Fault-Related CO 2 Degassing, Geothermics, and Fluid Flow in Southern California Basins--Physiochemical Evidence and Modeling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garven, Grant

2015-08-11

Our studies have had an important impact on societal issues. Experimental and field observations show that CO 2 degassing, such as might occur from stored CO 2 reservoir gas, can result in significant stable isotopic disequilibrium. In the offshore South Ellwood field of the Santa Barbara channel, we show how oil production has reduced natural seep rates in the area, thereby reducing greenhouse gases. Permeability is calculated to be ~20-30 millidarcys for km-scale fault-focused fluid flow, using changes in natural gas seepage rates from well production, and poroelastic changes in formation pore-water pressure. In the Los Angeles (LA) basin, ourmore » characterization of formation water chemistry, including stable isotopic studies, allows the distinction between deep and shallow formations waters. Our multiphase computational-based modeling of petroleum migration demonstrates the important role of major faults on geological-scale fluid migration in the LA basin, and show how petroleum was dammed up against the Newport-Inglewood fault zone in a “geologically fast” interval of time (less than 0.5 million years). Furthermore, these fluid studies also will allow evaluation of potential cross-formational mixing of formation fluids. Lastly, our new study of helium isotopes in the LA basin shows a significant leakage of mantle helium along the Newport Inglewood fault zone (NIFZ), at flow rates up to 2 cm/yr. Crustal-scale fault permeability (~60 microdarcys) and advective versus conductive heat transport rates have been estimated using the observed helium isotopic data. The NIFZ is an important deep-seated fault that may crosscut a proposed basin decollement fault in this heavily populated area, and appears to allow seepage of helium from the mantle sources about 30 km beneath Los Angeles. The helium study has been widely cited in recent weeks by the news media, both in radio and on numerous web sites.« less

Carbon dioxide sequestration monitoring and verification via laser based detection system in the 2 mum band

NASA Astrophysics Data System (ADS)

Humphries, Seth David

Carbon Dioxide (CO2) is a known contributor to the green house gas effect. Emissions of CO2 are rising as the global demand for inexpensive energy is placated through the consumption and combustion of fossil fuels. Carbon capture and sequestration (CCS) may provide a method to prevent CO2 from being exhausted to the atmosphere. The carbon may be captured after fossil fuel combustion in a power plant and then stored in a long term facility such as a deep geologic feature. The ability to verify the integrity of carbon storage at a location is key to the success of all CCS projects. A laser-based instrument has been built and tested at Montana State University (MSU) to measure CO2 concentrations above a carbon storage location. The CO2 Detection by Differential Absorption (CODDA) Instrument uses a temperature-tunable distributed feedback (DFB) laser diode that is capable of accessing a spectral region, 2.0027 to 2.0042 mum, that contains three CO2 absorption lines and a water vapor absorption line. This instrument laser is aimed over an open-air, two-way path of about 100 m, allowing measurements of CO2 concentrations to be made directly above a carbon dioxide release test site. The performance of the instrument for carbon sequestration site monitoring is studied using a newly developed CO2 controlled release facility. The field and CO2 releases are managed by the Zero Emissions Research Technology (ZERT) group at MSU. Two test injections were carried out through vertical wells simulating seepage up well paths. Three test injections were done as CO2 escaped up through a slotted horizontal pipe simulating seepage up through geologic fault zones. The results from these 5 separate controlled release experiments over the course of three summers show that the CODDA Instrument is clearly capable of verifying the integrity of full-scale CO2 storage operations.

Greenhouse gases dissolved in soil solution - often ignored, but important?

NASA Astrophysics Data System (ADS)

Weymann, Daniel; Brueggemann, Nicolas; Puetz, Thomas; Vereecken, Harry

2014-05-01

Flux measurements of climate-relevant trace gases from soils are frequently undertaken in contemporary ecosystem studies and substantially contribute to our understanding of greenhouse gas balances of the biosphere. While the great majority of such investigations builds on closed chamber and eddy covariance measurements, where upward gas fluxes to the atmosphere are measured, fewest concurrently consider greenhouse gas dissolution in the seepage and leaching of dissolved gases via the vadose zone to the groundwater. Here we present annual leaching losses of dissolved N2O and CO2 from arable, grassland, and forest lysimeter soils from three sites differing in altitude and climate. We aim to assess their importance in comparison to direct N2O emission, soil respiration, and further leaching parameters of the C- and N cycle. The lysimeters are part of the Germany-wide lysimeter network initiative TERENO-SoilCan, which investigates feedbacks of climate change to the pedosphere on a long-term scale. Soil water samples were collected weekly from different depths of the profiles by means of suction cups. A laboratory pre-experiment proved that no degassing occurred under those sampling conditions. We applied the headspace equilibration technique to determine dissolved gas concentrations by gas chromatography. The seepage water of all lysimeters was consistently supersaturated with N2O and CO2 compared to water equilibrated ambient air. In terms of N2O, leaching losses increased in the ascending order forest, grassland, and arable soils, respectively. In case of the latter soils, we observed a strong variability of N2O, with dissolved concentrations up to 23 μg N L-1. However, since seepage discharge of the arable lysimeters was comparatively small and mostly limited to the hydrological winter season, leached N2O appeared to be less important than direct N2O emissions. In terms of dissolved CO2,our measurements revealed considerable leaching losses from the mountainous forest and grassland soils, based on concentrations up to 24 mg C L-1 and high seepage discharge. Such losses turned out to be similarly important like soil respiration, particularly during winter when temperature-dependent soil respiration declined. In conclusion, the results of the first year of our measurements provide evidence that dissolved greenhouse gases should be considered in studies which aim to assess full greenhouse gas balances, particularly in ecosystems where hydrological conditions favour microbial activity and high leaching losses.

A Dynamic Programming Model for Optimizing Frequency of Time-Lapse Seismic Monitoring in Geological CO2 Storage

NASA Astrophysics Data System (ADS)

Bhattacharjya, D.; Mukerji, T.; Mascarenhas, O.; Weyant, J.

2005-12-01

Designing a cost-effective and reliable monitoring program is crucial to the success of any geological CO2 storage project. Effective design entails determining both, the optimal measurement modality, as well as the frequency of monitoring the site. Time-lapse seismic provides the best spatial coverage and resolution for reservoir monitoring. Initial results from Sleipner (Norway) have demonstrated effective monitoring of CO2 plume movement. However, time-lapse seismic is an expensive monitoring technique especially over the long term life of a storage project and should be used judiciously. We present a mathematical model based on dynamic programming that can be used to estimate site-specific optimal frequency of time-lapse surveys. The dynamics of the CO2 sequestration process are simplified and modeled as a four state Markov process with transition probabilities. The states are M: injected CO2 safely migrating within the target zone; L: leakage from the target zone to the adjacent geosphere; R: safe migration after recovery from leakage state; and S: seepage from geosphere to the biosphere. The states are observed only when a monitoring survey is performed. We assume that the system may go to state S only from state L. We also assume that once observed to be in state L, remedial measures are always taken to bring it back to state R. Remediation benefits are captured by calculating the expected penalty if CO2 seeped into the biosphere. There is a trade-off between the conflicting objectives of minimum discounted costs of performing the next time-lapse survey and minimum risk of seepage and its associated costly consequences. A survey performed earlier would spot the leakage earlier. Remediation methods would have been utilized earlier, resulting in savings in costs attributed to excessive seepage. On the other hand, there are also costs for the survey and remedial measures. The problem is solved numerically using Bellman's optimality principal of dynamic programming to optimize over the entire finite time horizon. We use a Monte Carlo approach to explore trade-offs between survey costs, remediation costs, and survey frequency and to analyze the sensitivity to leakage probabilities, and carbon tax. The model can be useful in determining a monitoring regime appropriate to a specific site's risk and set of remediation options, rather than a generic one based on a maximum downside risk threshold for CO2 storage as a whole. This may have implications on the overall costs associated with deploying Carbon capture and storage on a large scale.

Rare earth elements (REE) as natural and applied tracers in the catchment area of Gessental valley, former uranium mining area of Eastern Thuringia, Germany

NASA Astrophysics Data System (ADS)

Buechel, G.; Merten, D.; Geletneky, J. W.; Kothe, E.

2003-04-01

Between 1947 and 1990 about 113.000 t of uranium were excavated at the former uranium mining site of Ronneburg (Eastern Thuringia, Germany). The legacy consists of more than 200 million m^3 of metasedimentary rocks rich in organic matter, sulfides and heavy metals originally deposited in mining heaps at the surface. The metasedimentary rocks formed under anoxic conditions about a 400 Mio. years ago are now exposed to oxic conditions. The oxidation of markasite and pyrite results in the formation of H_2SO_4. The formation of acid mine drainage (AMD) leads to high concentrations of uranium, rare earth elements (REE) and other heavy metals in surface water, seepage water and groundwater. This mobilization is due to alteration enhanced by high microbial activity and low pH. The tolerance mechanisms towards heavy metal pollution of soil substrate and surface/groundwater has allowed the selection of microbes which have, e.g. specific transporter genes and which are associated to plants in symbiotic interactions like mycorrhiza. In order to follow the processes linking alteration of metasedimentary rocks to biological systems the use of tracers is needed. One group of such tracers occuring in high concentrations in the water phase at the Ronneburg mining site are the REE (La-Lu) which are featured by very similar chemical behaviour. They show smooth but continuous variations of their chemical behaviour as a function of atomic number. For seepage water of the waste rock dump Nordhalde - sampled over a period of two years - the shale normalized REE patterns show enrichment of heavy REE and only minor variations, although the concentration differs. At sampling points in the surface water and in groundwater rather similar REE patterns were observed. Thus, REE can be used as tracers to identify diffuse inflow of REE-rich acid mine drainage of the dumps into the creek and the sediments. The absolute concentrations of REE in the creek and in ground water are up to 1000 times less than in seepage water due to mixing and (co)precipitation of REE. Lu/La and Sm/La relations show a significant decrease with increasing distance from the dump caused by preferential (co)precipitation of heavy REE with amorphous Fe-hydroxides along the Gessenbach. Thus, REE patterns can not only be used as tracers but also to study processes. In contrast to the patterns of the seepage, the REE patterns of the Silurian rocks as determined by LA-ICP-MS feature rather flat patterns with enrichment of middle REE (Sm - Dy). Results from batch experiments show preferentially leaching of heavy REE for all investigated source rocks. The highest absolute concentrations of REE appear in the eluates of the Silurian 'Ockerkalk'. Since the REE pattern closely reflects the pattern found in the seepage water it is assumed to be the most important source for the occurence of the REE pattern observed in seepage water. Studies of microbial heavy metal retention were performed by direct incubation of seepage water using well characterized fungal and bacterial strains. Using the bacterium Escherichia coli for incubation of seepage water sorption of heavy metals to biomass was observed. Use of the fungus Schizophyllum commune for incubation, however, has a much more pronounced effect including significant fractionation of REE pointing to the possibility of a specific active uptake mechanism. Bioextraction with bacteria and fungal mycelia might be an alternative to plant growth and phytoextraction and might be preferable for AMD water treatment since no soil substrate is necessary. Future research must be directed towards genes for active transport, intra- or extracellular storage proteins and their application. Biotechnological use of such genes in, e.g., strains of E. coli, might yield highly useful bioremediation strains that can help to reduce the ecological effects of pollution resulting from former mining activities.

Mud extrusion and ring-fault gas seepage - upward branching fluid discharge at a deep-sea mud volcano.

PubMed

Loher, M; Pape, T; Marcon, Y; Römer, M; Wintersteller, P; Praeg, D; Torres, M; Sahling, H; Bohrmann, G

2018-04-19

Submarine mud volcanoes release sediments and gas-rich fluids at the seafloor via deeply-rooted plumbing systems that remain poorly understood. Here the functioning of Venere mud volcano, on the Calabrian accretionary prism in ~1,600 m water depth is investigated, based on multi-parameter hydroacoustic and visual seafloor data obtained using ship-borne methods, ROVs, and AUVs. Two seepage domains are recognized: mud breccia extrusion from a summit, and hydrocarbon venting from peripheral sites, hosting chemosynthetic ecosystems and authigenic carbonates indicative of long-term seepage. Pore fluids in freshly extruded mud breccia (up to 13 °C warmer than background sediments) contained methane concentrations exceeding saturation by 2.7 times and chloride concentrations up to five times lower than ambient seawater. Gas analyses indicate an underlying thermogenic hydrocarbon source with potential admixture of microbial methane during migration along ring faults to the peripheral sites. The gas and pore water analyses point to fluids sourced deep (>3 km) below Venere mud volcano. An upward-branching plumbing system is proposed to account for co-existing mud breccia extrusion and gas seepage via multiple surface vents that influence the distribution of seafloor ecosystems. This model of mud volcanism implies that methane-rich fluids may be released during prolonged phases of moderate activity.

Reduced gas seepages in serpentinized peridotite complexes: Evidences for multiple origins of the H2-CH4-N2 gas mixtures

NASA Astrophysics Data System (ADS)

Deville, E.; Vacquand, C.; Beaumont, V.; Francois, G.; Sissmann, O.; Pillot, D.; Arcilla, C. A.; Prinzhofer, A.

2017-12-01

A comparative study of reduced gas seepages associated to serpentinized ultrabasic rocks was conducted in the ophiolitic complexes of Oman, the Philippines, Turkey and New Caledonia. This study is based on analyzes of the gas chemical composition, noble gases contents, and stable isotopes of carbon, hydrogen and nitrogen. These gas seepages are mostly made of mixtures of three main components which are H2, CH4 and N2 in various proportions. The relative contents of the three main gas components show 4 distinct families of gas mixtures (H2-rich, N2-rich, N2-H2-CH4 and H2-CH4). These families are interpreted as reflecting different zones of gas generation within or below the ophiolitic complexes. In the H2-rich family associated noble gases display signatures close to the value of air. In addition to the atmospheric component, mantle and crustal contributions are present in the N2-rich, N2-H2-CH4 and H2-CH4 families. H2-bearing gases are either associated to ultra-basic (pH 10-12) spring waters or they seep directly in fracture systems from the ophiolitic rocks. In ophiolitic contexts, ultrabasic rocks provide an adequate environment with available Fe2+ and high pH conditions that favor H2 production. CH4 is produced either directly by reaction of dissolved CO2 with basic-ultrabasic rocks during the serpentinization process or in a second step by H2-CO2 interaction. H2 is present in the gas when no more carbon is available in the system to generate CH4 (conditions of strong carbon restriction). The N2-rich family is associated with relatively high contents of crustal 4He. In this family N2 is interpreted as issued mainly from sediments located below the ophiolitic units.

Chemistry of water collected from an unventilated drift, Yucca Mountain, Nevada

USGS Publications Warehouse

Marshall, B.D.; Oliver, T.A.; Peterman, Z.E.

2007-01-01

Water samples (referred to as puddle water samples) were collected from the surfaces of a conveyor belt and plastic sheeting in the unventilated portion of the Enhanced Characterization of the Repository Block (ECRB) Cross Drift in 2003 and 2005 at Yucca Mountain, Nevada. The chemistry of these puddle water samples is very different than that of pore water samples from borehole cores in the same region of the Cross Drift or than seepage water samples collected from the Exploratory Studies Facility tunnel in 2005. The origin of the puddle water is condensation on surfaces of introduced materials and its chemistry is dominated by components of the introduced materials. Large CO2 concentrations may be indicative of localized chemical conditions induced by biologic activity. ?? 2007 Materials Research Society.

Lagoon Seepage Testing Report for Central Facilities Area (CFA) Sewage Lagoons at Idaho National Laboratory, Butte County, Idaho

DOE Office of Scientific and Technical Information (OSTI.GOV)

Morrison, Bridger

J-U-B ENGINEERS, Inc. (J-U-B) performed seepage tests on the CFA Wastewater Lagoons 1, 2, and 3 between August 26th and September 22nd, 2014. The lagoons were tested to satisfy the Idaho Department of Environmental Quality (DEQ) Rules (IDAPA 58.01.16) that require all lagoons be tested at a frequency of every 10 years and the Compliance Activity CA-141-03 in the DEQ Wastewater Reuse Permit for the CFA Sewage Treatment Plant (LA-000141-03). The lagoons were tested to determine if the average seepage rates are less than 0.25 in/day, the maximum seepage rate allowed for lagoons built prior to April 15, 2007. Themore » average seepage rates were estimated for each lagoon and are given in Table-ES1. The average seepage rates for Lagoons 1 and 2 are less than the allowable seepage rate of 0.25 in/day. Lagoon 1 and 2 passed the seepage test and will not have to be tested again until the year 20241. However, the average seepage rate for Lagoon 3 appears to exceed the allowable seepage rate of 0.25 in/day which means the potential source for the excessive leakage should be investigated further.« less

Response of soil C fluxes to warming and irrigation in a lysimeter experiment

NASA Astrophysics Data System (ADS)

Beck, Kerstin; Schindlbacher, Andreas; Borken, Werner

2017-04-01

Current climate change alters the temperature and precipitation regime of alpine forests, but its impact on soil carbon (C) dynamics is not well known. Recent studies suggest substantial soil C losses through persistently enhanced mineralization of soil organic matter in the Northern European Calcareous Alps. These C losses could result from increasing soil respiration as the most important pathway of soil C processes followed by leaching of dissolved inorganic and organic C (DIC, DOC). Here, we studied the response of these three C fluxes to (I) soil warming (+4°C), (II) irrigation (+40% water), and (III) a combination of soil warming and irrigation relative to a (IV) control in a field lysimeter experiment. The lysimeters (n=5 per treatment) were filled with mineral soil from a humus-rich A-horizon of a Rendzic Leptosol and detrital dolomite (C-horizon). Soil warming revealed an increase in soil respiration by 52%, but no or little change in soil CO2 concentration, DIC and DOC leaching during the growing season. Irrigation increased DIC and DOC leaching by >70% but had no effect on soil respiration. The combination of soil warming and irrigation increased soil CO2 efflux by only 28%, while the DIC and DOC fluxes increased by about 70% as in the irrigation treatment. The positive correlation between seepage fluxes and DIC fluxes (R2=0.97) suggests that precipitation is a strong driver of DIC losses. Despite the strong linear relationship between DIC and soil CO2 concentrations (R2=0.82), latter was poorly correlated with DIC losses (R2=0.44). A first estimate using the concentrations of dissolved Mg and Ca cations in seepage suggests that abiogenic DIC from dolomite weathering contributed about 30% to the total DIC flux. The biogenic DIC flux contributed 1-3% and the DOC flux <1% to the total soil C loss during the growing season. Taking average seepage fluxes of about 1000 mm into account, as typical for the Northern European Alps, the DIC flux could account for up to 7% of the annual soil C loss. Our results suggest that warming triggers elevated C losses by CO2 efflux, while increasing precipitation enhances DIC losses.

Characterization of focused seepage through an earthfill dam using geoelectrical methods.

PubMed

Ikard, S J; Revil, A; Schmutz, M; Karaoulis, M; Jardani, A; Mooney, M

2014-01-01

Resistivity and self-potential tomography can be used to investigate anomalous seepage inside heterogeneous earthen dams. The self-potential (SP) signals provide a unique signature to groundwater flow because the source current density responsible for the SP signals is proportional to the Darcy velocity. The distribution of the SP signals is also influenced by the distribution of the resistivity; therefore, resistivity and SP need to be used in concert to elucidate groundwater flow pathways. In this study, a survey is conducted at a small earthen dam in Colorado where anomalous seepage is observed on the downstream face at the dam toe. The data reveal SP and direct current resistivity anomalies that are used to delineate three anomalous seepage zones within the dam and to estimate the source of the localized seepage discharge. The SP data are inverted in two dimensions using the resistivity distribution to determine the distribution of the Darcy velocity responsible for the observed seepage. The inverted Darcy velocity agrees with an estimation of the Darcy velocity from the hydraulic conductivity obtained from a slug test and the observed head gradient. © 2013, National Ground Water Association.

Synoptic estimates of diffuse groundwater seepage to a spring-fed karst river at high spatial resolution using an automated radon measurement technique

NASA Astrophysics Data System (ADS)

Khadka, Mitra B.; Martin, Jonathan B.; Kurz, Marie J.

2017-01-01

Groundwater (GW) seepage can provide a major source of water, solutes, and contaminants to rivers, but identifying magnitudes, directions and locations of seepage is complicated by its diffuse and heterogeneous distributions. However, such information is necessary to develop programs and policies for protecting ecosystems and managing water resources. Here, we assess GW seepage to the Ichetucknee River, a spring-fed, low gradient, gaining stream in north-central Florida, through automated longitudinal surveys of radon (222Rn) activities at three different flow conditions. A 222Rn mass balance model, which integrates groundwater and spring water end member 222Rn activities and longitudinal 222Rn distributions in river water, shows that diffuse groundwater seepage represents about 16% of the total river baseflow, consistent with previous results obtained from ion (Ca2+, Cl-, SRP and Fe) mass balances and dye tracer methods. During high river stage, the contribution from seepage increases to 18-23% of the river flow. The spatial distribution of GW seepage is more variable in the upper 2.2-km reach of the river than the lower 2.8-km reach, regardless of river flow conditions. The upper reach has a narrower flood plain than the lower reach, which limits evapotranspiration and increases hydraulic gradients toward the river following storm events. Seepage in the lower reach is also limited by hydrologic damming by the receiving river, which inundates the floodplain during high flow conditions, and reduces the hydraulic head gradient. These results demonstrate the variable nature of seepage to a gaining river in both time and space and indicate that multiple synoptic analyses of GW seepage are required to assess seepage rates, determine time-averaged solute fluxes, and develop optimal management policies for riverine ecosystems.

Effects of experimental CO2 leakage on solubility and transport of seven trace metals in seawater and sediment.

PubMed

Ardelan, Murat V; Steinnes, Eiliv; Lierhagen, Syverin; Linde, Sven Ove

2009-12-01

The impact of CO(2) leakage on solubility and distribution of trace metals in seawater and sediment has been studied in lab scale chambers. Seven metals (Al, Cr, Ni, Pb, Cd, Cu, and Zn) were investigated in membrane-filtered seawater samples, and DGT samplers were deployed in water and sediment during the experiment. During the first phase (16 days), "dissolved" (<0.2 microm) concentrations of all elements increased substantially in the water. The increase in dissolved fractions of Al, Cr, Ni, Cu, Zn, Cd and Pb in the CO(2) seepage chamber was respectively 5.1, 3.8, 4.5, 3.2, 1.4, 2.3 and 1.3 times higher than the dissolved concentrations of these metals in the control. During the second phase of the experiment (10 days) with the same sediment but replenished seawater, the dissolved fractions of Al, Cr, Cd, and Zn were partly removed from the water column in the CO(2) chamber. DNi and DCu still increased but at reduced rates, while DPb increased faster than that was observed during the first phase. DGT-labile fractions (Me(DGT)) of all metals increased substantially during the first phase of CO(2) seepage. DGT-labile fractions of Al, Cr, Ni, Cu, Zn, Cd and Pb were respectively 7.9, 2.0, 3.6, 1.7, 2.1, 1.9 and 2.3 times higher in the CO(2) chamber than that of in the control chamber. Al(DGT), Cr(DGT), Ni(DGT), and Pb(DGT) continued to increase during the second phase of the experiment. There was no change in Cd(DGT) during the second phase, while Cu(DGT) and Zn(DGT) decreased by 30% and 25%, respectively in the CO(2) chamber. In the sediment pore water, DGT labile fractions of all the seven elements increased substantially in the CO(2) chamber. Our results show that CO(2) leakage affected the solubility, particle reactivity and transformation rates of the studied metals in sediment and at the sediment-water interface. The metal species released due to CO(2) acidification may have sufficiently long residence time in the seawater to affect bioavailability and toxicity of the metals to biota.

Nitrogen and Phosphorus Loads to Temperate Seepage Lakes Associated With Allochthonous Dissolved Organic Carbon Loads

Treesearch

J.R. Corman; B.L. Bertolet; N.J. Casson; S.D. Sebestyen; R.K. Kolka; E.H. Stanley

2018-01-01

Terrestrial loads of dissolved organic matter (DOM) have increased in recent years in many north temperate lakes. While much of the focus on the "browning" phenomena has been on its consequences for carbon cycling, much less is known about how it influences nutrient loading to lakes. We characterize potential loads of nitrogen and phosphorus to seepage lakes...

Influence of Hydrological Perturbations and Riverbed Sediment Characteristics on Hyporheic Zone Respiration of CO2 and N2

NASA Astrophysics Data System (ADS)

Newcomer, Michelle E.; Hubbard, Susan S.; Fleckenstein, Jan H.; Maier, Ulrich; Schmidt, Christian; Thullner, Martin; Ulrich, Craig; Flipo, Nicolas; Rubin, Yoram

2018-03-01

Rivers in climatic zones characterized by dry and wet seasons often experience periodic transitions between losing and gaining conditions across the river-aquifer continuum. Infiltration shifts can stimulate hyporheic microbial biomass growth and cycling of riverine carbon and nitrogen leading to major exports of biogenic CO2 and N2 to rivers. In this study, we develop and test a numerical model that simulates biological-physical feedback in the hyporheic zone. We used the model to explore different initial conditions in terms of dissolved organic carbon availability, sediment characteristics, and stochastic variability in aerobic and anaerobic conditions from water table fluctuations. Our results show that while highly losing rivers have greater hyporheic CO2 and N2 production, gaining rivers allowed the greatest fraction of CO2 and N2 production to return to the river. Hyporheic aerobic respiration and denitrification contributed 0.1-2 g/m2/d of CO2 and 0.01-0.2 g/m2/d of N2; however, the suite of potential microbial behaviors varied greatly among sediment characteristics. We found that losing rivers that consistently lacked an exit pathway can store up to 100% of the entering C/N as subsurface biomass and dissolved gas. Our results demonstrate the importance of subsurface feedbacks whereby microbes and hydrology jointly control fate of C and N and are strongly linked to wet-season control of initial sediment conditions and hydrologic control of seepage direction. These results provide a new understanding of hydrobiological and sediment-based controls on hyporheic zone respiration, including a new explanation for the occurrence of anoxic microzones and large denitrification rates in gravelly riverbeds.

Heterogeneous seepage at the Nopal I natural analogue site, Chihuahua, Mexico

NASA Astrophysics Data System (ADS)

Dobson, Patrick F.; Ghezzehei, Teamrat A.; Cook, Paul J.; Rodríguez-Pineda, J. Alfredo; Villalba, Lourdes; de La Garza, Rodrigo

2012-02-01

A study of seepage occurring in an adit at the Nopal I uranium mine in Chihuahua, Mexico, was conducted as part of an integrated natural analogue study to evaluate the effects of infiltration and seepage on the mobilization and transport of radionuclides. An instrumented seepage collection system and local automated weather station permit direct correlation between local precipitation events and seepage. Field observations recorded between April 2005 and December 2006 indicate that seepage is highly heterogeneous with respect to time, location, and quantity. Seepage, precipitation, and fracture data were used to test two hypotheses: (1) that fast flow seepage is triggered by large precipitation events, and (2) that an increased abundance of fractures and/or fracture intersections leads to higher seepage volumes. A few zones in the back adit recorded elevated seepage volumes immediately following large (>20 mm/day) precipitation events, with transit times of less than 4 h through the 8-m thick rock mass. In most locations, there is a 1-6 month time lag between the onset of the rainy season and seepage, with longer times observed for the front adit. There is a less clear-cut relation between fracture abundance and seepage volume; processes such as evaporation and surface flow along the ceiling may also influence seepage.

The need to consider temporal variability when modelling exchange at the sediment-water interface

USGS Publications Warehouse

Rosenberry, Donald O.

2011-01-01

Most conceptual or numerical models of flows and processes at the sediment-water interface assume steady-state conditions and do not consider temporal variability. The steady-state assumption is required because temporal variability, if quantified at all, is usually determined on a seasonal or inter-annual scale. In order to design models that can incorporate finer-scale temporal resolution we first need to measure variability at a finer scale. Automated seepage meters that can measure flow across the sediment-water interface with temporal resolution of seconds to minutes were used in a variety of settings to characterize seepage response to rainfall, wind, and evapotranspiration. Results indicate that instantaneous seepage fluxes can be much larger than values commonly reported in the literature, although seepage does not always respond to hydrological processes. Additional study is needed to understand the reasons for the wide range and types of responses to these hydrologic and atmospheric events.

Hydrogeochemistry of Maine seepage lakes and related groundwaters

NASA Astrophysics Data System (ADS)

Stauffer, Robert E.; Wittchen, Bruce D.

1992-10-01

Southeastern Maine contains numerous small seepage lakes (no perennial surface inflows or outflows), set in felsic, glacial deposits (eskers, pitted outwash, glacio-marine deltaic terraces) dating from the Wisconsin glacial retreat ca. 12 500 years B.P. The modern landscape is either forested or maintained as low blueberry heath by semi-annual mowing and burning. Although local precipitation is currently moderately acidic (volume-weighted pH ≈ 4.5), spring waters issuing from the glacial deposits are only weakly acidic (6.1 < pH < 7.0), and bicarbonate-buffered (120 to 300 mmol m -3) on account of tertiary weathering by dissolved CO 2. The order of mobility (denudation rate) for base cations (BC) is: Ca > Na > Mg > K, the same as for upland granitic terrane in the same region. Springwater composition is temporally stable but geographically variable. The most dilute springwaters drain blueberry barrens. Here, chemical weathering is limited by available acidity as evidenced by the relatively high final pHs (> 6.3) and low concentrations of strong oxy-anions (nitrate, sulfate) and dissolved inorganic carbon (DIC < 250 μM). Closely neighboring lakes often range widely in alkalinity, BC, and F, depending on their connection to the local groundwater system. Tracer analysis indicates seepage inflow is equal to 5-50 cm year -1 for typical regional seepage lakes, vs. higher rates (> 100 cm year -1) for groundwater discharge lakes. Approximately 88% of Si inputs to regional seepage lakes is retained in the sediments. Non-marine sulfate is lowest in groundwater discharge lakes containing the highest concentrations of BC and F, and featuring the shortest hydraulic residence times, suggesting that S retention in lake sediments is currently less efficient than in the adjoining terrestrial soils and vegetation.

The potential of near-surface geophysical methods in a hierarchical monitoring approach for the detection of shallow CO2 seeps at geological storage sites

NASA Astrophysics Data System (ADS)

Sauer, U.; Schuetze, C.; Dietrich, P.

2013-12-01

The MONACO project (Monitoring approach for geological CO2 storage sites using a hierarchic observation concept) aims to find reliable monitoring tools that work on different spatial and temporal scales at geological CO2 storage sites. This integrative hierarchical monitoring approach based on different levels of coverage and resolutions is proposed as a means of reliably detecting CO2 degassing areas at ground surface level and for identifying CO2 leakages from storage formations into the shallow subsurface, as well as CO2 releases into the atmosphere. As part of this integrative hierarchical monitoring concept, several methods and technologies from ground-based remote sensing (Open-path Fourier-transform infrared (OP-FTIR) spectroscopy), regional measurements (near-surface geophysics, chamber-based soil CO2 flux measurement) and local in-situ measurements (using shallow boreholes) will either be combined or used complementary to one another. The proposed combination is a suitable concept for investigating CO2 release sites. This also presents the possibility of adopting a modular monitoring concept whereby our monitoring approach can be expanded to incorporate other methods in various coverage scales at any temporal resolution. The link between information obtained from large-scale surveys and local in-situ monitoring can be realized by sufficient geophysical techniques for meso-scale monitoring, such as geoelectrical and self-potential (SP) surveys. These methods are useful for characterizing fluid flow and transport processes in permeable near-surface sedimentary layers and can yield important information concerning CO2-affected subsurface structures. Results of measurements carried out a natural analogue site in the Czech Republic indicate that the hierarchical monitoring approach represents a successful multidisciplinary modular concept that can be used to monitor both physical and chemical processes taking place during CO2 migration and seepage. The application of FTIR spectroscopy in combination with soil gas surveys and geophysical investigations results in a comprehensive site characterization, including atmospheric and near-surface CO2 distribution, as well as subsurface structural features. We observed a correlation of higher CO2 concentration and flux rates at the meso-scale that coincides with distinct geophysical anomalies. Here, we found prominent SP anomalies and zones of lower resistivity in the geoelectrical images compared to undisturbed regions nearby. This presentation will discuss the results we obtained and illustrate the influence of CO2 on electrical parameters measured under field conditions in relation to environmental parameters.

Multi-scale modeling of CO2 dispersion leaked from seafloor off the Japanese coast.

PubMed

Kano, Yuki; Sato, Toru; Kita, Jun; Hirabayashi, Shinichiro; Tabeta, Shigeru

2010-02-01

A numerical simulation was conducted to predict the change of pCO(2) in the ocean caused by CO(2) leaked from an underground aquifer, in which CO(2) is purposefully stored. The target space of the present model was the ocean above the seafloor. The behavior of CO(2) bubbles, their dissolution, and the advection-diffusion of dissolved CO(2) were numerically simulated. Here, two cases for the leakage rate were studied: an extreme case, 94,600 t/y, which assumed that a large fault accidentally connects the CO(2) reservoir and the seafloor; and a reasonable case, 3800 t/y, based on the seepage rate of an existing EOR site. In the extreme case, the calculated increase in DeltapCO(2) experienced by floating organisms was less than 300 ppm, while that for immobile organisms directly over the fault surface periodically exceeded 1000 ppm, if momentarily. In the reasonable case, the calculated DeltapCO(2) and pH were within the range of natural fluctuation. Copyright 2009 Elsevier Ltd. All rights reserved.

A seepage meter designed for use in flowing water

USGS Publications Warehouse

Rosenberry, D.O.

2008-01-01

Seepage meters provide one of the most direct means to measure exchange of water across the sediment-water interface, but they generally have been unsuitable for use in fluvial settings. Although the seepage bag can be placed inside a rigid container to minimize velocity head concerns, the seepage cylinder installed in the sediment bed projects into and disrupts the flow field, altering both the local-scale fluid exchange as well as measurement of that exchange. A low-profile seepage meter designed for use in moving water was tested in a seepage meter flux tank where both current velocity and seepage velocity could be controlled. The conical seepage cylinder protrudes only slightly above the sediment bed and is connected via tubing to a seepage bag or flowmeter positioned inside a rigid shelter that is located nearby where current velocity is much slower. Laboratory and field tests indicate that the net effect of the small protrusion of the seepage cylinder into the surface water flow field is inconsequentially small for surface water currents up to 65 cm s-1. Current velocity affects the variability of seepage measurements; seepage standard deviation increased from ???2 to ???6 cm d-1 as current velocity increased from 9 to 65 cm s-1. Substantial bias can result if the shelter is not placed to minimize hydraulic gradient between the bag and the seepage cylinder.

CO2 diffuse emission from maar lake: An example in Changbai volcanic field, NE China

NASA Astrophysics Data System (ADS)

Sun, Yutao; Guo, Zhengfu; Liu, Jiaqi; Du, Jianguo

2018-01-01

Numerous maars and monogenetic volcanic cones are distributed in northeast China, which are related to westward deep subduction of the Pacific Ocean lithosphere, comprising a significant part of the "Pacific Ring of Fire". It is well known that diffuse CO2 emissions from monogenetic volcanoes, including wet (e.g., maar lake) and dry degassing systems (e.g., soil diffuse emission, fault degassing, etc.), may contribute to budget of globally nature-derived greenhouse gases. However, their relationship between wet (e.g., maar lake) and concomitant dry degassing systems (e.g., soil diffuse emission, fault degassing, etc.) related to monogenetic volcanic field is poorly understood. Yuanchi maar, one of the typical monogenetic volcanic systems, is located on the eastern flank of Tianchi caldera in Changbai volcanic field of northeast China, which displays all of three forms of CO2 degassing including the maar lake, soil micro-seepage and fault degassing. Measurements of efflux of CO2 diffusion from the Yuanchi maar system (YMS) indicate that the average values of CO2 emissions from soil micro-seepage, fault degassing and water-air interface diffusion are 24.3 ± 23.3 g m- 2 d- 1, 39.2 ± 22.4 g m- 2 d- 1 and 2.4 ± 1.1 g m- 2 d- 1, respectively. The minimum output of CO2 diffuse emission from the YMS to the atmosphere is about 176.1 ± 88.3 ton/yr, of which 80.4% results from the dry degassing system. Degassing from the fault contributes to the most of CO2 emissions in all of the three forms of degassing in the YMS. Contributions of mantle, crust, air and organic CO2 to the soil gas are 0.01-0.10%, 10-20%, 32-36% and 48-54%, respectively, which are quantitatively constrained by a He-C isotope coupling calculation model. We propose that CO2 exsolves from the upper mantle melting beneath the Tianchi caldera, which migrates to the crustal magma chamber and further transports to the surface of YMS along the deep fault system. During the transportation processes, the emission of gas experiences crustal contamination, influence of magma chamber beneath the YMS, sub-surface processes and air dilution.

Analysis of the influence of the interlayer staggered zone in the basalt of Jinsha River Basin on the main buildings

NASA Astrophysics Data System (ADS)

Guo, Qiaona; Huang, Jiangwei

2018-02-01

In this paper, the finite element software FEFLOW is used to simulate the seepage field of the interlayer staggered zone C2 in the basalt of Jinsha River Basin. The influence of the interlayer staggered zone C2 on the building is analyzed. Combined with the waterproof effect of current design scheme of anti-seepage curtain, the seepage field in the interlayer staggered zone C2 is discussed under different design schemes. The optimal design scheme of anti-seepage curtain is put forward. The results showed that the case four can effectively reduce the head and hydraulic gradient of underground powerhouse area, and improve the groundwater seepage field in the plant area.

Effect of surficial disturbance on exchange between groundwater and surface water in nearshore margins

USGS Publications Warehouse

Rosenberry, Donald O.; Toran, Laura; Nyquist, Jonathan E.

2010-01-01

Low‐permeability sediments situated at or near the sediment‐water interface can influence seepage in nearshore margins, particularly where wave energy or currents are minimal. Seepage meters were used to quantify flow across the sediment‐water interface at two lakes where flow was from surface water to groundwater. Disturbance of the sediment bed substantially increased seepage through the sandy sediments of both lakes. Seepage increased by factors of 2.6 to 7.7 following bed disturbance at seven of eight measurement locations at Mirror Lake, New Hampshire, where the sediment representing the greatest restriction to flow was situated at the sediment‐water interface. Although the veneer of low‐permeability sediment was very thin and easily disturbed, accumulation on the bed surface was aided by a physical setting that minimized wind‐generated waves and current. At Lake Belle Taine, Minnesota, where pre‐disturbance downward seepage was smaller than at Mirror Lake, but hydraulic gradients were very large, disturbance of a 20 to 30 cm thick medium sand layer resulted in increases in seepage of 2 to 3 orders of magnitude. Exceptionally large seepage rates, some exceeding 25,000 cm/d, were recorded following bed disturbance. Since it is common practice to walk on the bed while installing or making seepage measurements, disruption of natural seepage rates may be a common occurrence in nearshore seepage studies. Disturbance of the bed should be avoided or minimized when utilizing seepage meters in shallow, nearshore settings, particularly where waves or currents are infrequent or minimal.

Numerical simulation of backward erosion piping in heterogeneous fields

NASA Astrophysics Data System (ADS)

Liang, Yue; Yeh, Tian-Chyi Jim; Wang, Yu-Li; Liu, Mingwei; Wang, Junjie; Hao, Yonghong

2017-04-01

Backward erosion piping (BEP) is one of the major causes of seepage failures in levees. Seepage fields dictate the BEP behaviors and are influenced by the heterogeneity of soil properties. To investigate the effects of the heterogeneity on the seepage failures, we develop a numerical algorithm and conduct simulations to study BEP progressions in geologic media with spatially stochastic parameters. Specifically, the void ratio e, the hydraulic conductivity k, and the ratio of the particle contents r of the media are represented as the stochastic variables. They are characterized by means and variances, the spatial correlation structures, and the cross correlation between variables. Results of the simulations reveal that the heterogeneity accelerates the development of preferential flow paths, which profoundly increase the likelihood of seepage failures. To account for unknown heterogeneity, we define the probability of the seepage instability (PI) to evaluate the failure potential of a given site. Using Monte-Carlo simulation (MCS), we demonstrate that the PI value is significantly influenced by the mean and the variance of ln k and its spatial correlation scales. But the other parameters, such as means and variances of e and r, and their cross correlation, have minor impacts. Based on PI analyses, we introduce a risk rating system to classify the field into different regions according to risk levels. This rating system is useful for seepage failures prevention and assists decision making when BEP occurs.

Widespread methane seepage along the continental margin off Svalbard - from Bjørnøya to Kongsfjorden

PubMed Central

Mau, S.; Römer, M.; Torres, M. E.; Bussmann, I.; Pape, T.; Damm, E.; Geprägs, P.; Wintersteller, P.; Hsu, C.-W.; Loher, M.; Bohrmann, G.

2017-01-01

Numerous articles have recently reported on gas seepage offshore Svalbard, because the gas emission from these Arctic sediments was thought to result from gas hydrate dissociation, possibly triggered by anthropogenic ocean warming. We report on findings of a much broader seepage area, extending from 74° to 79°, where more than a thousand gas discharge sites were imaged as acoustic flares. The gas discharge occurs in water depths at and shallower than the upper edge of the gas hydrate stability zone and generates a dissolved methane plume that is hundreds of kilometer in length. Data collected in the summer of 2015 revealed that 0.02–7.7% of the dissolved methane was aerobically oxidized by microbes and a minor fraction (0.07%) was transferred to the atmosphere during periods of low wind speeds. Most flares were detected in the vicinity of the Hornsund Fracture Zone, leading us to postulate that the gas ascends along this fracture zone. The methane discharges on bathymetric highs characterized by sonic hard grounds, whereas glaciomarine and Holocene sediments in the troughs apparently limit seepage. The large scale seepage reported here is not caused by anthropogenic warming. PMID:28230189

South-France caves monitoring : present day cave air dynamics characterization,paleoclimatic and archaeological interests

NASA Astrophysics Data System (ADS)

Bourges, F.; Genty, D.; Genthon, P.; Mangin, A.; D'Hulst, D.

2012-04-01

Cave climatic environment survey covers different sort of analyses on air and water, and has various interests from the conservation of prehistoric caves to the study of paleoclimates. Depending on the purpose, the cave monitoring can be entirely automatic or combine both automatic and manual data acquisitions. Apparatus are adapted to cave environment to measure specific parameters (i.e. drip rate, air humidity, CO2) and during the long-term monitorings, several generations of techniques have been used. We present here examples of cave monitoring (1996 →) from South-France: Chauvet, Orgnac (Ardèche), Esparros (Hautes-Pyrénées) and Villars (Dordogne). In all these sites, we obtained among the longest series of climatic parameters of inside the caves, coupled sometimes with geochemical and isotopic analyses on air and seepage water, which allow to better understand cave air circulation behaviour and their sensitivity to the external climatic and environmental variations. High precision temperature measurements in Orgnac and Chauvet caves, coupled with pCO2 and radon analyses, allowed the reconstruction of seasonal air circulation patterns in each cave. While the Chauvet and Esparros caves are quite confined environments with temperature changes mainly controlled by air pressure variations, the Orgnac cave, like most caves, shows a well marked summer/winter regime alternation. Quantification of air flows of known CO2 concentration allowed the calculation of carbon fluxes toward the earth atmosphere which is estimated to about 340 gm-2yr-1. Since 15 years, the monitoring made in the Villars cave at two different levels has shown that the air temperature displays small seasonal variations in the upper galleries while it is not detectable in the lower ones. Average annual temperature difference between these two levels is of more than 1°C, showing that local differences in a single cave can be significant. A global warming trend likely correlated with local external temperature changes is observed in both levels since the beginning of the monitoring in 1996 which is not the case in Chauvet and Esparros caves. The stable isotope composition of the seepage water of the Villars cave and drip rates measured under several stalactites give precious information about the mixture of the rainfall infiltration signal in the unsaturated zone; these long isotopic series are discussed and compared with the rainfall (quantity and isotopic composition) sampled at this site.

An evaluation of seepage gains and losses in Indian Creek Reservoir, Ada County, Idaho, April 2010–November 2011

USGS Publications Warehouse

Williams, Marshall L.; Etheridge, Alexandra B.

2013-01-01

The U.S. Geological Survey, in cooperation with the Idaho Department of Water Resources, conducted an investigation on Indian Creek Reservoir, a small impoundment in east Ada County, Idaho, to quantify groundwater seepage into and out of the reservoir. Data from the study will assist the Idaho Water Resources Department’s Comprehensive Aquifer Management Planning effort to estimate available water resources in Ada County. Three independent methods were utilized to estimate groundwater seepage: (1) the water-budget method; (2) the seepage-meter method; and (3) the segmented Darcy method. Reservoir seepage was quantified during the periods of April through August 2010 and February through November 2011. With the water-budget method, all measureable sources of inflow to and outflow from the reservoir were quantified, with the exception of groundwater; the water-budget equation was solved for groundwater inflow to or outflow from the reservoir. The seepage-meter method relies on the placement of seepage meters into the bottom sediments of the reservoir for the direct measurement of water flux across the sediment-water interface. The segmented-Darcy method utilizes a combination of water-level measurements in the reservoir and in adjacent near-shore wells to calculate water-table gradients between the wells and the reservoir within defined segments of the reservoir shoreline. The Darcy equation was used to calculate groundwater inflow to and outflow from the reservoir. Water-budget results provided continuous, daily estimates of seepage over the full period of data collection, while the seepage-meter and segmented Darcy methods provided instantaneous estimates of seepage. As a result of these and other difference in methodologies, comparisons of seepage estimates provided by the three methods are considered semi-quantitative. The results of the water-budget derived estimates of seepage indicate seepage to be seasonally variable in terms of the direction and magnitude of flow. The reservoir tended to gain water from seepage of groundwater in the early spring months (March–May), while seepage losses to groundwater from the reservoir occurred in the drier months (June–October). Net monthly seepage rates, as computed by the water-budget method, varied greatly. Reservoir gains from seepage ranged from 0.2 to 59.4 acre-feet per month, while reservoir losses to seepage ranged from 1.6 and 26.8 acre-feet per month. An analysis of seepage meter estimates and segmented-Darcy estimates qualitatively supports the seasonal patterns in seepage provided by the water-budget calculations, except that they tended to be much smaller in magnitude. This suggests that actual seepage might be smaller than those estimates made by the water-budget method. Although the results of all three methods indicate that there is some water loss from the reservoir to groundwater, the seepage losses may be due to rewetting of unsaturated near-shore soils, possible replenishment of a perched aquifer, or both, rather than through percolation to the local aquifer that lies 130 feet below the reservoir. A lithologic log from an adjacent well indicates the existence of a clay lithology that is well correlated to the original reservoir’s base elevation. If the clay lithologic unit extends beneath the reservoir basin underlying the fine-grain reservoir bed sediments, the clay layer should act as an effective barrier to reservoir seepage to the local aquifer, which would explain the low seepage loss estimates calculated in this study.

In situ quantification of spatial and temporal variability of hyporheic exchange in static and mobile gravel-bed rivers

USGS Publications Warehouse

Rosenberry, Donald O.; Klos, P. Zion; Neal, Andrew

2012-01-01

Seepage meters modified for use in flowing water were used to directly measure rates of exchange between surface and subsurface water in a gravel- and cobble bed river in western Pennsylvania, USA (Allegheny River, Q mean = 190 m 3/s) and a sand- and gravel-bed river in Colorado, USA (South Platte River, Q mean = 9??7 m 3/s). Study reaches at the Allegheny River were located downstream from a dam. The bed was stable with moss, algae, and river grass present in many locations. Median seepage was + 0??28 m/d and seepage was highly variable among measurement locations. Upward and downward seepage greatly exceeded the median seepage rate, ranging from + 2??26 (upward) to - 3??76 (downward) m/d. At the South Platte River site, substantial local-scale bed topography as well as mobile bedforms resulted in spatial and temporal variability in seepage greatly in exceedence of the median groundwater discharge rate of 0??24 m/d. Both upward and downward seepage were recorded along every transect across the river with rates ranging from + 2??37 to - 3??40 m/d. Despite a stable bed, which commonly facilitates clogging by fine-grained or organic sediments, seepage rates at the Allegheny River were not reduced relative to those at the South Platte River. Seepage rate and direction depended primarily on measurement position relative to local- and meso-scale bed topography at both rivers. Hydraulic gradients were small at nearly all seepage-measurement locations and commonly were not a good indicator of seepage rate or direction. Therefore, measuring hydraulic gradient and hydraulic conductivity at in-stream piezometers may be misleading if used to determine seepage flux across the sediment-water interface. Such a method assumes that flow between the well screen and sediment-water interface is vertical, which appears to be a poor assumption in coarse-grained hyporheic settings.

The influence of different diffusion pattern to the sub- and super-critical fluid flow in brown coal

NASA Astrophysics Data System (ADS)

Peng, Peihuo

2018-03-01

Sub- and super-critical CO2 flowing in nanoscale pores are recently becoming of great interest due to that it is closely related to many engineering applications, such as geological burial and sequestration of carbon dioxide, Enhanced Coal Bed Methane recovery ( ECBM), super-critical CO2 fracturing and so on. Gas flow in nanopores cannot be described simply by the Darcy equation. Different diffusion pattern such as Fick diffusion, Knudsen diffusion, transitional diffusion and slip flow at the solid matrix separate the seepage behaviour from Darcy-type flow. According to the principle of different diffusion pattern, the flow of sub- and super-critical CO2 in brown coal was simulated by numerical method, and the results were compared with the experimental results to explore the contribution of different diffusion pattern and swelling effect in sub- and super-critical CO2 flow in nanoscale pores.

Continental-scale magmatic carbon dioxide seepage recorded by dawsonite in the Bowen-Gunnedah-Sydney basin system, eastern Australia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Baker, J.C.; Bai, G.P.; Hamilton, P.J.

1995-07-03

Dawsonite, NaAlCO{sub 3}(OH){sub 2}, is widespread as a cement, replacement, and cavity filling in Permo-Triassic sedimentary rocks of the Bowen-Gunnedah-Sydney basin system eastern Australia. The origin of dawsonite in these rocks was studied by petrographic and stable isotope analysis. Dawsonite {delta}{sup 13}C (PDB) values range from {minus}4.0 to +4.1{per_thousand} and are remarkably consistent throughout the Bowen-Gunnedah-Sydney basin system. These values indicate either a marine carbonate or magmatic source for carbon in the dawsonite. A magmatic carbon source is considered more likely on the basis that (1) evidence of and the cause for widespread marine carbonate dissolution in the sedimentary successionsmore » are not apparent, (2) dawsonite is widespread in both marine and nonmarine facies, (3) the region has been the site of major igneous activity, (4) other dawsonite deposits of similar carbon isotopic composition are linked to igneous activity, and (5) magmatic CO{sub 2} accumulations are known in parts of the Bowen-Gunnedah-Sydney basin system. The timing of igneous activity in the Bowen Basin constrains the timing of dawsonite formation in the Bowen-Gunnedah-Sydney basin system to the Tertiary, consistent with textural relationships, which indicate that dawsonite formed late during the burial history of the Permo-triassic sequences. The distribution and interpreted origin of dawsonite implies magmatic CO{sub 2} seepage in the Bowen-Gunnedah-Sydney basin system on a continental scale.« less

Quantifying seepage using heat as a tracer in selected irrigation canals, Walker River Basin, Nevada, 2012 and 2013

USGS Publications Warehouse

Naranjo, Ramon C.; Smith, David W.

2016-11-16

The Walker River is an important source of water for western Nevada. The river provides water for agriculture and recharge to local aquifers used by several communities. Farmers began diverting water from the Walker River in the 1860s to support growing agricultural development. Over time, the reduced inflows into Walker Lake from upstream reservoirs and diversions have resulted in 170 feet of lake level decline and increased dissolved-solids concentrations to levels that threaten aquatic ecosystems, including survival of Lahonton cutthroat trout, a native species listed in the Endangered Species Act. Investigations of the water-budget components in the Walker River Basin have revealed uncertainty in the recharge to aquifers from irrigation canals. To address this need, the U.S. Geological Survey conducted an extensive field study from March 2012 through October 2013 to quantify seepage losses in selected canals in the Smith Valley, Mason Valley, and Walker Lake Valley irrigation areas.The seepage rates estimated for the 2012 and 2013 irrigation seasons in the Smith Valley transect sites (Saroni and Plymouth canals) ranged between 0.01 to 2.5 feet per day (ft/d) (0.01 to 0.68 cubic feet per second per mile [ft3/s-mi]). From 2012 to 2013, the average number of days the canals had flowing water decreased from 190 to 125 due to drier climate and lack of water available for diversion from the Walker River. The nearly 50-percent reductions in volumetric loss rates between 2012 and 2013 were associated with less than average diversions into canals from the Walker River and reductions in infiltration rates following routine canal maintenance.Models developed for the Saroni canal in 2012 were recalibrated in 2013 to evaluate changes in seepage as a result of siltation. Just prior to the 2012 irrigation season, nearly the entire length of the canal was cleared of vegetation and debris to improve flow conveyance. In 2013, following the first year of maintenance, a 90-percent reduction in seepage was observed at one of the transect sites. The removal of sediment-clogged layers during canal maintenance may have more profound effects on seepage rates beyond what was observed at the transect sites. The seepage rates for the Saroni canal in 2012 ranged from 0.02 to 1.6 ft/d (0.03 to 0.4 ft3/s-mi). The total seepage loss in the Saroni canal for the 2012 and 2013 irrigation seasons was estimated to be 1,100 and 590 acre-feet (acre-ft), respectively.Seepage rates on the Plymouth canal in Smith Valley in 2012 were among the lowest, ranging from 0.01 to 0.2 ft/d (0.01 to 0.1 ft3/s-mi). In 2013, the seepage rate on the Plymouth canal was similar to 2012; however, the volumetric loss was reduced by 50 percent due to the 50-percent reduction in number of canal flow days. Lower rates of seepage on the Plymouth canal for the 2012 and 2013 irrigation seasons were estimated to be 210 and 130 acre-ft, respectively.The seepage rates estimated for the 2012 and 2013 irrigation seasons in the Mason Valley transect sites (Fox, Mickey, and Campbell ditches) ranged from 0.1 to 3.3 ft/d (0.2 to 1.3 ft3/s-mi). The influence of water-table declines on seepage was observed at the Mickey and Campbell ditches. In 2012, the estimated seepage on the Mickey ditch was 1.6 ft/d during a period when the water-table altitude was at or above the canal altitude. Following extensive declines in the water table, the hydraulic gradient increased between the canal and the shallow aquifer, thereby increasing the seepage rates to 3.2 ft/d in 2013. During the period of hydraulic disconnection, seepage rates increased to 9.5 ft/d during intermittent periods of canal flow. For the Mickey ditch, the seepage loss in 2013 was 1.5 times the rate estimated in 2012 despite the canal having 45 days less flow. Similarly, the Campbell ditch seepage loss increased slightly from 660 to 700 acre-ft, a factor of 1.1, with 49 days less flow. The seepage loss for the Fox ditch did not exhibit significant year to year variability. The annual seepage loss estimated for 2012 and 2013 in the Fox ditch was 2,100 and 2,200 acre-ft, respectively.The seepage rates estimated for the 2013 irrigation season in the Walker Lake Valley transect sites (Schurz Lateral Canals 1A and 2A, and Canal 2) ranged from 0.7 to 0.9 ft/d (0.4 to 1.3 ft3/s-mi). In Walker Lake Valley, diversions into Lateral Canals 1A and 2A during the 2013 irrigation season were highly intermittent, a characteristic common of lateral diversions. The annual estimated seepage loss in Walker Lake Valley ranged between 50 and 725 acre-ft among the transect sites.

Estimated seepage rates from selected ditches, ponds, and lakes at the Camas National Wildlife Refuge, eastern Idaho

USGS Publications Warehouse

Rattray, Gordon W.

2017-01-01

The Camas National Wildlife Refuge (Refuge) in eastern Idaho, established in 1937, contains wetlands, ponds, and wet meadows that are essential resting and feeding habitat for migratory birds and nesting habitat for waterfowl. Initially, natural sources of water supported these habitats. However, during the past few decades, changes in climate and surrounding land use have altered and reduced natural groundwater and surface-water inflows, resulting in a 5-meter decline in the water table and an earlier, and more frequent, occurrence of no flow in Camas Creek at the Refuge. Due to these changes in water availability, water management that includes extensive groundwater pumping is now necessary to maintain the wetlands, ponds, and wet meadows.These water management activities have proven to be inefficient and expensive, and the Refuge is seeking alternative water-management options that are more efficient and less expensive. More efficient water management at the Refuge may be possible through knowledge of the seepage rates from ditches, ponds, and lakes at the Refuge. With this knowledge, water-management efficiency may be improved by natural means through selective use of water bodies with the smallest seepage rates or through engineering efforts to minimize seepage losses from water bodies with the largest seepage rates.The U.S. Geological Survey performed field studies in 2015 and 2016 to estimate seepage rates for selected ditches, ponds, and lakes at the Refuge. Estimated seepage rates from ponds and lakes ranged over an order of magnitude, from 3.4 ± 0.2 to 103.0 ± 0.5 mm/d, with larger seepage rates calculated for Big Pond and Redhead Pond, intermediate seepage rates calculated for Two-way Pond, and smaller seepages rates calculated for the south arm of Sandhole Lake. Estimated seepage losses from two reaches of Main Diversion Ditch were 21 ± 2 and 17 ± 2 percent/km. These losses represent seepage rates of about 890 and 860 mm/d, which are one- to two-orders-of-magnitude larger than seepage rates from the ponds and lake.The depth-integrated vertical hydraulic conductivity (Kv) for sediment underlying the ponds and lake was the primary control of seepage rates. The Kv's were 30 and 34 m/d for Big Pond, 14 and 18 m/d for Toomey Pond, 8 and 10 m/d for Two-way Pond, and 47 m/d for the north arm of Sandhole Lake.

Estimated seepage rates from selected ditches, ponds, and lakes at the Camas National Wildlife Refuge, eastern Idaho.

PubMed

Rattray, Gordon W

2017-12-01

The Camas National Wildlife Refuge (Refuge) in eastern Idaho, established in 1937, contains wetlands, ponds, and wet meadows that are essential resting and feeding habitat for migratory birds and nesting habitat for waterfowl. Initially, natural sources of water supported these habitats. However, during the past few decades, changes in climate and surrounding land use have altered and reduced natural groundwater and surface-water inflows, resulting in a 5-meter decline in the water table and an earlier, and more frequent, occurrence of no flow in Camas Creek at the Refuge. Due to these changes in water availability, water management that includes extensive groundwater pumping is now necessary to maintain the wetlands, ponds, and wet meadows. These water management activities have proven to be inefficient and expensive, and the Refuge is seeking alternative water-management options that are more efficient and less expensive. More efficient water management at the Refuge may be possible through knowledge of the seepage rates from ditches, ponds, and lakes at the Refuge. With this knowledge, water-management efficiency may be improved by natural means through selective use of water bodies with the smallest seepage rates or through engineering efforts to minimize seepage losses from water bodies with the largest seepage rates. The U.S. Geological Survey performed field studies in 2015 and 2016 to estimate seepage rates for selected ditches, ponds, and lakes at the Refuge. Estimated seepage rates from ponds and lakes ranged over an order of magnitude, from 3.4 ± 0.2 to 103.0 ± 0.5 mm/d, with larger seepage rates calculated for Big Pond and Redhead Pond, intermediate seepage rates calculated for Two-way Pond, and smaller seepages rates calculated for the south arm of Sandhole Lake. Estimated seepage losses from two reaches of Main Diversion Ditch were 21 ± 2 and 17 ± 2 percent/km. These losses represent seepage rates of about 890 and 860 mm/d, which are one- to two-orders-of-magnitude larger than seepage rates from the ponds and lake. The depth-integrated vertical hydraulic conductivity (K v ) for sediment underlying the ponds and lake was the primary control of seepage rates. The K v 's were 30 and 34 m/d for Big Pond, 14 and 18 m/d for Toomey Pond, 8 and 10 m/d for Two-way Pond, and 47 m/d for the north arm of Sandhole Lake. Published by Elsevier Ltd.

Methane seepage effects on biodiversity and biological traits of macrofauna inhabiting authigenic carbonates

NASA Astrophysics Data System (ADS)

Levin, Lisa A.; Mendoza, Guillermo F.; Grupe, Benjamin M.

2017-03-01

Authigenic carbonate rocks at methane seeps are recognized as hosting diverse and abundant invertebrate assemblages, with potential forcing from fluid seepage and hydrography. Mensurative studies of carbonate macrofauna (>0.3 mm) at Hydrate Ridge, OR revealed little effect of water depth and overlying oxygenation (at 600 m and 800 m) but a large influence of seepage activity on density, taxonomic composition, diversity, and biological traits (feeding, lifestyle, motility, size and calcification). Rocks exposed to active seepage had 3-4× higher total macrofaunal densities than under inactive conditions. Assemblages exhibited higher species richness and reduced evenness (greater dominance) under active seepage than inactive conditions, but no difference in H‧ or rarefaction diversity. Actively seeping sites were characterized by errant (motile), bacterial grazing, small- and medium-sized, heavily calcified species, whereas inactive sites exhibited a greater diversity of feeding modes and more burrowers, sessile, large and lightly calcified species. Active rocks supported more exogonid (Syllidae), ampharetid, and cirratulid polychaetes, provannid snails, pyropeltid limpets, nemerteans, and sponges; whereas inactive rocks supported higher densities of ophiuroids, isopods, gammarid amphipods, hydroids, Typosyllis (Syllidae) and tanaids. Transplant experiments, in which rocks were transferred between active and inactive sites at Hydrate Ridge North (600 m), revealed that assemblages respond within 13 months to increase or cessation of seepage, taking on the feeding, size and calcification characteristics of the background fauna at the new site. Lifestyles and motility patterns shifted more slowly as the sessile, attached species did not track seepage as quickly. Provannid snails and pyropeltid limpets rapidly colonized rocks transplanted to active sites and disappeared when transplanted to inactive sites. Given the known variability of fluid fluxes and rapid community response, a mosaic of communities changing in space and time is hypothesized to generate the relatively high species diversity at methane seeps.

CO2 diffusion into pore spaces limits weathering rate of an experimental basalt landscape

USGS Publications Warehouse

van Haren, Joost; Dontsova, Katerina; Barron-Gafford, Greg A.; Troch, Peter A.; Chorover, Jon; DeLong, Stephen B.; Breshears, David D.; Huxman, Travis E.; Pelletier, Jon D.; Saleska, Scott; Zeng, Xubin; Ruiz, Joaquin

2017-01-01

Basalt weathering is a key control over the global carbon cycle, though in situ measurements of carbon cycling are lacking. In an experimental, vegetation-free hillslope containing 330 m3 of ground basalt scoria, we measured real-time inorganic carbon dynamics within the porous media and seepage flow. The hillslope carbon flux (0.6–5.1 mg C m–2 h–1) matched weathering rates of natural basalt landscapes (0.4–8.8 mg C m–2 h–1) despite lacking the expected field-based impediments to weathering. After rainfall, a decrease in CO2 concentration ([CO2]) in pore spaces into solution suggested rapid carbon sequestration but slow reactant supply. Persistent low soil [CO2] implied that diffusion limited CO2 supply, while when sufficiently dry, reaction product concentrations limited further weathering. Strong influence of diffusion could cause spatial heterogeneity of weathering even in natural settings, implying that modeling studies need to include variable soil [CO2] to improve carbon cycling estimates associated with potential carbon sequestration methods.

Widespread methane seepage along the continental margin off Svalbard - from Bjørnøya to Kongsfjorden

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mau, S.; Romer, M.; Torres, M. E.

Numerous articles have recently reported on gas seepage offshore Svalbard, because the gas emission from these Arctic sediments was thought to result from gas hydrate dissociation, possibly triggered by anthropogenic ocean warming. We report on findings of a much broader seepage area, extending from 74° to 79°, where more than a thousand gas discharge sites were imaged as acoustic flares. The gas discharge occurs in water depths at and shallower than the upper edge of the gas hydrate stability zone and generates a dissolved methane plume that is hundreds of kilometer in length. Data collected in the summer of 2015more » revealed that 0.02–7.7% of the dissolved methane was aerobically oxidized by microbes and a minor fraction (0.07%) was transferred to the atmosphere during periods of low wind speeds. Most flares were detected in the vicinity of the Hornsund Fracture Zone, leading us to postulate that the gas ascends along this fracture zone. The methane discharges on bathymetric highs characterized by sonic hard grounds, whereas glaciomarine and Holocene sediments in the troughs apparently limit seepage. The large scale seepage reported here is not caused by anthropogenic warming.« less

Widespread methane seepage along the continental margin off Svalbard - from Bjørnøya to Kongsfjorden

DOE PAGES

Mau, S.; Romer, M.; Torres, M. E.; ...

2017-02-23

Numerous articles have recently reported on gas seepage offshore Svalbard, because the gas emission from these Arctic sediments was thought to result from gas hydrate dissociation, possibly triggered by anthropogenic ocean warming. We report on findings of a much broader seepage area, extending from 74° to 79°, where more than a thousand gas discharge sites were imaged as acoustic flares. The gas discharge occurs in water depths at and shallower than the upper edge of the gas hydrate stability zone and generates a dissolved methane plume that is hundreds of kilometer in length. Data collected in the summer of 2015more » revealed that 0.02–7.7% of the dissolved methane was aerobically oxidized by microbes and a minor fraction (0.07%) was transferred to the atmosphere during periods of low wind speeds. Most flares were detected in the vicinity of the Hornsund Fracture Zone, leading us to postulate that the gas ascends along this fracture zone. The methane discharges on bathymetric highs characterized by sonic hard grounds, whereas glaciomarine and Holocene sediments in the troughs apparently limit seepage. The large scale seepage reported here is not caused by anthropogenic warming.« less

Drift-Scale THC Seepage Model

DOE Office of Scientific and Technical Information (OSTI.GOV)

C.R. Bryan

The purpose of this report (REV04) is to document the thermal-hydrologic-chemical (THC) seepage model, which simulates the composition of waters that could potentially seep into emplacement drifts, and the composition of the gas phase. The THC seepage model is processed and abstracted for use in the total system performance assessment (TSPA) for the license application (LA). This report has been developed in accordance with ''Technical Work Plan for: Near-Field Environment and Transport: Coupled Processes (Mountain-Scale TH/THC/THM, Drift-Scale THC Seepage, and Post-Processing Analysis for THC Seepage) Report Integration'' (BSC 2005 [DIRS 172761]). The technical work plan (TWP) describes planning information pertainingmore » to the technical scope, content, and management of this report. The plan for validation of the models documented in this report is given in Section 2.2.2, ''Model Validation for the DS THC Seepage Model,'' of the TWP. The TWP (Section 3.2.2) identifies Acceptance Criteria 1 to 4 for ''Quantity and Chemistry of Water Contacting Engineered Barriers and Waste Forms'' (NRC 2003 [DIRS 163274]) as being applicable to this report; however, in variance to the TWP, Acceptance Criterion 5 has also been determined to be applicable, and is addressed, along with the other Acceptance Criteria, in Section 4.2 of this report. Also, three FEPS not listed in the TWP (2.2.10.01.0A, 2.2.10.06.0A, and 2.2.11.02.0A) are partially addressed in this report, and have been added to the list of excluded FEPS in Table 6.1-2. This report has been developed in accordance with LP-SIII.10Q-BSC, ''Models''. This report documents the THC seepage model and a derivative used for validation, the Drift Scale Test (DST) THC submodel. The THC seepage model is a drift-scale process model for predicting the composition of gas and water that could enter waste emplacement drifts and the effects of mineral alteration on flow in rocks surrounding drifts. The DST THC submodel uses a drift-scale process model relying on the same conceptual model and many of the same input data (i.e., physical, hydrologic, thermodynamic, and kinetic) as the THC seepage model. The DST THC submodel is the primary means for validating the THC seepage model. The DST THC submodel compares predicted water and gas compositions, and mineral alteration patterns, with observed data from the DST. These models provide the framework to evaluate THC coupled processes at the drift scale, predict flow and transport behavior for specified thermal-loading conditions, and predict the evolution of mineral alteration and fluid chemistry around potential waste emplacement drifts. The DST THC submodel is used solely for the validation of the THC seepage model and is not used for calibration to measured data.« less

Delineating a road-salt plume in lakebed sediments using electrical resistivity, piezometers, and seepage meters at Mirror Lake, New Hampshire, U.S.A

USGS Publications Warehouse

Toran, Laura; Johnson, Melanie; Nyquist, Jonathan E.; Rosenberry, Donald O.

2010-01-01

Electrical-resistivity surveys, seepage meter measurements, and drive-point piezometers have been used to characterize chloride-enriched groundwater in lakebed sediments of Mirror Lake, New Hampshire, U.S.A. A combination of bottom-cable and floating-cable electrical-resistivity surveys identified a conductive zone (<100ohm-m)">(<100ohm-m)(<100ohm-m) overlying resistive bedrock (<1000ohm-m)">(<1000ohm-m)(<1000ohm-m)beneath the lake. Shallow pore-water samples from piezometers in lakebed sediments have chloride concentrations of 200–1800μeq/liter">200–1800μeq/liter200–1800μeq/liter, and lake water has a chloride concentration of 104μeq/liter">104μeq/liter104μeq/liter. The extent of the plume was estimated and mapped using resistivity and water-sample data. The plume (20×35m">20×35m20×35m wide and at least 3m">3m3m thick) extends nearly the full length and width of a small inlet, overlying the top of a basin formed by the bedrock. It would not have been possible to mapthe plume's shape without the resistivity surveys because wells provided only limited coverage. Seepage meters were installed approximately 40m">40m40m from the mouth of a small stream discharging at the head of the inlet in an area where the resistivity data indicated lake sediments are thin. These meters recorded in-seepage of chloride-enriched groundwater at rates similar to those observed closer to shore, which was unexpected because seepage usually declines away from shore. Although the concentration of road salt in the northeast inlet stream is declining, the plume map and seepage data indicate the groundwater contribution of road salt to the lake is not declining. The findings demonstrate the benefit of combining geophysical and hydrologic data to characterize discharge of a plume beneath Mirror Lake. The extent of the plume in groundwater beneath the lake and stream indicate there will likely be a long-term source of chloride to the lake from groundwater.

[Quantification study on the runoff and seepage distribution and N, P pollutants removal of the vegetated buffer strips].

PubMed

Wang, Min; Huang, Yu-Chi; Wu, Jian-Qiang

2010-11-01

By using the constructed buffer strips test base and the runoff hydrometric devices, a research on stagnant runoff and nitrogen (N), phosphorous (P) pollutants removal capacity of the vegetated buffer strips was conducted. The results show that the vegetated buffer strips might reduce the speed of runoff significantly and improve the hydraulic permeability of soil. The runoff water output time of 19 m buffer strips planted with Cynodon dactylon, Festuca arundinacea and Trifolium repens are 2.46, 1.72 and 2.03 times higher than the control (no vegetation) respectively; The seepage water quantity of three vegetation buffer strips are 3.01, 2.16 and 2.45 times higher than the control respectively as well. Total removal efficiency of the three buffer strips increase about 237%, 268% and 274% comparing with the control respectively. The N, P removal capacity of seepage is significantly higher than that of the runoff, the larger seepage water quantity will cause higher N, P total removal efficiency and removal loads of unit area. With different vegetated buffer strips, the TN, NH4(+) -N, TP removal ratio of seepage and runoff are 2.79, 2.02 and 2.83 respectively.

Seepage and Piping through Levees and Dikes using 2D and 3D Modeling Codes

DTIC Science & Technology

2016-06-01

by the Hydrologic Systems Branch of the Flood and Storm Protection Division (CEERD-HF), U.S. Army Engineer Research and Development Center, Coastal ...ER D C/ CH L TR -1 6- 6 Flood & Coastal Storm Damage Reduction Program Seepage and Piping through Levees and Dikes Using 2D and 3D...Flood & Coastal Storm Damage Reduction Program ERDC/CHL TR-16-6 June 2016 Seepage and Piping through Levees and Dikes Using 2D and 3D Modeling Codes

POST-PROCESSING ANALYSIS FOR THC SEEPAGE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Y. SUN

This report describes the selection of water compositions for the total system performance assessment (TSPA) model of results from the thermal-hydrological-chemical (THC) seepage model documented in ''Drift-Scale THC Seepage Model'' (BSC 2004 [DIRS 169856]). The selection has been conducted in accordance with ''Technical Work Plan for: Near-Field Environment and Transport: Coupled Processes (Mountain-Scale TH/THC/THM, Drift-Scale THC Seepage, and Post-Processing Analysis for THC Seepage) Report Integration'' (BSC 2004 [DIRS 171334]). This technical work plan (TWP) was prepared in accordance with AP-2.27Q, ''Planning for Science Activities''. Section 1.2.3 of the TWP describes planning information pertaining to the technical scope, content, and managementmore » of this report. The post-processing analysis for THC seepage (THC-PPA) documented in this report provides a methodology for evaluating the near-field compositions of water and gas around a typical waste emplacement drift as these relate to the chemistry of seepage, if any, into the drift. The THC-PPA inherits the conceptual basis of the THC seepage model, but is an independently developed process. The relationship between the post-processing analysis and other closely related models, together with their main functions in providing seepage chemistry information for the Total System Performance Assessment for the License Application (TSPA-LA), are illustrated in Figure 1-1. The THC-PPA provides a data selection concept and direct input to the physical and chemical environment (P&CE) report that supports the TSPA model. The purpose of the THC-PPA is further discussed in Section 1.2. The data selection methodology of the post-processing analysis (Section 6.2.1) was initially applied to results of the THC seepage model as presented in ''Drift-Scale THC Seepage Model'' (BSC 2004 [DIRS 169856]). Other outputs from the THC seepage model (DTN: LB0302DSCPTHCS.002 [DIRS 161976]) used in the P&CE (BSC 2004 [DIRS 169860], Section 6.6) were also subjected to the same initial selection. The present report serves as a full documentation of this selection and also provides additional analyses in support of the choice of waters selected for further evaluation in ''Engineered Barrier System: Physical and Chemical Environment'' (BSC 2004 [DIRS 169860], Section 6.6). The work scope for the studies presented in this report is described in the TWP (BSC 2004 [DIRS 171334]) and other documents cited above and can be used to estimate water and gas compositions near waste emplacement drifts. Results presented in this report were submitted to the Technical Data Management System (TDMS) under specific data tracking numbers (DTNs) as listed in Appendix A. The major change from previous selection of results from the THC seepage model is that the THC-PPA now considers data selection in space around the modeled waste emplacement drift, tracking the evolution of pore-water and gas-phase composition at the edge of the dryout zone around the drift. This post-processing analysis provides a scientific background for the selection of potential seepage water compositions.« less

Groundwater-derived nutrient inputs to the Upper Gulf of Thailand

NASA Astrophysics Data System (ADS)

Burnett, William C.; Wattayakorn, Gullaya; Taniguchi, Makoto; Dulaiova, Henrieta; Sojisuporn, Pramot; Rungsupa, Sompop; Ishitobi, Tomotoshi

2007-01-01

We report here the first direct measurements of nutrient fluxes via groundwater discharge into the Upper Gulf of Thailand. Nutrient and standard oceanographic surveys were conducted during the wet and dry seasons along the Chao Phraya River, Estuary and out into the Upper Gulf of Thailand. Additional measurements in selected near-shore regions of the Gulf included manual and automatic seepage meter deployments, as well as nutrient evaluations of seepage and coastal waters. The river transects characterized the distribution of biogeochemical parameters in this highly contaminated urban environment. Seepage flux measurements together with nutrient analyses of seepage fluids were used to estimate nutrient fluxes via groundwater pathways for comparison to riverine fluxes. Our findings show that disseminated seepage of nutrient-rich mostly saline groundwater into the Upper Gulf of Thailand is significant. Estimated fluxes of dissolved inorganic nitrogen (DIN) supplied via groundwater discharge were 40-50% of that delivered by the Chao Phraya River, inorganic phosphate was 60-70%, and silica was 15-40%. Dissolved organic nitrogen (DON) and phosphorus (DOP) groundwater fluxes were also high at 30-40% and 30-130% of the river inputs, respectively. These observations are especially impressive since the comparison is being made to the river that is the largest source of fresh water into the Gulf of Thailand and flows directly through the megacity of Bangkok with high nutrient loadings from industrial and domestic sources.

Methanogenic activity and diversity in the centre of the Amsterdam Mud Volcano, Eastern Mediterranean Sea.

PubMed

Lazar, Cassandre Sara; John Parkes, R; Cragg, Barry A; L'Haridon, Stephane; Toffin, Laurent

2012-07-01

Marine mud volcanoes are geological structures emitting large amounts of methane from their active centres. The Amsterdam mud volcano (AMV), located in the Anaximander Mountains south of Turkey, is characterized by intense active methane seepage produced in part by methanogens. To date, information about the diversity or the metabolic pathways used by the methanogens in active centres of marine mud volcanoes is limited. (14)C-radiotracer measurements showed that methylamines/methanol, H(2)/CO(2) and acetate were used for methanogenesis in the AMV. Methylotrophic methanogenesis was measured all along the sediment core, Methanosarcinales affiliated sequences were detected using archaeal 16S PCR-DGGE and mcrA gene libraries, and enrichments of methanogens showed the presence of Methanococcoides in the shallow sediment layers. Overall acetoclastic methanogenesis was higher than hydrogenotrophic methanogenesis, which is unusual for cold seep sediments. Interestingly, acetate porewater concentrations were extremely high in the AMV sediments. This might be the result of organic matter cracking in deeper hotter sediment layers. Methane was also produced from hexadecanes. For the most part, the methanogenic community diversity was in accordance with the depth distribution of the H(2)/CO(2) and acetate methanogenesis. These results demonstrate the importance of methanogenic communities in the centres of marine mud volcanoes. © 2012 Federation of European Microbiological Societies. Published by Blackwell Publishing Ltd. All rights reserved.

Combined use of thermal methods and seepage meters to efficiently locate, quantify, and monitor focused groundwater discharge to a sand-bed stream

USGS Publications Warehouse

Rosenberry, Donald O.; Briggs, Martin A.; Delin, Geoffrey N.; Hare, Danielle K.

2016-01-01

Quantifying flow of groundwater through streambeds often is difficult due to the complexity of aquifer-scale heterogeneity combined with local-scale hyporheic exchange. We used fiber-optic distributed temperature sensing (FO-DTS), seepage meters, and vertical temperature profiling to locate, quantify, and monitor areas of focused groundwater discharge in a geomorphically simple sand-bed stream. This combined approach allowed us to rapidly focus efforts at locations where prodigious amounts of groundwater discharged to the Quashnet River on Cape Cod, Massachusetts, northeastern USA. FO-DTS detected numerous anomalously cold reaches one to several m long that persisted over two summers. Seepage meters positioned upstream, within, and downstream of 7 anomalously cold reaches indicated that rapid groundwater discharge occurred precisely where the bed was cold; median upward seepage was nearly 5 times faster than seepage measured in streambed areas not identified as cold. Vertical temperature profilers deployed next to 8 seepage meters provided diurnal-signal-based seepage estimates that compared remarkably well with seepage-meter values. Regression slope and R2 values both were near 1 for seepage ranging from 0.05 to 3.0 m d−1. Temperature-based seepage model accuracy was improved with thermal diffusivity determined locally from diurnal signals. Similar calculations provided values for streambed sediment scour and deposition at subdaily resolution. Seepage was strongly heterogeneous even along a sand-bed river that flows over a relatively uniform sand and fine-gravel aquifer. FO-DTS was an efficient method for detecting areas of rapid groundwater discharge, even in a strongly gaining river, that can then be quantified over time with inexpensive streambed thermal methods.

Application of environmental isotopes and hydrochemistry in the identification of source of seepage and likely connection with lake water in Lesser Himalaya, Uttarakhand, India

NASA Astrophysics Data System (ADS)

Rai, Shive Prakash; Singh, Dharmaveer; Rai, Ashwani Kumar; Kumar, Bhishm

2017-12-01

Oxygen (δ^{18}O) and hydrogen (δ2H and 3H) isotopes of water, along with their hydrochemistry, were used to identify the source of a newly emerged seepage water in the downstream of Lake Nainital, located in the Lesser Himalayan region of Uttarakhand, India. A total of 57 samples of water from 19 different sites, in and around the seepage site, were collected. Samples were analysed for chemical tracers like Ca^{++}, Mg^{++}, Na+, K+, {SO4}^{-} and Cl- using an Ion Chromatograph (Dionex IC-5000). A Dual Inlet Isotope Ratio Mass Spectrometer (DIIRMS) and an Ultra-Low Level Liquid Scintillation Counter (ULLSC), were used in measurements of stable isotopes (δ2H and δ^{18}O) and a radioisotope (3H), respectively. Results obtained in this study repudiate the possibility of any likely connection between seepage water and the lake water, and indicate that the source of seepage water is mainly due to locally recharged groundwater. The study suggests that environmental isotopes (δ2H, δ^{18}O and 3H) can effectively be used as `tracers' in the detection of the source of seepage water in conjunction with other hydrochemical tracers, and can help in water resource management and planning.

Application of the top specified boundary layer (TSBL) approximation to initial characterization of an inland aquifer mineralization: 2. Seepage of saltwater through semi-confining layers

USGS Publications Warehouse

Rubin, H.; Buddemeier, R.W.

1998-01-01

This paper presents a generalized basic study that addresses practical needs for an understanding of the major mechanisms involved in the mineralization of groundwater in the Great Bend Prairie aquifer in south- central Kansas. This Quaternary alluvial aquifer and associated surface waters are subject to contamination by saltwater, which in some areas seeps from the deeper Permian bedrock formation into the overlying freshwater aquifer through semiconfining layers. A simplified conceptual model is adopted. It incorporates the freshwater aquifer whose bottom is comprised of a semiconfining layer through which a hydrologically minor but geochemically important saline water discharge seeps into the aquifer. A hierarchy of approximate approaches is considered to analyze the mineralization processes taking place in the aquifer. The recently developed top specified boundary layer (TSBL) approach is very convenient to use for the initial characterization of these processes, and is further adapted to characterization of head-driven seepage through semi-confining layers. TSBL calculations indicate that the seeping saline water may create two distinct new zones in the aquifer: (1) a completely saline zone (CSZ) adjacent to the semiconfining bottom of the aquifer, and (2) a transition zone (TZ) which develops between the CSZ and the freshwater zone. Some possible scenarios associated with the various mineralization patterns are analyzed and discussed.

Relationship of oil seep in Kudat Peninsula with surrounding rocks based on geochemical analysis

NASA Astrophysics Data System (ADS)

Izzati Azman, Nurul; Nur Fathiyah Jamaludin, Siti

2017-10-01

This study aims to investigate the relation of oil seepage at Sikuati area with the structural and petroleum system of Kudat Peninsula. The abundance of highly carbonaceous rocks with presence of lamination in the Sikuati Member outcrop at Kudat Peninsula may give an idea on the presence of oil seepage in this area. A detailed geochemical analysis of source rock sample and oil seepage from Sikuati area was carried out for their characterization and correlation. Hydrocarbon propectivity of Sikuati Member source rock is poor to good with Total Organic Carbon (TOC) value of 0.11% to 1.48%. and also categorized as immature to early mature oil window with Vitrinite Reflectance (VRo) value of 0.43% to 0.50 %Ro. Based on biomarker distribution, from Gas Chromatography (GC) and Gas Chromatography-Mass Spectrometry (GC-MS) analysis, source rock sample shows Pr/Ph, CPI and WI of 2.22 to 2.68, 2.17 to 2.19 and 2.46 to 2.74 respectively indicates the source rock is immature and coming from terrestrial environment. The source rock might be rich in carbonaceous material organic matter resulting from planktonic/bacterial activity which occurs at fluvial to fluvio-deltaic environment. Overall, the source rock from outcrop level of Kudat Peninsula is moderately prolific in term of prospectivity and maturity. However, as go far deeper beneath the surface, we can expect more activity of mature source rock that generate and expulse hydrocarbon from the subsurface then migrating through deep-seated fault beneath the Sikuati area.

Using self-potential housing technique to model water seepage at the UNHAS housing Antang area

NASA Astrophysics Data System (ADS)

Syahruddin, Muhammad Hamzah

2017-01-01

The earth's surface has an electric potential that is known as self-potentiall (SP). One of the causes of the electrical potential at the earth's surface is water seepage into the ground. Electrical potential caused by water velocity seepage into the ground known as streaming potential. How to model water seepage into the ground at the housing Unhas Antang? This study was conducted to answer these questions. The self-potential measurements performed using a simple digital voltmeter Sanwa brand PC500 with a precision of 0.01 mV. While the coordinates of measurements points are self-potential using Global Positioning System. Mmeasurements results thus obtained are plotted using surfer image distribution self-potential housing Unhas Antang. The self-potential data housing Unhas Antang processed by Forward Modeling methods to get a model of water infiltration into the soil. Housing Unhas Antang self-potential has a value of 5 to 23 mV. Self-potential measurements carried out in the rainy season so it can be assumed that the measurement results caused by the velocity water seepage into the ground. The results of modeling the velocity water seepage from the surface to a depth of 3 meters was 2.4 cm/s to 0.2 cm /s. Modeling results showed that the velocity water seepage of the smaller with depth.

Characterization Of Contaminant Migration Potential In The Vicinity Of An In-Place Sand Cap

EPA Science Inventory

This study characterized the chemical transport potential of polycyclic aromatic hydrocarbons (PAHs) and total petroleum hydrocarbons (TPHs) in the vicinity of a sand cap placed in the nearshore zone of a tidal marine embayment. Groundwater seepage was investigated along the per...

Effect of anisotropy and groundwater system geometry on seepage through lakebeds. 1. Analog and dimensional analysis

USGS Publications Warehouse

Pfannkuch, H.O.; Winter, T.C.

1984-01-01

Distribution of seepage through lakebeds is controlled partly by geometric configuration of the lake and of the groundwater system interacting with the lake. To evaluate the effect of these factors, conductive-paper electric-analog models were used to analyze a number of lake and groundwater settings having different geometric configurations. Most settings analyzed are of lakes that do not penetrate the groundwater system. The width ratio, the ratio of half the lake width to thickness of the groundwater system, is the principal geometric characteristic used in this study. Because the distribution of groundwater seepage into a lake is not uniform across the lakebed, the concept of a streamlinecrowding factor is developed, and is used to determine seepage patterns from geometric characteristics of the lake and its contiguous groundwater system. Analysis of fourteen different width ratios of lake and groundwater systems indicates that lakes can be defined by three general groups of seepage patterns, which include flow patterns, volumes and rates: (1) lakes having width ratios less than ??? 0.6 show relatively uniform distribution of seepage across the lakebed; (2) lakes having width ratios of ??? 0.6 to ??? 2.0 change in absolute and relative streamline crowding in the near-shore region; and (3) lakes having width ratios greater than ??? 2.0 show stable flow patterns near shore; however, with increasing lake width, the relative streamline crowding increases relative to that width. For deep lakes and those in anisotropic media, the crowding effect is decreased, resulting in more uniform seepage across the lakebed. ?? 1984.

Modelling groundwater seepage zones in an unconfined aquifer with MODFLOW: different approaches

NASA Astrophysics Data System (ADS)

Leterme, Bertrand; Gedeon, Matej

2014-05-01

In areas where groundwater level occurs close to surface topography, the discharge of groundwater flow to the ground surface (or seepage) can be an important aspect of catchment hydrological cycle. It is also associated with valuable zones from an ecological point of view, often having a permanent shallow water table and constant lithotrophic water quality (Batelaan et al., 2003). In the present study, we try to implement a correct representation of this seepage process in a MODFLOW-HYDRUS coupled model for a small catchment (18.6 km²) of north-east Belgium. We started from an exisiting transient groundwater model of the unconfined aquifer in the study area (Gedeon and Mallants, 2009) discretized in 50x50 m cells. As the model did not account for seepage, hydraulic heads were simulated above the surface topography in certain zones. In the coupled MODFLOW-HYDRUS setup, transient boundary conditions (potential evapotranspiration and precipitation) are used to calculate the recharge with the HYDRUS package (Seo et al., 2007) for MODFLOW-2000 (Harbaugh et al., 2000). Coupling HYDRUS to MODFLOW involves the definition of a number of zones based on similarity in estimated groundwater depth, soil type and land cover. Concerning simulation of seepage, several existing packages are tested, including the DRAIN package (as in Reeve et al., 2006), the SPF package (from VSF Process; Thoms et al., 2006) and the PBC package (Post, 2011). Alternatively to the HYDRUS package for MODFLOW, the UZF package (Niswonger et al., 2006) for the simulation of recharge (and seepage) is also tested. When applicable, the parameterization of drain conductance in the top layer is critical and is investigated in relation to the soil hydraulic conductivity values used for the unsaturated zone (HYDRUS). Furthermore, stability issues are discussed, and where successful model runs are obtained, simulation results are compared with observed groundwater levels from a piezometric network. Spatial and temporal variability of the seepage zones is obtained and can be compared against seepage indicators such as soil maps or types of plant habitat. References Batelaan, O., De Smedt, F., Triest, L., 2003. Regional groundwater discharge: phreatophyte mapping, groundwater modelling and impact analysis of land-use change. Journal of Hydrology 275, 86-108. Gedeon, M., Mallants, D., 2009. Local-scale transient groundwater flow calculations. Project near surface disposal of category A waste at Dessel, NIRAS/ONDRAF, 74 p. Harbaugh, A.W., Banta, E.R., Hill, M.C., McDonald, M.G., 2000. MODFLOW-2000, the U.S. Geological Survey modular ground-water model user guide to modularization concepts and the ground-water flow process. USGS, Denver, CO. Niswonger, R.G., Prudic, D.E., Regan, R.S., 2006. Documentation of the Unsaturated-Zone Flow (UZF1) package for modeling unsaturated flow between the land surface and the water table with MODFLOW-2005. Techniques and Methods 6-A19, USGS, Denver, CO. Post, V.E.A., 2011. A new package for simulating periodic boundary conditions in MODFLOW and SEAWAT. Computers & Geosciences 37, 1843-1849. Reeve, A.S., Evensen, R., Glaser, P.H., Siegel, D.I., Rosenberry, D., 2006. Flow path oscillations in transient ground-water simulations of large peatland systems. Journal of Hydrology 316, 313-324. Seo, H.S., Šimůnek, J., Poeter, E.P., 2007. Documentation of the HYDRUS Package for MODFLOW-2000, the U.S. Geological Survey Modular Ground-Water Model. Colorado School of Mines, Golden, CO. Thoms, R.B., Johnson, R.L., Healy, R.W., 2006. User's guide to the Variably Saturated Flow (VSF) Process for MODFLOW. U.S. Geological Survey Techniques and Methods 6-A18, p. 58.

Characterization of the Spatial and Temporal Variations of Submarine Groundwater Discharge Using Electrical Resistivity and Seepage Measurements

NASA Astrophysics Data System (ADS)

Durand, Josephine Miryam Kalyanie

Submarine groundwater discharge (SGD) encompasses all fluids crossing the sediment/ocean interface, regardless of their origin, composition or driving forces. SGD provides a pathway for terrestrial contaminants that can significantly impact coastal ecosystems. Overexploitation of groundwater resources can decrease SGD which favors seawater intrusion at depth. Understanding SGD is therefore crucial for water quality and resource management. Quantifying SGD is challenging due to its diffuse and heterogeneous nature, in addition to significant spatio-temporal variations at multiple scales. In this thesis, an integrated approach combining electrical resistivity (ER) surveys, conductivity and temperature point measurements, seepage rates using manual and ultrasonic seepage meters, and pore fluid salinities was used to characterize SGD spatio-temporal variations and their implications for contaminant transport at several locations on Long Island, NY. The influence of surficial sediments on SGD distribution was investigated in Stony Brook Harbor. A low-permeability mud layer, actively depositing in the harbor, limits SGD at the shoreline, prevents mixing with seawater and channels a significant volume of freshwater offshore. SGD measured at locations without mud is high and indicates significant mixing between porewater and seawater. A 2D steady-state density-difference numerical model of the harbor was developed using SEAWAT and was validated by our field observations. Temporal variations of SGD due to semi-diurnal tidal forcing were studied in West Neck Bay, Shelter Island, using a 12-hr time-lapse ER survey together with continuous salinity and seepage measurements in the intertidal zone. The observed dynamic patterns of groundwater flux and salinity distribution disagree with published standard transient state numerical models, suggesting the need for developing more specific models of non-homogeneous anisotropic aquifers. SGD distribution and composition were characterized in Forge River, a tidal river that experiences chronic hypoxia due to nitrogen contamination. We found that nitrogen speciation and concentration are linked to different SGD regimes. Near shore sandy zones with high SGD show little nitrate reduction and constitute the major source of nitrogen input to surface waters. Offshore areas rich in silt and organic matter exhibit low SGD and higher denitrification. Dredging activities have altered the sediment distribution and subsequently have created preferential flow paths focusing freshwater discharge into the center of the river.

Measurement of submarine groundwater discharge using diverse methods in Coleroon Estuary, Tamil Nadu, India

NASA Astrophysics Data System (ADS)

Prakash, R.; Srinivasamoorthy, K.; Gopinath, S.; Saravanan, K.

2018-03-01

Submarine groundwater discharge (SGD) is described as submarine inflow of fresh and brackish groundwater from land into the sea. The release of sewages from point and non-point source pollutants from industries, agricultural and domestic activities gets discharged through groundwater to ocean creating natural disparity like decreasing flora fauna and phytoplankton blooms. Hence, to quantify fluxes of SGD in coastal regions is important. Quantification of SGD was attempted in Coleroon estuary, India, using three dissimilar methods like water budget, Darcy law and manual seepage meter. Three seepage meters were installed at two prominent litho units (alluvium and fluvio marine) at a distance of (0-14.7 km) away from Bay of Bengal. The water budget and Darcy law-quantified submarine seepage at a rate of 6.9 × 106 and 3.2 × 103 to 308.3 × 103 m3 year-1, respectively, and the seepage meter quantified seepage rate of 0.7024 m h-1 at an average. Larger seepage variations were isolated from three different techniques and the seepage rates were found to be influenced by hydrogeological characteristics of the litho units and distance from the coast.

Modelling stream aquifer seepage in an alluvial aquifer: an improved loosing-stream package for MODFLOW

NASA Astrophysics Data System (ADS)

Osman, Yassin Z.; Bruen, Michael P.

2002-07-01

Seepage from a stream, which partially penetrates an unconfined alluvial aquifer, is studied for the case when the water table falls below the streambed level. Inadequacies are identified in current modelling approaches to this situation. A simple and improved method of incorporating such seepage into groundwater models is presented. This considers the effect on seepage flow of suction in the unsaturated part of the aquifer below a disconnected stream and allows for the variation of seepage with water table fluctuations. The suggested technique is incorporated into the saturated code MODFLOW and is tested by comparing its predictions with those of a widely used variably saturated model, SWMS_2D simulating water flow and solute transport in two-dimensional variably saturated media. Comparisons are made of both seepage flows and local mounding of the water table. The suggested technique compares very well with the results of variably saturated model simulations. Most currently used approaches are shown to underestimate the seepage and associated local water table mounding, sometimes substantially. The proposed method is simple, easy to implement and requires only a small amount of additional data about the aquifer hydraulic properties.

Assessment of electrical resistivity method to map groundwater seepage zones in heterogeneous sediments

USGS Publications Warehouse

Gagliano, Michael P.; Nyquist, Jonathan E.; Toran, Laura; Rosenberry, Donald O.

