NASA Astrophysics Data System (ADS)
dos Santos, F. C.; Longo, K.; Guenther, A. B.; Gu, D.; Kim, S.; Freitas, S.; Moreira, D. S.; Flávio, L.; Braz, R.; Brito, J.; Oram, D.; Foster, G.; Lee, J. D.
2017-12-01
Emitted by vegetation, isoprene (2-methyl-1,3-butadiene) is the most abundant non-methane hydrocarbons, with an annual global emission calculated ranging from 440 to 660Tg carbon, depending on the driving variables like temperature, solar radiation, LAI and PFT. The natural compounds like isoprene and terpenes present in the troposphere are about 90% and 50%, respectively, removed from the atmosphere by oxidation performed by hydroxyl radical (OH). Considering the importance of these emissions and the hydroxyl radical reaction in the atmosphere, the SAMBBA (South American Biomass Burning Analysis) experiment, which occurred during the dry season (September 2012) in the Brazilian Amazon Rainforest, provided information about the chemical composition of the atmosphere through airborne observations. Although primarily focused on biomass burning flights, the SAMBBA project carried out flights in pristine environment. In this study, we determine the ambient distribution of CO, NOx and O3, and evaluate the oxidative capacity of the Amazon rainforest in different chemical regimes, using the ratio [MVK + MACR]/[Isoprene]. Beyond that, we proposed an improvement on the formulation of indirect OH density calculation, using the photochemical aging [O3]/[CO] as a parameter. Balancing numerical modeling and direct observations, the numerical model BRAMS was coupled to MEGAN emission model to get a better result for isoprene and OH in the atmosphere, representing the observations during SAMBBA field campaign. In relation to OH estimation, we observed an improvement in the concentration values using the modified sequential reaction model, for both biomass burning regimes and background environment. We also detected a long-range transport events of O3, considering the high levels of O3 in aged plumes at high altitudes (5,500 - 6,500 m), and the detection of an O3 inflow in the Amazon basin from Africa. These findings support the importance of long-range transport events as a source of O3 into the troposphere in the Amazon basin, which could even alter the atmospheric composition within the planetary boundary layer and alter the oxidative capacity in the region. The coupled model results showed a reasonable agreement for isoprene concentration, although more investigation needed for the OH simulation.
Amaral, Simone Simões; de Carvalho, João Andrade; Costa, Maria Angélica Martins; Soares Neto, Turíbio Gomes; Dellani, Rafael; Leite, Luiz Henrique Scavacini
2014-07-01
Two different types of typical Brazilian forest biomass were burned in the laboratory in order to compare their combustion characteristics and pollutant emissions. Approximately 2 kg of Amazon biomass (hardwood) and 2 kg of Araucaria biomass (softwood) were burned. Gaseous emissions of CO2, CO, and NOx and particulate matter smaller than 2.5 μm (PM2.5) were evaluated in the flaming and smoldering combustion phases. Temperature, burn rate, modified combustion efficiency, emissions factor, and particle diameter and concentration were studied. A continuous analyzer was used to quantify gas concentrations. A DataRam4 and a Cascade Impactor were used to sample PM2.5. Araucaria biomass (softwood) had a lignin content of 34.9%, higher than the 23.3% of the Amazon biomass (hardwood). CO2 and CO emissions factors seem to be influenced by lignin content. Maximum concentrations of CO2, NOx and PM2.5 were observed in the flaming phase. Copyright © 2014 Elsevier Ltd. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Smith, JN
2016-04-01
The Thermal Desorption Chemical Ionization Mass Spectrometer (TDCIMS) deployment to the U.S. Department of Energy (DOE)’s Atmospheric Radiation Measurement (ARM) Climate Research Facility T3 site in Manacapuru, Brazil, was motivated by two main scientific objectives of the Green Ocean Amazon (GoAmazon) 2014/15 field campaign. 1) Study the interactions between anthropogenic and biogenic emissions by determining important molecular species in ambient nanoparticles. To address this, TDCIMS data will be combined with coincident measurements such as gas-phase sulfuric acid to determine the contribution of sulfuric acid condensation to nucleation and growth. We can then compare that result to TDCIMS-derived nanoparticle composition tomore » determine the fraction of growth that can be attributed to the uptake of organic compounds. The molecular composition of sampled particles will also be used to attribute specific chemical species and mechanisms to growth, such as the condensation of low-volatility species or the oligomerization of α-dicarbonyl compounds. 2) Determine the source of new ambient nanoparticles in the Amazon. The hypothesis prior to measurements was that potassium salts formed from the evaporation of primary particles emitted by fungal spores can provide a unique and important pathway for new particle production in the Amazon basin. To explore this hypothesis, the TDCIMS recorded the mass spectra of sampled ambient particles using a protonated water cluster Chemical Ionization Mass Spectrometer (CIMS). Laboratory tests performed using potassium salts show that the TDCIMS can detect potassium with high sensitivity with this technique.« less
Modeling investigation of light-absorbing aerosols in the Amazon Basin during the wet season
NASA Astrophysics Data System (ADS)
Wang, Qiaoqiao; Saturno, Jorge; Chi, Xuguang; Walter, David; Lavric, Jost; Moran-Zuloaga, Daniel; Ditas, Florian; Pöhlker, Christopher; Brito, Joel; Carbone, Samara; Artaxo, Paulo; Andreae, Meinrat
2017-04-01
We use a global chemical transport model (GEOS-Chem) to interpret observed light-absorbing aerosols in Amazonia during the wet season. Observed aerosol properties, including black carbon (BC) concentration and light absorption, at the Amazon Tall Tower Observatory (ATTO) site in the central Amazon have relatively low background levels but frequently show high peaks during the study period of January-April 2014. With daily temporal resolution for open fire emissions and modified aerosol optical properties, our model successfully captures the observed variation in fine/coarse aerosol and BC concentrations as well as aerosol light absorption and its wavelength dependence over the Amazon Basin. The source attribution in the model indicates the important influence of open fire on the observed variances of aerosol concentrations and absorption, mainly from regional sources (northern South America) and from northern Africa. The contribution of open fires from these two regions is comparable, with the latter becoming more important in the late wet season. The analysis of correlation and enhancement ratios of BC versus CO suggests transport times of < 3 days for regional fires and 11 days for African plumes arriving at ATTO during the wet season. The model performance of long-range transport of African plumes is also evaluated with observations from AERONET, MODIS, and CALIOP. Simulated absorption aerosol optical depth (AAOD) averaged over the wet season is lower than 0.0015 over the central Amazon, including the ATTO site. We find that more than 50% of total absorption at 550 nm is from BC, except for the northeastern Amazon and the Guianas, where the influence of dust becomes significant (up to 35 %). The brown carbon contribution is generally between 20 and 30 %. The distribution of absorption Ångström exponents (AAE) suggests more influence from fossil fuel combustion in the southern part of the basin (AAE 1) but more open fire and dust influence in the northern part (AAE > 1.8). Uncertainty analysis shows that accounting for absorption due to secondary organic aerosol (SOA) and primary biogenic aerosol (PBA) particles could result in differences of < 8 and 5-40% in total absorption, respectively.
Remote tropical and sub-tropical responses to Amazon deforestation
NASA Astrophysics Data System (ADS)
Badger, Andrew M.; Dirmeyer, Paul A.
2016-05-01
Replacing natural vegetation with realistic tropical crops over the Amazon region in a global Earth system model impacts vertical transport of heat and moisture, modifying the interaction between the atmospheric boundary layer and the free atmosphere. Vertical velocity is decreased over a majority of the Amazon region, shifting the ascending branch and modifying the seasonality of the Hadley circulation over the Atlantic and eastern Pacific oceans. Using a simple model that relates circulation changes to heating anomalies and generalizing the upper-atmosphere temperature response to deforestation, agreement is found between the response in the fully-coupled model and the simple solution. These changes to the large-scale dynamics significantly impact precipitation in several remote regions, namely sub-Saharan Africa, Mexico, the southwestern United States and extratropical South America, suggesting non-local climate repercussions for large-scale land use changes in the tropics are possible.
Moreira, Fatima Maria de Souza; Nóbrega, Rafaela Simão Abrahão; Jesus, Ederson da Conceição; Ferreira, Daniel Furtado; Pérez, Daniel Vidal
2009-12-20
The Upper Solimões river region, western Amazon, is the homeland of indigenous populations and contains small-scale agricultural systems that are important for biodiversity conservation. Although traditional slash-and-burn agriculture is being practiced over many years, deforestation there is relatively small compared to other Amazon regions. Pastures are restricted to the vicinity of cities and do not spread to the small communities along the river. Inceptisols are the main soil order (>90%) in the area and have unique attributes including high Al content and high cation exchange capacity (CEC) due to the enrichment of the clay fraction with 2:1 secondary aluminosilicates. Despite its importance, few studies have focussed on this soil order when considering land use effects on the fertility of Amazon soils. Thus, the objective of this study was to evaluate changes in soil fertility of representative land use systems (LUSs) in the Upper Solimões region, namely: primary rainforest, old secondary forest, young secondary forest, agroforestry, pasture and agriculture. LUSs were significantly differentiated by the chemical attributes of their topsoil (0-20 cm). Secondary forests presented soil chemical attributes more similar to primary rainforest areas, while pastures exhibited the highest dissimilarity from all the other LUSs. As a whole, soil chemical changes among Inceptisols dominated LUSs showed patterns that were distinct from those reported from other Amazon soils like Oxisols and Ultisols. This is probably related to the presence of high-activity clays enriched in exchangeable aluminum that heavily influenced the soil chemical reactions over the expected importance of organic matter found in most studies conducted over Oxisol and Ultisol.
