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Sample records for charge exchange analysis

  1. Charge exchange system

    DOEpatents

    Anderson, Oscar A.

    1978-01-01

    An improved charge exchange system for substantially reducing pumping requirements of excess gas in a controlled thermonuclear reactor high energy neutral beam injector. The charge exchange system utilizes a jet-type blanket which acts simultaneously as the charge exchange medium and as a shield for reflecting excess gas.

  2. Charge exchange molecular ion source

    DOEpatents

    Vella, Michael C.

    2003-06-03

    Ions, particularly molecular ions with multiple dopant nucleons per ion, are produced by charge exchange. An ion source contains a minimum of two regions separated by a physical barrier and utilizes charge exchange to enhance production of a desired ion species. The essential elements are a plasma chamber for production of ions of a first species, a physical separator, and a charge transfer chamber where ions of the first species from the plasma chamber undergo charge exchange or transfer with the reactant atom or molecules to produce ions of a second species. Molecular ions may be produced which are useful for ion implantation.

  3. Charge Exchange with Highly Charged Ions

    NASA Astrophysics Data System (ADS)

    Glick, Jeremy; Ferri, Kevin; Schmitt, Jaclyn; Hanson, Joshua; Marler, Joan

    2016-05-01

    A detailed study of the physics of highly charged ions (HCIs) is critical for a deep understanding of observed phenomena resulting from interactions of HCIs with neutral atoms in astrophysical and fusion environments. Specifically the charge transfer rates and spectroscopy of the subsequent decay fluorescence are of great interest to these communities. Results from a laboratory based investigation of these rates will be presented. The experiment takes advantage of an energy and charge state selected beam of HCIs from the recently on-line Clemson University EBIT (CUEBIT). Progress towards an experimental apparatus for retrapping HCIs towards precision spectroscopy of HCIs will also be presented.

  4. Analysis of x-ray emission spectra in charge-exchange collisions of C6 + with He and H2

    NASA Astrophysics Data System (ADS)

    Leung, Anthony C. K.; Kirchner, Tom

    2016-05-01

    Charge exchange in C6 +-He and -H2 collisions followed by x-ray emission is examined using the two-center basis generator method for low to intermediate projectile energies. Within the independent electron model, we calculate capture cross sections and perform a radiative cascade analysis to obtain Lyman line-emission ratios. Single capture is considered for the C6 +-He system, while both single capture and autoionizing double capture are considered for the C6 +-H2 system. Effects of a time-dependent screening potential that models target response on the l distribution of capture cross sections and the line-emission ratios are examined as well. Calculated line-emission ratios based on the no-response approximation are in satisfactory agreement with previous measurements.

  5. Charge exchange in zinc-neon

    NASA Technical Reports Server (NTRS)

    Chubb, D. L.

    1975-01-01

    Excitation of the 4d and 5p levels of Zn+ by charge exchange bewteen Ne+ and Zn was investigated. From measured electron temperature and line intensity ratios it was concluded that charge exchange is the dominate mechanism for populating the 4d2D5/2 level of Zn+. Comparison of Zn-Ne and Zn-Ar results imply the same conclusion. No evidence for charge exchange as the dominant pumping mechanism for the 5p2Pl/2, 5p2P3/2, or 4d2D3/2 levels was obtained.

  6. Analysis of x-ray emission in charge-exchange collisions of C6+ ions with He and H2

    NASA Astrophysics Data System (ADS)

    Leung, Anthony C. K.; Kirchner, T.

    2016-05-01

    Charge exchange in C6+-He and - H2 collisions followed by x-ray emission is examined using the two-center basis generator method within the independent electron model. The analysis examines the two collision systems for low to intermediate projectile energies. We perform capture cross section and radiative cascade calculations to obtain Lyman line emission ratios which can be compared to measurements that were carried out at the Oak Ridge National Laboratory Multicharged Ion Research Facility. Single-electron capture is considered for the C6+-He system while both single and autoionizing double capture are considered for the C6+- H2 system. We also examine the effects of a time-dependent screening potential that models target response on the l distribution of the capture cross sections and the emission ratios. Calculated line emission ratios based on the no-response approximation are found to be in satisfactory agreement with the measurements. Work supported by SHARCNET, OGS, and NSERC, Canada

  7. Visible charge exchange recombination spectroscopy on TFTR

    SciTech Connect

    Stratton, B.C.; Fonck, R.J.; Jaehnig, K.P.; Schechtman, N.; Synakowski, E.J.

    1991-03-01

    Visible charge exchange recombination spectroscopy is routinely used to measure the time evolution of the ion temperature (T{sub i}) and toroidal rotation velocity (v{sub {phi}}) profiles on TFTR. These measurements are made with the CHERS diagnostic, a fiber-optically coupled spectrometer equipped with a two-dimensional photodiode array detector which provides both spectral and spatial resolution. The instrumentation, data analysis techniques, and examples of T{sub i} and v{sub {phi}} measurements are described. Recently, CHERS has been used to perform impurity transport experiments: radial profiles of diffusivities and convective velocities for helium and iron have been deduced from measurements of the time evolutions of He{sup 2+} and Fe{sup 24+} profiles following impurity injection. Examples of these measurements are given. 12 refs., 8 figs.

  8. Boltzmann-BCA Analysis on the Role of Charge Exchange in Microscopic Erosion of Fusion-Relevant Plasma Facing Components

    NASA Astrophysics Data System (ADS)

    Keniley, Shane; Curreli, Davide

    2016-10-01

    Charge-exchange is expected to play an important role in microscopic erosion of plasma facing components under fusion-relevant conditions. In this work we present a set of detailed Boltzmann simulations of the near-wall plasma including surface response, with the goal of highlighting the relative role of charge exchange against ion-induced erosion. The simulations reveal that the charge-exchange processes occurring in the collisional presheath release energetic neutrals toward the wall with angular distributions ranging from grazing to normal incidence; the ions accelerated across the collisional and magnetic presheath acts as a dominant factor in affecting the initial phase of the neutral population reaching the wall, and ultimately its energy-angle distribution at the surface. The effect on erosion rates, plasma sheath/presheath structure, and moments of the distributions are highlighted. The study has been made possible thanks to a newly-developed dynamically-coupled Boltzmann-BCA model retaining the effects of both the plasma and the material erosion. Material based on work supported by the U.S. Department of Energy, Office of Advanced Scientific Computing Research through the SciDAC project on Plasma-Surface Interactions, Award No. DE-SC0008875.

  9. Pion double charge exchange and hadron dynamics

    SciTech Connect

    Johnson, M.B.

    1991-01-01

    This paper will review theoretical results to show how pion double charge exchange is contributing to our understanding of hadron dynamics in nuclei. The exploitation of the nucleus as a filter is shown to be essential in facilitating the comparison between theory and experiment. 23 refs., 3 figs., 2 tabs.

  10. Charge exchange avalanche at the cometopause

    NASA Technical Reports Server (NTRS)

    Gombosi, Tamas I.

    1987-01-01

    A sharp transition from a solar wind proton dominated flow to a plasma population primarily consisting of relatively cold cometary heavy ions has been observed at a cometocentric distance of about 160,000 km by the VEGA and GIOTTO missions. This boundary (the cometopause) was thought to be related to charge transfer processes, but its location and thickness are inconsistent with conventionally estimated ion - neutral coupling boundaries. In this paper a two-fluid model is used to investigate the major physical processes at the cometopause. By adopting observed comet Halley parameters the model is able to reproduce the location and the thickness of this charge exchange boundary.

  11. Solar wind charge exchange during geomagnetic storms

    NASA Astrophysics Data System (ADS)

    Robertson, I. P.; Cravens, T. E.; Sibeck, D. G.; Collier, M. R.; Kuntz, K. D.

    2012-04-01

    On 2001 March 31 a coronal mass ejection pushed the subsolar magnetopause to the vicinity of geosynchronous orbit at 6.6 R_E. The NASA/GSFC Community Coordinated Modeling Center (CCMC) employed a global magnetohydrodynamic (MHD) model to simulate the solar wind-magnetosphere interaction during the peak of this geomagnetic storm. Robertson et al. then modeled the expected soft X-ray emission due to solar wind charge exchange with geocoronal neutrals in the dayside cusp and magnetosheath. The locations of the bow shock, magnetopause and cusps were clearly evident in their simulations. Another geomagnetic storm took place on 2000 July 14 (Bastille Day). We again modeled X-ray emission due to solar wind charge exchange, but this time as observed from a moving spacecraft. This paper discusses the impact of spacecraft location on observed X-ray emission and the degree to which the locations of the bow shock and magnetopause can be detected in images.

  12. Ring current proton decay by charge exchange

    NASA Technical Reports Server (NTRS)

    Smith, P. H.; Hoffman, R. A.; Fritz, T.

    1975-01-01

    Explorer 45 measurements during the recovery phase of a moderate magnetic storm have confirmed that the charge exchange decay mechanism can account for the decay of the storm-time proton ring current. Data from the moderate magnetic storm of 24 February 1972 was selected for study since a symmetrical ring current had developed and effects due to asymmetric ring current losses could be eliminated. It was found that after the initial rapid decay of the proton flux, the equatorially mirroring protons in the energy range 5 to 30 keV decayed throughout the L-value range of 3.5 to 5.0 at the charge exchange decay rate calculated by Liemohn. After several days of decay, the proton fluxes reached a lower limit where an apparent equilibrium was maintained, between weak particle source mechanisms and the loss mechanisms, until fresh protons were injected into the ring current region during substorms. While other proton loss mechanisms may also be operating, the results indicate that charge exchange can entirely account for the storm-time proton ring current decay, and that this mechanism must be considered in all studies involving the loss of proton ring current particles.

  13. New Charge Exchange Calculations for Lowly-Charged Ions

    NASA Astrophysics Data System (ADS)

    Stancil, P. C.

    2005-05-01

    The process of charge exchange, which occurs during the collision of an ion with a neutral species, is important in a variety of astrophysical and atmospheric environments. It can have an influence on the ionization and thermal balances of the plasma and may also contribute to the emission spectrum. The charge exchange of multiply-charged ions (q>2) usually proceeds at a fast rate with rate coefficients typically of 10-10 to 10-9 cm3s-1. Therefore, highly-charged ions, which are created in UV or x-ray ionized gas, quickly recombine to smaller charges. However, the rate coefficients for singly- and doubly-charged ions can vary over five orders of magnitude depending on the ion species, the neutral target, and the temperature. In particular, the rate coefficients depend sensitively on the dominant mechanism which may be due to radial, rotational, radiative, or spin-orbit coupling and the corresponding quasi-molecular curves can be very complicated. Measurements of such processes are complicated by metastable contamination and uncertainties in target purity and estimates of empirical values inferred from astrophysical modeling are typically suspect. Therefore, the state of knowledge of lowly-charged electron transfer processes is generally poor, but these reactions can be critical in determining the state of the plasma. If, for example, the rate coefficient for a q=2 ion is very small, the process would result in a bottle-neck in the recombination cascade from higer charges. In an effort to address these problems, quantum-mechanical calculations have been carried out for a number of singly- and doubly-charged ions and benchmarked to measurements when available. I will present a summary of these results which reveal significant differences from values adopted in rate coefficient compilations used by various modeling packages. This work was performed in collaboration with L. B. Zhao, C. Y. Lin, J. P. Gu, H. P. Liebermann, R. J. Buenker, and M. Kimura. Support from NASA

  14. Charge-exchange plasma environment for an ion drive spacecraft

    NASA Technical Reports Server (NTRS)

    Kaufman, H. R.; Carruth, M. R., Jr.

    1981-01-01

    A model was reviewed which describes the propagation of the mercury charge-exchange plasma and extended to describe the flow of the molybdenum component of the charge-exchange plasma. The uncertainties in the models for various conditions are discussed. Such topics as current drain to the solar array, charge-exchange plasma material deposition, and the effects of space plasma on the charge-exchange plasma propagation are addressed.

  15. Charge symmetry breaking two-pion exchange

    SciTech Connect

    Niskanen, J.A. )

    1992-06-01

    Two-pion exchange (TPE) contribution to the charge symmetry breaking class IV neutron-proton interaction is examined in a potential and coupled channels approach. Based on nonrelativistic {pi}{ital NN} and {pi}{ital N}{Delta} vertices, a TPE interaction is treated in two ways, as a potential or as a part calculable by the coupled channels method plus a residual potential interaction. A practical parametrization of the TPE potentials is given, which can also be used in the case of class III charge symmetry breaking (CSB) forces as well as for charge symmetric interactions. The results show that below 300 MeV the TPE contribution to CSB in elastic {ital np} scattering is insignificant, whereas at higher energies it should not be neglected.

  16. Charge exchange lifetimes for ions in the magnetosphere

    NASA Technical Reports Server (NTRS)

    Smith, P. H.; Bewtra, N. K.

    1977-01-01

    Latest and best measurements of physical quantities involved in complete calculation of the charge exchange lifetime of mirroring magnetospheric ions are coalesced and summarized. It is critical that the charge exchange lifetimes for ions be known as accurately as possible in order to apply the charge exchange mechanism to ion phenomena within the earth's magnetosphere.

  17. Pion Charge Exchange Cross Section on Liquid Argon

    NASA Astrophysics Data System (ADS)

    Nelson, Kevin; LArIAT (FNAL T-1034) Collaboration

    2017-01-01

    The observation of neutrino oscillations allows charge parity violation to be probed in the neutrino sector. Detectors with high calorimetric energy resolution and high spatial resolution will provide precise measurements of neutrino oscillations. By measuring small π+/- cross sections for individual interaction channels, specifically charge exchange, we will make a measurement in the first of its kind on liquid Argon and demonstrate the physics capabilities of a relatively new detector technology: the Liquid Argon Time Projection Chamber (LAr TPC). This analysis will report on the thin slab cross section measurement technique and the Monte Carlo cross section measurements in the energy range of 0.2 - 1.0 GeV. This analysis is the first iteration in classifying charge exchange events from a sample of incident pions, and it aims to identify events in which a π0 was produced without any charged pions leaving the interaction vertex. We will also report on the methodology and efficiency of this algorithm in identifying particles and their interactions in liquid argon. This analysis will inform a future measurement of the π+/- charge exchange cross section on liquid argon. This work was supported in part by the National Science Foundation under Grant No. PHY-1359364.

  18. Solar Wind Charge Exchange During Geomagnetic Storms

    NASA Technical Reports Server (NTRS)

    Robertson, Ina P.; Cravens, Thomas E.; Sibeck, David G.; Collier, Michael R.; Kuntz, K. D.

    2012-01-01

    On March 31st. 2001, a coronal mass ejection pushed the subsolar magnetopause to the vicinity of geosynchronous orbit at 6.6 RE. The NASA/GSFC Community Coordinated Modeling Center (CCMe) employed a global magnetohydrodynamic (MHD) model to simulate the solar wind-magnetosphere interaction during the peak of this geomagnetic storm. Robertson et aL then modeled the expected 50ft X-ray emission due to solar wind charge exchange with geocoronal neutrals in the dayside cusp and magnetosheath. The locations of the bow shock, magnetopause and cusps were clearly evident in their simulations. Another geomagnetic storm took place on July 14, 2000 (Bastille Day). We again modeled X-ray emission due to solar wind charge exchange, but this time as observed from a moving spacecraft. This paper discusses the impact of spacecraft location on observed X-ray emission and the degree to which the locations of the bow shock and magnetopause can be detected in images.

  19. Ring current proton decay by charge exchange

    NASA Technical Reports Server (NTRS)

    Smith, P. H.; Hoffman, R. A.; Fritz, T. A.

    1976-01-01

    Explorer 45 (S3-A) measurements were made during the recovery phase of the moderate magnetic storm of February 24, 1972, in which a symmetric ring current had developed and effects due to asymmetric ring current losses could be eliminated. It was found that after the initial rapid decay of the proton flux, which is a consequence of the dissipation of the asymmetric ring current, the equatorially mirroring protons in the energy range 5-30 keV decayed throughout the L value range of 3.5-5.0 at the charge exchange decay rate calculated by Liemohn (1961). After several days of decay, the proton fluxes reached a lower limit where an apparent equilibrium was maintained, between weak particle source mechanisms and the loss mechanisms, until fresh protons were injected into the ring current region during substorms. While other proton loss mechanisms may also be operating, the results indicate that charge exchange is more than sufficient as a particle loss mechanism for the storm time proton ring current decay.

  20. Compact, accurate description of diagnostic neutral beam propagation and attenuation in a high temperature plasma for charge exchange recombination spectroscopy analysis.

    PubMed

    Bespamyatnov, Igor O; Rowan, William L; Granetz, Robert S

    2008-10-01

    Charge exchange recombination spectroscopy on Alcator C-Mod relies on the use of the diagnostic neutral beam injector as a source of neutral particles which penetrate deep into the plasma. It employs the emission resulting from the interaction of the beam atoms with fully ionized impurity ions. To interpret the emission from a given point in the plasma as the density of emitting impurity ions, the density of beam atoms must be known. Here, an analysis of beam propagation is described which yields the beam density profile throughout the beam trajectory from the neutral beam injector to the core of the plasma. The analysis includes the effects of beam formation, attenuation in the neutral gas surrounding the plasma, and attenuation in the plasma. In the course of this work, a numerical simulation and an analytical approximation for beam divergence are developed. The description is made sufficiently compact to yield accurate results in a time consistent with between-shot analysis.

  1. Charge exchange in the Io torus and exosphere

    NASA Technical Reports Server (NTRS)

    Johnson, R. E.; Strobel, D. F.

    1982-01-01

    Charge-exchange cross sections and their velocity dependence have been estimated for the most important reactions in the Io torus and exosphere. The methods used for calculating the cross sections are given and discussed in some detail. For symmetric-resonant single and double charge exchange, the cross sections are slowly varying functions of velocity. For inelastic charge-exchange collisions, the transition probabilities into a given final state can depend critically on velocity. Models are described which can be used to estimate both the most rapid charge-exchange processes and those states which play an important role. Calculated cross sections are used to obtain reaction rates as a function of radial position, demonstrating the importance of charge exchange in the inner torus. Charge-exchange reactions of torus ions with molecular species in Io's exosphere may yield a net supply of neutrals and plasma to the torus.

  2. Dependence of the charge exchange lifetimes on mirror latitude

    NASA Technical Reports Server (NTRS)

    Smith, P. H.; Bewtra, N. K.

    1976-01-01

    The dependence of the charge exchange lifetimes on the mirror latitude for ions mirroring off the geomagnetic equator was re-computed using the improved hydrogen distribution models. The Chamberlain model was used to define the spatial distribution of the neutral hydrogen environment through which the ring current ions traverse. The resultant dependence of the charge exchange lifetime on mirror latitude is best fitted by the approximation that contains the charge exchange lifetime for equatorial particles.

  3. Suzaku Observations of Charge Exchange Emission from Solar System Objects

    NASA Technical Reports Server (NTRS)

    Ezoe, Y.; Fujimoto, R.; Yamasaki, N. Y.; Mitsuda, K.; Ohashi, T.; Ishikawa, K.; Oishi, S.; Miyoshi, Y; Terada, N.; Futaana, Y.; Porter, F. S.; Brown, G. V.

    2012-01-01

    Recent results of charge exchange emission from solar system objects observed with the Japanese Suzaku satellite are reviewed. Suzaku is of great importance to investigate diffuse X-ray emission like the charge exchange from planetary exospheres and comets. The Suzaku studies of Earth's exosphere, Martian exosphere, Jupiter's aurorae, and comets are overviewed.

  4. 76 FR 10498 - Exchange Visitor Program-Fees and Charges

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-02-25

    ... Part 62 RIN 1400-AC67 Exchange Visitor Program--Fees and Charges AGENCY: Department of State. ACTION: Final rule. SUMMARY: The Department of State is amending its regulations regarding fees and charges for Exchange Visitor Program services. The fees permit the Department to recoup the cost of providing...

  5. X-ray emission from charge exchange of highly-charged ions in atoms and molecules

    NASA Technical Reports Server (NTRS)

    Greenwood, J. B.; Williams, I. D.; Smith, S. J.; Chutjian, A.

    2000-01-01

    Charge exchange followed by radiative stabilization are the main processes responsible for the recent observations of X-ray emission from comets in their approach to the Sun. A new apparatus was constructed to measure, in collisions of HCIs with atoms and molecules, (a) absolute cross sections for single and multiple charge exchange, and (b) normalized X-ray emission cross sections.

  6. Charge-exchange plasma generated by an ion thruster

    NASA Technical Reports Server (NTRS)

    Kaufman, H. R.

    1977-01-01

    The charge exchange plasma generated by an ion thruster was investigated experimentally using both 5 cm and 15 cm thrusters. Results are shown for wide ranges of radial distance from the thruster and angle from the beam direction. Considerations of test environment, as well as distance from the thruster, indicate that a valid simulation of a thruster on a spacecraft was obtained. A calculation procedure and a sample calculation of charge exchange plasma density and saturation electron current density are included.

  7. Charge-exchange collisions of C 60z+ : a probe of the ion charge distribution

    NASA Astrophysics Data System (ADS)

    Cameron, Douglas B.; Parks, Joel H.

    1997-06-01

    We present Paul trap measurements of charge-exchange collisions of Li, Cs and C 60 with C 60z+ ions ( z = 1-3) at thermal energies. Surprisingly, the measured charge-exchange rates for each neutral species are not proportional to the ion charge z as would be expected for Langevin collisions involving a uniformly charged ion. The relative rates can be reproduced by a model based on a symmetric distribution of point charges that are free to move on the ion surface during the neutral trajectory. Such behavior can be attributed to static and possibly dynamic Jahn-Teller effects in C 60z+ ions.

  8. 78 FR 28137 - Exchange Visitor Program-Fees and Charges

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-05-14

    ... Part 62 RIN 1400-AD28 Exchange Visitor Program--Fees and Charges AGENCY: Department of State. ACTION... Application Fee for Sponsor Designation or Redesignation and the Administrative Fee for Exchange Visitor (J-1..., 2013 (RIN 1400-AD28; 78 FR 6263), with a request for comments, to amend 22 CFR 62.17 (``Fees...

  9. Ion momentum and energy transfer rates for charge exchange collisions

    NASA Technical Reports Server (NTRS)

    Horwitz, J.; Banks, P. M.

    1973-01-01

    The rates of momentum and energy transfer have been obtained for charge exchange collisions between ion and neutral gases having arbitrary Maxwellian temperatures and bulk transport velocities. The results are directly applicable to the F-region of the ionosphere where 0+ - 0 charge is the dominant mechanism affecting ion momentum and energy transfer.

  10. Impurity charge-exchange processes processes in Tokamak plasmas

    NASA Astrophysics Data System (ADS)

    Puiatti, M. E.; Breton, C.; Michelis, C.; Mattioll, M.

    1981-02-01

    Charge exchange reactions between multiply charged impurity ions and neutral hydrogen isotopes were considered. Ionization equilibrium and radiative losses were evaluated for oxygen and iron in the presence of either thermal or beam neutrals. The influence of thermal neutrals on recently reported results from chemically heated TFR discharges is also discussed.

  11. Charge exchange cooling in the tandem mirror plasma confinement apparatus

    DOEpatents

    Logan, B. Grant

    1978-01-01

    Method and apparatus for cooling a plasma of warm charged species confined in the center mirror cell of the tandem mirror apparatus by injecting cold neutral species of the plasma into at least one mirroring region of the center mirror cell, the cooling due to the loss of warm charged species through charge exchange with the cold neutral species with resulting diffusion of the warm neutral species out of the plasma.

  12. Characterization of an atomic hydrogen source for charge exchange experiments

    NASA Astrophysics Data System (ADS)

    Leutenegger, M. A.; Beiersdorfer, P.; Betancourt-Martinez, G. L.; Brown, G. V.; Hell, N.; Kelley, R. L.; Kilbourne, C. A.; Magee, E. W.; Porter, F. S.

    2016-11-01

    We characterized the dissociation fraction of a thermal dissociation atomic hydrogen source by injecting the mixed atomic and molecular output of the source into an electron beam ion trap containing highly charged ions and recording the x-ray spectrum generated by charge exchange using a high-resolution x-ray calorimeter spectrometer. We exploit the fact that the charge exchange state-selective capture cross sections are very different for atomic and molecular hydrogen incident on the same ions, enabling a clear spectroscopic diagnostic of the neutral species.

  13. Charge Exchange Spectra of Hydrogenic and He-like Iron

    SciTech Connect

    Wargelin, B J; Beiersdorfer, P; Neill, P A; Olson, R E; Scofield, J H

    2005-04-27

    We present H-like Fe XXVI and He-like Fe XXV charge-exchange spectra resulting from collisions of highly charged iron with N{sub 2} gas at an energy of {approx}10 eV amu{sup -1} in an electron beam ion trap. Although high-n emission lines are not resolved in our measurements, we observe that the most likely level for Fe{sup 25+} {yields} Fe{sup 24+} electron capture is n{sub max} {approx} 9, in line with expectations, while the most likely value for Fe{sup 26+} {yields} Fe{sup 25+} charge exchange is significantly higher. In the Fe XXV spectrum, the K{alpha} emission feature dominates, whether produced via charge exchange or collisional excitation. The K{alpha} energy centroid is lower in the former case than the latter (6666 versus 6685 eV, respectively), as expected because of the strong enhancement of emission from the forbidden and intercombination lines, relative to the resonance line, in charge-exchange spectra. In contrast, the Fe XXVI high-n Lyman lines have a summed intensity greater than that of Ly{alpha}, and are substantially stronger than predicted from theoretical calculations of charge exchange with atomic H. A discussion is presented of the relevance of our results to studies of diffuse Fe emission in the Galactic Center and Galactic Ridge, particularly with ASTRO-E2.

  14. Charge-exchange reactions with a radioactive triton beam

    SciTech Connect

    Jaenecke, J.

    1998-12-21

    A high-resolution (t, {sup 3}He) test experiment has been performed recently by making use of a secondary triton beam produced by fragmentation of {alpha}-particles. The purpose of this charge-exchange experiment was to achieve good energy resolution in an (n,p)-type reaction at intermediate bombarding energies. The experiment was carried out with the K1200 cyclotron at the National Superconducting Cyclotron Laboratory using the A1200 beam-analysis system and the S800 magnetic spectrometer. The beam-analysis system was used to transport the energy-dispersed radioactive triton beam from the production target to the target position, and the magnetic spectrometer was used to focus the dispersion-matched {sup 3}He particles from the (t, {sup 3}He) reaction at 0 degree sign onto the focal plane of the spectrometer. An energy resolution of 200-250 keV was achieved.

  15. Chemical exchange program analysis.

    SciTech Connect

    Waffelaert, Pascale

    2007-09-01

    As part of its EMS, Sandia performs an annual environmental aspects/impacts analysis. The purpose of this analysis is to identify the environmental aspects associated with Sandia's activities, products, and services and the potential environmental impacts associated with those aspects. Division and environmental programs established objectives and targets based on the environmental aspects associated with their operations. In 2007 the most significant aspect identified was Hazardous Materials (Use and Storage). The objective for Hazardous Materials (Use and Storage) was to improve chemical handling, storage, and on-site movement of hazardous materials. One of the targets supporting this objective was to develop an effective chemical exchange program, making a business case for it in FY07, and fully implementing a comprehensive chemical exchange program in FY08. A Chemical Exchange Program (CEP) team was formed to implement this target. The team consists of representatives from the Chemical Information System (CIS), Pollution Prevention (P2), the HWMF, Procurement and the Environmental Management System (EMS). The CEP Team performed benchmarking and conducted a life-cycle analysis of the current management of chemicals at SNL/NM and compared it to Chemical Exchange alternatives. Those alternatives are as follows: (1) Revive the 'Virtual' Chemical Exchange Program; (2) Re-implement a 'Physical' Chemical Exchange Program using a Chemical Information System; and (3) Transition to a Chemical Management Services System. The analysis and benchmarking study shows that the present management of chemicals at SNL/NM is significantly disjointed and a life-cycle or 'Cradle-to-Grave' approach to chemical management is needed. This approach must consider the purchasing and maintenance costs as well as the cost of ultimate disposal of the chemicals and materials. A chemical exchange is needed as a mechanism to re-apply chemicals on site. This will not only reduce the quantity of

  16. Charge exchange and energy loss of slow highly charged ions in 1 nm thick carbon nanomembranes.

    PubMed

    Wilhelm, Richard A; Gruber, Elisabeth; Ritter, Robert; Heller, René; Facsko, Stefan; Aumayr, Friedrich

    2014-04-18

    Experimental charge exchange and energy loss data for the transmission of slow highly charged Xe ions through ultrathin polymeric carbon membranes are presented. Surprisingly, two distinct exit charge state distributions accompanied by charge exchange dependent energy losses are observed. The energy loss for ions exhibiting large charge loss shows a quadratic dependency on the incident charge state indicating that equilibrium stopping force values do not apply in this case. Additional angle resolved transmission measurements point on a significant contribution of elastic energy loss. The observations show that regimes of different impact parameters can be separated and thus a particle's energy deposition in an ultrathin solid target may not be described in terms of an averaged energy loss per unit length.

  17. X-ray Line Formation by Charge Exchange

    NASA Astrophysics Data System (ADS)

    Beiersdorfer, Peter

    Existing X-ray telescopes have revealed charge exchange to be a key astrophysical process leading to X-ray emission when highly charged ions from such diverse sources as stellar winds, supernova remnants, or galactic super-winds interact with comets, planetary atmospheres, or the interstellar neutral gas. Charge exchange with bare sulfur ions, for example, was proposed as an alternative explanation of the 3.5 keV X-ray feature in the emission of galactic clusters that had been associated with the possible decay of sterile neutrinos. Fe XVII dominates the spectral emission of a large number of astrophysical X-ray sources and, thus, is of prime diagnostic importance, as illustrated in numerous measurements by Chandra and XMM-Newton. Although immense progress has been made in laboratory measurements and spectral calculations of collisional plasmas since the launch of these X-ray observatories, model calculations of the Fe XVII X-ray spectrum still do not yield agreement with astrophysical observations that is completely satisfactory. As a result, charge exchange has been invoked as an alternative explanation for the poor agreement between models and observations. Theoretically, line formation by charge exchange, however, is still only poorly understood both in the case of the rather 'simple'K-shell spectra of hydrogenlike or heliumlike ions, such as Fe XXV and Fe XXVI, and the more complex L-shell spectra of neonlike ions such as Fe XVII. Experimentally, there is only a small set of laboratory measurements involving X-rays from K-shell ions, and almost no measurements of the charge exchange produced X-ray emission involving L-shell ions. Moreover, the existing laboratory measurements have focused mostly on charge exchange processes pertaining to the solar wind interacting with complex (molecular) gases in cometary and planetary atmospheres. By contrast, we propose here to perform X-ray measurements pertaining to astrophysical exchange processes dominated by atomic

  18. Krypton charge exchange cross sections for Hall effect thruster models

    SciTech Connect

    Hause, Michael L.; Prince, Benjamin D.; Bemish, Raymond J.

    2013-04-28

    Following discharge from a Hall effect thruster, charge exchange occurs between ions and un-ionized propellant atoms. The low-energy cations produced can disturb operation of onboard instrumentation or the thruster itself. Charge-exchange cross sections for both singly and doubly charged propellant atoms are required to model these interactions. While xenon is the most common propellant currently used in Hall effect thrusters, other propellants are being considered, in particular, krypton. We present here guided-ion beam measurements and comparisons to semiclassical calculations for Kr{sup +} + Kr and Kr{sup 2+} + Kr cross sections. The measurements of symmetric Kr{sup +} + Kr charge exchange are in good agreement with both the calculations including spin-orbit effects and previous measurements. For the symmetric Kr{sup 2+} + Kr reaction, we present cross section measurements for center-of-mass energies between 1 eV and 300 eV, which spans energies not previously examined experimentally. These cross section measurements compare well with a simple one-electron transfer model. Finally, cross sections for the asymmetric Kr{sup 2+} + Kr {yields} Kr{sup +} + Kr{sup +} reaction show an onset near 12 eV, reaching cross sections near constant value of 1.6 A{sup 2} with an exception near 70-80 eV.

  19. A time-resolved study on the interaction of oppositely charged bicelles--implications on the charged lipid exchange kinetics.

    PubMed

    Yang, Po-Wei; Lin, Tsang-Lang; Hu, Yuan; Jeng, U-Ser

    2015-03-21

    Time-resolved small-angle X-ray scattering was applied to study charged lipid exchange between oppositely charged disc-shaped bicelles. The exchange of charged lipids gradually reduces the surface charge density and weakens the electrostatic attraction between the oppositely charged bicelles which form alternately stacked aggregates upon mixing. Initially, at a high surface charge density with almost no free water layer between the stacked bicelles, fast exchange kinetics dominate the exchange process. At a later stage with a lower surface charge density and a larger water gap between the stacked bicelles, slow exchange kinetics take over. The fast exchange kinetics are correlated with the close contact of the bicelles when there is almost no free water layer between the tightly bound bicelles with a charged lipid exchange time constant as short as 20-40 min. When the water gap becomes large enough to have a free water layer between the stacked bicelles, the fast lipid exchange kinetics are taken over by slow lipid exchange kinetics with time constants around 200-300 min, which are comparable to the typical time constant of lipid exchange between vesicles in aqueous solution. These two kinds of exchange mode fit well with the lipid exchange models of transient hemifusion for the fast mode and monomer exchange for the slow mode.

  20. Pion double charge exchange scattering above the delta resonance

    SciTech Connect

    Burleson, G.R.

    1989-01-01

    Data are presented on pion-nucleus double-charge-exchange scattering at energies between 300 and 500 MeV, the highest energies measured so far, together with a review of results at lower energies. The small-angle excitation functions disagree with predictions based on a sex-quark cluster model and on an optical model consistent with single-charge-exchange scattering at these energies, but they are consistent with a distorted-wave calculation. Data on f{sub 7/2}-shell nuclei are in partial agreement with a two-amplitude model which is successful at lower energies. In order to achieve good understanding of this process at these energies, more work; both experimental and theoretical, is needed. 16 refs., 6 figs.

  1. Significant enhancement of the charging efficiency in the cavities of ferroelectrets through gas exchange during charging

    NASA Astrophysics Data System (ADS)

    Qiu, Xunlin

    2016-11-01

    Ferroelectrets are non-polar polymer foams or polymer systems with internally charged cavities. They are charged through a series of dielectric barrier discharges (DBDs) that are caused by the electrical breakdown of the gas inside the cavities. Thus, the breakdown strength of the gas strongly influences the charging process of ferroelectrets. A gas with a lower breakdown strength has a lower threshold voltage, thus decreasing the onset voltage for DBD charging. However, a lower threshold voltage also leads to a lower value for the remanent polarization, as back discharges that are caused by the electric field of the internally deposited charges can take place already at lower charge levels. On this basis, a charging strategy is proposed where the DBDs start in a gas with a lower breakdown strength (in the present example, helium) and are completed at a higher breakdown strength (e.g., nitrogen or atmospheric air). Thus, the exchange of the gas in the cavities during charging can significantly enhance the charging efficiency, i.e., yield much higher piezoelectric coefficients in ferroelectrets at significantly lower charging voltages.

  2. PLASIM: A computer code for simulating charge exchange plasma propagation

    NASA Technical Reports Server (NTRS)

    Robinson, R. S.; Deininger, W. D.; Winder, D. R.; Kaufman, H. R.

    1982-01-01

    The propagation of the charge exchange plasma for an electrostatic ion thruster is crucial in determining the interaction of that plasma with the associated spacecraft. A model that describes this plasma and its propagation is described, together with a computer code based on this model. The structure and calling sequence of the code, named PLASIM, is described. An explanation of the program's input and output is included, together with samples of both. The code is written in ANSI Standard FORTRAN.

  3. Momentum transfer in relativistic heavy ion charge-exchange reactions

    NASA Technical Reports Server (NTRS)

    Townsend, L. W.; Wilson, J. W.; Khan, F.; Khandelwal, G. S.

    1991-01-01

    Relativistic heavy ion charge-exchange reactions yield fragments (Delta-Z = + 1) whose longitudinal momentum distributions are downshifted by larger values than those associated with the remaining fragments (Delta-Z = 1, -2,...). Kinematics alone cannot account for the observed downshifts; therefore, an additional contribution from collision dynamics must be included. In this work, an optical model description of collision momentum transfer is used to estimate the additional dynamical momentum downshift. Good agreement between theoretical estimates and experimental data is obtained.

  4. Systematics of heavy-ion charge-exchange straggling

    NASA Astrophysics Data System (ADS)

    Sigmund, P.; Schinner, A.

    2016-10-01

    The dependence of heavy-ion charge-exchange straggling on the beam energy has been studied theoretically for several ion-target combinations. Our previous work addressed ions up to krypton, while the present study focuses on heavier ions, especially uranium. Particular attention has been paid to a multiple-peak structure which has been predicted theoretically in our previous work. For high-Z1 and high-Z2 systems, exemplified by U in Au, we identify three maxima in the energy dependence of charge-exchange straggling, while the overall magnitude is comparable with that of collisional straggling. Conversely, for U in C, charge-exchange straggling dominates, but only two peaks lie in the energy range where we presently are able to produce credible predictions. For U-Al we find good agreement with experiment in the energy range around the high-energy maximum. The position of the high-energy peak - which is related to processes in the projectile K shell - is found to scale as Z12 , in contrast to the semi-empirical Z13/2 dependence proposed by Yang et al. Measurements for heavy ions in heavy targets are suggested in order to reconcile a major discrepancy between the present calculations and the frequently-used formula by Yang et al.

  5. Charge-exchange plasma generated by an ion thruster

    NASA Technical Reports Server (NTRS)

    Kaufman, H. R.

    1975-01-01

    The use of high voltage solar arrays greatly reduces or eliminates power processing requirements in space electric propulsion systems. This use also requires substantial areas of solar array to be at high positive potential relative to space and most of the spacecraft. The charge exchange plasma conducts electrons from the ion beam to such positive surfaces, and thereby electrically load the high voltage solar array. To evaluate this problem, the charge-exchange plasma generated by an ion beam was investigated experimentally. Based upon the experimental data, a simple model was derived for the charge-exchange plasma. This model is conservative in the sense that both the electron/ion density and the electron current density should be equal to, or less than, the preducted value for all directions in the hemisphere upstream of the ion beam direction. Increasing the distance between a positive potential surface (such as a high voltage solar array) and the thruster is the simplest way to control interactions. Both densities and currents vary as the inverse square of this distance.

  6. Charge Exchange Reaction in Dopant-Assisted Atmospheric Pressure Chemical Ionization and Atmospheric Pressure Photoionization.

    PubMed

    Vaikkinen, Anu; Kauppila, Tiina J; Kostiainen, Risto

    2016-08-01

    The efficiencies of charge exchange reaction in dopant-assisted atmospheric pressure chemical ionization (DA-APCI) and dopant-assisted atmospheric pressure photoionization (DA-APPI) mass spectrometry (MS) were compared by flow injection analysis. Fourteen individual compounds and a commercial mixture of 16 polycyclic aromatic hydrocarbons were chosen as model analytes to cover a wide range of polarities, gas-phase ionization energies, and proton affinities. Chlorobenzene was used as the dopant, and methanol/water (80/20) as the solvent. In both techniques, analytes formed the same ions (radical cations, protonated molecules, and/or fragments). However, in DA-APCI, the relative efficiency of charge exchange versus proton transfer was lower than in DA-APPI. This is suggested to be because in DA-APCI both dopant and solvent clusters can be ionized, and the formed reagent ions can react with the analytes via competing charge exchange and proton transfer reactions. In DA-APPI, on the other hand, the main reagents are dopant-derived radical cations, which favor ionization of analytes via charge exchange. The efficiency of charge exchange in both DA-APPI and DA-APCI was shown to depend heavily on the solvent flow rate, with best efficiency seen at lowest flow rates studied (0.05 and 0.1 mL/min). Both DA-APCI and DA-APPI showed the radical cation of chlorobenzene at 0.05-0.1 mL/min flow rate, but at increasing flow rate, the abundance of chlorobenzene M(+.) decreased and reagent ion populations deriving from different gas-phase chemistry were recorded. The formation of these reagent ions explains the decreasing ionization efficiency and the differences in charge exchange between the techniques. Graphical Abstract ᅟ.

  7. Charge Exchange Reaction in Dopant-Assisted Atmospheric Pressure Chemical Ionization and Atmospheric Pressure Photoionization

    NASA Astrophysics Data System (ADS)

    Vaikkinen, Anu; Kauppila, Tiina J.; Kostiainen, Risto

    2016-08-01

    The efficiencies of charge exchange reaction in dopant-assisted atmospheric pressure chemical ionization (DA-APCI) and dopant-assisted atmospheric pressure photoionization (DA-APPI) mass spectrometry (MS) were compared by flow injection analysis. Fourteen individual compounds and a commercial mixture of 16 polycyclic aromatic hydrocarbons were chosen as model analytes to cover a wide range of polarities, gas-phase ionization energies, and proton affinities. Chlorobenzene was used as the dopant, and methanol/water (80/20) as the solvent. In both techniques, analytes formed the same ions (radical cations, protonated molecules, and/or fragments). However, in DA-APCI, the relative efficiency of charge exchange versus proton transfer was lower than in DA-APPI. This is suggested to be because in DA-APCI both dopant and solvent clusters can be ionized, and the formed reagent ions can react with the analytes via competing charge exchange and proton transfer reactions. In DA-APPI, on the other hand, the main reagents are dopant-derived radical cations, which favor ionization of analytes via charge exchange. The efficiency of charge exchange in both DA-APPI and DA-APCI was shown to depend heavily on the solvent flow rate, with best efficiency seen at lowest flow rates studied (0.05 and 0.1 mL/min). Both DA-APCI and DA-APPI showed the radical cation of chlorobenzene at 0.05-0.1 mL/min flow rate, but at increasing flow rate, the abundance of chlorobenzene M+. decreased and reagent ion populations deriving from different gas-phase chemistry were recorded. The formation of these reagent ions explains the decreasing ionization efficiency and the differences in charge exchange between the techniques.

  8. Charge-Exchange Processes of Titanium-Doped Aluminate Crystals

    NASA Astrophysics Data System (ADS)

    Wong, Wing Cheong

    1995-01-01

    Titanium exists in more than one charge state in the aluminate crystals: it is stable as Ti^ {3+} and Ti^{4+}. Other than the intense Ti^{4+ } absorption, a ubiquitous absorption/luminescence excitation band in the UV region is identified as a titanium -bound exciton in Al_2rm O_3, Y_3Al_5rm O_{12}, {rm YAlO}_3, MgAl_2O _4, and LaMgAl_{11} {rm O}_{19}. One -step and two-step photoconductivities of Ti^ {3+} are measured and compared. While the selectivity of the two-step process is demonstrated, its use in locating the energy threshold is hampered by the small Franck-Condon factor for the transition between the Ti^{3+} ^2{ rm E} excited state and Ti^ {4+}. The titanium-bound exciton band, together with the one-step photocurrent signal, makes it possible to determine the photoionization energy threshold accurately. The charge-transfer transition energy thresholds of Ti^{4+} are obtained from the emission and the luminescence excitation spectra. Locally and non-locally charge compensated Ti^{4+ } are found in Al_2{rm O}_3. The luminescence kinetics for the two kinds of Ti^{4+} are well explained by a three-level system with a lower triplet excited state and a higher singlet excited state. These charge-exchange threshold energies can be deduced from the Born-Haber thermodynamical cycle. The electrostatic site potentials are calculated and from it, the calculated photoionization and charge-transfer energy thresholds are found to be consistent with the experimental results. The deficiency of this model is pointed out and possible improvement is discussed. Quantitatively, the sum of the two charge-exchange energy thresholds is close to the band-gap energy of the host crystal. This offers a convenient way for material characterization. Provided that any two of the three quantities (band-gap energy, photoionization energy threshold, and charge-transfer transition energy threshold) have been found, the third quantity can be calculated. In addition, the trapping of charge

  9. Population inversion calculations using near resonant charge exchange as a pumping mechanism

    NASA Technical Reports Server (NTRS)

    Chubb, D. L.; Rose, J. R.

    1972-01-01

    Near resonance charge exchange between ions of a large ionization potential gas such as helium or neon and vapors of metals such as zinc, cadmium, selenium, or tellurium has produced laser action in the metal ion gas. The possibility of obtaining population inversions in near resonant charge exchange systems (Xe-Ca, Xe-Mg, Xe-Sr, Xe-Ba, Ar-Mg, N-Ca) was investigated. The analysis is an initial value problem that utilizes rate equations for the densities of relevant levels of the laser gas (Ca, Ba, Mg, or Sr) and an electron energy equation. Electron excitation rates are calculated using the Bohr-Thomson approximation for the cross section. Approximations to experimental values of the electron ionization cross section and the ion-atom charge exchange cross section are used. Preliminary results have been obtained for the Ca-Xe system and show that it is possible to obtain gains greater than 10 to the 14th power/m with inversion times up to 8x10 to the minus 7th power second. A possible charge exchange laser system using a MPD arc plasma accelerator is also described.

  10. Anion exchangers with negatively charged functionalities in hyperbranched ion-exchange layers for ion chromatography.

    PubMed

    Uzhel, Anna S; Zatirakha, Alexandra V; Smirnov, Konstantin N; Smolenkov, Alexandr D; Shpigun, Oleg A

    2017-01-27

    Novel pellicular poly(styrene-divinylbenzene)-based (PS-DVB) anion exchangers with covalently-bonded hyperbranched functional ion-exchange layers containing negatively charged functionalities are obtained and examined. The hyperbranched coating is created on the surface of aminated PS-DVB substrate by repeating the modification cycles including alkylation with 1,4-butanediol diglycidyl ether (1,4-BDDGE), and amination of the terminal epoxide rings with methylamine (MA) or glycine (Gly). The influence of the position and the number of the layers with glycine, as well as of the total number of the layers of amine in the coating on the chromatographic properties of the obtained stationary phases is investigated. Chromatographic performance of the obtained stationary phases is evaluated using the model mixtures of inorganic and organic anions with hydroxide eluent. It is shown that the best selectivity toward weakly retained organic acids and oxyhalides is possessed by the anion exchanger obtained after 5 modification cycles, with glycine being used in the first one. Such anion exchanger packed in 25-cm long column is capable of separating 22 anions in 58min including 7 standard anions, mono-, di- and trivalent organic acids, oxyhalides, and some other double- and triple-charged anions.

  11. Charge exchange in slow collisions of Si3+ with H

    NASA Astrophysics Data System (ADS)

    Joseph, D. C.; Saha, B. C.

    2010-10-01

    Low energy electron capture from atomic hydrogen by multi-charged ions continues to be of interest and has wide applications including both magnetically confined^ fusion and astrophysical plasmas. The charge exchange process reported here, Si^3+ + H -- Si^2+ + H^+ is an important destruction mechanism of Si^3+ in photo-ionized gas. The soft X-ray emission from comets has been explained by charge transfer of solar wind ions, among them Si^3+, with neutrals in the cometary gas vapor. The state selective cross sections are evaluated using the semi-classical molecular orbital close coupling (MOCC) [1] methods. Adiabatic potentials and wave functions for a number of low-lying singlet and triplet states are calculated using the MRD-CI package [2]. Details will be presented at the conference. [1] M. Kimura and N. F. Lane, At. Mol. Opt. Phys 26, 79 (1990). [3] R. J. Buenker, ``Current Aspects of Quantum Chemistry'' 1981, Vol 21, edited by R. Carbo (Elsevier, Amsterdam) p 17.

  12. 78 FR 6263 - Exchange Visitor Program-Fees and Charges

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-01-30

    .... This analysis was grounded on the guiding principle that fees should be fair and reflect the full cost... ``activity-based costing'' (ABC) approach to develop a sustainable model to align the associated costs of the.... According to legislative and regulatory guidance, user charges should be based on the full cost to...

  13. Pionic charge exchange on the proton from 40 to 250 MeV

    NASA Astrophysics Data System (ADS)

    Breitschopf, J.; Bauer, M.; Clement, H.; Cröni, M.; Denz, H.; Friedman, E.; Gibson, E. F.; Meier, R.; Wagner, G. J.

    2006-08-01

    The total cross sections for pionic charge exchange on hydrogen were measured using a transmission technique on thin CH2 and C targets. Data were taken for π- lab energies from 39 to 247 MeV with total errors of typically 2% over the Δ-resonance and up to 10% at the lowest energies. Deviations from the predictions of the SAID phase shift analysis in the 60-80 MeV region are interpreted as evidence for isospin-symmetry breaking in the s-wave amplitudes. The charge dependence of the Δ-resonance properties appears to be smaller than previously reported.

  14. Improved edge charge exchange recombination spectroscopy in DIII-D

    DOE PAGES

    Chrystal, Colin; Burrell, K. H.; Grierson, Brian A.; ...

    2016-08-02

    The charge exchange recombination spectroscopy diagnostic on the DIII-D tokamak has been upgraded with the addition of more high radial resolution view chords near the edge of the plasma (r/a > 0.8). The additional views are diagnosed with the same number of spectrometers by placing fiber optics side-by-side at the spectrometer entrance with a precise separation that avoids wavelength shifted crosstalk without the use of bandpass filters. The new views improve measurement of edge impurity parameters in steep gradient, H-mode plasmas with many different shapes. The number of edge view chords with 8 mm radial separation has increased from 16more » to 38.As a result, new fused silica fibers have improved light throughput and clarify the observation of non-Gaussian spectra that suggest the ion distribution function can be non-Maxwellian in low collisionality plasmas.« less

  15. Improved edge charge exchange recombination spectroscopy in DIII-D

    SciTech Connect

    Chrystal, Colin; Burrell, K. H.; Grierson, Brian A.; Haskey, Shaun R.; Groebner, R. J.; Kaplan, David H.; Briesemeister, Alexis R.

    2016-08-02

    The charge exchange recombination spectroscopy diagnostic on the DIII-D tokamak has been upgraded with the addition of more high radial resolution view chords near the edge of the plasma (r/a > 0.8). The additional views are diagnosed with the same number of spectrometers by placing fiber optics side-by-side at the spectrometer entrance with a precise separation that avoids wavelength shifted crosstalk without the use of bandpass filters. The new views improve measurement of edge impurity parameters in steep gradient, H-mode plasmas with many different shapes. The number of edge view chords with 8 mm radial separation has increased from 16 to 38.As a result, new fused silica fibers have improved light throughput and clarify the observation of non-Gaussian spectra that suggest the ion distribution function can be non-Maxwellian in low collisionality plasmas.

  16. Improved edge charge exchange recombination spectroscopy in DIII-D

    NASA Astrophysics Data System (ADS)

    Chrystal, C.; Burrell, K. H.; Grierson, B. A.; Haskey, S. R.; Groebner, R. J.; Kaplan, D. H.; Briesemeister, A.

    2016-11-01

    The charge exchange recombination spectroscopy diagnostic on the DIII-D tokamak has been upgraded with the addition of more high radial resolution view chords near the edge of the plasma (r/a > 0.8). The additional views are diagnosed with the same number of spectrometers by placing fiber optics side-by-side at the spectrometer entrance with a precise separation that avoids wavelength shifted crosstalk without the use of bandpass filters. The new views improve measurement of edge impurity parameters in steep gradient, H-mode plasmas with many different shapes. The number of edge view chords with 8 mm radial separation has increased from 16 to 38. New fused silica fibers have improved light throughput and clarify the observation of non-Gaussian spectra that suggest the ion distribution function can be non-Maxwellian in low collisionality plasmas.

  17. Cometary X-Rays: Line Emission Cross Sections for Multiply Charged Solar Wind Ion Charge Exchange

    SciTech Connect

    Otranto, S; Olson, R E; Beiersdorfer, P

    2006-12-22

    Absolute line emission cross sections are presented for 1 keV/amu charge exchange collisions of multiply charged solar wind ions with H{sub 2}O, H, O, CO{sub 2}, and CO cometary targets. The present calculations are contrasted with available laboratory data. A parameter-free model is used to successfully predict the recently observed x-ray spectra of comet C/LINEAR 1999 S4. We show that the resulting spectrum is extremely sensitive to the time variations of the solar wind composition. Our results suggest that orbiting x-ray satellites may be a viable way to predict the solar wind intensities and composition on the Earth many hours before the ions reach the earth.

  18. Two-pion exchange contributions to nuclear charge asymmetry

    SciTech Connect

    Coon, S.A.; Niskanen, J.A.

    1995-04-01

    An explicit 2{pi} exchange (TPE) potential based on non-relativistic {pi}NN and {pi}{Delta}N vertices with the baryon mass differences taken into account in the vertices is extended to the study of mirror nuclear systems. For the latter study, one must also include baryon mass differences in the intermediate state energy denominators. The TPE potential includes box and crossed box diagrams with two nucleons and those with one nucleon and one {Delta}. Nuclear charge asymmetry is characterized, in part, by a positive value for the difference {Delta}a = {vert_bar}a{sub nn}{vert_bar} {minus} {vert_bar}a{sub pp}{vert_bar} {approx} O(1 fm) and a positive value for the {sup 3}H - {sup 3}He binding energy difference {Delta}E {approx} O(100 keV). The charge asymmetry from baryon mass differences in the vertices is small on this scale and in the wrong direction compared to the empirical values. The contribution from baryon mass differences in the intermediate state energy denominators is positive and is of the order of the empirical scales, in contrast to the previous estimate of {Delta}a {approx} +0.3 fm obtained from an SU(2) symmetric covariant field theoretical potential. This discrepancy between models of TPE is being investigated.

  19. Numerical calculation of charge exchange cross sections for plasma diagnostics

    NASA Astrophysics Data System (ADS)

    Mendez, Luis

    2016-09-01

    The diagnostics of impurity density and temperature in the plasma core in tokamak plasmas is carried out by applying the charge exchange recombination spectroscopy (CXRS) technique, where a fast beam of H atoms collides with the plasma particles leading to electron capture reactions with the impurity ions. The diagnostics is based on the emission of the excited ions formed in the electron capture. The application of the CXRS requires the knowledge of accurate state-selective cross sections, which in general are not accessible experimentally, and the calculation of cross sections for the high n capture levels, required for the diagnostics in the intermediate energy domain of the probe beam, is particularly difficult. In this work, we present a lattice numerical method to solve the time dependent Schrödinger equation. The method is based on the GridTDSE package, it is applicable in the wide energy range 1 - 500 keV/u and can be used to assess the accuracy of previous calculations. The application of the method will be illustrated with calculations for collisions of multiply charged ions with H. Work partially supported by project ENE2014-52432-R (Secretaria de Estado de I+D+i, Spain).

  20. High-throughput charge exchange recombination spectroscopy system on MAST

    SciTech Connect

    Conway, N. J.; Carolan, P. G.; McCone, J.; Walsh, M. J.; Wisse, M.

    2006-10-15

    A major upgrade to the charge exchange recombination spectroscopy system on MAST has recently been implemented. The new system consists of a high-throughput spectrometer coupled to a total of 224 spatial channels, including toroidal and poloidal views of both neutral heating beams on MAST. Radial resolution is {approx}1 cm, comparable to the ion Larmor radius. The toroidal views are configured with 64 channels per beam, while the poloidal views have 32 channels per beam. Background channels for both poloidal and toroidal views are also provided. A large transmission grating is at the heart of the new spectrometer, with high quality single lens reflex lenses providing excellent imaging performance and permitting the full exploitation of the available etendue of the camera sensor. The charge-coupled device camera chosen has four-tap readout at a maximum aggregate speed of 8.8 MHz, and it is capable of reading out the full set of 224 channels in less than 4 ms. The system normally operates at 529 nm, viewing the C{sup 5+} emission line, but can operate at any wavelength in the range of 400-700 nm. Results from operating the system on MAST are shown, including impurity ion temperature and velocity profiles. The system's excellent spatial resolution is ideal for the study of transport barrier phenomena on MAST, an activity which has already been advanced significantly by data from the new diagnostic.

  1. ROSAT Observations of Solar Wind Charge Exchange with the Lunar Exosphere

    NASA Technical Reports Server (NTRS)

    Collier, Michael R.; Snowden, S. L.; Benna, M.; Carter, J. A.; Cravens, T. E.; Hills, H. Kent; Hodges, R. R.; Kuntz, K. D.; Porter, F. Scott; Read, A.; Robertson, I. P.; Sembay, S. F.; Sibeck, D. G.; Stubbs, Timothy J.; Travnicek, P.

    2012-01-01

    We analyze the ROSAT PSPC soft X-ray image of the Moon taken on 29 June 1990 by examining the radial profile of the count rate in three wedges, two wedges (one north and one south) 13-32 degrees off (19 degrees wide) the terminator towards the dark side and one wedge 38 degrees wide centered on the anti-solar direction. The radial profiles of both the north and the south wedges show substantial limb brightening that is absent in the 38 degree wide antisolar wedge. An analysis of the count rate increase associated with the limb brightening shows that its magnitude is consistent with that expected due to solar wind charge exchange (SWCX) with the tenuous lunar atmosphere. Along with Mars, Venus, and Earth, the Moon represents another solar system body at which solar wind charge exchange has been observed. This technique can be used to explore the solar wind-lunar interaction.

  2. Charge-exchange reaction by Reggeon exchange and W{sup +}W{sup −}-fusion

    SciTech Connect

    Schicker, R.

    2015-04-10

    Charge-exchange reactions at high energies are examined. The existing cross section data on the Reggeon induced reaction pp → n + Δ{sup ++} taken at the ZGS and ISR accelerators are extrapolated to the energies of the RHIC and LHC colliders. The interest in the charge-exchange reaction induced by W{sup ±}-fusion is presented, and the corresponding QCD-background is examined.

  3. USING KAPPA FUNCTIONS TO CHARACTERIZE OUTER HELIOSPHERE PROTON DISTRIBUTIONS IN THE PRESENCE OF CHARGE-EXCHANGE

    SciTech Connect

    Zirnstein, E. J.; McComas, D. J. E-mail: dmccomas@swri.edu

    2015-12-10

    Kappa functions have long been used in the analysis and modeling of suprathermal particles in various space plasmas. In situ observations of the supersonic solar wind show its distribution contains a cold ion core and power-law tail, which is well-represented by a kappa function. In situ plasma observations by Voyager, as well as observations of energetic neutral atom (ENA) spectra by the Interstellar Boundary Explorer (IBEX), showed that the compressed and heated inner heliosheath (IHS) plasma beyond the termination shock can also be represented by a kappa function. IBEX exposes the IHS plasma properties through the detection of ENAs generated by charge-exchange in the IHS. However, charge-exchange modifies the plasma as it flows through the IHS, and makes it difficult to ascertain the parent proton distribution. In this paper we investigate the evolution of proton distributions, initially represented by a kappa function, that experience losses due to charge-exchange in the IHS. In the absence of other processes, it is no longer representable by a single kappa function due to the energy-dependent, charge-exchange process. While one can still fit a kappa function to the evolving proton distribution over limited energy ranges, this yields fitting parameters (pseudo-density, pseudo-temperature, pseudo-kappa index) that depend on the energy range of the fit. We discuss the effects of fitting a kappa function to the IHS proton distribution over limited energy ranges, its dependence on the initial proton distribution properties at the termination shock, and implications for understanding the observations.

  4. XMM-Newton Observations of Solar Wind Charge Exchange Emission

    NASA Technical Reports Server (NTRS)

    Snowden, S. L.; Collier, M. R.; Kuntz, K. D.

    2004-01-01

    We present an XMM-Newton spectrum of diffuse X-ray emission from within the solar system. The spectrum is dominated by O VII and O VIII lines at 0.57 keV and 0.65 keV, O VIII (and possibly Fe XVII) lines at approximately 0.8 keV, Ne IX lines at approximately 0.92 keV, and Mg XI lines at approximately 1.35 keV. This spectrum is consistent with what is expected from charge exchange emission between the highly ionized solar wind and either interstellar neutrals in the heliosphere or material from Earth's exosphere. The emission is clearly seen as a low-energy ( E less than 1.5 keV) spectral enhancement in one of a series of observations of the Hubble Deep Field North. The X-ray enhancement is concurrent with an enhancement in the solar wind measured by the ACE satellite. The solar wind enhancement reaches a flux level an order of magnitude more intense than typical fluxes at 1 AU, and has ion ratios with significantly enhanced higher ionization states. Whereas observations of the solar wind plasma made at a single point reflect only local conditions which may only be representative of solar wind properties with spatial scales ranging from less than half of an Earth radii (approximately 10 s) to 100 Earth radii, X-ray observations of solar wind charge exchange are remote sensing measurements which may provide observations which are significantly more global in character. Besides being of interest in its own right for studies of the solar system, this emission can have significant consequences for observations of more cosmological objects. It can provide emission lines at zero redshift which are of particular interest (e.g., O VII and O VIII) in studies of diffuse thermal emission, and which can therefore act as contamination in objects which cover the entire detector field of view. We propose the use of solar wind monitoring data, such as from the ACE and Wind spacecraft, as a diagnostic to screen for such possibilities.

  5. Spin-Isospin responses via charge exchange reactions of RI beams at SHARAQ

    SciTech Connect

    Shimoura, Susumu

    2012-11-12

    Nuclear spectroscopy via direct reactions of RI beams is discussed focusing on characteristics of charge-exchange reactions of RI beams. Recent experiments using the SHARAQ spectrometer at the RIBF are presented, where isovector spin monopole and spin-non-flip monopole responses are studied by charge exchange reaction of RI beams. Some experimental plans and perspectives are also presented.

  6. Double charge exchange on Te isotopes in the generalized seniority scheme

    SciTech Connect

    Wu, H.C. |; Ginocchio, J.N.; Dieperink, A.E.; Scholten, O.

    1996-09-01

    The pion double-charge-exchange reactions on the Te isotopes are discussed in the generalized seniority scheme. The elementary process of charge exchange is described in a double scattering process within the plane wave limit. The transition rates are calculated for double-isobaric-analog state as well as for ground-state reactions. {copyright} {ital 1996 The American Physical Society.}

  7. Charge Exchange, from the Laboratory to Galaxy Clusters

    NASA Astrophysics Data System (ADS)

    Betancourt-Martinez, Gabriele; Beiersdorfer, Peter; Brown, Gregory; Hell, Natalie; Leutenegger, Maurice A.; Porter, Frederick S.; Reynolds, Christopher S.

    2016-04-01

    X-ray emission due to charge exchange (CX) between solar wind ions and neutrals in comets and planetary atmospheres is ubiquitous in the solar system, and is also a significant foreground in all observations from low-Earth orbit. It is also possible that CX is common astrophysically, in any environment where hot plasma and cold gas interact. A current challenge is that theoretical models of CX spectra do not always accurately describe observations, and require further experimental verification. This is especially important to focus on now, as the recent launch of Astro-H is providing us with the first high-resolution spectra of extended x-ray sources. In order to improve our understanding and modeling of CX spectra, we take advantage of the laboratory astrophysics program at the Lawrence Livermore National Laboratory and use an Electron Beam Ion Trap (EBIT) to perform CX experiments, using the EBIT Calorimeter Spectrometer. We present experimental benchmarks that can be used to develop a more comprehensive and accurate CX theory. On the observational side, we also investigate the possibility of CX occurring in the filaments around the central galaxy of the Perseus cluster, NGC 1275. We use Chandra ACIS data, combined with what we know about laboratory CX spectra, to investigate the possibility of CX being a significant contributor to the x-ray emission.

  8. Charge exchange recombination spectroscopy on the T-10 tokamak.

    PubMed

    Klyuchnikov, L A; Krupin, V A; Nurgaliev, M R; Korobov, K V; Nemets, A R; Dnestrovskij, A Yu; Tugarinov, S N; Serov, S V; Naumenko, N N

    2016-05-01

    The charge exchange recombination spectroscopy (CXRS) diagnostics on the T-10 tokamak is described. The system is based on a diagnostic neutral beam and includes three high etendue spectrometers designed for the ITER edge CXRS system. A combined two-channel spectrometer is developed for simultaneous measurements of two beam-induced spectral lines using the same lines of sight. A basic element of the combined spectrometer is a transmitting holographic grating designed for the narrow spectral region 5291 ± 100 Å. The whole CXRS system provides simultaneous measurements of two CXRS impurity spectra and Hα beam line. Ion temperature measurements are routinely provided using the C(6+) CXRS spectral line 5291 Å. Simultaneous measurements of carbon densities and one more impurity (oxygen, helium, lithium etc.) are carried out. Two light collecting systems with 9 lines of sight in each system are used in the diagnostics. Spatial resolution is up to 2.5 cm and temporal resolution of 1 ms is defined by the diagnostic neutral beam diameter and pulse duration, respectively. Experimental results are shown to demonstrate a wide range of the CXRS diagnostic capabilities on T-10 for investigation of impurity transport processes in tokamak plasma. Developed diagnostics provides necessary experimental data for studying of plasma electric fields, heat and particle transport processes, and for investigation of geodesic acoustic modes.

  9. STUDIES OF X-RAY PRODUCTION FOLLOWING CHARGE EXCHANGE RECOMBINATION BETWEEN HIGHLY CHARGED IONS AND NEUTRAL ATOMS AND MOLECULES

    SciTech Connect

    Brown, G V; Beiersdorfer, P; Chen, H; Clementson, J; Frankel, M; Gu, M F; Kelley, R L; Kilbourne, C A; Porter, F S; Thorn, D B; Wargelin, B J

    2008-08-28

    We have used microcalorimeters built by the NASA/Goddard Space Flight Center and the Lawrence Livermore National Laboratory Electron Beam Ion Trap to measure X-ray emission produced by charge exchange reactions between highly charged ions colliding with neutral helium, hydrogen, and nitrogen gas. Our measurements show the spectral dependence on neutral species and also show the distinct differences between spectra produced by charge exchange reactions and those produced by direct impact excitation. These results are part of an ongoing experimental investigation at the LLNL EBIT facility of charge exchange spectral signatures and can be used to interpret X-ray spectra produced by a variety of laboratory and celestial sources including cometary and planetary atmospheres, the Earth's magnetosheath, the heliosphere, and tokamaks.

  10. The loss rates of O{sup +} in the inner magnetosphere caused by both magnetic field line curvature scattering and charge exchange reactions

    SciTech Connect

    Ji, Y.; Shen, C.

    2014-03-15

    With consideration of magnetic field line curvature (FLC) pitch angle scattering and charge exchange reactions, the O{sup +} (>300 keV) in the inner magnetosphere loss rates are investigated by using an eigenfunction analysis. The FLC scattering provides a mechanism for the ring current O{sup +} to enter the loss cone and influence the loss rates caused by charge exchange reactions. Assuming that the pitch angle change is small for each scattering event, the diffusion equation including a charge exchange term is constructed and solved; the eigenvalues of the equation are identified. The resultant loss rates of O{sup +} are approximately equal to the linear superposition of the loss rate without considering the charge exchange reactions and the loss rate associated with charge exchange reactions alone. The loss time is consistent with the observations from the early recovery phases of magnetic storms.

  11. Excitation and Charge Exchange Phenomena in Astronomical Objects: Measurement of Cross Sections and Lifetimes

    NASA Technical Reports Server (NTRS)

    Chutjian, Ara; Smith, S.; Lozano, J.; Cadez, I.; Greewnood, J.; Mawhovter, R.; Williams, I.; Niimura, M.

    2003-01-01

    This document addresses extreme ultraviolet radiation and X-ray emissions from comets, planets and heliospheric gases focusing on the measurement of charge-exchange cross sections and radiative lifetimes. Highly-charged heavy ions present in the solar wind, and their abundance relative to the total oxygen-ion abundance are detailed. The plan for the Jet Propulsion Laboratory high-charge ion facility is outlined detailing its ability to measure absolute collisional excitation cross sections, absolute charge-exchange cross sections, lifetimes of metastable ion levels, and X-ray emission spectra following charge changes.

  12. Neutral Collisions and Charge Exchange in Titan's Exosphere

    NASA Astrophysics Data System (ADS)

    Sillanpää, I.; Johnson, R. E.

