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Sample records for chaplygin gas model

  1. Phase space analysis of some interacting Chaplygin gas models

    NASA Astrophysics Data System (ADS)

    Khurshudyan, M.; Myrzakulov, R.

    2017-02-01

    In this paper we discuss a phase space analysis of various interacting Chaplygin gas models in general relativity. Linear and nonlinear sign changeable interactions are considered. For each case appropriate late time attractors of field equations are found. The Chaplygin gas is one of the dark fluids actively considered in modern cosmology due to the fact that it is a joint model of dark energy and dark matter.

  2. Dynamics of warm Chaplygin gas inflationary models with quartic potential

    NASA Astrophysics Data System (ADS)

    Jawad, Abdul; Butt, Sadaf; Rani, Shamaila

    2016-05-01

    Warm inflationary universe models in the context of the generalized Chaplygin gas, the modified Chaplygin gas, and the generalized cosmic Chaplygin gas are being studied. The dissipative coefficient of the form Γ ∝ T, and the weak and the strong dissipative regimes are being considered. We use the quartic potential, λ _{*}φ 4/4, which is ruled out by current data in cold inflation but in our models by analysis it is seen to be in agreement with the WMAP9 and the latest Planck data. In these scenarios, the power spectrum, the spectral index, and the tensor-to-scalar ratio are being examined in the slow-roll approximation. We show the dependence of the tensor-scalar ratio r on the spectral index ns and observe that the range of the tensor-scalar ratio is r<0.05 in the generalized Chaplygin gas, r<0.15 in the modified Chaplygin gas, and r<0.12 in the generalized cosmic Chaplygin gas models. Our results are in agreement with recent observational data like WMAP9 and the latest Planck data.

  3. Modified Chaplygin gas inspired inflationary model in braneworld scenario

    NASA Astrophysics Data System (ADS)

    Jawad, Abdul; Rani, Shamaila; Mohsaneen, Sidra

    2016-05-01

    We investigate the modified Chaplygin gas inspired inflationary regime in the brane-world framework in the presence of standard and tachyon scalar fields. We consider the intermediate inflationary scenario and construct the slow-roll parameters, e-folding numbers, spectral index, scalar and tensor power spectra, tensor to scalar ratio for both scalar field models. We develop the ns - N and r - N planes and concluded that ns˜eq96^{+0.5}_{-0.5} and r≤0.0016 for N˜eq60^{+5}_{-5} in both cases of scalar field models as well as for all values of m. These constraints are consistent with observational data such as WMAP7, WMAP9 and Planck data.

  4. Effect of Varying Bulk Viscosity on Generalized Chaplygin Gas

    NASA Astrophysics Data System (ADS)

    Saadat, H.; Pourhassan, B.

    2014-04-01

    In this paper, viscous generalized Chaplygin gas as a model of dark energy considered. We assume non-constant bulk viscous coefficient and study dark energy density. We consider several cases of density-dependent viscosities. We find that, in the special case, the viscous generalized Chaplygin gas is corresponding to modified Chaplygin gas.

  5. Observational constraints on cosmological models with Chaplygin gas and quadratic equation of state

    NASA Astrophysics Data System (ADS)

    Sharov, G. S.

    2016-06-01

    Observational manifestations of accelerated expansion of the universe, in particular, recent data for Type Ia supernovae, baryon acoustic oscillations, for the Hubble parameter H(z) and cosmic microwave background constraints are described with different cosmological models. We compare the ΛCDM, the models with generalized and modified Chaplygin gas and the model with quadratic equation of state. For these models we estimate optimal model parameters and their permissible errors with different approaches to calculation of sound horizon scale rs(zd). Among the considered models the best value of χ2 is achieved for the model with quadratic equation of state, but it has 2 additional parameters in comparison with the ΛCDM and therefore is not favored by the Akaike information criterion.

  6. Modified Chaplygin gas cosmology with bulk viscosity

    NASA Astrophysics Data System (ADS)

    Benaoum, H. B.

    2014-09-01

    In this paper, we investigate the viscous modified Chaplygin gas cosmological model. Solutions for different values of the viscosity parameter are obtained using both analytical and numerical methods. We have calculated the deceleration and defined newly statefinder {r, s} pair in D dimensions. It is shown that when D = 4, the usual statefinder parameters are recovered. Furthermore, we apply the statefinder diagnostic to the MCG model with and without viscosity in D dimensions and explore these parameters graphically.

  7. Cosmological Imprints of a Generalized Chaplygin Gas Model for the Early Universe

    SciTech Connect

    Bouhmadi-Lopez, Mariam; Chen, Pisin; Liu, Yen-Wei; /Taiwan, Natl. Taiwan U.

    2012-06-06

    We propose a phenomenological model for the early universe where there is a smooth transition between an early quintessence phase and a radiation-dominated era. The matter content is modeled by an appropriately modified Chaplygin gas for the early universe. We constrain the model observationally by mapping the primordial power spectrum of the scalar perturbations to the latest data of WMAP7. We compute as well the spectrum of the primordial gravitational waves as would be measured today. We show that the high frequencies region of the spectrum depends on the free parameter of the model and most importantly this region of the spectrum can be within the reach of future gravitational waves detectors.

  8. Anisotropic Bianchi Type I Cosmological Models with Generalized Chaplygin Gas and Dynamical Gravitational and Cosmological Constants

    NASA Astrophysics Data System (ADS)

    Kotambkar, S.; Singh, G. P.; Kelkar, R.; Bishi, Binaya K.

    2017-02-01

    This paper deals with study of generalized Chaplygin gas model with dynamical gravitational and cosmological constants. In this paper a new set of exact solutions of Einstein field equations for spatially homogeneous and anisotropic Bianchi type I space-time have been obtained. The solutions of the Einstein’s field equations are obtained by considering (i) the power law relation between Hubble parameter H and scale factor R and (ii) scale factor of the form R = ‑1/t + t 2, t > 1. The assumptions lead to constant and variable deceleration parameter respectively. The physical and dynamical behaviors of the models have been discussed with the help of graphical representations. Also we have discussed the stability and physical acceptability of solutions for solution type-I and solution type-II.

  9. The generalized Chaplygin-Jacobi gas

    SciTech Connect

    Villanueva, J.R.

    2015-07-01

    The present paper is devoted to find a new generalization of the generalized Chaplygin gas. Therefore, starting from the Hubble parameter associated to the Chaplygin scalar field and using some elliptic identities, the elliptic generalization is straightforward. Thus, all relevant quantities that drive inflation are calculated exactly. Finally, using the measurement on inflation from the Planck 2015 results, observational constraints on the parameters are given.

  10. Scalar perturbations in the late Universe: viability of the Chaplygin gas models

    SciTech Connect

    Bouhmadi-López, Mariam; Brilenkov, Maxim; Brilenkov, Ruslan; Morais, João

    2015-12-01

    We study the late-time evolution of the Universe where dark energy (DE) is parametrised by a modified generalised Chaplygin gas (mGCG) on top of cold dark matter (CDM) . We also take into account the radiation content of the Universe. In this context, the late stage of the evolution of the universe refers to the epoch where CDM is already clustered into inhomogeneously distributed discrete structures (galaxies, groups and clusters of galaxies). Under these conditions, the mechanical approach is an adequate tool to study the Universe deep inside the cell of uniformity. To be more accurate, we study scalar perturbations of the Friedmann-Lemaȋtre-Robertson-Walker metric due to inhomogeneities of CDM as well as fluctuations of radiation and mGCG, the later driving the late-time acceleration of the universe. Our analysis applies as well to the case where mGCG plays the role of DM and DE . We select the sets of parameters of the mGCG that are compatible with the mechanical approach. These sets define prospective mGCG models. By comparing the selected sets of models with some of the latest observational data results, we conclude that the mGCG is in tight agreement with those observations particularly for a mGCG playing the role of DE and DM.

  11. Extended Chaplygin gas in Horava-Lifshitz gravity

    NASA Astrophysics Data System (ADS)

    Pourhassan, B.

    2016-09-01

    In this paper, we investigate cosmological models of the extended Chaplygin gas in a universe governed by Horava-Lifshitz gravity. The equation of state for an extended Chaplygin gas is a (n + 2) -variable equation determined by An, α, and B. In this work, we are interested to the case of second order (n = 2) equation of state which recovers quadratic barotropic equation of state. In that case there are four free parameters. We solve conservation equation approximately and obtain energy density in terms of scale factor with mentioned free parameters. Under some assumptions we relate free parameters to each other to have only one free independent parameter (A2) . It help us to obtain explicit expression for energy density in terms of scale factor. The allowed values of the second order extended Chaplygin gas parameter is fixed using the recent astrophysical and cosmological observational data. Thermodynamics of the model investigated based on the first and second law of thermodynamics.

  12. Cosmological constraints on a decomposed Chaplygin gas

    NASA Astrophysics Data System (ADS)

    Wang, Yuting; Wands, David; Xu, Lixin; De-Santiago, Josue; Hojjati, Alireza

    2013-04-01

    Any unified dark matter cosmology can be decomposed into dark matter interacting with vacuum energy, without introducing any additional degrees of freedom. We present observational constraints on an interacting vacuum plus dark energy corresponding to a generalized Chaplygin gas cosmology. We consider two distinct models for the interaction leading to either a barotropic equation of state or dark matter that follows geodesics, corresponding to a rest-frame sound speed equal to the adiabatic sound speed or zero sound speed, respectively. For the barotropic model, the most stringent constraint on α comes from the combination of CMB+SNIa+LSS(m) gives α<5.66×10-6 at the 95% confidence level, which indicates that the barotropic model must be extremely close to the ΛCDM cosmology. For the case where the dark matter follows geodesics, perturbations have zero sound speed, and CMB+SNIa+gISW then gives the much weaker constraint -0.15<α<0.26 at the 95% confidence level.

  13. Viscous Generalized Chaplygin Gas in Non-flat Universe

    NASA Astrophysics Data System (ADS)

    Saadat, H.

    2013-05-01

    In this paper we study viscous generalized Chaplygin gas and obtain modified Friedmann equations due to viscosity. In the case of non-flat universe we calculate time-dependent energy density of generalized Chaplygin gas. By using stability condition and speed of sound we find critical value of viscosity coefficient where speed of sound is finite.

  14. FRW bulk viscous cosmology with modified cosmic Chaplygin gas

    NASA Astrophysics Data System (ADS)

    Saadat, H.; Pourhassan, B.

    2013-03-01

    In this paper we study FRW bulk viscous cosmology in presence of modified cosmic Chaplygin gas. We obtain generalized Friedmann equations due to bulk viscosity and modified cosmic Chaplygin gas. Then, we calculate time-dependent energy density and discuss Hubble expansion parameter.

  15. Quintessence and (anti-)Chaplygin gas in loop quantum cosmology

    SciTech Connect

    Lamon, Raphael; Woehr, Andreas J.

    2010-01-15

    The concordance model of cosmology contains several unknown components such as dark matter and dark energy. Many proposals have been made to describe them by choosing an appropriate potential for a scalar field. We study four models in the realm of loop quantum cosmology: the Chaplygin gas, an inflationary and radiationlike potential, quintessence and an anti-Chaplygin gas. For the latter we show that all trajectories start and end with a type II singularity and, depending on the initial value, may go through a bounce. On the other hand the evolution under the influence of the first three scalar fields behaves classically at times far away from the big bang singularity and bounces as the energy density approaches the critical density.

  16. Warm modified Chaplygin gas shaft inflation

    NASA Astrophysics Data System (ADS)

    Jawad, Abdul; Ilyas, Amara; Rani, Shamaila

    2017-02-01

    In this paper, we examine the possible realization of a new inflation family called "shaft inflation" by assuming the modified Chaplygin gas model and a tachyon scalar field. We also consider the special form of the dissipative coefficient Γ ={a_0}T3/φ ^{2 } and calculate the various inflationary parameters in the scenario of strong and weak dissipative regimes. In order to examine the behavior of inflationary parameters, the n_s - φ , n_s - r, and n_s - α _s planes (where n_s, α _s, r, and φ represent the spectral index, its running, tensor-to-scalar ratio, and scalar field, respectively) are being developed, which lead to the constraints r< 0.11, n_s=0.96 ± 0.025, and α _s =-0.019 ± 0.025. It is quite interesting that these results of the inflationary parameters are compatible with BICEP2, WMAP (7+9) and recent Planck data.

  17. Thin-shell wormholes with a generalized Chaplygin gas

    SciTech Connect

    Eiroa, Ernesto F.

    2009-08-15

    In this article, spherically symmetric thin-shell wormholes supported by a generalized Chaplygin gas are constructed and their stability under perturbations preserving the symmetry is studied. Wormholes with charge and with a cosmological constant are analyzed and the results are compared with those obtained for the original Chaplygin gas, which was considered in a previous work. For some values of the parameters, one stable configuration is also present and a new extra unstable solution is found.

  18. Variable modified Chaplygin gas in the holographic dark energy scenario

    NASA Astrophysics Data System (ADS)

    Chattopadhyay, Surajit; Debnath, Ujjal

    2012-07-01

    The holographic principle emerged in the context of black-holes, where it was noted that a local quantum field theory can not fully describe the black holes [1]. Some long standing debates regarding the time evolution of a system, where a black hole forms and then evaporates, played the key role in the development of the holographic principle [2,3,4]. The Chaplygin gas is characterized by an exotic equation of state p=-B/ρ. where B is a positive constant. Role of Chaplygin gas in the accelerated universe has been studied by several authors. The above mentioned equation of state has been modified to p=-B/ρ^{α}, where α lies between 0 and 1. This equation has been further modified to p=-A+B/ρ^{α}. This is called the modified Chaplygin gas. Debnath [5] introduced a variable modified Chaplygin gas by considering B as a function of scale factor a. In this work, we have considered that the universe is filled with normal matter and variable modified Chaplygin gas. Also we have considered the interaction between normal matter and variable modified Chaplygin gas in FRW universe. Then we have considered a correspondence between the holographic dark energy density and interacting variable modified Chaplygin gas energy density. Then we have reconstructed the potential of the scalar field which describes the variable modified Chaplygin cosmology References: [1] K. Enqvist, S. Hannested and M. S. Sloth, JCAP 2, 004 (2005). [2] L. Thorlocius, hep-th/0404098. [3] G. T. Hooft, gr-qc/9310026. [4] L. Susskind, J. Math. Phys. 36, 6377 (1995). [5] U. Debnath, Astrophys. Space Sci. 312, 295 (2007).

  19. Observational tests of non-adiabatic Chaplygin gas

    SciTech Connect

    Carneiro, S.; Pigozzo, C. E-mail: cpigozzo@ufba.br

    2014-10-01

    In a previous paper [1] it was shown that any dark sector model can be mapped into a non-adiabatic fluid formed by two interacting components, one with zero pressure and the other with equation-of-state parameter ω = -1. It was also shown that the latter does not cluster and, hence, the former is identified as the observed clustering matter. This guarantees that the dark matter power spectrum does not suffer from oscillations or instabilities. It applies in particular to the generalised Chaplygin gas, which was shown to be equivalent to interacting models at both background and perturbation levels. In the present paper we test the non-adiabatic Chaplygin gas against the Hubble diagram of type Ia supernovae, the position of the first acoustic peak in the anisotropy spectrum of the cosmic microwave background and the linear power spectrum of large scale structures. We consider two different compilations of SNe Ia, namely the Constitution and SDSS samples, both calibrated with the MLCS2k2 fitter, and for the power spectrum we use the 2dFGRS catalogue. The model parameters to be adjusted are the present Hubble parameter, the present matter density and the Chaplygin gas parameter α. The joint analysis best fit gives α ≈ - 0.5, which corresponds to a constant-rate energy flux from dark energy to dark matter, with the dark energy density decaying linearly with the Hubble parameter. The ΛCDM model, equivalent to α = 0, stands outside the 3σ confidence interval.

  20. Crossing the phantom divide in an interacting generalized Chaplygin gas

    SciTech Connect

    Garcia-Compean, H; Garcia-Jimenez, G; Ramirez, C; Obregon, O E-mail: ggarcia@fcfm.buap.mx E-mail: octavio@fisica.ugto.mx

    2008-07-15

    Unified generalized Chaplygin gas models assuming an interaction between dark energy and dark matter fluids have been previously proposed. Following these ideas, we consider a particular relation between dark densities, which allows the possibility of a time varying equation of state for dark energy that crosses the phantom divide at a recent epoch. Moreover, these densities decay throughout the evolution of the Universe, avoiding a big rip. We find also a scaling solution, i.e. these densities are asymptotically proportional in the future, which contributes to the solution of the coincidence problem.

  1. Chaplygin gas braneworld inflation according to WMAP7 data

    SciTech Connect

    Zarrouki, R.; Bennai, M.

    2010-12-15

    We consider a Chaplygin gas model with an exponential potential in framework of braneworld inflation. We apply the slow-roll approximation in the high-energy limit to derive various inflationary spectrum perturbation parameters. We show that the inflation observables depend only on the e-folding number N and the final value of the slow-roll parameter {epsilon}{sub end}. Whereas for small running of the scalar spectral index (dn{sub s}/dlnk), the inflation observables are in good agreement with recent WMAP7 data.

  2. Inflationary cosmology with Chaplygin gas in Palatini formalism

    SciTech Connect

    Borowiec, Andrzej; Wojnar, Aneta; Stachowski, Aleksander; Szydłowski, Marek E-mail: aleksander.stachowski@uj.edu.pl E-mail: aneta.wojnar@ift.uni.wroc.pl

    2016-01-01

    We present a simple generalisation of the ΛCDM model which on the one hand reaches very good agreement with the present day experimental data and provides an internal inflationary mechanism on the other hand. It is based on Palatini modified gravity with quadratic Starobinsky term and generalized Chaplygin gas as a matter source providing, besides a current accelerated expansion, the epoch of endogenous inflation driven by type III freeze singularity. It follows from our statistical analysis that astronomical data favors negative value of the parameter coupling quadratic term into Einstein-Hilbert Lagrangian and as a consequence the bounce instead of initial Big-Bang singularity is preferred.

  3. Recent observational constraints on generalized Chaplygin gas in UDME scenario

    NASA Astrophysics Data System (ADS)

    Thakur, P.

    2017-03-01

    Recent observational predictions suggest that our Universe is passing through an accelerating phase in the recent past. This acceleration may be realized with the negatively pressured dark energy. Generalized Chaplygin gas may be suitable to describe the evolution of the Universe as a candidate of unified dark matter energy (UDME) model. Its EoS parameters are constrained using (i) dimensionless age parameter ( H 0 t 0) and (ii) the observed Hubble ( H( z)- z) data (OHD) + baryon acoustic oscillation (BAO) data + cosmic microwave background (CMB) shift data + supernovae (Union2.1) data. Dimensionless age parameter puts loose bounds on the EoS parameters. Best-fit values of the EoS parameters H 0, A s and α ( A s and α are defined in the energy density for generalized Chaplygin gas (GCG) and in EoS) are then determined from OHD + BAO + CMB + Union2.1 data and contours are drawn to obtain their allowed range of values. The present age of the Universe ( t 0) and the present Hubble parameter ( H 0) have been estimated with 1 σ confidence level. Best-fit values of deceleration parameter ( q), squared sound speed (cs2) and EoS parameter ( ω) of this model are then determined. It is seen that GCG satisfactorily accommodates an accelerating phase and structure formation phase.

  4. Spherical thin-shell wormholes and modified Chaplygin gas

    SciTech Connect

    Sharif, M.; Azam, M. E-mail: azammath@gmail.com

    2013-05-01

    The purpose of this paper is to construct spherical thin-shell wormhole solutions through cut and paste technique and investigate the stability of these solutions in the vicinity of modified Chaplygin gas. The Darmois-Israel formalism is used to formulate the stresses of the surface concentrating the exotic matter. We explore the stability of the wormhole solutions by using the standard potential method. We conclude that there exist more stable as well as unstable solutions than the previous study with generalized Chaplygin gas [19].

  5. Viscous generalized Chaplygin gas as a unified dark fluid

    NASA Astrophysics Data System (ADS)

    Li, Wei; Xu, Lixin

    2013-06-01

    In this paper, we revisit viscous generalized Chaplygin gas (VGCG) as a unified dark fluid, which modifies the pressure only by redefining the effective pressure p eff, according to p_{eff}=p-√{3}ζ0ρ, where ζ 0 is the newly added model parameter which characterizes the viscous property and can be determined by the cosmic observations. By using the currently available cosmic observational data from WMAP, BAO, and SN Ia, the model parameter space is obtained via a Markov Chain Monte Carlo method: ζ0=0.000708_{- 0.00155- 0.00311- 0.00503}^{+ 0.00151+ 0.00275+ 0.00425} in 1, 2, 3 σ regions. The results show that the viscous effect is very small due the value ζ 0≈0 and the VGCG model can match observational data points as well as ΛCDM model.

  6. Interacting Modified Cosmic Chaplygin Gas with Variable Cosmological Constant and Viscosity

    NASA Astrophysics Data System (ADS)

    Saadat, Hassan

    2014-12-01

    In this paper we study interaction between modified cosmic Chaplygin gas and pressureless matter in presence of both bulk and shear viscosities as a model of our Universe. Also we consider variable cosmological constant and investigate some cosmological parameters such as sound speed and time-dependent density. We investigate stability of model by using first order linear perturbation.

  7. Viscous Chaplygin Gas in Non-flat Universe

    NASA Astrophysics Data System (ADS)

    Saadat, Hassan; Farahani, Hoda

    2013-04-01

    In this work we study viscous Chaplygin gas and obtain modified Friedmann equations due to viscosity. We calculate time-dependent energy density for the case of non-flat universe. By using stability condition and speed of sound we find critical value of viscosity coefficient where speed of sound is finite.

  8. Bouncing universe in the presence of an extended Chaplygin gas

    NASA Astrophysics Data System (ADS)

    Salehi, A.

    2016-12-01

    In this paper, we investigate the possibility of setting a model of a nonsingular universe in the context of the extended Chaplygin gas model with the equation of state p =A ρ -B/ρα through the framework of four-dimensional Friedmann-Robertson-Walker background. We find the following solutions of the singularity-free cosmological model: a cyclic universe with the minimal and maximal values of the scale factor that remains the same in every cycle, for an open universe with k =-1 and a negative cosmological constant; a nonsingular oscillating universe as a single bouncing solution for the cases of k =0 and k =1 curvature; and an oscillating universe with the minimal and maximal values of the scale factor that periodically rises up and down in the presence of a self-interacting scalar field model for all cases of the curved universe (with k =-1 , k =0 and k =1 ). We also study whether a nonsingular bounce requires violation of the null energy condition.

  9. Chaplygin gas inspired scalar fields inflation via well-known potentials

    NASA Astrophysics Data System (ADS)

    Jawad, Abdul; Butt, Sadaf; Rani, Shamaila

    2016-08-01

    Brane inflationary universe models in the context of modified Chaplygin gas and generalized cosmic Chaplygin gas are being studied. We develop these models in view of standard scalar and tachyon fields. In both models, the implemented inflationary parameters such as scalar and tensor power spectra, scalar spectral index and tensor to scalar ratio are derived under slow roll approximations. We also use chaotic and exponential potential in high energy limits and discuss the characteristics of inflationary parameters for both potentials. These models are compatible with recent astronomical observations provided by WMAP7{+}9 and Planck data, i.e., ηs=1.027±0.051, 1.009±0.049, 0.096±0.025 and r<0.38, 0.36, 0.11.

  10. FRW bulk viscous cosmology with modified Chaplygin gas in flat space

    NASA Astrophysics Data System (ADS)

    Saadat, H.; Pourhassan, B.

    2013-02-01

    In this paper we study FRW bulk viscous cosmology in presence of modified Chaplygin gas. We write modified Friedmann equations due to bulk viscosity and Chaplygin gas and obtain time-dependent energy density for the special case of flat space.

  11. Time-Dependent Density of Viscous Modified Chaplygin Gas with Arbitrary α

    NASA Astrophysics Data System (ADS)

    Saadat, H.

    2013-11-01

    In this paper we study modified Chaplygin gas which has viscosity for the case of arbitrary α instead of α=0.5. We obtain behavior of the energy density of modified Chaplygin gas with respect to the constant and time-dependent bulk viscosity. We find also, numerically, effect of α on the energy density.

  12. Viscous generalized Chaplygin gas interacting with f(R,T) gravity

    NASA Astrophysics Data System (ADS)

    Baffou, E. H.; Houndjo, M. J. S.; Salako, I. G.

    In this paper, we study in Friedmann-Robertson-Walker universe the interaction between the viscous generalized Chaplygin gas with f(R,T) gravity, which is an arbitrary function of the Ricci scalar R and the trace T of the energy-momentum tensor. Assuming that the contents of universe are dominated by a generalized Chaplygin gas and dark energy, we obtained the modified Friedmann equations and also the time-dependent energy density and pressure of dark energy due to the shear and bulk viscosities for three interacting models depending on an input parameter Q. Within the simple form of scale factor (power-law), we discuss the graphical representation of dark energy density parameter and investigate the shear and bulk viscosities effects on the accelerating expansion of the universe for each interacting model.

  13. Chaplygin gas Hořava-Lifshitz quantum cosmology

    NASA Astrophysics Data System (ADS)

    Ardehali, Hossein; Pedram, Pouria

    2016-02-01

    In this paper, we study the Chaplygin gas Hořava-Lifshitz quantum cosmology. Using Schutz formalism and Arnowitt-Deser-Misner decomposition, we obtain the corresponding Schrödinger-Wheeler-DeWitt equation. We obtain exact classical and quantum mechanical solutions and construct wave packets to study the time evolution of the expectation value of the scale factor for two cases. We show that unlike classical solutions and upon choosing appropriate initial conditions, the expectation value of the scale factor never tends to the singular point which exhibits the singularity-free behavior of the solutions in the quantum domain.

  14. Viability of variable generalised Chaplygin gas: a thermodynamical approach

    NASA Astrophysics Data System (ADS)

    Panigrahi, D.; Chatterjee, S.

    2017-03-01

    The viability of the variable generalised Chaplygin gas (VGCG) model is analysed from the standpoint of its thermodynamical stability criteria with the help of an equation of state, P = - B/ρ ^{α }, where B = B0V^{-n/3}. Here B0 is assumed to be a positive universal constant, n is a constant parameter and V is the volume of the cosmic fluid. We get the interesting result that if the well-known stability conditions of a fluid is adhered to, the values of n are constrained to be negative definite to make ( partial P/partial V) S <0 & ( partial P/partial V) T <0 throughout the evolution. Moreover the positivity of thermal capacity at constant volume cV as also the validity of the third law of thermodynamics are ensured in this case. For the particular case n = 0 the effective equation of state reduces to Λ CDM model in the late stage of the universe while for n <0 it mimics a phantom-like cosmology which is in broad agreement with the present SNe Ia constraints like VGCG model. The thermal equation of state is discussed and the EoS parameter is found to be an explicit function of temperature only. Further for large volume the thermal equation of state parameter is identical with the caloric equation of state parameter when T → 0. It may also be mentioned that like Santos et al. our model does not admit of any critical points. We also observe that although the earlier model of Lu explains many of the current observational findings of different probes it fails to explain the crucial tests of thermodynamical stability.

  15. Tolman-Oppenheimer-Volkoff equations in the presence of the Chaplygin gas: Stars and wormholelike solutions

    SciTech Connect

    Gorini, V.; Moschella, U.; Kamenshchik, A. Yu.; Pasquier, V.; Starobinsky, A. A.

    2008-09-15

    We study static solutions of the Tolman-Oppenheimer-Volkoff equations for spherically symmetric objects (stars) living in a space filled with the Chaplygin gas. Two cases are considered. In the normal case, all solutions (excluding the de Sitter one) realize a three-dimensional spheroidal geometry because the radial coordinate achieves a maximal value (the 'equator'). After crossing the equator, three scenarios are possible: a closed spheroid having a Schwarzschild-type singularity with infinite blueshift at the 'south pole', a regular spheroid, and a truncated spheroid having a scalar curvature singularity at a finite value of the radial coordinate. The second case arises when the modulus of the pressure exceeds the energy density (the phantom Chaplygin gas). There is no more equator and all solutions have the geometry of a truncated spheroid with the same type of singularity. We also consider static spherically symmetric configurations existing in a universe filled with only the phantom Chaplygin gas. In this case, two classes of solutions exist: truncated spheroids and solutions of the wormhole type with a throat. However, the latter are not asymptotically flat and possess curvature singularities at finite values of the radial coordinate. Thus, they may not be used as models of observable compact astrophysical objects.

  16. Co-Existence of Modified Chaplygin Gas and Other Dark Energies in the Framework of Fractal Universe

    NASA Astrophysics Data System (ADS)

    Maity, Sayani; Debnath, Ujjal

    2016-05-01

    In this work, we consider a non-flat universe in the framework of fractal cosmology. We have investigated the co-existence of different kinds of dark energy models such as tachyonic field, DBI-essence, hessence, k-essence, dilaton, quintessence with the modified Chaplygin gas (MCG) in fractal universe and obtained the statefinder parameters. The natures of the scalar fields and the concerned potentials have been analyzed by the correspondence scenario in the fractal universe.

  17. Viscous Varying Generalized Chaplygin Gas with Cosmological Constant and Space Curvature

    NASA Astrophysics Data System (ADS)

    Saadat, H.; Pourhassan, B.

    2013-10-01

    In this paper we study varying generalized Chaplygin gas which has viscosity in presence of cosmological constant and space curvature. By using well-known forms of scale factor in non-linear differential equation we obtain behavior of dark energy density numerically. We use observational data to fix solution and discuss about stability of our system.

  18. Viscous New Varying Modified Cosmic Chaplygin Gas with Cosmological Constant in Non-flat Universe

    NASA Astrophysics Data System (ADS)

    Naji, Jalil; Saadat, Hassan

    2014-05-01

    In this paper we study new varying modified cosmic Chaplygin gas which has viscosity in presence of cosmological constant and space curvature. By using well-known forms of scale factor in Friedmann equation we obtain behavior of dark energy density numerically. We use observational data to fix solution and discuss about stability of our system.

  19. Wormholes admitting conformal Killing vectors and supported by generalized Chaplygin gas

    NASA Astrophysics Data System (ADS)

    Kuhfittig, Peter K. F.

    2015-08-01

    When Morris and Thorne first proposed that traversable wormholes may be actual physical objects, they concentrated on the geometry by specifying the shape and redshift functions. This mathematical approach necessarily raises questions regarding the determination of the required stress-energy tensor. This paper discusses a natural way to obtain a complete wormhole solution by assuming that the wormhole (1) is supported by generalized Chaplygin gas and (2) admits conformal Killing vectors.

  20. Inflationary generalized Chaplygin gas and dark energy in light of the Planck and BICEP2 experiments

    NASA Astrophysics Data System (ADS)

    Dinda, Bikash R.; Kumar, Sumit; Sen, Anjan A.

    2014-10-01

    In this work, we study an inflationary scenario in the presence of generalized Chaplygin gas (GCG). We show that in Einstein gravity, GCG is not a suitable candidate for inflation; but in a five-dimensional brane-world scenario, it can work as a viable inflationary model. We calculate the relevant quantities such as ns, r, and As related to the primordial scalar and tensor fluctuations, and using their recent bounds from Planck and BICEP2, we constrain the model parameters as well as the five-dimensional Planck mass. But as a slow-roll inflationary model with a power-law type scalar primordial power spectrum, GCG as an inflationary model cannot resolve the tension between results from BICEP2 and Planck with a concordance ΛCDM Universe. We show that by going beyond the concordance ΛCDM model and incorporating more general dark energy behavior, we may ease this tension. We also obtain the constraints on the ns and r and the GCG model parameters using Planck+WP +BICEP2 data considering the CPL dark energy behavior.

  1. Does a generalized Chaplygin gas correctly describe the cosmological dark sector?

    NASA Astrophysics Data System (ADS)

    vom Marttens, R. F.; Casarini, L.; Zimdahl, W.; Hipólito-Ricaldi, W. S.; Mota, D. F.

    2017-03-01

    Yes, but only for a parameter value that makes it almost coincide with the standard model. We reconsider the cosmological dynamics of a generalized Chaplygin gas (gCg) which is split into a cold dark matter (CDM) part and a dark energy (DE) component with constant equation of state. This model, which implies a specific interaction between CDM and DE, has a ΛCDM limit and provides the basis for studying deviations from the latter. Including matter and radiation, we use the (modified) CLASS code (Blas et al., 2011) to construct the CMB and matter power spectra in order to search for a gCg-based concordance model that is in agreement with the SNIa data from the JLA sample and with recent Planck data. The results reveal that the gCg parameter α is restricted to | α | ≲ 0 . 05, i.e., to values very close to the ΛCDM limit α = 0. This excludes, in particular, models in which DE decays linearly with the Hubble rate.

  2. Extended Chaplygin gas as a unified fluid of dark components in varying gravitational constant theory

    NASA Astrophysics Data System (ADS)

    Lu, Jianbo; Xu, Lixin; Tan, Hongyan; Gao, Shanshan

    2014-03-01

    Varying gravitational constant G(t) (VG) cosmology is studied in this paper, where the modified Friedmann equation and the modified energy conservation equation are given with respect to the constant-G theory. Considering the extended Chaplygin gas (ECG) as background fluid (or thinking that ECG fluid is induced by the variation of G), the unified model of dark matter and dark energy is obtained in VG theory. The parameter spaces are investigated in the VG-ECG model by using the recent cosmic data. Constraint results show β =-G/.HG =-0.003-0.020-0.055+0.021+0.034 for the VG-GCG unified model and β=-0.027-0.032-0.066+0.032+0.059 for the VG-MCG unified model. Equivalently, they correspond to the limits on the current variation of Newton's gravitational constant at 95.4% confidence level |G/.G|today≲4.1×10-12 yr-1 and |G/.G|today≲6.6×10-12 yr-1. And for z ≤3.5, bounds on the variation of G/.G in the VG-ECG unified model are in accordance with the experiment explorations of varying G. In addition, in VG theory the used observational data point still cannot distinguish the VG-GCG and VG-MCG unified model from the most popular ΛCDM cosmology. Furthermore, to see the effects of varying G and physical properties for VG-ECG fluid, we discuss the evolutionary behaviors of cosmological quantities in VG theory, such as G/.G, G./.G and equation of state w, etc. For β <0 a quintom scenario crossing over w=-1 can be realized in the VG-GCG model.

  3. Relativistic compact anisotropic charged stellar models with Chaplygin equation of state

    NASA Astrophysics Data System (ADS)

    Bhar, Piyali; Murad, Mohammad Hassan

    2016-10-01

    This paper presents a new model of static spherically symmetric relativistic charged stellar objects with locally anisotropic matter distribution together with the Chaplygin equation of state. The interior spacetime has been matched continuously to the exterior Reissner-Nordström geometry. Different physical properties of the stellar model have been investigated, analyzed, and presented graphically.

  4. Chaplygin gas of Tachyon Nature Imposed by Noether Symmetry and constrained via H(z) data

    NASA Astrophysics Data System (ADS)

    Gardai Collodel, Lucas; Medeiros Kremer, Gilberto

    2016-04-01

    An action of general form is proposed for a Universe containing matter, radiation and dark energy. The latter is interpreted as a tachyon field non-minimally coupled to the scalar curvature. The Palatini approach is used when varying the action so the connection is given by a more generic form. Both the self-interaction potential and the non-minimally coupling function are obtained by constraining the system to present invariability under global point transformation of the fields (Noether Symmetry). The only possible solution is shown to be that of minimal coupling and constant potential (Chaplygin gas). The behavior of the dynamical properties of the system is compared to recent observational data, which infers that the tachyon field must indeed be dynamical.

  5. Interacting modified Chaplygin gas in f(T) gravity framework and analysis of its stability against gravitational perturbation

    NASA Astrophysics Data System (ADS)

    Chattopadhyay, Surajit

    In this work, we investigate the cosmological application of modified Chaplygin gas (MCG) interacting with pressureless dark matter (DM) in the f(T) modified gravity framework, where T is the torsion scalar in teleparallelism. The interaction term has been chosen proportional to the MCG density with positive coupling constant. In the Einstein general relativity (GR) framework, the interacting MCG has been found to have equation of state (EoS) parameter behaving like quintessence. However, the f(T) gravity reconstructed via the interacting MCG has been found to have EoS crossing the phantom boundary of ‑ 1. Thus, one can generate a quintom-like EoS from an interacting MCG model in flat universe in the modified gravity cosmology framework. The reconstructed f(T) model has been found to interpolate between dust and ΛCDM. Stability of the reconstructed f(T) has been investigated and it has been observed that the model is stable against gravitational perturbation. Cosmological evolution of primordial perturbations has also been investigated and the self-interacting potential has been found to increase with cosmic time and the squared speed of sound has been found to be non-negative.

  6. Duality gives rise to Chaplygin cosmologies with a big rip

    NASA Astrophysics Data System (ADS)

    Chimento, Luis P.; Lazkoz, Ruth

    2006-05-01

    We consider modifications to the Friedmann equation motivated by recent proposals along these lines pursuing an explanation to the observed late time acceleration. Here we show that these approaches can be framed within a theory with modified gravity, and we discuss the construction of the duals of the cosmologies generated within that framework. We then investigate the modifications required to generate extended, generalized and modified Chaplygin cosmologies, and then show that their duals belong to a larger family of cosmologies we call enlarged Chaplygin cosmologies. Finally, by letting the parameters of these models take values not earlier considered in the literature we show that some representatives of that family of cosmologies display sudden future singularities. This fact indicates that the behaviour of these spacetimes is rather different from that of generalized or modified Chaplygin gas cosmologies. This reinforces the idea that modifications of gravity can be responsible for unexpected evolutionary features in the universe.

  7. Chaplygin traversable wormholes

    SciTech Connect

    Lobo, Francisco S.N.

    2006-03-15

    The generalized Chaplygin gas (GCG) is a candidate for the unification of dark energy and dark matter, and is parametrized by an exotic equation of state given by p{sub ch}=-A/{rho}{sub ch}{sup {alpha}}, where A is a positive constant and 0<{alpha}{<=}1. In this paper, exact solutions of spherically symmetric traversable wormholes supported by the GCG are found, possibly arising from a density fluctuation in the GCG cosmological background. To be a solution of a wormhole, the GCG equation of state imposes the following generic restriction A<(8{pi}r{sub 0}{sup 2}){sup -(1+{alpha})}, where r{sub 0} is the wormhole throat radius, consequently violating the null energy condition. The spatial distribution of the exotic GCG is restricted to the throat neighborhood, and the physical properties and characteristics of these Chaplygin wormholes are further analyzed. Four specific solutions are explored in some detail, namely, that of a constant redshift function, a specific choice for the form function, a constant energy density, and finally, isotropic pressure Chaplygin wormhole geometries.

  8. Reconstruction of f(T) Gravity with Interacting Variable-Generalised Chaplygin Gas and the Thermodynamics with Corrected Entropies

    NASA Astrophysics Data System (ADS)

    Chattopadhyay, Surajit

    2017-03-01

    This article reports a study on variable-generalised Chaplygin gas (VGCG) interacting with pressureless dark matter (DM) with interaction term Q chosen in the form Q=3HδρΛ, where ρΛ denotes the density of the VGCG. Detailed cosmology of the interacting VGCG has been studied and a quintom behaviour of the equation of state (EoS) parameter has been observed. A statefinder analysis has shown attainment of ΛCDM fixed point by the interacting VGCG. Subsequently, a reconstruction scheme for f(T) gravity has been presented based on the interacting VGCG with power-law form of scale factor. The EoS parameter corresponding to the reconstructed f(T) has shown quintom behaviour. Finally, we have studied the generalised second law (GSL) of thermodynamics in reconstructed f(T) cosmology considering the universe as a closed bounded system with future event horizon as the cosmological boundary. We have associated two different entropies with the cosmological horizons with a logarithmic correction term and a power-law correction term. We have studied the validity of the GSL for both of these corrections.

  9. Regular and chaotic dynamics in the rubber model of a Chaplygin top

    NASA Astrophysics Data System (ADS)

    Borisov, Alexey V.; Kazakov, Alexey O.; Pivovarova, Elena N.

    2016-12-01

    This paper is concerned with the rolling motion of a dynamically asymmetric unbalanced ball (Chaplygin top) in a gravitational field on a plane under the assumption that there is no slipping and spinning at the point of contact. We give a description of strange attractors existing in the system and discuss in detail the scenario of how one of them arises via a sequence of period-doubling bifurcations. In addition, we analyze the dynamics of the system in absolute space and show that in the presence of strange attractors in the system the behavior of the point of contact considerably depends on the characteristics of the attractor and can be both chaotic and nearly quasi-periodic.

  10. Anisotropic charged fluids with Chaplygin equation of state in (2+1) dimension

    NASA Astrophysics Data System (ADS)

    Bhar, Piyali; Rahaman, Farook; Jawad, Abdul; Islam, Sayeedul

    2015-11-01

    Present paper provides a new non-singular model for anisotropic charged fluid sphere in (2+1)-dimensional anti de-Sitter spacetime corresponding to the exterior BTZ spacetime (Banados et al., Phys. Rev. Lett. 69:1849, 1992). The model is obtained by assuming Krori and Barua (KB) ansatz (Krori and Barua, J. Phys. A, Math. Gen., 8:508, 1975). To solve the Einstein-Maxwell field equations we choose modified Chaplygin gas. Various physical quantities have been discussed and from our analysis we show that our model satisfies all required physical conditions for representing compact stars.

  11. A Cosmological Model of the Early Universe Based on ECG with Variable Λ-Term in Lyra Geometry

    NASA Astrophysics Data System (ADS)

    Saadat, H.

    2016-05-01

    In this paper, we study interacting extended Chaplygin gas as dark matter and quintessence scalar field as dark energy with an effective Λ-term in Lyra manifold. As we know Chaplygin gas behaves as dark matter at the early universe while cosmological constant at the late time. Modified field equations are given and motivation of the phenomenological models discussed in details. Four different models based on the interaction term are investigated in this work. Then, we consider other models where Extended Chaplygin gas and quintessence field play role of dark matter and dark energy respectively with two different forms of interaction between the extended Chaplygin gas and quintessence scalar field for both constant and varying Λ. Concerning to the mathematical hardness of the problems we discuss results numerically and graphically. Obtained results give us hope that proposed models can work as good models for the early universe with later stage of evolution containing accelerated expansion.

  12. A note on observational signatures in superluminal unified dark matter models

    SciTech Connect

    Urakawa, Yuko; Kobayashi, Tsutomu E-mail: tsutomu@gravity.phys.waseda.ac.jp

    2010-07-01

    We explore the possibility that the dark matter and dark energy are mimicked by a single fluid or by a single k-essence-like scalar field. The so called Chaplygin gas unified dark matter models can reproduce the observed matter power spectrum by adding a baryon component. It has been argued that the evolution of the baryon fluctuations is particularly favoured for the ''superluminal'' case where the sound speed of the Chaplygin gas exceeds the speed of light at late times, as well as for the models with the negligibly small sound speed. In this note we compute the integrated Sachs-Wolfe signal in the Chaplygin gas models, focusing on the superluminal case which has not been investigated before because of the premature understanding of causality. It is shown that the superluminal model leads to large enhancement of the integrated Sachs-Wolfe effect, which is inconsistent with the CMB measurements.

  13. Discriminating dark energy models by using the Statefinder hierarchy and the growth rate of matter perturbations

    SciTech Connect

    Li, Jun; Yang, Rongjia; Chen, Bohai E-mail: yangrj08@gmail.com

    2014-12-01

    We apply the Statefinder hierarchy and the growth rate of matter perturbations to discriminate modified Chaplygin gas (MCG), generalized Chaplygin gas (GCG), superfluid Chaplygin gas (SCG), purely kinetic k-essence (PKK), and ΛCDM model. We plot the evolutional trajectories of these models in the Statefinder plane and in the composite diagnostic plane. We find that GCG, MCG, SCG, PKK, and ΛCDM can be distinguished well from each other at the present epoch by using the composite diagnostic (ε(z), S{sup (1)}{sub 5}). Using other combinations, such as (S{sup (1)}{sub 3}, S{sup (1)}{sub 4}), (S{sup (1)}{sub 3}, S{sub 5}), (ε(z), S{sup (1)}{sub 3}), and (ε(z), S{sub 4}), some of these five dark energy models cannot be distinguished.

  14. Routh symmetry in the Chaplygin's rolling ball

    NASA Astrophysics Data System (ADS)

    Kim, Byungsoo

    2011-12-01

    The Routh integral in the symmetric Chaplygin's rolling ball has been regarded as a mysterious conservation law due to its interesting form of sqrt {I_1 I_3 + m< {I_s ,s} rangle } Ω _3 . In this paper, a new form of the Routh integral is proposed as a Noether's pairing form of a conservation law. An explicit symmetry vector for the Routh integral is proved to associate the conserved quantity with the invariance of the Lagrangian function under the rollingly constrained nonholonomic variation. Then, the form of the Routh symmetry vector is discussed for its origin as the linear combination of the configurational vectors.

  15. Oil and Gas Supply Modeling

    NASA Astrophysics Data System (ADS)

    Gass, S. I.

    1982-05-01

    The theoretical and applied state of the art of oil and gas supply models was discussed. The following areas were addressed: the realities of oil and gas supply, prediction of oil and gas production, problems in oil and gas modeling, resource appraisal procedures, forecasting field size and production, investment and production strategies, estimating cost and production schedules for undiscovered fields, production regulations, resource data, sensitivity analysis of forecasts, econometric analysis of resource depletion, oil and gas finding rates, and various models of oil and gas supply.

  16. The general class of Bianchi cosmological models with dark energy and variable Λ and G in viscous cosmology

    NASA Astrophysics Data System (ADS)

    Chaubey, R.; Shukla, A. K.; Raushan, Rakesh

    2017-04-01

    The general class of Bianchi cosmological models with dark energy in the form of modified Chaplygin gas with variable Λ and G and bulk viscosity have been considered. We discuss three types of average scale factor by using a special law for deceleration parameter which is linear in time with negative slope. The exact solutions to the corresponding field equations are obtained. We obtain the solution of bulk viscosity ( ξ), cosmological constant (Λ), gravitational parameter ( G) and deceleration parameter ( q) for different equations of state. The model describes an accelerating Universe for large value of time t, wherein the effective negative pressure induced by Chaplygin gas and bulk viscous pressure are driving the acceleration.

  17. Modelling gas generation for landfill.

    PubMed

    Chakma, Sumedha; Mathur, Shashi

    2016-09-27

    A methodology was developed to predict the optimum long-term spatial and temporal generation of landfill gases such as methane, carbon dioxide, ammonia, and hydrogen sulphide on post-closure landfill. The model incorporated the chemical and the biochemical processes responsible for the degradation of the municipal solid waste. The developed model also takes into account the effects of heterogeneity with different layers as observed at the site of landfills' morphology. The important parameters for gas generation due to biodegradation such as temperature, pH, and moisture content were incorporated. The maximum and the minimum generations of methane and hydrogen sulphide were observed. The rate of gas generation was found almost same throughout the depth after 30 years of landfill closure. The proposed model would be very useful for landfill engineering in the mining landfill gas and proper design for landfill gas management systems.

  18. Gas-Filled Capillary Model

    NASA Astrophysics Data System (ADS)

    Steinhauer, L. C.; Kimura, W. D.

    2006-11-01

    We have developed a 1-D, quasi-steady-state numerical model for a gas-filled capillary discharge that is designed to aid in selecting the optimum capillary radius in order to guide a laser beam with the required intensity through the capillary. The model also includes the option for an external solenoid B-field around the capillary, which increases the depth of the parabolic density channel in the capillary, thereby allowing for propagation of smaller laser beam waists. The model has been used to select the parameters for gas-filled capillaries to be utilized during the Staged Electron Laser Acceleration — Laser Wakefield (STELLA-LW) experiment.

  19. Information theoretic model selection applied to supernovae data

    NASA Astrophysics Data System (ADS)

    Biesiada, Marek

    2007-02-01

    Current advances in observational cosmology suggest that our Universe is flat and dominated by dark energy. There are several different theoretical ideas invoked to explain the dark energy with relatively little guidance of which one of them might be right. Therefore the emphasis of ongoing and forthcoming research in this field shifts from estimating specific parameters of the cosmological model to the model selection. In this paper we apply an information theoretic model selection approach based on the Akaike criterion as an estimator of Kullback Leibler entropy. Although this approach has already been used by some authors in a similar context, this paper provides a more systematic introduction to the Akaike criterion. In particular, we present the proper way of ranking the competing models on the basis of Akaike weights (in Bayesian language: posterior probabilities of the models). This important ingredient is lacking from alternative studies dealing with cosmological applications of the Akaike criterion. Of the many particular models of dark energy we focus on four: quintessence, quintessence with a time varying equation of state, the braneworld scenario and the generalized Chaplygin gas model, and test them on Riess's gold sample. As a result we obtain that the best model—in terms of the Akaike criterion—is the quintessence model. The odds suggest that although there exist differences in the support given to specific scenarios by supernova data, most of the models considered receive similar support. The only exception is the Chaplygin gas which is considerably less supported. One can also note that models similar in structure, e.g. ΛCDM, quintessence and quintessence with a variable equation of state, are closer to each other in terms of Kullback Leibler entropy. Models having different structure, e.g. Chaplygin gas and the braneworld scenario, are more distant (in the Kullback Leibler sense) from the best one.

  20. Entropy-corrected new agegraphic dark energy model in the context of Chern-Simons modified gravity

    NASA Astrophysics Data System (ADS)

    Aly, Ayman A.; Fekry, M.; Mansour, H.

    2015-04-01

    Within the framework of Chern-Simons (CS) modified gravity, we studied dark energy models. The new agegraphic dark energy (NADE) model, entropy-corrected new agegraphic dark energy (ECNADE) model and NADE model with generalized uncertainty principle (GUP) are investigated. For these models, we studied the evolution of scale factor a, Hubble parameter H and deceleration parameter q. On meantime, we studied the state finder parameters s and r. These models show some similar behavior with modified Chaplygin gas model in some regions, while in other regions some similarity with phantom and quintessence dark energy is noticed.

  1. Comparison of dark energy models after Planck 2015

    NASA Astrophysics Data System (ADS)

    Xu, Yue-Yao; Zhang, Xin

    2016-11-01

    We make a comparison for ten typical, popular dark energy models according to their capabilities of fitting the current observational data. The observational data we use in this work include the JLA sample of type Ia supernovae observation, the Planck 2015 distance priors of cosmic microwave background observation, the baryon acoustic oscillations measurements, and the direct measurement of the Hubble constant. Since the models have different numbers of parameters, in order to make a fair comparison, we employ the Akaike and Bayesian information criteria to assess the worth of the models. The analysis results show that, according to the capability of explaining observations, the cosmological constant model is still the best one among all the dark energy models. The generalized Chaplygin gas model, the constant w model, and the α dark energy model are worse than the cosmological constant model, but still are good models compared to others. The holographic dark energy model, the new generalized Chaplygin gas model, and the Chevalliear-Polarski-Linder model can still fit the current observations well, but from an economically feasible perspective, they are not so good. The new agegraphic dark energy model, the Dvali-Gabadadze-Porrati model, and the Ricci dark energy model are excluded by the current observations.

  2. The global smooth symmetric solution to 2-D full compressible Euler system of Chaplygin gases

    NASA Astrophysics Data System (ADS)

    Ding, Bingbing; Witt, Ingo; Yin, Huicheng

    2015-01-01

    For one dimensional or multidimensional compressible Euler system of polytropic gases, it is well known that the smooth solution will generally develop singularities in finite time. However, for three dimensional Chaplygin gases, due to the crucial role of "null condition" in the potential equation which is derived by the irrotational and isentropic flow, P. Godin in [9] has proved the global existence of a smooth 3-D spherically symmetric flow with variable entropy when the initial data are of small smooth perturbations with compact supports to a constant state. It is noted that there are some clear differences for the global solution or blowup problems between 2-D and 3-D hyperbolic equations or systems. In this paper, we will focus on the global symmetric solution problem of 2-D full compressible Euler system of Chaplygin gases. Through carrying out involved analysis and finding an appropriate weight we can derive some uniform weighted energy estimates on the small symmetric solution to 2-D compressible Euler system of Chaplygin gases and further establish the global existence of the smooth solution by the continuous induction method.

  3. Modeling Leaking Gas Plume Migration

    SciTech Connect

    Silin, Dmitriy; Patzek, Tad; Benson, Sally M.

    2007-08-20

    In this study, we obtain simple estimates of 1-D plume propagation velocity taking into account the density and viscosity contrast between CO{sub 2} and brine. Application of the Buckley-Leverett model to describe buoyancy-driven countercurrent flow of two immiscible phases leads to a transparent theory predicting the evolution of the plume. We obtain that the plume does not migrate upward like a gas bubble in bulk water. Rather, it stretches upward until it reaches a seal or until the fluids become immobile. A simple formula requiring no complex numerical calculations describes the velocity of plume propagation. This solution is a simplification of a more comprehensive theory of countercurrent plume migration that does not lend itself to a simple analytical solution (Silin et al., 2006). The range of applicability of the simplified solution is assessed and provided. This work is motivated by the growing interest in injecting carbon dioxide into deep geological formations as a means of avoiding its atmospheric emissions and consequent global warming. One of the potential problems associated with the geologic method of sequestration is leakage of CO{sub 2} from the underground storage reservoir into sources of drinking water. Ideally, the injected green-house gases will stay in the injection zone for a geologically long time and eventually will dissolve in the formation brine and remain trapped by mineralization. However, naturally present or inadvertently created conduits in the cap rock may result in a gas leak from primary storage. Even in supercritical state, the carbon dioxide viscosity and density are lower than those of the indigenous formation brine. Therefore, buoyancy will tend to drive the CO{sub 2} upward unless it is trapped beneath a low permeability seal. Theoretical and experimental studies of buoyancy-driven supercritical CO{sub 2} flow, including estimation of time scales associated with plume evolution, are critical for developing technology

  4. Hazardous gas model evaluation with field observations

    NASA Astrophysics Data System (ADS)

    Hanna, S. R.; Chang, J. C.; Strimaitis, D. G.

    Fifteen hazardous gas models were evaluated using data from eight field experiments. The models include seven publicly available models (AFTOX, DEGADIS, HEGADAS, HGSYSTEM, INPUFF, OB/DG and SLAB), six proprietary models (AIRTOX, CHARM, FOCUS, GASTAR, PHAST and TRACE), and two "benchmark" analytical models (the Gaussian Plume Model and the analytical approximations to the Britter and McQuaid Workbook nomograms). The field data were divided into three groups—continuous dense gas releases (Burro LNG, Coyote LNG, Desert Tortoise NH 3-gas and aerosols, Goldfish HF-gas and aerosols, and Maplin Sands LNG), continuous passive gas releases (Prairie Grass and Hanford), and instantaneous dense gas releases (Thorney Island freon). The dense gas models that produced the most consistent predictions of plume centerline concentrations across the dense gas data sets are the Britter and McQuaid, CHARM, GASTAR, HEGADAS, HGSYSTEM, PHAST, SLAB and TRACE models, with relative mean biases of about ±30% or less and magnitudes of relative scatter that are about equal to the mean. The dense gas models tended to overpredict the plume widths and underpredict the plume depths by about a factor of two. All models except GASTAR, TRACE, and the area source version of DEGADIS perform fairly well with the continuous passive gas data sets. Some sensitivity studies were also carried out. It was found that three of the more widely used publicly-available dense gas models (DEGADIS, HGSYSTEM and SLAB) predicted increases in concentration of about 70% as roughness length decreased by an order of magnitude for the Desert Tortoise and Goldfish field studies. It was also found that none of the dense gas models that were considered came close to simulating the observed factor of two increase in peak concentrations as averaging time decreased from several minutes to 1 s. Because of their assumption that a concentrated dense gas core existed that was unaffected by variations in averaging time, the dense gas

  5. Core Accretion - Gas Capture Model for Gas Giant Planet Formation

    NASA Astrophysics Data System (ADS)

    Hubickyj, O.; Bodenheimer, P.; Lissauer, J. J.

    2005-12-01

    The core accretion - gas capture model is generally accepted as the standard formation model for gas giant planets. This model proposes that a solid core grows via the accretion of planetesimals and then captures a massive envelope from the solar nebula gas. Simulations based on this model (Pollack et al. 1996, Bodenheimer et al. 2000) have been successful in explaining many features of giant planets. We have computed simulations (Hubickyj et al. 2005) of the growth of Jupiter using various values for the opacity produced by grains in the protoplanet's atmosphere and for the initial planetesimal surface density in the protoplanetary disk. We also explore the implications of halting the solid accretion at selected core mass values during the protoplanet's growth. Halting planetesimal accretion at low core mass simulates the presence of a competing embryo, and decreasing the atmospheric opacity due to grains emulates the settling and coagulation of grains within the protoplanet's atmosphere. We examine the effects of adjusting these parameters to determine whether or not gas runaway can occur for small mass cores on a reasonable timescale. Our results demonstrate that reducing grain opacities results in formation times less than half of those for models computed with full interstellar grain opacity values. The reduction of opacity due to grains in the upper portion of the envelope with T ≤ 500 K has the largest effect on the lowering of the formation time. If the accretion of planetesimals is not cut off prior to the accretion of gas, then decreasing the surface density of planetesimals lowers the final core mass of the protoplanet, but increases the formation timescale considerably. Finally, a core mass cutoff results in a reduction of the time needed for a protoplanet to evolve to the stage of runaway gas accretion, provided the cutoff mass is sufficiently large. The overall results indicate that, with reasonable parameters, it is possible that Jupiter formed at

  6. Dairy gas emissions model: reference manual

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The Dairy Gas Emissions Model (DairyGEM) is a software tool for estimating ammonia, hydrogen sulfide, and greenhouse gas (GHG) emissions of dairy production systems as influenced by climate and farm management. A production system is defined to include emissions during the production of all feeds wh...

  7. Computational modeling of intraocular gas dynamics

    NASA Astrophysics Data System (ADS)

    Noohi, P.; Abdekhodaie, M. J.; Cheng, Y. L.

    2015-12-01

    The purpose of this study was to develop a computational model to simulate the dynamics of intraocular gas behavior in pneumatic retinopexy (PR) procedure. The presented model predicted intraocular gas volume at any time and determined the tolerance angle within which a patient can maneuver and still gas completely covers the tear(s). Computational fluid dynamics calculations were conducted to describe PR procedure. The geometrical model was constructed based on the rabbit and human eye dimensions. SF6 in the form of pure and diluted with air was considered as the injected gas. The presented results indicated that the composition of the injected gas affected the gas absorption rate and gas volume. After injection of pure SF6, the bubble expanded to 2.3 times of its initial volume during the first 23 h, but when diluted SF6 was used, no significant expansion was observed. Also, head positioning for the treatment of retinal tear influenced the rate of gas absorption. Moreover, the determined tolerance angle depended on the bubble and tear size. More bubble expansion and smaller retinal tear caused greater tolerance angle. For example, after 23 h, for the tear size of 2 mm the tolerance angle of using pure SF6 is 1.4 times more than that of using diluted SF6 with 80% air. Composition of the injected gas and conditions of the tear in PR may dramatically affect the gas absorption rate and gas volume. Quantifying these effects helps to predict the tolerance angle and improve treatment efficiency.

  8. Computational modeling of intraocular gas dynamics.

    PubMed

    Noohi, P; Abdekhodaie, M J; Cheng, Y L

    2015-12-18

    The purpose of this study was to develop a computational model to simulate the dynamics of intraocular gas behavior in pneumatic retinopexy (PR) procedure. The presented model predicted intraocular gas volume at any time and determined the tolerance angle within which a patient can maneuver and still gas completely covers the tear(s). Computational fluid dynamics calculations were conducted to describe PR procedure. The geometrical model was constructed based on the rabbit and human eye dimensions. SF6 in the form of pure and diluted with air was considered as the injected gas. The presented results indicated that the composition of the injected gas affected the gas absorption rate and gas volume. After injection of pure SF6, the bubble expanded to 2.3 times of its initial volume during the first 23 h, but when diluted SF6 was used, no significant expansion was observed. Also, head positioning for the treatment of retinal tear influenced the rate of gas absorption. Moreover, the determined tolerance angle depended on the bubble and tear size. More bubble expansion and smaller retinal tear caused greater tolerance angle. For example, after 23 h, for the tear size of 2 mm the tolerance angle of using pure SF6 is 1.4 times more than that of using diluted SF6 with 80% air. Composition of the injected gas and conditions of the tear in PR may dramatically affect the gas absorption rate and gas volume. Quantifying these effects helps to predict the tolerance angle and improve treatment efficiency.

  9. Modelling magmatic gas scrubbing in hydrothermal systems

    NASA Astrophysics Data System (ADS)

    Di Napoli, Rossella; Aiuppa, Alessandro; Valenza, Mariano; Bergsson, Baldur; Ilyinskaya, Evgenia; Pfeffer, Melissa Anne; Rakel Guðjónsdóttir, Sylvía

    2015-04-01

    In volcano-hosted hydrothermal systems, the chemistry of deeply rising magmatic gases is extensively modified by gas-water-rock interactions taking place within the hydrothermal reservoir, and/or at shallow groundwaters conditions. These reactions can scrub reactive, water-soluble species (S, halogens) from the magmatic gas phase, so that their quantitative assessment is central to understanding the chemistry of surface gas manifestations, and brings profound implications to the interpretation of volcanic-hydrothermal unrests. Here, we present the results of numerical simulations of magmatic gas scrubbing, in which the reaction path modelling approach (Helgeson, 1968) is used to reproduce hydrothermal gas-water-rock interactions at both shallow (temperature up to 109°C; low-T model runs) and deep reservoir (temperature range: 150-250 °C; high-T model runs) conditions. The model was built based upon the EQ3/6 software package (Wolery and Daveler, 1992), and consisted into a step by step addition of a high-temperature magmatic gas to an initial meteoric water, in the presence of a dissolving aquifer rock. The model outputted, at each step of gas addition, the chemical composition of a new aqueous solution formed after gas-water-rock interactions; which, upon reaching gas over-pressuring (PgasTOT > Psat(H2O) at run T), is degassed (by single-step degassing) to separate a scrubbed gas phase. As an application of the model results, the model compositions of the separated gases are finally compared with compositions of natural gas emissions from Hekla volcano (T< 100°C) and from Krisuvik geothermal system (T> 100°C), resulting into an excellent agreement. The compositions of the model solutions are also in fair agreement with compositions of natural thermal water samples. We conclude that our EQ3/6-based reaction path simulations offer a realistic representation of gas-water-rock interaction processes occurring underneath active magmatic-hydrothermal systems

  10. Adsorption Model for Off-Gas Separation

    SciTech Connect

    Veronica J. Rutledge

    2011-03-01

    The absence of industrial scale nuclear fuel reprocessing in the U.S. has precluded the necessary driver for developing the advanced simulation capability now prevalent in so many other countries. Thus, it is essential to model complex series of unit operations to simulate, understand, and predict inherent transient behavior and feedback loops. A capability of accurately simulating the dynamic behavior of advanced fuel cycle separation processes will provide substantial cost savings and many technical benefits. The specific fuel cycle separation process discussed in this report is the off-gas treatment system. The off-gas separation consists of a series of scrubbers and adsorption beds to capture constituents of interest. Dynamic models are being developed to simulate each unit operation involved so each unit operation can be used as a stand-alone model and in series with multiple others. Currently, an adsorption model has been developed in gPROMS software. Inputs include gas stream constituents, sorbent, and column properties, equilibrium and kinetic data, and inlet conditions. It models dispersed plug flow in a packed bed under non-isothermal and non-isobaric conditions for a multiple component gas stream. The simulation outputs component concentrations along the column length as a function of time from which the breakthrough data is obtained. It also outputs temperature along the column length as a function of time and pressure drop along the column length. Experimental data will be input into the adsorption model to develop a model specific for iodine adsorption on silver mordenite as well as model(s) specific for krypton and xenon adsorption. The model will be validated with experimental breakthrough curves. Another future off-gas modeling goal is to develop a model for the unit operation absorption. The off-gas models will be made available via the server or web for evaluation by customers.

  11. Comet Gas and Dust Dynamics Modeling

    NASA Technical Reports Server (NTRS)

    Von Allmen, Paul A.; Lee, Seungwon

    2010-01-01

    This software models the gas and dust dynamics of comet coma (the head region of a comet) in order to support the Microwave Instrument for Rosetta Orbiter (MIRO) project. MIRO will study the evolution of the comet 67P/Churyumov-Gerasimenko's coma system. The instrument will measure surface temperature, gas-production rates and relative abundances, and velocity and excitation temperatures of each species along with their spatial temporal variability. This software will use these measurements to improve the understanding of coma dynamics. The modeling tool solves the equation of motion of a dust particle, the energy balance equation of the dust particle, the continuity equation for the dust and gas flow, and the dust and gas mixture energy equation. By solving these equations numerically, the software calculates the temperature and velocity of gas and dust as a function of time for a given initial gas and dust production rate, and a dust characteristic parameter that measures the ability of a dust particle to adjust its velocity to the local gas velocity. The software is written in a modular manner, thereby allowing the addition of more dynamics equations as needed. All of the numerical algorithms are added in-house and no third-party libraries are used.

  12. Combustion modeling in advanced gas turbine systems

    SciTech Connect

    Smoot, L.D.; Hedman, P.O.; Fletcher, T.H.

    1995-10-01

    The goal of the U.S. Department of Energy`s Advanced Turbine Systems (ATS) program is to help develop and commercialize ultra-high efficiency, environmentally superior, and cost competitive gas turbine systems for base-load applications in the utility, independent power producer, and industrial markets. Combustion modeling, including emission characteristics, has been identified as a needed, high-priority technology by key professionals in the gas turbine industry.

  13. GAS eleven node thermal model (GEM)

    NASA Technical Reports Server (NTRS)

    Butler, Dan

    1988-01-01

    The Eleven Node Thermal Model (GEM) of the Get Away Special (GAS) container was originally developed based on the results of thermal tests of the GAS container. The model was then used in the thermal analysis and design of several NASA/GSFC GAS experiments, including the Flight Verification Payload, the Ultraviolet Experiment, and the Capillary Pumped Loop. The model description details the five cu ft container both with and without an insulated end cap. Mass specific heat values are also given so that transient analyses can be performed. A sample problem for each configuration is included as well so that GEM users can verify their computations. The model can be run on most personal computers with a thermal analyzer solution routine.

  14. International Natural Gas Model 2011, Model Documentation Report

    EIA Publications

    2013-01-01

    This report documents the objectives, analytical approach and development of the International Natural Gas Model (INGM). It also catalogues and describes critical assumptions, computational methodology, parameter estimation techniques, and model source code.

  15. World Energy Projection System Plus Model Documentation: Natural Gas Model

    EIA Publications

    2011-01-01

    This report documents the objectives, analytical approach and development of the World Energy Projection System Plus (WEPS ) Natural Gas Model. It also catalogues and describes critical assumptions, computational methodology, parameter estimation techniques, and model source code.