R.C. Oliveira Junior; Michael Keller; P. Crill; T. Beldini; J. Van Haren; P. Camargo
2015-01-01
The emission of gases that may potentially intensify the greenhouse effect has received special attention due to their ability to raise global temperatures and possibly modify conditions for life on earth. The objectives of this study were the quantification of trace gas flux (N2O, CO2 and CH4) in soils of the lower Amazon basin that are planted with rice and soybean,...
USDA-ARS?s Scientific Manuscript database
Traditional slash and burn agriculture practiced in the Peruvian Amazon region is leading to soil degradation and deforestation of native forest flora. The only way to stop such destructive processes is through the adoptation of sustainable alternatives such as growing crops in agroforestry systems....
NASA Astrophysics Data System (ADS)
Kastner, Thomas P.; Goñi, Miguel A.
2003-04-01
Analyses of more than 60 sediment samples from the Amazon deep sea fan show remarkably constant terrigenous biomarkers (lignin phenols and cutin acids) and stable carbon isotopic compositions of organic matter (δ13COM) deposited from 10 to 70 ka. Sediments from the nine Amazon deep sea fan channel-levee systems investigated in this study yielded relatively narrow ranges for diagnostic parameters such as organic carbon (OC) normalized total lignin yields (Λ = 3.1 ± 1.1 mg/100 mg OC), syringyl:vanillyl phenol ratios (S/V = 0.84 ± 0.06), cinnamyl:vanillyl phenol ratios (C/V = 0.08 ± 0.02), isomeric abundances of cutin-derived dihydroxyhexadecanoic acid (f10,16-OH = 0.65 ± 0.02), and δ13COM (-27.6% ± 0.6 ‰). Our measurements support the hypothesis that the vegetation of the Amazon Basin did not change significantly during the late Pleistocene, even during the Last Glacial Maximum. Moreover, the compositions obtained from the Amazon deep sea fan are similar to those of modern Amazon River suspended sediments. Such results strongly indicate that the current tropical rainforest vegetation has been a permanent and dominant feature of the Amazon River watershed over the past 70 k.y. Specifically, we found no evidence for the development of large savannas that had been previously postulated as indicators of increased glacial aridity in Amazonia. Climate models need to be modified to account for the uninterrupted input of moisture to the tropical Amazon region over the late Pleistocene Holocene period.
Regional aerosol chemistry of the Amazon Basin during the dry season
NASA Technical Reports Server (NTRS)
Talbot, R. W.; Harriss, R. C.; Andreae, M. O.; Andreae, T. W.
1988-01-01
The distribution and chemical composition of the atmospheric aerosol over the Amazon Basin forest were determined during the 1985 July-August dry season, using data on the aerosol chemical constituent concentration collected during the NASA Global Tropospheric Experiment Amazon Boundary Layer Experiment 2A mission. The results of the analyses suggest that there is a remarkable compositional and spatial homogeneity of the atmospheric aerosol on an extensive regional scale. Particulate organic carbon is the dominant component of the atmospheric aerosol, exhibiting an average concentration of about 740 nmol/cu m in the mixed layer and about 220 nmol/cu m in free tropospheric air. Oxalate and SO4(2-) exhibited the greatest enrichment in the mixed layer, while Cl(-) showed essentially no enrichment. The aerosol in the Amazonian atmosphere is essentially acid-base neutral, primarily as a result of incorporation of NH(+), which is presumably derived from NH3 released by the forest ecosystem.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Jardine, Kolby
In conjunction with the U.S. Department of Energy (DOE)’s Atmospheric Radiation Measurement (ARM) Climate Research Facility GoAmazon campaign, the Terrestrial Ecosystem Science (TES)-funded Green Ocean Amazon (GoAmazon 2014/15) terrestrial ecosystem project (Geco) was designed to: • evaluate the strengths and weaknesses of leaf-level algorithms for biogenic volatile organic compounds (BVOCs) emissions in Amazon forests near Manaus, Brazil, and • conduct mechanistic field studies to characterize biochemical and physiological processes governing leaf- and landscape-scale tropical forest BVOC emissions, and the influence of environmental drivers that are expected to change with a warming climate. Through a close interaction between modeling and observationalmore » activities, including the training of MS and PhD graduate students, post-doctoral students, and technicians at the National Institute for Amazon Research (INPA), the study aimed at improving the representation of BVOC-mediated biosphere-atmosphere interactions and feedbacks under a warming climate. BVOCs can form cloud condensation nuclei (CCN) that influence precipitation dynamics and modify the quality of down welling radiation for photosynthesis. However, our ability to represent these coupled biosphere-atmosphere processes in Earth system models suffers from poor understanding of the functions, identities, quantities, and seasonal patterns of BVOC emissions from tropical forests as well as their biological and environmental controls. The Model of Emissions of Gases and Aerosols from Nature (MEGAN), the current BVOC sub-model of the Community Earth System Model (CESM), was evaluated to explore mechanistic controls over BVOC emissions. Based on that analysis, a combination of observations and experiments were studied in forests near Manaus, Brazil, to test existing parameterizations and algorithm structures in MEGAN. The model was actively modified as needed to improve tropical BVOC emission simulations on a regional scale.« less
MR-Tandem: parallel X!Tandem using Hadoop MapReduce on Amazon Web Services.
Pratt, Brian; Howbert, J Jeffry; Tasman, Natalie I; Nilsson, Erik J
2012-01-01
MR-Tandem adapts the popular X!Tandem peptide search engine to work with Hadoop MapReduce for reliable parallel execution of large searches. MR-Tandem runs on any Hadoop cluster but offers special support for Amazon Web Services for creating inexpensive on-demand Hadoop clusters, enabling search volumes that might not otherwise be feasible with the compute resources a researcher has at hand. MR-Tandem is designed to drop in wherever X!Tandem is already in use and requires no modification to existing X!Tandem parameter files, and only minimal modification to X!Tandem-based workflows. MR-Tandem is implemented as a lightly modified X!Tandem C++ executable and a Python script that drives Hadoop clusters including Amazon Web Services (AWS) Elastic Map Reduce (EMR), using the modified X!Tandem program as a Hadoop Streaming mapper and reducer. The modified X!Tandem C++ source code is Artistic licensed, supports pluggable scoring, and is available as part of the Sashimi project at http://sashimi.svn.sourceforge.net/viewvc/sashimi/trunk/trans_proteomic_pipeline/extern/xtandem/. The MR-Tandem Python script is Apache licensed and available as part of the Insilicos Cloud Army project at http://ica.svn.sourceforge.net/viewvc/ica/trunk/mr-tandem/. Full documentation and a windows installer that configures MR-Tandem, Python and all necessary packages are available at this same URL. brian.pratt@insilicos.com
Volatile isoprenoids as defense compounds during abiotic stress in tropical plants
NASA Astrophysics Data System (ADS)
Jardine, K.
2015-12-01
Emissions of volatile isoprenoids from tropical forests play central roles in atmospheric processes by fueling atmospheric chemistry resulting in modified aerosol and cloud lifecycles and their associated feedbacks with the terrestrial biosphere. However, the identities of tropical isoprenoids, their biological and environmental controls, and functions within plants and ecosystems remain highly uncertain. As part of the DOE ARM program's GoAmazon 2014/15 campaign, extensive field and laboratory observations of volatile isoprenoids are being conducted in the central Amazon. Here we report the results of our completed and ongoing activities at the ZF2 forest reserve in the central Amazon. Among the results of the research are the suprisingly high abundance of light-dependent volatile isoprenoid emissions across abundant tree genera in the Amazon in both primary and secondary forests, the discovery of highly reactive monoterpene emissions from Amazon trees, and evidence for the importance of volatile isoprenoids in protecting photosynthesis during oxidative stress under elevated temperatures including energy consumption and direct antioxidant functions and a tight connection betwen volatile isoprenoid emissions, photorespiration, and CO2 recycling within leaves. The results highlight the need to model allocation of carbon to isoprenoids during elevated temperature stress in the tropics.
da Costa Lobato, Tarcísio; Hauser-Davis, Rachel Ann; de Oliveira, Terezinha Ferreira; Maciel, Marinalva Cardoso; Tavares, Maria Regina Madruga; da Silveira, Antônio Morais; Saraiva, Augusto Cesar Fonseca
2015-02-15
The Amazon area has been increasingly suffering from anthropogenic impacts, especially due to the construction of hydroelectric power plant reservoirs. The analysis and categorization of the trophic status of these reservoirs are of interest to indicate man-made changes in the environment. In this context, the present study aimed to categorize the trophic status of a hydroelectric power plant reservoir located in the Brazilian Amazon by constructing a novel Water Quality Index (WQI) and Trophic State Index (TSI) for the reservoir using major ion concentrations and physico-chemical water parameters determined in the area and taking into account the sampling locations and the local hydrological regimes. After applying statistical analyses (factor analysis and cluster analysis) and establishing a rule base of a fuzzy system to these indicators, the results obtained by the proposed method were then compared to the generally applied Carlson and a modified Lamparelli trophic state index (TSI), specific for trophic regions. The categorization of the trophic status by the proposed fuzzy method was shown to be more reliable, since it takes into account the specificities of the study area, while the Carlson and Lamparelli TSI do not, and, thus, tend to over or underestimate the trophic status of these ecosystems. The statistical techniques proposed and applied in the present study, are, therefore, relevant in cases of environmental management and policy decision-making processes, aiding in the identification of the ecological status of water bodies. With this, it is possible to identify which factors should be further investigated and/or adjusted in order to attempt the recovery of degraded water bodies. Copyright © 2014 Elsevier B.V. All rights reserved.
