Tracy

2017-06-01

A new experiment continuously visualizing shock wave perturbation decay through an increasing thickness of granular material has been tested with a gas gun. The experiment confines powders of either tungsten carbide or cerium oxide into a wedge geometry formed by tilting the downstream observation window, plated with a reflective aluminum film, at a shallow angle from the driver plate. The driver is machined with a sinusoidal wavy pattern for incident shock wave perturbation. After projectile impact, the perturbed shock wave passes through the granular material, first emerging at the wedge toe. Image sequences collected at 5 MHz of reflectivity loss at the plated window-granular material interface capture the spatial variation in wave propagation with increasing sample thickness. Extracting the evolving wavy pattern from the images determines the temporal perturbation amplitude. The data are compared to continuum and mesoscale simulations in normalized terms of perturbation amplitude and wavelength. Sandia National Laboratories is a multi-mission laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

Mechanics of Granular Materials (MGM) Test Cell

NASA Technical Reports Server (NTRS)

1998-01-01

A test cell for Mechanics of Granular Materials (MGM) experiment is shown approximately 20 and 60 minutes after the start of an experiment on STS-89. Sand and soil grains have faces that can cause friction as they roll and slide against each other, or even cause sticking and form small voids between grains. This complex behavior can cause soil to behave like a liquid under certain conditions such as earthquakes or when powders are handled in industrial processes. Mechanics of Granular Materials (MGM) experiments aboard the Space Shuttle use the microgravity of space to simulate this behavior under conditons that carnot be achieved in laboratory tests on Earth. MGM is shedding light on the behavior of fine-grain materials under low effective stresses. Applications include earthquake engineering, granular flow technologies (such as powder feed systems for pharmaceuticals and fertilizers), and terrestrial and planetary geology. Nine MGM specimens have flown on two Space Shuttle flights. Another three are scheduled to fly on STS-107. The principal investigator is Stein Sture of the University of Colorado at Boulder. Credit: NASA/Marshall Space Flight Center (MSFC)

Mechanics of Granular Materials Test Cell

NASA Technical Reports Server (NTRS)

1998-01-01

A test cell for Mechanics of Granular Materials (MGM) experiment is shown from all three sides by its video camera during STS-89. Sand and soil grains have faces that can cause friction as they roll and slide against each other, or even cause sticking and form small voids between grains. This complex behavior can cause soil to behave like a liquid under certain conditions such as earthquakes or when powders are handled in industrial processes. Mechanics of Granular Materials (MGM) experiments aboard the Space Shuttle use the microgravity of space to simulate this behavior under conditons that carnot be achieved in laboratory tests on Earth. MGM is shedding light on the behavior of fine-grain materials under low effective stresses. Applications include earthquake engineering, granular flow technologies (such as powder feed systems for pharmaceuticals and fertilizers), and terrestrial and planetary geology. Nine MGM specimens have flown on two Space Shuttle flights. Another three are scheduled to fly on STS-107. The principal investigator is Stein Sture of the University of Colorado at Boulder. Credit: NASA/Marshall Space Flight Center (MSFC)

Computational Modeling of Sinkage of Objects into Porous Bed under Cyclic Loading

NASA Astrophysics Data System (ADS)

Sheikh, B.; Qiu, T.; Liu, X.

2017-12-01

This work is a companion of another abstract submitted to this session on the computational modeling for the prediction of underwater munitions. In the other abstract, the focus is the hydrodynamics and sediment transport. In this work, the focus is on the geotechnical aspect and granular material behavior when the munitions interact with the porous bed. The final goal of the project is to create and utilize a comprehensive modeling framework, which integrates the flow and granular material models, to simulate and investigate the motion of the munitions. In this work, we present the computational modeling of one important process: the sinkage of rigid-body objects into porous bed under cyclic loading. To model the large deformation of granular bed materials around sinking objects under cyclic loading, a rate-independent elasto-plastic constitutive model is implemented into a Smoothed Particle Hydrodynamics (SPH) model. The effect of loading conditions (e.g., amplitude and frequency of shaking), object properties (e.g., geometry and density), and granular bed material properties (e.g., density) on object singkage is discussed.

Vesta and low gravity impact mixing

NASA Astrophysics Data System (ADS)

Hoffmann, Martin; Nathues, Andreas; Vincent, Jean-Baptiste; Sierks, Holger

2013-04-01

Re-impacting material in the velocity range of a few meters per second to a couple of hundred meters per second encounters the surface of Vesta. Studying Vesta's ejecta blankets, this specific constraint has to be taken into account. As on other planetary bodies, young craters are characterized by ray patterns. Combining this information with the evidence of Vesta's unique compaction patterns, the kinematics of the deposition process and its consequences for the spectral properties can be studied. We attempt to tackle the following questions: From which depth of a primary crater and to which extent does ejected material contribute to the mixing of surface material? What are the consequences for the local morphology and a global layer of regolith? Experiments of slow impacts into granular material resulted in the following significant effects: 1) Different depth to diameter ratios, and different profiles of the impact crater have been found, indicating transition from three dimensional interaction to surface effects. 2) The inner surfaces as well as their ejecta blanket showed quite different mixtures of material from different depths of the target area. These are interpreted as the result of pattern formation, slope and boundary effects. 3) At sufficiently low velocity and suitable projectile density the transition from inelastic to elastic interaction has been observed. 4) Between the elastic response of very slow impacts and a violent irregular agitation of the material by faster impacts, a regime of de-voiding and hence of compaction has been observed. 5) The action of force chains (Daniels et al. 2004, Rivas et al. 2011) became apparent inside the granular material, which efficiently trap energy (Daraio et al. 2006) and lead to the ray system. These results confirm and expand previous experimental, simulated and theoretically investigated evidence on the behavior of mobilized granular material. As already demonstrated by Cook and Mortensen (1967), low velocity impacts into granular material lead to anything but a simple crater morphology. Unusual scaling laws (Uehara et al. 2003) and much more diverse phase patterns than in ordinary solid media have to be taken into account, if a consistent interpretation of the formation of a crater in very deep regolith is attempted (e.g. Opsomer et al. 2011). Additional effects are due to the low gravity environment on a small planetary body like Vesta (Tancredi et al. 2012). On Vesta many apparent counterparts to the results of the experiments can be found, as demonstrated by some examples. On a global scale, the multitude of small, unresolved primary and secondary impacts into the granular regolith contributes to the observed maturity on Vesta even after short time scales. References Cook, M. A., Mortensen, K. S. 1967. Impact cratering in granular materials. J. Appl. Phys. 38, 5125-5128. Daniels, K. E., Coppock, J. E., Behringer, R. P. 2004. Dynamics of meteor impacts. Chaos 14, 84. Daraio, C., Nesterenko, V. F., Herbold, E. B., Jin S. 2006. Energy trapping and shock desintegration in a composite granular medium. Phys. Rev. Lett. 96, 058002, 1-4. Opsomer, E., Ludewig, F., Vandewalle, N. 2011. Phase transitions in vibrated granular systems in microgravity. Phys. Rev. E84, 051306, 1-5. Rivas, N., Ponce, S., Gellet, B., Risso, D., Soto, R., Cordero, P. 2011. Sudden chain energy transfer events in vibrated granular media. Phys. Rev. Lett. 106, 088001, 1-4. Tancredi, G., Maciel, A., Heredia, L., Richeri, P., Nesmachnow, S. 2012. Granular physics in low-gravity environments using discrete element method. Monthly Not. Royal Astron. Soc. 420, 3368-3380. Uehara, J. S., Ambroso, M. A., Ojha, R. J., Durian, D. J. 2003. Low-speed impact craters in loose granular media. Phys. Rev. Lett. 90, 194301, 1-4.

Granular dynamics under shear with deformable boundaries

NASA Astrophysics Data System (ADS)

Geller, Drew; Backhaus, Scott; Ecke, Robert

2015-03-01

Granular materials under shear develop complex patterns of stress as the result of granular positional rearrangements under an applied load. We consider the simple planar shear of a quasi two-dimensional granular material consisting of bi-dispersed nylon cylinders confined between deformable boundaries. The aspect ratio of the gap width to total system length is 50, and the ratio of particle diameter to gap width is about 10. This system, designed to model a long earthquake fault with long range elastic coupling through the plates, is an interesting model system for understanding effective granular friction because it essentially self tunes to the jamming condition owing to the hardness of the grains relative to that of the boundary material, a ratio of more than 1000 in elastic moduli. We measure the differential strain displacements of the plates, the inhomogeneous stress distribution in the plates, the positions and angular orientations of the individual grains, and the shear force, all as functions of the applied normal stress. There is significant stick-slip motion in this system that we quantify through our quantitative measurements of both the boundary and the grain motion, resulting in a good characterization of this sheared 2D hard sphere system.

The contemporary cement cycle of the United States

USGS Publications Warehouse

Kapur, A.; Van Oss, H. G.; Keoleian, G.; Kesler, S.E.; Kendall, A.

2009-01-01

A country-level stock and flow model for cement, an important construction material, was developed based on a material flow analysis framework. Using this model, the contemporary cement cycle of the United States was constructed by analyzing production, import, and export data for different stages of the cement cycle. The United States currently supplies approximately 80% of its cement consumption through domestic production and the rest is imported. The average annual net addition of in-use new cement stock over the period 2000-2004 was approximately 83 million metric tons and amounts to 2.3 tons per capita of concrete. Nonfuel carbon dioxide emissions (42 million metric tons per year) from the calcination phase of cement manufacture account for 62% of the total 68 million tons per year of cement production residues. The end-of-life cement discards are estimated to be 33 million metric tons per year, of which between 30% and 80% is recycled. A significant portion of the infrastructure in the United States is reaching the end of its useful life and will need to be replaced or rehabilitated; this could require far more cement than might be expected from economic forecasts of demand for cement. ?? 2009 Springer Japan.

Characterization of composite materials based on cement-ceramic powder blended binder

NASA Astrophysics Data System (ADS)

Kulovaná, Tereza; Pavlík, Zbyšek

2016-06-01

Characterization of newly developed composite mortars with incorporated ceramic powder coming from precise brick cutting as partial Portland cement replacement up to 40 mass% is presented in the paper. Fine ceramic powder belongs to the pozzolanic materials. Utilization of pozzolanic materials is accompanied by lower request on energy needed for Portland clinker production which generally results in lower production costs of blended binder and lower CO2 emission. In this paper, the ceramic powder is used in cement based mortar composition in amount of 8, 16, 24, 32, and 40 mass% of cement. Chemical composition of ceramic powder is analyzed by X-Ray Fluorescence and X-Ray Diffraction. The particle size distribution of ceramics is accessed on laser diffraction principle. For 28 days cured mortar samples, basic physical and mechanical properties are experimentally determined. The obtained results demonstrate that ceramic powder has potential to replace a part of Portland cement in composition of cement based composites and to reduce negative environmental impact of their production.

Characterization of composite materials based on cement-ceramic powder blended binder

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kulovaná, Tereza; Pavlík, Zbyšek

Characterization of newly developed composite mortars with incorporated ceramic powder coming from precise brick cutting as partial Portland cement replacement up to 40 mass% is presented in the paper. Fine ceramic powder belongs to the pozzolanic materials. Utilization of pozzolanic materials is accompanied by lower request on energy needed for Portland clinker production which generally results in lower production costs of blended binder and lower CO{sub 2} emission. In this paper, the ceramic powder is used in cement based mortar composition in amount of 8, 16, 24, 32, and 40 mass% of cement. Chemical composition of ceramic powder is analyzedmore » by X-Ray Fluorescence and X-Ray Diffraction. The particle size distribution of ceramics is accessed on laser diffraction principle. For 28 days cured mortar samples, basic physical and mechanical properties are experimentally determined. The obtained results demonstrate that ceramic powder has potential to replace a part of Portland cement in composition of cement based composites and to reduce negative environmental impact of their production.« less

Granular-front formation in free-surface flow of concentrated suspensions

NASA Astrophysics Data System (ADS)

Leonardi, Alessandro; Cabrera, Miguel; Wittel, Falk K.; Kaitna, Roland; Mendoza, Miller; Wu, Wei; Herrmann, Hans J.

2015-11-01

A granular front emerges whenever the free-surface flow of a concentrated suspension spontaneously alters its internal structure, exhibiting a higher concentration of particles close to its front. This is a common and yet unexplained phenomenon, which is usually believed to be the result of fluid convection in combination with particle size segregation. However, suspensions composed of uniformly sized particles also develop a granular front. Within a large rotating drum, a stationary recirculating avalanche is generated. The flowing material is a mixture of a viscoplastic fluid obtained from a kaolin-water dispersion with spherical ceramic particles denser than the fluid. The goal is to mimic the composition of many common granular-fluid materials, such as fresh concrete or debris flow. In these materials, granular and fluid phases have the natural tendency to separate due to particle settling. However, through the shearing caused by the rotation of the drum, a reorganization of the phases is induced, leading to the formation of a granular front. By tuning the particle concentration and the drum velocity, it is possible to control this phenomenon. The setting is reproduced in a numerical environment, where the fluid is solved by a lattice-Boltzmann method, and the particles are explicitly represented using the discrete element method. The simulations confirm the findings of the experiments, and provide insight into the internal mechanisms. Comparing the time scale of particle settling with the one of particle recirculation, a nondimensional number is defined, and is found to be effective in predicting the formation of a granular front.

Granular-front formation in free-surface flow of concentrated suspensions.

PubMed

Leonardi, Alessandro; Cabrera, Miguel; Wittel, Falk K; Kaitna, Roland; Mendoza, Miller; Wu, Wei; Herrmann, Hans J

2015-11-01

A granular front emerges whenever the free-surface flow of a concentrated suspension spontaneously alters its internal structure, exhibiting a higher concentration of particles close to its front. This is a common and yet unexplained phenomenon, which is usually believed to be the result of fluid convection in combination with particle size segregation. However, suspensions composed of uniformly sized particles also develop a granular front. Within a large rotating drum, a stationary recirculating avalanche is generated. The flowing material is a mixture of a viscoplastic fluid obtained from a kaolin-water dispersion with spherical ceramic particles denser than the fluid. The goal is to mimic the composition of many common granular-fluid materials, such as fresh concrete or debris flow. In these materials, granular and fluid phases have the natural tendency to separate due to particle settling. However, through the shearing caused by the rotation of the drum, a reorganization of the phases is induced, leading to the formation of a granular front. By tuning the particle concentration and the drum velocity, it is possible to control this phenomenon. The setting is reproduced in a numerical environment, where the fluid is solved by a lattice-Boltzmann method, and the particles are explicitly represented using the discrete element method. The simulations confirm the findings of the experiments, and provide insight into the internal mechanisms. Comparing the time scale of particle settling with the one of particle recirculation, a nondimensional number is defined, and is found to be effective in predicting the formation of a granular front.

Current perspectives of bio-ceramic technology in endodontics: calcium enriched mixture cement - review of its composition, properties and applications

PubMed Central

Nawal, Ruchika Roongta; Talwar, Sangeeta; Verma, Mahesh

2015-01-01

Advancements in bio-ceramic technology has revolutionised endodontic material science by enhancing the treatment outcome for patients. This class of dental materials conciliates excellent biocompatibility with high osseoconductivity that render them ideal for endodontic care. Few recently introduced bio-ceramic materials have shown considerable clinical success over their early generations in terms of good handling characteristics. Calcium enriched mixture (CEM) cement, Endosequence sealer, and root repair materials, Biodentine and BioAggregate are the new classes of bio-ceramic materials. The aim of this literature review is to present investigations regarding properties and applications of CEM cement in endodontics. A review of the existing literature was performed by using electronic and hand searching methods for CEM cement from January 2006 to December 2013. CEM cement has a different chemical composition from that of mineral trioxide aggregate (MTA) but has similar clinical applications. It combines the biocompatibility of MTA with more efficient characteristics, such as significantly shorter setting time, good handling characteristics, no staining of tooth and effective seal against bacterial leakage. PMID:25671207

Radiopacity of different resin-based and conventional luting cements compared to human and bovine teeth.

PubMed

Pekkan, Gürel; Ozcan, Mutlu

2012-02-03

This study evaluated the radiopacity of different resin-based luting materials and compared the results to human and bovine dental hard tissues. Disc specimens (N=130, n=10 per group) (diameter: 6 mm, thickness: 1 mm) were prepared from 10 resin-based and 3 conventional luting cements. Human canine dentin (n=10), bovine enamel (n=10), bovine dentin (n=10) and Aluminium (Al) step wedge were used as references. The optical density values of each material were measured from radiographic images using a transmission densitometer. Al step wedge thickness and optical density values were plotted and equivalent Al thickness values were determined for radiopacity measurements of each material. The radiopacity values of conventional cements and two resin luting materials (Rely X Unicem and Variolink II), were significantly higher than that of bovine enamel that could be preferred for restorations cemented on enamel. Since all examined resin-based luting materials showed radiopacity values equivalent to or greater than that of human and bovine dentin, they could be considered suitable for the restorations cemented on dentin.

Modeling Framework for Fracture in Multiscale Cement-Based Material Structures

PubMed Central

Qian, Zhiwei; Schlangen, Erik; Ye, Guang; van Breugel, Klaas

2017-01-01

Multiscale modeling for cement-based materials, such as concrete, is a relatively young subject, but there are already a number of different approaches to study different aspects of these classical materials. In this paper, the parameter-passing multiscale modeling scheme is established and applied to address the multiscale modeling problem for the integrated system of cement paste, mortar, and concrete. The block-by-block technique is employed to solve the length scale overlap challenge between the mortar level (0.1–10 mm) and the concrete level (1–40 mm). The microstructures of cement paste are simulated by the HYMOSTRUC3D model, and the material structures of mortar and concrete are simulated by the Anm material model. Afterwards the 3D lattice fracture model is used to evaluate their mechanical performance by simulating a uniaxial tensile test. The simulated output properties at a lower scale are passed to the next higher scale to serve as input local properties. A three-level multiscale lattice fracture analysis is demonstrated, including cement paste at the micrometer scale, mortar at the millimeter scale, and concrete at centimeter scale. PMID:28772948

Polymer-cement interactions towards improved wellbore cement fracture sealants

NASA Astrophysics Data System (ADS)

Beckingham, B. S.; Iloejesi, C.; Minkler, M. J.; Schindler, A. K.; Beckingham, L. E.

2017-12-01

Carbon capture, utilization, and storage (CCUS) in deep geologic formations is a promising means of reducing point source emissions of CO2. In these systems, CO2 is captured at the source and then injected to be utilized (eg. in enhanced oil recovery or as a working fluid in enhanced geothermal energy plants) or stored in geologic formations such as depleted oil and gas reservoirs or saline aquifers. While CCUS in subsurface systems could aid in reducing atmospheric CO2 emissions, the potential for CO2 leakage from these systems to overlying formations remains a major limitation and poses a significant risk to the security of injected CO2. Thus, improved materials for both initial wellbore isolation and repairing leakage pathways that develop over time are sought. One approach for the repair of cement fractures in wellbore (and other) systems is the injection of polymer materials into the fracture with a subsequent environmentally dependent (temperature, pressure, pH, etc.) densification or solidification. Here, we aim to investigate novel polymer materials for use to repair leaking wellbores in the context of CCUS. We synthesize and fully characterize a series of novel polymer materials and utilize a suite of analysis techniques to examine polymer-cement interactions at a range of conditions (namely temperature, pressure and pH). Initial findings will be leveraged to design novel polymer materials for further evaluation in polymer-cement composite cores, cement fracture healing, and the aging behavior of healed cements.

Complexity in modeling of residual stresses and strains during polymerization of bone cement: effects of conversion, constraint, heat transfer, and viscoelastic property changes.

PubMed

Gilbert, Jeremy L

2006-12-15

Aseptic loosening of cemented joint prostheses remains a significant concern in orthopedic biomaterials. One possible contributor to cement loosening is the development of porosity, residual stresses, and local fracture of the cement that may arise from the in-situ polymerization of the cement. In-situ polymerization of acrylic bone cement is a complex set of interacting processes that involve polymerization reactions, heat generation and transfer, full or partial mechanical constraint, evolution of conversion- and temperature-dependent viscoelastic material properties, and thermal and conversion-driven changes in the density of the cement. Interactions between heat transfer and polymerization can lead to polymerization fronts moving through the material. Density changes during polymerization can, in the presence of mechanical constraint, lead to the development of locally high residual strain energy and residual stresses. This study models the interactions during bone cement polymerization and determines how residual stresses develop in cement and incorporates temperature and conversion-dependent viscoelastic behavior. The results show that the presence of polymerization fronts in bone cement result in locally high residual strain energies. A novel heredity integral approach is presented to track residual stresses incorporating conversion and temperature dependent material property changes. Finally, the relative contribution of thermal- and conversion-dependent strains to residual stresses is evaluated and it is found that the conversion-based strains are the major contributor to the overall behavior. This framework provides the basis for understanding the complex development of residual stresses and can be used as the basis for developing more complex models of cement behavior.

The biocompatibility of modified experimental Portland cements with potential for use in dentistry.

PubMed

Camilleri, J

2008-12-01

To evaluate the biocompatibility of a group of new potential dental materials and their eluants by assessing cell viability. Calcium sulpho-aluminate cement (CSA), calcium fluoro-aluminate cement (CFA) and glass-ionomer cement (GIC; Ketac Molar), used as the control, were tested for biocompatibility. Using a direct test method cell viability was measured quantitatively using alamarBluetrade mark dye, and an indirect test method where cells were grown on material elutions and cell viability was assessed using methyltetrazolium (MTT) assay as recommended by ISO 10 993-Part 5 for in vitro testing. Statistical analysis was performed by analysis of variance and Tukey multi-comparison test method. Elution collected from the prototype cements and the GIC cured for 1 and 7 days allowed high cell activity after 24 h cell exposure, which reduced after 48 h when compared to the nontoxic glass-ionomer control, but increased significantly after 72 h cell contact. Elutions collected after 28 days revealed reduced cell activity at all cell exposure times. Cells placed in direct contact with the prototype materials showed reduced cell activity when compared with the control. Cell growth was poor when seeded in direct contact with the prototype cements. GIC encouraged cell growth after 1 day of contact. The eluted species for all the cements tested exhibited adequate cell viability in the early ages with reduced cell activity at 28 days. Changes in the production of calcium hydroxide as a by-product of cement hydration affect the material biocompatibility adversely.

76 FR 50252 - Gray Portland Cement and Cement Clinker From Japan; Scheduling of an Expedited Five-Year Review...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-08-12

... and Cement Clinker From Japan; Scheduling of an Expedited Five-Year Review Concerning the Antidumping Duty Order on Gray Portland Cement and Cement Clinker From Japan AGENCY: United States International... clinker from Japan would be likely to lead to continuation or recurrence of material injury within a...

Spectroscopic investigation of Ni speciation in hardened cement paste.

PubMed

Vespa, M; Dähn, R; Grolimund, D; Wieland, E; Scheidegger, A M

2006-04-01

Cement-based materials play an important role in multi-barrier concepts developed worldwide for the safe disposal of hazardous and radioactive wastes. Cement is used to condition and stabilize the waste materials and to construct the engineered barrier systems (container, backfill, and liner materials) of repositories for radioactive waste. In this study, Ni uptake by hardened cement paste has been investigated with the aim of improving our understanding of the immobilization process of heavy metals in cement on the molecular level. X-ray absorption spectroscopy (XAS) coupled with diffuse reflectance spectroscopy (DRS) techniques were used to determine the local environment of Ni in cement systems. The Ni-doped samples were prepared at two different water/cement ratios (0.4, 1.3) and different hydration times (1 hour to 1 year) using a sulfate-resisting Portland cement. The metal loadings and the metal salts added to the system were varied (50 up to 5000 mg/kg; NO3(-), SO4(2-), Cl-). The XAS study showed that for all investigated systems Ni(ll) is predominantly immobilized in a layered double hydroxide (LDH) phase, which was corroborated by DRS measurements. Only a minor extent of Ni(ll) precipitates as Ni-hydroxides (alpha-Ni(OH)2 and beta-Ni(OH)2). This finding suggests that Ni-Al LDH, rather than Ni-hydroxides, is the solubility-limiting phase in the Ni-doped cement system.

Universal scaling of permeability through the granular-to-continuum transition

NASA Astrophysics Data System (ADS)

Wadsworth, F. B.; Scheu, B.; Heap, M. J.; Kendrick, J. E.; Vasseur, J.; Lavallée, Y.; Dingwell, D. B.

2015-12-01

Magmas fragment forming a transiently granular material, which can weld back to a fluid-continuum. This process results in dramatic changes in the gas-volume fraction of the material, which impacts the gas permeability. We collate published data for the gas-volume fraction and permeability of volcanic and synthetic materials which have undergone this process to different amounts and note that in all cases there exists a discontinuity in the relationship between these two properties. By discriminating data for which good microstructural information are provided, we use simple scaling arguments to collapse the data in both the still-granular, high gas-volume fraction regime and the fluid-continuum low gas-volume fraction regime such that a universal description can be achieved. We use this to argue for the microstructural meaning of the well-described discontinuity between gas-permeability and gas-volume fraction and to infer the controls on the position of this transition between dominantly granular and dominantly fluid-continuum material descriptions. As a specific application, we consider the transiently granular magma transported through and deposited in fractures in more-coherent magmas, thought to be a primary degassing pathway in high viscosity systems. We propose that our scaling coupled with constitutive laws for densification can provide insights into the longevity of such degassing channels, informing sub-surface pressure modelling at such volcanoes.

Dilatant shear bands in solidifying metals.

PubMed

Gourlay, C M; Dahle, A K

2007-01-04

Compacted granular materials expand in response to shear, and can exhibit different behaviour from that of the solids, liquids and gases of which they are composed. Application of the physics of granular materials has increased the understanding of avalanches, geological faults, flow in hoppers and silos, and soil mechanics. During the equiaxed solidification of metallic alloys, there exists a range of solid fractions where the microstructure consists of a geometrically crowded disordered assembly of crystals saturated with liquid. It is therefore natural to ask if such a microstructure deforms as a granular material and what relevance this might have to solidification processing. Here we show that partially solidified alloys can exhibit the characteristics of a cohesionless granular material, including Reynolds' dilatancy and strain localization in dilatant shear bands 7-18 mean crystals wide. We show that this behaviour is important in defect formation during high pressure die casting of Al and Mg alloys, a global industry that contributes over $7.3 billion to the USA's economy alone and is used in the manufacture of products that include mobile-phone covers and steering wheels. More broadly, these findings highlight the potential to apply the principles and modelling approaches developed in granular mechanics to the field of solidification processing, and also indicate the possible benefits that might be gained from exploring and exploiting further synergies between these fields.

Ultrafine-grained mineralogy and matrix chemistry of olivine-rich chondritic interplanetary dust particles

NASA Technical Reports Server (NTRS)

Rietmeijer, F. J. M.

1989-01-01

Olivine-rich chondritic interplanetary dust particles (IDPs) are an important subset of fluffy chondritic IDPs collected in the earth's stratosphere. Particles in this subset are characterized by a matrix of nonporous, ultrafine-grained granular units. Euhedral single crystals, crystals fragments, and platey single crystals occur dispersed in the matrix. Analytical electron microscopy of granular units reveals predominant magnesium-rich olivines and FeNi-sulfides embedded in amorphous carbonaceous matrix material. The variable ratio of ultrafine-grained minerals vs. carbonaceous matrix material in granular units support variable C/Si ratios, and some fraction of sulfur is associated with carbonaceous matrix material. The high Mg/(Mg+Fe) ratios in granular units is similar to this distribution in P/Comet Halley dust. The chondritic composition of fine-grained, polycrystalline IDPs gradually breaks down into nonchondritic, and ultimately, single mineral compositions as a function of decreased particle mass. The relationship between particle mass and composition in the matrix of olivine-rich chondritic IDPs is comparable with the relationship inferred for P/Comet Halley dust.

Thermal Properties of Consolidated Granular Salt as a Backfill Material

NASA Astrophysics Data System (ADS)

Paneru, Laxmi P.; Bauer, Stephen J.; Stormont, John C.

2018-03-01

Granular salt has been proposed as backfill material in drifts and shafts of a nuclear waste disposal facility where it will serve to conduct heat away from the waste to the host rock. Creep closure of excavations in rock salt will consolidate (reduce the porosity of) the granular salt. This study involved measuring the thermal conductivity and specific heat of granular salt as a function of porosity and temperature to aid in understanding how thermal properties will change during granular salt consolidation accomplished at pressures and temperatures consistent with a nuclear waste disposal facility. Thermal properties of samples from laboratory-consolidated granular salt and in situ consolidated granular salt were measured using a transient plane source method at temperatures ranging from 50 to 250 °C. Additional measurements were taken on a single crystal of halite and dilated polycrystalline rock salt. Thermal conductivity of granular salt decreased with increases in temperature and porosity. Specific heat of granular salt at lower temperatures decreased with increasing porosity. At higher temperatures, porosity dependence was not apparent. The thermal conductivity and specific heat data were fit to empirical models and compared with results presented in the literature. At comparable densities, the thermal conductivities of granular salt samples consolidated hydrostatically in this study were greater than those measured previously on samples formed by quasi-static pressing. Petrographic studies of the consolidated salt indicate that the consolidation method influenced the nature of the porosity; these observations are used to explain the variation of measured thermal conductivities between the two consolidation methods. Thermal conductivity of dilated polycrystalline salt was lower than consolidated salt at comparable porosities. The pervasive crack network along grain boundaries in dilated salt impedes heat flow and results in a lower thermal conductivity compared to hydrostatically consolidated salt.

The Impact of Coal Combustion Fly Ash Used as a Supplemental Cementitious Material on the Leaching of Constituents from Cements and Concretes

EPA Science Inventory

The objective of this report is to compare the leaching of portland cement-based materials that have been prepared with and without coal combustion fly ash to illustrate whether there is evidence that the use of fly ash in cement and concrete products may result in increased leac...

The influence of carbon nanotubes on the properties of water solutions and fresh cement pastes

NASA Astrophysics Data System (ADS)

Leonavičius, D.; Pundienė, I.; Girskas, G.; Pranckevičienė, J.; Kligys, M.; Sinica, M.

2017-10-01

It is known, that the properties of cement-based materials can be significantly improved by addition of carbon nanotubes (CNTs). The dispersion of CNTs is an important process due to an extremely high specific surface area. This aspect is very relevant and is one of the main factors for the successful use of CNTs in cement-based materials. The influence of CNTs in different amounts (from 0 to 0.5 percent) on the pH values of water solutions and fresh cement pastes, and also on rheological properties, flow characteristics, setting time and EXO reaction of the fresh cement pastes was analyzed in this work. It was found that the increment of the amount of CNTs leads to decreased pH values of water solutions and fresh cement pastes, and also increases viscosity, setting times and EXO peak times of fresh cement pastes.

Possibilities of using aluminate cements in high-rise construction

NASA Astrophysics Data System (ADS)

Kaddo, Maria

2018-03-01

The article describes preferable ways of usage of alternative binders for high-rise construction based on aluminate cements. Possible areas of rational use of aluminate cements with the purpose of increasing the service life of materials and the adequacy of the durability of materials with the required durability of the building are analyzed. The results of the structure, shrinkage and physical and mechanical properties of concrete obtained from dry mixes on the base of aluminate cements for self-leveling floors are presented. To study the shrinkage mechanism of curing binders and to evaluate the role of evaporation of water in the development of shrinkage was undertaken experiment with simple unfilled systems: gypsum binder, portland cement and «corrosion resistant high alumina cement + gypsum». Principle possibility of binder with compensated shrinkage based on aluminate cement, gypsum and modern superplasticizers was defined, as well as cracking resistance and corrosion resistance provide durability of the composition.

Application of Granulated Blast Furnace Slag in Cement Composites Exposed to Biogenic Acid Attack

NASA Astrophysics Data System (ADS)

Kovalcikova, M.; Estokova, A.; Luptakova, A.

2015-11-01

The deterioration of cement-based materials used for the civil infrastructure has led to the realization that cement-based materials, such as concrete, must be improved in terms of their properties and durability. Leaching of calcium ions increases the porosity of cement- based materials, consequently resulting in a negative effect on durability since it provides an entry for aggressive harmful ions, causing corrosion of concrete. The use supplementary cementing composite materials have been reported to improve the resistance of concrete to deterioration by aggressive chemicals. The paper is focused on the investigation of the influence of biogenic acid attack on the cement composites affected by bacteria Acidithiobacillus thiooxidans. The concrete specimens with 65 wt. % addition of antimicrobial activated granulated blast furnace slag as durability increasing factor as well as without any addition were studied. The experiments proceeded during 150 days under model laboratory conditions. The pH values and chemical composition of leachates were measured after each 30- day cycle. The calcium and silicon contents in leachates were evaluated using X - ray fluorescence method (XRF). Summarizing the results, the 65% wt. addition of antimicrobial activated granulated blast furnace slag was not confirmed to be more resistant.

Phosphoric and carboxylic methacrylate esters as bonding agents in self-adhesive resin cements

PubMed Central

Liu, Wenshu; Meng, Hongmei; Sun, Zhiguang; Jiang, Riwen; Dong, Chang-An; Zhang, Congxiao

2018-01-01

The aim of the present study was to investigate the effect of pH and phosphoric ester structure (phosphonate or phosphate) on the bond strength of different dental restorative materials. The following three self-adhesive resin cements were used in the present study: RelyX™ Unicem, Maxcem and Multilink Sprint The pH of each cement was measured using a pH meter. The cements were used to attach a variety of restorative materials to human dentin and the bond strength was measured by assessing shear strength using a universal testing machine. The pH values of RelyX Unicem, Maxcem and Multilink Sprint were 3.78, 1.78 and 3.42, respectively. Maxcem, a phosphate-based self-adhesive cement, was demonstrated to form the weakest bonds. No significant difference in bond strength was observed between RelyX Unicem and Multilink Sprint, which are phosphonate-based cements. The results of the present study suggest that the chemical structure of the functional monomer influences the performance of an adhesive material. Furthermore, the pH of acidic functional monomers containing phosphonate or phosphate groups has an effect on the strength of bonds formed between dentin and restorative materials. PMID:29731837

Investigation of Interrelation between Deformation, Composition and Structural Characteristics of Magnesium Oxychloride Cements

NASA Astrophysics Data System (ADS)

Averina, G. F.; Chernykh, T. N.; Kramar, L. Ya

2017-11-01

The paper studies the process of volume deformation changes in magnesium cement at its hardening in accordance with its composition and structural peculiarities, which result from the roasting parameters of the raw materials. The study has been carried out with the aim of broadening raw materials sources for production of magnesia cements and construction materials through the use waste products of ore-dressing and processing enterprises. The mineralogical and phase composition of magnesium cements, obtained on the basis of magnesite with high content of impurity minerals from the mine dumps, has been studied by the X-ray phase analysis and derivatography. The roasting of the initial raw materials was carried out at various temperature conditions in order to get cements of different activities. The typical content of hydrated phases has been found for the hardened magnesian stone obtained from cements with different activity degrees. The characteristics of volume deformations developed in the magnesian stone have been described in relation to its phase composition. The influence of low- and high-activity crystals and calcium oxide crystals on the soundness and the structural integrity of magnesian stone has been covered.