  16. Performance Evaluation of Dense Gas Dispersion Models.

    NASA Astrophysics Data System (ADS)

    Touma, Jawad S.; Cox, William M.; Thistle, Harold; Zapert, James G.

    1995-03-01

    This paper summarizes the results of a study to evaluate the performance of seven dense gas dispersion models using data from three field experiments. Two models (DEGADIS and SLAB) are in the public domain and the other five (AIRTOX, CHARM, FOCUS, SAFEMODE, and TRACE) are proprietary. The field data used are the Desert Tortoise pressurized ammonia releases, Burro liquefied natural gas spill tests, and the Goldfish anhydrous hydrofluoric acid spill experiments. Desert Tortoise and Goldfish releases were simulated as horizontal jet releases, and Burro as a liquid pool. Performance statistics were used to compare maximum observed concentrations and plume half-width to those predicted by each model. Model performance varied and no model exhibited consistently good performance across all three databases. However, when combined across the three databases, all models performed within a factor of 2. Problems encountered are discussed in order to help future investigators.

  17. Modeling internal ballistics of gas combustion guns.

    PubMed

    Schorge, Volker; Grossjohann, Rico; Schönekess, Holger C; Herbst, Jörg; Bockholdt, Britta; Ekkernkamp, Axel; Frank, Matthias

    2016-05-01

    Potato guns are popular homemade guns which work on the principle of gas combustion. They are usually constructed for recreational rather than criminal purposes. Yet some serious injuries and fatalities due to these guns are reported. As information on the internal ballistics of homemade gas combustion-powered guns is scarce, it is the aim of this work to provide an experimental model of the internal ballistics of these devices and to investigate their basic physical parameters. A gas combustion gun was constructed with a steel tube as the main component. Gas/air mixtures of acetylene, hydrogen, and ethylene were used as propellants for discharging a 46-mm caliber test projectile. Gas pressure in the combustion chamber was captured with a piezoelectric pressure sensor. Projectile velocity was measured with a ballistic speed measurement system. The maximum gas pressure, the maximum rate of pressure rise, the time parameters of the pressure curve, and the velocity and path of the projectile through the barrel as a function of time were determined according to the pressure-time curve. The maximum gas pressure was measured to be between 1.4 bar (ethylene) and 4.5 bar (acetylene). The highest maximum rate of pressure rise was determined for hydrogen at (dp/dt)max = 607 bar/s. The muzzle energy was calculated to be between 67 J (ethylene) and 204 J (acetylene). To conclude, this work provides basic information on the internal ballistics of homemade gas combustion guns. The risk of injury to the operator or bystanders is high, because accidental explosions of the gun due to the high-pressure rise during combustion of the gas/air mixture may occur.

  18. Modeling gas transport in the Martian subsurface

    NASA Astrophysics Data System (ADS)

    Gloesener, Elodie; Karatekin, Özgür; Dehant, Véronique

    2015-04-01

    Modeling gas transport through Martian subsurface and outgassing processes is essential in the study of atmospheric evolution of Mars. We present an overview of gas transport in Martian soil focusing on water vapor and methane diffusion to explain the recent observations of methane in Martian atmosphere with a diffusive transport model. The range of parameters that have the largest effect on transport in Martian conditions is investigated. Among the possible sources of methane, clathrate hydrates destabilization is one potential mechanism. Hydrate stability zone in subsurface is also investigated. In 2016, ExoMars Trace Gas Orbiter (TGO) will have the capabilities to detect and characterize trace gases in Martian atmosphere and will bring additional information to validate the different possible outgassing scenarios.

  19. Statistical Modeling Efforts for Headspace Gas

    SciTech Connect

    Weaver, Brian Phillip

    2016-03-17

    The purpose of this document is to describe the statistical modeling effort for gas concentrations in WIPP storage containers. The concentration (in ppm) of CO2 in the headspace volume of standard waste box (SWB) 68685 is shown. A Bayesian approach and an adaptive Metropolis-Hastings algorithm were used.

  20. Lattice gas models with long range interactions

    NASA Astrophysics Data System (ADS)

    Aristoff, David; Zhu, Lingjiong

    2017-02-01

    We study microcanonical lattice gas models with long range interactions, including power law interactions. We rigorously obtain a variational principle for the entropy. In a one dimensional example, we find a first order phase transition by proving the entropy is non-differentiable along a certain curve.

  1. A varying polytropic gas universe and phase space analysis

    NASA Astrophysics Data System (ADS)

    Khurshudyan, M.

    2016-05-01

    In this paper, we will consider a phenomenological model of a dark fluid that is able to explain an accelerated expansion of our low redshift universe and the phase transition to this accelerated expanding universe. Recent developments in modern cosmology towards understanding of the accelerated expansion of the large scale universe involve various scenarios and approaches. Among these approaches, one of well-known and accepted practice is modeling of the content of our universe via dark fluid. There are various models of dark energy fluid actively studied in recent literature and polytropic gas is among them. In this work, we will consider a varying polytropic gas which is a phenomenological modification of polytropic gas. Our model of varying polytropic dark fluid has been constructed to analogue to a varying Chaplygin gas actively discussed in the literature. We will consider interacting models, where dark matter is a pressureless fluid, to have a comprehensive picture. Phase space analysis is an elegant mathematical tool to earn general understanding of large scale universe and easily see an existence of a solution to cosmological coincidence problem. Imposing some constraints on parameters of the models, we found late time attractors for each case analytically. Cosmological consequences for the obtained late time attractors are discussed.

  2. Theoretical models for trace gas preconcentrators

    NASA Astrophysics Data System (ADS)

    Kim, Jihyun

    2013-11-01

    Muntz et al., in 2004 and 2011, had attempted to describe theoretical models about the shape of a main flow channel and the concentration ratio of trace gas for a Continuous Flow-Through Trace Gas Preconcentrator by concepts of net flux and mass flow rate respectively. The possibilities were suggested to obtain theoretical models for the preconcentrator even through they were not satisfied with experimental results, because the theoretical models were only considered for free molecular flow. In this study, new theoretical models based on net flux and mass flow rate have been applied for each regime; free molecular flow, transition flow, and hydrodynamic flow. There are comprehensive numerical models to describe entire regimes with the new theoretical models induced by mass flow rate, but the new theoretical models induced by net flux can be only obtained for the hydrodynamic flow. The numerical predictions were compared with existing experimental results of the prototype of the preconcentrator. The numerical predictions of hydrodynamic and transition flows by mass flow rate were close to the experimental results, but other cases were different to the experimental data. Nevertheless, the theoretical models can provide the possibility to develop the theory of preconcentrator.

  3. Multisite Interactions in Lattice-Gas Models

    NASA Astrophysics Data System (ADS)

    Einstein, T. L.; Sathiyanarayanan, R.

    For detailed applications of lattice-gas models to surface systems, multisite interactions often play at least as significant a role as interactions between pairs of adatoms that are separated by a few lattice spacings. We recall that trio (3-adatom, non-pairwise) interactions do not inevitably create phase boundary asymmetries about half coverage. We discuss a sophisticated application to an experimental system and describe refinements in extracting lattice-gas energies from calculations of total energies of several different ordered overlayers. We describe how lateral relaxations complicate matters when there is direct interaction between the adatoms, an issue that is important when examining the angular dependence of step line tensions. We discuss the connector model as an alternative viewpoint and close with a brief account of recent work on organic molecule overlayers.

  4. Chemical Dense Gas Modeling in Cities

    NASA Astrophysics Data System (ADS)

    Brown, M. J.; Williams, M. D.; Nelson, M. A.; Streit, G. E.

    2007-12-01

    Many industrial facilities have on-site storage of chemicals and are within a few kilometers of residential population. Chemicals are transported around the country via trains and trucks and often go through populated areas on their journey. Many of the chemicals, like chlorine and phosgene, are toxic and when released into the air are heavier-than-air dense gases that hug the ground and result in high airborne concentrations at breathing level. There is considerable concern about the vulnerability of these stored and transported chemicals to terrorist attack and the impact a release could have on highly-populated urban areas. There is the possibility that the impacts of a dense gas release within a city would be exacerbated since the buildings might act to trap the toxic cloud at street level and channel it over a large area down side streets. However, no one is quite sure what will happen for a release in cities since there is a dearth of experimental data. There are a number of fast-running dense gas models used in the air pollution and emergency response community, but there are none that account for the complex flow fields and turbulence generated by buildings. As part of this presentation, we will discuss current knowledge regarding dense gas releases around buildings and other obstacles. We will present information from wind tunnel and field experiments, as well as computational fluid dynamics modeling. We will also discuss new fast response modeling efforts which are trying to account for dense gas transport and dispersion in cities.

  5. Gas flow modelling through clay and claystones

    NASA Astrophysics Data System (ADS)

    Alonso, E.

    2012-12-01

    Large scale gas flow experiments conducted in connection with nuclear waste disposal research have shown the dominant effect of "minor" details such as interfaces, contacts and layer boundaries. Even if the scale of the analysis is highly reduced, in search of homogeneous point-like conditions, a systematic development of preferential paths is very often reported. Small size samples become boundary value problems. Preferential paths, when their thickness is modified by the stress-strain response of the media, under the combined action of stress and fluid pressure changes, become highly conductive features for gas flow. The development of preferential paths for fluid flow has been approached in a simple manner by embedding a discontinuity feature into an otherwise continuous element which models clay or claystone matrix behavior. The joint is activated when tensile strains develop in the continuous element. Then, hydraulic properties (permeability, retention behavior) are modified by means of laws derived from the physics of flow in discontinuities. The outlined idea was incorporated into a full Thermo-Hydro-Mechanical finite element code (CODE_BRIGHT) which has a wide range of capabilities for the modeling of two-phase flow in elasto-viscoplastic porous materials. A particular aspect which required attention is the modeling of expansive and shrinkage behavior induced by suction changes. In this way, healing effects during re-saturation may be simulated. Two experimental programs on clay shale samples, performed under triaxial stress conditions will be discussed. In the first case samples of Opalinus shale were subjected to a series of gas pulse decay tests during the application of stress paths involving a particular sequence of confining stress and shearing up to failure. In the second experimental program, performed on a tertiary mudstone from the Norwegian shelf, attention was paid to the effect of bedding-induced anisotropy. Experimental results will be

  6. Kinetic Global Modeling of Rare Gas Lasers

    NASA Astrophysics Data System (ADS)

    Parsey, Guy; Verboncoeur, John; Christlieb, Andrew

    2016-10-01

    Akin to diode-pumped alkali metal lasers, electronically excited states of rare gases (e.g. Ar and Kr) have been shown to operate as chemically inert three-level gain media for an optically pumped laser system. As opposed to vaporization heating, these systems rely on electric discharge to efficiently maintain a population of metastable states acting as the bottom laser level. We propose that a modified electron energy distribution (EEDF) in the electric heating can tune optically pumped rare gas laser (OPRGL) efficiencies. The EEDF factors into all plasma phase chemistry within the underlying reaction network, and is assumed to be maintained by discharge and electron sources. Using parameter scanning methods within the kinetic global modeling framework (KGMf), optimized EEDFs are found for metastable production and increasing OPRGL operational efficiencies. Finally, we investigate the feasibility of using a modified EEDF to drive a rare gas laser system without optical pumping. Supported by AFOSR and an MSU SPG.

  7. Reservoir model for Hillsboro gas storage field management

    USGS Publications Warehouse

    Udegbunam, Emmanuel O.; Kemppainen, Curt; Morgan, Jim; ,

    1995-01-01

    A 3-dimensional reservoir model is used to understand the behavior of the Hillsboro Gas Storage Field and to investigate the field's performance under various future development. Twenty-two years of the gas storage reservoir history, comprising the initial gas bubble development and seasonal gas injection and production cycles, are examined with a full-field, gas water, reservoir simulation model. The results suggest that the gas-water front is already in the vicinity of the west observation well that increasing the field's total gas-in-place volume would cause gas to migrate beyond the east, north and west observation well. They also suggest that storage enlargement through gas injection into the lower layers may not prevent gas migration. Moreover, the results suggest that the addition of strategically-located new wells would boost the simulated gas deliverabilities.

  8. Laboratory model of gas microchromatograph: construction and testing

    NASA Astrophysics Data System (ADS)

    Mroz, Jerzy; Szczygielska, Malgorzata; Dziuban, Jan; Gorecka-Drzazga, Anna

    2001-08-01

    The paper describes the microsystems for total chemical analysis and the structure of a gas microchromatograph. The construction and technical data of capillary micro column of thermo conducting detector and gas microvalve are also described. The paper refers to the test of a model of gas micro chromatography, the analyses of gas samples and presents the exemplary chromatograms.

  9. Integrated Belowground Greenhouse Gas Flux Modeling (Invited)

    NASA Astrophysics Data System (ADS)

    Davidson, E. A.; Savage, K. E.

    2013-12-01

    Soil greenhouse gas (GHG) emissions play a significant role as biotic feedbacks to climate change. However, these complex processes, involving C, N, and O2 substrates and inhibitors, interactions with plant processes, and environmental influences of temperature, moisture, and gas transport, remain challenging to simulate in process models. Because CO2, CH4, and N2O production and consumption processes are inter-linked through common substrates and the contrasting effects of O2 as either an essential substrate or a potential inhibitor, the simulation of fluxes of any one gas must be consistent with mechanistic simulations and observations of fluxes of the other gases. Simulating the fluxes of one gas alone is a simpler task, but simulating all three gases simultaneously would provide multiple constraints and would afford greater confidence that the most important mechanisms are aptly simulated. A case in point is the challenge of resolving the apparent paradox of observed simultaneous CO2 production by aerobic respiration, CH4 uptake (oxidation), CH4 production, and N2O uptake (reduction) in the same soil profile. Consumption of atmospheric N2O should occur only under reducing conditions, and yet we have observed uptake of atmospheric CH4 (oxidation) and N2O (reduction) simultaneously. One of the great challenges of numerical modeling is determining the appropriate level of complexity when representing the most important environmental controllers. Ignoring complexity, such as simulating microbial processes with only simple Q10 functions, often results in poor model performance, because soil moisture and substrate supply can also be important factors. On the other hand, too much complexity, while perhaps mechanistically compelling, may result in too many poorly constrained parameters. Here we explore a parsimonious modeling framework for consistently integrated mechanistic and mathematical representation of the biophysical processes of belowground GHG production and

  10. A topological classification of the Chaplygin systems in the dynamics of a rigid body in a fluid

    SciTech Connect

    Nikolaenko, S S

    2014-02-28

    The paper is concerned with the topological analysis of the Chaplygin integrable case in the dynamics of a rigid body in a fluid. A full list of the topological types of Chaplygin systems in their dependence on the energy level is compiled on the basis of the Fomenko-Zieschang theory. An effective description of the topology of the Liouville foliation in terms of natural coordinate variables is also presented, which opens a direct way to calculating topological invariants. It turns out that on all nonsingular energy levels Chaplygin systems are Liouville equivalent to the well-known Euler case in the dynamics of a rigid body with fixed point. Bibliography: 23 titles.

  11. The Dairy Greenhouse Gas Emission Model: Reference Manual

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The Dairy Greenhouse Gas Model (DairyGHG) is a software tool for estimating the greenhouse gas emissions and carbon footprint of dairy production systems. A relatively simple process-based model is used to predict the primary greenhouse gas emissions, which include the net emission of carbon dioxide...

  12. Stochastic Modeling of Buoyancy driven Gas Flow Pattern: Can Continuum Models describe Channelized Gas Flow?

    NASA Astrophysics Data System (ADS)

    Geistlinger, H. W.; Samani, S.

    2010-12-01

    The injection of gases into the subsurface has become an important research topic in groundwater remediation technology, e.g. air sparging, and in CCS-technology, e.g. CO2-sequestration into saline aquifers. In both cases risk assessment is based on 2-phase flow modeling assuming that the stochastic gas flow patterns can be described by the continuum approach. As Cinar et al. (2009) have stated: “The fundamental understanding of drainage, as it applies to CO2 sequestration process, is limited primarily by the lack of well characterized experiments that allow a detailed classification of the microscopic flow regimes”. In case of air sparging the two important flow regimes are capillary fingering and viscous fingering. Using pore scale network modeling Ewing and Berkowitz (1998) were able to describe the transition from capillary fingering (= incoherent channelized flow) to viscous fingering (= coherent channelized flow). In order to investigate the stability of buoyancy-driven gas flow and the transition between coherent channelized flow and incoherent channelized flow we conducted high-resolution optical bench scale experiments. Our main results, which are in strong contradiction to the commonly used continuum models (CM) are: (1) Capillary trapping can already occur during injection and at the front of the plume (Lazik and Geistlinger, 2008) (2) Gas clusters or bubbles can be mobile (incoherent gas flow) and immobile (capillary trapping), and (3) Incoherent gas flow can not be described by a generalized Darcy law (Geistlinger et al., 2006, 2009). Glass et al. (2000) conducted CO2-gas injection experiments. Based on their experimental results they also questioned the validity of CM to describe coherent and incoherent gas flow and the validity of homogeneous stability analysis to predict channel width, channel number and channel velocity in heterogeneous porous media. Despite these findings there is an ongoing controversial discussion in the literature about

  13. Modeling Gas Distribution in Protoplanetary Accretion Disks

    NASA Astrophysics Data System (ADS)

    Kronberg, Martin; Lewis, Josiah; Brittain, Sean

    2010-07-01

    Protoplanetary accretion disks are disks of dust and gas which surround and feed material onto a forming star in the earliest stages of its evolution. One of the most useful methods for studying these disks is near infrared spectroscopy of rovibrational CO emission. This paper presents the methods in which synthetically generated spectra are modeled and fit to spectral data gathered from protoplanetary disks. This paper also discussed the methods in which this code can be improved by modifying the code to run a Monte Carlo analysis of best fit across the CONDOR cluster at Clemson University, thereby allowing for the creation of a catalog of protoplanetary disks with detailed information about them as gathered from the model.

  14. A modeling of buoyant gas plume migration

    SciTech Connect

    Silin, D.; Patzek, T.; Benson, S.M.

    2008-12-01

    This work is motivated by the growing interest in injecting carbon dioxide into deep geological formations as a means of avoiding its atmospheric emissions and consequent global warming. Ideally, the injected greenhouse gas stays in the injection zone for a geologic time, eventually dissolves in the formation brine and remains trapped by mineralization. However, one of the potential problems associated with the geologic method of sequestration is that naturally present or inadvertently created conduits in the cap rock may result in a gas leakage from primary storage. Even in a supercritical state, the carbon dioxide viscosity and density are lower than those of the formation brine. Buoyancy tends to drive the leaked CO{sub 2} plume upward. Theoretical and experimental studies of buoyancy-driven supercritical CO{sub 2} flow, including estimation of time scales associated with plume evolution and migration, are critical for developing technology, monitoring policy, and regulations for safe carbon dioxide geologic sequestration. In this study, we obtain simple estimates of vertical plume propagation velocity taking into account the density and viscosity contrast between CO{sub 2} and brine. We describe buoyancy-driven countercurrent flow of two immiscible phases by a Buckley-Leverett type model. The model predicts that a plume of supercritical carbon dioxide in a homogeneous water-saturated porous medium does not migrate upward like a bubble in bulk water. Rather, it spreads upward until it reaches a seal or until it becomes immobile. A simple formula requiring no complex numerical calculations describes the velocity of plume propagation. This solution is a simplification of a more comprehensive theory of countercurrent plume migration (Silin et al., 2007). In a layered reservoir, the simplified solution predicts a slower plume front propagation relative to a homogeneous formation with the same harmonic mean permeability. In contrast, the model yields much higher

  15. Coordinated scheduling of electricity and natural gas infrastructures with a transient model for natural gas flow.

    PubMed

    Liu, Cong; Shahidehpour, Mohammad; Wang, Jianhui

    2011-06-01

    This paper focuses on transient characteristics of natural gas flow in the coordinated scheduling of security-constrained electricity and natural gas infrastructures. The paper takes into account the slow transient process in the natural gas transmission systems. Considering their transient characteristics, natural gas transmission systems are modeled as a set of partial differential equations (PDEs) and algebraic equations. An implicit finite difference method is applied to approximate PDEs by difference equations. The coordinated scheduling of electricity and natural gas systems is described as a bi-level programming formulation from the independent system operator's viewpoint. The objective of the upper-level problem is to minimize the operating cost of electric power systems while the natural gas scheduling optimization problem is nested within the lower-level problem. Numerical examples are presented to verify the effectiveness of the proposed solution and to compare the solutions for steady-state and transient models of natural gas transmission systems.

  16. Modeling gas-dust interactions in debris disks

    NASA Astrophysics Data System (ADS)

    Richert, Alex J. W.; Kuchner, Marc J.; Lyra, Wladimir

    2017-01-01

    The discovery of gas in debris disks has raised the question of whether gas-dust interactions can observably affect global disk structure. This has important implications for identifying planets in debris disks, as well as probing dust grain composition, which is key to understanding the habitability of planetary systems. In this dissertation talk, I present two-dimensional global hydrodynamical models of debris disks with gas and discuss the effects of the gas on the global distribution of the dust.

  17. Modeling of heavy-gas effects on airfoil flows

    NASA Technical Reports Server (NTRS)

    Drela, Mark

    1992-01-01

    Thermodynamic models were constructed for a calorically imperfect gas and for a non-ideal gas. These were incorporated into a quasi one dimensional flow solver to develop an understanding of the differences in flow behavior between the new models and the perfect gas model. The models were also incorporated into a two dimensional flow solver to investigate their effects on transonic airfoil flows. Specifically, the calculations simulated airfoil testing in a proposed high Reynolds number heavy gas test facility. The results indicate that the non-idealities caused significant differences in the flow field, but that matching of an appropriate non-dimensional parameter led to flows similar to those in air.

  18. Adsorption modeling for off-gas treatment

    SciTech Connect

    Ladshaw, A.; Sharma, K.; Yiacoumi, S.; Tsouris, C.; De Paoli, D.W.

    2013-07-01

    Off-gas generated from the reprocessing of used nuclear fuel contains a mixture of several radioactive gases including {sup 129}I{sub 2}, {sup 85}Kr, HTO, and {sup 14}CO{sub 2}. Over the past few decades, various separation and recovery processes have been studied for capturing these gases. Adsorption data for gaseous mixtures of species can be difficult to determine experimentally. Therefore, procedures capable of predicting the adsorption behavior of mixtures need to be developed from the individual isotherms of each of the pure species. A particular isotherm model of interest for the pure species is the Generalized Statistical Thermodynamic Adsorption isotherm. This model contains an adjustable number of parameters and will therefore describe a wide range of adsorption isotherms for a variety of components. A code has been developed in C++ to perform the non-linear regression analysis necessary for the determination of the isotherm parameters, as well as the least number of parameters needed to describe an entire set of data. (authors)

  19. GASCAP: Wellhead Gas Productive Capacity Model documentation, June 1993

    SciTech Connect

    Not Available

    1993-07-01

    The Wellhead Gas Productive Capacity Model (GASCAP) has been developed by EIA to provide a historical analysis of the monthly productive capacity of natural gas at the wellhead and a projection of monthly capacity for 2 years into the future. The impact of drilling, oil and gas price assumptions, and demand on gas productive capacity are examined. Both gas-well gas and oil-well gas are included. Oil-well gas productive capacity is estimated separately and then combined with the gas-well gas productive capacity. This documentation report provides a general overview of the GASCAP Model, describes the underlying data base, provides technical descriptions of the component models, diagrams the system and subsystem flow, describes the equations, and provides definitions and sources of all variables used in the system. This documentation report is provided to enable users of EIA projections generated by GASCAP to understand the underlying procedures used and to replicate the models and solutions. This report should be of particular interest to those in the Congress, Federal and State agencies, industry, and the academic community, who are concerned with the future availability of natural gas.

  20. 3D modeling of gas/water distribution in water-bearing carbonate gas reservoirs: the Longwangmiao gas field, China

    NASA Astrophysics Data System (ADS)

    Ou, Chenghua; Li, ChaoChun; Ma, Zhonggao

    2016-10-01

    A water-bearing carbonate gas reservoir is an important natural gas resource being developed worldwide. Due to the long-term water/rock/gas interaction during geological evolution, complex gas/water distribution has formed under the superposed effect of sedimentary facies, reservoir space facies and gravity difference of fluid facies. In view of these challenges, on the basis of the conventional three-stage modeling method, this paper presents a modelling method controlled by four-stage facies to develop 3D model of a water-bearing carbonate gas reservoir. Key to this method is the reservoir property modelling controlled by two-stage facies, and the fluid property modelling controlled by another two-stage facies. The prerequisite of this method is a reliable database obtained from solid geological investigation. On the basis of illustrating the principles of the modelling method controlled by four-stage facies, this paper further implements systematically modeling of the heterogeneous gas/water distribution of the Longwangmiao carbonate formation in the Moxi-Gaoshiti area, Sichuan basin, China.

  1. Modeling of Fission Gas Release in UO2

    SciTech Connect

    MH Krohn

    2006-01-23

    A two-stage gas release model was examined to determine if it could provide a physically realistic and accurate model for fission gas release under Prometheus conditions. The single-stage Booth model [1], which is often used to calculate fission gas release, is considered to be oversimplified and not representative of the mechanisms that occur during fission gas release. Two-stage gas release models require saturation at the grain boundaries before gas is release, leading to a time delay in release of gases generated in the fuel. Two versions of a two-stage model developed by Forsberg and Massih [2] were implemented using Mathcad [3]. The original Forsbers and Massih model [2] and a modified version of the Forsberg and Massih model that is used in a commercially available fuel performance code (FRAPCON-3) [4] were examined. After an examination of these models, it is apparent that without further development and validation neither of these models should be used to calculate fission gas release under Prometheus-type conditions. There is too much uncertainty in the input parameters used in the models. In addition. the data used to tune the modified Forsberg and Massih model (FRAPCON-3) was collected under commercial reactor conditions, which will have higher fission rates relative to Prometheus conditions [4].

  2. Modeling structure-function interdependence of pulmonary gas exchange.

    PubMed

    Weibel, Ewald R

    2008-01-01

    Modeling functional processes, such as gas exchange, that occur deep in the lung far from where one can directly observe, depends on knowledge about the precise and quantitative design of the structure of the gas exchanger. This is the case as well for the actual arrangement of alveoli and blood capillaries at the gas exchange surface as for the disposition of gas exchange units with respect to the airway and vascular trees. The serial arrangement of alveoli and their perfusion as parallel units have important consequences for gas exchange.

  3. Modeling biogenic gas bubbles formation and migration in coarse sand

    NASA Astrophysics Data System (ADS)

    Ye, S.

    2011-12-01

    Shujun Ye Department of Hydrosciences, School of Earth Sciences and Engineering, Nanjing University, Nanjing 210093, China; sjye@nju.edu.cn Brent E. Sleep Department of Civil Engineering, University of Toronto, Toronto, ON, M5S 1A4 CANADA; sleep@ecf.utoronto.ca Methane gas generation in porous media was investigated in an anaerobic two-dimensional sand-filled cell. Inoculation of the lower portion of the cell with a methanogenic culture and addition of methanol to the bottom of the cell led to biomass growth and formation of a gas phase. The formation, migration, distribution and saturation of gases in the cell were visualized by the charge-coupled device (CCD) camera. Gas generated at the bottom of the cell in the biologically active zone moved upwards in discrete fingers, so that gas phase saturations (gas-filled fraction of void space) in the biologically active zone at the bottom of the cell did not exceed 40-50%, while gas accumulation at the top of the cell produced gas phase saturations as high as 80%. Macroscopic invasion percolation (MIP) at near pore scale[Glass, et al., 2001; Kueper and McWhorter, 1992]was used to model gas bubbles growth in porous media. The nonwetting phase migration pathway can be yielded directly by MIP. MIP was adopted to simulate the expansion, fragmentation, and mobilization of gas clusters in the cell. The production of gas, and gas phash saturations were simulated by a continuum model - compositional simulator (COMPSIM) [Sleep and Sykes, 1993]. So a combination of a continuum model and a MIP model was used to simulate the formation, fragmentation and migration of biogenic gas bubbles. Key words: biogenic gas; two dimensional; porous media; MIP; COMPSIM

  4. PC Windows finite element modeling of landfill gas flow

    SciTech Connect

    Mull, S.R.; Lang, R.J.; Vigil, S.A.; Cota, H.

    1996-09-01

    A two dimensional demonstration program, GAS, has been developed for the solution of landfill gas (LFG) flow problems on a personal computer (PC). The program combines a Windows{trademark} graphical user interface, object oriented programming (OOP) techniques, and finite element modeling (FEM) to demonstrate the practicality of performing LFG flow modeling on the PC. GAS is demonstrated on a sample LFG problem consisting of a landfill, one gas extraction well, the landfill liner, cap, and surrounding soil. Analyses of the program results are performed for successively finer grid resolutions. Element flux imbalance, execution time, and required memory are characterized as a function of grid resolution.

  5. Modeling the Phase Composition of Gas Condensate in Pipelines

    NASA Astrophysics Data System (ADS)

    Dudin, S. M.; Zemenkov, Yu D.; Shabarov, A. B.

    2016-10-01

    Gas condensate fields demonstrate a number of thermodynamic characteristics to be considered when they are developed, as well as when gas condensate is transported and processed. A complicated phase behavior of the gas condensate system, as well as the dependence of the extracted raw materials on the phase state of the deposit other conditions being equal, is a key aspect. Therefore, when designing gas condensate lines the crucial task is to select the most appropriate methods of calculating thermophysical properties and phase equilibrium of the transported gas condensate. The paper describes a physical-mathematical model of a gas-liquid flow in the gas condensate line. It was developed based on balance equations of conservation of mass, impulse and energy of the transported medium within the framework of a quasi-1D approach. Constitutive relationships are given separately, and practical recommendations on how to apply the research results are provided as well.

  6. Development of a gas systems analysis model (GSAM)

    SciTech Connect

    Godec, M.L.

    1995-04-01

    The objectives of developing a Gas Systems Analysis Model (GSAM) are to create a comprehensive, non-proprietary, PC based model of domestic gas industry activity. The system is capable of assessing the impacts of various changes in the natural gas system within North America. The individual and collective impacts due to changes in technology and economic conditions are explicitly modeled in GSAM. Major gas resources are all modeled, including conventional, tight, Devonian Shale, coalbed methane, and low-quality gas sources. The modeling system asseses all key components of the gas industry, including available resources, exploration, drilling, completion, production, and processing practices, both for now and in the future. The model similarly assesses the distribution, storage, and utilization of natural gas in a dynamic market-based analytical structure. GSAM is designed to provide METC managers with a tool to project the impacts of future research, development, and demonstration (RD&D) benefits in order to determine priorities in a rapidly changing, market-driven gas industry.

  7. Model documentation: Natural gas transmission and distribution model of the National Energy Modeling System. Volume 1

    SciTech Connect

    1995-02-17

    The Natural Gas Transmission and Distribution Model (NGTDM) is the component of the National Energy Modeling System (NEMS) that is used to represent the domestic natural gas transmission and distribution system. NEMS was developed in the Office of integrated Analysis and Forecasting of the Energy information Administration (EIA). NEMS is the third in a series of computer-based, midterm energy modeling systems used since 1974 by the EIA and its predecessor, the Federal Energy Administration, to analyze domestic energy-economy markets and develop projections. The NGTDM is the model within the NEMS that represents the transmission, distribution, and pricing of natural gas. The model also includes representations of the end-use demand for natural gas, the production of domestic natural gas, and the availability of natural gas traded on the international market based on information received from other NEMS models. The NGTDM determines the flow of natural gas in an aggregate, domestic pipeline network, connecting domestic and foreign supply regions with 12 demand regions. The methodology employed allows the analysis of impacts of regional capacity constraints in the interstate natural gas pipeline network and the identification of pipeline capacity expansion requirements. There is an explicit representation of core and noncore markets for natural gas transmission and distribution services, and the key components of pipeline tariffs are represented in a pricing algorithm. Natural gas pricing and flow patterns are derived by obtaining a market equilibrium across the three main elements of the natural gas market: the supply element, the demand element, and the transmission and distribution network that links them. The NGTDM consists of four modules: the Annual Flow Module, the Capacity F-expansion Module, the Pipeline Tariff Module, and the Distributor Tariff Module. A model abstract is provided in Appendix A.

  8. Estatística de lentes gravitacionais e o gás de chaplygin generalizado

    NASA Astrophysics Data System (ADS)

    Oliveira, A. L. S.

    2003-08-01

    A estatística de lentes gravitacionais constitui uma poderosa ferramenta utilizada na obtenção de vínculos sobre parâmetros cosmológicos, principalmente sobre modelos com uma constante cosmológica. Embora de forma às vezes controversa, antes de 1998, a análise tradicional mostrava que modelos com o parâmetro de densidade da matéria da ordem da unidade são preferidos. Esse resultado começou a ser questionado, alguns anos atrás, com as indicações, advindas da análise de supernovas com alto valor de desvio para o vermelho, de que nosso Universo está acelerando. Atualmente há enorme interesse em saber qual é a natureza da componente responsável pela aceleração cósmica. Energia escura é a denominação usual dessa componente e sua característica principal é possuir pressão negativa. Nos modelos cosmológicos tradicionais, além da energia escura, considera-se também uma outra componente de origem desconhecida. Ela é denominada matéria escura e possui pressão nula. Mais recentemente modelos unificadores em que energia escura e matéria escura são manifestações distintas de um mesmo fluido (altas densidades matéria escura, baixas densidades energia escura) foram sugeridos. Um desses modelos é conhecido como Gás de Chaplygin Generalizado que é o modelo que investigaremos. Em nosso trabalho apresentamos vínculos sobre parâmetros desse modelo usando a estatística de lentes gravitacionais. Usamos observações de quasares na faixa do visível e consideramos extinção em nosso estudo. Análises semelhantes anteriores com esse tipo de objetos e que não consideram extinção são inconsistentes. Comparação dos vínculos obtidos através de lentes gravitacionais com outros advindos de outros testes será também apresentada.

  9. Common inconsistencies in modeling gas transport in porous electrodes: The dusty-gas model and the Fick law

    NASA Astrophysics Data System (ADS)

    Bertei, A.; Nicolella, C.

    2015-04-01

    The paper shows as two assumptions typically made in modeling gas transport in solid oxide fuel cell electrodes, i.e., a) uniform pressure in the dusty-gas model, and b) validity of the Bosanquet formula in the Fick model, may lead to serious inconsistencies (such as molar fractions that do not sum up to one or fluxes that do not obey reaction stoichiometry), thus nullifying the efforts of the mechanistic modeling of transport phenomena. The nature of the inconsistent use of the models is explained with clear examples, then the correct implementation of the gas transport models is discussed. The study aims to promote a coherent physically-based modeling of gas transport phenomena in porous electrodes in order to assist their rational design.

  10. Physical modeling of gas dispersion over urban area

    NASA Astrophysics Data System (ADS)

    Michálek, Petr; Zacho, David

    2016-06-01

    Experimental study of gas dispersion over urban area model was conducted in boundary layer wind tunnel in VZLU Prague. A scale model of urban area near the Centre of Liberec was made and dispersion of gas emissions from nearby heating plant was measured. The measurements included velocity field and concentration field by means of hot wire anemometer and flame ionization detector. The purpose of this work was to validate and verify a new computational dispersion model, which was developed in VZLU.

  11. Comparison of effective medium models for marine gas hydrate templates

    NASA Astrophysics Data System (ADS)

    Terry, D. A.; Knapp, C. C.; Knapp, J. H.

    2010-12-01

    Motivated by the value of marine gas hydrates as an energy resource and their potential influence on climate, we are engaged in a study to characterize gas hydrates in the Gulf of Mexico as part of the Gulf of Mexico Hydrates Research Consortium (GoM-HRC) at a research site on the continental margin. The locations of marine gas hydrates are commonly inferred by the presence of a distinctive Bottom Simulating Reflector (BSR) which typically marks the base of the gas hydrate stability zone (GHSZ) in seismic records. Yet lithology, as defined through sediment composition, grain size, particle shape, and fluid flow, is also critical in their emplacement and growth. Over more than thirty years, variations of Hertz-Mindlin type effective medium models have been developed for unconsolidated sediments. In the past few years improvements have been suggested to these models. This paper is directed at two objectives: 1) briefly review and consolidate the models, 2) apply and compare the models in context of rock physics templates for marine gas hydrates in unconsolidated, saturated sand and clay sediments. Here, we apply petroleum systems analysis to quantitatively estimate (and understand) the lithologic influence on gas hydrate seismic response. To do so, we are implementing recently developed rock physics models for saturated sediments with gas hydrates.

  12. Revisions to the hydrogen gas generation computer model

    SciTech Connect

    Jerrell, J.W.

    1992-08-31

    Waste Management Technology has requested SRTC to maintain and extend a previously developed computer model, TRUGAS, which calculates hydrogen gas concentrations within the transuranic (TRU) waste drums. TRUGAS was written by Frank G. Smith using the BASIC language and is described in the report A Computer Model of gas Generation and Transport within TRU Waste Drums (DP- 1754). The computer model has been partially validated by yielding results similar to experimental data collected at SRL and LANL over a wide range of conditions. The model was created to provide the capability of predicting conditions that could potentially lead to the formation of flammable gas concentrations within drums, and to assess proposed drum venting methods. The model has served as a tool in determining how gas concentrations are affected by parameters such as filter vent sizes, waste composition, gas generation values, the number and types of enclosures, water instrusion into the drum, and curie loading. The success of the TRUGAS model has prompted an interest in the program`s maintenance and enhancement. Experimental data continues to be collected at various sites on such parameters as permeability values, packaging arrangements, filter designs, and waste contents. Information provided by this data is used to improve the accuracy of the model`s predictions. Also, several modifications to the model have been made to enlarge the scope of problems which can be analyzed. For instance, the model has been used to calculate hydrogen concentrations inside steel cabinets containing retired glove boxes (WSRC-RP-89-762). The revised TRUGAS computer model, H2GAS, is described in this report. This report summarizes all modifications made to the TRUGAS computer model and provides documentation useful for making future updates to H2GAS.

  13. Practical Techniques for Modeling Gas Turbine Engine Performance

    NASA Technical Reports Server (NTRS)

    Chapman, Jeffryes W.; Lavelle, Thomas M.; Litt, Jonathan S.

    2016-01-01

    The cost and risk associated with the design and operation of gas turbine engine systems has led to an increasing dependence on mathematical models. In this paper, the fundamentals of engine simulation will be reviewed, an example performance analysis will be performed, and relationships useful for engine control system development will be highlighted. The focus will be on thermodynamic modeling utilizing techniques common in industry, such as: the Brayton cycle, component performance maps, map scaling, and design point criteria generation. In general, these topics will be viewed from the standpoint of an example turbojet engine model; however, demonstrated concepts may be adapted to other gas turbine systems, such as gas generators, marine engines, or high bypass aircraft engines. The purpose of this paper is to provide an example of gas turbine model generation and system performance analysis for educational uses, such as curriculum creation or student reference.

  14. Efficient computation of the compositional model for gas condensate reservoirs

    NASA Astrophysics Data System (ADS)

    Zhou, Jifu; Li, Jiachun; Ye, Jigen

    2000-12-01

    In this paper, a direct method, unsymmetric-pattern multifrontal factorization, for a large sparse system of linear equations is applied in the compositional reservoir model. The good performances of this approach are shown by solving the Poisson equation. And then the numerical module is embedded in the compositional model for simulating X1/5 (3) gas condensate reservoir in KeKeYa gas field, Northwest China. The results of oil/gas reserves, variations of stratum pressure and oil/gas production, etc. are compared with the observation. Good agreement comparable to COMP4 model is achieved, suggesting that the present model is both efficient and powerful in compositional reservoir simulations.

  15. RAETRAD MODEL OF RADON GAS GENERATION, TRANSPORT, AND INDOOR ENTRY

    EPA Science Inventory

    The report describes the theoretical basis, implementation, and validation of the Radon Emanation and Transport into Dwellings (RAETRAD) model, a conceptual and mathematical approach for simulating radon (222Rn) gas generation and transport from soils and building foundations to ...

  16. Validation study of air-sea gas transfer modeling

    SciTech Connect

    Asher, W.E.; Farley, P.J.; Leifer, I.S.

    1995-07-01

    Laboratory results have demonstrated the importance of bubble plumes to air-water gas transfer (Asher et al., 1994). Bubble plumes enhance gas transfer by disrupting surface films, by directly transporting a gas, and by the creation of turbulence. Models of bubble gas transfer have been developed by different authors (Atkinson, 1973; Memery and Merlivat, 1985; Woolf and Thorpe, 1991) to determine the magnitude of gas transfer due to bubbles. Laboratory measurements of both the gas transfer rate k{sub L}, and the bubble distribution {phi} in a whitecap simulation tank (WST) have allowed these models to be validated and deficiencies in the theoretical assumptions to be explored. In the WST, each bucket tip simulates a wave breaking event. Important tests of these models include whether they can explain the experimentally determined solubility and Schmidt number dependency of k{sub L}, predict the time varying bubble concentrations, predict the evasion-invasion asymmetry, and predict the fraction of k{sub L} due to bubble plumes. Four different models were tested, a steady state model (Atkinson, 1973), a non-turbulence model with constant bubble radius (Memery and Merlivat, 1985), a turbulence model with constant bubble radius (Wolf and Thorpe, 1991), and a turbulence model with varying bubble radius. All models simulated multiple bubble tip cycles. The two turbulence models were run for sufficient tip cycles to generate statistically significant number of eddies ({number_sign}{gt}50) for bubbles affected by turbulence (V{sub B}{le}V{sub T}), found to be at least four tip cycles. The models allowed up to nine gases simultaneously and were run under different conditions of trace and major gas concentrations and partial pressures.

  17. Revisions to the hydrogen gas generation computer model

    SciTech Connect

    Jerrell, J.W.

    1992-08-31

    Waste Management Technology has requested SRTC to maintain and extend a previously developed computer model, TRUGAS, which calculates hydrogen gas concentrations within the transuranic (TRU) waste drums. TRUGAS was written by Frank G. Smith using the BASIC language and is described in the report A Computer Model of gas Generation and Transport within TRU Waste Drums (DP- 1754). The computer model has been partially validated by yielding results similar to experimental data collected at SRL and LANL over a wide range of conditions. The model was created to provide the capability of predicting conditions that could potentially lead to the formation of flammable gas concentrations within drums, and to assess proposed drum venting methods. The model has served as a tool in determining how gas concentrations are affected by parameters such as filter vent sizes, waste composition, gas generation values, the number and types of enclosures, water instrusion into the drum, and curie loading. The success of the TRUGAS model has prompted an interest in the program's maintenance and enhancement. Experimental data continues to be collected at various sites on such parameters as permeability values, packaging arrangements, filter designs, and waste contents. Information provided by this data is used to improve the accuracy of the model's predictions. Also, several modifications to the model have been made to enlarge the scope of problems which can be analyzed. For instance, the model has been used to calculate hydrogen concentrations inside steel cabinets containing retired glove boxes (WSRC-RP-89-762). The revised TRUGAS computer model, H2GAS, is described in this report. This report summarizes all modifications made to the TRUGAS computer model and provides documentation useful for making future updates to H2GAS.

  18. Sensitivity analysis of the fission gas behavior model in BISON.

    SciTech Connect

    Swiler, Laura Painton; Pastore, Giovanni; Perez, Danielle; Williamson, Richard

    2013-05-01

    This report summarizes the result of a NEAMS project focused on sensitivity analysis of a new model for the fission gas behavior (release and swelling) in the BISON fuel performance code of Idaho National Laboratory. Using the new model in BISON, the sensitivity of the calculated fission gas release and swelling to the involved parameters and the associated uncertainties is investigated. The study results in a quantitative assessment of the role of intrinsic uncertainties in the analysis of fission gas behavior in nuclear fuel.

  19. A dynamic plunger-lift model for gas wells

    SciTech Connect

    1998-07-01

    A free piston or plunger traveling up and down the tubing has been used for different applications in oil and gas production for decades. Its most widespread use is in conventional plunger lift, which is an artificial-lift technique characterized by use of reservoir energy stored in the gas phase to lift fluids to the surface. The plunger acts as an interface between the liquid slug and the gas to keep the ballistic-shaped flow pattern of the higher-velocity gas phase from breaking through the liquid phase during production. Several authors have modeled plunger-lift installations. Static models have been proposed and are widely accepted. Dynamic models also have been published to describe the phenomenon of a plunger-lift cycle. The dynamic model developed in the full-length paper overcomes some of the assumptions used in previous models. It includes reservoir performance, gas expansion with friction effects, and the transient behavior of the gas above the liquid slug when the surface valve is opened. It also includes a blow-down or afterflow period for production after the liquid slug surfaces. The upstroke model includes a transition phase that describes the production of the slug into the flowline.

  20. A Generalized Kinetic Model for Heterogeneous Gas-Solid Reactions

    SciTech Connect

    Xu, Zhijie; Sun, Xin; Khaleel, Mohammad A.

    2012-08-15

    We present a generalized kinetic model for gas-solid heterogeneous reactions taking place at the interface between two phases. The model studies the reaction kinetics by taking into account the reactions at the interface, as well as the transport process within the product layer. The standard unreacted shrinking core model relies on the assumption of quasi-static diffusion that results in a steady-state concentration profile of gas reactant in the product layer. By relaxing this assumption and resolving the entire problem, general solutions can be obtained for reaction kinetics, including the reaction front velocity and the conversion (volume fraction of reacted solid). The unreacted shrinking core model is shown to be accurate and in agreement with the generalized model for slow reaction (or fast diffusion), low concentration of gas reactant, and small solid size. Otherwise, a generalized kinetic model should be used.

  1. USERS MANUAL: LANDFILL GAS EMISSIONS MODEL - VERSION 2.0

    EPA Science Inventory

    The document is a user's guide for a computer model, Version 2.0 of the Landfill Gas Emissions Model (LandGEM), for estimating air pollution emissions from municipal solid waste (MSW) landfills. The model can be used to estimate emission rates for methane, carbon dioxide, nonmet...

  2. On the flow of a compressible fluid by the hodograph method II : fundamental set of particular flow solutions of the Chaplygin differential equation

    NASA Technical Reports Server (NTRS)

    Garrick, I E; Kaplan, Carl

    1944-01-01

    The differential equation of Chaplygin's jet problem is utilized to give a systematic development of particular solutions of the hodograph flow equations, which extends the treatment of Chaplygin into the supersonic range and completes the set of particular solutions. The particular solutions serve to place on a reasonable basis the use of velocity correction formulas for the comparison of incompressible and compressible flows. It is shown that the geometric-mean type of velocity correction formula introduced in part I has significance as an over-all type of approximation in the subsonic range. A brief review of general conditions limiting the potential flow of an adiabatic compressible fluid is given and application is made to the particular solutions, yielding conditions for the existence of singular loci in the supersonic range. The combining of particular solutions in accordance with prescribed boundary flow conditions is not treated in the present paper.

  3. On the Flow of a Compressible Fluid by the Hodograph Method. II - Fundamental Set of Particular Flow Solutions of the Chaplygin Differential Equation

    NASA Technical Reports Server (NTRS)

    Garrick, I. E.; Kaplan, Carl

    1944-01-01

    The differential equation of Chaplygin's jet problem is utilized to give a systematic development of particular solutions of the hodograph flow equations, which extends the treatment of Chaplygin into the supersonic range and completes the set of particular solutions. The particular solutions serve to place on a reasonable basis the use of velocity correction formulas for the comparison of incompressible and compressible flows. It is shown that the geometric-mean type of velocity correction formula introduced in part I has significance as an over-all type of approximation in the subsonic range. A brief review of general conditions limiting the potential flow of an adiabatic compressible fluid is given and application is made to the particular solutions, yielding conditions for the existence of singular loci in the supersonic range. The combining of particular solutions in accordance with prescribed boundary flow conditions is not treated in the present paper.

  4. Process simulation and modeling for gas processing plant

    NASA Astrophysics Data System (ADS)

    Alhameli, Falah Obaid Kenish Mubarak

    Natural gas is one of the major energy sources and its demand is increasing rapidly due to its environmental and economic advantages over other fuels. Gas processing is an essential component of natural gas system. In this work, gas processing plant is introduced with the objective of meeting pipeline gas quality. It consists of separation, sweetening and dehydration units. The separation unit contains phase separators along with stabilizer (conventional distillation column). The sweetening unit is an amine process with MDEA (Methyl DiEthanol Amine) solvent. The dehydration unit is glycol absorption with TEG (TriEthyleneGlycol) solvent. ProMaxRTM 3.2 was used to simulate the plant. Box-Behnken design was applied to build a black-box model using design of experiments (DoE). MinitabRTM 15 was used to generate and analyse the design. The chosen variables for the model were 10. They represent the gas feed conditions and units' parameters. The total runs were 170. They were successfully implemented and analysed. Total energy of the plant and water content for the product gas models were obtained. Case study was conducted to investigate the impact of H2S composition increase in the feed gas. The models were used for the case study with the objective of total energy minimization and constraint of 4 lb/MMscf for water content in the product gas. Lingo 13 was used for the optimization. It was observed that the feed pressure had the highest influence among the other parameters. Finally, some recommendations were pointed out for the future works.

  5. Empirical Modeling of Plant Gas Fluxes in Controlled Environments

    NASA Technical Reports Server (NTRS)

    Cornett, Jessie David

    1994-01-01

    As humans extend their reach beyond the earth, bioregenerative life support systems must replace the resupply and physical/chemical systems now used. The Controlled Ecological Life Support System (CELSS) will utilize plants to recycle the carbon dioxide (CO2) and excrement produced by humans and return oxygen (O2), purified water and food. CELSS design requires knowledge of gas flux levels for net photosynthesis (PS(sub n)), dark respiration (R(sub d)) and evapotranspiration (ET). Full season gas flux data regarding these processes for wheat (Triticum aestivum), soybean (Glycine max) and rice (Oryza sativa) from published sources were used to develop empirical models. Univariate models relating crop age (days after planting) and gas flux were fit by simple regression. Models are either high order (5th to 8th) or more complex polynomials whose curves describe crop development characteristics. The models provide good estimates of gas flux maxima, but are of limited utility. To broaden the applicability, data were transformed to dimensionless or correlation formats and, again, fit by regression. Polynomials, similar to those in the initial effort, were selected as the most appropriate models. These models indicate that, within a cultivar, gas flux patterns appear remarkably similar prior to maximum flux, but exhibit considerable variation beyond this point. This suggests that more broadly applicable models of plant gas flux are feasible, but univariate models defining gas flux as a function of crop age are too simplistic. Multivariate models using CO2 and crop age were fit for PS(sub n), and R(sub d) by multiple regression. In each case, the selected model is a subset of a full third order model with all possible interactions. These models are improvements over the univariate models because they incorporate more than the single factor, crop age, as the primary variable governing gas flux. They are still limited, however, by their reliance on the other environmental

  6. Dynamic Absorption Model for Off-Gas Separation

    SciTech Connect

    Veronica J. Rutledge

    2011-07-01

    Modeling and simulations will aid in the future design of U.S. advanced reprocessing plants for the recovery and recycle of actinides in used nuclear fuel. The specific fuel cycle separation process discussed in this report is the off-gas treatment system. The off-gas separation consists of a series of scrubbers and adsorption beds to capture constituents of interest. Dynamic models are being developed to simulate each unit operation involved so each unit operation can be used as a stand-alone model and in series with multiple others. Currently, a rate based, dynamic absorption model is being developed in gPROMS software. Inputs include liquid and gas stream constituents, column properties, liquid and gas phase reactions, number of stages, and inlet conditions. It simulates multiple component absorption with countercurrent flow and accounts for absorption by mass transfer and chemical reaction. The assumption of each stage being a discrete well-mixed entity was made. Therefore, the model is solved stagewise. The simulation outputs component concentrations in both phases as a function of time from which the rate of absorption is determined. Temperature of both phases is output as a function of time also. The model will be used able to be used as a standalone model in addition to in series with other off-gas separation unit operations. The current model is being generated based on NOx absorption; however, a future goal is to develop a CO2 specific model. The model will have the capability to be modified for additional absorption systems. The off-gas models, both adsorption and absorption, will be made available via the server or web for evaluation by customers.

  7. Development of dense gas dispersion model for emergency preparedness

    NASA Astrophysics Data System (ADS)

    Mohan, Manju; Panwar, T. S.; Singh, M. P.

    Mathematical models are recognized as important tools for providing quantitative assessment of the consequences of the accidental release of hazardous materials. In several accidental release situations, denser-than-air vapour clouds are formed which exhibit dispersion behaviour markedly different from that observed for passive atmospheric pollutants. The present work undertakes the development and validation of conceptually simple and computationally efficient dense gas dispersion models which could be used for emergency response. Here, IIT Heavy Gas Models I and II have been developed for instantaneous and continuous releases, respectively, of dense toxic materials in the atmosphere. Sensitivity tests have been performed to determine the various empirical coefficients which are found to be quite different than those used in the earlier studies. Particular emphasis has been laid on model validation by comparing their performance against relevant field trial data (Thorney Island, Burro Series and Maplin Sands Trials) as well as with other models. On the basis of statistical evaluation, a good performance of the model has been established. The performance of the IIT Heavy Gas Model is close to the model showing the best performance amongst 11-14 other models developed in various countries. Using the IIT Heavy Gas Model, the Safe distance/vulnerable zones can be easily estimated for different meteorological and release conditions for the storage of various hazardous chemicals.

  8. Integrated CFD modeling of gas turbine combustors

    NASA Technical Reports Server (NTRS)

    Fuller, E. J.; Smith, C. E.

    1993-01-01

    3D, curvilinear, multi-domain CFD analysis is becoming a valuable tool in gas turbine combustor design. Used as a supplement to experimental testing. CFD analysis can provide improved understanding of combustor aerodynamics and used to qualitatively assess new combustor designs. This paper discusses recent advancements in CFD combustor methodology, including the timely integration of the design (i.e. CAD) and analysis (i.e. CFD) processes. Allied Signal's F124 combustor was analyzed at maximum power conditions. The assumption of turbulence levels at the nozzle/swirler inlet was shown to be very important in the prediction of combustor exit temperatures. Predicted exit temperatures were compared to experimental rake data, and good overall agreement was seen. Exit radial temperature profiles were well predicted, while the predicted pattern factor was 25 percent higher than the harmonic-averaged experimental pattern factor.

  9. Transient Catalytic Combustor Model With Detailed Gas and Surface Chemistry

    NASA Technical Reports Server (NTRS)

    Struk, Peter M.; Dietrich, Daniel L.; Mellish, Benjamin P.; Miller, Fletcher J.; Tien, James S.

    2005-01-01

    In this work, we numerically investigate the transient combustion of a premixed gas mixture in a narrow, perfectly-insulated, catalytic channel which can represent an interior channel of a catalytic monolith. The model assumes a quasi-steady gas-phase and a transient, thermally thin solid phase. The gas phase is one-dimensional, but it does account for heat and mass transfer in a direction perpendicular to the flow via appropriate heat and mass transfer coefficients. The model neglects axial conduction in both the gas and in the solid. The model includes both detailed gas-phase reactions and catalytic surface reactions. The reactants modeled so far include lean mixtures of dry CO and CO/H2 mixtures, with pure oxygen as the oxidizer. The results include transient computations of light-off and system response to inlet condition variations. In some cases, the model predicts two different steady-state solutions depending on whether the channel is initially hot or cold. Additionally, the model suggests that the catalytic ignition of CO/O2 mixtures is extremely sensitive to small variations of inlet equivalence ratios and parts per million levels of H2.

  10. HEAVY-DUTY GREENHOUSE GAS EMISSIONS MODEL ...

    EPA Pesticide Factsheets

    Class 2b-8 vocational truck manufacturers and Class 7/8 tractor manufacturers would be subject to vehicle-based fuel economy and emission standards that would use a truck simulation model to evaluate the impact of the truck tires and/or tractor cab design on vehicle compliance with any new standards. The EPA has created a model called “GHG Emissions Model (GEM)”, which is specifically tailored to predict truck GHG emissions. As the model is designed for the express purpose of vehicle compliance demonstration, it is less configurable than similar commercial products and its only outputs are GHG emissions and fuel consumption. This approach gives a simple and compact tool for vehicle compliance without the overhead and costs of a more sophisticated model. Evaluation of both fuel consumption and CO2 emissions from heavy-duty highway vehicles through a whole-vehicle operation simulation model.

  11. SIMPLODE: An Imploding Gas Puff Plasma Model. I. Neon.

    DTIC Science & Technology

    2014-09-26

    recent experimental results obtained on GAMBLE II. In addition, the influence of the Plasma Erosion Opening Switch on the K-shell yield is...LTE radiation physics model and is ideal for use with the gas puff experiments at NRL on the GAMBLE II facility. Recently the GAMBLE II pulse power...facility has been upgraded to accomodate gas puff loads. This modification enhances GAMBLE II’s versatility by expanding the types of material loads that

  12. Statistical time-dependent model for the interstellar gas

    NASA Technical Reports Server (NTRS)

    Gerola, H.; Kafatos, M.; Mccray, R.

    1974-01-01

    We present models for temperature and ionization structure of low, uniform-density (approximately 0.3 per cu cm) interstellar gas in a galactic disk which is exposed to soft X rays from supernova outbursts occurring randomly in space and time. The structure was calculated by computing the time record of temperature and ionization at a given point by Monte Carlo simulation. The calculation yields probability distribution functions for ionized fraction, temperature, and their various observable moments. These time-dependent models predict a bimodal temperature distribution of the gas that agrees with various observations. Cold regions in the low-density gas may have the appearance of clouds in 21-cm absorption. The time-dependent model, in contrast to the steady-state model, predicts large fluctuations in ionization rate and the existence of cold (approximately 30 K), ionized (ionized fraction equal to about 0.1) regions.

  13. A Continuum Model for Metabolic Gas Exchange in Pear Fruit

    PubMed Central

    Ho, Q. Tri; Verboven, Pieter; Verlinden, Bert E.; Lammertyn, Jeroen; Vandewalle, Stefan; Nicolaï, Bart M.

    2008-01-01

    Exchange of O2 and CO2 of plants with their environment is essential for metabolic processes such as photosynthesis and respiration. In some fruits such as pears, which are typically stored under a controlled atmosphere with reduced O2 and increased CO2 levels to extend their commercial storage life, anoxia may occur, eventually leading to physiological disorders. In this manuscript we have developed a mathematical model to predict the internal gas concentrations, including permeation, diffusion, and respiration and fermentation kinetics. Pear fruit has been selected as a case study. The model has been used to perform in silico experiments to evaluate the effect of, for example, fruit size or ambient gas concentration on internal O2 and CO2 levels. The model incorporates the actual shape of the fruit and was solved using fluid dynamics software. Environmental conditions such as temperature and gas composition have a large effect on the internal distribution of oxygen and carbon dioxide in fruit. Also, the fruit size has a considerable effect on local metabolic gas concentrations; hence, depending on the size, local anaerobic conditions may result, which eventually may lead to physiological disorders. The model developed in this manuscript is to our knowledge the most comprehensive model to date to simulate gas exchange in plant tissue. It can be used to evaluate the effect of environmental stresses on fruit via in silico experiments and may lead to commercial applications involving long-term storage of fruit under controlled atmospheres. PMID:18369422

  14. Effective-Medium Models for Marine Gas Hydrates, Mallik Revisited

    NASA Astrophysics Data System (ADS)

    Terry, D. A.; Knapp, C. C.; Knapp, J. H.

    2011-12-01

    Hertz-Mindlin type effective-medium dry-rock elastic models have been commonly used for more than three decades in rock physics analysis, and recently have been applied to assessment of marine gas hydrate resources. Comparisons of several effective-medium models with derivative well-log data from the Mackenzie River Valley, Northwest Territories, Canada (i.e. Mallik 2L-38 and 5L-38) were made several years ago as part of a marine gas hydrate joint industry project in the Gulf of Mexico. The matrix/grain supporting model (one of the five models compared) was clearly a better representation of the Mallik data than the other four models (2 cemented sand models; a pore-filling model; and an inclusion model). Even though the matrix/grain supporting model was clearly better, reservations were noted that the compressional velocity of the model was higher than the compressional velocity measured via the sonic logs, and that the shear velocities showed an even greater discrepancy. Over more than thirty years, variations of Hertz-Mindlin type effective medium models have evolved for unconsolidated sediments and here, we briefly review their development. In the past few years, the perfectly smooth grain version of the Hertz-Mindlin type effective-medium model has been favored over the infinitely rough grain version compared in the Gulf of Mexico study. We revisit the data from the Mallik wells to review assertions that effective-medium models with perfectly smooth grains are a better predictor than models with infinitely rough grains. We briefly review three Hertz-Mindlin type effective-medium models, and standardize nomenclature and notation. To calibrate the extended effective-medium model in gas hydrates, we use a well accepted framework for unconsolidated sediments through Hashin-Shtrikman bounds. We implement the previously discussed effective-medium models for saturated sediments with gas hydrates and compute theoretical curves of seismic velocities versus gas hydrate

  15. Microplume model of spatial-yield spectra. [applying to electron gas degradation in molecular nitrogen gas

    NASA Technical Reports Server (NTRS)

    Green, A. E. S.; Singhal, R. P.

    1979-01-01

    An analytic representation for the spatial (radial and longitudinal) yield spectra is developed in terms of a model containing three simple 'microplumes'. The model is applied to electron energy degradation in molecular nitrogen gas for 0.1 to 5 keV incident electrons. From the nature of the cross section input to this model it is expected that the scaled spatial yield spectra for other gases will be quite similar. The model indicates that each excitation, ionization, etc. plume should have its individual spatial and energy dependence. Extensions and aeronomical and radiological applications of the model are discussed.

  16. Application of dispersion modeling to indoor gas release scenarios.

    PubMed

    Rasouli, F; Williams, T A

    1995-03-01

    Many complex models are available to study the dispersion of contaminants or ventilation effectiveness in indoor spaces. Because of the computationally complex numerical schemes employed, most of these models require mainframe computers or workstations. However, simple design tools or guidelines are needed, in addition to complicated models. A dispersion model based on the basic governing equations was developed and uses an analytical solution. Because the concentration is expressed by an analytical solution, the grid size and time steps are user definable. A computer program was used to obtain numerical results and to obtain release history from a thermodynamic source model. The model can be used to estimate three-dimensional spatial and temporal variations in concentrations resulting from transient gas releases in an enclosure. The model was used to study a gas release scenario from a pressurized cylinder into a large ventilated building, in this case, a transit parking and fueling facility.

  17. Modeling of neutral gas dynamics in high-density plasmas

    NASA Astrophysics Data System (ADS)

    Canupp, Patrick Wellington

    This thesis describes a physical model of chemically reactive neutral gas flow and discusses numerical solutions of this model for the flow in an inductively coupled plasma etch reactor. To obtain these solutions, this research develops an efficient, implicit numerical method. As a result of the enhanced numerical stability of the scheme, large time steps advance the solution from initial conditions to a final steady state in fewer iterations and with less computational expense than simpler explicit methods. This method would incorporate suitably as a module in currently existing large scale plasma simulation tools. In order to demonstrate the accuracy of the numerical technique, this thesis presents results from two simulations of flows that possess theoretical solutions. The first case is the inviscid flow of a gas through a converging nozzle. A comparison of the numerical solution to isentropic flow theory shows that the numerical technique capably captures the essential flow features of this environment. The second case is the Couette flow of a gas between two parallel plates. The simulation results compare well with the exact solution for this flow. After establishing the accuracy of the numerical technique, this thesis discusses results for the flow of chemically reactive gases in a chlorine plasma etch reactor. This research examines the influence of the plasma on the neutral gas and the dynamics exhibited by the neutral gas in the reactor. This research finds that the neutral gas temperature strongly depends on the rate at which inelastic, electron-impact dissociation reactions occur and on atomic chlorine wall recombination rates. Additionally, the neutral gas Aow in the reactor includes a significant mass flux of etch product from the wafer surface. Resolution of these effects is useful for neutral gas simulation. Finally, this thesis demonstrates that continuum fluid models provide reasonable accuracy for these low pressure reactor flows due to the fact

  18. Model documentation Natural Gas Transmission and Distribution Model of the National Energy Modeling System. Volume 1

    SciTech Connect

    1996-02-26

    The Natural Gas Transmission and Distribution Model (NGTDM) of the National Energy Modeling System is developed and maintained by the Energy Information Administration (EIA), Office of Integrated Analysis and Forecasting. This report documents the archived version of the NGTDM that was used to produce the natural gas forecasts presented in the Annual Energy Outlook 1996, (DOE/EIA-0383(96)). The purpose of this report is to provide a reference document for model analysts, users, and the public that defines the objectives of the model, describes its basic approach, and provides detail on the methodology employed. Previously this report represented Volume I of a two-volume set. Volume II reported on model performance, detailing convergence criteria and properties, results of sensitivity testing, comparison of model outputs with the literature and/or other model results, and major unresolved issues.

  19. Potential biodefense model applications for portable chlorine dioxide gas production.

    PubMed

    Stubblefield, Jeannie M; Newsome, Anthony L

    2015-01-01

    Development of decontamination methods and strategies to address potential infectious disease outbreaks and bioterrorism events are pertinent to this nation's biodefense strategies and general biosecurity. Chlorine dioxide (ClO2) gas has a history of use as a decontamination agent in response to an act of bioterrorism. However, the more widespread use of ClO2 gas to meet current and unforeseen decontamination needs has been hampered because the gas is too unstable for shipment and must be prepared at the application site. Newer technology allows for easy, onsite gas generation without the need for dedicated equipment, electricity, water, or personnel with advanced training. In a laboratory model system, 2 unique applications (personal protective equipment [PPE] and animal skin) were investigated in the context of potential development of decontamination protocols. Such protocols could serve to reduce human exposure to bacteria in a decontamination response effort. Chlorine dioxide gas was capable of reducing (2-7 logs of vegetative and spore-forming bacteria), and in some instances eliminating, culturable bacteria from difficult to clean areas on PPE facepieces. The gas was effective in eliminating naturally occurring bacteria on animal skin and also on skin inoculated with Bacillus spores. The culturable bacteria, including Bacillus spores, were eliminated in a time- and dose-dependent manner. Results of these studies suggested portable, easily used ClO2 gas generation systems have excellent potential for protocol development to contribute to biodefense strategies and decontamination responses to infectious disease outbreaks or other biothreat events.

  20. An Equilibrium-Based Model of Gas Reaction and Detonation

    SciTech Connect

    Trowbridge, L.D.

