A Probabilistic Analysis of Surface Water Flood Risk in London.

PubMed

Jenkins, Katie; Hall, Jim; Glenis, Vassilis; Kilsby, Chris

2018-06-01

Flooding in urban areas during heavy rainfall, often characterized by short duration and high-intensity events, is known as "surface water flooding." Analyzing surface water flood risk is complex as it requires understanding of biophysical and human factors, such as the localized scale and nature of heavy precipitation events, characteristics of the urban area affected (including detailed topography and drainage networks), and the spatial distribution of economic and social vulnerability. Climate change is recognized as having the potential to enhance the intensity and frequency of heavy rainfall events. This study develops a methodology to link high spatial resolution probabilistic projections of hourly precipitation with detailed surface water flood depth maps and characterization of urban vulnerability to estimate surface water flood risk. It incorporates probabilistic information on the range of uncertainties in future precipitation in a changing climate. The method is applied to a case study of Greater London and highlights that both the frequency and spatial extent of surface water flood events are set to increase under future climate change. The expected annual damage from surface water flooding is estimated to be to be £171 million, £343 million, and £390 million/year under the baseline, 2030 high, and 2050 high climate change scenarios, respectively. © 2017 Society for Risk Analysis.

Modelling surface-water depression storage in a Prairie Pothole Region

USGS Publications Warehouse

Hay, Lauren E.; Norton, Parker A.; Viger, Roland; Markstrom, Steven; Regan, R. Steven; Vanderhoof, Melanie

2018-01-01

In this study, the Precipitation-Runoff Modelling System (PRMS) was used to simulate changes in surface-water depression storage in the 1,126-km2 Upper Pipestem Creek basin located within the Prairie Pothole Region of North Dakota, USA. The Prairie Pothole Region is characterized by millions of small water bodies (or surface-water depressions) that provide numerous ecosystem services and are considered an important contribution to the hydrologic cycle. The Upper Pipestem PRMS model was extracted from the U.S. Geological Survey's (USGS) National Hydrologic Model (NHM), developed to support consistent hydrologic modelling across the conterminous United States. The Geospatial Fabric database, created for the USGS NHM, contains hydrologic model parameter values derived from datasets that characterize the physical features of the entire conterminous United States for 109,951 hydrologic response units. Each hydrologic response unit in the Geospatial Fabric was parameterized using aggregated surface-water depression area derived from the National Hydrography Dataset Plus, an integrated suite of application-ready geospatial datasets. This paper presents a calibration strategy for the Upper Pipestem PRMS model that uses normalized lake elevation measurements to calibrate the parameters influencing simulated fractional surface-water depression storage. Results indicate that inclusion of measurements that give an indication of the change in surface-water depression storage in the calibration procedure resulted in accurate changes in surface-water depression storage in the water balance. Regionalized parameterization of the USGS NHM will require a proxy for change in surface-storage to accurately parameterize surface-water depression storage within the USGS NHM.

78 FR 45871 - National Oil and Hazardous Substances Pollution Contingency Plan; National Priorities List...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-07-30

... components: Hydrogeologic study; Surface water sampling study; Stream biological study; Air quality survey... components: Biological survey; Biota survey; Surface water and sediment characterization; Groundwater... impacted groundwater in three water bearing zones at the Site; the unconsolidated materials zone, the upper...

CHARACTERIZING SURFACE WATERS THAT MAY NOT REQUIRE FILTRATION

EPA Science Inventory

Field data from various utilities were studied with the object of identifying a set of characteristics of a surface water that might allow it to be successfully treated by disinfection alone, thus avoiding the need to filter. It was found possible to define water quality standard...

Characterization of the surface properties of wheat spikelet components

USDA-ARS?s Scientific Manuscript database

The physicochemical surface properties of wheat spikelet components were determined. The water and water:acetone (1:1, v/v) contact angle for the glumes and lemmas of two wheat cultivars were measured. The results demonstrate that the surface chemistry and ultrastructure of glume and lemma tissues...

Captive bubble and sessile drop surface characterization of a submerged aquatic plant, Hydrilla verticillata

USDA-ARS?s Scientific Manuscript database

The surface energy parameters of the invasive aquatic weed, Hydrilla verticillata, were determined using contact angle measurements using two different methods. The abaxial and adaxial surfaces of the leaves and stem were characterized for the weed while submerged in water using captive air and octa...

Characterizing Variability In Ohio River Natural Organic Matter

EPA Science Inventory

Surface water contains natural organic matter (NOM) which reacts with disinfectants creating disinfection byproducts (DBPs), some of which are USEPA regulated contaminants. Characterizing NOM can provide important insight on DBP formation and water treatment process adaptation t...

Characterization of the Intrinsic Water Wettability of Graphite Using Contact Angle Measurements: Effect of Defects on Static and Dynamic Contact Angles.

PubMed

Kozbial, Andrew; Trouba, Charlie; Liu, Haitao; Li, Lei

2017-01-31

Elucidating the intrinsic water wettability of the graphitic surface has increasingly attracted research interests, triggered by the recent finding that the well-established hydrophobicity of graphitic surfaces actually results from airborne hydrocarbon contamination. Currently, static water contact angle (WCA) is often used to characterize the intrinsic water wettability of graphitic surfaces. In the current paper, we show that because of the existence of defects, static WCA does not necessarily characterize the intrinsic water wettability. Freshly exfoliated graphite of varying qualities, characterized using atomic force microscopy and Raman spectroscopy, was studied using static, advancing, and receding WCA measurements. The results showed that graphite of different qualities (i.e., defect density) always has a similar advancing WCA, but it could have very different static and receding WCAs. This finding indicates that defects play an important role in contact angle measurements, and the static contact angle does not always represent the intrinsic water wettability of pristine graphite. On the basis of the experimental results, a qualitative model is proposed to explain the effect of defects on static, advancing, and receding contact angles. The model suggests that the advancing WCA reflects the intrinsic water wettability of pristine (defect-free) graphite. Our results showed that the advancing WCA for pristine graphite is 68.6°, which indicates that graphitic carbon is intrinsically mildly hydrophilic.

Finding No Significant Impact: Aircraft Weather Shelter at Laughlin AFB, TX

DTIC Science & Technology

2004-06-01

surface water flow is southeast into the Ro Grande and down toward the Gulf of Mexico. Lake Amistad reservoir, located approximately 12 miles northwest...characterized Lake Amistad reservoir as having excellent water quality (USAF, 1997). Laughlin AFB contains a total of 19 acres of surface water

Resolving inter-annual terrestrial water storage variations using microwave-based surface soil moisture retrievals

USDA-ARS?s Scientific Manuscript database

Due to their shallow vertical support, remotely-sensed surface soil moisture retrievals are commonly regarded as being of limited value for water budget applications requiring the characterization of temporal variations in total terrestrial water storage (S). However, advances in our ability to esti...

Hydration level dependence of the microscopic dynamics of water adsorbed in ultramicroporous carbon

DOE PAGES

Mamontov, Eugene; Yue, Yanfeng; Bahadur, Jitendra; ...

2016-10-20

Even when not functionalized intentionally, most carbon materials are not hydrophobic and readily adsorb water molecules from atmospheric water vapor. We have equilibrated an ultramicroporous carbon at several levels of relative humidity, thereby attaining various hydration levels. The water molecules were adsorbed on the pore walls (but did not fill completely the pore volume) and thus could be better described as hydration, or surface, rather than confined, water. We used quasielastic neutron scattering to perform a detailed investigation of the dependence of microscopic dynamics of these adsorbed water species on the hydration level and temperature. The behavior of hydration watermore » in ultramicroporous carbon clearly demonstrates the same universal traits that characterize surface (hydration) water in other materials that are surface-hydrated. In addition, unless special treatment is intentionally applied to ultramicroporous carbon, the species filling its pores in various applications, ranging from hydrogen molecules to electrolytes, likely find themselves in contact with non-freezing water molecules characterized by rich microscopic dynamics.« less

Effects of surface roughness and energy on ice adhesion strength

NASA Astrophysics Data System (ADS)

Zou, M.; Beckford, S.; Wei, R.; Ellis, C.; Hatton, G.; Miller, M. A.

2011-02-01

The aim of this study is to investigate the effects of surface roughness and surface energy on ice adhesion strength. Sandblasting technique was used to prepare samples with high roughness. Silicon-doped hydrocarbon and fluorinated-carbon thin films were employed to alter the surface energy of the samples. Silicon-doped hydrocarbon films were deposited by plasma-enhanced chemical vapor deposition, while fluorinated-carbon films were produced using deep reactive ion etching equipment by only activating the passivation step. Surface topographies were characterized using scanning electron microscopy and a stylus profilometer. The surface wetting properties were characterized by a video-based contact angle measurement system. The adhesion strength of ice formed from a water droplet on these surfaces was studied using a custom-built shear force test apparatus. It was found that the ice adhesion strength is correlated to the water contact angles of the samples only for surfaces with similar roughness: the ice adhesion strength decreases with the increase in water contact angle. The study also shows that smoother as-received sample surfaces have lower ice adhesion strength than the much rougher sandblasted surfaces.

INVESTIGATING SURFACE WATER QUALITY IMPACTS ON GROUNDWATER QUALITY UNDER VARYING FLOW CONDITIONS IN THE BARTON SPRINGS SEGMENT OF THE EDWARDS AQUIFER, CENTRAL TEXAS

EPA Science Inventory

The expected results from this research include: i) the quantification of the proportion of surface water comprising spring discharge under varying flow conditions; ii) the characterization of surface watersheds under varying antecedent moisture conditions, and evaluation of ...

Theoretical vibrational sum-frequency generation spectroscopy of water near lipid and surfactant monolayer interfaces. II. Two-dimensional spectra.

PubMed

Roy, S; Gruenbaum, S M; Skinner, J L

2014-12-14

The structural stability and function of biomolecules is strongly influenced by the dynamics and hydrogen bonding of interfacial water. Understanding and characterizing the dynamics of these water molecules require a surface-sensitive technique such as two-dimensional vibrational sum-frequency generation (2DSFG) spectroscopy. We have combined theoretical 2DSFG calculations with molecular dynamics simulations in order to investigate the dynamics of water near different lipid and surfactant monolayer surfaces. We show that 2DSFG can distinguish the dynamics of interfacial water as a function of the lipid charge and headgroup chemistry. The dynamics of water is slow compared to the bulk near water-zwitterionic and water-anionic interfaces due to conformational constraints on interfacial water imposed by strong phosphate-water hydrogen bonding. The dynamics of water is somewhat faster near water-cationic lipid interfaces as no such constraint is present. Using hydrogen bonding and rotational correlation functions, we characterize the dynamics of water as a function of the distance from the interface between water and zwitterionic lipids. We find that there is a transition from bulk-like to interface-like dynamics approximately 7 Å away from a zwitterionic phosphatidylcholine monolayer surface.

The development of deep karst in the anticlinal aquifer structure based on the coupling of multistage flow systems

NASA Astrophysics Data System (ADS)

Xu, M.; Zhong, L.; Yang, Y.

2017-12-01

Under the background of neotectonics, the multistage underground flow system has been form due the different responses of main stream and tributaries to crust uplift. The coupling of multistage underground flow systems influences the development of karst thoroughly. At first, the research area is divided into vadose area, shunted area and exorheic area based on the development characteristics of transverse valley. Combining the controlling-drain action with topographic index and analyzing the coupling features of multistage underground flow system. And then, based on the coupling of multistage underground flow systems, the characteristics of deep karst development were verified by the lossing degree of surface water, water bursting and karst development characteristics of tunnels. The vadose area is regional water system based, whose deep karst developed well. It resulted the large water inflow of tunnels and the surface water drying up. The shunted area, except the region near the transverse valleys, is characterized by regional water system. The developed deep karst make the surface water connect with deep ground water well, Which caused the relatively large water flow of tunnels and the serious leakage of surface water. The deep karst relatively developed poor in the regions near transverse valleys which is characterized by local water system. The exorheic area is local water system based, whose the deep karst developed poor, as well as the connection among surface water and deep ground water. It has result in the poor lossing of the surface water under the tunnel construction. This study broadens the application field of groundwater flow systems theory, providing a new perspective for the study of Karst development theory. Meanwhile it provides theoretical guidance for hazard assessment and environmental negative effect in deep-buried Karst tunnel construction.

Characterization of Copper Corrosion Products in Drinking Water by Combining Electrochemical and Surface Analyses

EPA Science Inventory

This study focuses on the application of electrochemical approaches to drinking water copper corrosion problems. Applying electrochemical approaches combined with copper solubility measurements, and solid surface analysis approaches were discussed. Tafel extrapolation and Electro...

Characterization of Copper Corrosion Products Formed in Drinking Water by Combining Electrochemical and Surface Analyses

EPA Science Inventory

This study focuses on the application of electrochemical approaches to drinking water copper corrosion problems. Applying electrochemical approaches combined with copper solubility measurements, and solid surface analysis approaches were discussed. Tafel extrapolation and Electro...

SURFACE APPLICATION SYSTEM FOR IN SITU GROUND-WATER BIOREMEDIATION: SITE CHARACTERIZATION AND MODELING

EPA Science Inventory

Surface application offers an inexpensive, noninvasive alternative to injection wells and infiltration galleries for in situ ground-water bioreniediation applications. The technology employs artificial recharge to create favorable hydraulic conditions for mixing and vertical tran...

Separation of oil from bilge water I. Bilge water characteristics and the interaction of bilge water with chemically modified surfaces. Interim report, October 1994-September 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chang, E.L.; Calvert, J.M.; Koloski, T.

1997-02-01

We report on the results of a project using surface characterization and novel surface-modification techniques to address the issues of developing a minimally fouling ceramic membrane filter. We have studied the physical characteristics of a synthetic bilge water mixture, examined the surfaces of the ceramic filters for evidence of fouling, and identified several surface modifications that, under laboratory conditions, work well in prevention of foulants. These surfaces include hydrophobic as well as polar coatings. For the bilge water, it was discovered that detergent, at certain concentrations, may be useful in separating and coalescing oil droplets from the bilge water. Basedmore » on the results of the studies, several strategies for optimizing the removal of oil from water are suggested.« less

Ground Water Modeling Research

EPA Pesticide Factsheets

EPA is supporting region, state, and tribal partners at Superfund sites and brownfields to develop new methods to better characterize, monitor, and treat ground water contamination; in order to protect drinking water, surface water, and indoor air.

Characterizing Ohio River NOM Variability and Reconstituted-Lyophilized NOM as a Source Surrogate

EPA Science Inventory

Surface water contains natural organic matter (NOM) that reacts with disinfectants creating disinfection byproducts (DBPs), some of which are USEPA regulated contaminants. Characterizing NOM can provide insight with respect to DBP formation and water treatment process adaptation...

Characterization of Missouri surface waters near point sources of pollution reveals potential novel atmospheric route of exposure for bisphenol A and wastewater hormonal activity pattern.

PubMed

Kassotis, Christopher D; Alvarez, David A; Taylor, Julia A; vom Saal, Frederick S; Nagel, Susan C; Tillitt, Donald E

2015-08-15

Surface water contamination by chemical pollutants increasingly threatens water quality around the world. Among the many contaminants found in surface water, there is growing concern regarding endocrine disrupting chemicals, based on their ability to interfere with some aspect of hormone action in exposed organisms, including humans. This study assessed water quality at several sites across Missouri (near wastewater treatment plants and airborne release sites of bisphenol A) based on hormone receptor activation potencies and chemical concentrations present in the surface water. We hypothesized that bisphenol A and ethinylestradiol would be greater in water near permitted airborne release sites and wastewater treatment plant inputs, respectively, and that these two compounds would be responsible for the majority of activities in receptor-based assays conducted with water collected near these sites. Concentrations of bisphenol A and ethinylestradiol were compared to observed receptor activities using authentic standards to assess contribution to total activities, and quantitation of a comprehensive set of wastewater compounds was performed to better characterize each site. Bisphenol A concentrations were found to be elevated in surface water near permitted airborne release sites, raising questions that airborne releases of BPA may influence nearby surface water contamination and may represent a previously underestimated source to the environment and potential for human exposure. Estrogen and androgen receptor activities of surface water samples were predictive of wastewater input, although the lower sensitivity of the ethinylestradiol ELISA relative to the very high sensitivity of the bioassay approaches did not allow a direct comparison. Wastewater-influenced sites also had elevated anti-estrogenic and anti-androgenic equivalence, while sites without wastewater discharges exhibited no antagonist activities. Published by Elsevier B.V.

Characterization of Missouri surface waters near point sources of pollution reveals potential novel atmospheric route of exposure for bisphenol A and wastewater hormonal activity pattern

USGS Publications Warehouse

Kassotis, Christopher D.; Alvarez, David A.; Taylor, Julia A.; vom Saal, Frederick S.; Nagel, Susan C.; Tillitt, Donald E.

2015-01-01

Surface water contamination by chemical pollutants increasingly threatens water quality around the world. Among the many contaminants found in surface water, there is growing concern regarding endocrine disrupting chemicals, based on their ability to interfere with some aspect of hormone action in exposed organisms, including humans. This study assessed water quality at several sites across Missouri (near wastewater treatment plants and airborne release sites of bisphenol A) based on hormone receptor activation potencies and chemical concentrationspresent in the surface water. We hypothesized that bisphenol A and ethinylestradiol would be greater in water near permitted airborne release sites and wastewater treatment plant inputs, respectively, and that these two compounds would be responsible for the majority of activities in receptor-based assays conducted with water collected near these sites. Concentrations of bisphenol A and ethinylestradiol were compared to observed receptor activities using authentic standards to assess contribution to total activities, and quantitation of a comprehensive set of wastewater compounds was performed to better characterize each site. Bisphenol A concentrations were found to be elevated in surface water near permitted airborne release sites, raising questions that airborne releases of BPA may influence nearby surface water contamination and may represent a previously underestimated source to the environment and potential for human exposure. Estrogen and androgen receptor activities of surface water samples were predictive of wastewater input, although the lower sensitivity of the ethinylestradiol ELISA relative to the very high sensitivity of the bioassay approaches did not allow a direct comparison. Wastewater-influenced sites also had elevated anti-estrogenic and anti-androgenic equivalence, while sites without wastewater discharges exhibited no antagonist activities.

Studying groundwater and surface water interactions using airborne remote sensing in Heihe River basin, northwest China

NASA Astrophysics Data System (ADS)

Liu, C.; Liu, J.; Hu, Y.; Zheng, C.

2015-05-01

Managing surface water and groundwater as a unified system is important for water resource exploitation and aquatic ecosystem conservation. The unified approach to water management needs accurate characterization of surface water and groundwater interactions. Temperature is a natural tracer for identifying surface water and groundwater interactions, and the use of remote sensing techniques facilitates basin-scale temperature measurement. This study focuses on the Heihe River basin, the second largest inland river basin in the arid and semi-arid northwest of China where surface water and groundwater undergoes dynamic exchanges. The spatially continuous river-surface temperature of the midstream section of the Heihe River was obtained by using an airborne pushbroom hyperspectral thermal sensor system. By using the hot spot analysis toolkit in the ArcGIS software, abnormally cold water zones were identified as indicators of the spatial pattern of groundwater discharge to the river.

Dust emission from wet and dry playas in the Mojave Desert, USA

USGS Publications Warehouse

Reynolds, R.L.; Yount, J.C.; Reheis, M.; Goldstein, H.; Chavez, P.; Fulton, R.; Whitney, J.; Fuller, C.; Forester, R.M.

2007-01-01

The interactions between playa hydrology and playa-surface sediments are important factors that control the type and amount of dust emitted from playas as a result of wind erosion. The production of evaporite minerals during evaporative loss of near-surface ground water results in both the creation and maintenance of several centimeters or more of loose sediment on and near the surfaces of wet playas. Observations that characterize the texture, mineralogic composition and hardness of playa surfaces at Franklin Lake, Soda Lake and West Cronese Lake playas in the Mojave Desert (California), along with imaging of dust emission using automated digital photography, indicate that these kinds of surface sediment are highly susceptible to dust emission. The surfaces of wet playas are dynamic - surface texture and sediment availability to wind erosion change rapidly, primarily in response to fluctuations in water-table depth, rainfall and rates of evaporation. In contrast, dry playas are characterized by ground water at depth. Consequently, dry playas commonly have hard surfaces that produce little or no dust if undisturbed except for transient silt and clay deposited on surfaces by wind and water. Although not the dominant type of global dust, salt-rich dusts from wet playas may be important with respect to radiative properties of dust plumes, atmospheric chemistry, windborne nutrients and human health.

Characterization of water bodies for mosquito habitat using a multi-sensor approach

NASA Astrophysics Data System (ADS)

Midekisa, A.; Wimberly, M. C.; Senay, G. B.

2012-12-01

Malaria is a major health problem in Ethiopia. Anopheles arabiensis, which inhabits and breeds in a variety of aquatic habitats, is the major mosquito vector for malaria transmission in the region. In the Amhara region of Ethiopia, mosquito breeding sites are heterogeneously distributed. Therefore, accurate characterization of aquatic habitats and potential breeding sites can be used as a proxy to measure the spatial distribution of malaria risk. Satellite remote sensing provides the ability to map the spatial distribution and monitor the temporal dynamics of surface water. The objective of this study is to map the probability of surface water accumulation to identify potential vector breeding sites for Anopheles arabiensis using remote sensing data from sensors at multiple spatial and temporal resolutions. The normalized difference water index (NDWI), which is based on reflectance in the green and the near infrared (NIR) bands were used to estimate fractional cover of surface water. Temporal changes in surface water were mapped using NDWI indices derived from MODIS surface reflectance product (MOD09A1) for the period 2001-2012. Landsat TM and ETM+ imagery were used to train and calibrate model results from MODIS. Results highlighted interannual variation and seasonal changes in surface water that were observed from the MODIS time series. Static topographic indices that estimate the potential for water accumulation were generated from 30 meter Shuttle Radar Topography Mission (SRTM) elevation data. Integrated fractional surface water cover was developed by combining the static topographic indices and dynamic NDWI indices using Geographic Information System (GIS) overlay methods. Accuracy of the results was evaluated based on ground truth data that was collected on presence and absence of surface water immediately after the rainy season. The study provided a multi-sensor approach for mapping areas with a high potential for surface water accumulation that are potential breeding habitats for anopheline mosquitoes. The resulting products are useful for public health decision making towards effective prevention and control of the malaria burden in the Amhara region of Ethiopia.

Ground-water and surface-water elevations in the Fairbanks International Airport area, Alaska, 1990-94

USGS Publications Warehouse

Claar, D.V.; Lilly, M.R.

1995-01-01

Ground-water and surface-water elevation data were collected at 52 sites from 1990 to 1994 by the U.S. Geological Survey in cooperation with the Alaska Department of Transportation and Public Facilities, Fairbanks International Airport. Water elevations were measured in 32 ground-water observation wells and at 20 surface-water sites to help characterize the geohydrology of the Fairbanks International Airport area. From 1990 to 1993, data were collected in the vicinity of the former fire-training area at the airport. From 1993 to 1994, the data-collection area was expanded to include the entire airport area.

Water surface elevation from the upcoming SWOT mission under different flows conditions

NASA Astrophysics Data System (ADS)

Domeneghetti, Alessio; Schumann, Guy J. P.; Wei, Rui; Frasson, Renato P. M.; Durand, Michael; Pavelsky, Tamlin; Castellarin, Attilio; Brath, Armando

2017-04-01

The upcoming SWOT (Surface Water and Ocean Topography) satellite mission will provide unprecedented bi-dimensional observations of terrestrial water surface heights along rivers wider than 100m. Despite the literature reports several activities showing possible uses of SWOT products, potential and limitations of satellite observations still remain poorly understood and investigated. We present one of the first analyses regarding the spatial observation of water surface elevation expected from SWOT for a 140 km reach of the middle-lower portion of the Po River, in Northern Italy. The river stretch is characterized by a main channel varying from 100-500 m in width and a floodplain delimited by a system of major embankments that can be as wide as 5 km. The reconstruction of the hydraulic behavior of the Po River is performed by means of a quasi-2D model built with detailed topographic and bathymetric information (LiDAR, 2m resolution), while the simulation of remotely sensed hydrometric data is performed with a SWOT simulator that mimics the satellite sensor characteristics. Referring to water surface elevations associated with different flow conditions (maximum, minimum and average flow) this work characterizes the spatial observations provided by SWOT and highlights the strengths and limitations of the expected products. The analysis provides a robust reference for spatial water observations that will be available from SWOT and assesses possible effects of river embankments, river width and river topography under different hydraulic conditions. Results of the study characterize the expected accuracy of the upcoming SWOT mission and provide additional insights towards the appropriate exploitation of future hydrological observations.

Biogeochemistry and Hydrology in Streams Impacted by Legacy Sediments and Urbanization: Implications for Stream Restoration

EPA Science Inventory

The groundwater–surface water interface, consisting of shallow groundwater adjacent to stream channels, is a hot spot for nitrogen removal processes, a storage zone for other solutes, and a target for restoration activities. Characterizing groundwater-surface water interac...

Characterizing Metal-Based Nanoparticles in Surface Water by Single-Particle ICPMS

EPA Science Inventory

Engineered metal-based nanomaterials are being used in increasing quantities in consumer and industrial products. These materials may be introduced into surface waters by a variety of paths depending on usage, and will be superimposed on concentrations of other particles containi...

Microbial and chemical contamination during and after flooding in the Ohio River-Kentucky, 2011.

PubMed

Yard, Ellen E; Murphy, Matthew W; Schneeberger, Chandra; Narayanan, Jothikumar; Hoo, Elizabeth; Freiman, Alexander; Lewis, Lauren S; Hill, Vincent R

2014-09-19

Surface water contaminants in Kentucky during and after 2011 flooding were characterized. Surface water samples were collected during flood stage (May 2-4, 2011; n = 15) and after (July 25-26, 2011; n = 8) from four different cities along the Ohio River and were analyzed for the presence of microbial indicators, pathogens, metals, and chemical contaminants. Contaminant concentrations during and after flooding were compared using linear and logistic regression. Surface water samples collected during flooding had higher levels of E. coli, enterococci, Salmonella, Campylobacter, E. coli O157:H7, adenovirus, arsenic, copper, iron, lead, and zinc compared to surface water samples collected 3-months post-flood (P < 0.05). These results suggest that flooding increases microbial and chemical loads in surface water. These findings reinforce commonly recommended guidelines to limit exposure to flood water and to appropriately sanitize contaminated surfaces and drinking wells after contamination by flood water.

Microbial and chemical contamination during and after flooding in the Ohio River—Kentucky, 2011

PubMed Central

Yard, Ellen E.; Murphy, Matthew W.; Schneeberger, Chandra; Narayanan, Jothikumar; Hoo, Elizabeth; Freiman, Alexander; Lewis, Lauren S.; Hill, Vincent R.

2017-01-01

Surface water contaminants in Kentucky during and after 2011 flooding were characterized. Surface water samples were collected during flood stage (May 2–4, 2011; n = 15) and after (July 25–26, 2011; n = 8) from four different cities along the Ohio River and were analyzed for the presence of microbial indicators, pathogens, metals, and chemical contaminants. Contaminant concentrations during and after flooding were compared using linear and logistic regression. Surface water samples collected during flooding had higher levels of E. coli, enterococci, Salmonella, Campylobacter, E. coli O157:H7, adenovirus, arsenic, copper, iron, lead, and zinc compared to surface water samples collected 3-months post-flood (P < 0.05). These results suggest that flooding increases microbial and chemical loads in surface water. These findings reinforce commonly recommended guidelines to limit exposure to flood water and to appropriately sanitize contaminated surfaces and drinking wells after contamination by flood water. PMID:24967556

Irrigation Water and Nitrate Loss Characterization in South Florida Nurseries: Cumulative Volumes, Runoff Rates, NO3-N Concentrations and Loadings, and Implications for Management

USDA-ARS?s Scientific Manuscript database

Enrichment of surface water with nitrate-nitrogen is a significant problem throughout the world. In support of developing a method for removing nitrate from water using denitrification, this project characterized runoff events at two nurseries in South Florida to provide information needed for desi...

Evaluation of automated urban surface water extraction from Sentinel-2A imagery using different water indices

NASA Astrophysics Data System (ADS)

Yang, Xiucheng; Chen, Li

2017-04-01

Urban surface water is characterized by complex surface continents and small size of water bodies, and the mapping of urban surface water is currently a challenging task. The moderate-resolution remote sensing satellites provide effective ways of monitoring surface water. This study conducts an exploratory evaluation on the performance of the newly available Sentinel-2A multispectral instrument (MSI) imagery for detecting urban surface water. An automatic framework that integrates pixel-level threshold adjustment and object-oriented segmentation is proposed. Based on the automated workflow, different combinations of visible, near infrared, and short-wave infrared bands in Sentinel-2 image via different water indices are first compared. Results show that object-level modified normalized difference water index (MNDWI with band 11) and automated water extraction index are feasible in urban surface water mapping for Sentinel-2 MSI imagery. Moreover, comparative results are obtained utilizing optimal MNDWI from Sentinel-2 and Landsat 8 images, respectively. Consequently, Sentinel-2 MSI achieves the kappa coefficient of 0.92, compared with that of 0.83 from Landsat 8 operational land imager.

Fractal characterization and wettability of ion treated silicon surfaces

NASA Astrophysics Data System (ADS)

Yadav, R. P.; Kumar, Tanuj; Baranwal, V.; Vandana, Kumar, Manvendra; Priya, P. K.; Pandey, S. N.; Mittal, A. K.

2017-02-01

Fractal characterization of surface morphology can be useful as a tool for tailoring the wetting properties of solid surfaces. In this work, rippled surfaces of Si (100) are grown using 200 keV Ar+ ion beam irradiation at different ion doses. Relationship between fractal and wetting properties of these surfaces are explored. The height-height correlation function extracted from atomic force microscopic images, demonstrates an increase in roughness exponent with an increase in ion doses. A steep variation in contact angle values is found for low fractal dimensions. Roughness exponent and fractal dimensions are found correlated with the static water contact angle measurement. It is observed that after a crossover of the roughness exponent, the surface morphology has a rippled structure. Larger values of interface width indicate the larger ripples on the surface. The contact angle of water drops on such surfaces is observed to be lowest. Autocorrelation function is used for the measurement of ripple wavelength.

Synthesis and characterization of methyltrihydroxysilane water repellent

NASA Astrophysics Data System (ADS)

Abidin, A. Z.; Harjandi, M. N.; Wirawan, V.; Suharno, S. M.

2018-03-01

Methyltrihydroxysilane (CH3Si (OH)3) as a water repellent has been synthesized from trichloromethylsilane and ethanol by varying their composition, reaction condition, and the addition of nanosilica. The properties of the material have been characterized using FTIR for identification of raw materials and water repellent product, SEM for identification of water repellent coating surface, and tensiometer for measurement of water repellent contact angle. The FTIR spectra confirm the reaction of the water-repellent formation. The water repellent product was applied by spraying or dip coating on the automotive window surface. This study shows that the best ethanol composition is 91% and the best contact angle of synthesized water repellent material is 149,46°. This contact angle is higher than that of a commercial product, which shows it as a property of the superhydrophobic material. Water repellency properties increase as the composition of trichloromethylsilane increases. It shows that the increasing of trichloromethylsilane composition can also increase methyltrihydroxysilane formation. However, glass surface becomes opaque as the composition of trichloromethylsilane increase because methyltrihydroxysilane will create the Si-O-Si layer that has a white color. The addition of nanomaterial also increases the surface roughness, but a binder is required to bind nanomaterial to the water-repellent layer. For an application, dip coating has better water repellency than spraying. This is because dip coating method creates more homogenous nanomaterial precipitation on the surface. On the other hand, the level of transparency is worse. Therefore, the water repellent of trichloromethylsilane is recommended for applications that do not need clarity such bathroom glass wall.

Statistical robustness of machine-learning estimates for characterizing a groundwater-surface water system, Southland, New Zealand

NASA Astrophysics Data System (ADS)

Friedel, M. J.; Daughney, C.

2016-12-01

The development of a successful surface-groundwater management strategy depends on the quality of data provided for analysis. This study evaluates the statistical robustness when using a modified self-organizing map (MSOM) technique to estimate missing values for three hypersurface models: synoptic groundwater-surface water hydrochemistry, time-series of groundwater-surface water hydrochemistry, and mixed-survey (combination of groundwater-surface water hydrochemistry and lithologies) hydrostratigraphic unit data. These models of increasing complexity are developed and validated based on observations from the Southland region of New Zealand. In each case, the estimation method is sufficiently robust to cope with groundwater-surface water hydrochemistry vagaries due to sample size and extreme data insufficiency, even when >80% of the data are missing. The estimation of surface water hydrochemistry time series values enabled the evaluation of seasonal variation, and the imputation of lithologies facilitated the evaluation of hydrostratigraphic controls on groundwater-surface water interaction. The robust statistical results for groundwater-surface water models of increasing data complexity provide justification to apply the MSOM technique in other regions of New Zealand and abroad.

Approaches to characterizing biogeochemistry effects of groundwater and surface water interaction at the riparian interface

EPA Science Inventory

Groundwater-surface water interaction (GSI) in riparian ecosystems strongly influences biological activity that controls nutrient flux and processes. Shallow groundwater in riparian zones is a hot spot for nitrogen removal processes, a storage zone for solutes, and a target for ...

Single Particle ICPMS for Characterizing Metal-based Nanoparticles and Monitoring Transformation Processes in Surface Water

EPA Science Inventory

Engineered metal-based nanomaterials will likely be used in increasing quantities in consumer and industrial products. These may be introduced into surface waters by a variety of paths depending on usage. Other naturally occurring and anthropogenic particles containing these met...

Analytical characterization of selective benthic flux components in estuarine and coastal waters

USGS Publications Warehouse

King, Jeffrey N.

2011-01-01

Benthic flux is the rate of flow across the bed of a water body, per unit area of bed. It is forced by component mechanisms, which interact. For example, pressure gradients across the bed, forced by tide, surface gravity waves, density gradients, bed–current interaction, turbulence, and terrestrial hydraulic gradients, drive an advective benthic flux of water and constituents between estuarine and coastal waters, and surficial aquifers. Other mechanisms also force benthic flux, such as chemical gradients, bioturbation, and dispersion. A suite of component mechanisms force a total benthic flux at any given location, where each member of the suite contributes a component benthic flux. Currently, the types and characteristics of component interactions are not fully understood. For example, components may interact linearly or nonlinearly, and the interaction may be constructive or destructive. Benthic flux is a surface water–groundwater interaction process. Its discharge component to a marine water body is referred to, in some literature, as submarine groundwater discharge. Benthic flux is important in characterizing water and constituent budgets of estuarine and coastal systems. Analytical models to characterize selective benthic flux components are reviewed. Specifically, these mechanisms are for the component associated with the groundwater tidal prism, and forced by surface gravity wave setup, surface gravity waves on a plane bed, and the terrestrial hydraulic gradient. Analytical models are applied to the Indian River Lagoon, Florida; Great South Bay, New York; and the South Atlantic Bight in South Carolina and portions of North Carolina.

Characterizing Variability in Ohio River NOM and Validating Reconstituted Freeze-Dried NOM as a Surrogate for its Aqueous Source

EPA Science Inventory

Surface water contains natural organic matter (NOM) which reacts with disinfectants creating disinfection byproducts (DBPs), some of which are USEPA regulated contaminants. Characterizing NOM can provide important insight on DBP formation and water treatment process adaptation t...

Characterizing Water Quality in Students' Own Community

ERIC Educational Resources Information Center

Lunsford, S. K.; Speelman, Nicole; Yeary, Amber; Slattery, William

2007-01-01

The surface water quality studies are developed to help first year college students who are preparing to become high school teachers. These water quality impact studies allow students to correlate geologic conditions and chemistry.

Fecal pollution source tracking toolbox for identification, evaluation and characterization of fecal contamination in receiving urban surface waters and groundwater.

PubMed

Tran, Ngoc Han; Gin, Karina Yew-Hoong; Ngo, Huu Hao

2015-12-15

The quality of surface waters/groundwater of a geographical region can be affected by anthropogenic activities, land use patterns and fecal pollution sources from humans and animals. Therefore, the development of an efficient fecal pollution source tracking toolbox for identifying the origin of the fecal pollution sources in surface waters/groundwater is especially helpful for improving management efforts and remediation actions of water resources in a more cost-effective and efficient manner. This review summarizes the updated knowledge on the use of fecal pollution source tracking markers for detecting, evaluating and characterizing fecal pollution sources in receiving surface waters and groundwater. The suitability of using chemical markers (i.e. fecal sterols, fluorescent whitening agents, pharmaceuticals and personal care products, and artificial sweeteners) and/or microbial markers (e.g. F+RNA coliphages, enteric viruses, and host-specific anaerobic bacterial 16S rDNA genetic markers) for tracking fecal pollution sources in receiving water bodies is discussed. In addition, this review also provides a comprehensive approach, which is based on the detection ratios (DR), detection frequencies (DF), and fate of potential microbial and chemical markers. DR and DF are considered as the key criteria for selecting appropriate markers for identifying and evaluating the impacts of fecal contamination in surface waters/groundwater. Copyright © 2015 Elsevier B.V. All rights reserved.

Ground-water and surface-water elevations in the Fairbanks International Airport area, Alaska, 1990-96, and selected geohydrologic report references

USGS Publications Warehouse

Claar, David V.; Lilly, Michael R.

1997-01-01

Ground-water and surface-water elevation data were collected at 61 sites from 1990 to 1996 by the U.S. Geological Survey in cooperation with the Alaska Department of Transportation and Public Facilities, Fairbanks International Airport. Water-surface elevations were measured in 41 ground-water observation wells and at 20 surface-water sites to help characterize the geohydrology of the Fairbanks International Airport area. From 1990 to 1993, data were collected in the vicinity of the former fire-training area at the airport. From 1993 to 1996, the data-collection area was expanded to include the entire airport area. The total number of data-collection sites varied each year because of changing project objectives and increased understanding of the geohydrology in the area.

Nanoscale Surface Characterization of Aqueous Copper Corrosion: Effects of Immersion Interval and Orthophosphate Concentration

EPA Science Inventory

Morphology changes for copper surfaces exposed to different water parameters were investigated at the nanoscale with atomic force microscopy (AFM), as influenced by changes in pH and the levels of orthophosphate ions. Synthetic water samples were designed to mimic physiological c...

Nanoscale Investigation of the Impact of pH and Orthophosphate on the Corrosion of Copper Surfaces in Water

EPA Science Inventory

Advanced surface characterization techniques were used to systematically investigate the passivation of copper during corrosion in water as impacted by pH and orthophosphate. Atomic force microscopy, depth profiling with time-of-flight secondary ion mass spectrometry and X-ray d...

Fluorescent solute-partitioning characterization of layered soft contact lenses.

PubMed

Dursch, T J; Liu, D E; Oh, Y; Radke, C J

2015-03-01

Partitioning of aqueous packaging, wetting, and care-solution agents into and out of soft contact lenses (SCLs) is important for improving wear comfort and also for characterizing lens physico-chemical properties. We illustrate both features of partitioning by application of fluorescent-solute partitioning into DAILIES TOTAL1® (delefilcon A) water-gradient SCLs, which exhibit a layered structure of a silicone-hydrogel (SiHy) core sandwiched between thin surface-gel layers. Two-photon fluorescence confocal laser-scanning microscopy and attenuated total-reflectance Fourier-transform infrared spectroscopy (ATR-FTIR) characterize the lens and assess uptake profiles of six prototypical fluorescent solutes. Comparison of solute uptake in a SiHy-core prototype lens (i.e., O2OPTIX(TM)) validates the core SiHy structure of DAILIESTOTAL1®. To establish surface-layer charge, partition coefficients and water contents are obtained for aqueous pH values of 4 and 7.4. Solute fluorescence-intensity profiles clearly confirm a layered structure for the DAILIES TOTAL1® lenses. In all cases, aqueous solute partition coefficients are greater in the surface layers than in the SiHy core, signifying higher water in the surface gels. ATR-FTIR confirms surface-layer mass water contents of 82±3%. Water uptake and hydrophilic-solute uptake at pH 4 compared with that at pH 7.4 reveal that the surface-gel layers are anionic at physiologic pH 7.4, whereas both the SiHy core and O2OPTIX™ (lotrafilcon B) are nonionic. We successfully confirm the layered structure of DAILIES TOTAL1®, consisting of an 80-μm-thick SiHy core surrounded by 10-μm-thick polyelectrolyte surface-gel layers of significantly greater water content and aqueous solute uptake compared with the core. Accordingly, fluorescent-solute partitioning in SCLs provides information on gel structure and composition, in addition to quantifying uptake and release amounts and rates. Copyright © 2014 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Characterizing water surface elevation under different flow conditions for the upcoming SWOT mission

NASA Astrophysics Data System (ADS)

Domeneghetti, A.; Schumann, G. J.-P.; Frasson, R. P. M.; Wei, R.; Pavelsky, T. M.; Castellarin, A.; Brath, A.; Durand, M. T.

2018-06-01

The Surface Water and Ocean Topography satellite mission (SWOT), scheduled for launch in 2021, will deliver two-dimensional observations of water surface heights for lakes, rivers wider than 100 m and oceans. Even though the scientific literature has highlighted several fields of application for the expected products, detailed simulations of the SWOT radar performance for a realistic river scenario have not been presented in the literature. Understanding the error of the most fundamental "raw" SWOT hydrology product is important in order to have a greater awareness about strengths and limits of the forthcoming satellite observations. This study focuses on a reach (∼140 km in length) of the middle-lower portion of the Po River, in Northern Italy, and, to date, represents one of the few real-case analyses of the spatial patterns in water surface elevation accuracy expected from SWOT. The river stretch is characterized by a main channel varying from 100 to 500 m in width and a large floodplain (up to 5 km) delimited by a system of major embankments. The simulation of the water surface along the Po River for different flow conditions (high, low and mean annual flows) is performed with inputs from a quasi-2D model implemented using detailed topographic and bathymetric information (LiDAR, 2 m resolution). By employing a simulator that mimics many SWOT satellite sensor characteristics and generates proxies of the remotely sensed hydrometric data, this study characterizes the spatial observations potentially provided by SWOT. We evaluate SWOT performance under different hydraulic conditions and assess possible effects of river embankments, river width, river topography and distance from the satellite ground track. Despite analyzing errors from the raw radar pixel cloud, which receives minimal processing, the present study highlights the promising potential of this Ka-band interferometer for measuring water surface elevations, with mean elevation errors of 0.1 cm and 21 cm for high and low flows, respectively. Results of the study characterize the expected performance of the upcoming SWOT mission and provide additional insights into potential applications of SWOT observations.

Characterization of organic composition in snow and surface waters in the Athabasca Oil Sands Region, using ultrahigh resolution Fourier transform mass spectrometry.

PubMed

Yi, Y; Birks, S J; Cho, S; Gibson, J J

2015-06-15

This study was conducted to characterize the composition of dissolved organic compounds present in snow and surface waters in the Athabasca Oil Sands Region (AOSR) with the goal of identifying whether atmospherically-derived organic compounds present in snow are a significant contributor to the compounds detected in surface waters (i.e., rivers and lakes). We used electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR MS) to characterize the dissolved organic compound compositions of snow and surface water samples. The organic profiles obtained for the snow samples show compositional differences between samples from near-field sites (<5 km from oil sands activities) and those from more distant locations (i.e., far-field sites). There are also significant compositional differences between samples collected in near-field sites and surface water samples in the AOSR. The composition of dissolved organic compounds at the upstream Athabasca River site (i.e., Athabasca River at Athabasca) is found to be different from samples obtained from downstream sites in the vicinity of oil sands operations (i.e., Athabasca River at Fort McMurray and Athabasca River at Firebag confluence). The upstream Athabasca River sites tended to share some compositional similarities with far-field snow deposition, while the downstream Athabasca River sites are more similar to local lakes and tributaries. This contrast likely indicates the relative role of regional snowmelt contributions to the Athabasca River vs inputs from local catchments in the reach downstream of Fort McMurray. Copyright © 2015 Elsevier B.V. All rights reserved.

Towards A Synthesis Of Land Dynamics And Hydrological Processes Across Central Asia

NASA Astrophysics Data System (ADS)

Sokolik, I. N.; Tatarskii, V.; Shiklomanov, A. I.; Henebry, G. M.; de Beurs, K.; Laruelle, M.

2016-12-01

We present results from an ongoing project that aims to synthesize land dynamics, hydrological processes, and socio-economic changes across the five countries of Central Asia. We have developed a fully coupled model that takes into account the reconstructed land cover and land use dynamics to simulate dust emissions. A comparable model has been developed to model smoke emissions from wildfires. Both models incorporate land dynamics explicitly. We also present a characterization of land surface change based on a suite of MODIS products including vegetation indices, evapotranspiration, land surface temperature, and albedo. These results are connected with ongoing land privatization reforms that different across the region. We also present a regional analysis of water resources, including the significant impact of using surface water for irrigation in an arid landscape. We applied the University of New Hampshire hydrological model to understand the consequences of changes in climate, water, and land use on regional hydrological processes and water use. Water security and its dynamic have been estimated through an analysis of multiple indices and variables characterizing the water availability and water use. The economic consequences of the water privatization processes will be presented.

Highly Transparent Water-Repelling Surfaces based on Biomimetic Hierarchical Structure

NASA Astrophysics Data System (ADS)

Wooh, Sanghyuk; Koh, Jai; Yoon, Hyunsik; Char, Kookheon

2013-03-01

Nature is a great source of inspiration for creating unique structures with special functions. The representative examples of water-repelling surfaces in nature, such as lotus leaves, rose petals, and insect wings, consist of an array of bumps (or long hairs) and nanoscale surface features with different dimension scales. Herein, we introduced a method of realizing multi-dimensional hierarchical structures and water-repellancy of the surfaces with different drop impact scenarios. The multi-dimensional hierarchical structures were fabricated by soft imprinting method with TiO2 nanoparticle pastes. In order to achieve the enhanced hydrophobicity, fluorinated moieties were attached to the etched surfaces to lower the surface energy. As a result, super-hydrophobic surfaces with high transparency were realized (over 176° water contact angle), and for further investigation, these hierarchical surfaces with different drop impact scenarios were characterized by varying the impact speed, drop size, and the geometry of the surfaces.

Surface modification of paper on a continuous atmospheric-pressure-plasma system

NASA Astrophysics Data System (ADS)

Cruz-Barba, Luis Emilio

Plasma technologies for the continuous modification of materials in atmospheric-pressure-plasma conditions were used to evaluate the surface modification of paper under different plasma conditions. The generation of hydrophobic layers was used to characterize the efficiency of the originally designed system for future application in the paper industry. Generation of hydrophobic layers was carried out by deposition of thin layers from fluorine containing gases, as well as cross-linking of pre-deposited thin layers of hydrophobic materials, such as fluoropolymers and silicones, in a continuous system plasma reactor (CSPR). Physical and chemical characterization of these layers was carried out by X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), scanning electron microscopy (SEM), contact angle goniometry, and water absorption evaluations. Pure gaseous CF4 and a CF4/CH4 mixture were used to deposit fluorinated layers, rendering paper surfaces with low to moderate relative surface atomic contents of fluorine (2.5 to 16.3%). Morphological characterization revealed that the deposition consists of small clusters of fluorinated species scattered on the surface. Contact angle evaluations (50°--70°) indicated a reduction in the water affinity of the paper. Thin layers of fluoropolymer pre-deposited on paper surfaces were cross-linked in the presence of CF4, CF4/CH4, and NH 3 plasmas. All of the gases proved to be effective for the cross-linking under different conditions. These cross-linked layers were determined to maintain the original polymer structure, consisting mainly of CF2-CF 2 and small quantities of CFx. Surface characterization by AFM indicated lower roughness values compared to the untreated additive-free paper (45.1 vs 67.1 nm). Paper samples treated by this approach showed a highly hydrophobic character with up to 160° contact angles, and water absorption was reduced by as much as 61.6%. Silicone layers were cross-linked in the presence of argon and oxygen plasmas. Characterization of the silicone-coated paper indicated, as in the case of fluoropolymers, the retention of the original chemical structure. Surface roughness values (AFM) were in the range of 11.8 to 18.2 nm, evidence of a very smooth surface. High hydrophobicity levels were reached, as shown by contact angles of up to 126°, and water absorption showed a maximum reduction of 76.8%.

Quadrant III RFI draft report: Volume 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1992-12-01

The purpose of the RCRA Facility Investigation (RFI) at The Portsmouth Gaseous Diffusion Plant (PORTS) is to acquire, analyze and interpret data that will: characterize the environmental setting, including ground water, surface water and sediment, soil and air; define and characterize sources of contamination; characterize the vertical and horizontal extent and degree of contamination of the environment; assess the risk to human health and the environment resulting from possible exposure to contaminants; and support the Corrective Measures Study (CMS), which will follow the RFI, if required. A total of 18 Solid Waste Management Units (SWMU's) were investigated. All surficial soilmore » samples (0--2 ft), sediment samples and surface-water samples proposed in the approved Quadrant III RFI Work Plan were collected as specified in the approved work plan and RFI Sampling Plan. All soil, sediment and surface-water samples were analyzed for parameters specified from the Target Compound List and Target Analyte List (TCL/TAL) as listed in the US EPA Statement of Work for Inorganic (7/88a) and Organic (2/88b) analyses for Soil and Sediment, and analyses for fluoride, Freon-113 and radiological parameters (total uranium, gross alpha, gross beta and technetium).« less

Quadrant III RFI draft report: Volume 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1992-12-01

The purpose of the RCRA Facility Investigation (RFI) at The Portsmouth Gaseous Diffusion Plant (PORTS) is to acquire, analyze and interpret data that will: characterize the environmental setting, including ground water, surface water and sediment, soil and air; define and characterize sources of contamination; characterize the vertical and horizontal extent and degree of contamination of the environment; assess the risk to human health and the environment resulting from possible exposure to contaminants; and support the Corrective Measures Study (CMS), which will follow the RFI, if required. A total of 18 Solid Waste Management Units (SWMU`s) were investigated. All surficial soilmore » samples (0--2 ft), sediment samples and surface-water samples proposed in the approved Quadrant III RFI Work Plan were collected as specified in the approved work plan and RFI Sampling Plan. All soil, sediment and surface-water samples were analyzed for parameters specified from the Target Compound List and Target Analyte List (TCL/TAL) as listed in the US EPA Statement of Work for Inorganic (7/88a) and Organic (2/88b) analyses for Soil and Sediment, and analyses for fluoride, Freon-113 and radiological parameters (total uranium, gross alpha, gross beta and technetium).« less

Characterization of MOSkin detector for in vivo skin dose measurement during megavoltage radiotherapy

PubMed Central

Jong, Wei Loong; Wong, Jeannie Hsiu Ding; Ng, Kwan Hoong; Ho, Gwo Fuang; Cutajar, Dean L.; Rosenfeld, Anatoly B.

2014-01-01

In vivo dosimetry is important during radiotherapy to ensure the accuracy of the dose delivered to the treatment volume. A dosimeter should be characterized based on its application before it is used for in vivo dosimetry. In this study, we characterize a new MOSFET‐based detector, the MOSkin detector, on surface for in vivo skin dosimetry. The advantages of the MOSkin detector are its water equivalent depth of measurement of 0.07 mm, small physical size with submicron dosimetric volume, and the ability to provide real‐time readout. A MOSkin detector was calibrated and the reproducibility, linearity, and response over a large dose range to different threshold voltages were determined. Surface dose on solid water phantom was measured using MOSkin detector and compared with Markus ionization chamber and GAFCHROMIC EBT2 film measurements. Dependence in the response of the MOSkin detector on the surface of solid water phantom was also tested for different (i) source to surface distances (SSDs); (ii) field sizes; (iii) surface dose; (iv) radiation incident angles; and (v) wedges. The MOSkin detector showed excellent reproducibility and linearity for dose range of 50 cGy to 300 cGy. The MOSkin detector showed reliable response to different SSDs, field sizes, surface, radiation incident angles, and wedges. The MOSkin detector is suitable for in vivo skin dosimetry. PACS number: 87.55.Qr PMID:25207573

Water quality in the vicinity of Mosquito Creek Lake, Trumbull County, Ohio, in relation of the chemistry of locally occurring oil, natural gas, and brine

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barton, G.J.; Burruss, R.C.; Ryder, R.T.

1998-12-31

The purpose of this report is to describe current water quality and the chemistry of oil, natural gas, and brine in the Mosquito Creek Lake area. Additionally, these data are used to characterize water quality in the Mosquito Creek Lake area in relation to past oil and natural gas well drilling and production. To meet the overall objective, several goals for this investigation were established. These include (1) collect water-quality and subsurface-gas data from shallow sediments and rock that can be used for future evaluation of possible effects of oil and natural gas well drilling and production on water supplies,more » (2) characterize current surface-water and ground-water quality as it relates to the natural occurrence and (or) release of oil, gas, and brine (3) sample and chemically characterize the oil in the shallow Mecca Oil Pool, gas from the Berea and Cussewago Sandstone aquifers, and the oil, gas, and brine from the Clinton sandstone, and (4) identify areas where aquifers are vulnerable to contamination from surface spills at oil and natural gas drilling and production sites.« less

An eddy covariance system to characterize the atmospheric surface layer and turbulent latent heat fluxes over a debris-covered Himalayan glacier.

NASA Astrophysics Data System (ADS)

Litt, Maxime; Steiner, Jakob F.; Stigter, Emmy E.; Immerzeel, Walter; Shea, Joseph Michael

2017-04-01

Over debris-covered glaciers, water content variations in the debris layer can drive significant changes in its thermal conductivity and significantly impact melt rates. Since sublimation and evaporation are favoured in high-altitude conditions, e.g., low atmospheric pressure and high wind speeds, they are expected to strongly influence the water balance of the debris-layer. Dedicated latent heat fluxes measurements at the debris surface are essential to characterize the debris heat conductivity in order to assess underlying ice melt. Furthermore, the contribution of the turbulent fluxes in the surface energy balance over debris covered glacier remains uncertain since they are generally evaluated through similarity methods which might not be valid in complex terrain. We present the first results of a 15-day eddy-covariance experiment installed at the end of the monsoon (September-October) on a 3-m tower above the debris-covered Lirung glacier in Nepal. The tower also included measurements of the 4 radiation components. The eddy covariance measurements allowed for the characterization of the turbulence in the atmospheric surface layer, as well as the direct measurements of evaporation, sublimation and turbulent sensible heat fluxes. The experiment helps us to evaluate the contribution of turbulent fluxes to the surface energy balance over this debris-covered glacier, through a precise characterization of the overlying turbulent atmospheric surface layer. It also helps to study the role of the debris-layer water content changes through evaporation and sublimation and its feedback on heat conduction in this layer. The large observed turbulent fluxes play a significant role in the energy balance at the debris surface and significantly influence debris moisture, conductivity and subsequently underlying ice melt.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lazauskas, A., E-mail: Algirdas.LAZAUSKAS@stud.ktu.lt; Guobienė, A., E-mail: Asta.GUOBIENE@ktu.lt; Prosyčevas, I., E-mail: IGORPROS@mail.ru

This work investigates water droplet behavior on superhydrophobic (water contact angle value of 162 ± 1°) SiO{sub 2} nanocomposite films subjected to repetitive icing/deicing treatments, changes in SiO{sub 2} nanocomposite film surface morphology and their non-wetting characteristics. During the experiment, water droplets on SiO{sub 2} nanocomposite film surface are subjected to a series of icing and deicing cycles in a humid (∼ 70% relative humidity) atmosphere and the resulting morphological changes are monitored and characterized using atomic force microscopy (AFM) and contact angle measurements. Our data show that the formation of the frozen or thawed water droplet, with no furthermore » shape change, on superhydrophobic SiO{sub 2} nanocomposite film, is obtained faster within each cycle as the number of the icing/deicing cycles increases. After 10 icing and deicing cycles, the superhydrophobic SiO{sub 2} nanocomposite film had a water contact angle value of 146 ± 2° which is effectively non-superhydrophobic. AFM analysis showed that the superhydrophobic SiO{sub 2} nanocomposite film surface area under the water droplet undergoes gradual mechanical damage during the repetitive icing/deicing cycles. We propose a possible mechanism of the morphological changes to the film surface that take place during the consecutive icing/deicing experiments. - Highlights: • Superhydrophobic film is subjected to repetitive icing/deicing treatments. • Water droplet shape transition is recorded and characterized thereafter. • Atomic force microscopy and contact angle measurements are performed. • The surface undergoes gradual mechanical damage during repetitive icing/deicing. • Mechanism for the observed surface morphological changes is suggested.« less

High Pressure Cosmochemistry of Major Planetary Interiors: Laboratory Studies of the Water-rich Region of the System Ammonia-water

NASA Technical Reports Server (NTRS)

Nicol, M.; Johnson, M.; Koumvakalis, A. S.

1985-01-01

The behavior of gas-ice mixtures in major planets at very high pressures was studied. Some relevant pressure-temperature-composition (P-T-X) regions of the hydrogen (H2)-helium (He)-water (H2O-ammonia (NH3)-methane (CH4) phase diagram were determined. The studies, and theoretical model, of the relevant phases, are needed to interpret the compositions of ice-gas systems at conditions of planetary interest. The compositions and structures of a multiphase, multicomponent system at very high pressures care characterized, and the goal is to characterize this system over a wide range of low and high temperatures. The NH3-H2O compositions that are relevant to planetary problems yet are easy to prepare were applied. The P-T surface of water was examined and the corresponding surface for NH3 was determined. The T-X diagram of ammonia-water at atmospheric pressure was studied and two water-rich phases were found, NH3-2H2O (ammonia dihydrate), which melts incongruently, and NH3.H2O (ammonia monohydrate), which is nonstoichiometric and melts at a higher temperature than the dihydrate. It is suggested that a P-T surface at approximately the monohydrate composition and the P-X surface at room temperature is determined.

High pressure rinsing system comparison

DOE Office of Scientific and Technical Information (OSTI.GOV)

D. Sertore; M. Fusetti; P. Michelato

2007-06-01

High pressure rinsing (HPR) is a key process for the surface preparation of high field superconducting cavities. A portable apparatus for the water jet characterization, based on the transferred momentum between the water jet and a load cell, has been used in different laboratories. This apparatus allows to collected quantitative parameters that characterize the HPR water jet. In this paper, we present a quantitative comparison of the different water jet produced by various nozzles routinely used in different laboratories for the HPR process

Water quality in the Cambridge, Massachusetts, drinking-water source area, 2005-8

USGS Publications Warehouse

Smith, Kirk P.; Waldron, Marcus C.

2015-01-01

During 2005-8, the U.S. Geological Survey, in cooperation with the Cambridge, Massachusetts, Water Department, measured concentrations of sodium and chloride, plant nutrients, commonly used pesticides, and caffeine in base-flow and stormwater samples collected from 11 tributaries in the Cambridge drinking-water source area. These data were used to characterize current water-quality conditions, to establish a baseline for future comparisons, and to describe trends in surface-water quality. The data also were used to assess the effects of watershed characteristics on surface-water quality and to inform future watershed management.

Potential for Small Unmanned Aircraft Systems applications for identifying groundwater-surface water exchange in a meandering river reach

USGS Publications Warehouse

Pai, H.; Malenda, H.; Briggs, Martin A.; Singha, K.; González-Pinzón, R.; Gooseff, M.; Tyler, S.W.; ,

2017-01-01

The exchange of groundwater and surface water (GW-SW), including dissolved constituents and energy, represents a critical yet challenging characterization problem for hydrogeologists and stream ecologists. Here, we describe the use of a suite of high spatial-resolution remote-sensing techniques, collected using a small unmanned aircraft system (sUAS), to provide novel and complementary data to analyze GW-SW exchange. sUAS provided centimeter-scale resolution topography and water surface elevations, which are often drivers of exchange along the river corridor. Additionally, sUAS-based vegetation imagery, vegetation-top elevation, and normalized difference vegetation index (NDVI) mapping indicated GW-SW exchange patterns that are difficult to characterize from the land surface and may not be resolved from coarser satellite-based imagery. We combined these data with estimates of sediment hydraulic conductivity to provide a direct estimate of GW “shortcutting” through meander necks, which was corroborated by temperature data at the riverbed interface.

Potential for Small Unmanned Aircraft Systems Applications for Identifying Groundwater-Surface Water Exchange in a Meandering River Reach

NASA Astrophysics Data System (ADS)

Pai, H.; Malenda, H. F.; Briggs, M. A.; Singha, K.; González-Pinzón, R.; Gooseff, M. N.; Tyler, S. W.

2017-12-01

The exchange of groundwater and surface water (GW-SW), including dissolved constituents and energy, represents a critical yet challenging characterization problem for hydrogeologists and stream ecologists. Here we describe the use of a suite of high spatial resolution remote sensing techniques, collected using a small unmanned aircraft system (sUAS), to provide novel and complementary data to analyze GW-SW exchange. sUAS provided centimeter-scale resolution topography and water surface elevations, which are often drivers of exchange along the river corridor. Additionally, sUAS-based vegetation imagery, vegetation-top elevation, and normalized difference vegetation index mapping indicated GW-SW exchange patterns that are difficult to characterize from the land surface and may not be resolved from coarser satellite-based imagery. We combined these data with estimates of sediment hydraulic conductivity to provide a direct estimate of GW "shortcutting" through meander necks, which was corroborated by temperature data at the riverbed interface.

MICROBIAL CHARACTERIZATION OF DRINKING WATER SYSTEMS RECEIVING GROUNDWATER AND SURFACE WATER AS THE PRIMARY SOURCES OF WATER

EPA Science Inventory

Earlier descriptions of water distribution systems (WDS) microbial communities have relied on culturing techniques. These techniques are known to be highly selective in nature, but more importantly, they tend to grossly underestimate the microbial diversity of most environments. ...

Water interactions with condensed organic phases: a combined experimental and theoretical study of molecular-level processes

NASA Astrophysics Data System (ADS)

Johansson, Sofia M.; Kong, Xiangrui; Thomson, Erik S.; Papagiannakopoulos, Panos; Pettersson, Jan B. C.; Lovrić, Josip; Toubin, Céline

2016-04-01

Water uptake on aerosol particles modifies their chemistry and microphysics with important implications for air quality and climate. A large fraction of the atmospheric aerosol consists of organic aerosol particles or inorganic particles with condensed organic components. Here, we combine laboratory studies using the environmental molecular beam (EMB) method1 with molecular dynamics (MD) simulations to characterize water interactions with organic surfaces in detail. The over-arching aim is to characterize the mechanisms that govern water uptake, in order to guide the development of physics-based models to be used in atmospheric modelling. The EMB method enables molecular level studies of interactions between gases and volatile surfaces at near ambient pressure,1 and the technique may provide information about collision dynamics, surface and bulk accommodation, desorption and diffusion kinetics. Molecular dynamics simulations provide complementary information about the collision dynamics and initial interactions between gas molecules and the condensed phase. Here, we focus on water interactions with condensed alcohol phases that serve as highly simplified proxies for systems in the environment. Gas-surface collisions are in general found to be highly inelastic and result in efficient surface accommodation of water molecules. As a consequence, surface accommodation of water can be safely assumed to be close to unity under typical ambient conditions. Bulk accommodation is inefficient on solid alcohol and the condensed materials appear to produce hydrophobic surface structures, with limited opportunities for adsorbed water to form hydrogen bonds with surface molecules. Accommodation is significantly more efficient on the dynamic liquid alcohol surfaces. The results for n-butanol (BuOH) are particularly intriguing where substantial changes in water accommodation taking place over a 10 K interval below and above the BuOH melting point.2 The governing mechanisms for the observed water accommodation are discussed based on the combined EMB and MD results. The studies illustrate that the detailed surface properties of the condensed organic phase may substantially modify water uptake, with potential implications for the properties and action of aerosols and clouds in the Earth system. References: 1. X.R. Kong, E. S. Thomson, P. Papagiannakopoulos, S.M. Johansson, and J.B.C. Pettersson, Water Accommodation on Ice and Organic Surfaces: Insights from Environmental Molecular Beam Experiments. J. Phys. Chem. B 118 (2014) 13378-13386. 2. P. Papagiannakopoulos, X. Kong, E. S. Thomson, N. Marković, and J. B. C. Pettersson, Surface Transformations and Water Uptake on Liquid and Solid Butanol near the Melting Temperature. J. Phys. Chem. C 117 (2013) 6678-6685.

The glass-liquid transition of water on hydrophobic surfaces

NASA Astrophysics Data System (ADS)

Souda, Ryutaro

2008-09-01

Interactions of thin water films with surfaces of graphite and vitrified room-temperature ionic liquid [1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6])] were investigated using time-of-flight secondary ion mass spectrometry as a function of temperature and annealing time to elucidate the glass-liquid transition of water at the molecular level. Surface diffusion of water occurs at temperatures higher than 120K, thereby forming three-dimensional clusters (a two-dimensional layer) on the [bmim][PF6] (graphite) surface. The hydrophobic effect of the surface decreases with increasing coverage of water; the bulklike properties evolve up to 40 ML, as evidenced by the occurrence of film dewetting at around the conventional glass transition temperature (140K). Results also showed that aging is necessary for the water monolayer (a 40 ML water film) to dewet the graphite ([bmim][PF6]) surface. The occurrence of aging is explainable by the successive evolution of two distinct liquids during the glass-liquid transition: low density liquid is followed by supercooled liquid water. The water monolayer on graphite is characterized by the preferred orientation of unpaired OH groups toward the surface; this structure is arrested during the aging time despite the occurrence of surface diffusion. However, the water monolayer formed on the [bmim][PF6] surface agglomerates immediately after the commencement of surface diffusion. The structure of low density liquid tends to be arrested by the attractive interaction with the neighbors.

Water adsorption on surface-modified cellulose nanocrystals

NASA Astrophysics Data System (ADS)

Wei, Zonghui; Sinko, Robert; Keten, Sinan; Luijten, Erik

Cellulose nanocrystals (CNCs) have attracted much attention as a filler phase for polymer nanocomposites due to their impressive mechanical properties, low cost, and environmental sustainability. Despite their promise for this application, there are still numerous obstacles that prevent optimal performance of CNC-polymer nanocomposites, such as poor filler dispersion and high levels of water absorption. One way to mitigate these negative effects is to modify CNC surfaces. Computational approaches can be utilized to obtain direct insight into the properties of modified CNC surfaces and probe the interactions of CNCs with other materials to facilitate the experimental design of nanocomposites. We use atomistic grand-canonical Monte Carlo simulations to study how surface modification of ion-exchanged sulfated cellulose nanocrystals (Na-CNCs) impacts water adsorption. We find that methyl(triphenyl)phosphonium-exchanged CNCs adsorb less water than Na-CNCs at the same relative humidity, supporting recent experimental dynamic vapor sorption measurements. By characterizing the distribution and configuration of water molecules near the modified CNC surfaces we determine how surface modifications disrupt CNC-water interactions.

77 FR 40836 - Pennsylvania Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2012-07-11

....302. Number, Location and Depth of Monitoring Points The water quality monitoring system shall accurately characterize groundwater and surface water flow and chemistry and flow systems on the site and... properties of coal ash beneficially used and water quality monitoring requirements. Pennsylvania is...

Multi-temporal AirSWOT elevations on the Willamette river: error characterization and algorithm testing

NASA Astrophysics Data System (ADS)

Tuozzolo, S.; Frasson, R. P. M.; Durand, M. T.

2017-12-01

We analyze a multi-temporal dataset of in-situ and airborne water surface measurements from the March 2015 AirSWOT field campaign on the Willamette River in Western Oregon, which included six days of AirSWOT flights over a 75km stretch of the river. We examine systematic errors associated with dark water and layover effects in the AirSWOT dataset, and test the efficacies of different filtering and spatial averaging techniques at reconstructing the water surface profile. Finally, we generate a spatially-averaged time-series of water surface elevation and water surface slope. These AirSWOT-derived reach-averaged values are ingested in a prospective SWOT discharge algorithm to assess its performance on SWOT-like data collected from a borderline SWOT-measurable river (mean width = 90m).

Image processing developments and applications for water quality monitoring and trophic state determination

NASA Technical Reports Server (NTRS)

Blackwell, R. J.

1982-01-01

Remote sensing data analysis of water quality monitoring is evaluated. Data anaysis and image processing techniques are applied to LANDSAT remote sensing data to produce an effective operational tool for lake water quality surveying and monitoring. Digital image processing and analysis techniques were designed, developed, tested, and applied to LANDSAT multispectral scanner (MSS) data and conventional surface acquired data. Utilization of these techniques facilitates the surveying and monitoring of large numbers of lakes in an operational manner. Supervised multispectral classification, when used in conjunction with surface acquired water quality indicators, is used to characterize water body trophic status. Unsupervised multispectral classification, when interpreted by lake scientists familiar with a specific water body, yields classifications of equal validity with supervised methods and in a more cost effective manner. Image data base technology is used to great advantage in characterizing other contributing effects to water quality. These effects include drainage basin configuration, terrain slope, soil, precipitation and land cover characteristics.

Hydrochemistry of surface water and groundwater in the shale bedrock, Cross River Basin and Niger Delta Region, Nigeria

NASA Astrophysics Data System (ADS)

Nganje, T. N.; Hursthouse, A. S.; Edet, Aniekan; Stirling, D.; Adamu, C. I.

2017-05-01

Water chemistry in the shale bedrock of the Cretaceous-Tertiary of the Cross River and Niger Delta hydrological basins has been investigated using major ions. To carry out a characterization of the water bearing units, 30 and 16 representatives surface and groundwater samples were collected. The evolution of the water is characterized by enhanced content of sodium, calcium and sulphate as a result of leaching of shale rock. The spatial changes in groundwater quality of the area shows an anomalous concentrations of ions in the central parts, while lower values characterize the eastern part of the basin covering Ogoja, Ikom and Odukpani areas. The values of total dissolved solids (TDS) and ions increases down gradient in the direction of groundwater flow. The dissolution of halite and gypsum explains part of the contained Na+, Ca2+, Cl- and SO4 2-, but other processes such as ion exchange, silicate weathering and pyrite oxidation also contribute to water composition. The assessment with contamination indicators such as TDS, hardness, chloride, nitrate and sulphate indicates that the water in area is suitable for human consumption in some locations. Modelling using MINTEQA2 program shows that the water from all the shale water bearing units are under saturated with respect to gypsum.

Characterization and disinfection by-product formation potential of natural organic matter in surface and ground waters from Northern Florida

USGS Publications Warehouse

Rostad, C.E.; Leenheer, J.A.; Katz, B.; Martin, B.S.; Noyes, T.I.

2000-01-01

Streamwaters in northern Florida have large concentrations of natural organic matter (NOM), and commonly flow directly into the ground water system through karst features, such as sinkholes. In this study NOM from northern Florida stream and ground waters was fractionated, the fractions characterized by infrared (IR) and nuclear magnetic resonance (NMR), and then chlorinated to investigate their disinfection by-product (DBP) formation potential (FP). As the NOM character changed (as quantified by changes in NOM distribution in various fractions, such as hydrophilic acids or hydrophobic neutrals) due to migration through the aquifer, the total organic halide (TOX)-FP and trihalomethane (THM)-FP yield of each of these fractions varied also. In surface waters, the greatest DBP yields were produced by the colloid fraction. In ground waters, DBP yield of the hydrophobic acid fraction (the greatest in terms of mass) decreased during infiltration.

Characterizations of the Formation of Polydopamine-Coated Halloysite Nanotubes in Various pH Environments.

PubMed

Feng, Junran; Fan, Hailong; Zha, Dao-An; Wang, Le; Jin, Zhaoxia

2016-10-11

Recent studies demonstrated that polydopamine (PDA) coating is universal to nearly all substrates, and it endows substrates with biocompatibility, postfunctionality, and other useful properties. Surface chemistry of PDA coating is important for its postmodifications and applications. However, there is less understanding of the formation mechanism and surface functional groups of PDA layers generated in different conditions. Halloysite is a kind of clay mineral with tubular nanostructure. Water-swellable halloysite has unique reactivity. In this study, we have investigated the reaction of dopamine in the presence of water-swellable halloysite. We have tracked the reaction progresses in different pH environments by using UV-vis spectroscopy and surface-enhanced Raman spectroscopy (SERS). The surface properties of PDA on halloysite were clarified by X-ray photoelectron spectroscopy (XPS), SERS, Fourier transform infrared (FTIR) characterizations, zeta potential, surface wettability, and morphological characterizations. We noticed that the interaction between halloysite surface and dopamine strongly influences the surface functionality of coated PDA. In addition, pH condition further modulates surface functional groups, resulting in less content of secondary/aromatic amine in PDA generated in weak acidic environment. This study demonstrates that the formation mechanism of polydopamine becomes complex in the presence of inorganic nanomaterials. Substrate property and reaction condition dominate the functionality of obtained PDA together.

Beaver Fever: Whole-Genome Characterization of Waterborne Outbreak and Sporadic Isolates To Study the Zoonotic Transmission of Giardiasis.

PubMed

Tsui, Clement K-M; Miller, Ruth; Uyaguari-Diaz, Miguel; Tang, Patrick; Chauve, Cedric; Hsiao, William; Isaac-Renton, Judith; Prystajecky, Natalie

2018-04-25

Giardia causes the diarrheal disease known as giardiasis; transmission through contaminated surface water is common. The protozoan parasite's genetic diversity has major implications for human health and epidemiology. To determine the extent of transmission from wildlife through surface water, we performed whole-genome sequencing (WGS) to characterize 89 Giardia duodenalis isolates from both outbreak and sporadic infections: 29 isolates from raw surface water, 38 from humans, and 22 from veterinary sources. Using single nucleotide variants (SNVs), combined with epidemiological data, relationships contributing to zoonotic transmission were described. Two assemblages, A and B, were identified in surface water, human, and veterinary isolates. Mixes of zoonotic assemblages A and B were seen in all the community waterborne outbreaks in British Columbia (BC), Canada, studied. Assemblage A was further subdivided into assemblages A1 and A2 based on the genetic variation observed. The A1 assemblage was highly clonal; isolates of surface water, human, and veterinary origins from Canada, United States, and New Zealand clustered together with minor variation, consistent with this being a panglobal zoonotic lineage. In contrast, assemblage B isolates were variable and consisted of several clonal lineages relating to waterborne outbreaks and geographic locations. Most human infection isolates in waterborne outbreaks clustered with isolates from surface water and beavers implicated to be outbreak sources by public health. In-depth outbreak analysis demonstrated that beavers can act as amplification hosts for human infections and can act as sources of surface water contamination. It is also known that other wild and domesticated animals, as well as humans, can be sources of waterborne giardiasis. This study demonstrates the utility of WGS in furthering our understanding of Giardia transmission dynamics at the water-human-animal interface. IMPORTANCE Giardia duodenalis causes large numbers of gastrointestinal illness in humans. Its transmission through the contaminated surface water/wildlife intersect is significant, and the water-dwelling rodents beavers have been implicated as one important reservoir. To trace human infections to their source, we used genome techniques to characterize genetic relationships among 89 Giardia isolates from surface water, humans, and animals. Our study showed the presence of two previously described genetic assemblages, A and B, with mixed infections detected from isolates collected during outbreaks. Study findings also showed that while assemblage A could be divided into A1 and A2, A1 showed little genetic variation among animal and human hosts in isolates collected from across the globe. Assemblage B, the most common type found in the study surface water samples, was shown to be highly variable. Our study demonstrates that the beaver is a possible source of human infections from contaminated surface water, while acknowledging that theirs is only one role in the complex cycle of zoonotic spread. Mixes of parasite groups have been detected in waterborne outbreaks. More information on Giardia diversity and its evolution using genomics will further the understanding of the epidemiology of spread of this disease-causing protozoan. © Crown copyright 2018.

76 FR 14923 - Endangered and Threatened Species; Take of Anadromous Fish

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-18

... (i.e., surface and bottom water temperature, salinity, near bottom dissolved oxygen concentration...-water and bottom trawls) are adequately characterizing schools of hake. The IVC research would take...

Oxidation of MnO(100) and NaMnO2 formation: Characterization of Mn2+ and Mn3+ surfaces via XPS and water TPD

NASA Astrophysics Data System (ADS)

Feng, Xu; Cox, David F.

2018-09-01

The oxidation of clean and Na precovered MnO(100) has been investigated by X-ray photoelectron spectroscopy (XPS), low energy electron diffraction (LEED) and temperature programmed desorption (TPD) of adsorbed water. XPS results indicate that Mn3O4-like and Mn2O3-like surfaces can be formed by various oxidation treatments of clean and nearly-stoichiometric MnO(100), while a NaMnO2-like surface can be produced by the oxidation of MnO(100) pre-covered with multilayers of metallic Na. Water TPD results indicate that water adsorption/desorption is sensitive to the available oxidation states of surface Mn cations, and can be used to distinguish between surfaces exposing Mn2+and Mn3+ cations, or a combination of these oxidation states. Carbon dioxide and water TPD results from the NaMnO2-like surface indicate that pre-adsorbed water blocks the uptake of CO2, while water displaces pre-adsorbed CO2. No indication of a strong reactive interaction is observed between CO2, water and the NaMnO2-like surface under the conditions of our study.