Effective friction of granular flows made of non-spherical particles

NASA Astrophysics Data System (ADS)

Somfai, Ellák; Nagy, Dániel B.; Claudin, Philippe; Favier, Adeline; Kálmán, Dávid; Börzsönyi, Tamás

2017-06-01

Understanding the rheology of dense granular matter is a long standing problem and is important both from the fundamental and the applied point of view. As the basic building blocks of granular materials are macroscopic particles, the nature of both the response to deformations and the dissipation is very different from that of molecular materials. In the absence of large gradients, the best approach formulates the constitutive equation as an effective friction: for sheared granular matter the ratio of the off-diagonal and the diagonal elements of the stress tensor depends only on dynamical parameters, in particular the inertial number. In this work we employ numerical simulations to extend this formalism to granular packings made of frictionless elongated particles. We measured how the shape of the particles affects the effective friction, volume fraction and first normal stress difference, and compared it to the spherical particle case. We had to introduce polydispersity in particle size in order to keep the systems of the more elongated particles disordered.

A trans-phase granular continuum relation and its use in simulation

NASA Astrophysics Data System (ADS)

Kamrin, Ken; Dunatunga, Sachith; Askari, Hesam

The ability to model a large granular system as a continuum would offer tremendous benefits in computation time compared to discrete particle methods. However, two infamous problems arise in the pursuit of this vision: (i) the constitutive relation for granular materials is still unclear and hotly debated, and (ii) a model and corresponding numerical method must wear ``many hats'' as, in general circumstances, it must be able to capture and accurately represent the material as it crosses through its collisional, dense-flowing, and solid-like states. Here we present a minimal trans-phase model, merging an elastic response beneath a fictional yield criterion, a mu(I) rheology for liquid-like flow above the static yield criterion, and a disconnection rule to model separation of the grains into a low-temperature gas. We simulate our model with a meshless method (in high strain/mixing cases) and the finite-element method. It is able to match experimental data in many geometries, including collapsing columns, impact on granular beds, draining silos, and granular drag problems.

Comparative study of methods to measure the density of Cementious powders.

PubMed

Helsel, Michelle A; Ferraris, Chiara F; Bentz, Dale

2016-11-01

The accurate measurement of the density of hydraulic cement has an essential role in the determination of concrete mixture proportions. As more supplementary cementitious materials (SCM), such as fly ash, and slag, or cement replacements materials such as limestone and calcium carbonate are used in blended cements, knowledge of the density of each powder or of the blended cement would allow a more accurate calculation of the proportions of a concrete mixture by volume instead of by mass. The current ASTM standard for measuring cement density is the "Test Method for Density of Hydraulic Cements" (ASTM C188-14), which utilizes a liquid displacement method to measure the volume of the cement. This paper will examine advantageous modifications of the current ASTM test, by alcohol substitutions for kerosene. In addition, a gas (helium) pycnometry method is evaluated as a possible alternative to the current standard. The described techniques will be compared to determine the most precise and reproducible method for measuring the density of hydraulic cements and other powders.

Negative permittivity and permeability spectra of Cu/yttrium iron garnet hybrid granular composite materials in the microwave frequency range

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tsutaoka, Takanori, E-mail: tsutaok@hiroshima-u.ac.jp; Fukuyama, Koki; Kinoshita, Hideaki

2013-12-23

The relative complex permittivity and permeability spectra of the coagulated copper and yttrium iron garnet (Cu/YIG) hybrid granular composite materials have been studied in the microwave range. The insulator to metal transition was observed at the percolation threshold of Cu particle content (φ{sub Cu} = 16.0 vol. %) in the electrical conductivity. In the percolation threshold, the low frequency plasmonic state caused by the metallic Cu particle networks was observed. The percolated Cu/YIG granular composites show simultaneous negative permittivity and permeability spectra under external magnetic fields.

Sound-absorbing slabs and structures based on granular materials (bound and unbound). [energy absorbing efficiency of porous material

NASA Technical Reports Server (NTRS)

Petre-Lazar, S.; Popeea, G.

1974-01-01

Sound absorbing slabs and structures made up of bound or unbound granular materials are considered and how to manufacture these elements at the building site. The raw material is a single grain powder (sand, expanded blast furnace slag, etc.) that imparts to the end products an apparent porosity of 25-45% and an energy dissipation within the structure leading to absorption coefficients that can be compared with those of mineral wool and urethane.

Wastewater Sludge Used as Material for Bricks Fabrication

NASA Astrophysics Data System (ADS)

Jianu, N. R.; Moga, I. C.; Pricop, F.; Chivoiu, A.

2018-06-01

Current world trends related to wastewater sludges are: reuse in agriculture, utilization as retaining material for petroleum products or utilization in construction. Bricks from sand-cement or autoclaved cellular concrete are commonly used in construction. The authors propose innovative receipts for bricks and plasters based on textile wastewaters sludge. Centrifuged sludge is mixed with cement to obtain bricks and plaster. For bricks, the mixture is represented by 45% cement and 55% sludge. The paper presents the obtained results and the new materials used for bricks fabrication.

Effect of cement dosage and early curing towards Kuala Perlis dredged marine sediments: a ɛv - σv and SEM-EDX approach

NASA Astrophysics Data System (ADS)

Syakeera Nordin, Nurul; Chan, Chee-Ming

2017-11-01

Cement is the primary material used in solidifying the soft soils. This material was applied in solidifying Kuala Perlis dredged marine sediments (DMS). These unwanted sediments are classified as high plasticity silt, MH with 3.36 LL of wc/LL value. At dosage 10 and 20 % of cemented-DMS and 3 days curing time, compression curve results shows the settlement criteria were enhanced than the natural DMS. Unfortunately, the settlement criteria are not complies with the permissible settlement limit and applicable pressure. The formation of cementing compounds appears in the SEM micrograph for 10 and 20 % of cemented-DMS. EDX analysis shows the Ca:Si ratio were increased for cemented-DMS due to the formation of C-S-H gel.

A Simple Method for Determination of the Density of Granular Materials

ERIC Educational Resources Information Center

Tsutsumanova, G. G.; Kirilov, K. M.; Russev, S. C.

2012-01-01

A simple experiment using low cost equipment for the determination of the density of granular materials, without immersing them in a liquid, is presented. It is based only on the ideal gas state equation, so it is a good experimental task for undergraduate and high school students. (Contains 2 tables and 5 figures.)

DEM study on the interaction between wet cohesive granular materials and tools

NASA Astrophysics Data System (ADS)

Tsuji, Takuya; Matsui, Yu; Nakagawa, Yuta; Kadono, Yuuichi; Tanaka, Toshitsugu

2013-06-01

A model based on discrete element method has been developed for the interaction between wet cohesive granular materials and mechanical tools with complex geometry. To obtain realistic results, the motion of 52.5 million particles has been simulated and the formation of multiple shear bands during an excavation process by a bulldozer blade was observed.

Physico-chemical studies of hardened cement paste structure with micro-reinforcing fibers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Steshenko, Aleksei, E-mail: steshenko.alexey@gmail.com; Kudyakov, Aleksander; Konusheva, Viktoriya

The results of physico-chemical studies of modified hardened cement paste with micro-reinforcing fibers are given in this article. The goal was to study the reasons of the increase of strength properties of modified hardened cement paste by the method of X-ray diffraction and electron microscopy. It is shown that the use of mineral fibers in the production of cement based material has positive effect on its properties. The study found out that the increase in the strength of the hardened cement paste with micro-reinforcing fibers is due to the increase of the rate of hydration of cement without a significantmore » change in the phase composition in comparison with hardened cement paste without additive. The results of microstructure investigation (of control samples and samples of the reinforced hardened cement paste) have shown that introduction of mineral fibers in the amount of 0.1-2 % by weight of cement provides the structure of the homogeneous microporous material with uniform distribution of the crystalline phase provided by densely packed hydrates.« less

The effect of lime-dried sewage sludge on the heat-resistance of eco-cement.

PubMed

Li, Wen-Quan; Liu, Wei; Cao, Hai-Hua; Xu, Jing-Cheng; Liu, Jia; Li, Guang-Ming; Huang, Juwen

2016-01-01

The treatment and disposal of sewage sludge is a growing problem for sewage treatment plants. One method of disposal is to use sewage sludge as partial replacement for raw material in cement manufacture. Although this process has been well researched, little attention has been given to the thermal properties of cement that has had sewage sludge incorporated in the manufacturing process. This study investigated the fire endurance of eco-cement to which lime-dried sludge (LDS) had been added. LDS was added in proportions of 0%, 3%, 6%, 9%, and 12% (by weight) to the raw material. The eco-cement was exposed to 200, 400, or 600 °C for 3 h. The residual strength and the microstructural properties of eco-cement were then studied. Results showed that the eco-cement samples suffered less damage than conventional cement at 600 °C. The microstructural studies showed that LDS incorporation could reduce Ca(OH)(2) content. It was concluded that LDS has the potential to improve the heat resistance of eco-cement products.

Submicron and Nanoparticulate Matter Removal by HEPA-Rated Media Filters and Packed Beds of Granular Materials

NASA Technical Reports Server (NTRS)

Perry, J. L.; Agui, J. H.; Vijayakimar, R

2016-01-01

Contaminants generated aboard crewed spacecraft by diverse sources consist of both gaseous chemical contaminants and particulate matter. Both HEPA media filters and packed beds of granular material, such as activated carbon, which are both commonly employed for cabin atmosphere purification purposes have efficacy for removing nanoparticulate contaminants from the cabin atmosphere. The phenomena associated with particulate matter removal by HEPA media filters and packed beds of granular material are reviewed relative to their efficacy for removing fine (less than 2.5 micrometers) and ultrafine (less than 0.01 micrometers) sized particulate matter. Considerations are discussed for using these methods in an appropriate configuration to provide the most effective performance for a broad range of particle sizes including nanoparticulates.

A constitutive law for dense granular flows.

PubMed

Jop, Pierre; Forterre, Yoël; Pouliquen, Olivier

2006-06-08

A continuum description of granular flows would be of considerable help in predicting natural geophysical hazards or in designing industrial processes. However, the constitutive equations for dry granular flows, which govern how the material moves under shear, are still a matter of debate. One difficulty is that grains can behave like a solid (in a sand pile), a liquid (when poured from a silo) or a gas (when strongly agitated). For the two extreme regimes, constitutive equations have been proposed based on kinetic theory for collisional rapid flows, and soil mechanics for slow plastic flows. However, the intermediate dense regime, where the granular material flows like a liquid, still lacks a unified view and has motivated many studies over the past decade. The main characteristics of granular liquids are: a yield criterion (a critical shear stress below which flow is not possible) and a complex dependence on shear rate when flowing. In this sense, granular matter shares similarities with classical visco-plastic fluids such as Bingham fluids. Here we propose a new constitutive relation for dense granular flows, inspired by this analogy and recent numerical and experimental work. We then test our three-dimensional (3D) model through experiments on granular flows on a pile between rough sidewalls, in which a complex 3D flow pattern develops. We show that, without any fitting parameter, the model gives quantitative predictions for the flow shape and velocity profiles. Our results support the idea that a simple visco-plastic approach can quantitatively capture granular flow properties, and could serve as a basic tool for modelling more complex flows in geophysical or industrial applications.

Evaluation of ternary cementitious combinations : tech summary.

DOT National Transportation Integrated Search

2012-02-01

Portland cement concrete (PCC) is the worlds most versatile and utilized construction material. Modern concrete consists of six : main ingredients: coarse aggregate, sand, portland cement, supplementary cementitious materials (SCMs), chemical admi...

Properties of Cement Mortar Produced from Mixed Waste Materials with Pozzolanic Characteristics.

PubMed

Yen, Chi-Liang; Tseng, Dyi-Hwa; Wu, Yue-Ze

2012-07-01

Waste materials with pozzolanic characteristics, such as sewage sludge ash (SSA), coal combustion fly ash (FA), and granulated blast furnace slag (GBS), were reused as partial cement replacements for making cement mortar in this study. Experimental results revealed that with dual replacement of cement by SSA and GBS and triple replacement by SSA, FA, and GBS at 50% of total cement replacement, the compressive strength (Sc) of the blended cement mortars at 56 days was 93.7% and 92.9% of the control cement mortar, respectively. GBS had the highest strength activity index value and could produce large amounts of CaO to enhance the pozzolanic activity of SSA/FA and form calcium silicate hydrate gels to fill the capillary pores of the cement mortar. Consequently, the Sc development of cement mortar with GBS replacement was better than that without GBS, and the total pore volume of blended cement mortars with GBS/SSA replacement was less than that with FA/SSA replacement. In the cement mortar with modified SSA and GBS at 70% of total cement replacement, the Sc at 56 days was 92.4% of the control mortar. Modifying the content of calcium in SSA also increased its pozzolanic reaction. CaCl(2) accelerated the pozzolanic activity of SSA better than lime did. Moreover, blending cement mortars with GBS/SSA replacement could generate more monosulfoaluminate to fill capillary pores.

Properties of Cement Mortar Produced from Mixed Waste Materials with Pozzolanic Characteristics

PubMed Central

Yen, Chi-Liang; Tseng, Dyi-Hwa; Wu, Yue-Ze

2012-01-01

Abstract Waste materials with pozzolanic characteristics, such as sewage sludge ash (SSA), coal combustion fly ash (FA), and granulated blast furnace slag (GBS), were reused as partial cement replacements for making cement mortar in this study. Experimental results revealed that with dual replacement of cement by SSA and GBS and triple replacement by SSA, FA, and GBS at 50% of total cement replacement, the compressive strength (Sc) of the blended cement mortars at 56 days was 93.7% and 92.9% of the control cement mortar, respectively. GBS had the highest strength activity index value and could produce large amounts of CaO to enhance the pozzolanic activity of SSA/FA and form calcium silicate hydrate gels to fill the capillary pores of the cement mortar. Consequently, the Sc development of cement mortar with GBS replacement was better than that without GBS, and the total pore volume of blended cement mortars with GBS/SSA replacement was less than that with FA/SSA replacement. In the cement mortar with modified SSA and GBS at 70% of total cement replacement, the Sc at 56 days was 92.4% of the control mortar. Modifying the content of calcium in SSA also increased its pozzolanic reaction. CaCl2 accelerated the pozzolanic activity of SSA better than lime did. Moreover, blending cement mortars with GBS/SSA replacement could generate more monosulfoaluminate to fill capillary pores. PMID:22783062

Three-dimensional culture of dental pulp stem cells in direct contact to tricalcium silicate cements.

PubMed

Widbiller, M; Lindner, S R; Buchalla, W; Eidt, A; Hiller, K-A; Schmalz, G; Galler, K M

2016-03-01

Calcium silicate cements are biocompatible dental materials applicable in contact with vital tissue. The novel tricalcium silicate cement Biodentine™ offers properties superior to commonly used mineral trioxide aggregate (MTA). Objective of this study was to evaluate its cytocompatibility and ability to induce differentiation and mineralization in three-dimensional cultures of dental pulp stem cells after direct contact with the material. Test materials included a new tricalcium silicate (Biodentine™, Septodont, Saint-Maur-des-Fossés, France), MTA (ProRoot® MTA, DENSPLY Tulsa Dental Specialities, Johnson City, TN, USA), glass ionomer (Ketac™ Molar Aplicap™, 3M ESPE, Seefeld, Germany), human dentin disks and polystyrene. Magnetic activated cell sorting for to the surface antigen STRO-1 was performed to gain a fraction enriched with mesenchymal stem cells. Samples were allowed to set and dental pulp stem cells in collagen carriers were placed on top. Scanning electron microscopy of tricalcium silicate cement surfaces with and without cells was conducted. Cell viability was measured for 14 days by MTT assay. Alkaline phosphatase activity was evaluated (days 3, 7, and 14) and expression of mineralization-associated genes (COL1A1, ALP, DSPP, and RUNX2) was quantified by real-time quantitative PCR. Nonparametric statistical analysis for cell viability and alkaline phosphatase data was performed to compare different materials as well as time points (Mann-Whitney U test, α = 0.05). Cell viability was highest on tricalcium silicate cement, followed by MTA. Viability on glass ionomer cement and dentin disks was significantly lower. Alkaline phosphatase activity was lower in cells on new tricalcium silicate cement compared to MTA, whereas expression patterns of marker genes were alike. Increased cell viability and similar levels of mineralization-associated gene expression in three-dimensional cell cultures on the novel tricalcium silicate cement and mineral trioxide aggregate indicate that the material is cytocompatible and bioactive. The tested new tricalcium silicate cement confirms its suitability as an alternative to MTA in vital pulp therapy.

The Comparison of Sorption and Solubility Behavior of Four Different Resin Luting Cements in Different Storage Media.

PubMed

Giti, Rashin; Vojdani, Mahroo; Abduo, Jaafar; Bagheri, Rafat

2016-06-01

Structural integrity and dimensional stability are the key factors that determine the clinical success and durability of luting cements in the oral cavity. Sorption and solubility of self-adhesive resin luting cements in food-simulating solutions has not been studied sufficiently. This study aimed to compare the sorption and solubility of 2 conventional and 2 self-adhesive resin-based luting cements immersed in four different storage media. A total of 32 disc-shaped specimens were prepared from each of four resin luting cements; seT (SDI), Panavia F (Kuraray), Clearfil SA Cement (Kuraray), and Choice 2 (Bisco). Eight specimens of each material were immersed in all tested solutions including n-heptane 97%, distilled water, apple juice, or Listerine mouth wash. Sorption and solubility were measured by weighing the specimens before and after immersion and desiccation. Data were analyzed by SPSS version 18, using two-way ANOVA and Tukey's HSD test with p≤ 0.05 set as the level of significance. There was a statistically significant interaction between the materials and solutions. The effect of media on the sorption and solubility was material-dependent. While seT showed the highest values of the sorption in almost all solutions, Choice 2 showed the least values of sorption and solubility. Immersion in apple juice caused more sorption than other solutions (p≤ 0.05). The sorption and solubility behavior of the studied cements were significantly affected by their composition and the storage media. The more hydrophobic materials with higher filler content like Choice 2 resin cement showed the least sorption and solubility. Due to their lower sorption and solubility, these types of resin-based luting cements are recommended to be used clinically.

Theoretical prediction and experimental determination of the effect of mold characteristics on temperature and monomer conversion fraction profiles during polymerization of a PMMA-based bone cement.

PubMed

Vallo, Claudia I

2002-01-01

The present work is concerned with applications of a kinetic model for free-radical polymerization of a polymethylmethacrylate-based bone cement. Autocatalytic behavior at the first part of the reaction as well as a diffusion control phenomenon near vitrification are described by the model. Comparison of theoretical computations with experimental measurements for the temperature evolution during batch casting demonstrated the capacity of the proposed model to represent the kinetic behavior of the polymerization reaction. Temperature evolution and monomer conversion were simulated for the cure of the cement in molds made of different materials. The maximum monomer conversion fraction was markedly influenced by the physical properties of the mold material. The unreacted monomer acts as a plasticizer that influences the mechanical behavior of the cement. Hence, the same cement formulation cured in molds of different materials may result in different mechanical response because of the differences in the amounts of residual monomer. Standardization of the mold type to prepare specimens for the mechanical characterization of bone cements is recommended. Theoretical prediction of temperature evolution during hip replacement indicated that for cement thickness lower than 6 mm the peak temperature at the bone-cement interface was below the limit stated for thermal injury (50 degrees C for more than 1 min). The use of thin cement layers is recommended to diminish the risk of thermal injury; however, it is accompanied by an increase in the amount of unreacted monomer present in the cured material. Copyright 2002 Wiley Periodicals, Inc. J Biomed Mater Res (Appl Biomater) 63: 627-642, 2002

Mechano-Physical Properties and Microstructure of Carbon Nanotube Reinforced Cement Paste after Thermal Load

PubMed Central

2017-01-01

The article presents the results obtained in the course of a study on the use of carbon nanotubes (CNTs) for the modification of a cement matrix. Carbon nanotubes were introduced into a cement paste in the form of an aqueous dispersion in the presence of a surfactant (SDS—sodium dodecyl sulfate), which was sonicated. The selected physical and mechanical parameters were examined, and the correlations between these parameters were determined. An analysis of the local microstructure of the modified cement pastes has been carried out using scanning electron microscope (SEM) and X-ray microanalysis (EDS). In addition, the effect of carbon nanotubes on the change in characteristics of the cementitious material exposed to the sudden, short-term thermal load, was determined. The obtained material was characterized by a much lower density than a traditional cement matrix because the phenomenon of foaming occurred. The material was also characterized by reduced durability, higher shrinkage, and higher resistance to the effect of elevated temperature. Further research on the carbon nanotube reinforced cement paste, with SDS, may contribute to the development of a modified cement binder for the production of a lightweight or an aerated concrete. PMID:28891976

Polymer nanocomposites for sealing microannulus cracks in wellbores cement-steel interface

NASA Astrophysics Data System (ADS)

Genedy, M.; Fernandez, S. G.; Stormont, J.; Matteo, E. N.; Dewers, T. A.; Reda Taha, M.

2017-12-01

Seal integrity of production and storage wellbores has become a critical challenge with the increasing oil and gas leakage incidents. The general consensus is that one of the potential leakage pathways is micro-annuli at the cement-steel interface. In this paper, we examine the efficiency of proposed polymer nanocomposite to seal microannulus cracks at the cement-steel interface. The repair material efficiency is defined as the ability of the repair material to reduce or eliminate the gas permeability of the cement-steel interface. The flow rate of an inert gas (Nitrogen) at the cement-steel interface was investigated for three cases: 1) repaired test samples with traditional repair material (microfine cement), 2) polymer nanocomposites, and 3) unrepaired test samples. Flow rates were measured and compared for all three cases. The experimental results show up to 99.5% seal efficiency achieved by using polymer nanocomposites compared to 20% efficiency achieved in the case of microfine cement. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology and Engineering Solutions of Sandia, LLC., a wholly owned subsidiary of Honeywell International, Inc., for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-NA-0003525. SAND2017-8094 A.

Photoactive glazed polymer-cement composite

NASA Astrophysics Data System (ADS)

Baltes, Liana; Patachia, Silvia; Tierean, Mircea; Ekincioglu, Ozgur; Ozkul, Hulusi M.

2018-04-01

Macro defect free cements (MDF), a kind of polymer-cement composites, are characterized by remarkably high mechanical properties. Their flexural strengths are 20-30 times higher than those of conventional cement pastes, nearly equal to that of an ordinary steel. The main drawback of MDF cements is their sensitivity to water. This paper presents a method to both diminish the negative impact of water on MDF cements mechanical properties and to enlarge their application by conferring photoactivity. These tasks were solved by glazing MDF cement with an ecological glaze containing nano-particles of TiO2. Efficiency of photocatalytic activity of this material was tested against methylene blue aqueous solution (4.4 mg/L). Influence of the photocatalyst concentration in the glaze paste and of the contact time on the photocatalysis process (efficiency and kinetic) was studied. The best obtained photocatalysis yield was of 97.35%, after 8 h of exposure to 254 nm UV radiation when used an MDF glazed with 10% TiO2 in the enamel paste. Surface of glazed material was characterized by optic microscopy, scratch test, SEM, XRD, and EDS. All these properties were correlated with the aesthetic aspect of the glazed surface aiming to propose using of this material for sustainable construction development.

Mechano-Physical Properties and Microstructure of Carbon Nanotube Reinforced Cement Paste after Thermal Load.

PubMed

Szeląg, Maciej

2017-09-11

The article presents the results obtained in the course of a study on the use of carbon nanotubes (CNTs) for the modification of a cement matrix. Carbon nanotubes were introduced into a cement paste in the form of an aqueous dispersion in the presence of a surfactant (SDS-sodium dodecyl sulfate), which was sonicated. The selected physical and mechanical parameters were examined, and the correlations between these parameters were determined. An analysis of the local microstructure of the modified cement pastes has been carried out using scanning electron microscope (SEM) and X-ray microanalysis (EDS). In addition, the effect of carbon nanotubes on the change in characteristics of the cementitious material exposed to the sudden, short-term thermal load, was determined. The obtained material was characterized by a much lower density than a traditional cement matrix because the phenomenon of foaming occurred. The material was also characterized by reduced durability, higher shrinkage, and higher resistance to the effect of elevated temperature. Further research on the carbon nanotube reinforced cement paste, with SDS, may contribute to the development of a modified cement binder for the production of a lightweight or an aerated concrete.

Evaluation of the strength and radiopacity of Portland cement with varying additions of bismuth oxide.

PubMed

Saliba, E; Abbassi-Ghadi, S; Vowles, R; Camilleri, J; Hooper, S; Camilleri, J

2009-04-01

To study the effect of addition of various proportions of bismuth oxide on compressive strength and radiopacity of Portland cement. The compressive strength of white Portland cement and cement replaced with 10, 15, 20, 25 and 30% bismuth oxide was evaluated by testing cylinders 6 mm in diameter and 12 mm high. Twelve cylinders were tested for each material under study. The radiopacity of the cements tested was evaluated using an aluminium step-wedge and densitometer. The optical density was compared with the relevant thickness of aluminium (Al). Statistical analysis was performed using Analysis of Variance (ANOVA) with P = 0.05 and Tukey test to perform multiple comparison tests. Various additions of bismuth oxide had no significant effect on the strength of the material when compared with the unmodified Portland cement (P > 0.05). The radiopacity of the cements tested ranged from 2.02 mm Al for Portland cement to 9.79 mm Al for the highest bismuth replacement. Addition of bismuth oxide did not affect the compressive strength of Portland cement. All the bismuth oxide cement mixtures had radio-opacities higher than 3 mm thickness of aluminium.

High strain rate behavior of saturated and non-saturated sandstone: implications for earthquake mechanisms.

NASA Astrophysics Data System (ADS)

Aben, F. M.; Doan, M. L.; Gratier, J. P.; Renard, F.

2015-12-01

Damage zones of active faults control their resistance to rupture and transport properties. Hence, knowing the damage's origin is crucial to shed light on the (paleo)seismic behavior of the fault. Coseismic damage in the damage zone occurs by stress-wave loading of a passing earthquake rupture tip, resulting in dynamic (high strain rate) loading and subsequent dynamic fracturing or pulverization. Recently, interest in this type of damage has increased and several experimental studies were performed on dry rock specimens to search for pulverization-controlling parameters. However, the influence of fluids in during dynamic loading needs to be constrained. Hence, we have performed compressional dynamic loading experiments on water saturated and oven dried Vosges sandstone samples using a Split Hopkinson Pressure Bar apparatus. Due to the high porosity in these rocks, close to 20%, the effect of fluids should be clear. Afterwards, microstructural analyses have been applied on thin sections. Water saturated samples reveal dynamic mechanical behavior that follows linear poro-elasticity for undrained conditions: the peak strength of the sample decreases by 30-50% and the accumulated strain increases relative to the dry samples that were tested under similar conditions. The mechanical behavior of partially saturated samples falls in between. Microstructural studies on thin section show that fractures are restricted to some quartz grains while other quartz grains remain intact, similar to co-seismically damaged sandstones observed in the field. Most deformation is accommodated by inter-granular processes, thereby appointing an important role to the cement matrix in between grains. Intra-granular fracture damage is highest for the saturated samples. The presence of pore fluids in the rocks lower the dynamic peak strength, especially since fast dynamic loading does not allow for time-dependent fluid dissipation. Thus, fluid-saturated rocks would show undrained mechanical behavior, creating local overpressure in the pore that breaks the inter-granular cement. This strength-decreasing effect provides an explanation for the presence of pulverized and coseismically damaged rocks at depth and extends the range of dynamic stress where dynamic damage can occur in fault zones.

Mixture design and treatment methods for recycling contaminated sediment.

PubMed

Wang, Lei; Kwok, June S H; Tsang, Daniel C W; Poon, Chi-Sun

2015-01-01

Conventional marine disposal of contaminated sediment presents significant financial and environmental burden. This study aimed to recycle the contaminated sediment by assessing the roles and integration of binder formulation, sediment pretreatment, curing method, and waste inclusion in stabilization/solidification. The results demonstrated that the 28-d compressive strength of sediment blocks produced with coal fly ash and lime partially replacing cement at a binder-to-sediment ratio of 3:7 could be used as fill materials for construction. The X-ray diffraction analysis revealed that hydration products (calcium hydroxide) were difficult to form at high sediment content. Thermal pretreatment of sediment removed 90% of indigenous organic matter, significantly increased the compressive strength, and enabled reuse as non-load-bearing masonry units. Besides, 2-h CO2 curing accelerated early-stage carbonation inside the porous structure, sequestered 5.6% of CO2 (by weight) in the sediment blocks, and acquired strength comparable to 7-d curing. Thermogravimetric analysis indicated substantial weight loss corresponding to decomposition of poorly and well crystalline calcium carbonate. Moreover, partial replacement of contaminated sediment by various granular waste materials notably augmented the strength of sediment blocks. The metal leachability of sediment blocks was minimal and acceptable for reuse. These results suggest that contaminated sediment should be viewed as useful resources. Copyright © 2014 Elsevier B.V. All rights reserved.

NMR relaxometry study of cement hydration in the presence of different oxidic fine fraction materials.

PubMed

Nestle, Nikolaus

2004-01-01

NMR relaxometry has been applied to study hydrating cements for about 25 years now. The most important advantage over other experimental approaches is the possibility to conduct non-destructive measurements with a time resolution of minutes. NMR relaxometry data thus can help to identify details in the time course of cement hydration that possibly would be overlooked in other experiments with lower temporal resolution. Time-resolved information on cement hydration kinetics can provide interesting insights into the impact of oxidic additive materials on cement hydration. For PbO, a very strong delay was observed which then was systematically studied. An explanation for this delay is suggested.

Wet granular materials

NASA Astrophysics Data System (ADS)

Mitarai, Namiko; Nori, Franco

2006-04-01

Most studies on granular physics have focused on dry granular media, with no liquids between the grains. However, in geology and many real world applications (e.g. food processing, pharmaceuticals, ceramics, civil engineering, construction, and many industrial applications), liquid is present between the grains. This produces inter-grain cohesion and drastically modifies the mechanical properties of the granular media (e.g. the surface angle can be larger than 90 degrees). Here we present a review of the mechanical properties of wet granular media, with particular emphasis on the effect of cohesion. We also list several open problems that might motivate future studies in this exciting but mostly unexplored field.

Compaction of granular materials composed of deformable particles

NASA Astrophysics Data System (ADS)

Nguyen, Thanh Hai; Nezamabadi, Saeid; Delenne, Jean-Yves; Radjai, Farhang

2017-06-01

In soft particle materials such as metallic powders the particles can undergo large deformations without rupture. The large elastic or plastic deformations of the particles are expected to strongly affect the mechanical properties of these materials compared to hard particle materials more often considered in research on granular materials. Herein, two numerical approaches are proposed for the simulation of soft granular systems: (i) an implicit formulation of the Material Point Method (MPM) combined with the Contact Dynamics (CD) method to deal with contact interactions, and (i) Bonded Particle Model (BPM), in which each deformable particle is modeled as an aggregate of rigid primary particles using the CD method. These two approaches allow us to simulate the compaction of an assembly of elastic or plastic particles. By analyzing the uniaxial compaction of 2D soft particle packings, we investigate the effects of particle shape change on the stress-strain relationship and volume change behavior as well as the evolution of the microstructure.

Parallel Program Systems for the Analysis of Wave Processes in Elastic-Plastic, Granular, Porous and Multi-Blocky Media

NASA Astrophysics Data System (ADS)

Sadovskaya, Oxana; Sadovskii, Vladimir

2017-04-01

Under modeling the wave propagation processes in geomaterials (granular and porous media, soils and rocks) it is necessary to take into account the structural inhomogeneity of these materials. Parallel program systems for numerical solution of 2D and 3D problems of the dynamics of deformable media with constitutive relationships of rather general form on the basis of universal mathematical model describing small strains of elastic, elastic-plastic, granular and porous materials are worked out. In the case of an elastic material, the model is reduced to the system of equations, hyperbolic by Friedrichs, written in terms of velocities and stresses in a symmetric form. In the case of an elastic-plastic material, the model is a special formulation of the Prandtl-Reuss theory in the form of variational inequality with one-sided constraints on the stress tensor. Generalization of the model to describe granularity and the collapse of pores is obtained by means of the rheological approach, taking into account different resistance of materials to tension and compression. Rotational motion of particles in the material microstructure is considered within the framework of a mathematical model of the Cosserat continuum. Computational domain may have a blocky structure, composed of an arbitrary number of layers, strips in a layer and blocks in a strip from different materials with self-consistent curvilinear interfaces. At the external boundaries of computational domain the main types of dissipative boundary conditions in terms of velocities, stresses or mixed boundary conditions can be given. Shock-capturing algorithm is proposed for implementation of the model on supercomputers with cluster architecture. It is based on the two-cyclic splitting method with respect to spatial variables and the special procedures of the stresses correction to take into account plasticity, granularity or porosity of a material. An explicit monotone ENO-scheme is applied for solving one-dimensional systems of equations at the stages of splitting method. The parallelizing of computations is carried out using the MPI library and the SPMD technology. The data exchange between processors occurs at step "predictor" of the finite-difference scheme. Program systems allow simulate the propagation of waves produced by external mechanical effects in a medium, aggregated of arbitrary number of heterogeneous blocks. Some computations of dynamic problems with and without taking into account the moment properties of a material were performed on clusters of ICM SB RAS (Krasnoyarsk) and JSCC RAS (Moscow). Parallel program systems 2Dyn_Granular, 3Dyn_Granular, 2Dyn_Cosserat, 3Dyn_Cosserat and 2Dyn_Blocks_MPI for numerical solution of 2D and 3D elastic-plastic problems of the dynamics of granular media and problems of the Cosserat elasticity theory, as well as for modeling of the dynamic processes in multi-blocky media with pliant viscoelastic, porous and fluid-saturated interlayers on cluster systems were registered by Rospatent.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schuett, K.J.; Pawlak, J.P.; Traina, L.

No. 13 Blast Furnace at US Steel`s Gary Works is a 35 tuyere furnace with a 36.5 ft. hearth capable of producing over 9,000 tons of hot metal per day. The current casthouse design was placed in service following the second reline in the fall of 1979. This design anticipated daily production rates averaging 7,500 tons of hot metal per day and provided for removable troughs at two of the three tapholes. At the time, the troughs were rammed with a high alumina/silicon carbide granular ramming material that provided the operators with trough campaign lives between 60,000--70,000 tons of hotmore » metal produced. As refractory technology progressed, low cement/low moisture castables were introduced to the trough systems on No. 13 Blast Furnace. The immediate success of the castables was tempered by emergence of a new unexpected problem. That problem was the thermal expansion of the castable. The paper describes the problems that resulted in the need to modify the trough design, the new design of the trough, and its improvement in iron trough campaign life and reliability.« less

Planning for the Collection and Analysis of Samples of Martian Granular Materials Potentially to be Returned by Mars Sample Return

NASA Astrophysics Data System (ADS)

Carrier, B. L.; Beaty, D. W.

2017-12-01

NASA's Mars 2020 rover is scheduled to land on Mars in 2021 and will be equipped with a sampling system capable of collecting rock cores, as well as a specialized drill bit for collecting unconsolidated granular material. A key mission objective is to collect a set of samples that have enough scientific merit to justify returning to Earth. In the case of granular materials, we would like to catalyze community discussion on what we would do with these samples if they arrived in our laboratories, as input to decision-making related to sampling the regolith. Numerous scientific objectives have been identified which could be achieved or significantly advanced via the analysis of martian rocks, "regolith," and gas samples. The term "regolith" has more than one definition, including one that is general and one that is much more specific. For the purpose of this analysis we use the term "granular materials" to encompass the most general meaning and restrict "regolith" to a subset of that. Our working taxonomy includes the following: 1) globally sourced airfall dust (dust); 2) saltation-sized particles (sand); 3) locally sourced decomposed rock (regolith); 4) crater ejecta (ejecta); and, 5) other. Analysis of martian granular materials could serve to advance our understanding areas including habitability and astrobiology, surface-atmosphere interactions, chemistry, mineralogy, geology and environmental processes. Results of these analyses would also provide input into planning for future human exploration of Mars, elucidating possible health and mechanical hazards caused by the martian surface material, as well as providing valuable information regarding available resources for ISRU and civil engineering purposes. Results would also be relevant to matters of planetary protection and ground-truthing orbital observations. We will present a preliminary analysis of the following, in order to generate community discussion and feedback on all issues relating to: What are the specific reasons (and their priorities) for collecting samples of granular materials? How do those reasons translate to sampling priorities? In what condition would these samples be expected to be received? What is our best projection of the approach by which these samples would be divided, prepared, and analyzed to achieve our objectives?