    2012-12-01

    Results from new hybrid simulations for Titan are presented. These simulations take into account the elastic collisions between ions and neutral gas as well as the charge exchange reactions for protons and oxygen ions. We used SRIM [1] cross sections for hydrogen and oxygen ions in nitrogen gas to calculate cross sections for the five ions species used in the HYB-Titan hybrid model [2, see also 3] (H+, H2+, O+, CH4+, and N2+). The N2 density profile used was from INMS measurements over a dozen flybys. In addition, we are studying the effect the charge transfer (CT) reactions for H+ and O+ leading to simple CT, dissociative CT and CT with ionization. All reaction cross sections are energy dependent. Neutral particles are not created, but the total ENA energy is recorded as well as the resulting reaction rates. The results show that both of neutral collisions and CT processes have a significant role in the development and shape of Titan's ionotail and wake structure. Results will be described in detail as well as the implications of the ion-neutral collisions for the heating of Titan's neutral corona and atmospheric escape [4]. References [1] Stopping and Range of Ions in Matter (SRIM), Monte Carlo software by James F. Ziegler (online at http://www.srim.org/ ) [2] Sillanpää, I., Hybrid Modelling of Titan's Interaction with the Magnetosphere of Saturn, Ph.D. dissertation, Finnish Meteorological Contributions, 68, Yliopistopaino, Helsinki, 2008. (online at http://urn.fi/URN:ISBN:978-951-697-660-3) [3] Sillanpää, I., D. Young, F. Crary, M. Thomsen, D. Reisenfeld, J-E.Wahlund, C. Bertucci, E. Kallio, R. Jarvinen, and P. Janhunen, Cassini Plasma Spectro:meter and Hybrid Model Study on Titan's Interaction: Effect of Oxygen Ions, J. Geophys. Res., doi:10.1029/2011JA016443, 2011. [4] Johnson, R.E., O.J. Tucker, M. Michael, E.C. Sittler, H.T. Smith, D.T. Young, and J.H. Waite, Mass Loss Processes in Titan's Upper Atmosphere, Chap. 15 in "Titan from Cassini-Huygens" (eds

  13. Trace adsorption of positively charged proteins onto Sepharose FF and Sepharose FF-based anion exchangers.

    PubMed

    Yu, Lin-Ling; Sun, Yan

    2012-08-31

    Agarose-based matrices have been widely used in ion exchange chromatography (IEC). We have herein observed that positively charged proteins (lysozyme and cytochrome c) are adsorbed on the agarose-based anion-exchangers (Q and DEAE Sepharose FF gels) in a capacity of 10-40 μg/mL. In contrast, negatively charged protein (bovine serum albumin) is not adsorbed to Sepharose FF and SP Sepharose FF gels. Elemental analysis of the gel indicated that the residual anionic sulfate groups in agarose would have worked as the cation exchange groups for the positively charged proteins. The trace adsorption behavior of lysozyme onto Sepharose FF and Sepharose FF-based anion exchangers was studied and the effects of NaCl concentration and cation group density on the adsorption were examined for better understanding of the trace adsorption in chromatographic processes. At NaCl concentrations less than 0.05 mol/L, which is the normal adsorption condition in IEC, the trace adsorption kept at a high level, so this trace adsorption cannot be avoided in the ionic strength range of routine IEC operations. Grafting poly(ethylenimine) (PEI) chain of 60 kDa to a cation group density of 700 mmol/L could reduce the adsorption capacity to about 20 μg/mL, but further reduction was not possible by increasing the cation group density to 1200 mmol/L. Therefore, attentions need to be paid to the phenomenon in protein purification practice using agarose-based matrices. The research is expected to call attentions to the trace adsorption on agarose-based matrices and to the importance in the selection of the suitable solid matrices in the production of high-purity protein products in large-scale bioprocesses.

  14. Highly charged swelling mica-type clays for selective Cu exchange.

    PubMed

    Ravella, Ramesh; Komarneni, Sridhar; Martinez, Carmen Enid

    2008-01-01

    There is a need to develop highly CU2+ selective materials which can potentially remediate copper contaminated soils and water. Here we show that several highly charged synthetic swelling mica-type clays are highly selective for copper exchange. The synthetic micas have cation exchange capacities (CECs), which are close to their theoretical values. Both Na-saturated and Mg-saturated micas were investigated for Cu ion exchange selectivity. Ion exchange isotherms and Kielland plots were constructed using the equilibrated solution analyses. From these studies it was found that Na-4-mica and Na-3-mica could selectively exchange copper at lower concentrations from solution, whereas Na-2-mica sample performed better by showing Cu ion exchange selectively to almost its capacity. The EPR spectra of Cu-exchanged micas coincide with the mica's charge characteristics that predict increased binding strength of exchangeable Cu in Na-4-mica and Na-3-mica than in Na-2-mica.

  15. First Demonstration of Laser-Assisted Charge Exchange for Microsecond Duration H- Beams

    NASA Astrophysics Data System (ADS)

    Cousineau, Sarah; Rakhman, Abdurahim; Kay, Martin; Aleksandrov, Alexander; Danilov, Viatcheslav; Gorlov, Timofey; Liu, Yun; Plum, Michael; Shishlo, Andrei; Johnson, David

    2017-02-01

    This Letter reports on the first demonstration of laser-assisted H- charge exchange for microsecond duration H- beam pulses. Laser-assisted charge exchange injection is a breakthrough technology that overcomes long-standing limitations associated with the traditional method of producing high intensity, time structured beams of protons in accelerators via the use of carbon foils for charge exchange injection. The central theme of this experiment is the demonstration of novel techniques that reduce the laser power requirement to allow high efficiency stripping of microsecond duration beams with commercial laser technology.

  16. X-ray emission cross sections following charge exchange by multiply charged ions of astrophysical interest

    SciTech Connect

    Otranto, S.; Olson, R. E.; Beiersdorfer, P.

    2006-02-15

    State selective nl-electron capture cross sections are presented for highly charged ions with Z=6-10 colliding with atoms and molecules. The energy range investigated was from 1 eV/amu(v=0.006 a.u.)to 100 keV/amu(v=2.0 a.u.). The energy dependence of the l-level populations is investigated. The K shell x-ray emission cross sections are determined by using the calculated state-selective electron capture results as input and then applying hydrogenic branching and cascading values for the photon emission. A major shift in the line emission from being almost solely Lyman-{alpha} transitions at the highest collisions energies to strong high-n to 1s transitions at the lowest energies is observed. The calculated cross sections are in reasonable accord with measurements made by Greenwood et al. [Phys. Rev. A 63, 062707 (2001)], using O{sup 8+} and Ne{sup 10+} on various targets at 3 keV/amu. The calculations are also in accord with x-ray emission cross section data obtained on the EBIT machine at Lawrence Livermore National Laboratory (LLNL) where O{sup 8+} and Ne{sup 10+} high resolution measurements were made at a temperature of 10 eV/amu for a series of targets with varying ionization potentials. The Ne{sup 10+} data clearly shows the contribution from multiple capture followed by Auger autoionization in the line emission spectra. Our calculated line emission cross sections are used to provide an ab initio determination of the soft x-ray spectrum of comet C/Linear 1999 S4 that was observed on the Chandra X-ray Observatory. The calculations show that the spectrum is due to the charge exchange of the neutral gases in the comet's coma with the ions of the slow solar wind.

  17. Recent Excitation, Charge Exchange, and Lifetime Results in Highly Charged Ions Relevant to Stellar, Interstellar, Solar and Comet Phenomena

    NASA Technical Reports Server (NTRS)

    Chutjian, A.; Hossain, S.; Mawhorter, R. J.; Smith, S. J.

    2006-01-01

    Recent JPL absolute excitation and charge exchange cross sections, and measurements of lifetimes of metastable levels in highly-charged ions (HCIs) are reported. These data provide benchmark comparisons to results of theoretical calculations. Theoretical approaches can then be used to calculate the vast array of data which cannot be measured due to experimental constraints. Applications to the X-ray emission from comets are given.

  18. Pion single- and double-charge-exchange reactions at low energies

    SciTech Connect

    Baer, H.W.

    1987-01-01

    The general features of pion charge-exchange reactions at energies of 20 to 80 MeV leading to nuclear isobaric-analog states (IAS) and double-isobaric-analog states (DIAS) are reviewed. The recent progress achieved in understanding the role of short-range N-N correlations in the double-charge-exchange reactions is presented. 36 refs., 21 figs., 2 tabs.

  19. Neutral atomic oxygen beam produced by ion charge exchange for Low Earth Orbital (LEO) simulation

    NASA Technical Reports Server (NTRS)

    Banks, Bruce; Rutledge, Sharon; Brdar, Marko; Olen, Carl; Stidham, Curt

    1987-01-01

    A low energy neutral atomic oxygen beam system was designed and is currently being assembled at the Lewis Research Center. The system utilizes a 15 cm diameter Kaufman ion source to produce positive oxygen ions which are charge exchange neutralized to produce low energy (variable from 5 to 150 eV) oxygen atoms at a flux simulating real time low Earth orbital conditions. An electromagnet is used to direct only the singly charged oxygen ions from the ion source into the charge exchange cell. A retarding potential grid is used to slow down the oxygen ions to desired energies prior to their charge exchange. Cryogenically cooled diatomic oxygen gas in the charge exchange cell is then used to transfer charge to the oxygen ions to produce a neutral atomic oxygen beam. Remaining non-charge exchanged oxygen ions are then swept from the beam by electromagnetic or electrostatic deflection depending upon the desired experiment configuration. The resulting neutral oxygen beam of 5 to 10 cm in diameter impinges upon target materials within a sample holder fixture that can also provide for simultaneous heating and UV exposure during the atomic oxygen bombardment.

  20. Lipid exchange between membranes: effects of membrane surface charge, composition, and curvature.

    PubMed

    Zhu, Tao; Jiang, Zhongying; Ma, Yuqiang

    2012-09-01

    Intermembrane lipid exchange is critical to membrane functions and pharmaceutical applications. The exchange process is not fully understood and it is explored by quartz crystal microbalance with dissipation monitor method in this research. It is found that intermembrane lipid exchange is accelerated with the decrease of vesicle size and the increase of charge and liquid crystalline lipid composition ratio. Vesicle adsorption rate, membrane lateral pressure gradient, and lipid lateral diffusion coefficient are inferred to be critical in deciding the lipid exchange kinetics between membranes. Besides that, the membrane contact situation during lipid exchange is also studied. The maximum total membrane contact area is found to increase with the decrease of vesicle size, charged and liquid crystalline lipid composition ratio. A competition mechanism between the vesicle adsorption rate and the intermembrane lipid exchange rate was proposed to control the maximum total membrane contact area.

  1. High spatial and temporal resolution charge exchange recombination spectroscopy on the HL-2A tokamak

    SciTech Connect

    Wei, Y. L.; Yu, D. L. Liu, L.; Cao, J. Y.; Sun, A. P.; Ma, Q.; Chen, W. J.; Liu, Yi; Yan, L. W.; Yang, Q. W.; Duan, X. R.; Liu, Yong; Ida, K.; Hellermann, M. von

    2014-10-01

    A 32/64-channel charge exchange recombination spectroscopy (CXRS) diagnostic system is developed on the HL-2A tokamak (R = 1.65 m, a = 0.4 m), monitoring plasma ion temperature and toroidal rotation velocity simultaneously. A high throughput spectrometer (F/2.8) and a pitch-controlled fiber bundle enable the temporal resolution of the system up to 400 Hz. The observation geometry and an optimized optic system enable the highest radial resolution up to ~1 cm at the plasma edge. The CXRS system monitors the carbon line emission (C VI, n = 8–7, 529.06 nm) whose Doppler broadening and Doppler shift provide ion temperature and plasma rotation velocity during the neutral beam injection. The composite CX spectral data are analyzed by the atomic data and analysis structure charge exchange spectroscopy fitting (ADAS CXSFIT) code. First experimental results are shown for the case of HL-2A plasmas with sawtooth oscillations, electron cyclotron resonance heating, and edge transport barrier during the high-confinement mode (H-mode)

  2. High spatial and temporal resolution charge exchange recombination spectroscopy on the HL-2A tokamak.

    PubMed

    Wei, Y L; Yu, D L; Liu, L; Ida, K; von Hellermann, M; Cao, J Y; Sun, A P; Ma, Q; Chen, W J; Liu, Yi; Yan, L W; Yang, Q W; Duan, X R; Liu, Yong

    2014-10-01

    A 32/64-channel charge exchange recombination spectroscopy (CXRS) diagnostic system is developed on the HL-2A tokamak (R = 1.65 m, a = 0.4 m), monitoring plasma ion temperature and toroidal rotation velocity simultaneously. A high throughput spectrometer (F/2.8) and a pitch-controlled fiber bundle enable the temporal resolution of the system up to 400 Hz. The observation geometry and an optimized optic system enable the highest radial resolution up to ∼1 cm at the plasma edge. The CXRS system monitors the carbon line emission (C VI, n = 8-7, 529.06 nm) whose Doppler broadening and Doppler shift provide ion temperature and plasma rotation velocity during the neutral beam injection. The composite CX spectral data are analyzed by the atomic data and analysis structure charge exchange spectroscopy fitting (ADAS CXSFIT) code. First experimental results are shown for the case of HL-2A plasmas with sawtooth oscillations, electron cyclotron resonance heating, and edge transport barrier during the high-confinement mode (H-mode).

  3. High spatial and temporal resolution charge exchange recombination spectroscopy on the HL-2A tokamak

    NASA Astrophysics Data System (ADS)

    Wei, Y. L.; Yu, D. L.; Liu, L.; Ida, K.; von Hellermann, M.; Cao, J. Y.; Sun, A. P.; Ma, Q.; Chen, W. J.; Liu, Yi; Yan, L. W.; Yang, Q. W.; Duan, X. R.; Liu, Yong

    2014-10-01

    A 32/64-channel charge exchange recombination spectroscopy (CXRS) diagnostic system is developed on the HL-2A tokamak (R = 1.65 m, a = 0.4 m), monitoring plasma ion temperature and toroidal rotation velocity simultaneously. A high throughput spectrometer (F/2.8) and a pitch-controlled fiber bundle enable the temporal resolution of the system up to 400 Hz. The observation geometry and an optimized optic system enable the highest radial resolution up to ˜1 cm at the plasma edge. The CXRS system monitors the carbon line emission (C VI, n = 8-7, 529.06 nm) whose Doppler broadening and Doppler shift provide ion temperature and plasma rotation velocity during the neutral beam injection. The composite CX spectral data are analyzed by the atomic data and analysis structure charge exchange spectroscopy fitting (ADAS CXSFIT) code. First experimental results are shown for the case of HL-2A plasmas with sawtooth oscillations, electron cyclotron resonance heating, and edge transport barrier during the high-confinement mode (H-mode).

  4. X-ray Signature of Charge Exchange in the Spectra of L-shell Iron Ions

    SciTech Connect

    Beiersdorfer, P; Schweikhard, L; Liebisch, P; Brown, G V

    2007-01-05

    The X-ray signature of charge exchange between highly charged L-shell iron ions and neutral gas atoms was studied in the laboratory in order to assess its diagnostic utility. Significant differences with spectra formed by electron-impact excitation were observed. In particular, a strong enhancement was found of the emission corresponding to n {le} 4 {yields} n = 2 transitions relative to the n = 3 {yields} n = 2 emission. This enhancement was detectable even with relatively low-resolution X-ray instrumentation (E/{Delta}E {approx} 10) and may enable future identification of charge exchange as a line-formation mechanism in astrophysical spectra.

  5. Laboratory simulation of charge exchange-produced X-ray emission from comets.

    PubMed

    Beiersdorfer, P; Boyce, K R; Brown, G V; Chen, H; Kahn, S M; Kelley, R L; May, M; Olson, R E; Porter, F S; Stahle, C K; Tillotson, W A

    2003-06-06

    In laboratory experiments using the engineering spare microcalorimeter detector from the ASTRO-E satellite mission, we recorded the x-ray emission of highly charged ions of carbon, nitrogen, and oxygen, which simulates charge exchange reactions between heavy ions in the solar wind and neutral gases in cometary comae. The spectra are complex and do not readily match predictions. We developed a charge exchange emission model that successfully reproduces the soft x-ray spectrum of comet Linear C/1999 S4, observed with the Chandra X-ray Observatory.

  6. Local charge exchange of He+ ions at Aluminum surfaces

    NASA Astrophysics Data System (ADS)

    Riccardi, P.; Sindona, A.; Dukes, C. A.

    2017-04-01

    We report on experiments designed to observe the correlation between the autoionization of doubly excited helium atoms and the Auger decay of 2p vacancies in Al. The autoionizing states are formed when incident He+* and He++ are neutralized by resonant electron capture at the surface. 2p excitation in Al occurs in dielectronic charge transfer during the close encounter of an excited helium ion and an Al atom. These results clarify the mechanism for Al-2p excitation in the case of singly charged ground state He+(1s) ion impact, where the dielectronic transition occurs after promotion of the 1s electron of incoming ions.

  7. Charge-Transfer Effects in Ligand Exchange Reactions of Au25 Monolayer-Protected Clusters.

    PubMed

    Carducci, Tessa M; Blackwell, Raymond E; Murray, Royce W

    2015-04-16

    Reported here are second-order rate constants of associative ligand exchanges of Au25L18 nanoparticles (L = phenylethanethiolate) of various charge states, measured by proton nuclear magnetic resonance at room temperature and below. Differences in second-order rate constants (M(-1) s(-1)) of ligand exchange (positive clusters ∼1.9 × 10(-5) versus negative ones ∼1.2 × 10(-4)) show that electron depletion retards ligand exchange. The ordering of rate constants between the ligands benzeneselenol > 4-bromobenzene thiol > benzenethiol reveals that exchange is accelerated by higher acidity and/or electron donation capability of the incoming ligand. Together, these observations indicate that partial charge transfer occurs between the nanoparticle and ligand during the exchange and that this is a rate-determining effect in the process.

  8. Multiproduct high-resolution monoclonal antibody charge variant separations by pH gradient ion-exchange chromatography.

    PubMed

    Farnan, Dell; Moreno, G Tony

    2009-11-01

    In the biotechnology industry, ion-exchange chromatography is widely used for profiling the charge heterogeneity of proteins, including monoclonal antibodies. Ionic strength based ion exchange separations, while having excellent resolving power and robustness, are product specific and time-consuming to develop. In the present work, a pH gradient based separation using a cation exchange column is described and shown to be a multiproduct charge sensitive separation method for monoclonal antibodies. Simple mixtures of defined buffer components were used to generate the pH-gradients that separate closely related antibody species. The form of the pH gradient was controlled and optimized by the pump as well as the buffer composition if necessary. During this work, the buffer compositions for the separation were optimized in parallel for several MAbs. The data shows that the multiproduct method is optimal for all of the MAbs studied. Operational aspects of the separation such as column chemistry, column length, and sample matrix indicate a very robust method. The pH gradient ion-exchange method is demonstrated to have significant resolving power and peak capacities far in excess of what we would expect for ionic strength elution ion-exchange. Data obtained demonstrates that the separation is relatively insensitive to column length. Direct analysis (no buffer exchange) of samples in matrixes consistent with in-process manufacturing pools is demonstrated. Such a capability is extremely useful for the high throughput evaluation of in-process and final product samples.

  9. Time-dependence ion charge state distributions of vacuum arcs: An interpretation involving atoms and charge exchange collisions

    SciTech Connect

    Anders, Andre

    2004-08-27

    Experimentally observed charge state distributions are known to be higher at the beginning of each arc discharge. Up to know, this has been attributed to cathode surface effects in terms of changes of temperature, chemical composition and spot mode. Here it is shown that the initial decay of charge states of cathodic arc plasmas may at least in part due to charge exchange collisions of ions with neutrals that gradually fill the discharge volume. Sources of neutrals may include evaporated atoms from macroparticles and still-hot craters of previously active arc spots. More importantly, atoms are also produced by energetic condensation of the cathodic arc plasma. Self-sputtering is significant when ions impact with near-normal angle of incidence, and ions have low sticking probability when impacting at oblique angle of incidence. Estimates show that the characteristic time for filling the near-cathode discharge volume agrees well with the charge state decay time, and the likelihood of charge exchange is reasonably large to be taken into account.

  10. X-Ray Emission Cross Sections following Charge Exchange by Multiply-Charged Ions of Astrophysical Interest

    SciTech Connect

    Otranto, S; Olson, R E; Beiersdorfer, P

    2007-03-12

    The CTMC method is used to calculate emission cross sections following charge exchange processes involving highly charged ions of astrophysical interest and typical cometary targets. Comparison is made to experimental data obtained on the EBIT-I machine at Lawrence Livermore National Laboratory LLNL for O{sup 8+} projectiles impinging on different targets at a collision energy of 10 eV/amu. The theoretical cross sections are used together with ion abundances measured by the Advanced Composition Explorer to reproduce cometary spectra. Discrepancies due to different estimated delays of solar wind events between the comet and the Earth-orbiting satellite are discussed.

  11. Study of multi-electron ionization and charge exchange in HIBF

    NASA Astrophysics Data System (ADS)

    Wu, Linchun

    Beam ion stripping on background gases or plasma in a Heavy Ion Beam Fusion (HIBF) chamber increases the charge state of the beam and the diameter of the focus, complicating the final focusing on the focusing target. To model beam transport in the chamber, it is necessary to know the beam charge-state evolution, including both ionization and charge exchange dynamics. The main objective of this research is to explore theoretical approaches including scaling law. Improved models are developed to calculate multi-electron loss, especially ion stripping and charge exchange cross sections, for both near-term experiments and future power plant scale HIBF research. First, a new space-charge neutralization approach that uses electron injection is proposed for the ion beam transport in HIBF chamber. An analytical study was performed to illustrate the plasma dynamics and final neutralization effects with this technique. The results examine the effect of different injected electron profiles. Next, to improve the accuracy of such simulations, methods to improve cross sections of ionization and charge exchange are studied. Both classical and quantum mechanical approaches are examined. Attention is focused on the interaction by low-charge-state heavy ions. Multi-electron processes for dressed ions, including screening and anti-screening effects, internuclear forces, are given special attention, This analysis is complex and requires a combining several different theoretical approaches. Finally, a Classic Trajectory Monte Carlo (CTMC) model based on an improvement of Olson's n-body CTMC method is presented. This model solves the n-body ion-atom ionization problem in a regime of intent to HIBF. In the paper, a new and complete computational module for these interactions has been developed. The cross section data for Xe, Cs, and Bi ions colliding with various background gases (Xe, N2, Ar and Flibe) is presented. After the calculation of the cross section data, the predicted energy

  12. Inference of the ring current ion composition by means of charge exchange decay

    NASA Technical Reports Server (NTRS)

    Smith, P. H.; Bewtra, N. K.; Hoffman, R. A.

    1978-01-01

    The analysis of the measured ion fluxes during the several day storm recovery period and the assumption that beside hydrogen other ions were present and that the decays were exponential in nature, it was possible to establish three separate lifetimes for the ions. These fitted decay lifetimes are in excellent agreement with the expected charge exchange decay lifetimes for H(+), O(+), and He(+) in the energy and L-value range of the data. This inference technique, thus, establishes the presence of measurable and appreciable quantities of oxygen and helium ions as well as protons in the storm-time ring current. Indications that He(+) may also be present under these same conditions were found.

  13. Removal of charged micropollutants from water by ion-exchange polymers -- effects of competing electrolytes.

    PubMed

    Bäuerlein, Patrick S; Ter Laak, Thomas L; Hofman-Caris, Roberta C H M; de Voogt, Pim; Droge, Steven T J

    2012-10-15

    A wide variety of environmental compounds of concern, e.g. pharmaceuticals or illicit drugs, are acids or bases that may predominantly be present as charged species in drinking water sources. These charged micropollutants may prove difficult to remove by currently used water treatment steps (e.g. UV/H(2)O(2), activated carbon (AC) or membranes). We studied the sorption affinity of some ionic organic compounds to both AC and different charged polymeric materials. Ion-exchange polymers may be effective as additional extraction phases in water treatment, because sorption of all charged compounds to oppositely charged polymers was stronger than to AC, especially for the double-charged cation metformin. Tested below 1% of the polymer ion-exchange capacity, the sorption affinity of charged micropollutants is nonlinear and depends on the composition of the aqueous medium. Whereas oppositely charged electrolytes do not impact sorption of organic ions, equally charged electrolytes do influence sorption indicating ion-exchange (IE) to be the main sorption mechanism. For the tested polymers, a tenfold increased salt concentration lowered the IE-sorption affinity by a factor two. Different electrolytes affect IE with organic ions in a similar way as inorganic ions on IE-resins, and no clear differences in this trend were observed between the sulphonated and the carboxylated cation-exchanger. Sorption of organic cations is five fold less in Ca(2+) solutions compared to similar concentrations of Na(+), while that of anionic compounds is three fold weaker in SO(4)(2-) solutions compared to equal concentrations of Cl(-).

  14. Atomic hydrogen escape rate due to charge exchange with hot plasmaspheric ions

    NASA Technical Reports Server (NTRS)

    Maher, L. J.; Tinsley, B. A.

    1977-01-01

    Data on ion and electron temperatures and concentrations to several thousand kilometers of altitude were obtained from the Atmosphere Explorer C satellite for 1974 and to 850 km from Arecibo incoherent scatter radar measurements. These data were used to normalize diffusive equilibrium profiles. From these profiles and by using the neutral atmospheric model of Jacchia (1971) and a new hydrogen model, the charge-exchange-induced neutral hydrogen escape fluxes for equatorial and middle latitudes were calculated. The data confirm earlier estimates that the charge exchange loss is more important than Jeans escape for the earth. It is also found that inside the plasmapause this charge exchange process with hot plasmapheric ions is the major production and loss process for the satellite population in the hydrogen geocorona.

  15. The influence of charge exchange on the velocity distribution of hydrogen in the Venus exosphere

    NASA Technical Reports Server (NTRS)

    Hodges, Richard R., Jr.; Tinsley, Brian A.

    1986-01-01

    The simulation of the exosphere of Venus by a Monte Carlo technique has been extended to provide velocity distribution profiles that can be used with radiative transfer simulation to model the Lyman-alpha emission seen by spacecraft. The line profiles show a narrow core due to the exobase thermal source of hydrogen superimposed on the broad profile of hot hydrogen from charge exchange with hot ions in the nighttime ionosphere. Nightside radial profiles show long tails of upward flowing, escaping atoms. There are some downward and lateral superescape signatures, because the charge exchange source extends well above the exobase. At higher altitudes, flattening and even shallow central valleys appear in the transverse profiles. The planetary average escape rate due to charge exchange was found to be 2.8 x 10 to the 7th/sq cm per s, which is several times larger than escape rates for other candidate mechanisms.

  16. Ion temperatures in HIP-1 and SUMMA from charge-exchange neutral optical emission spectra

    NASA Technical Reports Server (NTRS)

    Patch, R. W.; Lauver, M. R.

    1976-01-01

    Ion temperatures were obtained from observations of the H sub alpha, D sub alpha, and He 587.6 nm lines emitted from hydrogen, deuterium, and helium plasmas in the SUMMA and HIP-1 mirror devices at Lewis Research Center. Steady state discharges were formed by applying a radially inward dc electric field between cylindrical or annular anodes and hollow cathodes located at the peaks of the mirrors. The ion temperatures were found from the Doppler broadening of the charge-exchange components of spectral lines. A statistical method was developed for obtaining scaling relations of ion temperature as a function of current, voltage, and magnetic flux density. Derivations are given that take into account triangular monochromator slit functions, loss cones, and superimposed charge-exchange processes. In addition, the Doppler broadening was found to be sensitive to the influence of drift on charge-exchange cross section. The effects of finite ion-cyclotron radius, cascading, and delayed emission are reviewed.

  17. Pion single charge exchange in three body nuclei at intermediate energies

    SciTech Connect

    Dowell, Marla L.

    1994-01-01

    The purpose of this thesis is to present new experimental information about modifications to the pion-nucleon single charge exchange interaction, π+n → π0 p or π- p → π0n, due to the presence of other nucleons. The results of two experimental studies of pion single charge exchange in the three nucleon system near the Δ-resonance are presented. Both of these experiments were performed at the Clinton P. Anderson Meson Physics Facility (LAMPF), a division of the Los Alamos National Laboratory. Each explored different aspects of pion single charge exchange in three body nuclei--3He and 3H. Since the nuclear wavefunctions of the three nucleon systems are believed to be well understood, it should be possible to perform theoretical calculations of pion interactions with this system and compare their predictions with the experimental results.

  18. Selective Cu{sup 2+} and Pb{sup 2+} exchange with highly charged cation exchanger of Na-4-mica

    SciTech Connect

    Kodama, Tatsuya; Komarneni, Sridhar

    1999-09-01

    Selective cation exchange for Cu and Pb has been demonstrated with the high-charge-density sodium fluorophlogopite mica, Na-4-mica. The 2Na{sup +} {yields} M{sup 2+} exchange reaction (M = Cu or Pb) was investigated with Na-4-micas prepared by two different synthetic processes. One was easily and economically prepared by crystallization from a mixture of NaF, MgO, and metakaolin, the latter serves as an inexpensive aluminosilicate source. Another was prepared by solution-sol-gel processing. Ion-exchange isotherms for Cu{sup 2+} and Pb{sup 2+} were obtained at room temperature. The thermodynamic functions for the initial ion-exchange reactions were calculated because the isotherms were not completed., High selectivities for both copper and lead exchange were found on the highly crystallized Na-4-mica prepared from metakaolin. Their ion-exchange capacities were 225 and 257 milliequivalents per 100 g of dry clay for Cu{sup 2+} and Pb{sup 2+}, respectively. This high level decontamination of copper and lead with the highly crystallized Na-4-mica from metakaolin will be a very important separation required for purification of drinking water as well as for wastewater treatment and disposal.

  19. Charge exchange and ionization in hydrogen atom-fully stripped ion collisions in Debye plasmas

    SciTech Connect

    Zhang, H.; Wang, J. G.; He, B.; Qiu, Y. B.; Janev, R. K.

    2007-05-15

    The processes of charge exchange and ionization in collisions of ground state hydrogen atom with fully stripped ions in a weakly coupled plasma are studied by the classical trajectory Monte Carlo method in the collision energy range 10-900 keV/amu. The interparticle interactions are described by the Debye-Hueckel model with inclusion of dynamical effects associated with the projectile velocity. The microcanonical distribution of initial state electronic coordinates and momenta has been determined by inclusion of plasma screening effects. The cross section dependencies on plasma parameters and ion charge and velocity are investigated. It is shown that plasma effects on charge exchange and ionization cross sections are significant and particularly pronounced at low collision velocities. The results of systematic cross section calculations for different values of Debye screening length (in the range 1-50a{sub 0}) and ion charges (in the range 1-14) are presented.

  20. Interaction of a solar array with an ion thruster due to the charge-exchange plasma

    NASA Technical Reports Server (NTRS)

    Kaufman, H. R.

    1976-01-01

    The generation of a charge exchange plasma by a thruster, the transport of this plasma to the solar array, and the interaction of the solar array with the plasma after it arrives are all described. The generation of this plasma is described accurately from thruster geometry and operating conditions. The transport of the charge exchange plasma was studied experimentally with a 15 cm thruster. A model was developed for simple thruster array configurations. A variety of experiments were surveyed for the interaction of the plasma at the solar array.

  1. Spectral Diagnostics of Galactic and Stellar X-Ray Emission from Charge Exchange Recombination

    NASA Technical Reports Server (NTRS)

    Wargelin, B.

    2003-01-01

    The proposed research uses the electron beam ion trap at the Lawrence Livermore National Laboratory to study the X-ray emission from charge-exchange recombination of highly charged ions with neutral gases. The resulting data fill a void in the existing experimental and theoretical data and are needed to explain all or part of the observed X-ray emission from the Galactic Ridge, solar and stellar winds, the Galactic Center, supernova ejecta, and photoionized nebulae.

  2. The roles of charge exchange and dissociation in spreading Saturn's neutral clouds

    NASA Astrophysics Data System (ADS)

    Fleshman, B. L.; Delamere, P. A.; Bagenal, F.; Cassidy, T.

    2012-05-01

    Neutrals sourced directly from Enceladus's plumes are initially confined to a dense neutral torus in Enceladus's orbit around Saturn. This neutral torus is redistributed by charge exchange, impact/photodissociation, and neutral-neutral collisions to produce Saturn's neutral clouds. Here we consider the former processes in greater detail than in previous studies. In the case of dissociation, models have assumed that OH is produced with a single speed of 1 km s-1, whereas laboratory measurements suggest a range of speeds between 1 and 1.6 km s-1. We show that the high-speed case increases dissociation's range of influence from 9 to 15 RS. For charge exchange, we present a new modeling approach, where the ions are followed within a neutral background, whereas neutral cloud models are conventionally constructed from the neutrals' point of view. This approach allows us to comment on the significance of the ions' gyrophase at the moment charge exchange occurs. Accounting for gyrophase (1) has no consequence on the H2O cloud, (2) doubles the local density of OH at the orbit of Enceladus, and (3) decreases the oxygen densities at Enceladus's orbit by less than 10%. Finally, we consider velocity-dependent, as well as species-dependent cross sections and find that the oxygen cloud produced from charge exchange is spread out more than H2O, whereas the OH cloud is the most confined.

  3. Effect of the disruptive instability on the flux of charge-exchange atoms in a tokamak

    SciTech Connect

    Alabyad, A.M.; Ivanov, N.V.; Khudoleev, A.V.

    1984-01-01

    Experiments have been carried out on the spatial distribution of the flux of neutral charge-exchange atoms from a tokamak plasma and on the time evolution of this distribution during a disruptive instability. The experimental results are analyzed on the basis of the model of the tearing-mode instability.

  4. Short-range NN and N. Delta. correlations in pion double charge exchange (DCX)

    SciTech Connect

    Johnson, M.B.

    1990-01-01

    I will review several important results related to the short-range nucleon-nucleon and delta-nucleon interaction that have been obtained from recent studies of pion double charge exchange in selected nuclei. 32 refs., 5 figs., 3 tabs.

  5. Charge-Exchange Excitation of the Isobaric Analog State and Implication for the Nuclear Symmetry Energy and Neutron Skin

    NASA Astrophysics Data System (ADS)

    Khoa, Dao T.; Loc, Bui Minh; Zegers, R. G. T.

    The charge-exchange (p, n) or (3He,t) reaction can be considered as elastic scattering of proton or 3He by the isovector term of the optical potential that flips the projectile isospin. Therefore, the accurately measured charge-exchange scattering cross section for the isobaric analog states can be a good probe of the isospin dependence of the optical potential, which is determined exclusively within the folding model by the difference between the neutron and proton densities and isospin dependence of the nucleon-nucleon interaction. On the other hand, the same isospin- and density-dependent nucleon-nucleon interaction can also be used in a Hartree-Fock calculation of asymmetric nuclear matter, to estimate the nuclear matter energy and its asymmetry part. As a result, the fine-tuning of the isospin dependence of the effective nucleon-nucleon interaction against the measured (p, n) or (3He,t) cross sections should allow us to make some realistic prediction of the nuclear symmetry energy and its density dependence. Moreover, given the neutron skin of the target related directly to the neutron-proton difference of the ground-state density, it can be well probed in the analysis of the charge-exchange (3He,t) reactions at medium energies when the two-step processes can be neglected and the t-matrix interaction can be used in the folding calculation.

  6. Charge-dependent many-body exchange and dispersion interactions in combined QM/MM simulations

    NASA Astrophysics Data System (ADS)

    Kuechler, Erich R.; Giese, Timothy J.; York, Darrin M.

    2015-12-01

    Accurate modeling of the molecular environment is critical in condensed phase simulations of chemical reactions. Conventional quantum mechanical/molecular mechanical (QM/MM) simulations traditionally model non-electrostatic non-bonded interactions through an empirical Lennard-Jones (LJ) potential which, in violation of intuitive chemical principles, is bereft of any explicit coupling to an atom's local electronic structure. This oversight results in a model whereby short-ranged exchange-repulsion and long-ranged dispersion interactions are invariant to changes in the local atomic charge, leading to accuracy limitations for chemical reactions where significant atomic charge transfer can occur along the reaction coordinate. The present work presents a variational, charge-dependent exchange-repulsion and dispersion model, referred to as the charge-dependent exchange and dispersion (QXD) model, for hybrid QM/MM simulations. Analytic expressions for the energy and gradients are provided, as well as a description of the integration of the model into existing QM/MM frameworks, allowing QXD to replace traditional LJ interactions in simulations of reactive condensed phase systems. After initial validation against QM data, the method is demonstrated by capturing the solvation free energies of a series of small, chlorine-containing compounds that have varying charge on the chlorine atom. The model is further tested on the SN2 attack of a chloride anion on methylchloride. Results suggest that the QXD model, unlike the traditional LJ model, is able to simultaneously obtain accurate solvation free energies for a range of compounds while at the same time closely reproducing the experimental reaction free energy barrier. The QXD interaction model allows explicit coupling of atomic charge with many-body exchange and dispersion interactions that are related to atomic size and provides a more accurate and robust representation of non-electrostatic non-bonded QM/MM interactions.

  7. Charge-dependent many-body exchange and dispersion interactions in combined QM/MM simulations

    SciTech Connect

    Kuechler, Erich R.; Giese, Timothy J.; York, Darrin M.

    2015-12-21

    Accurate modeling of the molecular environment is critical in condensed phase simulations of chemical reactions. Conventional quantum mechanical/molecular mechanical (QM/MM) simulations traditionally model non-electrostatic non-bonded interactions through an empirical Lennard-Jones (LJ) potential which, in violation of intuitive chemical principles, is bereft of any explicit coupling to an atom’s local electronic structure. This oversight results in a model whereby short-ranged exchange-repulsion and long-ranged dispersion interactions are invariant to changes in the local atomic charge, leading to accuracy limitations for chemical reactions where significant atomic charge transfer can occur along the reaction coordinate. The present work presents a variational, charge-dependent exchange-repulsion and dispersion model, referred to as the charge-dependent exchange and dispersion (QXD) model, for hybrid QM/MM simulations. Analytic expressions for the energy and gradients are provided, as well as a description of the integration of the model into existing QM/MM frameworks, allowing QXD to replace traditional LJ interactions in simulations of reactive condensed phase systems. After initial validation against QM data, the method is demonstrated by capturing the solvation free energies of a series of small, chlorine-containing compounds that have varying charge on the chlorine atom. The model is further tested on the S{sub N}2 attack of a chloride anion on methylchloride. Results suggest that the QXD model, unlike the traditional LJ model, is able to simultaneously obtain accurate solvation free energies for a range of compounds while at the same time closely reproducing the experimental reaction free energy barrier. The QXD interaction model allows explicit coupling of atomic charge with many-body exchange and dispersion interactions that are related to atomic size and provides a more accurate and robust representation of non-electrostatic non-bonded QM

  8. Transport, charge exchange and loss of energetic heavy ions in the earth's radiation belts - Applicability and limitations of theory

    NASA Technical Reports Server (NTRS)

    Spjeldvik, W. N.

    1981-01-01

    Computer simulations of processes which control the relative abundances of ions in the trapping regions of geospace are compared with observations from discriminating ion detectors. Energy losses due to Coulomb collisions between ions and exospheric neutrals are considered, along with charge exchange losses and internal charge exchanges. The time evolution of energetic ion fluxes of equatorially mirroring ions under radial diffusion is modelled to include geomagnetic and geoelectric fluctutations. Limits to the validity of diffusion transport theory are discussed, and the simulation is noted to contain provisions for six ionic charge states and the source effect on the radiation belt oxygen ion distributions. Comparisons are made with ion flux data gathered on Explorer 45 and ISEE-1 spacecraft and results indicate that internal charge exchanges cause the radiation belt ion charge state to be independent of source charge rate characteristics, and relative charge state distribution is independent of the radially diffusive transport rate below the charge state redistribution zone.

  9. Cometary X-ray emission: theoretical cross sections following charge exchange by multiply charged ions of astrophysical interest

    SciTech Connect

    Otranto, S; Olson, R E; Beiersdorfer, P

    2007-02-13

    The CTMC method is used to calculate emission cross sections following charge exchange collisions involving highly charged ions of astrophysical interest and typical cometary targets. Comparison is made to experimental data obtained on the EBIT machine at Lawrence Livermore National Laboratory (LLNL) for O{sup 8+} projectiles impinging on different targets at a collision energy of 10 eV/amu. The theoretical cross sections are used together with ion abundances measured by the Advanced Composition Explorer as well as those obtained by a fitting procedure using laboratory emission cross sections in order to reproduce the x-ray spectrum of comet C/LINEAR S4 measured on July 14th 2001.

  10. Solar charged electric vehicle project analysis

    SciTech Connect

    Patten, J.A.; Bonnett, C.T.; Hartgen, D.T.; Barry, A.

    1996-11-01

    This paper addresses the cost of a solar charged electric vehicle and the energy and environmental savings derived from such a system. The analysis determines the energy and environmental savings attributed to the solar charging system in comparison to an EV charged from the utility grid. The solar charging provides an environmental benefit of $335--$694 per year in avoided pollution when compared to the costs for removing the pollution from the utility power plant. These pollutants include NO{sub x}, SO{sub 2} and PM{sub 10}. Pollution cost savings over the life of the vehicle and charging station (20 years) are nearly $14,000. In addition, solar charging provides an energy cost savings of about $312--$440/year which generates nearly $9,000 in additional cost savings over the life of the vehicle. The combined savings amounts to $23,000 over the life of the solar charged EV system. Therefore the initial investment of $20,000 for the solar charging system can be recaptured over the life of the system.

  11. Observations of solar wind ion charge exchange in the comet Halley coma

    NASA Technical Reports Server (NTRS)

    Fuselier, S. A.; Shelley, E. G.; Goldstein, B. E.; Goldstein, R.; Neugebauer, M.; Ip, W.-H.; Balsiger, H.; Reme, H.

    1991-01-01

    Giotto Ion Mass Spectrometer/High Energy Range Spectrometer (IMS/HERS) observations of solar wind ions show charge exchange effects and solar wind compositional changes in the coma of comet Halley. As the comet was approached, the He(++) to proton density ratio increased until about 1 hour before closest approach after which time it decreased. Abrupt increases in this ratio were also observed in the beginning and near the end of the so-called Mystery Region (8.6 - 5.5(10)(exp 5) km from the comet along the spacecraft trajectory). These abrupt increases in the density ratio were well correlated with enhanced fluxes of keV electrons as measured by the Giotto plasma electron spectrometer. The general increase and then decrease of the He(++) to proton density ratio is quantitatively consistent with a combination of the addition of protons of cometary origin to the plasma and loss of plasma through charge exchange of protons and He(++). In general agreement with the solar wind proton and He(++) observations, solar wind oxygen and carbon ions were observed to charge exchange from higher to lower charge states with decreasing distance to the comet. The more abrupt increases in the He(++) to proton and the He(++) to O(6+) density ratios in the mystery region require a change in the solar wind ion composition in this region while the correlation with energetic electrons indicates processes associated with the comet.

  12. Absolute Charge Exchange Cross Sections for ^3He^2+ Collisions with ^4He and H_2

    NASA Astrophysics Data System (ADS)

    Mawhorter, R. J.; Greenwood, J.; Smith, S. J.; Chutjian, A.

    2002-05-01

    The JPL charge exchange beam-line(J.B. Greenwood, et al., Phys. Rev A 63), 062707 (2001) was modified to increase the forward acceptance angle and enable the measurement of total charge-exchange cross sections for slow, light, highly-charged ion collisions with neutral targets(R. E. Olson and M. Kimura, J. Phys. B 15), 4231 (1982). Data are presented for single charge exchange cross sections for ^3He^2+ nuclei scattered by ^4He and H2 in the energy range 0.33-4.67 keV/amu. For both targets there is good agreement with Kusakabe, et al.(T. Kusakabe, et al., J. Phys. Soc. Japan 59), 1218 (1990). Angular collection is studied by a comparison with differential measurements(D. Bordenave-Montesquieu and R. Dagnac, J. Phys. B 27), 543 (1994), as well as with earlier JPL results(J.B. Greenwood, et al., Ap. J. 533), L175 (2000), ibid. 529, 605 (2000) using heavier projectiles and targets. This work was carried out at JPL/Caltech, and was supported through contract with NASA. RJM thanks the NRC for a Senior Associateship at JPL.

  13. Charge Exchange Cross Sections for Multiply-Charged Ions Colliding with Water

    SciTech Connect

    Otranto, S.; Olson, R. E.

    2009-03-10

    The classical trajectory Monte Carlo method is used to calculate total and state selective nl-electron capture cross sections for highly charged ions Z = 4-10, 14, 18 and 26 colliding with water. The initialization for the 1B1 and 3A1 orbitals of the water molecule is based on a Slater orbital expansion. The Z-dependence of the calculated total cross sections is in reasonable agreement with recent data. The K-shell x-ray emission cross sections are determined from the calculated state-selective electron capture results.

  14. Dynamics of the fully stripped ion-hydrogen atom charge exchange process in dense quantum plasmas

    SciTech Connect

    Zhang, Ling-yu; Wan, Jiang-feng; Zhao, Xiao-ying; Xiao, Guo-qing; Duan, Wen-shan; Qi, Xin; Yang, Lei

    2014-09-15

    The plasma screening effects of dense quantum plasmas on charge exchange processes of a fully stripped ion colliding with a hydrogen atom are studied by the classical trajectory Monte Carlo method. The inter-particle interactions are described by the exponential cosine-screened Coulomb potentials. It is found that in weak screening conditions, cross sections increase with the increase of the ionic charge Z. However, in strong screening conditions, the dependence of cross sections on the ionic charge is related to the incident particle energy. At high energies, cross sections show a linear increase with the increase of Z, whereas at low energies, cross sections for Z≥4 become approximately the same. The He{sup 2+} and C{sup 6+} impacting charge exchange cross sections in dense quantum plasmas are also compared with those in weakly coupled plasmas. The interactions are described by the static screened Coulomb potential. It is found that for both He{sup 2+} and C{sup 6+}, the oscillatory screening effects of dense quantum plasmas are almost negligible in weak screening conditions. However, in strong screening conditions, the oscillatory screening effects enhance the screening effects of dense quantum plasmas, and the enhancement becomes more and more significant with the increase of the screening parameter and the ionic charge.

  15. Spectral Diagnostics of Galactic and Stellar X-Ray Emission from Charge Exchange Recombination

    NASA Technical Reports Server (NTRS)

    Wargelin, B.

    2002-01-01

    The proposed research uses the electron beam ion trap at the Lawrence Livermore National Laboratory (LLNL) to study X-ray emission from charge-exchange recombination of highly charged ions with neutral gases. The resulting data fill a void in existing experimental and theoretical understanding of this atomic physics process, and are needed to explain all or part of the observed X-ray emission from the soft X-ray background, stellar winds, the Galactic Center, supernova ejecta, and photoionized nebulae. Progress made during the first year of the grant is described, as is work planned for the second year.

  16. ({sup 18}O,{sup 18}Ne) double charge-exchange with MAGNEX

    SciTech Connect

    Bondí, M.; Cappuzzello, F.; Nicolosi, D.; Tropea, S.; Agodi, C.; Carbone, D.; Cavallaro, M.; Cunsolo, A.; De Napoli, M.; Foti, A.

    2014-05-09

    An experimental study concerning Double Gamow-Teller (DGT) modes in ({sup 18}O,{sup 18}Ne) Double Charge-Exchange reactions has been very recently performed at INFN-LNS laboratory in Catania. The experiment was performed using a {sup 40}Ca solid target and a {sup 18}O Cyclotron beam at 270 MeV incident energy. Charged ejectiles produced in the reaction were momentum analyzed and identified by MAGNEX spectrometer at very forward angles. Preliminary results are presented in the present paper.

  17. Experimental evidence of charge exchange recombination of highly ionized iron and titanium in Princeton Large Torus

    SciTech Connect

    Suckewer, S.; Hinnov, E.; Bitter, M.; Hulse, R.; Post, D.

    1980-02-01

    The observed behavior of the emissivitives of boron-like FeXXIII, lithium-like FeXXIV and TiXX, and the helium-like FeXXV ions in the PLT tokamak during highpower neutral (H/sup 0/ or D/sup 0/) beam heating is described. A substantial lowering of the dominant ionization state in the center of the discharge while the electron temperature is rising, is attributed primarily to increased recombination rate of the ions through charge exchange with neutral hydrogen. This interpretation is supported by the different space and time behavior of the lithium-like annd boron-like ions of comparable ionization potentials, and by comparisons of neutral beam heating of the plasma with ion cyclotron resonance heating, which does not appreciably change the neutral hydrogen concentration. The observations are compared with approximate zero-dimensional model calculations, using experimental plasma conditions and estimated charge exchange rates.

  18. Tailoring of ion species composition in complex plasmas with charge exchange collisions

    NASA Astrophysics Data System (ADS)

    Ostrikov, K.

    2005-06-01

    A generic approach towards tailoring of ion species composition in reactive plasmas used for nanofabrication of various functional nanofilms and nanoassemblies, based on a simplified model of a parallel-plate rf discharge, is proposed. The model includes an idealized reactive plasma containing two neutral and two ionic species interacting via charge exchange collisions in the presence of a microdispersed solid component. It is shown that the number densities of the desired ionic species can be efficiently managed by adjusting the dilution of the working gas in a buffer gas, rates of electron impact ionization, losses of plasma species on the discharge walls, and surfaces of fine particles, charge exchange rates, and efficiency of three-body recombination processes in the plasma bulk. The results are relevant to the plasma-aided nanomanufacturing of ordered patterns of carbon nanotip and nanopyramid microemitters.

  19. Charge exchange contamination of CRIT-II barium CIV experiment. [critical ionization velocity in ionosphere

    NASA Technical Reports Server (NTRS)

    Swenson, G. R.; Mende, S. B.; Meyerott, R. E.; Rairden, R. L.

    1991-01-01

    Experiments have been recently performed which attempted to confirm critical ionization velocity (CIV) ionization by deploying chemicals at high velocity in the ionosphere. Specifically, the CRIT-II rocket performed a barium release in the ionosphere, where observations of Ba(+) resonant emissions following the release are believed to have resulted from the CIV process. Calculations are presented which suggest a significant fraction (if not all) of the Ba(+) observed likely resulted from charge exchange with the thermosphere ions and not through CIV processes. The results presented here are pertinent to other CIV experiments performed in the ionosphere. It is recommended that laboratory measurements should be made of the charge exchange cross section between O(+) and Ba as well as other metal vapors used in CIV experiments.

  20. Charge exchange and ionization cross sections of H{sup +}+H collision in dense quantum plasmas

    SciTech Connect

    Zhang, Ling-yu; Qi, Xin; Zhao, Xiao-ying; Meng, Dong-yuan; Xiao, Guo-qing; Duan, Wen-shan; Yang, Lei

    2013-11-15

    The plasma screening effects of dense quantum plasmas on H{sup +}+H charge exchange and ionization cross sections are calculated by the classical trajectory Monte Carlo method. For charge exchange cross sections, it is found that the screening effects reduce cross sections slightly in weak screening conditions. However, cross sections are reduced substantially in strong screening conditions. For ionization cross sections, with the increase of screening effects, cross sections for low energies increase more rapidly than those for high energies. When the screening effects are strong enough, it is found that ionization cross sections decrease with the increase of incident H{sup +} energy. In addition, the cross sections have been compared with those in weakly coupled plasmas. It is found that in weak screening conditions, plasma screening effects in the two plasmas are approximately the same, while in strong screening conditions, screening effects of dense quantum plasmas are stronger than those of weakly coupled plasmas.

  1. Competition between charge exchange and chemical reaction - The D2/+/ + H system

    NASA Technical Reports Server (NTRS)

    Preston, R. K.; Cross, R. J., Jr.

    1973-01-01

    Study of the special features of molecular charge exchange and its competition with chemical reaction in the case of the D2(+) + H system. The trajectory surface hopping (TSH) model proposed by Tully and Preston (1971) is used to study this competition for a number of reactions involving the above system. The diatomics-in-molecules zero-overlap approximation is used to calculate the three adiabatic surfaces - one triplet and two singlet - which are needed to describe this system. One of the significant results of this study is that the chemical reaction and charge exchange are strongly coupled. It is also found that the number of trajectories passing into the chemical regions of the three surfaces depends very strongly on the surface crossings.-

  2. Charge-exchange erosion studies of accelerator grids in ion thrusters

    NASA Technical Reports Server (NTRS)

    Peng, Xiaohang; Ruyten, Wilhelmus M.; Keefer, Dennis

    1993-01-01

    A particle simulation model is developed to study the charge-exchange grid erosion in ion thrusters for both ground-based and space-based operations. Because the neutral gas downstream from the accelerator grid is different for space and ground operation conditions, the charge-exchange erosion processes are also different. Based on an assumption of now electric potential hill downstream from the ion thruster, the calculations show that the accelerator grid erosion rate for space-based operating conditions should be significantly less than experimentally observed erosion rates from the ground-based tests conducted at NASA Lewis Research Center (LeRC) and NASA Jet Propulsion Laboratory (JPL). To resolve this erosion issue completely, we believe that it is necessary to accurately measure the entire electric potential field downstream from the thruster.

  3. Influence of resonant charge exchange on the viscosity of partially ionized plasma in a magnetic field

    SciTech Connect

    Zhdanov, V. M. Stepanenko, A. A.

    2013-12-15

    The influence of resonant charge exchange for ion-atom interaction on the viscosity of partially ionized plasma embedded in the magnetic field is investigated. The general system of equations used to derive the viscosity coefficients for an arbitrary plasma component in the 21-moment approximation of Grad’s method is presented. The expressions for the coefficients of total and partial viscosities of a multicomponent partially ionized plasma in the magnetic field are obtained. As an example, the coefficients of the parallel and transverse viscosities for the ionic and neutral components of the partially ionized hydrogen plasma are calculated. It is shown that the account for resonant charge exchange can lead to a substantial change of the parallel and transverse viscosity of the plasma components in the region of low degrees of ionization on the order of 0.1.

  4. Nuclear fragmentation and charge-exchange reactions induced by pions in the Δ -resonance region

    NASA Astrophysics Data System (ADS)

    Feng, Zhao-Qing

    2016-11-01

    The dynamics of the nuclear fragmentations and the charge exchange reactions in pion-nucleus collisions near the Δ (1232) resonance energies has been investigated within the Lanzhou quantum molecular dynamics transport model. An isospin-, momentum-, and density-dependent pion-nucleon potential is implemented in the model, which influences the pion dynamics, in particular the kinetic energy spectra, but weakly impacts the fragmentation mechanism. The absorption process in pion-nucleon collisions to form the Δ (1232) resonance dominates the heating mechanism of the target nucleus. The excitation energy transferred to the target nucleus increases with the pion kinetic energy and is similar for both π-- and π+-induced reactions. The magnitude of fragmentation of the target nucleus weakly depends on the pion energy. The isospin ratio in the pion double-charge exchange is influenced by the isospin ingredient of target nucleus.

  5. Inference of the ring current ion composition by means of charge exchange decay

    SciTech Connect

    Smith, P.H.; Bewtra, N.K.; Hoffman, R.A.

    1981-05-01

    The analysis of data from the Explorer 45 (S/sup 3/-A) electrostatic analyzer in the energy range 5--30 keV has provided some new results of the ring current ion composition. It has been well established that the storm time ring current has a decay time of several days, during which the particle fluxes decrease nearly monotonically. In the past, ring current studies have assumed or stated that hydrogen was the dominant ion in the earth's ring current. By analyzing the measured ion fluxes during the several day storm recovery period and assuming that beside hydrogen other ions were present and that the decays were exponential in nature, we were able to establish three separate lifetimes for the ions. These fitted decay lifetimes are in excellent agreement with the expected charge exchange decay lifetimes for H/sup +/, O/sup +/, and He/sup +/ in the energy and L value of the data. This inference technique thus establishes the presence of measureable and appreciable quantities of oxygen and helium ions as well as protons in the storm time ring current; we also find indicatons that He/sup + +/ may also be present under these same conditions. The existence of additional ions is not rules out by this technique.

  6. Energy-loss cross sections for inclusive charge-exchange reactions at intermediate energies

    NASA Technical Reports Server (NTRS)

    Cucinotta, Francis A.; Townsend, Lawrence W.; Dubey, Rajendra R.

    1993-01-01

    Charge-exchange reactions for scattering to the continuum are considered in a high-energy multiple scattering model. Calculations for (p,n) and (He-3,H-3) reactions are made and compared with experimental results for C-12, O-16, and Al-27 targets. Coherent effects are shown to lead to an important role for inelastic multiple scattering terms when light projectiles are considered.

  7. Charge Exchange and Ablation Rates of a Titanium Wire Plasma Corona

    SciTech Connect

    Terry, Robert E.

    2009-01-21

    Wire ablation rates are important features in any examination of precursors or transparent mode implosions of wire arrays. When ion temperatures in a Ti wire plasma corona exceed a few eV, the process of resonant charge exchange competes with elastic scattering. Ions pushed into the corona from an anode bias wire array can be expected to drive a fast neutral wind into the surrounding volume, while a cathode bias wire array would not show the strong neutral wind.

  8. Measurement of pion double charge exchange on carbon-13, carbon-14, magnesium-26, and iron-56

    SciTech Connect

    Seidl, P.A.

    1985-02-01

    Cross sections for the /sup 13,14/C,/sup 26/Mg,/sup 56/Fe(..pi../sup +/,..pi../sup -/)/sup 13,14/O,/sup 26/Si,/sup 56/Ni reactions were measured with the Energetic Pion Channel and Spectrometer at the Clinton P. Anderson Meson Physics Facility for 120 less than or equal to T/sub ..pi../ less than or equal to 292 MeV and 0 less than or equal to theta less than or equal to 50. The double isobaric analog states (DIAS) are of primary interest. In addition, cross sections for transitions to /sup 14/O(0/sup +/, 5.92 MeV), /sup 14/O(2/sup +/, 7.77 MeV), /sup 56/Ni(gs), /sup 13/O(gs), and /sup 13/O(4.21 MeV) are presented. The /sup 13/O(4.21 MeV) state is postulated to have J/sup ..pi../ = 1/2/sup -/. The data are compared to previously measured double-charge-exchange cross sections on other nuclei, and the systematics of double charge exchange on T greater than or equal to 1 target nuclei leading to the DIAS are studied. Near the ..delta../sub 33/ resonance, cross sections for the DIAS transitions are in disagreement with calculations in which the reaction is treated as sequential charge exchange through the free pion-nucleon amplitude, while for T/sub ..pi../ > 200 MeV the anomalous features of the 164 MeV data are not apparent. This is evidence for significant higher order contributions to the double-charge-exchange amplitude near the reasonable energy. Two theoretical approaches that include two nucleon processes are applied to the DIAS data. 64 references.

  9. Neutralizing positive charges at the surface of a protein lowers its rate of amide hydrogen exchange without altering its structure or increasing its thermostability.

    PubMed

    Shaw, Bryan F; Arthanari, Haribabu; Narovlyansky, Max; Durazo, Armando; Frueh, Dominique P; Pollastri, Michael P; Lee, Andrew; Bilgicer, Basar; Gygi, Steven P; Wagner, Gerhard; Whitesides, George M

    2010-12-15

    This paper combines two techniques--mass spectrometry and protein charge ladders--to examine the relationship between the surface charge and hydrophobicity of a representative globular protein (bovine carbonic anhydrase II; BCA II) and its rate of amide hydrogen-deuterium (H/D) exchange. Mass spectrometric analysis indicated that the sequential acetylation of surface lysine-ε-NH3(+) groups--a type of modification that increases the net negative charge and hydrophobicity of the surface of BCA II without affecting its secondary or tertiary structure--resulted in a linear decrease in the aggregate rate of amide H/D exchange at pD 7.4, 15 °C. According to analysis with MS, the acetylation of each additional lysine generated between 1.4 and 0.9 additional hydrogens that are protected from H/D exchange during the 2 h exchange experiment at 15 °C, pD 7.4. NMR spectroscopy demonstrated that none of the hydrogen atoms which became protected upon acetylation were located on the side chain of the acetylated lysine residues (i.e., lys-ε-NHCOCH3) but were instead located on amide NHCO moieties in the backbone. The decrease in rate of exchange associated with acetylation paralleled a decrease in thermostability: the most slowly exchanging rungs of the charge ladder were the least thermostable (as measured by differential scanning calorimetry). This observation--that faster rates of exchange are associated with slower rates of denaturation--is contrary to the usual assumptions in protein chemistry. The fact that the rates of H/D exchange were similar for perbutyrated BCA II (e.g., [lys-ε-NHCO(CH2)2CH3]18) and peracetylated BCA II (e.g., [lys-ε-NHCOCH3]18) suggests that the electrostatic charge is more important than the hydrophobicity of surface groups in determining the rate of H/D exchange. These electrostatic effects on the kinetics of H/D exchange could complicate (or aid) the interpretation of experiments in which H/D exchange methods are used to probe the structural

  10. Modeling the Hydrogen-Proton Charge-Exchange Process in Global Heliospheric Simulations

    NASA Astrophysics Data System (ADS)

    DeStefano, A.; Heerikhuisen, J.

    2015-12-01

    The environment surrounding our Solar System has a vast and dynamic structure. As the Sun rounds the Milky Way galaxy, interstellar dust and gas interact with the Sun's outflow of solar wind. A bubble of hot plasma forms around the Sun due to this interaction, called the heliosphere. In order to understand the structure of the heliosphere, observations and simulations must work in tandem. Within the past decade or so, 3D models of the heliosphere have been developed exhibiting non- symmmetric as well as predicting structures such as the hydrogen wall and the IBEX ribbon. In this poster we explore new ways to compute charge-exchange source terms. The charge-exchange process is the coupling mechanism between the MHD and kinetic theories. The understanding of this process is crucial in order to make valuable predictions. Energy dependant cross section terms will aid in settling non-linear affects coupling the intestellar and solar particles. Through these new ways of computing source terms, resolving fine structures in the plasma in the heliopause may be possible. In addition, other non-trivial situations, such as charge-exchange mediated shocks, may be addressed.

  11. Helium escape from the Earth's atmosphere - The charge exchange mechanism revisited

    NASA Technical Reports Server (NTRS)

    Lie-Svendsen, O.; Rees, M. H.; Stamnes, K.

    1992-01-01

    We have studied the escape of neutral helium from the terrestrial atmosphere through exothermic charge exchange reactions between He(+) ions and the major atmospheric constituents N2, O2 and O. Elastic collisions with the neutral background particles were treated quantitatively using a recently developed kinetic theory approach. An interhemispheric plasma transport model was employed to provide a global distribution of He(+) ions as a function of altitude, latitude and local solar time and for different levels of solar ionization. Combining these ion densities with neutral densities from an MSIS model and best estimates for the reaction rate coefficients of the charge exchange reactions, we computed the global distribution of the neutral He escape flux. The escape rates show large diurnal and latitudinal variations, while the global average does not vary by more than a factor of three over a solar cycle. We find that this escape mechanism is potentially important for the overall balance of helium in the Earth's atmosphere. However, more accurate values for the reaction rate coefficients of the charge exchange reactions are required to make a definitive assessment of its importance.

  12. Experiments with an ion-neutral hybrid trap: cold charge-exchange collisions

    NASA Astrophysics Data System (ADS)

    Smith, W. W.; Goodman, D. S.; Sivarajah, I.; Wells, J. E.; Banerjee, S.; Côté, R.; Michels, H. H.; Mongtomery, J. A.; Narducci, F. A.

    2014-01-01

    Due to their large trap depths (˜1 eV or 10,000 K), versatility, and ease of construction, Paul traps have important uses in high-resolution spectroscopy, plasma physics, and precision measurements of fundamental constants. An ion-neutral hybrid trap consisting of two separate but spatially concentric traps [a magneto-optic trap (MOT) for the neutral species and a mass-selective linear Paul trap for the ionic species] is an ideal apparatus for sympathetic cooling. However, over the past few years, hybrid traps have proven most useful in measuring elastic and charge-exchange rate constants of ion-neutral collisions over a wide temperature range from kilo-Kelvin to nano-Kelvin. We report some initially surprising results from a hybrid trap system in our laboratory where we have loaded the Paul trap with Ca+ ions in the presence of a Na MOT (localized dense gas of cold Na atoms). We find a strong loss of Ca+ ions with MOT exposure, attributed to an exothermic, non-resonant ion-neutral charge-exchange process with an activation barrier, which leads to the formation of Na+ ions. We propose a detailed mechanism for this process. We obtain an estimated measure of the rate constant for this charge exchange of ˜2 × 10-11 cm3/s, much less than the Langevin rate, which suggests that the Langevin assumption of unit efficiency in the reaction region is not correct in this case.

  13. The inconsistency between proton charge exchange and the observed ring current decay

    NASA Technical Reports Server (NTRS)

    Lyons, L. R.; Evans, D. S.

    1976-01-01

    The equatorial pitch-angle distributions of ring-current ions observed during a storm recovery phase at L values between 3 and 4 are compared with the pitch-angle distributions predicted by proton charge exchange with neutral hydrogen. Large disagreements are found, and three alternative explanations are explored. (1) A strong proton source acts to mask the effects of charge exchange. It is believed that the required strong continual source with a unique pitch-angle and energy dependence is unrealistic at these low L values. (2) Presently accepted neutral hydrogen density models have densities well over an order of magnitude too large for a storm recovery phase. No evidence is known to support the required large errors in the densities. (3) The ring current at particle energies not exceeding 50 keV was dominated by some ion species other than protons during the storm recovery phase. Such ions must have much longer lifetimes for charge exchange with hydrogen than do protons. This alternative is strongly favored, with He(+) being an attractive candidate.

  14. Coherent control of charge exchange in strong-field dissociation of LiF

    NASA Astrophysics Data System (ADS)

    Armstrong, Greg; Esry, Brett

    2016-05-01

    The alkali-metal-halides family of molecules are useful prototypes in the study of laser-assisted charge exchange. Typically these molecules possess a field-free crossing between the ionic and covalent diabatic Born-Oppenheimer potential curves, leading to Li+ + F- and Li + F in LiF. These channels are energetically well-separated from higher-lying potentials, and may be easily distinguished experimentally. Moreover, charge exchange involves non-adiabatic transitions between the ionic and covalent channels, thereby allowing the investigation of physics beyond the Born-Oppenheimer approximation. The focus of this work is to control the preference between ionic and covalent dissociative products. We solve the time-dependent Schrödinger equation for the nuclear motion in full dimensionality, and investigate a pump-probe scheme for charge-exchange control. The degree of control is investigated by calculating the kinetic-energy release spectrum as a function of pump-probe delay for the ionic and covalent fragments. This work is supported by the Chemical Sciences, Geosciences, and Biosciences Division, Office of Basic Energy Sciences, Office of Science, U.S. Department of Energy.

  15. Wavelength calibration of the charge exchange recombination spectroscopy system on the DIII-D tokamak

    SciTech Connect

    Gohil, P.; Burrell, K.H.; Groebner, R.J.; Holtrop, K.; Kaplan, K.H.; Monier-Garbet, P.

    1998-06-01

    A wavelength calibration of all the detectors on the charge exchange recombination spectroscopy (CER) system is performed after every plasma discharge on the DIII-D tokamak. This is done to insure that the rest wavelength position of the C VI 5290.5 {angstrom} charge exchange line on the detector is accurately known so that the Doppler shift of the spectral line emitted during the discharge can be used for measurements of plasma rotation. In addition, this calibration provides a check on the spectral dispersion needed to determine the ion temperature. The reference spectra for the calibration are Ne I lines created by neon capillary discharge lamps contained within specially designed, diffuse reflectors. The Ne I lines at 3520.4720 {angstrom}, 5274.0393 {angstrom}, 5280.0853 {angstrom}, 5298.1891 {angstrom}, and 5304.7580 {angstrom} are used in this work. The location of these lines on the linear detectors can be determined to an accuracy of 0.1 pixel, which corresponds to a plasma rotation accuracy of 1.2 km/s and 0.7 km/s for the central and edge rotation measurements, respectively. Use of oppositely directed views of the plasma at the same major radius have been used to verify that the nominal 5290.5 {angstrom} wavelength of the C VI (n = 8 {r_arrow} 7) multiplet is the correct wavelength for the line emitted owing to charge exchange excitation.

  16. Fast charge exchange ions in high power impulse magnetron sputtering of titanium as probes for the electrical potential

    NASA Astrophysics Data System (ADS)

    Breilmann, W.; Maszl, C.; von Keudell, A.