    2000-04-01

    During gaseous diffusion plant operations, conditions leading to the formation of flammable gas mixtures may occasionally arise. Currently, these could consist of the evaporative coolant CFC-114 and fluorinating agents such as F2 and ClF3. Replacement of CFC-114 with a non-ozone-depleting substitute is planned. Consequently, in the future, the substitute coolant must also be considered as a potential fuel in flammable gas mixtures. Two questions of practical interest arise: (1) can a particular mixture sustain and propagate a flame if ignited, and (2) what is the maximum pressure that can be generated by the burning (and possibly exploding) gas mixture, should it ignite? Experimental data on these systems, particularly for the newer coolant candidates, are limited. To assist in answering these questions, a mathematical model was developed to serve as a tool for predicting the potential detonation pressures and for estimating the composition limits of flammability for these systems based on empirical correlations between gas mixture thermodynamics and flammability for known systems. The present model uses the thermodynamic equilibrium to determine the reaction endpoint of a reactive gas mixture and uses detonation theory to estimate an upper bound to the pressure that could be generated upon ignition. The model described and documented in this report is an extended version of related models developed in 1992 and 1999.

  1. Cytochrome c biosensor--a model for gas sensing.

    PubMed

    Hulko, Michael; Hospach, Ingeborg; Krasteva, Nadejda; Nelles, Gabriele

    2011-01-01

    This work is about gas biosensing with a cytochrome c biosensor. Emphasis is put on the analysis of the sensing process and a mathematical model to make predictions about the biosensor response. Reliable predictions about biosensor responses can provide valuable information and facilitate biosensor development, particularly at an early development stage. The sensing process comprises several individual steps, such as phase partition equilibrium, intermediate reactions, mass-transport, and reaction kinetics, which take place in and between the gas and liquid phases. A quantitative description of each step was worked out and finally combined into a mathematical model. The applicability of the model was demonstrated for a particular example of methanethiol gas detection by a cytochrome c biosensor. The model allowed us to predict the optical readout response of the biosensor from tabulated data and data obtained in simple liquid phase experiments. The prediction was experimentally verified with a planar three-electrode electro-optical cytochrome c biosensor in contact with methanethiol gas in a gas tight spectroelectrochemical measurement cell.

  2. Mathematical modelling of landfill gas migration in MSW sanitary landfills.

    PubMed

    Martín, S; Marañón, E; Sastre, H

    2001-10-01

    The laws that govern the displacement of landfill gas in a sanitary landfill are analysed. Subsequently, a 2-D finite difference flow model of a fluid in a steady state in a porous medium with infinite sources of landfill gas is proposed. The fact that landfill gas is continuously generated throughout the entire mass of the landfill differentiates this model from others extensively described in the literature and used in a variety of different applications, such as oil recovery, groundwater flow, etc. Preliminary results are then presented of the application of the model. Finally, the results obtained employing data from the literature and experimental assays carried out at the La Zoreda sanitary landfill (Asturias, Spain) are discussed and future lines of research are proposed.

  3. Computational technology of multiscale modeling the gas flows in microchannels

    NASA Astrophysics Data System (ADS)

    Podryga, V. O.

    2016-11-01

    The work is devoted to modeling the gas mixture flows in engineering microchannels under conditions of many scales of computational domain. The computational technology of using the multiscale approach combining macro - and microscopic models is presented. At macrolevel the nature of the flow and the external influence on it are considered. As a model the system of quasigasdynamic equations is selected. At microlevel the correction of gasdynamic parameters and the determination of boundary conditions are made. As a numerical model the Newton's equations and the molecular dynamics method are selected. Different algorithm types used for implementation of multiscale modeling are considered. The results of the model problems for separate stages are given.

  4. Algebraic operator approach to gas kinetic models

    NASA Astrophysics Data System (ADS)

    Il'ichov, L. V.

    1997-02-01

    Some general properties of the linear Boltzmann kinetic equation are used to present it in the form ∂ tϕ = - †Âϕ with the operators Âand† possessing some nontrivial algebraic properties. When applied to the Keilson-Storer kinetic model, this method gives an example of quantum ( q-deformed) Lie algebra. This approach provides also a natural generalization of the “kangaroo model”.

  5. Hydrodynamical Models of Gas Cloud - Galaxy Collisions

    NASA Astrophysics Data System (ADS)

    Franklin, M.; Dinge, D.; Jones, T.; Benjamin, B.

    1999-05-01

    Clouds of neutral hydrogen falling toward the Galactic plane with a speed of about 100 km/s or more are among those considered to be "high velocity clouds" (HVCs). As HVCs are often observed approaching the midplane, the collision of such clouds with the gaseous disk of the Galaxy has been proposed as a precursor event to the phenomena known as "supershells" and as a catalyst to star formation. While many previous analytic calculations have assumed that ram pressure of the resisting medium was negligible, and a ballistic approximation was valid, observations showing a correlation between speed and increased height above the plane, the opposite of what is expected for free fall, suggest otherwise. Benjamin & Danly suggested in 1997 that clouds falling at terminal velocity provide a simple explanation for the observed velocity distribution. In this work, numerical models are used to test the above hypotheses with clouds falling through a more modern model of the interstellar medium than that used in the seminal work by Tenorio-Tagle et al. (TT) in 1987. With the addition of more dense material to the model background, clouds were still able to form supershell-like remnants, though star formation does not appear to be triggered. Further, though agreement was not perfect, the terminal velocity model was found to be a better approximation for these clouds' fall than the ballistic case. Cooling was a physical process included in TT's work which was not included here, but was found to be non-negligible. Simulations which include a cooling algorithm must be done to confirm these results. This work was supported in part by NSF grant AST96-19438.

  6. Modeling Gas Dynamics in California Sea Lions

    DTIC Science & Technology

    2015-09-30

    for diving California sea lions. Aim 1: Pressure-volume (compliance) loops from excised California sea lions lungs and upper airways (trachea...were used to update the parameters that estimate the pulmonary shunt during diving. The compliance estimates were related to lung and tracheal volumes...during compression to pulmonary shunt (Bostrom, Fahlman et al. 2008). In the existing model, the compliance parameter for the lung was for

  7. Two-Dimensional Motion of a Gas at Large Supersonic Velocities

    NASA Technical Reports Server (NTRS)

    Falkovich, S. V.

    1949-01-01

    A large number of papers have been devoted to the problem of integration of equations of two-dimensional steady nonvertical adiabatic motion of a gas. Most of these papers are based on the application of the hodograph method of S. A. Chaplygin in which the plane of the hodograph of the velocity is taken as the region of variation of the independent variables in the equations of motion; the equations become linear in this plane. The exact integration of these equations is, however, obtained in the form of infinite series containing hypergeometric functions. The obtaining of such solutions and their investigation involves extensive computations. As a result, methods have been developed for the approximate integration of the equations of motion first transformed to a linear form. S. A. Chaplygin first pointed out such an approximate method applicable to flows in which the Mach number does not exceed 0.4.

  8. Off-gas Adsorption Model and Simulation - OSPREY

    SciTech Connect

    Veronica J Rutledge

    2013-10-01

    The absence of industrial scale nuclear fuel reprocessing in the U.S. has precluded the necessary driver for developing the advanced simulation capability now prevalent in so many other countries. Thus, it is essential to model complex series of unit operations to simulate, understand, and predict inherent transient behavior. A capability of accurately simulating the dynamic behavior of advanced fuel cycle separation processes is expected to provide substantial cost savings and many technical benefits. To support this capability, a modeling effort focused on the off-gas treatment system of a used nuclear fuel recycling facility is in progress. The off-gas separation consists of a series of scrubbers and adsorption beds to capture constituents of interest. Dynamic models are being developed to simulate each unit operation involved so each unit operation can be used as a stand-alone model and in series with multiple others. Currently, an adsorption model has been developed within Multi-physics Object Oriented Simulation Environment (MOOSE) developed at the Idaho National Laboratory (INL). Off-gas Separation and REcoverY (OSPREY) models the adsorption of offgas constituents for dispersed plug flow in a packed bed under non-isothermal and non-isobaric conditions. Inputs to the model include gas composition, sorbent and column properties, equilibrium and kinetic data, and inlet conditions. The simulation outputs component concentrations along the column length as a function of time from which breakthrough data can be obtained. The breakthrough data can be used to determine bed capacity, which in turn can be used to size columns. In addition to concentration data, the model predicts temperature along the column length as a function of time and pressure drop along the column length. A description of the OSPREY model, results from krypton adsorption modeling and plans for modeling the behavior of iodine, xenon, and tritium will be discussed.

  9. Modelling and identification for control of gas bearings

    NASA Astrophysics Data System (ADS)

    Theisen, Lukas R. S.; Niemann, Hans H.; Santos, Ilmar F.; Galeazzi, Roberto; Blanke, Mogens

    2016-03-01

    Gas bearings are popular for their high speed capabilities, low friction and clean operation, but suffer from poor damping, which poses challenges for safe operation in presence of disturbances. Feedback control can achieve enhanced damping but requires low complexity models of the dominant dynamics over its entire operating range. Models from first principles are complex and sensitive to parameter uncertainty. This paper presents an experimental technique for "in situ" identification of a low complexity model of a rotor-bearing-actuator system and demonstrates identification over relevant ranges of rotational speed and gas injection pressure. This is obtained using parameter-varying linear models that are found to capture the dominant dynamics. The approach is shown to be easily applied and to suit subsequent control design. Based on the identified models, decentralised proportional control is designed and shown to obtain the required damping in theory and in a laboratory test rig.

  10. Modelling and interpretation of gas detection using remote laser pointers.

    PubMed

    Hodgkinson, J; van Well, B; Padgett, M; Pride, R D

    2006-04-01

    We have developed a quantitative model of the performance of laser pointer style gas leak detectors, which are based on remote detection of backscattered radiation. The model incorporates instrumental noise limits, the reflectivity of the target background surface and a mathematical description of gas leak dispersion in constant wind speed and turbulence conditions. We have investigated optimum instrument performance and limits of detection in simulated leak detection situations. We predict that the optimum height for instruments is at eye level or above, giving an operating range of 10 m or more for most background surfaces, in wind speeds of up to 2.5 ms(-1). For ground based leak sources, we find laser pointer measurements are dominated by gas concentrations over a short distance close to the target surface, making their readings intuitive to end users in most cases. This finding is consistent with the results of field trials.

  11. Gas phase metal cluster model systems for heterogeneous catalysis.

    PubMed

    Lang, Sandra M; Bernhardt, Thorsten M

    2012-07-14

    Since the advent of intense cluster sources, physical and chemical properties of isolated metal clusters are an active field of research. In particular, gas phase metal clusters represent ideal model systems to gain molecular level insight into the energetics and kinetics of metal-mediated catalytic reactions. Here we summarize experimental reactivity studies as well as investigations of thermal catalytic reaction cycles on small gas phase metal clusters, mostly in relation to the surprising catalytic activity of nanoscale gold particles. A particular emphasis is put on the importance of conceptual insights gained through the study of gas phase model systems. Based on these concepts future perspectives are formulated in terms of variation and optimization of catalytic materials e.g. by utilization of bimetals and metal oxides. Furthermore, the future potential of bio-inspired catalytic material systems are highlighted and technical developments are discussed.

  12. Modeling CO2 air dispersion from gas driven lake eruptions

    NASA Astrophysics Data System (ADS)

    Chiodini, Giovanni; Costa, Antonio; Rouwet, Dmitri; Tassi, Franco

    2016-04-01

    The most tragic event of gas driven lake eruption occurred at Lake Nyos (Cameroon) on 21 August 1986, when a dense cloud of CO2 suffocated more than 1700 people and an uncounted number of animals in just one night. The event stimulated a series of researches aimed to understand gas origins, gas release mechanisms and strategies for gas hazard mitigation. Very few studies have been carried out for describing the transport of dense CO2 clouds in the atmosphere. Although from a theoretical point of view, gas dispersion can be fully studied by solving the complete equations system for mass, momentum and energy transport, in actual practice, different simplified models able to describe only specific phases or aspects have to be used. In order to simulate dispersion of a heavy gas and to assess the consequent hazard we used a model based on a shallow layer approach (TWODEE2). This technique which uses depth-averaged variables to describe the flow behavior of dense gas over complex topography represents a good compromise between the complexity of computational fluid dynamic models and the simpler integral models. Recently the model has been applied for simulating CO2 dispersion from natural gas emissions in Central Italy. The results have shown how the dispersion pattern is strongly affected by the intensity of gas release, the topography and the ambient wind speed. Here for the first time we applied TWODEE2 code to simulate the dispersion of the large CO2 clouds released by limnic eruptions. An application concerns the case of the 1986 event at lake Nyos. Some difficulties for the simulations were related to the lack of quantitative information: gas flux estimations are not well constrained, meteorological conditions are only qualitatively known, the digital model of the terrain is of poor quality. Different scenarios were taken into account in order to reproduce the qualitative observations available for such episode. The observations regard mainly the effects of gas on

  13. Off-gas adsorption model and simulation - OSPREY

    SciTech Connect

    Rutledge, V.J.

    2013-07-01

    A capability of accurately simulating the dynamic behavior of advanced fuel cycle separation processes is expected to provide substantial cost savings and many technical benefits. To support this capability, a modeling effort focused on the off-gas treatment system of a used nuclear fuel recycling facility is in progress. The off-gas separation consists of a series of scrubbers and adsorption beds to capture constituents of interest. Dynamic models are being developed to simulate each unit operation involved so each unit operation can be used as a stand-alone model and in series with multiple others. Currently, an adsorption model has been developed within Multi-physics Object Oriented Simulation Environment (MOOSE) developed at the Idaho National Laboratory (INL). Off-gas Separation and Recovery (OSPREY) models the adsorption of offgas constituents for dispersed plug flow in a packed bed under non-isothermal and non-isobaric conditions. Inputs to the model include gas composition, sorbent and column properties, equilibrium and kinetic data, and inlet conditions. The simulation outputs component concentrations along the column length as a function of time from which breakthrough data can be obtained. The breakthrough data can be used to determine bed capacity, which in turn can be used to size columns. In addition to concentration data, the model predicts temperature along the column length as a function of time and pressure drop along the column length. A description of the OSPREY model, results from krypton adsorption modeling and plans for modeling the behavior of iodine, xenon, and tritium will be discussed. (author)

  14. A Model of Gas Recycling Based on Condensed H2

    NASA Astrophysics Data System (ADS)

    Pfenniger, D.

    2004-06-01

    To address, among other questions, puzzling observations about star forming in the extreme outer HI disk of M 31 (Cuillandre et al. 2001), a scenario of interstellar gas cycling between the visible and a very cold invisible phase is investigated. The key new element sketched here, allowing to maintain the bulk of the gas out of sight, is that molecular hydrogen becomes liquid or solid below 33 K at sufficiently high pressure, allowing AU-sized spheres of very cold gas to be stabilised by incompressible cores of condensed H2 (Pfenniger 2004). These predicted cold gas globules are relatively weakly bound (˜ 10-3 eV/nucleon), such that their lifetime depends directly on the ambient UV/CR excitation level. At galactic scale the globules behave as collisionless bodies, and evaporate and become the usual visible ISM gas through heating. Much of the ISM gas can thus spend a long time in this cold condensed phase in low excitation regions. N-body simulations of galactic disks modeling such effects have been run, and some of their features are described in more detail in this volume and elsewhere (Revaz & Pfenniger 2004).

  15. Multiscale Aspects of Modeling Gas-Phase Nanoparticle Synthesis

    PubMed Central

    Buesser, B.; Gröhn, A.J.

    2013-01-01

    Aerosol reactors are utilized to manufacture nanoparticles in industrially relevant quantities. The development, understanding and scale-up of aerosol reactors can be facilitated with models and computer simulations. This review aims to provide an overview of recent developments of models and simulations and discuss their interconnection in a multiscale approach. A short introduction of the various aerosol reactor types and gas-phase particle dynamics is presented as a background for the later discussion of the models and simulations. Models are presented with decreasing time and length scales in sections on continuum, mesoscale, molecular dynamics and quantum mechanics models. PMID:23729992

  16. Modeling acid-gas generation from boiling chloride brines

    SciTech Connect

    Zhang, Guoxiang; Spycher, Nicolas; Sonnenthal, Eric; Steefel, Carl

    2009-11-16

    This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150 C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent

  17. Turbulence modeling of gas-solid suspension flows

    NASA Technical Reports Server (NTRS)

    Chen, C. P.

    1988-01-01

    The purpose here is to discuss and review advances in two-phase turbulent modeling techniques and their applications in various gas-solid suspension flow situations. In addition to the turbulence closures, heat transfer effect, particle dispersion and wall effects are partially covered.

  18. Evaluation of dense-gas simulation models. Final report

    SciTech Connect

    Zapert, J.G.; Londergan, R.J.; Thistle, H.

    1991-05-01

    The report describes the approach and presents the results of an evaluation study of seven dense gas simulation models using data from three experimental programs. The models evaluated are two in the public domain (DEGADIS and SLAB) and five that are proprietary (AIRTOX, CHARM, FOCUS, SAFEMODE, and TRACE). The data bases used in the evaluation are the Desert Tortoise Pressurized Ammonia Releases, Burro Liquefied Natural Gas Spill Tests and the Goldfish Anhydrous Hydroflouric Acid Spill Experiments. A uniform set of performance statistics are calculated and tabulated to compare maximum observed concentrations and cloud half-width to those predicted by each model. None of the models demonstrated good performance consistently for all three experimental programs.

  19. A heterogeneous model for gas transport in carbon molecular sieves.

    PubMed

    Ding, L P; Yuan, Y X; Farooq, S; Bhatia, S K

    2005-01-18

    A dual resistance model with distribution of either barrier or pore diffusional activation energy is proposed in this work for gas transport in carbon molecular sieve (CMS) micropores. This is a novel approach in which the equilibrium is homogeneous, but the kinetics is heterogeneous. The model seems to provide a possible explanation for the concentration dependence of the thermodynamically corrected barrier and pore diffusion coefficients observed in previous studies from this laboratory on gas diffusion in CMS. The energy distribution is assumed to follow the gamma distribution function. It is shown that the energy distribution model can fully capture the behavior described by the empirical model established in earlier studies to account for the concentration dependence of thermodynamically corrected barrier and pore diffusion coefficients. A methodology is proposed for extracting energy distribution parameters, and it is further shown that the extracted energy distribution parameters can effectively predict integral uptake and column breakthrough profiles over a wide range of operating pressures.

  20. Modeling of diode pumped metastable rare gas lasers.

    PubMed

    Yang, Zining; Yu, Guangqi; Wang, Hongyan; Lu, Qisheng; Xu, Xiaojun

    2015-06-01

    As a new kind of optically pumped gaseous lasers, diode pumped metastable rare gas lasers (OPRGLs) show potential in high power operation. In this paper, a multi-level rate equation based model of OPRGL is established. A qualitative agreement between simulation and Rawlins et al.'s experimental result shows the validity of the model. The key parameters' influences and energy distribution characteristics are theoretically studied, which is useful for the optimized design of high efficient OPRGLs.

  1. Three dimensional thermobaric modeling of a gas hydrate system

    NASA Astrophysics Data System (ADS)

    Williams, Amanda Quigley

    Seismic imaging is recognized as the most cost effective method for identifying the presence of gas hydrate resources. The base of the gas hydrate stability zone is recognized by the presence of regionally extensive bottom simulating reflectors (BSR). However, in some areas such as the Gulf of Mexico, regionally extensive BSRs are not found. In such cases, an understanding of the thermobaric conditions may be used to determine the location of gas hydrates and the base of the gas hydrate stability zone. The aim of this research is to combine seismic velocity analysis and thermal modeling to predict the base of the hydrate stability zone. As a case study, we apply this modeling to the extensively documented site at Woolsey Mound, MC-118, Gulf of Mexico. Woolsey Mound, and much of the Gulf of Mexico, has been greatly affected by salt tectonics. Multiple seismic and CHIRP surveys have been collected at Woolsey Mound, but the base of the gas hydrate stability zone has been elusive due to the complexities associated with the presence of salt. The velocity analysis and previous studies on the sedimentary environment were the basis to derive the thermal and salinity conditions. Data from the heat flow survey provide an upper boundary condition at the sea floor in order to create a more accurate thermal model; the velocity model helped accurately place the salt diapir within the mound system. Hydrate phase equilibrium models were used to estimate a thermobaric model for Woolsey Mound. Using two different salinity gradients, the base of the gas hydrate stability zone was found to be located within 70 m of the seafloor with a salt concentration up to 90% at the shallowest point of the salt diapir, and 120 m of the seafloor with a salt concentration up to standard temperature and pressure conditions of salt (of approximately 56%) at the shallowest point of the salt diapir. This study provides a preliminary look at how the temperature and salinity affect the depth at which gas

  2. Modeling the Conductivity of a Subnanosecond Breakdown Gas Switch

    NASA Astrophysics Data System (ADS)

    Chen, Jinhui; Scott Tyo, J.; Jerald Buchenauer, C.

    We present two different modeling methods for understanding subnanosecond breakdown processes in gas plasma switches. The first method uses a finite element time domain method in order to understand experimental measurements of the remote electromagnetic (EM) fields. This method only models the EM fields and is good for analysis, but lacks a predictive capability for the full nonlinear plasma system. The second modeling method uses a PIC code, and is fully self consistent. We make comparisons with experimental measurements and conclude that the PIC model may provide a good understanding of the subnanosecond breakdown phenomena.

  3. Axisymmetric model of the ionized gas in the Orion Nebula

    NASA Technical Reports Server (NTRS)

    Rubin, R. H.; Simpson, J. P.; Haas, M. R.; Erickson, E. F.

    1991-01-01

    New ionization and thermal equilibrium models for the ionized gas in the Orion Nebula with an axisymmetric two-dimensional 'blister' geometry/density distribution are presented. The HII region is represented more realistically than in previous models, while the physical detail of the microphysics and radiative transfer of the earlier spherical modeling is maintained. The predicted surface brightnesses are compared with observations for a large set of lines at different positions to determine the best-fitting physical parameters. The model explains the strong singly ionized line emission along the lines of sight near the Trapezium.

  4. Natural Gas Transmission and Distribution Model of the National Energy Modeling System. Volume 1

    SciTech Connect

    1998-01-01

    The Natural Gas Transmission and Distribution Model (NGTDM) is the component of the National Energy Modeling System (NEMS) that is used to represent the domestic natural gas transmission and distribution system. The NGTDM is the model within the NEMS that represents the transmission, distribution, and pricing of natural gas. The model also includes representations of the end-use demand for natural gas, the production of domestic natural gas, and the availability of natural gas traded on the international market based on information received from other NEMS models. The NGTDM determines the flow of natural gas in an aggregate, domestic pipeline network, connecting domestic and foreign supply regions with 12 demand regions. The purpose of this report is to provide a reference document for model analysts, users, and the public that defines the objectives of the model, describes its basic design, provides detail on the methodology employed, and describes the model inputs, outputs, and key assumptions. Subsequent chapters of this report provide: an overview of NGTDM; a description of the interface between the NEMS and NGTDM; an overview of the solution methodology of the NGTDM; the solution methodology for the Annual Flow Module; the solution methodology for the Distributor Tariff Module; the solution methodology for the Capacity Expansion Module; the solution methodology for the Pipeline Tariff Module; and a description of model assumptions, inputs, and outputs.

  5. Model documentation: Natural Gas Transmission and Distribution Model of the National Energy Modeling System; Volume 1

    SciTech Connect

    1994-02-24

    The Natural Gas Transmission and Distribution Model (NGTDM) is a component of the National Energy Modeling System (NEMS) used to represent the domestic natural gas transmission and distribution system. NEMS is the third in a series of computer-based, midterm energy modeling systems used since 1974 by the Energy Information Administration (EIA) and its predecessor, the Federal Energy Administration, to analyze domestic energy-economy markets and develop projections. This report documents the archived version of NGTDM that was used to produce the natural gas forecasts used in support of the Annual Energy Outlook 1994, DOE/EIA-0383(94). The purpose of this report is to provide a reference document for model analysts, users, and the public that defines the objectives of the model, describes its basic design, provides detail on the methodology employed, and describes the model inputs, outputs, and key assumptions. It is intended to fulfill the legal obligation of the EIA to provide adequate documentation in support of its models (Public Law 94-385, Section 57.b.2). This report represents Volume 1 of a two-volume set. (Volume 2 will report on model performance, detailing convergence criteria and properties, results of sensitivity testing, comparison of model outputs with the literature and/or other model results, and major unresolved issues.) Subsequent chapters of this report provide: (1) an overview of the NGTDM (Chapter 2); (2) a description of the interface between the National Energy Modeling System (NEMS) and the NGTDM (Chapter 3); (3) an overview of the solution methodology of the NGTDM (Chapter 4); (4) the solution methodology for the Annual Flow Module (Chapter 5); (5) the solution methodology for the Distributor Tariff Module (Chapter 6); (6) the solution methodology for the Capacity Expansion Module (Chapter 7); (7) the solution methodology for the Pipeline Tariff Module (Chapter 8); and (8) a description of model assumptions, inputs, and outputs (Chapter 9).

  6. Exact solutions in a model of vertical gas migration

    SciTech Connect

    Silin, Dmitriy B.; Patzek, Tad W.; Benson, Sally M.

    2006-06-27

    This work is motivated by the growing interest in injectingcarbon dioxide into deep geological formations as a means of avoidingatmospheric emissions of carbon dioxide and consequent global warming.One of the key questions regarding the feasibility of this technology isthe potential rate of leakage out of the primary storage formation. Weseek exact solutions in a model of gas flow driven by a combination ofbuoyancy, viscous and capillary forces. Different combinations of theseforces and characteristic length scales of the processes lead todifferent time scaling and different types of solutions. In the case of athin, tight seal, where the impact of gravity is negligible relative tocapillary and viscous forces, a Ryzhik-type solution implies square-rootof time scaling of plume propagation velocity. In the general case, a gasplume has two stable zones, which can be described by travelling-wavesolutions. The theoretical maximum of the velocity of plume migrationprovides a conservative estimate for the time of vertical migration.Although the top of the plume has low gas saturation, it propagates witha velocity close to the theoretical maximum. The bottom of the plumeflows significantly more slowly at a higher gas saturation. Due to localheterogeneities, the plume can break into parts. Individual plumes alsocan coalesce and from larger plumes. The analytical results are appliedto studying carbon dioxide flow caused by leaks from deep geologicalformations used for CO2 storage. The results are also applicable formodeling flow of natural gas leaking from seasonal gas storage, or formodeling of secondary hydrocarbon migration.

  7. Validation of DWPF Melter Off-Gas Combustion Model

    SciTech Connect

    Choi, A.S.

    2000-08-23

    The empirical melter off-gas combustion model currently used in the DWPF safety basis calculations is valid at melter vapor space temperatures above 570 degrees C, as measured in the thermowell. This lower temperature bound coincides with that of the off-gas data used as the basis of the model. In this study, the applicability of the empirical model in a wider temperature range was assessed using the off-gas data collected during two small-scale research melter runs. The first data set came from the Small Cylindrical Melter-2 run in 1985 with the sludge feed coupled with the precipitate hydrolysis product. The second data set came from the 774-A melter run in 1996 with the sludge-only feed prepared with the modified acid addition strategy during the feed pretreatment step. The results of the assessment showed that the data from these two melter runs agreed well with the existing model, and further provided the basis for extending the lower temperature bound of the model to the measured melter vapor space temperature of 445 degrees C.

  8. Modeling signal loss in surficial marine sediments containing occluded gas

    NASA Astrophysics Data System (ADS)

    Gardner, Trevor

    2003-03-01

    The presence of occluded gas in inland lakes, harbor muds, and surficial marine sediments is well documented. Surficial gassy sediments cause underlying beds to be acoustically impenetrable to seismic surveys; therefore, the modeling of signal loss arising from mudline reflection and transmission absorption is of particular interest. The Anderson and Hampton [J. Acoust. Soc. Am. 67, 1890-1903 (1980)] model for attenuation in gassy sediments was evaluated against the physical and acoustical properties of eight laboratory silty clay soils containing different amounts of occluded gas in bubbles of 0.2- to 1.8-mm diameter. The model was shown to give good agreement with measured data over the lower frequencies of bubble resonance and above resonance. It did not agree with measured data at frequencies below resonance, for which the model did not simulate the bulk properties of the gassy soils. The Mackenzie [J. Acoust. Soc. Am. 32, 221-231 (1960)] model for reflection loss was also examined for the gassy soils. The maximum reflection losses of 6 dB, at a grazing angle of 40°, does not wholly support speculation by Levin [Geophysics 27, 35-47 (1962)] of highly reflective pressure-release boundaries arising from substantial reflection and absorption losses in gassy sediments. It was found that mudlines formed from sediments with significant occluded gas may be successfully penetrated, although the substantial absorption loss arising from signal transmission through the sediment prevents penetration of the surficial layers to much beyond a meter in depth.

  9. Off-Gas Adsorption Model Capabilities and Recommendations

    SciTech Connect

    Lyon, Kevin L.; Welty, Amy K.; Law, Jack; Ladshaw, Austin; Yiacoumi, Sotira; Tsouris, Costas

    2016-03-01

    Off-gas treatment is required to reduce emissions from aqueous fuel reprocessing. Evaluating the products of innovative gas adsorption research requires increased computational simulation capability to more effectively transition from fundamental research to operational design. Early modeling efforts produced the Off-Gas SeParation and REcoverY (OSPREY) model that, while efficient in terms of computation time, was of limited value for complex systems. However, the computational and programming lessons learned in development of the initial model were used to develop Discontinuous Galerkin OSPREY (DGOSPREY), a more effective model. Initial comparisons between OSPREY and DGOSPREY show that, while OSPREY does reasonably well to capture the initial breakthrough time, it displays far too much numerical dispersion to accurately capture the real shape of the breakthrough curves. DGOSPREY is a much better tool as it utilizes a more stable set of numerical methods. In addition, DGOSPREY has shown the capability to capture complex, multispecies adsorption behavior, while OSPREY currently only works for a single adsorbing species. This capability makes DGOSPREY ultimately a more practical tool for real world simulations involving many different gas species. While DGOSPREY has initially performed very well, there is still need for improvement. The current state of DGOSPREY does not include any micro-scale adsorption kinetics and therefore assumes instantaneous adsorption. This is a major source of error in predicting water vapor breakthrough because the kinetics of that adsorption mechanism is particularly slow. However, this deficiency can be remedied by building kinetic kernels into DGOSPREY. Another source of error in DGOSPREY stems from data gaps in single species, such as Kr and Xe, isotherms. Since isotherm data for each gas is currently available at a single temperature, the model is unable to predict adsorption at temperatures outside of the set of data currently

  10. Gas Modelling in the Disc of HD 163296

    NASA Technical Reports Server (NTRS)

    Tilling, I.; Woitke, P.; Meeus, G.; Mora, A.; Montesinos, B.; Riviere-Marichalar, P.; Eiroa, C.; Thi, W. -F.; Isella, A.; Roberge, A.; Martin-Zaidi, C.; Kamp, I.; Pinte, C.; Sandell, G.; Vacca, W. D.; Menard, F.; Mendigutia, I.; Duchene, G.; Dent, W. R. F.; Aresu, G.; Meijerink, R.; Spaans, M.

    2011-01-01

    We present detailed model fits to observations of the disc around the Herbig Ae star HD 163296. This well-studied object has an age of approx. 4Myr, with evidence of a circumstellar disc extending out to approx. 540AU. We use the radiation thermo-chemical disc code ProDiMo to model the gas and dust in the circumstellar disc of HD 163296, and attempt to determine the disc properties by fitting to observational line and continuum data. These include new Herschel/PACS observations obtained as part of the open-time key program GASPS (Gas in Protoplanetary Systems), consisting of a detection of the [Oi] 63 m line and upper limits for several other far infrared lines. We complement this with continuum data and ground-based observations of the CO-12 3-2, 2-1 and CO-13 J=1-0 line transitions, as well as the H2 S(1) transition. We explore the effects of stellar ultraviolet variability and dust settling on the line emission, and on the derived disc properties. Our fitting efforts lead to derived gas/dust ratios in the range 9-100, depending on the assumptions made. We note that the line fluxes are sensitive in general to the degree of dust settling in the disc, with an increase in line flux for settled models. This is most pronounced in lines which are formed in the warm gas in the inner disc, but the low excitation molecular lines are also affected. This has serious implications for attempts to derive the disc gas mass from line observations. We derive fractional PAH abundances between 0.007 and 0.04 relative to ISM levels. Using a stellar and UV excess input spectrum based on a detailed analysis of observations, we find that the all observations are consistent with the previously assumed disc geometry

  11. Estimating methane gas generation from Devil's swamp landfill using greenhouse gas emission models

    NASA Astrophysics Data System (ADS)

    Adeyemi, Ayodeji Thompson

    Greenhouse gas (GHG) has been a key issue in the study, design, and management of landfills. Landfill gas (LFG) is considered either as a significant source of renewable energy (if extracted and processed accordingly) or significant source of pollution and risk (if not mitigated or processed). A municipal solid waste (MSW) landfill emits a significant amount of methane, a potent GHG. Thus, quantification and mitigation of GHG emissions is an important area of study in engineering and other sciences related to landfill technology and management. The present study will focus on estimating methane generation from Devils swamp landfill (DSLF), a closed landfill in Baton Rouge, LA. The landfill operated for 53 years (1940-1993) and contains both industrial and municipal waste products. Since the Clean Air Act of 1963, landfills are now classified as New Source Performance Standard (NSPS) waste (i.e., waste that will decompose to generate LFG). Currently, the DSLF is being used as source of renewable energy through the "Waste to Energy" program. For this study, to estimate the methane potential in the DSLF, it is important to determine the characteristics and classification of the landfill's wastes. The study uses and compares different GHG modeling tools---LandGEM, a multiphase model, and a simple first-order model---to estimate methane gas emission and compare results with the actual emissions from the DSLF. The sensitivity of the methane generation rate was analyzed by the methane generation models to assess the effects of variables such as initial conditions, specific growth rate, and reaction rate constants. The study concludes that methane (L0) and initial organic concentration in waste (k) are the most important parameters when estimating methane generation using the models.

  12. Sorption Modeling and Verification for Off-Gas Treatment

    SciTech Connect

    Tavlarides, Lawrence; Yiacoumi, Sotira; Tsouris, Costas; Gabitto, Jorge; DePaoli, David

    2016-12-20

    This project was successfully executed to provide valuable adsorption data and improve a comprehensive model developed in previous work by the authors. Data obtained were used in an integrated computer program to predict the behavior of adsorption columns. The model is supported by experimental data and has been shown to predict capture of off gas similar to that evolving during the reprocessing of nuclear waste. The computer program structure contains (a) equilibrium models of off-gases with the adsorbate; (b) mass-transfer models to describe off-gas mass transfer to a particle, diffusion through the pores of the particle, and adsorption on the active sites of the particle; and (c) incorporation of these models into fixed bed adsorption modeling, which includes advection through the bed. These models are being connected with the MOOSE (Multiphysics Object-Oriented Simulation Environment) software developed at the Idaho National Laboratory through DGOSPREY (Discontinuous Galerkin Off-gas SeParation and REcoverY) computer codes developed in this project. Experiments for iodine and water adsorption have been conducted on reduced silver mordenite (Ag0Z) for single layered particles. Adsorption apparatuses have been constructed to execute these experiments over a useful range of conditions for temperatures ranging from ambient to 250°C and water dew points ranging from -69 to 19°C. Experimental results were analyzed to determine mass transfer and diffusion of these gases into the particles and to determine which models best describe the single and binary component mass transfer and diffusion processes. The experimental results were also used to demonstrate the capabilities of the comprehensive models developed to predict single-particle adsorption and transients of the adsorption-desorption processes in fixed beds. Models for adsorption and mass transfer have been developed to mathematically describe adsorption kinetics and transport via diffusion and advection

  13. Preliminary numerical analysis of improved gas chromatograph model

    NASA Technical Reports Server (NTRS)

    Woodrow, P. T.

    1973-01-01

    A mathematical model for the gas chromatograph was developed which incorporates the heretofore neglected transport mechanisms of intraparticle diffusion and rates of adsorption. Because a closed-form analytical solution to the model does not appear realizable, techniques for the numerical solution of the model equations are being investigated. Criteria were developed for using a finite terminal boundary condition in place of an infinite boundary condition used in analytical solution techniques. The class of weighted residual methods known as orthogonal collocation is presently being investigated and appears promising.

  14. Gas Generation in Radioactive Wastes - MAGGAS Predictive Life Cycle Model

    SciTech Connect

    Streatfield, R.E.; Hebditch, D.J.; Swift, B.T.; Hoch, A.R.; Constable, M.

    2006-07-01

    Gases may form from radioactive waste in quantities posing different potential hazards throughout the waste package life cycle. The latter includes surface storage, transport, placing in an operating repository, storage in the repository prior to backfill, closure and the post-closure stage. Potentially hazardous situations involving gas include fire, flood, dropped packages, blocked package vents and disruption to a sealed repository. The MAGGAS (Magnox Gas generation) model was developed to assess gas formation for safety assessments during all stages of the waste package life cycle. This is a requirement of the U.K. regulatory authorities and Nirex and progress in this context is discussed. The processes represented in the model include: Corrosion, microbial degradation, radiolysis, solid-state diffusion, chemico-physical degradation and pressurisation. The calculation was split into three time periods. First the 'aerobic phase' is used to model the periods of surface storage, transport and repository operations including storage in the repository prior to backfill. The second and third periods were designated 'anaerobic phase 1' and 'anaerobic phase 2' and used to model the waste packages in the post-closure phase of the repository. The various significant gas production processes are modeled in each phase. MAGGAS (currently Version 8) is mounted on an Excel spreadsheet for ease of use and speed, has 22 worksheets and is operated routinely for assessing waste packages (e.g. for ventilation of stores and pressurisation of containers). Ten operational and decommissioning generic nuclear power station waste streams were defined as initial inputs, which included ion exchange materials, sludges and concentrates, fuel element debris, graphite debris, activated components, contaminated items, desiccants and catalysts. (authors)

  15. Multi-Scale Modeling of Hypersonic Gas Flow

    NASA Astrophysics Data System (ADS)

    Boyd, Iain D.

    On March 27, 2004, NASA successfully flew the X-43A hypersonic test flight vehicle at a velocity of 5000 mph to break the aeronautics speed record that had stood for over 35 years. The final flight of the X-43A on November 16, 2004 further increased the speed record to 6,600 mph which is almost ten times the speed of sound. The very high speed attainable by hypersonic airplanes could revolutionize air travel by dramatically reducing inter-continental flight times. For example, a hypersonic flight from New York to Sydney, Australia, a distance of 10,000 miles, would take less than 2 h. Reusable hypersonic vehicles are also being researched to significantly reduce the cost of access to space. Computer modeling of the gas flows around hypersonic vehicles will play a critical part in their development. This article discusses the conditions that can prevail in certain hypersonic gas flows that require a multi-scale modeling approach.

  16. Calculations of hot gas ingestion for a STOVL aircraft model

    NASA Technical Reports Server (NTRS)

    Fricker, David M.; Holdeman, James D.; Vanka, Surya P.

    1992-01-01

    Hot gas ingestion problems for Short Take-Off, Vertical Landing (STOVL) aircraft are typically approached with empirical methods and experience. In this study, the hot gas environment around a STOVL aircraft was modeled as multiple jets in crossflow with inlet suction. The flow field was calculated with a Navier-Stokes, Reynolds-averaged, turbulent, 3D computational fluid dynamics code using a multigrid technique. A simple model of a STOVL aircraft with four choked jets at 1000 K was studied at various heights, headwind speeds, and thrust splay angles in a modest parametric study. Scientific visualization of the computed flow field shows a pair of vortices in front of the inlet. This and other qualitative aspects of the flow field agree well with experimental data.

  17. Modeling of modification experiments involving neutral-gas release

    SciTech Connect

    Bernhardt, P.A.

    1983-01-01

    Many experiments involve the injection of neutral gases into the upper atmosphere. Examples are critical velocity experiments, MHD wave generation, ionospheric hole production, plasma striation formation, and ion tracing. Many of these experiments are discussed in other sessions of the Active Experiments Conference. This paper limits its discussion to: (1) the modeling of the neutral gas dynamics after injection, (2) subsequent formation of ionosphere holes, and (3) use of such holes as experimental tools.

  18. 75 FR 53371 - Liquefied Natural Gas Facilities: Obtaining Approval of Alternative Vapor-Gas Dispersion Models

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-08-31

    ... Pipeline and Hazardous Materials Safety Administration Liquefied Natural Gas Facilities: Obtaining Approval... Safety Administration (PHMSA) issues federal safety standards for siting liquefied natural gas (LNG...) NFPA 59A: Standard for the Production, Storage, and Handling of Liquefied Natural Gas. That...

  19. Compressible cell gas models for asymmetric fluid criticality

    NASA Astrophysics Data System (ADS)

    Cerdeiriña, Claudio A.; Orkoulas, Gerassimos

    2017-03-01

    We thoroughly describe a class of models recently presented by Fisher and coworkers [Phys. Rev. Lett. 116, 040601 (2016)], 10.1103/PhysRevLett.116.040601. The crucial feature of such models, termed compressible cell gases (CCGs), is that the individual cell volumes of a lattice gas are allowed to fluctuate. They are studied via the seldom-used (μ , p , T ) ensemble, which leads to their exact mapping onto the Ising model. Remarkably, CCGs obey complete scaling, a formulation for the thermodynamic behavior of fluids near the gas-liquid critical point that accommodates features inherent to the asymmetric nature of this phase transition like the Yang-Yang (YY) and singular coexistence-curve diameter anomalies. The CCG0 models generated when volumes vary freely reveal local free volume fluctuations as the origin of these phenomena. Local energy-volume coupling is found to be another relevant microscopic factor. Furthermore, the CCG class is greatly extended by using the decoration transformation, with an interesting example being the Sastry-Debenedetti-Sciortino-Stanley model for hydrogen bonding in low-temperature water. The magnitude of anomalies is characterized by a single parameter, the YY ratio, which for the models so far considered here ranges from -∞ to 1/2 .

  20. Robustness of disaggregate oil and gas discovery forecasting models

    USGS Publications Warehouse

    Attanasi, E.D.; Schuenemeyer, J.H.

    1989-01-01

    The trend in forecasting oil and gas discoveries has been to develop and use models that allow forecasts of the size distribution of future discoveries. From such forecasts, exploration and development costs can more readily be computed. Two classes of these forecasting models are the Arps-Roberts type models and the 'creaming method' models. This paper examines the robustness of the forecasts made by these models when the historical data on which the models are based have been subject to economic upheavals or when historical discovery data are aggregated from areas having widely differing economic structures. Model performance is examined in the context of forecasting discoveries for offshore Texas State and Federal areas. The analysis shows how the model forecasts are limited by information contained in the historical discovery data. Because the Arps-Roberts type models require more regularity in discovery sequence than the creaming models, prior information had to be introduced into the Arps-Roberts models to accommodate the influence of economic changes. The creaming methods captured the overall decline in discovery size but did not easily allow introduction of exogenous information to compensate for incomplete historical data. Moreover, the predictive log normal distribution associated with the creaming model methods appears to understate the importance of the potential contribution of small fields. ?? 1989.

  1. Filter-matrix lattice Boltzmann model for microchannel gas flows.

    PubMed

    Zhuo, Congshan; Zhong, Chengwen

    2013-11-01

    The lattice Boltzmann method has been shown to be successful for microscale gas flows, and it has attracted significant research interest. In this paper, the recently proposed filter-matrix lattice Boltzmann (FMLB) model is first applied to study the microchannel gas flows, in which a Bosanquet-type effective viscosity is used to capture the flow behaviors in the transition regime. A kinetic boundary condition, the combined bounce-back and specular-reflection scheme with the second-order slip scheme, is also designed for the FMLB model. By analyzing a unidirectional flow, the slip velocity and the discrete effects related to the boundary condition are derived within the FMLB model, and a revised scheme is presented to overcome such effects, which have also been validated through numerical simulations. To gain an accurate simulation in a wide range of Knudsen numbers, covering the slip and the entire transition flow regimes, a set of slip coefficients with an introduced fitting function is adopted in the revised second-order slip boundary condition. The periodic and pressure-driven microchannel flows have been investigated by the present model in this study. The numerical results, including the velocity profile and the mass flow rate, as well as the nonlinear pressure distribution along the channel, agree fairly well with the solutions of the linearized Boltzmann equation, the direct simulation Monte Carlo results, the experimental data, and the previous results of the multiple effective relaxation lattice Boltzmann model. Also, the present results of the velocity profile and the mass flow rate show that the present model with the fitting function can yield improved predictions for the microchannel gas flow with higher Knudsen numbers in the transition flow regime.

  2. Shawnee flue gas desulfurization computer model users manual

    SciTech Connect

    Sudhoff, F.A.; Torstrick, R.L.

    1985-03-01

    In conjunction with the US Enviromental Protection Agency sponsored Shawnee test program, Bechtel National, Inc., and the Tennessee Valley Authority jointly developed a computer model capable of projecting preliminary design and economics for lime- and limestone-scrubbing flue gas desulfurization systems. The model is capable of projecting relative economics for spray tower, turbulent contact absorber, and venturi-spray tower scrubbing options. It may be used to project the effect on system design and economics of variations in required SO/sub 2/ removal, scrubber operating parameters (gas velocity, liquid-to-gas (L/G) ration, alkali stoichiometry, liquor hold time in slurry recirculation tanks), reheat temperature, and scrubber bypass. It may also be used to evaluate alternative waste disposal methods or additives (MgO or adipic acid) on costs for the selected process. Although the model is not intended to project the economics of an individual system to a high degree of accuracy, it allows prospective users to quickly project comparative design and costs for limestone and lime case variations on a common design and cost basis. The users manual provides a general descripton of the Shawnee FGD computer model and detailed instructions for its use. It describes and explains the user-supplied input data which are required such as boiler size, coal characteristics, and SO/sub 2/ removal requirments. Output includes a material balance, equipment list, and detailed capital investment and annual revenue requirements. The users manual provides information concerning the use of the overall model as well as sample runs to serve as a guide to prospective users in identifying applications. The FORTRAN-based model is maintained by TVA, from whom copies or individual runs are available. 25 refs., 3 figs., 36 tabs.

  3. Material point method modeling in oil and gas reservoirs

    DOEpatents

    Vanderheyden, William Brian; Zhang, Duan

    2016-06-28

    A computer system and method of simulating the behavior of an oil and gas reservoir including changes in the margins of frangible solids. A system of equations including state equations such as momentum, and conservation laws such as mass conservation and volume fraction continuity, are defined and discretized for at least two phases in a modeled volume, one of which corresponds to frangible material. A material point model technique for numerically solving the system of discretized equations, to derive fluid flow at each of a plurality of mesh nodes in the modeled volume, and the velocity of at each of a plurality of particles representing the frangible material in the modeled volume. A time-splitting technique improves the computational efficiency of the simulation while maintaining accuracy on the deformation scale. The method can be applied to derive accurate upscaled model equations for larger volume scale simulations.

  4. Gas dynamics modeling of the HYLIFE-II reactor

    SciTech Connect

    Jantzen, C.

    1995-08-01

    Gas dynamics in the IFE reactor, HYLIFE-II is modeled using the code, TSUNAMI. This code is a 2-D shock-solver that uses the Godunov method with operator splitting. Results from a cylindrically symmetric simulation indicate an initial, low density, burst of high energy particles enters the final focus transport lens within 40 microseconds after the blast, much faster than the proposed 1 millisecond shutter closing time. After approximately 100 microseconds the chamber debris flux levels off to one eighth its peak value and maintains this intensity until the shutter closes. Although initial protective jet ablation is considered, neither secondary radiation nor condensation are modeled. Therefore results are conservative.

  5. Empirical slip and viscosity model performance for microscale gas flows.

    SciTech Connect

    Gallis, Michail A.; Boyd, Iain D.; McNenly, Matthew J.

    2004-07-01

    For the simple geometries of Couette and Poiseuille flows, the velocity profile maintains a similar shape from continuum to free molecular flow. Therefore, modifications to the fluid viscosity and slip boundary conditions can improve the continuum based Navier-Stokes solution in the non-continuum non-equilibrium regime. In this investigation, the optimal modifications are found by a linear least-squares fit of the Navier-Stokes solution to the non-equilibrium solution obtained using the direct simulation Monte Carlo (DSMC) method. Models are then constructed for the Knudsen number dependence of the viscosity correction and the slip model from a database of DSMC solutions for Couette and Poiseuille flows of argon and nitrogen gas, with Knudsen numbers ranging from 0.01 to 10. Finally, the accuracy of the models is measured for non-equilibrium cases both in and outside the DSMC database. Flows outside the database include: combined Couette and Poiseuille flow, partial wall accommodation, helium gas, and non-zero convective acceleration. The models reproduce the velocity profiles in the DSMC database within an L{sub 2} error norm of 3% for Couette flows and 7% for Poiseuille flows. However, the errors in the model predictions outside the database are up to five times larger.

  6. Electro-thermal modeling of a microbridge gas sensor

    SciTech Connect

    Manginell, R.P.; Smith, J.H.; Ricco, A.J.; Hughes, R.C.; Moreno, D.J.; Huber, R.J.

    1997-08-01

    Fully CMOS-compatible, surface-micromachined polysilicon microbridges have been designed, fabricated, and tested for use in catalytic, calorimetric gas sensing. To improve sensor behavior, extensive electro-thermal modeling efforts were undertaken using SPICE. The validity of the SPICE model was verified comparing its simulated behavior with experiment. Temperature distribution of an electrically heated microbridges was measured using an infrared microscope. Comparisons among the measured distribution, the SPICE simulation, and distributions obtained by analytical methods show that heating at the ends of a microbridges has important implications for device response. Additional comparisons between measured and simulated current-voltage characteristics, as well as transient response, further support the accuracy of the model. A major benefit of electro- thermal modeling with SPICE is the ability to simultaneously simulate the behavior of a device and its control/sensing electronics. Results for the combination of a unique constant-resistance control circuit and microbridges gas sensor are given. Models of in situ techniques for monitoring catalyst deposition are shown to be in agreement with experiment. Finally, simulated chemical response of the detector is compared with the data, and methods of improving response through modifications in bridge geometry are predicted.

  7. Natural gas production problems : solutions, methodologies, and modeling.

    SciTech Connect

    Rautman, Christopher Arthur; Herrin, James M.; Cooper, Scott Patrick; Basinski, Paul M.; Olsson, William Arthur; Arnold, Bill Walter; Broadhead, Ronald F.; Knight, Connie D.; Keefe, Russell G.; McKinney, Curt; Holm, Gus; Holland, John F.; Larson, Rich; Engler, Thomas W.; Lorenz, John Clay

    2004-10-01

    Natural gas is a clean fuel that will be the most important domestic energy resource for the first half the 21st centtuy. Ensuring a stable supply is essential for our national energy security. The research we have undertaken will maximize the extractable volume of gas while minimizing the environmental impact of surface disturbances associated with drilling and production. This report describes a methodology for comprehensive evaluation and modeling of the total gas system within a basin focusing on problematic horizontal fluid flow variability. This has been accomplished through extensive use of geophysical, core (rock sample) and outcrop data to interpret and predict directional flow and production trends. Side benefits include reduced environmental impact of drilling due to reduced number of required wells for resource extraction. These results have been accomplished through a cooperative and integrated systems approach involving industry, government, academia and a multi-organizational team within Sandia National Laboratories. Industry has provided essential in-kind support to this project in the forms of extensive core data, production data, maps, seismic data, production analyses, engineering studies, plus equipment and staff for obtaining geophysical data. This approach provides innovative ideas and technologies to bring new resources to market and to reduce the overall environmental impact of drilling. More importantly, the products of this research are not be location specific but can be extended to other areas of gas production throughout the Rocky Mountain area. Thus this project is designed to solve problems associated with natural gas production at developing sites, or at old sites under redevelopment.

  8. Monte Carlo modeling and optimization of buffer gas positron traps

    NASA Astrophysics Data System (ADS)

    Marjanović, Srđan; Petrović, Zoran Lj

    2017-02-01

    Buffer gas positron traps have been used for over two decades as the prime source of slow positrons enabling a wide range of experiments. While their performance has been well understood through empirical studies, no theoretical attempt has been made to quantitatively describe their operation. In this paper we apply standard models as developed for physics of low temperature collision dominated plasmas, or physics of swarms to model basic performance and principles of operation of gas filled positron traps. The Monte Carlo model is equipped with the best available set of cross sections that were mostly derived experimentally by using the same type of traps that are being studied. Our model represents in realistic geometry and fields the development of the positron ensemble from the initial beam provided by the solid neon moderator through voltage drops between the stages of the trap and through different pressures of the buffer gas. The first two stages employ excitation of N2 with acceleration of the order of 10 eV so that the trap operates under conditions when excitation of the nitrogen reduces the energy of the initial beam to trap the positrons without giving them a chance to become annihilated following positronium formation. The energy distribution function develops from the assumed distribution leaving the moderator, it is accelerated by the voltage drops and forms beams at several distinct energies. In final stages the low energy loss collisions (vibrational excitation of CF4 and rotational excitation of N2) control the approach of the distribution function to a Maxwellian at room temperature but multiple non-Maxwellian groups persist throughout most of the thermalization. Optimization of the efficiency of the trap may be achieved by changing the pressure and voltage drops and also by selecting to operate in a two stage mode. The model allows quantitative comparisons and test of optimization as well as development of other properties.

  9. Sorption Modeling and Verification for Off-Gas Treatment

    SciTech Connect

    Tavlarides, Lawrence L.; Lin, Ronghong; Nan, Yue; Yiacoumi, Sotira; Tsouris, Costas; Ladshaw, Austin; Sharma, Ketki; Gabitto, Jorge; DePaoli, David

    2015-04-29

    The project has made progress toward developing a comprehensive modeling capability for the capture of target species in off gas evolved during the reprocessing of nuclear fuel. The effort has integrated experimentation, model development, and computer code development for adsorption and absorption processes. For adsorption, a modeling library has been initiated to include (a) equilibrium models for uptake of off-gas components by adsorbents, (b) mass transfer models to describe mass transfer to a particle, diffusion through the pores of the particle and adsorption on the active sites of the particle, and (c) interconnection of these models to fixed bed adsorption modeling which includes advection through the bed. For single-component equilibria, a Generalized Statistical Thermodynamic Adsorption (GSTA) code was developed to represent experimental data from a broad range of isotherm types; this is equivalent to a Langmuir isotherm in the two-parameter case, and was demonstrated for Kr on INL-engineered sorbent HZ PAN, water sorption on molecular sieve A sorbent material (MS3A), and Kr and Xe capture on metal-organic framework (MOF) materials. The GSTA isotherm was extended to multicomponent systems through application of a modified spreading pressure surface activity model and generalized predictive adsorbed solution theory; the result is the capability to estimate multicomponent adsorption equilibria from single-component isotherms. This advance, which enhances the capability to simulate systems related to off-gas treatment, has been demonstrated for a range of real-gas systems in the literature and is ready for testing with data currently being collected for multicomponent systems of interest, including iodine and water on MS3A. A diffusion kinetic model for sorbent pellets involving pore and surface diffusion as well as external mass transfer has been established, and a methodology was developed for determining unknown diffusivity parameters from transient

  10. The nonequilibrium Ehrenfest gas: A chaotic model with flat obstacles?

    NASA Astrophysics Data System (ADS)

    Bianca, Carlo; Rondoni, Lamberto

    2009-03-01

    It is known that the nonequilibrium version of the Lorentz gas (a billiard with dispersing obstacles [Ya. G. Sinai, Russ. Math. Surv. 25, 137 (1970)], electric field, and Gaussian thermostat) is hyperbolic if the field is small [N. I. Chernov, Ann. Henri Poincare 2, 197 (2001)]. Differently the hyperbolicity of the nonequilibrium Ehrenfest gas constitutes an open problem since its obstacles are rhombi and the techniques so far developed rely on the dispersing nature of the obstacles [M. P. Wojtkowski, J. Math. Pures Appl. 79, 953 (2000)]. We have developed analytical and numerical investigations that support the idea that this model of transport of matter has both chaotic (positive Lyapunov exponent) and nonchaotic steady states with a quite peculiar sensitive dependence on the field and on the geometry, not observed before. The associated transport behavior is correspondingly highly irregular, with features whose understanding is of both theoretical and technological interests.

  11. Modeling the hole configuration on gas turbine blade vane

    NASA Astrophysics Data System (ADS)

    Zakaria, Mohamad Shukri; Manaf, Muhammad Zaidan Abdul; Saadun, Mohd Noor Asril; Jumaidin, Ridhwan; Hafizan, Andi Hairul

    2015-05-01

    The performance of Gas Turbine can be improved by increasing the inlet temperature gradually. The high level temperature of component that contact with hot gases due to internal combustion in gas turbine will make possibility failure especially on turbine vane. Thus, this study aims to identify the best hole arrangement of cooling on turbine vane, and investigate the critical region for failure possibilities occur on turbine vane caused by the hot gases that considered into two parameter which are steady temperature profile and average temperature decreasing on blade. This study will implement C3X type vane in order to improve the process in turbine blades. An arrangement of two dimensional blade hole will be model Commercial software ANSYS Fluent. It is found that best arrangement and configuration between the hole shape can improve resistances in relation to thermal collapse and satisfied the blade cooling goal.

  12. Generalized gas-solid adsorption modeling: Single-component equilibria

    SciTech Connect

    Ladshaw, Austin; Yiacoumi, Sotira; Tsouris, Costas; DePaoli, David W.

    2015-01-07

    Over the last several decades, modeling of gas–solid adsorption at equilibrium has generally been accomplished through the use of isotherms such as the Freundlich, Langmuir, Tóth, and other similar models. While these models are relatively easy to adapt for describing experimental data, their simplicity limits their generality to be used with many different sets of data. This limitation forces engineers and scientists to test each different model in order to evaluate which one can best describe their data. Additionally, the parameters of these models all have a different physical interpretation, which may have an effect on how they can be further extended into kinetic, thermodynamic, and/or mass transfer models for engineering applications. Therefore, it is paramount to adopt not only a more general isotherm model, but also a concise methodology to reliably optimize for and obtain the parameters of that model. A model of particular interest is the Generalized Statistical Thermodynamic Adsorption (GSTA) isotherm. The GSTA isotherm has enormous flexibility, which could potentially be used to describe a variety of different adsorption systems, but utilizing this model can be fairly difficult due to that flexibility. To circumvent this complication, a comprehensive methodology and computer code has been developed that can perform a full equilibrium analysis of adsorption data for any gas-solid system using the GSTA model. The code has been developed in C/C++ and utilizes a Levenberg–Marquardt’s algorithm to handle the non-linear optimization of the model parameters. Since the GSTA model has an adjustable number of parameters, the code iteratively goes through all number of plausible parameters for each data set and then returns the best solution based on a set of scrutiny criteria. Data sets at different temperatures are analyzed serially and then linear correlations with temperature are made for the parameters of the model. The end result is a full set of

  13. Generalized gas-solid adsorption modeling: Single-component equilibria

    DOE PAGES

    Ladshaw, Austin; Yiacoumi, Sotira; Tsouris, Costas; ...

    2015-01-07

    Over the last several decades, modeling of gas–solid adsorption at equilibrium has generally been accomplished through the use of isotherms such as the Freundlich, Langmuir, Tóth, and other similar models. While these models are relatively easy to adapt for describing experimental data, their simplicity limits their generality to be used with many different sets of data. This limitation forces engineers and scientists to test each different model in order to evaluate which one can best describe their data. Additionally, the parameters of these models all have a different physical interpretation, which may have an effect on how they can bemore » further extended into kinetic, thermodynamic, and/or mass transfer models for engineering applications. Therefore, it is paramount to adopt not only a more general isotherm model, but also a concise methodology to reliably optimize for and obtain the parameters of that model. A model of particular interest is the Generalized Statistical Thermodynamic Adsorption (GSTA) isotherm. The GSTA isotherm has enormous flexibility, which could potentially be used to describe a variety of different adsorption systems, but utilizing this model can be fairly difficult due to that flexibility. To circumvent this complication, a comprehensive methodology and computer code has been developed that can perform a full equilibrium analysis of adsorption data for any gas-solid system using the GSTA model. The code has been developed in C/C++ and utilizes a Levenberg–Marquardt’s algorithm to handle the non-linear optimization of the model parameters. Since the GSTA model has an adjustable number of parameters, the code iteratively goes through all number of plausible parameters for each data set and then returns the best solution based on a set of scrutiny criteria. Data sets at different temperatures are analyzed serially and then linear correlations with temperature are made for the parameters of the model. The end result is a full set

  14. Modeling Circumgalactic Gas During the Peak Epoch of Galaxy Growth

    NASA Astrophysics Data System (ADS)

    Dave, Romeel

    During the peak of cosmic star formation at z=1-4, galaxy growth is increasingly believed to be modulated by large-scale inflows and outflows of baryons that intimately connect galaxies to their surrounding circumgalactic medium (CGM). Unfortunately, direct observational signatures of these baryon cycling processes are elusive and fragmented, owing to the diffuse and multi- phase nature of the CGM. This proposal aims to use advanced multi-scale cosmological hydrodynamic simulations to investigate how inflows and outflows within circumgalactic gas are manifested in present and future observables, and how those observables in turn constrain the physical processes driving galaxy evolution. The simulation methodology includes ``random" cosmological runs, ``zoom" runs of individual halos, and radiative transfer to better model the ionization conditions. We will focus on absorption and emission signatures in HI and metal lines using common rest-UV and rest-optical tracers. Key questions include: How do metal absorbers trace the enrichment and ionization conditions within circumgalactic gas? How much absorption arises from inflow versus outflow, and what are the characteristic absorption, emission, and/or kinematic signatures of each? What emission lines from CGM gas are predicted to be observable, and how does the combination of emission and absorption constrain CGM properties? What are the roles of metallicity, ionization, and large-scale structure in establishing the correlations of metal absorbers and galaxies on CGM scales? How do all these CGM properties relate to host galaxy properties such as mass, and how do they vary with outflow model? The overall goal is to develop a comprehensive hierarchical-based framework for assembling various observations of circumgalactic gas into a unified scenario for how inflows and outflows govern the growth of galaxies.

  15. Gas-Grain Models for Interstellar Anion Chemistry

    NASA Technical Reports Server (NTRS)

    Cordiner, M. A.; Charnely, S. B.

    2012-01-01

    Long-chain hydrocarbon anions C(sub n) H(-) (n = 4, 6, 8) have recently been found to be abundant in a variety of interstellar clouds. In order to explain their large abundances in the denser (prestellar/protostellar) environments, new chemical models are constructed that include gas-grain interactions. Models including accretion of gas-phase species onto dust grains and cosmic-ray-induced desorption of atoms are able to reproduce the observed anion-to-neutral ratios, as well as the absolute abundances of anionic and neutral carbon chains, with a reasonable degree of accuracy. Due to their destructive effects, the depletion of oxygen atoms onto dust results in substantially greater polyyne and anion abundances in high-density gas (with n(sub H2) approx > / cubic cm). The large abundances of carbon-chain-bearing species observed in the envelopes of protostars such as L1527 can thus be explained without the need for warm carbon-chain chemistry. The C6H(-) anion-to-neutral ratio is found to be most sensitive to the atomic O and H abundances and the electron density. Therefore, as a core evolves, falling atomic abundances and rising electron densities are found to result in increasing anion-to-neutral ratios. Inclusion of cosmic-ray desorption of atoms in high-density models delays freeze-out, which results in a more temporally stable anion-to-neutral ratio, in better agreement with observations. Our models include reactions between oxygen atoms and carbon-chain anions to produce carbon-chain-oxide species C6O, C7O, HC6O, and HC7O, the abundances of which depend on the assumed branching ratios for associative electron detachment

  16. GAS-GRAIN MODELS FOR INTERSTELLAR ANION CHEMISTRY

    SciTech Connect

    Cordiner, M. A.; Charnley, S. B.

    2012-04-20

    Long-chain hydrocarbon anions C{sub n}H{sup -} (n = 4, 6, 8) have recently been found to be abundant in a variety of interstellar clouds. In order to explain their large abundances in the denser (prestellar/protostellar) environments, new chemical models are constructed that include gas-grain interactions. Models including accretion of gas-phase species onto dust grains and cosmic-ray-induced desorption of atoms are able to reproduce the observed anion-to-neutral ratios, as well as the absolute abundances of anionic and neutral carbon chains, with a reasonable degree of accuracy. Due to their destructive effects, the depletion of oxygen atoms onto dust results in substantially greater polyyne and anion abundances in high-density gas (with n{sub H{sub 2}}{approx}>10{sup 5} cm{sup -3}). The large abundances of carbon-chain-bearing species observed in the envelopes of protostars such as L1527 can thus be explained without the need for warm carbon-chain chemistry. The C{sub 6}H{sup -} anion-to-neutral ratio is found to be most sensitive to the atomic O and H abundances and the electron density. Therefore, as a core evolves, falling atomic abundances and rising electron densities are found to result in increasing anion-to-neutral ratios. Inclusion of cosmic-ray desorption of atoms in high-density models delays freeze-out, which results in a more temporally stable anion-to-neutral ratio, in better agreement with observations. Our models include reactions between oxygen atoms and carbon-chain anions to produce carbon-chain-oxide species C{sub 6}O, C{sub 7}O, HC{sub 6}O, and HC{sub 7}O, the abundances of which depend on the assumed branching ratios for associative electron detachment.

  17. MODELING THE POLLUTION OF PRISTINE GAS IN THE EARLY UNIVERSE

    SciTech Connect

    Pan, Liubin; Scannapieco, Evan; Scalo, Jon E-mail: evan.scannapieco@asu.edu

    2013-10-01

    We conduct a comprehensive theoretical and numerical investigation of the pollution of pristine gas in turbulent flows, designed to provide useful new tools for modeling the evolution of the first generation of stars. The properties of such Population III (Pop III) stars are thought to be very different than those of later stellar generations, because cooling is dramatically different in gas with a metallicity below a critical value Z{sub c}, which lies between ∼10{sup –6} and ∼10{sup –3} Z{sub ☉}. The critical value is much smaller than the typical overall average metallicity, , and therefore the mixing efficiency of the pristine gas in the interstellar medium plays a crucial role in determining the transition from Pop III to normal star formation. The small critical value, Z{sub c}, corresponds to the far left tail of the probability distribution function (PDF) of the metal abundance. Based on closure models for the PDF formulation of turbulent mixing, we derive evolution equations for the fraction of gas, P, lying below Z{sub c}, in statistically homogeneous compressible turbulence. Our simulation data show that the evolution of the pristine fraction P can be well approximated by a generalized 'self-convolution' model, which predicts that P-dot = - (n/τ{sub con}) P (1-P{sup 1/n}), where n is a measure of the locality of the mixing or PDF convolution events and the convolution timescale τ{sub con} is determined by the rate at which turbulence stretches the pollutants. Carrying out a suite of numerical simulations with turbulent Mach numbers ranging from M = 0.9 to 6.2, we are able to provide accurate fits to n and τ{sub con} as a function of M, Z{sub c}/(Z), and the length scale, L{sub p}, at which pollutants are added to the flow. For pristine fractions above P = 0.9, mixing occurs only in the regions surrounding blobs of pollutants, such that n = 1. For smaller values of P, n is larger as the mixing process becomes more global. We show how

  18. Enantiomeric phase separation in a lattice gas model: Guggenheim approximation

    NASA Astrophysics Data System (ADS)

    Huckaby, Dale A.; Shinmi, Masato; Ausloos, Marcel; Clippe, Paulette

    1986-05-01

    We consider a lattice gas in which the two enantiomeric forms of a tetrahedral molecule, consisting of a central carbon atom bonded to four different groups A, B, G, and H, are adsorbed onto a triangular lattice, such that the carbon atom is above a lattice site, the three bonds to A, B, and G point toward neighboring lattice sites, and the bond to H points perpendicular to and away from the plane of the lattice. For a certain choice of intermolecular interactions, such as may exist between the zwitterion forms of an amino acid, the phase diagram was investigated using a Guggenheim approximation with two order parameters. Enantiomeric phase separation into two symmetric condensed phases occurs at low temperatures. These condensed phases become a single racemic condensed phase at a critical line, and they are in equilibrium with a racemic gas phase along a line of triple points. These two lines coincide at a critical endpoint. The racemic condensed and gas phases are in equilibrium along a two phase coexistence line which begins at the critical endpoint and ends at a critical point. No tricritical point was found in the model for the special choice of interactions studied.