NASA Astrophysics Data System (ADS)
Shilling, J.; Pekour, M. S.; Fortner, E.; Hubbe, J. M.; Longo, K.; Martin, S. T.; Mei, F.; Springston, S. R.; Tomlinson, J. M.; Wang, J.
2014-12-01
The Green Ocean Amazon (GoAmazon) campaign conducted from January 2014 - December 2015 in the vicinity of Manaus, Brazil, was designed to study the aerosol lifecycle and aerosol-cloud interactions in both pristine and anthropogenically influenced conditions. As part of this campaign, the DOE G-1 research aircraft was deployed from February 17th - March 25th 2014 and September 6th - October 5th 2014 to investigate aerosol and cloud properties aloft. An Aerodyne High Resolution Aerosol Mass Spectrometer (AMS) and an Ionicon Proton Transfer Reaction Mass Spectrometer (PTRMS) were part of the G-1 research aircraft payload and were used to investigate aerosol gas- and particle-phase chemical composition. Here we present preliminary analysis of the aerosol and gas phase chemical composition. PTR-MS measurements show that isoprene and its oxidation products are the dominant VOCs during research flights. HR-AMS measurements reveal that the particle phase is dominated by organic material with smaller concentrations of sulfate and nitrate observed. Organic particle concentrations are enhanced when encountering the urban plume from Manaus. During the wet season, we observe increased concentrations of organic particle when passing through low-altitude clouds. PMF analysis of the organic mass spectra shows that the chemical composition of the particles observed in-cloud is distinctly different from particles observed outside clouds. We will also compare measurements made during the wet and dry seasons.
The Amazon Boundary Layer Experiment (ABLE 2A) - Dry season 1985
NASA Technical Reports Server (NTRS)
Harriss, R. C.; Browell, E. V.; Hoell, J. M., Jr.; Bendura, R. J.; Beck, S. M.; Wofsy, S. C.; Mcneal, R. J.; Navarro, R. L.; Riley, J. T.; Snell, R. L.
1988-01-01
The Amazon Boundary Layer Experiment (ABLE 2A) used data from aircraft, ground-based, and satellite platforms to characterize the chemistry and dynamics of the lower atmosphere over the Amazon Basin during the early-to-middle dry season, July and August 1985. This paper reports the conceptual framework and experimental approach used in ABLE 2A and serves as an introduction to the detailed papers which follow in this issue. The results of ABLE 2A demonstrate that isoprene, methane, carbon dioxide, nitric oxide, dimethylsulfide, and organic aerosol emissions from soils and vegetation play a major role in determining the chemical composition of the atmospheric mixed layer over undisturbed forest and wetland environments. As the dry season progresses, emissions from both local and distant biomass burning become an important source of carbon monoxide, nitric oxide and ozone in the atmosphere over the central Amazon Basin.
MR-Tandem: parallel X!Tandem using Hadoop MapReduce on Amazon Web Services
Pratt, Brian; Howbert, J. Jeffry; Tasman, Natalie I.; Nilsson, Erik J.
2012-01-01
Summary: MR-Tandem adapts the popular X!Tandem peptide search engine to work with Hadoop MapReduce for reliable parallel execution of large searches. MR-Tandem runs on any Hadoop cluster but offers special support for Amazon Web Services for creating inexpensive on-demand Hadoop clusters, enabling search volumes that might not otherwise be feasible with the compute resources a researcher has at hand. MR-Tandem is designed to drop in wherever X!Tandem is already in use and requires no modification to existing X!Tandem parameter files, and only minimal modification to X!Tandem-based workflows. Availability and implementation: MR-Tandem is implemented as a lightly modified X!Tandem C++ executable and a Python script that drives Hadoop clusters including Amazon Web Services (AWS) Elastic Map Reduce (EMR), using the modified X!Tandem program as a Hadoop Streaming mapper and reducer. The modified X!Tandem C++ source code is Artistic licensed, supports pluggable scoring, and is available as part of the Sashimi project at http://sashimi.svn.sourceforge.net/viewvc/sashimi/trunk/trans_proteomic_pipeline/extern/xtandem/. The MR-Tandem Python script is Apache licensed and available as part of the Insilicos Cloud Army project at http://ica.svn.sourceforge.net/viewvc/ica/trunk/mr-tandem/. Full documentation and a windows installer that configures MR-Tandem, Python and all necessary packages are available at this same URL. Contact: brian.pratt@insilicos.com PMID:22072385
Geochemistry of the Amazon Estuary
Smoak, Joseph M.; Krest, James M.; Swarzenski, Peter W
2006-01-01
The Amazon River supplies more freshwater to the ocean than any other river in the world. This enormous volume of freshwater forces the estuarine mixing out of the river channel and onto the continental shelf. On the continental shelf, the estuarine mixing occurs in a very dynamic environment unlike that of a typical estuary. The tides, the wind, and the boundary current that sweeps the continental shelf have a pronounced influence on the chemical and biological processes occurring within the estuary. The dynamic environment, along with the enormous supply of water, solutes and particles makes the Amazon estuary unique. This chapter describes the unique features of the Amazon estuary and how these features influence the processes occurring within the estuary. Examined are the supply and cycling of major and minor elements, and the use of naturally occurring radionuclides to trace processes including water movement, scavenging, sediment-water interaction, and sediment accumulation rates. The biogeochemical cycling of carbon, nitrogen, and phosphorus, and the significances of the Amazon estuary in the global mass balance of these elements are examined.
NASA Astrophysics Data System (ADS)
Smith, J. N.; Park, J. H.; Kuang, C.; Bustillos, J. O. V.; Souza, R. A. F. D.; Wiedemann, K. T.; Munger, J. W.; Wofsy, S. C.; Rizzo, L. V.; Artaxo, P.; Martin, S. T.; Seco, R.; Kim, S.; Guenther, A. B.; Batalha, S. S. A.; Alves, E. G.; Tota, J.
2014-12-01
The Amazon rainforest is a unique and important place for studying aerosol formation and its impacts on atmospheric chemistry and climate. In remote areas, the atmosphere is characterized by low particle number concentrations and high humidity; perturbations in the particle number concentrations and climate-relevant physical and chemical properties could therefore have a great impact on cloud formation and thus on regional climate and precipitation. While it was previously believed that new particle formation occurs rarely in the Amazon, observations in the Amazon of a sustained steady-state particle number concentration, along with an abundance of dry and wet surfaces upon which particles may deposit, imply that sources of new particles must exist in this region. We present observations from two studies, GOAmazon2014 and Tapajos Upwind Forest Flux Study (TUFFS), which seek to identify and quantify the sources of aerosol particles in the Amazon. Measurements of the chemical composition of 20 - 100 nm diameter aerosol particles at the T3 measurement site during the wet and dry season campaigns of GOAmazon2014 show the presence of inorganic ions such as potassium ion and sulfate, as well as organic ion such as oxalate, in ambient nanoparticles. These observations, combined with 1.5 - 300 nm diameter particle number size distributions and trace gas measurements of organic compounds and sulfuric acid, are used to determine the relative importance of sulfuric acid, organic compounds, and primary biological particle emissions to nanoparticle formation and growth. Observations of 3 - 100 nm diameter particle number size distributions at the KM67 tower site during TUFFS show frequent new particle formation events during the wet season in April, transitioning to a scenario of less frequent events in July at the onset of the dry season. These observations highlight the regional nature of new particle formation in the Amazon, and suggest that additional observations at a variety of locales are needed to fully understand the roles of new particle formation in this region.
Satellite-based Analysis of CO Variability over the Amazon Basin
NASA Astrophysics Data System (ADS)
Deeter, M. N.; Emmons, L. K.; Martinez-Alonso, S.; Tilmes, S.; Wiedinmyer, C.
2017-12-01
Pyrogenic emissions from the Amazon Basin exert significant influence on both climate and air quality but are highly variable from year to year. The ability of models to simulate the impact of biomass burning emissions on downstream atmospheric concentrations depends on (1) the quality of surface flux estimates (i.e., emissions inventories), (2) model dynamics (e.g., horizontal winds, large-scale convection and mixing) and (3) the representation of atmospheric chemical processes. With an atmospheric lifetime of a few months, carbon monoxide (CO) is a commonly used diagnostic for biomass burning. CO products are available from several satellite instruments and allow analyses of CO variability over extended regions such as the Amazon Basin with useful spatial and temporal sampling characteristics. The MOPITT ('Measurements of Pollution in the Troposphere') instrument was launched on the NASA Terra platform near the end of 1999 and is still operational. MOPITT is uniquely capable of measuring tropospheric CO concentrations using both thermal-infrared and near-infrared observations, resulting in the ability to independently retrieve lower- and upper-troposphere CO concentrations. We exploit the 18-year MOPITT record and related datasets to analyze the variability of CO over the Amazon Basin and evaluate simulations performed with the CAM-chem chemical transport model. We demonstrate that observed differences between MOPITT observations and model simulations provide important clues regarding emissions inventories, convective mixing and long-range transport.