    2017-03-01

    High power impulse magnetron sputtering (HiPIMS) plasmas exhibit a high ionization fraction of the sputtered material and ions with high kinetic energies, which produce thin films with superior quality. These ion energy distribution functions (IEDF) contain energetic peaks, which are believed to be linked to a distinct electrical potential hump {{Δ }}{{{Φ }}}{{ionization}{{zone}}} inside rotating localized ionization zones, so called spokes, at target power densities above 1 kW cm‑2. Any direct measurement of this electrical potential structure is, however, very difficult due to the dynamic nature of the spokes and the very high local power density, which hampers the use of conventional emissive probes. Instead, we use a careful analysis of the IEDFs for singly and doubly charged titanium ions from a HiPIMS plasma at varying target power density. The energy peaks in the IEDFs measured at the substrate depend on the point of ionization and any charge exchange collisions on the path between ionization and impact at the substrate. Thereby, the IEDFs contain a convoluted information about the electrical potential structure inside the plasma. The analysis of these IEDFs reveal that higher ionization states originate at high target power densities from the central part of the plasma spoke, whereas singly charged ions originate from the perimeter of the plasma spoke. Consequently, we observe different absolute ion energies with the energy of Ti2+ being slightly higher than two times the energy of Ti+. Additional peaks are observed in the IEDFs of Ti+ originating from charge exchange reactions from Ti2+ and Ti3+ with titanium neutrals. Based on this analysis of the IEDFs, the structure of the electrical potential inside a spoke is inferred yielding {{Δ }}{{{Φ }}}{{ionization}{{zone}}} = 25 V above the plasma potential, irrespective of target power density.

  17. Design and operation of the pellet charge exchange diagnostic for measurement of energetic confined alphas and tritons on TFTR

    SciTech Connect

    Medley, S.S.; Duong, H.H.; Fisher, R.K.

    1996-05-01

    Radially-resolved energy and density distributions of the energetic confined alpha particles in D-T experiments on TFTR are being measured by active neutral particle analysis using low-Z impurity pellet injection. When injected into a high temperature plasma, an impurity pellet (e.g. Lithium or Boron) rapidly ablates forming an elongated cloud which is aligned with the magnetic field and moves with the pellet. This ablation cloud provides a dense target with which the alpha particles produced in D-T fusion reactions can charge exchange. A small fraction of the alpha particles incident on the pellet ablation cloud will be converted to helium neutrals whose energy is essentially unchanged by the charge transfer process. By measuring the resultant helium neutrals escaping from the plasma using a mass and energy resolving charge exchange analyzer, this technique offers a direct measurement of the energy distribution of the incident high-energy alpha particles. Other energetic ion species can be detected as well, such as tritons generated in D-D plasmas and H or He{sup 3} RF-driven minority ion tails. The diagnostic technique and its application on TFTR are described in detail.

  18. Ultrafast spin exchange-coupling torque via photo-excited charge-transfer processes

    SciTech Connect

    Ma, X.; Fang, F.; Li, Q.; Zhu, J.; Yang, Y.; Wu, Y. Z.; Zhao, H. B.; Lüpke, G.

    2015-10-28

    In this study, optical control of spin is of central importance in the research of ultrafast spintronic devices utilizing spin dynamics at short time scales. Recently developed optical approaches such as ultrafast demagnetization, spin-transfer and spin-orbit torques open new pathways to manipulate spin through its interaction with photon, orbit, charge or phonon. However, these processes are limited by either the long thermal recovery time or the low-temperature requirement. Here we experimentally demonstrate ultrafast coherent spin precession via optical charge-transfer processes in the exchange-coupled Fe/CoO system at room temperature. The efficiency of spin precession excitation is significantly higher and the recovery time of the exchange-coupling torque is much shorter than for the demagnetization procedure, which is desirable for fast switching. The exchange coupling is a key issue in spin valves and tunnelling junctions, and hence our findings will help promote the development of exchange-coupled device concepts for ultrafast coherent spin manipulation.

  19. Ultrafast spin exchange-coupling torque via photo-excited charge-transfer processes

    DOE PAGES

    Ma, X.; Fang, F.; Li, Q.; ...

    2015-10-28

    In this study, optical control of spin is of central importance in the research of ultrafast spintronic devices utilizing spin dynamics at short time scales. Recently developed optical approaches such as ultrafast demagnetization, spin-transfer and spin-orbit torques open new pathways to manipulate spin through its interaction with photon, orbit, charge or phonon. However, these processes are limited by either the long thermal recovery time or the low-temperature requirement. Here we experimentally demonstrate ultrafast coherent spin precession via optical charge-transfer processes in the exchange-coupled Fe/CoO system at room temperature. The efficiency of spin precession excitation is significantly higher and the recoverymore » time of the exchange-coupling torque is much shorter than for the demagnetization procedure, which is desirable for fast switching. The exchange coupling is a key issue in spin valves and tunnelling junctions, and hence our findings will help promote the development of exchange-coupled device concepts for ultrafast coherent spin manipulation.« less

  20. Ultrafast spin exchange-coupling torque via photo-excited charge-transfer processes

    PubMed Central

    Ma, X.; Fang, F.; Li, Q.; Zhu, J.; Yang, Y.; Wu, Y. Z.; Zhao, H. B.; Lüpke, G.

    2015-01-01

    Optical control of spin is of central importance in the research of ultrafast spintronic devices utilizing spin dynamics at short time scales. Recently developed optical approaches such as ultrafast demagnetization, spin-transfer and spin-orbit torques open new pathways to manipulate spin through its interaction with photon, orbit, charge or phonon. However, these processes are limited by either the long thermal recovery time or the low-temperature requirement. Here we experimentally demonstrate ultrafast coherent spin precession via optical charge-transfer processes in the exchange-coupled Fe/CoO system at room temperature. The efficiency of spin precession excitation is significantly higher and the recovery time of the exchange-coupling torque is much shorter than for the demagnetization procedure, which is desirable for fast switching. The exchange coupling is a key issue in spin valves and tunnelling junctions, and hence our findings will help promote the development of exchange-coupled device concepts for ultrafast coherent spin manipulation. PMID:26508587

  1. Determination of 16O and 18O sensitivity factors and charge-exchange processes in low-energy ion scattering

    NASA Astrophysics Data System (ADS)

    Téllez, H.; Chater, R. J.; Fearn, S.; Symianakis, E.; Brongersma, H. H.; Kilner, J. A.

    2012-10-01

    Quantitative analysis in low-energy ion scattering (LEIS) requires an understanding of the charge-exchange processes to estimate the elemental sensitivity factors. In this work, the neutralization of He+ scattered by 18O-exchanged silica at energies between 0.6 and 7 keV was studied. The process is dominated by Auger neutralization for Ei < 0.8 keV. An additional mechanism starts above the reionization threshold. This collision-induced neutralization becomes the dominant mechanism for Ei > 2 keV. The ion fractions P+ were determined for Si and O using the characteristic velocity method to quantify the surface density. The 18O/16O sensitivity ratio indicates an 18% higher sensitivity for the heavier O isotope.

  2. Modeling of protein-anion exchange resin interaction for the human growth hormone charge variants.

    PubMed

    Lapelosa, Mauro; Patapoff, Thomas W; Zarraga, Isidro E

    2015-12-01

    Modeling ion exchange chromatography (IEC) behavior has generated significant interest because of the wide use of IEC as an analytical technique as well as a preparative protein purification process; indeed there is a need for better understanding of what drives the unique behavior of protein charge variants. We hypothesize that a complex protein molecule, which contains both hydrophobic and charged moieties, would interact strongly with an in silico designed resin through charged electrostatic patches on the surface of the protein. In the present work, variants of recombinant human growth hormone that mimic naturally-occurring deamidation products were produced and characterized in silico. The study included these four variants: rhGH, N149D, N152D, and N149D/N152D. Poisson-Boltzmann calculations were used to determine surface electrostatic potential. Metropolis Monte Carlo simulations were carried out with the resulting variants to simulate IEC systems, examining the free energy of the interaction of the protein with an in silico anion exchange column represented by polylysine polypeptide. The results show that the charge variants have different average binding energies and the free energy of interaction can be used to predict the retention time for the different variants.

  3. Charge exchange of medium energy H and He ions emerging from solid surfaces

    NASA Astrophysics Data System (ADS)

    Kitsudo, Y.; Shibuya, K.; Nishimura, T.; Hoshino, Y.; Vickridge, I.; Kido, Y.

    2009-02-01

    Charge exchange of medium energy H and He ions emerging from clean solid surfaces is studied extensively using a toroidal electrostatic analyzer with an excellent energy resolution. The charge distributions of He ions scattered from sub-monolayers near a surface are non-equilibrated, resulting in a surface peak even for poly-crystal solids. By solving simultaneous rate equations numerically, we derive electron capture and loss cross sections for Ni and Au surfaces. Based on a free electron gas model, non-equilibrated He+ fractions dependent on emerging angle reveals uniform electronic surfaces for metals and corrugated surfaces for Si and graphite with covalent bonds. It is also found that equilibrium charge fractions of H+ are independent of surface materials (Z2) and in contrast equilibrium He+ fractions depend pronouncedly on Z2. The data obtained are compared with semi-empirical formulas.

  4. Observed Limits on Charge Exchange Contributions to the Diffuse X-Ray Background

    NASA Technical Reports Server (NTRS)

    Crowder, S. G.; Barger, K. A.; Brandl, D. E.; Eckart, M. E.; Galeazzi, M.; Kelley, R. L.; Kilbourne, C. A.; McCammon, D.; Pfendner, C. G.; Porter, F. S.; Rocks, L.; Szymkowiak, A. E.; Teplin, I. M.

    2012-01-01

    We present a high-resolution spectrum of the diffuse X-ray background from 0.1 to 1 keV for an approximately 1 sr region of the sky centered at l = 90 degrees b = +60 degrees using a 36 pixel array of microcalorimeters flown on a sounding rocket. With an energy resolution of 11 eV FWHM below 1 keV, the spectrum s observed line ratios help separate charge exchange contributions originating within the heliosphere from thermal emission of hot gas in the interstellar medium. The X-ray sensitivity below 1 keV was reduced by about a factor of four from contamination that occurred early in the flight, limiting the significance of the results. The observed centroid of helium-like O VII is 568 (sup +2 (sub -3) eV at 90% confidence. Since the centroid expected for thermal emission is 568.4 eV and for charge exchange is 564.2 eV, thermal emission appears to dominate for this line complex. The dominance of thermal emission is consistent with much of the high-latitude O VII emission originating in 2-3 x 10(exp 6) K gas in the Galactic halo. On the other hand, the observed ratio of C VI Lygamma to Lyalpha is 0.3 plus or minus 0.2. The expected ratios are 0.04 for thermal emission and 0.24 for charge exchange, indicating that charge exchange must contribute strongly to this line and therefore potentially to the rest of the ROSAT R12 band usually associated with 10(sup 6) K emission from the Local Hot Bubble. The limited statistics of this experiment and systematic uncertainties due to the contamination require only greater than 32% thermal emission for O VII and greater than 20% from charge exchange for C VI at the 90% confidence level. An experimental gold coating on the silicon substrate of the array greatly reduced extraneous signals induced on nearby pixels from cosmic rays passing through the substrate, reducing the triggered event rate by a factor of 15 from a previous flight of the instrument.

  5. Charge-displacement analysis for excited states

    SciTech Connect

    Ronca, Enrico Tarantelli, Francesco; Pastore, Mariachiara Belpassi, Leonardo; De Angelis, Filippo; Angeli, Celestino; Cimiraglia, Renzo

    2014-02-07

    We extend the Charge-Displacement (CD) analysis, already successfully employed to describe the nature of intermolecular interactions [L. Belpassi et al., J. Am. Chem. Soc. 132, 13046 (2010)] and various types of controversial chemical bonds [L. Belpassi et al., J. Am. Chem. Soc. 130, 1048 (2008); N. Salvi et al., Chem. Eur. J. 16, 7231 (2010)], to study the charge fluxes accompanying electron excitations, and in particular the all-important charge-transfer (CT) phenomena. We demonstrate the usefulness of the new approach through applications to exemplary excitations in a series of molecules, encompassing various typical situations from valence, to Rydberg, to CT excitations. The CD functions defined along various spatial directions provide a detailed and insightful quantitative picture of the electron displacements taking place.

  6. Toward a predictive understanding of water and charge transport in proton exchange membranes.

    PubMed

    Selvan, Myvizhi Esai; Calvo-Muñoz, Elisa; Keffer, David J

    2011-03-31

    An analytical model for water and charge transport in highly acidic and highly confined systems such as proton exchange membranes of fuel cells is developed and compared to available experimental data. The model is based on observations from both experiment and multiscale simulation. The model accounts for three factors in the system including acidity, confinement, and connectivity. This model has its basis in the molecular-level mechanisms of water transport but has been coarse-grained to the extent that it can be expressed in an analytical form. The model uses the concentration of H(3)O(+) ion to characterize acidity, interfacial surface area per water molecule to characterize confinement, and percolation theory to describe connectivity. Several important results are presented. First, an integrated multiscale simulation approach including both molecular dynamics simulation and confined random walk theory is capable of quantitatively reproducing experimentally measured self-diffusivities of water in the perfluorinated sulfonic acid proton exchange membrane material, Nafion. The simulations, across a range of hydration conditions from minimally hydrated to fully saturated, have an average error for the self-diffusivity of water of 16% relative to experiment. Second, accounting for three factors-acidity, confinement, and connectivity-is necessary and sufficient to understand the self-diffusivity of water in proton exchange membranes. Third, an analytical model based on percolation theory is capable of quantitatively reproducing experimentally measured self-diffusivities of both water and charge in Nafion across a full range of hydration.

  7. Development of Laboratory Experimental System to Clarify Solar Wind Charge Exchange Mechanism with TES Microcalorimeter

    NASA Astrophysics Data System (ADS)

    Enoki, T.; Ishisaki, Y.; Akamatsu, H.; Ezoe, Y.; Ohashi, T.; Kanda, T.; Ishida, T.; Tanuma, H.; Ohashi, H.; Shinozaki, K.; Mitsuda, K.

    2012-06-01

    Significant fraction of the cosmic diffuse soft X-ray emission (0.1-1 keV) is caused by the Solar Wind Charge eXchange (SWCX) process between the solar wind ion (C q+, N q+, O q+ etc.) and the interplanetary neutral matter. It is difficult to identify spectral features of SWCX with the spectral resolution of existing X-ray astronomy satellites. We are developing a laboratory experimental system with transition edge sensor (TES) X-ray microcalorimeters, in order to clarify the SWCX mechanism. This experiment is designed to measure Charge eXchange (CX) X-rays using Electron Cyclotron Resonance Ion Source (ECRIS) that generates multi-charged ions. Emission lines (OVIII: 2p→1s; 654 eV) by CX between O8+ and neutral He atom is aimed to be measured with energy resolution better than 10 eV. The TES microcalorimeter is cooled by a double-stage adiabatic demagnetization refrigerator (DADR), however, our TES microcalorimeter are not working potentially due to magnetic field contamination. This paper reports our experimental system, present results, and future prospects.

  8. Charge exchange collisions of slow C6 + with atomic and molecular H

    NASA Astrophysics Data System (ADS)

    Saha, Bidhan C.; Guevara, Nicolais L.; Sabin, John R.; Deumens, Erik; Öhrn, Yngve

    2016-04-01

    Charge exchange in collisions of C6+ ions with H and H2 is investigated theoretically at projectile energies 0.1 < E < 10 keV/amu, using electron nuclear dynamics (END) - a semi-classical approximation which not only includes electron translation factors for avoiding spurious couplings but also employs full dynamical trajectories to treat nuclear motions. Both the total and partial cross sections are reported for the collision of C6+ ions with atomic and molecular hydrogen. A comparison with other theoretical and experimental results shows, in general good agreement except at very low energy, considered here. For H2, the one- and two-electron charge exchange cross sections are calculated and compared with other theoretical and experimental results. Small but non-negligible isotope effects are found at the lowest energy studied in the charge transfer of C6+ with H. In low energy region, it is observed that H2 has larger isotope effects than H atom due to the polarizability effect which is larger than the mass effect.

  9. A comprehensive model of ion diffusion and charge exchange in the cold Io torus

    NASA Technical Reports Server (NTRS)

    Barbosa, D. D.; Moreno, M. A.

    1988-01-01

    A comprehensive analytic model of radial diffusion in the cold Io torus is developed. The model involves a generalized molecular cloud theory of SO2 and its dissociation fragments SO, O2, S, and O, which are formed at a relatively large rate by solar UV photodissociation of SO2. The key component of the new theory is SO, which can react with S(+) through a near-resonant charge exchange process that is exothermic. This provides a mechanism for the rapid depletion of singly ionized sulfur in the cold torus and can account for the large decrease in the total flux tube content inward of Io's orbit. The model is used to demonstrate quantitatively the effects of radial diffusion in a charge exchange environment that acts as a combined source and sink for ions in various charge states. A detailed quantitative explanation for the O(2+) component of the cold torus is given, and insight is derived into the workings of the so-called plasma 'ribbon'.

  10. Charge exchange fast neutral measurement with natural diamond detectors in neon plasma on LHD

    NASA Astrophysics Data System (ADS)

    Saida, T.; Sasao, M.; Isobe, M.; Krasilnikov, A. V.

    2003-03-01

    Charge exchange (CX) fast neutral spectra produced by ion cyclotron resonance frequency hydrogen minority heating in neon and helium majority plasmas sustained by neutral beam injection were measured with perpendicular Natural Diamond Detectors during the fifth campaign in 2002 on large helical devices (LHDs). It was observed that there were differences between fast neutral spectra shapes in neon plasma and those in helium of the same discharge condition with similar plasma parameters. Dominant CX processes in neon and helium plasmas were studied for ionization components from outside of the last closed flux surface. High-energy proton spectra were obtained by taking account of each charge state distribution and responsible charge exchange cross sections. The high-energy proton tail formations in both plasmas were similar for the same heating regime. The relaxation time tendencies of the effective temperatures of a high-energy proton have also shown no differences, indicating that the acceleration and confinement of energetic ions in LHDs are similar in neon and helium plasmas.

  11. Charge-exchange plasma environment for an ion drive spacecraft. [a model for describing mercury ion engines and its effect on spacecraft subsystems

    NASA Technical Reports Server (NTRS)

    Kaufman, H. R.; Carruth, M. R., Jr.

    1979-01-01

    The charge exchange plasma environment around a spacecraft that uses mercury ion thrusters for propulsion is described. The interactions between the plasma environment and the spacecraft are determined and a model which describes the propagation of the mercury charge exchange plasma is discussed. The model is extended to describe the flow of the molybdenum component of the charge exchange plasma. The uncertainties in the models for various conditions are discussed and current drain to the solar array, charge exchange plasma material deposition, and the effects of space plasma on the charge exchange plasma propagation are addressed.

  12. Spectral modeling of the charge-exchange X-ray emission from M82

    SciTech Connect

    Zhang, Shuinai; Ji, Li; Zhou, Xin; Wang, Q. Daniel; Smith, Randall K.; Foster, Adam R.

    2014-10-10

    It has been proposed that the charge-exchange (CX) process at the interface between hot and cool interstellar gases could contribute significantly to the observed soft X-ray emission in star-forming galaxies. We analyze the XMM-Newton/reflection grating spectrometer (RGS) spectrum of M82 using a newly developed CX model combined with a single-temperature thermal plasma to characterize the volume-filling hot gas. The CX process is largely responsible for not only the strongly enhanced forbidden lines of the Kα triplets of various He-like ions but also good fractions of the Lyα transitions of C VI (∼87%), O VIII, and N VII (≳50%) as well. In total about a quarter of the X-ray flux in the RGS 6-30 Å band originates in the CX. We infer an ion incident rate of 3 × 10{sup 51} s{sup –1} undergoing CX at the hot and cool gas interface and an effective area of the interface of ∼2 × 10{sup 45} cm{sup 2} that is one order of magnitude larger than the cross section of the global biconic outflow. With the CX contribution accounted for, the best-fit temperature of the hot gas is 0.6 keV, and the metal abundances are approximately solar. We further show that the same CX/thermal plasma model also gives an excellent description of the EPIC-pn spectrum of the outflow Cap, projected at 11.6 kpc away from the galactic disk of M82. This analysis demonstrates that the CX is potentially an important contributor to the X-ray emission from starburst galaxies and also an invaluable tool to probe the interface astrophysics.

  13. Possible Charge-Exchange X-Ray Emission in the Cygnus Loop Detected with Suzaku

    NASA Technical Reports Server (NTRS)

    Katsuda, Satoru; Tsunemi, Hiroshi; Mori, Koji; Uchida, Hiroyuki; Kosugi, Hiroko; Kimura, Masashi; Nakajima, Hiroshi; Takakura, Satoru; Petre, Robert; Hewitt. John W.; Yamaguchi, Hiroya

    2011-01-01

    X-ray spectroscopic measurements of the Cygnus Loop supernova remnant indicate that metal abundances throughout most of the remnant s rim are depleted to approx.0.2 times the solar value. However, recent X-ray studies have revealed in some narrow regions along the outermost rim anomalously "enhanced" abundances (up to approx. 1 solar). The reason for these anomalous abundances is not understood. Here, we examine X-ray spectra in annular sectors covering nearly the entire rim of the Cygnus Loop using Suzaku (21 pointings) and XMM-Newton (1 pointing). We find that spectra in the "enhanced" abundance regions commonly show a strong emission feature at approx.0.7 keV. This feature is likely a complex of He-like O K(gamma + delta + epsilon), although other possibilities cannot be fully excluded. The intensity of this emission relative to He-like O K(alpha) appears to be too high to be explained as thermal emission. This fact, as well as the spatial concentration of the anomalous abundances in the outermost rim, leads us to propose an origin from charge-exchange processes between neutrals and H-like O. We show that the presence of charge-exchange emission could lead to the inference of apparently "enhanced" metal abundances using pure thermal emission models. Accounting for charge-exchange emission, the actual abundances could be uniformly low throughout the rim. The overall abundance depletion remains an open question. Subject headings: ISM: abundances ISM: individual objects (Cygnus Loop) ISM: supernova remnants X-rays: ISM atomic processes

  14. Correlation between charge transfer and exchange coupling in carbon-based magnetic materials

    SciTech Connect

    Nguyen, Anh Tuan; Nguyen, Van Thanh; Nguyen, Huy Sinh; Pham, Thi Tuan Anh; Do, Viet Thang; Dam, Hieu Chi

    2015-10-15

    Several forms of carbon-based magnetic materials, i.e. single radicals, radical dimers, and alternating stacks of radicals and diamagnetic molecules, have been investigated using density-functional theory with dispersion correction and full geometry optimization. Our calculated results demonstrate that the C{sub 31}H{sub 15} (R{sub 4}) radical has a spin of ½. However, in its [R{sub 4}]{sub 2} dimer structure, the net spin becomes zero due to antiferromagnetic spin-exchange between radicals. To avoid antiferromagnetic spin-exchange of identical face-to-face radicals, eight alternating stacks, R{sub 4}/D{sub 2m}/R{sub 4} (with m = 3-10), were designed. Our calculated results show that charge transfer (Δn) between R{sub 4} radicals and the diamagnetic molecule D{sub 2m} occurs with a mechanism of spin exchange (J) in stacks. The more electrons that transfer from R{sub 4} to D{sub 2m}, the stronger the ferromagnetic spin-exchange in stacks. In addition, our calculated results show that Δn can be tailored by adjusting the electron affinity (E{sub a}) of D{sub 2m}. The correlation between Δn, E{sub a}, m, and J is discussed. These results give some hints for the design of new ferromagnetic carbon-based materials.

  15. Neutrino nuclear responses for double beta decays and astro neutrinos by charge exchange reactions

    NASA Astrophysics Data System (ADS)

    Ejiri, Hiroyasu

    2014-09-01

    Neutrino nuclear responses are crucial for neutrino studies in nuclei. Charge exchange reactions (CER) are shown to be used to study charged current neutrino nuclear responses associated with double beta decays(DBD)and astro neutrino interactions. CERs to be used are high energy-resolution (He3 ,t) reactions at RCNP, photonuclear reactions via IAR at NewSUBARU and muon capture reactions at MUSIC RCNP and MLF J-PARC. The Gamow Teller (GT) strengths studied by CERs reproduce the observed 2 neutrino DBD matrix elements. The GT and spin dipole (SD) matrix elements are found to be reduced much due to the nucleon spin isospin correlations and the non-nucleonic (delta isobar) nuclear medium effects. Impacts of the reductions on the DBD matrix elements and astro neutrino interactions are discussed.

  16. Oxygen ionization rates at Mars and Venus - Relative contributions of impact ionization and charge exchange

    NASA Technical Reports Server (NTRS)

    Zhang, M. H. G.; Luhmann, J. G.; Nagy, A. F.; Spreiter, J. R.; Stahara, S. S.

    1993-01-01

    Oxygen ion production rates above the ionopauses of Venus and Mars are calculated for photoionization, charge exchange, and solar wind electron impact ionization processes. The latter two require the use of the Spreiter and Stahara (1980) gas dynamic model to estimate magnetosheath velocities, densities, and temperatures. The results indicate that impact ionization is the dominant mechanism for the production of O(+) ions at both Venus and Mars. This finding might explain both the high ion escape rates measured by Phobos 2 and the greater mass loading rate inferred for Venus from the bow shock positions.

  17. Fast time resolution charge-exchange measurements during the fishbone instability in the poloidal divertor experiment

    SciTech Connect

    Beiersdorfer, P.; Kaita, R.; Goldston, R.J.

    1984-01-01

    Measurements of fast ion losses due to the fishbone instability during high ..beta../sub T/q neutral beam heated discharges in the Poloidal Divertor Experiment have been made using two new vertical-viewing charge-exchange analyzers. The measurements show that the instability has an n=1 toroidal mode number, and that it ejects beam ions in a toroidally rotating beacon directed outward along a major radius. Observations of ejected ions with energies up to twice the beam injection energy at R approx. = R/sub 0/ + a indicate the presence of a non-..mu..-conserving acceleration mechanism.

  18. Neutron skin thickness of {sup 90}Zr determined by charge exchange reactions

    SciTech Connect

    Yako, K.; Sakai, H.; Sagawa, H.

    2006-11-15

    Charge exchange spin-dipole (SD) excitations of {sup 90}Zr are studied by the {sup 90}Zr(p,n) and {sup 90}Zr(n,p) reactions at 300 MeV. A multipole decomposition technique is employed to obtain the SD strength distributions in the cross-section spectra. For the first time, a model-independent SD sum rule value is obtained: 148{+-}12 fm{sup 2}. The neutron skin thickness of {sup 90}Zr is determined to be 0.07{+-}0.04 fm from the SD sum rule value.

  19. Laser interferometric measurement of ion electrode shape and charge exchange erosion

    NASA Technical Reports Server (NTRS)

    Macrae, Gregory S.; Mercer, Carolyn R.

    1991-01-01

    A projected fringe profilometry system was applied to surface contour measurements of an accelerator electrode from an ion thrustor. The system permitted noncontact, nondestructive evaluation of the fine and gross structure of the electrode. A 3-D surface map of a dished electrode was generated without altering the electrode surface. The same system was used to examine charge exchange erosion pits near the periphery of the electrode to determine the depth, location, and volume of material lost. This electro-optical measurement system allowed rapid, nondestructive, digital data acquisition coupled with automated computer data processing. In addition, variable sensitivity allowed both coarse and fine measurements of objects having various surface finishes.

  20. Simulations of ion velocity distribution functions taking into account both elastic and charge exchange collisions

    NASA Astrophysics Data System (ADS)

    Wang, Huihui; Sukhomlinov, Vladimir S.; Kaganovich, Igor D.; Mustafaev, Alexander S.

    2017-02-01

    Based on accurate representation of the He+-He angular differential scattering cross sections consisting of both elastic and charge exchange collisions, we performed detailed numerical simulations of the ion velocity distribution functions (IVDF) by Monte Carlo collision method (MCC). The results of simulations are validated by comparison with the experimental data of the ion mobility and the transverse diffusion. The IVDF simulation study shows that due to significant effect of scattering in elastic collisions IVDF cannot be separated into product of two independent IVDFs in the transverse and parallel to the electric field directions.

  1. X-Ray Emission Cross Sections following Charge Exchange by Multiply-Charged Ions of Astrophysical Interest

    SciTech Connect

    Otranto, S; Olson, R E; Beiersdorfer, P

    2005-09-19

    State selective nl-electron capture cross sections are presented for highly charged ions with Z = 6-10 colliding with atoms and molecules. The energy range investigated was from 1 eV/amu (v = 0.006 a.u.) to 100 keV/amu (v =2.0 a.u.). The energy dependence of the l-level populations is investigated. The K-shell x-ray emission cross sections are determined by using the calculated state-selective electron capture results as input and then applying hydrogenic branching and cascading values for the photon emission. A major shift in the line emission from being almost solely Lyman-{alpha} transitions at the highest collisions energies to strong high-n to 1s transitions at the lowest energies is observed. The calculated cross sections are in reasonable accord with measurements made by Greenwood et al, Phys. Rev. A 63, 062707 (2001), using O{sup 8+} and Ne{sup 10+} on various targets at 3 keV/amu. The calculations are also in accord with x-ray emission cross section data obtained on the EBIT machine at LLNL where O{sup 8+} and Ne{sup 10+} high resolution measurements were made at a temperature of 10 eV/amu for a series of targets with varying ionization potentials. The Ne{sup 10+} data clearly shows the contribution from multiple capture followed by Auger autoionization in the line emission spectra. Our calculated line emission cross sections are used to provide an ab initio determination of the soft x-ray spectrum of comet C/Linear 1999 S4 that was observed on the Chandra X-ray Observatory. The calculations show that the spectrum is due to charge exchange of the neutral gases in the comet's coma with the ions of the slow solar wind.

  2. New Measurements of the Solar Wind Charge Exchange, Local Bubble, and Halo 3/4 keV Emission from XMM-Newton and Suzaku Shadowing Observations

    NASA Astrophysics Data System (ADS)

    Shelton, Robin L.; Henley, David

    2016-06-01

    We report on the analyses of XMM-Newton and/or Suzaku observations of 6 on-cloud and off-cloud shadowing pairs. This study provides the first analysis of two of these pairs and the first uniform analysis of the larger dataset. For every shadowing pair, we determined the foreground and halo components by simultaneously fitting the spectra from both members of the pair with a model that included a foreground component and an absorbed background component. In the past, foreground X-ray emission was thought to come from the Local Bubble of hot gas surrounding the solar neighborhood and so thermal spectral models were used. Now that solar wind charge exchange is recognized as a source of foreground X-ray photons, it is appropriate to consider charge exchange models as well. For this reason, we repeated the analyses using one of 3 possible foreground models: a charge exchange spectral model whose line ratios come from atomic physics calculations and are presented in Cumbee et al. (2014), a charge exchange model based on the AtomDB Charge Exchange code, or a thermal spectrum. The analyses of the larger dataset enabled us to place an upper limit on the Local Bubble's O VII contribution, provide measurements of the local and halo contributions in the 0.4 to 1.0 keV band, comment on the abilities of the various solar wind models to fit the data, and comment on the sensitivity of the fit parameters to the choice of foreground model, metal abundance tables, and X-ray observatory.

  3. Metal-ion-specific screening of charge effects in protein amide H/D exchange and the Hofmeister series.

    PubMed

    Abdolvahabi, Alireza; Gober, Jennifer L; Mowery, Richard A; Shi, Yunhua; Shaw, Bryan F

    2014-10-21

    In this study, protein charge ladders and mass spectrometry were used to quantify how metal cations in the Hofmeister series (Na(+), K(+), Li(+), Mg(2+), and Ca(2+)) permute the effects of lysine acetylation on the rate of amide H/D exchange in a representative protein (myoglobin, Mb). The successive acetylation of up to 18 Lys-ε-NH3(+) groups in Mb caused a linear decrease in its global rate of amide H/D exchange (as measured by mass spectrometry), despite also decreasing the thermostability of Mb by >10 °C. The ability of a metal cation to screen kinetic electrostatic effects during H/D exchange-and to abolish the protective effect of acetylation against H/D exchange-was found to depend on the position of the cation in the Hofmeister series. Na(+) and K(+) cations did not fully equalize the rates of H/D exchange among each "rung" of the charge ladder, whereas Mg(2+) and Ca(2+) did equalize rates without eliminating the hydrophobic core of the protein (i.e., without unfolding Mb); Li(+) exhibited intermediate effects. The ability of Mg(2+) and Ca(2+) to completely screen electrostatic effects associated with the H/D exchange of charge isomers of Mb suggests that Mg(2+) or Ca(2+) (but not Na(+) or K(+)) can be used to quantify the magnitude by which electrostatic charge contributes to the observed rates of amide H/D exchange in proteins.

  4. Predicting Salt Permeability Coefficients in Highly Swollen, Highly Charged Ion Exchange Membranes.

    PubMed

    Kamcev, Jovan; Paul, Donald R; Manning, Gerald S; Freeman, Benny D

    2017-02-01

    This study presents a framework for predicting salt permeability coefficients in ion exchange membranes in contact with an aqueous salt solution. The model, based on the solution-diffusion mechanism, was tested using experimental salt permeability data for a series of commercial ion exchange membranes. Equilibrium salt partition coefficients were calculated using a thermodynamic framework (i.e., Donnan theory), incorporating Manning's counterion condensation theory to calculate ion activity coefficients in the membrane phase and the Pitzer model to calculate ion activity coefficients in the solution phase. The model predicted NaCl partition coefficients in a cation exchange membrane and two anion exchange membranes, as well as MgCl2 partition coefficients in a cation exchange membrane, remarkably well at higher external salt concentrations (>0.1 M) and reasonably well at lower external salt concentrations (<0.1 M) with no adjustable parameters. Membrane ion diffusion coefficients were calculated using a combination of the Mackie and Meares model, which assumes ion diffusion in water-swollen polymers is affected by a tortuosity factor, and a model developed by Manning to account for electrostatic effects. Agreement between experimental and predicted salt diffusion coefficients was good with no adjustable parameters. Calculated salt partition and diffusion coefficients were combined within the framework of the solution-diffusion model to predict salt permeability coefficients. Agreement between model and experimental data was remarkably good. Additionally, a simplified version of the model was used to elucidate connections between membrane structure (e.g., fixed charge group concentration) and salt transport properties.

  5. Ionosphere-exosphere coupling through charge exchange and momentum transfer in hydrogen-proton collisions

    NASA Technical Reports Server (NTRS)

    Hodges, R. R., Jr.; Breig, E. L.

    1991-01-01

    The implications of a traditional assumption of exospheric physics, that collisions of hydrogen atoms and protons preferentially result in charge exchange with negligible momentum transfer are examined. Initially adopted as a necessary convenience to accommodate limited computer resources in exosphere model calculations, this approximation results in a direct transformation of the proton velocity distribution into a hot component of neutral hydrogen. With expanding computational facilities, the need for the approximation has passed. As the first step toward its replacement with a realistic, quantum mechanical model of the H - H(+) collision process, differential and cumulative cross sections were calculated for quantum elastic scattering of indistinguishable nuclei for a fine grid of encounter energies and scattering angles. These data are used to study the nature of ionosphere-exosphere coupling through H - H(+) collisions, and to demonstrate that the distribution of velocities of scattered H produced in the traditional exospheric charge exchange approximation, as well as that arising from an alternative, fluid dynamic approach, leads to unacceptable abundances of coronal atoms in long-term, highly elliptic trajectories.

  6. Charge Exchange Contribution to the Decay of the Ring Current, Measured by Energetic Neutral Atoms (ENAs)

    NASA Technical Reports Server (NTRS)

    Jorgensen, A. M.; Henderson, M. G.; Roelof, E. C.; Reeves, G. D.; Spence, H. E.

    2001-01-01

    In this paper we calculate the contribution of charge exchange to the decay of the ring current. Past works have suggested that charge exchange of ring current protons is primarily responsible for the decay of the ring current during the late recovery phase, but there is still much debate about the fast decay of the early recovery phase. We use energetic neutral atom (ENA) measurements from Polar to calculate the total ENA energy escape. To get the total ENA escape we apply a forward modeling technique, and to estimate the total ring current energy escape we use the Dessler-Parker-Sckopke relationship. We find that during the late recovery phase of the March 10, 1998 storm ENAs with energies greater than 17.5 keV can account for 75% of the estimated energy loss from the ring current. During the fast recovery the measured ENAs can only account for a small portion of the total energy loss. We also find that the lifetime of the trapped ions is significantly shorter during the fast recovery phase than during the late recovery phase, suggesting that different processes are operating during the two phases.

  7. CHARGE-EXCHANGE LIMITS ON LOW-ENERGY {alpha}-PARTICLE FLUXES IN SOLAR FLARES

    SciTech Connect

    Hudson, H. S.; Fletcher, L.; MacKinnon, A. L.; Woods, T. N.

    2012-06-20

    This paper reports on a search for flare emission via charge-exchange radiation in the wings of the Ly{alpha} line of He II at 304 A, as originally suggested for hydrogen by Orrall and Zirker. Via this mechanism a primary {alpha} particle that penetrates into the neutral chromosphere can pick up an atomic electron and emit in the He II bound-bound spectrum before it stops. The Extreme-ultraviolet Variability Experiment on board the Solar Dynamics Observatory gives us our first chance to search for this effect systematically. The Orrall-Zirker mechanism has great importance for flare physics because of the essential roles that particle acceleration plays; this mechanism is one of the few proposed that would allow remote sensing of primary accelerated particles below a few MeV nucleon{sup -1}. We study 10 events in total, including the {gamma}-ray events SOL2010-06-12 (M2.0) and SOL2011-02-24 (M3.5) (the latter a limb flare), seven X-class flares, and one prominent M-class event that produced solar energetic particles. The absence of charge-exchange line wings may point to a need for more complete theoretical work. Some of the events do have broadband signatures, which could correspond to continua from other origins, but these do not have the spectral signatures expected from the Orrall-Zirker mechanism.

  8. Influence of a wick lining on the evaporation rate of lithium from a charge exchange canal

    NASA Astrophysics Data System (ADS)

    Thampi, N. S.; Berger, S.; Dworschak, F.

    1992-02-01

    A wick lining is used with a lithium charge exchange canal for reducing the consumption of lithium. The wick helps to condense the lithium vapour more effectively and to make it flow back to the main oven. For its efficient functioning, the temperature gradient along the wick has to be properly maintained. The present studies were carried out to assess the extent of reduction in lithium loss when using the wick and to determine the optimum temperature settings. The evaporation rate of lithium vapour from a charge exchange canal (General Ionex Model-712) has been investigated in the temperature range from 470 to 575° C. The measurements were carried out with and without a stainless steel wire mesh wick lining, inside the canal. A quartz crystal oscillator type rate meter was used for monitoring the evaporation rate. The results indicate that, when the wick lining is inserted, the reduction in evaporation rate of lithium is only 20%. This differs much from the result of Greenway [Report 85/11, Oxford University, Nuclear Physics Laboratory (1985)] who reported a reduction by a factor of 8. The evaporation rate is also found to depend on the canal end heater temperature, maintained high enough to keep the condensing vapour in liquid state. The optimum temperature settings for the end heaters have been found to be 300 ° C. The experimental arrangements and results are presented in this paper.

  9. A high etendue spectrometer suitable for core charge eXchange recombination spectroscopy on ITER

    SciTech Connect

    Jaspers, R. J. E.; Scheffer, M.; Kappatou, A.; Valk, N. C. J. van der; Durkut, M.; Snijders, B.; Marchuk, O.; Biel, W.; Pokol, G. I.; Erdei, G.; Zoletnik, S.; Dunai, D.

    2012-10-15

    A feasibility study for the use of core charge exchange recombination spectroscopy on ITER has shown that accurate measurements on the helium ash require a spectrometer with a high etendue of 1mm{sup 2}sr to comply with the measurement requirements [S. Tugarinov et al., Rev. Sci. Instrum. 74, 2075 (2003)]. To this purpose such an instrument has been developed consisting of three separate wavelength channels (to measure simultaneously He/Be, C/Ne, and H/D/T together with the Doppler shifted direct emission of the diagnostic neutral beam, the beam emission (BES) signal), combining high dispersion (0.02 nm/pixel), sufficient resolution (0.2 nm), high efficiency (55%), and extended wavelength range (14 nm) at high etendue. The combined measurement of the BES along the same sightline within a third wavelength range provides the possibility for in situ calibration of the charge eXchange recombination spectroscopy signals. In addition, the option is included to use the same instrument for measurements of the fast fluctuations of the beam emission intensity up to 2 MHz, with the aim to study MHD activity.

  10. DXL: A sounding rocket mission measuring Solar Wind Charge eXchange properties

    NASA Astrophysics Data System (ADS)

    Galeazzi, Massimiliano

    2016-04-01

    Solar Wind interacts with the interstellar neutrals via charge exchange mechanism to produce spatially and temporally varying x-rays making it difficult to separate from other diffuse sources. The Diffuse X-rays from the Local Galaxy (DXL) mission measured the spatial signature of Solar Wind Charge eXchange (SWCX) emission due to the helium focusing cone. The mission used 2 large area proportional counters and was able to separate the SWCX contribution from Local Hot Bubble emission. The data from the mission provide a robust estimate of the SWCX contribution to the ROSAT maps, measuring the compound SWCX cross section with He in all ROSAT bands. The results showed that the total SWCX contribution in the ¼ keV band is, on average, ~27%. A new mission, DXL-2, was launched on December 4, 2015 with two new counters for a better understanding of the energy distribution of heliospheric SWCX photons, by using a multi-band approach. A dedicated scan to accurately measure the cone position and solve the IBEX controversy was also performed. The talk will discuss the DXL mission, the results from the first flight, and the preliminary results from the latest flight.Submitted for the DXL Collaboration

  11. Upgrade of the Edge Charge Exchange Diagnostic on Alcator C-Mod

    NASA Astrophysics Data System (ADS)

    McDermott, Rachael; Lipschultz, Bruce; Marr, Kenneth

    2006-10-01

    The current edge Charge Exchange Spectroscopy system is being upgraded to include both a beam viewing and a background viewing toroidal periscope. The beam viewing periscope will be focused on the center of the DNB and will cover a 4cm radial region at the edge of the plasma starting a few centimeters in from and extending up to 1centimeter outside of the last closed flux surface. The background periscope will view the same radial region but will be displaced toroidally by 36 degrees. Each periscope has 20 chordal views with a radial resolution of 2.5-3mm. The presence of a background periscope obviates the need for a chopped DNB by providing time synchronized background B^+4 spectral data that can be subtracted directly from the active beam-derived B^+4 line-shapes. This system has been designed to work in conjunction with the current poloidal Charge Exchange periscope which has 25 fibers focused in the same region with equivalent radial resolution. The new toroidal system will enable concurrent measurements of the poloidal and toroidal velocity as well as the temperature and density of the B^+5 ions in the edge pedestal region; a measurement that currently does not exist on C-Mod. This information will then be used to calculate radial electric field profiles and study edge physics phenomena.

  12. Observations of solar wind ion charge exchange in the Comet Halley coma

    NASA Technical Reports Server (NTRS)

    Fuselier, S. A.; Shelley, E. G.; Goldstein, B. E.; Goldstein, R.; Neugebauer, M.; Ip, W.-H.; Balsiger, H.; Reme, H.

    1991-01-01

    Giotto Ion Mass Spectrometer/High Energy Range Spectrometer (IMS/HERS) observations of solar wind ions show charge exchange effects and solar wind compositional changes in the coma of Comet Halley. As the comet was approached, the He(2+) to proton density ratio increased from 2.5 percent in the solar wind to about 4 percent about 1 hr before closest approach after which time it decreased to about 1 percent. Abrupt increases in this ratio from 2.5 to 4.5 percent were also observed in the beginning and near the end of the so-called Mystery Region. These abrupt increases in the density ratio were well correlated with enhanced fluxes of keV electrons as measured by the Giotto plasma electron spectrometer. The general increase and then decrease of the He(2+) to proton density ratio is quantitatively consistent with a combination of the addition of protons of Cometary origin to the plasma and loss of plasma through charge exchange of protons and He(2+).

  13. Ne X X-ray emission due to charge exchange in M82

    NASA Astrophysics Data System (ADS)

    Cumbee, R. S.; Liu, L.; Lyons, D.; Schultz, D. R.; Stancil, P. C.; Wang, J. G.; Ali, R.

    2016-06-01

    Recent X-ray observations of star-forming galaxies such as M82 have shown the Ly β/Ly α line ratio of Ne X to be in excess of predictions for thermal electron impact excitation. Here, we demonstrate that the observed line ratio may be due to charge exchange and can be used to constrain the ion kinetic energy to be ≲ 500 eV/u. This is accomplished by computing spectra and line ratios via a range of theoretical methods and comparing these to experiments with He over astrophysically relevant collision energies. The charge exchange emission spectra calculations were performed for Ne10++ H and Ne10++ He using widely applied approaches including the atomic orbital close coupling, classical trajectory Monte Carlo, and multichannel Landau-Zener (MCLZ) methods. A comparison of the results from these methods indicates that for the considered energy range and neutrals (H, He) the so-called low-energy ℓ-distribution MCLZ method provides the most likely reliable predictions.

  14. First measurement of the edge charge exchange recombination spectroscopy on EAST tokamak.

    PubMed

    Li, Y Y; Yin, X H; Fu, J; Jiang, D; Feng, S Y; Lyu, B; Shi, Y J; Yi, Y; Zhou, X J; Hu, C D; Ye, M Y; Wan, B N

    2016-11-01

    An edge toroidal charge exchange recombination spectroscopy (eCXRS) diagnostic, based on a heating neutral beam injection (NBI), has been deployed recently on the Experimental Advanced Superconducting Tokamak (EAST). The eCXRS, which aims to measure the plasma ion temperature and toroidal rotation velocity in the edge region simultaneously, is a complement to the exiting core CXRS (cCXRS). Two rows with 32 fiber channels each cover a radial range from ∼2.15 m to ∼2.32 m with a high spatial resolution of ∼5-7 mm. Charge exchange emission of Carbon VI CVI at 529.059 nm induced by the NBI is routinely observed, but can be tuned to any interested wavelength in the spectral range from 400 to 700 nm. Double-slit fiber bundles increase the number of channels, the fibers viewing the same radial position are binned on the CCD detector to improve the signal-to-noise ratio, enabling shorter exposure time down to 5 ms. One channel is connected to a neon lamp, which provides the real-time wavelength calibration on a shot-to-shot basis. In this paper, an overview of the eCXRS diagnostic on EAST is presented and the first results from the 2015 experimental campaign will be shown. Good agreements in ion temperature and toroidal rotation are obtained between the eCXRS and cCXRS systems.

  15. Recent Advances in Computational Studies of Charge Exchange X-ray Emission

    NASA Astrophysics Data System (ADS)

    Cumbee, Renata

    2016-06-01

    Interest in astrophysical sources of charge exchange (CX) has grown since X-ray emission from comet Hyakutake was first observed, the origin of which is primarily due to CX processes between neutral species in the comet’s atmosphere and highly charged ions from the solar wind. More recent observations have shown that CX may have a significant contribution to the X-ray emission spectra of a wide variety of environments within our solar system including solar wind charge exchange (SWCX) with neutral gases in the heliosphere and in planetary atmospheres, as well as beyond the solar system in galaxy clusters, supernova remnants, and star forming galaxies.While the basic process of CX has been studied for many decades, the reliability of the existing data is not uniform, and the coverage of the astrophysically important projectile and target combinations and collisional velocities is insufficient. The need for reliable and robust CX X-ray emission models will only be amplified with the with the high resolution X-ray spectra expected from the soft X-ray imaging calorimeter spectrometer (SXS) onboard the Hitomi X-ray observatory. In this talk, I will discuss recent advances in theoretical CX cross sections and X-ray modeling with a focus on CX diagnostics. The need for experimental X-ray spectra and cross sections for benchmarking current theory will also be highlighted. This work was performed in collaboration with David Lyons, Patrick Mullen, David Schultz, Phillip Stancil, and Robin Shelton. Work at UGA was partially supported by NASA grant NNX09AC46G.

  16. Social Network Analysis of the Farabi Exchange Program: Student Mobility

    ERIC Educational Resources Information Center

    Ugurlu, Zeynep

    2016-01-01

    Problem Statement: Exchange programs offer communication channels created through student and instructor exchanges; a flow of information takes place through these channels. The Farabi Exchange Program (FEP) is a student and instructor exchange program between institutions of higher education. Through the use of social network analysis and…

  17. Charge Noise Spectroscopy Using Coherent Exchange Oscillations in a Singlet-Triplet Qubit

    NASA Astrophysics Data System (ADS)

    Dial, O. E.; Shulman, M. D.; Harvey, S. P.; Bluhm, H.; Umansky, V.; Yacoby, A.

    2013-04-01

    Two level systems that can be reliably controlled and measured hold promise as qubits both for metrology and for quantum information science. Since a fluctuating environment limits the performance of qubits in both capacities, understanding environmental coupling and dynamics is key to improving qubit performance. We show measurements of the level splitting and dephasing due to the voltage noise of a GaAs singlet-triplet qubit during exchange oscillations. Unexpectedly, the voltage fluctuations are non-Markovian even at high frequencies and exhibit a strong temperature dependence. This finding has impacts beyond singlet-triplet qubits since nearly all solid state qubits suffer from some kind of charge noise. The magnitude of the fluctuations allows the qubit to be used as a charge sensor with a sensitivity of 2×10-8e/Hz, 2 orders of magnitude better than a quantum-limited rf single electron transistor. Based on these measurements, we provide recommendations for improving qubit coherence, allowing for higher fidelity operations and improved charge sensitivity.

  18. Design of a strong cation exchange methodology for the evaluation of charge heterogeneity in glatiramer acetate.

    PubMed

    Campos-García, Víctor R; López-Morales, Carlos A; Benites-Zaragoza, Eleuterio; Jiménez-Miranda, Armando; Espinosa-de la Garza, Carlos E; Herrera-Fernández, Daniel; Padilla-Calderón, Jesús; Pérez, Néstor O; Flores-Ortiz, Luis F; Medina-Rivero, E

    2017-01-05

    Complex pharmaceuticals are in demand of competent analytical methods able to analyze charge heterogeneity as a critical quality attribute (CQA), in compliance with current regulatory expectations. A notorious example is glatiramer acetate (GA), a complex polypeptide mixture useful for the treatment of relapsing-remitting multiple sclerosis. This pharmaceutical challenges the current state of analytical technology in terms of the capacity to study their constituent species. Thus, a strong cation exchange methodology was designed under the lifecycle approach to support the establishment of GA identity, trough the evaluation of its chromatographic profile, which acts as a charge heterogeneity fingerprint. In this regard, a maximum relative margin of error of 5% for relative retention time and symmetry factor were proposed for the analytical target profile. The methodology met the proposed requirements after precision and specificity tests results, the former comprised of sensitivity and selectivity. Subsequently, method validation was conducted and showed that the method is able to differentiate between intact GA and heterogeneity profiles coming from stressed, fractioned or process-modified samples. In summary, these results provide evidence that the method is adequate to assess charge heterogeneity as a CQA of this complex pharmaceutical.

  19. The velocity dependence of X-ray emission due to Charge Exchange in the Cygnus Loop

    NASA Astrophysics Data System (ADS)

    Cumbee, Renata; Lyons, David; Mullen, Patrick Dean; Shelton, Robin L.; Stancil, Phillip C.; Schultz, David R.

    2016-01-01

    The fundamental collisional process of charge exchange (CX) has been been established as a primary source of X-ray emission from the heliosphere [1], planetary exospheres [2], and supernova remnants [3,4]. In this process, X-ray emission results from the capture of an electron by a highly charged ion from a neutral atom or molecule, to form a highly-excited, high charge state ion. As the captured electron cascades down to the lowest energy level, photons are emitted, including X-rays.To provide reliable CX-induced X-ray spectral models to realistically simulate these environments, line ratios and spectra are computed using theoretical CX cross-sections obtained with the multi-channel Landau-Zener, atomic-orbital close-coupling, and classical-trajectory Monte Carlo methods for various collisional velocities relevant to astrophysics for collisions of bare and H-like C to Al ions with H, He, and H2. Using these line ratios, XSPEC models of CX emission in the northeast rim of the Cygnus Loop supernova remnant will be shown as an example with ion velocity dependence.[1] Henley, D. B. & Shelton, R. L. 2010, ApJSS, 187, 388[2] Dennerl, K. et al. 2002, A&A 386, 319[3] Katsuda, S. et al. 2011, ApJ 730 24[4] Cumbee, R. S. et al. 2014, ApJ 787 L31This work was partially supported by NASA grant NNX09AC46G.

  20. Calculation of total cross sections for charge exchange in molecular collisions

    NASA Technical Reports Server (NTRS)

    Ioup, J.

    1979-01-01

    Areas of investigation summarized include nitrogen ion-nitrogen molecule collisions; molecular collisions with surfaces; molecular identification from analysis of cracking patterns of selected gases; computer modelling of a quadrupole mass spectrometer; study of space charge in a quadrupole; transmission of the 127 deg cylindrical electrostatic analyzer; and mass spectrometer data deconvolution.

  1. X-Ray Emission Cross Sections following Charge Exchange by Multiply-Charged Ions of Astrophysical Interest

    NASA Astrophysics Data System (ADS)

    Olson, Ronald

    2006-05-01

    State selective nl-electron capture cross sections are presented for highly charged ions with Z = 6-10 colliding with molecules. The energy range investigated was from 1 eV/amu (v = 1.4x10^6 cm/s) to 100 keV/amu (v = 4.4x10^8 cm/s). The K-shell x-ray emission cross sections are determined by using the calculated state-selective electron capture results as input and then applying the branching and cascading values for the photon emission. A major shift in the line emission from being almost solely Lyman-alpha transitions at the highest collisions energies to strong high-n to 1s transitions at the lowest energies is observed. The calculated emission cross sections are in reasonable accord with measurements made by Greenwood et al^1 for O^8+ and Ne^10+ on various targets at 3 keV/amu. The calculations are also in accord with x-ray emission cross section data obtained on the EBIT machine at LLNL where O^8+ and Ne^10+ high resolution measurements were made at a temperature of 10 eV/amu for a series of targets with varying ionization potentials. The Ne^10+ data clearly show the contribution from multiple capture followed by Auger autoionization in the line emission spectra. Our calculated line emission cross sections are used to provide an ab initio determination of the soft x-ray spectrum of comet C/Linear 1999 S4 that was observed on the Chandra X-ray Observatory. The calculations reproduce the measured spectrum and show that it is due to charge exchange of the neutral gases in the comet's coma with the ions of the slow solar wind. Details of the calculations are presented in a recent paper by Otranto et al^2. 1. J. B. Greenwood, I. D. Williams, S. J. Smith and A. Chutjian, Phys. Rev. A 63, 062707 (2001). 2. S. Otranto, R. E. Olson, and P. Beiersdorfer, Phys. Rev. A (in press).

  2. Tuning a High Transmission Ion Guide to Prevent Gas-Phase Proton Exchange During H/D Exchange MS Analysis.

    PubMed

    Guttman, Miklos; Wales, Thomas E; Whittington, Dale; Engen, John R; Brown, Jeffery M; Lee, Kelly K

    2016-04-01

    Hydrogen/deuterium exchange (HDX) mass spectrometry (MS) for protein structural analysis has been adopted for many purposes, including biopharmaceutical development. One of the benefits of examining amide proton exchange by mass spectrometry is that it can readily resolve different exchange regimes, as evidenced by either binomial or bimodal isotope patterns. By careful analysis of the isotope pattern during exchange, more insight can be obtained on protein behavior in solution. However, one must be sure that any observed bimodal isotope patterns are not artifacts of analysis and are reflective of the true behavior in solution. Sample carryover and certain stationary phases are known as potential sources of bimodal artifacts. Here, we describe an additional undocumented source of deuterium loss resulting in artificial bimodal patterns for certain highly charged peptides. We demonstrate that this phenomenon is predominantly due to gas-phase proton exchange between peptides and bulk solvent within the initial stages of high-transmission conjoined ion guides. Minor adjustments of the ion guide settings, as reported here, eliminate the phenomenon without sacrificing signal intensity. Such gas-phase deuterium loss should be appreciated for all HDX-MS studies using such ion optics, even for routine studies not focused on interpreting bimodal spectra. Graphical Abstract ᅟ.

  3. MINERνA charged current inclusive analysis

    SciTech Connect

    Caicedo, D. A. M.

    2015-05-15

    MINERνA is a few-GeV neutrino scattering experiment that has been taking data in the NuMI beam line at Fermilab since November 2009. The experiment will provide important inputs, both in support of neutrino oscillation searches and as a pure weak probe of the nuclear medium. For this, MINERvA employs a fine-grained detector, with an eight ton active target region composed of plastic scintillator and a suite of nuclear targets composed of helium, carbon, iron, lead and water placed upstream of the active region. We will describe the current status of the charged current inclusive analysis in plastic scintillator.

  4. MINERνA charged current inclusive analysis

    NASA Astrophysics Data System (ADS)

    Caicedo, D. A. M.

    2015-05-01

    MINERνA is a few-GeV neutrino scattering experiment that has been taking data in the NuMI beam line at Fermilab since November 2009. The experiment will provide important inputs, both in support of neutrino oscillation searches and as a pure weak probe of the nuclear medium. For this, MINERvA employs a fine-grained detector, with an eight ton active target region composed of plastic scintillator and a suite of nuclear targets composed of helium, carbon, iron, lead and water placed upstream of the active region. We will describe the current status of the charged current inclusive analysis in plastic scintillator.

  5. The role of spin exchange in charge transfer in low-bandgap polymer: Fullerene bulk heterojunctions

    SciTech Connect

    Krinichnyi, V. I. Yudanova, E. I.; Denisov, N. N.

    2014-07-28

    Formation, relaxation and dynamics of polarons and methanofullerene anion radicals photoinitiated in poly[N-9″-hepta-decanyl-2,7-carbazole-alt-5,5-(4′,7′-di-2-thienyl-2′,1′, 3′-benzothiadiazole)]:-[6,6]-phenyl-C{sub 61}-butyric acid methyl ester (PCDTBT:PC{sub 61}BM) bulk heterojunctions were studied mainly by light-induced EPR (LEPR) spectroscopy in wide photon energy and temperature ranges. Some polarons are pinned by spin traps whose number and depth are governed by the composite morphology and photon energy. The proximity of the photon energy and the polymer bandgap reduces the number of such traps, inhibits recombination of mobile charge carriers, and facilitates their mobility in polymer network. Spin relaxation and charge carrier dynamics were studied by the steady-state saturation method at wide range of temperature and photon energy. These processes were shown to be governed by spin exchange as well as by the photon energy. Charge transfer in the composite is governed by the polaron scattering on the lattice phonons of crystalline domains embedded into amorphous polymer matrix and its activation hopping between polymer layers. The energy barrier required for polaron interchain hopping exceeds that of its intrachain diffusion. Anisotropy of polaron dynamics in the PCDTBT:PC61BM composite is less than that of poly(3-alkylthiophenes)-based systems that evidences for better ordering of the former. Lorentzian shape of LEPR lines of both charge carriers, lower concentration of spin traps as well as behaviours of the main magnetic resonance parameters were explained by layer ordered morphology of polymer matrix.

  6. Scrape-off layer modeling with kinetic or diffusion description of charge-exchange atoms

    NASA Astrophysics Data System (ADS)

    Tokar, M. Z.

    2016-12-01

    Hydrogen isotope atoms, generated by charge-exchange (c-x) of neutral particles recycling from the first wall of a fusion reactor, are described either kinetically or in a diffusion approximation. In a one-dimensional (1-D) geometry, kinetic calculations are accelerated enormously by applying an approximate pass method for the assessment of integrals in the velocity space. This permits to perform an exhaustive comparison of calculations done with both approaches. The diffusion approximation is deduced directly from the velocity distribution function of c-x atoms in the limit of charge-exchanges with ions occurring much more frequently than ionization by electrons. The profiles across the flux surfaces of the plasma parameters averaged along the main part of the scrape-off layer (SOL), beyond the X-point and divertor regions, are calculated from the one-dimensional equations where parallel flows of charged particles and energy towards the divertor are taken into account as additional loss terms. It is demonstrated that the heat losses can be firmly estimated from the SOL averaged parameters only; for the particle loss the conditions in the divertor are of importance and the sensitivity of the results to the so-called "divertor impact factor" is investigated. The coupled 1-D models for neutral and charged species, with c-x atoms described either kinetically or in the diffusion approximation, are applied to assess the SOL conditions in a fusion reactor, with the input parameters from the European DEMO project. It is shown that the diffusion approximation provides practically the same profiles across the flux surfaces for the plasma density, electron, and ion temperatures, as those obtained with the kinetic description for c-x atoms. The main difference between the two approaches is observed in the characteristics of these species themselves. In particular, their energy flux onto the wall is underestimated in calculations with the diffusion approximation by 20 % - 30

  7. High resolution main-ion charge exchange spectroscopy in the DIII-D H-mode pedestal

    SciTech Connect

    Grierson, B. A.; Burrell, K. H.; Chrystal, C.; Groebner, R. J.; Haskey, S. R.; Kaplan, D. H.

    2016-09-12

    A new high spatial resolution main-ion (deuterium) charge-exchange spectroscopy system covering the tokamak boundary region has been installed on the DIII-D tokamak. Sixteen new edge main-ion charge-exchange recombination sightlines have been combined with nineteen impurity sightlines in a tangentially viewing geometry on the DIII-D midplane with an interleaving design that achieves 8 mm inter-channel radial resolution for detailed profiles of main-ion temperature, velocity, charge-exchange emission, and neutral beam emission. At the plasma boundary, we find a strong enhancement of the main-ion toroidal velocity that exceeds the impurity velocity by a factor of two. Furthermore, the unique combination of experimentally measured main-ion and impurity profiles provides a powerful quasi-neutrality constraint for reconstruction of tokamak H-mode pedestals.

  8. High resolution main-ion charge exchange spectroscopy in the DIII-D H-mode pedestal

    NASA Astrophysics Data System (ADS)

    Grierson, B. A.; Burrell, K. H.; Chrystal, C.; Groebner, R. J.; Haskey, S. R.; Kaplan, D. H.

    2016-11-01

    A new high spatial resolution main-ion (deuterium) charge-exchange spectroscopy system covering the tokamak boundary region has been installed on the DIII-D tokamak. Sixteen new edge main-ion charge-exchange recombination sightlines have been combined with nineteen impurity sightlines in a tangentially viewing geometry on the DIII-D midplane with an interleaving design that achieves 8 mm inter-channel radial resolution for detailed profiles of main-ion temperature, velocity, charge-exchange emission, and neutral beam emission. At the plasma boundary, we find a strong enhancement of the main-ion toroidal velocity that exceeds the impurity velocity by a factor of two. The unique combination of experimentally measured main-ion and impurity profiles provides a powerful quasi-neutrality constraint for reconstruction of tokamak H-mode pedestals.

  9. High resolution main-ion charge exchange spectroscopy in the DIII-D H-mode pedestal

    DOE PAGES

    Grierson, B. A.; Burrell, K. H.; Chrystal, C.; ...

    2016-09-12

    A new high spatial resolution main-ion (deuterium) charge-exchange spectroscopy system covering the tokamak boundary region has been installed on the DIII-D tokamak. Sixteen new edge main-ion charge-exchange recombination sightlines have been combined with nineteen impurity sightlines in a tangentially viewing geometry on the DIII-D midplane with an interleaving design that achieves 8 mm inter-channel radial resolution for detailed profiles of main-ion temperature, velocity, charge-exchange emission, and neutral beam emission. At the plasma boundary, we find a strong enhancement of the main-ion toroidal velocity that exceeds the impurity velocity by a factor of two. Furthermore, the unique combination of experimentally measuredmore » main-ion and impurity profiles provides a powerful quasi-neutrality constraint for reconstruction of tokamak H-mode pedestals.« less

  10. High-resolution Studies of Charge Exchange in Supernova Remnants with Magellan, XMM-Newton, and Micro-X

    NASA Astrophysics Data System (ADS)

    Heine, Sarah N.; Figueroa-Feliciano, Enectali; Castro, Daniel

    2015-01-01

    Charge exchange, the semi-resonant transfer of an electron from a neutral atom to an excited state in an energetic ion, can occur in plasmas where energetic ions are incident on a cold, at least partially neutral gas. Supernova remnants, especially in the immediate shock region, provide conditions conducive to charge exchange. The emission from post charge-exchange ions as the captured electron cascades down to the ground state, can shed light on the physical conditions of the shock and the immediate post-shock material, providing an important tool to understanding supernova explosions and their aftermath.I present a study of charge exchange in the galactic supernova remnant G296.1-0.5 in two bands: the optical and the X-ray. The optical study, performed using both imaging and spectroscopy from the IMACS instrument on the Magellan Baade Telescope at Las Companas Observatory, seeks to identify `Balmer-dominated shocks' in the remnant, which occur when charge exchange occurs between hot, post-shock protons and colder neutral hydrogen in the environment. The X-ray study probes line ratios in dispersed spectral data obtained with XMM-Newton RGS from an X-ray lobe in the NW of the remnant to hunt for signatures of charge exchange. The dispersed data are degraded by the extended nature of the source, blending many of the lines.We are working towards the future of spectroscopic studies in the X-ray for such extended sources with Micro-X: a sounding rocket-borne, high energy resolution X-ray telescope, utilizing an array of microcalorimeters to achieve high energy resolution for extended sources. I describe the design and commissioning of the payload and the steps toward launch, which is anticipated in the summer of 2015.

  11. Production of vibrationally excited H(2)O from charge exchange of H(3)O(+) with cesium.

    PubMed

    Mann, Jennifer E; Xie, Zhen; Savee, John D; Bowman, Joel M; Continetti, Robert E

    2009-01-28

    The center-of-mass kinetic energy release for the dissociation of H(3)O following charge exchange of H(3)O(+) with cesium has been studied experimentally and modeled using quasiclassical trajectory calculations based on an ab initio potential energy surface for H(3)O(+) and "direct dynamics" for H(3)O. Branching fractions for the H(2)O+H and OH+H(2) dissociation channels have been measured and compared to the calculations. The dominant channel is found to be H(2)O+H and the experimental kinetic energy release spectrum reveals that H(2)O is formed with a vibrational inversion in stretching vibrations, coupled with low bending and rotational excitation.

  12. Observation of Solar Wind Charge Exchange Emission from Exospheric Material in and Outside Earth's Magnetosheath

    NASA Technical Reports Server (NTRS)

    Snowden, S. L.; Collier, M. R.; Cravens, T.; Kuntz, K. D.; Lepri, S. T.; Robertson, I.; Tomas, L.

    2008-01-01

    A long XMM-Newton exposure is used to observe solar wind charge exchange (SWCX) emission from exospheric material in and outside Earth s magnetosheath. The light curve of the O VII (0.5-0.62 keV) band is compared with a model for the expected emission, and while the emission is faint and the light curve has considerable scatter, the correlation is significant to better than 99.9%. This result demonstrates the validity of the geocoronal SWCX emission model for predicting a contribution to astrophysical observations to a scale factor of order unity (1.36). The results also demonstrate the potential utility of using X-ray observations to study global phenomena of the magnetosheath which currently are only investigated using in situ measurements.

  13. Charge-exchange QRPA with the Gogny Force for Axially-symmetric Deformed Nuclei

    SciTech Connect

    Martini, M.; Goriely, S.; Péru, S.

    2014-06-15

    In recent years fully consistent quasiparticle random-phase approximation (QRPA) calculations using finite range Gogny force have been performed to study electromagnetic excitations of several axially-symmetric deformed nuclei up to the {sup 238}U. Here we present the extension of this approach to the charge-exchange nuclear excitations (pnQRPA). In particular we focus on the Isobaric Analog and Gamow-Teller resonances. A comparison of the predicted GT strength distribution with existing experimental data is presented. The role of nuclear deformation is shown. Special attention is paid to β-decay half-lives calculations for which experimental data exist and for specific isotone chains of relevance for the r-process nucleosynthesis.

  14. Corrections to charge exchange spectroscopic measurements in TFTR due to energy-dependent excitation rates

    SciTech Connect

    Howell, R.B.; Fonck, R.J.; Knize, R.J.; Jaehnig, K.P.