Durability of pulp fiber-cement composites

NASA Astrophysics Data System (ADS)

Mohr, Benjamin J.

Wood pulp fibers are a unique reinforcing material as they are non-hazardous, renewable, and readily available at relatively low cost compared to other commercially available fibers. Today, pulp fiber-cement composites can be found in products such as extruded non-pressure pipes and non-structural building materials, mainly thin-sheet products. Although natural fibers have been used historically to reinforce various building materials, little scientific effort has been devoted to the examination of natural fibers to reinforce engineering materials until recently. The need for this type of fundamental research has been emphasized by widespread awareness of moisture-related failures of some engineered materials; these failures have led to the filing of national- and state-level class action lawsuits against several manufacturers. Thus, if pulp fiber-cement composites are to be used for exterior structural applications, the effects of cyclical wet/dry (rain/heat) exposure on performance must be known. Pulp fiber-cement composites have been tested in flexure to examine the progression of strength and toughness degradation. Based on scanning electron microscopy (SEM), environmental scanning electron microscopy (ESEM), energy dispersive spectroscopy (EDS), a three-part model describing the mechanisms of progressive degradation has been proposed: (1) initial fiber-cement/fiber interlayer debonding, (2) reprecipitation of crystalline and amorphous ettringite within the void space at the former fiber-cement interface, and (3) fiber embrittlement due to reprecipitation of calcium hydroxide filling the spaces within the fiber cell wall structure. Finally, as a means to mitigate kraft pulp fiber-cement composite degradation, the effects of partial portland cement replacement with various supplementary cementitious materials (SCMs) has been investigated for their effect on mitigating kraft pulp fiber-cement composite mechanical property degradation (i.e., strength and toughness losses) during wet/dry cycling. SCMs have been found to be effective in mitigating composite degradation through several processes, including a reduction in the calcium hydroxide content, stabilization of monosulfate by maintaining pore solution pH, and a decrease in ettringite reprecipitation accomplished by increased binding of aluminum in calcium aluminate phases and calcium in the calcium silicate hydrate (C-S-H) phase.

Recycling stabilised/solidified drill cuttings for forage production in acidic soils.

PubMed

Kogbara, Reginald B; Dumkhana, Bernard B; Ayotamuno, Josiah M; Okparanma, Reuben N

2017-10-01

Stabilisation/solidification (S/S), which involves fixation and immobilisation of contaminants using cementitious materials, is one method of treating drill cuttings before final fate. This work considers reuse of stabilised/solidified drill cuttings for forage production in acidic soils. It sought to improve the sustainability of S/S technique through supplementation with the phytoremediation potential of plants, eliminate the need for landfill disposal and reduce soil acidity for better plant growth. Drill cuttings with an initial total petroleum hydrocarbon (TPH) concentration of 17,125 mg kg -1 and low concentrations of metals were treated with 5%, 10%, and 20% cement dosages. The treated drill cuttings were reused in granular form for growing a forage, elephant grass (Pennisetum purpureum), after mixing with uncontaminated soil. The grasses were also grown in uncontaminated soil. The phytoremediation and growth potential of the plants was assessed over a 12-week period. A mix ratio of one part drill cuttings to three parts uncontaminated soil was required for active plant growth. The phytoremediation ability of elephant grass (alongside abiotic losses) reduced the TPH level (up to 8795 mg kg -1 ) in the soil-treated-drill cuttings mixtures below regulatory (1000 mg kg -1 ) levels. There were also decreased concentrations of metals. The grass showed better heights and leaf lengths in soil containing drill cuttings treated with 5% cement dosage than in uncontaminated soil. The results suggest that recycling S/S treated drill cuttings for forage production may be a potential end use of the treated waste. Copyright © 2017 Elsevier Ltd. All rights reserved.

40 CFR 147.2104 - Requirements for all wells.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (PVC, ABS, or others) casings shall: (1) Not construct a well deeper than 500 feet; (2) Use cement and additives compatible with such casing material; and (3) Cement the annular space above the injection... feet below the lowermost USDW; (ii) Cementing surface casing by recirculating the cement to the surface...

40 CFR 147.305 - Requirements for all wells.

Code of Federal Regulations, 2010 CFR

2010-07-01

..., and others) casings shall: (1) Not construct a well deeper than 500 feet; (2) Use cement and additives compatible with such casing material; (3) Cement the annular space above the injection interval from the... base of the lowermost USDW; (ii) Cementing surface casing by recirculating the cement to the surface...

40 CFR 147.2104 - Requirements for all wells.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (PVC, ABS, or others) casings shall: (1) Not construct a well deeper than 500 feet; (2) Use cement and additives compatible with such casing material; and (3) Cement the annular space above the injection... feet below the lowermost USDW; (ii) Cementing surface casing by recirculating the cement to the surface...

40 CFR 147.305 - Requirements for all wells.

Code of Federal Regulations, 2011 CFR

2011-07-01

..., and others) casings shall: (1) Not construct a well deeper than 500 feet; (2) Use cement and additives compatible with such casing material; (3) Cement the annular space above the injection interval from the... base of the lowermost USDW; (ii) Cementing surface casing by recirculating the cement to the surface...

ELIMINATION OF WATER POLLUTION BY RECYCLING CEMENT PLANT KILN DUST

EPA Science Inventory

Excessive amounts of alkalies can have deleterious effects upon the process of cement manufacture and the product. Normally much of the alkali present in cement raw materials is volatilized in the cement kiln and condenses on the particles of kiln dust which are carried out of th...

Investigation of sub-slab pressure field extension in specified granular fill materials incorporating a sump-based soil depressurisation system for radon mitigation.

PubMed

Hung, Le Chi; Goggins, Jamie; Fuente, Marta; Foley, Mark

2018-05-14

Design of bearing layers (granular fill material layers) is important for a house with a soil depressurisation (SD) system for indoor radon mitigation. These layers should not only satisfy the bearing capacity and serviceability criteria but should also provide a sufficient degree of the air permeability for the system. Previous studies have shown that a critical parameter for a SD system is the sub-slab pressure field extension in the bearing layers, but this issue has not been systematically investigated. A series of two-dimensional computational fluid dynamic simulations that investigate the behaviour of the sub-slab pressure field extension developed in a SD system is presented in this paper. The SD system considered in this paper consists of a granular fill material layer and a radon sump. The granular fill materials are 'T1 Struc' and 'T2 Perm', which are standard materials for building in the Republic of Ireland. Different conditions, which might be encountered in a practical situation, were examined. The results show that the air permeability and thickness of the granular fill materials are the two key factors which affect the sub slab pressure field extension (SPFE) significantly. Furthermore, the air permeability of native soil is found to be a fundamental factor for the SPFE so that it should be well understood when designing a SD system. Therefore, these factors should be considered sufficiently in each practical situation. Finally, a significant improvement of the pressure field extension can be achieved by ensuring air tightness of the SD system. Copyright © 2018 Elsevier B.V. All rights reserved.

Study of the formation of duricrusts on the martian surface and their effect on sampling equipment

NASA Astrophysics Data System (ADS)

Kömle, Norbert; Pitcher, Craig; Gao, Yang; Richter, Lutz

2017-01-01

The Powdered Sample Dosing and Distribution System (PSDDS) of the ExoMars rover will be required to handle and contain samples of Mars regolith for long periods of time. Cementation of the regolith, caused by water and salts in the soil, results in clumpy material and a duricrust layer forming on the surface. It is therefore possible that material residing in the sampling system may cement, and could potentially hinder its operation. There has yet to be an investigation into the formation of duricrusts under simulated Martian conditions, or how this may affect the performance of sample handling mechanisms. Therefore experiments have been performed to create a duricrust and to explore the cementation of Mars analogues, before performing a series of tests on a qualification model of the PSDDS under simulated Martian conditions. It was possible to create a consolidated crust of cemented material several millimetres deep, with the material below remaining powder-like. It was seen that due to the very low permeability of the Montmorillonite component material, diffusion of water through the material was quickly blocked, resulting in a sample with an inhomogeneous water content. Additionally, samples with a water mass content of 10% or higher would cement into a single solid piece. Finally, tests with the PSDDS revealed that samples with a water mass content of just 5% created small clumps with significant internal cohesion, blocking the sample funnels and preventing transportation of the material. These experiments have highlighted that the cementation of regolith in Martian conditions must be taken into consideration in the design of sample handling instruments.

A modified cementing technique using BoneSource to augment fixation of the acetabulum in a sheep model.

PubMed

Timperley, A John; Nusem, Iulian; Wilson, Kathy; Whitehouse, Sarah L; Buma, Pieter; Crawford, Ross W

2010-08-01

Our aim was to assess in an animal model whether the use of HA paste at the cement-bone interface in the acetabulum improves fixation. We examined, in sheep, the effect of interposing a layer of hydroxyapatite cement around the periphery of a polyethylene socket prior to fixing it using polymethylmethacrylate (PMMA). We performed a randomized study involving 22 sheep that had BoneSource hydroxyapatite material applied to the surface of the acetabulum before cementing a polyethylene cup at arthroplasty. We studied the gross radiographic appearance of the implant-bone interface and the histological appearance at the interface. There were more radiolucencies evident in the control group. Histologically, only sheep randomized into the BoneSource group exhibited a fully osseointegrated interface. Use of the hydroxyapatite material did not give any detrimental effects. In some cases, the material appeared to have been fully resorbed. When the material was evident in histological sections, it was incorporated into an osseointegrated interface. There was no giant cell reaction present. There was no evidence of migration of BoneSource to the articulation. The application of HA material prior to cementation of a socket produced an improved interface. The technique may be useful in humans, to extend the longevity of the cemented implant by protecting the socket interface from the effect of hydrodynamic fluid flow and particulate debris.

A Twofold Comparison between Dual Cure Resin Modified Cement and Glass Ionomer Cement for Orthodontic Band Cementation.

PubMed

Attar, Hanaa El; Elhiny, Omnia; Salem, Ghada; Abdelrahman, Ahmed; Attia, Mazen

2016-12-15

To test the solubility of dual cure resin modified resin cement in a food simulating solution and the shear bond strength compared to conventional Glass ionomer cement. The materials tested were self-adhesive dual cure resin modified cement and Glass Ionomer (GIC). Twenty Teflon moulds were divided into two groups of tens. The first group was injected and packed with the modified resin cement, the second group was packed with GIC. To test the solubility, each mould was weighed before and after being placed in an analytical reagent for 30 days. The solubility was measured as the difference between the initial and final drying mass. To measure the Shear bond strength, 20 freshly extracted wisdom teeth were equally divided into two groups and embedded in self-cure acrylic resin. Four mm sections of stainless steel bands were cemented to the exposed buccal surfaces of teeth under a constant load of 500 g. Shear bond strength was measured using a computer controlled materials testing machine and the load required to deband the samples was recorded in Newtons. GIC showed significantly higher mean weight loss and an insignificant lower Shear bond strength, compared to dual cure resin Cement. It was found that dual cure resin modified cement was less soluble than glass ionomer cement and of comparable bond strength rendering it more useful clinically for orthodontic band cementation.

Mechanics of Granular Materials (MGM) Test Cell

NASA Technical Reports Server (NTRS)

2000-01-01

A test cell for Mechanics of Granular Materials (MGM) experiment is tested for long-term storage with water in the system as plarned for STS-107. This view shows the compressed sand column with the protective water jacket removed. Sand and soil grains have faces that can cause friction as they roll and slide against each other, or even cause sticking and form small voids between grains. This complex behavior can cause soil to behave like a liquid under certain conditions such as earthquakes or when powders are handled in industrial processes. Mechanics of Granular Materials (MGM) experiments aboard the Space Shuttle use the microgravity of space to simulate this behavior under conditons that cannot be achieved in laboratory tests on Earth. MGM is shedding light on the behavior of fine-grain materials under low effective stresses. Applications include earthquake engineering, granular flow technologies (such as powder feed systems for pharmaceuticals and fertilizers), and terrestrial and planetary geology. Nine MGM specimens have flown on two Space Shuttle flights. Another three are scheduled to fly on STS-107. The principal investigator is Stein Sture of the University of Colorado at Boulder. Credit: University of Colorado at Boulder

Mechanics of Granular Materials (MGM) Cell

NASA Technical Reports Server (NTRS)

1996-01-01

One of three Mechanics of Granular Materials (MGM) test cells after flight on STS-79 and before impregnation with resin. Note that the sand column has bulged in the middle, and that the top of the column is several inches lower than the top of the plastic enclosure. Sand and soil grains have faces that can cause friction as they roll and slide against each other, or even cause sticking and form small voids between grains. This complex behavior can cause soil to behave like a liquid under certain conditions such as earthquakes or when powders are handled in industrial processes. Mechanics of Granular Materials (MGM) experiments aboard the Space Shuttle use the microgravity of space to simulate this behavior under conditons that carnot be achieved in laboratory tests on Earth. MGM is shedding light on the behavior of fine-grain materials under low effective stresses. Applications include earthquake engineering, granular flow technologies (such as powder feed systems for pharmaceuticals and fertilizers), and terrestrial and planetary geology. Nine MGM specimens have flown on two Space Shuttle flights. Another three are scheduled to fly on STS-107. The principal investigator is Stein Sture of the University of Colorado at Boulder. Credit: University of Colorado at Boulder

Mechanics of Granular Materials (MGM) Test Cell

NASA Technical Reports Server (NTRS)

2000-01-01

A test cell for Mechanics of Granular Materials (MGM) experiment is tested for long-term storage with water in the system as plarned for STS-107. This view shows the top of the sand column with the metal platten removed. Sand and soil grains have faces that can cause friction as they roll and slide against each other, or even cause sticking and form small voids between grains. This complex behavior can cause soil to behave like a liquid under certain conditions such as earthquakes or when powders are handled in industrial processes. Mechanics of Granular Materials (MGM) experiments aboard the Space Shuttle use the microgravity of space to simulate this behavior under conditons that cannot be achieved in laboratory tests on Earth. MGM is shedding light on the behavior of fine-grain materials under low effective stresses. Applications include earthquake engineering, granular flow technologies (such as powder feed systems for pharmaceuticals and fertilizers), and terrestrial and planetary geology. Nine MGM specimens have flown on two Space Shuttle flights. Another three are scheduled to fly on STS-107. The principal investigator is Stein Sture of the University of Colorado at Boulder. Credit: University of Colorado at Boulder

Effects of fabric anisotropy on elastic shear modulus of granular soils

NASA Astrophysics Data System (ADS)

Li, Bo; Zeng, Xiangwu

2014-06-01

The fabric anisotropy of a granular soil deposit can strongly influence its engineering properties and behavior. This paper presents the results of a novel experimental study designed to examine the effects of fabric anisotropy on smallstrain stiffness and its evolution with loading on the elastic shear modulus of granular materials under a K 0 condition. Two primary categories of fabric anisotropy, i.e., deposition-induced and particle shape-induced, are investigated. Toyoura sand deposits with relative densities of 40% and 80% were prepared using deposition angles oriented at 0° and 90°. Piezoelectric transducers were used to obtain the elastic shear modulus in the vertical and horizontal directions ( G vh and G hh). The measurements indicate distinct differences in the values of G with respect to the different deposition angles. Particle shapeinduced fabric anisotropy was examined using four selected sands. It was concluded that sphericity is a controlling factor dominating the small-strain stiffness of granular materials. The degree of fabric anisotropy proves to be a good indicatorin the characterization of stress-induced fabric evolution during loading and unloading stress cycles. The experimental data were used to calibrate an existing micromechanical model, which was able to represent the behavior of the granular material and the degree of fabric anisotropy reasonably well.

Polymeric additives to enhance the functional properties of calcium phosphate cements

PubMed Central

Perez, Roman A; Kim, Hae-Won

2012-01-01

The vast majority of materials used in bone tissue engineering and regenerative medicine are based on calcium phosphates due to their similarity with the mineral phase of natural bone. Among them, calcium phosphate cements, which are composed of a powder and a liquid that are mixed to obtain a moldable paste, are widely used. These calcium phosphate cement pastes can be injected using minimally invasive surgery and adapt to the shape of the defect, resulting in an entangled network of calcium phosphate crystals. Adding an organic phase to the calcium phosphate cement formulation is a very powerful strategy to enhance some of the properties of these materials. Adding some water-soluble biocompatible polymers in the calcium phosphate cement liquid or powder phase improves physicochemical and mechanical properties, such as injectability, cohesion, and toughness. Moreover, adding specific polymers can enhance the biological response and the resorption rate of the material. The goal of this study is to overview the most relevant advances in this field, focusing on the different types of polymers that have been used to enhance specific calcium phosphate cement properties. PMID:22511991

Influence of various amount of diatomaceous earth used as cement substitute on mechanical properties of cement paste

NASA Astrophysics Data System (ADS)

Pokorný, Jaroslav; Pavlíková, Milena; Medved, Igor; Pavlík, Zbyšek; Zahálková, Jana; Rovnaníková, Pavla; Černý, Robert

2016-06-01

Active silica containing materials in the sub-micrometer size range are commonly used for modification of strength parameters and durability of cement based composites. In addition, these materials also assist to accelerate cement hydration. In this paper, two types of diatomaceous earths are used as partial cement replacement in composition of cement paste mixtures. For raw binders, basic physical and chemical properties are studied. The chemical composition of tested materials is determined using classical chemical analysis combined with XRD method that allowed assessment of SiO2 amorphous phase content. For all tested mixtures, initial and final setting times are measured. Basic physical and mechanical properties are measured on hardened paste samples cured 28 days in water. Here, bulk density, matrix density, total open porosity, compressive and flexural strength, are measured. Relationship between compressive strength and total open porosity is studied using several empirical models. The obtained results give evidence of high pozzolanic activity of tested diatomite earths. Their application leads to the increase of both initial and final setting times, decrease of compressive strength, and increase of flexural strength.

Evaluation of selected properties of a new root repair cement containing surface pre-reacted glass ionomer fillers.

PubMed

Yassen, Ghaeth H; Huang, Ruijie; Al-Zain, Afnan; Yoshida, Takamitsu; Gregory, Richard L; Platt, Jeffrey A

2016-11-01

This study evaluated selected properties of a prototype root repair cement containing surface pre-reacted glass ionomer fillers (S-PRG) in comparison to mineral trioxide aggregate (MTA) and intermediate restorative material (IRM). The antibacterial effect of S-PRG, MTA, and IRM cements was tested against Porphyromonas gingivalis and Enterococcus faecalis after 1 and 3 days of aging of the cements. The set cements were immersed in distilled water for 4 h to 28 days, and ion-releasing ability was evaluated. Initial and final setting times of all cements were evaluated using Gilmore needles. The push-out bond strength between radicular dentin and all cements was tested at different levels of the roots. S-PRG and IRM cements, but not MTA cement, demonstrated significant antibacterial effect against P. gingivalis. All types of cements exhibited significant antibacterial effect against E. faecalis without being able to eliminate the bacterium. S-PRG cement provided continuous release of fluoride, strontium, boron, sodium, aluminum, and zinc throughout all tested time points. Both initial and final setting times were significantly shorter for S-PRG and IRM cements in comparison to MTA. The push-out bond strength was significantly lower for S-PRG cement in comparison to MTA and IRM at coronal and middle levels of the roots. S-PRG cement demonstrated significant antibacterial effects against endodontic pathogens, multiple ion-releasing ability, relatively short setting time, and low bonding strength. S-PRG cement can be used as a one-visit root repair material with promising antibacterial properties and ion-releasing capacity.

40 CFR 411.30 - Applicability; description of the materials storage piles runoff subcategory.

Code of Federal Regulations, 2014 CFR

2014-07-01

... PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS CEMENT MANUFACTURING POINT SOURCE CATEGORY... products, finished products and waste materials which are used in or derived from the manufacture of cement...

40 CFR 411.30 - Applicability; description of the materials storage piles runoff subcategory.

Code of Federal Regulations, 2011 CFR

2011-07-01

... PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS CEMENT MANUFACTURING POINT SOURCE CATEGORY... products, finished products and waste materials which are used in or derived from the manufacture of cement...

40 CFR 411.30 - Applicability; description of the materials storage piles runoff subcategory.

Code of Federal Regulations, 2013 CFR

2013-07-01

... PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS CEMENT MANUFACTURING POINT SOURCE CATEGORY... products, finished products and waste materials which are used in or derived from the manufacture of cement...

40 CFR 411.30 - Applicability; description of the materials storage piles runoff subcategory.

Code of Federal Regulations, 2012 CFR

2012-07-01

... PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS CEMENT MANUFACTURING POINT SOURCE CATEGORY... products, finished products and waste materials which are used in or derived from the manufacture of cement...

Utilizing Coal Fly Ash and Recycled Glass in Developing Green Concrete Materials

DOT National Transportation Integrated Search

2012-06-01

The environmental impact of Portland cement concrete production has motivated researchers and the construction industry to evaluate alternative technologies for incorporating recycled cementing materials and recycled aggregates in concrete. One such ...

Evaluation of concrete patching materials : final report.

DOT National Transportation Integrated Search

1985-01-01

The project evaluated numerous repairs on portland cement concrete pavements and bridge decks made with a number of laboratory accepted, proprietary patching materials and portland cement concrete mixtures of different designs. It was ascertained tha...

40 CFR 411.30 - Applicability; description of the materials storage piles runoff subcategory.

Code of Federal Regulations, 2010 CFR

2010-07-01

... PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS CEMENT MANUFACTURING POINT SOURCE CATEGORY... products, finished products and waste materials which are used in or derived from the manufacture of cement...

Apparatus and methods for filtering granular solid material

NASA Technical Reports Server (NTRS)

Backes, Douglas J. (Inventor); Poulter, Clay B. (Inventor); Godfrey, Max R. (Inventor); Tolman, Dennis K. (Inventor); Dutton, Melinda S. (Inventor)

2011-01-01

Apparatuses for screening granular solid particulate material include a generally planar first screen and a second screen. A plurality of apertures extends through the first screen. At least a portion of the second screen is oriented at an angle to the first screen, and apertures extend through a perforated region of the second screen. The second screen includes at least one region configured to prevent at least some particles of solid material from passing through the second screen.

Temperature rise in ion-leachable cements during setting reaction.

PubMed

Kanchanavasita, W; Pearson, G J; Anstice, H M

1995-11-01

Resin-modified ion-leachable cements have been developed for use as aesthetic restorative materials. Their apparent improved physical and handling properties can make them more attractive for use than conventional glass-ionomers. However, they contain monomers which are known to contract on polymerization and produce a polymerization exotherm. This study evaluated the temperature rise during setting and the rate of dimensional change of several ion-leachable materials. The resin-modified ion-leachable cements demonstrated greater temperature rises and higher rates of contraction than conventional materials. Generally, the behaviour of these resin-modified materials was similar to that of composite resins. However, some resin-modified cements produced a temperature rise of up to 20 degrees C during polymerization which was greater than that of the composite resin. This temperature rise must be taken into account when using the materials in direct contact with dentine in deep cavities without pulp protection. Longer irradiation time than the recommended 20 s did not significantly increase the maximum temperature rise but slightly extended the time before the temperature started to decline. The temperature of the environment had a significant effect on the rate of dimensional change in some materials. The rate of polymerization contraction of light-activated cements was directly related to the observed temperature rise.

Production, characterization, and mechanical behavior of cementitious materials incorporating carbon nanofibers

NASA Astrophysics Data System (ADS)

Yazdanbakhsh, Ardavan

Carbon nanotubes (CNTs) and carbon nanofirbers (CNFs) have excellent properties (mechanical, electrical, magnetic, etc.), which can make them effective nanoreinforcements for improving the properties of materials. The incorporation of CNT/Fs in a wide variety of materials has been researched extensively in the past decade. However, the past study on the reinforcement of cementitious materials with these nanofilaments has been limited. The findings from those studies indicate that CNT/Fs did not significantly improve the mechanical properties of cementitious materials. Two major parameters influence the effectiveness of any discrete inclusion in composite material: The dispersion quality of the inclusions and the interfacial bond between the inclusions and matrix. The main focus of this dissertation is on the dispersion factor, and consists of three main tasks: First a novel thermodynamic-based method for dispersion quantification was developed. Second, a new method, incorporating the utilization of silica fume, was devised to improve and stabilize the dispersion of CNFs in cement paste. And third, the dispersion quantification method and mechanical testing were employed to measure, compare, and correlate the dispersion and mechanical properties of CNF-incorporated cement paste produced with the conventional and new methods. Finally, the main benefits, including the increase in strength and resistance to shrinkage cracking, obtained from the utilization of CNFs in cement paste will be presented. The investigations and the corresponding results show that the novel dispersion quantification method can be implemented easily to perform a wide variety of tasks ranging from measuring dispersion of nanofilaments in composites using their optical/SEM micrographs as input, to measuring the effect of cement particle/clump size on the dispersion of nano inclusions in cement paste. It was found that cement particles do not affect the dispersion of nano inclusions in cement paste significantly while the dispersion of nano inclusions can notably degenerates if the cement particles are agglomerated. The novel dispersion quantification method shows that, the dispersion of CNFs in cement paste significantly improves by utilizing silica fume. However, it was found that the dispersion of silica fume particles is an important parameter and poorly dispersed silica fume cannot enhance the overall dispersion of nano inclusions in cementitious materials. Finally, the mechanical testing and experimentations showed that CNFs, in absence of moist curing, even if poorly dispersed, can provide important benefits in terms of strength and crack resistance.

Noise and diffusion of a vibrated self-propelled granular particle

NASA Astrophysics Data System (ADS)

Walsh, Lee; Wagner, Caleb G.; Schlossberg, Sarah; Olson, Christopher; Baskaran, Aparna; Menon, Narayanan

Granular materials are an important physical realization of active matter. In vibration-fluidized granular matter, both diffusion and self-propulsion derive from the same collisional forcing, unlike many other active systems where there is a clean separation between the origin of single-particle mobility and the coupling to noise. Here we present experimental studies of single-particle motion in a vibrated granular monolayer, along with theoretical analysis that compares grain motion at short and long time scales to the assumptions and predictions, respectively, of the active Brownian particle (ABP) model. The results demonstrate that despite the unique relation between noise and propulsion, granular media do show the generic features predicted by the ABP model and indicate that this is a valid framework to predict collective phenomena. Additionally, our scheme of analysis for validating the inputs and outputs of the model can be applied to other granular and non-granular systems.

A Study of SDT in an Ammonium Nitrate (NH4 NO3) Based Granular Explosive

NASA Astrophysics Data System (ADS)

Burns, Malcolm; Taylor, Peter

2007-06-01

In order to study the SDT process in a granular non ideal explosive (NIE) an experimental technique has been developed that allows the granular explosive to be shock initiated at a well controlled ``tap density''. The granular NIE was contained in a PMMA cone and a planar shock was delivered to the explosive through buffer plates of varying material. A combination of piezoelectric probes, ionization pins, PVDF stress gauges and a high speed framing camera were used to measure the input shock pressure and shock and detonation wave positions in the explosive. Four trials were performed to characterize the run to detonation distance versus pressure relationship (Pop plot) of the granular NH4 NO3 explosive. Input pressures ranged from close to the 4GPa predicted CJ pressure of the granular explosive down to 1.4 GPa, giving run distances up to 14mm for the lowest pressure. The data indicates a steady acceleration of the input shock to the detonation velocity, implying significant reaction growth at the shock front. This is in contrast to the behaviour of most high density pressed PBXs which show little growth in shock front velocity before transit to detonation. The experimentally observed initiation behaviour is compared to that predicted by a simple JWL++ reactive burn model for the granular NH4 NO3 explosive which has been fitted to other detonics experiments on this material.

Post-irradiation hardening of dual-cured and light-cured resin cements through machinable ceramics.

PubMed

Yoshida, Keiichi; Atsuta, Mitsuru

2006-10-01

To evaluate the surface hardness (Knoop Hardness Number) of the thin layer in three light-cured and dual-cured resin cements irradiated through or not through 2.0 mm thick machinable ceramics. A piece of adhesive polyethylene tape with a circular hole was positioned on the surface of the ceramic plate to control the cement layer (approximately 50 microm). The cement paste was placed on the ceramic surface within the circle. The ceramic plate with resin cement paste was placed on a clear micro cover glass over a zirconia ceramic block to obtain a flat surface, and the material was polymerized using a visible-light-curing unit. The surface hardness was recorded at a series of time intervals up to 5 days, starting from the end of a light-irradiation period. The hardness steadily increased with post-irradiation time and tended towards a maximum, usually reached after 1 or 2 days. In all cases, the increase in hardness was relatively rapid over the first 30 minutes and continued at a lower rate thereafter. The dual-cured resin cement for each material showed a significantly higher hardness value than the light-cured resin cement irradiated either through or not through ceramics at all post-irradiation times. The resin cements cured through ceramic for each material were significantly less hard compared with those cured not through ceramics at all post-irradiation times.

Effect of ultrasonic agitation on push-out bond strength and adaptation of root-end filling materials.

PubMed

Alcalde, Murilo Priori; Vivan, Rodrigo Ricci; Marciano, Marina Angélica; Duque, Jussaro Alves; Fernandes, Samuel Lucas; Rosseto, Mariana Bailo; Duarte, Marco Antonio Hungaro

2018-05-01

This study evaluated the effect of ultrasonic agitation of mineral trioxide aggregate (MTA), calcium silicate-based cement (CSC), and Sealer 26 (S26) on adaptation at the cement/dentin interface and push-out bond strength. Sixty maxillary canines were divided into 6 groups ( n = 10): MTA, S26, and CSC, with or without ultrasonic activation (US). After obturation, the apical portions of the teeth were sectioned, and retrograde cavities were prepared and filled with cement by hand condensation. In the US groups, the cement was activated for 60 seconds: 30 seconds in the mesio-distal direction and 30 seconds in the buccal-lingual direction, using a mini Irrisonic insert coupled with the ultrasound transducer. After the materials set, 1.5-mm thick sections were obtained from the apexes. The presence of gaps and the bond between cement and dentin were analyzed using low-vacuum scanning electron microscopy. Push-out bond strength was measured using a universal testing machine. Ultrasonic agitation increased the interfacial adaptation of the cements. The S26 US group showed a higher adaptation value than MTA ( p < 0.05). US improved the push-out bond strength for all the cements ( p < 0.05). The US of retrograde filling cements enhanced the bond to the dentin wall of the root-end filling materials tested.

Recycling the product of thermal transformation of cement-asbestos for the preparation of calcium sulfoaluminate clinker.

PubMed

Viani, Alberto; Gualtieri, Alessandro F

2013-09-15

According to recent resolutions of the European Parliament (2012/2065(INI)), the need for environmentally friendly alternative solutions to landfill disposal of hazardous wastes, such as asbestos-containing materials, prompts their recycling as secondary raw materials (end of waste concept). In this respect, for the first time, we report the recycling of the high temperature product of cement-asbestos, in the formulation of calcium sulfoaluminate cement clinkers (novel cementitious binders designed to reduce CO₂ emissions), as a continuation of a previous work on their systematic characterization. Up to 29 wt% of the secondary raw material was successfully introduced into the raw mix. Different clinker samples were obtained at 1250 °C and 1300 °C, reproducing the phase composition of industrial analogues. As an alternative source of Ca and Si, this secondary raw material allows for a reduction of the CO₂ emissions in cement production, mitigating the ecological impact of cement manufacturing, and reducing the need for natural resources. Copyright © 2013 Elsevier B.V. All rights reserved.

ELECTROCHEMICAL DEGRADATION OF POLYCHLOROBIPHENYLS

EPA Science Inventory

Granular graphite is an ideal conductive material for electrochemical reduction technology applications in the field. Granular graphite was used to enhance the transfer of chlorinated aliphatic compounds in saturated, low permeability soils by electroosmosis. It was also used to ...

The effect of endodontic materials on the optical density of dyes used in marginal leakage studies.

PubMed

Kubo, Claudio Hideki; Valera, Marcia Carneiro; Gomes, Ana Paula Martins; Mancini, Maria Nadir Gasparoto; Camargo, Carlos Henrique Ribeiro

2008-01-01

The aim of this study was to determine the effect of the exposure of different endodontic materials to different dye solutions by evaluating the optical density of the dye solutions. Seventy-five plastic tubes were filled with one of the following materials: AH Plus, Sealapex, Portland cement, MTA (Angelus and Pro Root) and fifteen control plastic tubes were not. Each specimen of material and control was immersed in a container with 1 ml of each dye solution. A 0.1 ml-dye solution aliquote was removed before immersion and after 12, 24, 48 and 72 hours of each specimen immersion to record its optical density (OD) in a spectrophotometer. Statistical analysis was performed with ANOVA and Tukey tests (5%). No significant difference was found among any of the solution OD values for AH Plus cement. Portland cement promoted different OD values after 12 hours of immersion. MTA-Angelus cement presented different OD values only for 2% rhodamine B and the MTA-Pro Root cement presented different OD values in all 2% rhodamine B samples. Sealapex cement promoted a reduction in the India Ink OD values. Dye evaluation through OD seems to be an interesting method to select the best dye solution to use in a given marginal leakage study.

Evaluation of the Ca ion release, pH and surface apatite formation of a prototype tricalcium silicate cement.

PubMed

Yamamoto, S; Han, L; Noiri, Y; Okiji, T

2017-12-01

To evaluate the Ca 2+ -releasing, alkalizing and apatite-like surface precipitate-forming abilities of a prototype tricalcium silicate cement, which was mainly composed of synthetically prepared tricalcium silicate and zirconium oxide radiopacifier. The prototype tricalcium silicate cement, white ProRoot MTA (WMTA) and TheraCal LC (a light-cured resin-modified calcium silicate-filled material) were examined. The chemical compositions were analysed with a wavelength-dispersive X-ray spectroscopy electron probe microanalyser with an image observation function (SEM-EPMA). The pH and Ca 2+ concentrations of water in which the set materials had been immersed were measured, and the latter was assessed with the EDTA titration method. The surface precipitates formed on the materials immersed in phosphate-buffered saline (PBS) were analysed with SEM-EPMA and X-ray diffraction (XRD). Kruskal-Wallis tests followed by Mann-Whitney U-test with Bonferroni correction were used for statistical analysis (α = 0.05). The prototype cement contained Ca, Si and Zr as major elemental constituents, whereas it did not contain some metal elements that were detected in the other materials. The Ca 2+ concentrations and pH of the immersion water samples exhibited the following order: WMTA = prototype cement > TheraCal LC (P < 0.05). All three materials produced Ca- and P-containing surface precipitates after PBS immersion, and the precipitates produced by TheraCal LC displayed lower Ca/P ratios than those formed by the other materials. XRD peaks corresponding to hydroxyapatite were detected in the precipitates produced by the prototype cement and WMTA. The prototype tricalcium silicate cement exhibited similar Ca 2+ -releasing, alkalizing and apatite-like precipitate-forming abilities to WMTA. The Ca 2+ -releasing, alkalizing and apatite-like precipitate-forming abilities of TheraCal LC were lower than those of the other materials. © 2016 International Endodontic Journal. Published by John Wiley & Sons Ltd.