Extratropical Respones to Amazon Deforestation
NASA Astrophysics Data System (ADS)
Badger, A.; Dirmeyer, P.
2014-12-01
Land-use change (LUC) is known to impact local climate conditions through modifications of land-atmosphere interactions. Large-scale LUC, such as Amazon deforestation, could have a significant effect on the local and regional climates. The question remains as to what the global impact of large-scale LUC could be, as previous modeling studies have shown non-local responses due to Amazon deforestation. A common shortcoming in many previous modeling studies is the use of prescribed ocean conditions, which can act as a boundary condition to dampen the global response with respect to changes in the mean and variability. Using fully coupled modeling simulations with the Community Earth System Model version 1.2.0, the Amazon rainforest has been replaced with a distribution of representative tropical crops. Through the modifications of local land-atmosphere interactions, a significant change in the region, both at the surface and throughout the atmosphere, can be quantified. Accompanying these local changes are significant changes to the atmospheric circulation across all scales, thus modifying regional climates in other locales. Notable impacts include significant changes in precipitation, surface fluxes, basin-wide sea surface temperatures and ENSO behavior.
Guerra, Denis L; Silva, Weber L L; Oliveira, Helen C P; Viana, Rúbia R; Airoldi, Claudio
2011-02-15
The objective of this study is to examine the adsorption behavior of Sumifix Brilliant Orange 3R textile dye from aqueous solution on smectite sample, an abundant Amazon clay. The original smectite clay mineral has been collected from Amazon region, Brazil. The compound 2-aminomethylpyridine was anchored onto smectite surface by heterogeneous route. The ability of these materials to remove the Sumifix Brilliant Orange 3R textile dye from aqueous solution was followed by a series of adsorption isotherms, using a batchwise process. The maximum number of moles adsorbed was determined to be 1.26 and 2.07 mmol g(-1) for natural and modified clay samples, respectively. The energetic effects caused by dye cations adsorption were determined through calorimetric titrations. Thermodynamics indicated the existence of favorable conditions for such dye-nitrogen interactions. Copyright © 2010. Published by Elsevier B.V.
NASA Astrophysics Data System (ADS)
Wolff, Stefan; Ganzeveld, Laurens; Tsokankunku, Anywhere; Saturno, Jorge; Souza, Rodrigo; Trebs, Ivonne; Sörgel, Matthias
2017-04-01
The ATTO (Amazon Tall Tower Observatory) site (02°08'38.8''S, 58°59'59.5''W) is located in the remote Amazon rainforest, allowing atmospheric and forest studies away from nearby anthropogenic emission sources. Starting with continuous measurements of vertical mixing ratio profiles of H2O, CO2 and O3 in April 2012 at 8 heights between 0.05 m and 80 m above ground, the longest continuous record of near surface O3 in the Amazon rainforest was established. Black carbon (BC), CO and micrometeorological measurements are available for the same period. During intensive campaigns, NOx was measured as well using the same profile system, and therefore several month of parallel NOx measurements are available. This data allows the analyses of diverse patterns regarding emission, deposition, turbulence and chemical reactions of trace gases within and above the rainforest for several rainy and dry seasons. The remote Amazon generally serves as a sink for O3 which is mainly deposited to the canopy. The deposition depends to a large extent on the aperture of the leaf stomata, which is correlated to temperature, humidity, solar radiation and water availability. Comparing these parameters with the in-canopy and above canopy gradients of O3, considering the turbulent conditions and further chemical reactions of O3 with NOx and VOC molecules, we estimated the role of the forest for the removal of ozone from the atmosphere under different meteorological conditions. We applied the Multi-Layer Canopy Chemical Exchange Model - MLC-CHEM to support the analysis of the observed profiles of NOx and O3. Under pristine conditions, the forest soil is the major source for NO emissions, which are directly reacting with O3 molecules, affecting the O3 gradient within the sub-canopy. We have analyzed differences between model and measurements in sub-canopy NO and O3 mixing ratios by the application of different NO soil emission scenarios and by the performance of several sensitivity analyses to investigate the deposition of O3 and NO2 in the canopy.
Land-use versus natural controls on soil fertility in the Subandean Amazon, Peru.
Lindell, Lina; Aström, Mats; Oberg, Tomas
2010-01-15
Deforestation to amplify the agricultural frontier is a serious threat to the Amazon forest. Strategies to attain and maintain satisfactory soil fertility, which requires knowledge of spatial and temporal changes caused by land-use, are important for reaching sustainable development. This study highlights these issues by evaluating the relative effects of agricultural land-use and natural factors on chemical fertility of Inceptisols on redbed lithologies in the Subandean Amazon. Macro and micronutrients were determined in topsoil and subsoil in the vicinity of two villages at a total of 80 sites including pastures, coffee plantations, swidden fields, secondary forest and, as a reference, adjacent primary forest. Differences in soil fertility between the land cover classes were investigated by principal component analysis (PCA) and partial least squares regression (PLSR). Primary forest soil was found to be chemically similar to that of coffee plantations, pastures and secondary forests. There were no significant differences between soils of these land cover types in terms of plant nutrients (e.g. N, P, K, Ca, Mg, Mo, Mn, Zn, Cu and Co) or other fertility indicators (OM, pH, BS, EC, CECe and exchangeable acidity). The parent material (as indicated by texture and sample geographical origin) and the slope of the sampled sites were stronger controls on soil fertility than land cover type. Elevated concentrations of a few nutrients (NO(3) and K) were, however detected in soils of swidden fields. Despite being fertile (higher CECe, Ca and P) compared to Oxisols and Ultisols in the Amazon lowland, the Subandean soils frequently showed deficiencies in several nutrients (e.g. P, K, NO(3), Cu and Zn), and high levels of free Al at acidic sites. This paper concludes that deforestation and agricultural land-use has not introduced lasting chemical changes in the studied Subandean soils that are significant in comparison to the natural variability. Copyright 2009 Elsevier B.V. All rights reserved.
Effects of Land Use Changes on the Water and Energy Balance Over South America
NASA Astrophysics Data System (ADS)
Nascimento, M.; Herdies, D. L.; Angelis, C.
2013-05-01
With the objective of analyzing the effects of land use changes in the Amazon and its consequences on the main components of the water and energy balance over South America, with emphasis on the Amazon and La Plata Basin, two experiments were carried for 10-year period (1999-2008), in which the land use conditions were modified, representing conditions for the 90s (CONTROL Experiment) and current conditions over land use in the Amazon region (Experiment 1). Changes in land use were observed mainly in the Amazon region and southern Brazil. The numerical model used to perform the simulations was the ETA in its climate version, using as an initial and boundary condition the CFSR/NCEP reanalysis datasets. The results show for the analyzed period that there was a reduction of 3.3 mm/month in average rainfall rates in the La Plata Basin and 4.2 mm/month in the Amazon region, with some places where this reduction was more pronounced. Seasonally was observed that during the summer there is an average reduction of 3.9 mm/month in the Amazon region. Already on the La Plata Basin was observed an average increase of 11.7 mm/month in the La Plata Basin during the summer and an reduction in winter season. Through the overall result was also possible to conclude that the changes in land use for more realistic conditions, there were significant reductions in evapotranspiration and latent heat fluxes, as well as an increase in sensible heat fluxes, especially over the regions where the changes were more pronounced. Through the analyzes it can be observed that in general the La Plata Basin is sensitive to changes in land use over the Amazon and adjacent regions, allowing to conclude that such changes can influence the amount of rainfall, the intensity of the major meteorological systems, as well as temperature trends on the regions analyzed.
Environmental Controls on Space-Time Biodiversity Patterns in the Amazon
NASA Astrophysics Data System (ADS)
Porporato, A. M.; Bonetti, S.; Feng, X.
2014-12-01
The Amazon/Andes territory is characterized by the highest biodiversity on Earth and understanding how all these ecological niches and different species originated and developed is an open challenge. The niche perspective assumes that species have evolved and occupy deterministically different roles within its environment. This view differs from that of the neutral theories, which assume ecological equivalence between all species but incorporates stochastic demographic processes along with long-term migration and speciation rates. Both approaches have demonstrated tremendous power in predicting aspects species biodiversity. By combining tools from both approaches, we use modified birth and death processes to simulate plant species diversification in the Amazon/Andes and their space-time ecohydrological controls. By defining parameters related to births and deaths as functions of available resources, we incorporate the role of space-time resource variability on niche formation and community composition. We also explicitly include the role of a heterogeneous landscape and topography. The results are discussed in relation to transect datasets from neotropical forests.
Smoke Invigoration Versus Inhibition of Clouds over the Amazon
NASA Technical Reports Server (NTRS)
Koren, Ilan; Martins, J. Vanderlei; Lorraine, A. Remer; Afargan, Hila
2008-01-01
The effect of anthropogenic aerosols on clouds is one of the most important and least understood aspects of human-induced climate change. Small changes in the amount of cloud coverage can produce a climate forcing equivalent in magnitude and opposite in sign to that caused by anthropogenic greenhouse gases, and changes in cloud height can shift the effect of clouds from cooling to warming. Focusing on the Amazon, we show a smooth transition between two opposing effects of aerosols on clouds: the microphysical and the radiative. We show how a feedback between the optical properties of aerosols and the cloud fraction can modify the aerosol forcing, changing the total radiative energy and redistributing it over the atmospheric column.