    1988-08-01

    The use of charge exchange spectrocopy to determine plasma rotation speeds and ion temperature is complicated by the energy dependence of the excitation cross sections. The Doppler-broadened spectral line shape is distorted by the relative velocity between the neutral hydrogen atoms of the injected beam and impurity ions. The asymmetric nature of the energy dependence of this cross section causes a non-motional shift of the line center and a non-thermal change in the line width. These effects vary with the angles between the beam direction, rotation velocity direction, and direction of the viewing sightline. When viewing two neutral beams at different angles on TFTR, the two measurements of v/sub phi/(r) show discrepancies about 20 to 30% with each other. The calculation of the spectral intensity profiles, using the excitation rates available, overcorrects these discrepancies and indicates the need for better excitation coefficients. 10 refs., 5 figs.

  15. Scaling for state-selective charge exchange due to collisions of multicharged ions with hydrogen

    NASA Astrophysics Data System (ADS)

    Jorge, A.; Illescas, Clara; Miraglia, J. E.; Gravielle, M. S.

    2015-12-01

    In this article we evaluate state-resolved charge exchange cross sections for Be{}4+, {{{B}}}5+, {{{C}}}6+, {{{N}}}7+, and {{{O}}}8+ projectiles colliding with atomic hydrogen employing two different methods: the classical trajectory Monte Carlo and the eikonal impulse approximations. These cross sections are used to extend previously derived scaling laws for n-, nl-, and nlm-distributions to highly excited final levels with 4≤slant n≤slant 9, covering energies in the range 50-2000 {{keV}}/ amu. Present total and partial capture cross sections are in agreement with available experimental and theoretical data for these collision systems. Besides, the proposed scaling rules are also verified by other theories, becoming a useful instrument for plasma research.

  16. Scaling for state-selective charge exchange due to collisions of multicharged ions with hydrogen

    NASA Astrophysics Data System (ADS)

    Jorge, A.; Illescas, Clara; Miraglia, J. E.; Gravielle, M. S.

    2014-12-01

    In this article we evaluate state-resolved charge exchange cross sections for Be{}4+, {{{B}}}5+, {{{C}}}6+, {{{N}}}7+, and {{{O}}}8+ projectiles colliding with atomic hydrogen employing two different methods: the classical trajectory Monte Carlo and the eikonal impulse approximations. These cross sections are used to extend previously derived scaling laws for n-, nl-, and nlm-distributions to highly excited final levels with 4≤slant n≤slant 9, covering energies in the range 50-2000 {{keV}}/ amu. Present total and partial capture cross sections are in agreement with available experimental and theoretical data for these collision systems. Besides, the proposed scaling rules are also verified by other theories, becoming a useful instrument for plasma research.

  17. Correlation of Resonance Charge Exchange Cross-Section Data in the Low-Energy Range

    NASA Technical Reports Server (NTRS)

    Sheldon, John W.

    1962-01-01

    During the course of a literature survey concerning resonance charge exchange, an unusual degree of agreement was noted between an extrapolation of the data reported by Kushnir, Palyukh, and Sena and the data reported by Ziegler. The data of Kushnir et al. are for ion-atom relative energies from 10 to 1000 ev, while the data of Ziegler are for a relative energy of about 1 ev. Extrapolation of the data of Kushnir et al. was made in accordance with Holstein's theory, 3 which is a combination of time-dependent perturbation methods and classical orbit theory. The results of this theory may be discussed in terms of a critical impact parameter b(sub c).

  18. Development of the charge exchange recombination spectroscopy and the beam emission spectroscopy on the EAST tokamak

    SciTech Connect

    Li, Y. Y.; Fu, J.; Lyu, B.; Du, X. W.; Li, C. Y.; Yu, Y.; Wang, Q. P.; Zhang, Y.; Yin, X. H.; Ye, M. Y.; Wan, B. N.; Hellermann, M. von; Shi, Y. J.

    2014-11-15

    Charge eXchange Recombination Spectroscopy (CXRS) and Beam Emission Spectroscopy (BES) diagnostics based on a heating neutral beam have recently been installed on EAST to provide local measurements of ion temperature, velocity, and density. The system design features common light collection optics for CXRS and BES, background channels for the toroidal views, multi-chord viewing sightlines, and high throughput lens-based spectrometers with good signal to noise ratio for high time resolution measurements. Additionally, two spectrometers each has a tunable grating to observe any wavelength of interest are used for the CXRS and one utilizes a fixed-wavelength grating to achieve higher diffraction efficiency for the BES system. A real-time wavelength correction is implemented to achieve a high-accuracy wavelength calibration. Alignment and calibration are performed. Initial performance test results are presented.

  19. PLASMA INSTABILITIES AS A RESULT OF CHARGE EXCHANGE IN THE DOWNSTREAM REGION OF SUPERNOVA REMNANT SHOCKS

    SciTech Connect

    Ohira, Yutaka; Takahara, Fumio; Terasawa, Toshio

    2009-09-20

    Halpha emission from supernova remnants (SNRs) implies the existence of neutral hydrogen in the circumstellar medium. Some of the neutral particles penetrating the shock are ionized by the charge-exchange process and make a cold ion beam in the shock downstream region. We perform linear analyses of collisionless plasma instabilities between the cold beam and the hot downstream plasma. We find that, under typical SNR conditions, either the resonant instability or the Weibel instability is the most unstable. This mechanism may amplify the magnetic field to more than 100 muG and changes the shock structure. As a result, the radio spectrum and the large magnetic field can be explained, apart from the widely discussed Bell's mechanism.

  20. Charge-exchange recombination spectroscopy of the plasma ion temperature at the T-10 tokamak

    SciTech Connect

    Krupin, V. A.; Tugarinov, S. N.; Barsukov, A. G.; Dnestrovskij, A. Yu.; Klyuchnikov, L. A.; Korobov, K. V.; Krasnyanskii, S. A.; Naumenko, N. N.; Nemets, A. R.; Sushkov, A. V.; Tilinin, G. N.

    2013-08-15

    Charge-exchange recombination spectroscopy (CXRS) based on a diagnostic neutral beam has been developed at the T-10 tokamak. The diagnostics allows one to measure the ion temperature profile in the cross section of the plasma column. In T-10 experiments, the measurement technique was adjusted and the elements of the CXRS diagnostics for ITER were tested. The used spectroscopic equipment makes it possible to reliably determine the ion temperature from the Doppler broadening of impurity lines (helium, carbon), as well as of the spectral lines of the working gas. The profiles of the plasma ion temperature in deuterium and helium discharges were measured at different plasma currents and densities, including with the use of active Doppler measurements of lines of different elements. The validity and reliability of ion temperature measurements performed by means of the developed CXRS diagnostics are analyzed.

  1. Cobalt(II) and Nickel(II) Transfer through Charged Polysulfonated Cation Exchange Membranes.

    PubMed

    Ersoz; Kara

    2000-12-15

    The transport of Co(II) and Ni(II) ions through charged polysulfonated ion exchange membranes under Donnan dialysis conditions has been studied as a function of pH gradient at 25 degrees C. In the Donnan dialysis process, the membrane is bounded by two electrolyte solutions, the one side (donor phase) initially containing metal salts and the other H(2)SO(4) with no external potential field applied. The transport of metal ions through membranes was correlated with the flux data as well as with estimated diffusion coefficients and was found to depend on the interaction between the fixed groups in the membrane and the metal ions. It was observed that the pH gradient influences the transport of metals and the flux of ions increases with H ion concentration in the receiver phase. Copyright 2000 Academic Press.

  2. Spin dipole nuclear matrix elements for double beta decay nuclei by charge-exchange reactions

    NASA Astrophysics Data System (ADS)

    Ejiri, H.; Frekers, D.

    2016-11-01

    Spin dipole (SD) strengths for double beta-decay (DBD) nuclei were studied experimentally for the first time by using measured cross sections of (3He, t) charge-exchange reactions (CERs). Then SD nuclear matrix elements (NMEs) {M}α ({{SD}}) for low-lying 2- states were derived from the experimental SD strengths by referring to the experimental α = GT (Gamow-Teller) and α = F (Fermi) strengths. They are consistent with the empirical NMEs M({{SD}}) based on the quasi-particle model with the empirical effective SD coupling constant. The CERs are used to evaluate the SD NME, which is associated with one of the major components of the neutrino-less DBD NME.

  3. Design of charge exchange recombination spectroscopy for the joint Texas experimental tokamak.

    PubMed

    Chi, Y; Zhuang, G; Cheng, Z F; Hou, S Y; Cheng, C; Li, Z; Wang, J R; Wang, Z J

    2014-11-01

    The old diagnostic neutral beam injector first operated at the University of Texas at Austin is ready for rejoining the joint Texas experimental tokamak (J-TEXT). A new set of high voltage power supplies has been equipped and there is no limitation for beam modulation or beam pulse duration henceforth. Based on the spectra of fully striped impurity ions induced by the diagnostic beam the design work for toroidal charge exchange recombination spectroscopy (CXRS) system is presented. The 529 nm carbon VI (n = 8 - 7 transition) line seems to be the best choice for ion temperature and plasma rotation measurements and the considered hardware is listed. The design work of the toroidal CXRS system is guided by essential simulation of expected spectral results under the J-TEXT tokamak operation conditions.

  4. Design of charge exchange recombination spectroscopy for the joint Texas experimental tokamak

    SciTech Connect

    Chi, Y.; Zhuang, G. Cheng, Z. F.; Hou, S. Y.; Cheng, C.; Li, Z.; Wang, J. R.; Wang, Z. J.

    2014-11-15

    The old diagnostic neutral beam injector first operated at the University of Texas at Austin is ready for rejoining the joint Texas experimental tokamak (J-TEXT). A new set of high voltage power supplies has been equipped and there is no limitation for beam modulation or beam pulse duration henceforth. Based on the spectra of fully striped impurity ions induced by the diagnostic beam the design work for toroidal charge exchange recombination spectroscopy (CXRS) system is presented. The 529 nm carbon VI (n = 8 − 7 transition) line seems to be the best choice for ion temperature and plasma rotation measurements and the considered hardware is listed. The design work of the toroidal CXRS system is guided by essential simulation of expected spectral results under the J-TEXT tokamak operation conditions.

  5. Design of charge exchange recombination spectroscopy for the joint Texas experimental tokamaka)

    NASA Astrophysics Data System (ADS)

    Chi, Y.; Zhuang, G.; Cheng, Z. F.; Hou, S. Y.; Cheng, C.; Li, Z.; Wang, J. R.; Wang, Z. J.

    2014-11-01

    The old diagnostic neutral beam injector first operated at the University of Texas at Austin is ready for rejoining the joint Texas experimental tokamak (J-TEXT). A new set of high voltage power supplies has been equipped and there is no limitation for beam modulation or beam pulse duration henceforth. Based on the spectra of fully striped impurity ions induced by the diagnostic beam the design work for toroidal charge exchange recombination spectroscopy (CXRS) system is presented. The 529 nm carbon VI (n = 8 - 7 transition) line seems to be the best choice for ion temperature and plasma rotation measurements and the considered hardware is listed. The design work of the toroidal CXRS system is guided by essential simulation of expected spectral results under the J-TEXT tokamak operation conditions.

  6. Localized description of surface energy gap effects in the resonant charge exchange between atoms and surfaces.

    PubMed

    Iglesias-García, A; García, Evelina A; Goldberg, E C

    2011-02-02

    The resonant charge exchange between atoms and surfaces is described by considering a localized atomistic view of the solid within the Anderson model. The presence of a surface energy gap is treated within a simplified tight-binding model of the solid, and a proper calculation of the Hamiltonian terms based on a LCAO expansion of the solid eigenstates is performed. It is found that interference terms jointly with a surface projected gap maximum at the Γ point and the Fermi level inside it, lead to hybridization widths negligible around the Fermi level. This result can explain experimental observations related to long-lived adsorbate states and anomalous neutral fractions of low energy ions in alkali/Cu(111) systems.

  7. Charge exchange and cluster formation in an rf Paul trap: interaction of alkali atoms with C +60

    NASA Astrophysics Data System (ADS)

    Pollack, Stuart; Cameron, Douglas; Rokni, Mordechai; Hill, Winfield; Parks, J. H.

    1996-06-01

    A Paul ion trap was used to study the formation of clusters under controlled temperature and pressure conditions. Exposure of cold C +60 ions to Li flux leads to the formation of Li nC +60 clusters ( n = 1-18) occurring by the sequential association of Li atoms. Cluster formation dependence on He pressure displayed a competition between vibrational relaxation and unimolecular dissociation. Collisions with Na, K, Rb and Cs atoms resulted in dissociative charge exchange. Decay rates of C +60 ions resulting from these low-energy charge exchange collisions were consistent with Langevin capture rates.

  8. What can be Learned from X-ray Spectroscopy Concerning Hot Gas in Local Bubble and Charge Exchange Processes?

    NASA Technical Reports Server (NTRS)

    Snowden, Steve

    2007-01-01

    What can be learned from x-ray spectroscopy in observing hot gas in local bubble and charge exchange processes depends on spectral resolution, instrumental grasp, instrumental energy band, signal-to-nose, field of view, angular resolution and observatory location. Early attempts at x-ray spectroscopy include ROSAT; more recently, astronomers have used diffuse x-ray spectrometers, XMM Newton, sounding rocket calorimeters, and Suzaku. Future observations are expected with calorimeters on the Spectrum Roentgen Gamma mission, and the Solar Wind Charge Exchange (SWCX). The Geospheric SWCX may provide remote sensing of the solar wind and magnetosheath and remote observations of solar CMEs moving outward from the sun.

  9. Validation of a pH gradient-based ion-exchange chromatography method for high-resolution monoclonal antibody charge variant separations.

    PubMed

    Rea, Jennifer C; Moreno, G Tony; Lou, Yun; Farnan, Dell

    2011-01-25

    Ion-exchange chromatography is widely used for profiling the charge heterogeneity of proteins, including monoclonal antibodies. Despite good resolving power and robustness, ionic strength-based ion-exchange separations are product-specific and time-consuming to develop. We have previously reported a novel pH-based separation of proteins by cation exchange chromatography that was multi-product, high-resolution, and robust against variations in sample matrix salt concentration and pH. In this study, a pH gradient-based separation method using cation exchange chromatography was evaluated in a mock validation. This method was shown to be robust for monoclonal antibodies and suitable for its intended purpose of charge heterogeneity analysis. Simple mixtures of defined buffer components were used to generate the pH gradients that separated closely related antibody species. Validation characteristics, such as precision and linearity, were evaluated. Robustness to changes in protein load, buffer pH and column oven temperature was demonstrated. The stability-indicating capability of this method was determined using thermally stressed antibody samples. In addition, intermediate precision was demonstrated using multiple instruments, multiple analysts, multiple column lots, and different column manufacturers. Finally, the precision for this method was compared to conventional ion-exchange chromatography and imaged capillary isoelectric focusing. These results demonstrate the superior precision and robustness of this multi-product method, which can be used for the high-throughput evaluation of in-process and final product samples.

  10. Ion-exchange molecularly imprinted polymer for the extraction of negatively charged acesulfame from wastewater samples.

    PubMed

    Zarejousheghani, Mashaalah; Schrader, Steffi; Möder, Monika; Lorenz, Pierre; Borsdorf, Helko

    2015-09-11

    Acesulfame is a known indicator that is used to identify the introduction of domestic wastewater into water systems. It is negatively charged and highly water-soluble at environmental pH values. In this study, a molecularly imprinted polymer (MIP) was synthesized for negatively charged acesulfame and successfully applied for the selective solid phase extraction (SPE) of acesulfame from influent and effluent wastewater samples. (Vinylbenzyl)trimethylammonium chloride (VBTA) was used as a novel phase transfer reagent, which enhanced the solubility of negatively charged acesulfame in the organic solvent (porogen) and served as a functional monomer in MIP synthesis. Different molecularly imprinted polymers were synthesized to optimize the extraction capability of acesulfame. The different materials were evaluated using equilibrium rebinding experiments, selectivity experiments and scanning electron microscopy (SEM). The most efficient MIP was used in a molecularly imprinted-solid phase extraction (MISPE) protocol to extract acesulfame from wastewater samples. Using high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS-MS) analysis, detection and quantification limits were achieved at 0.12μgL(-1) and 0.35μgL(-1), respectively. Certain cross selectivity for the chemical compounds containing negatively charged sulfonamide functional group was observed during selectivity experiments.

  11. Temperature dependence of the rate coefficient for charge exchange of metastable O/+//2D/ with N2. [in atmosphere

    NASA Technical Reports Server (NTRS)

    Torr, M. R.; Torr, D. G.

    1980-01-01

    Using a data base of aeronomical parameters measured on board the Atmosphere Explorer-C satellite, temperature dependence of the reaction rate coefficient is deduced for the charge exchange of O(+)(2D) with N2. The results indicate the Explorer values determined over the temperature range from 700 to 1900 K are not in conflict with laboratory measurements made at higher temperatures.

  12. Critical validity assessment of theoretical models: charge-exchange at intermediate and high energies

    NASA Astrophysics Data System (ADS)

    Belkić, Dževad

    1999-06-01

    Exact comprehensive computations are carried out by means of four leading second-order approximations yielding differential cross sections dQ/ dΩ for the basic charge exchange process H ++H(1s)→H(1s)+H + at intermediate and high energies. The obtained extensive set of results is thoroughly tested against all the existing experimental data with the purpose of critically assessing the validity of the boundary corrected second-Born (CB2), continuum-distorted wave (CDW), impulse approximation (IA) and the reformulated impulse approximation (RIA). The conclusion which emerges from this comparative study clearly indicates that the RIA agrees most favorably with the measurements available over a large energy range 25 keV-5 MeV. Such a finding reaffirms the few-particle quantum scattering theory which imposes several strict conditions on adequate second-order methods. These requirements satisfied by the RIA are: (i) normalisations of all the scattering wave functions, (ii) correct boundary conditions in both entrance and exit channels, (iii) introduction of a mathematically justified two-center continuum state for the sum of an attractive and a repulsive Coulomb potential with the same interaction strength, (iv) inclusion of the multiple scattering effects neglected in the IA, (v) a proper description of the Thomas double scattering in good agreement with the experiments and without any unobserved peak splittings. Nevertheless, the performed comparative analysis of the above four approximations indicates that none of the methods is free from some basic shortcomings. Despite its success, the RIA remains essentially a high-energy model like the other three methods under study. More importantly, their perturbative character leaves virtually no room for further systematic improvements, since the neglected higher-order terms are prohibitively tedious for practical purposes and have never been computed exactly. To bridge this gap, we presently introduce the variational Pad

  13. Capillary ion-exchange chromatography with nanogram sensitivity for the analysis of monoclonal antibodies.

    PubMed

    Rea, Jennifer C; Freistadt, Benny S; McDonald, Daniel; Farnan, Dell; Wang, Yajun Jennifer

    2015-12-11

    Ion-exchange chromatography (IEC) is widely used for profiling the charge heterogeneity of proteins, including monoclonal antibodies (mAbs). Despite good resolving power and robustness, ionic strength-based ion-exchange separations are generally product specific and can be time consuming to develop. In addition, conventional analytical scale ion-exchange separations require tens of micrograms of mAbs for each injection, amounts that are often unavailable in sample-limited applications. We report the development of a capillary IEC (c-IEC) methodology for the analysis of nanogram amounts of mAb charge variants. Several key modifications were made to a commercially available liquid chromatography system to perform c-IEC for charge variant analysis of mAbs with nanogram sensitivity. We demonstrate the method for multiple monoclonal antibodies, including antibody fragments, on different columns from different manufacturers. Relative standard deviations of <10% were achieved for relative peak areas of main peak, acidic and basic regions, which are common regions of interest for quantifying monoclonal antibody charge variants using IEC. The results herein demonstrate the excellent sensitivity of this c-IEC characterization method, which can be used for analyzing charge variants in sample-limited applications, such as early-stage candidate screening and in vivo studies.

  14. Observation and modeling of geocoronal charge exchange X-ray emission during solar wind gusts

    SciTech Connect

    Wargelin, B. J.; Kornbleuth, M.; Juda, M.; Martin, P. L.

    2014-11-20

    Solar wind charge exchange (SWCX) X-rays are emitted when highly charged solar wind ions such as O{sup 7{sup +}} collide with neutral gas, including the Earth's tenuous outer atmosphere (exosphere or geocorona) and hydrogen and helium from the local interstellar medium drifting through the heliosphere. This geocoronal and heliospheric emission comprises a significant and varying fraction of the soft X-ray background (SXRB) and is seen in every X-ray observation, with the intensity dependent on solar wind conditions and observation geometry. Under the right conditions, geocoronal emission can increase the apparent SXRB by roughly an order of magnitude for an hour or more. In this work, we study a dozen occasions when the near-Earth solar wind flux was exceptionally high. These gusts of wind lead to abrupt changes in SWCX X-ray emission around Earth, which may or may not be seen by X-ray observatories depending on their line of sight. Using detailed three-dimensional magnetohydrodynamical simulations of the solar wind's interaction with the Earth's magnetosphere, and element abundances and ionization states measured by ACE, we model the time-dependent brightness of major geocoronal SWCX emission lines during those gusts and compare with changes in the X-ray background measured by the Chandra X-ray Observatory. We find reasonably good agreement between model and observation, with measured geocoronal line brightnesses averaged over 1 hr of up to 136 photons s{sup –1} cm{sup –2} sr{sup –1} in the O VII Kα triplet around 564 eV.

  15. Mechanistic modeling of ion-exchange process chromatography of charge variants of monoclonal antibody products.

    PubMed

    Kumar, Vijesh; Leweke, Samuel; von Lieres, Eric; Rathore, Anurag S

    2015-12-24

    Ion-exchange chromatography (IEX) is universally accepted as the optimal method for achieving process scale separation of charge variants of a monoclonal antibody (mAb) therapeutic. These variants are closely related to the product and a baseline separation is rarely achieved. The general practice is to fractionate the eluate from the IEX column, analyze the fractions and then pool the desired fractions to obtain the targeted composition of variants. This is, however, a very cumbersome and time consuming exercise. A mechanistic model that is capable of simulating the peak profile will be a much more elegant and effective way to make a decision on the pooling strategy. This paper proposes a mechanistic model, based on the general rate model, to predict elution peak profile for separation of the main product from its variants. The proposed approach uses inverse fit of process scale chromatogram for estimation of model parameters using the initial values that are obtained from theoretical correlations. The packed bed column has been modeled along with the chromatographic system consisting of the mixer, tubing and detectors as a series of dispersed plug flow and continuous stirred tank reactors. The model uses loading ranges starting at 25% to a maximum of 70% of the loading capacity and hence is applicable to process scale separations. Langmuir model has been extended to include the effects of salt concentration and temperature on the model parameters. The extended Langmuir model that has been proposed uses one less parameter than the SMA model and this results in a significant ease of estimating the model parameters from inverse fitting. The proposed model has been validated with experimental data and has been shown to successfully predict peak profile for a range of load capacities (15-28mg/mL), gradient lengths (10-30CV), bed heights (6-20cm), and for three different resins with good accuracy (as measured by estimation of residuals). The model has been also

  16. Testing and analysis of immersed heat exchangers

    SciTech Connect

    Farrington, R.B.; Bingham, C.E.

    1986-08-01

    The objectives were to determine the performance of four immersed, ''supply-side'' heat exchangers used in solar domestic-hot-water systems; to examine the effects of flow rate, temperature difference, and coil configuration on performance; and to develop a simple model to predict the performance of immersed heat exchangers. We tested four immersed heat exchangers: a smooth coil, a finned spiral, a single-wall bayonet, and a double-wall bayonet. We developed two analyticl models and a simple finite difference model. We experimentally verified that the performance of these heat exchangers depends on the flow rate through them; we also showed that the temperature difference between the heat exchanger's inlet and the storage tank can strongly affect a heat exchanger's performance. We also compared the effects of the heat exchanger's configuration and correlated Nusselt and Rayleigh numbers for each heat exchanger tested. The smooth coil had a higher effectiveness than the others, while the double-wall bayonet had a very low effectiveness. We still do not know the long-term effectiveness of heat exchangers regarding scale accumulation, nor do we know the effects of very low flow rates on a heat exchanger's performance.

  17. Spectroscopic evidence of charge exchange X-ray emission from galaxies

    NASA Astrophysics Data System (ADS)

    Wang, Q. D.; Liu, J.

    2012-04-01

    What are the origins of the soft X-ray line emission from non-AGN galaxies? XMM-Newton RGS spectra of nearby non-AGN galaxies (including starforming ones: M82, NGC 253, M51, M83, M61, NGC 4631, M94, NGC 2903, and the Antennae galaxies, as well as the inner bulge of M31) have been analyzed. In particular, the K\\alpha triplet of O VII shows that the resonance line is typically weaker than the forbidden and/or inter-combination lines. This suggests that a substantial fraction of the emission may not arise directly from optically thin thermal plasma, as commonly assumed, and may instead originate at its interface with neutral gas via charge exchange. This latter origin naturally explains the observed spatial correlation of the emission with various tracers of cool gas in some of the galaxies. However, alternative scenarios, such as the resonance scattering by the plasma and the relic photo-ionization by AGNs in the recent past, cannot be ruled out, at least in some cases, and are being examined. Such X-ray spectroscopic studies are important to the understanding of the relationship of the emission to various high-energy feedback processes in galaxies.

  18. Charge-exchange reactions and nuclear matrix elements for {beta}{beta} decay

    SciTech Connect

    Frekers, D.

    2009-11-09

    Charge-exchange reactions of (n, p) and (p, n) type at intermediate energies are a powerful tool for the study of nuclear matrix element in {beta}{beta} decay. The present paper reviews some of the most recent experiments in this context. Here, the (n, p) type reactions are realized through (d, {sup 2}He), where {sup 2}He refers to two protons in a singlet {sup 1}S{sub 0} state and where both of these are momentum analyzed and detected by the same spectrometer and detector. These reactions have been developed and performed exclusively at KVI, Groningen (NL), using an incident deuteron energy of 183 MeV. Final state resolutions of about 100 keV have routinely been available. On the other hand, the ({sup 3}He, t) reaction is of (p, n) type and was developed at the RCNP facility in Osaka (JP). Measurements with an unprecedented high resolution of 30 keV at incident energies of 420 MeV are now readily possible. Using both reaction types one can extract the Gamow-Teller transition strengths B(GT{sup +}) and B(GT{sup -}), which define the two ''legs'' of the {beta}{beta} decay matrix elements for the 2v{beta}{beta} decay The high resolution available in both reactions allows a detailed insight into the excitations of the intermediate odd-odd nuclei and, as will be shown, some unexpected features are being unveiled.

  19. X-ray emission from the local hot bubble and solar wind charge exchange

    NASA Astrophysics Data System (ADS)

    Uprety, Youaraj

    DXL (Diffuse X-rays from the Local galaxy) is a sounding rocket mission to quantify the Solar Wind Charge Exchange (SWCX) X-ray emission in the interplanetary medium, and separate its contribution from the Local Hot Bubble (LHB) emission. The first launch of DXL took place in December 2012. This thesis will describe the DXL instrumentation and calibrations, and discuss the results obtained. The mission uses two large area proportional counters to scan through the Helium Focusing Cone (HFC), a high helium density region in the solar system emitting excess X-rays due to SWCX. Using well determined models of the interplanetary neutral distribution and comparing the DXL results with data from the same region obtained by the ROSAT satellite away from the cone, we calculated that SWCX contributes at most 36% to the ¼ keV ROSAT band and 13% to the ¾ keV ROSAT band, in the galactic plane. This provides a firm proof for existence of a LHB which dominates the Diffuse X-ray Background (DXB) at ¼ keV, while raising new questions on the origin of the ¾ keV emission.

  20. Temperatures of individual ion species and heating due to charge exchange in the ionosphere of Venus

    NASA Technical Reports Server (NTRS)

    Kim, Jhoon; Nagy, Andrew F.; Cravens, Thomas E.; Shinagawa, Hiroyuki

    1990-01-01

    The coupled electron and multispecies ion energy equations were solved for daytime conditions in the Venus ionosphere. The heating rates due to charge exchange between hot oxygen atoms and thermal oxygen ions were calculated and incorporated into the energy equations. The combination of the traditional EUV heating and this hot oxygen energy source leads to calculated electron and individual ion temperatures significantly lower than the measured values during solar cycle maximum conditions. Calculations were also carried out for solar cycle minimum conditions, which led to considerably lower temperatures; no data are available which would allow direct comparisons of these results with measurements. In order to obtain calculated temperature values consistent with the observed ones, for solar cycle maximum conditions, topside heat inflows into the ion and electron gases have to be introduced or the thermal conductivity must be reduced by considering the effect of steady and fluctuating magnetic fields, as was done in previous studies. The addition of hot oxygen heating leads to minor increases in the calculated ion temperatures except for the case of reduced thermal conductivities. Separate temperatures were calculated for each ion species for a number of different conditions and in general the differences were found to be relatively small.

  1. Suzaku and XMM-Newton observations of the North Polar Spur: Charge exchange or ISM absorption?

    NASA Astrophysics Data System (ADS)

    Gu, Liyi; Mao, Junjie; Costantini, Elisa; Kaastra, Jelle

    2016-10-01

    By revisiting the Suzaku and XMM-Newton data of the North Polar Spur, we discovered that the spectra are inconsistent with the traditional model consisting of pure thermal emission and neutral absorption. The most prominent discrepancies are the enhanced O vii and Ne ix forbidden-to-resonance ratios, and a high O viii Lyβ line relative to other Lyman series. A collisionally ionized absorption model can naturally explain both features, while a charge exchange component can only account for the former. By including the additional ionized absorption, the plasma in the North Polar Spur can be described by a single-phase collisional ionization equilibrium (CIE) component with a temperature of 0.25 keV, and nitrogen, oxygen, neon, magnesium, and iron abundances of 0.4-0.8 solar. The abundance pattern of the North Polar Spur is well in line with those of the Galactic halo stars. The high nitrogen-to-oxygen ratio reported in previous studies can be migrated to the large transmission of the O viii Lyα line. The ionized absorber is characterized by a balance temperature of 0.17-0.20 keV and a column density of 3-5 × 1019 cm-2. Based on the derived abundances and absorption, we speculate that the North Polar Spur is a structure in the Galactic halo, so that the emission is mostly absorbed by the Galactic interstellar medium in the line of sight.

  2. On charge exchange and knock-on processes in the exosphere of Io

    NASA Technical Reports Server (NTRS)

    Ip, W.-H.

    1982-01-01

    One direct consequence of magnetospheric interaction of Io is the strong dynamical coupling of its neutral atmosphere with the corotating plasma. The absorption of the thermal ions and the associated neutral injection is an improtant issue not yet explored. As far as nonthermal escape of the neutral atmosphere is concerned, three processes stand out. That is, apart from sputtering, exospheric interactions like atom-ion knock-on collision and charge exchange recombination could be a significant source of the neutral clouds in the Jovian system. Using a current electrodynamic model of Io, both the absorption rate of the corotating thermal plasma and the production rates of new exospheric ions and the fast neutrals are considered. It is found that the source strength of the neutral atoms and molecules with speeds of about 100 km/sec could amount to 10 to the 26th/sec whereas exospheric neutrals emitted at lower speed (of about 10 km/sec) amounts to 4 x 10 to the 25th/sec. The generation of the new ions in connection with the streaming of the magnetospheric plasma around Io could also produce an asymmetric sputtering with a neutral flux of about 10 to the 27th/sec emitted from the region of Io which faces Jupiter. These results may be related to a number of sodium observations.

  3. Analysis of proton exchange kinetics with time-dependent exchange rate.

    PubMed

    Rutkowska-Wlodarczyk, Izabela; Kierdaszuk, Borys; Wlodarczyk, Jakub

    2010-04-01

    Mass spectrometry is used to probe the kinetics of hydrogen-deuterium exchange in lysozyme in pH 5, 6 and 7.4. An analysis based on a Verhulst growth model is proposed and effectively applied to the kinetics of the hydrogen exchange. The data are described by a power-like function which is based on a time-dependence of the exchange rate. Experimental data ranging over many time scales is considered and accurate fits of a power-like function are obtained. Results of fittings show correlation between faster hydrogen-deuterium exchange and increase of pH. Furthermore a model is presented that discriminates between easily exchangeable hydrogens (located in close proximity to the protein surface) and those protected from the exchange (located in the protein interior). A possible interpretation of the model and its biological significance are discussed.

  4. Protein adsorption on ion exchange resins and monoclonal antibody charge variant modulation.

    PubMed

    Guélat, Bertrand; Khalaf, Rushd; Lattuada, Marco; Costioli, Matteo; Morbidelli, Massimo

    2016-05-20

    A novel multicomponent adsorption equilibrium model for proteins on ion-exchange resins is developed on a statistical thermodynamic basis including surface coverage effects and protein-resin and protein-protein interactions. The resulting model exhibits a general competitive Langmuirian behavior and was applied to the study and optimization of the separation of monoclonal antibody charge variants on two strong cation exchangers. The model accounts explicitly for the effect of both pH and salt concentration, and its parameters can be determined in diluted conditions, that is, through physically sound assumptions, all model parameters can be obtained using solely experiments in diluted conditions, and be used to make predictions in overloaded conditions. The parameterization of the model and optimization of the separation is based on a two-step approach. First, gradient experiments in diluted conditions are undertaken in order to determine the model parameters. Based on these experiments and on information about the proteins of interest and the stationary phase used, all the model parameters can be estimated. Second, using the parameterized model, an initial Pareto optimization is undertaken where overloaded operating conditions are investigated. Experiments from this Pareto set are then used to refine the estimation of the model parameters. A second Pareto optimization can then be undertaken, this time with the refined parameters. This can be repeated until a satisfactory set of model parameters is found. This iterative approach is shown to be extremely efficient and to provide large amounts of knowledge based on only a few experiments. It is shown that due to the strong physical foundation of the model and the very low number of adjustable parameters, the number of iterations is expected to be at most two or three. Furthermore, the model based tool is improved as more experimental knowledge is provided, allowing for better estimations of the chromatographic

  5. Effects of exchanged cation and layer charge on the sorption of water and EGME vapors on montmorillonite clays

    USGS Publications Warehouse

    Chiou, C.T.; Rutherford, D.W.

    1997-01-01

    The effects of exchanged cation and layer charge on the sorption of water and ethylene glycol monoethyl ether (EGME) vapors on montmorillonite have been studied on SAz-1 and SWy-1 source clays, each exchanged respectively with Ca, Na, K, Cs and tetramethylammonium (TMA) cations. The corresponding lattice expansions were also determined, and the corresponding N2 adsorption data were provided for comparison. For clays exchanged with cations of low hydrating powers (such as K, Cs and TMA), water shows a notably lower uptake than does N2 at low relative pressures (P/P0). By contrast, EGME shows higher uptakes than N2 on all exchanged clays at all P/P0. The anomaly for water is attributed to its relatively low attraction for siloxane surfaces of montmorillonite because of its high cohesive energy density. In addition to solvating cations and expanding interlayers, water and EGME vapors condense into small clay pores and interlayer voids created by interlayer expansion. The initial (dry) interlayer separation varies more significantly with cation type than with layer charge; the water-saturated interlayer separation varies more with cation type than the EGME-saturated interlayer separation. Because of the differences in surface adsorption and interlayer expansion for water and EGME, no general correspondence is found between the isotherms of water and EGME on exchanged clays, nor is a simple relation observed between the overall uptake of either vapor and the cation solvating power. The excess interlayer capacities of water and of EGME that result from lattice expansion of the exchanged clays are estimated by correcting for amounts of vapor adsorption on planar clay surfaces and of vapor condensation into intrinsic clay pores. The resulting data follow more closely the relative solvating powers of the exchanged cations.

  6. Charge variant analysis of proposed biosimilar to Trastuzumab.

    PubMed

    Dakshinamurthy, Pravinkumar; Mukunda, Pavithra; Prasad Kodaganti, Bhargav; Shenoy, Bharath Ravindra; Natarajan, Bairavabalakumar; Maliwalave, Amol; Halan, Vivek; Murugesan, Sathyabalan; Maity, Sunit

    2017-03-01

    Trastuzumab is a humanized monoclonal antibody (mAb) employed for the treatment of HER2 Positive Breast Cancer. A HER2 overexpressing tumor cell binds to Trastuzumab and attracts immune cells which lead to induction of Antibody Dependent Cellular Cytotoxicity (ADCC) by binding to Fc receptors (CD16a or FcγRIIIa) on an effector cell, such as natural killer (NK) cells. The most commonly expressed receptor on NK cell is CD16a which binds to the Fc portion of Trastuzumab. The ligand-independent HER2-HER3 dimerization is the most potent stimulator of downstream pathways for regulation of cell growth and survival. An attempt has been made in this study to understand the impact of charge heterogeneity on the binding kinetics and potency of the monoclonal antibody. Trastuzumab has a pI range of 8.7-8.9 and is composed of mixture of acidic and basic variants beside the main peak. Ion exchange chromatography was used to isolate the acidic, basic, and main peak fractions from in-house proposed biosimilar to Trastuzumab and their activities were compared to the Innovator Trastuzumab Herclon(®). Data from the mass analysis confirmed the potential modifications in both acidic and basic variant. Binding activity studies performed using Surface Plasmon Resonance (SPR) revealed that acidic variants had lesser binding to HER2 in comparison to the basic variants. Both acidic and basic variant showed no significant changes in their binding to soluble CD16a receptors. In vitro assay studies using a breast cancer cell line (BT-474) confirmed the binding potency of acidic variant to be lesser than basic variant, along with reduced anti-proliferative activity for the acidic variant of Trastuzumab. Overall, these data has provided meaningful insights to the impact of antibody charge variants on in vitro potency and CD16 binding affinity of trastuzumab.

  7. Semiautomated pH gradient ion-exchange chromatography of monoclonal antibody charge variants.

    PubMed

    Talebi, Mohammad; Shellie, Robert A; Hilder, Emily F; Lacher, Nathan A; Haddad, Paul R

    2014-10-07

    A new approach using a chromatography system equipped with isocratic pumps and an electrolytic eluent generator (EG) is introduced, replacing external pH gradient delivery using conventional gradient systems, in which bottled buffers with preadjusted pH are mixed using a gradient pump. The EG is capable of generating high purity base or acid required for online preparation of the buffer at the point of use, utilizing deionized water as the only carrier stream. Typically, the buffer was generated from online titration of a reagent composed of low molecular weight amines. The reagent was delivered isocratically into a static mixing tee, where it was titrated to the required pH with electrolytically generated base or acid. The required pH gradient was thus conveniently generated by electrically controlling the concentration of titrant. Also, since the pH was adjusted at the point of use, this approach offered enhanced throughput in terms of eluent preparation time and labor, and with a more reproducible pH profile. The performance of the system was demonstrated by running pH gradients ranging from pH 8.2 to 10.9 on a polymer monolith cation-exchange column for high throughput profiling of charge heterogeneity of intact, basic therapeutic monoclonal antibodies. A high degree of flexibility in modulating the key parameters of the pH gradient, including the buffer concentration, the pH gradient slope and the operating pH range was demonstrated. This enabled fine-tuning of the separation conditions for each individual antibody in order to enhance the chromatographic resolution.

  8. Solar Wind Charge Exchange Contribution to the ROSAT All Sky Survey Maps

    NASA Astrophysics Data System (ADS)

    Uprety, Y.; Chiao, M.; Collier, M. R.; Cravens, T.; Galeazzi, M.; Koutroumpa, D.; Kuntz, K. D.; Lallement, R.; Lepri, S. T.; Liu, W.; McCammon, D.; Morgan, K.; Porter, F. S.; Prasai, K.; Snowden, S. L.; Thomas, N. E.; Ursino, E.; Walsh, B. M.

    2016-10-01

    DXL (Diffuse X-ray emission from the Local Galaxy) is a sounding rocket mission designed to estimate the contribution of solar wind charge eXchange (SWCX) to the diffuse X-ray background and to help determine the properties of the Local Hot Bubble. The detectors are large area thin-window proportional counters with a spectral response that is similar to that of the PSPC used in the ROSAT All Sky Survey (RASS). A direct comparison of DXL and RASS data for the same part of the sky viewed from quite different vantage points in the solar system, and the assumption of approximate isotropy for the solar wind, allowed us to quantify the SWCX contribution to all six RASS bands (R1-R7, excluding R3). We find that the SWCX contribution at l=140^\\circ ,b=0^\\circ , where the DXL path crosses the Galactic plane, is 33 % +/- 6 % ({statistical})+/- 12 % ({systematic}) for R1, 44 % +/- 6 % +/- 5 % for R2, 18 % +/- 12 % +/- 11 % for R4, 14 % +/- 11 % +/- 9 % for R5, and negligible for the R6 and R7 bands. Reliable models for the distribution of neutral H and He in the solar system permit estimation of the contribution of interplanetary SWCX emission over the the whole sky and correction of the RASS maps. We find that the average SWCX contribution in the whole sky is 26 % +/- 6 % +/- 13 % for R1, 30 % +/- 4 % +/- 4 % for R2, 8 % +/- 5 % +/- 5 % for R4, 6 % +/- 4 % +/- 4 % for R5, and negligible for R6 and R7.

  9. The TFTR E Parallel B Spectrometer for Mass and Energy Resolved Multi-Ion Charge Exchange Diagnostics

    SciTech Connect

    A.L. Roquemore; S.S. Medley

    1998-01-01

    The Charge Exchange Neutral Analyzer diagnostic for the Tokamak Fusion Test Reactor was designed to measure the energy distributions of both the thermal ions and the supra thermal populations arising from neutral-beam injection and ion cyclotron radio-frequency heating. These measurements yield the plasma ion temperature, as well as several other plasma parameters necessary to provide an understanding of the plasma condition and the performance of the auxiliary heating methods. For this application, a novel charge-exchange spectrometer using a dee-shaped region of parallel electric and magnetic fields was developed at the Princeton Plasma Physics Laboratory. The design and performance of this spectrometer is described in detail, including the effects of exposure of the microchannel plate detector to magnetic fields, neutrons, and tritium.

  10. Heavy-ion double charge exchange reactions: A tool toward 0 νββ nuclear matrix elements

    NASA Astrophysics Data System (ADS)

    Cappuzzello, F.; Cavallaro, M.; Agodi, C.; Bondì, M.; Carbone, D.; Cunsolo, A.; Foti, A.

    2015-11-01

    The knowledge of the nuclear matrix elements for the neutrinoless double beta decay is fundamental for neutrino physics. In this paper, an innovative technique to extract information on the nuclear matrix elements by measuring the cross section of a double charge exchange nuclear reaction is proposed. The basic point is that the initial- and final-state wave functions in the two processes are the same and the transition operators are similar. The double charge exchange cross sections can be factorized in a nuclear structure term containing the matrix elements and a nuclear reaction factor. First pioneering experimental results for the 40Ca(18O,18Ne)40Ar reaction at 270 MeV incident energy show that such cross section factorization reasonably holds for the crucial 0+ → 0+ transition to 40Args, at least at very forward angles.

  11. Upper-limit charge exchange cross sections for mercury (plus) on molybdenum and cesium (plus) on aluminum

    NASA Technical Reports Server (NTRS)

    Dugan, J. V., Jr.

    1972-01-01

    Upper-limit charge exchange cross sections are calculated for Hg(+) on Mo and Cs(+) on Al. The cross sections are calculated from the polarization interaction at low ion energies (1 to 500 eV) and by assuming favorable curve crossings with a hard-core reaction radius at higher energies (500 eV to 10 keV). The cross sections for Hg(+) on Mo becomes greater than corresponding Hg Hg(+) resonance values at ion energies below 2 eV, whereas the Cs(+) Al values remain considerably lower than the Cs(+)Cs resonance value at all ion energies. It is also shown that charge exchange of slow Hg(+) with Mo may be important for spacecraft with electron bombardment thrusters.

  12. Method for decomposing observed line shapes resulting from multiple causes - Application to plasma charge-exchange-neutral spectra

    NASA Technical Reports Server (NTRS)

    Patch, R. W.

    1979-01-01

    A method is given for decomposing the widths of observed spectral lines resulting from unresolved line splitting, additive kinetic processes of different types, instrumental broadening (slit function), Doppler broadening, etc. all superimposed. The second moments are used as measures of the various widths involved. The method is not applicable if dispersion type (Lorentz) broadening occurs. Application is made to plasma charge-exchange-neutral spectra of hydrogen, deuterium, and helium.

  13. High-resolution Crystal Spectroscopy of Charge-Exchange Produced K-shell X-ray Emission Lines

    NASA Astrophysics Data System (ADS)

    Beiersdorfer, P.; Bitter, M.; Olson, R.; Marion, M.

    2005-05-01

    Charge-exchange spectral models needed to describe and predict the X-ray emission of cometary and planetary atmospheres interacting with solar wind heavy ions are under development and require laboratory data for guidance. The relative intensity of the four K-shell emission lines in heliumlike ions is particularly uncertain, as the individual lines have not yet been fully resolved in charge-exchange-produced spectra. Using a high-resolution crystal spectrometer, we have measured the charge exchange induced K-shell X-ray emission from Ar16+ following the interaction of Ar17+ ions with fast, 40 keV/amu deuterium atoms. The measurement was performed on the National Spherical Torus Experiment (NSTX). The Ar17+ ions were constituents of the plasma, while deuterium was injected via a 80 keV neutral beam. During the brief, 20 ms neutral beam injection emission from electron-impact collisions ceases, and X-ray line emission is solely due to charge exchange. The measurement fully resolves the resonance, intercombination, and forbidden lines. We have constructed a complete radiative cascade model of Ar16+ that includes electron capture into levels as high as n=29 and all E1, M1, E2, and M2 radiative transitions. We find excellent agreement between the model and the NSTX crystyal spectrum. We will present these findings as well as our predictions of the emission in other spectral bands from the optical and extreme ultraviolet to the soft X-ray region. This work was performed under the auspices of the U.S. DOE by UC-LLNL under contract W-7405-Eng-48, by UMR under contract DE-FG02-84ER53175, and by PPPL under contract DE-AC02-76CHO3073.

  14. Spacecraft Charging Analysis of a CubeSat

    NASA Technical Reports Server (NTRS)

    Willis, Emily M.; Minow, Joseph I.; Parker, Linda Neergaard

    2014-01-01

    Spacecraft charging occurs when charged particles from the surrounding space plasma environment contact a spacecraft and unequal charging currents result in a net charge density accumulation on or in spacecraft materials. Charging becomes a threat when differential potentials between two points on the spacecraft or between the spacecraft and the ambient space environment build to the level that electric fields associated with the potentials exceed the electric breakdown strength of the spacecraft materials and electrostatic discharge arcs are generated. Electrostatic discharges resulting from spacecraft charging can adversely affect telemetry and cause irreparable damage to electronics. Other spacecraft charging effects include damage of solar arrays and thermal protection, enhancement of contamination of surfaces, and degradation of optics. Typically, the large government and commercial space programs include spacecraft charging analysis as part of the design process. CubeSat projects, however, usually do not have the time or funding to include a spacecraft charging analysis due to their low budget and quick-turnaround requirements. CubeSat projects also tend to rely heavily on commercial "off-the-shelf" products, many of which are not qualified for use in space, and are particularly vulnerable to the effects of the space environment. As the demand for longer and more complex CubeSat missions increases, it is becoming more and more important to consider the effects of spacecraft charging in the design process. Results of surface charging analysis using Nascap-2k on a typical CubeSat design for a polar orbit scenario are illustrated. These results show that for a polar orbiting CubeSat, spacecraft charging could be an issue and steps should be taken to mitigate the effects for these small satellites.

  15. Charge exchange produced K-shell x-ray emission from Ar16+ in a tokamak plasma with neutral beam injection

    SciTech Connect

    Beiersdorfer, P; Bitter, M; Marion, M; Olson, R E

    2004-12-27

    High-resolution spectroscopy of hot tokamak plasma seeded with argon ions and interacting with an energetic, short-pulse neutral hydrogen beam was used to obtain the first high-resolution K-shell x-ray spectrum formed solely by charge exchange. The observed K-shell emission of Ar{sup 16+} is dominated by the intercombination and forbidden lines, providing clear signatures of charge exchange. Results from an ab initio atomic cascade model provide excellent agreement, validating a semiclassical approach for calculating charge exchange cross sections.

  16. Determination of {sup 16}O and {sup 18}O sensitivity factors and charge-exchange processes in low-energy ion scattering

    SciTech Connect

    Tellez, H.; Chater, R. J.; Fearn, S.; Symianakis, E.; Kilner, J. A.; Brongersma, H. H.

    2012-10-08

    Quantitative analysis in low-energy ion scattering (LEIS) requires an understanding of the charge-exchange processes to estimate the elemental sensitivity factors. In this work, the neutralization of He{sup +} scattered by {sup 18}O-exchanged silica at energies between 0.6 and 7 keV was studied. The process is dominated by Auger neutralization for E{sub i} < 0.8 keV. An additional mechanism starts above the reionization threshold. This collision-induced neutralization becomes the dominant mechanism for E{sub i} > 2 keV. The ion fractions P{sup +} were determined for Si and O using the characteristic velocity method to quantify the surface density. The {sup 18}O/{sup 16}O sensitivity ratio indicates an 18% higher sensitivity for the heavier O isotope.

  17. Dynamic Analysis of Capture Devices for Momentum Exchange with Tethers

    NASA Technical Reports Server (NTRS)

    Canfield, Stephen

    2002-01-01

    One of the significant challenges in developing a momentum exchange / electrodynamic reboost tether system is in the analysis and design of the capture device and its effects on the overall dynamics of the system. The goal of this work is to develop appropriate tether momentum exchange models that can simulate and evaluate the requirements of such a system, and be used to create specifications on the design of a capture device. This report briefly describes dynamic model development, simulation of the momentum exchange process, evaluation of dynamic effects of errors in the momentum exchange process, and the development of guidelines in selecting dynamic properties in the design of a capture device.

  18. Charge exchange spectroscopy of multiply charged ions for the development of the EUV light source for the next generation photo lithography

    NASA Astrophysics Data System (ADS)

    Tanuma, Hajime

    2015-09-01

    As a candidate of an extreme ultra-violet (EUV) light source for a next generation lithography, laser produced plasmas (LPP) of Xe and Sn have been investigated intensively in this decade because these plasmas have a strong emission around 13.5 nm which had been determined as the wavelength for the EUV lithography. This emission was considered to be due to multiply charged Xe and Sn ions in hot plasmas. However, the detail atomic spectroscopic data of these multiply charged heavy ions had not been reported yet. To provide atomic data for the understanding and development of the LPP as the EUV light source, we have observed the EUV emission spectra from individual charge states of Xe and Sn ions by means of a charge exchange spectroscopy method. Multiply charged Xeq+ (q = 7-23) and Snq+ (q = 5-21) ions were produced with a 14.25 GHz electron cyclotron resonance ion source, and a charge-selected ion beam was directed into a collision chamber, where the ion interact with a target gas of He and Xe. EUV emissions from the collision center were observed with a compact flat-field grazing-incident spectrometer equipped with a liquid nitrogen cooled CCD camera. In experiments using Xe ions, we have found only Xe XI has a strong UTA (unresolved transition array) around 13.5 nm. On the other hand, various charge states of Sn from VIII to XIV contribute to the 13.5 nm emission. Identification of the transition lines was carried out by calculations using the Hebrew university Livermore laboratory atomic physics code and the Cowan code. Most of the emissions in the EUV region are attributed to the 4p-4d and 4d- nl (nl = 4f, 5p, and 5f) transitions. However, the 4d-4f transitions have approximately constant differences of about 0.5 nm between the experimental and theoretical results. This can be explained by considering the strong configuration interactions in the n=4 subshells. Using the experimental transition wavelengths of multiply charged Sn ions, theoretical modeling of

  19. Removing Spectral Diagnostics of Galactic and Stellar X-Ray Emission from Charged Exchange Recombination

    NASA Technical Reports Server (NTRS)

    Wargelin, Brad

    2004-01-01

    Our research uses the electron beam ion trap (EBIT) at the Lawrence Livermore National Laboratory to study X-ray emission from the charge exchange (CX) of highly charged ions with neutral gases. The resulting data help to fill a void in existing experimental and theoretical understanding of this atomic physics process, and are needed to explain all or part of the observed X-ray emission from the soft X-ray background, stellar winds, the Galactic Center and Galactic Ridge, supernova ejecta, and photoionized nebulae. Appreciation of the astrophysical relevance of our work continues to grow with the publication of roughly a dozen papers in the past four years describing Chandra and XMM observations of geocoronal and heliospheric CX emission, the temporal variation of such emission and correlation with X-ray emission enhancements observed by ROSAT, the theoretical spatial distribution of that emission, and CX emission around other stars. A similar number of papers were also published during that time describing CX emission from planets and comets. We expect that the launch of ASTRSE2, with its second-generation XRS microcalo- (with 6-eV resolution), will reveal even more clearly the contributions of CX to astrophysical emission. In our EBIT work we collected CX spectra from such ions as H-like and He-like Ne, Ar, and Fe. Our early measurements were made with a high-purity Ge detector, but during the second year we began operation of the first-generation XRS microcalorimeter (a twin of the XRS on ASTRO-E) and greatly improved the resolution of our measurements from roughly 150 eV (FWHM) with the Ge detectors to 10 eV with the XRS. We found that saturation of the XRS counting apparatus, which we described in our proposal as a potential concern, is not a problem for studying CX. During the course of our research, we expanded the number of injection gases permitted by the LLNL safety team, purchased and eventually operated an atomic H source, and clearly demonstrated the

  20. Solar Wind Charge Exchange Contribution To The ROSAT Sky Survey Maps

    NASA Technical Reports Server (NTRS)

    Uprety, Y.; Chiao, M.; Collier, M. R.; Cravens, T.; Galeazzi, M.; Koutroumpa, D.; Kuntz, K. D.; Lallement, R.; Lepri, S. T.; Liu, W.; McCammon, D.; Morgan, K.; Porter, F. S.; Prasai, K.; Snowden, S. L.; Thomas, N. E.; Ursino, E.; Walsh, B. M.

    2016-01-01

    DXL (Diffuse X-ray emission from the Local Galaxy) is a sounding rocket mission designed to estimate the contribution of solar wind charge eXchange (SWCX) to the diffuse X-ray background and to help determine the properties of the Local Hot Bubble. The detectors are large area thin-window proportional counters with a spectral response that is similar to that of the PSPC (Position Sensitive Proportional Counters) used in the ROSAT All Sky Survey (RASS). A direct comparison of DXL and RASS data for the same part of the sky viewed from quite different vantage points in the solar system, and the assumption of approximate isotropy for the solar wind, allowed us to quantify the SWCX contribution to all six RASS bands (R1-R7, excluding R3). We find that the SWCX contribution at l = 140 degrees, b = 0 degrees, where the DXL path crosses the Galactic plane, is 33 percent plus or minus 6 percent (statistical) plus or minus 12 percent (systematic) for R1, 44 percent plus or minus 6 percent plus or minus 5 percent for R2, 18 percent plus or minus 12 percent plus or minus 11 percent for R4, 14 percent plus or minus 11 percent plus or minus 9 percent for R5, and negligible for the R6 and R7 bands. Reliable models for the distribution of neutral H and He in the solar system permit estimation of the contribution of interplanetary SWCX emission over the the whole sky and correction of the RASS maps. We find that the average SWCX contribution in the whole sky is 26 percent plus or minus 6 percent plus or minus 13 percent for R1, 30 percent plus or minus 4 percent plus or minus 4 percent for R2, 8 percent plus or minus 5 percent plus or minus 5 percent for R4, 6 percent plus or minus 4 percent plus or minus 4 percent for R5, and negligible for R6 and R7.

  1. Measurement of the left-right asymmetry in pion-proton radiative exchange and charge exchange scattering from 301 to 625 MeV/c on a transversely polarized target

    SciTech Connect

    Kim, George Jung-Kwang

    1988-05-01

    The left-right asymmetry A/sub N/ in ..pi../sup /minus//p ..-->.. ..gamma..n has been measured at p/sub ..pi.. = 301, 316, 427, 471, 547, 586, and 625 MeV/c using a transversely polarized target. The final-state neutron and gamma were detected in coincidence by two states of matching neutron and gamma detectors at gamma angles centered around 90/degree and 110/degree/ c.m. A gamma detector consisted of an array of 15 counters, each was 15/times/15/times/25 cm/sup 3/ block of lead-glass. A neutron detector consisted of 15 counters also, each one was a cylindrical plastic scintillator 7.6 cm in diameter and 45.7 cm long. The A/sub N/ results are compared with the predictions from the most recent single-pion photoproduction partial-wave analysis by Arai and Fujii. The agreement is poor, casting doubt on the correctness of the value for the radiative-decay amplitude of the neutral Roper resonance now in use. A comparison is made with the 90/degree/recoil proton polarization data of the inverse reaction derived from ..gamma..d scattering, there are substantial discrepencies. Charge exchange (..pi../sup /minus/p/ ..-->.. ..gamma../degree/n) events were the major yield in this experiment. Very precise values of the charge exchange analyzing power were obtained with an error of typically 3%. The charge exchange results are compared with the predictions from recent ..gamma..n partial wave analyses. At the lower incident energies little difference is seen between the VPI, Karlsruhe-Helsinki, and CMU-LBL analyses, and there is excellent agreement with our experiment. From the onset of the Roper resonance the VPI solution is strongly favored.

  2. Analysis of a Flooded Heat Exchanger

    ERIC Educational Resources Information Center

    Fink, Aaron H.; Luyben, William L.

    2015-01-01

    Flooded heat exchangers are often used in industry to reduce the required heat-transfer area and the size of utility control valves. These units involve a condensing vapor on the hot side that accumulates as a liquid phase in the lower part of the vessel. The heat transfer occurs mostly in the vapor space, but the condensate becomes somewhat…

  3. Analysis of electrolyte transport through charged nanopores

    NASA Astrophysics Data System (ADS)

    Peters, P. B.; van Roij, R.; Bazant, M. Z.; Biesheuvel, P. M.

    2016-05-01

    We revisit the classical problem of flow of electrolyte solutions through charged capillary nanopores or nanotubes as described by the capillary pore model (also called "space charge" theory). This theory assumes very long and thin pores and uses a one-dimensional flux-force formalism which relates fluxes (electrical current, salt flux, and fluid velocity) and driving forces (difference in electric potential, salt concentration, and pressure). We analyze the general case with overlapping electric double layers in the pore and a nonzero axial salt concentration gradient. The 3 ×3 matrix relating these quantities exhibits Onsager symmetry and we report a significant new simplification for the diagonal element relating axial salt flux to the gradient in chemical potential. We prove that Onsager symmetry is preserved under changes of variables, which we illustrate by transformation to a different flux-force matrix given by Gross and Osterle [J. Chem. Phys. 49, 228 (1968), 10.1063/1.1669814]. The capillary pore model is well suited to describe the nonlinear response of charged membranes or nanofluidic devices for electrokinetic energy conversion and water desalination, as long as the transverse ion profiles remain in local quasiequilibrium. As an example, we evaluate electrical power production from a salt concentration difference by reverse electrodialysis, using an efficiency versus power diagram. We show that since the capillary pore model allows for axial gradients in salt concentration, partial loops in current, salt flux, or fluid flow can develop in the pore. Predictions for macroscopic transport properties using a reduced model, where the potential and concentration are assumed to be invariant with radial coordinate ("uniform potential" or "fine capillary pore" model), are close to results of the full model.

  4. Reduced exchange narrowing caused by gate-induced charge carriers in high-mobility donor-acceptor copolymers

    NASA Astrophysics Data System (ADS)

    Tsutsumi, Jun'ya; Matsuoka, Satoshi; Osaka, Itaru; Kumai, Reiji; Hasegawa, Tatsuo

    2017-03-01

    Variations in exciton absorption resulting from charge accumulation in various semiconducting donor-acceptor (DA) copolymer thin films were systematically investigated by gate modulation (GM) spectroscopy by using the field-effect transistor device structure. The GM spectra obtained for high-mobility DA copolymer thin films exhibited second-derivative like line shapes due to an effect of spectral broadening of ordinary exciton absorption spectra by accumulated charges. In contrast, the GM spectra obtained for relatively low-mobility DA copolymer thin films exhibited simple bleaching of exciton absorption spectra, as well as observed for non-DA-type polymers like poly(3-hexylthiophene-2,5-diyl) (P3HT). From a systematic comparison of the GM spectra with temperature-dependent absorption spectra for the polymers in solution, we found that the spectral broadening observed in the GM spectra can be attributed to a reduced effect on the exchange narrowing where excitonic transitions of individual polymer chains are coherently coupled within highly ordered crystalline domains in the polymer thin films. We discuss that the gate-induced charge accumulation in the polymer films effects to suppress the exciton coherence length, which contributes to the reduced exchange narrowing. We also discuss that the whole feature of the GM spectra can be understood in terms of a decomposition into ordered and disordered polymers and that the GM spectra can be used as fine probes for a degree of structural ordering in semiconductor channels of polymer field-effect transistors.

  5. An ion-exchange nanomembrane sensor for detection of nucleic acids using a surface charge inversion phenomenon.

    PubMed

    Senapati, Satyajyoti; Slouka, Zdenek; Shah, Sunny S; Behura, Susanta K; Shi, Zonggao; Stack, M Sharon; Severson, David W; Chang, Hsueh-Chia

    2014-10-15

    We present a novel low-cost biosensor for rapid, sensitive and selective detection of nucleic acids based on an ionic diode feature of an anion exchange nanoporous membrane under DC bias. The ionic diode feature is associated with external surface charge inversion on the positively charged anion exchange nanomembrane upon hybridization of negatively charged nucleic acid molecules to single-stranded oligoprobes functionalized on the membrane surface resulting in the formation of a cation selective monolayer. The resulting bipolar membrane causes a transition from electroconvection-controlled to water-splitting controlled ion conductance, with a large ion current signature that can be used to accurately quantify the hybridized nucleic acids. The platform is capable of distinguishing two base-pair mismatches in a 22-base pairing segment of microRNAs associated with oral cancer, as well as serotype-specific detection of dengue virus. We also show the sensor' capability to selectively capture target nucleic acids from a heterogeneous mixture. The limit of detection is 1 pM for short 27 base target molecules in a 15-min assay. Similar hybridization results are shown for short DNA molecules as well as RNAs from Brucella and Escherichia coli. The versatility and simplicity of this low-cost biosensor should enable point-of-care diagnostics in food, medical and environmental safety markets.

  6. A semi-interpenetrating network approach for dimensionally stabilizing highly-charged anion exchange membranes for alkaline fuel cells.

    PubMed

    He, Steve S; Strickler, Alaina L; Frank, Curtis W

    2015-04-24

    There is a delicate balance between ion exchange capacity (IEC), conductivity, and dimensional stability in anion exchange membranes as higher charge content can lead to increased water uptake, causing excessive swelling and charge dilution. Using highly-charged benzyltrimethylammonium polysulfone (IEC=2.99 mEq g(-1) ) as a benchmark (which ruptured in water even at room temperature), we report the ability to dramatically decrease water uptake using a semi-interpenetrating network wherein we reinforced the linear polyelectrolyte with a crosslinked poly(styrene-co-divinylbenzene) network. These membranes show enhanced dimensional stability as a result of lower water uptake (75 % vs. 301 % at 25 °C) while maintaining excellent hydroxide conductivity (up to 50 mS cm(-1) at 25 °C). These improvements produced an enhanced alkaline fuel cell capable of generating 236 mW cm(-2) peak power density at 80 °C. This method is easily adaptable and can be a viable strategy for stabilizing existing systems.

  7. Cometary Solar Wind Charge Exchange Line Ratios: Source of X-rays in Comet C/2000 WM1 (linear)

    NASA Astrophysics Data System (ADS)

    Mullen, Patrick Dean; Cumbee, Renata; Lyons, David; Gu, Liyi; Kaastra, Jelle S.; Shelton, Robin L.; Stancil, Phillip C.

    2016-06-01

    Cometary solar wind charge exchange (C-SWCX) occurs when highly charged projectile ions present in solar wind capture an electron from a target neutral species present in the cometary atmosphere. The availability of atomic and molecular data necessary for the X-ray emission modeling due to C-SWCX is limited; therefore, we apply multi-channel Landau-Zener (MCLZ) theory (Mullen et al. 2016) to generate cross section data and theoretical X-ray line ratios for a variety of bare and non-bare ion single electron capture (SEC) collisions. Namely, we consider collisions between the solar wind constituent H-like and He-like ions of C, N, O, Ne, Na, Al, and Si and the cometary neutrals H, H2O, CO, CO2, OH, and O. To exemplify the application of this data, we model the X-ray emission of comet C/2000 WM1 (linear) using the charge exchange package in SPEX (Gu et al. 2015) and find excellent agreement with observations made with the XMM-RGS detector. Our analyses show that the X-ray intensity is dominated by C-SWCX with H.Work at UGA was partially funded by NASA grant NNX13AF31G.References:Gu et al. 2016, A&A, accepted 22 January 2016Mullen et al. 2016, ApJS, in press

  8. X-ray Emission Cross Sections following Charge Exchange by Multiply-Charged Ions of Astrophysical Interest.

    NASA Astrophysics Data System (ADS)

    Otranto, Sebastian; Olson, Ronald; Beiersdorfer, Peter

    2006-05-01

    State selective nl-electron capture cross sections calculated using the classical trajectory Monte Carlo (CTMC) model are presented for highly charged ions with Z = 6-10 colliding with atoms and molecules. The energy dependence of the l-level populations is investigated. The calculated cross sections are compared with measurements made by Greenwood et al [1], using O^8+ and Ne^10+ on various targets at 3 keV/amu, and with recent x-ray emission cross sections measured with the EBIT machine at LLNL using O^8+ and Ne^9+,10+ on different targets at 10 eV/amu. We use the calculated cross sections to present an ab initio determination of the soft x-ray spectrum of comet C/Linear 1999 S4 that was observed on the Chandra X-ray Observatory [2]. [1] J. B. Greenwood, I. D. Williams, S. J. Smith and A. Chutjian, Phys. Rev. A 63, 062707 (2001). [2] C. M. Lisse, D. J. Christian, K. Dennerl, K. J. Meech, R. Petre, H. A. Weaver and S. J. Wolk, Science 292, 1343 (2001).

  9. Charge exchange and x-ray emission cross sections for multiply charged ions colliding with H{sub 2}O

    SciTech Connect

    Otranto, S.; Olson, R. E.

    2008-02-15

    Total and state selective nl-electron capture cross sections are presented for highly charged ions Z=4-10, 14, 18, and 26 colliding with water molecules. The energy range investigated was from 10 eV/amu (v=0.02 a.u.) to 100 keV/amu (v=2 a.u.). An initialization for the 1B1 and 3A1 orbitals of the water molecule is introduced based on the one center expansion of Moccia and compared to our previous studies based on a hydrogenic approximation within the microcanonical ensemble. The Z dependence of the calculated total cross sections is in reasonable agreement with the recent data of Mawhorter et al. [Phys. Rev. A 75, 032704 (2007)] and is improved over previous results. The energy dependence of the n- and l-level populations is investigated. The K-shell x-ray emission cross sections are determined by using the calculated state-selective electron capture results as input and then applying hydrogenic branching and cascading values for the photon emission. Our results compare favorably with experimental data from the KVI-Groningen, Jet Propulsion Laboratory and Lawrence Livermore National Laboratory groups.

  10. Core-ion temperature measurement of the ADITYA tokamak using passive charge exchange neutral particle energy analyzer.

    PubMed

    Pandya, Santosh P; Ajay, Kumar; Mishra, Priyanka; Dhingra, Rajani D; Govindarajan, J

    2013-02-01

    Core-ion temperature measurements have been carried out by the energy analysis of passive charge exchange (CX) neutrals escaping out of the ADITYA tokamak plasma (minor radius, a = 25 cm and major radius, R = 75 cm) using a 45° parallel plate electrostatic energy analyzer. The neutral particle analyzer (NPA) uses a gas cell configuration for re-ionizing the CX-neutrals and channel electron multipliers (CEMs) as detectors. Energy calibration of the NPA has been carried out using ion-source and ΔE∕E of high-energy channel has been found to be ∼10%. Low signal to noise ratio (SNR) due to VUV reflections on the CEMs was identified during the operation of the NPA with ADITYA plasma discharges. This problem was rectified by upgrading the system by incorporating the additional components and arrangements to suppress VUV radiations and improve its VUV rejection capabilities. The noise rejection capability of the NPA was experimentally confirmed using a standard UV-source and also during the plasma discharges to get an adequate SNR (>30) at the energy channels. Core-ion temperature Ti(0) during flattop of the plasma current has been measured to be up to 150 eV during ohmically heated plasma discharges which is nearly 40% of the average core-electron temperature (typically Te(0) ∼ 400 eV). The present paper describes the principle of tokamak ion temperature measurement, NPA's design, development, and calibration along with the modifications carried out for minimizing the interference of plasma radiations in the CX-spectrum. Performance of the NPA during plasma discharges and experimental results on the measurement of ion-temperature have also been reported here.