CEM V based special cementitious materials investigated by means of SANS method. Preliminary results

NASA Astrophysics Data System (ADS)

Dragolici, A. C.; Balasoiu, M.; Orelovich, O. L.; Ionascu, L.; Nicu, M.; Soloviov, D. V.; Kuklin, A. I.; Lizunov, E. I.; Dragolici, F.

2017-05-01

The management of the radioactive waste assume the conditioning in a cement matrix as an embedding, stable, disposal material. Cement matrix is the first and most important engineering barrier against the migration in the environment of the radionuclides contained in the waste packages. Knowing how the microstructure develops is therefore desirable in order to assess the compatibility of radioactive streams with cement and predict waste form performance during storage and disposal. For conditioning wastes containing radioactive aluminum new formulas of low basicity cements, using coatings as a barrier between the metal and the conditioning environment or introducing a corrosion inhibitor in the matrix system are required. Preliminary microstructure investigation of such improved CEM V based cement matrix is reported.

Development of Carbon Nanotube Modified Cement Paste with Microencapsulated Phase-Change Material for Structural–Functional Integrated Application

PubMed Central

Cui, Hongzhi; Yang, Shuqing; Memon, Shazim Ali

2015-01-01

Microencapsulated phase-change materials (MPCM) can be used to develop a structural–functional integrated cement paste having high heat storage efficiency and suitable mechanical strength. However, the incorporation of MPCM has been found to degrade the mechanical properties of cement based composites. Therefore, in this research, the effect of carbon nanotubes (CNTs) on the properties of MPCM cement paste was evaluated. Test results showed that the incorporation of CNTs in MPCM cement paste accelerated the cement hydration reaction. SEM micrograph showed that CNTs were tightly attached to the cement hydration products. At the age of 28 days, the percentage increase in flexural and compressive strength with different dosage of CNTs was found to be up to 41% and 5% respectively. The optimum dosage of CNTs incorporated in MPCM cement paste was found to be 0.5 wt %. From the thermal performance test, it was found that the cement paste panels incorporated with different percentages of MPCM reduced the temperature measured at the center of the room by up to 4.6 °C. Inverse relationship was found between maximum temperature measured at the center of the room and the dosage of MPCM. PMID:25867476

Comparative study of methods to measure the density of Cementious powders

PubMed Central

Helsel, Michelle A.; Bentz, Dale

2016-01-01

The accurate measurement of the density of hydraulic cement has an essential role in the determination of concrete mixture proportions. As more supplementary cementitious materials (SCM), such as fly ash, and slag, or cement replacements materials such as limestone and calcium carbonate are used in blended cements, knowledge of the density of each powder or of the blended cement would allow a more accurate calculation of the proportions of a concrete mixture by volume instead of by mass. The current ASTM standard for measuring cement density is the “Test Method for Density of Hydraulic Cements” (ASTM C188-14), which utilizes a liquid displacement method to measure the volume of the cement. This paper will examine advantageous modifications of the current ASTM test, by alcohol substitutions for kerosene. In addition, a gas (helium) pycnometry method is evaluated as a possible alternative to the current standard. The described techniques will be compared to determine the most precise and reproducible method for measuring the density of hydraulic cements and other powders. PMID:27099404

Re-use of drinking water treatment plant (DWTP) sludge: Characterization and technological behaviour of cement mortars with atomized sludge additions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Husillos Rodriguez, N., E-mail: nuriah@ietcc.csic.e; Martinez Ramirez, S.; Blanco Varela, M.T.

This paper aims to characterize spray-dried DWTP sludge and evaluate its possible use as an addition for the cement industry. It describes the physical, chemical and micro-structural characterization of the sludge as well as the effect of its addition to Portland cements on the hydration, water demand, setting and mechanical strength of standardized mortars. Spray drying DWTP sludge generates a readily handled powdery material whose particle size is similar to those of Portland cement. The atomized sludge contains 12-14% organic matter (mainly fatty acids), while its main mineral constituents are muscovite, quartz, calcite, dolomite and seraphinite (or clinoclor). Its amorphousmore » material content is 35%. The mortars were made with type CEM I Portland cement mixed with 10 to 30% atomized sludge exhibited lower mechanical strength than the control cement and a decline in slump. Setting was also altered in the blended cements with respect to the control.« less

Considerations for proper selection of dental cements.

PubMed

Simon, James F; Darnell, Laura A

2012-01-01

Selecting the proper cement for sufficient bond strength has become progressively complicated as the number of different materials for indirect restorations has increased. The success of any restoration is highly dependent on the proper cement being chosen and used. The function of the cement is not only to seal the restoration on the tooth but also, in some cases, to support the retention of the restoration. This ability to strengthen retention varies by the cement chosen by the clinician; therefore, careful consideration must precede cement selection.

Class C fly ash in pavements.

DOT National Transportation Integrated Search

2010-07-01

Portland cement is the most dominant material used in concrete pavements in the state of Nebraska. In order to improve performance, reduce cost, and advance sustainability, a percentage of the Portland cement is replaced with a recycled material know...

Economical concrete mix design utilizing blended cements, performance-based specifications, and pay factors.

DOT National Transportation Integrated Search

2013-05-01

This report showcases several new approaches of using materials science and structural mechanics to accomplish : sustainable design of concrete materials. The topics addressed include blended cements, fiber-reinforced concrete : (FRC), internal curin...

Cement stackdust treatment for materials in place.

DOT National Transportation Integrated Search

1976-07-01

This paper is a presentation of the experiences of : District 20 of the State Department of Highways and : Public Transportation in experimenting with cement : stackdust as a stabilizing agent for base and subbase : roadway materials. It includes lab...

Sulfate and acid resistant concrete and mortar

DOEpatents

Liskowitz, John W.; Wecharatana, Methi; Jaturapitakkul, Chai; Cerkanowicz, deceased, Anthony E.

1998-01-01

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction and other applications, which hardenable mixtures demonstrate significant levels of acid and sulfate resistance while maintaining acceptable compressive strength properties. The acid and sulfate hardenable mixtures of the invention containing fly ash comprise cementitious materials and a fine aggregate. The cementitous materials may comprise fly ash as well as cement. The fine aggregate may comprise fly ash as well as sand. The total amount of fly ash in the hardenable mixture ranges from about 60% to about 120% of the total amount of cement, by weight, whether the fly ash is included as a cementious material, fine aggregate, or an additive, or any combination of the foregoing. In specific examples, mortar containing 50% fly ash and 50% cement in cementitious materials demonstrated superior properties of corrosion resistance.

Sulfate and acid resistant concrete and mortar

DOEpatents

Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

1998-06-30

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction and other applications, which hardenable mixtures demonstrate significant levels of acid and sulfate resistance while maintaining acceptable compressive strength properties. The acid and sulfate hardenable mixtures of the invention containing fly ash comprise cementitious materials and a fine aggregate. The cementitous materials may comprise fly ash as well as cement. The fine aggregate may comprise fly ash as well as sand. The total amount of fly ash in the hardenable mixture ranges from about 60% to about 120% of the total amount of cement, by weight, whether the fly ash is included as a cementious material, fine aggregate, or an additive, or any combination of the foregoing. In specific examples, mortar containing 50% fly ash and 50% cement in cementitious materials demonstrated superior properties of corrosion resistance. 6 figs.

The automated design of materials far from equilibrium

NASA Astrophysics Data System (ADS)

Miskin, Marc Z.

Automated design is emerging as a powerful concept in materials science. By combining computer algorithms, simulations, and experimental data, new techniques are being developed that start with high level functional requirements and identify the ideal materials that achieve them. This represents a radically different picture of how materials become functional in which technological demand drives material discovery, rather than the other way around. At the frontiers of this field, materials systems previously considered too complicated can start to be controlled and understood. Particularly promising are materials far from equilibrium. Material robustness, high strength, self-healing and memory are properties displayed by several materials systems that are intrinsically out of equilibrium. These and other properties could be revolutionary, provided they can first be controlled. This thesis conceptualizes and implements a framework for designing materials that are far from equilibrium. We show how, even in the absence of a complete physical theory, design from the top down is possible and lends itself to producing physical insight. As a prototype system, we work with granular materials: collections of athermal, macroscopic identical objects, since these materials function both as an essential component of industrial processes as well as a model system for many non-equilibrium states of matter. We show that by placing granular materials in the context of design, benefits emerge simultaneously for fundamental and applied interests. As first steps, we use our framework to design granular aggregates with extreme properties like high stiffness, and softness. We demonstrate control over nonlinear effects by producing exotic aggregates that stiffen under compression. Expanding on our framework, we conceptualize new ways of thinking about material design when automatic discovery is possible. We show how to build rules that link particle shapes to arbitrary granular packing density. We examine how the results of a design process are contingent upon operating conditions by studying which shapes dissipate energy fastest in a granular gas. We even move to create optimization algorithms for the expressed purpose of material design, by integrating them with statistical mechanics. In all of these cases, we show that turning to machines puts a fresh perspective on materials far from equilibrium. By matching forms to functions, complexities become possibilities, motifs emerge that describe new physics, and the door opens to rational design.

Wellbore Seal Repair Using Nanocomposite Materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stormont, John

2016-08-31

Nanocomposite wellbore repair materials have been developed, tested, and modeled through an integrated program of laboratory testing and numerical modeling. Numerous polymer-cement nanocomposites were synthesized as candidate wellbore repair materials using various combinations of base polymers and nanoparticles. Based on tests of bond strength to steel and cement, ductility, stability, flowability, and penetrability in opening of 50 microns and less, we identified Novolac epoxy reinforced with multi-walled carbon nanotubes and/or alumina nanoparticles to be a superior wellbore seal material compared to conventional microfine cements. A system was developed for testing damaged and repaired wellbore specimens comprised of a cement sheathmore » cast on a steel casing. The system allows independent application of confining pressures and casing pressures while gas flow is measured through the specimens along the wellbore axis. Repair with the nanocomposite epoxy base material was successful in dramatically reducing the flow through flaws of various sizes and types, and restoring the specimen comparable to an intact condition. In contrast, repair of damaged specimens with microfine cement was less effective, and the repair degraded with application of stress. Post-test observations confirm the complete penetration and sealing of flaws using the nanocomposite epoxy base material. A number of modeling efforts have supported the material development and testing efforts. We have modeled the steel-repair material interface behavior in detail during slant shear tests, which we used to characterize bond strength of candidate repair materials. A numerical model of the laboratory testing of damaged wellbore specimens was developed. This investigation found that microannulus permeability can satisfactorily be described by a joint model. Finally, a wellbore model has been developed that can be used to evaluate the response of the wellbore system (casing, cement, and microannulus), including the use of either cement or a nanocomposite in the microannulus to represent a repaired system. This wellbore model was successfully coupled with a field-scale model of CO 2 injection, to enable predictions of stress and strains in the wellbore subjected to subsurface changes (i.e. domal uplift) associated with fluid injection.« less

Analysis of the properties of dental cements after exposure to incubation media containing Streptococcus mutans.

PubMed

de Menezes, Fernando Carlos Hueb; Junior, Geraldo Thedei; de Oliveira, Wildomar Jose; Paulino, Tony de Paiva; de Moura, Marcelo Boaventura; da Silva, Igor Lima; de Moura, Marcos Boaventura

2011-09-01

Indirect restorations are increasingly used in dentistry, and the cementation interface is possibly the most critical region of the work. The objective of the present work was to evaluate the influence of exposure to a culture medium containing S. mutans on the hardness and solubility of four different cementing agents (zinc phosphate, glass ionomer, glass ionomer modified with resin and resin cement). Test specimens composed of these cements were exposed for 30 days in a culture medium containing S. mutans. After leaching, the test materials were assessed in terms of their solubility (loss of mass) and Knoop (KHN) microhardness. Changes in surface morphology were identified using scanning electron microscopy (SEM). The resin cement showed no significant solubility and its hardness increased following exposure and leaching, while the zinc phosphate cement was the most soluble and its hardness decreased after exposure to the culture medium. SEM analyses identified morphological alterations on the surfaces of the test materials that were compatible with the solubility results. It is concluded that resinous cements perform better than water-based cements when exposed to acidic conditions. The effects of acids from Streptococcus mutans can interfere with the efficiency and properties of some cements used for fixation of indirect restorations, exposed to the buccal environment.

Spatiotemporally Resolved Acoustics in a Photoelastic Granular Material

NASA Astrophysics Data System (ADS)

Owens, Eli; Daniels, Karen

2010-03-01

In granular materials, stress transmission is manifested as force chains that propagate through the material in a branching structure. We send acoustic pulses into a two dimensional photoelastic granular material in which force chains are visible and investigate how the force chains influence the amplitude, speed, and dispersion of the sound waves. We observe particle scale dynamics using two methods, movies which provide spatiotemporally resolved measurements and accelerometers within individual grains. The movies allow us to visualize the sound's path through the material, revealing that the sound travels primarily along the force chains. Using the brightness of the photoelastic particles as a measure of the force chain strength, we observe that the sound travels both faster and at higher amplitude along the strong force chains. An exception to this trend is seen in transient force chains that only exist while the sound is closing particle contacts. We also measure the frequency dependence of the amplitude, speed, and dispersion of the sound wave.

[Effect of ceramic thickness and resin cement shades on final color of heat-pressed ceramic veneers].

PubMed

Ren, D F; Zhan, K R; Chen, X D; Xing, W Z

2017-02-09

Objective: To analyze the effect of ceramic materials thickness and resin cement shades on the final color of ceramic veneers in the discolored teeth, and to investigate the color agreement of try-in pastes to the corresponding resin cements. Methods: Sixty artificial maxillary central incisor teeth (C2 shade) were used to simulate the natural discolored teeth and prepared according to veneer tooth preparation protocol. Veneers of different thickness in the body region (0.50 and 0.75 mm) were fabricated using ceramic materials (LT A2 shade, IPS e.max Press). The ceramic veneer specimens were bonded to the artificial teeth using the 6 shades of resin cements (Variolink Veneer: shades of LV-3, LV-2, HV+3; RelyX™ Veneer: shades of TR, A3, WO) ( n= 5). A clinical spectrophotometer was used to measure the color parameters of ceramic veneers at the cervical, body and incisal regions. Color changes of veneers before and after cementation were calculated and registered as ΔE1, and the changes between try-in paste and the corresponding resin cements were registered as ΔE2. Results: Three-way ANOVA indicated that ΔE1 and ΔE2 values were significantly affected by the ceramic thickness, resin cement shades and measuring regions ( P< 0.05). The ΔE1 values of six shades ranged from 0.59-8.27. The ΔE1 values were more than 2.72 when the ceramic veneers were cemented with resin cements in shades of HV+3 and WO. The ΔE2 values of six shades ranged from 0.60-2.56. The shades of HV+3, WO and A3 resin cements were more than 1.60. Conclusions: Different thickness of ceramic materials, resin cement shades and measuring regions could affect the final color of ceramic veneers. The color differences of some resin cements and corresponding try-in pastes might be observed in clinical practice.

Calcium Orthophosphate Cements and Concretes

PubMed Central

Dorozhkin, Sergey V.

2009-01-01

In early 1980s, researchers discovered self-setting calcium orthophosphate cements, which are a bioactive and biodegradable grafting material in the form of a powder and a liquid. Both phases form after mixing a viscous paste that after being implanted, sets and hardens within the body as either a non-stoichiometric calcium deficient hydroxyapatite (CDHA) or brushite, sometimes blended with unreacted particles and other phases. As both CDHA and brushite are remarkably biocompartible and bioresorbable (therefore, in vivo they can be replaced with newly forming bone), calcium orthophosphate cements represent a good correction technique for non-weight-bearing bone fractures or defects and appear to be very promising materials for bone grafting applications. Besides, these cements possess an excellent osteoconductivity, molding capabilities and easy manipulation. Furthermore, reinforced cement formulations are available, which in a certain sense might be described as calcium orthophosphate concretes. The concepts established by calcium orthophosphate cement pioneers in the early 1980s were used as a platform to initiate a new generation of bone substitute materials for commercialization. Since then, advances have been made in the composition, performance and manufacturing; several beneficial formulations have already been introduced as a result. Many other compositions are in experimental stages. In this review, an insight into calcium orthophosphate cements and concretes, as excellent biomaterials suitable for both dental and bone grafting application, has been provided.

Material Performance and Animal Clinical Studies on Performance-Optimized Hwangtoh Mixed Mortar and Concrete to Evaluate Their Mechanical Properties and Health Benefits

PubMed Central

Koo, Bon-Min; Kim, Jang-Ho Jay; Kim, Tae-Kyun; Kim, Byung-Yun

2015-01-01

In this study, the amount of cement used in a concrete mix is minimized to reduce the toxic effects on users by adjusting the concrete mixture contents. The reduction of cement is achieved by using various admixtures (ground granulated blast-furnace slag, flyash, ordinary Portland cement, and activated Hwangtoh powder). To apply the mix to construction, material property tests such as compressive strength, slump, and pH are performed. Preliminary experimental results showed that the Hwangtoh concrete could be used as a healthy construction material. Also, the health issues and effects of Hwangtoh mortar are quantitatively evaluated through an animal clinical test. Mice are placed in Hwangtoh mortar and cement mortar cages to record their activity. For the test, five cages are made with Hwangtoh and ordinary Portland cement mortar floors, using Hwangtoh powder replacement ratios of 20%, 40%, 60%, and 80% of the normal cement mortar mixing ratio, and two cages are made with Hwangtoh mortar living quarters. The activity parameter measurements included weight, food intake, water intake, residential space selection, breeding activity, and aggression. The study results can be used to evaluate the benefits of using Hwangtoh as a cement replacing admixture for lifestyle, health and sustainability. PMID:28793563

Material Performance and Animal Clinical Studies on Performance-Optimized Hwangtoh Mixed Mortar and Concrete to Evaluate Their Mechanical Properties and Health Benefits.

PubMed

Koo, Bon-Min; Kim, Jang-Ho Jay; Kim, Tae-Kyun; Kim, Byung-Yun

2015-09-17

In this study, the amount of cement used in a concrete mix is minimized to reduce the toxic effects on users by adjusting the concrete mixture contents. The reduction of cement is achieved by using various admixtures (ground granulated blast-furnace slag, flyash, ordinary Portland cement, and activated Hwangtoh powder). To apply the mix to construction, material property tests such as compressive strength, slump, and pH are performed. Preliminary experimental results showed that the Hwangtoh concrete could be used as a healthy construction material. Also, the health issues and effects of Hwangtoh mortar are quantitatively evaluated through an animal clinical test. Mice are placed in Hwangtoh mortar and cement mortar cages to record their activity. For the test, five cages are made with Hwangtoh and ordinary Portland cement mortar floors, using Hwangtoh powder replacement ratios of 20%, 40%, 60%, and 80% of the normal cement mortar mixing ratio, and two cages are made with Hwangtoh mortar living quarters. The activity parameter measurements included weight, food intake, water intake, residential space selection, breeding activity, and aggression. The study results can be used to evaluate the benefits of using Hwangtoh as a cement replacing admixture for lifestyle, health and sustainability.

Accretion Dynamics on Wet Granular Materials

NASA Astrophysics Data System (ADS)

Saingier, Guillaume; Sauret, Alban; Jop, Pierre

2017-05-01

Wet granular aggregates are common precursors of construction materials, food, and health care products. The physical mechanisms involved in the mixing of dry grains with a wet substrate are not well understood and difficult to control. Here, we study experimentally the accretion of dry grains on a wet granular substrate by measuring the growth dynamics of the wet aggregate. We show that this aggregate is fully saturated and its cohesion is ensured by the capillary depression at the air-liquid interface. The growth dynamics is controlled by the liquid fraction at the surface of the aggregate and exhibits two regimes. In the viscous regime, the growth dynamics is limited by the capillary-driven flow of liquid through the granular packing to the surface of the aggregate. In the capture regime, the capture probability depends on the availability of the liquid at the saturated interface, which is controlled by the hydrostatic depression in the material. We propose a model that rationalizes our observations and captures both dynamics based on the evolution of the capture probability with the hydrostatic depression.

Reducing cement content in concrete mixtures : [research brief].

DOT National Transportation Integrated Search

2011-12-01

Concrete mixtures contain crushed rock or gravel, and sand, bound together by Portland cement in combination with supplemental cementitious materials (SCMs), which harden through a chemical reaction with water. Portland cement is the most costly comp...

Optimization of fly ash as sand replacement materials (SRM) in cement composites containing coconut fiber

NASA Astrophysics Data System (ADS)

Nadzri, N. I. M.; Jamaludin, S. B.; Mazlee, M. N.; Jamal, Z. A. Z.

2016-07-01

The need of utilizing industrial and agricultural wastes is very important to maintain sustainability. These wastes are often incorporated with cement composites to improve performances in term of physical and mechanical properties. This study presents the results of the investigation of the response of cement composites containing coconut fiber as reinforcement and fly ash use as substitution of sand at different hardening days. Hardening periods of time (7, 14 and 28 days) were selected to study the properties of cement composites. Optimization result showed that 20 wt. % of fly ash (FA) is a suitable material for sand replacement (SRM). Meanwhile 14 days of hardening period gave highest compressive strength (70.12 MPa) from the cement composite containing 9 wt. % of coconut fiber and fly ash. This strength was comparable with the cement without coconut fiber (74.19 MPa) after 28 days of curing.

Magnesium-phosphate-glass cements with ceramic-type properties

DOEpatents

Sugama, T.; Kukacka, L.E.

1982-09-23

Rapid setting magnesium phosphate (Mg glass) cementitious materials consisting of magnesium phosphate cement paste, polyborax and water-saturated aggregate, exhibits rapid setting and high early strength characteristics. The magnesium glass cement is prepared from a cation-leachable powder and a bivalent metallic ion-accepting liquid such as an aqueous solution of diammonium phosphate and ammonium polyphosphate. The cation-leachable powder includes a mixture of two different magnesium oxide powders processed and sized differently which when mixed with the bivalent metallic ion-accepting liquid provides the magnesium glass cement consisting primarily of magnesium ortho phosphate tetrahydrate, with magnesium hydroxide and magnesium ammonium phosphate hexahydrate also present. The polyborax serves as a set-retarder. The resulting magnesium mono- and polyphosphate cements are particularly suitable for use as a cementing matrix in rapid repair systems for deteriorated concrete structures as well as construction materials and surface coatings for fireproof structures.

Magnesium phosphate glass cements with ceramic-type properties

DOEpatents

Sugama, Toshifumi; Kukacka, Lawrence E.

1984-03-13

Rapid setting magnesium phosphate (Mg glass) cementitious materials consisting of magnesium phosphate cement paste, polyborax and water-saturated aggregate exhibiting rapid setting and high early strength characteristics. The magnesium glass cement is prepared from a cation-leachable powder and a bivalent metallic ion-accepting liquid such as an aqueous solution of diammonium phosphate and ammonium polyphosphate. The cation-leachable powder includes a mixture of two different magnesium oxide powders processed and sized differently which when mixed with the bivalent metallic ion-accepting liquid provides the magnesium glass cement consisting primarily of magnesium ortho phosphate tetrahydrate, with magnesium hydroxide and magnesium ammonium phosphate hexahydrate also present. The polyborax serves as a set-retarder. The resulting magnesium mono- and polyphosphate cements are particularly suitable for use as a cementing matrix in rapid repair systems for deteriorated concrete structures as well as construction materials and surface coatings for fireproof structures.

Nano-scale hydrogen-bond network improves the durability of greener cements

PubMed Central

Jacobsen, Johan; Rodrigues, Michelle Santos; Telling, Mark T. F.; Beraldo, Antonio Ludovico; Santos, Sérgio Francisco; Aldridge, Laurence P.; Bordallo, Heloisa N.

2013-01-01

More than ever before, the world's increasing need for new infrastructure demands the construction of efficient, sustainable and durable buildings, requiring minimal climate-changing gas-generation in their production. Maintenance-free “greener” building materials made from blended cements have advantages over ordinary Portland cements, as they are cheaper, generate less carbon dioxide and are more durable. The key for the improved performance of blends (which substitute fine amorphous silicates for cement) is related to their resistance to water penetration. The mechanism of this water resistance is of great environmental and economical impact but is not yet understood due to the complexity of the cement's hydration reactions. Using neutron spectroscopy, we studied a blend where cement was replaced by ash from sugar cane residuals originating from agricultural waste. Our findings demonstrate that the development of a distinctive hydrogen bond network at the nano-scale is the key to the performance of these greener materials. PMID:24036676

General scaling relations for locomotion in granular media

NASA Astrophysics Data System (ADS)

Slonaker, James; Motley, D. Carrington; Zhang, Qiong; Townsend, Stephen; Senatore, Carmine; Iagnemma, Karl; Kamrin, Ken

2017-05-01

Inspired by dynamic similarity in fluid systems, we have derived a general dimensionless form for locomotion in granular materials, which is validated in experiments and discrete element method (DEM) simulations. The form instructs how to scale size, mass, and driving parameters in order to relate dynamic behaviors of different locomotors in the same granular media. The scaling can be derived by assuming intrusion forces arise from resistive force theory or equivalently by assuming the granular material behaves as a continuum obeying a frictional yield criterion. The scalings are experimentally confirmed using pairs of wheels of various shapes and sizes under many driving conditions in a common sand bed. We discuss why the two models provide such a robust set of scaling laws even though they neglect a number of the complexities of granular rheology. Motivated by potential extraplanetary applications, the dimensionless form also implies a way to predict wheel performance in one ambient gravity based on tests in a different ambient gravity. We confirm this using DEM simulations, which show that scaling relations are satisfied over an array of driving modes even when gravity differs between scaled tests.

Nonlinear coherent structures in granular crystals

NASA Astrophysics Data System (ADS)

Chong, C.; Porter, Mason A.; Kevrekidis, P. G.; Daraio, C.

2017-10-01

The study of granular crystals, which are nonlinear metamaterials that consist of closely packed arrays of particles that interact elastically, is a vibrant area of research that combines ideas from disciplines such as materials science, nonlinear dynamics, and condensed-matter physics. Granular crystals exploit geometrical nonlinearities in their constitutive microstructure to produce properties (such as tunability and energy localization) that are not conventional to engineering materials and linear devices. In this topical review, we focus on recent experimental, computational, and theoretical results on nonlinear coherent structures in granular crystals. Such structures—which include traveling solitary waves, dispersive shock waves, and discrete breathers—have fascinating dynamics, including a diversity of both transient features and robust, long-lived patterns that emerge from broad classes of initial data. In our review, we primarily discuss phenomena in one-dimensional crystals, as most research to date has focused on such scenarios, but we also present some extensions to two-dimensional settings. Throughout the review, we highlight open problems and discuss a variety of potential engineering applications that arise from the rich dynamic response of granular crystals.

PRODUCTION OF SHEET FROM PARTICULATE MATERIAL

DOEpatents

Blainey, A.

1959-05-12

A process is presented for forming coherent sheet material from particulate material such as granular or powdered metal, granular or powdered oxide, slurries, pastes, and plastic mixes which cohere under pressure. The primary object is to avoid the use of expensive and/ or short lived pressing tools, that is, dies and specially profiled rolls, and so to reduce the cost of the product and to prcvide in a simple manner for the making of the product in a variety of shapes or sizes. The sheet material is formed when the particulate material is laterally confined in a boundary material deformable in all lateral directions under axial pressure and then axially compressing the layer of particulate material together with the boundary material.

A dilation-driven vortex flow in sheared granular materials explains a rheometric anomaly.

PubMed

Krishnaraj, K P; Nott, Prabhu R

2016-02-11

Granular flows occur widely in nature and industry, yet a continuum description that captures their important features is yet not at hand. Recent experiments on granular materials sheared in a cylindrical Couette device revealed a puzzling anomaly, wherein all components of the stress rise nearly exponentially with depth. Here we show, using particle dynamics simulations and imaging experiments, that the stress anomaly arises from a remarkable vortex flow. For the entire range of fill heights explored, we observe a single toroidal vortex that spans the entire Couette cell and whose sense is opposite to the uppermost Taylor vortex in a fluid. We show that the vortex is driven by a combination of shear-induced dilation, a phenomenon that has no analogue in fluids, and gravity flow. Dilatancy is an important feature of granular mechanics, but not adequately incorporated in existing models.

Predictive Mechanical Characterization of Macro-Molecular Material Chemistry Structures of Cement Paste at Nano Scale - Two-phase Macro-Molecular Structures of Calcium Silicate Hydrate, Tri-Calcium Silicate, Di-Calcium Silicate and Calcium Hydroxide

NASA Astrophysics Data System (ADS)

Padilla Espinosa, Ingrid Marcela

Concrete is a hierarchical composite material with a random structure over a wide range of length scales. At submicron length scale the main component of concrete is cement paste, formed by the reaction of Portland cement clinkers and water. Cement paste acts as a binding matrix for the other components and is responsible for the strength of concrete. Cement paste microstructure contains voids, hydrated and unhydrated cement phases. The main crystalline phases of unhydrated cement are tri-calcium silicate (C3S) and di-calcium silicate (C2S), and of hydrated cement are calcium silicate hydrate (CSH) and calcium hydroxide (CH). Although efforts have been made to comprehend the chemical and physical nature of cement paste, studies at molecular level have primarily been focused on individual components. Present research focuses on the development of a method to model, at molecular level, and analysis of the two-phase combination of hydrated and unhydrated phases of cement paste as macromolecular systems. Computational molecular modeling could help in understanding the influence of the phase interactions on the material properties, and mechanical performance of cement paste. Present work also strives to create a framework for molecular level models suitable for potential better comparisons with low length scale experimental methods, in which the sizes of the samples involve the mixture of different hydrated and unhydrated crystalline phases of cement paste. Two approaches based on two-phase cement paste macromolecular structures, one involving admixed molecular phases, and the second involving cluster of two molecular phases are investigated. The mechanical properties of two-phase macromolecular systems of cement paste consisting of key hydrated phase CSH and unhydrated phases C3S or C2S, as well as CSH with the second hydrated phase CH were calculated. It was found that these cement paste two-phase macromolecular systems predicted an isotropic material behavior. Also, these systems exhibited a high bulk modulus, compared to the elastic modulus. These results are an indication and concur with the high compression strength of cement paste seen at engineering length scale. In addition, the bulk modulus of two-phase systems consisting of hydrated CSH and unhydrated C3S or C2S was found to increase with higher levels of unhydrated components. The interaction energies of two-phase cement paste molecular structures studied in the present work were calculated, showing that a higher interaction is attained when the two phases are admixed as small components instead of cluster of phases. Finally, the mechanical behavior under shear deformation was predicted by using a quasi-static deformation method and analyzed for a representative two-phase (CSH and C2S) macromolecular structure of cement paste.

Analog and numerical experiments investigating force chain influences on bed conditions in granular flows

NASA Astrophysics Data System (ADS)

Estep, J.; Dufek, J.

2013-12-01

Granular flows are fundamental processes in several terrestrial and planetary natural events; including surficial flows on volcanic edifices, debris flows, landslides, dune formation, rock falls, sector collapses, and avalanches. Often granular flows can be two-phase, whereby interstitial fluids occupy void space within the particulates. The mobility of granular flows has received significant attention, however the physics that govern their internal behavior remain poorly understood. Here we extend upon previous research showing that force chains can transmit extreme localized forces to the substrates of free surface granular flows, and we combine experimental and computational approaches to further investigate the forces at the bed of simplified granular flows. Analog experiments resolve discrete bed forces via a photoelastic technique, while numerical experiments validate laboratory tests using discrete element model (DEM) simulations. The current work investigates (1) the role of distributed grain sizes on force transmission via force chains, and (2) how the inclusion of interstitial fluids effects force chain development. We also include 3D numerical simulations to apply observed 2D characteristics into real world perspective, and ascertain if the added dimension alters force chain behavior. Previous research showed that bed forces generated by force chain structures can transiently greatly exceed (by several 100%) the bed forces predicted from continuum approaches, and that natural materials are more prone to excessive bed forces than photoelastic materials due to their larger contact stiffnesses. This work suggests that force chain activity may play an important role in the bed physics of dense granular flows by influencing substrate entrainment. Photoelastic experiment image showing force chains in gravity driven granular flow.

Multiscale Phenomena in the Solid-Liquid Transition State of a Granular Material: Analysis, Modeling and Experimentation

DTIC Science & Technology

2010-11-21

The number of undergraduates funded by your agreement who graduated during this period and will receive scholarships or fellowships for further... geology and engineering – to understand and predict the multiscale behaviour of granular materials. Several pioneering achievements have led to...breakage. Purpose of the Research We have recently established, in close collaboration with experimentalists (from geology , physics

Sealing of cracks in cement using microencapsulated sodium silicate

NASA Astrophysics Data System (ADS)

Giannaros, P.; Kanellopoulos, A.; Al-Tabbaa, A.

2016-08-01

Cement-based materials possess an inherent autogenous self-healing capability allowing them to seal, and potentially heal, microcracks. This can be improved through the addition of microencapsulated healing agents for autonomic self-healing. The fundamental principle of this self-healing mechanism is that when cracks propagate in the cementitious matrix, they rupture the dispersed capsules and their content (cargo material) is released into the crack volume. Various healing agents have been explored in the literature for their efficacy to recover mechanical and durability properties in cementitious materials. In these materials, the healing agents are most commonly encapsulated in macrocontainers (e.g. glass tubes or capsules) and placed into the material. In this work, microencapsulated sodium silicate in both liquid and solid form was added to cement specimens. Sodium silicate reacts with the calcium hydroxide in hydrated cement paste to form calcium-silicate-hydrate gel that fills cracks. The effect of microcapsule addition on rheological and mechanical properties of cement is reported. It is observed that the microcapsule addition inhibits compressive strength development in cement and this is observed through a plateau in strength between 28 and 56 days. The improvement in crack-sealing for microcapsule-containing specimens is quantified through sorptivity measurements over a 28 day healing period. After just seven days, the addition of 4% microcapsules resulted in a reduction in sorptivity of up to 45% when compared to specimens without any microcapsule addition. A qualitative description of the reaction between the cargo material and the cementitious matrix is also provided using x-ray diffraction analysis.

Sol-gel methods for synthesis of aluminosilicates for dental applications.

PubMed

Cestari, Alexandre

2016-12-01

Amorphous aluminosilicates glasses containing fluorine, phosphorus and calcium are used as a component of the glass ionomer dental cement. This cement is used as a restorative, basis or filling material, but presents lower mechanical resistance than resin-modified materials. The Sol-Gel method is a possible route for preparation of glasses with lower temperature and energy consumption, with higher homogeneity and with uniform and nanometric particles, compared to the industrial methods Glass ionomer cements with uniform, homogeneous and nanometric particles can present higher mechanical resistance than commercial ionomers. The aim of this work was to adapt the Sol-Gel methods to produce new aluminosilicate glass particles by non-hydrolytic, hydrolytic acid and hydrolytic basic routes, to improve glass ionomer cements characteristics. Three materials were synthesized with the same composition, to evaluate the properties of the glasses produced from the different methods, because multicomponent oxides are difficult to prepare with homogeneity. The objective was to develop a new route to produce new glass particles for ionomer cements with possible higher resistance. The particles were characterized by thermal analysis (TG, DTA, DSC), transmission electron microscopy (TEM), X-ray diffraction (XRD), infrared spectroscopy (FTIR) and scanning electron microscopy coupled with energy dispersive spectroscopy (SEM-EDS). The glasses were tested with polyacrylic acid to form the glass ionomer cement by the setting reaction. It was possible to produce distinct materials for dental applications and a sample presented superior characteristics (homogeneity, nanometric particles, and homogenous elemental distribution) than commercial glasses for ionomer cements. The new route for glass production can possible improve the mechanical resistance of the ionomer cements. Copyright © 2016 Elsevier Ltd. All rights reserved.