Resolving the Structure of a Well-Ordered Hydroxyl Overlayer on In 2O 3 (111): Nanomanipulation and Theory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wagner, Margareta; Lackner, Peter; Seiler, Steffen

Changes in chemical and physical properties resulting from water adsorption play an important role in the characterization and performance of device-relevant materials. Studies of model oxides with well-characterized surfaces can provide detailed information that is vital for a general understanding of water–oxide interactions. In this work, we study single crystals of indium oxide, the prototypical transparent contact material that is heavily used in a wide range of applications and most prominently in optoelectronic technologies. Water adsorbs dissociatively already at temperatures as low as 100 K, as confirmed by scanning tunneling microscopy (STM), photoelectron spectroscopy, and density functional theory. This dissociationmore » takes place on lattice sites of the defect-free surface. While the In 2O 3(111)-(1 × 1) surface offers four types of surface oxygen atoms (12 atoms per unit cell in total), water dissociation happens exclusively at one of them together with a neighboring pair of 5-fold coordinated In atoms. These O–In groups are symmetrically arranged around the 6-fold coordinated In atoms at the surface. At room temperature, the In 2O 3(111) surface thus saturates at three dissociated water molecules per unit cell, leading to a well-ordered hydroxylated surface with (1 × 1) symmetry, where the three water OWH groups plus the surface OSH groups are imaged together as one bright triangle in STM. Manipulations with the STM tip by means of voltage pulses preferentially remove the H atom of one surface OSH group per triangle. The change in contrast due to strong local band bending provides insights into the internal structure of these bright triangles. The experimental results are further confirmed by quantitative simulations of the STM image corrugation.« less

Resolving the Structure of a Well-Ordered Hydroxyl Overlayer on In 2O 3 (111): Nanomanipulation and Theory

DOE PAGES

Wagner, Margareta; Lackner, Peter; Seiler, Steffen; ...

2017-11-01

Changes in chemical and physical properties resulting from water adsorption play an important role in the characterization and performance of device-relevant materials. Studies of model oxides with well-characterized surfaces can provide detailed information that is vital for a general understanding of water–oxide interactions. In this work, we study single crystals of indium oxide, the prototypical transparent contact material that is heavily used in a wide range of applications and most prominently in optoelectronic technologies. Water adsorbs dissociatively already at temperatures as low as 100 K, as confirmed by scanning tunneling microscopy (STM), photoelectron spectroscopy, and density functional theory. This dissociationmore » takes place on lattice sites of the defect-free surface. While the In 2O 3(111)-(1 × 1) surface offers four types of surface oxygen atoms (12 atoms per unit cell in total), water dissociation happens exclusively at one of them together with a neighboring pair of 5-fold coordinated In atoms. These O–In groups are symmetrically arranged around the 6-fold coordinated In atoms at the surface. At room temperature, the In 2O 3(111) surface thus saturates at three dissociated water molecules per unit cell, leading to a well-ordered hydroxylated surface with (1 × 1) symmetry, where the three water OWH groups plus the surface OSH groups are imaged together as one bright triangle in STM. Manipulations with the STM tip by means of voltage pulses preferentially remove the H atom of one surface OSH group per triangle. The change in contrast due to strong local band bending provides insights into the internal structure of these bright triangles. The experimental results are further confirmed by quantitative simulations of the STM image corrugation.« less

Wetlands inform how climate extremes influence surface water expansion and contraction

NASA Astrophysics Data System (ADS)

Vanderhoof, Melanie K.; Lane, Charles R.; McManus, Michael G.; Alexander, Laurie C.; Christensen, Jay R.

2018-03-01

Effective monitoring and prediction of flood and drought events requires an improved understanding of how and why surface water expansion and contraction in response to climate varies across space. This paper sought to (1) quantify how interannual patterns of surface water expansion and contraction vary spatially across the Prairie Pothole Region (PPR) and adjacent Northern Prairie (NP) in the United States, and (2) explore how landscape characteristics influence the relationship between climate inputs and surface water dynamics. Due to differences in glacial history, the PPR and NP show distinct patterns in regards to drainage development and wetland density, together providing a diversity of conditions to examine surface water dynamics. We used Landsat imagery to characterize variability in surface water extent across 11 Landsat path/rows representing the PPR and NP (images spanned 1985-2015). The PPR not only experienced a 2.6-fold greater surface water extent under median conditions relative to the NP, but also showed a 3.4-fold greater change in surface water extent between drought and deluge conditions. The relationship between surface water extent and accumulated water availability (precipitation minus potential evapotranspiration) was quantified per watershed and statistically related to variables representing hydrology-related landscape characteristics (e.g., infiltration capacity, surface storage capacity, stream density). To investigate the influence stream connectivity has on the rate at which surface water leaves a given location, we modeled stream-connected and stream-disconnected surface water separately. Stream-connected surface water showed a greater expansion with wetter climatic conditions in landscapes with greater total wetland area, but lower total wetland density. Disconnected surface water showed a greater expansion with wetter climatic conditions in landscapes with higher wetland density, lower infiltration and less anthropogenic drainage. From these findings, we can expect that shifts in precipitation and evaporative demand will have uneven effects on surface water quantity. Accurate predictions regarding the effect of climate change on surface water quantity will require consideration of hydrology-related landscape characteristics including wetland storage and arrangement.

Flow characterization in the Santee Cave system in the Chapel Branch Creek watershed, upper coastal plain of South Carolina, USA

Treesearch

Amy E. Edwards; Devendra M. Amatya; Thomas M. Williams; Daniel R. Hitchcock; April L. James

2013-01-01

Karst watersheds possess both diffuse and conduit flow and varying degrees of connectivity between surface and groundwater over spatial scales that result in complex hydrology and contaminant transport processes. The flow regime and surface-groundwater connection must be properly identified and characterized to improve management in karst watersheds with impaired water...

Field and laboratory determination of water-surface elevation and velocity using noncontact measurements

USGS Publications Warehouse

Nelson, Jonathan M.; Kinzel, Paul J.; Schmeeckle, Mark Walter; McDonald, Richard R.; Minear, Justin T.

2016-01-01

Noncontact methods for measuring water-surface elevation and velocity in laboratory flumes and rivers are presented with examples. Water-surface elevations are measured using an array of acoustic transducers in the laboratory and using laser scanning in field situations. Water-surface velocities are based on using particle image velocimetry or other machine vision techniques on infrared video of the water surface. Using spatial and temporal averaging, results from these methods provide information that can be used to develop estimates of discharge for flows over known bathymetry. Making such estimates requires relating water-surface velocities to vertically averaged velocities; the methods here use standard relations. To examine where these relations break down, laboratory data for flows over simple bumps of three amplitudes are evaluated. As anticipated, discharges determined from surface information can have large errors where nonhydrostatic effects are large. In addition to investigating and characterizing this potential error in estimating discharge, a simple method for correction of the issue is presented. With a simple correction based on bed gradient along the flow direction, remotely sensed estimates of discharge appear to be viable.

Application of Diffuse Reflectance FT-IR Spectroscopy for the Surface Study of Kevlar Fibers

NASA Astrophysics Data System (ADS)

Chatzi, E. G.; Ishida, H.; Koenig, J. L.

1985-12-01

The surfaces of Kevlar-49 aramid fibers, being used in high-performance composite materials, have been characterized by diffuse reflectance Fourier transform infrared (FT-IR) spectroscopy. Enhancement of the surface selectivity of the technique has been achieved using KBr overlayers. The water absorbed by both the skin and the core of the fibers has been characterized by using this technique and the accessibility of the fiber functional groups has been evaluated.

Phenotypic and Genotypic Characteristics of Shiga Toxin-Producing Escherichia coli Isolated from Surface Waters and Sediments in a Canadian Urban-Agricultural Landscape.

PubMed

Nadya, Stephanie; Delaquis, Pascal; Chen, Jessica; Allen, Kevin; Johnson, Roger P; Ziebell, Kim; Laing, Chad; Gannon, Victor; Bach, Susan; Topp, Edward

2016-01-01

A hydrophobic grid membrane filtration-Shiga toxin immunoblot method was used to examine the prevalence of Shiga toxin-producing Escherichia coli (STEC) in four watersheds located in the Lower Mainland of British Columbia, Canada, a region characterized by rapid urbanization and intensive agricultural activity. STEC were recovered from 21.6, 23.2, 19.5, and 9.2% of surface water samples collected monthly from five sites in each watershed over a period of 1 year. Overall prevalence was subject to seasonal variation however, ranging between 13.3% during fall months and 34.3% during winter months. STEC were also recovered from 23.8% of sediment samples collected in one randomly selected site. One hundred distinct STEC isolates distributed among 29 definitive and 4 ambiguous or indeterminate serotypes were recovered from water and sediments, including isolates from Canadian "priority" serogroups O157 (3), O26 (4), O103 (5), and O111 (7). Forty seven isolates were further characterized by analysis of whole genome sequences to detect Shiga toxin gene (stx 1 and stx 2), intimin gene (eaeA) allelic variants and acquired virulence factors. These analyses collectively showed that surface waters from the region support highly diverse STEC populations that include strains with virulence factors commonly associated with human pathotypes. The present work served to characterize the microbiological hazard implied by STEC to support future assessments of risks to public health arising from non-agricultural and agricultural uses of surface water resources in the region.

Fabrication of TiO2/EP super-hydrophobic thin film on filter paper surface.

PubMed

Gao, Zhengxin; Zhai, Xianglin; Liu, Feng; Zhang, Ming; Zang, Deli; Wang, Chengyu

2015-09-05

A composite filter paper with super-hydrophobicity was obtained by adhering micro/nano structure of amorphous titanium dioxide on the filter paper surface with modifying low surface energy material. By virtue of the coupling agent, which plays an important part in bonding amorphous titanium dioxide and epoxy resin, the structure of super-hydrophobic thin film on the filter paper surface is extremely stable. The microstructure of super-hydrophobic filter paper was characterized by scanning electron microscopy (SEM), the images showed that the as-prepared filter paper was covered with uniform amorphous titanium dioxide particles, generating a roughness structure on the filter paper surface. The super-hydrophobic performance of the filter paper was characterized by water contact angle measurements. The observations showed that the wettability of filter paper samples transformed from super-hydrophilicity to super-hydrophobicity with the water contact angle of 153 ± 1°. Some experiments were also designed to test the effect of water-oil separation and UV-resistant by the super-hydrophobic filter paper. The prepared super-hydrophobic filter paper worked efficiently and simply in water-oil separation as well as enduringly in anti-UV property after the experiments. This method offers an opportunity to the practical applications of the super-hydrophobic filter paper. Copyright © 2015 Elsevier Ltd. All rights reserved.

Uranium in US surface, ground, and domestic waters. Volume 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Drury, J.S.; Reynolds, S.; Owen, P.T.

1981-04-01

The report Uranium in US Surface, Ground, and Domestic Waters comprises four volumes. Volumes 2, 3, and 4 contain data characterizing the location, sampling date, type, use, and uranium conentrations of 89,994 individual samples presented in tabular form. The tabular data in volumes 2, 3, and 4 are summarized in volume 1 in narrative form and with maps and histograms.

Simple treatment of cotton textile to impart high water repellent properties

NASA Astrophysics Data System (ADS)

Ivanova, N. A.; Zaretskaya, A. K.

2010-12-01

We describe two methods to impart the water repellency for the surface of cotton fabric, using a commercially available and a laboratory synthesized fluoroalkylsiloxanes. To characterize the wettability and the durability of water repellent properties of hydrophobic coating produced, we have studied the advancing water contact angles, rolling angles and the evolution of water contact angle in time during a continuous contact of the surface with the water drop. The quality of the coatings was also assessed after the washing procedure. The analysis of the wettability of hydrophobized fabrics indicated that a better effect, leading to the superhydrophobic state of the surface, was observed when the surface relief of the fabric with the coating is determined by not only the structure and braiding of the fabric, but also the additional elements of texture created by the aggregates of molecules of hydrophobic agent.

Characterization of the Martian surface deposits by the Mars Pathfinder rover, Sojourner.

NASA Astrophysics Data System (ADS)

Matijevic, J. R.; Crisp, J.; Bickler, D. B.; Banes, R. S.; Cooper, B. K.; Eisen, H. J.; Gensler, J.; Haldemann, A.; Hartman, F.; Jewett, K. A.; Matthies, L. H.; Laubach, S. L.; Mishkin, A. H.; Morrison, J. C.; Nguyen, T. T.; Sirota, A. R.; Stone, H. W.; Stride, S.; Sword, L. F.; Tarsala, J. A.; Thompson, A. D.; Wallace, M. T.; Welch, R.; Wellman, E.; Wilcox, B. H.; Ferguson, D.; Jenkins, P.; Kolecki, J.; Landis, G. A.; Wilt, D.; Rover Team

1997-12-01

The Mars Pathfinder rover discovered pebbles on the surface and in rocks that may be sedimentary - not volcanic - in origin. Surface pebbles may have been rounded by Ares flood waters or liberated by weathering of sedimentary rocks called conglomerates. Conglomerates imply that water existed elsewhere and earlier than the Ares flood. Most soil-like deposits are similar to moderately dense soils on Earth. Small amounts of dust are currently settling from the atmosphere.

Quantitatively identifying the roles of interfacial water and solid surface in governing peptide adsorption.

PubMed

Xu, Zhijun; Yang, Xiao; Wei, Qichao; Zhao, Weilong; Cui, Beiliang; Yang, Xiaoning; Sahai, Nita

2018-06-11

Understanding the molecular mechanism of protein adsorption on solids is critical to their applications in materials synthesis and tissue engineering. Though the water phase at the surface/water interface has been recognized as three types: free water in the bulk region, intermediate water phase and surface-bound water layers adjacent to the surface, the roles of the water and surface in determining the protein adsorption are not clearly identified, particularly at the quantitative level. Herein, we provide a methodology involving the combination of microsecond strengthen sampling simulation and force integration to quantitatively characterize the water-induced contribution and the peptide-surface interactions into the adsorption free energy. Using hydroxyapatite and graphene surfaces as examples, we demonstrate how the distinct interfacial features dominate the delicate force balance between these two thermodynamics parameters, leading to surface preference/resistance to peptide adsorption. Specifically, the water layer provides sustained repelling force against peptide adsorption, as indicated by a monotonic increase in the water-induced free energy profile, whereas the contribution to the free energy from the surface effect is thermodynamically favorable, thus acting as the dominant driving force for peptide adsorptions. More importantly, the revealed adsorption mechanism is critically dictated by the distribution of water phase at the solid/water interface, which plays a crucial role in establishing the force balance between the interactions of the peptide with the water layer and the surface. For the HAP surface, the charged peptide exhibits strong binding affinity to the surface, which is ascribed to the controlling contribution of peptide-surface interaction in the intermediate water phase and the surface-bound water layers are observed as the origin of bioresistance of solid surfaces towards the adsorption of charge-neutral peptides. The preferred peptide adsorption on the graphene, however, is dominated by the surface-induced component at the water layers adjacent to the surface. Our results further elucidate that the intermediate water phase significantly shortens the effective range of the surface dispersion force to guide the diffusion of the peptide to the interface, in sharp contrast to the observation in interfacial systems involving the strong water-surface interaction.

Variation of Water Quality Parameters with Siltation Depth for River Ichamati Along International Border with Bangladesh Using Multivariate Statistical Techniques

NASA Astrophysics Data System (ADS)

Roy, P. K.; Pal, S.; Banerjee, G.; Biswas Roy, M.; Ray, D.; Majumder, A.

2014-12-01

River is considered as one of the main sources of freshwater all over the world. Hence analysis and maintenance of this water resource is globally considered a matter of major concern. This paper deals with the assessment of surface water quality of the Ichamati river using multivariate statistical techniques. Eight distinct surface water quality observation stations were located and samples were collected. For the samples collected statistical techniques were applied to the physico-chemical parameters and depth of siltation. In this paper cluster analysis is done to determine the relations between surface water quality and siltation depth of river Ichamati. Multiple regressions and mathematical equation modeling have been done to characterize surface water quality of Ichamati river on the basis of physico-chemical parameters. It was found that surface water quality of the downstream river was different from the water quality of the upstream. The analysis of the water quality parameters of the Ichamati river clearly indicate high pollution load on the river water which can be accounted to agricultural discharge, tidal effect and soil erosion. The results further reveal that with the increase in depth of siltation, water quality degraded.

Microbial Community Profile of a Lead Service Line Removed from a Drinking Water Distribution System

EPA Science Inventory

A corroded lead water pipe was removed from a drinking water distribution system and the microbial community was profiled using 16S rDNA techniques. This is the first report of the characterization of biofilm on a surface of a corroded lead drinking water pipe. The majority of ...

CHARACTERIZATION OF ENDEMIC DISEASE: HEALTH EFFECTS ASSOCIATED WITH DIFFERENCES IN SOURCE WATER QUALITY AND TREATMENT

EPA Science Inventory

A study in Canada by Payment et al. found that up to 35% of gastrointestinal illness in a community served by surface water was associated with drinking water that met current drinking water standards. A similar follow-up study by the same investigators tended to repeat the resul...

Surface characterization of gallium nitride modified with peptides before and after exposure to ionizing radiation in solution.

PubMed

Berg, Nora G; Nolan, Michael W; Paskova, Tania; Ivanisevic, Albena

2014-12-30

An aqueous surface modification of gallium nitride was employed to attach biomolecules to the surface. The modification was a simple two-step process using a single linker molecule and mild temperatures. The presence of the peptide on the surface was confirmed with X-ray photoelectron spectroscopy. Subsequently, the samples were placed in water baths and exposed to ionizing radiation to examine the effects of the radiation on the material in an environment similar to the body. Surface analysis confirmed degradation of the surface of GaN after radiation exposure in water; however, the peptide molecules successfully remained on the surface following exposure to ionizing radiation. We hypothesize that during radiation exposure of the samples, the radiolysis of water produces peroxide and other reactive species on the sample surface. Peroxide exposure promotes the formation of a more stable layer of gallium oxyhydroxide which passivates the surface better than other oxide species.

Quality characterization and pollution source identification of surface water using multivariate statistical techniques, Nalagarh Valley, Himachal Pradesh, India

NASA Astrophysics Data System (ADS)

Herojeet, Rajkumar; Rishi, Madhuri S.; Lata, Renu; Dolma, Konchok

2017-09-01

Sirsa River flows through the central part of the Nalagarh valley, belongs to the rapid industrial belt of Baddi, Barotiwala and Nalagarh (BBN). The appraisal of surface water quality to ascertain its utility in such ecologically sensitive areas is need of the hour. The present study envisages the application of multivariate analysis, water utility class and conventional graphical representation to reveal the hidden factor responsible for deterioration of water quality and determine the hydrochemical facies and its evolution processes of water types in Nalagarh valley, India. The quality assessment is made by estimating pH, electrical conductivity (EC), total dissolved solids (TDS), total hardness, major ions (Na+, K+, Ca2+, Mg2+, HCO3 -, Cl-, SO4 2-, NO3 - and PO4 3-), dissolved oxygen (DO), biological oxygen demand (BOD) and total coliform (TC) to determine its suitability for drinking and domestic purposes. The parameters like pH, TDS, TH, Ca2+, HCO3 -, Cl-, SO4 2-, NO3 - are within the desirable limit as per Bureau of Indian Standards (Indian Standard Drinking Water Specification (Second Edition) IS:10500. Indian Standard Institute, New Delhi, pp 1-18, 2012). Mg2+, Na+ and K+ ions for pre monsoon and EC during pre and post monsoon at few sites and approx 40% samples of BOD and TC for both seasons exceeds the permissible limits indicate organic contamination from human activities. Water quality classification for designated use indicates that maximum surface water samples are not suitable for drinking water source without conventional treatment. The result of piper trillinear and Chadha's diagram classified majority of surface water samples for both seasons fall in the fields of Ca2+-Mg2+-HCO3 - water type indicating temporary hardness. PCA and CA reveal that the surface water chemistry is influenced by natural factors such as weathering of minerals, ion exchange processes and anthropogenic factors. Thus, the present paper illustrates the importance of multivariate techniques for reliable quality characterization of surface water quality to develop effective pollution reduction strategies and maintain a fine balance between the industrialization and ecological integrity.

Characterization of the Cell Surface Properties of Drinking Water Pathogens by Microbial Adhesion to Hydrocarbon and Electrophoretic Mobility Measurements

EPA Science Inventory

The surface characteristics of microbial cells directly influence their mobility and behavior within aqueous environments. The cell surface hydrophobicity (CSH) and electrophoretic mobility (EPM) of microbial cells impact a number of interactions and processes including aggregati...

Water-quality effects and characterization of indicators of onsite wastewater disposal systems in the east-central Black Hills area, South Dakota, 2006-08

USGS Publications Warehouse

Putnam, Larry D.; Hoogestraat, Galen K.; Sawyer, J. Foster

2008-01-01

Onsite wastewater disposal systems (OWDS) are used extensively in the Black Hills of South Dakota where many of the watersheds and aquifers are characterized by fractured or solution-enhanced bedrock with thin soil cover. A study was conducted during 2006-08 to characterize water-quality effects and indicators of OWDS. Water samples were collected and analyzed for potential indicators of OWDS, including chloride, bromide, boron, nitrite plus nitrate (NO2+NO3), ammonia, major ions, nutrients, selected trace elements, isotopes of nitrate, microbiological indicators, and organic wastewater compounds (OWCs). The microbiological indicators were fecal coliforms, Escherichia coli (E. coli), enterococci, Clostridium perfringens (C. perfringens), and coliphages. Sixty ground-water sampling sites were located either downgradient from areas of dense OWDS or in background areas and included 25 monitoring wells, 34 private wells, and 1 spring. Nine surface-water sampling sites were located on selected streams and tributaries either downstream or upstream from residential development within the Precambrian setting. Sampling results were grouped by their hydrogeologic setting: alluvial, Spearfish, Minnekahta, and Precambrian. Mean downgradient dissolved NO2+NO3 concentrations in ground water for the alluvial, Spearfish, Minnekahta, and Precambrian settings were 0.734, 7.90, 8.62, and 2.25 milligrams per liter (mg/L), respectively. Mean downgradient dissolved chloride concentrations in ground water for these settings were 324, 89.6, 498, and 33.2 mg/L, respectively. Mean downgradient dissolved boron concentrations in ground water for these settings were 736, 53, 64, and 43 micrograms per liter (ug/L), respectively. Mean dissolved surface-water concentrations for NO2+NO3, chloride, and boron for downstream sites were 0.222 mg/L, 32.1 mg/L, and 28 ug/L, respectively. Mean values of delta-15N and delta-18O (isotope ratios of 14N to 15N and 18O to 16O relative to standard ratios) for nitrate in ground-water samples were 10.4 and -2.0 per mil (0/100), respectively, indicating a relatively small contribution from synthetic fertilizer and probably a substantial contribution from OWDS. The surface-water sample with the highest dissolved NO2+NO3 concentration of 1.6 mg/L had a delta-15N value of 12.36 0/100, which indicates warm-blooded animals (including humans) as the nitrate source. Fecal coliforms were detected in downgradient ground water most frequently in the Spearfish (19 percent) and Minnekahta (9.7 percent) settings. E. coli was detected most frequently in the Minnekahta (29 percent) and Spearfish (13 percent) settings. Enterococci were detected more frequently than other microbiological indicators in all four settings. Fecal coliforms and E. coli were detected in 73 percent and 95 percent of all surface-water samples, respectively. Enterococci, coliphages (somatic), and C. perfringens were detected in 50, 70, and 50 percent of surface-water samples, respectively. Of the 62 OWC analytes, 12 were detected only in environmental samples, 10 were detected in at least one environmental and one blank sample (not necessarily companion pairs), 2 were detected only in blank samples, and 38 were not detected in any blank, environmental, or replicate sample from either ground or surface water. Eleven different organic compounds were detected in ground-water samples at eight different sites. The most frequently occurring compound was DEET, which was found in 32 percent of the environmental samples, followed by tetrachloroethene, which was detected in 20 percent of the samples. For surface-water samples, 16 organic compounds were detected in 9 of the 10 total samples. The compound with the highest occurrence in surface-water samples was camphor, which was detected in 50 percent of samples. The alluvial setting was characterized by relatively low dissolved NO2+NO3 concentrations, detection of ammonia nitrogen, and relatively high concentr

Subsurface water and clay mineral formation during the early history of Mars.

PubMed

Ehlmann, Bethany L; Mustard, John F; Murchie, Scott L; Bibring, Jean-Pierre; Meunier, Alain; Fraeman, Abigail A; Langevin, Yves

2011-11-02

Clay minerals, recently discovered to be widespread in Mars's Noachian terrains, indicate long-duration interaction between water and rock over 3.7 billion years ago. Analysis of how they formed should indicate what environmental conditions prevailed on early Mars. If clays formed near the surface by weathering, as is common on Earth, their presence would indicate past surface conditions warmer and wetter than at present. However, available data instead indicate substantial Martian clay formation by hydrothermal groundwater circulation and a Noachian rock record dominated by evidence of subsurface waters. Cold, arid conditions with only transient surface water may have characterized Mars's surface for over 4 billion years, since the early-Noachian period, and the longest-duration aqueous, potentially habitable environments may have been in the subsurface.

The stable isotopes of site wide waters at an oil sands mine in northern Alberta, Canada

NASA Astrophysics Data System (ADS)

Baer, Thomas; Barbour, S. Lee; Gibson, John J.

2016-10-01

Oil sands mines have large disturbance footprints and contain a range of new landforms constructed from mine waste such as shale overburden and the byproducts of bitumen extraction such as sand and fluid fine tailings. Each of these landforms are a potential source of water and chemical release to adjacent surface and groundwater, and consequently, the development of methods to track water migration through these landforms is of importance. The stable isotopes of water (i.e. 2H and 18O) have been widely used in hydrology and hydrogeology to characterize surface water/groundwater interactions but have not been extensively applied in mining applications, or specifically to oil sands mining in northern Alberta. A prerequisite for applying these techniques is the establishment of a Local Meteoric Water Line (LMWL) to characterize precipitation at the mine sites as well as the development of a 'catalogue' of the stable water isotope signatures of various mine site waters. This study was undertaken at the Mildred Lake Mine Site, owned and operated by Syncrude Canada Ltd. The LMWL developed from 2 years (2009/2012) of sample collection is shown to be consistent with other LMWLs in western Canada. The results of the study highlight the unique stable water isotope signatures associated with hydraulically placed tailings (sand or fluid fine tailings) and overburden shale dumps relative to natural surface water and groundwater. The signature associated with the snow melt water on reclaimed landscapes was found to be similar to ground water recharge in the region. The isotopic composition of the shale overburden deposits are also distinct and consistent with observations made by other researchers in western Canada on undisturbed shales. The process water associated with the fine and coarse tailings streams has highly enriched 2H and 18O signatures. These signatures are developed through the non-equilibrium fractionation of imported fresh river water during evaporation from cooling towers used within the raw water process circuit. This highly fractionated surface water eventually becomes part of the recycled tailings water circuit, and as a consequence it undergoes further non-equilibrium fractionation as a result of surface evaporation, leading to additional enrichment along local evaporation lines.

Paraho environmental data. Part I. Process characterization. Par II. Air quality. Part III. Water quality

DOE Office of Scientific and Technical Information (OSTI.GOV)

Heistand, R.N.; Atwood, R.A.; Richardson, K.L.

1980-06-01

From 1973 to 1978, Development Engineering, Inc. (DEI), a subsidiary of Paraho Development Corporation, demostrated the Paraho technology for surface oil shale retorting at Anvil Points, Colorado. A considerable amount of environmentally-related research was also conducted. This body of data represents the most comprehensive environmental data base relating to surface retorting that is currently available. In order to make this information available, the DOE Office of Environment has undertaken to compile, assemble, and publish this environmental data. The compilation has been prepared by DEI. This report includes the process characterization, air quality, and water quality categories.

A semiempirical model for interpreting microwave emission from semiarid land surfaces as seen from space

NASA Technical Reports Server (NTRS)

Kerr, Yann H.; Njoku, Eni G.

1990-01-01

A radiative-transfer model for simulating microwave brightness temperatures over land surfaces is described. The model takes into account sensor viewing conditions (spacecraft altitude, viewing angle, frequency, and polarization) and atmospheric parameters over a soil surface characterized by its moisture, roughness, and temperature and covered with a layer of vegetation characterized by its temperature, water content, single scattering albedo, structure, and percent coverage. In order to reduce the influence of atmospheric and surface temperature effects, the brightness temperatures are expressed as polarization ratios that depend primarily on the soil moisture and roughness, canopy water content, and percentage of cover. The sensitivity of the polarization ratio to these parameters is investigated. Simulation of the temporal evolution of the microwave signal over semiarid areas in the African Sahel is presented and compared to actual satellite data from the SMMR instrument on Nimbus-7.

Characterization of the Deep Water Surface Wave Variability in the California Current Region

NASA Astrophysics Data System (ADS)

Villas Bôas, Ana B.; Gille, Sarah T.; Mazloff, Matthew R.; Cornuelle, Bruce D.

2017-11-01

Surface waves are crucial for the dynamics of the upper ocean not only because they mediate exchanges of momentum, heat, energy, and gases between the ocean and the atmosphere, but also because they determine the sea state. The surface wave field in a given region is set by the combination of local and remote forcing. The present work characterizes the seasonal variability of the deep water surface wave field in the California Current region, as retrieved from over two decades of satellite altimetry data combined with wave buoys and wave model hindcast (WaveWatch III). In particular, the extent to which the local wind modulates the variability of the significant wave height, peak period, and peak direction is assessed. During spring/summer, regional-scale wind events of up to 10 m/s are the dominant forcing for waves off the California coast, leading to relatively short-period waves (8-10 s) that come predominantly from the north-northwest. The wave climatology throughout the California Current region shows average significant wave heights exceeding 2 m during most of the year, which may have implications for the planning and retrieval methods of the Surface Water and Ocean Topography (SWOT) satellite mission.

Corrosion protection of reusable surgical instruments.

PubMed

Shah, Sadiq; Bernardo, Mildred

2002-01-01

To understand the corrosion properties of surgical scissors, 416 stainless steel disks and custom electrodes were used as simulated surfaces under various conditions. These simulated surfaces were exposed to tap water and 400-ppm synthetic hard water as Ca2CO3 under different conditions. The samples were evaluated by various techniques for corrosion potential and the impact of environmental conditions on the integrity of the passive film. The electrodes were used to monitor the corrosion behavior by potentiodynamic polarization technique in water both in the presence and absence of a cleaning product. The surface topography of the 416 stainless steel disks was characterized by visual observations and scanning electron microscopy (SEM), and the surface chemistry of the passive film on the surface of the scissors was characterized by x-ray photoelectron spectroscopy (XPS). The results suggest that surgical instruments made from 416 stainless steel are not susceptible to uniform corrosion; however, they do undergo localized corrosion. The use of suitable cleaning products can offer protection against localized corrosion during the cleaning step. More importantly, the use of potentiodynamic polarization techniques allowed for a quick and convenient approach to evaluate the corrosion properties of surgical instruments under a variety of simulated-use environmental conditions.

Characterization of hydrology and water quality of Piceance Creek in the Alkali Flat area, Rio Blanco County, Colorado, March 2012

USGS Publications Warehouse

Thomas, Judith C.

2015-12-07

Water-quality samples were collected at five surface-water sites in December 2010 that were sampled as part of a previous USGS study in 2000. Water-quality data collected during December 2010 showed no appreciable difference from water-quality data collected during December 2000 at the five sites.

Adsorption and Wetting in Model Mesoporous Silicas and in Complex Metal Oxide Catalysts

NASA Astrophysics Data System (ADS)

Jayaraman, Karthik

The surface of most metal oxides is covered by hydroxyl groups which influence many surface phenomena such as adsorption and wetting, catalysis and surface reactions. Surface chemistry of silica is a subject of exhaustive studies owing to a wide variety of practical applications of silica. In Chapter 1, a brief review of classification, synthesis and characterization of silica is provided. The hydroxylation of silica surface i.e the number of hydroxyl (-OH) groups on the surface is of utmost importance for its practical applications. In Chapter 2, a brief introduction to surface hydration of silica is provided followed by the gas adsorption measurements and characterization. Pore wetting is critical to many applications of mesoporous adsorbents, catalysts, and separation materials. In the work presented in Chapter 3, we employed the combined vapor adsorption study using nitrogen (77K) and water (293K) isotherms to evaluate the water contact angles for a series of ordered mesoporous silicas (ex:SBA-15). The proposed method of contact angle relies on the statistical film thickness (t-curve) of the adsorbed water. There were no t-curves for water for dehydroxylated or hydrophobic surfaces in literature and we addressed this issue by measuring t-curves for a series of model surfaces with known and varying silanol coverage. Using the radius of menisci ((H2O)), statistical film thickness t(H2O) from water isotherm, and the true radius of pores (rp(N 2)), from nitrogen isotherms, the water contact angle inside pores were calculated. As it was anticipated, the results obtained showed that the silica pore contact angles were strongly influenced by the number of the surface silanol groups and, therefore, by the thermal and hydration treatments of silicas. Phthalocyanines (Pcs) present an interesting class of catalytically active of molecules with unique spectroscopic, photoelectric, and sometimes magnetic properties. In the work presented in Chapter 4, we have undertaken a systematic study to explore the possibility of preparing a supported catalyst material i.e loading fluorinated metal phthalocyanines onto metal oxide surfaces by two other techniques in addition to solution adsorption. Techniques or procedures that have been used to immobilize MPcs include: i) physical adsorption (from solution) onto metal oxide surface, ii) deposition by pore filling and encapsulation and iii) mesopore entrapment or confinement. The MPcs are loaded on to metal oxides with an aim to: a) maximize the surface area of the Pcs by distributing it over the support, b) immobilize the Pcs so that they do not leach into the solution environment, c) improve the thermal stability of the Pcs and d) attempt to achieve single-site catalysis. All the immobilization techniques were carried out with F64PcZn as the model MPc, acetone as the immobilization solvent and silica or alumina as adsorbents (solid support). An understanding of gas adsorption mechanisms on metal phthalocyanines (MPcs) is essential for their practical application in biological processes, gas sensing, and catalysis. In this work, the surface characteristics were probed by performing nitrogen and water adsorption on the free-form MPcs (without immobilization on solid support) and characterization of their physical properties. The combined vapor adsorption study (developed in Chapter 3) enabled in understanding the affinity of Pcs towards water vapor i.e number of water molecules adsorbed per phthalocyanine molecule was obtained. This information is very relevant towards using Pcs as catalyst since water vapor is guaranteed to be present in most of the catalytic reaction environment.

Dragonfly: Exploring Titan's Surface with a New Frontiers Relocatable Lander

NASA Astrophysics Data System (ADS)

Barnes, Jason W.; Turtle, Elizabeth P.; Trainer, Melissa G.; Lorenz, Ralph

2017-10-01

We proposed to the NASA New Frontiers 4 mission call a lander to assess Titan's prebiotic chemistry, evaluate its habitability, and search for biosignatures on its surface. Titan as an Ocean World is ideal for the study of prebiotic chemical processes and the habitability of an extraterrestrial environment due to its abundant complex carbon-rich chemistry and because both liquid water and liquid hydrocarbons can occur on its surface. Transient liquid water surface environments can be created by both impacts and cryovolcanic processes. In both cases, the water could mix with surface organics to form a primordial soup. The mission would sample both organic sediments and water ice to measure surface composition, achieving surface mobility by using rotors to take off, fly, and land at new sites. The Dragonfly rotorcraft lander can thus convey a single capable instrument suite to multiple locations providing the capability to explore diverse locations 10s to 100s of kilometers apart to characterize the habitability of Titan's environment, investigate how far prebiotic chemistry has progressed, and search for chemical signatures indicative of water- and/or hydrocarbon-based life.

PERCHLORATE ENVIRONMENTAL CONTAMINATION: TOXICOLOGICAL REVIEW AND RISK CHARACTERIZATION (EXTERNAL REVIEW DRAFT) 2002

EPA Science Inventory

Perchlorate (ClO4-) is an anion that originates as a contaminant in ground water and surface waters when the salts of ammonium, potassium, magnesium, or sodium dissolve in water. One major source of contamination is the manufacture or improper disposal of ammonium perchlorate th...

Validation of a new device to quantify groundwater-surface water exchange

NASA Astrophysics Data System (ADS)

Cremeans, Mackenzie M.; Devlin, J. F.

2017-11-01

Distributions of flow across the groundwater-surface water interface should be expected to be as complex as the geologic deposits associated with stream or lake beds and their underlying aquifers. In these environments, the conventional Darcy-based method of characterizing flow systems (near streams) has significant limitations, including reliance on parameters with high uncertainties (e.g., hydraulic conductivity), the common use of drilled wells in the case of streambank investigations, and potentially lengthy measurement times for aquifer characterization and water level measurements. Less logistically demanding tools for quantifying exchanges across streambeds have been developed and include drive-point mini-piezometers, seepage meters, and temperature profiling tools. This project adds to that toolbox by introducing the Streambed Point Velocity Probe (SBPVP), a reusable tool designed to quantify groundwater-surface water interactions (GWSWI) at the interface with high density sampling, which can effectively, rapidly, and accurately complement conventional methods. The SBPVP is a direct push device that measures in situ water velocities at the GWSWI with a small-scale tracer test on the probe surface. Tracer tests do not rely on hydraulic conductivity or gradient information, nor do they require long equilibration times. Laboratory testing indicated that the SBPVP has an average accuracy of ± 3% and an average precision of ± 2%. Preliminary field testing, conducted in the Grindsted Å in Jutland, Denmark, yielded promising agreement between groundwater fluxes determined by conventional methods and those estimated from the SBPVP tests executed at similar scales. These results suggest the SBPVP is a viable tool to quantify groundwater-surface water interactions in high definition in sandy streambeds.

Removal of estrogens through water disinfection processes and formation of by-products.

PubMed

Pereira, Renata Oliveira; Postigo, Cristina; de Alda, Miren López; Daniel, Luiz Antonio; Barceló, Damià

2011-02-01

Estrogens constitute a recognized group of environmental emerging contaminants which have been proven to induce estrogenic effects in aquatic organisms exposed to them. Low removal efficiency in wastewater treatment plants results in the presence of this type of contaminants in surface waters and also even in finished drinking water. This manuscript reviews the environmental occurrence of natural (estrone, estradiol and estriol) and synthetic (ethynyl estradiol) estrogens in different water matrices (waste, surface, ground and drinking water), and their removal mainly via chemical oxidative processes. Oxidative treatments have been observed to be very efficient in eliminating estrogens present in water; however, disinfection by-products (DBPs) are generated during the process. Characterization of these DBPs is essential to assess the risk that drinking water may potentially pose to human health since these DBPs may also have endocrine disrupting properties. This manuscript reviews the DBPs generated during oxidative processes identified so far in the literature and the estrogenicity generated by the characterized DBPs and/or by the applied disinfection technology. Copyright © 2010 Elsevier Ltd. All rights reserved.

Bacterial community diversity and variation in spray water sources and the tomato fruit surface.

PubMed

Telias, Adriana; White, James R; Pahl, Donna M; Ottesen, Andrea R; Walsh, Christopher S

2011-04-21

Tomato (Solanum lycopersicum) consumption has been one of the most common causes of produce-associated salmonellosis in the United States. Contamination may originate from animal waste, insects, soil or water. Current guidelines for fresh tomato production recommend the use of potable water for applications coming in direct contact with the fruit, but due to high demand, water from other sources is frequently used. We sought to describe the overall bacterial diversity on the surface of tomato fruit and the effect of two different water sources (ground and surface water) when used for direct crop applications by generating a 454-pyrosequencing 16S rRNA dataset of these different environments. This study represents the first in depth characterization of bacterial communities in the tomato fruit surface and the water sources commonly used in commercial vegetable production. The two water sources tested had a significantly different bacterial composition. Proteobacteria was predominant in groundwater samples, whereas in the significantly more diverse surface water, abundant phyla also included Firmicutes, Actinobacteria and Verrucomicrobia. The fruit surface bacterial communities on tomatoes sprayed with both water sources could not be differentiated using various statistical methods. Both fruit surface environments had a high representation of Gammaproteobacteria, and within this class the genera Pantoea and Enterobacter were the most abundant. Despite the major differences observed in the bacterial composition of ground and surface water, the season long use of these very different water sources did not have a significant impact on the bacterial composition of the tomato fruit surface. This study has provided the first next-generation sequencing database describing the bacterial communities living in the fruit surface of a tomato crop under two different spray water regimes, and therefore represents an important step forward towards the development of science-based metrics for Good Agricultural Practices.

Useful surface parameters for biomaterial discrimination.

PubMed

Etxeberria, Marina; Escuin, Tomas; Vinas, Miquel; Ascaso, Carlos

2015-01-01

Topographical features of biomaterials' surfaces are determinant when addressing their application site. Unfortunately up to date there has not been an agreement regarding which surface parameters are more representative in discriminating between materials. Discs (n = 16) of different currently used materials for implant prostheses fabrication, such as cast cobalt-chrome, direct laser metal soldered (DLMS) cobalt-chrome, titanium grade V, zirconia (Y-TZP), E-glass fiber-reinforced composite and polyetheretherketone (PEEK) were manufactured. Nanoscale topographical surface roughness parameters generated by atomic force microscopy (AFM), microscale surface roughness parameters obtained by white light interferometry (WLI) and water angle values obtained by the sessile-water-drop method were analyzed in order to assess which parameter provides the best optimum surface characterization method. Correlations between nanoroughness, microroughness, and hydrophobicity data were performed to achieve the best parameters giving the highest discriminatory power. A subset of six parameters for surface characterization were proposed. AFM and WLI techniques gave complementary information. Wettability did not correlate with any of the nanoroughness parameters while it however showed a weak correlation with microroughness parameters. © Wiley Periodicals, Inc.

Characterizing heterogeneous dynamics at hydrated electrode surfaces.

PubMed

Willard, Adam P; Limmer, David T; Madden, Paul A; Chandler, David

2013-05-14

In models of Pt 111 and Pt 100 surfaces in water, motions of molecules in the first hydration layer are spatially and temporally correlated. To interpret these collective motions, we apply quantitative measures of dynamic heterogeneity that are standard tools for considering glassy systems. Specifically, we carry out an analysis in terms of mobility fields and distributions of persistence times and exchange times. In so doing, we show that dynamics in these systems is facilitated by transient disorder in frustrated two-dimensional hydrogen bonding networks. The frustration is the result of unfavorable geometry imposed by strong metal-water bonding. The geometry depends upon the structure of the underlying metal surface. Dynamic heterogeneity of water on the Pt 111 surface is therefore qualitatively different than that for water on the Pt 100 surface. In both cases, statistics of this ad-layer dynamic heterogeneity responds asymmetrically to applied voltage.

Characterizing heterogeneous dynamics at hydrated electrode surfaces

NASA Astrophysics Data System (ADS)

Willard, Adam P.; Limmer, David T.; Madden, Paul A.; Chandler, David

2013-05-01

In models of Pt 111 and Pt 100 surfaces in water, motions of molecules in the first hydration layer are spatially and temporally correlated. To interpret these collective motions, we apply quantitative measures of dynamic heterogeneity that are standard tools for considering glassy systems. Specifically, we carry out an analysis in terms of mobility fields and distributions of persistence times and exchange times. In so doing, we show that dynamics in these systems is facilitated by transient disorder in frustrated two-dimensional hydrogen bonding networks. The frustration is the result of unfavorable geometry imposed by strong metal-water bonding. The geometry depends upon the structure of the underlying metal surface. Dynamic heterogeneity of water on the Pt 111 surface is therefore qualitatively different than that for water on the Pt 100 surface. In both cases, statistics of this ad-layer dynamic heterogeneity responds asymmetrically to applied voltage.

Characterization of photocatalytic TiO 2 powder under varied environments using near ambient pressure X-ray photoelectron spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Krishnan, Padmaja; Liu, Minghui; Itty, Pierre A.

Consecutive eight study phases under the successive presence and absence of UV irradiation, water vapor, and oxygen were conducted to characterize surface changes in the photocatalytic TiO2 powder using near-ambient-pressure X-ray photoelectron spectroscopy (XPS). Both Ti 2p and O 1s spectra show hysteresis through the experimental course. Under all the study environments, the bridging hydroxyl (OH br) and terminal hydroxyl (OH t) are identified at 1.1–1.3 eV and 2.1–2.3 eV above lattice oxygen, respectively. This enables novel and complementary approach to characterize reactivity of TiO 2 powder. The dynamic behavior of surface-bound water molecules under each study environment is identified,more » while maintaining a constant distance of 1.3 eV from the position of water vapor. In the dark, the continual supply of both water vapor and oxygen is the key factor retaining the activated state of the TiO 2 powder for a time period. Two new surface peaks at 1.7–1.8 and 4.0–4.2 eV above lattice oxygen are designated as peroxides (OOH/H 2O 2) and H 2O 2 dissolved in water, respectively. The persistent peroxides on the powder further explain previously observed prolonged oxidation capability of TiO 2 powder without light irradiation.« less

Characterization of photocatalytic TiO 2 powder under varied environments using near ambient pressure X-ray photoelectron spectroscopy

DOE PAGES

Krishnan, Padmaja; Liu, Minghui; Itty, Pierre A.; ...

2017-02-27

Consecutive eight study phases under the successive presence and absence of UV irradiation, water vapor, and oxygen were conducted to characterize surface changes in the photocatalytic TiO2 powder using near-ambient-pressure X-ray photoelectron spectroscopy (XPS). Both Ti 2p and O 1s spectra show hysteresis through the experimental course. Under all the study environments, the bridging hydroxyl (OH br) and terminal hydroxyl (OH t) are identified at 1.1–1.3 eV and 2.1–2.3 eV above lattice oxygen, respectively. This enables novel and complementary approach to characterize reactivity of TiO 2 powder. The dynamic behavior of surface-bound water molecules under each study environment is identified,more » while maintaining a constant distance of 1.3 eV from the position of water vapor. In the dark, the continual supply of both water vapor and oxygen is the key factor retaining the activated state of the TiO 2 powder for a time period. Two new surface peaks at 1.7–1.8 and 4.0–4.2 eV above lattice oxygen are designated as peroxides (OOH/H 2O 2) and H 2O 2 dissolved in water, respectively. The persistent peroxides on the powder further explain previously observed prolonged oxidation capability of TiO 2 powder without light irradiation.« less

CHARACTERIZATION OF ENDEMIC DISEASE: HEALTH EFFECTS ASSOCIATED WITH DIFFERENCES IN SOURCE WATER QUALITY AND TREATMENT PROCESS

EPA Science Inventory

A study in Canada by Payment et al. found that up to 35% of gastrointestinal illness in a community served by surface water was associated with drinking water that met current drinking water standards. A similar follow-up study by the same investigators tended to repeat the resul...

Characterization of protein hydration by solution NMR spectroscopy

NASA Astrophysics Data System (ADS)

Wand, Joshua

A comprehensive understanding of the interactions between protein molecules and hydration water remains elusive. Solution nuclear magnetic resonance (NMR) spectroscopy has been proposed as a means to characterize these interactions but is plagued with artifacts when employed in bulk aqueous solution. Encapsulation of proteins in reverse micelles prepared in short chain alkane solvents can overcome these technical limitations. Application of this approach has revealed that the interaction of water with the surface of protein molecules is quite heterogeneous with some regions of the protein having long-lived interactions while other regions show relatively transient hydration. Results from several proteins will be presented including ubiquitin, staphylococcal nuclease, interleukin 1beta, hen egg white lysozyme (HEWL) and T4 lysozyme. Ubiquitin and interleukin 1beta are signaling proteins and interact with other proteins through formation of dry protein-protein interfaces. Interestingly, the protein surfaces of the free proteins show relatively slowed (restricted) motion at the surface, which is indicative of low residual entropy. Other regions of the protein surface have relatively high mobility water. These results are consistent with the idea that proteins have evolved to maximize the hydrophobic effect in optimization of binding with protein partners. As predicted by simulation and theory, we find that hydration of internal hydrophobic cavities of interleukin 1beta and T4 lysozyme is highly disfavored. In contrast, the hydrophilic polar cavity of HEWL is occupied by water. Initial structural correlations suggest that hydration of alpha helical structure is characterized by relatively mobile water while those of beta strands and loops are more ordered and slowed. These and other results from this set of proteins reveals that the dynamical and structural character of hydration of proteins is heterogeneous and complex. Supported by the National Science Foundation.

Comparison of Nitronic 50 and Stainless Steel 316 for use in Supercritical Water Environments

NASA Astrophysics Data System (ADS)

Karmiol, Zachary

Increased efficiency can greatly benefit any mode of power production. Many proposed coal, natural gas, and nuclear reactors attempt to realize this goal through the use of increased operating temperatures and pressures, and as such require materials capable of withstanding extreme conditions. One such design employs supercritical water, which in addition to high temperatures and pressures is also highly oxidizing. A critical understanding of both mechanical and oxidation characteristics of candidate materials are required to determine the viability of materials for these reactors. This work investigates two potential materials, austenitic stainless steels, namely, Nitronic-50 and stainless steel 316, for use in these conditions. The supercritical water loop at the University of Nevada, Reno allowed for the study of materials at both subcritical and supercritical conditions. The materials were investigated mechanically using slow strain rate tests under conditions ranging from an inert nitrogen atmosphere, to both subcritical and supercritical water, with the failed samples surface characterized by optical microscopy, scanning electron microscopy, and Raman spectroscopy. Electrochemical studies were performed via potentiodynamic polarization in subcritical water only, and characterized using Raman spectroscopy. The samples were also exposed to supercritical water, and characterized using Raman spectroscopy. Nitronic-50 was found to have superior mechanical characteristics to stainless steel 316. SS-316 was found to have a surface film consisting of iron oxides, while the surface film of N-50 consisted predominantly of nickel-iron spinel. The crack interior of the sample was different from the exterior, indicating that the time and temperature of the exposure might play a defining role in determining the chemistry of the film.

Surface and Flow Field Measurements on the FAITH Hill Model

NASA Technical Reports Server (NTRS)

Bell, James H.; Heineck, James T.; Zilliac, Gregory; Mehta, Rabindra D.; Long, Kurtis R.

2012-01-01

A series of experimental tests, using both qualitative and quantitative techniques, were conducted to characterize both surface and off-surface flow characteristics of an axisymmetric, modified-cosine-shaped, wall-mounted hill named "FAITH" (Fundamental Aero Investigates The Hill). Two separate models were employed: a 6" high, 18" base diameter machined aluminum model that was used for wind tunnel tests and a smaller scale (2" high, 6" base diameter) sintered nylon version that was used in the water channel facility. Wind tunnel and water channel tests were conducted at mean test section speeds of 165 fps (Reynolds Number based on height = 500,000) and 0.1 fps (Reynolds Number of 1000), respectively. The ratio of model height to boundary later height was approximately 3 for both tests. Qualitative techniques that were employed to characterize the complex flow included surface oil flow visualization for the wind tunnel tests, and dye injection for the water channel tests. Quantitative techniques that were employed to characterize the flow included Cobra Probe to determine point-wise steady and unsteady 3D velocities, Particle Image Velocimetry (PIV) to determine 3D velocities and turbulence statistics along specified planes, Pressure Sensitive Paint (PSP) to determine mean surface pressures, and Fringe Imaging Skin Friction (FISF) to determine surface skin friction (magnitude and direction). This initial report summarizes the experimental set-up, techniques used, data acquired and describes some details of the dataset that is being constructed for use by other researchers, especially the CFD community. Subsequent reports will discuss the data and their interpretation in more detail

Hydrographic characterization of southeast Arabian Sea during the wane of southwest monsoon and spring intermonsoon.

PubMed

Vimal Kumar, K G; Dinesh Kumar, P K; Smitha, B R; Habeeb Rahman, H; Josia, Jacob; Muraleedharan, K R; Sanjeevan, V N; Achuthankutty, C T

2008-05-01

Seasonal variation of the hydrography along the southeast Arabian Sea is described using data collected onboard FORV Sagar Sampada in September--October 2003 (later phase of Southwest monsoon, SWM) and March--April 2004 (Spring inter monsoon, SIM). During the later phase of the SWM, upwelling was in the withdrawal phase and the frontal structure was clearer in the northern sections (13 and 15 degrees N lat) indicating strong upwelling in the area. The driving force of upwelling is identified as the combination of alongshore wind stress and remote forcing with a latitudinal variability. Although a more prominent upwelling was found in the north, a maximum surface Chlorophyll-a was found in the south (10 degrees N). During the SIM, the area was characterized by oligotrophic water with relatively high Sea Surface Temperature (>29 degrees C) and low salinity (33.8 to 35.4). During March, the surface hydrography was found to be controlled mainly by the intrusion of low-saline waters from the south, while during September by the high saline water from the north. The presence of various water masses [Arabian Sea High Salinity Water (ASHSW), Persian Gulf Water (PGW), Red Sea Water (RSW)] and their seasonal variations in the region is discussed and their decreasing influence towards the south is noted during both periods of observation. During the SWM, the dynamic topography showed the equator-ward flow of the West India Coastal Current (WICC) at the surface and a pole-ward coastal under current at sub-thermocline depth. During the SIM, surface circulation revealed the WICC flowing pole-ward north of 13 degrees N, but equator-ward flow in the south, with a clockwise circulation around the Lakshadweep High.

Interactions between groundwater and surface water: The state of the science

USGS Publications Warehouse

Sophocleous, M.

2002-01-01

The interactions between groundwater and surface water are complex. To understand these interactions in relation to climate, landform, geology, and biotic factors, a sound hydrogeoecological framework is needed. All these aspects are synthesized and exemplified in this overview. In addition, the mechanisms of interactions between groundwater and surface water (GW-SW) as they affect recharge-discharge processes are comprehensively outlined, and the ecological significance and the human impacts of such interactions are emphasized. Surface-water and groundwater ecosystems are viewed as linked components of a hydrologic continuum leading to related sustainability issues. This overview concludes with a discussion of research needs and challenges facting this evolving field. The biogeochemical processes within the upper few centimeters of sediments beneath nearly all surface-water bodies (hyporheic zone) have a profound effect on the chemistry of the water interchange, and here is where most of the recent research has been focusing. However, to advance conceptual and other modeling of GW-SW systems, a broader perspective of such interactions across and between surface-water bodies is needed, including multidimensional analyses, interface hydraulic characterization and spatial variability, site-to-region regionalization approaches, as well as cross-disciplinary collaborations.

Characterization of Surface Water and Groundwater Quality in the Lower Tano River Basin Using Statistical and Isotopic Approach.

NASA Astrophysics Data System (ADS)

Edjah, Adwoba; Stenni, Barbara; Cozzi, Giulio; Turetta, Clara; Dreossi, Giuliano; Tetteh Akiti, Thomas; Yidana, Sandow

2017-04-01

Adwoba Kua- Manza Edjaha, Barbara Stennib,c,Giuliano Dreossib, Giulio Cozzic, Clara Turetta c,T.T Akitid ,Sandow Yidanae a,eDepartment of Earth Science, University of Ghana Legon, Ghana West Africa bDepartment of Enviromental Sciences, Informatics and Statistics, Ca Foscari University of Venice, Italy cInstitute for the Dynamics of Environmental Processes, CNR, Venice, Italy dDepartment of Nuclear Application and Techniques, Graduate School of Nuclear and Allied Sciences University of Ghana Legon This research is part of a PhD research work "Hydrogeological Assessment of the Lower Tano river basin for sustainable economic usage, Ghana, West - Africa". In this study, the researcher investigated surface water and groundwater quality in the Lower Tano river basin. This assessment was based on some selected sampling sites associated with mining activities, and the development of oil and gas. Statistical approach was applied to characterize the quality of surface water and groundwater. Also, water stable isotopes, which is a natural tracer of the hydrological cycle was used to investigate the origin of groundwater recharge in the basin. The study revealed that Pb and Ni values of the surface water and groundwater samples exceeded the WHO standards for drinking water. In addition, water quality index (WQI), based on physicochemical parameters(EC, TDS, pH) and major ions(Ca2+, Na+, Mg2+, HCO3-,NO3-, CL-, SO42-, K+) exhibited good quality water for 60% of the sampled surface water and groundwater. Other statistical techniques, such as Heavy metal pollution index (HPI), degree of contamination (Cd), and heavy metal evaluation index (HEI), based on trace element parameters in the water samples, reveal that 90% of the surface water and groundwater samples belong to high level of pollution. Principal component analysis (PCA) also suggests that the water quality in the basin is likely affected by rock - water interaction and anthropogenic activities (sea water intrusion). This was confirm by further statistical analysis (cluster analysis and correlation matrix) of the water quality parameters. Spatial distribution of water quality parameters, trace elements and the results obtained from the statistical analysis was determined by geographical information system (GIS). In addition, the isotopic analysis of the sampled surface water and groundwater revealed that most of the surface water and groundwater were of meteoric origin with little or no isotopic variations. It is expected that outcomes of this research will form a baseline for making appropriate decision on water quality management by decision makers in the Lower Tano river Basin. Keywords: Water stable isotopes, Trace elements, Multivariate statistics, Evaluation indices, Lower Tano river basin.

Evaluation of water-quality data and monitoring program for Lake Travis, near Austin, Texas

USGS Publications Warehouse

Rast, Walter; Slade, Raymond M.

1998-01-01

The multiple-comparison tests indicate that, for some constituents, a single sampling site for a constituent or property might adequately characterize the water quality of Lake Travis for that constituent or property. However, multiple sampling sites are required to provide information of sufficient temporal and spatial resolution to accurately evaluate other water-quality constituents for the reservoir. For example, the water-quality data from surface samples and from bottom samples indicate that nutrients (nitrogen, phosphorus) might require additional sampling sites for a more accurate characterization of their in-lake dynamics.

Surface characterization of selected LDEF tray clamps

NASA Technical Reports Server (NTRS)

Cromer, T. F.; Grammer, H. L.; Wightman, J. P.; Young, Philip R.; Slemp, Wayne S.

1993-01-01

The surface characterization of chromic acid anodized 6061-T6 aluminum alloy tray clamps has shown differences in surface chemistry depending upon the position on the Long Duration Exposure Facility (LDEF). Water contact angle results showed no changes in wettability of the tray clamps. The overall surface topography of the control, trailing edge(E3) and leading edge(D9) samples was similar. The thickness of the aluminum oxide layer for all samples determined by Auger depth profiling was less than one micron. X-ray photoelectron spectroscopy (XPS) analysis of the tray clamps showed significant differences in the surface composition. Carbon and silicon containing compounds were the primary contaminants detected.

Wetlands inform how climate extremes influence surface water expansion and contraction

USGS Publications Warehouse

Vanderhoof, Melanie; Lane, Charles R.; McManus, Michael L.; Alexander, Laurie C.; Christensen, Jay R.

2018-01-01

Effective monitoring and prediction of flood and drought events requires an improved understanding of how and why surface water expansion and contraction in response to climate varies across space. This paper sought to (1) quantify how interannual patterns of surface water expansion and contraction vary spatially across the Prairie Pothole Region (PPR) and adjacent Northern Prairie (NP) in the United States, and (2) explore how landscape characteristics influence the relationship between climate inputs and surface water dynamics. Due to differences in glacial history, the PPR and NP show distinct patterns in regards to drainage development and wetland density, together providing a diversity of conditions to examine surface water dynamics. We used Landsat imagery to characterize variability in surface water extent across 11 Landsat path/rows representing the PPR and NP (images spanned 1985–2015). The PPR not only experienced a 2.6-fold greater surface water extent under median conditions relative to the NP, but also showed a 3.4-fold greater change in surface water extent between drought and deluge conditions. The relationship between surface water extent and accumulated water availability (precipitation minus potential evapotranspiration) was quantified per watershed and statistically related to variables representing hydrology-related landscape characteristics (e.g., infiltration capacity, surface storage capacity, stream density). To investigate the influence stream connectivity has on the rate at which surface water leaves a given location, we modeled stream-connected and stream-disconnected surface water separately. Stream-connected surface water showed a greater expansion with wetter climatic conditions in landscapes with greater total wetland area, but lower total wetland density. Disconnected surface water showed a greater expansion with wetter climatic conditions in landscapes with higher wetland density, lower infiltration and less anthropogenic drainage. From these findings, we can expect that shifts in precipitation and evaporative demand will have uneven effects on surface water quantity. Accurate predictions regarding the effect of climate change on surface water quantity will require consideration of hydrology-related landscape characteristics including wetland storage and arrangement.

Impact of the Hydration States of Polymers on Their Hemocompatibility for Medical Applications: A Review

PubMed Central

Bag, Min A.

2017-01-01

Water has a key role in the functioning of all biological systems, it mediates many biochemical reactions, as well as other biological activities such as material biocompatibility. Water is often considered as an inert solvent, however at the molecular level, it shows different behavior when sorbed onto surfaces like polymeric implants. Three states of water have been recognized: non-freezable water, which does not freeze even at −100 °C; intermediate water, which freezes below 0 °C; and, free water, which freezes at 0 °C like bulk water. This review describes the different states of water and the techniques for their identification and quantification, and analyzes their relationship with hemocompatibility in polymer surfaces. Intermediate water content higher than 3 wt % is related to better hemocompatibility for poly(ethylene glycol), poly(meth)acrylates, aliphatic carbonyls, and poly(lactic-co-glycolic acid) surfaces. Therefore, characterizing water states in addition to water content is key for polymer selection and material design for medical applications. PMID:28771174

X-Ray-Based Imaging for Characterizing Heterogeneous Gas Diffusion Layers for Polymer Electrolyte Membrane Fuel Cells

NASA Astrophysics Data System (ADS)

George, Michael G.

Characterization of gas diffusion layers (GDLs) for polymer electrolyte membrane (PEM) fuel cells informs modeling studies and the manufacturers of next generation fuel cell materials. Identifying the physical properties related to the primary functions of the modern GDL (thermal, electrical, and mass transport) is necessary for understanding the impact of GDL design choices. X-ray micro-computed tomographic reconstructions of GDLs were studied to isolate GDL surface morphologies. Surface roughness was measured for a wide variety of samples and a sensitivity study highlighted the scale-dependence of surface roughness measurements. Furthermore, a spatially resolved distribution map of polytetrafluoroethylene (PTFE) in the microporous layer (MPL), critical for water management and mass transport, was identified and the existence of PTFE agglomerations was highlighted. Finally, the impact of accelerated degradation on GDL wettability and water transport increases in liquid water accumulation and oxygen mass transport resistance were quantified as a result of accelerated GDL degradation.

The Europa Lander Mission Concept and Science Goals — Highlighting Ice Properties and Surface Activity

NASA Astrophysics Data System (ADS)

Hand, K. P.; Murray, A. E.; Garvin, J.; Horst, S.; Brinckerhoff, W.; Edgett, K.; Hoehler, T.; Russell, M.; Rhoden, A.; Yingst, R. A.; German, C.; Schmidt, B.; Paranicas, C.; Smith, D.; Willis, P.; Hayes, A.; Ehlmann, B.; Lunine, J.; Templeton, A.; Nealson, K.; Christner, B.; Cable, M.; Craft, K.; Pappalardo, R.; Hofmann, A.; Nordheim, T.; Phillips, C.

2018-06-01

The Europa Lander mission concept would address key questions regarding ice properties and surface activity, including characterizing any plume deposits, understanding local topography, searching for evidence of interactions with liquid water.

Thiolated poly(ɛ-caprolactone) macroligand with vacant coordination sites on gold substrate: Synthesis and surface characterization

NASA Astrophysics Data System (ADS)

Farah, Abdiaziz A.; Zheng, Susan H.; Morin, Sylvie; Bensebaa, Farid; Pietro, William J.

2007-04-01

Surface-confined telechelic poly(ɛ-caprolactone) macroligand with two distinct functional groups per polymeric chain has been synthesized and characterized. The molecular microstructure of the macroligand with regard to the properties of the end-capped functionalities and with those on surface substrate has been studied by solution and surface analytical methods (i.e., X-ray photoelectron spectroscopy (XPS), grazing angle reflectance-Fourier transform IR spectroscopy (GA-FTIR), water contact angle measurements, and atomic force microscopy (AFM)) to elucidate the structure and properties of such multifunctional polymer on gold (1 1 1) substrate.

Gypsies in the palace: Experimentalist's view on the use of 3-D physics-based simulation of hillslope hydrological response

USGS Publications Warehouse

James, A.L.; McDonnell, Jeffery J.; Tromp-Van Meerveld, I.; Peters, N.E.

2010-01-01

As a fundamental unit of the landscape, hillslopes are studied for their retention and release of water and nutrients across a wide range of ecosystems. The understanding of these near-surface processes is relevant to issues of runoff generation, groundwater-surface water interactions, catchment export of nutrients, dissolved organic carbon, contaminants (e.g. mercury) and ultimately surface water health. We develop a 3-D physics-based representation of the Panola Mountain Research Watershed experimental hillslope using the TOUGH2 sub-surface flow and transport simulator. A recent investigation of sub-surface flow within this experimental hillslope has generated important knowledge of threshold rainfall-runoff response and its relation to patterns of transient water table development. This work has identified components of the 3-D sub-surface, such as bedrock topography, that contribute to changing connectivity in saturated zones and the generation of sub-surface stormflow. Here, we test the ability of a 3-D hillslope model (both calibrated and uncalibrated) to simulate forested hillslope rainfall-runoff response and internal transient sub-surface stormflow dynamics. We also provide a transparent illustration of physics-based model development, issues of parameterization, examples of model rejection and usefulness of data types (e.g. runoff, mean soil moisture and transient water table depth) to the model enterprise. Our simulations show the inability of an uncalibrated model based on laboratory and field characterization of soil properties and topography to successfully simulate the integrated hydrological response or the distributed water table within the soil profile. Although not an uncommon result, the failure of the field-based characterized model to represent system behaviour is an important challenge that continues to vex scientists at many scales. We focus our attention particularly on examining the influence of bedrock permeability, soil anisotropy and drainable porosity on the development of patterns of transient groundwater and sub-surface flow. Internal dynamics of transient water table development prove to be essential in determining appropriate model parameterization. ?? 2010 John Wiley & Sons, Ltd.

Compositions of surface layers formed on amalgams in air, water, and saline.

PubMed

Hanawa, T; Gnade, B E; Ferracane, J L; Okabe, T; Watari, F

1993-12-01

The surface layers formed on both a zinc-free and a zinc-containing dental amalgam after polishing and aging in air, water, or saline, were characterized using x-ray photoelectron spectroscopy (XPS) to determine the compositions of the surface layers which might govern the release of mercury from amalgam. The XPS data revealed that the formation of the surface layer on the zinc-containing amalgam was affected by the environment in which the amalgam was polished and aged, whereas that on the zinc-free amalgam was not affected. In addition, among the elements contained in amalgam, zinc was the most reactive with the environment, and was preferentially dissolved from amalgam into water or saline. Mercury atoms existed in the metallic state in the surface layer.

Spectroscopic analyses of Fe and water in clays: A Martian surface weathering study

NASA Technical Reports Server (NTRS)

Bishop, J. L.; Pieters, Carle M.; Edwards, J. O.; Coyne, L. M.; Chang, S.

1991-01-01

Martian surface morphology suggests the presence of liquid H2O on Mars in the past. Reflectance spectra of the Martian surface include features which correspond to the crystal field transitions of iron, as well as features supporting the presence of ice and minerals containing structural OH and surface water. Researchers initiated further spectroscopic studies of surface iron and water and structural OH in clays in order to determine what remotely obtained spectra can indicate about the presence of clays on Mars based on a clearer understanding of the factors influencing the spectral features. Current technology allows researchers to better correlate the low frequency fundamental stretching and bending vibrations of O-H bonds with the diagnostic near infrared overtone and combination bands used in mineral characterization and identification.

Results of soil, ground-water, surface-water, and streambed-sediment sampling at Air Force Plane 85, Columbus, Ohio, 1996

USGS Publications Warehouse

Parnell, J.M.

1997-01-01

The U.S. Geological Survey (USGS), in cooperation with Aeronautical Systems Center, Environmental Management Directorate, Restoration Division, prepared the Surface- and Ground- Water Monitoring Work Plan for Air Force Plant 85 (AFP 85 or Plant), Columbus, Ohio, under the Air Force Installation Restoration Program to characterize any ground-water, surface-water, and soil contamination that may exist at AFP 85. The USGS began the study in November 1996. The Plant was divided into nine sampling areas, which included some previously investi gated study sites. The investigation activities included the collection and presentation of data taken during drilling and water-quality sampling. Data collection focused on the saturated and unsatur ated zones and surface water. Twenty-three soil borings were completed. Ten monitoring wells (six existing wells and four newly constructed monitoring wells) were selected for water-quality sam pling. Surface-water and streambed-sediment sampling locations were chosen to monitor flow onto and off of the Plant. Seven sites were sampled for both surface-water and streambed-sediment quality. This report presents data on the selected inorganic and organic constituents in soil, ground water, surface water, and streambed sediments at AFP 85. The methods of data collection and anal ysis also are included. Knowledge of the geologic and hydrologic setting could aid Aeronautical Systems Center, Environmental Management Directorate, Restoration Division, and its governing regulatory agencies in future remediation studies.

Characterizing the concentration of Cryptosporidium in Australian surface waters for setting health-based targets for drinking water treatment.

PubMed

Petterson, S; Roser, D; Deere, D

2015-09-01

It is proposed that the next revision of the Australian Drinking Water Guidelines will include 'health-based targets', where the required level of potable water treatment quantitatively relates to the magnitude of source water pathogen concentrations. To quantify likely Cryptosporidium concentrations in southern Australian surface source waters, the databases for 25 metropolitan water supplies with good historical records, representing a range of catchment sizes, land use and climatic regions were mined. The distributions and uncertainty intervals for Cryptosporidium concentrations were characterized for each site. Then, treatment targets were quantified applying the framework recommended in the World Health Organization Guidelines for Drinking-Water Quality 2011. Based on total oocyst concentrations, and not factoring in genotype or physiological state information as it relates to infectivity for humans, the best estimates of the required level of treatment, expressed as log10 reduction values, ranged among the study sites from 1.4 to 6.1 log10. Challenges associated with relying on historical monitoring data for defining drinking water treatment requirements were identified. In addition, the importance of quantitative microbial risk assessment input assumptions on the quantified treatment targets was investigated, highlighting the need for selection of locally appropriate values.

Shallow cumulus rooted in photosynthesis

NASA Astrophysics Data System (ADS)

Vila-Guerau Arellano, J.; Ouwersloot, H.; Horn, G.; Sikma, M.; Jacobs, C. M.; Baldocchi, D.

2014-12-01

We investigate the interaction between plant evapotranspiration, controlled by photosynthesis (for a low vegetation cover by C3 and C4 grasses), and the moist thermals that are responsible for the formation and development of shallow cumulus clouds (SCu). We perform systematic numerical experiments at fine spatial scales using large-eddy simulations explicitly coupled to a plant-physiology model. To break down the complexity of the vegetation-atmospheric system at the diurnal scales, we design the following experiments with increasing complexity: (a) clouds that are transparent to radiation, (b) clouds that shade the surface from the incoming shortwave radiation and (c) plant stomata whose apertures react with an adjustment in time to cloud perturbations. The shading by SCu leads to a strong spatial variability in photosynthesis and the surface energy balance. As a result, experiment (b) simulates SCu that are characterized by less extreme and less skewed values of the liquid water path and cloud-base height. These findings are corroborated by the calculation of characteristics lengths scales of the thermals and clouds using autocorrelation and spectral analysis methods. We find that experiments (a) and (b) are characterized by similar cloud cover evolution, but different cloud population characteristics. Experiment (b), including cloud shading, is characterized by smaller clouds, but closer to each other. By performing a sensitivity analysis on the exchange of water vapor and carbon dioxide at the canopy level, we show that the larger water-use efficiency of C4 grass leads to two opposing effects that directly influence boundary-layer clouds: the thermals below the clouds are more vigorous and deeper driven by a larger buoyancy surface flux (positive effect), but are characterized by less moisture content (negative effect). We conclude that under the investigated mid-latitude atmospheric and well-watered soil conditions, SCu over C4 grass fields is characterized by larger cloud cover and an enhanced liquid water path compared to C3 grass fields.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Giri, R. P., E-mail: rajendra.giri@saha.ac.in; Mukhopadhyay, M. K.

The spontaneous surface aggregation of diblock copolymer, containing polystyrene-polydimethylsiloxane or PS-PDMS, have been studied at air-water interface using Brewster’s angle microscopy (BAM) and grazing incidence small angle x-ray scattering (GISAXS) technique. Pronounced differences in the molecular weight and solvent dependence of the size of aggregation on the water surface are observed. Structural characterization is done using atomic force microscopy (AFM) for a monolayer transferred to Si substrate. It shows that, individual polymer chains coalesce to form some disc like micelle aggregation on the Si surface which is also evident from the BAM image of the water floated monolayer. GISAXS studymore » is also corroborating the same result.« less

Superhydrophobic aluminum alloy surfaces by a novel one-step process.

PubMed

Saleema, N; Sarkar, D K; Paynter, R W; Chen, X-G

2010-09-01

A simple one-step process has been developed to render aluminum alloy surfaces superhydrophobic by immersing the aluminum alloy substrates in a solution containing NaOH and fluoroalkyl-silane (FAS-17) molecules. Scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and water contact angle measurements have been performed to characterize the morphological features, chemical composition and superhydrophobicity of the surfaces. The resulting surfaces provided a water contact angle as high as ∼162° and a contact angle hysteresis as low as ∼4°. The study indicates that it is possible to fabricate superhydrophobic aluminum surfaces easily and effectively without involving the traditional two-step processes.

Adsorption and wetting characterization of hydrophobic SBA-15 silicas.

PubMed

Bernardoni, Frank; Fadeev, Alexander Y

2011-04-15

This work describes adsorption and wetting characterization of hydrophobic ordered mesoporous silicas (OMSs) with the SBA-15 motif. Three synthetic approaches to prepare hydrophobic SBA-15 silicas were explored: grafting with (1) covalently-attached monolayers (CAMs) of C(n)H(2)(n+1)Si(CH(3))(2)N(CH(3))(2), (2) self-assembled monolayers (SAMs) of C(n)H(2)(n+1)Si(OEt)(3), and (3) direct ("one-pot") co-condensation of TEOS with C(n)H(2)(n+1)Si(OEt)(3) in presence of P123 (n=1-18). The materials prepared were characterized by nitrogen adsorption, TEM, and chemical analysis. The surface properties of the materials were assessed by water contact angles (CAs) and by BET C constants. The results showed that, while loadings of the alkyl groups (%C) were comparable, the surface properties and pore ordering of the materials prepared through different methods were quite different. The best quality hydrophobic surfaces were prepared for SBA-15 grafted with CAMs of alkylsilanes. For these materials, the water CAs were above ∼120°/100° (adv/rec) and BET C constants were in the range of ∼15-25, indicating uniform low-energy surfaces of closely packed alkyl groups on external and internal surfaces of the pores respectively. Moreover, surfaces grafted with the long-chained (C(12)-C(18)) silanes showed super-hydrophobic behavior (CAs∼150-180°) and extremely low adhesion for water. The pore uniformity of parental SBA-15 was largely preserved and the pore volume and pore diameter were consistent with the formation of a single layer of alkylsilyl groups inside the pores. Post-synthesis grafting of SBA-15 with SAMs worked not as well as CAMs: the surfaces prepared demonstrated lower water CAs and higher BET C constants, thereby indicating a small amount of accessible polar groups (Si-OH) related to packing constrains for SAMs supported on highly curved surfaces of mesopores. The co-condensation method produced substantially more disordered materials and less hydrophobic surfaces than any of the grafting methods. The surfaces of these materials showed low water CAs and high BET C constants (∼100-200) thereby demonstrating a non-uniform surface coverage and presence of unmodified silica. It is concluded that CAMs chemistry is the most efficient approach in preparation of the functionalized OMS materials with uniform surfaces and pores. Copyright © 2011 Elsevier Inc. All rights reserved.

Perfluoroalkyl acids in surface waters and tapwater in the Qiantang River watershed-Influences from paper, textile, and leather industries.

PubMed

Lu, Guo-Hui; Gai, Nan; Zhang, Peng; Piao, Hai-Tao; Chen, Shu; Wang, Xiao-Chun; Jiao, Xing-Chun; Yin, Xiao-Cai; Tan, Ke-Yan; Yang, Yong-Liang

2017-10-01

Perfluoroalkyl acids (PFAAs) are widely used as multi-purpose surfactants or water/oil repellents. In order to understand the contamination level and compositional profiles of PFAAs in aqueous environment in textile, leather, and paper making industrial areas, surface waters and tap waters were collected along the watershed of the Qiantang River where China's largest textile, leather, and paper making industrial bases are located. For comparison, surface water and tapwater samples were also collected in Hangzhou and its adjacent areas. 17 PFAAs were analyzed by solid phase extraction-high performance liquid chromatography-tandem mass spectrometry. The results show that the total concentrations of PFAAs (ΣPFAAs) in the Qiantang River waters ranged from 106.1 to 322.9 ng/L, averaging 164.2 ng/L. The contamination levels have been found to be extremely high, comparable to the levels of the most serious PFAA contamination in surface waters of China. The PFAA composition profiles were characterized by the dominant PFOA (average 58.1% of the total PFAAs), and PFHxA (average 18.8%). The ΣPFAAs in tap water ranged from 9.5 to 174.8 ng/L, showing PFAA compositional pattern similar to the surface waters. Good correlations between PFAA composition profiles in tap waters and the surface waters were observed. Copyright © 2017 Elsevier Ltd. All rights reserved.

Surface characterization of U(AlxSi1-x)3 alloy and its interaction with O2 and H2O, at room temperature

NASA Astrophysics Data System (ADS)

Matmor, M.; Cohen, S.; Rafailov, G.; Vaknin, M.; Shamir, N.; Gouder, T.; Zalkind, S.