  11. EXCHANGE

    SciTech Connect

    Boltz, J.C.

    1992-09-01

    EXCHANGE is published monthly by the Idaho National Engineering Laboratory (INEL), a multidisciplinary facility operated for the US Department of Energy (DOE). The purpose of EXCHANGE is to inform computer users about about recent changes and innovations in both the mainframe and personal computer environments and how these changes can affect work being performed at DOE facilities.

  12. Longwave radiative exchange analysis of cloudy atmospheres with a net exchange formulation

    NASA Astrophysics Data System (ADS)

    Eymet, V.; Blanco, S.; Dufresne, J.-L.; Fournier, R.

    2003-04-01

    The Next Exchange Formulation (NEF) is an alternative to the usual radiative transfer equation. It was proposed in 1967 by Green for atmospheric sciences and by Hottel for engineering sciences. Until now, the NEF has been used only in a very few cases for atmospheric studies. Recently we have developed a longwave radiative code based on this formulation for a GCM of the Mars planet. Here, we will present results for the Earth atmosphere, obtained with a Monte Carlo Method based on the NEF. In this method, the fluxes are no more considered. The basic variables are the net exchange rates (NER) between each pair of atmospheric layer {i,j}, i.e. the radiative power emitted by i and absorbed by j minus the radiative power emitted by j and absorbed by i. The graphical representation of the NER matrix highlight the radiative exchanges which dominate the radiative budget of the atmosphere and allows one to have a very good insight of the radiative exchanges. Results will be shown for clear sky atmosphere, cloudy atmosphere and atmosphere with dust aerosols. The role of scattering in the longwave radiative exchanges will also be analyzed. The calculation of sensitivity parameter being automatically implemented in the Monte Carlo Method, a complementary sensitivity analysis will be presented that examines how radiative exchanges depend on concentrations profiles of main absorbing and scattering species.

  13. Physical explosion analysis in heat exchanger network design

    NASA Astrophysics Data System (ADS)

    Pasha, M.; Zaini, D.; Shariff, A. M.

    2016-06-01

    The failure of shell and tube heat exchangers is being extensively experienced by the chemical process industries. This failure can create a loss of production for long time duration. Moreover, loss of containment through heat exchanger could potentially lead to a credible event such as fire, explosion and toxic release. There is a need to analyse the possible worst case effect originated from the loss of containment of the heat exchanger at the early design stage. Physical explosion analysis during the heat exchanger network design is presented in this work. Baker and Prugh explosion models are deployed for assessing the explosion effect. Microsoft Excel integrated with process design simulator through object linking and embedded (OLE) automation for this analysis. Aspen HYSYS V (8.0) used as a simulation platform in this work. A typical heat exchanger network of steam reforming and shift conversion process was presented as a case study. It is investigated from this analysis that overpressure generated from the physical explosion of each heat exchanger can be estimated in a more precise manner by using Prugh model. The present work could potentially assist the design engineer to identify the critical heat exchanger in the network at the preliminary design stage.

  14. Calculating field emission current in nanodiodes—A multi-group formalism with space charge and exchange-correlation effects

    SciTech Connect

    Biswas, Debabrata; Kumar, Raghwendra

    2014-03-21

    Inclusion of electron-electron interaction is essential in nano-diodes to understand the underlying physical phenomenon and tailor devices accordingly. However, both space charge and exchange-correlation interaction involve electrons at different energies and hence a self-consistent multi-energy-group solution of the Schrödinger-Poisson system is required. It is shown here that the existence of a limiting density-dependent potential at low applied voltages allows calculation of the field emission current. Despite additional interactions, a Fowler-Nordheim behaviour is observed. It is also found that the exchange-correlation potential dominates at these voltages in nanogaps and possibly leads to a higher turn-on voltage.

  15. Investigation of Anion-Exchange and Immunoaffinity Particle-Loaded Membranes for the Isolation of Charged Organic Analytes from Water

    USGS Publications Warehouse

    Dombrowski, T.R.; Wilson, G.S.; Thurman, E.M.

    1998-01-01

    Anion-exchange and immunoaffinity particle loaded membranes (PLMs) were investigated as a mechanism for the isolation of charged organic analytes from water. Kinetic properties determined theoretically included dynamic capacity, pressure drop (??P), residence and diffusion times (Tr, Td), and total membrane porosity (???T). These properties were confirmed through experimental evaluation, and the PLM method showed significant improvement over conventional solid-phase extraction (SPE) and ion-exchange formats. Recoveries of more than 90% were observed for a variety of test compounds at flow rates up to 70 mL/min (equipment-limited maximum flow rate). A fast-flow immunoaffinity column was developed using antibodies (Abs) attached to the PLMs. Reproducible recoveries (88% ?? 4%) were observed at flow rates up to 70 mL/min for the antibody (Ab)-loaded PLMs. Findings indicate increased selectivity over anion-exchange PLMs and conventional SPE or ion-exchange methods and rapid Ab-antigen binding rates given the excellent mass-transfer characteristics of the PLMs.

  16. iSat Surface Charging and Thruster Plume Interactions Analysis

    NASA Technical Reports Server (NTRS)

    Parker, L. Neergaard; Willis, E. M.; Minow, J. I.

    2016-01-01

    Characterizing the electromagnetic interaction of a satellite in low Earth, high inclination orbit with the space plasma environment and identifying viable charging mitigation strategies is a critical mission design task. High inclination orbits expose the vehicle to auroral charging environments that can potentially charge surfaces to kilovolt potentials and electric thruster propulsion systems will interact with the ambient plasma environment throughout the orbit. NASA is designing the Iodine Satellite (iSAT) cubesat mission to demonstrate operations of an iodine electric thruster system. The spacecraft will be deployed as a secondary payload from a launch vehicle which has not yet been identified so the program must plan for the worst case environments over a range of orbital inclinations. We will first present results from a NASA and Air Force Charging Analyzer Program (Nascap) -2k surface charging calculation used to evaluate the effects of auroral charging on the spacecraft and to provide the charging levels at other locations in orbit for a thruster plume interaction analysis for the iSAT mission. We will then discuss results from the thruster interactions analysis using the Electric Propulsion Interactions Code (EPIC) with inputs from Nascap-2k. The results of these analyses are being used by the iSAT program to better understand how their spacecraft will interact with the space plasma environment in the range of environments that could be encountered when the final mission orbit is selected.

  17. NUMEN Project @ LNS : Heavy ions double charge exchange reactions towards the 0νββ nuclear matrix element determination

    SciTech Connect

    Agodi, C. Calabretta, L.; Calanna, A.; Carbone, D.; Cavallaro, M.; Colonna, M.; Cuttone, G.; Finocchiaro, P.; Pandola, L.; Rifuggiato, D.; Tudisco, S.; Cappuzzello, F.; Greco, V.; Bonanno, D. L.; Bongiovanni, D. G.; Longhitano, F.; Branchina, V.; Foti, A.; Lo Presti, D.; Lanzalone, G.; and others

    2015-10-28

    In the NUMEN Project it is proposed an innovative technique to access the nuclear matrix elements entering in the expression of the life-time of the neutrinoless double beta decay, using relevant cross sections of double charge exchange reactions. A key aspect is the use of MAGNEX large acceptance magnetic spectrometer, for the detection of the ejectiles, and of the INFN Laboratori Nazionali del Sud (LNS) K800 Superconducting Cyclotron (CS), for the acceleration of the required high resolution and low emittance heavy-ion beams.

  18. A three-dimensional, quantum mechanical study of exchange and charge transfer processes in the (Ar+H2) + system

    NASA Astrophysics Data System (ADS)

    Baer, Michael; Nakamura, Hiroki

    1987-10-01

    A three-dimensional quantum mechanical study of the (Ar+H2)+ system was carried out within the reactive infinite order sudden approximation. All three arrangement channels for exchange and charge transfer were treated simultaneously. Steric factors, opacity functions, angular distributions, and integral cross sections were calculated. Whenever possible, these were compared with both experimental and trajectory surface hopping (TSH) results. Whereas the fit with the TSH results was reasonable, the fit obtained with the experiment was less satisfactory. The reason for that can be attributed at least partially to the semiempirical DIM potential employed in the calculation.

  19. Measurement of derivative of ion temperature using high spatial resolution charge exchange spectroscopy with space modulation optics

    SciTech Connect

    Ida, K.; Yoshinuma, M.; Inagaki, S.; Kobuchi, T.; Sakamoto, Y.; Matsunaga, G.; Koide, Y.

    2008-05-15

    A new technique to measure the first and second derivatives of the ion temperature profile has been developed by using a charge exchange spectroscopy system with space modulation optics. The space observed is scanned up to {+-}3 cm with a cosine wave modulation frequency up to 30 Hz by shifting the object lens in front of the optical fiber bundle by 0.5 mm with a piezoelement. The first and second derivatives of ion temperature are derived from the modulation component of the ion temperature measured by using Fourier series expansion.

  20. iSat Surface Charging and Thruster Plume Interactions Analysis

    NASA Technical Reports Server (NTRS)

    Parker, L. Neergaard; Willis, E.; Minow, J.

    2016-01-01

    NASA is designing the Iodine Satellite (iSAT) cubesat mission to demonstrate operations of an iodine electric thruster system. The spacecraft will be deployed as a secondary payload from a launch vehicle which has not yet been identified so the program must plan for the worst case environments over a range of orbital inclinations. We present results from a NASA and Air Force Charging Analyzer Program (NASCAP-2K) surface charging calculation used to evaluate the effects of charging on the spacecraft and to provide the charging levels at other locations in orbit for a thruster plume interaction analysis for the iSAT mission. We will then discuss results from the thruster interactions analysis using the Electric Propulsion Interactions Code (EPIC). The results of these analyses are being used by the iSAT program for a range of environments that could be encountered when the final mission orbit is selected.

  1. Quantifying charge resonance and multiexciton character in coupled chromophores by charge and spin cumulant analysis

    SciTech Connect

    Luzanov, Anatoliy V.; Casanova, David; Feng, Xintian; Krylov, Anna I.

    2015-06-14

    We extend excited-state structural analysis to quantify the charge-resonance and multi-exciton character in wave functions of weakly interacting chromophores such as molecular dimers. The approach employs charge and spin cumulants which describe inter-fragment electronic correlations in molecular complexes. We introduce indexes corresponding to the weights of local, charge resonance, and biexciton (with different spin structure) configurations that can be computed for general wave functions thus allowing one to quantify the character of doubly excited states. The utility of the approach is illustrated by applications to several small dimers, e.g., He-H{sub 2}, (H{sub 2}){sub 2}, and (C{sub 2}H{sub 4}){sub 2}, using full and restricted configuration interaction schemes. In addition, we present calculations for several systems relevant to singlet fission, such as tetracene, 1,6-diphenyl-1,3,5-hexatriene, and 1,3-diphenylisobenzofuran dimers.

  2. Effect of dense plasmas on exchange-energy shifts in highly charged ions: An alternative approach for arbitrary perturbation potentials

    SciTech Connect

    Rosmej, F.; Bennadji, K.; Lisitsa, V. S.

    2011-09-15

    An alternative method of calculation of dense plasma effects on exchange-energy shifts {Delta}E{sub x} of highly charged ions is proposed which results in closed expressions for any plasma or perturbation potential. The method is based on a perturbation theory expansion for the inner atomic potential produced by charged plasma particles employing the Coulomb Green function method. This approach allows us to obtain analytic expressions and scaling laws with respect to the electron temperature T, density n{sub e}, and nuclear charge Z. To demonstrate the power of the present method, two specific models were considered in detail: the ion sphere model (ISM) and the Debye screening model (DSM). We demonstrate that analytical expressions can be obtained even for the finite temperature ISM. Calculations have been carried out for the singlet 1s2p{sup 1} P{sub 1} and triplet 1s2p{sup 3} P{sub 1} configurations of He-like ions with charge Z that can be observed in dense plasmas via the He-like resonance and intercombination lines. Finally we discuss recently available purely numerical calculations and experimental data.

  3. Charge heterogeneity profiling of monoclonal antibodies using low ionic strength ion-exchange chromatography and well-controlled pH gradients on monolithic columns.

    PubMed

    Talebi, Mohammad; Nordborg, Anna; Gaspar, Andras; Lacher, Nathan A; Wang, Qian; He, Xiaoping Z; Haddad, Paul R; Hilder, Emily F

    2013-11-22

    In this work, the suitability of employing shallow pH gradients generated using single component buffer systems as eluents through cation-exchange (CEX) monolithic columns is demonstrated for the high-resolution separation of monoclonal antibody (mAb) charge variants in three different biopharmaceuticals. A useful selection of small molecule buffer species is described that can be used within very narrow pH ranges (typically 1 pH unit) defined by their buffer capacity for producing controlled and smooth pH profiles when used together with porous polymer monoliths. Using very low ionic strength eluents also enabled direct coupling with electrospray ionisation mass spectrometry. The results obtained by the developed pH gradient approach for the separation of closely related antibody species appear to be consistent with those obtained by imaged capillary isoelectric focusing (iCE) in terms of both resolution and separation profile. Both determinants of resolution, i.e., peak compression and peak separation contribute to the gains in resolution, evidently through the Donnan potential effect, which is increased by decreasing the eluent concentration, and also through the way electrostatic charges are distributed on the protein surface. Retention mechanisms based on the trends observed in retention of proteins at pH values higher than the electrophoretic pI are also discussed using applicable theories. Employing monolithic ion-exchangers is shown to enable fast method development, short analysis time, and high sample throughput owing to the accelerated mass transport of the monolithic media. The possibility of short analysis time, typically less than 15 min, and high sample throughput is extremely useful in the assessment of charge-based changes to the mAb products, such as during manufacturing or storage.

  4. Chiral anion exchangers applied to capillary electrochromatography enantioseparation of oppositely charged chiral analytes: investigation of stationary and mobile phase parameters.

    PubMed

    Lämmerhofer, M; Tobler, E; Lindner, W

    2000-07-28

    Weak anion-exchange (WAX) type chiral stationary phases (CSPs) based on tert.-butyl carbamoyl quinine as chiral selector (SO) and different types of silica particles (porous and non-porous) as chromatographic support are evaluated in packed capillary electrochromatography (CEC). Their ability to resolve the enantiomers of negatively charged chiral analytes, e.g., N-derivatized amino acids, in the anion-exchange mode and their electrochromatographic characteristics are described in dependence of several mobile phase parameters (pH, buffer type and concentration, organic modifier type and concentration) and other experimental variables (electric field strength, capillary temperature). The inherent "zwitterionic" surface character of such silica-based WAX type CSPs (positively charged SO and negatively charged residual silanols) allows the reversal of the electroosmotic flow (EOF) towards the anode at pH values below the isoelectric point (pI) of the modified surface, whereas a cathodic EOF results at pH values above the pI. Since for negatively charged analytes also an electrophoretic transport increment has to be considered, which can be either in or against the EOF direction, several distinct modes of elution have been observed under different stationary phase and mobile phase conditions: (i) co-electrophoretic elution of the negatively charged solutes with the anodic EOF in the negative polarity mode, (ii) counter-electrophoretic elution with the cathodic EOF in the positive polarity mode, and (iii) electrophoretically dominated elution in the negative polarity mode with a cathodic EOF directed to the injection end of the capillary. Useful enantioseparations of chiral acids have been obtained with all three modes. Enantioselectivity values as high as under pressure-driven conditions and theoretical plate numbers up to 120000 per meter could be achieved under electrically driven conditions. A repeatability study yielded RSD values below 2% for retention times and

  5. Use of the TFTR prototype charge exchange neutral analyzer for fast He/sub 3//sup + +/ diagnostics during ICRF heating on PLT

    SciTech Connect

    Medley, S.S.

    1981-07-01

    The Charge Exchange Neutral Analyzer (CENA) for TFTR is designed to measure singly charged ion species of atomic mass A = 1, 2, and 3 simultaneously with up to 75 energy channels per mass and an energy range of 0.5 < AE < 600, where AE is in units of AMU.keV. Plans to test the prototype analyzer on PLT prior to installation on TFTR are discussed. The capability of the analyzer to simultaneously measure singly reionized H, D, and He/sub 3/ charge exchange neutrals makes the analyzer of particular interest for recently proposed fast He/sub 3//sup + +/ diagnostics during ICRF heating on PLT.

  6. Analytical and experimental analysis of tube coil heat exchanger

    NASA Astrophysics Data System (ADS)

    Smusz, R.

    2016-09-01

    The paper presents the analytical and experimental analysis of heat transfer for the finned tube coil heat exchanger immersed in thermal storage tank. The tank is equipped with three helical-shaped heating coils and cylindrical- shaped stratification device. Two coils, upper and lower, use the water as a heating medium. The third, double wall heat exchanger coil, located at the bottom head on the tank is filled by the refrigerant (freon). Calculations of thermal power of water coil were made. Correlations of heat transfer coefficients in curved tubes were applied. In order to verify the analytical calculations the experimental studies of heat transfer characteristic for coil heat exchanger were performed.

  7. Charge variants characterization of a monoclonal antibody by ion exchange chromatography coupled on-line to native mass spectrometry: Case study after a long-term storage at +5°C.

    PubMed

    Leblanc, Y; Ramon, C; Bihoreau, N; Chevreux, G

    2017-03-24

    Numerous putative post-translational modifications may induce variations of monoclonal antibodies charge distribution that can potentially affect their biological activity. The characterization and the monitoring of these charge variants are critical quality requirements to ensure stability and process consistency. Charge variants are usually characterized by preparative ion exchange chromatography, collection of fractions and subsequent reverse-phase liquid chromatography with mass spectrometry analysis. While this process can be automatized by on-line two-dimensional chromatography, it remains often complex and time consuming. For this reason, a straightforward on-line charge variant analysis method is highly desirable and analytical laboratories are actively pursuing efforts to overcome this challenge. In this study, a mixed mode ion exchange chromatographic method using volatile salts and coupled on-line to native mass spectrometry was developed in association with a middle-up approach for a detailed characterization of monoclonal antibodies charge variants. An aged monoclonal antibody, presenting a complex charge variant profile was successfully investigated by this methodology as a case study. Results demonstrate that deamidation of the heavy chain was the major degradation pathway after long-term storage at 5°C while oxidation was rather low. The method was also very useful to identify all the clipped forms of the antibody.

  8. Comparative analysis of compact heat exchangers for application as the intermediate heat exchanger for advanced nuclear reactors

    SciTech Connect

    Bartel, N.; Chen, M.; Utgikar, V. P.; Sun, X.; Kim, I. -H.; Christensen, R.; Sabharwall, P.

    2015-04-04

    A comparative evaluation of alternative compact heat exchanger designs for use as the intermediate heat exchanger in advanced nuclear reactor systems is presented in this article. Candidate heat exchangers investigated included the Printed circuit heat exchanger (PCHE) and offset strip-fin heat exchanger (OSFHE). Both these heat exchangers offer high surface area to volume ratio (a measure of compactness [m2/m3]), high thermal effectiveness, and overall low pressure drop. Helium–helium heat exchanger designs for different heat exchanger types were developed for a 600 MW thermal advanced nuclear reactor. The wavy channel PCHE with a 15° pitch angle was found to offer optimum combination of heat transfer coefficient, compactness and pressure drop as compared to other alternatives. The principles of the comparative analysis presented here will be useful for heat exchanger evaluations in other applications as well.

  9. Comparative analysis of compact heat exchangers for application as the intermediate heat exchanger for advanced nuclear reactors

    DOE PAGES

    Bartel, N.; Chen, M.; Utgikar, V. P.; ...

    2015-04-04

    A comparative evaluation of alternative compact heat exchanger designs for use as the intermediate heat exchanger in advanced nuclear reactor systems is presented in this article. Candidate heat exchangers investigated included the Printed circuit heat exchanger (PCHE) and offset strip-fin heat exchanger (OSFHE). Both these heat exchangers offer high surface area to volume ratio (a measure of compactness [m2/m3]), high thermal effectiveness, and overall low pressure drop. Helium–helium heat exchanger designs for different heat exchanger types were developed for a 600 MW thermal advanced nuclear reactor. The wavy channel PCHE with a 15° pitch angle was found to offer optimummore » combination of heat transfer coefficient, compactness and pressure drop as compared to other alternatives. The principles of the comparative analysis presented here will be useful for heat exchanger evaluations in other applications as well.« less

  10. Statistical Analysis of the Exchange Rate of Bitcoin

    PubMed Central

    Chu, Jeffrey; Nadarajah, Saralees; Chan, Stephen

    2015-01-01

    Bitcoin, the first electronic payment system, is becoming a popular currency. We provide a statistical analysis of the log-returns of the exchange rate of Bitcoin versus the United States Dollar. Fifteen of the most popular parametric distributions in finance are fitted to the log-returns. The generalized hyperbolic distribution is shown to give the best fit. Predictions are given for future values of the exchange rate. PMID:26222702

  11. Statistical Analysis of the Exchange Rate of Bitcoin.

    PubMed

    Chu, Jeffrey; Nadarajah, Saralees; Chan, Stephen

    2015-01-01

    Bitcoin, the first electronic payment system, is becoming a popular currency. We provide a statistical analysis of the log-returns of the exchange rate of Bitcoin versus the United States Dollar. Fifteen of the most popular parametric distributions in finance are fitted to the log-returns. The generalized hyperbolic distribution is shown to give the best fit. Predictions are given for future values of the exchange rate.

  12. Charge transfer and momentum exchange in exospheric D-H(+) and H-D(+) collisions

    NASA Technical Reports Server (NTRS)

    Hodges, R. R., Jr.; Breig, E. L.

    1993-01-01

    Mechanisms that control the escape of deuterium from planetary exospheres include the acceleration of D(+) in the polar wind, and the production of suprathermal D atoms through nonthermal collisions. In this paper we examine the effects of neutral-ion interactions involving deuterium and hydrogen on the velocity distribution of neutral D. A two-center scattering approximation is used as the basis for calculations of the differential cross sections for charge transfer and elastic scatter in collision of H with D(+) and of D with H(+) for ionosphere-exosphere collision energies below 10 e V. These data are used to derive temperature dependent rate coefficients for the charge transfer branches of these interactions, and to determine the effects of ion-neutral temperature differences on the rate of generation of suprathermal D through charge transfer and elastic scatter.

  13. The effect of the charge exchange source on the velocity and 'temperature' distributions and their anisotropies in the earth's exosphere

    NASA Astrophysics Data System (ADS)

    Hodges, R. R., Jr.; Rohrbaugh, R. P.; Tinsley, B. A.

    1981-08-01

    The velocity distribution of atomic hydrogen in the earth's exosphere is calculated as a function of altitude and direction taking into account both the classic exobase source and the higher-altitude plasmaspheric charge exchange source. Calculations are performed on the basis of a Monte Carlo technique in which random ballistic trajectories of individual atoms are traced through a three-dimensional grid of audit zones, at which relative concentrations and momentum or energy fluxes are obtained. In the case of the classical exobase source alone, the slope of the velocity distribution is constant only for the upward radial velocity component and increases dramatically with altitude for the incoming radial and transverse velocity components, resulting in a temperature decrease. The charge exchange source, which produces the satellite hydrogen component and the hot ballistic and escape components of the exosphere, is found to enhance the wings of the velocity distributions, however this effect is not sufficient to overcome the temperature decreases at altitudes above one earth radius. The resulting global model of the hydrogen exosphere may be used as a realistic basis for radiative transfer calculations.

  14. The effect of the charge exchange source on the velocity and 'temperature' distributions and their anisotropies in the earth's exosphere

    NASA Technical Reports Server (NTRS)

    Hodges, R. R., Jr.; Rohrbaugh, R. P.; Tinsley, B. A.

    1981-01-01

    The velocity distribution of atomic hydrogen in the earth's exosphere is calculated as a function of altitude and direction taking into account both the classic exobase source and the higher-altitude plasmaspheric charge exchange source. Calculations are performed on the basis of a Monte Carlo technique in which random ballistic trajectories of individual atoms are traced through a three-dimensional grid of audit zones, at which relative concentrations and momentum or energy fluxes are obtained. In the case of the classical exobase source alone, the slope of the velocity distribution is constant only for the upward radial velocity component and increases dramatically with altitude for the incoming radial and transverse velocity components, resulting in a temperature decrease. The charge exchange source, which produces the satellite hydrogen component and the hot ballistic and escape components of the exosphere, is found to enhance the wings of the velocity distributions, however this effect is not sufficient to overcome the temperature decreases at altitudes above one earth radius. The resulting global model of the hydrogen exosphere may be used as a realistic basis for radiative transfer calculations.

  15. Nongeminate Radiative Recombination of Free Charges in Cation-Exchanged PbS Quantum Dot Films

    SciTech Connect

    Marshall, Ashley R.; Beard, Matthew C.; Johnson, Justin C.

    2016-06-01

    Using photoluminescence (PL) spectroscopy we explore the radiative recombination pathways in PbS quantum dots (QDs) synthesized by two methods. We compare conventionally synthesized PbS from a PbO precursor to PbS synthesized using cation-exchange from CdS QDs. We show that strongly coupled films of PbS QDs from the cation-exchange luminesce with significant efficiency at room temperature. This is in stark contrast to conventional PbS QDs, which have exceedingly weak room temperature emission. Moreover, the power dependence of the emission is quadratic, indicating bimolecular radiative recombination that is reasonably competitive with trap-assisted recombination, a feature previously unreported in coupled PbS QD films. We interpret these results in terms of a greatly reduced defect concentration for cation-exchanged QDs that mitigates the influence of trap-assisted recombination. Cation-exchanged QDs have recently been employed in highly efficient and air-stable lead chalcogenide QD devices, and the reduced number of trap states inferred here may lead to improved current collection and higher open circuit voltage.

  16. Polycation-exchanged clays as sorbents for organic pollutants: Influence of layer charge on pollutant sorption capacity

    SciTech Connect

    Breen, C.; Watson, R.

    1998-12-15

    The uptake curves for the adsorption of a polycation ([CH{sub 2}CH(OH)CH{sub 2}N(CH{sub 3}){sub 2}]{sub n}{sup n+}(Cl){sub n}{sup n{minus}}) onto a low iron Texas bentonite, WL, have been determined and compared with those onto two source smectites, SWy-1 and SAz-1. The polycation exhibited a marked affinity for all the smectite surfaces but polycation uptake was maximized on the fine fractions of Na{sup +}-WL. Variable temperature X-ray diffraction of the clay polycation complexes showed that the polycation was segregated into different interlayers at loadings below 30% of the CEC. The adsorption of benzene onto TMA{sup +}-exchanged SWy-1, SAz-1, and WL showed that, despite having a comparable layer charge to SWy-1, WL was as poor a sorbent for benzene as SAz-1, which has a much higher layer charge. The adsorption of p-nitrophenol (PNP) from aqueous solution onto the TMA{sup +}-exchanged sorbents exhibited the same trends, although a smaller amount was adsorbed due to the greater size of PNP. The amount of PNP adsorbed by polycation-treated SWy-1 depended upon the polycation loading, and PNP uptake maximized at loadings of 28 and 46 mg/(g clay). At higher loadings (80, 102, and 147 mg/(g clay)) the uptake curves became linear and the PNP uptake decreased with increased polycation loading. No polycation-treated clay was as effective as TMA{sup +}-exchanged SWy-1 for the removal of PNP from water.

  17. Exchange bias effect in Au-Fe3O4 dumbbell nanoparticles induced by the charge transfer from gold

    SciTech Connect

    Feygenson, Mikhail; Bauer, John C.; Gai, Zheng; Marques, Carlos; Aronson, Meigan C.; Teng, Xiaowei; Su, Dong; Stanic, Vesna; Urban, Volker S.; Beyer, Kevin A.; Dai, Sheng

    2015-08-10

    We have studied the origin of the exchange bias effect in the Au-Fe3O4 dumbbell nanoparticles in two samples with different sizes of the Au seed nanoparticles (4.1 and 2.7 nm) and same size of Fe3O4 nanoparticles (9.8 nm). The magnetization, small-angle neutron-scattering, synchrotron x-ray diffraction, and scanning transmission electron microscope measurements determined the antiferromagnetic FeO wustite phase within Fe3O4 nanoparticles, originating at the interface with the Au nanoparticles. The interface between antiferromagnetic FeO and ferrimagnetic Fe3O4 is giving rise to the exchange bias effect. The strength of the exchange bias fields depends on the interfacial area and lattice mismatch between both phases. We propose that the charge transfer from the Au nanoparticles is responsible for a partial reduction of the Fe3O4 into the FeO phase at the interface with Au nanoparticles. The Au-O bonds are formed, presumably across the interface to accommodate an excess of oxygen released during the reduction of magnetite

  18. Exchange bias effect in Au-Fe3O4 dumbbell nanoparticles induced by the charge transfer from gold

    DOE PAGES

    Feygenson, Mikhail; Bauer, John C; Gai, Zheng; ...

    2015-08-10

    We have studied the origin of the exchange bias effect in the Au-Fe3O4 dumbbell nanoparticles in two samples with different sizes of the Au seed nanoparticles (4.1 and 2.7 nm) and same size of Fe3O4 nanoparticles (9.8 nm). The magnetization, small-angle neutron scattering, synchrotron x-ray diffraction and scanning transmission electron microscope measurements determined the antiferromagnetic FeO wüstite phase within Fe3O4 nanoparticles, originating at the interface with the Au nanoparticles. The interface between antiferromagnetic FeO and ferrimagnetic Fe3O4 is giving rise to the exchange bias effect. The strength of the exchange bias fields depends on the interfacial area and lattice mismatchmore » between both phases. We propose that the charge transfer from the Au nanoparticles is responsible for a partial reduction of the Fe3O4 into FeO phase at the interface with Au nanoparticles. The Au-O bonds are formed across the interface to accommodate an excess of oxygen released during the reduction of magnetite.« less

  19. Ion Mobility Spectrometry-Hydrogen Deuterium Exchange Mass Spectrometry of Anions: Part 2. Assessing Charge Site Location and Isotope Scrambling.

    PubMed

    Khakinejad, Mahdiar; Kondalaji, Samaneh Ghassabi; Donohoe, Gregory C; Valentine, Stephen J

    2016-03-01

    Ion mobility spectrometry (IMS) coupled with gas-phase hydrogen deuterium exchange (HDX)-mass spectrometry (MS) and molecular dynamic simulations (MDS) has been used for structural investigation of anions produced by electrospraying a sample containing a synthetic peptide having the sequence KKDDDDDIIKIIK. In these experiments the potential of the analytical method for locating charge sites on ions as well as for utilizing collision-induced dissociation (CID) to reveal the degree of deuterium uptake within specific amino acid residues has been assessed. For diffuse (i.e., more elongated) [M - 2H](2-) ions, decreased deuterium content along with MDS data suggest that the D4 and D6 residues are charge sites, whereas for the more diffuse [M - 3H](3-) ions, the data suggest that the D4, D7, and the C-terminus are deprotonated. Fragmentation of mobility-selected, diffuse [M - 2H](2-) ions to determine deuterium uptake at individual amino acid residues reveals a degree of deuterium retention at incorporation sites. Although the diffuse [M - 3H](3-) ions may show more HD scrambling, it is not possible to clearly distinguish HD scrambling from the expected deuterium uptake based on a hydrogen accessibility model. The capability of the IMS-HDX-MS/MS approach to provide relevant details about ion structure is discussed. Additionally, the ability to extend the approach for locating protonation sites on positively-charged ions is presented.

  20. Ion Mobility Spectrometry-Hydrogen Deuterium Exchange Mass Spectrometry of Anions: Part 2. Assessing Charge Site Location and Isotope Scrambling

    NASA Astrophysics Data System (ADS)

    Khakinejad, Mahdiar; Ghassabi Kondalaji, Samaneh; Donohoe, Gregory C.; Valentine, Stephen J.

    2016-03-01

    Ion mobility spectrometry (IMS) coupled with gas-phase hydrogen deuterium exchange (HDX)-mass spectrometry (MS) and molecular dynamic simulations (MDS) has been used for structural investigation of anions produced by electrospraying a sample containing a synthetic peptide having the sequence KKDDDDDIIKIIK. In these experiments the potential of the analytical method for locating charge sites on ions as well as for utilizing collision-induced dissociation (CID) to reveal the degree of deuterium uptake within specific amino acid residues has been assessed. For diffuse (i.e., more elongated) [M - 2H]2- ions, decreased deuterium content along with MDS data suggest that the D4 and D6 residues are charge sites, whereas for the more diffuse [M - 3H]3- ions, the data suggest that the D4, D7, and the C-terminus are deprotonated. Fragmentation of mobility-selected, diffuse [M - 2H]2- ions to determine deuterium uptake at individual amino acid residues reveals a degree of deuterium retention at incorporation sites. Although the diffuse [M - 3H]3- ions may show more HD scrambling, it is not possible to clearly distinguish HD scrambling from the expected deuterium uptake based on a hydrogen accessibility model. The capability of the IMS-HDX-MS/MS approach to provide relevant details about ion structure is discussed. Additionally, the ability to extend the approach for locating protonation sites on positively-charged ions is presented.

  1. Shorting time of magnetically insulated reflex-ion diodes from the neutral-atom charge-exchange mechanism

    SciTech Connect

    Strobel, G.

    1981-10-01

    In a magnetically insulated diode, collision-free electrons return to the cathode and no electron current is present at the anode. Electron transport to the anode is studied in this paper. Steady-state space-charge-limited flow is assumed initially. Breakdown of ion flow occurs when static neutral atoms at the anode undergo charge exchange, which results in neutral atoms drifting across the diode. These are subsequently ionized by reflexing ions producing electrons trapped in Larmor orbits throughout the diode. These electrons drift to the anode via ionization and inelastic collisions with other neutral atoms. Model calculations compare the effects of foil and mesh cathodes. Steady-state space-charge-limited ion current densities are calculated. The neutral atom density at the cathode is determined as a function of time. The shorting time of the diode is scaled versus the electrode separation d, the diode potential V/sub 0/, the magnetic field, and the initial concentration of static neutron atoms.

  2. The velocity dependence of X-ray emission due to Charge Exchange: Applications in the Cygnus Loop

    NASA Astrophysics Data System (ADS)

    Cumbee, Renata; Lyons, David; Mullen, Patrick; Shelton, Robin L.; Stancil, Phillip C.; Schultz, David R.

    2016-04-01

    The fundamental collisional process of charge exchange (CX) has been been established as a primary source of X-ray emission from the heliosphere [1], planetary exospheres [2], and supernova remnants [3,4]. In this process, X-ray emission results from the capture of an electron by a highly charged ion from a neutral atom or molecule, to form a highly-excited, high charge state ion. As the captured electron cascades down to the lowest energy level, photons are emitted, including X-rays.To provide reliable CX-induced X-ray spectral models to realistically simulate high-energy astrophysical environments, line ratios and spectra are computed using theoretical CX cross-sections obtained with the multi-channel Landau-Zener, atomic-orbital close-coupling, and classical-trajectory Monte Carlo methods for various collisional velocities. Collisions of bare and H-like C to Al ions with H, He, and H2 are considered. Using these line ratios, XSPEC models of CX emission in the northeast rim of the Cygnus Loop supernova remnant will be shown as an example with ion velocity dependence.[1] Henley, D. B. & Shelton, R. L. 2010, ApJSS, 187, 388[2] Dennerl, K. et al. 2002, A&A 386, 319[3] Katsuda, S. et al. 2011, ApJ 730 24[4] Cumbee, R. S. et al. 2014, ApJ 787 L31

  3. Ionization and Charge Exchange Reactions in Neutral Entrainment of a Field Reversed Configuration Thruster

    DTIC Science & Technology

    2012-07-16

    exchange and ionization rates for neon are plotted in Fig. 3 (right). The recombination rate is not shown as it was found, similar to helium , to be much...temperature for light gas, helium are shown in Fig. 2 (left). It can be concluded that at those temperatures and a number density on the order of 1018 m−3...process in a helium -based FRC thruster may be expected to be fairly efficient, especially for lower plasma temperatures. Note however that for

  4. Forensic analysis of explosions: Inverse calculation of the charge mass.

    PubMed

    van der Voort, M M; van Wees, R M M; Brouwer, S D; van der Jagt-Deutekom, M J; Verreault, J

    2015-07-01

    Forensic analysis of explosions consists of determining the point of origin, the explosive substance involved, and the charge mass. Within the EU FP7 project Hyperion, TNO developed the Inverse Explosion Analysis (TNO-IEA) tool to estimate the charge mass and point of origin based on observed damage around an explosion. In this paper, inverse models are presented based on two frequently occurring and reliable sources of information: window breakage and building damage. The models have been verified by applying them to the Enschede firework disaster and the Khobar tower attack. Furthermore, a statistical method has been developed to combine the various types of data, in order to determine an overall charge mass distribution. In relatively open environments, like for the Enschede firework disaster, the models generate realistic charge masses that are consistent with values found in forensic literature. The spread predicted by the IEA tool is however larger than presented in the literature for these specific cases. This is also realistic due to the large inherent uncertainties in a forensic analysis. The IEA-models give a reasonable first order estimate of the charge mass in a densely built urban environment, such as for the Khobar tower attack. Due to blast shielding effects which are not taken into account in the IEA tool, this is usually an under prediction. To obtain more accurate predictions, the application of Computational Fluid Dynamics (CFD) simulations is advised. The TNO IEA tool gives unique possibilities to inversely calculate the TNT equivalent charge mass based on a large variety of explosion effects and observations. The IEA tool enables forensic analysts, also those who are not experts on explosion effects, to perform an analysis with a largely reduced effort.

  5. Precision evaluation of the 71Ga(νe,e- ) solar neutrino capture rate from the (3He,t ) charge-exchange reaction

    NASA Astrophysics Data System (ADS)

    Frekers, D.; Adachi, T.; Akimune, H.; Alanssari, M.; Brown, B. A.; Cleveland, B. T.; Ejiri, H.; Fujita, H.; Fujita, Y.; Fujiwara, M.; Gavrin, V. N.; Harakeh, M. N.; Hatanaka, K.; Holl, M.; Iwamoto, C.; Lennarz, A.; Okamoto, A.; Okamura, H.; Suzuki, T.; Tamii, A.

    2015-03-01

    A precision measurement of the 71Ga(3He,t ) 71Ge charge-exchange reaction was performed. By using a rather complete set of theoretical form factors to describe the cross-section angular distributions over a large angular range, the Gamow-Teller strength distribution up to the effective neutron-separation energy in 71Ge was extracted. The data and the analysis constrain the 71Ga(νe,e- ) solar neutrino rate in a neutrino nonoscillation scenario. For nonoscillating neutrinos we report a solar neutrino capture rate of 122.4 ±3.4 (stat ) ±1.1 (sys ) SNU, which is lower than the presently accepted value of 132 ±18 SNU, though not in disagreement given the quoted errors.

  6. Ion-exchange chromatographic analysis of peroxynitric acid.

    PubMed

    Nakashima, Yoichi; Ikawa, Satoshi; Tani, Atsushi; Kitano, Katsuhisa

    2016-01-29

    Ion-exchange chromatographic analysis of peroxynitric acid (O2NOOH) was performed by combining an acidic eluate with an UV-vis detector and immersing the separation column in an ice-water bath. The decomposition behavior of peroxynitric acid in the solution was also studied using this system. The fraction for the peroxynitric acid peak was collected. Ion-exchange chromatographic analysis of this fraction, after standing at room temperature for 24h, showed that the decomposition products were mainly nitrate ions with a very small amount of nitrous acid. The peroxynitric acid peak area correlated perfectly with the total amount of decomposition products. The ion-exchange chromatographic isolation allowed us to evaluate the molar extinction coefficient of peroxynitric acid precisely in a wider wavelength range than previous reports. The value decreases monotonically from 1729±26M(-1)cm(-1) at 200nm to 12.0±0.5M(-1)cm(-1) at 290nm.

  7. Strong cation exchange chromatography in analysis of posttranslational modifications: innovations and perspectives.

    PubMed

    Edelmann, Mariola J

    2011-01-01

    Strong cation exchange (SCX) chromatography has been utilized as an excellent separation technique that can be combined with reversed-phase (RP) chromatography, which is frequently used in peptide mass spectrometry. Although SCX is valuable as the second component of such two-dimensional separation methods, its application goes far beyond efficient fractionation of complex peptide mixtures. Here I describe how SCX facilitates mapping of the protein posttranslational modifications (PTMs), specifically phosphorylation and N-terminal acetylation. The SCX chromatography has been mainly used for enrichment of these two PTMs, but it might also be beneficial for high-throughput analysis of other modifications that alter the net charge of a peptide.

  8. Charge exchange ionization in collision cells as a method to detect the presence of long-lived excited electronic states of polyatomic ions.

    PubMed

    Kwon, C H; Kim, M S; Choe, J C

    2001-10-01

    Charge exchange ionization in collision cells installed in a double focusing mass spectrometer with reversed geometry has been used to detect the presence of a long-lived excited electronic state of benzene ion. In particular, the first collision cell located between the ion source and the magnetic sector was modified to serve as an ion source for the reagent ion generated by charge exchange with the primary ion. Strong reagent ion signals were observed when the ionization energies of the reagents (1,3-C4H6, CS2, CH3Cl) were lower than the recombination energy (approximately 11.5 eV) of the excited state benzene ion, while the signals were negligible for reagents (CH3F,CH4) with higher ionization energy. The fact that a strong signal is observable only for electronically exoergic charge exchange is useful for detecting the presence of a long-lived electronically excited state.

  9. Symmetric Resonance Charge Exchange Cross Section Based on Impact Parameter Treatment

    NASA Technical Reports Server (NTRS)

    Omidvar, Kazem; Murphy, Kendrah; Atlas, Robert (Technical Monitor)

    2002-01-01

    Using a two-state impact parameter approximation, a calculation has been carried out to obtain symmetric resonance charge transfer cross sections between nine ions and their parent atoms or molecules. Calculation is based on a two-dimensional numerical integration. The method is mostly suited for hydrogenic and some closed shell atoms. Good agreement has been obtained with the results of laboratory measurements for the ion-atom pairs H+-H, He+-He, and Ar+-Ar. Several approximations in a similar published calculation have been eliminated.

  10. Mechanism of charged pollutants removal in an ion exchange membrane bioreactor: drinking water denitrification.

    PubMed

    Velizarov, S; Rodrigues, C M; Reis, M A; Crespo, J G

    The mechanism of anionic pollutant removal in an ion exchange membrane bioreactor (IEMB) was studied for drinking water denitrification. This hybrid process combines continuous ion exchange transport (Donnan dialysis) of nitrate and its simultaneous bioreduction to gaseous nitrogen. A nonporous mono-anion permselective membrane precludes direct contact between the polluted water and the denitrifying culture and prevents secondary pollution of the treated water with dissolved nutrients and metabolic products. Complete denitrification may be achieved without accumulation of NO3(-) and NO2(-) ions in the biocompartment. Focus was given to the effect of the concentration of co-ions, counterions, and ethanol on the IEMB performance. The nitrate overall mass transfer coefficient in this hybrid process was found to be 2.8 times higher compared to that in a pure Donnan dialysis process without denitrification. Furthermore, by adjusting the ratio of co-ions between the biocompartment and the polluted water compartment, the magnitude and direction of each individual anion flux can be easily regulated, allowing for flexible process operation and control. Synthetic groundwater containing 135-350 mg NO3(-) L(-1) was treated in the IEMB system. A surface denitrification rate of 33 g NO3(-) per square meter of membrane per day was obtained at a nitrate loading rate of 360 g NO3(-) m(-3)d(-1), resulting in a nitrate removal efficiency of 85%.

  11. Energy exchange between a laser beam and charged particles using inverse transition radiation and method for its use

    DOEpatents

    Kimura, Wayne D.; Romea, Richard D.; Steinhauer, Loren C.

    1998-01-01

    A method and apparatus for exchanging energy between relativistic charged particles and laser radiation using inverse diffraction radiation or inverse transition radiation. The beam of laser light is directed onto a particle beam by means of two optical elements which have apertures or foils through which the particle beam passes. The two apertures or foils are spaced by a predetermined distance of separation and the angle of interaction between the laser beam and the particle beam is set at a specific angle. The separation and angle are a function of the wavelength of the laser light and the relativistic energy of the particle beam. In a diffraction embodiment, the interaction between the laser and particle beams is determined by the diffraction effect due to the apertures in the optical elements. In a transition embodiment, the interaction between the laser and particle beams is determined by the transition effect due to pieces of foil placed in the particle beam path.

  12. Forward sum rule for the 2 γ -exchange correction to the charge-radius extraction from elastic electron scattering

    NASA Astrophysics Data System (ADS)

    Gorchtein, Mikhail

    2014-11-01

    Two-photon-exchange (TPE) contributions to elastic electron-proton scattering in the forward regime in leading logarithmic ˜t ln|t | approximation in the momentum transfer t are considered. The imaginary part of the TPE amplitude in the forward kinematics is related to the total photoabsorption cross section. The real part of the TPE amplitude is obtained from an unsubtracted fixed-t dispersion relation. This allows a clean prediction of the real part of the TPE amplitude at forward angles with the leading term ˜t ln|t | . Numerical estimates are comparable with or exceed the experimental precision in extracting the charge radius from the experimental data.

  13. Charge-exchange x-ray spectra: Evidence for significant contributions from radiative decays of doubly excited states

    NASA Astrophysics Data System (ADS)

    Ali, R.; Beiersdorfer, P.; Harris, C. L.; Neill, P. A.

    2016-01-01

    Charge-exchange collisions of slow Ne+10 ions with He, Ne, and Ar targets were studied with simultaneous x-ray and cold-target recoil-ion-momentum spectroscopy proving the contribution of several mechanisms to the radiative stabilization of apparent (4,4) doubly excited states for He and Ne targets and of (5,6) states for Ar. In particular, the stabilization efficiency of the mechanism of dynamic auto-transfer to Rydberg states is confirmed. Moreover, we present evidence for direct radiative decays of (4,4) states populated in collisions with He, which is an experimental indication of the population of so-called unnatural-parity states in such collisions. These mechanisms lead to the emission of x-rays that have considerably higher energies than those predicted by current spectral models and may explain recent observations of anomalously large x-ray emission from Rydberg levels.

  14. Cyclic voltammetry on sputter-deposited films of electrochromic Ni oxide: Power-law decay of the charge density exchange

    SciTech Connect

    Wen, Rui-Tao Granqvist, Claes G.; Niklasson, Gunnar A.

    2014-10-20

    Ni-oxide-based thin films were produced by reactive direct-current magnetron sputtering and were characterized by X-ray diffraction and Rutherford backscattering spectroscopy. Intercalation of Li{sup +} ions was accomplished by cyclic voltammetry (CV) in an electrolyte of LiClO{sub 4} in propylene carbonate, and electrochromism was documented by spectrophotometry. The charge density exchange, and hence the optical modulation span, decayed gradually upon repeated cycling. This phenomenon was accurately described by an empirical power law, which was valid for at least 10{sup 4} cycles when the applied voltage was limited to 4.1 V vs Li/Li{sup +}. Our results allow lifetime assessments for one of the essential components in an electrochromic device such as a “smart window” for energy-efficient buildings.

  15. Monte Carlo simulation of ion-neutral charge exchange collisions and grid erosion in an ion thruster

    NASA Technical Reports Server (NTRS)

    Peng, Xiaohang; Ruyten, Wilhelmus M.; Keefer, Dennis

    1991-01-01

    A combined particle-in-cell (PIC)/Monte Carlo simulation model has been developed in which the PIC method is used to simulate the charge exchange collisions. It is noted that a number of features were reproduced correctly by this code, but that its assumption of two-dimensional axisymmetry for a single set of grid apertures precluded the reproduction of the most characteristic feature of actual test data; namely, the concentrated grid erosion at the geometric center of the hexagonal aperture array. The first results of a three-dimensional code, which takes into account the hexagonal symmetry of the grid, are presented. It is shown that, with this code, the experimentally observed erosion patterns are reproduced correctly, demonstrating explicitly the concentration of sputtering between apertures.

  16. Observation of Solar Wind Charge Exchange Emission From Exospheric Material in and Outside Earth's Magnetosheath 2008 September 25

    NASA Technical Reports Server (NTRS)

    Snowden, S. L.; Collier, M. R.; Cravens, T.; Kuntz, K. D.; Lepri, S. T.; Robertson, I.; Tomas, L.

    2009-01-01

    A long XMM-Newton exposure is used to observe solar wind charge exchange (SWCX) emission from exospheric material in and outside Earth's magnetosheath. The light curve of the O vii (0.5-0.62 keV) band is compared with a model for the expected emission, and while the emission is faint and the light curve has considerable scatter, the correlation is significant to better than 99.9%. This result demonstrates the validity of the geocoronal SWCX emission model for predicting a contribution to astrophysical observations to a scale factor of order unity (1.5). In addition, an average value of the SWCX O vii emission from the magnetosheath over the observation of 2.6 +/- 0.5 LU is derived. The results also demonstrate the potential utility of using X-ray observations to study global phenomena of the magnetosheath which currently are only investigated using in situ measurements.

  17. Charge-exchange and fusion reaction measurements during compression experiments with neutral beam heating in the Tokamak Fusion Test Reactor

    SciTech Connect

    Kaita, R.; Heidbrink, W.W.; Hammett, G.W.; Chan, A.A.; England, A.C.; Hendel, H.W.; Medley, S.S.; Nieschmidt, E.; Roquemore, A.L.; Scott, S.D.

    1986-04-01

    Adiabatic toroidal compression experiments were performed in conjunction with high power neutral beam injection in the Tokamak Fusion Test Reactor (TFTR). Acceleration of beam ions to energies nearly twice the injection energy was measured with a charge-exchange neutral particle analyzer. Measurements were also made of 2.5 MeV neutrons and 15 MeV protons produced in fusion reactions between the deuterium beam ions and the thermal deuterium and /sup 3/He ions, respectively. When the plasma was compressed, the d(d,n)/sup 3/He fusion reaction rate increased a factor of five, and the /sup 3/He(d,p)/sup 4/He rate by a factor of twenty. These data were simulated with a bounce-averaged Fokker-Planck program, which assumed conservation of angular momentum and magnetic moment during compression. The results indicate that the beam ion acceleration was consistent with adiabatic scaling.

  18. Optimization of a compact multicusp He{sup +} ion source for double-charge-exchanged He{sup -} beam

    SciTech Connect

    Shinto, K.; Sugawara, H.; Takenaga, M.; Takeuchi, S.; Tanaka, N.; Okamoto, A.; Kitajima, S.; Sasao, M.; Nishiura, M.; Wada, M.

    2006-03-15

    Preliminary test bench results to study the beam quality extracted from a compact multicusp He{sup +} ion source for He{sup -} beam production are reported. The bench is a part of the beam diagnostic system equipped with energy analyzers, emittance meters, focusing beam optics, an alkali-metal charge-exchange cell, a neutral particle energy analyzer, a double focusing magnetic momentum analyzer, a postaccelerator, and a drift tube. Utilizing the front end of the bench, the transverse emittance and the energy distribution function of a He{sup +} beam extracted from a multi-line-cusp magnetic-field ion source 8 cm in diameter and 9 cm in length were measured. The results indicated that improvements in both formation of the plasma meniscus and reinforcement of pumping in the extraction region are necessary to produce a higher brightness He{sup +} beam.

  19. Exchange-Induced Negative-U Charge Order in N-Doped WO3: A Spin-Peierls-Like System

    SciTech Connect

    Huda, M. N.; Yan, Y.; Wei, S.-H.; Al-Jassim, M. M.

    2009-01-01

    An unconventional spin-Peierls-type distortion was found in a nonmagnetic atom N doped pseudo-one-dimensional WO{sub 3} system. The periodicity of the initial ferromagnetic WO{sub 3}:N is doubled in one direction, and the band gap opens up due to this distortion. The magnetic moment at the N site is asymmetric in the distorted system, and the interaction between the localized spin is very weak. We show that the large exchange interaction of the nitrogen 2p atomic orbital and the pseudo-one-dimensional W-O-W chain in monoclinic WO{sub 3} structure is the origin of this spin-Peierls-like transition that leads to the stabilization of an unusual negative-U charge-ordered system.

  20. THE ION-INDUCED CHARGE-EXCHANGE X-RAY EMISSION OF THE JOVIAN AURORAS: MAGNETOSPHERIC OR SOLAR WIND ORIGIN?

    SciTech Connect

    Hui Yawei; Schultz, David R.; Kharchenko, Vasili A.; Stancil, Phillip C.; Cravens, Thomas E.; Lisse, Carey M. E-mail: schultzd@ornl.gov E-mail: stancil@physast.uga.edu E-mail: carey.lisse@jhuapl.edu

    2009-09-10

    A new and more comprehensive model of charge-exchange induced X-ray emission, due to ions precipitating into the Jovian atmosphere near the poles, has been used to analyze spectral observations made by the Chandra X-ray Observatory. The model includes for the first time carbon ions, in addition to the oxygen and sulfur ions previously considered, in order to account for possible ion origins from both the solar wind and the Jovian magnetosphere. By comparing the model spectra with newly reprocessed Chandra observations, we conclude that carbon ion emission provides a negligible contribution, suggesting that solar wind ions are not responsible for the observed polar X-rays. In addition, results of the model fits to observations support the previously estimated seeding kinetic energies of the precipitating ions ({approx}0.7-2 MeV u{sup -1}), but infer a different relative sulfur-to-oxygen abundance ratio for these Chandra observations.

  1. The Ion-induced Charge-exchange X-ray Emission of the Jovian Auroras: Magnetospheric or Solar Wind Origin?

    SciTech Connect

    Hui, Yawei; Schultz, David Robert; Kharchenko, Vasili A; Stancil, Phillip C.; Cravens, Thomas E. E.; Lisse, Carey M.; Dalgarno, A.

    2009-01-01

    A new and more comprehensive model of charge-exchange induced X-ray emission, due to ions precipitating into the Jovian atmosphere near the poles, has been used to analyze spectral observations made by the Chandra X-ray Observatory. The model includes for the first time carbon ions, in addition to the oxygen and sulfur ions previously considered, in order to account for possible ion origins from both the solar wind and the Jovian magnetosphere. By comparing the model spectra with newly reprocessed Chandra observations, we conclude that carbon ion emission provides a negligible contribution, suggesting that solar wind ions are not responsible for the observed polar X-rays. In addition, results of the model fits to observations support the previously estimated seeding kinetic energies of the precipitating ions ( 0.7-2 MeV/u), but infer a different relative sulfur to oxygen abundance ratio for these Chandra observations.

  2. Inclusive measurement of (p,. pi. /sup -/xn) double charge exchange reactions on bismuth from threshold to 800 MeV

    SciTech Connect

    Dombsky, M.; D'Auria, J.M.; Kelson, I.; Yavin, A.I.; Ward, T.E.; Clark, J.L.; Ruth, T.; Sheffer, G.

    1985-07-01

    The energy dependence of the total angle-integrated cross section for the production of astatine isotopes from (p,..pi../sup -/xn) double charge exchange reactions on bismuth (/sup 209/Bi) was measured from 120 to 800 MeV using activation and radiochemical techniques. Chemical yields were estimated by direct radioassaying of /sup 211/At activity in thin (approx.1 mg/cm/sup 2/), irradiated bismuth targets. Calculations of the contributions of secondary (two-step) reactions to these measured astatine yields were performed, based partially upon the observed /sup 211/At activity although even at the highest energies, the contribution to products lighter than /sup 207/At was negligible. These data for products with as many as seven neutrons removed from the doubly coherent product (/sup 210/At) display nearly Gaussian shapes for the mass distributions of the astatine residues, with the maximum occurring for about /sup 204/At. The most probable momentum transfer deduced from these distributions for the initial ..pi../sup -/ production step was 335 MeV/c. The observed excitation functions display a behavior similar to that observed for the yield of /sup 210/Po from a (p,..pi../sup 0/) reaction on /sup 209/Bi, but radically different from that observed for inclusive ..pi../sup -/ reactions on a heavy nucleus. These data are discussed in terms of recent theoretical approaches to negative pion production from bismuth. In addition, a simple, schematic model is developed to treat the rapidly decreasing percentage of the total inclusive ..pi../sup -/ emission which is observed for this double charge exchange reaction. This model reflects the opacity of a nucleus to a source of internal energetic protons.

  3. Optimization and application of cooled avalanche photodiodes for spectroscopic fluctuation measurements with ultra-fast charge exchange recombination spectroscopy

    NASA Astrophysics Data System (ADS)

    Truong, D. D.; Fonck, R. J.; McKee, G. R.

    2016-11-01

    The Ultra-Fast Charge Exchange Recombination Spectroscopy (UF-CHERS) diagnostic is a highly specialized spectroscopic instrument with 2 spatial channels consisting of 8 spectral channels each and a resolution of ˜0.25 nm deployed at DIII-D to measure turbulent ion temperature fluctuations. Charge exchange emissions are obtained between 528 and 530 nm with 1 μs time resolution to study plasma instabilities. A primary challenge of extracting fluctuation measurements from raw UF-CHERS signals is photon and electronic noise. In order to reduce dark current, the Avalanche Photodiode (APD) detectors are thermo-electrically cooled. State-of-the-art components are used for the signal amplifiers and conditioners to minimize electronic noise. Due to the low incident photon power (≤1 nW), APDs with a gain of up to 300 are used to optimize the signal to noise ratio. Maximizing the APDs' gain while minimizing the excess noise factor (ENF) is essential since the total noise of the diagnostic sets a floor for the minimum level of detectable broadband fluctuations. The APDs' gain should be high enough that photon noise dominates electronic noise, but not excessive so that the ENF overwhelms plasma fluctuations. A new generation of cooled APDs and optimized preamplifiers exhibits significantly enhanced signal-to-noise compared to a previous generation. Experiments at DIII-D have allowed for characterization and optimization of the ENF vs. gain. A gain of ˜100 at 1700 V is found to be near optimal for most plasma conditions. Ion temperature and toroidal velocity fluctuations due to the edge harmonic oscillation in quiescent H-mode plasmas are presented to demonstrate UF-CHERS' capabilities.

  4. The Production of Energetic Atomic Beams via Charge Exchange for the Simulation of the Low-Earth Orbit Environment.

    NASA Astrophysics Data System (ADS)

    Ketsdever, Andrew David

    The interactions of energetic atoms with solid materials and other gases are important to a wide range of engineering disciplines. The interactions between low -Earth orbit (LEO) atomic oxygen and spacecraft surfaces, outgassed molecules, rocket exhaust plume species and other atmospheric gases are of great interest to the aerospace engineering community. The approach taken in this study was to design a facility which can be used to understand the physics of energetic gas-gas and gas-surface collisions. The type of facility needed to accomplish this requires a continuous, high energy (5-100eV) atomic beam with a low energy spread and a moderate flux. The flux of atoms from this facility, although estimated to be several orders of magnitude lower than LEO conditions, is sufficient to gain qualitative and quantitative insight into LEO environmental interactions. In the pilot scale true energy atmospheric simulator (TEAS) developed in this research, ion engine technology is incorporated to produce a beam of energetic ions. Because the ion source discharges can be operated on several gases, simulation of any atmospheric species can be achieved; however, atomic oxygen is the species of interest in this study. The ions are accelerated to the desired energy range and undergo a charge exchange process in molecular hydrogen to produce the energetic atomic beam Molecular hydrogen is chosen as the charge exchange gas because of the relatively large cross section for the reaction and the small scattering angle per collision. An electrostatic energy analyzer, a mass spectrometer and thin silver reaction films are used to diagnose the beams produced by the TEAS.

  5. Understanding the charge transport and polarities in organic donor-acceptor mixed-stack crystals: molecular insights from the super-exchange couplings.

    PubMed

    Geng, Hua; Zheng, Xiaoyan; Shuai, Zhigang; Zhu, Lingyun; Yi, Yuanping

    2015-02-25

    Charge transport and polarity in organic D-A mixed-stack crystals are examined in terms of super-exchange electronic couplings. When the super-exchange coupling is dominated by the interaction between donor HOMO and acceptor LUMO, ambipolar transport is achieved. Otherwise, involvement of other bridge orbitals can lead to unbalanced, even to unipolar transport in a special case that the HOMO-LUMO interaction vanishes.

  6. INTERACTION OF LASER RADIATION WITH MATTER. LASER PLASMA: Intense charge exchange of laser-plasma ions with the atoms of a pulsed gas jet

    NASA Astrophysics Data System (ADS)

    Antonov, V. M.; Boyarintsev, Y. L.; Melekhov, A. V.; Posukh, V. G.; Ponomarenko, A. G.; Shaikhislamov, I. F.

    2007-09-01

    The results of experiments on the interaction of a laser plasma with a pulsed gas jet are presented. The charge exchange of ions with neutral particles was realised for the first time under controllable conditions for a density of the reagents of no less than 1016 cm-3. The resonance pumping of the C3+ ion level with n=3 was observed by spectral methods. The structure of the region of intense charge exchange was determined from plasma photographs. The data obtained suggest that experiments on soft X-ray lasing at a C5+ ion transition are promising.

  7. Charge exchange between two nearest neighbour ions immersed in a dense plasma

    NASA Astrophysics Data System (ADS)

    Sauvan, P.; Angelo, P.; Derfoul, H.; Leboucher-Dalimier, E.; Devdariani, A.; Calisti, A.; Talin, B.

    1999-04-01

    In dense plasmas the quasimolecular model is relevant to describe the radiative properties: two nearest neighbor ions remain close to each other during a time scale of the order of the emission time. Within the frame of a quasistatic approach it has been shown that hydrogen-like spectral line shapes can exhibit satellite-like features. In this work we present the effect on the line shapes of the dynamical collision between the two ions exchanging transiently their bound electron. This model is suitable for the description of the core, the wings and the red satellite-like features. It is post-processed to the self consistent code (IDEFIX) giving the adiabatic transition energies and the oscillator strengths for the transient molecule immersed in a dense free electron bath. It is shown that the positions of the satellites are insensitive to the dynamics of the ion-ion collision. Results for fluorine Lyβ are presented.

  8. Charge exchange transition probability for collisions between unlike ions and atoms within the adiabatic approximation

    NASA Technical Reports Server (NTRS)

    Xu, Y. J.; Khandelwal, G. S.; Wilson, John W.

    1989-01-01

    A simple formula for the transition probability for electron exchange between unlike ions and atoms is established within the adiabatic approximation by employing the Linear Combination of Atomic Orbitals (LCAO) method. The formula also involves an adiabatic parameter, introduced by Massey, and thus the difficulties arising from the internal energy defect and the adiabatic approximation are avoided. Specific reactions Li(+++) + H to Li(++) + H(+) and Be(4+) + H to Be(3+) + H(+) are considered as examples. The calculated capture cross section results of the present work are compared with the experimental data and with the calculation of other authors over the velocity range of 10(7) cm/sec to 10(8) cm/sec.

  9. Solidification and immobilization of MSWI fly ash through aluminate geopolymerization: Based on partial charge model analysis.

    PubMed

    Zheng, Lei; Wang, Wei; Gao, Xingbao

    2016-12-01

    This study presents an integrated synopsis of the solidification and immobilization mechanisms of fly ash-based geopolymers. A rational analysis of the ion reactions involved in geopolymerization was conducted using the partial charge model (PCM). The following conclusions were obtained: (1) heavy metal cations cannot be immobilized as counter cations through exchange with Na(+); (2) isomorphous substitution of heavy metals in the geopolymer can be expected from the condensation reaction between the hydrolyzed heavy metal species and aluminosilicate; (3) the hydrolyzed species condensation could result in solidification and immobilization and be promoted by aluminates; and (4) a geopolymer with the highest immobilization and solidification efficiency can be obtained at an intermediate pH value. The partial charges on the framework of Si, Al, and O in the primary building blocks of aluminosilicate and heavy metal-doped aluminosilicate were confirmed through XPS and (29)Si NMR spectroscopy analyses. The effects of activator dosage and types on fly ash-based geopolymers were also investigated, and the results verify the PCM analysis. A geopolymer with the highest strength was produced at an intermediate alkaline dosage. Silicate or aluminate introduced into the activator improved the strength and immobilization efficiency, and aluminate exhibited better performance. Heavy metals bound to the exchangeable or acid-soluble fraction were transformed into aluminosilicate species during geopolymerization.

  10. Sorption of doubly charged metal ions from ammonium fluoride solutions by KFP-23 cation-exchange resin

    SciTech Connect

    Ganyaev, V.P.; Pimneva, L.A.; Pakholkov, V.S.

    1982-10-20

    This report examines the results of a study of sorption of a number of doubly charged cations by the macroporous cation-exchange KFP-12 from 0.1 N MeF/sub 2/ solutions containing NH/sub 4/F in concentrations from 0 to 3.0 M. As the result of an investigation of the sorption, under dynamic conditions, of copper, zinc, cadmium, manganese, cobalt, and nickel ions from ammonium fluoride solutions by KFP-12 cation-exchange resin in the influence of the ionic form (H/sup +/ or NH/sub 4//sup +/) of the resin and of the NH/sub 4/F concentration on the degree of sorption and on the breakthrough capacity was established. The character of bonding and coordination of the sorbed cations with the ionic groups of the resin has been established. The possibilty of thorough purification of ammonium fluoride and (NH/sub 4/)/sub 2/BeF/sub 4/ solutions with the aid of KFP-12 resin in NH/sub 4//sup +/ form has been demonstrated. The purification co-efficients were calculated.

  11. Plasma Vehicle Charging Analysis for Orion Flight Test 1

    NASA Technical Reports Server (NTRS)

    Lallement, L.; McDonald, T.; Norgard, J.; Scully, B.

    2014-01-01

    In preparation for the upcoming experimental test flight for the Orion crew module, considerable interest was raised over the possibility of exposure to elevated levels of plasma activity and vehicle charging both externally on surfaces and internally on dielectrics during the flight test orbital operations. Initial analysis using NASCAP-2K indicated very high levels of exposure, and this generated additional interest in refining/defining the plasma and spacecraft models used in the analysis. This refinement was pursued, resulting in the use of specific AE8 and AP8 models, rather than SCATHA models, as well as consideration of flight trajectory, time duration, and other parameters possibly affecting the levels of exposure and the magnitude of charge deposition. Analysis using these refined models strongly indicated that, for flight test operations, no special surface coatings were necessary for the thermal protection system, but would definitely be required for future GEO, trans-lunar, and extra-lunar missions...

  12. Plasma Vehicle Charging Analysis for Orion Flight Test 1

    NASA Technical Reports Server (NTRS)

    Scully, B.; Norgard, J.

    2015-01-01

    In preparation for the upcoming experimental test flight for the Orion crew module, considerable interest was raised over the possibility of exposure to elevated levels of plasma activity and vehicle charging both externally on surfaces and internally on dielectrics during the flight test orbital operations. Initial analysis using NASCAP-2K indicated very high levels of exposure, and this generated additional interest in refining/defining the plasma and spacecraft models used in the analysis. This refinement was pursued, resulting in the use of specific AE8 and AP8 models, rather than SCATHA models, as well as consideration of flight trajectory, time duration, and other parameters possibly affecting the levels of exposure and the magnitude of charge deposition. Analysis using these refined models strongly indicated that, for flight test operations, no special surface coatings were necessary for the Thermal Protection System (TPS), but would definitely be required for future GEO, trans-lunar, and extra-lunar missions.

  13. Experimental investigation of the reaction of helium ions with dimethyl ether: stereodynamics of the dissociative charge exchange process.

    PubMed

    Cernuto, Andrea; Tosi, Paolo; Martini, Luca Matteo; Pirani, Fernando; Ascenzi, Daniela

    2017-03-09

    The fate of dimethyl ether (DME, CH3OCH3) in collisions with He(+) ions is of high relevance for astrochemical models aimed at reproducing the abundances of complex organic molecules in the interstellar medium. Here we report an investigation on the reaction of He(+) ions with DME carried out using a Guided Ion Beam Mass Spectrometer (GIB-MS), which allows the measurement of reactive cross-sections and branching ratios (BRs) as a function of the collision energy. We obtain insights into the dissociative charge (electron) exchange mechanism by investigating the nature of the non-adiabatic transitions between the relevant potential energy surfaces (PESs) in an improved Landau-Zener approach. We find that the large interaction anisotropy could induce a pronounced orientation of the polar DME molecule in the electric field generated by He(+) so that at short distances the collision complex is confined within pendular states, a particular case of bending motion, which gives rise to intriguing stereodynamic effects. The positions of the intermolecular potential energy curve crossings indicate that He(+) captures an electron from an inner valence orbital of DME, thus causing its dissociation. In addition to the crossing positions, the symmetry of the electron density distribution of the involved DME orbitals turns out to be a further major point affecting the probability of electron transfer. Thus, the anisotropy of the intermolecular interaction and the electron densities of the orbitals involved in the reaction are the key "ingredients" for describing the dynamics of this dissociative charge transfer.