2009-01-01

Underwater electrical‐resistivity data were collected along the southwest shore of Mirror Lake, NH, as part of a multi‐year assessment of the utility of geophysics for mapping groundwater seepage beneath lakes. We found that resistivity could locate shoreline sections where water is seeping out of the lake. A resistivity line along the lake bottom starting 27‐m off shore and continuing 27‐m on shore (1‐m electrode spacing) showed the water table dipping away from the lake, the gradient indicative of lake discharge in this area. Resistivity could also broadly delineate high‐seepage zones. An 80‐m line run parallel to shore using a 0.5‐m electrode spacing was compared with measurements collected the previous year using 1‐m electrode spacing. Both data sets showed the transition from high‐seepage glacial outwash, to low‐seepage glacial till, demonstrating reproducibility. However, even the finer 0.5‐m electrode spacing was insufficient to resolve the heterogeneity well enough to predict seepage variability within each zone. For example, over a 12.5‐m stretch where seepage varied from 1–38 cm/day, resistivity varied horizontally from 700–3900 ohm‐m and vertically in the top 2‐m from 900–4000 ohm‐m without apparent correlation with seepage. In two sections along this 80‐m line, one over glacial outwash, the other over till, we collected 14 parallel lines of resistivity, 13.5 m long spaced 1 m apart to form a 13.5 × 13 m data grid. These lines were inverted individually using a 2‐D inversion program and then interpolated to create a 3‐D volume. Examination of resistivity slices through this volume highlights the heterogeneity of both these materials, suggesting groundwater flow takes sinuous flow paths. In such heterogeneous materials the goal of predicting the precise location of high‐seepage points remains elusive.

NPDES Permit for Fort Carson Landfill No. 5 in Colorado

EPA Pesticide Factsheets

Under NPDES permit CO-0034771, the United States Army, HQ, Fort Carson, is authorized to discharge groundwater seepage from the Landfill No. 5 facility at the Fort Carson Army Post in El Paso County, Colorado, to B Ditch, a tributary of Fountain Creek.

Simulation of Sub-Drains Performance Using Visual MODFLOW for Slope Water Seepage Problem

NASA Astrophysics Data System (ADS)

Baharuddin, M. F. T.; Tajudin, S. A. A.; Abidin, M. H. Z.; Yusoff, N. A.

2016-07-01

Numerical simulation technique was used for investigating water seepage problem at the Botanic Park Kuala Lumpur. A proposed sub-drains installation in problematic site location was simulated using Modular Three-Dimensional Finite Difference Groundwater Flow (MODFLOW) software. The results of simulation heads during transient condition showed that heads in between 43 m (water seepage occurred at level 2) until 45 m (water seepage occurred at level 4) which heads measurement are referred to mean sea level. However, elevations measurements for level 2 showed the values between 41 to 42 m from mean sea level and elevations for level 4 between 42 to 45 m from mean sea level. These results indicated an increase in heads for level 2 and level 4 between 1 to 2 m when compared to elevations slope at the level 2 and level 4. The head increases surpass the elevation level of the slope area that causing water seepage at level 2 and level 4. In order to overcome this problems, the heads level need to be decrease to 1 until 2 m by using two options of sub-drain dimension size. Sub-drain with the dimension of 0.0750 m (diameter), 0.10 m (length) and using 4.90 m spacing was the best method to use as it was able to decrease the heads to the required levels of 1 to 2 m.

Transient Seepage for Levee Engineering Analyses

NASA Astrophysics Data System (ADS)

Tracy, F. T.

2017-12-01

Historically, steady-state seepage analyses have been a key tool for designing levees by practicing engineers. However, with the advances in computer modeling, transient seepage analysis has become a potentially viable tool. A complication is that the levees usually have partially saturated flow, and this is significantly more complicated in transient flow. This poster illustrates four elements of our research in partially saturated flow relating to the use of transient seepage for levee design: (1) a comparison of results from SEEP2D, SEEP/W, and SLIDE for a generic levee cross section common to the southeastern United States; (2) the results of a sensitivity study of varying saturated hydraulic conductivity, the volumetric water content function (as represented by van Genuchten), and volumetric compressibility; (3) a comparison of when soils do and do not exhibit hysteresis, and (4) a description of proper and improper use of transient seepage in levee design. The variables considered for the sensitivity and hysteresis studies are pore pressure beneath the confining layer at the toe, the flow rate through the levee system, and a levee saturation coefficient varying between 0 and 1. Getting results for SEEP2D, SEEP/W, and SLIDE to match proved more difficult than expected. After some effort, the results matched reasonably well. Differences in results were caused by various factors, including bugs, different finite element meshes, different numerical formulations of the system of nonlinear equations to be solved, and differences in convergence criteria. Varying volumetric compressibility affected the above test variables the most. The levee saturation coefficient was most affected by the use of hysteresis. The improper use of pore pressures from a transient finite element seepage solution imported into a slope stability computation was found to be the most grievous mistake in using transient seepage in the design of levees.

A new Arctic seepage site? Preliminary evidence from benthic community

NASA Astrophysics Data System (ADS)

Caridi, Francesca; Sabbatini, Anna; Morigi, Caterina; Giulia Lucchi, Renata

2017-04-01

The Kveithola Trough is an abrupt and narrow sedimentary system located in the NW Barents Sea. The hydrographic, bio-geochemical conditions and the possible existence of gas seepage activity of the area have been investigated during the Eurofleets 2- BURSTER cruise, conducted on board the German icebreaker RV Polarstern. The aim of our work is to characterize the benthic biota and more specifically the macrofaunal community structure coupled to the study of benthic foraminiferal meiofauna. Preliminary qualitative results revealed that in the inner Kveithola Trough, the macrofaunal community is composed by abundant black worm tubes (Chaetopteridae worms and Siboglinidae-like taxa) with presence of Thyasiridae bivalve species. The occurrence of these macrofaunal taxa is usually associated to oxygen-reduced environments, hydrothermal vents and cold seeps. The living benthic foraminiferal assemblage in the same stations is characterized by the presence of typically oxygen-depleted environmental taxa including the calcareous species Nonionellina labradorica and Globobulimina spp.. Conversely, in the outer Kveithola trough, both benthic macrofauna and foraminiferal meiofauna assemblages are characterized by less opportunistic taxa with a higher biodiversity suggesting very distinct oceanographic sea bottom conditions. The organic matter richness plays a large role in the Kveithola Trough environmental setting and may bring anoxic conditions that could affect the biota of the area. In fact, the benthic community structure of this area inhabits suboxic, anoxic and organic-enriched sediments and disturbed environments, forming assemblages with low diversity and high abundances of a few tolerant and/or specialized species. This preliminary finding could be consistent with other studies examining benthic community structure around Svalbard and in particular cold seep and vents habitats where faunal characteristics are patchy, suggesting small-scale heterogeneity in the environment surrounding cold seeps. For said reasons we envisage the presence of a new Arctic seepage site having a strong local impact on the benthic system.

Massive asphalt deposits, oil seepage, and gas venting support abundant chemosynthetic communities at the Campeche Knolls, southern Gulf of Mexico

NASA Astrophysics Data System (ADS)

Sahling, Heiko; Borowski, Christian; Escobar-Briones, Elva; Gaytán-Caballero, Adriana; Hsu, Chieh-Wei; Loher, Markus; MacDonald, Ian; Marcon, Yann; Pape, Thomas; Römer, Miriam; Rubin-Blum, Maxim; Schubotz, Florence; Smrzka, Daniel; Wegener, Gunter; Bohrmann, Gerhard

2016-08-01

Hydrocarbon seepage is a widespread process at the continental margins of the Gulf of Mexico. We used a multidisciplinary approach, including multibeam mapping and visual seafloor observations with different underwater vehicles to study the extent and character of complex hydrocarbon seepage in the Bay of Campeche, southern Gulf of Mexico. Our observations showed that seafloor asphalt deposits previously only known from the Chapopote Knoll also occur at numerous other knolls and ridges in water depths from 1230 to 3150 m. In particular the deeper sites (Chapopopte and Mictlan knolls) were characterized by asphalt deposits accompanied by extrusion of liquid oil in form of whips or sheets, and in some places (Tsanyao Yang, Mictlan, and Chapopote knolls) by gas emission and the presence of gas hydrates in addition. Molecular and stable carbon isotopic compositions of gaseous hydrocarbons suggest their primarily thermogenic origin. Relatively fresh asphalt structures were settled by chemosynthetic communities including bacterial mats and vestimentiferan tube worms, whereas older flows appeared largely inert and devoid of corals and anemones at the deep sites. The gas hydrates at Tsanyao Yang and Mictlan Knolls were covered by a 5-to-10 cm-thick reaction zone composed of authigenic carbonates, detritus, and microbial mats, and were densely colonized by 1-2 m-long tube worms, bivalves, snails, and shrimps. This study increased knowledge on the occurrences and dimensions of asphalt fields and associated gas hydrates at the Campeche Knolls. The extent of all discovered seepage structure areas indicates that emission of complex hydrocarbons is a widespread, thus important feature of the southern Gulf of Mexico.

Seepage investigation of the Rio Grande from below Leasburg Dam, Leasburg, New Mexico, to above American Dam, El Paso, Texas, 2015

USGS Publications Warehouse

Briody, Alyse C.; Robertson, Andrew J.; Thomas, Nicole

2016-03-22

Net seepage gain or loss was computed for each subreach (the interval between two adjacent measurement locations along the river) by subtracting the discharge measured at the upstream location from the discharge measured at the closest downstream location along the river and then subtracting any inflow to the river within the subreach. An estimated gain or loss was determined to be meaningful when it exceeded the cumulative measurement uncertainty associated with the net seepage computation. The cumulative seepage loss in the 64-mile study reach in 2015 was 17.3 plus or minus 2.6 cubic feet per second. Gaining and losing reaches identified in this investigation generally correspond to seepage patterns observed in previous investigations conducted during dry years, with the gaining reaches occurring primarily at the southern (downstream) end of the basin.

Levee Seepage Detection in the Sacramento-San Joaquin Delta Using Polarimetric SAR

NASA Astrophysics Data System (ADS)

An, K.; Jones, C. E.; Bekaert, D. P.

2017-12-01

The Sacramento-San Joaquin Delta's extensive levee system protects over 2,800 km2 of reclaimed lands and serves as the main irrigation and domestic water supply for the state of California. However, ongoing subsidence and disaster threats from floods and earthquakes make the Delta levee system highly vulnerable, endangering water supplies for 23 million California residents and 2.5 million acres of agricultural land. Levee failure in the Delta can cause saltwater intrusion from San Francisco Bay, reducing water quality and curtailing water exports to residents, commercial users, and farmers. To protect the Delta levee system, it is essential to search for signs of seepage in which water is piping through or beneath levees, which can be associated with deformation of the levees themselves. Until now, in-situ monitoring has largely been applied, however, this is a time-consuming and expensive approach. We use data acquired with NASA's UAVSAR (Uninhabited Aerial Vehicle Synthetic Aperture Radar) airborne radar instrument to identify and characterize levee seepages and associated land subsidence through advanced remote sensing technologies. The high spatial resolution of UAVSAR can help to direct surveys to areas that are likely to be experiencing damage. UAVSAR is an L-band airborne sensor with high signal-to-noise ratio, repeat flight track accuracy, and spatial resolution of 7x7 m2 (for multi-looked products) that is necessary for detailed levee monitoring. The adaptability of radar instruments in their ability to see through smoke, haze, and clouds during the day or night, is especially relevant during disaster events, when cloud cover or lack of solar illumination inhibits traditional visual surveys of damage. We demonstrate the advantages of combining polarimetric radar imagery with geographic information systems (GIS) datasets in locating seepage features along critical levee infrastructure in the Delta for 2009-2016. The ability to efficiently locate potential areas of instability will also be automated into GIS tools for the California Dept. of Water Resources, who have oversight of the levee system, that will help to bolster their current ground-based monitoring programs and to aid emergency response during a flood or earthquake.

Authigenic carbonates from newly discovered active cold seeps on the northwestern slope of the South China Sea: Constraints on fluid sources, formation environments, and seepage dynamics

NASA Astrophysics Data System (ADS)

Liang, Qianyong; Hu, Yu; Feng, Dong; Peckmann, Jörn; Chen, Linying; Yang, Shengxiong; Liang, Jinqiang; Tao, Jun; Chen, Duofu

2017-06-01

Authigenic carbonates recovered from two newly discovered active cold seeps on the northwestern slope of the South China Sea have been studied using petrography, mineralogy, stable carbon and oxygen isotopic, as well as trace element compositions, together with AMS 14C ages of shells of seep-dwelling bivalves to unravel fluid sources, formation conditions, and seepage dynamics. The two seeps (ROV1 and ROV2), referred to as 'Haima seeps' herein, are approximately 7 kilometers apart, and are typified by abundant carbonate rocks represented bycrusts and nodules. Aragonite and high-Mg calcite are the main carbonate minerals. Based on low δ13Ccarbonate values ranging from -43.0‰ to -27.5‰ (V-PDB) methane is apparently the predominant carbon source of seep carbonates. The corresponding δ18O values, varying from 2.5‰ to 5.8‰ (V-PDB), mostly are higher than calculated values representing precipitation in equilibrium with seawater (2.5‰ to 3.8‰), which probably reflects past destabilization of locally abundant gas hydrates. In addition, we found that carbonates with bivalve shells are generally aragonite-dominated, and bear no barium enrichment but uranium enrichments, reflecting shallow formation depths close to the seafloor. In contrast, carbonate crusts without bivalve shells and nodules contain more calcite, and are characterized by major molybdenum enrichment and different degrees of barium enrichment, agreeing with precipitation at greater depth under strictly anoxic conditions. AMS 14C ages suggest that a major episode of carbonate precipitation occurred between 6.1 ka and 5.1 ka BP at the Haima seeps, followed by a possibly subordinate episode from approximately 3.9 ka to 2.9 ka BP. The common occurrence of dead bivalves at both sites indicates that chemosynthesis-based communities flourished to a greater extent in the past, probably reflecting a decline of seepage activity in recent times. Overall, these results confirm that authigenic carbonates from gas hydrate-bearing areas can provide insight into long-term seepage dynamics and the genesis and fate of marine gas hydrate reservoirs.

Development of High Yield Feedstocks and Biomass Conversion Technology for Renewable Energy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hashimoto, Andrew G.; Crow, Susan; DeBeryshe, Barbara

2015-04-09

This project had two main goals. The first goal was to evaluate several high yielding tropical perennial grasses as feedstock for biofuel production, and to characterize the feedstock for compatible biofuel production systems. The second goal was to assess the integration of renewable energy systems for Hawaii. The project focused on high-yield grasses (napiergrass, energycane, sweet sorghum, and sugarcane). Field plots were established to evaluate the effects of elevation (30, 300 and 900 meters above sea level) and irrigation (50%, 75% and 100% of sugarcane plantation practice) on energy crop yields and input. The test plots were extensive monitored including:more » hydrologic studies to measure crop water use and losses through seepage and evapotranspiration; changes in soil carbon stock; greenhouse gas flux (CO 2, CH 4, and N 2O) from the soil surface; and root morphology, biomass, and turnover. Results showed significant effects of environment on crop yields. In general, crop yields decrease as the elevation increased, being more pronounced for sweet sorghum and energycane than napiergrass. Also energy crop yields were higher with increased irrigation levels, being most pronounced with energycane and less so with sweet sorghum. Daylight length greatly affected sweet sorghum growth and yields. One of the energy crops (napiergrass) was harvested at different ages (2, 4, 6, and 8 months) to assess the changes in feedstock characteristics with age and potential to generate co-products. Although there was greater potential for co-products from younger feedstock, the increased production was not sufficient to offset the additional cost of harvesting multiple times per year. The feedstocks were also characterized to assess their compatibility with biochemical and thermochemical conversion processes. The project objectives are being continued through additional support from the Office of Naval Research, and the Biomass Research and Development Initiative. Renewable energy assessments included: biomass feedstocks currently being produced by Hawaiian Commercial & Sugar Co., and possibilities of producing methane from agricultural and livestock wastes and the potential of photovoltaic systems for irrigation pumping at HC&S. Finally, the impact of a micro-hydroelectric system on a small-farm economics and the local community was assessed.« less

Geophysical Investigations at Hidden Dam, Raymond, California: Summary of Fieldwork and Data Analysis

USGS Publications Warehouse

Minsley, Burke J.; Burton, Bethany L.; Ikard, Scott; Powers, Michael H.

2010-01-01

Geophysical field investigations have been carried out at the Hidden Dam in Raymond, California for the purpose of better understanding the hydrogeology and seepage-related conditions at the site. Known seepage areas on the northwest right abutment area of the downstream side of the dam are documented by Cedergren. Subsequent to the 1980 seepage study, a drainage blanket with a subdrain system was installed to mitigate downstream seepage. Flow net analysis provided by Cedergren suggests that the primary seepage mechanism involves flow through the dam foundation due to normal reservoir pool elevations, which results in upflow that intersects the ground surface in several areas on the downstream side of the dam. In addition to the reservoir pool elevations and downstream surface topography, flow is also controlled by the existing foundation geology as well as the presence or absence of a horizontal drain within the downstream portion of the dam. The purpose of the current geophysical work is to (1) identify present-day seepage areas that may not be evident due to the effectiveness of the drainage blanket in redirecting seepage water, and (2) provide information about subsurface geologic structures that may control subsurface flow and seepage. These tasks are accomplished through the use of two complementary electrical geophysical methods, self-potentials (SP) and direct-current (DC) electrical resistivity, which have been commonly utilized in dam-seepage studies. SP is a passive method that is primarily sensitive to active subsurface groundwater flow and seepage, whereas DC resistivity is an active-source method that is sensitive to changes in subsurface lithology and groundwater saturation. The focus of this field campaign was on the downstream area on the right abutment, or northwest side of the dam, as this is the main area of interest regarding seepage. Two exploratory self-potential lines were also collected on the downstream left abutment of the dam to identify potential seepage in that area. This report is primarily a summary of the field geophysical data acquisition, with some preliminary results and interpretation. Further work will involve a more rigorous analysis of the geophysical datasets and an examination of a large dataset of historical observations of water levels in a number of observation wells and piezometers compared with reservoir elevation. In addition, a partially saturated flow model will be developed to better understand seepage patterns given the available information about dam construction, geophysical results, and data from installed observation wells and piezometers.

Along - Strike Analysis of Contemporary Ocean Temperature Change on the Cascadia Margin and Implications to Upper Slope Hydrate Instability

NASA Astrophysics Data System (ADS)

Phrampus, B.; Harris, R. N.; Trehu, A. M.; Embley, R. W.; Merle, S. G.

2017-12-01

Gas hydrates are found globally on continental margins and due to the large amount of sequestered carbon in hydrate reservoirs, whether these deposits are dynamic or stable has significant implications for slope stability, ocean/atmosphere carbon budget, and deep-water energy exploration. Recent studies indicate that upper slope hydrate degradation may be relatively widespread on passive margins due to recent ocean temperature warming between 0.012 and 0.033 °C/yr (e.g. Svalbard, North Alaska, and US Atlantic margin). However, the potential and breadth of warming induced hydrate instability remains contentious based on multiple observations including: 1) seep locations not consistent with locations of hydrate dissociation, 2) a lack of hydrate in regions of warming, and 3) evidence for long-lived seepage in regions associated with contemporary warming-induced hydrate dissociation. At the Cascadia margin, a recent study suggests that contemporary warming of intermediate water intersects the hydrate stability zone leading to hydrate dissociation that feeds upper slope seeps. Here, we provide a systematic analysis of along-strike variations in hydrate distribution along the Cascadia margin combined with a multivariable regression of ocean temperatures to characterize the potential of upper slope hydrate instability. Preliminary seep locations reveal upper slope seeps and observed regions of hydrate are correlated spatially between 42.5 and 48.0 °N, outside this region there is a dearth of identified upper slope hydrate and seeps. Between 44.5 and 48.0 °N a contemporary warming trend is as large as 0.006 °C/yr and is collocated with upper slope hydrate and gas seepage. This warming rate is relatively small, 2-5x smaller than warming trends identified in the Arctic where temperature induced hydrate instability remains uncertain. Additionally, we identify a region between 42.5 and 44.5 °N with collocated upper slope seepage and hydrate but no evidence of ocean warming, suggesting upper slope seepage is not driven by temperature induced hydrate instability, but maybe driven by tectonic uplift. These results highlight the absence of temperature driven seepage and slope instability on the Cascadia margin and deemphasize the impact of lower latitude warming on global hydrate dynamics and carbon budget.

Modeling of coupled heat transfer and reactive transport processesin porous media: Application to seepage studies at Yucca Mountain, Nevada

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mukhopadhyay, Sumit; Sonnenthal, Eric L.; Spycher, Nicolas

When hot radioactive waste is placed in subsurface tunnels, a series of complex changes occurs in the surrounding medium. The water in the pore space of the medium undergoes vaporization and boiling. Subsequently, vapor migrates out of the matrix pore space, moving away from the tunnel through the permeable fracture network. This migration is propelled by buoyancy, by the increased vapor pressure caused by heating and boiling, and through local convection. In cooler regions, the vapor condenses on fracture walls, where it drains through the fracture network. Slow imbibition of water thereafter leads to gradual rewetting of the rock matrix.more » These thermal and hydrological processes also bring about chemical changes in the medium. Amorphous silica precipitates from boiling and evaporation, and calcite from heating and CO2 volatilization. The precipitation of amorphous silica, and to a much lesser extent calcite, results in long-term permeability reduction. Evaporative concentration also results in the precipitation of gypsum (or anhydrite), halite, fluorite and other salts. These evaporative minerals eventually redissolve after the boiling period is over, however, their precipitation results in a significant temporary decrease in permeability. Reduction of permeability is also associated with changes in fracture capillary characteristics. In short, the coupled thermal-hydrological-chemical (THC) processes dynamically alter the hydrological properties of the rock. A model based on the TOUGHREACT reactive transport software is presented here to investigate the impact of THC processes on flow near an emplacement tunnel at Yucca Mountain, Nevada. We show how transient changes in hydrological properties caused by THC processes often lead to local flow channeling and saturation increases above the tunnel. For models that include only permeability changes to fractures, such local flow channeling may lead to seepage relative to models where THC effects are ignored. However, coupled THC seepage models that include both permeability and capillary changes to fractures may not show this additional seepage.« less

Modeling of coupled heat transfer and reactive transport processesin porous media: Application to seepage studies at Yucca Mountain, Nevada

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mukhopadhyay, S.; Sonnenthal, E.L.; Spycher, N.

When hot radioactive waste is placed in subsurface tunnels, a series of complex changes occurs in the surrounding medium. The water in the pore space of the medium undergoes vaporization and boiling. Subsequently, vapor migrates out of the matrix pore space, moving away from the tunnel through the permeable fracture network. This migration is propelled by buoyancy, by the increased vapor pressure caused by heating and boiling, and through local convection. In cooler regions, the vapor condenses on fracture walls, where it drains through the fracture network. Slow imbibition of water thereafter leads to gradual rewetting of the rock matrix.more » These thermal and hydrological processes also bring about chemical changes in the medium. Amorphous silica precipitates from boiling and evaporation, and calcite from heating and CO{sub 2} volatilization. The precipitation of amorphous silica, and to a much lesser extent calcite, results in long-term permeability reduction. Evaporative concentration also results in the precipitation of gypsum (or anhydrite), halite, fluorite and other salts. These evaporative minerals eventually redissolve after the boiling period is over, however, their precipitation results in a significant temporary decrease in permeability. Reduction of permeability is also associated with changes in fracture capillary characteristics. In short, the coupled thermal-hydrological-chemical (THC) processes dynamically alter the hydrological properties of the rock. A model based on the TOUGHREACT reactive transport software is presented here to investigate the impact of THC processes on flow near an emplacement tunnel at Yucca Mountain, Nevada. We show how transient changes in hydrological properties caused by THC processes often lead to local flow channeling and saturation increases above the tunnel. For models that include only permeability changes to fractures, such local flow channeling may lead to seepage relative to models where THC effects are ignored. However, coupled THC seepage models that include both permeability and capillary changes to fractures may not show this additional seepage.« less

Hydrogeophysical investigations at Hidden Dam, Raymond, California

USGS Publications Warehouse

Minsley, Burke J.; Burton, Bethany L.; Ikard, Scott; Powers, Michael H.

2011-01-01

Self-potential and direct current resistivity surveys are carried out at the Hidden Dam site in Raymond, California to assess present-day seepage patterns and better understand the hydrogeologic mechanisms that likely influence seepage. Numerical modeling is utilized in conjunction with the geophysical measurements to predict variably-saturated flow through typical two-dimensional dam cross-sections as a function of reservoir elevation. Several different flow scenarios are investigated based on the known hydrogeology, as well as information about typical subsurface structures gained from the resistivity survey. The flow models are also used to simulate the bulk electrical resistivity in the subsurface under varying saturation conditions, as well as the self-potential response using petrophysical relationships and electrokinetic coupling equations.The self-potential survey consists of 512 measurements on the downstream area of the dam, and corroborates known seepage areas on the northwest side of the dam. Two direct-current resistivity profiles, each approximately 2,500 ft (762 m) long, indicate a broad sediment channel under the northwest side of the dam, which may be a significant seepage pathway through the foundation. A focusing of seepage in low-topography areas downstream of the dam is confirmed from the numerical flow simulations, which is also consistent with past observations. Little evidence of seepage is identified from the self-potential data on the southeast side of the dam, also consistent with historical records, though one possible area of focused seepage is identified near the outlet works. Integration of the geophysical surveys, numerical modeling, and observation well data provides a framework for better understanding seepage at the site through a combined hydrogeophysical approach.

Mapping on Slope Seepage Problem using Electrical Resistivity Imaging (ERI)

NASA Astrophysics Data System (ADS)

Hazreek, Z. A. M.; Nizam, Z. M.; Aziman, M.; Dan, M. F. Md; Shaylinda, M. Z. N.; Faizal, T. B. M.; Aishah, M. A. N.; Ambak, K.; Rosli, S.; Rais, Y.; Ashraf, M. I. M.; Alel, M. N. A.

2018-04-01

The stability of slope may influenced by several factors such as its geomaterial properties, geometry and environmental factors. Problematic slope due to seepage phenomenon will influenced the slope strength thus promoting to its failure. In the past, slope seepage mapping suffer from several limitation due to cost, time and data coverage. Conventional engineering tools to detect or mapped the seepage on slope experienced those problems involving large and high elevation of slope design. As a result, this study introduced geophysical tools for slope seepage mapping based on electrical resistivity method. Two spread lines of electrical resistivity imaging were performed on the slope crest using ABEM SAS 4000 equipment. Data acquisition configuration was based on long and short arrangement, schlumberger array and 2.5 m of equal electrode spacing interval. Raw data obtained from data acquisition was analyzed using RES2DINV software. Both of the resistivity results show that the slope studied consists of three different anomalies representing top soil (200 – 1000 Ωm), perched water (10 – 100 Ωm) and hard/dry layer (> 200 Ωm). It was found that seepage problem on slope studied was derived from perched water zones with electrical resistivity value of 10 – 100 Ωm. Perched water zone has been detected at 6 m depth from the ground level with varying thickness at 5 m and over. Resistivity results have shown some good similarity output with reference to borehole data, geological map and site observation thus verified the resistivity results interpretation. Hence, this study has shown that the electrical resistivity imaging was applicable in slope seepage mapping which consider efficient in term of cost, time, data coverage and sustainability.

Numerical Analysis on Seepage in the deep overburden CFRD

NASA Astrophysics Data System (ADS)

Zeyu, GUO; Junrui, CHAI; Yuan, QIN

2017-12-01

There are many problems in the construction of hydraulic structures on deep overburden because of its complex foundation structure and poor geological condition. Seepage failure is one of the main problems. The Combination of the seepage control system of the face rockfill dam and the deep overburden can effectively control the seepage of construction of the concrete face rockfill dam on the deep overburden. Widely used anti-seepage measures are horizontal blanket, waterproof wall, curtain grouting and so on, but the method, technique and its effect of seepage control still have many problems thus need further study. Due to the above considerations, Three-dimensional seepage field numerical analysis based on practical engineering case is conducted to study the seepage prevention effect under different seepage prevention methods, which is of great significance to the development of dam technology and the development of hydropower resources in China.

Seepage through a hazardous-waste trench cover

USGS Publications Warehouse

Healy, R.W.

1989-01-01

Water movement through a waste-trench cover under natural conditions at a low-level radioactive waste disposal site in northwestern Illinois was studied from July 1982 to June 1984, using tensiometers, a moisture probe, and meteorological instruments. Four methods were used to estimate seepage: the Darcy, zero-flux plane, surface-based water-budget, and groundwater-based water-budget methods. Annual seepage estimates ranged from 48 to 216 mm (5-23% of total precipitation), with most seepage occurring in spring. The Darcy method, although limited in accuracy by uncertainty in hydraulic conductivity, was capable of discretizing seepage in space and time and indicated that seepage varied by almost an order of magnitude across the width of the trench. Lowest seepage rates occurred near the center of the cover, where seepage was gradual. Highest rates occurred along the edge of the cover, where seepage was highly episodic, with 84% of the total there being traced to wetting fronts from 28 individual storms. Limitations of the zero-flux-plane method were severe enough for the method to be judged inappropriate for use in this study.Water movement through a waste-trench cover under natural conditions at a low-level radioactive waste disposal site in northwestern Illinois was studied from July 1982 to June 1984, using tensiometers, a moisture probe, and meteorological instruments. Four methods were used to estimate seepage: the Darcy, zero-flux plane, surface-based water-budget, and groundwater-based water-budget methods. Annual seepage estimates ranged from 48 to 216mm (5-23% of total precipitation), with most seepage occurring in spring. The Darcy method, although limited in accuracy by uncertainty in hydraulic conductivity, was capable of discretizing seepage in space and time and indicated that seepage varied by almost an order of magnitude across the width of the trench. Lowest seepage rates occurred near the center of the cover, where seepage was gradual. Highest rates occurred along the edge of the cover, where seepage was highly episodic, with 84% of the total there being traced to wetting fronts from 28 individual storms. Limitations of the zero-flux-plane method were severe enough for the method to be judged inappropriate for use in this study.

Geological timing and duration of methane seepage in different sedimentary and tectonic settings in the Lower Congo Basin

NASA Astrophysics Data System (ADS)

Wenau, S.; Spiess, V.

2016-12-01

Methane seepage sites have been investigated in the Lower Congo Basin using seismo-acoustic methods in combination with geological and geochemical sampling. Pockmarks were observed in different areas of the Lower Congo Basin that are affected by different styles of salt-tectonic deformation and sedimentary input. At the salt front in the southern part of the basin, methane seepage shifts continuously westwards as previously undeformed sediments are affected by westward moving salt. Older seepage sites to the East are cut off from methane supply in the process of continuing salt-tectonic deformation. The initiation of gas accumulation and seepage directly at the deformation front is expected in the late Miocene due to salt-induced uplift. In the northern part of the basin on the lower slope, methane seepage is focused along salt-tectonic faults connecting Pliocene fan deposits to the seafloor, breaching the hemipelagic seal. These sites show indications for continuing seepage for the last 640 kyrs. Such long term seepage activity may be due to the lack of polygonal faults in the hemipelagic seal, focusing gas migration on fewer, salt-tectonic faults. Westward of the salt front, seepage features include the Regab pockmark where a potential reservoir in an Early Pleistocene channel flank is connected to the seafloor feature via a seismic chimney. Seepage activity in this area is also documented to be continuous over geologic time scales by seafloor and sub-seafloor seepage indications such as chimneys, pockmarks and buried seepage features. The Lower Congo Basin thus documents the longevity of seepage processes in the context of various tectonic and sedimentary regimes on a passive continental margin. Indications of the duration of seepage activity at individual sites may be used for methane budgeting in combination with emission rates estimated for typical seepage sites.

Use of an Electromagnetic Seepage Meter to Investigate Temporal Variability in Lake Seepage

USGS Publications Warehouse

Rosenberry, D.O.; Morin, R.H.

2004-01-01

A commercially available electromagnetic flowmeter is attached to a seepage cylinder to create an electromagnetic seepage meter (ESM) for automating measurement of fluxes across the sediment/water interface between ground water and surface water. The ESM is evaluated through its application at two lakes in New England, one where water seeps into the lake and one where water seeps out of the lake. The electromagnetic flowmeter replaces the seepage-meter bag and provides a continuous series of measurements from which temporal seepage processes can be investigated. It provides flow measurements over a range of three orders of magnitude, and contains no protruding components or moving parts. The ESM was used to evaluate duration of seepage disturbance following meter installation and indicated natural seepage rates resumed approximately one hour following meter insertion in a sandy lakebed. Lakebed seepage also varied considerably in response to lakebed disturbances, near-shore waves, and rain-falls, indicating hydrologic processes are occurring in shallow lakebed settings at time scales that have largely gone unobserved.

A Tube Seepage Meter for In Situ Measurement of Seepage Rate and Groundwater Sampling.

PubMed

Solder, John E; Gilmore, Troy E; Genereux, David P; Solomon, D Kip

2016-07-01

We designed and evaluated a "tube seepage meter" for point measurements of vertical seepage rates (q), collecting groundwater samples, and estimating vertical hydraulic conductivity (K) in streambeds. Laboratory testing in artificial streambeds show that seepage rates from the tube seepage meter agreed well with expected values. Results of field testing of the tube seepage meter in a sandy-bottom stream with a mean seepage rate of about 0.5 m/day agreed well with Darcian estimates (vertical hydraulic conductivity times head gradient) when averaged over multiple measurements. The uncertainties in q and K were evaluated with a Monte Carlo method and are typically 20% and 60%, respectively, for field data, and depend on the magnitude of the hydraulic gradient and the uncertainty in head measurements. The primary advantages of the tube seepage meter are its small footprint, concurrent and colocated assessments of q and K, and that it can also be configured as a self-purging groundwater-sampling device. © 2015, National Ground Water Association.

A tube seepage meter for in situ measurement of seepage rate and groundwater sampling

USGS Publications Warehouse

Solder, John; Gilmore, Troy E.; Genereux, David P.; Solomon, D. Kip

2016-01-01

We designed and evaluated a “tube seepage meter” for point measurements of vertical seepage rates (q), collecting groundwater samples, and estimating vertical hydraulic conductivity (K) in streambeds. Laboratory testing in artificial streambeds show that seepage rates from the tube seepage meter agreed well with expected values. Results of field testing of the tube seepage meter in a sandy-bottom stream with a mean seepage rate of about 0.5 m/day agreed well with Darcian estimates (vertical hydraulic conductivity times head gradient) when averaged over multiple measurements. The uncertainties in q and K were evaluated with a Monte Carlo method and are typically 20% and 60%, respectively, for field data, and depend on the magnitude of the hydraulic gradient and the uncertainty in head measurements. The primary advantages of the tube seepage meter are its small footprint, concurrent and colocated assessments of q and K, and that it can also be configured as a self-purging groundwater-sampling device.

Use of an electromagnetic seepage meter to investigate temporal variability in lake seepage.

PubMed

Rosenberry, Donald O; Morin, Roger H

2004-01-01

A commercially available electromagnetic flowmeter is attached to a seepage cylinder to create an electromagnetic seepage meter (ESM) for automating measurement of fluxes across the sediment/water interface between ground water and surface water. The ESM is evaluated through its application at two lakes in New England, one where water seeps into the lake and one where water seeps out of the lake. The electromagnetic flowmeter replaces the seepage-meter bag and provides a continuous series of measurements from which temporal seepage processes can be investigated. It provides flow measurements over a range of three orders of magnitude, and contains no protruding components or moving parts. The ESM was used to evaluate duration of seepage disturbance following meter installation and indicated natural seepage rates resumed approximately one hour following meter insertion in a sandy lakebed. Lakebed seepage also varied considerably in response to lakebed disturbances, near-shore waves, and rainfalls, indicating hydrologic processes are occurring in shallow lakebed settings at time scales that have largely gone unobserved.

Geological and geophysical properties of cap rock in a natural CO2 occurrence, Mihályi-Répcelak area, Western Hungary

NASA Astrophysics Data System (ADS)

Király, Csilla; Szamosfalvi, Ágnes; Sendula, Eszter; Páles, Mariann; Kovács, István; Kónya, Péter; Falus, György; Szabó, Csaba

2015-04-01

The physical and geochemical consistency of the cap rock is primarily important for safe geological storage of CO2.. As a consequence of CO2 injection reactions took place between the minerals of the reservoir, the cap rock and CO2 saturated pore water. These reactions may change the mineral composition and petrophysical properties of the storage reservoir as well as the cap rock that provides the only physical barrier that retains carbon dioxide in the target reservoir formation. Study of the natural CO2 occurrences delivers information to understand which properties of a cap rock provide the sustainable closure and retainment. Knowledge of the long term effect of CO2 on the behavior of the cap rock is an important input in the selection procedure of a potential CO2 injection site. Yet, very few data exist on geochemical properties and reactivity of the cap rocks. During normal commercial operations the reservoir is typically cored, but not the cap rock. This study may enhance our knowledge about possible mineralogical reactions, which can occur in clayey-aleuritic cap rocks. The Mihályi-Répcelak natural CO2 occurrence is believed to be leakage safe. There is no known seepage on the surface. It is suggested that the aleuritic clay rich cap rock occurring at the natural reservoir can stop CO2 migration into other reservoirs or to the surface. The most important characteristics of cap rocks that they have low permeability (<0.1 mD) and porosity (eff.por. = 4%) and high clayeyness (approx. 80%). However, we demonstrate that in addition to these parameters the geochemical properties of cap rock is also important. In order to characterize the natural CO2 occurrence, we applied the following analysis, like XRD, FTIR, SEM. The petrophysical properties are determined from the interpretation of geophysical well-logs and grain size distribution. The most important result of this study that adequate petrophysical properties do not completely define the suitability of a cap rock. The effective porosity (~4 %), permeability (0.026 mD) and clayeyness (~80%) data imply that the studied aleurolites are good cap rocks. The mineral composition of cap rock is similar to that of reservoir rock, however, the ratio of components is different. The mineralogical analysis and petrography yield to the reaction between CO2 and the cap rocks. The most visible effect of CO2 presence is the dawsonite precipitation after albite dissolution within the cap rocks. Therefore, the CO2 may migrate through the cap rocks in geological time scale, however the total system could be leakage safe.

Utilizing geochemical, hydrologic, and boron isotopic data to assess the success of a salinity and selenium remediation project, Upper Colorado River Basin, Utah

USGS Publications Warehouse

Naftz, D.L.; Bullen, T.D.; Stolp, B.J.; Wilkowske, C.D.

2008-01-01

Stream discharge and geochemical data were collected at two sites along lower Ashley Creek, Utah, from 1999 to 2003, to assess the success of a site specific salinity and Se remediation project. The remediation project involved the replacement of a leaking sewage lagoon system that was interacting with Mancos Shale and increasing the dissolved salinity and Se load in Ashley Creek. Regression modeling successfully simulated the mean daily dissolved salinity and Se loads (R2 values ranging from 0.82 to 0.97) at both the upstream (AC1) and downstream (AC2/AC2A) sites during the study period. Prior to lagoon closure, net gain in dissolved-salinity load exceeded 2177??metric tons/month and decreased after remediation to less than 590??metric tons/month. The net gain in dissolved Se load during the same pre-closure period exceeded 120??kg/month and decreased to less than 18??kg/month. Sen's slope estimator verified the statistical significance of the modeled reduction in monthly salinity and Se loads. Measured gain in dissolved constituent loads during seepage tests conducted during September and November 2003 ranged from 0.334 to 0.362??kg/day for dissolved Se and 16.9 to 26.1??metric tons/day for dissolved salinity. Stream discharge and changes in the isotopic values of delta boron-11 (??11B) were used in a mixing model to differentiate between constituent loadings contributed by residual sewage effluent and naturally occurring ground-water seepage entering Ashley Creek. The majority of the modeled ??11B values of ground-water seepage were positive, indicative of minimal seepage contributions from sewage effluent. The stream reach between sites S3 and AC2A contained a modeled ground-water seepage ??11B value of - 2.4???, indicative of ground-water seepage composed of remnant water still draining from the abandoned sewage lagoons.

Utilizing geochemical, hydrologic, and boron isotopic data to assess the success of a salinity and selenium remediation project, Upper Colorado River Basin, Utah.

PubMed

Naftz, David L; Bullen, Thomas D; Stolp, Bert J; Wilkowske, Christopher D

2008-03-15

Stream discharge and geochemical data were collected at two sites along lower Ashley Creek, Utah, from 1999 to 2003, to assess the success of a site specific salinity and Se remediation project. The remediation project involved the replacement of a leaking sewage lagoon system that was interacting with Mancos Shale and increasing the dissolved salinity and Se load in Ashley Creek. Regression modeling successfully simulated the mean daily dissolved salinity and Se loads (R(2) values ranging from 0.82 to 0.97) at both the upstream (AC1) and downstream (AC2/AC2A) sites during the study period. Prior to lagoon closure, net gain in dissolved-salinity load exceeded 2177 metric tons/month and decreased after remediation to less than 590 metric tons/month. The net gain in dissolved Se load during the same pre-closure period exceeded 120 kg/month and decreased to less than 18 kg/month. Sen's slope estimator verified the statistical significance of the modeled reduction in monthly salinity and Se loads. Measured gain in dissolved constituent loads during seepage tests conducted during September and November 2003 ranged from 0.334 to 0.362 kg/day for dissolved Se and 16.9 to 26.1 metric tons/day for dissolved salinity. Stream discharge and changes in the isotopic values of delta boron-11 (delta(11)B) were used in a mixing model to differentiate between constituent loadings contributed by residual sewage effluent and naturally occurring ground-water seepage entering Ashley Creek. The majority of the modeled delta(11)B values of ground-water seepage were positive, indicative of minimal seepage contributions from sewage effluent. The stream reach between sites S3 and AC2A contained a modeled ground-water seepage delta(11)B value of -2.4 per thousand, indicative of ground-water seepage composed of remnant water still draining from the abandoned sewage lagoons.

Geoelectrical Methods and Monitoring for Dam Safety Assessment, Republic of Korea

NASA Astrophysics Data System (ADS)

Lim, S. K.; Oldenburg, D.; Kang, S.; Song, S. H.

2016-12-01

Geoelectrical methods and monitoring to detect the seepage and internal erosion are essential for the safety assessment of earth dams. This work aims to develop improved methodologies to analyze the observed data and to monitor changes in seepage flow using direct current (DC) and self-potential (SP) methods. The seasonal variation of water level at dams causes a change in seepage and water saturation and hence alters the resistivity of the dam material. DC data are sensitive to water saturation and hence changes in saturation can be obtained by repeatedly measuring DC data. However, a more diagnostic parameter for safety assessment is fluid flow, and resistivity is only weakly coupled to that. Fortunately SP signals are directly related to fluid flow, and thus an SP survey has the potential to characterize fluid flow through the earth matrix. In Korea, the safety assessment of earth fill dams has been dealt by Korea Rural Community Corporation (KRC). Most of the dams are relatively old ( >50 years), hence assessing deterioration and corresponding seepage of those dams are crucial. In order to evaluate the engineering geological properties of the soil at earth dams in Korea, two boreholes in each dam were drilled to a bedrock depth that exceeds the height of the dam. A large set of field tests, including standard penetration tests (SPT) and in-situ permeability tests, were carried out along the boreholes. However, seepage paths in the dam is complex hence those limited measurements at a few points is not sufficient to delineate the zone of preferential seepage flow. For this, KRC developed permanent DC monitoring systems at a number of agricultural dams in Korea. The data were automatically collected every 6 hours. During the monitoring, the measurements of the water level at two boreholes were gathered at the same time. In this presentation we select an agricultural dam and delineate an anomalous leakage zone by inverting and interpreting time-lapse DC resistivity data acquired under conditions of variable water level. We use these results to simulate SP signals and investigate their potential in monitoring seepage. Our results lay the foundation for developing an automated analysis of DC and SP data to recognize normal and abnormal conditions and to provide an alert when variations beyond a specified threshold are detected.

Response of rock-fissure seepage to snowmelt in Mount Taihang slope-catchment, North China.

PubMed

Cao, Jiansheng; Liu, Changming; Zhang, Wanjun

2013-01-01

The complex physiographic and hydrogeological systems of mountain terrains facilitate intense rock-fissure seepages and multi-functional ecological interactions. As mountain eco-hydrological terrains are the common water sources of river basins across the globe, it is critical to build sufficient understanding into the hydrological processes in this unique ecosystem. This study analyzes infiltration and soil/rock-fissure seepage processes from a 65 mm snowfall/melt in November 2009 in the typical granitic gneiss slope catchment in the Taihang Mountains. The snowfall, snowmelt and melt-water processes are monitored using soil-water time-domain reflectometry (TDR) probes and tipping bucket flowmeters. The results suggest that snowmelt infiltration significantly influences soil/rock water seepage in the 0-100 cm soil depth of the slope-catchment. It is not only air temperature that influences snowmelt, but also snowmelt infiltration and rock-fissure seepage. Diurnal variations in rock-fissure seepage are in close correlation with air temperature (R(2) > 0.7). Temperature also varies with soil/rock water viscosity, which element in turn influences soil/rock water flow. Invariably, water dynamics in the study area is not only a critical water supply element for domestic, industrial and agricultural uses, but also for food security and social stability.

Integrating seepage heterogeneity with the use of ganged seepage meters

USGS Publications Warehouse

Rosenberry, D.O.

2005-01-01

The usefulness of standard half-barrel seepage meters for measurement of fluxes between groundwater, and surface water is limited by the small bed area that each measurement represents and the relatively large associated labor costs. Standard half-barrel cylinders were ganged together to allow one measurement of the summed seepage through all of the meters, reducing labor cost and increasing the representative area of measurement. Comparisons of ganged versus individual-meter measurements at two lakes, under both inseepage and outseepage conditions, indicate little loss of efficiency resulting from routing seepage water through the ganging system. Differences between summed and ganged seepage rates were not significant for all but the fastest rates of seepage. At flow rates greater than about 250 mL min-1, ganged values were as low as 80% of summed values. Ganged-meter head losses also were calculated to determine their significance relative to hydraulic-head gradients measured at the field sites. The calculated reduction in hydraulic gradient beneath the seepage meters was significant only for the largest measured seepage rates. A calibration tank was used to determine single-meter and ganged-meter efficiencies compared to known seepage rates. Single-cylinder seepage meters required an average correction factor of 1.05 to convert measured to actual values, whereas the ganged measurements made in the tank required a larger correction factor of 1.14. Although manual measurements were used in these tests, the concept of ganging seepage cylinders also would be useful when used in conjunction with automated flowmeters. ?? 2005, by the American Society of Limnology and Oceanography, Inc.

Tectonic impact on the dynamics of CO2-rich fluid migration in Utah

NASA Astrophysics Data System (ADS)

Nadine, E. Z.; Jean Luc, F.; Remy, D.; Battani, A.; Olivier, V.

2009-12-01

With the objective to rank the first order parameters acting in the long term CO2 storage, IFP is developing an integrated study based on the analytical results around the natural silici-clastic analogue of the Colorado Plateau in Utah. What are the dominant parameters which governed the fluid/gas migration in front of the Sevier fold-and-thrust Belt, particularly the CO2-enriched ones? Several sites have been investigated in Utah and Idaho provinces; in the Colorado Plateau, East and in front of the Sevier fold-and-thrust belt, as well as in the Basin & Range geological province North and South West of Salt Lake city (Sevier basin). As a first site selection, three distinct structural provinces have been analysed depending on their seal/reservoir characteristics for confinement: the Green River leaking area (Utah), where large WNW-ESE faults (Salt Wash, Little Wash F...) show several water, oil and gas (CO2, HC) seepages; the Basin & Range province (Utah & Idaho provinces) where low-angle normal faults are seismically active (leaking locally); and the Canyonlands zone (Utah), south of the Moab fault, where the system is well confined. The migration pathways used by composite gas and particularly CO2-enriched fluids (in the Green River area) combined with a reducing agent are locally easily recognisable by the bleaching effect where some reservoir levels or the faults pathways have been flushed. The architecture of the paleo and active fluid migration network can thus be mapped. As a second selective ranking, natural gas have been sampled either from oil/gas producing wells in the Moab area and Ferron Valley, or from natural seepages along leaking fault sections or from geysers along the Green-River fault system. The results, based on noble gas isotope analyses (Battani et al, AGU fall meeting 2009) show that 3 distinct provinces can be "isolated", either marked by the occurrence of mantle-derived CO2, or mixed mantle/crustal CO2 signature of varying ratio. How to explain the existence of these distinct provinces? Is it due to the physical properties of the reservoirs, to the evolution of the fracture and fault patterns changing through time in connection with paleostress fields, to the occurrence of a thick salt pillow in the Moab area which has driven the tectonic style and played as local seal, to the shale sealing properties when PCO2 increased at depth to the physical phase of the CO2 during migration or storage (dissolved, super-critical or gas), or finally to the seismic cyclicity. A possible strong linkage between the seismicity and the volcanic activity, corresponding to large CO2-rich gas expel, have been investigated. In order to constrain the architecture of the deep buried reservoirs and traps we analyzed the deformation through analogue models, the models have been acquired with X-Ray tomography at IFP. These parameters have been analysed for the three investigated areas, allowing to propose an integrated model of the local circulation and/or storage of the CO2-enriched fluid for each area.

Carbon dioxide dynamics in a lake and a reservoir on a tropical island (Bali, Indonesia).

PubMed

Macklin, Paul A; Suryaputra, I Gusti Ngurah Agung; Maher, Damien T; Santos, Isaac R

2018-01-01

Water-to-air carbon dioxide fluxes from tropical lakes and reservoirs (artificial lakes) may be an important but understudied component of global carbon fluxes. Here, we investigate the seasonal dissolved carbon dioxide (CO2) dynamics in a lake and a reservoir on a tropical volcanic island (Bali, Indonesia). Observations were performed over four seasonal surveys in Bali's largest natural lake (Lake Batur) and largest reservoir (Palasari Reservoir). Average CO2 partial pressures in the natural lake and reservoir were 263.7±12.2 μatm and 785.0±283.6 μatm respectively, with the highest area-weighted partial pressures in the wet season for both systems. The strong correlations between seasonal mean values of dissolved oxygen (DO) and pCO2 in the natural lake (r2 = 0.92) suggest that surface water metabolism was an important driver of CO2 dynamics in this deep system. Radon (222Rn, a natural groundwater discharge tracer) explained up to 77% of the variability in pCO2 in the shallow reservoir, suggesting that groundwater seepage was the major CO2 driver in the reservoir. Overall, the natural lake was a sink of atmospheric CO2 (average fluxes of -2.8 mmol m-2 d-1) while the reservoir was a source of CO2 to the atmosphere (average fluxes of 7.3 mmol m-2 d-1). Reservoirs are replacing river valleys and terrestrial ecosystems, particularly throughout developing tropical regions. While the net effect of this conversion on atmospheric CO2 fluxes remains to be resolved, we speculate that reservoir construction will partially offset the CO2 sink provided by deep, volcanic, natural lakes and terrestrial environments.

Saturated CO2 inhibits microbial processes in CO2-vented deep-sea sediments

NASA Astrophysics Data System (ADS)

de Beer, D.; Haeckel, M.; Neumann, J.; Wegener, G.; Inagaki, F.; Boetius, A.

2013-02-01

This study focused on biogeochemical processes and microbial activity in sediments of a natural deep-sea CO2 seepage area (Yonaguni Knoll IV hydrothermal system, Japan). The aim was to assess the influence of the geochemical conditions occurring in highly acidic and CO2 saturated sediments on sulphate reduction (SR) and anaerobic methane oxidation (AOM). Porewater chemistry was investigated from retrieved sediment cores and in situ by microsensor profiling. The sites sampled around a sediment-hosted hydrothermal CO2 vent were very heterogeneous in porewater chemistry, indicating a complex leakage pattern. Near the vents, droplets of liquid CO2 were observed to emanate from the sediments, and the pH reached approximately 4.5 in a sediment depth >6 cm, as determined in situ by microsensors. Methane and sulphate co-occurred in most sediment samples from the vicinity of the vents down to a depth of at least 3 m. However, SR and AOM were restricted to the upper 7-15 cm below seafloor, although neither temperature, low pH, nor the availability of methane and sulphate could be limiting microbial activity. We argue that the extremely high subsurface concentrations of dissolved CO2 (1000-1700 mM), through the ensuing high H2CO3 levels (approx. 1-2 mM) uncouples the proton-motive-force (PMF) and thus inhibits biological energy conservation by ATPase-driven phosphorylation. This limits life to the surface sediment horizons above the liquid CO2 phase, where less extreme conditions prevail. Our results may have to be taken into consideration in assessing the consequences of deep-sea CO2 sequestration on benthic element cycling and on the local ecosystem state.

Characterization of Preferential Ground-Water Seepage From a Chlorinated Hydrocarbon-Contaminated Aquifer to West Branch Canal Creek, Aberdeen Proving Ground, Maryland, 2002-04

USGS Publications Warehouse

Majcher, Emily H.; Phelan, Daniel J.; Lorah, Michelle M.; McGinty, Angela L.

2007-01-01

Wetlands act as natural transition zones between ground water and surface water, characterized by the complex interdependency of hydrology, chemical and physical properties, and biotic effects. Although field and laboratory demonstrations have shown efficient natural attenuation processes in the non-seep wetland areas and stream bottom sediments of West Branch Canal Creek, chlorinated volatile organic compounds are present in a freshwater tidal creek at Aberdeen Proving Ground, Maryland. Volatile organic compound concentrations in surface water indicate that in some areas of the wetland, preferential flow paths or seeps allow transport of organic compounds from the contaminated sand aquifer to the overlying surface water without undergoing natural attenuation. From 2002 through 2004, the U.S. Geological Survey, in cooperation with the Environmental Conservation and Restoration Division of the U.S. Army Garrison, Aberdeen Proving Ground, characterized preferential ground-water seepage as part of an ongoing investigation of contaminant distribution and natural attenuation processes in wetlands at this site. Seep areas were discrete and spatially consistent during thermal infrared surveys in 2002, 2003, and 2004 throughout West Branch Canal Creek wetlands. In these seep areas, temperature measurements in shallow pore water and sediment more closely resembled those in ground water than those in nearby surface water. Generally, pore water in seep areas contaminated with chlorinated volatile organic compounds had lower methane and greater volatile organic compound concentrations than pore water in non-seep wetland sediments. The volatile organic compounds detected in shallow pore water in seeps were spatially similar to the dominant volatile organic compounds in the underlying Canal Creek aquifer, with both parent and anaerobic daughter compounds detected. Seep locations characterized as focused seeps contained the highest concentrations of chlorinated parent compounds, relatively low concentrations of chlorinated daughter compounds, and insignificant concentrations of methane in shallow pore water samples. These seeps were primarily along the creek edge or formed a dendritic-like pattern between the wetland and creek channel. In contrast, seep locations characterized as diffuse seeps contained relatively high concentrations of chlorinated daughter compounds (or a mixture of daughter and parent compounds) and detectable methane concentrations in shallow pore water samples. These seeps were primarily along the wetland boundary. Qualitative thermal infrared surveys coupled with quantitative verification of temperature differences, and screening for volatile organic compound and methane concentrations proved to be effective tools in determining the overall extent of preferential seepage. Hydrologic and physical properties of wetland sediments were characterized at two focused and one diffuse seep location. In the seeps with focused discharge, measured seepage was consistent over the tidal cycle, whereas more variability with tidal fluctuation was measured in the diffuse seep location. At all locations, areas were identified within the general seep boundaries where discharge was minimal. In all cases, the geometric mean of non-zero vertical flux measurements was greater than those previously reported in the non-seep wetland sediments using flow-net analysis. Flux was greater in the focused discharge areas than in the diffuse discharge area, and all fluxes were within the range reported in the literature for wetland discharge. Vertical hydraulic conductivity estimated from seepage flux and a mean vertical gradient at seeps with focused discharge resulted in a minimum hydraulic conductivity two orders of magnitude greater than those estimated in the non-seep sediment. In contrast, vertical conductivity estimates at a diffuse seep were similar to estimates along a nearby line of section through a non-seep area. Horizontal hydraulic cond

Incorporating seepage losses into the unsteady streamflow equations for simulating intermittent flow along mountain front streams

USGS Publications Warehouse

Niswonger, R.G.; Prudic, David E.; Pohll, G.; Constantz, J.

2005-01-01

Seepage losses along numerous mountain front streams that discharge intermittently onto alluvial fans and piedmont alluvial plains are an important source of groundwater in the Basin and Range Province of the Western United States. Determining the distribution of seepage loss along mountain front streams is important when assessing groundwater resources of the region. Seepage loss along a mountain front stream in northern Nevada was evaluated using a one-dimensional unsteady streamflow model. Seepage loss was incorporated into the spatial derivatives of the streamflow equations. Because seepage loss from streams is dependent on stream depth, wetted perimeter, and streambed properties, a two-dimensional variably saturated flow model was used to develop a series of relations between seepage loss and stream depth for each reach. This method works when streams are separated from groundwater by variably saturated sediment. Two periods of intermittent flow were simulated to evaluate the modeling approach. The model reproduced measured flow and seepage losses along the channel. Seepage loss in the spring of 2000 was limited to the upper reaches on the alluvial plain and totaled 196,000 m3, whereas 64% of the seepage loss in the spring of 2004 occurred at the base of the alluvial plain and totaled 273,000 m3. A greater seepage loss at the base of the piedmont alluvial plain is attributed to increased streambed hydraulic conductivity caused by less armoring of the channel. The modeling approach provides a method for quantifying and distributing seepage loss along mountain front streams that cross alluvial fans or piedmont alluvial plains. Copyright 2005 by the American Geophysical Union.

Spatial variability of induced ground-water recharge beneath the Russian River, California

NASA Astrophysics Data System (ADS)

Rosenberry, D. O.; Hatch, C. E.; Cox, M. H.; Zamora, C.; Cloud, A.; Constantz, J. E.; Seymour, D.

2004-12-01

The Sonoma County Water Agency extracts water from the alluvial aquifer adjacent to and beneath the Russian River via large-volume Ranney-type collector wells. To aid in this extraction, the stage of the river is increased approximately 3 meters by an inflatable dam. In addition, raising the dam allows water to be diverted into infiltration basins that are located adjacent to the river. Removal of aquifer water induces large fluxes from surface water to ground water through the beds of the infiltration basins and the river. Total extraction during maximum summer withdrawals via five collector wells indicates an average flux from surface water to ground water through the riverbed and infiltration basins of 153 cm/d. Measurements of flux using in-river and in-pond piezometers, diurnal sediment-temperature data, and seepage meters, indicate that actual seepage fluxes are spatially variable and large seepage fluxes are concentrated in specific locations, some of which may not be intuitive. For example, we expected greatest induced seepage fluxes to occur above laterals that extend beneath the river and deliver water to a collector well. Seepage flux along a transverse transect of the riverbed that was located above laterals from one of the collector wells averaged 10 cm/d. At the same time, seepage flux along a transect that was 500 m upstream, and farther from the influence of the collector-well system, averaged 40 cm/d. Seepage fluxes from the central portion of one of the recharge basins averaged 3 cm/d whereas seepage fluxes near the margin of that infiltration basin averaged 250 cm/d. Seepage fluxes derived from in-stream-piezometer Darcy calculations were surprisingly consistent with seepage fluxes derived from seepage-meter measurements. Seepage fluxes derived from temperature measurements were slightly less comparable to the piezometer and seepage-meter measurements. The 121 cm/d average of all seepage-flux measurements was similar to the spatially-integrated rate (153 cm/d) based on the volume of water extracted from the river by the pumping wells divided by the affected area of the riverbed and the flooded infiltration ponds.

Comparison of Scour and Flow Characteristics Around Circular and Oblong Bridge Piers in Seepage Affected Alluvial Channels

NASA Astrophysics Data System (ADS)

Chavan, Rutuja; Venkataramana, B.; Acharya, Pratik; Kumar, Bimlesh

2018-06-01

The present study examines scour geometry and turbulent flow characteristics around circular and oblong piers in alluvial channel with downward seepage. Experiments were conducted in plane sand bed of non-uniform sand under no seepage, 10% seepage and 15% seepage conditions. Scour depth at oblong pier is significantly lesser than the scour depth at circular one. However, the scour depth at both piers reduces with downward seepage. The measurements show that the velocity and Reynolds stresses are negative near the bed at upstream of piers where the strong reversal occurs. At downstream of oblong pier near the free surface, velocity and Reynolds stresses are less positive; whereas, they are negative at downstream of circular pier. The streamline shape of oblong pier leads to reduce the strength of wake vortices and consequently reversal flow at downstream of pier. With application of downward seepage turbulent kinetic energy is decreasing. The results show that the wake vortices at oblong pier are weaker than the wake vortices at circular pier. The strength of wake vortices diminishes with downward seepage. The Strouhal number is lesser for oblong pier and decreases with downward seepage for both oblong and circular piers.

Seepage erosion mechanisms of bank collapse: three-dimensional seepage particle mobilization and undercutting

USDA-ARS?s Scientific Manuscript database

Seepage flow initiates undercutting, similar to development and headward migration of internal gullies, by liquefaction of soil particles, followed by mass wasting of the bank. Although seepage erosion has three-dimensional characteristics, two-dimensional lysimeters have been used in previous resea...

Impact on sediments and water by release of copper from chalcopyrite bearing rock due to acidic mine drainage

NASA Astrophysics Data System (ADS)

Shukla, Anoop Kant; Pradhan, Manoj; Tiwari, Onkar Nath

2018-04-01

Mining activity causes transition of rock-mass from its original position in earth into open environment. The action of environmental elements such air, water, microorganisms leads to oxidation of minerals which constitute the rock. The oxidation of sulphide minerals in presence of moisture releases acidic mine discharge (AMD). The acidic nature of AMD causes leaching of metals from rock minerals. Dissolution of other minerals may occur upon reaction with AMD. Chalcopyrite (CuFeS2) undergoes oxidation in acidic condition releasing copper among other products. This study reveals contamination of copper in sediment samples and seepage water from the tailing dam of a large copper project in located in central India. Elevation was studied using GIS to ascertain to the topographic elevation of tailing dam area. It was located at relatively high altitude causing seepage to flow away from tailing dam. The seepage water from tailing dam was found to be acidic with mean pH value of 4.0 and elevated copper content. Similarly, sediments from seepage water flow displayed elevated copper concentration. The copper concentration in seepage water was found with a mean value of 10.73 mg/l. The sediments from seepage water flow also displayed elevated copper concentration with mean value of 26.92 g/kg. This indicates impact on sediments by release of copper due to acidic mine drainage.

Thermal Imagery of Groundwater Seeps: Possibilities and Limitations.

PubMed

Mundy, Erin; Gleeson, Tom; Roberts, Mark; Baraer, Michel; McKenzie, Jeffrey M

2017-03-01

Quantifying groundwater flow at seepage faces is crucial because seepage faces influence the hydroecology and water budgets of watersheds, lakes, rivers and oceans, and because measuring groundwater fluxes directly in aquifers is extremely difficult. Seepage faces provide a direct and measurable groundwater flux but there is no existing method to quantitatively image groundwater processes at this boundary. Our objective is to determine the possibilities and limitations of thermal imagery in quantifying groundwater discharge from discrete seeps. We developed a conceptual model of temperature below discrete seeps, observed 20 seeps spectacularly exposed in three dimensions at an unused limestone quarry and conducted field experiments to examine the role of diurnal changes and rock face heterogeneity on thermal imagery. The conceptual model suggests that convective air-water heat exchange driven by temperature differences is the dominant heat transfer mechanism. Thermal imagery is effective at locating and characterizing the flux of groundwater seeps. Areas of active groundwater flow and ice growth can be identified from thermal images in the winter, and seepage rates can be differentiated in the summer. However, the application of thermal imagery is limited by diverse factors including technical issues of image acquisition, diurnal changes in radiation and temperature, and rock face heterogeneity. Groundwater discharge rates could not be directly quantified from thermal imagery using our observations but our conceptual model and experiments suggest that thermal imagery could quantify groundwater discharge when there are large temperature differences, simple cliff faces, non-freezing conditions, and no solar radiation. © 2016, National Ground Water Association.

Temporal variability of exchange between groundwater and surface water based on high-frequency direct measurements of seepage at the sediment-water interface

USGS Publications Warehouse

Rosenberry, Donald O.; Sheibley, Rich W.; Cox, Stephen E.; Simonds, Frederic W.; Naftz, David L.

2013-01-01

Seepage at the sediment-water interface in several lakes, a large river, and an estuary exhibits substantial temporal variability when measured with temporal resolution of 1 min or less. Already substantial seepage rates changed by 7% and 16% in response to relatively small rain events at two lakes in the northeastern USA, but did not change in response to two larger rain events at a lake in Minnesota. However, seepage at that same Minnesota lake changed by 10% each day in response to withdrawals from evapotranspiration. Seepage increased by more than an order of magnitude when a seiche occurred in the Great Salt Lake, Utah. Near the head of a fjord in Puget Sound, Washington, seepage in the intertidal zone varied greatly from −115 to +217 cm d−1 in response to advancing and retreating tides when the time-averaged seepage was upward at +43 cm d−1. At all locations, seepage variability increased by one to several orders of magnitude in response to wind and associated waves. Net seepage remained unchanged by wind unless wind also induced a lake seiche. These examples from sites distributed across a broad geographic region indicate that temporal variability in seepage in response to common hydrological events is much larger than previously realized. At most locations, seepage responded within minutes to changes in surface-water stage and within minutes to hours to groundwater recharge associated with rainfall. Likely implications of this dynamism include effects on water residence time, geochemical transformations, and ecological conditions at and near the sediment-water interface.

Assessment of the hydraulic connection between ground water and the Peace River, west-central Florida

USGS Publications Warehouse

Lewelling, B.R.; Tihansky, A.B.; Kindinger, J.L.

1998-01-01

The hydraulic connection between the Peace River and the underlying aquifers along the length of the Peace River from Bartow to Arcadia was assessed to evaluate flow exchanges between these hydrologic systems. Methods included an evaluation of hydrologic and geologic records and seismic-reflection profiles, seepage investigations, and thermal infrared imagery interpretation. Along the upper Peace River, a progressive long-term decline in streamflow has occurred since 1931 due to a lowering of the potentiometric surface of the Upper Floridan aquifer by as much as 60 feet because of intensive ground-water withdrawals for phosphate mining and agriculture. Another effect from lowering the potentiometric surface has been the cessation of flow at several springs located near and within the Peace River channel, including Kissengen Spring, that once averaged a flow of about 19 million gallons a day. The lowering of ground-water head resulted in flow reversals at locations where streamflow enters sinkholes along the streambed and floodplain. Hydrogeologic conditions along the Peace River vary from Bartow to Arcadia. Three distinctive hydrogeologic areas along the Peace River were delineated: (1) the upper Peace River near Bartow, where ground-water recharge occurs; (2) the middle Peace River near Bowling Green, where reversals of hydraulic gradients occur; and (3) the lower Peace River near Arcadia, where ground-water discharge occurs. Seismic-reflection data were used to identify geologic features that could serve as potential conduits for surface-water and ground-water exchange. Depending on the hydrologic regime, this exchange could be recharge of surface water into the aquifer system or discharge of ground water into the stream channel. Geologic features that would provide pathways for water movement were identified in the seismic record; they varied from buried irregular surfaces to large-scale subsidence flexures and vertical fractures or enlarged solution conduits. Generally, the upper Peace River is characterized by a shallow, buried irregular top of rock, numerous observed sinkholes, and subsidence depressions. The downward head gradient provides potential for the Peace River to lose water to the ground-water system. Along the middle Peace River area, head gradients alternate between downward and upward, creating both recharging and discharging ground-water conditions. Seismic records show that buried, laterally continuous reflectors in the lower Peace River pinch out in the middle Peace River streambed. Small springs have been observed along the streambed where these units pinch out. This area corresponds to the region where highest ground-water seepage volumes were measured during this study. Further south, along the lower Peace River, upward head gradients provide conditions for ground-water discharge into the Peace River. Generally, confinement between the surficial aquifer and the confined ground-water systems in this area is better than to the north. However, localized avenues for surface-water and ground-water interactions may exist along discontinuities observed in seismic reflectors associated with large-scale flexures or subsidence features. Ground-water seepage gains or losses along the Peace River were quantified by making three seepage runs during periods of: (1) low base flow, (2) high base flow, and (3) high flow. Low and high base-flow seepage runs were performed along a 74-mile length of the Peace River, between Bartow and Nocatee. Maximum losses of 17.3 cubic feet per second (11.2 million gallons per day) were measured along a 3.2-mile reach of the upper Peace River. The high-flow seepage run was conducted to quantify losses in the Peace River channel and floodplain between Bartow and Fort Meade. Seepage losses calculated during high-flow along a 7.2-mile reach of the Peace River, from the Clear Springs Mine bridge to the Mobil Mine bridge, were approximately 10 percent of the river flow, or 118 c

Quantity and quality of seepage from two earthen basins used to store livestock waste in southern Minnesota during the first year of operation, 1997-98

USGS Publications Warehouse

Ruhl, James F.

1999-01-01

Seepage from the site B basin (based on 10 samples each from the bottom and sidewall) had chloride concentrations of 11 to 100 mg/L; ammonium-N concentrations of 2.58 mg/L or less; nitrate-N concentrations of 25.7 mg/L or less (except for one concentration of 146 mg/L); and organic-N concentrations of 0.92 mg/L or less. Nitrate-N concentrations in the seepage exceeded the U.S. Environmental Protection Agency (1996). MCL (maximum contaminant level) of 10 mg/L in 17 of 22 samples. Background ground-water quality, however, indicated that nitrate-N concentrations were greater than the MCL prior to operation of the basin. Fecal Coliform bacteria, as at the site A basin, were abundant in the basin wastewater, but not in the seepage.

Heat as a tracer to estimate dissolved organic carbon flux from a restored wetland

USGS Publications Warehouse

Burow, K.R.; Constantz, J.; Fujii, R.

2005-01-01

Heat was used as a natural tracer to characterize shallow ground water flow beneath a complex wetland system. Hydrogeologic data were combined with measured vertical temperature profiles to constrain a series of two-dimensional, transient simulations of ground water flow and heat transport using the model code SUTRA (Voss 1990). The measured seasonal temperature signal reached depths of 2.7 m beneath the pond. Hydraulic conductivity was varied in each of the layers in the model in a systematic manual calibration of the two-dimensional model to obtain the best fit to the measured temperature and hydraulic head. Results of a series of representative best-fit simulations represent a range in hydraulic conductivity values that had the best agreement between simulated and observed temperatures and that resulted in simulated pond seepage values within 1 order of magnitude of pond seepage estimated from the water budget. Resulting estimates of ground water discharge to an adjacent agricultural drainage ditch were used to estimate potential dissolved organic carbon (DOC) loads resulting from the restored wetland. Estimated DOC loads ranged from 45 to 1340 g C/(m2 year), which is higher than estimated DOC loads from surface water. In spite of the complexity in characterizing ground water flow in peat soils, using heat as a tracer provided a constrained estimate of subsurface flow from the pond to the agricultural drainage ditch. Copyright ?? 2005 National Ground Water Association.

MTBE, TBA, and TAME attenuation in diverse hyporheic zones.

PubMed

Landmeyer, James E; Bradley, Paul M; Trego, Donald A; Hale, Kevin G; Haas, Joseph E

2010-01-01

Groundwater contamination by fuel-related compounds such as the fuel oxygenates methyl tert-butyl ether (MTBE), tert-butyl alcohol (TBA), and tert-amyl methyl ether (TAME) presents a significant issue to managers and consumers of groundwater and surface water that receives groundwater discharge. Four sites were investigated on Long Island, New York, characterized by groundwater contaminated with gasoline and fuel oxygenates that ultimately discharge to fresh, brackish, or saline surface water. For each site, contaminated groundwater discharge zones were delineated using pore water geochemistry data from 15 feet (4.5 m) beneath the bottom of the surface water body in the hyporheic zone and seepage-meter tests were conducted to measure discharge rates. These data when combined indicate that MTBE, TBA, and TAME concentrations in groundwater discharge in a 5-foot (1.5-m) thick section of the hyporheic zone were attenuated between 34% and 95%, in contrast to immeasurable attenuation in the shallow aquifer during contaminant transport between 0.1 and 1.5 miles (0.1 to 2.4 km). The attenuation observed in the hyporheic zone occurred primarily by physical processes such as mixing of groundwater and surface water. Biodegradation also occurred as confirmed in laboratory microcosms by the mineralization of U- (14)C-MTBE and U-(14)C-TBA to (14)CO(2) and the novel biodegradation of U- (14)C-TAME to (14)CO(2) under oxic and anoxic conditions. The implication of fuel oxygenate attenuation observed in diverse hyporheic zones suggests an assessment of the hyporheic zone attenuation potential (HZAP) merits inclusion as part of site assessment strategies associated with monitored or engineered attenuation.

A system for calibrating seepage meters used to measure flow between ground water and surface water

USGS Publications Warehouse

Rosenberry, Donald O.; Menheer, Michael A.

2006-01-01

The in-line flowmeter used with this system is incapable of measuring seepage rates below about 7 centimeters per day. Smaller seepage rates can be measured manually. The seepage- control system also can be modified for measuring slower seepage rates with the use of two flowmeters and a slightly different water-routing system, or a fluid-metering pump can be used to control flow through the flux tank instead of an adjustable-height reservoir.

Seepage investigation of the Rio Grande from below Leasburg Dam, Leasburg, New Mexico, to above American Dam, El Paso, Texas, 2014

USGS Publications Warehouse

Briody, Alyse C.; Robertson, Andrew J.; Thomas, Nicole

2016-03-22

Seepage investigations have been conducted annually by the U.S. Geological Survey from 1988 to 1998 and from 2004 to the present (2014) along a 64-mile reach of the Rio Grande from below Leasburg Dam, Leasburg, New Mexico, to above American Dam, El Paso, Texas, as part of the Mesilla Basin monitoring program. Results of the investigation conducted in 2014 are presented in this report. The 2014 seepage investigation was conducted on February 11, 2014, during the low-flow conditions of the non-irrigation season. During the 2014 investigation, discharge was measured at 23 sites along the main-stem Rio Grande and 19 inflow sites within the study reach. Because of extended drought conditions affecting the basin, many sites along the Rio Grande (17 main-stem and 9 inflow) were observed to be dry in February 2014. Water-quality samples were collected during the seepage investigation at sites with flowing water as part of a long-term monitoring effort in the region.Net seepage gain or loss was computed for each subreach (the interval between two adjacent measurement locations along the river) by subtracting the discharge measured at the upstream location from the discharge measured at the closest downstream location along the river and then subtracting any inflow to the river within the subreach. An estimated gain or loss was determined to be meaningful when it exceeded the cumulative measurement uncertainty associated with the net seepage computation. The cumulative seepage loss in the 64-mile study reach in 2014 was 16.0 plus or minus 2.9 cubic feet per second.

Field Evaluation of Seepage Meters in the Coastal Marine Environment

NASA Astrophysics Data System (ADS)

Cable, J. E.; Burnett, W. C.; Chanton, J. P.; Corbett, D. R.; Cable, P. H.

1997-09-01

The response of seepage meters was evaluated in a nearshore marine environment where water motion effects are more pronounced than in lake settings, where these meters have been used traditionally. Temporal and spatial variations of seepage, as well as potential artifacts, were evaluated using empty and 1000-ml pre-filled bag measurements. Time-series measurements confirmed earlier observations that anomalously high fluxes occur during the early stages (≤10 min) of collection. As deployment times increased (30-60 min), measured flow rates stabilized at a level thought to represent the actual seepage flux. Pre-filling the plastic measurement bags effectively alleviated this anomalous, short-term influx. Reliable seepage measurements required deployment times sufficient to allow a net volume of at least 150 ml into the collection bag. Control experiments, designed by placing seepage meters inside sand-filled plastic swimming pools, served as indicators of external effects on these measurements, i.e. they served as seepage meter blanks. When winds were under 15 knots, little evidence was found that water motion caused artifacts in the seepage measurements. Tidal cycle influences on seepage rates were negligible in the present study area, but long-term temporal variations (weeks to months) proved substantial. Observed long-term changes in groundwater flux into the Gulf of Mexico correlated with water table elevation at a nearby monitoring well.

Nitrogen removal and greenhouse gas emissions from constructed wetlands receiving tile drainage water.

PubMed

Groh, Tyler A; Gentry, Lowell E; David, Mark B

2015-05-01

Loss of nitrate from agricultural lands to surface waters is an important issue, especially in areas that are extensively tile drained. To reduce these losses, a wide range of in-field and edge-of-field practices have been proposed, including constructed wetlands. We re-evaluated constructed wetlands established in 1994 that were previously studied for their effectiveness in removing nitrate from tile drainage water. Along with this re-evaluation, we measured the production and flux of greenhouse gases (GHGs) (CO, NO, and CH). The tile inlets and outlets of two wetlands were monitored for flow and N during the 2012 and 2013 water years. In addition, seepage rates of water and nitrate under the berm and through the riparian buffer strip were measured. Greenhouse gas emissions from the wetlands were measured using floating chambers (inundated fluxes) or static chambers (terrestrial fluxes). During this 2-yr study, the wetlands removed 56% of the total inlet nitrate load, likely through denitrification in the wetland. Some additional removal of nitrate occurred in seepage water by the riparian buffer strip along each berm (6.1% of the total inlet load, for a total nitrate removal of 62%). The dominant GHG emitted from the wetlands was CO, which represented 75 and 96% of the total GHG emissions during the two water years. The flux of NO contributed between 3.7 and 13% of the total cumulative GHG flux. Emissions of NO were 3.2 and 1.3% of the total nitrate removed from wetlands A and B, respectively. These wetlands continue to remove nitrate at rates similar to those measured after construction, with relatively little GHG gas loss. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Natural seepage of crude oil into the marine environment

USGS Publications Warehouse

Kvenvolden, K.A.; Cooper, C.K.

2003-01-01

Recent global estimates of crude-oil seepage rates suggest that about 47% of crude oil currently entering the marine environment is from natural seeps, whereas 53% results from leaks and spills during the extraction, transportation, refining, storage, and utilization of petroleum. The amount of natural crude-oil seepage is currently estimated to be 600,000 metric tons per year, with a range of uncertainty of 200,000 to 2,000,000 metric tons per year. Thus, natural oil seeps may be the single most important source of oil that enters the ocean, exceeding each of the various sources of crude oil that enters the ocean through its exploitation by humankind.

Upward revision of global fossil fuel methane emissions based on isotope database.

PubMed

Schwietzke, Stefan; Sherwood, Owen A; Bruhwiler, Lori M P; Miller, John B; Etiope, Giuseppe; Dlugokencky, Edward J; Michel, Sylvia Englund; Arling, Victoria A; Vaughn, Bruce H; White, James W C; Tans, Pieter P

2016-10-06

Methane has the second-largest global radiative forcing impact of anthropogenic greenhouse gases after carbon dioxide, but our understanding of the global atmospheric methane budget is incomplete. The global fossil fuel industry (production and usage of natural gas, oil and coal) is thought to contribute 15 to 22 per cent of methane emissions to the total atmospheric methane budget. However, questions remain regarding methane emission trends as a result of fossil fuel industrial activity and the contribution to total methane emissions of sources from the fossil fuel industry and from natural geological seepage, which are often co-located. Here we re-evaluate the global methane budget and the contribution of the fossil fuel industry to methane emissions based on long-term global methane and methane carbon isotope records. We compile the largest isotopic methane source signature database so far, including fossil fuel, microbial and biomass-burning methane emission sources. We find that total fossil fuel methane emissions (fossil fuel industry plus natural geological seepage) are not increasing over time, but are 60 to 110 per cent greater than current estimates owing to large revisions in isotope source signatures. We show that this is consistent with the observed global latitudinal methane gradient. After accounting for natural geological methane seepage, we find that methane emissions from natural gas, oil and coal production and their usage are 20 to 60 per cent greater than inventories. Our findings imply a greater potential for the fossil fuel industry to mitigate anthropogenic climate forcing, but we also find that methane emissions from natural gas as a fraction of production have declined from approximately 8 per cent to approximately 2 per cent over the past three decades.

Reactive-transport modeling of iron diagenesis and associated organic carbon remineralization in a Florida (USA) subterranean estuary

USGS Publications Warehouse

Roy, Moutusi; Martin, Jonathan B.; Smith, Christopher G.; Cable, Jaye E.

2011-01-01

Iron oxides are important terminal electron acceptors for organic carbon (OC) remineralization in subterranean estuaries, particularly where oxygen and nitrate concentrations are low. In Indian River Lagoon, Florida, USA, terrestrial Fe-oxides dissolve at the seaward edge of the seepage face and flow upward into overlying marine sediments where they precipitate as Fe-sulfides. The dissolved Fe concentrations vary by over three orders of magnitude, but Fe-oxide dissolution rates are similar across the 25-m wide seepage face, averaging around 0.21 mg/cm2/yr. The constant dissolution rate, but differing concentrations, indicate Fe dissolution is controlled by a combination of increasing lability of dissolved organic carbon (DOC) and slower porewater flow velocities with distance offshore. In contrast, the average rate constants of Fe-sulfide precipitation decrease from 21.9 × 10-8 s-1 to 0.64 × 10-8 s-1 from the shoreline to the seaward edge of the seepage face as more oxygenated surface water circulates through the sediment. The amount of OC remineralized by Fe-oxides varies little across the seepage face, averaging 5.34 × 10-2 mg/cm2/yr. These rates suggest about 3.4 kg of marine DOC was remineralized in a 1-m wide, shore-perpendicular strip of the seepage face as the terrestrial sediments were transgressed over the past 280 years. During this time, about 10 times more marine solid organic carbon (SOC) accumulated in marine sediments than were removed from the underlying terrestrial sediments. Indian River Lagoon thus appears to be a net sink for marine OC.

Advances in Using Fiber-Optic Distributed Temperature Sensing to Identify the Mixing of Waters

NASA Astrophysics Data System (ADS)

Briggs, M. A.; Day-Lewis, F. D.; Rosenberry, D. O.; Harvey, J. W.; Lane, J. W., Jr.; Hare, D. K.; Boutt, D. F.; Voytek, E. B.; Buckley, S.

2014-12-01

Fiber-optic distributed temperature sensing (FO-DTS) provides thermal data through space and time along linear cables. When installed along a streambed, FO-DTS can capture the influence of upwelling groundwater (GW) as thermal anomalies. The planning of labor-intensive physical measurements can make use of FO-DTS data to target areas of focused GW discharge that can disproportionately affect surface-water (SW) quality and temperature. Typical longitudinal FO-DTS spatial resolution ranges 0.25 to1.0 m, and cannot resolve small-scale water-column mixing or sub-surface diurnal fluctuations. However, configurations where the cable is wrapped around rods can improve the effective vertical resolution to sub-centimeter scales, and the pipes can be actively heated to induce a thermal tracer. Longitudinal streambed and high-resolution vertical arrays were deployed at the upper Delaware River (PA, USA) and the Quashnet River (MA, USA) for aquatic habitat studies. The resultant datasets exemplify the varied uses of FO-DTS. Cold anomalies found along the Delaware River steambed coincide with zones of known mussel populations, and high-resolution vertical array data showed relatively stable in-channel thermal refugia. Cold anomalies at the Quashnet River identified in 2013 were found to persist in 2014, and seepage measurements and water samples at these locations showed high GW flux with distinctive chemistry. Cable location is paramount to seepage identification, particularly in faster flowing deep streams such as the Quashnet and Delaware Rivers where steambed FO-DTS identified many seepage zones with no surface expression. The temporal characterization of seepage dynamics are unique to FO-DTS. However, data from Tidmarsh Farms, a cranberry bog restoration site in MA, USA indicate that in slower flowing shallow steams GW inflow affects surface temperature; therefore infrared imaging can provide seepage location information similar to FO-DTS with substantially less effort.

A pragmatic method for estimating seepage losses for small reservoirs with application in rural India

NASA Astrophysics Data System (ADS)

Oblinger, Jennifer A.; Moysey, Stephen M. J.; Ravindrinath, Rangoori; Guha, Chiranjit

2010-05-01

SummaryThe informal construction of small dams to capture runoff and artificially recharge ground water is a widespread strategy for dealing with water scarcity. A lack of technical capacity for the formal characterization of these systems, however, is often an impediment to the implementation of effective watershed management practices. Monitoring changes in reservoir storage provides a conceptually simple approach to quantify seepage, but does not account for the losses occurring when seepage is balanced by inflows to the reservoir and the stage remains approximately constant. To overcome this problem we evaluate whether a physically-based volume balance model that explicitly represents watershed processes, including reservoir inflows, can be constrained by a limited set of data readily collected by non-experts, specifically records of reservoir stage, rainfall, and evaporation. To assess the impact of parameter non-uniqueness associated with the calibration of the non-linear model, we perform a Monte Carlo analysis to quantify uncertainty in the total volume of water contributed to the subsurface by the 2007 monsoon for a dam located in the Deccan basalts near the village of Salri in Madhya Pradesh, India. The Monte Carlo analysis demonstrated that subsurface losses from the reservoir could be constrained with the available data, but additional measurements are required to constrain reservoir inflows. Our estimate of seepage from the reservoir (7.0 ± 0.6 × 10 4 m 3) is 3.5 times greater than the recharge volume estimated by considering reservoir volume changes alone. This result suggests that artificial recharge could be significantly underestimated when reservoir inflows are not explicitly included in models. Our seepage estimate also accounts for about 11% of rainfall occurring upstream of the dam and is comparable in magnitude to natural ground water recharge, thereby indicating that the reservoir plays a significant role in the hydrology of this small watershed.

The importance of groundwater discharge to the methane budgets of nearshore and continental shelf waters of the northeastern Gulf of Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bugna, G.C.; Chanton, J.P.; Cable, P.H.

1996-12-01

Methane concentrations in groundwater (wells, sinkholes, and springs) averaged 61 {+-} 9 {mu}M, while concentrations in nearshore and continental shelf waters within the study area averaged 62 {+-} 7 nM and 27 {+-} 5 nM, respectively. We tested the hypothesis that the three orders of magnitude difference between groundwater and seawater concentration would make CH{sub 4} an indicator of submarine groundwater discharge to surficial waters. Methane budgets for nearshore and continental shelf water columns were consistent with the hypothesis that groundwater seepage or seawater recirculation through the seabed is the dominant source of CH{sub 4} relative to benthic diffusive flux,more » riverine flux, and in situ water column production. Seepage/recirculation appears to account for approximately 83-99% of the total CH{sub 4} input into the water column within the study area. Utilizing measured porewater CH{sub 4} concentrations, the calculated amounts of seepage required to support the observed benthic fluxes were comparable to seepage rates measured in the field. Nearshore seepage meter transacts showed a strong and direct correlation between the integrated quantity of groundwater seepage along a shoreline and the inventory of CH{sub 4} in those waters. Our study further showed a similar correlation between {sup 222}Rn (another potential groundwater tracer) and CH{sub 4} in offshore waters supporting the hypothesis of a common benthic source for these constituents. 67 refs., 10 figs., 2 tabs.« less

Investigation of Seepage Meter Measurements in Steady Flow and Wave Conditions.

PubMed

Russoniello, Christopher J; Michael, Holly A

2015-01-01

Water exchange between surface water and groundwater can modulate or generate ecologically important fluxes of solutes across the sediment-water interface. Seepage meters can directly measure fluid flux, but mechanical resistance and surface water dynamics may lead to inaccurate measurements. Tank experiments were conducted to determine effects of mechanical resistance on measurement efficiency and occurrence of directional asymmetry that could lead to erroneous net flux measurements. Seepage meter efficiency was high (average of 93%) and consistent for inflow and outflow under steady flow conditions. Wave effects on seepage meter measurements were investigated in a wave flume. Seepage meter net flux measurements averaged 0.08 cm/h-greater than the expected net-zero flux, but significantly less than theoretical wave-driven unidirectional discharge or recharge. Calculations of unidirectional flux from pressure measurements (Darcy flux) and theory matched well for a ratio of wave length to water depth less than 5, but not when this ratio was greater. Both were higher than seepage meter measurements of unidirectional flux made with one-way valves. Discharge averaged 23% greater than recharge in both seepage meter measurements and Darcy calculations of unidirectional flux. Removal of the collection bag reduced this net discharge. The presence of a seepage meter reduced the amplitude of pressure signals at the bed and resulted in a nearly uniform pressure distribution beneath the seepage meter. These results show that seepage meters may provide accurate measurements of both discharge and recharge under steady flow conditions and illustrate the potential measurement errors associated with dynamic wave environments. © 2014, National Ground Water Association.

Evaluation of 2D resistivity imaging technique for delineating subsurface seepage of hydrocarbon-contaminated water southeast of Karbala city, Iraq.

PubMed

Al-Menshed, Firas H; Thabit, Jassim M

2017-03-01

2D imaging technique was applied in (8) transects near a pit of contaminated water near contaminated well southeast of Karbala city, Iraq. Each transect was 30 m long with 1 m electrode spacing. Data acquisition was fulfilled by using Wenner electrode array. The resistivity of water-contaminated zone is found less than 3Ω.m and the top dry zone recorded relatively high resistivity (more than 170Ω.m). It is found that the greatest amount of seepage was found moving towards northeast direction coincided with groundwater movement direction, whereas there was no movement towards northwest and southeast directions and restricted on the closest areas to the pit location. The outcomes suggested that the 2D imaging technique is a successful and powerful tool in separating contaminated zone from clear one and in detecting underground seepage depth and moving direction.

Microbial Community Response to Simulated Petroleum Seepage in Caspian Sea Sediments

PubMed Central

Stagars, Marion H.; Mishra, Sonakshi; Treude, Tina; Amann, Rudolf; Knittel, Katrin

2017-01-01

Anaerobic microbial hydrocarbon degradation is a major biogeochemical process at marine seeps. Here we studied the response of the microbial community to petroleum seepage simulated for 190 days in a sediment core from the Caspian Sea using a sediment-oil-flow-through (SOFT) system. Untreated (without simulated petroleum seepage) and SOFT sediment microbial communities shared 43% bacterial genus-level 16S rRNA-based operational taxonomic units (OTU0.945) but shared only 23% archaeal OTU0.945. The community differed significantly between sediment layers. The detection of fourfold higher deltaproteobacterial cell numbers in SOFT than in untreated sediment at depths characterized by highest sulfate reduction rates and strongest decrease of gaseous and mid-chain alkane concentrations indicated a specific response of hydrocarbon-degrading Deltaproteobacteria. Based on an increase in specific CARD-FISH cell numbers, we suggest the following groups of sulfate-reducing bacteria to be likely responsible for the observed decrease in aliphatic and aromatic hydrocarbon concentration in SOFT sediments: clade SCA1 for propane and butane degradation, clade LCA2 for mid- to long-chain alkane degradation, clade Cyhx for cycloalkanes, pentane and hexane degradation, and relatives of Desulfobacula for toluene degradation. Highest numbers of archaea of the genus Methanosarcina were found in the methanogenic zone of the SOFT core where we detected preferential degradation of long-chain hydrocarbons. Sequencing of masD, a marker gene for alkane degradation encoding (1-methylalkyl)succinate synthase, revealed a low diversity in SOFT sediment with two abundant species-level MasD OTU0.96. PMID:28503173

Microseismicity Linked to Gas Migration and Leakage on the Western Svalbard Shelf

NASA Astrophysics Data System (ADS)

Franek, Peter; Plaza-Faverola, Andreia; Mienert, Jürgen; Buenz, Stefan; Ferré, Bénédicte; Hubbard, Alun

2017-12-01

The continental margin off Prins Karls Forland, western Svalbard, is characterized by widespread natural gas seepage into the water column at and upslope of the gas hydrate stability zone. We deployed an ocean bottom seismometer integrated into the MASOX (Monitoring Arctic Seafloor-Ocean Exchange) automated seabed observatory at the pinch-out of this zone at 389 m water depth to investigate passive seismicity over a continuous 297 day period from 13 October 2010. An automated triggering algorithm was applied to detect over 220,000 short duration events (SDEs) defined as having a duration of less than 1 s. The analysis reveals two different types of SDEs, each with a distinctive characteristic seismic signature. We infer that the first type consists of vocal signals generated by moving mammals, likely finback whales. The second type corresponds to signals with a source within a few hundred meters of the seismometer, either due east or west, that vary on short (˜tens of days) and seasonal time scales. Based on evidence of prevalent seafloor seepage and subseafloor gas accumulations, we hypothesize that the second type of SDEs is related to subseafloor fluid migration and gas seepage. Furthermore, we postulate that the observed temporal variations in microseismicity are driven by transient fluid release and due to the dynamics of thermally forced, seasonal gas hydrate decomposition. Our analysis presents a novel technique for monitoring the duration, intensity, and periodicity of fluid migration and seepage at the seabed and can help elucidate the environmental controls on gas hydrate decomposition and release.

Hydrological and chemical estimates of the water balance of a closed-basin lake in north central Minnesota

USGS Publications Warehouse

LaBaugh, James W.; Winter, Thomas C.; Rosenberry, Donald O.; Schuster, Paul F.; Reddy, Michael M.; Aiken, George R.

1997-01-01

Chemical mass balances for sodium, magnesium, chloride, dissolved organic carbon, and oxygen 18 were used to estimate groundwater seepage to and from Williams Lake, Minnesota, over a 15-month period, from April 1991 through June 1992. Groundwater seepage to the lake and seepage from the lake to groundwater were determined independently using a flow net approach using data from water table wells installed as part of the study. Hydrogeological analysis indicated groundwater seepage to the lake accounted for 74% of annual water input to the lake; the remainder came from atmospheric precipitation, as determined from a gage in the watershed and from nearby National Weather Service gages. Seepage from the lake accounted for 69% of annual water losses from the lake; the remainder was removed by evaporation, as determined by the energy budget method. Calculated annual water loss exceeded calculated annual water gain, and this imbalance was double the value of the independently measured decrease in lake volume. Seepage to the lake determined from oxygen 18 was larger (79% of annual water input) than that determined from the flow net approach and made the difference between calculated annual water gain and loss consistent with the independently measured decrease in lake volume. Although the net difference between volume of seepage to the lake and volume of seepage from the lake was 1% of average lake volume, movement of water into and out of the lake by seepage represented an annual exchange of groundwater with the lake equal to 26–27% of lake volume. Estimates of seepage to the lake from sodium, magnesium, chloride, and dissolved organic carbon did not agree with the values determined from flow net approach or oxygen 18. These results indicated the importance of using a combination of hydrogeological and chemical approaches to define volume of seepage to and from Williams Lake and identify uncertainties in chemical fluxes.

Hydrocarbon Degradation in Caspian Sea Sediment Cores Subjected to Simulated Petroleum Seepage in a Newly Designed Sediment-Oil-Flow-Through System.

PubMed

Mishra, Sonakshi; Wefers, Peggy; Schmidt, Mark; Knittel, Katrin; Krüger, Martin; Stagars, Marion H; Treude, Tina

2017-01-01

The microbial community response to petroleum seepage was investigated in a whole round sediment core (16 cm length) collected nearby natural hydrocarbon seepage structures in the Caspian Sea, using a newly developed Sediment-Oil-Flow-Through (SOFT) system. Distinct redox zones established and migrated vertically in the core during the 190 days-long simulated petroleum seepage. Methanogenic petroleum degradation was indicated by an increase in methane concentration from 8 μM in an untreated core compared to 2300 μM in the lower sulfate-free zone of the SOFT core at the end of the experiment, accompanied by a respective decrease in the δ 13 C signal of methane from -33.7 to -49.5‰. The involvement of methanogens in petroleum degradation was further confirmed by methane production in enrichment cultures from SOFT sediment after the addition of hexadecane, methylnapthalene, toluene, and ethylbenzene. Petroleum degradation coupled to sulfate reduction was indicated by the increase of integrated sulfate reduction rates from 2.8 SO 4 2- m -2 day -1 in untreated cores to 5.7 mmol SO 4 2- m -2 day -1 in the SOFT core at the end of the experiment, accompanied by a respective accumulation of sulfide from 30 to 447 μM. Volatile hydrocarbons (C2-C6 n -alkanes) passed through the methanogenic zone mostly unchanged and were depleted within the sulfate-reducing zone. The amount of heavier n -alkanes (C10-C38) decreased step-wise toward the top of the sediment core and a preferential degradation of shorter (C30) was seen during the seepage. This study illustrates, to the best of our knowledge, for the first time the development of methanogenic petroleum degradation and the succession of benthic microbial processes during petroleum passage in a whole round sediment core.