2018-02-01

Surface characterization and the interactions of U(AlxSi1-x)3 alloy (x = 0.57) with oxygen and water vapor were studied, utilizing X-Ray Photoelectron Spectroscopy and Direct Recoil Spectrometry, at room temperature. The U 4f spectrum of U(AlxSi1-x)3 alloy exhibits weak correlation satellites, suggesting an itinerant description of the U 5f states for this compound. The Al and Si 2p lines are chemically shifted to lower binding energies. Exposing the alloy to oxygen and water vapor results in oxidation of mainly the uranium and aluminum components, while silicon is only slightly oxidized. Oxygen was found to be a stronger oxidizer than water vapor and the trend is consistent with the more negative enthalpies of formation of metal oxides produced by the O2 reaction, as compared to H2O. During oxygen exposure, fast oxidation occurs by oxide islands nucleation and lateral growth, followed by oxidation of the sub-surface, up to ∼4 nm, at 1000 L exposure. Water initially reacts with the surface by full dissociation and oxide islands formation, which is then covered by hydroxides. Only a minor increase in the oxide thickness of up to ∼2.5 nm, was observed after coalescence.

Preparation of enhanced hydrophobic poly(L-lactide-co-ɛ-caprolactone) films surface and its blood compatibility

NASA Astrophysics Data System (ADS)

Kim, Seung Il; Lim, Jin Ik; Jung, Youngmee; Mun, Cho Hay; Kim, Ji Heung; Kim, Soo Hyun

2013-07-01

Hydrophobicity-enhanced poly(L-lactide-co-ɛ-caprolactone) (PLCL) (50:50) films were cast by using the solvent-nonsolvent casting method. PLCL (50:50) was synthesized by the well-known random copolymerization process and confirmed by 1H NMR analysis. The molecular weight of the synthesized PLCL was measured by gel permeation chromatography (GPC). Number-average (Mn), weight-average (Mw) molecular weights and polydispersity (Mw/Mn) were 7 × 104, 1.2 × 105, and 1.7, respectively. PLCL films were cast in vacuum condition with various nonsolvents and nonsolvent ratios. Tetrahydrofuran (THF) was used as the solvent and three different alcohols were used as the nonsolvent: methanol, ethanol, and isopropyl alcohol (IPA). Surface hydrophobicity was confirmed by water contact angle. The water contact angle was increased from 81° ± 2° to 107° ± 2°. Water contact angle was influenced by surface porosity and topography. The prepared film surfaces were characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The change of crystalline property was characterized by X-ray diffraction (XRD). Platelet adhesion tests on the modified PLCL film surfaces were evaluated by platelet-rich plasma (PRP). The modified film surface exhibited enhanced hydrophobicity and reduced platelet adhesion ratio depending on the surface topography. One of the candidate products proposed as a potential blood compatible material showed a markedly reduced platelet adhesion property.

Evaluation of Ohio River NOM Variability and NOM Concentration vs. Reconstitution

EPA Science Inventory

Surface water contains natural organic matter (NOM) which reacts with disinfectants creating disinfection byproducts (DBPs), some of which are USEPA regulated contaminants. Characterizing NOM can provide important insight on DBP formation and water treatment process adaptation t...

Spatial and Temporal Scales of Surface Water-Groundwater Interactions

NASA Astrophysics Data System (ADS)

Boano, F.

2016-12-01

The interfaces between surface water and groundwater (i.e., river and lake sediments) represent hotspots for nutrient transformation in watersheds. This intense biochemical activity stems from the peculiar physicochemical properties of these interface areas. Here, the exchange of water and nutrients between surface and subsurface environments creates an ecotone region that can support the presence of different microbial species responsible for nutrient transformation. Previous studies have elucidated that water exchange between rivers and aquifers is organized in a complex system of nested flow cells. Each cell entails a range of residence timescales spanning multiple order of magnitudes, providing opportunities for different biochemical reactions to occur. Physically-bases models represent useful tools to deal with the wide range of spatial and temporal scales that characterize surface-subsurface water exchange. This contribution will present insights about how hydrodynamic processes control scale organization for surface water - groundwater interactions. The specific focus will be the influence of exchange processes on microbial activity and nutrient transformation, discussing how groundwater flow at watershed scale controls flow conditions and hence constrain microbial reactions at much smaller scales.

Enhancement of Biomass and Lipid Productivities of Water Surface-Floating Microalgae by Chemical Mutagenesis

PubMed Central

Nojima, Daisuke; Ishizuka, Yuki; Muto, Masaki; Ujiro, Asuka; Kodama, Fumito; Yoshino, Tomoko; Maeda, Yoshiaki; Matsunaga, Tadashi; Tanaka, Tsuyoshi

2017-01-01

Water surface-floating microalgae have great potential for biofuel applications due to the ease of the harvesting process, which is one of the most problematic steps in conventional microalgal biofuel production. We have collected promising water surface-floating microalgae and characterized their capacity for biomass and lipid production. In this study, we performed chemical mutagenesis of two water surface-floating microalgae to elevate productivity. Floating microalgal strains AVFF007 and FFG039 (tentatively identified as Botryosphaerella sp. and Chlorococcum sp., respectively) were exposed to ethyl methane sulfonate (EMS) or 1-methyl-3-nitro-1-nitrosoguanidine (MNNG), and pale green mutants (PMs) were obtained. The most promising FFG039 PM formed robust biofilms on the surface of the culture medium, similar to those formed by wild type strains, and it exhibited 1.7-fold and 1.9-fold higher biomass and lipid productivities than those of the wild type. This study indicates that the chemical mutation strategy improves the lipid productivity of water surface-floating microalgae without inhibiting biofilm formation and floating ability. PMID:28555001

Enhancement of Biomass and Lipid Productivities of Water Surface-Floating Microalgae by Chemical Mutagenesis.

PubMed

Nojima, Daisuke; Ishizuka, Yuki; Muto, Masaki; Ujiro, Asuka; Kodama, Fumito; Yoshino, Tomoko; Maeda, Yoshiaki; Matsunaga, Tadashi; Tanaka, Tsuyoshi

2017-05-27

Water surface-floating microalgae have great potential for biofuel applications due to the ease of the harvesting process, which is one of the most problematic steps in conventional microalgal biofuel production. We have collected promising water surface-floating microalgae and characterized their capacity for biomass and lipid production. In this study, we performed chemical mutagenesis of two water surface-floating microalgae to elevate productivity. Floating microalgal strains AVFF007 and FFG039 (tentatively identified as Botryosphaerella sp. and Chlorococcum sp., respectively) were exposed to ethyl methane sulfonate (EMS) or 1-methyl-3-nitro-1-nitrosoguanidine (MNNG), and pale green mutants (PMs) were obtained. The most promising FFG039 PM formed robust biofilms on the surface of the culture medium, similar to those formed by wild type strains, and it exhibited 1.7-fold and 1.9-fold higher biomass and lipid productivities than those of the wild type. This study indicates that the chemical mutation strategy improves the lipid productivity of water surface-floating microalgae without inhibiting biofilm formation and floating ability.

Characterization of Preferential Ground-Water Seepage From a Chlorinated Hydrocarbon-Contaminated Aquifer to West Branch Canal Creek, Aberdeen Proving Ground, Maryland, 2002-04

USGS Publications Warehouse

Majcher, Emily H.; Phelan, Daniel J.; Lorah, Michelle M.; McGinty, Angela L.

2007-01-01

Wetlands act as natural transition zones between ground water and surface water, characterized by the complex interdependency of hydrology, chemical and physical properties, and biotic effects. Although field and laboratory demonstrations have shown efficient natural attenuation processes in the non-seep wetland areas and stream bottom sediments of West Branch Canal Creek, chlorinated volatile organic compounds are present in a freshwater tidal creek at Aberdeen Proving Ground, Maryland. Volatile organic compound concentrations in surface water indicate that in some areas of the wetland, preferential flow paths or seeps allow transport of organic compounds from the contaminated sand aquifer to the overlying surface water without undergoing natural attenuation. From 2002 through 2004, the U.S. Geological Survey, in cooperation with the Environmental Conservation and Restoration Division of the U.S. Army Garrison, Aberdeen Proving Ground, characterized preferential ground-water seepage as part of an ongoing investigation of contaminant distribution and natural attenuation processes in wetlands at this site. Seep areas were discrete and spatially consistent during thermal infrared surveys in 2002, 2003, and 2004 throughout West Branch Canal Creek wetlands. In these seep areas, temperature measurements in shallow pore water and sediment more closely resembled those in ground water than those in nearby surface water. Generally, pore water in seep areas contaminated with chlorinated volatile organic compounds had lower methane and greater volatile organic compound concentrations than pore water in non-seep wetland sediments. The volatile organic compounds detected in shallow pore water in seeps were spatially similar to the dominant volatile organic compounds in the underlying Canal Creek aquifer, with both parent and anaerobic daughter compounds detected. Seep locations characterized as focused seeps contained the highest concentrations of chlorinated parent compounds, relatively low concentrations of chlorinated daughter compounds, and insignificant concentrations of methane in shallow pore water samples. These seeps were primarily along the creek edge or formed a dendritic-like pattern between the wetland and creek channel. In contrast, seep locations characterized as diffuse seeps contained relatively high concentrations of chlorinated daughter compounds (or a mixture of daughter and parent compounds) and detectable methane concentrations in shallow pore water samples. These seeps were primarily along the wetland boundary. Qualitative thermal infrared surveys coupled with quantitative verification of temperature differences, and screening for volatile organic compound and methane concentrations proved to be effective tools in determining the overall extent of preferential seepage. Hydrologic and physical properties of wetland sediments were characterized at two focused and one diffuse seep location. In the seeps with focused discharge, measured seepage was consistent over the tidal cycle, whereas more variability with tidal fluctuation was measured in the diffuse seep location. At all locations, areas were identified within the general seep boundaries where discharge was minimal. In all cases, the geometric mean of non-zero vertical flux measurements was greater than those previously reported in the non-seep wetland sediments using flow-net analysis. Flux was greater in the focused discharge areas than in the diffuse discharge area, and all fluxes were within the range reported in the literature for wetland discharge. Vertical hydraulic conductivity estimated from seepage flux and a mean vertical gradient at seeps with focused discharge resulted in a minimum hydraulic conductivity two orders of magnitude greater than those estimated in the non-seep sediment. In contrast, vertical conductivity estimates at a diffuse seep were similar to estimates along a nearby line of section through a non-seep area. Horizontal hydraulic cond

Soil water sensing for climate change studies; Applicability of COSMOS and local sensor networks

USDA-ARS?s Scientific Manuscript database

Soil water sensors are used to characterize water content in the near-surface, the root zone and below for agricultural and ecosystem management, but only a few are capable of sensing soil volumes larger than a few hundred liters. Scientists with the USDA-ARS Conservation & Production Research Labor...

Heterogeneous nucleation of ice on carbon surfaces.

PubMed

Lupi, Laura; Hudait, Arpa; Molinero, Valeria

2014-02-26

Atmospheric aerosols can promote the heterogeneous nucleation of ice, impacting the radiative properties of clouds and Earth's climate. The experimental investigation of heterogeneous freezing of water droplets by carbonaceous particles reveals widespread ice freezing temperatures. It is not known which structural and chemical characteristics of soot account for the variability in ice nucleation efficiency. Here we use molecular dynamics simulations to investigate the nucleation of ice from liquid water in contact with graphitic surfaces. We find that atomically flat carbon surfaces promote heterogeneous nucleation of ice, while molecularly rough surfaces with the same hydrophobicity do not. Graphitic surfaces and other surfaces that promote ice nucleation induce layering in the interfacial water, suggesting that the order imposed by the surface on liquid water may play an important role in the heterogeneous nucleation mechanism. We investigate a large set of graphitic surfaces of various dimensions and radii of curvature and find that variations in nanostructures alone could account for the spread in the freezing temperatures of ice on soot in experiments. We conclude that a characterization of the nanostructure of soot is needed to predict its ice nucleation efficiency.

2D-HB-Network at the air-water interface: A structural and dynamical characterization by means of ab initio and classical molecular dynamics simulations

NASA Astrophysics Data System (ADS)

Pezzotti, Simone; Serva, Alessandra; Gaigeot, Marie-Pierre

2018-05-01

Following our previous work where the existence of a special 2-Dimensional H-Bond (2D-HB)-Network was revealed at the air-water interface [S. Pezzotti et al., J. Phys. Chem. Lett. 8, 3133 (2017)], we provide here a full structural and dynamical characterization of this specific arrangement by means of both Density Functional Theory based and Force Field based molecular dynamics simulations. We show in particular that water at the interface with air reconstructs to maximize H-Bonds formed between interfacial molecules, which leads to the formation of an extended and non-interrupted 2-Dimensional H-Bond structure involving on average ˜90% of water molecules at the interface. We also show that the existence of such an extended structure, composed of H-Bonds all oriented parallel to the surface, constrains the reorientional dynamics of water that is hence slower at the interface than in the bulk. The structure and dynamics of the 2D-HB-Network provide new elements to possibly rationalize several specific properties of the air-water interface, such as water surface tension, anisotropic reorientation of interfacial water under an external field, and proton hopping.

Structural and dynamical characterization of water on the Au (100) and graphene surfaces: A molecular dynamics simulation approach

NASA Astrophysics Data System (ADS)

Foroutan, Masumeh; Darvishi, Mehdi; Fatemi, S. Mahmood

2017-09-01

The positioning, adsorption, and movement of water on substrates is dependent upon the chemical nature and arrangement of the atoms of the surface. Therefore the behavior of water molecules on a substrate is a reflection of properties of the surface. Based on this premise, graphene and gold substrates were chosen to study this subject from a molecular perspective. In this work, the structural and dynamical behaviors of a water nanodroplet on Au (100) and the graphene interfaces have been studied by molecular dynamics simulation. The results have shown how the structural and dynamical behaviors of water molecules at the interface reflect the characteristics of these surfaces. The results have demonstrated that residence time and hydrogen bonds' lifetime at the water-Au (100) interface are bigger than at the water-graphene interface. Energy contour map analysis indicates a more uniform surface energy on graphene than on the gold surface. The obtained results illustrate that water clusters on gold and graphene form tetramer and hexamer structures, respectively. Furthermore, the water molecules are more ordered on the gold surface than on graphene. The study of hydrogen bonds showed that the order, stability, and the number of hydrogen bonds is higher on the gold surface. The positioning pattern of water molecules is also similar to the arrangement of gold atoms while no regularity was observed on graphene. The study of dynamical behavior of water molecules revealed that the movement of water on gold is much less than on graphene which is in agreement with the strong water-gold interaction in comparison to the water-graphene interaction.

Facile Fabrication and Characterization of a PDMS-Derived Candle Soot Coated Stable Biocompatible Superhydrophobic and Superhemophobic Surface.

PubMed

Iqbal, R; Majhy, B; Sen, A K

2017-09-13

We report a simple, inexpensive, rapid, and one-step method for the fabrication of a stable and biocompatible superhydrophobic and superhemophobic surface. The proposed surface comprises candle soot particles embedded in a mixture of PDMS+n-hexane serving as the base material. The mechanism responsible for the superhydrophobic behavior of the surface is explained, and the surface is characterized based on its morphology and elemental composition, wetting properties, mechanical and chemical stability, and biocompatibility. The effect of %n-hexane in PDMS, the thickness of the PDMS+n-hexane layer (in terms of spin coating speed) and sooting time on the wetting property of the surface is studied. The proposed surface exhibits nanoscale surface asperities (average roughness of 187 nm), chemical compositions of soot particles, very high water and blood repellency along with excellent mechanical and chemical stability and excellent biocompatibility against blood sample and biological cells. The water contact angle and roll-off angle is measured as 160° ± 1° and 2°, respectively, and the blood contact angle is found to be 154° ± 1°, which indicates that the surface is superhydrophobic and superhemophobic. The proposed superhydrophobic and superhemophobic surface offers significantly improved (>40%) cell viability as compared to glass and PDMS surfaces.

Water at surfaces with tunable surface chemistries

NASA Astrophysics Data System (ADS)

Sanders, Stephanie E.; Vanselous, Heather; Petersen, Poul B.

2018-03-01

Aqueous interfaces are ubiquitous in natural environments, spanning atmospheric, geological, oceanographic, and biological systems, as well as in technical applications, such as fuel cells and membrane filtration. Where liquid water terminates at a surface, an interfacial region is formed, which exhibits distinct properties from the bulk aqueous phase. The unique properties of water are governed by the hydrogen-bonded network. The chemical and physical properties of the surface dictate the boundary conditions of the bulk hydrogen-bonded network and thus the interfacial properties of the water and any molecules in that region. Understanding the properties of interfacial water requires systematically characterizing the structure and dynamics of interfacial water as a function of the surface chemistry. In this review, we focus on the use of experimental surface-specific spectroscopic methods to understand the properties of interfacial water as a function of surface chemistry. Investigations of the air-water interface, as well as efforts in tuning the properties of the air-water interface by adding solutes or surfactants, are briefly discussed. Buried aqueous interfaces can be accessed with careful selection of spectroscopic technique and sample configuration, further expanding the range of chemical environments that can be probed, including solid inorganic materials, polymers, and water immiscible liquids. Solid substrates can be finely tuned by functionalization with self-assembled monolayers, polymers, or biomolecules. These variables provide a platform for systematically tuning the chemical nature of the interface and examining the resulting water structure. Finally, time-resolved methods to probe the dynamics of interfacial water are briefly summarized before discussing the current status and future directions in studying the structure and dynamics of interfacial water.

Effects of farmhouse hotel and paper mill effluents on bacterial community structures in sediment and surface water of Nanxi River, China.

PubMed

Lu, Xiao-Ming; Lu, Peng-Zhen

2014-11-01

The pyrosequencing technique was used to evaluate bacterial community structures in sediment and surface water samples taken from Nanxi River receiving effluents from a paper mill and a farmhouse hotel, respectively. For each sample, 4,610 effective bacterial sequences were selected and used to do the analysis of diversity and abundance, respectively. Bacterial phylotype richness in the sediment sample without effluent input was higher than the other samples, and the surface water sample with addition of effluent from the paper mill contained the least richness. Effluents from both the paper mill and farmhouse hotel have a potential to reduce the bacterial diversity and abundance in the sediment and surface water, especially it is more significant in the sediment. The effect of the paper mill effluent on the sediment and surface water bacterial communities was more serious than that of the farmhouse hotel effluent. Characterization of microbial community structures in the sediment and surface water from two tributaries of the downstream river indicated that various effluents from the paper mill and farmhouse hotel have the similar potential to decrease the natural variability in riverine microbial ecosystems.

Modeling Flow and Pollutant Transport in a Karst Watershed with SWAT

USDA-ARS?s Scientific Manuscript database

Karst hydrology is characterized by multiple springs, sinkholes, and losing streams resulting from acidic water percolating through limestone. These features provide direct connections between surface water and groundwater and increase the risk of groundwater, springs and stream contamination. Anthr...

Characterization of water quality and biological communities, Fish Creek, Teton County, Wyoming, 2007-08

USGS Publications Warehouse

Eddy-Miller, Cheryl A.; Peterson, David A.; Wheeler, Jerrod D.; Leemon, Daniel J.

2010-01-01

Fish Creek, a tributary to the Snake River, is about 25 river kilometers long and is located in Teton County in western Wyoming near the town of Wilson. Public concern about nuisance growths of aquatic plants in Fish Creek have been increasing in recent years. To address this concern, the U.S. Geological Survey conducted a study in cooperation with the Teton Conservation District to characterize the water quality and biological communities in Fish Creek. Water-quality samples were collected for analyses of physical properties and water chemistry (nutrients, nitrate isotopes, and wastewater chemicals) between March 2007 and October 2008 from seven surface-water sites and three groundwater wells. During this same period, aquatic plant and macroinvertebrate samples were collected and habitat characteristics were measured at the surface-water sites. The main objectives of this study were to (1) evaluate nutrient concentrations (that influence biological indicators of eutrophication) and potential sources of nutrients by using stable isotope analysis and other indicator chemicals (such as caffeine and disinfectants) that could provide evidence of anthropogenic sources, such as wastewater or septic tank contamination in Fish Creek and adjacent groundwater, and (2) characterize the algal, macrophyte, and macroinvertebrate communities and habitat of Fish Creek. Nitrate was the dominant species of dissolved nitrogen present in all samples and was the only bioavailable species detected at concentrations greater than the laboratory reporting level in all surface-water samples. Average concentrations of dissolved nitrate in surface water were largest in samples collected from the two sites with seasonal flow near Teton Village and decreased downstream; the smallest concentration was at downstream site A-Wck. Concentrations of dissolved nitrate in groundwater were consistently greater than concentrations in corresponding surface-water sites during the same sampling event. Orthophosphate was the primary dissolved species of phosphorus present in all surface-water and groundwater samples. The average concentration of dissolved orthophosphate in surface water was largest in samples collected from near Teton Village; samples from all other sites had similar average concentrations. Concentrations of dissolved orthophosphate in groundwater also were typically greater than concentrations in corresponding surface-water sites during the same sampling event. The aquatic plant communities in Fish Creek typically were composed of a mixture of macrophytes, macroalgae, microalgae, and moss. The composition of the aquatic plant community in Fish Creek appeared to shift in the downstream direction in 2007. On average, the proportion of macrophytes ranged from about 1 percent at site A-R1U, the most upstream site, to 54 percent of the plant community at site A-R6D, the farthest downstream site sampled during 2007. The downstream increase in macrophytes was accompanied by a downstream decrease in microalgae. The average proportion of microalgae ranged from 80 percent at site A-R1U to 24 percent at site A-R6D. The proportion of the macroalgae Cladophora in the aquatic plant community was relatively high at sites A-Wck and A-R3D in both 2007 and 2008.

Stable superhydrophilic coating on superhydrophobic porous media by functionalized nanoparticles

NASA Astrophysics Data System (ADS)

Khazaei, Masoud; Taghi Sadeghi, Mohammad; Sadat Hosseini, Marzieh

2018-01-01

In this study, the hydrophilicity property of TiO2 nano-coating was improved by zinc acetate-assisted sol-gel method. The stable superhydrophilic coating was fabricated on a superhydrophobic mineral rock surface. The wettability of surface before and after coating was characterized by contact angle measurements. The n-heptane and water droplet contact angle was 0° and 168° respectively, so the untreated rock was superhydrophobic. After nano-treatment, the n-heptane and water contact angle changed to 172° and 0° respectively, so the superhydrophilic coating was formed on the superhydrophobic surface. The thermal, mechanical and salinity stability of the fabricated coatings was investigated. The coatings had high thermal and salinity stability; they also had moderate mechanical stability that was evaluated by abrasion test. The morphology and composition of synthesized nanoparticles were characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy and x-ray diffraction (XRD) analyses. Characterization of the coated surfaces was conducted by SEM and XRD analyses. Applications of these nano-coatings include surfaces where cleanliness is paramount such as in hospitals as well as the protection of public monuments and building facades from weathering. Novel industrial application includes wettability alteration of oil wet carbonate rock for enhanced oil recovery.

Lanthanide-labeled clay: A new method for tracing sediment transport in Karst

USGS Publications Warehouse

Mahler, B.J.; Bennett, P.C.; Zimmerman, M.

1998-01-01

Mobile sediment is a fundamental yet poorly characterized aspect of mass transport through karst aquifers. Here the development and field testing of an extremely sensitive particle tracer that may be used to characterize sediment transport in karst aquifers is described. The tracer consists of micron-size montmorillonite particles homoionized to the lanthanide form; after injection and retrieval from a ground water system, the lanthanide ions are chemically stripped from the clay and quantified by high performance liquid chromatography. The tracer meets the following desired criteria: low detection limit; a number of differentiable signatures; inexpensive production and quantification using standard methods; no environmental risks; and hydrodynamic properties similar to the in situ sediment it is designed to trace. The tracer was tested in laboratory batch experiments and field tested in both surface water and ground water systems. In surface water, arrival times of the tracer were similar to those of a conservative water tracer, although a significant amount of material was lost due to settling. Two tracer tests were undertaken in a karst aquifer under different flow conditions. Under normal flow conditions, the time of arrival and peak concentration of the tracer were similar to or preceded that of a conservative water tracer. Under low flow conditions, the particle tracer was not detected, suggesting that in low flow the sediment settles out of suspension and goes into storage.Mobile sediment is a fundamental yet poorly characterized aspect of mass transport through karst aquifers. Here the development and field testing of an extremely sensitive particle tracer that may be used to characterize sediment transport in karst aquifers is described. The tracer consists of micron-size montmorillonite particles homoionized to the lanthanide form; after injection and retrieval from a ground water system, the lanthanide ions are chemically stripped from the clay and quantified by high performance liquid chromatography. The tracer meets the following desired criteria: low detection limit; a number of differentiable signatures; inexpensive production and quantification using standard methods; no environmental risks; and hydrodynamic properties similar to the in situ sediment it is designed to trace. The tracer was tested in laboratory batch experiments and field tested in both surface water and ground water systems. In surface water, arrival times of the tracer were similar to those of a conservative water tracer, although a significant amount of material was lost due to settling. Two tracer tests were undertaken in a karst aquifer under different flow conditions. Under normal flow conditions, the time of arrival and peak concentration of the tracer were similar to or preceded that of a conservative water tracer. Under low flow conditions, the particle tracer was not detected, suggesting that in low flow the sediment settles out of suspension and goes into storage.

Potentiometric Surface of the Ozark Aquifer in Northern Arkansas, 2007

USGS Publications Warehouse

Pugh, Aaron L.

2008-01-01

The Ozark aquifer in northern Arkansas is composed of dolomite, limestone, sandstone, and shale of Late Cambrian to Middle Devonian age, and ranges in thickness from approximately 1,100 feet to more than 4,000 feet. Hydrologically, the aquifer is complex, characterized by discrete and discontinuous flow components with large variations in permeability. The potentiometric-surface map, based on 58 well and 5 spring water-level measurements collected in 2007 in Arkansas and Missouri, has a maximum water-level altitude measurement of 1,169 feet in Carroll County and a minimum water-level altitude measurement of 118 feet in Randolph County. Regionally, the flow within the aquifer is to the south and southeast in the eastern and central part of the study area and to the west, northwest, and north in the western part of the study area. Comparing the 2007 potentiometric-surface map with a predevelopment potentiometric-surface map indicates general agreement between the two surfaces except in the northwestern part of the study area. Potentiometric-surface differences can be attributed to withdrawals related to increasing population, changes in public-supply sources, processes or water withdrawals outside the study area, or differences in data-collection or map-construction methods. The rapidly increasing population within the study area appears to have some effect on ground-water levels. Although, the effect appears to have been minimized by the development and use of surface-water distribution infrastructure, suggesting most of the incoming populations are fulfilling their water needs from surface-water sources. The conversion of some users from ground water to surface water may be allowing water levels in wells to recover (rise) or decline at a slower rate, such as in Benton, Carroll, and Washington Counties.

A Methodology to Assess the Accuracy with which Remote Data Characterize a Specific Surface, as a Function of Full Width at Half Maximum (FWHM): Application to Three Italian Coastal Waters

PubMed Central

Cavalli, Rosa Maria; Betti, Mattia; Campanelli, Alessandra; Di Cicco, Annalisa; Guglietta, Daniela; Penna, Pierluigi; Piermattei, Viviana

2014-01-01

This methodology assesses the accuracy with which remote data characterizes a surface, as a function of Full Width at Half Maximum (FWHM). The purpose is to identify the best remote data that improves the characterization of a surface, evaluating the number of bands in the spectral range. The first step creates an accurate dataset of remote simulated data, using in situ hyperspectral reflectances. The second step evaluates the capability of remote simulated data to characterize this surface. The spectral similarity measurements, which are obtained using classifiers, provide this capability. The third step examines the precision of this capability. The assumption is that in situ hyperspectral reflectances are considered the “real” reflectances. They are resized with the same spectral range of the remote data. The spectral similarity measurements which are obtained from “real” resized reflectances, are considered “real” measurements. Therefore, the quantity and magnitude of “errors” (i.e., differences between spectral similarity measurements obtained from “real” resized reflectances and from remote data) provide the accuracy as a function of FWHM. This methodology was applied to evaluate the accuracy with which CHRIS-mode1, CHRIS-mode2, Landsat5-TM, MIVIS and PRISMA data characterize three coastal waters. Their mean values of uncertainty are 1.59%, 3.79%, 7.75%, 3.15% and 1.18%, respectively. PMID:24434875

Field Techniques for Estimating Water Fluxes Between Surface Water and Ground Water

USGS Publications Warehouse

Rosenberry, Donald O.; LaBaugh, James W.

2008-01-01

This report focuses on measuring the flow of water across the interface between surface water and ground water, rather than the hydrogeological or geochemical processes that occur at or near this interface. The methods, however, that use hydrogeological and geochemical evidence to quantify water fluxes are described herein. This material is presented as a guide for those who have to examine the interaction of surface water and ground water. The intent here is that both the overview of the many available methods and the in-depth presentation of specific methods will enable the reader to choose those study approaches that will best meet the requirements of the environments and processes they are investigating, as well as to recognize the merits of using more than one approach. This report is designed to make the reader aware of the breadth of approaches available for the study of the exchange between surface and ground water. To accomplish this, the report is divided into four chapters. Chapter 1 describes many well-documented approaches for defining the flow between surface and ground waters. Subsequent chapters provide an in-depth presentation of particular methods. Chapter 2 focuses on three of the most commonly used methods to either calculate or directly measure flow of water between surface-water bodies and the ground-water domain: (1) measurement of water levels in well networks in combination with measurement of water level in nearby surface water to determine water-level gradients and flow; (2) use of portable piezometers (wells) or hydraulic potentiomanometers to measure hydraulic gradients; and (3) use of seepage meters to measure flow directly. Chapter 3 focuses on describing the techniques involved in conducting water-tracer tests using fluorescent dyes, a method commonly used in the hydrogeologic investigation and characterization of karst aquifers, and in the study of water fluxes in karst terranes. Chapter 4 focuses on heat as a tracer in hydrological investigations of the near-surface environment.

Preparation and characterization of soy protein films with a durable water resistance-adjustable and antimicrobial surface.

PubMed

Li, Shuzhao; Donner, Elizabeth; Xiao, Huining; Thompson, Michael; Zhang, Yachuan; Rempel, Curtis; Liu, Qiang

2016-12-01

A water resistant surface was first obtained by immobilizing hydrophobic copolymers, poly (styrene-co-glycidyl methacrylate) (PSG), with functional groups on soy protein isolate (SPI) films. XPS and AFM results showed that PSG copolymers were immobilized on the film by chemical bonding, and formed a rough surface with some bumps because of the segregation of two different phases on PSG copolymers. Water resistance of the modified films could be adjusted dramatically by further immobilizing different amounts of guanidine-based antimicrobial polymers, poly (hexamethylene guanidine hydrochloride) (PHMG) on the resulting hydrophobic surface. The introduction of hydrophilic PHMG on the resulting surface generated many micropores, which potentially increased the water uptake of the modified films. Furthermore, the modified SPI films showed higher thermostability compared to native SPI film and broad-spectrum antimicrobial activity by contact killing, attributed to the presence of PHMG on the surface. The modified SPI film with a multi-functional surface showed potential for applications in the packaging and medical fields. Crown Copyright © 2016. Published by Elsevier B.V. All rights reserved.

Hydrogen-Bonding Surfaces for Ice Mitigation

NASA Technical Reports Server (NTRS)

Smith, Joseph G., Jr.; Wohl, Christopher J.; Kreeger, Richard E.; Hadley, Kevin R.; McDougall, Nicholas

2014-01-01

Ice formation on aircraft, either on the ground or in-flight, is a major safety issue. While ground icing events occur predominantly during the winter months, in-flight icing can happen anytime during the year. The latter is more problematic since it could result in increased drag and loss of lift. Under a Phase I ARMD NARI Seedling Activity, coated aluminum surfaces possessing hydrogen-bonding groups were under investigation for mitigating ice formation. Hydroxyl and methyl terminated dimethylethoxysilanes were prepared via known chemistries and characterized by spectroscopic methods. These materials were subsequently used to coat aluminum surfaces. Surface compositions were based on pure hydroxyl and methyl terminated species as well as mixtures of the two. Coated surfaces were characterized by contact angle goniometry. Receding water contact angle data suggested several potential surfaces that may exhibit reduced ice adhesion. Qualitative icing experiments performed under representative environmental temperatures using supercooled distilled water delivered via spray coating were inconclusive. Molecular modeling studies suggested that chain mobility affected the interface between ice and the surface more than terminal group chemical composition. Chain mobility resulted from the creation of "pockets" of increased free volume for longer chains to occupy.

Evaluation of methods to sample fecal indicator bacteria in foreshore sand and pore water at freshwater beaches.

PubMed

Vogel, Laura J; Edge, Thomas A; O'Carroll, Denis M; Solo-Gabriele, Helena M; Kushnir, Caitlin S E; Robinson, Clare E

2017-09-15

Fecal indicator bacteria (FIB) are known to accumulate in foreshore beach sand and pore water (referred to as foreshore reservoir) where they act as a non-point source for contaminating adjacent surface waters. While guidelines exist for sampling surface waters at recreational beaches, there is no widely-accepted method to collect sand/sediment or pore water samples for FIB enumeration. The effect of different sampling strategies in quantifying the abundance of FIB in the foreshore reservoir is unclear. Sampling was conducted at six freshwater beaches with different sand types to evaluate sampling methods for characterizing the abundance of E. coli in the foreshore reservoir as well as the partitioning of E. coli between different components in the foreshore reservoir (pore water, saturated sand, unsaturated sand). Methods were evaluated for collection of pore water (drive point, shovel, and careful excavation), unsaturated sand (top 1 cm, top 5 cm), and saturated sand (sediment core, shovel, and careful excavation). Ankle-depth surface water samples were also collected for comparison. Pore water sampled with a shovel resulted in the highest observed E. coli concentrations (only statistically significant at fine sand beaches) and lowest variability compared to other sampling methods. Collection of the top 1 cm of unsaturated sand resulted in higher and more variable concentrations than the top 5 cm of sand. There were no statistical differences in E. coli concentrations when using different methods to sample the saturated sand. Overall, the unsaturated sand had the highest amount of E. coli when compared to saturated sand and pore water (considered on a bulk volumetric basis). The findings presented will help determine the appropriate sampling strategy for characterizing FIB abundance in the foreshore reservoir as a means of predicting its potential impact on nearshore surface water quality and public health risk. Copyright © 2017 Elsevier Ltd. All rights reserved.

Evolution of a Man-Made Plume in Coastal Waters

DOE Office of Scientific and Technical Information (OSTI.GOV)

Steinmaus, Karen L.; Bowles, Jeff; Woodruff, Dana L.

2006-12-19

The ability to understand the biogeophysical parameters that create ocean color in coastal waters is fundamental to the ability to exploit remote sensing for coastal applications. This article describes an experiment in which a controlled quantity of a single inorganic material with known absorption and scattering properties was released into a coastal environment. The plume experiment was conducted in conjunction with a Pacific Northwest National Laboratory (PNNL) field collection campaign in and around Sequim Bay on the Strait of Juan de Fuca in Washington State. The objective of the field campaign was to identify and characterize features in the nearmore » shore environment from the standpoint of quantifying environmental parameters to improve operational planning in littoral regions. The aerial component of the mission involved imagery acquisitions from the NRL's PHILLS hyperspectral sensor, and two commercial IR cameras. Coincident satellite data was obtained from commercial sources. Ground truth activities included atmospheric profiles, ground, surface water, and in-water spectral measurements, panels for radiometric calibration, water column water optics, water samples and profiles from support vessels, in-situ tide and weather measurements, and beach and intertidal transects and surveys (via scientific dive teams). This field collection campaign provided a unique opportunity for a multisensor data collection effort in littoral regions, to identify and characterize features from multiple platforms (satellite, aerial, water surface and subsurface) and sensors. Data from this mission is being used as input to both radiative transfer and ocean transport models, for characterizing the water column and the near-shore, and quantitatively estimating circulation and transport in coastal environments.« less

Physicochemical Study of Viral Nanoparticles at the Air/Water Interface.

PubMed

Torres-Salgado, Jose F; Comas-Garcia, Mauricio; Villagrana-Escareño, Maria V; Durán-Meza, Ana L; Ruiz-García, Jaime; Cadena-Nava, Ruben D

2016-07-07

The assembly of most single-stranded RNA (ssRNA) viruses into icosahedral nucleocapsids is a spontaneous process driven by protein-protein and RNA-protein interactions. The precise nature of these interactions results in the assembly of extremely monodisperse and structurally indistinguishable nucleocapsids. In this work, by using a ssRNA plant virus (cowpea chlorotic mottle virus [CCMV]) as a charged nanoparticle we show that the diffusion of these nanoparticles from the bulk solution to the air/water interface is an irreversible adsorption process. By using the Langmuir technique, we measured the diffusion and adsorption of viral nucleocapsids at the air/water interface at different pH conditions. The pH changes, and therefore in the net surface charge of the virions, have a great influence in the diffusion rate from the bulk solution to the air/water interface. Moreover, assembly of mesoscopic and microscopic viral aggregates at this interface depends on the net surface charge of the virions and the surface pressure. By using Brewster's angle microscopy we characterized these structures at the interface. Most common structures observed were clusters of virions and soap-frothlike micron-size structures. Furthermore, the CCMV films were compressed to form monolayers and multilayers from moderate to high surface pressures, respectively. After transferring the films from the air/water interface onto mica by using the Langmuir-Blodgett technique, their morphology was characterized by atomic force microscopy. These viral monolayers showed closed-packing nano- and microscopic arrangements.

Application of 2D electrical resistivity imaging and cone penetration test (CPT) to assess the harzadous effect of near surface water on foundations in Lagos Nigeria

NASA Astrophysics Data System (ADS)

Adewoyin, O. O.; Joshua, E. O.; Akinyemi, M. L.; Omeje, M.; Joel, E. S.

2017-05-01

Adequate information on the condition of the subsurface is very important for site evaluation for engineering purposes. In this study two dimensional (2D) geoelectrical resistivity survey and cone penetration tests were conducted to study the hazardous effect of excess near surface water on the foundation of building in a reclaimed land located at Victoria Island area of Lagos State. The results of the inverted 2D geoelectrical resistivity data revealed three distinct geoelectrical layers characterized by low to moderate electrical resistivity of 2.23 and 129Ωm and 9.46 to 636Ωm respectively. The topsoil is characterized by wet sandy soil, which is underlain by sandy clay and banded at the below by a geologic formation of low resistivity which is suspected to be clay. The clay material may be responsible for the excess water retention observed in the area. The CPT method on the other hand revealed a geological formation of low resistance to penetration between 2-3 kg/cm2 from the topsoil to a depth of 7 m, which may be the effect of excess water in the near surface. This study revealed that the foundation of building may not be founded directly on the soil in any reclaimed land as this may result in collapse as a result of upward migration of water to the near surface.

Spatial distribution of perchlorate, iodide and thiocyanate in the aquatic environment of Tianjin, China: environmental source analysis.

PubMed

Qin, Xiaolei; Zhang, Tao; Gan, Zhiwei; Sun, Hongwen

2014-09-01

Although China is the largest producer of fireworks (perchlorate-containing products) in the world, the pathways through which perchlorate enters the environment have not been characterized completely in this country. In this study, perchlorate, iodide and thiocyanate were measured in 101 water samples, including waste water, surface water, sea water and paired samples of rain water and surface runoff collected in Tianjin, China. The concentrations of the target anions were generally on the order of rain>surface water≈waste water treatment plant (WWTP) influent>WWTP effluent. High concentrations of perchlorate, iodide and thiocyanate were detected in rain samples, ranging from 0.35 to 27.3 (median: 4.05), 0.51 to 8.33 (2.92), and 1.31 to 107 (5.62) ngmL(-)(1), respectively. Furthermore, the concentrations of the target anions in rain samples were significantly (r=0.596-0.750, p<0.01) positively correlated with the concentrations obtained in the paired surface runoff samples. The anions tested showed a clear spatial distribution, and higher concentrations were observed in the upper reaches of rivers, sea waters near the coast, and rain-surface runoff pairs sampled in urban areas. Our results revealed that precipitation may act as an important source of perchlorate, iodide and thiocyanate in surface water. Moreover, iodide concentrations in the Haihe River and Dagu Drainage Canal showed a good correlation with an ideal marker (acesulfame) of domestic waste water, indicating that input from domestic waste water was an important source of iodide in the surface waters of Tianjin. Copyright © 2014 Elsevier Ltd. All rights reserved.

Spatial characterization of long-term hydrological change in the Arkavathy watershed adjacent to Bangalore, India

NASA Astrophysics Data System (ADS)

Penny, Gopal; Srinivasan, Veena; Dronova, Iryna; Lele, Sharachchandra; Thompson, Sally

2018-01-01

The complexity and heterogeneity of human water use over large spatial areas and decadal timescales can impede the understanding of hydrological change, particularly in regions with sparse monitoring of the water cycle. In the Arkavathy watershed in southern India, surface water inflows to major reservoirs decreased over a 40-year period during which urbanization, groundwater depletion, modification of the river network, and changes in agricultural practices also occurred. These multiple, interacting drivers combined with limited hydrological monitoring make attribution of the causes of diminishing water resources in the watershed challenging and impede effective policy responses. To mitigate these challenges, we developed a novel, spatially distributed dataset to understand hydrological change by characterizing the residual trends in surface water extent that remain after controlling for precipitation variations and comparing the trends with historical land use maps to assess human drivers of change. Using an automated classification approach with subpixel unmixing, we classified water extent in nearly 1700 man-made lakes, or tanks, in Landsat images from 1973 to 2010. The classification results compared well with a reference dataset of water extent of tanks (R2 = 0.95). We modeled the water extent of 42 clusters of tanks in a multiple regression on simple hydrological covariates (including precipitation) and time. Inter-annual variability in precipitation accounted for 63 % of the predicted variability in water extent. However, precipitation did not exhibit statistically significant trends in any part of the watershed. After controlling for precipitation variability, we found statistically significant temporal trends in water extent, both positive and negative, in 13 of the clusters. Based on a water balance argument, we inferred that these trends likely reflect a non-stationary relationship between precipitation and watershed runoff. Independently of precipitation, water extent increased in a region downstream of Bangalore, likely due to increased urban effluents, and declined in the northern portion of the Arkavathy. Comparison of the drying trends with land use indicated that they were most strongly associated with irrigated agriculture, sourced almost exclusively by groundwater. This suggests that groundwater abstraction was a major driver of hydrological change in this watershed. Disaggregating the watershed-scale hydrological response via remote sensing of surface water bodies over multiple decades yielded a spatially resolved characterization of hydrological change in an otherwise poorly monitored watershed. This approach presents an opportunity to understand hydrological change in heavily managed watersheds where surface water bodies integrate upstream runoff and can be delineated using satellite imagery.

Bacterial community diversity and variation in spray water sources and the tomato fruit surface

PubMed Central

2011-01-01

Background Tomato (Solanum lycopersicum) consumption has been one of the most common causes of produce-associated salmonellosis in the United States. Contamination may originate from animal waste, insects, soil or water. Current guidelines for fresh tomato production recommend the use of potable water for applications coming in direct contact with the fruit, but due to high demand, water from other sources is frequently used. We sought to describe the overall bacterial diversity on the surface of tomato fruit and the effect of two different water sources (ground and surface water) when used for direct crop applications by generating a 454-pyrosequencing 16S rRNA dataset of these different environments. This study represents the first in depth characterization of bacterial communities in the tomato fruit surface and the water sources commonly used in commercial vegetable production. Results The two water sources tested had a significantly different bacterial composition. Proteobacteria was predominant in groundwater samples, whereas in the significantly more diverse surface water, abundant phyla also included Firmicutes, Actinobacteria and Verrucomicrobia. The fruit surface bacterial communities on tomatoes sprayed with both water sources could not be differentiated using various statistical methods. Both fruit surface environments had a high representation of Gammaproteobacteria, and within this class the genera Pantoea and Enterobacter were the most abundant. Conclusions Despite the major differences observed in the bacterial composition of ground and surface water, the season long use of these very different water sources did not have a significant impact on the bacterial composition of the tomato fruit surface. This study has provided the first next-generation sequencing database describing the bacterial communities living in the fruit surface of a tomato crop under two different spray water regimes, and therefore represents an important step forward towards the development of science-based metrics for Good Agricultural Practices. PMID:21510867

Spatially variable stage-driven groundwater-surface water interaction inferred from time-frequency analysis of distributed temperature sensing data

USGS Publications Warehouse

Mwakanyamale, Kisa; Slater, Lee; Day-Lewis, Frederick D.; Elwaseif, Mehrez; Johnson, Carole D.

2012-01-01

Characterization of groundwater-surface water exchange is essential for improving understanding of contaminant transport between aquifers and rivers. Fiber-optic distributed temperature sensing (FODTS) provides rich spatiotemporal datasets for quantitative and qualitative analysis of groundwater-surface water exchange. We demonstrate how time-frequency analysis of FODTS and synchronous river stage time series from the Columbia River adjacent to the Hanford 300-Area, Richland, Washington, provides spatial information on the strength of stage-driven exchange of uranium contaminated groundwater in response to subsurface heterogeneity. Although used in previous studies, the stage-temperature correlation coefficient proved an unreliable indicator of the stage-driven forcing on groundwater discharge in the presence of other factors influencing river water temperature. In contrast, S-transform analysis of the stage and FODTS data definitively identifies the spatial distribution of discharge zones and provided information on the dominant forcing periods (≥2 d) of the complex dam operations driving stage fluctuations and hence groundwater-surface water exchange at the 300-Area.

Environmental impact of leachate characteristics on water quality.

PubMed

Cumar, Sampath Kumar Mandyam; Nagaraja, Balasubramanya

2011-07-01

Improper urbanization and industrialization are causing a critical stress on groundwater quality in urban areas of the developing countries. The present study under investigation describes the pollution caused by leachate from a waste management site in southwestern Bangalore city causing pollution of the surface water and groundwater reserves. The characterization of 20 groundwater samples and Haralukunte lake sample indicated high pollution of these water reserves by leachate entry into the groundwater and surface water sources. The study area focuses around the solid waste management site, carrying out bio-composting and vermi-composting of municipal solid waste. Further investigations on the severe health problems faced by the public in the study area has revealed a clear pointer towards the usage of polluted water for rearing live-stock, farming, and domestic activities. The characterization of the leachate with high values of BOD at 1,450 mg/l, TDS at 17,200 mg/l, nitrates at 240 mg/l, and MPN at 545/100 ml indicates a clear nuisance potential, which has been substantiated by the characterization of lake water sample with chlorides at 3,400 mg/l, TDS at 8,020 mg/l, and lead and cadmium at 0.18 and 0.08 mg/l, respectively. Analysis of groundwater samples shows alarming physicochemical values closer to the waste disposal site and relatively reduced values away from the source of the waste management site. Bureau of Indian Standards have been adapted as the benchmark for the analysis and validation of observed water quality criteria.

Full 2D observation of water surface elevation from SWOT under different flow conditions

NASA Astrophysics Data System (ADS)

Domeneghetti, Alessio; Schumann, Guy; Rui, Wei; Durand, Michael; Pavelsky, Tamlin

2016-04-01

The upcoming Surface Water and Ocean Topography (SWOT) satellite mission is a joint project of NASA, Centre National d'Etudes Spatiales (CNES, France), the Canadian Space Agency, and the Space Agency of the UK that will provide a first global, high-resolution observation of ocean and terrestrial water surface heights. Characterized by an observation swath of 120 km and an orbit repeat interval of about 21 days, SWOT will provide unprecedented bi-dimensional observations of rivers wider than 50-100 m. Despite many research activities that have investigated potential uses of remotely sensed data from SWOT, potentials and limitations of the spatial observations provided by the satellite mission for flood modeling still remain poorly understood and investigated. In this study we present a first analysis of the spatial observation of water surface elevation that is expected from SWOT for a 140 km reach of the middle-lower portion of the Po River, in Northern Italy. The river stretch is characterized by a main channel varying from 200-500 m in width and a floodplain that can be as wide as 5 km and that is delimited by a system of major embankments. The reconstruction of the hydraulic behavior of the Po River is performed by means of a quasi-2d model built with detailed topographic and bathymetric information (LiDAR, 2 m resolution), while the simulation of the spatial observation sensed by SWOT is performed with a SWOT simulator that mimics the satellite sensor characteristics. Referring to water surface elevations associated with different flow conditions (maximum, minimum and average flow reproduced by means of the quasi-2d numerical model) this work provides a first characterization of the spatial observations provided by SWOT and highlights the strengths and limitations of the expected products. By referring to a real river reach the analysis provides a credible example of the type of spatial observations that will be available after launch of SWOT and offers a first evaluation of the possible effects of river embankments, river width and river topography under different hydraulic conditions. Results of the study characterize the expected accuracy of the upcoming SWOT mission and provide additional insights towards more appropriate exploitation of future potential hydrologic data.

Surface hydrophobic modification of polyurethanes by diaryl carbene chemistry: Synthesis and characterization

NASA Astrophysics Data System (ADS)

Yang, Pengfei; Wang, Yongqing; Lu, Ling; Yu, Xi; Liu, Lian

2018-03-01

Dodecyl diaryl diazomethane was firstly synthesized from 4,4-dihydroxybenzophenone and 1-bromododecane by a series of reaction steps. Then water-borne polyurethane films with different amount of DMPA were prepared, as well as a type of solvent-borne polyurethane film for comparison. Finally, all these polyurethane films were modified by dodecyl diaryl diazomethane. The dodecyl diaryl carbene was generated from dodecyl diaryl diazomethane by strong solar light, which was very convenient to insert into the Xsbnd H bonds (X = C, N) on the surface of polyurethane films. The contact angle test was used to characterize these films and depict the surface property. DSC analysis and tensile test were used to investigate the physical properties of polyurethane films before and after modification. It was suggested that the hydrophobic modification protocol with carbene insertion was very useful and convenient to prepare water-proof coatings outdoors under direct solar-light exposure.

Characterizing the potential energy surface of the water dimer with DFT: failures of some popular functionals for hydrogen bonding.

PubMed

Anderson, Julie A; Tschumper, Gregory S

2006-06-08

Ten stationary points on the water dimer potential energy surface have been examined with ten density functional methods (X3LYP, B3LYP, B971, B98, MPWLYP, PBE1PBE, PBE, MPW1K, B3P86, and BHandHLYP). Geometry optimizations and vibrational frequency calculations were carried out with the TZ2P(f,d)+dif basis set. All ten of the density functionals correctly describe the relative energies of the ten stationary points. However, correctly describing the curvature of the potential energy surface is far more difficult. Only one functional (BHandHLYP) reproduces the number of imaginary frequencies from CCSD(T) calculations. The other nine density functionals fail to correctly characterize the nature of at least one of the ten (H(2)O)(2) stationary points studied here.

In vitro degradation and release characteristics of spin coated thin films of PLGA with a “breath figure” morphology

PubMed Central

Ponnusamy, Thiruselvam; Lawson, Louise B.; Freytag, Lucy C.; Blake, Diane A.; Ayyala, Ramesh S.; John, Vijay T.

2012-01-01

Poly (lactic-co-glycolic acid) (PLGA) coatings on implant materials are widely used in controlled drug delivery applications. Typically, such coatings are made with non-porous films. Here, we have synthesized a thin PLGA film coating with a highly ordered microporous structure using a simple and inexpensive water templating “breath figure” technique. A single stage process combining spin coating and breath figure process was used to obtain drug incorporated porous thin films. The films were characterized by scanning electron microscope (SEM) to observe the surface and bulk features of porosity and also, degradation pattern of the films. Moreover, the effect of addition of small amount of poly (ethylene glycol) (PEG) into PLGA was characterized. SEM analysis revealed an ordered array of ~2 µm sized pores on the surface with the average film thickness measured to be 20 µm. The incorporation of hydrophilic poly (ethylene glycol) (PEG) enhances pore structure uniformity and facilitates ingress of water into the structure. A five week in vitro degradation study showed a gradual deterioration of the breath figure pores. During the course of degradation, the surface pore structure deteriorates to initially flatten the surface. This is followed by the formation of new pinprick pores that eventually grow into a macroporous film prior to film breakup. Salicylic acid (highly water soluble) and Ibuprofen (sparingly water soluble) were chosen as model drug compounds to characterize release rates, which are higher in films of the breath figure morphology rather than in non-porous films. The results are of significance in the design of biodegradable films used as coatings to modulate delivery. PMID:23507805

Altered Landscapes and Groundwater Sustainability — Exploring Impacts with Induced Polarization, DC Resistivity, and Thermal Tracing

NASA Astrophysics Data System (ADS)

Eddy-Miller, C.; Caldwell, R.; Wheeler, J.; McCarthy, P.; Binley, A. M.; Constantz, J. E.; Stonestrom, D. A.

2009-12-01

Anthropogenically impacted landscapes constitute rising proportions of the Earth’s surface that are characterized by generally elevated nutrient and sediment loadings concurrent with increased consumptive water withdrawals. In recent years a growing number of hydraulically engineered riparian habitat restoration projects have attempted to ameliorate negative impacts of land use on groundwater-surface water systems resulting, e.g., from agricultural practices and urban development. Often the nature of groundwater-surface water interactions in pre- and minimally altered systems is poorly known, making it difficult to assess the impacts of land use and restoration projects on groundwater sustainability. Traditional assessments of surface water parameters (flow, temperature, dissolved oxygen, biotic composition, etc.) can be complemented by hydraulic and thermal measurements to better understand the important role played by groundwater-surface water interactions. Hydraulic and thermal measurements are usually limited to point samples, however, making non-invasive and spatially extensive geophysical characterizations an attractive additional tool. Groundwater-surface water interactions along the Smith River, a tributary to the Missouri River in Montana, and Fish Creek and Flat Creek, tributaries to the Snake River in Wyoming, are being examined using a combination of hydraulic measurements, thermal tracing, and electrical-property imaging. Ninety-two direct-current (DC) resistivity and induced polarization cross sections were obtained at stream transects covering a wide variety of hydrogeologic settings ranging from shallow bedrock to thick alluvial sequences, nature of groundwater-surface water interactions (always gaining, always losing, or seasonally varying) and anthropogenic impacts (minimal low-intensity agriculture to major landscape engineering, including channel reconstruction). DC resistivity and induced polarization delineated mutually distinct features related to hydraulic architecture. For example, induced polarization imaging resolved channel-edge muck deposits that are presumed to be sites of low hydraulic conductivity, chemical reduction, and metal accumulation. DC resistivity delineated bedrock-alluvium contacts and showed potential for tracking changes in salinization. While electrical properties cannot substitute for hydraulic and thermal data, the addition of relatively rapidly acquired, spatially extensive resistivity and induced polarization imaging offers synergistic opportunities for interpretive hydrologic investigations.

Chemistry of water collected from an unventilated drift, Yucca Mountain, Nevada

USGS Publications Warehouse

Marshall, B.D.; Oliver, T.A.; Peterman, Z.E.

2007-01-01

Water samples (referred to as puddle water samples) were collected from the surfaces of a conveyor belt and plastic sheeting in the unventilated portion of the Enhanced Characterization of the Repository Block (ECRB) Cross Drift in 2003 and 2005 at Yucca Mountain, Nevada. The chemistry of these puddle water samples is very different than that of pore water samples from borehole cores in the same region of the Cross Drift or than seepage water samples collected from the Exploratory Studies Facility tunnel in 2005. The origin of the puddle water is condensation on surfaces of introduced materials and its chemistry is dominated by components of the introduced materials. Large CO2 concentrations may be indicative of localized chemical conditions induced by biologic activity. ?? 2007 Materials Research Society.

Engineering tunable bio-inspired polymeric coatings for amphiphobic fibrous materials

NASA Astrophysics Data System (ADS)

Oyola-Reynoso, Stephanie

Chemical grafting has been widely used to modify the surface properties of materials, especially surface energy for controlled wetting, because of the resilience of such coatings/modifications. Reagents with multiple reactive sites have been used with the expectation that a monolayer will form. The step-growth polymerization mechanism, however, suggests the possibility of gel formation for hydrolysable moieties in the presence of physisorbed water. In the following chapters, we demonstrate that using alkyltrichlorosilanes (trivalent [3 reactive sites]) in the surface modification of a cellulosic material (paper) does not yield a monolayer but rather gives surface-bound polymeric particles. We infer that the presence of physisorbed (surface-bound) water allows for polymerization (or oligomerization) of the silane, prior to its attachment on the surface. Surface energy mismatch between the hydrophobic tails of the growing polymer and any unreacted bound water leads to the assembly of the polymerizing material into spherical particles to minimize surface tension. By varying paper grammage (16.2-201.4 g/m2), we varied the accessible surface area and thus the amount of surface-adsorbed water, allowing us to control the ratio of the silane to the bound water. Using this approach, polymeric particles were formed on the surface of cellulose fibers ranging from 70 nm to a film. The hydrophobicity of the surface, as determined by water contact angles, correlates with particle sizes (p < 0.001, Student t-test), and, hence, the hydrophobicity can be tuned (contact angle between 94° and 149°). Using a model structure of a house, we demonstrated that as a result of this modification, cardboard houses can be rendered self-cleaning or tolerant to surface running water. Each of the chapters below supports the mechanism via a series of applications, material characterization, and/or, smart engineering.

Estimating changes in heat energy stored within a column of wetland surface water and factors controlling their importance in the surface energy budget

USGS Publications Warehouse

Shoemaker, W. Barclay; Sumner, David M.; Castillo, Adrian

2005-01-01

Changes in heat energy stored within a column of wetland surface water can be a considerable component of the surface energy budget, an attribute that is demonstrated by comparing changes in stored heat energy to net radiation at seven sites in the wetland areas of southern Florida, including the Everglades. The magnitude of changes in stored heat energy approached the magnitude of net radiation more often during the winter dry season than during the summer wet season. Furthermore, the magnitude of changes in stored heat energy in wetland surface water generally decreased as surface energy budgets were upscaled temporally. A new method was developed to estimate changes in stored heat energy that overcomes an important data limitation, namely, the limited spatial and temporal availability of water temperature measurements. The new method is instead based on readily available air temperature measurements and relies on the convolution of air temperature changes with a regression‐defined transfer function to estimate changes in water temperature. The convolution‐computed water temperature changes are used with water depths and heat capacity to estimate changes in stored heat energy within the Everglades wetland areas. These results likely can be adapted to other humid subtropical wetlands characterized by open water, saw grass, and rush vegetation type communities.

Concentration data for anthropogenic organic compounds in ground water, surface water, and finished water of selected community water systems in the United States, 2002-05

USGS Publications Warehouse

Carter, Janet M.; Delzer, Gregory C.; Kingsbury, James A.; Hopple, Jessica A.

2007-01-01

The National Water-Quality Assessment Program of the U.S. Geological Survey began implementing Source Water-Quality Assessments (SWQAs) in 2001 that focus on characterizing the quality of source water and finished water of aquifers and major rivers used by some of the larger community water systems (CWSs) in the United States. As used for SWQA studies, source water is the raw (ambient) water collected at the supply well prior to water treatment (for ground water) or the raw (ambient) water collected from the river near the intake (for surface water), and finished water is the water that is treated and ready to be delivered to consumers. Finished water is collected before entering the distribution system. SWQA studies are conducted in two phases, and the objectives of SWQA studies are twofold: (1) to determine the occurrence and, for rivers, seasonal changes in concentrations of a broad list of anthropogenic organic compounds (AOCs) in aquifers and rivers that have some of the largest withdrawals for drinking-water supply (phase 1), and (2) for those AOCs found to occur most frequently in source water, characterize the extent to which these compounds are present in finished water (phase 2). These objectives were met for SWQA studies by collecting ground-water and surface-water (source) samples and analyzing these samples for 258 AOCs during phase 1. Samples from a subset of wells and surface-water sites located in areas with substantial agricultural production in the watershed were analyzed for 19 additional AOCs, for a total of 277 compounds analyzed for SWQA studies. The 277 compounds were classified according to the following 13 primary use or source groups: (1) disinfection by-products; (2) fumigant-related compounds; (3) fungicides; (4) gasoline hydrocarbons, oxygenates, and oxygenate degradates; (5) herbicides and herbicide degradates; (6) insecticides and insecticide degradates; (7) manufacturing additives; (8) organic synthesis compounds; (9) pavement- and combustion-derived compounds; (10) personal care and domestic use products; (11) plant- or animal-derived biochemicals; (12) refrigerants and propellants; and (13) solvents. Source and finished water samples were collected during phase 2 and analyzed for constituents that were detected frequently during phase 1. This report presents concentration data for AOCs in ground water, surface water, and finished water of CWSs sampled for SWQA studies during 2002-05. Specifically, this report presents the analytical results of samples collected during phase 1 including (1) samples from 221 wells that were analyzed for 258 AOCs; (2) monthly samples from 9 surface-water sites that were analyzed for 258 AOCs during phase 1; and (3) samples from a subset of the wells and surface-water sites located in areas with substantial agricultural production that were analyzed for 3 additional pesticides and 16 pesticide degradates. Samples collected during phase 2 were analyzed for selected AOCs that were detected most frequently in source water during phase 1 sampling; analytical results for phase 2 are presented for (1) samples of source water and finished water from 94 wells; and (2) samples of source water and finished water samples that were collected monthly and during selected flow conditions at 8 surface-water sites. Results of quality-assurance/quality-control samples collected for SWQA studies during 2002-05 also are presented.

Methods for LWIR Radiometric Calibration and Characterization

NASA Technical Reports Server (NTRS)

Ryan, Robert; Pagnutti, Mary; Zanoni, Vicki; Harrington, Gary; Howell, Dane; Stewart, Randy

2002-01-01

The utility of a thermal remote sensing system increases with it's ability to retrieve surface temperature or radiance accurately. The radiometer measures the water surface radiant temperature. Combining these measurements with atmospheric pressure, temperature, and water vapor profiles, a top-of-the-atmosphere tradiance estimate can be caluclated with a radiativer transfer code to compare to trhe sensor's output. A novel approach has been developed using an uncooled infrared camera mounted on a boom, to quantify buoy effects.

Novel nanocomposite Kevlar fabric membranes: Fabrication characterization, and performance in oil/water separation

NASA Astrophysics Data System (ADS)

Karimnezhad, Hanieh; Rajabi, Laleh; Salehi, Ehsan; Derakhshan, Ali Ashraf; Azimi, Sara

2014-02-01

Nanocomposite membranes with hydrophilic surface were fabricated for separation of oil (n-hexane) from oil/water emulsion. Three different nanomaterials namely, para-aminobenzoate alumoxane (PAB-A), boehmite-epoxide and polycitrate alumoxane (PC-A) were coated on the Kevlar fabric (support), according to a three-step dip-coating protocol. FTIR, SEM, TEM, UV/vis spectrophotometer, and wettability analyses were used to characterize the composite membranes. The three coating layers interacted chemically with one another and also physically with the Kevlar fabric. Water uptake measurements indicated that the membrane is a hydrophilic one. SEM and TEM analyses showed the smooth surface of the composite membrane and three-dimensional dendrimeric hyper-branched structure of (PC-A), respectively. A dead-end filtration setup was applied to test the membranes performance under natural gravity force. Effect of pH as an important variable affecting separation process was investigated with the neutral pH provided the optimum condition for the separation. Oil rejection and permeate fluxes were also monitored. The optimum flux and rejection obtained, were 7392 (Lm-2 h-1) and 89.06% at pH 7, respectively. Fouling occurred as a gel layer on the membrane surface. The deposited oil droplets on the surface of the membrane were successfully washed away with satisfactory permeate flux recovery (FRR = 88.88% at neutral pH), using hot distilled water and acidic solution as eluents.

Hydrologic and geochemical characterization of the Santa Rosa Plain watershed, Sonoma County, California

USGS Publications Warehouse

Nishikawa, Tracy

2013-01-01

The Santa Rosa Plain is home to approximately half of the population of Sonoma County, California, and faces growth in population and demand for water. Water managers are confronted with the challenge of meeting the increasing water demand with a combination of water sources, including local groundwater, whose future availability could be uncertain. To meet this challenge, water managers are seeking to acquire the knowledge and tools needed to understand the likely effects of future groundwater development in the Santa Rosa Plain and to identify efficient strategies for surface- and groundwater management that will ensure the long-term viability of the water supply. The U.S. Geological Survey, in cooperation with the Sonoma County Water Agency and other stakeholders in the area (cities of Cotati, Rohnert Park, Santa Rosa, and Sebastopol, town of Windsor, Cal-American Water Company, and the County of Sonoma), undertook this study to characterize the hydrology of the Santa Rosa Plain and to develop tools to better understand and manage the groundwater system. The objectives of the study are: (1) to develop an updated assessment of the hydrogeology and geochemistry of the Santa Rosa Plain; (2) to develop a fully coupled surface-water and groundwater-flow model for the Santa Rosa Plain watershed; and (3) to evaluate the potential hydrologic effects of alternative groundwater-management strategies for the basin. The purpose of this report is to describe the surface-water and groundwater hydrology, hydrogeology, and water-quality characteristics of the Santa Rosa Plain watershed and to develop a conceptual model of the hydrologic system in support of the first objective. The results from completing the second and third objectives will be described in a separate report.

Hydrochemical and environmental isotope analysis of groundwater and surface water in a dry mountain region in Northern Chile.

PubMed

Zang, Carina; Dame, Juliane; Nüsser, Marcus

2018-05-08

This case study examines the geological imprint and land use practices on water quality in the arid Huasco Valley against the backdrop of ongoing water conflicts surrounding competing demands for agriculture and mining. The study is based on a detailed analysis of spatial and temporal variations of monthly surface and bi-monthly groundwater quality samples measured during the Chilean summer of 2015/16. Additional information on source regions and river-groundwater interactions were collected using stable water isotopes. Regarding the geological impact on water quality, high concentrations of Ca 2+ , SO 4 2- and HCO 3 - indicate a strong influence of magmatic rocks, which constitute this high mountain basin, on the hydrochemistry. Piper and Gibbs-diagrams revealed that all samples show a homogenous distribution dominated by rock-water interactions. Measured NO 3 - concentrations in surface water are generally low. However, groundwater aquifers exhibit higher concentrations. Mn is the only heavy metal with elevated concentrations in surface water, which are possibly related to mining activities. The results illustrate that both surface and groundwater can be classified as suitable for irrigation. In addition, groundwater has been found to be suitable as drinking water. High similarities in isotopic signatures indicate a strong connection between surface and groundwater. Isotopic analyses suggest a strong influence of evaporation. This combined approach of hydrogeochemical and isotopic analysis proved to be a helpful tool in characterizing the catchment and can serve as a basis for future sustainable water management.

Possibilities and Challenges for Modeling Flow and Pollutant Transport in a Karst Watershed with SWAT

USDA-ARS?s Scientific Manuscript database

Karst hydrology is characterized by multiple springs, sinkholes, and losing streams resulting from acidic water percolating through limestone. These features provide direct connections between surface water and groundwater and increase the risk of groundwater, spring and stream contamination. Anthro...

Characterizing the Diurnal Cycle of Land Surface Temperature and Evapotranspiration at High Spatial Resolution Using Thermal Observations from sUAS.

NASA Astrophysics Data System (ADS)

Dutta, D.; Drewry, D.; Johnson, W. R.

2017-12-01

The surface temperature of plant canopies is an important indicator of the stomatal regulation of plant water use and the associated water flux from plants to atmosphere (evapotranspiration (ET)). Remotely sensed thermal observations using compact, low-cost, lightweight sensors from small unmanned aerial systems (sUAS) have the potential to provide surface temperature (ST) and ET estimates at unprecedented spatial and temporal resolutions, allowing us to characterize the intra-field diurnal variations in canopy ST and ET for a variety of vegetation systems. However, major challenges exist for obtaining accurate surface temperature estimates from low-cost uncooled microbolometer-type sensors. Here we describe the development of calibration methods using thermal chamber experiments, taking into account the ambient optics and sensor temperatures, and applying simple models of spatial non-uniformity correction to the sensor focal-plane-array. We present a framework that can be used to derive accurate surface temperatures using radiometric observations from low-cost sensors, and demonstrate this framework using a sUAS-mounted sensor across a diverse set of calibration and vegetation targets. Further, we demonstrate the use of the Surface Temperature Initiated Closure (STIC) model for computing spatially explicit, high spatial resolution ET estimates across several well-monitored agricultural systems, as driven by sUAS acquired surface temperatures. STIC provides a physically-based surface energy balance framework for the simultaneous retrieval of the surface and atmospheric vapor conductances and surface energy fluxes, by physically integrating radiometric surface temperature information into the Penman-Monteith equation. Results of our analysis over agricultural systems in Ames, IA and Davis, CA demonstrate the power of this approach for quantifying the intra-field spatial variability in the diurnal cycle of plant water use at sub-meter resolutions.

Interaction of hydrogen chloride with alumina. [atmospheric effluent concentrations and interaction of solid rocket propellants used in space shuttle

NASA Technical Reports Server (NTRS)

Bailey, R. R.; Wightman, J. P.

1978-01-01

The influence of temperature, pressure, and outgas conditions on the absorption of hydrogen chloride and water vapor on both alpha and gamma alumina was studied. Characterization of the adsorbents was performed using X-ray powder diffraction, scanning electron microscopy (SEM), low temperature nitrogen adsorption desorption measurements, BET nitrogen surface area measurements and electron spectroscopy for chemical analysis (ESCA). Water vapor adsorption isotherms at 30, 40, and 50 C were measured on alpha and gamma alumina after outgassing at 80, 200, and 400 C. Both outgas temperature and adsorption temperature influenced the adsorption of water vapor on the aluminas. The water vapor adsorption was completely reversible. Alpha alumina absorbed more water per unit area than gamma alumina. Differences in the adsorption capacity for water vapor of the two aluminas were explained on the basis of ideal surface models of alpha and gamma alumina. Isosteric heats of adsorption for water vapor on the aluminas were determined over a limited range of surface coverage.

Spatial and temporal characterization of trace elements and nutrients in the Rawal Lake Reservoir, Pakistan using multivariate analysis techniques.

PubMed

Malik, Riffat Naseem; Nadeem, Muhammad

2011-12-01

Rawal Lake Reservoir is renowned for its ecological significance and is the sole source of drinking water of the third largest city of Pakistan. However, fish kill in recent years and anthropogenic impacts from human-related activities in its catchment area have resulted in deterioration of its surface water quality. This study aims to characterize spatial and temporal variations in surface water quality, identify contaminant sources, and compare their levels with quality guidelines. Surface water samples were collected from 10 sites and analyzed for 27 physicochemical parameters for a period of 2 years on a seasonal basis. Concentration of metals in surface water in pre-monsoon were in the order: Fe > Mg > Ca > Mn > Zn > Ni > Cr > Cu > Co > Pb, whereas in post-monsoon, the order of elemental concentrations was: Ca > Mg > Na > Fe > K > Zn > Cr > Li > Pb > Co > Ni > Cu > Mn > Cd. Metals (Ni, Fe, Zn, and Ca), pH, electrical conductivity (EC), dissolved oxygen (DO), chemical oxygen demand (COD), and nutrients (PO (4) (3-) , NO(3)-N, and SO (4) (2-) ) were measured higher in pre-monsoon, whereas concentration of Cu, Mn, Cr, Co, Pb, Cd, K, Na, Mg, Li, Cl(-), and NH(4)-N were recorded higher in post-monsoon. Results highlighted serious metal pollution of surface water. Mean concentration of Zn, Cd, Ni, Cu, Fe, Cr, and Pb in both seasons and Mn in post-monsoon were well above the permissible level of surface water quality criteria. Results stress the dire need to reduce heavy-metal input into the lake basin and suggest that heavy-metal contamination should be considered as an integral part of future planning and management strategies for restoration of water quality of the lake reservoir.

Improvement in surface hydrophilicity and resistance to deformation of natural leather through O2/H2O low-temperature plasma treatment

NASA Astrophysics Data System (ADS)

You, Xuewei; Gou, Li; Tong, Xingye

2016-01-01

The natural leather was modified through O2/H2O low-temperature plasma treatment. Surface morphology was characterized by scanning electron microscopy (SEM) and the results showed that the pores on the leather surface became deeper and larger with enhanced permeability of water and vapor. XPS and FTIR-ATR was performed to determine the chemical composition of natural leather surface. Oxygen-containing groups were successfully grafted onto the surface of natural leather and oxygen content increased with longer treatment time. After O2/H2O plasma treatment, initial water contact angle was about 21° and water contact angles were not beyond 55° after being stored for 3 days. Furthermore, the tensile test indicated that the resistance to deformation had a prominent transform without sacrificing the tensile strength.

Distribution of icy particles across Enceladus' surface as derived from Cassini-VIMS measurements

USGS Publications Warehouse

Jaumann, R.; Stephan, K.; Hansen, G.B.; Clark, R.N.; Buratti, B.J.; Brown, R.H.; Baines, K.H.; Newman, S.F.; Bellucci, G.; Filacchione, G.; Coradini, A.; Cruikshank, D.P.; Griffith, C.A.; Hibbitts, C.A.; McCord, T.B.; Nelson, R.M.; Nicholson, P.D.; Sotin, Christophe; Wagner, R.

2008-01-01

The surface of Enceladus consists almost completely of water ice. As the band depths of water ice absorptions are sensitive to the size of particles, absorptions can be used to map variations of icy particles across the surface. The Visual and Infrared Mapping Spectrometer (VIMS) observed Enceladus with a high spatial resolution during three Cassini flybys in 2005 (orbits EN 003, EN 004 and EN 011). Based on these data we measured the band depths of water ice absorptions at 1.04, 1.25, 1.5, and 2 ??m. These band depths were compared to water ice models that represent theoretically calculated reflectance spectra for a range of particle diameters between 2 ??m and 1 mm. The agreement between the experimental (VIMS) and model values supports the assumption that pure water ice characterizes the surface of Enceladus and therefore that variations in band depth correspond to variations in water ice particle diameters. Our measurements show that the particle diameter of water ice increases toward younger tectonically altered surface units with the largest particles exposed in relatively "fresh" surface material. The smallest particles were generally found in old densely cratered terrains. The largest particles (???0.2 mm) are concentrated in the so called "tiger stripes" at the south pole. In general, the particle diameters are strongly correlated with geologic features and surface ages, indicating a stratigraphic evolution of the surface that is caused by cryovolcanic resurfacing and impact gardening. ?? 2007 Elsevier Inc. All rights reserved.

Impact of Water Recovery from Wastes on the Lunar Surface Mission Water Balance

NASA Technical Reports Server (NTRS)

Fisher, John W.; Hogan, John Andrew; Wignarajah, Kanapathipi; Pace, Gregory S.

2010-01-01

Future extended lunar surface missions will require extensive recovery of resources to reduce mission costs and enable self-sufficiency. Water is of particular importance due to its potential use for human consumption and hygiene, general cleaning, clothes washing, radiation shielding, cooling for extravehicular activity suits, and oxygen and hydrogen production. Various water sources are inherently present or are generated in lunar surface missions, and subject to recovery. They include: initial water stores, water contained in food, human and other solid wastes, wastewaters and associated brines, ISRU water, and scavenging from residual propellant in landers. This paper presents the results of an analysis of the contribution of water recovery from life support wastes on the overall water balance for lunar surface missions. Water in human wastes, metabolic activity and survival needs are well characterized and dependable figures are available. A detailed life support waste model was developed that summarizes the composition of life support wastes and their water content. Waste processing technologies were reviewed for their potential to recover that water. The recoverable water in waste is a significant contribution to the overall water balance. The value of this contribution is discussed in the context of the other major sources and loses of water. Combined with other analyses these results provide guidance for research and technology development and down-selection.

Quantifying Surface Water, Porewater, and Groundwater Interactions Using Tracers: Tracer Fluxes, Water Fluxes, and End-member Concentrations

NASA Astrophysics Data System (ADS)

Cook, Peter G.; Rodellas, Valentí; Stieglitz, Thomas C.

2018-03-01

Tracer approaches to estimate both porewater exchange (the cycling of water between surface water and sediments, with zero net water flux) and groundwater inflow (the net flow of terrestrially derived groundwater into surface water) are commonly based on solute mass balances. However, this requires appropriate characterization of tracer end-member concentrations in exchanging or discharging water. Where either porewater exchange or groundwater inflow to surface water occur in isolation, then the water flux is easily estimated from the net tracer flux if the end-member is appropriately chosen. However, in most natural systems porewater exchange and groundwater inflow will occur concurrently. Our analysis shows that if groundwater inflow (Qg) and porewater exchange (Qp) mix completely before discharging to surface water, then the combined water flux (Qg + Qp) can be approximated by dividing the combined tracer flux by the difference between the porewater and surface water concentrations, (cp - c). If Qg and Qp do not mix prior to discharge, then (Qg + Qp) can only be constrained by minimum and maximum values. The minimum value is obtained by dividing the net tracer flux by the groundwater concentration, and the maximum is obtained by dividing by (cp - c). Dividing by the groundwater concentration gives a maximum value for Qg. If porewater exchange and groundwater outflow occur concurrently, then dividing the net tracer flux by (cp - c) will provide a minimum value for Qp. Use of multiple tracers, and spatial and temporal replication should provide a more complete picture of exchange processes and the extent of subsurface mixing.

Groundwater recharge in suburban areas of Hanoi, Vietnam: effect of decreasing surface-water bodies and land-use change

NASA Astrophysics Data System (ADS)

Kuroda, Keisuke; Hayashi, Takeshi; Do, An Thuan; Canh, Vu Duc; Nga, Tran Thi Viet; Funabiki, Ayako; Takizawa, Satoshi

2017-05-01

Over-exploited groundwater is expected to remain the predominant source of domestic water in suburban areas of Hanoi, Vietnam. In order to evaluate the effect on groundwater recharge, of decreasing surface-water bodies and land-use change caused by urbanization, the relevant groundwater systems and recharge pathways must be characterized in detail. To this end, water levels and water quality were monitored for 3 years regarding groundwater and adjacent surface-water bodies, at two typical suburban sites in Hanoi. Stable isotope (δ18O, δD of water) analysis and hydrochemical analysis showed that the water from both aquifers and aquitards, including the groundwater obtained from both the monitoring wells and the neighboring household tubewells, was largely derived from evaporation-affected surface-water bodies (e.g., ponds, irrigated farmlands) rather than from rivers. The water-level monitoring results suggested distinct local-scale flow systems for both a Holocene unconfined aquifer (HUA) and Pleistocene confined aquifer (PCA). That is, in the case of the HUA, lateral recharge through the aquifer from neighboring ponds and/or irrigated farmlands appeared to be dominant, rather than recharge by vertical rainwater infiltration. In the case of the PCA, recharge by the above-lying HUA, through areas where the aquitard separating the two aquifers was relatively thin or nonexistent, was suggested. As the decrease in the local surface-water bodies will likely reduce the groundwater recharge, maintaining and enhancing this recharge (through preservation of the surface-water bodies) is considered as essential for the sustainable use of groundwater in the area.