  19. Gas transport model for chemical vapor infiltration. Topical report

    SciTech Connect

    Starr, T.L.

    1995-05-01

    A node-bond percolation model is presented for the gas permeability and pore surface area of the coarse porosity in woven fiber structures during densification by chemical vapor infiltration (CVI). Model parameters include the number of nodes per unit volume and their spatial distribution, and the node and bond radii and their variability. These parameters relate directly to structural features of the weave. Some uncertainty exists in the proper partition of the porosity between {open_quotes}node{close_quotes} and{open_quote}bond{close_quotes} and between intra-tow and inter-tow, although the total is constrained by the known fiber loading in the structure. Applied to cloth layup preforms the model gives good agreement with the limited number of available measurements.

  20. Jet fire consequence modeling for high-pressure gas pipelines

    NASA Astrophysics Data System (ADS)

    Coccorullo, Ivano; Russo, Paola

    2016-12-01

    A simple and reliable approach for sizing the hazard area potentially affected by a jet fire as consequence of the failure of high-pressure pipeline is proposed. A release rate model, taking pipeline operation properties and source release properties into account, is coupled with SLAB dispersion model and point source radiation model to calculate the hazard distance. The hazard distance is set beyond the distance at which a low chance of fatality can occur to people exposed and a wooden structure is not expected to burn due to radiation heat of jet fire. The comparison between three gases with different physico-chemical properties (i.e. natural gas, hydrogen, ethylene) is shown. The influence of pipeline operating parameters, such as: pressure, pipeline diameter and length, hole size, on the hazard area for the three gases is evaluated. Finally, a simple correlation is proposed for calculating the hazard distance as function of these parameters.

  1. Mathematical model of gas plasma applied to chronic wounds

    NASA Astrophysics Data System (ADS)

    Wang, J. G.; Liu, X. Y.; Liu, D. W.; Lu, X. P.; Zhang, Y. T.

    2013-11-01

    Chronic wounds are a major burden for worldwide health care systems, and patients suffer pain and discomfort from this type of wound. Recently gas plasmas have been shown to safely speed chronic wounds healing. In this paper, we develop a deterministic mathematical model formulated by eight-species reaction-diffusion equations, and use it to analyze the plasma treatment process. The model follows spatial and temporal concentration within the wound of oxygen, chemoattractants, capillary sprouts, blood vessels, fibroblasts, extracellular matrix material, nitric oxide (NO), and inflammatory cell. Two effects of plasma, increasing NO concentration and reducing bacteria load, are considered in this model. The plasma treatment decreases the complete healing time from 25 days (normal wound healing) to 17 days, and the contributions of increasing NO concentration and reducing bacteria load are about 1/4 and 3/4, respectively. Increasing plasma treatment frequency from twice to three times per day accelerates healing process. Finally, the response of chronic wounds of different etiologies to treatment with gas plasmas is analyzed.

  2. Mathematical model of gas plasma applied to chronic wounds

    SciTech Connect

    Wang, J. G.; Liu, X. Y.; Liu, D. W.; Lu, X. P.; Zhang, Y. T.

    2013-11-15

    Chronic wounds are a major burden for worldwide health care systems, and patients suffer pain and discomfort from this type of wound. Recently gas plasmas have been shown to safely speed chronic wounds healing. In this paper, we develop a deterministic mathematical model formulated by eight-species reaction-diffusion equations, and use it to analyze the plasma treatment process. The model follows spatial and temporal concentration within the wound of oxygen, chemoattractants, capillary sprouts, blood vessels, fibroblasts, extracellular matrix material, nitric oxide (NO), and inflammatory cell. Two effects of plasma, increasing NO concentration and reducing bacteria load, are considered in this model. The plasma treatment decreases the complete healing time from 25 days (normal wound healing) to 17 days, and the contributions of increasing NO concentration and reducing bacteria load are about 1/4 and 3/4, respectively. Increasing plasma treatment frequency from twice to three times per day accelerates healing process. Finally, the response of chronic wounds of different etiologies to treatment with gas plasmas is analyzed.

  3. Modeling of Linear Gas Tungsten Arc Welding of Stainless Steel

    NASA Astrophysics Data System (ADS)

    Maran, P.; Sornakumar, T.; Sundararajan, T.

    2008-08-01

    A heat and fluid flow model has been developed to solve the gas tungsten arc (GTA) linear welding problem for austenitic stainless steel. The moving heat source problem associated with the electrode traverse has been simplified into an equivalent two-dimensional (2-D) transient problem. The torch residence time has been calculated from the arc diameter and torch speed. The mathematical formulation considers buoyancy, electromagnetic induction, and surface tension forces. The governing equations have been solved by the finite volume method. The temperature and velocity fields have been determined. The theoretical predictions for weld bead geometry are in good agreement with experimental measurements.

  4. Anelastic models of the zonal winds in gas giants

    NASA Astrophysics Data System (ADS)

    Gastine, T.; Wicht, J.

    2012-12-01

    The banded structures observed at the surfaces of Jupiter and Saturn are associated with eastward and westward zonal flows. In both gas giants, we observe a large amplitude prograde equatorial jet, which is flanked by multiple alternating zonal winds of weaker amplitudes. The depth of these jets is however poorly known and highly debated. Theoretical scenarios encompass "shallow models", that assume that these zonal flows are restricted to the outer weather layer; as well as "deep models" that suppose that the jets penetrate deeper down in the molecular envelope. The latter idea has been supported by 3-D numerical simulations using the so-called "Boussinesq approximation", that assumes the reference state to be constant with radius (e.g. Heimpel et al., 2005). While this approximation is well-adapted to weakly-stratified fluids (e.g. iron cores of Earth-like planets), it becomes more questionable in the gas giants interiors, where the density contrast is huge (ρ bot/ρ top ˜ 104). The "anelastic approximation", already employed in recent models of the gas giants (e.g. Jones & Kuzanyan 2009; Gastine & Wicht 2012), thus provides a more realistic framework to simulate the interior dynamics of such planets. We present here the results of a systematic parameter study where we explore the dependence of convection and zonal flows on density stratification. While the density contrast affects the convective flow amplitude and the typical lengthscale of convection, global quantities and zonal jets properties are found to be fairly independent of the density contrast. Notwithstanding these common properties, compressibility effects also yield interesting differences to Boussinesq approaches. For instance, in the strongly stratified models, the main force balance can significantly vary with depth. While the flow in the deep interior is dominated by rotation, buoyancy can indeed become larger than Coriolis force close to the surface. This "transitional regime" has a visible

  5. Study on Turbulent Modeling in Gas Entrainment Evaluation Method

    NASA Astrophysics Data System (ADS)

    Ito, Kei; Ohshima, Hiroyuki; Nakamine, Yoshiaki; Imai, Yasutomo

    Suppression of gas entrainment (GE) phenomena caused by free surface vortices are very important to establish an economically superior design of the sodium-cooled fast reactor in Japan (JSFR). However, due to the non-linearity and/or locality of the GE phenomena, it is not easy to evaluate the occurrences of the GE phenomena accurately. In other words, the onset condition of the GE phenomena in the JSFR is not predicted easily based on scaled-model and/or partial-model experiments. Therefore, the authors are developing a CFD-based evaluation method in which the non-linearity and locality of the GE phenomena can be considered. In the evaluation method, macroscopic vortex parameters, e.g. circulation, are determined by three-dimensional CFD and then, GE-related parameters, e.g. gas core (GC) length, are calculated by using the Burgers vortex model. This procedure is efficient to evaluate the GE phenomena in the JSFR. However, it is well known that the Burgers vortex model tends to overestimate the GC length due to the lack of considerations on some physical mechanisms. Therefore, in this study, the authors develop a turbulent vortex model to evaluate the GE phenomena more accurately. Then, the improved GE evaluation method with the turbulent viscosity model is validated by analyzing the GC lengths observed in a simple experiment. The evaluation results show that the GC lengths analyzed by the improved method are shorter in comparison to the original method, and give better agreement with the experimental data.

  6. Parameters of cosmological models and recent astronomical observations

    SciTech Connect

    Sharov, G.S.; Vorontsova, E.G. E-mail: elenavor@inbox.ru

    2014-10-01

    For different gravitational models we consider limitations on their parameters coming from recent observational data for type Ia supernovae, baryon acoustic oscillations, and from 34 data points for the Hubble parameter H(z) depending on redshift. We calculate parameters of 3 models describing accelerated expansion of the universe: the ΛCDM model, the model with generalized Chaplygin gas (GCG) and the multidimensional model of I. Pahwa, D. Choudhury and T.R. Seshadri. In particular, for the ΛCDM model 1σ estimates of parameters are: H{sub 0}=70.262±0.319 km {sup -1}Mp {sup -1}, Ω{sub m}=0.276{sub -0.008}{sup +0.009}, Ω{sub Λ}=0.769±0.029, Ω{sub k}=-0.045±0.032. The GCG model under restriction 0α≥ is reduced to the ΛCDM model. Predictions of the multidimensional model essentially depend on 3 data points for H(z) with z≥2.3.

  7. Parameters of cosmological models and recent astronomical observations

    NASA Astrophysics Data System (ADS)

    Sharov, G. S.; Vorontsova, E. G.

    2014-10-01

    For different gravitational models we consider limitations on their parameters coming from recent observational data for type Ia supernovae, baryon acoustic oscillations, and from 34 data points for the Hubble parameter H(z) depending on redshift. We calculate parameters of 3 models describing accelerated expansion of the universe: the ΛCDM model, the model with generalized Chaplygin gas (GCG) and the multidimensional model of I. Pahwa, D. Choudhury and T.R. Seshadri. In particular, for the ΛCDM model 1σ estimates of parameters are: H0=70.262±0.319 km -1Mp -1, Ωm=0.276-0.008+0.009, ΩΛ=0.769±0.029, Ωk=-0.045±0.032. The GCG model under restriction 0α>= is reduced to the ΛCDM model. Predictions of the multidimensional model essentially depend on 3 data points for H(z) with z>=2.3.

  8. An electricity price model with consideration to load and gas price effects.

    PubMed

    Huang, Min-xiang; Tao, Xiao-hu; Han, Zhen-xiang

    2003-01-01

    Some characteristics of the electricity load and prices are studied, and the relationship between electricity prices and gas (fuel) prices is analyzed in this paper. Because electricity prices are strongly dependent on load and gas prices, the authors constructed a model for electricity prices based on the effects of these two factors; and used the Geometric Mean Reversion Brownian Motion (GMRBM) model to describe the electricity load process, and a Geometric Brownian Motion(GBM) model to describe the gas prices; deduced the price stochastic process model based on the above load model and gas price model. This paper also presents methods for parameters estimation, and proposes some methods to solve the model.

  9. Modeling heating curve for gas hydrate dissociation in porous media.

    PubMed

    Dicharry, Christophe; Gayet, Pascal; Marion, Gérard; Graciaa, Alain; Nesterov, Anatoliy N

    2005-09-15

    A method for modeling the heating curve for gas hydrate dissociation in porous media at isochoric conditions (constant cell volume) is presented. This method consists of using an equation of state of the gas, the cumulative volume distribution (CVD) of the porous medium, and a van der Waals-Platteeuw-type thermodynamic model that includes a capillary term. The proposed method was tested to predict the heating curves for methane hydrate dissociation in a mesoporous silica glass for saturated conditions (liquid volume = pore volume) and for a fractional conversion of water to hydrate of 1 (100% of the available water was converted to hydrate). The shape factor (F) of the hydrate-water interface was found equal to 1, supporting a cylindrical shape for the hydrate particles during hydrate dissociation. Using F = 1, it has been possible to predict the heating curve for different ranges of pressure and temperature. The excellent agreement between the calculated and experimental heating curves supports the validity of our approach.

  10. Dynamic-structure-factor measurements on a model Lorentz gas

    NASA Astrophysics Data System (ADS)

    Egelstaff, P. A.; Eder, O. J.; Glaser, W.; Polo, J.; Renker, B.; Soper, A. K.

    1990-02-01

    A model system for the Lorentz gas can be made [Eder, Chen, and Egelstaff, Proc. Phys. Soc. London 89, 833 (1966); McPherson and Egelstaff, Can. J. Phys. 58, 289 (1980)] by mixing small quantities of hydrogen with an argon host. For neutron-scattering experiments the large H-to-Ar cross section ratio (~200) makes the argon relatively invisible. Dynamic-structure-factor [S(Q,ω) for H2] measurements at room temperature have been made on this system using the IN4 spectrometer at the Institute Laue Langevin, Grenoble, France. Argon densities between 1.9 and 10.5 atoms/nm3 were used for 0.4gas host at densities of 4 and 10.5 atoms/nm3; helium is relatively invisible also compared to hydrogen. These experiments are described, and some examples of the results are presented to show the qualitative effects observed. The principle observation is a pronounced narrowing of S(Q,ω) as a function of ω as the argon density is increased. This effect is large at low Q and decreases with increasing Q, and also decreases substantially when helium is used in place of argon. In addition, the shape of S(Q,ω) is more complex than can be accommodated within a simple model, but slightly less complicated than a computer simulation so showing the significance of multiple-collision processes.

  11. Dynamic lattice-gas model of underpotential deposition

    NASA Astrophysics Data System (ADS)

    Brown, Gregory; Rikvold, Per Arne; Novotny, M. A.; Wieckowski, Andrzej

    1998-03-01

    Underpotential deposition (UPD) is the process by which a monolayer or less of one metal is adsorbed onto the surface of another at electrode potentials more positive than those at which bulk deposition occurs. For particular combinations of metals, lattice-gas models have been formulated and studied using both analytical and numerical techniques. Dynamic Monte Carlo simulations of a lattice-gas model of UPD of copper onto Au(111) in the presence of sulfuric acid are presented. The simulations include adsorption, desorption, and lateral diffusion and span timescales from 10-9 to 10^1 s. The results reproduce the strong asymmetry seen in experimental current profiles that occur after a sudden potential change.(M. H. Hölzle, et al.), J. Electroanal. Chem. \\underbar371, 101 (1994). The simulation technique can also be used to understand features in cyclic-voltammetry profiles, where the applied potential is changed continuously.

  12. Nahoon: Time-dependent gas-phase chemical model

    NASA Astrophysics Data System (ADS)

    Wakelam, V.

    2014-09-01

    Nahoon is a gas-phase chemical model that computes the chemical evolution in a 1D temperature and density structure. It uses chemical networks downloaded from the KInetic Database for Astrochemistry (KIDA) but the model can be adapted to any network. The program is written in Fortran 90 and uses the DLSODES (double precision) solver from the ODEPACK package to solve the coupled stiff differential equations. The solver computes the chemical evolution of gas-phase species at a fixed temperature and density and can be used in one dimension (1D) if a grid of temperature, density, and visual extinction is provided. Grains, both neutral and negatively charged, and electrons are considered as chemical species and their concentrations are computed at the same time as those of the other species. Nahoon contains a test to check the temperature range of the validity of the rate coefficients and avoid extrapolations outside this range. A test is also included to check for duplication of chemical reactions, defined over complementary ranges of temperature.

  13. Monitoring temperature for gas turbine blade: correction of reflection model

    NASA Astrophysics Data System (ADS)

    Gao, Shan; Wang, Lixin; Feng, Chi; Xiao, Yihan; Daniel, Ketui

    2015-06-01

    For a gas turbine blade working in a narrow space, the accuracy of blade temperature measurements is greatly impacted by environmental irradiation. A reflection model is established by using discrete irregular surfaces to calculate the angle factor between the blade surface and the hot adjacent parts. The model is based on the rotational angles and positions of the blades, and can correct for measurement error caused by background radiation when the blade is located at different rotational positions. This method reduces the impact of reflected radiation on the basis of the turbine's known geometry and the physical properties of the material. The experimental results show that when the blade temperature is 911.2±5 K and the vane temperature ranges from 1011.3 to 1065.8 K, the error decreases from 4.21 to 0.75%.

  14. Modeling of flowing gas diode pumped alkali lasers: dependence of the operation on the gas velocity and on the nature of the buffer gas.

    PubMed

    Barmashenko, B D; Rosenwaks, S

    2012-09-01

    A simple, semi-analytical model of flowing gas diode pumped alkali lasers (DPALs) is presented. The model takes into account the rise of temperature in the lasing medium with increasing pump power, resulting in decreasing pump absorption and slope efficiency. The model predicts the dependence of power on the flow velocity in flowing gas DPALs and checks the effect of using a buffer gas with high molar heat capacity and large relaxation rate constant between the 2P3/2 and 2P1/2 fine-structure levels of the alkali atom. It is found that the power strongly increases with flow velocity and that by replacing, e.g., ethane by propane as a buffer gas the power may be further increased by up to 30%. Eight kilowatt is achievable for 20 kW pump at flow velocity of 20  m/s.

  15. Greenhouse Gas Emissions Model (GEM) for Medium- and Heavy-Duty Vehicle Compliance

    EPA Pesticide Factsheets

    EPA’s Greenhouse Gas Emissions Model (GEM) is a free, desktop computer application that estimates the greenhouse gas (GHG) emissions and fuel efficiency performance of specific aspects of heavy-duty vehicles.

  16. Natural gas transmission and distribution model of the National Energy Modeling System

    SciTech Connect

    1997-02-01

    The Natural Gas Transmission and Distribution Model (NGTDM) is the component of the National Energy Modeling System (NEMS) that is used to represent the domestic natural gas transmission and distribution system. NEMS was developed in the Office of Integrated Analysis and Forecasting of the Energy Information Administration (EIA). NEMS is the third in a series of computer-based, midterm energy modeling systems used since 1974 by the EIA and its predecessor, the Federal Energy Administration, to analyze domestic energy-economy markets and develop projections. From 1982 through 1993, the Intermediate Future Forecasting System (IFFS) was used by the EIA for its analyses, and the Gas Analysis Modeling System (GAMS) was used within IFFS to represent natural gas markets. Prior to 1982, the Midterm Energy Forecasting System (MEFS), also referred to as the Project Independence Evaluation System (PIES), was employed. NEMS was developed to enhance and update EIA`s modeling capability by internally incorporating models of energy markets that had previously been analyzed off-line. In addition, greater structural detail in NEMS permits the analysis of a broader range of energy issues. The time horizon of NEMS is the midterm period (i.e., through 2015). In order to represent the regional differences in energy markets, the component models of NEMS function at regional levels appropriate for the markets represented, with subsequent aggregation/disaggregation to the Census Division level for reporting purposes.

  17. Adapting a weather forecast model for greenhouse gas simulation

    NASA Astrophysics Data System (ADS)

    Polavarapu, S. M.; Neish, M.; Tanguay, M.; Girard, C.; de Grandpré, J.; Gravel, S.; Semeniuk, K.; Chan, D.

    2015-12-01

    The ability to simulate greenhouse gases on the global domain is useful for providing boundary conditions for regional flux inversions, as well as for providing reference data for bias correction of satellite measurements. Given the existence of operational weather and environmental prediction models and assimilation systems at Environment Canada, it makes sense to use these tools for greenhouse gas simulations. In this work, we describe the adaptations needed to reasonably simulate CO2 with a weather forecast model. The main challenges were the implementation of a mass conserving advection scheme, and the careful implementation of a mixing ratio defined with respect to dry air. The transport of tracers through convection was also added, and the vertical mixing through the boundary layer was slightly modified. With all these changes, the model conserves CO2 mass well on the annual time scale, and the high resolution (0.9 degree grid spacing) permits a good description of synoptic scale transport. The use of a coupled meteorological/tracer transport model also permits an assessment of approximations needed in offline transport model approaches, such as the neglect of water vapour mass when computing a tracer mixing ratio with respect to dry air.

  18. Anyonic behavior of an intermediate-statistics fermion gas model.

    PubMed

    Algin, Abdullah; Irk, Dursun; Topcu, Gozde

    2015-06-01

    We study the high-temperature behavior of an intermediate-statistics fermionic gas model whose quantum statistical properties enable us to effectively deduce the details about both the interaction among deformed (quasi)particles and their anyonic behavior. Starting with a deformed fermionic grand partition function, we calculate, in the thermodynamical limit, several thermostatistical functions of the model such as the internal energy and the entropy by means of a formalism of the fermionic q calculus. For high temperatures, a virial expansion of the equation of state for the system is obtained in two and three dimensions and the first five virial coefficients are derived in terms of the model deformation parameter q. From the results obtained by the effect of fermionic deformation, it is found that the model parameter q interpolates completely between bosonlike and fermionic systems via the behaviors of the third and fifth virial coefficients in both two and three spatial dimensions and in addition it characterizes effectively the interaction among quasifermions. Our results reveal that the present deformed (quasi)fermion model could be very efficient and effective in accounting for the nonlinear behaviors in interacting composite particle systems.

  19. A paradigm for modeling and computation of gas dynamics

    NASA Astrophysics Data System (ADS)

    Xu, Kun; Liu, Chang

    2017-02-01

    In the continuum flow regime, the Navier-Stokes (NS) equations are usually used for the description of gas dynamics. On the other hand, the Boltzmann equation is applied for the rarefied flow. These two equations are based on distinguishable modeling scales for flow physics. Fortunately, due to the scale separation, i.e., the hydrodynamic and kinetic ones, both the Navier-Stokes equations and the Boltzmann equation are applicable in their respective domains. However, in real science and engineering applications, they may not have such a distinctive scale separation. For example, around a hypersonic flying vehicle, the flow physics at different regions may correspond to different regimes, where the local Knudsen number can be changed significantly in several orders of magnitude. With a variation of flow physics, theoretically a continuous governing equation from the kinetic Boltzmann modeling to the hydrodynamic Navier-Stokes dynamics should be used for its efficient description. However, due to the difficulties of a direct modeling of flow physics in the scale between the kinetic and hydrodynamic ones, there is basically no reliable theory or valid governing equations to cover the whole transition regime, except resolving flow physics always down to the mean free path scale, such as the direct Boltzmann solver and the Direct Simulation Monte Carlo (DSMC) method. In fact, it is an unresolved problem about the exact scale for the validity of the NS equations, especially in the small Reynolds number cases. The computational fluid dynamics (CFD) is usually based on the numerical solution of partial differential equations (PDEs), and it targets on the recovering of the exact solution of the PDEs as mesh size and time step converging to zero. This methodology can be hardly applied to solve the multiple scale problem efficiently because there is no such a complete PDE for flow physics through a continuous variation of scales. For the non-equilibrium flow study, the direct

  20. Greenhouse Gas Source Attribution: Measurements Modeling and Uncertainty Quantification

    SciTech Connect

    Liu, Zhen; Safta, Cosmin; Sargsyan, Khachik; Najm, Habib N.; van Bloemen Waanders, Bart Gustaaf; LaFranchi, Brian W.; Ivey, Mark D.; Schrader, Paul E.; Michelsen, Hope A.; Bambha, Ray P.

    2014-09-01

    In this project we have developed atmospheric measurement capabilities and a suite of atmospheric modeling and analysis tools that are well suited for verifying emissions of green- house gases (GHGs) on an urban-through-regional scale. We have for the first time applied the Community Multiscale Air Quality (CMAQ) model to simulate atmospheric CO2 . This will allow for the examination of regional-scale transport and distribution of CO2 along with air pollutants traditionally studied using CMAQ at relatively high spatial and temporal resolution with the goal of leveraging emissions verification efforts for both air quality and climate. We have developed a bias-enhanced Bayesian inference approach that can remedy the well-known problem of transport model errors in atmospheric CO2 inversions. We have tested the approach using data and model outputs from the TransCom3 global CO2 inversion comparison project. We have also performed two prototyping studies on inversion approaches in the generalized convection-diffusion context. One of these studies employed Polynomial Chaos Expansion to accelerate the evaluation of a regional transport model and enable efficient Markov Chain Monte Carlo sampling of the posterior for Bayesian inference. The other approach uses de- terministic inversion of a convection-diffusion-reaction system in the presence of uncertainty. These approaches should, in principle, be applicable to realistic atmospheric problems with moderate adaptation. We outline a regional greenhouse gas source inference system that integrates (1) two ap- proaches of atmospheric dispersion simulation and (2) a class of Bayesian inference and un- certainty quantification algorithms. We use two different and complementary approaches to simulate atmospheric dispersion. Specifically, we use a Eulerian chemical transport model CMAQ and a Lagrangian Particle Dispersion Model - FLEXPART-WRF. These two models share the same WRF

  1. CFD modeling of water spray interaction with dense gas plumes

    NASA Astrophysics Data System (ADS)

    Meroney, Robert N.

    2012-07-01

    Numerical calculations are performed to reproduce the transport and dispersion of the continuous release of dense gases over flat homogeneous surfaces with and without the mitigating influence of a downwind water curtain. Frequently such plumes are released as a result of a chemical manufacturing, storage or gas transportation accident resulting in a ground-level hazard due to gas flammability or toxicity. A field situation in which cold carbon dioxide was released upwind of water curtains (Moodie et al., 1981) was simulated using the open-source software FDS (Fire Dynamic Simulator) a full 3-d CFD model. Only water-spray enhancement of dispersion was considered; hence, no chemical removal or reactions were present or simulated. Wind-tunnel measurements for a 1:28.9 scale replication of the Moodie experiments are also compared with the 3-d CFD results. Concentration distributions, percent dilution and forced diffusion parameters were compared in scatter diagrams. Concentration field contours with and without active spray curtains are also presented.

  2. CONSTRAINING INTRACLUSTER GAS MODELS WITH AMiBA13

    SciTech Connect

    Molnar, Sandor M.; Umetsu, Keiichi; Ho, Paul T. P.; Koch, Patrick M.; Victor Liao, Yu-Wei; Lin, Kai-Yang; Liu, Guo-Chin; Nishioka, Hiroaki; Birkinshaw, Mark; Bryan, Greg; Haiman, Zoltan; Shang, Cien; Hearn, Nathan

    2010-11-10

    Clusters of galaxies have been extensively used to determine cosmological parameters. A major difficulty in making the best use of Sunyaev-Zel'dovich (SZ) and X-ray observations of clusters for cosmology is that using X-ray observations it is difficult to measure the temperature distribution and therefore determine the density distribution in individual clusters of galaxies out to the virial radius. Observations with the new generation of SZ instruments are a promising alternative approach. We use clusters of galaxies drawn from high-resolution adaptive mesh refinement cosmological simulations to study how well we should be able to constrain the large-scale distribution of the intracluster gas (ICG) in individual massive relaxed clusters using AMiBA in its configuration with 13 1.2 m diameter dishes (AMiBA13) along with X-ray observations. We show that non-isothermal {beta} models provide a good description of the ICG in our simulated relaxed clusters. We use simulated X-ray observations to estimate the quality of constraints on the distribution of gas density, and simulated SZ visibilities (AMiBA13 observations) for constraints on the large-scale temperature distribution of the ICG. We find that AMiBA13 visibilities should constrain the scale radius of the temperature distribution to about 50% accuracy. We conclude that the upgraded AMiBA, AMiBA13, should be a powerful instrument to constrain the large-scale distribution of the ICG.

  3. Modeling of Gas Production from Shale Reservoirs Considering Multiple Transport Mechanisms.

    PubMed

    Guo, Chaohua; Wei, Mingzhen; Liu, Hong

    2015-01-01

    Gas transport in unconventional shale strata is a multi-mechanism-coupling process that is different from the process observed in conventional reservoirs. In micro fractures which are inborn or induced by hydraulic stimulation, viscous flow dominates. And gas surface diffusion and gas desorption should be further considered in organic nano pores. Also, the Klinkenberg effect should be considered when dealing with the gas transport problem. In addition, following two factors can play significant roles under certain circumstances but have not received enough attention in previous models. During pressure depletion, gas viscosity will change with Knudsen number; and pore radius will increase when the adsorption gas desorbs from the pore wall. In this paper, a comprehensive mathematical model that incorporates all known mechanisms for simulating gas flow in shale strata is presented. The objective of this study was to provide a more accurate reservoir model for simulation based on the flow mechanisms in the pore scale and formation geometry. Complex mechanisms, including viscous flow, Knudsen diffusion, slip flow, and desorption, are optionally integrated into different continua in the model. Sensitivity analysis was conducted to evaluate the effect of different mechanisms on the gas production. The results showed that adsorption and gas viscosity change will have a great impact on gas production. Ignoring one of following scenarios, such as adsorption, gas permeability change, gas viscosity change, or pore radius change, will underestimate gas production.

  4. Modeling of Gas Production from Shale Reservoirs Considering Multiple Transport Mechanisms

    PubMed Central

    Guo, Chaohua; Wei, Mingzhen; Liu, Hong

    2015-01-01

    Gas transport in unconventional shale strata is a multi-mechanism-coupling process that is different from the process observed in conventional reservoirs. In micro fractures which are inborn or induced by hydraulic stimulation, viscous flow dominates. And gas surface diffusion and gas desorption should be further considered in organic nano pores. Also, the Klinkenberg effect should be considered when dealing with the gas transport problem. In addition, following two factors can play significant roles under certain circumstances but have not received enough attention in previous models. During pressure depletion, gas viscosity will change with Knudsen number; and pore radius will increase when the adsorption gas desorbs from the pore wall. In this paper, a comprehensive mathematical model that incorporates all known mechanisms for simulating gas flow in shale strata is presented. The objective of this study was to provide a more accurate reservoir model for simulation based on the flow mechanisms in the pore scale and formation geometry. Complex mechanisms, including viscous flow, Knudsen diffusion, slip flow, and desorption, are optionally integrated into different continua in the model. Sensitivity analysis was conducted to evaluate the effect of different mechanisms on the gas production. The results showed that adsorption and gas viscosity change will have a great impact on gas production. Ignoring one of following scenarios, such as adsorption, gas permeability change, gas viscosity change, or pore radius change, will underestimate gas production. PMID:26657698

  5. Gas Phase Model of Surface Reactions for N{2} Afterglows

    NASA Astrophysics Data System (ADS)

    Marković, V. Lj.; Petrović, Z. Lj.; Pejović, M. M.

    1996-07-01

    The adequacy of the homogeneous gas phase model as a representation of the surface losses of diffusing active particles in gas phase is studied. As an example the recent data obtained for the surface recombination coefficients are reanalyzed. The data were obtained by the application of the breakdown delay times which consists of the measurements of the breakdown delay times t_d as a function of the afterglow period tau. It was found that for the conditions of our experiment, the diffusion should not be neglected as the final results are significantly different when obtained by approximate gas phase representation and by exact numerical solution to the diffusion equation. While application of the gas phase effective coefficients to represent surface losses gives an error in the value of the recombination coefficient, it reproduces correctly other characteristics such as order of the process which can be obtained from simple fits to the experimental data. Dans cet article, nous étudions la validité du modèle approximatif représentant les pertes superficielles des particules actives qui diffusent de la phase gazeuse comme pertes dans la phase homogène du gaz. Les données actuelles du coefficient de recombination en surface sont utilisées par cette vérification . Les données experimentales sont obtenues en utilisant la technique qui consiste en la mesure du temps de retard du début de la décharge en fonction de la période de relaxation. Nous avons trouvé que, pour nos conditions expérimentales, la diffusion ne peut être négligée. Aussi, les résultats finals sont considérablement différents quand ils sont obtenus en utilisant le modèle approximatif par comparaison aves les résultats obtenus par la solution numérique exacte de l'équation de la diffusion. L'application des coefficients effectifs dans la phase gaseuse pour la présentation des pertes superficielles donne, pour les coefficients de la recombinaison, des valeurs qui diffèrent en

  6. Ammonia concentration modeling based on retained gas sampler data

    SciTech Connect

    Terrones, G.; Palmer, B.J.; Cuta, J.M.

    1997-09-01

    The vertical ammonia concentration distributions determined by the retained gas sampler (RGS) apparatus were modeled for double-shell tanks (DSTs) AW-101, AN-103, AN-104, and AN-105 and single-shell tanks (SSTs) A-101, S-106, and U-103. One the vertical transport of ammonia in the tanks were used for the modeling. Transport in the non-convective settled solids and floating solids layers is assumed to occur primarily via some type of diffusion process, while transport in the convective liquid layers is incorporated into the model via mass transfer coefficients based on empirical correlations. Mass transfer between the top of the waste and the tank headspace and the effects of ventilation of the headspace are also included in the models. The resulting models contain a large number of parameters, but many of them can be determined from known properties of the waste configuration or can be estimated within reasonable bounds from data on the waste samples themselves. The models are used to extract effective diffusion coefficients for transport in the nonconvective layers based on the measured values of ammonia from the RGS apparatus. The modeling indicates that the higher concentrations of ammonia seen in bubbles trapped inside the waste relative to the ammonia concentrations in the tank headspace can be explained by a combination of slow transport of ammonia via diffusion in the nonconvective layers and ventilation of the tank headspace by either passive or active means. Slow transport by diffusion causes a higher concentration of ammonia to build up deep within the waste until the concentration gradients between the interior and top of the waste are sufficient to allow ammonia to escape at the same rate at which it is being generated in the waste.

  7. Modelling of Spherical Gas Bubble Oscillations and Sonoluminescence

    NASA Technical Reports Server (NTRS)

    Prosperetti, A.; Hao, Y.

    1999-01-01

    The discovery of single-bubble sonoluminescence has led to a renewed interest in the forced radial oscillations of gas bubbles. Many of the more recent studies devoted to this topic have used several simplifications in the modelling, and in particular in accounting for liquid compressibility and thermal processes in the bubble. In this paper the significance of these simplifications is explored by contrasting the results of Lohse and co-workers with those of a more detailed model. It is found that, even though there may be little apparent difference between the radius-versus time behaviour of the bubble as predicted by the two models, quantities such as the spherical stability boundary and the threshold for rectified diffusion are affected in a quantitatively significant way. These effects are a manifestation of the subtle dependence upon dissipative processes of the phase of radial motion with respect to the driving sound field. The parameter space region, where according to the theory of Lohse and co-workers, sonoluminescence should be observable, is recalculated with the new model and is found to be enlarged with respect to the earlier estimate. The dependence of this parameter region on sound frequency is also illustrated.

  8. On final motions of a Chaplygin ball on a rough plane

    NASA Astrophysics Data System (ADS)

    Ivanov, Alexander P.

    2016-12-01

    A heavy balanced nonhomogeneous ball moving on a rough horizontal plane is considered. The classical model of a "marble" body means a single point of contact, where sliding is impossible. We suggest that the contact forces be described by Coulomb's law and show that in the final motion there is no sliding. Another, relatively new, contact model is the "rubber" ball: there is no sliding and no spinning. We treat this situation by applying a local Coulomb law within a small contact area. It is proved that the final motion of a ball with such friction is the motion of the "rubber" ball.

  9. Modeling of information flows in natural gas storage facility

    NASA Astrophysics Data System (ADS)

    Ranjbari, Leyla; Bahar, Arifah; Aziz, Zainal Abdul

    2013-09-01

    The paper considers the natural-gas storage valuation based on the information-based pricing framework of Brody-Hughston-Macrina (BHM). As opposed to many studies which the associated filtration is considered pre-specified, this work tries to construct the filtration in terms of the information provided to the market. The value of the storage is given by the sum of the discounted expectations of the cash flows under risk-neutral measure, conditional to the constructed filtration with the Brownian bridge noise term. In order to model the flow of information about the cash flows, we assume the existence of a fixed pricing kernel with liquid, homogenous and incomplete market without arbitrage.

  10. Inhomogeneous imperfect fluid inflation

    NASA Astrophysics Data System (ADS)

    Elizalde, E.; Silva, Luis G. T.

    2017-01-01

    A generalized equation of state corresponding to a model that includes a Chaplygin gas and a viscous term is investigated, in the context of the reconstruction program in scalar field cosmology. The corresponding inflationary model parameters can be conveniently adjusted in order to reproduce the most recent PLANCK data. The influence of the Chaplygin gas term contribution, in relation with previous models, is discussed. Exit from inflation is shown to occur quite naturally in the new model.

  11. Monte Carlo model for electron degradation in xenon gas

    PubMed Central

    Bhardwaj, Anil

    2016-01-01

    We have developed a Monte Carlo model for studying the local degradation of electrons in the energy range 9–10 000 eV in xenon gas. Analytically fitted form of electron impact cross sections for elastic and various inelastic processes are fed as input data to the model. The two-dimensional numerical yield spectrum (NYS), which gives information on the number of energy loss events occurring in a particular energy interval, is obtained as the output of the model. The NYS is fitted analytically, thus obtaining the analytical yield spectrum (AYS). The AYS can be used to calculate electron fluxes, which can be further employed for the calculation of volume production rates. Using the yield spectrum, mean energy per ion pair and efficiencies of inelastic processes are calculated. The value for mean energy per ion pair for Xe is 22 eV at 10 keV. Ionization dominates for incident energies greater than 50 eV and is found to have an efficiency of approximately 65% at 10 keV. The efficiency for the excitation process is approximately 30% at 10 keV. PMID:27118913

  12. Origin of marine sour natural gas and gas-filling model for the Wolonghe Gas Field, Sichuan Basin, China

    NASA Astrophysics Data System (ADS)

    Liu, Quanyou; Jin, Zhijun; Li, Jian; Hu, Anping; Bi, Changchun

    2012-09-01

    The chemical and isotopic composition of natural gases from the Wolonghe Gas Field, Sichuan Basin, Southwest China, was investigated to assess the potential gas sources and reconstruct the gas-filling history of the reservoirs. All natural gases in this field are dominated by gaseous hydrocarbons (C1-C3) with varied amounts of non-hydrocarbon components (CO2, H2S and N2). The H2S content varies with reservoir intervals. It ranges from zero to 1.84% with an average of 0.37% in the Carboniferous reservoir, from 0.05% to 0.76% with an average of 0.30% in the Permian reservoir, and from 1.09% to 18.83% with an average of 5.39% in the Lower Triassic reservoir. The gas dryness coefficient (C1/C1-3) ranges from 0.97 to 1.0 with an average of 0.99. The carbon isotopic compositions of methane and its homologues in the Wolonghe Gas Field vary widely, with δ13C1 ⩾ δ13C2 < δ13C3 in the Carboniferous and Permian gas reservoirs, and δ13C1 < δ13C2 < δ13C3 in the Lower Triassic Jialingjiang Formation gas reservoirs. The δD1 values range from -140‰ to -100‰, with an average of -124.5‰. The δ34SH2S values in the field extend from 5.7‰ to 31.0‰, with δ34SH2S values in the Lower Triassic Jialingjiang Formation reservoirs being much higher than those in the Carboniferous and Permian reservoirs. The sour natural gases in the field originated from cracking of oil and were sourced from the marine sapropelic organic matter at high maturity levels. The natural gases underwent alteration by thermochemical sulfate reduction (TSR). Although the limited extent TSR occurred in the Carboniferous and Permian gas reservoirs, the TSR alteration is likely to have caused the high gas dryness and the 13C enrichment of CH4. The present low content of H2S in the Carboniferous and Permian gases would be related to the loss of H2S dissolved in water under the reconstruction of these gas reservoirs. In contrast, the high H2S in the Jialingjiang Formation gases is determined by both the

  13. Formation of natural gas hydrates in marine sediments 1. Conceptual model of gas hydrate growth conditioned by host sediment properties

    USGS Publications Warehouse

    Clennell, M.B.; Hovland, M.; Booth, J.S.; Henry, P.; Winters, W.J.

    1999-01-01

    The stability of submarine gas hydrates is largely dictated by pressure and temperature, gas composition, and pore water salinity. However, the physical properties and surface chemistry of deep marine sediments may also affect the thermodynamic state, growth kinetics, spatial distributions, and growth forms of clathrates. Our conceptual model presumes that gas hydrate behaves in a way analogous to ice in a freezing soil. Hydrate growth is inhibited within fine-grained sediments by a combination of reduced pore water activity in the vicinity of hydrophilic mineral surfaces, and the excess internal energy of small crystals confined in pores. The excess energy can be thought of as a "capillary pressure" in the hydrate crystal, related to the pore size distribution and the state of stress in the sediment framework. The base of gas hydrate stability in a sequence of fine sediments is predicted by our model to occur at a lower temperature (nearer to the seabed) than would be calculated from bulk thermodynamic equilibrium. Capillary effects or a build up of salt in the system can expand the phase boundary between hydrate and free gas into a divariant field extending over a finite depth range dictated by total methane content and pore-size distribution. Hysteresis between the temperatures of crystallization and dissociation of the clathrate is also predicted. Growth forms commonly observed in hydrate samples recovered from marine sediments (nodules, and lenses in muds; cements in sands) can largely be explained by capillary effects, but kinetics of nucleation and growth are also important. The formation of concentrated gas hydrates in a partially closed system with respect to material transport, or where gas can flush through the system, may lead to water depletion in the host sediment. This "freeze-drying" may be detectable through physical changes to the sediment (low water content and overconsolidation) and/or chemical anomalies in the pore waters and metastable

  14. Formation mechanism of gas bubble superlattice in UMo metal fuels: Phase-field modeling investigation

    NASA Astrophysics Data System (ADS)

    Hu, Shenyang; Burkes, Douglas E.; Lavender, Curt A.; Senor, David J.; Setyawan, Wahyu; Xu, Zhijie

    2016-10-01

    Nano-gas bubble superlattices are often observed in irradiated UMo nuclear fuels. However, the formation mechanism of gas bubble superlattices is not well understood. A number of physical processes may affect the gas bubble nucleation and growth; hence, the morphology of gas bubble microstructures including size and spatial distributions. In this work, a phase-field model integrating a first-passage Monte Carlo method to investigate the formation mechanism of gas bubble superlattices was developed. Six physical processes are taken into account in the model: 1) heterogeneous generation of gas atoms, vacancies, and interstitials informed from atomistic simulations; 2) one-dimensional (1-D) migration of interstitials; 3) irradiation-induced dissolution of gas atoms; 4) recombination between vacancies and interstitials; 5) elastic interaction; and 6) heterogeneous nucleation of gas bubbles. We found that the elastic interaction doesn't cause the gas bubble alignment, and fast 1-D migration of interstitials along <110> directions in the body-centered cubic U matrix causes the gas bubble alignment along <110> directions. It implies that 1-D interstitial migration along [110] direction should be the primary mechanism of a fcc gas bubble superlattice which is observed in bcc UMo alloys. Simulations also show that fission rates, saturated gas concentration, and elastic interaction all affect the morphology of gas bubble microstructures.

  15. Formation mechanism of gas bubble superlattice in UMo metal fuels: Phase-field modeling investigation

    SciTech Connect

    Hu, Shenyang; Burkes, Douglas E.; Lavender, Curt A.; Senor, David J.; Setyawan, Wahyu; Xu, Zhijie

    2016-07-08

    Nano-gas bubble superlattices are often observed in irradiated UMo nuclear fuels. However, the for- mation mechanism of gas bubble superlattices is not well understood. A number of physical processes may affect the gas bubble nucleation and growth; hence, the morphology of gas bubble microstructures including size and spatial distributions. In this work, a phase-field model integrating a first-passage Monte Carlo method to investigate the formation mechanism of gas bubble superlattices was devel- oped. Six physical processes are taken into account in the model: 1) heterogeneous generation of gas atoms, vacancies, and interstitials informed from atomistic simulations; 2) one-dimensional (1-D) migration of interstitials; 3) irradiation-induced dissolution of gas atoms; 4) recombination between vacancies and interstitials; 5) elastic interaction; and 6) heterogeneous nucleation of gas bubbles. We found that the elastic interaction doesn’t cause the gas bubble alignment, and fast 1-D migration of interstitials along $\\langle$110$\\rangle$ directions in the body-centered cubic U matrix causes the gas bubble alignment along $\\langle$110$\\rangle$ directions. It implies that 1-D interstitial migration along [110] direction should be the primary mechanism of a fcc gas bubble superlattice which is observed in bcc UMo alloys. Simulations also show that fission rates, saturated gas concentration, and elastic interaction all affect the morphology of gas bubble microstructures.

  16. Overview: Understanding nucleation phenomena from simulations of lattice gas models

    NASA Astrophysics Data System (ADS)

    Binder, Kurt; Virnau, Peter

    2016-12-01

    Monte Carlo simulations of homogeneous and heterogeneous nucleation in Ising/lattice gas models are reviewed with an emphasis on the general insight gained on the mechanisms by which metastable states decay. Attention is paid to the proper distinction of particles that belong to a cluster (droplet), that may trigger a nucleation event, from particles in its environment, a problem crucial near the critical point. Well below the critical point, the lattice structure causes an anisotropy of the interface tension, and hence nonspherical droplet shapes result, making the treatment nontrivial even within the conventional classical theory of homogeneous nucleation. For temperatures below the roughening transition temperature facetted crystals rather than spherical droplets result. The possibility to find nucleation barriers from a thermodynamic analysis avoiding a cluster identification on the particle level is discussed, as well as the question of curvature corrections to the interfacial tension. For the interpretation of heterogeneous nucleation at planar walls, knowledge of contact angles and line tensions is desirable, and methods to extract these quantities from simulations will be mentioned. Finally, also the problem of nucleation near the stability limit of metastable states and the significance of the spinodal curve will be discussed, in the light of simulations of Ising models with medium range interactions.

  17. Development of a natural gas systems analysis model (GSAM)

    SciTech Connect

    1999-10-01

    This report provides an overview of the activities to date and schedule for future testing, validation, and authorized enhancements of Natural Gas Systems Analysis Model (GSAM). The goal of this report is to inform DOE managers of progress in model development and to provide a benchmark for ongoing and future research. Section II of the report provides a detailed discussion on the major GSAM development programs performed and completed during the period of performance, July 1, 1998 to September 30, 1999. Key improvements in the new GSAM version are summarized in Section III. Programmer's guides for GSAM main modules were produced to provide detailed descriptions of all major subroutines and main variables of the computer code. General logical flowcharts of the subroutines are also presented in the guides to provide overall picture of interactions between the subroutines. A standard structure of routine explanation is applied in every programmer's guide. The explanation is started with a brief description or main purpose of the routine, lists of input and output files read and created, and lists of invoked/child and calling/parent routines. In some of the guides, interactions between the routine itself and its parent and child routines are presented in the form of graphical flowchart. The explanation is then proceeded with step by step description of computer code in the subroutine where each step delegates a section of related code. Between steps, if a certain section of code needs further explanation, a Note is inserted with relevant explanation.

  18. Heuristic overlap-exchange model of noble gas chemical shifts

    NASA Astrophysics Data System (ADS)

    Adrian, Frank J.

    2004-05-01

    It is now generally recognized that overlap-exchange interactions are the primary cause of the medium-dependent magnetic shielding (chemical shift) in all noble gases except helium, although the attractive electrostatic-dispersion (van der Waals) interactions play an indirect role in determining the penetration of the interacting species into the repulsive overlap-exchange region. The short-range nature of these overlap-exchange interactions, combined with the fact that they often can be approximated by simple functions of the overlap of the wave functions of the interacting species, suggests a useful semiempirical model of these chemical shifts. In it the total shielding is the sum of shieldings due to pairwise interactions of the noble gas atom with the individual atoms of the medium, with the "atomic" shielding terms either estimated by simple functions of the atomic overlap integrals averaged over their Boltzmann-weighted separations, or determined by fits to experimental data in systems whose complexity makes the former procedure impractical. Results for 129Xe chemical shifts in the noble gases and in a variety of molecular and condensed systems, including families of n-alkanes, straight-chain alcohols, and the endohedral compounds Xe@C60 and Xe@C70 are encouraging for the applicability of the model to systems of technical and biomedical interest.

  19. Hierarchical framework for coupling a biogeochemical trace gas model to a general circulation model

    SciTech Connect

    Miller, N.L.; Foster, I.T.

    1994-04-01

    A scheme is described for the computation of terrestrial biogeochemical trace gas fluxes in the context of a general circulation model. This hierarchical system flux scheme (HSFS) incorporates five major components: (1) a general circulation model (GCM), which provides a medium-resolution (i.e., 1{degrees} by 1{degrees}) simulation of the atmospheric circulation; (2) a procedure for identifying regions of defined homogeneity of surface type within GCM grid cells; (3) a set of surface process models, to be run within each homogeneous region, which include a biophysical model, the Biosphere Atmospheric Transfer Scheme (BATS), and a biogeochemical model (BGCM); (4) an interpolation/integration system that transfers information between the GCM and surface process models with finer resolution; and (5) an interactive data array based on a geographic information system (GIS), which provides land characteristic information via the interpolator. The goals of this detailed investigation are to compute the local and global sensitivities of trace gas fluxes to GCM and BATS variables, the effects of trace gas fluxes on global climate, and the effects of global climate on specific biomes.

  20. [A line-by-line trace gas absorption model and its application in NDIR gas detection technology].

    PubMed

    Fang, Jing; Liu, Wen-qing; Zhang, Tian-shu

    2008-06-01

    An accurate line-by-line integral trace gas absorption model is presented in the present article. It is for mid-infrared band and can be used in the study on and application to detecting trace gas (or pollution gas). First of all, two algorithms of trace gas radioactive properties, line-by-line integral method and band model method, were introduced. The merits and demerits of each were compared. Several recent developed line-by-line integral calculation models were also introduced. Secondly, the basic principle of line-by-line integral trace gas absorption calculation model was described in detail. The absorption coefficient is a function of temperature, frequency (wave number), pressure, gas volume mixing ratio and constants associated with all contributing line transitions. The average monochromatic absorption coefficient at a given frequency of a given gas species can be written as the product of the number density of the molecular species to which the spectral line belongs, the line intensity and a line shape factor. Efficient calculation of the line shape factor may be required for different atmospheric conditions. In the lower atmosphere, the shape of spectral lines is dominated by pressure broadening and can be represented most simply by the Lorentz line shape factor. At high altitudes, the shape of spectral lines is governed by Doppler broadening At intermediate altitudes, they can be modeled using the Voigt line shape factor, a convolution of the Lorentz and Doppler line shape factors. Finally, in the section of experiment, the results calculated by model were compared with that measured by Fourier transform infrared spectrometer. As an instance, the model was applied to the detectors design of NDIR (non-dispersive infrared) technology and the relationship between signal intensity of detectors and concentration of CO2/CO was simulated by model. Available concentration range of detector was given by calculating the results of the model. It is based on

  1. Leakage detection of Marcellus Shale natural gas at an Upper Devonian gas monitoring well: a 3-d numerical modeling approach.

    PubMed

    Zhang, Liwei; Anderson, Nicole; Dilmore, Robert; Soeder, Daniel J; Bromhal, Grant

    2014-09-16

    Potential natural gas leakage into shallow, overlying formations and aquifers from Marcellus Shale gas drilling operations is a public concern. However, before natural gas could reach underground sources of drinking water (USDW), it must pass through several geologic formations. Tracer and pressure monitoring in formations overlying the Marcellus could help detect natural gas leakage at hydraulic fracturing sites before it reaches USDW. In this study, a numerical simulation code (TOUGH 2) was used to investigate the potential for detecting leaking natural gas in such an overlying geologic formation. The modeled zone was based on a gas field in Greene County, Pennsylvania, undergoing production activities. The model assumed, hypothetically, that methane (CH4), the primary component of natural gas, with some tracer, was leaking around an existing well between the Marcellus Shale and the shallower and lower-pressure Bradford Formation. The leaky well was located 170 m away from a monitoring well, in the Bradford Formation. A simulation study was performed to determine how quickly the tracer monitoring could detect a leak of a known size. Using some typical parameters for the Bradford Formation, model results showed that a detectable tracer volume fraction of 2.0 × 10(-15) would be noted at the monitoring well in 9.8 years. The most rapid detection of tracer for the leak rates simulated was 81 days, but this scenario required that the leakage release point was at the same depth as the perforation zone of the monitoring well and the zones above and below the perforation zone had low permeability, which created a preferred tracer migration pathway along the perforation zone. Sensitivity analysis indicated that the time needed to detect CH4 leakage at the monitoring well was very sensitive to changes in the thickness of the high-permeability zone, CH4 leaking rate, and production rate of the monitoring well.

  2. The real-time estimation of hazardous gas dispersion by the integration of gas detectors, neural network and gas dispersion models.

    PubMed

    Wang, Bing; Chen, Bingzhen; Zhao, Jinsong

    2015-12-30

    Release of hazardous materials in chemical industries is a major threat to surrounding areas. Current gas dispersion models like PHAST and FLACS, use release velocity, release elevation, meteorological parameters, and other related information as model input. In general, such information is not always available during an on-going accident. In this paper, we develop a fast prediction approach which could bypass the input parameters that are difficult to obtain and predict the released gas concentration at certain off-site location using parameters that could be obtained easily. The new approach is an integration of gas detectors, artificial neural network (ANN) and one of the aforementioned gas dispersion models. PHAST is applied to simulate numbers of release scenarios and the results containing the spatial and temporal distributions of released gas concentration are prepared as input and target data samples for training the neural network. The approach was applied to a case study involving a hypothetical chlorine release with varying release rates and atmospheric conditions. The results of the approach that are concentration and dispersion time profiles in the environmental sensitive locations were validated against PHAST. The validation shows highly correlations with PHAST and convincingly demonstrates the effectiveness of the proposed approach.

  3. Testing Equilibrium Models of Molecular Gas in the Magellanic Clouds

    NASA Astrophysics Data System (ADS)

    Wong, Tony

    We propose to study the molecular gas fractions and physical conditions of diffuse molecular clouds in the Magellanic Clouds using ultraviolet (UV) and optical absorption spectra, principally from the Far Ultraviolet Spectroscopic Explorer (FUSE) and Hubble Space Telescope (HST) archives. We will use these data to constrain the abundance of molecular hydrogen (H_2) undetectable in CO emission surveys and to test equilibrium models that seek to predict the H_2 mass fraction and the H_2/HI ratio as functions of metallicity, column density, and thermal pressure. Our approach complements HI and CO surveys by providing direct estimates of HI and H_2 column densities. For sight lines where sufficiently high resolution spectra are available, we will use the excitation of CI to determine thermal pressures, allowing us to test models that assume thermodynamic equilibrium in order to determine the HI-H_2 balance. The recently completed Spitzer Legacy surveys of the MCs provide images of PAH emission on sub-parsec scales, which may provide a means to model the distribution and small-scale clumping of gas in the vicinity of the absorption sight lines, and thus connect the absorption data with the much coarser resolution radio data. We will investigate this possibility and the implications that small-scale clumping have for comparisons with theoretical models. A preliminary analysis of the FUSE and HST data is already underway, and we present a few early results. We seek support to continue this effort over the next two years and to disseminate our results. Our methodology is novel in several respects. It includes the use of high-resolution optical spectra to derive component models for the FUSE absorption spectra, in order to derive more accurate column densities, especially for the higher J transitions of H_2 which provide key diagnostics of density and radiation field strength. Such component models will also aid in the analysis of the CI spectra. We will work to increase

  4. Rarefied gas flow simulations using high-order gas-kinetic unified algorithms for Boltzmann model equations

    NASA Astrophysics Data System (ADS)

    Li, Zhi-Hui; Peng, Ao-Ping; Zhang, Han-Xin; Yang, Jaw-Yen

    2015-04-01

    This article reviews rarefied gas flow computations based on nonlinear model Boltzmann equations using deterministic high-order gas-kinetic unified algorithms (GKUA) in phase space. The nonlinear Boltzmann model equations considered include the BGK model, the Shakhov model, the Ellipsoidal Statistical model and the Morse model. Several high-order gas-kinetic unified algorithms, which combine the discrete velocity ordinate method in velocity space and the compact high-order finite-difference schemes in physical space, are developed. The parallel strategies implemented with the accompanying algorithms are of equal importance. Accurate computations of rarefied gas flow problems using various kinetic models over wide ranges of Mach numbers 1.2-20 and Knudsen numbers 0.0001-5 are reported. The effects of different high resolution schemes on the flow resolution under the same discrete velocity ordinate method are studied. A conservative discrete velocity ordinate method to ensure the kinetic compatibility condition is also implemented. The present algorithms are tested for the one-dimensional unsteady shock-tube problems with various Knudsen numbers, the steady normal shock wave structures for different Mach numbers, the two-dimensional flows past a circular cylinder and a NACA 0012 airfoil to verify the present methodology and to simulate gas transport phenomena covering various flow regimes. Illustrations of large scale parallel computations of three-dimensional hypersonic rarefied flows over the reusable sphere-cone satellite and the re-entry spacecraft using almost the largest computer systems available in China are also reported. The present computed results are compared with the theoretical prediction from gas dynamics, related DSMC results, slip N-S solutions and experimental data, and good agreement can be found. The numerical experience indicates that although the direct model Boltzmann equation solver in phase space can be computationally expensive

  5. Modeling Grade IV Gas Emboli using a Limited Failure Population Model with Random Effects

    NASA Technical Reports Server (NTRS)

    Thompson, Laura A.; Conkin, Johnny; Chhikara, Raj S.; Powell, Michael R.

    2002-01-01

    Venous gas emboli (VGE) (gas bubbles in venous blood) are associated with an increased risk of decompression sickness (DCS) in hypobaric environments. A high grade of VGE can be a precursor to serious DCS. In this paper, we model time to Grade IV VGE considering a subset of individuals assumed to be immune from experiencing VGE. Our data contain monitoring test results from subjects undergoing up to 13 denitrogenation test procedures prior to exposure to a hypobaric environment. The onset time of Grade IV VGE is recorded as contained within certain time intervals. We fit a parametric (lognormal) mixture survival model to the interval-and right-censored data to account for the possibility of a subset of "cured" individuals who are immune to the event. Our model contains random subject effects to account for correlations between repeated measurements on a single individual. Model assessments and cross-validation indicate that this limited failure population mixture model is an improvement over a model that does not account for the potential of a fraction of cured individuals. We also evaluated some alternative mixture models. Predictions from the best fitted mixture model indicate that the actual process is reasonably approximated by a limited failure population model.

  6. A SIMPLE PHYSICAL MODEL FOR THE GAS DISTRIBUTION IN GALAXY CLUSTERS

    SciTech Connect

    Patej, Anna; Loeb, Abraham

    2015-01-01

    The dominant baryonic component of galaxy clusters is hot gas whose distribution is commonly probed through X-ray emission arising from thermal bremsstrahlung. The density profile thus obtained has been traditionally modeled with a β-profile, a simple function with only three parameters. However, this model is known to be insufficient for characterizing the range of cluster gas distributions and attempts to rectify this shortcoming typically introduce additional parameters to increase the fitting flexibility. We use cosmological and physical considerations to obtain a family of profiles for the gas with fewer parameters than the β-model but which better accounts for observed gas profiles over wide radial intervals.

  7. FIRST ORDER KINETIC GAS GENERATION MODEL PARAMETERS FOR WET LANDFILLS

    EPA Science Inventory

    Landfill gas is produced as a result of a sequence of physical, chemical, and biological processes occurring within an anaerobic landfill. Landfill operators, energy recovery project owners, regulators, and energy users need to be able to project the volume of gas produced and re...

  8. Modeling Coma Gas Jets in Comet Hale-Bopp

    NASA Technical Reports Server (NTRS)

    Lederer, S. M.; Campins, H.

    2001-01-01

    We present an analysis of OH, CN, and C2 jets observed in Comet Hale-Bopp. The relative contributions from and composition of the coma gas sources, and the parameters describing the active areas responsible for the gas jets will be discussed. Additional information is contained in the original extended abstract.

  9. Teaching Pulmonary Gas Exchange Physiology Using Computer Modeling

    ERIC Educational Resources Information Center

    Kapitan, Kent S.

    2008-01-01

    Students often have difficulty understanding the relationship of O[subscript 2] consumption, CO[subscript 2] production, cardiac output, and distribution of ventilation-perfusion ratios in the lung to the final arterial blood gas composition. To overcome this difficulty, I have developed an interactive computer simulation of pulmonary gas exchange…

  10. Model operating permits for natural gas processing plants

    SciTech Connect

    Arend, C.

    1995-12-31

    Major sources as defined in Title V of the Clean Air Act Amendments of 1990 that are required to submit an operating permit application will need to: Evaluate their compliance status; Determine a strategic method of presenting the general and specific conditions of their Model Operating Permit (MOP); Maintain compliance with air quality regulations. A MOP is prepared to assist permitting agencies and affected facilities in the development of operating permits for a specific source category. This paper includes a brief discussion of example permit conditions that may be applicable to various types of Title V sources. A MOP for a generic natural gas processing plant is provided as an example. The MOP should include a general description of the production process and identify emission sources. The two primary elements that comprise a MOP are: Provisions of all existing state and/or local air permits; Identification of general and specific conditions for the Title V permit. The general provisions will include overall compliance with all Clean Air Act Titles. The specific provisions include monitoring, record keeping, and reporting. Although Title V MOPs are prepared on a case-by-case basis, this paper will provide a general guideline of the requirements for preparation of a MOP. Regulatory agencies have indicated that a MOP included in the Title V application will assist in preparation of the final permit provisions, minimize delays in securing a permit, and provide support during the public notification process.

  11. Calculating soil gas fluxes from gas concentration profiles: can we use standard DS models or should we use site-specific DS models?

    NASA Astrophysics Data System (ADS)

    Paulus, Sinikka; Jochheim, Hubert; Wirth, Stephan; Maier, Martin

    2015-04-01

    The apparent gas diffusion coefficient in soil (DS) is an important parameter describing soil aeration. It also links the profiles of soil gas concentration and soil gas flux using Fick's law. Soil gas diffusivity depends mainly on the structure of the pore system and the soil moisture status. There are several standard DS-models available that can easily be used for calculating DS. Another, more laborious option is to calibrate site specific DS models on soil core samples from the respective profile. We tested 4 standard DS models and a site-specific model and compared the resulting soil gas fluxes in two forest soils. Differences between the models were substantial. Another very important effect, however, is that standard DS models are usually derived from a single soil moisture measurement (device), that can result in an substantial offset in soil moisture estimation. The mean soil moisture content at a depth can be addressed more accurately by taking several soil cores. As a consequence, using standard DS models in combination with a single soil moisture measurement is less reliable than using site-specific models based on several soil samples.

  12. A petroleum system model for gas hydrate deposits in northern Alaska

    USGS Publications Warehouse

    Lorenson, T.D.; Collett, Timothy S.; Wong, Florence L.

    2011-01-01

    Gas hydrate deposits are common on the North Slope of Alaska around Prudhoe Bay, however the extent of these deposits is unknown outside of this area. As part of a United States Geological Survey (USGS) and the Bureau of Land Management (BLM) gas hydrate research collaboration, well cutting and mud gas samples have been collected and analyzed from mainly industry-drilled wells on the Alaska North Slope for the purpose of prospecting for gas hydrate deposits. On the Alaska North Slope, gas hydrates are now recognized as an element within a petroleum systems approach or TPS (Total Petroleum System). Since 1979, 35 wells have been samples from as far west as Wainwright to Prudhoe Bay in the east. Geochemical studies of known gas hydrate occurrences on the North Slope have shown a link between gas hydrate and more deeply buried conventional oil and gas deposits. Hydrocarbon gases migrate from depth and charge the reservoir rock within the gas hydrate stability zone. It is likely gases migrated into conventional traps as free gas, and were later converted to gas hydrate in response to climate cooling concurrent with permafrost formation. Gas hydrate is known to occur in one of the sampled wells, likely present in 22 others based gas geochemistry and inferred by equivocal gas geochemistry in 11 wells, and absent in one well. Gas migration routes are common in the North Slope and include faults and widespread, continuous, shallowly dipping permeable sand sections that are potentially in communication with deeper oil and gas sources. The application of this model with the geochemical evidence suggests that gas hydrate deposits may be widespread across the North Slope of Alaska.

  13. Literature search for offsite data to improve the DWPF melter off-gas model

    SciTech Connect

    Daniel, W.E.

    2000-05-04

    This report documents the literature search performed and any relevant data that may help relax some of the constraints on the DWPF melter off-gas model. The objective of this task was to look for outside sources of technical data to help reduce some of the conservatism built in the DWPF melter off-gas model.

  14. Ammonia quantitative analysis model based on miniaturized Al ionization gas sensor and non-linear bistable dynamic model

    PubMed Central

    Ma, Rongfei

    2015-01-01

    In this paper, ammonia quantitative analysis based on miniaturized Al ionization gas sensor and non-linear bistable dynamic model was proposed. Al plate anodic gas-ionization sensor was used to obtain the current-voltage (I-V) data. Measurement data was processed by non-linear bistable dynamics model. Results showed that the proposed method quantitatively determined ammonia concentrations. PMID:25975362

  15. Multiscale development of a fission gas thermal conductivity model: Coupling atomic, meso and continuum level simulations

    NASA Astrophysics Data System (ADS)

    Tonks, Michael R.; Millett, Paul C.; Nerikar, Pankaj; Du, Shiyu; Andersson, David; Stanek, Christopher R.; Gaston, Derek; Andrs, David; Williamson, Richard

    2013-09-01

    Fission gas production and evolution significantly impact the fuel performance, causing swelling, a reduction in the thermal conductivity and fission gas release. However, typical empirical models of fuel properties treat each of these effects separately and uncoupled. Here, we couple a fission gas release model to a model of the impact of fission gas on the fuel thermal conductivity. To quantify the specific impact of grain boundary (GB) bubbles on the thermal conductivity, we use atomistic and mesoscale simulations. Atomistic molecular dynamic simulations were employed to determine the GB thermal resistance. These values were then used in mesoscale heat conduction simulations to develop a mechanistic expression for the effective GB thermal resistance of a GB containing gas bubbles, as a function of the percentage of the GB covered by fission gas. The coupled fission gas release and thermal conductivity model was implemented in Idaho National Laboratory's BISON fuel performance code to model the behavior of a 10-pellet LWR fuel rodlet, showing how the fission gas impacts the UO2 thermal conductivity. Furthermore, additional BISON simulations were conducted to demonstrate the impact of average grain size on both the fuel thermal conductivity and the fission gas release.