CO 2-induced chemo-mechanical alteration in reservoir rocks assessed via batch reaction experiments and scratch testing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aman, Michael; Espinoza, D. Nicolas; Ilgen, Anastasia G.

Here, the injection of carbon dioxide (CO 2) into geological formations results in a chemical re-equilibration between the mineral assemblage and the pore fluid, with ensuing mineral dissolution and re-precipitation. Hence, target rock formations may exhibit changes of mechanical and petrophysical properties due to CO 2 exposure. We conducted batch reaction experiments with Entrada Sandstone and Summerville Siltstone exposed to de-ionized water and synthetic brine under reservoir pressure (9–10 MPa) and temperature (80°C) for up to four weeks. Samples originate from the Crystal Geyser field site, where a naturally occurring CO 2 seepage alters portions of these geologic formations. Wemore » conducted micro-scratch tests on rock samples without alteration, altered under laboratory conditions, and naturally altered over geologic time. Scratch toughness and hardness decrease as a function of exposure time and water salinity up to 52% in the case of Entrada and 87% in the case of Summerville after CO 2-induced alteration in the laboratory. Imaging of altered cores with SEM-EDS and X-ray microCT methods show dissolution of carbonate and silica cements and matrix accompanied by minor dissolution of Fe-oxides, clays, and other silicates. Parallel experiments using powdered samples confirm that dissolution of carbonate and silica are the primary reactions. The batch reaction experiments in the autoclave utilize a high fluid to rock volume ratio and represent an end member of possible alteration associated with CO 2 storage systems. These types of tests serve as a pre-screening tool to identify the susceptibility of rock facies to CO 2-related chemical-mechanical alteration during long-term CO 2 storage.« less

CO 2-induced chemo-mechanical alteration in reservoir rocks assessed via batch reaction experiments and scratch testing

DOE PAGES

Aman, Michael; Espinoza, D. Nicolas; Ilgen, Anastasia G.; ...

2017-09-22

Here, the injection of carbon dioxide (CO 2) into geological formations results in a chemical re-equilibration between the mineral assemblage and the pore fluid, with ensuing mineral dissolution and re-precipitation. Hence, target rock formations may exhibit changes of mechanical and petrophysical properties due to CO 2 exposure. We conducted batch reaction experiments with Entrada Sandstone and Summerville Siltstone exposed to de-ionized water and synthetic brine under reservoir pressure (9–10 MPa) and temperature (80°C) for up to four weeks. Samples originate from the Crystal Geyser field site, where a naturally occurring CO 2 seepage alters portions of these geologic formations. Wemore » conducted micro-scratch tests on rock samples without alteration, altered under laboratory conditions, and naturally altered over geologic time. Scratch toughness and hardness decrease as a function of exposure time and water salinity up to 52% in the case of Entrada and 87% in the case of Summerville after CO 2-induced alteration in the laboratory. Imaging of altered cores with SEM-EDS and X-ray microCT methods show dissolution of carbonate and silica cements and matrix accompanied by minor dissolution of Fe-oxides, clays, and other silicates. Parallel experiments using powdered samples confirm that dissolution of carbonate and silica are the primary reactions. The batch reaction experiments in the autoclave utilize a high fluid to rock volume ratio and represent an end member of possible alteration associated with CO 2 storage systems. These types of tests serve as a pre-screening tool to identify the susceptibility of rock facies to CO 2-related chemical-mechanical alteration during long-term CO 2 storage.« less

Analytical Modeling of Groundwater Seepages to St. Lucie Estuary

NASA Astrophysics Data System (ADS)

Lee, J.; Yeh, G.; Hu, G.

2008-12-01

In this paper, six analytical models describing hydraulic interaction of stream-aquifer systems were applied to St Lucie Estuary (SLE) River Estuaries. These are analytical solutions for: (1) flow from a finite aquifer to a canal, (2) flow from an infinite aquifer to a canal, (3) the linearized Laplace system in a seepage surface, (4) wave propagation in the aquifer, (5) potential flow through stratified unconfined aquifers, and (6) flow through stratified confined aquifers. Input data for analytical solutions were obtained from monitoring wells and river stages at seepage-meter sites. Four transects in the study area are available: Club Med, Harbour Ridge, Lutz/MacMillan, and Pendarvis Cove located in the St. Lucie River. The analytical models were first calibrated with seepage meter measurements and then used to estimate of groundwater discharges into St. Lucie River. From this process, analytical relationships between the seepage rate and river stages and/or groundwater tables were established to predict the seasonal and monthly variation in groundwater seepage into SLE. It was found the seepage rate estimations by analytical models agreed well with measured data for some cases but only fair for some other cases. This is not unexpected because analytical solutions have some inherently simplified assumptions, which may be more valid for some cases than the others. From analytical calculations, it is possible to predict approximate seepage rates in the study domain when the assumptions underlying these analytical models are valid. The finite and infinite aquifer models and the linearized Laplace method are good for sites Pendarvis Cove and Lutz/MacMillian, but fair for the other two sites. The wave propagation model gave very good agreement in phase but only fairly agreement in magnitude for all four sites. The stratified unconfined and confined aquifer models gave similarly good agreements with measurements at three sites but poorly at the Club Med site. None of the analytical models presented here can fit the data at this site. To give better estimates at all sites numerical modeling that couple river hydraulics and groundwater flow involving less simplifications of and assumptions for the system may have to be adapted.

Emission of Methane and Heavier Alkanes From the La Brea Tar Pits Seepage Area, Los Angeles

NASA Astrophysics Data System (ADS)

Etiope, G.; Doezema, L. A.; Pacheco, C.

2017-11-01

Natural hydrocarbon (oil and gas) seeps are widespread in Los Angeles, California, due to gas migration, along faults, from numerous subsurface petroleum fields. These seeps may represent important natural contributors of methane (CH4) and heavier alkanes (C2-C4) to the atmosphere, in addition to anthropogenic fossil fuel and biogenic sources. We measured the CH4 flux by closed-chamber method from the La Brea Tar Pits park (0.1 km2), one of the largest seepage sites in Los Angeles. The gas seepage occurs throughout the park, not only from visible oil-asphalt seeps but also diffusely from the soil, affecting grass physiology. About 500 kg CH4 d-1 is emitted from the park, especially along a belt of enhanced degassing that corresponds to the 6th Street Fault. Additional emissions are from bubble plumes in the lake within the park (order of 102-103 kg d-1) and at the intersection of Wilshire Boulevard and Curson Avenue (>130 kg d-1), along the same fault. The investigated area has the highest natural gas flux measured thus far for any onshore seepage zone in the USA. Gas migration, oil biodegradation, and secondary methanogenesis altered the molecular composition of the original gas accumulated in the Salt Lake Oil Field (>300 m deep), leading to high C1/C2+ and i-butane/n-butane ratios. These molecular alterations can be important tracers of natural seepage and should be considered in the atmospheric modeling of the relative contribution of fossil fuel (anthropogenic fugitive emission and natural geologic sources) versus biogenic sources of methane, on local and global scales.

Hydrogeology, groundwater seepage, nitrate distribution, and flux at the Raleigh hydrologic research station, Wake County, North Carolina, 2005-2007

USGS Publications Warehouse

McSwain, Kristen Bukowski; Bolich, Richard E.; Chapman, Melinda J.

2013-01-01

rom 2005 to 2007, the U.S. Geological Survey and the North Carolina Department of Environment and Natural Resources, Division of Water Quality, conducted a study to describe the geologic framework, measure groundwater quality, characterize the groundwater-flow system, and describe the groundwater/surface-water interaction at the 60-acre Raleigh hydrogeologic research station (RHRS) located at the Neuse River Waste Water Treatment Plant in eastern Wake County, North Carolina. Previous studies have shown that the local groundwater quality of the surficial and bedrock aquifers at the RHRS had been affected by high levels of nutrients. Geologic, hydrologic, and water-quality data were collected from 3 coreholes, 12 wells, and 4 piezometers at 3 well clusters, as well as from 2 surface-water sites, 2 multiport piezometers, and 80 discrete locations in the streambed of the Neuse River. Data collected were used to evaluate the three primary zones of the Piedmont aquifer (regolith, transition zone, and fractured bedrock) and characterize the interaction of groundwater and surface water as a mechanism of nutrient transport to the Neuse River. A conceptual hydrogeologic cross section across the RHRS was constructed using new and existing data. Two previously unmapped north striking, nearly vertical diabase dikes intrude the granite beneath the site. Groundwater within the diabase dike appeared to be hydraulically isolated from the surrounding granite bedrock and regolith. A correlation exists between foliation and fracture orientation, with most fractures striking parallel to foliation. Flowmeter logging in two of the bedrock wells indicated that not all of the water-bearing fractures labeled as water bearing were hydraulically active, even when stressed by pumping. Groundwater levels measured in wells at the RHRS displayed climatic and seasonal trends, with elevated groundwater levels occurring during the late spring and declining to a low in the late fall. Vertical gradients in the groundwater discharge area near the Neuse River were complex and were affected by fluctuations in river stage, with the exception of a well completed in a diabase dike. Water-quality data from the wells and surface-water sites at the RHRS were collected continuously as well as during periodic sampling events. Surface-water samples collected from a tributary were most similar in chemical composition to groundwater found in the regolith and transition zone. Nitrate (measured as nitrite plus nitrate, as nitrogen) concentrations in the sampled wells and tributary ranged from about 5 to more than 120 milligrams per liter as nitrogen. Waterborne continuous resistivity profiling conducted on the Neuse River in the area of the RHRS measured areas of low apparent resistivity that likely represent groundwater contaminated by high concentrations of nitrate. These areas were located on either side of a diabase dike and at the outfall of two unnamed tributaries. The diabase dike preferentially directed the discharge of groundwater to the Neuse River and may isolate groundwater movement laterally. Discrete temperature measurements made within the pore water beneath the Neuse River revealed seeps of colder groundwater discharging into warmer surface water near a diabase dike. Water-quality samples collected from the pore water beneath the Neuse River indicated that nitrate was present at concentrations as high as 80 milligrams per liter as nitrogen on the RHRS side of the river. The highest concentrations of nitrate were located within pore water collected from an area near a diabase dike that was identified as a suspected seepage area. Hydraulic head was measured and pore water samples were collected from two 140-centimeter-deep (55.1-inch-deep) multiport piezometers that were installed in bed sediments on opposite sides of a diabase dike. The concentration of nitrate in pore water at a suspected seepage area ranged from 42 to 82 milligrams per liter as nitrogen with a median concentration of 79 milligrams per liter as nitrogen. On the opposite side of the dike, concentrations of nitrate in pore water samples ranged from 3 to 91 milligrams per liter as nitrogen with a median concentration of 52 milligrams per liter. At one of the multiport piezometers the vertical gradient of hydraulic head between the Neuse River and the groundwater was too small to measure. At the multiport piezometer located in the suspected seepage area, an upward gradient of about 0.1 was present and explains the occurrence of higher concentrations of nitrate near the sediment/water interface. Horizontal seepage flux from the surficial aquifer to the edge of the Neuse River was estimated for 2006. Along a 130-foot flow path, the estimated seepage flux ranged from –0.52 to 0.2 foot per day with a median of 0.09 foot per day. The estimated advective horizontal mass flux of nitrate along a 300-foot reach of the Neuse River ranged from –10.9 to 5 pounds per day with a median of 2.2 pounds per day. The total horizontal mass flux of nitrate from the surficial aquifer to the Neuse River along the 130-foot flow path was estimated to be about 750 pounds for all of 2006. Seepage meters were deployed on the bed of the Neuse River in the areas of the multiport piezometers on either side of the diabase dike to estimate rates of vertical groundwater discharge and flux of nitrate. The average estimated daily seepage flux differed by two orders of magnitude between seepage areas. The potential vertical flux of nitrate from groundwater to the Neuse River was estimated at an average of 2.5 grams per day near one of the multiport piezometers and an average of 784 grams per day at the other. These approximations suggest that under some hydrologic conditions there is the potential for substantial quantities of nitrate to discharge from the groundwater to the Neuse River.

Using Heat Pulses for Quantifying 3d Seepage Velocity in Groundwater-Surface Water Interactions, Considering Source Size, Regime, and Dispersion

NASA Astrophysics Data System (ADS)

Zlotnik, V. A.; Tartakovsky, D. M.

2017-12-01

The study is motivated by rapid proliferation of field methods for measurements of seepage velocity using heat tracing and is directed to broadening their potential for studies of groundwater-surface water interactions, and hyporheic zone in particular. In vast majority, existing methods assume vertical or horizontal, uniform, 1D seepage velocity. Often, 1D transport assumed as well, and analytical models of heat transport by Suzuki-Stallman are heavily used to infer seepage velocity. However, both of these assumptions (1D flow and 1D transport) are violated due to the flow geometry, media heterogeneity, and localized heat sources. Attempts to apply more realistic conceptual models still lack full 3D view, and known 2D examples are treated numerically, or by making additional simplifying assumptions about velocity orientation. Heat pulse instruments and sensors already offer an opportunity to collect data sufficient for 3D seepage velocity identification at appropriate scale, but interpretation tools for groundwater-surface water interactions in 3D have not been developed yet. We propose an approach that can substantially improve capabilities of already existing field instruments without additional measurements. Proposed closed-form analytical solutions are simple and well suited for using in inverse modeling. Field applications and ramifications for applications, including data analysis are discussed. The approach simplifies data collection, determines 3D seepage velocity, and facilitates interpretation of relations between heat transport parameters, fluid flow, and media properties. Results are obtained using tensor properties of transport parameters, Green's functions, and rotational coordinate transformations using the Euler angles

Origins of hydrocarbon gas seeping out from offshore mud volcanoes in the Nile delta

NASA Astrophysics Data System (ADS)

Prinzhofer, Alain; Deville, Eric

2013-04-01

This paper discusses the origin of gas seepages (free gas or dissolved gas in ground water or brine) sampled with the Nautile submarine during the Nautinil cruise at the seafloor of the deep water area of the Nile turbiditic system on different mud volcanoes and brine pools. Generally, the gas is wet and includes C1, C2, C3, iC4, nC4, CO2. These gas samples show no evidence of biodegradation which is not the case of the gas present in the deep hydrocarbon accumulations at depth. It indicates that the gas expelled by the mud volcanoes is not issued from direct leakages from deep gas fields. The collected gas samples mainly have a thermogenic origin and show different maturities. Some samples show very high maturities indicating that these seepages are sourced from great depths, below the Messinian salt. Moreover, the different chemical compositions of the gas samples reflect not only differences in maturity but also the fact that the gas finds its origin in different deep source rocks. Carbon dioxide has an organic signature and cannot result from carbonate decomposition or mantle fluids. The crustal-derived radiogenic isotopes show that the analyzed gas samples have suffered a fractionation processes after the production of the radiogenic isotopes, due either to oil occurrence at depth interacting with the flux of gas, and/or fractionation during the fluid migration.

Measurements of seepage losses and gains, East Maui Irrigation diversion system, Maui, Hawaiʻi

USGS Publications Warehouse

Cheng, Chui Ling

2012-01-01

The U.S. Geological Survey conducted a field study from March to October 2011 to identify ditch characteristics and quantify seepage losses and gains in the East Maui Irrigation (EMI) diversion system, east Maui, Hawaiʻi. The EMI diversion system begins at Makapipi Stream in the east and ends at Māliko Gulch in the west. It consists of four primary ditches known as the Wailoa, New Hāmākua, Lowrie, and Haʻikū Ditches. Additional ditches that connect to the four primary ditches include the Koʻolau, Spreckels, Kauhikoa, Spreckels at Pāpaʻaʻea, Manuel Luis, and Center Ditches. Ditch characteristics for about 63 miles of the EMI diversion system, excluding abandoned ditches and stream conveyances, were identified. About 46 miles (73 percent) of the surveyed diversion system are tunnels and 17 miles are open ditches—in which 11 miles are unlined, 3.5 miles are lined, and 2.5 miles are partially lined. The Wailoa, Kauhikoa, and Haʻikū Ditches have greater than 96 percent of their total lengths as tunnels, whereas more than half of the Lowrie Ditch and Spreckels Ditch at Pāpaʻaʻea are open ditches. About 70 percent of the total length of lined open ditches in the EMI diversion system is located along the Koʻolau Ditch, whereas about 67 percent of the total length of unlined open ditches in the diversion system is located along the Lowrie Ditch. Less than 4 percent of the EMI diversion system is partially lined open ditches, and about half of the total partially lined open-ditch length is in the Spreckels Ditch. EMI regularly maintains and repairs the diversion system; therefore, ditch characteristics documented in this report are representative of conditions existing during the period of this study. Discharge measurements were made along 26 seepage-run measurement reaches that are a total of about 15 miles in length. The seepage-run measurement reaches represent 23 percent of the total length of ditches in the EMI diversion system. Discharge measurements were made along the measurement reaches during periods of stable ditch flow in the months of June, August, and September 2011. The discharge measurements indicate that Koʻolau Ditch and Spreckels Ditch at Pāpaʻaʻea generally had seepage losses, whereas Wailoa, Kauhikoa, and New Hāmākua Ditches had seepage gains within the measured reaches. The Manuel Luis, Center, Lowrie, and Haʻikū Ditches had variable seepage losses and gains within the seepage-run measurement reaches. Open-ditch measurement reaches generally had seepage losses that ranged from 0.1 cubic feet per second per mile of ditch at the Lowrie Ditch to 3.0 cubic feet per second per mile at the Koʻolau Ditch. Tunnel measurement reaches generally had seepage gains that ranged from 0.1 cubic feet per second per mile at the Manuel Luis Ditch to 5.2 cubic feet per second per mile at the Wailoa Ditch.

Synthesis, characterization, and activity of Co/Fe alumina/silica supported Ft catalysts and the study of promoter effect of ruthenium

NASA Astrophysics Data System (ADS)

Esumike, Sunday Azubike

The alumina and hybrid alumina-silica FT catalyst were prepared by one-step solgel/oil-drop methods using metal-nitrate-solutions (method-I), and nanoparticle-metaloxides (method-2). The nanoparticle-metal-oxides did not participate in solubility equilibria in contrast to metal nitrate in method-1 causing no metal ion seepage; therefore, method-2 yields higher XRF metal loading efficiency than method-1. The thermal analysis confirmed that the metal loading by method-1 and method-2 involved two different pathways. Method-1 involves solubility equilibria in the conversion of metal-nitrate to metal- hydroxide and finally to metal-oxide, while in method-2 nanoparticle-metal-oxide remained intact during sol-gel-oil-drop and calcination steps. The alumina supported catalysts were dominated by gamma-alumina PXRD peaks in alumina catalysts while amorphous alumino-silicate phase was the bulk of hybrid alumina-silica catalysts. The presence of cobalt oxides (CoO, Co3O4) and iron oxides (FeO, Fe2O3) phases are confirmed in the catalysts prepared by method-1 and method-2. The PXRD analysis indicated weak peak intensities in catalysts with 5 wt. % total metal loading. PXRD pattern confirmed alloy formation in the bimetallic catalysts (CoFe2O4) on alumina support phase gamma-A12 O3. The surface area and pore diameter of hybrid alumina-silica granules (301 - 372 m2/g and 7.3 nm) showed better values than the alumina granules (251 - 256 m2/g and 6.5 nm). The support pore diameter of both types of granules is within the mesoporous range (1 - 50 nm). The morphology of all the catalysts is preserved upon metal loading and heat treatments. The surface characteristics of the sol-gel-oil-drop method prepared catalysts indicate there was no significant pore blockage of the support below 10 wt % total metal loading. The CO conversion of the FT catalysts was measured to screen catalytic active metals and determine the optimum temperatures of the FT reaction for the alumina catalysts. The alumina FT catalysts showed an optimum reaction temperature of 250 °C. Hydrocarbon production and CO conversion of alumina and hybrid alumina-silica FT catalysts were investigated. Among monometallic alumina catalysts, Co(5%) showed a higher CO conversion. The incorporation of Fe to Co increased CO conversion and hydrocarbon production. Increased Fe content in the bimetallic catalysts prepared by combined method-1&2, decreased CO conversion and hydrocarbon production, and increased CO 2 production. The bimetallic nano-Co(2.5%)nano-Fe(2.5%) prepared by method-2 alone showed higher CO conversion comparable to the Co(4%)nano-Fe(l %). Hybrid alumina-silica FT catalysts showed a higher CO conversion than the alumina FT catalysts due to better surface characteristics. The monometallic catalysts showed higher selectivity to C1-C4 hydrocarbon than bimetallic. The bimetallic alumina FT catalysts prepared by method-2 showed slightly higher C5+ selectivity compared to the higher Co catalysts prepared by combined method- I &2. The Ru promotion showed a significant effect on the CO conversion and 11 product distribution of the monometallic catalysts. There was no significant effect on the CO conversion on the (Co-Fe) bimetallic catalysts, but hydrocarbon production slightly increased when promoted by 0.5 wt.% Ru.

Method for estimating spatially variable seepage loss and hydraulic conductivity in intermittent and ephemeral streams

USGS Publications Warehouse

Niswonger, R.G.; Prudic, David E.; Fogg, G.E.; Stonestrom, David A.; Buckland, E.M.

2008-01-01

A method is presented for estimating seepage loss and streambed hydraulic conductivity along intermittent and ephemeral streams using streamflow front velocities in initially dry channels. The method uses the kinematic wave equation for routing streamflow in channels coupled to Philip's equation for infiltration. The coupled model considers variations in seepage loss both across and along the channel. Water redistribution in the unsaturated zone is also represented in the model. Sensitivity of the streamflow front velocity to parameters used for calculating seepage loss and for routing streamflow shows that the streambed hydraulic conductivity has the greatest sensitivity for moderate to large seepage loss rates. Channel roughness, geometry, and slope are most important for low seepage loss rates; however, streambed hydraulic conductivity is still important for values greater than 0.008 m/d. Two example applications are presented to demonstrate the utility of the method.

Support for the Annual Meeting (30th) of the Cognitive Science Society

DTIC Science & Technology

2008-10-01

Schunn Sponsors Co-Chairs: Jennifer Wiley and Christopher Sanchez Member Abstracts Chair: Hedderik Van Rijn Awards Chair: Niels Taatgen...The winner of the 2008 Marr Prize for Best Student Paper is: Michael Frank, Evelina Fedorenko, Edward Gibson (seepage 19 of the program) Language...Stellan Ohlsson, Ute Schmid, Alex Petrov, Hedderik van Rijn, Niels Taatgen. CogSci 2008 Final Program CogSci 2008 Sponsors, Exhibitors, & Advertisers

MTBE, TBA, and TAME attenuation in diverse hyporheic zones

USGS Publications Warehouse

Landmeyer, J.E.; Bradley, P.M.; Trego, D.A.; Hale, K.G.; Haas, J.E.

2010-01-01

Groundwater contamination by fuel-related compounds such as the fuel oxygenates methyl tert-butyl ether (MTBE), tert-butyl alcohol (TBA), and tert-amyl methyl ether (TAME) presents a significant issue to managers and consumers of groundwater and surface water that receives groundwater discharge. Four sites were investigated on Long Island, New York, characterized by groundwater contaminated with gasoline and fuel oxygenates that ultimately discharge to fresh, brackish, or saline surface water. For each site, contaminated groundwater discharge zones were delineated using pore water geochemistry data from 15 feet (4.5 m) beneath the bottom of the surface water body in the hyporheic zone and seepage-meter tests were conducted to measure discharge rates. These data when combined indicate that MTBE, TBA, and TAME concentrations in groundwater discharge in a 5-foot (1.5-m) thick section of the hyporheic zone were attenuated between 34% and 95%, in contrast to immeasurable attenuation in the shallow aquifer during contaminant transport between 0.1 and 1.5 miles (0.1 to 2.4 km). The attenuation observed in the hyporheic zone occurred primarily by physical processes such as mixing of groundwater and surface water. Biodegradation also occurred as confirmed in laboratory microcosms by the mineralization of U- 14C-MTBE and U- 14C-TBA to 14CO2 and the novel biodegradation of U- 14C-TAME to 14CO2 under oxic and anoxic conditions. The implication of fuel oxygenate attenuation observed in diverse hyporheic zones suggests an assessment of the hyporheic zone attenuation potential (HZAP) merits inclusion as part of site assessment strategies associated with monitored or engineered attenuation. ?? 2009 National Ground Water Association.

Drivers of pCO2 dynamics in two contrasting coral reef lagoons: The influence of submarine groundwater discharge (Invited)

NASA Astrophysics Data System (ADS)

Cyronak, T.; Santos, I. R.; Erler, D.; Maher, D. T.; Eyre, B.

2013-12-01

The carbon chemistry of coral reef lagoons can be highly variable over short time scales. While much of the diel variability in seawater carbon chemistry is explained by biological processes, external sources such as river and groundwater seepage may deliver large amounts of organic and inorganic carbon to coral reefs and represent a poorly understood feedback to ocean acidification. Here, we assess the impact of submarine groundwater discharge (SGD) on pCO2 variability in two coral reef lagoons with distinct SGD driving mechanisms. Diel variability of pCO2 in the two ecosystems was explained by a combination of biological drivers and SGD inputs. In Rarotonga, a South Pacific volcanic island, SGD was driven primarily by a steep terrestrial hydraulic gradient, and the lagoon was influenced by the high pCO2 (5,501 μatm) of the fresh groundwater. In Heron Island, a Great Barrier Reef coral cay, SGD was dominated by seawater recirculation through sediments (i.e. tidal pumping) and pCO2 was mainly impacted through the stimulation of biological processes. The Rarotonga water column had a relatively higher average pCO2 (549 μatm) than Heron Island (471 μatm). However, pCO2 exhibited a greater diel range in Heron Island (778 μatm) than in Rarotonga (507 μatm). The Rarotonga lagoon received 31.2 mmol CO2 m-2 d-1 from SGD, while the Heron Island lagoon received 12.3 mmol CO2 m-2 d-1. Over the course of this study both systems were sources of CO2 to the atmosphere (3.00 to 9.67 mmol CO2 m-2 d-1), with SGD-derived CO2 contributing a large portion to the air-sea CO2 flux. The relationship between both water column pH and aragonite saturation state (ΩAr) and radon (222Rn) concentrations indicate that SGD may enhance the local acidification of some coral reef lagoons. Studies measuring the carbon chemistry of coral reefs (e.g. community metabolism, calcification rates) may need to consider SGD-derived CO2.

Sources, extent and history of methane seepage on the continental shelf off northern Norway

NASA Astrophysics Data System (ADS)

Sauer, Simone; Lepland, Aivo; Chand, Shyam; Schubert, Carsten J.; Eichinger, Florian; Knies, Jochen

2014-05-01

Active natural hydrocarbon gas seepage was recently discovered in the Hola area on the continental shelf off Vesterålen, northern Norway. We conducted acoustic and geochemical investigations to assess the modern and past extent, source and pathways of the gas seepage . Water column echosounder surveys showed bubble plumes up to several tens of metres above the seafloor. Analyses of dissolved methane in the water column indicated slightly elevated concentrations (50 nM) close to the seafloor. To identify fluxes and origin of methane in the sediments we analysed sediment pore water chemistry, the isotopic composition of methane and of dissolved inorganic carbon (d13CCH4, d2HCH4, d13CDIC) in three closely spaced (

A seepage investigation of an area at and near Oak Ridge National Laboratory, Oak Ridge, Tennessee, March through August 1993

USGS Publications Warehouse

Johnson, G.C.

1996-01-01

A seepage investigation was conducted of an area surrounding the Oak Ridge National Laboratory from March through August 1993. The project was divided into three phases: a reconnaissance to inventory and map seeps, springs, and stream-measurement sites; a high base flow seepage investigation; and a low base flow seepage investigation. The reconnaissance consisted of following each tributary to its source to inventory each site where water was issuing from the ground. Stream- measurement sites were also located along stream reaches at 500-foot intervals. A total of 822 sites were identified. A global positioning system was used to locate 483 sites to within 3- to 5-meter accuracy. The high base flow seepage investigation was conducted from April 29 through May 3, 1993, and from May 7 through May 10, 1993. During the high base flow seepage investigation, sites identified during the reconnaissance were revisited. At almost all sites with flowing water, discharge, pH, specific conductance, and temperature were recorded. Two hundred and fourteen sites were dry. The low base flow seepage investigation was conducted from August 8 through August 10, 1993, and consisted of revisiting the seeps and springs that were flowing during the high base flow seepage investigation. Stream- measurement sites were not revisited. One hundred and forty-one sites were dry.

Damage evaluation for crops exposed to a simulated leakage of geologically stored CO2 using hyperspectral imaging technology

NASA Astrophysics Data System (ADS)

Burud, Ingunn; Moni, Christophe; Flø, Andreas; Rolstad Denby, Cecilie; Rasse, Daniel

2013-04-01

Facilities for the geological storage of carbon dioxide (CO2) as part of carbon capture and storage (CCS) schemes will be designed to prevent any leakage from the defined 'storage complex'. However, even though the risk is of low probability, the precautionary principle requires that near surface environments that might be at risk be thoroughly monitored to detect a leak, were it to happen. Among all currently proposed monitoring methods, only hyperspectral imaging of vegetation stress response allows one to scan large areas rapidly and in detail. Until now, however, only a handful of studies have been carried out on using this novel technology. The aim of the present communication was to characterize the impacts that a simulated CO2 leak might have on the hyperspectral signature of a Norwegian oats crop. In order to test the effects of different intensity of leakage, a CO2 exposure field experiment was designed to create a longitudinal CO2 gradient. For this purpose a gas supply pipe was inserted at one end of a 6m by 3m experimental plot at the base of a 45 cm thick layer of sand buried 40 cm below the surface under a silt loam plough layer. CO2 was then injected at a rate of 2l.min-1 just after the oats had germinated at the end of June, and Facilities for the geological storage of carbon dioxide (CO2) as part of carbon capture and storage (CCS) schemes will be designed to prevent any leakage from the defined 'storage complex'. However, even though the risk is of low probability, the precautionary principle requires that near surface environments that might be at risk be thoroughly monitored to detect a leak, were it to happen. Among all currently proposed monitoring methods, only hyperspectral imaging of vegetation stress response allows one to scan large areas rapidly and in detail. Until now, however, only a handful of studies have been carried out on using this novel technology. The aim of the present communication was to characterize the impacts that a simulated CO2 leak might have on the hyperspectral signature of a Norwegian oats crop. In order to test the effects of different intensity of leakage, a CO2 exposure field experiment was designed to create a longitudinal CO2 gradient. For this purpose a gas supply pipe was inserted at one end of a 6m by 3m experimental plot at the base of a 45 cm thick layer of sand buried 40 cm below the surface under a silt loam plough layer. CO2 was then injected at a rate of 2l.min-1 just after the oats had germinated at the end of June, and continued until it was harvested at the end of August. Then soil CO2 fluxes were recorded at the surface using a (60 x 60 cm) grid sampling pattern. Hyperspectral images of the experimental plot were taken at different dates during the gassing period using a SPECIM camera with 800 spectral bands, covering the wavelength range 400 - 1000 nm. The change in the reflectance spectra were characterized over time within the plot by the computation of various hyperspectral vegetation indices for small discretized spatial units (i.e. 10 cm by 10 cm square). The results showed that one month after injection, reduced plant growth, yellowing of the leaves and purple discoloration of the stems were observed just above the injection points were high CO2 fluxes had been identified. These high CO2 flux zones were further associated with an increase of the reflectance that occurred in the red region of the spectra indicating a decrease of the chlorophyll content in the plants. To conclude, plant health, as indicated by the hyperspectral signature, was closely related to the leakage pattern, indicating that hyperspectral imaging could be used to identify a CO2 seepage in an agricultural field. Acknowledgments This work is part of the RISCS project (Research into Impacts and Safety in CO2 Storage), funded by the EC 7th Framework Programme and by industry partners ENEL I&I, Statoil, Vattenfall AB, E.ON and RWE. R&D partners are BGS, CERTH, IMARES, OGS, PML, SINTEF, University of Nottingham, Sapienza Università di Roma, Quintessa, CO2 GeoNet, Bioforsk, BGR and ZERO. For more information please go to the website (www.riscs-co2.eu) or contact the project coordinator David Jones (e-mail: dgj@bgs.ac.uk tel. +44(0)115-936-3576).

Carbon isotope fractionation of dissolved inorganic carbon (DIC) due to outgassing of carbon dioxide from a headwater stream

USGS Publications Warehouse

Doctor, D.H.; Kendall, C.; Sebestyen, S.D.; Shanley, J.B.; Ohte, N.; Boyer, E.W.

2008-01-01

The stable isotopic composition of dissolved inorganic carbon (??13C-DIC) was investigated as a potential tracer of streamflow generation processes at the Sleepers River Research Watershed, Vermont, USA. Downstream sampling showed ?? 13C-DIC increased between 3-5??? from the stream source to the outlet weir approximately 0??5 km downstream, concomitant with increasing pH and decreasing PCO2. An increase in ??13C-DIC of 2.4 ?? 0??1??? per log unit decrease of excess PCO2 (stream PCO2 normalized to atmospheric PCO2) was observed from downstream transect data collected during snowmelt. Isotopic fractionation of DIC due to CO2 outgassing rather than exchange with atmospheric CO2 may be the primary cause of increased ?? 13C-DIC values downstream when PCO2 of surface freshwater exceeds twice the atmospheric CO2 concentration. Although CO2 outgassing caused a general increase in stream ??13C-DIC values, points of localized groundwater seepage into the stream were identified by decreases in ??13C-DIC and increases in DIC concentration of the stream water superimposed upon the general downstream trend. In addition, comparison between snowmelt, early spring and summer seasons showed that DIC is flushed from shallow groundwater flowpaths during snowmelt and is replaced by a greater proportion of DIC derived from soil CO2 during the early spring growing season. Thus, in spite of effects from CO2 outgassing, ??13C of DIC can be a useful indicator of groundwater additions to headwater streams and a tracer of carbon dynamics in catchments. Copyright ?? 2007 John Wiley & Sons, Ltd.

Interactions of artificial lakes with groundwater applying an integrated MODFLOW solution

NASA Astrophysics Data System (ADS)

El-Zehairy, A. A.; Lubczynski, M. W.; Gurwin, J.

2018-02-01

Artificial lakes (reservoirs) are regulated water bodies with large stage fluctuations and different interactions with groundwater compared with natural lakes. A novel modelling study characterizing the dynamics of these interactions is presented for artificial Lake Turawa, Poland. The integrated surface-water/groundwater MODFLOW-NWT transient model, applying SFR7, UZF1 and LAK7 packages to account for variably-saturated flow and temporally variable lake area extent and volume, was calibrated throughout 5 years (1-year warm-up, 4-year simulation), applying daily lake stages, heads and discharges as control variables. The water budget results showed that, in contrast to natural lakes, the reservoir interactions with groundwater were primarily dependent on the balance between lake inflow and regulated outflow, while influences of precipitation and evapotranspiration played secondary roles. Also, the spatio-temporal lakebed-seepage pattern was different compared with natural lakes. The large and fast-changing stages had large influence on lakebed-seepage and water table depth and also influenced groundwater evapotranspiration and groundwater exfiltration, as their maxima coincided not with rainfall peaks but with highest stages. The mean lakebed-seepage ranged from 0.6 mm day-1 during lowest stages (lake-water gain) to 1.0 mm day-1 during highest stages (lake-water loss) with largest losses up to 4.6 mm day-1 in the peripheral zone. The lakebed-seepage of this study was generally low because of low lakebed leakance (0.0007-0.0015 day-1) and prevailing upward regional groundwater flow moderating it. This study discloses the complexity of artificial lake interactions with groundwater, while the proposed front-line modelling methodology can be applied to any reservoir, and also to natural lake interactions with groundwater.

Modeling Coupled Thermal-Hydrological-Chemical Processes in the Unsaturated Fractured Rock of Yucca Mountain, Nevada: Heterogeneity and Seepage

DOE Office of Scientific and Technical Information (OSTI.GOV)

S. Mukhopadhyay; E.L. Donnenthal; N. Spycher

An understanding of processes affecting seepage into emplacement tunnels is needed for correctly predicting the performance of underground radioactive waste repositories. It has been previously estimated that the capillary and vaporization barriers in the unsaturated fractured rock of Yucca Mountain are enough to prevent seepage under present day infiltration conditions. It has also been thought that a substantially elevated infiltration flux will be required to cause seepage after the thermal period is over. While coupled thermal-hydrological-chemical (THC) changes in Yucca Mountain host rock due to repository heating has been previously investigated, those THC models did not incorporate elements of themore » seepage model. In this paper, we combine the THC processes in unsaturated fractured rock with the processes affecting seepage. We observe that the THC processes alter the hydrological properties of the fractured rock through mineral precipitation and dissolution. We show that such alteration in the hydrological properties of the rock often leads to local flow channeling. We conclude that such local flow channeling may result in seepage under certain conditions, even with nonelevated infiltration fluxes.« less

Hydrocarbon Degradation in Caspian Sea Sediment Cores Subjected to Simulated Petroleum Seepage in a Newly Designed Sediment-Oil-Flow-Through System

PubMed Central

Mishra, Sonakshi; Wefers, Peggy; Schmidt, Mark; Knittel, Katrin; Krüger, Martin; Stagars, Marion H.; Treude, Tina

2017-01-01

The microbial community response to petroleum seepage was investigated in a whole round sediment core (16 cm length) collected nearby natural hydrocarbon seepage structures in the Caspian Sea, using a newly developed Sediment-Oil-Flow-Through (SOFT) system. Distinct redox zones established and migrated vertically in the core during the 190 days-long simulated petroleum seepage. Methanogenic petroleum degradation was indicated by an increase in methane concentration from 8 μM in an untreated core compared to 2300 μM in the lower sulfate-free zone of the SOFT core at the end of the experiment, accompanied by a respective decrease in the δ13C signal of methane from -33.7 to -49.5‰. The involvement of methanogens in petroleum degradation was further confirmed by methane production in enrichment cultures from SOFT sediment after the addition of hexadecane, methylnapthalene, toluene, and ethylbenzene. Petroleum degradation coupled to sulfate reduction was indicated by the increase of integrated sulfate reduction rates from 2.8 SO42-m-2 day-1 in untreated cores to 5.7 mmol SO42-m-2 day-1 in the SOFT core at the end of the experiment, accompanied by a respective accumulation of sulfide from 30 to 447 μM. Volatile hydrocarbons (C2–C6 n-alkanes) passed through the methanogenic zone mostly unchanged and were depleted within the sulfate-reducing zone. The amount of heavier n-alkanes (C10–C38) decreased step-wise toward the top of the sediment core and a preferential degradation of shorter (C30) was seen during the seepage. This study illustrates, to the best of our knowledge, for the first time the development of methanogenic petroleum degradation and the succession of benthic microbial processes during petroleum passage in a whole round sediment core. PMID:28503172

Failure Behavior of Granite Affected by Confinement and Water Pressure and Its Influence on the Seepage Behavior by Laboratory Experiments.

PubMed

Cheng, Cheng; Li, Xiao; Li, Shouding; Zheng, Bo

2017-07-14

Failure behavior of granite material is paramount for host rock stability of geological repositories for high-level waste (HLW) disposal. Failure behavior also affects the seepage behavior related to transportation of radionuclide. Few of the published studies gave a consistent analysis on how confinement and water pressure affect the failure behavior, which in turn influences the seepage behavior of the rock during the damage process. Based on a series of laboratory experiments on NRG01 granite samples cored from Alxa area, a candidate area for China's HLW disposal, this paper presents some detailed observations and analyses for a better understanding on the failure mechanism and seepage behavior of the samples under different confinements and water pressure. The main findings of this study are as follows: (1) Strength reduction properties were found for the granite under water pressure. Besides, the complete axial stress-strain curves show more obvious yielding process in the pre-peak region and a more gradual stress drop in the post-peak region; (2) Shear fracturing pattern is more likely to form in the granite samples with the effect of water pressure, even under much lower confinements, than the predictions from the conventional triaxial compressive results; (3) Four stages of inflow rate curves are divided and the seepage behaviors are found to depend on the failure behavior affected by the confinement and water pressure.

Submarine gas seepage in a mixed contractional and shear deformation regime: Cases from the Hikurangi oblique-subduction margin

NASA Astrophysics Data System (ADS)

Plaza-Faverola, Andreia; Pecher, Ingo; Crutchley, Gareth; Barnes, Philip M.; Bünz, Stefan; Golding, Thomas; Klaeschen, Dirk; Papenberg, Cord; Bialas, Joerg

2014-02-01

Gas seepage from marine sediments has implications for understanding feedbacks between the global carbon reservoir, seabed ecology, and climate change. Although the relationship between hydrates, gas chimneys, and seafloor seepage is well established, the nature of fluid sources and plumbing mechanisms controlling fluid escape into the hydrate zone and up to the seafloor remain one of the least understood components of fluid migration systems. In this study, we present the analysis of new three-dimensional high-resolution seismic data acquired to investigate fluid migration systems sustaining active seafloor seepage at Omakere Ridge, on the Hikurangi subduction margin, New Zealand. The analysis reveals at high resolution, complex overprinting fault structures (i.e., protothrusts, normal faults from flexural extension, and shallow (<1 km) arrays of oblique shear structures) implicated in fluid migration within the gas hydrate stability zone in an area of 2 × 7 km. In addition to fluid migration systems sustaining seafloor seepage on both sides of a central thrust fault, the data show seismic evidence for subseafloor gas-rich fluid accumulation associated with proto-thrusts and extensional faults. In these latter systems fluid pressure dissipation through time has been favored, hindering the development of gas chimneys. We discuss the elements of the distinct fluid migration systems and the influence that a complex partitioning of stress may have on the evolution of fluid flow systems in active subduction margins.

Groundwater-Seepage Meter

NASA Technical Reports Server (NTRS)

Walthall, Harry G.; Reay, William G.

1993-01-01

Instrument measures seepage of groundwater into inland or coastal body of water. Positioned at depth as great as 40 meters, and measures flow at low rate and low pressure differential. Auxiliary pressure meter provides data for correlation of flow of groundwater with tides and sea states. Seepage meter operates independently for several weeks. Its sampling rate adjusted to suit hydrologic conditions; to measure more frequently when conditions changing rapidly. Used in water-quality management and for biological and geological research. Potential industrial uses include measurement of seepage of caustic and corrosive liquids.

Influence of a thin veneer of low-hydraulic-conductivity sediment on modelled exchange between river water and groundwater in response to induced infiltration

USGS Publications Warehouse

Rosenberry, Donald O.; Healy, Richard W.

2012-01-01

A thin layer of fine-grained sediment commonly is deposited at the sediment–water interface of streams and rivers during low-flow conditions, and may hinder exchange at the sediment–water interface similar to that observed at many riverbank-filtration (RBF) sites. Results from a numerical groundwater-flow model indicate that a low-permeability veneer reduces the contribution of river water to a pumping well in a riparian aquifer to various degrees, depending on simulated hydraulic gradients, hydrogeological properties, and pumping conditions. Seepage of river water is reduced by 5–10% when a 2-cm thick, low-permeability veneer is present on the bed surface. Increasing thickness of the low-permeability layer to 0·1 m has little effect on distribution of seepage or percentage contribution from the river to the pumping well. A three-orders-of-magnitude reduction in hydraulic conductivity of the veneer is required to reduce seepage from the river to the extent typically associated with clogging at RBF sites. This degree of reduction is much larger than field-measured values that were on the order of a factor of 20–25. Over 90% of seepage occurs within 12 m of the shoreline closest to the pumping well for most simulations. Virtually no seepage occurs through the thalweg near the shoreline opposite the pumping well, although no low-permeability sediment was simulated for the thalweg. These results are relevant to natural settings that favour formation of a substantial, low-permeability sediment veneer, as well as central-pivot irrigation systems, and municipal water supplies where river seepage is induced via pumping wells

Calcareous forest seepages acting as biodiversity hotspots and refugia for woodland snail faunas

NASA Astrophysics Data System (ADS)

Horsák, Michal; Tajovská, Eva; Horsáková, Veronika

2017-07-01

Land-snail species richness has repeatedly been found to increase with the increasing site calcium content and humidity. These two factors, reported as the main drivers of land-snail assemblage diversity, are also among the main habitat characteristics of calcareous seepages. Here we explore local species richness and compositional variation of forest spring-fed patches (i.e. seepages), to test the hypothesis that these habitats might act as biodiversity hotspots and refugia of regional snail faunas. In contrast to treeless spring fens, only little is known about land snail faunas inhabiting forest seepages. Studying 25 isolated calcareous forest seepages, evenly distributed across the White Carpathians Protected Landscape Area (SE Czech Republic), we found that these sites, albeit spatially very limited, can harbour up to 66% of the shelled land-snail species known to occur in this well-explored protected area (in total 83 species). By comparing land snail assemblages of the studied seepages with those occurring in the woodland surroundings of each site as well as those previously sampled in 28 preserved forest sites within the study area, we found the seepages to be among the most species rich sites. Although the numbers of species did not statistically differ among these three systems, we found highly significant differences in species composition. Seepage faunas were composed of many species significantly associated with spring sites, in contrast to the assemblages of both surrounding and preserved forest sites. Our results highly support the hypothesis that calcareous forest seepages might serve as refugia and biodiversity hotspots of regional land snail faunas. Protection of these unique habitats challenges both conservation plans and forest management guidelines as they might act as sources for the recolonization and restoration of forest snail assemblages particularly in areas impoverished by harvesting and clearcutting.

Distributed optical fiber-based monitoring approach of spatial seepage behavior in dike engineering

NASA Astrophysics Data System (ADS)

Su, Huaizhi; Ou, Bin; Yang, Lifu; Wen, Zhiping

2018-07-01

The failure caused by seepage is the most common one in dike engineering. As to the characteristics of seepage in dike, such as longitudinal extension engineering, the randomness, strong concealment and small initial quantity order, by means of distributed fiber temperature sensor system (DTS), adopting an improved optical fiber layer layout scheme, the location of initial interpolation point of the saturation line is obtained. With the barycentric Lagrange interpolation collocation method (BLICM), the infiltrated surface of dike full-section is generated. Combined with linear optical fiber monitoring seepage method, BLICM is applied in an engineering case, which shows that a real-time seepage monitoring technique is presented in full-section of dike based on the combination method.

Ground-water/surface-water relations along Honey Creek, Washtenaw County, Michigan, 2003

USGS Publications Warehouse

Healy, Denis F.

2005-01-01

The U.S. Geological Survey (USGS), in cooperation with the city of Ann Arbor, Mich., investigated the ground-water/ surface-water relations along the lower reaches of Honey Creek, Washtenaw County, Mich., and an unnamed tributary to Honey Creek (the discharge tributary) from June through October 2003. Streamflow in these reaches was artificially high during a naturally low-flow period due to an anthropogenic discharge. Ground-water/surface-water relations were examined by seepage runs (series of streamflow measurements for the computation of streams gains or losses) and measurements of the difference in head between the stream surface and shallow aquifer. Specific conductance and water-temperature measurements were used as ancillary data to help identify gaining and losing reaches. Three seepage runs and four runs in which hydraulic-head differences between the stream and shallow aquifer were measured (piezometer runs) were made during periods of base flow. Streamflow measurements were made at 18 sites for the seepage runs. Instream piezometers were installed at 16 sites and bank piezometers were installed at 2 sites. Two deeper instream piezometers were installed at site 13 on September 4, 2003 to collect additional data on the ground-water/surface-water relations at that site. The seepage runs indicate that the main stem of Honey Creek and the discharge tributary in the study area are overall gaining reaches. The seepage runs also indicate that smaller reaches of Honey Creek and the discharge tributary may be losing reaches and that this relation may change over time with changing hydraulic conditions. The piezometer-run measurements support the seepage-run results on the main stem, whereas piezometer-run measurements both support and conflict with seepage-run measurements on the discharge tributary. Seepage runs give an average for the reach, whereas piezometer head-difference measurements are for a specific area around the piezometer. Data that may appear to be conflicting actually may be showing that within a gaining reach there are localized areas that lose streamflow. The overall gain in streamflow along with specific measurements of head differences, specific conductance, and water temperature indicate that ground water is discharging to Honey Creek and the discharge tributary. Although reaches and areas that lose streamflow have been identified, data collected during this study cannot confirm or disprove that the loss is to the regional ground-water system.

Potential incremental seepage losses in an alluvial channel in the Rio Grande Basin, New Mexico

USGS Publications Warehouse

Gold, R.L.

1985-01-01

A two-dimensional, digital, cross-sectional model was used to simulate seepage of water from an alluvial channel, which had the general characteristic of the Rio Grande channel, into the underlying alluvium within the reach from Cochiti Dam to Elephant Butte Reservoir. Seepage rates were determined for losing and gaining reaches, and reaches affected by pumping of ground water. The seepage rates were computed for stream surcharges (height of additional water applied on top of base flow) ranging from 0.5 foot to 3 feet and for application periods ranging from 1 to 100 days. The net seepage rates, which were nearly identical for each type of reach, ranged from 0.0 cubic foot per second per mile of channel length for a 0.5 foot surcharge applied for 1 day to 0.37 cubic foot per second per mile of channel length for a 3 feet surcharge applied for 100 days, followed by a 180 day seepage return flow from the aquifer. (USGS)

Drift-Scale Coupled Processes (DST and THC Seepage) Models

DOE Office of Scientific and Technical Information (OSTI.GOV)

P. Dixon

The purpose of this Model Report (REV02) is to document the unsaturated zone (UZ) models used to evaluate the potential effects of coupled thermal-hydrological-chemical (THC) processes on UZ flow and transport. This Model Report has been developed in accordance with the ''Technical Work Plan for: Performance Assessment Unsaturated Zone'' (Bechtel SAIC Company, LLC (BSC) 2002 [160819]). The technical work plan (TWP) describes planning information pertaining to the technical scope, content, and management of this Model Report in Section 1.12, Work Package AUZM08, ''Coupled Effects on Flow and Seepage''. The plan for validation of the models documented in this Model Reportmore » is given in Attachment I, Model Validation Plans, Section I-3-4, of the TWP. Except for variations in acceptance criteria (Section 4.2), there were no deviations from this TWP. This report was developed in accordance with AP-SIII.10Q, ''Models''. This Model Report documents the THC Seepage Model and the Drift Scale Test (DST) THC Model. The THC Seepage Model is a drift-scale process model for predicting the composition of gas and water that could enter waste emplacement drifts and the effects of mineral alteration on flow in rocks surrounding drifts. The DST THC model is a drift-scale process model relying on the same conceptual model and much of the same input data (i.e., physical, hydrological, thermodynamic, and kinetic) as the THC Seepage Model. The DST THC Model is the primary method for validating the THC Seepage Model. The DST THC Model compares predicted water and gas compositions, as well as mineral alteration patterns, with observed data from the DST. These models provide the framework to evaluate THC coupled processes at the drift scale, predict flow and transport behavior for specified thermal-loading conditions, and predict the evolution of mineral alteration and fluid chemistry around potential waste emplacement drifts. The DST THC Model is used solely for the validation of the THC Seepage Model and is not used for calibration to measured data.« less

Geophysical investigation of seepage beneath an earthen dam.

PubMed

Ikard, S J; Rittgers, J; Revil, A; Mooney, M A

2015-01-01

A hydrogeophysical survey is performed at small earthen dam that overlies a confined aquifer. The structure of the dam has not shown evidence of anomalous seepage internally or through the foundation prior to the survey. However, the surface topography is mounded in a localized zone 150 m downstream, and groundwater discharges from this zone periodically when the reservoir storage is maximum. We use self-potential and electrical resistivity tomography surveys with seismic refraction tomography to (1) determine what underlying hydrogeologic factors, if any, have contributed to the successful long-term operation of the dam without apparent indicators of anomalous seepage through its core and foundation; and (2) investigate the hydraulic connection between the reservoir and the seepage zone to determine whether there exists a potential for this success to be undermined. Geophysical data are informed by hydraulic and geotechnical borehole data. Seismic refraction tomography is performed to determine the geometry of the phreatic surface. The hydro-stratigraphy is mapped with the resistivity data and groundwater flow patterns are determined with self-potential data. A self-potential model is constructed to represent a perpendicular profile extending out from the maximum cross-section of the dam, and self-potential data are inverted to recover the groundwater velocity field. The groundwater flow pattern through the aquifer is controlled by the bedrock topography and a preferential flow pathway exists beneath the dam. It corresponds to a sandy-gravel layer connecting the reservoir to the downstream seepage zone. © 2014, National Ground Water Association.

Failure Behavior of Granite Affected by Confinement and Water Pressure and Its Influence on the Seepage Behavior by Laboratory Experiments

PubMed Central

Cheng, Cheng; Li, Xiao; Li, Shouding; Zheng, Bo

2017-01-01

Failure behavior of granite material is paramount for host rock stability of geological repositories for high-level waste (HLW) disposal. Failure behavior also affects the seepage behavior related to transportation of radionuclide. Few of the published studies gave a consistent analysis on how confinement and water pressure affect the failure behavior, which in turn influences the seepage behavior of the rock during the damage process. Based on a series of laboratory experiments on NRG01 granite samples cored from Alxa area, a candidate area for China’s HLW disposal, this paper presents some detailed observations and analyses for a better understanding on the failure mechanism and seepage behavior of the samples under different confinements and water pressure. The main findings of this study are as follows: (1) Strength reduction properties were found for the granite under water pressure. Besides, the complete axial stress–strain curves show more obvious yielding process in the pre-peak region and a more gradual stress drop in the post-peak region; (2) Shear fracturing pattern is more likely to form in the granite samples with the effect of water pressure, even under much lower confinements, than the predictions from the conventional triaxial compressive results; (3) Four stages of inflow rate curves are divided and the seepage behaviors are found to depend on the failure behavior affected by the confinement and water pressure. PMID:28773157

Estimation of past seepage volumes from calcite distribution in the Topopah Spring Tuff, Yucca Mountain, Nevada

USGS Publications Warehouse

Marshall, B.D.; Neymark, L.A.; Peterman, Z.E.

2003-01-01

Low-temperature calcite and opal record the past seepage of water into open fractures and lithophysal cavities in the unsaturated zone at Yucca Mountain, Nevada, site of a proposed high-level radioactive waste repository. Systematic measurements of calcite and opal coatings in the Exploratory Studies Facility (ESF) tunnel at the proposed repository horizon are used to estimate the volume of calcite at each site of calcite and/or opal deposition. By estimating the volume of water required to precipitate the measured volumes of calcite in the unsaturated zone, seepage rates of 0.005 to 5 liters/year (l/year) are calculated at the median and 95th percentile of the measured volumes, respectively. These seepage rates are at the low end of the range of seepage rates from recent performance assessment (PA) calculations, confirming the conservative nature of the performance assessment. However, the distribution of the calcite and opal coatings indicate that a much larger fraction of the potential waste packages would be contacted by this seepage than is calculated in the performance assessment.

Air Compressibility Effect on Bouwer and Rice Seepage Meter.

PubMed

Peng, Xin; Zhan, Hongbin

2017-11-01

Measuring a disconnected streambed seepage flux using a seepage meter can give important streambed information and help understanding groundwater-surface water interaction. In this study, we provide a correction for calculating the seepage flux rate with the consideration of air compressibility inside the manometer of the Bouwer and Rice seepage meter. We notice that the effect of air compressibility in the manometer is considerably larger when more air is included in the manometer. We find that the relative error from neglecting air compressibility can be constrained within 5% if the manometer of the Bouwer and Rice seepage meter is shorter than 0.8 m and the experiment is done in a suction mode in which air is pumped out from the manometer before the start of measurement. For manometers longer than 0.8 m, the relative error will be larger than 5%. It may be over 10% if the manometer height is longer than 1.5 m and the experiment is done in a no-suction mode, in which air is not pumped out from the manometer before the start of measurement. © 2017, National Ground Water Association.

Solution of AntiSeepage for Mengxi River Based on Numerical Simulation of Unsaturated Seepage

PubMed Central

Ji, Youjun; Zhang, Linzhi; Yue, Jiannan

2014-01-01

Lessening the leakage of surface water can reduce the waste of water resources and ground water pollution. To solve the problem that Mengxi River could not store water enduringly, geology investigation, theoretical analysis, experiment research, and numerical simulation analysis were carried out. Firstly, the seepage mathematical model was established based on unsaturated seepage theory; secondly, the experimental equipment for testing hydraulic conductivity of unsaturated soil was developed to obtain the curve of two-phase flow. The numerical simulation of leakage in natural conditions proves the previous inference and leakage mechanism of river. At last, the seepage control capacities of different impervious materials were compared by numerical simulations. According to the engineering actuality, the impervious material was selected. The impervious measure in this paper has been proved to be effectible by hydrogeological research today. PMID:24707199

Quantifying exchange between groundwater and surface water in rarely measured organic sediments

NASA Astrophysics Data System (ADS)

Rosenberry, D. O.; Cavas, M.; Keith, D.; Gefell, M. J.; Jones, P. M.

2016-12-01

Transfer of water and chemicals between poorly competent organic sediments and surface water in low-energy riverine and lentic settings depends on several factors, including rate and direction of flow, redox state, number and type of benthic invertebrates, and chemical gradients at and near the sediment-water interface. In spite of their commonly large areal extent, direct measurements of flow in soft, organic sediments are rarely made and little is known about flux direction, rate, or heterogeneity. Commonly used monitoring wells are difficult to install and suffer from slow response to changing hydraulic head due to the low permeability of these sediments. Seepage meters can directly quantify seepage flux if several challenges can be overcome. Meters are difficult to install and operate where water is deep, visibility is poor, and the position of the sediment-water interface is not readily apparent. Soft, easily eroded sediment can be displaced during meter installation, creating bypass flow beneath the bottom of the seepage cylinder. Poorly competent sediments often cannot support the weight of the meters; they slowly sink into the bed and displace water inside the seepage cylinder, which leads to the interpretation of large upward flow. Decaying organic material within the sediment generates gas that can displace water and corrupt seepage-meter measurements. Several inexpensive modifications to a standard seepage meter, as well as precautions during installation and operation, can minimize these sources of error. Underwater video cameras can be mounted to the meter to remotely observe sediment disturbance during sensor installation and monitor the stability of the meter insertion depth during the period of deployment. Anchor rods can be driven a meter or more into the sediment until refusal, firmly anchoring the seepage meter at a constant sediment insertion depth. Data collected from modified seepage meters installed in Minnesota and New York demonstrate the importance of quantifying flows in these challenging settings where biogeochemistry is complex and seepage rates commonly have been assumed to be insignificantly small.

Fresh Versus Marine Submarine Groundwater Discharge: How 222Rn Might Help Distinguish These Two Sources

NASA Astrophysics Data System (ADS)

Smith, C. G.; Cable, J. E.; Martin, J. B.; Roy, M.

2008-05-01

Pore water distributions of 222Rn (t1/2 = 3.83 d), obtained during two sampling trips 9-12 May 2005 and 6-8 May 2006, are used to determine spatial and temporal variations of fluid discharge from a seepage face located along the mainland shoreline of Indian River Lagoon, Florida. Porewater samples were collected from a 30 m transect of multi-level piezometers and analyzed for 222Rn via liquid scintillation counting; the mean of triplicate measurements was used to represent the porewater 222Rn activities. Sediment samples were collected from five vibracores (0, 10, 17.5, 20, and 30 m offshore) and emanation rates of 222Rn (sediment supported) were determined using a standard cryogenic extraction technique. A conceptual 222Rn transport model and subsequent numerical model were developed based on the vertical distribution of dissolved and sediment-supported 222Rn and applicable processes occurring along the seepage face (e.g. advection, diffusion, and nonlocal exchange). The model was solved inversely with the addition of two Monte Carlo (MC) simulations to increase the statistical reliability of three parameters: fresh groundwater seepage velocity (v), irrigation intensity (α0), and irrigation attenuation (α1). The first MC simulation ensures that the Nelder-Mead minimization algorithm converges on a global minimum of the merit function and that the parameters estimates are consistent within this global minimum. The second MC simulation provides 90% confidence intervals on the parameter estimates using the measured 222Rn activity variance. Fresh groundwater seepage velocities obtained from the model decrease linearly with distance from the shoreline; seepage velocities range between 0.6 and 42.2 cm d-1. Based on this linear relationship, the terminus of the fresh groundwater seepage is approximately 25 m offshore and total fresh groundwater discharge for the May-2005 and May-2006 sampling trips are 1.16 and 1.45 m3 d-1 m-1 of shoreline, respectively. We hypothesize that the 25% increase in specific discharge between May-2005 and May- 2006 reflects higher recharge via precipitation to the Surficial aquifer during the highly active 2005 Atlantic hurricane season. Irrigation rates generally decrease offshore for both sampling periods; irrigation rates range between 4.9 and 85.7 cm d-1. Physical and biological mechanisms reasonable for the observed irrigation likely include density-driven convection, wave pumping, and bio-irrigation. The inclusion of both advective and nonlocal exchange processes in the model permits the separation of submarine groundwater discharge into fresh submarine groundwater discharge (seepage velocities) and (re)circulated lagoon water (as irrigation).

Phase II Interim Report -- Assessment of Hydrocarbon Seepage Detection Methods on the Fort Peck Reservation, Northeast Montana

DOE Office of Scientific and Technical Information (OSTI.GOV)

Monson, Lawrence M.

2002-04-24

The following work was performed: (1) collected reconnaissance micro-magnetic data and background field data for Area 1, (2) identified and collected soil sample data in three anomalous regions of Area 1, (3) sampled soils in Northwest Poplar Oil Field, (4) graphed, mapped, and interpreted all data areas listed above, (5) registered for the AAPG Penrose Conference on Hydrocarbon Seepage Mechanisms and Migration (postponed from 9/16/01 until 4/7/02 in Vancouver, B.C.). Results include the identification and confirmation of an oil and gas prospect in the northwest part of Area 1 and the verification of a potential shallow gas prospect in themore » West Poplar Area. Correlation of hydrocarbon micro-seepage to TM tonal anomalies needs further data analysis.« less

Numerical modeling of crater lake seepage

NASA Astrophysics Data System (ADS)

Todesco, M.; Rouwet, D.

2012-04-01

The fate of crater lake waters seeping into the volcanic edifice is poorly constrained. Quantification of the seepage flux is important in volcanic surveillance as this water loss counterbalances the inflow of hot magmatic fluids into the lake, and enters the mass balance computation. Uncertainties associated with the estimate of seepage therefore transfer to the estimate of magmatic degassing and hazard assessment. Moreover, when the often acidic lake brines disperse into the volcanic edifice, they may lead to acid attack (stress corrosion) and eventually to mechanical weakening of the volcano flanks, thereby causing an indirect volcanic risk. Understanding of the features that control the underground propagation of lake waters and their interactions with the magmatic-hydrothermal system is therefore highly recommended in volcanic hazard assessment. In this work, we use the TOUGH2 geothermal simulator to investigate crater lake water seepage in different volcanic settings. Modeling is carried out to describe the evolution of a hydrothermal system open on a hot, pressurized reservoir of dry gas and capped by a volcanic lake. Numerical simulations investigate the role of lake morphology, system geometry, rock properties, and of the conditions applied to the lake and to the gas reservoir at depth.

How much CO2 is trapped in carbonate minerals of a natural CO2 occurrence?

NASA Astrophysics Data System (ADS)

Király, Csilla; Szabó, Zsuzsanna; Szamosfalvi, Ágnes; Cseresznyés, Dóra; Király, Edit; Szabó, Csaba; Falus, György

2017-04-01

Carbon Capture and Storage (CCS) is a transitional technology to decrease CO2 emissions from human fossil fuel usage and, therefore, to mitigate climate change. The most important criteria of a CO2 geological storage reservoir is that it must hold the injected CO2 for geological time scales without its significant seepage. The injected CO2 undergoes physical and chemical reactions in the reservoir rocks such as structural-stratigraphic, residual, dissolution or mineral trapping mechanisms. Among these, the safest is the mineral trapping, when carbonate minerals such as calcite, ankerite, siderite, dolomite and dawsonite build the CO2 into their crystal structures. The study of natural CO2 occurrences may help to understand the processes in CO2 reservoirs on geological time scales. This is the reason why the selected, the Mihályi-Répcelak natural CO2 occurrence as our research area, which is able to provide particular and highly significant information for the future of CO2 storage. The area is one of the best known CO2 fields in Central Europe. The main aim of this study is to estimate the amount of CO2 trapped in the mineral phase at Mihályi-Répcelak CO2 reservoirs. For gaining the suitable data, we apply petrographic, major and trace element (microprobe and LA-ICP-MS) and stable isotope analysis (mass spectrometry) and thermodynamic and kinetic geochemical models coded in PHREEQC. Rock and pore water compositions of the same formation, representing the pre-CO2 flooding stages of the Mihályi-Répcelak natural CO2 reservoirs are used in the models. Kinetic rate parameters are derived from the USGS report of Palandri and Kharaka (2004). The results of petrographic analysis show that a significant amount of dawsonite (NaAlCO3(OH)2, max. 16 m/m%) precipitated in the rock due to its reactions with CO2 which flooded the reservoir. This carbonate mineral alone traps about 10-30 kg/m3 of the reservoir rock from the CO2 at Mihályi-Répcelak area, which is an unexpectedly high proportion of total amount of CO2. Further results enlightened that other carbonates, ankerite, calcite and siderite have precipitated in two generations, the first before and the second after the CO2 flooding. Further laboratory analysis and geochemical models allow us to estimate the ratio of these two generations and also to understand how far the reservoir rock is in the CO2 mineral trapping process.

Recovery Act: Geologic Sequestration Training and Research

DOE Office of Scientific and Technical Information (OSTI.GOV)

Walsh, Peter; Esposito, Richard; Theodorou, Konstantinos

2013-06-30

Work under the project entitled "Geologic Sequestration Training and Research," was performed by the University of Alabama at Birmingham and Southern Company from December 1, 2009, to June 30, 2013. The emphasis was on training of students and faculty through research on topics central to further development, demonstration, and commercialization of carbon capture, utilization, and storage (CCUS). The project had the following components: (1) establishment of a laboratory for measurement of rock properties, (2) evaluation of the sealing capacity of caprocks, (3) evaluation of porosity, permeability, and storage capacity of reservoirs, (4) simulation of CO{sub 2} migration and trapping inmore » storage reservoirs and seepage through seal layers, (5) education and training of students through independent research on rock properties and reservoir simulation, and (6) development of an advanced undergraduate/graduate level course on coal combustion and gasification, climate change, and carbon sequestration. Four graduate students and one undergraduate student participated in the project. Two were awarded Ph.D. degrees for their work, the first in December 2010 and the second in August 2013. A third graduate student has proposed research on an advanced technique for measurement of porosity and permeability, and has been admitted to candidacy for the Ph.D. The fourth graduate student is preparing his proposal for research on CCUS and solid waste management. The undergraduate student performed experimental measurements on caprock and reservoir rock samples and received his B.S.M.E. degree in May 2012. The "Caprock Integrity Laboratory," established with support from the present project, is fully functional and equipped for measurement of porosity, permeability, minimum capillary displacement pressure, and effective permeability to gas in the presence of wetting phases. Measurements are made at ambient temperature and under reservoir conditions, including supercritical CO{sub 2}. During the course of the project, properties of 19 samples provided by partners on companion projects supported by NETL were measured, covering a range of permeabilities from 0.28 ndarcy to 81 mdarcy. Reservoir simulations were performed for injection of 530,000 tonnes of CO{sub 2} through a single well into the Middle Donovan formation in Citronelle Dome, in southwest Alabama, over 40 years, followed by migration and trapping for 10,000 years, using the TOUGH2 and TOUGHREACT software packages from Lawrence Berkeley National Laboratory. It was estimated that 50 kg CO{sub 2}/m{sup 3} of formation would be converted to mineral phases within the CO{sub 2} plume during that time. None of the sand units considered for CO{sub 2} storage in Citronelle Dome have thickness exceeding the estimated critical CO{sub 2} column height (Berg, 1975) at which seepage might begin, through their confining shale layers. A model for leakage through caprock, based on work by Hildenbrand et al. (2004), including a functional relationship between capillary pressure and the effective permeability to gas in the presence of a wetting phase, demonstrated the sensitivity of long-term storage to caprock permeability and thickness. A traditional course on coal combustion was augmented with material on climate change, coal gasification, and carbon sequestration. A total of 49 students completed the course during two offerings, in Fall 2010 and Fall 2012. It has become a popular advanced elective course in the Department of Mechanical Engineering.« less

Multidisciplinary Investigations of Submarine Flow to Biscayne Bay, Florida

NASA Astrophysics Data System (ADS)

Halley, R. B.; Reich, C. D.; Swarzenski, P. W.; Langevin, C. D.

2005-05-01

Biscayne Bay and Biscayne National Park (BNP) are located next to the Miami-Dade urban complex and are adjacent to the Dade County South Dade Landfill Facility and the Miami-Dade Water and Sewer South District Plant. The base of the landfill is lined to separate it from the underlying Miami Limestone, the host rock for the surficial Biscayne Aquifer. The sewage-treatment facility injects treated sewage into the lower Florida Aquifer (750 m) that is overlain by an aquitard termed the Middle Confining Unit (450 m). The Biscayne Aquifer (up to 50 m thick) borders the western margin of BNP, and the Floridan Aquifer underlies the entire park. There is concern about leakage of contaminated aquifer water into BNP and its potential effects on water quality. Groundwater flux to Biscayne Bay is being studied using pressure measurements and geochemical analyses from submarine wells, electromagnetic seepage meters, streaming resistivity profiling, and local and regional model simulations. Both seepage meters and water analyses provide point information that can be placed into the regional context provided by flow models and geochemical and geophysical profiling, which, in turn, constrain the groundwater contribution. Water samples were collected approximately quarterly from August 2002 until March 2004 from submarine wells along a transect through Biscayne Bay and across the reef to the shelf edge. Samples were analyzed for conductivity (salinity), dissolved oxygen, temperature, redox potential, nutrients, metals, strontium isotopes, radon, sulfate, and wastewater compounds. Low-salinity water was identified from nearshore wells and indicates seepage from the Biscayne Aquifer and/or surface-water intrusion into the rocks along western Biscayne Bay. Analyses of water samples (n = 109) collected from wells across the Florida shelf show no consistent evidence of wastewater contaminants occurring in groundwater beneath BNP. No significant leakage from the Floridan Aquifer (characterized by low strontium-isotope ratios) was detected in the wells. The groundwater beneath the shelf can be characterized as reduced seawater, modified by microbial respiration to remove oxygen, and interacting with sediments and minerals in the host limestone. The data from submarine well samples are consistent with groundwater model results that indicate a narrow zone of discharge along the western margin of Biscayne Bay. This zone varies in width from 100 to 1000 m along the coast. A seepage meter placed in this zone during March 2004 recorded an average flow of 23 cm/day. Submarine discharge is estimated to be about 6% of the surface-water flow to Biscayne Bay, and almost all of this is in the northern half of the bay, where shoreline and water-table elevations are greatest. Saltwater intrusion extends farther inland in the southern portion of the bay, where water-table and coastal elevations are low. Shoreline-parallel radon-222 profiles also indicate more seepage in the north than south, but suggest low-salinity water extends between 1 and 2 km offshore. Resistivity profiling provided a fourth technique (along with wells, models, and radon) that documents low-salinity water along the coast, particularly toward the northern bay. Resistivity is the only methodology that indicates presence of brackish water 5 km offshore, an observation that requires verification. Interdisciplinary approaches that estimate submarine flow to this tropical estuary are helping reinforce observations made by complimentary methods, while clearly identifying other observations as worthy of further investigation and verification.

Geophysical Investigations at Hidden Dam, Raymond, California Flow Simulations

USGS Publications Warehouse

Minsley, Burke J.; Ikard, Scott

2010-01-01

Numerical flow modeling and analysis of observation-well data at Hidden Dam are carried out to supplement recent geophysical field investigations at the site (Minsley and others, 2010). This work also is complementary to earlier seepage-related studies at Hidden Dam documented by Cedergren (1980a, b). Known seepage areas on the northwest right abutment area of the downstream side of the dam was documented by Cedergren (1980a, b). Subsequent to the 1980 seepage study, a drainage blanket with a sub-drain system was installed to mitigate downstream seepage. Flow net analysis provided by Cedergren (1980a, b) suggests that the primary seepage mechanism involves flow through the dam foundation due to normal reservoir pool elevations, which results in upflow that intersects the ground surface in several areas on the downstream side of the dam. In addition to the reservoir pool elevations and downstream surface topography, flow is also controlled by the existing foundation geology as well as the presence or absence of a horizontal drain in the downstream portion of the dam. The current modeling study is aimed at quantifying how variability in dam and foundation hydrologic properties influences seepage as a function of reservoir stage. Flow modeling is implemented using the COMSOL Multiphysics software package, which solves the partially saturated flow equations in a two-dimensional (2D) cross-section of Hidden Dam that also incorporates true downstream topography. Use of the COMSOL software package provides a more quantitative approach than the flow net analysis by Cedergren (1980a, b), and allows for rapid evaluation of the influence of various parameters such as reservoir level, dam structure and geometry, and hydrogeologic properties of the dam and foundation materials. Historical observation-well data are used to help validate the flow simulations by comparing observed and predicted water levels for a range of reservoir elevations. The flow models are guided by, and discussed in the context of, the geophysical work (Minsley and others, 2010) where appropriate.

Quantification and characterization of leakage errors

NASA Astrophysics Data System (ADS)

Wood, Christopher J.; Gambetta, Jay M.

2018-03-01

We present a general framework for the quantification and characterization of leakage errors that result when a quantum system is encoded in the subspace of a larger system. To do this we introduce metrics for quantifying the coherent and incoherent properties of the resulting errors and we illustrate this framework with several examples relevant to superconducting qubits. In particular, we propose two quantities, the leakage and seepage rates, which together with average gate fidelity allow for characterizing the average performance of quantum gates in the presence of leakage and show how the randomized benchmarking protocol can be modified to enable the robust estimation of all three quantities for a Clifford gate set.

Biodiversity on the Rocks: Macrofauna Inhabiting Authigenic Carbonate at Costa Rica Methane Seeps

PubMed Central

Levin, Lisa A.; Mendoza, Guillermo F.; Grupe, Benjamin M.; Gonzalez, Jennifer P.; Jellison, Brittany; Rouse, Greg; Thurber, Andrew R.; Waren, Anders

2015-01-01

Carbonate communities: The activity of anaerobic methane oxidizing microbes facilitates precipitation of vast quantities of authigenic carbonate at methane seeps. Here we demonstrate the significant role of carbonate rocks in promoting diversity by providing unique habitat and food resources for macrofaunal assemblages at seeps on the Costa Rica margin (400–1850 m). The attendant fauna is surprisingly similar to that in rocky intertidal shores, with numerous grazing gastropods (limpets and snails) as dominant taxa. However, the community feeds upon seep-associated microbes. Macrofaunal density, composition, and diversity on carbonates vary as a function of seepage activity, biogenic habitat and location. The macrofaunal community of carbonates at non-seeping (inactive) sites is strongly related to the hydrography (depth, temperature, O2) of overlying water, whereas the fauna at sites of active seepage is not. Densities are highest on active rocks from tubeworm bushes and mussel beds, particularly at the Mound 12 location (1000 m). Species diversity is higher on rocks exposed to active seepage, with multiple species of gastropods and polychaetes dominant, while crustaceans, cnidarians, and ophiuroids were better represented on rocks at inactive sites. Macro-infauna (larger than 0.3 mm) from tube cores taken in nearby seep sediments at comparable depths exhibited densities similar to those on carbonate rocks, but had lower diversity and different taxonomic composition. Seep sediments had higher densities of ampharetid, dorvilleid, hesionid, cirratulid and lacydoniid polychaetes, whereas carbonates had more gastropods, as well as syllid, chrysopetalid and polynoid polychaetes. Stable isotope signatures and metrics: The stable isotope signatures of carbonates were heterogeneous, as were the food sources and nutrition used by the animals. Carbonate δ13Cinorg values (mean = -26.98‰) ranged from -53.3‰ to +10.0‰, and were significantly heavier than carbonate δ13Corg (mean = -33.83‰), which ranged from -74.4‰ to -20.6‰. Invertebrates on carbonates had average δ13C (per rock) = -31.0‰ (range -18.5‰ to -46.5‰) and δ15N = 5.7‰ (range -4.5‰ to +13.4‰). Average δ13C values did not differ between active and inactive sites; carbonate fauna from both settings depend on chemosynthesis-based nutrition. Community metrics reflecting trophic diversity (SEAc, total Hull Area, ranges of δ13C and δ15N) and species packing (mean distance to centroid, nearest neighbor distance) also did not vary as a function of seepage activity or site. However, distinct isotopic signatures were observed among related, co-occurring species of gastropods and polychaetes, reflecting intense microbial resource partitioning. Overall, the substrate and nutritional heterogeneity introduced by authigenic seep carbonates act to promote diverse, uniquely adapted assemblages, even after seepage ceases. The macrofauna in these ecosystems remain largely overlooked in most surveys, but are major contributors to biodiversity of chemosynthetic ecosystems and the deep sea in general. PMID:26158723

Groundwater-Surface Water Interaction: A Case Study of Embankment Dam Safety Assessment in Sweden.

NASA Astrophysics Data System (ADS)

Ferdos, F.; Dargahi, B.

2015-12-01

Seepage, when excessive and unimpeded, can cause embankment dam failure. Such failures are often initiated by internal erosion and piping. Modelling these phenomena in embankment dams, accounting for the groundwater-surface water interactions, is crucial when performing dam safety assessments. The aim of this study was to evaluate the applicability of modelling seepage flows in multi-region dams using a finite element based multi-physics model. The model was applied to the Trängslet dam, the largest dam in Sweden. The objectives were to analyze the characteristics of both the flow and the surface-ground water interactions occurring in the dam, including: i) the saturated and unsaturated laminar flow regimes within the dam body, ii) the non-linear through-flow in the dam shoulders' coarse material, iii) the influence of the surface waves in the reservoir on the seepage flow by coupling the physics to a hydrodynamic interface, and iv) the influence of a conceptual "erosion tunnel" on the seepage flow and its interaction with the surface water flow by coupling the physics to a CFD interface. The focus of the study was on the influence of the transient water head boundary condition, surface waves and the internal erosion tunnel on the location of the phreatic line and the seepage flow rate. The simulated seepage flow of the dam in its original condition tallied with the monitoring measurements (40-70 l/s). The main feature found was the relatively high position of the phreatic line, which could compromise the stability of the dam. The combination of the seepage model with the reservoir hydrodynamics indicated a negligible influence of the surface waves on seepage flow. Results from the combination of the seepage model with fluid dynamics indicated that a conceptual "erosion tunnel" placed within the dam, even as high as in the unsaturated zone, significantly affects the phreatic line's position. This also causes the seepage flow to increase by several orders of magnitude, resulting in non-linear turbulent flow regimes in the downstream shoulder of the dam and, ultimately, dam failure. While the modelling was limited by a lack of reliable geometrical and geotechnical data, the results of the study do highlight the importance of including groundwater-surface water interactions in dam safety assessments.

An analytical solution for predicting the transient seepage from a subsurface drainage system

NASA Astrophysics Data System (ADS)

Xin, Pei; Dan, Han-Cheng; Zhou, Tingzhang; Lu, Chunhui; Kong, Jun; Li, Ling

2016-05-01

Subsurface drainage systems have been widely used to deal with soil salinization and waterlogging problems around the world. In this paper, a mathematical model was introduced to quantify the transient behavior of the groundwater table and the seepage from a subsurface drainage system. Based on the assumption of a hydrostatic pressure distribution, the model considered the pore-water flow in both the phreatic and vadose soil zones. An approximate analytical solution for the model was derived to quantify the drainage of soils which were initially water-saturated. The analytical solution was validated against laboratory experiments and a 2-D Richards equation-based model, and found to predict well the transient water seepage from the subsurface drainage system. A saturated flow-based model was also tested and found to over-predict the time required for drainage and the total water seepage by nearly one order of magnitude, in comparison with the experimental results and the present analytical solution. During drainage, a vadose zone with a significant water storage capacity developed above the phreatic surface. A considerable amount of water still remained in the vadose zone at the steady state with the water table situated at the drain bottom. Sensitivity analyses demonstrated that effects of the vadose zone were intensified with an increased thickness of capillary fringe, capillary rise and/or burying depth of drains, in terms of the required drainage time and total water seepage. The analytical solution provides guidance for assessing the capillary effects on the effectiveness and efficiency of subsurface drainage systems for combating soil salinization and waterlogging problems.

Longitudinal hydraulic analysis of river‐aquifer exchanges

USGS Publications Warehouse

Konrad, C.P.

2006-01-01

A longitudinal analysis of transient flow between a river and an underlying aquifer is developed to calculate flow rates between the river and the aquifer and the location of groundwater seepage into the river as it changes over time. Two flow domains are defined in the analysis: an upstream domain of fluvial recharge, where water flows vertically from the river into the unsaturated portion of the aquifer and horizontally in saturated parts of the aquifer, and a downstream domain of groundwater seepage to the river, where groundwater flows parallel to the underlying impermeable base. The river does not necessarily penetrate completely through the aquifer. A one‐dimensional, unsteady flow equation is derived from mass conservation, Darcy's law, and the geometry of the river‐aquifer system to calculate the water table position and the groundwater seepage rate into the river. Models based on numerical and analytical solutions of the flow equation were applied to a reach of the Methow River in north central Washington. The calibrated models simulated groundwater seepage with a root‐mean‐square error less than 5% of the mean groundwater seepage rates for three low‐flow evaluation periods. The analytical model provides a theoretical basis for a nonlinear exponential base flow recession generated by a draining aquifer, but not an explicit functional form for the recession. Unlike cross‐sectional approaches, the longitudinal approach allows the analysis of the length and location of groundwater seepage to a river, which have important ecological implications in many rivers. In the numerical simulations, the length of the groundwater seepage varied seasonally by about 4 km and the upstream boundary of groundwater seepage was within 689 m of its location at a stream gage on 9 September 2001 and within 91 m of its location on 6 October 2002. To demonstrate its utility in ecological applications, the numerical model was used to calculate differences in length of groundwater seepage to the Methow River under an early runoff scenario and the timing of those differences with respect to life stages of chinook salmon.

Analysis of a mesoscale infiltration and water seepage test in unsaturated fractured rock: Spatial variabilities and discrete fracture patterns

USGS Publications Warehouse

Zhou, Q.; Salve, R.; Liu, H.-H.; Wang, J.S.Y.; Hudson, D.

2006-01-01

A mesoscale (21??m in flow distance) infiltration and seepage test was recently conducted in a deep, unsaturated fractured rock system at the crossover point of two underground tunnels. Water was released from a 3??m ?? 4??m infiltration plot on the floor of an alcove in the upper tunnel, and seepage was collected from the ceiling of a niche in the lower tunnel. Significant temporal and (particularly) spatial variabilities were observed in both measured infiltration and seepage rates. To analyze the test results, a three-dimensional unsaturated flow model was used. A column-based scheme was developed to capture heterogeneous hydraulic properties reflected by these spatial variabilities observed. Fracture permeability and van Genuchten ?? parameter [van Genuchten, M.T., 1980. A closed-form equation for predicting the hydraulic conductivity of unsaturated soils. Soil Sci. Soc. Am. J. 44, 892-898] were calibrated for each rock column in the upper and lower hydrogeologic units in the test bed. The calibrated fracture properties for the infiltration and seepage zone enabled a good match between simulated and measured (spatially varying) seepage rates. The numerical model was also able to capture the general trend of the highly transient seepage processes through a discrete fracture network. The calibrated properties and measured infiltration/seepage rates were further compared with mapped discrete fracture patterns at the top and bottom boundaries. The measured infiltration rates and calibrated fracture permeability of the upper unit were found to be partially controlled by the fracture patterns on the infiltration plot (as indicated by their positive correlations with fracture density). However, no correlation could be established between measured seepage rates and density of fractures mapped on the niche ceiling. This lack of correlation indicates the complexity of (preferential) unsaturated flow within the discrete fracture network. This also indicates that continuum-based modeling of unsaturated flow in fractured rock at mesoscale or a larger scale is not necessarily conditional explicitly on discrete fracture patterns. ?? 2006 Elsevier B.V. All rights reserved.

Can a Red Wood-Ant Nest Be Associated with Fault-Related CH4 Micro-Seepage? A Case Study from Continuous Short-Term In-Situ Sampling

PubMed Central

Grumpe, Arne; Becker, Adrian; Wöhler, Christian

2018-01-01

Simple Summary Methane (CH4) is common on Earth but its natural sources are not well-characterized. We investigated concentrations of CH4 and its stable carbon isotope (δ13C-CH4) within a red wood-ant (RWA; Formica polyctena) nest in the Neuwied Basin, a part of the East Eifel Volcanic Field (EEVF), and tested for associations between methane concentration and RWA activity patterns, earthquakes, and earth tides. Methane degassing was not synchronized with earth tides, nor was it influenced by a micro-earthquake or RWA activity. Elevated CH4 concentrations in nest gas appear to result from a combination of microbial activity and fault-related emissions. The latter could result from micro-seepage of methane derived from low-temperature gas-water-rock reactions that subsequently moves via fault networks through the RWA nest or from overlapping micro-seepage of magmatic CH4 from the Eifel plume. Given the abundance of RWA nests on the landscape, their role as sources of microbial CH4 and biological indicators for abiotically-derived CH4 should be included in estimations of methane emissions that are contributing to climatic change. Abstract We measured methane (CH4) and stable carbon isotope of methane (δ13C-CH4) concentrations in ambient air and within a red wood-ant (RWA; Formica polyctena) nest in the Neuwied Basin (Germany) using high-resolution in-situ sampling to detect microbial, thermogenic, and abiotic fault-related micro-seepage of CH4. Methane degassing from RWA nests was not synchronized with earth tides, nor was it influenced by micro-earthquake degassing or concomitantly measured RWA activity. Two δ13C-CH4 signatures were identified in nest gas: −69‰ and −37‰. The lower peak was attributed to microbial decomposition of organic matter within the RWA nest, in line with previous observations that RWA nests are hot-spots of microbial CH4. The higher peak has not been reported in previous studies. We attribute this peak to fault-related CH4 emissions moving via fault networks into the RWA nest, which could originate either from thermogenic or abiotic CH4 formation. Sources of these micro-seepages could be Devonian schists, iron-bearing “Klerf Schichten”, or overlapping micro-seepage of magmatic CH4 from the Eifel plume. Given the abundance of RWA nests on the landscape, their role as sources of microbial CH4 and biological indicators for abiotically-derived CH4 should be included in estimation of methane emissions that are contributing to climatic change. PMID:29597318

Calibration and use of continuous heat-type automated seepage meters for submarine groundwater discharge measurements

USGS Publications Warehouse

Mwashote, B.M.; Burnett, W.C.; Chanton, J.; Santos, I.R.; Dimova, N.; Swarzenski, P.W.

2010-01-01

Submarine groundwater discharge (SGD) assessments were conducted both in the laboratory and at a field site in the northeastern Gulf of Mexico, using a continuous heat-type automated seepage meter (seepmeter). The functioning of the seepmeter is based on measurements of a temperature gradient in the water between downstream and upstream positions in its flow pipe. The device has the potential of providing long-term, high-resolution measurements of SGD. Using a simple inexpensive laboratory set-up, we have shown that connecting an extension cable to the seepmeter has a negligible effect on its measuring capability. Similarly, the observed influence of very low temperature (???3 ??C) on seepmeter measurements can be accounted for by conducting calibrations at such temperatures prior to field deployments. Compared to manual volumetric measurements, calibration experiments showed that at higher water flow rates (>28 cm day-1 or cm3 cm-2 day-1) an analog flowmeter overestimated flow rates by ???7%. This was apparently due to flow resistance, turbulence and formation of air bubbles in the seepmeter water flow tubes. Salinity had no significant effect on the performance of the seepmeter. Calibration results from fresh water and sea water showed close agreement at a 95% confidence level significance between the data sets from the two media (R2 = 0.98). Comparatively, the seepmeter SGD measurements provided data that are comparable to manually-operated seepage meters, the radon geochemical tracer approach, and an electromagnetic (EM) seepage meter. ?? 2009 Elsevier Ltd.

Compacted Sewage Sludge as a Barrier for Tailings: The Heavy Metal Speciation and Total Organic Carbon Content in the Compacted Sludge Specimen

PubMed Central

Zhang, Huyuan; Zhang, Qing; Yang, Bo; Wang, Jinfang

2014-01-01

Acid mine drainage (AMD) was the main environmental problem facing the mining industry. For AMD had high heavy metals content and low pH, the compacted sewage sludge might be a barrier for tailings whose oxidation and weathering produced AMD, with its own carbon source, microorganism reduction ability and impermeability. To study the heavy metals environmental risk, under the simulate AMD, the deionized water (DW), and the pH 2.1 sulfuric acid water (SA) seepage conditions, respectively, the changes of the chemical speciation of heavy metals Cd, Cu, Fe, Ni, Zn and total organic carbon (TOC) content in the compacted sewage sludge were assessed in the different periods. The results indicated according to the distribution of heavy metals, the potential mobility was for Cd: 6.08 under AMD, 7.48 under SA, ∞ under DW; for Cu: 0.08 under AMD, 0.17 under SA, 0.59 under DW; for Fe: 0.15 under AMD, 0.22 under SA, 0.22 under DW; for Ni: 2.60 under AMD, 1.69 under SA, 1.67 under DW; and for Zn: 0.15 under AMD, 0.23 under SA and 0.21 under DW at the second checking time. TOC content firstly decreased from 67.62±0% to 66.29±0.35%, then increased to 67.74±0.65% under the AMD seepage while TOC decreased to 63.30±0.53%, then to 61.33±0.37% under the DW seepage, decreased to 63.86±0.41%, then to 63.28±0.49% under SA seepage. That indicated under the AMD seepage, the suitable microorganisms communities in the compacted sewage sludge were activated. And the heavy metals environmental risk of compacted sewage sludge was lower with AMD condition than with other two. So the compacted sewage sludge as a barrier for tailings was feasible as the aspect of environmental risk assessment. PMID:24979755

A steady state solution for ditch drainage problem with special reference to seepage face and unsaturated zone flow contribution: Derivation of a new drainage spacing eqaution

NASA Astrophysics Data System (ADS)

Yousfi, Ammar; Mechergui, Mohammed

2016-04-01

The seepage face is an important feature of the drainage process when recharge occurs to a permeable region with lateral outlets. Examples of the formation of a seepage face above the downstream water level include agricultural land drained by ditches. Flow problem to these drains has been investigated extensively by many researchers (e.g. Rubin, 1968; Hornberger et al. 1969; Verma and Brutsaert, 1970; Gureghian and Youngs, 1975; Vauclin et al., 1975; Skaggs and Tang, 1976; Youngs, 1990; Gureghian, 1981; Dere, 2000; Rushton and Youngs, 2010; Youngs, 2012; Castro-Orgaz et al., 2012) and may be tackled either using variably saturated flow models, or the complete 2-D solution of Laplace equation, or using the Dupuit-Forchheimer approximation; the most widely accepted methods to obtain analytical solutions for unconfined drainage problems. However, the investigation reported by Clement et al. (1996) suggest that accounting for the seepage face alone, as in the fully saturated flow model, does not improve the discharge estimate because of disregarding flow the unsaturated zone flow contribution. This assumption can induce errors in the location of the water table surface and results in an underestimation of the seepage face and the net discharge (e.g. Skaggs and Tang, 1976; Vauclin et al., 1979; Clement et al., 1996). The importance of the flow in the unsaturated zone has been highlighted by many authors on the basis of laboratory experiments and/or numerical experimentations (e.g. Rubin, 1968; Verma and Brutsaert, 1970; Todsen, 1973; Vauclin et al., 1979; Ahmad et al., 1993; Anguela, 2004; Luthin and Day, 1955; Shamsai and Narasimhan, 1991; Wise et al., 1994; Clement et al., 1996; Boufadel et al., 1999; Romano et al., 1999; Kao et al., 2001; Kao, 2002). These studies demonstrate the failure of fully saturated flow models and suggested that the error made when using these models not only depends on soil properties but also on the infiltration rate as reported by Kao et al. (2001). In this work, a novel solution based on theoretical approach will be adapted to incorporate both the seepage face and the unsaturated zone flow contribution for solving ditch drained aquifers problems. This problem will be tackled on the basis of the approximate 2D solution given by Castro-Orgaz et al. (2012). This given solution yields the generalized water table profile function with a suitable boundary condition to be determined and provides a modified DF theory which permits as an outcome the analytical determination of the seepage face. To assess the ability of the developed equation for water-table estimations, the obtained results were compared with numerical solutions to the 2-D problem under different conditions. It is shown that results are in fair agreement and thus the resulting model can be used for designing ditch drainage systems. With respect to drainage design, the spacings calculated with the newly derived equation are compared with those computed from the DF theory. It is shown that the effect of the unsaturated zone flow contribution is limited to sandy soils and The calculated maximum increase in drain spacing is about 30%. Keywords: subsurface ditch drainage; unsaturated zone; seepage face; water-table, ditch spacing equation

Modeling coupled thermal-hydrological-chemical processes in theunsaturated fractured rock of Yucca Mountain, Nevada: Heterogeneity andseepage

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mukhopadhyay, Sumit; Sonnenthal, Eric L.; Spycher, Nicolas

An understanding of processes affecting seepage intoemplacement tunnels is needed for correctly predicting the performance ofunderground radioactive waste repositories. It has been previouslyestimated that the capillary and vaporization barriers in the unsaturatedfractured rock of Yucca Mountain are enough to prevent seepage underpresent day infiltration conditions. It has also been thought that asubstantially elevated infiltration flux will be required to causeseepage after the thermal period is over. While coupledthermal-hydrological-chemical (THC) changes in Yucca Mountain host rockdue to repository heating has been previously investigated, those THCmodels did not incorporate elements of the seepage model. In this paper,we combine the THC processes inmore » unsaturated fractured rock with theprocesses affecting seepage. We observe that the THC processes alter thehydrological properties of the fractured rock through mineralprecipitation and dissolution. We show that such alteration in thehydrological properties of the rock often leads to local flow channeling.We conclude that such local flow channeling may result in seepage undercertain conditions, even with nonelevated infiltrationfluxes.« less

Remote semi-continuous flow rate logging seepage meter

NASA Technical Reports Server (NTRS)

Reay, William G.; Walthall, Harry G.

1991-01-01

The movement of groundwater and its associated solutes from upland regions was implicated in the degradation of receiving surface water bodies. Current efforts to directly measure this influx of water incorporate manually operated seepage meters which are hindered by severe limitations. A prototype seepage meter was developed by NASA Langley Research Center and Virginia Polytechnic Institute and State University that will allow for the semi-continuous collection and data logging of seepage flux across the sediment water interface. The meter is designed to operate at depths to 40 meters, and alleviate or minimize all disadvantages associated with traditional methods while remaining cost effective. The unit was designed to operate independently for time periods on the order of weeks with adjustable sample sequences depending upon hydrologic conditions. When used in conjunction with commercially available pressure transducers, this seepage meter allows for correlations to be made between groundwater discharge and tidal/sea state conditions in coastal areas. Field data from the Chesapeake Bay and Florida Bay systems are presented.

The Seepage Simulation of Single Hole and Composite Gas Drainage Based on LB Method

NASA Astrophysics Data System (ADS)

Chen, Yanhao; Zhong, Qiu; Gong, Zhenzhao

2018-01-01

Gas drainage is the most effective method to prevent and solve coal mine gas power disasters. It is very important to study the seepage flow law of gas in fissure coal gas. The LB method is a simplified computational model based on micro-scale, especially for the study of seepage problem. Based on fracture seepage mathematical model on the basis of single coal gas drainage, using the LB method during coal gas drainage of gas flow numerical simulation, this paper maps the single-hole drainage gas, symmetric slot and asymmetric slot, the different width of the slot combined drainage area gas flow under working condition of gas cloud of gas pressure, flow path diagram and flow velocity vector diagram, and analyses the influence on gas seepage field under various working conditions, and also discusses effective drainage method of the center hole slot on both sides, and preliminary exploration that is related to the combination of gas drainage has been carried on as well.