Potential groundwater contribution to Amazon evapotranspiration
NASA Astrophysics Data System (ADS)
Fan, Y.; Miguez-Macho, G.
2010-07-01
Climate and land ecosystem models simulate a dry-season vegetation stress in the Amazon forest, but observations show enhanced growth in response to higher radiation under less cloudy skies, indicating an adequate water supply. Proposed mechanisms include larger soil water store and deeper roots in nature and the ability of roots to move water up and down (hydraulic redistribution). Here we assess the importance of the upward soil water flux from the groundwater driven by capillarity. We present a map of water table depth from observations and groundwater modeling, and a map of potential capillary flux these water table depths can sustain. The maps show that the water table beneath the Amazon can be quite shallow in lowlands and river valleys (<5 m in 36% and <10 m in 60% of Amazonia). The water table can potentially sustain a capillary flux of >2.1 mm day-1 to the land surface averaged over Amazonia, but varies from 0.6 to 3.7 mm day-1 across nine study sites. Current models simulate a large-scale reduction in dry-season photosynthesis under today's climate and a possible dieback under projected future climate with a longer dry season, converting the Amazon from a net carbon sink to a source and accelerating warming. The inclusion of groundwater and capillary flux may modify the model results.
Galosi, Livio; Farneti, Silvana; Rossi, Giacomo; Cork, Susan Catherine; Ferraro, Stefano; Magi, Gian Enrico; Petrini, Stefano; Valiani, Andrea; Cuteri, Vincenzo; Attili, Anna-Rita
2015-09-01
Necropsies were conducted on a female blue-fronted Amazon (Amazona aestiva) and a female yellow-headed Amazon (Amazona oratrix) that died after depression, ruffled feathers, diarrhea, and biliverdin in the urine. Gross and microscopic examinations revealed multifocal necrosis in the liver, spleen, lungs, kidneys, intestines, and heart caused by acute bacteremia. Yersinia pseudotuberculosis, serogroup O:1a, was isolated by culturing from the visceral lesions in the liver, intestines, and spleen. Virulence gene analysis showed the presence of the inv gene and the complete pathogenicity island: IS100, psn, yptE, irp1, irp2 ybtP-ybtQ, ybtX-ybtS, and int asnT-Int. Histopathologic findings and chemical analysis also demonstrated hepatic hemosiderosis. As has been demonstrated in other species, hemosiderosis may predispose Amazona spp. to systemic infection with Y. pseudotuberculosis after enteric disease.
Cloud Condensation Nuclei Activity of Aerosols during GoAmazon 2014/15 Field Campaign Report
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wang, J.; Martin, S. T.; Kleinman, L.
2016-03-01
Aerosol indirect effects, which represent the impact of aerosols on climate through influencing the properties of clouds, remain one of the main uncertainties in climate predictions (Stocker et al. 2013). Reducing this large uncertainty requires both improved understanding and representation of aerosol properties and processes in climate models, including the cloud activation properties of aerosols. The Atmospheric System Research (ASR) science program plan of January 2010 states that: “A key requirement for simulating aerosol-cloud interactions is the ability to calculate cloud condensation nuclei and ice nuclei (CCN and IN, respectively) concentrations as a function of supersaturation from the chemical andmore » microphysical properties of the aerosol.” The Observations and Modeling of the Green Ocean Amazon (GoAmazon 2014/15) study seeks to understand how aerosol and cloud life cycles are influenced by pollutant outflow from a tropical megacity (Manaus)—in particular, the differences in cloud-aerosol-precipitation interactions between polluted and pristine conditions. One key question of GoAmazon2014/5 is: “What is the influence of the Manaus pollution plume on the cloud condensation nuclei (CCN) activities of the aerosol particles and the secondary organic material in the particles?” To address this question, we measured size-resolved CCN spectra, a critical measurement for GoAmazon2014/5.« less
Souza, Marcy J; Sanchez-Migallon Guzman, David; Paul-Murphy, Joanne R; Cox, Sherry K
2012-08-01
To determine pharmacokinetics after IV and oral administration of a single dose of tramadol hydrochloride to Hispaniolan Amazon parrots (Amazona ventralis). 9 healthy adult Hispaniolan Amazon parrots (3 males, 5 females, and 1 of unknown sex). Tramadol (5 mg/kg, IV) was administered to the parrots. Blood samples were collected from -5 to 720 minutes after administration. After a 3-week washout period, tramadol (10 and 30 mg/kg) was orally administered to parrots. Blood samples were collected from -5 to 1,440 minutes after administration. Three formulations of oral suspension (crushed tablets in a commercially available suspension agent, crushed tablets in sterile water, and chemical-grade powder in sterile water) were evaluated. Plasma concentrations of tramadol and its major metabolites were measured via high-performance liquid chromatography. Mean plasma tramadol concentrations were > 100 ng/mL for approximately 2 to 4 hours after IV administration of tramadol. Plasma concentrations after oral administration of tramadol at a dose of 10 mg/kg were < 40 ng/mL for the entire time period, but oral administration at a dose of 30 mg/kg resulted in mean plasma concentrations > 100 ng/mL for approximately 6 hours after administration. Oral administration of the suspension consisting of the chemical-grade powder resulted in higher plasma tramadol concentrations than concentrations obtained after oral administration of the other 2 formulations; however, concentrations differed significantly only at 120 and 240 minutes after administration. Oral administration of tramadol at a dose of 30 mg/kg resulted in plasma concentrations (> 100 ng/mL) that have been associated with analgesia in Hispaniolan Amazon parrots.
NASA Astrophysics Data System (ADS)
Carbone, S.; Brito, J.; Rizzo, L. V.; Holanda, B. A.; Cirino, G. G.; Saturno, J.; Krüger, M. L.; Pöhlker, C.; Ng, N. L.; Xu, L.; Andreae, M. O.; Artaxo, P.
2015-12-01
The study of the chemical composition of aerosol particles in the Amazon forest represents a step forward to understand the strong coupling between the atmosphere and the forest. For this reason submicron aerosol particles were investigated in the Amazon forest, where biogenic and anthropogenic aerosol particles coexist at the different seasons (wet/dry). The measurements were performed at the ATTO station, which is located about 150 km northeast of Manaus. At ATTO station the Aerosol chemical speciation monitor (ACSM, Aerodyne) and the Multiangle absorption photometer (MAAP, Thermo 5012) have been operated continuously from March 2014 to July 2015. In this study, long-term measurements (near-real-time, ~30 minutes) of PM1 chemical composition were investigated for the first time in this environment.The wet season presented lower concentrations than the dry season (~5 times). In terms of chemical composition, both seasons were dominated by organics (75 and 63%) followed by sulfate (11 and 13%). Nitrate presented different ratio values between the mass-to-charges 30 to 46 (main nitrate fragments) suggesting the presence of nitrate as inorganic and organic nitrate during both seasons. The results indicated that about 75% of the nitrate signal was from organic nitrate during the dry season. In addition, several episodes with elevated amount of chloride, likely in the form of sea-salt from the Atlantic Ocean, were observed during the wet season. During those episodes, chloride comprised up to 7% of the PM1. During the dry season, chloride was also observed; however, with different volatility, which suggested that Chloride was present in different form and source. Moreover, the constant presence of sulfate and BC during the wet season might be related to biomass burning emissions from Africa. BC concentration was 2.5 times higher during the dry season. Further characterization of the organic fraction was accomplished with the positive matrix factorization (PMF), which revealed four different organic aerosol components with very distinct chemical characteristics for the dry season and three for the wet season.
Impact of implementation of spaceborne lidar-retrieved canopy height in the WRF model
NASA Astrophysics Data System (ADS)
Lee, Junhong; Hong, Jinkyu
2017-04-01
Canopy height is closely related to biomass and aerodynamic properties, which regulate turbulent transfer of energy and mass at the soil-vegetation-atmosphere continuum. However, this key information has been prescribed as a constant value in a fixed plant functional type in atmospheric models. This presentation reports impacts of using realistic forest canopy height, retrieved from spaceborne LiDAR, on regional climate simulation in the Weather Research and Forecasting (WRF) model's land surface model. Numerical simulations were conducted over the Amazon Basin and East Asia during summer season. Over these regions, the LiDAR-retrieved canopy heights were higher than the default values used in the WRF,which are dependent only on plant functional type. By modifying roughness length and zero-plane displacement height, the change of canopy height resulted in changes in surface energy balance by regulating aerodynamic conductances and vertical temperature gradient, thus modifying the lifting condensation level and equivalent potential temperature in the atmospheric boundary layer. Our analysis also showed that the WRF model better reproduced the observed precipitation when LiDAR-retrieved canopy height was used over the Amazon Basin.
Implementation of spaceborne lidar-retrieved canopy height in the WRF model
NASA Astrophysics Data System (ADS)
Lee, Junhong; Hong, Jinkyu
2016-06-01
Canopy height is closely related to biomass and aerodynamic properties, which regulate turbulent transfer of energy and mass at the soil-vegetation-atmosphere continuum. However, this key information has been prescribed as a constant value in a fixed plant functional type in atmospheric models. This paper is the first to report impacts of using realistic forest canopy height, retrieved from spaceborne lidar, on regional climate simulation by using the canopy height data in the Weather Research and Forecasting (WRF) model's land surface model. Numerical simulations were conducted over the Amazon Basin during summer season. Over this region, the lidar-retrieved canopy heights were higher than the default values used in the WRF, which are dependent only on plant functional type. By modifying roughness length and zero-plane displacement height, the change of canopy height resulted in changes in surface energy balance by regulating aerodynamic conductances and vertical temperature gradient, thus modifying the lifting condensation level and equivalent potential temperature in the atmospheric boundary layer. Our analysis also showed that the WRF model better reproduced the observed precipitation when lidar-retrieved canopy height was used over the Amazon Basin.