Mapping the environmental risk potential on surface water of pesticide contamination in the Prosecco's vineyard terraced landscape

NASA Astrophysics Data System (ADS)

Pizarro, Patricia; Ferrarese, Francesco; Loddo, Donato; Eugenio Pappalardo, Salvatore; Varotto, Mauro

2016-04-01

Intensive cropping systems today represent a paramount issue in terms of environmental impacts, since agricultural pollutants can constitute a potential threat to surface water, non-target organisms and aquatic ecosystems. Levels of pesticide concentrations in surface waters are indeed unquestionably correlated to crop and soil management practices at field-scale. Due to the numerous applications of pesticides required, orchards and vineyards can represent relevant non-point sources for pesticide contamination of water bodies, mainly prompted by soil erosion, surface runoff and spray drift. To reduce risks of pesticide contamination of surface water, the Directive 2009/128/CET imposed the local implementation of agricultural good practices and mitigation actions such as the use of vegetative buffer filter strips and hedgerows along river and pond banks. However, implementation of mitigation actions is often difficult, especially in extremely fragmented agricultural landscapes characterized by a complex territorial matrix set up on urban sprawling, frequent surface water bodies, important geomorphological processes and protected natural areas. Typically, such landscape matrix is well represented by the, Prosecco-DOCG vineyards area (NE of Italy, Province of Treviso) which lays on hogback hills of conglomerate, marls and sandstone that ranges between 50 and 500 m asl. Moreover such vineyards landscape is characterized by traditional and non-traditional agricultural terraces The general aim of this paper is to identify areas of surface water bodies with high potential risk of pesticide contamination from surrounding vineyards in the 735 ha of Lierza river basin (Refrontolo, TV), one of the most representative terraced landscape of the Prosecco-DOCG area. Specific aims are i) mapping terraced Prosecco-DOCG vineyards, ii) classifying potential risk from pesticide of the different areas. Remote sensing technologies such as four bands aerial photos (RGB+NIR) and Light Detection and Ranging (LiDAR) have been used to map vineyards and to evaluate slope and drainage systems. All the data and statistics analyses have been performed in GIS environment. The areas of surface water located within a buffer zone of 20 linear meters from vineyard perimeter were considered at risk of pesticide contamination, according to European guidelines and on-site experimental results about the pesticide drift effect. Preliminary results show that 26 ha of the total vineyards within the river basin can potentially affect surface water bodies, highlighting that 19,410 m of perimeter is within 20 m from water courses. Moreover, vineyard classification based on proximity analysis indicates that 6.8 ha are at very high potential risk (<1m from water courses), 8.6 ha are at high risk level (from 1 to 5 m); 4.3 ha are at medium level (from 5 to 10 m), while 8.6 ha are at low level (>10 m).

Dragonfly: Investigating the Surface Composition of Titan

NASA Technical Reports Server (NTRS)

Brinckerhoff, W. B.; Lawrence, D. J.; Barnes, J. W.; Lorenz, R. D.; Horst, S. M.; Zacny, K.; Freissinet, C.; Parsons, A. M.; Turtle, E. P.; Trainer, M. G.;

GEWEX Water and Energy Budget Study

NASA Technical Reports Server (NTRS)

Roads, J.; Bainto, E.; Masuda, K.; Rodell, Matthew; Rossow, W. B.

2008-01-01

Closing the global water and energy budgets has been an elusive Global Energy and Water-cycle Experiment (GEWEX) goal. It has been difficult to gather many of the needed global water and energy variables and processes, although, because of GEWEX, we now have globally gridded observational estimates for precipitation and radiation and many other relevant variables such as clouds and aerosols. Still, constrained models are required to fill in many of the process and variable gaps. At least there are now several atmospheric reanalyses ranging from the early National Centers for Environmental Prediction/National Center for Atmospheric Research (NCEP/NCAR) and NCEP/Department of Energy (DOE) reanalyses to the more recent ERA40 and JRA-25 reanalyses. Atmospheric constraints include requirements that the models state variables remain close to in situ observations or observed satellite radiances. This is usually done by making short-term forecasts from an analyzed initial state; these short-term forecasts provide the next guess, which is corrected by comparison to available observations. While this analysis procedure is likely to result in useful global descriptions of atmospheric temperature, wind and humidity, there is no guarantee that relevant hydroclimate processes like precipitation, which we can observe and evaluate, and evaporation over land, which we cannot, have similar verisimilitude. Alternatively, the Global Land Data Assimilation System (GLDAS), drives uncoupled land surface models with precipitation, surface solar radiation, and surface meteorology (from bias-corrected reanalyses during the study period) to simulate terrestrial states and surface fluxes. Further constraints are made when a tuned water balance model is used to characterize the global runoff observational estimates. We use this disparate mix of observational estimates, reanalyses, GLDAS and calibrated water balance simulations to try to characterize and close global and terrestrial atmospheric and surface water and energy budgets to within 10-20% for long term (1986-1995), large-scale global to regional annual means.

Self-cleaning superhydrophobic epoxy coating based on fibrous silica-coated iron oxide magnetic nanoparticles.

PubMed

Alamri, Haleema; Al-Shahrani, Abdullah; Bovero, Enrico; Khaldi, Turki; Alabedi, Gasan; Obaid, Waleed; Al-Taie, Ihsan; Fihri, Aziz

2018-03-01

Inspired by the self-cleaning lotus leaf, a facile method of fabricating superhydrophobic silica coated magnetite nanoparticles using a cost-effective process is presented in this work. The structural characterizations and magnetic properties of the obtained core-shell magnetic nanoparticles were characterized by means of X-ray diffraction (XRD), thermal gravimetric analysis (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and vibrating sample magnetometer (VSM). TEM analysis revealed that the particles present flower-like dendrimeric fibers morphology. The particles were uniformly dispersed on the surface of an epoxy resin coating with the purpose to increase the roughness and reduce the surface energy of the surface. The resulting superhydrophobic surface provides robust water-repellent surface under harsh conditions, thanks to its self-cleaning characteristic. The superhydrophobicity of this surface was confirmed based on the measurements of a water contact angle around 175°, which surpasses the theoretical limit of the superhydrophobicity. The simplicity and the cost-effectiveness of the process developed in this study appears to be a promising route for the preparation of other magnetic superhydrophobic organic-inorganic hybrid materials that would be beneficial in a wide variety of applications. Copyright © 2017 Elsevier Inc. All rights reserved.

A Study of Drop-Microstructured Surface Interactions during Dropwise Condensation with Quartz Crystal Microbalance

PubMed Central

Su, Junwei; Charmchi, Majid; Sun, Hongwei

2016-01-01

Dropwise condensation (DWC) on hydrophobic surfaces is attracting attention for its great potential in many industrial applications, such as steam power plants, water desalination, and de-icing of aerodynamic surfaces, to list a few. The direct dynamic characterization of liquid/solid interaction can significantly accelerate the progress toward a full understanding of the thermal and mass transport mechanisms during DWC processes. This work reports a novel Quartz Crystal Microbalance (QCM) based method that can quantitatively analyze the interaction between water droplets and micropillar surfaces during different condensation states such as filmwise, Wenzel, and partial Cassie states. A combined nanoimprinting lithography and chemical surface treatment approach was utilized to fabricate the micropillar based superhydrophobic and superhydrophilic surfaces on the QCM substrates. The normalized frequency shift of the QCM device together with the microscopic observation of the corresponding drop motion revealed the droplets growth and their coalescence processes and clearly demonstrated the differences between the three aforementioned condensation states. In addition, the transition between Cassie and Wenzel states was successfully captured by this method. The newly developed QCM system provides a valuable tool for the dynamic characterization of different condensation processes. PMID:27739452

Reduction of DOM fractions and their trihalomethane formation potential in surface river water by in-line coagulation with ceramic membrane filtration.

PubMed

Rakruam, Pharkphum; Wattanachira, Suraphong

2014-03-01

This research was aimed at investigating the reduction of DOM fractions and their trihalomethane formation potential (THMFP) by in-line coagulation with 0.1 μm ceramic membrane filtration. The combination of ceramic membrane filtration with a coagulation process is an alternative technology which can be applied to enhance conventional coagulation processes in the field of water treatment and drinking water production. The Ping River water (high turbidity water) was selected as the raw surface water because it is currently the main raw water source for water supply production in the urban and rural areas of Chiang Mai Province. From the investigation, the results showed that the highest percent reductions of DOC, UV-254, and THMFP (47.6%, 71.0%, and 67.4%, respectively) were achieved from in-line coagulation with ceramic membrane filtration at polyaluminum chloride dosage 40 mg/L. Resin adsorption techniques were employed to characterize the DOM in raw surface water and filtered water. The results showed that the use of a ceramic membrane with in-line coagulation was able to most efficiently reduce the hydrophobic fraction (HPOA) (68.5%), which was then followed by the hydrophilic fraction (HPIA) (49.3%). The greater mass DOC reduction of these two fractions provided the highest THMFP reductions (55.1% and 37.2%, respectively). Furthermore, the in-line coagulation with ceramic membrane filtration was able to reduce the hydrophobic (HPOB) fraction which is characterized by high reactivity toward THM formation. The percent reduction of mass DOC and THMFP of HPOB by in-line coagulation with ceramic membrane filtration was 45.9% and 48.0%, respectively. Copyright © 2014 The Research Centre for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

Surface Characterization on Corrosion By-products on Cu in Drinking Water Pipes

EPA Science Inventory

Copper is widely used in house-hold plumbing due to its anti-corrosion property. However, as water travels within the distribution system into corroded copper pipes, copper may be released into consumer’s tap causing major problems. In an attempt to understand the mechanism and...

Surface characterization of cottonseed meal products by SEM, SEM-EDS, XRD and XPS analysis

USDA-ARS?s Scientific Manuscript database

The utilization of cottonseed meal as a valuable industrial feedstock needs to be exploited. We have recently produced water-washed cottonseed meal, total cottonseed protein, sequentially extracted water- and alkali-soluble proteins, and two residues after the total and sequential protein extraction...

Estimated Costs of Sporadic Gastrointestinal Illness Associated with Surface Water Recreation: A Combined Analysis of Data from NEEAR and CHEERS Studies

EPA Science Inventory

BACKGROUND: The ·burden of illness can be described by addressing both incidence and illness severity attributable to water recreation. Monetized as cost. attributable disease burden estimates can be useful for environmental management decisions. OBJECTIVES: We characterize the ...

A protocol for conducting rainfall simulation to study soil runoff

USDA-ARS?s Scientific Manuscript database

Rainfall is a driving force for the transport of environmental contaminants from agricultural soils to surficial water bodies via surface runoff. The objective of this study was to characterize the effects of antecedent soil moisture content on the fate and transport of surface applied commercial ur...

On the parameters influencing air-water gas exchange

NASA Astrophysics Data System (ADS)

JäHne, Bernd; Münnich, Karl Otto; BöSinger, Rainer; Dutzi, Alfred; Huber, Werner; Libner, Peter

1987-02-01

Detailed gas exchange measurements from two circular and one linear wind/wave tunnels are presented. Heat, He, CH4, CO2, Kr, and Xe have been used as tracers. The experiments show the central importance of waves for the water-side transfer process. With the onset of waves the Schmidt number dependence of the transfer velocity k changes from k ∝ Sc-⅔ to k ∝ Sc-½indicating a change in the boundary conditions at the surface. Moreover, energy put into the wave field by wind is transferred to near-surface turbulence enhancing gas transfer. The data show that the mean square slope of the waves is the best parameter to characterize the free wavy surface with respect to water-side transfer processes.

Preparation of Ag superhydrophobic surface on metal substrates

NASA Astrophysics Data System (ADS)

Li, J. Y.; Lu, S. X.; Xu, W. G.; Duan, Y. Q.; Yang, X. C.; Cheng, Y. Y.; He, G.; Cui, S.

2018-01-01

In this work, the facile approaches are developed for preparation the Ag superhydrophobic surfaces (SHSs) on zinc (Zn), copper (Cu) and aluminium (Al) substrates. The water contact angles (WCAs) of the Ag SHSs on Zn, Cu and Al substrates are 167°, 165° and 154°, respectively. Furthermore, the water sliding angle (WSA) of each surface is less than 1°. The morphology and chemical composition of the samples are characterized using scanning electron microscopy (SEM) and X-ray diffraction pattern (XRD). The as-prepared three kinds of SHSs possess the self-cleaning performance, which can quickly take the chalk away when the water droplets fall down the SHSs. In addition, the superhydrophobicity of the SHSs can well maintain after exposure to the air for 6 months, indicating that the surfaces can sustain good stability.

Humidity-dependent compression-induced glass transition of the air–water interfacial Langmuir films of poly(D,L-lactic acid- ran-glycolic acid) (PLGA)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, Hyun Chang; Lee, Hoyoung; Jung, Hyunjung

2015-08-26

Constant rate compression isotherms of the air–water interfacial Langmuir films of poly(D,L-lactic acid- ran-glycolic acid) (PLGA)show a distinct feature of an exponential increase in surface pressure in the high surface polymer concentration regime. We have previously demonstrated that this abrupt increase in surface pressure is linked to the glass transition of the polymer film, but the detailed mechanism of this process is not understood. In order to obtain a molecular-level understanding of this behavior, we performed extensive characterizations of the surface mechanical, structural and rheological properties of Langmuir PLGA films at the air–water interface, using combined experimental techniques including themore » Langmuir film balance, X-ray reflectivity and double-wall-ring interfacial rheometry methods.« less

Characterizing hydrophobicity of amino acid side chains in a protein environment via measuring contact angle of a water nanodroplet on planar peptide network

PubMed Central

Zhu, Chongqin; Gao, Yurui; Li, Hui; Meng, Sheng; Li, Lei; Francisco, Joseph S.; Zeng, Xiao Cheng

2016-01-01

Hydrophobicity of macroscopic planar surface is conventionally characterized by the contact angle of water droplets. However, this engineering measurement cannot be directly extended to surfaces of proteins, due to the nanometer scale of amino acids and inherent nonplanar structures. To measure the hydrophobicity of side chains of proteins quantitatively, numerous parameters were developed to characterize behavior of hydrophobic solvation. However, consistency among these parameters is not always apparent. Herein, we demonstrate an alternative way of characterizing hydrophobicity of amino acid side chains in a protein environment by constructing a monolayer of amino acids (i.e., artificial planar peptide network) according to the primary and the β-sheet secondary structures of protein so that the conventional engineering measurement of the contact angle of a water droplet can be brought to bear. Using molecular dynamics simulations, contact angles θ of a water nanodroplet on the planar peptide network, together with excess chemical potentials of purely repulsive methane-sized Weeks−Chandler−Andersen solute, are computed. All of the 20 types of amino acids and the corresponding planar peptide networks are studied. Expectedly, all of the planar peptide networks with nonpolar amino acids are hydrophobic due to θ > 90°, whereas all of the planar peptide networks of the polar and charged amino acids are hydrophilic due to θ < 90°. Planar peptide networks of the charged amino acids exhibit complete-wetting behavior due to θ = 0°. This computational approach for characterization of hydrophobicity can be extended to artificial planar networks of other soft matter. PMID:27803319

Super-hydrophobic, highly adhesive, polydimethylsiloxane (PDMS) surfaces.

PubMed

Stanton, Morgan M; Ducker, Robert E; MacDonald, John C; Lambert, Christopher R; McGimpsey, W Grant

2012-02-01

Super-hydrophobic surfaces have been fabricated by casting polydimethylsiloxane (PDMS) on a textured substrate of known surface topography, and were characterized using contact angle, atomic force microscopy, surface free energy calculations, and adhesion measurements. The resulting PDMS has a micro-textured surface with a static contact angle of 153.5° and a hysteresis of 27° when using de-ionized water. Unlike many super-hydrophobic materials, the textured PDMS is highly adhesive, allowing water drops as large as 25.0 μL to be inverted. This high adhesion, super-hydrophobic behavior is an illustration of the "petal effect". This rapid, reproducible technique has promising applications in transport and analysis of microvolume samples. Copyright © 2011 Elsevier Inc. All rights reserved.

Sea-surface dynamics changes in the North Atlantic Ocean (IODP Site U1314) during late Pliocene deduced from calcareous nannofossil observation

NASA Astrophysics Data System (ADS)

Jatiningrum, R. S.; Sato, T.; Effendi, R.

2016-12-01

Calcareous nannofossils were analyzed on the late Pliocene sediments (2.55 to 2.88 Ma) from the southern Gardar Drift, in the subpolar North Atlantic IODP Site U1314 (56°21.9'1N, 27°53.3'W) at an average resolution of 3 kyr. In this study, a total 131 samples were analyzed and a total of 24 species from 14 genera were identified by polarizing microscope observation. In general, the coccolith assemblage is dominated by Reticulofenestra spp., whilst significant changes in paleoceanographic conditions are mainly shown by the ratio of Reticulofenstra morphometric and several subordinate species. Top of D. tamalis found at 272.81 mcd, which dates to an age of 2.756 Ma. The age is based on correlation with the age model established by Hayashi et al. (2012) and modified partly by Sato et al. (2015). The presence of abundant large reticulofenestrids and lower abundance of C. pelagicus characterized the interval through G12 to G10, indicate oligotrophic surface waters and northward heat transport by intensified NAC. During G9/G8 transition the abundance of large reticulofenestrids decreased abruptly and alternating with small reticulofenestrids. Above G9/G8 transition is characterized by abundance of small reticulofenestrids, higher abundance of P. lacunosa and the cold-water species C. pelagicus, suggesting higher surface water productivity and the prevalence of cold waters over the site. Thus, reflecting a weakened influence of the NAC and southward position of AF that is characterized by high eddy activity in correspondence with cooler and nutrient-rich waters.

Foulant Analysis of Three RO Membranes Used in Treating Simulated Brackish Water of the Iraqi Marshes

PubMed Central

Sachit, Dawood Eisa; Veenstra, John N.

2017-01-01

In this work, three different types of Reverse Osmosis (RO) (Thin-Film Composite (SE), Cellulose Acetate (CE), and Polyamide (AD)) were used to perform foulant analysis (autopsy) study on the deposited materials from three different simulated brackish surface feed waters. The brackish surface water qualities represented the water quality in Iraqi marshes. The main foulants from the simulated feed waters were characterized by using Scanning Electron Microscope (SEM) images and Energy-Dispersive X-ray Spectroscopy (EDXS) spectra. The effect of feed water temperatures (37 °C and 11 °C) on the formation of the fouled material deposited on the membrane surface was examined in this study. Also, pretreatment by a 0.1 micron microfiltration (MF) membrane of the simulated feed water in advance of the RO membrane on the precipitated material on the membrane surface was investigated. Finally, Fourier Transform Infrared Spectroscopy (FTIR) analysis was used to identify the functional groups of the organic matter deposited on the RO membrane surfaces. The SEM images and EDSX spectra suggested that the fouled material was mainly organic matter, and the major crystal deposited on the RO membrane was calcium carbonate (CaCO3). The FTIR spectra of the fouled RO membranes suggested that the constituents of the fouled material included aliphatic and aromatic compounds. PMID:28406468

Investigating Deliquescence of Mars-like Soils from the Atacama Desert and Implications for Liquid Water Near the Martian Surface

NASA Astrophysics Data System (ADS)

Van Alstyne, A. M.; Tolbert, M. A.; Gough, R. V.; Primm, K.

2017-12-01

Recent images obtained from orbiters have shown that the Martian surface is more dynamic than previously thought. These images, showing dark features that resemble flowing water near the surface, have called into question the habitability of the Mars today. Recurring slope lineae (RSL), or the dark features seen in these images, are characterized as narrow, dark streaks that form and grow in the warm season, fade in the cold season, and recur seasonally. It is widely hypothesized that the movement of liquid water near the surface is what causes the appearance of RSL. However, the origin of the water and the potential for water to be stable near the surface is a question of great debate. Here, we investigate the potential for stable or metastable liquid water via deliquescence and efflorescence. The deliquescent properties of salts from the Atacama Desert, a popular terrestrial analog for Martian environments, were investigated using a Raman microscope outfitted with an environmental cell. The salts were put under Mars-relevant conditions and spectra were obtained to determine the presence or absence of liquid phases. The appearance of liquid phases under Mars-relevant conditions would demonstrate that liquid water could be available to cause or play a role in the formations of RSL.

Carbon and nitrogen biogeochemistry of a Prairie Pothole Wetland, Stutsman County, North Dakota, USA

USGS Publications Warehouse

Holloway, JoAnn M.; Goldhaber, Martin B.; Mills, Christopher T.

2011-01-01

The concentration and form of dissolved organic C (DOC) and N species (NH4+ and NO3-) were investigated as part of a larger hydrogeochemical study of the Cottonwood Lake Study Area within the Prairie Potholes region. Groundwater, pore water and surface wetland water data were used to help characterize the relationships between surface and groundwater with respect to nutrient dynamics. Photosynthesis and subsequent decomposition of vegetation in these hydrologically dynamic wetlands generates a large amount of dissolved C and N, although the subsurface till, derived in part from organic matter rich Pierre Shale, is a likely secondary source of nutrients in deeper groundwater. While surface water DOC concentrations ranged from 2.2 to 4.6 mM, groundwater values were 0.15 mM to 3.7 mM. Greater specific UV absorbance (SUVA254) in the wetland water column and in soil pore waters relative to groundwater indicate more reactive DOC in the surface to near-surface waters. Circumneutral wetlands had greater SUVA254, possibly because of variations in vegetation communities. The dominant inorganic nitrogen species was NH4+ in both wetland water and most ground water samples. The exceptions were 3 wells with NO3- ranging from 38 to 115 μM. Shallow groundwater wells (Well 28 and Well 13S) with greater connection to wetland surface water had greater NH4+ concentrations (1.1 mM and 120 μM) than other well samples (3–90 μM). Pore water nutrient chemistry was more similar to surface water than ground water. Nitrogen results suggest reducing conditions in both groundwater and surface water, possibly due to the microbial uptake of O2 by decaying vegetation in the wetland water column, labile organic C available in shallow groundwater, or the oxidation of pyrite associated with the subsurface.

Kinetic model of water vapour adsorption by gluten-free starch

NASA Astrophysics Data System (ADS)

Ocieczek, Aneta; Kostek, Robert; Ruszkowska, Millena

2015-01-01

This study evaluated the kinetics of water vapour adsorption on the surface of starch molecules derived from wheat. The aim of the study was to determine an equation that would allow estimation of water content in tested material in any timepoint of the adsorption process aimed at settling a balance with the environment. An adsorption isotherm of water vapour on starch granules was drawn. The parameters of the Guggenheim, Anderson, and De Boer equation were determined by characterizing the tested product and adsorption process. The equation of kinetics of water vapour adsorption on the surface of starch was determined based on the Guggenheim, Anderson, and De Boer model describing the state of equilibrium and on the model of a first-order linear inert element describing the changes in water content over time.

Biofilm-like properties of the sea surface and predicted effects on air-sea CO2 exchange

NASA Astrophysics Data System (ADS)

Wurl, Oliver; Stolle, Christian; Van Thuoc, Chu; The Thu, Pham; Mari, Xavier

2016-05-01

Because the sea surface controls various interactions between the ocean and the atmosphere, it has a profound function for marine biogeochemistry and climate regulation. The sea surface is the gateway for the exchange of climate-relevant gases, heat and particles. Thus, in order to determine how the ocean and the atmosphere interact and respond to environmental changes on a global scale, the characterization and understanding of the sea surface are essential. The uppermost part of the water column is defined as the sea-surface microlayer and experiences strong spatial and temporal dynamics, mainly due to meteorological forcing. Wave-damped areas at the sea surface are caused by the accumulation of surface-active organic material and are defined as slicks. Natural slicks are observed frequently but their biogeochemical properties are poorly understood. In the present study, we found up to 40 times more transparent exopolymer particles (TEP), the foundation of any biofilm, in slicks compared to the underlying bulk water at multiple stations in the North Pacific, South China Sea, and Baltic Sea. We found a significant lower enrichment of TEP (up to 6) in non-slick sea surfaces compared to its underlying bulk water. Moreover, slicks were characterized by a large microbial biomass, another shared feature with conventional biofilms on solid surfaces. Compared to non-slick samples (avg. pairwise similarity of 70%), the community composition of bacteria in slicks was increasingly (avg. pairwise similarity of 45%) different from bulk water communities, indicating that the TEP-matrix creates specific environments for its inhabitants. We, therefore, conclude that slicks can feature biofilm-like properties with the excessive accumulation of particles and microbes. We also assessed the potential distribution and frequency of slick-formation in coastal and oceanic regions, and their effect on air-sea CO2 exchange based on literature data. We estimate that slicks can reduce CO2 fluxes by up to 15%, and, therefore, play important local and regional roles in regulating air-sea interactions.

Columbia River Component Data Gap Analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

L. C. Hulstrom

2007-10-23

This Data Gap Analysis report documents the results of a study conducted by Washington Closure Hanford (WCH) to compile and reivew the currently available surface water and sediment data for the Columbia River near and downstream of the Hanford Site. This Data Gap Analysis study was conducted to review the adequacy of the existing surface water and sediment data set from the Columbia River, with specific reference to the use of the data in future site characterization and screening level risk assessments.

Heliport Noise Model (HNM). Version 1. (User’s Guide)

DTIC Science & Technology

1988-02-01

Examples of acoustically hard surfaces include concrete or asphalt paving, water or baked clay surfaces. Mote that if the site does not meet the...neighbor should be characterized as either Hard (H) or Soft (S). From an acoustic point of view, "hard" ground is either pavement or water . All other...GROUND DISraNCE 10 - MAP - SEIUP 11 - HELIPADS 3 - HELIPADS 12- rAKEOI tRACKS 4 - HELICOPrERS 13 - APPROACH IRACKS 5 - IAKt-OFFS 14- rAxx fRACKS C6

Size-resolved characterization of the polysaccharidic and proteinaceous components of sea spray aerosol

NASA Astrophysics Data System (ADS)

Aller, Josephine Y.; Radway, JoAnn C.; Kilthau, Wendy P.; Bothe, Dylan W.; Wilson, Theodore W.; Vaillancourt, Robert D.; Quinn, Patricia K.; Coffman, Derek J.; Murray, Benjamin J.; Knopf, Daniel A.

2017-04-01

Dissolved organic polymers released by phytoplankton and bacteria abiologically self-assemble in surface ocean waters into nano-to micro-sized gels containing polysaccharides, proteins, lipids and other components. These gels concentrate in the sea surface microlayer (SML), where they can potentially contribute to sea spray aerosol (SSA). Sea spray is a major source of atmospheric aerosol mass over much of the earth's surface, and knowledge of its properties (including the amount and nature of the organic content), size distributions and fluxes are fundamental for determining its role in atmospheric chemistry and climate. Using a cascade impactor, we collected size-fractionated aerosol particles from ambient air and from freshly generated Sea Sweep SSA in the western North Atlantic Ocean together with biological and chemical characterization of subsurface and SML waters. Spectrophotometric methods were applied to quantify the polysaccharide-containing transparent exopolymer (TEP) and protein-containing Coomassie stainable material (CSM) in these particles and waters. This study demonstrates that both TEP and CSM in surface ocean waters are aerosolized with sea spray with the greatest total TEP associated with particles <180 nm in diameter and >5 000 nm. The higher concentrations of TEP and CSM in particles >5 000 nm most likely reflects collection of microorganism cells and/or fragments. The greater concentration of CSM in larger size particles may also reflect greater stability of proteinaceous gels compared to polysaccharide-rich gels in surface waters and the SML. Both TEP and CSM were measured in the ambient marine air sample with concentrations of 2.1 ± 0.16 μg xanthan gum equivalents (XG eq.) m-3 and 14 ± 1.0 μg bovine serum albumin equivalents (BSA eq.) m-3. TEP in Sea Sweep SSA averaged 4.7 ± 3.1 μg XG eq. m-3 and CSM 8.6 ± 7.3 μg BSA eq. m-3. This work shows the transport of marine biogenic material across the air-sea interface through primary particle emission and the first demonstration of particle size discriminated TEP and CSM characterization of SSA and ambient aerosol under field conditions.

Fabricating Superhydrophobic and Superoleophobic Surfaces with Multiscale Roughness Using Airbrush and Electrospray

NASA Astrophysics Data System (ADS)

AL-Milaji, Karam N.

Examples of superhydrophobic surfaces found in nature such as self-cleaning property of lotus leaf and walking on water ability of water strider have led to an extensive investigation in this area over the past few decades. When a water droplet rests on a textured surface, it may either form a liquid-solid-vapor composite interface by which the liquid droplet partially sits on air pockets or it may wet the surface in which the water replaces the trapped air depending on the surface roughness and the surface chemistry. Super water repellent surfaces have numerous applications in our daily life such as drag reduction, anti-icing, anti-fogging, energy conservation, noise reduction, and self-cleaning. In fact, the same concept could be applied in designing and producing surfaces that repel organic contaminations (e.g. low surface tension liquids). However, superoleophobic surfaces are more challenging to fabricate than superhydrophobic surfaces since the combination of multiscale roughness with re-entrant or overhang structure and surface chemistry must be provided. In this study, simple, cost-effective and potentially scalable techniques, i.e., airbrush and electrospray, were employed for the sake of making superhydrophobic and superoleophobic coatings with random and patterned multiscale surface roughness. Different types of silicon dioxide were utilized in this work to in order to study and to characterize the effect of surface morphology and surface roughness on surface wettability. The experimental findings indicated that super liquid repellent surfaces with high apparent contact angles and extremely low sliding angles were successfully fabricated by combining re-entrant structure, multiscale surface roughness, and low surface energy obtained from chemically treating the fabricated surfaces. In addition to that, the experimental observations regarding producing textured surfaces in mask-assisted electrospray were further validated by simulating the actual working conditions and geometries using COMSOL Multiphysics.

Characterization of dissolved organic matter for prediction of trihalomethane formation potential in surface and sub-surface waters.

PubMed

Awad, John; van Leeuwen, John; Chow, Christopher; Drikas, Mary; Smernik, Ronald J; Chittleborough, David J; Bestland, Erick

2016-05-05

Dissolved organic matter (DOM) in surface waters used for drinking purposes can vary markedly in character dependent on their sources within catchments. The character of DOM further influences the formation of disinfection by products when precursor DOM present in drinking water reacts with chlorine during disinfection. Here we report the development of models that describe the formation potential of trihalomethanes (THMFP) dependent on the character of DOM in waters from discrete catchments with specific land-use and soil textures. DOM was characterized based on UV absorbance at 254 nm, apparent molecular weight and relative abundances of protein-like and humic-like compounds. DOM character and Br concentration (up to 0.5 mg/L) were used as variables in models (R(2)>0.93) of THMFP, which ranged from 19 to 649 μg/L. Chloroform concentration (12-594 μg/L) and relative abundance (27-99%) were first modeled (R(2)>0.85) and from these, the abundances of bromodichloromethane and chlorodibromomethane estimated using power and exponential functions, respectively (R(2)>0.98). From these, the abundance of bromoform is calculated. The proposed model may be used in risk assessment of catchment factors on formation of trihalomethanes in drinking water, in context of treatment efficiency for removal of organic matter. Crown Copyright © 2016. Published by Elsevier B.V. All rights reserved.

Biodegradability of Chlorophenols in Surface Waters from the Urban Area of Buenos Aires.

PubMed

Gallego, A; Laurino Soulé, J; Napolitano, H; Rossi, S L; Vescina, C; Korol, S E

2018-04-01

Biodegradability of 2-Chlorophenol (2-CP), 3-Chlorophenol (3-CP), 4-Chlorophenol (4-CP), 2,4-Dichlorophenol (2,4-DCP) and 2,4,6 Trichlorophenol (2,4,6-TCP) has been tested in surface waters in the urban area of Buenos Aires. Samples were taken from the La Plata River and from the Reconquista and Matanza-Riachuelo basins, with a total amount of 18 sampling points. Water quality was established measuring chemical oxygen demand (COD), biochemical oxygen demand (BOD 5 ), and both Escherichia coli and Enterococcus counts. Biodegradability was carried out by a respirometric method, using a concentration of 20 mg L -1 of chlorophenol, and the surface water as inoculum. Chlorophenols concentration in the same water samples were simultaneously measured by a solid phase microextraction (SPME) procedure followed by gas chromatography-mass spectrometry (GC-MS). 2,4-DCP was the most degradable compound followed by 2,4,6-TCP, 4-CP, 3-CP and 2-CP. Biodegradability showed no correlation with compound concentration. At most sampling points the concentration was below the detection limit for all congeners. Biodegradability does not correlate even with COD, BOD 5 , or fecal contamination. Biodegradability assays highlighted information about bacterial exposure to contaminants that parameters routinely used for watercourse characterization do not reveal. For this reason, they might be a helpful tool to complete the characterization of a site.

Processus et bilan des flux hydriques d'un bassin versant de milieu tropical de socle au Bénin (Donga, haut Ouémé)

NASA Astrophysics Data System (ADS)

Kamagaté, Bamory; Séguis, Luc; Favreau, Guillaume; Seidel, Jean-Luc; Descloitres, Marc; Affaton, Pascal

2007-05-01

Hydrodynamic, geochemical, and subsurface geophysical investigations, for two consecutive years with contrasting rainfall conditions, were used to characterize the hydrological processes occurring, and the water balance of a 586-km 2 watershed in Benin (Africa). The water table's monitoring shows that recharge occurs by direct infiltration of rainfall, and represents between 5 to 24% of the annual rainfall. Both surface water outflow, limited to the rainy season, and water chemistry indicate a weak groundwater contribution to river discharge. This implies that the calculated variations in annual runoff coefficients (of 14 and 28%) are mainly governed by surface and subsurface flows.

Primary acoustic signal structure during free falling drop collision with a water surface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chashechkin, Yu. D., E-mail: chakin@ipmnet.ru; Prokhorov, V. E., E-mail: prohorov@ipmnet.ru

2016-04-15

Consistent optical and acoustic techniques have been used to study the structure of hydrodynamic disturbances and acoustic signals generated as a free falling drop penetrates water. The relationship between the structures of hydrodynamic and acoustic perturbations arising as a result of a falling drop contacting with the water surface and subsequent immersion into water is traced. The primary acoustic signal is characterized, in addition to stably reproduced features (steep leading edge followed by long decay with local pressure maxima), by irregular high-frequency packets, which are studied for the first time. Reproducible experimental data are used to recognize constant and variablemore » components of the primary acoustic signal.« less

Combining Remotely Sensed Environmental Characteristics with Social and Behavioral Conditions that Affect Surface Water Use in Spatiotemporal Modelling of Schistosomiasis in Ghana

NASA Astrophysics Data System (ADS)

Kulinkina, A. V.; Walz, Y.; Liss, A.; Kosinski, K. C.; Biritwum, N. K.; Naumova, E. N.

2016-06-01

Schistosoma haematobium transmission is influenced by environmental conditions that determine the suitability of the parasite and intermediate host snail habitats, as well as by socioeconomic conditions, access to water and sanitation infrastructure, and human behaviors. Remote sensing is a demonstrated valuable tool to characterize environmental conditions that support schistosomiasis transmission. Socioeconomic and behavioral conditions that propagate repeated domestic and recreational surface water contact are more difficult to quantify at large spatial scales. We present a mixed-methods approach that builds on the remotely sensed ecological variables by exploring water and sanitation related community characteristics as independent risk factors of schistosomiasis transmission.

Water-elevation, stream-discharge, and ground-water quality data in the Alaska Railroad Industrial Area, Fairbanks, Alaska, May 1993 to May 1995

USGS Publications Warehouse

Kriegler, A.T.; Lilly, M.R.

1995-01-01

From May 1993 to May 1995, the U.S. Geological Survey in cooperation with the Alaska Department of Natural Resources, Division of Mining and Water Management collected data on ground-water and surface-water elevations, stream discharge, and ground-water quality in the Alaska Railroad Industrial area in Fairbanks, Alaska. The data- collection efforts were coordinated with environmental efforts being made in the study area by the Alaska Railroad Corporation. These data were collected as part of an effort to characterize the hydrogeology of the Alaska Railroad Industrial area and to define the extent of petroleum hydrocarbons in the area. Ground-water data were collected at 52 observation wells, surface-water data at 12 sites, stream discharge data at 9 sites, and chemical water-quality data at 32 observation wells.

Single particle ICP-MS characterization of titanium dioxide, silver, and gold nanoparticles during drinking water treatment.

PubMed

Donovan, Ariel R; Adams, Craig D; Ma, Yinfa; Stephan, Chady; Eichholz, Todd; Shi, Honglan

2016-02-01

One of the most direct means for human exposure to nanoparticles (NPs) released into the environment is drinking water. Therefore, it is critical to understand the occurrence and fate of NPs in drinking water systems. The objectives of this study were to develop rapid and reliable analytical methods and apply them to investigate the fate and transportation of NPs during drinking water treatments. Rapid single particle ICP-MS (SP-ICP-MS) methods were developed to characterize and quantify titanium-containing, titanium dioxide, silver, and gold NP concentration, size, size distribution, and dissolved metal element concentration in surface water and treated drinking water. The effectiveness of conventional drinking water treatments (including lime softening, alum coagulation, filtration, and disinfection) to remove NPs from surface water was evaluated using six-gang stirrer jar test simulations. The selected NPs were nearly completely (97 ± 3%) removed after lime softening and alum coagulation/activated carbon adsorption treatments. Additionally, source and drinking waters from three large drinking water treatment facilities utilizing similar treatments with the simulation test were collected and analyzed by the SP-ICP-MS methods. Ti-containing particles and dissolved Ti were present in the river water samples, but Ag and Au were not present. Treatments used at each drinking water treatment facility effectively removed over 93% of the Ti-containing particles and dissolved Ti from the source water. Copyright © 2015 Elsevier Ltd. All rights reserved.

Surface force and vibrational spectroscopic analyses of interfacial water molecules in the vicinity of methoxy-tri(ethylene glycol)-terminated monolayers: mechanisms underlying the effect of lateral packing density on bioinertness.

PubMed

Sekine, Taito; Asatyas, Syifa; Sato, Chikako; Morita, Shigeaki; Tanaka, Masaru; Hayashi, Tomohiro

Unequivocal dependence of bioinertness of self-assembled monolayers of methoxy-tri(ethylene glycol)-terminated alkanethiol (EG3-OMe SAMs) on their packing density has been a mystery for more than two decades. We tackled this long-standing question by performing surface force and surface-enhanced infrared absorption (SEIRA) spectroscopic measurements. Our surface force measurements revealed a physical barrier of interfacial water in the vicinity of the Au-supported EG3-OMe SAM (low packing density), whereas the Ag-supported one (high packing density) did not possess such interfacial water. In addition, the results of SEIRA measurements clearly exhibited that hydrogen bonding states of the interfacial water differ depending on the substrates. We also characterized the bioinertness of these SAMs by protein adsorption tests and adhesion assays of platelet and human umbilical vein endothelial cells. The hydrogen bonding states of the interfacial water and water-induced interaction clearly correlated with the bioinertness of the SAMs, suggesting that the interfacial water plays an important role determining the interaction of the SAMs with biomolecules and cells.

Suitability of temperature, hydraulic heads, and acesulfame to quantify wastewater-related fluxes in the hyporheic and riparian zone

NASA Astrophysics Data System (ADS)

Engelhardt, Irina; Prommer, Henning; Moore, Catherine; Schulz, Manoj; Schüth, Christoph; Ternes, Thomas A.

2013-01-01

Groundwater and surface water are in many cases closely linked components of the water cycle with respect to both quantity and quality. Bank filtrates may eventually be impacted by the infiltration of wastewater-derived micropollutants from surface waters. Artificial sweeteners such as acesulfame have recently been reported as a novel class of potentially valuable tracers to study the fate of wastewater-derived substances in groundwater and, in particular, to determine the (bio)degradability of micropollutants. In this paper, a model-based analysis of a field experiment within the hyporheic and riparian zone of a highly polluted German stream was performed to assess the physical and chemical behavior of the artificial sweetener acesulfame. In the first part of this study, a reliable flow and transport model was established by jointly using hydraulic heads, temperatures, and acesulfame concentrations as inverse model calibration constraints. The analysis confirmed the conservative behavior of acesulfame and, therefore, its usability as an indicator of sewage flux provenance. However, a comparison of the appropriateness of hydraulic head, temperature, and acesulfame concentrations revealed that the characterization of the surface water-groundwater flux data indicated diurnal temperature fluctuations are the best indicator in terms of characterizing the flow and transport behavior in the groundwater system.

Characterization of Free Surface-Bound and Entrapped Water Environments in Poly(N-Isopropyl Acrylamide) Hydrogels via 1H HRMAS PFG NMR Spectroscopy

DOE PAGES

Alam, Todd Michael; Childress, Kimberly Kay; Pastoor, Kevin; ...

2014-09-19

We found that different water environments in poly(N-isopropyl acrylamide) (PNIPAAm) hydrogels are identified and characterized using 1H high resolution magic angle spinning (HRMAS) nuclear magnetic resonance (NMR). Local water environments corresponding to a “free” highly mobile species, along with waters showing restricted dynamics are resolved in these swollen hydro-gels. For photo-initiated polymerized PNIPAAm gels, an additional entrapped water species is observed. Spin–spin R 2 relaxation experiments support the argument of reduced mobility in the restricted and entrapped water species. Furthermore, by combining pulse field gradient techniques with HRMAS NMR it is possible to directly measure the self-diffusion rate for thesemore » different water environments. The behavior of the heterogeneous water environments through the lower critical solution temperature transition is described.« less

The Relationship Between Microscopic Grain Surface Structure and the Dynamic Capillary-Driven Advance of Water Films over Individual Dry Natural Sand Grains

NASA Astrophysics Data System (ADS)

Kibbey, T. C. G.; Adegbule, A.; Yan, S.

2017-12-01

The movement of nonvolatile solutes in unsaturated porous media at low water contents depends on transport in surface-associated water films. The focus of the work described here was on studying solute movement in water films advancing by capillary forces over initially-dry grain surfaces, to understand how microscopic surface roughness features influence the initial velocity of water film advance. For this work, water containing a non-adsorbing conservative tracer was used to track the movement of advancing water films. A stainless steel capillary tube connected to an external reservoir a fixed distance below the grain surface was used to transmit solution to the grain surface under negative pressure (positive capillary pressure), consistent with conditions that might be expected in the unsaturated zone. The small internal diameter of the capillary prevents solution from draining out of the capillary back into the reservoir. When the capillary is contacted with a grain surface, capillary forces that result from contact between the fluid and the rough grain surface cause water films to wick across the grain surface. Multiple experiments were conducted on the same grain, rotating the grain and varying the capillary contact point around the circumference of the grain. Imaging was conducted at fixed intervals using an automated Extended Depth of Field (EDF) imaging system, and images were analyzed to determine initial velocity. Grain surfaces were then characterized through scanning electron microscope (SEM) imaging, using a hybrid stereoscopic reconstruction method designed to extract maximum detail in creating elevation maps of geologic surfaces from tilted pairs of SEM images. The resulting elevation maps were used to relate surface roughness profiles around the grain with initial velocities. Results suggest that velocity varies significant with contact point around an individual grain, and correlates quantitatively with the local grain surface structure. Preliminary simulation results will also be discussed.

Farm water budgets for semiarid irrigated floodplains of northern New Mexico: characterizing the surface water-groundwater interactions

NASA Astrophysics Data System (ADS)

Gutierrez, K. Y.; Fernald, A.; Ochoa, C. G.; Guldan, S. J.

2013-12-01

KEY WORDS - Hydrology, Water budget, Deep percolation, Surface water-Groundwater interactions. With the recent projections for water scarcity, water balances have become an indispensable water management tool. In irrigated floodplains, deep percolation from irrigation can represent one of the main aquifer recharge sources. A better understanding of surface water and groundwater interactions in irrigated valleys is needed for properly assessing the water balances in these systems and estimating potential aquifer recharge. We conducted a study to quantify the parameters and calculate the water budgets in three flood irrigated hay fields with relatively low, intermediate and, high water availability in northern New Mexico. We monitored different hydrologic parameters including total amount of water applied, change in soil moisture, drainage below the effective root zone, and shallow water level fluctuations in response to irrigation. Evapotranspiration was calculated from weather station data collected in-situ using the Samani-Hargreaves. Previous studies in the region have estimated deep percolation as a residual parameter of the water balance equation. In this study, we used both, the water balance method and actual measurements of deep percolation using passive lysimeters. Preliminary analyses for the three fields show a relatively rapid movement of water through the upper 50 cm of the vadose zone and a quick response of the shallow aquifer under flood irrigation. Further results from this study will provide a better understanding of surface water-groundwater interactions in flood irrigated valleys in northern New Mexico.

SH-wave refraction/reflection and site characterization

USGS Publications Warehouse

Wang, Z.; Street, R.L.; Woolery, E.W.; Madin, I.P.

2000-01-01

Traditionally, nonintrusive techniques used to characterize soils have been based on P-wave refraction/reflection methods. However, near-surface unconsolidated soils are oftentimes water-saturated, and when groundwater is present at a site, the velocity of the P-waves is more related to the compressibility of the pore water than to the matrix of the unconsolidated soils. Conversely, SH-waves are directly relatable to the soil matrix. This makes SH-wave refraction/reflection methods effective in site characterizations where groundwater is present. SH-wave methods have been used extensively in site characterization and subsurface imaging for earthquake hazard assessments in the central United States and western Oregon. Comparison of SH-wave investigations with geotechnical investigations shows that SH-wave refraction/reflection techniques are viable and cost-effective for engineering site characterization.

Influence of surface structure and chemistry on water droplet splashing.

PubMed

Koch, Kerstin; Grichnik, Roland

2016-08-06

Water droplet splashing and aerosolization play a role in human hygiene and health systems as well as in crop culturing. Prevention or reduction of splashing can prevent transmission of diseases between animals and plants and keep technical systems such as pipe or bottling systems free of contamination. This study demonstrates to what extent the surface chemistry and structures influence the water droplet splashing behaviour. Smooth surfaces and structured replicas of Calathea zebrina (Sims) Lindl. leaves were produced. Modification of their wettability was done by coating with hydrophobizing and hydrophilizing agents. Their wetting was characterized by contact angle measurement and splashing behaviour was observed with a high-speed video camera. Hydrophobic and superhydrophilic surfaces generally showed fewer tendencies to splash than hydrophobic ones. Structuring amplified the underlying behaviour of the surface chemistries, increasing hydrophobic surfaces' tendency to splash and decreasing splash on hydrophilic surfaces by quickly transporting water off the impact point by capillary forces. The non-porous surface structures found in C. zebrina could easily be applied to technical products such as plastic foils or mats and coated with hydrophilizing agents to suppress splash in areas of increased hygiene requirements or wherever pooling of liquids is not desirable.This article is part of the themed issue 'Bioinspired hierarchically structured surfaces for green science'. © 2016 The Author(s).

Molecular layer deposition of APTES on silicon nanowire biosensors: Surface characterization, stability and pH response

NASA Astrophysics Data System (ADS)

Liang, Yuchen; Huang, Jie; Zang, Pengyuan; Kim, Jiyoung; Hu, Walter

2014-12-01

We report the use of molecular layer deposition (MLD) for depositing 3-aminopropyltriethoxysilane (APTES) on a silicon dioxide surface. The APTES monolayer was characterized using spectroscopic ellipsometry, contact angle goniometry, and atomic force microscopy. Effects of reaction time of repeating pulses and simultaneous feeding of water vapor with APTES were tested. The results indicate that the synergistic effects of water vapor and reaction time are significant for the formation of a stable monolayer. Additionally, increasing the number of repeating pulses improved the APTES surface coverage but led to saturation after 10 pulses. In comparing MLD with solution-phase deposition, the APTES surface coverage and the surface quality were nearly equivalent. The hydrolytic stability of the resulting films was also studied. The results confirmed that the hydrolysis process was necessary for MLD to obtain stable surface chemistry. Furthermore, we compared the pH sensing results of Si nanowire field effect transistors (Si NWFETs) modified by both the MLD and solution methods. The highly repeatable pH sensing results reflected the stability of APTES monolayers. The results also showed an improved pH response of the sensor prepared by MLD compared to the one prepared by the solution treatment, which indicated higher surface coverage of APTES.

Evaluation of agricultural best-management practices in the Conestoga River headwaters, Pennsylvania : characterization of surface-runoff and ground-water quantity and quality in a small carbonate basin near Churchtown, Pennsylvania, prior to terracing and implementation of nutrient management : water-quality study of the Conestoga River headwaters, Pennsylvania

USGS Publications Warehouse

Leitman, Patricia L.; Hall, D.W.; Langland, M.J.; Chichester, D.C.; Ward, J.R.

1996-01-01

Surface-runoff and ground-water quantity and quality of a 22.1-acre field site were characterized from January 1983 through September 1984, before implementation of terracing and nutrient-management practices. The site, underlain by carbonate rock, was cropland used primarily for the production of corn and alfalfa. Average annual application of nutrients to the 14.4 acres of cornfields was 410 pounds of nitrogen and 110 pounds of phosphorus. About three times more nutrients were applied during the 1984 water year than during the 1983 water year. During the investigation, 714,000 cubic feet of runoff transported 244 tons of suspended sediment, 300 pounds of nitrogen, and 170 pounds of phosphorus during the 1984 water year. Runoff from storms on frozen ground produced the highest loads of nitrogen. Regression analyses indicate that runoff rates and quantities were controlled by precipitation intensities of quantities and the amount of crop cover, and that mean concentrations of nitrogen for runoff events increased with increased surface-nitrogen applications made prior to runoff. Ground-water levels responded quickly to recharge, with peaks occurring several hours to a day after precipitation. Median concentrations of dissolved nitrate in ground water ranged from 9.2 to 13 milligrams per liter as nitrogen. A lag time of 1 to 3 months was observed between the time that nitrogen was applied to the land surface and local maximums in nitrate concentrations were detected in ground water unaffected by recharge events. About 3 million cubic feet of ground water and an associated 2,200 pounds of nitrate-nitrogen discharged from the site during the study period. For the study period, 42 percent of the precipitation recharged to ground water, 10 percent became runoff, and 48 percent evapotranspired. Inputs of nitrogen to the study area were estimated to be 93 percent from manure, 5 percent from commercial fertilizer, and 2 percent from precipitation. Nitrogen outputs from the system were estimated to be 38 percent to crop uptake, 39 percent to volatilization, 20 percent to ground- water discharge, and 3 percent to surface runoff.

Interaction between Air Bubbles and Superhydrophobic Surfaces in Aqueous Solutions.

PubMed

Shi, Chen; Cui, Xin; Zhang, Xurui; Tchoukov, Plamen; Liu, Qingxia; Encinas, Noemi; Paven, Maxime; Geyer, Florian; Vollmer, Doris; Xu, Zhenghe; Butt, Hans-Jürgen; Zeng, Hongbo

2015-07-07

Superhydrophobic surfaces are usually characterized by a high apparent contact angle of water drops in air. Here we analyze the inverse situation: Rather than focusing on water repellency in air, we measure the attractive interaction of air bubbles and superhydrophobic surfaces in water. Forces were measured between microbubbles with radii R of 40-90 μm attached to an atomic force microscope cantilever and submerged superhydrophobic surfaces. In addition, forces between macroscopic bubbles (R = 1.2 mm) at the end of capillaries and superhydrophobic surfaces were measured. As superhydrophobic surfaces we applied soot-templated surfaces, nanofilament surfaces, micropillar arrays with flat top faces, and decorated micropillars. Depending on the specific structure of the superhydrophobic surfaces and the presence and amount of entrapped air, different interactions were observed. Soot-templated surfaces in the Cassie state showed superaerophilic behavior: Once the electrostatic double-layer force and a hydrodynamic repulsion were overcome, bubbles jumped onto the surface and fully merged with the entrapped air. On nanofilaments and micropillar arrays we observed in addition the formation of sessile bubbles with finite contact angles below 90° or the attachment of bubbles, which retained their spherical shape.

Surface-water quality assessment of the North Fork Red River basin upstream from Lake Altus, Oklahoma, 2002

USGS Publications Warehouse

Smith, S. Jerrod; Schneider, M.L.; Masoner, J.R.; Blazs, R.L.

2003-01-01

Elevated salinity in the North Fork Red River is a major concern of the Bureau of Reclamation W. C. Austin Project at Lake Altus. Understanding the relation between surface-water runoff, ground-water discharge, and surface-water quality is important for maintaining the beneficial use of water in the North Fork Red River basin. Agricultural practices, petroleum production, and natural dissolution of salt-bearing bedrock have the potential to influence the quality of nearby surface water. The U.S. Geological Survey, in cooperation with the Bureau of Reclamation, sampled stream discharge and water chemistry at 19 stations on the North Fork Red River and tributaries. To characterize surface-water resources of the basin in a systematic manner, samples were collected synoptically during receding streamflow conditions during July 8-11, 2002. Together, sulfate and chloride usually constitute greater than half of the dissolved solids. Concentrations of sulfate ranged from 87.1 to 3,450 milligrams per liter. The minimum value was measured at McClellan Creek near Back (07301220), and the maximum value was measured at Bronco Creek near Twitty (07301303). Concentrations of chloride ranged from 33.2 to 786 milligrams per liter. The minimum value was measured at a North Fork Red River tributary (unnamed) near Twitty (07301310), and the maximum value was measured at the North Fork Red River near Back (07301190), the most upstream sample station.

Characterizing the interaction of groundwater and surface water in the karst aquifer of Fangshan, Beijing (China)

NASA Astrophysics Data System (ADS)

Chu, Haibo; Wei, Jiahua; Wang, Rong; Xin, Baodong

2017-03-01

Correct understanding of groundwater/surface-water (GW-SW) interaction in karst systems is of greatest importance for managing the water resources. A typical karst region, Fangshan in northern China, was selected as a case study. Groundwater levels and hydrochemistry analyses, together with isotope data based on hydrogeological field investigations, were used to assess the GW-SW interaction. Chemistry data reveal that water type and the concentration of cations in the groundwater are consistent with those of the surface water. Stable isotope ratios of all samples are close to the local meteoric water line, and the 3H concentrations of surface water and groundwater samples are close to that of rainfall, so isotopes also confirm that karst groundwater is recharged by rainfall. Cross-correlation analysis reveals that rainfall leads to a rise in groundwater level with a lag time of 2 months and groundwater exploitation leads to a fall within 1 month. Spectral analysis also reveals that groundwater level, groundwater exploitation and rainfall have significantly similar response periods, indicating their possible inter-relationship. Furthermore, a multiple nonlinear regression model indicates that groundwater level can be negatively correlated with groundwater exploitation, and positively correlated with rainfall. The overall results revealed that groundwater level has a close correlation with groundwater exploitation and rainfall, and they are indicative of a close hydraulic connection and interaction between surface water and groundwater in this karst system.

A long history of equatorial deep-water upwelling in the Pacific Ocean

NASA Astrophysics Data System (ADS)

Zhang, Yi Ge; Pagani, Mark; Henderiks, Jorijntje; Ren, Haojia

2017-06-01

Cold, nutrient- and CO2-rich waters upwelling in the eastern equatorial Pacific (EEP) give rise to the Pacific cold tongue. Quasi-periodic subsidence of the thermocline and attenuation in wind strength expressed by El Niño conditions decrease upwelling rates, increase surface-water temperatures in the EEP, and lead to changes in regional climates both near and far from the equatorial Pacific. EEP surface waters have elevated CO2 concentrations during neutral (upwelling) or La Niña (strong upwelling) conditions. In contrast, approximate air-sea CO2 equilibrium characterizes El Niño events. One hypothesis proposes that changes in physical oceanography led to the establishment of a deep tropical thermocline and expanded mixed-layer prior to 3 million years ago. These effects are argued to have substantially reduced deep-water upwelling rates in the EEP and promoted a "permanent El Niño-like" climate state. For this study, we test this supposition by reconstructing EEP "excess CO2" and upwelling history for the past 6.5 million years using the alkenone-pCO2 methodology. Contrary to previous assertions, our results indicate that average temporal conditions in the EEP over the past ∼6.5 million years were characterized by substantial CO2 disequilibrium and high nutrient delivery to surface waters - characteristics that imply strong upwelling of deep waters. Upwelling appears most vigorous between ∼6.5 to 4.5 million years ago coinciding with high accumulation rates of biogenic material during the late Miocene - early Pliocene "biogenic bloom".

Quantifying Water Stress Using Total Water Volumes and GRACE

NASA Astrophysics Data System (ADS)

Richey, A. S.; Famiglietti, J. S.; Druffel-Rodriguez, R.

2011-12-01

Water will follow oil as the next critical resource leading to unrest and uprisings globally. To better manage this threat, an improved understanding of the distribution of water stress is required today. This study builds upon previous efforts to characterize water stress by improving both the quantification of human water use and the definition of water availability. Current statistics on human water use are often outdated or inaccurately reported nationally, especially for groundwater. This study improves these estimates by defining human water use in two ways. First, we use NASA's Gravity Recovery and Climate Experiment (GRACE) to isolate the anthropogenic signal in water storage anomalies, which we equate to water use. Second, we quantify an ideal water demand by using average water requirements for the domestic, industrial, and agricultural water use sectors. Water availability has traditionally been limited to "renewable" water, which ignores large, stored water sources that humans use. We compare water stress estimates derived using either renewable water or the total volume of water globally. We use the best-available data to quantify total aquifer and surface water volumes, as compared to groundwater recharge and surface water runoff from land-surface models. The work presented here should provide a more realistic image of water stress by explicitly quantifying groundwater, defining water availability as total water supply, and using GRACE to more accurately quantify water use.

Baseline risk assessment of ground water contamination at the uranium mill tailings site near Durango, Colorado. Revision 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1995-09-01

For the UMTRA Project site located near Durango, Colorado (the Durango site), the Surface Project cleanup occurred from 1986 to 1991. An evaluation was made to determine whether exposure to ground water contaminated by uranium processing could affect people`s health. Exposure could occur from drinking water pumped from a hypothetical well drilled in the contaminated ground water area. In addition, environmental risks may result if plants or animals are exposed to contaminated ground water, or surface water that has mixed with contaminated ground water. This risk assessment report is the first site-specific document prepared for the UMTRA Ground Water Projectmore » at the Durango site. The results of this report and further site characterization of the Durango site will be used to determine what is necessary to protect public health and the environment, and to comply with the EPA standards.« less

Enterococcus in surface waters from the Des Moines River (Iowa) watershed: location, persistence and vancomycin resistance.

PubMed

Larsen, Bryan; Essmann, Michael K; Geletta, Simon; Duff, Barbara

2012-01-01

The object of this study was to quantify vancomycin-resistant enterococci in surface water from Central Iowa obtained from April 2007 to August 2007. Water from established sampling sites in four watersheds was plated on bile-esculin agar. Presumptively identified enterococci were categorized as "above the level of concern" if the sample contained ≥ 107 CFU per 100 ml. Confirmation of isolates as enterococci was based on growth at elevated temperature in high salt and on Enterococcus agar. Isolates that grew on 6 μg/ml vancomycin agar were deemed resistant. PCR analysis of resistant strains characterized vancomycin resistance genes. 77.2% of surface water samples from Central Iowa contained enterococci. Among enterococcal isolates, 10.4% grew on media containing 6 μg/ml vancomycin. PCR analysis of resistance genes showed a preponderance of VanC2/C3 in the area studied and VanB was not detected. Vancomycin-resistant Enterococcus is present in Central Iowa surface waters but resistance rarely involved VanA genotypes. Nevertheless, the potential for community-acquired infections remains a risk.

Development and assessment of photo-catalytic membranes for water purification using solar radiation

NASA Astrophysics Data System (ADS)

Coto, M.; Troughton, S. C.; Duan, J.; Kumar, R. V.; Clyne, T. W.

2018-03-01

This paper describes a novel set-up for characterization of the performance of membranes designed for purification of water. It involves a recirculatory system, with continuous monitoring of the concentration in the water of a representative pollutant (Methylene Blue). Pressures, flow rates and temperatures are also measured. Results, in the form of rate constants for reduction in pollutant concentration, are presented for three different types of membrane, all of which incorporate relatively high surface areas of titania and have permeability values in a range making them suitable for this type of processing (∼10-11 m2). These results are rationalized in terms of the surface areas of the membranes, and the likely water flow characteristics within them. It is concluded that all of the titania surfaces within them have similar efficiencies for photo-catalytic oxidation of pollutants, but there are significant differences in the ways that the water is exposed to these surfaces, and hence in the pollutant oxidation rates. These points are relevant to the optimization of membrane design for this purpose.

Flying fish accelerate at 5 G to leap from the water surface

NASA Astrophysics Data System (ADS)

Yang, Patricia; Phonekeo, Sulisay; Xu, Ke; Chang, Shui-Kai; Hu, David

2013-11-01

Flying fish can both swim underwater and glide in air. Transitioning from swimming to gliding requires penetration of the air-water interface, or breaking the ``surface tension barrier,'' a formidable task for juvenile flying fish measuring 1 to 5 cm in length. In this experimental investigation, we use high-speed videography to characterize the kinematics of juvenile flying fish as they leap from the water surface. During this process, which lasts 0.05 seconds, flying fish achieve body accelerations of 5 times earth's gravity and gliding speeds of 1.3 m/s, an order of magnitude higher than their steady swimming speed. We rationalize this anomalously high speed on the basis of the hydrodynamic and surface tension forces and torques experienced by the fish. Specifically, leaping fish experience skin friction forces only on the submerged part of their body, permitting them to achieve much higher speeds than in steady underwater swimming. We also perform experiments using a towed flying fish mimc to determine optimality of various parameters in this process, including body angle and start position with respect to the water surface.

Surface-Water and Ground-Water Resources of Kendall County, Illinois

USGS Publications Warehouse

Kay, Robert T.; Mills, Patrick C.; Hogan, Jennifer L.; Arnold, Terri L.

2005-01-01

Water-supply needs in Kendall County, in northern Illinois, are met exclusively from ground water derived from glacial drift aquifers and bedrock aquifers open to Silurian, Ordovician, and Cambrian System units. As a result of population growth in Kendall County and the surrounding area, water use has increased from about 1.2 million gallons per day in 1957 to more than 5 million gallons per day in 2000. The purpose of this report is to characterize the surface-water and ground-water resources of Kendall County. The report presents a compilation of available information on geology, surface-water and ground-water hydrology, water quality, and water use. The Fox River is the primary surface-water body in Kendall County and is used for both wastewater disposal and as a drinking-water supply upstream of the county. Water from the Fox River requires pretreatment for use as drinking water, but the river is a potentially viable additional source of water for the county. Glacial drift aquifers capable of yielding sufficient water for municipal supply are expected to be present in northern Kendall County, along the Fox River, and in the Newark Valley and its tributaries. Glacial drift aquifers capable of yielding sufficient water for residential supply are present in most of the county, with the exception of the southeastern portion. Volatile organic compounds and select trace metals and pesticides have been detected at low concentrations in glacial drift aquifers near waste-disposal sites. Agricultural-related constituents have been detected infrequently in glacial drift aquifers near agricultural areas. However, on the basis of the available data, widespread, consistent problems with water quality are not apparent in these aquifers. These aquifers are a viable source for additional water supply, but would require further characterization prior to full development. The shallow bedrock aquifer is composed of the sandstone units of the Ancell Group, the Prairie du Chien Group, the Galena-Platteville dolomite, the Maquoketa Group, and the Silurian dolomite where these units are at the bedrock surface. The availability of water from the shallow bedrock aquifer depends primarily on the geologic unit utilized. The Silurian dolomite, Galena-Platteville dolomite, and Ancell Group can yield sufficient water for residential and municipal supply in at least some parts of the county. The Cambrian-Ordovician aquifer system is composed of the most widespread, productive aquifers in northern Illinois and is used for water supply by a number of municipalities and industrial facilities. Water levels in the aquifer system have declined by as much as 600 feet in Kendall County and the aquifer frequently contains concentrations of radium above established health guidelines.

Detection and Characterization of Deep Water Wave Breaking Using Moderate Incidence Angle Microwave Backscatter from the Sea Surface

DTIC Science & Technology

1990-06-01

interaction and wave breaking. The ocean surface can be modelled as a two-scale or composite surface - 21 - made up of short wind-generated ripples... composite or two-scale rough surface (Barrick and Peake, 1968). For radar wavelengths on the order of a few centimeters, the resonant scatterers are...short wind ripples which ride on top of long gravity waves, and a - 46 - composite model is used to describe the two-scale nature of the sea surface

Silage storage runoff characterization: Annual nutrient loading rate and first flush analysis of bunder silos

USDA-ARS?s Scientific Manuscript database

Silage runoff produced during the preservation and storage of dairy forage in horizontal bunkers is a source of nutrient loss from the farmstead and a threat to surface water quality. This research evaluated the runoff characteristics from six dairy bunker facilities to determine runoff water qualit...

Characterizing mercury concentrations and fluxes in a coastal plain watershed: insights from dynamic modeling and data

EPA Science Inventory

Mercury (Hg) is one of the leading water quality concerns in surface waters of the United States (U.S.). Although watershed-scale Hg cycling research has escalated in the past two decades, advances in the modeling of watershed Hg cycling processes in diverse physiographic regions...

PERCHLORATE ENVIRONMENTAL CONTAMINATION: TOXICOLOGICAL REVIEW AND RISK CHARACTERIZATION BASED ON EMERGING INFORMATION (EXTERNAL REVIEW DRAFT) 1998

EPA Science Inventory

Perchlorate (ClO4-) is an anion that originates as a contaminant in ground water and surface waters from the dissolution of ammonium, potassium, magnesium, or sodium salts. Because perchlorate is nonlabile kinetically (i.e., the reduction of the central chlorine atom occurs extre...

Micelle-template synthesis of hollow silica spheres for improving water vapor permeability of waterborne polyurethane membrane

PubMed Central

Bao, Yan; Wang, Tong; Kang, Qiaoling; Shi, Chunhua; Ma, Jianzhong

2017-01-01

Hollow silica spheres (HSS) with special interior spaces, high specific surface area and excellent adsorption and permeability performance were synthesized via micelle-template method using cetyl trimethyl ammonium bromide (CTAB) micelles as soft template and tetraethoxysilane (TEOS) as silica precursor. SEM, TEM, FT-IR, XRD, DLS and BET-BJH were carried out to characterize the morphology and structure of as-obtained samples. The results demonstrated that the samples were amorphous with a hollow structure and huge specific surface area. The growth of HSS was an inward-growth mechanism along template. Notably, we have provided a new and interesting fundamental principle for HSS materials by precisely controlling the ethanol-to-water volume ratio. In addition, the as-obtained HSS were mixed with waterborne polyurethane (WPU) to prepare WPU/HSS composite membrane. Various characterizations (SEM, TEM, FT-IR and TGA) revealed the morphology, polydispersity and adherence between HSS and WPU. Performance tests showed that the introduction of HSS can improve the water vapor permeability of composite membrane, promoting its water resistance and mechanical performance at the same time. PMID:28429740

Micelle-template synthesis of hollow silica spheres for improving water vapor permeability of waterborne polyurethane membrane

NASA Astrophysics Data System (ADS)

Bao, Yan; Wang, Tong; Kang, Qiaoling; Shi, Chunhua; Ma, Jianzhong

2017-04-01

Hollow silica spheres (HSS) with special interior spaces, high specific surface area and excellent adsorption and permeability performance were synthesized via micelle-template method using cetyl trimethyl ammonium bromide (CTAB) micelles as soft template and tetraethoxysilane (TEOS) as silica precursor. SEM, TEM, FT-IR, XRD, DLS and BET-BJH were carried out to characterize the morphology and structure of as-obtained samples. The results demonstrated that the samples were amorphous with a hollow structure and huge specific surface area. The growth of HSS was an inward-growth mechanism along template. Notably, we have provided a new and interesting fundamental principle for HSS materials by precisely controlling the ethanol-to-water volume ratio. In addition, the as-obtained HSS were mixed with waterborne polyurethane (WPU) to prepare WPU/HSS composite membrane. Various characterizations (SEM, TEM, FT-IR and TGA) revealed the morphology, polydispersity and adherence between HSS and WPU. Performance tests showed that the introduction of HSS can improve the water vapor permeability of composite membrane, promoting its water resistance and mechanical performance at the same time.

Micelle-template synthesis of hollow silica spheres for improving water vapor permeability of waterborne polyurethane membrane.

PubMed

Bao, Yan; Wang, Tong; Kang, Qiaoling; Shi, Chunhua; Ma, Jianzhong

2017-04-21

Hollow silica spheres (HSS) with special interior spaces, high specific surface area and excellent adsorption and permeability performance were synthesized via micelle-template method using cetyl trimethyl ammonium bromide (CTAB) micelles as soft template and tetraethoxysilane (TEOS) as silica precursor. SEM, TEM, FT-IR, XRD, DLS and BET-BJH were carried out to characterize the morphology and structure of as-obtained samples. The results demonstrated that the samples were amorphous with a hollow structure and huge specific surface area. The growth of HSS was an inward-growth mechanism along template. Notably, we have provided a new and interesting fundamental principle for HSS materials by precisely controlling the ethanol-to-water volume ratio. In addition, the as-obtained HSS were mixed with waterborne polyurethane (WPU) to prepare WPU/HSS composite membrane. Various characterizations (SEM, TEM, FT-IR and TGA) revealed the morphology, polydispersity and adherence between HSS and WPU. Performance tests showed that the introduction of HSS can improve the water vapor permeability of composite membrane, promoting its water resistance and mechanical performance at the same time.

Characterizing droplet kinetic energy applied by moving spray-plate center pivot irrigation sprinklers

USDA-ARS?s Scientific Manuscript database

The kinetic energy of discrete drops impacting a bare soil surface is generally observed to lead to a drastic reduction in water infiltration rate due to soil surface seal formation. Under center pivot sprinkler irrigation, kinetic energy transferred to the soil prior to crop canopy development can...

Visible light activated TiO2/microcrystalline cellulose nanocatalyst to destroy organic contaminants in water.

EPA Science Inventory

Hybrid TiO2/microcrystalline cellulose (MC) nanophotocatalyst was prepared in situ by a facile and simple synthesis utilizing benign precursors such as MC and TiCl4. The as-prepared nanocomposite was characterized by XRD, XPS, BET surface area analyzer, UV–vis DRS and TGA. Surfac...

Characterization of surface and ground water δ18O seasonal variation and its use for estimating groundwater residence times

USGS Publications Warehouse

Reddy, Michael M.; Schuster, Paul; Kendall, Carol; Reddy, Micaela B.

2006-01-01

18O is an ideal tracer for characterizing hydrological processes because it can be reliably measured in several watershed hydrological compartments. Here, we present multiyear isotopic data, i.e. 18O variations (δ18O), for precipitation inputs, surface water and groundwater in the Shingobee River Headwaters Area (SRHA), a well-instrumented research catchment in north-central Minnesota. SRHA surface waters exhibit δ18O seasonal variations similar to those of groundwaters, and seasonal δ18O variations plotted versus time fit seasonal sine functions. These seasonal δ18O variations were interpreted to estimate surface water and groundwater mean residence times (MRTs) at sampling locations near topographically closed-basin lakes. MRT variations of about 1 to 16 years have been estimated over an area covering about 9 km2 from the basin boundary to the most downgradient well. Estimated MRT error (±0·3 to ±0·7 years) is small for short MRTs and is much larger (±10 years) for a well with an MRT (16 years) near the limit of the method. Groundwater transit time estimates based on Darcy's law, tritium content, and the seasonal δ18O amplitude approach appear to be consistent within the limits of each method. The results from this study suggest that use of the δ18O seasonal variation method to determine MRTs can help assess groundwater recharge areas in small headwaters catchments.

Characterization of surface and ground water δ18O seasonal variation and its use for estimating groundwater residence times

USGS Publications Warehouse

Reddy, Michael M.; Schuster, Paul F.; Kendall, Carol; Reddy, Micaela B.

2006-01-01

18O is an ideal tracer for characterizing hydrological processes because it can be reliably measured in several watershed hydrological compartments. Here, we present multiyear isotopic data, i.e. 18O variations (δ18O), for precipitation inputs, surface water and groundwater in the Shingobee River Headwaters Area (SRHA), a well-instrumented research catchment in north-central Minnesota. SRHA surface waters exhibit δ18O seasonal variations similar to those of groundwaters, and seasonal δ18O variations plotted versus time fit seasonal sine functions. These seasonal δ18O variations were interpreted to estimate surface water and groundwater mean residence times (MRTs) at sampling locations near topographically closed-basin lakes. MRT variations of about 1 to 16 years have been estimated over an area covering about 9 km2 from the basin boundary to the most downgradient well. Estimated MRT error (±0·3 to ±0·7 years) is small for short MRTs and is much larger (±10 years) for a well with an MRT (16 years) near the limit of the method. Groundwater transit time estimates based on Darcy's law, tritium content, and the seasonal δ18O amplitude approach appear to be consistent within the limits of each method. The results from this study suggest that use of the δ18O seasonal variation method to determine MRTs can help assess groundwater recharge areas in small headwaters catchments.

Hydraulic and field water-chemistry characteristics of piedmont alluvial deposits in the Middle Tyger River near Lyman, Spartanburg County, South Carolina, 2005

USGS Publications Warehouse

Harrelson, Larry G.; Addison, Adrian D.

2006-01-01

This study explores the possibility of developing a bank-filtration process to improve water quality in which alluvial deposits serve as a natural sand filter to pretreat water to be used as a secondary drinking-water source in a small piedmont reservoir along the Middle Tyger River near Lyman in Spartanburg County, South Carolina. From January 2004 to September 2005, data from 10 auger borings, 2 sediment cores, 29 ground-penetrating radar transects, and 3 temporary observation wells, and field water-chemistry data were collected and analyzed. These data were collected and used to characterize the lithology, geometry, hydraulic properties, yield potential, and water-chemistry characteristics of the alluvial deposits in the channel and on the right bank of the reservoir. The assessment was undertaken to determine if an adequate amount of water could be withdrawn from the alluvial deposits to sustain a bank-filtration process and to characterize the water chemistry of the surface water and pore water. The heterogeneous alluvial and fill material at the study site--clay, silty clay, clayey sand, fine- to coarse-grained sand, and mica--on the right bank of the Middle Tyger River ranges in thickness from 0.6 to 7 meters, has a calculated horizontal hydraulic conductivity of 1 meter per day, and yields approximately 0.07 liter per second of water. The small calculated horizontal hydraulic conductivity and water yield for these deposits restrict the use of the right bank as a potential bank-filtration site. The coarse-grained alluvial sand deposit in the channel of the Middle Tyger River, however, may be used for a limited bank-filtration process. The discharge during pumping of the channel deposit yielded water at the rate of 1.9 liters per second. The coarse-grained channel deposit is approximately 49 meters wide and 3 meters thick near the dam. At approximately 183 meters upstream from the dam, the channel narrows to roughly 9 meters and the channel deposits thin to approximately 0.1 meter. Slug tests conducted in the channel deposits near the dam produced a calculated horizontal hydraulic conductivity of 60 meters per day. The limited thickness and aerial extent of the coarse-grained channel deposits coupled with large horizontal hydraulic conductivity likely would allow rapid transmission of water and may degrade the effectiveness of some water-chemistry improvements typical of a bank-filtration process. Field water-chemistry data were collected for approximately 1 hour and 45 minutes at 10 to 15 minute intervals to compare the surface-water and pore-water quality in and beneath the channel of the Middle Tyger River. The waterchemistry data indicate that (1) the mean water temperature was higher in surface water (22.5 degrees Celsius) than in pore water (18.5 degrees Celsius), (2) the mean specific conductance was less in surface water (56.9 microsiemens per centimeter at 25 degrees Celsius) than in pore water (125.7 microsiemens per centimeter at 25 degrees Celsius), (3) alkalinity was lower in surface water (22.5 milligrams per liter) than in pore water (44.6 milligrams per liter), and (4) recorded pH values ranged between 6.2 and 6.3 in the surface water and pore water during the sampling period. The flow velocity was orders of magnitude slower in the pore water than in the surface water; therefore, the pore water interacts with the alluvial sediment for a longer period of time producing the variation in water-chemistry data between the two waters.

Recent decline in crop water productivity in the United States: a call to grow "more crop per drop"

NASA Astrophysics Data System (ADS)

Marshall, M. T.; Tu, K. P.; Thenkabail, P.; Brown, J. F.