Chamber and eddy covariance comparisons of alternate wetting and drying and continuous flood irrigation in mid-South rice

NASA Astrophysics Data System (ADS)

Reba, M. L.; Fong, B.; Adviento-Borbe, A.; Runkle, B.

2016-12-01

The subtropical humid mid-south region produces nearly 75% of US rice. Rice cultivation contributes higher amounts of GHG emissions (CO2, CH4, and N2O) due to flooded field conditions. Accurate measurements of gas fluxes are important to regional and global climate models. A comparison between eddy covariance and static vented flux chamber measurement techniques is presented. These measurements were collected in two NE Arkansas commercial rice fields in 2015 and 2016 production seasons under two irrigation treatments: Alternate Wetting and Drying (AWD) and continuous flood (CF) irrigation. AWD can reduce GHG emissions and water use compared to CF by introducing aerobic conditions that reduce methanogen activity and drained conditions decrease water loss due to seepage or evapotranspiration. N2O was measured only with vented chambers, while CO2 and CH4 were measured with both techniques. In the vented flux chamber technique, headspace gas sampling occurred at least once a week every 20 minutes for one hour of chamber closure. Gas Chromatograph equipped with ECD and FID were used to analyze gas concentrations. Eddy covariance used high frequency measurements wind and concentration measurements to determine fluxes. Chamber measurements were found to be more sensitive during seedling and early vegetative growth while eddy covariance was more sensitive after canopy closure during mid-vegetative to reproductive growth. Unlike eddy covariance which measured net CO2 exchange, flux chamber method measured only CO2 ecosystem respiration because flux measurements occurred using an opaque chamber material.

Microbial processes and communities in sediment samples along a transect across the Lusi mud volcano, Indonesia

NASA Astrophysics Data System (ADS)

Krueger, Martin; Straaten, Nontje; Mazzini, Adriano

2015-04-01

The Lusi eruption represents one of the largest ongoing sedimentary hosted geothermal systems. This eruption started in 2006 following to a 6.3 M earthquake that stroke Java Island. Since then it has been spewing boiling mud from a central crater with peaks reaching 180.000 m3 per day. Today an area of about 8 km2 is covered by locally dried mud breccia where a network of hundreds of satellite seeping pools is active. Numerous investigations focused on the study of offshore microbial colonies that commonly thrive at offshore methane seeps and mud volcanoes, however very little has been done for onshore seeping structures. Lusi represents a unique opportunity to complete a comprehensive study of onshore microbial communities fed by the seepage of CH4 and CO2 as well as of heavier liquid hydrocarbons originating from several km below the surface. We conducted a sampling campaign at the Lusi site collecting samples of fresh mud close to the erupting crater using a remote controlled drone. In addition we completed a transect towards outer parts of the crater to collect older, weathered samples for comparison. In all samples active microorganisms were present. The highest activities for CO2 and CH4 production as well as for CH4 oxidation and hydrocarbon degradation were observed in medium-age mud samples collected roughly in the middle of the transect. Rates for aerobic methane oxidation were high, as was the potential of the microbial communities to degrade hydrocarbons (oils, alkanes, BTEX tested). The data suggests a transition of microbial populations from an anaerobic, hydrocarbon-driven metabolism in fresher samples from center or from small seeps to more generalistic, aerobic microbial communities in older, more consolidated sediments. Currently, the microbial communities in the different sediment samples are analyzed using quantitative PCR and T-RFLP combined with MiSeq sequencing. This study represents an initial step to better understand onshore seepage systems and provides an ideal analogue for comparison with the better investigated offshore structures.

Study on seepage characteristics of inclined wall dam after heavy drought

NASA Astrophysics Data System (ADS)

Wei, YE; Fuheng, MA

2018-05-01

For seepage of the dam slope with cracks after drought, there are two methods to study including the physical model test and numerical calculation. However, the physical model test can not visualize the seepage field in the dam body intuitively, and the mathematical model is not accurate because of the precision of the parameter. So in this paper, combined physical model with mathematical model, the surface crack development on the dam slope and the changes of pore water pressure were studied through the physical model test, and then numerical calculation was carried out to analyze the internal seepage of the dam body. The results showed that cracks were more likely to develop at middle of the upstream dam slope and dam heel, and cracks for different degrees appeared at different parts of the dam slope after drought. The development of cracks provided a preferential permeable channel which caused that the area near the crack was easily to become saturated. The saturated zone kept expanding leading the infiltration line to be close to the transition layer and the infiltration line was no longer a smooth curve. There were seepage damages and landslide hazards existing with such seepage characteristics, which would threaten the safety of the dam.

Treatment of septic tank effluents by a full-scale capillary seepage soil biofiltration system.

PubMed

Fan, Chihhao; Chang, Fang-Chih; Ko, Chun-Han; Teng, Chia-Ji; Chang, Tzi-Chin; Sheu, Yiong-Shing

2009-03-01

The purpose of this study is to evaluate the efficiency of septic tank effluent treatment by an underground capillary seepage soil biofiltration system in a suburban area of Taipei, Taiwan. In contrast to traditional subsurface wastewater infiltration systems, capillary seepage soil biofiltration systems initially draw incoming influent upwards from the distribution pipe by capillary and siphonage actions, then spread influent throughout the soil biofiltration bed. The underground capillary seepage soil biofiltration system consists of a train of underground treatment units, including one wastewater distribution tank, two capillary seepage soil biofiltration units in series, and a discharge tank. Each capillary seepage soil biofiltration unit contains one facultative digestion tank and one set of biofiltration beds. At the flow rate of 50 m3/day, average influent concentrations of biochemical oxygen demand (BOD), suspended solid (SS), ammonia nitrogen (NH3-N), and total phosphates (TP), were 36.15 mg/L, 29.14 mg/L, 16.05 mg/L, and 1.75 mg/L, respectively. After 1.5 years of system operation, the measured influent and effluent results show that the treatment efficiencies of the soil biofiltration system for BOD, SS, NH3-N, TP, and total coliforms are 82.96%, 60.95%, 67.17%, 74.86%, and 99.99%, respectively.

R-Area Reactor 1993 annual groundwater monitoring report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1994-09-01

Groundwater was sampled and analyzed during 1993 from wells monitoring the following locations in R Area: Well cluster P20 east of R Area (one well each in the water table and the McBean formation), the R-Area Acid/Caustic Basin (the four water-table wells of the RAC series), the R-Area Ash Basin/Coal Pile (one well of the RCP series in the Congaree formation and one in the water table), the R-Area Disassembly Basin (the three water-table wells of the RDB series), the R-Area Burning/Rubble Pits (the four water-table wells of the RRP series), and the R-Area Seepage Basins (numerous water-table wells inmore » the RSA, RSB, RSC, RSD, RSE, and RSF series). Lead was the only constituent detected above its 50{mu}g/L standard in any but the seepage basin wells; it exceeded that level in one B well and in 23 of the seepage basin wells. Cadmium exceeded its drinking water standard (DWS) in 30 of the seepage basin wells, as did mercury in 10. Nitrate-nitrite was above DWS once each in two seepage basin wells. Tritium was above DWS in six seepage basin wells, as was gross alpha activity in 22. Nonvolatile beta exceeded its screening standard in 29 wells. Extensive radionuclide analyses were requested during 1993 for the RCP series and most of the seepage basin wells. Strontium-90 in eight wells was the only specific radionuclide other than tritium detected above DWS; it appeared about one-half of the nonvolatile beta activity in those wells.« less

Flow units classification for geostatisitical three-dimensional modeling of a non-marine sandstone reservoir: A case study from the Paleocene Funing Formation of the Gaoji Oilfield, east China

NASA Astrophysics Data System (ADS)

Zhang, Penghui; Zhang, Jinliang; Wang, Jinkai; Li, Ming; Liang, Jie; Wu, Yingli

2018-05-01

Flow units classification can be used in reservoir characterization. In addition, characterizing the reservoir interval into flow units is an effective way to simulate the reservoir. Paraflow units (PFUs), the second level of flow units, are used to estimate the spatial distribution of continental clastic reservoirs at the detailed reservoir description stage. In this study, we investigate a nonroutine methodology to predict the external and internal distribution of PFUs. The methodology outlined enables the classification of PFUs using sandstone core samples and log data. The relationships obtained between porosity, permeability and pore throat aperture radii (r35) values were established for core and log data obtained from 26 wells from the Funing Formation, Gaoji Oilfield, Subei Basin, China. The present study refines predicted PFUs at logged (0.125-m) intervals, whose scale is much smaller than routine methods. Meanwhile, three-dimensional models are built using sequential indicator simulation to characterize PFUs in wells. Four distinct PFUs are classified and located based on the statistical methodology of cluster analysis, and each PFU has different seepage ability. The results of this study demonstrate the obtained models are able to quantify reservoir heterogeneity. Due to different petrophysical characteristics and seepage ability, PFUs have a significant impact on the distribution of the remaining oil. Considering these allows a more accurate understanding of reservoir quality, especially within non-marine sandstone reservoirs.

Evaluation of the use of reach transmissivity to quantify leakage beneath Levee 31N, Miami-Dade County, Florida

USGS Publications Warehouse

Nemeth, Mark S.; Wilcox, Walter M.; Solo-Gabriele, Helena M.

2000-01-01

A coupled ground- and surface-water model (MODBRANCH) was developed to estimate ground-water flow beneath Levee 31N in Miami-Dade County, Florida, and to simulate hydrologic conditions in the surrounding area. The study included compilation of data from monitoring stations, measurement of vertical seepage rates in wetlands, and analysis of the hydrogeologic properties of the ground-water aquifer within the study area. In addition, the MODBRANCH code was modified to calculate the exchange between surface-water channels and ground water using a relation based on the concept of reach transmissivity. The modified reach-transmissivity version of the MODBRANCH code was successfully tested on three simple problems with known analytical solutions. It was also tested and determined to function adequately on one field problem that had previously been solved using the unmodified version of the software. The modified version of MODBRANCH was judged to have performed satisfactorily, and it required about 60 percent as many iterations to reach a solution. Additionally, its input parameters are more physically-based and less dependent on model-grid spacing. A model of the Levee 31N area was developed and used with the original and modified versions of MODBRANCH, which produced similar output. The mean annual modeled ground-water heads differed by only 0.02 foot, and the mean annual canal discharge differed by less than 1.0 cubic foot per second. Seepage meters were used to quantify vertical seepage rates in the Everglades wetlands area west of Levee 31N. A comparison between results from the seepage meters and from the computer model indicated substantial differences that seemed to be a result of local variations in the hydraulic properties in the topmost part of the Biscayne aquifer. The transmissivity of the Biscayne aquifer was estimated to be 1,400,000 square feet per day in the study area. The computer model was employed to simulate seepage of ground water beneath Levee 31N. Modeled seepage rates were usually between 100 and 400 cubic feet per day per foot of levee, but extreme values ranged from about -200 to 500 cubic feet per day (positive values indicate eastward seepage beneath the levee). The modeled seepage results were used to develop an algorithm to estimate seepage based on head differential at selected monitoring stations. The algorithm was determined to adequately predict ground-water seepage.

Experimental study of hyperspectral responses of plants grown on mud pit soil

NASA Astrophysics Data System (ADS)

Credoz, Anthony; Hédacq, Rémy; Barreau, Christophe; Dubucq, Dominique

2016-10-01

On-shore, hyperspectral imagery is currently used to detect and measure remotely oil spill extension for environmental purpose and hydrocarbon seepage for petroleum exploration. In this study, variations of hyperspectral signatures of vegetal species have been analyzed at the laboratory scale to detect indirectly the potential impacts on the plants of crude oil seepage and spills in the soil. Experimental study has been performed under greenhouse to simulate the exposure of two species of plants to a co-contamination of hydrocarbons and heavy metals contained in sludge from mud pit. Maize and bramble have been selected for this study since they are cultivated and spontaneous species respectively located in the region of interest. Five levels of exposure were performed over a period of 100 days. Reflectance evolution of each plant was measured with a spectroradiometer from 350 nm to 2500 nm with a dedicated leaf clip. Net morphological impacts were observed for maize with a global reduction of plants and leaves sizes correlated to the level of cocontamination. Hyperspectral measurement on maize revealed a higher reflectance in the absorption wavelength of water at 1450 and 1900 nm due to contamination and water stress. Reflectance in the visible increased at 600 nm (red interval) for bramble plants exposed to co-contamination. Then, the level of reflectance in the NIR decreased between 700 and 800 nm (red-edge) and absorption of water also decreased at 1450 and 1900 nm as described previously for the maize.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nelson, E.A.; Westbury, H.M. Jr.

The F- and H-Area Seepage Basins received liquid waste from the F and H chemical separation facilities from 1955 through 1988. Tree mortality in seepline fed wetlands down-slope from the basins was observed in the late 1970`s, and investigations were conducted to determine the cause and source of the impacts. Analysis of the soil and water in the tree-kill zones demonstrated a strong chemical linkage with the F- and H-Area seepage basins. Although no single cause of the mortality was determined, it was believed to be the result of interactions of alterations in the hydrology and erosional deposition, along withmore » lowering of pH and increased conductivity, sodium, aluminum, and nitrogen compounds. A mild drought during the growing season may also have increased the concentration of the chemical contaminants in the soils matrix. In 1988, the F- and H-Area Seepage Basins were closed and covered with a clay cap to reduce the rate of dispersion of the contaminants in the soil beneath the basins. Subsequent studies of the chemical composition of the tree-kill zone groundwater and toxicological characteristics of the seepline soil have shown a reduced contaminant flux. In 1993, an initial vegetation study was undertaken to determine the level of recovery by the plant communities in the tree-kill zones. This study repeats the initial vegetation investigation in order to further analyze and characterize the recovery of plant communities in the zones after an additional year of growth.« less

Geochemical characterization of tarballs on beaches along the California coast. Part I - Shallow seepage impacting the Santa Barbara Channel Islands, Santa Cruz, Santa Rosa and San Miguel

USGS Publications Warehouse

Hostettler, F.D.; Rosenbauer, R.J.; Lorenson, T.D.; Dougherty, J.

2004-01-01

Tarballs are common along the southern California coastline. This study investigates tarballs from beaches along this coastline, with a focus on Santa Cruz, Santa Rosa, and San Miquel Islands in the Santa Barbara Channel. The tarballs were fingerprinted using biomarker and stable carbon isotope parameters, and then grouped according to genetic similarities. The data show that the tarballs are of natural and not anthropogenic origin and that all originate from source rock within the Miocene Monterey Formation via shallow seeps offshore. Sterane biomarker parameters were found to vary widely in the sample set. Biodegradation, especially of the regular steranes, is the primary process impacting the biomarker distributions in a large group of samples. The most common tarball occurrences appear to come from offshore seepage near the west end of Santa Cruz Island. Another major group most likely was transported north from near Santa Monica Bay. Several individual occurrences of some of these tarball groups also were found on beaches as far north as Pt. Reyes and as far south as San Diego, indicating significant long-distance dispersal by ocean currents. This study begins a library of tarball fingerprints to be used as a database to help distinguish between natural and anthropogenic tar occurrences all along the California coast, and to compare shallow seepage with future samples of deeper production oils from the same area.

Shallow bedrock limits groundwater seepage-based headwater climate refugia

USGS Publications Warehouse

Briggs, Martin A.; Lane, John W.; Snyder, Craig D.; White, Eric A.; Johnson, Zachary; Nelms, David L.; Hitt, Nathaniel P.

2018-01-01

Groundwater/surface-water exchanges in streams are inexorably linked to adjacent aquifer dynamics. As surface-water temperatures continue to increase with climate warming, refugia created by groundwater connectivity is expected to enable cold water fish species to survive. The shallow alluvial aquifers that source groundwater seepage to headwater streams, however, may also be sensitive to seasonal and long-term air temperature dynamics. Depth to bedrock can directly influence shallow aquifer flow and thermal sensitivity, but is typically ill-defined along the stream corridor in steep mountain catchments. We employ rapid, cost-effective passive seismic measurements to evaluate the variable thickness of the shallow colluvial and alluvial aquifer sediments along a headwater stream supporting cold water-dependent brook trout (Salvelinus fontinalis) in Shenandoah National Park, VA, USA. Using a mean depth to bedrock of 2.6 m, numerical models predicted strong sensitivity of shallow aquifer temperature to the downward propagation of surface heat. The annual temperature dynamics (annual signal amplitude attenuation and phase shift) of potential seepage sourced from the shallow modeled aquifer were compared to several years of paired observed stream and air temperature records. Annual stream water temperature patterns were found to lag local air temperature by ∼8–19 d along the stream corridor, indicating that thermal exchange between the stream and shallow groundwater is spatially variable. Locations with greater annual signal phase lag were also associated with locally increased amplitude attenuation, further suggestion of year-round buffering of channel water temperature by groundwater seepage. Numerical models of shallow groundwater temperature that incorporate regional expected climate warming trends indicate that the summer cooling capacity of this groundwater seepage will be reduced over time, and lower-elevation stream sections may no longer serve as larger-scale climate refugia for cold water fish species, even with strong groundwater discharge.

Improving the accuracy of canal seepage detection through geospatial techniques

NASA Astrophysics Data System (ADS)

Arshad, Muhammad

With climatic change, many western states in the United States are experiencing drought conditions. Numerous irrigation districts are losing significant amount of water from their canal systems due to leakage. Every year, on the average 2 million acres of prime cropland in the US is lost to soil erosion, waterlogging and salinity. Lining of canals could save enormous amount of water for irrigating crops but in present time due to soaring costs of construction and environmental mitigation, adopting such program on a large scale would be excessive. Conventional techniques of seepage detection are expensive, time consuming and labor intensive besides being not very accurate. Technological advancements in remote sensing have made it possible to investigate irrigation canals for seepage sites identification. In this research, band-9 in the [NIR] region and band-45 in the [TIR] region of an airborne MASTER data has been utilized to highlight anomalies along irrigation canal at Phoenix, Arizona. High resolution (1 to 4 meter pixels) satellite images provided by private companies for scientific research and made available by Google to the public on Google Earth is then successfully used to separate those anomalies into water activity sites, natural vegetation, and man-made structures and thereby greatly improving the seepage detection ability of airborne remote sensing. This innovative technique is much faster and cost effective as compared to conventional techniques and past airborne remote sensing techniques for verification of anomalies along irrigation canals. This technique also solves one of the long standing problems of discriminating false impression of seepage sites due to dense natural vegetation, terrain relief and low depressions of natural drainages from true water related activity sites.

Evaluation of seepage and discharge uncertainty in the middle Snake River, southwestern Idaho

USGS Publications Warehouse

Wood, Molly S.; Williams, Marshall L.; Evetts, David M.; Vidmar, Peter J.

2014-01-01

The U.S. Geological Survey, in cooperation with the State of Idaho, Idaho Power Company, and the Idaho Department of Water Resources, evaluated seasonal seepage gains and losses in selected reaches of the middle Snake River, Idaho, during November 2012 and July 2013, and uncertainty in measured and computed discharge at four Idaho Power Company streamgages. Results from this investigation will be used by resource managers in developing a protocol to calculate and report Adjusted Average Daily Flow at the Idaho Power Company streamgage on the Snake River below Swan Falls Dam, near Murphy, Idaho, which is the measurement point for distributing water to owners of hydropower and minimum flow water rights in the middle Snake River. The evaluated reaches of the Snake River were from King Hill to Murphy, Idaho, for the seepage studies and downstream of Lower Salmon Falls Dam to Murphy, Idaho, for evaluations of discharge uncertainty. Computed seepage was greater than cumulative measurement uncertainty for subreaches along the middle Snake River during November 2012, the non-irrigation season, but not during July 2013, the irrigation season. During the November 2012 seepage study, the subreach between King Hill and C J Strike Dam had a meaningful (greater than cumulative measurement uncertainty) seepage gain of 415 cubic feet per second (ft3/s), and the subreach between Loveridge Bridge and C J Strike Dam had a meaningful seepage gain of 217 ft3/s. The meaningful seepage gain measured in the November 2012 seepage study was expected on the basis of several small seeps and springs present along the subreach, regional groundwater table contour maps, and results of regional groundwater flow model simulations. Computed seepage along the subreach from C J Strike Dam to Murphy was less than cumulative measurement uncertainty during November 2012 and July 2013; therefore, seepage cannot be quantified with certainty along this subreach. For the uncertainty evaluation, average uncertainty in discharge measurements at the four Idaho Power Company streamgages in the study reach ranged from 4.3 percent (Snake River below Lower Salmon Falls Dam) to 7.8 percent (Snake River below C J Strike Dam) for discharges less than 7,000 ft3/s in water years 2007–11. This range in uncertainty constituted most of the total quantifiable uncertainty in computed discharge, represented by prediction intervals calculated from the discharge rating of each streamgage. Uncertainty in computed discharge in the Snake River below Swan Falls Dam near Murphy was 10.1 and 6.0 percent at the Adjusted Average Daily Flow thresholds of 3,900 and 5,600 ft3/s, respectively. All discharge measurements and records computed at streamgages have some level of uncertainty that cannot be entirely eliminated. Knowledge of uncertainty at the Adjusted Average Daily Flow thresholds is useful for developing a measurement and reporting protocol for purposes of distributing water to hydropower and minimum flow water rights in the middle Snake River.

Seepage investigation using geophysical techniques at Coursier Lake Dam, B.C., Canada

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sirles, P.

1997-10-01

Subsurface seepage flow at Coursier Lake Dam was identified by onshore and offshore self-potential surveys, and electrical resistivity profiles and soundings during a Deficiency Investigation by BChydro. For typical seepage investigations baseline geophysical data are collected at {open_quotes}low-pool{close_quotes} level and the measurements are repeated when high hydraulic gradient conditions exist. At Coursier Lake Dam a rather unanticipated outcome of the low-pool surveys was that significant seepage beneath the structure was detected. The low-pool results were conclusive enough that, when combined with visual inspection and observation of sinkholes on the embankment, an immediate restriction was placed on the pool elevation. Thus,more » because of the identified potential hazard, the remaining geophysical investigations were conducted under a {open_quotes}minimum-pool{close_quotes} reservoir level in order to complete the comparative study. Therefore, the dam was studied under low- and minimum-pool reservoir conditions in the spring and fall of 1993, respectively. Low-pool data indicated very high resistivities (3000 to 5000 ohm-m) throughout the embankment indicating a coarse-average grain size, probably unsaturated sands and gravels. Higher resistivities (>5000 ohm-m) were obtained within the foundation deposits along the downstream toe indicating a combination of lower moisture content, coarser average grain size and higher porosity than the embankment. These electrical data indicate the subsurface conditions in the embankment and the foundation to be conducive to seepage. Results from low-pool SP surveys, performed both on-shore and offshore, indicate a dispersed or sheet flow seepage occurring nearly 1100 feet upstream of the intake. Therefore, apparently the seepage source begins far upstream of the embankment within the foundation deposits.« less

Timing of fluid seepage on summits of Quaker and Conical serpentine mud volcanoes, Mariana forearc: Evidence from U/Th dating of carbonate chimneys

NASA Astrophysics Data System (ADS)

Tong, Hongpeng; Fryer, Patricia; Feng, Dong; Chen, Duofu

2017-04-01

Serpetinization of forearc mantle along deep faults in the Mariana convergent plate margin permits formation of large active serpentinite mud volcanoes on the overiding plate within 90 km of the trench. Fluid seepage on summits of the mud volcanoes lead to the formation of authigenic carbonate chimneys close to the seafloor. Such carbonate chimneys are unique archives of past fluid seepage and assciated envrionemtnal parameters. Here, we report U/Th dating and stable carbon and oxygen isotopes of the chimneys from Quaker and Conical serpentine mud volcanoes. The resulting U/Th ages of samples from Quaker Seamount show three time intervals of 11,081 to10,542 yBP, 5,857 to 5,583 yBP, and 781 to 164 yBP, respectively. By comparison, carbonates from Conical Seamount have U/Th ages between 3,070 yBP and 1,623 yBP. Our results suggest that fluid seepage on the summits of serpentine mud volcanoes are episodic and probably locally controlled. Samples from Quaker seamount show depletion of 13C (δ13C=-7.0-0.4‰ V-PDB), indicating contribution of carbon from anoxic oxidation of abiogenic methane. By contrast, samples from Conical seamount have positive δ18O values (0.6-6.3), suggesting enrichment of 18O in the seepage fluid. The data obtained provide time integrated variation of seepage fluids and seepage dynamics that are archived in authigenic carbonates. This finding adds to the ongoing multidisciplinary effort to better constrain the environment in the Mariana forearc region and to determine the locally dominant biogeochemical processes. Acknowlegment: This study was funded by the CAS (Grant No. XDB06030102).

Importance of the colmation layer in the transport and removal of cyanobacteria, viruses, and dissolved organic carbon during natural lake-bank filtration

USGS Publications Warehouse

Harvey, Ronald W.; Metge, David W.; LeBlanc, Denis R.; Underwood, Jennifer C.; Aiken, George R.; Butler, Kenna D.; McCobb, Timothy D.; Jasperse, Jay

2015-01-01

This study focused on the importance of the colmation layer in the removal of cyanobacteria, viruses, and dissolved organic carbon (DOC) during natural bank filtration. Injection-and-recovery studies were performed at two shallow (0.5 m deep), sandy, near-shore sites at the southern end of Ashumet Pond, a waste-impacted, kettle pond on Cape Cod, MA, that is subject to periodic blooms of cyanobacteria and continuously recharges a sole-source drinking-water aquifer. The experiment involved assessing the transport behaviors of bromide (conservative tracer), Synechococcus sp. IU625 (cyanobacterium, 2.6 ± 0.2 µm), AS-1 (tailed cyanophage, 110 nm long), MS2 (coliphage, 26 nm diameter), and carboxylate-modified microspheres (1.7 µm diameter) introduced to the colmation layer using a bag-and-barrel (Lee-type) seepage meter. The injectate constituents were tracked as they were advected across the pond water–groundwater interface and through the underlying aquifer sediments under natural-gradient conditions past push-point samplers placed at ∼30-cm intervals along a 1.2-m-long, diagonally downward flow path. More than 99% of the microspheres, IU625, MS2, AS-1, and ∼44% of the pond DOC were removed in the colmation layer (upper 25 cm of poorly sorted bottom sediments) at two test locations characterized by dissimilar seepage rates (1.7 vs. 0.26 m d−1). Retention profiles in recovered core material indicated that >82% of the attached IU625 were in the top 3 cm of bottom sediments. The colmation layer was also responsible for rapid changes in the character of the DOC and was more effective (by three orders of magnitude) at removing microspheres than was the underlying 20-cm-thick segment of sediment.

Calibration and application of an automated seepage meter for monitoring water flow across the sediment-water interface.

PubMed

Zhu, Tengyi; Fu, Dafang; Jenkinson, Byron; Jafvert, Chad T

2015-04-01

The advective flow of sediment pore water is an important parameter for understanding natural geochemical processes within lake, river, wetland, and marine sediments and also for properly designing permeable remedial sediment caps placed over contaminated sediments. Automated heat pulse seepage meters can be used to measure the vertical component of sediment pore water flow (i.e., vertical Darcy velocity); however, little information on meter calibration as a function of ambient water temperature exists in the literature. As a result, a method with associated equations for calibrating a heat pulse seepage meter as a function of ambient water temperature is fully described in this paper. Results of meter calibration over the temperature range 7.5 to 21.2 °C indicate that errors in accuracy are significant if proper temperature-dependence calibration is not performed. The proposed calibration method allows for temperature corrections to be made automatically in the field at any ambient water temperature. The significance of these corrections is discussed.

Delineation and Characterization of Furnace Brook Watershed in Marshfield, Massachusetts: A Study of Effects upon Conjunctive Water Use within a Watershed

NASA Astrophysics Data System (ADS)

Croll, E. D.; Enright, R.

2012-12-01

An understanding of conjunctive use between surface and ground water is essential to resource management both for sustained public use and watershed conservation practices. The Furnace Brook watershed in Marshfield, Massachusetts supplies a coastal community of 25,132 residents with nearly 50% of the town water supply. As with many other coastal communities, development pressure has increased creating a growing demand for freshwater extraction. It has been observed, however, that portions of the stream and Furnace Pond disappear entirely. This has created a conflict between protection of the designated wetland areas and meeting public pressure for water resources, even within what is traditionally viewed as a humid region. Questions have arisen as to whether the town water extraction is influencing this losing behavior by excessively lowering water-table elevations and potentially endangering the health of the stream. This study set out to initially characterize these behaviors and identify possible influences of anthropogenic and natural sources acting upon the watershed including stream flow obstructions, water extraction, and geologic conditions. The initial characterization was conducted utilizing simple, low-cost and minimally intrusive methods as outlined by Lee and Cherry (1978), Rosenberry and LaBaugh (2008) and others during a six week period. Five monitoring stations were established along a 3.0 mile reach of the basin consisting of mini-piezometers, seepage meters, survey elevation base-lines, and utilizing a Marsh-McBirney flow velocity meter. At each station stream discharge, seepage flux rates and hydraulic gradients were determined to develop trends of stream behavior. This methodology had the benefit of demonstrating the efficacy of an intrinsically low-expense, minimally intrusive initial approach to characterizing interactions between surface and ground water resources. The data was correlated with town pumping information, previous geologic surveys and meteorological data. Early data analysis indicated that the stream behaved in an anomalous manner decreasing in discharge with downstream flow despite normal precipitation inputs. The behavior within this particular watershed appeared to be influenced by four primary factors resulting in the stream "running dry" during the June-August period. These factors included: (1) A losing gradient induced by well pumping (2) Obstructions to stream flow reduced contribution from upper reaches to lower reaches (3) A highly anisotropic layer of lower conductivity material regulated infiltration rates and (4) Evapotranspiration effects are such that during this period the basin is in a deficit situation even without additional losses. Additionally, relationships between well pumping and decreasing discharge, seepage flux loss rates and hydraulic gradients have demonstrated that even within humid region watersheds it cannot be assumed aquifer recharge is sufficient to avoid conflict between surface water protection and ground water utilization. Timing of precipitation events combined with geological governance of aquifer recharge play critical roles in managing the conjunctive use of water resources and cannot be assumed to have a negligible effect, even within relatively humid regions.

Soil gas anomalies along the Watukosek fault system, East Java, Indonesia

NASA Astrophysics Data System (ADS)

Sciarra, A.; Ruggiero, L.; Bigi, S.; Mazzini, A.

2017-12-01

Two soil gas surveys were carried out in the Sidoarjo district (East Java, Indonesia) to investigate the gas leaking properties along fractured zones that coincide with a strike-slip system in NE Java, the Watukosek Fault System. This structure has been the focus of attention since the beginning of the spectacular Lusi mud eruption on the 29th May 2006. This fault system appear to be a sinistral strike-slip system that originates from the Arjuno-Welirang volcanic complex, intersects the active Lusi eruption site displaying a system of antithetic faults, and extends towards the NE of Java where mud volcanic structures reside. In the Lusi region we completed two geochemical surveys (222Rn and 220Rn activity, CO2 and CH4 flux and concentration) along four profiles crossing the Watukosek fault system. In May 2015 two profiles ( 1.2 km long) were performed inside the 7 km2 embankment area framing the erupted mud breccia zone and across regions characterized by intense fracturing and surface deformation. In April 2017 two additional profiles ( 4 km long) were carried out in the northern and southern part outside the Lusi embankment mud eruption area, intersecting the direction of main Watukosek fault system. All the profiles highlight that the fractured zones have the highest 222Rn activity, CO2 and CH4 flux and concentration values. The relationship existing among the measured parameters suggest that the Watukosek fault system acts as a preferential pathway for active rise of deep fluids. In addition the longer profiles outside the embankment show very high average values of CO2 (5 - 8 %,v/v) and 222Rn (17 - 11.5 kBq/m3), while soil gas collected along the profiles inside the Lusi mud eruption are CH4-dominant (up to 4.5%,v/v).This suggests that inside the embankment area (i.e. covered by tens of meters thick deposits of erupted mud breccia) the seepage is overall methane-dominated. This is likely the result of microbial reactions ongoing in the organic-rich sediments producing shallow gas that gets mixed with deeper rising fluids. In contrasts profiles collected in areas not covered by the organic rich mud breccia, and that are crossing the main Watukosek fault system, have the highest 222Rn activity and CO2 concentration values. We suggest that at these localities the rise of deep fluids is not affected by shallower gas production.

Comparative human health risk analysis of coastal community water and waste service options.

PubMed

Schoen, Mary E; Xue, Xiaobo; Hawkins, Troy R; Ashbolt, Nicholas J

2014-08-19

As a pilot approach to describe adverse human health effects from alternative decentralized community water systems compared to conventional centralized services (business-as-usual [BAU]), selected chemical and microbial hazards were assessed using disability adjusted life years (DALYs) as the common metric. The alternatives included: (1) composting toilets with septic system, (2) urine-diverting toilets with septic system, (3) low flush toilets with blackwater pressure sewer and on-site greywater collection and treatment for nonpotable reuse, and (4) alternative 3 with on-site rainwater treatment and use. Various pathogens (viral, bacterial, and protozoan) and chemicals (disinfection byproducts [DBPs]) were used as reference hazards. The exposure pathways for BAU included accidental ingestion of contaminated recreational water, ingestion of cross-connected sewage to drinking water, and shower exposures to DBPs. The alternative systems included ingestion of treated greywater from garden irrigation, toilet flushing, and crop consumption; and ingestion of treated rainwater while showering. The pathways with the highest health impact included the ingestion of cross-connected drinking water and ingestion of recreational water contaminated by septic seepage. These were also among the most uncertain when characterizing input parameters, particularly the scale of the cross-connection event, and the removal of pathogens during groundwater transport of septic seepage. A comparison of the health burdens indicated potential health benefits by switching from BAU to decentralized water and wastewater systems.

Relative Abundances of Calcite and Silica in Fracture Coatings as a Possible Indicator of Evaporation in a Thick Unsaturated Zone, Yucca Mountain, Nevada

NASA Astrophysics Data System (ADS)

Marshall, B. D.; Moscati, R. J.

2005-12-01

Yucca Mountain, a ridge of shallowly dipping, Miocene-age volcanic rocks in southwest Nevada, is the proposed site for a nuclear waste repository to be constructed in the 500- to 700-m-thick unsaturated zone (UZ). At the proposed repository, the 300-m-thick Topopah Spring Tuff welded unit (TSw) is overlain by approximately 30 m of nonwelded tuffs (PTn); the Tiva Canyon Tuff welded unit (TCw) overlies the PTn with a range in thickness from 0 to approximately 130 m at the site. The amount of water percolation through the UZ is low and difficult to measure directly, but local seepage into mined tunnels has been observed in the TCw. Past water seepage in the welded tuffs is recorded by widespread, thin (0.3 cm) coatings of calcite and silica on fracture surfaces and within cavities. Abundances of calcite and silica in the coatings were determined by X-ray microfluorescence mapping and subsequent multispectral image analysis of over 200 samples. The images were classified into constituent phases including opal-chalcedony-quartz (secondary silica) and calcite. In the TCw samples, the median calcite/silica ratio is 8; in the TSw samples within 35 m below the PTn, median calcite/silica falls to 2, perhaps reflecting an increase in soluble silica from the presence of glass in the nonwelded tuffs. In the deeper parts of the TSw, median calcite/silica reaches 100 and many samples contain no detectable secondary silica phase. Evaporation and changing pCO2 control precipitation of calcite from water percolating downward in the UZ, but precipitation of opal requires only evaporation. Calcite/silica ratios, therefore, can constrain the relative importance of evaporation in the UZ. Although calcite/silica values scatter widely within the TSw, reflecting the spatial variability of gas and water flow, average calcite/silica ratios increase with stratigraphic depth, indicating less evaporation at the deeper levels of the UZ. Coupled with the much smaller calcite/silica ratios observed in coatings from the TCw, these data indicate that evaporation decreases with depth in the UZ. Evaporation at the repository horizon and in the overlying units is an important process that reduces the amount of seepage at the repository horizon.

Availability and distribution of low flow in Anahola Stream, Kauaʻi, Hawaiʻi

USGS Publications Warehouse

Cheng, Chui Ling; Wolff, Reuben H.

2012-01-01

Anahola Stream is a perennial stream in northeast Kauaʻi, Hawaiʻi, that supports agricultural, domestic, and cultural uses within its drainage basin. Beginning in the late 19th century, Anahola streamflow was diverted by Makee Sugar Company at altitudes of 840 feet (upper intake) and 280 feet (lower intake) for irrigating sugarcane in the Keālia area. When sugarcane cultivation in the Keālia area ceased in 1988, part of the Makee Sugar Company’s surface-water collection system (Makee diversion system) in the Anahola drainage basin was abandoned. In an effort to better manage available surface-water resources, the State of Hawaiʻi Department of Hawaiian Home Lands is considering using the existing ditches in the Anahola Stream drainage basin to provide irrigation water for Native Hawaiian farmers in the area. To provide information needed for successful management of the surface-water resources, the U.S. Geological Survey investigated the availability and distribution of natural low flow in Anahola Stream and also collected low-flow data in Goldfish Stream, a stream that discharges into Kaneha Reservoir, which served as a major collection point for the Makee diversion system. Biological surveys of Anahola Stream were conducted as part of a study to determine the distribution of native and nonnative aquatic stream fauna. Results of the biological surveys indicated the presence of the following native aquatic species in Anahola Stream: ʻoʻopu ʻakupa (Sandwich Island sleeper) and ʻoʻopu naniha (Tear-drop goby) in the lower stream reaches surveyed; and ʻoʻopu nākea (Pacific river goby), ʻoʻopu nōpili (Stimpson’s goby), and ʻōpae kalaʻole (Mountain shrimp) in the middle and upper stream reaches surveyed. Nonnative aquatic species were found in all of the surveyed stream reaches along Anahola Stream. The availability and distribution of natural low flow were determined using a combination of discharge measurements made from February 2011 to May 2012 at low-flow partial-record and seepage-run stations established at locations of interest along study-area streams. Upstream of the upper intake, the estimated natural (undiverted) median flow in Anahola Stream is 2.7 million gallons per day, and the flow is expected to be greater than or equal to 0.97 million gallons per day 95 percent of the time. About 0.7 mile upstream of the lower intake and downstream from the confluence with Keaʻoʻopu Stream, the estimated natural (undiverted) median flow in Anahola Stream is 6.3 million gallons per day, and the flow is expected to be greater than or equal to 2.7 million gallons per day 95 percent of the time. In Goldfish Stream, about 0.4 mile upstream from the point of discharge into Kaneha Reservoir, the estimated natural median flow is 0.54 million gallons per day, and the flow is expected to be greater than or equal to 0.23 million gallons per day 95 percent of the time. The discharge estimates are representative of low-flow conditions in the study-area streams, and they are applicable to the base period (water years 1961–2011) over which they have been computed. The distribution of natural low flow in Anahola Stream was characterized through data collected during wet- and dry-season seepage runs. Seepage-run results show that Anahola Stream was generally a gaining stream under natural low-flow conditions. During the wet-season seepage run, Anahola Stream at the station located upstream of tributary Kaʻalula Stream had more than five times the flow that was measured upstream from the upper intake. The estimated total gain (including tributary inflow) in the 6.1-mile seepage-run reach was 6.97 million gallons per day; about 42 percent of that gain was groundwater discharge to the main channel of Anahola Stream. During the dry-season seepage run, about 34 percent of the estimated total gain of 3.93 million gallons per day in the same seepage-run reach was groundwater discharge to the main channel of Anahola Stream. A 15-percent seepage loss was estimated in a 0.3-mile reach downstream from the confluence of Anahola and Keaʻoʻopu Streams. The report summarizes scenarios that describe (1) surface-water availability under regulated conditions of Anahola Stream if the upper and lower intakes are restored in the future; and (2) amount of flow available for agricultural use at the upper intake under a variety of potential instream-flow standards that may be established by the State of Hawaiʻi for the protection of instream uses.

Numerical simulation of the free surface and water inflow of a slope, considering the nonlinear flow properties of gravel layers: a case study

NASA Astrophysics Data System (ADS)

Yang, Bin; Yang, Tianhong; Xu, Zenghe; Liu, Honglei; Shi, Wenhao; Yang, Xin

2018-02-01

Groundwater is an important factor of slope stability, and 90% of slope failures are related to the influence of groundwater. In the past, free surface calculations and the prediction of water inflow were based on Darcy's law. However, Darcy's law for steady fluid flow is a special case of non-Darcy flow, and many types of non-Darcy flows occur in practical engineering applications. In this paper, based on the experimental results of laboratory water seepage tests, the seepage state of each soil layer in the open-pit slope of the Yanshan Iron Mine, China, were determined, and the seepage parameters were obtained. The seepage behaviour in the silt layer, fine sand layer, silty clay layer and gravelly clay layer followed the traditional Darcy law, while the gravel layers showed clear nonlinear characteristics. The permeability increases exponentially and the non-Darcy coefficient decreases exponentially with an increase in porosity, and the relation among the permeability, the porosity and the non-Darcy coefficient is investigated. A coupled mathematical model is established for two flow fields, on the basis of Darcy flow in the low-permeability layers and Forchheimer flow in the high-permeability layers. In addition, the effect of the seepage in the slope on the transition from Darcy flow to Forchheimer flow was considered. Then, a numerical simulation was conducted by using finite-element software (FELAC 2.2). The results indicate that the free surface calculated by the Darcy-Forchheimer model is in good agreement with the in situ measurements; however, there is an evident deviation of the simulation results from the measured data when the Darcy model is used. Through a parameter sensitivity analysis of the gravel layers, it can be found that the height of the overflow point and the water inflow calculated by the Darcy-Forchheimer model are consistently less than those of the Darcy model, and the discrepancy between these two models increases as the permeability increases. The necessity of adopting the Darcy-Forchheimer model was explained. The Darcy-Forchheimer model would be applicable in slope engineering applications with highly permeable rock.

Numerical simulation of the free surface and water inflow of a slope, considering the nonlinear flow properties of gravel layers: a case study.

PubMed

Yang, Bin; Yang, Tianhong; Xu, Zenghe; Liu, Honglei; Shi, Wenhao; Yang, Xin

2018-02-01

Groundwater is an important factor of slope stability, and 90% of slope failures are related to the influence of groundwater. In the past, free surface calculations and the prediction of water inflow were based on Darcy's law. However, Darcy's law for steady fluid flow is a special case of non-Darcy flow, and many types of non-Darcy flows occur in practical engineering applications. In this paper, based on the experimental results of laboratory water seepage tests, the seepage state of each soil layer in the open-pit slope of the Yanshan Iron Mine, China, were determined, and the seepage parameters were obtained. The seepage behaviour in the silt layer, fine sand layer, silty clay layer and gravelly clay layer followed the traditional Darcy law, while the gravel layers showed clear nonlinear characteristics. The permeability increases exponentially and the non-Darcy coefficient decreases exponentially with an increase in porosity, and the relation among the permeability, the porosity and the non-Darcy coefficient is investigated. A coupled mathematical model is established for two flow fields, on the basis of Darcy flow in the low-permeability layers and Forchheimer flow in the high-permeability layers. In addition, the effect of the seepage in the slope on the transition from Darcy flow to Forchheimer flow was considered. Then, a numerical simulation was conducted by using finite-element software (FELAC 2.2). The results indicate that the free surface calculated by the Darcy-Forchheimer model is in good agreement with the in situ measurements; however, there is an evident deviation of the simulation results from the measured data when the Darcy model is used. Through a parameter sensitivity analysis of the gravel layers, it can be found that the height of the overflow point and the water inflow calculated by the Darcy-Forchheimer model are consistently less than those of the Darcy model, and the discrepancy between these two models increases as the permeability increases. The necessity of adopting the Darcy-Forchheimer model was explained. The Darcy-Forchheimer model would be applicable in slope engineering applications with highly permeable rock.

Numerical simulation of the free surface and water inflow of a slope, considering the nonlinear flow properties of gravel layers: a case study

PubMed Central

Yang, Bin; Xu, Zenghe; Liu, Honglei; Shi, Wenhao; Yang, Xin

2018-01-01

Groundwater is an important factor of slope stability, and 90% of slope failures are related to the influence of groundwater. In the past, free surface calculations and the prediction of water inflow were based on Darcy's law. However, Darcy's law for steady fluid flow is a special case of non-Darcy flow, and many types of non-Darcy flows occur in practical engineering applications. In this paper, based on the experimental results of laboratory water seepage tests, the seepage state of each soil layer in the open-pit slope of the Yanshan Iron Mine, China, were determined, and the seepage parameters were obtained. The seepage behaviour in the silt layer, fine sand layer, silty clay layer and gravelly clay layer followed the traditional Darcy law, while the gravel layers showed clear nonlinear characteristics. The permeability increases exponentially and the non-Darcy coefficient decreases exponentially with an increase in porosity, and the relation among the permeability, the porosity and the non-Darcy coefficient is investigated. A coupled mathematical model is established for two flow fields, on the basis of Darcy flow in the low-permeability layers and Forchheimer flow in the high-permeability layers. In addition, the effect of the seepage in the slope on the transition from Darcy flow to Forchheimer flow was considered. Then, a numerical simulation was conducted by using finite-element software (FELAC 2.2). The results indicate that the free surface calculated by the Darcy–Forchheimer model is in good agreement with the in situ measurements; however, there is an evident deviation of the simulation results from the measured data when the Darcy model is used. Through a parameter sensitivity analysis of the gravel layers, it can be found that the height of the overflow point and the water inflow calculated by the Darcy–Forchheimer model are consistently less than those of the Darcy model, and the discrepancy between these two models increases as the permeability increases. The necessity of adopting the Darcy–Forchheimer model was explained. The Darcy–Forchheimer model would be applicable in slope engineering applications with highly permeable rock. PMID:29515904

River-aquifer interactions, geologic heterogeneity, and low-flow management

USGS Publications Warehouse

Fleckenstein, J.H.; Niswonger, R.G.; Fogg, G.E.

2006-01-01

Low river flows are commonly controlled by river-aquifer exchange, the magnitude of which is governed by hydraulic properties of both aquifer and aquitard materials beneath the river. Low flows are often important ecologically. Numerical simulations were used to assess how textural heterogeneity of an alluvial system influences river seepage and low flows. The Cosumnes River in California was used as a test case. Declining fall flows in the Cosumnes River have threatened Chinook salmon runs. A ground water-surface water model for the lower river basin was developed, which incorporates detailed geostatistical simulations of aquifer heterogeneity. Six different realizations of heterogeneity and a homogenous model were run for a 3-year period. Net annual seepage from the river was found to be similar among the models. However, spatial distribution of seepage along the channel, water table configuration and the level of local connection, and disconnection between the river and aquifer showed strong variations among the different heterogeneous models. Most importantly, the heterogeneous models suggest that river seepage losses can be reduced by local reconnections, even when the regional water table remains well below the riverbed. The percentage of river channel responsible for 50% of total river seepage ranged from 10% to 26% in the heterogeneous models as opposed to 23% in the homogeneous model. Differences in seepage between the models resulted in up to 13 d difference in the number of days the river was open for salmon migration during the critical fall months in one given year. Copyright ?? 2006 The Author(s).

Fine-Scale Community Structure Analysis of ANME in Nyegga Sediments with High and Low Methane Flux

PubMed Central

Roalkvam, Irene; Dahle, Håkon; Chen, Yifeng; Jørgensen, Steffen Leth; Haflidason, Haflidi; Steen, Ida Helene

2012-01-01

To obtain knowledge on how regional variations in methane seepage rates influence the stratification, abundance, and diversity of anaerobic methanotrophs (ANME), we analyzed the vertical microbial stratification in a gravity core from a methane micro-seeping area at Nyegga by using 454-pyrosequencing of 16S rRNA gene tagged amplicons and quantitative PCR. These data were compared with previously obtained data from the more active G11 pockmark, characterized by higher methane flux. A down core stratification and high relative abundance of ANME were observed in both cores, with transition from an ANME-2a/b dominated community in low-sulfide and low methane horizons to ANME-1 dominance in horizons near the sulfate-methane transition zone. The stratification was over a wider spatial region and at greater depth in the core with lower methane flux, and the total 16S rRNA copy numbers were two orders of magnitude lower than in the sediments at G11 pockmark. A fine-scale view into the ANME communities at each location was achieved through operational taxonomical units (OTU) clustering of ANME-affiliated sequences. The majority of ANME-1 sequences from both sampling sites clustered within one OTU, while ANME-2a/b sequences were represented in unique OTUs. We suggest that free-living ANME-1 is the most abundant taxon in Nyegga cold seeps, and also the main consumer of methane. The observation of specific ANME-2a/b OTUs at each location could reflect that organisms within this clade are adapted to different geochemical settings, perhaps due to differences in methane affinity. Given that the ANME-2a/b population could be sustained in less active seepage areas, this subgroup could be potential seed populations in newly developed methane-enriched environments. PMID:22715336

Influence of groundwater on distribution of dwarf wedgemussels (Alasmidonta heterodon) in the upper reaches of the Delaware River, northeastern USA

USGS Publications Warehouse

Rosenberry, Donald O.; Briggs, Martin A.; Voytek, Emily B.; Lane, John W.

2016-01-01

The remaining populations of the endangered dwarf wedgemussel (DWM) (Alasmidonta heterodon) in the upper Delaware River, northeastern USA, were hypothesized to be located in areas of greater-than-normal groundwater discharge to the river. We combined physical (seepage meters, monitoring wells and piezometers), thermal (fiber-optic distributed temperature sensing, infrared, vertical bed-temperature profiling), and geophysical (electromagnetic-induction) methods at several spatial scales to characterize known DWM habitat and explore this hypothesis. Numerous springs were observed using visible and infrared imaging along the river banks at all three known DWM-populated areas, but not in adjacent areas where DWM were absent. Vertical and lateral groundwater gradients were toward the river along all three DWM-populated reaches, with median upward gradients 3 to 9 times larger than in adjacent reaches. Point-scale seepage-meter measurements indicated that upward seepage across the riverbed was faster and more consistently upward at DWM-populated areas. Discrete and areally distributed riverbed-temperature measurements indicated numerous cold areas of groundwater discharge during warm summer months; all were within areas populated by DWM. Electromagnetic-induction measurements, which may indicate riverbed geology, showed patterning but little correlation between bulk streambed electromagnetic conductivity and areal distribution of DWM. In spite of complexity introduced by hyporheic exchange, multiple lines of research provide strong evidence that DWM are located within or directly downstream of areas of substantial focused groundwater discharge to the river. Broad scale thermal-reconnaissance methods (e.g., infrared) may be useful in locating and protecting other currently unknown mussel populations.

A method for estimating spatially variable seepage and hydrualic conductivity in channels with very mild slopes

USGS Publications Warehouse

Shanafield, Margaret; Niswonger, Richard G.; Prudic, David E.; Pohll, Greg; Susfalk, Richard; Panday, Sorab

2014-01-01

Infiltration along ephemeral channels plays an important role in groundwater recharge in arid regions. A model is presented for estimating spatial variability of seepage due to streambed heterogeneity along channels based on measurements of streamflow-front velocities in initially dry channels. The diffusion-wave approximation to the Saint-Venant equations, coupled with Philip's equation for infiltration, is connected to the groundwater model MODFLOW and is calibrated by adjusting the saturated hydraulic conductivity of the channel bed. The model is applied to portions of two large water delivery canals, which serve as proxies for natural ephemeral streams. Estimated seepage rates compare well with previously published values. Possible sources of error stem from uncertainty in Manning's roughness coefficients, soil hydraulic properties and channel geometry. Model performance would be most improved through more frequent longitudinal estimates of channel geometry and thalweg elevation, and with measurements of stream stage over time to constrain wave timing and shape. This model is a potentially valuable tool for estimating spatial variability in longitudinal seepage along intermittent and ephemeral channels over a wide range of bed slopes and the influence of seepage rates on groundwater levels.

Steady flow rate to a partially penetrating well with seepage face in an unconfined aquifer

NASA Astrophysics Data System (ADS)

Behrooz-Koohenjani, Siavash; Samani, Nozar; Kompani-Zare, Mazda

2011-06-01

The flow rate to fully screened, partially penetrating wells in an unconfined aquifer is numerically simulated using MODFLOW 2000, taking into account the flow from the seepage face and decrease in saturated thickness of the aquifer towards the well. A simple three-step method is developed to find the top of the seepage face and hence the seepage-face length. The method is verified by comparing it with the results of previous predictive methods. The results show that the component of flow through the seepage face can supply a major portion of the total pumping rate. Variations in flow rate as a function of the penetration degree, elevation of the water level in the well and the distance to the far constant head boundary are investigated and expressed in terms of dimensionless curves and equations. These curves and equations can be used to design the degree of penetration for which the allowable steady pumping rate is attained for a given elevation of water level in the well. The designed degree of penetration or flow rate will assure the sustainability of the aquifer storage, and can be used as a management criterion for issuing drilling well permits by groundwater protection authorities.

Riverbed clogging associated with a California riverbank filtration system: An assessment of mechanisms and monitoring approaches

USGS Publications Warehouse

Ulrich, Craig; Hubbard, Susan S.; Florsheim, Joan; Rosenberry, Donald O.; Borglin, Sharon; Trotta, Marcus; Seymour, Donald

2015-01-01

An experimental field study was performed to investigate riverbed clogging processes and associated monitoring approaches near a dam-controlled riverbank filtration facility in Northern California. Motivated by previous studies at the site that indicated riverbed clogging plays an important role in the performance of the riverbank filtration system, we investigated the spatiotemporal variability and nature of the clogging. In particular, we investigated whether the clogging was due to abiotic or biotic mechanisms. A secondary aspect of the study was the testing of different methods to monitor riverbed clogging and related processes, such as seepage. Monitoring was conducted using both point-based approaches and spatially extensive geophysical approaches, including: grain-size analysis, temperature sensing, electrical resistivity tomography, seepage meters, microbial analysis, and cryocoring, along two transects. The point monitoring measurements suggested a substantial increase in riverbed biomass (2 orders of magnitude) after the dam was raised compared to the small increase (∼2%) in fine-grained sediment. These changes were concomitant with decreased seepage. The decreased seepage eventually led to the development of an unsaturated zone beneath the riverbed, which further decreased infiltration capacity. Comparison of our time-lapse grain-size and biomass datasets suggested that biotic processes played a greater role in clogging than did abiotic processes. Cryocoring and autonomous temperature loggers were most useful for locally monitoring clogging agents, while electrical resistivity data were useful for interpreting the spatial extent of a pumping-induced unsaturated zone that developed beneath the riverbed after riverbed clogging was initiated. The improved understanding of spatiotemporally variable riverbed clogging and monitoring approaches is expected to be useful for optimizing the riverbank filtration system operations.

Geochemical record of methane seepage in authigenic carbonates and surrounding host sediments: A case study from the South China Sea

NASA Astrophysics Data System (ADS)

Hu, Yu; Chen, Linying; Feng, Dong; Liang, Qianyong; Xia, Zhen; Chen, Duofu

2017-05-01

Sediments at marine methane seep sites provide potential archives of past fluid flow that serve to explore seepage activities over time. Three gravity cores (D-8, D-F, and D-7) were collected from seep sites on the northern slope of the South China Sea where gas hydrates were drilled in the subsurface. Various carbon and sulfur contents, δ13C values of total inorganic carbon (δ13CTIC), δ34S values of chromium reducible sulfur (δ34SCRS), trace element contents, grain size, and AMS 14C dating of planktonic Foraminifera in the sediments were determined to explore the availability of related proxies at seeps and to trace past methane seepage activities. Evidence for the presence of methane seepage and consequently anaerobic oxidation of methane comes from the occurrence of 13C-depleted authigenic carbonate nodules (δ13C values as low as -49‰) discovered at an interval of 150-200 cm in core D-7. This finding is supported by high S/C ratios and molybdenum enrichment in the same interval. However, low contents of CRS and negative δ34SCRS values are present. It is suggested to reflect a transient methane seepage event, which continued for about 1 ka based on the 14C ages. Cores D-8 and D-F have δ13CTIC values close to zero, low S/C ratios and CRS contents, negative δ34SCRS values, and no trace element enrichment, suggesting a negligible impact of methane-seepage on the sediments. The negative δ34SCRS values of the studied seep-impacted and background sediments suggest that the application of δ34SCRS alone as a proxy to identify AOM-related process may be insufficient. Sediment carbon-sulfur-trace element systematics and 14C ages used here have the potential to be a promising tool to recognize transient methane seepages and constrain their timescales.

Water quality effects of seepage from earthen dams

USGS Publications Warehouse

Yost, C.; Naney, J.W.

1974-01-01

Analyses of surface and seepage waters from selected floodwater retarding structures in west-central Oklahoma, U.S.A. show the salinity of seepage to be several times greater than that of the impounded waters. The increases in concentration of the several chemical components are not proportional. This phenomenon appears to be caused largely by simple solution, which is closely related to the chemical character of the geologic formation that provides the reservoir site and the earth fill of the dam. Concentration of certain chemical components in the seepage water progressively decreases as the structure ages. This is probably a function of depletion, which is related to the amounts and solubility of the parent materials subjected to solution. In contrast, the concentration of certain other components, such as iron and calcium, increases with time. The chemical activities within the accumulating mud on the bottom of the reservoir apparently cause these increases. ?? 1974.

Comparative treatment effectiveness of conventional trench and seepage pit systems.

PubMed

Field, J P; Farrell-Poe, K L; Walworth, J L

2007-03-01

On-site wastewater treatment systems can be a potential source of groundwater contamination in regions throughout the United States and other parts of the world. Here, we evaluate four conventional trench systems and four seepage pit systems to determine the relative effectiveness of these systems for the treatment of septic tank effluent in medium- to coarse-textured arid and semiarid soils. Soil borings were advanced up to twice the depth of the trenches (4 m) and seepage pits (15 m) at two horizontal distances (30 cm and 1.5 m) from the sidewalls of the systems. Soil samples were analyzed for various biological and chemical parameters, including Escherichia coli, total coliform, pH, total organic carbon, total dissolved solids, total nitrogen, ammonium-nitrogen, and nitrate-nitrogen. Most soil parameters investigated approached background levels more rapidly near the trenches than the seepage pits, as sampling distance increased both vertically and horizontally from the sidewalls of the systems.

Groundwater quality assessment/corrective action feasibility plan: New TNX Seepage Basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nichols, R.L.

1989-12-05

The New TNX Seepage Basin is located across River Road east of the TNX Area at the Savannah River Site. Currently the basin is out of service and is awaiting closure in accordance with the Consent Decree settled under Civil Act No. 1:85-2583. Groundwater monitoring data from the detection monitoring network around the New TNX Seepage Basin was recently analyzed using South Carolina Hazardous Waste Management Regulations R.61-79.264.92 methods to determine if groundwater downgradient of the New TNX Seepage Basin had been impacted. Results from the data analysis indicate that the groundwater has been impacted by inorganic constituents with nomore » associated health risks. The impacts resulting from elevated levels of inorganic constituents, such as Mn, Na, and Total PO{sub 4} in the water table, do not pose a threat to human health and the environment.« less

Formation of Box Canyon, Idaho, by megaflood: implications for seepage erosion on Earth and Mars.

PubMed

Lamb, Michael P; Dietrich, William E; Aciego, Sarah M; Depaolo, Donald J; Manga, Michael

2008-05-23

Amphitheater-headed canyons have been used as diagnostic indicators of erosion by groundwater seepage, which has important implications for landscape evolution on Earth and astrobiology on Mars. Of perhaps any canyon studied, Box Canyon, Idaho, most strongly meets the proposed morphologic criteria for groundwater sapping because it is incised into a basaltic plain with no drainage network upstream, and approximately 10 cubic meters per second of seepage emanates from its vertical headwall. However, sediment transport constraints, 4He and 14C dates, plunge pools, and scoured rock indicate that a megaflood (greater than 220 cubic meters per second) carved the canyon about 45,000 years ago. These results add to a growing recognition of Quaternary catastrophic flooding in the American northwest, and may imply that similar features on Mars also formed by floods rather than seepage erosion.

Variations in Gas and Water Pulses at an Arctic Seep: Fluid Sources and Methane Transport

NASA Astrophysics Data System (ADS)

Hong, W.-L.; Torres, M. E.; Portnov, A.; Waage, M.; Haley, B.; Lepland, A.

2018-05-01

Methane fluxes into the oceans are largely dependent on the methane phase as it migrates upward through the sediments. Here we document decoupled methane transport by gaseous and aqueous phases in Storfjordrenna (offshore Svalbard) and propose a three-stage evolution model for active seepage in the region where gas hydrates are present in the shallow subsurface. In a preactive seepage stage, solute diffusion is the primary transport mechanism for methane in the dissolved phase. Fluids containing dissolved methane have high 87Sr/86Sr ratios due to silicate weathering in the microbial methanogenesis zone. During the active seepage stage, migration of gaseous methane results in near-seafloor gas hydrate formation and vigorous seafloor gas discharge with a thermogenic fingerprint. In the postactive seepage stage, the high concentration of dissolved lithium points to the contribution of a deeper-sourced aqueous fluid, which we postulate advects upward following cessation of gas discharge.

Final Scientific/Technical Report: Characterizing the Response of the Cascadia Margin Gas Hydrate Reservoir to Bottom Water Warming Along the Upper Continental Slope

DOE Office of Scientific and Technical Information (OSTI.GOV)

Solomon, Evan A.; Johnson, H. Paul; Salmi, Marie

The objective of this project is to understand the response of the WA margin gas hydrate system to contemporary warming of bottom water along the upper continental slope. Through pre-cruise analysis and modeling of archive and recent geophysical and oceanographic data, we (1) inventoried bottom simulating reflectors along the WA margin and defined the upper limit of gas hydrate stability, (2) refined margin-wide estimates of heat flow and geothermal gradients, (3) characterized decadal scale temporal variations of bottom water temperatures at the upper continental slope of the Washington margin, and (4) used numerical simulations to provide quantitative estimates of howmore » the shallow boundary of methane hydrate stability responds to modern environmental change. These pre-cruise results provided the context for a systematic geophysical and geochemical survey of methane seepage along the upper continental slope from 48° to 46°N during a 10-day field program on the R/V Thompson from October 10-19, 2014. This systematic inventory of methane emissions along this climate-sensitive margin corridor and comprehensive sediment and water column sampling program provided data and samples for Phase 3 of this project that focused on determining fluid and methane sources (deep-source vs. shallow; microbial, thermogenic, gas hydrate dissociation) within the sediment, and how they relate to contemporary intermediate water warming. During the 2014 research expedition, we sampled nine seep sites between ~470 and 520 m water depth, within the zone of predicted methane hydrate retreat over the past 40 years. We imaged 22 bubble plumes with heights commonly rising to ~300 meters below sea level with one reaching near the sea surface. We collected 22 gravity cores and 20 CTD/hydrocasts from the 9 seeps and at background locations (no acoustic evidence of seepage) within the depth interval of predicted downslope retreat of the methane hydrate stability zone. Approximately 300 pore water samples were extracted from the gravity cores, and the pore water was analyzed for a comprehensive suite of solutes, gases, and stable isotope ratios. This comprehensive geochemical dataset was used to characterize the fluid and gas source(s) at each of the seep sites surveyed. The primary results of this project are: 1) Bottom simulating reflector-derived heat flow values decrease from 95 mW/m2 10 km east of the deformation front to ~60 mW/m2 60 km landward of the deformation front, with anomalously low values of ~25 mW/m2 on a prominent mid-margin terrace off central Washington. 2) The temperature of the incoming sediment/ocean crust interface at the deformation front ranges between 164-179 oC off central Washington, and the 350 oC isotherm at the top of the subducting ocean crust occurs 95 km landward of the deformation front. Differences between BSR-derived heat flow and modeled conductive heat flow suggest mean upward fluid flow rates of 0.4 cm/yr across the margin, with local regions (e.g. fault zones) exhibiting fluid flow rates up to 3.5 cm/yr. 3) A compilation of 2122 high-resolution CTD, glider, and Argo float temperature profiles spanning the upper continental slope of the Washington margin from the years 1968 to 2013 show a long-term warming trend that ranges from 0.006-0.008 oC/yr. Based on this long-term bottom water warming, we developed a 2-D thermal model to simulate the change in sediment temperature distribution over this period, along with the downslope retreat of the methane hydrate stability field. Over the 43 years of the simulation, the thermal disturbance propagated 30 m into the sediment column, causing the base of the methane hydrate stability field to shoal ~13 m and to move ~1 km downslope. 4) A preliminary analysis of seafloor observations and mid-water column acoustic data to detect bubble plumes was used to characterize the depth distribution of seeps along the Cascadia margin. These results indicate high bubble plume densities along the continental shelf at water depths <180 m and at the upper limit of methane hydrate stability along the Washington margin. 5) The majority of the seeps cored during the 2014 research expedition on the R/V Thompson contained abundant authigenic carbonate indicating that they are locations of long-lived seepage rather than emergent seep systems related to methane hydrate dissociation. Despite the evidence for enhanced methane seepage at the upper limit of methane hydrate stability along the Washington margin, we found no unequivocal evidence for active methane hydrate dissociation as a source of fluid and gas at the seeps surveyed. The pore fluid and bottom water chemistry shows that the seeps are fed by a variety of fluid and methane sources, but that methane hydrate dissociation, if occurring, is not widespread and is only a minor source (below the detection limit of our methods). Collectively, these results provide a significant advance in our understanding of the thermal structure of the Cascadia subduction zone and the fluid and methane sources feeding seeps along the upper continental slope of the Washington-sector of the Cascadia margin. Though we did not find unequivocal evidence for methane hydrate dissociation as a source of water and methane at the upper pressure-temperature limit of methane hydrate stability at present, continued warming of North Pacific Intermediate Water in the future has the potential to impact the methane hydrate reservoir in sediments at greater depths along the slope. Thus, this study provides a strong foundation and the necessary characterization of the background state of seepage at the upper limit of methane hydrate stability for future investigations of this important process.« less

Detection of zone of seepage beneath earthfill dam

DOT National Transportation Integrated Search

2008-02-01

MST proposes to acquire resistivity and self-potential data at the Lake Sherwood earth fill dam site. These geophysical data will be processed, analyzed and interpreted with the objective of locating and mapping seepage pathways that might compromise...

Gas migration through Opouawe Bank at the Hikurangi margin offshore New Zealand

NASA Astrophysics Data System (ADS)

Koch, Stephanie; Schroeder, Henning; Haeckel, Matthias; Berndt, Christian; Bialas, Joerg; Papenberg, Cord; Klaeschen, Dirk; Plaza-Faverola, Andreia

2016-06-01

This study presents 2D seismic reflection data, seismic velocity analysis, as well as geochemical and isotopic porewater compositions from Opouawe Bank on New Zealand's Hikurangi subduction margin, providing evidence for essentially pure methane gas seepage. The combination of geochemical information and seismic reflection images is an effective way to investigate the nature of gas migration beneath the seafloor, and to distinguish between water advection and gas ascent. The maximum source depth of the methane that migrates to the seep sites on Opouawe Bank is 1,500-2,100 m below seafloor, generated by low-temperature degradation of organic matter via microbial CO2 reduction. Seismic velocity analysis enabled identifying a zone of gas accumulation underneath the base of gas hydrate stability (BGHS) below the bank. Besides structurally controlled gas migration along conduits, gas migration also takes place along dipping strata across the BGHS. Gas migration on Opouawe Bank is influenced by anticlinal focusing and by several focusing levels within the gas hydrate stability zone.

Evaluation of seepage from Chester Morse Lake and Masonry Pool, King County, Washington

USGS Publications Warehouse

Hidaka, F.T.; Garrett, Arthur Angus

1967-01-01

Hydrologic data collected in the Cedar and Snoqualmie River basins on the west slope of the Cascade Range have been analyzed to determine the amount of water lost by seepage from Chester Morse Lake and Masonry Pool and the. consequent gain by seepage to the Cedar and South Fork Snoqualmie Rivers. For water years 1957-64, average losses were about 220 cfs (cubic feet per second) while average gains were about 180 cfs in the Cedar River and 50 cfs in the South Fork Snoqualmie River. Streamflow and precipitation data for water years 1908-26 and 1930-F2 indicate that a change in runoff regimen occurred in Cedar and South Fork Snoqualmie Rivers after the Boxley Creek washout in December 1918. For water years 1919-26 and 1930-32, the flow of Cedar River near Landsburg averaged about 80 cfs less than it would have if the washout had not occurred. In contrast, the flow of South Fork Snoqualmie River at North Bend averaged about 60 cfs more than it would have.

Initial characterization of the groundwater system near the Lower Colorado Water Supply Project, Imperial Valley, California

USGS Publications Warehouse

Coes, Alissa L.; Land, Michael; Densmore, Jill N.; Landrum, Michael T.; Beisner, Kimberly R.; Kennedy, Jeffrey R.; Macy, Jamie P.; Tillman, Fred D.

2015-01-01

During and after lining the All-American Canal (2007–11), groundwater elevations in the Lower Colorado Water Supply Project area declined, while total dissolved solids concentrations remained relatively constant. The total dissolved solids concentrations in well LCWSP-2 ranged from 650 to 800 milligrams per liter during this study. Depth-specific water-quality and isotope sampling at well LCWSP-2 indicated the groundwater pumped from the deeper part of the screened interval (240–280 feet below land surface) contained a greater proportion of historical groundwater than the groundwater pumped from the shallower part of the screened interval (350–385 feet below land surface). Age-tracer data at well LCWSP-2 indicated that all depths of the screened interval had received recent recharge from seepage of Colorado River water from the All-American Canal.

Best Technical Approach Analysis (BTA) for Force Provider Wastewater Management

DTIC Science & Technology

1994-07-07

Sanitation methods involving burnout latrines and seepage pits are no longer permitted in many areas. Further, those methods are generally only applicable...and profit. * 4-3 I 4-jcrz E CO 3 I* 0U 0 c0 QQ 0 1%CDt 0 sJ19100IUMSOO 6AAlo soll~v4 l ss oUOIS~a M*. I I COLLECT PACKAGED FIELD OXIDATION AND PLANT...DISTRIBUTION: BQDA, ATTN: DALO-TST/D O-FD/DAMO-FDD/DAMO-FDL/DALO-PLZ/ DAMA-PPM/DALO-SMS/DýMO- C/DAPE- MBI CINC, USAREUR and Seventh y, ATTN: AEAGX-SA/AEAGC

Geotechnical Applications of the Self-Potential Method. Report 3. Development of Self-Potential Interpretation Techniques for Seepage Detection

DTIC Science & Technology

1989-02-01

potentials M Modeling or interpretation of SP data T Streaming potential theory TM Telluric current measurement 0 Other 57 REFERENCES Abaza, M. M. I ...470-483. L, T Abaza, M. M. I . 1966. Streaming Current and Streaming Potential Induced by Water Flow Through Porous Media: Ph.D. Thesis, Utah State...IO-- L* - CDU -c) low- -co M~ <__ _ _ i7L - 7 ____~~~~ < K- I ~ 1I1iiij § r~L K mn LKzz{ - i ----_ - t -C 71L- C > 0amp- Daily_ _ Recrd fo Ce uft an

The effect of elevated CO2 and temperature on nutrient uptake by plants grown in basaltic soil

NASA Astrophysics Data System (ADS)

Villasenor Iribe, E.; Dontsova, K.; Juarez, S.; Le Galliard, J. F.; Chollet, S.; Llavata, M.; Massol, F.; Barré, P.; Gelabert, A.; Daval, D.; Troch, P.; Barron-Gafford, G.; Van Haren, J. L. M.; Ferrière, R.

2017-12-01

Mineral weathering is an important process in soil formation. The interactions between the hydrologic, geologic and atmospheric cycles often determine the rate at which weathering occurs. Elements and nutrients weathered from the soil by water can be removed from soils in the runoff and seepage, but they can also remain in situ as newly precipitated secondary minerals or in biomass as a result of plant uptake. Here we present data from an experiment that was conducted at the controlled environment facility, Ecotron Ile-de-France (Saint-Pierre-les-Nemours, France) that studied mineral weathering and plant growth in granular basaltic material with high glass content that is being used to simulate soil in large scale Biosphere 2 Landscape Evolution Observatory (LEO) project. The experiment used 3 plant types: velvet mesquite (Prosopis velutina), green spangletop (Leptochloa dubia), and alfalfa (Medicago sativa), which were grown under varying temperature and CO2 conditions. We hypothesized that plants grown under warmer, higher CO2 conditions would have larger nutrient concentrations as more mineral weathering would occur. Results of plant digestions and analysis showed that plant concentrations of lithogenic elements were significantly influenced by the plant type and were different between above- and below-ground parts of the plant. Temperature and CO2 treatment effects were less pronounced, but we observed significant temperature effect on plant uptake. A number of major and trace elements showed increase in concentration with increase in temperature at elevated atmospheric CO2. Effect was observed both in the shoots and in the roots, but more significant differences were observed in the shoots. Results presented here indicate that climate change would have strong effect on plant uptake and mobility of weathered elements during soil formation and give further evidence of interactions between abiotic and biological processes in terrestrial ecosystems.

[Study on the stability of tetrandrine microsphere].

PubMed

Cheng, Guohu; Luo, Jiabo

2005-05-01

To study the stability of Tetrandrine Microsphere. Higher speed test and room temperature test were adopted to investigate the indexes, such as properties of appearance, amount of medicine loaded, seal rate, seepage rate, microbial stability, etc. Through the test of six months, properties of appearance, amount of medicine loaded, seal rate, seepage rate, microbial stability have not obviously change. But after testing for 6 months with higher temperature, the seal rate was reduced, and the seepage rate was increased. Tetrandrine microsphere is steady under the room temperature condition, but is unstable to hot, and ought to keep in conformity with low-temperature.

Synthesis, characterization and investigation of electrochemical and spectroelectrochemical properties of peripherally tetra 4-phenylthiazole-2-thiol substituted metal-free, zinc(II), copper(II) and cobalt(II) phthalocyanines

NASA Astrophysics Data System (ADS)

Demirbaş, Ümit; Akçay, Hakkı Türker; Koca, Atıf; Kantekin, Halit

2017-08-01

In this study novel peripherally tetra 4-phenylthiazole-2-thiol substituted metal-free phthalocyanine (4) and its zinc(II) (5), copper(II) (6) and cobalt(II) (7) derivatives were synthesized and characterized by a combination of various spectroscopic techniques such as FT-IR, 1H-NMR, UV-vis and MALDI-TOF mass. Electrochemical characterizations of metallo-phthalocyanine complexes were conducted by voltammetric and in situ spectroelectrochemical measurements. CoIIPc went [CoIIPc-2]/[CoIPc-2]1-, [CoIPc-2]1-/[CoIPc-3]2-, [CoIPc-3]2-/[CoIPc-4]3- and [CoIIPc-2]/[CoIIPc-2]1+ reduction and oxidation processes respectively. Differently ZnIIPc only showed four ligand-based reductions and two ligand based oxidation processes.

Evidence for natural molecular hydrogen seepage associated with Carolina bays (surficial, ovoid depressions on the Atlantic Coastal Plain, Province of the USA)

NASA Astrophysics Data System (ADS)

Zgonnik, Viacheslav; Beaumont, Valérie; Deville, Eric; Larin, Nikolay; Pillot, Daniel; Farrell, Kathleen M.

2015-12-01

A study of soil gases was made in North Carolina (USA) in and around morphological depressions called "Carolina bays." This type of depression is observed over the Atlantic coastal plains of the USA, but their origin remains debated. Significant concentrations of molecular hydrogen (H2) were detected, notably around the bays. These measurements suggest that Carolina bays are the surficial expression of fluid flow pathways for hydrogen gas moving from depth to the surface. The potential mechanisms of H2 production and transport and the geological controls on the fluid migration pathways are discussed, with reference to the hypothesis that Carolina bays are the result of local collapses caused by the alteration of rock along the deep pathways of H2 migrating towards the surface. The present H2 seepages are comparable to those in similar structures previously observed in the East European craton.

Eddy Covariance Method for CO2 Emission Measurements: CCS Applications, Principles, Instrumentation and Software

NASA Astrophysics Data System (ADS)

Burba, George; Madsen, Rod; Feese, Kristin

2013-04-01

The Eddy Covariance method is a micrometeorological technique for direct high-speed measurements of the transport of gases, heat, and momentum between the earth's surface and the atmosphere. Gas fluxes, emission and exchange rates are carefully characterized from single-point in-situ measurements using permanent or mobile towers, or moving platforms such as automobiles, helicopters, airplanes, etc. Since the early 1990s, this technique has been widely used by micrometeorologists across the globe for quantifying CO2 emission rates from various natural, urban and agricultural ecosystems [1,2], including areas of agricultural carbon sequestration. Presently, over 600 eddy covariance stations are in operation in over 120 countries. In the last 3-5 years, advancements in instrumentation and software have reached the point when they can be effectively used outside the area of micrometeorology, and can prove valuable for geological carbon capture and sequestration, landfill emission measurements, high-precision agriculture and other non-micrometeorological industrial and regulatory applications. In the field of geological carbon capture and sequestration, the magnitude of CO2 seepage fluxes depends on a variety of factors. Emerging projects utilize eddy covariance measurement to monitor large areas where CO2 may escape from the subsurface, to detect and quantify CO2 leakage, and to assure the efficiency of CO2 geological storage [3,4,5,6,7,8]. Although Eddy Covariance is one of the most direct and defensible ways to measure and calculate turbulent fluxes, the method is mathematically complex, and requires careful setup, execution and data processing tailor-fit to a specific site and a project. With this in mind, step-by-step instructions were created to introduce a novice to the conventional Eddy Covariance technique [9], and to assist in further understanding the method through more advanced references such as graduate-level textbooks, flux networks guidelines, journals and technical papers. A free open-source software package with a user-friendly interface was developed accordingly for computing final fully corrected CO2 emission numbers [10]. The presentation covers highlights of the eddy covariance method, its application to geological carbon sequestration, key requirements, instrumentation and software, and reviews educational resources particularly useful for carbon sequestration research. References: [1] Aubinet, M., T. Vesala, and D. Papale (Eds.), 2012. Eddy Covariance: A Practical Guide to Measurement and Data Analysis. Springer-Verlag, 442 pp. [2] Foken T., 2008. Micrometeorology. Springer-Verlag, 308 pp. [4] Finley, R., 2009. An Assessment of Geological Carbon Sequestration in the Illinois Basin Overview of the Decatur-Illinois Basin Site. MGSC, http://www.istc.illinois.edu/info/govs_awards_docs/2009-GSA-1100-Finley.pdf [5] Liu, G. (Ed.), 2012. Greenhouse Gases: Capturing, Utilization and Reduction. Intech, 338 pp. [6] LI-COR Biosciences, 2011. Surface Monitoring for Geologic Carbon Sequestration Monitoring: Methods, Instrumentation, and Case Studies. LI-COR Biosciences, Pub. 980-11916, 15 pp. [7] Benson, S., 2006. Monitoring carbon dioxide sequestration in deep geological formations for inventory verification and carbon credits, SPE-102833, Presentation [8] Lewicki, J., G. Hilley, M. Fischer, L. Pan, C. Olden-burg, C. Dobeck, and L. Spangler, 2009.Eddy covariance observations of leakage during shallow subsurface CO2 releases. Journal of Geophys Res, 114: D12302 [9] Burba, G., 2013. Eddy Covariance Method for Scientific, Industrial, Agricultural and Regulatory Applications. LI-COR Biosciences, 328 pp. [10] LI-COR Biosciences, 2012. EddyPro 4.0: Help and User's Guide. Lincoln, NE, 208 pp.

Using air/water/sediment temperature contrasts to identify groundwater seepage locations in small streams

NASA Astrophysics Data System (ADS)

Karan, S.; Sebok, E.; Engesgaard, P. K.

2016-12-01

For identifying groundwater seepage locations in small streams within a headwater catchment, we present a method expanding on the linear regression of air and stream temperatures. Thus, by measuring the temperatures in dual-depth; in the stream column and at the streambed-water interface (SWI), we apply metrics from linear regression analysis of temperatures between air/stream and air/SWI (linear regression slope, intercept and coefficient of determination), and the daily mean temperatures (temperature variance and the average difference between the minimum and maximum daily temperatures). Our study show that using metrics from single-depth stream temperature measurements only are not sufficient to identify substantial groundwater seepage locations within a headwater stream. Conversely, comparing the metrics from dual-depth temperatures show significant differences so that at groundwater seepage locations, temperatures at the SWI, merely explain 43-75 % of the variation opposed to ≥91 % at the corresponding stream column temperatures. The figure showing a box-plot of the variation in daily mean temperature depict that at several locations there is great variation in the range the upper and lower loggers due to groundwater seepage. In general, the linear regression show that at these locations at the SWI, the slopes (<0.25) and intercepts (>6.5oC) are substantially lower and higher, while the mean diel amplitudes (<0.98oC) are decreased compared to remaining locations. The dual-depth approach was applied in a post-glacial fluvial setting, where metrics analyses overall corresponded to field measurements of groundwater fluxes deduced from vertical streambed temperatures and stream flow accretions. Thus, we propose a method reliably identifying groundwater seepage locations along streambed in such settings.

Seasonal patterns in the soil water balance of a Spartina marsh site at North Inlet, South Carolina, USA

USGS Publications Warehouse

Gardner, L.R.; Reeves, H.W.

2002-01-01

Time series of ground-water head at a mid-marsh site near North Inlet, South Carolina, USA can be classified into five types of forcing signatures based on the dominant water flux governing water-level dynamics during a given time interval. The fluxes that can be recognized are recharge by tides and rain, evapotranspiration (ET), seepage into the near surface soil from below, and seepage across the soil surface to balance either ET losses or seepage influxes from below. Minimal estimates for each flux can be made by multiplying the head change induced by it by the measured specific yield of the soil. These flux estimates are provide minimal values because ET fluxes resulting from this method are about half as large as those estimated from calculated potential evapotranspiration (PET), which place an upper limit on the actual ET. As evapotranspiration is not moisture-limited at this regularly submerged site, the actual ET is probably nearly equal to PET. Thus, all of the other fluxes are probably twice as large as those given by this method. Application of this method shows that recharge by tides and rain only occurs during spring and summer when ET exceeds upward seepage from below and is thereby able to draw down the water table below the marsh surface occasionally. During fall and winter, seepage of fresh water from below is largely balanced by seepage out of the soil into overlying tidal water or into sheet flow during tidal exposure. The resulting reduction in soil water salinity may thereby enhance the growth of Spartina in the following spring. ?? 2002, The Society of Wetland Scientists.

Characterization of salinity loads and selenium loads in the Smith Fork Creek region of the Lower Gunnison River Basin, western Colorado, 2008-2009

USGS Publications Warehouse

Richards, Rodney J.; Linard, Joshua I.; Hobza, Christopher M.

2014-01-01

The lower Gunnison River Basin of the Colorado River Basin has elevated salinity and selenium levels. The Colorado River Basin Salinity Control Act of June 24, 1974 (Public Law 93–320, amended by Public Law 98–569), authorized investigation of the Lower Gunnison Basin Unit Salinity Control Project by the U.S. Department of the Interior. The Bureau of Reclamation (Reclamation) and the Natural Resources Conservation Service are responsible for assessing and implementing measures to reduce salinity and selenium loading in the Colorado River Basin. Cost-sharing programs help farmers, ranchers, and canal companies improve the efficiency of water delivery systems and irrigation practices. The delivery systems (irrigation canals) have been identified as potential sources of seepage, which can contribute to salinity loading. Reclamation wants to identify seepage from irrigation systems in order to maximize the effectiveness of the various salinity-control methods, such as polyacrylamide lining and piping of irrigation canals programs. The U.S. Geological Survey, in cooperation with Reclamation, developed a study to characterize the salinity and selenium loading of seven subbasins in the Smith Fork Creek region and identify where control efforts can be maximized to reduce salinity and selenium loading. Total salinity loads ranged from 27.9±19.1 tons per year (t/yr) to 87,500±80,500 t/yr. The four natural subbasins—BkKm, RCG1, RCG2, and SF1—had total salinity loads of 27.9±19.1 t/yr, 371±248 t/yr, 2,180±1,590 t/yr, and 4,200±2,720 t/yr, respectively. The agriculturally influenced sites had salinity loads that ranged from 7,580±6,900 t/yr to 87,500±80,500 t/yr. Salinity loads for the subbasins AL1, B1, CK1, SF2, and SF3 were 7,580±6,900 t/yr; 28,300±26,700 t/yr; 48,700±36,100 t/yr; 87,500±80,900 t/yr; and 52,200±31,800 t/yr, respectively. The agricultural salinity load was separated into three components: tail water, deep percolation, and canal seepage. Annual tail-water salinity loads ranged from 48.0 to 2,750 tons in the Smith Fork Creek region. The largest tail-water salinity load was in subbasin SF3, and the lowest salinity load from tail water was in subbasin R1. The remaining four agricultural subbasins—AL1, B1, CK1, and SF2—had tail-water loads of 285 t/yr, 180 t/yr, 333 t/yr, and 1,700 t/yr, respectively. The deep percolation component of the agricultural salinity load ranged from 3,300 t/yr in subbasin AL1 to 51,800 t/yr in subbasin SF2. Subbasins R1, B1, CK1, and SF3 had deep percolation salinity loads of 4,940 t/yr, 15,200 t/yr, 21,200 t/yr, and 23,600 t/yr, respectively. The canal seepage component of the agricultural salinity load ranged from 1,100 t/yr in subbasin AL1 to 15,300 t/yr in subbasin CK1. Subbasins B1, R1, SF2, and SF3 had canal seepage salinity loads of 6,610 t/yr, 3,890 t/yr, 9,430 t/yr, and 12,100 t/yr, respectively. Four natural subbasins—RCG1, RCG2, SF1, and BkKm—were used to calculate natural salinity yields for the remaining subbasins. The appropriate salinity yield was applied to the corresponding number of acres and resulted in a natural salinity load for each subbasin. The annual salinity yields for the Dakota Sandstone and Burro Canyon Formation, Mancos Shale, and crystalline geologies are 0.217 tons per acre (t/acre), 0.113 t/acre, and 0.151 t/acre, respectively. Three of the four natural subbasins had little to no selenium load based on the measured data and calculated selenium loads. Subbasins RCG1 and RCG2 had surface-water selenium loads of 0.106±0.024 pounds (lb) and 0.00 lb, respectively. Subbasin BkKm did not have an estimated surface-water selenium load because of the lack of any water-quality samples during the study period. The subbasin designated by site CK1 had the highest selenium load with 135±38.7 lb, and the next highest subbasins in decreasing order are B1, SF3, AL1, SF1, and R1 with selenium loads of 69.6±28.4 lb, 56.5±23.8 lb, 30.5±16.6 lb, 26.8±6.95 lb, and 15.6±27.7 lb, respectively.

A numerical procedure for transient free surface seepage through fracture networks

NASA Astrophysics Data System (ADS)

Jiang, Qinghui; Ye, Zuyang; Zhou, Chuangbing

2014-11-01

A parabolic variational inequality (PVI) formulation is presented for the transient free surface seepage problem defined for a whole fracture network. Because the seepage faces are specified as Signorini-type conditions, the PVI formulation can effectively eliminate the singularity of spillpoints that evolve with time. By introducing a continuous penalty function to replace the original Heaviside function, a finite element procedure based on the PVI formulation is developed to predict the transient free surface response in the fracture network. The effects of the penalty parameter on the solution precision are analyzed. A relative error formula for evaluating the flow losses at steady state caused by the penalty parameter is obtained. To validate the proposed method, three typical examples are solved. The solutions for the first example are compared with the experimental results. The results from the last two examples further demonstrate that the orientation, extent and density of fractures significantly affect the free surface seepage behavior in the fracture network.

Seepage Bifurcation as a Critical Process

NASA Astrophysics Data System (ADS)

Yi, R.; Rothman, D.

2015-12-01

Channel networks form beautiful and surprisingly intricate geometries, yet diligently evade comprehensive mathematical understanding. Work in recent years has shed light on this problem. Networks driven by seepage flow, in particular, have been shown to grow in a field that can be described by the Laplace equation, providing us with an understanding of valley growth and shape. However, the process by which such networks branch to form these ramified shapes is yet a mystery. We focus our attention on a highly ramified seepage valley network in Bristol, Florida. We study the behavior of flux to valley heads as a function of valley length, and use this result to motivate our discussion of branch formation. We then hypothesize that a critical groundwater flux demarcates a transition point where topographic diffusion is overcome by branching processes, and we present network-wide flux calculations, cosmogenic data, and simulation to support our claim. Our results ultimately suggest a mechanism for seepage bifurcation, and inform our understanding of pattern formation in river networks.

Surface water-ground water interactions along the lower Dungeness River and vertical hydraulic conductivity of streambed sediments, Clallam County, Washington, September 1999-July 2001

USGS Publications Warehouse

Simonds, F. William; Sinclair, Kirk A.

2002-01-01

The Dungeness River emerges from the Olympic Mountains and flows generally north toward the Strait of Juan De Fuca, crossing the broad, fertile alluvial fan of the Sequim-Dungeness peninsula in northeastern Clallam County, Washington. Increasing competition for the peninsula's ground-water resources, changing water-use patterns, and recent requirements to maintain minimum in-stream flows to enhance endangered salmon and trout populations have severely strained the peninsula's water resources and necessitated a better understanding of the interaction between surface water and groundwater. Three methods were used to characterize the interchange between surface water and groundwater along the lower 11.8 miles of the Dungeness River corridor between September 1999 and July 2001. In-stream mini-piezometers were used to measure vertical hydraulic gradients between the river and the water-table aquifer at 27 points along the river and helped to define the distribution of gaining and losing stream reaches. Seepage runs were used to quantify the net volume of water exchanged between the river and ground water within each of five river reaches, termed 'seepage reaches.' Continuous water-level and water-temperature monitoring at two off-stream well transects provided data on near-river horizontal hydraulic gradients and temporal patterns of water exchange for a representative gaining stream reach and a representative losing stream reach. Vertical hydraulic gradients in the mini-piezometers generally were negative between river miles 11.8 and 3.6, indicating loss of water from the river to ground water. Gradients decreased in the downstream direction from an average of -0.86 at river mile 10.3 to -0.23 at river mile 3.7. Small positive gradients (+0.01 to +0.02) indicating ground-water discharge occurred in three localized reaches below river mile 3.7. Data from the seepage runs and off-stream transect wells supported and were generally consistent with the mini-piezometer findings. An exception occurred between river miles 8.1 and 5.5 where seepage results showed a small gain and the mini-piezometers showed negative gradients. Vertical hydraulic conductivity of riverbed sediments was estimated using hydraulic gradients measured with the mini-piezometers and estimated seepage fluxes. The resulting conductivity values ranged from an average of 1 to 29 feet per day and are similar to values reported for similar river environments elsewhere. The results of this study will be used to calibrate a transient, three-dimensional ground-water flow model of the Sequim-Dungeness peninsula. The model will be used to assess the potential effects on ground-water levels and river flows that result from future water use and land-use changes on the peninsula.

Electrical resistivity investigation of fluvial geomorphology to evaluate potential seepage conduits to agricultural lands along the San Joaquin River, Merced County, California, 2012–13

USGS Publications Warehouse

Groover, Krishangi D.; Burgess, Matthew K.; Howle, James F.; Phillips, Steven P.

2017-02-08

Increased flows in the San Joaquin River, part of the San Joaquin River Restoration Program, are designed to help restore fish populations. However, increased seepage losses could result from these higher restoration flows, which could exacerbate existing drainage problems in neighboring agricultural lands and potentially damage crops. Channel deposits of abandoned river meanders that are hydraulically connected to the river could act as seepage conduits, allowing rapid and widespread water-table rise during restoration flows. There is a need to identify the geometry and properties of these channel deposits to assess their role in potential increased seepage effects and to evaluate management alternatives for reducing seepage. Electrical and electromagnetic surface geophysical methods have provided a reliable proxy for lithology in studies of fluvial and hyporheic systems where a sufficient electrical contrast exists between deposits of differing grain size. In this study, direct-current (DC) resistivity was used to measure subsurface resistivity to identify channel deposits and to map their subsurface geometry. The efficacy of this method was assessed by using DC resistivity surveys collected along a reach of the San Joaquin River in Merced County, California, during the summers of 2012 and 2013, in conjunction with borings and associated measurements from a hydraulic profiling tool. Modeled DC resistivity data corresponded with data from cores, hand-auger samples, a hydraulic profiling tool, and aerial photographs, confirming that DC resistivity is effective for differentiating between silt and sand deposits in this setting. Modeled DC resistivity data provided detailed two-dimensional cross-sectional resistivity profiles to a depth of about 20 meters. The distribution of high-resistivity units in these profiles was used as a proxy for identifying areas of high hydraulic conductivity. These data were used subsequently to guide the location and depth of wells installed onsite for monitoring flow in the channel deposits. Estimates of the cross-sectional area of channel deposits from DC resistivity pseudosections can provide critical input for groundwater-flow models designed to simulate river seepage and evaluate seepage-management alternatives.

Ubiquitous Presence and Novel Diversity of Anaerobic Alkane Degraders in Cold Marine Sediments.

PubMed

Gittel, Antje; Donhauser, Johanna; Røy, Hans; Girguis, Peter R; Jørgensen, Bo B; Kjeldsen, Kasper U

2015-01-01

Alkanes are major constituents of crude oil and are released to the marine environment by natural seepage and from anthropogenic sources. Due to their chemical inertness, their removal from anoxic marine sediments is primarily controlled by the activity of anaerobic alkane-degrading microorganisms. To facilitate comprehensive cultivation-independent surveys of the diversity and distribution of anaerobic alkane degraders, we designed novel PCR primers that cover all known diversity of the 1-methylalkyl succinate synthase gene (masD/assA), which catalyzes the initial activation of alkanes. We studied masD/assA gene diversity in pristine and seepage-impacted Danish coastal sediments, as well as in sediments and alkane-degrading enrichment cultures from the Middle Valley (MV) hydrothermal vent system in the Pacific Northwest. MasD/assA genes were ubiquitously present, and the primers captured the diversity of both known and previously undiscovered masD/assA gene diversity. Seepage sediments were dominated by a single masD/assA gene cluster, which is presumably indicative of a substrate-adapted community, while pristine sediments harbored a diverse range of masD/assA phylotypes including those present in seepage sediments. This rare biosphere of anaerobic alkane degraders will likely increase in abundance in the event of seepage or accidental oil spillage. Nanomolar concentrations of short-chain alkanes (SCA) were detected in pristine and seepage sediments. Interestingly, anaerobic alkane degraders closely related to strain BuS5, the only SCA degrader in pure culture, were found in mesophilic MV enrichments, but not in cold sediments from Danish waters. We propose that the new masD/assA gene lineages in these sediments represent novel phylotypes that are either fueled by naturally occurring low levels of SCA or that metabolize medium- to long-chain alkanes. Our study highlights that masD/assA genes are a relevant diagnostic marker to identify seepage and microseepage, e.g., during prospecting for oil and gas, and may act as an indicator of anthropogenic oil spills in marine sediments.

The linear stability of vertical mixture seepage into the close porous filter with clogging

NASA Astrophysics Data System (ADS)

Maryshev, Boris S.