  16. Modeling the Relative GHG Emissions of Conventional and Shale Gas Production

    PubMed Central

    2011-01-01

    Recent reports show growing reserves of unconventional gas are available and that there is an appetite from policy makers, industry, and others to better understand the GHG impact of exploiting reserves such as shale gas. There is little publicly available data comparing unconventional and conventional gas production. Existing studies rely on national inventories, but it is not generally possible to separate emissions from unconventional and conventional sources within these totals. Even if unconventional and conventional sites had been listed separately, it would not be possible to eliminate site-specific factors to compare gas production methods on an equal footing. To address this difficulty, the emissions of gas production have instead been modeled. In this way, parameters common to both methods of production can be held constant, while allowing those parameters which differentiate unconventional gas and conventional gas production to vary. The results are placed into the context of power generation, to give a ″well-to-wire″ (WtW) intensity. It was estimated that shale gas typically has a WtW emissions intensity about 1.8–2.4% higher than conventional gas, arising mainly from higher methane releases in well completion. Even using extreme assumptions, it was found that WtW emissions from shale gas need be no more than 15% higher than conventional gas if flaring or recovery measures are used. In all cases considered, the WtW emissions of shale gas powergen are significantly lower than those of coal. PMID:22085088

  17. Modeling the relative GHG emissions of conventional and shale gas production.

    PubMed

    Stephenson, Trevor; Valle, Jose Eduardo; Riera-Palou, Xavier

    2011-12-15

    Recent reports show growing reserves of unconventional gas are available and that there is an appetite from policy makers, industry, and others to better understand the GHG impact of exploiting reserves such as shale gas. There is little publicly available data comparing unconventional and conventional gas production. Existing studies rely on national inventories, but it is not generally possible to separate emissions from unconventional and conventional sources within these totals. Even if unconventional and conventional sites had been listed separately, it would not be possible to eliminate site-specific factors to compare gas production methods on an equal footing. To address this difficulty, the emissions of gas production have instead been modeled. In this way, parameters common to both methods of production can be held constant, while allowing those parameters which differentiate unconventional gas and conventional gas production to vary. The results are placed into the context of power generation, to give a ″well-to-wire″ (WtW) intensity. It was estimated that shale gas typically has a WtW emissions intensity about 1.8-2.4% higher than conventional gas, arising mainly from higher methane releases in well completion. Even using extreme assumptions, it was found that WtW emissions from shale gas need be no more than 15% higher than conventional gas if flaring or recovery measures are used. In all cases considered, the WtW emissions of shale gas powergen are significantly lower than those of coal.

  18. Gas-dynamic modeling of gas flow in semi-closed space including channel surface fluctuation

    NASA Astrophysics Data System (ADS)

    Petrova, E. N.; Salnikov, A. F.

    2016-10-01

    In this article frequency interaction conditions, that affect on acoustic stability of solid-propellant rocket engine (SPRE) action, and its influence on level change of pressure fluctuations with longitudinal gas oscillations in the combustion chamber (CC) are considered. Studies of CC in the assessment of the operating rocket engine stability are reported.

  19. Gas cushion model and hydrodynamic boundary conditions for superhydrophobic textures

    NASA Astrophysics Data System (ADS)

    Nizkaya, Tatiana V.; Asmolov, Evgeny S.; Vinogradova, Olga I.

    2014-10-01

    Superhydrophobic Cassie textures with trapped gas bubbles reduce drag, by generating large effective slip, which is important for a variety of applications that involve a manipulation of liquids at the small scale. Here we discuss how the dissipation in the gas phase of textures modifies their friction properties. We propose an operator method, which allows us to map the flow in the gas subphase to a local slip boundary condition at the liquid-gas interface. The determined uniquely local slip length depends on the viscosity contrast and underlying topography, and can be immediately used to evaluate an effective slip of the texture. Besides superlubricating Cassie surfaces, our approach is valid for rough surfaces impregnated by a low-viscosity "lubricant," and even for Wenzel textures, where a liquid follows the surface relief. These results provide a framework for the rational design of textured surfaces for numerous applications.

  20. EIA model documentation: Documentation of the Oil and Gas Supply Module (OGSM)

    SciTech Connect

    1997-01-01

    The purpose of this report is to define the objectives of the Oil and Gas Supply Model (OGSM), to describe the model`s basic approach, and to provide detail on how the model works. This report is intended as a reference document for model analysts, users, and the public. Projected production estimates of US crude oil and natural gas are based on supply functions generated endogenously within National Energy Modeling System (NEMS) by the OGSM. OGSM encompasses domestic crude oil and natural gas supply by both conventional and nonconventional recovery techniques. Nonconventional recovery includes enhanced oil recovery (EOR), and unconventional gas recovery (UGR) from tight gas formations, Devonian shale and coalbeds. Crude oil and natural gas projects are further disaggregated by geographic region. OGSM projects US domestic oil and gas supply for six Lower 48 onshore regions, three offshore regions, and Alaska. The general methodology relies on forecasted drilling expenditures and average drilling costs to determine exploratory and developmental drilling levels for each region and fuel type. These projected drilling levels translate into reserve additions, as well as a modification of the production capacity for each region. OGSM also represents foreign trade in natural gas, imports and exports by entry region.

  1. INTEGRATED PROCESS GAS MODELING FOR TRITIUM SYSTEMS AT THE SAVANNAH RIVER SITE

    SciTech Connect

    Hang, T; Anita Poore, A

    2007-08-30

    Significant savings are being realized from the consolidated tritium gas-processing operations at the Savannah River Site. However, the trade-off is some reduction of operational flexibility due to decreased storage capacity for process and waste gases. Savannah River National Laboratory researchers are developing an integrated process gas model for tritium processing using Aspen Custom Modeler{trademark} (ACM) software. The modeling involves fully characterizing process flow streams (gas composition, quantity), frequency of batch transfers, and availability of equipment in the flow stream. The model provides a valuable engineering tool to identify flow bottlenecks, thereby enabling adjustments to be made to improve process operations.

  2. Fast and accurate calculation of dilute quantum gas using Uehling-Uhlenbeck model equation

    NASA Astrophysics Data System (ADS)

    Yano, Ryosuke

    2017-02-01

    The Uehling-Uhlenbeck (U-U) model equation is studied for the fast and accurate calculation of a dilute quantum gas. In particular, the direct simulation Monte Carlo (DSMC) method is used to solve the U-U model equation. DSMC analysis based on the U-U model equation is expected to enable the thermalization to be accurately obtained using a small number of sample particles and the dilute quantum gas dynamics to be calculated in a practical time. Finally, the applicability of DSMC analysis based on the U-U model equation to the fast and accurate calculation of a dilute quantum gas is confirmed by calculating the viscosity coefficient of a Bose gas on the basis of the Green-Kubo expression and the shock layer of a dilute Bose gas around a cylinder.

  3. Modelling and simulation of heavy gas dispersion on the basis of modifications in plume path theory.

    PubMed

    Khan, F I; Abbasi, S A

    2000-12-30

    An analytical model for heavy gas dispersion based on the modifications in plume path theory has been developed. The model takes into account the variations in temperature, density, and specific heat during the movement of heavy gas plume. The model has been tested for three hazardous gases - chlorine, natural gas and liquefied petroleum gas. The results have been compared with the recently generated experimental data as also with the outputs of other models. A good agreement is observed qualitatively as well as quantitatively. A study has also been carried out to simulate the effect of the wind speed, density of the gas, and venting speed on dispersion. Based on the simulation study a set of empirical equations has been developed. The equations are validated by theoretical as well as experimental studies.

  4. Critique of the mid-range energy forecasting, system oil and gas supply models

    SciTech Connect

    Patton, W.P.

    1980-10-01

    The Mid-Range Energy Forecasting System (MEFS) is a model used by the Department of Energy to forecast domestic production, consumption and price for conventional energy sources on a regional basis over a period of 5 to 15 years. Among the energy sources included in the model are oil, gas and other petroleum fuels, coal, uranium, and electricity. Final consumption of alternative energy sources is broken into end-use categories, such as residential, commercial and industrial uses. Regional prices for all energy sources are calculated by iteratively equating domestic supply and demand. The purpose of this paper is to assess the ability of the Oil and Gas Supply Submodels of MEFS to reliably and accurately project oil and gas supply curves, which are used in the integrating model, along with fuel demand curves to estimate market price. The reliability and accuracy of the oil and gas model cannot be judged by comparing its predictions against actual observations because those observations have not yet occurred. The reliability and reasonableness of the oil and gas supply model can be judged, however, by analyzing how well its assumptions and predictions correspond to accepted economic principles. This is the approach taken in this critique. The remainder of this paper describes the general structure of the oil and gas supply model and how it functions to project the quantity of oil and gas forthcoming at given prices in a particular year, then discusses the economic soundness of the model, and finally suggests model changes to improve its performance.

  5. Short-Term Energy Outlook Model Documentation: Natural Gas Consumption and Prices

    EIA Publications

    2015-01-01

    The natural gas consumption and price modules of the Short-Term Energy Outlook (STEO) model are designed to provide consumption and end-use retail price forecasts for the residential, commercial, and industrial sectors in the nine Census districts and natural gas working inventories in three regions. Natural gas consumption shares and prices in each Census district are used to calculate an average U.S. retail price for each end-use sector.

  6. Scattering, Adsorption, and Langmuir-Hinshelwood Desorption Models for Physisorptive and Chemisorptive Gas-Surface Systems

    DTIC Science & Technology

    2013-09-01

    Gas -Surface Interaction Models in DSMC Analysis of Rarefied Hypersonic Flow ,” 39th AIAA Thermophysics Conference. Miami: AIAA, June 2007. 128. Payne...collides with the surface. θ is measured in monolayers (ML). 2. The gas molecule scatters using a scattering method or kernel. Accommoda- tion coefficients...Simulation of Gas Flows . New York: Oxford University Press, 1994. 21. Bitensky, I., E. Parilis, S. Della-Negra, and Y. Beyec. “Emission of hydrogen ions

  7. A numerical study of gas transport in human lung models

    NASA Astrophysics Data System (ADS)

    Lin, Ching-Long; Hoffman, Eric A.

    2005-04-01

    Stable Xenon (Xe) gas has been used as an imaging agent for decades in its radioactive form, is chemically inert, and has been used as a ventilation tracer in its non radioactive form during computerized tomography (CT) imaging. Magnetic resonance imaging (MRI) using hyperpolarized Helium (He) gas and Xe has also emerged as a powerful tool to study regional lung structure and function. However, the present state of knowledge regarding intra-bronchial Xe and He transport properties is incomplete. As the use of these gases rapidly advances, it has become critically important to understand the nature of their transport properties and to, in the process, better understand the role of gas density in general in determining regional distribution of respiratory gases. In this paper, we applied the custom developed characteristic-Galerkin finite element method, which solves the three-dimensional (3D) incompressible variable-density Navier-Stokes equations, to study the transport of Xe and He in the CT-based human lung geometries, especially emulating the washin and washout processes. The realistic lung geometries are segmented and reconstructed from CT images as part of an effort to build a normative atlas (NIH HL-064368) documenting airway geometry over 4 decades of age in healthy and disease-state adult humans. The simulation results show that the gas transport process depends on the gas density and the body posture. The implications of these results on the difference between washin and washout time constants are discussed.

  8. Universal model for water costs of gas exchange by animals and plants.

    PubMed

    Woods, H Arthur; Smith, Jennifer N

    2010-05-04

    For terrestrial animals and plants, a fundamental cost of living is water vapor lost to the atmosphere during exchange of metabolic gases. Here, by bringing together previously developed models for specific taxa, we integrate properties common to all terrestrial gas exchangers into a universal model of water loss. The model predicts that water loss scales to gas exchange with an exponent of 1 and that the amount of water lost per unit of gas exchanged depends on several factors: the surface temperature of the respiratory system near the outside of the organism, the gas consumed (oxygen or carbon dioxide), the steepness of the gradients for gas and vapor, and the transport mode (convective or diffusive). Model predictions were largely confirmed by data on 202 species in five taxa--insects, birds, bird eggs, mammals, and plants--spanning nine orders of magnitude in rate of gas exchange. Discrepancies between model predictions and data seemed to arise from biologically interesting violations of model assumptions, which emphasizes how poorly we understand gas exchange in some taxa. The universal model provides a unified conceptual framework for analyzing exchange-associated water losses across taxa with radically different metabolic and exchange systems.

  9. Models, Simulators, and Data-driven Resources for Oil and Natural Gas Research

    DOE Data Explorer

    NETL provides a number of analytical tools to assist in conducting oil and natural gas research. Software, developed under various DOE/NETL projects, includes numerical simulators, analytical models, databases, and documentation.[copied from http://www.netl.doe.gov/technologies/oil-gas/Software/Software_main.html] Links lead users to methane hydrates models, preedictive models, simulators, databases, and other software tools or resources.

  10. A Mathematical Model of Gas-Turbine Pump Complex

    NASA Astrophysics Data System (ADS)

    Shpilevoy, V. A.; Chekardovsky, S. M.; Zakirazkov, A. G.

    2016-10-01

    The articles analyzes the state of an extensive network of main oil pipelines of Tyumen region on the basis of statistical data, and also suggest ways of improving the efficiency of energy-saving policy on the main transport oil. Various types of main oil pipelines pump drives were examined. It was determined that now there is no strict analytical dependence between main operating properties of the power turbine of gas turbine engine. At the same time it is necessary to determine the operating parameters using a turbine at GTPU, interconnection between power and speed frequency, as well as the feasibility of using a particular mode. Analysis of foreign experience, the state of domestic enterprises supplying the country with gas turbines, features of the further development of transport of hydrocarbon resources allows us to conclude the feasibility of supplying the oil transportation industry of our country with pumping units based on gas turbine drive.

  11. Numerical models of starburst galaxies: Galactic winds and entrained gas

    NASA Astrophysics Data System (ADS)

    Tanner, Ryan

    My three-dimensional hydro-dynamical simulations of starbursts examine the formation of starburst-driven superbubbles over a range of driving luminosities and mass loadings that determine superbubble growth and wind velocity; floors of both 10 and 10. 4 K are considered. From this I determine the relationshipbetween the velocity of a galactic wind and the characteristics of the starburst. I find a threshold for the formation of a wind, above which the wind speed is not affected by grid resolution or the temperature floor of the radiative cooling employed. Optically bright filaments form at the edge of merging superbubbles, or where a cold dense cloud has been disrupted by the wind. Filaments formed by merging superbubbles will persist and grow to >400 pc in length if anchored to and fed from a star forming complex. For galaxies viewed edge on I use total emission from the superbubble to infer the wind velocity and starburst properties such as thermalization efficiency and mass loading factor. Using synthetic absorption profiles I probe different temperature regimes and measure the velocity of the cold, warm and hot gas phases. I find that the cold and warm gas entrained in the wind move at a much lower velocity than the hot gas, with some of the cold gas in the filaments hardly moving with respect to the galaxy. The absorption profiles show that the velocity of the hot galactic outflow does not depend on the star formation rate (SFR), but the velocity of the warm gas does. The velocity of the warm gas scales as SFR. delta untilthe wind velocity reaches 80 % of the analytic terminal wind speed. The value of delta depends on the atomic ionization with a lower value for low ionization, and a higher value for higher ionization.

  12. Computational modeling of Krypton gas puffs with tailored mass density profiles on Z

    SciTech Connect

    Jennings, C. A.; Ampleford, D. J.; Lamppa, D. C.; Hansen, S. B.; Jones, B.; Harvey-Thompson, A. J.; Jobe, M.; Strizic, T.; Reneker, J.; Rochau, G. A.; Cuneo, M. E.

    2015-05-15

    Large diameter multi-shell gas puffs rapidly imploded by high current (∼20 MA, ∼100 ns) on the Z generator of Sandia National Laboratories are able to produce high-intensity Krypton K-shell emission at ∼13 keV. Efficiently radiating at these high photon energies is a significant challenge which requires the careful design and optimization of the gas distribution. To facilitate this, we hydrodynamically model the gas flow out of the nozzle and then model its implosion using a 3-dimensional resistive, radiative MHD code (GORGON). This approach enables us to iterate between modeling the implosion and gas flow from the nozzle to optimize radiative output from this combined system. Guided by our implosion calculations, we have designed gas profiles that help mitigate disruption from Magneto-Rayleigh–Taylor implosion instabilities, while preserving sufficient kinetic energy to thermalize to the high temperatures required for K-shell emission.

  13. Computational modeling of Krypton gas puffs with tailored mass density profiles on Z

    SciTech Connect

    Jennings, Christopher A.; Ampleford, David J.; Lamppa, Derek C.; Hansen, Stephanie B.; Jones, Brent Manley; Harvey-Thompson, Adam James; Jobe, Marc Ronald Lee; Reneker, Joseph; Rochau, Gregory A.; Cuneo, Michael Edward; Strizic, T.

    2015-05-18

    Large diameter multi-shell gas puffs rapidly imploded by high current (~20 MA, ~100 ns) on the Z generator of Sandia National Laboratories are able to produce high-intensity Krypton K-shell emission at ~13 keV. Efficiently radiating at these high photon energies is a significant challenge which requires the careful design and optimization of the gas distribution. To facilitate this, we hydrodynamically model the gas flow out of the nozzle and then model its implosion using a 3-dimensional resistive, radiative MHD code (GORGON). This approach enables us to iterate between modeling the implosion and gas flow from the nozzle to optimize radiative output from this combined system. Furthermore, guided by our implosion calculations, we have designed gas profiles that help mitigate disruption from Magneto-Rayleigh–Taylor implosion instabilities, while preserving sufficient kinetic energy to thermalize to the high temperatures required for K-shell emission.

  14. Computational modeling of Krypton gas puffs with tailored mass density profiles on Z

    DOE PAGES

    Jennings, Christopher A.; Ampleford, David J.; Lamppa, Derek C.; ...

    2015-05-18

    Large diameter multi-shell gas puffs rapidly imploded by high current (~20 MA, ~100 ns) on the Z generator of Sandia National Laboratories are able to produce high-intensity Krypton K-shell emission at ~13 keV. Efficiently radiating at these high photon energies is a significant challenge which requires the careful design and optimization of the gas distribution. To facilitate this, we hydrodynamically model the gas flow out of the nozzle and then model its implosion using a 3-dimensional resistive, radiative MHD code (GORGON). This approach enables us to iterate between modeling the implosion and gas flow from the nozzle to optimize radiativemore » output from this combined system. Furthermore, guided by our implosion calculations, we have designed gas profiles that help mitigate disruption from Magneto-Rayleigh–Taylor implosion instabilities, while preserving sufficient kinetic energy to thermalize to the high temperatures required for K-shell emission.« less

  15. Atmosphere behavior in gas-closed mouse-algal systems - An experimental and modelling study

    NASA Technical Reports Server (NTRS)

    Averner, M. M.; Moore, B., III; Bartholomew, I.; Wharton, R.

    1984-01-01

    A NASA-sponsored research program initiated using mathematical modelling and laboratory experimentation aimed at examining the gas-exchange characteristics of artificial animal/plant systems closed to the ambient atmosphere is studied. The development of control techniques and management strategies for maintaining the atmospheric levels of carbon dioxide and oxygen at physiological levels is considered. A mathematical model simulating the behavior of a gas-closed mouse-algal system under varying environmental conditions is described. To verify and validate the model simulations, an analytical system with which algal growth and gas exchange characteristics can be manipulated and measured is designed, fabricated, and tested. The preliminary results are presented.

  16. A simple model of gas flow in a porous powder compact.

    SciTech Connect

    Shugard, Andrew D.; Robinson, David B.

    2014-04-01

    This report describes a simple model for ideal gas flow from a vessel through a bed of porous material into another vessel. It assumes constant temperature and uniform porosity. Transport is treated as a combination of viscous and molecular flow, with no inertial contribution (low Reynolds number). This model can be used to fit data to obtain permeability values, determine flow rates, understand the relative contributions of viscous and molecular flow, and verify volume calibrations. It draws upon the Dusty Gas Model and other detailed studies of gas flow through porous media.

  17. Models for Gas Hydrate-Bearing Sediments Inferred from Hydraulic Permeability and Elastic Velocities

    USGS Publications Warehouse

    Lee, Myung W.

    2008-01-01

    Elastic velocities and hydraulic permeability of gas hydrate-bearing sediments strongly depend on how gas hydrate accumulates in pore spaces and various gas hydrate accumulation models are proposed to predict physical property changes due to gas hydrate concentrations. Elastic velocities and permeability predicted from a cementation model differ noticeably from those from a pore-filling model. A nuclear magnetic resonance (NMR) log provides in-situ water-filled porosity and hydraulic permeability of gas hydrate-bearing sediments. To test the two competing models, the NMR log along with conventional logs such as velocity and resistivity logs acquired at the Mallik 5L-38 well, Mackenzie Delta, Canada, were analyzed. When the clay content is less than about 12 percent, the NMR porosity is 'accurate' and the gas hydrate concentrations from the NMR log are comparable to those estimated from an electrical resistivity log. The variation of elastic velocities and relative permeability with respect to the gas hydrate concentration indicates that the dominant effect of gas hydrate in the pore space is the pore-filling characteristic.

  18. Mathematical model of diffusion-limited gas bubble dynamics in unstirred tissue with finite volume

    NASA Technical Reports Server (NTRS)

    Srinivasan, R. Srini; Gerth, Wayne A.; Powell, Michael R.

    2002-01-01

    Models of gas bubble dynamics for studying decompression sickness have been developed by considering the bubble to be immersed in an extravascular tissue with diffusion-limited gas exchange between the bubble and the surrounding unstirred tissue. In previous versions of this two-region model, the tissue volume must be theoretically infinite, which renders the model inapplicable to analysis of bubble growth in a finite-sized tissue. We herein present a new two-region model that is applicable to problems involving finite tissue volumes. By introducing radial deviations to gas tension in the diffusion region surrounding the bubble, the concentration gradient can be zero at a finite distance from the bubble, thus limiting the tissue volume that participates in bubble-tissue gas exchange. It is shown that these deviations account for the effects of heterogeneous perfusion on gas bubble dynamics, and are required for the tissue volume to be finite. The bubble growth results from a difference between the bubble gas pressure and an average gas tension in the surrounding diffusion region that explicitly depends on gas uptake and release by the bubble. For any given decompression, the diffusion region volume must stay above a certain minimum in order to sustain bubble growth.

  19. LANDFILL GAS EMISSIONS MODEL (LANDGEM) VERSION 3.02 USER'S GUIDE

    EPA Science Inventory

    The Landfill Gas Emissions Model (LandGEM) is an automated estimation tool with a Microsoft Excel interface that can be used to estimate emission rates for total landfill gas, methane, carbon dioxide, nonmethane organic compounds, and individual air pollutants from municipal soli...

  20. Uncertainty and sensitivity analysis of fission gas behavior in engineering-scale fuel modeling

    SciTech Connect

    Pastore, Giovanni; Swiler, L. P.; Hales, Jason D.; Novascone, Stephen R.; Perez, Danielle M.; Spencer, Benjamin W.; Luzzi, Lelio; Uffelen, Paul Van; Williamson, Richard L.

    2014-10-12

    The role of uncertainties in fission gas behavior calculations as part of engineering-scale nuclear fuel modeling is investigated using the BISON fuel performance code and a recently implemented physics-based model for the coupled fission gas release and swelling. Through the integration of BISON with the DAKOTA software, a sensitivity analysis of the results to selected model parameters is carried out based on UO2 single-pellet simulations covering different power regimes. The parameters are varied within ranges representative of the relative uncertainties and consistent with the information from the open literature. The study leads to an initial quantitative assessment of the uncertainty in fission gas behavior modeling with the parameter characterization presently available. Also, the relative importance of the single parameters is evaluated. Moreover, a sensitivity analysis is carried out based on simulations of a fuel rod irradiation experiment, pointing out a significant impact of the considered uncertainties on the calculated fission gas release and cladding diametral strain. The results of the study indicate that the commonly accepted deviation between calculated and measured fission gas release by a factor of 2 approximately corresponds to the inherent modeling uncertainty at high fission gas release. Nevertheless, higher deviations may be expected for values around 10% and lower. Implications are discussed in terms of directions of research for the improved modeling of fission gas behavior for engineering purposes.

  1. Uncertainty and sensitivity analysis of fission gas behavior in engineering-scale fuel modeling

    DOE PAGES

    Pastore, Giovanni; Swiler, L. P.; Hales, Jason D.; ...

    2014-10-12

    The role of uncertainties in fission gas behavior calculations as part of engineering-scale nuclear fuel modeling is investigated using the BISON fuel performance code and a recently implemented physics-based model for the coupled fission gas release and swelling. Through the integration of BISON with the DAKOTA software, a sensitivity analysis of the results to selected model parameters is carried out based on UO2 single-pellet simulations covering different power regimes. The parameters are varied within ranges representative of the relative uncertainties and consistent with the information from the open literature. The study leads to an initial quantitative assessment of the uncertaintymore » in fission gas behavior modeling with the parameter characterization presently available. Also, the relative importance of the single parameters is evaluated. Moreover, a sensitivity analysis is carried out based on simulations of a fuel rod irradiation experiment, pointing out a significant impact of the considered uncertainties on the calculated fission gas release and cladding diametral strain. The results of the study indicate that the commonly accepted deviation between calculated and measured fission gas release by a factor of 2 approximately corresponds to the inherent modeling uncertainty at high fission gas release. Nevertheless, higher deviations may be expected for values around 10% and lower. Implications are discussed in terms of directions of research for the improved modeling of fission gas behavior for engineering purposes.« less

  2. Hot gas cleanup for molten carbonate fuel cells: A zinc reactor model

    NASA Astrophysics Data System (ADS)

    Steinfeld, G.

    1980-09-01

    Of the two near term options available for desulfurization of gasifier effluent, namely low temperature cleanup utilizing absorber/stripper technology, and hot gas cleanup utilizing metal oxides, there is a clear advantage to using hot gas cleanup. Since the MCFC will operate at 1200 F, and the gasifier effluent could be between 1200 to 1900 F, a hot gas cleanup system will require little or no change in process gas temperature, thereby contributing to a high overall system efficiency. Simulated operating characteristics to aid in system design and system simulations of gasifier/MCFC systems are described. The modeling of the ZnO reactor is presented.

  3. TESTING NONSTANDARD COSMOLOGICAL MODELS WITH SNLS3 SUPERNOVA DATA AND OTHER COSMOLOGICAL PROBES

    SciTech Connect

    Li Zhengxiang; Yu Hongwei; Wu Puxun

    2012-01-10

    We investigate the implications for some nonstandard cosmological models using data from the first three years of the Supernova Legacy Survey (SNLS3), assuming a spatially flat universe. A comparison between the constraints from the SNLS3 and those from other SN Ia samples, such as the ESSENCE, Union2, SDSS-II, and Constitution samples, is given and the effects of different light-curve fitters are considered. We find that analyzing SNe Ia with SALT2 or SALT or SiFTO can give consistent results and the tensions between different data sets and different light-curve fitters are obvious for fewer-free-parameters models. At the same time, we also study the constraints from SNLS3 along with data from the cosmic microwave background and the baryonic acoustic oscillations (CMB/BAO), and the latest Hubble parameter versus redshift (H(z)). Using model selection criteria such as {chi}{sup 2}/dof, goodness of fit, Akaike information criterion, and Bayesian information criterion, we find that, among all the cosmological models considered here ({Lambda}CDM, constant w, varying w, Dvali-Gabadadze-Porrati (DGP), modified polytropic Cardassian, and the generalized Chaplygin gas), the flat DGP is favored by SNLS3 alone. However, when additional CMB/BAO or H(z) constraints are included, this is no longer the case, and the flat {Lambda}CDM becomes preferred.

  4. Compilation of gas intrusion measurements, variations, and consequence modeling for SPR caverns.

    SciTech Connect

    Hinkebein, Thomas E.

    2003-03-01

    The intrusion of gas into oils stored within the SPR has been examined. When oil is stored in domal salts, gases intrude into the stored oil from the surrounding salt. Aspects of the mechanism of gas intrusion have been examined. In all cases, this gas intrusion results in increases in the oil vapor pressure. Data that have been gathered from 1993 to August 2002 are presented to show the resultant increases in bubble-point pressure on a cavern-by-cavern as well as on a stream basis. The measurement techniques are presented with particular emphasis on the TVP 95. Data analysis methods are presented to show the methods required to obtain recombined cavern oil compositions. Gas-oil ratios are also computed from the data and are presented on a cavern-by-cavern and stream basis. The observed increases in bubble-point pressure and gas-oil ratio are further statistically analyzed to allow data interpretation. Emissions plume modeling is used to determine adherence to state air regulations. Gas intrusion is observed to be variable among the sites and within each dome. Gas intrusions at Bryan Mound and Big Hill have resulted in the largest increases in bubble-point pressure for the Strategic Petroleum Reserve (SPR). The streams at Bayou Choctaw and West Hackberry show minimal bubble-point pressure increases. Emissions plume modeling, using the state mandated ISCST code, of oil storage tanks showed that virtually no gas may be released when H2S standards are considered. DOE plans to scavenge H2S to comply with the very tight standards on this gas. With the assumption of scavenging, benzene releases become the next most controlling factor. Model results show that a GOR of 0.6 SCF/BBL may be emissions that are within standards. Employing the benzene gas release standard will significantly improve oil deliverability. New plume modeling using the computational fluid dynamics code, FLUENT, is addressing limitations of the state mandated ISCST model.

  5. Uncertainty and sensitivity analysis of fission gas behavior in engineering-scale fuel modeling

    NASA Astrophysics Data System (ADS)

    Pastore, Giovanni; Swiler, L. P.; Hales, J. D.; Novascone, S. R.; Perez, D. M.; Spencer, B. W.; Luzzi, L.; Van Uffelen, P.; Williamson, R. L.

    2015-01-01

    The role of uncertainties in fission gas behavior calculations as part of engineering-scale nuclear fuel modeling is investigated using the BISON fuel performance code with a recently implemented physics-based model for fission gas release and swelling. Through the integration of BISON with the DAKOTA software, a sensitivity analysis of the results to selected model parameters is carried out based on UO2 single-pellet simulations covering different power regimes. The parameters are varied within ranges representative of the relative uncertainties and consistent with the information in the open literature. The study leads to an initial quantitative assessment of the uncertainty in fission gas behavior predictions with the parameter characterization presently available. Also, the relative importance of the single parameters is evaluated. Moreover, a sensitivity analysis is carried out based on simulations of a fuel rod irradiation experiment, pointing out a significant impact of the considered uncertainties on the calculated fission gas release and cladding diametral strain. The results of the study indicate that the commonly accepted deviation between calculated and measured fission gas release by a factor of 2 approximately corresponds to the inherent modeling uncertainty at high fission gas release. Nevertheless, significantly higher deviations may be expected for values around 10% and lower. Implications are discussed in terms of directions of research for the improved modeling of fission gas behavior for engineering purposes.

  6. Modeling the final phase of landfill gas generation from long-term observations.

    PubMed

    Tintner, Johannes; Kühleitner, Manfred; Binner, Erwin; Brunner, Norbert; Smidt, Ena

    2012-06-01

    For waste management, methane emissions from landfills and their effect on climate change are of serious concern. Current models for biogas generation that focus on the economic use of the landfill gas are usually based on first order chemical reactions (exponential decay), underestimating the long-term emissions of landfills. The presented study concentrated on the curve fitting and the quantification of the gas generation during the final degradation phase under optimal anaerobic conditions. For this purpose the long-term gas generation (240-1,830 days) of different mechanically biologically treated (MBT) waste materials was measured. In this study the late gas generation was modeled by a log-normal distribution curve to gather the maximum gas generation potential. According to the log-normal model the observed gas sum curve leads to higher values than commonly used exponential decay models. The prediction of the final phase of landfill gas generation by a fitting model provides a basis for CO(2) balances in waste management and some information to which extent landfills serve as carbon sink.

  7. A new pressure formulation for gas-compressibility dampening in bubble dynamics models.

    PubMed

    Gadi Man, Yezaz Ahmed; Trujillo, Francisco J

    2016-09-01

    We formulated a pressure equation for bubbles performing nonlinear radial oscillations under ultrasonic high pressure amplitudes. The proposed equation corrects the gas pressure at the gas-liquid interface on inertial bubbles. This pressure formulation, expressed in terms of gas-Mach number, accounts for dampening due to gas compressibility during the violent collapse of cavitation bubbles and during subsequent rebounds. We refer to this as inhomogeneous pressure, where the gas pressure at the gas-liquid interface can differ to the pressure at the centre of the bubble, in contrast to homogenous pressure formulations that consider that pressure inside the bubble is spatially uniform from the wall to the centre. The pressure correction was applied to two bubble dynamic models: the incompressible Rayleigh-Plesset equation and the compressible Keller and Miksis equation. This improved the predictions of the nonlinear radial motion of the bubble vs time obtained with both models. Those simulations were also compared with other bubble dynamics models that account for liquid and gas compressibility effects. It was found that our corrected models are in closer agreement with experimental data than alternative models. It was concluded that the Rayleigh-Plesset family of equations improve accuracy by using our proposed pressure correction.

  8. Alaska North Slope regional gas hydrate production modeling forecasts

    USGS Publications Warehouse

    Wilson, S.J.; Hunter, R.B.; Collett, T.S.; Hancock, S.; Boswell, R.; Anderson, B.J.

    2011-01-01

    A series of gas hydrate development scenarios were created to assess the range of outcomes predicted for the possible development of the "Eileen" gas hydrate accumulation, North Slope, Alaska. Production forecasts for the "reference case" were built using the 2002 Mallik production tests, mechanistic simulation, and geologic studies conducted by the US Geological Survey. Three additional scenarios were considered: A "downside-scenario" which fails to identify viable production, an "upside-scenario" describes results that are better than expected. To capture the full range of possible outcomes and balance the downside case, an "extreme upside scenario" assumes each well is exceptionally productive.Starting with a representative type-well simulation forecasts, field development timing is applied and the sum of individual well forecasts creating the field-wide production forecast. This technique is commonly used to schedule large-scale resource plays where drilling schedules are complex and production forecasts must account for many changing parameters. The complementary forecasts of rig count, capital investment, and cash flow can be used in a pre-appraisal assessment of potential commercial viability.Since no significant gas sales are currently possible on the North Slope of Alaska, typical parameters were used to create downside, reference, and upside case forecasts that predict from 0 to 71??BM3 (2.5??tcf) of gas may be produced in 20 years and nearly 283??BM3 (10??tcf) ultimate recovery after 100 years.Outlining a range of possible outcomes enables decision makers to visualize the pace and milestones that will be required to evaluate gas hydrate resource development in the Eileen accumulation. Critical values of peak production rate, time to meaningful production volumes, and investments required to rule out a downside case are provided. Upside cases identify potential if both depressurization and thermal stimulation yield positive results. An "extreme upside

  9. Modeling of Aerobrake Ballute Stagnation Point Temperature and Heat Transfer to Inflation Gas

    NASA Technical Reports Server (NTRS)

    Bahrami, Parviz A.

    2012-01-01

    A trailing Ballute drag device concept for spacecraft aerocapture is considered. A thermal model for calculation of the Ballute membrane temperature and the inflation gas temperature is developed. An algorithm capturing the most salient features of the concept is implemented. In conjunction with the thermal model, trajectory calculations for two candidate missions, Titan Explorer and Neptune Orbiter missions, are used to estimate the stagnation point temperature and the inflation gas temperature. Radiation from both sides of the membrane at the stagnation point and conduction to the inflating gas is included. The results showed that the radiation from the membrane and to a much lesser extent conduction to the inflating gas, are likely to be the controlling heat transfer mechanisms and that the increase in gas temperature due to aerodynamic heating is of secondary importance.

  10. Modeling of fault reactivation and induced seismicity during hydraulic fracturing of shale-gas reservoirs

    EPA Science Inventory

    We have conducted numerical simulation studies to assess the potential for injection-induced fault reactivation and notable seismic events associated with shale-gas hydraulic fracturing operations. The modeling is generally tuned toward conditions usually encountered in the Marce...

  11. Short-Term Energy Outlook Model Documentation: Hydrocarbon Gas Liquids Supply and Demand

    EIA Publications

    2015-01-01

    The hydrocarbon gas liquids (ethane, propane, butanes, and natural gasoline) module of the Short-Term Energy Outlook (STEO) model is designed to provide forecasts of U.S. production, consumption, refinery inputs, net imports, and inventories.

  12. Model for overscreened Kondo effect in ultracold Fermi gas

    NASA Astrophysics Data System (ADS)

    Kuzmenko, I.; Kuzmenko, T.; Avishai, Y.; Kikoin, K.

    2015-04-01

    The feasibility of realizing the overscreened Kondo effect in ultracold Fermi gas of atoms with spin s ≥ 3/2 in the presence of a localized magnetic impurity atom is proved realistic. Specifying (as a mere example) a system of ultracold 22Na Fermi gas and a trapped 6Li impurity, the mechanism of exchange interaction between the Na and Li atoms is elucidated and the exchange constant is found to be positive (antiferromagnetic). The corresponding exchange Hamiltonian is derived, and the Kondo temperature is estimated at the order of 500 nK. Within a weak-coupling renormalization group scheme, it is shown that the coupling renormalizes to the non-Fermi-liquid fixed point. An observable displaying multichannel features even in the weak-coupling regime is the impurity magnetization that is negative for T ≫TK and becomes positive with decreasing temperature.

  13. Atmosphere Behavior in Gas-Closed Mouse-Algal Systems: An Experimental and Modelling Study

    NASA Technical Reports Server (NTRS)

    Averner, M. M.; Moore, B., III; Bartholomew, I.; Wharton, R.

    1985-01-01

    A dual approach of mathematical modelling and laboratory experimentation aimed at examining the gas exchange characteristics of artificial animal/plant systems closed to the ambient atmosphere was initiated. The development of control techniques and management strategies for maintaining the atmospheric levels of carbon dioxide and oxygen at physiological levels is examined. A mathematical model simulating the atmospheric behavior in these systems was developed and an experimental gas closed system was constructed. These systems are described and preliminary results are presented.

  14. Computational Modeling of Microstructural-Evolution in AISI 1005 Steel During Gas Metal Arc Butt Welding

    DTIC Science & Technology

    2013-05-01

    of the commercially available metallic materials, in particular, steels (including stainless steels ), super alloys, aluminum alloys, etc.; (b) welding...REPORT Computational Modeling of Microstructural-Evolution in AISI 1005 Steel During Gas Metal Arc Butt Welding 14. ABSTRACT 16. SECURITY...Computational Modeling of Microstructural-Evolution in AISI 1005 Steel During Gas Metal Arc Butt Welding Report Title ABSTRACT A fully coupled (two-way

  15. Galactic evolution. I - Single-zone models. [encompassing stellar evolution and gas-star dynamic theories

    NASA Technical Reports Server (NTRS)

    Thuan, T. X.; Hart, M. H.; Ostriker, J. P.

    1975-01-01

    The two basic approaches of physical theory required to calculate the evolution of a galactic system are considered, taking into account stellar evolution theory and the dynamics of a gas-star system. Attention is given to intrinsic (stellar) physics, extrinsic (dynamical) physics, and computations concerning the fractionation of an initial mass of gas into stars. The characteristics of a 'standard' model and its variants are discussed along with the results obtained with the aid of these models.

  16. Analytical model of the temperature dependent properties of microresonators immersed in a gas

    SciTech Connect

    Ilin, E. A.; Kehrbusch, J.; Radzio, B.; Oesterschulze, E.

    2011-02-01

    A comprehensive theoretical model of microresonators immersed in a viscous gas of varying temperature is presented and verified by experiments. Analytical expressions for both the temperature dependent resonant frequency and quality factor of the first flexural eigenmode were derived extending Sader's theory of viscous damping to small temperature variations. The model provides useful implications for the thermal stabilization of microresonators immersed in a gas as well as for the reduction in the influence of the temperature dependent gas properties on the resonant frequency. Finally, an analytical expression is deduced for the mass detection capability of a microresonator that undergoes temperature variations.

  17. Gas transfer model to design a ventilator for neonatal total liquid ventilation.

    PubMed

    Bonfanti, Mirko; Cammi, Antonio; Bagnoli, Paola

    2015-12-01

    The study was aimed to optimize the gas transfer in an innovative ventilator for neonatal Total Liquid Ventilation (TLV) that integrates the pumping and oxygenation functions in a non-volumetric pulsatile device made of parallel flat silicone membranes. A computational approach was adopted to evaluate oxygen (O2) and carbon dioxide (CO2) exchanges between the liquid perfluorocarbon (PFC) and the oxygenating gas, as a function of the geometrical parameter of the device. A 2D semi-empirical model was implemented to this purpose using Comsol Multiphysics to study both the fluid dynamics and the gas exchange in the ventilator. Experimental gas exchanges measured with a preliminary prototype were compared to the simulation outcomes to prove the model reliability. Different device configurations were modeled to identify the optimal design able to guarantee the desired gas transfer. Good agreement between experimental and simulation outcomes was obtained, validating the model. The optimal configuration, able to achieve the desired gas exchange (ΔpCO2 = 16.5 mmHg and ΔpO2 = 69 mmHg), is a device comprising 40 modules, 300 mm in length (total exchange area = 2.28 m(2)). With this configuration gas transfer performance is satisfactory for all the simulated settings, proving good adaptability of the device.

  18. Mathematical model of diffusion-limited evolution of multiple gas bubbles in tissue

    NASA Technical Reports Server (NTRS)

    Srinivasan, R. Srini; Gerth, Wayne A.; Powell, Michael R.

    2003-01-01

    Models of gas bubble dynamics employed in probabilistic analyses of decompression sickness incidence in man must be theoretically consistent and simple, if they are to yield useful results without requiring excessive computations. They are generally formulated in terms of ordinary differential equations that describe diffusion-limited gas exchange between a gas bubble and the extravascular tissue surrounding it. In our previous model (Ann. Biomed. Eng. 30: 232-246, 2002), we showed that with appropriate representation of sink pressures to account for gas loss or gain due to heterogeneous blood perfusion in the unstirred diffusion region around the bubble, diffusion-limited bubble growth in a tissue of finite volume can be simulated without postulating a boundary layer across which gas flux is discontinuous. However, interactions between two or more bubbles caused by competition for available gas cannot be considered in this model, because the diffusion region has a fixed volume with zero gas flux at its outer boundary. The present work extends the previous model to accommodate interactions among multiple bubbles by allowing the diffusion region volume of each bubble to vary during bubble evolution. For given decompression and tissue volume, bubble growth is sustained only if the bubble number density is below a certain maximum.

  19. Hydrate Formation in Gas-Rich Marine Sediments: A Grain-Scale Model

    NASA Astrophysics Data System (ADS)

    Holtzman, R.; Juanes, R.

    2009-12-01

    We present a grain-scale model of marine sediment, which couples solid- and multiphase fluid-mechanics together with hydrate kinetics. The model is applied to investigate the spatial distribution of the different methane phases - gas and hydrate - within the hydrate stability zone. Sediment samples are generated from three-dimensional packs of spherical grains, mapping the void space into a pore network by tessellation. Gas invasion into the water-saturated sample is simulated by invasion-percolation, coupled with a discrete element method that resolves the grain mechanics. The coupled model accounts for forces exerted by the fluids, including cohesion associated with gas-brine surface tension. Hydrate growth is represented by a hydrate film along the gas-brine interface, which increases sediment cohesion by cementing the grain contacts. Our model of hydrate growth includes the possible rupture of the hydrate layer, which leads to the creation of new gas-water interface. In previous work, we have shown that fine-grained sediments (FGS) exhibit greater tendency to fracture, whereas capillary invasion is the preferred mode of methane gas transport in coarse-grained sediments (CGS). The gas invasion pattern has profound consequences on the hydrate distribution: a larger area-to-volume ratio of the gas cluster leads to a larger drop in gas pressure inside the growing hydrate shell, causing it to rupture. Repeated cycles of imbibition and hydrate growth accompanied by trapping of gas allow us to determine the distribution of hydrate and gas within the sediment as a function of time. Our pore-scale model suggests that, even when film rupture takes place, the conversion of gas to hydrate is slow. This explains two common field observations: the coexistence of gas and hydrate within the hydrate stability zone in CGS, and the high methane fluxes through fracture conduits in FGS. These results demonstrate the importance of accounting for the strong coupling among multiphase

  20. A computer model of gas generation and transport within TRU waste drums

    SciTech Connect

    Smith, F.G. III

    1988-06-01

    A computer model has been developed to predict radiolytic gas generation and transport within Transuranic (TRU) waste drums and surrounding enclosures. Gas generation from the radiolytic decomposition of organic material contaminated with plutonium is modeled and the concentrations of gas throughout the waste drum and enclosures are determined using a diffusional transport model. The model accurately reproduces experimentally measured gas concentrations. With polyethylene waste in unvented drums, the model predicts that the concentration of hydrogen gas can exceed 4 mole percent (lower flammable limit) with only about 5 curies of plutonium. If the drum liner is punctured and an unrestricted 0.75-in. carbon composite filter vent is installed in the drum lid, the plutonium loading can be increased to 240 Ci without generating flammable gas mixtures. Larger diameter filters can be used to increase the curie loading. The model has been used to show that shipments of 1000 Ci of plutonium-238 contaminated waste from Savannah River to the WIPP site are feasible using the TRUPACT shipping container. 10 refs., 17 figs., 6 tabs.

  1. The atomic gas in outer disks in semi-analytic models of galaxy formation†

    NASA Astrophysics Data System (ADS)

    Fu, Jian; Luo, Yu

    2017-03-01

    We use semi-analytic models of galaxy formation L-Galaxies based on ΛCDM cosmology to study the HI gas component in galaxy outskirts. We adopt the radially-resolved version of the models by Fu et al. (2013), which includes both atomic and molecular gas component in interstellar medium. This model has been recently updated by Luo et al. (2016) to include cold gas stripping in the outer disk regions of the satellite galaxies by ram pressure. In our models, we can perfectly reproduce the HI size-mass relation, which is discovered by Broeils & Rhee (1997) and confirmed by many subsequent observations. In our model, the reason for such tight correlation between HI size and mass is atomic-molecular phase conversion in high gas surface density regions while HI ionization in low gas surface density region, which leads to very narrow distribution of HI mean surface density. The models also reproduce the universal exponential HI radial profiles in galaxy outskirts found by Bluedisk (Wang et al. 2013), which arises from cold gas accretion onto the galaxy disks in exponentially profiles.

  2. Cosmological study in loop quantum cosmology through dark energy model

    NASA Astrophysics Data System (ADS)

    Jawad, Abdul; Rani, Shamaila; Salako, Ines G.; Gulshan, Faiza

    The interacting generalized ghost version of pilgrim dark energy (GGPDE) is discussed in the framework of loop quantum cosmology (LQC). We analyze the behavior of cosmological parameters (Hubble, equation of state (EoS), deceleration) and cosmological planes (ωD ‑ ωD‧ and r-s) in the present scenario (ωD represents the EoS parameter and ωD‧ indicates the evolution of the EoS parameter, r,s are statefinder parameters). It is observed that the deceleration parameter corresponds to the accelerated expansion of the universe. The EoS parameter lies in vacuum and phantom regions for all cases of u (pilgrim dark energy (PDE) parameter). The ωD ‑ ωD‧ plane lies in thawing region for all cases of u. The r ‑ s plane corresponds to Λ cold dark matter (CDM) and Chaplygin gas model. We have also mentioned the constraints on calculated cosmological parameters and found that all the trajectories of cosmological parameters and planes show the consistence behavior with the observational schemes.

  3. Gas Chromatographic Verification of a Mathematical Model: Product Distribution Following Methanolysis Reactions.

    ERIC Educational Resources Information Center

    Lam, R. B.; And Others

    1983-01-01

    Investigated application of binomial statistics to equilibrium distribution of ester systems by employing gas chromatography to verify the mathematical model used. Discusses model development and experimental techniques, indicating the model enables a straightforward extension to symmetrical polyfunctional esters and presents a mathematical basis…

  4. Some insights in novel risk modeling of liquefied natural gas carrier maintenance operations

    NASA Astrophysics Data System (ADS)

    Nwaoha, T. C.; John, Andrew

    2016-06-01

    This study discusses the analysis of various modeling approaches and maintenance techniques applicable to the Liquefied Natural Gas (LNG) carrier operations in the maritime environment. Various novel modeling techniques are discussed; including genetic algorithms, fuzzy logic and evidential reasoning. We also identify the usefulness of these algorithms in the LNG carrier industry in the areas of risk assessment and maintenance modeling.

  5. Experimental studies and model analysis of noble gas fractionation in porous media

    USGS Publications Warehouse

    Ding, Xin; Kennedy, B. Mack.; Evans, William C.; Stonestrom, David A.

    2016-01-01

    The noble gases, which are chemically inert under normal terrestrial conditions but vary systematically across a wide range of atomic mass and diffusivity, offer a multicomponent approach to investigating gas dynamics in unsaturated soil horizons, including transfer of gas between saturated zones, unsaturated zones, and the atmosphere. To evaluate the degree to which fractionation of noble gases in the presence of an advective–diffusive flux agrees with existing theory, a simple laboratory sand column experiment was conducted. Pure CO2 was injected at the base of the column, providing a series of constant CO2 fluxes through the column. At five fixed sampling depths within the system, samples were collected for CO2 and noble gas analyses, and ambient pressures were measured. Both the advection–diffusion and dusty gas models were used to simulate the behavior of CO2 and noble gases under the experimental conditions, and the simulations were compared with the measured depth-dependent concentration profiles of the gases. Given the relatively high permeability of the sand column (5 ´ 10−11 m2), Knudsen diffusion terms were small, and both the dusty gas model and the advection–diffusion model accurately predicted the concentration profiles of the CO2 and atmospheric noble gases across a range of CO2 flux from ?700 to 10,000 g m−2 d−1. The agreement between predicted and measured gas concentrations demonstrated that, when applied to natural systems, the multi-component capability provided by the noble gases can be exploited to constrain component and total gas fluxes of non-conserved (CO2) and conserved (noble gas) species or attributes of the soil column relevant to gas transport, such as porosity, tortuosity, and gas saturation.

  6. A view to the future of natural gas and electricity: An integrated modeling approach

    SciTech Connect

    Cole, Wesley J.; Medlock, Kenneth B.; Jani, Aditya

    2016-03-17

    This paper demonstrates the value of integrating two highly spatially resolved models: the Rice World Gas Trade Model (RWGTM) of the natural gas sector and the Regional Energy Deployment System (ReEDS) model of the U.S. electricity sector. The RWGTM passes electricity-sector natural gas prices to the ReEDS model, while the ReEDS model returns electricity-sector natural gas demand to the RWGTM. The two models successfully converge to a solution under reference scenario conditions. We present electricity-sector and natural gas sector evolution using the integrated models for this reference scenario. This paper demonstrates that the integrated models produced similar national-level results as when running in a stand-alone form, but that regional and state-level results can vary considerably. As we highlight, these regional differences have potentially significant implications for electric sector planners especially in the wake of substantive policy changes for the sector (e.g., the Clean Power Plan).

  7. A view to the future of natural gas and electricity: An integrated modeling approach

    DOE PAGES

    Cole, Wesley J.; Medlock, Kenneth B.; Jani, Aditya

    2016-03-17

    This paper demonstrates the value of integrating two highly spatially resolved models: the Rice World Gas Trade Model (RWGTM) of the natural gas sector and the Regional Energy Deployment System (ReEDS) model of the U.S. electricity sector. The RWGTM passes electricity-sector natural gas prices to the ReEDS model, while the ReEDS model returns electricity-sector natural gas demand to the RWGTM. The two models successfully converge to a solution under reference scenario conditions. We present electricity-sector and natural gas sector evolution using the integrated models for this reference scenario. This paper demonstrates that the integrated models produced similar national-level results asmore » when running in a stand-alone form, but that regional and state-level results can vary considerably. As we highlight, these regional differences have potentially significant implications for electric sector planners especially in the wake of substantive policy changes for the sector (e.g., the Clean Power Plan).« less

  8. Gas-kinetic model of heat conduction of heterogeneous substances

    NASA Astrophysics Data System (ADS)

    Gladkov, S. O.

    2008-07-01

    A theoretical approach is proposed for calculating thermal conductivity κ of an arbitrary type of porous structures as a function of porosity ξ, temperature T, density ρ, and a number of other parameters. The general computational algorithm is based on the theory of nonequilibrium processes. Its modification in the language of gas-kinetic approximation makes it possible to derive compact relations for κ and to easily estimate the corresponding dependences. Theoretical formulas are compared to experimental results and their good agreement is demonstrated for a specific example of refractory concrete, which is a very important substance for practical applications.

  9. Modeling the flow regime near the source in underwater gas releases

    NASA Astrophysics Data System (ADS)

    Premathilake, Lakshitha T.; Yapa, Poojitha D.; Nissanka, Indrajith D.; Kumarage, Pubudu

    2016-12-01

    Recent progress in calculating gas bubble sizes in a plume, based on phenomenological approaches using the release conditions is a significant improvement to make the gas plume models self-reliant. Such calculations require details of conditions Near the Source of Plume (NSP); (i.e. the plume/jet velocity and radius near the source), which inspired the present work. Determining NSP conditions for gas plumes are far more complex than that for oil plumes due to the substantial density difference between gas and water. To calculate NSP conditions, modeling the early stage of the plume is important. A novel method of modeling the early stage of an underwater gas release is presented here. Major impact of the present work is to define the correct NSP conditions for underwater gas releases, which is not possible with available methods as those techniques are not based on the physics of flow region near the source of the plume/jet. We introduce super Gaussian profiles to model the density and velocity variations of the early stages of plume, coupled with the laws of fluid mechanics to define profile parameters. This new approach, models the velocity profile variation from near uniform, across the section at the release point to Gaussian some distance away. The comparisons show that experimental data agrees well with the computations.

  10. Chemical models of interstellar gas-grain processes. II - The effect of grain-catalysed methane on gas phase evolution

    NASA Technical Reports Server (NTRS)

    Brown, Paul D.; Charnley, S. B.

    1991-01-01

    The effects on gas phase chemistry which result from the continuous desorption of methane molecules from grain surfaces are studied. Significant and sustained enhancements in the abundances of several complex hydrocarbon molecules are found, in good agreement with their observed values in TMC-1. The overall agreement is, however, just as good for the case of zero CH4 desorption efficiency. It is thus impossible to determine from the models whether or not the grain-surface production of methane is responsible for the observed abundances of some hydrocarbon molecules.

  11. ORAL ISSUE OF THE JOURNAL "USPEKHI FIZICHESKIKH NAUK": Modeling of gas discharge plasma

    NASA Astrophysics Data System (ADS)

    Smirnov, Boris M.

    2009-06-01

    The condition for the self-maintenance of a gas discharge plasma (GDP) is derived from its ionization balance expressed in the Townsend form and may be used as a definition of a gas discharge plasma in its simplest form. The simple example of a gas discharge plasma in the positive column of a cylindrical discharge tube allows demonstrating a wide variety of possible GDP regimes, revealing a contradiction between simple models used to explain gas discharge regimes and the large number of real processes responsible for the self-maintenance of GDP. The variety of GDP processes also results in a stepwise change of plasma parameters and developing some instabilities as the voltage or discharge current is varied. As a consequence, new forms and new applications of gas discharge arise as technology progresses.

  12. The nonlinear model for emergence of stable conditions in gas mixture in force field

    NASA Astrophysics Data System (ADS)

    Kalutskov, Oleg; Uvarova, Liudmila

    2016-06-01

    The case of M-component liquid evaporation from the straight cylindrical capillary into N - component gas mixture in presence of external forces was reviewed. It is assumed that the gas mixture is not ideal. The stable states in gas phase can be formed during the evaporation process for the certain model parameter valuesbecause of the mass transfer initial equationsnonlinearity. The critical concentrations of the resulting gas mixture components (the critical component concentrations at which the stable states occur in mixture) were determined mathematically for the case of single-component fluid evaporation into two-component atmosphere. It was concluded that this equilibrium concentration ratio of the mixture components can be achieved by external force influence on the mass transfer processes. It is one of the ways to create sustainable gas clusters that can be used effectively in modern nanotechnology.

  13. DEVELOPMENT AND VALIDATION OF A MULTIFIELD MODEL OF CHURN-TURBULENT GAS/LIQUID FLOWS

    SciTech Connect

    Elena A. Tselishcheva; Steven P. Antal; Michael Z. Podowski; Donna Post Guillen

    2009-07-01

    The accuracy of numerical predictions for gas/liquid two-phase flows using Computational Multiphase Fluid Dynamics (CMFD) methods strongly depends on the formulation of models governing the interaction between the continuous liquid field and bubbles of different sizes. The purpose of this paper is to develop, test and validate a multifield model of adiabatic gas/liquid flows at intermediate gas concentrations (e.g., churn-turbulent flow regime), in which multiple-size bubbles are divided into a specified number of groups, each representing a prescribed range of sizes. The proposed modeling concept uses transport equations for the continuous liquid field and for each bubble field. The overall model has been implemented in the NPHASE-CMFD computer code. The results of NPHASE-CMFD simulations have been validated against the experimental data from the TOPFLOW test facility. Also, a parametric analysis on the effect of various modeling assumptions has been performed.

  14. Modeling Studies to Constrain Fluid and Gas Migration Associated with Hydraulic Fracturing Operations

    NASA Astrophysics Data System (ADS)

    Rajaram, H.; Birdsell, D.; Lackey, G.; Karra, S.; Viswanathan, H. S.; Dempsey, D.

    2015-12-01

    The dramatic increase in the extraction of unconventional oil and gas resources using horizontal wells and hydraulic fracturing (fracking) technologies has raised concerns about potential environmental impacts. Large volumes of hydraulic fracturing fluids are injected during fracking. Incidents of stray gas occurrence in shallow aquifers overlying shale gas reservoirs have been reported; whether these are in any way related to fracking continues to be debated. Computational models serve as useful tools for evaluating potential environmental impacts. We present modeling studies of hydraulic fracturing fluid and gas migration during the various stages of well operation, production, and subsequent plugging. The fluid migration models account for overpressure in the gas reservoir, density contrast between injected fluids and brine, imbibition into partially saturated shale, and well operations. Our results highlight the importance of representing the different stages of well operation consistently. Most importantly, well suction and imbibition both play a significant role in limiting upward migration of injected fluids, even in the presence of permeable connecting pathways. In an overall assessment, our fluid migration simulations suggest very low risk to groundwater aquifers when the vertical separation from a shale gas reservoir is of the order of 1000' or more. Multi-phase models of gas migration were developed to couple flow and transport in compromised wellbores and subsurface formations. These models are useful for evaluating both short-term and long-term scenarios of stray methane release. We present simulation results to evaluate mechanisms controlling stray gas migration, and explore relationships between bradenhead pressures and the likelihood of methane release and transport.

  15. Study of Gas Flow Characteristics in Tight Porous Media with a Microscale Lattice Boltzmann Model

    NASA Astrophysics Data System (ADS)

    Zhao, Jianlin; Yao, Jun; Zhang, Min; Zhang, Lei; Yang, Yongfei; Sun, Hai; An, Senyou; Li, Aifen

    2016-09-01

    To investigate the gas flow characteristics in tight porous media, a microscale lattice Boltzmann (LB) model with the regularization procedure is firstly adopted to simulate gas flow in three-dimensional (3D) digital rocks. A shale digital rock and a sandstone digital rock are reconstructed to study the effects of pressure, temperature and pore size on microscale gas flow. The simulation results show that because of the microscale effect in tight porous media, the apparent permeability is always higher than the intrinsic permeability, and with the decrease of pressure or pore size, or with the increase of temperature, the difference between apparent permeability and intrinsic permeability increases. In addition, the Knudsen numbers under different conditions are calculated and the results show that gas flow characteristics in the digital rocks under different Knudsen numbers are quite different. With the increase of Knudsen number, gas flow in the digital rocks becomes more uniform and the effect of heterogeneity of the porous media on gas flow decreases. Finally, two commonly used apparent permeability calculation models are evaluated by the simulation results and the Klinkenberg model shows better accuracy. In addition, a better proportionality factor in Klinkenberg model is proposed according to the simulation results.

  16. Study of Gas Flow Characteristics in Tight Porous Media with a Microscale Lattice Boltzmann Model

    PubMed Central

    Zhao, Jianlin; Yao, Jun; Zhang, Min; Zhang, Lei; Yang, Yongfei; Sun, Hai; An, Senyou; Li, Aifen

    2016-01-01

    To investigate the gas flow characteristics in tight porous media, a microscale lattice Boltzmann (LB) model with the regularization procedure is firstly adopted to simulate gas flow in three-dimensional (3D) digital rocks. A shale digital rock and a sandstone digital rock are reconstructed to study the effects of pressure, temperature and pore size on microscale gas flow. The simulation results show that because of the microscale effect in tight porous media, the apparent permeability is always higher than the intrinsic permeability, and with the decrease of pressure or pore size, or with the increase of temperature, the difference between apparent permeability and intrinsic permeability increases. In addition, the Knudsen numbers under different conditions are calculated and the results show that gas flow characteristics in the digital rocks under different Knudsen numbers are quite different. With the increase of Knudsen number, gas flow in the digital rocks becomes more uniform and the effect of heterogeneity of the porous media on gas flow decreases. Finally, two commonly used apparent permeability calculation models are evaluated by the simulation results and the Klinkenberg model shows better accuracy. In addition, a better proportionality factor in Klinkenberg model is proposed according to the simulation results. PMID:27587293

  17. Enhanced Generic Phase-field Model of Irradiation Materials: Fission Gas Bubble Growth Kinetics in Polycrystalline UO2

    SciTech Connect

    Li, Yulan; Hu, Shenyang Y.; Montgomery, Robert O.; Gao, Fei; Sun, Xin

    2012-05-30

    Experiments show that inter-granular and intra-granular gas bubbles have different growth kinetics which results in heterogeneous gas bubble microstructures in irradiated nuclear fuels. A science-based model predicting the heterogeneous microstructure evolution kinetics is desired, which enables one to study the effect of thermodynamic and kinetic properties of the system on gas bubble microstructure evolution kinetics and morphology, improve the understanding of the formation mechanisms of heterogeneous gas bubble microstructure, and provide the microstructure to macroscale approaches to study their impact on thermo-mechanical properties such as thermo-conductivity, gas release, volume swelling, and cracking. In our previous report 'Mesoscale Benchmark Demonstration, Problem 1: Mesoscale Simulations of Intra-granular Fission Gas Bubbles in UO2 under Post-irradiation Thermal Annealing', we developed a phase-field model to simulate the intra-granular gas bubble evolution in a single crystal during post-irradiation thermal annealing. In this work, we enhanced the model by incorporating thermodynamic and kinetic properties at grain boundaries, which can be obtained from atomistic simulations, to simulate fission gas bubble growth kinetics in polycrystalline UO2 fuels. The model takes into account of gas atom and vacancy diffusion, vacancy trapping and emission at defects, gas atom absorption and resolution at gas bubbles, internal pressure in gas bubbles, elastic interaction between defects and gas bubbles, and the difference of thermodynamic and kinetic properties in matrix and grain boundaries. We applied the model to simulate gas atom segregation at grain boundaries and the effect of interfacial energy and gas mobility on gas bubble morphology and growth kinetics in a bi-crystal UO2 during post-irradiation thermal annealing. The preliminary results demonstrate that the model can produce the equilibrium thermodynamic properties and the morphology of gas bubbles at

  18. Relating landfill gas emissions to atmospheric pressure using numerical modelling and state-space analysis.

    PubMed

    Poulsen, Tjalfe G; Christophersen, Mette; Moldrup, Per; Kjeldsen, Peter

    2003-08-01

    Landfill gas (CO2 and CH4) concentrations and fluxes in soil adjacent to an old, unlined Danish municipal landfill measured over a 48-hour period during the passage of a low-pressure weather system were used to identify processes governing gas fluxes and concentrations. Two different approaches were applied: (I) State-space analysis was used to identify relations between gas flux and short-term (hourly) variations in atmospheric pressure. (II) A numerical gas transport model was fitted to the data and used to quantify short-term impacts of variations in atmospheric pressure, volumetric soil-water content, soil gas permeability, soil gas diffusion coefficients, and biological CH4 degradation rate upon landfill gas concentration and fluxes in the soil. Fluxes and concentrations were found to be most sensitive to variations in volumetric soil water content, atmospheric pressure variations and gas permeability whereas variations in CH4 oxidation rate and molecular coefficients had less influence. Fluxes appeared to be most sensitive to atmospheric pressure at intermediate distances from the landfill edge. Also overall CH4 fluxes out of the soil over longer periods (years) were largest during periods with rapidly decreasing atmospheric pressures resulting in emission of large amounts of CH4 during short periods of time. This effect, however, was less significant for the CO2 fluxes.

  19. Educating students and stakeholders about shale gas production using a physical model of hydraulic fracturing

    NASA Astrophysics Data System (ADS)

    Stute, M.; Garten, L.

    2013-12-01

    Natural gas from shale gas deposits in the United States can potentially help reduce the dependency on foreign energy sources, reduce greenhouse gas emissions, and improve economic development in currently depressed regions of the country. However, the hydraulic fracturing process (';fracking') employed to release natural gas from formation such as the Marcellus Shale in New York State and Pennsylvania carries significant environmental risks, in particular for local and regional water resources. The current polarized discussion of the topic needs to be informed by sound data and a better understanding of the technical, scientific, social, and economic aspects of hydrofracking. We developed, built and tested an interactive portable physical model of the gas production by hydrofracking that can be used in class rooms and at public events to visualize the procedures and associated risks including the dynamics of water, gas and fracking fluids. Dyes are used to identify shale, fracking fluids and backflow and can be traced in the adjacent groundwater system. Gas production is visualized by a CO2 producing acid/bicarbonate solution reaction. The tank was shown to considerably improve knowledge of environmental issues related to unconventional gas production by hydrofracking in an advanced undergraduate course.

  20. Microscopic reversibility and macroscopic irreversibility: A lattice gas model

    NASA Astrophysics Data System (ADS)

    Pérez-Cárdenas, Fernando C.; Resca, Lorenzo; Pegg, Ian L.

    2016-09-01

    We present coarse-grained descriptions and computations of the time evolution of a lattice gas system of indistinguishable particles, whose microscopic laws of motion are exactly reversible, in order to investigate how or what kind of macroscopically irreversible behavior may eventually arise. With increasing coarse-graining and number of particles, relative fluctuations of entropy rapidly decrease and apparently irreversible behavior unfolds. Although that behavior becomes typical in those limits and within a certain range, it is never absolutely irreversible for any individual system with specific initial conditions. Irreversible behavior may arise in various ways. We illustrate one possibility by replacing detailed integer occupation numbers at lattice sites with particle probability densities that evolve diffusively.

  1. CELSS experiment model and design concept of gas recycle system

    NASA Technical Reports Server (NTRS)

    Nitta, K.; Oguchi, M.; Kanda, S.