  14. A Cold Atom Measurement of Charge Exchange Collisions between Trapped Yb^+ and Yb

    NASA Astrophysics Data System (ADS)

    Grier, Andrew; Cetina, Marko; Orucevic, Fedja; Vuletic, Vladan

    2008-05-01

    We measure the collisional cross-section and rate constant of the ^174Yb and ^172Yb^+ charge-transfer process. The neutral atoms are trapped in a magneto-optical trap (MOT) resonant with their 399 nm, ^1S0->^1P1 transition and are near the Doppler-limited temperature of 680 μK. The ions are confined in a planar Paul trap with a secular frequency of 39 kHz, Doppler cooled, and spatially overlapped with the neutral atoms. The collisional energy is varied from 4 meV to 100s of neV by varying the micromotion energy of the ions by displacement from the center of the Paul trap. We report the rate constant in comparison to that derived from the Langevin cross-section.

  15. Quantum-mechanical interference in charge exchange between hydrogen and graphene-like surfaces.

    PubMed

    Romero, M; Iglesias-García, A; Goldberg, E C

    2012-02-01

    The neutral to negative charge fluctuation of a hydrogen atom in front of a graphene surface is calculated by using the Anderson model within an infinite intra atomic Coulomb repulsion approximation. We perform an ab initio calculation of the Anderson hybridization function that allows investigation of the effect of quantum-mechanical interference related to the Berry phase inherent to the graphene band structure. We find that consideration of the interaction of hydrogen on top of many C atoms leads to a marked asymmetry of the imaginary part of the hybridization function with respect to the Fermi level. Consequently, Fano factors larger than one and strongly dependent on the energy around the Fermi level are predicted. Moreover, the suppression of the hybridization for energies above the Fermi level can explain the unexpected large negative ion formation measured in the scattering of protons by graphite-like surfaces.

  16. Thermodynamic analysis and optimization of air-cooled heat exchangers

    NASA Astrophysics Data System (ADS)

    Salimpour, Mohammad Reza; Bahrami, Zabihollah

    2011-01-01

    In the present study, a thermodynamic second-law analysis was performed to investigate the effects of different geometry and flow parameters on the air-cooled heat exchanger performance. For this purpose, the entropy generation due to heat transfer and pressure loss of internal and external flows of the air-cooled heat exchanger was calculated; and it was observed that the total entropy generation has a minimum at special tube-side Reynolds number. Also, it was seen that the increasing of the tube-side Reynolds number resulted in the rise of the irreversibility of the air-cooled heat exchanger. The results also showed when air-side Reynolds number decreased, the entropy generation rate of the external flow reduced. Finally, based on the computed results, a new correlation was developed to predict the optimum Reynolds number of the tube-side fluid flow.

  17. Multivariate Comparative Analysis of Stock Exchanges: The European Perspective

    NASA Astrophysics Data System (ADS)

    Koralun-Bereźnicka, Julia

    The aim of the research is to perform a multivariate comparative analysis of 20 European stock exchanges in order to identify the main similarities between the objects. Due to the convergence process of capital markets in Europe the similarities between stock exchanges could be expected to increase over time. The research is meant to show whether and how these similarities change. Consequently, the distances between clusters of similar stock exchanges should become less significant, which the analysis also aims at verifying. The basis of comparison is a set of 48 monthly variables from the period January, 2003 to December, 2006. The variables are classified into three categories: size of the market, equity trading and bonds. The paper aims at identifying the clusters of alike stock exchanges and at finding the characteristic features of each of the distinguished groups. The obtained categorization to some extent corresponds with the division of the European Union into “new” and “old” member countries. Clustering method, performed for each quarter separately, also reveals that the classification is fairly stable in time. The factor analysis, which was carried out to reduce the number of variables, reveals three major factors behind the data, which are related with the earlier mentioned categories of variables.

  18. Spin exchange dominated by charge fluctuations of the Wigner lattice in the chain cuprate Na5Cu3O6

    NASA Astrophysics Data System (ADS)

    Ali, Naveed Zafar; Sirker, Jesko; Nuss, Jürgen; Horsch, Peter; Jansen, Martin

    2011-07-01

    Na5Cu3O6, a new member of one-dimensional charge-ordered chain cuprates, was synthesized via the azide/nitrate route by reacting NaN3, NaNO3, and CuO. According to single-crystal x-ray analysis, one-dimensional ∞1CuO2n- chains built up from planar, edge-sharing CuO4 squares are a dominant feature of the crystal structure. From the analysis of the Cu-O bond lengths, we find that the system forms a Wigner lattice. The commensurate charge order allows the explicit assignment of the valence states of either +2 or +3 to each copper atom, resulting in a repetition according to Cu2+-Cu3+-Cu2+-Cu2+-Cu3+-Cu2+. Following the theoretical analysis of the previously synthesized compounds Na3Cu2O4 and Na8Cu5O10, the magnetic susceptibility was expected to show a large dimer gap. Surprisingly, this is not the case. To resolve this puzzle, we show that the magnetic couplings in this compound are strongly affected by excitations across the Wigner charge gap. By including these contributions, which are distinct from conventional superexchange in Mott-insulators, we obtain a quantitatively satisfying theoretical description of the magnetic susceptibility data.

  19. Low heat transfer oxidizer heat exchanger design and analysis

    NASA Technical Reports Server (NTRS)

    Kanic, P. G.; Kmiec, T. D.; Peckham, R. J.

    1987-01-01

    The RL10-IIB engine, a derivative of the RLIO, is capable of multi-mode thrust operation. This engine operates at two low thrust levels: tank head idle (THI), which is approximately 1 to 2 percent of full thrust, and pumped idle (PI), which is 10 percent of full thrust. Operation at THI provides vehicle propellant settling thrust and efficient engine thermal conditioning; PI operation provides vehicle tank pre-pressurization and maneuver thrust for log-g deployment. Stable combustion of the RL10-IIB engine at THI and PI thrust levels can be accomplished by providing gaseous oxygen at the propellant injector. Using gaseous hydrogen from the thrust chamber jacket as an energy source, a heat exchanger can be used to vaporize liquid oxygen without creating flow instability. This report summarizes the design and analysis of a United Aircraft Products (UAP) low-rate heat transfer heat exchanger concept for the RL10-IIB rocket engine. The design represents a second iteration of the RL10-IIB heat exchanger investigation program. The design and analysis of the first heat exchanger effort is presented in more detail in NASA CR-174857. Testing of the previous design is detailed in NASA CR-179487.

  20. The Uranian corona as a charge exchange cascade of plasma sheet protons

    NASA Astrophysics Data System (ADS)

    Herbert, F.

    1993-03-01

    The paper uses models of magnetic convection and interparticle interactions to examine the collisional interactions between atmospheric neutral hydrogen and magnetospheric charged particles observed by Voyager to be convecting through the Uranian magnetosphere. The e(-)-H collisional ionization process, continually reenergized by compressional heating of the electrons as they drift toward Uranus, produces a cascade of new plasma. This process has been suggested elsewhere as the source of the warm (10 eV at L = 5) plasma and is found in the present study to continue in a cascade to even cooler and more abundant plasma. This newly created plasma consists almost entirely of electrons and protons because He and H2 are nearly absent from the uppermost layers of the atmosphere. If this plasma crosses the dayside magnetopause and mixes with magnetopause boundary layers such as the plasma mantle, there to be swept back along the magnetotail, reincorporated into the magnetotail by the same processes postulated for solar wind plasma entry, and reenergized in the magnetotail current sheet, it would constitute an important source for the hot plasma observed by Voyager.

  1. X-ray and EUV spectroscopy of various astrophysical and laboratory plasmas: Collisional, photoionization and charge-exchange plasmas

    SciTech Connect

    Liang, G. Y.; Li, F.; Wang, F. L.; Zhong, J. Y.; Zhao, G.; Wu, Y.

    2014-03-10

    Several laboratory facilities were used to benchmark theoretical spectral models that are extensively used by astronomical communities. However, there are still many differences between astrophysical environments and laboratory miniatures that can be archived. Here we setup a spectral analysis system for astrophysical and laboratory plasmas to make a bridge between them, and we investigate the effects from non-thermal electrons and the contributions from a metastable level population on level populations and charge stage distribution for coronal-like, photoionized, and geocoronal plasmas. Test applications to laboratory measurement (i.e., electron beam ion trap plasma) and astrophysical observation (i.e., Comet, Cygnus X-3) are presented. A time evolution of the charge stage and level population are also explored for collisional and photoionized plasmas.

  2. Charge Exchange-induced X-Ray Emission of Fe xxv and Fe xxvI via a Streamlined Model

    NASA Astrophysics Data System (ADS)

    Mullen, P. D.; Cumbee, R. S.; Lyons, D.; Stancil, P. C.

    2016-06-01

    Charge exchange (CX) is an important process for the modeling of X-ray spectra obtained by the Chandra, XMM-Newton, and Suzaku X-ray observatories, as well as the anticipated Astro-H mission. The understanding of the observed X-ray spectra produced by many astrophysical environments is hindered by the current incompleteness of available atomic and molecular data—especially for CX. Here, we implement a streamlined program set that applies quantum defect methods and the Landau-Zener theory to generate total, n-resolved, and n{\\ell }S-resolved cross sections for any given projectile ion/target CX collision. By using these data in a cascade model for X-ray emission, theoretical spectra for such systems can be predicted. With these techniques, Fe25+ and Fe26+ CX collisions with H, He, H2, N2, H2O, and CO are studied for single-electron capture (SEC). These systems have been selected because they illustrate computational difficulties for high projectile charges. Furthermore, Fe xxv and Fe xxvi emission lines have been detected in the Galactic center and Galactic ridge. Theoretical X-ray spectra for these collision systems are compared to experimental data generated by an electron-beam ion trap study. Several ℓ-distribution models have been tested for Fe25+ and Fe26+ SEC. Such analyses suggests that commonly used ℓ-distribution models struggle to accurately reflect the true distribution of electron capture as understood by more advanced theoretical methods.

  3. Charged Particle Multiplicity Analysis in MicroBooNE

    NASA Astrophysics Data System (ADS)

    Rafique, Aleena; MicroBooNE Experiment Collaboration

    2017-01-01

    MicroBooNE is a short baseline neutrino experiment that utilizes 89 ton active volume liquid argon Time Projection Chamber (TPC) situated on the Booster Neutrino Beamline at Fermilab. It is the first of three liquid argon TPC detectors planned for the Fermilab Short Baseline Neutrino program and will directly probe the source of the anomalous excess of electron-like events in MiniBooNE, while also measuring low-energy neutrino cross sections and providing important R&D for future detectors. In this talk, a study of charged particle multiplicity using neutrino charged-current inclusive events is presented. This analysis can be used to test models of neutrino-argon scattering, and it may be particularly sensitive to nuclear final state interaction effects. Kansas State University.

  4. Threshold for Transportation Charge Review Cost Benefit Analysis

    DTIC Science & Technology

    1990-07-01

    ole ai m o of Informtion is erstimreto rq htC0Ccion.ieldn ttm for 1111~~n mnttc2os ieem goewnS data vnu’rnq*Ve.I..o e (d me oin in o t ae ata ne.ed. sn...S u ite 1 0 4 .A ln g tO n . V A 2 2 2 0 2 -4 1 0 2 . a n d to th e O ff ice o f M a n a q e m e n t d u d e t. P"o t R e d u t ian P c 0ot1 0 ? 0...charges after they are reviewed and approved. This cost-benefit analysis found that the transportation charge threshold rhould be changed to $190. e

  5. Statistical analysis of the particulation of shaped charge jets

    SciTech Connect

    Minich, R W, Baker, E L; Schwartz, A J

    1999-08-12

    A statistical analysis of shaped charge jet break-up was carried out in order to investigate the role of nonlinear instabilities leading to the particulation of the jet. Statistical methods generally used for studying fluctuations in nonlinear dynamical systems are applied to experimentally measured velocities of the individual particles. In particular we present results suggesting the deviation of non-Gaussian behavior for interparticle velocity correlations, characteristic of nonlinear dynamical systems. Results are presented for two silver shaped charge jets that differ primarily in their material processing. We provide evidence that the particulation of a jet is not random, but has its origin in a deterministic dynamical process involving the nonlinear coupling of two oscillators analogous to the underling dynamics observed in Rayleigh-Benard convection and modeled in the return map of Curry and Yorke.

  6. Pion single charge exchange scattering from 3He at 285, 428, and 525 MeV

    NASA Astrophysics Data System (ADS)

    Källne, J.; Altemus, R.; Gugelot, P. C.; McCarthy, J. S.; Minehart, R. C.; Orphanos, L.; Gram, P. A. M.; Höistad, B.; Morris, C. L.; Wadlinger, E. A.; Perdrisat, C. F.

    1982-02-01

    We have measured the cross section of 3He(π-,π0)3H at T=285, 428, and 525 MeV for angles in the range of 60°<~θ<~135° covering the momentum transfer range 0.5<~q<~1.0 GeV/c. Comparison is made with Glauber model calculations to discuss the sensitivity to nuclear structure and pion-nucleus interaction effects. NUCLEAR REACTIONS π-+3He-->3H+π0, T=285, 428, and 525 MeV, θπ0~70-140° measured σ(θt,Tπ). Analysis based on optical and Glauber model predictions.

  7. Wide-view charge exchange recombination spectroscopy diagnostic for Alcator C-Moda)

    NASA Astrophysics Data System (ADS)

    Rowan, W. L.; Bespamyatnov, I. O.; Granetz, R. S.

    2008-10-01

    This diagnostic measures temperature, density, and rotation for the fully stripped boron ion between the pedestal top and the plasma core with resolution consistent with the profile gradients. The diagnostic neutral beam used for the measurements generates a 50 keV, 6 A hydrogen beam. The optical systems provide views in both poloidal and toroidal directions. The imaging spectrometer is optimized to simultaneously accept 45 views as input with minimum cross-talk. In situ calibration techniques are applied for spatial location, spectral intensity, and wavelength. In the analysis, measured spectra are fitted to a model constructed from a detailed description of the emission physics. Methods for removal of interfering spectra are included. Applications include impurity and thermal transport.

  8. Transient energetic charge exchange flux enhancement observed in NSTX neutral-beam-heated H-mode discharges

    NASA Astrophysics Data System (ADS)

    Medley, S. S.; Kramer, G. J.; Bell, R. E.; Belova, E.; Fredrickson, E. D.; Gerhardt, S. P.; Leblanc, B. P.; Podestá, M.; Ren, Y.; Roquemore, A. L.; Crocker, N. A.; NSTX Team

    2011-10-01

    Large increases in the E | | B Neutral Particle Analyzer (NPA) charge exchange neutral flux localized at the Neutral Beam Injection (NBI) full energy are observed in the National Spherical Torus Experiment (NSTX). Termed the High-Energy Feature (HEF), it appears only at the NBI full energy, exhibits growth times ~ 20-80 ms, seldom develops a slowing down distribution and arises only in discharges where NTM modes (f < 30 kHz) are absent, TAE activity (f ~ 30-150 kHz) is weak and GAE/CAE activity (f ~ 400-1200 kHz) is robust. The HEF occurs only in H-mode discharges with Pb >= 3 MW and v||/v ~ 0.7-0.9; i.e. only for passing ions. The HEF appears to be caused by a GAE wave-particle interaction that modifies of the NB fast ion distribution, fi(E,v||/v,r). This proposed mechanism was studied using the SPIRAL code that imports a TRANSP-calculated fi(E,v||/v,r) distribution and evolves it under drive from GAE wave-particle resonances. Supported by U.S. DoE Contract Nos. DE-AC02-09CH11466, DE-FG02-99ER54527.

  9. Charge-exchange X-ray emission of M82: Kα triplets of O VII, Ne IX and Mg XI

    NASA Astrophysics Data System (ADS)

    Liu, Jiren; Mao, Shude; Wang, Q. Daniel

    2011-07-01

    Starburst galaxies are primary feedback sources of mechanical energy and metals, which are generally measured from associated X-ray emission lines, assuming that they are from the thermal emission of the outflowing hot gas. Such line emission, however, can also arise from the charge-exchange X-ray emission (CXE) between highly ionized ions and neutral species. To understand the feedback of energy and metals, it is crucial to determine the origin of the X-ray emission lines and to distinguish the contributions from the CXE and the thermal emission. The origin of the lines can be diagnosed by the Kα triplets of He-like ions, because the CXE favours the intercombination and forbidden lines, while the thermal emission favours the resonance line. We analyse the triplets of O VII, Ne IX and Mg XI observed in the XMM-Newton reflection grating spectra of the starburst galaxy M82. The flux contribution of the CXE is 90, 50 and 30 per cent to the O VII, Ne IX and Mg XI triplets, respectively. Averaged over all the three triplets, the contribution of the CXE is ˜50 per cent of the total observed triplet flux. To correctly understand the hot outflow of starburst galaxies, it is necessary to include the CXE. Based on the measured CXE fluxes of the O VII, Ne IX and Mg XI triplets, we estimate the relative abundances of O, Ne and Mg of the outflow and find they are similar to the solar ratios.

  10. Microscopic analysis of currency and stock exchange markets

    NASA Astrophysics Data System (ADS)

    Kador, L.

    1999-08-01

    Recently it was shown that distributions of short-term price fluctuations in foreign-currency exchange exhibit striking similarities to those of velocity differences in turbulent flows. Similar profiles represent the spectral-diffusion behavior of impurity molecules in disordered solids at low temperatures. It is demonstrated that a microscopic statistical theory of the spectroscopic line shapes can be applied to the other two phenomena. The theory interprets the financial data in terms of information which becomes available to the traders and their reactions as a function of time. The analysis shows that there is no characteristic time scale in financial markets, but that instead stretched-exponential or algebraic memory functions yield good agreement with the price data. For an algebraic function, the theory yields truncated Lévy distributions which are often observed in stock exchange markets.

  11. Microscopic analysis of currency and stock exchange markets.

    PubMed

    Kador, L

    1999-08-01

    Recently it was shown that distributions of short-term price fluctuations in foreign-currency exchange exhibit striking similarities to those of velocity differences in turbulent flows. Similar profiles represent the spectral-diffusion behavior of impurity molecules in disordered solids at low temperatures. It is demonstrated that a microscopic statistical theory of the spectroscopic line shapes can be applied to the other two phenomena. The theory interprets the financial data in terms of information which becomes available to the traders and their reactions as a function of time. The analysis shows that there is no characteristic time scale in financial markets, but that instead stretched-exponential or algebraic memory functions yield good agreement with the price data. For an algebraic function, the theory yields truncated Lévy distributions which are often observed in stock exchange markets.

  12. Studies of energetic confined alphas using the pellet charge exchange diadgnostic on TFTR

    SciTech Connect

    Petrov, M.P.; Budny, R.V.; Duong, H.H.

    1995-07-01

    Results from recent DT experiments on TFIR to measure the energy distribution and radial density profile of fast confined alphas with the use of Li pellets and neutral particle analysis are presented. When a pellet is injected into the plasma, a toroidally extended ablation cloud is formed that travels with the pellet. A small fraction of the fusion alphas incident on the cloud are converted to helium neutrals as a result of electron capture processes. The escaping energetic helium neutrals are analyzed and detected by the neutral particle analyzer. Radially resolved energy spectra of trapped confined alphas in 0.5-2 MeV range and radial alpha density profiles are presented in this paper. The experimental data are compared with modeling results obtained with the TRANSP Monte-Carlo Code and with a specially developed Fokker-Planck Post Processor (FPP) that uses the alpha source distribution produced by TRANSP. Comparison of the experimental data with TRANSP and FPP show that the alphas in the plasma core of sawtooth free discharges in TFIR are well confined and slow down classically. The energy and radial profiles distributions outside the plasma core show the influence of stochastic ripple losses on alphas. Measurements for sawtoothing plasmas show a significant outward radial transport of trapped alphas.

  13. Using (18)O/(16)O exchange to probe an equilibrium space-charge layer at the surface of a crystalline oxide: method and application.

    PubMed

    De Souza, Roger A; Martin, Manfred

    2008-05-07

    The use of an (18)O/(16)O exchange experiment as a means for probing surface space-charge layers in oxides is examined theoretically and experimentally. On the basis of a theoretical treatment, isotope penetration profiles are calculated for (18)O/(16)O exchange across a gas-solid interface and subsequent diffusion of the labelled isotope through an equilibrium space-charge layer depleted of mobile oxygen vacancies and into a homogeneous bulk phase. Profiles calculated for a range of conditions all have a characteristic shape: a sharp drop in isotope fraction close to the surface followed by a normal bulk diffusion profile. Experimental (18)O profiles in an exchanged (001) oriented single crystal of Fe-doped SrTiO(3) were measured by time-of-flight secondary ion mass spectrometry (ToF-SIMS). By extracting the space-charge potential from such profiles, we demonstrate that this method allows the spatially resolved characterization of space-charge layers at the surfaces of crystalline oxides under thermodynamically well-defined conditions.

  14. Charged Current Quasielastic Analysis from MINERνA

    SciTech Connect

    Ghosh, Anushree

    2015-08-01

    The MINERνA detector situated in Fermilab, is designed to make precision cross-section measurements for scattering processes on various nuclei. In this proceeding, the results of the charged current quasi-elastic (CCQE) analysis using lepton kinematics and with proton kinematics have been presented. Comparison of these with theoretical models suggested that further studies are required to include the additional nuclear effects in the current simulations. The first direct measurement of electron-neutrino quasielastic-like scattering in the few-GeV region of incident neutrino energy has also been presented. All three analyses, discussed here, are carried out on hydrocarbon target.

  15. Analysis of LEAM experiment response to charged particles

    NASA Technical Reports Server (NTRS)

    Perkins, D.

    1976-01-01

    The objectives of the Lunar Ejecta and Meteorites Experiment (LEAM) were to measure the long-term variations in cosmic dust influx rates and the extent and nature of the lunar ejecta. While analyzing these characteristics in the data, it was discovered that a majority of the events could not be associated with hypervelocity particle impacts of the type usually identified with cosmic dust, but could only be correlated with the lunar surface and local sun angle. The possibility that charged particles could be incident on the sensors led to an analysis of the electronics to determine if such signals could cause the large pulse height analysis (PHA) signals. A qualitative analysis of the PHA circuit showed that an alternative mode of operation existed if the input signal were composed of pulses with pulse durations very long compared to the durations for which it was designed. This alternative mode would give large PHA outputs even though the actual input amplitudes were small. This revelation led to the examination of the sensor and its response to charged particles to determine the type of signals that could be expected.

  16. EXCHANGE

    SciTech Connect

    Boltz, J.C.

    1993-01-01

    This report contains the following news headlines: ADPE acquisition process made easy with SRP; scientific reference material available; ORPS WordPerfect macro setup procedure; system managed storage is here; LIBSPOOL for MVS mainframe end-users; training center course schedule for February 1993; enjoy NJOY; scientific user services staff decreased; new release of Forwarn, a static source code analysis tool for FORTRAN programs; out of the cold with HEAT; coping cells from one table to another in word perfect; used PC equipment pool; and video training.

  17. Multifluid Modeling of the Partially Ionized Chromosphere with Effects of Impact Ionization, Radiative Recombination and Charge Exchange

    NASA Astrophysics Data System (ADS)

    Maneva, Y. G.; Poedts, D. S.; Alvarez Laguna, A.; Lani, A.

    2015-12-01

    Neutrals play an important role in the evolution of the weakly ionized solar chromosphere where the number density of neutrals can vastly exceed the number density of protons. Therefore modeling the neutral-ion interactions and studying the effect of neutrals on the ambient plasma properties is an important task for better understanding the observed emission lines and the propagation of disturbances from the photosphere to the transition region and the corona. To pursue this goal we have developed two-fluid and three-fluid simulation setups to study the interaction between electrons, ions and neutrals in a reactive gravitationally stratified collisional media. The model considers the electrons and ions within the resistive MHD approach with Coulomb collisions and anisotropic heat flux determined by Braginskii's transport coefficients. The electromagnetic fields are evolved according to the full Maxwell equations, allowing for propagation of higher frequency waves neglected by the standard MHD approximation. Separate mass, momentum and energy conservation equations are considered for the neutrals and the interaction between the different fluids is determined by the chemical reactions, such as impact ionization, radiative recombination and charge exchange, provided as additional source terms. To initialize the system we consider an ideal gas equation of state with equal initial temperatures for the electrons, ions and the neutrals and different density profiles. The initial temperature and density profiles are height-dependent and follow VAL C atmospheric model for the solar chromosphere. We have searched for a chemical and collisional equilibrium between the ions and the neutrals in the hydrostatic case to avoid unphysical outflows and artificial heating induced by initial pressure imbalances. Next we consider ion-neutral interactions in magnetized plasma with an initial magnetic profile, corresponding to emerging magnetic funnel. Finally we include an external

  18. Ultra-fast charge exchange spectroscopy for turbulent ion temperature fluctuation measurements on the DIII-D tokamak (invited)

    SciTech Connect

    Uzun-Kaymak, I. U.; Fonck, R. J.; McKee, G. R.

    2012-10-15

    A novel two-channel, high throughput, high efficiency spectrometer system has been developed to measure impurity ion temperature and toroidal velocity fluctuations associated with long-wavelength turbulence and other plasma instabilities. The spectrometer observes the emission of the n= 8-7 hydrogenic transition of C{sup +5} ions ({lambda}{sub air}= 529.06 nm) resulting from charge exchange reactions between deuterium heating beams and intrinsic carbon. Novel features include a large, prism-coupled high-dispersion, volume-phase-holographic transmission grating and high-quantum efficiency, high-gain, low-noise avalanche photodiode detectors that sample emission at 1 MHz. This new diagnostic offers an order-of-magnitude increase in sensitivity compared to earlier ion thermal turbulence measurements. Increased sensitivity is crucial for obtaining enough photon statistics from plasmas with much less impurity content. The irreducible noise floor set by photon statistics sets the ultimate sensitivity to plasma fluctuations. Based on the measured photon flux levels for the entire spectral line, photon noise levels for T(tilde sign){sub i}/T{sub i} and V(tilde sign){sub i}/V{sub i} of {approx}1% are expected, while statistical averaging over long data records enables reduction in the detectable plasma fluctuation levels to values less than that. Broadband ion temperature fluctuations are observed to near 200 kHz in an L-mode discharge. Cross-correlation with the local beam emission spectroscopy measurements demonstrates a strong coupling of the density and temperature fields, and enables the cross-phase measurements between density and ion temperature fluctuations.

  19. X-ray emission cross sections following Ar{sup 18+} charge-exchange collisions on neutral argon: The role of the multiple electron capture

    SciTech Connect

    Otranto, S.; Olson, R. E.

    2011-03-15

    X-ray emission originating in charge-exchange collisions between Ar{sup 18+} and neutral argon is studied at impact energies of 5-4000 eV/amu by means of the classical trajectory Monte Carlo method (CTMC). Line emission and charge-exchange cross sections obtained from different CTMC versions based on the one-active electron approximation are contrasted among themselves and against the results obtained by means of a three-active electron code that lets us infer the role of multiple electron capture. The present results are compared to the recent experimental data available from the EBIT groups operating at Livermore, NIST, and Berlin. We were not able to reconcile the major difference in x-ray emission cross sections obtained from in situ measurements made in EBIT, versus those made in an exterior, field-free collision chamber using ions extracted from the EBIT. Our calculations support the extracted beam results.

  20. Laboratory Measurements Compellingly Support a Charge-exchange Mechanism for the ’Dark Matter’ ~3.5 keV X-Ray Line

    NASA Astrophysics Data System (ADS)

    Shah, Chintan; Dobrodey, Stepan; Bernitt, Sven; Steinbrügge, René; Crespo López-Urrutia, José R.; Gu, Liyi; Kaastra, Jelle

    2016-12-01

    The reported observations of an unidentified X-ray line feature at ∼3.5 keV have driven a lively discussion about its possible dark matter origin. Motivated by this, we have measured the K-shell X-ray spectra of highly ionized bare sulfur ions following charge exchange with gaseous molecules in an electron beam ion trap, as a source of or a contributor to this X-ray line. We produced S16+ and S15+ ions and let them capture electrons in collision with those molecules with the electron beam turned off while recording X-ray spectra. We observed a charge-exchange-induced X-ray feature at the Lyman series limit (3.47 ± 0.06 keV). The inferred X-ray energy is in full agreement with the reported astrophysical observations and supports the novel scenario proposed by Gu et al.

  1. On Lunar Exospheric Column Densities and Solar Wind Access Beyond the Terminator from ROSAT Soft X-Ray Observations of Solar Wind Charge Exchange

    NASA Technical Reports Server (NTRS)

    Collier, Michael R.; Snowden, S. L.; Sarantos, M.; Benna, M.; Carter, J. A.; Cravens, T. E.; Farrell, W. M.; Fatemi, S.; Hills, H. Kent; Hodges, R. R.; Holmstrom, M.; Kuntz, K. D.; Porter, F. Scott; Read, A.; Robertson, I. P.; Sembay, S. F.; Sibeck, D. G.; Stubbs, T. J.; Travnicek, P.; Walsh, B. M.

    2014-01-01

    We analyze the Rontgen satellite (ROSAT) position sensitive proportional counter soft X-ray image of the Moon taken on 29 June 1990 by examining the radial profile of the surface brightness in three wedges: two 19 deg wedges (one north and one south) 13-32 deg off the terminator toward the dark side and one wedge 38 deg wide centered on the antisolar direction. The radial profiles of both the north and the south wedges show significant limb brightening that is absent in the 38 deg wide antisolar wedge. An analysis of the soft X-ray intensity increase associated with the limb brightening shows that its magnitude is consistent with that expected due to solar wind charge exchange (SWCX) with the tenuous lunar atmosphere based on lunar exospheric models and hybrid simulation results of solar wind access beyond the terminator. Soft X-ray imaging thus can independently infer the total lunar limb column density including all species, a property that before now has not been measured, and provide a large-scale picture of the solar wind-lunar interaction. Because the SWCX signal appears to be dominated by exospheric species arising from solar wind implantation, this technique can also determine how the exosphere varies with solar wind conditions. Now, along with Mars, Venus, and Earth, the Moon represents another solar system body at which SWCX has been observed.

  2. Fully self-consistent study of charge-exchange resonances and the impact on the symmetry energy parameters

    NASA Astrophysics Data System (ADS)

    Roca-Maza, X.; Cao, Li-Gang; Colò, G.; Sagawa, H.

    2016-10-01

    We have examined within a fully self-consistent theoretical framework the energy difference between the anti-analog giant dipole resonance (AGDR) and the isobaric analog state (IAS), EAGDR-EIAS , as an indicator of the neutron skin and of the density behavior of the symmetry energy. We have improved two specific points in our HF+RPA calculations: (1) the exchange term of the two-body Coulomb interaction is treated exactly without Slater approximation; and (2) the two-parameters spin-orbit interaction is treated in a consistent way within the energy density functional theory. The estimated values for the neutron skin in 208Pb and the slope parameter of symmetry energy are compared with previous analysis available in the literature.

  3. Performance analysis of charge plasma based dual electrode tunnel FET

    NASA Astrophysics Data System (ADS)

    Anand, Sunny; Intekhab Amin, S.; Sarin, R. K.

    2016-05-01

    This paper proposes the charge plasma based dual electrode doping-less tunnel FET (DEDLTFET). The paper compares the device performance of the conventional doping-less TFET (DLTFET) and doped TFET (DGTFET). DEDLTEFT gives the superior results with high ON state current (ION ∼ 0.56 mA/μm), ION/IOFF ratio ∼ 9.12 × 1013 and an average subthreshold swing (AV-SS ∼ 48 mV/dec). The variation of different device parameters such as channel length, gate oxide material, gate oxide thickness, silicon thickness, gate work function and temperature variation are done and compared with DLTFET and DGTFET. Through the extensive analysis it is found that DEDLTFET shows the better performance than the other two devices, which gives the indication for an excellent future in low power applications.

  4. Chromosome breakage and sister chromatid exchange analysis in computer operators

    SciTech Connect

    Butler, M.G.; Yost, J.; Jenkins, B.B.

    1987-01-01

    Chromosome breakage analysis with Mitomycin C (MMC) and sister chromatid exchanges (SCE) were obtained on 10 computer operators with computer exposure for a minimum of 3 hours per day for 4 years and 10 control subjects matched for age and personal lifestyle. No difference was found between the two groups in the total number of chromatid and chromosome aberrations in cells grown at 48 and/or 96 hours in Mitomycin C (20 or 50 ng/ml-final concentration). The average number of SCE per cell in approximately 30 cells from each person was 6.4 +/- 1.1 (mean +/- standard deviation) for the computer operators and 9.2 +/- 1.6 for the controls. This difference was significant (p < .001). The replicative index was significantly higher (p < .01) in computer operators than in control subjects. The number of SCE appeared not to be influenced by the years of computer exposure. Additional studies with larger sample sizes will be needed to identify if significant differences exist in cell kinetics and sister chromatid exchanges in individuals employed as computer operators.

  5. PARAFAC analysis of IBIL spectra from silver ion exchanged glasses

    NASA Astrophysics Data System (ADS)

    Valotto, G.; Cattaruzza, E.; Mardegan, M.; Quaranta, A.

    2017-01-01

    In this work we present for the first time an application of PARAllel FACtor (PARAFAC) analysis to the investigation of Ion Beam Induced Luminescence (IBIL) spectra of Ag+ ↔ Na+ ion exchanged silicate glasses, in order to check the possibility to obtain additional information on the formation of silver aggregates under ion irradiation by a proper statistical rearrangement of experimental spectra. We decomposed the data by PARAFAC taking into account both IBIL emission features and their evolution as a function of the time. Shape and trend under irradiation of the extracted components were correlated to silver concentration and aggregates in the investigated systems. Strength and weakness of this statistical approach applied to IBIL spectra recorded as a function of time were evidenced and discussed.

  6. Revised Thermal Analysis of LANL Ion Exchange Column

    SciTech Connect

    Laurinat, J

    2006-04-11

    This document updates a previous calculation of the temperature distributions in a Los Alamos National Laboratory (LANL) ion exchange column.1 LANL operates two laboratory-scale anion exchange columns, in series, to extract Pu-238 from nitric acid solutions. The Defense Nuclear Facilities Safety Board has requested an updated analysis to calculate maximum temperatures for higher resin loading capacities obtained with a new formulation of the Reillex HPQ anion exchange resin. The increased resin loading capacity will not exceed 118 g plutonium per L of resin bed. Calculations were requested for normal operation of the resin bed at the minimum allowable solution feed rate of 30 mL/min and after an interruption of flow at the end of the feed stage, when one of the columns is fully loaded. The object of the analysis is to demonstrate that the decay heat from the Pu-238 will not cause resin bed temperatures to increase to a level where the resin significantly degrades. At low temperatures, resin bed temperatures increase primarily due to decay heat. At {approx}70 C a Low Temperature Exotherm (LTE) resulting from the reaction between 8-12 M HNO{sub 3} and the resin has been observed. The LTE has been attributed to an irreversible oxidation of pendant ethyl benzene groups at the termini of the resin polymer chains by nitric acid. The ethyl benzene groups are converted to benzoic acid moities. The resin can be treated to permanently remove the LTE by heating a resin suspension in 8M HNO{sub 3} for 30-45 minutes. No degradation of the resin performance is observed after the LTE removal treatment. In fact, heating the resin in boiling ({approx}115-120 C) 12 M HNO{sub 3} for 3 hr displays thermal stability analogous to resin that has been treated to remove the LTE. The analysis is based on a previous study of the SRS Frames Waste Recovery (FWR) column, performed in support of the Pu-238 production campaign for NASA's Cassini mission. In that study, temperature transients

  7. Reliability analysis on a shell and tube heat exchanger

    NASA Astrophysics Data System (ADS)

    Lingeswara, S.; Omar, R.; Mohd Ghazi, T. I.

    2016-06-01

    A shell and tube heat exchanger reliability was done in this study using past history data from a carbon black manufacturing plant. The heat exchanger reliability study is vital in all related industries as inappropriate maintenance and operation of the heat exchanger will lead to major Process Safety Events (PSE) and loss of production. The overall heat exchanger coefficient/effectiveness (Uo) and Mean Time between Failures (MTBF) were analyzed and calculated. The Aspen and down time data was taken from a typical carbon black shell and tube heat exchanger manufacturing plant. As a result of the Uo calculated and analyzed, it was observed that the Uo declined over a period caused by severe fouling and heat exchanger limitation. This limitation also requires further burn out period which leads to loss of production. The MTBF calculated is 649.35 hours which is very low compared to the standard 6000 hours for the good operation of shell and tube heat exchanger. The guidelines on heat exchanger repair, preventive and predictive maintenance was identified and highlighted for better heat exchanger inspection and repair in the future. The fouling of heat exchanger and the production loss will be continuous if proper heat exchanger operation and repair using standard operating procedure is not followed.

  8. Chemical analysis of charged Li/SO(sub)2 cells

    NASA Technical Reports Server (NTRS)

    Subbarao, S.; Lawson, D.; Frank, H.; Halpert, G.; Barnes, J.; Bis, R.

    1987-01-01

    The initial focus of the program was to confirm that charging can indeed result in explosions and constitute a significant safety problem. Results of this initial effort clearly demonstrated that cells do indeed explode on charge and that charging does indeed constitute a real and severe safety problem. The results of the effort to identify the chemical reactions involved in and responsible for the observed behavior are described.

  9. Charge-dependent model for many-body polarization, exchange, and dispersion interactions in hybrid quantum mechanical/molecular mechanical calculations.

    PubMed

    Giese, Timothy J; York, Darrin M

    2007-11-21

    This work explores a new charge-dependent energy model consisting of van der Waals and polarization interactions between the quantum mechanical (QM) and molecular mechanical (MM) regions in a combined QMMM calculation. van der Waals interactions are commonly treated using empirical Lennard-Jones potentials, whose parameters are often chosen based on the QM atom type (e.g., based on hybridization or specific covalent bonding environment). This strategy for determination of QMMM nonbonding interactions becomes tedious to parametrize and lacks robust transferability. Problems occur in the study of chemical reactions where the "atom type" is a complex function of the reaction coordinate. This is particularly problematic for reactions, where atoms or localized functional groups undergo changes in charge state and hybridization. In the present work we propose a new model for nonelectrostatic nonbonded interactions in QMMM calculations that overcomes many of these problems. The model is based on a scaled overlap model for repulsive exchange and attractive dispersion interactions that is a function of atomic charge. The model is chemically significant since it properly correlates atomic size, softness, polarizability, and dispersion terms with minimal one-body parameters that are functions of the atomic charge. Tests of the model are examined for rare-gas interactions with neutral and charged atoms in order to demonstrate improved transferability. The present work provides a new framework for modeling QMMM interactions with improved accuracy and transferability.

  10. Analysis of the heat transfer in double and triple concentric tube heat exchangers

    NASA Astrophysics Data System (ADS)

    Rădulescu, S.; Negoiţă, L. I.; Onuţu, I.

    2016-08-01

    The tubular heat exchangers (shell and tube heat exchangers and concentric tube heat exchangers) represent an important category of equipment in the petroleum refineries and are used for heating, pre-heating, cooling, condensation and evaporation purposes. The paper presents results of analysis of the heat transfer to cool a petroleum product in two types of concentric tube heat exchangers: double and triple concentric tube heat exchangers. The cooling agent is water. The triple concentric tube heat exchanger is a modified constructive version of double concentric tube heat exchanger by adding an intermediate tube. This intermediate tube improves the heat transfer by increasing the heat area per unit length. The analysis of the heat transfer is made using experimental data obtained during the tests in a double and triple concentric tube heat exchanger. The flow rates of fluids, inlet and outlet temperatures of water and petroleum product are used in determining the performance of both heat exchangers. Principally, for both apparatus are calculated the overall heat transfer coefficients and the heat exchange surfaces. The presented results shows that triple concentric tube heat exchangers provide better heat transfer efficiencies compared to the double concentric tube heat exchangers.

  11. Wannier function analysis of charge states in transition metal oxides

    NASA Astrophysics Data System (ADS)

    Quan, Yundi; Pickett, Warren

    2015-03-01

    The charge (or oxidation) state of a cation has been a crucial concept in analyzing the electronic and magnetic properties of oxides as well as interpreting ``charge ordering'' metal-insulator transitions. In recent years a few methods have been proposed for the objective identification of charge states, beyond the conventional (and occasionally subjective) use of projected densities of states, weighted band structures (fatbands), and Born effective charges. In the past two decades Wannier functions (WFs) and particularly maximally localized WFs (MLWFs), have become an indispensable tool for several different purposes in electronic structure studies. These developments have motivated us to explore the charge state picture from the perspective of MLWFs. We will illustrate with a few transition metal oxide examples such as AgO and YNiO3 that the shape, extent, and location of the charge centers of the MLWFs provide insights into how cation-oxygen hybridization determines chemical bonding, charge distribution, and ``charge ordering.'' DOE DE-FG02-04ER46111.

  12. XMM-Newton Observations of MBM 12: More Constraints on the Solar Wind Charge Exchange and Local Bubble Emissions

    NASA Technical Reports Server (NTRS)

    Koutroumpa, Dimitra; Smith, Randall K.; Edgar, Richard J.; Kuntz, Kip D.; Plucinsky, Paul P.; Snowden, Steven L.

    2010-01-01

    We present the first analysis of an XMM-Newton observation of the nearby molecular cloud MBM 12. We find that in the direction of MBM 12 the total O VII (0.57 keV) triplet emission is 1.8(+0.5/-0.6) photons/sq cm/s/sr (or Line Units - LU) while for the O VIII (0.65 keV) line emission we find a 3(sigma) upper limit of <1 LU. We also use a heliospheric model to calculate the O VII and O VIII emission generated by Solar Wind Charge-eXchange (SWCX) which we compare to the XMM-Newton observations. This comparison provides new constraints on the relative heliospheric and Local Bubble contributions to the local diffuse X-ray background. The heliospheric SWCX model predicts 0.82 LU for O VII, which accounts for approx. 46+/-15% of the observed value, and 0.33 LU for the O VIII line emission consistent with the XMM-Newton observed value. We discuss our results in combination with previous observations of the MBM 12 with CHANDRA and Suzaku.

  13. Analysis of electrostatic charge on small-arms projectiles

    NASA Astrophysics Data System (ADS)

    Vinci, Stephen; Zhu, Jack; Hull, David

    2012-06-01

    Triboelectric (frictional) and combustion processes impart electrostatic charge on projectiles as they are fired. Additional charging and discharging processes alter the magnitude of charge in-flight and are complex functions of a plethora of environmental conditions. There is an interest in using electric-field sensors to help detect and track projectiles in counter-sniper and projectile ranging systems. These applications require knowledge of the quantity of charge, as well as the sensitivity of electric-field sensors. The U.S. Army Research Laboratory (ARL) took part in multiple experiments at Aberdeen Proving Grounds (APG) to simulate a battlefield-like environment. Sensors were placed in strategic locations along the bullets' paths and recorded the electric-field signatures of charged small-arms bullets. The focus of this effort was to analyze the electric-field signatures collected during the APG experiment in order to estimate electrostatic charge on the bullets. Algorithms were written to extract electric-field bullet signatures from raw data; these signatures were further processed to estimate the miss distance, velocity and charge. The estimates of range and velocity were compared to similar estimates from acoustic signatures for verification. Ground-truth Global Positioning System (GPS) data were used to independently calculate ranges, azimuths, and miss distances. Signatures were filtered to remove clutter signals from power lines and other unwanted field sources. Closed-form equations were then fitted to the collected signatures to retrieve estimates for the magnitude of charge on the bullets. Test data, collected with sensors placed on a wall, showed enhanced E-field intensity. A Method of Moments (MoM) model of the wall was created to improve signature simulation. Detectable charges on bullets were found to exist in the 1 pC to 1 nC (10-12 - 10-9 C) range. Relationships between estimated charge, gun type, bullet caliber, noise thresholds and number

  14. Contextual determinants of condom use among female sex exchangers in East Harlem, NYC: an event analysis.

    PubMed

    McMahon, James M; Tortu, Stephanie; Pouget, Enrique R; Hamid, Rahul; Neaigus, Alan

    2006-11-01

    Recent studies have revealed a variety of contexts involving HIV risk behaviors among women who exchange sex for money or drugs. Event analysis was used to identify the individual, relationship, and contextual factors that contribute to these high-risk sex exchange practices. Analyses were conducted on data obtained from 155 drug-using women who reported details of their most recent sex exchange event with male clients. The majority of sex exchange encounters (78%) involved consistent condom use. In multivariable analysis, protective behavior was associated primarily with situational and relationship variables, such as exchange location, substance use, sexual practices, and respondent/client discussion and control. In order to inform HIV prevention programs targeted to women sex exchangers, further research is needed on the contextual determinants of risk, especially with regard to condom-use negotiation and factors involving substance use that adversely affect women's ability to manage protective behavior in the context of sex exchange.

  15. N-reactor charge-discharge system analysis

    SciTech Connect

    Tokarz, R.D.; Marr, G.D.; Nesbitt, J.F.

    1982-09-01

    This report documents an analysis of the existing systems in the N-Reactor fuel flow path. It recommends equipment improvements and changes in that path to allow the charge-discharge rates to be increased to 500 tubes per outage without increasing reactor outage time. The estimated program cost of $14 million is projected over an estimated 3-year period. It does not include costs detailed as part of the existing restoration program or any costs that are considered as normal maintenance. The recommendations contained in this report provide a direction and goal for every critical aspect of the fuel flow path. The way in which these recommendations are implemented may greatly affect the schedule and costs. Previous studies by UNC have shown that enhanced fuel element handling has the potential of increasing productivity by 33 days at a cost benefit estimated at $18 million per year. Enhanced fuel handling provides the greatest potential for productivity improvement of any of the areas considered in these studies.

  16. [Chemiluminescence spectroscopic analysis of homogeneous charge compression ignition combustion processes].

    PubMed

    Liu, Hai-feng; Yao, Ming-fa; Jin, Chao; Zhang, Peng; Li, Zhe-ming; Zheng, Zun-qing

    2010-10-01

    To study the combustion reaction kinetics of homogeneous charge compression ignition (HCCI) under different port injection strategies and intake temperature conditions, the tests were carried out on a modified single-cylinder optical engine using chemiluminescence spectroscopic analysis. The experimental conditions are keeping the fuel mass constant; fueling the n-heptane; controlling speed at 600 r x min(-1) and inlet pressure at 0.1 MPa; controlling inlet temperature at 95 degrees C and 125 degrees C, respectively. The results of chemiluminescence spectrum show that the chemiluminescence is quite faint during low temperature heat release (LTHR), and these bands spectrum originates from formaldehyde (CH2O) chemiluminescence. During the phase of later LTHR-negative temperature coefficient (NTC)-early high temperature heat release (HTHR), these bands spectrum also originates from formaldehyde (CH2O) chemiluminescence. The CO--O* continuum is strong during HTHR, and radicals such as OH, HCO, CH and CH2O appear superimposed on this CO--O* continuum. After the HTHR, the chemiluminescence intensity is quite faint. In comparison to the start of injection (SOI) of -30 degrees ATDC, the chemiluminescence intensity is higher under the SOI = -300 degrees ATDC condition due to the more intense emissions of CO--O* continuum. And more radicals of HCO and OH are formed, which also indicates a more intense combustion reaction. Similarly, more intense CO--O* continuum and more radicals of HCO and OH are emitted under higher intake temperature case.

  17. Effect of ligand exchange of Cu2ZnSnS4 nanocrystals on the charge transport and photovoltaic performance of nanostructured depleted bulk heterojunction solar cell

    NASA Astrophysics Data System (ADS)

    Zhang, Zhuo-Xi; Zhou, Zheng-Ji; Bai, Bing; Liu, Ming-Hua; Zhou, Wen-Hui; Kou, Dong-Xing; Wu, Si-Xin

    2015-12-01

    Cu2ZnSnS4 (CZTS) nanocrystals combining the advantage of feasible solution-phase synthesis and processing are perceived as promising materials for application in efficient, low-cost photovoltaic technology. Herein, we have got surfactant-free CZTS nanocrystals by a novel ligand exchange method, and the obtained CZTS nanocrystals were deposited onto ZnO nanorod arrays to construct depleted bulk heterojunction solar cell. The all-inorganic CZTS nanocrystal solar cells demonstrated a remarkable improvement in J sc (from 8.14 to 13.97 mA/cm2) and power conversion efficiency (from 1.83 to 3.34 %) compared with surfactant-capped CZTS nanocrystals. Using surface photovoltage spectrum, the influence of ligand exchange of CZTS nanocrystals on the charge transport and photovoltaic performance of the nanostructured CZTS solar cells was discussed.

  18. Charge transfer-induced magnetic exchange bias and electron localization in (111)- and (001)-oriented LaNiO3/LaMnO3 superlattices

    NASA Astrophysics Data System (ADS)

    Wei, Haoming; Barzola-Quiquia, Jose Luis; Yang, Chang; Patzig, Christian; Höche, Thomas; Esquinazi, Pablo; Grundmann, Marius; Lorenz, Michael

    2017-03-01

    High-quality lattice-matched LaNiO3/LaMnO3 superlattices with monolayer terrace structure have been grown on both (111)- and (001)-oriented SrTiO3 substrates by pulsed laser deposition. In contrast to the previously reported experiments, a magnetic exchange bias is observed that reproducibly occurs in both (111)- and (001)-oriented superlattices with the thin single layers of 5 and 7 unit cells, respectively. The exchange bias is theoretically explained by charge transfer-induced magnetic moments at Ni atoms. Furthermore, magnetization data at low temperature suggest two magnetic phases in the superlattices, with Néel temperature around 10 K. Electrical transport measurements reveal a metal-insulator transition with strong localization of electrons in the superlattices with the thin LaNiO3 layers of 4 unit cells, in which the electrical transport is dominated by two-dimensional variable range hopping.

  19. Interaction of plasma jets produced from pinch plasma with neutral atoms in order to achieve an effective charge exchange table top X-laser

    SciTech Connect

    Engel, A.; Lebert, R.; Koshelev, K. N.; Sidelnikov, Yu. V.; Churilov, S. S.; Gavrilescu, C.; Neff, W.

    1997-05-05

    Charge exchange recombination is known as an effective scheme to get population inversion in the EUV-range. Highly ionised plasma jets and a neutral target could be very efficient ({sigma}{sub CE}>10{sup -15} cm{sup 2}) to realisation of this atomic scheme. Theoretical estimates and preliminary experiments show that for plasma focus with a stored energy of several kJ one can reach a substantial population inversion for ions of light elements with charge number Z<10. Experimental studies of production of these plasma jets in a 2 kJ plasma focus device is presented. Moreover the optimal properties of possible targets are investigated. Experimental results for the interaction of the plasma jets and targets are presented.

  20. DXL: A Sounding Rocket Mission for the Study of Solar Wind Charge Exchange and Local Hot Bubble X-Ray Emission

    NASA Technical Reports Server (NTRS)

    Galeazzi, M.; Prasai, K.; Uprety, Y.; Chiao, M.; Collier, M. R.; Koutroumpa, D.; Porter, F. S.; Snowden, S.; Cravens, T.; Robertson, I.; Kuntz, K. D.; Lepri, S.; McCammon, D.

    2011-01-01

    The Diffuse X-rays from the Local galaxy (DXL) mission is an approved sounding rocket project with a first launch scheduled around December 2012. Its goal is to identify and separate the X-ray emission generated by solar wind charge exchange from that of the local hot bubble to improve our understanding of both. With 1,000 square centimeters proportional counters and grasp of about 10 square centimeters sr both in the 1/4 and 3/4 keV bands, DXL will achieve in a 5-minute flight what cannot be achieved by current and future X-ray satellites.

  1. Charge exchange in cometary coma: Discovery of H(-) ions in the solar wind close to comet 67P/Churyumov-Gerasimenko.

    PubMed

    Burch, J L; Cravens, T E; Llera, K; Goldstein, R; Mokashi, P; Tzou, C-Y; Broiles, T

    2015-07-16

    As Rosetta was orbiting comet 67P/Churyumov-Gerasimenko, the Ion and Electron Sensor detected negative particles with angular distributions like those of the concurrently measured solar wind protons but with fluxes of only about 10% of the proton fluxes and energies of about 90% of the proton energies. Using well-known cross sections and energy-loss data, it is determined that the fluxes and energies of the negative particles are consistent with the production of H(-) ions in the solar wind by double charge exchange with molecules in the coma.

  2. Measurement of Anomalously Strong Emission from the 1s-9p Transition in the Spectrum of H-like Phosphorus Following Charge Exchange with Molecular Hydrogen

    NASA Technical Reports Server (NTRS)

    Leutenegger, M. A.; Beiersdorfer, P.; Brown, G. V.; Kelley, R. L.; Porter, F. S.

    2010-01-01

    We have measured K-shell x-ray spectra of highly ionized argon and phosphorus following charge exchange with molecular hydrogen at low collision energy in an electron beam ion trap using an x-ray calorimeter array with approx.6 eV resolution. We find that the emission at the high-end of the Lyman series is greater by a factor of two for phosphorus than for argon, even though the measurement was performed concurrently and the atomic numbers are similar. This does not agree with current theoretical models and deviates from the trend observed in previous measurements.

  3. Cross section database for carbon atoms and ions: Electron-impact ionization, excitation, and charge exchange in collisions with hydrogen atoms

    SciTech Connect

    Suno, Hiroya . E-mail: suno@jamstec.go.jp; Kato, Takako

    2006-07-15

    A database has been constructed consisting of the recommended cross sections for electron-impact excitation and ionization of carbon atoms and ions C, C{sup +}-C{sup 5+}, asl as for charge exchange processes between carbon ions C{sup +}-C{sup 6+} and hydrogen atoms. We have collected a large amount of theoretical and experimental cross section data from the literature, and have critically assessed their accuracy. The recommended cross sections, the best values for use, are expressed in the form of simple analytical functions. These are also presented in graphical form.

  4. The effect of N2/+/ recombination on the aeronomic determination of the charge exchange rate coefficient of O/+//2D/ with N2

    NASA Technical Reports Server (NTRS)

    Torr, D. G.; Orsini, N.

    1978-01-01

    The Atmosphere Explorer (AE) data are reexamined in the light of new laboratory measurements of the N2(+) recombination rate coefficient alpha. The new measurements support earlier measurements which yielded values of alpha significantly lower than the AE values. It is found that the values for alpha determined from the satellite data can be reconciled with the laboratory measurements, if the charge exchange rate coefficient for O(+)(2D) with N2 is less than one-quarter of that derived in the laboratory by Rutherford and Vroom (1971).

  5. Charge exchange in cometary coma: Discovery of H− ions in the solar wind close to comet 67P/Churyumov‐Gerasimenko

    PubMed Central

    Cravens, T. E.; Llera, K.; Goldstein, R.; Mokashi, P.; Tzou, C.‐Y.; Broiles, T.

    2015-01-01

    Abstract As Rosetta was orbiting comet 67P/Churyumov‐Gerasimenko, the Ion and Electron Sensor detected negative particles with angular distributions like those of the concurrently measured solar wind protons but with fluxes of only about 10% of the proton fluxes and energies of about 90% of the proton energies. Using well‐known cross sections and energy‐loss data, it is determined that the fluxes and energies of the negative particles are consistent with the production of H− ions in the solar wind by double charge exchange with molecules in the coma. PMID:27656008

  6. Exchange factor method: An alternative basis for zonal analysis of radiating enclosures

    SciTech Connect

    Larson, M.E.; Howell, J.R.

    1985-11-01

    In zonal analysis of an enclosure containing a radiatively participating medium, the volume and bounding surface are divided into volume and area elements which are assumed to be isothermal. For a system of M elements consisting of N surfaces and GAMMA volume elements (M = N+GAMMA), M/sup 2/ relationships (direct- or total-exchange areas of conventional zonal analysis) define all possible radiant interchange between element pairs. Due to reciprocity there are at most M(M+1)/2 unique direct-exchange areas. The use of symmetry may greatly reduce the number of unique exchange areas. In the alternative form presented, exchange factors are defined such that a gray medium's gas-to-gas exchange factors describe only the redistribution of radiative source terms. Only surface-to-surface and surface-to-gas (gas-to-surface) relationships are required to wholly define the system in radiative equilibrium. That is, a system in radiative equilibrium may be characterized by as many as GAMMA(GAMMA+1)/2 fewer factors. These same exchange factors may be augmented by gas-to-gas exchange factors to analyze media not in radiative equilibrium. In an isotropically scattering, gray medium, exchange factors are functions of system geometry and total extinction only. The degree of extinction due to scattering does not affect exchange factor. Transformations between direct-exchange areas and exchange factors are developed.

  7. Modeling Philippine Stock Exchange Composite Index Using Time Series Analysis

    NASA Astrophysics Data System (ADS)

    Gayo, W. S.; Urrutia, J. D.; Temple, J. M. F.; Sandoval, J. R. D.; Sanglay, J. E. A.

    2015-06-01

    This study was conducted to develop a time series model of the Philippine Stock Exchange Composite Index and its volatility using the finite mixture of ARIMA model with conditional variance equations such as ARCH, GARCH, EG ARCH, TARCH and PARCH models. Also, the study aimed to find out the reason behind the behaviorof PSEi, that is, which of the economic variables - Consumer Price Index, crude oil price, foreign exchange rate, gold price, interest rate, money supply, price-earnings ratio, Producers’ Price Index and terms of trade - can be used in projecting future values of PSEi and this was examined using Granger Causality Test. The findings showed that the best time series model for Philippine Stock Exchange Composite index is ARIMA(1,1,5) - ARCH(1). Also, Consumer Price Index, crude oil price and foreign exchange rate are factors concluded to Granger cause Philippine Stock Exchange Composite Index.

  8. Molecular orbital (SCF-X-α-SW) theory of Fe2+-Mn3+, Fe3+-Mn2+, and Fe3+-Mn3+ charge transfer and magnetic exchange in oxides and silicates

    USGS Publications Warehouse

    Sherman, David M.

    1990-01-01

    Metal-metal charge-transfer and magnetic exchange interactions have important effects on the optical spectra, crystal chemistry, and physics of minerals. Previous molecular orbital calculations have provided insight on the nature of Fe2+-Fe3+ and Fe2+-Ti4+ charge-transfer transitions in oxides and silicates. In this work, spin-unrestricted molecular orbital calculations on (FeMnO10) clusters are used to study the nature of magnetic exchange and electron delocalization (charge transfer) associated with Fe3+-Mn2+, Fe3+-Mn3+, and Fe2+-Mn3+ interactions in oxides and silicates. 

  9. Electrostatic analysis of charge-coupled structures. [numerical analysis of electrostatics for shift registers

    NASA Technical Reports Server (NTRS)

    Gassaway, J. D.

    1976-01-01

    An analysis is presented which is based upon a numerical solution of Gauss's law for the multiple dielectric semiconductor and electrode structure. The formulation resulted in a large set of equations, usually nonlinear, which were solved by an iterative scheme based upon the Gauss-Seidel method employing a relaxation parameter. Proper consideration of the nonlinearity of the space-charge in the semiconductor allowed convergent solutions which can give reasonable approximations to the channel potential profiles though not as good for estimating the space charge itself. The results of this work, which are three computer programs, are listed. None of the programs give the electric field explicitly as output data. However, when this information is desired, the programs can be expanded to include field estimations based on a polynominal fit to the potential field, or they may serve as subprograms for main programs dealing with general aspects of charge transfer.

  10. A Spacebased Ocean Surface Exchange Data Analysis System

    NASA Technical Reports Server (NTRS)

    Tang, Wenqing; Liu, W. Timothy

    2000-01-01

    Emerging technologies have provided unprecedented opportunities to transform information into knowledge and disseminate them in a much faster, cheaper, and userfriendly mode. We have set up a system to produce and disseminate high level (gridded) ocean surface wind data from the NASA Scatterometer and European Remote Sensing missions. The data system is being expanded to produce real-time gridded ocean surface winds from an improved sensor SeaWinds on the Quikscat Mission. The wind field will be combined with hydrologic parameters from the Tropical Rain Measuring Mission to monitor evolving weather systems and natural hazard in real time. It will form the basis for spacebased Ocean Surface Exchange Data Analysis System (SOSEDAS) which will include the production of ocean surface momentum, heat, and water fluxes needed for interdisciplinary studies of ocean-atmosphere interaction. Various commercial or non-commercial software tools have been compared and selected in terms of their ability in database management, remote data accessing, graphical interface, data quality, storage needs and transfer speed, etc. Issues regarding system security and user authentication, distributed data archiving and accessing, strategy to compress large-volume geophysical and satellite data/image. and increasing transferring speed are being addressed. A simple and easy way to access information and derive knowledge from spacebased data of multiple missions is being provided. The evolving 'knowledge system' will provide relevant infrastructure to address Earth System Science, make inroads in educating an informed populace, and illuminate decision and policy making.

  11. Measurement of absolute charge-exchange cross sections for He{sup 2+} collisions with He and H{sub 2}

    SciTech Connect

    Mawhorter, R. J.; Greenwood, J. B.; Chutjian, A.; Simcic, J.; Haley, T.; Mitescu, C. D.

    2011-11-15

    Reported are total, absolute charge-exchange cross sections for collisions of {sup 3}He{sup 2+} ions with He and H{sub 2}. Measurements are reported at fixed energies between 0.33 and 4.67 keV/amu. Both the present results and earlier results of others are analyzed in terms of available experimental small-angle differential cross sections as a function of collision energy, and hence the geometry of the exit aperture of the gas-collision cells used by the various experimental groups. In addition, the effective length of gas-collision cells is studied using fluid dynamic and molecular flow simulations to address the density patterns near the cell entrance and exit apertures. When small acceptance-angle corrections were applied, the results of present and previous measurements for the single electron capture in these systems were brought into good accord in the relevant energy ranges. Taken in their entirety, the present data for {sup 3}He{sup 2+} with He and H{sub 2} lend themselves to new theoretical calculations of the multichannel charge-exchange cross sections.

  12. Heterodimers formed through a partial anionic exchange process: scanning tunneling spectroscopy to monitor bands across the junction vis-à-vis photoinduced charge separation.

    PubMed

    Bera, Abhijit; Saha, Sudip K; Pal, Amlan J

    2015-11-07

    We report controlled formation of heterodimers and their charge separation properties. CdS|CdTe heterodimers were formed through an anionic exchange process of CdS nanostructures. With control over the duration of the anionic exchange process, bulk|dot, bulk|bulk, and then dot|bulk phases of the semiconductors could be observed to have formed. A mapping of density of states as derived from scanning tunneling spectroscopy (STS) brought out conduction and valence band-edges along the nanostructures and heterodimers. The CdS|CdTe heterodimers evidenced a type-II band-alignment between the semiconductors along with the formation of a depletion region at the interface. The width (of the depletion region) and the energy-offset at the interface depended on the size of the semiconductors. We report that the width that is instrumental for photoinduced charge separation in the heterodimers has a direct correlation with the performance of hybrid bulk-heterojunction solar cells based on the nanostructures in a polymer matrix.

  13. Radiochemical study of the medium energy pion double charge exchange reactions: /sup 209/Bi(pi/sup +/pi/sup -/)/sup 209-x/At

    SciTech Connect

    Clark, J.L.

    1980-01-01

    Carrier-free radiochemical techniques have been used to measure cross sections for the double charge exchange reactions of the type /sup 209/Bi(pi/sup +/, pi/sup -/xn)/sup 209-x/At for 100, 180, and 300 MeV incident pions. The observed formation of astatine products with mass numbers ranging from 208 to 205 is interpreted as evidence of processes in which energy deposited in the initial double charge exchange interaction is subsequently dissipated through neutron evaporation. The excitation functions for these reactions are seen to rise rapidly with decreasing incident pion energy with the maximum results for this study at 100 MeV. The astatine production cross secions measured for these positive pion irradiations of thick bismuth targets must be corrected for secondary processes, particularly the pion induced production of fast alpha particles which can contribute to the total cross sections through reactions like /sup 209/Bi(alpha,xn)/sup 213-x/At. The importance of these secondary contributions was studied through a series of negative pion irradiations of bismuth in which secondary pathways furnish the only means of producing astatine. The failure of evaporation calculations to reproduce the astatine product mass yields observed in these secondary studies suggests that direct mechanisms for energetic complex particle formation are quite important. Values for the alpha decay branches of /sup 207/At, /sup 208/At, and /sup 209/At were determined through a study of the electron capture and alpha decay characteristics of chemically purified astatine fractions.

  14. Design and operation of the pellet charge exchange diagnostic for measurement of energetic confined α particles and tritons on the Tokamak Fusion Test Reactor

    NASA Astrophysics Data System (ADS)

    Medley, S. S.; Mansfield, D. K.; Roquemore, A. L.; Fisher, R. K.; Duong, H. H.; McChesney, J. M.; Parks, P. B.; Petrov, M. P.; Khudoleev, A. V.; Gorelenkov, N. N.

    1996-09-01

    Radially resolved energy and density distributions of the confined α particles in D-T experiments on the Tokamak Fusion Test Reactor (TFTR) are being measured with the pellet charge exchange (PCX) diagnostic. Other energetic ion species can be detected as well, such as tritons produced in D-D plasmas and H, He3, or tritium rf-driven minority ion tails. The ablation cloud formed by injected low-Z impurity pellets provides the neutralization target for this active charge exchange technique. Because the cloud neutralization efficiency is uncertain, the PCX diagnostic is not absolutely calibrated so only relative density profiles are obtained. A mass and energy resolving E∥B neutral particle analyzer (NPA) is used which has eight energy channels covering the energy range of 0.3-3.7 MeV for α particles with energy resolution ranging from 5.8% to 11.3% and a spatial resolution of ˜5 cm. The PCX diagnostic views deeply trapped ions in a narrow pitch angle range around a mean value of v∥/v=-0.048±10-3. For D-T operation, the NPA was shielded by a polyethylene-lead enclosure providing 100× attenuation of ambient γ radiation and 14 MeV neutrons. The PCX diagnostic technique and its application on TFTR are described in detail.

  15. Two-phase/two-phase heat exchanger analysis

    NASA Technical Reports Server (NTRS)

    Kim, Rhyn H.

    1992-01-01

    A capillary pumped loop (CPL) system with a condenser linked to a double two-phase heat exchanger is analyzed numerically to simulate the performance of the system from different starting conditions to a steady state condition based on a simplified model. Results of the investigation are compared with those of similar apparatus available in the Space Station applications of the CPL system with a double two-phase heat exchanger.

  16. An Analysis of Charged Anisotropic Star with de Sitter Spacetime

    NASA Astrophysics Data System (ADS)

    Das, Kanika; Ali, Nawsad

    2016-02-01

    We propose a model for charged anisotropic star in de Sitter spacetime. We have taken Krori and Barua (J. Phys. A, Math. Gen. 8, 508, 1975) metric in de Sitter spacetime with non-zero cosmological constant. The model is free from singularity. We incorporate the existence of the cosmological constant on a small scale to study the structure of anisotropic charged star. To solve the Einstein-Maxwell field equations we assume the relation between the radial and transverse pressure as p t - p r = g q( r)2 r 2 (where g is a non-zero positive constant). The physical conditions inside the stellar model are also discussed.