2017-02-01

In the present paper, filtration of a mixture through a close porous filter is considered. A heavy solute penetrates from the upper side of the filter into the filter body due to seepage flow and diffusion. In the presence of heavy solute a domain with a heavy fluid is formed near the upper boundary of the filter. The stratification, at which the heavy fluid is located above the light, is unstable. When the mass of the heavy solute exceeds the critical value, one can observe the onset of instability. As a result, two regimes of vertical filtration can occur: (1) homogeneous seepage and (2) convective filtration. Filtration of a mixture in porous media is a complex process. It is necessary to take into account the solute immobilization (or sorption) and clogging of porous medium. We consider the case of low solute concentrations, in which the immobilization is described by the linear MIM (mobile/immobile media) model. The clogging is described by the dependence of permeability on porosity in terms of the Carman-Kozeny formula. The presence of immobile (or adsorbed) particles of the solute decreases the porosity of media and porous media becomes less permeable. The purpose of the paper is to find the stability conditions for the homogeneous vertical seepage of the mixture into the close porous filter. The linear stability problem is solved using the quasi-static approach. The critical times of instability are estimated. The stability maps have been plotted in the space of system parameters. The applicability of quasi-static approach is substantiated by direct numerical simulation.

Gas seepage in the Northern Adriatic Sea

NASA Astrophysics Data System (ADS)

Matilde Ferrante, Giulia; Donda, Federica; Volpi, Valentina; Tinivella, Umberta

2017-04-01

In the Northern Adriatic Sea, the occurrence of gas seepage has been widely documented. However, the origin of seeping gas was not clearly constrained. Geophysical data with different scale of resolution, i.e. multichannel seismic profiles, CHIRP and morpho-bathymetry data collected in 2009 and 2014 by OGS reveal that several the gas-enriched fluid vents are deeply rooted. In fact, the entire Plio-Quaternary succession is characterized by widespread seismic anomalies represented by wipe-out zones and interpreted as gas chimneys. They commonly root at the base of the Pliocene sequence but also within the Paleogene succession, where they appear to be associated to deep-seated, Mesozoic-to-Paleogene faults. These chimneys originate and terminate at different stratigraphic levels; they also commonly reach the seafloor, where rock outcrops interpreted as authigenic carbonate deposits have been recognized. In places, gas is then capable to escape in the water column as shown by numerous gas flares. On going studies are addressed to: 1. re-examining the structural setting of the study area, in order to verify a possible structural control on chimney distribution and gas migration; 2. performing geochemical analysis on gas which have been sampled in some key emission points; 3. a quantitative analysis of some selected boreholes well logs (made available through the public VidePi database (www.videpi.com)) aimed to estimate the amount of gas present in sediments. This work presents the preliminary results regarding the latter aspect of our research. In a first instance, for each selected borehole the geophysical logs have been digitized. This procedure consists in a manual picking of curves, in a set system of reference. Static corrections for vertical offset are made at this stage. Logs are then divided by type and converted in common scales, amplifications and units. Every log is resampled in order to cut high frequencies not useful in the comparison with seismic data. Estimation of gas requires a petrophysical characterization of sediments, but unfortunately the available wells are not sufficient for our investigations. For this reason, we are presently trying to establish empirical relationships between the available logs. All information available from wells and results from literature are used to fit cross-plots, and related chi-square tests are performed. Some correlations among our petrophysical logs and common trends in the investigated area have been already found, but our work is still in progress. This analysis will hopefully provide a petrophysical characterization of the study area and will be used to estimate density, velocity and porosity profiles. Next step will consist in an ad hoc processing of seismic data, applying a True Amplitude Recovery and keeping the amplitude information unaffected, which is the first request in our analysis. References: Deep-sourced gas seepage and methane-derived carbonates in the Northern Adriatic Sea, Donda et al., 2015; Sound velocity and related properties of marine sediments, Hamilton et al., 1982; Archie's law - a reappraisal, Glover, 2016.

Characterizing Volcanic Processes using Near-bottom, High Resolution Magnetic Mapping of the Caldera and Inner Crater of the Kick'em Jenny Submarine Volcano

NASA Astrophysics Data System (ADS)

Ruchala, T. L.; Chen, M.; Tominaga, M.; Carey, S.

2016-12-01

Kick'em Jenny (KEJ) is an active submarine volcano located in the Lesser Antilles subduction zone, 7.5 km north of the Caribbean island Grenada. KEJ, known as one of the most explosive volcanoes in Caribbean, erupted 12 times since 1939 with recent eruptions in 2001 and possibly in 2015. Multiple generations of submarine landslides and canyons have been observed in which some of them can be attributed to past eruptions. The structure of KEJ can be characterized as a 1300 m high conical profile with its summit crater located around 180 m in depth. Active hydrothermal venting and dominantly CO2 composition gas seepage take place inside this 250m diameter crater, with the most activity occurring primarily within a small ( 70 x 110 m) depression zone (inner crater). In order to characterize the subsurface structure and decipher the processes of this volcanic system, the Nautilus NA054 expedition in 2014 deployed the underwater Remotely Operated Vehicle (ROV) Hercules to conduct near-bottom geological observations and magnetometry surveys transecting KEJ's caldera. Raw magnetic data was corrected for vehicle induced magnetic noise, then merged with ROV to ship navigation at 1 HZ. To extract crustal magnetic signatures, the reduced magnetic data was further corrected for external variations such as the International Geomagnetic Reference Field and diurnal variations using data from the nearby San Juan Observatory. We produced a preliminary magnetic anomaly map of KEJ's caldera for subsequent inversion and forward modeling to delineate in situ magnetic source distribution in understanding volcanic processes. We integrated the magnetic characterization of the KEJ craters with shipboard multibeam, ROV visual descriptions, and photomosaics. Initial observations show the distribution of short wavelength scale highly magnetized source centered at the north western part of the inner crater. Although locations of gas seeps are ubiquitous over the inner crater area along ROV survey lines, some of their provinces coincide with distinctive magnetic characters, suggesting possible in situ structural or alteration boundaries (i.e. subsurface faults and hydrothermal destruction zones).

Stream simulation in an analog model of the ground-water system on Long Island, New York

USGS Publications Warehouse

Harbaugh, Arlen W.; Getzen, Rufus T.

1977-01-01

The stream circuits of an electric analog model of the ground-water system of Long Island were modified to more accurately represent the relationahip between streamflow and ground-water levels. Assumptions for use of the revised circuits are (1) that streams are strictly gaining, and (2) that ground-water seepage into the streams is proportional to the difference between streambed elevation and the average water-table elevation near the stream. No seepage into streams occurs when ground-water levels drop below the streambed elevation. Regional simulation of the 1962-68 drought on Long Island was significantly improved by use of the revised stream circuits.

Behavior of fiber reinforced sandy slopes under seepage

USDA-ARS?s Scientific Manuscript database

Seepage flow is a major contributor to instability of natural hill slopes, river banks and engineered embankments. In order to increase the factor of safety, an emerging technology involves the inclusion of synthetic fibers in the soil. The addition of tension resisting fibers has a favorable effec...

Reactivity of a series of isostructural cobalt pincer complexes with CO2, CO, and H(+).

PubMed

Shaffer, David W; Johnson, Samantha I; Rheingold, Arnold L; Ziller, Joseph W; Goddard, William A; Nielsen, Robert J; Yang, Jenny Y

2014-12-15

The preparation and characterization of a series of isostructural cobalt complexes [Co(t-Bu)2P(E)Py(E)P(t-Bu)2(CH3CN)2][BF4]2 (Py = pyridine, E = CH2, NH, O, and X = BF4 (1a-c)) and the corresponding one-electron reduced analogues [Co(t-Bu)2P(E)Py(E)P(t-Bu)2(CH3CN)2][BF4]2 (2a-c) are reported. The reactivity of the reduced cobalt complexes with CO2, CO, and H(+) to generate intermediates in a CO2 to CO and H2O reduction cycle are described. The reduction of 1a-c and subsequent reactivity with CO2 was investigated by cyclic voltammetry, and for 1a also by infrared spectroelectrochemistry. The corresponding CO complexes of (2a-c) were prepared, and the Co-CO bond strengths were characterized by IR spectroscopy. Quantum mechanical methods (B3LYP-d3 with solvation) were used to characterize the competitive reactivity of the reduced cobalt centers with H(+) versus CO2. By investigating a series of isostructural complexes, correlations in reactivity with ligand electron withdrawing effects are made.

Effect of Seepage on Change in Stress Distribution Scenario in Static and Seismic Behaviour of Earthen Dams

NASA Astrophysics Data System (ADS)

Nandi, N.; Chowdhury, Roy; Dutta, S. C.

2018-02-01

The present study makes an effort to understand the damage of earthen dams under static and seismic loading condition. To make the investigation more realistic, behaviour of earthen dams considering the occurrence of a phreatic line indicating the submerged zone due to seepage within the dam body is considered. In case of earthen dams, homogeneous or nonhomogeneous, the consideration of the occurrence of a phreatic line or seepage line through the dam body is an important part of the earthen dam design methodology. The impervious material properties in the submerged zone below the phreatic line due to seepage may differ a lot in magnitudes as compared to the value of the same materials lying above this line. Hence, to have the exact stress distribution scenarios within the earthen dam, the different material properties above and below the phreatic line are considered in this present study. The study is first carried out by two-dimensional as well as three-dimensional finite element analysis under static loading condition. The work is further extended to observe the effect of seepage due to the consideration of the phreatic line on dynamic characteristics of earthen dams. Free vibration analysis and seismic analysis based on the Complete Quadratic Combination (CQC) method by considering twodimensional and three-dimensional modeling are carried out to present the frequencies, mode shapes and the stress distribution pattern of the earthen dam.

Experimental study on distributed optical fiber-based approach monitoring saturation line in levee engineering

NASA Astrophysics Data System (ADS)

Su, Huaizhi; Li, Hao; Kang, Yeyuan; Wen, Zhiping

2018-02-01

Seepage is one of key factors which affect the levee engineering safety. The seepage danger without timely detection and rapid response may likely lead to severe accidents such as seepage failure, slope instability, and even levee break. More than 90 percent of levee break events are caused by the seepage. It is very important for seepage behavior identification to determine accurately saturation line in levee engineering. Furthermore, the location of saturation line has a major impact on slope stability in levee engineering. Considering the structure characteristics and service condition of levee engineering, the distributed optical fiber sensing technology is introduced to implement the real-time observation of saturation line in levee engineering. The distributed optical fiber temperature sensor system (DTS)-based monitoring principle of saturation line in levee engineering is investigated. An experimental platform, which consists of DTS, heating system, water-supply system, auxiliary analysis system and levee model, is designed and constructed. The monitoring experiment of saturation line in levee model is implemented on this platform. According to the experimental results, the numerical relationship between moisture content and thermal conductivity in porous medium is identified. A line heat source-based distributed optical fiber method obtaining the thermal conductivity in porous medium is developed. A DTS-based approach is proposed to monitor the saturation line in levee engineering. The embedment pattern of optical fiber for monitoring saturation line is presented.

Occurrence, distribution and prey items of juvenile marbled sole Pseudopleuronectes yokohamae around a submarine groundwater seepage on a tidal flat in southwestern Japan

NASA Astrophysics Data System (ADS)

Hata, Masaki; Sugimoto, Ryo; Hori, Masakazu; Tomiyama, Takeshi; Shoji, Jun

2016-05-01

Occurrence, distribution and prey items of juvenile marbled sole Pseudopleuronectes yokohamae were investigated around a submarine groundwater seepage on a tidal flat in southwestern Japan. Spatial distribution of radon-222 (222Rn) concentration in water showed more submarine groundwater seepage in the offshore area. The lower salinities at offshore sampling stations corresponded with the highest 222Rn concentrations. Juvenile marbled sole were collected from March through June with seasonal peak in April in 2013 and 2014. Mean abundance of juvenile marbled sole was highest at the second most offshore station where high submarine groundwater seepage was indicated. Major prey items in the stomachs of the marbled sole at the post-settlement stage (10-40 mm) were small crustaceans such as cumaceans and gammarids, which were partially replaced with polychaetes in larger juveniles (40-50 mm). Abundance of these major prey items was also higher at offshore stations. A negative correlation between gammarid abundance and salinity indicated a higher concentration of gammarids around the area of high submarine groundwater seepage, a pattern not observed for the other major prey organisms. Stable isotope analysis showed greater dependence of post-settlement stage marbled sole on the small crustaceans with low δ13C indicating that nutrients of terrestrial origin contribute to production of the juvenile marbled sole on the tidal flat.

3-D direct numerical model for failure of non-cohesive granular soils with upward seepage flow

NASA Astrophysics Data System (ADS)

Fukumoto, Yutaka; Ohtsuka, Satoru

2017-12-01

The paper reports the application of a 3-D direct particle-fluid simulation model to the seepage failure of granular soils. The goal of this study is to numerically capture the process of the failure which is induced by the seepage flow from the micromechanical aspects with no macroscopic assumptions. In order to accomplish this goal, non-cohesive granular assemblies with an upward seepage flow and a variety of pressure gradients are investigated. The motion and the collision of the soil particles are calculated by a soft sphere model, such as the discrete element method, and the flow of the pore fluid is directly solved at a smaller scale than the diameter of the soil particles by the lattice Boltzmann method. By coupling these methods, the interaction between the soil particles and the seepage flow is also considered. As a result of the series of analyses, the numerically predicted value for the critical hydraulic gradient is found to be in good agreement with the theoretical value. In addition, the rapid change in the flow pattern around the critical hydraulic gradient can be microscopically captured. By observing the evolution of the force chains inside the soils, it is demonstrated that the failure process of the contact networks can also be reproduced by the simulation model presented here.

Primary producing prokaryotic communities of brine, interface and seawater above the halocline of deep anoxic lake L'Atalante, Eastern Mediterranean Sea.

PubMed

Yakimov, Michail M; La Cono, Violetta; Denaro, Renata; D'Auria, Giuseppe; Decembrini, Franco; Timmis, Kenneth N; Golyshin, Peter N; Giuliano, Laura

2007-12-01

Meso- and bathypelagic ecosystems represent the most common marine ecological niche on Earth and contain complex communities of microorganisms that are for the most part ecophysiologically poorly characterized. Gradients of physico-chemical factors (for example, depth-related gradients of light, temperature, salinity, nutrients and pressure) constitute major forces shaping ecosystems at activity 'hot spots' on the ocean floor, such as hydrothermal vents, cold seepages and mud volcanoes and hypersaline lakes, though the relationships between community composition, activities and environmental parameters remain largely elusive. We report here results of a detailed study of primary producing microbial communities in the deep Eastern Mediterranean Sea. The brine column of the deep anoxic hypersaline brine lake, L'Atalante, the overlying water column and the brine-seawater interface, were characterized physico- and geochemically, and microbiologically, in terms of their microbial community compositions, functional gene distributions and [(14)C]bicarbonate assimilation activities. The depth distribution of genes encoding the crenarchaeal ammonia monooxygenase alpha subunit (amoA), and the bacterial ribulose-1,5-biphosphate carboxylase/oxygenase large subunit (RuBisCO), was found to coincide with two different types of chemoautotrophy. Meso- and bathypelagic microbial communities were enriched in ammonia-oxidizing Crenarchaeota, whereas the autotrophic community at the oxic/anoxic interface of L'Atalante lake was dominated by Epsilonproteobacteria and sulfur-oxidizing Gammaproteobacteria. These autotrophic microbes are thus the basis of the food webs populating these deep-sea ecosystems.

Our trial to develop a risk assessment tool for CO2 geological storage (GERAS-CO2GS)

NASA Astrophysics Data System (ADS)

Tanaka, A.; Sakamoto, Y.; Komai, T.

2012-12-01

We will introduce our researches about to develop a risk assessment tool named 'GERAS-CO2GS' (Geo-environmental Risk Assessment System, CO2 Geological Storage Risk Assessment System) for 'Carbon Dioxide Geological Storage (Geological CCS)'. It aims to facilitate understanding of size of impact of risks related with upper migration of injected CO2. For gaining public recognition about feasibility of Geological CCS, quantitative estimation of risks is essential, to let public knows the level of the risk: whether it is negligible or not. Generally, in preliminary hazard analysis procedure, potential hazards could be identified within Geological CCS's various facilities such as: reservoir, cap rock, upper layers, CO2 injection well, CO2 injection plant and CO2 transport facilities. Among them, hazard of leakage of injected C02 is crucial, because it is the clue to estimate risks around a specific injection plan in terms of safety, environmental protection effect and economy. Our risk assessment tool named GERAS-CO2GS evaluates volume and rate of retention and leakage of injected CO2 in relation with fractures and/or faults, and then it estimates impact of seepages on the surface of the earth. GERAS-CO2GS has four major processing segments: (a) calculation of CO2 retention and leakage volume and rate, (b) data processing of CO2 dispersion on the surface and ambient air, (c) risk data definition and (d) evaluation of risk. Concerning to the injection site, we defined a model, which is consisted from an injection well and a geological strata model: which involves a reservoir, a cap rock, an upper layer, faults, seabed, sea, the surface of the earth and the surface of the sea. For retention rate of each element of CO2 injection site model, we use results of our experimental and numerical studies on CO2 migration within reservoirs and faults with specific lithological conditions. For given CO2 injection rate, GERAS-CO2GS calculates CO2 retention and leakage of each segment of injection site model. It also evaluates dispersion of CO2 on the surface of the earth and ambient air, and displays evaluated risk level on Goole earth contour of risk levels with color classification. As regard with numerical estimation of CO2's surface dispersion, we use ADMER 2.5 (Atmospheric Dispersion Model for Exposure and Risk Assessment, AIST), which assesses ambient dispersion of materials using real observed atmospheric data such as wind direction and temperatures by meteorological observatory. As far as our simulations, it is obvious that cause of Lake Nyos type accident is owes its maar topography of the lake and the volume and duration of the CO2 outburst (about 1 km3). It's unlikely to cause similar happenings in geological CCS site, because there are significant difference amount of CO2 and topography. At this moment, GERAS-CO2GS is prototype system. We are going to extend GERAS-CO2GS functions and evaluate risks of further risk scenarios. Concerning to the route of seabed to sea and the surface of the sea, we hope to implement outer research findings into our logics. In the course of further research, we are going to develop GERAS-CO2GS will be able to estimate broader risks, and to contribute to the efforts for legislations and standards of CO2 Geological storage.

Polyacrylamide and biopolymer effects on flocculation, aggregate stability, and water seepage in a silt loam

USDA-ARS?s Scientific Manuscript database

Researcher’s seek a more renewable and natural alternative for water soluble anionic polyacrylamide (PAM), a highly-effective, petroleum-derived polymer used in agriculture to control erosion and reduce water seepage from unlined irrigation structures. This study evaluated two anionic polymers: a ba...

Influence of riparian seepage zones on nitrate variability in two agricultural headwater streams

USDA-ARS?s Scientific Manuscript database

Riparian seepage zones are one of the primary pathways of groundwater transport to headwater streams. While seeps have been recognized for their contributions to streamflow, there is little information on how seeps affect stream water quality. The objective of this study was to examine the influence...

Groundwater impacts on surface water quality and nutrient loads in lowland polder catchments: monitoring the greater Amsterdam area

NASA Astrophysics Data System (ADS)

Yu, Liang; Rozemeijer, Joachim; van Breukelen, Boris M.; Ouboter, Maarten; van der Vlugt, Corné; Broers, Hans Peter

2018-01-01

The Amsterdam area, a highly manipulated delta area formed by polders and reclaimed lakes, struggles with high nutrient levels in its surface water system. The polders receive spatially and temporally variable amounts of water and nutrients via surface runoff, groundwater seepage, sewer leakage, and via water inlets from upstream polders. Diffuse anthropogenic sources, such as manure and fertiliser use and atmospheric deposition, add to the water quality problems in the polders. The major nutrient sources and pathways have not yet been clarified due to the complex hydrological system in lowland catchments with both urban and agricultural areas. In this study, the spatial variability of the groundwater seepage impact was identified by exploiting the dense groundwater and surface water monitoring networks in Amsterdam and its surrounding polders. A total of 25 variables (concentrations of total nitrogen (TN), total phosphorus (TP), NH4, NO3, HCO3, SO4, Ca, and Cl in surface water and groundwater, N and P agricultural inputs, seepage rate, elevation, land-use, and soil type) for 144 polders were analysed statistically and interpreted in relation to sources, transport mechanisms, and pathways. The results imply that groundwater is a large source of nutrients in the greater Amsterdam mixed urban-agricultural catchments. The groundwater nutrient concentrations exceeded the surface water environmental quality standards (EQSs) in 93 % of the polders for TP and in 91 % for TN. Groundwater outflow into the polders thus adds to nutrient levels in the surface water. High correlations (R2 up to 0.88) between solutes in groundwater and surface water, together with the close similarities in their spatial patterns, confirmed the large impact of groundwater on surface water chemistry, especially in the polders that have high seepage rates. Our analysis indicates that the elevated nutrient and bicarbonate concentrations in the groundwater seepage originate from the decomposition of organic matter in subsurface sediments coupled to sulfate reduction and possibly methanogenesis. The large loads of nutrient-rich groundwater seepage into the deepest polders indirectly affect surface water quality in the surrounding area, because excess water from the deep polders is pumped out and used to supply water to the surrounding infiltrating polders in dry periods. The study shows the importance of the connection between groundwater and surface water nutrient chemistry in the greater Amsterdam area. We expect that taking account of groundwater-surface water interaction is also important in other subsiding and urbanising deltas around the world, where water is managed intensively in order to enable agricultural productivity and achieve water-sustainable cities.

National Levee Database: monitoring, vulnerability assessment and management in Italy

NASA Astrophysics Data System (ADS)

Barbetta, Silvia; Camici, Stefania; Maccioni, Pamela; Moramarco, Tommaso

2015-04-01

A properly designed and constructed levees system can often be an effective device for repelling floodwaters and provide barriers against inundation to protect urbanized and industrial areas. However, the delineation of flooding-prone areas and the related hydraulic hazard mapping taking account of uncertainty (Apel et al., 2008) are usually developed with a scarce consideration of the possible occurrence of levee failures along river channels (Mazzoleni et al., 2014). Indeed, it is well known that flooding is frequently the result of levee failures that can be triggered by several factors, as: (1) overtopping, (2) scouring of the foundation, (3) seepage/piping of levee body/foundation, and (4) sliding of the foundation. Among these failure mechanisms that are influenced by the levee's geometrical configuration, hydraulic conditions (e.g. river level and seepage), and material properties (e.g. permeability, cohesion, porosity, compaction), the piping caused by seepage (ICOLD, http://www.icold-cigb.org) is considered one of the most dominant levee failure mechanisms (Colleselli F., 1994; Wallingford H. R., 2003). The difficulty of estimating the hydraulic parameters to properly describe the seepage line within the body and foundation of the levee implies that the study of the critical flood wave routing is typically carried out by assuming that the levee system is undamaged during the flood event. In this context, implementing and making operational a National Levee Database (NLD), effectively structured and continuously updated, becomes fundamental to have a searchable inventory of information about levees available as a key resource supporting decisions and actions affecting levee safety. The ItaliaN LEvee Database (INLED) has been recently developed by the Research Institute for Geo-Hydrological Protection (IRPI) for the Civil Protection Department of the Presidency of Council of Ministers. INLED has the main focus of collecting comprehensive information about Italian levees and historical breach failures to be exploited in the framework of an operational procedure addressed to the seepage vulnerability assessment of river reaches where the levee system is an important structural measure against flooding. For its structure, INLED is a dynamic geospatial database with ongoing efforts to add levee data from authorities with the charge of hydraulic risk mitigation. In particular, the database is aimed to provide the available information about: i) location and condition of levees; ii) morphological and geometrical properties; iii) photographic documentation; iv) historical levee failures; v) assessment of vulnerability to overtopping and seepage carried out through a procedure based on simple vulnerability indexes (Camici et al. 2014); vi) management, control and maintenance; vii)flood hazard maps developed by assuming the levee system undamaged/damaged during the flood event. Currently, INLED contains data of levees that are mostly located in the Tiber basin, Central Italy. References Apel H., Merz B. & Thieken A.H. Quantification of uncertainties in flood risk assessments. Int J River Basin Manag 2008, 6, (2), 149-162. Camici S,, Barbetta S., Moramarco T., Levee body vulnerability to seepage: the case study of the levee failure along the Foenna stream on 1st January 2006 (central Italy)", Journal of Flood Risk Management, in press. Colleselli F. Geotechnical problems related to river and channel embankments. Rotterdam, the Netherlands: Springer, 1994. H. R.Wallingford Consultants (HRWC). Risk assessment for flood and coastal defence for strategic planning: high level methodology technical report, London, 2003. Mazzoleni M., Bacchi B., Barontini S., Di Baldassarre G., Pilotti M. & Ranzi R. Flooding hazard mapping in floodplain areas affected by piping breaches in the Po River, Italy. J Hydrol Eng 2014, 19, (4), 717-731.

Importance of the Colmation Layer in the Transport and Removal of Cyanobacteria, Viruses, and Dissolved Organic Carbon during Natural Lake-Bank Filtration.

PubMed

Harvey, Ronald W; Metge, David W; LeBlanc, Denis R; Underwood, Jen; Aiken, George R; Butler, Kenna; McCobb, Timothy D; Jasperse, Jay

2015-09-01

This study focused on the importance of the colmation layer in the removal of cyanobacteria, viruses, and dissolved organic carbon (DOC) during natural bank filtration. Injection-and-recovery studies were performed at two shallow (0.5 m deep), sandy, near-shore sites at the southern end of Ashumet Pond, a waste-impacted, kettle pond on Cape Cod, MA, that is subject to periodic blooms of cyanobacteria and continuously recharges a sole-source drinking-water aquifer. The experiment involved assessing the transport behaviors of bromide (conservative tracer), sp. IU625 (cyanobacterium, 2.6 ± 0.2 µm), AS-1 (tailed cyanophage, 110 nm long), MS2 (coliphage, 26 nm diameter), and carboxylate-modified microspheres (1.7 µm diameter) introduced to the colmation layer using a bag-and-barrel (Lee-type) seepage meter. The injectate constituents were tracked as they were advected across the pond water-groundwater interface and through the underlying aquifer sediments under natural-gradient conditions past push-point samplers placed at ∼30-cm intervals along a 1.2-m-long, diagonally downward flow path. More than 99% of the microspheres, IU625, MS2, AS-1, and ∼44% of the pond DOC were removed in the colmation layer (upper 25 cm of poorly sorted bottom sediments) at two test locations characterized by dissimilar seepage rates (1.7 vs. 0.26 m d). Retention profiles in recovered core material indicated that >82% of the attached IU625 were in the top 3 cm of bottom sediments. The colmation layer was also responsible for rapid changes in the character of the DOC and was more effective (by three orders of magnitude) at removing microspheres than was the underlying 20-cm-thick segment of sediment. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Tufa in Northern England: depositional facies, carbonate mineral fabrics, and role of biomineralization

NASA Astrophysics Data System (ADS)

Manzo, E.; Mawson, M.; Perri, E.; Tucker, M. E.

2009-04-01

Tufas are widely scattered in northern England, being concentrated in areas of limestone (Carboniferous and Permian), where there are springs, seepages, streams and waterfalls with waters supersatured in respect of calcite. Some deposits are clearly related to faults. Tufas have been examined in Gordale and Malham (SW Yorkshire), Teesdale and Weardale (Co. Durham), Sunderland (Tyne & Wear) and Great Asby Fell (Cumbria). A variety of tufa types are developed: spring-related pisoids and moss tufa, fluviatile barrage and waterfall tufa, and seepage and spring tufa with microbial oncoids in a paludal setting. We present preliminary data and observations on tufa in the Teesdale area, which forms along the valley-side adjacent to the River Tees. Locally here, a tiny stream draining agricultural land runs over a sandstone outcrop at the top of a 30 metre high slope; water descends the 30-60 degrees slope, creating tiny waterfalls and pools across an area reaching 10 metres wide, on the way down towards the river. Three main facies are recognizable in the tufa deposits: carbonate crusts, moss tufa and pisoids. In the upper part of the slope tufa occurs as sub-vertical 0.5-5 cm thick carbonate crusts forming "sheets" with a bulbous external surface covered by a green biofilm, with some insect larvae. Encrustations form upon surfaces of rock exposures and pebbles, and coat plant fragments (leaves, twigs, pine cones). Tufa precipitation, particularly on mosses, liverworts and leaves (moss tufa), creates a series of rimmed pools, a few decimetres across and centimetres deep. Apart from the presence of moss, which gives the tufa has a vacuolar texture, the main constituents are cyanobacteria and diatoms. The moss tufa deposit may reach a metre or more in height and several metres in width, notably towards the base of the slope, adjacent to the river. Within the small pools on the slope, pisoids and partially calcified plant remains accumulate. They also occur abundantly in the soil hereabouts, and are gradually being washed down slope. Pisoids vary in size and shape, ranging from rods to sub-spherical forms, up to several cm long or a cm or more in diameter. The external surface is a smooth dull surface of a pale grey-buff colour; the nucleus may be a plant fragment, tufa intraclast or rock fragment. Microfacies Teesdale tufa is characterized by three microfacies all contributing to a basic stromatolitic or laminated microfabric: dendrolite, dense micrite and palisades of sparite. Laminae consist of an irregular alternation of the three microfacies, which vary in abundance within the main depositional facies. Dendrolitic layers are characterized of mineralized, upward-branching cyanobacterial filaments, forming bush-like fans. Coarse sparitic layers consist of palisades of bladed calcite spar characterized by rhombohedral terminations. Micritic layers consist of dark-brown dense laminae with some clotted fabric, composed of dark micritic crystals. In thin-section molds of moss stems are often preserved by a sparitic layer that formed a coating before decay of the moss organic tissues. Cavities are abundant in moss tufa and crusts. They are often empty or in some case filled by detrital particles. Pisoids under the microscope show a cortex characterized by a concentric structure consisting mainly dense micritic layers alternating with sporadic sparitic and/or dendrolitic layers. Calcified cyanobacterial filaments or their molds are very evident in the dendrolitic laminae, but also occur in the other microfacies, being incorporated in both the sparite macro-crystals and the micritic layers. Nanofacies of minerals The mineral composition of the autochthonous carbonate forming tufa is calcite with a few mole% Mg. Sub-hedral crystals of calcite, several tens of microns in size, form sparite crystals. Sub-polygonal micro-crystals and elongate fibres a few microns in size compose dense micrite and calcified filaments. Under extra-high SEM magnifications, all crystal forms seem be made of sub-spherical to rod-like nano-crystals, ranging in size from 100 to 300 nm. Other than cyanobacteria, calcified organic components like diatoms, plant tissues, and extra-cellular polymeric substances (EPS) are mineralized with the same crystal nano-elements. Conclusions Tufa formation seems strongly influenced by the inclination of the slope, water energy, the biota, including the biofilm, and the organic matter substrate (mainly EPS); super-saturation of water with respect to calcite is a pre-requisite for precipitation. The inclination of the slope determines the water energy and so the degassing of CO2 which leads to precipitation of carbonate. Photosynthesis by macrophytes, microphytes and cyanobacteria could also contribute to CO2 degassing. EPS degradation processes, particularly those involving heterotrophic micro-organisms which can induce an increase in alkalinity, could be a further mechanism of biomineralization in these tufa carbonates.

Studies on the reactivity of [Ge9]4- towards [Fe(cot)(CO)3]: synthesis and characterization of [Ge8Fe(CO)3]3- and of the anionic organometallic species [Fe(cot)(CO)3]-.

PubMed

Zhou, Binbin; Goicoechea, Jose M

2010-09-24

Reaction of cyclooctatetraene (COT) iron(II) tricarbonyl, [Fe(cot)(CO)(3)], with one equivalent of K(4)Ge(9) in ethylenediamine (en) yielded the cluster anion [Ge(8)Fe(CO)(3)](3-) which was crystallographically-characterized as a [K(2,2,2-crypt)](+) salt in [K(2,2,2-crypt)](3)[Ge(8)Fe(CO)(3)]. The chemically-reduced organometallic species [Fe(η(3)-C(8)H(8))(CO)(3)](-) was also isolated as a side-product from this reaction as [K(2,2,2-crypt)][Fe(η(3)-C(8)H(8))(CO)(3)]. Both species were further characterized by EPR and IR spectroscopy and electrospray mass spectrometry. The [Ge(8)Fe(CO)(3)](3-) cluster anion represents an unprecedented functionalized germanium Zintl anion in which the nine-atom precursor cluster has lost a vertex, which has been replaced by a transition-metal moiety.

Technique for predicting ground-water discharge to surface coal mines and resulting changes in head

USGS Publications Warehouse

Weiss, L.S.; Galloway, D.L.; Ishii, Audrey L.

1986-01-01

Changes in seepage flux and head (groundwater level) from groundwater drainage into a surface coal mine can be predicted by a technique that considers drainage from the unsaturated zone. The user applies site-specific data to precalculated head and seepage-flux profiles. Groundwater flow through hypothetical aquifer cross sections was simulated using the U.S. Geological Survey finite-difference model, VS2D, which considers variably saturated two-dimensional flow. Conceptual models considered were (1) drainage to a first cut, and (2) drainage to multiple cuts, which includes drainage effects of an area surface mine. Dimensionless head and seepage flux profiles from 246 simulations are presented. Step-by-step instructions and examples are presented. Users are required to know aquifer characteristics and to estimate size and timing of the mine operation at a proposed site. Calculated groundwater drainage to the mine is from one excavated face only. First cut considers confined and unconfined aquifers of a wide range of permeabilities; multiple cuts considers unconfined aquifers of higher permeabilities only. The technique, developed for Illinois coal-mining regions that use area surface mining and evaluated with an actual field example, will be useful in assessing potential hydrologic impacts of mining. Application is limited to hydrogeologic settings and mine operations similar to those considered. Fracture flow, recharge, and leakage are nor considered. (USGS)

Effects of the proposed Prosperity Reservoir on ground water and water quality in lower Center Creek basin, Missouri

USGS Publications Warehouse

Berkas, Wayne R.; Barks, James H.

1980-01-01

Effects of the proposed Prosperity Reservoir on ground water and water quality in lower Center Creek basin depend partly on the effectiveness of Grove Creek as a hydrologic boundary between the reservoir site and the Oronogo-Duenweg mining belt. Results of two dye traces indicate that Grove Creek probably is not an effective boundary. Therefore, higher water levels near the reservoir may cause more ground water to move into the mining belt and cause a greater discharge of zinc-laden mine water into Center Creek.Ground-water-level measurements and seepage runs on Center Creek indicate a relationship between ground-water levels, mine-water discharge and seepage, and base flow in Center Creek. From March to October 1979, ground-water levels generally decreased from 5 to 20 feet at higher elevations (recharge areas) and from 1 to 3 feet near Center Creek (discharge area); total mine water discharged to the surface before entering Center Creek decreased from 5.4 to 2.2 cubic feet per second; mine-water seepage directly to Center Creek decreased from an estimated 1.9 to 1.1 cubic feet per second; and the discharge of Center Creek near Carterville decreased from 184 to 42 cubic feet per second.Fertilizer industry wastes discharged into Grove Creek resulted in significant increases of nitrogen and phosphorus in lower Center Creek.

A Field Exercise on Groundwater Flow Using Seepage Meters and Mini-Piezometers.

ERIC Educational Resources Information Center

Lee, David R.; Cherry, John A.

1979-01-01

Basic principles of physical hydrogeology and the nature of hydrologic interactions between groundwater and surface water can be demonstrated using two devices, the miniature piezometer and the seepage meter which can be cheaply constructed by the teacher and students. Use of the devices and learning activities are presented. (RE)

Development a fluvial detachment rate model to predict the erodibility of cohesive soils under the influence of seepage

USDA-ARS?s Scientific Manuscript database

Seepage influences the erodibility of streambanks, streambeds, dams, and embankments. Usually the erosion rate of cohesive soils due to fluvial forces is computed using an excess shear stress model, dependent on two major soil parameters: the critical shear stress (tc) and the erodibility coefficie...

Use of strontium isotopes to identify buried water main leakage into groundwater in a highly urbanized coastal area.

PubMed

Leung, Chi-Man; Jiao, Jiu Jimmy

2006-11-01

Previous studies indicate that the local aquifer systems in the Mid-Levels, a highly urbanized coastal area in Hong Kong, have commonly been affected by leakage from water mains. The identification of leakage locations was done by conventional water quality parameters including major and trace elements. However, these parameters may lead to ambiguous results and fail to identify leakage locations especially where the leakage is from drinking water mains because the chemical composition of drinking water is similar to that of natural groundwater. In this study, natural groundwater, seepage in the developed spaces, leakage from water mains, and parent aquifer materials were measured for strontium isotope (87Sr/86Sr) compositions to explore the feasibility of using these ratios to better constrain the seepage sources. The results show that the 87Sr/86Sr ratios of natural groundwater and leakage from water mains are distinctly different and thus, they can provide additional information on the sources of seepage in developed spaces. A classification system based on the aqueous 87Sr/86Sr ratio is proposed for seepage source identification.

High mobilization of arsenic, metals and rare earth elements in seepage waters driven by respiration of old allochthonous organic carbon.

PubMed

Weiske, Arndt; Schaller, Jörg; Hegewald, Tilo; Machill, Susanne; Werner, Ingo; Dudel, E Gert

2013-12-01

Metal and metalloid mobilization processes within seepage water are of major concern in a range of water reservoir systems. The mobilization process of arsenic and heavy metals within a dam and sediments of a drinking water reservoir was investigated. Principle component analysis (PCA) on time series data of seepage water showed a clear positive correlation of arsenic with iron and DOC (dissolved organic carbon), and a negative correlation with nitrate due to respiratory processes. A relationship of reductive metal and metalloid mobilization with respiration of old carbon was shown. The system is influenced by sediment layers as well as a recent DOC input from degraded ombrotrophic peatbogs in the catchment area. The isotopic composition ((12)C, (13)C and (14)C) of DOC is altered along the path from basin to seepage water, but no significant changes in structural parameters (LC-OCD-OND, FT-IR) could be seen. DIC (dissolved inorganic carbon) in seepage water partly originates from respiratory processes, and a higher relationship of it with sediment carbon than with the DOC inventory of infiltrating water was found. This study revealed the interaction of respiratory processes with metal and metalloid mobilization in sediment water flows. In contrast to the presumption that emerging DOC via respiratory processes mainly controls arsenic and metal mobilization it could be shown that the presence of aged carbon compounds is essential. The findings emphasize the importance of aged organic carbon for DOC, DIC, arsenic and metal turnover.

Albedo and land surface temperature shift in hydrocarbon seepage potential area, case study in Miri Sarawak Malaysia

NASA Astrophysics Data System (ADS)

Suherman, A.; Rahman, M. Z. A.; Busu, I.

2014-02-01

The presence of hydrocarbon seepage is generally associated with rock or mineral alteration product exposures, and changes of soil properties which manifest with bare development and stress vegetation. This alters the surface thermodynamic properties, changes the energy balance related to the surface reflection, absorption and emission, and leads to shift in albedo and LST. Those phenomena may provide a guide for seepage detection which can be recognized inexpensively by remote sensing method. District of Miri is used for study area. Available topographic maps of Miri and LANDSAT ETM+ were used for boundary construction and determination albedo and LST. Three land use classification methods, namely fixed, supervised and NDVI base classifications were employed for this study. By the intensive land use classification and corresponding statistical comparison was found a clearly shift on albedo and land surface temperature between internal and external seepage potential area. The shift shows a regular pattern related to vegetation density or NDVI value. In the low vegetation density or low NDVI value, albedo of internal area turned to lower value than external area. Conversely in the high vegetation density or high NDVI value, albedo of internal area turned to higher value than external area. Land surface temperature of internal seepage potential was generally shifted to higher value than external area in all of land use classes. In dense vegetation area tend to shift the temperature more than poor vegetation area.

Subduction zone earthquake probably triggered submarine hydrocarbon seepage offshore Pakistan

NASA Astrophysics Data System (ADS)

Fischer, David; José M., Mogollón; Michael, Strasser; Thomas, Pape; Gerhard, Bohrmann; Noemi, Fekete; Volkhard, Spiess; Sabine, Kasten

2014-05-01

Seepage of methane-dominated hydrocarbons is heterogeneous in space and time, and trigger mechanisms of episodic seep events are not well constrained. It is generally found that free hydrocarbon gas entering the local gas hydrate stability field in marine sediments is sequestered in gas hydrates. In this manner, gas hydrates can act as a buffer for carbon transport from the sediment into the ocean. However, the efficiency of gas hydrate-bearing sediments for retaining hydrocarbons may be corrupted: Hypothesized mechanisms include critical gas/fluid pressures beneath gas hydrate-bearing sediments, implying that these are susceptible to mechanical failure and subsequent gas release. Although gas hydrates often occur in seismically active regions, e.g., subduction zones, the role of earthquakes as potential triggers of hydrocarbon transport through gas hydrate-bearing sediments has hardly been explored. Based on a recent publication (Fischer et al., 2013), we present geochemical and transport/reaction-modelling data suggesting a substantial increase in upward gas flux and hydrocarbon emission into the water column following a major earthquake that occurred near the study sites in 1945. Calculating the formation time of authigenic barite enrichments identified in two sediment cores obtained from an anticlinal structure called "Nascent Ridge", we find they formed 38-91 years before sampling, which corresponds well to the time elapsed since the earthquake (62 years). Furthermore, applying a numerical model, we show that the local sulfate/methane transition zone shifted upward by several meters due to the increased methane flux and simulated sulfate profiles very closely match measured ones in a comparable time frame of 50-70 years. We thus propose a causal relation between the earthquake and the amplified gas flux and present reflection seismic data supporting our hypothesis that co-seismic ground shaking induced mechanical fracturing of gas hydrate-bearing sediments creating pathways for free gas to migrate from a shallow reservoir within the gas hydrate stability zone into the water column. Our results imply that free hydrocarbon gas trapped beneath a local gas hydrate seal was mobilized through earthquake-induced mechanical failure and in that way circumvented carbon sequestration within the sediment. These findings lead to conclude that hydrocarbon seepage triggered by earthquakes can play a role for carbon budgets at other seismically active continental margins. The newly identified process presented in our study is conceivable to help interpret data from similar sites. Reference: Fischer, D., Mogollon, J.M., Strasser, M., Pape, T., Bohrmann, G., Fekete, N., Spieß, V. and Kasten, S., 2013. Subduction zone earthquake as potential trigger of submarine hydrocarbon seepage. Nature Geoscience 6: 647-651.

Analysis of dark albedo features on a southern polar dune field of Mars.

PubMed

Horváth, András; Kereszturi, Akos; Bérczi, Szaniszló; Sik, András; Pócs, Tamás; Gánti, Tibor; Szathmáry, Eörs

2009-01-01

We observed 20-200 m sized low-albedo seepage-like streaks and their annual change on defrosting polar dunes in the southern hemisphere of Mars, based on the Mars Orbiter Camera (MOC), High Resolution Stereo Camera (HRSC), and High Resolution Imaging Science Experiment (HiRISE) images. The structures originate from dark spots and can be described as elongated or flowlike and, at places, branching streaks. They frequently have another spotlike structure at their end. Their overall appearance and the correlation between their morphometric parameters suggest that some material is transported downward from the spots and accumulates at the bottom of the dune's slopes. Here, we present possible scenarios for the origin of such streaks, including dry avalanche, liquid CO(2), liquid H(2)O, and gas-phase CO(2). Based on their morphology and the currently known surface conditions of Mars, no model interprets the streaks satisfactorily. The best interpretation of only the morphology and morphometric characteristics is only given by the model that implies some liquid water. The latest HiRISE images are also promising and suggest liquid flow. We suggest, with better knowledge of sub-ice temperatures that result from extended polar solar insolation and the heat insulator capacity of water vapor and water ice, future models and measurements may show that ephemeral water could appear and flow under the surface ice layer on the dunes today.

Methane Seepage on Mars: Where to Look and Why.

PubMed

Oehler, Dorothy Z; Etiope, Giuseppe

2017-12-01

Methane on Mars is a topic of special interest because of its potential association with microbial life. The variable detections of methane by the Curiosity rover, orbiters, and terrestrial telescopes, coupled with methane's short lifetime in the martian atmosphere, may imply an active gas source in the planet's subsurface, with migration and surface emission processes similar to those known on Earth as "gas seepage." Here, we review the variety of subsurface processes that could result in methane seepage on Mars. Such methane could originate from abiotic chemical reactions, thermogenic alteration of abiotic or biotic organic matter, and ancient or extant microbial metabolism. These processes can occur over a wide range of temperatures, in both sedimentary and igneous rocks, and together they enhance the possibility that significant amounts of methane could have formed on early Mars. Methane seepage to the surface would occur preferentially along faults and fractures, through focused macro-seeps and/or diffuse microseepage exhalations. Our work highlights the types of features on Mars that could be associated with methane release, including mud-volcano-like mounds in Acidalia or Utopia; proposed ancient springs in Gusev Crater, Arabia Terra, and Valles Marineris; and rims of large impact craters. These could have been locations of past macro-seeps and may still emit methane today. Microseepage could occur through faults along the dichotomy or fractures such as those at Nili Fossae, Cerberus Fossae, the Argyre impact, and those produced in serpentinized rocks. Martian microseepage would be extremely difficult to detect remotely yet could constitute a significant gas source. We emphasize that the most definitive detection of methane seepage from different release candidates would be best provided by measurements performed in the ground or at the ground-atmosphere interface by landers or rovers and that the technology for such detection is currently available. Key Words: Mars-Methane-Seepage-Clathrate-Fischer-Tropsch-Serpentinization. Astrobiology 17, 1233-1264.

Single-Site Zeolite-Anchored Organoiridium Carbonyl Complexes: Characterization of Structure and Reactivity by Spectroscopy and Computational Chemistry

DOE PAGES

Martinez-Macias, Claudia; Chen, Mingyang; Dixon, David A.; ...

2015-07-03

We formed a family of HY zeolite-supported cationic organoiridium carbonyl complexes by reaction of Ir(CO) 2(acac) (acac=acetylacetonate) to form supported Ir(CO) 2 complexes, which were treated at 298K and 1atm with flowing gas-phase reactants, including C 2H 4, H 2, (CO)-C-12, (CO)-C-13, and D 2O. Mass spectrometry was used to identify effluent gases, and infrared and X-ray absorption spectroscopies were used to characterize the supported species, with the results bolstered by DFT calculations. The support is crystalline and presents a nearly uniform array of bonding sites for the iridium species, so these were characterized by a high degree of uniformity,more » which allowed a precise determination of the species involved in the replacement, for example, of one CO ligand of each Ir(CO) 2 complex with ethylene. The supported species include the following: Ir(CO) 2, Ir(CO)(C 2H 4) 2, Ir(CO)(C 2H 4), Ir(CO)(C 2H 5), and (tentatively) Ir(CO)(H). The data determine a reaction network involving all of these species.« less

Hydrological and Geological Features Contributing to a Seepage Event at Yucca Mountain

NASA Astrophysics Data System (ADS)

Fedors, R. W.; Smart, K. J.; Parrott, J. D.

2006-05-01

The occurrence of an unusual seepage event in the Exploratory Studies Facility (ESF) tunnel at Yucca Mountain (YM) in 2005 provides an opportunity to further understand the hydrological system associated with flow in fractured rocks and seepage into tunnels. Understanding the contributing factors for this seepage occurrence in the ventilated tunnel will assist U.S. Nuclear Regulatory Commission in its assessment of Department of Energy flow models. The seepage event begin in the later portion of an El Nino winter (February 2005) predominantly along a 40-m [130-ft] section of the south ramp of the ESF tunnel. The stratigraphic section at this location is comprised of a portion of the Tiva Canyon Tuff, which is a rhyolitic ignimbrite. The effect of El Nino conditions in the semi-arid climate of southern Nevada near YM is greatly increased winter precipitation. Based on the ~50 years of record at a nearby meteorological station, the winter of 2004-2005 was the wettest winter on record. The previous largest winter precipitation amounts were recorded in the El Nino years of 1992-1993 and 1997-1998. During the 1997 El Nino year, a monitored set of boreholes in nearby Pagany Wash indicated that a saturated front traversed the entire Tiva Canyon Tuff section during a single event (Le Cain and Kurmack, 2002, USGS Water Resources Investigations Report 02-4035). It is unclear if the fracture system in the south ramp location was saturated in the February 2005 event; no data were available to estimate the saturated state of the fracture system. With heavy precipitation occurring throughout the winter, however, the matrix and fracture systems were likely primed (i.e., saturation levels were likely significantly higher than normal) for a significant percolation event. Ponding caused by focusing of runoff at the ground surface above seepage location in the south ramp of the ESF tunnel likely did not occur based on topographical and catchment considerations (no significant depressions or gullies). Analyses of the geological characteristics associated with the seepage location suggest the contributing factors that constrained seepage to this particular portion of the tunnel include (i) distance to the surface (i.e., ~60 m [200 ft]), (ii) gently dipping strata with distinct lithological contacts that may have laterally diverted water, (iii) faults and fractures, and (iv) downslope capping by rock units with different hydrological characteristics. This is an independent product of the CNWRA and does not necessarily reflect the views of regulatory positions of the NRC. The NRC staff views expressed herein are preliminary and do not constitute a final judgment or determination of the matters addressed or of the acceptability of a license application for a geologic repository at Yucca Mountain.

Character of Submarine Groundwater Discharge (SGD) at the Coast of Mallorca Island

NASA Astrophysics Data System (ADS)

Coffey, R.; Bokuniewicz, H. J.; Basterretxea, G.; Tovar Sánchez, A.

2007-12-01

Preliminary results of geochemical tracers indicated that submarine groundwater discharge (SGD) is prevalent around the Mallorca coast, Spain; SGD would be an important source of trace metals and phosphorus to the coastal ocean. During September 2006, vented benthic chambers (a.k.a. seepage meters) were used at four diverse sites along the coast (Es Caragol, Porto Colom, Santa Ponça and Sóller) to directly measure SGD in order to investigate the characteristics of SGD. Mallorca is an example of a (Miocene) carbonate platform. The site at Sóller on the northeast coast is located on a wide stretch of beach in an embayment surrounded by part of the high relief of the Tramuntana Range; the other three sites were in areas of relatively low relief. The average rate of groundwater seepage at the four sites ranged from 3 to 19 cm d-1, being highest at Es Caragol, a wide embayment on the southern coast of Mallorca. All sites were characterized by an irregular, spatial distribution of seepage which was dominated by low values, less than 15 cm d-1 in most locations, but punctuated by high values (up to 65 cm d-1) in discrete locations. This characteristic was best represented by the observations at Sóller, where one device documented a consistently higher SGD, averaging 52 cm d-1, while the rest of the study area had an average SGD of 6 cm d-1. Such an irregular distribution would be expected to characterize fractured rock or karstic aquifers. There was little or no tidal modulation of the SGD which suggested to us that the driving forces adjusted, for the most part, to the tidal elevations in open water. In addition, the water seeping across the sediment-water interface showed little or no dilution from the ambient, open-water salinity, in fact, in one case, the salinity of the SGD was greater than ambient sea water. SGD at these locations appeared to be dominated by the recirculation of sea water through the aquifer, driven by oceanic processes. This work was supported by the Balearic Island Government (Govern de les Illes Balears, Econom Hisen I Innov; Núm: 8171/2006: 6014/2007).

Study of Movement and Seepage Along Levees Using DINSAR and the Airborne UAVSAR Instrument

NASA Technical Reports Server (NTRS)

Jones, Cathleen E.; Bawden, Gerald; Deverel, Steven; Dudas, Joel; Hensley, Scott

2012-01-01

We have studied the utility of high resolution SAR (synthetic aperture radar) for levee monitoring using UAVSAR (Uninhabited Aerial Vehicle Synthetic Aperture Radar) data collected along the dikes and levees in California's Sacramento-San Joaquin Delta and along the lower Mississippi River. Our study has focused on detecting and tracking changes that are indicative of potential problem spots, namely deformation of the levees, subsidence along the levee toe, and seepage through the levees, making use of polarimetric and interferometric SAR techniques. Here was present some results of those studies, which show that high resolution, low noise SAR imaging could supplement more traditional ground-based monitoring methods by providing early indicators of seepage and deformation.

Lake Okeechobee seepage monitoring network

USGS Publications Warehouse

McKenzie, Donald J.

1973-01-01

This report summarizes the data collected at the five original monitoring sites along the south shore of Lake Okeechobee from January 29, 1970 to June 28, 1972. In order to use the hydrographs in this report to full advantage, they should be studied in conjunction with Meyer's graphs and text (1971). During steady-state conditions, water seeps from the lake through the filtercake and through the aquifers beneath the dike. At those sites where the filtercake is missing, or has about the same permeability as the aquifers, the seepage from the lake is about equivalent to the flow through the aquifers. Present data are insufficient to determine whether or not filtercake buildup has reduced seepage. No appreciable change in drainage occurred during the observed period.

Attenuation of dissolved metals in neutral mine drainage in the Zambian Copperbelt.

PubMed

Sracek, Ondra; Filip, Jan; Mihaljevič, Martin; Kříbek, Bohdan; Majer, Vladimír; Veselovský, František

2011-01-01

Behaviour of metals like Cu and Co was studied in nearly neutral (pH ≥ 6.4) mine drainage seepage in a stream downgradient of a tailing dam at Chambishi site in the Copperbelt of Zambia. They are attenuated by precipitation of ferruginous ochres that incorporate significant quantities of metals. Using chemical analysis, X-ray powder diffraction and Mössbauer spectroscopy, we show that the ochres are composed mostly of amorphous ferric hydroxide. Close to the seepage face, the total Fe content of ochres increases due to precipitation of amorphous ferric hydroxide, but total Fe in sediment decreases further downstream. The stream then flows through wetland (dambo) where the remaining fraction of metals is removed. During rainy periods, increased flow rate may result in re-suspension of ochres, increasing thus the mobility of metals. Major ions like sulphate are conservative at the start of the dry period (May), but gypsum may probably precipitate later at the end of the dry period. Sequential extractions of bulk sediments indicate that Mn behaves differently to Fe, with a trend of increasing Mn with distance from the tailing dam. There is much more Fe than Mn in residual (Aqua Regia) fraction, indicating that amorphous ferric hydroxides are transformed to more crystalline phases deeper in sediment. Environmental impact of mine drainage is relatively limited due to its neutral character.

Remote thermal infrared imaging as an identifier for groundwater dependent ecosystems of esker aquifers in Northern boreal region

NASA Astrophysics Data System (ADS)

Rossi, Pekka M.; Korkka-Niemi, Kirsti; Rautio, Anne; Jyväsjärvi, Jussi; Isokangas, Elina; Jaros, Anna; Kløve, Bjørn

2017-04-01

Remote thermal infrared imaging (TIR) is a rapid and feasible method to map groundwater seepages in different surroundings. As the thermal cameras are more available, TIR could be more used as a mapping and management tool for groundwater dependent ecosystems (GDEs). This study demonstrates how TIR was used in a boreal esker aquifer where springs, peatlands, lakes and stream ecosystems are present. Two esker aquifer areas in Finland were mapped with a two-day helicopter based thermal imaging campaign. Imaging included 67 lakes, a bog mire, three headwater streams and a peatland forestry area with ditches. The results of the TIR indicated that many of the lakes had shore seepage points or longer shoreline seepage areas of groundwater. When compared to a previous groundwater dependence study with stable water isotopes of the same lakes, a one-way analysis of covariate (ANCOVA) indicated a correlation between the groundwater dependence and the seepages of a selected lake. The studied mire bog had unmapped springs 0.5 - 1 km beyond the current groundwater protection area of the esker. Also the temperature of the headwater streams referred to a groundwater connection beyond protection limits. The forestry ditches of the discharge zone had a complex temperature pattern due to groundwater seepage. With carefully planned imaging route the TIR resulted to be highly informative and an efficient method to study different GDEs on varying surroundings. The study results emphasize the use of TIR as a standard tool in GDE management planning of boreal eskers comparable to the vegetation based mapping.

Evaluating long-term patterns of decreasing groundwater discharge through a lake-bottom permeable reactive barrier.

PubMed

McCobb, Timothy D; Briggs, Martin A; LeBlanc, Denis R; Day-Lewis, Frederick D; Johnson, Carole D

2018-05-18

Identifying and quantifying groundwater exchange is critical when considering contaminant fate and transport at the groundwater/surface-water interface. In this paper, areally distributed temperature and point seepage measurements are used to efficiently assess spatial and temporal groundwater discharge patterns through a glacial-kettle lakebed area containing a zero-valent iron permeable reactive barrier (PRB). Concern was that the PRB was becoming less permeable with time owing to biogeochemical processes within the PRB. Patterns of groundwater discharge over an 8-year period were examined using fiber-optic distributed temperature sensing (FO-DTS) and snapshot-in-time point measurements of temperature. The resulting thermal maps show complex and uneven distributions of temperatures across the lakebed and highlight zones of rapid seepage near the shoreline and along the outer boundaries of the PRB. Repeated thermal mapping indicates an increase in lakebed temperatures over time at periods of similar stage and surface-water temperature. Flux rates in six seepage meters permanently installed on the lakebed in the PRB area decreased on average by 0.021 md -1 (or about 4.5 percent) annually between 2004 and 2015. Modeling of diurnal temperature signals from shallow vertical profiles yielded mean flux values ranging from 0.39 to 1.15 md -1 , with stronger fluxes generally related to colder lakebed temperatures. The combination of an increase in lakebed temperatures, declines in direct seepage, and observations of increased cementation of the lakebed surface provide in situ evidence that the permeability of the PRB is declining. The presence of temporally persistent rapid seepage zones is also discussed. Published by Elsevier Ltd.

Quantity and quality of groundwater discharge in a hypersaline lake environment

USGS Publications Warehouse

Anderson, R.B.; Naftz, D.L.; Day-Lewis, F. D.; Henderson, R.D.; Rosenberry, D.O.; Stolp, B.J.; Jewell, P.

2014-01-01

Geophysical and geochemical surveys were conducted to understand groundwater discharge to Great Salt Lake (GSL) and assess the potential significance of groundwater discharge as a source of selenium (Se). Continuous resistivity profiling (CRP) focusing below the sediment/water interface and fiber-optic distributed temperature sensing (FO-DTS) surveys were conducted along the south shore of GSL. FO-DTS surveys identified persistent cold-water temperature anomalies at 10 separate locations. Seepage measurements were conducted at 17 sites (mean seepage rate = 0.8 cm/day). High resistivity anomalies identified by the CRP survey were likely a mirabilite (Na2SO4·10H2O) salt layer acting as a semi-confining layer for the shallow groundwater below the south shore of the lake. Positive seepage rates measured along the near-shore areas of GSL indicate that a ∼1-m thick oolitic sand overlying the mirabilite layer is likely acting as a shallow, unconfined aquifer. Using the average seepage rate of 0.8 cm/day over an area of 1.6 km2, an annual Se mass loading to GSL of 23.5 kg was estimated. Determination of R/Ra values (calculated 3He/4He ratio over the present-day atmospheric 3He/4He ratio) 34S and δ18O isotopic values in samples of dissolved sulfate from the shallow groundwater below the mirabilite are almost identical to the isotopic signature of the mirabilite core material. The saturation index calculated for groundwater samples using PHREEQC indicates the water is at equilibrium with mirabilite. Water samples collected from GSL immediately off shore contained Se concentrations that were 3–4 times higher than other sampling sites >25 km offshore from the study site and may be originating from less saline groundwater seeps mixing with the more saline water from GSL. Additional evidence for mixing with near shore seeps is found in the δD and δ18O isotopic values and Br:Cl ratios. Geochemical modeling for a water sample collected in the vicinity of the study area indicates that under chemically reducing conditions, arsenic- (As) bearing minerals could dissolve while Se-bearing minerals will likely precipitate out of solution, possibly explaining why the shallow groundwater below and within the mirabilite salt layer contains low concentrations of Se (0.9–2.3 μg/L).

An In-Well Point Velocity Probe for the rapid determination of groundwater velocity at the centimeter-scale

NASA Astrophysics Data System (ADS)

Osorno, Trevor C.; Devlin, J. F.; Firdous, Rubina

2018-02-01

The In-Well Point Velocity Probe (IWPVP) is a novel device designed for obtaining rapid, initial measurements of groundwater velocity at the centimeter-scale using a standard monitoring well to access the subsurface. IWPVP measurements of groundwater speed are quantified on the basis of a mini-tracer test that is conducted within the body of the probe. Information regarding horizontal flow directions is obtained from differential responses at detectors placed in the four quadrants of the probe. The viability of the IWPVP design was confirmed by (1) numerical modeling that accounted for laminar flow in the porous medium outside the well and turbulent flow inside the well (and probe), and (2) a series of laboratory tank experiments in which the probe was calibrated to quantify seepage rates in a medium-grain sand. Laboratory tests were completed in less than 20 min in all cases, when seepage velocity was between 50 and 400 cm/day. The magnitude of the groundwater velocity was determined with a precision of ±7% on average, and accuracy of ±11% for seepage velocities up to 400 cm/day. The flow direction was determined within ±15°. The IWPVP appears to be a viable tool for rapid assessment of groundwater velocity.

Toxicity of Water Samples Collected in the Vicinity of F and H Seepage Basin 1990-1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

Specht, W.L.; Bowers, B.

1996-09-01

Water and contaminants from the F- and H-Area Seepage Basins outcrop as shallow groundwater seeps down gradient from the basins. In 1990, 1991, 1993, 1994, and 1995, toxicity tests were performed on water collected from a number of these seeps, as well as from several locations in Fourmile Branch and several uncontaminated reference locations.

Unsaturated flow and transport through a fault embedded in fractured welded tuff

USGS Publications Warehouse

Salve, Rohit; Liu, Hui‐Hai; Cook, Paul; Czarnomski, Atlantis; Hu, Qinhong; Hudson, David

2004-01-01

To evaluate the importance of matrix diffusion as a mechanism for retarding radionuclide transport in the vicinity of a fault located in unsaturated fractured rock, we carried out an in situ field experiment in the Exploratory Studies Facility at Yucca Mountain, Nevada. This experiment involved the release of ∼82,000 L of water over a period of 17 months directly into a near‐vertical fault under both constant positive head (at ∼0.04 m) and decreasing fluxes. A mix of conservative tracers (pentafluorobenzoic acid (PFBA) and bromide (applied in the form of lithium bromide)) was released along the fault over a period of 9 days, 7 months after the start of water release along the fault. As water was released into the fault, seepage rates were monitored in a large cavity excavated below the test bed. After the release of tracers, seepage water was continuously collected from three locations and analyzed for the injected tracers. Observations of bromide concentrations in seepage water during the early stages of the experiment and bromide and PFBA concentrations in the seepage water indicate the significant effects of matrix diffusion on transport through a fault embedded in fractured, welded rock.

Methane seepage intensities traced by biomarker patterns in authigenic carbonates from the South China Sea

NASA Astrophysics Data System (ADS)

Guan, H.; Feng, D.

2015-12-01

Authigenic carbonate rocks from an active seep (Site F) at 1120 m water depth of the South China Sea (SCS) were studied using mineralogical and lipid biomarker analyses. Carbonate mineral compositions, in specific samples, were predominantly aragonite, high-Mg calcite (HMC), or a mixture of both. Abundant 13C-depleted lipid biomarkers (various isoprenoids) diagnostic for archaea provide evidence that anaerobic oxidation of methane (AOM) mediated by anaerobic methane oxidizing archaea (ANME) and their bacterial partners is the major process leading to formation of the carbonates. Nearly a pure suite of AOM biomarkers was preserved in aragonitic carbonate in which predominant consortia were most likely ANME-2/Desulfosarcina & Desulfococcus (DSS) assemblages and a mixture of ANME-2/DSS and ANME-1/DSS consortia in the mixed mineral sample, the predominant consortia are in good accordance with the point that the relative higher methane seepage intensity favors the precipitation of aragonite over HMC. In contrast, the completely different biomarker patterns in HMC sample were mainly composed terrestrial organic matter and marine Thaumarchaea, which most likely originally within sediments accompanied with high organic matter input and low methane supply. This environment is known to be favored for archaea of ANME-1 and precipitation of HMC. High concentrations of 13C-depleted hopanoids, including diplopterol, hopanoic acids and hopanols were observed in the aragonite sample that may be sourced by the intermittent presence of oxic conditions in an overall anoxic condition, which was possibly induced by changing seepage intensities.

Synthesis and Electrochemical Properties Characterization of SnO2-coated LiNi1/3Co1/3Mn1/3O2 Cathode Material for Lithium Ion Batteries

DTIC Science & Technology

2009-01-01

Synthesis and electrochemical properties characterization of SnO2-coated LiNi1/3Co1/3Mn1/3O2 cathode material for lithium ion batteries Ping Yang...electrochemical properties characterization of SnO2-coated LiNi1/3Co1/3Mn1/3O2 cathode material for lithium ion batteries 5a. CONTRACT NUMBER 5b. GRANT NUMBER...electrochemical reaction. References 1. N Yabuuchi, T Ohzuku, “Novel lithium insertion material of LiCo1/3Ni1/3Mn1/3O2 for advanced lithium - ion batteries ”, J

Seepage tests on No Name Creek, Colville Indian Reservation, Washington, May 12-13, 1977

USGS Publications Warehouse

MacNish, Robert D.

1977-01-01

To gain information for a water-management situation, a seepage test was performed on May 12-13, 1977, on a reach of No Name Creek on the Colville Indian Reservation in north-central Washington. On May 13, injection of a concentrated brine at the head of the test reach permitted chloride-concentration data to be combined with the discharge measurements made to define the pattern of gain and loss along the reach. Equations describing discharge and chloride mass balance were used to determine this pattern of gain and loss. The seepage tests showed that the streamflow gain of at least 0.58 cfs from springflow contributions was offset by losses of at least 0.59 cfs over the same reach. (Woodard-USGS)

Unsteady free surface flow in porous media: One-dimensional model equations including vertical effects and seepage face

NASA Astrophysics Data System (ADS)

Di Nucci, Carmine

2018-05-01

This note examines the two-dimensional unsteady isothermal free surface flow of an incompressible fluid in a non-deformable, homogeneous, isotropic, and saturated porous medium (with zero recharge and neglecting capillary effects). Coupling a Boussinesq-type model for nonlinear water waves with Darcy's law, the two-dimensional flow problem is solved using one-dimensional model equations including vertical effects and seepage face. In order to take into account the seepage face development, the system equations (given by the continuity and momentum equations) are completed by an integral relation (deduced from the Cauchy theorem). After testing the model against data sets available in the literature, some numerical simulations, concerning the unsteady flow through a rectangular dam (with an impermeable horizontal bottom), are presented and discussed.

Analysis of flow near a dug well in an unconfined aquifer

NASA Astrophysics Data System (ADS)

Sridharan, K.; Sathyanarayana, D.; Reddy, A. Siva

1990-11-01

A numerical analysis of flow to a dug well in an unconfined aquifer is made, taking into account well storage, elastic storage release, gravity drainage, anisotropy, partial penetration, vertical flow and seepage surface at the well face, and treating the water table in the aquifer and water level in the well as unknown boundaries. The pumped discharge is maintained constant. The solution is obtained by a two-level iterative scheme. The effects of governing parameters on the drawdown, development of seepage surface and contribution from aquifer flow to the total discharge are discussed. The degree of anisotropy and partial penetration are found to be the parameters which affect the flow characteristics most significantly. The effect of anisotropy on the development of seepage surface is very pronounced.

Field Testing of an In-well Point Velocity Probe for the Rapid Characterization of Groundwater Velocity

NASA Astrophysics Data System (ADS)

Osorno, T.; Devlin, J. F.

2017-12-01

Reliable estimates of groundwater velocity is essential in order to best implement in-situ monitoring and remediation technologies. The In-well Point Velocity Probe (IWPVP) is an inexpensive, reusable tool developed for rapid measurement of groundwater velocity at the centimeter-scale in monitoring wells. IWPVP measurements of groundwater speed are based on a small-scale tracer test conducted as ambient groundwater passes through the well screen and the body of the probe. Horizontal flow direction can be determined from the difference in tracer mass passing detectors placed in four funnel-and-channel pathways through the probe, arranged in a cross pattern. The design viability of the IWPVP was confirmed using a two-dimensional numerical model in Comsol Multiphysics, followed by a series of laboratory tank experiments in which IWPVP measurements were calibrated to quantify seepage velocities in both fine and medium sand. Lab results showed that the IWPVP was capable of measuring the seepage velocity in less than 20 minutes per test, when the seepage velocity was in the range of 0.5 to 4.0 m/d. Further, the IWPVP estimated the groundwater speed with a precision of ± 7%, and an accuracy of ± 14%, on average. The horizontal flow direction was determined with an accuracy of ± 15°, on average. Recently, a pilot field test of the IWPVP was conducted in the Borden aquifer, C.F.B. Borden, Ontario, Canada. A total of approximately 44 IWPVP tests were conducted within two 2-inch groundwater monitoring wells comprising a 5 ft. section of #8 commercial well screen. Again, all tests were completed in under 20 minutes. The velocities estimated from IWPVP data were compared to 21 Point Velocity Probe (PVP) tests, as well as Darcy-based estimates of groundwater velocity. Preliminary data analysis shows strong agreement between the IWPVP and PVP estimates of groundwater velocity. Further, both the IWPVP and PVP estimates of groundwater velocity appear to be reasonable when compared to a Darcy-based estimate of groundwater velocity, using the range of hydraulic conductivity values previously reported at the Borden aquifer. Based on these promising results, the IWPVP appears to be a viable tool for the determination of groundwater velocity at the centimeter-scale.

Preliminary interpretation of thermal data from the Nevada Test Site

USGS Publications Warehouse

Sass, John Harvey; Lachenbruch, Arthur H.

1982-01-01

Analysis of data from 60 wells in and around the Nevada Test Site, including 16 in the Yucca Mountain area, indicates a thermal regime characterized by large vertical and lateral gradients in heat flow. Estimates of heat flow indicate considerable variation on both regional and local scales. The variations are attributable primarily to hydrologic processes involving interbasin flow with a vertical component of (seepage) velocity (volume flux) of a few mm/yr. Apart from indicating a general downward movement of water at a few mm/yr, the results from Yucca Mountain are as yet inconclusive.

Massachusetts Lowell low speed wind tunnel (LSWT) test section

NASA Astrophysics Data System (ADS)

Anderson, Erik William

The alumina and hybrid alumina-silica FT catalyst were prepared by one-step solgel/oil-drop methods using metal-nitrate-solutions (method-I), and nanoparticle-metaloxides (method-2). The nanoparticle-metal-oxides did not participate in solubility equilibria in contrast to metal nitrate in method-1 causing no metal ion seepage; therefore, method-2 yields higher XRF metal loading efficiency than method-1. The thermal analysis confirmed that the metal loading by method-1 and method-2 involved two different pathways. Method-1 involves solubility equilibria in the conversion of metal-nitrate to metal- hydroxide and finally to metal-oxide, while in method-2 nanoparticle-metal-oxide remained intact during sol-gel-oil-drop and calcination steps. The alumina supported catalysts were dominated by gamma-alumina PXRD peaks in alumina catalysts while amorphous alumino-silicate phase was the bulk of hybrid alumina-silica catalysts. The presence of cobalt oxides (CoO, Co3O4) and iron oxides (FeO, Fe2O3) phases are confirmed in the catalysts prepared by method-1 and method-2. The PXRD analysis indicated weak peak intensities in catalysts with 5 wt. % total metal loading. PXRD pattern confirmed alloy formation in the bimetallic catalysts (CoFe2O4) on alumina support phase gamma-A12 O3. The surface area and pore diameter of hybrid alumina-silica granules (301 - 372 m2/g and 7.3 nm) showed better values than the alumina granules (251 - 256 m2/g and 6.5 nm). The support pore diameter of both types of granules is within the mesoporous range (1 - 50 nm). The morphology of all the catalysts is preserved upon metal loading and heat treatments. The surface characteristics of the sol-gel-oil-drop method prepared catalysts indicate there was no significant pore blockage of the support below 10 wt % total metal loading. The CO conversion of the FT catalysts was measured to screen catalytic active metals and determine the optimum temperatures of the FT reaction for the alumina catalysts. The alumina FT catalysts showed an optimum reaction temperature of 250 °C. Hydrocarbon production and CO conversion of alumina and hybrid alumina-silica FT catalysts were investigated. Among monometallic alumina catalysts, Co(5%) showed a higher CO conversion. The incorporation of Fe to Co increased CO conversion and hydrocarbon production. Increased Fe content in the bimetallic catalysts prepared by combined method-1&2, decreased CO conversion and hydrocarbon production, and increased CO 2 production. The bimetallic nano-Co(2.5%)nano-Fe(2.5%) prepared by method-2 alone showed higher CO conversion comparable to the Co(4%)nano-Fe(l %). Hybrid alumina-silica FT catalysts showed a higher CO conversion than the alumina FT catalysts due to better surface characteristics. The monometallic catalysts showed higher selectivity to C1-C4 hydrocarbon than bimetallic. The bimetallic alumina FT catalysts prepared by method-2 showed slightly higher C5+ selectivity compared to the higher Co catalysts prepared by combined method- I &2. The Ru promotion showed a significant effect on the CO conversion and 11 product distribution of the monometallic catalysts. There was no significant effect on the CO conversion on the (Co-Fe) bimetallic catalysts, but hydrocarbon production slightly increased when promoted by 0.5 wt.% Ru.

Summary of Seepage Investigations in the Yakima River Basin, Washington

USGS Publications Warehouse

Magirl, C.S.; Julich, R.J.; Welch, W.B.; Curran, C.R.; Mastin, M.C.; Vaccaro, J.J.

2009-01-01

Discharge data collected by the U.S. Geological Survey, Washington State Department of Ecology, and Yakama Nation for seepage investigations in the Yakima River basin are made available as downloadable Microsoft Excel files. These data were collected for more than a century at various times for several different studies and are now available in one location to facilitate future analysis by interested parties.

Paleozoic Hydrocarbon-Seep Limestones

NASA Astrophysics Data System (ADS)

Peckmann, J.

2007-12-01

To date, five Paleozoic hydrocarbon-seep limestones have been recognized based on carbonate fabrics, associated fauna, and stable carbon isotopes. These are the Middle Devonian Hollard Mound from the Antiatlas of Morocco [1], Late Devonian limestone lenses with the dimerelloid brachiopod Dzieduszyckia from the Western Meseta of Morocco [2], Middle Mississippian limestones with the dimerelloid brachiopod Ibergirhynchia from the Harz Mountains of Germany [3], Early Pennsylvanian limestones from the Tantes Mound in the High Pyrenees of France [4], and Late Pennsylvanian limestone lenses from the Ganigobis Shale Member of southern Namibia [5]. Among these examples, the composition of seepage fluids varied substantially as inferred from delta C-13 values of early diagenetic carbonate phases. Delta C-13 values as low as -50 per mil from the Tantes Mound and -51 per mil from the Ganigobis limestones reveal seepage of biogenic methane, whereas values of -12 per mil from limestones with Dzieduszyckia associated with abundant pyrobitumen agree with oil seepage. Intermediate delta C-13 values of carbonate cements from the Hollard Mound and Ibergirhynchia deposits probably reflect seepage of thermogenic methane. It is presently very difficult to assess the faunal evolution at seeps in the Paleozoic based on the limited number of examples. Two of the known seeps were typified by extremely abundant rhynchonellide brachiopods of the superfamily Dimerelloidea. Bivalve mollusks and tubeworms were abundant at two of the known Paleozoic seep sites; one was dominated by bivalve mollusks (Hollard Mound, Middle Devonian), another was dominated by tubeworms (Ganigobis Shale Member, Late Pennsylvanian). The tubeworms from these two deposits are interpreted to represent vestimentiferan worms, based on studies of the taphonomy of modern vestimentiferans. However, this interpretation is in conflict with the estimated evolutionary age of vestimentiferans based on molecular clock methods, which suggest a maximal age of 126 million years for this group. 1. Peckmann et al. (1999) Facies 40, 281. 2. Peckmann et al. (2007) Palaios 22, 114. 3. Peckmann et al. (2001) Geology 29, 271. 4. Buggisch and Krumm (2005) Facies 51, 566. 5. Himmler et al. (submitted) Palaeogeogr., Palaeoclimatol., Palaeoecol.

Synthesis and redox properties of fac-BrRe(CO)3[1,2-(PPh2)2-closo-1,2-C2B10H10]: The first structurally characterized rhenium carbonyl containing a carboranyl-based diphosphine ligand

NASA Astrophysics Data System (ADS)

Lin, Chen-Hao; Nesterov, Vladimir N.; Richmond, Michael G.

2018-03-01

The diphosphine 1,2-(PPh2)2-closo-1,2-C2B10H10 reacts with BrRe(CO)5 and fac-BrRe(CO)3(THF)2 to give fac-BrRe(CO)3[1,2-(PPh2)2-closo-1,2-C2B10H10] (1) in high yields (>80%). Compound 1 is the first structurally characterized rhenium carbonyl that contains an ancillary carborane-based diphosphine ligand. 1 has been characterized in solution by IR and NMR spectroscopies (1H and 31P), and the solid-state structure has been determined by X-ray diffraction analysis. The electrochemical properties of 1 have been investigated by cyclic voltammetry, and the composition of the DFT-computed HOMO and LUMO levels are discussed relative to the electrochemical data. The thermodynamics for the formation of 1 from the rhenium precursors BrRe(CO)5 and fac-BrRe(CO)3(THF)2 have been evaluated by DFT calculations.

North-south comparison of springtime dark slope structures on Mars, and the possibility of liquid water

NASA Astrophysics Data System (ADS)

Kereszturi, A.; Berczi, Sz.; Horvath, A.; Ganti, T.; Kuti, A.; Pocs, T.; Sik, A.; Szathmary, E.

2008-09-01

Introduction Various polar seasonal surface albedo structures were analyzed by several authors in the past [1, 2, 3, 4, 5, 6, 7, 8, 8, 9], partly in connection with the possibility of liquid water. In our previous work [10] we identified two groups of slope streaks emanating form Dark Dune Spots of polar dunes, which grow in size and number during spring with the advancement of the season. The diffuse shaped group appears earlier and formed probably by CO2 geysers [8]. The confine shaped group appears in a later seasonal phase, when the temperature is higher. They are probably connected with exposed water-ice on the surface, and may formed by the seepage of undercooled interfacial water on microscopic scale [11]. Methods For the analysis of northern slope structures we used MGS MOC, MRO HiRISE images, and MRG TES data [12] using the "vanilla" software. Temperature data show annual trend, and were derived for daytime. Note that the surface temperature values have spatial resolution around 3 km, and they can be taken only as a rough approach of the surface temperature of the whole dune complex, and not different parts of it. Discussion The target area of the analysis was (84N 233E) in the northern circumpolar sand sea, with 300-500 m diameter overlapping dunes. We searched for springtime confined and elongated dark slope streaks, similar to those, which we observed at south. Basic similarities between northern and southern structures are: 1. streaks always emanate from Dark Dune Spots in downward direction, 2. streaks are present in local spring, when the temperature is above the CO2 buffered level, suggesting there are parts of the surface without CO2 ice, where possibly H2O ice is exposed (Fig. 1.), 4. the streaks show branching pattern (Fig. 2.). Basic differences between the northern and southern structures: 1. at north there is a dark annulus around the Dark Dune Spots, which is absent at south, 2. there are fewer and fainter diffuse streaks of gas jet activity at north, 3. there are fewer pond-like accumulated structures at the streaks' end at north. Conclusion The branching dark pattern suggests the movement of liquid-like material, while the temperature data suggest these dark features are formed possibly in connection with H2O ice. The moving material may be composed of dry or adsorbed water [13] lubricated grains also. Based on the probably presence of waterice, and the model of adsorbed water, northern DDSslope structures may be the result of seepage by interfacial water around solar heated dune grains, as well as the southern ones. This situation may have astrobiological consequences [14] too. Acknowledgment This work was supported by the ESA ECS-project No. 98004 and the Pro Renovanda Cultura Hungariae Foundation. References [1] Kieffer H. et al. (2000) 2nd Conf. Mars Pol. Sci. 93., [2] Ness & Orme JBIS (2002) 55, 85-109. [3] Piqueux S. et al. (2003) JGR 108, 5084. [4] Christensen et al. (2005) AGU, Fall Meeting #P23C- 04. [5] Malin M.C. et al., (1998) Science 279, 1681-1685. [6] Malin M.C. and Edgett K.S. (2000) XXXIth LPSC #1056. [7] Zuber T.M. (2003) Science 302, 1694-1695. [8] Kieffer H.H. et al.

Seismic and structural characterization of the fluid bypass system using 3D and partial stack seismic from passive margin: inside the plumbing system.

NASA Astrophysics Data System (ADS)

Iacopini, David; Maestrelli, Daniele; Jihad, Ali; Bond, Clare; Bonini, Marco

2017-04-01

In recent years enormous attention has been paid to the understanding of the process and mechanism controlling the gas seepage and more generally the fluid expulsion affecting the earth system from onshore to offshore environment. This is because of their demonstrated impact to our environment, climate change and during subsea drilling operation. Several example from active and paleo system has been so far characterized and proposed using subsurface exploration, geophysical and geochemical monitoring technology approaches with the aims to explore what trigger and drive the overpressure necessary maintain the fluid/gas/material expulsion and what are the structure that act as a gateway for gaseous fluid and unconsolidated rock. In this contribution we explore a series of fluid escape structure (ranging from seepage pipes to large blowout pipes structure of km length) using 3D and partial stack seismic data from two distinctive passive margin from the north sea (Loyal field, West Shetland) and the Equatorial Brazil (Ceara' Basin). We will focuses on the characterization of the plumbing system internal architecture and, for selected example, exploring the AVO response (using partial stack) of the internal fluid/unconsolidated rock. The detailed seismic mapping and seismic attributes analysis of the conduit system helped us to recover some detail from the signal response of the chimney internal structures. We observed: (1) small to medium seeps and pipes following structural or sedimentary discontinuities (2) large pipes (probably incipient mud volcanoes) and blowup structures propagating upward irrespective of pre-existing fault by hydraulic fracturing and assisted by the buoyancy of a fluidised and mobilised mud-hydrocarbon mixture. The reflector termination observed inside the main conduits, the distribution of stacked bright reflectors and the AVO analysis suggests an evolution of mechanisms (involving mixture of gas, fluid and probably mud) during pipe birth and development, cycling through classical fluid escape pipes evoking non-Darcy flow to Darcy flow exploiting surrounding permeable bodies (during low fluid recharge period). Limit and uncertainty of the seismic data imaging the internal structure are still controlled by illumination factor, the lateral and vertical resolution (Fresnel. Tuning thickness) and scattering/noise effect of seismic wave when they interact with the plumbing system.

Methane Seepage on Mars: Where to Look and Why

NASA Astrophysics Data System (ADS)

Oehler, Dorothy Z.; Etiope, Giuseppe

2017-12-01

Methane on Mars is a topic of special interest because of its potential association with microbial life. The variable detections of methane by the Curiosity rover, orbiters, and terrestrial telescopes, coupled with methane's short lifetime in the martian atmosphere, may imply an active gas source in the planet's subsurface, with migration and surface emission processes similar to those known on Earth as "gas seepage." Here, we review the variety of subsurface processes that could result in methane seepage on Mars. Such methane could originate from abiotic chemical reactions, thermogenic alteration of abiotic or biotic organic matter, and ancient or extant microbial metabolism. These processes can occur over a wide range of temperatures, in both sedimentary and igneous rocks, and together they enhance the possibility that significant amounts of methane could have formed on early Mars. Methane seepage to the surface would occur preferentially along faults and fractures, through focused macro-seeps and/or diffuse microseepage exhalations. Our work highlights the types of features on Mars that could be associated with methane release, including mud-volcano-like mounds in Acidalia or Utopia; proposed ancient springs in Gusev Crater, Arabia Terra, and Valles Marineris; and rims of large impact craters. These could have been locations of past macro-seeps and may still emit methane today. Microseepage could occur through faults along the dichotomy or fractures such as those at Nili Fossae, Cerberus Fossae, the Argyre impact, and those produced in serpentinized rocks. Martian microseepage would be extremely difficult to detect remotely yet could constitute a significant gas source. We emphasize that the most definitive detection of methane seepage from different release candidates would be best provided by measurements performed in the ground or at the ground-atmosphere interface by landers or rovers and that the technology for such detection is currently available.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rintoul, B.

Humble Oil and Refining Co. has developed a bottom-tension boom which successfully contained oil in 6 to 8-ft waves and 20-kn winds, against an imposed current of approx. 1-1/2 kn during a test program in the Santa Barbara Channel. In addition to oil swept up in the Coal Oil Point area near Santa Barbara, an area of natural oil seepage, the device has been used to sweep up popcorn--as many as fifty 3-cu-ft bags per test--purposely spilled in the channel for field test purposes. The boom was designed to operate in the vicinity of a continuous spill source, in heavymore » seas, and to remain in service for a long period of time. Humble says it is designed to survive in an environmental condition of 20-ft waves, 2-kn currents, and 60-kn winds, although claims are not made for effective containment under such severe circumstances. The boom may be towed by fishing-fleet vessels--one on each end of a bottom-tension tow cable--to sweep the sea, or it may be attached to anchors to provide a nt level technology.« less

Geological Carbon Sequestration: A New Approach for Near-Surface Assurance Monitoring

PubMed Central

Wielopolski, Lucian

2011-01-01

There are two distinct objectives in monitoring geological carbon sequestration (GCS): Deep monitoring of the reservoir’s integrity and plume movement and near-surface monitoring (NSM) to ensure public health and the safety of the environment. However, the minimum detection limits of the current instrumentation for NSM is too high for detecting weak signals that are embedded in the background levels of the natural variations, and the data obtained represents point measurements in space and time. A new approach for NSM, based on gamma-ray spectroscopy induced by inelastic neutron scatterings (INS), offers novel and unique characteristics providing the following: (1) High sensitivity with a reducible error of measurement and detection limits, and, (2) temporal- and spatial-integration of carbon in soil that results from underground CO2 seepage. Preliminary field results validated this approach showing carbon suppression of 14% in the first year and 7% in the second year. In addition the temporal behavior of the error propagation is presented and it is shown that for a signal at the level of the minimum detection level the error asymptotically approaches 47%. PMID:21556180

Role of the bottom sediments immediately beneath the lake water-groundwater interface in the transport and removal of cyanobacteria, cyanophage, and dissolved organic carbon during natural lake-bank filtration at a kettle pond subject to harmful algal blooms

NASA Astrophysics Data System (ADS)

Harvey, R. W.; Metge, D. W.; LeBlanc, D. R.; Underwood, J. C.; Aiken, G.; McCobb, T. D.; Jasperse, J.

2015-12-01

Bank filtration has proven to be a sustainable, cost-effective method of removing cyanobacteria and their harmful toxins from surface water during filtration through bottom and aquifer sediments. The biologically active layer of sediments immediately beneath the sediment-water interface (colmation layer) is believed to be particularly important in this process. An in situ experiment was conducted that involved assessing the transport behaviors of bromide (conservative tracer), Synechococcus sp. IU625 (cyanobacterium, 2.6 ± 0.2 µm), AS-1 (tailed cyanophages, 110 nm long), MS2 (coliphages, 26 nm diameter), and carboxylate-modified microspheres (1.7 µm diameter) introduced to the colmation layer using a bag-and-barrel (Lee-type) seepage meter. The constituents were monitored as they advected through the colmation layer and underlying aquifer sediments at Ashumet Pond in Cape Cod, MA, a mesotrophic kettle pond that recharges a portion of a sole-source, drinking water aquifer. Because the pond DOC includes the various cyanotoxins produced during harmful algal bloom senescence, the DOC and aforementioned colloids were tracked concomitantly. The tracer test constituents were monitored as they advected across the pond water-groundwater interface and through the underlying aquifer sediments under natural-gradient conditions past push-points samplers placed at ~30-cm intervals along a 1.2-m-long, diagonally downward flow path. More than 99% of the microspheres, IU625, MS2, AS-1, and ~42% of the pond DOC were removed in the colmation layer (upper 25 cm of poorly sorted bottom sediments) at two test locations characterized by dissimilar seepage rates (1.7 vs. 0.26 m d-1). Retention profiles in recovered core material indicated that >82% of the attached IU625 were in the top 3 cm of bottom sediments. The colmation layer was also responsible for rapid changes in the character of the DOC and was more effective (by 3 orders of magnitude) at removing microspheres than was the underlying 30-cm-long segment of sediment. A follow-up study conducted the following year at the same location demonstrated that removal of the top 5 cm of sediment resulted in a six-fold decrease in the efficiency of the near-surface bottom sediments for filtering out Synechococcus, cyanophage, and well-characterized microspheres.

Anaerobic oxidation of methane in the Concepción Methane Seep Area, Chilean continental margin

NASA Astrophysics Data System (ADS)

Steeb, P.; Linke, P.; Scholz, F.; Schmidt, M.; Liebetrau, V.; Treude, T.

2012-04-01

Within subduction zones of active continental margins, large amounts of methane can be mobilized by dewatering processes and transported to the seafloor along migration pathways. A recently discovered seep area located off Concepción (Chile) at water depth between 600 to 1100 mbsl is characterized by active methane vent sites as well as massive carbonates boulders and plates which probably are related to methane seepage in the past. During the SO210 research expedition "Chiflux" (Sept-Oct 2010), sediment from the Concepción Methane Seep Area (CSMA) at the fore arc of the Chilean margin was sampled to study microbial activity related to methane seepage. We sampled surface sediments (0-30cm) from sulfur bacteria mats, as well as clam, pogonophoran, and tubeworm fields with push cores and a TV-guided multicorer system. Anaerobic oxidation of methane (AOM) and sulfate reduction rates were determined using ex-situ radioisotope tracer techniques. Additionally, porewater chemistry of retrieved cores as well as isotopic composition and age record of surrounding authigenic carbonates were analyzed. The shallowest sulfate-methane-transition zone (SMTZ) was identified at 4 cm sediment depth hinting to locally strong fluid fluxes. However, a lack of Cl- anomalies in porewater profiles indicates a shallow source of these fluids, which is supported by the biogenic origin of the methane (δ13C -70‰ PDB). Sulfide and alkalinity was relatively high (up to 20 mM and 40 mEq, respectively). Rates of AOM and sulfate reduction within this area reached magnitudes typical for seeps with variation between different habitat types, indicating a diverse methane supply, which is affecting the depths of the SMTZ. Rates were highest at sulfur a bacteria mats (20 mmol m-2 d-1) followed by a large field of dead clams, a pogonophoran field, a black sediment spot, and a carbonate rich clam field. Lowest rates (0.2 mmol m-2 d-1) were measured in close vicinity to these hot spots. Abundant massive carbonate blocks and plates hint to a very old seep system with a probably much higher activity in the past. The U-Th age record of these authigenic carbonates reach back to periods of venting activity with more than 150 ka ago. Carbon isotopic signatures of authigenic carbonates (δ13C -50 to -40‰ PDB) suggest a biogenic carbon source (i.e. methane), also in the past. We found several indications for the impact of recent earthquakes within the seep area (cracks, shifted seafloor), which could be an important mechanism for the triggering of new seepage activity, change in fluid expulsion rates and colonization patterns of the cold seep fauna.

Estimating Water Fluxes Across the Sediment-Water Interface in the Lower Merced River, California

USGS Publications Warehouse

Zamora, Celia

2008-01-01

The lower Merced River Basin was chosen by the U.S. Geological Survey?s (USGS) National Water Quality Assessment Program (NAWQA) to be included in a national study on how hydrological processes and agricultural practices interact to affect the transport and fate of agricultural chemicals. As part of this effort, surface-water?ground-water (sw?gw) interactions were studied in an instrumented 100-m reach on the lower Merced River. This study focused on estimating vertical rates of exchange across the sediment?water interface by direct measurement using seepage meters and by using temperature as a tracer coupled with numerical modeling. Temperature loggers and pressure transducers were placed in monitoring wells within the streambed and in the river to continuously monitor temperature and hydraulic head every 15 minutes from March 2004 to October 2005. One-dimensional modeling of heat and water flow was used to interpret the temperature and head observations and deduce the sw?gw fluxes using the USGS numerical model, VS2DH, which simulates variably saturated water flow and solves the energy transport equation. Results of the modeling effort indicate that the Merced River at the study reach is generally a slightly gaining stream with small head differences (cm) between the surface water and ground water, with flow reversals occurring during high streamflow events. The average vertical flux across the sediment?water interface was 0.4?2.2 cm/day, and the range of hydraulic conductivities was 1?10 m/day. Seepage meters generally failed to provide accurate data in this high-energy system because of slow seepage rates and a moving streambed resulting in scour or burial of the seepage meters. Estimates of streambed hydraulic conductivity were also made using grain-size analysis and slug tests. Estimated hydraulic conductivity for the upstream transect determined using slug tests ranged from 40 to 250 m/day, whereas the downstream transect ranged from 10 to 100 m/day. The range in variability was a result of position along each transect. A relative percent difference was used to describe the variability in estimates of hydraulic conductivity by grain-size analysis and slug test. Variability in applied methods at the upstream transect ranged from 0 to 9 percent, whereas the downstream transect showed greater variability, with a range of 80 to 133 percent.

Groundwater seepage controls salinity in a hydrologically terminal basin of semi-arid northwest Australia

NASA Astrophysics Data System (ADS)

Skrzypek, Grzegorz; Dogramaci, Shawan; Rouillard, Alexandra; Grierson, Pauline F.

2016-11-01

Very small groundwater outflows have the potential to significantly impact the hydrochemistry and salt accumulation processes of notionally terminal basins in arid environments. However, this limited groundwater outflow can be very difficult to quantify using classical water budget calculations due to large uncertainties in estimates of evaporation and evapotranspiration rates from the surface of dry lake beds. In this study, we used a dimensionless time evaporation model to estimate the range of groundwater outflow required to maintain salinity levels observed at the Fortescue Marsh (FM), one of the largest wetlands of semi-arid northwest Australia (∼1100 km2). The groundwater outflow from aquifers underlying the FM to the Lower Fortescue catchment is constrained by an extremely low hydraulic gradient of <0.0001 and a small 'alluvial outlet' of 0.35 km2 because of relatively high bedrock elevation. However, FM groundwater salinity is far below saturation with respect to halite (TDS < 160 g/L), episodic flood water is fresh to brackish, and salt efflorescences are very sparse and evident only when the FM is dry. We show that if the FM was 100% "leakage free" i.e., a true terminal basin, groundwater would have achieved halite saturation (>300 g/L) after ∼45 ka. We calculated that only a very small seepage of ∼2G L/yr (∼0.03% of the FM water volume) is sufficient to maintain current salinity conditions. The minimum time required to develop the current hydrochemical groundwater composition under the FM ranges from ∼60 to ∼165 ka. We conclude that a dimensionless time evaporation model versus inflow over outflow ratio model is likely more suitable than classical water budget calculations for determining outflow from large saline lakes and to estimate groundwater seepage from hydrologically terminal basins.

Distribution and Characteristics of Seafloor Seepage Features in the Active Margin Offshore of SW Taiwan

NASA Astrophysics Data System (ADS)

Chen, T. T.; Hsu, H. H.; Liu, C. S.; Su, C. C.; Paull, C. K.; Chen, Y. H.; Caress, D. W.; Gwiazda, R.; Lundsten, E. M.

2017-12-01

In the active margin offshore of southwest (SW) Taiwan, west-vergent imbricated thrusts, folds and dipping strata are the main structural features. This is also the area where gas hydrates are widely distributed beneath the seafloor. Fluids from deep strata may migrate upwards along porous dipping layers or faults and then vent out to form seafloor seepage features in many of the gas hydrate prospects. A joint survey was conducted in May 2017 using MBARI mapping AUV and miniROV to investigate the seafloor seepage features. Numerous comet-shaped depressions (CSD) are mapped along flanks of several anticlinal ridges, and four carbonate mounds around CSD are observed from the ultra-high-resolution (1-m lateral resolution) bathymetry data collected by AUV. Samples of the carbonate mounds were collected by the mini-ROV, and their mineral compositions contain dolomite and ankerite. The AUV collected chirp sonar profiles and previously collected surface ship multichannel seismic reflection profiles across these seafloor features show that potential fluid migration pathways connect free gas trapped below the base of gas hydrate stability zone and the seafloor in the vicinity of these features. Our study suggests that the CSD could be an indicator of seafloor seepage and may be distribution widely in the active margin setting.