2016-12-01

Irrigation for agriculture accounts for approximately 80 to 90% of U.S. consumptive water use. Recent declines in freshwater supply for irrigated agriculture in the western U.S. is particularly alarming, because climate change, water withdrawals from growing and competing sectors, and water pollution, are projected to put further strain on this vital sector. Innovative water management strategies are being proposed to combat this eminent water crisis and include: developing water markets, improving crop water productivity (CWP: "more crop per drop"), and coordinating the use of surface and groundwater supplies. The increase in CWP through crop type or variety selection is particularly lucrative, because it aims to increase the marketable yield of a crop, while reducing the cost of consumptive water use. Here we estimated CWP from 2000-2015 for the Contiguous United States over the primary growing season (mid May - late October) using a recently developed and validated light-use efficiency model for estimating crop yield and the transpiration component of the Priestley-Taylor Jet Propulsion Laboratory evapotranspiration model. The models were parameterized with daily DAYMET 1 km meteorological and 7-day EROS Moderate Resolution Imaging Spectroradiometer 250 m vegetation data. An analysis will be performed on CWP and its components to characterize the magnitude, direction, and persistence of trends. CWP estimates and trends will be overlaid with the U.S. Department of Agriculture's Cropland Data Layer to rank major crops by water use versus marketable yield and to characterize intervention hotspots, respectively. County-level data on surface and ground water withdrawals for irrigated agriculture available through the U.S. Geological Survey will be used to further scrutinize emerging patterns. It is anticipated that over much of the irrigated areas of the western U.S. that persistent and decreasing trends in CWP for major water users (e.g. alfalfa) due to temperature-driven increases in atmospheric moisture demand or potential evapotranspiration will correspond to a decrease (increase) in surface (ground) water use for irrigation.

Relation between Enterococcus concentrations and turbidity in fresh and saline recreational waters, coastal Horry County, South Carolina, 2003–04

USGS Publications Warehouse

Landmeyer, James E.; Garigen, Thomas J.

2016-06-24

The positive relation observed between turbidity and Enterococcus concentrations in surface water at the water-quality data collection station located in the channel that drains a freshwater swamp may be attributed to bacterial survival in the abundant channel bed sediments that characterized this more naturalized area. Surface-water bed sediments collected near each water-quality data collection station and the surf zone were incubated in static microcosms in the laboratory and analyzed for Enterococcus concentrations over time. Enterococcus concentrations continued to persist in bed sediments collected in the channel that drains the swamp even after almost 4 months of incubation. Conversely, enterococci were not observed to persist in bed sediments characterized by high specific conductance. Although it is currently (2016) unknown whether this persistence of enterococci demonstrates growth or viability, the data indicate that enterococci can exist in channel bed-sediment environments outside of a host for a long time. This observation confirms previous reports that challenge the use of Enterococcus concentrations as an indicator of the recent introduction of fecal-related material and the associated acute risk to other pathogens.

Self-assembled biomimetic superhydrophobic CaCO3 coating inspired from fouling mineralization in geothermal water.

PubMed

Wang, Gong G; Zhu, Li Q; Liu, Hui C; Li, Wei P

2011-10-18

Inspired from fouling self-mineralization in geothermal water, a novel biomimetic cactuslike CaCO(3) coating with superhydrophobic features is reported in this letter. The structure, morphologies, and phases of the CaCO(3) coating were characterized by X-ray diffractometry, scanning electron microscopy, transmission electron microscopy, and infrared spectrophotometry. After prenucleation treatment, a continuous cactuslike CaCO(3) coating with hierarchical nano- and microstructures was self-assembled on stainless steel surfaces after immersion in simulated geothermal water at 50 °C for 48 h. After being modified with a low-surface-energy monolayer of sodium stearate, the as-prepared coating exhibited superhydrophobic properties with a water contact angle of 158.9° and a sliding angle of 2°. Therefore, this work might open up a new application field of geothermal resources and provide insight into designing multidimensional structures with functional applications, including superhydrophobic surfaces. © 2011 American Chemical Society

Area G perimeter surface-soil and single-stage water sampling: Environmental surveillance for fiscal year 95. Progress report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Childs, M.; Conrad, R.

1997-09-01

ESH-19 personnel collected soil and single-stage water samples around the perimeter of Area G at Los Alamos National Laboratory (LANL) during FY 95 to characterize possible radionuclide movement out of Area G through surface water and entrained sediment runoff. Soil samples were analyzed for tritium, total uranium, isotopic plutonium, americium-241, and cesium-137. The single-stage water samples were analyzed for tritium and plutonium isotopes. All radiochemical data was compared with analogous samples collected during FY 93 and 94 and reported in LA-12986 and LA-13165-PR. Six surface soils were also submitted for metal analyses. These data were included with similar data generatedmore » for soil samples collected during FY 94 and compared with metals in background samples collected at the Area G expansion area.« less

Erosion and flow of hydrophobic granular materials

NASA Astrophysics Data System (ADS)

Utter, Brian; Benns, Thomas; Mahler, Joseph

2013-11-01

We experimentally investigate submerged granular flows of hydrophobic and hydrophilic grains both in a rotating drum geometry and under erosion by a surface water flow. While slurry and suspension flows are common in nature and industry, effects of surface chemistry on flow behavior have received relatively little attention. In the rotating drum , we use varying concentrations of hydrophobic and hydrophilic grains of sand submerged in water rotated at a constant angular velocity. Sequential images of the resulting avalanches are taken and analyzed. High concentrations of hydrophobic grains result in an effectively cohesive interaction between the grains forming aggregates, with aggregate size and repose angle increasing with hydrophobic concentration. However, the formation and nature of the aggregates depends significantly on the presence of air in the system. We present results from a related experiment on erosion by a surface water flow designed to characterize the effects of heterogeneous granular surfaces on channelization and erosion. Supported by NSF CBET Award 1067598.

Erosion and flow of hydrophobic granular materials

NASA Astrophysics Data System (ADS)

Utter, Brian; Benns, Thomas; Foltz, Benjamin; Mahler, Joseph

2015-03-01

We experimentally investigate submerged granular flows of hydrophobic and hydrophilic grains both in a rotating drum geometry and under erosion by a surface water flow. While slurry and suspension flows are common in nature and industry, effects of surface chemistry on flow behavior have received relatively little attention. In the rotating drum, we use varying concentrations of hydrophobic and hydrophilic grains of sand submerged in water rotated at a constant angular velocity. Sequential images of the resulting avalanches are taken and analyzed. High concentrations of hydrophobic grains result in an effectively cohesive interaction between the grains forming aggregates, with aggregate size and repose angle increasing with hydrophobic concentration. However, the formation and nature of the aggregates depends significantly on the presence of air in the system. We present results from a related experiment on erosion by a surface water flow designed to characterize the effects of heterogeneous granular surfaces on channelization and erosion.

Internal processes affecting surfaces of low-density satellites - Ganymede and Callisto

NASA Technical Reports Server (NTRS)

Parmentier, E. M.; Head, J. W.

1979-01-01

Possible significant physical processes on low-density (icy) satellites, particularly Ganymede and Callisto, are outlined, and the relations of these interior processes to the formation and evolution of satellite surfaces are discussed. A variety of mechanisms is shown to lead to interior melting in early satellite history and a configuration characterized by a predominantly water ice lithosphere overlying a mantle containing liquid water. Physical processes capable of affecting the lithosphere of an ice-silicate body and thus creating observable surface features are assessed, including tectonic stresses from tidal deformation and volume changes, gravitational effects on density differences and water volcanism. The residence time of surface features on icy bodies produced by the outlined processes and by impact cratering is considered, and a tentative outline of the geologic history of Ganymede and Callisto is presented. Observations from Voyager and Galileo are expected to provide evidence on the evolution and geologic history of low-density satellites.

Stereolithography of perfluoropolyethers for the microfabrication of robust omniphobic surfaces

NASA Astrophysics Data System (ADS)

Credi, Caterina; Levi, Marinella; Turri, Stefano; Simeone, Giovanni

2017-05-01

In this work, we provide a simple and straightforward method for the fabrication of stable highly hydrophobic and oleophobic surfaces by applying stereolithography (SL) to perfluoropolyethers (PFPEs). Inspired by the liquid repellency widely shown in nature, our approach enables to easily mimic the interplay between the chemistry and physics by microtexturing low surface tension PFPEs. To this end, UV-curable resins suitable for SL-processing were formulated by blending multifunctional (meth-)acrylates PFPEs oligomers with photoinitiator and visible dyes whose content was tuned to tailor resin SL sensitivities. Photocalorimetric studies were also performed to investigate the curing behavior of the different formulations upon SL light exposure. Being the first example of stereolithography applied to PFPEs, stereolithographic processability of new developed PFPEs photopolymer was compared with a standard photoresist taken as benchmark (DL260®). Optimized formulations were characterized by reduced laser penetration depth (<75 μm) and small critical energies thus enabling for fast printing of micrometric structures. Arrays of cylindrical pillars (85 μm diameter, 400 μm height) characterized by varied pillars spacing (200 ÷ 350 μm) were rapidly printed with high fidelity as attested by SEM examination. Contact angle measurements in static and dynamic conditions were performed to investigate the surface properties of textured samples using water and oil as the probing liquids. PFPEs liquid repellent performances were compared with those from DL260® textured surfaces arrayed by SL. High water contact angles coupled with low hysteresis asserted that high hydrophobic surfaces were successfully obtained and best-performing textured surfaces were also characterized by high oil repellency. Finally, this study demonstrated that omniphobic surfaces can be easily realized via a single-step, cost-effective, and time-saving process.

Filamentary superhydrophobic Teflon surfaces: Moderate apparent contact angle but superior air-retaining properties.

PubMed

Di Mundo, Rosa; Bottiglione, Francesco; Palumbo, Fabio; Notarnicola, Michele; Carbone, Giuseppe

2016-11-15

Micro-scale textured Teflon surfaces, resulting from plasma etching modification, show extremely high water contact angle values and fairly good resistance to water penetration when hit by water drops at medium-high speed. This behavior is more pronounced when these surfaces present denser and smaller micrometric reliefs. Tailoring the top of these reliefs with a structure which further stabilizes the air may further increase resistance to wetting (water penetration) under static and dynamic conditions. Conditions of the oxygen fed plasma were tuned in order to explore the possibility of obtaining differently topped structures on the surface of the polymer. Scanning Electron Microscopy (SEM) was used to explore topography and X-ray Photoelectron Spectroscopy (XPS) to assess chemical similarity of the modified surfaces. Beside the usual advancing and receding water contact angle (WCA) measurements, surfaces were subjected to high speed impacting drops and immersion in water. At milder, i.e. shorter time and lower input power, plasma conditions formation of peculiar filaments is observed on the top of the sculpted reliefs. Filamentary topped surfaces result in a lower WCA than the spherical ones, appearing in this sense less superhydrophobic. However, these surfaces give rise to the formation of a more pronounced air layer when placed underwater. Further, when hit by water drops falling at medium/high speed, they show a higher resistance to water penetration and a sensitively lower surface-liquid contact time. The contact time is as low as previously observed only on heated solids. This behavior may be ascribed to the cavities formed beneath the filaments which, similarly with the salvinia leaf structures, require a surplus of pressure to be filled by water. Also, it suggests a different concept of superhydrophobicity, which cannot be expected on the basis of the conventional water contact angle characterization. Copyright © 2016 Elsevier Inc. All rights reserved.

The Surface Water and Ocean Topography Satellite Mission - An Assessment of Swath Altimetry Measurements of River Hydrodynamics

NASA Technical Reports Server (NTRS)

Wilson, Matthew D.; Durand, Michael; Alsdorf, Douglas; Chul-Jung, Hahn; Andreadis, Konstantinos M.; Lee, Hyongki

2012-01-01

The Surface Water and Ocean Topography (SWOT) satellite mission, scheduled for launch in 2020 with development commencing in 2015, will provide a step-change improvement in the measurement of terrestrial surface water storage and dynamics. In particular, it will provide the first, routine two-dimensional measurements of water surface elevations, which will allow for the estimation of river and floodplain flows via the water surface slope. In this paper, we characterize the measurements which may be obtained from SWOT and illustrate how they may be used to derive estimates of river discharge. In particular, we show (i) the spatia-temporal sampling scheme of SWOT, (ii) the errors which maybe expected in swath altimetry measurements of the terrestrial surface water, and (iii) the impacts such errors may have on estimates of water surface slope and river discharge, We illustrate this through a "virtual mission" study for a approximately 300 km reach of the central Amazon river, using a hydraulic model to provide water surface elevations according to the SWOT spatia-temporal sampling scheme (orbit with 78 degree inclination, 22 day repeat and 140 km swath width) to which errors were added based on a two-dimension height error spectrum derived from the SWOT design requirements. Water surface elevation measurements for the Amazon mainstem as may be observed by SWOT were thereby obtained. Using these measurements, estimates of river slope and discharge were derived and compared to those which may be obtained without error, and those obtained directly from the hydraulic model. It was found that discharge can be reproduced highly accurately from the water height, without knowledge of the detailed channel bathymetry using a modified Manning's equation, if friction, depth, width and slope are known. Increasing reach length was found to be an effective method to reduce systematic height error in SWOT measurements.

Characterization of the cell surface properties of drinking water pathogens by microbial adhesion to hydrocarbon and electrophoretic mobility measurements.

PubMed

Popovici, Jonathan; White, Colin P; Hoelle, Jill; Kinkle, Brian K; Lytle, Darren A

2014-06-01

The surface characteristics of microbial cells directly influence their mobility and behavior within aqueous environments. The cell surface hydrophobicity (CSH) and electrophoretic mobility (EPM) of microbial cells impact a number of interactions and processes including aggregation, adhesion to surfaces, and stability of the cells within the aqueous environments. These cell characteristics are unique to the bacterial species and are a reflection of the large diversity of surface structures, proteins, and appendages of microorganisms. CSH and EPM of bacterial cells contribute substantially to the effectiveness of drinking water treatment to remove them, and therefore an investigation of these properties will be useful in predicting their removal through drinking water treatment processes and transport through drinking water distribution systems. EPM and CSH measurements of six microbiological pathogen or surrogate species suspended in phosphate-buffered water are reported in this work. Two strains of Vibrio cholerae were hydrophobic, while three strains of Escherichia coli were hydrophilic. Bacillus cereus was categorized as moderately hydrophobic. The strains of E. coli had the highest (most negative) EPM. Based on the measurements, E. coli species is predicted to be most difficult to remove from water while V. cholerae will be the easiest to remove. Copyright © 2014 Elsevier B.V. All rights reserved.

A New Technique for the Retrieval of Near Surface Water Vapor Using DIAL Measurements

NASA Technical Reports Server (NTRS)

Ismail, Syed; Kooi, Susan; Ferrare, Richard; Winker, David; Hair, Johnathan; Nehrir, Amin; Notari, Anthony; Hostetler, Chris

2015-01-01

Water vapor is one of the most important atmospheric trace gas species and influences radiation, climate, cloud formation, surface evaporation, precipitation, storm development, transport, dynamics, and chemistry. For improvements in NWP (numerical weather prediction) and climate studies, global water vapor measurements with higher accuracy and vertical resolution are needed than are currently available. Current satellite sensors are challenged to characterize the content and distribution of water vapor in the Boundary Layer (BL) and particularly near the first few hundred meters above the surface within the BL. These measurements are critically needed to infer surface evaporation rates in cloud formation and climate studies. The NASA Langley Research Center Lidar Atmospheric Sensing Experiment (LASE) system, which uses the Differential Absorption Lidar (DIAL) technique, has demonstrated the capability to provide high quality water vapor measurements in the BL and across the troposphere. A new retrieval technique is investigated to extend these DIAL water vapor measurements to the surface. This method uses signals from both atmospheric backscattering and the strong surface returns (even over low reflectivity oceanic surfaces) using multiple gain channels to cover the large signal dynamic range. Measurements can be made between broken clouds and in presence of optically thin cirrus. Examples of LASE measurements from a variety of conditions encountered during NASA hurricane field experiments over the Atlantic Ocean are presented. Comparisons of retrieved water vapor profiles from LASE near the surface with dropsonde measurements show very good agreement. This presentation also includes a discussion of the feasibility of developing space-based DIAL capability for high resolution water vapor measurements in the BL and above and an assessment of the technology needed for developing this capability.

Application of Analysis and Modeling for Surface Water-Ground Water System: Preliminary Study of Artificial Recharge in Jeju Island, Korea

NASA Astrophysics Data System (ADS)

Kim, Y.; Koo, M.; Lee, K.; Ko, K.; Barry, J. M.

2008-12-01

The primary goal of this study is to secure sustainable groundwater resources with application of the analysis and modeling of coupled surface water-groundwater system to Jeju Island in the form of artificial recharge. Artificial recharge technology is a feasible method to augment groundwater resources in Jeju Island, Korea. Jeju-friendly Aquifer Recharge Technology (J-ART) that will be developed in this study is a technology for securing sustainable water resources by capturing ephemeral stream water with no interference in the environment such as natural recharge or eco-system, capturing the water in the reservoirs, recharging it through designed borehole after appropriate treatment, and then making it to be used at down-gradient production wells. Precipitation pattern in the study area is shifting to more sparsely-distributed and heavier rain type in summer season which reduces infiltration and/or groundwater recharge but increases runoff and flash flood on stream. Stream water as a source for J-ART is available only a few times a year since the stream bed is highly feasible to be percolated. To characterize quantitatively stream water, automatic temporal data collection system for water level, water velocity, and water qualities of total 8 parameters including temperature, water depth, pH, EC, DO, turbidity, NO3-N and Cl-. Characterizing groundwater flow from recharge area to discharge area should be achieved to evaluate the efficiency of J-ART. Jeju volcanic island has very thick unsaturated zone which is approximately 50 percent of the elevation on which it is. This hydrogeological property is good to inject source water through unsaturated zone to increase transport time, to get main basal aquifer, and to naturally filter the injected water during the transport. However, characterizing groundwater flow through the thick unsaturated zone with repeatedly overlapping permeable/impermeable layers would be a challenge. Estimation method of the infiltration velocity of soil water, groundwater age dating, and evaluation method for groundwater flow/circulation using stable isotopes are developed to evaluate artificial recharge. Input parameters for groundwater flow model are collected and analyzed quantitatively to develop model for simulating groundwater flow and thermal transport during artificial recharge. Self-potential survey method is reviewed theoretically as a geophysical evaluation method to characterize unsaturated flow during artificial recharge.

Airborne Imaging in the Yukon River Basin to Characterize SWOT Mission Phenomenology

NASA Astrophysics Data System (ADS)

Moller, D.; Pavelsky, T.; Arvesen, J. C.

2015-12-01

Remote sensing offers intriguing tools to track Arctic hydrology, but current techniques are largely limited to tracking either inundation or water surface elevation only. For the first time, the proposed Surface Water Ocean Topography (SWOT) satellite mission will provide regular, simultaneous observations of inundation extent and water level from space. SWOT is unique and distinct from precursor altimetry missions in some notable regards: 1) 100km+ of swath will provide complete ocean coverage, 2) in addition to the ocean product, land surface water will be mapped for storage measurement and discharge estimation and 3) Ka-band single-pass interferometry will produce the height measurements introducing a new measurement technique. This new approach introduces additional algorithmic, characterization and calibration/validation needs for which the Ka-band SWOT Phenomenology Airborne Radar (KaSPAR) was developed. In May 2015, AirSWOT (comprised of KaSPAR and a color infrared (CIR) high resolution aerial camera) was part of an intensive field campaign including observations of inundation extent and water level and in situ hydrologic measurements in two rivers and 20 lakes within the Yukon River Basin, Alaska. One goal is to explore the fundamental phenomenology of the SWOT measurement. This includes assessment of the effects of vegetation layover and attenuation, wind roughening and classification. Further KaSPAR-derived inundation extent will to be validated using a combination of ground surveys and coregistered CIR imagery. Ultimately, by combining measurements of changing inundation extent and water level between two collection dates, it will be possible to validate lake water storage variations against storage changes computed from in situ water levels and inundation area derived from AirSWOT. Our paper summarizes the campaign, the airborne and in situ measurements and presents some initial KaSPAR and CIR imagery from the Yukon flats region.

Monitoring and Characterizing Seasonal Drought, Water Supply Pattern and Their Impact on Vegetation Growth Using Satellite Soil Moisture Data, GRACE Water Storage and In-situ Observations.

NASA Astrophysics Data System (ADS)

A, G.; Velicogna, I.; Kimball, J. S.; Kim, Y.; Colliander, A.; Njoku, E. G.

2015-12-01

We combine soil moisture (SM) data from AMSR-E, AMSR-2 and SMAP, terrestrial water storage (TWS) changes from GRACE, in-situ groundwater measurements and atmospheric moisture data to delineate and characterize the evolution of drought and its impact on vegetation growth. GRACE TWS provides spatially continuous observations of total terrestrial water storage changes and regional drought extent, persistence and severity, while satellite derived soil moisture estimates provide enhanced delineation of plant-available soil moisture. Together these data provide complementary metrics quantifying available plant water supply. We use these data to investigate the supply changes from water components at different depth in relation to satellite based vegetation metrics, including vegetation greenness (NDVI) measures from MODIS and related higher order productivity (GPP) before, during and following the major drought events observed in the continental US for the past 14 years. We observe consistent trends and significant correlations between monthly time series of TWS, SM, NDVI and GPP. We study how changes in atmosphere moisture stress and coupling of water storage components at different depth impact on the spatial and temporal correlation between TWS, SM and vegetation metrics. In Texas, we find that surface SM and GRACE TWS agree with each other in general, and both capture the underlying water supply constraints to vegetation growth. Triggered by a transit increase in precipitation following the 2011 hydrological drought, vegetation productivity in Texas shows more sensitivity to surface SM than TWS. In the Great Plains, the correspondence between TWS and vegetation productivity is modulated by temperature-induced atmosphere moisture stress and by the coupling between surface soil moisture and groundwater through irrigation.

Fabrication and characterization of akaganeite/graphene oxide nanocomposite for arsenic removal from water

NASA Astrophysics Data System (ADS)

Trang, Nguyen Thi Thuy; Thy, Lu Thi Mong; Cuong, Pham Mai; Tu, Tran Hoang; Hieu, Nguyen Huu

2018-04-01

In this study, akageneite/graphene oxide (β-FeOOH/GO) nanocomposite was fabricated by in situ forced hydrolysis of iron (III) chloride. The structure and morphology of β-FeOOH/GO were characterized by Fourier Transform Infrared Spectroscopy (FTIR), X-ray diffraction (XRD), transmission electron microscopy (TEM), and Brunauer-Emmett- Teller (BET) specific surface area. XRD, FTIR, and TEM results indicated that β-FeOOH nanoparticles were successfully decorated on the surface of GO nanosheets. The BET specific surface area of β-FeOOH/GO was observed of 97.94 m2/g. The nanocomposite was used as an adsorbent for removal of arsenic (As5+) from water. Adsorption experiments were carried out to investigate contact time, pH values, and As5+ initial concentrations. The adsorption equilibrium time was reached within 180 minutes. The adsorption was well-fitted by a pseudo-second-order kinetic and Langmuir isotherm model. The maximum adsorption capacity of β-FeOOH/GO for As5+ ions of 94.34 mg/g that was calculated from the Langmuir model at pH 3. Accordingly, the nanocomposite β-FeOOH/GO could be considered as a highly efficient adsorbent for removing arsenic from water.

A novel algorithm for delineating wetland depressions and ...

EPA Pesticide Factsheets

In traditional watershed delineation and topographic modeling, surface depressions are generally treated as spurious features and simply removed from a digital elevation model (DEM) to enforce flow continuity of water across the topographic surface to the watershed outlets. In reality, however, many depressions in the DEM are actual wetland landscape features that are seldom fully filled with water. For instance, wetland depressions in the Prairie Pothole Region (PPR) are seasonally to permanently flooded wetlands characterized by nested hierarchical structures with dynamic filling- spilling-merging surface-water hydrological processes. The objectives of this study were to delineate hierarchical wetland catchments and model their hydrologic connectivity using high-resolution LiDAR data and aerial imagery. We proposed a novel algorithm delineate the hierarchical wetland catchments and characterize their geometric and topological properties. Potential hydrologic connectivity between wetlands and streams were simulated using the least-cost path algorithm. The resulting flow network delineated putative temporary or seasonal flow paths connecting wetland depressions to each other or to the river network at scales finer than available through the National Hydrography Dataset. The results demonstrated that our proposed framework is promising for improving overland flow modeling and hydrologic connectivity analysis. Presentation at AWRA Spring Specialty Conference in Sn

Doppler spectra of airborne ultrasound forward scattered by the rough surface of open channel turbulent water flows.

PubMed

Dolcetti, Giulio; Krynkin, Anton

2017-11-01

Experimental data are presented on the Doppler spectra of airborne ultrasound forward scattered by the rough dynamic surface of an open channel turbulent flow. The data are numerically interpreted based on a Kirchhoff approximation for a stationary random water surface roughness. The results show a clear link between the Doppler spectra and the characteristic spatial and temporal scales of the water surface. The decay of the Doppler spectra is proportional to the velocity of the flow near the surface. At higher Doppler frequencies the measurements show a less steep decrease of the Doppler spectra with the frequency compared to the numerical simulations. A semi-empirical equation for the spectrum of the surface elevation in open channel turbulent flows over a rough bed is provided. The results of this study suggest that the dynamic surface of open channel turbulent flows can be characterized remotely based on the Doppler spectra of forward scattered airborne ultrasound. The method does not require any equipment to be submerged in the flow and works remotely with a very high signal to noise ratio.

Characterization of seasonal and inter-annual variability in global water bodies using annual MODIS water maps 2000 - 2016

NASA Astrophysics Data System (ADS)

Hubbard, A. B.; Carroll, M.

2017-12-01

Accurate maps of surface water resources are critical for long-term resource management, characterization of extreme events, and integration into various science products. Unfortunately, most of the currently available surface water products do not adequately represent inter- and intra-annual variation in water extent, resulting from both natural fluctuations in the hydrologic cycle and human activities. To capture this variability, annual water maps were generated from Terra MODIS data at 250 m resolution for the years 2000 through 2016, using the same algorithm employed to generate the previously released MOD44W Collection 5 static water mask (Carroll et al., 2009). Following efforts to verify the data and remove false positives, the final maps were submitted to the Land Processes DAAC for publication as MOD44W Collection 6.1. Analysis of these maps indicate that only about two thirds of inland water pixels were persistent throughout all 16 years of data, meaning that roughly one third of the surface water detected in this period displayed some degree of inter-annual variation. In addition to the annual datasets, water observations were aggregated by quarter for each year from 2003 through 2016 using the same algorithm and observations from both Terra and Aqua. Analysis of these seasonal maps is ongoing, but preliminary investigation indicates they capture dramatic intra-annual fluctuations of water extent in many regions. In cloudy regions, it is difficult or impossible to consistently measure this intra-annual variation without the twice-daily temporal resolution of the MODIS sensors. While the moderate spatial resolution of MODIS is a constraint, these datasets are suitable for studying such fluctuations in medium to large water bodies, or at regional to global scales. These maps also provide a baseline record of historical surface water resources, against which future change can be compared. Finally, comparisons with the MOD44W Collection 5 static water mask indicate that major changes have occurred in many areas since the early 2000s, rendering these maps an equally valuable update for static water masking applications. ReferencesCarroll, M.L., Townshend, J.R., DiMiceli, C.M., Noojipady, P., & Sohlberg, R.A. (2009). A new global raster water mask at 250 m resolution. Int J Digit Earth, 2, 291-308.

Agricultural Groundwater Demands in the Conterminous United States

NASA Astrophysics Data System (ADS)

Ho, M. W.; Parthasarathy, V.; Etienne, E.; Russo, T. A.; Devineni, N.; Lall, U.

2016-12-01

In the conterminous United States (CONUS), over 40% of water consumed for irrigation, livestock and domestic water is sourced from groundwater. The late 20th century and 21st century saw an expansion in irrigated agriculture across the CONUS that was accompanied by increased pumping of groundwater. Groundwater is typically used to mitigate impacts of drought on surface water supplies enabling water demands to be met as well as to augment sparse surface water resources in arid regions or where surface water availability is highly variable temporally and/or spatially. A Demand Sensitive Drought Index (DSDI) is used to examine the impacts of agricultural water needs on groundwater in the CONUS. The DSDI accounts for agricultural water deficits driven by low precipitation, high agricultural water demand, or a combination of both. Changes in groundwater levels relative to agricultural water deficits are characterized relative to precipitation during the growing season and winter precipitation. In several key irrigated agricultural regions in the CONUS, long-term trends in groundwater levels appear to reflect prolonged periods of surface water deficits resulting from land use and associated unsustainable water demands. These areas are subsequent unable to recover from persistent states of agricultural drought. Conversely, reductions in agricultural water demands for crops do not necessarily lead to immediate recovery of groundwater levels due to the demand for groundwater in other sectors. Calls to establish or reform groundwater policies have recently been made in an effort to achieve holistic groundwater management strategies that consider the human demands on both surface water and groundwater. There is a need for relevant groundwater policies to ensure that water demands are adequately managed across sectors without unsustainably depleting groundwater resources and to ensure efficient economic activity.

Potentiometric surface of the Ozark aquifer in northern Arkansas, 2010

USGS Publications Warehouse

Czarnecki, John B.; Pugh, Aaron L.; Blackstock, Joshua M.

2014-01-01

The Ozark aquifer in northern Arkansas is composed of dolomite, limestone, sandstone, and shale of Late Cambrian to Middle Devonian age and ranges in thickness from approximately 1,100 feet to more than 4,000 feet. Hydrologically, the aquifer is complex, characterized by discrete and discontinuous flow components with large variations in permeability. The potentiometric-surface map, based on 56 well and 5 spring water-level measurements made in 2010 in Arkansas and Missouri, has a maximum water-level altitude measurement of 1,174 feet in Carroll County and a minimum water-level altitude measurement of 120 feet in Randolph County. Regionally, the flow within the aquifer is to the south and southeast in the eastern and central part of the study area and to the west, northwest, and north in the western part of the study area. Water-level altitudes changed 0.5 feet or less in 31 out of 56 wells measured between 2007 and 2010. Despite rapidly increasing population within the study area, the increase appears to have minimal effect on groundwater levels, although the effect may have been minimized by the development and use of surface-water distribution infrastructure, suggesting that most of the incoming populations are fulfilling their water needs from surface-water sources. The conversion of some users from groundwater to surface water may be allowing water levels in some wells to recover (rise) or decline at a slower rate in some areas such as in Benton, Carroll, and Washington Counties.

Surface deformation induced by water pumping for construction of Mass Rapid Transportation in Taipei basin

NASA Astrophysics Data System (ADS)

Hu, J. C.; Wu, P. C.; Tung, H.; Tsai, M. C.

2017-12-01

In 1968, there were 2,200 wells in the Taipei Basin used for water supply to meet the requirement of high population density. The overuse of ground water lead to the land subsidence rate up to 5 cm/yr. Although the government had already begun to limit groundwater pumping since 1968, the groundwater in the Taipei Basin demonstrated temporary fluctuation induced by pumping water for large deep excavation site or engineering usage. The previous study based on precise leveling suggested that the surface deformation was highly associated with the recovery of water level. In 1989, widespread uplift dominated in Taipei basin due to the recovery of ground water Table. In this study, we use 37 high-resolution X-band COSMO-SkyMed radar images from May 2011 to April 2015 to characterize deformation pattern in the period of construction of Mass Rapid Transportation (MRT). We also use 30 wells and 380 benchmarks of precise leveling in Taipei basin to study the correlation of surface deformation and change of ground water table. The storability is roughly constant across most of the aquifer with values between 0.8 x 10-4 and 1.3 x 10-3. Moreover, the high water pumping in two major aquifers, Jignme and Wuku Foramtions, before the underground construction for MRT led to inflict surface deformation and no time delay observed for surface deformation during the water pumping. It implies that the poro-elastic effect dominates in major aquifers in Taipei basin.

Hydrophobization of epoxy nanocomposite surface with 1H,1H,2H,2H-perfluorooctyltrichlorosilane for superhydrophobic properties

NASA Astrophysics Data System (ADS)

Psarski, Maciej; Marczak, Jacek; Celichowski, Grzegorz; Sobieraj, Grzegorz B.; Gumowski, Konrad; Zhou, Feng; Liu, Weimin

2012-10-01

Nature inspires the design of synthetic materials with superhydrophobic properties, which can be used for applications ranging from self-cleaning surfaces to microfluidic devices. Their water repellent properties are due to hierarchical (micrometer- and nanometre-scale) surface morphological structures, either made of hydrophobic substances or hydrophobized by appropriate surface treatment. In this work, the efficiency of two surface treatment procedures, with a hydrophobic fluoropolymer, synthesized and deposited from 1H,1H,2H,2H-perfluorooctyltrichlorosilane (PFOTS) is investigated. The procedures involved reactions from the gas and liquid phases of the PFOTS/hexane solutions. The hierarchical structure is created in an epoxy nanocomposite surface, by filling the resin with alumina nanoparticles and micron-sized glass beads and subsequent sandblasting with corundum microparticles. The chemical structure of the deposited fluoropolymer was examined using XPS spectroscopy. The topography of the modified surfaces was characterized using scanning electron microscopy (SEM), and atomic force microscopy (AFM). The hydrophobic properties of the modified surfaces were investigated by water contact and sliding angles measurements. The surfaces exhibited water contact angles of above 150° for both modification procedures, however only the gas phase modification provided the non-sticking behaviour of water droplets (sliding angle of 3°). The discrepancy is attributed to extra surface roughness provided by the latter procedure.

Hydrogeology and water quality of at the management systems evaluation area near Piketon, Ohio

USGS Publications Warehouse

Jagucki, M.L.; Finton, C.D.; Springer, A.E.; Bair, E.S.

1995-01-01

This report presents the results of a study by the U.S. Geological Survey, The Ohio State University, and the U.S. Department of Agriculture to describe the hydrology, water quality, and geochemical factors controlling water quality at the Ohio Management Systems Evaluation Area (MSEA). The Ohio MSEA is located on a 650-acre farm in the Scioto River Valley in Pike County, south-central Ohio. The farm is underlain by an incised bedrock valley filled with about 70 feet of sand and gravel outwash deposits that are covered by a veneer of silty clay alluvium and silty loam and sandy loam soils. Outwash sediment are composed predominantly of dolomite, quartz, and calcite, and have a median organic carbon concentration of 0.39 weight percent. Horizontal hydraulic conductivity of the sediment based on results of multiple-well aquifer tests ranges from 400 to 560 feet per day. Ground-water flow is from east to west-southwest at an average velocity of 1.5 to 2.5 feet per day. Ground water and surface water at the site are highly interconnected. Big Beaver Creek recharges the outwash aquifer along the eastern edge of the study area, and ground water discharges to the Scioto River at the western edge of the study area. High-stage events on the Scioto River cause frequent flow reversals in the aquifer that allow streamwater to travel a maximum observed distance of 190 feet inland. A zone of oxidizing waters (characterized by high dissolved oxygen concentration and Eh) is found in shallow ground water for several hundred feet adjacent to Big Beaver Creek and the Scioto River. This zone of oxidizing ground water is caused by the periodic inflow of surface waters to the aquifer. A ground-water budget for the study area indicates that the aquifer received 17.7 inches of recharge during water year 1992; of this amount, 72 percent originated as infiltrating precipitation, 28 percent as infiltration of surface water from Big Beaver Creek, and 0.2 percent as leakage from bedrock. Areal variation in water quality is caused by areal differences in the relative importance of these three recharge sources. The effects of bedrock leakage are evident only in the northeast corner of the study area. Here, deep outwash waters are transitional in composition between the calcium magnesium bicarbonate waters found elsewhere in the outwash aquifer and the calcium sodium chloride waters of the bedrock aquifer. Mixing calculations indicate that these deep outwash waters are composed of as much as 26 percent bedrock water. In the southern part of the MSEA, ground water is diluted by surface water from Big Beaver Creek as it recharges the aquifer through a sand and gravel streambed. At the northeast corner of the MSEA, however, Big Beaver Creek flows across a shale streambed through which no infiltration occurs. Redox reactions in the outwash aquifer control variations in aquifer chemistry with depth. From the water table to about 40 feet below land surface, oxidizing conditions are characterized by the presence of dissolved oxygen and nitrates in ground water, Eh greater than 200 millivolts, ferrihydrite coatings on sediment grains, and the absence of dissolved iron and manganese. From about 40 feet below land surface to the base of the aquifer, reducing conditions are characterized by dissolved oxygen concentrations less than 2 mg/L, Eh less than 200 millivolts, and the presence of dissolved iron and manganese. Denitrification in the reducing zone naturally remediates anthropogenic nitrate contamination of the aquifer while oxidizing pyrite in the aquifer sediment. ? The Ohio State University, Department of Geological Sciences, Columbus, Ohio.

Characterizing hydrophobicity of amino acid side chains in a protein environment via measuring contact angle of a water nanodroplet on planar peptide network.

PubMed

Zhu, Chongqin; Gao, Yurui; Li, Hui; Meng, Sheng; Li, Lei; Francisco, Joseph S; Zeng, Xiao Cheng

2016-11-15

Hydrophobicity of macroscopic planar surface is conventionally characterized by the contact angle of water droplets. However, this engineering measurement cannot be directly extended to surfaces of proteins, due to the nanometer scale of amino acids and inherent nonplanar structures. To measure the hydrophobicity of side chains of proteins quantitatively, numerous parameters were developed to characterize behavior of hydrophobic solvation. However, consistency among these parameters is not always apparent. Herein, we demonstrate an alternative way of characterizing hydrophobicity of amino acid side chains in a protein environment by constructing a monolayer of amino acids (i.e., artificial planar peptide network) according to the primary and the β-sheet secondary structures of protein so that the conventional engineering measurement of the contact angle of a water droplet can be brought to bear. Using molecular dynamics simulations, contact angles θ of a water nanodroplet on the planar peptide network, together with excess chemical potentials of purely repulsive methane-sized Weeks-Chandler-Andersen solute, are computed. All of the 20 types of amino acids and the corresponding planar peptide networks are studied. Expectedly, all of the planar peptide networks with nonpolar amino acids are hydrophobic due to θ [Formula: see text] 90°, whereas all of the planar peptide networks of the polar and charged amino acids are hydrophilic due to θ [Formula: see text] 90°. Planar peptide networks of the charged amino acids exhibit complete-wetting behavior due to θ [Formula: see text] 0°. This computational approach for characterization of hydrophobicity can be extended to artificial planar networks of other soft matter.

Water repellent properties of dispersed metals containing low-dimensional forms of ammonium compounds on the surface

NASA Astrophysics Data System (ADS)

Syrkov, A. G.; Kabirov, V. R.; Silivanov, M. O.

2017-07-01

For the first time the change of the water repellent properties of dispersed copper, modified using quaternary ammonium compounds on 24 h time scale in saturated water vapours was studied. Exponential time dependences of the water repellent properties of dispersed copper with adsopted QAC were derived and characterized. It was established that the samples modified in mixed and consistent modes by both modifiers reach the saturation state faster than others, due to the small number of hydrophilic centers on the surface of metals. The last conclusion was confirmed by the distribution spectra of centers of adsorption, which were obtained by the adsorption of acid-base indicators for more dispersed samples based on aluminum powder.

Effect of polyethyleneimine modified graphene on the mechanical and water vapor barrier properties of methyl cellulose composite films.

PubMed

Liu, Hongyu; Liu, Cuiyun; Peng, Shuge; Pan, Bingli; Lu, Chang

2018-02-15

A series of novel methyl cellulose (MC) composite films were prepared using polyethyleneimine reduced graphene oxide (PEI-RGO) as an effective filler for water vapor barrier application. The as-prepared PEI-RGO/MC composites were characterized by Fourier transform infrared spectroscopy, X-ray diffraction, thermogravimetric analysis, tensile test and scanning electron microscopy. The experimental and theoretical results exhibited that PEI-RGO was uniformly dispersed in the MC matrix without aggregation and formed an aligned dispersion. The addition of PEI-RGO resulted in an enhanced surface hydrophobicity and a tortuous diffusion pathway for water molecules. Water vapor permeability of PEI-RGO/MC with loading of 3.0% of surface modified graphene was as low as 5.98×10 -11 gmm -2 s -1 Pa -1 . The synergistic effects of enhanced surface hydrophobicity and tortuous diffusion pathway were accounted for the improved water vapor barrier performance of the PEI-RGO/MC composite films. Copyright © 2017 Elsevier Ltd. All rights reserved.

Microbial Community Profile of a Lead Service Line Removed from a Drinking Water Distribution System▿

PubMed Central

White, Colin; Tancos, Matthew; Lytle, Darren A.

2011-01-01

A corroded lead service line was removed from a drinking water distribution system, and the microbial community was profiled using 16S rRNA gene techniques. This is the first report of the characterization of a biofilm on the surface of a corroded lead drinking water service line. The majority of phylotypes have been linked to heavy-metal-contaminated environments. PMID:21652741

Surface modification of boron nitride nanosheets by polyelectrolytes via atom transfer radical polymerization

NASA Astrophysics Data System (ADS)

Wu, Yuanpeng; Guo, Meiling; Liu, Guanfei; Xue, Shishan; Xia, Yuanmeng; Liu, Dan; Lei, Weiwei

2018-04-01

In this study, the surface modification of boron nitride nanosheets (BNNSs) with poly 2-acrylamido-2-methyl- propanesulfonate (PAMPS) brushes is achieved through electron transfer atom transfer radical polymerization (ARGET ATRP). BNNSs surface was first modified with α-bromoisobutyryl bromide (BIBB) via hydroxyl groups, then PAMPS brushes were grown on the surface through ARGET ATRP. Polyelectrolyte brushes modified BNNSs were further characterized by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analyses (TGA), x-ray powder diffraction (XRD) and scanning electron microscopy (SEM). The concentraction of water-dispersion of BNNSs have been enhanced significantly by PAMPS and the high water-dispersible functional BNNSs/PAMPS composites are expected to have potential applications in biomedical and thermal management in electronics.

KSC-98pc1652

NASA Image and Video Library

1998-11-03

The second stage of a Delta II rocket arrives at pad 17A at Cape Canaveral Air Station. The rocket is scheduled to be launched on Dec. 10, 1998, heading for Mars and carrying the Mars Climate Orbiter. The orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for 657 days. It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface. The orbiter will primarily support its companion Mars Polar Lander spacecraft, which is planned for launch on Jan. 3, 1999

Surface flow measurements from drones

NASA Astrophysics Data System (ADS)

Tauro, Flavia; Porfiri, Maurizio; Grimaldi, Salvatore

2016-09-01

Drones are transforming the way we sense and interact with the environment. However, despite their increased capabilities, the use of drones in geophysical sciences usually focuses on image acquisition for generating high-resolution maps. Motivated by the increasing demand for innovative and high performance geophysical observational methodologies, we posit the integration of drone technology and optical sensing toward a quantitative characterization of surface flow phenomena. We demonstrate that a recreational drone can be used to yield accurate surface flow maps of sub-meter water bodies. Specifically, drone's vibrations do not hinder surface flow observations, and velocity measurements are in agreement with traditional techniques. This first instance of quantitative water flow sensing from a flying drone paves the way to novel observations of the environment.

Experimental evaluation of theoretical sea surface reflectance factors relevant to above-water radiometry.

PubMed

Zibordi, Giuseppe

2016-03-21

Determination of the water-leaving radiance L_W through above-water radiometry requires knowledge of accurate reflectance factors ρ of the sea surface. Publicly available ρ relevant to above-water radiometry include theoretical data sets generated: i. by assuming a sky radiance distribution accounting for aerosols and multiple scattering, but neglecting polarization, and quantifying sea surface effects through Cox-Munk wave slope statistics; or differently ii. accounting for polarization, but assuming an ideal Rayleigh sky radiance distribution, and quantifying sea surface effects through modeled wave elevation and slope variance spectra. The impact on above-water data products of differences between those factors ρ was quantified through comparison of L_W from the Ocean Color component of the Aerosol Robotic Network (AERONET-OC) with collocated L_W from in-water radiometry. Results from the analysis of radiance measurements from the sea performed with 40 degrees viewing angle and 90 degrees azimuth offset with respect to the sun plane, indicated a slightly better agreement between above- and in-water L_W determined for wind speeds tentatively lower than 4 m s^-1 with ρ computed accounting for aerosols, multiple scattering and Cox-Munk surfaces. Nevertheless, analyses performed by partitioning the investigated data set also indicated that actual ρ values would exhibit dependence on sun zenith comprised between those characterizing the two sets of reflectance factors.

Radiolytic hydrogen generation at silicon carbide-water interfaces

NASA Astrophysics Data System (ADS)

Schofield, Jennifer; Reiff, Sarah C.; Pimblott, Simon M.; LaVerne, Jay A.

2016-02-01

While many of the proposed uses of SiC in the nuclear industry involve systems that are assumed to be dry, almost all materials have dissociated chemisorbed water associated with their surface, which can undergo chemistry in radiation fields. Silicon carbide α-phase and β-phase nanoparticles with water were irradiated with γ-rays and 5 MeV 4He ions followed by the determination of the production of molecular hydrogen, H2, and characterization of changes in the particle surface. The yields of H2 from SiC-water slurries were always greater than expected from a simple mixture rule indicating that the presence of SiC was influencing the production of H2 from water, probably through an energy transfer from the solid to liquid phase. Although the increase in H2 yields was modest, a decrease in the water mass percentage led to an increase in H2 yields, especially for very low amounts of water. Surface analysis techniques included diffuse reflectance infrared Fourier transform spectroscopy (DRIFT), nitrogen absorption with the Brunauer - Emmett - Teller (BET) methodology for surface area determination, X-ray diffraction (XRD), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS). Little change in the SiC surface was observed following radiolysis except for some conversion of β-phase SiC to the α-phase and the formation of SiO2 with He ion radiolysis.

Sensor for detection of liquid spills on surfaces

DOEpatents

Davis, Brent C.; Gayle, Tom M.

1989-07-04

A surface liquid detector is disclosed for detecting liquids spilled on surfaces such as floors. A temperature-sensitive thermistor probe is used in a bridge circuit to detect the change in resistance in the thermistor due to the change in thermal conductivity that occurs when a liquid contacts the probe. The device is characterized by the ability to detect either conductive or nonconductive liquids, such as water or oil spills.

Sensor for detection of liquid spills on surfaces

DOEpatents

Davis, Brent C.; Gayle, Tom M.

1989-01-01

A surface liquid detector is disclosed for detecting liquids spilled on surfaces such as floors. A temperature-sensitive thermistor probe is used in a bridge circuit to detect the change in resistance in the thermistor due to the change in thermal conductivity that occurs when a liquid contacts the probe. The device is characterized by the ability to detect either conductive or nonconductive liquids, such as water or oil spills.

Seasonality of change: Summer warming rates do not fully represent effects of climate change on lake temperatures

USGS Publications Warehouse

Winslow, Luke; Read, Jordan S.; Hansen, Gretchen J. A.; Rose, Kevin C.; Robertson, Dale M.

2017-01-01

Responses in lake temperatures to climate warming have primarily been characterized using seasonal metrics of surface-water temperatures such as summertime or stratified period average temperatures. However, climate warming may not affect water temperatures equally across seasons or depths. We analyzed a long-term dataset (1981–2015) of biweekly water temperature data in six temperate lakes in Wisconsin, U.S.A. to understand (1) variability in monthly rates of surface- and deep-water warming, (2) how those rates compared to summertime average trends, and (3) if monthly heterogeneity in water temperature trends can be predicted by heterogeneity in air temperature trends. Monthly surface-water temperature warming rates varied across the open-water season, ranging from 0.013 in August to 0.073°C yr−1 in September (standard deviation [SD]: 0.025°C yr−1). Deep-water trends during summer varied less among months (SD: 0.006°C yr−1), but varied broadly among lakes (–0.056°C yr−1 to 0.035°C yr−1, SD: 0.034°C yr−1). Trends in monthly surface-water temperatures were well correlated with air temperature trends, suggesting monthly air temperature trends, for which data exist at broad scales, may be a proxy for seasonal patterns in surface-water temperature trends during the open water season in lakes similar to those studied here. Seasonally variable warming has broad implications for how ecological processes respond to climate change, because phenological events such as fish spawning and phytoplankton succession respond to specific, seasonal temperature cues.

Contamination assessments of surface water in coastal lagoon (Maluan Bay, China) incorporating biomarker responses and bioaccumulation in hepatopancreas of exposed shrimp (Litopenaeus vannamei)--an integrative approach.

PubMed

Wang, Zaosheng; Dong, Xiaoxia; Zhou, Shilei; Yan, Changzhou; Yan, Yijun; Chi, Qiaoqiao

2014-01-01

Maluan Bay, characterized by various degrees of anthropogenic contamination, is considered as one of the most industrialized and urbanized coastal lagoon in China, where large amounts of metal contaminants in surface water and biota were detected in previous studies. However, no clear discriminating power among sampling sites could be made only through comparisons between contaminant levels and Environmental Quality Standards and especially biological-based monitoring integrating biomarkers and bioaccumulation of exposure are scarce. For this purpose, antioxidants enzymes (superoxide dismutase, catalase, and glutathione peroxidase) and glutathione-S-transferase were assessed using the hepatopancreas of shrimp Litopenaeus vannamei after 7 days laboratory exposure under controlled conditions to characterize the effects of polluted waters to shrimps. The metal concentrations of sampled water and bioaccumulation in hepatopancreatic tissues were also analyzed, and data were linked to biomarkers' responses by multivariate (principal component analysis-factor) analysis. A representation of estimated factor scores was performed to confirm the factor descriptions classifying the pollution status and characterizing the studied sites, which pointed out the impact of multiple sources of contaminants to the water quality and provided further evidences to the existence of clear pollution and toxicological gradients in critical areas. The results of the present investigation underlined that the integrated approach could be a powerful tool for the identification of causal toxic contaminants in complex mixtures and the assessment of human-induced environmental quality of the system in coastal zones.

Summer distributions of forage fish in the eastern Bering Sea

NASA Astrophysics Data System (ADS)

Parker-Stetter, Sandra L.; Horne, John K.; Farley, Edward V.; Barbee, David H.; Andrews, Alexander G.; Eisner, Lisa B.; Nomura, Jennifer M.

2013-10-01

Juvenile and small adult fish, typically called forage fish, are an important but poorly studied part of the eastern Bering Sea (EBS) ecosystem. Acoustic and trawl data from a non-target survey were used to evaluate distributions of capelin (Mallotus villosus), age-0 Pacific cod (Gadus macrocephalus), and age-0 walleye pollock (Theragra chalcogramma, herein pollock) in 2006-2010. Within the surface zone (15 m to ~35 m, evaluated 2006-2010), capelin occurred throughout the EBS but primarily in the middle shelf. Capelin were also present in the midwater zone (~35 m to 0.5 m off-bottom) in both 2009 and 2010 (evaluated 2009-2010), and resulted in water column zone (15 m to 0.5 m off-bottom) distributions that differed from surface zone characterizations. Age-0 Pacific cod occurred primarily in the surface zone of the middle and outer shelf regions in all years. As midwater and surface zone age-0 Pacific cod were often coincident, water column zone distributions in 2009-2010 were similar to surface zone distributions. Age-0 pollock were found in the EBS surface zone in all years, primarily in the middle and outer shelf regions. High densities of age-0 pollock occurred in the midwater zone in 2006-2007 and 2009-2010. Water column zone distributions of age-0 pollock were similar to surface zone distributions in 2006-2007, but differed in 2009-2010 due to low numbers of age-0 pollock in the surface zone and presence of high densities in the midwater zone of the outer shelf region. While general patterns in capelin distribution in the surface zone were similar between the present and the previous studies, the acoustic-trawl characterization suggested that capelin densities were high in the middle shelf region. As expected, surface zone distributions of age-0 Pacific cod and age-0 pollock were similar to previous characterizations. Observed high densities of midwater age-0 pollock have not been described by previous studies. Annual abundance indices based on bottom or surface trawl data alone will not be sufficient in all years. Data and conclusions from non-target surveys may be constrained compared to dedicated survey efforts, but can provide baseline distributions, potential abundance indices, and insight for planning future research.

Picosecond Pulsed Laser Ablation for the Surface Preparation of Epoxy Composites

NASA Technical Reports Server (NTRS)

Palmieri, Frank; Ledesma, Rodolfo; Fulton, Tayler; Arthur, Alexandria; Eldridge, Keishara; Thibeault, Sheila; Lin, Yi; Wohl, Chris; Connell, John

2017-01-01

As part of a technical challenge under the Advanced Composites Program, methods for improving pre-bond process control for aerospace composite surface treatments and inspections, in conjunction with Federal Aviation Administration guidelines, are under investigation. The overall goal is to demonstrate high fidelity, rapid and reproducible surface treatment and surface characterization methods to reduce uncertainty associated with the bonding process. The desired outcomes are reliable bonded airframe structure, and reduced timeline to certification. In this work, laser ablation was conducted using a q-switched Nd:YVO4 laser capable of nominal pulse durations of 8 picoseconds (ps). Aerospace structural carbon fiber reinforced composites with an epoxy resin matrix were laser treated, characterized, processed into bonded assemblies and mechanically tested. The characterization of ablated surfaces were conducted using scanning electron microscopy (SEM), water contact angle (WCA) goniometry, micro laser induced breakdown spectroscopy (uLIBS), and electron spin resonance (ESR). The bond performance was assessed using a double cantilever beam (DCB) test with an epoxy adhesive. The surface characteristics and bond performance obtained from picosecond ablated carbon fiber reinforced plastics (CFRPs) are presented herein.

Composition profiles, levels, distributions and ecological risk assessments of trihalomethanes in surface water from a typical estuary of Bohai Bay, China.

PubMed

Niu, Zhiguang; Li, Xiaonan; Zhang, Ying

2017-04-15

To characterize the spatiotemporal distribution and potential ecological risk for trihalomethanes (THMs) in the surface water of a river estuary, surface water samples were collected over five consecutive months (from March to July 2016) from four sites in the Haihe River estuary of Bohai Bay. The potential ecological risks of THMs were evaluated quantitatively based on a species sensitivity distribution (SSD) model. The results demonstrate that trichloromethane (TCM) was the predominant THM in surface water of the Haihe River estuary (2.93±1.98μg/L) followed by tribromomethane (TBM) (0.42±0.33μg/L), bromodichloromethane (BDCM) (0.14±0.06μg/L) and dibromochloromethane (DBCM) (0.09±0.10μg/L). The concentration of TCM was higher in summer than that in spring, while TBM displayed the opposite trend. The TCM concentration decreased from the estuary to the adjacent sea. However, the levels of TBM and DBCM in the adjacent sea were higher than those in the estuary. The ecological risks of THMs in surface water of Haihe River were notably low, and the ecological risks of THMs in freshwater were generally higher than those in seawater. Compared with other contaminants in water and surface sediment from rivers and coastal areas, the ecological risk levels of THMs in surface water can be considered low. This study is a contribution to the progress of ecological risk assessment of THMs. Copyright © 2017 Elsevier Ltd. All rights reserved.

Robust superhydrophobic surface by nature-inspired polyphenol chemistry for effective oil-water separation

NASA Astrophysics Data System (ADS)

Bu, Yiming; Huang, Jingjing; Zhang, Shiyu; Wang, Yinghua; Gu, Shaojin; Cao, Genyang; Yang, Hongjun; Ye, Dezhan; Zhou, Yingshan; Xu, Weilin

2018-05-01

With the ever-increasing oil spillages, oil-water separation has attracted widespread concern in recent years. In this work, a nature-inspired polyphenol method has been developed to fabricate the durable superhydrophobic surfaces for the oil-water separation. Inspiring from the adhesion of polyphenol and reducing capacity of free catechol/pyrogallol groups in polyphenol, firstly, the simple immersion of commercial materials (melamine sponge, PET, and nonwoven cotton fabrics) in tannic acid (TA) solution allows to form a multifunctional coating on the surface of sponge or fabrics, which was used as reducing reagent to generate Ag nanoparticles (NPs). Then, decoration of 1H, 1H, 2H, 2H-perfluorodecanethiol (PFDT) molecules produced superhydrophobic surfaces. The surface topological structure, chemical composition, and superhydrophobic property of the as-prepared surface are characterized by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), energy dispersive spectroscopy (EDS), and water contact angle (WCA) measurements. The WCAs of as-prepared sponge and fabrics were higher than 150°. The stability, absorption capacity, and recyclability of as-prepared sponge and fabrics were investigated. The as-prepared sponge demonstrates high oil/water selectivity and high absorption capacity (66-150 g/g) for a broad variety of oils and organic solvents, and was chemically resistant, robust against abrasion, and long-term durability in harsh environments. Most important of all, it can continuously separate various kinds of oils or organic pollutants from the surface of water. This study presents a facile strategy to fabricate superhydrophobic materials for continuous oil-water separation, displaying great potential in large-scale practical application.

Continuous measurements of water surface height and width along a 6.5km river reach for discharge algorithm development

NASA Astrophysics Data System (ADS)

Tuozzolo, S.; Durand, M. T.; Pavelsky, T.; Pentecost, J.

2015-12-01

The upcoming Surface Water and Ocean Topography (SWOT) satellite will provide measurements of river width and water surface elevation and slope along continuous swaths of world rivers. Understanding water surface slope and width dynamics in river reaches is important for both developing and validating discharge algorithms to be used on future SWOT data. We collected water surface elevation and river width data along a 6.5km stretch of the Olentangy River in Columbus, Ohio from October to December 2014. Continuous measurements of water surface height were supplemented with periodical river width measurements at twenty sites along the study reach. The water surface slope of the entire reach ranged from during 41.58 cm/km at baseflow to 45.31 cm/km after a storm event. The study reach was also broken into sub-reaches roughly 1km in length to study smaller scale slope dynamics. The furthest upstream sub-reaches are characterized by free-flowing riffle-pool sequences, while the furthest downstream sub-reaches were directly affected by two low-head dams. In the sub-reaches immediately upstream of each dam, baseflow slope is as low as 2 cm/km, while the furthest upstream free-flowing sub-reach has a baseflow slope of 100 cm/km. During high flow events the backwater effect of the dams was observed to propagate upstream: sub-reaches impounded by the dams had increased water surface slopes, while free flowing sub-reaches had decreased water surface slopes. During the largest observed flow event, a stage change of 0.40 m affected sub-reach slopes by as much as 30 cm/km. Further analysis will examine height-width relationships within the study reach and relate cross-sectional flow area to river stage. These relationships can be used in conjunction with slope data to estimate discharge using a modified Manning's equation, and are a core component of discharge algorithms being developed for the SWOT mission.

Characterizing the SWOT discharge error budget on the Sacramento River, CA

NASA Astrophysics Data System (ADS)

Yoon, Y.; Durand, M. T.; Minear, J. T.; Smith, L.; Merry, C. J.

2013-12-01

The Surface Water and Ocean Topography (SWOT) is an upcoming satellite mission (2020 year) that will provide surface-water elevation and surface-water extent globally. One goal of SWOT is the estimation of river discharge directly from SWOT measurements. SWOT discharge uncertainty is due to two sources. First, SWOT cannot measure channel bathymetry and determine roughness coefficient data necessary for discharge calculations directly; these parameters must be estimated from the measurements or from a priori information. Second, SWOT measurement errors directly impact the discharge estimate accuracy. This study focuses on characterizing parameter and measurement uncertainties for SWOT river discharge estimation. A Bayesian Markov Chain Monte Carlo scheme is used to calculate parameter estimates, given the measurements of river height, slope and width, and mass and momentum constraints. The algorithm is evaluated using simulated both SWOT and AirSWOT (the airborne version of SWOT) observations over seven reaches (about 40 km) of the Sacramento River. The SWOT and AirSWOT observations are simulated by corrupting the ';true' HEC-RAS hydraulic modeling results with the instrument error. This experiment answers how unknown bathymetry and roughness coefficients affect the accuracy of the river discharge algorithm. From the experiment, the discharge error budget is almost completely dominated by unknown bathymetry and roughness; 81% of the variance error is explained by uncertainties in bathymetry and roughness. Second, we show how the errors in water surface, slope, and width observations influence the accuracy of discharge estimates. Indeed, there is a significant sensitivity to water surface, slope, and width errors due to the sensitivity of bathymetry and roughness to measurement errors. Increasing water-surface error above 10 cm leads to a corresponding sharper increase of errors in bathymetry and roughness. Increasing slope error above 1.5 cm/km leads to a significant degradation due to direct error in the discharge estimates. As the width error increases past 20%, the discharge error budget is dominated by the width error. Above two experiments are performed based on AirSWOT scenarios. In addition, we explore the sensitivity of the algorithm to the SWOT scenarios.

Methods for LWIR Radiometric Calibration and Characterization

NASA Technical Reports Server (NTRS)

Ryan, Robert; Harrington, Gary; Howell, Dane; Pagnutti, Mary; Zanoni, Vicki

2002-01-01

The utility of a remote sensing system increases with its ability to retrieve surface temperature or radiance accurately. Research applications, such as sea temperature and power plant discharge, require a 0.2 C resolution or better for absolute temperature retrievals. Other applications, including agriculture water stress detection, require at least a 1 C resolution. To achieve these levels of accuracy routinely, scientists must perform laboratory and onboard calibration, as well as in-flight vicarious radiometric characterization. A common approach used for in-flight radiometric characterization incorporates a well-calibrated infrared radiometer that is mounted on a bouy and placed on a uniform water body. The radiometer monitors radiant temperature along with pressure, humidity, and temperature measurements of an associated column of atmosphere. On very still waters, however, a buoy can significantly distrub these measurements. Researchers at NASA's Stennis Space Center (SSC) have developed a novel approach of using an uncooled infrared camera mounted on a boom to quantify buoy effects. Another critical aspect of using buoy-mounted infrared radiometers is the need for extensive laboratory characterization of the instruments' radiometric sensitivity, field of view, and spectral response. Proper surface temperature retrieval also requires detailed knowledge of both the upward emission and the reflected sky emission. Recent work at SSC has demonstrated that the use of a polarization-based radiometer operating at the Brewster angle can greatly simplify temperature retrieval as well as improve overall accuracy.

Synthesis and characterization of alginate beads encapsulated zinc oxide nanoparticles for bacteria disinfection in water.

PubMed

Motshekga, Sarah Constance; Sinha Ray, Suprakas; Maity, Arjun

2018-02-15

The use of polymer nanocomposites as novel materials for water remediation has emerged as a promising alternative for disinfection of bacteria contaminated water. Sodium alginate, a natural biopolymer has been investigated in this study by encapsulating antimicrobial zinc oxide nanoparticles supported bentonite. The confirmation of the alginate nanocomposites was done by use of TEM, SEM-EDS and XRD. The antimicrobial activity of the alginate nanocomposites was investigated by batch studies using surface water and synthetic bacteria contaminated water containing Staphylococcus aureus. The effect of nanocomposite amount and initial bacteria concentration has been studied. The inactivation results indicated that the nanocomposite effectively inactivated bacteria in both the synthetic and surface water. With an amount of 0.5 g of the nanocomposites, no bacteria was observed in the water after 70 min of contact time with initial bacteria concentration of 200 cfu/ml for synthetic water and within a min, no bacteria was observed in the water for surface water. It is worth noting that 200 cfu/ml is the bacteria concentration range in which environmental water is likely to contain. Therefore, the results of this study have indicated that the alginate nanocomposites can be deemed as a potential antimicrobial agent for water disinfection. Copyright © 2017 Elsevier Inc. All rights reserved.

Use of chemical and isotopic tracers to characterize the interactions between ground water and surface water in mantled karst

DOE Office of Scientific and Technical Information (OSTI.GOV)

Katz, B.G.; Davis, J.H.; Coplen, T.B.

1997-11-01

In the mantled karst terrane of northern Florida, the water quality of the Upper Floridan aquifer is influenced by the degree of connectivity between the aquifer and the surface. Chemical and isotopic analyses [{sup 18}O/{sup 16}O ({delta}{sup 18}O), {sup 2}H/{sup 1}H ({delta}D), {sup 13}C/{sup 12}C ({delta}{sup 13}C), tritium ({sup 3}H), and strontium-87/strontium-86 ({sup 87}Sr/{sup 86}Sr)] along with geochemical mass-balance modeling were used to identify the dominant hydrochemical processes that control the composition of ground water as it evolves downgradient in two systems. In one system, surface water enters the Upper Florida aquifer through a sinkhole located in the Northern Highlandsmore » physiographic unit. In the other system, surface water enters the aquifer through a sinkhole lake (Lake Bradford) in the Woodville Karst Plain. Differences in the composition of water isotopes ({delta}{sup 18}O and {delta}D) in rainfall, ground water, and surface water were used to develop mixing models of surface water (leakage of water to the Upper Floridan aquifer from a sinkhole lake and a sinkhole) and ground water. Using mass-balance calculations, based on differences in {delta}{sup 18}O and {delta}D, the proportion of lake water that mixed with meteoric water ranged from 7 to 86% in water from wells located in close proximity to lake Bradford. In deeper parts of the Upper Floridan aquifer, water enriched in {sup 18}O and D from five of 12 samples municipal wells indicated that recharge from a sinkhole (1 to 24%) and surface water with an evaporated isotopic signature (2 to 32%) was mixing with ground water. The solute isotopes, {delta}{sup 13}C and {sup 87}Sr/{sup 86}Sr, were used to test the sensitivity of binary and ternary mixing models, and to estimate the amount of mass transfer of carbon and other dissolved species in geochemical reactions.« less

Use of chemical and isotopic tracers to characterize the interactions between ground water and surface water in mantled karst

USGS Publications Warehouse

Katz, B.G.; Coplen, T.B.; Bullen, T.D.; Hal, Davis J.

1997-01-01

In the mantled karst terrane of northern Florida, the water quality of the Upper Floridan aquifer is influenced by the degree of connectivity between the aquifer and the surface. Chemical and isotopic analyses [18O/16O (??18O), 2H/1H (??D), 13C/12C (??13C), tritium(3H), and strontium-87/strontium-86(87Sr/86Sr)]along with geochemical mass-balance modeling were used to identify the dominant hydrochemical processes that control the composition of ground water as it evolves downgradient in two systems. In one system, surface water enters the Upper Floridan aquifer through a sinkhole located in the Northern Highlands physiographic unit. In the other system, surface water enters the aquifer through a sinkhole lake (Lake Bradford) in the Woodville Karst Plain. Differences in the composition of water isotopes (??18O and ??D) in rainfall, ground water, and surface water were used to develop mixing models of surface water (leakage of water to the Upper Floridan aquifer from a sinkhole lake and a sinkhole) and ground water. Using mass-balance calculations, based on differences in ??18O and ??D, the proportion of lake water that mixed with meteoric water ranged from 7 to 86% in water from wells located in close proximity to Lake Bradford. In deeper parts of the Upper Floridan aquifer, water enriched in 18O and D from five of 12 sampled municipal wells indicated that recharge from a sinkhole (1 to 24%) and surface water with an evaporated isotopic signature (2 to 32%) was mixing with ground water. The solute isotopes, ??13C and 87Sr/86Sr, were used to test the sensitivity of binary and ternary mixing models, and to estimate the amount of mass transfer of carbon and other dissolved species in geochemical reactions. In ground water downgradient from Lake Bradford, the dominant processes controlling carbon cycling in ground water were dissolution of carbonate minerals, aerobic degradation of organic matter, and hydrolysis of silicate minerals. In the deeper parts of the Upper Floridan aquifer, the major processes controlling the concentrations of major dissolved species included dissolution of calcite and dolomite, and degradation of organic matter under oxic conditions. The Upper Floridan aquifer is highly susceptible to contamination from activities at the land surface in the Tallahassee area. The presence of post-1950s concentrations of 3H in ground water from depths greater than 100 m below land surface indicates that water throughout much of the Upper Floridan aquifer has been recharged during the last 40 years. Even though mixing is likely between ground water and surface water in many parts of the study area, the Upper Floridan aquifer produces good quality water, which due to dilution effects shows little if any impact from trace elements or nutrients that are present in surface waters.The water quality of the Upper Floridan aquifer is influenced by the degree of connectivity between the aquifer and the surface water. Chemical and isotopic analyses, tritium, and strontium-87/strontium-86 along with geochemical mass-balance modeling were used to identify the dominant hydrochemical processes that control the composition of groundwater. Differences in the composition of water isotopes in rainfall, groundwater and surface water were used to develop mixing models of surface water and groundwater. Even though mixing is likely between groundwater and surface water in many parts of the study area, the Upper Floridan aquifer produces good quality water, showing little impact from trace elements present in surface waters.

Hydrology and water quality of forested lands in eastern North Carolina

Treesearch

G.M. Chescheir; M.E. Lebo; D.M. Amatya; J. Hughes; J.W. Gilliam; R.W. Skaggs; R.B. Herrmann

2003-01-01

Nonpoint sources of nutrients (NPS) are a widespread source of surface water pollution throu&out the United States. Characterizing the sources of this NPS nutrient loading is challenging due to variation in land management practices, physioyaphic setting, site conditions such as soil type, and climatic variation. For nutrients, there is the added challenge of...

CHARACTERIZING THE EFFECT OF CHLORINE AND CHLORAMINES ON THE FORMATION OF BIOFILM IN A SIMULATED DRINKING WATER DISTRIBUTION SYSTEM

EPA Science Inventory

Drinking wate treatment in the US has played a major role in protecting public health through the reduction of wateborne disease. However, carcinogenic and toxic contaminants continue to threaten the quality of surface and ground water in the US. The passage of the Safe Drinking ...

THE USE OF PYROLYSIS/GC/MS TO CHARACTERIZE THE ORGANIC QUALITY OF SURFACE WATERS; SPECIAL APPLICATION TO DRINKING WATER TREATMENT AND THE FORMATION OF DISINFECTION BYPRODUCTS

EPA Science Inventory

Natural Organ Material (NOM) in aquatic systems controls the effectiveness of engineered treatment processes and the fate of metals and pollutants in natural systems. At present less than 20% of NOM components can be identified. Pyrolysis-Gas Chromatography-Mass Spectrometry (P...

The effect of changes in surface wettability on two-phase saturated flow in horizontal replicas of single natural fractures.

PubMed

Bergslien, Elisa; Fountain, John

2006-12-15

By using translucent epoxy replicas of natural single fractures, it is possible to optically measure aperture distribution and directly observe NAPL flow. However, detailed characterization of epoxy reveals that it is not a sufficiently good analogue to natural rock for many two-phase flow studies. The surface properties of epoxy, which is hydrophobic, are quite unlike those of natural rock, which is generally assumed to be hydrophilic. Different surface wettabilities result in dramatically different two-phase flow behavior and residual distributions. In hydrophobic replicas, the NAPL flows in well-developed channels, displacing water and filling all of the pore space. In hydrophilic replicas, the invading NAPL is confined to the largest aperture pathways and flow frequently occurs in pulses, with no limited or no stable channel development, resulting in isolated blobs with limited accessible surface area. The pulsing and channel abandonment behaviors described are significantly different from the piston-flow frequently assumed in current modeling practice. In addition, NAPL never achieved total saturation in hydrophilic models, indicating that significantly more than a monolayer of water was bound to the model surface. Despite typically only 60-80% NAPL saturation, there was generally good agreement between theoretically calculated Young-Laplace aperture invasion boundaries and the observed minimum apertures invaded. The key to determining whether surface wettability is negligible, or not, lies in accurate characterization of the contaminant-geologic media system under study. As long as the triple-point contact angle of the system is low (<20 degrees), the assumption of perfect water wettability is not a bad one.

Fabrication of polyamide thin-film nanocomposite membranes with enhanced surface charge for nitrate ion removal from water resources.

PubMed

Ghaee, A; Zerafat, M M; Askari, P; Sabbaghi, S; Sadatnia, B

2017-03-01

Exclusion due to membrane surface charge is considered as one of the main separation mechanisms occurring in charged membranes, which can be varied through various approaches to affect membrane rejection performance. In this study, thin-film composite (TFC) polyamide (PA) membranes were fabricated via interfacial polymerization of m-phenylenediamine (m-PDA) and 2,4-diaminobenzene sulfonic acid with trimesoyl chloride (TMC) on a polysulfone sub-layer. The ability of the prepared membrane to remove nitrate ions from water resources has been investigated. In order to improve membrane permeability, zeolite-PA thin film nanocomposite (TFN) membranes were fabricated by incorporating natural zeolite nanoparticles obtained through ball milling of an Iranian natural zeolite powder in the interfacial polymerization process. The size, morphology and specific surface area of the as-obtained nanozeolite were characterized using particle size analysis, FE-SEM and BET. The functional groups, morphology and surface charge of the membrane were characterized using ATR-FTIR, SEM and zeta potential analyses. Also, field-emission scanning electron microscopy (FE-SEM) and energy dispersive X-ray spectroscopy (EDS) were used to determine the distribution of nanozeolite in TFN membranes. The influence of zeolite addition to surface roughness was accessed by atomic force microscopy. The performance of TFC and TFN membranes was evaluated in terms of pure water flux and nitrate rejection. The results showed that in case of sulfonated diamine, nitrate ions rejection was enhanced from 63% to 85% which could be attributed to surface charge enhancement. TFN permeability was almost doubled by the addition of nanozeolite.

The Role of the Persian Gulf in Shaping Southwest Asian Surface Climate

NASA Astrophysics Data System (ADS)

Pal, J. S.; Eltahir, E. A. B.

2015-12-01

Summer surface climate of the Persian Gulf region is characterized by hot and humid conditions. Despite such conditions - which in other regions tends to trigger moist convection - typically this region experiences clear sky conditions and very little rainfall in the summer. In this study, we customize the MIT Regional Climate Model specifically for the Southwest Asia region and apply it at a 25-km grid spacing using reanalysis boundary conditions for present-day climate (1975-2005). Specific customizations include accurate representations of surface albedo and emissivity as well as mineral dust processes, all of which improve model bias. To assess the role of the Persian Gulf in shaping the region's climate, a 30-year experiment is performed without the Persian Gulf characterized. Results suggest that observed conditions over the Persian Gulf are due to a combination of physical processes involving adiabatic and diabatic descent. First, virtually clear sky conditions, due to subsidence during summer associated with the rising air motion over the monsoon region to the east, suppress upward motion and deep convection and increase incoming solar radiation. Second, the low surface albedo of the Persian Gulf results in enhanced absorption of solar radiation and total heat flux. Third, high evaporation rates increase water vapor, and therefore trap heat at the surface via the greenhouse effect for water vapor. Fourth, the relatively shallow boundary layer over the Persian Gulf concentrates water vapor and heat close to the surface. These combined factors maximize the total flux of heat in the boundary layer and hence moist static energy over the Persian Gulf.

Characterization of dissolved organic matter from surface waters with low to high dissolved organic carbon and the related disinfection byproduct formation potential.

PubMed

Li, Angzhen; Zhao, Xu; Mao, Ran; Liu, Huijuan; Qu, Jiuhui

2014-04-30

In this study, the disinfection byproduct formation potential (DBPFP) of three surface waters with the dissolved organic carbon (DOC) content of 2.5, 5.2, and 7.9mg/L was investigated. The formation and distribution of trihalomethanes and haloacetic acids were evaluated. Samples collected from three surface waters in China were fractionated based on molecular weight and hydrophobicity. The raw water containing more hydrophobic (Ho) fraction exhibited higher formation potentials of haloacetic acid and trihalomethane. The DBPFP of the surface waters did not correlate with the DOC value. The values of DBPFP per DOC were correlated with the specific ultraviolet absorbance (SUVA) for Ho and Hi fractions. The obtained results suggested that SUVA cannot reveal the ability of reactive sites to form disinfection byproducts for waters with few aromatic structures. Combined with the analysis of FTIR and nuclear magnetic resonance spectra of the raw waters and the corresponding fractions, it was concluded that the Ho fraction with phenolic hydroxyl and conjugated double bonds was responsible for the production of trichloromethanes and trichloroacetic acids. The Hi fraction with amino and carboxyl groups had the potential to form dichloroacetic acids and chlorinated trihalomethanes. Copyright © 2014. Published by Elsevier B.V.

Relating landscape characteristics to non-point source pollution in mine waste-located watersheds using geospatial techniques.

PubMed

Xiao, Huaguo; Ji, Wei

2007-01-01

Landscape characteristics of a watershed are important variables that influence surface water quality. Understanding the relationship between these variables and surface water quality is critical in predicting pollution potential and developing watershed management practices to eliminate or reduce pollution risk. To understand the impacts of landscape characteristics on water quality in mine waste-located watersheds, we conducted a case study in the Tri-State Mining District which is located in the conjunction of three states (Missouri, Kansas and Oklahoma). Severe heavy metal pollution exists in that area resulting from historical mining activities. We characterized land use/land cover over the last three decades by classifying historical multi-temporal Landsat imagery. Landscape metrics such as proportion, edge density and contagion were calculated based on the classified imagery. In-stream water quality data over three decades were collected, including lead, zinc, iron, cadmium, aluminum and conductivity which were used as key water quality indicators. Statistical analyses were performed to quantify the relationship between landscape metrics and surface water quality. Results showed that landscape characteristics in mine waste-located watersheds could account for as much as 77% of the variation of water quality indicators. A single landscape metric alone, such as proportion of mine waste area, could be used to predict surface water quality; but its predicting power is limited, usually accounting for less than 60% of the variance of water quality indicators.

Site characterization summary report for dry weather surface water sampling upper East Fork Poplar Creek characterization area Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

This report describes activities associated with conducting dry weather surface water sampling of Upper East Fork Poplar Creek (UEFPC) at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee. This activity is a portion of the work to be performed at UEFPC Operable Unit (OU) 1 [now known as the UEFPC Characterization Area (CA)], as described in the RCRA Facility Investigation Plan for Group 4 at the Oak- Ridge Y-12 Plant, Oak Ridge, Tennessee and in the Response to Comments and Recommendations on RCRA Facility Investigation Plan for Group 4 at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee, Volume 1,more » Operable Unit 1. Because these documents contained sensitive information, they were labeled as unclassified controlled nuclear information and as such are not readily available for public review. To address this issue the U.S. Department of Energy (DOE) published an unclassified, nonsensitive version of the initial plan, text and appendixes, of this Resource Conservation and Recovery Act (RCRA) Facility Investigation (RFI) Plan in early 1994. These documents describe a program for collecting four rounds of wet weather and dry weather surface water samples and one round of sediment samples from UEFPC. They provide the strategy for the overall sample collection program including dry weather sampling, wet weather sampling, and sediment sampling. Figure 1.1 is a schematic flowchart of the overall sampling strategy and other associated activities. A Quality Assurance Project Plan (QAPJP) was prepared to specifically address four rounds of dry weather surface water sampling and one round of sediment sampling. For a variety of reasons, sediment sampling has not been conducted and has been deferred to the UEFPC CA Remedial Investigation (RI), as has wet weather sampling.« less

Methane evasion and oxidation in the Big Cypress National Preserve—a low relief carbonate wetland

NASA Astrophysics Data System (ADS)

Ward, N. D.; Bianchi, T. S.; Cohen, M. J.; Martin, J. B.; Quintero, C.; Brown, A.; Osborne, T.; Sawakuchi, H. O.