    1986-01-01

    In order to prolong the duration of manned missions around the Earth and to expand the human existing region from the Earth to other planets such as a Lunar Base or a manned Mars flight mission, the controlled ecological life support system (CELSS) becomes an essential factor of the future technology to be developed through utilization of space station. The preliminary system engineering and integration efforts regarding CELSS have been carried out by the Japanese CELSS concept study group for clarifying the feasibility of hardware development for Space station experiments and for getting the time phased mission sets after FY 1992. The results of these studies are briefly summarized and the design and utilization methods of a Gas Recycle System for CELSS experiments are discussed.

  2. Langasite surface acoustic wave gas sensors: modeling and verification

    SciTech Connect

    Peng Zheng,; Greve, D. W.; Oppenheim, I. J.

    2013-03-01

    We report finite element simulations of the effect of conductive sensing layers on the surface wave velocity of langasite substrates. The simulations include both the mechanical and electrical influences of the conducting sensing layer. We show that three-dimensional simulations are necessary because of the out-of-plane displacements of the commonly used (0, 138.5, 26.7) Euler angle. Measurements of the transducer input admittance in reflective delay-line devices yield a value for the electromechanical coupling coefficient that is in good agreement with the three-dimensional simulations on bare langasite substrate. The input admittance measurements also show evidence of excitation of an additional wave mode and excess loss due to the finger resistance. The results of these simulations and measurements will be useful in the design of surface acoustic wave gas sensors.

  3. Solution of an associating lattice-gas model with density anomaly on a Husimi lattice

    NASA Astrophysics Data System (ADS)

    Oliveira, Tiago J.; Stilck, Jürgen F.; Barbosa, Marco Aurélio A.

    2010-11-01

    We study a model of a lattice gas with orientational degrees of freedom which resemble the formation of hydrogen bonds between the molecules. In this model, which is the simplified version of the Henriques-Barbosa model, no distinction is made between donors and acceptors in the bonding arms. We solve the model in the grand-canonical ensemble on a Husimi lattice built with hexagonal plaquettes with a central site. The ground state of the model, which was originally defined on the triangular lattice, is exactly reproduced by the solution on this Husimi lattice. In the phase diagram, one gas and two liquid [high density liquid (HDL) and low density liquid (LDL)] phases are present. All phase transitions (GAS-LDL, GAS-HDL, and LDL-HDL) are discontinuous, and the three phases coexist at a triple point. A line of temperatures of maximum density in the isobars is found in the metastable GAS phase, as well as another line of temperatures of minimum density appears in the LDL phase, part of it in the stable region and another in the metastable region of this phase. These findings are at variance with simulational results for the same model on the triangular lattice, which suggested a phase diagram with two critical points. However, our results show very good quantitative agreement with the simulations, both for the coexistence loci and the densities of particles and of hydrogen bonds. We discuss the comparison of the simulations with our results.

  4. Solution of an associating lattice-gas model with density anomaly on a Husimi lattice.

    PubMed

    Oliveira, Tiago J; Stilck, Jürgen F; Barbosa, Marco Aurélio A

    2010-11-01

    We study a model of a lattice gas with orientational degrees of freedom which resemble the formation of hydrogen bonds between the molecules. In this model, which is the simplified version of the Henriques-Barbosa model, no distinction is made between donors and acceptors in the bonding arms. We solve the model in the grand-canonical ensemble on a Husimi lattice built with hexagonal plaquettes with a central site. The ground state of the model, which was originally defined on the triangular lattice, is exactly reproduced by the solution on this Husimi lattice. In the phase diagram, one gas and two liquid [high density liquid (HDL) and low density liquid (LDL)] phases are present. All phase transitions (GAS-LDL, GAS-HDL, and LDL-HDL) are discontinuous, and the three phases coexist at a triple point. A line of temperatures of maximum density in the isobars is found in the metastable GAS phase, as well as another line of temperatures of minimum density appears in the LDL phase, part of it in the stable region and another in the metastable region of this phase. These findings are at variance with simulational results for the same model on the triangular lattice, which suggested a phase diagram with two critical points. However, our results show very good quantitative agreement with the simulations, both for the coexistence loci and the densities of particles and of hydrogen bonds. We discuss the comparison of the simulations with our results.

  5. Exhaust Gas Modeling Effects on Hypersonic Powered Simulation at Mach 10

    NASA Technical Reports Server (NTRS)

    Tatum, Kenneth E.; Huebner, Lawrence D.

    1995-01-01

    A numerical study was performed to investigate the accuracy and validity of cold-gas simulation of actual hot scramjet exhaust within a Mach 10 free stream over a representative single-stage-to-orbit airbreathing configuration. In particular, exhausts of various noncombusting chemistry models were studied to characterize their effects on the vehicle aftbody performance and the plume flow field definition. Two approximations of the hot scramjet combustion products were utilized to determine the requirement for expensive, multi-species numerical modeling, and to establish a baseline for the validation of cold-gas simulation. Cold-gas simulation at Mach 10 is shown to be a viable technique using an appropriate thermally perfect gas mixture for reproducing hot scramjet exhaust effects.

  6. Analysis of a system modelling the motion of a piston in a viscous gas

    NASA Astrophysics Data System (ADS)

    Maity, Debayan; Takahashi, Takéo; Tucsnak, Marius

    2016-09-01

    We study a free boundary problem modelling the motion of a piston in a viscous gas. The gas-piston system fills a cylinder with fixed extremities, which possibly allow gas from the exterior to penetrate inside the cylinder. The gas is modeled by the 1D compressible Navier-Stokes system and the piston motion is described by the second Newton's law. We prove the existence and uniqueness of global in time strong solutions. The main novelty brought in by our results is that they include the case of nonhomogeneous boundary conditions which, as far as we know, have not been studied in this context. Moreover, even for homogeneous boundary conditions, our results require less regularity of the initial data than those obtained in previous works.

  7. Numerical simulation of high pressure release and dispersion of hydrogen into air with real gas model

    NASA Astrophysics Data System (ADS)

    Khaksarfard, R.; Kameshki, M. R.; Paraschivoiu, M.

    2010-06-01

    Hydrogen is a renewable and clean source of energy, and it is a good replacement for the current fossil fuels. Nevertheless, hydrogen should be stored in high-pressure reservoirs to have sufficient energy. An in-house code is developed to numerically simulate the release of hydrogen from a high-pressure tank into ambient air with more accuracy. Real gas models are used to simulate the flow since high-pressure hydrogen deviates from ideal gas law. Beattie-Bridgeman and Abel Noble equations are applied as real gas equation of state. A transport equation is added to the code to calculate the concentration of the hydrogen-air mixture after release. The uniqueness of the code is to simulate hydrogen in air release with the real gas model. Initial tank pressures of up to 70 MPa are simulated.

  8. Modeling of transport phenomena during gas hydrate decomposition by depressurization and/or thermal stimulation

    NASA Astrophysics Data System (ADS)

    Abendroth*, Sven; Klump, Jens; Thaler, Jan; Schicks, Judith M.

    2013-04-01

    In the context of the German joint project SUGAR (Submarine Gas Hydrate Reservoirs: exploration, extraction and transport) we conducted a series of experiments in the LArge Reservoir Simulator (LARS) at the German Research Centre of Geosciences Potsdam (Beeskow-Strauch et al., this volume). These experiments allow us to investigate the formation and dissociation of hydrates at large scale laboratory conditions. Processes inside LARS are modeled to study the effects of sediment properties as well as physical and chemical processes on parameters such as hydrate dissociation rate and methane production rate. The experimental results from LARS are used to provide details about processes inside the pressure vessel, validate the models through history matching, and feed back into the design of future experiments. In experiments in LARS the amount of methane produced from gas hydrates was much lower than expected. Previously published models predict a methane production rate higher than the observed in experiments and field studies (Uddin and Wright 2005; Uddin et al. 2010; Wright et al. 2011). The authors of the aforementioned studies point out that the current modeling approach overestimates the gas production rate when modeling gas production by depressurization. Uddin and Wright (2005) suggested that trapping of gas bubbles inside the porous medium is responsible for the reduced gas production rate. They point out that this behavior of multi-phase flow is not well explained by a "residual oil" model, but rather resembles a "foamy oil" model. Our study applies Uddin's (2010) "foamy oil" model and combines it with history matches of our experiments in LARS. First results indicate a better agreement between experimental and model results when using the "foamy oil" model instead of conventional models featuring gas flow in water. Further experiments with LARS, including hydrate dissociation by depressurization and thermal stimulation by in-situ combustion will be used to

  9. Simplified gas sensor model based on AlGaN/GaN heterostructure Schottky diode

    NASA Astrophysics Data System (ADS)

    Das, Subhashis; Majumdar, S.; Kumar, R.; Chakraborty, A.; Bag, A.; Biswas, D.

    2015-08-01

    Physics based modeling of AlGaN/GaN heterostructure Schottky diode gas sensor has been investigated for high sensitivity and linearity of the device. Here the surface and heterointerface properties are greatly exploited. The dependence of two dimensional electron gas (2DEG) upon the surface charges is mainly utilized. The simulation of Schottky diode has been done in Technology Computer Aided Design (TCAD) tool and I-V curves are generated, from the I-V curves 76% response has been recorded in presence of 500 ppm gas at a biasing voltage of 0.95 Volt.

  10. Simplified gas sensor model based on AlGaN/GaN heterostructure Schottky diode

    SciTech Connect

    Das, Subhashis Majumdar, S.; Kumar, R.; Bag, A.; Chakraborty, A.; Biswas, D.

    2015-08-28

    Physics based modeling of AlGaN/GaN heterostructure Schottky diode gas sensor has been investigated for high sensitivity and linearity of the device. Here the surface and heterointerface properties are greatly exploited. The dependence of two dimensional electron gas (2DEG) upon the surface charges is mainly utilized. The simulation of Schottky diode has been done in Technology Computer Aided Design (TCAD) tool and I-V curves are generated, from the I-V curves 76% response has been recorded in presence of 500 ppm gas at a biasing voltage of 0.95 Volt.

  11. Non-Volcanic release of CO2 in Italy: quantification, conceptual models and gas hazard

    NASA Astrophysics Data System (ADS)

    Chiodini, G.; Cardellini, C.; Caliro, S.; Avino, R.

    2011-12-01

    Central and South Italy are characterized by the presence of many reservoirs naturally recharged by CO2 of deep provenance. In the western sector, the reservoirs feed hundreds of gas emissions at the surface. Many studies in the last years were devoted to (i) elaborating a map of CO2 Earth degassing of the region; (ii) to asses the gas hazard; (iii) to develop methods suitable for the measurement of the gas fluxes from different types of emissions; (iv) to elaborate the conceptual model of Earth degassing and its relation with the seismic activity of the region and (v) to develop physical numerical models of CO2 air dispersion. The main results obtained are: 1) A general, regional map of CO2 Earth degassing in Central Italy has been elaborated. The total flux of CO2 in the area has been estimated in ~ 10 Mt/a which are released to the atmosphere trough numerous dangerous gas emissions or by degassing spring waters (~ 10 % of the CO2 globally estimated to be released by the Earth trough volcanic activity). 2) An on line, open access, georeferenced database of the main CO2 emissions (~ 250) was settled up (http://googas.ov.ingv.it). CO2 flux > 100 t/d characterise 14% of the degassing sites while CO2 fluxes from 100 t/d to 10 t/d have been estimated for about 35% of the gas emissions. 3) The sites of the gas emissions are not suitable for life: the gas causes many accidents to animals and people. In order to mitigate the gas hazard a specific model of CO2 air dispersion has been developed and applied to the main degassing sites. A relevant application regarded Mefite d'Ansanto, southern Apennines, which is the largest natural emission of low temperature CO2 rich gases, from non-volcanic environment, ever measured in the Earth (˜2000 t/d). Under low wind conditions, the gas flows along a narrow natural channel producing a persistent gas river which has killed over a period of time many people and animals. The application of the physical numerical model allowed us to

  12. General slip regime permeability model for gas flow through porous media

    NASA Astrophysics Data System (ADS)

    Zhou, Bo; Jiang, Peixue; Xu, Ruina; Ouyang, Xiaolong

    2016-07-01

    A theoretical effective gas permeability model was developed for rarefied gas flow in porous media, which holds over the entire slip regime with the permeability derived as a function of the Knudsen number. This general slip regime model (GSR model) is derived from the pore-scale Navier-Stokes equations subject to the first-order wall slip boundary condition using the volume-averaging method. The local closure problem for the volume-averaged equations is studied analytically and numerically using a periodic sphere array geometry. The GSR model includes a rational fraction function of the Knudsen number which leads to a limit effective permeability as the Knudsen number increases. The mechanism for this behavior is the viscous fluid inner friction caused by converging-diverging flow channels in porous media. A linearization of the GSR model leads to the Klinkenberg equation for slightly rarefied gas flows. Finite element simulations show that the Klinkenberg model overestimates the effective permeability by as much as 33% when a flow approaches the transition regime. The GSR model reduces to the unified permeability model [F. Civan, "Effective correlation of apparent gas permeability in tight porous media," Transp. Porous Media 82, 375 (2010)] for the flow in the slip regime and clarifies the physical significance of the empirical parameter b in the unified model.

  13. Investigation on a gas-liquid ejector using three-dimensional CFD model

    NASA Astrophysics Data System (ADS)

    Kang, S. H.; Song, X. G.; Park, Y. C.

    2012-11-01

    This paper is focusing on the numeral study of a gas-liquid ejector used for ballast water treatment. The gasliquid ejector is investigated through steady three-dimensional multiphase CFD analysis with commercial software ANSYS-CFX 13.0. Water as the primary fluid is driven through the driving nozzle and air is ejected into as the second gas instead of the ozone in real application. Several turbulence models such as Standard k-ɛ model, RNG k-ɛ model, SST model and k-ω model, and different mesh size and compared extensively with the experimental results to eliminate the influence of the auxiliary system, turbulence models and mesh generation. The appropriate numerical model in terms of the best combination of turbulence model and mesh size are used in the subsequent research the study the influence of the operating condition such as the driving pressure/velocity and the back pressure of the ejector on its performance. The results provide deep insight on the influence of various factors on the performance of gas-liquid ejector. And the proposed numerical model will be very helpful in the further design optimization of the gas-liquid ejectors.

  14. Using the majorant frequency scheme in the statistical modeling of rarefied gas flows

    NASA Astrophysics Data System (ADS)

    Titov, E. V.; Gimel'Shein, S. F.

    1990-12-01

    The practical possibilities of the majorant frequency scheme are investigated using one-dimensional and plane problems in rarefied gas dynamics. Two versions of the majorant frequency scheme, cellular and noncellular, are shown to provide good results in the statistical modeling of rarefied gas flows. The cellular scheme is preferred for one- and two-dimensional problems with simple geometry, while the noncellular scheme is preferable in the case of two-dimensional problems with complex geometry.

  15. Competition and liberalization in European gas markets: Towards a continental European model

    SciTech Connect

    Stern, J.P.

    1998-06-01

    Many of the long-awaited changes to the European gas market are now imminent. Institutional developments and market forces are combining to produce a transformation. This major study analyzes the developments in a wide range of European countries, including central and eastern Europe. In examining how different institutional traditions and political priorities will affect the gas market, Stern explores the potential for a distinct continental European model of competition and liberalization.

  16. Assessment of thermodynamic models for dense gas dynamics

    NASA Astrophysics Data System (ADS)

    Guardone, A.; Vigevano, L.; Argrow, B. M.

    2004-11-01

    The accuracy of thermodynamic models in the computation of nonclassical gasdynamic phenomena is discussed, to investigate their suitability in connection with the design of experimental apparatuses aimed at the observation of nonclassical wavefields. The Soave-Redlich-Kwong and the Peng-Robinson are preliminarily suggested as alternative thermodynamic models to the Martin-Hou usually considered in nonclassical gasdynamics of fluorinated substances. The validity of these models is assessed by comparisons to reference experimental data for fluorinated R13, R125, C318, FC-72, FC-75, and SF6 and to the Martin-Hou model itself. The three models are found to exhibit a comparable accuracy for reduced volumes ranging from 1.4 to 2.5 and near the critical isotherm, i.e., in the thermodynamic region where heavier fluorinated substances such as PP10 are expected to exhibit nonclassical gasdynamic phenomena. The Soave-Redlich-Kwong and the Peng-Robinson models are then used to supplement previous numerical results for a three-discontinuity nonclassical shock-tube experiment with fluid PP10, which was designed under the Martin-Hou model. Under the initial conditions chosen for the experiment, the three models agree in predicting the formation of a supersonic nonclassical rarefaction wave, with wave Mach number in the range 1.01-1.02, thus providing further confidence on the possibility of experimentally observing nonclassical gasdynamic behavior in fluid PP10.

  17. Modelling gas exchange during platelet storage without agitation.

    PubMed

    Torres, R; Tormey, C A

    2016-11-01

    The aim of this study was to create a model of oxygen distribution within platelet storage bags to evaluate implications of reduced agitation approaches. Based on our model, platelet concentration and surface area most affect internal partial pressure of oxygen, while temperature modifications have least effect, indicating primary potential approaches for optimization of platelet storage with reduced or absent agitation.

  18. MODELING AN IRRITANT GAS PLUME FOR EPIDEMIOLOGIC STUDY

    PubMed Central

    Jani, Dev D.; Reed, David; Feigley, Charles E.

    2015-01-01

    Plume dispersion modeling systems are often used in assessing human exposures to chemical hazards for epidemiologic study. We modeled the 2005 Graniteville, South Carolina, 54,915 kg railcar chlorine release using both the Areal Locations of Hazardous Atmospheres (ALOHA) and Hazard Prediction and Assessment Capability (HPAC) plume modeling systems. We estimated the release rate by an engineering analysis combining semi-quantitative observations and fundamental physical principles. The use of regional meteorological conditions was validated by comparing concentration estimates generated by two source-location weather data sets. The HPAC model estimated a chlorine plume with 20 ppm outdoor concentrations up to 7 km downwind and 0.25 km upwind/downgrade. A comparative analysis of our two models showed that HPAC was the best candidate for use as a model system on which epidemiologic studies could be based after further model validation. Further validation studies are needed before individual exposure estimates can be reliable and the chlorine plume more definitively modeled. PMID:25772143

  19. Elastic-wave velocity in marine sediments with gas hydrates: Effective medium modeling

    USGS Publications Warehouse

    Helgerud, M.B.; Dvorkin, J.; Nur, A.; Sakai, A.; Collett, T.

    1999-01-01

    We offer a first-principle-based effective medium model for elastic-wave velocity in unconsolidated, high porosity, ocean bottom sediments containing gas hydrate. The dry sediment frame elastic constants depend on porosity, elastic moduli of the solid phase, and effective pressure. Elastic moduli of saturated sediment are calculated from those of the dry frame using Gassmann's equation. To model the effect of gas hydrate on sediment elastic moduli we use two separate assumptions: (a) hydrate modifies the pore fluid elastic properties without affecting the frame; (b) hydrate becomes a component of the solid phase, modifying the elasticity of the frame. The goal of the modeling is to predict the amount of hydrate in sediments from sonic or seismic velocity data. We apply the model to sonic and VSP data from ODP Hole 995 and obtain hydrate concentration estimates from assumption (b) consistent with estimates obtained from resistivity, chlorinity and evolved gas data. Copyright 1999 by the American Geophysical Union.

  20. A simple, closed-form, mathematical model for gas exchange in microchannel artificial lungs.

    PubMed

    Potkay, Joseph A

    2013-06-01

    Microfabrication techniques are attractive for constructing artificial lungs due to the ability to create features similar in size to those in the natural lung. However, a simple and intuitive mathematical model capable of accurately predicting the gas exchange performance of microchannel artificial lungs does not currently exist. Such a model is critical to understanding and optimizing these devices. Here, we describe a simple, closed-form mathematical model for gas exchange in microchannel artificial lungs and qualify it through application to experimental data from several research groups. We utilize lumped parameters and several assumptions to obtain a closed-form set of equations that describe gas exchange. This work is intended to augment computational models by providing a more intuitive, albeit potentially less accurate, understanding of the operation and trade-offs inherent in microchannel artificial lung devices.

  1. A combustion model for studying the effects of ideal gas properties on jet noise

    NASA Astrophysics Data System (ADS)

    Jacobs, Jerin; Tinney, Charles

    2016-11-01

    A theoretical combustion model is developed to simulate the influence of ideal gas effects on various aeroacoustic parameters over a range of equivalence ratios. The motivation is to narrow the gap between laboratory and full-scale jet noise testing. The combustion model is used to model propane combustion in air and kerosene combustion in air. Gas properties from the combustion model are compared to real lab data acquired at the National Center for Physical Acoustics at the University of Mississippi as well as outputs from NASA's Chemical Equilibrium Analysis code. Different jet properties are then studied over a range of equivalence ratios and pressure ratios for propane combustion in air, kerosene combustion in air and heated air. The findings reveal negligible differences between the three constituents where the density and sound speed ratios are concerned. Albeit, the area ratio required for perfectly expanded flow is shown to be more sensitive to gas properties, relative to changes in the temperature ratio.

  2. MELTING OF GLASS BATCH: MODEL FOR MULTIPLE OVERLAPPING GAS-EVOLVING REACTIONS

    SciTech Connect

    Pokorny, Richard; Pierce, David A.; Hrma, Pavel R.

    2012-08-10

    In this study, we present a model for the kinetics of multiple overlapping reactions. Mathematical representation of the kinetics of gas-evolving reactions is crucial for the modeling of the feed-to-glass conversion in a waste-glass melter. The model simulates multiple gas-evolving reactions that occur during heating of a high-alumina high-level waste melter feed. To obtain satisfactory kinetic parameters, we employed Kissinger's method combined with least-squares analysis. The power-law kinetics with variable reaction order sufficed for obtaining excellent agreement with measured thermogravimetric analysis data.

  3. MELTING OF GLASS BATCH - MODEL FOR MULTIPLE OVERLAPPING GAS-EVOLVING REACTIONS

    SciTech Connect

    KRUGER AA; PIERCE DA; POKORNY R; HRMA PR

    2012-02-07

    In this study, we present a model for the kinetics of multiple overlapping reactions. Mathematical representation of the kinetics of gas-evolving reactions is crucial for the modeling of the feed-to-glass conversion in a waste-glass melter. The model simulates multiple gas-evolving reactions that occur during heating of a high-alumina high-level waste melter feed. To obtain satisfactory kinetic parameters, we employed Kissinger's method combined with least-squares analysis. The power-law kinetics with variable reaction order sufficed for obtaining excellent agreement with measured thermogravimetric analysis data.

  4. TOWARD A DETERMINISTIC MODEL OF PLANETARY FORMATION. VII. ECCENTRICITY DISTRIBUTION OF GAS GIANTS

    SciTech Connect

    Ida, S.; Lin, D. N. C.

    2013-09-20

    The ubiquity of planets and diversity of planetary systems reveal that planet formation encompasses many complex and competing processes. In this series of papers, we develop and upgrade a population synthesis model as a tool to identify the dominant physical effects and to calibrate the range of physical conditions. Recent planet searches have led to the discovery of many multiple-planet systems. Any theoretical models of their origins must take into account dynamical interactions between emerging protoplanets. Here, we introduce a prescription to approximate the close encounters between multiple planets. We apply this method to simulate the growth, migration, and dynamical interaction of planetary systems. Our models show that in relatively massive disks, several gas giants and rocky/icy planets emerge, migrate, and undergo dynamical instability. Secular perturbation between planets leads to orbital crossings, eccentricity excitation, and planetary ejection. In disks with modest masses, two or less gas giants form with multiple super-Earths. Orbital stability in these systems is generally maintained and they retain the kinematic structure after gas in their natal disks is depleted. These results reproduce the observed planetary mass-eccentricity and semimajor axis-eccentricity correlations. They also suggest that emerging gas giants can scatter residual cores to the outer disk regions. Subsequent in situ gas accretion onto these cores can lead to the formation of distant (∼> 30 AU) gas giants with nearly circular orbits.

  5. New paradigm for simplified combustion modeling of energetic solids: Branched chain gas reaction

    SciTech Connect

    Brewster, M.Q.; Ward, M.J.; Son, S.F.

    1997-09-01

    Two combustion models with simple but rational chemistry are compared: the classical high gas activation energy (E{sub g}/RT {much_gt} 1) Denison-Baum-Williams (DBW) model, and a new low gas activation energy (E{sub g}/RT {much_lt} 1) model recently proposed by Ward, Son, and Brewster (WSB). Both models make the same simplifying assumptions of constant properties, Lewis number unity, single-step, second order gas phase reaction, and single-step, zero order, high activation energy condensed phase decomposition. The only difference is in the gas reaction activation energy E{sub g} which is asymptotically large for DBW and vanishingly small for WSB. For realistic parameters the DBW model predicts a nearly constant temperature sensitivity {sigma}{sub p} and a pressure exponent n approaching 1. The WSB model predicts generally observed values of n = 0.7 to 0.9 and {sigma}{sub p}(T{sub o},P) with the generally observed variations with temperature (increasing) and pressure (decreasing). The WSB temperature profile also matches measured profiles better. Comparisons with experimental data are made using HMX as an illustrative example (for which WSB predictions for {sigma}{sub p}(T{sub o},P) are currently more accurate than even complex chemistry models). WSB has also shown good agreement with NC/NG double base propellant and HNF, suggesting that at the simplest level of combustion modeling, a vanishingly small gas activation energy is more realistic than an asymptotically large one. The authors conclude from this that the important (regression rate determining) gas reaction zone near the surface has more the character of chain branching than thermal decomposition.

  6. Dopant gas effect on silicon chemical vapor depositions: A surface potential model

    NASA Technical Reports Server (NTRS)

    Chang, C. A.

    1975-01-01

    A surface potential model is proposed to consistently explain the known dopant gas effects on silicon chemical vapor deposition. This model predicts that the effects of the same dopant gases on the diamond deposition rate using methane and carbon tetrachloride should be opposite and similar to those of silane, respectively. Available data are in agreement with this prediction.

  7. MATHEMATICAL MODEL FOR GAS/PARTICLE PARTITIONING OF SECONDARY ORGANIC AEROSOLS. (R824970)

    EPA Science Inventory

    A dynamic model is developed for gas-particle absorptive partitioning of semi-volatile organic aerosols. The model is applied to simulate a pair of m-xylene/NOx outdoor smog chamber experiments. In the presence of an inorganic seed aerosol a threshold ...

  8. Kinetic Models for Adiabatic Reversible Expansion of a Monatomic Ideal Gas.

    ERIC Educational Resources Information Center

    Chang, On-Kok

    1983-01-01

    A fixed amount of an ideal gas is confined in an adiabatic cylinder and piston device. The relation between temperature and volume in initial/final phases can be derived from the first law of thermodynamics. However, the relation can also be derived based on kinetic models. Several of these models are discussed. (JN)

  9. Multiple temperature kinetic model and gas-kinetic method for hypersonic non-equilibrium flow computations

    NASA Astrophysics Data System (ADS)

    Xu, Kun; He, Xin; Cai, Chunpei

    2008-07-01

    It is well known that for increasingly rarefied flowfields, the predictions from continuum formulation, such as the Navier-Stokes equations lose accuracy. For the high speed diatomic molecular flow in the transitional regime, the inaccuracies are partially attributed to the single temperature approximations in the Navier-Stokes equations. Here, we propose a continuum multiple temperature model based on the Bhatnagar-Gross-Krook (BGK) equation for the non-equilibrium flow computation. In the current model, the Landau-Teller-Jeans relaxation model for the rotational energy is used to evaluate the energy exchange between the translational and rotational modes. Due to the multiple temperature approximation, the second viscosity coefficient in the Navier-Stokes equations is replaced by the temperature relaxation term. In order to solve the multiple temperature kinetic model, a multiscale gas-kinetic finite volume scheme is proposed, where the gas-kinetic equation is numerically solved for the fluxes to update the macroscopic flow variables inside each control volume. Since the gas-kinetic scheme uses a continuous gas distribution function at a cell interface for the fluxes evaluation, the moments of a gas distribution function can be explicitly obtained for the multiple temperature model. Therefore, the kinetic scheme is much more efficient than the DSMC method, especially in the near continuum flow regime. For the non-equilibrium flow computations, i.e., the nozzle flow and hypersonic rarefied flow over flat plate, the computational results are validated in comparison with experimental measurements and DSMC solutions.

  10. MSW to synthetic natural gas: System modeling and thermodynamics assessment.

    PubMed

    Zhu, Lin; Zhang, Le; Fan, Junming; Jiang, Peng; Li, Luling

    2016-02-01

    To achieve environmental-friendly and energy-efficiency synthetic natural gas (SNG) production routing from municipal solid waste (MSW), a MSW-to-SNG process is unprecedentedly presented in this work, of which the designed configuration is developed and simulated with the aid of Aspen Plus. In addition, sensitivity analyses on major operation parameters, such as equivalence volume ratio (ER), steam-to-MSW mass ratio (S/M) and methanation pressure, are performed with the discussion of process efficiencies and SNG quality. In parallel, the comparison analysis is considered by adopting various MSW material. In this work, the composition of SNG mainly consists of 87.7% CH4, 2.9% CO2, 2.3% H2 and 7.1% N2. And lower heating value (LHV) together with Wobbe index of SNG are separately 31.66MJ/Nm(3) and 45.90MJ/Nm(3). Moreover, the wood-to-SNG, MSW-to-SNG and coal-to-SNG processes are carried out to demonstrate the superiority of the MSW-to-SNG process. The results reveal that the MSW-to-SNG process is a promising option to dispose MSW environmentally, meanwhile converting MSW to the valuable SNG.

  11. Deterministic Stress Modeling of Hot Gas Segregation in a Turbine

    NASA Technical Reports Server (NTRS)

    Busby, Judy; Sondak, Doug; Staubach, Brent; Davis, Roger

    1998-01-01

    Simulation of unsteady viscous turbomachinery flowfields is presently impractical as a design tool due to the long run times required. Designers rely predominantly on steady-state simulations, but these simulations do not account for some of the important unsteady flow physics. Unsteady flow effects can be modeled as source terms in the steady flow equations. These source terms, referred to as Lumped Deterministic Stresses (LDS), can be used to drive steady flow solution procedures to reproduce the time-average of an unsteady flow solution. The goal of this work is to investigate the feasibility of using inviscid lumped deterministic stresses to model unsteady combustion hot streak migration effects on the turbine blade tip and outer air seal heat loads using a steady computational approach. The LDS model is obtained from an unsteady inviscid calculation. The LDS model is then used with a steady viscous computation to simulate the time-averaged viscous solution. Both two-dimensional and three-dimensional applications are examined. The inviscid LDS model produces good results for the two-dimensional case and requires less than 10% of the CPU time of the unsteady viscous run. For the three-dimensional case, the LDS model does a good job of reproducing the time-averaged viscous temperature migration and separation as well as heat load on the outer air seal at a CPU cost that is 25% of that of an unsteady viscous computation.

  12. Geostatistical modeling of the gas emission zone and its in-place gas content for Pittsburgh-seam mines using sequential Gaussian simulation

    USGS Publications Warehouse

    Karacan, C.O.; Olea, R.A.; Goodman, G.

    2012-01-01

    Determination of the size of the gas emission zone, the locations of gas sources within, and especially the amount of gas retained in those zones is one of the most important steps for designing a successful methane control strategy and an efficient ventilation system in longwall coal mining. The formation of the gas emission zone and the potential amount of gas-in-place (GIP) that might be available for migration into a mine are factors of local geology and rock properties that usually show spatial variability in continuity and may also show geometric anisotropy. Geostatistical methods are used here for modeling and prediction of gas amounts and for assessing their associated uncertainty in gas emission zones of longwall mines for methane control.This study used core data obtained from 276 vertical exploration boreholes drilled from the surface to the bottom of the Pittsburgh coal seam in a mining district in the Northern Appalachian basin. After identifying important coal and non-coal layers for the gas emission zone, univariate statistical and semivariogram analyses were conducted for data from different formations to define the distribution and continuity of various attributes. Sequential simulations performed stochastic assessment of these attributes, such as gas content, strata thickness, and strata displacement. These analyses were followed by calculations of gas-in-place and their uncertainties in the Pittsburgh seam caved zone and fractured zone of longwall mines in this mining district. Grid blanking was used to isolate the volume over the actual panels from the entire modeled district and to calculate gas amounts that were directly related to the emissions in longwall mines.Results indicated that gas-in-place in the Pittsburgh seam, in the caved zone and in the fractured zone, as well as displacements in major rock units, showed spatial correlations that could be modeled and estimated using geostatistical methods. This study showed that GIP volumes may

  13. Geostatistical modeling of the gas emission zone and its in-place gas content for Pittsburgh-seam mines using sequential Gaussian simulation

    PubMed Central

    Karacan, C. Özgen; Olea, Ricardo A.; Goodman, Gerrit

    2015-01-01

    Determination of the size of the gas emission zone, the locations of gas sources within, and especially the amount of gas retained in those zones is one of the most important steps for designing a successful methane control strategy and an efficient ventilation system in longwall coal mining. The formation of the gas emission zone and the potential amount of gas-in-place (GIP) that might be available for migration into a mine are factors of local geology and rock properties that usually show spatial variability in continuity and may also show geometric anisotropy. Geostatistical methods are used here for modeling and prediction of gas amounts and for assessing their associated uncertainty in gas emission zones of longwall mines for methane control. This study used core data obtained from 276 vertical exploration boreholes drilled from the surface to the bottom of the Pittsburgh coal seam in a mining district in the Northern Appalachian basin. After identifying important coal and non-coal layers for the gas emission zone, univariate statistical and semivariogram analyses were conducted for data from different formations to define the distribution and continuity of various attributes. Sequential simulations performed stochastic assessment of these attributes, such as gas content, strata thickness, and strata displacement. These analyses were followed by calculations of gas-in-place and their uncertainties in the Pittsburgh seam caved zone and fractured zone of longwall mines in this mining district. Grid blanking was used to isolate the volume over the actual panels from the entire modeled district and to calculate gas amounts that were directly related to the emissions in longwall mines. Results indicated that gas-in-place in the Pittsburgh seam, in the caved zone and in the fractured zone, as well as displacements in major rock units, showed spatial correlations that could be modeled and estimated using geostatistical methods. This study showed that GIP volumes may

  14. Assessment of gas-surface interaction models for computation of rarefied hypersonic flows

    NASA Astrophysics Data System (ADS)

    Padilla, Jose Fernando

    Over the next few decades, spaceflight is expected to become more common through the resurgence of manned space exploration and the rise of commercial manned spaceflight. An essential role for the efficient research and development of suborbital spaceflight is played by computational simulation of rarefied hypersonic flows. Among the few classes of computational approaches for examining rarefied gas dynamics, the most widely used approach, for spatial scales relevant to suborbital spaceflight, is the direct simulation Monte Carlo (DSMC) method. Although the DSMC method has been under development for over forty years, there are still many areas where improvements can be made. One particular area is the associated numerical modeling of interactions between gas molecules and solid surfaces. Gas-surface interactions are not well understood for rarefied hypersonic conditions, although various models have been developed. This thesis ultimately focuses on assessing two common gas-surface interaction models in use with the DSMC method, the Maxwell model and the Cercignani, Lampis and Lord (CLL) model. In the search for a definitive thesis goal and as a consequence of the analysis tools developed for achieving the definitive thesis goal, several aspects of DSMC analysis are examined. Initially, procedures to determine aerodynamic coefficients from DSMC simulations are validated against certain windtunnel test data and an independent DSMC code. Then, sensitivity studies are performed involving aerothermodynamics predictions for the Apollo 6, at the 110 km altitude return trajectory point. This reveals the significance of gas-surface surface interaction models in rarefied hypersonic flows. A review of existing gas-surface interaction models motivates the assessment of the Maxwell and CLL models. The two models are scrutinized with the help of relatively recent windtunnel test measurements and procedures to extract surface scattering distributions. Both models yield similar

  15. A Cloud Microphysics Model for the Gas Giant Planets

    NASA Astrophysics Data System (ADS)

    Palotai, Csaba J.; Le Beau, Raymond P.; Shankar, Ramanakumar; Flom, Abigail; Lashley, Jacob; McCabe, Tyler

    2016-10-01

    Recent studies have significantly increased the quality and the number of observed meteorological features on the jovian planets, revealing banded cloud structures and discrete features. Our current understanding of the formation and decay of those clouds also defines the conceptual modes about the underlying atmospheric dynamics. The full interpretation of the new observational data set and the related theories requires modeling these features in a general circulation model (GCM). Here, we present details of our bulk cloud microphysics model that was designed to simulate clouds in the Explicit Planetary Hybrid-Isentropic Coordinate (EPIC) GCM for the jovian planets. The cloud module includes hydrological cycles for each condensable species that consist of interactive vapor, cloud and precipitation phases and it also accounts for latent heating and cooling throughout the transfer processes (Palotai and Dowling, 2008. Icarus, 194, 303-326). Previously, the self-organizing clouds in our simulations successfully reproduced the vertical and horizontal ammonia cloud structure in the vicinity of Jupiter's Great Red Spot and Oval BA (Palotai et al. 2014, Icarus, 232, 141-156). In our recent work, we extended this model to include water clouds on Jupiter and Saturn, ammonia clouds on Saturn, and methane clouds on Uranus and Neptune. Details of our cloud parameterization scheme, our initial results and their comparison with observations will be shown. The latest version of EPIC model is available as open source software from NASA's PDS Atmospheres Node.

  16. Numerical simulation of gas-dynamic, thermal processes and evaluation of the stress-strain state in the modeling compressor of the gas-distributing unit

    NASA Astrophysics Data System (ADS)

    Shmakov, A. F.; Modorskii, V. Ya.

    2016-10-01

    This paper presents the results of numerical modeling of gas-dynamic processes occurring in the flow path, thermal analysis and evaluation of the stress-strain state of a three-stage design of the compressor gas pumping unit. Physical and mathematical models of the processes developed. Numerical simulation was carried out in the engineering software ANSYS 13. The problem is solved in a coupled statement, in which the results of the gas-dynamic calculation transferred as boundary conditions for the evaluation of the thermal and stress-strain state of a three-stage design of the compressor gas pumping unit. The basic parameters, which affect the stress-strain state of the housing and changing gaps of labyrinth seals in construction. The method of analysis of the pumped gas flow influence on the strain of construction was developed.

  17. Compilation of Gas Intrusion Measurements, Variations, and Consequence Modeling for SPR Caverns

    SciTech Connect

    HINKEBEIN, THOMAS E.

    2003-03-01

    The intrusion of gas into oils stored within the SPR has been examined. When oil is stored in domal salts, gases intrude into the stored oil from the surrounding salt. Aspects of the mechanism of gas intrusion have been examined. In all cases, this gas intrusion results in increases in the oil vapor pressure. Data that have been gathered from 1993 to August 2002 are presented to show the resultant increases in bubble-point pressure on a cavern-by-cavern as well as on a stream basis. The measurement techniques are presented with particular emphasis on the TVP 95. Data analysis methods are presented to show the methods required to obtain recombined cavern oil compositions. Gas-oil ratios are also computed from the data and are presented on a cavern-by-cavern and stream basis. The observed increases in bubble-point pressure and gas-oil ratio are further statistically analyzed to allow data interpretation. Emissions plume modeling is used to determine adherence to state air regulations. Gas intrusion is observed to be variable among the sites and within each dome. Gas intrusions at Bryan Mound and Big Hill have resulted in the largest increases in bubble-point pressure for the Strategic Petroleum Reserve (SPR). The streams at Bayou Choctaw and West Hackberry show minimal bubble-point pressure increases. Emissions plume modeling, using the state mandated ISCST code, of oil storage tanks showed that virtually no gas may be released when H2S standards are considered. DOE plans to scavenge H{sub 2}S to comply with the very tight standards on this gas. With the assumption of scavenging, benzene releases become the next most controlling factor. Model results show that a GOR of 0.6 SCF/BBL may be emissions that are within standards. Employing the benzene gas release standard will significantly improve oil deliverability. New plume modeling using the computational fluid dynamics code, FLUENT, is addressing limitations of the state mandated ISCST model.

  18. Noble gas encapsulation into carbon nanotubes: Predictions from analytical model and DFT studies

    NASA Astrophysics Data System (ADS)

    Balasubramani, Sree Ganesh; Singh, Devendra; Swathi, R. S.

    2014-11-01

    The energetics for the interaction of the noble gas atoms with the carbon nanotubes (CNTs) are investigated using an analytical model and density functional theory calculations. Encapsulation of the noble gas atoms, He, Ne, Ar, Kr, and Xe into CNTs of various chiralities is studied in detail using an analytical model, developed earlier by Hill and co-workers. The constrained motion of the noble gas atoms along the axes of the CNTs as well as the off-axis motion are discussed. Analyses of the forces, interaction energies, acceptance and suction energies for the encapsulation enable us to predict the optimal CNTs that can encapsulate each of the noble gas atoms. We find that CNTs of radii 2.98 - 4.20 Å (chiral indices, (5,4), (6,4), (9,1), (6,6), and (9,3)) can efficiently encapsulate the He, Ne, Ar, Kr, and Xe atoms, respectively. Endohedral adsorption of all the noble gas atoms is preferred over exohedral adsorption on various CNTs. The results obtained using the analytical model are subsequently compared with the calculations performed with the dispersion-including density functional theory at the M06 - 2X level using a triple-zeta basis set and good qualitative agreement is found. The analytical model is however found to be computationally cheap as the equations can be numerically programmed and the results obtained in comparatively very less time.

  19. Noble gas encapsulation into carbon nanotubes: Predictions from analytical model and DFT studies

    SciTech Connect

    Balasubramani, Sree Ganesh; Singh, Devendra; Swathi, R. S.

    2014-11-14

    The energetics for the interaction of the noble gas atoms with the carbon nanotubes (CNTs) are investigated using an analytical model and density functional theory calculations. Encapsulation of the noble gas atoms, He, Ne, Ar, Kr, and Xe into CNTs of various chiralities is studied in detail using an analytical model, developed earlier by Hill and co-workers. The constrained motion of the noble gas atoms along the axes of the CNTs as well as the off-axis motion are discussed. Analyses of the forces, interaction energies, acceptance and suction energies for the encapsulation enable us to predict the optimal CNTs that can encapsulate each of the noble gas atoms. We find that CNTs of radii 2.98 − 4.20 Å (chiral indices, (5,4), (6,4), (9,1), (6,6), and (9,3)) can efficiently encapsulate the He, Ne, Ar, Kr, and Xe atoms, respectively. Endohedral adsorption of all the noble gas atoms is preferred over exohedral adsorption on various CNTs. The results obtained using the analytical model are subsequently compared with the calculations performed with the dispersion-including density functional theory at the M06 − 2X level using a triple-zeta basis set and good qualitative agreement is found. The analytical model is however found to be computationally cheap as the equations can be numerically programmed and the results obtained in comparatively very less time.

  20. Comparisons of the Maxwell and CLL Gas/Surface Interaction Models Using DSMC

    NASA Technical Reports Server (NTRS)

    Hedahl, Marc O.

    1995-01-01

    Two contrasting models of gas-surface interactions are studied using the Direct Simulation Monte Carlo (DSMC) method. The DSMC calculations examine differences in predictions of aerodynamic forces and heat transfer between the Maxwell and Cercignani-Lampis-Lord (CLL) models for flat plate configurations at freestream conditions corresponding to a 140 km orbit around Venus. The size of the flat plate is that of one of the solar panels on the Magellan spacecraft, and the freestream conditions are one of those experienced during aerobraking maneuvers. Results are presented for both a single flat plate and a two-plate configuration as a function of angle of attack and gas-surface accommodation coefficients. The two plate system is not representative of the Magellan geometry, but is studied to explore possible experiments that might be used to differentiate between the two gas surface interaction models.

  1. Motion of the heliospheric termination shock - A gas dynamic model

    NASA Technical Reports Server (NTRS)

    Barnes, Aaron

    1993-01-01

    A simple quantitative model is presented for the heliospheric termination shock's anticipated movement in response to upstream solar wind condition variations, under the assumption that the termination shock is initially a strong gasdynamic shock that is at rest relative to the sun, and that there is a discontinuous increase or decrease in the dynamical pressure upstream of the shock. The model suggests that the termination shock is constantly in motion, and that the mean position of the shock lies near the mean equilibrium position which corresponds to the balance between the mean solar wind dynamical pressure and the mean interstellar pressure.

  2. Cumulus cloud model estimates of trace gas transports

    NASA Technical Reports Server (NTRS)

    Garstang, Michael; Scala, John; Simpson, Joanne; Tao, Wei-Kuo; Thompson, A.; Pickering, K. E.; Harris, R.

    1989-01-01

    Draft structures in convective clouds are examined with reference to the results of the NASA Amazon Boundary Layer Experiments (ABLE IIa and IIb) and calculations based on a multidimensional time dependent dynamic and microphysical numerical cloud model. It is shown that some aspects of the draft structures can be calculated from measurements of the cloud environment. Estimated residence times in the lower regions of the cloud based on surface observations (divergence and vertical velocities) are within the same order of magnitude (about 20 min) as model trajectory estimates.

  3. Modelling trace gas chemistry in the Martian atmosphere

    NASA Astrophysics Data System (ADS)

    Duffy, M. K. D.; Lewis, S. R.; Mason, N. J.

    2012-09-01

    Dust-bourne heterogeneous reactions have been modelled using the UK Mars Global Circulation Model (MGCM) coupled with physics and chemistry schemes used in the Laboratoire de Météorologie Dynamique (LMD) MGCM. The seasonal ozone column abundance has been calculated using a number of different dust scenarios. Reactions involving volcanically interesting species such as water vapour, SO2 and HCl have been included and tracer release experiments have been conducted to mimic short and long-term volcanic outgassing. The effect of these new reactions on the bulk chemistry of the Martian atmosphere has been quantified.

  4. 2D models of gas flow and ice grain acceleration in Enceladus' vents using DSMC methods

    NASA Astrophysics Data System (ADS)

    Tucker, Orenthal J.; Combi, Michael R.; Tenishev, Valeriy M.

    2015-09-01

    The gas distribution of the Enceladus water vapor plume and the terminal speeds of ejected ice grains are physically linked to its subsurface fissures and vents. It is estimated that the gas exits the fissures with speeds of ∼300-1000 m/s, while the micron-sized grains are ejected with speeds comparable to the escape speed (Schmidt, J. et al. [2008]. Nature 451, 685-688). We investigated the effects of isolated axisymmetric vent geometries on subsurface gas distributions, and in turn, the effects of gas drag on grain acceleration. Subsurface gas flows were modeled using a collision-limiter Direct Simulation Monte Carlo (DSMC) technique in order to consider a broad range of flow regimes (Bird, G. [1994]. Molecular Gas Dynamics and the Direct Simulation of Gas Flows. Oxford University Press, Oxford; Titov, E.V. et al. [2008]. J. Propul. Power 24(2), 311-321). The resulting DSMC gas distributions were used to determine the drag force for the integration of ice grain trajectories in a test particle model. Simulations were performed for diffuse flows in wide channels (Reynolds number ∼10-250) and dense flows in narrow tubular channels (Reynolds number ∼106). We compared gas properties like bulk speed and temperature, and the terminal grain speeds obtained at the vent exit with inferred values for the plume from Cassini data. In the simulations of wide fissures with dimensions similar to that of the Tiger Stripes the resulting subsurface gas densities of ∼1014-1020 m-3 were not sufficient to accelerate even micron-sized ice grains to the Enceladus escape speed. In the simulations of narrow tubular vents with radii of ∼10 m, the much denser flows with number densities of 1021-1023 m-3 accelerated micron-sized grains to bulk gas speed of ∼600 m/s. Further investigations are required to understand the complex relationship between the vent geometry, gas source rate and the sizes and speeds of ejected grains.

  5. Hot gas cleanup for molten carbonate fuel cells. A zinc oxide reactor model, Final report

    SciTech Connect

    Steinfeld, G.

    1980-09-16

    Utilization of coal gasifiers to power MCFC requires a cleanup system to remove sulfur and particulates. Of the two near term options available for desulfurization of gasifier effluent, namely low temperature cleanup utilizing absorber/stripper technology, and hot gas cleanup utilizing metal oxides, there is a clear advantage to using hot gas cleanup. Since the MCFC will operate at 1200/sup 0/F, and the gasifier effluent could be between 1200 to 1900/sup 0/F, a hot gas cleanup system will require little or no change in process gas temperature, thereby contributing to a high overall system efficiency. A hot gas cleanup system will consist of FeO for bulk H/sub 2/S removal and ZnO for reduction of H/sub 2/S to sub ppM levels. Hot gas cleanup systems at present are not available commercially, and therefore it is the objective of this project to model the components of the system in order to help bring this technology closer to commercialization, by providing simulated operating characteristics to aid in system design, and system simulations of gasifier/MCFC systems. The modeling of the ZnO reactor is presented.

  6. Distribution of Organophosphate Esters between the Gas and Particle Phase-Model Predictions vs Measured Data.

    PubMed

    Sühring, Roxana; Wolschke, Hendrik; Diamond, Miriam L; Jantunen, Liisa M; Scheringer, Martin

    2016-07-05

    Gas-particle partitioning is one of the key factors that affect the environmental fate of semivolatile organic chemicals. Many organophosphate esters (OPEs) have been reported to primarily partition to particles in the atmosphere. However, because of the wide range of their physicochemical properties, it is unlikely that OPEs are mainly in the particle phase "as a class". We compared gas-particle partitioning predictions for 32 OPEs made by the commonly used OECD POV and LRTP Screening Tool ("the Tool") with the partitioning models of Junge-Pankow (J-P) and Harner-Bidleman (H-B), as well as recently measured data on OPE gas-particle partitioning. The results indicate that half of the tested OPEs partition into the gas phase. Partitioning into the gas phase seems to be determined by an octanol-air partition coefficient (log KOA) < 10 and a subcooled liquid vapor pressure (log PL) > -5 (PL in Pa), as well as the total suspended particle concentration (TSP) in the sampling area. The uncertainty of the physicochemical property data of the OPEs did not change this estimate. Furthermore, the predictions by the Tool, J-P- and H-B-models agreed with recently measured OPE gas-particle partitioning.

  7. Development of a natural Gas Systems Analysis Model (GSAM). Annual report

    SciTech Connect

    Not Available

    1994-02-01

    Lacking a detailed characterization of the resource base and a comprehensive borehole-to-burnertip evaluation model of the North American natural gas system, past R&D, tax and regulatory policies have been formulated without a full understanding of their likely direct and indirect impacts on future gas supply and demand. The recent disappearance of the deliverability surplus, pipeline deregulation, and current policy debates about regulatory initiatives in taxation, environmental compliance and leasing make the need for a comprehensive gas evaluation system critical. Traditional econometric or highly aggregated energy models are increasingly regarded as unable to incorporate available geologic detail and explicit technology performance and costing algorithms necessary to evaluate resource-technology-economic interactions in a market context. The objective of this research is to create a comprehensive, non-proprietary, microcomputer model of the North American natural gas system. GSAM explicitly evaluates the key components of the natural gas system, including resource base, exploration and development, extraction technology performance and costs, transportation and storage and end use. The primary focus is the detailed characterization of the resource base at the reservoir and sub-reservoir level and the impact of alternative extraction technologies on well productivity and economics. GSAM evaluates the complex interactions of current and alternative future technology and policy initiatives in the context of the evolving gas markets. Scheduled for completion in 1995, a prototype is planned for early 1994. ICF Resources reviewed relevant natural gas upstream, downstream and market models to identify appropriate analytic capabilities to incorporate into GSAM. We have reviewed extraction technologies to better characterize performance and costs in terms of GSAM parameters.

  8. Observation and modelling of dissolved gases as indicators for mass transfer during gas sparging in a contaminated aquifer

    NASA Astrophysics Data System (ADS)

    Oswald, S.; Balcke, G.

    2009-04-01

    Degradation of organic contaminants in aquifers is often limited by the availability of electron acceptors, and the attenuation of contaminants could be enhanced by additional supply of oxygen. Gas sparging is a remediation technique that supplies additional oxygen to ground water via injection of air or oxygen gas. For the performance of this method the mass transfer of gases from the gas phase trapped after injection is a key process. Our study investigated kinetic gas-water mass transfer between trapped gas phase in porous media and groundwater by spatially and temporally resolved dissolved gas measurements in an unconfined model aquifer. The aquifer model was built on-site as a 12 m tall underground tank filled with aquifer material and recharged in vertical direction by the local, contaminated groundwater. For the injection of short gas pulses, oxygen and air as injected gas phase were studied in view of interfacial mass transfer, gas transport in the aqueous phase, and accumulation of trapped gas in the porous space. At several locations dissolved nitrogen, methane and oxygen were observed at different stages of gas dissolution. Kinetic gas-water mass transfer in presence of oxygen demanding reactions in the polluted aquifer material and the transport of dissolved gases were simulated numerically for heterogeneous distribution of gas phase as was observed. Partitioning of nitrogen played an important role in the accumulation of trapped gas and contributes additional information on gas transfer processes. While injection of pure oxygen resulted in complete dissolution of trapped gas within a few meters, nitrogen and methane showed distinct patterns of mass transfer into the gas phase and back into aqueous phase. Naturally occurring gases such as methane or nitrogen were demonstrated to be valuable tracers to describe multiple compound gas-water mass transfer and to assist in predicting gas dissolution and oxygen consumption in porous media.

  9. Multi-period natural gas market modeling Applications, stochastic extensions and solution approaches

    NASA Astrophysics Data System (ADS)

    Egging, Rudolf Gerardus

    This dissertation develops deterministic and stochastic multi-period mixed complementarity problems (MCP) for the global natural gas market, as well as solution approaches for large-scale stochastic MCP. The deterministic model is unique in the combination of the level of detail of the actors in the natural gas markets and the transport options, the detailed regional and global coverage, the multi-period approach with endogenous capacity expansions for transportation and storage infrastructure, the seasonal variation in demand and the representation of market power according to Nash-Cournot theory. The model is applied to several scenarios for the natural gas market that cover the formation of a cartel by the members of the Gas Exporting Countries Forum, a low availability of unconventional gas in the United States, and cost reductions in long-distance gas transportation. 1 The results provide insights in how different regions are affected by various developments, in terms of production, consumption, traded volumes, prices and profits of market participants. The stochastic MCP is developed and applied to a global natural gas market problem with four scenarios for a time horizon until 2050 with nineteen regions and containing 78,768 variables. The scenarios vary in the possibility of a gas market cartel formation and varying depletion rates of gas reserves in the major gas importing regions. Outcomes for hedging decisions of market participants show some significant shifts in the timing and location of infrastructure investments, thereby affecting local market situations. A first application of Benders decomposition (BD) is presented to solve a large-scale stochastic MCP for the global gas market with many hundreds of first-stage capacity expansion variables and market players exerting various levels of market power. The largest problem solved successfully using BD contained 47,373 variables of which 763 first-stage variables, however using BD did not result in

  10. HEAVY-DUTY GREENHOUSE GAS EMISSIONS MODEL (GEM)

    EPA Science Inventory

    Class 2b-8 vocational truck manufacturers and Class 7/8 tractor manufacturers would be subject to vehicle-based fuel economy and emission standards that would use a truck simulation model to evaluate the impact of the truck tires and/or tractor cab design on vehicle compliance wi...

  11. Trace Gas/Aerosol Interactions and GMI Modeling Support

    NASA Technical Reports Server (NTRS)

    Penner, Joyce E.; Liu, Xiaohong; Das, Bigyani; Bergmann, Dan; Rodriquez, Jose M.; Strahan, Susan; Wang, Minghuai; Feng, Yan

    2005-01-01

    Current global aerosol models use different physical and chemical schemes and parameters, different meteorological fields, and often different emission sources. Since the physical and chemical parameterization schemes are often tuned to obtain results that are consistent with observations, it is difficult to assess the true uncertainty due to meteorology alone. Under the framework of the NASA global modeling initiative (GMI), the differences and uncertainties in aerosol simulations (for sulfate, organic carbon, black carbon, dust and sea salt) solely due to different meteorological fields are analyzed and quantified. Three meteorological datasets available from the NASA DAO GCM, the GISS-II' GCM, and the NASA finite volume GCM (FVGCM) are used to drive the same aerosol model. The global sulfate and mineral dust burdens with FVGCM fields are 40% and 20% less than those with DAO and GISS fields, respectively due to its heavier rainfall. Meanwhile, the sea salt burden predicted with FVGCM fields is 56% and 43% higher than those with DAO and GISS, respectively, due to its stronger convection especially over the Southern Hemispheric Ocean. Sulfate concentrations at the surface in the Northern Hemisphere extratropics and in the middle to upper troposphere differ by more than a factor of 3 between the three meteorological datasets. The agreement between model calculated and observed aerosol concentrations in the industrial regions (e.g., North America and Europe) is quite similar for all three meteorological datasets. Away from the source regions, however, the comparisons with observations differ greatly for DAO, FVGCM and GISS, and the performance of the model using different datasets varies largely depending on sites and species. Global annual average aerosol optical depth at 550 nm is 0.120-0.131 for the three meteorological datasets.

  12. Comparisons of the Maxwell and CLL gas/surface interaction models using DSMC

    NASA Technical Reports Server (NTRS)

    Hedahl, Marc O.; Wilmoth, Richard G.

    1995-01-01

    The behavior of two different models of gas-surface interactions is studied using the Direct Simulation Monte Carlo (DSMC) method. The DSMC calculations examine differences in predictions of aerodynamic forces and heat transfer between the Maxwell and the Cercignani-Lampis-Lord (CLL) models for flat plate configurations at freestream conditions corresponding to a 140 km orbit around Venus. The size of the flat plate represents one of the solar panels on the Magellan spacecraft, and the freestream conditions correspond to those experienced during aerobraking maneuvers. Results are presented for both a single flat plate and a two-plate configuration as a function of angle of attack and gas-surface accommodation coefficients. The two-plate system is not representative of the Magellan geometry but is studied to explore possible experiments that might be used to differentiate between the two gas-surface interaction models. The Maxwell and CLL models produce qualitatively similar results for the aerodynamic forces and heat transfer on a single flat plate. However, the flow fields produced with the two models are qualitatively different for both the single-plate and two-plate calculations. These differences in the flowfield lead to predictions of the angle of attack for maximum heat transfer in a two plate configuration that are distinctly different for the two gas-surface interactions models.

  13. Partially invariant solutions of models obtained from the Nambu-Goto action

    NASA Astrophysics Data System (ADS)

    Grundland, A. M.; Hariton, A. J.

    2004-08-01

    The concept of partially invariant solutions is discussed in the framework of the group analysis of models derived from the Nambu-Goto action. In particular, we consider the nonrelativistic Chaplygin gas and the relativistic Born-Infeld theory for a scalar field. Using a general systematic approach based on subgroup classification methods, nontrivial partially invariant solutions with defect structure δ=1 are constructed. For this purpose, a classification of the subgroups of the Lie point symmetry group, which have generic orbits of dimension 2, has been performed. These subgroups allow us to introduce the corresponding symmetry variables and next to reduce the initial equations to different nonequivalent classes of partial differential equations and ordinary differential equations. The latter can be transformed to standard form and, in some cases, solved in terms of elementary and Jacobi elliptic functions. This results in a large number of new partially invariant solutions, which are determined to be either reducible or irreducible with respect to the symmetry group. Some physical interpretation of the results in the area of fluid dynamics and field theory are discussed. The solutions represent traveling and centered waves, algebraic solitons, kinks, bumps, cnoidal and snoidal waves.

  14. Probing the Physical Conditions of Dense Molecular Gas in ULIRGs with LVG modelling

    NASA Astrophysics Data System (ADS)

    Leonidaki, Ioanna; Zhang, Zhi-Yu; Greve, Thomas; Xilouris, Manolis

    2015-08-01

    The gas-rich content of Ultra Luminous Infrared Galaxies (ULIRGs) constitutes a great laboratory in characterising the physical processes occuring in molecular gas and hence probing star formation properties. In particular, molecules with large dipole moments such as CS, HCN, HCO+, which are the fuel of star formation, can reveal the physical/excitation conditions of molecular gas phases in galaxies. For that reason, we compiled the aforementioned dense gas tracers in a sample of local (U)LIRGs in order to investigate the physical properties of the gas while at the same time put constrains on their excitation conditions. The sample in use consists of 26 galaxies all observed within the framework of the Herschel Comprehensive (U)LIRG Emission Survey (HerCULES). For all galaxies, we compiled our ground-based spectral line observations as well as all available data from the literature. Using Large Velocity Gradient (LVG) radiative transfer models in these spectral lines and in a wide parameter space [n(H2), Tkin, Nmol], and combining multiple molecules and multiple excitation components, it is possible to break the degeneracy between different parameters and to probe molecular gas physical conditions ranging from the cold and low-density average states in giant molecular clouds all the way up to the state of the gas found only near their star-forming regions. We then analyse the best LVG solution ranges to match the observed SLEDs (using more than one excitation components where necessary) in order to disentangle different molecular gas phases and possibly different molecular gas heating mechanisms.

  15. THE IMPACT OF MOLECULAR GAS ON MASS MODELS OF NEARBY GALAXIES

    SciTech Connect

    Frank, B. S.; Blok, W. J. G. de; Walter, F.; Leroy, A.; Carignan, C.

    2016-04-15

    We present CO velocity fields and rotation curves for a sample of nearby galaxies, based on data from HERACLES. We combine our data with THINGS, SINGS, and KINGFISH results to provide a comprehensive sample of mass models of disk galaxies inclusive of molecular gas. We compare the kinematics of the molecular (CO from HERACLES) and atomic (H i from THINGS) gas distributions to determine the extent to which CO may be used to probe the dynamics in the inner part of galaxies. In general, we find good agreement between the CO and H i kinematics, with small differences in the inner part of some galaxies. We add the contribution of the molecular gas to the mass models in our galaxies by using two different conversion factors α{sub CO} to convert CO luminosity to molecular gas mass surface density—the constant Milky Way value and the radially varying profiles determined in recent work based on THINGS, HERACLES, and KINGFISH data. We study the relative effect that the addition of the molecular gas has on the halo rotation curves for Navarro–Frenk–White and the observationally motivated pseudo-isothermal halos. The contribution of the molecular gas varies for galaxies in our sample—for those galaxies where there is a substantial molecular gas content, using different values of α{sub CO} can result in significant differences to the relative contribution of the molecular gas and hence the shape of the dark matter halo rotation curves in the central regions of galaxies.

  16. PARTICLE TRANSPORTATION AND DEPOSITION IN HOT GAS FILTER VESSELS - A COMPUTATIONAL AND EXPERIMENTAL MODELING APPROACH

    SciTech Connect

    Goodarz Ahmadi

    2002-07-01

    In this project, a computational modeling approach for analyzing flow and ash transport and deposition in filter vessels was developed. An Eulerian-Lagrangian formulation for studying hot-gas filtration process was established. The approach uses an Eulerian analysis of gas flows in the filter vessel, and makes use of the Lagrangian trajectory analysis for the particle transport and deposition. Particular attention was given to the Siemens-Westinghouse filter vessel at Power System Development Facility in Wilsonville in Alabama. Details of hot-gas flow in this tangential flow filter vessel are evaluated. The simulation results show that the rapidly rotation flow in the spacing between the shroud and the vessel refractory acts as cyclone that leads to the removal of a large fraction of the larger particles from the gas stream. Several alternate designs for the filter vessel are considered. These include a vessel with a short shroud, a filter vessel with no shroud and a vessel with a deflector plate. The hot-gas flow and particle transport and deposition in various vessels are evaluated. The deposition patterns in various vessels are compared. It is shown that certain filter vessel designs allow for the large particles to remain suspended in the gas stream and to deposit on the filters. The presence of the larger particles in the filter cake leads to lower mechanical strength thus allowing for the back-pulse process to more easily remove the filter cake. A laboratory-scale filter vessel for testing the cold flow condition was designed and fabricated. A laser-based flow visualization technique is used and the gas flow condition in the laboratory-scale vessel was experimental studied. A computer model for the experimental vessel was also developed and the gas flow and particle transport patterns are evaluated.

  17. Particle-in-cell modeling of gas-confined barrier discharge

    NASA Astrophysics Data System (ADS)

    Levko, Dmitry; Raja, Laxminarayan L.

    2016-04-01

    Gas-confined barrier discharge is studied using the one-dimensional Particle-in-Cell Monte Carlo Collisions model for the conditions reported by Guerra-Garcia and Martinez-Sanchez [Appl. Phys. Lett. 106, 041601 (2015)]. Depending on the applied voltage, two modes of discharge are observed. In the first mode, the discharge develops in the entire interelectrode gap. In the second mode, the discharge is ignited and develops only in the gas layer having smaller breakdown voltage. The one-dimensional model shows that for the conditions considered, there is no streamer stage of breakdown as is typical for a traditional dielectric barrier discharge.

  18. A Unified Theory of Non-Ideal Gas Lattice Boltzmann Models

    NASA Technical Reports Server (NTRS)

    Luo, Li-Shi

    1998-01-01

    A non-ideal gas lattice Boltzmann model is directly derived, in an a priori fashion, from the Enskog equation for dense gases. The model is rigorously obtained by a systematic procedure to discretize the Enskog equation (in the presence of an external force) in both phase space and time. The lattice Boltzmann model derived here is thermodynamically consistent and is free of the defects which exist in previous lattice Boltzmann models for non-ideal gases. The existing lattice Boltzmann models for non-ideal gases are analyzed and compared with the model derived here.

  19. Preliminary Results from Electric Arc Furnace Off-Gas Enthalpy Modeling

    SciTech Connect

    Nimbalkar, Sachin U; Thekdi, Arvind; Keiser, James R; Storey, John Morse

    2015-01-01

    This article describes electric arc furnace (EAF) off-gas enthalpy models developed at Oak Ridge National Laboratory (ORNL) to calculate overall heat availability (sensible and chemical enthalpy) and recoverable heat values (steam or power generation potential) for existing EAF operations and to test ORNL s new EAF waste heat recovery (WHR) concepts. ORNL s new EAF WHR concepts are: Regenerative Drop-out Box System and Fluidized Bed System. The two EAF off-gas enthalpy models described in this paper are: 1.Overall Waste Heat Recovery Model that calculates total heat availability in off-gases of existing EAF operations 2.Regenerative Drop-out Box System Model in which hot EAF off-gases alternately pass through one of two refractory heat sinks that store heat and then transfer it to another gaseous medium These models calculate the sensible and chemical enthalpy of EAF off-gases based on the off-gas chemical composition, temperature, and mass flow rate during tap to tap time, and variations in those parameters in terms of actual values over time. The models provide heat transfer analysis for the aforementioned concepts to confirm the overall system and major component sizing (preliminary) to assess the practicality of the systems. Real-time EAF off-gas composition (e.g., CO, CO2, H2, and H2O), volume flow, and temperature data from one EAF operation was used to test the validity and accuracy of the modeling work. The EAF off-gas data was used to calculate the sensible and chemical enthalpy of the EAF off-gases to generate steam and power. The article provides detailed results from the modeling work that are important to the success of ORNL s EAF WHR project. The EAF WHR project aims to develop and test new concepts and materials that allow cost-effective recovery of sensible and chemical heat from high-temperature gases discharged from EAFs.