Use of hydrologic budgets and hydrochemistry to determine ground-water and surface-water interactions for Rapid Creek, Western South Dakota

USGS Publications Warehouse

Anderson, Mark T.

1995-01-01

The study of ground-water and surface-water interactions often employs streamflow-gaging records and hydrologic budgets to determine ground-water seepage. Because ground-water seepage usually is computed as a residual in the hydrologic budget approach, all uncertainty of measurement and estimation of budget components is associated with the ground-water seepage. This uncertainty can exceed the estimate, especially when streamflow and its associated error of measurement, is large relative to other budget components. In a study of Rapid Creek in western South Dakota, the hydrologic budget approach with hydrochemistry was combined to determine ground-water seepage. The City of Rapid City obtains most of its municipal water from three infiltration galleries (Jackson Springs, Meadowbrook, and Girl Scout) constructed in the near-stream alluvium along Rapid Creek. The reach of Rapid Creek between Pactola Reservoir and Rapid City and, in particular the two subreaches containing the galleries, were studied intensively to identify the sources of water to each gallery. Jackson Springs Gallery was found to pump predominantly ground water with a minor component of surface water. Meadowbrook and Girl Scout Galleries induce infiltration of surface water from Rapid Creek but also have a significant component of ground water.

Bubble composition of natural gas seeps discovered along the Cascadia Continental Margin

NASA Astrophysics Data System (ADS)

Baumberger, T.; Merle, S. G.; Embley, R. W.; Seabrook, S.; Raineault, N.; Lilley, M. D.; Evans, L. J.; Walker, S. L.; Lupton, J. E.

2016-12-01

Gas hydrates and gas-filled pockets present in sedimentary deposits have been recognized as large reservoirs for reduced carbon in the Earth's crust. This is particularly relevant in geological settings with high carbon input, such as continental margins. During expedition NA072 on the E/V Nautilus (operated by the Ocean Exploration Trust Inc.) in June 2016, the U.S. Cascadia Continental Margin (Washington, Oregon and northern California) was explored for gas seepage from sediments. During this expedition, over 400 bubble plumes at water depths ranging from 125 and 1640 m were newly discovered, and five of them were sampled for gas bubble composition using specially designed gas tight fluid samplers mounted on the Hercules remotely operated vehicle (ROV). These gas bubble samples were collected at four different depths, 494 m (rim of Astoria Canyon), 615 and 620 m (SW Coquille Bank), 849 m (floor of Astoria Canyon) and 1227 m (Heceta SW). At the two deeper sites, exposed hydrate was present in the same area where bubbles were seeping out from the seafloor. Other than the escaping gas bubbles, no other fluid flow was visible. However, the presence of bacterial mats point to diffuse fluid flow present in the affected area. In this study we present the results of the currently ongoing geochemical analysis of the gas bubbles released at the different sites and depths. Noble gas analysis, namely helium and neon, will give information about the source of the helium as well as about potential fractionation between helium and neon associated with gas hydrates. The characterization of these gas samples will also include total gas (CO2, H2, N2, O2, Ar, CH4 and other hydrocarbons) and stable isotope analysis (C and H). This dataset will reveal the chemical composition of the seeping bubbles as well as give information about the possible sources of the carbon contained in the seeping gas.

Characterization of the fate and transport of nitroaromatic compounds at a former DoD ordnance depot site

DOE Office of Scientific and Technical Information (OSTI.GOV)

Klausmeier, M.E.; Yoon, J.

1999-07-01

The 975-acre Former Nansemond Ordnance Depot (FNOD) in Suffolk, Virginia was used by the Department of Defense (DoD) from 1917 until the mid-1950's for preparation, storage, transportation, inspection and demilitarization of many classes of ammunition and ordnance. Approximately 28 areas of Concern (AOC) have been identified by the EPA as areas that could pose potential risk to human health or the environment. The primary contaminants of concern are some trace metals and explosive compounds. During a summer 1987 field investigation, a slab of crystalline TNT was found which was estimated to weigh several tons. An enhanced MODFLOW model is beingmore » used to identify subsurface flow patterns. The calibrated model will be used to identify contaminant fate and transport behavior at the site. Enhancements to the MODFLOW model include an updated block-centered flow package (BCF4) and an updated recharge-seepage face boundary package (RSF4) to utilize for the FNOD site flow characterization. BCF4 package accurately delineates the water table without relying on an ad hoc rewetting procedure. This is accomplished by calculating the hydraulic head value required to transmit recharging water through the unsaturated zone without inactivating dry cells. The recharge-seepage face package eliminates the projection of heads above the ground surface by adjusting recharge to a cell when a user supplied ponding depth is reached. Using a regional model, a telescoping grid refinement technique was implemented to calculate the boundary conditions around the area of interest and to model quantity and quality interactions between surface and subsurface water regimes in a realistic manner.« less

Site Safety and Health Plan (Phase 3) for the treatability study for in situ vitrification at Seepage Pit 1 in Waste Area Grouping 7, Oak Ridge National Laboratory, Oak Ridge, TN

DOE Office of Scientific and Technical Information (OSTI.GOV)

Spalding, B.P.; Naney, M.T.

1995-06-01

This plan is to be implemented for Phase III ISV operations and post operations sampling. Two previous project phases involving site characterization have been completed and required their own site specific health and safety plans. Project activities will take place at Seepage Pit 1 in Waste Area Grouping 7 at ORNL, Oak Ridge, Tennessee. Purpose of this document is to establish standard health and safety procedures for ORNL project personnel and contractor employees in performance of this work. Site activities shall be performed in accordance with Energy Systems safety and health policies and procedures, DOE orders, Occupational Safety and Healthmore » Administration Standards 29 CFR Part 1910 and 1926; applicable United States Environmental Protection Agency requirements; and consensus standards. Where the word ``shall`` is used, the provisions of this plan are mandatory. Specific requirements of regulations and orders have been incorporated into this plan in accordance with applicability. Included from 29 CFR are 1910.120 Hazardous Waste Operations and Emergency Response; 1910.146, Permit Required - Confined Space; 1910.1200, Hazard Communication; DOE Orders requirements of 5480.4, Environmental Protection, Safety and Health Protection Standards; 5480.11, Radiation Protection; and N5480.6, Radiological Control Manual. In addition, guidance and policy will be followed as described in the Environmental Restoration Program Health and Safety Plan. The levels of personal protection and the procedures specified in this plan are based on the best information available from reference documents and site characterization data. Therefore, these recommendations represent the minimum health and safety requirements to be observed by all personnel engaged in this project.« less

Investigation of shallow gas hydrate occurrence and gas seep activity on the Sakhalin continental slope, Russia

NASA Astrophysics Data System (ADS)

Jin, Young Keun; Baranov, Boris; Obzhirov, Anatoly; Salomatin, Alexander; Derkachev, Alexander; Hachikubo, Akihiro; Minami, Hrotsugu; Kuk Hong, Jong

2016-04-01

The Sakhalin continental slope has been a well-known gas hydrate area since the first finding of gas hydrate in 1980's. This area belongs to the southernmost glacial sea in the northern hemisphere where most of the area sea is covered by sea ice the winter season. Very high organic carbon content in the sediment, cold sea environment, and active tectonic regime in the Sakhalin slope provide a very favorable condition for occurring shallow gas hydrate accumulation and gas emission phenomena. Research expeditions under the framework of a Korean-Russian-Japanese long-term international collaboration projects (CHAOS, SSGH-I, SSGH-II projects) have been conducted to investigate gas hydrate occurrence and gas seepage activities on the Sakhalin continental slope, Russia from 2003 to 2015. During the expeditions, near-surface gas hydrate samples at more than 30 sites have been retrieved and hundreds of active gas seepage structures on the seafloor were newly registered by multidisciplinary surveys. The gas hydrates occurrence at the various water depths from about 300 m to 1000 m in the study area were accompanied by active gas seepage-related phenomena in the sub-bottom, on the seafloor, and in the water column: well-defined upward gas migration structures (gas chimney) imaged by high-resolution seismic, hydroacoustic anomalies of gas emissions (gas flares) detected by echosounders, seafloor high backscatter intensities (seepage structures) imaged by side-scan sonar and bathymetric structures (pockmarks and mounds) mapped by single/multi-beam surveys, and very shallow SMTZ (sulphate-methane transition zone) depths, strong microbial activities and high methane concentrations measured in sediment/seawater samples. The highlights of the expeditions are shallow gas hydrate occurrences around 300 m in the water depth which is nearly closed to the upper boundary of gas hydrate stability zone in the area and a 2,000 m-high gas flare emitted from the deep seafloor.

Active Heat Injection to Investigate Seepage Conditions Along the Interface Between a Concrete Diversion Sluiceway and Earthen Embankment Dam

NASA Astrophysics Data System (ADS)

Ringeri, A.; Butler, K. E.; MacQuarrie, K. T. B.

2016-12-01

The interface between embankment dams and adjoining hydraulic structures are regions which can give rise to seepage defects. A field experiment was conducted at the Mactaquac Generating Station in New Brunswick, Canada using active thermometry to investigate seepage conditions along the interface of a diversion sluiceway and earth embankment. The method involved monitoring the time evolution of temperature following the injection of a controlled heat pulse from a subsurface heat cable acting as a line source. Transient anomalies in the induced temperature field can result from the aberration of thermal properties and flow conditions which accompany defects. An industrial heat trace cable and distributed temperature sensing (DTS) fibre optic cable were installed in two parallel, 42 m deep, sub-vertical boreholes separated by 3 m and offset 0.5 m from the core-concrete interface. The heat and DTS cables were installed in the upstream and downstream boreholes respectively. Heat was injected as a box car function at a constant rate of 78.72 W/m for 51 d while the DTS cable, with a 20 cm sampling resolution, was averaged over 10 min at 30 min intervals for 300 d. The DTS cable successfully detected temperature changes induced by the upstream heat pulse. A coherent temperature response occurred along a 13 m section of deep fibre, where mean peak temperatures rose 1.59 ± 0.03 °C above ambient temperatures with an average time lag of 8.2 d following the end of the heating cycle. Two temperature anomalies above this region coincided with the position of the water table and the location of a previously detected fibre break. The method appears to be particularly useful in seepage surveillance of the deeper regions of the interface. Further analysis is required to remove the influence of seasonal temperatures on the heat pulse response at shallow depths.

Structural characterization of framework-gas interactions in the metal-organic framework Co2(dobdc) by in situ single-crystal X-ray diffraction.

PubMed

Gonzalez, Miguel I; Mason, Jarad A; Bloch, Eric D; Teat, Simon J; Gagnon, Kevin J; Morrison, Gregory Y; Queen, Wendy L; Long, Jeffrey R

2017-06-01

The crystallographic characterization of framework-guest interactions in metal-organic frameworks allows the location of guest binding sites and provides meaningful information on the nature of these interactions, enabling the correlation of structure with adsorption behavior. Here, techniques developed for in situ single-crystal X-ray diffraction experiments on porous crystals have enabled the direct observation of CO, CH 4 , N 2 , O 2 , Ar, and P 4 adsorption in Co 2 (dobdc) (dobdc 4- = 2,5-dioxido-1,4-benzenedicarboxylate), a metal-organic framework bearing coordinatively unsaturated cobalt(ii) sites. All these molecules exhibit such weak interactions with the high-spin cobalt(ii) sites in the framework that no analogous molecular structures exist, demonstrating the utility of metal-organic frameworks as crystalline matrices for the isolation and structural determination of unstable species. Notably, the Co-CH 4 and Co-Ar interactions observed in Co 2 (dobdc) represent, to the best of our knowledge, the first single-crystal structure determination of a metal-CH 4 interaction and the first crystallographically characterized metal-Ar interaction. Analysis of low-pressure gas adsorption isotherms confirms that these gases exhibit mainly physisorptive interactions with the cobalt(ii) sites in Co 2 (dobdc), with differential enthalpies of adsorption as weak as -17(1) kJ mol -1 (for Ar). Moreover, the structures of Co 2 (dobdc)·3.8N 2 , Co 2 (dobdc)·5.9O 2 , and Co 2 (dobdc)·2.0Ar reveal the location of secondary (N 2 , O 2 , and Ar) and tertiary (O 2 ) binding sites in Co 2 (dobdc), while high-pressure CO 2 , CO, CH 4 , N 2 , and Ar adsorption isotherms show that these binding sites become more relevant at elevated pressures.

Remaining gaps for "safe" CO2 storage: the INGV CO2GAPS vision of "learning by doing" monitoring geogas leakage, reservoirs contamination/mixing and induced/triggered seismicity

NASA Astrophysics Data System (ADS)

Quattrocchi, F.; Vinciguerra, S.; Chiarabba, C.; Boschi, E.; Anselmi, M.; Burrato, P.; Buttinelli, M.; Cantucci, B.; Cinti, D.; Galli, G.; Improta, L.; Nazzari, M.; Pischiutta, M.; Pizzino, L.; Procesi, M.; Rovelli, A.; Sciarra, A.; Voltattorni, N.

2012-12-01

The CO2GAPS project proposed by INGV is intended to build up an European Proposal for a new kind of research strategy in the field of the geogas storage. Aim of the project would be to fill such key GAPS concerning the main risks associated to CO2 storage and their implications on the entire Carbon Capture and Storage (CCS) process, which are: i) the geogas leakage both in soils and shallow aquifers, up to indoor seepage; ii) the reservoirs contamination/mixing by hydrocarbons and heavy metals; iii) induced or triggered seismicity and microseismicity, especially for seismogenic blind faults. In order to consider such risks and make the CCS public acceptance easier, a new kind of research approach should be performed by: i) a better multi-disciplinary and "site specific" risk assessment; ii) the development of more reliable multi-disciplinary monitoring protocols. In this view robust pre-injection base-lines (seismicity and degassing) as well as identification and discrimination criteria for potential anomalies are mandatory. CO2 injection dynamic modelling presently not consider reservoirs geomechanical properties during reactive mass-transport large scale simulations. Complex simulations of the contemporaneous physic-chemical processes involving CO2-rich plumes which move, react and help to crack the reservoir rocks are not totally performed. These activities should not be accomplished only by the oil-gas/electric companies, since the experienced know-how should be shared among the CCS industrial operators and research institutions, with the governments support and overview, also flanked by a transparent and "peer reviewed" scientific popularization process. In this context, a preliminary and reliable 3D modelling of the entire "storage complex" as defined by the European Directive 31/2009 is strictly necessary, taking into account the above mentioned geological, geochemical and geophysical risks. New scientific results could also highlighting such opportunities recently shown by strategic researches on the synergies between the use of underground space (e.g. CH4, CO2 storage and deep geothermics) for energetic supplying purposes. The CO2GAPS approach would merge together geomechanical and geochemical data with seismic velocity and anisotropy properties of the crust, induced seismicity data, gravimetry, EM techniques, and "early alarm" procedures for leakage/cracks detection in shallow geo-spheres (e.g. abandoned wells, naturally seismic and degassing zones). Moreover, a full merging of those data is necessary for a reliable 3D-Earth modelling and the subsequent reactive transport simulations. CO2GAPS vision would apply and verify these issues working on several European selected sites, taking also into account complex systems such as "inland" active faulted blocks close to potential off-shore CO2 storage sites, ECBM faulted prone-areas, "inland" injection test site and CO2 natural faulted analogues. The purpose of these activities focus on the study of long-term fate of stored CO2, leakage mechanisms through the cap-rock and/or abandoned wells, cement wells reactivity, as well as the effects of impurities in the CO2 streams, their removal costs, the use of tracers and the role of biota.

Salina-margin tepees, pisoliths, and aragonite cements, Lake MacLeod, Western Australia: Their significance in interpreting ancient analogs

NASA Astrophysics Data System (ADS)

Robertson Handford, C.; Kendall, Alan C.; Prezbindowski, Dennis R.; Dunham, John B.; Logan, Brian W.

1984-09-01

Tepee structures, banded aragonite cements, and pisoliths are currently forming in Lake MacLeod, a carbonate-evaporite salina in Western Australia. Although Lake MacLeod is separated from the Indian Ocean by a barrier, it lies 3 4 m below sea level, which promotes the seepage of seawater through the barrier and its discharge from vents and seepage mounds around the margin of the salina. Discharging waters have precipitated and diagenetically altered carbonate sediments within these seepage mounds to form tepee structures of lithified protodolomite overlying cavities that are lined with banded aragonite cement and floored by both cement and pisoliths. Significant variations in δ18O (5.1‰ PDB) and δ13C (5.5‰ PDB) of the aragonite cements were documented and are thought to record shifts in the isotopic composition of the water brought about by the effects of evaporation, influx of meteoric water, and oxidation of organic water. Carbon-14 dating of cements indicates that cementation began about 3400 B.P. and has proceeded at a rate of about 0.2 to 0.4 mm/100 yr, the highest rate occurring during evaporative episodes. By analogy with Lake MacLeod and other Australian salinas, peritidal tepee structures and associated diagenetic carbonates in the Permian Capitan Reef complex may owe their origin to speleanlike diagenesis operative in a marine groundwater discharge zone.

Evaluation of groundwater discharge into small lakes based on the temporal distribution of radon-222

USGS Publications Warehouse

Dimova, N.T.; Burnett, W.C.

2011-01-01

In order to evaluate groundwater discharge into small lakes we constructed a model that is based on the budget of 222Rn (radon t1/2 5 3.8 d) as a tracer. The main assumptions in our model are that the lake's waters are wellmixed horizontally and vertically; the only significant 222Rn source is via groundwater discharge; and the only losses are due to decay and atmospheric evasion. In order to evaluate the groundwater-derived 222Rn flux, we monitored the 222Rn concentration in lake water over periods long enough (usually 1-3 d) to observe changes likely caused by variations in atmospheric exchange (primarily a function of wind speed and temperature). We then attempt to reproduce the observed record by accounting for decay and atmospheric losses and by estimating the total 222Rn input flux using an iterative approach. Our methodology was tested in two lakes in central Florida: one of which is thought to have significant groundwater inputs (Lake Haines) and another that is known not to have any groundwater inflows but requires daily groundwater augmentation from a deep aquifer (Round Lake). Model results were consistent with independent seepage meter data at both Lake Haines (positive seepage of ??? 1.6 ?? 104 m3 d-1 in Mar 2008) and at Round Lake (no net groundwater seepage). ?? 2011, by the American Society of Limnology and Oceanography, Inc.

Widespread methane leakage from the sea floor on the northern US Atlantic margin

USGS Publications Warehouse

Skarke, Adam; Ruppel, Carolyn; Kodis, Mali'o; Brothers, Daniel S.; Lobecker, Elizabeth A.

2014-01-01

Methane emissions from the sea floor affect methane inputs into the atmosphere, ocean acidification and de-oxygenation, the distribution of chemosynthetic communities and energy resources. Global methane flux from seabed cold seeps has only been estimated for continental shelves, at 8 to 65 Tg CH4 yr−1, yet other parts of marine continental margins are also emitting methane. The US Atlantic margin has not been considered an area of widespread seepage, with only three methane seeps recognized seaward of the shelf break. However, massive upper-slope seepage related to gas hydrate degradation has been predicted for the southern part of this margin, even though this process has previously only been recognized in the Arctic. Here we use multibeam water-column backscatter data that cover 94,000 km2 of sea floor to identify about 570 gas plumes at water depths between 50 and 1,700 m between Cape Hatteras and Georges Bank on the northern US Atlantic passive margin. About 440 seeps originate at water depths that bracket the updip limit for methane hydrate stability. Contemporary upper-slope seepage there may be triggered by ongoing warming of intermediate waters, but authigenic carbonates observed imply that emissions have continued for more than 1,000 years at some seeps. Extrapolating the upper-slope seep density on this margin to the global passive margin system, we suggest that tens of thousands of seeps could be discoverable.

Mono- and polynuclear Co(II) silanethiolates with aliphatic diamines

NASA Astrophysics Data System (ADS)

Pladzyk, Agnieszka; Baranowska, Katarzyna

2014-01-01

Four Co(II) complexes, [Co{SSi(OtBu)3}2(dmpda)] 1, [Co{SSi(OtBu)3}2(bda)2]n2 [Co{SSi(OtBu)3}2(pda)2]n3 and [Co{SSi(OtBu)3}2(hda)2]n4 [dmpda = 3-(dimethylamino)-1-propylamine; bda = 1.4-butanediamine; pda = 1.5-pentanediamine; had = 1.6-hexanediamine] have been synthesized and characterized using X-ray diffraction. Complex 1 is mononuclear and contains Co(II) coordinated by dmpda molecule in chelating mode, whereas compounds 3 and 4 are one-dimensional polymers with pda and hda diamines as bridges between the metallic centers respectively. In all complexes tri-tert-butoxysilanethiolate residue acts as terminal S-donor ligand. Full characterization of obtained compounds 1-4 was additionally carried out with the use of IR and UV-vis spectroscopy, elemental and thermal analysis.

Removal of Polycyclic Aromatic Hydrocarbons from Precipitation in an Urban Forest of Guangzhou, South China.

PubMed

Chen, Bufeng; Pei, Nancai; Huang, Junbiao; Liu, Shuguang; Zhang, Na; Xiao, Yihua; Pan, Yongjun

2015-08-01

Polycyclic aromatic hydrocarbon (PAH) concentrations and fluxes were measured monthly in situ from rain events in an urban forest in the megapolitan city Guangzhou, China, to investigate impacts of forest canopy and soils on PAHs. Mean Σ9-PAH concentrations were 107.5, 101.6, 106.3, 107.1 and 42.4 ng L(-1) in precipitation, throughfall, seepage water at the 30 and 60 cm soil depth, and runoff, respectively, indicating a great decrease in the form of runoff. Meanwhile, annual fluxes of total PAHs decreased from precipitation (205.9 µg m(-2) year(-1)), to throughfall (156.3 µg m(-2) year(-1)), and to seepage water (65.3 µg m(-2) year(-1) at 30-cm soil depth and 7.5 µg m(-2) year(-1) at 60-cm soil depth), but increased in runoff (34.1 µg m(-2) year(-1)). When compared to precipitation, PAH fluxes decreased by 83.4% in runoff, with 29% contributed by forest canopy and 71% by soils. Soil biodegradation explained 18.2% of PAH reduction by the surface soil layer and 34.6% by the middle soil layer.

Evaluation and characterization of the methane-carbon dioxide decomposition reaction

NASA Technical Reports Server (NTRS)

Davenport, R. J.; Schubert, F. H.; Shumar, J. W.; Steenson, T. S.

1975-01-01

A program was conducted to evaluate and characterize the carbon dioxide-methane (CO2-CH4) decomposition reaction, i.e., CO2 + CH4 = 2C + 2H2O. The primary objective was to determine the feasibility of applying this reaction at low temperatures as a technique for recovering the oxygen (O2) remaining in the CO2 which exits mixed with CH4 from a Sabatier CO2 reduction subsystem (as part of an air revitalization system of a manned spacecraft). A test unit was designed, fabricated, and assembled for characterizing the performance of various catalysts for the reaction and ultraviolet activation of the CH4 and CO2. The reactor included in the test unit was designed to have sufficient capacity to evaluate catalyst charges of up to 76 g (0.17 lb). The test stand contained the necessary instrumentation and controls to obtain the data required to characterize the performance of the catalysts and sensitizers tested: flow control and measurement, temperature control and measurement, product and inlet gas analysis, and pressure measurement. A product assurance program was performed implementing the concepts of quality control and safety into the program effort.

Multiple technologies applied to characterization of the porosity and permeability of the Biscayne aquifer, Florida

USGS Publications Warehouse

Cunningham, K.J.; Sukop, M.C.

2011-01-01

Research is needed to determine how seepage-control actions planned by the Comprehensive Everglades Restoration Plan (CERP) will affect recharge, groundwater flow, and discharge within the dual-porosity karstic Biscayne aquifer where it extends eastward from the Everglades to Biscayne Bay. A key issue is whether the plan can be accomplished without causing urban flooding in adjacent populated areas and diminishing coastal freshwater flow needed in the restoration of the ecologic systems. Predictive simulation of groundwater flow is a prudent approach to understanding hydrologic change and potential ecologic impacts. A fundamental problem to simulation of karst groundwater flow is how best to represent aquifer heterogeneity. Currently, U.S. Geological Survey (USGS) researchers and academic partners are applying multiple innovative technologies to characterize the spatial distribution of porosity and permeability within the Biscayne aquifer.

Structural safety evaluation of Gerber Arch Dam

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barrie, R.E.

1995-12-31

Gerber Dam, a variable radius arch structure, has experienced seepage and extensive freeze-thaw damage since its construction. A construction key was found cracked at its crest. A finite element investigation was made to evaluate the safety of the arch structure. Design methods and assumptions are evaluated. Historical performance is used in the evaluation. Stress levels, patterns, and distributions were evaluated for loads the structure has experienced to determine behavior contributing to seepage and cracking.

A new device for collecting time-integrated water samples from springs and surface water bodies

USGS Publications Warehouse

Panno, S.V.; Krapac, I.G.; Keefer, D.A.

1998-01-01

A new device termed the 'seepage sampler' was developed to collect representative water samples from springs, streams, and other surface-water bodies. The sampler collects composite, time-integrated water samples over short (hours) or extended (weeks) periods without causing significant changes to the chemical composition of the samples. The water sample within the sampler remains at the ambient temperature of the water body and does not need to be cooled. Seepage samplers are inexpensive to construct and easy to use. A sampling program of numerous springs and/or streams can be designed at a relatively low cost through the use of these samplers. Transient solutes migrating through such flow systems, potentially unnoticed by periodic sampling, may be detected. In addition, the mass loading of solutes (e.g., agrichemicals) may be determined when seepage samplers are used in conjunction with discharge measurements.

Performance characterization of CNTs and γ-Al2O3 supported cobalt catalysts in Fischer-Tropsch reaction

NASA Astrophysics Data System (ADS)

Ali, Sardar; Zabidi, Noor Asmawati Mohd; Subbarao, Duvvuri

2014-10-01

Catalysts were prepared via a wet impregnation method. Different physicochemical properties of the samples were revealed by transmission electron microscope (TEM), temperature programmed reduction (H2-TPR) and carbon dioxide desorption (CO2-desorption). Fischer-Tropsch reaction (FTS) was carried out in a fixed-bed microreactor at 220°C and 1 atm, with H2/ CO = 2v / v and space velocity, SV of 12L/g.h for 5 h. Various characterization techniques revealed that there was a stronger interaction between Co and Al2O3 support compared to that of CNTs support. CNTs support increased the reducibility and decreased Co particle size. A significant increase in % CO conversion and FTS reaction rate was observed over CNTs support compared to that of Co / Al2O3. Co/CNTs resulted in higher C5+ hydrocarbons selectivity compared to that of Co / Al2O3 catalyst. CNTs are a better support for Co compared to Al2O3.

Intrafen and interfen variation of Indiana fens: water chemistry

USGS Publications Warehouse

Stewart, Paul M.; Kessler, Katrina; Dunbar, Richard

1993-01-01

This study establishes a baseline of water chemistry information for selected Indiana fens over the course of one year. Fens are peatlands fed by groundwater seepage and are characterized by their dominant plant communities. Most of the fens discussed in this paper are located on property controlled and protected by the State of Indiana or the Federal government. Comparisons were made of variability in water chemistry data between fens located in the same area and those located some distance away. This survey indicated extensive variability in fen water chemistry with greater variability in water chemistry between fens in separate locations than in yearly variation within individual fens.

Impact of natural oil and higher hydrocarbons on microbial diversity, distribution, and activity in Gulf of Mexico cold-seep sediments

NASA Astrophysics Data System (ADS)

Orcutt, Beth N.; Joye, Samantha B.; Kleindienst, Sara; Knittel, Katrin; Ramette, Alban; Reitz, Anja; Samarkin, Vladimir; Treude, Tina; Boetius, Antje

2010-11-01

Gulf of Mexico cold seeps characterized by variable compositions and magnitudes of hydrocarbon seepage were sampled in order to investigate the effects of natural oils, methane, and non-methane hydrocarbons on microbial activity, diversity, and distribution in seafloor sediments. Though some sediments were characterized by relatively high quantities of oil, which may be toxic to some microorganisms, high rates of sulfate reduction (SR, 27.9±14.7 mmol m-2 d-1), anaerobic oxidation of methane (AOM, 16.2±6.7 mmol m-2 d-1), and acetate oxidation (2.74±0.76 mmol m-2 d-1) were observed in radiotracer measurements. In many instances, the SR rate was higher than the AOM rate, indicating that non-methane hydrocarbons fueled SR. Analysis of 16S rRNA gene clone libraries revealed phylogenetically diverse communities that were dominated by phylotypes of sulfate-reducing bacteria (SRB) and anaerobic methanotrophs of the ANME-1 and ANME-2 varieties. Another group of archaea form a Gulf of Mexico-specific clade (GOM ARC2) that may be important in brine-influenced, oil-impacted sediments from deeper water. Additionally, species grouping within the uncultivated Deltaproteobacteria clades SEEP-SRB3 and -SRB4, as well as relatives of Desulfobacterium anilini, were observed in relatively higher abundance in the oil-impacted sediments, suggesting that these groups of SRB may be involved in or influenced by degradation of higher hydrocarbons or petroleum byproducts.

Experimental multi-phase CO2-brine-rock interactions at elevated temperature and pressure: Implications for CO2 sequestration in deep-saline aquifers

USGS Publications Warehouse

Rosenbauer, R.J.; Koksalan, T.

2004-01-01

Long-term CO2 saturated brine-rock experiments were conducted to evaluate the effects of multiphase H2O-CO2 fluids on mineral equilibria and the potential for CO2 sequestration mineral phases within deep-saline aquifers. Experimental results were consistent with theoretical thermodynamic calculations when CO2-saturated brines were reacted with limestone rocks. The CO2-saturated brine-limestone reactions were characterized by compositional and mineralogical-changes in the aquifer fluid and formation rocks that were dependent on initial brine composition as were the changes in formation porosity, especially dissolved sulfate. The solubility of CO2 was enhanced in brines in the presence of both limestone and sandstone rocks relative to brines alone. Reactions between CO2 saturated brines and arkosic sandstones were characterized by desiccation of the brine and changes in the chemical composition of the brine suggesting fixation of CO2 in mineral phases. These reactions occured on a measurable but kinetically slow time scale at 120??C.

Characterization, Monitoring, and Risk Assessment at the IEA GHG Weyburn-Midale CO2 Monitoring and Storage Project, Saskatchewan, Canada.

NASA Astrophysics Data System (ADS)

Ben, R.; Chalaturnyk, R.; Gardner, C.; Hawkes, C.; Johnson, J.; White, D.; Whittaker, S.

2008-12-01

In July 2000, a major research project was initiated to study the geological storage of CO2 as part of a 5000 tonnes/day EOR project planned for the Weyburn Field in Saskatchewan, Canada. Major objectives of the IEA GHG Weyburn CO2 monitoring and storage project included: assessing the integrity of the geosphere encompassing the Weyburn oil pool for effective long-term storage of CO2; monitoring the movement of the injected CO2, and assessing the risk of migration of CO2 from the injection zone (approximately 1500 metres depth) to the surface. Over the period 2000-2004, a diverse group of 80+ researchers worked on: geological, geophysical, and hydrogeological characterizations at both the regional (100 km beyond the field) and detailed scale (10 km around the field); conducted time-lapse geophysical surveys; carried out surface and subsurface geochemical surveys; and undertook numerical reservoir simulations. Results of the characterization were used for a performance assessment that concluded the risk of CO2 movement to the biosphere was very small. By September 2007, more than 14 Mtonnes of CO2 had been injected into the Weyburn reservoir, including approximately 3 Mtonnes recycled from oil production. A "Final Phase" research project was initiated (2007- 2011) to contribute to a "Best Practices" guide for long-term CO2 storage in EOR settings. Research objectives include: improving the geoscience characterization; further detailed analysis and data collection on the role of wellbores; additional geochemical and geophysical monitoring activities; and an emphasis on quantitative risk assessments using multiple analysis techniques. In this talk a review of results from Phase I will be presented followed by plans and initial results for the Final Phase.

Measuring surface-water loss in Honouliuli Stream near the ‘Ewa Shaft, O‘ahu, Hawai‘i

USGS Publications Warehouse

Rosa, Sarah N.

2017-05-30

The Honolulu Board of Water Supply is currently concerned with the possibility of bacteria in the pumped water of the ‘Ewa Shaft (State well 3-2202-21). Groundwater from the ‘Ewa Shaft could potentially be used to meet future potable water needs in the ‘Ewa area on the island of O‘ahu. The source of the bacteria in the pumped water is unknown, although previous studies indicate that surface water may be lost to the subsurface near the site. The ‘Ewa Shaft consists of a vertical shaft, started near the south bank of Honouliuli Stream at an altitude of about 161 feet, and two horizontal infiltration tunnels near sea level. The shaft extracts groundwater from near the top of the freshwater lens in the Waipahu-Waiawa aquifer system within the greater Pearl Harbor Aquifer Sector, a designated Water Management Area.The surface-water losses were evaluated with continuous groundwater-level data from the ‘Ewa Shaft and a nearby monitoring well, continuous stream-discharge data from U.S. Geological Survey streamflow-gaging station 16212490 (Honouliuli Stream at H-1 Freeway near Waipahu), and seepage-run measurements in Honouliuli Stream and its tributary. During storms, discharge at the Honouliuli Stream gaging station increases and groundwater levels at ‘Ewa Shaft and a nearby monitoring well also increase. The concurrent increase in water levels at ‘Ewa Shaft and the nearby monitoring well during storms indicates that regional groundwater-level changes related to increased recharge, reduced withdrawals (due to a decrease in demand during periods of rainfall), or both may be occurring; although these data do not preclude the possibility of local recharge from Honouliuli Stream. Discharge measurements from two seepage runs indicate that surface water in the immediate area adjacent to ‘Ewa Shaft infiltrates into the streambed and may later reach the groundwater system developed by the ‘Ewa Shaft. The estimated seepage loss rates in the vicinity of ‘Ewa Shaft from the two seepage runs generally ranged from 0.27 to 1.78 million gallons per day per mile of stream reach; although higher seepage rates may occur during periods of higher discharge in Honouliuli Stream. A potential source of bacteria in ‘Ewa Shaft maybe related to seepage from Honouliuli Stream; however, other sources of bacteria were not studied and cannot be excluded.

JPL Developments in Retrieval Algorithms for Geostationary Observations - Applications to H2CO

NASA Technical Reports Server (NTRS)

Kurosu, Thomas P.; Kulawik, Susan; Natraj, Vijay

2012-01-01

JPL has strong expertise in atmospheric retrievals from UV and thermal IR, and a wide range of tools to apply to observations and instrument characterization. Radiative Transfer, AMF, Inversion, Fitting, Assimilation. Tools were applied for a preliminary study of H2CO sensitivities from GEO. Results show promise for moderate/strong H2CO lading but also that low background conditions will prove a challenge. H2CO DOF are not too strongly dependent on FWHM. GEMS (Geostationary Environmental Monitoring Spectrometer) choice of 0.6 nm FWHM (?) spectral resolution is adequate for H2CO retrievals. Case study can easily be adapted to GEMS observations/instrument model for more in-depth sensitivity characterization.

A facile thermal decomposition route to synthesise CoFe2O4 nanostructures

NASA Astrophysics Data System (ADS)

Kalpanadevi, K.; Sinduja, C. R.; Manimekalai, R.

2014-01-01

The synthesis of CoFe2O4 nanoparticles has been achieved by a simple thermal decomposition method from an inorganic precursor, cobalt ferrous cinnamate hydrazinate (CoFe2(cin)3(N2H4)3) which was obtained by a novel precipitation method from the corresponding metal salts, cinnamic acid and hydrazine hydrate. The precursor was characterized by hydrazine and metal analyses, infrared spectral analysis and thermo gravimetric analysis. Under appropriate annealing, CoFe2(cin)3(N2H4)3 yielded CoFe2O4 nanoparticles, which were characterized for their size and structure using X-Ray diffraction (XRD), high resolution transmission electron microscopic (HRTEM), selected area electron diffraction (SAED) and scanning electron microscopic (SEM) techniques.

Characterization of commercial off-the shelf regenerable sorbent to scrub carbon dioxide in a portable life support system

NASA Astrophysics Data System (ADS)

Arai, Tatsuya; Fricker, John

2018-06-01

A resin bead Mitsubishi DIAION™ CR20 was identified and characterized as a first commercial off-the shelf regenerable carbon dioxide (CO2) sorbent candidate for space life support system applications at room temperature. The CO2 adsorption rates and capacities of CR20 at varying CO2 partial pressures were obtained. The data were used to numerically simulate CO2 adsorption by a swingbed, a pair of two sorbent beds that alternately adsorb and desorb CO2 in a space suit portable life support system (PLSS). The result demonstrated that a reasonable volume of CR20 would be able to continuously adsorb CO2 with bed-swing interval of 4 min at 300-W metabolic rate, and that commercial off-the shelf CR20 would have similar performance of CO2 adsorption to the proprietary swingbed sorbent SA9T for PLSS applications.

44 CFR 65.10 - Mapping of areas protected by levee systems.

Code of Federal Regulations, 2013 CFR

2013-10-01

... compaction, penetrations, other design factors affecting seepage (such as drainage layers), and other design..., compressibility of embankment soils, compressibility of foundation soils, age of the levee system, and... described in the COE manual, “Soil Mechanics Design—Settlement Analysis” (EM 1100-2-1904) must be submitted...

44 CFR 65.10 - Mapping of areas protected by levee systems.

Code of Federal Regulations, 2011 CFR

2011-10-01

... compaction, penetrations, other design factors affecting seepage (such as drainage layers), and other design..., compressibility of embankment soils, compressibility of foundation soils, age of the levee system, and... described in the COE manual, “Soil Mechanics Design—Settlement Analysis” (EM 1100-2-1904) must be submitted...

44 CFR 65.10 - Mapping of areas protected by levee systems.

Code of Federal Regulations, 2014 CFR

2014-10-01

... compaction, penetrations, other design factors affecting seepage (such as drainage layers), and other design..., compressibility of embankment soils, compressibility of foundation soils, age of the levee system, and... described in the COE manual, “Soil Mechanics Design—Settlement Analysis” (EM 1100-2-1904) must be submitted...

44 CFR 65.10 - Mapping of areas protected by levee systems.

Code of Federal Regulations, 2012 CFR

2012-10-01

... compaction, penetrations, other design factors affecting seepage (such as drainage layers), and other design..., compressibility of embankment soils, compressibility of foundation soils, age of the levee system, and... described in the COE manual, “Soil Mechanics Design—Settlement Analysis” (EM 1100-2-1904) must be submitted...

Improved Visualization of Hydroacoustic Plumes Using the Split-Beam Aperture Coherence.

PubMed

Blomberg, Ann E A; Weber, Thomas C; Austeng, Andreas

2018-06-25

Natural seepage of methane into the oceans is considerable, and plays a role in the global carbon cycle. Estimating the amount of this greenhouse gas entering the water column is important in order to understand their environmental impact. In addition, leakage from man-made structures such as gas pipelines may have environmental and economical consequences and should be promptly detected. Split beam echo sounders (SBES) detect hydroacoustic plumes due to the significant contrast in acoustic impedance between water and free gas. SBES are also powerful tools for plume characterization, with the ability to provide absolute acoustic measurements, estimate bubble trajectories, and capture the frequency dependent response of bubbles. However, under challenging conditions such as deep water and considerable background noise, it can be difficult to detect the presence of gas seepage from the acoustic imagery alone. The spatial coherence of the wavefield measured across the split beam sectors, quantified by the coherence factor (CF), is a computationally simple, easily available quantity which complements the acoustic imagery and may ease the ability to automatically or visually detect bubbles in the water column. We demonstrate the benefits of CF processing using SBES data from the Hudson Canyon, acquired using the Simrad EK80 SBES. We observe that hydroacoustic plumes appear more clearly defined and are easier to detect in the CF imagery than in the acoustic backscatter images.

Caprock Breach: A Threat to Secure Geologic Sequestration

NASA Astrophysics Data System (ADS)

Selvadurai, A. P.; Dong, W.

2013-12-01

The integrity of caprock in providing a reliable barrier is crucial to several environmental geosciences endeavours related to geologic sequestration of CO2, deep geologic disposal of hazardous wastes and contaminants. The integrity of geologic barriers can be compromised by several factors. The re-activation of dormant fractures and development of new fractures in the caprock during the injection process are regarded as effects that can pose a threat to storage security. Other poromechanical influences of pore structure collapse due to chemically induced erosion of the porous fabric resulting in worm-hole type features can also contribute to compromising storage security. The assessment of the rate of steady or transient seepage through defects in the caprock can allow geoscientists to make prudent evaluations of the effectiveness of a sequestration strategy. While complicated computational simulations can be used to calculate leakage through defects, it is useful to explore alternative analytical results that could be used in providing preliminary estimates of leakage rates through defects in the caprock in a storage setting. The relevance of such developments is underscored by the fact that the permeability characteristics of the storage formation, the fracture and the surficial rocks overlying the caprock can rarely be quantified with certainty. This paper presents the problem of a crack in a caprock that connects to a storage formation and an overburden rock or surficial soil formation. The geologic media are maintained at constant far-field flow potentials and leakage takes place at either steady or transient conditions. The paper develops an analytical result that can be used to estimate the steady seepage through the crack. The analytical result can also be used to estimate the leakage through hydraulically non-intersecting cracks and leakage from caprock-well casing interfaces. The analytical result is used to estimate the accuracy of a computational procedure based on a finite element procedure.

Methane Seepage on Mars: Where to Look and Why

PubMed Central

Etiope, Giuseppe

2017-01-01

Abstract Methane on Mars is a topic of special interest because of its potential association with microbial life. The variable detections of methane by the Curiosity rover, orbiters, and terrestrial telescopes, coupled with methane's short lifetime in the martian atmosphere, may imply an active gas source in the planet's subsurface, with migration and surface emission processes similar to those known on Earth as “gas seepage.” Here, we review the variety of subsurface processes that could result in methane seepage on Mars. Such methane could originate from abiotic chemical reactions, thermogenic alteration of abiotic or biotic organic matter, and ancient or extant microbial metabolism. These processes can occur over a wide range of temperatures, in both sedimentary and igneous rocks, and together they enhance the possibility that significant amounts of methane could have formed on early Mars. Methane seepage to the surface would occur preferentially along faults and fractures, through focused macro-seeps and/or diffuse microseepage exhalations. Our work highlights the types of features on Mars that could be associated with methane release, including mud-volcano-like mounds in Acidalia or Utopia; proposed ancient springs in Gusev Crater, Arabia Terra, and Valles Marineris; and rims of large impact craters. These could have been locations of past macro-seeps and may still emit methane today. Microseepage could occur through faults along the dichotomy or fractures such as those at Nili Fossae, Cerberus Fossae, the Argyre impact, and those produced in serpentinized rocks. Martian microseepage would be extremely difficult to detect remotely yet could constitute a significant gas source. We emphasize that the most definitive detection of methane seepage from different release candidates would be best provided by measurements performed in the ground or at the ground-atmosphere interface by landers or rovers and that the technology for such detection is currently available. Key Words: Mars—Methane—Seepage—Clathrate—Fischer-Tropsch—Serpentinization. Astrobiology 17, 1233–1264. PMID:28771029

Modelling river bank retreat by combining fluvial erosion, seepage and mass failure

NASA Astrophysics Data System (ADS)

Dapporto, S.; Rinaldi, M.

2003-04-01

Streambank erosion processes contribute significantly to the sediment yielded from a river system and represent an important issue in the contexts of soil degradation and river management. Bank retreat is controlled by a complex interaction of hydrologic, geotechnical, and hydraulic processes. The capability of modelling these different components allows for a full reconstruction and comprehension of the causes and rates of bank erosion. River bank retreat during a single flow event has been modelled by combining simulation of fluvial erosion, seepage, and mass failures. The study site, along the Sieve River (Central Italy), has been subject to extensive researches, including monitoring of pore water pressures for a period of 4 years. The simulation reconstructs fairly faithfully the observed changes, and is used to: a) test the potentiality and discuss advantages and limitations of such type of methodology for modelling bank retreat; c) quantify the contribution and mutual role of the different processes determining bank retreat. The hydrograph of the event is divided in a series of time steps. Modelling of the riverbank retreat includes for each step the following components: a) fluvial erosion and consequent changes in bank geometry; b) finite element seepage analysis; c) stability analysis by limit equilibrium method. Direct fluvial shear erosion is computed using empirically derived relationships expressing lateral erosion rate as a function of the excess of shear stress to the critical entrainment value for the different materials along the bank profile. Lateral erosion rate has been calibrated on the basis of the total bank retreat measured by digital terrestrial photogrammetry. Finite element seepage analysis is then conducted to reconstruct the saturated and unsaturated flow within the bank and the pore water pressure distribution for each time step. The safety factor for mass failures is then computed, using the pore water pressure distribution obtained by the seepage analysis, and the geometry of the upper bank is modified in case of failure.

Ecohydrology of seepage springs in an urban National Park

NASA Astrophysics Data System (ADS)

Knee, K.; Melone, J.; Friedel, B.; Fong, D.

2014-12-01

Shallow groundwater-fed seepage springs, also known as hypotelminorheic habitats, are found around the Washington, DC area, including in the George Washington Parkway, a National Park unit in northern Virginia. These springs differ from better-known vernal pools both in their hydrology and their ecology: because they are groundwater-fed, they are more resistant to drying out than vernal pools, and they harbor cave-adapted arthropod species including amphipods of the genus Stygobroumus. This project seeks to understand the ecohydrology of the hypotelminorheic habitats that support these species, some of which are endangered, and which comprise an important but underappreciated component of biodiversity in DC-area National Parks. Our study focuses on two hypotelminorheic habitats in the GW Parkway area and consists of three main components: (1) a weekly population census of Stygobroumus using multiple mark-recapture methodology, (2) weekly monitoring of dissolved radon, a tracer of groundwater discharge, as well as conductivity, dissolved oxygen, and pH, and (3) continuous logging of spring water temperature. This poster presents preliminary data from the Stygobroumus population census and explores how these animals may be affected by spring hydrology. Specifically, we use temperature, conductivity, radon activity and precipitation data from a nearby weather station to understand how the springs respond to episodic and seasonal variation in temperature, precipitation and groundwater seepage and how this affects Stygobromus populations. We also explore whether variations in Stygobromus counts reflect (1) active migration between the surficial spring and the larger subterranean habitat, or (2) passive flushing driven by groundwater discharge. Our results provide basic hydrologic data about a little-understood habitat type and will help managers protect Stygobromus in the urban park environment.

Quality Assurance Project Plan for the treatability study of in situ vitrification of Seepage Pit 1 in Waste Area Grouping 7 at Oak Ridge National Laboratory

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

This Quality Assurance Project Plan (QAPjP) establishes the quality assurance procedures and requirements to be implemented for the control of quality-related activities for Phase 3 of the Treatability Study (TS) of In Situ Vitrification (ISV) of Seepage Pit 1, ORNL Waste Area Grouping 7. This QAPjP supplements the Quality Assurance Plan for Oak Ridge National Laboratory Environmental Restoration Program by providing information specific to the ISV-TS. Phase 3 of the TS involves the actual ISV melt operations and posttest monitoring of Pit 1 and vicinity. Previously, Phase 1 activities were completed, which involved determining the boundaries of Pit 1, usingmore » driven rods and pipes and mapping the distribution of radioactivity using logging tools within the pipes. Phase 2 involved sampling the contents, both liquid and solids, in and around seepage Pit 1 to determine their chemical and radionuclide composition and the spatial distribution of these attributes. A separate QAPjP was developed for each phase of the project. A readiness review of the Phase 3 activities presented QAPjP will be conducted prior to initiating field activities, and an Operational Acceptance, Test (OAT) will also be conducted with no contamination involved. After, the OAT is complete, the ISV process will be restarted, and the melt will be allowed to increase with depth and incorporate the radionuclide contamination at the bottom of Pit 1. Upon completion of melt 1, the equipment will be shut down and mobilized to an adjacent location at which melt 2 will commence.« less

Geohydrology of, and simulation of ground-water flow in, the Milford-Souhegan glacial-drift aquifer, Milford, New Hampshire

USGS Publications Warehouse

Harte, P.T.; Mack, Thomas J.

1992-01-01

Hydrogeologic data collected since 1990 were assessed and a ground-water-flow model was refined in this study of the Milford-Souhegan glacial-drift aquifer in Milford, New Hampshire. The hydrogeologic data collected were used to refine estimates of hydraulic conductivity and saturated thickness of the aquifer, which were previously calculated during 1988-90. In October 1990, water levels were measured at 124 wells and piezometers, and at 45 stream-seepage sites on the main stem of the Souhegan River, and on small tributary streams overlying the aquifer to improve an understanding of ground-water-flow patterns and stream-seepage gains and losses. Refinement of the ground-water-flow model included a reduction in the number of active cells in layer 2 in the central part of the aquifer, a revision of simulated hydraulic conductivity in model layers 2 and representing the aquifer, incorporation of a new block-centered finite-difference ground-water-flow model, and incorporation of a new solution algorithm and solver (a preconditioned conjugate-gradient algorithm). Refinements to the model resulted in decreases in the difference between calculated and measured heads at 22 wells. The distribution of gains and losses of stream seepage calculated in simulation with the refined model is similar to that calculated in the previous model simulation. The contributing area to the Savage well, under average pumping conditions, decreased by 0.021 square miles from the area calculated in the previous model simulation. The small difference in the contrib- uting recharge area indicates that the additional data did not enhance model simulation and that the conceptual framework for the previous model is accurate.

Hydrological and geophysical investigation of streamflow losses and restoration strategies in an abandoned mine lands setting

USGS Publications Warehouse

Cravotta, Charles A.; Sherrod, Laura; Galeone, Daniel G.; Lehman, Wayne G.; Ackman, Terry E.; Kramer, Alexa

2017-01-01

Longitudinal discharge and water-quality campaigns (seepage runs) were combined with surface-geophysical surveys, hyporheic-temperature profiling, and watershed-scale hydrological monitoring to evaluate the locations, magnitude, and impact of streamwater losses from the West Creek subbasin of the West West Branch Schuylkill River into the underground Oak Hill Mine complex that extends beneath the watershed divide. Abandoned mine drainage (AMD), containing iron and other contaminants, from the Oak Hill Boreholes to the West Branch Schuylkill River was sustained during low-flow conditions and correlated to streamflow lost through the West Creek streambed. During high-flow conditions, streamflow was transmitted throughout West Creek; however, during low-flow conditions, all streamflow from the perennial headwaters was lost within the 300-to-600-m "upper reach" where an 1889 mine map indicated steeply dipping coalbeds underlie the channel. During low-flow conditions, the channel within the "intermediate reach" 700-to-1650-m downstream gained groundwater seepage with higher pH and specific conductance than upstream; however, all streamflow 1650-to-2050-m downstream was lost to underlying mines. Electrical resistivity and electromagnetic conductivity surveys indicated conductive zones beneath the upper reach, where flow loss occurred, and through the intermediate reach, where gains and losses occurred. Temperature probes at 0.06-to-0.10-m depth within the hyporheic zone of the intermediate reach indicated potential downward fluxes as high as 2.1x10-5 m/s. Cumulative streamflow lost from West Creek during seepage runs averaged 53.4 L/s, which equates to 19.3 percent of the daily average discharge of AMD from the Oak Hill Boreholes and a downward flux of 1.70x10-5 m/s across the 2.1-km-by-1.5-m West Creek stream-channel area.

Quantifying the fate of agricultural nitrogen in an unconfined aquifer: Stream-based observations at three measurement scales

NASA Astrophysics Data System (ADS)

Gilmore, Troy E.; Genereux, David P.; Solomon, D. Kip; Solder, John E.; Kimball, Briant A.; Mitasova, Helena; Birgand, François

2016-03-01

We compared three stream-based sampling methods to study the fate of nitrate in groundwater in a coastal plain watershed: point measurements beneath the streambed, seepage blankets (novel seepage-meter design), and reach mass-balance. The methods gave similar mean groundwater seepage rates into the stream (0.3-0.6 m/d) during two 3-4 day field campaigns despite an order of magnitude difference in stream discharge between the campaigns. At low flow, estimates of flow-weighted mean nitrate concentrations in groundwater discharge ([NO3-]FWM) and nitrate flux from groundwater to the stream decreased with increasing degree of channel influence and measurement scale, i.e., [NO3-]FWM was 654, 561, and 451 µM for point, blanket, and reach mass-balance sampling, respectively. At high flow the trend was reversed, likely because reach mass-balance captured inputs from shallow transient high-nitrate flow paths while point and blanket measurements did not. Point sampling may be better suited to estimating aquifer discharge of nitrate, while reach mass-balance reflects full nitrate inputs into the channel (which at high flow may be more than aquifer discharge due to transient flow paths, and at low flow may be less than aquifer discharge due to channel-based nitrate removal). Modeling dissolved N2 from streambed samples suggested (1) about half of groundwater nitrate was denitrified prior to discharge from the aquifer, and (2) both extent of denitrification and initial nitrate concentration in groundwater (700-1300 µM) were related to land use, suggesting these forms of streambed sampling for groundwater can reveal watershed spatial relations relevant to nitrate contamination and fate in the aquifer.

Quantification of tidally-influenced seasonal groundwater discharge to the Bay of Bengal by seepage meter study

NASA Astrophysics Data System (ADS)

Debnath, Palash; Mukherjee, Abhijit

2016-06-01

Submarine groundwater discharges (SGD) play a major role in solute transport and nutrient flux to the ocean. We have conducted a spatio-temporal high-resolution lunar-tidal cycle-scale seepage meter experiment during pre-monsoon and post-monsoon seasons, to quantify the spatio-temporal patterns and variability of SGD, its terrestrial (T-SGD) and marine components (M-SGD). The measured daily average SGD rates range from no discharge to 3.6 m3 m-2 d-1 during pre-monsoon season and 0.08-5.9 m3 m-2 d-1 during post-monsoon seasons, depending on the tidal pattern. The uncertainty for SGD measurement is calculated as ±0.8% to ±11% for pre-monsoon and ±1.8% to ±17% for post-monsoon respectively. A linear, inverse relationship was observed between the calculated T-SGD and M-SGD components, which varied along the distance from the coast and position in the tidal-cycle, spatial and temporal (daily) variations of seepage rates within the lunar tidal cycle period distinctly demonstrate the influence of tides on groundwater seepage rate. As an instance, for the identification of the bulk discharge location, the centroid of the integrated SGD rate has been calculated and found to be near 20 m offshore area. The average discharge rate per unit area further extrapolated to total SGD fluxes to the Bay of Bengal from eastern Indian coast by extrapolation of the annual and seasonal fluxes observed in the study area, which are first direct/experimental estimate of SGD to the Bay of Bengal. Approximations suggest that in present-day condition, total average annual SGD to the Bay of Bengal is about 8.98 ± 0.6 × 108 m3/y. This is suggested that the SGD input to the ocean through the Bay of Bengal is approximately 0.9% of the global input from the inter-tidal zone and that has an implication on the mass balance of discharging solutes/nutrients to the global oceans. High T-SGD input is observed for all season, which is largest toward landward direction from the delineated saltwater-freshwater interface. The high magnitude of T-SGD could play an important role in mass balance of fresh water discharge and solute transport to the global ocean, thereby influence coastal ecohydrological systems.

National Program for Inspection of Non-Federal Dams. Powdermill Brook Detention Dam (MA 00605) Connecticut River Basin, Westfield, Massachusetts. Phase I Inspection Report.

DTIC Science & Technology

1978-08-01

Date Not Known Surface Cracks None observed Pavement Condition No Pavement Movement or Settlement of Crest None observed Lateral Movement None...Protection - Riprap Failures No riprapp ap • .• Unusual Movement or Cracking at or None observed near Toes Unusual Embankment or Downstream None...Seepage or Efflorescence None observed Joint Alignment Good Unusual Seepage or Leaks in Gate Chamber Cracks None observed . Rusting or Corrosion of

Manual for Calculating the Seepage Strength of Earthfill Dams,

DTIC Science & Technology

1976-07-01

gravity of material of soil particles; d--diameter of soil particles; dio...d 17 ...dsr-diameters of soil particles, the smallest of which in its...compcsition may be present as 10... 17 ...60% by weight; dci--diameter of (piping) particles of soil which may be carried away by the seepage flow; -dso Y1 d...should, however, be reduced, assuming: k" onnfrmsi S(Jk)dnonuniform soil = [(Jk)d]uniform soil ( 17 ) where 7is the coefficient of reduction (less than

Productions of sunflower oil biodiesel and used cooking oil through heterogeneous catalysts compared to conventional homogeneous catalysts

NASA Astrophysics Data System (ADS)

Gutiérrez-Zapata, C. A.; Blanco Martínez, D.; Collazos, C. A.; Castellanos Acuña, H. E.; Cuervo, J. A.; Fernandez, C. P.

2017-01-01

This document compares homogeneous and heterogeneous catalysts used by production of biodiesel of sunflower oil and cooking oil used in frying. For this, NaOH was used as a catalyst homogeneous, and K2CO3 and Na2CO3 supported in gamma-alumina (K2CO3/γ Al2O3 y Na2CO3 /γ-Al2O3) were synthesized as heterogeneous catalysts, which were characterized by X-ray diffraction. The transesterification tests were carried out for the sunflower oil and used cooking oil, in a reflux system, to different molar relations methanol/oil, depending on the type of oil and characterization of the same. The reflux system is performed at a temperature of 55-60°C for one hour. Finally, biofuel was characterized and the yield of the reaction was calculated.

Exploring the effects of data quality, data worth, and redundancy of CO2 gas pressure and saturation data on reservoir characterization through PEST Inversion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fang, Zhufeng; Hou, Zhangshuan; Lin, Guang

2014-04-01

This study examined the impacts of reservoir properties on CO2 migration after subsurface injection and evaluated the possibility of characterizing reservoir properties using CO2 monitoring data such as saturation distribution. The injection reservoir was assumed to be located 1400-1500 m below the ground surface such that CO2 remained in the supercritical state. The reservoir was assumed to contain layers with alternating conductive and resistive properties, which is analogous to actual geological formations such as the Mount Simon Sandstone unit. The CO2 injection simulation used a cylindrical grid setting in which the injection well was situated at the center of themore » domain, which extended up to 8000 m from the injection well. The CO2 migration was simulated using the PNNL-developed simulator STOMP-CO2e (the water-salt-CO2 module). We adopted a nonlinear parameter estimation and optimization modeling software package, PEST, for automated reservoir parameter estimation. We explored the effects of data quality, data worth, and data redundancy on the detectability of reservoir parameters using CO2 saturation monitoring data, by comparing PEST inversion results using data with different levels of noises, various numbers of monitoring wells and locations, and different data collection spacing and temporal sampling intervals. This study yielded insight into the use of CO2 saturation monitoring data for reservoir characterization and how to design the monitoring system to optimize data worth and reduce data redundancy.« less

Interaction of Aquifer and River-Canal Network near Well Field.

PubMed

Ghosh, Narayan C; Mishra, Govinda C; Sandhu, Cornelius S S; Grischek, Thomas; Singh, Vikrant V

2015-01-01

The article presents semi-analytical mathematical models to asses (1) enhancements of seepage from a canal and (2) induced flow from a partially penetrating river in an unconfined aquifer consequent to groundwater withdrawal in a well field in the vicinity of the river and canal. The nonlinear exponential relation between seepage from a canal reach and hydraulic head in the aquifer beneath the canal reach is used for quantifying seepage from the canal reach. Hantush's (1967) basic solution for water table rise due to recharge from a rectangular spreading basin in absence of pumping well is used for generating unit pulse response function coefficients for water table rise in the aquifer. Duhamel's convolution theory and method of superposition are applied to obtain water table position due to pumping and recharge from different canal reaches. Hunt's (1999) basic solution for river depletion due to constant pumping from a well in the vicinity of a partially penetrating river is used to generate unit pulse response function coefficients. Applying convolution technique and superposition, treating the recharge from canal reaches as recharge through conceptual injection wells, river depletion consequent to variable pumping and recharge is quantified. The integrated model is applied to a case study in Haridwar (India). The well field consists of 22 pumping wells located in the vicinity of a perennial river and a canal network. The river bank filtrate portion consequent to pumping is quantified. © 2014, National GroundWater Association.

Effect of TiO2, ZrO2, and TiO2-ZrO2 on the performance of CuO-ZnO catalyst for CO2 hydrogenation to methanol

NASA Astrophysics Data System (ADS)

Xiao, Jie; Mao, Dongsen; Guo, Xiaoming; Yu, Jun

2015-05-01

The influence of TiO2, ZrO2, and TiO2-ZrO2 mixed oxide on the catalytic performance of CuO-ZnO catalyst in the methanol synthesis from CO2 hydrogenation was studied. The catalysts were prepared by oxalate co-precipitation method and characterized by TGA, N2 adsorption, XRD, reactive N2O adsorption, XPS, H2-TPR, H2-TPD, and CO2-TPD techniques. Characterization results reveal that all the additives improve the CuO dispersion in the catalyst body and increase the Cu surface area and adsorption capacities of CO2 and H2. The results of catalytic test reveal that the additives increase both the CO2 conversion and methanol selectivity, and TiO2-ZrO2 mixed oxide is more effective than single components of TiO2 or ZrO2. Moreover, the activity of methanol synthesis is correlated directly with CO2 adsorption capacity over the catalysts.

Natural Offshore Oil Seepage and Related Tarball Accumulation on the California Coastline - Santa Barbara Channel and the Southern Santa Maria Basin: Source Identification and Inventory

USGS Publications Warehouse

Lorenson, T.D.; Hostettler, Frances D.; Rosenbauer, Robert J.; Peters, Kenneth E.; Dougherty, Jennifer A.; Kvenvolden, Keith A.; Gutmacher, Christina E.; Wong, Florence L.; Normark, William R.

2009-01-01

Oil spillage from natural sources is very common in the waters of southern California. Active oil extraction and shipping is occurring concurrently within the region and it is of great interest to resource managers to be able to distinguish between natural seepage and anthropogenic oil spillage. The major goal of this study was to establish the geologic setting, sources, and ultimate dispersal of natural oil seeps in the offshore southern Santa Maria Basin and Santa Barbara Basins. Our surveys focused on likely areas of hydrocarbon seepage that are known to occur between Point Arguello and Ventura, California. Our approach was to 1) document the locations and geochemically fingerprint natural seep oils or tar; 2) geochemically fingerprint coastal tar residues and potential tar sources in this region, both onshore and offshore; 3) establish chemical correlations between offshore active seeps and coastal residues thus linking seep sources to oil residues; 4) measure the rate of natural seepage of individual seeps and attempt to assess regional natural oil and gas seepage rates; and 5) interpret the petroleum system history for the natural seeps. To document the location of sub-sea oil seeps, we first looked into previous studies within and near our survey area. We measured the concentration of methane gas in the water column in areas of reported seepage and found numerous gas plumes and measured high concentrations of methane in the water column. The result of this work showed that the seeps were widely distributed between Point Conception east to the vicinity of Coal Oil Point, and that they by in large occur within the 3-mile limit of California State waters. Subsequent cruises used sidescan and high resolution seismic to map the seafloor, from just south of Point Arguello, east to near Gaviota, California. The results of the methane survey guided the exploration of the area west of Point Conception east to Gaviota using a combination of seismic instruments. The seafloor was mapped by sidescan sonar, and numerous lines of high -resolution seismic surveys were conducted over areas of interest. Biomarker and stable carbon isotope ratios were used to infer the age, lithology, organic matter input, and depositional environment of the source rocks for 388 samples of produced crude oil, seep oil, and tarballs mainly from coastal California. These samples were used to construct a chemometric fingerprint (multivariate statistics) decision tree to classify 288 additional samples, including tarballs of unknown origin collected from Monterey and San Mateo County beaches after a storm in early 2007. A subset of 9 of 23 active offshore platform oils and one inactive platform oil representing a few oil reservoirs from the western Santa Barbara Channel were used in this analysis, and thus this model is not comprehensive and the findings are not conclusive. The platform oils included in this study are from west to east: Irene, Hildago, Harvest, Hermosa, Heritage, Harmony, Hondo, Holly, Platform A, and Hilda (now removed). The results identify three 'tribes' of 13C-rich oil samples inferred to originate from thermally mature equivalents of the clayey-siliceous, carbonaceous marl, and lower calcareous-siliceous members of the Monterey Formation. Tribe 1 contains four oil families having geochemical traits of clay-rich marine shale source rock deposited under suboxic conditions with substantial higher-plant input. Tribe 2 contains four oil families with intermediate traits, except for abundant 28,30-bisnorhopane, indicating suboxic to anoxic marine marl source rock with hemipelagic input. Tribe 3 contains five oil families with traits of distal marine carbonate source rock deposited under anoxic conditions with pelagic but little or no higher-plant input. Tribes 1 and 2 occur mainly south of Point Conception in paleogeographic settings where deep burial of the Monterey Formation source rock favored generation from all thre

Two new species of scale worms (Polychaeta: Aphroditiformia) from deep-sea habitats in the Gulf of Cadiz (NE Atlantic).

PubMed

Ravara, Ascensão; Cunha, Marina R

2016-03-31

Two new species of scale worms are described from the Gulf of Cadiz (NE Atlantic), at depths between 1100 and 2230 m. Australaugeneria iberica sp. nov. (Polynoidae) was obtained from an alcyonarian colony collected at the flank of Carlos Ribeiro mud volcano; it is characterized by the presence of neuropodial hooks only on segment two and by having the first parapodia not enlarged. This is the first report of the genus for the deep sea. The diagnosis of Australaugeneria is emended and a table comparing all species of the genus is provided. Pholoe petersenae sp. nov. (Pholoidae) was collected from the crater of three mud volcanoes (Darwin, Captain Arutyunov and Carlos Ribeiro) in areas of active seepage. This species is characterized by the presence of prostomial peaks and parapodia stylodes and the absence of eyes.

A Qualitative Evidence of the Breeding Sites of Anopheles arabiensis Patton (Diptera: Culicidae) in and Around Kassala Town, Eastern Sudan

PubMed Central

Hamza, Asma Mahmoud; El Rayah, El Amin

2016-01-01

Anopheles arabiensis Patton (Diptera: Culicidae) is considered the most efficient malaria vector in eastern Sudan. This study aims to characterize the breeding sites of An. arabiensis throughout the year in and around Kassala town, eastern Sudan. Diverse larval habitat types were visited and characterized based on the habitat type and chemical composition. Mosquito larvae were found in many diverse habitats. During the rainy season, rain pools and water bodies created by the seasonal Gash River serve as the main breeding sites. In the dry season, irrigation canals, seepage from water pipes, neglected wells, artificial containers, and man-made ditches serve as the main breeding sites. Breeding water showed a pH of 7.9 and a low concentration of the total dissolved salts. The results of this study may be considered in planning and implementing larval control programs in the area. PMID:27547039

Microporous metal organic framework [M2(hfipbb)2(ted)] (M=Zn, Co; H2hfipbb=4,4-(hexafluoroisopropylidene)-bis(benzoic acid); ted=triethylenediamine): Synthesis, structure analysis, pore characterization, small gas adsorption and CO2/N2 separation properties

NASA Astrophysics Data System (ADS)

Xu, William W.; Pramanik, Sanhita; Zhang, Zhijuan; Emge, Thomas J.; Li, Jing

2013-04-01

Carbon dioxide is a greenhouse gas that is a major contributor to global warming. Developing methods that can effectively capture CO2 is the key to reduce its emission to the atmosphere. Recent research shows that microporous metal organic frameworks (MOFs) are emerging as a promising family of adsorbents that may be promising for use in adsorption based capture and separation of CO2 from power plant waste gases. In this work we report the synthesis, crystal structure analysis and pore characterization of two microporous MOF structures, [M2(hfipbb)2(ted)] (M=Zn (1), Co (2); H2hfipbb=4,4-(hexafluoroisopropylidene)-bis(benzoic acid); ted=triethylenediamine). The CO2 and N2 adsorption experiments and IAST calculations are carried out on [Zn2(hfipbb)2(ted)] under conditions that mimic post-combustion flue gas mixtures emitted from power plants. The results show that the framework interacts with CO2 strongly, giving rise to relatively high isosteric heats of adsorption (up to 28 kJ/mol), and high adsorption selectivity for CO2 over N2, making it promising for capturing and separating CO2 from CO2/N2 mixtures.

Dynamic characterization of fractured carbonates at the Hontomín CO2 storage site

NASA Astrophysics Data System (ADS)

Le Gallo, yann; de Dios, José Carlos; Salvador, Ignacio; Acosta Carballo, Taimara

2017-04-01

The geological storage of CO2 is investigated at the Technology Development Plant (TDP) at Hontomín (Burgos, Spain) into a deep saline aquifer, formed by fractured carbonates with poor matrix porosity. During the hydraulic characterization tests, 2,300 tons of liquid CO2 and 14,000 m3 synthetic brine were co-injected on site in various sequences to determine the pressure and temperature responses of the facture network. The results of the pressure tests were analyzed using an analytical approach to determine the overall petrophysical characteristics of the storage formation. Later on, these characteristics were implemented in a 3-D numerical model. The model is a compositional dual medium (fracture + matrix) which accounts for temperature effects, as CO2 is liquid at the well bottom-hole, and multiphase flow hysteresis as alternating water and CO2 injection tests were performed. The pressure and temperature responses of the storage formation were history-matched mainly through the petrophysical and geometrical characteristics of the facture network. This dynamic characterization of the fracture network controls the CO2 migration while the matrix does not appear to significantly contribute to the storage capacity. Consequently, the hydrodynamic behavior of the aquifer is one of the main challenge of the modeling workflow.

Integrated Monitoring and Modeling of Carbon Dioxide Leakage Risk Using Remote Sensing, Ground-Based Monitoring, Atmospheric Models and Risk-Indexing Tools

NASA Astrophysics Data System (ADS)

Burton, E. A.; Pickles, W. L.; Gouveia, F. J.; Bogen, K. T.; Rau, G. H.; Friedmann, J.

2006-12-01

Correct assessment of the potential for CO2 leakage to the atmosphere or near surface is key to managing the risk associated with CO2 storage. Catastrophic, point-source leaks, diffuse seepage, and low leakage rates all merit assessment. Smaller leaks may be early warnings of catastrophic failures, and may be sufficient to damage natural vegetation or crops. Small leaks also may lead to cumulative build-up of lethal levels of CO2 in enclosed spaces, such as basements, groundwater-well head spaces, and caverns. Working with our ZERT partners, we are integrating a variety of monitoring and modeling approaches to understand how to assess potential health, property and environmental risks across this spectrum of leakage types. Remote sensing offers a rapid technique to monitor large areas for adverse environmental effects. If it can be deployed prior to the onset of storage operations, remote sensing also can document baseline conditions against which future claims of environmental damage can be compared. LLNL has been using hyperspectral imaging to detect plant stress associated with CO2 gas leakage, and has begun investigating use of NASA's new satellite or airborne instrumentation that directly measures gas compositions in the atmosphere. While remote sensing techniques have been criticized as lacking the necessary resolution to address environmental problems, new instruments and data processing techniques are demonstrated to resolve environmental changes at the scale associated with gas-leakage scenarios. During the shallow low-flow- CO2 release field experiments planned by ZERT, for the first time, we will have the opportunity to ground- truth hyperspectral data by simultaneous measurement of changes in hyperspectral readings, soil and root zone microbiology, ambient air, soil and aquifer CO2 concentrations. When monitoring data appear to indicate a CO2 leakage event, risk assessment and mitigation of that event requires a robust and nearly real-time method for estimating its associated risk, spatially and temporally. This requires integration of subsurface, surface and atmospheric data and models. To date, we have developed techniques to map risk based on predicted atmospheric plumes and GIS/MT (meteorologic- topographic) risk-indexing tools. This methodology was derived from study of large CO2 releases from an abandoned well penetrating a natural CO2 reservoir at Crystal Geyser, Utah. This integrated approach will provide a powerful tool to screen for high-risk zones at proposed sequestration sites, to design and optimize surface networks for site monitoring and/or to guide setting science-based regulatory compliance requirements for monitoring sequestration sites, as well as to target critical areas for first responders should a catastrophic-release event occur. This work was performed under the auspices of the U.S. Dept. of Energy by University of California, Lawrence Livermore National Laboratory under Contract W-7405-Eng-48.

Fayalite Dissolution and Siderite Formation in Water-Saturated Supercritical CO2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Qafoku, Odeta; Kovarik, Libor; Kukkadapu, Ravi K.

2012-11-25

Olivines, a significant constituent of basaltic rocks, have the potential to immobilize permanently CO2 after it is injected in the deep subsurface, due to carbonation reactions occurring between CO2 and the host rock. To investigate the reactions of fayalitic olivine with supercritical CO2 (scCO2) and formation of mineral carbonates, experiments were conducted at temperatures of 35 °C to 80 °C, 90 atm pressure and anoxic conditions. For every temperature, the dissolution of fayalite was examined both in the presence of liquid water and H2O-saturated scCO2. The experiments were conducted in a high pressure batch reactor at reaction time extending upmore » to 85 days. The newly formed products were characterized using a comprehensive suite of bulk and surface characterization techniques X-ray diffraction, Transmission/Emission Mössbauer Spectroscopy, Scanning Electron Microscopy coupled with Focused Ion Beam, and High Resolution Transmission Electron Microscopy. Siderite with rhombohedral morphology was formed at 35 °C, 50 °C, and 80 °C in the presence of liquid water and scCO2. In H2O-saturated scCO2, the formation of siderite was confirmed only at high temperature (80 °C). Characterization of reacted samples in H2O-saturated scCO2 with high resolution TEM indicated that siderite formation initiated inside voids created during the initial steps of fayalite dissolution. Later stages of fayalite dissolution result in the formation of siderite in layered vertical structures, columns or pyramids with a rhombus base morphology.« less

Imaging Catalytic Activation of CO 2 on Cu 2O (110): A First-Principles Study

DOE PAGES

Li, Liang; Zhang, Rui; Vinson, John; ...

2018-03-05

Balancing global energy needs against increasing greenhouse gas emissions requires new methods for efficient CO 2 reduction. While photoreduction of CO 2 is a viable approach for fuel generation, the rational design of photocatalysts hinges on precise characterization of the surface catalytic reactions. Cu 2O is a promising next-generation photocatalyst, but the atomic-scale description of the interaction between CO 2 and the Cu 2O surface is largely unknown, and detailed experimental measurements are lacking. In this study, density-functional-theory (DFT) calculations have been performed to identify the Cu 2O (110) surface stoichiometry that favors CO 2 reduction. To facilitate interpretation ofmore » scanning tunneling microscopy (STM) and X-ray absorption near-edge structures (XANES) measurements, which are useful for characterizing catalytic reactions, we present simulations based on DFT-derived surface morphologies with various adsorbate types. STM and XANES simulations were performed using the Tersoff Hamann approximation and Bethe-Salpeter equation (BSE) approach, respectively. The results provide guidance for observation of CO 2 reduction reaction on, and rational surface engineering of, Cu 2O (110). In conclusion, they also demonstrate the effectiveness of computational image and spectroscopy modeling as a predictive tool for surface catalysis characterization.« less

Imaging Catalytic Activation of CO 2 on Cu 2O (110): A First-Principles Study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Liang; Zhang, Rui; Vinson, John

Balancing global energy needs against increasing greenhouse gas emissions requires new methods for efficient CO 2 reduction. While photoreduction of CO 2 is a viable approach for fuel generation, the rational design of photocatalysts hinges on precise characterization of the surface catalytic reactions. Cu 2O is a promising next-generation photocatalyst, but the atomic-scale description of the interaction between CO 2 and the Cu 2O surface is largely unknown, and detailed experimental measurements are lacking. In this study, density-functional-theory (DFT) calculations have been performed to identify the Cu 2O (110) surface stoichiometry that favors CO 2 reduction. To facilitate interpretation ofmore » scanning tunneling microscopy (STM) and X-ray absorption near-edge structures (XANES) measurements, which are useful for characterizing catalytic reactions, we present simulations based on DFT-derived surface morphologies with various adsorbate types. STM and XANES simulations were performed using the Tersoff Hamann approximation and Bethe-Salpeter equation (BSE) approach, respectively. The results provide guidance for observation of CO 2 reduction reaction on, and rational surface engineering of, Cu 2O (110). In conclusion, they also demonstrate the effectiveness of computational image and spectroscopy modeling as a predictive tool for surface catalysis characterization.« less

RATE-DEPENDENT PULL-OUT BEARING CAPACITY OF PILES BY SIMILITUDE MODEL TESTS USING SEEPAGE FORCE

NASA Astrophysics Data System (ADS)

Kato, Tatsuya; Kokusho, Takaji

Pull-out test of model piles was conducted by varying the pull-out velocity and skin friction of piles using a seepage force similitude model test apparatus. Due to the seepage consolidation under the pressure of 150kPa, the effective stress distribution in a prototype saturated soil of 17m could be successfully reproduced in the model ground of 28cm thick, in which the pull-out tests were carried out. The pull-out load rose to a peak value at small displacement, and then decreased to a residual value. At the same time, pore pressure in the vicinity of the pile decreased due to suction near the tip and the positive dilatancy near the pile skin. The maximum pull-out load, pile axial load, side friction and the corresponding displacement increased dramatically with increasing pull-out velocity. It was found that these rate-dependent trends become more prominent with increasing skin friction.

Seepage investigation on the Rio Grande from below Caballo Reservoir, New Mexico, to El Paso, Texas, 2012

USGS Publications Warehouse

Gunn, Mark A.; Roark, D. Michael

2014-01-01

A seepage investigation was conducted by the U.S. Geological Survey, in cooperation with the New Mexico Interstate Stream Commission, along an approximately 106-mile reach of the Rio Grande from below Caballo Reservoir, New Mexico, to El Paso, Texas, during June 26–28, 2012, to determine gain or loss of streamflow due to seepage to or from the river channel. Discharge measurements were made during the irrigation season at high flow including 5 sites along the Rio Grande, 5 diversions, and 63 inflows. The net gain or loss of flow in the river channel was computed for four reaches within the 106-mile reach of the Rio Grande. The normalized percentage difference was computed for each reach to determine the difference between discharge measured at upstream and downstream sites, and the normalized percentage uncertainty was computed to determine if a computed gain or loss exceeded cumulative uncertainty associated with measurement of discharge.

Characterization of Qatar's surface carbonates for CO2 capture and thermochemical energy storage

NASA Astrophysics Data System (ADS)

Kakosimos, Konstantinos E.; Al-Haddad, Ghadeer; Sakellariou, Kyriaki G.; Pagkoura, Chrysa; Konstandopoulos, Athanasios G.

2017-06-01

Samples of surface carbonates were collected from three different areas of the Qatar peninsula. We employed material characterization techniques to examine the morphology and composition of the samples, while their CO2 capture capacity was assessed via multiple successive calcination-carbonation cycles. Our samples were mainly calcite and dolomite based. Calcite samples showed higher initial capacity of around 11 mmol CO2 g-1 which decayed rapidly to less than 2 mmol CO2 g-1. On the other hand, dolomite samples showed an excellent stability (˜15 cycles) with a capacity of 6 mmol CO2 g-1. The performance of the dolomite samples is better compared to other similar natural samples, from literature. A promising result for future studies towards improving their performance by physical and chemical modification.

Pulsed CO2 characterization for lidar use

NASA Technical Reports Server (NTRS)

Jaenisch, Holger M.

1992-01-01

An account is given of a scaled functional testbed laser for space-qualified coherent-detection lidar applications which employs a CO2 laser. This laser has undergone modification and characterization for inherent performance capabilities as a model of coherent detection. While characterization results show good overall performance that is in agreement with theoretical predictions, frequency-stability and pulse-length limitations severely limit the laser's use in coherent detection.

Metal-organic coordination architectures of tetrazole heterocycle ligands bearing acetate groups: Synthesis, characterization and magnetic properties

NASA Astrophysics Data System (ADS)

Hu, Bo-Wen; Zheng, Xiang-Yu; Ding, Cheng

2015-12-01

Two new coordination complexes with tetrazole heterocycle ligands bearing acetate groups, [Co(L)2]n (1) and [Co3(L)4(N3)2·2MeOH]n (2) (L=tetrazole-1-acetate) have been synthesized and structurally characterized. Single crystal structure analysis shows that the cobalt-complex 1 has the 3D 3,6-connected (42.6)2(44.62.88.10)-ant topology. By introducing azide in this system, complex 2 forms the 2D network containing the [Co3] units. And the magnetic properties of 1 and 2 have been studied.

Synthesis and Structural Characterization of a Novel Indium Mercapto Derivative [clln(sch2(co)o)2]2-[(4-mepyh)2]2+

NASA Technical Reports Server (NTRS)

Banger, Kulbinder K.; Duraj, Stan A.; Fanwick, Philip E.; Hepp, Aloysius F.; Martock, Robert A.

2004-01-01

The synthesis and structural characterization of a novel In(III) complex is described. The reaction between InCl3 with sodium mercapto-acetic acid, (NaSCH2(CO)OH) in 4-methylpyridine, (CH3(C5H5N), (4-Mepy)) at 25 C affords [ClIn(SCH2(CO)O)2]2- [(4-MepyH)2]2+. X-ray diffraction studies show it to have a distorted square pyramidal geometry, with the [(-SCH2(CO)CO-)] ligands in a trans conformation. The compound crystallizes in the P(raised dash) 1 (No. 2) space group with a = 7.8624 Angstrom, b = 9.950 Angstrom, c = 13.793 Angstrom, alpha = 107.60 degrees, beta= 90.336 degrees, gamma = 98.983 degrees, V = 1014.3 Angstroms (sup 3), R(F(raised circle)) = 0.037, and R(sub w) = 0.048.

Carbon dioxide binding at a Ni/Fe center: synthesis and characterization of Ni(η1-CO2-κC) and Ni-μ-CO2-κC:κ2 O,O′-Fe† †Electronic supplementary information (ESI) available: Characterization data for 3 and 5. CCDC 1492006 and 1492007. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc03450k Click here for additional data file. Click here for additional data file.

PubMed Central

Yoo, Changho

2017-01-01

The degree of CO2 activation can be tuned by incorporating a distinct electronic coordination environment at the nickel center. A mononuclear nickel carboxylate species (Ni–CO2, 3) and a dinuclear nickel–iron carboxylate species (Ni–CO2–Fe, 5) were prepared. The structure of 3 reveals a rare η1-κC binding mode of CO2, while that of 5 shows bridging CO2 binding (μ2-κC:κ2 O,O′) between the nickel and iron, presented as the first example of a nickel-μ-CO2-iron species. The structural analyses of 3 and 5 based on XRD and DFT data reveal a higher degree of CO2 activation in 5, imparted by the additional interaction with an iron ion. PMID:28616135

Quantifying surface water–groundwater interactions using time series analysis of streambed thermal records: Method development

USGS Publications Warehouse

Hatch, Christine E; Fisher, Andrew T.; Revenaugh, Justin S.; Constantz, Jim; Ruehl, Chris

2006-01-01

We present a method for determining streambed seepage rates using time series thermal data. The new method is based on quantifying changes in phase and amplitude of temperature variations between pairs of subsurface sensors. For a reasonable range of streambed thermal properties and sensor spacings the time series method should allow reliable estimation of seepage rates for a range of at least ±10 m d−1 (±1.2 × 10−2 m s−1), with amplitude variations being most sensitive at low flow rates and phase variations retaining sensitivity out to much higher rates. Compared to forward modeling, the new method requires less observational data and less setup and data handling and is faster, particularly when interpreting many long data sets. The time series method is insensitive to streambed scour and sedimentation, which allows for application under a wide range of flow conditions and allows time series estimation of variable streambed hydraulic conductivity. This new approach should facilitate wider use of thermal methods and improve understanding of the complex spatial and temporal dynamics of surface water–groundwater interactions.

Post flooding damage assessment of earth dams and historical reservoirs using non-invasive geophysical techniques

NASA Astrophysics Data System (ADS)

Sentenac, Philippe; Benes, Vojtech; Budinsky, Vladimir; Keenan, Helen; Baron, Ron

2017-11-01

This paper describes the use of four geophysical techniques to map the structural integrity of historical earth reservoir embankments which are susceptible to natural decay with time. The four techniques that were used to assess the post flood damage were 1. A fast scanning technique using a dipole electromagnetic profile apparatus (GEM2), 2. Electrical Resistivity Tomography (ERT) in order to obtain a high resolution image of the shape of the damaged/seepage zone, 3. Self-Potential surveys were carried out to relate the detected seepage evolution and change of the water displacement inside the embankment, 4. The washed zone in the areas with piping was characterised with microgravimetry. The four geophysical techniques used were evaluated against the case studies of two reservoirs in South Bohemia, Czech Republic. A risk approach based on the Geophysical results was undertaken for the reservoir embankments. The four techniques together enabled a comprehensive non-invasive assessment whereby remedial action could be recommended where required. Conclusions were also drawn on the efficiency of the techniques to be applied for embankments with wood structures.

Hydrocarbon seeps in petroliferous basins in China: A first inventory

NASA Astrophysics Data System (ADS)

Zheng, Guodong; Xu, Wang; Etiope, Giuseppe; Ma, Xiangxian; Liang, Shouyun; Fan, Qiaohui; Sajjad, Wasim; Li, Yang

2018-01-01

Natural hydrocarbon seepage is a widespread phenomenon in sedimentary basins, with important implications in petroleum exploration and emission of greenhouse gases to the atmosphere. China has vast petroleum (oil and gas) bearing sedimentary basins, but hydrocarbon seepage has rarely been the object of systematic studies and measurements. Based on the available Chinese literature, we report a first inventory of 932 hydrocarbon seeps or seepage zones (710 onshore seeps and 222 offshore seeps), including 81 mud volcanoes, 449 oil seeps, 215 gas seeps, and 187 solid seeps (bitumen outcrops). The seeps are located within the main 20 Mesozoic-Cenozoic petroliferous sedimentary basins, especially along the marginal, regional and local faults. The type of manifestations (oil, gas or mud volcano) reflects the type and maturity of the subsurface petroleum system and the sedimentary conditions of the basin. Oil seeps are particularly abundant in the Junggar Basin. Gas seeps mostly developed in the Lunpola Basin, in smaller basins of the eastern Guizhou and Yunnan provinces, onshore Taiwan and in the offshore Yinggehai Basin. Mud volcanoes developed in basins (Junggar, Qaidam, Qiangtang, onshore and offshore Taiwan) that experienced rapid sedimentation, which induced gravitative instability of shales and diapirism. In comparison to available global onshore seep data-bases, China results to be the country with the highest number of seeps in the world. The massive gas seepage in China could represent a considerable natural source of methane to the atmosphere, and a key process that may drive future hydrocarbon exploration.

Application of short-range photogrammetry for monitoring seepage erosion of riverbank by laboratory experiments

NASA Astrophysics Data System (ADS)

Masoodi, A.; Noorzad, A.; Majdzadeh Tabatabai, M. R.; Samadi, A.

2018-03-01

Temporal and spatial monitoring play a significant role in evaluating and examining the riverbank morphology and its spatiotemporal changes. Unlike the terrestrial laser scanners, other previously used methods such as satellite images, total station surveying, and erosion pins have limited application to quantify the small-scale bank variations due to the lack of rapid survey and resolution in data acquisition. High cost, lack of availability, specialized equipment and hard movement of laser scanners make it necessary to develop new accurate, economical and easily available methods. The present study aims to test the Kinect photogrametric technology for measuring and assessing riverbank variations in laboratory environment. For this purpose, three models of layered soil blocks for three different levels of groundwater (i.e. 24, 34 and 44 cm) were designed to investigate the seepage erosion behavior experimentally. The results indicate the high accuracy of Kinect in measuring the bank erosion cavity dimensions (i.e., 0.5% error) with high spatial resolution data (i.e. 300,000 points per frame). The high speed of Kinect in riverbank scanning enables the analysis of time variations of mechanisms such as seepage erosion which occurs rather rapidly. The results confirmed that there is a power relationship between the seepage gradient and the time of the bank failure with a determination coefficient of 0.97. Moreover, an increase in the level of groundwater on the riverbank increases the rate of undercutting retreat that caused more rapid failure of the riverbank.

Detection of Natural Oil Seeps in the Atlantic Ocean Using MODIS

NASA Technical Reports Server (NTRS)

Reahard, Ross; Jones, Jason B.; Mitchell, Mark

2010-01-01

Natural oil seepage is the release of crude oil into the ocean from fissures in the seabed. Oil seepage is a major contributor to the total amount of oil entering the world s oceans. According to a 2003 study by the National Academy of Sciences (NAS), 47 percent of oil entering the world s oceans is from natural seeps, and 53 percent is from human sources (extraction, transportation, and consumption). Oil seeps cause smooth oil slicks to form on the water s surface. Oil seeps can indicate the location of stores of fossil fuel beneath the ocean floor. Knowledge of the effect of oil seepage on marine life and marine ecosystems remains limited. In the past, remote sensing has been used to detect oil seeps in the Gulf of Mexico and off of the coast of southern California. This project utilized sun glint MODIS imagery to locate oil slicks off of the Atlantic coast, an area that had not previously been surveyed for natural oil seeps using remote sensing. Since 1982, the Atlantic Ocean has been closed to any oil and gas drilling. Recently, however, the U.S. Minerals Management Services (MMS) has proposed a lease for oil and gas drilling off the coasts of Virginia and North Carolina. Determining the location of seepage sites in the Atlantic Ocean will help MMS locate potential deposits of oil and natural gas, thereby reducing the risk of leasing areas for petroleum extraction that do not contain these natural resources.

Performance characterization of CNTs and γ-Al{sub 2}O{sub 3} supported cobalt catalysts in Fischer-Tropsch reaction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ali, Sardar, E-mail: alikhan-635@yahoo.com; Zabidi, Noor Asmawati Mohd, E-mail: noorasmawati-mzabidi@petronas.com.my; Subbarao, Duvvuri, E-mail: duvvuri-subbarao@petronas.com.my

2014-10-24

Catalysts were prepared via a wet impregnation method. Different physicochemical properties of the samples were revealed by transmission electron microscope (TEM), temperature programmed reduction (H{sub 2}-TPR) and carbon dioxide desorption (CO{sub 2}-desorption). Fischer-Tropsch reaction (FTS) was carried out in a fixed-bed microreactor at 220°C and 1 atm, with H{sub 2}/CO = 2v/v and space velocity, SV of 12L/g.h for 5 h. Various characterization techniques revealed that there was a stronger interaction between Co and Al{sub 2}O{sub 3} support compared to that of CNTs support. CNTs support increased the reducibility and decreased Co particle size. A significant increase in % CO conversion andmore » FTS reaction rate was observed over CNTs support compared to that of Co/Al{sub 2}O{sub 3}. Co/CNTs resulted in higher C{sub 5+} hydrocarbons selectivity compared to that of Co/Al{sub 2}O{sub 3} catalyst. CNTs are a better support for Co compared to Al{sub 2}O{sub 3}.« less

Flux growth of high-quality CoFe 2O 4 single crystals and their characterization

NASA Astrophysics Data System (ADS)

Wang, W. H.; Ren, X.

2006-04-01

We report the growth of high-quality CoFe 2O 4 single crystals using a borax flux method. The crystals were characterized by powder X-ray diffraction, electron probe microanalysis and Raman spectroscopy. We found the crystals are flux-free and highly homogeneous in composition. X-ray rocking curves of the CoFe 2O 4 single crystals showed a full-width at half-maximum of 0.15°. The saturation magnetization of the CoFe 2O 4 single crystals was measured to be 90 emu/g or equivalently 3.65 μ B/f.u. at 5 K.

An alternative gas sensor material: Synthesis and electrical characterization of SmCoO{sub 3}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Michel, Carlos Rafael; Delgado, Emilio; Santillan, Gloria

2007-01-18

Single-phase perovskite SmCoO{sub 3} was prepared by a wet-chemical synthesis technique using metal-nitrates and citric acid; after its characterization by thermal analyses and X-ray diffraction, sintering at 900 deg. C in air, gave single phase and well crystallized powders. The powders were mixed with an organic solvent to prepare a slurry, which was deposited on alumina substrates as thick films, using the screen-printing technique. Electrical and gas sensing properties of sintered SmCoO{sub 3} films were investigated in air, O{sub 2} and CO{sub 2}, the results show that sensitivity reached a maximum value at 420 deg. C, for both gases. Dynamicmore » tests revealed a better behavior of SmCoO{sub 3} in CO{sub 2} than O{sub 2}, due to a fast response and a larger electrical resistance change to this gas. X-ray diffraction made on powders after electrical characterization in gases, showed that perovskite-type structure was preserved.« less

CO2 Biofixation of Actinobacillus succinogenes Through Novel Amine-Functionalized Polystyrene Microsphere Materials.

PubMed

Zhu, Wenhao; Li, Qiang; Dai, Ning

2017-02-01

CO 2 -derived succinate production was enhanced by Actinobacillus succinogenes through polystyrene (PSt) microsphere materials for CO 2 adsorption in bioreactor, and the adhesion forces between A. succinogenes bacteria and PSt materials were characterized. Synthesized uniformly sized and highly cross-linked PSt microspheres had high specific surface areas. After modification with amine functional groups, the novel amine-functionalized PSt microspheres exhibited a high adsorption capacity of 25.3 mg CO 2 /g materials. After addition with the functionalized microspheres into the culture broth, CO 2 supply to the cells increased. Succinate production by A. succinogenes can be enhanced from 29.6 to 48.1 g L -1 . Moreover, the characterization of interaction forces between A. succinogenes cells and the microspheres indicated that the maximal adhesive force was about 250 pN. The amine-functionalized PSt microspheres can adsorb a large amount of CO 2 and be employed for A. succinogenes anaerobic cultivation in bioreactor for high-efficiency production of CO 2 -derived succinate.

Structural characterization of framework–gas interactions in the metal–organic framework Co 2 (dobdc) by in situ single-crystal X-ray diffraction

DOE PAGES

Gonzalez, Miguel I.; Mason, Jarad A.; Bloch, Eric D.; ...

2017-04-19

The crystallographic characterization of framework–guest interactions in metal–organic frameworks allows the location of guest binding sites and provides meaningful information on the nature of these interactions, enabling the correlation of structure with adsorption behavior. Here, techniques developed for in situ single-crystal X-ray diffraction experiments on porous crystals have enabled the direct observation of CO, CH 4, N 2, O 2, Ar, and P 4 adsorption in Co2(dobdc) (dobdc 4– = 2,5-dioxido-1,4-benzenedicarboxylate), a metal–organic framework bearing coordinatively unsaturated cobalt(II) sites. All these molecules exhibit such weak interactions with the high-spin cobalt(II) sites in the framework that no analogous molecular structures exist,more » demonstrating the utility of metal–organic frameworks as crystalline matrices for the isolation and structural determination of unstable species. Notably, the Co–CH 4 and Co–Ar interactions observed in Co 2(dobdc) represent, to the best of our knowledge, the first single-crystal structure determination of a metal–CH 4 interaction and the first crystallographically characterized metal–Ar interaction. Analysis of low-pressure gas adsorption isotherms confirms that these gases exhibit mainly physisorptive interactions with the cobalt(II) sites in Co 2(dobdc), with differential enthalpies of adsorption as weak as –17(1) kJ mol –1 (for Ar). Moreover, the structures of Co 2(dobdc)·3.8N 2, Co 2(dobdc)·5.9O 2, and Co 2(dobdc)·2.0Ar reveal the location of secondary (N 2, O 2, and Ar) and tertiary (O 2) binding sites in Co 2(dobdc), while high-pressure CO 2, CO, CH 4, N 2, and Ar adsorption isotherms show that these binding sites become more relevant at elevated pressures.« less

Improved Detection and Mapping of Deepwater Hydrocarbon Seeps: Optimizing Acquisition and Processing Parameters for Marine Seep Hunting

NASA Astrophysics Data System (ADS)

Mitchell, G. A.; Orange, D.; Gharib, J. J.; Saade, E. J.; Joye, S. B.