2016-12-01

The Big Cypress National Preserve is a low relief carbonate wetland characterized by unique basin patterning known as "cypress domes." Here we examine the concentration and stable isotopic composition of methane in pore waters, surface waters, and bubbles from the sediment across horizontal gradients in four domes during three sampling campaigns. The proportion of methane oxidized in surface waters was estimated based on isotopic differences between surface water and pore waters/bubbles. Rates of methane evasion from surface waters, soils, and cypress knees to the atmosphere were also measured. Surface water CH4 concentrations ranged from 170 to 4,533 ppm with the highest levels generally being observed during wet periods. Pore water CH4 concentrations ranged from 748 to 75,213 ppm. The concentration of methane in bubbles ranged from 6.5 to 71%. The stable isotopic composition of CH4 ranged from -69.2 to -43.8‰ for all samples and was generally more enriched in surface waters compared to bubbles and porewaters, particularly in the two domes that were persistently inundated throughout the year. Based on these isotopic values, the average percentage of surface water CH4 that was oxidized was 37 ± 16% (maximum of 67%) and 19 ± 4% (maximum of 47%) in the two domes that are persistently inundated versus the two domes that are not inundated during the dry season, respectively. The average rate of CH4 evasion was 3.6 ± 1.6 mmol m-2 d-1 via diffusion, 7.6 ± 4.7 mmol m-2 d-1 via ebullition, 10.9 ± 11.4 mmol m-2 d-1­ from soil surfaces, and 34.3 ± 27.4 mmol m-2 d-1 from cypress knees. These results indicate that CH4 is produced in great quantities in inundated sediments, particularly in the center of the cypress domes. Diffusive fluxes from surface waters are suppressed by microbial oxidation in the water column, whereas ebullition from sediments and evasion through cypress knees, and likely other vascular vegetation, are the primary pathways for CH4 outgassing.

Interaction of poly(ethylene-glycols) with air-water interfaces and lipid monolayers: investigations on surface pressure and surface potential.

PubMed Central

Winterhalter, M; Bürner, H; Marzinka, S; Benz, R; Kasianowicz, J J

1995-01-01

We have characterized the surface activity of different-sized poly(ethylene-glycols) (PEG; M(r) 200-100,000 Da) in the presence or absence of lipid monolayers and over a wide range of bulk PEG concentrations (10(-8)-10% w/v). Measurements of the surface potential and surface pressure demonstrate that PEGs interact with the air-water and lipid-water interfaces. Without lipid, PEG added either to the subphase or to the air-water interface forms relatively stable monolayers. Except for very low molecular weight polymers (PEGs < 1000 Da), low concentrations of PEG in the subphase (between 10(-5) and 10(-4)% w/v) increase the surface potential from zero (with respect to the potential of a pure air-water interface) to a plateau value of approximately 440 mV. At much higher polymer concentrations, > 10(-1)% (w/v), depending on the molecular weight of the PEG and corresponding to the concentration at which the polymers in solution are likely to overlap, the surface potential decreases. High concentrations of PEG in the subphase cause a similar decrease in the surface potential of densely packed lipid monolayers spread from either diphytanoyl phosphatidylcholine (DPhPC), dipalmitoyl phosphatidylcholine (DPPC), or dioleoyl phosphatidylserine (DOPS). Adding PEG as a monolayer at the air-water interface also affects the surface activity of DPhPC or DPPC monolayers. At low lipid concentration, the surface pressure and potential are determined by the polymer. For intermediate lipid concentrations, the surface pressure-area and surface potential-area isotherms show that the effects due to lipid and PEG are not always additive and that the polymer's effect is distinct for the two lipids. When PEG-lipid-mixed monolayers are compressed to surface pressures greater than the collapse pressure for a PEG monolayer, the surface pressure-area and surface potential-area isotherms approach that of the lipid alone, suggesting that for this experimental condition PEG is expelled from the interface. PMID:8534807

Nanoscale Structure at Mineral-Fluid Interfaces

NASA Astrophysics Data System (ADS)

Sturchio, N. C.; Sturchio, N. C.; Fenter, P.; Cheng, L.; Park, C.; Zhang, Z.; Zhang, Z.; Nagy, K. L.; Schlegel, M. L.

2001-12-01

The nature of nanoparticles and their role in the natural environment is currently a subject of renewed interest. The high surface area (and surface area-to-volume ratio) of nanoparticles exerts a widespread influence on geochemical reactions and transport processes. A thorough understanding of the nanoscale world remains largely hypothetical, however, because of the challenges associated with characterizing nanoscale structures and processes. Recent insights gained from high-resolution synchrotron x-ray reflectivity measurements at the solid-fluid interfaces of macroscopic (i.e., mm-scale) mineral particles may provide relevant guidelines for expected nanoparticle surface structures. For example, at calcite-water and barite-water interfaces, undercoordinated surface cations bond with water species of variable protonation, and modest relaxations (to several hundredths of a nanometer) affect the outermost unit cells [1,2]. Undercoordinated tetrahedral ions at aluminosilicate surfaces also bond with water species, whereas interstitial or interlayer alkali or alkaline earth ions at the surface may readily exchange with hydronium or other ions; modest relaxations also affect the outermost unit cells [3,4]. Modulation of liquid water structure out to about one nanometer has been observed at the (001) cleavage surface of muscovite in deionized water, and may be present at other mineral-fluid interfaces [4]. Dissolution mechanisms at the orthoclase-water interface have been clarified by combining x-ray reflectivity and scanning force microscopy measurements [5]. Further progress in understanding nanoscale structures and processes at macroscopic mineral-water interfaces is likely to benefit nanoparticle studies. [1] Fenter et al. (2000) Geochim. Cosmochim. Acta 64, 1221-1228. [2] Fenter et al. (2001) J. Phys. Chem. B 105(34), 8112-8119. [3] Fenter et al. (2000) Geochim. Cosmochim. Acta 64, 3663-3673. [4] Cheng et al. (2001) Phys. Rev. Lett., (in press). [5] Teng et al. (2001) Geochim. Cosmochim. Acta 65, (in press).

Investigating summer flow paths in a Dutch agricultural field using high frequency direct measurements

NASA Astrophysics Data System (ADS)

Delsman, J. R.; Waterloo, M. J.; Groen, M. M. A.; Groen, J.; Stuyfzand, P. J.

2014-11-01

The search for management strategies to cope with projected water scarcity and water quality deterioration calls for a better understanding of the complex interaction between groundwater and surface water in agricultural catchments. We separately measured flow routes to tile drains and an agricultural ditch in a deep polder in the coastal region of the Netherlands, characterized by exfiltration of brackish regional groundwater flow and intake of diverted river water for irrigation and water quality improvement purposes. We simultaneously measured discharge, electrical conductivity and temperature of these separate flow routes at hourly frequencies, disclosing the complex and time-varying patterns and origins of tile drain and ditch exfiltration. Tile drainage could be characterized as a shallow flow system, showing a non-linear response to groundwater level changes. Tile drainage was fed primarily by meteoric water, but still transported the majority (80%) of groundwater-derived salt to surface water. In contrast, deep brackish groundwater exfiltrating directly in the ditch responded linearly to groundwater level variations and is part of a regional groundwater flow system. We could explain the observed salinity of exfiltrating drain and ditch water from the interaction between the fast-responding pressure distribution in the subsurface that determined groundwater flow paths (wave celerity), and the slow-responding groundwater salinity distribution (water velocity). We found water demand for maintaining water levels and diluting salinity through flushing to greatly exceed the actual sprinkling demand. Counterintuitively, flushing demand was found to be largest during precipitation events, suggesting the possibility of water savings by operational flushing control.

Acoustic activation of water-in-oil microemulsions for controlled salt dissolution.

PubMed

Baxamusa, Salmaan; Ehrmann, Paul; Ong, Jemi

2018-06-18

The dynamic nature of the oil-water interface allows for sequestration of material within the dispersed domains of a microemulsion. Microstructural changes should therefore change the dissolution rate of a solid surface in a microemulsion. We hypothesize that microstructural changes due to formulation and cavitation in an acoustic field will enable control over solid dissolution rates. Water-in-oil microemulsions were formulated using cyclohexane, water, Triton X-100, and hexanol. The microstructure and solvation properties of Winsor Type IV formulations were characterized. Dissolution rates of KH 2 PO 4 (KDP), were measured. A kinetic analysis isolated the effect of the microstructure, and rate enhancements due to cavitation effects on the microstructure were characterized by measuring dissolution rates in an ultrasonic field. Dispersed aqueous domains of 2-6 nm radius dissolve a solid block of KDP at 0-10 nm/min. Dissolution rate is governed not by the domain-surface collision frequency but rather by a dissolution probability per domain-surface encounter. Higher probabilities are correlated with larger domains. Rapid and reversible dissolution rate increases of up to 270× were observed under ultrasonic conditions, with <20% of the increase due to bulk heating effects. The rest is attributed to cavitation-induced changes to the domain microstructure, providing a simple method for remotely activating and de-activating dissolution. Copyright © 2018 Elsevier Inc. All rights reserved.

Detection of Vegetable Oil Variance Using Surface Plasmon Resonance (SPR) Technique

NASA Astrophysics Data System (ADS)

Supardianningsih; Panggabean, R. D.; Romadhon, I. A.; Laksono, F. D.; Nofianti, U.; Abraha, K.

2018-05-01

The difference between coconut oil, corn oil, olive oil, and palm oil has been detected using surface plasmon resonance (SPR) technique. This is a new method in material characterization that can be used to identify vegetable oil variance. The SPR curve was measured by SPR system consisting of optical instruments, mechanical instruments, Main UNIT, and user interface (computer). He-Ne laser beam of wavelength 633 nm was used as light source, while gold (Au) thin film evaporated on half cylinder prism was used as the base so that surface plasmon polariton (SPP) waves propagate at the interface. Tween-80 and PEG-400 are used as surfactant and co-surfactant to make water-oil emulsion from each sample. The sample was prepared with the ratio of oil: surfactant: co-surfactant as 1:2:1 and then stirred on the water to make emulsions. The angle shift was measured by the change of SPR angle from prism/Au/air system to prism/Au/water-oil emulsion. The different SPR angle of each sample has been detected in the various number of spray, a method that was used for depositing the emulsion. From this work, we conclude that the saturated fatty acid component was the most significant component that changes the refractive index in the vegetable oil in water emulsion that can be used to characterize the vegetable oil variance.

Pulsed losses and degradation of aldicarb in a South Florida agricultural watershed.

PubMed

Wilson, P Chris; Foos, Jane Ferguson; Jones, Russell L

2005-01-01

The objectives of these studies were to characterize patterns of movement of aldicarb, aldicarb sulfoxide, and aldicarb sulfone from a typical canalized South Florida watershed and to evaluate aldicarb dissipation in surface water in situ within a citrus grove. Surface water samples were collected daily or every other day from the discharge point for the watershed beginning May 15, 2001, through August 15, 2002. Of 457 samples collected, aldicarb, aldicarb sulfoxide, and aldicarb sulfone were detected in 6, 1, and 13, respectively. Aldicarb was detected from February through May 2002, corresponding to the legal application season of January 1 through April 30 in Florida. Aldicarb concentrations ranged from <0.16 to 4.97 ng ml(-1). A single detection (0.99 ng ml(-1)) of aldicarb sulfoxide occurred in March 2001. The majority of aldicarb sulfone detections occurred during June and July, 2001, after the application season, and ranged from <0.22 to 0.89 ng ml(-1). The half-life for aldicarb in fortified, native surface water ranged from 1.86 to 3.64 days depending on the source of water and the presence of sediments. These results demonstrated the utility of sampling on a frequent basis (compared with monthly or quarterly) for better characterizing pesticide discharges, especially in flashy systems such as canal-drained watersheds within South Florida.

Are engineered nano iron oxide particles safe? an environmental risk assessment by probabilistic exposure, effects and risk modeling.

PubMed

Wang, Yan; Deng, Lei; Caballero-Guzman, Alejandro; Nowack, Bernd

2016-12-01

Nano iron oxide particles are beneficial to our daily lives through their use in paints, construction materials, biomedical imaging and other industrial fields. However, little is known about the possible risks associated with the current exposure level of engineered nano iron oxides (nano-FeOX) to organisms in the environment. The goal of this study was to predict the release of nano-FeOX to the environment and assess their risks for surface waters in the EU and Switzerland. The material flows of nano-FeOX to technical compartments (waste incineration and waste water treatment plants) and to the environment were calculated with a probabilistic modeling approach. The mean value of the predicted environmental concentrations (PECs) of nano-FeOX in surface waters in the EU for a worst-case scenario (no particle sedimentation) was estimated to be 28 ng/l. Using a probabilistic species sensitivity distribution, the predicted no-effect concentration (PNEC) was determined from ecotoxicological data. The risk characterization ratio, calculated by dividing the PEC by PNEC values, was used to characterize the risks. The mean risk characterization ratio was predicted to be several orders of magnitude smaller than 1 (1.4 × 10 - 4 ). Therefore, this modeling effort indicates that only a very limited risk is posed by the current release level of nano-FeOX to organisms in surface waters. However, a better understanding of the hazards of nano-FeOX to the organisms in other ecosystems (such as sediment) needs to be assessed to determine the overall risk of these particles to the environment.

Fabrication of a novel superhydrophobic and superoleophilic surface by one-step electrodeposition method for continuous oil/water separation

NASA Astrophysics Data System (ADS)

Xiang, Meisu; Jiang, Meihuizi; Zhang, Yanzong; Liu, Yan; Shen, Fei; Yang, Gang; He, Yan; Wang, Lilin; Zhang, Xiaohong; Deng, Shihuai

2018-03-01

A novel superhydrophobic and superoleophilic surface was fabricated by one-step electrodeposition on stainless steel meshes, and the durability and oil/water separation properties were assessed. Field emission scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), fourier transform infrared spectroscopy (FT-IR) and optical contact angle measurements were used to characterize surface morphologies, chemical compositions, and wettabilities, respectively. The results indicated that the as-prepared mesh preformed excellent superhydrophobicity and superoleophilicity with a high water contact angle (WCA) of 162 ± 1° and oil contact angle of (OCA) 0°. Meanwhile, the as-prepared mesh also exhibited continuous separation capacity of many kinds of oil/water mixtures, and the separation efficiency for lubrication oil/water mixture was about 98.6%. In addition, after 10 separation cycles, the as-prepared mesh possessed the WCAs of 155 ± 2°, the OCAs of 0° and the separation efficiency of 97.8% for lubrication oil/water mixtures. The as-prepared mesh also retained superhydrophobic and superoleophilic properties after abrading, immersing in salt solutions and different pH solutions.

Interaction of hydrogen chloride and water with oxide surfaces. III - Titanium dioxide

NASA Technical Reports Server (NTRS)

Siriwardane, R. V.; Wightman, J. P.

1983-01-01

The adsorption of hydrogen chloride and water vapors on five TiO2 powders in both the anatase and rutile crystalline forms was studied as a function of temperature, pressure, and outgas conditions. The adsorbents were characterized utilizing X-ray powder diffraction, scanning electron microscopy, surface area analysis, indicator method, microelectrophoresis, XPS, and infrared spectroscopy. It was found that both outgas temperature and adsorption temperature influenced the adsorption of water vapor on TiO2, while water vapor adsorption on TiO2 was completely reversible. It is argued that the number of hydroxyl groups present on the surface determines the adsorption capacity of water on the different titanium dioxides. It was found that heats of immersion in water were affected significantly by outgas temperature. Hydrogen chloride adsorption isotherms at 30 C measured on TiO2 after outgassing at 100-400 C showed that a part of the total HCl adsorbed was irreversibly adsorbed. The highest HCl adsorption capacity per unit area was exhibited by anatase, while pure rutile exhibited the lowest adsorption capacity.

Challenges for implementing water quality monitoring and analysis on a small Costa Rican catchment

NASA Astrophysics Data System (ADS)

Golcher, Christian; Cernesson, Flavie; Tournoud, Marie-George; Bonin, Muriel; Suarez, Andrea

2016-04-01

The Costa Rican water regulatory framework (WRF) (2007), expresses the national concern about the degradation of surface water quality observed in the country since several years. Given the urgency of preserving and restoring the surface water bodies, and facing the need of defining a monitoring tool to classify surface water pollution, the Costa-Rican WRF relies on two water quality indexes: the so-called "Dutch Index" (D.I) and the Biological Monitoring Working Party adapted to Costa Rica (BMWP'CR), allowing an "easy" physicochemical and biological appraisal of the water quality and the ecological integrity of water bodies. Herein, we intend to evaluate whether the compound of water quality indexes imposed by Costa Rican legislation, is suitable to assess rivers local and global anthropogenic pressure and environmental conditions. We monitor water quality for 7 points of Liberia River (northern pacific region - Costa Rica) from March 2013 to July 2015. Anthropogenic pressures are characterized by catchment land use and riparian conditions. Environmental conditions are built from rainfall daily series. Our results show (i) the difficulties to monitor new sites following the recent implementation of the WRF; (ii) the statistical characteristics of each index; and (iii) a modelling tentative of relationships between water quality indexes and explanatory factors (land-use, riparian characteristics and climate conditions).

Structure of a model TiO2 photocatalytic interface

NASA Astrophysics Data System (ADS)

Hussain, H.; Tocci, G.; Woolcot, T.; Torrelles, X.; Pang, C. L.; Humphrey, D. S.; Yim, C. M.; Grinter, D. C.; Cabailh, G.; Bikondoa, O.; Lindsay, R.; Zegenhagen, J.; Michaelides, A.; Thornton, G.

2017-04-01

The interaction of water with TiO2 is crucial to many of its practical applications, including photocatalytic water splitting. Following the first demonstration of this phenomenon 40 years ago there have been numerous studies of the rutile single-crystal TiO2(110) interface with water. This has provided an atomic-level understanding of the water-TiO2 interaction. However, nearly all of the previous studies of water/TiO2 interfaces involve water in the vapour phase. Here, we explore the interfacial structure between liquid water and a rutile TiO2(110) surface pre-characterized at the atomic level. Scanning tunnelling microscopy and surface X-ray diffraction are used to determine the structure, which is comprised of an ordered array of hydroxyl molecules with molecular water in the second layer. Static and dynamic density functional theory calculations suggest that a possible mechanism for formation of the hydroxyl overlayer involves the mixed adsorption of O2 and H2O on a partially defected surface. The quantitative structural properties derived here provide a basis with which to explore the atomistic properties and hence mechanisms involved in TiO2 photocatalysis.

Structure of a model TiO2 photocatalytic interface.

PubMed

Hussain, H; Tocci, G; Woolcot, T; Torrelles, X; Pang, C L; Humphrey, D S; Yim, C M; Grinter, D C; Cabailh, G; Bikondoa, O; Lindsay, R; Zegenhagen, J; Michaelides, A; Thornton, G

2017-04-01

The interaction of water with TiO 2 is crucial to many of its practical applications, including photocatalytic water splitting. Following the first demonstration of this phenomenon 40 years ago there have been numerous studies of the rutile single-crystal TiO 2 (110) interface with water. This has provided an atomic-level understanding of the water-TiO 2 interaction. However, nearly all of the previous studies of water/TiO 2 interfaces involve water in the vapour phase. Here, we explore the interfacial structure between liquid water and a rutile TiO 2 (110) surface pre-characterized at the atomic level. Scanning tunnelling microscopy and surface X-ray diffraction are used to determine the structure, which is comprised of an ordered array of hydroxyl molecules with molecular water in the second layer. Static and dynamic density functional theory calculations suggest that a possible mechanism for formation of the hydroxyl overlayer involves the mixed adsorption of O 2 and H 2 O on a partially defected surface. The quantitative structural properties derived here provide a basis with which to explore the atomistic properties and hence mechanisms involved in TiO 2 photocatalysis.

Real-space characterization of reactivity towards water at the B i 2 T e 3 (111) surface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Kai-Wen; Ding, Ding; Yang, Chao-Long

2016-06-01

Surface reactivity is important in modifying the physical and chemical properties of surface-sensitive materials, such as the topological insulators. Even though many studies addressing the reactivity of topological insulators towards external gases have been reported, it is still under heavy debate whether and how the topological insulators react with H2O. Here, we employ scanning tunneling microscopy to directly probe the surface reaction of Bi2Te3 towards H2O. Surprisingly, it is found that only the top quintuple layer is reactive to H2O, resulting in a hydrated Bi bilayer as well as some Bi islands, which passivate the surface and prevent subsequent reaction.more » A reaction mechanism is proposed with H2Te and hydrated Bi as the products. Unexpectedly, our study indicates that the reaction with water is intrinsic and not dependent on any surface defects. Since water inevitably exists, these findings provide key information when considering the reactions of Bi2Te3 with residual gases or atmosphere.« less

Physical basis for river segmentation from water surface observables

NASA Astrophysics Data System (ADS)

Samine Montazem, A.; Garambois, P. A.; Calmant, S.; Moreira, D. M.; Monnier, J.; Biancamaria, S.

2017-12-01

With the advent of satellite missions such as SWOT we will have access to high resolution estimates of the elevation, slope and width of the free surface. A segmentation strategy is required in order to sub-sample the data set into reach master points for further hydraulic analyzes and inverse modelling. The question that arises is : what will be the best node repartition strategy that preserves hydraulic properties of river flow? The concept of hydraulic visibility introduced by Garambois et al. (2016) is investigated in order to highlight and characterize the spatio-temporal variations of water surface slope and curvature for different flow regimes and reach geometries. We show that free surface curvature is a powerful proxy for characterizing the hydraulic behavior of a reach since concavity of water surface is driven by variations in channel geometry that impacts the hydraulic properties of the flow. We evaluated the performance of three segmentation strategies by means of a well documented case, that of the Garonne river in France. We conclude that local extrema of free surface curvature appear as the best candidate for locating the segment boundaries for an optimal hydraulic representation of the segmented river. We show that for a given river different segmentation scales are possible: a fine-scale segmentation which is driven by fine-scale hydraulic to large-scale segmentation driven by large-scale geomorphology. The segmentation technique is then applied to high resolution GPS profiles of free surface elevation collected on the Negro river basin, a major contributor of the Amazon river. We propose two segmentations: a low-resolution one that can be used for basin hydrology and a higher resolution one better suited for local hydrodynamic studies.

Fringe Capacitance Correction for a Coaxial Soil Cell

PubMed Central

Pelletier, Mathew G.; Viera, Joseph A.; Schwartz, Robert C.; Lascano, Robert J.; Evett, Steven R.; Green, Tim R.; Wanjura, John D.; Holt, Greg A.

2011-01-01

Accurate measurement of moisture content is a prime requirement in hydrological, geophysical and biogeochemical research as well as for material characterization and process control. Within these areas, accurate measurements of the surface area and bound water content is becoming increasingly important for providing answers to many fundamental questions ranging from characterization of cotton fiber maturity, to accurate characterization of soil water content in soil water conservation research to bio-plant water utilization to chemical reactions and diffusions of ionic species across membranes in cells as well as in the dense suspensions that occur in surface films. One promising technique to address the increasing demands for higher accuracy water content measurements is utilization of electrical permittivity characterization of materials. This technique has enjoyed a strong following in the soil-science and geological community through measurements of apparent permittivity via time-domain-reflectometry (TDR) as well in many process control applications. Recent research however, is indicating a need to increase the accuracy beyond that available from traditional TDR. The most logical pathway then becomes a transition from TDR based measurements to network analyzer measurements of absolute permittivity that will remove the adverse effects that high surface area soils and conductivity impart onto the measurements of apparent permittivity in traditional TDR applications. This research examines an observed experimental error for the coaxial probe, from which the modern TDR probe originated, which is hypothesized to be due to fringe capacitance. The research provides an experimental and theoretical basis for the cause of the error and provides a technique by which to correct the system to remove this source of error. To test this theory, a Poisson model of a coaxial cell was formulated to calculate the effective theoretical extra length caused by the fringe capacitance which is then used to correct the experimental results such that experimental measurements utilizing differing coaxial cell diameters and probe lengths, upon correction with the Poisson model derived correction factor, all produce the same results thereby lending support and for an augmented measurement technique for measurement of absolute permittivity. PMID:22346601

Natural attenuation of chlorinated-hydrocarbon contamination at Fort Wainwright, Alaska; a hydrogeochemical and microbiological investigation workplan

USGS Publications Warehouse

McCarthy, Kathleen A.; Lilly, Michael R.; Braddock, Joan F.; Hinzman, Larry D.

1998-01-01

Natural attenuation processes include biological degradation, by which microorganisms break down contaminants into simpler product compounds; adsorption of contaminants to soil particles, which decreases the mass of contaminants dissolved in ground water; and dispersion, which decreases dissolved contaminant concentrations through dilution. The primary objectives of this study are to (1) assess the degree to which such natural processes are attenuating chlorinated-hydrocarbon contamination in ground water, and (2) evaluate the effects of ground-water/surface-water interactions on natural-attenuation processes in the area of the former East and West Quartermasters Fueling Systems for Fort Wainwright, Alaska. The study will include investigations of the hydrologic, geochemical, and microbiological processes occurring at this site that influence the transport and fate of chlorinated hydrocarbons in ground water. To accomplish these objectives, a data-collection program has been initiated that includes measurements of water-table elevations and the stage of the Chena River; measurements of vertical temperature profiles within the subsurface; characterization of moisture distribution and movement in the unsaturated zone; collection of ground-water samples for determination of both organic and inorganic chemical constituents; and collection of ground-water samples for enumeration of microorganisms and determination of their potential to mineralize contaminants. We will use results from the data-collection program described above to refine our conceptual model of hydrology and contaminant attenuation at this site. Measurements of water-table elevations and river stage will help us to understand the magnitude and direction of ground-water flow and how changes in the stage of the Chena River affect ground-water flow. Because ambient ground water and surface water typically have different temperature characteristics, temperature monitoring will likely provide further insight into ground-water/surface-water interactions in the subsurface. Characterization of the unsaturated zone will improve our understanding of interactions among ground water, the unsaturated zone, and the atmosphere. The interactions likely of importance to this study include the migration of water, dissolved contaminants, nutrients, and gases (oxygen, carbon dioxide, and methane) between the saturated and unsaturated zones. We will use the results of ground-water chemical analyses to determine the spatial and temporal distribution of (1) chlorinated-hydrocarbon contaminants and their degradation products, (2) oxidation-reduction indicators, (3) nutrients, and (4) major ground-water ions. These water-quality data will provide insight into ground-water flow directions, interactions between ground water and surface water, attenuation of contaminant concentrations caused by dispersion, and intrinsic microbiological processes. Microbiological analyses will indicate whether microorganisms at the site are capable of degrading the contaminants of interest, and will allow us to estimate their potential to attenuate existing contamination. Physical and chemical data interpreted as part of the analysis of ground water and surface water mixing will improve our understanding of the relationship between water quality and contaminant source mixing.

An anti-bacterial approach to nanoscale roughening of biomimetic rice-like pattern PP by thermal annealing

NASA Astrophysics Data System (ADS)

Jafari Nodoushan, Emad; Ebrahimi, Nadereh Golshan; Ayazi, Masoumeh

2017-11-01

In this paper, we introduced thermal annealing treatment as an effective way of increasing the nanoscale roughness of a semi-crystalline polymer surface. Annealing treatment applied to a biomimetic microscale pattern of rice leaf to achieve a superhydrophobic surface with a hierarchical roughness. Resulted surfaces was characterized by XRD, AFM and FE-SEM instruments and showed an increase of roughness and cristallinity within both time and temperature of treatment. These two parameters also impact on measured static contact angle up to 158°. Bacterial attachment potency has an inverse relationship with the similarity of surface pattern dimensions and bacterial size and due to that, thermal annealing could be an effective way to create anti-bacterial surface beyond its effect on water repellency. Point in case, the anti-bacterial properties of produced water-repellence surfaces of PP were measured and counted colonies of both gram-negative (E. coli) and gram-positive (S. aureus) bacteria reduced with the nature of PP and hierarchical pattern on that. Anti-bacterial characterization of the resulted surface reveals a stunning reduction in adhesion of gram-positive bacteria to the surface. S. aureus reduction rates equaled to 95% and 66% when compared to control blank plate and smooth surface of PP. Moreover, it also could affect the other type of bacteria, gram-negative (E. coli). In the latter case, adhesion reduction rates calculated 66% and 53% when against to the same controls, respectively.

Fabrication of phytic acid sensor based on mixed phytase-lipid Langmuir-Blodgett films.

PubMed

Caseli, Luciano; Moraes, Marli L; Zucolotto, Valtencir; Ferreira, Marystela; Nobre, Thatyane M; Zaniquelli, Maria Elisabete D; Rodrigues Filho, Ubirajara P; Oliveira, Osvaldo N

2006-09-26

This paper reports the surface activity of phytase at the air-water interface, its interaction with lipid monolayers, and the construction of a new phytic acid biosensor on the basis of the Langmuir-Blodgett (LB) technique. Phytase was inserted in the subphase solution of dipalmitoylphosphatidylglycerol (DPPG) Langmuir monolayers, and its incorporation to the air-water interface was monitored with surface pressure measurements. Phytase was able to incorporate into DPPG monolayers even at high surface pressures, ca. 30 mN/m, under controlled ionic strength, pH, and temperature. Mixed Langmuir monolayers of phytase and DPPG were characterized by surface pressure-area and surface potential-area isotherms, and the presence of the enzyme provided an expansion in the monolayers (when compared to the pure lipid at the interface). The enzyme incorporation also led to significant changes in the equilibrium surface compressibility (in-plane elasticity), especially in liquid-expanded and liquid-condensed regions. The dynamic surface elasticity for phytase-containing interfaces was investigated using harmonic oscillation and axisymmetric drop shape analysis. The insertion of the enzyme at DPPG monolayers caused an increase in the dynamic surface elasticity at 30 mN m(-)(1), indicating a strong interaction between the enzyme and lipid molecules at a high-surface packing. Langmuir-Blodgett (LB) films containing 35 layers of mixed phytase-DPPG were characterized by ultraviolet-visible and fluorescence spectroscopy and crystal quartz microbalance nanogravimetry. The ability in detecting phytic acid was studied with voltammetric measurements.

Characterizing ecosystem response to water supply changes inferred from GRACE drought severity index and surface soil moisture anomalies from ESA CCI and SMAP

NASA Astrophysics Data System (ADS)

Zhao, M.; Velicogna, I.; Kimball, J. S.

2017-12-01

Climate change such as more frequent heatwaves and drought is threatening our food security and ecosystem by reducing water supply to vegetation. Characterizing vegetation response to water supply changes is not only important for evaluating and mitigating climatic change impacts on ecosystem functions and services, but also to determine the feedback mechanisms that ecosystem response may generate on the climate itself. However, such characterization is not well-known at the global scale partly because large scale observations of underground water supply changes are limited. Satellite observations of soil moisture (SM) datasets such as from Soil Moisture Active and Passive (SMAP) and European Space Agency Climate Change Initiative (ESA CCI) do not penetrate more than a few centimeters and do not capture the entire root-zone. Here we employ a newly developed Drought Severity Index from Gravity Recovery and Climate Experiment (GRACE-DSI) to complement SM observations by informing total water supply changes in the entire terrestrial hydrological cycle. We use MODIS vegetation indices as proxies for vegetation growth and investigate their seasonal and interannual variability in relation to GRACE-DSI. We find that total water supply constrains vegetation growth across the entire continental US. Water constraint begins at an earlier date of year and lasts for a longer period in the lower latitude than in the higher latitude. We also find that water constraint occurs at different phenological stages depending on vegetation type. For instance, water constrain forest growth during reproductive period in eastern US but constrain shrub land growth during green-up in Arizona (Fig. 1). In western United States, eastern Australia and the horn of Africa, we find that vegetation growth changes closely follows GRACE-DSI but can have 16-day to one-month delay with respect to SM anomalies from SMAP and ESA CCI. This suggests that in these regions, vegetation is sensitive to water supply changes in the deeper soil layers than in the shallower surface.

Underwater MASW to evaluate stiffness of water-bottom sediments

USGS Publications Warehouse

Park, C.B.; Miller, R.D.; Xia, J.; Ivanov, J.; Sonnichsen, G.V.; Hunter, J.A.; Good, R.L.; Burns, R.A.; Christian, H.

2005-01-01

The multichannel analysis of surface waves (MASW) is initially intended as a land survey method to investigate the near-surface materials for their elastic properties. The acquired data are first analyzed for dispersion characteristics and, from these the shear-wave velocity is estimated using an inversion technique. Land applications show the potential of the MASW method to map 2D bedrock surface, zones of low strength, Poisson's ratio, voids, as well as to generate shear-wave profiles for various othe geotechnical problems. An overview is given of several underwater applications of the MASW method to characterize stiffness distribution of water-bottom sediments. The first application details the survey under shallow-water (1-6 m) in the Fraser River (Canada). The second application is an innovative experimental marine seismic survey in the North Atlantic Ocean near oil fields in Grand Bank offshore Newfoundland.

Manufacturing and actuation characterization of ionic polymer metal composites with silver as electrodes

NASA Astrophysics Data System (ADS)

Pandita, Surya D.; Lim, Hyoung Tae; Yoo, Youngtai; Park, Hoon Cheol

2006-03-01

Manufacturing and characterization of ionic polymer metal composites (IPMCs) with silver as electrodes have been investigated. Tollen's reagent that contains ion Ag(NH 3) II + was used as a raw material for silver deposition on the surfaces of the polymer membrane Nafion"R". Two types of inner solvents, namely common water based electrolyte solution (LiOH 1N) and ionic liquid were used and investigated. Compared to IPMCs with platinum electrodes, silver-plated IPMCs with water electrolyte showed higher conductivity. The actuation response of silver-plated IPMCs with the water based electrolyte was faster than that of platinum IPMCs. However, the silver electrode was too brittle and severely damaged during the solvent exchange process from water to ionic liquid, resulted in high resistance and hence very low actuation behavior.

Adsorbent synthesis of polypyrrole/TiO(2) for effective fluoride removal from aqueous solution for drinking water purification: Adsorbent characterization and adsorption mechanism.

PubMed

Chen, Jie; Shu, Chiajung; Wang, Ning; Feng, Jiangtao; Ma, Hongyu; Yan, Wei

2017-06-01

More than 20 countries are still suffering problems of excessive fluoride containing water, and greater than 8mg/L fluoride groundwater has been reported in some villages in China. In order to meet the challenge in the drinking water defluoridation engineering, a high efficiency and affinity defluoridation adsorbent PPy/TiO 2 composite was designed and synthetized by in-situ chemical oxidative polymerization. Fourier Transform Infrared Spectroscopy (FTIR), X-ray diffraction Investigator (XRD), X-ray photoelectron spectroscopy (XPS), Thermogravimetric analysis (TG), N 2 isotherm analysis, Scanning Electron Microscopy (SEM) and Zeta potential analysis were conducted to characterize surface and textural properties of the as-prepared PPy/TiO 2 , and the possibility of fluoride adsorption was carefully estimated by adsorption isotherm and kinetic studies. Characterization investigations demonstrate the uniqueness of surface and textural properties, such as suitable specific surface area and abundant positively charged nitrogen atoms (N + ), which indicate the composite is a suitable material for the fluoride adsorption. Adsorption isotherms and kinetics follow better with Langmuir and pseudo-second-order model, respectively. The maximum adsorption capacity reaches 33.178mg/g at 25°C according to Langmuir model, and particular interest was the ability to reduce the concentration of fluoride from 11.678mg/L to 1.5mg/L for drinking water at pH of 7 within 30min. Moreover, the adsorbent can be easily recycled without the loss of adsorption capacity after six cycles, greatly highlighting its outstanding affinity to fluoride, low-cost and novel to be used in the purification of fluoride containing water for drinking. Furthermore, the adsorption mechanism was extensively investigated and discussed by FTIR investigation and batch adsorption studies including effect of pH, surface potential and thermodynamics. The adsorption is confirmed to be a spontaneous and exothermic process with decreasing entropy, which is prominently conducted through electrostatic attraction, and ionic exchange, and chelation may be also involved. Hydroxyls and positively charged nitrogen atoms play important roles in the adsorption. Copyright © 2017 Elsevier Inc. All rights reserved.

Wastewater Characterization Survey, Cannon Air Force Base, New Mexico

DTIC Science & Technology

1993-05-01

Consultant, Water Qu 1ity Franch Chief, Bioenironmental Engineering Division Form ApprovedREPORT DOCUMENTATION PAGE OMB No. 0704-0188 Public reporting burden...aquatic food chain and/or storage in plant Water Act are followed; sewers. and animal tissues, can be magnified to 10. provides continuing technical train...continuously throughout the year in all food chains, will cause death, disease, be- face or ground water at a frequency and years; its upper surface

Manipulating surface wettability and oil absorbency of diatomite depending on processing and ambient conditions

NASA Astrophysics Data System (ADS)

Özen, İlhan; Şimşek, Süleyman; Okyay, Gamze

2015-03-01

In this study, a diatomite sample, which is a natural inorganic mineral with inherently high water and oil absorption capacity, was subjected to grinding before surface modification. Afterwards, the diatomite surface was modified via facile methods using a fluorocarbon (FC) chemical and stearic acid (SA) in addition to the sol-gel fluorosilanization (FS) process. The water and oil wettability, and oil absorbency properties of the unmodified and modified diatomites were investigated in addition to diatomite characterizations such as chemical content, surface area, particle size distribution, morphology, and modification efficiency. It was revealed that the wettability was changed completely depending on the surface modification agent and the media used, while the oil absorbency property surprisingly did not change. On the other hand, the oil absorbency was worsened by the grinding process, whereas the wettability was not affected.

Fundamental characteristics study of anion-exchange PVDF-SiO(2) membranes.

PubMed

Zuo, Xingtao; Shi, Wenxin; Yu, Shuili; He, Jiajie

2012-01-01

A new type of poly(vinylidene fluoride)(PVDF)-SiO(2) hybrid anion-exchange membrane was prepared by blending method. The anion-exchange groups were introduced by the reaction of epoxy groups with trimethylamine (TMA). Contact angle between water and the membrane surface was measured to characterize the hydrophilicity change of the membrane surface. The effects of nano-sized SiO(2) particles in the membrane-forming materials on the membrane mechanical properties and conductivity were also investigated. The experimental results indicated that PVDF-SiO(2) anion-exchange membranes exhibited better water content, ion-exchange capacity, conductivity and mechanic properties, and so may find potential applications in alkaline membrane fuel cells and water treatment processes.

Microbial control of silicate weathering in organic-rich ground water

USGS Publications Warehouse

Hiebert, Franz K.; Bennett, Philip C.

1992-01-01

An in situ microcosm study of the influence of surface-adhering bacteria on silicate diagenesis in a shallow petroleum-contaminated aquifer showed that minerals were colonized by indigenous bacteria and chemically weathered at a rate faster than theoretically predicted. Feldspar and quartz fragments were placed in anoxic, organic-rich ground water, left for 14 months, recovered, and compared to unreacted controls with scanning electron microscopy. Ground-water geochemistry was characterized before and after the experiment. Localized mineral etching probably occurred in a reaction zone at the bacteria-mineral interface where high concentrations of organic acids, formed by bacteria during metabolism of hydrocarbon, selectively mobilized silica and aluminum from the mineral surface.

Satellite Soil Moisture and Water Storage Observations Identify Early and Late Season Water Supply Influencing Plant Growth in the Missouri Watershed

NASA Astrophysics Data System (ADS)

A, G.; Velicogna, I.; Kimball, J. S.; Du, J.; Kim, Y.; Colliander, A.; Njoku, E. G.

2017-12-01

We employ an array of continuously overlapping global satellite sensor observations including combined surface soil moisture (SM) estimates from SMAP, AMSR-E and AMSR-2, GRACE terrestrial water storage (TWS), and satellite precipitation measurements, to characterize seasonal timing and inter-annual variations of the regional water supply pattern and its associated influence on vegetation growth estimates from MODIS enhanced vegetation index (EVI), AMSR-E/2 vegetation optical depth (VOD) and GOME-2 solar-induced florescence (SIF). Satellite SM is used as a proxy of plant-available water supply sensitive to relatively rapid changes in surface condition, GRACE TWS measures seasonal and inter-annual variations in regional water storage, while precipitation measurements represent the direct water input to the analyzed ecosystem. In the Missouri watershed, we find surface SM variations are the dominant factor controlling vegetation growth following the peak of the growing season. Water supply to growth responds to both direct precipitation inputs and groundwater storage carry-over from prior seasons (winter and spring), depending on land cover distribution and regional climatic condition. For the natural grassland in the more arid central and northwest watershed areas, an early season anomaly in precipitation or surface temperature can have a lagged impact on summer vegetation growth by affecting the surface SM and the underlying TWS supplies. For the croplands in the more humid eastern portions of the watershed, the correspondence between surface SM and plant growth weakens. The combination of these complementary remote-sensing observations provides an effective means for evaluating regional variations in the timing and availability of water supply influencing vegetation growth.

Characterizing water-metal interfaces and machine learning potential energy surfaces

NASA Astrophysics Data System (ADS)

Ryczko, Kevin

In this thesis, we first discuss the fundamentals of ab initio electronic structure theory and density functional theory (DFT). We also discuss statistics related to computing thermodynamic averages of molecular dynamics (MD). We then use this theory to analyze and compare the structural, dynamical, and electronic properties of liquid water next to prototypical metals including platinum, graphite, and graphene. Our results are built on Born-Oppenheimer molecular dynamics (BOMD) generated using density functional theory (DFT) which explicitly include van der Waals (vdW) interactions within a first principles approach. All calculations reported use large simulation cells, allowing for an accurate treatment of the water-electrode interfaces. We have included vdW interactions through the use of the optB86b-vdW exchange correlation functional. Comparisons with the Perdew-Burke-Ernzerhof (PBE) exchange correlation functional are also shown. We find an initial peak, due to chemisorption, in the density profile of the liquid water-Pt interface not seen in the liquid water-graphite interface, liquid watergraphene interface, nor interfaces studied previously. To further investigate this chemisorption peak, we also report differences in the electronic structure of single water molecules on both Pt and graphite surfaces. We find that a covalent bond forms between the single water molecule and the platinum surface, but not between the single water molecule and the graphite surface. We also discuss the effects that defects and dopants in the graphite and graphene surfaces have on the structure and dynamics of liquid water. Lastly, we introduce artificial neural networks (ANNs), and demonstrate how they can be used to machine learn electronic structure calculations. As a proof of principle, we show the success of an ANN potential energy surfaces for a dimer molecule with a Lennard-Jones potential.

Modeling the interaction Between Ethylene Diamine and Water Films on the Surface of a Carbon Nanotube

NASA Technical Reports Server (NTRS)

Jaffe, Richard L.; Walther, Jens H.; Zimmerli, Urs; Koumoutsakos, Petros

2004-01-01

It has been observed that a carbon nanotube (CNT) AFM tip coated with ethylene diamine (EDA) penetrates the liquid water-air interface more easily than an uncoated nanotube tip. The EDA coating remains intact through repeated cycles of dipping and removal. In order to understand the physical basis for this observation, we use ab initio quantum chemistry calculations to study the EDA-CNT-water interaction and to parameterize a force field describing this system. Molecular dynamics (MD) simulations are carried out for EDA-water mixtures and an EDA-coated carbon nanotube immmed in water. These simulations are similar to our earlier MD study that characterized the CNT-water interface. The attractive CNT-EDA and CNT-water interactions arise primarily from van der Waals forces, and the EDA-EDA, EDA-water and water-water interactions are mainly due to hydrogen bond formation. The binding energ of single EDA molecule to the nanotube is nearly three times larger than the corresponding value found for water (4.3 versus 1.5 kcal mol, respectively). The EDA molecules readily stick to and diffuse along the CNT surface. As a resulf mixing of the EDA and water films does not occur on the timescale of the MD simulations. The EDA film reduces the hydrophobicity of the nanotube surface and acts like a prototypical surfactant in stabilizing the suspension of carbon nanotubes in water. For this presentation, we use the MD simulations to determine how the presence of the carbon nanotube surface perturbs the properties of EDA-water mixtures.

Variable exchange between a stream and an aquifer in the Rio Grande Project Area

NASA Astrophysics Data System (ADS)

Sheng, Z.; Abudu, S.; Michelsen, A.; King, P.

2016-12-01

Both surface water and groundwater in the Rio Grande Project area in southern New Mexico and Far West Texas have been stressed by natural conditions such as droughts and human activities, including urban development and agricultural irrigation. In some area pumping stress in the aquifer becomes so great that it depletes the river flow especially during the irrigation season, typically from March through October. Therefore understanding such relationship between surface water and groundwater becomes more important in regional water resources planning and management. In this area, stream flows are highly regulated by the upstream reservoirs during the irrigation season and greatly influenced by return flows during non-irrigation season. During a drought additional groundwater pumping to supplement surface water shortage further complicates the surface water and groundwater interaction. In this paper the authors will use observation data and results of numerical models (MODFLOW) to characterize and quantify hydrological exchange fluxes between groundwater in the aquifers and surface water as well as impacts of groundwater pumping. The interaction shows a very interesting seasonal variation (irrigation vs. non-irrigation) as well as impact of a drought. Groundwater has been pumped for both municipal supplies and agricultural irrigation, which has imposed stresses toward both stream flows and aquifer storage. The results clearly show that historic groundwater pumping has caused some reaches of the river change from gaining stream to losing stream. Beyond the exchange between surface water and groundwater in the shallow aquifer, groundwater pumping in a deep aquifer could also enhance the exchanges between different aquifers through leaky confining layers. In the earlier history of pumping, pumping from the shallow aquifer is compensated by simple depletion of surface water, while deep aquifer tends to use the aquifer storage. With continued pumping, the cumulative stresses from deeper aquifers migrate upward, resulting in additional depletion of surface water. Eventually such impacts turn some reaches of a gaining river into a losing stream. The research finding provides information needed for future regional water planning and conjunctive management of surface water and groundwater resources.

Characterizing groundwater/surface-water interactions in the interior of Jianghan Plain, central China

NASA Astrophysics Data System (ADS)

Du, Yao; Ma, Teng; Deng, Yamin; Shen, Shuai; Lu, Zongjie

2018-06-01

Quantifying groundwater/surface-water interactions is essential for managing water resources and revealing contaminant fate. There has been little concern on the exchange between streams and aquifers through an extensive aquitard thus far. In this study, hydrogeologic calculation and tritium modeling were jointly applied to characterize such interactions through an extensive aquitard in the interior of Jianghan Plain, an alluvial plain of Yangtze River, China. One groundwater simulation suggested that the lateral distance of influence from the river was about 1,000 m; vertical flow in the aquitard followed by lateral flow in the aquifer contributed significantly more ( 90%) to the aquifer head change near the river than lateral bank storage in the aquitard followed by infiltration. The hydrogeologic calculation produced vertical fluxes of the order 0.01 m/day both near and farther from the river, suggesting that similar shorter-lived (half-monthly) vertical fluxes occur between the river and aquitard near the river, and between the surface end members and aquitard farther from the river. Tritium simulation based on the OTIS model produced an average groundwater residence time of about 15 years near the river and a resulting vertical flux of the order 0.001 m/day. Another tritium simulation based on a dispersion model produced a vertical flux of the order 0.0001 m/day away from the river, coupled with an average residence time of around 90 years. These results suggest an order of magnitude difference for the longer-lived (decadal) vertical fluxes between surface waters and the aquifer near and away from the river.

Characterizing groundwater/surface-water interactions in the interior of Jianghan Plain, central China

NASA Astrophysics Data System (ADS)

Du, Yao; Ma, Teng; Deng, Yamin; Shen, Shuai; Lu, Zongjie

2018-01-01

Quantifying groundwater/surface-water interactions is essential for managing water resources and revealing contaminant fate. There has been little concern on the exchange between streams and aquifers through an extensive aquitard thus far. In this study, hydrogeologic calculation and tritium modeling were jointly applied to characterize such interactions through an extensive aquitard in the interior of Jianghan Plain, an alluvial plain of Yangtze River, China. One groundwater simulation suggested that the lateral distance of influence from the river was about 1,000 m; vertical flow in the aquitard followed by lateral flow in the aquifer contributed significantly more ( 90%) to the aquifer head change near the river than lateral bank storage in the aquitard followed by infiltration. The hydrogeologic calculation produced vertical fluxes of the order 0.01 m/day both near and farther from the river, suggesting that similar shorter-lived (half-monthly) vertical fluxes occur between the river and aquitard near the river, and between the surface end members and aquitard farther from the river. Tritium simulation based on the OTIS model produced an average groundwater residence time of about 15 years near the river and a resulting vertical flux of the order 0.001 m/day. Another tritium simulation based on a dispersion model produced a vertical flux of the order 0.0001 m/day away from the river, coupled with an average residence time of around 90 years. These results suggest an order of magnitude difference for the longer-lived (decadal) vertical fluxes between surface waters and the aquifer near and away from the river.

Providing Data and Modeling to Help Manage Water Supplies

USGS Publications Warehouse

Nickles, James

2008-01-01

The Sonoma County Water Agency (SCWA) and other local water purveyors have partnered with the U.S. Geological Survey (USGS) to assess hydrologic conditions and to quan-tify the county-wide interconnections between surface water and ground water. Through this partnership, USGS scientists have completed assessments of the geohydrology and geochemistry of the Sonoma and Alexander Valley ground-water basins. Now, the USGS is constructing a detailed ground-water flow model of the Santa Rosa Plain. It will be used to help identify strategies for surface-water/ground-water management and help to ensure long-term viability of the water supply. The USGS is also working with the SCWA to help meet future demand in the face of possible new restrictions on its main source of water, the Russian River. SCWA draws water from the alluvial aquifer underlying and adjacent to the Russian River and may want to extend riverbank filtration facilities to new areas. USGS scientists are conducting research to charac-terize riverbank filtration processes and changes in water quality during reduced river flows.

The Interplay Between Transpiration and Runoff Formulations in Land Surface Schemes Used with Atmospheric Models

NASA Technical Reports Server (NTRS)

Koster, Rindal D.; Milly, P. C. D.

1997-01-01

The Project for Intercomparison of Land-surface Parameterization Schemes (PILPS) has shown that different land surface models (LSMS) driven by the same meteorological forcing can produce markedly different surface energy and water budgets, even when certain critical aspects of the LSMs (vegetation cover, albedo, turbulent drag coefficient, and snow cover) are carefully controlled. To help explain these differences, the authors devised a monthly water balance model that successfully reproduces the annual and seasonal water balances of the different PILPS schemes. Analysis of this model leads to the identification of two quantities that characterize an LSM's formulation of soil water balance dynamics: (1) the efficiency of the soil's evaporation sink integrated over the active soil moisture range, and (2) the fraction of this range over which runoff is generated. Regardless of the LSM's complexity, the combination of these two derived parameters with rates of interception loss, potential evaporation, and precipitation provides a reasonable estimate for the LSM's simulated annual water balance. The two derived parameters shed light on how evaporation and runoff formulations interact in an LSM, and the analysis as a whole underscores the need for compatibility in these formulations.

Using Iron-Manganese Co-Oxide Filter Film to Remove Ammonium from Surface Water

PubMed Central

Zhang, Ruifeng; Huang, Tinglin; Wen, Gang; Chen, Yongpan; Cao, Xin; Zhang, Beibei

2017-01-01

An iron-manganese co-oxide filter film (MeOx) has been proven to be a good catalyst for the chemical catalytic oxidation of ammonium in groundwater. Compared with groundwater, surface water is generally used more widely and has characteristics that make ammonium removal more difficult. In this study, MeOx was used to remove ammonium from surface water. It indicated that the average ammonium removal efficiency of MeOx was greater than 90%, even though the water quality changed dramatically and the water temperature was reduced to about 6–8 °C. Then, through inactivating microorganisms, it showed that the removal capability of MeOx included both biological (accounted for about 41.05%) and chemical catalytic oxidation and chemical catalytic oxidation (accounted for about 58.95%). The investigation of the characterizations suggested that MeOx was formed by abiotic ways and the main elements on the surface of MeOx were distributed homogenously. The analysis of the catalytic oxidation process indicated that ammonia nitrogen may interact with MeOx as both ammonia molecules and ammonium ions and the active species of O2 were possibly •O and O2−. PMID:28753939

Using Iron-Manganese Co-Oxide Filter Film to Remove Ammonium from Surface Water.

PubMed

Zhang, Ruifeng; Huang, Tinglin; Wen, Gang; Chen, Yongpan; Cao, Xin; Zhang, Beibei

2017-07-19

An iron-manganese co-oxide filter film (MeO x ) has been proven to be a good catalyst for the chemical catalytic oxidation of ammonium in groundwater. Compared with groundwater, surface water is generally used more widely and has characteristics that make ammonium removal more difficult. In this study, MeO x was used to remove ammonium from surface water. It indicated that the average ammonium removal efficiency of MeO x was greater than 90%, even though the water quality changed dramatically and the water temperature was reduced to about 6-8 °C. Then, through inactivating microorganisms, it showed that the removal capability of MeO x included both biological (accounted for about 41.05%) and chemical catalytic oxidation and chemical catalytic oxidation (accounted for about 58.95%). The investigation of the characterizations suggested that MeO x was formed by abiotic ways and the main elements on the surface of MeO x were distributed homogenously. The analysis of the catalytic oxidation process indicated that ammonia nitrogen may interact with MeO x as both ammonia molecules and ammonium ions and the active species of O₂ were possibly • O and O₂ - .

The interplay between transpiration and Runoff formulations in land surface schemes used with atmospheric models

USGS Publications Warehouse

Koster, R.D.; Milly, P.C.D.

1997-01-01

The Project for Intercomparison of Land-surface Parameterization Schemes (PILPS) has shown that different land surface models (LSMs) driven by the same meteorological forcing can produce markedly different surface energy and water budgets, even when certain critical aspects of the LSMs (vegetation cover, albedo, turbulent drag coefficient, and snowcover) are carefully controlled. To help explain these differences, the authors devised a monthly water balance model that successfully reproduces the annual and seasonal water balances of the different PILPS schemes. Analysis of this model leads to the identification of two quantities that characterize an LSM's formulation of soil water balance dynamics: 1) the efficiency of the soil's evaporation sink integrated over the active soil moisture range, and 2) the fraction of this range over which runoff is generated. Regardless of the LSM's complexity, the combination of these two derived parameters with rates of interception loss, potential evaporation, and precipitation provides a reasonable estimate for the LSM's simulated annual water balance. The two derived parameters shed light on how evaporation and runoff formulations interact in an LSM, and the analysis as a whole underscores the need for compatibility in these formulations.

Groundwater flow and hydrogeochemical evolution in the Jianghan Plain, central China

NASA Astrophysics Data System (ADS)

Gan, Yiqun; Zhao, Ke; Deng, Yamin; Liang, Xing; Ma, Teng; Wang, Yanxin

2018-05-01

Hydrogeochemical analysis and multivariate statistics were applied to identify flow patterns and major processes controlling the hydrogeochemistry of groundwater in the Jianghan Plain, which is located in central Yangtze River Basin (central China) and characterized by intensive surface-water/groundwater interaction. Although HCO3-Ca-(Mg) type water predominated in the study area, the 457 (21 surface water and 436 groundwater) samples were effectively classified into five clusters by hierarchical cluster analysis. The hydrochemical variations among these clusters were governed by three factors from factor analysis. Major components (e.g., Ca, Mg and HCO3) in surface water and groundwater originated from carbonate and silicate weathering (factor 1). Redox conditions (factor 2) influenced the geogenic Fe and As contamination in shallow confined groundwater. Anthropogenic activities (factor 3) primarily caused high levels of Cl and SO4 in surface water and phreatic groundwater. Furthermore, the factor score 1 of samples in the shallow confined aquifer gradually increased along the flow paths. This study demonstrates that enhanced information on hydrochemistry in complex groundwater flow systems, by multivariate statistical methods, improves the understanding of groundwater flow and hydrogeochemical evolution due to natural and anthropogenic impacts.

Potentiometric surface of the Ozark aquifer in northern Arkansas, 2004

USGS Publications Warehouse

Schrader, T.P.

2005-01-01

The Ozark aquifer in northern Arkansas comprises dolomites, limestones, sandstones, and shales of Late Cambrian to Middle Devonian age, and ranges in thickness from approximately 1,100 feet to more than 4,000 feet. Hydrologically, the aquifer is complex, characterized by discrete and discontinuous flow components with large variations in permeability. The potentiometric-surface map, based on 59 well and 5 spring water-level measurements collected in 2004 in Arkansas and Missouri, indicates maximum water-level altitudes of about 1,188 feet in Benton County and minimum water-level altitudes of about 116 feet in Randolph County. Regionally, the flow within the aquifer is to the south and southeast in the eastern and central part of the study area and to the northwest and north in the western part of the study area. Comparing the 2004 potentiometric- surface map with a predevelopment potentiometricsurface map indicates general agreement between the two surfaces. Potentiometric-surface differences could be attributed to differences in pumping related to changing population from 1990 to 2000, change in source for public supplies, processes or water use outside the study area, or differences in data-collection or map-construction methods.

Characterization of surface-water resources in the Great Basin National Park area and their susceptibility to ground-water withdrawals in adjacent valleys, White Pine County, Nevada

USGS Publications Warehouse

Elliott, Peggy E.; Beck, David A.; Prudic, David E.

2006-01-01

Eight drainage basins and one spring within the Great Basin National Park area were monitored continually from October 2002 to September 2004 to quantify stream discharge and assess the natural variability in flow. Mean annual discharge for the stream drainages ranged from 0 cubic feet per second at Decathon Canyon to 9.08 cubic feet per second at Baker Creek. Seasonal variability in streamflow generally was uniform throughout the network. Minimum and maximum mean monthly discharges occurred in February and June, respectively, at all but one of the perennial streamflow sites. Synoptic-discharge, specific-conductance, and water- and air-temperature measurements were collected during the spring, summer, and autumn of 2003 along selected reaches of Strawberry, Shingle, Lehman, Baker, and Snake Creeks, and Big Wash to determine areas where surface-water resources would be susceptible to ground-water withdrawals in adjacent valleys. Comparison of streamflow and water-property data to the geology along each stream indicated areas where surface-water resources likely or potentially would be susceptible to ground-water withdrawals. These areas consist of reaches where streams (1) are in contact with permeable rocks or sediments, or (2) receive water from either spring discharge or ground-water inflow.

Using fluorescent dissolved organic matter to trace and distinguish the origin of Arctic surface waters

PubMed Central

Gonçalves-Araujo, Rafael; Granskog, Mats A.; Bracher, Astrid; Azetsu-Scott, Kumiko; Dodd, Paul A.; Stedmon, Colin A.

2016-01-01

Climate change affects the Arctic with regards to permafrost thaw, sea-ice melt, alterations to the freshwater budget and increased export of terrestrial material to the Arctic Ocean. The Fram and Davis Straits represent the major gateways connecting the Arctic and Atlantic. Oceanographic surveys were performed in the Fram and Davis Straits, and on the east Greenland Shelf (EGS), in late summer 2012/2013. Meteoric (fmw), sea-ice melt, Atlantic and Pacific water fractions were determined and the fluorescence properties of dissolved organic matter (FDOM) were characterized. In Fram Strait and EGS, a robust correlation between visible wavelength fluorescence and fmw was apparent, suggesting it as a reliable tracer of polar waters. However, a pattern was observed which linked the organic matter characteristics to the origin of polar waters. At depth in Davis Strait, visible wavelength FDOM was correlated to apparent oxygen utilization (AOU) and traced deep-water DOM turnover. In surface waters FDOM characteristics could distinguish between surface waters from eastern (Atlantic + modified polar waters) and western (Canada-basin polar waters) Arctic sectors. The findings highlight the potential of designing in situ multi-channel DOM fluorometers to trace the freshwater origins and decipher water mass mixing dynamics in the region without laborious samples analyses. PMID:27667721

Installation-restoration program. Phase 2. Confirmation/quantification. Stage 1 for Shaw Air Force Base, South Carolina. Final report, January 1984-October 1986

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alexander, W.J.; Liddle, S.K.

1986-09-01

The primary objectives of this project were to collect and analyze groundwater, surface water, and sediment samples and to perform an initial characterization of the hydrogeochemical regime at potential contamination sites on Shaw Air Force Base near Sumter, South Carolina. This study constituted Phase II of the U.S. Air Force Installation Restoration Program (IRP). Five potential sources of groundwater pollution were studied. The evaluation primarily included the drilling of soil test borings, the installation, development, and sampling of groundwater monitoring wells, and the analyses of soil, surface water, and groundwater samples. Also used in the study were field measurements ofmore » water quality, water-level measurements site observations, published hydrogeologic data and Shaw AFB documents.« less

Observational Evidence of Changes in Water Vapor, Clouds, and Radiation at the ARM SGP Site

NASA Technical Reports Server (NTRS)

Dong, Xiquan; Xi, Baike; Minnus, Patrick

2006-01-01

Characterizing water vapor and cloud effects on the surface radiation budget is critical for understanding the current climate because water vapor is the most important greenhouse gas in the atmosphere and clouds are one of the largest sources of uncertainty in predicting potential future climate change. Several studies have shown that insolation over land declined until 1990 then increased until the present. Using 8 years of surface data, we observed the increasing trend of insolation from 1997 to 2000, but detected a significant decrease from 2001 to 2004. The variation of cloud fraction mirrors that of insolation with an overall increase of 1 percent per year. Under clear-sky conditions, water vapor changes have a greater impact on longwave flux than on insolation.

Global Precipitation Measurement (GPM) Ground Validation (GV) Science Implementation Plan

NASA Technical Reports Server (NTRS)

Petersen, Walter A.; Hou, Arthur Y.

2008-01-01

For pre-launch algorithm development and post-launch product evaluation Global Precipitation Measurement (GPM) Ground Validation (GV) goes beyond direct comparisons of surface rain rates between ground and satellite measurements to provide the means for improving retrieval algorithms and model applications.Three approaches to GPM GV include direct statistical validation (at the surface), precipitation physics validation (in a vertical columns), and integrated science validation (4-dimensional). These three approaches support five themes: core satellite error characterization; constellation satellites validation; development of physical models of snow, cloud water, and mixed phase; development of cloud-resolving model (CRM) and land-surface models to bridge observations and algorithms; and, development of coupled CRM-land surface modeling for basin-scale water budget studies and natural hazard prediction. This presentation describes the implementation of these approaches.

KSC-98pc1657

NASA Image and Video Library

1998-11-03

At pad 17A at Cape Canaveral Air Station, the second stage of a Delta II rocket is lowered into the first stage. The rocket is scheduled to be launched on Dec. 10, 1998, heading for Mars and carrying the Mars Climate Orbiter. The orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for 657 days. It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface. The orbiter will primarily support its companion Mars Polar Lander spacecraft, which is planned for launch on Jan. 3, 1999

KSC-98pc1654

NASA Image and Video Library

1998-11-03

Workers at pad 17A at Cape Canaveral Air Station begin lifting the second stage of a Delta II rocket up the gantry . The rocket is scheduled to be launched on Dec. 10, 1998, heading for Mars and carrying the Mars Climate Orbiter. The orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for 657 days. It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface. The orbiter will primarily support its companion Mars Polar Lander spacecraft, which is planned for launch on Jan. 3, 1999

KSC-98pc1655

NASA Image and Video Library

1998-11-03

At pad 17A, Cape Canaveral Air Station, the second stage of a Delta II rocket is lifted up the gantry . The rocket is scheduled to be launched on Dec. 10, 1998, heading for Mars and carrying the Mars Climate Orbiter. The orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for 657 days. It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface. The orbiter will primarily support its companion Mars Polar Lander spacecraft, which is planned for launch on Jan. 3, 1999

KSC-98pc1656

NASA Image and Video Library

1998-11-03

Workers at pad 17A at Cape Canaveral Air Station maneuver the second stage of a Delta II rocket inside the gantry. The rocket is scheduled to be launched on Dec. 10, 1998, heading for Mars and carrying the Mars Climate Orbiter. The orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for 657 days. It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface. The orbiter will primarily support its companion Mars Polar Lander spacecraft, which is planned for launch on Jan. 3, 1999

KSC-98pc1653

NASA Image and Video Library

1998-11-03

The second stage of a Delta II rocket is prepared for its shift to vertical alongside the gantry at pad 17A at Cape Canaveral Air Station. The rocket is scheduled to be launched on Dec. 10, 1998, heading for Mars and carrying the Mars Climate Orbiter. The orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for 657 days. It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface. The orbiter will primarily support its companion Mars Polar Lander spacecraft, which is planned for launch on Jan. 3, 1999

KSC-98pc1620

NASA Image and Video Library

1998-10-30

KENNEDY SPACE CENTER, FLA. -- On Pad 17A at Cape Canaveral Air Station, a Delta II rocket is maneuvered into position for launch on Dec. 10, 1998. The rocket is carrying the Mars Climate Orbiter which will head for Mars primarily to support its companion Mars Polar Lander spacecraft, which is planned for launch on Jan. 3, 1999. The orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for one Martian year (1.8 Earth years). It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface

KSC-98pc1723

NASA Image and Video Library

1998-11-16

KENNEDY SPACE CENTER, FLA. -- In the Spacecraft Assembly and Encapsulation Facility -2 (SAEF-2), the Mars Climate Orbiter is in place for its spin test. Targeted for launch aboard a Delta II rocket on Dec. 10, 1998, the orbiter is heading for Mars where it will primarily support its companion Mars Polar Lander spacecraft, which is planned for launch on Jan. 3, 1999. The orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for 687 Earth days. It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface

KSC-98pc1722

NASA Image and Video Library

1998-11-16

KENNEDY SPACE CENTER, FLA. -- In the Spacecraft Assembly and Encapsulation Facility -2 (SAEF-2), workers lower the Mars Climate Orbiter into place on the spin test equipment. Targeted for launch aboard a Delta II rocket on Dec. 10, 1998, the orbiter is heading for Mars where it will primarily support its companion Mars Polar Lander spacecraft, which is planned for launch on Jan. 3, 1999. The orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for 687 Earth days. It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface

Molecular dynamics study on the microscopic details of the evaporation of water.

PubMed

Mason, Phillip E

2011-06-16

Molecular dynamics simulations were conducted on a drop of water (containing 4890 TIP3P waters) at 350 K. About 70 evaporation events were found and characterized in enough detail to determine significant patterns relating to the mechanism of evaporation. It was found that in almost all evaporation events that a single, high-energy state immediately preceded the evaporation event. In ∼50% of the cases, this high-energy state involved a short oxygen-oxygen distance, suggesting a van der Waals collision, whereas in the remaining cases, a short hydrogen-hydrogen distance was found, suggesting an electrostatic "collision". Of the high-energy states that led to evaporation, about half occurred when the coordination number of water was 1, and about half, when the coordination number was 2. It was found that the 1-coordinated waters (∼1% of the surface waters) and 2-coordinated waters (6% of the surface waters) were responsible for almost all the evaporation events. © 2011 American Chemical Society

Importance of unsaturated zone flow for simulating recharge in a humid climate

USGS Publications Warehouse

Hunt, R.J.; Prudic, David E.; Walker, J.F.; Anderson, M.P.

2008-01-01

Transient recharge to the water table is often not well understood or quantified. Two approaches for simulating transient recharge in a ground water flow model were investigated using the Trout Lake watershed in north-central Wisconsin: (1) a traditional approach of adding recharge directly to the water table and (2) routing the same volume of water through an unsaturated zone column to the water table. Areas with thin (less than 1 m) unsaturated zones showed little difference in timing of recharge between the two approaches; when water was routed through the unsaturated zone, however, less recharge was delivered to the water table and more discharge occurred to the surface because recharge direction and magnitude changed when the water table rose to the land surface. Areas with a thick (15 to 26 m) unsaturated zone were characterized by multimonth lags between infiltration and recharge, and, in some cases, wetting fronts from precipitation events during the fall overtook and mixed with infiltration from the previous spring snowmelt. Thus, in thicker unsaturated zones, the volume of water infiltrated was properly simulated using the traditional approach, but the timing was different from simulations that included unsaturated zone flow. Routing of rejected recharge and ground water discharge at land surface to surface water features also provided a better simulation of the observed flow regime in a stream at the basin outlet. These results demonstrate that consideration of flow through the unsaturated zone may be important when simulating transient ground water flow in humid climates with shallow water tables.

Surface-water quality assessment of the Clover Creek basin, Pierce County, Washington, 1991-1992

USGS Publications Warehouse

McCarthy, K.A.

1996-01-01

Increasing urbanization in the 67-square-mile Clover Creek Basin has generated interest in the effects of land-use changes on local water quality. To investigate these effects, water-quality and streamflow data were collected from 19 surface-water sites in the basin over a 16-month period from January 1991 through April 1992. These data were used to understand the effects of surficial geology, land-use practices, and wastewater disposal practices on surface-water quality within the basin. The basin was divided into four drainage subbasins with dissimilar hydrogeologic, land-use, and water-quality characteristics. In the Upper Clover Creek subbasin, the high permeability of surficial geologic materials promotes infiltration of precipitation to ground water and thus attenuates the response of streams to rainfall. Significant interaction occurs between surface and ground water in this subbasin, and nitrate concentrations and specific conductance values, similar to those found historically in local ground water, indicate that sources such as subsurface waste-disposal systems and fertilizers are affecting surface- water quality in this area. In the Spanaway subbasin, the presence of Spanaway and Tule Lakes affects water quality, primarily because of the reduced velocity and long residence time of water in the lakes. Reduced water velocity and long residence times (1) cause settling of suspended materials, thereby reducing concentrations of suspended sediment and constituents that are bound to the sediment; (2) promote biological activity, which tends to trap nutrients in the lakes; and (3) allow dispersion to attenuate peaks in discharge and water-quality constituent concentrations. In the North Fork subbasin, the low permeability of surficial geologic materials and areas of intensive land development inhibit infiltration of precipitation and thus promote surface runoff to streams. Surface pathways provide little attenuation of storm runoff and result in rapid increases in stream discharge in response to rainfall. Substantial increases in concentrations of constituents associated with surface wash off, for example, suspended sediment, ammonia, phosphorus, and fecal coliform, also were observed in this subbasin during rainfall. In the Lower Clover Creek subbasin, which is the most downstream subbasin, stream-discharge and water-quality characteristics show the integrated effects of the entire basin. The data show that further characterization of local ground water and discharge from stormwater outfalls entering Clover Creek and its tributaries would be necessary to successfully apply a numerical water-quality model to the basin.

Surface changes of biopolymers PHB and PLLA induced by Ar+ plasma treatment and wet etching

NASA Astrophysics Data System (ADS)

Slepičková Kasálková, N.; Slepička, P.; Sajdl, P.; Švorčík, V.

2014-08-01

Polymers, especially group of biopolymers find potential application in a wide range of disciplines due to their biodegradability. In biomedical applications these materials can be used as a scaffold or matrix. In this work, the influence of the Ar+ plasma treatment and subsequent wet etching (acetone/water) on the surface properties of polymers were studied. Two biopolymers - polyhydroxybutyrate with 8% polyhydroxyvalerate (PHB) and poly-L-lactic acid (PLLA) were used in these experiments. Modified surface layers were analyzed by different methods. Surface wettability was characterized by determination of water contact angle. Changes in elemental composition of modified surfaces were performed by X-ray Photoelectron Spectroscopy (XPS). Surface morphology and roughness was examined using Atomic Force Microscopy (AFM). Gravimetry method was used to study the mass loss. It was found that the modification from both with plasma and wet etching leads to dramatic changes of surface properties (surface chemistry, morphology and roughness). Rate of changes of these features strongly depends on the modification parameters.

Poly(ethylene oxide) surfactant polymers.

PubMed

Vacheethasanee, Katanchalee; Wang, Shuwu; Qiu, Yongxing; Marchant, Roger E

2004-01-01

We report on a series of structurally well-defined surfactant polymers that undergo surface-induced self-assembly on hydrophobic biomaterial surfaces. The surfactant polymers consist of a poly(vinyl amine) backbone with poly(ethylene oxide) and hexanal pendant groups. The poly(vinyl amine) (PVAm) was synthesized by hydrolysis of poly(N-vinyl formamide) following free radical polymerization of N-vinyl formamide. Hexanal and aldehyde-terminated poly(ethylene oxide) (PEO) were simultaneously attached to PVAm via reductive amination. Surfactant polymers with different PEO:hexanal ratios and hydrophilic/hydrophobic balances were prepared, and characterized by FT-IR, 1H-NMR and XPS spectroscopies. Surface active properties at the air/water interface were determined by surface tension measurements. Surface activity at a solid surface/water interface was demonstrated by atomic force microscopy, showing epitaxially molecular alignment for surfactant polymers adsorbed on highly oriented pyrolytic graphite. The surfactant polymers described in this report can be adapted for simple non-covalent surface modification of biomaterials and hydrophobic surfaces to provide highly hydrated interfaces.

Data package for the Low-Level Waste Disposal Development and Demonstration Program environmental impact statement: Volume 2, Appendices E-O

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ketelle, R.H.

1988-09-01

This volume contains 11 appendices to the main document in Volume 1. Topics in Volume 2 include hydrologic data for a proposed solid waste storage area, soil characterizations, well logs, surface water discharge data, water quality data, atmospheric precipitation and stream flow, a small mammal survey, and general ecological information. (TEM)

Origin of bending in uncoated microcantilever - Surface topography?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lakshmoji, K.; Prabakar, K.; Tripura Sundari, S., E-mail: sundari@igcar.gov.in

2014-01-27

We provide direct experimental evidence to show that difference in surface topography on opposite sides of an uncoated microcantilever induces bending, upon exposure to water molecules. Examination on opposite sides of the microcantilever by atomic force microscopy reveals the presence of localized surface features on one side, which renders the induced stress non-uniform. Further, the root mean square inclination angle characterizing the surface topography shows a difference of 73° between the opposite sides. The absence of deflection in another uncoated microcantilever having similar surface topography confirms that in former microcantilever bending is indeed induced by differences in surface topography.

Nanocolloids in Natural Water: Isolation, Characterization, and Toxicity.

PubMed

Ouyang, Shaohu; Hu, Xiangang; Zhou, Qixing; Li, Xiaokang; Miao, Xinyu; Zhou, Ruiren

2018-04-17

Nanocolloids are widespread in natural water systems, but their characterization and ecological risks are largely unknown. Herein, tangential flow ultrafiltration (TFU) was used to separate and concentrate nanocolloids from surface waters. Unexpectedly, nanocolloids were present in high concentrations ranging from 3.7 to 7.2 mg/L in the surface waters of the Harihe River in Tianjin City, China. Most of the nanocolloids were 10-40 nm in size, contained various trace metals and polycyclic aromatic hydrocarbons, and exhibited fluorescence properties. Envelopment effects and aggregation of Chlorella vulgaris in the presence of nanocolloids were observed. Nanocolloids entered cells and nanocolloid-exposed cells exhibited stronger plasmolysis, chloroplast damage and more starch grains than the control cells. Moreover, nanocolloids inhibited the cell growth, promoted reactive oxygen species (ROS), reduce the chlorophyll a content and increased the cell permeability. The genotoxicity of nanocolloids was also observed. The metabolomics analysis revealed a significant ( p < 0.05) downregulation of amino acids and upregulation of fatty acids contributing to ROS increase, chlorophyll a decrease and plasmolysis. The present work reveals that nanocolloids, which are different from specific, engineered nanoparticles (e.g., Ag nanoparticles), are present at high concentrations, exhibit an obvious toxicity in environments, and deserve more attention in the future.

Improving spatial prediction of Schistosoma haematobium prevalence in southern Ghana through new remote sensors and local water access profiles.

PubMed

Kulinkina, Alexandra V; Walz, Yvonne; Koch, Magaly; Biritwum, Nana-Kwadwo; Utzinger, Jürg; Naumova, Elena N

2018-06-04

Schistosomiasis is a water-related neglected tropical disease. In many endemic low- and middle-income countries, insufficient surveillance and reporting lead to poor characterization of the demographic and geographic distribution of schistosomiasis cases. Hence, modeling is relied upon to predict areas of high transmission and to inform control strategies. We hypothesized that utilizing remotely sensed (RS) environmental data in combination with water, sanitation, and hygiene (WASH) variables could improve on the current predictive modeling approaches. Schistosoma haematobium prevalence data, collected from 73 rural Ghanaian schools, were used in a random forest model to investigate the predictive capacity of 15 environmental variables derived from RS data (Landsat 8, Sentinel-2, and Global Digital Elevation Model) with fine spatial resolution (10-30 m). Five methods of variable extraction were tested to determine the spatial linkage between school-based prevalence and the environmental conditions of potential transmission sites, including applying the models to known human water contact locations. Lastly, measures of local water access and groundwater quality were incorporated into RS-based models to assess the relative importance of environmental and WASH variables. Predictive models based on environmental characterization of specific locations where people contact surface water bodies offered some improvement as compared to the traditional approach based on environmental characterization of locations where prevalence is measured. A water index (MNDWI) and topographic variables (elevation and slope) were important environmental risk factors, while overall, groundwater iron concentration predominated in the combined model that included WASH variables. The study helps to understand localized drivers of schistosomiasis transmission. Specifically, unsatisfactory water quality in boreholes perpetuates reliance of surface water bodies, indirectly increasing schistosomiasis risk and resulting in rapid reinfection (up to 40% prevalence six months following preventive chemotherapy). Considering WASH-related risk factors in schistosomiasis prediction can help shift the focus of control strategies from treating symptoms to reducing exposure.