  20. Effects of Turbulence Model on Prediction of Hot-Gas Lateral Jet Interaction in a Supersonic Crossflow

    DTIC Science & Technology

    2015-07-01

    ARL-TR-7332 ● JULY 2015 US Army Research Laboratory Effects of Turbulence Model on Prediction of Hot -Gas Lateral Jet Interaction...Effects of Turbulence Model on Prediction of Hot -Gas Lateral Jet Interaction in a Supersonic Crossflow by James DeSpirito Weapons and Materials...December 2014 4. TITLE AND SUBTITLE Effects of Turbulence Model on Prediction of Hot -Gas Lateral Jet Interaction in a Supersonic Crossflow 5a

  1. Determination and evaluation of gas holdup time with the quadratic equation model and comparison with nonlinear equation models for isothermal gas chromatography

    PubMed Central

    Wu, Liejun; Chen, Maoxue; Chen, Yongli; Li, Qing X.

    2013-01-01

    Gas holdup time (tM) is a basic parameter in isothermal gas chromatography (GC). Determination and evaluation of tM and retention behaviors of n-alkanes under isothermal GC conditions have been extensively studied since the 1950s, but still remains unresolved. The difference equation (DE) model [J. Chromatogr. A 1260:215–223] reveals retention behaviors of n-alkanes excluding tM, while the quadratic equation (QE) model [J. Chromatogr. A 1260:224–231] including tM is suitable for applications. In the present study, tM values were calculated with the QE model, which is referred to as tMT, evaluated and compared with other three typical nonlinear models. The QE model gives an accurate estimation of tM in isothermal GC. The tMT values are highly accurate, stable, and easy to calculate and use. There is only one tMT value at each GC condition. The proper classification of tM values can clarify their disagreement and facilitate GC retention data standardization for which tMT values are promising reference tM values. PMID:23726077

  2. Estimating Policy-Driven Greenhouse Gas Emissions Trajectories in California: The California Greenhouse Gas Inventory Spreadsheet (GHGIS) Model

    SciTech Connect

    Greenblatt, Jeffery B.

    2013-10-10

    A California Greenhouse Gas Inventory Spreadsheet (GHGIS) model was developed to explore the impact of combinations of state policies on state greenhouse gas (GHG) and regional criteria pollutant emissions. The model included representations of all GHG- emitting sectors of the California economy (including those outside the energy sector, such as high global warming potential gases, waste treatment, agriculture and forestry) in varying degrees of detail, and was carefully calibrated using available data and projections from multiple state agencies and other sources. Starting from basic drivers such as population, numbers of households, gross state product, numbers of vehicles, etc., the model calculated energy demands by type (various types of liquid and gaseous hydrocarbon fuels, electricity and hydrogen), and finally calculated emissions of GHGs and three criteria pollutants: reactive organic gases (ROG), nitrogen oxides (NOx), and fine (2.5 ?m) particulate matter (PM2.5). Calculations were generally statewide, but in some sectors, criteria pollutants were also calculated for two regional air basins: the South Coast Air Basin (SCAB) and the San Joaquin Valley (SJV). Three scenarios were developed that attempt to model: (1) all committed policies, (2) additional, uncommitted policy targets and (3) potential technology and market futures. Each scenario received extensive input from state energy planning agencies, in particular the California Air Resources Board. Results indicate that all three scenarios are able to meet the 2020 statewide GHG targets, and by 2030, statewide GHG emissions range from between 208 and 396 MtCO2/yr. However, none of the scenarios are able to meet the 2050 GHG target of 85 MtCO2/yr, with emissions ranging from 188 to 444 MtCO2/yr, so additional policies will need to be developed for California to meet this stringent future target. A full sensitivity study of major scenario assumptions was also performed. In terms of criteria pollutants

  3. Modeling studies of gas movement and moisture migration at Yucca Mountain, Nevada

    SciTech Connect

    Tsang, Y.W.; Pruess, K.

    1991-06-01

    Modeling studies on moisture redistribution processes that are mediated by gas phase flow and diffusion have been carried out. The problem addressed is the effect of a lowered humidity of the soil gas at the land surface on moisture removal from Yucca Mountain, the potential site for a high-level nuclear waste repository. At the land surface, humid formation gas contacts much drier atmospheric air. Near this contact, the humidity of the soil gas may be considerably lower than at greater depth, where the authors expect equilibrium with the liquid phase and close to 100% humidity. The lower relative humidity of the soil gas may be modeled by imposing, at the land surface, an additional negative capillary suction corresponding to vapor pressure lowering according to Kelvin`s Equation, thus providing a driving force for the upward movement of moisture in both the vapor and liquid phases. Sensitivity studies show that moisture removal from Yucca Mountain arising from the lowered-relative-humidity boundary condition is controlled by vapor diffusion. There is much experimental evidence in the soil literature that diffusion of vapor is enhanced due to pore-level phase change effects by a few orders of magnitude. Modeling results presented here will account for this enhancement in vapor diffusion.

  4. A Pore-Centric Model for Combined Shrinkage and Gas Porosity in Alloy Solidification

    NASA Astrophysics Data System (ADS)

    Khalajzadeh, Vahid; Carlson, Kent D.; Backman, Daniel G.; Beckermann, Christoph

    2017-04-01

    A unified model has been developed for combined gas- and shrinkage-induced pore formation during solidification of metal alloys. The model is based on a pore-centric approach, in which the temporal evolution of the pore radius is calculated as a function of cooling rate, thermal gradient, gas diffusion, and shrinkage. It accounts for the effect of porosity formation on the liquid velocity within the mushy zone. Simulations for an aluminum alloy show that the porosity transitions smoothly from shrinkage-induced to gas-induced as the Niyama value is increased. A Blake (cavitation) instability is observed to occur when the porosity is both gas- and shrinkage-driven. A revised dimensionless Niyama curve for pure shrinkage is presented. The experimentally observed gas porosity trend that the pore volume decreases with increasing cooling rate is well predicted. The pore-centric formulation allows the present model to be solved locally, at any point in a casting, during a regular casting simulation.

  5. A model for the interaction between stars and gas in the interstellar medium

    NASA Astrophysics Data System (ADS)

    Chiang, Wei-Hwan; Bregman, Joel N.

    1988-05-01

    A model for the ISM is considered in which stars lose mass and heat the gas while the gas can form into stars. Three scale-free models are calculated, and in each case the star formation instability leads to a network of dense filaments that surround hotter, more rarefied gas, all of which are close to pressure equilibrium. Depending upon the star formation and cooling laws adopted, the stars are located either in the middle of a bubble or along the inside edge of a dense filament. When a model for the ISM with a cooling curve appropriate for gas of cosmic abundance and a star formation rate proportional to the local gas density is used, the star formation instability is found to grow at temperatures below about 10,000 K. A network structure develops in which most of the mass is in neutral filaments. Newly formed stars lie adjacent to the filaments and create pressure forces that lead to filament motion.

  6. A Pore-Centric Model for Combined Shrinkage and Gas Porosity in Alloy Solidification

    NASA Astrophysics Data System (ADS)

    Khalajzadeh, Vahid; Carlson, Kent D.; Backman, Daniel G.; Beckermann, Christoph

    2017-01-01

    A unified model has been developed for combined gas- and shrinkage-induced pore formation during solidification of metal alloys. The model is based on a pore-centric approach, in which the temporal evolution of the pore radius is calculated as a function of cooling rate, thermal gradient, gas diffusion, and shrinkage. It accounts for the effect of porosity formation on the liquid velocity within the mushy zone. Simulations for an aluminum alloy show that the porosity transitions smoothly from shrinkage-induced to gas-induced as the Niyama value is increased. A Blake (cavitation) instability is observed to occur when the porosity is both gas- and shrinkage-driven. A revised dimensionless Niyama curve for pure shrinkage is presented. The experimentally observed gas porosity trend that the pore volume decreases with increasing cooling rate is well predicted. The pore-centric formulation allows the present model to be solved locally, at any point in a casting, during a regular casting simulation.

  7. Unitized Regenerative Fuel Cell System Gas Dryer/Humidifier Analytical Model Development

    NASA Technical Reports Server (NTRS)

    Burke, Kenneth A.; Jakupca, Ian

    2004-01-01

    A lightweight Unitized Regenerative Fuel Cell (URFC) Energy Storage System concept is being developed at the NASA Glenn Research Center (GRC). This Unitized Regenerative Fuel Cell System (URFCS) is unique in that it uses Regenerative Gas Dryers/Humidifiers (RGD/H) that are mounted on the surface of the gas storage tanks that act as the radiators for thermal control of the Unitized Regenerative Fuel Cell System (URFCS). As the gas storage tanks cool down during URFCS charging the RGD/H dry the hydrogen and oxygen gases produced by electrolysis. As the gas storage tanks heat up during URFCS discharging, the RGD/H humidify the hydrogen and oxygen gases used by the fuel cell. An analytical model was developed to simulate the URFCS RGD/H. The model is in the form of a Microsoft (registered trademark of Microsoft Corporation) Excel worksheet that allows the investigation of the RGD/H performance. Finite Element Analysis (FEA) modeling of the RGD/H and the gas storage tank wall was also done to analyze spatial temperature distribution within the RGD/H and the localized tank wall. Test results obtained from the testing of the RGD/H in a thermal vacuum environment were used to corroborate the analyses.

  8. A model for the interaction between stars and gas in the interstellar medium

    NASA Technical Reports Server (NTRS)

    Chiang, Wei-Hwan; Bregman, Joel N.

    1988-01-01

    A model for the ISM is considered in which stars lose mass and heat the gas while the gas can form into stars. Three scale-free models are calculated, and in each case the star formation instability leads to a network of dense filaments that surround hotter, more rarefied gas, all of which are close to pressure equilibrium. Depending upon the star formation and cooling laws adopted, the stars are located either in the middle of a bubble or along the inside edge of a dense filament. When a model for the ISM with a cooling curve appropriate for gas of cosmic abundance and a star formation rate proportional to the local gas density is used, the star formation instability is found to grow at temperatures below about 10,000 K. A network structure develops in which most of the mass is in neutral filaments. Newly formed stars lie adjacent to the filaments and create pressure forces that lead to filament motion.

  9. A computational model of insect discontinuous gas exchange: A two-sensor, control systems approach.

    PubMed

    Grieshaber, Beverley J; Terblanche, John S

    2015-06-07

    The insect gas exchange system is characterised by branching air-filled tubes (tracheae/tracheoles) and valve-like structures in their outer integument (spiracles) which allow for a periodic gas exchange pattern known as the discontinuous gas exchange cycle (DGC). The DGC facilitates the temporal decoupling of whole animal gas exchange from cellular respiration rates and may confer several physiological benefits, which are nevertheless highly controversial (primarily reduction of cellular oxidative damage and/or respiratory water saving). The intrinsic and extrinsic factors influencing DGCs are the focus of extensive ongoing research and little consensus has been reached on the evolutionary genesis or mechanistic costs and benefits of the pattern. Despite several hypotheses and much experimental and evolutionary biology research, a mechanistic physical model, which captures various key elements of the DGC pattern, is currently lacking. Here, we present a biologically realistic computational, two-sensor DGC model (pH/carbon dioxide and oxygen setpoints) for an Orthopteran gas exchange system, and show computationally for the first time that a control system of two interacting feedback loops is capable of generating a full DGC pattern with outputs which are physiologically realistic, quantitatively matching experimental results found in this taxonomic model elsewhere. A finite-element mathematical approach is employed and various trigger sets are considered. Parameter sensitivity analyses suggest that various aspects of insect DGC are adequately captured in this model. In particular, with physiologically relevant input parameters, the full DGC pattern is induced; and the phase durations, endotracheal carbon dioxide partial pressure ranges, and pH fluctuations which arise are physically realistic. The model results support the emergent property hypothesis for the existence of DGC, and indicate that asymmetric loading and off-loading (hysteresis) in one of the sensor

  10. Resource planning for gas utilities: Using a model to analyze pivotal issues

    SciTech Connect

    Busch, J.F.; Comnes, G.A.

    1995-11-01

    With the advent of wellhead price decontrols that began in the late 1970s and the development of open access pipelines in the 1980s and 90s, gas local distribution companies (LDCs) now have increased responsibility for their gas supplies and face an increasingly complex array of supply and capacity choices. Heretofore this responsibility had been share with the interstate pipelines that provide bundled firm gas supplies. Moreover, gas supply an deliverability (capacity) options have multiplied as the pipeline network becomes increasing interconnected and as new storage projects are developed. There is now a fully-functioning financial market for commodity price hedging instruments and, on interstate Pipelines, secondary market (called capacity release) now exists. As a result of these changes in the natural gas industry, interest in resource planning and computer modeling tools for LDCs is increasing. Although in some ways the planning time horizon has become shorter for the gas LDC, the responsibility conferred to the LDC and complexity of the planning problem has increased. We examine current gas resource planning issues in the wake of the Federal Energy Regulatory Commission`s (FERC) Order 636. Our goal is twofold: (1) to illustrate the types of resource planning methods and models used in the industry and (2) to illustrate some of the key tradeoffs among types of resources, reliability, and system costs. To assist us, we utilize a commercially-available dispatch and resource planning model and examine four types of resource planning problems: the evaluation of new storage resources, the evaluation of buyback contracts, the computation of avoided costs, and the optimal tradeoff between reliability and system costs. To make the illustration of methods meaningful yet tractable, we developed a prototype LDC and used it for the majority of our analysis.

  11. Marine Gas Turbine Modeling for Modern Control Design.

    DTIC Science & Technology

    1986-06-01

    MOZO E-4ZW𔃺a" ~ C E- 0F.ZwEi.E- -inn4= 974WE.)O -4L c E-4 Ha W: WZ ( 0 ~ ) 0 "a . 4W< W .wz z 00 w 4 *0 = 0 ::) O=W( 0 0 C.M 0 =0UU n.X0 - Z -O)0 uo...Models/e/Dian criteria, AlfAVL-TR- 7B--74_,1976.6q 2. Merril,W., Lehtinen, B., Zeller J. , TheRole of Moo Theory in the Des3n of Coro fOrft Journal o

  12. A soliton gas model for astrophysical magnetized plasma turbulence

    NASA Astrophysics Data System (ADS)

    Spangler, S. R.; Sheerin, J. P.

    1982-06-01

    Plasma turbulence is considered as an ensemble of solitons. The derivation of the Alfven soliton by Spangler and Sheering (1981) is reviewed, and expressions are derived for the magnetic irregularity spectrum and the relationship between the magnetic and density irregularity power spectra. A derived expression also provides the answer to the question of the correlation between magnetic field and density enhancements. The properties of the turbulence model are compared with observations of plasma turbulence in the solar wind, and are found to reasonably account for them.

  13. Critical lines for a generalized three state binary gas-liquid lattice model

    NASA Astrophysics Data System (ADS)

    Meijer, Paul H. E.; Keskin, Mustafa; Pegg, Ian L.

    1988-02-01

    The critical properties of several compressible binary gas-liquid models are described: the three state lattice gas, the Tompa model for polymer solutions, the van der Waals equation for binary mixtures, and an intermediate model. The critical lines are expressed as functions of x1 and x2, the density of type 1 molecules and the density of type 2 molecules, instead of using the pressure and temperature; representative figures are given for each of the models. The general conditions for criticality, stability, and tricriticality are given as functions of x1 and x2 through the intermediary of the spinodal temperature function T(x1,x2). A closed form solution is given for the Berthelot case (geometrical-mean combining rule). All the models exhibit a characteristic intersection of two critical lines, and the behavior near this point is investigated. In the van der Waals case we confirm the coordinates given by van Laar.

  14. Validation of hydrogen gas stratification and mixing models

    SciTech Connect

    Wu, Hsingtzu; Zhao, Haihua

    2015-05-26

    Two validation benchmarks confirm that the BMIX++ code is capable of simulating unintended hydrogen release scenarios efficiently. The BMIX++ (UC Berkeley mechanistic MIXing code in C++) code has been developed to accurately and efficiently predict the fluid mixture distribution and heat transfer in large stratified enclosures for accident analyses and design optimizations. The BMIX++ code uses a scaling based one-dimensional method to achieve large reduction in computational effort compared to a 3-D computational fluid dynamics (CFD) simulation. Two BMIX++ benchmark models have been developed. One is for a single buoyant jet in an open space and another is for a large sealed enclosure with both a jet source and a vent near the floor. Both of them have been validated by comparisons with experimental data. Excellent agreements are observed. The entrainment coefficients of 0.09 and 0.08 are found to fit the experimental data for hydrogen leaks with the Froude number of 99 and 268 best, respectively. In addition, the BIX++ simulation results of the average helium concentration for an enclosure with a vent and a single jet agree with the experimental data within a margin of about 10% for jet flow rates ranging from 1.21 × 10⁻⁴ to 3.29 × 10⁻⁴ m³/s. In conclusion, computing time for each BMIX++ model with a normal desktop computer is less than 5 min.

  15. Validation of hydrogen gas stratification and mixing models

    DOE PAGES

    Wu, Hsingtzu; Zhao, Haihua

    2015-05-26

    Two validation benchmarks confirm that the BMIX++ code is capable of simulating unintended hydrogen release scenarios efficiently. The BMIX++ (UC Berkeley mechanistic MIXing code in C++) code has been developed to accurately and efficiently predict the fluid mixture distribution and heat transfer in large stratified enclosures for accident analyses and design optimizations. The BMIX++ code uses a scaling based one-dimensional method to achieve large reduction in computational effort compared to a 3-D computational fluid dynamics (CFD) simulation. Two BMIX++ benchmark models have been developed. One is for a single buoyant jet in an open space and another is for amore » large sealed enclosure with both a jet source and a vent near the floor. Both of them have been validated by comparisons with experimental data. Excellent agreements are observed. The entrainment coefficients of 0.09 and 0.08 are found to fit the experimental data for hydrogen leaks with the Froude number of 99 and 268 best, respectively. In addition, the BIX++ simulation results of the average helium concentration for an enclosure with a vent and a single jet agree with the experimental data within a margin of about 10% for jet flow rates ranging from 1.21 × 10⁻⁴ to 3.29 × 10⁻⁴ m³/s. In conclusion, computing time for each BMIX++ model with a normal desktop computer is less than 5 min.« less

  16. A lattice-Boltzman model for noble gas diffusion

    NASA Astrophysics Data System (ADS)

    Cassata, W. S.; Huber, C.; Renne, P. R.

    2010-12-01

    Thermochronometry by the 40Ar/39Ar, 4He/3He, and (U-Th)/He techniques provides insights into a array of planetary processes that span immense time and temperature regimes, from rapid and high temperature asteroid impact events to mountain uplift occurring over plate tectonic timescales at near surface temperatures. Thermal modeling has expanded from simple calculations for quantifying diffusion from a single spherical domain or log normal distributions of domains to include crystals having discrete domain distributions, fast diffusion pathways, diffusive anisotropy, complex crystal geometries, alpha damage, and alpha ejection. Despite these advances, our understanding of diffusion within crystals that have complex microstructural features (e.g., exsolution and diffusive sinks) or highly asymmetric concentration gradients remains fragmentary. Improved computational speeds now enable thermochronologists to quantitatively explore many such problems. We have developed a code based on the lattice-Boltzmann (LB) method to model diffusion from a variety of complex 2-D geometries having isotropic, temperature-independent anisotropic, and temperature-dependent anisotropic diffusivity. We utilize the LB diffusion code to examine the effects of non-zero concentration boundaries, fast diffusion pathways, diffusive sinks, exsolution lamellae, asymmetrical concentration distributions, and temperature gradients on calculated diffusion parameters, age data, and inferred thermal histories. Animations and geological examples illustrate the applicability of the code to natural settings.

  17. Monte Carlo model for electron degradation in methane gas

    NASA Astrophysics Data System (ADS)

    Bhardwaj, Anil; Mukundan, Vrinda

    2015-06-01

    We present a Monte Carlo model for degradation of 1-10,000 eV electrons in an atmosphere of methane. The electron impact cross sections for CH4 are compiled and analytical representations of these cross sections are used as input to the model."Yield spectra", which provides information about the number of inelastic events that have taken place in each energy bin, is used to calculate the yield (or population) of various inelastic processes. The numerical yield spectra, obtained from the Monte Carlo simulations, is represented analytically, thus generating the Analytical Yield Spectra (AYS). AYS is employed to obtain the mean energy per ion pair and efficiencies of various inelastic processes. Mean energy per ion pair for neutral CH4 is found to be 26 (27.8) eV at 10 (0.1) keV. Efficiency calculation showed that ionization is the dominant process at energies > 50 eV, for which more than 50% of the incident electron energy is used. Above 25 eV, dissociation has an efficiency of ∼ 27 %. Below 10 eV, vibrational excitation dominates. Contribution of emission is around 1.2% at 10 keV. Efficiency of attachment process is ∼ 0.1 % at 8 eV and efficiency falls down to negligibly small values at energies greater than 15 eV. The efficiencies can be used to calculate volume production rate in planetary atmospheres by folding with electron production rate and integrating over energy.

  18. Three-Dimensional Model for Electrospinning Processes in Controlled Gas Counterflow

    PubMed Central

    2016-01-01

    We study the effects of a controlled gas flow on the dynamics of electrified jets in the electrospinning process. The main idea is to model the air drag effects of the gas flow by using a nonlinear Langevin-like approach. The model is employed to investigate the dynamics of electrified polymer jets at different conditions of air drag force, showing that a controlled gas counterflow can lead to a decrease of the average diameter of electrospun fibers, and potentially to an improvement of the quality of electrospun products. We probe the influence of air drag effects on the bending instabilities of the jet and on its angular fluctuations during the process. The insights provided by this study might prove useful for the design of future electrospinning experiments and polymer nanofiber materials. PMID:26859532

  19. A general computer model for predicting the performance of gas sorption refrigerators

    NASA Technical Reports Server (NTRS)

    Sigurdson, K. B.

    1983-01-01

    Projected performance requirements for cryogenic spacecraft sensor cooling systems which demand higher reliability and longer lifetimes are outlined. The gas/solid sorption refrigerator is viewed as a potential solution to cryogenic cooling needs. A software model of an entire gas sorption refrigerator system was developed. The numerical model, evaluates almost any combination and order of refrigerator components and any sorbent-sorbate pair or which the sorption isotherm data are available. Parametric curves for predicting system performance were generated for two types of refrigerators, a LaNi5-H2 absorption cooler and a Charcoal-N2 adsorption cooler. It is found that precooling temperature and heat exchanger effectiveness affect the refrigerator performance. It is indicated that gas sorption refrigerators are feasible for a number of space applications.

  20. Three-Dimensional Model for Electrospinning Processes in Controlled Gas Counterflow.

    PubMed

    Lauricella, Marco; Pisignano, Dario; Succi, Sauro

    2016-07-14

    We study the effects of a controlled gas flow on the dynamics of electrified jets in the electrospinning process. The main idea is to model the air drag effects of the gas flow by using a nonlinear Langevin-like approach. The model is employed to investigate the dynamics of electrified polymer jets at different conditions of air drag force, showing that a controlled gas counterflow can lead to a decrease of the average diameter of electrospun fibers, and potentially to an improvement of the quality of electrospun products. We probe the influence of air drag effects on the bending instabilities of the jet and on its angular fluctuations during the process. The insights provided by this study might prove useful for the design of future electrospinning experiments and polymer nanofiber materials.

  1. Modeling of ultrasound transmission through a solid-liquid interface comprising a network of gas pockets

    NASA Astrophysics Data System (ADS)

    Paumel, K.; Moysan, J.; Chatain, D.; Corneloup, G.; Baqué, F.

    2011-08-01

    Ultrasonic inspection of sodium-cooled fast reactor requires a good acoustic coupling between the transducer and the liquid sodium. Ultrasonic transmission through a solid surface in contact with liquid sodium can be complex due to the presence of microscopic gas pockets entrapped by the surface roughness. Experiments are run using substrates with controlled roughness consisting of a network of holes and a modeling approach is then developed. In this model, a gas pocket stiffness at a partially solid-liquid interface is defined. This stiffness is then used to calculate the transmission coefficient of ultrasound at the entire interface. The gas pocket stiffness has a static, as well as an inertial component, which depends on the ultrasonic frequency and the radiative mass.

  2. Noble gases solubility models of hydrocarbon charge mechanism in the Sleipner Vest gas field

    NASA Astrophysics Data System (ADS)

    Barry, P. H.; Lawson, M.; Meurer, W. P.; Warr, O.; Mabry, J. C.; Byrne, D. J.; Ballentine, C. J.

    2016-12-01

    -water exchange (i.e., volumetric gas-water ratios). These data are discussed within the framework of several conceptual models: (i) total gas-stripping model, which assumes all noble gases have been stripped from the water phase, thus defining the minimum volume of water to have interacted with the hydrocarbon phase; (ii) equilibrium model, which assumes equilibration between groundwater and hydrocarbon phase at reservoir P, T and salinity; and (iii) open and closed system gas-stripping models, using concentrations and elemental ratios. By applying these models to Ne-Ar data from Sleipner, we estimate volumetric gas-water ratios (Vg/Vw) between 0.02 and 0.07, which are lower than standard geologic gas-water estimates of ∼0.24, estimated by combining gas-in-place estimates with groundwater porosity estimates. Sleipner Vest data can be best approximated by an open system model, which predicts more than an order of magnitude more groundwater interaction during migration than geologic estimates, indicating a dynamic aquifer system and/or a hydrous migration pathway. In an open system, the extent of gas loss can be estimated to be between 8 and 10 reservoir volumes, which have passed through the system and been lost (i.e., filled and spilled).

  3. Modeling CO2 air dispersion from gas driven lake eruptions (Invited)

    NASA Astrophysics Data System (ADS)

    Chiodini, G.; Costa, A.; Rouwet, D.; Tassi, F.

    2010-12-01

    The most tragic event of gas driven lake eruption occurred at Lake Nyos (Cameroon) on 21 August 1986, when a dense cloud of CO2 suffocated more than 1700 people and an uncounted number of animals in just one night. The event stimulated a series of researches aimed to understand gas origins, gas release mechanisms and strategies for gas hazard mitigation. Very few studies have been carried out for describing the transport of dense CO2 clouds in the atmosphere. Although from a theoretical point of view, gas dispersion can be fully studied by solving the complete equations system for mass, momentum and energy transport, in actual practice, different simplified models able to describe only specific phases or aspects have to be used. In order to simulate dispersion of a heavy gas and to assess the consequent hazard we used a model based on a shallow layer approach (TWODEE2). This technique which uses depth-averaged variables to describe the flow behavior of dense gas over complex topography represents a good compromise between the complexity of computational fluid dynamic models and the simpler integral models. Recently the model has been applied for simulating CO2 dispersion from natural gas emissions in Central Italy. The results have shown how the dispersion pattern is strongly affected by the intensity of gas release, the topography and the ambient wind speed. Here for the first time we applied TWODEE2 code to simulate the dispersion of the large CO2 clouds released by limnic eruptions. An application concerns the case of the 1986 event at lake Nyos. Some difficulties for the simulations were related to the lack of quantitative information: gas flux estimations are not well constrained, meteorological conditions are only qualitatively known, the digital model of the terrain is of poor quality. Different scenarios were taken into account in order to reproduce the qualitative observations available for such episode. The observations regard mainly the effects of gas on

  4. A practical tool for simulating the presence of gas comae in thermophysical modelling of cometary nuclei

    NASA Astrophysics Data System (ADS)

    Davidsson, B.; Skorov, Y.

    Ideally, thermophysical modelling of cometary nuclei should be made in parallel with modelling of the coma, due to the strong nucleus-coma coupling. Furthermore, the coma model should include a suitable treatment of the non - equilibrium Knudsen layer adjacent to the surface, which s impossible with a purely hydrodynamicali description. Only then is it possible to fully account for surface heating due to backscattered recondensing coma molecules, and to evaluate the surface gas density needed as boundary condition in the thermophysical equations for the nucleus. However, due to the vast complexity of the problem and the extreme hardware requirements associated with such unified models, most thermophysical models of comets developed so far use oversimplified assumptions regarding coma properties, which may introduce substantial errors. We present a practical tool for simulating the presence of a gas coma in parallel with thermophysical models, emphasising both reasonable accuracy and practicality. The tool is in form of interpolation tables and approximate analytical expressions for surface gas density, surface gas pressure, percentage of recondensing backflux, and surface cooling by diffusely scattered coma molecules. These quantities are given as functions of surface temperature and temperature gradient, for porous ice-dust mixtures. The interpolation tables have been obtained by first considering a Direct Simulation Monte Carlo model of Knudsen flow in a sublimating porous medium, thus obtaining the transmission distribution function for molecules entering the coma. Then, the Knudsen layer collision-dominated flow has been considered using another Direct Simulation Monte Carlo model. The latter model includes a Variable HardSphere description of intermolecular collisions a d takes rotational degrees ofn freedom into account according to the Larsen-Borgnakke model. Examples of practical applications of the interpolation tables are presented.

  5. Star formation in semi-analytic galaxy formation models with multiphase gas

    NASA Astrophysics Data System (ADS)

    Somerville, Rachel S.; Popping, Gergö; Trager, Scott C.

    2015-11-01

    We implement physically motivated recipes for partitioning cold gas into different phases (atomic, molecular, and ionized) in galaxies within semi-analytic models of galaxy formation based on cosmological merger trees. We then model the conversion of molecular gas into stars using empirical recipes motivated by recent observations. We explore the impact of these new recipes on the evolution of fundamental galaxy properties such as stellar mass, star formation rate (SFR), and gas and stellar phase metallicity. We present predictions for stellar mass functions, stellar mass versus SFR relations, and cold gas phase and stellar mass-metallicity relations for our fiducial models, from redshift z ˜ 6 to the present day. In addition we present predictions for the global SFR, mass assembly history, and cosmic enrichment history. We find that the predicted stellar properties of galaxies (stellar mass, SFR, metallicity) are remarkably insensitive to the details of the recipes used for partitioning gas into H I and H2. We see significant sensitivity to the recipes for H2 formation only in very low mass haloes (M_h ≲ 10^{10.5} M_{⊙}), which host galaxies with stellar masses m_* ≲ 10^8 M_{⊙}. The properties of low-mass galaxies are also quite insensitive to the details of the recipe used for converting H2 into stars, while the formation epoch of massive galaxies does depend on this significantly. We argue that this behaviour can be interpreted within the framework of a simple equilibrium model for galaxy evolution, in which the conversion of cold gas into stars is balanced on average by inflows and outflows.

  6. Ideal-gas-like market models with savings: Quenched and annealed cases

    NASA Astrophysics Data System (ADS)

    Chatterjee, Arnab; Chakrabarti, Bikas K.

    2007-08-01

    We analyze the ideal-gas-like models of markets and review the different cases where a ‘savings’ factor changes the nature and shape of the distribution of wealth. These models can produce similar distribution of wealth as observed across varied economies. We present a more realistic model where the saving factor can vary over time (annealed savings) and yet produce Pareto distribution of wealth in certain cases. We discuss the relevance of such models in the context of wealth distribution, and address some recent issues in the context of these models.

  7. A macroscopic model for slightly compressible gas slip-flow in homogeneous porous media

    NASA Astrophysics Data System (ADS)

    Lasseux, D.; Parada, F. J. Valdes; Tapia, J. A. Ochoa; Goyeau, B.

    2014-05-01

    The study of gas slip-flow in porous media is relevant in many applications ranging from nanotechnology to enhanced oil recovery and in any situation involving low-pressure gas-transport through structures having sufficiently small pores. In this paper, we use the method of volume averaging for deriving effective-medium equations in the framework of a slightly compressible gas flow. The result of the upscaling process is an effective-medium model subjected to time- and length-scale constraints, which are clearly identified in our derivation. At the first order in the Knudsen number, the macroscopic momentum transport equation corresponds to a Darcy-like model involving the classical intrinsic permeability tensor and a slip-flow correction tensor that is also intrinsic. It generalizes the Darcy-Klinkenberg equation for ideal gas flow, and exhibits a more complex form for dense gas. The component values of the two intrinsic tensors were computed by solving the associated closure problems on two- and three-dimensional periodic unit cells. Furthermore, the dependence of the slip-flow correction with the porosity was also verified to agree with approximate analytical results. Our predictions show a power-law relationship between the permeability and the slip-flow correction that is consistent with other works. Nevertheless, the generalization of such a relationship to any configuration requires more analysis.

  8. A physiological model of the release of gas bubbles from crevices under decompression.

    PubMed

    Chappell, M A; Payne, S J

    2006-09-28

    Moving bubbles have been observed in the blood during or after decompression using ultrasonic techniques. It has been proposed that these may grow from nuclei housed on the blood vessel wall. One candidate for bubble nucleation is hydrophobic crevices. This work explores the growth of gas pockets that might exist in conical crevices and the release of bubbles from these crevices under decompression. An existing dynamic mathematical model for the stability of gas pockets in crevices [Chappell, M.A., Payne, S.J., in press. A physiological model of gas pockets in crevices and their behavior under compression. Respir. Physiol. Neurobiol.] is extended to include the behavior as the gas pocket reaches the crevice mouth and bubbles seed into the bloodstream. The behavior of the crevice bubble is explored for a single inert gas, both alone and with metabolic gases included. It was found that the presence of metabolic gases has a significant effect on the behavior under decompression and that this appears to be due to the high diffusivity of these gases.

  9. Landfill Gas Energy Cost Model Version 3.0 (LFGcost-Web V3.0)

    EPA Science Inventory

    To help stakeholders estimate the costs of a landfill gas (LFG) energy project, in 2002, LMOP developed a cost tool (LFGcost). Since then, LMOP has routinely updated the tool to reflect changes in the LFG energy industry. Initially the model was designed for EPA to assist landfil...

  10. From chiral quark dynamics with Polyakov loop to the hadron resonance gas model

    SciTech Connect

    Arriola, E. R.; Salcedo, L. L.; Megias, E.

    2013-03-25

    Chiral quark models with Polyakov loop at finite temperature have been often used to describe the phase transition. We show how the transition to a hadron resonance gas is realized based on the quantum and local nature of the Polyakov loop.

  11. Development of a Gas Dynamic and Thermodynamic Simulation Model of the Lontra Blade Compressor™

    NASA Astrophysics Data System (ADS)

    Karlovsky, Jerome

    2015-08-01

    The Lontra Blade Compressor™ is a patented double acting, internally compressing, positive displacement rotary compressor of innovative design. The Blade Compressor is in production for waste-water treatment, and will soon be launched for a range of applications at higher pressure ratios. In order to aid the design and development process, a thermodynamic and gas dynamic simulation program has been written in house. The software has been successfully used to optimise geometries and running conditions of current designs, and is also being used to evaluate future designs for different applications and markets. The simulation code has three main elements. A positive displacement chamber model, a leakage model and a gas dynamic model to simulate gas flow through ports and to track pressure waves in the inlet and outlet pipes. All three of these models are interlinked in order to track mass and energy flows within the system. A correlation study has been carried out to verify the software. The main correlation markers used were mass flow, chamber pressure, pressure wave tracking in the outlet pipe, and volumetric efficiency. It will be shown that excellent correlation has been achieved between measured and simulated data. Mass flow predictions were to within 2% of measured data, and the timings and magnitudes of all major gas dynamic effects were well replicated. The simulation will be further developed in the near future to help with the optimisation of exhaust and inlet silencers.

  12. A Model for Gas Dynamics and Chemical Evolution of the Fornax Dwarf Spheroidal Galaxy

    NASA Astrophysics Data System (ADS)

    Yuan, Zhen

    We present an empirical model for the halo evolution, global gas dynamics and chemical evolution of Fornax, the brightest Milky Way (MW) dwarf spheroidal galaxy (dSph). Assuming a global star formation rate psi(t) = lambda*(t)[Mg( t)/M[solar masses

  13. A Multi-Fidelity Surrogate Model for Handling Real Gas Equations of State

    NASA Astrophysics Data System (ADS)

    Ouellet, Frederick; Park, Chanyoung; Rollin, Bertrand; Balachandar, S."bala"

    2016-11-01

    The explosive dispersal of particles is an example of a complex multiphase and multi-species fluid flow problem. This problem has many engineering applications including particle-laden explosives. In these flows, the detonation products of the explosive cannot be treated as a perfect gas so a real gas equation of state is used to close the governing equations (unlike air, which uses the ideal gas equation for closure). As the products expand outward from the detonation point, they mix with ambient air and create a mixing region where both of the state equations must be satisfied. One of the more accurate, yet computationally expensive, methods to deal with this is a scheme that iterates between the two equations of state until pressure and thermal equilibrium are achieved inside of each computational cell. This work strives to create a multi-fidelity surrogate model of this process. We then study the performance of the model with respect to the iterative method by performing both gas-only and particle laden flow simulations using an Eulerian-Lagrangian approach with a finite volume code. Specifically, the model's (i) computational speed, (ii) memory requirements and (iii) computational accuracy are analyzed to show the benefits of this novel modeling approach. This work was supported by the U.S. Department of Energy, National Nuclear Security Administration, Advanced Simulation and Computing Program, as a Cooperative Agreement under the Predictive Science Academic Alliance Program, under Contract No. DE-NA00023.

  14. Estimating Risk of Natural Gas Portfolios by Using GARCH-EVT-Copula Model

    PubMed Central

    Tang, Jiechen; Zhou, Chao; Yuan, Xinyu; Sriboonchitta, Songsak

    2015-01-01

    This paper concentrates on estimating the risk of Title Transfer Facility (TTF) Hub natural gas portfolios by using the GARCH-EVT-copula model. We first use the univariate ARMA-GARCH model to model each natural gas return series. Second, the extreme value distribution (EVT) is fitted to the tails of the residuals to model marginal residual distributions. Third, multivariate Gaussian copula and Student t-copula are employed to describe the natural gas portfolio risk dependence structure. Finally, we simulate N portfolios and estimate value at risk (VaR) and conditional value at risk (CVaR). Our empirical results show that, for an equally weighted portfolio of five natural gases, the VaR and CVaR values obtained from the Student t-copula are larger than those obtained from the Gaussian copula. Moreover, when minimizing the portfolio risk, the optimal natural gas portfolio weights are found to be similar across the multivariate Gaussian copula and Student t-copula and different confidence levels. PMID:26351652

  15. Estimating Risk of Natural Gas Portfolios by Using GARCH-EVT-Copula Model.

    PubMed

    Tang, Jiechen; Zhou, Chao; Yuan, Xinyu; Sriboonchitta, Songsak

    2015-01-01

    This paper concentrates on estimating the risk of Title Transfer Facility (TTF) Hub natural gas portfolios by using the GARCH-EVT-copula model. We first use the univariate ARMA-GARCH model to model each natural gas return series. Second, the extreme value distribution (EVT) is fitted to the tails of the residuals to model marginal residual distributions. Third, multivariate Gaussian copula and Student t-copula are employed to describe the natural gas portfolio risk dependence structure. Finally, we simulate N portfolios and estimate value at risk (VaR) and conditional value at risk (CVaR). Our empirical results show that, for an equally weighted portfolio of five natural gases, the VaR and CVaR values obtained from the Student t-copula are larger than those obtained from the Gaussian copula. Moreover, when minimizing the portfolio risk, the optimal natural gas portfolio weights are found to be similar across the multivariate Gaussian copula and Student t-copula and different confidence levels.

  16. Modeling the adsorption of mixed gases based on pure gas adsorption properties

    NASA Astrophysics Data System (ADS)

    Tzabar, N.; Holland, H. J.; Vermeer, C. H.; ter Brake, H. J. M.

    2015-12-01

    Sorption-based Joule-Thomson (JT) cryocoolers usually operate with pure gases. A sorption-based compressor has many benefits; however, it is limited by the pressure ratios it can provide. Using a mixed-refrigerant (MR) instead of a pure refrigerant in JT cryocoolers allows working at much lower pressure ratios. Therefore, it is attractive using MRs in sorption- based cryocoolers in order to reduce one of its main limitations. The adsorption of mixed gases is usually investigated under steady-state conditions, mainly for storage and separation processes. However, the process in a sorption compressor goes through various temperatures, pressures and adsorption concentrations; therefore, it differs from the common mixed gases adsorption applications. In order to simulate the sorption process in a compressor a numerical analysis for mixed gases is developed, based on pure gas adsorption characteristics. The pure gas adsorption properties have been measured for four gases (nitrogen, methane, ethane, and propane) with Norit-RB2 activated carbon. A single adsorption model is desired to describe the adsorption of all four gases. This model is further developed to a mixed-gas adsorption model. In future work more adsorbents will be tested using these four gases and the adsorption model will be verified against experimental results of mixed-gas adsorption measurements.

  17. Identifying key sources of uncertainty in the modelling of greenhouse gas emissions from wastewater treatment.

    PubMed

    Sweetapple, Christine; Fu, Guangtao; Butler, David

    2013-09-01

    This study investigates sources of uncertainty in the modelling of greenhouse gas emissions from wastewater treatment, through the use of local and global sensitivity analysis tools, and contributes to an in-depth understanding of wastewater treatment modelling by revealing critical parameters and parameter interactions. One-factor-at-a-time sensitivity analysis is used to screen model parameters and identify those with significant individual effects on three performance indicators: total greenhouse gas emissions, effluent quality and operational cost. Sobol's method enables identification of parameters with significant higher order effects and of particular parameter pairs to which model outputs are sensitive. Use of a variance-based global sensitivity analysis tool to investigate parameter interactions enables identification of important parameters not revealed in one-factor-at-a-time sensitivity analysis. These interaction effects have not been considered in previous studies and thus provide a better understanding wastewater treatment plant model characterisation. It was found that uncertainty in modelled nitrous oxide emissions is the primary contributor to uncertainty in total greenhouse gas emissions, due largely to the interaction effects of three nitrogen conversion modelling parameters. The higher order effects of these parameters are also shown to be a key source of uncertainty in effluent quality.

  18. A Petroleum Vapor Intrusion Model Involving Upward Advective Soil Gas Flow Due to Methane Generation.

    PubMed

    Yao, Yijun; Wu, Yun; Wang, Yue; Verginelli, Iason; Zeng, Tian; Suuberg, Eric M; Jiang, Lin; Wen, Yuezhong; Ma, Jie

    2015-10-06

    At petroleum vapor intrusion (PVI) sites at which there is significant methane generation, upward advective soil gas transport may be observed. To evaluate the health and explosion risks that may exist under such scenarios, a one-dimensional analytical model describing these processes is introduced in this study. This new model accounts for both advective and diffusive transport in soil gas and couples this with a piecewise first-order aerobic biodegradation model, limited by oxygen availability. The predicted results from the new model are shown to be in good agreement with the simulation results obtained from a three-dimensional numerical model. These results suggest that this analytical model is suitable for describing cases involving open ground surface beyond the foundation edge, serving as the primary oxygen source. This new analytical model indicates that the major contribution of upward advection to indoor air concentration could be limited to the increase of soil gas entry rate, since the oxygen in soil might already be depleted owing to the associated high methane source vapor concentration.

  19. Modeling the Potential Volume of Gas Hydrates Over Time and During Transient Climate Events

    NASA Astrophysics Data System (ADS)

    Dickens, G. R.; Dickens, G. R.

    2001-12-01

    Gas hydrates in marine sediment probably serve as a large bacterially mediated capacitor in the global carbon cycle, storing and releasing CH4 with changes in external forcing. Although germinal, models of the global carbon cycle that incorporate gas hydrates require characterization of the available pore space -- the potential volume -- over time, especially during transient climate events. Potentially, gas hydrates can occur between the seafloor and a locus of subbottom depths where geothermal gradients intersect gas-gas hydrate-pore water equilibrium curves. Perpendicular to a given continental margin, the lens shaped area between these two bounding surfaces (Asl) varies according to seven basic parameters: gas composition, water activity (aw), bottom water temperature (Tb), geothermal gradient (G), slope depth (zslb), slope gradient (Z) and sea level relative to the shelf break (zo). Assuming pure CH4 gas, ~35 km2 of sediment can host gas hydrate across an average continental margin at a Pleistocene lowstand (aw = 0.981, Tb = 0° C, G = 0.05° C/m; zslb = 4000 m; Z = 0.04; zo = 0). However, this potential area would decrease with smaller aw, higher Tb, greater G, shallower zslb, steeper Z and lower zo, and increase with opposite external conditions. Of the basic parameters, temperature (Tb and G) and bathymetry (zslb and Z) can particularly influence the distribution of gas hydrate on continental slopes. A hydrothermal gradient (i.e., surface temperatures > Tb) will also decrease Asl, although minimally, especially if Tb exceeds 5° . The sum of parallel cross-sectional areas along a margin combined with porosity (φ ) gives the potential volume of gas hydrate (V). Assuming ~200,000 km of continental margin with φ of 0.50, ~3.5 x 106 km3 of pore space can contain gas hydrates at present-day, a volume that compares favorably with previous estimates (1.2 to 6.4 x 106 km3) although underlying approaches differ fundamentally. Since the Triassic, VGlob probably has

  20. Chemistry in disks. IV. Benchmarking gas-grain chemical models with surface reactions

    NASA Astrophysics Data System (ADS)

    Semenov, D.; Hersant, F.; Wakelam, V.; Dutrey, A.; Chapillon, E.; Guilloteau, St.; Henning, Th.; Launhardt, R.; Piétu, V.; Schreyer, K.

    2010-11-01

    Context. We describe and benchmark two sophisticated chemical models developed by the Heidelberg and Bordeaux astrochemistry groups. Aims: The main goal of this study is to elaborate on a few well-described tests for state-of-the-art astrochemical codes covering a range of physical conditions and chemical processes, in particular those aimed at constraining current and future interferometric observations of protoplanetary disks. Methods: We considered three physical models: a cold molecular cloud core, a hot core, and an outer region of a T Tauri disk. Our chemical network (for both models) is based on the original gas-phase osu_03_2008 ratefile and includes gas-grain interactions and a set of surface reactions for the H-, O-, C-, S-, and N-bearing molecules. The benchmarking was performed with the increasing complexity of the considered processes: (1) the pure gas-phase chemistry, (2) the gas-phase chemistry with accretion and desorption, and (3) the full gas-grain model with surface reactions. The chemical evolution is modeled within 109 years using atomic initial abundances with heavily depleted metals and hydrogen in its molecular form. Results: The time-dependent abundances calculated with the two chemical models are essentially the same for all considered physical cases and for all species, including the most complex polyatomic ions and organic molecules. This result, however, required a lot of effort to make all necessary details consistent through the model runs, e.g., definition of the gas particle density, density of grain surface sites, or the strength and shape of the UV radiation field. Conclusions: The reference models and the benchmark setup, along with the two chemical codes and resulting time-dependent abundances are made publicly available on the internet. This will facilitate and ease the development of other astrochemical models and provide nonspecialists with a detailed description of the model ingredients and requirements to analyze the cosmic

  1. The modeling of gas phase permeation through iron and nickel membranes

    NASA Technical Reports Server (NTRS)

    Kuhn, David K.; Shanabarger, Mickey R.

    1989-01-01

    The gas phase permeation of hydrogen through metal membranes encompasses many kinetic processes. This paper reviews a permeation model which incorporates second order gas-surface reaction kinetics with simple bulk diffusion. The model is used to investigate the effect of this particular surface reaction of steady-state permeation. The dependence of the steady-state permeation flux on temperature, pressure, and thickness of the membrane has been calculated. The model predicts that the bulk controlled steady-state flux will change to a surface limited steady-state flux as either the temperature or thickness of the membrane is reduced. Finally, using independently derived parameters, the model is compared with permeation measurements on iron and nickel membranes.

  2. Experimental investigation and modeling of a wet flue gas desulfurization pilot plant

    SciTech Connect

    Kiil, S.; Michelsen, M.L.; Dam-Johansen, K.

    1998-07-01

    A detailed model for a wet flue gas desulfurization (FGD) pilot plant, based on the packed tower concept, has been developed. All important rate-determining steps, absorption of SO{sub 2}, oxidation of HSO{sub 3}{sup {minus}}, dissolution of limestone, and crystallization of gypsum were included. Population balance equations, governing the description of particle size distributions of limestone in the plant, were derived. Model predictions were compared to experimental data such as gas-phase concentration profiles of SO{sub 2}, slurry pH profiles, solids content of the slurry, liquid-phase concentrations, and residual limestone in the gypsum. Simulations were found to match experimental data for the two limestone types investigated. A parameter study of the model was conducted with the purpose of validating assumptions and extracting information on wet FGD systems. The modeling tools developed may be applicable to other wet FGD plants.

  3. Statistical mechanical model of gas adsorption in porous crystals with dynamic moieties.

    PubMed

    Simon, Cory M; Braun, Efrem; Carraro, Carlo; Smit, Berend

    2017-01-17

    Some nanoporous, crystalline materials possess dynamic constituents, for example, rotatable moieties. These moieties can undergo a conformation change in response to the adsorption of guest molecules, which qualitatively impacts adsorption behavior. We pose and solve a statistical mechanical model of gas adsorption in a porous crystal whose cages share a common ligand that can adopt two distinct rotational conformations. Guest molecules incentivize the ligands to adopt a different rotational configuration than maintained in the empty host. Our model captures inflections, steps, and hysteresis that can arise in the adsorption isotherm as a signature of the rotating ligands. The insights disclosed by our simple model contribute a more intimate understanding of the response and consequence of rotating ligands integrated into porous materials to harness them for gas storage and separations, chemical sensing, drug delivery, catalysis, and nanoscale devices. Particularly, our model reveals design strategies to exploit these moving constituents and engineer improved adsorbents with intrinsic thermal management for pressure-swing adsorption processes.

  4. Computational Modeling of the Working Process in the Combustion Chamber for Casing-Head Gas Recovery

    NASA Astrophysics Data System (ADS)

    Bachev, N. L.; Betinskaya, O. A.; Bul‧bovich, R. V.

    2016-01-01

    The present paper considers problems of computational modeling of the working process in multizone combustion chambers (CC) forming a part of gas-turbine power plants for recovering casing-head and other process gases. To investigate the turbulent flow and combustion, we use the LES method with a Smagorinskii subnet model. Various schemes of feeding components into combustion and dilution zones are considered. A comparison is made between the calculated and experimental data on the temperature in the combustion zone.

  5. Multi-agent social and organizational modeling of the electric power and natural gas markets.

    SciTech Connect

    North, M. J.; Decision and Information Sciences

    2001-12-01

    Complex Adaptive Systems (CAS) can be applied to investigate large-scale socio-cognitive-technical systems. Viewing such systems from a multi-agent social and organizational perspective allows innovative computational policy analysis. Argonne National Laboratory (ANL) has taken such a perspective to produce an integrated model of the electric power and natural gas markets. This model focuses on the organizational interdependencies between these markets. These organizational interdependencies are being strained by fundamental market transformations.

  6. Monitoring and modeling wetland chloride concentrations in relationship to oil and gas development

    USGS Publications Warehouse

    Post van der Burg, Max; Tangen, Brian A.

    2015-01-01

    Extraction of oil and gas via unconventional methods is becoming an important aspect of energy production worldwide. Studying the effects of this development in countries where these technologies are being widely used may provide other countries, where development may be proposed, with some insight in terms of concerns associated with development. A fairly recent expansion of unconventional oil and gas development in North America provides such an opportunity. Rapid increases in energy development in North America have caught the attention of managers and scientists as a potential stressor for wildlife and their habitats. Of particular concern in the Northern Great Plains of the U.S. is the potential for chloride-rich produced water associated with unconventional oil and gas development to alter the water chemistry of wetlands. We describe a landscape scale modeling approach designed to examine the relationship between potential chloride contamination in wetlands and patterns of oil and gas development. We used a spatial Bayesian hierarchical modeling approach to assess multiple models explaining chloride concentrations in wetlands. These models included effects related to oil and gas wells (e.g. age of wells, number of wells) and surficial geology (e.g. glacial till, outwash). We found that the model containing the number of wells and the surficial geology surrounding a wetland best explained variation in chloride concentrations. Our spatial predictions showed regions of localized high chloride concentrations. Given the spatiotemporal variability of regional wetland water chemistry, we do not regard our results as predictions of contamination, but rather as a way to identify locations that may require more intensive sampling or further investigation. We suggest that an approach like the one outlined here could easily be extended to more of an adaptive monitoring approach to answer questions about chloride contamination risk that are of interest to managers.

  7. Monitoring and modeling wetland chloride concentrations in relationship to oil and gas development.

    PubMed

    Post van der Burg, Max; Tangen, Brian A

    2015-03-01

    Extraction of oil and gas via unconventional methods is becoming an important aspect of energy production worldwide. Studying the effects of this development in countries where these technologies are being widely used may provide other countries, where development may be proposed, with some insight in terms of concerns associated with development. A fairly recent expansion of unconventional oil and gas development in North America provides such an opportunity. Rapid increases in energy development in North America have caught the attention of managers and scientists as a potential stressor for wildlife and their habitats. Of particular concern in the Northern Great Plains of the U.S. is the potential for chloride-rich produced water associated with unconventional oil and gas development to alter the water chemistry of wetlands. We describe a landscape scale modeling approach designed to examine the relationship between potential chloride contamination in wetlands and patterns of oil and gas development. We used a spatial Bayesian hierarchical modeling approach to assess multiple models explaining chloride concentrations in wetlands. These models included effects related to oil and gas wells (e.g. age of wells, number of wells) and surficial geology (e.g. glacial till, outwash). We found that the model containing the number of wells and the surficial geology surrounding a wetland best explained variation in chloride concentrations. Our spatial predictions showed regions of localized high chloride concentrations. Given the spatiotemporal variability of regional wetland water chemistry, we do not regard our results as predictions of contamination, but rather as a way to identify locations that may require more intensive sampling or further investigation. We suggest that an approach like the one outlined here could easily be extended to more of an adaptive monitoring approach to answer questions about chloride contamination risk that are of interest to managers.

  8. The Prevalence of Gas Outflows in Type 2 AGNs. II. 3D Biconical Outflow Models

    NASA Astrophysics Data System (ADS)

    Bae, Hyun-Jin; Woo, Jong-Hak

    2016-09-01

    We present 3D models of biconical outflows combined with a thin dust plane for investigating the physical properties of the ionized gas outflows and their effect on the observed gas kinematics in type 2 active galactic nuclei (AGNs). Using a set of input parameters, we construct a number of models in 3D and calculate the spatially integrated velocity and velocity dispersion for each model. We find that three primary parameters, i.e., intrinsic velocity, bicone inclination, and the amount of dust extinction, mainly determine the simulated velocity and velocity dispersion. Velocity dispersion increases as the intrinsic velocity or the bicone inclination increases, while velocity (i.e., velocity shifts with respect to systemic velocity) increases as the amount of dust extinction increases. Simulated emission-line profiles well reproduce the observed [O iii] line profiles, e.g., narrow core and broad wing components. By comparing model grids and Monte Carlo simulations with the observed [O iii] velocity-velocity dispersion distribution of ˜39,000 type 2 AGNs, we constrain the intrinsic velocity of gas outflows ranging from ˜500 to ˜1000 km s-1 for the majority of AGNs, and up to ˜1500-2000 km s-1 for extreme cases. The Monte Carlo simulations show that the number ratio of AGNs with negative [O iii] velocity to AGNs with positive [O iii] velocity correlates with the outflow opening angle, suggesting that outflows with higher intrinsic velocity tend to have wider opening angles. These results demonstrate the potential of our 3D models for studying the physical properties of gas outflows, applicable to various observations, including spatially integrated and resolved gas kinematics.

  9. A Finite-Rate Gas-Surface Interaction Model Informed by Fundamental Computational Chemistry Simulations

    DTIC Science & Technology

    2013-03-31

    jet tests, are inferred from heat flux measurements . This requires an accurate model of the arc-jet flow field and predicted convective heat flux...published an AIAA conference paper in 2007 entitled, “Molecular mechanisms of gas surface interactions in hypersonic flow ” [24]. In this paper, Cozmuta...cristobalite(100)  surface’,  Proceedings  of  the   Rarefied   Gas  Dynamics:  26th  International  Symposium,   AIP  Conf.  Proc

  10. Preconcentration modeling for the optimization of a micro gas preconcentrator applied to environmental monitoring.

    PubMed

    Camara, Malick; Breuil, Philippe; Briand, Danick; Viricelle, Jean-Paul; Pijolat, Christophe; de Rooij, Nico F

    2015-04-21

    This paper presents the optimization of a micro gas preconcentrator (μ-GP) system applied to atmospheric pollution monitoring, with the help of a complete modeling of the preconcentration cycle. Two different approaches based on kinetic equations are used to illustrate the behavior of the micro gas preconcentrator for given experimental conditions. The need for high adsorption flow and heating rate and for low desorption flow and detection volume is demonstrated in this paper. Preliminary to this optimization, the preconcentration factor is discussed and a definition is proposed.

  11. Operation, Modeling and Analysis of the Reverse Water Gas Shift Process

    NASA Technical Reports Server (NTRS)

    Whitlow, Jonathan E.

    2001-01-01

    The Reverse Water Gas Shift process is a candidate technology for water and oxygen production on Mars under the In-Situ Propellant Production project. This report focuses on the operation and analysis of the Reverse Water Gas Shift (RWGS) process, which has been constructed at Kennedy Space Center. A summary of results from the initial operation of the RWGS, process along with an analysis of these results is included in this report. In addition an evaluation of a material balance model developed from the work performed previously under the summer program is included along with recommendations for further experimental work.

  12. Are BL Lac-type objects nearby black holes. [gas accretion model

    NASA Technical Reports Server (NTRS)

    Shapiro, S. L.; Elliot, J. L.

    1974-01-01

    It is pointed out that isolated black holes accreting interstellar gas can account for the characteristic properties of the Lacertids. Emission spectra for various interstellar gas densities and black hole masses are compared with the data plotted by Strittmatter et al. (1972) for the BL Lac-type objects. Rough estimates indicate that there may indeed be a finite number of stellar-mass black holes close to the earth as required by the theory. If it is determined that the BL Lac-type objects lie outside of the galactic disk a black hole accretion model may still apply if certain conditions are satisfied.

  13. Gas Transport Parameters for Landfill Final Cover Soil: Measurements and Model Modification by Dry Bulk Density

    NASA Astrophysics Data System (ADS)

    Wickramarachchi, P. N.; Kawamoto, K.; Hamamoto, S.; Nagamori, M.; Moldrup, P.; Komatsu, T.

    2011-12-01

    coarser (< 35 mm) fraction became larger than finer (< 2 mm) for the given soil-air content. Further, compaction effort was much significant for ka than Dp for both fractions. We suggest this is because of compaction effects caused to create well-aligned macropore networks that are available for gas transport through the porous material. Then, the famous predictive models, the water induced linear reduction (WLR) model for Dp and the reference point law (RPL) model for ka were modified with reference point measurements (dry conditions) and model parameters and they correlated linearly to dry bulk density values for both fractions of landfill final cover soil.

  14. Effect of grain morphology on gas bubble swelling in UMo fuels - A 3D microstructure dependent Booth model

    NASA Astrophysics Data System (ADS)

    Hu, Shenyang; Burkes, Douglas; Lavender, Curt A.; Joshi, Vineet

    2016-11-01

    A three dimensional microstructure dependent swelling model is developed for studying the fission gas swelling kinetics in irradiated nuclear fuels. The model is extended from the Booth model [1] in order to investigate the effect of heterogeneous microstructures on gas bubble swelling kinetics. As an application of the model, the effect of grain morphology, fission gas diffusivity, and spatially dependent fission rate on swelling kinetics are simulated in UMo fuels. It is found that the decrease of grain size, the increase of grain aspect ratio for the grain having the same volume, and the increase of fission gas diffusivity (fission rate) cause the increase of swelling kinetics. Other heterogeneities such as second phases and spatially dependent thermodynamic properties including diffusivity of fission gas, sink and source strength of defects could be naturally integrated into the model to enhance the model capability.

  15. Effect of grain morphology on gas bubble swelling in UMo fuels – A 3D microstructure dependent Booth model

    SciTech Connect

    Hu, Shenyang; Burkes, Douglas; Lavender, Curt A.; Joshi, Vineet

    2016-11-01

    A three dimensional microstructure dependent swelling model is developed for studying the fission gas swelling kinetics in irradiated nuclear fuels. The model is extended from the Booth model [1] in order to investigate the effect of heterogeneous microstructures on gas bubble swelling kinetics. As an application of the model, the effect of grain morphology, fission gas diffusivity, and spatial dependent fission rate on swelling kinetics are simulated in UMo fuels. It is found that the decrease of grain size, the increase of grain aspect ratio for the grain having the same volume, and the increase of fission gas diffusivity (fission rate) cause the increase of swelling kinetics. Other heterogeneities such as second phases and spatial dependent thermodynamic properties including diffusivity of fission gas, sink and source strength of defects could be naturally integrated into the model to enhance the model capability.

  16. HI Gas in Disk and Dwarf Galaxies in the Semi-analytic Models of Galaxy Formation†

    NASA Astrophysics Data System (ADS)

    Fu, Jian; Wang, Jing; Luo, Yu

    We construct the radially-resolved semi-analytic models of galaxy formation based on the L-Galaxies model framework, which include both atomic and molecular gas phase in ISM. The models run on the halo outputs of ΛCDM cosmology N-body simulation. Our models can reproduce varies observations of HI gas in nearby galaxies, e.g. the HI mass function, the HI-to-star ratio vs stellar mass and stellar surface density, universal HI radial surface density profile in outer disks etc. We also give the physical origin of HI size-mass relation. Based on our model results for local dwarf galaxies, we show that the ``missing satellite problem'' also exists in the HI component, i.e., the models over-predict dwarf galaxies with low HI mass around the Milky Way. That is a shortcoming of current ΛCDM cosmology framework. Future survey for HI gas in local dwarf galaxies (e.g. MeerKAT, SKA & FAST) can help to verify the nature of dark matter (cold or warm).

  17. Semi-analytic models for HI gas in disk and local dwarf galaxies

    NASA Astrophysics Data System (ADS)

    Fu, Jian

    2015-08-01

    We construct the radially-resolved semi-analytic models of galaxy formation based on the L-Galaxies model framework, which include both atomic and molecular gas phase in ISM. The models adopt the ΛCDM cosmology simulation Millennium, Millennium II and Aquarius. Our models can reproduce varies properties of HI gas in nearby galaxies, e.g. the HI mass function, the HI-to-star ratio vs stellar mass and stellar surface density, universal HI radial surface density profile in outer disks etc. We can also give some physical origins of HI size mass relation in many observations.Based on our model results for local dwarf galaxies, we show that the "missing satellite problem" also exists in the HI component, i.e., the models over predict dwarf galaxies with low HI mass. That is a shortcoming of current ΛCDM cosmology framework. Future survey for HI gas in dwarf galaxies (e.g. SKA or FAST) in local group can help to verify the correctness of cold dark matter.

  18. Assessment of MELCOR condensation models with the presence of noncondensable gas in natural convection flow regime

    DOE PAGES

    Yoon, Dhongik S; Jo, HangJin; Corradini, Michael L

    2017-04-01

    Condensation of steam vapor is an important mode of energy removal from the reactor containment. The presence of noncondensable gas complicates the process and makes it difficult to model. MELCOR, one of the more widely used system codes for containment analyses, uses the heat and mass transfer analogy to model condensation heat transfer. To investigate previously reported nodalization-dependence in natural convection flow regime, MELCOR condensation model as well as other models are studied. The nodalization-dependence issue is resolved by using physical length from the actual geometry rather than node size of each control volume as the characteristic length scale formore » MELCOR containment analyses. At the transition to turbulent natural convection regime, the McAdams correlation for convective heat transfer produces a better prediction compared to the original MELCOR model. The McAdams correlation is implemented in MELCOR and the prediction is validated against a set of experiments on a scaled AP600 containment. The MELCOR with our implemented model produces improved predictions. For steam molar fractions in the gas mixture greater than about 0.58, the predictions are within the uncertainty margin of the measurements. The simulation results still underestimate the heat transfer from the gas-steam mixture, implying that conservative predictions are provided.« less

  19. a Diffusivity Model for Gas Diffusion in Dry Porous Media Composed of Converging-Diverging Capillaries

    NASA Astrophysics Data System (ADS)

    Wang, Shifang; Wu, Tao; Deng, Yongju; Zheng, Qiusha; Zheng, Qian

    2016-08-01

    Gas diffusion in dry porous media has been a hot topic in several areas of technology for many years. In this paper, a diffusivity model for gas diffusion in dry porous media is developed based on fractal theory and Fick’s law, which incorporates the effects of converging-diverging pores and tortuous characteristics of capillaries as well as Knudsen diffusion. The effective gas diffusivity model is expressed as a function of the fluctuation amplitude of the capillary cross-section size variations, the porosity, the pore area fractal dimension and the tortuosity fractal dimension. The results show that the relative diffusivity decreases with the increase of the fluctuation amplitude and increases with the increase of pore area fractal dimension. To verify the validity of the present model, the relative diffusivity from the proposed fractal model is compared with the existing experimental data as well as two available models of Bruggeman and Shou. Our proposed diffusivity model with pore converging-diverging effect included is in good agreement with reported experimental data.

  20. A tidal breathing model of the inert gas sinewave technique for inhomogeneous lungs.

    PubMed

    Whiteley, J P; Gavaghan, D J; Hahn, C E

    2001-01-01

    The tidal breathing model conservation of mass equations for the sinewave technique have been described for a homogeneous alveolar compartment by Gavaghan and Hahn, 1996 [Gavaghan, D.J., Hahn, C.E.W., 1996. A tidal breathing model of the forced inspired gas sinewave technique. Respir. Physiol. 106, 209-221]. We develop these equations first to a multi-discrete alveolar compartment lung model and then to a lung model with a continuous distribution of volume, ventilation and perfusion. The effect on the output parameters of a multi-compartment model is discussed, and the results are compared to those derived from the conventional continuous-ventilation model. Using the barely soluble gas argon as the tracer gas, an empirical index of alveolar inhomogeneity is presented which uses the end-expired and mixed-expired partial pressures on each breath. This index distinguishes between a narrow unimodal distribution of ventilation-volume, a wide unimodal distribution of ventilation-volume and a bimodal distribution of ventilation-volume. By using Monte Carlo simulations, this index is shown to be stable to experimental error of realistic magnitude.

  1. Numerical calculations of gaseous reacting flows in a model of gas turbine combustors

    NASA Astrophysics Data System (ADS)

    Yan, Chuanjun; Tang, Ming; Zhu, Huiling; Sun, Huixian

    1991-02-01

    The numerical calculations of gaseous reaction flows in a model of gas-turbine combustors are described. The profiles of hydrodynamic and thermodynamic patterns in a 3D combustor model are obtained by solving the governing differential transport equations. The well-established numerical prediction algorithm SIMPLE; a modified turbulence model, and a turbulent diffusion flame model are adopted in the computations. The beta-function is selected as the probability density function. The effect of the combustion process on flow patterns is investigated. The calculated results are verified by experiments, and are in good agreement.