  17. Exchange bias effect in Au-Fe3O4 dumbbell nanoparticles induced by the charge transfer from gold

    SciTech Connect

    Feygenson, Mikhail; Bauer, John C; Gai, Zheng; Marques, Carlos; Aronson, Meigan C.; Teng, Xiaowei; Su, Dong; Stanic, Vesna; Urban, Volker S; Kevin, Beyer; Dai, Sheng

    2015-08-10

    We have studied the origin of the exchange bias effect in the Au-Fe3O4 dumbbell nanoparticles in two samples with different sizes of the Au seed nanoparticles (4.1 and 2.7 nm) and same size of Fe3O4 nanoparticles (9.8 nm). The magnetization, small-angle neutron scattering, synchrotron x-ray diffraction and scanning transmission electron microscope measurements determined the antiferromagnetic FeO wüstite phase within Fe3O4 nanoparticles, originating at the interface with the Au nanoparticles. The interface between antiferromagnetic FeO and ferrimagnetic Fe3O4 is giving rise to the exchange bias effect. The strength of the exchange bias fields depends on the interfacial area and lattice mismatch between both phases. We propose that the charge transfer from the Au nanoparticles is responsible for a partial reduction of the Fe3O4 into FeO phase at the interface with Au nanoparticles. The Au-O bonds are formed across the interface to accommodate an excess of oxygen released during the reduction of magnetite.

  18. Mass transfer of single- and double-charged anions through an MA-41L anion-exchange membrane

    SciTech Connect

    Kulikova, O.M.; Sharkova, O.V.; Kulikov, S.M.

    1995-02-20

    Selective anion transfer through an MA-41L anion-exchange membrane in the Cl{sup -}-F{sup -}, Cl{sup -}-SO{sub 4}{sup 2-}, F{sup -}-SO{sub 4}{sup 2-}, and F{sup -}-CO{sub 3}{sup 2-} systems has been studied. The feasibility of partial anion separation in the chloride-sulfate system has been demonstrated. The separation of fluoride ions from accompanying anions was found to be practically impossible.

  19. Analysis of high-resolution foreign exchange data of USD-JPY for 13 years

    NASA Astrophysics Data System (ADS)

    Mizuno, Takayuki; Kurihara, Shoko; Takayasu, Misako; Takayasu, Hideki

    2003-06-01

    We analyze high-resolution foreign exchange data consisting of 20 million data points of USD-JPY for 13 years to report firm statistical laws in distributions and correlations of exchange rate fluctuations. A conditional probability density analysis clearly shows the existence of trend-following movements at time scale of 8-ticks, about 1 min.

  20. Analysis of Electric Vehicle Charging Impact on the Electric Power Grid

    SciTech Connect

    Jiang, Zeming; Tian, Hao; Beshir, Mohammed J.; Vohra, Surendra; Mazloomzadeh, Ali

    2016-09-24

    In order to evaluate the impact of electric vehicles (EVs) on the distribution grid and assess their potential benefits to the future smart grid, it is crucial to study the EV charging patterns and the usage charging station. Though EVs are not yet widely adopted nationwide, a valuable methodology to conduct such studies is the statistical analysis of real-world charging data. This paper presents actual EV charging behavior of 64 EVs (5 brands, 8 models) from EV users and charging stations at Los Angeles Department of Water and Power for more than one year. Twenty-four-hour EV charging load curves have been generated and studied for various load periods: daily, monthly, seasonally and yearly. Finally, the effect and impact of EV load on the California distribution network are evaluated at different EV penetration rates.

  1. Quantum Monte Carlo analysis of a charge ordered insulating antiferromagnet: The Ti4O7 Magneli phase

    DOE PAGES

    Benali, Anouar; Shulenburger, Luke; Krogel, Jaron T.; ...

    2016-06-07

    The Magneli phase Ti4O7 is an important transition metal oxide with a wide range of applications because of its interplay between charge, spin, and lattice degrees of freedom. At low temperatures, it has non-trivial magnetic states very close in energy, driven by electronic exchange and correlation interactions. We have examined three low- lying states, one ferromagnetic and two antiferromagnetic, and calculated their energies as well as Ti spin moment distributions using highly accurate Quantum Monte Carlo methods. We compare our results to those obtained from density functional theory- based methods that include approximate corrections for exchange and correlation. Our resultsmore » confirm the nature of the states and their ordering in energy, as compared with density-functional theory methods. However, the energy differences and spin distributions differ. Here, a detailed analysis suggests that non-local exchange-correlation functionals, in addition to other approximations such as LDA+U to account for correlations, are needed to simultaneously obtain better estimates for spin moments, distributions, energy differences and energy gaps.« less

  2. A multifractal analysis of Asian foreign exchange markets

    NASA Astrophysics Data System (ADS)

    Oh, G.; Eom, C.; Havlin, S.; Jung, W.-S.; Wang, F.; Stanley, H. E.; Kim, S.

    2012-06-01

    We analyze the multifractal spectra of daily foreign exchange rates for Japan, Hong-Kong, Korea, and Thailand with respect to the United States in the period from 1991 until 2005. We find that the return time series show multifractal spectrum features for all four cases. To observe the effect of the Asian currency crisis, we also estimate the multifractal spectra of limited series before and after the crisis. We find that the Korean and Thai foreign exchange markets experienced a significant increase in multifractality compared to Hong-Kong and Japan. We also show that the multifractality is stronger related to the presence of high values of returns in the series.

  3. Multifractal Analysis of Asian Foreign Exchange Markets and Financial Crisis

    NASA Astrophysics Data System (ADS)

    Oh, Gabjin; Kwon, Okyu; Jung, Woo-Sung

    2012-02-01

    We analyze the multifractal spectra of daily foreign exchange rates for Japan, Hong-Kong, Korea, and Thailand with respect to the United States Dollar from 1991 to 2005. We find that the return time series show multifractal spectrum features for all four cases. To observe the effect of the Asian currency crisis, we also estimate the multifractal spectra of limited series before and after the crisis. We find that the Korean and Thai foreign exchange markets experienced a significant increase in multifractality compared to Hong-Kong and Japan. We also show that the multifractality is stronge related to the presence of high values of returns in the series.

  4. Dimensional Analysis of Ocean Thermal Energy Conversion Heat Exchangers

    DTIC Science & Technology

    1977-06-30

    8217thIJt4IiTY CLASSIFICATION OF TWI4S PAG(E ona Dola t ern.r) 20. (continued) c-a• of factors having significance in OTEC (Ocean Thermal Energy Conversion...heat exchangers. Certain of these groups are then evaluated for a model and prototype OTEC -Type heat exchanger using the same working fluid and ex...Development Administration, and the U. S. Navy are brought out. Chapter II investigates the scaling problems of heat ex- changers in OTEC (Ocean Thermal

  5. Analysis of Lunar Surface Charging for a Candidate Spacecraft Using NASCAP-2K

    NASA Technical Reports Server (NTRS)

    Parker, Linda; Minow, Joseph; Blackwell, William, Jr.

    2007-01-01

    The characterization of the electromagnetic interaction for a spacecraft in the lunar environment, and identification of viable charging mitigation strategies, is a critical lunar mission design task, as spacecraft charging has important implications both for science applications and for astronaut safety. To that end, we have performed surface charging calculations of a candidate lunar spacecraft for lunar orbiting and lunar landing missions. We construct a model of the spacecraft with candidate materials having appropriate electrical properties using Object Toolkit and perform the spacecraft charging analysis using Nascap-2k, the NASA/AFRL sponsored spacecraft charging analysis tool. We use nominal and atypical lunar environments appropriate for lunar orbiting and lunar landing missions to establish current collection of lunar ions and electrons. In addition, we include a geostationary orbit case to demonstrate a bounding example of extreme (negative) charging of a lunar spacecraft in the geostationary orbit environment. Results from the charging analysis demonstrate that minimal differential potentials (and resulting threat of electrostatic discharge) occur when the spacecraft is constructed entirely of conducting materials, as expected. We compare charging results to data taken during previous lunar orbiting or lunar flyby spacecraft missions.

  6. Analysis of charge transfer effects in molecular complexes based on absolutely localized molecular orbitals

    SciTech Connect

    Khaliullin, Rustam Z.; Head-Gordon, Martin; Bell, Alexis T.

    2008-05-14

    A new method based on absolutely localized molecular orbitals (ALMOs) is proposed to measure the degree of intermolecular electron density delocalization (charge transfer) in molecular complexes. ALMO charge transfer analysis (CTA) enables separation of the forward and backward charge transfer components for each pair of molecules in the system. The key feature of ALMO CTA is that all charge transfer terms have corresponding well defined energetic effects that measure the contribution of the given term to the overall energetic stabilization of the system. To simplify analysis of charge transfer effects, the concept of chemically significant complementary occupied-virtual orbital pairs (COVPs) is introduced. COVPs provide a simple description of intermolecular electron transfer effects in terms of just a few localized orbitals. ALMO CTA is applied to understand fundamental aspects of donor-acceptor interactions in borane adducts, synergic bonding in classical and nonclassical metal carbonyls, and multiple intermolecular hydrogen bonds in a complex of isocyanuric acid and melamine. These examples show that the ALMO CTA results are generally consistent with the existing conceptual description of intermolecular bonding. The results also show that charge transfer and the energy lowering due to charge transfer are not proportional to each other, and some interesting differences emerge which are discussed. Additionally, according to ALMO CTA, the amount of electron density transferred between molecules is significantly smaller than charge transfer estimated from various population analysis methods.

  7. Analysis of charge transfer effects in molecular complexes based on absolutely localized molecular orbitals.

    PubMed

    Khaliullin, Rustam Z; Bell, Alexis T; Head-Gordon, Martin

    2008-05-14

    A new method based on absolutely localized molecular orbitals (ALMOs) is proposed to measure the degree of intermolecular electron density delocalization (charge transfer) in molecular complexes. ALMO charge transfer analysis (CTA) enables separation of the forward and backward charge transfer components for each pair of molecules in the system. The key feature of ALMO CTA is that all charge transfer terms have corresponding well defined energetic effects that measure the contribution of the given term to the overall energetic stabilization of the system. To simplify analysis of charge transfer effects, the concept of chemically significant complementary occupied-virtual orbital pairs (COVPs) is introduced. COVPs provide a simple description of intermolecular electron transfer effects in terms of just a few localized orbitals. ALMO CTA is applied to understand fundamental aspects of donor-acceptor interactions in borane adducts, synergic bonding in classical and nonclassical metal carbonyls, and multiple intermolecular hydrogen bonds in a complex of isocyanuric acid and melamine. These examples show that the ALMO CTA results are generally consistent with the existing conceptual description of intermolecular bonding. The results also show that charge transfer and the energy lowering due to charge transfer are not proportional to each other, and some interesting differences emerge which are discussed. Additionally, according to ALMO CTA, the amount of electron density transferred between molecules is significantly smaller than charge transfer estimated from various population analysis methods.

  8. Analysis of charge transfer effects in molecular complexes based on absolutely localized molecular orbitals

    NASA Astrophysics Data System (ADS)

    Khaliullin, Rustam Z.; Bell, Alexis T.; Head-Gordon, Martin

    2008-05-01

    A new method based on absolutely localized molecular orbitals (ALMOs) is proposed to measure the degree of intermolecular electron density delocalization (charge transfer) in molecular complexes. ALMO charge transfer analysis (CTA) enables separation of the forward and backward charge transfer components for each pair of molecules in the system. The key feature of ALMO CTA is that all charge transfer terms have corresponding well defined energetic effects that measure the contribution of the given term to the overall energetic stabilization of the system. To simplify analysis of charge transfer effects, the concept of chemically significant complementary occupied-virtual orbital pairs (COVPs) is introduced. COVPs provide a simple description of intermolecular electron transfer effects in terms of just a few localized orbitals. ALMO CTA is applied to understand fundamental aspects of donor-acceptor interactions in borane adducts, synergic bonding in classical and nonclassical metal carbonyls, and multiple intermolecular hydrogen bonds in a complex of isocyanuric acid and melamine. These examples show that the ALMO CTA results are generally consistent with the existing conceptual description of intermolecular bonding. The results also show that charge transfer and the energy lowering due to charge transfer are not proportional to each other, and some interesting differences emerge which are discussed. Additionally, according to ALMO CTA, the amount of electron density transferred between molecules is significantly smaller than charge transfer estimated from various population analysis methods.

  9. Analysis of ``soft`` recovered shaped charge jet particles

    SciTech Connect

    Lassila, D.H.; Nikkel, D.J. Jr.; Kershaw, R.P.; Walters, W.P.

    1996-04-01

    A shaped charge with an 81 mm diameter, 42{degree} apex angle oxygen-free high-conductivity (OFHC) copper conical liner was fired into a ``soft`` recovery bunker to allow metallurgical examination of recovered jet particles and the slug. The initial weight of the copper liner was 245 g, of which 184 g was recovered. The number of jet particles recovered was 37 (approximately 63% of the particles formed by the charge). Extensive metallurgical analyses were performed on the recovered slug and jet particles. The microstructural features associated with voids, e.g., dendritic grain growth, clearly indicate that the regions in the vicinity of the centerline of the slug and jet particles were melted. In this work the authors present calculations of jet temperature as a function of constitutive behavior. In order to predict melt in the center region of the jet they find it necessary to scale flow stress with a pressure dependent shear modulus.

  10. Child Language Data Exchange System Tools for Clinical Analysis.

    PubMed

    MacWhinney, Brian; Fromm, Davida

    2016-05-01

    The Child Language Data Exchange System Project has developed methods for analyzing many aspects of child language development, including grammar, lexicon, discourse, gesture, phonology, and fluency. This article will describe the methods available for each of these six fields, and how they can be used for assessment in the clinical setting.

  11. Thermal Analysis for Ion-Exchange Column System

    SciTech Connect

    Lee, Si Y.; King, William D.

    2012-12-20

    Models have been developed to simulate the thermal characteristics of crystalline silicotitanate ion exchange media fully loaded with radioactive cesium either in a column configuration or distributed within a waste storage tank. This work was conducted to support the design and operation of a waste treatment process focused on treating dissolved, high-sodium salt waste solutions for the removal of specific radionuclides. The ion exchange column will be installed inside a high level waste storage tank at the Savannah River Site. After cesium loading, the ion exchange media may be transferred to the waste tank floor for interim storage. Models were used to predict temperature profiles in these areas of the system where the cesium-loaded media is expected to lead to localized regions of elevated temperature due to radiolytic decay. Normal operating conditions and accident scenarios (including loss of solution flow, inadvertent drainage, and loss of active cooling) were evaluated for the ion exchange column using bounding conditions to establish the design safety basis. The modeling results demonstrate that the baseline design using one central and four outer cooling tubes provides a highly efficient cooling mechanism for reducing the maximum column temperature. In-tank modeling results revealed that an idealized hemispherical mound shape leads to the highest tank floor temperatures. In contrast, even large volumes of CST distributed in a flat layer with a cylindrical shape do not result in significant floor heating.

  12. O₂(X³Σg⁻) and O₂(a¹Δg) charge exchange with simple ions.

    PubMed

    Ziółkowski, Marcin; Schatz, George C; Viggiano, A A; Midey, Anthony; Dotan, Itzhak

    2014-06-07

    We present theory and experiments which describe charge transfer from the X³Σg⁻ and a(1)Δg states of molecular oxygen and atomic and molecular cations. Included in this work are new experimental results for O2(a(1)Δg) and the cations O(+), CO(+), Ar(+), and N₂⁺, and new theory based on complete active space self-consistent field method calculations and an extended Langevin model to calculate rate constants for ground and excited O2 reacting with the atomic ions Ar(+), Kr(+), Xe(+), Cl(+), and Br(+). The T-shaped orientation of the (X - O2)(+) potential surface is used for the calculations, including all the low lying states up to the second singlet state of the oxygen molecule b¹Σ(g)⁺. The calculated rate constants for both O₂(X³Σg⁻) and O2(a(1)Δg) show consistent trends with the experimental results, with a significant dependence of rate constant on charge transfer exothermicity that does not depend strongly on the nature of the cation. The comparisons with theory show that partners with exothermicities of about 1 eV have stronger interactions with O2, leading to larger Langevin radii, and also that more of the electronic states are attractive rather than repulsive, leading to larger rate constants. Rate constants for charge transfer involving O2(a(1)Δg) are similar to those for O₂(X³Σg⁻) for a given exothermicity ignoring the electronic excitation of the O2(a(1)Δg) state. This means (and the electronic structure calculations support) that the ground and excited states of O2 have about the same attractive interactions with ions.

  13. Measurement of deuterium density profiles in the H-mode steep gradient region using charge exchange recombination spectroscopy on DIII-D

    SciTech Connect

    Haskey, S. R.; Grierson, B. A.; Burrell, K. H.; Chrystal, C.; Groebner, R. J.; Kaplan, D. H.; Pablant, N. A.; Stagner, L.

    2016-09-26

    Recent completion of a thirty two channel main-ion (deuterium) charge exchange recombination spectroscopy (CER) diagnostic on the DIII-D tokamak enables detailed comparisons between impurity and main-ion temperature, density, and toroidal rotation. In a H-mode DIII-D discharge, these new measurement capabilities are used to provide the deuterium density profile, demonstrate the importance of profile alignment between Thomson scattering and CER diagnostics, and aid in determining the electron temperature at the separatrix. Sixteen sightlines cover the core of the plasma and another sixteen are densely packed towards the plasma edge, providing high resolution measurements across the pedestal and steep gradient region in H-mode plasmas. Extracting useful physical quantities such as deuterium density is challenging due to multiple photoemission processes. Finally, these challenges are overcome using a detailed fitting model and by forward modeling the photoemission using the FIDASIM code, which implements a comprehensive collisional radiative model. Published by AIP Publishing.

  14. Expressions for Form Factors for Inelastic Scattering and Charge Exchange in Plane-Wave, Distorted-Wave, and Coupled-Channels Reaction Formalisms

    SciTech Connect

    Dietrich, F S

    2006-09-25

    This document is intended to facilitate calculation of inelastic scattering and charge-exchange cross sections in a variety of reaction models, including the plane-wave and distorted-wave approximations and the full coupled-channels treatments. Expressions are given for the coupling potentials between the relevant channels in both coordinate and momentum space. In particular, it is expected that the plane-wave calculations should be useful as a check on the correctness of coupled-channels calculations. The Fourier transform methods used to calculate the plane-wave approximation cross sections are also intended to be used to generate the transition potentials for coupled-channels codes, using a folding model with local effective interactions. Specific expressions are given for calculating transition densities for the folding model in the random phase approximation (RPA).

  15. Measurement of deuterium density profiles in the H-mode steep gradient region using charge exchange recombination spectroscopy on DIII-D

    NASA Astrophysics Data System (ADS)

    Haskey, S. R.; Grierson, B. A.; Burrell, K. H.; Chrystal, C.; Groebner, R. J.; Kaplan, D. H.; Pablant, N. A.; Stagner, L.

    2016-11-01

    Recent completion of a thirty two channel main-ion (deuterium) charge exchange recombination spectroscopy (CER) diagnostic on the DIII-D tokamak [J. L. Luxon, Nucl. Fusion 42, 614 (2002)] enables detailed comparisons between impurity and main-ion temperature, density, and toroidal rotation. In a H-mode DIII-D discharge, these new measurement capabilities are used to provide the deuterium density profile, demonstrate the importance of profile alignment between Thomson scattering and CER diagnostics, and aid in determining the electron temperature at the separatrix. Sixteen sightlines cover the core of the plasma and another sixteen are densely packed towards the plasma edge, providing high resolution measurements across the pedestal and steep gradient region in H-mode plasmas. Extracting useful physical quantities such as deuterium density is challenging due to multiple photoemission processes. These challenges are overcome using a detailed fitting model and by forward modeling the photoemission using the FIDASIM code, which implements a comprehensive collisional radiative model.

  16. Analysis of Surface Charging for a Candidate Solar Sail Mission Using Nascap-2k

    NASA Technical Reports Server (NTRS)

    Parker, Linda Neergaard; Minow, Joseph I.; Davis, Victoria; Mandell, Myron; Gardner, Barbara

    2005-01-01

    The characterization of the electromagnetic interaction for a solar sail in the solar wind environment and identification of viable charging mitigation strategies are critical solar sail mission design task. Spacecraft charging has important implications both for science applications and for lifetime and reliability issues of sail propulsion systems. To that end, surface charging calculations of a candidate 150-meter-class solar sail spacecraft for the 0.5 AU solar polar and 1.0 AU L1 solar wind environments are performed. A model of the spacecraft with candidate materials having appropriate electrical properties is constructed using Object Toolkit. The spacecraft charging analysis is performed using Nascap-2k, the NASA/AFRL sponsored spacecraft charging analysis tool. Nominal and atypical solar wind environments appropriate for the 0.5 AU and 1.0 AU missions are used to establish current collection of solar wind ions and electrons. Finally, a geostationary orbit environment case is included to demonstrate a bounding example of extreme (negative) charging of a solar sail spacecraft. Results from the charging analyses demonstrate that minimal differential potentials (and resulting threat of electrostatic discharge) occur when the spacecraft is constructed entirely of conducting materials, as anticipated from standard guidelines for mitigation of spacecraft charging issues. Examples with dielectric materials exposed to the space environment exhibit differential potentials ranging from a few volts to extreme potentials in the kilovolt range.

  17. Analysis of Surface Charging for a Candidate Solar Sail Mission Using NASCAP-2K

    NASA Technical Reports Server (NTRS)

    Parker, Linda Neergaard; Minow, Joseph L.; Davis, V. A.; Mandell, Myron; Gardner, Barbara

    2005-01-01

    The characterization of the electromagnetic interaction for a solar sail in the solar wind environment and identification of viable charging mitigation strategies are critical solar sail mission design tasks. Spacecraft charging has important implications both for science applications and for lifetime and reliability issues of sail propulsion systems. To that end, surface charging calculations of a candidate 150-meter-class solar sail spacecraft for the 0.5 AU solar polar and 1.9 AU LI solar wind environments are performed. A model of the spacecraft with candidate materials having appropriate electrical properties is constructed using Object Toolkit. The spacecraft charging analysis is performed using Nascap-2k. the NASA/AFRL sponsored spacecraft charging analysis tool. Nominal and atypical solar wind environments appropriate for the 0.5 AU and 1.0 AU missions are used to establish current collection of solar wind ions and electrons. Finally, a geostationary orbit environment case is included to demonstrate a bounding example of extreme (negative) charging of a solar sail spacecraft. Results from the charging analyses demonstrate that minimal differential potentials (and resulting threat of electrostatic discharge) occur when the spacecraft is constructed entirely of conducting materials, as anticipated from standard guidelines for mitigation of spacecraft charging issues. Examples with dielectric materials exposed to the space environment exhibit differential potentials ranging from a few volts to extreme potentials in the kilovolt range.

  18. Low energy charge exchange cross sections between sodium and H/sup +/, H/sup +//sub 2/, H/sup +//sub 3/, N/sup +//sub 2/, H/sub 2/O/sup +/, and O/sup +//sub 2/

    SciTech Connect

    Loch, R.; Stengler, R.; Werth, G.

    1989-08-15

    We confined ions of different molecules in a Penning quadrupole ion trap and observed the exponential loss of the stored ion cloud as the result of charge exchange collisions with a Na atomic beam passing through the trap. From the ion loss rates and the Na density we determined the charge exchange cross sections between Na and the ions noted in the title at a mean ion energy of 2 eV. The results are in reasonable agreement with theoretical expectations and other experiments.

  19. Entropy analysis in foreign exchange markets and economic crisis

    NASA Astrophysics Data System (ADS)

    Ha, Jin-Gi; Yim, Kyubin; Kim, Seunghwan; Jung, Woo-Sung

    2012-08-01

    We investigate the relative market efficiency in 11 foreign exchange markets by using the Lempel-Ziv (LZ) complexity algorithm and several entropy values such as the Shannon entropy, the approximate entropy, and the sample entropy. With daily data in 11 foreign exchange markets from Jan. 2000 to Sep. 2011, we observe that mature markets have higher LZ complexities and entropy values than emerging markets. Furthermore, with sliding time windows, we also investigate the temporal evolutions of those entropies from Jan. 1994 to Sep. 2011, and we find that, after an economic crisis, the approximate entropy and the sample entropy of mature markets such as Japan, Europe and the United Kingdom suddenly become lower.

  20. Ion-exchange controls the kinetics of deswelling of polyelectrolyte microgels in solutions of oppositely charged surfactant.

    PubMed

    Nilsson, Peter; Hansson, Per

    2005-12-22

    The kinetics of deswelling of sodium polyacrylate microgels (radius 30-140 microm) in aqueous solutions of dodecyltrimethylammonium bromide is investigated by means of micropipet-assisted light microscopy. The purpose of the study is to test a recent model (J. Phys. Chem. B 2003, 107, 9203) proposing that the rate of the volume change is controlled by the transport of surfactant from the solution to the gel core (ion exchange) via the surfactant-rich surface phase appearing in the gel during the volume transition. Equilibrium swelling characteristics of the gel network in surfactant-free solutions and with various amounts of surfactant present are presented and discussed with reference to related systems. A relationship between gel volume and degree of surfactant binding is determined and used in theoretical predictions of the deswelling kinetics. Experimental data for single gel beads observed during deswelling under conditions of forced convection are presented and compared with model calculations. It is demonstrated that the dependences of the kinetics on initial gel size, the surfactant concentration in the solution, and the liquid flow rate are well accounted for by the model. It is concluded that the deswelling rates of the studied gels are strongly influenced by the mass transport of surfactant between gel and solution (stagnant layer diffusion), but only to a minor extent by the transport through the surface phase. The results indicate that, during the volume transition, swelling equilibrium (network relaxation/transport of water) is established on a relatively short time scale and, therefore, can be treated as independent of the ion-exchange kinetics. Theoretical aspects of the kinetics and mechanisms of surfactant transport through the surface phase are discussed.

  1. Performance analysis of a medical record exchanges model.

    PubMed

    Huang, Ean-Wen; Liou, Der-Ming

    2007-03-01

    Electronic medical record exchange among hospitals can provide more information for physician diagnosis and reduce costs from duplicate examinations. In this paper, we proposed and implemented a medical record exchange model. According to our study, exchange interface servers (EISs) are designed for hospitals to manage the information communication through the intra and interhospital networks linked with a medical records database. An index service center can be given responsibility for managing the EIS and publishing the addresses and public keys. The prototype system has been implemented to generate, parse, and transfer the health level seven query messages. Moreover, the system can encrypt and decrypt a message using the public-key encryption algorithm. The queuing theory is applied to evaluate the performance of our proposed model. We estimated the service time for each queue of the CPU, database, and network, and measured the response time and possible bottlenecks of the model. The capacity of the model is estimated to process the medical records of about 4000 patients/h in the 1-MB network backbone environments, which comprises about the 4% of the total outpatients in Taiwan.

  2. Thermal analysis for ion-exchange column system

    SciTech Connect

    Lee, S. Y.; King, W. D.

    2012-07-01

    Models have been developed to simulate the thermal characteristics of Crystalline Silico-titanate (CST) ion exchange media fully loaded with radioactive cesium in a column configuration and distributed within a waste storage tank. This work was conducted to support the Small Column Ion Exchange (SCIX) program which is focused on processing dissolved, high-sodium salt waste for the removal of specific radionuclides (including Cs-137, Sr-90, and actinides) within a High Level Waste (HLW) storage tank at the Savannah River Site. A two-dimensional computational modeling approach for the in-column ion-exchange domain was taken to include conservative, bounding estimates for key parameters such that the results would provide the maximum centerline temperatures achievable under the design configurations using a feed composition known to promote high cesium loading on CST. A primary objective of these calculations was to estimate temperature distributions across packed CST beds immersed in waste supernate or filled with dry air under various accident scenarios. Accident scenarios evaluated included loss of salt solution flow through the bed, inadvertent column drainage, and loss of active cooling in the column. The modeling results demonstrate that the baseline design using one central and four outer cooling tubes provides a highly efficient cooling mechanism for reducing the maximum column temperature. (authors)

  3. Effect of resin charged functional group, porosity, and chemical matrix on the long-term pharmaceutical removal mechanism by conventional ion exchange resins.

    PubMed

    Wang, Wei; Li, Xiaofeng; Yuan, Shengliu; Sun, Jian; Zheng, Shaokui

    2016-10-01

    This study attempted to clarify the long-term pharmaceutical removal mechanism from sewage treatment plant effluent during the cyclical adsorption-regeneration operation of 5 commercial resin-based fixed-bed reactors with the simultaneous occurrence of electrostatic interactions and complex non-electrostatic interactions. It examined 12 pharmaceuticals belonging to 10 therapeutic classes with different predominant existing forms and hydrophobicities. Furthermore, the effect of the resin charged functional group (strong-base vs. strong-acid vs. non-ionic), porosity (macroporous vs. gel), and chemical matrix (polystyrenic vs. polyacrylic) on the mechanism was investigated to optimize resin properties and achieve higher pharmaceutical removal. The results reported herein indicate the importance of non-electrostatic interactions between pharmaceuticals and the resin backbone during short-term cyclical operation (i.e., the 1st adsorption-regeneration cycle). With the development of cyclical operation, however, non-electrostatic interaction-induced pharmaceutical removal generally decreased and even disappeared when equilibrium was achieved between the influent and the resin. Despite pharmaceutical therapeutic class or hydrophilicity, anion (or cation) exchange resin preferentially removed those pharmaceuticals that were predominantly present as organic anions (or cations) by ion exchange process during long-term cyclical operation (i.e., ≥6 adsorption-regeneration cycles). Besides pharmaceuticals predominantly present as undissociated molecules, some amphoteric pharmaceuticals containing large amounts of zwitterions were also difficult to remove by ion exchange resin. Additionally, neither resin porosity nor chemical matrix had any significant effect on the long-term pharmaceutical removal mechanism.

  4. Effects of weakly coupled and dense quantum plasmas environments on charge exchange and ionization processes in Na+ + Rb(5s) atom collisions

    NASA Astrophysics Data System (ADS)

    Pandey, Mukesh Kumar; Lin, Yen-Chang; Ho, Yew Kam

    2017-02-01

    The effects of weakly coupled or classical and dense quantum plasmas environment on charge exchange and ionization processes in Na+ + Rb(5s) atom collision at keV energy range have been investigated using classical trajectory Monte Carlo (CTMC) method. The interaction of three charged particles are described by the Debye-Hückel screen potential for weakly coupled plasma, whereas exponential cosine-screened Coulomb potential have been used for dense quantum plasma environment and the effects of both conditions on the cross sections are compared. It is found that screening effects on cross sections in high Debye length condition is quite small in both plasma environments. However, enhanced screening effects on cross sections are observed in dense quantum plasmas for low Debye length condition, which becomes more effective while decreasing the Debye length. Also, we have found that our calculated results for plasma-free case are comparable with the available theoretical results. These results are analyzed in light of available theoretical data with the choice of model potentials.

  5. Proposal of Simplified Method of Analysis of Charge Transfer Associated with Return Strokes

    NASA Astrophysics Data System (ADS)

    Michishita, Koji; Umehara, Satoshi; Kawamoto, Shinji; Maeda, Koji

    Charge transfer is one of the most important parameters when one discusses the damage to the equipments on a power line due to the energy of the lightning. The amount of charge transfer associated with a lightning flash or individual strokes can be estimated by using the electric field change measured with a slow antenna. In this letter, the authors propose a simplified method of analysis of charge transfer associated with cloud-to-ground strokes along with estimation of the height of a charge in the point charge model. The height is evaluated by the product of the average speed of the downward propagating stepped leader and the time difference between the beginning of the preliminary breakdown and the onset of a return stroke.

  6. Controlling hydrogen scrambling in multiply charged protein ions during collisional activation: implications for top-down hydrogen/deuterium exchange MS utilizing collisional activation in the gas phase.

    PubMed

    Abzalimov, Rinat R; Kaltashov, Igor A

    2010-02-01

    Hydrogen exchange in solution combined with ion fragmentation in the gas phase followed by MS detection emerged in recent years as a powerful tool to study higher order protein structure and dynamics. However, a certain type of ion chemistry in the gas phase, namely, internal rearrangement of labile hydrogen atoms (the so-called hydrogen scrambling), is often cited as a factor limiting the utility of this experimental technique. Although several studies have been carried out to elucidate the roles played by various factors in the occurrence and the extent of hydrogen scrambling, there is still no consensus as to what experimental protocol should be followed to avoid or minimize it. In this study we employ fragmentation of mass-selected subpopulations of protein ions to assess the extent of internal proton mobility prior to dissociation. A unique advantage of tandem MS is that it not only provides a means to map the deuterium content of protein ions whose overall levels of isotope incorporation can be precisely defined by controlling the mass selection window, but also correlates this spatial isotope distribution with such global characteristic as the protein ion charge state. Hydrogen scrambling does not occur when the charge state of the precursor protein ions selected for fragmentation is high. Fragment ions derived from both N- and C-terminal parts of the protein are equally unaffected by scrambling. However, spatial distribution of deuterium atoms obtained by fragmenting low-charge-density protein ions is consistent with a very high degree of scrambling prior to the dissociation events. The extent of hydrogen scrambling is also high when multistage fragmentation is used to probe deuterium incorporation locally. Taken together, the experimental results provide a coherent picture of intramolecular processes occurring prior to the dissociation event and provide guidance for the design of experiments whose outcome is unaffected by hydrogen scrambling.

  7. Numerical analysis of the steam flow field in shell and tube heat exchanger

    NASA Astrophysics Data System (ADS)

    Bartoszewicz, Jarosław; Bogusławski, Leon

    2016-06-01

    In the paper, the results of numerical simulations of the steam flow in a shell and tube heat exchanger are presented. The efficiency of different models of turbulence was tested. In numerical calculations the following turbulence models were used: k-ɛ, RNG k-ɛ, Wilcox k-ω, Chen-Kim k-ɛ, and Lam-Bremhorst k-ɛ. Numerical analysis of the steam flow was carried out assuming that the flow at the inlet section of the heat exchanger were divided into three parts. The angle of steam flow at inlet section was determined individually in order to obtain the best configuration of entry vanes and hence improve the heat exchanger construction. Results of numerical studies were verified experimentally for a real heat exchanger. The modification of the inlet flow direction according to theoretical considerations causes the increase of thermal power of a heat exchanger of about 14%.

  8. Analysis of the Na+/Ca2+ exchanger gene family within the phylum Nematoda.

    PubMed

    He, Chao; O'Halloran, Damien M

    2014-01-01

    Na+/Ca2+ exchangers are low affinity, high capacity transporters that rapidly transport calcium at the plasma membrane, mitochondrion, endoplasmic (and sarcoplasmic) reticulum, and the nucleus. Na+/Ca2+ exchangers are widely expressed in diverse cell types where they contribute homeostatic balance to calcium levels. In animals, Na+/Ca2+ exchangers are divided into three groups based upon stoichiometry: Na+/Ca2+ exchangers (NCX), Na+/Ca2+/K+ exchangers (NCKX), and Ca2+/Cation exchangers (CCX). In mammals there are three NCX genes, five NCKX genes and one CCX (NCLX) gene. The genome of the nematode Caenorhabditis elegans contains ten Na+/Ca2+ exchanger genes: three NCX; five CCX; and two NCKX genes. Here we set out to characterize structural and taxonomic specializations within the family of Na+/Ca2+ exchangers across the phylum Nematoda. In this analysis we identify Na+/Ca2+ exchanger genes from twelve species of nematodes and reconstruct their phylogenetic and evolutionary relationships. The most notable feature of the resulting phylogenies was the heterogeneous evolution observed within exchanger subtypes. Specifically, in the case of the CCX exchangers we did not detect members of this class in three Clade III nematodes. Within the Caenorhabditis and Pristionchus lineages we identify between three and five CCX representatives, whereas in other Clade V and also Clade IV nematode taxa we only observed a single CCX gene in each species, and in the Clade III nematode taxa that we sampled we identify NCX and NCKX encoding genes but no evidence of CCX representatives using our mining approach. We also provided re-annotation for predicted CCX gene structures from Heterorhabditis bacteriophora and Caenorhabditis japonica by RT-PCR and sequencing. Together, these findings reveal a complex picture of Na+/Ca2+ transporters in nematodes that suggest an incongruent evolutionary history of proteins that provide central control of calcium dynamics.

  9. Analysis of the Na+/Ca2+ Exchanger Gene Family within the Phylum Nematoda

    PubMed Central

    He, Chao; O'Halloran, Damien M.

    2014-01-01

    Na+/Ca2+ exchangers are low affinity, high capacity transporters that rapidly transport calcium at the plasma membrane, mitochondrion, endoplasmic (and sarcoplasmic) reticulum, and the nucleus. Na+/Ca2+ exchangers are widely expressed in diverse cell types where they contribute homeostatic balance to calcium levels. In animals, Na+/Ca2+ exchangers are divided into three groups based upon stoichiometry: Na+/Ca2+ exchangers (NCX), Na+/Ca2+/K+ exchangers (NCKX), and Ca2+/Cation exchangers (CCX). In mammals there are three NCX genes, five NCKX genes and one CCX (NCLX) gene. The genome of the nematode Caenorhabditis elegans contains ten Na+/Ca2+ exchanger genes: three NCX; five CCX; and two NCKX genes. Here we set out to characterize structural and taxonomic specializations within the family of Na+/Ca2+ exchangers across the phylum Nematoda. In this analysis we identify Na+/Ca2+ exchanger genes from twelve species of nematodes and reconstruct their phylogenetic and evolutionary relationships. The most notable feature of the resulting phylogenies was the heterogeneous evolution observed within exchanger subtypes. Specifically, in the case of the CCX exchangers we did not detect members of this class in three Clade III nematodes. Within the Caenorhabditis and Pristionchus lineages we identify between three and five CCX representatives, whereas in other Clade V and also Clade IV nematode taxa we only observed a single CCX gene in each species, and in the Clade III nematode taxa that we sampled we identify NCX and NCKX encoding genes but no evidence of CCX representatives using our mining approach. We also provided re-annotation for predicted CCX gene structures from Heterorhabditis bacteriophora and Caenorhabditis japonica by RT-PCR and sequencing. Together, these findings reveal a complex picture of Na+/Ca2+ transporters in nematodes that suggest an incongruent evolutionary history of proteins that provide central control of calcium dynamics. PMID:25397810

  10. Experimental testing and analytical analysis of a plastic panel heat exchanger for greenhouse heating

    SciTech Connect

    Olszewski, M.; Thomas, J.F.

    1980-02-01

    The performance of a plastic panel-type heat exchanger, suitable for greenhouse heating using low-grade (25 to 60/sup 0/C water) power plant reject heat, was investigated theoretically and experimentally. The theoretical analysis showed that a plastic panel heat exchanger would have an overall heat transfer coefficient, U/sub 0/, of about 18 w/m/sup 2/-/sup 0/C compared to about 12 w/m/sup 2/-/sup 0/C for a fin-tube heat exchanger, under typical greenhouse conditions. Furthermore the plastic heat exchanger would require less fan power due to reduced air pressure losses. The experimental data revealed a similar functional relationship for U/sub 0/ and air flow when compared with the theoretical calculations, however the experimental values of U/sub 0/ were consistently larger by 20 to 30%. It was concluded that a properly designed plastic heat exchanger can compete with metal fin tube type exchangers on a performance basis, but the plastic heat exchangers are 3 to 4 times larger by volume. However, because of the lower cost of plastic, a substantial cost reduction is expected. It appears that further study, examining heat exchanger lifetime, performance and costs, is warranted.

  11. Multiply Controlled Verbal Operants: An Analysis and Extension to the Picture Exchange Communication System

    ERIC Educational Resources Information Center

    Bondy, A.; Tincani, M.; Frost, L.

    2004-01-01

    This paper presents Skinner's (1957) analysis of verbal behavior as a framework for understanding language acquisition in children with autism. We describe Skinner's analysis of pure and impure verbal operants and illustrate how this analysis may be applied to the design of communication training programs. The picture exchange communication system…

  12. HEAT TRANSFER ANALYSIS FOR ION-EXCHANGE COLUMN SYSTEM

    SciTech Connect

    Lee, S.; King, W.

    2011-05-23

    Models have been developed to simulate the thermal characteristics of Crystalline Silicotitanate (CST) ion exchange media fully loaded with radioactive cesium in a column configuration and distributed within a waste storage tank. This work was conducted to support the Small Column Ion Exchange (SCIX) program which is focused on processing dissolved, high-sodium salt waste for the removal of specific radionuclides (including Cs-137, Sr-90, and actinides) within a High Level Waste (HLW) storage tank at the Savannah River Site. The SCIX design includes CST columns inserted and supported in the tank top risers for cesium removal. Temperature distributions and maximum temperatures across the column were calculated with a focus on process upset conditions. A two-dimensional computational modeling approach for the in-column ion-exchange domain was taken to include conservative, bounding estimates for key parameters such that the results would provide the maximum centerline temperatures achievable under the design configurations using a feed composition known to promote high cesium loading on CST. The current full-scale design for the CST column includes one central cooling pipe and four outer cooling tubes. Most calculations assumed that the fluid within the column was stagnant (i.e. no buoyancy-induced flow) for a conservative estimate. A primary objective of these calculations was to estimate temperature distributions across packed CST beds immersed in waste supernate or filled with dry air under various accident scenarios. Accident scenarios evaluated included loss of salt solution flow through the bed, inadvertent column drainage, and loss of active cooling in the column. The modeling results demonstrate that the baseline design using one central and four outer cooling tubes provides a highly efficient cooling mechanism for reducing the maximum column temperature.

  13. Analysis on influencing factors of EV charging station planning based on AHP

    NASA Astrophysics Data System (ADS)

    Yan, F.; Ma, X. F.

    2016-08-01

    As a new means of transport, electric vehicle (EV) is of great significance to alleviate the energy crisis. EV charging station planning has a far-reaching significance for the development of EV industry. This paper analyzes the impact factors of EV charging station planning, and then uses the analytic hierarchy process (AHP) to carry on the further analysis to the influencing factors, finally it gets the weight of each influence factor, and provides the basis for the evaluation scheme of the planning of charging stations for EV.

  14. Development of a laser cleaning method for the first mirror surface of the charge exchange recombination spectroscopy diagnostics on ITER

    SciTech Connect

    Kuznetsov, A. P.; Buzinskij, O. I.; Gubsky, K. L.; Nikitina, E. A.; Savchenkov, A. V.; Tarasov, B. A.; Tugarinov, S. N.

    2015-12-15

    A set of optical diagnostics is expected for measuring the plasma characteristics in ITER. Optical elements located inside discharge chambers are exposed to an intense radiation load, sputtering due to collisions with energetic atoms formed in the charge transfer processes, and contamination due to recondensation of materials sputtered from different parts of the construction of the chamber. Removing the films of the sputtered materials from the mirrors with the aid of pulsed laser radiation is an efficient cleaning method enabling recovery of the optical properties of the mirrors. In this work, we studied the efficiency of removal of metal oxide films by pulsed radiation of a fiber laser. Optimization of the laser cleaning conditions was carried out on samples representing metal substrates polished with optical quality with deposition of films on them imitating the chemical composition and conditions expected in ITER. It is shown that, by a proper selection of modes of radiation exposure to the surface with a deposited film, it is feasible to restore the original high reflection characteristics of optical elements.

  15. Determining the cation exchange capacity of montmorillonite by simultaneous thermal analysis method

    NASA Astrophysics Data System (ADS)

    Boeva, N. M.; Bocharnikova, Yu. I.; Belousov, P. E.; Zhigarev, V. V.

    2016-08-01

    A way of determining the cation exchange capacity of montmorillonite by simultaneous thermal analysis is developed using as an example the bentonites of the 10th Khutor deposit (Republic of Khakassia) and the Vodopadnyi area (Sakhalin Island). A correlation is established between the cation exchange capacity of smectite and its weight loss upon heating in the range of dehydration; the enthalpy of dehydration of montmorillonite; and the weight loss and the enthalpy of thermal dissociation of ethylene glycol contained in the interlayer space of the mineral's crystal structure. These data open up new possibilities for determining the cation exchange capacity of montmorillonite, the most important technological indicator of the natural clay nanomineral.

  16. Charge translocation by the Na+/K+-ATPase investigated on solid supported membranes: rapid solution exchange with a new technique.

    PubMed Central

    Pintschovius, J; Fendler, K

    1999-01-01

    Adsorption of Na+/K+-ATPase containing membrane fragments from pig kidney to lipid membranes allows the detection of electrogenic events during the Na+/K+-ATPase reaction cycle with high sensitivity and time resolution. High stability preparations can be obtained using solid supported membranes (SSM) as carrier electrodes for the membrane fragments. The SSMs are prepared using an alkanethiol monolayer covalently linked to a gold surface on a glass substrate. The hydrophobic surface is covered with a lipid monolayer (SAM, self-assembled monolayer) to obtain a double layer system having electrical properties similar to those of unsupported bilayer membranes (BLM). As we have previously shown (, Biophys. J. 64:384-391), the Na+/K+-ATPase on a SSM can be activated by photolytic release of ATP from caged ATP. In this publication we show the first results of a new technique which allows rapid solution exchange at the membrane surface making use of the high mechanical stability of SSM preparations. Especially for substrates, which are not available as a caged substance-such as Na+ and K+-this technique is shown to be capable of yielding new results. The Na+/K+-ATPase was activated by rapid concentration jumps of ATP and Na+ (in the presence of ATP). A time resolution of up to 10 ms was obtained in these experiments. The aim of this paper is to present the new technique together with the first results obtained from the investigation of the Na+/K+-ATPase. A comparison with data taken from the literature shows considerable agreement with our experiments. PMID:9929483

  17. NMR analysis of t‐butyl‐catalyzed deuterium exchange at unactivated arene localities

    PubMed Central

    Eastman, Rachel

    2016-01-01

    Regioselective labelling of arene rings via electrophilic exchange is often dictated by the electronic environment caused by substituents present on the aromatic system. Previously, we observed the presence of a t‐butyl group, either covalently bond or added as an external reagent, could impart deuterium exchange to the unactivated, C1‐position of estrone. Here, we provide nuclear magnetic resonance analysis of this exchange in a solvent system composed of 50:50 trifluoroacetic acid and D2O with either 2‐t‐butylestrone or estrone in the presence of t‐butyl alcohol has shed insights into the mechanism of this t‐butyl‐catalyzed exchange. Fast exchange of the t‐butyl group concurrent with the gradual reduction of the H1 proton signal in both systems suggest a mechanism involving ipso attack of the t‐butyl position by deuterium. The reversible addition/elimination of the t‐butyl group activates the H1 proton towards exchange by a mechanism of t‐butyl incorporation, H1 activation and exchange, followed by eventual t‐butyl elimination. Density functional calculations are consistent with the observation of fast t‐butyl exchange concurrent with slower H1 exchange. The σ‐complex resulting from ipso attack of deuterium at the t‐butyl carbon was 6.6 kcal/mol lower in energy than that of the σ‐complex resulting from deuterium attack at C1. A better understanding of the t‐butyl‐catalyzed exchange could help in the design of labelling recipes for other phenolic metabolites. PMID:27645832

  18. Three-Dimensional Analysis of Longitudinal Space Charge Microbunching Starting From Shot Noise

    SciTech Connect

    Ratner, D.; Chao, A.; Huang, Z.

    2008-09-24

    The commissioning of the Linac Coherent Light Source (LCLS) injector showed unexpected coherent optical transition radiation (COTR) for an uncompressed electron bunch downstream of a dog-leg transport line. In this paper, we develop a three-dimensional analysis of longitudinal space charge microbunching to explain the phenomenon. Our analysis takes into account the transverse correlation of the longitudinal space charge field due to shot-noise startup and finite observation angles of the radiation. We also apply this analysis to the LCLS COTR observations.

  19. Plasma exchange for renal vasculitis and idiopathic rapidly progressive glomerulonephritis: a meta-analysis

    PubMed Central

    Walsh, Michael; Catapano, Fausta; Szpirt, Wladimir; Thorlund, Kristian; Bruchfeld, Annette; Guillevin, Loic; Haubitz, Marion; Merkel, Peter A.; Peh, Chen Au; Pusey, Charles; Jayne, David

    2011-01-01

    Background Plasma exchange may be effective adjunctive treatment for renal vasculitis. We performed a systematic review and meta-analysis of randomized control trials of plasma exchange for renal vasculitis. Study Design Systematic review and meta-analysis of manuscripts identified from electronic databases, bibliographies, and studies identified by experts. Data was abstracted in parallel by two reviewers. Setting & Population Adults with idiopathic renal vasculitis or rapidly progressive glomerulonephritis Selection Criteria for Studies Randomized controlled trials that compared standard care with standard care plus adjuvant plasma exchange in adult patients with either renal vasculitis or idiopathic rapidly progressive glomerulonephritis. Intervention Adjuvant plasma exchange Outcome Composite of end-stage renal disease or death. Results We identified 9 trials including 387 patients. In a fixed-effects model the pooled relative risk of end-stage renal disease or death was 0.80 for patients treated with adjunctive plasma exchange compared to standard care alone (95% confidence interval 0.65 to 0.99; p=0.04). No significant heterogeneity was detected (p=0.5; I2=0%). The effect of plasma exchange did not differ significantly across the range of baseline serum creatinine values (p=0.7) or number of plasma exchange treatments (p=0.8). The relative risk for end-stage renal disease was 0.64 (95% confidence interval 0.47 to 0.88; p=0.006) while the relative risk for death alone was 1.01 (95% confidence interval 0.71 to 1.4; p=0.9). Limitations Although the primary result was statistically significant, there is insufficient statistical information to reliable determine if plasma exchange reduces the composite of end-stage renal disease or death. Conclusions Plasma exchange may reduce the composite endpoint of end-stage renal disease or death in renal vasculitis. Further trials are required given the limited data available. PMID:21194817

  20. Two-phase/two-phase heat exchanger simulation analysis

    NASA Technical Reports Server (NTRS)

    Kim, Rhyn H.

    1992-01-01

    The capillary pumped loop (CPL) system is one of the most desirable devices to dissipate heat energy in the radiation environment of the Space Station providing a relatively easy control of the temperature. A condenser, a component of the CPL system, is linked with a buffer evaporator in the form of an annulus section of a double tube heat exchanger arrangement: the concentric core of the double tube is the condenser; the annulus section is used as a buffer between the conditioned space and the radiation surrounding but works as an evaporator. A CPL system with this type of condenser is modeled to simulate its function numerically. Preliminary results for temperature variations of the system are shown and more investigations are suggested for further improvement.

  1. Joy of cex: Sharpening the (t,He-3) probe at 345 MeV for the charge-exchange knife drawer

    NASA Astrophysics Data System (ADS)

    Howard, Meredith E.

    This data set represents the first step in a campaign of (t, 3He) charge-exchange experiments at the National Superconducting Cyclotron Laboratory designed explicitly to measure Gamow-Teller strength distributions in the electron capture direction for stable medium-heavy atomic nuclei, with particular interest in reaching the nuclei in the pf -shell or masses up to A=112. The 115 MeV/nucleon secondary triton beam with an average intensity of 4x106 pps on 10 mg/cm2 thick target foils produces 3He that are measured in the focal plane detectors of the S800 magnetic spectrometer. From these data, the scattering angle of the tritons is reconstructed to within 7 mrad and the energy of the recoil nucleus is reconstructed to better then 250 keV. Since there is no comprehensive study of the (t, 3He) probe for triton energies of 100-400 MeV/nucleon, this data is the first step in evaluating the advantages of extracting B(GT) from the (t,3He) probe over other hadronic probes. The first target is a CD2 target used for calibrating cross section. This is the third measurement for the (t, 3He) probe on 12C above 100 MeV/nucleon. The present 12C(t,3He) cross section for the 12B ground state (Jpi = 1 +) is lower than a previous measurement at the NSCL by more than one standard deviation in uncertainty but agrees with 12C( 3He,t)12N. This (t,3He) measurement for 24Mg, the second target, is the first above 100 MeV/nucleon. The B(GT) distribution for 24Na is extracted from differential cross sections as a function of residual nucleus excitation energy up to 7 MeV. For each peak in excitation energy, the differential cross section as a function of reconstructed scattering angle is extrapolated to zero degrees using angular distrubutions calculated with the distorted wave calculations from the code FOLD and transformed to q = 0 zero momentum transfer. Uncertainties in the B(GT) include a calculation of interference to Jpi=1 + expected from DeltaL=2, DeltaS=1 reactions. Comparisons of B

  2. Multi-frequency inversion-charge pumping for charge separation and mobility analysis in high-k/InGaAs metal-oxide-semiconductor field-effect transistors

    SciTech Connect

    Djara, V.; Cherkaoui, K.; Negara, M. A.; Hurley, P. K.

    2015-11-28

    An alternative multi-frequency inversion-charge pumping (MFICP) technique was developed to directly separate the inversion charge density (N{sub inv}) from the trapped charge density in high-k/InGaAs metal-oxide-semiconductor field-effect transistors (MOSFETs). This approach relies on the fitting of the frequency response of border traps, obtained from inversion-charge pumping measurements performed over a wide range of frequencies at room temperature on a single MOSFET, using a modified charge trapping model. The obtained model yielded the capture time constant and density of border traps located at energy levels aligned with the InGaAs conduction band. Moreover, the combination of MFICP and pulsed I{sub d}-V{sub g} measurements enabled an accurate effective mobility vs N{sub inv} extraction and analysis. The data obtained using the MFICP approach are consistent with the most recent reports on high-k/InGaAs.

  3. Quantum Monte Carlo analysis of a charge ordered insulating antiferromagnet: the Ti4O7 Magnéli phase

    DOE PAGES

    Benali, Anouar; Shulenburger, Luke; Krogel, Jaron T.; ...

    2016-06-07

    The Magnéli phase Ti4O7 is an important transition metal oxide with a wide range of applications because of its interplay between charge, spin, and lattice degrees of freedom. At low temperatures, it has non-trivial magnetic states very close in energy, driven by electronic exchange and correlation interactions. In this paper, we have examined three low-lying states, one ferromagnetic and two antiferromagnetic, and calculated their energies as well as Ti spin moment distributions using highly accurate quantum Monte Carlo methods. We compare our results to those obtained from density functional theory-based methods that include approximate corrections for exchange and correlation. Ourmore » results confirm the nature of the states and their ordering in energy, as compared with density-functional theory methods. However, the energy differences and spin distributions differ. Finally, a detailed analysis suggests that non-local exchange–correlation functionals, in addition to other approximations such as LDA+U to account for correlations, are needed to simultaneously obtain better estimates for spin moments, distributions, energy differences and energy gaps.« less

  4. Bi-directional exchange of ammonia in a pine forest ecosystem - a model sensitivity analysis

    NASA Astrophysics Data System (ADS)

    Moravek, Alexander; Hrdina, Amy; Murphy, Jennifer

    2016-04-01

    Ammonia (NH3) is a key component in the global nitrogen cycle and of great importance for atmospheric chemistry, neutralizing atmospheric acids and leading to the formation of aerosol particles. For understanding the role of NH3 in both natural and anthropogenically influenced environments, the knowledge of processes regulating its exchange between ecosystems and the atmosphere is essential. A two-layer canopy compensation point model is used to evaluate the NH3 exchange in a pine forest in the Colorado Rocky Mountains. The net flux comprises the NH3 exchange of leaf stomata, its deposition to leaf cuticles and exchange with the forest ground. As key parameters the model uses in-canopy NH3 mixing ratios as well as leaf and soil emission potentials measured at the site in summer 2015. A sensitivity analysis is performed to evaluate the major exchange pathways as well as the model's constraints. In addition, the NH3 exchange is examined for an extended range of environmental conditions, such as droughts or varying concentrations of atmospheric pollutants, in order to investigate their influence on the overall net exchange.

  5. Exchange bias and anisotropy analysis of nano-composite Co84Zr16N thin films

    NASA Astrophysics Data System (ADS)

    Singh, Jitendra; Taube, William Ringal; Ansari, Akhtar Saleem; Gupta, Sanjeev Kumar; Kulriya, Pawan Kumar; Akhtar, Jamil

    2015-03-01

    Nano-composite Co84Zr16N (CZN) films were prepared by reactive co-sputter deposition. As-deposited CZN films have not shown any exchange bias effect. But annealed (390 K) and field cooled samples have shown exchange bias phenomena. The observed exchange bias is attributed to inter-cluster exchange coupling between ferromagnetic and antiferromagnetic nano-composite phase. High resolution transmission electron microscope study reveals that, the CZN films are composed of ordered and crystalline ferromagnetic Cobalt nano-clusters embedded in an antiferromagnetic matrix. X-ray diffraction confirms the poly-crystalline growth of the CZN films with a preferred fcc (622) phase formation. In-plane anisotropy of the exchange biased films was investigated by rotational magnetization curve, and the analysis shows that the magnetization reversal behaves according to the coherent rotation of the magnetic moment vector. Effectively, exchange bias effect in such single layer films could be attributed to co-existing antiferromagnetic and ferromagnetic phase within the single layer. Such single layer nano-composite films can be a possible alternative to the bilayer combination of antiferromagnetic/ferromagnetic exchange biased films and are ideally suited for spintronics and tunnel junction applications.

  6. Motion of the Debris from a High-Altitude Nuclear Explosion: Simulations Including Collisionless Shock and Charge Exchange

    DTIC Science & Technology

    2014-06-01

    INTRODUCTION .......................................................................................................1   A.   INTRODUCTION ...INTENTIONALLY LEFT BLANK 1 I. INTRODUCTION A. INTRODUCTION STARFISH PRIME (hereafter referred to as STARFISH) was a high-altitude nuclear...analysis and presentation of the data. The editors stated in the introduction that, “a central purpose of this introduction is to call attention to the

  7. Time domain analysis of superradiant instability for the charged stringy black hole-mirror system

    NASA Astrophysics Data System (ADS)

    Li, Ran; Tian, Yu; Zhang, Hongbao; Zhao, Junkun

    2015-11-01

    It has been proved that the charged stringy black holes are stable under the perturbations of massive charged scalar fields. However, superradiant instability can be generated by adding the mirror-like boundary condition to the composed system of charged stringy black hole and scalar field. The unstable boxed quasinormal modes have been calculated by using both analytical and numerical methods. In this paper, we further provide a time domain analysis by performing a long time evolution of charged scalar field configuration in the background of the charged stringy black hole with the mirror-like boundary condition imposed. We have used the ingoing Eddington-Finkelstein coordinates to derive the evolution equation, and adopted Pseudo-spectral method and the forth-order Runge-Kutta method to evolve the scalar field with the initial Gaussian wave packet. It is shown by our numerical scheme that Fourier transforming the evolution data coincides well with the unstable modes computed from frequency domain analysis. The existence of the rapid growth mode makes the charged stringy black hole a good test ground to study the nonlinear development of superradiant instability.

  8. Analysis of In-Route Wireless Charging for the Shuttle System at Zion National Park

    SciTech Connect

    Meintz, Andrew; Prohaska, Robert; Konan, Arnaud; Ragatz, Adam; Markel, Tony; Kelly, Ken

    2016-10-05

    System right-sizing is critical to implementation of wireless power transfer (WPT) for electric vehicles (EVs). This study will analyze potential WPT scenarios for the electrification of shuttle buses at Zion National Park utilizing a modelling tool developed by NREL called WPTSim. This tool uses second-by-second speed, location, and road grade data from the conventional shuttles in operation to simulate the incorporation of WPT at fine granularity. Vehicle power and state of charge are simulated over the drive cycle to evaluate potential system designs. The required battery capacity is determined based on the rated power at a variable number of charging locations. The outcome of this work is an analysis of the design tradeoffs for the electrification of the shuttle fleet with wireless charging versus conventional overnight charging.

  9. Analysis of In-Route Wireless Charging for the Shuttle System at Zion National Park

    SciTech Connect

    Meintz, Andrew; Prohaska, Robert; Konan, Arnaud; Ragatz, Adam; Markel, Tony; Kelly, Ken

    2016-12-08

    System right-sizing is critical to implementation of wireless power transfer (WPT) for electric vehicles. This study will analyze potential WPT scenarios for the electrification of shuttle buses at Zion National Park utilizing a modelling tool developed by the National Renewable Energy Laboratory called WPTSim. This tool uses second-by-second speed, location, and road grade data from the conventional shuttles in operation to simulate the incorporation of WPT at fine granularity. Vehicle power and state of charge are simulated over the drive cycle to evaluate potential system designs. The required battery capacity is determined based on the rated power at a variable number of charging locations. The outcome of this work is an analysis of the design tradeoffs for the electrification of the shuttle fleet with wireless charging versus conventional overnight charging.

  10. Construction and operation of parallel electric and magnetic field spectrometers for mass/energy resolved multi-ion charge exchange diagnostics on the Tokamak Fusion Test Reactor

    NASA Astrophysics Data System (ADS)

    Medley, S. S.; Roquemore, A. L.

    1998-07-01

    A novel charge exchange spectrometer using a dee-shaped region of parallel electric and magnetic fields was developed at the Princeton Plasma Physics Laboratory for neutral particle diagnostics on the Tokamak Fusion Test Reactor (TFTR). The E∥B spectrometer has an energy range of 0.5⩽A (amu)E (keV)⩽600 and provides mass-resolved energy spectra of H+, D+, and T+ (or 3He+) ion species simultaneously during a single discharge. The detector plane exhibits parallel rows of analyzed ions, each row containing the energy dispersed ions of a given mass-to-charge ratio. The detector consists of a large area microchannel plate (MCP) which is provided with three rectangular, semicontinuous active area strips, one coinciding with each of the mass rows for detection of H+, D+, and T+ (or 3He+) and each mass row has 75 energy channels. To suppress spurious signals attending operation of the plate in the magnetic fringe field of the spectrometer, the MCP was housed in a double-walled iron shield with a wire mesh ion entrance window. Using an accelerator neutron generator, the MCP neutron detection efficiency was measured to be 1.7×10-3 and 6.4×10-3 counts/neutron/cm2 for 2.5 MeV-DD and 14 MeV-DT neutrons, respectively. The design and calibration of the spectrometer are described in detail, including the effect of MCP exposure to tritium, and results obtained during high performance D-D operation on TFTR are presented to illustrate the performance of the E∥B spectrometer. The spectrometers were not used during D-T plasma operation due to the cost of providing the required radiation shielding.

  11. An Exchange Structure Analysis of the Development of Online Intercultural Activity

    ERIC Educational Resources Information Center

    Kitade, Keiko

    2012-01-01

    Internet-mediated intercultural discussions have been adopted for intercultural and second-language learning. However, the notion of community development in this context has received less attention. This study employs exchange structure (ES) analysis (Stubbs, M. (1983). "Discourse analysis." Oxford: Basil Blackwell) to investigate the…

  12. Atom Probe Analysis of Ex Situ Gas-Charged Stable Hydrides.

    PubMed

    Haley, Daniel; Bagot, Paul A J; Moody, Michael P

    2017-01-30

    In this work, we report on the atom probe tomography analysis of two metallic hydrides formed by pressurized charging using an ex situ hydrogen charging cell, in the pressure range of 200-500 kPa (2-5 bar). Specifically we report on the deuterium charging of Pd/Rh and V systems. Using this ex situ system, we demonstrate the successful loading and subsequent atom probe analysis of deuterium within a Pd/Rh alloy, and demonstrate that deuterium is likely present within the oxide-metal interface of a native oxide formed on vanadium. Through these experiments, we demonstrate the feasibility of ex situ hydrogen analysis for hydrides via atom probe tomography, and thus a practical route to three-dimensional imaging of hydrogen in hydrides at the atomic scale.

  13. Lipid analysis via HPLC with a charged aerosol detector

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Most lipid extracts are a mixture of saturated and unsaturated molecules. Therefore, the most successful HPLC detectors for the quantitative analysis of lipids have involved the use of “universal” or “mass” detectors such as flame ionization detectors (FID) and evaporative light scattering detectors...

  14. Experimental investigation on heat transfer analysis of conical coil heat exchanger with 90° cone angle

    NASA Astrophysics Data System (ADS)

    Purandare, Pramod S.; Lele, Mandar M.; Gupta, Raj Kumar

    2015-03-01

    In the present study, an experimental investigation on thermal performance of the conical coil heat exchanger with 90° conical coil heat exchanger is reported. Three different conical coil heat exchangers of same mean coil diameter (Dm = 200 mm) with different tube diameters ( di = 8, 10, 12.5 mm) are analyzed under steady state condition. The analysis is carried out for the tube side hot fluid flow range of 10-100 lph ( Re = 500-5,000), while the shell side flow range of 30-90 lph. The data available from experimentation leads to evaluate heat transfer coefficients for inside and outside the tube of the conical coil heat exchanger by Wilsons plot method. The calculations are further extended to estimate Nusselt Number ( Nu) and effectiveness. The empirical correlations are proposed for predicting Nu and the outlet temperatures of hot and cold fluids. The predicted empirical correlations show reasonable agreement with the experimental results within the given range of parameters.

  15. Mixed Multifractal Analysis of Crude Oil, Gold and Exchange Rate Series

    NASA Astrophysics Data System (ADS)

    Dai, Meifeng; Shao, Shuxiang; Gao, Jianyu; Sun, Yu; Su, Weiyi

    2016-11-01

    The multifractal analysis of one time series, e.g. crude oil, gold and exchange rate series, is often referred. In this paper, we apply the classical multifractal and mixed multifractal spectrum to study multifractal properties of crude oil, gold and exchange rate series and their inner relationships. The obtained results show that in general, the fractal dimension of gold and crude oil is larger than that of exchange rate (RMB against the US dollar), reflecting a fact that the price series in gold and crude oil are more heterogeneous. Their mixed multifractal spectra have a drift and the plot is not symmetric, so there is a low level of mixed multifractal between each pair of crude oil, gold and exchange rate series.

  16. Application of nonlinear time series analysis techniques to high-frequency currency exchange data

    NASA Astrophysics Data System (ADS)

    Strozzi, Fernanda; Zaldívar, José-Manuel; Zbilut, Joseph P.

    2002-09-01

    In this work we have applied nonlinear time series analysis to high-frequency currency exchange data. The time series studied are the exchange rates between the US Dollar and 18 other foreign currencies from within and without the Euro zone. Our goal was to determine if their dynamical behaviours were in some way correlated. The nonexistence of stationarity called for the application of recurrence quantification analysis as a tool for this analysis, and is based on the definition of several parameters that allow for the quantification of recurrence plots. The method was checked using the European Monetary System currency exchanges. The results show, as expected, the high correlation between the currencies that are part of the Euro, but also a strong correlation between the Japanese Yen, the Canadian Dollar and the British Pound. Singularities of the series are also demonstrated taking into account historical events, in 1996, in the Euro zone.

  17. Analysis of induced temperature anomalies along borehole heat exchangers

    NASA Astrophysics Data System (ADS)

    Lindner, Michael; Schelenz, Sophie; Stollberg, Reiner; Gossel, Wolfgang; Dietrich, Peter; Vienken, Thomas

    2015-04-01

    Over the last years, the thermal use of the shallow subsurface for heat generation, cooling, and thermal energy storage has increased. However, the injection or extraction of heat potentially drives changes in the subsurface temperature regime; especially in urban areas. The presented case study investigates the intensive use of borehole heat exchangers (BHE) and their potential thermal impacts on subsurface temperatures, as well as thermal interactions between individual BHE's for a residential neighborhood in Cologne, Germany. Based on on-site subsurface parameterization, a 3D subsurface model was designed, using the finite element software FEFLOW (DHI WASY). The model contains five BHE, extracting 8.2 kW, with a maximum BHE depth of 38 m, whereby the thickness of the unsaturated zone is 22 m. The simulated time span is 10 years. This study focusses on two questions: How will different BHE arrangements vary in terms of temperature plume formation and potential system interaction and what is the influence of seasonal subsurface heat storage on soil and ground water temperatures.

  18. Comparative Analysis and Approximations of Space -Charge Formation in Langmuir Electrodes Including Temperature Effects.

    NASA Astrophysics Data System (ADS)

    Valdeblànquez, Eder

    2001-10-01

    Eder Valdeblànquez,Universidad del Zulia,Apartado 4011-A 526,Maracaibo,Venezuela. ABSTRACT: In this paper by space charge effect in Langmuir probes are compared for different kind of symmetries; plane, cylindrical and spherical. A detailed analysis is performed here including temperature effects, and therefore kinetic theory is used instead of fluid equations as other authors. The strongly non-linear equations obtained here have been solved first by numerical analysis and later by approximations using Bessel functions. The accuracy of each approximaton is also discussed. Space Charge effects are important in plane geometries than in the case of cylindrical or spherical symmetries.

  19. Measurement of deuterium density profiles in the H-mode steep gradient region using charge exchange recombination spectroscopy on DIII-D

    DOE PAGES

    Haskey, S. R.; Grierson, B. A.; Burrell, K. H.; ...