2016-12-01

Marine seep hunting surveys are a current focus of hydrocarbon exploration due to recent advances in offshore geophysical and geochemical technologies. Hydrocarbon seeps are ephemeral, small, discrete, and often difficult to sample on the deep seafloor. Low to mid-frequency multibeam echosounders (MBES) are an ideal exploration tool to remotely locate and map seafloor features associated with seepage. Geophysical signatures from hydrocarbon seeps are evident in bathymetric datasets (fluid expulsion features), seafloor backscatter datasets (carbonate outcrops, gassy sediments, methane hydrate deposits), and midwater backscatter datasets (gas bubble and oil droplet plumes). Interpretation of these geophysical seep signatures in backscatter datasets is a fundamental component in seep hunting. Degradation of backscatter datasets resulting from environmental, geometric, and system noise can interfere with the detection and delineation of seeps. We present a backscatter intensity normalization method and a 2X acquisition technique that can enhance the geologic resolvability within backscatter datasets and assist in interpretation and characterization of seeps. We use GC600 in the Northern Gulf of Mexico as a seep calibration site for a Kongsberg EM302 30 kHz MBES prior to the start of the Gigante seep hunting survey. We analyze the results of a backscatter intensity normalization, assess the effectiveness of 2X seafloor coverage in resolving geologic features in backscatter data, and determine off-nadir detection limits of bubble plumes. GC600's location and robust venting make it a natural laboratory in which to study natural hydrocarbon seepage. The site has been the focus of several near-seafloor surveys as well as in-situ studies using advanced deepwater technologies analyzing fluid flux and composition. These datasets allow for ground-truthing of our remote backscatter measurements prior to commencing exploration within the frontier regions of the Southern Gulf of Mexico and Caribbean Sea. Our study shows that a comprehensive multibeam calibration involving bathymetric difference grids, a seafloor backscatter intensity normalization, a 2X acquisition survey technique, and processing with multiple processing packages can improve resolvability of seep features and interpretation.

Simulation of climate-change effects on streamflow, lake water budgets, and stream temperature using GSFLOW and SNTEMP, Trout Lake Watershed, Wisconsin

USGS Publications Warehouse

Hunt, Randall J.; Walker, John F.; Selbig, William R.; Westenbroek, Stephen M.; Regan, R. Steve

2013-01-01

Although groundwater and surface water are considered a single resource, historically hydrologic simulations have not accounted for feedback loops between the groundwater system and other hydrologic processes. These feedbacks include timing and rates of evapotranspiration, surface runoff, soil-zone flow, and interactions with the groundwater system. Simulations that iteratively couple the surface-water and groundwater systems, however, are characterized by long run times and calibration challenges. In this study, calibrated, uncoupled transient surface-water and steady-state groundwater models were used to construct one coupled transient groundwater/surface-water model for the Trout Lake Watershed in north-central Wisconsin, USA. The computer code GSFLOW (Ground-water/Surface-water FLOW) was used to simulate the coupled hydrologic system; a surface-water model represented hydrologic processes in the atmosphere, at land surface, and within the soil-zone, and a groundwater-flow model represented the unsaturated zone, saturated zone, stream, and lake budgets. The coupled GSFLOW model was calibrated by using heads, streamflows, lake levels, actual evapotranspiration rates, solar radiation, and snowpack measurements collected during water years 1998–2007; calibration was performed by using advanced features present in the PEST parameter estimation software suite. Simulated streamflows from the calibrated GSFLOW model and other basin characteristics were used as input to the one-dimensional SNTEMP (Stream-Network TEMPerature) model to simulate daily stream temperature in selected tributaries in the watershed. The temperature model was calibrated to high-resolution stream temperature time-series data measured in 2002. The calibrated GSFLOW and SNTEMP models were then used to simulate effects of potential climate change for the period extending to the year 2100. An ensemble of climate models and emission scenarios was evaluated. Downscaled climate drivers for the period 2010–2100 showed increases in maximum and minimum temperature over the scenario period. Scenarios of future precipitation did not show a monotonic trend like temperature. Uncertainty in the climate drivers increased over time for both temperature and precipitation. Separate calibration of the uncoupled groundwater and surface-water models did not provide a representative initial parameter set for coupled model calibration. A sequentially linked calibration, in which the uncoupled models were linked by means of utility software, provided a starting parameter set suitable for coupled model calibration. Even with sequentially linked calibration, however, transmissivity of the lower part of the aquifer required further adjustment during coupled model calibration to attain reasonable parameter values for evaporation rates off a small seepage lake (a lake with no appreciable surface-water outlets) with a long history of study. The resulting coupled model was well calibrated to most types of observed time-series data used for calibration. Daily stream temperatures measured during 2002 were successfully simulated with SNTEMP; the model fit was acceptable for a range of groundwater inflow rates into the streams. Forecasts of potential climate change scenarios showed growing season length increasing by weeks, and both potential and actual evapotranspiration rates increasing appreciably, in response to increasing air temperature. Simulated actual evapotranspiration rates increased less than simulated potential evapotranspiration rates as a result of water limitation in the root zone during the summer high-evapotranspiration period. The hydrologic-system response to climate change was characterized by a reduction in the importance of the snow-melt pulse and an increase in the importance of fall and winter groundwater recharge. The less dynamic hydrologic regime is likely to result in drier soil conditions in rainfed wetlands and uplands, in contrast to less drying in groundwater-fed systems. Seepage lakes showed larger forecast stage declines related to climate change than did drainage lakes (lakes with outlet streams). Seepage lakes higher in the watershed (nearer to groundwater divides) had less groundwater inflow and thus had larger forecast declines in lake stage; however, ground-water inflow to seepage lakes in general tended to increase as a fraction of the lake budgets with lake-stage decline because inward hydraulic gradients increased. Drainage lakes were characterized by less simulated stage decline as reductions in outlet streamflow of set losses to other water flows. Net groundwater inflow tended to decrease in drainage lakes over the scenario period. Simulated stream temperatures increased appreciably with climate change. The estimated increase in annual average temperature ranged from approximately 1 to 2 degrees Celsius by 2100 in the stream characterized by a high groundwater inflow rate and 2 to 3 degrees Celsius in the stream with a lower rate. The climate drivers used for the climate-change scenarios had appreciable variation between the General Circulation Model and emission scenario selected; this uncertainty was reflected in hydrologic flow and temperature model results. Thus, as with all forecasts of this type, the results are best considered to approximate potential outcomes of climate change.

Hydrology of Crater, East and Davis Lakes, Oregon; with section on Chemistry of the Lakes

USGS Publications Warehouse

Phillips, Kenneth N.; Van Denburgh, A.S.

1968-01-01

Crater, East, and Davis Lakes are small bodies of fresh water that occupy topographically closed basins in Holocene volcanic terrane. Because the annual water supply exceeds annual evaporation, water must be lost by seepage from each lake. The seepage rates vary widely both in volume and in percentage of the total water supply. Crater Lake loses about 89 cfs (cubic feet per second), equivalent to about 72 percent of its average annual supply. East Lake loses about 2.3 cfs, or about 44 percent of its estimated supply. Davis Lake seepage varies greatly with lake level, but the average loss is about 150 cfs, more than 90 percent of its total supply. The destination of the seepage loss is not definitely known for any of the lakes. An approximate water budget was computed for stationary level for each lake, by using estimates 'by the writer to supplement the hydrologic data available. The three lake waters are dilute. Crater Lake contains about 80 ppm, (parts per million) of dissolved solids---mostly silica, sodium, and bicarbonate, and lesser amounts of calcium, sulfate, and chloride. Much of the dissolved-solids content of Crater Lake---especially the sulfate and chloride---may be related to fumarole and thermal-spring activity that presumably followed the collapse of Mount Mazama. Although Grater Lake loses an estimated 7,000 tons of its 1.5million-ton salt content each year by leakage, the chemical character of the lake did not change appreciably between 1912 and 1964. East Lake contains 200 ppm of dissolved solids, which includes major proportions of calcium, sodium, bicarbonate, and sulfate, but almost no chloride. The lake apparently receives much of its dissolved solids from subsurface thermal springs. Annual solute loss from East Lake by leakage is about 450 tons, or 3 percent of the lake's 15,000-ton estimated solute content. Davis Lake contains only 48 ppm of dissolved solids, much of which is silica and bicarbonate; chloride is almost completely absent. Approximate physical and hydrologic data for the lakes are summarized in the following table. [Table

C/O Ratio as a Dimension for Characterizing Exoplanetary Atmospheres

NASA Astrophysics Data System (ADS)

Madhusudhan, Nikku

2012-10-01

Until recently, infrared observations of exoplanetary atmospheres have typically been interpreted using models that assumed solar elemental abundances. With the chemical composition fixed, attempts have been made to classify hot Jupiter atmospheres on the basis of stellar irradiation. However, recent observations have revealed deviations from predictions based on such classification schemes, and chemical compositions retrieved from some data sets have also indicated non-solar abundances. The data require a two-dimensional (2D) characterization scheme with dependence on both irradiation and chemistry. In this work, we suggest the carbon-to-oxygen (C/O) ratio as an important second dimension for characterizing exoplanetary atmospheres. In hot-hydrogen-dominated atmospheres, the C/O ratio critically influences the relative concentrations of several spectroscopically dominant species. Between a C/O of 0.5 (solar value) and 2, the H2O and CH4 abundances can vary by several orders of magnitude in the observable atmosphere, and new hydrocarbon species such as HCN and C2H2 become prominent for C/O >= 1, while the CO abundance remains almost unchanged. Furthermore, a C/O >= 1 can preclude a strong thermal inversion due to TiO and VO in a hot Jupiter atmosphere, since TiO and VO are naturally underabundant for C/O >= 1. We, therefore, suggest a new 2D classification scheme for hydrogen-dominated exoplanetary atmospheres with irradiation (or temperature) and C/O ratio as the two dimensions. We define four classes in this 2D space (O1, O2, C1, and C2) with distinct chemical, thermal, and spectral properties. Based on the most recent observations, we characterize the thermal structure and C/O ratios of six hot Jupiters (XO-1b, CoRoT-2b, WASP-14b, WASP-19b, WASP-33b, and WASP-12b) in the framework of our proposed 2D classification scheme. While the data for several systems in our sample are consistent with C-rich atmospheres, new observations are required to conclusively constrain their C/O ratios in the day side as well as the terminator regions of their atmospheres. We discuss how observations using existing and forthcoming facilities can constrain C/O ratios in exoplanetary atmospheres.

C/O RATIO AS A DIMENSION FOR CHARACTERIZING EXOPLANETARY ATMOSPHERES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Madhusudhan, Nikku, E-mail: Nikku.Madhusudhan@yale.edu; Department of Astronomy, Yale University, New Haven, CT 06511

2012-10-10

Until recently, infrared observations of exoplanetary atmospheres have typically been interpreted using models that assumed solar elemental abundances. With the chemical composition fixed, attempts have been made to classify hot Jupiter atmospheres on the basis of stellar irradiation. However, recent observations have revealed deviations from predictions based on such classification schemes, and chemical compositions retrieved from some data sets have also indicated non-solar abundances. The data require a two-dimensional (2D) characterization scheme with dependence on both irradiation and chemistry. In this work, we suggest the carbon-to-oxygen (C/O) ratio as an important second dimension for characterizing exoplanetary atmospheres. In hot-hydrogen-dominated atmospheres,more » the C/O ratio critically influences the relative concentrations of several spectroscopically dominant species. Between a C/O of 0.5 (solar value) and 2, the H{sub 2}O and CH{sub 4} abundances can vary by several orders of magnitude in the observable atmosphere, and new hydrocarbon species such as HCN and C{sub 2}H{sub 2} become prominent for C/O {>=} 1, while the CO abundance remains almost unchanged. Furthermore, a C/O {>=} 1 can preclude a strong thermal inversion due to TiO and VO in a hot Jupiter atmosphere, since TiO and VO are naturally underabundant for C/O {>=} 1. We, therefore, suggest a new 2D classification scheme for hydrogen-dominated exoplanetary atmospheres with irradiation (or temperature) and C/O ratio as the two dimensions. We define four classes in this 2D space (O1, O2, C1, and C2) with distinct chemical, thermal, and spectral properties. Based on the most recent observations, we characterize the thermal structure and C/O ratios of six hot Jupiters (XO-1b, CoRoT-2b, WASP-14b, WASP-19b, WASP-33b, and WASP-12b) in the framework of our proposed 2D classification scheme. While the data for several systems in our sample are consistent with C-rich atmospheres, new observations are required to conclusively constrain their C/O ratios in the day side as well as the terminator regions of their atmospheres. We discuss how observations using existing and forthcoming facilities can constrain C/O ratios in exoplanetary atmospheres.« less

Tracer Transport Along a Vertical Fault Located in Welded Tuffs

NASA Astrophysics Data System (ADS)

Salve, R.; Liu, H.; Hu, Q.

2002-12-01

A near-vertical fault that intercepts the fractured welled tuff formation in the underground Exploratory Studies Facility (ESF) at Yucca Mountain, Nevada, has provided a unique opportunity to evaluate important hydrological parameters associated with faults (e.g., flow velocity, matrix diffusion, fault-fracture-matrix interactions). Alcove 8, which intersects the fault is located in the cross drift of the ESF, has been excavated for liquid releases through this fault and a network of fractures. Located 25 m below Alcove 8 in the main drift of the ESF, Niche 3 which also intercepts the fault, serves as the site for monitoring the wetting front and for collecting seepage following liquid releases in Alcove 8. To investigate the importance of matrix diffusion and the extent of area subject to fracture-matrix interactions, we released a mix of conservative tracers (pentafluorobenzoic acid [PFBA] and lithium bromide [LiBr]) along the fault. The ceiling of Niche 3 was blanketed with an array of trays to capture seepage, and seepage rates were continuously monitored by a water collection system connected to the trays. Additionally, a water sampling device, the passive-discreet water sampler (PDWS), was connected to three of the collections trays in Niche 3 into which water was seeping. The PDWS, designed to isolate continuous seepage from each tray into discreet samples for chemical analysis, remained connected to the trays over a period of three months. During this time, all water that seeped into the three trays was captured sequentially into sampling bottles and analyzed for concentrations of PFBA and LiBr. Water released along the fault initially traveled the 25 m vertical distance over a period of 36 days (at a velocity ~0.7 m/day). The seepage recovered in Niche 3 was less than 10% of the injected water with significant spatial and temporal fluctuations in seepage rates. Along a fast flow path, the benzoic tracer (PFBA) and LiBr were first detected ~12 days after they were released into the fault. Along slower flow paths the tracers appeared ~ two weeks later, with PFBA preceding the LiB. The differing travel times of the two conservative tracers suggests the impact of matrix diffusion in the transport process. This work was supported by the Director, Office of Civilian Radioactive Waste Management, U.S. Department of Energy, through Memorandum Purchase Order EA9013MC5X between Bechtel SAIC Company, LLC, and the Ernest Orlando Lawrence Berkeley National Laboratory (Berkeley Lab). The support is provided to Berkeley Lab through the U.S. Department of Energy Contract No. DE-AC03-76SF00098.

Submarine groundwater discharge in the Sarasota Bay system: Its assessment and implications for the nearshore coastal environment

NASA Astrophysics Data System (ADS)

Mwashote, B. M.; Murray, M.; Burnett, W. C.; Chanton, J.; Kruse, S.; Forde, A.

2013-02-01

A study was conducted from July 2002 through June 2006 in order to assess the significance of submarine groundwater discharge (SGD) to Sarasota Bay (SB), Florida. The assessment approaches used in this study included manual seepage meters, geochemical tracers (radon, 222Rn and methane, CH4), and subseafloor resistivity measurements. The estimated SGD advection rates in the SB system were found to range from 0.7 to 24.0 cm/day, except for some isolated hot spot occurrences where higher rates were observed. In general, SGD estimates were relatively higher (5.9-24.0 cm/day) in the middle and south regions of the bay compared to the north region (0.7-5.9 cm/day). Average dissolved inorganic nutrient concentrations within the SB water column ranged: 0.1-11 μM (NO2+NO3), 0.1-9.1 μM (NH4) and 0.2-1.4 μM (PO4). The average N/P ratio was higher in the north compared to the middle and south regions of the bay. On average, we conservatively estimate that about 27% of the total N in the SB system was derived via SGD. The prevalence of shallow embayed areas in the SB system and the presence of numerous septic tanks in the surrounding settlements enhanced the potential effects of nutrient rich seepages. Statistical comparison of the quantitative approaches revealed a good agreement between SGD estimates from manual seepage meters and those derived from the 222Rn model (p=0.67; α=0.05; n=18). CH4 was found to be useful for qualitative SGD assessments. CH4 and 222Rn were correlated (r2=0.31; α=0.05; n=54). Large scale resistivity surveys showed spatial variability that correlates more clearly with lithology than with SGD patterns.

A Study of the Effect of Hysteresis on Transient Seepage in Levees

NASA Astrophysics Data System (ADS)

Tracy, F. T.; Walshire, L. A.; Corcoran, M. K.

2016-12-01

The capability of modeling hysteresis in soils is not often provided in commercial 2-D finite element seepage programs. However, hysteresis can be important in the modeling process. This research shows the effect of hysteresis on transient seepage results for a generic levee common to the southeastern United States where moisture content and hydraulic conductivity curves for the unsaturated zone are modeled using van Genuchten drying curves only, wetting curves only, and hysteresis. Quantities measured are (1) a levee saturation coefficient that is zero when the river is at initial conditions and one when steady-state has been achieved at the maximum river elevation, (2) the pore pressure at the toe of the levee beneath the confining layer, and (3) flow rate through the downstream flux section. A model for switching from the wetting curve to the drying curve and visa versa for hysteresis has been implemented in a 2-D finite element program to perform the described research. The levee system is considered homogeneous in this study. The hydrograph of the river for a 20-foot levee begins at -5 ft, goes up at 1 ft/day until it reaches 17.5 ft, remains for 10 days, and then descends at 1 ft/day until the river reaches -5 ft again, giving a simulation time of 55 days. Saturated hydraulic conductivity values of 0.01, 0.001, and 0.0001 cm/sec were considered. Values of the three output variables for wetting only, drying only, and hysteresis curves for the 55 days were collected, and closeness coefficients in terms of percentages were defined and computed from the collected data. It was found that the closeness coefficient was as high as 24.61% for levee saturation coefficient, 5.15% for pore pressure, and 119.93% for flow rate. Clearly, it is important to consider hysteresis in the modeling process.

Ar + CO2 and He + CO2 Plasmas in ASTRAL

NASA Astrophysics Data System (ADS)

Boivin, R. F.; Gardner, A.; Munoz, J.; Kamar, O.; Loch, S.

2007-11-01

Spectroscopy study of the ASTRAL helicon plasma source running Ar + CO2 and He + CO2 gas mixes is presented. ASTRAL produces plasmas with the following parameters: ne = 10^10 - 10^13 cm-3, Te = 2 - 10 eV and Ti = 0.03 - 0.5 eV, B-field <= 1.3 kGauss, rf power <= 2 kWatt. A 0.33 m scanning monochromator is used for this study. Using Ar + CO2 gas mixes, very different plasmas are observed as the concentration of CO2 is changed. At low CO2 concentration, the bluish plasma is essentially atomic and argon transitions dominate the spectra. Weak C I and O I lines are present in the 750 - 1000 nm range. At higher CO2 concentration, the plasma becomes essentially molecular and is characterized by intense, white plasma columns. Here, spectra are filled with molecular bands (CO2, CO2^+, CO and CO^+). Limited molecular dissociative excitation processes associated with the production of C I and O I emission are also observed. On the other hand, He + CO2 plasmas are different. Here, rf matches are only possible at low CO2 concentration. Under these conditions, the spectra are characterized by strong C I and O I transitions with little or no molecular bands. Strong dissociative processes observed in these plasmas can be link to the high Te associated with He plasmas. An analysis of the spectra with possible scientific and industrial applications will be presented.

A sediment ecotoxicity assessment platform for in situ measures of chemistry, bioaccumulation and toxicity. Part 2: Integrated application to a shallow estuary.

PubMed

Rosen, Gunther; Chadwick, D Bart; Burton, G Allen; Taulbee, W Keith; Greenberg, Marc S; Lotufo, Guilherme R; Reible, Danny D

2012-03-01

A comprehensive, weight-of-evidence based ecological risk assessment approach integrating laboratory and in situ bioaccumulation and toxicity testing, passive sampler devices, hydrological characterization tools, continuous water quality sensing, and multi-phase chemical analyses was evaluated. The test site used to demonstrate the approach was a shallow estuarine wetland where groundwater seepage and elevated organic and inorganic contaminants were of potential concern. Although groundwater was discharging into the surficial sediments, little to no chemical contamination was associated with the infiltrating groundwater. Results from bulk chemistry analysis, toxicity testing, and bioaccumulation, however, suggested possible PAH toxicity at one station, which might have been enhanced by UV photoactivation, explaining the differences between in situ and laboratory amphipod survival. Concurrently deployed PAH bioaccumulation on solid-phase micro-extraction fibers positively correlated (r(2) ≥ 0.977) with in situ PAH bioaccumulation in amphipods, attesting to their utility as biomimetics, and contributing to the overall improved linkage between exposure and effects demonstrated by this approach. Published by Elsevier Ltd.

Synthesis, characterization and color performance of novel Co²+-doped alumina/titania nanoceramic pigments.

PubMed

Hafez, Hoda S; El-Fadaly, E

2012-09-01

Blue-green nanoceramic pigments from Co(2+)-doped alumina-titania (xCo(2+)-Al(2)O(3)/TiO(2)) have been synthesized by alkoxide sol-gel route from a mixture of titania and boehmite sols that derived from titanium isopropoxide and aluminum nitrate precursors. The composition of the alumina/titania (AT) matrix is 3:1M ratio. A series of xCo(2+):3TiO(2):1Al(2)O(3) mixed oxides with different Co(2+)-dopant ion concentration has been prepared. The molar ratio of the Co(2+)-dopant ion in the Al(2)O(3)/TiO(2) matrix is from x=0 to 0.5M ratio relative to the titania composition. Characterizations of Co(2+)-doped alumina/titania nanocomposites are carried out using reflectance spectroscopy, transmission electron microscope (TEM), scanning electron microscopy (SEM-EDS), thermo-gravimetric analysis (TGA) and X-ray diffractometer (XRD). The experimental results demonstrated that the prepared Co(2+)-doped alumina-titania nanocomposites fulfill the current technological requirements for ceramic pigment applications that exhibit a high physico-chemical and thermal stabilities at high firing temperatures. Copyright © 2012 Elsevier B.V. All rights reserved.

Short-term monitoring of a gas seep field in the Katakolo bay (Western Greece) using Raman spectra DTS and DAS fibre-optic methods

NASA Astrophysics Data System (ADS)

Chalari, A.; Mondanos, M.; Finfer, D.; Christodoulou, D.; Kordella, S.; Papatheodorou, G.; Geraga, M.; Ferentinos, G.

2012-12-01

A wide submarine seep of thermogenic gas in the Katakolo bay, Western Greece, was monitored passively using the intelligent Distributed Acoustic Sensor (iDAS) and Ultima Raman spectra Distributed Temperature Sensor (DTS), in order to study the thermal and noise signal of the bubble plumes released from the seafloor. Katakolo is one one of the most prolific thermogenic gas seepage zones in Europe and the biggest methane seep ever reported in Greece. Very detailed repetitive offshore gas surveys, including marine remote sensing (sub-bottom profiling, side scan sonar), underwater exploration by a towed instrumented system (MEDUSA), long-term monitoring benthic station (GMM), compositional and isotopic analyses, and flux measurements of gas, showed that: (a) gas seepage takes place over an extended area in the Katakolo harbour and along two main normal faults off the harbour; (b) at least 823 gas bubble ( 10-20 cm in diameter) plumes escaping over an area of 94,200 m2, at depths ranging from 5.5 to 16 m; (c) the gas consists mainly of methane and has H2S levels of hundreds to thousands ppmv, and shows significant amounts of other light hydrocarbons like ethane, propane, iso-butane and C6 alkanes, (d) offshore and onshore seeps release the same type of thermogenic gas; (e) due to the shallow depth, more than 90 % of CH4 released at the seabed enters the atmosphere, and (f) the gas seeps may produce severe geohazards for people, buildings and construction facilities due to the explosive and toxicological properties of methane and hydrogen sulfide, respectively. For the short-term monitoring, the deployment took place on a site located inside the harbour of Katakolo within a thermogenic gas seepage area where active faults are intersected. The iDAS system makes it possible to observe the acoustical signal along the entire length of an unmodified optical cable without introducing any form of point sensors such as Bragg gratings. When the bubble plumes are released by the seabed into the water column, they ring at their resonance frequency in a manner consistent with standard bubble acoustics. This bubble ringing can be detected by iDAS allowing for both seepage detection, quantification and relationship with seismic activity. The DTS system makes it possible to observe temporal variations of the gas plumes and its relationship with the meteorological factors of the area. Moreover, DTS and iDAS data interpretation needs a detailed examination in comparison with the long-term GMM monitoring data (O2, CH4, H2S, temperature, pressure and conductivity) which was collected from the same location. The processing chain used to observe this phenomenon can have applications in both industrial and environmental monitoring capacities.

Ion-beam mixed ultra-thin cobalt suicide (CoSi2) films by cobalt sputtering and rapid thermal annealing

NASA Astrophysics Data System (ADS)

Kal, S.; Kasko, I.; Ryssel, H.

1995-10-01

The influence of ion-beam mixing on ultra-thin cobalt silicide (CoSi2) formation was investigated by characterizing the ion-beam mixed and unmixed CoSi2 films. A Ge+ ion-implantation through the Co film prior to silicidation causes an interface mixing of the cobalt film with the silicon substrate and results in improved silicide-to-silicon interface roughness. Rapid thermal annealing was used to form Ge+ ion mixed and unmixed thin CoSi2 layer from 10 nm sputter deposited Co film. The silicide films were characterized by secondary neutral mass spectroscopy, x-ray diffraction, tunneling electron microscopy (TEM), Rutherford backscattering, and sheet resistance measurements. The experi-mental results indicate that the final rapid thermal annealing temperature should not exceed 800°C for thin (<50 nm) CoSi2 preparation. A comparison of the plan-view and cross-section TEM micrographs of the ion-beam mixed and unmixed CoSi2 films reveals that Ge+ ion mixing (45 keV, 1 × 1015 cm-2) produces homogeneous silicide with smooth silicide-to-silicon interface.

Preparation and Thermoelectric Properties of IR(sub x)Co(sub 1-x)Sb(sub 2) Alloys

NASA Technical Reports Server (NTRS)

Caillat, Thierry

1995-01-01

The preparation and characterization of the binary arsenopyrite compounds CoSb2 and IrSb2 and IrxCo1-xSb2 alloys is reported. Single crystals of CoSb2 were grown by the vertical gradient freeze technique from solution rich in antimony. Polycrystalline samples of IrSb2 and IrxCo1-xSb2 alloys were prepared by hot-pressing of prereacted elemental powders. Samples were investigated by X-ray diffractometry, microprobe analysis and density measurements. It was found that a range of solid solution exist in the system IrxCo1-xSb2 for 0.1

Gas separation performance of carbon molecular sieve membranes based on 6FDA-mPDA/DABA (3:2) polyimide.

PubMed

Qiu, Wulin; Zhang, Kuang; Li, Fuyue Stephanie; Zhang, Ke; Koros, William J

2014-04-01

6FDA-mPDA/DABA (3:2) polyimide was synthesized and characterized for uncross-linked, thermally crosslinked, and carbon molecular sieve (CMS) membranes. The membranes were characterized with thermogravimetric analysis, FTIR spectroscopy, wide-angle X-ray diffraction, and gas permeation tests. Variations in the d spacing, the formation of pore structures, and changes in the pore sizes of the CMS membranes were discussed in relation to pyrolysis protocols. The uncross-linked polymer membranes showed high CO2 /CH4 selectivity, whereas thermally crosslinked membranes exhibited significantly improved CO2 permeability and excellent CO2 plasticization resistance. The CMS membranes showed even higher CO2 permeability and CO2 /CH4 selectivity. An increase in the pyrolysis temperature resulted in CMS membranes with lower gas permeability but higher selectivity. The 550 °C pyrolyzed CMS membranes showed CO2 permeability as high as 14 750 Barrer with CO2 /CH4 selectivity of approximately 52. Even 800 °C pyrolyzed CMS membranes still showed high CO2 permeability of 2610 Barrer with high CO2 /CH4 selectivity of approximately 118. Both polymer membranes and the CMS membranes are very attractive in aggressive natural gas purification applications. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Enhanced characterization of faults and fractures at EGS sites by CO2 injection coupled with active seismic monitoring, pressure-transient testing, and well logging

NASA Astrophysics Data System (ADS)

Oldenburg, C. M.; Daley, T. M.; Borgia, A.; Zhang, R.; Doughty, C.; Jung, Y.; Altundas, B.; Chugunov, N.; Ramakrishnan, T. S.

2016-12-01

Faults and fractures in geothermal systems are difficult to image and characterize because they are nearly indistinguishable from host rock using traditional seismic and well-logging tools. We are investigating the use of CO2 injection and production (push-pull) in faults and fractures for contrast enhancement for better characterization by active seismic, well logging, and push-pull pressure transient analysis. Our approach consists of numerical simulation and feasibility assessment using conceptual models of potential enhanced geothermal system (EGS) sites such as Brady's Hot Spring and others. Faults in the deep subsurface typically have associated damage and gouge zones that provide a larger volume for uptake of CO2 than the slip plane alone. CO2 injected for push-pull well testing has a preference for flowing in the fault and fractures because CO2 is non-wetting relative to water and the permeability of open fractures and fault gouge is much higher than matrix. We are carrying out numerical simulations of injection and withdrawal of CO2 using TOUGH2/ECO2N. Simulations show that CO2 flows into the slip plane and gouge and damage zones and is driven upward by buoyancy during the push cycle over day-long time scales. Recovery of CO2 during the pull cycle is limited because of buoyancy effects. We then use the CO2 saturation field simulated by TOUGH2 in our anisotropic finite difference code from SPICE-with modifications for fracture compliance-that we use to model elastic wave propagation. Results show time-lapse differences in seismic response using a surface source. Results suggest that CO2 can be best imaged using time-lapse differencing of the P-wave and P-to-S-wave scattering in a vertical seismic profile (VSP) configuration. Wireline well-logging tools that measure electrical conductivity show promise as another means to detect and image the CO2-filled fracture near the injection well and potential monitoring well(s), especially if a saline-water pre-flush is carried out to enhance conductivity contrast. Pressure-transient analysis is also carried out to further constrain fault zone characteristics. These multiple complementary characterization approaches are being used to develop working models of fault and fracture zone characteristics relevant to EGS energy recovery.

Conditions for the formation and atmospheric dispersion of a toxic, heavy gas layer during thermal metamorphism of coal and evaporite deposits by sill intrusion

NASA Astrophysics Data System (ADS)

Storey, Michael; Hankin, Robin K. S.

2010-05-01

There is compelling evidence for massive discharge of volatiles, including toxic species, into the atmosphere at the end of the Permian. It has been argued that most of the gases were produced during thermal metamorphism of coal and evaporite deposits in the East Siberia Tunguska basin following sill intrusion (Retallack and Jahren, 2008; Svensen et al., 2009). The release of the volatiles has been proposed as a major cause of environmental and extinction events at the end of the Permian, with venting of carbon gases and halocarbons to the atmosphere leading to global warming and atmospheric ozone depletion (Svensen et al., 2009) Here we consider the conditions required for the formation and dispersion of toxic, heavier than air, gas plumes, made up of a mixture of CO2, CH4, H2S and SO2 and formed during the thermal metamorphism of C- and S- rich sediments. Dispersion models and density considerations within a range of CO2/CH4 ratios and volatile fluxes and temperatures, for gas discharge by both seepage and from vents, allow the possibility that following sill emplacement much of the vast East Siberia Tunguska basin was - at least intermittently - covered by a heavy, toxic gas layer that was unfavorable for life. Dispersion scenarios for a heavy gas layer beyond the Siberian region during end-Permian times will be presented. REFERENCES G. J. Retallack and A. H. Jahren, Methane release from igneous intrusion of coal during Late Permian extinction events, Journal of Geology, volume 116, 1-20, 2008 H. Svensen et al., Siberian gas venting and the end-Permian environmental crisis, Earth and Planetary Science Letters, volume 277, 490-500, 2009

Chemistry of group 9 dimetallaborane analogues of octaborane(12).

PubMed

Barik, Subrat Kumar; Roy, Dipak Kumar; Ghosh, Sundargopal

2015-01-14

We report the synthesis, isolation and structural characterization of several moderately air stable nido-metallaboranes that represent boron rich open cage systems. The reaction of [Cp*CoCl]2, (Cp* = η(5)-C5Me5), with [BH3·thf] in toluene at ice cold temperature, followed by thermolysis in boiling toluene produced [(Cp*Co)B9H13], 1 [(Cp*Co)2B8H12], 2 and [(Cp*Co)2B6H10] 3. Building upon our earlier reactivity studies on rhodaboranes, we continue to explore the reactivity of dicobalt analogues of octaborane(12) cluster 3 with [Fe2(CO)9] and [Ru3(CO)12] at ambient conditions that yielded novel fused clusters [Fe2(CO)6(Cp*Co)2B6H10], 4 and [Ru4(CO)11(Cp*Co)2B3H3], 5 respectively. In an attempt to synthesize a heterometallic metallaborane compound we performed the reaction of [(Cp*Rh)2B6H10], 6 with [Cp*IrH4] that yielded a Ir-Ir double bonded compound [(Cp*Ir)2H3][B(OH)4], 7. All the new compounds have been characterized by IR, (1)H, (11)B, (13)C NMR spectroscopy, and the molecular structures were unambiguously established by X-ray diffraction analysis.

Modeling of time-lapse multi-scale seismic monitoring of CO2 injected into a fault zone to enhance the characterization of permeability in enhanced geothermal systems

NASA Astrophysics Data System (ADS)

Zhang, R.; Borgia, A.; Daley, T. M.; Oldenburg, C. M.; Jung, Y.; Lee, K. J.; Doughty, C.; Altundas, B.; Chugunov, N.; Ramakrishnan, T. S.

2017-12-01

Subsurface permeable faults and fracture networks play a critical role for enhanced geothermal systems (EGS) by providing conduits for fluid flow. Characterization of the permeable flow paths before and after stimulation is necessary to evaluate and optimize energy extraction. To provide insight into the feasibility of using CO2 as a contrast agent to enhance fault characterization by seismic methods, we model seismic monitoring of supercritical CO2 (scCO2) injected into a fault. During the CO2 injection, the original brine is replaced by scCO2, which leads to variations in geophysical properties of the formation. To explore the technical feasibility of the approach, we present modeling results for different time-lapse seismic methods including surface seismic, vertical seismic profiling (VSP), and a cross-well survey. We simulate the injection and production of CO2 into a normal fault in a system based on the Brady's geothermal field and model pressure and saturation variations in the fault zone using TOUGH2-ECO2N. The simulation results provide changing fluid properties during the injection, such as saturation and salinity changes, which allow us to estimate corresponding changes in seismic properties of the fault and the formation. We model the response of the system to active seismic monitoring in time-lapse mode using an anisotropic finite difference method with modifications for fracture compliance. Results to date show that even narrow fault and fracture zones filled with CO2 can be better detected using the VSP and cross-well survey geometry, while it would be difficult to image the CO2 plume by using surface seismic methods.

Studies on the Condensation Pathway to and Properties of Diiron Azadithiolate Carbonyls

PubMed Central

Stanley, Jane L.; Rauchfuss, Thomas B.; Wilson, Scott R.

2008-01-01

Reaction of Fe2(SH)2(CO)6 and HCHO, which gives Fe2[(SCH2)2NH](CO)6 in the presence of NH3, affords the possible intermediate Fe2(SCH2OH)2(CO)6, which has been characterized crystallographically as its axial–equatorial isomer. Fe2(SCH2OH)2(CO)6 was shown to react with ammonia and amines to give Fe2[(SCH2)2NR](CO)6 (R = H, alkyl). Related hemithioacetal intermediates were generated by treatment of Fe2(SH)2(CO)6 with RC(O)C(O)R (R = H, Ph, 4-F-C6H4) to give cycloadducts. The benzil derivative Fe2[S2C2(OH)2Ph2](CO)6, a C2-symmetric species, was also characterized crystallographically. The acylated azadithiolate Fe2[(SCH2)2NAc](CO)6 was prepared by reaction of Li2Fe2S2(CO)6 with (ClCH2)2NC(O)Me. DNMR experiments show that the free energies of activation for rotation of the amide bond are the same for Fe2[(SCH2)2NAc](CO)6 and Fe2[(SCH2)2NAc](CO)4(PMe3)2, which implies that the ligands on the iron centers do not strongly affect the basicity of the nitrogen. As a control, we showed that the thioamide Fe2[(SCH2)2NC(S)Me](CO)6 does exhibit a significantly higher barrier to rotation, attributable to the increased double-bond character of the N–C(S) bond. PMID:18592045

Improved Characterization and Modeling of Tight Oil Formations for CO 2 Enhanced Oil Recovery Potential and Storage Capacity Estimation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sorensen, James; Smith, Steven; Kurz, Bethany

Tight oil formations such as those in the Bakken petroleum system are known to hold hundreds of billions of barrels of oil in place; however, the primary recovery factor for these plays is typically less than 10%. Tight oil formations, including the Bakken Formation, therefore, may be attractive candidates for enhanced oil recovery (EOR) using CO 2. Multiphase fluid behavior and flow in fluid-rich shales can vary substantially depending on the size of pore throats, and properties such as fluid viscosity and density are much different in nanoscale pores than in macroscale pores. Thus it is critical to understand themore » nature and distribution of nano-, micro-, and macroscale pores and fracture networks. To address these issues, the Energy & Environmental Research Center (EERC) has been conducting a research program entitled “Improved Characterization and Modeling of Tight Oil Formations for CO 2 Enhanced Oil Recovery Potential and Storage Capacity Estimation.” The objectives of the project are 1) the use of advanced characterization methods to better understand and quantify the petrophysical and geomechanical factors that control CO 2 and oil mobility within tight oil formation samples, 2) the determination of CO 2 permeation and oil extraction rates in tight reservoir rocks and organic-rich shales of the Bakken, and 3) the integration of the laboratory-based CO 2 permeation and oil extraction data and the characterization data into geologic models and dynamic simulations to develop predictions of CO 2 storage resource and EOR in the Bakken tight oil formation. A combination of standard and advanced petrophysical characterization techniques were applied to characterize samples of Bakken Formation tight reservoir rock and shales from multiple wells. Techniques included advanced computer tomography (CT) imaging, scanning electron microscopy (SEM) techniques, whole-core and micro x-ray CT imaging, field emission (FE) SEM, and focused ion beam (FIB) SEM. Selected samples were also analyzed for geomechanical properties. X-ray CT imaging yielded information on the occurrence of fractures, bedding planes, fossils, and bioturbation in core, as well as data on bulk density and photoelectric factor logs, which were used to interpret porosity, organic content, and mineralogy. FESEM was used for characterization of nano- and microscale features, including nanoscale pore visualization and micropore and pore throat mineralogy. FIBSEM yielded micro- to nanoscale visualization of fracture networks, porosity and pore-size distribution, connected versus isolated porosity, and distribution of organics. Results from the characterization activities provide insight on nanoscale fracture properties, pore throat mineralogy and connectivity, rock matrix characteristics, mineralogy, and organic content. Laboratory experiments demonstrated that CO 2 can permeate the tight matrix of Bakken shale and nonshale reservoir samples and mobilize oil from those samples. Geologic models were created at scales ranging from the core plug to the reservoir, and dynamic simulations were conducted. The data from the characterization and laboratory-based activities were integrated into modeling research activities to determine the fundamental mechanisms controlling fluid transport in the Bakken, which support EOR scheme design and estimation of CO 2 storage potential in tight oil formations. Simulation results suggest a CO 2 storage resource estimate range of 169 million to 1.5 billion tonnes for the Bakken in North Dakota, possibly resulting in 1.8 billion to 16 billion barrels of incremental oil.« less

Thermal and Evolved Gas Analysis of "Nanophase" Carbonates: Implications for Thermal and Evolved Gas Analysis on Mars Missions

NASA Technical Reports Server (NTRS)

Lauer, Howard V., Jr.; Archer, P. D., Jr.; Sutter, B.; Niles, P. B.; Ming, Douglas W.

2012-01-01

Data collected by the Mars Phoenix Lander's Thermal and Evolved Gas Analyzer (TEGA) suggested the presence of calcium-rich carbonates as indicated by a high temperature CO2 release while a low temperature (approx.400-680 C) CO2 release suggested possible Mg- and/or Fe-carbonates [1,2]. Interpretations of the data collected by Mars remote instruments is done by comparing the mission data to a database on the thermal properties of well-characterized Martian analog materials collected under reduced and Earth ambient pressures [3,4]. We are proposing that "nano-phase" carbonates may also be contributing to the low temperature CO2 release. The objectives of this paper is to (1) characterize the thermal and evolved gas proper-ties of carbonates of varying particle size, (2) evaluate the CO2 releases from CO2 treated CaO samples and (3) examine the secondary CO2 release from reheated calcite of varying particle size.

Interactive Effects of CO2 and O2 in Soil on Root and Top Growth of Barley and Peas

PubMed Central

Geisler, G.

1967-01-01

Barley and pea plants were grown under several regimens of different compositions of soil atmosphere, the O2 concentration varying from 0 to 21% and the CO2 concentration from 0 to 8%. In absence of CO2, the effect of O2 on root length in barley was characterized by equal root lengths within the range of 21 to 7% O2 and a steep decline between 7 and 0%. In peas, while showing the same general response, the decline occurred between 14 and 7% O2. Root numbers of the seminal roots of barley decreased already with reduction in O2 concentration from 21 to 14%. Dry matter production was affected somewhat differently by O2 and CO2 concentration. Dry matter production in barley was reduced at 14% O2 while root length decreased between 7 and 0%. In peas, dry matter production was favored by low CO2 concentrations except where there was no oxygen. At 21% O2, increasing CO2 concentrations did not seem to affect root length up to concentrations of 2% CO2. At 8% CO2, root length was decreased. The inter-active effects of CO2 and O2 are characterized by a reduced susceptibility to CO2 at O2 values below 7%, and a very deleterious effect of 8% CO2 at 7% O2. PMID:16656508

W-Incorporated CoMo/{lambda}-Al{sub 2}O{sub 3} hydrosulfurization catalyst. II. Characterization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, D.K.; Lee, H.T.

1996-03-01

Series of W-incorporated CoMo/{gamma}-Al{sub 2}O{sub 3} catalysts were characterized with TPR, DRS, ESR, and XPS. Two series of catalysts with varying content of tungsten were prepared for characterization by changing the impregnation order of cobalt and tungsten to a base Mo/{gamma}-Al{sub 2}O{sub 3} catalyst. The activity promotion by relatively low content of tungsten arose from the roles of tungsten in changing the Mo-oxide coordination from tetrahedral to octahedral, facilitating the reduction of Mo-oxide species, and increasing the dispersion of MoS{sub 2}. By incorporation of tungsten at a content as much as 0.025 in W/(W + Mo) atomic ratio, the MoS{submore » 2} dispersion of CoMo/{gamma}-Al{sub 2}O{sub 3} catalyst was considered to be maximized without noticeable detriment to the active Co-Mo-O phase, resulting in the maximum activity promotion. The formation of the Co-Mo-O phases was more favored in the catalysts prepared by impregnating W onto CoMo/{gamma}-Al{sub 2}O{sub 3} than in those by impregnating W onto Mo/{gamma}-Al{sub 2}O{sub 3} before impregnation of Co. The effect of tungsten on the dispersion of active phase was not discriminated between the two series of catalysts. The activity decrease observed in the catalysts containing higher content of tungsten originated from the increase in the W-oxide coverage on the surface of Mo-oxides or Co-Mo-O phases, resulting in not only impeding the reduction or sulfidation of the oxidic precursor but facilitating the formation of less active Co-W-O at the sacrifice of more active Co-Mo-O phase. 40 refs., 11 figs., 1 tab.« less

Biogenic methane leakage on the Aquitaine Shelf: fluid system characterization from source to emission

NASA Astrophysics Data System (ADS)

Michel, Guillaume; Dupré, Stéphanie; Baltzer, Agnès; Imbert, Patrice; Ehrhold, Axel; Battani, Anne; Deville, Eric

2017-04-01

The recent discovery of biogenic methane emissions associated with methane-derived authigenic carbonate mounds along the Aquitaine Shelf edge offshore SW France (140 to 220 m water depth) questions about the initiation and temporal evolution of this fluid system (80 km N-S and 8 km E-W). Based on a multi-data study (including multibeam echosounder, subbottom profiler, single channel sparker seismic, 80 traces air gun seismic data and well cuttings and logs), different scenarii are proposed for the organic matter source levels and migration pathways of the methane. Several evidence of the presence of gas are observed on seismic data and interpreted to be linked to the biogenic system. Single channel sparker seismic lines exhibit an acoustic blanking (between 75-100 ms TWT below seafloor and the first multiple) below the present-day seepage area and westwards up to 8 km beyond the shelf-break. An air gun seismic line exhibits chaotic reflections along 8 km below the seepage area from the seabed down to 700 ms TWT below seafloor. Based on 1) the local geothermal gradient about 26 °C/km and 2) the window for microbial methanogenesis ranging from 4 to 56 °C, the estimation of the bottom limit for biogenic generation window is about 1.5 km below seafloor. Cuttings from 3 wells of the area within the methanogenesis window show average TOC (Total Organic Carbon) of 0.5 %; however, one well shows some coal levels with 30-35 % TOC in the Oligocene between 1490 and 1540 m below seafloor. Geochemical analysis on crushed cuttings evidenced heavy hydrocarbons up to mid-Paleogene, while shallower series did not evidence any. In the first scenario, we propose that methane is sourced from the Neogene prograding system. The 0.5% average TOC is sufficient to generate a large volume of methane over the thickness of this interval (up to 1 km at the shelf break area). In the second scenario, methane would be sourced from the Oligocene coals; however their spatial extension with regard to available data is too limited to supply the gas system along 80 km from north to south. The third scenario corresponds to methane production in the early Paleogene and Cretaceous source levels; but evidence for heavy hydrocarbons is not consistent with the isotopic signatures of the gases seeping at the seabed. The first scenario is therefore the most coherent one even if the TOC is relatively low in the Neogene formations. Regarding the fluid system geometry and the associated source level position, migration pathways may involve 1) upslope migration from the base of the Neogene clinoforms, 2) sub-vertical migration through faults and fractures at the shelf edge, and 3) groundwater circulation from onshore forcing methane migration westward through hydrodynamism. The PhD thesis of Guillaume Michel as well as the oceanographic expeditions Gazcogne1 (http://dx.doi.org/10.17600/13020070) and Gazcogne2 (http://dx.doi.org/10.17600/13030090) are co-funded by TOTAL and IFREMER as part of the PAMELA (Passive Margin Exploration Laboratories) scientific project.

Enhancement of C-H Oxidizing Ability in Co-O2  Complexes through an Isolated Heterobimetallic Oxo Intermediate.

PubMed

DeRosha, Daniel E; Mercado, Brandon Q; Lukat-Rodgers, Gudrun; Rodgers, Kenton R; Holland, Patrick L

2017-03-13

The characterization of intermediates formed through the reaction of transition-metal complexes with dioxygen (O 2 ) is important for understanding oxidation in biological and synthetic processes. Here, the reaction of the diketiminate-supported cobalt(I) complex L tBu Co with O 2 gives a rare example of a side-on dioxygen complex of cobalt. Structural, spectroscopic, and computational data are most consistent with its assignment as a cobalt(III)-peroxo complex. Treatment of L tBu Co(O 2 ) with low-valent Fe and Co diketiminate complexes affords isolable oxo species with M 2 O 2 "diamond" cores, including the first example of a crystallographically characterized heterobimetallic bis(μ-oxo) complex of two transition metals. The bimetallic species are capable of cleaving C-H bonds in the supporting ligands, and kinetic studies show that the Fe/Co heterobimetallic species activates C-H bonds much more rapidly than the Co/Co homobimetallic analogue. Thus heterobimetallic oxo intermediates provide a promising route for enhancing the rates of oxidation reactions. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Synthesis and characterization of fac-[M(CO)3(P)(OO)] and cis-trans-[M(CO)2(P)2(OO)] complexes (M = Re, (99m)Tc) with acetylacetone and curcumin as OO donor bidentate ligands.

PubMed

Triantis, Charalampos; Tsotakos, Theodoros; Tsoukalas, Charalampos; Sagnou, Marina; Raptopoulou, Catherine; Terzis, Aris; Psycharis, Vassilis; Pelecanou, Maria; Pirmettis, Ioannis; Papadopoulos, Minas

2013-11-18

The synthesis and characterization of neutral mixed ligand complexes fac-[M(CO)3(P)(OO)] and cis-trans-[M(CO)2(P)2(OO)] (M = Re, (99m)Tc), with deprotonated acetylacetone or curcumin as the OO donor bidentate ligands and a phosphine (triphenylphosphine or methyldiphenylphosphine) as the monodentate P ligand, is described. The complexes were synthesized through the corresponding fac-[M(CO)3(H2O)(OO)] (M = Re, (99m)Tc) intermediate aqua complex. In the presence of phosphine, replacement of the H2O molecule of the intermediate complex at room temperature generates the neutral tricarbonyl monophosphine fac-[Re(CO)3(P)(OO)] complex, while under reflux conditions further replacement of the trans to the phosphine carbonyl generates the new stable dicarbonyl bisphosphine complex cis-trans-[Re(CO)2(P)2(OO)]. The Re complexes were fully characterized by elemental analysis, spectroscopic methods, and X-ray crystallography showing a distorted octahedral geometry around Re. Both the monophosphine and the bisphosphine complexes of curcumin show selective binding to β-amyloid plaques of Alzheimer's disease. At the (99m)Tc tracer level, the same type of complexes, fac-[(99m)Tc(CO)3(P)(OO)] and cis-trans-[(99m)Tc(CO)2(P)2(OO)], are formed introducing new donor combinations for (99m)Tc(I). Overall, β-diketonate and phosphine constitute a versatile ligand combination for Re(I) and (99m)Tc(I), and the successful employment of the multipotent curcumin as β-diketone provides a solid example of the pharmacological potential of this system.

FIELD STUDY OF THE IMPACT OF A GASOHOL SPILL ON NATURAL ATTENUATION OF PRE-EXISTING BTEX/MTBE CONTAMINATION (VANDENBERG AFB, CALIFORNIA)

EPA Science Inventory

(1) Measure the seepage velocity of the ground water using travel time of tracers to monitoring wells.
(2) Measure the concentration of benzene, the other BTEX compounds, and ethanol in monitoring wells along the flow path of the tracer plume.
(3) Calculate and compare ...

Characterization of CG6178 gene product with high sequence similarity to firefly luciferase in Drosophila melanogaster.

PubMed

Oba, Yuichi; Ojika, Makoto; Inouye, Satoshi

2004-03-31

This is the first identification of a long-chain fatty acyl-CoA synthetase in Drosophila by enzymatic characterization. The gene product of CG6178 (CG6178) in Drosophila melanogaster genome, which has a high sequence similarity to firefly luciferase, has been expressed and characterized. CG6178 showed long-chain fatty acyl-CoA synthetic activity in the presence of ATP, CoA and Mg(2+), suggesting a fatty acyl adenylate is an intermediate. Recently, it was revealed that firefly luciferase has two catalytic functions, monooxygenase (luciferase) and AMP-mediated CoA ligase (fatty acyl-CoA synthetase). However, unlike firefly luciferase, CG6178 did not show luminescence activity in the presence of firefly luciferin, ATP, CoA and Mg(2+). The enzymatic properties of CG6178 including substrate specificity, pH dependency and optimal temperature were close to those of firefly luciferase and rat fatty acyl-CoA synthetase. Further, phylogenic analyses strongly suggest that the firefly luciferase gene may have evolved from a fatty acyl-CoA synthetase gene as a common ancestral gene.

Preparation, Characterization, and Catalytic Activity of MoCo/USY Catalyst on Hydrodeoxygenation Reaction of Anisole

NASA Astrophysics Data System (ADS)

Nugrahaningtyas, K. D.; Suharbiansah, R. S. R.; Rahmawati, F.

2018-03-01

This research aims to prepare, characterize, and study the catalytic activity of Molybdenum (Mo) and Cobalt (Co) metal with supporting material Ultra Stable Y-Zeolite (USY), to produce catalysts with activity in hydrotreatment reaction and in order to eliminate impurities compounds that containing unwanted groups heteroatoms. The bimetallic catalysts MoCo/USY were prepared by wet impregnation method with weight variation of Co metal 0%, 2%, 4%, 6%, 8%, and Mo metal 8% (w/w), respectively. Activation method of the catalyst included calcination, oxidation, reduction and the crystallinity was characterized using X-ray diffraction (XRD), the acidity of the catalyst was analyzed using Fourier Transform Infrared Spectroscopy (FT-IR) and gravimetry method, minerals present in the catalyst was analyzed using X-Ray Fluorescence (XRF), and surface of the catalyst was analyzed using Surface Area Analyzer (SAA). Catalytic activity test (benzene yield product) of MoCo/USY on hydrodeoxigenation reaction of anisole aimed to determine the effect of Mo-Co/USY for catalytic activity in the reaction hydrodeoxigenation (HDO) anisole. Based on characterization and test of catalytic activity, it is known that catalytic of MoCo/USY 2% (catalyst B) shows best activities with acidity of 10.209 mmol/g, specific area of catalyst of 426.295 m2/g, pore average of 14.135 Å, total pore volume 0.318 cc/g, and total yield of HDO products 6.06%.

Origin of dolostone reservoir rocks, Smackover Formation (Oxfordian), northeastern Gulf Coast, U. S. A

DOE Office of Scientific and Technical Information (OSTI.GOV)

Prather, B.E.

Formation of regionally extensive dolostone reservoir rocks in the Smackover can be understood despite the possible effects of recrystallization. Geochemical and petrographic data suggest that dolomitization took place in (1) seawater-seepage, (2) reflux, (3) near-surface mixed-water, (4) shallow-burial mixed-water, and (5) deeper burial environments, which overlapped in time and space to form a platform-scale' dolostone body composed of a complex mixture of dolomites. Seawater-seepage and reflux dolomitization occurred in the near surface penecontemporaneously with deposition of the Smackover and overlying Haynesville Formations. Dolomitization by seawater seepage occurred within an oolite grainstone sill which separated an intraplatform salt basin from themore » open sea. Seawater flowed landward through the sill in response to evaporitic drawdown of brines in the isolated intraplatform basin. Isolation of the salt basin occurred during the Oxfordian when the shoreline retreated from the Conecuh embayment. Dolomite located at the top of the Smackover enriched in {sup 18}O suggests additional dolomitization by reflux of hypersaline brines. Reflux occurred as Buckner coastal sabkhas prograded over Smackover oolite grainstone shoreface deposits. Vugs lined with shallow-burial calcite and dolomite cements indicate flushing of the Smackover grainstone aquifer with fresh water. Freshwater intrusion probably occurred following sea level lowstands during the Late Jurassic and Early Cretaceous. Leaching in the proximal portion of the freshwater aquifer produced excellent limestone reservoir rocks in the updip Smackover. Dolomitization in the contemporaneous downdip mixed connate/freshwater zone formed dolostone reservoir rocks with depleted isotopic compositions consistent with a shallow-burial mixed-water origin.« less

Impact of Neotectonic activities on coral reef Red Sea Egypt; Case study Jubal Island

NASA Astrophysics Data System (ADS)

Hamouda, A.

2016-12-01

Abstract:The Red Sea considered the youngest oceanic basin of the world. It separates the Arabian sub-plate from the African plate. Neotectonic activity is a fundamental issue at the northern Red Sea for our understanding of the tectonic hazards at this region. The tectonic activity research will thus be geared to understand how a single tectonic process works and how a group of processes work together as a part of larger system ultimately leading to the formation of mountain systems and evolution of the solid earth. The recent seismic activity in the northern Red Sea has been impact on surface geology and coral reef. The most major earthquake swarm sequence around Jubal Island is the migration of epicenters northward in diameter circle about 50 km with focal depths less than 2 to 15 km. This swarm may release energy that can be accumulated to cause larger events in the future. This affects the accumulation of oil and gas reservoir causing natural seepage on the seafloor. The main aim of this study represents the impact of this seepage which is related to tectonic activity on the coral reef states at the northern part of Red Sea. The greatest impact of crude oil on marine organisms are categorized as: direct lethal toxicity, sub-lethal disruption of physiological behavioral activities, effects of direct coating, incorporation of hydrocarbons and alteration of habitat, especially substrate character. Adult marine organisms may exhibit lethal toxic and Sub-lethal effects from exposures to soluble aromatic derivative hydrocarbons. Keywords: Neotectonic activity, earthquakes, hydrocarbon seepage, coral reef, Red Sea.

Geological and geophysical investigation of water leakage from two micro-dam reservoirs: Implications for future site selection, northern Ethiopia

NASA Astrophysics Data System (ADS)

Berhane, Gebremedhin; Amare, Mogos; Gebreyohannes, Tesfamichael; Walraevens, Kristine

2017-05-01

Water resources are essential to human development activities and to eradicate extreme poverty and hunger. Geological problems of two water harvesting Micro-Dam Reservoirs (MDRs) were evaluated from leakage perspectives in the northern part of Ethiopia, East Africa. Conventional geological mapping, discontinuity and weathering descriptions, test pits and geophysical methods were used to characterize the hydrogeological features of the MDRs. Vertical Electrical Sounding (VES) and Electrical Profiling (EP), were executed using Terrameter SAS (signal averaging system) 1000 manufactured by ABEM, Sweden, with Schlumberger and Wenner array configuration respectively. It was concluded that the foundations of both MDRs, except the right abutment for Adishuhu which is partly composed of dolerite, are pervious due to the presence of thin bedding planes, joints, weathered materials and fault. The presence of water in the downstream toe of the MDRs, at depressions, existing test pits and test pits excavated during the present study which lie within the seepage zone demarcated during surface geological mapping, correspond with the electrical resistivity study. The results of the electrical resistivity survey (EP and VES) were merged with the geological and structural mapping and the observation of seepage zones, for the delineation of weak zones responsible for leakage. Monitoring of the leakage (reservoir water and groundwater levels), both manually and using automatic divers, is recommended, along with monitoring of the stability of the embankments and the discharge or flow downstream of the MDRs.

Microbial life in a liquid asphalt desert.

PubMed

Schulze-Makuch, Dirk; Haque, Shirin; de Sousa Antonio, Marina Resendes; Ali, Denzil; Hosein, Riad; Song, Young C; Yang, Jinshu; Zaikova, Elena; Beckles, Denise M; Guinan, Edward; Lehto, Harry J; Hallam, Steven J

2011-04-01

Pitch Lake in Trinidad and Tobago is a natural asphalt reservoir nourished by pitch seepage, a form of petroleum that consists of mostly asphaltines, from the surrounding oil-rich region. During upward seepage, pitch mixes with mud and gases under high pressure, and the lighter portion evaporates or is volatilized, which produces a liquid asphalt residue characterized by low water activity, recalcitrant carbon substrates, and noxious chemical compounds. An active microbial community of archaea and bacteria, many of them novel strains (particularly from the new Tar ARC groups), totaling a biomass of up to 10(7) cells per gram, was found to inhabit the liquid hydrocarbon matrix of Pitch Lake. Geochemical and molecular taxonomic approaches revealed diverse, novel, and deeply branching microbial lineages with the potential to mediate anaerobic hydrocarbon degradation processes in different parts of the asphalt column. In addition, we found markers for archaeal methane metabolism and specific gene sequences affiliated with facultative and obligate anaerobic sulfur- and nitrite-oxidizing bacteria. The microbial diversity at Pitch Lake was found to be unique when compared to microbial communities analyzed at other hydrocarbon-rich environments, which included Rancho Le Brea, a natural asphalt environment in California, USA, and an oil well and a mud volcano in Trinidad and Tobago, among other sites. These results open a window into the microbial ecology and biogeochemistry of recalcitrant hydrocarbon matrices and establish the site as a terrestrial analogue for modeling the biotic potential of hydrocarbon lakes such as those found on Saturn's largest moon Titan.

Seafloor geomorphic manifestations of gas venting and shallow subbottom gas hydrate occurrences

USGS Publications Warehouse

Paull, C K; Caress, D W; Thomas, Hans; Lundsten, Eve M.; Anderson, Kayce; Gwiazda, Roberto; Riedel, M; McGann, Mary; Herguera, J C

2015-01-01

High-resolution multibeam bathymetry data collected with an autonomous underwater vehicle (AUV) complemented by compressed high-intensity radar pulse (Chirp) profiles and remotely operated vehicle (ROV) observations and sediment sampling reveal a distinctive rough topography associated with seafloor gas venting and/or near-subsurface gas hydrate accumulations. The surveys provide 1 m bathymetric grids of deep-water gas venting sites along the best-known gas venting areas along the Pacific margin of North America, which is an unprecedented level of resolution. Patches of conspicuously rough seafloor that are tens of meters to hundreds of meters across and occur on larger seafloor topographic highs characterize seepage areas. Some patches are composed of multiple depressions that range from 1 to 100 m in diameter and are commonly up to 10 m deeper than the adjacent seafloor. Elevated mounds with relief of >10 m and fractured surfaces suggest that seafloor expansion also occurs. Ground truth observations show that these areas contain broken pavements of methane-derived authigenic carbonates with intervening topographic lows. Patterns seen in Chirp profiles, ROV observations, and core data suggest that the rough topography is produced by a combination of diagenetic alteration, focused erosion, and inflation of the seafloor. This characteristic texture allows previously unknown gas venting areas to be identified within these surveys. A conceptual model for the evolution of these features suggests that these morphologies develop slowly over protracted periods of slow seepage and shows the impact of gas venting and gas hydrate development on the seafloor morphology.

Microbial Life in a Liquid Asphalt Desert

NASA Astrophysics Data System (ADS)

Schulze-Makuch, Dirk; Haque, Shirin; de Sousa Antonio, Marina Resendes; Ali, Denzil; Hosein, Riad; Song, Young C.; Yang, Jinshu; Zaikova, Elena; Beckles, Denise M.; Guinan, Edward; Lehto, Harry J.; Hallam, Steven J.

2011-04-01

Pitch Lake in Trinidad and Tobago is a natural asphalt reservoir nourished by pitch seepage, a form of petroleum that consists of mostly asphaltines, from the surrounding oil-rich region. During upward seepage, pitch mixes with mud and gases under high pressure, and the lighter portion evaporates or is volatilized, which produces a liquid asphalt residue characterized by low water activity, recalcitrant carbon substrates, and noxious chemical compounds. An active microbial community of archaea and bacteria, many of them novel strains (particularly from the new Tar ARC groups), totaling a biomass of up to 107 cells per gram, was found to inhabit the liquid hydrocarbon matrix of Pitch Lake. Geochemical and molecular taxonomic approaches revealed diverse, novel, and deeply branching microbial lineages with the potential to mediate anaerobic hydrocarbon degradation processes in different parts of the asphalt column. In addition, we found markers for archaeal methane metabolism and specific gene sequences affiliated with facultative and obligate anaerobic sulfur- and nitrite-oxidizing bacteria. The microbial diversity at Pitch Lake was found to be unique when compared to microbial communities analyzed at other hydrocarbon-rich environments, which included Rancho Le Brea, a natural asphalt environment in California, USA, and an oil well and a mud volcano in Trinidad and Tobago, among other sites. These results open a window into the microbial ecology and biogeochemistry of recalcitrant hydrocarbon matrices and establish the site as a terrestrial analogue for modeling the biotic potential of hydrocarbon lakes such as those found on Saturn's largest moon Titan.

Cation exchange in a temporally fluctuating thin freshwater lens on top of saline groundwater

NASA Astrophysics Data System (ADS)

Eeman, S.; De Louw, P. G. B.; Van der Zee, S. E. A. T. M.

2017-01-01

In coastal-zone fields with a high groundwater level and sufficient rainfall, freshwater lenses are formed on top of saline or brackish groundwater. The fresh and the saline water meet at shallow depth, where a transition zone is found. This study investigates the mixing zone that is characterized by this salinity change, as well as by cation exchange processes, and which is forced by seepage and by rainfall which varies as a function of time. The processes are first investigated for a one-dimensional (1D) stream tube perpendicular to the interface concerning salt and major cation composition changes. The complex sequence of changes is explained with basic cation exchange theory. It is also possible to show that the sequence of changes is maintained when a two-dimensional field is considered where the upward saline seepage flows to drains. This illustrates that for cation exchange, the horizontal component (dominant for flow of water) has a small impact on the chemical changes in the vertical direction. The flow's horizontal orientation, parallel to the interface, leads to changes in concentration that are insignificant compared with those that are found perpendicular to the interface, and are accounted for in the 1D flow tube. Near the drains, differences with the 1D considerations are visible, especially in the longer term, exceeding 100 years. The simulations are compared with field data from the Netherlands which reveal similar patterns.

Generalized hydrology of prairie potholes on the Coteau du Missouri, North Dakota

USGS Publications Warehouse

Eisenlohr, William Stewart; Sloan, Charles E.

1968-01-01

This report presents all the information, obtained during the investigation, that lends itself to generalization. It describes conditions on that part of the Coteau du Missouri where there is little integration of drainage systems. The surface of the glacial drift in this region is dotted with shallow depressions known as prairie potholes that hold water for varying lengths of time. Precipitation directly on a pothole is the basic source of its water supply, but it is only about half the potential evaporation; therefore, potholes tend to go dry. Basin inflow from melting snow or rain occurs only when the soil is frozen or saturated, a condition so erratic in occurrence that seasonal or annual precipitation is of little value as an indication of basin inflow. Net seepage outflow occurs from potholes on the higher parts of the Coteau at very low rates, but it can amount to 20 to 30 percent of the total water loss from a pothole. Net seepage inflow occurs at the potholes on the lower parts of the Coteau. The phreatic surface (water table) tends to be a subdued image of the topography and is generally very near the land surface. The water surfaces of the potholes are part of the phreatic surface, and therefore they can be used to prepare a contour map of the phreatic surface; wells usually act as piezometers and thus are useless for such a purpose. Generally, potholes with water relatively low in dissolved solids have net seepage outflow, and those with water containing high concentration of dissolved solids have net seepage inflow. The direction of ground-water movement can therefore be inferred from the quality of water in potholes. The total salinity of water in a pothole is largely a function of the rate of ground-water flow and the relationship of seepage inflow to outflow. The species of emergent aquatic vegetation that grow in a pothole are directly related to the permanence and salinity of the water at the particular site of each species. The report contains a table of the common species that can be used as indicators of these conditions.

Strong seepage of shallow groundwater shifts the timing of the annual thermal signals in stream water

NASA Astrophysics Data System (ADS)

Briggs, M. A.; Johnson, Z. C.; Snyder, C.; Hitt, N. P.; White, E. A.; Lane, J. W., Jr.; Nelms, D. L.

2016-12-01

Conventional wisdom indicates that while short-term (e.g. diurnal) thermal variance in streams may be attenuated by groundwater seepage, annual temperature swings will essentially track the local air temperature signal. However, the temperature of shallow (less than 5 m depth) groundwater from seepage zones may not be constant and near the local mean air temperature, but instead will fluctuate seasonally, and show a pronounced phase lag from the annual air signal. The degree of phase lag will be dependent on the rate of vertical fluid and heat exchange through shallow aquifer sediments. Gaining headwater streams might be expected to adopt similar phase lags to local seepage zones. We explore these dynamics through 9 mountain watersheds in Shenandoah National Park, VA, USA that harbor critical habitat for cold-water brook trout (Salvelinus fontinalis). Daily paired air and stream water temperature records were collected for up to 5 years at several stream locations along each watershed. Sinusoids fit to multiple-year data from more than 100 total locations indicate an average phase shift from air to surface water of approximately 10 d; this may primarily be due to strong conductive exchange with the rocky alluvial aquifer in generally incised and shaded channels. A subset of these transects (n=4) showed phase-lags greater than 20 d, coinciding with locations of particularly pronounced diurnal variance attenuation, indicating strong groundwater influence. Shallow bedrock, evaluated throughout the watersheds with passive seismic methods, restricts downward infiltration of precipitation in the mountain bedrock aquifers. Numerical 1D vertical aquifer models indicate similar phase lags in shallow groundwater at the bedrock contact to that observed in stream seepage zones. Therefore, contrary to conventional wisdom, shaded mountain streams with strong groundwater influence may adopt the annual thermal signature of the adjacent aquifer, shifting the stream thermal maxima timing from that predicted by air temperature. This research illustrates the utility of long-term paired air/stream thermal records, which further refine the evaluation of apparent groundwater influence to aquatic habitat.

U.S. Department of Energy's site screening, site selection, and initial characterization for storage of CO2 in deep geological formations

USGS Publications Warehouse

Rodosta, T.D.; Litynski, J.T.; Plasynski, S.I.; Hickman, S.; Frailey, S.; Myer, L.

2011-01-01

The U.S. Department of Energy (DOE) is the lead Federal agency for the development and deployment of carbon sequestration technologies. As part of its mission to facilitate technology transfer and develop guidelines from lessons learned, DOE is developing a series of best practice manuals (BPMs) for carbon capture and storage (CCS). The "Site Screening, Site Selection, and Initial Characterization for Storage of CO2 in Deep Geological Formations" BPM is a compilation of best practices and includes flowchart diagrams illustrating the general decision making process for Site Screening, Site Selection, and Initial Characterization. The BPM integrates the knowledge gained from various programmatic efforts, with particular emphasis on the Characterization Phase through pilot-scale CO2 injection testing of the Validation Phase of the Regional Carbon Sequestration Partnership (RCSP) Initiative. Key geologic and surface elements that suitable candidate storage sites should possess are identified, along with example Site Screening, Site Selection, and Initial Characterization protocols for large-scale geologic storage projects located across diverse geologic and regional settings. This manual has been written as a working document, establishing a framework and methodology for proper site selection for CO2 geologic storage. This will be useful for future CO2 emitters, transporters, and storage providers. It will also be of use in informing local, regional, state, and national governmental agencies of best practices in proper sequestration site selection. Furthermore, it will educate the inquisitive general public on options and processes for geologic CO2 storage. In addition to providing best practices, the manual presents a geologic storage resource and capacity classification system. The system provides a "standard" to communicate storage and capacity estimates, uncertainty and project development risk, data guidelines and analyses for adequate site characterization, and guidelines for reporting estimates within the classification based on each project's status. 

First identification and thermodynamic characterization of the ternary U(VI) species, UO2(O2)(CO3)2(4-), in UO2-H2O2-K2CO3 solutions.

PubMed

Goff, George S; Brodnax, Lia F; Cisneros, Michael R; Peper, Shane M; Field, Stephanie E; Scott, Brian L; Runde, Wolfgang H

2008-03-17

In alkaline carbonate solutions, hydrogen peroxide can selectively replace one of the carbonate ligands in UO2(CO3)3(4-) to form the ternary mixed U(VI) peroxo-carbonato species UO2(O2)(CO3)2(4-). Orange rectangular plates of K4[UO2(CO3)2(O2)].H2O were isolated and characterized by single crystal X-ray diffraction studies. Crystallographic data: monoclinic, space group P2(1)/ n, a = 6.9670(14) A, b = 9.2158(10) A, c = 18.052(4) A, Z = 4. Spectrophotometric titrations with H 2O 2 were performed in 0.5 M K 2CO 3, with UO2(O2)(CO3)2(4-) concentrations ranging from 0.1 to 0.55 mM. The molar absorptivities (M(-1) cm(-1)) for UO2(CO3)3(4-) and UO2(O2)(CO3)2(4-) were determined to be 23.3 +/- 0.3 at 448.5 nm and 1022.7 +/- 19.0 at 347.5 nm, respectively. Stoichiometric analyses coupled with spectroscopic comparisons between solution and solid state indicate that the stable solution species is UO2(O2)(CO3)2(4-), which has an apparent formation constant of log K' = 4.70 +/- 0.02 relative to the tris-carbonato complex.

Hydrogen generation during serpentinisation in ophiolite complexes: A comparison of H2-rich gases from Oman, Philippines and Turkey.

NASA Astrophysics Data System (ADS)

Beaumont, Valérie; Vacquand, Christèle; Deville, Eric; Prinzhofer, Alain

2013-04-01

H2-rich gas seepages in ultrabasic to basic contexts both in marine and continental environment are by-products of serpentinisation. Hydrothermal systems at MOR expose ultrabasic rocks to thermodynamic conditions favouring oxidation of FeII bearing minerals and water reduction. In continental context such thermodynamic conditions do not exist although active serpentinisation occurs in all known ophiolitic complexes (Barnes et al., 1978; Bruni et al., 2002; Cipolli et al., 2004; Boschetti and Toscani, 2008; Marques et al., 2008). Hyperalkaline springs are reported in these contexts as evidence of this active serpentinisation (Barnes et al., 1967) and are often associated with seepages of reduced gases (Neal and Stanger, 1983; Sano et al., 1993). Dry gas seepages are also observed (Abrajano et al., 1988, 1990; Hosgörmez, 2007; Etiope et al., 2011) Such H2-rich gases from ophiolite complexes were sampled in the Sultanate of Oman, the Philippines and Turkey and were analysed for chemical composition, noble gases contents, stable isotopes of carbon, hydrogen and nitrogen. The conditions for present-day serpentinisation in ophiolites were recognised as low temperature processes in Oman with high rock/water ratios (Neal and Stanger, 1985), while the origin of gases is not as univocal for Philippines and Turkey gas seepages. Although, H2 generation is directly linked with FeII oxidation, different reactions can occur during peridotite hydration (McCollom and Bach, 2009; Marcaillou et al., 2011) and serpentine weathering. Produced H2 can react with carbonate species to produce methane via processes that could be biological or abiotic, while carbon availability depends on water recharge chemistry. In the present study, the geochemical properties of gases sampled from three different ophiolite complexes are compared and provide evidence that weathering reactions producing H2 depend on structural, geological, geomorphologic and hydrological local features. REFERENCES Abrajano, T. A., et al. (1988). Chemical Geology, 71(1-3), 211-222. Abrajano, T. A, et al. (1990). Applied Geochemistry, 5(5-6), 625-630. Barnes, I., et al. (1967). Science (New York, N.Y.), 156(3776), 830-2. Barnes, I., et al. (1978). Geochimica et Cosmochimica Acta, 42(1), 144-145. Boschetti, T., & Toscani, L. (2008). Chemical Geology, 257(1-2), 76-91. Bruni, J., et al. (2002). Applied Geochemistry, 17, 455-474. Cipolli, F., et al. (2004). Applied Geochemistry, 19(5), 787-802. Etiope, G., et al. (2011). Earth and Planetary Science Letters, 310(1-2), 96-104. Hosgörmez, H. (2007). Journal of Asian Earth Sciences, 30(1), 131-141. Marcaillou, C., et al. (2011). Earth and Planetary Science Letters, 303(3-4), 281-290. Marques, J. M., et al. (2008). Applied Geochemistry, 23(12), 3278-3289. McCollom, T. M. & Bach, W. (2009). Geochimica et Cosmochimica Acta, 73(3), 856-875. Neal, C. & Stanger, G. (1983). Earth and Planetary Science Letters, 66(66), 315-320. Neal, C. & Stanger, G. (1985). In J. I. Dever (Ed.), The Chemistry of Weathering (pp. 249-275). D. Reidel Publishing Company. Sano, Y., et al. (1993). Applied Geochemistry, 8(1), 1-8.

Geophysical Assessment of the Control of a Jetty on a Barrier Beach and Estuary System

NASA Astrophysics Data System (ADS)

Ulrich, C.; Hubbard, S. S.; Peterson, J.; Blom, K.; Black, W.; Delaney, C.; Mendoza, J.

2014-12-01

An evaluation is underway at the Goat Rock State Park, located at the mouth of the Russian River near Jenner, CA, to quantify the influence of a man made jetty on the functioning of a barrier beach and associated implications for estuary fish habitat and flood control. Flow through the beach results from water level differences between the estuary and the ocean. When the estuary is closed or perched, one of the major sources of outflow from the lagoon is seepage flow through the barrier beach. The location and design of the jetty could be altering subsurface flow paths through the jetty and possibly impeding subsurface flow where the jetty is still intact. This will result in unnatural connectivity between the ocean and the estuary leading to atypical surface water elevations and possibly salinity imbalance. We are monitoring seepage through the jetty and beach berm with multiple surface and borehole geophysical methods, including: electrical resistivity (ERT), seismic refraction (SR), ground penetrating radar (GPR), and electromagnetic methods (EM). We use SR data to characterize deeper bedrock controls on beach barrier functioning; ERT and EM methods to characterize the beach sediment layers that could contribute to preferential flow paths during tide cycles in addition to preferential flow paths created by the jetty structure; time-lapse ERT and EM data to monitor moisture changes and mixing of saline and fresh water within the beach berm, and borehole ERT and GPR data to delineate the geometry of the (often buried) jetty. Preliminary ERT and EM results indicate two preferential flow paths through zones of missing jetty structure, while time-lapse borehole ERT data is expected to image saltwater flow impedance in zones of intact jetty structure. All data are being integrated with topography, tidal, borehole, and hydrological information and the results of the assessment will enable the Sonoma County Water Agency to develop the feasibility of alternatives to the existing jetty that may help achieve target estuarine water surface elevations.

High density of structurally controlled, shallow to deep water fluid seep indicators imaged offshore Costa Rica

NASA Astrophysics Data System (ADS)

Kluesner, Jared W.; Silver, Eli A.; Bangs, Nathan L.; McIntosh, Kirk D.; Gibson, James; Orange, Daniel; Ranero, Cesar R.; von Huene, Roland

2013-03-01

We used high-resolution mapping to document 161 sites of potential fluid seepage on the shelf and slope regions where no geophysical seep indicators had been reported. Identified potential seabed seepage sites show both high-backscatter anomalies and bathymetric expressions, such as pockmarks, mounds, and ridges. Almost all identified seabed features are associated with bright spots and flat spots beneath, as mapped within the 3-D seismic grid. We obtained EM122 multi-beam data using closely spaced receiver beams and 4-5 times overlapping multi-beam swaths, which greatly improved the sounding density and geologic resolvability of the data. At least one location shows an acoustic plume in the water column on a 3.5 kHz profile, and this plume is located along a fault trace and above surface and subsurface seepage indicators. Fluid indicators are largely associated with folds and faults within the sediment section, and many of the faults continue into and offset the reflective basement. A dense pattern of normal faults is seen on the outer shelf in the multi-beam bathymetry, backscatter, and 3-D seismic data, and the majority of fluid seepage indicators lie along mapped fault traces. Furthermore, linear mounds, ridges, and pockmark chains are found on the upper, middle, and lower slope regions. The arcuate shape of the shelf edge, projection of the Quepos Ridge, and high density of potential seep sites suggest that this area may be a zone of former seamount/ridge subduction. These results demonstrate a much greater potential seep density and distribution than previously reported across the Costa Rican margin.

Vertical migration of fine-grained sediments from interior to surface of seabed driven by seepage flows-`sub-bottom sediment pump action'

NASA Astrophysics Data System (ADS)

Zhang, Shaotong; Jia, Yonggang; Wen, Mingzheng; Wang, Zhenhao; Zhang, Yaqi; Zhu, Chaoqi; Li, Bowen; Liu, Xiaolei

2017-02-01

A scientific hypothesis is proposed and preliminarily verified in this paper: under the driving of seepage flows, there might be a vertical migration of fine-grained soil particles from interior to surface of seabed, which is defined as `sub-bottom sediment pump action' in this paper. Field experiments were performed twice on the intertidal flat of the Yellow River delta to study this process via both trapping the pumped materials and recording the pore pressures in the substrate. Experimental results are quite interesting as we did observe yellow slurry which is mainly composed of fine-grained soil particles appearing on the seabed surface; seepage gradients were also detected in the intertidal flat, under the action of tides and small wind waves. Preliminary conclusions are that `sediment pump' occurs when seepage force exceeds a certain threshold: firstly, it is big enough to disconnect the soil particles from the soil skeleton; secondly, the degree of seabed fluidization or bioturbation is big enough to provide preferred paths for the detached materials to migrate upwards. Then they would be firstly pumped from interior to the surface of seabed and then easily re-suspended into overlying water column. Influential factors of `sediment pump' are determined as hydrodynamics (wave energy), degree of consolidation, index of bioturbation (permeability) and content of fine-grained materials (sedimentary age). This new perspective of `sediment pump' may provide some implications for the mechanism interpretation of several unclear geological phenomena in the Yellow River delta area.

Hydrochemistry of urban groundwater, Seoul, Korea: the impact of subway tunnels on groundwater quality.

PubMed

Chae, Gi-Tak; Yun, Seong-Taek; Choi, Byoung-Young; Yu, Soon-Young; Jo, Ho-Young; Mayer, Bernhard; Kim, Yun-Jong; Lee, Jin-Yong

2008-10-23

Hydrogeologic and hydrochemical data for subway tunnel seepage waters in Seoul (Republic of Korea) were examined to understand the effect of underground tunnels on the degradation of urban groundwater. A very large quantity of groundwater (up to 63 million m3 year(-1)) is discharged into subway tunnels with a total length of 287 km, resulting in a significant drop of the local groundwater table and the abandonment of groundwater wells. For the tunnel seepage water samples (n = 72) collected from 43 subway stations, at least one parameter among pathogenic microbes (total coliform, heterotrophic bacteria), dissolved Mn and Fe, NH4+, NO3(-), turbidity, and color exceeded the Korean Drinking Water Standards. Locally, tunnel seepage water was enriched in dissolved Mn (avg. 0.70 mg L(-1), max. 5.58 mg L(-1)), in addition to dissolved Fe, NH4+, and pathogenic microbes, likely due to significant inflow of sewage water from broken or leaking sewer pipes. Geochemical modeling of redox reactions was conducted to simulate the characteristic hydrochemistry of subway tunnel seepage. The results show that variations in the reducing conditions occur in urban groundwater, dependent upon the amount of organic matter-rich municipal sewage contaminating the aquifer. The organic matter facilitates the reduction and dissolution of Mn- and Fe-bearing solids in aquifers and/or tunnel construction materials, resulting in the successive increase of dissolved Mn and Fe. The present study clearly demonstrates that locally significant deterioration of urban groundwater is caused by a series of interlinked hydrogeologic and hydrochemical changes induced by underground tunnels.

Nanoparticles of ZrPO4 for green catalytic applications

NASA Astrophysics Data System (ADS)

Sreenivasulu, Peta; Pendem, Chandrasekhar; Viswanadham, Nagabhatla

2014-11-01

Here we report the successful room temperature synthesis of zirconium phosphate nanoparticles (ZPNP) using the P123 tri-co-block polymer for the first time. The samples were characterized by SEM, TEM, XRD, TPD, and BET and were employed for fixation of CO2 on aniline to produce pharmaceutically important acetanilide under mild reaction conditions (150 °C and 150 Psi CO2 pressure).Here we report the successful room temperature synthesis of zirconium phosphate nanoparticles (ZPNP) using the P123 tri-co-block polymer for the first time. The samples were characterized by SEM, TEM, XRD, TPD, and BET and were employed for fixation of CO2 on aniline to produce pharmaceutically important acetanilide under mild reaction conditions (150 °C and 150 Psi CO2 pressure). Electronic supplementary information (ESI) available: Experimental details, wide angle XRD, EDX, IR spectra, GC data etc. See DOI: 10.1039/c4nr03209h

Methanogenic biodegradation of creosote contaminants in natural and simulated ground-water ecosystems

USGS Publications Warehouse

Godsy, E. Michael; Goerlitz, Donald; Grbic-Galic, Dunja

1992-01-01

Wastes from a wood preserving plant in Pensacola, Florida have contaminated the near-surface sand-and-gravel aquifer with creosote-derived compounds and pentachlorophenol. Contamination resulted from the discharge of plant waste waters to and subsequent seepage from unlined surface impoundments that were in direct hydraulic contact with the ground water. Two distinct phases resulted when the creosote and water mixed: a denser than water hydrocarbon phase that moved vertically downward, and an organic-rich aqueous phase that moved laterally with the ground-water flow. The aqueous phase is enriched in organic acids, phenolic compounds, single- and double-ring nitrogen, sulfur, and oxygen containing compounds, and single- and double-ring aromatic hydrocarbons. The ground water is devoid of dissolved O2, is 60-70% saturated with CH4 and contains H2S. Field analyses document a greater decrease in concentration of organic fatty acids, benzoic acid, phenol, 2-, 3-, 4-methylphenol, quinoline, isoquinoline, 1(2H)-quinolinone, and 2(1H)-isoquinolinone during downgradient movement in the aquifer than could be explained by dilution and/or dispersion. Laboratory microcosm studies have shown that within the study region, this effect can be attributed to microbial degradation to CH4 and CO2. A small but active methanogenic population was found on sediment materials taken from highly contaminated parts of the aquifer.

Sedimentology of the saline lakes of the Cariboo Plateau, Interior British Columbia, Canada

NASA Astrophysics Data System (ADS)

Renaut, Robin W.; Long, Peter R.

1989-10-01

There are several hundred saline lakes in Interior British Columbia, including muddy siliciclastic playas, saline playas, perennial lakes (including meromictic sulphate lakes), and ephemeral lakes, some with permanent salts. The lake waters have highly variable compositions, with Na-CO 3-Cl, Na-CO 3-(SO 4)-Cl, Mg-Na-SO 4 and Na-Mg-SO 4, the dominant types of brine. On the Cariboo Plateau, where they are most abundant, the saline lakes are small, shallow, and occupy depressions within glacial and glacio-fluvial deposits. Most are groundwater-fed. The region is characterized by extremely cold winters and short hot summers. Dense coniferous forest mantles much of the plateau and surrounds most of the lakes. Most basins comprise three main subenvironments—hillslope, mudflat (saline and dry) and lake (ephemeral or perennial). Fluvial sediments are of little significance. Mudflats are primarily a zone of extensive interstitial carbonate precipitation from shallow groundwaters, including abundant magnesite and hydromagnesite. The amount of carbonate formed varies with groundwater composition. Some mudflats are carbonate-dominated; others are predominantly siliciclastic with only highly soluble interstitial salts forming. Sedimentary structures are disrupted by carbonate precipitation and displacive salt crystallization. Springs and ephemeral seepages are locally present. Microbial mats form extensively along many littoral zones and around springs; laminates are preserved in some cores. Efflorescent salt crusts cover saline mudflats around most lakes and playas. Subaqueous salts (including natron, epsomite, bloedite, mirabilite) are precipitated during late summer, autumn and winter in several hypersaline lakes, some by evaporative concentration, others by brine cooling and freeze-out. Several hypersaline, ephemeral lakes have an unusual "spotted" morphology, with hundreds of individual brine pools within carbonate-siliciclastic muds. Most recent sedimentation in the Cariboo lakes has been autochthonous, with a predominance of carbonates, evaporites and organic-rich muds. This reflects the dense vegetation in the catchment which has stabilized soils and limited clastic influx, the predominance of groundwater recharge, the lack of basin marginal relief, and the common occurrence of inflow waters with {( Ca + Mg) }/{( HCO 3 + CO 3) } near unity which provide abundant carbonate sediment.

Advanced Reservoir Characterization and Evaluation of CO2 Gravity Drainage in the Naturally Fractured Spraberry Trend Area, Class III

DOE Office of Scientific and Technical Information (OSTI.GOV)

Knight, Bill; Schechter, David S.

The goal of this project was to assess the economic feasibility of CO2 flooding the naturally fractured Spraberry Trend Area in west Texas. This objective was accomplished through research in four areas: (1) extensive characterization of the reservoirs, (2) experimental studies of crude oil/brine/rock (COBR) interactions in the reservoirs, (3) reservoir performance analysis, and (4) experimental investigations on CO2 gravity drainage in Spraberry whole cores. This provides results of the final year of the six-year project for each of the four areas.

Preparation of boron doped diamond modified by iridium for electroreduction of carbon dioxide (CO2)

NASA Astrophysics Data System (ADS)

Ichzan, A. M.; Gunlazuardi, J.; Ivandini, T. A.

2017-04-01

Electroreduction of carbon dioxide (CO2) at iridium oxide-modified boron-doped diamond (IrOx-BDD) electrodes in aqueous electrolytes was studied by voltammetric method. The aim of this study was to find out the catalytic effect of IrOx to produce fine chemicals contained of two or more carbon atoms (for example acetic acid) in high percentage. Characterization using FE-SEM and XPS indicated that IrO2 can be deposited at BDD electrode, whereas characterization using cyclic voltammetry indicated that the electrode was applicable to be used as working electrode for CO2 electroreduction.

Metal-templated synthesis of macrocyclic (triphosphine)molybdenum complexes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Diel, B.N.; Brandt, P.F.; Haltiwanger, R.C.

1989-07-12

Reaction of CH{sub 2}=CHCH{sub 2}PH{sub 2}, CH{sub 2}=CHCH{sub 2}CH{sub 2}PH{sub 2}, and CH{equivalent to}CCH{sub 2}PPH{sub 2} with (mesitylene)Mo(CO){sub 3} or (cycloheptatriene)Mo(CO){sub 3} yields the complexes (CH{sub 2}=CHCH{sub 2}PH{sub 2}){sub 3} (1), (CH{sub 2}=CHCH{sub 2}CH{sub 2}PH{sub 2}){sub 3}Mo(CO){sub 3} (2), and (CH{equivalent to}CCH{sub 2}PH{sub 2}){sub 3}Mo(CO){sub 3}, (3), respectively. Reaction of CH{sub 2}=CHCH{sub 2}PH{sub 2} and CH{equivalent to}CCH{sub 2}PH{sub 2} with cis-(piperidine){sub 2}Mo(CO){sub 4} yields cis-(CH{sub 2}=CHCH{sub 2}PH{sub 2}){sub 2}Mo(CO){sub 4} (4) and cis-(CH{equivalent to}CCH{sub 2}PH{sub 2}){sub 2}Mo(CO){sub 4} (5). Free-radical-initiated cyclooligomerization of 1 and 2 yields the triligated macrocyclic secondary-phosphine complexes fac-(HP(CH{sub 2}){sub 3}){sub 3}Mo(CO){sub 3} (6) and fac-(HP-(CH{sub 2}){submore » 4}){sub 3}Mo(CO){sub 3} (7). Under similar conditions, reaction of 4 yields an acyclic diphosphine complex characterized tentatively as cis-(H{sub 2}P(CH{sub 2}){sub 3}PH(CH{sub 2}CH=CH{sub 2}))Mo(CO){sub 4} (8). Compounds 1-7 and 10 have been characterized by spectral ({sup 31}P, {sup 13}C, and {sup 1}H, NMR and IR and mass) data. 6 has been characterized in the solid state by single-crystal x-ray analysis, and the results are reported. {sup 31}P NMR spectra studies of the cyclooligomerization of 1 show the partially cyclized intermediates formed prior to 6. The macrocyclic complexes 6 and 7 are kinetically stable, showing no sign of ligand displacement in reactions with pH{sub 3}P, PF{sub 3}, KCN, or P(OMe){sub 3}. 44 refs., 4 figs., 4 tabs.« less

Gaia's breath - Global methane exhalations

USGS Publications Warehouse

Kvenvolden, K.A.; Rogers, B.W.

2005-01-01

Methane (CH4) is the most abundant organic compound in the Earth's atmosphere, where it acts as a greenhouse gas and thus has implications for global climate change. The current atmospheric CH4 budget, however, does not take into account geologically-sourced CH4 seepage. Geological sources of CH4 include natural macro- and micro-seeps, mud volcanoes, and other miscellaneous sources such as gas hydrates, magmatic volcanoes, geothermal regions, and mid-ocean ridges. Macro-seeps contribute ???25 Tg (teragrams) CH4/yr to the atmosphere, whereas, micro-seepage contributes perhaps 7 Tg CH4/yr. Mud volcanoes emit ???5 Tg CH4/yr, and miscellaneous sources emit ???8 Tg CH4/yr to the atmosphere. Thus, the total contribution to the atmosphere from geological sources is estimated to be 45 Tg CH4/yr, which is significant to the atmospheric organic carbon cycle and should be included in any global inventory of atmospheric CH4. We argue that the atmospheric CH4 global inventory of the Interplanetary Panel on Climate Change must be adjusted in order to incorporate geologically-sourced CH4 from naturally occurring seepage.

Modelling of mechanical and filtration processes near the well with regard to anisotropy

NASA Astrophysics Data System (ADS)

Karev, V. I.; Klimov, D. M.; Kovalenko, Yu F.; Ustinov, K. B.

2018-04-01

A geomechanical approach to modeling deformation and seepage is presented. Three stages of modeling are described: choice of an appropriate mechanical model and its adaptation to the case in question, experimental determination of parameters of the model, simulation of processes of seepage for particular configurations of the well. The applied model allows describing the main specific characteristics of mechanical behavior of the collector: the influence of the pore pressure on deformation; the influence of not only shear but also comprehensive stresses and pore pressure on the transition to inelastic behavior; the appearance of inelastic volumetric deformation and its nontrivial dependence on the stress state; the anisotropy of elastic, strength and seepage properties; non-obvious dependence of permeability on the stress strain state. The model unites essential characteristics of Hill’s plastic flow theory for anisotropic materials and the Drucker–Prager theory for inelastic deformation of soils. The results of experimental determination of the involved parameters obtained using true triaxial loading system for the collector of Vladimir Filanovsky field in the Caspian Sea are presented.

Geological and biological heterogeneity of the Aleutian margin (1965-4822 m)

NASA Astrophysics Data System (ADS)

Rathburn, A. E.; Levin, L. A.; Tryon, M.; Gieskes, J. M.; Martin, J. B.; Pérez, M. E.; Fodrie, F. J.; Neira, C.; Fryer, G. J.; Mendoza, G.; McMillan, P. A.; Kluesner, J.; Adamic, J.; Ziebis, W.

2009-01-01

Geological, biological and biogeochemical characterization of the previously unexplored margin off Unimak Island, Alaska between 1965 and 4822 m water depth was conducted to examine: (1) the geological processes that shaped the margin, (2) the linkages between depth, geomorphology and environmental disturbance in structuring benthic communities of varying size classes and (3) the existence, composition and nutritional sources of methane seep biota on this margin. The study area was mapped and sampled using multibeam sonar, a remotely operated vehicle (ROV) and a towed camera system. Our results provide the first characterization of the Aleutian margin mid and lower slope benthic communities (microbiota, foraminifera, macrofauna and megafauna), recognizing diverse habitats in a variety of settings. Our investigations also revealed that the geologic feature known as the “Ugamak Slide” is not a slide at all, and could not have resulted from a large 1946 earthquake. However, sediment disturbance appears to be a pervasive feature of this margin. We speculate that the deep-sea occurrence of high densities of Elphidium, typically a shallow-water foraminiferan, results from the influence of sediment redeposition from shallower habitats. Strong representation of cumacean, amphipod and tanaid crustaceans among the Unimak macrofauna may also reflect sediment instability. Although some faunal abundances decline with depth, habitat heterogeneity and disturbance generated by canyons and methane seepage appear to influence abundances of biota in ways that supercede any clear depth gradient in organic matter input. Measures of sediment organic matter and pigment content as well as C and N isotopic signatures were highly heterogeneous, although the availability of organic matter and the abundance of microorganisms in the upper sediment (1-5 cm) were positively correlated. We report the first methane seep on the Aleutian slope in the Unimak region (3263-3285 m), comprised of clam bed, pogonophoran field and carbonate habitats. Seep foraminiferal assemblages were dominated by agglutinated taxa, except for habitats above the seafloor on pogonophoran tubes. Numerous infaunal taxa in clam bed and pogonophoran field sediments and deep-sea “reef” cnidarians (e.g., corals and hydroids) residing on rocks near seepage sites exhibited light organic δ 13C signatures indicative of chemosynthetic nutritional sources. The extensive geological, biogeochemical and biological heterogeneity as well as disturbance features observed on the Aleutian slope provide an attractive explanation for the exceptionally high biodiversity characteristic of the world’s continental margins.