Schaffer, Débora P H; de Araújo, Nayone L L C; Raposo, Ana Cláudia S; Filho, Emanoel F Martins; Vieira, João Victor R; Oriá, Arianne P
2017-09-01
Safe and effective sedation protocols are important for chemical restraint of birds in clinical and diagnostic procedures, such as clinical evaluations, radiographic positioning, and blood collection. These protocols may reduce stress and ease the management of wild-caught birds, which are susceptible to injury or death when exposed to stressful situations. We compare the sedative effect of intranasal midazolam in wild-caught blue-fronted (Amazona aestiva) and orange-winged (Amazona amazonica) Amazon parrots. Ten adult parrots of each species (n = 20), of unknown sex, weighing 0.337 ± 0.04 (blue-fronted) and 0.390 ± 0.03 kg (orange-winged), kg were used. Midazolam (2 mg/kg) was administered intranasally and the total volume of the drug was divided equally between the 2 nostrils. Onset time and total sedation time were assessed. Satisfactory sedation for clinical evaluation was induced in all birds. Onset time and total sedation times were similar in both species: 5.36 ± 1.16 and 25.40 ± 5.72 minutes, respectively, for blue-fronted Amazons and 5.09 ± 0.89 and 27.10 ± 3.73 minutes, respectively, for orange-winged Amazons. A total of 15 animals showed absence of vocalization, with moderate muscle relaxation and wing movement upon handling, and 2 animals presented with lateral recumbence, with intense muscle relaxation and no wing movement, requiring no restraint. Three blue-fronted Amazons had no effective sedation. Intranasally administered midazolam at a dose of 2 mg/kg effectively promoted sedative effects with a short latency time and fast recovery in wild-caught parrots.
Martin, S. T.; Artaxo, P.; Machado, L.; ...
2017-05-15
The Observations and Modeling of the Green Ocean Amazon 2014–2015 (GoAmazon2014/5) experiment took place around the urban region of Manaus in central Amazonia across 2 years. The urban pollution plume was used to study the susceptibility of gases, aerosols, clouds, and rainfall to human activities in a tropical environment. Many aspects of air quality, weather, terrestrial ecosystems, and climate work differently in the tropics than in the more thoroughly studied temperate regions of Earth. GoAmazon2014/5, a cooperative project of Brazil, Germany, and the United States, employed an unparalleled suite of measurements at nine ground sites and on board two aircraftmore » to investigate the flow of background air into Manaus, the emissions into the air over the city, and the advection of the pollution downwind of the city. Here in this paper, to visualize this train of processes and its effects, observations aboard a low-flying aircraft are presented. Comparative measurements within and adjacent to the plume followed the emissions of biogenic volatile organic carbon compounds (BVOCs) from the tropical forest, their transformations by the atmospheric oxidant cycle, alterations of this cycle by the influence of the pollutants, transformations of the chemical products into aerosol particles, the relationship of these particles to cloud condensation nuclei (CCN) activity, and the differences in cloud properties and rainfall for background compared to polluted conditions. The observations of the GoAmazon2014/5 experiment illustrate how the hydrologic cycle, radiation balance, and carbon recycling may be affected by present-day as well as future economic development and pollution over the Amazonian tropical forest.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Martin, S. T.; Artaxo, P.; Machado, L.
The Observations and Modeling of the Green Ocean Amazon 2014–2015 (GoAmazon2014/5) experiment took place around the urban region of Manaus in central Amazonia across 2 years. The urban pollution plume was used to study the susceptibility of gases, aerosols, clouds, and rainfall to human activities in a tropical environment. Many aspects of air quality, weather, terrestrial ecosystems, and climate work differently in the tropics than in the more thoroughly studied temperate regions of Earth. GoAmazon2014/5, a cooperative project of Brazil, Germany, and the United States, employed an unparalleled suite of measurements at nine ground sites and on board two aircraftmore » to investigate the flow of background air into Manaus, the emissions into the air over the city, and the advection of the pollution downwind of the city. Here in this paper, to visualize this train of processes and its effects, observations aboard a low-flying aircraft are presented. Comparative measurements within and adjacent to the plume followed the emissions of biogenic volatile organic carbon compounds (BVOCs) from the tropical forest, their transformations by the atmospheric oxidant cycle, alterations of this cycle by the influence of the pollutants, transformations of the chemical products into aerosol particles, the relationship of these particles to cloud condensation nuclei (CCN) activity, and the differences in cloud properties and rainfall for background compared to polluted conditions. The observations of the GoAmazon2014/5 experiment illustrate how the hydrologic cycle, radiation balance, and carbon recycling may be affected by present-day as well as future economic development and pollution over the Amazonian tropical forest.« less
The Amazon Boundary-Layer Experiment (ABLE 2B) - A meteorological perspective
NASA Technical Reports Server (NTRS)
Garstang, Michael; Greco, Steven; Scala, John; Swap, Robert; Ulanski, Stanley; Fitzjarrald, David; Martin, David; Browell, Edward; Shipman, Mark; Connors, Vickie
1990-01-01
The Amazon Boundary-Layer Experiments (ABLE) 2A and 2B, which were performed near Manaus, Brazil in July-August, 1985, and April-May, 1987 are discussed. The experiments were performed to study the sources, sinks, concentrations, and transports of trace gases and aerosols in rain forest soils, wetlands, and vegetation. Consideration is given the design and preliminary results of the experiment, focusing on the relationships between meteorological scales of motion and the flux, transports, and reactions of chemical species and aerosols embedded in the atmospheric fluid. Meteorological results are presented and the role of the meteorological results in the atmospheric chemistry experiment is examined.
Aston, Emily J; Mayor, Pedro; Bowman, Dwight D; Mohammed, Hussni O; Liotta, Janice L; Kwok, Oliver; Dubey, J P
2014-04-01
Toxoplasmosis is a zoonosis caused by the protozoan Toxoplasma gondii, and it is found worldwide. To determine whether ungulates are reservoirs of T. gondii in an isolated and remote region of the northeastern Peruvian Amazon, antibodies to T. gondii were determined in 5 species of ungulates by the modified agglutination test (MAT). These animals were hunted by subsistence hunters along the Yavarí-Mirín River, in the northeastern Peruvian Amazon. Blood samples were collected by hunters on filter papers. For determination of T. gondii antibodies, blood was eluted from filter papers, and a titer of 1:25 was considered indicative of exposure to T. gondii. Antibodies to T. gondii were found in 26 (31.0%) peccaries (Pecari tajacu, Tayassu pecari), six (17.1%) brocket deer (Mazama americana, Mazama gouazoubira), and four (40.0%) lowland tapir (Tapirus terrestris). We also introduced a modification to the MAT protocol that allows the extraction of fluid samples from several types of laboratory-grade filter paper, thus enabling researchers to easily adapt their approaches to the materials presented to them.
Seasonal uranium distributions in the coastal waters off the Amazon and Mississippi Rivers
Swarzenski, P.W.; McKee, B.A.
1998-01-01
The chemical reactivity of uranium was investigated across estuarine gradients from two of the world's largest river systems: the Amazon and Mississippi. Concentrations of dissolved (<0.45 ??m) uranium (U) were measured in surface waters of the Amazon shelf during rising (March 1990), flood (June 1990) and low (November 1991) discharge regimes. The dissolved U content was also examined in surface waters collected across estuarine gradients of the Mississippi outflow region during April 1992, August 1993, and November (1993). All water samples were analyzed for U by isotope dilution inductively coupled plasma mass spectrometry (ICP-MS). In Amazon shelf surface waters uranium increased nonconservatively from about 0.01 ??g l-1 at the river's mouth to over 3 ??g l-1 at the distal site, irrespective of river discharge stage. Observed large-scale U removal at salinities generally less than 15 implies a) that riverine dissolved U was extensively adsorbed by freshly-precipitated hydrous metal oxides (e.g., FeOOH, MnO2) as a result of flocculation and aggregation, and b) that energetic resuspension and reworking of shelf sediments and fluid muds on the Amazon shelf released a chemically reactive particle/colloid to the water column which can further scavenge dissolved U across much of the estuarine gradient. In contrast, the estuarine chemistry of U is inconclusive within surface waters of the Mississippi shelf-break region. U behavior is most likely controlled less by traditional sorption and/or desorption reactions involving metal oxides or colloids than by the river's variable discharge regime (e.g., water parcel residence time during estuarine mixing, nature of particulates, sediment storage and resuspension in the confined lower river), and plume dispersal. Mixing of the thin freshwater lens into ambient seawater is largely defined by wind-driven rather than physical processes. As a consequence, in the Mississippi outflow region uranium predominantly displays ConserVative behavior; removal is evident only during anomalous river discharge regimes. 'Products-approach' mixing experiments conducted during the Flood of 1993 suggest the importance of small particles and/or colloids in defining a depleted U versus salinity distribution.