Effect of curing mode on the micro-mechanical properties of dual-cured self-adhesive resin cements.

PubMed

Ilie, Nicoleta; Simon, Alexander

2012-04-01

Light supplying to luting resin cements is impeded in several clinical situations, causing us to question whether materials can properly be cured to achieve adequately (or adequate) mechanical properties. The aim of this study was therefore to analyse the effect of light on the micro-mechanical properties of eight popular dual-cured self-adhesive resin cements by comparing them with two conventional, also dual-cured, resin cements. Four different curing procedures were applied: auto-polymerisation (dark curing) and light curing (LED unit, Freelight 2, 20 s) by applying the unit directly on the samples' surface, at a distance of 5 and 10 mm. Twenty minutes after curing, the samples were stored for 1 week at 37°C in a water-saturated atmosphere. The micro-mechanical properties-Vickers hardness, modulus of elasticity, creep and elastic/plastic deformation-were measured. Data were analysed with multivariate ANOVA followed by Tukey's test and partial eta-squared statistics (p < 0.05). A very strong influence of the material as well as filler volume and weight on the micro-mechanical properties was measured, whereas the influence of the curing procedure and type of cement-conventional or self-adhesive-was generally low. The influence of light on the polymerisation process was material dependent, with four different behaviour patterns to be distinguished. As a material category, significantly higher micro-mechanical properties were measured for the conventional compared to the self-adhesive resin cements, although this difference was low. Within the self-adhesive resin cements group, the variation in micro-mechanical properties was high. The selection of suitable resin cements should be done by considering, besides its adhesive properties, its micro-mechanical properties and curing behaviour also.

Ion release, fluoride charge of and adhesion of an orthodontic cement paste containing microcapsules.

PubMed

Burbank, Brant D; Slater, Michael; Kava, Alyssa; Doyle, James; McHale, William A; Latta, Mark A; Gross, Stephen M

2016-02-01

Dental materials capable of releasing calcium, phosphate and fluoride are of great interest for remineralization. Microencapsulated aqueous solutions of these ions in orthodontic cement demonstrate slow, sustained release by passive diffusion through a permeable membrane without the need for dissolution or etching of fillers. The potential to charge a dental material formulated with microencapsulated water with fluoride by toothbrushing with over the counter toothpaste and the effect of microcapsules on cement adhesion to enamel was determined. Orthodontic cements that contained microcapsules with water and controls without microcapsules were brushed with over-the-counter toothpaste and fluoride release was measured. Adhesion measurements were performed loading orthodontic brackets to failure. Cements that contained microencapsulated solutions of 5.0M Ca(NO3)2, 0.8M NaF, 6.0MK2HPO4 or a mixture of all three were prepared. Ion release profiles were measured as a function of time. A greater fluoride charge and re-release from toothbrushing was demonstrated compared to a control with no microcapsules. Adhesion of an orthodontic cement that contained microencapsulated remineralizing agents was 8.5±2.5MPa compared to the control without microcapsules which was of 8.3±1.7MPa. Sustained release of fluoride, calcium and phosphate ions from cement formulated with microencapsulated remineralizing agents was demonstrated. Orthodontic cements with microcapsules show a release of bioavailable fluoride, calcium, and phosphate ions near the tooth surface while having the ability to charge with fluoride and not effect the adhesion of the material to enamel. Incorporation of microcapsules in dental materials is promising for promoting remineralization. Copyright © 2015 Elsevier Ltd. All rights reserved.

CAD-FEA modeling and analysis of different full crown monolithic restorations.

PubMed

Dal Piva, Amanda Maria de Oliveira; Tribst, João Paulo Mendes; Borges, Alexandre Luiz Souto; Souza, Rodrigo Othávio de Assunção E; Bottino, Marco Antonio

2018-06-19

To investigate the influence of different materials for monolithic full posterior crowns using 3D-Finite Element Analysis (FEA). Twelve (12) 3D models of adhesively-restored teeth with different crowns according to the material and its elastic modulus were analysed: Acrylic resin, Polyetheretherketone, Composite resin, Hybrid ceramic, pressable and machinable Zirconia reinforced lithium silicate, Feldspathic, Lithium disilicate, Gold alloy, Cobalt-Chromium alloy (Co-Cr), Zirconia tetragonal partially stabilized with yttria, and Alumina. All materials were assumed to behave elastically throughout the entire deformation. Results in restoration and cementing line were obtained using maximum principal stress. In addition, maximum shear stress criteria was used for the cementing line. Restorative materials with higher elastic modulus present higher stress concentration inside the crown, mainly tensile stress on an intaglio surface. On the other hand, materials with lower elastic modulus allow stress passage for cement, increasing shear stress on this layer. Stiffer materials promote higher stress peak values. Materials with higher elastic modulus such as Co-Cr, zirconia and alumina enable higher tensile stress concentration on the crown intaglio surface and higher shear stress on the cement layer, facilitating crown debonding. Copyright © 2018 The Academy of Dental Materials. Published by Elsevier Inc. All rights reserved.

Effect of Admixtures on the Yield Stresses of Cement Pastes under High Hydrostatic Pressures

PubMed Central

Yim, Hong Jae; Kim, Jae Hong; Kwon, Seung Hee

2016-01-01

When cement-based materials are transported at a construction site, they undergo high pressures during the pumping process. The rheological properties of the materials under such high pressures are unknown, and estimating the workability of the materials after pumping is a complex problem. Among various influential factors on the rheology of concrete, this study investigated the effect of mineral and chemical admixtures on the high-pressure rheology. A rheometer was fabricated that could measure the rheological properties while maintaining a high pressure to simulate the pumping process. The effects of superplasticizer, silica fume, nanoclay, fly ash, or ground granulated blast furnace slag were investigated when mixed with two control cement pastes. The water-to-cement ratios were 0.35 and 0.50. PMID:28773273

Lateral-access Class II restoration using resin-modified glass-ionomer or silver-cermet cement.

PubMed

Croll, T P

1995-02-01

Direct-access preparation of a carious proximal surface is perhaps the most conservative approach to restoration. Physical properties and handling characteristics of silver amalgam and of resin composite and lack of fluoride ion release make these materials unsuitable for direct buccal- or lingual-access proximal restoration. Insufficient strengths and radiolucency of self-hardening glass-ionomer cements preclude their use for Class II restorations. However, glass-ionomer silver-cermet cement and some resin-modified glass-ionomer materials are proving useful for non-stress-bearing Class II restorations and may have applications in preventive dentistry. This article describes lateral-access Class II restoration with modified glass-ionomer cements. Emphasis is placed on careful handling of materials, maintenance of an ideal operative field, and conservation of tooth structure.

Micro-mechanical modeling of the cement-bone interface: the effect of friction, morphology and material properties on the micromechanical response.

PubMed

Janssen, Dennis; Mann, Kenneth A; Verdonschot, Nico

2008-11-14

In order to gain insight into the micro-mechanical behavior of the cement-bone interface, the effect of parametric variations of frictional, morphological and material properties on the mechanical response of the cement-bone interface were analyzed using a finite element approach. Finite element models of a cement-bone interface specimen were created from micro-computed tomography data of a physical specimen that was sectioned from an in vitro cemented total hip arthroplasty. In five models the friction coefficient was varied (mu=0.0; 0.3; 0.7; 1.0 and 3.0), while in one model an ideally bonded interface was assumed. In two models cement interface gaps and an optimal cement penetration were simulated. Finally, the effect of bone cement stiffness variations was simulated (2.0 and 2.5 GPa, relative to the default 3.0 GPa). All models were loaded for a cycle of fully reversible tension-compression. From the simulated stress-displacement curves the interface deformation, stiffness and hysteresis were calculated. The results indicate that in the current model the mechanical properties of the cement-bone interface were caused by frictional phenomena at the shape-closed interlock rather than by adhesive properties of the cement. Our findings furthermore show that in our model maximizing cement penetration improved the micromechanical response of the cement-bone interface stiffness, while interface gaps had a detrimental effect. Relative to the frictional and morphological variations, variations in the cement stiffness had only a modest effect on the micro-mechanical behavior of the cement-bone interface. The current study provides information that may help to better understand the load-transfer mechanisms taking place at the cement-bone interface.

In vitro fatigue resistance of glass ionomer cements used in post-and-core applications.

PubMed

Gateau, P; Sabek, M; Dailey, B

2001-08-01

New glass ionomer cements exhibit better mechanical properties than their older counterparts. However, there is concern about their use as a core material in post-and-core applications. This in vitro study evaluated the fatigue resistance of 2 new glass ionomer cements, Shofu Hi-Dense and Fuji IX GP, and compared their mechanical behavior as a core material under masticatory load with a silver-reinforced glass ionomer (ESPE Ketac-Silver) and a silver amalgam (Cavex Avaloy LC). A total of 100 commercial plastic teeth were divided into 4 groups of 25 specimens each. Titanium posts were placed in the prepared root canals, and cores were built up in amalgam, silver-reinforced glass ionomer cement, and the 2 new glass ionomer cements. The post-and-core specimens were prepared for full cast metal crowns, which were fabricated and cemented with glass ionomer cement. Twenty specimens from each group were placed in a mastication simulator and cyclically loaded with a 400 N force for 1.5 million cycles. The 5 remaining specimens were used as controls. The specimens were sectioned and observed macroscopically and microscopically to determine the number of defects (alterations) in each material. Observed defects were verified with the Kruskal-Wallis test, and the 4 core materials were ranked with the Tukey multiple comparisons test. The mean rank sum values of the defects were as follows: Cavex Avaloy LC Amalgam (16.75), Fuji IX GP (38.50), Shofu Hi-Dense (39.53), and ESPE Ketac-Silver (67.22). The amalgam alloy was significantly different (P< .05) from the others. Under the conditions of this study, the 2 new glass ionomer cements used as core materials showed a higher number of defects than amalgam. These results suggest that their fatigue resistance may be inadequate for post-and-core applications.

Performance study of cementitious systems containing zeolite and silica fume: effects of four metal nitrates on the setting time, strength and leaching characteristics.

PubMed

Gervais, C; Ouki, S K

2002-07-22

The aim of this study is to investigate the effect of four metal nitrate contaminants, namely chromium, manganese, lead and zinc on the mechanical and leaching characteristics of cement-based materials. For this purpose, three different matrices made of: (i) Portland cement, (ii) Portland cement and silica fume, and (iii) Portland cement and natural zeolite were studied. The effects of metals on the stabilised/solidified (S/S) product characteristics were monitored by measuring: (i) setting time, (ii) compressive strength, (iii) acid neutralisation capacity (ANC), and (iv) solubility of the metal contaminants as a function of pH. The results of both mechanical and leaching tests showed the importance of the contaminant/matrix couple considered. Setting time was accelerated in presence of chromium, while in presence of manganese, lead and zinc it was delayed. However, for the last two contaminants, a 10% replacement of cement by silica fume and zeolite, markedly accelerated the setting time compared to the cement-only matrix. Although the early strength development was adversely affected in presence of all four contaminants, the long-term strength was less affected compared to the control materials. Although the ANC of the materials was not markedly affected by the presence of contaminants, the nature of the matrix did modify the ANC behaviour of the solidified materials. The increased strength and reduced ANC observed in the presence of silica fume are both due to pozzolanic reaction. The type of matrix used for solidification did not affect the solubility of the four metal contaminants. Overall, the results showed that the use of blended cements must be carried out with care and the performance assessment of waste-containing cement-based materials must take into consideration both the mechanical and leaching characteristics of the systems.

Effect of Nano-SiO₂ on the Hydration and Microstructure of Portland Cement.

PubMed

Wang, Liguo; Zheng, Dapeng; Zhang, Shupeng; Cui, Hongzhi; Li, Dongxu

2016-12-15

This paper systematically studied the modification of cement-based materials by nano-SiO₂ particles with an average diameter of about 20 nm. In order to obtain the effect of nano-SiO₂ particles on the mechanical properties, hydration, and pore structure of cement-based materials, adding 1%, 3%, and 5% content of nano-SiO₂ in cement paste, respectively. The results showed that the reaction of nano-SiO₂ particles with Ca(OH)₂ (crystal powder) started within 1 h, and formed C-S-H gel. The reaction speed was faster after aging for three days. The mechanical properties of cement-based materials were improved with the addition of 3% nano-SiO₂, and the early strength enhancement of test pieces was obvious. Three-day compressive strength increased 33.2%, and 28-day compressive strength increased 18.5%. The exothermic peak of hydration heat of cement increased significantly after the addition of nano-SiO₂. Appearance time of the exothermic peak was advanced and the total heat release increased. Thermogravimetric-differential scanning calorimetry (TG-DSC) analysis showed that nano-SiO₂ promoted the formation of C-S-H gel. The results of mercury intrusion porosimetry (MIP) showed that the total porosity of cement paste with 3% nano-SiO₂ was reduced by 5.51% and 5.4% at three days and 28 days, respectively, compared with the pure cement paste. At the same time, the pore structure of cement paste was optimized, and much-detrimental pores and detrimental pores decreased, while less harmful pores and innocuous pores increased.

An in vitro radiographic analysis of the density of dental luting cements as measured by CCD-based digital radiography.

PubMed

Antonijevic, Djordje; Jevremovic, Danimir; Jovanovic, Svetlana; Obradovic-Djuricic, Kosovka

2012-05-01

According to the ISO, the radiopacity of luting cements should be equal to or greater than that of aluminum. The aim of this in vitro study was to determine the radiopacity of 13 commercially available dental luting cements and compare them with human enamel and dentin. Five classes of luting cements were evaluated: zinc phosphate (Cegal N and Harvard Zinc Phosphate), zinc polycarboxylate (Harvard Polycarboxylate and Hoffmann's Carboxylate), glass ionomers (Ketac Cem Easymix, Ketac Cem Radiopaque, and Fuji I), resin-modified glass ionomer (Rely X Luting), and resin cements (Multilink Automix, Variolink II, Speed CEM, Rely X Unicem Automix, and three shades of Variolink Veneer). Tooth slices served as controls. Five specimens of each material measuring 8 mm in diameter and 1 mm thick were prepared and radiographed alongside tooth slices and an aluminum stepwedge using a Trophy RVG sensor. The radiopacity values were expressed in mm Al and analyzed by the ANOVA and Tukey tests (P < .05). All the cements examined except Variolink Veneer had significantly higher radiopacities than that of dentin. Rely X Unicem Automix, glass ionomer, and resin-modified glass-ionomer cements demonstrated radiopacities that were not significantly different with respect to enamel. Zinc phosphate, zinc polycarboxylate, and three of the resin cements presented radiopacity values that were significantly greater than that of enamel. Almost all the investigated materials presented an acceptable radiopacity. Radiopacity of dental cements seems to depend more on the presence of elements with high atomic numbers than on the type of the material.

The chemical constitution and biocompatibility of accelerated Portland cement for endodontic use.

PubMed

Camilleri, J; Montesin, F E; Di Silvio, L; Pitt Ford, T R

2005-11-01

To evaluate the biocompatibility of mineral trioxide aggregate and accelerated Portland cement and their eluants by assessing cell metabolic function and proliferation. The chemical constitution of grey and white Portland cement, grey and white mineral trioxide aggregate (MTA) and accelerated Portland cement produced by excluding gypsum from the manufacturing process (Aalborg White) was determined using both energy dispersive analysis with X-ray and X-ray diffraction analysis. Biocompatibility of the materials was assessed using a direct test method where cell proliferation was measured quantitatively using Alamar Blue dye and an indirect test method where cells were grown on material elutions and cell proliferation was assessed using methyltetrazolium assay as recommended by the International standard guidelines, ISO 10993-Part 5 for in vitro testing. The chemical constitution of all the materials tested was similar. Indirect studies of the eluants showed an increase in cell activity after 24 h compared with the control in culture medium (P<0.05). Direct cell contact with the cements resulted in a fall in cell viability for all time points studied (P<0.001). Biocompatibility testing of the cement eluants showed the presence of no toxic leachables from the grey or white MTA, and that the addition of bismuth oxide to the accelerated Portland cement did not interfere with biocompatibility. The new accelerated Portland cement showed similar results. Cell growth was poor when seeded in direct contact with the test cements. However, the elution made up of calcium hydroxide produced during the hydration reaction was shown to induce cell proliferation.

Microleakage along Glassix glass fibre posts cemented with three different materials assessed using a fluid transport system.

PubMed

Rogić-Barbić, M; Segović, S; Pezelj-Ribarić, S; Borcić, J; Jukić, S; Anić, I

2006-05-01

To evaluate the microleakage along Glassix fibre posts cemented with three different materials. The root canals of maxillary central incisor teeth were filled and restored with Glassix posts (Harald Nordin sa, Chailly/Montreux, Switzerland) cemented with either a zinc-phosphate Harvard cement (Richter & Hoffmann, Harvard Dental GmbH, Berlin, Germany), Fuji PLUS cement (GC Corporation, Tokyo, Japan) or Variolink II cement (Vivadent, Schaan, Lichtenstein) in three groups of 15 canals each. Twenty unrestored canals served as a control group, 10 filled with gutta-percha and sealer (negative control group), the remaining 10 with gutta-percha only (positive control group). Coronal microleakage was evaluated using a fluid transport system. The movement of an air bubble in a capillary glass tube connected to the apex of the experimental root section was measured over 5-min periods. Measurements were performed four times for each specimen and the mean values recorded. ANOVA and Duncan's test were performed. The positive control group had the highest values of microleakage. Amongst experimental groups, the highest values of microleakage occurred in the group with the posts cemented with Harvard cement, followed by Fuji PLUS and Variolink II cements. Groups with Fuji PLUS, Variolink II and the negative control group had significantly (P < 0.00001) less microleakage compared with the Harvard cement group and the positive control group. Canals with Glassix posts cemented with Variolink II and Fuji PLUS cement had the least leakage when assessed using a fluid transport system.

Shear dispersion in dense granular flows

DOE PAGES

Christov, Ivan C.; Stone, Howard A.

2014-04-18

We formulate and solve a model problem of dispersion of dense granular materials in rapid shear flow down an incline. The effective dispersivity of the depth-averaged concentration of the dispersing powder is shown to vary as the Péclet number squared, as in classical Taylor–Aris dispersion of molecular solutes. An extension to generic shear profiles is presented, and possible applications to industrial and geological granular flows are noted.

Influence of glass-ionomer cement on the interface and setting reaction of mineral trioxide aggregate when used as a furcal repair material using laser Raman spectroscopic analysis.

PubMed

Nandini, Suresh; Ballal, Suma; Kandaswamy, Deivanayagam

2007-02-01

The prolonged setting time of mineral trioxide aggregate (MTA) is the main disadvantage of this material. This study analyzes the influence of glass-ionomer cement on the setting of MTA using laser Raman spectroscopy (LRS). Forty hollow glass molds were taken in which MTA was placed. In Group I specimens, MTA was layered with glass-ionomer cement after 45 minutes. Similar procedures were done for Groups II and III at 4 hours and 3 days, respectively. No glass ionomer was added in Group IV, which were then considered as control samples. Each sample was scanned at various time intervals. At each time interval, the interface between MTA and glass-ionomer cement was also scanned (excluding Group IV). The spectral analysis proved that placement of glass-ionomer cement over MTA after 45 minutes did not affect its setting reaction and calcium salts may be formed in the interface of these two materials.

From Rocks to Cement. What We Make. Science and Technology Education in Philippine Society.

ERIC Educational Resources Information Center

Philippines Univ., Quezon City. Science Education Center.

This module deals with the materials used in making concrete hollow blocks. Topics discussed include: (1) igneous, metamorphic, and sedimentary rocks; (2) weathering (the process of breaking down rocks) and its effects on rocks; (3) cement; (4) stages in the manufacturing of Portland cement; and (5) the transformation of cement into concrete…

Note: "Lock-in accelerometry" to follow sink dynamics in shaken granular matter.

PubMed

Sánchez-Colina, G; Alonso-Llanes, L; Martínez, E; Batista-Leyva, A J; Clement, C; Fliedner, C; Toussaint, R; Altshuler, E

2014-12-01

Understanding the penetration dynamics of intruders in granular beds is relevant not only for fundamental physics, but also for geophysical processes and construction on sediments or granular soils in areas potentially affected by earthquakes. While the penetration of intruders in two dimensional (2D) laboratory granular beds can be followed using video recording, this is useless in three dimensional (3D) beds of non-transparent materials such as common sand. Here, we propose a method to quantify the sink dynamics of an intruder into laterally shaken granular beds based on the temporal correlations between the signals from a reference accelerometer fixed to the shaken granular bed, and a probe accelerometer deployed inside the intruder. Due to its analogy with the working principle of a lock-in amplifier, we call this technique lock-in accelerometry.

Challenges in Predicting Planetary Granular Mechanics

NASA Technical Reports Server (NTRS)

Metzger, Philip T.

2005-01-01

Through the course of human history, our needs in agriculture, habitat construction, and resource extraction have driven us to gain more experience working with the granular materials of planet Earth than with any other type of substance in nature, with the possible exception being water. Furthermore, throughout the past two centuries we have seen a dramatic and ever growing interest among scientists and engineers to understand and predict both its static and rheological properties. Ironically, however, despite this wealth of experience we still do not have a fundamental understanding of the complex physical phenomena that emerge even as just ordinary sand is shaken, squeezed or poured. As humanity is now reaching outward through the solar system, not only robotic ally but also with our immediate human presence, the need to understand and predict granular mechanics has taken on a new dimension. We must learn to farm, build and mine the regoliths of other planets where the environmental conditions are different than on Earth, and we are rapidly discovering that the effects of these environmental conditions are not trivial. Some of the relevant environmental features include the regolith formation processes throughout a planet's geologic and hydrologic history, the unknown mixtures of volatiles residing within the soil, the relative strength of gravitation, d the atm9spheric pressure and its seasonal variations. The need to work with soils outside our terrestrial experience base provides us with both a challenge and an opportunity. The challenge is to learn how to extrapolate our experience into these new planetary conditions, enabling the engineering decisions that are needed right now as we take the next few steps in solar system exploration. The opportunity is to use these new planetary environments as laboratories that will help us to see granular mechanics in new ways, to challenge our assumptions, and to help us finally unravel the elusive physics that lie behind complex granular phenomena. Toward these goals, a workshop was held recently at NASA's John F. Kennedy Space Center, attracting over a hundred scientists and engineers from around the world and from a broad crosssection of scientific and engineering disciplines. This talk will provide an out-briefing from that workshop, communicating some of its early findings in regard to lunar and Martian exploration: (1) the requirements for working with granular materials, (2) the challenges that granular materials will pose, (3) the environmental conditions that affect granular mechanics, (4) instruments and measurements that are needed on the Moon and Mars to support granular material research, and (5) some of the possible research avenues that should be pursued.

Radiological risk of building materials using homemade airtight radon chamber

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khalid, Norafatin; Majid, Amran Ab.; Yahaya, Redzuwan

Soil based building materials known to contain various amounts of natural radionuclide mainly {sup 238}U and {sup 232}Th series and {sup 40}K. In general most individuals spend 80% of their time indoors and the natural radioactivity in building materials is a main source of indoor radiation exposure. The internal exposure due to building materials in dwellings and workplaces is mainly caused by the activity concentrations of short lived {sup 222}Radon and its progenies which arise from the decay of {sup 226}Ra. In this study, the indoor radon concentration emanating from cement brick, red-clay brick, gravel aggregate and Portland cement samplesmore » were measured in a homemade airtight radon chamber using continuous radon monitor 1029 model of Sun Nuclear. Radon monitor were left in the chamber for 96 hours with an hour counting time interval. From the result, the indoor radon concentrations for cement brick, red-clay brick, gravel aggregate and Portland cement samples determined were 396 Bq m{sup −3}, 192 Bq m{sup −3}, 176 Bq m{sup −3} and 28 Bq m{sup −3}, respectively. The result indicates that the radon concentration in the studied building materials have more than 100 Bq m{sup −3} i.e. higher than the WHO action level except for Portland cement sample. The calculated annual effective dose for cement brick, red-clay brick, gravel aggregate and Portland cement samples were determined to be 10 mSv y{sup −1}, 4.85 mSv y{sup −1}, 4.44 mSv y{sup −1} and 0.72 mSv y{sup −1}, respectively. This study showed that all the calculated effective doses generated from indoor radon to dwellers or workers were in the range of limit recommended ICRP action levels i.e. 3 - 10 mSv y{sup −1}. As consequences, the radiological risk for the dwellers in terms of fatal lifetime cancer risk per million for cement brick, red-clay brick, gravel aggregate and Portland cement were calculated to be 550, 267, 244 and 40 persons respectively.« less

Influences of Shear History and Infilling on the Mechanical Characteristics and Acoustic Emissions of Joints

NASA Astrophysics Data System (ADS)

Meng, Fanzhen; Zhou, Hui; Wang, Zaiquan; Zhang, Liming; Kong, Liang; Li, Shaojun; Zhang, Chuanqing

2017-08-01

Filled joints, which are characterized by high deformability and low shear strength, are among the most critical discontinuities in rock mass and may be sheared repeatedly when subject to cyclic loading. Shear tests were carried out on tension splitting joints, with soil and granular cement mortar particles used as infillings, and the effects of the shear history on the mechanical behavior and acoustic emission (AE) of clean and filled joints were studied. The maximum strength in the subsequent shears was approximately 60% of the peak strength of the first shear for a clean joint, and the friction angle degraded from 63° to 45° after the first shear. The maximum shear strength of the filled joints was lower than 35% of the peak strength of the clean joint under the same normal stress. The change in the shear strength of filled joints with the number of shearing cycles was closely related to the transformation of the shear medium. Rolling friction occurred and the shear strength was low for the granular particle-filled joint, but the strength was elevated when the particles were crushed and sliding friction occurred. The AEs were significantly reduced during the second shear for the clean joint, and the peak AEs were mainly obtained at or near the turning point of the shear stress curve for the filled joint. The AEs were the highest for the cement particle-filled joint and lowest for the dry soil-filled joint; when subjected to repeated shears, the AEs were more complex because of the continuous changes to the shear medium. The evolution of the AEs with the shear displacement can accurately reflect the shear failure mechanism during a single shear process.

Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brent Constantz; Randy Seeker; Martin Devenney

2010-06-30

Calera's innovative Mineralization via Aqueous Precipitation (MAP) technology for the capture and conversion of CO{sub 2} to useful materials for use in the built environment was further developed and proven in the Phase 1 Department of Energy Grant. The process was scaled to 300 gallon batch reactors and subsequently to Pilot Plant scale for the continuous production of product with the production of reactive calcium carbonate material that was evaluated as a supplementary cementitious material (SCM). The Calera SCM{trademark} was evaluated as a 20% replacement for ordinary portland cement and demonstrated to meet the industry specification ASTM 1157 which ismore » a standard performance specification for hydraulic cement. The performance of the 20% replacement material was comparable to the 100% ordinary portland cement control in terms of compressive strength and workability as measured by a variety of ASTM standard tests. In addition to the performance metrics, detailed characterization of the Calera SCM was performed using advanced analytical techniques to better understand the material interaction with the phases of ordinary portland cement. X-ray synchrotron diffraction studies at the Advanced Photon Source in Argonne National Lab confirmed the presence of an amorphous phase(s) in addition to the crystalline calcium carbonate phases in the reactive carbonate material. The presence of carboaluminate phases as a result of the interaction of the reactive carbonate materials with ordinary portland cement was also confirmed. A Life Cycle Assessment was completed for several cases based on different Calera process configurations and compared against the life cycle of ordinary portland cement. In addition to the materials development efforts, the Calera technology for the production of product using an innovative building materials demonstration plant was developed beyond conceptual engineering to a detailed design with a construction schedule and cost estimate.« less

0-6717 : investigation of alternative supplementary cementing materials (SCMs) : [project summary].

DOT National Transportation Integrated Search

2014-08-01

In Texas, Class F fly ash is extensively used as a : supplementary cementing material (SCM) : because of its ability to control thermal cracking : in mass concrete and to mitigate deleterious : expansions in concrete from alkali-silica reaction : (AS...

Microgravity Investigation of Cement Solidification

NASA Technical Reports Server (NTRS)

Neves, Juliana; Radlinska, Aleksandra; Scheetz, Barry

2017-01-01

Concrete is the most widely used man-made material in the world, second only to water. The large-scale production of cements contributes to approximately 5% anthropogenic CO2 emission. Microgravity research can lead to more durable and hence more cost-effective material.

Grout formulation for disposal of low-level and hazardous waste streams containing fluoride

DOEpatents

McDaniel, E.W.; Sams, T.L.; Tallent, O.K.

1987-06-02

A composition and related process for disposal of hazardous waste streams containing fluoride in cement-based materials is disclosed. the presence of fluoride in cement-based materials is disclosed. The presence of fluoride in waste materials acts as a set retarder and as a result, prevents cement-based grouts from setting. This problem is overcome by the present invention wherein calcium hydroxide is incorporated into the dry-solid portion of the grout mix. The calcium hydroxide renders the fluoride insoluble, allowing the grout to set up and immobilize all hazardous constituents of concern. 4 tabs.

Comparison of an experimental bone cement with surgical Simplex P, Spineplex and Cortoss.

PubMed

Boyd, D; Towler, M R; Wren, A; Clarkin, O M

2008-04-01

Conventional polymethylmethacrylate (PMMA) cements and more recently Bisphenol-a-glycidyl dimethacrylate (BIS-GMA) composite cements are employed in procedures such as vertebroplasty. Unfortunately, such materials have inherent drawbacks including, a high curing exotherm, the incorporation of toxic components in their formulations, and critically, exhibit a modulus mismatch between cement and bone. The literature suggests that aluminium free, zinc based glass polyalkenoate cements (Zn-GPC) may be suitable alternative materials for consideration in such applications as vertebroplasty. This paper, examines one formulation of Zn-GPC and compares its strengths, modulus, and biocompatibility with three commercially available bone cements, Spineplex, Simplex P and Cortoss. The setting times indicate that the current formulation of Zn-GPC sets in a time unsuitable for clinical deployment. However during setting, the peak exotherm was recorded to be 33 degrees C, the lowest of all cements examined, and well below the threshold level for tissue necrosis to occur. The data obtained from mechanical testing shows the Zn-GPC has strengths of 63 MPa in compression and 30 MPa in biaxial flexure. Importantly these strengths remain stable with maturation; similar long term stability was exhibited by both Spineplex and Simplex P. Conversely, the strengths of Cortoss were observed to rapidly diminish with time, a cause for clinical concern. In addition to strengths, the modulus of each material was determined. Only the Zn-GPC exhibited a modulus similar to vertebral trabecular bone, with all commercial materials exhibiting excessively high moduli. Such data indicates that the use of Zn-GPC may reduce adjacent fractures. The final investigation used the well established simulated body fluid (SBF) method to examine the ability of each material to bond with bone. The results indicate that the Zn-GPC is capable of producing a bone like apatite layer at its surface within 24 h which increased in coverage and density up to 7 days. Conversely, Spineplex, and Simplex P exhibit no apatite layer formation, while Cortoss exhibits only minimal formation of an apatite layer after 7 days incubation in SBF. This paper shows that Zn-GPC, with optimised setting times, are suitable candidate materials for further development as bone cements.

A comparative evaluation of dental luting cements by fracture toughness tests and fractography.

PubMed

Ryan, A K; Orr, J F; Mitchell, C A

2001-01-01

In recent years there has been a shift from traditional methods of investigating dental materials to a fracture mechanics approach. Fracture toughness (KIC) is an intrinsic material property which can be considered to be a measure of a material's resistance to crack propagation. Glass-ionomer cements are biocompatible and bioactive dental restorative materials, but they suffer from poor fracture toughness and are extremely susceptible to dehydration. The main objective of this study was to evaluate the fracture toughness of three types of commercially available dental cements (polyacid-modified composite resin, resin-modified and conventional glass ionomer) using a short-rod chevron-notch test and to investigate and interpret the results by means of fractography using scanning electron microscopy. Ten specimens of each cement were fabricated according to manufacturers' instructions, coated in varnish, and stored at ambient laboratory humidity, 100 per cent relative humidity, or in water at 37 degrees C for 7 days prior to preparation for testing. Results indicated that significant differences existed between each group of materials and that the fracture toughness ranged from 0.27 to 0.72 MN/m3/2. It was concluded that the resin-modified glass-ionomer cement demonstrated the highest resistance to crack propagation. Fractographs clearly showed areas of stable and unstable crack growth along the fractured surfaces for the three materials examined.

Effect of mechanical cleaning with granular material on the permeability of submerged membranes in the MBR process.

PubMed

Siembida, B; Cornel, P; Krause, S; Zimmermann, B

2010-07-01

The research on fouling reduction and permeability loss in membrane bioreactors (MBRs) was carried out at two MBR pilot plants with synthetic and real wastewater. On the one hand, the effect of mechanical cleaning with an abrasive granular material on the performance of a submerged MBR process was tested. Additionally, scanning electron microscopy (SEM) measurements and integrity tests were conducted to check whether the membrane material was damaged by the granulate.The results indicate that the fouling layer formation was significantly reduced by abrasion using the granular material. This technique allowed a long-term operation of more than 600 days at a flux up to 40 L/(m2 h) without chemical cleaning of the membranes. Moreover, it was demonstrated that the membrane bioreactor (MBR) with granulate could be operated with more than 20% higher flux compared to a conventional MBR operation. SEM images and integrity tests showed that in consequence of abrasive cleaning, the granular material left brush marks on the membrane surface, however, the membrane function was not affected.In a parallel experimental set up, the impact of the operationally defined "truly soluble fraction" <0.04 microm from wastewater and activated sludge on the ultrafiltration membrane fouling characteristics was investigated. It was shown that the permeability loss was caused predominantly by the colloidal fraction >0.04 microm rather than by the dissolved fraction of wastewater and activated sludge.

Low Carbon Footprint mortar from Pozzolanic Waste Material

NASA Astrophysics Data System (ADS)

Mehmannavaz, Taha; Mehman navaz, Hossein Ali; Moayed Zefreh, Fereshteh; Aboata, Zahra

2017-04-01

Nowadays, Portland cement clinker leads to emission of CO2 into the atmosphere and therefore causes greenhouse effect. Incorporating of Palm Oil Fuel Ash (POFA) and Pulverized Fuel Ash (PFA) as partial cement replacement materials into mix of low carbon mortar decreases the amount of cement use and reduces high dependence on cements compared to ordinary mortar. The result of this research supported use of the new concept in preparing low carbon mortar for industrial constructions. Strength of low carbon mortar with POFA and PFA replacement in cement was affected and changed by replacing percent finesse, physical and chemical properties and pozzolanic activity of these wastes. Waste material replacement instead of Ordinary Portland Cement (OPC) was used in this study. This in turn was useful for promoting better quality of construction and innovative systems in construction industry, especially in Malaysia. This study was surely a step forward to achieving quality products which were affordable, durable and environmentally friendly. Disposing ash contributes to shortage of landfill space in Malaysia. Besides, hazard of ash might be another serious issue for human health. The ash disposal area also might create a new problem, which is the area's sedimentation and erosion.

Influence of viscosity modifying admixtures on the rheological behavior of cement and mortar pastes

NASA Astrophysics Data System (ADS)

Bouras, R.; Kaci, A.; Chaouche, M.