    2016-09-26

    Recent completion of a thirty two channel main-ion (deuterium) charge exchange recombination spectroscopy (CER) diagnostic on the DIII-D tokamak enables detailed comparisons between impurity and main-ion temperature, density, and toroidal rotation. In a H-mode DIII-D discharge, these new measurement capabilities are used to provide the deuterium density profile, demonstrate the importance of profile alignment between Thomson scattering and CER diagnostics, and aid in determining the electron temperature at the separatrix. Sixteen sightlines cover the core of the plasma and another sixteen are densely packed towards the plasma edge, providing high resolution measurements across the pedestal and steep gradient region inmore » H-mode plasmas. Extracting useful physical quantities such as deuterium density is challenging due to multiple photoemission processes. Finally, these challenges are overcome using a detailed fitting model and by forward modeling the photoemission using the FIDASIM code, which implements a comprehensive collisional radiative model. Published by AIP Publishing.« less

  20. A diagnostic neutral beam system for the MST reversed-field pinch: Charge-exchange recombination spectroscopy and Rutherford scattering (abstract)

    NASA Astrophysics Data System (ADS)

    Den Hartog, D. J.; Fiksel, G.; Davydenko, V.; Ivanov, A.; Mishagin, V.

    1999-01-01

    A diagnostic neutral beam system is being purchased for the MST reversed-field pinch. Initially, this beam will be used for charge-exchange recombination spectroscopy (CHERS) to measure impurity ion velocity and temperature, both equilibrium and fluctuating. This work is an extension of an existing MST spectroscopic diagnostic which has successfully measured chord-averaged flow with 10 μs time resolution [D. J. Den Hartog and R. J. Fonck, Rev. Sci. Instrum. 65, 3238 (1994)]. CHERS will provide high spatial resolution, critically needed for the investigation of fluctuations associated with the dynamo and transport. This beam will also be applied to Rutherford scattering for local measurements of majority ion velocity and temperature. Ion velocity is determined by the shift of the energy spectrum of the scattered neutral beam; ion temperature by the width of the energy spectrum. The scattered spectrum will be detected by two multichannel neutral particle analyzers. In order to achieve a time resolution of about 10 μs, the neutral beam equivalent current density and current must be high; both of these characteristics are hallmarks of the DINA beam design.

  1. Double-peak elution profile of a monoclonal antibody in cation exchange chromatography is caused by histidine-protonation-based charge variants.

    PubMed

    Luo, Haibin; Cao, Mingyan; Newell, Kelcy; Afdahl, Christopher; Wang, Jihong; Wang, William K; Li, Yuling

    2015-12-11

    We have systemically investigated unusual elution behaviors of an IgG4 (mAb A) in cation exchange chromatography (CEX). This mAb A exhibited two elution peaks under certain conditions when being purified by several strong CEX columns. When either of the two peaks was isolated and re-injected on the same column, the similar pattern was observed again during elution. The protein distribution between the two peaks could be altered by NaCl concentration in the feed, or NaCl concentration in wash buffer, or elution pH, suggesting two pH-associated strong-and-weak binding configurations. The protein distributions under different pH values showed good correlation with protonated/un-protonated fractions of a histidine residue. These results suggest that the double-peak elution profile associates with histidine-protonation-based charge variants. By conducting pepsin digestion, amino-acid specific chemical modifications, peptide mapping, and measuring the effects of elution residence time, a histidine in the variable fragment (Fab) was identified to be the root cause. Besides double-peak pattern, mAb A can also exhibit peak-shouldering or single elution peak on different CEX resins, reflecting different resins' resolving capability on protonated/un-protonated forms. This work characterizes a novel cause for unusual elution behaviors in CEX and also provides alternative avenues of purification development for mAbs with similar behaviors.

  2. Determination of gas phase protein ion densities via ion mobility analysis with charge reduction.

    PubMed

    Maisser, Anne; Premnath, Vinay; Ghosh, Abhimanyu; Nguyen, Tuan Anh; Attoui, Michel; Hogan, Christopher J

    2011-12-28

    We use a charge reduction electrospray (ESI) source and subsequent ion mobility analysis with a differential mobility analyzer (DMA, with detection via both a Faraday cage electrometer and a condensation particle counter) to infer the densities of single and multiprotein ions of cytochrome C, lysozyme, myoglobin, ovalbumin, and bovine serum albumin produced from non-denaturing (20 mM aqueous ammonium acetate) and denaturing (1 : 49.5 : 49.5, formic acid : methanol : water) ESI. Charge reduction is achieved through use of a Po-210 radioactive source, which generates roughly equal concentrations of positive and negative ions. Ions produced by the source collide with and reduce the charge on ESI generated drops, preventing Coulombic fissions, and unlike typical protein ESI, leading to gas-phase protein ions with +1 to +3 excess charges. Therefore, charge reduction serves to effectively mitigate any role that Coulombic stretching may play on the structure of the gas phase ions. Density inference is made via determination of the mobility diameter, and correspondingly the spherical equivalent protein volume. Through this approach it is found that for both non-denaturing and denaturing ESI-generated ions, gas-phase protein ions are relatively compact, with average densities of 0.97 g cm(-3) and 0.86 g cm(-3), respectively. Ions from non-denaturing ESI are found to be slightly more compact than predicted from the protein crystal structures, suggesting that low charge state protein ions in the gas phase are slightly denser than their solution conformations. While a slight difference is detected between the ions produced with non-denaturing and denaturing ESI, the denatured ions are found to be much more dense than those examined previously by drift tube mobility analysis, in which charge reduction was not employed. This indicates that Coulombic stretching is typically what leads to non-compact ions in the gas-phase, and suggests that for gas phase

  3. Application of transient analysis methodology to quantify thermal performance of heat exchangers

    SciTech Connect

    Rampall, I.; Singh, K.P.; Soler, A.I.; Scott, B.H.

    1997-10-01

    A transient testing technique is developed to evaluate the thermal performance of industrial-scale heat exchangers. A Galerkin-based numerical method with a choice of spectral basis elements to account for spatial temperature variations in heat exchangers is developed to solve the transient heat exchanger model equations. Testing a heat exchanger in the transient state may be the only viable alternative where conventional steady-state testing procedures are impossible or infeasible. For example, this methodology is particularly suited to the determination of apparent fouling levels in component cooling water system heat exchangers in nuclear power plants. The heat load on these so-called component coolers under steady-state conditions is too small to permit meaningful testing. An adequate heat load develops immediately after a reactor shutdown when the exchanger inlet temperatures are highly time-dependent. The application of the analysis methodology is illustrated with reference to an in-situ transient testing carried out at a nuclear power plant. The method, however, is applicable to any transient testing application.

  4. NASA Li/CF(x) cell problem analysis: Anion exchange chromatography analysis

    NASA Astrophysics Data System (ADS)

    Bytella, Joseph

    1991-05-01

    An analysis was made of wiper samples used to wipe down lithium/chlorine fluorine battery components and production equipment. These components and equipment were potentially exposed to thionyl chloride vapors. In the presence of moisture, thionyl chloride decomposes to sulfur dioxide and hydrogen chloride. The wiper samples were analyzed for soluble chlorides and fluorides by anion exchange chromatography. During the examination of the test chromatographs, fluoride contamination was discovered in wiper samples from the test equipment. An analytical method to determine fluoride was developed. The first 3 extracts from the potentially exposed and clean wiper samples were tested, and the total fluoride from both groups determined. A comparison of the results from both groups was made to determine the extent of fluoride contamination.

  5. NASA Li/CF(x) cell problem analysis: Anion exchange chromatography analysis

    NASA Technical Reports Server (NTRS)

    Bytella, Joseph

    1991-01-01

    An analysis was made of wiper samples used to wipe down lithium/chlorine fluorine battery components and production equipment. These components and equipment were potentially exposed to thionyl chloride vapors. In the presence of moisture, thionyl chloride decomposes to sulfur dioxide and hydrogen chloride. The wiper samples were analyzed for soluble chlorides and fluorides by anion exchange chromatography. During the examination of the test chromatographs, fluoride contamination was discovered in wiper samples from the test equipment. An analytical method to determine fluoride was developed. The first 3 extracts from the potentially exposed and clean wiper samples were tested, and the total fluoride from both groups determined. A comparison of the results from both groups was made to determine the extent of fluoride contamination.

  6. Exergy destruction analysis of a vortices generator in a gas liquid finned tube heat exchanger: an experimental study

    NASA Astrophysics Data System (ADS)

    Ghazikhani, M.; Khazaee, I.; Monazzam, S. M. S.; Takdehghan, H.

    2016-11-01

    In the present work, the effect of using different shapes of vortices generator (VG) on a gas liquid finned heat exchanger is investigated experimentally with irreversibility analysis. In this project the ambient air with mass flow rates of 0.047-0.072 kg/s is forced across the finned tube heat exchanger. Hot water with constant flow rate of 240 L/h is circulated inside heat exchanger tubes with inlet temperature range of 45-73 °C. The tests are carried out on the flat finned heat exchanger and then repeated on the VG finned heat exchanger. The results show that using the vortex generator can decrease the ratio of air side irreversibility to heat transfer (ASIHR) of the heat exchanger. Also the results show that the IASIHR is >1.05 for all air mass flow rates, which means that ASIHR for the initial heat exchanger is higher than 5 % greater than that of improved heat exchanger.

  7. Dimensional Analysis and Electric Potential Due to a Uniformly Charged Sheet

    ERIC Educational Resources Information Center

    Aghamohammadi, Amir

    2011-01-01

    Dimensional analysis, superposition principle, and continuity of electric potential are used to study the electric potential of a uniformly charged square sheet on its plane. It is shown that knowing the electric potential on the diagonal and inside the square sheet is equivalent to knowing it everywhere on the plane of the square sheet. The…

  8. Detailed Analysis and Control Issues of Homogeneous Charge Compression Ignition (HCCI)

    SciTech Connect

    Aceves, Salvador M.; Flowers, Daniel L.; Martinez-Frias, Joel; Espinosa-Loza, Francisco; Dibble, Robert

    2002-08-25

    Homogeneous charge compression ignition (HCCI) is a new combustion technology that may develop as an alternative to diesel engines with high efficiency and low NOx and particulate matter emissions. This paper describes the HCCI research activities being currently pursued at Lawrence Livermore National Laboratory and at the University of California Berkeley. Current activities include analysis as well as experimental work.

  9. Automated Techniques for Rapid Analysis of Momentum Exchange Devices

    DTIC Science & Technology

    2013-12-01

    intuitive feel for how objects react on Earth . This intuition does not translate to objects in space because the motive forces used on Earth are not...will create a cone, an effect commonly called nutation [5, pg.53]. This makes the momentum vector time dependent and complicates the analysis

  10. Calorimetry Sample Exchange analysis of data report for October--December, 1988

    SciTech Connect

    Lyons, J.E.

    1989-12-31

    The goals of the Calorimetry Sample Exchange Program are to: discuss measurement differences; review and improve analytical measurements and methods; discuss new measurement capabilities; provide data to DOE on measurement capabilities to evaluate shipper-receiver differences; provide characterized or standard materials as necessary for exchange participants; and provide a measurement control program for plutonium analysis. A sample of PuO{sub 2} powder is available at each participating site for NDA measurement, including either or both calorimetry and high-resolution gamma-ray spectroscopy, the elements which are typically combined to provide a calorimetric assay of plutonium. The facilities measure the sample as frequently and to the level of precision which they desire, and then submit the data to the Exchange for analysis. Statistical tests are used to evaluate the data and to determine if there are significant differences from accepted values for the exchange sample or from data previously reported by that facility. This information is presented, in the form of a quarterly report, intended for use by Exchange participants in measurement control programs, or to indicate when bias corrections may be appropriate. No attempt, however, has been made to standardize methods or frequency of data collection, calibration, or operating procedures. Direct comparisons between laboratories may, therefore, be misleading since data have not bee collected to the same precision or for the same time periods. The six participating laboratories are Lawrence Livermore, Los Alamos, MRC-Mound, Westinghouse Hanford, Rocky Flats, and Savannah River.

  11. Detrended cross-correlation analysis on RMB exchange rate and Hang Seng China Enterprises Index

    NASA Astrophysics Data System (ADS)

    Ruan, Qingsong; Yang, Bingchan; Ma, Guofeng

    2017-02-01

    In this paper, we investigate the cross-correlations between the Hang Seng China Enterprises Index and RMB exchange markets on the basis of a cross-correlation statistic test and multifractal detrended cross-correlation analysis (MF-DCCA). MF-DCCA has, at best, serious limitations for most of the signals describing complex natural processes and often indicates multifractal cross-correlations when there are none. In order to prevent these false multifractal cross-correlations, we apply MFCCA to verify the cross-correlations. Qualitatively, we find that the return series of the Hang Seng China Enterprises Index and RMB exchange markets were, overall, significantly cross-correlated based on the statistical analysis. Quantitatively, we find that the cross-correlations between the stock index and RMB exchange markets were strongly multifractal, and the multifractal degree of the onshore RMB exchange markets was somewhat larger than the offshore RMB exchange markets. Moreover, we use the absolute return series to investigate and confirm the fact of multifractality. The results from the rolling windows show that the short-term cross-correlations between volatility series remain high.

  12. Proton exchange membrane fuel cell conductivity and system analysis

    NASA Astrophysics Data System (ADS)

    Han, Qian

    A fuel cell converts chemical energy to electrical energy. It is a device that uses the electrochemical reaction of hydrogen and an oxidant, to produce electrical energy silently, without combustion. The role of the electrolyte in a PEM fuel cell is played by a proton exchange membrane. NafionRTM and its derivatives are the most widely used and studied polymers. Percolation theory holds a key to understanding the behavior of these polymers. In this dissertation, the percolation phenomenon was first simulated for the thermal conductivity of a representative polymer material. The simulation program was based on the finite element method, using Ansys software, which not only simplifies the method of calculation, but also increases the accuracy of the result. Ansys programs were developed to study the effects of matrix thickness, filler particle volume percentage, and various conductivities of the base material and filler particles. Comparison with existing experimental results and other models showed that the results from the finite element method were more accurate than the other models, especially the three-dimensional model. A similar Ansys program was utilized to predict the percolation threshold for the polymer electric conductivity, and its relationship with extra water content over the studied temperature range. The result showed that the percolation threshold varied with temperature and is in the range of 22% to 26% at room temperature, and matches the experimental data within 10% error margin. A natural gas fuel cell (NGFC) is a direct-energy conversion system which uses natural gas as the hydrogen carrier. A parametric model was developed to predict the overall system performance of a natural-gas-fueled PEM fuel cell system sized for a residential or small commercial building. The model accounts for interactions between various operating parameters: fuel consumption, air and water requirements, power produced, and heat and waste water discharge. For example

  13. SCAP - a Shaped Charge Analysis Program: user's manual for SCAP 1. 0

    SciTech Connect

    Robinson, A.C.

    1985-04-01

    The basic modeling and format for a shaped charge analysis program, SCAP, is described. The code models the motion of liner elements due to explosive loading, jet formation, jet breakup and target penetration through application of a series of analytical approximations. The structure of the code is intended to provide flexibility in shaped charge device and target configurations and in modeling techniques. The code is designed for interactive use and produces both printed and plotted output. Examples of code output are given and compared with experimental data. 19 refs., 13 figs.

  14. Analysis and test of a breadboard cryogenic hydrogen/Freon heat exchanger

    NASA Technical Reports Server (NTRS)

    Desjardins, L. F.; Hooper, J.

    1973-01-01

    System studies required to verify a tube-in-tube cryogenic heat exchanger as optimum for the space shuttle mission are described. Design of the optimum configuration, which could be fabricated from commercially available hardware, is discussed. Finally, testing of the proposed configuration with supercritical hydrogen and Freon 21 is discussed and results are compared with thermal and dynamic analysis.

  15. Quantitative Synthesis and Component Analysis of Single-Participant Studies on the Picture Exchange Communication System

    ERIC Educational Resources Information Center

    Tincani, Matt; Devis, Kathryn

    2011-01-01

    The "Picture Exchange Communication System" (PECS) has emerged as the augmentative communication intervention of choice for individuals with autism spectrum disorder (ASD), with a supporting body of single-participant studies. This report describes a meta-analysis of 16 single-participant studies on PECS with percentage of nonoverlapping data…

  16. Advanced view factor analysis method for radiation exchange

    NASA Astrophysics Data System (ADS)

    Park, Sookuk; Tuller, Stanton E.

    2014-03-01

    A raster-based method for determining complex view factor patterns is presented (HURES model). The model uses Johnson and Watson's view factor analysis method for fisheye lens photographs. The entire sphere is divided into 13 different view factors: open sky; sunny and shaded building walls, vegetation (trees) and ground surfaces above and below 1.2 m from the ground surface. The HURES model gave reasonable view factor results in tests at two urban study sites on summer days: downtown Nanaimo, B.C., Canada and Changwon, Republic of Korea. HURES gave better estimates of open sky view factors determined from fisheye lens photographs than did ENVI-met 3.1 and RayMan Pro. However, all three models underestimated sky view factor. For view factor analysis in outdoor urban areas, the 10° interval of rotation angle at 100 m distance of annuli will be suitable settings for three-dimensional computer simulations. The HURES model can be used for the rapid determination of complex view factor patterns which facilitates the analysis of their effects. Examples of how differing view factor patterns can affect human thermal sensation indices are given. The greater proportion of sunny view factors increased the computed predicted mean vote (PMV) by 1.3 on the sunny side of the street compared with the shady side during mid-morning in downtown Nanaimo. In another example, effects of differing amounts of open sky, sunny ground, sunny buildings and vegetation combined to produce only slight differences in PMV and two other human thermal sensation indices, PET and UTCI.

  17. Analysis of incomplete charge transfer effects in a CMOS image sensor

    NASA Astrophysics Data System (ADS)

    Liqiang, Han; Suying, Yao; Jiangtao, Xu; Chao, Xu; Zhiyuan, Gao

    2013-05-01

    A method to judge complete charger transfer is proposed for a four-transistor CMOS image sensor with a large pixel size. Based on the emission current theory, a qualitative photoresponse model is established to the preliminary prediction. Further analysis of noise for incomplete charge transfer predicts the noise variation. The test pixels were fabricated in a specialized 0.18 μm CMOS image sensor process and two different processes of buried N layer implantation are compared. The trend prediction corresponds with the test results, especially as it can distinguish an unobvious incomplete charge transfer. The method helps us judge whether the charge transfer time satisfies the requirements of the readout circuit for the given process especially for pixels of a large size.

  18. Global analysis of proton elastic form factor data with two-photon exchange corrections

    SciTech Connect

    J. Arrington; W. Melnitchouk; J. A. Tjon

    2007-09-01

    We use the world's data on elastic electron-proton scattering and calculations of two-photon exchange effects to extract corrected values of the proton's electric and magnetic form factors over the full Q^2 range of the existing data. Our analysis combines the corrected Rosenbluth cross section and polarization transfer data, and is the first extraction of G_Ep and G_Mp including explicit two-photon exchange corrections and their associated uncertainties. In addition, we examine the angular dependence of the corrected cross sections, and discuss the possible nonlinearities of the cross section as a function of epsilon.

  19. Steady state thermal radiation analysis between the TOPAZ-II radiator and a heat exchanger

    SciTech Connect

    Maveety, J.G.; Wold, S.K.

    1995-12-31

    In this study the authors investigate the feasibility and efficiency of coupling a single-pass heat exchanger to the TOPAZ-II space power system operating at steady state conditions. A first and second law analysis was performed in order to determine the optimal operating conditions which minimize the pumping power and maximize the flow exergy of the working fluid. The results of this study show that (1) the space power system is basically unaffected by the addition of this heat exchanger and (2) as much as 60% of the availability is destroyed by irreversibilities while operating at optimal flow conditions.

  20. Longitudinal hydraulic analysis of river-aquifer exchanges

    USGS Publications Warehouse

    Konrad, C.P.

    2006-01-01

    A longitudinal analysis of transient flow between a river and an underlying aquifer is developed to calculate flow rates between the river and the aquifer and the location of groundwater seepage into the river as it changes over time. Two flow domains are defined in the analysis: an upstream domain of fluvial recharge, where water flows vertically from the river into the unsaturated portion of the aquifer and horizontally in saturated parts of the aquifer, and a downstream domain of groundwater seepage to the river, where groundwater flows parallel to the underlying impermeable base. The river does not necessarily penetrate completely through the aquifer. A one-dimensional, unsteady flow equation is derived from mass conservation, Darcy's law, and the geometry of the river-aquifer system to calculate the water table position and the groundwater seepage rate into the river. Models based on numerical and analytical solutions of the flow equation were applied to a reach of the Methow River in north central Washington. The calibrated models simulated groundwater seepage with a root-mean-square error less than 5% of the mean groundwater seepage rates for three low-flow evaluation periods. The analytical model provides a theoretical basis for a nonlinear exponential base flow recession generated by a draining aquifer, but not an explicit functional form for the recession. Unlike cross-sectional approaches, the longitudinal approach allows the analysis of the length and location of groundwater seepage to a river, which have important ecological implications in many rivers. In the numerical simulations, the length of the groundwater seepage varied seasonally by about 4 km and the upstream boundary of groundwater seepage was within 689 m of its location at a stream gage on 9 September 2001 and within 91 m of its location on 6 October 2002. To demonstrate its utility in ecological applications, the numerical model was used to calculate differences in length of groundwater

  1. Charge exchange recombination spectroscopy on a diagnostic hydrogen beam—measuring impurity rotation and radial electric field at the tokamak TEXTOR

    NASA Astrophysics Data System (ADS)

    Coenen, J. W.; Schweer, B.; Clever, M.; Freutel, S.; Schmitz, O.; Stoschus, H.; Samm, U.; Unterberg, B.

    2010-07-01

    In this work we present an overview on the charge exchange recombination spectroscopy (CXRS) diagnostic operated with the modulated diagnostic hydrogen beam at the tokamak TEXTOR. The diagnostic setup combines two observation systems used for the measurement of the poloidal (vpol) and the toroidal (vtor) ion velocity component. At TEXTOR a differential Doppler spectroscopy approach (accurate absolute rotation scale) is combined with the high intensity and spatial resolution of a direct imaging system necessary for accurate poloidal rotation measurements on a shot-by-shot basis. This setup allows the full utilization of a 2D CCD detector in the spectral and radial direction. In the case of the poloidal system this allows spatial resolution in the range of mm to cm depending on the intensity requirements for the velocity. The toroidal system comprises a fibre-optic array. The combination of the two measurements with a low-power diagnostic beam can in principle be operated during any available heating scenario without interfering with the discharge. Time resolution is limited by the necessary averaging process; typically a stable plateau of 3 s during a TETXOR pulse is used. The TEXTOR tokamak has the ability to apply momentum input with two tangential neutral beam heating injectors, allowing for measurements under various heating and momentum input scenarios. With the presented diagnostic half the plasma minor radius at a spatial resolution of {\\sim} 1\\,\\rm cm is covered. With the CVI line at 529.053 nm an accuracy of 0.7\\, \\rm km\\,s^{-1} for the poloidal and ~5 \\rm km\\,s^{-1} for the toroidal system is given. The temperature is measured with an accuracy of a few eV. The presented work illustrates the capability of the system during a toroidal momentum scan, showing the self-consistent determination of the radial electric field from experimental CXRS data based on the radial force balance.

  2. Multifractal analysis of managed and independent float exchange rates

    NASA Astrophysics Data System (ADS)

    Stošić, Darko; Stošić, Dusan; Stošić, Tatijana; Stanley, H. Eugene

    2015-06-01

    We investigate multifractal properties of daily price changes in currency rates using the multifractal detrended fluctuation analysis (MF-DFA). We analyze managed and independent floating currency rates in eight countries, and determine the changes in multifractal spectrum when transitioning between the two regimes. We find that after the transition from managed to independent float regime the changes in multifractal spectrum (position of maximum and width) indicate an increase in market efficiency. The observed changes are more pronounced for developed countries that have a well established trading market. After shuffling the series, we find that the multifractality is due to both probability density function and long term correlations for managed float regime, while for independent float regime multifractality is in most cases caused by broad probability density function.

  3. Charge-density analysis using multipolar atom and spherical charge models: 2-methyl-1,3-cyclopentanedione, a compound displaying a resonance-assisted hydrogen bond.

    PubMed

    Nassour, Ayoub; Kubicki, Maciej; Wright, Jonathan; Borowiak, Teresa; Dutkiewicz, Grzegorz; Lecomte, Claude; Jelsch, Christian

    2014-04-01

    The experimental charge-density distribution in 2-methyl-1,3-cyclopentanedione in the crystal state was analyzed by synchrotron X-ray diffraction data collection at 0.33 Å resolution. The molecule in the crystal is in the enol form. The experimental electron density was refined using the Hansen-Coppens multipolar model and an alternative modeling, based on spherical atoms and additional charges on the covalent bonds and electron lone-pair sites. The crystallographic refinements, charge-density distributions, molecular electrostatic potentials, dipole moments and intermolecular interaction energies obtained from the different charge-density models were compared. The experimental results are also compared with the theoretical charge densities using theoretical structure factors obtained from periodic quantum calculations at the B3LYP/6-31G** level. A strong intermolecular O-H···O hydrogen bond connects molecules along the [001] direction. The deformation density maps show the resonance within the O=C-C=C-OH fragment and merged lone pair lobes on the hydroxyl O atom. This resonance is further confirmed by the analysis of charges and topology of the electron density.

  4. Value at risk estimation with entropy-based wavelet analysis in exchange markets

    NASA Astrophysics Data System (ADS)

    He, Kaijian; Wang, Lijun; Zou, Yingchao; Lai, Kin Keung

    2014-08-01

    In recent years, exchange markets are increasingly integrated together. Fluctuations and risks across different exchange markets exhibit co-moving and complex dynamics. In this paper we propose the entropy-based multivariate wavelet based approaches to analyze the multiscale characteristic in the multidimensional domain and improve further the Value at Risk estimation reliability. Wavelet analysis has been introduced to construct the entropy-based Multiscale Portfolio Value at Risk estimation algorithm to account for the multiscale dynamic correlation. The entropy measure has been proposed as the more effective measure with the error minimization principle to select the best basis when determining the wavelet families and the decomposition level to use. The empirical studies conducted in this paper have provided positive evidence as to the superior performance of the proposed approach, using the closely related Chinese Renminbi and European Euro exchange market.

  5. Least-squares smoothing of direct-exchange in zonal analysis

    NASA Astrophysics Data System (ADS)

    Larsen, M. E.; Howell, J. R.

    1984-08-01

    The method of Lagrange-multipliers has been used to determine adjustments to be made to a set of direct-exchange areas used in zonal analysis of a radiating enclosure containing a participating medium. The resulting adjusted direct-exchange areas satisfy conservation laws and the condition that an objective function be minimized. The objective function allows weights to be assigned to each adjustment. The solution of a set of linear algebraic equations yields the required adjustments. The method is well-suited for adjusting a set of direct-exchange areas which are assumed to include random inaccuracies. Other adjustment techniques in the literature are discussed and compared, and application of the present method is demonstrated.

  6. Least-squares smoothing of direct-exchange areas in zonal analysis

    SciTech Connect

    Larsen, M.E.; Howell, J.R.

    1984-01-01

    The method of Lagrange-multipliers has been used to determine adjustments to be made to a set of direct-exchange areas used in zonal analysis of a radiating enclosure containing a participating medium. The resulting adjusted direct-exchange areas satisfy conservation laws and the condition that an objective function be minimized. The objective function allows weights to be assigned to each adjustment. The solution of a set of linear algebraic equations yields the required adjustments. The method is well-suited for adjusting a set of direct-exchange areas which are assumed to include random inaccuracies. Other adjustment techniques in the literature are discussed and compared, and application of the present method is demonstrated.

  7. Multifractal detrended Cross Correlation Analysis of Foreign Exchange and SENSEX fluctuation in Indian perspective

    NASA Astrophysics Data System (ADS)

    Dutta, Srimonti; Ghosh, Dipak; Chatterjee, Sucharita

    2016-12-01

    The manuscript studies autocorrelation and cross correlation of SENSEX fluctuations and Forex Exchange Rate in respect to Indian scenario. Multifractal detrended fluctuation analysis (MFDFA) and multifractal detrended cross correlation analysis (MFDXA) were employed to study the correlation between the two series. It was observed that the two series are strongly cross correlated. The change of degree of cross correlation with time was studied and the results are interpreted qualitatively.

  8. Cumulant analysis of charge recombination kinetics in bacterial reaction centers reconstituted into lipid vesicles.

    PubMed Central

    Palazzo, G; Mallardi, A; Giustini, M; Berti, D; Venturoli, G

    2000-01-01

    The kinetics of charge recombination between the primary photoxidized donor (P(+)) and the secondary reduced quinone acceptor (Q(B)(-)) have been studied in reaction centers (RCs) from the purple photosynthetic bacterium Rhodobacter sphaeroides incorporated into lecithin vesicles containing large ubiquinone pools over the temperature range 275 K exchange of quinone between different vesicles is negligible; 2) the exchange of quinone between the Q(B) site of the RC and the quinone pool within each single vesicle is faster than the return of the electron from the primary reduced acceptor Q(A)(-) to P(+); 3) the size polydispersity of proteoliposomes and the distribution of quinone molecules among them result in a quinone concentration distribution function, P(Q). The first and second moments of P(Q) have been evaluated from the size distribution of proteoliposomes probed by quasi-elastic light scattering (mean radius, = (50 +/- 15) nm). Following these premises, we describe the kinetics of P(+)Q(B)(-) recombination with a truncated cumulant expansion and relate it to P(Q) and to the free energy changes for Q(A)(-)Q(B) --> Q(A)Q(B)(-) electron transfer (DeltaG(AB)(o)) and for quinone binding (DeltaG(bind)(o)) at Q(B). The model accounts well for the temperature and quinone dependence of the charge recombination kinetics, yielding DeltaG(AB)(o) = -7.67 +/- 0.05 kJ mol(-1) and DeltaG(bind)(o) = -14.6 +/- 0.6 kJ mol(-1) at 298 K. PMID:10968981

  9. A meta-analysis of leaf gas exchange and water status responses to drought

    NASA Astrophysics Data System (ADS)

    Yan, Weiming; Zhong, Yangquanwei; Shangguan, Zhouping

    2016-02-01

    Drought is considered to be one of the most devastating natural hazards, and it is predicted to become increasingly frequent and severe in the future. Understanding the plant gas exchange and water status response to drought is very important with regard to future climate change. We conducted a meta-analysis based on studies of plants worldwide and aimed to determine the changes in gas exchange and water status under different drought intensities (mild, moderate and severe), different photosynthetic pathways (C3 and C4) and growth forms (herbs, shrubs, trees and lianas). Our results were as follows: 1) drought negatively impacted gas exchange and water status, and stomatal conductance (gs) decreased more than other physiological traits and declined to the greatest extent in shrubs and C3 plants. Furthermore, C4 plants had an advantage compared to C3 plants under the same drought conditions. 2) The decrease in gs mainly reduced the transpiration rate (Tr), and gs could explain 55% of the decrease in the photosynthesis (A) and 74% of the decline in Tr. 3). Finally, gas exchange showed a close relationship with the leaf water status. Our study provides comprehensive information about the changes in plant gas exchange and water status under drought.

  10. Large Scale Asynchronous and Distributed Multi-Dimensional Replica Exchange Molecular Simulations and Efficiency Analysis

    PubMed Central

    Xia, Junchao; Flynn, William F.; Gallicchio, Emilio; Zhang, Bin W.; He, Peng; Tan, Zhiqiang; Levy, Ronald M.

    2015-01-01

    We describe methods to perform replica exchange molecular dynamics (REMD) simulations asynchronously (ASyncRE). The methods are designed to facilitate large scale REMD simulations on grid computing networks consisting of heterogeneous and distributed computing environments as well as on homogeneous high performance clusters. We have implemented these methods on NSF XSEDE clusters and BOINC distributed computing networks at Temple University, and Brooklyn College at CUNY. They are also being implemented on the IBM World Community Grid. To illustrate the methods we have performed extensive (more than 60 microseconds in aggregate) simulations for the beta-cyclodextrin-heptanoate host-guest system in the context of one and two dimensional ASyncRE and we used the results to estimate absolute binding free energies using the Binding Energy Distribution Analysis Method (BEDAM). We propose ways to improve the efficiency of REMD simulations: these include increasing the number of exchanges attempted after a specified MD period up to the fast exchange limit, and/or adjusting the MD period to allow sufficient internal relaxation within each thermodynamic state. Although ASyncRE simulations generally require long MD periods (> picoseconds) per replica exchange cycle to minimize the overhead imposed by heterogeneous computing networks, we found that it is possible to reach an efficiency similar to conventional synchronous REMD, by optimizing the combination of the MD period and the number of exchanges attempted per cycle. PMID:26149645

  11. Large-scale asynchronous and distributed multidimensional replica exchange molecular simulations and efficiency analysis.

    PubMed

    Xia, Junchao; Flynn, William F; Gallicchio, Emilio; Zhang, Bin W; He, Peng; Tan, Zhiqiang; Levy, Ronald M

    2015-09-05

    We describe methods to perform replica exchange molecular dynamics (REMD) simulations asynchronously (ASyncRE). The methods are designed to facilitate large scale REMD simulations on grid computing networks consisting of heterogeneous and distributed computing environments as well as on homogeneous high-performance clusters. We have implemented these methods on NSF (National Science Foundation) XSEDE (Extreme Science and Engineering Discovery Environment) clusters and BOINC (Berkeley Open Infrastructure for Network Computing) distributed computing networks at Temple University and Brooklyn College at CUNY (the City University of New York). They are also being implemented on the IBM World Community Grid. To illustrate the methods, we have performed extensive (more than 60 ms in aggregate) simulations for the beta-cyclodextrin-heptanoate host-guest system in the context of one- and two-dimensional ASyncRE, and we used the results to estimate absolute binding free energies using the binding energy distribution analysis method. We propose ways to improve the efficiency of REMD simulations: these include increasing the number of exchanges attempted after a specified molecular dynamics (MD) period up to the fast exchange limit and/or adjusting the MD period to allow sufficient internal relaxation within each thermodynamic state. Although ASyncRE simulations generally require long MD periods (>picoseconds) per replica exchange cycle to minimize the overhead imposed by heterogeneous computing networks, we found that it is possible to reach an efficiency similar to conventional synchronous REMD, by optimizing the combination of the MD period and the number of exchanges attempted per cycle.

  12. A meta-analysis of leaf gas exchange and water status responses to drought

    PubMed Central

    Yan, Weiming; Zhong, Yangquanwei; Shangguan, Zhouping

    2016-01-01

    Drought is considered to be one of the most devastating natural hazards, and it is predicted to become increasingly frequent and severe in the future. Understanding the plant gas exchange and water status response to drought is very important with regard to future climate change. We conducted a meta-analysis based on studies of plants worldwide and aimed to determine the changes in gas exchange and water status under different drought intensities (mild, moderate and severe), different photosynthetic pathways (C3 and C4) and growth forms (herbs, shrubs, trees and lianas). Our results were as follows: 1) drought negatively impacted gas exchange and water status, and stomatal conductance (gs) decreased more than other physiological traits and declined to the greatest extent in shrubs and C3 plants. Furthermore, C4 plants had an advantage compared to C3 plants under the same drought conditions. 2) The decrease in gs mainly reduced the transpiration rate (Tr), and gs could explain 55% of the decrease in the photosynthesis (A) and 74% of the decline in Tr. 3). Finally, gas exchange showed a close relationship with the leaf water status. Our study provides comprehensive information about the changes in plant gas exchange and water status under drought. PMID:26868055

  13. A quantitative analysis of municipal solid waste disposal charges in China.

    PubMed

    Wu, Jian; Zhang, Weiqian; Xu, Jiaxuan; Che, Yue

    2015-03-01

    Rapid industrialization and economic development have caused a tremendous increase in municipal solid waste (MSW) generation in China. China began implementing a policy of MSW disposal fees for household waste management at the end of last century. Three charging methods were implemented throughout the country: a fixed disposal fee, a potable water-based disposal fee, and a plastic bag-based disposal fee. To date, there has been little qualitative or quantitative analysis on the effectiveness of this relatively new policy. This paper provides a general overview of MSW fee policy in China, attempts to verify whether the policy is successful in reducing general waste collected, and proposes an improved charging system to address current problems. The paper presents an empirical statistical analysis of policy effectiveness derived from an environmental Kuznets curve (EKC) test on panel data of China. EKC tests on different kinds of MSW charge systems were then examined for individual provinces or cities. A comparison of existing charging systems was conducted using environmental and economic criteria. The results indicate the following: (1) the MSW policies implemented over the study period were effective in the reduction of waste generation, (2) the household waste discharge fee policy did not act as a strong driver in terms of waste prevention and reduction, and (3) the plastic bag-based disposal fee appeared to be performing well according to qualitative and quantitative analysis. Based on current situation of waste discharging management in China, a three-stage transitional charging scheme is proposed and both advantages and drawbacks discussed. Evidence suggests that a transition from a fixed disposal fee to a plastic bag-based disposal fee involving various stakeholders should be the next objective of waste reduction efforts.

  14. 2004 on Warsaw Stock Exchange via Zipf Analysis, Scatter and Lag Plots

    NASA Astrophysics Data System (ADS)

    Bachnik, W.; Chomiuk, P.; Faltynowicz, Sz.; Gawin, M.; Gorajek, W.; Kedzierski, J.; Kosk, K.; Kucharczyk, A.; Leszczynski, P.; Podsiadlo, R.; Makowiec, D.

    2005-08-01

    This paper presents the last year on Warsaw Stock Exchange (WSE) and world stock exchanges by graphical analysis: Scatter Plot, Zipf Analysis and Lag Plot of selected Polish (WIG, WIG20, WIG-BANKI, TECHWIG) and foreign (NIKKEI, DOW JONES Industrial Average) indices, and also selected companies listed on WSE. Zipf analysis proves that although, generally, holding securities was the best way to earn money in the last year, however, Zipf based strategy also could be profitable. Scatter Plots show no similarities between Polish and foreign indices, however, behaviour of Polish ones is similar. The volatility of indices and most companies was highest on Monday and lowest on Friday. Distribution of returns in continuous trading is neither Gaussian nor uniform.

  15. Educator Exchange Resource Guide.

    ERIC Educational Resources Information Center

    Garza, Cris; Rodriguez, Victor

    This resource guide was developed for teachers and administrators interested in participating in intercultural and international exchange programs or starting an exchange program. An analysis of an exchange program's critical elements discusses exchange activities; orientation sessions; duration of exchange; criteria for participation; travel,…

  16. Analysis of a compartmental model of amyloid beta production, irreversible loss and exchange in humans.

    PubMed

    Elbert, Donald L; Patterson, Bruce W; Bateman, Randall J

    2015-03-01

    Amyloid beta (Aβ) peptides, and in particular Aβ42, are found in senile plaques associated with Alzheimer's disease. A compartmental model of Aβ production, exchange and irreversible loss was recently developed to explain the kinetics of isotope-labeling of Aβ peptides collected in cerebrospinal fluid (CSF) following infusion of stable isotope-labeled leucine in humans. The compartmental model allowed calculation of the rates of production, irreversible loss (or turnover) and short-term exchange of Aβ peptides. Exchange of Aβ42 was particularly pronounced in amyloid plaque-bearing participants. In the current work, we describe in much greater detail the characteristics of the compartmental model to two distinct audiences: physician-scientists and biokineticists. For physician-scientists, we describe through examples the types of questions the model can and cannot answer, as well as correct some misunderstandings of previous kinetic analyses applied to this type of isotope labeling data. For biokineticists, we perform a system identifiability analysis and a sensitivity analysis of the kinetic model to explore the global and local properties of the model. Combined, these analyses motivate simplifications from a more comprehensive physiological model to the final model that was previously presented. The analyses clearly demonstrate that the current dataset and compartmental model allow determination with confidence a single 'turnover' parameter, a single 'exchange' parameter and a single 'delay' parameter. When combined with CSF concentration data for the Aβ peptides, production rates may also be obtained.

  17. Ion exchange separation of chromium from natural water matrix for stable isotope mass spectrometric analysis

    USGS Publications Warehouse

    Ball, J.W.; Bassett, R.L.

    2000-01-01

    A method has been developed for separating the Cr dissolved in natural water from matrix elements and determination of its stable isotope ratios using solid-source thermal-ionization mass spectrometry (TIMS). The separation method takes advantage of the existence of the oxidized form of Cr as an oxyanion to separate it from interfering cations using anion-exchange chromatography, and of the reduced form of Cr as a positively charged ion to separate it from interfering anions such as sulfate. Subsequent processing of the separated sample eliminates residual organic material for application to a solid source filament. Ratios for 53Cr/52Cr for National Institute of Standards and Technology Standard Reference Material 979 can be measured using the silica gel-boric acid technique with a filament-to-filament standard deviation in the mean 53Cr/52Cr ratio for 50 replicates of 0.00005 or less. (C) 2000 Elsevier Science B.V. All rights reserved.

  18. Surface charge fine tuning of reversed-phase/weak anion-exchange type mixed-mode stationary phases for milder elution conditions.

    PubMed

    Zimmermann, Aleksandra; Horak, Jeannie; Sánchez-Muñoz, Orlando L; Lämmerhofer, Michael

    2015-08-28

    A series of new mixed-mode reversed-phase/weak anion-exchange (RP/WAX) phases have been synthesized by immobilization of N-undecenyl-3-α-aminotropane onto thiol-modified silica gel by thiol-ene click chemistry and subsequent introduction of acidic thiol-endcapping functionalities of different type and surface densities. Click chemistry allowed to adjust a controlled surface concentration of the RP/WAX ligand in such a way that a sufficient quantity of residual thiols remained unmodified which have been capped by thiol click with either 3-butenoic acid or allylsulfonic acid as co-ligands. In another embodiment, performic acid oxidation of N-undecenyl-3-α-aminotropane-derivatized thiol-modified silica gave a RP/WAX phase with high density of sulfonic acid end-capping groups. ζ-Potential determinations confirmed the fine-tuned pI of these mixed-mode stationary phases which was shifted from 9.5 to 8.2, 7.8, and 6.5 with 3-butenoic acid and allylsulfonic acid end-capping as well as performic acid oxidation. For acidic solutes, the co-ionic endcapping leads to strongly reduced retention times and clearly allowed elution of these analytes under lower ionic strength thus milder elution conditions. In spite of the acidic endcapping, the new mixed-mode phases maintained their hydrophobic and anion-exchange selectivity as well as their multimodal nature featuring RP and HILIC elution domains at acetonitrile percentages below and above 50%, respectively. Column classification by principal component analysis of an extended retention map in comparison to a set of polar commercial and in-house synthesized stationary phases confirmed complementarity of the new mixed-mode phases with respect to HILIC, polar RP, amino and commercial mixed-mode phases.

  19. A Simple Geotracer Compositional Correlation Analysis Reveals Oil Charge and Migration Pathways

    PubMed Central

    Yang, Yunlai; Arouri, Khaled

    2016-01-01

    A novel approach, based on geotracer compositional correlation analysis is reported, which reveals the oil charge sequence and migration pathways for five oil fields in Saudi Arabia. The geotracers utilised are carbazoles, a family of neutral pyrrolic nitrogen compounds known to occur naturally in crude oils. The approach is based on the concept that closely related fields, with respect to filling sequence, will show a higher carbazole compositional correlation, than those fields that are less related. That is, carbazole compositional correlation coefficients can quantify the charge and filling relationships among different fields. Consequently, oil migration pathways can be defined based on the established filling relationships. The compositional correlation coefficients of isomers of C1 and C2 carbazoles, and benzo[a]carbazole for all different combination pairs of the five fields were found to vary extremely widely (0.28 to 0.94). A wide range of compositional correlation coefficients allows adequate differentiation of separate filling relationships. Based on the established filling relationships, three distinct migration pathways were inferred, with each apparently being charged from a different part of a common source kitchen. The recognition of these charge and migration pathways will greatly aid the search for new accumulations. PMID:26965479

  20. Analysis of Charge Carrier Transport in Organic Photovoltaic Thin Films and Nanoparticle Assemblies

    NASA Astrophysics Data System (ADS)

    Han, Xu; Maroudas, Dimitrios

    2014-03-01

    We present a systematic analysis of charge carrier transport in organic photovoltaic (OPV) devices based on phenomenological charge carrier transport models. These transient drift-diffusion-reaction models describe electron and hole transport and their trapping, detrapping, and recombination self-consistently with Poisson's equation for the electric field in the active layer. We predict transient currents in devices with active layers composed of P3HT, PCBM, and PBTDV polymers, as well as donor-acceptor blends. The propensity of the material to generate charge, zero-field carrier mobilities, as well as trapping, detrapping, and recombination rate coefficients are determined by fitting the modeling predictions to experimental data of photocurrent evolution. We have investigated effects of material structure and morphology by comparing the fitting outcomes for active layers consisting of both thin films and nanoparticle assemblies. We have also analyzed the effect on charge carrier transport of nanoparticle surface characteristics, as well as of thermal annealing of both thin-film and nanoparticle-assembly active layers. The model predictions provide valuable input toward synthesis of new nanoparticle assemblies that lead to improved OPV device performance.

  1. A Simple Geotracer Compositional Correlation Analysis Reveals Oil Charge and Migration Pathways

    NASA Astrophysics Data System (ADS)

    Yang, Yunlai; Arouri, Khaled

    2016-03-01

    A novel approach, based on geotracer compositional correlation analysis is reported, which reveals the oil charge sequence and migration pathways for five oil fields in Saudi Arabia. The geotracers utilised are carbazoles, a family of neutral pyrrolic nitrogen compounds known to occur naturally in crude oils. The approach is based on the concept that closely related fields, with respect to filling sequence, will show a higher carbazole compositional correlation, than those fields that are less related. That is, carbazole compositional correlation coefficients can quantify the charge and filling relationships among different fields. Consequently, oil migration pathways can be defined based on the established filling relationships. The compositional correlation coefficients of isomers of C1 and C2 carbazoles, and benzo[a]carbazole for all different combination pairs of the five fields were found to vary extremely widely (0.28 to 0.94). A wide range of compositional correlation coefficients allows adequate differentiation of separate filling relationships. Based on the established filling relationships, three distinct migration pathways were inferred, with each apparently being charged from a different part of a common source kitchen. The recognition of these charge and migration pathways will greatly aid the search for new accumulations.

  2. Rapid quantitative analysis of monoclonal antibody heavy and light chain charge heterogeneity

    PubMed Central

    Vanam, Ram P; Schneider, Michael A; Marlow, Michael S

    2015-01-01

    An alternative method to traditional 2-dimensional gel electrophoresis (2D-PAGE) and its application in characterizing the inherent charge heterogeneity of chromatographically isolated monoclonal antibody heavy and light chains is described. This method, referred to as ChromiCE, utilizes analytical size-exclusion chromatography (SEC), performed under reducing and denaturing conditions, followed by imaged capillary isoelectric focusing (icIEF) of the chromatographically separated heavy and light chains. Under conditions suitable for the subsequent icIEF analysis, the absolute and relative SEC elution volumes of the heavy and light chains were found to be highly pH dependent, a phenomenon that can be exploited in optimizing chromatographic separation. Compared to 2D-PAGE, the ChromiCE method substantially decreases the time and labor needed to complete the analysis, improves reproducibility, and provides fully quantitative assessment of charge heterogeneity. The ChromiCE methodology was applied to a set of diverse monoclonal antibodies to demonstrate suitability for quantitative charge variant analysis of heavy and light chains. A typical application of ChromiCE in extended characterization and stability studies of a purified antibody is shown. PMID:26305772

  3. Soft X-ray study of solar wind charge exchange from the Earth's magnetosphere : Suzaku observations and a future X-ray imaging mission concept

    NASA Astrophysics Data System (ADS)

    Ezoe, Y.; Ishisaki, Y.; Ohashi, T.; Ishikawa, K.; Miyoshi, Y.; Fujimoto, R.; Terada, N.; Kasahara, S.; Fujimoto, M.; Mitsuda, K.; Nishijo, K.; Noda, A.

    2013-12-01

    Soft X-ray observations of solar wind charge exchange (SWCX) emission from the Earth's magnetosphere using the Japanese X-ray astronomy satellite Suzaku are shown, together with our X-ray imaging mission concept to characterize the solar wind interaction with the magnetosphere. In recent years, the SWCX emission from the Earth's magnetosphere, originally discovered as unexplained noise during the soft X-ray all sky survey (Snowden et al. 1994), is receiving increased attention on studying geospace. The SWCX is a reaction between neutrals in exosphere and highly charged ions in the magnetosphere originated from solar wind. Robertson et al. (2005) modeled the SWCX emission as seen from an observation point 50 Re from Earth. In the resulting X-ray intensities, the magnetopause, bow shock and cusp were clearly visible. High sensitivity soft X-ray observation with CCDs onboard recent X-ray astronomy satellites enables us to resolve SWCX emission lines and investigate time correlation with solar wind as observed with ACE and WIND more accurately. Suzaku is the 5th Japanese X-ray astronomy satellite launched in 2005. The line of sight direction through cusp is observable, while constraints on Earth limb avoidance angle of other satellites often limits observable regions. Suzaku firstly detected the SWCX emission while pointing in the direction of the north ecliptic pole (Fujimoto et al. 2007). Using the Tsyganenko 1996 magnetic field model, the distance to the nearest SWCX region was estimated as 2-8 Re, implying that the line of sight direction can be through magnetospheric cusp. Ezoe et al. (2010) reported SWCX events toward the sub-solar side of the magnetosheath. These cusp and sub-solar side magnetosheath regions are predicted to show high SWCX fluxes by Robertson et al. (2005). On the other hand, Ishikawa et al. (2013) discovered a similarly strong SWCX event when the line of sight direction did not transverse these two regions. Motivated by these detections

  4. Experimental performance investigation of a shell and tube heat exchanger by exergy based sensitivity analysis

    NASA Astrophysics Data System (ADS)

    Mert, Suha Orçun; Reis, Alper

    2016-06-01

    Heat exchangers are used extensively in many industrial branches, primarily so in chemical and energy sectors. They also have important household usage as they are used in central and local heating systems. Any betterment on heat exchangers will serve greatly in preserving our already dwindling and costly energy resources. Strong approach of exergy analysis -which helps find out where the first steps should be taken in determining sources of inefficiencies and how to remedy them- will be used as a means to this end. The maximum useful work that can be harnessed from systems relationships with its environment is defined as exergy. In this study, the inlet and outlet flow rate values of fluids and temperature of hot stream both on shell and tube parts of a shell-tube heat exchange system have been inspected and their effects on the exergy efficiency of this thermal system have been analyzed. It is seen that the combination of high tube side inlet temperature, low shell side flow rate and high tube side flow rate are found to be the optimum for this experimental system with reaching 75, 65, and 32 % efficiencies respectively. Selecting operating conditions suitable to this behavior will help to increase the overall efficiency of shell-tube heat exchange systems and cause an increment in energy conservation.

  5. Topological analysis of the electronic charge density in the ethene protonation reaction catalyzed by acidic zeolite.

    PubMed

    Zalazar, M Fernanda; Peruchena, Nélida M

    2007-08-16

    In the present work, the distribution of the electronic charge density in the ethene protonation reaction by a zeolite acid site is studied within the framework of the density functional theory and the atoms in molecules (AIM) theory. The key electronic effects such as topological distribution of the charge density involved in the reaction are presented and discussed. The results are obtained at B3LYP/6-31G(**) level theory. Attention is focused on topological parameters such as electron density, its Laplacian, kinetic energy density, potential energy density, and electronic energy density at the bond critical points (BCP) in all bonds involved in the interaction zone, in the reactants, pi-complex, transition state, and alkoxy product. In addition, the topological atomic properties are determined on the selected atoms in the course of the reaction (average electron population, N(Omega), atomic net charge, q(Omega), atomic energy, E(Omega), atomic volume, v(Omega), and first moment of the atomic charge distribution, M(Omega)) and their changes are analyzed exhaustively. The topological study clearly shows that the ethene interaction with the acid site of the zeolite cluster, T5-OH, in the ethene adsorbed, is dominated by a strong O-H...pi interaction with some degree of covalence. AIM analysis based on DFT calculation for the transition state (TS) shows that the hydrogen atom from the acid site in the zeolitic fragment is connected to the carbon atom by a covalent bond with some contribution of electrostatic interaction and to the oxygen atom by closed shell interaction with some contribution of covalent character. The C-O bond formed in the alkoxy product can be defined as a weaker shared interaction. Our results show that in the transition state, the dominant interactions are partially electrostatic and partially covalent in nature, in which the covalent contribution increases as the concentration and accumulation of the charge density along the bond path between

  6. A common neighbor analysis of crystallization kinetics and excess entropy of charged spherical colloids

    NASA Astrophysics Data System (ADS)

    Urrutia Bañuelos, Efraín; Contreras Aburto, Claudio; Maldonado Arce, Amir

    2016-03-01

    The topological analysis tool known as the common neighbor analysis (CNA) is used for the first time in this work to analyze crystallization kinetics and excess entropy of charge-stabilized colloidal suspensions. For this purpose, Brownian dynamics computer simulations are implemented to investigate the crystallization kinetics of homogeneously melted colloidal crystals that are composed of hard-core-screened-Coulomb interacting particles. The results are in agreement with recent static structure factor measurements that could indicate the presence of icosahedral units in the metastable melt, and with the fact that weakly screened charged colloids crystallize into body-centered-cubic (bcc) ordering. A two-step crystallization pathway is found, in which the population of bcc-subunit CNA-pairs satisfactorily obeys a Verhulst model. Moreover, the CNA helped to unveil that the excess entropy obeys a quasi-universal functional form, relating the behavior of colloidal, molecular, and metallic liquid systems. The work contributes to the scientific understanding of the crystallization pathway of charged colloids, and to the development of new ways to assess the degree of crystalline order, starting from the excess entropy.

  7. A common neighbor analysis of crystallization kinetics and excess entropy of charged spherical colloids.

    PubMed

    Urrutia Bañuelos, Efraín; Contreras Aburto, Claudio; Maldonado Arce, Amir

    2016-03-07

    The topological analysis tool known as the common neighbor analysis (CNA) is used for the first time in this work to analyze crystallization kinetics and excess entropy of charge-stabilized colloidal suspensions. For this purpose, Brownian dynamics computer simulations are implemented to investigate the crystallization kinetics of homogeneously melted colloidal crystals that are composed of hard-core-screened-Coulomb interacting particles. The results are in agreement with recent static structure factor measurements that could indicate the presence of icosahedral units in the metastable melt, and with the fact that weakly screened charged colloids crystallize into body-centered-cubic (bcc) ordering. A two-step crystallization pathway is found, in which the population of bcc-subunit CNA-pairs satisfactorily obeys a Verhulst model. Moreover, the CNA helped to unveil that the excess entropy obeys a quasi-universal functional form, relating the behavior of colloidal, molecular, and metallic liquid systems. The work contributes to the scientific understanding of the crystallization pathway of charged colloids, and to the development of new ways to assess the degree of crystalline order, starting from the excess entropy.

  8. Charge structure analysis of a severe hailstorm with predominantly positive cloud-to-ground lightning

    NASA Astrophysics Data System (ADS)

    Pineda, Nicolau; Rigo, Tomeu; Montanyà, Joan; van der Velde, Oscar A.

    2016-09-01

    The present study makes use of cloud-to-ground lightning, three-dimensional mapping from a Lightning Mapping Array and Doppler C-band radar observations to analyze the lightning trends and the underlying electrical charge structure of a large-hail bearing storm that produced important damages on the local agriculture. The analysis reported an extremely active storm, evolving through distinct phases, which stood out from a multicell structure to finally become a supercell. The onset of newer regions of convective development interacting with the main cell made the charge structure to be rather complex during some stages of this long-lived hailstorm. Evidence suggests the presence of regions with the charge layer being inverted from that of normal, non-severe convective storms, producing predominantly positive cloud-to-ground lightning. The analysis also suggests that strong cloud signals were misclassified as low peak current single-stroke negative cloud-to-ground flashes, masking the predominant positive nature of the storm.

  9. Critical review of electrical conductivity measurements and charge distribution analysis of magnesium oxide

    NASA Technical Reports Server (NTRS)

    Freund, Friedemann; Freund, Minoru M.; Batllo, Francois

    1993-01-01

    The electrical conductivity sigma of MgO single crystals shows a sharp increase at 500-800 C, in particular of sigma surface, generally attributed to surface contamination. Charge Distribution Analysis (CDA), a new technique providing information on fundamental properties that was previously unavailable, allows for the determination of surface charges, their sign and associated internal electric field. Data on 99.99% purity, arc-fusion grown MgO crystals show that mobile charge carriers start to appear in the bulk of the MgO crystals between 200 and 400 C when sigma (measured by conventional techniques) is in t he 10(exp -14) to 10(exp -16) /omega/cm range. Above 500 C, as sigma increases to 10(exp -6) to 10(exp -7)/omega/cm, more charges appear giving rise to a strong positive surface charge supported by a strong internal field. This indicates that charges are generated in the bulk and diffuse to the surface by an internally controlled process. On the basis of their positive sign they are identified as holes (defect electrons). Because of the low cation content of these very pure MgO crystals, theses holes cannnot be associated with transition metal impurties. Instead, they are associated with the O(2-) sublattice, e.g. consist of O(-) states or positive holes. This conclusion is supported by magnetic susceptibility data showing the appearance of 1000 +/- 500 ppm paramagnetic species between 200-500 C. The magnetic data are consistent with strongly coupled, diamagnetic O(-) pairs below 200-500 C, chemically equivalent to peroxy anions, O2(2-), and probably associated with cation vacancies in the MgO matrix. The formation of O2(2-) in arc-fusion grown MgO crystals is very unexpected because of the highly reducing growth conditions. Their presence implies an internal redox reaction involving dissolved 'water' by which OH(-) pairs convert to O2(2-) plus H2 molecules. This redox conversion is supported by mass spectroscopic measurements of the H2 release from highly

  10. Analysis of full charge reconstruction algorithms for x-ray pixelated detectors

    SciTech Connect

    Baumbaugh, A.; Carini, G.; Deptuch, G.; Grybos, P.; Hoff, J.; Siddons, P., Maj.; Szczygiel, R.; Trimpl, M.; Yarema, R.; /Fermilab

    2011-11-01

    Existence of the natural diffusive spread of charge carriers on the course of their drift towards collecting electrodes in planar, segmented detectors results in a division of the original cloud of carriers between neighboring channels. This paper presents the analysis of algorithms, implementable with reasonable circuit resources, whose task is to prevent degradation of the detective quantum efficiency in highly granular, digital pixel detectors. The immediate motivation of the work is a photon science application requesting simultaneous timing spectroscopy and 2D position sensitivity. Leading edge discrimination, provided it can be freed from uncertainties associated with the charge sharing, is used for timing the events. Analyzed solutions can naturally be extended to the amplitude spectroscopy with pixel detectors.

  11. Analysis of Full Charge Reconstruction Algorithms for X-Ray Pixelated Detectors

    SciTech Connect

    Baumbaugh, A.; Carini, G.; Deptuch, G.; Grybos, P.; Hoff, J.; Siddons, P., Maj.; Szczygiel, R.; Trimpl, M.; Yarema, R.; /Fermilab

    2012-05-21

    Existence of the natural diffusive spread of charge carriers on the course of their drift towards collecting electrodes in planar, segmented detectors results in a division of the original cloud of carriers between neighboring channels. This paper presents the analysis of algorithms, implementable with reasonable circuit resources, whose task is to prevent degradation of the detective quantum efficiency in highly granular, digital pixel detectors. The immediate motivation of the work is a photon science application requesting simultaneous timing spectroscopy and 2D position sensitivity. Leading edge discrimination, provided it can be freed from uncertainties associated with the charge sharing, is used for timing the events. Analyzed solutions can naturally be extended to the amplitude spectroscopy with pixel detectors.

  12. Charge integration in external PIXE-PIGE for the analysis of aerosol samples

    NASA Astrophysics Data System (ADS)

    Li, X. F.; Wang, G. F.; Chu, J. H.; Yu, L. D.

    2012-10-01

    The beam current in an external-beam PIXE-PIGE is difficult to accurately measure due to ionization along the beam path in the atmosphere. Charge integration was measured using a homemade Faraday cup, and assessed by the peak area of Ar Kα X-rays, which were induced by protons near the sample. The X-ray peak integral from a thin Fe reference sample, which was positioned between the exit window and the Faraday cup, was determined to evaluate the performance of the homemade Faraday cup. Moreover, the effects of different membrane filters and samples with different elements on the beam current measurement of the aforementioned methods were studied by placing different blank films or reference standards behind a reference Mn target. The results indicated that the charge measurement of the homemade Faraday cup was reliable for external PIXE-PIGE analysis of aerosol samples.

  13. Quantum Monte Carlo analysis of a charge ordered insulating antiferromagnet: The Ti4O7 Magneli phase

    SciTech Connect

    Benali, Anouar; Shulenburger, Luke; Krogel, Jaron T.; Zhong, Xiaoling; Kent, Paul R. C.; Heinonen, Olle

    2016-06-07

    The Magneli phase Ti4O7 is an important transition metal oxide with a wide range of applications because of its interplay between charge, spin, and lattice degrees of freedom. At low temperatures, it has non-trivial magnetic states very close in energy, driven by electronic exchange and correlation interactions. We have examined three low- lying states, one ferromagnetic and two antiferromagnetic, and calculated their energies as well as Ti spin moment distributions using highly accurate Quantum Monte Carlo methods. We compare our results to those obtained from density functional theory- based methods that include approximate corrections for exchange and correlation. Our results confirm the nature of the states and their ordering in energy, as compared with density-functional theory methods. However, the energy differences and spin distributions differ. Here, a detailed analysis suggests that non-local exchange-correlation functionals, in addition to other approximations such as LDA+U to account for correlations, are needed to simultaneously obtain better estimates for spin moments, distributions, energy differences and energy gaps.

  14. Sister chromatid exchange analysis to monitor genotoxic chemicals. (Latest citations from Pollution abstracts). Published Search

    SciTech Connect

    1996-04-01

    The bibliography contains citations concerning the use of the sister chromatid exchange (SCE) analysis for toxicological studies. SCE analysis are very sensitive measures of genotoxic damage to chromosomes. SCE toxicological studies analyzing ionizing radiation, chromium compounds, styrene, paint thinner, mercury, cigarette smoke, coal dust, fuel oil, insecticides, ethylene oxide, diesel exhaust, and polychlorinated biphenyls are discussed. SCE studies using both human and animal tissue cultures are described. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  15. HDX Workbench: Software for the Analysis of H/D Exchange MS Data

    NASA Astrophysics Data System (ADS)

    Pascal, Bruce D.; Willis, Scooter; Lauer, Janelle L.; Landgraf, Rachelle R.; West, Graham M.; Marciano, David; Novick, Scott; Goswami, Devrishi; Chalmers, Michael J.; Griffin, Patrick R.

    2012-09-01

    Hydrogen/deuterium exchange mass spectrometry (HDX-MS) is an established method for the interrogation of protein conformation and dynamics. While the data analysis challenge of HDX-MS has been addressed by a number of software packages, new computational tools are needed to keep pace with the improved methods and throughput of this technique. To address these needs, we report an integrated desktop program titled HDX Workbench, which facilitates automation, management, visualization, and statistical cross-comparison of large HDX data sets. Using the software, validated data analysis can be achieved at the rate of generation. The application is available at the project home page http://hdx.florida.scripps.edu.

  16. Analysis of a membrane-based condesate recovery heat exchanger (CRX)

    NASA Technical Reports Server (NTRS)

    Newbold, D.D.

    1993-01-01

    The development of a temperature and humidity control system that can remove heat and recover water vapor is key to the development of an Environmental Control and Life Support System (ECLSS). Large quantities of water vapor must be removed from air, and this operation has proven difficult in the absense of gravity. This paper presents the modeling results from a program to develop a novel membrane-based heat exchanger known as the condensate recovery heat exchanger (CRX). This device cools and dehumidifies humid air and simultaneously recovers water-vapor condensate. In this paper, the CRX is described and the results of an analysis of the heat- and mass-transfer characteristics of the device are given.

  17. Analysis of chromite by cation-exchange using ethylenediaminetetra-acetic acid.

    PubMed

    Jawaid, M; Ingman, F

    1975-12-01

    A method for the separation and determination of five major elements in chromite ore (and chrome-bearing refractories), based on complexation of the metals with EDTA is described. After removal of silica, the cations are separated into two groups by passing the solution through a cation-exchange resin (Dowex 50W-X8, in Na-form) in the presence of an excess of the complexing agent. The optimum conditions for the separation are discussed on the basis of exchange constants that were either known or determined. The first group contains Cr and Fe, which emerge in the filtrate at pH between 1.5 and 2.1, whereas A1, Mg and Ca, which are adsorbed on the resin, form another group. Complexometric titrations are used for the subsequent determination of the cations in each group. The method is simpler and more rapid and accurate for routine analysis than the current methods.

  18. Combining ion mobility spectrometry with hydrogen-deuterium exchange and top-down MS for peptide ion structure analysis.

    PubMed

    Khakinejad, Mahdiar; Kondalaji, Samaneh Ghassabi; Maleki, Hossein; Arndt, James R; Donohoe, Gregory C; Valentine, Stephen J

    2014-12-01

    The gas-phase conformations of electrosprayed ions of the model peptide KKDDDDIIKIIK have been examined by ion mobility spectrometry (IMS) and hydrogen deuterium exchange (HDX)-tandem mass spectrometry (MS/MS) techniques. [M+4H](4+) ions exhibit two conformers with collision cross sections of 418 Å(2) and 471 Å(2). [M+3H](3+) ions exhibit a predominant conformer with a collision cross section of 340 Å(2) as well as an unresolved conformer (shoulder) with a collision cross section of ~367 Å(2). Maximum HDX levels for the more compact [M+4H](4+) ions and the compact and partially-folded [M+3H](3+) ions are ~12.9, ~15.5, and ~14.9, respectively. Ion structures obtained from molecular dynamics simulations (MDS) suggest that this ordering of HDX level results from increased charge-site/exchange-site density for the more compact ions of lower charge. Additionally, a new model that includes two distance calculations (charge site to carbonyl group and carbonyl group to exchange site) for the computer-generated structures is shown to better correlate to the experimentally determined per-residue deuterium uptake. Future comparisons of IMS-HDX-MS data with structures obtained from MDS are discussed with respect to novel experiments that will reveal the HDX rates of individual residues.

  19. Combining Ion Mobility Spectrometry with Hydrogen-Deuterium Exchange and Top-Down MS for Peptide Ion Structure Analysis

    NASA Astrophysics Data System (ADS)

    Khakinejad, Mahdiar; Kondalaji, Samaneh Ghassabi; Maleki, Hossein; Arndt, James R.; Donohoe, Gregory C.; Valentine, Stephen J.

    2014-12-01

    The gas-phase conformations of electrosprayed ions of the model peptide KKDDDDIIKIIK have been examined by ion mobility spectrometry (IMS) and hydrogen deuterium exchange (HDX)-tandem mass spectrometry (MS/MS) techniques. [M+4H]4+ ions exhibit two conformers with collision cross sections of 418 Å2 and 471 Å2. [M+3H]3+ ions exhibit a predominant conformer with a collision cross section of 340 Å2 as well as an unresolved conformer (shoulder) with a collision cross section of ~367 Å2. Maximum HDX levels for the more compact [M+4H]4+ ions and the compact and partially-folded [M+3H]3+ ions are ~12.9, ~15.5, and ~14.9, respectively. Ion structures obtained from molecular dynamics simulations (MDS) suggest that this ordering of HDX level results from increased charge-site/exchange-site density for the more compact ions of lower charge. Additionally, a new model that includes two distance calculations (charge site to carbonyl group and carbonyl group to exchange site) for the computer-generated structures is shown to better correlate to the experimentally determined per-residue deuterium uptake. Future comparisons of IMS-HDX-MS data with structures obtained from MDS are discussed with respect to novel experiments that will reveal the HDX rates of individual residues.

  20. The Analysis of Information Exchange Capability for Battlefield Networks Using M&S Techniques of the NetSPIN

    DTIC Science & Technology

    2013-06-01

    battlefield network, which are modeled and simulated using the OPNET . In this paper, we suggest the analysis method of information exchange capability for...battlefield network, which are modeled and simulated using the OPNET . In this paper, we suggest the analysis method of information exchange capability...SPIDER, ATCIS, OPNET 1. INTRODUCTION For the NCW (Network Centric Warfare) that networks of a battlefield are interconnected in real time, the