  2. Physical model of the vapor-liquid (insulator-metal) transition in an exciton gas

    SciTech Connect

    Khomkin, A. L. Shumikhin, A. S.

    2015-04-15

    We propose a simple physical model describing the transition of an exciton gas to a conducting exciton liquid. The transition occurs due to cohesive coupling of excitons in the vicinity of the critical point, which is associated with transformation of the exciton ground state to the conduction band and the emergence of conduction electrons. We calculate the cohesion binding energy for the exciton gas and, using it, derive the equations of state, critical parameters, and binodal. The computational method is analogous to that used by us earlier [5] for predicting the vapor-liquid (insulator-metal) phase transition in atomic (hypothetical, free of molecules) hydrogen and alkali metal vapors. The similarity of the methods used for hydrogen and excitons makes it possible to clarify the physical nature of the transition in the exciton gas and to predict more confidently the existence of a new phase transition in atomic hydrogen.

  3. Using a direct simulation Monte Carlo approach to model collisions in a buffer gas cell.

    PubMed

    Doppelbauer, Maximilian J; Schullian, Otto; Loreau, Jerome; Vaeck, Nathalie; van der Avoird, Ad; Rennick, Christopher J; Softley, Timothy P; Heazlewood, Brianna R

    2017-01-28

    A direct simulation Monte Carlo (DSMC) method is applied to model collisions between He buffer gas atoms and ammonia molecules within a buffer gas cell. State-to-state cross sections, calculated as a function of the collision energy, enable the inelastic collisions between He and NH3 to be considered explicitly. The inclusion of rotational-state-changing collisions affects the translational temperature of the beam, indicating that elastic and inelastic processes should not be considered in isolation. The properties of the cold molecular beam exiting the cell are examined as a function of the cell parameters and operating conditions; the rotational and translational energy distributions are in accord with experimental measurements. The DSMC calculations show that thermalisation occurs well within the typical 10-20 mm length of many buffer gas cells, suggesting that shorter cells could be employed in many instances-yielding a higher flux of cold molecules.

  4. Some astrophysical implication of gas profiles in a new galaxy clusters model

    NASA Astrophysics Data System (ADS)

    Piedipalumbo, Ester; Cardone, V. F.; Tortora, C.

    2004-12-01

    The structure of the dark matter and the thermodynamical status of the hot gas in galaxy clusters is an interesting and widely discussed topic in modern astrophysics. Recently, Rasia et al. (2004) have proposed a new dynamical model of clusters of galaxies, which describes both the dark matter halo and the hot intracluster gas. We analyze the influence of the gas density and temperature profiles on the properties of the X-emission and the comptonization parameter that determines the CMBR temperature decrement due to the Sunyaev - Zel’dovich effect† .A complete traetment of this topic is found in Cardone V.F., Piedipalumbo E., Tortora C., 2005, A&A, 429, 49

  5. Using a direct simulation Monte Carlo approach to model collisions in a buffer gas cell

    NASA Astrophysics Data System (ADS)

    Doppelbauer, Maximilian J.; Schullian, Otto; Loreau, Jerome; Vaeck, Nathalie; van der Avoird, Ad; Rennick, Christopher J.; Softley, Timothy P.; Heazlewood, Brianna R.

    2017-01-01

    A direct simulation Monte Carlo (DSMC) method is applied to model collisions between He buffer gas atoms and ammonia molecules within a buffer gas cell. State-to-state cross sections, calculated as a function of the collision energy, enable the inelastic collisions between He and NH3 to be considered explicitly. The inclusion of rotational-state-changing collisions affects the translational temperature of the beam, indicating that elastic and inelastic processes should not be considered in isolation. The properties of the cold molecular beam exiting the cell are examined as a function of the cell parameters and operating conditions; the rotational and translational energy distributions are in accord with experimental measurements. The DSMC calculations show that thermalisation occurs well within the typical 10-20 mm length of many buffer gas cells, suggesting that shorter cells could be employed in many instances—yielding a higher flux of cold molecules.

  6. Modeling of gas generation from the Cameo coal zone in the Piceance Basin Colorado

    SciTech Connect

    Zhang, E.; Hill, R.J.; Katz, B.J.; Tang, Y.C.

    2008-08-15

    The gas generative potential of the Cretaceous Cameo coal in the Piceance Basin, northwestern Colorado, was evaluated quantitatively by sealed gold tube pyrolysis. The H/C and O/C elemental ratios show that pyrolyzed Cameo coal samples follow the Van Krevelen humic coal evolution pathway, reasonably simulating natural coal maturation. Kinetic parameters (activation energy and frequency factor) for gas generation and vitrinite reflectance (R{sub o}) changes were calculated from pyrolysis data. Experimental R{sub o} results from this study are not adequately predicted by published R{sub o} kinetics and indicate the necessity of deriving basin-specific kinetic parameters when building predictive basin models. Using derived kinetics for R{sub o}, evolution and gas generation, basin modeling was completed for 57 wells across the Piceance Basin, which enabled the mapping of coal-rank and coalbed gas potential. Quantities of methane generated at approximately 1.2% R{sub o} are about 300 standard cubic feet per ton (scf/ton) and more than 2500 scf/ton (in-situ dry-ash-free coal) at R{sub o}, values reaching 1.9%. Gases generated in both low- and high-maturity coals are less wet, whereas the wetter gas is expected where R{sub o} is approximately 1.4-1.5%. As controlled by regional coal rank and net coal thickness, the largest in-place coalbed gas resources are located in the central part of the basin, where predicted volumes exceed 150 bcf/mi, excluding gases in tight sands.

  7. Gas removal in the Ursa Minor Galaxy: Linking Hydrodynamics and Chemical Evolution Models

    NASA Astrophysics Data System (ADS)

    Caproni, Anderson; Amaral Lanfranchi, Gustavo; Campos Baio, Gabriel Henrique; Kowal, Grzegorz; Falceta-Gonçalves, Diego

    2017-04-01

    We present results from a non-cosmological, three-dimensional hydrodynamical simulation of the gas in the dwarf spheroidal galaxy Ursa Minor. Assuming an initial baryonic-to-dark-matter ratio derived from the cosmic microwave background radiation, we evolved the galactic gas distribution over 3 Gyr, taking into account the effects of the types Ia and II supernovae. For the first time, we used in our simulation the instantaneous supernovae rates derived from a chemical evolution model applied to spectroscopic observational data of Ursa Minor. We show that the amount of gas that is lost in this process is variable with time and radius, being the highest rates observed during the initial 600 Myr in our simulation. Our results indicate that types Ia and II supernovae must be essential drivers of the gas loss in Ursa Minor galaxy (and probably in other similar dwarf galaxies), but it is ultimately the combination of galactic winds powered by these supernovae and environmental effects (e.g., ram-pressure stripping) that results in the complete removal of the gas content.

  8. Atomistic modeling of structure II gas hydrate mechanics: Compressibility and equations of state

    NASA Astrophysics Data System (ADS)

    Vlasic, Thomas M.; Servio, Phillip; Rey, Alejandro D.

    2016-08-01

    This work uses density functional theory (DFT) to investigate the poorly characterized structure II gas hydrates, for various guests (empty, propane, butane, ethane-methane, propane-methane), at the atomistic scale to determine key structure and mechanical properties such as equilibrium lattice volume and bulk modulus. Several equations of state (EOS) for solids (Murnaghan, Birch-Murnaghan, Vinet, Liu) were fitted to energy-volume curves resulting from structure optimization simulations. These EOS, which can be used to characterize the compressional behaviour of gas hydrates, were evaluated in terms of their robustness. The three-parameter Vinet EOS was found to perform just as well if not better than the four-parameter Liu EOS, over the pressure range in this study. As expected, the Murnaghan EOS proved to be the least robust. Furthermore, the equilibrium lattice volumes were found to increase with guest size, with double-guest hydrates showing a larger increase than single-guest hydrates, which has significant implications for the widely used van der Waals and Platteeuw thermodynamic model for gas hydrates. Also, hydrogen bonds prove to be the most likely factor contributing to the resistance of gas hydrates to compression; bulk modulus was found to increase linearly with hydrogen bond density, resulting in a relationship that could be used predictively to determine the bulk modulus of various structure II gas hydrates. Taken together, these results fill a long existing gap in the material chemical physics of these important clathrates.

  9. Evolution of natural gas composition: Predictive multi-phase reaction-transport modeling

    SciTech Connect

    Ortoleva, P.J.; Chang, K.A.; Maxwell, J.M.

    1995-12-31

    A computational modeling approach is used to investigate reaction and transport processes affecting natural gas composition over geological time. Three basic stages are integrated -- gas generation from organic solids or liquids, interactions during source rock expulsion to the reservoir and reactions within the reservoir. Multi-phase dynamics is handled by solving the fully coupled problem of phase-to-phase transfer, intra-phase organic and inorganic reactions and redox and other reactions between fluid phase molecules and minerals. Effects of capillarity and relative permeability are accounted for. Correlations will be determined between gas composition, temperature history, the mineralogy of rocks with which the gas was in contact and the composition of source organic phases. Questions of H{sub 2}S scavenging by oxidizing minerals and the production or removal of CO{sub 2} are focused upon. Our three spatial dimensional, reaction-transport simulation approach has great promise for testing general concepts and as a practical tool for the exploration and production of natural gas.

  10. Numerical Model of Hydrate Formation and Dissociation With Free Gas Flow for a Global Inventory

    NASA Astrophysics Data System (ADS)

    Scandella, B.; Juanes, R.

    2009-12-01

    Methane hydrates hold great potential as an energy resource but also pose the threat, if they dissociate, of contributing to the greenhouse effect. In order to evaluate the risks and opportunities they present, we have developed a numerical model of hydrate formation and dissociation. This one-dimensional, continuum model is simple enough to be applied globally to estimate the total inventory of hydrate and trapped gas, yet captures multiphase flow effects not accounted for in previous inventory estimates. Preliminary results compare behavior regimes in typical active and passive continental margins, including fracture-dominated gas invasion, slow capillary invasion, and dynamic steady states. These results identify the key parameters that need to be estimated at a global scale in order to model the formation of current hydrate accumulations and their response to production and climate change.

  11. An improved computer model for prediction of axial gas turbine performance losses

    NASA Technical Reports Server (NTRS)

    Jenkins, R. M.

    1984-01-01

    The calculation model performs a rapid preliminary pitchline optimization of axial gas turbine annular flowpath geometry, as well as an initial estimate of blade profile shapes, given only a minimum of thermodynamic cycle requirements. No geometric parameters need be specified. The following preliminary design data are determined: (1) the optimum flowpath geometry, within mechanical stress limits; (2) initial estimates of cascade blade shapes; and (3) predictions of expected turbine performance. The model uses an inverse calculation technique whereby blade profiles are generated by designing channels to yield a specified velocity distribution on the two walls. Velocity distributions are then used to calculate the cascade loss parameters. Calculated blade shapes are used primarily to determine whether the assumed velocity loadings are physically realistic. Model verification is accomplished by comparison of predicted turbine geometry and performance with an array of seven NASA single-stage axial gas turbine configurations.

  12. Comparison of kinetic and equilibrium reaction models insimulating gas hydrate behavior in porous media

    SciTech Connect

    Kowalsky, Michael B.; Moridis, George J.

    2006-11-29

    In this study we compare the use of kinetic and equilibriumreaction models in the simulation of gas (methane) hydrate behavior inporous media. Our objective is to evaluate through numerical simulationthe importance of employing kinetic versus equilibrium reaction modelsfor predicting the response of hydrate-bearing systems to externalstimuli, such as changes in pressure and temperature. Specifically, we(1) analyze and compare the responses simulated using both reactionmodels for natural gas production from hydrates in various settings andfor the case of depressurization in a hydrate-bearing core duringextraction; and (2) examine the sensitivity to factors such as initialhydrate saturation, hydrate reaction surface area, and numericaldiscretization. We find that for large-scale systems undergoing thermalstimulation and depressurization, the calculated responses for bothreaction models are remarkably similar, though some differences areobserved at early times. However, for modeling short-term processes, suchas the rapid recovery of a hydrate-bearing core, kinetic limitations canbe important, and neglecting them may lead to significantunder-prediction of recoverable hydrate. The use of the equilibriumreaction model often appears to be justified and preferred for simulatingthe behavior of gas hydrates, given that the computational demands forthe kinetic reaction model far exceed those for the equilibrium reactionmodel.

  13. Hydrogen turbines for space power systems: A simplified axial flow gas turbine model

    NASA Technical Reports Server (NTRS)

    Hudson, Steven L.

    1988-01-01

    Hydrogen cooled, turbine powered space weapon systems require a relatively simple, but reasonably accurate hydrogen gas expansion turbine model. Such a simplified turbine model would require little computational time and allow incorporation into system level computer programs while providing reasonably accurate volume/mass estimates. This model would then allow optimization studies to be performed on multiparameter space power systems and provide improved turbine mass and size estimates for the various operating conditions (when compared to empirical and power law approaches). An axial flow gas expansion turbine model was developed for these reasons and is in use as a comparative bench mark in space power system studies at Sandia. The turbine model is based on fluid dynamic, thermodynamic, and material strength considerations, but is considered simplified because it does not account for design details such as boundary layer effects, shock waves, turbulence, stress concentrations, and seal leakage. Although the basic principles presented here apply to any gas or vapor axial flow turbine, hydrogen turbines are discussed because of their immense importance on space burst power platforms.

  14. Comparative Model Evaluation Studies of Biogenic Trace Gas Fluxes in Tropical Forests

    NASA Technical Reports Server (NTRS)

    Potter, C. S.; Peterson, David L. (Technical Monitor)

    1997-01-01

    Simulation modeling can play a number of important roles in large-scale ecosystem studies, including synthesis of patterns and changes in carbon and nutrient cycling dynamics, scaling up to regional estimates, and formulation of testable hypotheses for process studies. Recent comparative studies have shown that ecosystem models of soil trace gas exchange with the atmosphere are evolving into several distinct simulation approaches. Different levels of detail exist among process models in the treatment of physical controls on ecosystem nutrient fluxes and organic substrate transformations leading to gas emissions. These differences are is in part from distinct objectives of scaling and extrapolation. Parameter requirements for initialization scalings, boundary conditions, and time-series driven therefore vary among ecosystem simulation models, such that the design of field experiments for integration with modeling should consider a consolidated series of measurements that will satisfy most of the various model requirements. For example, variables that provide information on soil moisture holding capacity, moisture retention characteristics, potential evapotranspiration and drainage rates, and rooting depth appear to be of the first order in model evaluation trials for tropical moist forest ecosystems. The amount and nutrient content of labile organic matter in the soil, based on accurate plant production estimates, are also key parameters that determine emission model response. Based on comparative model results, it is possible to construct a preliminary evaluation matrix along categories of key diagnostic parameters and temporal domains. Nevertheless, as large-scale studied are planned, it is notable that few existing models age designed to simulate transient states of ecosystem change, a feature which will be essential for assessment of anthropogenic disturbance on regional gas budgets, and effects of long-term climate variability on biosphere-atmosphere exchange.

  15. A Frequency Model of Vibrational Processes in Gas-Turbine Drives of Compressor Stations of Main Gas Pipelines

    NASA Astrophysics Data System (ADS)

    Chekardovskiy, M. N.; Chekardovskiy, S. M.; Razboynikov, A. A.; Ponomareva, T. G.

    2016-10-01

    At compressor stations, systematic measurements of noise and vibration of power equipment - gas compressor units - are carried out. The article presents basic equations for calculating natural and forced frequencies at which the main defects appear. According to the studied dependences, results of calculations are obtained on the following types of drives for gas-compressor units GTK-10-4, Avon-1534, DG-90.

  16. Numerical Modeling of Reactive Multiphase Flow for FCC and Hot Gas Desulfurization Circulating Fluidized Beds

    SciTech Connect

    Miller, Aubrey L.

    2005-07-01

    This work was carried out to understand the behavior of the solid and gas phases in a CFB riser. Only the riser is modeled as a straight pipe. A model with linear algebraic approximation to solids viscosity of the form, {musubs} = 5.34{epsisubs}, ({espisubs} is the solids volume fraction) with an appropriate boundary condition at the wall obtained by approximate momentum balance solution at the wall to acount for the solids recirculation is tested against experimental results. The work done was to predict the flow patterns in the CFB risers from available experimental data, including data from a 7.5-cm-ID CFB riser at the Illinois Institute of Technology and data from a 20.0-cm-ID CFB riser at the Particulate Solid Research, Inc., facility. This research aims at modeling the removal of hydrogen sulfide from hot coal gas using zinc oxide as the sorbent in a circulating fluidized bed and in the process indentifying the parameters that affect the performance of the sulfidation reactor. Two different gas-solid reaction models, the unreacted shrinking core (USC) and the grain model were applied to take into account chemical reaction resistances. Also two different approaches were used to affect the hydrodynamics of the process streams. The first model takes into account the effect of micro-scale particle clustering by adjusting the gas-particle drag law and the second one assumes a turbulent core with pseudo-steady state boundary condition at the wall. A comparison is made with experimental results.

  17. Modeling to Evaluate Contribution of Oil and Gas Emissions to Air Pollution.

    PubMed

    Thompson, Tammy M; Shepherd, Donald; Stacy, Andrea; Barna, Michael G; Schichtel, Bret A

    2017-04-01

    Oil and gas production in the Western United States has increased considerably over the past 10 years. While many of the still limited oil and gas impact assessments have focused on potential human health impacts, the typically remote locations of production in the Intermountain West suggests that the impacts of oil and gas production on national parks and wilderness areas (Class I and II areas) could also be important. To evaluate this, we utilize the Comprehensive Air quality Model with Extensions (CAMx) with a year-long modeling episode representing the best available representation of 2011 meteorology and emissions for the Western United States. The model inputs for the 2011 episodes were generated as part of the Three State Air Quality Study (3SAQS). The study includes a detailed assessment of oil and gas (O&G) emissions in Western States. The year-long modeling episode was run both with and without emissions from O&G production. The difference between these two runs provides an estimate of the contribution of the O&G production to air quality. These data were used to assess the contribution of O&G to the 8 hour average ozone concentrations, daily and annual fine particulate concentrations, annual nitrogen deposition totals and visibility in the modeling domain. We present the results for the Class I and II areas in the Western United States. Modeling results suggest that emissions from O&G activity are having a negative impact on air quality and ecosystem health in our National Parks and Class I areas.

  18. Numerical modeling of landfill gas and heat transport in the deformable MSW landfill body. Part 1. Development of the model

    NASA Astrophysics Data System (ADS)

    Kutsyi, D. V.

    2015-06-01

    The article is devoted to studying the parameters of wells that are used as part of vertical gas extraction systems for degassing landfills. To this end, approaches to modeling the main processes occurring in the landfill's porous medium are considered. The considered approaches served as a basis for elaborating a thermophysical gas and heat transport model that takes into account variation in the hydrodynamic properties of wastes resulting from their secondary settlement. The adequacy of the results obtained using the developed model is confirmed by the data of classic works. The effect the secondary settlement of wastes has on the distribution of pressure and temperature in the landfill body is determined. It is shown that compaction of wastes due to their secondary settlement results in a growth of pressure by 40% on the average.

  19. A stochastic equilibrium model for the North American natural gas market

    NASA Astrophysics Data System (ADS)

    Zhuang, Jifang

    This dissertation is an endeavor in the field of energy modeling for the North American natural gas market using a mixed complementarity formulation combined with the stochastic programming. The genesis of the stochastic equilibrium model presented in this dissertation is the deterministic market equilibrium model developed in [Gabriel, Kiet and Zhuang, 2005]. Based on some improvements that we made to this model, including proving new existence and uniqueness results, we present a multistage stochastic equilibrium model with uncertain demand for the deregulated North American natural gas market using the recourse method of the stochastic programming. The market participants considered by the model are pipeline operators, producers, storage operators, peak gas operators, marketers and consumers. Pipeline operators are described with regulated tariffs but also involve "congestion pricing" as a mechanism to allocate scarce pipeline capacity. Marketers are modeled as Nash-Cournot players in sales to the residential and commercial sectors but price-takers in all other aspects. Consumers are represented by demand functions in the marketers' problem. Producers, storage operators and peak gas operators are price-takers consistent with perfect competition. Also, two types of the natural gas markets are included: the long-term and spot markets. Market participants make both high-level planning decisions (first-stage decisions) in the long-term market and daily operational decisions (recourse decisions) in the spot market subject to their engineering, resource and political constraints, resource constraints as well as market constraints on both the demand and the supply side, so as to simultaneously maximize their expected profits given others' decisions. The model is shown to be an instance of a mixed complementarity problem (MiCP) under minor conditions. The MiCP formulation is derived from applying the Karush-Kuhn-Tucker optimality conditions of the optimization problems

  20. Consistent dust and gas models for protoplanetary disks. I. Disk shape, dust settling, opacities, and PAHs

    NASA Astrophysics Data System (ADS)

    Woitke, P.; Min, M.; Pinte, C.; Thi, W.-F.; Kamp, I.; Rab, C.; Anthonioz, F.; Antonellini, S.; Baldovin-Saavedra, C.; Carmona, A.; Dominik, C.; Dionatos, O.; Greaves, J.; Güdel, M.; Ilee, J. D.; Liebhart, A.; Ménard, F.; Rigon, L.; Waters, L. B. F. M.; Aresu, G.; Meijerink, R.; Spaans, M.

    2016-02-01

    We propose a set of standard assumptions for the modelling of Class II and III protoplanetary disks, which includes detailed continuum radiative transfer, thermo-chemical modelling of gas and ice, and line radiative transfer from optical to cm wavelengths. The first paper of this series focuses on the assumptions about the shape of the disk, the dust opacities, dust settling, and polycyclic aromatic hydrocarbons (PAHs). In particular, we propose new standard dust opacities for disk models, we present a simplified treatment of PAHs in radiative equilibrium which is sufficient to reproduce the PAH emission features, and we suggest using a simple yet physically justified treatment of dust settling. We roughly adjust parameters to obtain a model that predicts continuum and line observations that resemble typical multi-wavelength continuum and line observations of Class II T Tauri stars. We systematically study the impact of each model parameter (disk mass, disk extension and shape, dust settling, dust size and opacity, gas/dust ratio, etc.) on all mainstream continuum and line observables, in particular on the SED, mm-slope, continuum visibilities, and emission lines including [OI] 63 μm, high-J CO lines, (sub-)mm CO isotopologue lines, and CO fundamental ro-vibrational lines. We find that evolved dust properties, i.e. large grains, often needed to fit the SED, have important consequences for disk chemistry and heating/cooling balance, leading to stronger near- to far-IR emission lines in general. Strong dust settling and missing disk flaring have similar effects on continuum observations, but opposite effects on far-IR gas emission lines. PAH molecules can efficiently shield the gas from stellar UV radiation because of their strong absorption and negligible scattering opacities in comparison to evolved dust. The observable millimetre-slope of the SED can become significantly more gentle in the case of cold disk midplanes, which we find regularly in our T Tauri models

  1. Carbon dioxide stripping in aquaculture -- part II: development of gas transfer models

    USGS Publications Warehouse

    Colt, John; Watten, Barnaby; Pfeiffer, Tim

    2012-01-01

    The basic mass transfer equation for gases such as oxygen and carbon dioxide can be derived from integration of the driving force equation. Because of the physical characteristics of the gas transfer processes, slightly different models are used for aerators tested under the non steady-state procedures, than for packed columns, or weirs. It is suggested that the standard condition for carbon dioxide should be 20 °C, 1 atm, CCO2=20 mg/kg, and XCO2=0.000285. The selection of the standard condition for carbon dioxide based on a fixed mole fraction ensures that standardized carbon dioxide transfer rates will be comparable even though the value of C*CO2 in the atmosphere is increasing with time. The computation of mass transfer for carbon dioxide is complicated by the impact of water depth and gas phase enrichment on the saturation concentration within the unit, although the importance of either factor depends strongly on the specific type of aerator. For some types of aerators, the most accurate gas phase model remains to be determined for carbon dioxide. The assumption that carbon dioxide can be treated as a non-reactive gas in packed columns may apply for cold acidic waters but not for warm alkaline waters.

  2. Atmosphere behavior in gas-closed mouse-algal systems: An experimental and modelling study

    NASA Astrophysics Data System (ADS)

    Averner, Maurice M.; Moore, Berrien; Bartholomew, Irene; Wharton, Robert

    Concepts of biologically-based regenerative life support systems anticipate the use of photosynthetic organisms for air revitalization. However, mismatches in the rates of production and uptake of oxygen or carbon dioxide between the crew and the plants will lead to an accumulation or depletion of these gases beyond tolerable limits. One method for correcting these atmospheric changes is to use physicochemical devices. This would conflict with the constraint of minimal size and weight imposed upon the successful development of a competitive bioregenerative system. An alternate control strategy is based upon reducing the gas exchange mismatch by manipulation of those environmental parameters known to affect plant or algae gas exchange ratios. We have initiated a research program using a dual approach of mathematical modelling and laboratory experimentation aimed at examining the gas exchange characteristics of artificial animal/plant systems closed to the ambient atmosphere. Our goal is to develop control techniques and management strategies for maintaining the atmospheric levels of carbon dioxide and oxygen at physiological levels. A mathematical model simulating the atmospheric behavior in these systems has been developed and an experimental gas-closed system has been constructed. These will be described and preliminary results will be presented.

  3. Sub-grid drag models for horizontal cylinder arrays immersed in gas-particle multiphase flows

    SciTech Connect

    Sarkar, Avik; Sun, Xin; Sundaresan, Sankaran

    2013-09-08

    Immersed cylindrical tube arrays often are used as heat exchangers in gas-particle fluidized beds. In multiphase computational fluid dynamics (CFD) simulations of large fluidized beds, explicit resolution of small cylinders is computationally infeasible. Instead, the cylinder array may be viewed as an effective porous medium in coarse-grid simulations. The cylinders' influence on the suspension as a whole, manifested as an effective drag force, and on the relative motion between gas and particles, manifested as a correction to the gas-particle drag, must be modeled via suitable sub-grid constitutive relationships. In this work, highly resolved unit-cell simulations of flow around an array of horizontal cylinders, arranged in a staggered configuration, are filtered to construct sub-grid, or `filtered', drag models, which can be implemented in coarse-grid simulations. The force on the suspension exerted by the cylinders is comprised of, as expected, a buoyancy contribution, and a kinetic component analogous to fluid drag on a single cylinder. Furthermore, the introduction of tubes also is found to enhance segregation at the scale of the cylinder size, which, in turn, leads to a reduction in the filtered gas-particle drag.

  4. Finite Element Modeling of Adsorption Processes for Gas Separation and Purification

    SciTech Connect

    Humble, Paul H.; Williams, Richard M.; Hayes, James C.

    2009-09-22

    Pacific Northwest National Laboratory (PNNL) has expertise in the design and fabrication of automated radioxenon collection systems for nuclear explosion monitoring. In developing new systems there is an ever present need to reduce size, power consumption and complexity. Most of these systems have used adsorption based techniques for gas collection and/or concentration and purification. These processes include pressure swing adsorption, vacuum swing adsorption, temperature swing adsorption, gas chromatography and hybrid processes that combine elements of these techniques. To better understand these processes, and help with the development of improved hardware, a finite element software package (COMSOL Multiphysics) has been used to develop complex models of these adsorption based operations. The partial differential equations used include a mass balance for each gas species and adsorbed species along with a convection conduction energy balance equation. These equations in conjunction with multicomponent temperature dependent isotherm models are capable of simulating separation processes ranging from complex multibed PSA processes, and multicomponent temperature programmed gas chromatography, to simple two component temperature swing adsorption. These numerical simulations have been a valuable tool for assessing the capability of proposed processes and optimizing hardware and process parameters.

  5. Relaxation limit of a compressible gas-liquid model with well-reservoir interaction

    NASA Astrophysics Data System (ADS)

    Solem, Susanne; Evje, Steinar

    2017-02-01

    This paper deals with the relaxation limit of a two-phase compressible gas-liquid model which contains a pressure-dependent well-reservoir interaction term of the form q (P_r - P) where q>0 is the rate of the pressure-dependent influx/efflux of gas, P is the (unknown) wellbore pressure, and P_r is the (known) surrounding reservoir pressure. The model can be used to study gas-kick flow scenarios relevant for various wellbore operations. One extreme case is when the wellbore pressure P is largely dictated by the surrounding reservoir pressure P_r. Formally, this model is obtained by deriving the limiting system as the relaxation parameter q in the full model tends to infinity. The main purpose of this work is to understand to what extent this case can be represented by a well-defined mathematical model for a fixed global time T>0. Well-posedness of the full model has been obtained in Evje (SIAM J Math Anal 45(2):518-546, 2013). However, as the estimates for the full model are dependent on the relaxation parameter q, new estimates must be obtained for the equilibrium model to ensure existence of solutions. By means of appropriate a priori assumptions and some restrictions on the model parameters, necessary estimates (low order and higher order) are obtained. These estimates that depend on the global time T together with smallness assumptions on the initial data are then used to obtain existence of solutions in suitable Sobolev spaces.

  6. He Interpolation Gas Thermometry with Different Virial Coefficients and Gas Densities and Model Calculation of a Temperature Profile with Radiative Heat Transfer

    NASA Astrophysics Data System (ADS)

    Tamura, O.; Nakano, T.; Takasu, S.

    2015-08-01

    He interpolating constant-volume gas thermometer scales are compared using different virial coefficients and gas densities for a temperature range of 3 K to the triple point of Ne (24.5561 K). The differences between the International Temperature Scale of 1990 (ITS-90) and the interpolation scale, which follows the definition of the ITS-90 but uses the second and third virial coefficients of the recent ab initio calculations, have maxima of about 0.08 mK and 0.13 mK for gas densities of and , respectively. The differences between the ITS-90 and the interpolation scale using only the ab initio second virial coefficient have maxima of about 0.08 mK and 0.14 mK for the same respective sequence of gas densities. The ITS-90 temperatures obtained in eight runs with gas densities from to agree with a polynomial of the resistance of a rhodium-iron resistance thermometer within 0.2 mK. To calculate the temperature profile along the pressure-sensing tube connecting the low temperature part of the constant-volume gas thermometer to room temperature, a calculation model is proposed that takes into account not only the thermal conductivity of the tube wall but also the radiative heat transfer between the tube and the vacuum jacket enclosing it. The calculation results of this model approximate the measured profile better than the conventional calculations that neglect the radiative heat transfer.

  7. Sabots, Obturator and Gas-In-Launch Tube Techniques for Heat Flux Models in Ballistic Ranges

    NASA Technical Reports Server (NTRS)

    Bogdanoff, David W.; Wilder, Michael C.

    2013-01-01

    For thermal protection system (heat shield) design for space vehicle entry into earth and other planetary atmospheres, it is essential to know the augmentation of the heat flux due to vehicle surface roughness. At the NASA Ames Hypervelocity Free Flight Aerodynamic Facility (HFFAF) ballistic range, a campaign of heat flux studies on rough models, using infrared camera techniques, has been initiated. Several phenomena can interfere with obtaining good heat flux data when using this measuring technique. These include leakage of the hot drive gas in the gun barrel through joints in the sabot (model carrier) to create spurious thermal imprints on the model forebody, deposition of sabot material on the model forebody, thereby changing the thermal properties of the model surface and unknown in-barrel heating of the model. This report presents developments in launch techniques to greatly reduce or eliminate these problems. The techniques include the use of obturator cups behind the launch package, enclosed versus open front sabot designs and the use of hydrogen gas in the launch tube. Attention also had to be paid to the problem of the obturator drafting behind the model and impacting the model. Of the techniques presented, the obturator cups and hydrogen in the launch tube were successful when properly implemented

  8. Development of a multiscale thermal conductivity model for fission gas in UO2

    NASA Astrophysics Data System (ADS)

    Tonks, Michael R.; Liu, Xiang-Yang; Andersson, David; Perez, Danielle; Chernatynskiy, Aleksandr; Pastore, Giovanni; Stanek, Christopher R.; Williamson, Richard

    2016-02-01

    Accurately predicting changes in the thermal conductivity of light water reactor UO2 fuel throughout its lifetime in reactor is an essential part of fuel performance modeling. However, typical thermal conductivity models from the literature are empirical. In this work, we begin to develop a mechanistic thermal conductivity model by focusing on the impact of gaseous fission products, which is coupled to swelling and fission gas release. The impact of additional defects and fission products will be added in future work. The model is developed using a combination of atomistic and mesoscale simulation, as well as analytical models. The impact of dispersed fission gas atoms is quantified using molecular dynamics simulations corrected to account for phonon-spin scattering. The impact of intragranular bubbles is accounted for using an analytical model that considers phonon scattering. The impact of grain boundary bubbles is determined using a simple model with five thermal resistors that are parameterized by comparing to 3D mesoscale heat conduction results. When used in the BISON fuel performance code to model four reactor experiments, it produces reasonable predictions without having been fit to fuel thermocouple data.

  9. A simple accretion model of a rotating gas sphere onto a Schwarzschild black hole

    NASA Astrophysics Data System (ADS)

    Huerta, E. A.; Mendoza, S.

    2007-04-01

    We construct a simple accretion model of a rotating gas sphere onto a Schwarzschild black hole. We show how to build analytic solutions in terms of Jacobi elliptic functions. This construction represents a general relativistic generalisation of the Newtonian accretion model first proposed by Ulrich (1976). In exactly the same form as it occurs for the Newtonian case, the flow naturally predicts the existence of an equatorial rotating accretion disc about the hole. However, the radius of the disc increases monotonically without limit as the flow reaches its minimum allowed angular momentum for this particular model.

  10. A non-empirical gas slippage model for low to moderate Knudsen numbers

    NASA Astrophysics Data System (ADS)

    Wang, Shihao; Lukyanov, Alexander A.; Wang, Lei; Wu, Yu-Shu; Pomerantz, Andrew; Xu, Wenyue; Kleinberg, Robert

    2017-01-01

    In this study, we present a novel derivation of the gas slip flow boundary condition within micro- and nano-flow channels. The newly derived boundary condition is of second order. Our model is based on the kinetic theory of gases. The slippage condition is obtained via the calculation of the shear stress in a confined micro-channel. We have benchmarked the mass transfer rate predicted by our model with existing numerical and physical experimental data, and the new model matches experiments within 10%.

  11. Collective Tunneling Model between Two-Dimensional Electron Gas to Si-Nano Dot

    NASA Astrophysics Data System (ADS)

    Muraguchi, M.; Sakurai, Y.; Takada, Y.; Nomura, S.; Shiraishi, K.; Makihara, K.; Ikeda, M.; Miyazaki, S.; Shigeta, Y.; Endoh, T.

    2011-12-01

    We study the temperature dependence of electron injection voltage in Si-Nano-Dot (Si-NDs) Floating Gate MOS capacitor by using the collective tunneling model, which models the tunneling between two-dimensional electron gas (2DEG) and the Si-NDs. We clarify the temperature dependence by numerical calculation, which emulate the experiment in this system, and we obtained a new insight into the origin of the temperature dependence. We have revealed that the collective tunneling model can reproduce the temperature dependence of electron tunneling.

  12. Non-thermal plasma destruction of allyl alcohol in waste gas: kinetics and modelling

    NASA Astrophysics Data System (ADS)

    DeVisscher, A.; Dewulf, J.; Van Durme, J.; Leys, C.; Morent, R.; Van Langenhove, H.

    2008-02-01

    Non-thermal plasma treatment is a promising technique for the destruction of volatile organic compounds in waste gas. A relatively unexplored technique is the atmospheric negative dc multi-pin-to-plate glow discharge. This paper reports experimental results of allyl alcohol degradation and ozone production in this type of plasma. A new model was developed to describe these processes quantitatively. The model contains a detailed chemical degradation scheme, and describes the physics of the plasma by assuming that the fraction of electrons that takes part in chemical reactions is an exponential function of the reduced field. The model captured the experimental kinetic data to less than 2 ppm standard deviation.

  13. Thermo-mechanical modelling of cyclic gas storage applications in salt caverns

    NASA Astrophysics Data System (ADS)

    Böttcher, Norbert; Watanabe, Norihiro; Görke, Uwe-Jens; Kolditz, Olaf; Nagel, Thomas

    2016-04-01

    Due to the growing importance of renewable energy sources it becomes more and more necessary to investigate energy storage potentials. One major way to store energy is the power-to-gas concept. Excessive electrical energy can be used either to produce hydrogen or methane by electrolysis or methanation or to compress air, respectively. Those produced gases can then be stored in artificial salt caverns, which are constructed in large salt formations by solution mining. In combination with renewable energy sources, the power-to-gas concept is subjected to fluctuations. Compression and expansion of the storage gases lead to temperature differences within the salt rock. The variations can advance several metres into the host rock, influencing its material behaviour, inducing thermal stresses and altering the creep response. To investigate the temperature influence on the cavern capacity, we have developed a numerical model to simulate the thermo-mechanical behaviour of salt caverns during cyclic gas storage. The model considers the thermodynamic behaviour of the stored gases as well as the heat transport and the temperature dependent material properties of the host rock. Therefore, we utilized well-known constitutive thermo-visco-plastic material models, implemented into the open source-scientific software OpenGeoSys. Both thermal and mechanical processes are solved using a finite element approach, connected via a staggered coupling scheme. The model allows the assessment of the structural safety as well as the convergence of the salt caverns.

  14. Modeling Sulfides, pH and Hydrogen Sulfide Gas in the Sewers of San Francisco.

    PubMed

    Vollertsen, Jes; Revilla, Nohemy; Hvitved-Jacobsen, Thorkild; Nielsen, Asbjørn Haaning

    2015-11-01

    An extensive measuring campaign targeted on sewer odor problems was undertaken in San Francisco. It was assessed whether a conceptual sewer process model could reproduce the measured concentrations of total sulfide in the wastewater and H2S gas in the sewer atmosphere, and to which degree such simulations have potential for further improving odor and sulfide management. The campaign covered measurement of wastewater sulfide by grab sampling and diurnal sampling, and H2S gas in the sewer atmosphere was logged. The tested model was based on the Wastewater Aerobic/Anaerobic Transformations in Sewers (WATS) sewer process concept, which never had been calibrated to such an extensive dataset. The study showed that the model was capable of reproducing the general levels of wastewater sulfide, wastewater pH, and sewer H2S gas. It could also reproduce the general variability of these parameters, albeit with some uncertainty. It was concluded that the model could be applied for the purpose in mind.

  15. Development of a natural gas systems analysis model (GSAM). Annual report, January 1994--January 1995

    SciTech Connect

    1994-07-01

    The objective of GSAM development is to create a comprehensive, non-proprietary, microcomputer model of the North American natural gas system. GSAM explicitly evaluates the key components of the system, including the resource base, exploration and development practices, extraction technology performance and costs, project economics, transportation costs and restrictions, storage, and end-use. The primary focus is the detailed characterization of the resource base at the reservoir and sub-reservoir level. This disaggregation allows direct evaluation of alternative extraction technologies based on discretely estimated, individual well productivity, required investments, and associated operating costs. GSAM`s design allows users to evaluate complex interactions of current and alternative future technology and policy initiatives as they directly impact the gas market. Key activities completed during the past year include: conducted a comparative analysis of commercial reservoir databases; licensed and screened NRG Associates Significant Oil and Gas Fields of the US reservoir database; developed and tested reduced form reservoir model production type curves; fully developed database structures for use in GSAM and linkage to other systems; developed a methodology for the exploration module; collected and updated upstream capital and operating cost parameters; completed initial integration of downstream/demand models; presented research results at METC Contractor Review Meeting; conducted other briefings for METC managers, including initiation of the GSAM Environmental Module; and delivered draft topical reports on technology review, model review, and GSAM methodology.

  16. New higher-order Godunov code for modelling performance of two-stage light gas guns

    NASA Technical Reports Server (NTRS)

    Bogdanoff, D. W.; Miller, R. J.

    1995-01-01

    A new quasi-one-dimensional Godunov code for modeling two-stage light gas guns is described. The code is third-order accurate in space and second-order accurate in time. A very accurate Riemann solver is used. Friction and heat transfer to the tube wall for gases and dense media are modeled and a simple nonequilibrium turbulence model is used for gas flows. The code also models gunpowder burn in the first-stage breech. Realistic equations of state (EOS) are used for all media. The code was validated against exact solutions of Riemann's shock-tube problem, impact of dense media slabs at velocities up to 20 km/sec, flow through a supersonic convergent-divergent nozzle and burning of gunpowder in a closed bomb. Excellent validation results were obtained. The code was then used to predict the performance of two light gas guns (1.5 in. and 0.28 in.) in service at the Ames Research Center. The code predictions were compared with measured pressure histories in the powder chamber and pump tube and with measured piston and projectile velocities. Very good agreement between computational fluid dynamics (CFD) predictions and measurements was obtained. Actual powder-burn rates in the gun were found to be considerably higher (60-90 percent) than predicted by the manufacturer and the behavior of the piston upon yielding appears to differ greatly from that suggested by low-strain rate tests.

  17. Model of Motion and Sedimentation of a Charged Gas Suspension in an Electric Field

    NASA Astrophysics Data System (ADS)

    Tukmakov, A. L.

    2014-01-01

    We have constructed a model of the dynamics of a charged gas suspension moving in an electric field under the action of interphase friction and Coulomb forces and used it to describe the process of powder coloration. The model incorporates the equations of motion of the carrier and dispersed phases obtained with account for the interphase momentum and energy exchange. The carrier medium is described by a system of Reynolds-averaged Navier-Stokes equations for a compressible heat-conducting gas with a Spalart-Allmaras model. The dispersed phase is given by the mass equation with account for the turbulent diffusion and by the conservation equations of momentum components with account for the action of the Coulomb force and aerodynamic friction, as well as by the internal energy equation. The system is written in generalized coordinates in dimensionless form and is solved by the explicit McCormack method with splitting into spatial directions and by the nonlinear correction scheme. The model is used to investigate the velocity and density fields of the gas suspension in the interelectrode space near the surface on which the powder is deposited.

  18. A compressible two-layer model for transient gas-liquid flows in pipes

    NASA Astrophysics Data System (ADS)

    Demay, Charles; Hérard, Jean-Marc

    2017-03-01

    This work is dedicated to the modeling of gas-liquid flows in pipes. As a first step, a new two-layer model is proposed to deal with the stratified regime. The starting point is the isentropic Euler set of equations for each phase where the classical hydrostatic assumption is made for the liquid. The main difference with the models issued from the classical literature is that the liquid as well as the gas is assumed compressible. In that framework, an averaging process results in a five-equation system where the hydrostatic constraint has been used to define the interfacial pressure. Closure laws for the interfacial velocity and source terms such as mass and momentum transfer are provided following an entropy inequality. The resulting model is hyperbolic with non-conservative terms. Therefore, regarding the homogeneous part of the system, the definition and uniqueness of jump conditions is studied carefully and acquired. The nature of characteristic fields and the corresponding Riemann invariants are also detailed. Thus, one may build analytical solutions for the Riemann problem. In addition, positivity is obtained for heights and densities. The overall derivation deals with gas-liquid flows through rectangular channels, circular pipes with variable cross section and includes vapor-liquid flows.

  19. A shallow water model for dense gas simulation in urban areas

    SciTech Connect

    Brown, Michael; Williams, Mike D; Gowardhan, Akshay; Brambilla, Sara; Manca, Davide

    2009-01-01

    Large quantities of toxic chemicals are stored at industrial facilities and transported around the country via train and truck. In the event of an accidental release, many of these chemicals are released as heavier-than-air gases that stay low to the ground as they are transported by the wind . Breathing height concentrations can remain high due to reduced vertical mixing and hazard zone coverage area can be larger due to near-source gravitational slumping . A number of fast-response dense gas dispersion models have been developed and are routinely used to deal with heavier-than-air releases over unobstructed terrain. If a release were to occur in a built-up environment, however, the effects of buildings and other obstacles will significantly alter the initial spreading, the transport direction, and the amount of mixing of the dense gas cloud . We have developed a new fast-running dense gas dispersion model that is intended for handling releases in cities and at large industrial facilities. In this paper we describe the scheme employed and how the model has been integrated into the Quick Urban & Industrial Complex (QUIC) dispersion modeling system.

  20. System Modeling and Building Energy Simulations of Gas Engine Driven Heat Pump

    SciTech Connect

    Mahderekal, Isaac; Vineyard, Edward

    2013-01-01

    To improve the system performance of a gas engine driven heat pump (GHP) system, an analytical modeling and experimental study has been made by using desiccant system in cooling operation (particularly in high humidity operations) and suction line waste heat recovery to augment heating capacity and efficiency. The performance of overall GHP system has been simulated with a detailed vapor compression heat pump system design model. The modeling includes: (1) GHP cycle without any performance improvements (suction liquid heat exchange and heat recovery) as a baseline (both in cooling and heating mode), (2) the GHP cycle in cooling mode with desiccant system regenerated by waste heat from engine incorporated, (3) GHP cycle in heating mode with heat recovery (recovered heat from engine). According to the system modeling results, by using the desiccant system the sensible heat ratio (SHR- sensible heat ratio) can be lowered to 40%. The waste heat of the gas engine can boost the space heating efficiency by 25% at rated operating conditions. In addtion,using EnergyPlus, building energy simulations have been conducted to assess annual energy consumptions of GHP in sixteen US cities, and the performances are compared to a baseline unit, which has a electrically-driven air conditioner with the seasonal COP of 4.1 for space cooling and a gas funace with 90% fuel efficiency for space heating.

  1. Comparison of the Results of Modeling the Flame Propagation in a Hybrid Gas Suspension with Experimental Data

    NASA Astrophysics Data System (ADS)

    Dement‧ev, A. A.; Moiseeva, K. M.; Krainov, Y. Yu.; Paleev, D. Yu.

    2016-11-01

    This article considers the laminary combustion of a hybrid gas suspension consisting of a gaseous combustible, an oxidizer, and an inert gas, as well as particles capable of interacting with the gas-phase oxidizer. The mathematical model takes into account the thermal expansion of the gas and its related relative motion of particles. The problem has been solved numerically in dimensionless variables. The dependences of the steady velocity of the flame front on the initial concentration of the combustible in the gas phase at various values of the parameters of the dispersed phase are presented. A comparison has been made between experimental and calculated data for a gas suspension consisting of a gaseous oxidizer, an inert gas, and reactive particles.

  2. Constraining Methane Emissions from Natural Gas Production in Northeastern Pennsylvania Using Aircraft Observations and Mesoscale Modeling

    NASA Astrophysics Data System (ADS)

    Barkley, Z.; Davis, K.; Lauvaux, T.; Miles, N.; Richardson, S.; Martins, D. K.; Deng, A.; Cao, Y.; Sweeney, C.; Karion, A.; Smith, M. L.; Kort, E. A.; Schwietzke, S.

    2015-12-01

    Leaks in natural gas infrastructure release methane (CH4), a potent greenhouse gas, into the atmosphere. The estimated fugitive emission rate associated with the production phase varies greatly between studies, hindering our understanding of the natural gas energy efficiency. This study presents a new application of inverse methodology for estimating regional fugitive emission rates from natural gas production. Methane observations across the Marcellus region in northeastern Pennsylvania were obtained during a three week flight campaign in May 2015 performed by a team from the National Oceanic and Atmospheric Administration (NOAA) Global Monitoring Division and the University of Michigan. In addition to these data, CH4 observations were obtained from automobile campaigns during various periods from 2013-2015. An inventory of CH4 emissions was then created for various sources in Pennsylvania, including coalmines, enteric fermentation, industry, waste management, and unconventional and conventional wells. As a first-guess emission rate for natural gas activity, a leakage rate equal to 2% of the natural gas production was emitted at the locations of unconventional wells across PA. These emission rates were coupled to the Weather Research and Forecasting model with the chemistry module (WRF-Chem) and atmospheric CH4 concentration fields at 1km resolution were generated. Projected atmospheric enhancements from WRF-Chem were compared to observations, and the emission rate from unconventional wells was adjusted to minimize errors between observations and simulation. We show that the modeled CH4 plume structures match observed plumes downwind of unconventional wells, providing confidence in the methodology. In all cases, the fugitive emission rate was found to be lower than our first guess. In this initial emission configuration, each well has been assigned the same fugitive emission rate, which can potentially impair our ability to match the observed spatial variability

  3. Revisiting low-fidelity two-fluid models for gas-solids transport

    NASA Astrophysics Data System (ADS)

    Adeleke, Najeem; Adewumi, Michael; Ityokumbul, Thaddeus

    2016-08-01

    Two-phase gas-solids transport models are widely utilized for process design and automation in a broad range of industrial applications. Some of these applications include proppant transport in gaseous fracking fluids, air/gas drilling hydraulics, coal-gasification reactors and food processing units. Systems automation and real time process optimization stand to benefit a great deal from availability of efficient and accurate theoretical models for operations data processing. However, modeling two-phase pneumatic transport systems accurately requires a comprehensive understanding of gas-solids flow behavior. In this study we discuss the prevailing flow conditions and present a low-fidelity two-fluid model equation for particulate transport. The model equations are formulated in a manner that ensures the physical flux term remains conservative despite the inclusion of solids normal stress through the empirical formula for modulus of elasticity. A new set of Roe-Pike averages are presented for the resulting strictly hyperbolic flux term in the system of equations, which was used to develop a Roe-type approximate Riemann solver. The resulting scheme is stable regardless of the choice of flux-limiter. The model is evaluated by the prediction of experimental results from both pneumatic riser and air-drilling hydraulics systems. We demonstrate the effect and impact of numerical formulation and choice of numerical scheme on model predictions. We illustrate the capability of a low-fidelity one-dimensional two-fluid model in predicting relevant flow parameters in two-phase particulate systems accurately even under flow regimes involving counter-current flow.

  4. Gas Core Reactor Numerical Simulation Using a Coupled MHD-MCNP Model

    NASA Technical Reports Server (NTRS)

    Kazeminezhad, F.; Anghaie, S.

    2008-01-01

    Analysis is provided in this report of using two head-on magnetohydrodynamic (MHD) shocks to achieve supercritical nuclear fission in an axially elongated cylinder filled with UF4 gas as an energy source for deep space missions. The motivation for each aspect of the design is explained and supported by theory and numerical simulations. A subsequent report will provide detail on relevant experimental work to validate the concept. Here the focus is on the theory of and simulations for the proposed gas core reactor conceptual design from the onset of shock generations to the supercritical state achieved when the shocks collide. The MHD model is coupled to a standard nuclear code (MCNP) to observe the neutron flux and fission power attributed to the supercritical state brought about by the shock collisions. Throughout the modeling, realistic parameters are used for the initial ambient gaseous state and currents to ensure a resulting supercritical state upon shock collisions.

  5. An improved Reynolds-equation model for gas damping of microbeam motion.

    SciTech Connect

    Gallis, Michail A.; Torczynski, John Robert

    2003-09-01

    An improved gas-damping model for the out-of-plane motion of a near-substrate microbeam is developed based on the Reynolds equation (RE). A boundary condition for the RE is developed that relates the pressure at the beam edge to the beam motion. The coefficients in this boundary condition are determined from Navier-Stokes slip-jump (NSSJ) simulations for small slip lengths (relative to the gap height) and from direct simulation Monte Carlo (DSMC) molecular gas dynamics simulations for larger slip lengths. This boundary condition significantly improves the accuracy of the RE when the microbeam width is only slightly greater than the gap height between the microbeam and the substrate. The improved RE model is applied to microbeams fabricated using the SUMMiT V process.

  6. Decay of the 3D inviscid liquid-gas two-phase flow model

    NASA Astrophysics Data System (ADS)

    Zhang, Yinghui

    2016-06-01

    We establish the optimal {Lp-L2(1 ≤ p < 6/5)} time decay rates of the solution to the Cauchy problem for the 3D inviscid liquid-gas two-phase flow model and analyze the influences of the damping on the qualitative behaviors of solution. Compared with the viscous liquid-gas two-phase flow model (Zhang and Zhu in J Differ Equ 258:2315-2338, 2015), our results imply that the friction effect of the damping is stronger than the dissipation effect of the viscosities and enhances the decay rate of the velocity. Our proof is based on Hodge decomposition technique, the {Lp-L2} estimates for the linearized equations and an elaborate energy method.

  7. Carbonation of gypsum from wet flue gas desulfurization process: experiments and modeling.

    PubMed

    Tan, Wenyi; Zhang, Zixin; Li, Hongyi; Li, Youxu; Shen, Zewen

    2017-02-13

    In this paper, waste gypsum from wet flue gas desulfurization (WFGD) mixed with NH3·H2O was applied for CO2 absorption in the solid-liquid-gas phase system. The effects of operation temperature, CO2 flow rates, and ammonia-to-gypsum ratio on carbonation process were discussed. Meanwhile, a model for CO2 absorption in the suspension of WFGD gypsum and ammonia was established. The results indicate that higher temperature favors the reaction, and WFGD gypsum conversion can be achieved above 90% even at lower ammonia-to-gypsum ratio, while CO2 conversion reaches 90% and ammonia utilization is up to 83.69%. The model fits well with the experimental results at various CO2 flow rates and predicts the concentration distribution of the main species, including CO2 absorbed, NH2COO(-), and HCO3(-).

  8. Development and validation of a new soot formation model for gas turbine combustor simulations

    SciTech Connect

    Di Domenico, Massimiliano; Gerlinger, Peter; Aigner, Manfred

    2010-02-15

    In this paper a new soot formation model for gas turbine combustor simulations is presented. A sectional approach for the description of Polycyclic Aromatic Hydrocarbons (PAHs) and a two-equation model for soot particle dynamics are introduced. By including the PAH chemistry the formulation becomes more general in that the soot formation is neither directly linked to the fuel nor to C{sub 2}-like species, as it is the case in simpler soot models currently available for CFD applications. At the same time, the sectional approach for the PAHs keeps the required computational resources low if compared to models based on a detailed description of the PAH kinetics. These features of the new model allow an accurate yet affordable calculation of soot in complex gas turbine combustion chambers. A careful model validation will be presented for diffusion and partially premixed flames. Fuels ranging from methane to kerosene are investigated. Thus, flames with different sooting characteristics are covered. An excellent agreement with experimental data is achieved for all configurations investigated. A fundamental feature of the new model is that with a single set of constants it is able to accurately describe the soot dynamics of different fuels at different operating conditions. (author)

  9. Geo-mechanical Model Testing for Stability of Underground Gas Storage in Halite During the Operational Period

    NASA Astrophysics Data System (ADS)

    Chen, Xuguang; Zhang, Qiangyong; Li, Shucai; Liu, Dejun

    2016-07-01

    A 3D geo-mechanical model test is conducted to study the stability of underground gas storage in halite, modeled after the Jintan gas storage constructed in bedded salt rock in China. A testing apparatus is developed to generate long-term stable trapezoid geostresses onto the model cavity, corresponding to the actual gas storage cavern. The time-depending character of the material is simulated using a rheological material, which was tested using a self-developed apparatus. The model cavern is built using an ellipsoid wooden mold divided into small blocks which are assembled and placed into the designed position during the model construction. They are then pulled out one by one to form the cavern. The ellipsoid cavern wall is then lined within a latex balloon. Gas is injected into the cavity and extracted to simulate the operational process of gas injection and recovery. Optical sensors embedded into the model to measure the displacement around the cavity showed that the largest deformation occurs in the middle section of the cavity. The deformation rate increases with increasing gas pressure. At 11 MPa the cavity is in equilibrium with the geostress. The pressure is highest during the gas recovery stages, indicating that gas recovery can threaten the cavern's operational stability, while high gas injection causes rock mass compression and deformation outward from the cavern. The deformation is the combination of cavern convergence and gas-induced rebound which leads to tensile and compression during gas injection and recovery. Hence, the fatigue properties of salt rock should be studied further.

  10. Modeling and experiments on differential pumping in linear plasma generators operating at high gas flows

    SciTech Connect

    Eck, H. J. N. van; Koppers, W. R.; Rooij, G. J. van; Goedheer, W. J.; Cardozo, N. J. Lopes; Kleyn, A. W.; Engeln, R.; Schram, D. C.

    2009-03-15

    The direct simulation Monte Carlo (DSMC) method was used to investigate the efficiency of differential pumping in linear plasma generators operating at high gas flows. Skimmers are used to separate the neutrals from the plasma beam, which is guided from the source to the target by a strong axial magnetic field. In this way, the neutrals are prevented to reach the target region. The neutral flux to the target must be lower than the plasma flux to enable ITER relevant plasma-surface interaction (PSI) studies. It is therefore essential to control the neutral gas dynamics. The DSMC method was used to model the expansion of a hot gas in a low pressure vessel where a small discrepancy in shock position was found between the simulations and a well-established empirical formula. Two stage differential pumping was modeled and applied in the linear plasma devices Pilot-PSI and PLEXIS. In Pilot-PSI a factor of 4.5 pressure reduction for H{sub 2} has been demonstrated. Both simulations and experiments showed that the optimum skimmer position depends on the position of the shock and therefore shifts for different gas parameters. The shape of the skimmer has to be designed such that it has a minimum impact on the shock structure. A too large angle between the skimmer and the forward direction of the gas flow leads to an influence on the expansion structure. A pressure increase in front of the skimmer is formed and the flow of the plasma beam becomes obstructed. It has been shown that a skimmer with an angle around 53 deg. gives the best performance. The use of skimmers is implemented in the design of the large linear plasma generator Magnum-PSI. Here, a three stage differentially pumped vacuum system is used to reach low enough neutral pressures near the target, opening a door to PSI research in the ITER relevant regime.

  11. Modeling gravity effects on water retention and gas transport characteristics in plant growth substrates

    NASA Astrophysics Data System (ADS)

    Chamindu Deepagoda, T. K. K.; Jones, Scott B.; Tuller, Markus; de Jonge, Lis Wollesen; Kawamoto, Ken; Komatsu, Toshiko; Moldrup, Per

    2014-08-01

    Growing plants to facilitate life in outer space, for example on the International Space Station (ISS) or at planned deep-space human outposts on the Moon or Mars, has received much attention with regard to NASA's advanced life support system research. With the objective of in situ resource utilization to conserve energy and to limit transport costs, native materials mined on Moon or Mars are of primary interest for plant growth media in a future outpost, while terrestrial porous substrates with optimal growth media characteristics will be useful for onboard plant growth during space missions. Due to limited experimental opportunities and prohibitive costs, liquid and gas behavior in porous substrates under reduced gravity conditions has been less studied and hence remains poorly understood. Based on ground-based measurements, this study examined water retention, oxygen diffusivity and air permeability characteristics of six plant growth substrates for potential applications in space, including two terrestrial analogs for lunar and Martian soils and four particulate substrates widely used in reduced gravity experiments. To simulate reduced gravity water characteristics, the predictions for ground-based measurements (1 - g) were scaled to two reduced gravity conditions, Martian gravity (0.38 - g) and lunar gravity (0.16 - g), following the observations in previous reduced gravity studies. We described the observed gas diffusivity with a recently developed model combined with a new approach that estimates the gas percolation threshold based on the pore size distribution. The model successfully captured measured data for all investigated media and demonstrated the implications of the poorly-understood shift in gas percolation threshold with improved gas percolation in reduced gravity. Finally, using a substrate-structure parameter related to the gaseous phase, we adequately described the air permeability under reduced gravity conditions.

  12. Modeling the Gas Dynamics Environment in a Subscale Solid Rocket Test Motor

    NASA Technical Reports Server (NTRS)

    Eaton, Andrew M.; Ewing, Mark E.; Bailey, Kirk M.; McCool, Alex (Technical Monitor)

    2001-01-01

    Subscale test motors are often used for the evaluation of solid rocket motor component materials such as internal insulation. These motors are useful for characterizing insulation performance behavior, screening insulation material candidates and obtaining material thermal and ablative property design data. One of the primary challenges associated with using subscale motors however, is the uncertainty involved when extrapolating the results to full-scale motor conditions. These uncertainties are related to differences in such phenomena as turbulent flow behavior and boundary layer development, propellant particle interactions with the wall, insulation off-gas mixing and thermochemical reactions with the bulk flow, radiation levels, material response to the local environment, and other anomalous flow conditions. In addition to the need for better understanding of physical mechanisms, there is also a need to better understand how to best simulate these phenomena using numerical modeling approaches such as computational fluid dynamics (CFD). To better understand and model interactions between major phenomena in a subscale test motor, a numerical study of the internal flow environment of a representative motor was performed. Simulation of the environment included not only gas dynamics, but two-phase flow modeling of entrained alumina particles like those found in an aluminized propellant, and offgassing from wall surfaces similar to an ablating insulation material. This work represents a starting point for establishing the internal environment of a subscale test motor using comprehensive modeling techniques, and lays the groundwork for improving the understanding of the applicability of subscale test data to full-scale motors. It was found that grid resolution, and inclusion of phenomena in addition to gas dynamics, such as two-phase and multi-component gas composition are all important factors that can effect the overall flow field predictions.

  13. Experimental and Numerical Modelling of CO2 Atmospheric Dispersion in Hazardous Gas Emission Sites.

    NASA Astrophysics Data System (ADS)

    Gasparini, A.; sainz Gracia, A. S.; Grandia, F.; Bruno, J.

    2015-12-01

    Under stable atmospheric conditions and/or in presence of topographic depressions, CO2 concentrations can reach high values resulting in lethal effect to living organisms. The distribution of denser than air gases released from the underground is governed by gravity, turbulence and dispersion. Once emitted, the gas distribution is initially driven by buoyancy and a gas cloud accumulates on the ground (gravitational phase); with time the density gradient becomes less important due to dispersion or mixing and gas distribution is mainly governed by wind and atmospheric turbulence (passive dispersion phase). Natural analogues provide evidences of the impact of CO2 leakage. Dangerous CO2 concentration in atmosphere related to underground emission have been occasionally reported although the conditions favouring the persistence of such a concentration are barely studied.In this work, the dynamics of CO2 in the atmosphere after ground emission is assessed to quantify their potential risk. Two approaches have been followed: (1) direct measurement of air concentration in a natural emission site, where formation of a "CO2 lake" is common and (2) numerical atmospheric modelling. Two sites with different morphology were studied: (a) the Cañada Real site, a flat terrain in the Volcanic Field of Campo de Calatrava (Spain); (b) the Solforata di Pomezia site, a rough terrain in the Alban Hills Volcanic Region (Italy). The comparison between field data and model calculations reveal that numerical dispersion models are capable of predicting the formation of CO2 accumulation over the ground as a consequence of underground gas emission. Therefore, atmospheric modelling could be included as a valuable methodology in the risk assessment of leakage in natural degassing systems and in CCS projects. Conclusions from this work provide clues on whether leakage may be a real risk for humans and under which conditions this risk needs to be included in the risk assessment.

  14. Numerical Prediction of Non-Reacting and Reacting Flow in a Model Gas Turbine Combustor

    NASA Technical Reports Server (NTRS)

    Davoudzadeh, Farhad; Liu, Nan-Suey

    2005-01-01

    The three-dimensional, viscous, turbulent, reacting and non-reacting flow characteristics of a model gas turbine combustor operating on air/methane are simulated via an unstructured and massively parallel Reynolds-Averaged Navier-Stokes (RANS) code. This serves to demonstrate the capabilities of the code for design and analysis of real combustor engines. The effects of some design features of combustors are examined. In addition, the computed results are validated against experimental data.

  15. DYNAMIC MODELING STRATEGY FOR FLOW REGIME TRANSITION IN GAS-LIQUID TWO-PHASE FLOWS

    SciTech Connect

    X. Wang; X. Sun; H. Zhao

    2011-09-01

    In modeling gas-liquid two-phase flows, the concept of flow regime has been used to characterize the global interfacial structure of the flows. Nearly all constitutive relations that provide closures to the interfacial transfers in two-phase flow models, such as the two-fluid model, are often flow regime dependent. Currently, the determination of the flow regimes is primarily based on flow regime maps or transition criteria, which are developed for steady-state, fully-developed flows and widely applied in nuclear reactor system safety analysis codes, such as RELAP5. As two-phase flows are observed to be dynamic in nature (fully-developed two-phase flows generally do not exist in real applications), it is of importance to model the flow regime transition dynamically for more accurate predictions of two-phase flows. The present work aims to develop a dynamic modeling strategy for determining flow regimes in gas-liquid two-phase flows through the introduction of interfacial area transport equations (IATEs) within the framework of a two-fluid model. The IATE is a transport equation that models the interfacial area concentration by considering the creation and destruction of the interfacial area, such as the fluid particle (bubble or liquid droplet) disintegration, boiling and evaporation; and fluid particle coalescence and condensation, respectively. For the flow regimes beyond bubbly flows, a two-group IATE has been proposed, in which bubbles are divided into two groups based on their size and shape (which are correlated), namely small bubbles and large bubbles. A preliminary approach to dynamically identifying the flow regimes is provided, in which discriminators are based on the predicted information, such as the void fraction and interfacial area concentration of small bubble and large bubble groups. This method is expected to be applied to computer codes to improve their predictive capabilities of gas-liquid two-phase flows, in particular for the applications in

  16. New approaches to toxicity: a seven-gas predictive model and toxicant suppressants.

    PubMed

    Levin, B C

    1997-11-01

    Two new research approaches in combustion toxicology are: 1. the prediction of smoke toxicity from mathematical equations, which are empirically derived from, experiments on the toxicological interactions of complex fire gas mixtures and 2. the use of toxicant suppressants in materials or products to prevent the formation of toxic combustion products. The predictive approach consists of burning materials using a bench-scale method that simulates realistic fire conditions, measuring the concentrations of the primary fire gases--CO, CO2, low O2, HCN, HCl, HBr, and NO2--and predicting the toxicity of the smoke using either the 6- or 7-gas N-Gas Model. These models are based on the results of toxicological studies of these primary gases as individual gases and as complex mixtures. The predicted toxic potency is checked with a small number of animal (Fischer 344 male rats) tests to assure that an unanticipated toxic gas is not generated or an unexpected synergistic or antagonistic effect has not occurred. The results indicate if the smoke from a material or product is extremely toxic (based on mass consumed at the predicted toxic level) or unusually toxic (based on the gases deemed responsible). The predictions based on bench-scale laboratory tests have been validated with full-scale room burns of a limited number of materials of widely differing characteristics chosen to challenge the system. The advantages of this new approach are 1. the number of test animals is minimized by predicting the toxic potency from the chemical analysis of the smoke, 2. smoke may be produced under conditions that simulate the fire scenario of concern, 3. fewer tests are needed, thereby reducing the overall cost of the testing and 4, information is obtained on both the toxic potency of the smoke and the responsible gases. The N-Gas Models have been developed into the N-Gas Method (described in this paper) and these results have been used in computations of fire hazard. The 6-Gas Model is now

  17. Propagation of uncertainty and sensitivity analysis in an integral oil-gas plume model

    NASA Astrophysics Data System (ADS)

    Wang, Shitao; Iskandarani, Mohamed; Srinivasan, Ashwanth; Thacker, W. Carlisle; Winokur, Justin; Knio, Omar M.

    2016-05