2012-03-01

The influence of Viscosity-modifying admixtures (VMA) dosage rate on the steady state rheological properties, including the yield stress, fluid consistency index and flow behaviour index, of cementitious materials is considered experimentally. The investigation is undertaken both at cement paste and mortar scales. It is found that the rheological behaviour of the material is in general dependent upon shear-rate interval considered. At sufficiently low shear-rates the materials exhibit shear-thinning. This behaviour is attributed to flow-induced defloculation of the solid particles and VMA polymer disentanglement and alignment. At relatively high shear-rates the pastes becomes shear-thickening, due to repulsive interactions among the solid particles. There is a qualitative difference between the influence of VMA dosage at cement and mortar scales: at cement scale we obtain a monotonic increase of the yield stress, while at mortar scale there exists an optimum VMA dosage for which the yield stress is a minimum. The flow behaviour index exhibit a maximum in the case of cement pastes and monotonically decreases in the case of mortars. On the other hand, the fluid consistency index presents a minimum for both cement pastes and mortars.

Application of alkaliphilic biofilm-forming bacteria to improve compressive strength of cement-sand mortar.

PubMed

Park, Sung-Jin; Chun, Woo-Young; Kim, Wha-Jung; Ghim, Sa-Youl

2012-03-01

The application of microorganisms in the field of construction material is rapidly increasing worldwide; however, almost all studies that were investigated were bacterial sources with mineral-producing activity and not with organic substances. The difference in the efficiency of using bacteria as an organic agent is that it could improve the durability of cement material. This study aimed to assess the use of biofilm-forming microorganisms as binding agents to increase the compressive strength of cement-sand material. We isolated 13 alkaliphilic biofilmforming bacteria (ABB) from a cement tetrapod block in the West Sea, Korea. Using 16S RNA sequence analysis, the ABB were partially identified as Bacillus algicola KNUC501 and Exiguobacterium marinum KNUC513. KNUC513 was selected for further study following analysis of pH and biofilm formation. Cement-sand mortar cubes containing KNUC513 exhibited greater compressive strength than mineral-forming bacteria (Sporosarcina pasteurii and Arthrobacter crystallopoietes KNUC403). To determine the biofilm effect, Dnase I was used to suppress the biofilm formation of KNUC513. Field emission scanning electron microscopy image revealed the direct involvement of organic-inorganic substance in cement-sand mortar.

Fabric and connectivity as field descriptors for deformations in granular media

NASA Astrophysics Data System (ADS)

Wan, Richard; Pouragha, Mehdi

2015-01-01

Granular materials involve microphysics across the various scales giving rise to distinct behaviours of geomaterials, such as steady states, plastic limit states, non-associativity of plastic and yield flow, as well as instability of homogeneous deformations through strain localization. Incorporating such micro-scale characteristics is one of the biggest challenges in the constitutive modelling of granular materials, especially when micro-variables may be interdependent. With this motivation, we use two micro-variables such as coordination number and fabric anisotropy computed from tessellation of the granular material to describe its state at the macroscopic level. In order to capture functional dependencies between micro-variables, the correlation between coordination number and fabric anisotropy limits is herein formulated at the particle level rather than on an average sense. This is the essence of the proposed work which investigates the evolutions of coordination number distribution (connectivity) and anisotropy (contact normal) distribution curves with deformation history and their inter-dependencies through discrete element modelling in two dimensions. These results enter as probability distribution functions into homogenization expressions during upscaling to a continuum constitutive model using tessellation as an abstract representation of the granular system. The end product is a micro-mechanically inspired continuum model with both coordination number and fabric anisotropy as underlying micro-variables incorporated into a plasticity flow rule. The derived plastic potential bears striking resemblance to cam-clay or stress-dilatancy-type yield surfaces used in soil mechanics.

A Novel Injectable Borate Bioactive Glass Cement as an Antibiotic Delivery Vehicle for Treating Osteomyelitis

PubMed Central

Cui, Xu; Gu, Yi-Fei; Jia, Wei-Tao; Rahaman, Mohamed N.; Wang, Yang; Huang, Wen-Hai; Zhang, Chang-Qing

2014-01-01

Background A novel injectable cement composed of chitosan-bonded borate bioactive glass (BG) particles was evaluated as a carrier for local delivery of vancomycin in the treatment of osteomyelitis in a rabbit tibial model. Materials and Methods The setting time, injectability, and compressive strength of the borate BG cement, and the release profile of vancomycin from the cement were measured in vitro. The capacity of the vancomycin-loaded BG cement to eradicate methicillin-resistant Staphylococcus aureus (MRSA)-induced osteomyelitis in rabbit tibiae in vivo was evaluated and compared with that for a vancomycin-loaded calcium sulfate (CS) cement and for intravenous injection of vancomycin. Results The BG cement had an injectability of >90% during the first 3 minutes after mixing, hardened within 30 minutes and, after hardening, had a compressive strength of 18±2 MPa. Vancomycin was released from the BG cement into phosphate-buffered saline for up to 36 days, and the cumulative amount of vancomycin released was 86% of the amount initially loaded into the cement. In comparison, vancomycin was released from the CS cement for up 28 days and the cumulative amount released was 89%. Two months post-surgery, radiography and microbiological tests showed that the BG and CS cements had a better ability to eradicate osteomyelitis when compared to intravenous injection of vancomycin, but there was no significant difference between the BG and CS cements in eradicating the infection. Histological examination showed that the BG cement was biocompatible and had a good capacity for regenerating bone in the tibial defects. Conclusions These results indicate that borate BG cement is a promising material both as an injectable carrier for vancomycin in the eradication of osteomyelitis and as an osteoconductive matrix to regenerate bone after the infection is cured. PMID:24427311

Preliminary Results of a Microgravity Investigation to Measure Net Charge on Granular Materials

NASA Technical Reports Server (NTRS)

Green, Robert D.; Myers, Jerry G.; Hansen, Bonnie L.

2003-01-01

Accurate characterization of the electrostatic charge on granular materials has typically been limited to materials with diameters on the order of 10 microns and below due to high settling velocities of larger particles. High settling velocities limit both the time and the acceptable uncertainty with which a measurement can be made. A prototype device has been developed at NASA Glenn Research Center (GRC) to measure coulombic charge on individual particles of granular materials that are 50 to 500 microns in diameter. This device, a novel extension of Millikan's classic oil drop experiment, utilizes the NASA GRC 2.2 second drop tower to extend the range of electrostatic charge measurements to accommodate moderate size granular materials. A dielectric material with a nominal grain diameter between 1.06 and 250 microns was tribocharged using a dry gas jet, suspended in a 5x10x10 cm enclosure during a 2.2 second period of microgravity and exposed to a known electric field. The response was recorded on video and post processed to allow tracking of individual particles. By determining the particle trajectory and velocity, estimates of the coulombic charge were made. Over 30 drops were performed using this technique and the analysis showed that first order approximations of coulombic charge could successfully be obtained, with the mean charge of 3.4E-14 coulombs measured for F-75 Ottawa quartz sand. Additionally, the measured charge showed a near-Gaussian distribution, with a standard deviation of 2.14E -14 coulombs.

In vitro effects of dental cements on hard and soft tissues associated with dental implants.

PubMed

Rodriguez, Lucas C; Saba, Juliana N; Chung, Kwok-Hung; Wadhwani, Chandur; Rodrigues, Danieli C

2017-07-01

Dental cements for cement-retained restorations are often chosen based on clinician preference for the product's material properties, mixing process, delivery mechanism, or viscosity. The composition of dental cement may play a significant role in the proliferation or inhibition of different bacterial strains associated with peri-implant disease, and the effect of dental cements on host cellular proliferation may provide further insight into appropriate cement material selection. The purpose of this in vitro study was to investigate the cellular host response of bone cells (osteoblasts) and soft tissue cells (gingival fibroblasts) to dental cements. Zinc oxide (eugenol and noneugenol), zinc phosphate, and acrylic resin cements were molded into pellets and directly applied to confluent preosteoblast (cell line MC3T3 E1) or gingival fibroblast cell cultures (cell line HGF) to determine cellular viability after exposure. Controls were defined as confluent cell cultures with no cement exposure. Direct contact cell culture testing was conducted following International Organization for Standardization 10993 methods, and all experiments were performed in triplicate. To compare either the MC3T3 E1 cell line, or the HGF cell line alone, a 1-way ANOVA test with multiple comparisons was used (α=.05). To compare the MC3T3 E1 cell line results and the HGF cell line results, a 2-way ANOVA test with multiple comparisons was used (α=.05). The results of this study illustrated that while both bone and soft tissue cell lines were vulnerable to the dental cement test materials, the soft tissue cell line (human gingival fibroblasts) was more susceptible to reduced cellular viability after exposure. The HGF cell line was much more sensitive to cement exposure. Here, the acrylic resin, zinc oxide (eugenol), and zinc phosphate cements significantly reduced cellular viability after exposure with respect to HGF cells only. Within the limitation of this in vitro cellular study, the results indicated that cell response to various implant cements varied significantly, with osteoblast proliferation much less affected than gingival fibroblast cells. Furthermore, the zinc oxide noneugenol dental cement appeared to affect the cell lines significantly less than the other test cements. Copyright © 2016 Editorial Council for the Journal of Prosthetic Dentistry. Published by Elsevier Inc. All rights reserved.

Research on the Application of GRC Material in Exhibition Decoration Engineering

NASA Astrophysics Data System (ADS)

Cai, Yan

2018-03-01

Glass fiber reinforced cement (GRC) is a kind of new building material which is based on cement and take the alkali resistant glass fiber as reinforcing material. It is mainly used in building decoration project and it has many advantages like environmental protection, economical, practical modeling and others. This paper mainly studies the concrete application of GRC material in exhibition building decoration project.

Computer-aided analysis for the Mechanics of Granular Materials (MGM) experiment

NASA Technical Reports Server (NTRS)

Parker, Joey K.

1986-01-01

The Mechanics of Granular Materials (MGM) program is planned to provide experimental determinations of the mechanics of granular materials under very low gravity conditions. The initial experiments will use small glass beads as the granular material, and a precise tracking of individual beads during the test is desired. Real-time video images of the experimental specimen were taken with a television camera, and subsequently digitized by a frame grabber installed in a microcomputer. Easily identified red tracer beads were randomly scattered throughout the test specimen. A set of Pascal programs was written for processing and analyzing the digitized images. Filtering the image with Laplacian, dilation, and blurring filters when using a threshold function produced a binary (black on white) image which clearly identified the red beads. The centroids and areas for each bead were then determined. Analyzing a series of the images determined individual red bead displacements throughout the experiment. The system can provide displacement accuracies on the order of 0.5 to 1 pixel is the image is taken directly from the video camera. Digitizing an image from a video cassette recorder introduces an additional repeatability error of 0.5 to 1 pixel. Other programs were written to provide hardcopy prints of the digitized images on a dot-matrix printer.

Influence of different luting protocols on shear bond strength of computer aided design/computer aided manufacturing resin nanoceramic material to dentin

PubMed Central

Poggio, Claudio; Pigozzo, Marco; Ceci, Matteo; Scribante, Andrea; Beltrami, Riccardo; Chiesa, Marco

2016-01-01

Background: The purpose of this study was to evaluate the influence of three different luting protocols on shear bond strength of computer aided design/computer aided manufacturing (CAD/CAM) resin nanoceramic (RNC) material to dentin. Materials and Methods: In this in vitro study, 30 disks were milled from RNC blocks (Lava Ultimate/3M ESPE) with CAD/CAM technology. The disks were subsequently cemented to the exposed dentin of 30 recently extracted bovine permanent mandibular incisors. The specimens were randomly assigned into 3 groups of 10 teeth each. In Group 1, disks were cemented using a total-etch protocol (Scotchbond™ Universal Etchant phosphoric acid + Scotchbond Universal Adhesive + RelyX™ Ultimate conventional resin cement); in Group 2, disks were cemented using a self-etch protocol (Scotchbond Universal Adhesive + RelyX™ Ultimate conventional resin cement); in Group 3, disks were cemented using a self-adhesive protocol (RelyX™ Unicem 2 Automix self-adhesive resin cement). All cemented specimens were placed in a universal testing machine (Instron Universal Testing Machine 3343) and submitted to a shear bond strength test to check the strength of adhesion between the two substrates, dentin, and RNC disks. Specimens were stressed at a crosshead speed of 1 mm/min. Data were analyzed with analysis of variance and post-hoc Tukey's test at a level of significance of 0.05. Results: Post-hoc Tukey testing showed that the highest shear strength values (P < 0.001) were reported in Group 2. The lowest data (P < 0.001) were recorded in Group 3. Conclusion: Within the limitations of this in vitro study, conventional resin cements (coupled with etch and rinse or self-etch adhesives) showed better shear strength values compared to self-adhesive resin cements. Furthermore, conventional resin cements used together with a self-etch adhesive reported the highest values of adhesion. PMID:27076822

Osteoclastic differentiation and resorption is modulated by bioactive metal ions Co2+, Cu2+ and Cr3+ incorporated into calcium phosphate bone cements.

PubMed

Bernhardt, Anne; Schamel, Martha; Gbureck, Uwe; Gelinsky, Michael

2017-01-01

Biologically active metal ions in low doses have the potential to accelerate bone defect healing. For successful remodelling the interaction of bone graft materials with both bone-forming osteoblasts and bone resorbing osteoclasts is crucial. In the present study brushite forming calcium phosphate cements (CPC) were doped with Co2+, Cu2+ and Cr3+ and the influence of these materials on osteoclast differentiation and activity was examined. Human osteoclasts were differentiated from human peripheral blood mononuclear cells (PBMC) both on the surface and in indirect contact to the materials on dentin discs. Release of calcium, phosphate and bioactive metal ions was determined using ICP-MS both in the presence and absence of the cells. While Co2+ and Cu2+ showed a burst release, Cr3+ was released steadily at very low concentrations (below 1 μM) and both calcium and phosphate release of the cements was considerably changed in the Cr3+ modified samples. Direct cultivation of PBMC/osteoclasts on Co2+ cements showed lower attached cell number compared to the reference but high activity of osteoclast specific enzymes tartrate resistant acid phosphatase (TRAP), carbonic anhydrase II (CAII) and cathepsin K (CTSK) and significantly increased gene expression of vitronectin receptor. Indirect cultivation with diluted Co2+ cement extracts revealed highest resorbed area compared to all other modifications and the reference. Cu2+ cements had cytotoxic effect on PBMC/osteoclasts during direct cultivation, while indirect cultivation with diluted extracts from Cu2+ cements did not provoke cytotoxic effects but a strictly inhibited resorption. Cr3+ doped cements did not show cytotoxic effects at all. Gene expression and enzyme activity of CTSK was significantly increased in direct culture. Indirect cultivation with Cr3+ doped cements revealed significantly higher resorbed area compared to the reference. In conclusion Cr3+ doped calcium phosphate cements are an innovative cement modification because of their high cytocompatibility and support of active resorption by osteoclasts.

BLENDED CALCIUM ALUMINATE-CALCIUM SULFATE CEMENT-BASED GROUT FOR P-REACTOR VESSEL IN-SITU DECOMMISSIONING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Langton, C.; Stefanko, D.

2011-03-10

The objective of this report is to document laboratory testing of blended calcium aluminate - calcium hemihydrate grouts for P-Reactor vessel in-situ decommissioning. Blended calcium aluminate - calcium hemihydrate cement-based grout was identified as candidate material for filling (physically stabilizing) the 105-P Reactor vessel (RV) because it is less alkaline than portland cement-based grout which has a pH greater than 12.4. In addition, blended calcium aluminate - calcium hemihydrate cement compositions can be formulated such that the primary cementitious phase is a stable crystalline material. A less alkaline material (pH {<=} 10.5) was desired to address a potential materials compatibilitymore » issue caused by corrosion of aluminum metal in highly alkaline environments such as that encountered in portland cement grouts [Wiersma, 2009a and b, Wiersma, 2010, and Serrato and Langton, 2010]. Information concerning access points into the P-Reactor vessel and amount of aluminum metal in the vessel is provided elsewhere [Griffin, 2010, Stefanko, 2009 and Wiersma, 2009 and 2010, Bobbitt, 2010, respectively]. Radiolysis calculations are also provided in a separate document [Reyes-Jimenez, 2010].« less

Tentative to use wastes from thermal power plants for construction building materials

NASA Astrophysics Data System (ADS)

Bui, Quoc-Bao; Phan, To-Anh-Vu; Tran, Minh-Tung; Le, Duc-Hien

2018-04-01

Thermal power plants (TPP) generates wastes (bottom and fly ashes) which become a serious environmental problem in Vietnam. Indeed, although in several countries fly ash can be used for cement industry, fly ash from actual TPP in Vietnam does not have enough good quality for cement production, because the fly ash treatment phase has not yet included in the generations of existing Vietnamese TPP. That is why bottom ash and fly ash purely become wastes and their evacuation is an urgent demand of the society. This paper presents an investigation using fly and bottom ashes in the manufacturing of construction materials. The main aims of this study is to reduce environmental impacts of fly and bottom ashes, and to test another non-conventional binder to replace cement in the manufacture of unburnt bricks. Several proportions of fly ash, bottom ash, cement, gravel, sand and water were tested to manufacture concretes. Then, geopolymer was prepared from the fly ash and an activator. Specimens were tested in uniaxial compressions. Results showed that the cement concrete tested had the compressive strengths which could be used for low rise constructions and the material using geopolymer could be used for non-load-bearing materials (unburnt bricks).

A New Biphasic Dicalcium Silicate Bone Cement Implant.

PubMed

Zuleta, Fausto; Murciano, Angel; Gehrke, Sergio A; Maté-Sánchez de Val, José E; Calvo-Guirado, José L; De Aza, Piedad N

2017-07-06

This study aimed to investigate the processing parameters and biocompatibility of a novel biphasic dicalcium silicate (C₂S) cement. Biphasic α´ L + β-C₂S ss was synthesized by solid-state processing, and was used as a raw material to prepare the cement. In vitro bioactivity and biocompatibility studies were assessed by soaking the cement samples in simulated body fluid (SBF) and human adipose stem cell cultures. Two critical-sized defects of 6 mm Ø were created in 15 NZ tibias. A porous cement made of the high temperature forms of C₂S, with a low phosphorous substitution level, was produced. An apatite-like layer covered the cement's surface after soaking in SBF. The cell attachment test showed that α´ L + β-C₂S ss supported cells sticking and spreading after 24 h of culture. The cement paste (55.86 ± 0.23) obtained higher bone-to-implant contact (BIC) percentage values (better quality, closer contact) in the histomorphometric analysis, and defect closure was significant compared to the control group (plastic). The residual material volume of the porous cement was 35.42 ± 2.08% of the initial value. The highest BIC and bone formation percentages were obtained on day 60. These results suggest that the cement paste is advantageous for initial bone regeneration.

Development of calcium phosphate cement using chitosan and citric acid for bone substitute materials.

PubMed

Yokoyama, Atsuro; Yamamoto, Satoru; Kawasaki, Takao; Kohgo, Takao; Nakasu, Masanori

2002-02-01

We developed a calcium phosphate cement that could be molded into any desired shape due to its chewing-gum-like consistency after mixing. The powder component of the cement consists of alpha-tricalcium phosphate and tetracalcium phosphate, which were made by decomposition of hydroxyapatite ceramic blocks. The liquid component consists of citric acid, chitosan and glucose solution. In this study, we used 20% citric acid (group 20) and 45% citric acid (group 45). The mechanical properties and biocompatibility of this new cement were investigated. The setting times of cements were 5.5 min, in group 20 and 6.4 min, in group 45. When incubated in physiological saline, the cements were transformed to hydroxyapatite at 3, and 6 weeks, the compressive strengths were 15.6 and 20.7 MPa, in group 45 and group 20, respectively. The inflammatory response around the cement implanted on the bone and in the subcutaneous tissue in rats was more prominent in group 45 than in group 20 at 1 week after surgery. After 4 weeks, the inflammation disappeared and the cement had bound to bone in both groups. These results indicate that this new calcium phosphate cement is a suitable bone substitute material and that the concentration of citric acid in the liquid component affects its mechanical properties and biocompatibility.

Capping a Pulpotomy with Calcium Aluminosilicate Cement: Comparison to Mineral Trioxide Aggregates

PubMed Central

Kramer, Phillip R.; Woodmansey, Karl F.; White, Robert; Primus, Carolyn M.; Opperman, Lynne A.

2014-01-01

Introduction Calcium aluminate cements have shown little affinity for bacterial growth, low toxicity, and immunogenicity when used as a restoration material, but calcium aluminate cements have not been tested in vivo in pulpotomy procedures. Methods To address this question, a calcium aluminate cement (Quick-Set) was tested along with 2 mineral trioxide aggregates, ProRoot MTA and MTA Plus. These cements were used as a capping agent after pulpotomy. Control rats had no pulpotomy, or the pulpotomy was not capped. Proinflammatory cytokines interleukin (IL)-1β and IL-1α were measured, and histology was performed at 30 and 60 days after capping. The nociceptive response was determined by measuring the lengthening of the rat's meal duration. Results and Conclusions: IL-1β and IL-1α concentrations were reduced in the capped teeth, but no differences were observed among the 3 cements. Dentinal bridging could be detected at both 30 and 60 days with each of the 3 cements, and the pulps were still vital 60 days after capping. Meal duration significantly shortened after placement of the 3 different cements, indicating a nociceptive response, but there were no differences among the materials. Calcium aluminate cements had similar properties to mineral trioxide aggregates and is a viable option for pulpotomy procedures. PMID:25146026

Application of Bacillus subtilis 168 as a multifunctional agent for improvement of the durability of cement mortar.

PubMed

Park, Sung-Jin; Park, Jong-Myong; Kim, Wha-Jung; Ghim, Sa-Youl

2012-11-01

Microbiological calcium carbonate precipitation (MCCP) has been investigated for its ability to improve the durability of cement mortar. However, very few strains have been applied to crack remediation and strengthening of cementitious materials. In this study, we report the biodeposition of Bacillus subtilis 168 and its ability to enhance the durability of cement material. B. subtilis 168 was applied to the surface of cement specimens. The results showed a new layer of deposited organic-inorganic composites on the surface of the cement paste. In addition, the water permeability of the cement paste treated with B. subtilis 168 was lower than that of non-treated specimens. Furthermore, artificial cracks in the cement paste were completely remediated by the biodeposition of B. subtilis 168. The compressive strength of cement mortar treated with B. subtilis 168 increased by about 19.5% when compared with samples completed with only B4 medium. Taken together, these findings suggest that the biodeposition of B. subtilis 168 could be used as a sealing and coating agent to improve the strength and water resistance of concrete. This is the first paper to report the application of Bacillus subtilis 168 for its ability to improve the durability of cement mortar through calcium carbonate precipitation.

Influence of Cellulosic Fibres on the Physical Properties of Fibre Cement Composites

NASA Astrophysics Data System (ADS)

Hospodarova, V.; Stevulova, N.; Vaclavik, V.; Dvorsky, T.

2017-10-01

Nowadays, there are new approaches directing to processing of non-conventional fibre-cement composites for application in the housing construction. Vegetable cellulosic fibres coming from natural resources used as reinforcement in cost-effective and environmental friendly building products are in the spotlight. The applying of natural fibres in cement based composites is narrowly linked to the ecological building sector, where a choice of materials is based on components including recyclable, renewable raw materials and low-resource manufacture techniques. In this paper, two types of cellulosic fibres coming from wood pulp and recycled waste paper with 0.2%; 0.3% and 0.5% of fibre addition into cement mixtures were used. Differences in the physical characteristics (flowability, density, coefficient of thermal conductivity and water absorbability) of 28 days hardened fibre-cement composites are investigated. Addition of cellulosic fibres to cement mixture caused worsening the workability of fresh mixture as well as absorbability of hardened composites due to hydrophilic nature of biomaterial, whereas density and thermal conductivity of manufactured cement based fibre plaster are enhanced. The physical properties of cement plasters based on cellulosic fibres depend on structural, physical characteristics of cellulosic fibres, their nature and processing.

Waste-Based Pervious Concrete for Climate-Resilient Pavements.

PubMed

Ho, Hsin-Lung; Huang, Ran; Hwang, Lih-Chuan; Lin, Wei-Ting; Hsu, Hui-Mi

2018-05-27

For the sake of environmental protection and circular economy, cement reduction and cement substitutes have become popular research topics, and the application of green materials has become an important issue in the development of building materials. This study developed green pervious concrete using water-quenched blast-furnace slag (BFS) and co-fired fly ash (CFFA) to replace cement. The objectives of this study were to gauge the feasibility of using a non-cement binder in pervious concrete and identify the optimal binder mix design in terms of compressive strength, permeability, and durability. For filled percentage of voids by cement paste (FPVs) of 70%, 80%, and 90%, which mixed with CFFA and BFS as the binder (40 + 60%, 50 + 50%, and 60 + 40%) to create pervious concrete with no cement. The results indicate that the complete (100%) replacement of cement with CFFA and BFS with no alkaline activator could induce hydration, setting, and hardening. After a curing period of 28 days, the compressive strength with different FPVs could reach approximately 90% that of the control cement specimens. The cementless pervious concrete specimens with BFS:CFFA = 7:3 and FPV = 90% presented better engineering properties and permeability.

Granular impact cratering by liquid drops: Understanding raindrop imprints through an analogy to asteroid strikes

PubMed Central

Zhao, Runchen; Zhang, Qianyun; Tjugito, Hendro; Cheng, Xiang

2015-01-01

When a granular material is impacted by a sphere, its surface deforms like a liquid yet it preserves a circular crater like a solid. Although the mechanism of granular impact cratering by solid spheres is well explored, our knowledge on granular impact cratering by liquid drops is still very limited. Here, by combining high-speed photography with high-precision laser profilometry, we investigate liquid-drop impact dynamics on granular surface and monitor the morphology of resulting impact craters. Surprisingly, we find that despite the enormous energy and length difference, granular impact cratering by liquid drops follows the same energy scaling and reproduces the same crater morphology as that of asteroid impact craters. Inspired by this similarity, we integrate the physical insight from planetary sciences, the liquid marble model from fluid mechanics, and the concept of jamming transition from granular physics into a simple theoretical framework that quantitatively describes all of the main features of liquid-drop imprints in granular media. Our study sheds light on the mechanisms governing raindrop impacts on granular surfaces and reveals a remarkable analogy between familiar phenomena of raining and catastrophic asteroid strikes. PMID:25548187

Dynamic Deformation and Collapse of Granular Columns

NASA Astrophysics Data System (ADS)

Uenishi, K.; Tsuji, K.; Doi, S.

2009-12-01

Large dynamic deformation of granular materials may be found in nature not only in the failure of slopes and cliffs — due to earthquakes, rock avalanches, debris flows and landslides — but also in earthquake faulting itself. Granular surface flows often consist of solid grains and intergranular fluid, but the effect of the fluid may be usually negligible because the volumetric concentration of grains is in many cases high enough for interparticle forces to dominate momentum transport. Therefore, the investigation of dry granular flow of a mass might assist in further understanding of the above mentioned geophysical events. Here, utilizing a high-speed digital video camera system, we perform a simple yet fully-controlled series of laboratory experiments related to the collapse of granular columns. We record, at an interval of some microseconds, the dynamic transient granular mass flow initiated by abrupt release of a tube that contains dry granular materials. The acrylic tube is partially filled with glass beads and has a cross-section of either a fully- or semi-cylindrical shape. Upon sudden removal of the tube, the granular solid may fragment under the action of its own weight and the particles spread on a rigid horizontal plane. This study is essentially the extension of the previous ones by Lajeunesse et al. (Phys. Fluids 2004) and Uenishi and Tsuji (JPGU 2008), but the striped layers of particles in a semi-cylindrical tube, newly introduced in this contribution, allow us to observe the precise particle movement inside the granular column: The development of slip lines inside the column and the movement of particles against each other can be clearly identified. The major controlling parameters of the spreading dynamics are the initial aspect ratio of the granular (semi-)cylindrical column, the frictional properties of the horizontal plane (substrate) and the size of beads. We show the influence of each parameter on the average flow velocity and final radius and height of the deposit, i.e., the fraction of granular mass mobilized by the flow, and the final shape of the deposit.

Peculiarities of hydration of Portland cement with synthetic nano-silica

NASA Astrophysics Data System (ADS)

Kotsay, Galyna

2017-12-01

Application of nano-materials in cement products significantly, improves their properties. Of course, the effectiveness of the materials depends on their quantity and the way they are introduced into the system. So far, amongst nano-materials used in construction, the most preferred was nano-silica. This research investigated the effect of synthetic precipitated nano-silica on the cement hydration as well as, on the physical and mechanical properties of pastes and mortars. Obtained results showed that admixture of nano-silica enhanced flexural and compressive strength of cement after 2 and 28 days, however, only when admixture made up 0.5% and 1.0%. On the other hand, the use of nano-silica in the amount 2% had some limitations, due to its ability to agglomerate, which resulted in deterioration of the rheological and mechanical properties.

Characterization of Cement Particles Found in Peri-implantitis-Affected Human Biopsy Specimens.

PubMed

Burbano, Maria; Wilson, Thomas G; Valderrama, Pilar; Blansett, Jonathan; Wadhwani, Chandur P K; Choudhary, Pankaj K; Rodriguez, Lucas C; Rodrigues, Danieli C

2015-01-01

Peri-implantitis is a disease characterized by soft tissue inflammation and continued loss of supporting bone, which can result in implant failure. Peri-implantitis is a multifactorial disease, and one of its triggering factors may be the presence of excess cement in the soft tissues surrounding an implant. This descriptive study evaluated the composition of foreign particles from 36 human biopsy specimens with 19 specimens selected for analysis. The biopsy specimens were obtained from soft tissues affected by peri-implantitis around cement-retained implant crowns and compared with the elemental composition of commercial luting cement. Nineteen biopsy specimens were chosen for the comparison, and five test cements (TempBond, Telio, Premier Implant Cement, Intermediate Restorative Material, and Relyx) were analyzed using scanning electron microscopy equipped with energy dispersive x-ray spectroscopy. This enabled the identification of the chemical composition of foreign particles embedded in the tissue specimens and the composition of the five cements. Statistical analysis was conducted using classification trees to pair the particles present in each specimen with the known cements. The particles in each biopsy specimen could be associated with one of the commercial cements with a level of probability ranging between .79 and 1. TempBond particles were found in one biopsy specimen, Telio particles in seven, Premier Implant Cement particles in four, Relyx particles in four, and Intermediate Restorative Material particles in three. Particles found in human soft tissue biopsy specimens around implants affected by peri-implant disease were associated with five commercially available dental cements.

Assessment of elemental and NROM/TENORM hazard potential from non-nuclear industries in North Sinai, Egypt.

PubMed

El-Mekawy, A F; Badran, H M; Seddeek, M K; Sharshar, T; Elnimr, T

2015-09-01

Non-nuclear industries use raw materials containing significant levels of naturally occurring radioactive material (NORM). The processing of these materials may expose workers engaged in or even people living near such sites to technologically enhanced naturally occurring radioactive material (TENORM) above the natural background. Inductively coupled plasma and gamma ray spectrometry have been used to determine major and trace elements and radionuclide concentrations in various samples, respectively, in order to investigate the environmental impact of coal mining and cement plant in North Sinai, Egypt. Generally, very little attention was directed to the large volumes of waste generated by either type of industrial activities. Different samples were analyzed including various raw materials, coal, charcoal, Portland and white cement, sludge, and wastes. Coal mine and cement plant workers dealing with waste and kaolin, respectively, are subjected to a relatively high annual effective dose. One of the important finding is the enhancement of all measured elements and radionuclides in the sludge found in coal mine. It may pose an environmental threat because of its large volume and its use as combustion material. The mine environment may have constituted Al, Fe, Cr, and V pollution source for the local area. Higher concentration of Al, Fe, Mn, B, Co, Cr, Mn, Ni, Sr, V, and TENORM were found in Portland cement and Zn in white cement. Coal has higher concentrations of Al, Fe, B, Co, Cr, and V as well as (226)Ra and (232)Th. The compiled results from the present study and different worldwide investigations demonstrate the obvious unrealistic ranges normally used for (226)Ra and (232)Th activity concentrations in coal and provided ranges for coal, Portland and white cement, gypsum, and limestone.

Present and future of glass-ionomers and calcium-silicate cements as bioactive materials in dentistry: biophotonics-based interfacial analyses in health and disease.

PubMed

Watson, Timothy F; Atmeh, Amre R; Sajini, Shara; Cook, Richard J; Festy, Frederic

2014-01-01

Since their introduction, calcium silicate cements have primarily found use as endodontic sealers, due to long setting times. While similar in chemistry, recent variations such as constituent proportions, purities and manufacturing processes mandate a critical understanding of service behavior differences of the new coronal restorative material variants. Of particular relevance to minimally invasive philosophies is the potential for ion supply, from initial hydration to mature set in dental cements. They may be capable of supporting repair and remineralization of dentin left after decay and cavity preparation, following the concepts of ion exchange from glass ionomers. This paper reviews the underlying chemistry and interactions of glass ionomer and calcium silicate cements, with dental tissues, concentrating on dentin-restoration interface reactions. We additionally demonstrate a new optical technique, based around high resolution deep tissue, two-photon fluorescence and lifetime imaging, which allows monitoring of undisturbed cement-dentin interface samples behavior over time. The local bioactivity of the calcium-silicate based materials has been shown to produce mineralization within the subjacent dentin substrate, extending deep within the tissues. This suggests that the local ion-rich alkaline environment may be more favorable to mineral repair and re-construction, compared with the acidic environs of comparable glass ionomer based materials. The advantages of this potential re-mineralization phenomenon for minimally invasive management of carious dentin are self-evident. There is a clear need to improve the bioactivity of restorative dental materials and these calcium silicate cement systems offer exciting possibilities in realizing this goal. Copyright © 2013 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

Enhanced bone screw fixation with biodegradable bone cement in osteoporotic bone model.

PubMed

Juvonen, Tiina; Koistinen, Arto; Kröger, Heikki; Lappalainen, Reijo

2012-09-27

The purpose of this study was to study the potential of novel biodegradable PCL bone cement to improve bone screw fixation strength in osteoporotic bone. The biomechanical properties of bone cement (ε-polycaprolactone, PCL) and fixation strength were studied using biomechanical tests and bone screws fixed in an osteoporotic bone model. Removal torques and pullout strengths were assessed for cortical, self-tapping, and cancellous screws inserted in the osteoporotic bone model (polyurethane foam blocks with polycarbonate plate) with and without PCL bone cement. Open cell and cellular rigid foam blocks with a density of 0.12 g/cm3 were used in this model. Removal torques were significantly (more than six-fold) improved with bone cement for cancellous screws. Furthermore, the bone cement improved pullout strengths three to 12 times over depending on the screw and model material. Biodegradable bone cement turned out to be a very potential material to stabilize screw fixation in osteoporotic bone. The results warrant further research before safe clinical use, especially to clarify clinically relevant factors using real osteoporotic bone under human body conditions and dynamic fatigue testing for long-term performance.

Leaching of heavy metals from cementitious composites made of new ternary cements

NASA Astrophysics Data System (ADS)

Kuterasińska-Warwas, Justyna; Król, Anna

2017-10-01

The paper presents a comparison of research methods concerning the leaching of harmful substances (selected heavy metal cations ie. Pb, Cu, Zn and Cr) and their degree of immobilization in cement matrices. The new types of ternary cements were used in the study, where a large proportion of cement clinker was replaced by other non-clinker components - industrial wastes, ie. siliceous fly ash from power industry and granulated blast furnace slag from the iron and steel industry. In studied cementitious binders also ground limestone was used, which is a widely available raw material. The aim of research is determining the suitability of new cements for neutralizing harmful substances in the obtained matrices. The application of two research methods in accordance with EN 12457-4 and NEN 7275 intends to reflection of changing environmental conditions whom composite materials may actually undergo during their exploitation or storing on landfills. The results show that cements with high addition of non-clinker components are suitable for stabilization of toxic substances and the obtained cement matrices retain a high degree of immobilization of heavy metals at the level of 99%.