T.P. Beldini; R.C. Oliveira Junior; Michael Keller; P.B. de Camargo; P.M. Crill; A. Damasceno da Silva; D. Bentes dos Santos; D. Rocha de Oliveira
2015-01-01
Land-use change in the Amazon basin has occurred at an accelerated pace during the last decade, and it is important that the effects induced by these changes on soil properties are better understood. This study investigated the chemical, physical, and biological properties of soil in a field under cultivation of soy and rice, and at an adjacent primary rain forest....
GoAmazon2014/15. Oxidation Flow Reactor Final Campaign Report
DOE Office of Scientific and Technical Information (OSTI.GOV)
Jimenez, J. L.; Day, D. A.; Hu, W.
The primary goal of the Green Ocean Amazon (GoAmazon2014/5) field campaign was to measure and mechanistically understand the formation of particle number and mass in a region affected by large tropical rainforest biogenic emissions and sometimes anthropogenic influence from a large urban center. As part of the two intensive operational periods (IOPs) and in collaboration with Pacific Northwest National Laboratory (PNNL) and Harvard, the Jimenez Group proposed to deploy a High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS), Thermal Denuder (TD), Scanning Mobility Particle Size (SMPS), two oxidation flow reactors (OFR; including supporting O 3, CO/CO 2/CH 4, RH analyzers), and amore » high volume filter sampler (MCV) for the measurement of gas and aerosol chemical, physicochemical, and volatility properties. The two IOPs were conducted during the wet season (February to March, 2014) and dry season (August to October, 2014). This proposal was part of a collaborative proposal involving other university and government laboratories.« less
Amazon Rain Forest Classification Using J-ERS-1 SAR Data
NASA Technical Reports Server (NTRS)
Freeman, A.; Kramer, C.; Alves, M.; Chapman, B.
1994-01-01
The Amazon rain forest is a region of the earth that is undergoing rapid change. Man-made disturbance, such as clear cutting for agriculture or mining, is altering the rain forest ecosystem. For many parts of the rain forest, seasonal changes from the wet to the dry season are also significant. Changes in the seasonal cycle of flooding and draining can cause significant alterations in the forest ecosystem.Because much of the Amazon basin is regularly covered by thick clouds, optical and infrared coverage from the LANDSAT and SPOT satellites is sporadic. Imaging radar offers a much better potential for regular monitoring of changes in this region. In particular, the J-ERS-1 satellite carries an L-band HH SAR system, which via an on-board tape recorder, can collect data from almost anywhere on the globe at any time of year.In this paper, we show how J-ERS-1 radar images can be used to accurately classify different forest types (i.e., forest, hill forest, flooded forest), disturbed areas such as clear cuts and urban areas, and river courses in the Amazon basin. J-ERS-1 data has also shown significant differences between the dry and wet season, indicating a strong potential for monitoring seasonal change. The algorithm used to classify J-ERS-1 data is a standard maximum-likelihood classifier, using the radar image local mean and standard deviation of texture as input. Rivers and clear cuts are detected using edge detection and region-growing algorithms. Since this classifier is intended to operate successfully on data taken over the entire Amazon, several options are available to enable the user to modify the algorithm to suit a particular image.
Preliminary characterization of submicron secondary aerosol in the amazon forest - ATTO station
NASA Astrophysics Data System (ADS)
Carbone, S.; Ferreira De Brito, J.; Andreae, M. O.; Pöhlker, C.; Chi, X.; Saturno, J.; Barbosa, H. M.; Artaxo, P.
2014-12-01
Biogenic secondary organic aerosol particles are investigated in the Amazon in the context of the GoAmazon Project. The forest naturally emits a large number of gaseous compounds; they are called the volatile organic compounds (VOCs). They are emitted through processes that are not totally understood. Part of those gaseous compounds are converted into aerosol particles, which affect the biogeochemical cycles, the radiation balance, the mechanisms involving cloud formation and evolution, among few other important effects. In this study the aerosol life-cycle is investigated at the ATTO station, which is located about 150 km northeast of Manaus, with emphasis on the natural organic component and its impacts in the ecosystem. To achieve these objectives physical and chemical aerosol properties have been investigated, such as the chemical composition with aerosol chemical speciation monitor (ACSM), nanoparticle size distribution (using the SMPS - Scanning Mobility Particle Sizer), optical properties with measurements of scattering and absorption (using nephelometers and aethalometers). Those instruments have been operating continuously since February 2014 together with trace gases (O3, CO2, CO, SO2 and NOx) analyzers and additional meteorological instruments. On average PM1 (the sum of black carbon, organic and inorganic ions) totalized 1.0±0.3 μg m-3, where the organic fraction was dominant (75%). During the beginning of the dry season (July/August) the organic aerosol presented a moderate oxygenated character with the oxygen to carbon ratio (O:C) of 0.7. In the wet season some episodes containing significant amount of chloride and backward wind trajectories suggest aerosol contribution from the Atlantic Ocean. A more comprehensive analysis will include an investigation of the different oxidized fractions of the organic aerosol and optical properties.
Water contamination from oil extraction activities in Northern Peruvian Amazonian rivers.
Yusta-García, Raúl; Orta-Martínez, Martí; Mayor, Pedro; González-Crespo, Carlos; Rosell-Melé, Antoni
2017-06-01
Oil extraction activities in the Northern Peruvian Amazon have generated a long-standing socio-environmental conflict between oil companies, governmental authorities and indigenous communities, partly derived from the discharge of produced waters containing high amounts of heavy metals and hydrocarbons. To assess the impact of produced waters discharges we conducted a meta-analysis of 2951 river water and 652 produced water chemical analyses from governmental institutions and oil companies reports, collected in four Amazonian river basins (Marañon, Tigre, Corrientes and Pastaza) and their tributaries. Produced water discharges had much higher concentrations of chloride, barium, cadmium and lead than are typically found in fresh waters, resulting in the widespread contamination of the natural water courses. A significant number of water samples had levels of cadmium, barium, hexavalent chromium and lead that did not meet Peruvian and international water standards. Our study shows that spillage of produced water in Peruvian Amazon rivers placed at risk indigenous population and wildlife during several decades. Furthermore, the impact of such activities in the headwaters of the Amazon extended well beyond the boundaries of oil concessions and national borders, which should be taken into consideration when evaluating large scale anthropogenic impacts in the Amazon. Copyright © 2017 Elsevier Ltd. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Guerra, Denis L., E-mail: denis@cpd.ufmt.b; Leidens, Victor L.; Viana, Rubia R.
2010-05-15
The compound N{sup 1}-[3-(trimethoxysilyl)propyl]diethylenetriamine was anchored onto Amazon kaolinite surface by heterogeneous route. The modified and natural kaolinite samples were characterized by transmission electron microscopy, scanning electron microscopic, X-ray diffraction, and nuclear magnetic nuclei of {sup 29}Si and {sup 13}C. The well-defined peaks obtained in the {sup 13}C NMR spectrum in the 5.0-62.1 ppm region confirmed the attachment of organic functional groups as pendant chains bonded into the porous clay. The ability of these materials to remove U(VI) from aqueous solution was followed by a series of adsorption isotherms adjusted to a Sips equation at room temperature and pH 4.0.more » The kinetic parameters analyzed by the Lagergren and Elovich models gave a good fit for a pseudo-second order reaction with k{sub 2} values 16.0 and 25.1 mmol g{sup -1} min{sup -1} ranges for natural and modified kaolinite clays, respectively. The energetic effects caused by metal ion adsorption were determined through calorimetric titrations. - Graphical abstract: This investigation reports the use of original and modified kaolinites as alternative absorbents. The compound N-[3-trimethoxysilyl)propyl]diethylenetriamine was anchored onto Amazon kaolinite surface by heterogeneous route.« less
A global perspective on the influence of environmental exposures on the nervous system.
Tshala-Katumbay, Desire; Mwanza, Jean-Claude; Rohlman, Diane S; Maestre, Gladys; Oriá, Reinaldo B
2015-11-19
Economic transitions in the era of globalization warrant a fresh look at the neurological risks associated with environmental change. These are driven by industrial expansion, transfer and mobility of goods, climate change and population growth. In these contexts, risk of infectious and non-infectious diseases are shared across geographical boundaries. In low- and middle-income countries, the risk of environmentally mediated brain disease is augmented several fold by lack of infrastructure, poor health and safety regulations, and limited measures for environmental protection. Neurological disorders may occur as a result of direct exposure to chemical and/or non-chemical stressors, including but not limited to, ultrafine particulate matters. Individual susceptibilities to exposure-related diseases are modified by genetic, epigenetic and metagenomic factors. The existence of several uniquely exposed populations, including those in the areas surrounding the Niger Delta or north western Amazon oil operations; those working in poorly regulated environments, such as artisanal mining industries; or those, mostly in sub-Saharan Africa, relying on cassava as a staple food, offers invaluable opportunities to advance the current understanding of brain responses to environmental challenges. Increased awareness of the brain disorders that are prevalent in low- and middle-income countries and investments in capacity for further environmental health-related research are positive steps towards improving human health.
A global perspective on the influence of environmental exposures on the nervous system
Tshala-Katumbay, Desire; Mwanza, Jean-Claude; Rohlman, Diane S.; Maestre, Gladys; Oriá, Reinaldo B.