Preparation, characterization and properties of ZnO nanomaterials

NASA Astrophysics Data System (ADS)

Luo, Jiaolian; Zhang, Xiaoming; Chen, Ruxue; Wang, Xiaohui; Zhu, Ji; Wang, Xiaomin

2017-06-01

In this paper, using the hydrothermal synthesis method, NaOH, Zn(NO3)2, anhydrous ethanol, deionized water as raw material to prepare ZnO nanomaterial, and by X ray diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence spectroscopy (PL) on the synthesis of nano materials, surface morphology and phase luminescence characterization. The results show that the nano materials synthesized for single-phase ZnO, belonging to the six wurtzite structure; material surface shaped, arranged evenly distributed, and were the top six party structure; ZnO nano materials synthesized with strong emission spectra, emission peak is located at 394nm.

The Pascal Mars Scout Mission

NASA Technical Reports Server (NTRS)

Haberle, R. M.; Fonda, Mark (Technical Monitor)

2002-01-01

Except for Earth, Mars is the planet most amenable to surface-based climate studies. Its surface is accessible, and the kind of observations that are needed, such as meteorological measurements from a long-lived global network, are readily achievable. Weather controls the movement of dust, the exchange of water between the surface and atmosphere, and the cycling of CO2 between the poles. We know there is a weather signal, we know how to measure it, and we know how to interpret it. Pascal seeks to understand the long-term global behavior of near-surface weather systems on Mars, how they interact with its surface, and, therefore, how they control its climate system. To achieve this, Pascal delivers 18 Science Stations to the surface of the planet that operate for three Mars years (5.6 Earth years). The network has stations operating in the tropics, midlatitudes, and polar regions of both hemispheres. During entry, descent, and landing, each Pascal probe acquires deceleration measurements to determine thermal structure, and descent images to characterize local terrain. On the surface, each Science Station takes daily measurements of pressure, opacity, temperature, wind speed, and water vapor concentration and monthly panoramic images of the landing environment. These data will characterize the planet's climate system and how atmosphere-surface interactions control it. The Pascal mission is named after 17th century French Scientist, Blaise Pascal, who pioneered measurements of atmospheric pressure. Pressure is the most critical measurement because it records the "heartbeat" of the planet's general circulation and climate system.

Global Water Surface Dynamics: Toward a Near Real Time Monitoring Using Landsat and Sentinel Data

NASA Astrophysics Data System (ADS)

Pekel, J. F.; Belward, A.; Gorelick, N.

2017-12-01

Global surface water dynamics and its long-term changes have been documented at 30m spatial resolution using the entire multi-temporal orthorectified Landsat 5, 7 and 8 archive for the years 1984 to 2015. This validated dataset recorded the months and years when water was present, where occurrence changed and what form changes took (in terms of seasonality), documents inter-annual variability, and multi-annual trends. This information is freely available from the global surface water explorer https://global-surface-water.appspot.com. Here we extend this work (doi:10.1038/nature20584 ) by combining post 2015 Landsat 7 and 8 data with imagery from the Copernicus program's Sentinel 2a and b satellites. Using these data in combination improves the spatial resolution (from 30m to a nominal 10m) and temporal resolution (from 8 days to 4 days revisit time at the equator). The improved geographic and temporal completeness of the combined Landsat / Sentinel dataset also offers new opportunities for the identification and characterization of seasonally occurring waterbodies. These improvements are also being examined in the light of reporting progress against Agenda 2030's Sustainable Development Goal 6, especially the indicator used to measure 'change in the extent of water-related ecosystems over time'.

First principles studies on the redox ability of (Ga(1-x)Zn(x))N(1-x)O(x) solid solutions and thermal reactions for H2 and O2 production on their surfaces.

PubMed

Du, Yaojun A; Chen, Yun-Wen; Kuo, Jer-Lai

2013-12-07

The (Ga1-xZnx)N1-xOx solid solution has been emerging as an effective photocatalyst for water splitting utilizing the visible solar spectrum, regarded as a host GaN bulk doped with ZnO impurities. H2 and O2 production occur simultaneously and stoichiometrically on the surface of (Ga1-xZnx)N1-xOx particles. In this work, we characterize the redox ability of (Ga1-xZnx)N1-xOx and find that a solid solution with a ZnO concentration of 0.125 < x < 0.250 is optimal for water splitting. This is consistent with the experimental finding that the maximum photocatalytic activity of (Ga1-xZnx)N1-xOx is achieved at x = 0.13. The thermal reactions of water splitting are modeled on both the GaN and an idealized (Ga1-xZnx)N1-xOx (101[combining macron]0) surface. The computed activation barriers allow us to gain some clues on the efficiency of water splitting on a specific photocatalyst surface. Our results suggest that the non-polar (101[combining macron]0) and polar (0001) surfaces may play different roles in water splitting, i.e., the (101[combining macron]0) surface is responsible for O2 production, while hydroxyl groups could dissociate on the (0001) surface.

Water surface locomotion in tropical canopy ants.

PubMed

Yanoviak, S P; Frederick, D N

2014-06-15

Upon falling onto the water surface, most terrestrial arthropods helplessly struggle and are quickly eaten by aquatic predators. Exceptions to this outcome mostly occur among riparian taxa that escape by walking or swimming at the water surface. Here we document sustained, directional, neustonic locomotion (i.e. surface swimming) in tropical arboreal ants. We dropped 35 species of ants into natural and artificial aquatic settings in Peru and Panama to assess their swimming ability. Ten species showed directed surface swimming at speeds >3 body lengths s(-1), with some swimming at absolute speeds >10 cm s(-1). Ten other species exhibited partial swimming ability characterized by relatively slow but directed movement. The remaining species showed no locomotory control at the surface. The phylogenetic distribution of swimming among ant genera indicates parallel evolution and a trend toward negative association with directed aerial descent behavior. Experiments with workers of Odontomachus bauri showed that they escape from the water by directing their swimming toward dark emergent objects (i.e. skototaxis). Analyses of high-speed video images indicate that Pachycondyla spp. and O. bauri use a modified alternating tripod gait when swimming; they generate thrust at the water surface via synchronized treading and rowing motions of the contralateral fore and mid legs, respectively, while the hind legs provide roll stability. These results expand the list of facultatively neustonic terrestrial taxa to include various species of tropical arboreal ants. © 2014. Published by The Company of Biologists Ltd.

Surface-water, ground-water, and sediment geochemistry of epizonal and shear-hosted mineral deposits in the Tintina Gold Province--arsenic and antimony distribution and mobility: Chapter G in Recent U.S. Geological Survey studies in the Tintina Gold Province, Alaska, United States, and Yukon, Canada--results of a 5-year project

USGS Publications Warehouse

Mueller, Seth H.; Goldfarb, Richard J.; Verplanck, Philip L.; Trainor, Thomas P.; Sanzolone, Richard F.; Adams, Monique; Gough, Larry P.; Day, Warren C.

2007-01-01

Epigenetic mineral deposits in the Tintina Gold Province are generally characterized by high concentrations of arsenic and antimony in their mineral assemblage. A total of 347 samples (ground water, surface water, and stream sediment) were collected to investigate the distribution and mobility of arsenic and antimony in the environment near known mineral deposits. Samples were collected from east to west at Keno Hill and Brewery Creek, Yukon, Canada; and Cleary Hill, True North, Scrafford Mine, Fairbanks, Ryan Lode, Stampede Creek, Slate Creek, and Donlin Creek, all in Alaska. Surface- and ground-water samples are all slightly acidic to near-neutral in pH (5-8), have a wide range in specific conductance (surface water 17-2,980 microsiemens per centimeter and ground water 170-2,940 microsiemens per centimeter), and show elevated dissolved arsenic and antimony concentrations (arsenic in surface water is less than 1 to 380 micrograms per liter and in ground water is less than 1 micrograms per liter to 1.5 milligrams per liter; antimony in surface water is less than 2 to 660 micrograms per liter and in ground water is less than 2 to 60 micrograms per liter). Stream sediments downstream from these deposits have high concentrations of arsenic and antimony (arsenic median is 1,670 parts per million, maximum is 10,000 parts per million; antimony median is 192 parts per million, maximum is 7,200 parts per million). The mobility of arsenic and antimony is controlled by the local redox environment, with arsenic being less mobile in oxidized surface waters relative to antimony, and arsenic more mobile in reduced ground water. These factors suggest that both antimony and arsenic may be useful pathfinder elements in water and sediment for targeting similar style deposits elsewhere in the Tintina Gold Province.

Hazard-Specific Vulnerability Mapping for Water Security in a Shale Gas Context

NASA Astrophysics Data System (ADS)

Allen, D. M.; Holding, S.; McKoen, Z.

2015-12-01

Northeast British Columbia (NEBC) is estimated to hold large reserves of unconventional natural gas and has experienced rapid growth in shale gas development activities over recent decades. Shale gas development has the potential to impact the quality and quantity of surface and ground water. Robust policies and sound water management are required to protect water security in relation to the water-energy nexus surrounding shale gas development. In this study, hazard-specific vulnerability mapping was conducted across NEBC to identify areas most vulnerable to water quality and quantity deterioration due to shale gas development. Vulnerability represents the combination of a specific hazard threat and the susceptibility of the water system to that threat. Hazard threats (i.e. potential contamination sources and water abstraction) were mapped spatially across the region. The shallow aquifer susceptibility to contamination was characterised using the DRASTIC aquifer vulnerability approach, while the aquifer susceptibility to abstraction was mapped according to aquifer productivity. Surface water susceptibility to contamination was characterised on a watershed basis to describe the propensity for overland flow (i.e. contaminant transport), while watershed discharge estimates were used to assess surface water susceptibility to water abstractions. The spatial distribution of hazard threats and susceptibility were combined to form hazard-specific vulnerability maps for groundwater quality, groundwater quantity, surface water quality and surface water quantity. The vulnerability maps identify priority areas for further research, monitoring and policy development. Priority areas regarding water quality occur where hazard threat (contamination potential) coincide with high aquifer susceptibility or high overland flow potential. Priority areas regarding water quantity occur where demand is estimated to represent a significant proportion of estimated supply. The identification of priority areas allows for characterization of the vulnerability of water security in the region. This vulnerability mapping approach, using the hazard threat and susceptibility indicators, can be applied to other shale gas areas to assess vulnerability to shale gas activities and support water security.

Characterization of recharge and flow behaviour of different water sources in Gunung Kidul and its impact on water quality based on hydrochemical and physico-chemical monitoring

NASA Astrophysics Data System (ADS)

Eiche, Elisabeth; Hochschild, Maren; Haryono, Eko; Neumann, Thomas

2016-09-01

Karst aquifers are important water resources but highly vulnerable due to their heterogeneous and complex characteristics. Various hydrological aspects (recharge, flow behaviour) have to be known in detail to develop a sustainable concept for water collection, distribution and treatment. In the karst area of Gunung Sewu (Java, Indonesia) such a concept was to be implemented within a German-Indonesian joint IWRM project. The basic hydrogeological conditions and water quality aspects were characterized on a regional scale through hydrochemical monitoring of springs, wells, subsurface and surface rivers. More detailed information about the recharge, flow and storage behaviour was obtained from high resolution monitoring of T, EC and discharge in one large underground river system. The water quality is well below any guideline values with regard to inorganic pollutants during dry season. During rainy season, dissolved Al concentrations are frequently above the Indonesian guideline value. Slow matrix flow is the most important recharge component during dry season, thus assuring the year-round water availability in the subsurface karst. During rainy season, quick infiltration of the surface water is a dominant recharge component. Rapid response of discharge, T and EC to heavy rain suggests the presence of point recharge that feeds a highly karstfied conduit system with fast conduit flow and short transit time of water. The strong variations in discharge and hydrochemistry are particularly challenging for technical water usage and treatment facilities. Piston flow is indicated to be the third important flow component and is induced by heavy rainfall.

Ocean Surface Emissivity at L-band (1.4 GHz): The Dependence on Salinity and Roughness

NASA Technical Reports Server (NTRS)

LeVine, D. M.; Lang, R.; Wentz, F.; Messiner, T.

2012-01-01

A characterization of the emissivity of sea water at L-band is important for the remote sensing of sea surface salinity. Measurements of salinity are currently being made in the radio astronomy band at 1.413 GHz by ESA's Soil Moisture and Ocean Salinity (SMOS) mission and NASA's Aquarius instrument aboard the Aquarius/SAC-D observatory. The goal of both missions is accuracy on the order of 0.1 psu. This requires accurate knowledge of the dielectric constant of sea water as a function of salinity and temperature and also the effect of waves (roughness). The former determines the emissivity of an ideal (i.e. flat) surface and the later is the major source of error from predictions based on a flat surface. These two aspects of the problem of characterizing the emissivity are being addressed in the context of the Aquarius mission. First, laboratory measurements are being made of the dielectric constant of sea water. This is being done at the George Washington University using a resonant cavity. In this technique, sea water of known salinity and temperature is fed into the cavity along its axis through a narrow tube. The sea water changes the resonant frequency and Q of the cavity which, if the sample is small enough, can be related to the dielectric constant of the sample. An extensive set of measurements have been conducted at 1.413 GHz to develop a model for the real and imaginary part of the dielectric constant as a function of salinity and temperature. The results are compared to the predictions of models based on parameterization of the Debye resonance of the water molecule. The models and measurements are close; however, the differences are significant for remote sensing of salinity. This is especially true at low temperatures where the sensitivity to salinity is lowest.

Design and characterization of a low cost CubeSat multi-band optical receiver to map water ice on the lunar surface for the Lunar Flashlight mission

NASA Astrophysics Data System (ADS)

Vinckier, Quentin; Crabtree, Karlton; Paine, Christopher G.; Hayne, Paul O.; Sellar, Glenn R.

2017-08-01

Lunar Flashlight is an innovative NASA CubeSat mission dedicated to mapping water ice in the permanently shadowed regions of the Moon, which may act as cold traps for volatiles. To this end, a multi-band reflectometer will be sent to orbit the Moon. This instrument consists of an optical receiver aligned with four lasers, each of which emits sequentially at a different wavelength in the near-infrared between 1 μm and 2 μm. The receiver measures the laser light reflected from the lunar surface; continuum/absorption band ratios are then analyzed to quantify water ice in the illuminated spot. Here, we present the current state of the optical receiver design. To optimize the optical signal-to-noise ratio, we have designed the receiver so as to maximize the laser signal collected, while minimizing the stray light reaching the detector from solarilluminated areas of the lunar surface outside the field-of-view, taking into account the complex lunar topography. Characterization plans are also discussed. This highly mass- and volume-constrained mission will demonstrate several firsts, including being one of the first CubeSats performing science measurements beyond low Earth orbit.

Specular Reflection of Sunlight from Earth

NASA Astrophysics Data System (ADS)

Varnai, T.; Marshak, A.

2018-02-01

The Deep Space Gateway vantage point offers advantages in observing specular reflection from water surfaces or ice crystals in clouds. Such data can give information on clouds and atmospheric aerosols, and help test algorithms of future exoplanet characterization.

Sublethal microcystin exposure and biochemical outcomes among hemodialysis patients

EPA Science Inventory

Cyanobacteria are commonly-occurring contaminants of surface waters worldwide. Microcystins, potent hepatotoxins, are among the best characterized cyanotoxins. During November, 2001, a group of 44 hemodialysis patients were exposed to microcystins via contaminated dialysate. Seru...

Complete characterization of the water dimer vibrational ground state and testing the VRT(ASP-W)III, SAPT-5st, and VRT(MCY-5f) surfaces

NASA Astrophysics Data System (ADS)

Keutsch, Frank N.; Goldman, Nir; Harker, Heather A.; Leforestier, Claude; Saykally, Richard J.

We report the observation of extensive a- and c-type rotation-tunnelling (RT) spectra of (H2O)2 for Ka =0-3, and (D2O)2 for Ka =0-4. These data allow a detailed characterization of the vibrational ground state to energies comparable to those of the low-lying (70-80 cm-1) intermolecular vibrations. We present a comparison of the experimentally determined molecular constants and tunnelling splittings with those calculated on the VRT(ASP-W)III, SAPT-5st, and VRT(MCY-5f) intermolecular potential energy surfaces. The SAPT-5st potential reproduces the vibrational ground state properties of the water dimer very well. The VRT(MCY-5f) and especially the VRT(ASP-W)III potentials show larger disagreements, in particular for the bifurcation tunnelling splitting.

Milling induced amorphisation and recrystallization of α-lactose monohydrate.

PubMed

Badal Tejedor, Maria; Pazesh, Samaneh; Nordgren, Niklas; Schuleit, Michael; Rutland, Mark W; Alderborn, Göran; Millqvist-Fureby, Anna

2018-02-15

Preprocessing of pharmaceutical powders is a common procedure to condition the materials for a better manufacturing performance. However, such operations may induce undesired material properties modifications when conditioning particle size through milling, for example. Modification of both surface and bulk material structure will change the material properties, thus affecting the processability of the powder. Hence it is essential to control the material transformations that occur during milling. Topographical and mechanical changes in surface properties can be a preliminary indication of further material transformations. Therefore a surface evaluation of the α-lactose monohydrate after short and prolonged milling times has been performed. Unprocessed α-lactose monohydrate and spray dried lactose were evaluated in parallel to the milled samples as reference examples of the crystalline and amorphous lactose structure. Morphological differences between unprocessed α-lactose, 1 h and 20 h milled lactose and spray dried lactose were detected from SEM and AFM images. Additionally, AFM was used to simultaneously characterize particle surface amorphicity by measuring energy dissipation. Extensive surface amorphicity was detected after 1 h of milling while prolonged milling times showed only a moderate particle surface amorphisation. Bulk material characterization performed with DSC indicated a partial amorphicity for the 1 h milled lactose and a fully amorphous thermal profile for the 20 h milled lactose. The temperature profiles however, were shifted somewhat in the comparison to the amorphous reference, particularly after extended milling, suggesting a different amorphous state compared to the spray-dried material. Water loss during milling was measured with TGA, showing lower water content for the lactose amorphized through milling compared to spray dried amorphous lactose. The combined results suggest a surface-bulk propagation of the amorphicity during milling in combination with a different amorphous structural conformation to that of the amorphous spray dried lactose. The hardened surface may be due to either surface crystallization of lactose or to formation of a low-water glass transition. Copyright © 2017 Elsevier B.V. All rights reserved.

Intensive exploitation of a karst aquifer leads to Cryptosporidium water supply contamination.

PubMed

Khaldi, S; Ratajczak, M; Gargala, G; Fournier, M; Berthe, T; Favennec, L; Dupont, J P

2011-04-01

Groundwater from karst aquifers is an important source of drinking water worldwide. Outbreaks of cryptosporidiosis linked to surface water and treated public water are regularly reported. Cryptosporidium oocysts are resistant to conventional drinking water disinfectants and are a major concern for the water industry. Here, we examined conditions associated with oocyst transport along a karstic hydrosystem, and the impact of intensive exploitation on Cryptosporidium oocyst contamination of the water supply. We studied a well-characterized karstic hydrosystem composed of a sinkhole, a spring and a wellbore. Thirty-six surface water and groundwater samples were analyzed for suspended particulate matter, turbidity, electrical conductivity, and Cryptosporidium and Giardia (oo)cyst concentrations. (Oo)cysts were identified and counted by means of solid-phase cytometry (ChemScan RDI(®)), a highly sensitive method. Cryptosporidium oocysts were detected in 78% of both surface water and groundwater samples, while Giardia cysts were found in respectively 22% and 8% of surface water and groundwater samples. Mean Cryptosporidium oocyst concentrations were 29, 13 and 4/100 L at the sinkhole, spring and wellbore, respectively. Cryptosporidium oocysts were transported from the sinkhole to the spring and the wellbore, with respective release rates of 45% and 14%, suggesting that oocysts are subject to storage and remobilization in karst conduits. Principal components analysis showed that Cryptosporidium oocyst concentrations depended on variations in hydrological forcing factors. All water samples collected during intensive exploitation contained oocysts. Control of Cryptosporidium oocyst contamination during intensive exploitation is therefore necessary to ensure drinking water quality. Copyright © 2011. Published by Elsevier Ltd.

Comparison of Performance and Oxidation of Nitronic-50 and Stainless Steel 316 in Subcritical and Supercritical Water Environments

NASA Astrophysics Data System (ADS)

Karmiol, Zachary; Chidambaram, Dev

2016-05-01

This work investigates two austenitic stainless steels, Nitronic-50 and stainless steel 316, for use in both subcritical and supercritical water (SCW) conditions. The mechanical characteristics of the materials were investigated using slow strain rate testing in a SCW test loop under the following conditions: nitrogen at ambient temperature and pressure, liquid water at 473 K (200 °C) and 8 MPa, liquid water at 573 K (300 °C) and 15 MPa, and SCW at 698 K (425 °C) and 27 MPa. The surfaces of the failed samples were characterized using Raman spectroscopy, and X-ray photoelectron spectroscopy. Nitronic-50 was found to have superior mechanical strength characteristics at all conditions compared to stainless steel 316. At all elevated temperature conditions, stainless steel 316 was found to have a surface film consisting of iron oxides, while the surface film of Nitronic-50 predominantly consisted of nickel-iron spinel.

Effects of Cr Content and Surface Finishes on Oxidation Behaviors of Austenitic Fe-Cr-Ni Alloys Exposed in Supercritical Water (SCW)

NASA Astrophysics Data System (ADS)

Xing, Bo

The scope of this work was to characterize the corrosion resistance of candidate austenitic alloys in supercritical water for the use of the fuel cladding material within the Canadian supercritical water-cooled reactor (SCWR) concept. A series of Commercial austenitic stainless steels (SS) and alloys were exposed to supercritical water for different exposure times up to 500 hours. Two surface finishes were applied - a coarse grinding with 120 grit abrasive or polishing with either 1200 grit or 0.05 microm alumina suspension. Gravimetric measurements and electron microscopy techniques were used to evaluate the oxidation behaviors of tested alloys. The superior corrosion resistance of alloy 310S was benefited from a critical Cr content of 25 wt.%. The surface finish played a significant role to vary the oxidation behavior of alloys containing slightly less than the critical Cr content. However, Oxide exfoliation was observed on low Cr content alloys.

Nanoscale surface characterization and miscibility study of a spray-dried injectable polymeric matrix consisting of poly(lactic-co-glycolic acid) and polyvinylpyrrolidone.

PubMed

Meeus, Joke; Chen, Xinyong; Scurr, David J; Ciarnelli, Valeria; Amssoms, Katie; Roberts, Clive J; Davies, Martyn C; van Den Mooter, Guy

2012-09-01

Injectable controlled-release formulations are of increasing interest for the treatment of chronic diseases. This study aims to develop and characterize a polymeric matrix for intramuscular or subcutaneous injection, consisting of two biocompatible polymers, particularly suitable for formulating poorly soluble drugs. For this matrix, the water-insoluble polymer poly(lactic-co-glycolic acid) (PLGA) is combined with the water-soluble polymer polyvinylpyrrolidone (PVP). Microparticles of these two polymers were prepared by spray drying. The phase behavior of the samples was studied by means of modulated differential scanning calorimetry and the results showed that phase separation occurred in the bulk sample through evidence of two mixed amorphous phases, namely, a PLGA-rich phase and a PVP-rich phase. Characterization of the samples by scanning electron microscopy demonstrated that the spray-dried particles were hollow with a thin shell. Because of the importance in relation to stability and drug release, information about the surface of the microparticles was collected by different complementary surface analysis techniques. Atomic force microscopy gathered information about the morphology and phase behavior of the microparticle surface. Time-of-flight secondary ion mass spectrometry analysis of the particles revealed that the surface consisted mainly of the PLGA-rich phase. This was confirmed by X-ray photoelectron spectroscopy at an increased sampling depth (≈ 10 nm). Nanothermal analysis proved to be an innovative way to thermally detect the presence of the PLGA-dominated surface layer and the underlying PVP phase. Taken together, this information provides a rational basis for predicting the likely drug release behavior this formulation will display. Copyright © 2012 Wiley Periodicals, Inc.

Isolation, screening, and characterization of surface-active agent-producing, oil-degrading marine bacteria of Mumbai Harbor.

PubMed

Mohanram, Rajamani; Jagtap, Chandrakant; Kumar, Pradeep

2016-04-15

Diverse marine bacterial species predominantly found in oil-polluted seawater produce diverse surface-active agents. Surface-active agents produced by bacteria are classified into two groups based on their molecular weights, namely biosurfactants and bioemulsifiers. In this study, surface-active agent-producing, oil-degrading marine bacteria were isolated using a modified Bushnell-Haas medium with high-speed diesel as a carbon source from three oil-polluted sites of Mumbai Harbor. Surface-active agent-producing bacterial strains were screened using nine widely used methods. The nineteen bacterial strains showed positive results for more than four surface-active agent screening methods; further, these strains were characterized using biochemical and nucleic acid sequencing methods. Based on the results, the organisms belonged to the genera Acinetobacter, Alcanivorax, Bacillus, Comamonas, Chryseomicrobium, Halomonas, Marinobacter, Nesterenkonia, Pseudomonas, and Serratia. The present study confirmed the prevalence of surface-active agent-producing bacteria in the oil-polluted waters of Mumbai Harbor. Copyright © 2016 Elsevier Ltd. All rights reserved.

Natural Sunlight Shapes Crude Oil-Degrading Bacterial Communities in Northern Gulf of Mexico Surface Waters

PubMed Central

Bacosa, Hernando P.; Liu, Zhanfei; Erdner, Deana L.

2015-01-01

Following the Deepwater Horizon (DWH) spill in 2010, an enormous amount of oil was observed in the deep and surface waters of the northern Gulf of Mexico. Surface waters are characterized by intense sunlight and high temperature during summer. While the oil-degrading bacterial communities in the deep-sea plume have been widely investigated, the effect of natural sunlight on those in oil polluted surface waters remains unexplored to date. In this study, we incubated surface water from the DWH site with amendments of crude oil, Corexit dispersant, or both for 36 days under natural sunlight in the northern Gulf of Mexico. The bacterial community was analyzed over time for total abundance, density of alkane and polycyclic aromatic hydrocarbon degraders, and community composition via pyrosequencing. Our results showed that, for treatments with oil and/or Corexit, sunlight significantly reduced bacterial diversity and evenness and was a key driver of shifts in bacterial community structure. In samples containing oil or dispersant, sunlight greatly reduced abundance of the Cyanobacterium Synechococcus but increased the relative abundances of Alteromonas, Marinobacter, Labrenzia, Sandarakinotalea, Bartonella, and Halomonas. Dark samples with oil were represented by members of Thalassobius, Winogradskyella, Alcanivorax, Formosa, Pseudomonas, Eubacterium, Erythrobacter, Natronocella, and Coxiella. Both oil and Corexit inhibited the Candidatus Pelagibacter with or without sunlight exposure. For the first time, we demonstrated the effects of light in structuring microbial communities in water with oil and/or Corexit. Overall, our findings improve understanding of oil pollution in surface water, and provide unequivocal evidence that sunlight is a key factor in determining bacterial community composition and dynamics in oil polluted marine waters. PMID:26648916

Natural Sunlight Shapes Crude Oil-Degrading Bacterial Communities in Northern Gulf of Mexico Surface Waters.

PubMed

Bacosa, Hernando P; Liu, Zhanfei; Erdner, Deana L

2015-01-01

Following the Deepwater Horizon (DWH) spill in 2010, an enormous amount of oil was observed in the deep and surface waters of the northern Gulf of Mexico. Surface waters are characterized by intense sunlight and high temperature during summer. While the oil-degrading bacterial communities in the deep-sea plume have been widely investigated, the effect of natural sunlight on those in oil polluted surface waters remains unexplored to date. In this study, we incubated surface water from the DWH site with amendments of crude oil, Corexit dispersant, or both for 36 days under natural sunlight in the northern Gulf of Mexico. The bacterial community was analyzed over time for total abundance, density of alkane and polycyclic aromatic hydrocarbon degraders, and community composition via pyrosequencing. Our results showed that, for treatments with oil and/or Corexit, sunlight significantly reduced bacterial diversity and evenness and was a key driver of shifts in bacterial community structure. In samples containing oil or dispersant, sunlight greatly reduced abundance of the Cyanobacterium Synechococcus but increased the relative abundances of Alteromonas, Marinobacter, Labrenzia, Sandarakinotalea, Bartonella, and Halomonas. Dark samples with oil were represented by members of Thalassobius, Winogradskyella, Alcanivorax, Formosa, Pseudomonas, Eubacterium, Erythrobacter, Natronocella, and Coxiella. Both oil and Corexit inhibited the Candidatus Pelagibacter with or without sunlight exposure. For the first time, we demonstrated the effects of light in structuring microbial communities in water with oil and/or Corexit. Overall, our findings improve understanding of oil pollution in surface water, and provide unequivocal evidence that sunlight is a key factor in determining bacterial community composition and dynamics in oil polluted marine waters.

Arsenic transport between surface and groundwater in a moderately reducing zone: Geochemical approach

NASA Astrophysics Data System (ADS)

Khaska, Mahmoud; Le Gal La Salle, Corinne; Verdoux, Patrick

2015-04-01

Arsenic contamination represents a major risk to human health as one of the most prominent environmental causes of cancer mortality. Mining activities, particularly those involving arsenic rich ores have an impact on the environment and on human health that may persist for many decades after mine closure. The relationships between As released from alluvial aquifer in the vicinity of the sulfide-rich mine dumps was demonstrated with geochemical and isotopic tracers (major and traces elements, 87Sr/86Sr, 18O, 2H). Strontium isotopes were used to trace the transport of As downstream from a As rich tailing dam. Increasing As and Fe concentrations in surface water are explained by As release associated with alluvial groundwater discharge to the stream. This process occurs in a moderately reduced section of the stream downgradient from the sulfide-rich tailing dam. High As, total Fe and low Eh in groundwater confirm the discharge of alluvial groundwater and explain its impact on surface water. Transport of As between surface and groundwater can be described as follows: 1- Subsurface moderately reducing conditions prevail in groundwater downgradient from the tailing dams. This suggests a flux of reduced water from sulfide-rich tailing dams which is characterized by its high As and Fe content resulting from the reduction of Fe-sulfides. 2- Upon mixing with surface water, oxidizing conditions prevails and precipitate as Fe hydroxide on the stream bed. As and Sr subsequently adsorbed on the Fe -oxyhydroxide surface. This process contributes to the immobilization of As in surface water. Remaining dissolved As in surface water can be re-introduced in alluvial groundwater downstream of the reducing zone.

Characterization and Fate of Dissolved Organic Matter in the Lena Delta Region, Siberia

NASA Astrophysics Data System (ADS)

Goncalves-Araujo, R.; Stedmon, C. A.; Heim, B.; Dubinenkov, I.; Kraberg, A.; Moiseev, D.; Bracher, A.

2016-02-01

Connectivity between the terrestrial and marine environment in the Artic is changing as a result of climate change, influencing both freshwater budgets and the supply of carbon to the sea. This study characterizes the optical properties of dissolved organic matter (DOM) within the Lena Delta region and evaluates the behavior of DOM across the fresh water-marine gradient. Six fluorescent components (four humic-like; one marine humic-like; one protein-like) were identified by Parallel Factor Analysis (PARAFAC) with a clear dominance of allochthonous humic-like signals. Colored DOM (CDOM) and dissolved organic carbon (DOC) were highly correlated and had their distribution coupled with hydrographical conditions. Higher DOM concentration and degree of humification were associated with the low salinity waters of the Lena River. Values decreased towards the higher salinity Laptev Sea shelf waters. Results demonstrate different responses of DOM mixing in relation to the vertical structure of the water column, as reflecting the hydrographical dynamics in the region. Two mixing curves for DOM were apparent. In surface waters above the pycnocline there was a sharper decrease in DOM concentration in relation to salinity indicating removal. In the bottom water layer the DOM decrease within salinity was less. We propose there is a removal of DOM occurring primarily at the surface layer, which is likely driven by photodegradation and flocculation.

Remote Sensing of Salinity: The Dielectric Constant of Sea Water

NASA Technical Reports Server (NTRS)

LeVine, David M.; Lang, R.; Utku, C.; Tarkocin, Y.

2011-01-01

Global monitoring of sea surface salinity from space requires an accurate model for the dielectric constant of sea water as a function of salinity and temperature to characterize the emissivity of the surface. Measurements are being made at 1.413 GHz, the center frequency of the Aquarius radiometers, using a resonant cavity and the perturbation method. The cavity is operated in a transmission mode and immersed in a liquid bath to control temperature. Multiple measurements are made at each temperature and salinity. Error budgets indicate a relative accuracy for both real and imaginary parts of the dielectric constant of about 1%.

Characterization of an island aquifer from tidal response

NASA Astrophysics Data System (ADS)

Banerjee, Pallavi; Sarwade, Deepak; Singh, V. S.

2008-08-01

Growing demand for potable water for various needs has lead to indiscriminate exploitation of groundwater resources, particularly, in the terrain where surface water resources are negligible. One such area is an island where groundwater is the only source of fresh water. Groundwater is the prime source of fresh water on most of the atolls in the world. Groundwater on these islands is in the form of thin fragile floating lens and is often vulnerable to overexploitation, draught, tidal waves, tsunami and cyclone resulting in seawater ingress. Sustainable development of this meager source of fresh groundwater for a longer time becomes a more difficult task on small atolls with a large population depending on this vital resource. To develop a sustainable management scheme and identify the vulnerable part of aquifer, characterization of the aquifer system on islands is imperative. Groundwater on an atoll is extremely vulnerable to seawater mixing through natural as well as human activities. One such natural process is the tides of the ocean. The response of sea tide to the water table on the island offers valuable data as well as cost-effective means to characterize an aquifer system. Such characterization is vital for the management of groundwater resources on an atoll. The obtained results have compared well with the parameters obtained through a conventional pumping test. Therefore, the use of tidal response to the water table, which can easily be recorded, provides a rapid and cost-effective means to characterization of the aquifer system on the island.

A basin-scale approach for assessing water resources in a semiarid environment: San Diego region, California and Mexico

USGS Publications Warehouse

Flint, L.E.; Flint, A.L.; Stolp, B.J.; Danskin, W.R.

2012-01-01

Many basins throughout the world have sparse hydrologic and geologic data, but have increasing demands for water and a commensurate need for integrated understanding of surface and groundwater resources. This paper demonstrates a methodology for using a distributed parameter water-balance model, gaged surface-water flow, and a reconnaissance-level groundwater flow model to develop a first-order water balance. Flow amounts are rounded to the nearest 5 million cubic meters per year. The San Diego River basin is 1 of 5 major drainage basins that drain to the San Diego coastal plain, the source of public water supply for the San Diego area. The distributed parameter water-balance model (Basin Characterization Model) was run at a monthly timestep for 1940–2009 to determine a median annual total water inflow of 120 million cubic meters per year for the San Diego region. The model was also run specifically for the San Diego River basin for 1982–2009 to provide constraints to model calibration and to evaluate the proportion of inflow that becomes groundwater discharge, resulting in a median annual total water inflow of 50 million cubic meters per year. On the basis of flow records for the San Diego River at Fashion Valley (US Geological Survey gaging station 11023000), when corrected for upper basin reservoir storage and imported water, the total is 30 million cubic meters per year. The difference between these two flow quantities defines the annual groundwater outflow from the San Diego River basin at 20 million cubic meters per year. These three flow components constitute a first-order water budget estimate for the San Diego River basin. The ratio of surface-water outflow and groundwater outflow to total water inflow are 0.6 and 0.4, respectively. Using total water inflow determined using the Basin Characterization Model for the entire San Diego region and the 0.4 partitioning factor, groundwater outflow from the San Diego region, through the coastal plain aquifer to the Pacific Ocean, is calculated to be approximately 50 million cubic meters per year. The area-scale assessment of water resources highlights several hydrologic features of the San Diego region. Groundwater recharge is episodic; the Basin Characterization Model output shows that 90 percent of simulated recharge occurred during 3 percent of the 1982–2009 period. The groundwater aquifer may also be quite permeable. A reconnaissance-level groundwater flow model for the San Diego River basin was used to check the water budget estimates, and the basic interaction of the surface-water and groundwater system, and the flow values, were found to be reasonable. Horizontal hydraulic conductivity values of the volcanic and metavolcanic bedrock in San Diego region range from 1 to 10 m per day. Overall, results establish an initial hydrologic assessment formulated on the basis of sparse hydrologic data. The described flow variability, extrapolation, and unique characteristics represent a realistic view of current (2012) hydrologic understanding for the San Diego region.

Colloidal Particle Adsorption at Water-Water Interfaces with Ultralow Interfacial Tension

NASA Astrophysics Data System (ADS)

Keal, Louis; Colosqui, Carlos E.; Tromp, R. Hans; Monteux, Cécile

2018-05-01

Using fluorescence confocal microscopy we study the adsorption of single latex microparticles at a water-water interface between demixing aqueous solutions of polymers, generally known as a water-in-water emulsion. Similar microparticles at the interface between molecular liquids have exhibited an extremely slow relaxation preventing the observation of expected equilibrium states. This phenomenon has been attributed to "long-lived" metastable states caused by significant energy barriers Δ F ˜γ Ad≫kBT induced by high interfacial tension (γ ˜10-2 N /m ) and nanoscale surface defects with characteristic areas Ad≃10 - 30 nm2 . For the studied water-water interface with ultralow surface tension (γ ˜10-4 N /m ) we are able to characterize the entire adsorption process and observe equilibrium states prescribed by a single equilibrium contact angle independent of the particle size. Notably, we observe crossovers from fast initial dynamics to slower kinetic regimes analytically predicted for large surface defects (Ad≃500 nm2). Moreover, particle trajectories reveal a position-independent damping coefficient that is unexpected given the large viscosity contrast between phases. These observations are attributed to the remarkably diffuse nature of the water-water interface and the adsorption and entanglement of polymer chains in the semidilute solutions. This work offers some first insights on the adsorption dynamics or kinetics of microparticles at water-water interfaces in biocolloidal systems.

Extraction and Characterization of Surfactants from Atmospheric Aerosols.

PubMed

Nozière, Barbara; Gérard, Violaine; Baduel, Christine; Ferronato, Corinne

2017-04-21

Surface-active compounds, or surfactants, present in atmospheric aerosols are expected to play important roles in the formation of liquid water clouds in the Earth's atmosphere, a central process in meteorology, hydrology, and for the climate system. But because specific extraction and characterization of these compounds have been lacking for decades, very little is known on their identity, properties, mode of action and origins, thus preventing the full understanding of cloud formation and its potential links with the Earth's ecosystems. In this paper we present recently developed methods for 1) the targeted extraction of all the surfactants from atmospheric aerosol samples and for the determination of 2) their absolute concentrations in the aerosol phase and 3) their static surface tension curves in water, including their Critical Micelle Concentration (CMC). These methods have been validated with 9 references surfactants, including anionic, cationic and non-ionic ones. Examples of results are presented for surfactants found in fine aerosol particles (diameter <1 μm) collected at a coastal site in Croatia and suggestions for future improvements and other characterizations than those presented are discussed.

Extraction and Characterization of Surfactants from Atmospheric Aerosols

PubMed Central

Baduel, Christine; Ferronato, Corinne

2017-01-01

Surface-active compounds, or surfactants, present in atmospheric aerosols are expected to play important roles in the formation of liquid water clouds in the Earth's atmosphere, a central process in meteorology, hydrology, and for the climate system. But because specific extraction and characterization of these compounds have been lacking for decades, very little is known on their identity, properties, mode of action and origins, thus preventing the full understanding of cloud formation and its potential links with the Earth's ecosystems. In this paper we present recently developed methods for 1) the targeted extraction of all the surfactants from atmospheric aerosol samples and for the determination of 2) their absolute concentrations in the aerosol phase and 3) their static surface tension curves in water, including their Critical Micelle Concentration (CMC). These methods have been validated with 9 references surfactants, including anionic, cationic and non-ionic ones. Examples of results are presented for surfactants found in fine aerosol particles (diameter <1 μm) collected at a coastal site in Croatia and suggestions for future improvements and other characterizations than those presented are discussed. PMID:28518073

Using in-situ observations of atmospheric water vapor isotopes to benchmark and isotope-enabled General Circulation Models and improve ice core paleo-climate reconstruction

NASA Astrophysics Data System (ADS)

Steen-Larsen, Hans Christian; Sveinbjörnsdottir, Arny; Masson-Delmotte, Valerie; Werner, Martin; Risi, Camille; Yoshimura, Kei

2016-04-01

We have since 2010 carried out in-situ continuous water vapor isotope observations on top of the Greenland Ice Sheet (3 seasons at NEEM), in Svalbard (1 year), in Iceland (4 years), in Bermuda (4 years). The expansive dataset containing high accuracy and precision measurements of δ18O, δD, and the d-excess allow us to validate and benchmark the treatment of the atmospheric hydrological cycle's processes in General Circulation Models using simulations nudged to reanalysis products. Recent findings from both Antarctica and Greenland have documented strong interaction between the snow surface isotopes and the near surface atmospheric water vapor isotopes on diurnal to synoptic time scales. In fact, it has been shown that the snow surface isotopes take up the synoptic driven atmospheric water vapor isotopic signal in-between precipitation events, erasing the precipitation isotope signal in the surface snow. This highlights the importance of using General or Regional Climate Models, which accurately are able to simulate the atmospheric water vapor isotopic composition, to understand and interpret the ice core isotope signal. With this in mind we have used three isotope-enabled General Circulation Models (isoGSM, ECHAM5-wiso, and LMDZiso) nudged to reanalysis products. We have compared the simulations of daily mean isotope values directly with our in-situ observations. This has allowed us to characterize the variability of the isotopic composition in the models and compared it to our observations. We have specifically focused on the d-excess in order to characterize why both the mean and the variability is significantly lower than our observations. We argue that using water vapor isotopes to benchmark General Circulation Models offers an excellent tool for improving the treatment and parameterization of the atmospheric hydrological cycle. Recent studies have documented a very large inter-model dispersion in the treatment of the Arctic water cycle under a future global warming and greenhouse gas emission scenario. Our results call for action to create an international pan-Arctic monitoring water vapor isotope network in order to improve future projections of Arctic climate.

Phoenix - the First Mars Scout Mission

NASA Technical Reports Server (NTRS)

Goldstein, Barry; Shotwell, Robert

2008-01-01

As the first of the new Mars Scouts missions, the Phoenix project was selected by NASA in August of 2003. Four years later, almost to the day, Phoenix was launched from Cape Canaveral Air Station and successfully injected into an interplanetary trajectory on its way to Mars. This paper will highlight some of the key changes since the 2006 IEEE paper of the same name, as well as activities, challenges and problems encountered on the way to the launch pad. Phoenix Follows the water responding directly to the recently published data from Dr. William Boynton, PI (and Phoenix co-I) of the Mars Odyssey Gamma Ray Spectrometer (GRS). GRS data indicate extremely large quantities of water ice (up to 50% by mass) within the upper 50 cm of the northern polar regolith. Phoenix will land within the north polar region at 68.2 N, 233.4 W identified by GRS to harbor near surface water ice and provide in-situ confirmation of this extraordinary find. Our mission will investigate water in all its phases, and will investigate the history of water as evidenced in the soil characteristics that will be carefully examined by the powerful suite of onboard instrumentation. Access to the critical subsurface region expected to contain this information is made possible by a third generation robotic arm capable of excavating the expected Martian regolith to a depth of 1m. Phoenix has four primary science objectives: 1) Determine the polar climate and weather, interaction with the surface, and composition of the lower atmosphere around 70 N for at least 90 sols focusing on water, ice, dust, noble gases, and CO2. Determine the atmospheric characteristics during descent through the atmosphere. 2) Characterize the geomorphology and active processes shaping the northern plains and the physical properties of the near surface regolith focusing on the role of water. 3) Determine the aqueous mineralogy and chemistry as well as the adsorbed gases and organic content of the regolith. Verify the Odyssey discovery of near-surface ice. 4) Characterize the history of water, ice, and the polar 1 1-4244-1488-1/08/$25.00 2008 IEEE 2 IEEEAC paper#1579, Version 1, Updated 2008:01:09 climate. Determine the past and present biological potential of the surface and subsurface environments.

Time Series Analysis of Subsidence and Water-Level Data for Aquifer System Characterization

NASA Astrophysics Data System (ADS)

Burbey, T. J.

2012-12-01

The accessibility of high resolution surface displacement data in the form of InSAR, PS-InSAR, GPS, and extensometer data in heavily pumped basins provides diagnostic information that can be used in powerful ways to characterize the hydraulic properties of both confining units and aquifers that water-level data alone cannot accomplish. Land surface deformation signals reflect the elastic and inelastic properties of the heterogeneous aquifer system. These deformation signals can be quite complex and coupled with water level data often exhibit temporal signals at daily, seasonal, and decadal scales resulting from accompanying cyclical pumping patterns. In Las Vegas Valley, for example, cyclical seasonal and daily water-level fluctuations are superimposed on long-term water-level declines. The resulting changes in effective stress have resulted in decades of inelastic land surface lowering with superimposed seasonal elastic deformation signals. In this investigation signal processing of both water level and deformation data was done to filter separate signals at daily, seasonal, and decadal time scales that can be individually evaluated to more accurately estimate the hydraulic properties of the principle aquifer system in the valley that consists of multiple aquifers and confining units. Both elastic and inelastic skeletal specific storage, the horizontal hydraulic conductivity of the aquifers, and the vertical hydraulic conductivity of the confining units can be readily evaluated in this manner. The results compare favorably with the parameters calculated from a complex one-dimensional numerical compaction model. The advantage of the time series approach is that a more thorough description of the system can be made and the analytical approach is far simpler than constructing and calibrating a numerical model.

Chemical and physical characterization of produced waters from conventional and unconventional fossil fuel resources.

PubMed

Alley, Bethany; Beebe, Alex; Rodgers, John; Castle, James W

2011-09-01

Characterization of produced waters (PWs) is an initial step for determining potential beneficial uses such as irrigation and surface water discharge at some sites. A meta-analysis of characteristics of five PW sources [i.e. shale gas (SGPWs), conventional natural gas (NGPWs), conventional oil (OPWs), coal-bed methane (CBMPWs), tight gas sands (TGSPWs)] was conducted from peer-reviewed literature, government or industry documents, book chapters, internet sources, analytical records from industry, and analyses of PW samples. This meta-analysis assembled a large dataset to extract information of interest such as differences and similarities in constituent and constituent concentrations across these sources of PWs. The PW data analyzed were comprised of 377 coal-bed methane, 165 oilfield, 137 tight gas sand, 4000 natural gas, and 541 shale gas records. Majority of SGPWs, NGPWs, OPWs, and TGSPWs contain chloride concentrations ranging from saline (>30000 mg L(-1)) to hypersaline (>40000 mg L(-1)), while most CBMPWs were fresh (<5000 mg L(-1)). For inorganic constituents, most SGPW and NGPW iron concentrations exceeded the numeric criterion for irrigation and surface water discharge, while OPW and CBMPW iron concentrations were less than the criterion. Approximately one-fourth of the PW samples in this database are fresh and likely need minimal treatment for metal and metalloid constituents prior to use, while some PWs are brackish (5000-30000 mg Cl(-) L(-1)) to saline containing metals and metalloids that may require considerable treatment. Other PWs are hypersaline and produce a considerable waste stream from reverse osmosis; remediation of these waters may not be feasible. After renovation, fresh to saline PWs may be used for irrigation and replenishing surface waters. Copyright © 2011 Elsevier Ltd. All rights reserved.

Geologic and hydrologic characterization and evaluation of the Basin and Range Province relative to the disposal of high-level radioactive waste: Part II, Geologic and hydrologic characterization

USGS Publications Warehouse

Sargent, Kenneth A.; Bedinger, M.S.

1985-01-01

The geology and hydrology of the Basin and Range Province of the western conterminous United States are characterized in a series of data sets depicted in maps compiled for evaluation of prospective areas for further study of geohydrologic environments for isolation of high-level radioactive waste. The data sets include: (1) Average precipitation and evaporation; (2) surface distribution of selected rock types; (3) tectonic conditions; and (4) surface- and ground -water hydrology and Pleistocene lakes and marshes.Rocks mapped for consideration as potential host media for the isolation of high-level radioactive waste are widespread and include argillaceous rocks, granitic rocks, tuffaceous rocks, mafic extrusive rocks, evaporites, and laharic breccias. The unsaturated zone, where probably as thick as 150 meters (500 feet), was mapped for consideration as an environment for isolation of high-level waste. Unsaturated rocks of various lithologic types are widespread in the Province.Tectonic stability in the Quaternary Period is considered the key to assessing the probability of future tectonism with regard to high-level radioactive waste disposal. Tectonic conditions are characterized on the basis of the seismic record, heat-flow measurements, the occurrence of Quaternary faults, vertical crustal movement, and volcanic features. Tectonic activity, as indicated by seismicity, is greatest in areas bordering the western margin of the Province in Nevada and southern California, the eastern margin of the Province bordering the Wasatch Mountains in Utah and in parts of the Rio Grande valley. Late Cenozoic volcanic activity is widespread, being greatest bordering the Sierra Nevada in California and Oregon, and bordering the Wasatch Mountains in southern Utah and Idaho.he arid to semiarid climate of the Province results in few perennial streams and lakes. A large part of the surface drainage is interior and the many closed basins commonly are occupied by playas or dry lake beds. The Province is divided into ground-water flow units defined on the basis of ground-water divides, ground-water flow lines, and surface streams that receive ground-water discharge.Ground water contains less than 500 milligrams per liter of dissolved solids throughout most of the Province. Ground water is more mineralized in areas underlain by evaporitic rocks, overlain by playas, and near saline lakes. Ground water is of the calcium, magnesium, or sodium bicarbonate type in the areas where dissolved-solids concentrations are less than 500 milligrams per liter, and of the calcium, magnesium, or sodium sulfate or chloride type where dissolved-solids concentrations are greater than 500 milligrams per liter.Geologic and hydrologic evidence is found for about 100 lakes and marshes that existed during the Pleistocene Epoch. The possibility of a recurrence of pluvial conditions, such as existed in the Pleistocene, is of concern in repository siting because of possible changes in hydrologic conditions. The Pleistocene lakes and marshes provide clues to the hydrology during pluvial climates.

Molecular dynamics study of a nanotube-binding amphiphilic helical peptide at different water/hydrophobic interfaces.

PubMed

Chiu, Chi-Cheng; Dieckmann, Gregg R; Nielsen, Steven O

2008-12-25

Many potential applications of single-walled carbon nanotubes (SWNTs) require that they be isolated from one another. This may be accomplished through covalent or noncovalent SWNT functionalization. The noncovalent approach preserves the intrinsic electrical, optical, and mechanical properties of SWNTs and can be achieved by dispersing SWNTs in aqueous solution using surfactants, polymers, or biomacromolecules like DNA or polypeptides. The designed amphiphilic helical peptide nano-1, which contains hydrophobic valine and aromatic phenylalanine residues for interaction with SWNTs and glutamic acid and lysine residues for water solubility, has been shown to debundle and disperse SWNTs, although the details of the peptide-SWNT interactions await elucidation. Here we use fully atomistic molecular dynamics simulations to investigate the nano-1 peptide at three different water/hydrophobic interfaces: water/oil, water/graphite, and water/SWNT. The amphiphilic nature of the peptide is characterized by its secondary structure, peptide-water hydrogen bonding, and peptide-hydrophobic surface van der Waals energy. We show that nano-1 has reduced amphiphilic character at the water/oil interface because the peptide helix penetrates into the hydrophobic phase. The peptide alpha-helix cannot match its hydrophobic face to the rigid planar graphite surface without partially unfolding. In contrast, nano-1 can curve on the SWNT surface in an alpha-helical conformation to simultaneously maximize its hydrophobic contacts with the SWNT and its hydrogen bonds with water. The molecular insight into the peptide conformation at the various hydrophobic surfaces provides guidelines for future peptide design.

Characterization and corrosion behavior of F6NM stainless steel treated in high temperature water

NASA Astrophysics Data System (ADS)

Li, Zheng-yang; Cai, Zhen-bing; Yang, Wen-jin; Shen, Xiao-yao; Xue, Guo-hong; Zhu, Min-hao

2018-03-01

F6NM martensitic stainless steel was exposed to 350 °C water condition for 500, 1500, and 2500 h to simulate pressurized water reactor (PWR) condition. The characterization and corrosion behavior of the oxide film were investigated. Results indicate that the exposed steel surface formed a double-layer oxide film. The outer oxide film is Fe-rich and contains two type oxide particles. However, the inner oxide film is Cr-rich, and two oxide films, whose thicknesses increase with increasing exposure time. The oxide film reduces the corrosion behavior because the outer oxide film has many crack and pores. Finally, the mechanism and factors affecting the formation of the oxide film were investigated.

Synoptic events force biological productivity in Patagonian fjord ecosystems

NASA Astrophysics Data System (ADS)

Daneri, Giovanni

2016-04-01

The annual cycle of primary productivity of the Patagonian fjords has, to date, been described as a two phase system consisting of a short non productive winter phase (during June and July) and a productive phase extending from late winter (August) to autumn (May). Low levels of primary production, phytoplankton biomass and high concentrations of surface nutrients have been described as characterizing winter conditions while pulsed productivity events typifies the productivity pattern during the extended productive season. Pulsed productivity events characterize coastal waters where inorganic nutrients in surface layers are replenished following periods of intensive utilization by autotrophs. Freshwater input in Patagonian fjords in southern Chile (41-55°S) results in one of the largest estuarine regions worldwide. Here strong haline water column stratification prevents nutrient mixing to the surface layers thus potentially shutting off algal production. Our working hypothesis considered that in order to reconcile the observed pulsed productivity pattern, periodic breaking (associated to surface nutrient replenishment) and re-establishment of estuarine conditions (associated to water column stratification) would be required. Up to now however our understanding of the physical processes that control water column conditions in the Patagonian fjord area has been extremely limited. Here we present evidence linking the passage of synoptic low pressure fronts to pulsed productivity events in the Patagonian fjord area. These front controls and influence local processes of interaction between the fjord and the atmosphere generating a rapid water column response. In the specific case of the Puyuhuapi fjord we have been able to show that such synoptic fronts induce surface flow reversal and water column mixing. Phytoplankton blooming occurs after the passage of the synoptic front once calmer conditions prevail and estuarine conditions are re established. The occurrence of an extremely productive bloom of the dinoflagellate Heterocapsa sp. in July 2014, after the passage of a synoptic low pressure front provided, for the first time, strong evidence that phytoplankton blooming in the Patagonian fjord ecosystems is controlled by synoptic processes and that they are not limited by light as previously reported. This research was funded by COPAS Sur-Austral (PFB-31) and FONDECYT 1131063

Modeling the Surface Water-Groundwater Interaction in Arid and Semi-Arid Regions Impacted by Agricultural Activities

NASA Astrophysics Data System (ADS)

Tian, Y.; Wu, B.; Zheng, Y.

2013-12-01

In many semi-arid and arid regions, interaction between surface water and groundwater plays an important role in the eco-hydrological system. The interaction is often complicated by agricultural activities such as surface water diversion, groundwater pumping, and irrigation. In existing surface water-groundwater integrated models, simulation of the interaction is often simplified, which could introduce significant simulation uncertainty under certain circumstance. In this study, GSFLOW, a USGS model coupling PRMS and MODFLOW, was improved to better characterize the surface water-groundwater interaction. The practices of water diversion from rivers, groundwater pumping and irrigation are explicitly simulated. In addition, the original kinematic wave routing method was replaced by a dynamic wave routing method. The improved model was then applied in Zhangye Basin (the midstream part of Heihe River Baisn), China, where the famous 'Silk Road' came through. It is a typical semi-arid region of the western China, with extensive agriculture in its oasis. The model was established and calibrated using the data in 2000-2008. A series of numerical experiments were conducted to evaluate the effect of those improvements. It has been demonstrated that with the improvements, the observed streamflow and groundwater level were better reproduced by the model. The improvements have a significant impact on the simulation of multiple fluxes associated with the interaction, such as groundwater discharge, riverbed seepage, infiltration, etc. Human activities were proved to be key elements of the water cycle in the study area. The study results have important implications to the water resources modeling and management in semi-arid and arid basins.

Evidence suggests water once flowed vigorously on Mars

NASA Astrophysics Data System (ADS)

Showstack, Randy

2012-10-01

"In some cases, when you do geology, a picture is worth 1000 words," Mars Science Laboratory project scientist John Grotzinger said at a 27 September news briefing to announce that imagery taken by a camera onboard NASA's Mars Curiosity rover shows evidence that water once flowed vigorously in a region on the surface of Mars. One of the pictured rock outcrops, about 10-15 centimeters thick and named Hottah after Canada's Hottah lake, "looked like somebody came along the surface of Mars with a jackhammer and lifted up a sidewalk that you might see in downtown LA in sort of a construction site," said Grotzinger, who is with the California Institute of Technology in Pasadena. "This is a rock that was formed in the presence of water, and we can characterize that water as being a vigorous flow on the surface of Mars," he said. "We were really excited about this because this is one of the reasons we were interested in coming to this landing site, because it presented from orbit quite a strong case that we would find evidence for water on the ground."

Anthropogenic organic compounds in source water of select community water systems in the United States, 2002-10

USGS Publications Warehouse

Valder, Joshua F.; Delzer, Gregory C.; Kingsbury, James A.; Hopple, Jessica A.; Price, Curtis V.; Bender, David A.

2014-01-01

Drinking water delivered by community water systems (CWSs) comes from one or both of two sources: surface water and groundwater. Source water is raw, untreated water used by CWSs and is usually treated before distribution to consumers. Beginning in 2002, the U.S. Geological Survey’s (USGS) National Water-Quality Assessment Program initiated Source Water-Quality Assessments (SWQAs) at select CWSs across the United States, primarily to characterize the occurrence of a large number of anthropogenic organic compounds that are predominantly unregulated by the U.S. Environmental Protection Agency. Source-water samples from CWSs were collected during 2002–10 from 20 surface-water sites (river intakes) and during 2002–09 from 448 groundwater sites (supply wells). River intakes were sampled approximately 16 times during a 1-year sampling period, and supply wells were sampled once. Samples were monitored for 265 anthropogenic organic compounds. An additional 3 herbicides and 16 herbicide degradates were monitored in samples collected from 8 river intakes and 118 supply wells in areas where these compounds likely have been used. Thirty-seven compounds have an established U.S. Environmental Protection Agency (EPA) Maximum Contaminant Level (MCL) for drinking water, 123 have USGS Health-Based Screening Levels (HBSLs), and 29 are included on the EPA Contaminant Candidate List 3. All compounds detected in source water were evaluated both with and without an assessment level and were grouped into 13 categories (hereafter termed as “use groups”) based on their primary use or source. The CWS sites were characterized in a national context using an extract of the EPA Safe Drinking Water Information System to develop spatially derived and system-specific ancillary data. Community water system information is contained in the EPA Public Supply Database, which includes 2,016 active river intakes and 112,099 active supply wells. Ancillary variables including population served, watershed size, land use, population density, and recharge were characterized for each of the watersheds for river intakes and contributing areas for supply wells. A total of 313 samples were collected from 20 river intakes. Between the years of 2002 through 2010, samples were collected approximately 16 times over the course of a year. Seventy-one compounds from 12 of the 13 use groups commonly occurred (detected in greater than or equal to 1 percent of samples using an assessment level of 0.05 microgram per liter or when a compound was detected in greater than or equal to 10 percent of samples without an assessment level) indicating a wide variety of sources and pathways to these rivers and highlighting the importance of source-water protection strategies. A total of 448 supply wells were sampled once during 2002–10 as part of 30 independent groundwater studies. About 15 CWS supply wells were sampled for each independent groundwater study. Twenty-eight compounds from 7 of the 13 use groups commonly occurred indicating a wide variety of sources and pathways exist for these compounds to reach these wells and highlighting the importance of wellhead protection strategies. About one-half the 265 compounds monitored (122) were detected in both surface water and groundwater samples. A more diverse suite of compounds were detected in surface water in comparison to groundwater. However, herbicides and herbicide degradates were the most frequent group of compounds detected in both surface water and groundwater. Sixty-five of the most commonly occurring compounds were detected in one or more samples from both surface water and groundwater. Human-health benchmarks (MCLs for regulated compounds and HBSLs for unregulated compounds) were available for more than one-half the compounds (160 of the 265) monitored in this study. Fifty-eight percent (41 of 71) of the commonly occurring compounds in surface water have a human-health benchmark to which concentrations can be compared; 19 have MCLs and 22 have HBSLs. Eighty-three percent (24 of 28) of the most commonly occurring compounds in groundwater have a human-health benchmark for which concentrations can be compared; 14 have MCLs and 10 have HBSLs. To put results from this study into context with the national distribution of river intakes and supply wells used by CWSs, sites were grouped into the respective national population of land-use quartiles. The increase in compound occurrence with increasing urban and agricultural land use in the watershed or contributing area was more evident for rivers than for supply wells. The increase in detection frequency of herbicides and herbicide degradates with increasing agricultural land use was more evident for rivers than for supply wells. The occurrence of solvents did not change substantially with increasing urban land use for rivers or supply wells. Basic co-occurrence analyses were completed with and without an assessment level. Considering all detections in surface water without an assessment level, approximately 86 percent of source-water samples contained 2 or more compounds, and 50 percent of samples contained at least 14 compounds. Considering all detections in groundwater without an assessment level, 50 percent of samples contained at least three compounds. For the most part, the compounds detected most frequently as individual compounds in the environment often composed the most frequent unique mixtures. Five of the 10 most frequently co-occurring unique mixtures in both surface water and groundwater were the same: atrazine and deethylatrazine; atrazine and chloroform; deethylatrazine and simazine; atrazine and simazine; and deethylatrazine, atrazine, and simazine. Because similar mixtures were identified in both surface water and groundwater without an assessment level, future studies could be directed toward better understanding the toxicological importance of these unique mixtures. Summed concentrations of herbicide degradates were compared to concentrations of the parent herbicides in surface-water and groundwater samples collected from 8 river intakes and 118 CWS wells, from which samples were analyzed for an additional 3 herbicides and 16 degradates. The toxicity to humans for many of these degradate products is largely unknown and thus points to the importance of monitoring these compounds (both the parent and degradate) in the environment. This study highlights the importance of anthropogenic organic compounds in source water of select CWSs in the United States by characterizing their occurrence in surface-water and groundwater samples. Compound concentrations and occurrence are summarized and evaluated in a human-health context, when possible. Additionally, compounds found to co-occur as mixtures for both surface water and groundwater highlight the significance of low-level compound co-occurrence.

A Multifunctional Surface That Simultaneously Balances Hydrophilic Enzyme Catalysis and Hydrophobic Water Repellency.

PubMed

Lawton, Timothy J; Uzarski, Joshua R; Filocamo, Shaun F

2016-08-16

The compatibility of multiple functions at a single interface is difficult to achieve, but is even more challenging when the functions directly counteract one another. This study provides insight into the creation of a simultaneously multifunctional surface formed by balancing two orthogonal functions; water repellency and enzyme catalysis. A partially fluorinated thiol is used to impart bulk hydrophobicity on the surface, and an N-hydroxysuccinimide ester-terminated thiol provides a specific anchoring sites for the covalent enzyme attachment. Different ratios of the two thiols are mixed together to form amphiphilic self-assembled monolayers, which are characterized with polarization-modulation infrared reflection-absorption spectroscopy and contact angle goniometry. The enzyme activity is measured by a fluorescence assay. With the results collected here, specific surface compositions are identified at which the orthogonal functions of water repellency and enzyme catalysis are balanced and exist simultaneously. An understanding of how to effectively balance orthogonal functions at surfaces can be extended to a number of higher-scale applications. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Dynamics of Water in Gemini Surfactant-Based Lyotropic Liquid Crystals

DOE PAGES

McDaniel, Jesse G.; Mantha, Sriteja; Yethiraj, Arun

2016-09-26

The dynamics of water confined to nanometer-sized domains is important in a variety of applications ranging from proton exchange membranes to crowding effects in biophysics. In this work we study the dynamics of water in gemini surfactant-based lyotropic liquid crystals (LLCs) using molecular dynamics simulations. These systems have well characterized morphologies, e.g., hexagonal, gyroid, and lamellar, and the surfaces of the confining regions can be controlled by modifying the headgroup of the surfactants. This allows one to study the effect of topology, functionalization, and interfacial curvature on the dynamics of confined water. Through analysis of the translational diffusion and rotationalmore » relaxation we conclude that the hydration level and resulting confinement lengthscale is the predominate determiner of the rates of water dynamics, and other effects, namely surface functionality and curvature, are largely secondary. In conclusion, this novel analysis of the water dynamics in these LLC systems provides an important comparison for previous studies of water dynamics in lipid bilayers and reverse micelles.« less

Friction and wear of metals in contact with pyrolytic graphite

NASA Technical Reports Server (NTRS)

Buckley, D. H.; Brainard, W. A.

1975-01-01

Sliding friction experiments were conducted with gold, iron, and tantalum single crystals sliding on prismatic and basal orientations of pyrolytic graphite in various environments, including vacuum, oxygen, water vapor, nitrogen, and hydrogen bromide. Surfaces were examined in the clean state and with various adsorbates present on the graphite surfaces. Auger and LEED spectroscopy, SEM, and EDXA were used to characterize the graphite surfaces. Results indicate that the prismatic and basal orientations do not contain nor do they chemisorb oxygen, water vapor, acetylene, or hydrogen bromide. All three metals exhibited higher friction on the prismatic than on the basal orientation and these metals transferred to the atomically clean prismatic orientation of pyrolytic graphite. No metal transfer to the graphite was observed in the presence of adsorbates at 760 torr. Ion bombardment of the graphite surface with nitrogen ions resulted in the adherence of nitrogen to the surface.

Visible and thermal imaging of sea ice and open water from Coast Guard Arctic Domain Awareness flights

NASA Astrophysics Data System (ADS)

Chickadel, C. C.; Lindsay, R. W.; Clark, D.

2014-12-01

An uncooled thermal camera (microbolometer) and RGB camera were mounted in the tail section of a US Coast Guard HC-130 to observe sea ice, open water, and cloud tops through the open rear cargo doors during routine Arctic Domain Awareness (ADA) flights. Recent flights were conducted over the Beaufort Sea in June, July, and August of 2014, with flights planned for September and October. Thermal and visible images were collected at low altitude (100m) during times when the cargo doors were open and recorded high resolution information on ice floes, melt ponds, and surface temperature variability associated with the marginal ice zone (MIZ). These observations of sea ice conditions and surface water temperatures will be used to characterize floe size development and the temperature and albedo of ice ponds and leads. This information will allow for a detailed characterization of sea ice that can be used in process studies and for model evaluation, calibration of satellite remote sensing products, and initialization of sea ice prediction schemes.

Measurement of Vapor Flow As an Important Source of Water in Dry Land Eco-Hydrology

NASA Astrophysics Data System (ADS)

Wang, Z.; He, Z.; Wang, Y.; Gao, Z.; Hishida, K.

2014-12-01

When the temperature of land surface is lower than that of air and deeper soils, water vapor gathers toward the ground surface where dew maybe formed depending on the prevailing dew point and wind speed. Some plants are able to absorb the dew and vapor flow while the soil can readily absorb both. Certain animals such as desert beetles and ants harvest the dew or fog for daily survival. Recently, it is also realized that the dew and vapor flow can be a life-saving amount of water for plant survival at the driest seasons of the year in arid and semi-arid regions. Researches are conducted to quantify the amount of near-surface vapor flow in arid and semi-arid regions in China and USA. Quantitative leaf water absorption and desorption functions were derived based on laboratory experiments. Results show that plant leaves absorb and release water at different speeds depending on species and varieties. The "ideal" native plants in the dry climates can quickly absorb water and slowly release it. This water-holding capacity of plant is characterized by the absorption and desorption functions derived for plant physiology and water balance studies. Field studies are conducted to measure the dynamic vapor flow movements from the atmosphere and the groundwater table to soil surface. Results show that dew is usually formed on soil and plant surfaces during the daily hours when the temperature gradients are inverted toward the soil surface. The amount of dew harvested using gravels on the soil surface was enough to support water melon agriculture on deserts. The vapor flow can be effectively intercepted by artificially seeded plants in semi-arid regions forming new forests. New studies are attempted to quantify the role of vapor flow for the survival of giant sequoias in the southern Sierra Nevada Mountains of California.

Enhanced water repellency of surfaces coated with multiscale carbon structures

NASA Astrophysics Data System (ADS)

Marchalot, Julien; Ramos, Stella. M. M.; Pirat, Christophe; Journet, Catherine

2018-01-01

Low cost and well characterized superhydrophobic surfaces are frequently required for industrial applications. Materials are commonly structured at the micro or nano scale. Surfaces decorated with nanotube derivatives synthesized by plasma enhanced chemical vapor deposition (PECVD) are of particular interest, since suitable modifications in the growth parameters can lead to numerous designs. In this article, we present surfaces that are selected for their specific wetting features with patterns ranging from dense forests to jungles with concave (re-entrant) surface such as flake-like multiscale roughness. Once these surfaces are functionalized adequately, their wetting properties are investigated. Their ability to sustain a superhydrophobic state for sessile water drops is examined. Finally, we propose a design to achieve a robust so-called ;Fakir; state, even for micrometer-sized drops, whereas with classic nanotubes forests it is not achievable. Thus, the drop remains on the apex of the protrusions with a high contact angle and a low contact angle hysteresis, while the surface features demonstrate good mechanical resistance against capillary forces.

Utilizing Temperature and Resistivity Data as a Way to Characterize Water and Solute Movement and Groundwater-Surface Water Interaction in Variably Saturated Porous Media

NASA Astrophysics Data System (ADS)

Scotch, C.; Murgulet, D.; Hay, R.

2012-12-01

This study utilizes a multidisciplinary approach to better analyze the extent to which groundwater and surface water interact in the Oso Creek water shed of South Texas using temperature data, electrical resistivity and numerical modeling methods. The three primary objectives of this study are to: (1) identify primary areas of streambed groundwater-surface water interaction using temperature time series and resistivity soundings; (2) improve understanding of solute flow and groundwater, surface water, and sediment interaction in a semiarid, urban coastal area; (3) improve our understanding of groundwater contribution to contaminant transport and discharge to the bays and estuaries and ultimately the Gulf of Mexico. Temperature data was acquired over a one year period, using temperature loggers, from June 11, 2009 to May 18, 2010 at 15-minute intervals from 17 monitoring sites along Oso Creek and its tributaries. Each monitoring site consisted of 4 temperature loggers equally vertically spaced from the stream surface down to a depth of one meter. Furthermore, groundwater temperatures and water levels were collected from wells adjacent to the temperature monitoring sites. In order to fulfill the objectives of this study, existing hydrogeologic, stratigraphic, and other ancillary data are being integrated into a finite difference model developed using the USGS VS2DT software for the Oso Creek Watershed. The model will be calibrated using existing temperature and water level data and a resistivity component will also be added to assure accuracy of the model and temperature data by helping to identify varying lithologies and water conductivities. Compiling a time-series of temperature data and incorporating available hydrostratigraphic, geomorphologic and water level data will enable the development of a comprehensive database. This database is necessary to develop the detailed flow model that will enable an understanding of the extent of groundwater surface water interaction and their associated flow regimes.

A methodological approach to characterize the resilience of aquatic ecosystems with application to Lake Annecy, France

NASA Astrophysics Data System (ADS)

Pinault, J.-L.; Berthier, F.

2007-01-01

We propose a methodological approach to characterize the resilience of aquatic ecosystems with respect to the evolution of environmental parameters as well as their aptitude to adapt to forcings. This method that is applied to Lake Annecy, France, proceeds in three stages. First, according to the depth, variations of physicochemical parameters versus time are separated into three components related to (1) energy transfer through the surface of the lake, (2) the flow of rivers and springs that feed the lake, and (3) long-term evolution of the benthic zone as a consequence of mineral and organic matter loads. Second, dynamics of the lake are deduced by analyzing the physicochemical parameter components related to the three boundary conditions. Third, a stochastic process associated with the transfer models aims to characterize the resilience of the lakes according to forcings. For Lake Annecy, whose dynamics are representative of oligotrophic stratified lakes controlled by decarbonation processes where turnover and mixing occurring once a year in winter, the major consequence is the impoverishment of dissolved oxygen in deep water in autumn due to a temperature increase of the surface water in summer. The simulation raises relevant questions about whether a connection exists between physicochemical parameters and global warming, which should not induce harmful consequences on water quality and biodiversity in deep water. This methodological approach is general since it does not use any physical conceptual model to predict the hydrosystem behavior but uses directly observed data.

Simulation of climate-change effects on streamflow, lake water budgets, and stream temperature using GSFLOW and SNTEMP, Trout Lake Watershed, Wisconsin

USGS Publications Warehouse

Hunt, Randall J.; Walker, John F.; Selbig, William R.; Westenbroek, Stephen M.; Regan, R. Steve

2013-01-01

Although groundwater and surface water are considered a single resource, historically hydrologic simulations have not accounted for feedback loops between the groundwater system and other hydrologic processes. These feedbacks include timing and rates of evapotranspiration, surface runoff, soil-zone flow, and interactions with the groundwater system. Simulations that iteratively couple the surface-water and groundwater systems, however, are characterized by long run times and calibration challenges. In this study, calibrated, uncoupled transient surface-water and steady-state groundwater models were used to construct one coupled transient groundwater/surface-water model for the Trout Lake Watershed in north-central Wisconsin, USA. The computer code GSFLOW (Ground-water/Surface-water FLOW) was used to simulate the coupled hydrologic system; a surface-water model represented hydrologic processes in the atmosphere, at land surface, and within the soil-zone, and a groundwater-flow model represented the unsaturated zone, saturated zone, stream, and lake budgets. The coupled GSFLOW model was calibrated by using heads, streamflows, lake levels, actual evapotranspiration rates, solar radiation, and snowpack measurements collected during water years 1998–2007; calibration was performed by using advanced features present in the PEST parameter estimation software suite. Simulated streamflows from the calibrated GSFLOW model and other basin characteristics were used as input to the one-dimensional SNTEMP (Stream-Network TEMPerature) model to simulate daily stream temperature in selected tributaries in the watershed. The temperature model was calibrated to high-resolution stream temperature time-series data measured in 2002. The calibrated GSFLOW and SNTEMP models were then used to simulate effects of potential climate change for the period extending to the year 2100. An ensemble of climate models and emission scenarios was evaluated. Downscaled climate drivers for the period 2010–2100 showed increases in maximum and minimum temperature over the scenario period. Scenarios of future precipitation did not show a monotonic trend like temperature. Uncertainty in the climate drivers increased over time for both temperature and precipitation. Separate calibration of the uncoupled groundwater and surface-water models did not provide a representative initial parameter set for coupled model calibration. A sequentially linked calibration, in which the uncoupled models were linked by means of utility software, provided a starting parameter set suitable for coupled model calibration. Even with sequentially linked calibration, however, transmissivity of the lower part of the aquifer required further adjustment during coupled model calibration to attain reasonable parameter values for evaporation rates off a small seepage lake (a lake with no appreciable surface-water outlets) with a long history of study. The resulting coupled model was well calibrated to most types of observed time-series data used for calibration. Daily stream temperatures measured during 2002 were successfully simulated with SNTEMP; the model fit was acceptable for a range of groundwater inflow rates into the streams. Forecasts of potential climate change scenarios showed growing season length increasing by weeks, and both potential and actual evapotranspiration rates increasing appreciably, in response to increasing air temperature. Simulated actual evapotranspiration rates increased less than simulated potential evapotranspiration rates as a result of water limitation in the root zone during the summer high-evapotranspiration period. The hydrologic-system response to climate change was characterized by a reduction in the importance of the snow-melt pulse and an increase in the importance of fall and winter groundwater recharge. The less dynamic hydrologic regime is likely to result in drier soil conditions in rainfed wetlands and uplands, in contrast to less drying in groundwater-fed systems. Seepage lakes showed larger forecast stage declines related to climate change than did drainage lakes (lakes with outlet streams). Seepage lakes higher in the watershed (nearer to groundwater divides) had less groundwater inflow and thus had larger forecast declines in lake stage; however, ground-water inflow to seepage lakes in general tended to increase as a fraction of the lake budgets with lake-stage decline because inward hydraulic gradients increased. Drainage lakes were characterized by less simulated stage decline as reductions in outlet streamflow of set losses to other water flows. Net groundwater inflow tended to decrease in drainage lakes over the scenario period. Simulated stream temperatures increased appreciably with climate change. The estimated increase in annual average temperature ranged from approximately 1 to 2 degrees Celsius by 2100 in the stream characterized by a high groundwater inflow rate and 2 to 3 degrees Celsius in the stream with a lower rate. The climate drivers used for the climate-change scenarios had appreciable variation between the General Circulation Model and emission scenario selected; this uncertainty was reflected in hydrologic flow and temperature model results. Thus, as with all forecasts of this type, the results are best considered to approximate potential outcomes of climate change.

Synthesis and Characterization of Hydroxyapatite/Fullerenol Nanocomposites.