40 CFR 63.1352 - Additional test methods.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) National Emission Standards for Hazardous Air Pollutants From the Portland Cement Manufacturing Industry... determine the rates of emission of HCl from kilns and associated bypass stacks at portland cement... emission of specific organic HAP from raw material dryers, and kilns at Portland cement manufacturing...

Application of antifungal CFB to increase the durability of cement mortar.

PubMed

Park, Jong-Myong; Park, Sung-Jin; Kim, Wha-Jung; Ghim, Sa-Youl

2012-07-01

Antifungal cement mortar or microbiological calcium carbonate precipitation on cement surface has been investigated as functional concrete research. However, these research concepts have never been fused with each other. In this study, we introduced the antifungal calciteforming bacteria (CFB) Bacillus aryabhattai KNUC205, isolated from an urban tunnel (Daegu, South Korea). The major fungal deteriogens in urban tunnel, Cladosporium sphaerospermum KNUC253, was used as a sensitive fungal strain. B. aryabhattai KNUC205 showed CaCO3 precipitation on B4 medium. Cracked cement mortar pastes were made and neutralized by modified methods. Subsequently, the mixture of B. aryabhattai KNUC205, conidiospore of C. sphaerospermum KNUC253, and B4 agar was applied to cement cracks and incubated at 18 degrees C for 16 days. B. aryabhattai KNUC205 showed fungal growth inhibition against C. sphaerospermum. Furthermore, B. aryabhattai KNUC205 showed crack remediation ability and water permeability reduction of cement mortar pastes. Taken together, these results suggest that the CaCO3 precipitation and antifungal properties of B. aryabhattai KNUC205 could be used as an effective sealing or coating material that can also prevent deteriorative fungal growth. This study is the first application and evaluation research that incorporates calcite formation with antifungal capabilities of microorganisms for an environment-friendly and more effective protection of cement materials. In this research, the conception of microbial construction materials was expanded.

Effect of Nano-SiO2 on the Hydration and Microstructure of Portland Cement

PubMed Central

Wang, Liguo; Zheng, Dapeng; Zhang, Shupeng; Cui, Hongzhi; Li, Dongxu

2016-01-01

This paper systematically studied the modification of cement-based materials by nano-SiO2 particles with an average diameter of about 20 nm. In order to obtain the effect of nano-SiO2 particles on the mechanical properties, hydration, and pore structure of cement-based materials, adding 1%, 3%, and 5% content of nano-SiO2 in cement paste, respectively. The results showed that the reaction of nano-SiO2 particles with Ca(OH)2 (crystal powder) started within 1 h, and formed C–S–H gel. The reaction speed was faster after aging for three days. The mechanical properties of cement-based materials were improved with the addition of 3% nano-SiO2, and the early strength enhancement of test pieces was obvious. Three-day compressive strength increased 33.2%, and 28-day compressive strength increased 18.5%. The exothermic peak of hydration heat of cement increased significantly after the addition of nano-SiO2. Appearance time of the exothermic peak was advanced and the total heat release increased. Thermogravimetric-differential scanning calorimetry (TG-DSC) analysis showed that nano-SiO2 promoted the formation of C–S–H gel. The results of mercury intrusion porosimetry (MIP) showed that the total porosity of cement paste with 3% nano-SiO2 was reduced by 5.51% and 5.4% at three days and 28 days, respectively, compared with the pure cement paste. At the same time, the pore structure of cement paste was optimized, and much-detrimental pores and detrimental pores decreased, while less harmful pores and innocuous pores increased. PMID:28335369

Stick-slip instabilities in sheared granular flow: The role of friction and acoustic vibrations.

PubMed

Lieou, Charles K C; Elbanna, Ahmed E; Langer, J S; Carlson, J M

2015-08-01

We propose a theory of shear flow in dense granular materials. A key ingredient of the theory is an effective temperature that determines how the material responds to external driving forces such as shear stresses and vibrations. We show that, within our model, friction between grains produces stick-slip behavior at intermediate shear rates, even if the material is rate strengthening at larger rates. In addition, externally generated acoustic vibrations alter the stick-slip amplitude, or suppress stick-slip altogether, depending on the pressure and shear rate. We construct a phase diagram that indicates the parameter regimes for which stick-slip occurs in the presence and absence of acoustic vibrations of a fixed amplitude and frequency. These results connect the microscopic physics to macroscopic dynamics and thus produce useful information about a variety of granular phenomena, including rupture and slip along earthquake faults, the remote triggering of instabilities, and the control of friction in material processing.

Slow dynamics and strength recovery in unconsolidated granular earth materials: a mechanistic theory

DOE PAGES

Lieou, Charles Ka Cheong; Daub, Eric G.; Ecke, Robert E.; ...

2017-09-08

Rock materials often display long-time relaxation, commonly termed aging or “slow dynamics”, after the cessation of acoustic perturbations. In this paper, we focus on unconsolidated rock materials and propose to explain such nonlinear relaxation through the Shear-Transformation-Zone (STZ) theory of granular media, adapted for small stresses and strains. The theory attributes the observed relaxation to the slow, irreversible change of positions of constituent grains, and posits that the aging process can be described in three stages: fast recovery before some characteristic time associated with the subset of local plastic events or grain rearrangements with a short time scale, log-linear recoverymore » of the elastic modulus at intermediate times, and gradual turnover to equilibrium steady-state behavior at long times. Here we demonstrate good agreement with experiments on aging in granular materials such as simulated fault gouge after an external disturbance. These results may provide insights into observed modulus recovery after strong shaking in the near surface region of earthquake zones.« less

Slow Dynamics and Strength Recovery in Unconsolidated Granular Earth Materials: A Mechanistic Theory

NASA Astrophysics Data System (ADS)

Lieou, Charles K. C.; Daub, Eric G.; Ecke, Robert E.; Johnson, Paul A.

2017-10-01

Rock materials often display long-time relaxation, commonly termed aging or "slow dynamics," after the cessation of acoustic perturbations. In this paper, we focus on unconsolidated rock materials and propose to explain such nonlinear relaxation through the shear-transformation-zone theory of granular media, adapted for small stresses and strains. The theory attributes the observed relaxation to the slow, irreversible change of positions of constituent grains and posits that the aging process can be described in three stages: fast recovery before some characteristic time associated with the subset of local plastic events or grain rearrangements with a short time scale, log linear recovery of the elastic modulus at intermediate times, and gradual turnover to equilibrium steady state behavior at long times. We demonstrate good agreement with experiments on aging in granular materials such as simulated fault gouge after an external disturbance. These results may provide insights into observed modulus recovery after strong shaking in the near surface region of earthquake zones.

ETV Program Report: Coatings for Wastewater Collection Systems - Standard Cement Materials, Epoxy Coating 4553

EPA Science Inventory

The Standard Cement Materials, Inc. Standard Epoxy Coating 4553™ (SEC 4553) epoxy coating used for wastewater collection system rehabilitation was evaluated by EPA’s Environmental Technology Verification Program under laboratory conditions at the Center for Innovative Grouting Ma...

Influences of cement source and sample of cement source on compressive strength variability of gravel aggregate concrete.

DOT National Transportation Integrated Search

2013-06-01

The strength of concrete is influenced by each constituent material used in the concrete : mixture and the proportions of each ingredient. Water-cementitious ratio, cementitious materials, air : content, chemical admixtures, and type of coarse aggreg...

Treatment of root fracture with accompanying resorption using cermet cement.

PubMed

Lui, J L

1992-02-01

A method of treating an apical root fracture with accompanying resorption at the junction of the fracture fragments using glass-cermet cement is described. Endodontically, the material had previously been used for repair of lateral resorptive root defects and retrograde root fillings. Complete bone regeneration was observed three years post-operatively following treatment of the root fracture in the conventional manner. The various advantages of glass-cermet cement as a root filling material used in the technique described are discussed.

Solubility of a new calcium silicate-based root-end filling material

PubMed Central

Singh, Shishir; Podar, Rajesh; Dadu, Shifali; Kulkarni, Gaurav; Purba, Rucheet

2015-01-01

Introduction: The purpose of this study was to compare solubility of a new calcium silicate-based cement, Biodentine with three commonly used root-end filling materials viz. glass-ionomer cement (GIC), intermediate restorative material (IRM), and mineral trioxide aggregate (MTA). Materials and Methods: Twenty stainless steel ring molds were filled with cements corresponding to four groups (n = 5). The weight of 20 dried glass bottles was recorded. Samples were transferred to bottles containing 5 ml of distilled water and stored for 24 h. The bottles were dried at 105΀C and weighed. This procedure was repeated for 3, 10, 30, and 60 days. Data was analyzed with one-way analysis of variance (ANOVA) test (P < 0.05). Results: Biodentine demonstrated significantly higher solubility than MTA for 30- and 60-day immersion periods. Statistical difference was noted between the solubility values of Biodentine samples amongst each of the five time intervals. Conclusions: Biodentine exhibited higher solubility in comparison with all other cements. PMID:25829696

Lime kiln dust as a potential raw material in portland cement manufacturing

USGS Publications Warehouse

Miller, M. Michael; Callaghan, Robert M.

2004-01-01

In the United States, the manufacture of portland cement involves burning in a rotary kiln a finely ground proportional mix of raw materials. The raw material mix provides the required chemical combination of calcium, silicon, aluminum, iron, and small amounts of other ingredients. The majority of calcium is supplied in the form of calcium carbonate usually from limestone. Other sources including waste materials or byproducts from other industries can be used to supply calcium (or lime, CaO), provided they have sufficiently high CaO content, have low magnesia content (less than 5 percent), and are competitive with limestone in terms of cost and adequacy of supply. In the United States, the lime industry produces large amounts of lime kiln dust (LKD), which is collected by dust control systems. This LKD may be a supplemental source of calcium for cement plants, if the lime and cement plants are located near enough to each other to make the arrangement economical.

Solidification/stabilization of dredged marine sediments for road construction.

PubMed

Wang, Dong Xing; Abriak, Nor Edine; Zentar, Rachid; Xu, WeiYa

2012-01-01

Cement/lime-based solidification is an environmentally sound solution for the management of dredged marine sediments, instead of traditional solutions such as immersion. Based on the mineralogical composition and physical characteristics of Dunkirk sediments, the effects of cement and lime are assessed through Atterberg limits, modified Proctor compaction, unconfined compressive strength and indirect tensile strength tests. The variation of Atterberg limits and the improvement in strength are discussed at different binder contents. The potential of sediments solidified with cement or lime for road construction is evaluated through a proposed methodology from two aspects: I-CBR value and material classification. The test results show the feasibility of solidified dredged sediments for beneficial use as a material in road construction. Cement is superior to lime in terms of strength improvement, and adding 6% cement is an economic and reasonable method to stabilize fine sediments.

Radiopacity of portland cement associated with different radiopacifying agents.

PubMed

Húngaro Duarte, Marco Antonio; de Oliveira El Kadre, Guâniara D'arc; Vivan, Rodrigo Ricci; Guerreiro Tanomaru, Juliane Maria; Tanomaru Filho, Mário; de Moraes, Ivaldo Gomes

2009-05-01

This study evaluated the radiopacity of Portland cement associated with the following radiopacifying agents: bismuth oxide, zinc oxide, lead oxide, bismuth subnitrate, bismuth carbonate, barium sulfate, iodoform, calcium tungstate, and zirconium oxide. A ratio of 20% radiopacifier and 80% white Portland cement by weight was used for analysis. Pure Portland cement and dentin served as controls. Cement/radiopacifier and dentin disc-shaped specimens were fabricated, and radiopacity testing was performed according to the ISO 6876/2001 standard for dental root sealing materials. Using Insight occlusal films, the specimens were radiographed near to a graduated aluminum stepwedge varying from 2 to 16 mm in thickness. The radiographs were digitized and radiopacity compared with the aluminum stepwedge using Digora software (Orion Corporation Soredex, Helsinki, Finland). The radiographic density data were converted into mmAl and analyzed statistically by analysis of variance and Tukey-Kramer test (alpha = 0.05). The radiopacity of pure Portland cement was significantly lower (p < 0.05) than that of dentin, whereas all cement/radiopacifier mixtures were significantly more radiopaque than dentin and Portland cement alone (p < 0.05). Portland cement/bismuth oxide and Portland cement/lead oxide presented the highest radiopacity values and differed significantly from the other materials (p < 0.05), whereas Portland cement/zinc oxide presented the lowest radiopacity values of all mixtures (p < 0.05). All tested substances presented higher radiopacity than that of dentin and may potentially be added to the Portland cement as radiopacifying agents. However, the possible interference of the radiopacifiers with the setting chemistry, biocompatibility, and physical properties of the Portland cement should be further investigated before any clinical recommendation can be done.

Contamination of the cement raw material in a quarry site by seawater intrusion, Darica-Turkey

NASA Astrophysics Data System (ADS)

Camur, M. Zeki; Doyuran, Vedat

2008-02-01

The open pit mining nearby shoreline is planned to be extended into below sea level in order to use additional reserves of the cement raw material (marl). The raw material is currently contaminated by seawater intrusion below a depth of 20 m up to the distance of 90 m from shoreline. Seawater intrusion related contamination of the material used for the cement production was investigated by means of diffusion process for the future two below sea level mining scenarios covering 43 years of period. According to the results, chloride concentrations higher than the tolerable limit of a cement raw material would be present in the material about 10-25 cm inward from each discontinuity surface, controlling groundwater flow, located between 170 and 300 m landward from the shoreline at below sea level mining depths of 0-30 m. The estimations suggest that total amounts of dilution required for the contaminated raw material to reduce its concentration level to the tolerance limit with uncontaminated raw material are about 113- to 124-fold for scenario I (13 years of below sea level mining after 30 years of above sea level mining) and about 126- to 138-fold for scenario II (43 years of simultaneous above and below sea level minings).

Effect of Fly Ash and Silica Fume on the Mechanical Properties of Cement Paste at Different Stages of Hydration

DTIC Science & Technology

2015-08-10

All materials were placed in a clean, labeled stainless steel mixing bowl and weighed to the nearest ten thousandth of a pound. The cement and fly...on the Mechanical Properties of Cement Paste at Different Stages of Hydration This thesis investigates the effect of fly ash and silica fume on... cement paste hydration. Percentages of each additive will replace the cement by volume to be studied at five ages. These percentages will be compared

40 CFR 63.1352 - Additional test methods.

Code of Federal Regulations, 2012 CFR

2012-07-01

... Standards for Hazardous Air Pollutants From the Portland Cement Manufacturing Industry Monitoring and... rates of emission of HCl from kilns and associated bypass stacks at portland cement manufacturing... specific organic HAP from raw material dryers, kilns and in-line kiln/raw mills at Portland cement...

40 CFR 63.1352 - Additional test methods.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Standards for Hazardous Air Pollutants From the Portland Cement Manufacturing Industry Monitoring and... rates of emission of HCl from kilns and associated bypass stacks at portland cement manufacturing... specific organic HAP from raw material dryers, kilns and in-line kiln/raw mills at Portland cement...

Heavy metal removal mechanisms of sorptive filter materials for road runoff treatment and remobilization under de-icing salt applications.

PubMed

Huber, Maximilian; Hilbig, Harald; Badenberg, Sophia C; Fassnacht, Julius; Drewes, Jörg E; Helmreich, Brigitte

2016-10-01

The objective of this research study was to elucidate the removal and remobilization behaviors of five heavy metals (i.e., Cd, Cu, Ni, Pb, and Zn) that had been fixed onto sorptive filter materials used in decentralized stormwater treatment systems receiving traffic area runoff. Six filter materials (i.e., granular activated carbon, a mixture of granular activated alumina and porous concrete, granular activated lignite, half-burnt dolomite, and two granular ferric hydroxides) were evaluated in column experiments. First, a simultaneous preloading with the heavy metals was performed for each filter material. Subsequently, the remobilization effect was tested by three de-icing salt experiments in duplicate using pure NaCl, a mixture of NaCl and CaCl2, and a mixture of NaCl and MgCl2. Three layers of each column were separated to specify the attenuation of heavy metals as a function of depth. Cu and Pb were retained best by most of the selected filter materials, and Cu was often released the least of all metals by the three de-icing salts. The mixture of NaCl and CaCl2 resulted in a stronger effect upon remobilization than the other two de-icing salts. For the material with the highest retention, the effect of the preloading level upon remobilization was measured. The removal mechanisms of all filter materials were determined by advanced laboratory methods. For example, the different intrusions of heavy metals into the particles were determined. Findings of this study can result in improved filter materials used in decentralized stormwater treatment systems. Copyright © 2016 Elsevier Ltd. All rights reserved.

Nonlinear softening of unconsolidated granular earth materials

NASA Astrophysics Data System (ADS)

Lieou, Charles K. C.; Daub, Eric G.; Guyer, Robert A.; Johnson, Paul A.

2017-09-01

Unconsolidated granular earth materials exhibit softening behavior due to external perturbations such as seismic waves, namely, the wave speed and elastic modulus decrease upon increasing the strain amplitude above dynamics strains of about 10-6 under near-surface conditions. In this letter, we describe a theoretical model for such behavior. The model is based on the idea that shear transformation zones—clusters of grains that are loose and susceptible to contact changes, particle displacement, and rearrangement—are responsible for plastic deformation and softening of the material. We apply the theory to experiments on simulated fault gouge composed of glass beads and demonstrate that the theory predicts nonlinear resonance shifts, reduction of the P wave modulus, and attenuation, in agreement with experiments. The theory thus offers insights on the nature of nonlinear elastic properties of a granular medium and potentially into phenomena such as triggering on earthquake faults.

A two-phase micromorphic model for compressible granular materials

NASA Astrophysics Data System (ADS)

Paolucci, Samuel; Li, Weiming; Powers, Joseph

2009-11-01

We introduce a new two-phase continuum model for compressible granular material based on micromorphic theory and treat it as a two-phase mixture with inner structure. By taking an appropriate number of moments of the local micro scale balance equations, the average phase balance equations result from a systematic averaging procedure. In addition to equations for mass, momentum and energy, the balance equations also include evolution equations for microinertia and microspin tensors. The latter equations combine to yield a general form of a compaction equation when the material is assumed to be isotropic. When non-linear and inertial effects are neglected, the generalized compaction equation reduces to that originally proposed by Bear and Nunziato. We use the generalized compaction equation to numerically model a mixture of granular high explosive and interstitial gas. One-dimensional shock tube and piston-driven solutions are presented and compared with experimental results and other known solutions.

Meso-scale framework for modeling granular material using computed tomography

DOE PAGES

Turner, Anne K.; Kim, Felix H.; Penumadu, Dayakar; ...

2016-03-17

Numerical modeling of unconsolidated granular materials is comprised of multiple nonlinear phenomena. Accurately capturing these phenomena, including grain deformation and intergranular forces depends on resolving contact regions several orders of magnitude smaller than the grain size. Here, we investigate a method for capturing the morphology of the individual particles using computed X-ray and neutron tomography, which allows for accurate characterization of the interaction between grains. The ability of these numerical approaches to determine stress concentrations at grain contacts is important in order to capture catastrophic splitting of individual grains, which has been shown to play a key role in themore » plastic behavior of the granular material on the continuum level. Discretization approaches, including mesh refinement and finite element type selection are presented to capture high stress concentrations at contact points between grains. The effect of a grain’s coordination number on the stress concentrations is also investigated.« less

Spreading granular material with a blade

NASA Astrophysics Data System (ADS)

Dressaire, Emilie; Singh, Vachitar; Grimaldi, Emma; Sauret, Alban

2015-11-01

The spreading of a complex fluid with a blade is encountered in applications that range from the bulldozing of granular material in construction projects to the coating of substrates with fluids in industrial applications. This spreading process is also present in everyday life, when we use a knife to turn a lump of peanut butter into a thin layer over our morning toast. In this study, we rely on granular media in a model experiment to describe the three-dimensional spreading of the material. Our experimental set-up allows tracking the spreading of a sandpile on a translating flat surface as the blade remains fixed. We characterize the spreading dynamics and the shape of the spread fluid layer when varying the tilt of the blade, its spacing with the surface and its speed. Our findings suggest that it is possible to tune the spreading parameters to optimize the coating.

Breakage mechanics for granular materials in surface-reactive environments

NASA Astrophysics Data System (ADS)

Zhang, Yida; Buscarnera, Giuseppe

2018-03-01

It is known that the crushing behaviour of granular materials is sensitive to the state of the fluids occupying the pore space. Here, a thermomechanical theory is developed to link such macroscopic observations with the physico-chemical processes operating at the microcracks of individual grains. The theory relies on the hypothesis that subcritical fracture propagation at intra-particle scale is the controlling mechanism for the rate-dependent, water-sensitive compression of granular specimens. First, the fracture of uniaxially compressed particles in surface-reactive environments is studied in light of irreversible thermodynamics. Such analysis recovers the Gibbs adsorption isotherm as a central component linking the reduction of the fracture toughness of a solid to the increase of vapour concentration. The same methodology is then extended to assemblies immersed in wet air, for which solid-fluid interfaces have been treated as a separate phase. It is shown that this choice brings the solid surface energy into the dissipation equations of the granular matrix, thus providing a pathway to (i) integrate the Gibbs isotherm with the continuum description of particle assemblies and (ii) reproduce the reduction of their yield strength in presence of high relative humidity. The rate-effects involved in the propagation of cracks and the evolution of breakage have been recovered by considering non-homogenous dissipation potentials associated with the creation of surface area at both scales. It is shown that the proposed model captures satisfactorily the compression response of different types of granular materials subjected to varying relative humidity. This result was achieved simply by using parameters based on the actual adsorption characteristics of the constituting minerals. The theory therefore provides a physically sound and thermodynamically consistent framework to study the behaviour of granular solids in surface-reactive environments.

Self-organized magnetic particles to tune the mechanical behavior of a granular system

NASA Astrophysics Data System (ADS)

Cox, Meredith; Wang, Dong; Barés, Jonathan; Behringer, Robert P.

2016-09-01

Above a certain density a granular material jams. This property can be controlled by either tuning a global property, such as the packing fraction or by applying shear strain, or at the micro-scale by tuning grain shape, inter-particle friction or externally controlled organization. Here, we introduce a novel way to change a local granular property by adding a weak anisotropic magnetic interaction between particles. We measure the evolution of the pressure, P, and coordination number, Z, for a packing of 2D photo-elastic disks, subject to uniaxial compression. A fraction R m of the particles have embedded cuboidal magnets. The strength of the magnetic interactions between particles is too weak to have a strong direct effect on P or Z when the system is jammed. However, the magnetic interactions play an important role in the evolution of latent force networks when systems containing a large enough fraction of the particles with magnets are driven through unjammed to jammed states. In this case, a statistically stable network of magnetic chains self-organizes before jamming and overlaps with force chains once jamming occurs, strengthening the granular medium. This property opens a novel way to control mechanical properties of granular materials.

Stationary bubble formation and cavity collapse in wedge-shaped hoppers

PubMed Central

Yagisawa, Yui; Then, Hui Zee; Okumura, Ko

2016-01-01

The hourglass is one of the apparatuses familiar to everyone, but reveals intriguing behaviors peculiar to granular materials, and many issues are remained to be explored. In this study, we examined the dynamics of falling sand in a special form of hourglass, i.e., a wedge-shaped hopper, when a suspended granular layer is stabilized to a certain degree. As a result, we found remarkably different dynamic regimes of bubbling and cavity. In the bubbling regime, bubbles of nearly equal size are created in the sand at a regular time interval. In the cavity regime, a cavity grows as sand beads fall before a sudden collapse of the cavity. Bubbling found here is quite visible to a level never discussed in the physics literature and the cavity regime is a novel phase, which is neither continuous, intermittent nor completely blocked phase. We elucidate the physical conditions necessary for the bubbling and cavity regimes and develop simple theories for the regimes to successfully explain the observed phenomena by considering the stability of a suspended granular layer and clogging of granular flow at the outlet of the hopper. The bubbling and cavity regimes could be useful for mixing a fluid with granular materials. PMID:27138747

Modelling polymeric deformable granular materials - from experimental data to numerical models at the grain scale

NASA Astrophysics Data System (ADS)

Teil, Maxime; Harthong, Barthélémy; Imbault, Didier; Peyroux, Robert

2017-06-01

Polymeric deformable granular materials are widely used in industry and the understanding and the modelling of their shaping process is a point of interest. This kind of materials often presents a viscoelasticplastic behaviour and the present study promotes a joint approach between numerical simulations and experiments in order to derive the behaviour law of such granular material. The experiment is conducted on a polystyrene powder on which a confining pressure of 7MPa and an axial pressure reaching 30MPa are applied. Between different steps of the in-situ test, the sample is scanned in an X-rays microtomograph in order to know the structure of the material depending on the density. From the tomographic images and by using specific algorithms to improve the images quality, grains are automatically identified, separated and a finite element mesh is generated. The long-term objective of this study is to derive a representative sample directly from the experiments in order to run numerical simulations using a viscoelactic or viscoelastic-plastic constitutive law and compare numerical and experimental results at the particle scale.

Granular compaction and the topology of pore deformation

NASA Astrophysics Data System (ADS)

Saadatfar, Mohammad; Takeuchi, Hiroshi; Hanifpour, Maryam; Robins, Vanessa; Francois, Nicolas; Hiraoka, Yasuaki

2017-06-01

The mechanism of crystallisation in highly dissipative materials such as foams or granular materials is still widely unknown. In macroscopic granular materials high levels of energy need to be injected to overcome the natural propensity of these dissipative materials to form amorphous structures [1, 2]. The transition from disordered to ordered packings in such systems triggers a wide range of geometrical, topological and mechanical changes at multi length scales [3]. Formation of cavities and patterns by aggregates of grains and their evolution during this transition requires a complete topological description of the system. Here, crystallisation of three-dimensional packings of frictional spheres is studied at the grain scale with x-ray tomography. Using a novel and powerful topological tool, Persistent Homology, we describe the complete formation process of perfect tetrahedral and octahedral patterns: the two building blocks of FCC and HCP crystalline arrangements. Additionally we present possible and allowable deformations of these components that accurately reproduce the main topological features of the system. These results give new insights into the crystallisation of these highly dissipative materials.

Shear flow of angular grains: acoustic effects and nonmonotonic rate dependence of volume.

PubMed

Lieou, Charles K C; Elbanna, Ahmed E; Langer, J S; Carlson, J M

2014-09-01

Naturally occurring granular materials often consist of angular particles whose shape and frictional characteristics may have important implications on macroscopic flow rheology. In this paper, we provide a theoretical account for the peculiar phenomenon of autoacoustic compaction-nonmonotonic variation of shear band volume with shear rate in angular particles-recently observed in experiments. Our approach is based on the notion that the volume of a granular material is determined by an effective-disorder temperature known as the compactivity. Noise sources in a driven granular material couple its various degrees of freedom and the environment, causing the flow of entropy between them. The grain-scale dynamics is described by the shear-transformation-zone theory of granular flow, which accounts for irreversible plastic deformation in terms of localized flow defects whose density is governed by the state of configurational disorder. To model the effects of grain shape and frictional characteristics, we propose an Ising-like internal variable to account for nearest-neighbor grain interlocking and geometric frustration and interpret the effect of friction as an acoustic noise strength. We show quantitative agreement between experimental measurements and theoretical predictions and propose additional experiments that provide stringent tests on the new theoretical elements.

Visualization of particle interactions in granular media.

PubMed

Meier, Holger A; Schlemmer, Michael; Wagner, Christian; Kerren, Andreas; Hagen, Hans; Kuhl, Ellen; Steinmann, Paul

2008-01-01

Interaction between particles in so-called granular media, such as soil and sand, plays an important role in the context of geomechanical phenomena and numerous industrial applications. A two scale homogenization approach based on a micro and a macro scale level is briefly introduced in this paper. Computation of granular material in such a way gives a deeper insight into the context of discontinuous materials and at the same time reduces the computational costs. However, the description and the understanding of the phenomena in granular materials are not yet satisfactory. A sophisticated problem-specific visualization technique would significantly help to illustrate failure phenomena on the microscopic level. As main contribution, we present a novel 2D approach for the visualization of simulation data, based on the above outlined homogenization technique. Our visualization tool supports visualization on micro scale level as well as on macro scale level. The tool shows both aspects closely arranged in form of multiple coordinated views to give users the possibility to analyze the particle behavior effectively. A novel type of interactive rose diagrams was developed to represent the dynamic contact networks on the micro scale level in a condensed and efficient way.

Low-resistive vibratory penetration in granular media.

PubMed

Darbois Texier, Baptiste; Ibarra, Alejandro; Melo, Francisco

2017-01-01

Non-cohesive materials such as sand, dry snow or cereals are encountered in various common circumstances, from everyday situations to industry. The process of digging into these materials remains a challenge to most animals and machines. Within the animal kingdom, different strategies are employed to overcome this issue, including excavation methods used by ants, the two-anchor strategy employed by soft burrowers such as razor-clams, and undulatory motions exhibited by sandfish lizards. Despite the development of technology to mimic these techniques in diggers and robots, the limitations of animals and machines may differ, and mimicry of natural processes is not necessarily the most efficient technological strategy. This study presents evidence that the resisting force for the penetration of an intruder into a dry granular media can be reduced by one order of magnitude with small amplitude (A ≃ 10 μm) and low frequency (f = 50 - 200 Hz) mechanical vibrations. This observed result is attributed to the local fluidization of the granular bed which induces the rupture of force chains. The drop in resistive force on entering dry granular materials may be relevant in technological development in order to increase the efficiency of diggers and robots.

Granular material flow in two-dimensional hoppers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brennen, C.; Pearce, J.C.

To aid in improving the transport of granular media for industrial purposes, the California Institute of Technology presents a comparison of experimental data with analytical results for the flow of dry granular media (such as coal) through a two-dimensional or wedge-shaped hopper. The analytical solution, which is based on the constitutive postulates (suggested by A.W. Jenike and R.T. Shield) of intergrain Coulomb friction and isotropy, produces results that are in good agreement with the experimental measurements.

In situ grain fracture mechanics during uniaxial compaction of granular solids

NASA Astrophysics Data System (ADS)

Hurley, R. C.; Lind, J.; Pagan, D. C.; Akin, M. C.; Herbold, E. B.

2018-03-01

Grain fracture and crushing are known to influence the macroscopic mechanical behavior of granular materials and be influenced by factors such as grain composition, morphology, and microstructure. In this paper, we investigate grain fracture and crushing by combining synchrotron x-ray computed tomography and three-dimensional x-ray diffraction to study two granular samples undergoing uniaxial compaction. Our measurements provide details of grain kinematics, contacts, average intra-granular stresses, inter-particle forces, and intra-grain crystal and fracture plane orientations. Our analyses elucidate the complex nature of fracture and crushing, showing that: (1) the average stress states of grains prior to fracture vary widely in their relation to global and local trends; (2) fractured grains experience inter-particle forces and stored energies that are statistically higher than intact grains prior to fracture; (3) fracture plane orientations are primarily controlled by average intra-granular stress and contact fabric rather than the orientation of the crystal lattice; (4) the creation of new surfaces during fracture accounts for a very small portion of the energy dissipated during compaction; (5) mixing brittle and ductile grain materials alters the grain-scale fracture response. The results highlight an application of combined x-ray measurements for non-destructive in situ analysis of granular solids and provide details about grain fracture that have important implications for theory and modeling.

Development of bioconcrete material using an enrichment culture of novel thermophilic anaerobic bacteria.

PubMed

Ghosh, P; Mandal, S; Pal, S; Bandyopadhyaya, G; Chattopadhyay, B D

2006-04-01

In the biosphere, bacteria can function as geo-chemical agents, promoting the dispersion, fractionation and/or concentration of materials. Microbial mineral precipitation is resulted from metabolic activities of microorganisms. Based on this biomineralogy concept, an attempt has been made to develop bioconcrete material incorporating of an enrichment culture of thermophilic and anaerobic bacteria within cement-sand mortar/concrete. The results showed a significant increase in compressive strength of both cement-sand mortar and concrete due to the development of filler material within the pores of cement sand matrix. Maximum strength was observed at concentration 10(5)cell/ml of water used in mortar/concrete. Addition of Escherichia coil or media composition on mortar showed no such improvement in strength.

The use of shale ash in dry mix construction materials

NASA Astrophysics Data System (ADS)

Gulbe, L.; Setina, J.; Juhnevica, I.

2017-10-01

The research was made to determine the use of shale ash usage in dry mix construction materials by replacing part of cement amount. Cement mortar ZM produced by SIA Sakret and two types of shale ashes from Narva Power plant (cyclone ash and electrostatic precipitator ash) were used. Fresh mortar properties, hardened mortar bulk density, thermal conductivity (λ10, dry) (table value) were tested in mortar ZM samples and mortar samples in which 20% of the amount of cement was replaced by ash. Compressive strenght, frost resistance and resistance to sulphate salt solutions were checked. It was stated that the use of electrostatic precipitator ash had a little change of the material properties, but the cyclone ash significantly reduced the mechanical strength of the material.

The self-propulsion of a helix in granular matter

NASA Astrophysics Data System (ADS)

Valdes, Rogelio; Angeles, Veronica; de La Calleja, Elsa; Zenit, Roberto

2017-11-01

The effect of the shape of helicoidal on the displacement of magnetic robots in granular media is studied experimentally. We quantify the influences of three main parameters of the shape of the helicoidal swimmers: body diameter, step, and the angle. We compare the experimental measurements with an empirically modified resistive force theory prediction that accounts for the static friction coefficient of the particles of the granular material, leading to good agreement. Comparisons are also made with the granular resistive force theory proposed by Goldman and collaborators. We found an optimal helix angle to produce movement and determined a relationship between the swimmer size and speed.

Drag force scaling for penetration into granular media.

PubMed

Katsuragi, Hiroaki; Durian, Douglas J

2013-05-01

Impact dynamics is measured for spherical and cylindrical projectiles of many different densities dropped onto a variety non-cohesive granular media. The results are analyzed in terms of the material-dependent scaling of the inertial and frictional drag contributions to the total stopping force. The inertial drag force scales similar to that in fluids, except that it depends on the internal friction coefficient. The frictional drag force scales as the square-root of the density of granular medium and projectile, and hence cannot be explained by the combination of granular hydrostatic pressure and Coulomb friction law. The combined results provide an explanation for the previously observed penetration depth scaling.

In Vivo Osteogenic Potential of Biomimetic Hydroxyapatite/Collagen Microspheres: Comparison with Injectable Cement Pastes

PubMed Central

Manzanares, Maria-Cristina; Ginebra, Maria-Pau; Franch, Jordi

2015-01-01

The osteogenic capacity of biomimetic calcium deficient hydroxyapatite microspheres with and without collagen obtained by emulsification of a calcium phosphate cement paste has been evaluated in an in vivo model, and compared with an injectable calcium phosphate cement with the same composition. The materials were implanted into a 5 mm defect in the femur condyle of rabbits, and bone formation was assessed after 1 and 3 months. The histological analysis revealed that the cements presented cellular activity only in the margins of the material, whereas each one of the individual microspheres was covered with osteogenic cells. Consequently, bone ingrowth was enhanced by the microspheres, with a tenfold increase compared to the cement, which was associated to the higher accessibility for the cells provided by the macroporous network between the microspheres, and the larger surface area available for osteoconduction. No significant differences were found in terms of bone formation associated with the presence of collagen in the materials, although a more extensive erosion of the collagen-containing microspheres was observed. PMID:26132468

Carbon Nanofiber Cement Sensors to Detect Strain and Damage of Concrete Specimens Under Compression.