Natural separation of the acyl-CoA ligase reaction results in a non-adenylating enzyme.

PubMed

Wang, Nan; Rudolf, Jeffrey D; Dong, Liao-Bin; Osipiuk, Jerzy; Hatzos-Skintges, Catherine; Endres, Michael; Chang, Chin-Yuan; Babnigg, Gyorgy; Joachimiak, Andrzej; Phillips, George N; Shen, Ben

2018-06-04

Acyl-coenzyme A (CoA) ligases catalyze the activation of carboxylic acids via a two-step reaction of adenylation followed by thioesterification. Here, we report the discovery of a non-adenylating acyl-CoA ligase PtmA2 and the functional separation of an acyl-CoA ligase reaction. Both PtmA1 and PtmA2, two acyl-CoA ligases from the biosynthetic pathway of platensimycin and platencin, are necessary for the two steps of CoA activation. Gene inactivation of ptmA1 and ptmA2 resulted in the accumulation of free acid and adenylate intermediates, respectively. Enzymatic and structural characterization of PtmA2 confirmed its ability to only catalyze thioesterification. Structural characterization of PtmA2 revealed it binds both free acid and adenylate substrates and undergoes the established mechanism of domain alternation. Finally, site-directed mutagenesis restored both the adenylation and complete CoA activation reactions. This study challenges the currently accepted paradigm of adenylating enzymes and inspires future investigations on functionally separated acyl-CoA ligases and their ramifications in biology.

Cu(II), Co(II) and Ni(II) complexes of new Schiff base ligand: Synthesis, thermal and spectroscopic characterizations

NASA Astrophysics Data System (ADS)

Refat, Moamen S.; El-Sayed, Mohamed Y.; Adam, Abdel Majid A.

2013-04-01

Cu(II), Co(II), and Ni(II) complexes were synthesized from 2-[(5-o-chlorophenylazo-2-hydroxybenzylidin)amino]-phenol Schiff base (H2L). Metal ions coordinate in a tetradentate or hexadentate features with these O2N donor ligand, which are characterized by elemental analyses, magnetic moments, infrared, Raman laser, electronic, and 1H NMR spectral studies. The elemental analysis suggests the stoichiometry to be 1:1 (metal:ligand). Reactions with Cu(II), Co(II) and Ni(II), resulted [Cu(H2L)(H2O)2(Cl)]Cl, [Co(H2L)(H2O)3]Cl2ṡ3H2O and [Ni(H2L)(H2O)2]Cl2ṡ6H2O. The thermal decomposition behavior of H2L complexes has been investigated by thermogravimetric analysis (TG/DTG) at a heating rate of 10 °C min-1 under nitrogen atmosphere. The brightness side in this study is to take advantage for the preparation and characterizations of single phases of CuO, CoO and NiO nanoparticles using H2L complexes as precursors via a solid-state decomposition procedure. The crystalline structures of products using X-ray diffractometer (XRD), morphology of particles by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX) were investigated.

Synthesis, characterization and magnetic behavior of Co/MCM-41 nano-composites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cuello, N.; Elías, V.; CONICET

2013-09-15

Synthesis, structure and magnetic properties of Co/MCM-41 as magnetic nano-composites have been investigated. Mesoporous materials with different degrees of metal loading were prepared by wet impregnation and characterized by ICP, XRD, N{sub 2} adsorption, UV–vis DRS, TPR and EPMA-EDS. Cobalt oxide clusters and Co{sub 3}O{sub 4} nano-particles could be confined inside the mesopores of MCM-41, being this fact favored by the Co loading increasing. In addition, larger crystals of Co{sub 3}O{sub 4} detectable by XRD also grow on the surface when the Co loading is enhanced. The magnetic characterization was performed in a SQUID magnetometer using a maximum magnetic appliedmore » field µ{sub 0}Ha=1 T. While the samples with the higher Co loadings showed a behavior typically paramagnetic, a superparamagnetic contribution is more notorious for lower loadings, suggesting high Co species dispersion. - Graphical abstract: Room temperature hysteresis loops as a function of the Co content. Display Omitted - Highlights: • Co species as isolated Co{sup 2+}, oxide clusters and Co{sub 3}O{sub 4} nano-particles were detected. • For higher Co loads were detected, by XRD, Co{sub 3}O{sub 4} particles on the external surface. • The confining of Co species inside the mesopores was achieved by increasing Co load. • Paramagnetism from oxide clusters/nano-particles becomes dominant for higher Co loads. • Superparamagnetism can be assigned to Co species of small size and finely dispersed.« less

DS2 Container and Weatherproofing Study

DTIC Science & Technology

1990-12-01

compatible with polyurethane based coating systems in general? Is it compatible with alkyd -based coatings? 10. How well do the labels placed on the...of the (older) alkyd enamel and (more recently) polyurethane camouflage coatings, leading eventually to seepage of the DS2. A shrink-wrap overpack...by John Wiley and Sons, Inc., Vol. 2, pp. 118- 119; Vol. 4, p. 3 and pp. 284-295; Vol. I, p. 133. 8. Fiber Composite Hybrid Materials, N.L. Hancox

Structural characterization of framework–gas interactions in the metal–organic framework Co2(dobdc) by in situ single-crystal X-ray diffraction† †Electronic supplementary information (ESI) available: Supplementary figures, crystallographic information, adsorption isotherms and fits, CCDC 1530119–1530126. For ESI and crystallographic data in CIF or other electronic format. See DOI: 10.1039/c7sc00449d Click here for additional data file. Click here for additional data file.

PubMed Central

Gonzalez, Miguel I.; Mason, Jarad A.; Bloch, Eric D.; Teat, Simon J.; Gagnon, Kevin J.; Morrison, Gregory Y.; Queen, Wendy L.

2017-01-01

The crystallographic characterization of framework–guest interactions in metal–organic frameworks allows the location of guest binding sites and provides meaningful information on the nature of these interactions, enabling the correlation of structure with adsorption behavior. Here, techniques developed for in situ single-crystal X-ray diffraction experiments on porous crystals have enabled the direct observation of CO, CH4, N2, O2, Ar, and P4 adsorption in Co2(dobdc) (dobdc4– = 2,5-dioxido-1,4-benzenedicarboxylate), a metal–organic framework bearing coordinatively unsaturated cobalt(ii) sites. All these molecules exhibit such weak interactions with the high-spin cobalt(ii) sites in the framework that no analogous molecular structures exist, demonstrating the utility of metal–organic frameworks as crystalline matrices for the isolation and structural determination of unstable species. Notably, the Co–CH4 and Co–Ar interactions observed in Co2(dobdc) represent, to the best of our knowledge, the first single-crystal structure determination of a metal–CH4 interaction and the first crystallographically characterized metal–Ar interaction. Analysis of low-pressure gas adsorption isotherms confirms that these gases exhibit mainly physisorptive interactions with the cobalt(ii) sites in Co2(dobdc), with differential enthalpies of adsorption as weak as –17(1) kJ mol–1 (for Ar). Moreover, the structures of Co2(dobdc)·3.8N2, Co2(dobdc)·5.9O2, and Co2(dobdc)·2.0Ar reveal the location of secondary (N2, O2, and Ar) and tertiary (O2) binding sites in Co2(dobdc), while high-pressure CO2, CO, CH4, N2, and Ar adsorption isotherms show that these binding sites become more relevant at elevated pressures. PMID:28966783

Quantifying time-varying ground-water discharge and recharge in wetlands of the northern Florida Everglades

USGS Publications Warehouse

Choi, J.; Harvey, J.W.

2000-01-01

Developing a more thorough understanding of water and chemical budgets in wetlands depends in part on our ability to quantify time-varying interactions between ground water and surface water. We used a combined water and solute mass balance approach to estimate time-varying ground-water discharge and recharge in the Everglades Nutrient Removal project (ENR), a relatively large constructed wetland (1544 hectare) built for removing nutrients from agricultural drainage in the norther Everglades in South Florida, USA. Over a 4-year period (1994 through 1998), ground-water recharge averaged 13.4 hectare-meter per day (ha-m/day) or 0.9 cm/day, which is approximately 31% of surface water pumped into the ENR for treatment. In contrast, ground-water discharge was much smaller (1.4 ha-m/day, or 0.09 cm/day, or 2.8% of water input to ENR for treatment). Using a water-balance approach alone only allowed net ground-water exchange (discharge - recharge) to be estimated (-12 ?? 2.4 ha-ma/day). Disharge and recharge were individually determined by combining a chloride mass balance with the water balance. For a variety of reasons, the ground-water discharge estimated by the combined mass balance approach was not reliable (1.4 ?? 37 ha-m/day). As a result, ground-water interactions could only be reliably estimated by comparing the mass-balance results with other independent approaches, including direct seepage-meter measurements and previous estimates using ground-water modeling. All three independent approaches provided similar estimates of average ground-water recharge, ranging from 13 to 14 ha-m/day. There was also relatively good agreement between ground-water discharge estimates for the mass balance and seepage meter methods, 1.4 and 0.9 ha-m/day, respectively. However, ground-water-flow modeling provided an average discharge estimate that was approximately a factor of four higher (5.4 ha-m/day) than the other two methods. Our study developed an initial understanding of how the design and operation of the ENR increases interactions between ground water and surface water. A considerable portion of recharged ground water (73%) was collected and returned to the ENR by a seepage canal. Additional recharge that was not captured by the seepage canal only occurred when pumped inflow rates to ENR (and ENR water levels) were relatively high. Management of surface water in the northern Everglades therefore clearly has the potential to increase interactions with ground water.

Characteristics of gas hydrate-bearing sediments of the northern South China Sea: insight into past hydrate episodic dissociations and intensities of seepage

NASA Astrophysics Data System (ADS)

Chen, F.; Su, X.; Zhou, Y.; Zhang, G.; Zhuang, C.; Lu, H.

2016-12-01

In 2013 the second China's major gas hydrate expedition, GMGS2, cored and recovered abundant gas hydrates at five sites, which were located in the South China Sea.Site GMGS08 (95m long) contained two gas hydrate intervals and five authigenic carbonate intervals. We analyzed carbon and oxygen isotopes of authigenic carbonates and foraminifera shells in sediments recovered at this site, in order to understanding of features of hydrate-bearing sediments and timing of gas hydrate dissociation and methane seepage at this site. An age of younger than 0.27 Ma was estimated for the 95 m sedimentary sequences at Site GMGS08. A detailed age model was further established by employing of U/Th and AMS14C dating of authigenic carbonates and seep bivalve fragments. These carbonates are featured by 13C-depleted (with a range from -38.9‰ to 56.7‰ δ13C) and positive δ18O (from 2.94‰ to 5.66‰ δ18O) values. A further analysis indicated the formation of carbonates were correlated to methane seepages derived from gas hydrate dissociation. Subsequently, these five authigenic carbonates intervals were seen as five hydrate episodic dissociation events since last 0.27Ma at this site. The most significant event during the period of 0.11 Ma to 0.13 Ma were account for the formation of thick authigenic carbonate (with the lowest -56.8‰ δ13C value) platform on paleo-seafloor at this site. The upmost authigenic carbonates interval is just overlying on the top of the upper gas hydrate occurrence zone, and it represents the latest methane seepage event with an age of 26ka to 36ka. Well correlated to these five events, it existed five intervals with strongly 13C-depleted carbon (-15.85‰ PDB) of foraminifera shells both from benthic and planktonic. The anomalous δ13C depletion records of planktonic G. ruber shells should be caused by formation of secondary authigenic carbonates on the shells, which were derived from the anaerobic oxidation of methane (AOM). The analyses on carbonate samples indicated varied intensity of methane flux in each event. The most intensive methane venting flux occurred during the event of 0.11 Ma to 0.13 Ma, which is correlated to a warm and relative high sea level period of MIS stage 5. These records obtained at Site GMGS08 implied much complicated causes for formation of authigenic carbonates and gas hydrate episodic dissociation.

Laser-Based Monitoring of CH4, CO2, NH3, and H2S in Animal Farming—System Characterization and Initial Demonstration

PubMed Central

Jaworski, Piotr; Nikodem, Michał

2018-01-01

In this paper, we present a system for sequential detection of multiple gases using laser-based wavelength modulation spectroscopy (WMS) method combined with a Herriot-type multi-pass cell. Concentration of hydrogen sulfide (H2S), methane (CH4), carbon dioxide (CO2), and ammonia (NH3) are retrieved using three distributed feedback laser diodes operating at 1574.5 nm (H2S and CO2), 1651 nm (CH4), and 1531 nm (NH3). Careful adjustment of system parameters allows for H2S sensing at single parts-per-million by volume (ppmv) level with strongly reduced interference from adjacent CO2 transitions even at atmospheric pressure. System characterization in laboratory conditions is presented and the results from initial tests in real-world application are demonstrated. PMID:29425175

Integrated Framework for Assessing Impacts of CO₂ Leakage on Groundwater Quality and Monitoring-Network Efficiency: Case Study at a CO₂ Enhanced Oil Recovery Site.

PubMed

Yang, Changbing; Hovorka, Susan D; Treviño, Ramón H; Delgado-Alonso, Jesus

2015-07-21

This study presents a combined use of site characterization, laboratory experiments, single-well push-pull tests (PPTs), and reactive transport modeling to assess potential impacts of CO2 leakage on groundwater quality and leakage-detection ability of a groundwater monitoring network (GMN) in a potable aquifer at a CO2 enhanced oil recovery (CO2 EOR) site. Site characterization indicates that failures of plugged and abandoned wells are possible CO2 leakage pathways. Groundwater chemistry in the shallow aquifer is dominated mainly by silicate mineral weathering, and no CO2 leakage signals have been detected in the shallow aquifer. Results of the laboratory experiments and the field test show no obvious damage to groundwater chemistry should CO2 leakage occur and further were confirmed with a regional-scale reactive transport model (RSRTM) that was built upon the batch experiments and validated with the single-well PPT. Results of the RSRTM indicate that dissolved CO2 as an indicator for CO2 leakage detection works better than dissolved inorganic carbon, pH, and alkalinity at the CO2 EOR site. The detection ability of a GMN was assessed with monitoring efficiency, depending on various factors, including the natural hydraulic gradient, the leakage rate, the number of monitoring wells, the aquifer heterogeneity, and the time for a CO2 plume traveling to the monitoring well.

Subsurface Characterization and Seismic Monitoring for the Southwest Partnerships Phase III Demonstration Project at Farnsworth Field, TX

NASA Astrophysics Data System (ADS)

Will, R. A.; Balch, R. S.

2015-12-01

The Southwest Partnership on Carbon Sequestration is performing seismic based characterization and monitoring activities at an active CO2 EOR project at Farnsworth Field, Texas. CO2 is anthropogenically sourced from a fertilizer and an ethanol plant. The field has 13 CO2 injectors and has sequestered 302,982 metric tonnes of CO2 since October 2013. The field site provides an excellent laboratory for testing a range of monitoring technologies in an operating CO2 flood since planned development is sequential and allows for multiple opportunities to record zero CO2 baseline data, mid-flood data, and fully flooded data. The project is comparing and contrasting several scales of seismic technologies in order to determine best practices for large scale commercial sequestration projects. Characterization efforts include an 85 km2 3D surface seismic survey, baseline and repeat 3D VSP surveys centered on injection wells, cross-well tomography baseline and repeat surveys between injector/producer pairs, and a borehole passive seismic array to monitor induced seismicity. All surveys have contributed to detailed geologic models which were then used for fluid flow and risk assessment simulations. 3D VSP and cross-well data with repeat surveys have allowed for direct comparisons of the reservoir prior to CO2 injection and at eight months into injection, with a goal of imaging the CO2 plume as it moves away from injection wells. Additional repeat surveys at regular intervals will continue to refine the plume. The goal of this work is to demonstrate seismic based technologies to monitor CO2 sequestration projects, and to contribute to best practices manuals for commercial scale CO2 sequestration projects. In this talk the seismic plan will be outlined, progress towards goals enumerated, and preliminary results from baseline and repeat seismic data will be discussed. Funding for this project is provided by the U.S. Department of Energy under Award No. DE-FC26-05NT42591.

Impulse-response functions and anthropogenic CO2

NASA Technical Reports Server (NTRS)

Tubiello, Francesco N.; Oppenheimer, Michael

1995-01-01

Non-linearities in the carbon cycle make the response to atmospheric CO2 perturbations dependent on emission history. We show that even when linear representations of the carbon cycle are used, the calculation of time scales characterizing the removal of excess CO2 depends on past emissions.

Experimental study on water content detection of traditional masonry based on infrared thermal image

NASA Astrophysics Data System (ADS)

Zhang, Baoqing; Lei, Zukang

2017-10-01

Based on infrared thermal imaging technology for seepage test of two kinds of brick masonry, find out the relationship between the distribution of one-dimensional two brick surface temperature distribution and one-dimensional surface moisture content were determined after seepage brick masonry minimum temperature zone and water content determination method of the highest point of the regression equation, the relationship between temperature and moisture content of the brick masonry reflected the quantitative and establish the initial wet masonry building disease analysis method, then the infrared technology is applied to the protection of historic buildings in.

Effect of cyanato, azido, carboxylato, and carbonato ligands on the formation of cobalt(II) polyoxometalates: characterization, magnetic, and electrochemical studies of multinuclear cobalt clusters.

PubMed

Lisnard, Laurent; Mialane, Pierre; Dolbecq, Anne; Marrot, Jérôme; Clemente-Juan, Juan Modesto; Coronado, Eugenio; Keita, Bineta; de Oliveira, Pedro; Nadjo, Louis; Sécheresse, Francis

2007-01-01

Five Co(II) silicotungstate complexes are reported. The centrosymmetric heptanuclear compound K(20)[{(B-beta-SiW(9)O(33)(OH))(beta-SiW(8)O(29)(OH)(2))Co(3)(H(2)O)}(2)Co(H(2)O)(2)]47 H(2)O (1) consists of two {(B-beta-SiW(9)O(33)(OH))(beta-SiW(8)O(29)(OH)(2))Co(3)(H(2)O)} units connected by a {CoO(4)(H(2)O)(2)} group. In the chiral species K(7)[Co(1.5)(H(2)O)(7))][(gamma-SiW(10)O(36))(beta-SiW(8)O(30)(OH))Co(4)(OH)(H(2)O)(7)]36 H(2)O (2), a {gamma-SiW(10)O(36)} and a {beta-SiW(8)O(30)(OH)} unit enclose a mononuclear {CoO(4)(H(2)O)(2)} group and a {Co(3)O(7)(OH)(H(2)O)(5)} fragment. The two trinuclear Co(II) clusters present in 1 enclose a mu(4)-O atom, while in 2 a mu(3)-OH bridging group connects the three paramagnetic centers of the trinuclear unit, inducing significantly larger Co-L-Co (L=mu(4)-O (1), mu(3)-OH (2)) bridging angles in 2 (theta(av(Co-L-Co))=99.1 degrees ) than in 1 (theta(av(Co-L-Co))=92.8 degrees ). Weaker ferromagnetic interactions were found in 2 than in 1, in agreement with larger Co-L-Co angles in 2. The electrochemistry of 1 was studied in detail. The two chemically reversible redox couples observed in the positive potential domain were attributed to the redox processes of Co(II) centers, and indicated that two types of Co(II) centers in the structure were oxidized in separate waves. Redox activity of the seventh Co(II) center was not detected. Preliminary experiments indicated that 1 catalyzes the reduction of nitrite and NO. Remarkably, a reversible interaction exists with NO or related species. The hybrid tetranuclear complexes K(5)Na(3)[(A-alpha-SiW(9)O(34))Co(4)(OH)(3)(CH(3)COO)(3)]18 H(2)O (3) and K(5)Na(3)[(A-alpha-SiW(9)O(34))Co(4)(OH)(N(3))(2)(CH(3)COO)(3)]18 H(2)O (4) were characterized: in both, a tetrahedral {Co(4)(L(1))(L(2))(2)(CH(3)COO)(3)} (3: L(1)=L(2)=OH; 4: L(1)=OH, L(2)=N(3)) unit capped the [A-alpha-SiW(9)O(34)](10-) trivacant polyanion. The octanuclear complex K(8)Na(8)[(A-alpha-SiW(9)O(34))(2)Co(8)(OH)(6)(H(2)O)(2)(CO(3))(3)]52 H(2)O (5), containing two {Co(4)O(9)(OH)(3)(H(2)O)} units, was also obtained. Compounds 2, 3, 4, and 5 were less stable than 1, but their partial electrochemical characterization was possible; the electronic effect expected for 3 and 4 was observed.

Atmospheric and geogenic CO2 within the crown and root of spruce (Picea abies L. Karst.) growing in a mofette area

NASA Astrophysics Data System (ADS)

Vodnik, D.; Thomalla, A.; Ferlan, M.; Levanič, T.; Eler, K.; Ogrinc, N.; Wittmann, C.; Pfanz, H.

2018-06-01

Mofettes are often investigated in ecology, either as extreme sites, natural analogues to future conditions under climate change, or model ecosystems for environmental impact assessments of carbon capture and storage systems. Much of this research, however, inadequately addresses the complexity of the gas environment at these sites, mainly focusing on aboveground CO2-enrichment. In the current research, the gaseous environment of Norway spruce (Picea abies (L) Karst.) trees growing at the Stavešinske slepice mofette (NE Slovenia) were studied by measuring both soil ([CO2]soil) and atmospheric CO2 concentrations ([CO2]air). Within the studied site (800 m2), soil CO2 enrichment was spatially heterogeneous; about 25% of the area was characterized by very high [CO2]soil (>40%) and hypoxic conditions. Aboveground gas measurements along vertical profiles not only revealed substantially elevated [CO2]air close to the ground (height up to 1.5 m), but also in the upper heights (20-25 m; crown layer). On the basis δ13C of CO2, it was shown that elevated CO2 relates to a geogenic source. Trees grown in high [CO2]soil were characterized by decreased radial growth; the δ13C of their wood was less negative than in trees growing in normal soil. Unfavorable gaseous soil conditions should generally be accepted as being by far the most important factor affecting (i.e. disturbing) the growth of mofette trees.

Titanium-incorporated organic–inorganic hybrid adsorbent for improved CO{sub 2} adsorption performance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Xiaoyun; Qin, Hongyan; Zhang, Sisi

2015-02-15

Highlights: • Titanium-incorporated organic–inorganic hybrid adsorbent was prepared. • The incorporation of Ti to the adsorbent showed significant effect. • The sorbent shows high CO{sub 2} capture capacity both in pure and diluted CO{sub 2} at RT. • The sorbent exhibits a high recycling stability after 15 cycling runs. - Abstract: The CO{sub 2} adsorption performance of acrylonitrile (AN)–tetraethylenepentamine (TEPA) adduct (hereafter referred to as TN) impregnated adsorbent was greatly enhanced by introduction of Titanium atom into the silica matrix. The adsorbents were characterized by X-ray fluorescence spectrometry (XRF), X-ray diffraction (XRD), transmission electron microscopy (TEM), N{sub 2} adsorption/desorption, UV–vismore » spectroscopy, Fourier transform infrared (FTIR) spectroscopy. The adsorption experiments together with the physicochemical characterization demonstrated that these adsorbents containing an optimal amount of Titanium (Ti/Si ≈ 0.1) remarkably reinforced the CO{sub 2} adsorption capacity and recycling stability. The highest CO{sub 2} uptakes reached 4.65 and 1.80 mmol CO{sub 2}/g adsorbent at 25 °C under 90% CO{sub 2} (CO{sub 2}/N{sub 2}, 90:10 V/V) and 1% CO{sub 2} (CO{sub 2}/N{sub 2}, 1:99 V/V) conditions for sample Ti(0.1)-DMS-TN, respectively. Repeated adsorption/desorption cycles revealed that the Ti-incorporated adsorbent showed only a tiny decrease in adsorption capacity (1.778 mmol CO{sub 2}/g adsorbent after 15 cycles, decreased by 0.95%), significantly enhanced the adsorbent recycling stability.« less

Hydrothermal synthesis and characterization of a novel supramolecular network compound of Co(NIA) 2(H 2O) 4 with molecular ladder hydrogen bond chains (NIA=nicotinate)

NASA Astrophysics Data System (ADS)

Jia, Hong-Bin; Yu, Jie-Hui; Xu, Ji-Qing; Ye, Ling; Ding, Hong; Jing, Wei-Jie; Wang, Tie-Gang; Xu, Jia-Ning; Li, Zeng-Chun

2002-10-01

By hydrothermal method, a novel supramolecular compound, Co(NIA) 2(H 2O) 4 was synthesized and its structure was characterized with elemental analysis, FT-IR spectrum, TGA and X-ray diffractometer, indicating that it is a novel polyporous supramolecule with molecular ladder hydrogen-bonded chains. TGA curve shows its thermal stability up to 520 °C.

Advanced reservoir characterization and evaluation of CO{sub 2} gravity drainage in the naturally fractured Spraberry Trend Area, Class III

DOE Office of Scientific and Technical Information (OSTI.GOV)

Heckman, Tracy; Schechter, David S.

2000-04-11

The overall goal of this project was to assess the economic feasibility of CO{sub 2} flooding the naturally fractured Spraberry Trend Area in West Texas. This objective was accomplished by conducting research in four areas: (1) extensive characterization of the reservoirs, (2) experimental studies of crude oil/brine/rock (COBR) interaction in the reservoirs, (3) analytical and numerical simulation of Spraberry reservoirs, and, (4) experimental investigations on CO{sub 2} gravity drainage in Spraberry whole cores. This report provides results of the fourth year of the five-year project for each of the four areas including a status report of field activities leading upmore » to injection of CO{sub 2}.« less

Compendium of Abstracts on Statistical Applications in Geotechnical Engineering.

DTIC Science & Technology

1983-09-01

research in the application of probabilistic and statistical methods to soil mechanics, rock mechanics, and engineering geology problems have grown markedly...probability, statistics, soil mechanics, rock mechanics, and engineering geology. 2. The purpose of this report is to make available to the U. S...Deformation Dynamic Response Analysis Seepage, Soil Permeability and Piping Earthquake Engineering, Seismology, Settlement and Heave Seismic Risk Analysis

Environmental Assessment for Integrated Natural Resources Management Plan Activities at Eglin Air Force Base, Florida

DTIC Science & Technology

2013-01-28

and coordination services by planning for and adapting to a rapidly changing military mission. 2. Restore the longleaf pine ecosystem and recover...success by supporting the Eglin AFB NRS adaptive management efforts through statistically sound, scientifically based monitoring of community...conservation targets, including sandhills, flatwoods, steepheads, seepage slopes, and stream habitats. Ecological monitoring supports adaptive

Synthesis, characterization and evaluation of CO-oxidation catalysts for high repetition rate CO2 TEA lasers

NASA Technical Reports Server (NTRS)

Moser, Thomas P.

1990-01-01

An extremely active class of noble metal catalysts supported on titania was developed and fabricated at Hughes for the recombination of oxygen (O2) and carbon monoxide (CO) in closed-cycle CO2 TEA lasers. The incipient wetness technique was used to impregnate titania and alumina pellets with precious metals including platinum and palladium. In particular, the addition of cerium (used as an oxygen storage promoter) produced an extremely active Pt/Ce/TiO2 catalyst. By comparison, the complementary Pt/Ce/ gamma-Al2O3 catalyst was considerably less active. In general, chloride-free catalyst precursors proved critical in obtaining an active catalyst while also providing uniform metal distributions throughout the support structure. Detailed characterization of the Pt/Ce/TiO2 catalyst demonstrated uniform dendritic crystal growth of the metals throughout the support. Electron spectroscopy for Chemical Analysis (ESCA) analysis was used to characterize the oxidation states of Pt, Ce and Ti. The performance of the catalysts was evaluated with an integral flow reactor system incorporating real time analysis of O2 and CO. With this system, the transient and steady-state behavior of the catalysts were evaluated. The kinetic evaluation was complemented by tests in a compact, closed-cycle Hughes CO2 TEA laser operating at a pulse repetition rate of 100 Hz with a catalyst temperature of 75 to 95 C. The Pt/Ce/TiO2 catalyst was compatible with a C(13)O(16)2 gas fill.

X-ray and dielectric characterization of Co doped tetragonal BaTiO3 ceramics

NASA Astrophysics Data System (ADS)

Bujakiewicz-Koronska, R.; Vasylechko, L.; Markiewicz, E.; Nalecz, D. M.; Kalvane, A.

2017-01-01

The crystal structure modifications of BaTiO3 induced by cobalt doping were studied. The polycrystalline (1 - x)BaTiO3 + xCo2O3 samples, with x ≤ 10 wt.%, were prepared by high temperature sintering conventional method. According to X-ray phase and structural characterization, performed by full-profile Rietveld refinement technique, all synthesized samples showed tetragonal symmetry perovskite structure with minor amount of parasitic phases. Pure single-phase composition has been detected only in the low level of doping BaTiO3. It was indicated that substitution of Co for the Ti sites in the (1 - x)BaTiO3 + xCo2O3 series led to decrease of tetragonality (c/a) of the BaTiO3 perovskite structure. This effect almost vanished in the (1 - x)BaTiO3 + xCo2O3 samples with nominal Co content higher than ∼1 wt.%, in which precipitation of parasitic Co-containing phases CoO and Co2TiO4 has been observed. Based on the results, the solubility limit of Co in Ti sub-lattice in the (1 - x)BaTiO3 + xCo2O3 series is estimated as x = 0.75 wt.%.

Hydrochemical Impacts of CO2 Leakage on Fresh Groundwater: a Field Scale Experiment

NASA Astrophysics Data System (ADS)

Lions, J.; Gal, F.; Gombert, P.; Lafortune, S.; Darmoul, Y.; Prevot, F.; Grellier, S.; Squarcioni, P.

2013-12-01

One of the questions related to the emerging technology for Carbon Geological Storage concerns the risk of CO2 migration beyond the geological storage formation. In the event of leakage toward the surface, the CO2 might affect resources in neighbouring formations (geothermal or mineral resources, groundwater) or even represent a hazard for human activities at the surface or in the subsurface. In view of the preservation of the groundwater resources mainly for human consumption, this project studies the potential hydrogeochemical impacts of CO2 leakage on fresh groundwater quality. One of the objectives is to characterize the bio-geochemical mechanisms that may impair the quality of fresh groundwater resources in case of CO2 leakage. To reach the above mentioned objectives, this project proposes a field experiment to characterize in situ the mechanisms that could impact the water quality, the CO2-water-rock interactions and also to improve the monitoring methodology by controlled CO2 leakage in shallow aquifer. The tests were carried out in an experimental site in the chalk formation of the Paris Basin. The site is equipped with an appropriate instrumentation and was previously characterized (8 piezometers, 25 m deep and 4 piezairs 11 m deep). The injection test was preceded by 6 months of monitoring in order to characterize hydrodynamics and geochemical baselines of the site (groundwater, vadose and soil). Leakage into groundwater is simulated via the injection of a small quantity of food-grade CO2 (~20 kg dissolved in 10 m3 of water) in the injection well at a depth of about 20 m. A plume of dissolved CO2 is formed and moves downward according to the direction of groundwater flow and probably by degassing in part to the surface. During the injection test, hydrochemical monitoring of the aquifer is done in situ and by sampling. The parameters monitored in the groundwater are the piezometric head, temperature, pH and electrical conductivity. Analysis on water samples provide chemical elements (major, minor and trace metals), dissolved gases, microbiological diversity and isotopes (13C). The evolution of the composition of the groundwater in terms of major elements, trace elements and isotope signatures is interpreted in terms of geochemical mechanisms, and the water-rock-CO2 interactions are characterized. Modification of the chemical composition of water in the aquifer due to CO2 injection is assessed in term of groundwater quality i.e. metal element release and the possibility of exceeding references and quality of water for human consumption. One outcome of the CIPRES project will be to highlight mechanisms that can impact groundwater quality when a CO2 leakage occurs and to propose recommendations to prevent or/and eliminate negative effects and any risks to the environment and human health. This project is partially funded by the French Research Agency (ANR).

A study of [Co2(alkyne)(binap)(CO)4] complexes (BINAP=(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine)).

PubMed

Gibson, Susan E; Kaufmann, Karina A C; Loch, Jennifer A; Steed, Jonathan W; White, Andrew J P

2005-04-08

Understanding the interaction of chiral ligands, alkynes, and alkenes with cobaltcarbonyl sources is critical to learning more about the mechanism of the catalytic, asymmetric Pauson-Khand reaction. We have successfully characterized complexes of the type [Co2(alkyne)(binap)(CO)4] (BINAP=(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine)) and shown that diastereomer interconversion occurs under Pauson-Khand reaction conditions when alkyne=HC[triple bond]CCO2Me. Attempts to isolate [Co2(alkyne)(binap)(CO)x] complexes with coordinated alkenes led to the formation of cobaltacyclopentadiene species.

CHARACTERIZATION OF CoRoT TARGET FIELDS WITH BERLIN EXOPLANET SEARCH TELESCOPE. II. IDENTIFICATION OF PERIODIC VARIABLE STARS IN THE LRc2 FIELD

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kabath, P.; Fruth, T.; Rauer, H.

2009-04-15

We report on photometric observations of the CoRoT LRc2 field with the new robotic Berlin Exoplanet Search Telescope II (BEST II). The telescope system was installed and commissioned at the Observatorio Cerro Armazones, Chile, in 2007. BEST II is a small aperture telescope with a wide field of view dedicated to the characterization of the stellar variability primarily in CoRoT target fields with high stellar densities. The CoRoT stellar field LRc2 was observed with BEST II up to 20 nights in 2007 July and August. From the acquired data containing about 100,000 stars, 426 new periodic variable stars were identifiedmore » and 90% of them are located within the CoRoT exoplanetary CCD segments and may be of further interest for CoRoT additional science programs.« less

Cold seeps and splay faults on Nankai margin

NASA Astrophysics Data System (ADS)

Henry, P.; Ashi, J.; Tsunogai, U.; Toki, T.; Kuramoto, S.; Kinoshita, M.; Lallemant, S. J.

2003-04-01

Cold seeps (bacterial mats, specific fauna, authigenic carbonates) are common on the Nankai margin and considered as evidence for seepage of methane bearing fluids. Camera and submersible surveys performed over the years have shown that cold seeps are generally associated with active faults. One question is whether part of the fluids expelled originate from the seismogenic zone and migrate along splay faults to the seafloor. The localisation of most cold seeps on the hanging wall of major thrusts may, however, be interpreted in various ways: (a) footwall compaction and diffuse flow (b) fluid channelling along the fault zone at depths and diffuse flow near the seafloor (c) erosion and channelling along permeable strata. In 2002, new observations and sampling were performed with submersible and ROV (1) on major thrusts along the boundary between the Kumano forearc basin domain and the accretionary wedge domain, (2) on a fault affecting the forearc (Kodaiba fault), (3) on mud volcanoes in the Kumano basin. In area (1) tsunami and seismic inversions indicate that the targeted thrusts are in the slip zone of the To-Nankai 1944 earthquakes. In this area, the largest seep zone, continuous over at least 2 km, coincides with the termination of a thrust trace, indicating local fluid channelling along the edge of the fault zone. Kodaiba fault is part of another splay fault system, which has both thrusting and strike-slip components and terminates westward into an en-echelon fold system. Strong seepage activity with abundant carbonates was found on a fold at the fault termination. One mud volcano, rooted in one of the en-echelon fold, has exceptionally high seepage activity compared with the others and thick carbonate crusts. These observations suggest that fluid expulsion along fault zones is most active at fault terminations and may be enhanced during fault initiation. Preliminary geochemical results indicate signatures differ between seep sites and suggests that the two fault systems tap in different sources.

Methane emission and consumption at a North Sea gas seep (Tommeliten area)

NASA Astrophysics Data System (ADS)

Niemann, H.; Elvert, M.; Hovland, M.; Orcutt, B.; Judd, A.; Suck, I.; Gutt, J.; Joye, S.; Damm, E.; Finster, K.; Boetius, A.

The Tommeliten seepage area is part of the Greater Ekofisk area, which is situated above the Tommeliten Delta salt diapir in the central North Sea (56°29.90' N, 2°59.80' E, Norwegian Block 1/9, 75 m water depth). Here, cracks in a buried marl horizon allow methane to migrate into overlying clay-silt and sandy sediments. Hydroacoustic sediment echosounding showed several venting spots coinciding with the apex of marl domes where methane is released into the water column and potentially to the atmosphere. In the vicinity of the gas seeps, sea floor observations showed small mats of giant sulphide-oxidizing bacteria above patches of black sediments as well as carbonate crusts, which are exposed 10 to 50 cm above seafloor forming small reefs. These Methane-Derived Authigenic Carbonates (MDACs) contain 13C-depleted, archaeal lipids indicating previous gas seepage and AOM activity. High amounts of sn2-hydroxyarchaeol relative to archaeol and low abundances of biphytanes in the crusts give evidence that ANaerobic MEthane-oxidising archaea (ANME) of the phylogenetic cluster ANME-2 were the potential mediators of Anaerobic Oxidation of Methane (AOM) at the time of carbonate formation. Small pieces of MDACs were also found subsurface at about 1.7 m sediment depth, associated with the AOM zone. This zone is characterized by elevated AOM and Sulphate Reduction (SR) rates, increased concentrations of 13C-depleted tetraether derived biphytanes, and specific bacterial Fatty Acids (FA). Further biomarker and 16S rDNA based analyses of this horizon give evidence that AOM is mediated by archaea belonging to the ANME-1b group and Sulphate Reducing Bacteria (SRB) most likely belonging to the Seep-SRB1 cluster. The zone of active methane consumption was restricted to a distinct horizon of about 20 cm. Concentrations of 13C-depleted lipid biomarkers (e.g. 500 ng g-dw-1 biphythanes, 140 ng g-dw-1 fatty acid ai-C15:0), cell numbers (1.5×108 cells cm-3), AOM and SR rates (3 nmol cm-3 d-1) in the Tommeliten AOM zone are 2 3 orders of magnitude lower compared to AOM zones of highly active deep water cold seeps such as Hydrate Ridge or the Gulf of Mexico.

Encapsulation of CO2 into amorphous alpha-cyclodextrin powder at different moisture contents - Part 2: Characterization of complexed powders and determination of crystalline structure.

PubMed

Ho, Thao M; Howes, Tony; Jack, Kevin S; Bhandari, Bhesh R

2016-09-01

This study aims to characterize CO2-α-cyclodextrin (α-CD) inclusion complexes produced from amorphous α-CD powder at moisture contents (MC) close to or higher than the critical level of crystallization (e.g. 13, 15 and 17% MC on wet basis, w.b.) at 0.4 and 1.6MPa pressure for 72h. The results of (13)C NMR, SEM, DSC and X-ray analyses showed that these MC levels were high enough to induce crystallization of CO2-α-CD complexed powders during encapsulation, by which amount of CO2 encapsulated by amorphous α-CD powder was significantly increased. The formation of inclusion complexes were well confirmed by results of FTIR and (13)C NMR analyses through an appearance of a peak associated with CO2 on the FTIR (2334cm(-1)) and NMR (125.3ppm) spectra. Determination of crystal packing patterns of CO2-α-CD complexed powders showed that during crystallization, α-CD molecules were arranged in cage-type structure in which CO2 molecules were entrapped in isolated cavities. Copyright © 2016 Elsevier Ltd. All rights reserved.

Hydrosalinity studies of the Virgin River, Dixie Hot Springs, and Littlefield Springs, Utah, Arizona, and Nevada

USGS Publications Warehouse

Gerner, Steven J.; Thiros, Susan A.; Gerner, Steven J.; Thiros, Susan A.

2014-01-01

The Virgin River contributes a substantial amount of dissolved solids (salt) to the Colorado River at Lake Mead in the lower Colorado River Basin. Degradation of Colorado River water by the addition of dissolved solids from the Virgin River affects the suitability of the water for municipal, industrial, and agricultural use within the basin. Dixie Hot Springs in Utah are a major localized source of dissolved solids discharging to the Virgin River. The average measured discharge from Dixie Hot Springs during 2009–10 was 11.0 cubic feet per second (ft3/s), and the average dissolved-solids concentration was 9,220 milligrams per liter (mg/L). The average dissolved-solids load—a measurement that describes the mass of salt that is transported per unit of time—from Dixie Hot Springs during this period was 96,200 tons per year (ton/yr). Annual dissolved-solids loads were estimated at 13 monitoring sites in the Virgin River Basin from streamflow data and discrete measurements of dissolved-solids concentrations and (or) specific conductance. Eight of the sites had the data needed to estimate annual dissolved-solids loads for water years (WYs) 1999 through 2010. During 1999–2010, the smallest dissolved-solids loads in the Virgin River were upstream of Dixie Hot Springs (59,900 ton/yr, on average) and the largest loads were downstream of Littlefield Springs (298,200 ton/yr, on average). Annual dissolved-solids loads were smallest during 2002–03, which was a period of below normal precipitation. Annual dissolved-solids loads were largest during 2005—a year that included a winter rain storm that resulted in flooding throughout much of the Virgin River Basin. An average seepage loss of 26.7 ft3/s was calculated from analysis of monthly average streamflow from July 1998 to September 2010 in the Virgin River for the reach that extends from just upstream of the Utah/Arizona State line to just above the Virgin River Gorge Narrows. Seepage losses from three river reaches in the Virgin River Gorge containing known fault zones accounted for about 48 percent of this total seepage loss. An additional seepage loss of 6.7 ft3/s was calculated for the reach of the Virgin River between Bloomington, Utah, and the Utah/Arizona State line. This loss in flow is small compared to total flow in the river and is comparable to the rated error in streamflow measurements in this reach; consequently, it should be used with caution. Littlefield Springs were studied to determine the fraction of its discharge that originates as upstream seepage from the Virgin River and residence time of this water in the subsurface. Geochemical and environmental tracer data from groundwater and surface-water sites in the Virgin River Gorge area suggest that discharge from Littlefield Springs is a mixture of modern (post-1950s) seepage from the Virgin River upstream of the springs and older groundwater from a regional carbonate aquifer. Concentrations of the chlorofluorocarbons (CFCs) CFC-12 and CFC-113, chloride/fluoride and chloride/bromide ratios, and the stable isotope deuterium indicate that water discharging from Littlefield Springs is about 60 percent seepage from the Virgin River and about 40 percent discharge from the regional carbonate aquifer. The river seepage component was determined to have an average subsurface traveltime of about 26 ±1.6 years before discharging at Littlefield Springs. Radiocarbon data for Littlefield Springs suggest groundwater ages from 1,000 to 9,000 years. Because these are mixed waters, the component of discharge from the carbonate aquifer is likely much older than the groundwater ages suggested by the Littlefield Springs samples. If the dissolved-solids load from Dixie Hot Springs to the Virgin River were reduced, the irrigation water subsequently applied to agricultural fields in the St. George and Washington areas, which originates as water from the Virgin River downstream of Dixie Hot Springs, would have a lower dissolved-solids concentration. Dissolved-solids concentrations in excess irrigation water draining from the agricultural fields are about 1,700 mg/L higher than the concentrations in the Virgin River water that is currently (2014) used for irrigation that contains inflow from Dixie Hot Springs; this increase results from evaporative concentration and dissolution of mineral salts in the irrigated agricultural fields. The water samples collected from drains downgradient from the irrigated areas are assumed to include the dissolution of all available minerals precipitated in the soil during the previous irrigation season. Based on this assumption, a change to more dilute irrigation water will not dissolve additional minerals and increase the dissolved-solids load in the drain discharge. Following the hypothetical reduction of salts from Dixie Hot Springs, which would result in more dilute Virgin River irrigation water than is currently used, the dissolution of minerals left in the soil from the previous irrigation season would result in a net increase in dissolved-solids concentrations in the drain discharge, but this increase should only last one irrigation season. After one (or several) seasons of irrigating with more dilute irrigation water, mineral precipitation and subsequent re-dissolution beneath the agricultural fields should be greatly reduced, leading to a reduction in dissolved-solids load to the Virgin River below the agricultural drains. A mass-balance model was used to predict changes in the dissolved-solids load in the Virgin River if the salt discharging from Dixie Hot Springs were reduced or removed. Assuming that 33.4 or 26.7 ft3/s of water seeps from the Virgin River to the groundwater system upstream of the Virgin River Gorge Narrows, the immediate hypothetical reduction in dissolved-solids load in the Virgin River at Littlefield, Arizona is estimated to be 67,700 or 71,500 ton/yr, respectively. The decrease in dissolved-solids load in seepage from the Virgin River to the groundwater system is expected to reduce the load discharging from Littlefield Springs in approximately 26 years, the estimated time lag between seepage from the river and discharge of the seepage water, after subsurface transport, from Littlefield Springs. At that time, the entire reduction in dissolved solids seeping from the Virgin River is expected to be realized as a reduction in dissolved solids discharging from Littlefield Springs, resulting in an additional reduction of 24,700 ton/yr (based on 33.4 ft3/s of seepage loss) or 21,000 ton/yr (based on 26.7 ft3/s of seepage loss) in the river’s dissolved-solids load at Littlefield.

The (2×2) reconstructions on the surface of cobalt silicides: Atomic configuration at the annealed Co/Si(111) interface

NASA Astrophysics Data System (ADS)

Kotlyar, V. G.; Alekseev, A. A.; Olyanich, D. A.; Utas, T. V.; Zotov, A. V.; Saranin, A. A.

2017-08-01

We have used scanning tunneling microscopy (STM) and ab initio total-energy calculations to characterize surface and interfacial structure of Co-Si(111) system. It has been found experimentally that two different types of the (2×2) surface structures occur. The coexistence of two phases is demonstrated by the example of STM image of the surface formed at the early stages of cobalt silicide formation under moderate annealing temperatures (500 °C). The measured height difference between the adjacent (2×2) reconstructed patches equal to about 1.0 Å (as determined from the filled-state STM images). In addition, the shift of the atomic rows by half of the row spacing is observed. Two adatom models of the (2×2) surface structures are developed. According to our data, these structures are assigned to CaF2-type CoSi2 and CsCl-type CoSi with a (2×2) array of Si adatoms on their surfaces. If the latter is the case, it has а coherent double interface CoSi/CoSi2/Si(111) with a two-layer CoSi2. Both of these interfaces are characterized by the eightfold cobalt coordination and incorporate a grown-in stacking fault.

A numerical study of granular dam-break flow

NASA Astrophysics Data System (ADS)

Pophet, N.; Rébillout, L.; Ozeren, Y.; Altinakar, M.

2017-12-01

Accurate prediction of granular flow behavior is essential to optimize mitigation measures for hazardous natural granular flows such as landslides, debris flows and tailings-dam break flows. So far, most successful models for these types of flows focus on either pure granular flows or flows of saturated grain-fluid mixtures by employing a constant friction model or more complex rheological models. These saturated models often produce non-physical result when they are applied to simulate flows of partially saturated mixtures. Therefore, more advanced models are needed. A numerical model was developed for granular flow employing a constant friction and μ(I) rheology (Jop et al., J. Fluid Mech. 2005) coupled with a groundwater flow model for seepage flow. The granular flow is simulated by solving a mixture model using Finite Volume Method (FVM). The Volume-of-Fluid (VOF) technique is used to capture the free surface motion. The constant friction and μ(I) rheological models are incorporated in the mixture model. The seepage flow is modeled by solving Richards equation. A framework is developed to couple these two solvers in OpenFOAM. The model was validated and tested by reproducing laboratory experiments of partially and fully channelized dam-break flows of dry and initially saturated granular material. To obtain appropriate parameters for rheological models, a series of simulations with different sets of rheological parameters is performed. The simulation results obtained from constant friction and μ(I) rheological models are compared with laboratory experiments for granular free surface interface, front position and velocity field during the flows. The numerical predictions indicate that the proposed model is promising in predicting dynamics of the flow and deposition process. The proposed model may provide more reliable insight than the previous assumed saturated mixture model, when saturated and partially saturated portions of granular mixture co-exist.

Microbial communities in methane seep sediments along US Atlantic Margin are structured by organic matter and seepage dynamics

NASA Astrophysics Data System (ADS)

Graw, M. F.; Pohlman, J.; Treude, T.; Ruppel, C. D.; Colwell, F. S.

2016-12-01

Methane seeps are dynamic environments on continental margins where subsurface methane reaches the ocean. Microbial communities play a critical role in carbon cycling within seep sediments via organic carbon degradation, methane production, and anaerobic oxidation of methane (AOM), which consumes 20-80% of methane in seep sediments. However, biogeochemical controls on microbial community structure at seeps on a margin-wide scale remain unclear. The passive US Atlantic Margin (USAM) has been identified as a region of active methane seepage. Passive margin seeps have traditionally been understudied relative to seeps on active margins. Passive margins exhibit large cross-margin variability in organic carbon deposition and are anticipated to have divergent seep dynamics from active margins. Thus, the USAM offers a unique opportunity to investigate controls on microbial communities in seep sediments. We undertook analysis of microbial communities inhabiting seep sediments at 6 biogeochemically distinct sites along the USAM. Microbiological samples were co-located with measurements of sediment geochemistry and AOM and sulfate reduction rates. Illumina sequencing of the 16S rRNA gene, using both universal (83 samples) and archaeal-specific (64 samples) primers, and the mcrA gene (18 samples) identified 44 bacterial phyla and 7 archaeal phyla. Seeps in canyons and on open slope, likely representing high and low organic content sediments, hosted distinct communities; the former was dominated by ammonia-oxidizing Marine Group I Thaumarchaeota and the latter by mixotrophic Hadesarchaeota. Seep stability also impacted microbial community structure, and in particular the establishment of an AOM community rather than a Bathyarchaeota-dominated community. These findings contribute to understanding how microbial communities are structured within methane seep sediments and pave the way for investigating broad differences in carbon cycling between seeps on passive and active margins.

Preparation and characterization of cross-linked excipient of coprocessed xanthan gum-acacia gum as matrix for sustained release tablets

NASA Astrophysics Data System (ADS)

Surini, Silvia; Wati, Dina Risma; Syahdi, Rezi Riadhi

2018-02-01

Sustained release tablet is solid dosage form which is designed to release drugs slowly in the body. This research was intended to prepare and characterize the cross-linked excipients of co-processed xanthan gum-acacia gum (CL-Co-XGGA) as matrices for sustained release tablets with gliclazide as a model drug. CL-Co-XGGA excipients were cross-linked materials of co-processed excipients of xanthan gum-acacia gum (Co-XGGA) using sodium trimetaphosphate. Co-processed excipients of xanthan gum-acacia gum were prepared in the ratio of each excipient 1:2, 1:1 and 2:1. Co-XGGA and CL-Co-XGGA excipients were characterized physically, chemically and functionally. Then, the sustained release (SR) tablets were formulated by wet granulation method using CL-Co-XGGA excipients as matrices. Also, the dissolution study of the gliclazide SR tablets was carried out in phosphate buffer medium pH 7,4 containing sodium lauryl sulphate 0.2% for 12 hours. The results showed that the degree of substitution (DS) of CL-Co-XGGA 1:2, 1:1, 2:1 excipients were respectively 0.067, 0.082 and 0.08. Besides that, the excipients gel strengths were 14.03, 17.27 and 20,70 gF, respectively. The cross-linked excipients had improved flow properties and swelling capability compared to the Co-XGGA excipients. The results of the gliclazide SR tablets evaluations showed that all tablets were passed all tablet requirements. Moreover, the gliclazide release from SR tablets F1 - F6 revealed the sustained release profile, which was following zero order kinetics (F1, F2, F3, F6) and Higuchi kinetics (F4 and F5). It could be concluded that the obtained CL-Co-XGGA excipients might be used as matrices for sustained release tablets and could retard drug release up to 8 until 32 hours.

Single crystal growth and characterization of kagomé-lattice shandites Co3Sn2-xInxS2

NASA Astrophysics Data System (ADS)

Kassem, Mohamed A.; Tabata, Yoshikazu; Waki, Takeshi; Nakamura, Hiroyuki

2015-09-01

Single crystals of the shandite-type half metallic ferromagnet Co3Sn2S2, and its In-substituted compounds, Co3Sn2-xInxS2 (0

Synthesis, characterizations and catalytic studies of a new two-dimensional metal-organic framework based on Co-carboxylate secondary building units

NASA Astrophysics Data System (ADS)

Bagherzadeh, Mojtaba; Ashouri, Fatemeh; Đaković, Marijana

2015-03-01

A metal-organic framework [Co3(BDC)3(DMF)2(H2O)2] was synthesized and structurally characterized. X-ray single crystal analysis revealed that the framework contains a 2D polymeric chain through coordination of 1,4-benzenedicarboxylic acid linker ligand to cobalt centers. The polymer crystallize in monoclinic P21/n space group with a=13.989(3) Å, b=9.6728(17) Å, c=16.707(3) Å, and Z=2. The polymer features a framework based on the perfect octahedral Co-O6 secondary building units. The catalytic activities of [Co3(BDC)3(DMF)2(H2O)2]n for olefins oxidation was conducted. The heterogeneous catalyst could be facilely separated from the reaction mixture, and reused three times without significant degradation in catalytic activity. Furthermore, no contribution from homogeneous catalysis of active species leaching into reaction solution was detected.

Characterization of Intermediate Oxidation States in CO2 Activation

NASA Astrophysics Data System (ADS)

Dodson, Leah G.; Thompson, Michael C.; Weber, J. Mathias

2018-04-01

Redox chemistry during the activation of carbon dioxide involves changing the charge state in a CO2 molecular unit. However, such changes are usually not well described by integer formal charges, and one can think of COO functional units as being in intermediate oxidation states. In this article, we discuss the properties of CO2 and CO2-based functional units in various charge states. Besides covering isolated CO2 and its ions, we describe the CO2-based ionic species formate, oxalate, and carbonate. Finally, we provide an overview of CO2-based functional groups and ligands in clusters and metal-organic complexes.

Impacts of upwind wildfire emissions on CO, CO2, and PM2.5 concentrations in Salt Lake City, Utah

Treesearch

D. V. Mallia; J. C. Lin; S. Urbanski; J. Ehleringer; T. Nehrkorn

2015-01-01

Biomass burning is known to contribute large quantities of CO2, CO, and PM2.5 to the atmosphere. Biomass burning not only affects the area in the vicinity of fire but may also impact the air quality far downwind from the fire. The 2007 and 2012 western U.S. wildfire seasons were characterized by significant wildfire...

Reactivity of alkaline lignite fly ashes towards CO{sub 2} in water

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martin Back; Michael Kuehn; Helge Stanjek

2008-06-15

The reaction kinetics between alkaline lignite fly ashes and CO{sub 2} (pCO{sub 2} = 0.01-0.03 MPa) were studied in a laboratory CO{sub 2} flow-through reactor at 25-75{sup o}C. The reaction is characterized by three phases that can be separated according to the predominating buffering systems and the rates of CO{sub 2} uptake. Phase I (pH > 12, < 30 min) is characterized by the dissolution of lime, the onset of calcite precipitation and a maximum uptake, the rate of which seems to be limited by dissolution of CO{sub 2}. Phase II (pH < 10.5, 10-60 min) is dominated by themore » carbonation reaction. CO{sub 2} uptake in phase III (pH < 8.3) is controlled by the dissolution of periclase (MgO) leading to the formation of dissolved magnesium-bicarbonate. Phase I could be significantly extended by increasing the solid-liquid ratios and temperature, respectively. At 75{sup o}C the rate of calcite precipitation was doubled leading to the neutralization of approximately 0.23 kg CO{sub 2} per kg fly ash within 4.5 h, which corresponds to nearly 90% of the total acid neutralizing capacity. 21 refs., 5 figs., 1 tab.« less

Study of a series of cobalt(II) sulfonamide complexes: Synthesis, spectroscopic characterization, and microbiological evaluation against M. tuberculosis. Crystal structure of [Co(sulfamethoxazole)2(H2O)2]·H2O

NASA Astrophysics Data System (ADS)

Mondelli, Melina; Pavan, Fernando; de Souza, Paula C.; Leite, Clarice Q.; Ellena, Javier; Nascimento, Otaciro R.; Facchin, Gianella; Torre, María H.

2013-03-01

Nowadays, the research for new and better antimicrobial compounds is an important field due to the increase of immunocompromised patients, the use of invasive medical procedures and extensive surgeries, among others, that can affect the incidence of infections. Another big problem associated is the occurrence of drug-resistant microbial strains that impels a ceaseless search for new antimicrobial agents. In this context, a series of heterocyclic-sulfonamide complexes with Co(II) was synthesized and characterized with the aim of obtaining new antimicrobial compounds. The structural characterization was performed using different spectroscopic methods (UV-Vis, IR, and EPR). In spite of the fact that the general stoichiometry for all the complexes was Co(sulfonamide)2·nH2O, the coordination atoms were different depending on the coordinated sulfonamide. The crystal structure of [Co(sulfamethoxazole)2(H2O)2]·H2O was obtained by X-ray diffraction showing that Co(II) is in a slightly tetragonal distorted octahedron where sulfamethoxazole molecules act as a head-to-tail bridges between two cobalt atoms, forming polymeric chains. Besides, the activity against Mycobacterium tuberculosis, one of the responsible for tuberculosis, and the cytotoxicity on J774A.1 macrophage cells were evaluated.

Fluvial sediment in the little Arkansas River basin, Kansas

USGS Publications Warehouse

Albert, C.D.; Stramel, G.J.

1966-01-01

Characteristics and transport of sediment in the Little Arkansas River basin in south-central Kansas were studied to determine if the water from the river could be used as a supplemental source for municipal supply or would provide adequate recharge to aquifers that are sources of municipal and agricultural water supplies. During periods when overland 1low contributed a significant amount to streamflow, the suspended sediment in the Little Arkansas River at Valley Center averaged about 85 percent of clay, about 13 percent of silt, and about 2 percent of sand. The average annual suspended-sediment discharge for the water years 1958, 1959, 1960, and 1961 was about 306,000 tons, and about 80 percent of the load was transported during 133 days of the 1,461-day period. The average daily water discharge of 352 cubic feet per second for the period 1958-61 was more than the long-term (i}9-year) average of 245 cfs; therefore, the average annual sediment load for 1958-61 was probably greater than the average annual load for the same long-term period. Studies of seepage in a part of the channel of Kisiwa Creek indicated that an upstream gravel-pit operation yielded clays which, when deposited in the channel, reduced seepage. A change in plant operation and subsequent runoff that removed the deposited clays restored natural seepage conditions. Experiments by the Wichita Water Department showed that artificial recharge probably cannot be accomplished by using raw turbid water that is injected into wells or by using pits. Recharge by raw turbid water on large permeable areas or by seepage canals may be feasible. Studies of chemical quality of surface water at several sites in the Little Arkansas River basin indicate that Turkey. Creek is a major contributor of chloride and other dissolved solids to the Little Arkansas River and that the dissolved-solids content is probably highest during low-flow periods when suspended-sediment concentration is low. Data collected by the Wichita Water Department indicate that chloride concentrations are diminishing with time at sampled locations. and they receive recharge from rainwater and snowmelt moving through overlying alluvium and from storage in the De Chelly sandstone which encloses the east half of the diatreme. The quality of water from all areas is suitable for domestic use. However, special treatment may be necessary to make the water suitable for pulp processing.

Simulated ground-water flow in the Hueco Bolson, an alluvial-basin aquifer system near El Paso, Texas

USGS Publications Warehouse

Heywood, Charles E.; Yager, Richard M.

2003-01-01

The neighboring cities of El Paso, Texas, and Ciudad Juarez, Chihuahua, Mexico, have historically relied on ground-water withdrawals from the Hueco Bolson, an alluvial-aquifer system, to supply water to their growing populations. By 1996, ground-water drawdown exceeded 60 meters in some areas under Ciudad Juarez and El Paso. A simulation of steady-state and transient ground-water flow in the Hueco Bolson in westernmost Texas, south-central New Mexico, and northern Chihuahua, Mexico, was developed using MODFLOW-96. The model is needed by El Paso Water Utilities to evaluate strategies for obtaining the most beneficial use of the Hueco Bolson aquifer system. The transient simulation represents a period of 100 years beginning in 1903 and ending in 2002. The period 1903 through 1968 was represented with 66 annual stress periods, and the period 1969 through 2002 was represented with 408 monthly stress periods. The ground-water flow model was calibrated using MODFLOWP and UCODE. Parameter values representing aquifer properties and boundary conditions were adjusted through nonlinear regression in a transient-state simulation with 96 annual time steps to produce a model that approximated (1) 4,352 water levels measured in 292 wells from 1912 to 1995, (2) three seepage-loss rates from a reach of the Rio Grande during periods from 1979 to 1981, (3) three seepage-loss rates from a reach of the Franklin Canal during periods from 1990 to 1992, and (4) 24 seepage rates into irrigation drains from 1961 to 1983. Once a calibrated model was obtained with MODFLOWP and UCODE, the optimal parameter set was used to create an equivalent MODFLOW-96 simulation with monthly temporal discretization to improve computations of seepage from the Rio Grande and to define the flow field for a chloride-transport simulation. Model boundary conditions were modified at appropriate times during the simulation to represent changes in well pumpage, drainage of agricultural fields, and channel modifications of the Rio Grande. The model input was generated from geographic information system databases, which facilitated rapid model construction and enabled testing of several conceptualizations of hydrogeologic facies boundaries. Specific yield of unconfined layers and hydraulic conductance of Quaternary faults in the fluvial facies were the most sensitive model parameters, suggesting that ground-water flow is impeded across the fault planes.

A laboratory study of supercritical CO2 adsorption on cap rocks in the geological storage conditions

NASA Astrophysics Data System (ADS)

Jedli, Hedi; Jbara, Abdessalem; Hedfi, Hachem; Bouzgarrou, Souhail; Slimi, Khalifa

2017-04-01

In the present study, various cap rocks have been experimentally reacted in water with supercritical CO2 in geological storage conditions ( P = 8 × 106 Pa and T = 80 °C) for 25 days. To characterize the potential CO2-water-rock interactions, an experimental setup has been built to provide additional information concerning the effects of structure, thermal and surface characteristics changes due to CO2 injection with cap rocks. In addition, CO2 adsorption capacities of different materials (i.e., clay evaporate and sandstone) are measured. These samples were characterized by XRD technique. The BET specific surface area was determined by nitrogen isotherms. In addition, thermal characteristics of untreated adsorbents were analyzed via TGA method and topography surfaces are identified by Scanning Electron Microscope (SEM). Taking into account pressure and temperature, the physical as well as chemical mechanisms of CO2 retention were determined. Isotherm change profiles of samples for relative pressure range indicate clearly that CO2 was adsorbed in different quantities. In accordance with the X-ray diffraction, a crystalline phase was formed due to the carbonic acid attack and precipitation of some carbonate.

Flow of ground water through fractured carbonate rocks in the Prairie du Chien-Jordan Aquifer, southeastern Minnesota

USGS Publications Warehouse

Ruhl, J.F.

1989-01-01

Contamination of groundwater from point and nonpoint sources (such as landfills, feedlots, agricultural chemicals applied to fields, and septic systems) is a recognized problem in the karst area of southeastern Minnesota. The US Geological Survey, in cooperation with the Minnesota Department of Natural Resources and the Legislative Commission on Minnesota Resources, Began a study in October 1987 to improve the understanding of local groundwater flow through karst terrain in southeastern Minnesota. The objectives of the study are to: (1) describe the orientations of systematic rock fractures and solution channels of the Prairie du Chien Group of Ordovician-age carbonate rocks in southeastern Minnesota, and, if possible, to define the principal and minor axes of these orientations; and (2) evaluate the effect of fractures and solution channels in the Prairie du Chien Group on the local flow of groundwater. Groundwater in the Upper Carbonate aquifer regionally flows toward the periphery of the aquifer and locally flows into streams and bedrock valleys. The hydraulic gradient in this aquifer generally is greatest near areas of groundwater seepage to streams. Regional groundwater flow in the Prairie du Chien-Jordan aquifer generally is to the south and east in much of Fillmore and Houston Counties and in the southern parts of Olmsted and Winona Counties. Groundwater seepage to selected streams was evaluated by current-meter measurements of downstream gains or losses of streamflow and by an experimental approach based on radon activity in streams. The activity of radon in groundwater ranges from two to four orders of magnitude greater than the activity in surface water; therefore, groundwater seepage to streams generally increases the in-stream radon activity.

Porous media flux sensitivity to pore-scale geostatistics: A bottom-up approach

NASA Astrophysics Data System (ADS)

Di Palma, P. R.; Guyennon, N.; Heße, F.; Romano, E.

2017-04-01

Macroscopic properties of flow through porous media can be directly computed by solving the Navier-Stokes equations at the scales related to the actual flow processes, while considering the porous structures in an explicit way. The aim of this paper is to investigate the effects of the pore-scale spatial distribution on seepage velocity through numerical simulations of 3D fluid flow performed by the lattice Boltzmann method. To this end, we generate multiple random Gaussian fields whose spatial correlation follows an assigned semi-variogram function. The Exponential and Gaussian semi-variograms are chosen as extreme-cases of correlation for short distances and statistical properties of the resulting porous media (indicator field) are described using the Matèrn covariance model, with characteristic lengths of spatial autocorrelation (pore size) varying from 2% to 13% of the linear domain. To consider the sensitivity of the modeling results to the geostatistical representativeness of the domain as well as to the adopted resolution, porous media have been generated repetitively with re-initialized random seeds and three different resolutions have been tested for each resulting realization. The main difference among results is observed between the two adopted semi-variograms, indicating that the roughness (short distances autocorrelation) is the property mainly affecting the flux. However, computed seepage velocities show additionally a wide variability (about three orders of magnitude) for each semi-variogram model in relation to the assigned correlation length, corresponding to pore sizes. The spatial resolution affects more the results for short correlation lengths (i.e., small pore sizes), resulting in an increasing underestimation of the seepage velocity with the decreasing correlation length. On the other hand, results show an increasing uncertainty as the correlation length approaches the domain size.

Effects of near-surface hydraulic gradients on nitrate and phosphorus losses in surface runoff.

PubMed

Zheng, Fen-Li; Huang, Chi-Hua; Norton, L Darrell

2004-01-01

Phosphorous (P) and nitrogen (N) in runoff from agricultural fields are key components of nonpoint-source pollution and can accelerate eutrophication of surface waters. A laboratory study was designed to evaluate effects of near-surface hydraulic gradients on P and N losses in surface runoff from soil pans at 5% slope under simulated rainfall. Experimental treatments included three rates of fertilizer input (control [no fertilizer input], low [40 kg P ha(-1), 100 kg N ha(-1)], and high [80 kg P ha(-1), 200 kg N ha(-1)]) and four near-surface hydraulic gradients (free drainage [FD], saturation [Sa], artesian seepage without rain [Sp], and artesian seepage with rain [Sp + R]). Simulated rainfall of 50 mm h(-1) was applied for 90 min. The results showed that near-surface hydraulic gradients have dramatic effects on NO(3)-N and PO(4)-P losses and runoff water quality. Under the low fertilizer treatment, the average concentrations in surface runoff from FD, Sa, Sp, and Sp + R were 0.08, 2.20, 529.5, and 71.8 mg L(-1) for NO(3)-N and 0.11, 0.54, 0.91, and 0.72 mg L(-1) for PO(4)-P, respectively. Similar trends were observed for the concentrations of NO(3)-N and PO(4)-P under the high fertilizer treatment. The total NO(3)-N loss under the FD treatment was only 0.01% of the applied nitrogen, while under the Sp and Sp + R treatments, the total NO(3)-N loss was 11 to 16% of the applied nitrogen. These results show that artesian seepage could make a significant contribution to water quality problems.

Methods to quantify seepage beneath Levee 30, Miami-Dade County, Florida

USGS Publications Warehouse

Sonenshein, R.S.

2001-01-01

A two-dimensional, cross-sectional, finite-difference, ground-water flow model and a simple application of Darcy?s law were used to quantify ground-water flow (from a wetlands) beneath Levee 30 in Miami-Dade County, Florida. Geologic and geophysical data, vertical seepage data from the wetlands, canal discharge data, ground-water-level data, and surface-water-stage data collected during 1995 and 1996 were used as boundary conditions and calibration data for the ground-water flow model and as input for the analytical model. Vertical seepage data indicated that water from the wetlands infiltrated the subsurface, near Levee 30, at rates ranging from 0.033 to 0.266 foot per day when the gates at the control structures along Levee 30 canal were closed. During the same period, stage differences between the wetlands (Water Conservation Area 3B) and Levee 30 canal ranged from 0.11 to 1.27 feet. A layer of low-permeability limestone, located 7 to 10 feet below land surface, restricts vertical flow between the surface water in the wetlands and the ground water. Based on measured water-level data, ground-water flow appears to be generally horizontal, except in the direct vicinity of the canal. The increase in discharge rate along a 2-mile reach of the Levee 30 canal ranged from 9 to 30 cubic feet per second per mile and can be attributed primarily to ground-water inflow. Flow rates in Levee 30 canal were greatest when the gates at the control structures were open. The ground-water flow model data were compared with the measured ground-water heads and vertical seepage from the wetlands. Estimating the horizontal ground-water flow rate beneath Levee 30 was difficult owing to the uncertainty in the horizontal hydraulic conductivity of the main flow zone of the Biscayne aquifer. Measurements of ground-water flows into Levee 30 canal, a substantial component of the water budget, were also uncertain, which lessened the ability to validate the model results. Because of vertical flows near Levee 30 canal and a very low hydraulic gradient east of the canal, a simplified Darcian approach simulated with the ground-water flow model does not accurately estimate the horizontal ground-water flow rate. Horizontal ground-water flow rates simulated with the ground-water flow model (for a 60-foot-deep by 1-foot-wide section of the Biscayne aquifer) ranged from 150 to 450 cubic feet per day west of Levee 30 and from 15 to 170 cubic feet per day east of Levee 30 canal. Vertical seepage from the wetlands, within 500 feet of Levee 30, generally accounted for 10 to 15 percent of the total horizontal flow beneath the levee. Simulated horizontal ground-water flow was highest during the wet season and when the gates at the control structures were open.

The Elusive Palladium-Diazo Adduct Captured: Synthesis, Isolation and Structural Characterization of [(ArNHC-PPh2 )Pd(η2 -N2 C(Ph)CO2 Et)].

PubMed

Rull, Silvia G; Álvarez, Eleuterio; Fructos, Manuel R; Belderrain, Tomás R; Pérez, Pedro J

2017-06-07

The first example of a diazo palladium adduct is reported. The complexes [(ArNHC-PPh 2 )M(η 2 -N 2 C(Ph)CO 2 Et)] (M=Ni, 3; M=Pd, 4; ArNHC-PPh 2 =3-(2,6-diisopropylphenyl)-1-[(diphenylphosphino)ethyl]imidazol-2-ylidene) were prepared by ligand exchange with styrene-coordinated precursors [(ArNHC-PPh 2 )M(styrene)] (M=Ni, 1; M=Pd, 2). Complex 4 was fully characterized, including X-ray analyses; this constitutes the first example of a diazo adduct compound with palladium, thereby closing the gap between Groups 8 and 10 regarding this type of compounds. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Growth and Electronic Structure Characterization of (SrCoOx)n :(SrTiO3)1 Superlattices

NASA Astrophysics Data System (ADS)

Cook, Say Young; Andersen, Tassie; Rosenberg, Richard; Hong, Hawoong; Marks, Laurence; Fong, Dillon

We report on the synthesis of a (SrCoOx)1 :(SrTiO3)1 superlattice by oxide molecular beam epitaxy and the characterization of its electronic structure by soft x-ray spectroscopy. X-ray photoelectron and absorption spectroscopy reveal that Ti remains octahedrally coordinated with a 4 + oxidation state, while the Co oxidation state is intermediate of 3 + and 4 +. Despite having the same half an oxygen vacancy per Co atom found in brownmillerite SrCoO2.5, which consists of alternating tetrahedral and octahedral layers of Co, the confinement of oxygen vacancies to isolated single atomic layers of SrCoOx stabilizes square pyramidal coordination of Co, as observed by the linear dichroism in the Co 2p-3d x-ray absorption. The corresponding stabilization of Co4+ along with Co3 + within the square pyramidal SrCoO2.5 layers gives rise to a Fermi-edge step observed at strong Co 2p-3d resonance in the resonant photoemission spectroscopy of the valence band, and reveals a band gap of 1.7 eV. Comparisons with a Sr(Co,Ti)Ox alloy and a (SrCoOx)2 :(SrTiO3)1 superlattice also will also be presented. The obtained results demonstrate artificial superlattices as effective means to defect engineer complex oxides by harnessing the confinement of oxygen vacancies to control the oxygen coordination environment of the transition metal.

Neutron scattering characterization of homopolymers and graft-copolymer micelles in supercritical carbon dioxide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chillura-Martino, D; Triolo, R.; McClain, J.B.

1995-12-31

Supercritical fluids are becoming an attractive alternative to the liquid solvents traditionally used as polymerization media. As the synthesis proceeds, a wide range of colloidal aggregates form, but there has hitherto been no way to measure such structures directly. We have applied small-angle neutron scattering (SANS) to characterize such systems, and although SCF polymerizations are carried out at high pressures, the penetrating power of the neutron beam means that typical cell windows are virtually transparent. Systems studied include molecules soluble in CO{sub 2} (e.g. polyfluoro-octyl acrylate or PFOA) and this polymer has previously been shown to exhibit a positive secondmore » virial coefficient (A{sub 2}). Other CO{sub 2}-soluble polymers include hexafluoro-polypropylene oxide (HFPPO), which appears to have a second virial coefficient which is close to zero (10{sup 4}A{sub 2} {approx_equal} 0 +{+-} 0.2 cm{sup 3} g{sup -2} mol). Polydimethylsiloxane (PDMS), is soluble on the molecular level only in the limit of dilute solution and seems to form aggregates as the concentration increases (c > 0.01 g cm{sup -3}). Other polymers (e.g. polystyrene) are insoluble in CO{sub 2}, though polymerizations may be accomplished via the use of PS-PFOA blockcopolymer stabilizers, which are also amenable to SANS characterization, and have been shown to form micelles in CO{sub 2}. Other amphiphilic surfactant molecules that form micelles include PFOA-polyethylene oxide (PFOA-PEO) graft copolymers, which swell as the CO{sub 2} medium is saturated with water. These systems have been characterized by SANS, by taking advantage of the different contrast options afforded by substituting D{sub 2}O for H{sub 2}O. This paper illustrates the utility of SANS to measure molecular dimensions, thermodynamic variables, molecular weights, micelle structures etc. in supercritical CO{sub 2}.« less

In-situ Characterization of Cu/CeO 2 Nanocatalysts during CO 2 Hydrogenation: Morphological Effects of Nanostructured Ceria on the Catalytic Activity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lin, Lili; Yao, Siyu; Liu, Zongyuan

Here, a combination of time-resolved X-ray diffraction (TR-XRD), ambient-pressure X-ray photoelectron spectroscopy (AP-XPS) and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) was used to carry out an in-situ characterization of Cu/CeO 2 nanocatalysts during the hydrogenation of CO 2. Morphological effects of the ceria supports on the catalytic performances were investigated by examining the behavior of copper/ceria-nanorods (NR) and nanospheres (NS). At atmospheric pressures, the hydrogenation of CO 2 on the copper-ceria catalysts produced mainly CO through the reverse-water gas shift reaction (RWGS) and a negligible amount of methanol. The Cu/CeO 2-NR catalyst displayed the higher activity, which demonstrates thatmore » the RWGS is a structure sensitive reaction. In-situ TR-XRD and AP-XPS characterization showed significant changes in the chemical state of the catalysts under reaction conditions with the copper being fully reduced and a partial Ce 4+ to Ce 3+ transformation occurring. A more effective CO 2 dissociative activation at high temperature and a preferential formation of active bidentate carbonate and formate intermediates over CeO 2(110) terminations are probably the main reasons for the better performance of the Cu/CeO 2-NR catalyst in the RWGS reaction.« less

In-situ Characterization of Cu/CeO 2 Nanocatalysts during CO 2 Hydrogenation: Morphological Effects of Nanostructured Ceria on the Catalytic Activity

DOE PAGES

Lin, Lili; Yao, Siyu; Liu, Zongyuan; ...

2018-05-28

Here, a combination of time-resolved X-ray diffraction (TR-XRD), ambient-pressure X-ray photoelectron spectroscopy (AP-XPS) and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) was used to carry out an in-situ characterization of Cu/CeO 2 nanocatalysts during the hydrogenation of CO 2. Morphological effects of the ceria supports on the catalytic performances were investigated by examining the behavior of copper/ceria-nanorods (NR) and nanospheres (NS). At atmospheric pressures, the hydrogenation of CO 2 on the copper-ceria catalysts produced mainly CO through the reverse-water gas shift reaction (RWGS) and a negligible amount of methanol. The Cu/CeO 2-NR catalyst displayed the higher activity, which demonstrates thatmore » the RWGS is a structure sensitive reaction. In-situ TR-XRD and AP-XPS characterization showed significant changes in the chemical state of the catalysts under reaction conditions with the copper being fully reduced and a partial Ce 4+ to Ce 3+ transformation occurring. A more effective CO 2 dissociative activation at high temperature and a preferential formation of active bidentate carbonate and formate intermediates over CeO 2(110) terminations are probably the main reasons for the better performance of the Cu/CeO 2-NR catalyst in the RWGS reaction.« less

Structural and Spectroscopic Characterization of 17- and 18-Electron Piano-Stool Complexes of Chromium. Thermochemical Analyses of Weak Cr–H Bonds

DOE Office of Scientific and Technical Information (OSTI.GOV)

van der Eide, Edwin F.; Helm, Monte L.; Walter, Eric D.

2013-02-04

The 17-electron radical CpCr(CO)2(IMe)• (IMe = 1,3-dimethylimidazol-2-ylidene) was synthesized by the reaction of IMe with [CpCr(CO)3]2, and characterized by single crystal X-ray diffraction and by EPR, IR and variable temperature 1H NMR spectroscopy. The metal-centered radical is monomeric under all conditions and exhibits Curie paramagnetic behavior in solution. An electrochemically reversible reduction to 18-electron CpCr(CO)2(IMe)- takes place at E½ = -1.89(1) V vs Cp2Fe+•/0 in MeCN, and was accomplished chemically with KC8 in THF. The salts K+(18-crown-6)[CpCr(CO)2(IMe)]- • ½THF and K+[CpCr(CO)2(IMe)]- • ¾THF were crystallographically characterized. Monomeric ion pairs are found in the former, whereas the latter has a polymericmore » structure due to a network of K∙∙∙O(CO) interactions. Protonation of K+(18-crown-6)[CpCr(CO)2(IMe)]- • ½THF gives the hydride CpCr(CO)2(IMe)H, which could not be isolated, but was characterized in solution; a pKa of 27.2(4) was determined in MeCN. A thermochemical analysis provides the Cr-H bond dissociation free energy (BDFE) for CpCr(CO)2(IMe)H in MeCN solution as 47.3(6) kcal mol-1. This value is exceptionally low for a transition metal hydride, and implies that the reaction 2 [Cr-H] → 2 [Cr•] + H2 is exergonic (ΔG = -9.0(8) kcal mol-1). This analysis explains the experimental observation that generated solutions of the hydride produce CpCr(CO)2(IMe)• (typically on the timescale of days). By contrast, CpCr(CO)2(PCy3)H has a higher Cr-H BDFE (52.9(4) kcal mol-1), is more stable with respect to H2 loss, and is isolable. We thank the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences for support. M.L.H. carried out the crystallographic studies and was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. The EPR studies were performed at the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the Department of Energy’s Office of Biological and Environmental Research located at PNNL. Pacific Northwest National Laboratory is a multiprogram national laboratory operated by Battelle for the U.S. Department of Energy.« less

Reactivity of cyclopentadienyl transition metal(ii) complexes with borate ligands: structural characterization of the toluene-activated molybdenum complex [Cp*Mo(CO)2(η3-CH2C6H5)].

PubMed

Ramalakshmi, Rongala; Maheswari, K; Sharmila, Dudekula; Paul, Anamika; Roisnel, Thierry; Halet, Jean-François; Ghosh, Sundargopal

2016-10-18

Reactions of cyclopentadienyl transition-metal halide complexes [Cp*Mo(CO) 3 Cl], 1, and [CpFe(CO) 2 I], 2, (Cp = C 5 H 5 ; Cp* = η 5 -C 5 Me 5 ) with borate ligands are reported. Treatment of 1 with [NaBt 2 ] (Bt 2 = dihydrobis(2-mercapto-benzothiazolyl)borate) in toluene yielded [Cp*Mo(CO) 2 (C 7 H 4 S 2 N)], 3, and [Cp*Mo(CO) 2 (η 3 -CH 2 C 6 H 5 )], 4, with a selective binding of toluene through C-H activation followed by orthometallation. Note that compound 4 is a structurally characterized toluene-activated molecule in which the metal is in η 3 -coordination mode. Under similar reaction conditions, [NaPy 2 ] (Py 2 = dihydrobis(2-mercaptopyridyl)borate) produced only the mercaptopyridyl molybdenum complex [Cp*Mo(CO) 2 (C 5 H 4 SN)], 5, in good yield. On the other hand, when compound 2 was treated individually with [NaBt] (Bt = trihydro(2-mercapto-benzothiazolyl)borate) and [NaPy 2 ] in THF, formation of the η 1 -coordinated complexes [CpFe(CO) 2 (C 7 H 4 S 2 N)], 6, and [CpFe(CO) 2 (C 5 H 4 SN)], 7, was observed. The solid-state molecular structures of compounds 3, 4, 6, and 7 have been established by single-crystal X-ray crystallographic analyses.

Unifying diffusion and seepage for nonlinear gas transport in multiscale porous media

NASA Astrophysics Data System (ADS)

Song, Hongqing; Wang, Yuhe; Wang, Jiulong; Li, Zhengyi

2016-09-01

We unify the diffusion and seepage process for nonlinear gas transport in multiscale porous media via a proposed new general transport equation. A coherent theoretical derivation indicates the wall-molecule and molecule-molecule collisions drive the Knudsen and collective diffusive fluxes, and constitute the system pressure across the porous media. A new terminology, nominal diffusion coefficient can summarize Knudsen and collective diffusion coefficients. Physical and numerical experiments show the support of the new formulation and provide approaches to obtain the diffusion coefficient and permeability simultaneously. This work has important implication for natural gas extraction and greenhouse gases sequestration in geological formations.

Geochemistry, faunal composition and trophic structure in reducing sediments on the southwest South Georgia margin

NASA Astrophysics Data System (ADS)

Bell, James B.; Aquilina, Alfred; Woulds, Clare; Glover, Adrian G.; Little, Crispin T. S.; Reid, William D. K.; Hepburn, Laura E.; Newton, Jason; Mills, Rachel A.

2016-09-01

Despite a number of studies in areas of focused methane seepage, the extent of transitional sediments of more diffuse methane seepage, and their influence upon biological communities is poorly understood. We investigated an area of reducing sediments with elevated levels of methane on the South Georgia margin around 250 m depth and report data from a series of geochemical and biological analyses. Here, the geochemical signatures were consistent with weak methane seepage and the role of sub-surface methane consumption was clearly very important, preventing gas emissions into bottom waters. As a result, the contribution of methane-derived carbon to the microbial and metazoan food webs was very limited, although sulfur isotopic signatures indicated a wider range of dietary contributions than was apparent from carbon isotope ratios. Macrofaunal assemblages had high dominance and were indicative of reducing sediments, with many taxa common to other similar environments and no seep-endemic fauna, indicating transitional assemblages. Also similar to other cold seep areas, there were samples of authigenic carbonate, but rather than occurring as pavements or sedimentary concretions, these carbonates were restricted to patches on the shells of Axinulus antarcticus (Bivalvia, Thyasiridae), which is suggestive of microbe-metazoan interactions.

Phytotoxicity and naphthenic acid dissipation from oil sands fine tailings treatments planted with the emergent macrophyte Phragmites australis.

PubMed

Armstrong, Sarah A; Headley, John V; Peru, Kerry M; Mikula, Randy J; Germida, James J

2010-01-01

During reclamation the water associated with the runoff or groundwater flushing from dry stackable tailings technologies may become available to the reclaimed environment within an oil sands lease. Here we evaluate the performance of the emergent macrophyte, common reed (Phragmites australis), grown in chemically amended mature fine tailings (MFT) and simulated runoff/seepage water from different MFT drying treatments. The present study also investigated the phytotoxicity of the concentration of oil sands naphthenic acids (NAs) in different MFT drying chemical treatments, in both planted and unplanted systems. We demonstrate that although growth was reduced, the emergent macrophyte common reed was capable of growing in diluted unamended MFT runoff, as well as in diluted runoff from MFT amended with either 0.25% lime and gypsum or 0.5% gypsum. Common reed can thus assist in the dewatering process of oil sands MFT. However, simulated runoff or seepage waters from chemically amended and dried MFT were phytotoxic, due to combined levels of salts, naphthenic acids and pH. Phytoremediation of runoff water/ground water seepage from dry-land applied MFT will thus require pre-treatment in order to make conditions more favorable for plant growth.

Geochemistry, faunal composition and trophic structure in reducing sediments on the southwest South Georgia margin

PubMed Central

Aquilina, Alfred; Woulds, Clare; Glover, Adrian G.; Little, Crispin T. S.; Hepburn, Laura E.; Newton, Jason; Mills, Rachel A.

2016-01-01

Despite a number of studies in areas of focused methane seepage, the extent of transitional sediments of more diffuse methane seepage, and their influence upon biological communities is poorly understood. We investigated an area of reducing sediments with elevated levels of methane on the South Georgia margin around 250 m depth and report data from a series of geochemical and biological analyses. Here, the geochemical signatures were consistent with weak methane seepage and the role of sub-surface methane consumption was clearly very important, preventing gas emissions into bottom waters. As a result, the contribution of methane-derived carbon to the microbial and metazoan food webs was very limited, although sulfur isotopic signatures indicated a wider range of dietary contributions than was apparent from carbon isotope ratios. Macrofaunal assemblages had high dominance and were indicative of reducing sediments, with many taxa common to other similar environments and no seep-endemic fauna, indicating transitional assemblages. Also similar to other cold seep areas, there were samples of authigenic carbonate, but rather than occurring as pavements or sedimentary concretions, these carbonates were restricted to patches on the shells of Axinulus antarcticus (Bivalvia, Thyasiridae), which is suggestive of microbe–metazoan interactions. PMID:27703692

Effects of seepage from fly-ash settling ponds and construction dewatering on ground-water levels in the Cowles unit, Indiana Dunes National Lakeshore, Indiana

USGS Publications Warehouse

Meyer, William R.; Tucci, Patrick

1979-01-01

Part of the Indiana Dunes National Lakeshore shares a common boundary with the Northern Indiana Public Service Company (NIPSCO). This area is underlain by unconsolidated deposits approximately 180 feet thick. NIPSCO accumulates fly ash from the burning of coal in electric-power generating units in settling ponds. Seepage from the ponds has raised ground-water levels above natural levels approximately 15 feet under the ponds and more than 10 feet within the Lakeshore. NIPSCO is presently (1977) constructing a nuclear powerplant, and construction activities include pumping ground water to dewater the construction site. The company has installed a slurry wall around the site to prevent lowering of ground-water levels within the Lakeshore. Plans call for continuous pumping through at least December 1979. A multilayered digital flow model was constructed to simulate the ground-water system. The model was used to demonstrate the effects of seepage from the fly-ash ponds on ground-water levels. Also, the model indicated a decline of 3 feet or less in the upper sand unit and 5 feet or less in the lower sand unit within the Lakeshore.

Radionuclide inventories for the F- and H-area seepage basin groundwater plumes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hiergesell, Robert A; Kubilius, Walter P.

2016-05-01

Within the General Separations Areas (GSA) at the Savannah River Site (SRS), significant inventories of radionuclides exist within two major groundwater contamination plumes that are emanating from the F- and H-Area seepage basins. These radionuclides are moving slowly with groundwater migration, albeit more slowly due to interaction with the soil and aquifer matrix material. The purpose of this investigation is to quantify the activity of radionuclides associated with the pore water component of the groundwater plumes. The scope of this effort included evaluation of all groundwater sample analyses obtained from the wells that have been established by the Environmental Compliancemore » & Area Completion Projects (EC&ACP) Department at SRS to monitor groundwater contamination emanating from the F- and H-Area Seepage Basins. Using this data, generalized groundwater plume maps for the radionuclides that occur in elevated concentrations (Am-241, Cm-243/244, Cs-137, I-129, Ni-63, Ra-226/228, Sr-90, Tc-99, U-233/234, U-235 and U-238) were generated and utilized to calculate both the volume of contaminated groundwater and the representative concentration of each radionuclide associated with different plume concentration zones.« less

Development of an SP simulation package for understanding fundamentals of self-potential responses at an earth dam

NASA Astrophysics Data System (ADS)

Kang, S.; Lim, S. K.; Oldenburg, D.

2016-12-01

Fluid flow in an underground porous medium pulls positive ions in the direction of flow and results in a streaming current. This movement of ions in the direction of flow creates a charge imbalance in the system which, in turn, causes conduction currents to flow in the opposite Although, the streaming current only flows in the saturated pores, the conduction currents will flow in the entire medium. The electrical potentials due to the fluid flow can be measured in the same manner as those in a direct current survey. This method is often called the self-potential (SP) method. A number of applications using the SP technique have been investigated including earthquake prediction, the vadose zone flow, locating sinkholes, mineral deposits and volcanic chambers. In this study, we particularly focus on the monitoring of seepage flow through earth dams. Earth dams are usually made of permeable materials and are designed to allow limited amounts of seepage flow from the reservoir. Due to seepage forces, the fine grains in the core can be washed out, and this internal erosion is one the most prevalent failure modes in earth dams. Therefore, identifying and monitoring the region of preferential seepage flow is a key for dam safety assessment. Usually, an earth dam is composed of fine-grained core and coarse-grained cover, which have different hydraulic conductivities. The distribution of hydraulic head, water saturation and fluid flow is found by solving hydrogeologic equations with applied boundary conditions. When a seepage path is induced due to internal erosion, the hydrological properties will be changed and this results in additional fluid flow. This is an additional source of SP signal. Understanding the impact of different sources of the SP signals is thus a crucial factor towards effective use of the SP technique for safety assessment at earth dams. Modelling SP signals requires two essential simulation capabilities: a) computing fluid flow in porous medium and b) solving steady-state Maxwell's equations. Since they are coupled having both systems in a single framework will be beneficial. This also allows the fundamentals of SP signals to be explored. By using an open-source modular framework, SimPEG, we develop an SP simulation package and demonstrate its effective use for understanding SP signals with an earth dam setup.

Study on of Seepage Flow Velocity in Sand Layer Profile as Affected by Water Depth and Slope Gradience

NASA Astrophysics Data System (ADS)

Han, Z.; Chen, X.

2017-12-01

BACKGROUND: The subsurface water flow velocity is of great significance in understanding the hydrodynamic characteristics of soil seepage and the influence of interaction between seepage flow and surface runoff on the soil erosion and sediment transport process. OBJECTIVE: To propose a visualized method and equipment for determining the seepage flow velocity and measuring the actual flow velocity and Darcy velocity as well as the relationship between them.METHOD: A transparent organic glass tank is used as the test soil tank, the white river sand is used as the seepage test material and the fluorescent dye is used as the indicator for tracing water flow, so as to determine the thickness and velocity of water flow in a visualized way. Water is supplied at the same flow rate (0.84 L h-1) to the three parts with an interval of 1m at the bottom of the soil tank and the pore water velocity and the thickness of each water layer are determined under four gradient conditions. The Darcy velocity of each layer is calculated according to the water supply flow and the discharge section area. The effective discharge flow pore is estimated according to the moisture content and porosity and then the relationship between Darcy velocity and the measured velocity is calculated based on the water supply flow and the water layer thickness, and finally the correctness of the calculation results is verified. RESULTS: According to the velocity calculation results, Darcy velocity increases significantly with the increase of gradient; in the sand layer profile, the flow velocity of pore water at different depths increases with the increase of gradient; under the condition of the same gradient, the lower sand layer has the maximum flow velocity of pore water. The air-filled porosity of sand layer determines the proportional relationship between Darcy velocity and pore flow velocity. CONCLUSIONS: The actual flow velocity and Darcy velocity can be measured by a visualized method and the relationship between Darcy velocity and pore velocity can be expressed well by the air-filled porosity of sand layer. The flow velocity measurement and test method adopted in the research is effective and feasible. IMPLICATIONS: The visualized flow velocity measurement method can be applied to simulate and measure the characteristics of subsurface water flow in the soil.

Quantitative and qualitative analysis of naphthenic acids in natural waters surrounding the Canadian oil sands industry.

PubMed

Ross, Matthew S; Pereira, Alberto dos Santos; Fennell, Jon; Davies, Martin; Johnson, James; Sliva, Lucie; Martin, Jonathan W

2012-12-04

The Canadian oil sands industry stores toxic oil sands process-affected water (OSPW) in large tailings ponds adjacent to the Athabasca River or its tributaries, raising concerns over potential seepage. Naphthenic acids (NAs; C(n)H(2n-Z)O(2)) are toxic components of OSPW, but are also natural components of bitumen and regional groundwaters, and may enter surface waters through anthropogenic or natural sources. This study used a selective high-resolution mass spectrometry method to examine total NA concentrations and NA profiles in OSPW (n = 2), Athabasca River pore water (n = 6, representing groundwater contributions) and surface waters (n = 58) from the Lower Athabasca Region. NA concentrations in surface water (< 2-80.8 μg/L) were 100-fold lower than previously estimated. Principal components analysis (PCA) distinguished sample types based on NA profile, and correlations to water quality variables identified two sources of NAs: natural fatty acids, and bitumen-derived NAs. Analysis of NA data with water quality variables highlighted two tributaries to the Athabasca River-Beaver River and McLean Creek-as possibly receiving OSPW seepage. This study is the first comprehensive analysis of NA profiles in surface waters of the region, and demonstrates the need for highly selective analytical methods for source identification and in monitoring for potential effects of development on ambient water quality.

Hydrologic data for the Big Spring basin, Clayton County, Iowa, water year 1988

USGS Publications Warehouse

Kalkhoff, Stephen J.

1989-01-01

During a baseflow seepage study, June 28 and 29, the discharge lost by streams in the basin was 5.57 cubic feet per second and the dissolved nitrogen load lost was 0.19 tons per day. The discharge and total dissolved nitrogen leaving the basin in streams was 2.93 cubic feet per second and 0.02 tons per day, respectively.

Chemical obtaining of LiMO2 and LiM2O4 (M=Co, Mn) oxides, for cathodic applications in Li-ion batteries

NASA Astrophysics Data System (ADS)

Y Neira-Guio, A.; Gómez Cuaspud, J. A.; López, E. Vera; Pineda Triana, Y.

2017-12-01

This paper describes the synthesis and characterization of two spinel and olivine-type multicomponent oxides based on LiMO2 and LiM2O4 systems (M=Co and Mn), which represent the current state of the art in the development of cathodes for Li-ion batteries. A simple combustion synthesis process was employed to obtain the nanometric oxides in powder form (crystal sizes around 5-8nm), with a number of improved surface characteristics. The characterization by X-Ray Diffraction (XRD), Scanning and Transmission Electron Microscopy (SEM, TEM) and X-Ray Fluorescence (XRF), allowed to evaluate the morphology and the stoichiometric compositions of solids, obtaining a concordant pure crystalline phase of LiCoO2 and LiMn2O4 oxides identified in a rhombohedral and cubic phase with punctual group R-3m (1 6 6) and Fm-3m (2 2 5) respectively. The electrical characterization of materials developed by impedance spectroscopy solid state, allowed to determine a p-type semiconducting behaviour with conductivity values of 6.2×10-3 and 2.7×10-7 S for LiCoO2 and LiMn2O4 systems, consistent with the state of the art for such materials.