PubMed

Djordjevic, Aleksandar; Ignjatovic, Nenad; Seke, Mariana; Jovic, Danica; Uskokovic, Dragan; Rakocevic, Zlatko

2015-02-01

Fullerenols are polyhydroxylated, water soluble derivatives of fullerene C60, with potential application in medicine as diagnostic agents, antioxidants or nano drug carriers. This paper describes synthesis and physical characterization of a new nanocomposite hydroxyapatite/fullerenol. Surface of the nanocomposite hydroxyapatite/fullerenol is inhomogeneous with the diameter of the particles in the range from 100 nm to 350 nm. The ζ potential of this nanocomposite is ten times lower when compared to hydroxyapatite. Surface phosphate groups of hydroxyapatite are prone to forming hydrogen bonds, when in close contact with hydroxyl groups, which could lead to formation of hydrogen bonds between hydroxyapatite and hydroxyl groups of fullerenol. The surface of hydroxyapatite particles (-2.5 mV) was modified by fullerenol particles, as confirmed by the obtained ζ potential value of the nanocomposite biomaterial hydroxyapatite/fullerenol (-25.0 mV). Keywords: Hydroxyapatite, Fullerenol, Nanocomposite, Surface Analysis.

Inferring field-scale properties of a fractured aquifer from ground surface deformation during a well test

NASA Astrophysics Data System (ADS)

Schuite, Jonathan; Longuevergne, Laurent; Bour, Olivier; Boudin, Frédérick; Durand, Stéphane; Lavenant, Nicolas

2015-12-01

Fractured aquifers which bear valuable water resources are often difficult to characterize with classical hydrogeological tools due to their intrinsic heterogeneities. Here we implement ground surface deformation tools (tiltmetry and optical leveling) to monitor groundwater pressure changes induced by a classical hydraulic test at the Ploemeur observatory. By jointly analyzing complementary time constraining data (tilt) and spatially constraining data (vertical displacement), our results strongly suggest that the use of these surface deformation observations allows for estimating storativity and structural properties (dip, root depth, and lateral extension) of a large hydraulically active fracture, in good agreement with previous studies. Hence, we demonstrate that ground surface deformation is a useful addition to traditional hydrogeological techniques and opens possibilities for characterizing important large-scale properties of fractured aquifers with short-term well tests as a controlled forcing.

Wetlands: Earth's Kidneys

EPA Science Inventory

Wetlands are unique, diverse, and productive habitats that emerge at the fringe of aquatic and upland land systems. The U.S. Environmental Protection Agency (EPA) defines wetlands as "areas that are regularly inundated by surface water or groundwater and characterized by a preva...

OPP Guidance for Submission of State and Tribal Water Quality Monitoring Data

EPA Pesticide Factsheets

This guidance describes the process to submit state and tribal surface and groundwater monitoring data for consideration in exposure characterizations for ecological and and human health risk assessments and in risk management decisions for pesticides.

ERTS-1 observes algal blooms in Lake Erie and Utah Lake

NASA Technical Reports Server (NTRS)

Strong, A. E.

1973-01-01

During late summer when the surface waters of Lake Erie reach their maximum temperature an algal bloom is likely to develop. Such phenomena have been noticed on other shallow lakes using ERTS-1 and characterize eutrophic conditions. The concentration of the algae into long streamers provides additional information on surface circulations. To augment the ERTS-1 MSS data of Lake Erie an aircraft was flown to provide correlative thermal-IR and additional multiband photographs. The algal bloom is highly absorptive in the visible wavelengths but reverses contrast with the surrounding water in the near-IR bands. The absorption of shortwave energy heats the dark brown algal mass, providing a hot surface target for the thermal-IR scanner.

Revisiting a Hydrological Analysis Framework with International Satellite Land Surface Climatology Project Initiative 2 Rainfall, Net Radiation, and Runoff Fields

NASA Technical Reports Server (NTRS)

Koster, Randal D.; Fekete, Balazs M.; Huffman, George J.; Stackhouse, Paul W.

2006-01-01

The International Satellite Land Surface Climatology Project Initiative 2 (ISLSCP-2) data set provides the data needed to characterize the surface water budget across much of the globe in terms of energy availability (net radiation) and water availability (precipitation) controls. The data, on average, are shown to be consistent with Budyko s decades-old framework, thereby demonstrating the continuing relevance of Budyko s semiempirical relationships. This consistency, however, appears only when a small subset of the data with hydrologically suspicious behavior is removed from the analysis. In general, the precipitation, net radiation, and runoff data also appear consistent in their interannual variability and in the phasing of their seasonal cycles.

Enhancing Europa surface characterization with ice penetrating radar: A Comparative study in Antarctica

NASA Astrophysics Data System (ADS)

Curra, C.; Arnold, E.; Karwoski, B.; Grima, C.; Schroeder, D. M.; Young, D. A.; Blankenship, D. D.

2013-12-01

The shape and composition of the surface of Europa result from multiple processes, most of them involving direct and indirect interactions between the liquid and solid phases of its outer water layer. The surface ice composition is likely to reflect the material exchanged with the sub-glacial ocean and potentially holds signatures of organic compounds that could demonstrate the ability of the icy moon to sustain life. Therefore, the most likely targets for in-situ landing missions are primarily located in complex terrains disrupted by exchange mechanisms with the ocean/lenses of sub-glacial liquid water. Any landing site selection process to ensure a safe delivery of a future lander, will then have to confidently characterize its surface roughness. We evaluate the capability of an ice-penetrating radar to characterize the roughness using a statistical method applied to the surface echoes. Our approach is to compare radar-derived data with nadir-imagery and laser altimetry simultaneously acquired on an airborne platform over Marie Byrd Land, West Antarctica, during the 2012-13 GIMBLE survey. The radar is the High-Capability Radar Sounder 2 (HiCARS 2, 60 MHz) system operated by the University of Texas Institute for Geophysics (UTIG), with specifications similar to the Ice Penetrating Radar (IPR) of the Europa Clipper project. Surface textures as seen by simultaneously collected nadir imagery are manually classified, allowing individual contrast stretching for better identification. We identified crevasse fields, blue ice patches, and families of wind-blown patterns. Homogeneity/heterogeneity of the textures has also been an important classification criterion. The various textures are geolocated and compared to the evolution and amplitude of laser-derived and radar-derived roughness. Similarities and discrepancies between these three datasets are illustrated and analyzed to qualitatively constrain radar sensitivity to the surface textures. The result allows for a first insight and discussion into how to interpret statistically-inverted radar data from an icy planetary surface.

Characterization of the intragranular water regime within subsurface sediments: Pore volume, surface area, and mass transfer limitations

USGS Publications Warehouse

Hay, M.B.; Stoliker, D.L.; Davis, J.A.; Zachara, J.M.

2011-01-01

Although "intragranular" pore space within grain aggregates, grain fractures, and mineral surface coatings may contain a relatively small fraction of the total porosity within a porous medium, it often contains a significant fraction of the reactive surface area, and can thus strongly affect the transport of sorbing solutes. In this work, we demonstrate a batch experiment procedure using tritiated water as a high-resolution diffusive tracer to characterize the intragranular pore space. The method was tested using uranium-contaminated sediments from the vadose and capillary fringe zones beneath the former 300A process ponds at the Hanford site (Washington). Sediments were contacted with tracers in artificial groundwater, followed by a replacement of bulk solution with tracer-free groundwater and the monitoring of tracer release. From these data, intragranular pore volumes were calculated and mass transfer rates were quantified using a multirate first-order mass transfer model. Tritium-hydrogen exchange on surface hydroxyls was accounted for by conducting additional tracer experiments on sediment that was vacuum dried after reaction. The complementary ("wet" and "dry") techniques allowed for the simultaneous determination of intragranular porosity and surface area using tritium. The Hanford 300A samples exhibited intragranular pore volumes of ???1% of the solid volume and intragranular surface areas of ???20%-35% of the total surface area. Analogous experiments using bromide ion as a tracer yielded very different results, suggesting very little penetration of bromide into the intragranular porosity. Copyright 2011 by the American Geophysical Union.

Characterization of the intragranular water regime within subsurface sediments: pore volume, surface area, and mass transfer limitations

USGS Publications Warehouse

Hay, Michael B.; Stoliker, Deborah L.; Davis, James A.; Zachara, John M.

2011-01-01

Although "intragranular" pore space within grain aggregates, grain fractures, and mineral surface coatings may contain a relatively small fraction of the total porosity within a porous medium, it often contains a significant fraction of the reactive surface area, and can thus strongly affect the transport of sorbing solutes. In this work, we demonstrate a batch experiment procedure using tritiated water as a high-resolution diffusive tracer to characterize the intragranular pore space. The method was tested using uranium-contaminated sediments from the vadose and capillary fringe zones beneath the former 300A process ponds at the Hanford site (Washington). Sediments were contacted with tracers in artificial groundwater, followed by a replacement of bulk solution with tracer-free groundwater and the monitoring of tracer release. From these data, intragranular pore volumes were calculated and mass transfer rates were quantified using a multirate first-order mass transfer model. Tritium-hydrogen exchange on surface hydroxyls was accounted for by conducting additional tracer experiments on sediment that was vacuum dried after reaction. The complementary ("wet" and "dry") techniques allowed for the simultaneous determination of intragranular porosity and surface area using tritium. The Hanford 300A samples exhibited intragranular pore volumes of ~1% of the solid volume and intragranular surface areas of ~20%–35% of the total surface area. Analogous experiments using bromide ion as a tracer yielded very different results, suggesting very little penetration of bromide into the intragranular porosity.

Effects of streambank fencing of pasture land on benthic macroinvertebrates and the quality of surface water and shallow ground water in the Big Spring Run basin of Mill Creek watershed, Lancaster County, Pennsylvania, 1993-2001

USGS Publications Warehouse

Galeone, Daniel G.; Brightbill, Robin A.; Low, Dennis J.; O'Brien, David L.

2006-01-01

Streambank fencing along stream channels in pastured areas and the exclusion of pasture animals from the channel are best-management practices designed to reduce nutrient and suspended-sediment yields from drainage basins. Establishment of vegetation in the fenced area helps to stabilize streambanks and provides better habitat for wildlife in and near the stream. This study documented the effectiveness of a 5- to 12-foot-wide buffer strip on the quality of surface water and near-stream ground water in a 1.42-mi2 treatment basin in Lancaster County, Pa. Two miles of stream were fenced in the basin in 1997 following a 3- to 4-year pre-treatment period of monitoring surface- and ground-water variables in the treatment and control basins. Changes in surface- and ground-water quality were monitored for about 4 years after fence installation. To alleviate problems in result interpretation associated with climatic and hydrologic variation over the study period, a nested experimental design including paired-basin and upstream/downstream components was used to study the effects of fencing on surface-water quality and benthic-macroinvertebrate communities. Five surface-water sites, one at the outlet of a 1.77-mi2 control basin (C-1), two sites in the treatment basin (T-3 and T-4) that were above any fence installation, and two sites (one at an upstream tributary site (T-2) and one at the outlet (T-1)) that were treated, were sampled intensively. Low-flow samples were collected at each site (approximately 25-30 per year at each site), and stormflow was sampled with automatic samplers at all sites except T-3. For each site where stormflow was sampled, from 35 to 60 percent of the storm events were sampled over the entire study period. Surface-water sites were sampled for analyses of nutrients, suspended sediment, and fecal streptococcus (only low-flow samples), with field parameters (only low-flow samples) measured during sample collection. Benthic-macroinvertebrate samples were collected in May and September of each year; samples were collected at the outlet of the control and treatment basins and at three upstream sites, two in the treatment basin and one in the control basin. For each benthic-macroinvertebrate sample: Stream riffles and pools were sampled using the kick-net method; habitat was characterized using Rapid Bioassessment Protocols (RBP); water-quality samples were collected for nutrients and suspended sediment; stream field parameters were measured; and multiple biological metrics were calculated. The experimental design to study the effects of fencing on the quality of near-stream shallow ground water involved a nested well approach. Two well nests were in the treatment basin, one each at surface-water sites T-1 and T-2. Within each well nest, the data from one deep well and three shallow wells (no greater than 12 ft deep) were used for regional characterization of ground-water quality. At each site, two of the shallow wells were inside the eventual fence (treated wells); the other shallow well was outside the eventual fence (control well). The wells were sampled monthly, primarily during periods with little to no recharge, for laboratory analysis of nutrients and fecal streptococcus; field parameters of water quality also were measured.

Water reservoir characteristics derivation from pubicly available global elevation data

NASA Astrophysics Data System (ADS)

Van De Giesen, N.; van Bemmelen, C.; Mann, M.; de Ridder, M.; Gupta, V.; Rutten, M.

2017-12-01

In order to assess human impact on the global hydrological cycle, it is imperative to characterize all major man made reservoirs. One important characteristic is the relationship between the surface area of a reservoir and its stored water volume. Surface areas can readily be determined through optical and radar satellite remote sensing. Once the relationship between the surface area of a reservoir and its stored water volume is known, one can determine the stored volumes over time using remotely sensed surface areas. It has been known for some time that this relationship between surface and stored volume shows a very high level of regional consistency [1]. This implies that if one knows this relationship in a certain region, one can predict the same for any nearby reservoir. We have tried to exploit this fact by examining whether one can build virtual dams in the neighborhood of an existing dam to determine the general relationship between surface area and stored volume. We examined twelve reservoirs around the world and found, generally, very good results. Especially in geomorphologically homogeneous areas, the relationships could reliable be extrapolated over space. Even in very heterogeneous areas, the final results were acceptable and much better than generic relationships used so far. Finally, we have examined to what extent it is possible to select virtual dam sites automatically. The first results for this are promising and show that it may be possible to characterize most major dams in the world according to this approach. It is likely that there will be the need for human detection for a reasonable percentage. For these relatively rare case, some human micro-tasking may be the way forward. It is expected, however, that >90% of the worldś dams can be characterized automatically [1] Liebe, J., N. Van De Giesen, and Marc Andreini. "Estimation of small reservoir storage capacities in a semi-arid environment: A case study in the Upper East Region of Ghana." Physics and Chemistry of the Earth, Parts A/B/C 30, no. 6 (2005): 448-454.

The spectroscopic chemical and photophysical properties of Martian soils and their analogs

NASA Technical Reports Server (NTRS)

Coyne, Lelia M.

1987-01-01

The program of research outlined should advance significantly the understanding of the spectral signal of montmorillonites in general and the variations produced in it by structural and surface ferric and ferrous iron and interlayer water as a function of several environmental conditions that are different between Earth and Mars. In addition, an extensive data base was collected providing spectral characterization of several features (iron, both surface and structural, OH-groups, both structural and from adsorbed water and O(-) centers) that are known, or thought to be, influential in directing the surface activity of these important materials. With this data base with which to assess the results of the Viking labeled release simulation studies, it should be possible to gain important insights into the mechanisms of surface reactivity for this important chemical reaction. The results to be gained from these studies will provide a significant body of ground base truth from which to assess: the presence of smectite clays on Mars; the mineralogical form in which the Martian iron is bound; establish upper limits on the present surface water content of Martian soils; perhaps provide insights on the Martian surface radiation history; and to make strong predictions about the nature of surface chemistry on Mars, if iron-bearing clays are a significant component of the surface mineralogical assemblage.

Environmental factors explaining the vegetation patterns in a temperate peatland.

PubMed

Pellerin, Stéphanie; Lagneau, Louis-Adrien; Lavoie, Martin; Larocque, Marie

2009-08-01

Although ombrotrophic temperate peatlands are important ecosystems for maintaining biodiversity in eastern North America, the environmental factors influencing their flora are only partly understood. The relationships between plant species distribution and environmental factors were thus studied within the oldest temperate peatland of Québec. Plant assemblages were identified by cluster analysis while CCA was used to related vegetation gradients to environmental factors. Five assemblages were identified; three typical of open bog and two characterized by more minerotrophic vegetation. Thicker peat deposit was encounter underlying the bog assemblages while higher water table level and percentage of free surface water distinguished the minerotrophic assemblages. Overall, the floristic patterns observed were spatially structured along the margins and the expanse. The most important environmental factors explaining this spatial gradient were the percentage of free surface water and the highest water-table level.

The Water Content of Martian Recurring Slope Lineae: Insights from THEMIS Thermal Infrared Data

NASA Astrophysics Data System (ADS)

Edwards, C. S.; Piqueux, S.

2016-12-01

Observations of Recurring Slope Lineae (RSL) have been interpreted as present-day, seasonally variable liquid water flows; however, orbital spectroscopy has not confirmed the presence of liquid H2O, only hydrated salts. Thermal Emission Imaging System (THEMIS) temperature data and a numerical heat transfer model definitively constrain the amount of water associated with RSL.We examine a well characterized RSL-site in Valles Marineris on the walls of Garni crater, with extensive daytime and nighttime THEMIS coverage. In addition to having been characterized in detail with HiRISE data, this area is suitable for thermal analysis as it displays: 1) limited bedrock outcrops at the origination of the RSL, avoiding anisothermal behaviors with slope materials; 2) high density of RSL terrain versus dry slope material (typically 40% and up to 88% of a THEMIS pixel) maximizing RSL-bearing signal; 3) an extensive areal region, encompassing multiple THEMIS pixels; 4) seasonal THEMIS coverage. Surface temperature differences between RSL-bearing and dry RSL-free terrains are consistent with no water associated with RSL and, based on measurement uncertainties, limit the water content of RSL to at most 0.5-3 wt%. In addition, distinct high thermal inertia regolith signatures expected with evaporitic salt deposits from cyclical briny water flows are not observed, indicating low water salinity (if any), and/or low enough volumes to prevent their formation. Alternatively, the observed salts may be pre-existing in soils at low abundances (i.e. near or below detection limits) and largely immobile. These RSL-rich surfaces experience 100K diurnal temperature oscillations, possible freeze/thaw cycles and/or complete evaporation on timescales that challenge their habitability potential. The unique surface temperature measurements provided by THEMIS are consistent with a dry RSL hypothesis, or at least significantly limit the water content of martian RSL.

Investigation on single walled carbon nanotube thin films deposited by Langmuir Blodgett method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vishalli,, E-mail: vishalli-2008@yahoo.com; Dharamvir, Keya; Kaur, Ramneek

2015-05-15

Langmuir Blodgett is a technique to deposit a homogeneous film with a fine control over thickness and molecular organization. Thin films of functionalized SWCNTs have been prepared by Langmuir Blodgett method. The good surface spreading properties of SWCNTs at air/water interface are indicated by surface pressure-area isotherm and the monolayer formed on water surface is transferred onto the quartz substrate by vertical dipping. A multilayer film is thus obtained in a layer by layer manner. The film is characterized by Atomic Force Microscope (AFM), UV-Vis-NIR spectroscopy and FTIR.AFM shows the surface morphology of the deposited film. UV-Vis-NIR spectroscopy shows themore » characteristic peaks of semiconducting SWCNTs. The uniformity of LB film can be used further in understanding the optical and electrical behavior of these materials.« less

Correlation between surface properties and wettability of multi-scale structured biocompatible surfaces

NASA Astrophysics Data System (ADS)

Gorodzha, S. N.; Surmeneva, M. A.; Prymak, O.; Wittmar, A.; Ulbricht, M.; Epple, M.; Teresov, A.; Koval, N.; Surmenev, R. A.

2015-11-01

The influence of surface properties of radio-frequency (RF) magnetron deposited hydroxyapatite (HA) and Si-containing HA coatings on wettability was studied. The composition and morphology of the coatings fabricated on titanium (Ti) were characterized using atomic force microscopy (AFM) and X-ray diffraction (XRD). The surface wettability was studied using contact angle analysis. Different geometric parameters of acid-etched (AE) and pulse electron beam (PEB)-treated Ti substrates and silicate content in the HA films resulted in the different morphology of the coatings at micro- and nano- length scales. Water contact angles for the HA coated Ti samples were evaluated as a combined effect of micro roughness of the substrate and nano-roughness of the HA films resulting in higher water contact angles compared with acid-etched (AE) or pulse electron beam (PEB) treated Ti substrates.

KSC-98pc1082

NASA Image and Video Library

1998-09-14

Technicians carefully maneuver the Mars Climate Orbiter toward its workstand in the Spacecraft Assembly and Encapsulation Facility-2 (SAEF-2). The Mars Climate Orbiter is heading for Mars where it will primarily support its companion Mars Polar Lander spacecraft, planned for launch on Jan. 3, 1999. After that, the Mars Climate Orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for one Martian year (two Earth years). It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface. The scheduled launch date for the Mars Climate Orbiter is Dec. 10, 1998, on a Boeing Delta II 7425 rocket

KSC-98pc1083

NASA Image and Video Library

1998-09-14

Technicians lower the Mars Climate Orbiter onto its workstand in the Spacecraft Assembly and Encapsulation Facility-2 (SAEF-2). The Mars Climate Orbiter is heading for Mars where it will primarily support its companion Mars Polar Lander spacecraft, planned for launch on Jan. 3, 1999. After that, the Mars Climate Orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for one Martian year (two Earth years). It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface. The scheduled launch date for the Mars Climate Orbiter is Dec. 10, 1998, on a Boeing Delta II 7425 rocket

KSC-98pc1350

NASA Image and Video Library

1998-10-16

In the Spacecraft Assembly and Encapsulation Facility-2 (SAEF-2), the Mars Climate Orbiter is on display for the media. The scheduled launch date for the Mars Climate Orbiter is Dec. 10, 1998, aboard a Boeing Delta II 7425 rocket. The Mars Climate Orbiter is heading for Mars where it will primarily support its companion Mars Polar Lander spacecraft, planned for launch on Jan. 3, 1999. After that, the Mars Climate Orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for one Martian year (two Earth years). It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface

The Mars Climate Orbiter is prepared for a spin test in the SAEF- 2

NASA Technical Reports Server (NTRS)

1998-01-01

In the Spacecraft Assembly and Encapsulation Facility -2 (SAEF- 2), the Mars Climate Orbiter is in place for its spin test. Targeted for launch aboard a Delta II rocket on Dec. 10, 1998, the orbiter is heading for Mars where it will primarily support its companion Mars Polar Lander spacecraft, which is planned for launch on Jan. 3, 1999. The orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for 687 Earth days. It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface.

The Mars Climate Orbiter is prepared for a spin test in the SAEF- 2

NASA Technical Reports Server (NTRS)

1998-01-01

In the Spacecraft Assembly and Encapsulation Facility -2 (SAEF- 2), workers lower the Mars Climate Orbiter into place on the spin test equipment. Targeted for launch aboard a Delta II rocket on Dec. 10, 1998, the orbiter is heading for Mars where it will primarily support its companion Mars Polar Lander spacecraft, which is planned for launch on Jan. 3, 1999. The orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for 687 Earth days. It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface.

KSC-98pc1351

NASA Image and Video Library

1998-10-16

KENNEDY SPACE CENTER, FLA. -- In the Spacecraft Assembly and Encapsulation Facility-2 (SAEF-2), a technician works on the Mars Climate Orbiter which is scheduled to launch on Dec. 10, 1998, aboard a Boeing Delta II rocket. The Mars Climate Orbiter is heading for Mars where it will primarily support its companion Mars Polar Lander spacecraft, planned for launch on Jan. 3, 1999. After that, the Mars Climate Orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for one Martian year (two Earth years). It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface

KSC-98pc1616

NASA Image and Video Library

1998-10-30

KENNEDY SPACE CENTER, FLA. -- On Pad 17A at Cape Canaveral Air Station, cables lift the Delta II rocket into position for launch. Scheduled for launch on Dec. 10, 1998, the rocket is carrying the Mars Climate Orbiter. The orbiter is heading for Mars where it will primarily support its companion Mars Polar Lander spacecraft, which is planned for launch on Jan. 3, 1999. The orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for one Martian year (1.8 Earth years). It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface

KSC-98pc1618

NASA Image and Video Library

1998-10-30

KENNEDY SPACE CENTER, FLA. -- On Pad 17A at Cape Canaveral Air Station, workers on the ground watch as cables lift a Delta II rocket into vertical position. Scheduled for launch on Dec. 10, 1998, the rocket is carrying the Mars Climate Orbiter. The orbiter is heading for Mars where it will primarily support its companion Mars Polar Lander spacecraft, which is planned for launch on Jan. 3, 1999. The orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for one Martian year (1.8 Earth years). It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface

KSC-98pc1617

NASA Image and Video Library

1998-10-30

KENNEDY SPACE CENTER, FLA. -- On Pad 17A at Cape Canaveral Air Station, workers on the gantry watch as cables lift a Delta II rocket into position for launch. Scheduled for launch on Dec. 10, 1998, the rocket is carrying the Mars Climate Orbiter. The orbiter is heading for Mars where it will primarily support its companion Mars Polar Lander spacecraft, which is planned for launch on Jan. 3, 1999. The orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for one Martian year (1.8 Earth years). It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface

KSC-98pc1721

NASA Image and Video Library

1998-11-16

KENNEDY SPACE CENTER, FLA. -- In the Spacecraft Assembly and Encapsulation Facility -2 (SAEF-2), a worker maneuvers the Mars Climate Orbiter, suspended by an overhead crane, to the spin test equipment at lower right. Targeted for launch aboard a Delta II rocket on Dec. 10, 1998, the orbiter is heading for Mars where it will primarily support its companion Mars Polar Lander spacecraft, which is planned for launch on Jan. 3, 1999. The orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for 687 Earth days. It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface

KSC-98pc1720

NASA Image and Video Library

1998-11-16

KENNEDY SPACE CENTER, FLA. -- In the Spacecraft Assembly and Encapsulation Facility -2 (SAEF-2), the Mars Climate Orbiter is lifted from the workstand to move it to another site for a spin test. Targeted for launch aboard a Delta II rocket on Dec. 10, 1998, the orbiter is heading for Mars where it will primarily support its companion Mars Polar Lander spacecraft, which is planned for launch on Jan. 3, 1999. The orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for 687 Earth days. It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface

A technician works on the Mars Climate Orbiter in SAEF-2

NASA Technical Reports Server (NTRS)

1998-01-01

In the Spacecraft Assembly and Encapsulation Facility-2 (SAEF-2), a technician works on the Mars Climate Orbiter which is scheduled to launch on Dec. 10, 1998, aboard a Boeing Delta II rocket. The Mars Climate Orbiter is heading for Mars where it will primarily support its companion Mars Polar Lander spacecraft, planned for launch on Jan. 3, 1999. After that, the Mars Climate Orbiter's instruments will monitor the Martian atmosphere and image the planet's surface on a daily basis for one Martian year (two Earth years). It will observe the appearance and movement of atmospheric dust and water vapor, as well as characterize seasonal changes on the surface. The detailed images of the surface features will provide important clues to the planet's early climate history and give scientists more information about possible liquid water reserves beneath the surface.

Arctic Marine Water Isotope Characteristics: In-situ, Continuous Surface and Water Column Isoscapes (δ18O and δ2H) and Linkages into the Marine Food Web

NASA Astrophysics Data System (ADS)

Welker, J. M.; Klein, E. S.; Collins, E.; Iken, K.; Hopcroft, R. R.; Norcross, B.

2016-12-01

The Arctic is under going rapid and profound sea ice, temperature, food web, ocean current, precipitation and synoptic weather changes. Delineating these changes requires a suite of tools, especially those that have the ability to depict the interactive nature of the marine system. Understanding the marine water isotope cycle is paramount to recognizing the unique isotopic properties of this region and to characterize possibly the reorganization of the Arctic. The Arctic marine water isotope system has been primarily examined with shore-based stations and or episodic station sampling; without continuous surface water sampling in combination with station-specific water column and organismic measurements. New technologies that allow in situ and continuous water isotope measurements (vapor and liquid) and the integration of inorganic and organic water isotope geochemistry provide a means to reveal in more detail the fundamental traits of the Arctic marine water isotope system. In July and August of 2016, we are measuring seawater surface (8 m depth) isotopes (δ18O and δ2H) in-situ and continuously (Picarro CWS system) along a research transect (60oN to 77oN) from the Gulf of Alaska to the Arctic Ocean Basin. These continuous surface water isotope measurements are being combined with periodic water column isotope profiling and corresponding organic δ18O and δ2H measurements of pelagic and benthic organisms (microbes to fish) to depths of up to 2600m. We measured surface seawater δ18O that from -1‰ to -6‰; while seawater profiles followed vertical separation in the water column; possibly reflecting divergent currents of the Arctic. Station based δ18O and δ2H values of surface water did not vary by more than 1‰ δ18O over the course of our 24-36 hour sampling periods. The δ18O and δ2H values of marine organism throughout the water column and by trophic level will be analyzed and a seawater-food web model will be developed in addition to surface and water column isoscapes. Our Arctic marine water isotope cycle research is providing the most detailed depiction ever of the western Arctic and sub-Arctic surface water, water column and marine food web O/H isotope properties. Our findings will provide an important new understanding of the Arctic and the high definition of its water isotope cycle.

Nanobubbles at Hydrophilic Particle-Water Interfaces.

PubMed

Pan, Gang; He, Guangzhi; Zhang, Meiyi; Zhou, Qin; Tyliszczak, Tolek; Tai, Renzhong; Guo, Jinghua; Bi, Lei; Wang, Lei; Zhang, Honggang

2016-11-01

The puzzling persistence of nanobubbles breaks Laplace's law for bubbles, which is of great interest for promising applications in surface processing, H 2 and CO 2 storage, water treatment, and drug delivery. So far, nanobubbles have mostly been reported on hydrophobic planar substrates with atomic flatness. It remains a challenge to quantify nanobubbles on rough and irregular surfaces because of the lack of a characterization technique that can detect both the nanobubble morphology and chemical composition inside individual nanobubble-like objects. Here, by using synchrotron-based scanning transmission soft X-ray microscopy (STXM) with nanometer resolution, we discern nanoscopic gas bubbles of >25 nm with direct in situ proof of O 2 inside the nanobubbles at a hydrophilic particle-water interface under ambient conditions. We find a stable cloud of O 2 nanobubbles at the diatomite particle-water interface hours after oxygen aeration and temperature variation. The in situ technique may be useful for many surface nanobubble-related studies such as material preparation and property manipulation, phase equilibrium, nucleation kinetics, and relationships with chemical composition within the confined nanoscale space. The oxygen nanobubble clouds may be important in modifying particle-water interfaces and offering breakthrough technologies for oxygen delivery in sediment and/or deep water environments.

Natural attenuation in a surface water channel and a coastal aquifer by monitoring presence and removal of indicator bacteria, pathogens and antibiotic resistance gene: model development

NASA Astrophysics Data System (ADS)

Masciopinto, Costantino; Visino, Fabrizio; Luprano, Maria Laura; Levantesi, Caterina; Tandoi, Valter

2015-04-01

The spreading of microbial contamination into the environment, represents a very relevant problem, which leads to an increasing health concern. For this reason, it is important to identify and characterize the extent of natural depuration in water environmental particularly for reducing the presence of faecal contamination indicator bacteria, pathogens and antibiotic resistance genes (ARG). In this study, the presence of the above reported microbial parameters was analyzed in a surface water channel and in a coastal aquifer in southern Italy (Ostuni) southern Italy, both affected by Ostuni municipal treatment plant effluents and by local run-off. Several samples were collected from surface water, flowing in channels, and from wells in our study area. In particular, the water samples were analyzed to detect 7 fecal contamination indicators (E. coli, total coliforms, Clostridium p. spores, somatic coliphages, Enterococci and heterotrophic bacteria), Salmonella spp and the presence of ARGs. The water samples were also tested for chemical constituents. Finally a mathematical model has been developed in order to simulate pathogen migration pathways in the fractured groundwater and corresponding possible mitigation of pathogens in pumping wells.

Extraction, characterization and application of malva nut gum in water treatment.

PubMed

Ho, Y C; Norli, I; Alkarkhi, Abbas F M; Morad, N

2015-06-01

In view of green developments in water treatment, plant-based flocculants have become the focus due to their safety, degradation and renewable properties. In addition, cost and energy-saving processes are preferable. In this study, malva nut gum (MNG), a new plant-based flocculant, and its composite with Fe in water treatment using single mode mixing are demonstrated. The result presents a simplified extraction of the MNG process. MNG has a high molecular weight of 2.3 × 10⁵ kDa and a high negative charge of -58.7 mV. From the results, it is a strong anionic flocculant. Moreover, it is observed to have a branch-like surface structure. Therefore, it conforms to the surface of particles well and exhibits good performance in water treatment. In water treatment, the Fe-MNG composite treats water at pH 3.01 and requires a low concentration of Fe and MNG of 0.08 and 0.06 mg/L, respectively, when added to the system. It is concluded that for a single-stage flocculation process, physico-chemical properties such as molecular weight, charge of polymer, surface morphology, pH, concentration of cation and concentration of biopolymeric flocculant affect the flocculating performance.

Adsorption of methanol, ethanol and water on well-characterized PtSn surface alloys

NASA Astrophysics Data System (ADS)

Panja, Chameli; Saliba, Najat; Koel, Bruce E.

1998-01-01

Adsorption and desorption of methanol (CH 3OH), ethanol (C 2H 5OH) and water on Pt(111) and two, ordered, PtSn alloys has been studied primarily using temperature-programmed desorption (TPD) mass spectroscopy. The two alloys studied were the {p(2 × 2) Sn}/{Pt(111) } and (√3 × √3) R30° {Sn}/{Pt(111) } surface alloys prepared by vapor deposition of Sn on Pt(111), with θSn = 0.25 and 0.33, respectively. All three molecules are weakly bonded and reversibly adsorbed under UHV conditions on all three surfaces, molecularly desorbing during TPD without any decomposition. The two PtSn surface alloys were found to chemisorb both methanol and ethanol slightly more weakly than on the Pt(111) surface. The desorption activation energies measured by TPD, and hence the adsorption energies, of both methanol and ethanol progressively decrease as the surface concentration of Sn increases, compared with Pt(111). The decreased binding energy leads one to expect a lower reactivity for these alcohols on the two alloys. The sticking coefficients and the monolayer coverages of these alcohols on the two alloys were identical to that on Pt(111) at 100 K, independent of the amount of Sn present in the surface layer. Alloying Sn in Pt(111) also slightly weakens the adsorption energy of water. Water clusters are formed even at low coverages on all three surfaces, eventually forming a water bilayer prior to the formation of a condensed ice phase. These results are relevant to a molecular-level explanation for the reactivity of Sn-promoted Pt surfaces that have been used in the electro-oxidation of simple organic molecules.

Temporal and spatial patterns of wetland extent influence variability of surface water connectivity in the Prairie Pothole Region, United States

USGS Publications Warehouse

Vanderhoof, Melanie; Alexander, Laurie C.; Todd, Jason

2016-01-01

Context. Quantifying variability in landscape-scale surface water connectivity can help improve our understanding of the multiple effects of wetlands on downstream waterways. Objectives. We examined how wetland merging and the coalescence of wetlands with streams varied both spatially (among ecoregions) and interannually (from drought to deluge) across parts of the Prairie Pothole Region. Methods. Wetland extent was derived over a time series (1990-2011) using Landsat imagery. Changes in landscape-scale connectivity, generated by the physical coalescence of wetlands with other surface water features, were quantified by fusing static wetland and stream datasets with Landsat-derived wetland extent maps, and related to multiple wetness indices. The usage of Landsat allows for decadal-scale analysis, but limits the types of surface water connections that can be detected. Results. Wetland extent correlated positively with the merging of wetlands and wetlands with streams. Wetness conditions, as defined by drought indices and runoff, were positively correlated with wetland extent, but less consistently correlated with measures of surface water connectivity. The degree of wetland-wetland merging was found to depend less on total wetland area or density, and more on climate conditions, as well as the threshold for how wetland/upland was defined. In contrast, the merging of wetlands with streams was positively correlated with stream density, and inversely related to wetland density. Conclusions. Characterizing the degree of surface water connectivity within the Prairie Pothole Region in North America requires consideration of 1) climate-driven variation in wetness conditions and 2) within-region variation in wetland and stream spatial arrangements.

Changes in optical characteristics of surface microlayers in the Peruvian upwelling region hint to photochemically and microbially-mediated DOM turnover

NASA Astrophysics Data System (ADS)

Engel, A.; Galgani, L.

2016-02-01

The coastal upwelling system off Peru is characterized by high biological activity and associated subsurface oxygen minimum zone, leading to an enhanced emission of atmospheric trace gases. High biological productivity in the water column may promote the establishment of enriched organic surface films, key environments for processes regulating gas fluxes across the water-air interface. During M91 cruise to the Peruvian upwelling, we focused our attention on the composition of the sea-surface microlayer (SML), the oceanic uppermost boundary directly subject to high solar radiation, often enriched in specific organic compounds of biological origin like Chromophoric Dissolved Organic Matter (CDOM) and marine gels. In the SML, the continuous photochemical and microbial recycling of organic matter may strongly influence gas exchange between marine systems and the atmosphere. In order to understand organic matter cycling in surface films, we analyzed SML and underlying water samples in 38 stations determining DOC concentrations, amino acids composition, marine gels, CDOM and bacterial abundance as indicators of photochemical and microbial alteration processes. CDOM composition was characterized by spectral slopes (S) values and Excitation-Emission Matrix fluorescence (EEMs), which allow to track changes in molecular weight (MW) of DOM, and to determine potential DOM sources. Profound changes in spectral slope properties were observed suggesting smaller MW CDOM in the SML compared to underlying water. Microbial and photochemical degradation are likely the main drivers for organic matter cycling in the top layer of the ocean. Consequences on the formation of inorganic and organic species highly relevant for air-sea gas exchange and for climate dynamics will be discussed.

Characterization of Surface-Active Biofilm Protein BslA in Self-Assembling Langmuir Monolayer at the Air-Water Interface.

PubMed

Liu, Wei; Li, Shanghao; Wang, Zhuguang; Yan, Elsa C Y; Leblanc, Roger M

2017-08-01

Biofilm is an extracellular matrix of bacteria and serves as a protective shield of bacterial communities. It is crucial for microbial growth and one of the leading causes of human chronic infections as well. However, the structures and molecular mechanism of biofilm formation remain largely unknown. Here, we examined a protein, BslA, expressed in the biofilms of Bacillus subtilis. We characterized the Langmuir monolayers of BslA at the air/water interface. Using techniques in surface chemistry and spectroscopy, we found that BslA forms a stable and robust Langmuir monolayer at the air/water interface. Our results show that the BslA Langmuir monolayer underwent two-stage elasticity in the solid state phase upon mechanical compression: one is possibly due to the intermolecular interaction and the other is likely due to both the intermolecular compulsion and the intramolecular distortion. The Langmuir monolayer of BslA shows abrupt changes in rigidities and elasticities at ∼25 mN/m. This surface pressure is close to the one at which BlsA saturates the air/water interface as a self-assembled film without mechanical compression, corresponding to a mean molecular area of ∼700 Å 2 per molecule. Based on the results of surface UV-visible spectroscopy and infrared reflective-absorption spectroscopy, we propose that the BslA Langmuir monolayer carries intermolecular elasticity before ∼25 mN/m and both intermolecular and intramolecular elasticity after ∼25 mN/m. These results provide valuable insights into the understanding of biofilm-associated protein under high mechanical force, shedding light on further investigation of biofilm structure and functionalities.

Role of Bacterial Exopolysaccharides (EPS) in the Fate of the Oil Released during the Deepwater Horizon Oil Spill

PubMed Central

Gutierrez, Tony; Berry, David; Yang, Tingting; Mishamandani, Sara; McKay, Luke; Teske, Andreas; Aitken, Michael D.

2013-01-01

Halomonas species are recognized for producing exopolysaccharides (EPS) exhibiting amphiphilic properties that allow these macromolecules to interface with hydrophobic substrates, such as hydrocarbons. There remains a paucity of knowledge, however, on the potential of Halomonas EPS to influence the biodegradation of hydrocarbons. In this study, the well-characterized amphiphilic EPS produced by Halomonas species strain TG39 was shown to effectively increase the solubilization of aromatic hydrocarbons and enhance their biodegradation by an indigenous microbial community from oil-contaminated surface waters collected during the active phase of the Deepwater Horizon oil spill. Three Halomonas strains were isolated from the Deepwater Horizon site, all of which produced EPS with excellent emulsifying qualities and shared high (97-100%) 16S rRNA sequence identity with strain TG39 and other EPS-producing Halomonas strains. Analysis of pyrosequence data from surface water samples collected during the spill revealed several distinct Halomonas phylotypes, of which some shared a high sequence identity (≥97%) to strain TG39 and the Gulf spill isolates. Other bacterial groups comprising members with well-characterized EPS-producing qualities, such as Alteromonas , Colwellia and Pseudoalteromonas , were also found enriched in surface waters, suggesting that the total pool of EPS in the Gulf during the spill may have been supplemented by these organisms. Roller bottle incubations with one of the Halomonas isolates from the Deepwater Horizon spill site demonstrated its ability to effectively produce oil aggregates and emulsify the oil. The enrichment of EPS-producing bacteria during the spill coupled with their capacity to produce amphiphilic EPS is likely to have contributed to the ultimate removal of the oil and to the formation of oil aggregates, which were a dominant feature observed in contaminated surface waters. PMID:23826336

Role of roughness parameters on the tribology of randomly nano-textured silicon surface.

PubMed

Gualtieri, E; Pugno, N; Rota, A; Spagni, A; Lepore, E; Valeri, S

2011-10-01

This experimental work is oriented to give a contribution to the knowledge of the relationship among surface roughness parameters and tribological properties of lubricated surfaces; it is well known that these surface properties are strictly related, but a complete comprehension of such correlations is still far to be reached. For this purpose, a mechanical polishing procedure was optimized in order to induce different, but well controlled, morphologies on Si(100) surfaces. The use of different abrasive papers and slurries enabled the formation of a wide spectrum of topographical irregularities (from the submicro- to the nano-scale) and a broad range of surface profiles. An AFM-based morphological and topographical campaign was carried out to characterize each silicon rough surface through a set of parameters. Samples were subsequently water lubricated and tribologically characterized through ball-on-disk tribometer measurements. Indeed, the wettability of each surface was investigated by measuring the water droplet contact angle, that revealed a hydrophilic character for all the surfaces, even if no clear correlation with roughness emerged. Nevertheless, this observation brings input to the purpose, as it allows to exclude that the differences in surface profile affect lubrication. So it is possible to link the dynamic friction coefficient of rough Si samples exclusively to the opportune set of surface roughness parameters that can exhaustively describe both height amplitude variations (Ra, Rdq) and profile periodicity (Rsk, Rku, Ic) that influence asperity-asperity interactions and hydrodynamic lift in different ways. For this main reason they cannot be treated separately, but with dependent approach through which it was possible to explain even counter intuitive results: the unexpected decreasing of friction coefficient with increasing Ra is justifiable by a more consistent increasing of kurtosis Rku.

Seasonal Variability in Mercury Speciation within Select Coastal Lagoons of Central California

NASA Astrophysics Data System (ADS)

Ganguli, P. M.; Conaway, C. H.; Dimova, N. T.; Swarzenski, P. W.; Kehrlein, N. C.; Flegal, A. R.

2011-12-01

Coastal lagoons may play an important role in mercury biogeochemical cycling at the land-sea margin. Along the coast of California, these systems are seasonally dynamic, behaving as estuaries during the wet season and as lagoons in the dry season when ephemeral sand berms develop and isolate terrestrial freshwater from direct exchange with the ocean. As a consequence, many lagoons become eutrophic in the dry season and are characterized by high nutrient and low dissolved oxygen concentrations. Because monomethylmercury (MMHg) production can be mediated by anaerobic bacteria, coastal lagoons are a potential source of biologically available MMHg that may be transported to the nearshore environment via submarine groundwater discharge. To evaluate the importance of coastal lagoons at the land-sea margin, we quantified total mercury (HgT) and MMHg concentrations in surface water and coastal seawater from six sites during dry and wet season conditions, including one storm event. Additionally, we conducted a tidal study at one lagoon in which we sampled surface water, seawater, and groundwater over a 10-hour period during a falling tide (+1.63 to 0.00 m). Groundwater was collected using a multi-port piezometer screened at depths ranging from 1 m to a few centimeters below the lagoon's sediment-water interface. This enabled us to characterize surface water - groundwater interaction. During wet season conditions, the average unfiltered HgT (U-HgT) concentration in surface water at the tidal study lagoon was 13 pM and did not fluctuate in response to tidal changes. Filtered (< 0.45 μm) HgT (F-HgT) concentrations in the lagoon were similar to U-HgT concentrations during high tide and decreased to 8 pM during low tide. Groundwater F-HgT concentrations were about 1.5 pM at a depth of 1 m and systematically increased at shallower depths, reaching approximately 6 pM near the surface. These data indicate F-HgT exchange between the lagoon and groundwater to a depth of at least 1 m. Seawater HgT was typically < 5 pM. MMHg concentrations in surface water at this lagoon during the dry season ranged from 2 to 5 pM, suggesting enhanced methylmercury production.

Laccase-Catalyzed Surface Modification of Thermo-Mechanical Pulp (TMP) for the Production of Wood Fiber Insulation Boards Using Industrial Process Water

PubMed Central

Schubert, Mark; Ruedin, Pascal; Civardi, Chiara; Richter, Michael; Hach, André; Christen, Herbert

2015-01-01

Low-density wood fiber insulation boards are traditionally manufactured in a wet process using a closed water circuit (process water). The water of these industrial processes contains natural phenolic extractives, aside from small amounts of admixtures (e.g., binders and paraffin). The suitability of two fungal laccases and one bacterial laccase was determined by biochemical characterization considering stability and substrate spectra. In a series of laboratory scale experiments, the selected commercial laccase from Myceliophtora thermophila was used to catalyze the surface modification of thermo-mechanical pulp (TMP) using process water. The laccase catalyzed the covalent binding of the phenolic compounds of the process water onto the wood fiber surface and led to change of the surface chemistry directly via crosslinking of lignin moieties. Although a complete substitution of the binder was not accomplished by laccase, the combined use of laccase and latex significantly improved the mechanical strength properties of wood fiber boards. The enzymatically-treated TMP showed better interactions with the synthetic binder, as shown by FTIR-analysis. Moreover, the enzyme is extensively stable in the process water and the approach requires no fresh water as well as no cost-intensive mediator. By applying a second-order polynomial model in combination with the genetic algorithm (GA), the required amount of laccase and synthetic latex could be optimized enabling the reduction of the binder by 40%. PMID:26046652

Protein-functionalized magnetic iron oxide nanoparticles: time efficient potential-water treatment

NASA Astrophysics Data System (ADS)

Okoli, Chuka; Boutonnet, Magali; Järås, Sven; Rajarao-Kuttuva, Gunaratna

2012-10-01

Recent advances in nanoscience suggest that the existing issues involving water quality could be resolved or greatly improved using nanomaterials, especially magnetic iron oxide nanoparticles. Magnetic nanoparticles have been synthesized for the development and use, in association with natural coagulant protein for water treatment. The nanoparticles size, morphology, structure, and magnetic properties were characterized by transmission electron microscope, X-ray diffraction, and superconducting quantum interference device magnetometry. Purified Moringa oleifera protein was attached onto microemulsions-prepared magnetic iron oxide nanoparticles (ME-MION) to form stable protein-functionalized magnetic nanoparticles (PMO+ME-MION). The turbidity removal efficiency in both synthetic and surface water samples were investigated and compared with the commonly used synthetic coagulant (alum) as well as PMO. More than 90 % turbidity could be removed from the surface waters within 12 min by magnetic separation of PMO+ME-MION; whereas gravimetrically, 70 % removal in high and low turbid waters can be achieved within 60 min. In contrast, alum requires 180 min to reduce the turbidity of low turbid water sample. These data support the advantage of separation with external magnetic field (magnetophoresis) over gravitational force. Time kinetics studies show a significant enhancement in ME-MION efficiency after binding with PMO implying the availability of large surface of the ME-MION. The coagulated particles (impurities) can be removed from PMO+ME-MION by washing with mild detergent or cleaning solution. To our knowledge, this is the first report on surface water turbidity removal using protein-functionalized magnetic nanoparticle.

Cadmium cycling in the water column of the Kuroshio-Oyashio Extension region: Insights from dissolved and particulate isotopic composition

NASA Astrophysics Data System (ADS)

Yang, Shun-Chung; Zhang, Jing; Sohrin, Yoshiki; Ho, Tung-Yuan

2018-07-01

We measured dissolved and particulate Cd isotopic composition in the water column of a meridional transect across the Kuroshio-Oyashio Extension region in a Japanese GEOTRACES cruise to investigate the relative influence of physical and biogeochemical processes on Cd cycling in the Northwestern Pacific Ocean. Located at 30-50°N along 165°E, the transect across the extension region possesses dramatic hydrographic contrast. Cold surface water and a relatively narrow and shallow thermocline characterizes the Oyashio Extension region in contrast to a relatively warm and highly stratified surface water and thermocline in the Kuroshio Extension region. The contrasting hydrographic distinction at the study site provides us with an ideal platform to investigate the spatial variations of Cd isotope fractionation systems in the ocean. Particulate samples demonstrated biologically preferential uptake of light Cd isotopes, and the fractionation effect varied dramatically in the surface water of the two regions, with relatively large fractionation factors in the Oyashio region. Based on the relationship of dissolved Cd concentrations and isotopic composition, we found that a closed system fractionation model can reasonably explain the relationship in the Kuroshio region. However, using dissolved Cd isotopic data, either a closed system or steady-state open system fractionation model may explain the relationship in the surface water of the Oyashio region. Particulate δ114/110Cd data further supports that the surface water of the Oyashio region matches a steady-state open system model more closely. Contrary to the surface water, the distribution of potential density exhibits comparable patterns with Cd elemental and isotopic composition in the thermocline and deep water in the two extension regions, showing that physical processes are the dominant forcing controlling Cd cycling in the deep waters. The results demonstrate that Cd isotope fractionation can match either a closed or open system Rayleigh fractionation model, depending on the relative contribution of physical and biogeochemical processes on its cycling.

Surface- and ground-water relations on the Portneuf river, and temporal changes in ground-water levels in the Portneuf Valley, Caribou and Bannock Counties, Idaho, 2001-02

USGS Publications Warehouse

Barton, Gary J.

2004-01-01

The State of Idaho and local water users are concerned that streamflow depletion in the Portneuf River in Caribou and Bannock Counties is linked to ground-water withdrawals for irrigated agriculture. A year-long field study during 2001 02 that focused on monitoring surface- and ground-water relations was conducted, in cooperation with the Idaho Department of Water Resources, to address some of the water-user concerns. The study area comprised a 10.2-mile reach of the Portneuf River downstream from the Chesterfield Reservoir in the broad Portneuf Valley (Portneuf River Valley reach) and a 20-mile reach of the Portneuf River in a narrow valley downstream from the Portneuf Valley (Pebble-Topaz reach). During the field study, the surface- and ground-water relations were dynamic. A losing river reach was delineated in the middle of the Portneuf River Valley reach, centered approximately 7.2 miles downstream from Chesterfield Reservoir. Two seepage studies conducted in the Portneuf Valley during regulated high flows showed that the length of the losing river reach increased from 2.6 to nearly 6 miles as the irrigation season progressed.Surface- and ground-water relations in the Portneuf Valley also were characterized from an analysis of specific conductance and temperature measurements. In a gaining reach, stratification of specific conductance and temperature across the channel of the Portneuf River was an indicator of ground water seeping into the river.An evolving method of using heat as a tracer to monitor surface- and ground-water relations was successfully conducted with thermistor arrays at four locations. Heat tracing monitored a gaining reach, where ground water was seeping into the river, and monitored a losing reach, where surface water was seeping down through the riverbed (also referred to as a conveyance loss), at two locations.Conveyance losses in the Portneuf River Valley reach were greatest, about 20 cubic feet per second, during the mid-summer regulated high flows. Conveyance losses in the Pebble-Topaz reach were greatest, about 283 cubic feet per second, during the spring regulated high flows and were attributed to a hydroelectric project.Comparison of water levels in 30 wells in the Portneuf Valley during September and October 1968 and 2001 indicated long-term declines since 1968; the median decline was 3.4 feet. September and October were selected for characterizing long-term ground-water-level fluctuations because declines associated with irrigation reach a maximum at the end of the irrigation season. The average annual snowpack in the study area has declined significantly; 1945 85 average annual snowpack was 16.1 inches, whereas 1986 through 2002 average annual snowpack was 11.6 inches. Water-level declines during 1998 2002 may be partially attributable to the extended dry climatic conditions. It is unclear whether the declines could be partially attributed to increases in ground-water withdrawals. Between 1968 and 1980, water rights for ground-water withdrawals nearly doubled from 23,500 to 46,000 acre-feet per year. During this period, ground-water levels were relatively constant and did not exhibit a declining trend that could be related to increased ground-water withdrawal rights. However, ground-water withdrawals are not measured in the valley; thus, the amount of water pumped is not known. Since the 1990s, there have been several years when the Chesterfield Reservoir has not completely refilled, and the water in storage behind the reservoir has been depleted by the middle of the irrigation season. In this situation, surface-water diversions for irrigation were terminated before the end of the irrigation season, and irrigators, who were relying in part on diversions from the Portneuf River, had to rely solely on ground water as an alternate supply. Smaller volumes of water in the Chesterfield Reservoir since the 1990s indicate a growing demand for ground-water supplies.

Surface-groundwater interactions in hard rocks in Sardon Catchment of western Spain: An integrated modeling approach

NASA Astrophysics Data System (ADS)

Hassan, S. M. Tanvir; Lubczynski, Maciek W.; Niswonger, Richard G.; Su, Zhongbo

2014-09-01

The structural and hydrological complexity of hard rock systems (HRSs) affects dynamics of surface-groundwater interactions. These complexities are not well described or understood by hydrogeologists because simplified analyses typically are used to study HRSs. A transient, integrated hydrologic model (IHM) GSFLOW (Groundwater and Surface water FLOW) was calibrated and post-audited using 18 years of daily groundwater head and stream discharge data to evaluate the surface-groundwater interactions in semi-arid, ∼80 km2 granitic Sardon hilly catchment in Spain characterized by shallow water table conditions, relatively low storage, dense drainage networks and frequent, high intensity rainfall. The following hydrological observations for the Sardon Catchment, and more generally for HRSs were made: (i) significant bi-directional vertical flows occur between surface water and groundwater throughout the HRSs; (ii) relatively large groundwater recharge represents 16% of precipitation (P, 562 mm.y-1) and large groundwater exfiltration (∼11% of P) results in short groundwater flow paths due to a dense network of streams, low permeability and hilly topographic relief; deep, long groundwater flow paths constitute a smaller component of the water budget (∼1% of P); quite high groundwater evapotranspiration (∼5% of P and ∼7% of total evapotranspiration); low permeability and shallow soils are the main reasons for relatively large components of Hortonian flow and interflow (15% and 11% of P, respectively); (iii) the majority of drainage from the catchment leaves as surface water; (iv) declining 18 years trend (4.44 mm.y-1) of groundwater storage; and (v) large spatio-temporal variability of water fluxes. This IHM study of HRSs provides greater understanding of these relatively unknown hydrologic systems that are widespread throughout the world and are important for water resources in many regions.

The Role of Global Hydrologic Processes in Interannual and Long-Term Climate Variability

NASA Technical Reports Server (NTRS)

Robertson, Franklin R.

1997-01-01

The earth's climate and its variability is linked inextricably with the presence of water on our planet. El Nino / Southern Oscillation-- the major mode of interannual variability-- is characterized by strong perturbations in oceanic evaporation, tropical rainfall, and radiation. On longer time scales, the major feedback mechanism in CO2-induced global warming is actually that due to increased water vapor holding capacity of the atmosphere. The global hydrologic cycle effects on climate are manifested through influence of cloud and water vapor on energy fluxes at the top of atmosphere and at the surface. Surface moisture anomalies retain the "memory" of past precipitation anomalies and subsequently alter the partitioning of latent and sensible heat fluxes at the surface. At the top of atmosphere, water vapor and cloud perturbations alter the net amount of radiation that the earth's climate system receives. These pervasive linkages between water, radiation, and surface processes present major complexities for observing and modeling climate variations. Major uncertainties in the observations include vertical structure of clouds and water vapor, surface energy balance, and transport of water and heat by wind fields. Modeling climate variability and change on a physical basis requires accurate by simplified submodels of radiation, cloud formation, radiative exchange, surface biophysics, and oceanic energy flux. In the past, we m safely say that being "data poor' has limited our depth of understanding and impeded model validation and improvement. Beginning with pre-EOS data sets, many of these barriers are being removed. EOS platforms with the suite of measurements dedicated to specific science questions are part of our most cost effective path to improved understanding and predictive capability. This talk will highlight some of the major questions confronting global hydrology and the prospects for significant progress afforded by EOS-era measurements.

Delineation and Characterization of Furnace Brook Watershed in Marshfield, Massachusetts: A Study of Effects upon Conjunctive Water Use within a Watershed

NASA Astrophysics Data System (ADS)

Croll, E. D.; Enright, R.

2012-12-01

An understanding of conjunctive use between surface and ground water is essential to resource management both for sustained public use and watershed conservation practices. The Furnace Brook watershed in Marshfield, Massachusetts supplies a coastal community of 25,132 residents with nearly 50% of the town water supply. As with many other coastal communities, development pressure has increased creating a growing demand for freshwater extraction. It has been observed, however, that portions of the stream and Furnace Pond disappear entirely. This has created a conflict between protection of the designated wetland areas and meeting public pressure for water resources, even within what is traditionally viewed as a humid region. Questions have arisen as to whether the town water extraction is influencing this losing behavior by excessively lowering water-table elevations and potentially endangering the health of the stream. This study set out to initially characterize these behaviors and identify possible influences of anthropogenic and natural sources acting upon the watershed including stream flow obstructions, water extraction, and geologic conditions. The initial characterization was conducted utilizing simple, low-cost and minimally intrusive methods as outlined by Lee and Cherry (1978), Rosenberry and LaBaugh (2008) and others during a six week period. Five monitoring stations were established along a 3.0 mile reach of the basin consisting of mini-piezometers, seepage meters, survey elevation base-lines, and utilizing a Marsh-McBirney flow velocity meter. At each station stream discharge, seepage flux rates and hydraulic gradients were determined to develop trends of stream behavior. This methodology had the benefit of demonstrating the efficacy of an intrinsically low-expense, minimally intrusive initial approach to characterizing interactions between surface and ground water resources. The data was correlated with town pumping information, previous geologic surveys and meteorological data. Early data analysis indicated that the stream behaved in an anomalous manner decreasing in discharge with downstream flow despite normal precipitation inputs. The behavior within this particular watershed appeared to be influenced by four primary factors resulting in the stream "running dry" during the June-August period. These factors included: (1) A losing gradient induced by well pumping (2) Obstructions to stream flow reduced contribution from upper reaches to lower reaches (3) A highly anisotropic layer of lower conductivity material regulated infiltration rates and (4) Evapotranspiration effects are such that during this period the basin is in a deficit situation even without additional losses. Additionally, relationships between well pumping and decreasing discharge, seepage flux loss rates and hydraulic gradients have demonstrated that even within humid region watersheds it cannot be assumed aquifer recharge is sufficient to avoid conflict between surface water protection and ground water utilization. Timing of precipitation events combined with geological governance of aquifer recharge play critical roles in managing the conjunctive use of water resources and cannot be assumed to have a negligible effect, even within relatively humid regions.

Geochemistry of the Birch Creek Drainage Basin, Idaho

USGS Publications Warehouse

Swanson, Shawn A.; Rosentreter, Jeffrey J.; Bartholomay, Roy C.; Knobel, LeRoy L.

2003-01-01

The U.S. Survey and Idaho State University, in cooperation with the U.S. Department of Energy, are conducting studies to describe the chemical character of ground water that moves as underflow from drainage basins into the eastern Snake River Plain aquifer (ESRPA) system at and near the Idaho National Engineering and Environmental Laboratory (INEEL) and the effects of these recharge waters on the geochemistry of the ESRPA system. Each of these recharge waters has a hydrochemical character related to geochemical processes, especially water-rock interactions, that occur during migration to the ESRPA. Results of these studies will benefit ongoing and planned geochemical modeling of the ESRPA at the INEEL by providing model input on the hydrochemical character of water from each drainage basin. During 2000, water samples were collected from five wells and one surface-water site in the Birch Creek drainage basin and analyzed for selected inorganic constituents, nutrients, dissolved organic carbon, tritium, measurements of gross alpha and beta radioactivity, and stable isotopes. Four duplicate samples also were collected for quality assurance. Results, which include analyses of samples previously collected from four other sites, in the basin, show that most water from the Birch Creek drainage basin has a calcium-magnesium bicarbonate character. The Birch Creek Valley can be divided roughly into three hydrologic areas. In the northern part, ground water is forced to the surface by a basalt barrier and the sampling sites were either surface water or shallow wells. Water chemistry in this area was characterized by simple evaporation models, simple calcite-carbon dioxide models, or complex models involving carbonate and silicate minerals. The central part of the valley is filled by sedimentary material and the sampling sites were wells that are deeper than those in the northern part. Water chemistry in this area was characterized by simple calcite-dolomite-carbon dioxide models. In the southern part, ground water enters the ESRPA. In this area, the sampling sites were wells with depths and water levels much deeper than those in the northern and central parts of the valley. The calcium and carbon water chemistry in this area was characterized by a simple calcite-carbon dioxide model, but complex calcite-silicate models more accurately accounted for mass transfer in these areas. Throughout the geochemical system, calcite precipitated if it was an active phase in the models. Carbon dioxide either precipitated (outgassed) or dissolved depending on the partial pressure of carbon dioxide in water from the modeled sites. Dolomite was an active phase only in models from the central part of the system. Generally the entire geochemical system could be modeled with either evaporative models, carbonate models, or carbonate-silicate models. In both of the latter types of models, a significant amount of calcite precipitated relative to the mass transfer to and from the other active phases. The amount of calcite precipitated in the more complex models was consistent with the amount of calcite precipitated in the simpler models. This consistency suggests that, although the simpler models can predict calcium and carbon concentrations in Birch Creek Valley ground and surface water, silicate-mineral-based models are required to account for the other constituents. The amount of mass transfer to and from the silicate mineral phases was generally small compared with that in the carbonate phases. It appears that the water chemistry of well USGS 126B represents the chemistry of water recharging the ESRPA by means of underflow from the Birch Creek Valley.

A Multi-Index Approach to Delineate Surface Water Bodies in the Pastoral Regions of Mali Using ASTER Imagery

NASA Astrophysics Data System (ADS)

Alemu, H.; Velpuri, N.; Senay, G. B.; Angerer, J.

2011-12-01

Information on the location and availability of water resources is a day-to-day challenge for pastoralists in the Sahelian region of Mali. They move seasonally along their migration corridors in search for water and forage. Satellite data can be used to map the spatial and temporal dynamics of these water resources. In this work, ASTER imagery is selected for its high (15 m) spatial resolution and suitable spectral bands for water body identification. Our research indicates that as most of the waterholes of interest in the study area are very shallow and heavily sediment-laden, using only one of those commonly used water identification indices such as the Simple Band Ratio (SBR), or the Normalized Difference Water Index (NDWI) alone does not help in effectively characterizing all the surface water bodies in the region. As a result, we used four different spectral indices to identify surface water features: (i) Simple Band Ratio (SBR), (ii) Normalized Difference Water Index (NDWI), (iii) Modified Normalized Difference Water Index (MNDWI), and (iv) the Mean Absolute Deviation (MAD) to identify and delineate surface water bodies using 91 ASTER images. Initial results indicate that the SBR method identified 17 waterholes while the NDWI 18, the MNDWI 36, and the MAD method identified 28 waterholes. However, by combining the results from the four aforementioned spectral indices following a multi-index approach, 89 waterholes that were previously unidentified by a single approach alone were identified. Furthermore, our analysis indicates that the SBR and the NDWI methods identify relatively clearer waterholes better (29% of the waterholes), whereas MNDWI and MAD proved to be good indices for identifying sediment-laden waterholes. Identifying the location and spatial distribution of surface water bodies is the first step towards monitoring their seasonal dynamics using a hydrologic modeling system, similar to an existing setup for east Africa (http://watermon.tamu.edu/). Seasonal trends in relative surface water levels are one of the most important inputs in the livestock early warning system (LEWS) along with forage and livestock market prices.

Soil moisture sensing via swept frequency based microwave sensors

USDA-ARS?s Scientific Manuscript database

Accurate measurement of moisture content is a prime requirement in hydrological, geophysical, and biogeochemical research as well as for material characterization, process control, and irrigation efficiency in water limited regions. Within these areas, consideration of the surface area and associate...

Characterizing the Connectivity and Cumulative Effects of Wetlands on Downstream Hydrology: A Modeling Analysis

EPA Science Inventory

Geographically isolated wetlands (GIWs) are depressional landscape features entirely surrounded by uplands. While “GIW” may imply functional isolation from other surface waters, these systems exhibit a gradient of hydrologic, biological, and/or chemical connectivity. ...

Remote sensing based water-use efficiency evaluation in sub-surface irrigated wine grape vines

NASA Astrophysics Data System (ADS)

Zúñiga, Carlos Espinoza; Khot, Lav R.; Jacoby, Pete; Sankaran, Sindhuja

2016-05-01

Increased water demands have forced agriculture industry to investigate better irrigation management strategies in crop production. Efficient irrigation systems, improved irrigation scheduling, and selection of crop varieties with better water-use efficiencies can aid towards conserving water. In an ongoing experiment carried on in Red Mountain American Viticulture area near Benton City, Washington, subsurface drip irrigation treatments at 30, 60 and 90 cm depth, and 15, 30 and 60% irrigation were applied to satisfy evapotranspiration demand using pulse and continuous irrigation. These treatments were compared to continuous surface irrigation applied at 100% evapotranspiration demand. Thermal infrared and multispectral images were acquired using unmanned aerial vehicle during the growing season. Obtained results indicated no difference in yield among treatments (p<0.05), however there was statistical difference in leaf temperature comparing surface and subsurface irrigation (p<0.05). Normalized vegetation index obtained from the analysis of multispectral images showed statistical difference among treatments when surface and subsurface irrigation methods were compared. Similar differences in vegetation index values were observed, when irrigation rates were compared. Obtained results show the applicability of aerial thermal infrared and multispectral images to characterize plant responses to different irrigation treatments and use of such information in irrigation scheduling or high-throughput selection of water-use efficient crop varieties in plant breeding.

Quantifying Surface Water Dynamics at 30 Meter Spatial Resolution in the North American High Northern Latitudes 1991-2011

NASA Technical Reports Server (NTRS)

Carroll, Mark; Wooten, Margaret; DiMiceli, Charlene; Sohlberg, Robert; Kelly, Maureen

2016-01-01

The availability of a dense time series of satellite observations at moderate (30 m) spatial resolution is enabling unprecedented opportunities for understanding ecosystems around the world. A time series of data from Landsat was used to generate a series of three maps at decadal time step to show how surface water has changed from 1991 to 2011 in the high northern latitudes of North America. Previous attempts to characterize the change in surface water in this region have been limited in either spatial or temporal resolution, or both. This series of maps was generated for the NASA Arctic and Boreal Vulnerability Experiment (ABoVE), which began in fall 2015. These maps show a nominal extent of surface water by using multiple observations to make a single map for each time step. This increases the confidence that any detected changes are related to climate or ecosystem changes not simply caused by short duration weather events such as flood or drought. The methods and comparison to other contemporary maps of the region are presented here. Initial verification results indicate 96% producer accuracy and 54% user accuracy when compared to 2-m resolution World View-2 data. All water bodies that were omitted were one Landsat pixel or smaller, hence below detection limits of the instrument.

An in situ XPS study of L-cysteine co-adsorbed with water on polycrystalline copper and gold

NASA Astrophysics Data System (ADS)

Jürgensen, Astrid; Raschke, Hannes; Esser, Norbert; Hergenröder, Roland

2018-03-01

The interactions of biomolecules with metal surfaces are important because an adsorbed layer of such molecules introduces complex reactive functionality to the substrate. However, studying these interactions is challenging: they usually take place in an aqueous environment, and the structure of the first few monolayers on the surface is of particular interest, as these layers determine most interfacial properties. Ideally, this requires surface sensitive analysis methods that are operated under ambient conditions, for example ambient pressure x-ray photoelectron spectroscopy (AP-XPS). This paper focuses on an AP-XPS study of the interaction of water vapour and l-Cysteine on polycrystalline copper and gold surfaces. Thin films of l-Cysteine were characterized with XPS in UHV and in a water vapour atmosphere (P ≤ 1 mbar): the structure of the adsorbed l-Cysteine layer depended on substrate material and deposition method, and exposure of the surface to water vapour led to the formation of hydrogen bonds between H2O molecules and the COO- and NH2 groups of adsorbed l-Cysteine zwitterions and neutral molecules, respectively. This study also proved that it is possible to investigate monolayers of biomolecules in a gas atmosphere with AP-XPS using a conventional laboratory Al-Kα x-ray source.

Evaluating the reliability of the stream tracer approach to characterize stream-subsurface water exchange

USGS Publications Warehouse

Harvey, Judson W.; Wagner, Brian J.; Bencala, Kenneth E.

1996-01-01

Stream water was locally recharged into shallow groundwater flow paths that returned to the stream (hyporheic exchange) in St. Kevin Gulch, a Rocky Mountain stream in Colorado contaminated by acid mine drainage. Two approaches were used to characterize hyporheic exchange: sub-reach-scale measurement of hydraulic heads and hydraulic conductivity to compute streambed fluxes (hydrometric approach) and reachscale modeling of in-stream solute tracer injections to determine characteristic length and timescales of exchange with storage zones (stream tracer approach). Subsurface data were the standard of comparison used to evaluate the reliability of the stream tracer approach to characterize hyporheic exchange. The reach-averaged hyporheic exchange flux (1.5 mL s−1 m−1), determined by hydrometric methods, was largest when stream base flow was low (10 L s−1); hyporheic exchange persisted when base flow was 10-fold higher, decreasing by approximately 30%. Reliability of the stream tracer approach to detect hyporheic exchange was assessed using first-order uncertainty analysis that considered model parameter sensitivity. The stream tracer approach did not reliably characterize hyporheic exchange at high base flow: the model was apparently more sensitive to exchange with surface water storage zones than with the hyporheic zone. At low base flow the stream tracer approach reliably characterized exchange between the stream and gravel streambed (timescale of hours) but was relatively insensitive to slower exchange with deeper alluvium (timescale of tens of hours) that was detected by subsurface measurements. The stream tracer approach was therefore not equally sensitive to all timescales of hyporheic exchange. We conclude that while the stream tracer approach is an efficient means to characterize surface-subsurface exchange, future studies will need to more routinely consider decreasing sensitivities of tracer methods at higher base flow and a potential bias toward characterizing only a fast component of hyporheic exchange. Stream tracer models with multiple rate constants to consider both fast exchange with streambed gravel and slower exchange with deeper alluvium appear to be warranted.

Fast Transport of Water Droplets over a Thermo-Switchable Surface Using Rewritable Wettability Gradient.

PubMed

Banuprasad, Theneyur Narayanaswamy; Vinay, Thamarasseril Vijayan; Subash, Cherumannil Karumuthil; Varghese, Soney; George, Sajan D; Varanakkottu, Subramanyan Namboodiri

2017-08-23

In spite of the reported temperature dependent tunability in wettability of poly(N-isopropylacrylamide) (PNIPAAm) surfaces for below and above lower critical solution temperature (32 °C), the transport of water droplets is inhibited by the large contact angle hysteresis. Herein, for the first time, we report on-demand, fast, and reconfigurable droplet manipulation over a PNIPAAm grafted structured polymer surface using temperature-induced wettability gradient. Our study reveals that the PNIPAAm grafted on intrinsically superhydrophobic surfaces exhibit hydrophilic nature with high contact angle hysteresis below 30 °C and superhydrophobic nature with ultralow contact angle hysteresis above 36 °C. The transition region between 30 and 36 °C is characterized by a large change in water contact angle (∼100°) with a concomitant change in contact angle hysteresis. By utilizing this "transport zone" wherein driving forces overcome the frictional forces, we demonstrate macroscopic transport of water drops with a maximum transport velocity of approximately 40 cm/s. The theoretical calculations on the force measurements concur with dominating behavior of driving forces across the transport zone. The tunability in transport velocity by varying the temperature gradient along the surface or the inclination angle of the surface (maximum angle of 15° with a reduced velocity 0.4 mm/s) is also elucidated. In addition, as a practical application, coalescence of water droplets is demonstrated by using the temperature controlled wettability gradient. The presented results are expected to provide new insights on the design and fabrication of smart multifunctional surfaces for applications such as biochemical analysis, self-cleaning, and microfluidics.

Tunable Physical Properties of Ethylcellulose/Gelatin Composite Nanofibers by Electrospinning.

PubMed

Liu, Yuyu; Deng, Lingli; Zhang, Cen; Feng, Fengqin; Zhang, Hui

2018-02-28

In this work, the ethylcellulose/gelatin blends at various weight ratios in water/ethanol/acetic acid solution were electrospun to fabricate nanofibers with tunable physical properties. The solution compatibility was predicted based on Hansen solubility parameters and evaluated by rheological measurements. The physical properties were characterized by scanning electron microscopy, porosity, differential scanning calorimetry, thermogravimetry, Fourier transform infrared spectroscopy, and water contact angle. Results showed that the entangled structures among ethylcellulose and gelatin chains through hydrogen bonds gave rise to a fine morphology of the composite fibers with improved thermal stability. The fibers with higher gelatin ratio (75%), possessed hydrophilic surface (water contact angle of 53.5°), and adequate water uptake ability (1234.14%), while the fibers with higher ethylcellulose proportion (75%) tended to be highly water stable with a hydrophobic surface (water contact angle of 129.7°). This work suggested that the composite ethylcellulose/gelatin nanofibers with tunable physical properties have potentials as materials for bioactive encapsulation, food packaging, and filtration applications.

Occurrence and fate of pharmaceutical products and by-products, from resource to drinking water.

PubMed

Mompelat, S; Le Bot, B; Thomas, O

2009-07-01

Among all emerging substances in water, pharmaceutical products (PPs) and residues are a lot of concern. These last two years, the number of studies has increased drastically, however much less for water resources and drinking water than for wastewater. This literature review based on recent works, deals with water resources (surface or groundwater), focusing on characteristics, occurrence and fate of numerous PPs studied, and drinking water including water quality. Through this review, it appears that the pharmaceutical risk must be considered even in drinking water where concentrations are very low. Moreover, there is a lack of research for by-products (metabolites and transformation products) characterization, occurrence and fate in all water types and especially in drinking water.

Thermal Characteristics of ThermoBrachytherapy Surface Applicators (TBSA) for Treating Chestwall Recurrence

PubMed Central

Arunachalam, K.; Maccarini, P. F.; Craciunescu, O. I.; Schlorff, J. L.; Stauffer, P. R.

2010-01-01

Purpose To study temperature and thermal dose distributions of ThermoBrachytherapy Surface Applicators (TBSA) developed for concurrent or sequential high dose rate (HDR) brachytherapy and microwave hyperthermia treatment of chest wall recurrence and other superficial disease. Methods A steady state thermodynamics model coupled with the fluid dynamics of water bolus and electromagnetic radiation of hyperthermia applicator is used to characterize the temperature distributions achievable with TBSA applicators in an elliptical phantom model of the human torso. Power deposited by 915 MHz conformal microwave array (CMA) applicators is used to assess the specific absorption rate (SAR) distributions of rectangular (500 cm2) and L-shaped (875 cm2) TBSA. The SAR distribution in tissue and fluid flow distribution inside the Dual-Input Dual-Output (DIDO) water bolus are coupled to solve the steady state temperature and thermal dose distributions of rectangular TBSA (R-TBSA) for superficial tumor targets extending 10–15 mm beneath the skin surface. Thermal simulations are carried out for a range of bolus inlet temperature (Tb=38–43°C), water flow rate (Qb=2–4 L/min) and tumor blood perfusion (ωb=2–5 kg/m3/s) to characterize their influence on thermal dosimetry. Results Steady state SAR patterns of R- and L-TBSA demonstrate the ability to produce conformal and localized power deposition inside tumor target sparing surrounding normal tissues and nearby critical organs. Acceptably low variation in tissue surface cooling and surface temperature homogeneity was observed for the new DIDO bolus at 2 L/min water flow rate. Temperature depth profiles and thermal dose volume histograms indicate bolus inlet temperature (Tb) to be the most influential factor on thermal dosimetry. A 42 °C water bolus was observed to be the optimal choice for superficial tumors extending 10–15 mm from the surface even under significant blood perfusion. Lower bolus temperature may be chosen to reduce thermal enhancement ratio (TER) in the most sensitive skin where maximum radiation dose is delivered and to extend thermal enhancement of radiation dose deeper. Conclusion This computational study indicates that well-localized elevation of tumor target temperature to 40–44 °C can be accomplished by large surface-conforming TBSA applicators using appropriate selection of coupling bolus temperature. PMID:20224154

Dynamics at a Peptide-TiO2 Anatase (101) Interface.

PubMed

Polimeni, Marco; Petridis, Loukas; Smith, Jeremy C; Arcangeli, Caterina

2017-09-28

The interface between biological matter and inorganic materials is a widely investigated research topic due to possible applications in biomedicine and nanotechnology. In this context, the molecular level adsorption mechanism that drives specific recognition between small peptide sequences and inorganic surfaces represents an important topic likely to provide much information useful for designing bioderived materials. Here, we investigate the dynamics at the interface between a Ti-binding peptide sequence (AMRKLPDAPGMHC) and a TiO 2 anatase surface by using molecular dynamics (MD) simulations. In the simulations the adsorption mechanism is characterized by diffusion of the peptide from the bulk water phase toward the TiO 2 surface, followed by the anchoring of the peptide to the surface. The anchoring is mediated by the interfacial water layers by means of the charged groups of the side chains of the peptide. The peptide samples anchored and dissociated states from the surface and its conformation is not affected by the surface when anchored.