PubMed

Galao, Oscar; Baeza, F Javier; Zornoza, Emilio; Garcés, Pedro

2017-11-24

Cement composites with nano-additions have been vastly studied for their functional applications, such as strain and damage sensing. The capacity of a carbon nanofiber (CNF) cement paste has already been tested. However, this study is focused on the use of CNF cement composites as sensors in regular concrete samples. Different measuring techniques and humidity conditions of CNF samples were tested to optimize the strain and damage sensing of this material. In the strain sensing tests (for compressive stresses up to 10 MPa), the response depends on the maximum stress applied. The material was more sensitive at higher loads. Furthermore, the actual load time history did not influence the electrical response, and similar curves were obtained for different test configurations. On the other hand, damage sensing tests proved the capability of CNF cement composites to measure the strain level of concrete samples, even for loads close to the material's strength. Some problems were detected in the strain transmission between sensor and concrete specimens, which will require specific calibration of each sensor one attached to the structure.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kara, Mustafa, E-mail: mustafa.kara@mam.gov.t; Guenay, Esin; Tabak, Yasemin

Municipal solid waste (MSW) is one of the most important environmental problems arising from rapid urbanization and industrialization. The use of alternative fuels in rotary kilns of cement plants is very important for reducing cost, saving fossil fuels and also eliminating waste materials, accumulated during production or after using these materials. Cement industries has an important potential for supplying preferable solutions to the waste management. Energy recovery from waste is also important for the reduction of CO{sub 2} emissions. This paper presents an investigation of the development of refuse derived fuel (RDF) materials from non-recycling wastes and the determination ofmore » its potential use as an alternative fuel in cement production in Istanbul, Turkey. RDF produced from MSW was analyzed and its effects on cement production process were examined. For this purpose, the produced RDF was mixed with the main fuel (LPG) in ratios of 0%, 5%, 10%, 15% and 20%. Then chemical and mineralogical analyses of the produced clinker were carried out. It is believed that successful results of this study will be a good example for municipalities and cement industries in order to achieve both economic and environmental benefits.« less

Numerical insight into the micromechanics of jet erosion of a cohesive granular material

NASA Astrophysics Data System (ADS)

Cuéllar, Pablo; Benseghier, Zeyd; Luu, Li-Hua; Bonelli, Stéphane; Delenne, Jean-Yves; Radjaï, Farhang; Philippe, Pierre

2017-06-01

Here we investigate the physical mechanisms behind the surface erosion of a cohesive granular soil induced by an impinging jet by means of numerical simulations coupling fluid and grains at the microscale. The 2D numerical model combines the Discrete Element and Lattice Boltzmann methods (DEM-LBM) and accounts for the granular cohesion with a contact model featuring a paraboloidal yield surface. Here we review first the hydrodynamical conditions imposed by the fluid jet on a solid granular packing, turning then the attention to the impact of cohesion on the erosion kinetics. Finally, the use of an additional subcritical debonding damage model based on the work of Silvani and co-workers provides a novel insight into the internal solicitation of the cohesive granular sample by the impinging jet.

Sealing ability of cermet ionomer cement as a retrograde filling material.

PubMed

Aktener, B O; Pehlivan, Y

1993-03-01

An in vitro dye leakage study was performed to compare the sealing ability of high copper amalgam with cavity varnish and cermet ionomer cement with and without varnish when used as retrofilling materials. The root canals of 54 maxillary anterior teeth were instrumented and obturated with gutta-percha and sealer. The apical 3 mm of the roots were resected and apical class I cavity preparations were made. The roots were then randomly divided into three groups and retrofilled with one of the experimental materials. After 72 h of immersion in India ink, the roots were cleared and evaluated for leakage with a stereomicroscope. Statistical analysis indicated that the cermet ionomer cement with varnish group had significantly less leakage than the amalgam group (P < 0.0014) and the cermet ionomer cement without varnish group (P < 0.001). There was no significant difference between the other two groups (P > 0.05).

Nano-Inclusions Applied in Cement-Matrix Composites: A Review

PubMed Central

Bastos, Guillermo; Patiño-Barbeito, Faustino; Patiño-Cambeiro, Faustino; Armesto, Julia

2016-01-01

Research on cement-based materials is trying to exploit the synergies that nanomaterials can provide. This paper describes the findings reported in the last decade on the improvement of these materials regarding, on the one hand, their mechanical performance and, on the other hand, the new properties they provide. These features are mainly based on the electrical and chemical characteristics of nanomaterials, thus allowing cement-based elements to acquire “smart” functions. In this paper, we provide a quantitative approach to the reinforcements achieved to date. The fundamental concepts of nanoscience are introduced and the need of both sophisticated devices to identify nanostructures and techniques to disperse nanomaterials in the cement paste are also highlighted. Promising results have been obtained, but, in order to turn these advances into commercial products, technical, social and standardisation barriers should be overcome. From the results collected, it can be deduced that nanomaterials are able to reduce the consumption of cement because of their reinforcing effect, as well as to convert cement-based products into electric/thermal sensors or crack repairing materials. The main obstacle to foster the implementation of such applications worldwide is the high cost of their synthesis and dispersion techniques, especially for carbon nanotubes and graphene oxide. PMID:28774135

Hall versus conventional stainless steel crown techniques: in vitro investigation of marginal fit and microleakage using three different luting agents.

PubMed

Erdemci, Zeynep Yalçınkaya; Cehreli, S Burçak; Tirali, R Ebru

2014-01-01

This study's purpose was to investigate microleakage and marginal discrepancies in stainless steel crowns (SSCs) placed using conventional and Hall techniques and cemented with three different luting agents. Seventy-eight human primary maxillary second molars were randomly assigned to two groups (N=39), and SSCs were applied either with the Hall or conventional technique. These two groups were further subgrouped according to the material used for crown cementation (N=13 per group). Two specimens in each group were processed for scanning electron microscopy investigation. The extent of microleakage and marginal fit was quantified in millimeters on digitally photographed sections using image analysis software. The data were compared with a two-way independent and a two-way mixed analysis of variance (P=.05). The scores in the Hall group were significantly worse than those in the conventional technique group (P<.05). In both groups, resin cement displayed the lowest extent of microleakage, followed by glass ionomer and polycarboxylate cements (P<.05). Stainless steel crowns applied using the Hall technique displayed higher microleakage scores than those applied using the conventional technique, regardless of the cementation material. When the interaction of the material and technique was assessed, resin cement presented as the best choice for minimizing microleakage in both techniques.

Interactions between chloride and cement-paste materials.

PubMed

Barberon, Fabien; Baroghel-Bouny, Véronique; Zanni, Hélène; Bresson, Bruno; d'Espinose de la Caillerie, Jean-Baptiste; Malosse, Lucie; Gan, Zehong

2005-02-01

The durability of cement-based materials with respect to exterior aggressions is one of the current priorities in civil engineering. Depending on their use, the cement-based materials can be exposed to different types of aggressive environments. For instance, damages to concrete structures in contact with a saline environment (sea water on bridges, deicing salts on roads, etc.) are of utmost importance. Upon exposure to saline water, Cl- ions penetrate into the structures and subsequently lead to reinforcement corrosion. Chloride attack is often combined with other aggressive influences such as temperature (e.g., freezing) or the ingress of other ions (e.g., sulfates in sea water). We therefore aim to explore the effect of sodium chloride (NaCl) on the structural chemistry of cement paste. Existing studies about reinforcement corrosion by chloride have focused on the penetration of Cl- ions and the comparison between "free" ions (water-soluble ions) and bound ones. However, little is known about the fixation mechanisms, the localization of Cl in the cement matrix and the structural interaction between Cl and the silicate and aluminate hydrate phases present in cement paste. We present here results of a multinuclear nuclear magnetic resonance study on the fixation of chloride in the hydration products and the characterization of new phases potentially appearing due to chloride ingress.

Traction test of temporary dental cements

PubMed Central

Millan-Martínez, Diego; Fons-Font, Antonio; Agustín-Panadero, Rubén; Fernández-Estevan, Lucía

2017-01-01

Background Classic self-curing temporary cements obstruct the translucence of provisional restorations. New dual-cure esthetic temporary cements need investigation and comparison with classic cements to ensure that they are equally retentive and provide adequate translucence. The objective is to analyze by means of traction testing in a in vitro study the retention of five temporary cements. Material and Methods Ten molars were prepared and ten provisional resin restorations were fabricated using CAD-CAM technology (n=10). Five temporary cements were selected: self-curing temporary cements, Dycal (D), Temp Bond (TB), Temp Bond Non Eugenol (TBNE); dual-curing esthetic cements Temp Bond Clear (TBC) and Telio CS link (TE). Each sample underwent traction testing, both with thermocycling (190 cycles at 5-55º) and without thermocycling. Results TE and TBC obtained the highest traction resistance values. Thermocycling reduced the resistance of all cements except TBC. Conclusions The dual-cure esthetic cements tested provided optimum outcomes for bonding provisional restorations. Key words:Temporary dental cements, cements resistance. PMID:28469824

Osteogenesis and angiogenesis properties of dental pulp cell on novel injectable tricalcium phosphate cement by silica doped.

PubMed

Su, Ying-Fang; Lin, Chi-Chang; Huang, Tsui-Hsien; Chou, Ming-Yung; Yang, Jaw-Ji; Shie, Ming-You

2014-09-01

β-Tricalcium phosphate (β-TCP) is an osteoconductive material in clinical. In this study, we have doped silica (Si) into β-TCP and enhanced its bioactive and osteostimulative properties. To check its effectiveness, a series of Si-doped with different ratios were prepared to make new bioactive and biodegradable biocomposites for bone repair. Formation of the diametral tensile strength, ions released and weight loss of cements was considered after immersion. In addition, we also examined the behavior of human dental pulp cells (hDPCs) cultured on Si-doped β-TCP cements. The results showed that setting time and injectability of the Si-doped β-TCP cements were decreased as the Si content was increased. At the end of the immersion point, weight losses of 30.1%, 36.9%, 48.1%, and 55.3% were observed for the cement doping 0%, 10%, 20%, and 30% Si into β-TCP cements, respectively. In vitro cell experiments show that the Si-rich cements promote human dental pulp cell (hDPC) proliferation and differentiation. However, when the Si-doped in the cement is more than 20%, the amount of cells and osteogenesis protein of hDPCs was stimulated by Si released from Si-doped β-TCP cements. The degradation of β-TCP and osteogenesis of Si gives a strong reason to believe that these Si-doped β-TCP cements may prove to be promising bone repair materials. Copyright © 2014 Elsevier B.V. All rights reserved.

Micro- and nano-scale characterization to study the thermal degradation of cement-based materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lim, Seungmin, E-mail: lim76@illinois.edu; Mondal, Paramita

2014-06-01

The degradation of hydration products of cement is known to cause changes in the micro- and nano-structure, which ultimately drive thermo-mechanical degradation of cement-based composite materials at elevated temperatures. However, a detailed characterization of these changes is still incomplete. This paper presents results of an extensive experimental study carried out to investigate micro- and nano-structural changes that occur due to exposure of cement paste to high temperatures. Following heat treatment of cement paste up to 1000 °C, damage states were studied by compressive strength test, thermogravimetric analysis (TGA), scanning electron microscopy (SEM) atomic force microscopy (AFM) and AFM image analysis.more » Using experimental results and research from existing literature, new degradation processes that drive the loss of mechanical properties of cement paste are proposed. The development of micro-cracks at the interface between unhydrated cement particles and paste matrix, a change in C–S–H nano-structure and shrinkage of C–S–H, are considered as important factors that cause the thermal degradation of cement paste. - Highlights: • The thermal degradation of hydration products of cement is characterized at micro- and nano-scale using scanning electron microscopy (SEM) and atomic force microscopy (AFM). • The interface between unhydrated cement particles and the paste matrix is considered the origin of micro-cracks. • When cement paste is exposed to temperatures above 300 ºC, the nano-structure of C-S-H becomes a more loosely packed globular structure, which could be indicative of C-S-H shrinkage.« less

Influence of curing protocol and ceramic composition on the degree of conversion of resin cement

PubMed Central

Lanza, Marcos Daniel Septimio; Andreeta, Marcello Rubens Barsi; Pegoraro, Thiago Amadei; Pegoraro, Luiz Fernando; Carvalho, Ricardo Marins De

2017-01-01

Abstract Due to increasing of aesthetic demand, ceramic crowns are widely used in different situations. However, to obtain long-term prognosis of restorations, a good conversion of resin cement is necessary. Objective: To evaluate the degree of conversion (DC) of one light-cure and two dual-cure resin cements under a simulated clinical cementation of ceramic crowns. Material and Methods: Prepared teeth were randomly split according to the ceramic's material, resin cement and curing protocol. The crowns were cemented as per manufacturer's directions and photoactivated either from occlusal suface only for 60 s; or from the buccal, occlusal and lingual surfaces, with an exposure time of 20 s on each aspect. After cementation, the specimens were stored in deionized water at 37°C for 7 days. Specimens were transversally sectioned from occlusal to cervical surfaces and the DC was determined along the cement line with three measurements taken and averaged from the buccal, lingual and approximal aspects using micro-Raman spectroscopy (Alpha 300R/WITec®). Data were analyzed by 3-way ANOVA and Tukey test at =5%. Results: Statistical analysis showed significant differences among cements, curing protocols and ceramic type (p<0.001). The curing protocol 3x20 resulted in higher DC for all tested conditions; lower DC was observed for Zr ceramic crowns; Duolink resin cement culminated in higher DC regardless ceramic composition and curing protocol. Conclusion: The DC of resin cement layers was dependent on the curing protocol and type of ceramic. PMID:29211292

ULTRASTRUCTURE OF THE NUCLEOLUS DURING THE CHINESE HAMSTER CELL CYCLE

PubMed Central

Noel, J. S.; Dewey, W. C.; Abel, J. H.; Thompson, R. P.

1971-01-01

Changes in the structure of the nucleolus during the cell cycle of the Chinese hamster cell in vitro were studied. Quantitative electron microscopic techniques were used to establish the size and volume changes in nucleolar structures. In mitosis, nucleolar remnants, "persistent nucleoli," consisting predominantly of ribosome-like granular material, and a granular coating on the chromosomes were observed. Persistent nucleoli were also observed in some daughter nuclei as they were leaving telophase and entering G1. During very early G1, a dense, fibrous material characteristic of interphase nucleoli was noted in the nucleoplasm of the cells. As the cells progressed through G1, a granular component appeared which was intimately associated with the fibrous material. By the middle of G1, complete, mature nucleoli were present. The nucleolar volume enlarged by a factor of two from the beginning of G1 to the middle of S primarily due to the accumulation of the granular component. During the G2 period, there was a dissolution or breakdown of the nucleolus prior to the entry of the cells into mitosis. Correlations between the quantitative aspects of this study and biochemical and cytochemical data available in the literature suggest the following: nucleolar reformation following division results from the activation of the nucleolar organizer regions which transcribe for RNA first appearing in association with protein as a fibrous component (45S RNA) and then later as a granular component (28S and 32S RNA). PMID:4933472

Micro- and macroscale coefficients of friction of cementitious materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lomboy, Gilson; Sundararajan, Sriram, E-mail: srirams@iastate.edu; Wang, Kejin

2013-12-15

Millions of metric tons of cementitious materials are produced, transported and used in construction each year. The ease or difficulty of handling cementitious materials is greatly influenced by the material friction properties. In the present study, the coefficients of friction of cementitious materials were measured at the microscale and macroscale. The materials tested were commercially-available Portland cement, Class C fly ash, and ground granulated blast furnace slag. At the microscale, the coefficient of friction was determined from the interaction forces between cementitious particles using an Atomic Force Microscope. At the macroscale, the coefficient of friction was determined from stresses onmore » bulk cementitious materials under direct shear. The study indicated that the microscale coefficient of friction ranged from 0.020 to 0.059, and the macroscale coefficient of friction ranged from 0.56 to 0.75. The fly ash studied had the highest microscale coefficient of friction and the lowest macroscale coefficient of friction. -- Highlights: •Microscale (interparticle) coefficient of friction (COF) was determined with AFM. •Macroscale (bulk) COF was measured under direct shear. •Fly ash had the highest microscale COF and the lowest macroscale COF. •Portland cement against GGBFS had the lowest microscale COF. •Portland cement against Portland cement had the highest macroscale COF.« less

Mineral of the month: cement

USGS Publications Warehouse

van Oss, Hendrik G.

2006-01-01

Hydraulic cement is a virtually ubiquitous construction material that, when mixed with water, serves as the binder in concrete and most mortars. Only about 13 percent of concrete by weight is cement (the rest being water and aggregates), but the cement contributes all of the concrete’s compressional strength. The term “hydraulic” refers to the cement’s ability to set and harden underwater through the hydration of the cement’s components.

A new polymer nanocomposite repair material for restoring wellbore seal integrity

DOE PAGES

Genedy, Moneeb; Kandil, Usama F.; Matteo, Edward N.; ...

2017-03-01

Seal integrity of functional oil wells and abandoned wellbores used for CO 2 subsequent storage has become of significant interest with the oil and gas leaks worldwide. This is attributed to the fact that wellbores intersecting geographical formations contain potential leakage pathways. One of the critical leakage pathways is the cement-shale interface. In this study, we examine the efficiency of a new polymer nanocomposite repair material that can be injected for sealing micro annulus in wellbores. The bond strength and microstructure of the interface of Type G oil well cement (reference), microfine cement, Novolac epoxy incorporating Neat, 0.25%, 0.5%, andmore » 1.0% Aluminum Nanoparticles (ANPs) with shale is investigated. Interfacial bond strength testing shows that injected microfine cement repair has considerably low bond strength, while ANPs-epoxy nanocomposites have a bond strength that is an order of magnitude higher than cement. Microscopic investigations of the interface show that micro annulus interfacial cracks with widths up to 40 μm were observed at the cement-shale interface while these cracks were absent at the cement-epoxy-shale interface. Finally, Fourier Transform Infrared and Dynamic mechanical analysis measurements showed that ANPs improve interfacial bond by limiting epoxy crosslinking, and therefore allowing epoxy to form robust bonds with cement and shale.« less

A New Biphasic Dicalcium Silicate Bone Cement Implant

PubMed Central

Murciano, Angel; Maté-Sánchez de Val, José E.

2017-01-01

This study aimed to investigate the processing parameters and biocompatibility of a novel biphasic dicalcium silicate (C2S) cement. Biphasic α´L + β-C2Sss was synthesized by solid-state processing, and was used as a raw material to prepare the cement. In vitro bioactivity and biocompatibility studies were assessed by soaking the cement samples in simulated body fluid (SBF) and human adipose stem cell cultures. Two critical-sized defects of 6 mm Ø were created in 15 NZ tibias. A porous cement made of the high temperature forms of C2S, with a low phosphorous substitution level, was produced. An apatite-like layer covered the cement’s surface after soaking in SBF. The cell attachment test showed that α´L + β-C2Sss supported cells sticking and spreading after 24 h of culture. The cement paste (55.86 ± 0.23) obtained higher bone-to-implant contact (BIC) percentage values (better quality, closer contact) in the histomorphometric analysis, and defect closure was significant compared to the control group (plastic). The residual material volume of the porous cement was 35.42 ± 2.08% of the initial value. The highest BIC and bone formation percentages were obtained on day 60. These results suggest that the cement paste is advantageous for initial bone regeneration. PMID:28773119

Portland cement hydration and early setting of cement stone intended for efficient paving materials

NASA Astrophysics Data System (ADS)

Grishina, A.

2017-10-01

Due to the growth of load on automotive roads, modern transportation engineering is in need of efficient paving materials. Runways and most advanced highways require Portland cement concretes. This makes important the studies directed to improvement of binders for such concretes. In the present work some peculiarities of the process of Portland cement hydration and early setting of cement stone with barium hydrosilicate sol were examined. It was found that the admixture of said sol leads to a shift in the induction period to later times without significant change in its duration. The admixture of a modifier with nanoscale barium hydrosilicates increases the degree of hydration of the cement clinker minerals and changes the phase composition of the hydration products; in particular, the content of portlandite and tricalcium silicate decreases, while the amount of ettringite increases. Changes in the hydration processes of Portland cement and early setting of cement stone that are caused by the nanoscale barium hydrosilicates, allow to forecast positive technological effects both at the stage of manufacturing and at the stage of operation. In particular, the formwork age can be reduced, turnover of molds can be increased, formation of secondary ettringite and corrosion of the first type can be eliminated.

Investigating the Influence of Waste Basalt Powder on Selected Properties of Cement Paste and Mortar

NASA Astrophysics Data System (ADS)

Dobiszewska, Magdalena; Beycioğlu, Ahmet

2017-10-01

Concrete is the most widely used man-made construction material in civil engineering applications. The consumption of cement and thus concrete, increases day by day along with the growth of urbanization and industrialization and due to new developments in construction technologies, population growing, increasing of living standard. Concrete production consumes much energy and large amounts of natural resources. It causes environmental, energy and economic losses. The most important material in concrete production is cement. Cement industry contributes to production of about 7% of all CO2 generated in the world. Every ton of cement production releases nearly one ton of CO2 to atmosphere. Thus the concrete and cement industry changes the environment appearance and influences it very much. Therefore, it has become very important for construction industry to focus on minimizing the environmental impact, reducing energy consumption and limiting CO2 emission. The need to meet these challenges has spurred an interest in the development of a blended Portland cement in which the amount of clinker is reduced and partially replaced with mineral additives - supplementary cementitious materials (SCMs). Many researchers have studied the possibility of using another mineral powder in mortar and concrete production. The addition of marble dust, basalt powder, granite or limestone powder positively affects some properties of cement mortar and concrete. This paper presents an experimental study on the properties of cement paste and mortar containing basalt powder. The basalt powder is a waste emerged from the preparation of aggregate used in asphalt mixture production. Previous studies have shown that analysed waste used as a fine aggregate replacement, has a beneficial effect on some properties of mortar and concrete, i.e. compressive strength, flexural strength and freeze resistance also. The present study shows the results of the research concerning the modification of cement paste and mortar with basalt powder. The modification consists in that the powder waste was added as partial replacement of cement. Four types of common cement were examined, i.e. CEM I, CEM II/A-S, CEM II/A-V and CEM II/B-V. The percentages of basalt powder in this research are 0%, 1%, 2%, 3%, 4%, 6%, 8% and 10% by mass. Results showed that the addition of basalt powder improved the strength of cement mortar. The use of mineral powder as the partial substitution of cement allows the effective management of industrial waste and improves some properties of cement mortar.

Calcium silicate-based cements and functional impacts of various constituents

PubMed Central

SAGHIRI, Mohammad Ali; ORANGI, Jafar; ASATOURIAN, Armen; GUTMANN, James L.; Garcia-Godoy, Franklin; LOTFI, Mehrdad; SHEIBANI, Nader

2016-01-01

Calcium silicate-based cements have superior sealing ability, bioactivity, and marginal adaptation, which make them suitable for different dental treatment applications. However, they exhibit some drawbacks such as long setting time and poor handling characteristics. To overcome these limitations calcium silicates are engineered with various constituents to improve specific characteristics of the base material, and are the focus of this review. An electronic search of the PubMed, MEDLINE, and EMBASE via OVID databases using appropriate terms and keywords related to the use, application, and properties of calcium silicate-based cements was conducted. Two independent reviewers obtained and analyzed the full texts of the selected articles. Although the effects of various constituents and additives to the base Portland cement-like materials have been investigated, there is no one particular ingredient that stands out as being most important. Applying nanotechnology and new synthesis methods for powders most positively affected the cement properties. PMID:27773894

Environmental Assessment of Different Cement Manufacturing Processes Based on Emergy and Ecological Footprint Analysis

EPA Science Inventory

Due to its high environmental impact and energy intensive production, the cement industry needs to adopt more energy efficient technologies to reduce its demand for fossil fuels and impact on the environment. Bearing in mind that cement is the most widely used material for housin...

Adsorption of Methyl Tertiary Butyl Ether on Granular Zeolites: Batch and Column Studies

PubMed Central

Abu-Lail, Laila; Bergendahl, John A.; Thompson, Robert W.

2010-01-01

Methyl tertiary butyl ether (MTBE) has been shown to be readily removed from water with powdered zeolites, but the passage of water through fixed beds of very small powdered zeolites produces high friction losses not encountered in flow through larger sized granular materials. In this study, equilibrium and kinetic adsorption of MTBE onto granular zeolites, a coconut shell granular activated carbon (CS-1240), and a commercial carbon adsorbent (CCA) sample was evaluated. In addition, the effect of natural organic matter (NOM) on MTBE adsorption was evaluated. Batch adsorption experiments determined that ZSM-5 was the most effective granular zeolite for MTBE adsorption. Further equilibrium and kinetic experiments verified that granular ZSM-5 is superior to CS-1240 and CCA in removing MTBE from water. No competitive-adsorption effects between NOM and MTBE were observed for adsorption to granular ZSM-5 or CS-1240, however there was competition between NOM and MTBE for adsorption onto the CCA granules. Fixed-bed adsorption experiments for longer run times were performed using granular ZSM-5. The bed depth service time model (BDST) was used to analyze the breakthrough data. PMID:20153106

Bone regeneration capacity of magnesium phosphate cements in a large animal model.

PubMed

Kanter, Britta; Vikman, Anna; Brückner, Theresa; Schamel, Martha; Gbureck, Uwe; Ignatius, Anita

2018-03-15

Magnesium phosphate minerals have captured increasing attention during the past years as suitable alternatives for calcium phosphate bone replacement materials. Here, we investigated the degradation and bone regeneration capacity of experimental struvite (MgNH 4 PO 4 ·6H 2 O) forming magnesium phosphate cements in two different orthotopic ovine implantation models. Cements formed at powder to liquid ratios (PLR) of 2.0 and 3.0 g ml -1 were implanted into trabecular bone using a non-load-bearing femoral drill-hole model and a load-bearing tibial defect model. After 4, 7 and 10 months the implants were retrieved and cement degradation and new bone formation was analyzed by micro-computed tomography (µCT) and histomorphometry. The results showed cement degradation in concert with new bone formation at both defect locations. Both cements were almost completely degraded after 10 months. The struvite cement formed with a PLR of 2.0 g ml -1 exhibited a slightly accelerated degradation kinetics compared to the cement with a PLR of 3.0 g ml -1 . Tartrat-resistant acid phosphatase (TRAP) staining indicated osteoclastic resorption at the cement surface. Energy dispersive X-ray analysis (EDX) revealed that small residual cement particles were mostly accumulated in the bone marrow in between newly formed bone trabeculae. Mechanical loading did not significantly increase bone formation associated with cement degradation. Concluding, struvite-forming cements might be promising bone replacement materials due to their good degradation which is coupled with new bone formation. Recently, the interest in magnesium phosphate cements (MPC) for bone substitution increased, as they exhibit high initial strength, comparably elevated degradation potential and the release of valuable magnesium ions. However, only few in vivo studies, mostly including non-load-bearing defects in small animals, have been performed to analyze the degradation and regeneration capability of MPC derived compounds. The present study examined the in vivo behavior of magnesiumammoniumphosphate hexahydrate (struvite) implants with different porosity in both mechanically loaded and non-loaded defects of merino sheep. For the first time, the effect of mechanical stimuli on the biological outcome of this clinically relevant replacement material is shown and directly compared to the conventional unloaded defect situation in a large animal model. Copyright © 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

The Microstructural Response of Granular Soil Under Uniaxial Strain

DTIC Science & Technology

1993-10-01

under uniaxial strains of up to 10 percent. The material tested was a poorly graded ottowa sand with specimens consisting of either 0.5- or 0.75-mm...microstructural effects in granular material under uniaxial strain of up to 10.0 percent. The relative influence of several microstructural effects (such as...uniaxial strain. The confinement vessel consisted of a base plate, four walls, and a loading cap. The sidewalls extended up beyond the specimen and served

Solvent extraction of diatomite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Williams, W.

1984-07-24

There is provided a method of extracting hydrocarbons from a diatomite ore. The particle size of the ore is first reduced to form a processed ore. The processed ore is then mixed with a substantially irregular granular material to form an unstratified ore mixture having increased permeability to an extracting solvent. The unstratified ore mixture is then permeated with an extracting solvent to obtain a hydrocarbon-solvent stream from which hydrocarbons are subsequently separated. The irregular granular material may be sand.

Mechanics of Granular Materials (MGM) Flight Hardware

NASA Technical Reports Server (NTRS)

1997-01-01

A test cell for the Mechanics of Granular Materials (MGM) experiment is shown in its on-orbit configuration in Spacehab during preparations for STS-89. The twin locker to the left contains the hydraulic system to operate the experiment. Sand and soil grains have faces that can cause friction as they roll and slide against each other, or even cause sticking and form small voids between grains. This complex behavior can cause soil to behave like a liquid under certain conditions such as earthquakes or when powders are handled in industrial processes. Mechanics of Granular Materials (MGM) experiments aboard the Space Shuttle use the microgravity of space to simulate this behavior under conditons that carnot be achieved in laboratory tests on Earth. MGM is shedding light on the behavior of fine-grain materials under low effective stresses. Applications include earthquake engineering, granular flow technologies (such as powder feed systems for pharmaceuticals and fertilizers), and terrestrial and planetary geology. Nine MGM specimens have flown on two Space Shuttle flights. Another three are scheduled to fly on STS-107. The principal investigator is Stein Sture of the University of Colorado at Boulder. Note: Because the image on the screen was muted in the original image, its brightness and contrast are boosted in this rendering to make the test cell more visible. Credit: NASA/Marshall Space Flight Center (MSFC)

Scaling behavior of immersed granular flows

NASA Astrophysics Data System (ADS)

Amarsid, L.; Delenne, J.-Y.; Mutabaruka, P.; Monerie, Y.; Perales, F.; Radjai, F.

2017-06-01

The shear behavior of granular materials immersed in a viscous fluid depends on fluid properties (viscosity, density), particle properties (size, density) and boundary conditions (shear rate, confining pressure). Using computational fluid dynamics simulations coupled with molecular dynamics for granular flow, and exploring a broad range of the values of parameters, we show that the parameter space can be reduced to a single parameter that controls the packing fraction and effective friction coefficient. This control parameter is a modified inertial number that incorporates viscous effects.

Nano-modified cement composites and its applicability as concrete repair material

NASA Astrophysics Data System (ADS)

Manzur, Tanvir

Nanotechnology or Nano-science, considered the forth industrial revolution, has received considerable attention in the past decade. The physical properties of a nano-scaled material are entirely different than that of bulk materials. With the emerging nanotechnology, one can build material block atom by atom. Therefore, through nanotechnology it is possible to enhance and control the physical properties of materials to a great extent. Composites such as concrete materials have very high strength and Young's modulus but relatively low toughness and ductility due to their covalent bonding between atoms and lacking of slip systems in the crystal structures. However, the strength and life of concrete structures are determined by the microstructure and mass transfer at nano scale. Cementitious composites are amenable to manipulation through nanotechnology due to the physical behavior and size of hydration products. Carbon nanotubes (CNT) are nearly ideal reinforcing agent due to extremely high aspect ratios and ultra high strengths. So there is a great potential to utilize CNT in producing new cement based composite materials. It is evident from the review of past literature that mechanical properties of nanotubes reinforced cementitious composites have been highly variable. Some researches yielded improvement in performance of CNT-cement composites as compared to plain cement samples, while other resulted in inconsequential changes in mechanical properties. Even in some cases considerable less strengths and modulus were obtained. Another major difficulty of producing CNT reinforced cementitious composites is the attainment of homogeneous dispersion of nanotubes into cement but no standard procedures to mix CNT within the cement is available. CNT attract more water to adhere to their surface due to their high aspect ratio which eventually results in less workability of the cement mix. Therefore, it is extremely important to develop a suitable mixing technique and an optimum mix proportion to produce CNT reinforced cement composites. In this study, an extensive parametric study has been conducted using different types of treated and untreated multi walled nanotubes (MWNT) as reinforcement of cementitious composites having different mix proportions. It is found that mixing of nanotubes within cement matrix is the key to develop composites having desirable properties. A mixing technique has been proposed to address the issues related to dispersion of nanotubes within cement matrix. Polycarboxylate based super plasticizer has been proposed to use as surfactant. It is evident that there exists an optimum concentration of MWNT and mix proportion to achieve proper reinforcement behavior and strength properties. The affect of size of MWNT on strengths (both compressive and flexure) of composites has also been investigated. Based on the parametric study and statistical analysis, a tentative optimum mix proportion has been proposed. Composites made by the proposed mixing technique and design mix obtained 26, 27 and 16% higher compressive strength as compared to control samples at the age of 3, 7 and 28 day, respectively. Flexural strengths of those composites at 3, 7 and 28 day were about 24, 24.5 and 20% higher than that of control samples, respectively. It has also been suggested that application of MWNT reinforced cement mortar as concrete repair material has excellent potential since composites exhibited desirable behavior in setting time, bleeding and slant shear.

Probing Dynamics in Granular Media of Contrasting Geometries via X-Ray Phase Contrast Imaging and PDV

NASA Astrophysics Data System (ADS)

Crum, Ryan; Pagan, Darren; Lind, Jon; Homel, Michael; Hurley, Ryan; Herbold, Eric; Akin, Minta

Granular systems are ubiquitous in our everyday world and play a central role in many dynamic scientific problems including mine blasting, projectile penetration, astrophysical collisions, explosions, and dynamic compaction. An understanding of granular media's behavior under various loading conditions is an ongoing scientific grand challenge. This is partly due to the intricate interplay between material properties, loading conditions, grain geometry, and grain connectivity. Previous dynamic studies in granular media predominantly utilize the macro-scale analyses VISAR or PDV, diagnostics that are not sensitive to the many degrees of freedom and their interactions, focusing instead on their aggregate effect. Results of a macro-scale analysis leave the principal interactions of these degrees of freedom too entangled to elucidate. To isolate the significance of grain geometry, this study probes various geometries of granular media subjected to gas gun generated waves via in-situ X-ray analysis. Analyses include evaluating displacement fields, grain fracture, inter- and intra-granular densification, and wave front motion. Phase Contrast Imaging (PCI) and PDV analyses feed directly into our concurrent meso-scale granular media modeling efforts to enhance our predictive capabilities.

β-Dicalcium silicate-based cement: synthesis, characterization and in vitro bioactivity and biocompatibility studies.

PubMed

Correa, Daniel; Almirall, Amisel; García-Carrodeguas, Raúl; dos Santos, Luis Alberto; De Aza, Antonio H; Parra, Juan; Delgado, José Ángel

2014-10-01

β-dicalcium silicate (β-Ca₂ SiO₄, β-C₂ S) is one of the main constituents in Portland cement clinker and many refractory materials, itself is a hydraulic cement that reacts with water or aqueous solution at room/body temperature to form a hydrated phase (C-S-H), which provides mechanical strength to the end product. In the present investigation, β-C₂ S was synthesized by sol-gel process and it was used as powder to cement preparation, named CSiC. In vitro bioactivity and biocompatibility studies were assessed by soaking the cement samples in simulated body fluid solutions and human osteoblast cell cultures for various time periods, respectively. The results showed that the sol-gel process is an available synthesis method in order to obtain a pure powder of β-C₂ S at relatively low temperatures without chemical stabilizers. A bone-like apatite layer covered the material surface after soaking in SBF and its compressive strength (CSiC cement) was comparable with that of the human trabecular bone. The extracts of this cement were not cytotoxic and the cell growth and relative cell viability were comparable to negative control. © 2013 Wiley Periodicals, Inc.