2016-01-01
Economic and social transitions in the era of globalization warrant a fresh look at the neurological risks associated with environmental change. These are driven by industrial expansion, transfer and mobility of goods, climate change and population growth. In these contexts, risk of both infectious and non-infectious diseases are shared across geographical boundaries. In low- and middle-income countries, the risk of environmentally mediated brain disease is augmented several-fold by lack of infrastructure, poor health and safety regulations, and limited measures for environmental protection. Neurological disorders may occur as a result of direct exposure to chemical and/or non-chemical stressors such as ultrafine particulate matters. Individual susceptibilities to exposure-related diseases are modified by genetic, epigenetic and metagenomic factors. The existence of several uniquely exposed populations, including those in the areas surrounding the Niger Delta or north western Amazon oil operations; those working in poorly regulated environments, such as artisanal mining industries; or those, mostly in sub-Saharan Africa, relying on cassava as a staple food, offers invaluable opportunities to advance the current understanding of brain responses to environmental challenges. Increased awareness of the brain disorders that are prevalent in low- and middle-income countries and investments in capacity for further environmental health-related research are positive steps towards improving human health. PMID:26580326
Lambs, L; Horwath, A; Otto, T; Julien, F; Antoine, P-O
2012-04-15
The Amazon River is a huge network of long tributaries, and little is known about the headwaters. Here we present a study of one wet tropical Amazon forest side, and one dry and cold Atiplano plateau, originating from the same cordillera. The aim is to see how this difference affects the water characteristics. Different kind of water (spring, lake, river, rainfall) were sampled to determine their stable isotopes ratios (oxygen 18/16 and hydrogen 2/1) by continuous flow isotope ratio mass spectrometry (IRMS). These ratios coupled with chemical analysis enabled us to determine the origin of the water, the evaporation process and the water recycling over the Amazon plain forest and montane cloud forest. Our study shows that the water flowing in the upper Madre de Dios basin comes mainly from the foothill humid forest, with a characteristic water recycling process signature, and not from higher glacier melt. On the contrary, the water flowing in the Altiplano Rivers is mainly from glacier melts, with a high evaporation process. This snow and glacier are fed mainly by Atlantic moisture which transits over the large Amazon forest. The Atlantic moisture and its recycling over this huge tropical forest display a progressive isotopic gradient, as a function of distance from the ocean. At the level of the montane cloud forest and on the altiplano, respectively, additional water recycling and evaporation occur, but they are insignificant in the total water discharge. Copyright © 2012 John Wiley & Sons, Ltd.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Martin, S. T.; Artaxo, P.; Machado, L.
The Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5) experiment took place around the urban region of Manaus in central Amazonia across two years. The urban pollution plume was used to study the susceptibility of gases, aerosols, clouds, and rainfall to human activities in a tropical environment. Many aspects of air quality, weather, terrestrial ecosystems, and climate work differently in the tropics than in the more thoroughly studied USA, employed an unparalleled suite of measurements at nine ground sites and onboard two aircraft to investigate the flow of background air into Manaus, the emissions into the air over themore » city, and the advection of the pollution downwind of the city. Herein, to visualize this train of processes and its effects, observations aboard a low-flying aircraft are presented. Comparative measurements within and adjacent to the plume followed the emissions of biogenic volatile organic carbon compounds (BVOCs) from the tropical forest, their transformations by the atmospheric oxidant cycle, alterations of this cycle by the influence of the pollutants, transformations of the chemical products into aerosol particles, the relationship of these particles to cloud condensation nuclei (CCN) activity, and the differences in cloud properties and rainfall for background compared to polluted conditions. The observations of the GoAmazon2014/5 experiment illustrate how the hydrologic cycle, radiation balance, and carbon recycling may be affected by present-day as well as future economic development and pollution over the Amazonian tropical forest.« less
GoAmazon2014/5 campaign points to deep-inflow approach to deep convection across scales.
Schiro, Kathleen A; Ahmed, Fiaz; Giangrande, Scott E; Neelin, J David
2018-05-01
A substantial fraction of precipitation is associated with mesoscale convective systems (MCSs), which are currently poorly represented in climate models. Convective parameterizations are highly sensitive to the assumptions of an entraining plume model, in which high equivalent potential temperature air from the boundary layer is modified via turbulent entrainment. Here we show, using multiinstrument evidence from the Green Ocean Amazon field campaign (2014-2015; GoAmazon2014/5), that an empirically constrained weighting for inflow of environmental air based on radar wind profiler estimates of vertical velocity and mass flux yields a strong relationship between resulting buoyancy measures and precipitation statistics. This deep-inflow weighting has no free parameter for entrainment in the conventional sense, but to a leading approximation is simply a statement of the geometry of the inflow. The structure further suggests the weighting could consistently apply even for coherent inflow structures noted in field campaign studies for MCSs over tropical oceans. For radar precipitation retrievals averaged over climate model grid scales at the GoAmazon2014/5 site, the use of deep-inflow mixing yields a sharp increase in the probability and magnitude of precipitation with increasing buoyancy. Furthermore, this applies for both mesoscale and smaller-scale convection. Results from reanalysis and satellite data show that this holds more generally: Deep-inflow mixing yields a strong precipitation-buoyancy relation across the tropics. Deep-inflow mixing may thus circumvent inadequacies of current parameterizations while helping to bridge the gap toward representing mesoscale convection in climate models.
Viers, Jérôme; Barroux, Guénaël; Pinelli, Marcello; Seyler, Patrick; Oliva, Priscia; Dupré, Bernard; Boaventura, Geraldo Resende
2005-03-01
The purpose of this paper is to forecast the role of riverine wetlands in the transfer of trace elements. One of the largest riverine wetlands in the world is the floodplain (várzea) of the Amazon River and its tributaries (Junk and Piedade, 1997). The central Amazon wetlands are constituted by a complex network of lakes and floodplains, named várzeas, that extend over more than 300,000 km2 (Junk, W.J., The Amazon floodplain--a sink or source for organic carbon? In Transport of Carbon and Minerals in Major World Rivers, edited by E.T. Degens, S. Kempe, R. Herrera, SCOPE/UNEP; 267-283, 1985.) and are among the most productive ecosystems in the world due to the regular enrichment in nutrients by river waters In order to understand if the adjacent floodplain of Amazon River have a significant influence on the trace element concentrations and fluxes of the mainstem, the concentrations of selected elements (i.e., Al, Mn, Fe, Co, Cu, Mo, Rb, Sr, Ba, and U) have been measured in the Amazon River water (Manacapuru Station, Amazonas State, Brazil) and in lake waters and plants (leaves) from a várzea(Ilha de Marchantaria, Amazonas State, Brazil) during different periods of the hydrological cycle. Four plant species (two perennial species: Pseudobombax munguba and Salix humboldtiana, and two annual herbaceous plants: Echinochloa polystachya and Eichhornia crassipes) were selected to represent the ecological functioning of the site. Time series obtained for dissolved Mn and Cu (<0.20 microm) in Amazon River water could not be explained by tributary mixing or instream processes only. Therefore, the contribution of the waters transiting the floodplains should be considered. These results suggest that the chemical composition of the waters draining these floodplains is controlled by reactions occurring at sediment-water and plant-water interfaces. Trace elements concentrations in the plants (leaves) vary strongly with hydrological seasonality. Based on the concentration data and the biological productivity of floodplain ecosystems, a first order approximation of trace element storage (permanent or temporary) in the vegetation of these floodplains was made. It was found that floodplain-mainstem elemental fluxes make a significant contribution to the dissolved flux of the Amazon River. This study is part of the Brazilian_French joint research program Hybam (Hydrology and Geochemistry of the Amazonian Basin).
Chemical Imaging and Stable Isotope Analysis of Atmospheric Particles by NanoSIMS (Invited)
NASA Astrophysics Data System (ADS)
Sinha, B.; Harris, E. J.; Pöhlker, C.; Wiedemann, K. T.; van Pinxteren, D.; Tilgner, A.; Fomba, K. W.; Schneider, J.; Roth, A.; Gnauk, T.; Fahlbusch, B.; Mertes, S.; Lee, T.; Collett, J. L.; Shiraiwa, M.; Gunthe, S. S.; Smith, M.; Artaxo, P. P.; Gilles, M.; Kilcoyne, A. L.; Moffet, R.; Weigand, M.; Martin, S. T.; Poeschl, U.; Andreae, M. O.; Hoppe, P.; Herrmann, H.; Borrmann, S.
2013-12-01
Chemical imaging analysis of the internal distribution of chemical compounds by a combination of SEM-EDX, and NanoSIMS allows investigating the physico-chemical properties and isotopic composition of individual aerosol particles. Stable sulphur isotope analysis provides insight into the sources, sinks and oxidation pathways of SO2 in the environment. Oxidation by OH radicals, O3 and H2O2 enriches the heavier isotope in the product sulphate, whereas oxidation by transition metal ions (TMI), hypohalites and hypohalous acids depletes the heavier isotope in the product sulphate. The isotope fractionation during SO2 oxidation by stabilized Criegee Intermediate radicals is unknown. We studied the relationship between aerosol chemical composition and predominant sulphate formation pathways in continental clouds in Central Europe and during the wet season in the Amazon rain forest. Sulphate formation in continental clouds in Central Europe was studied during HCCT-2010, a lagrangian-type field experiment, during which an orographic cloud was used as a natural flow-through reactor to study in-cloud aerosol processing (Harris et al. 2013). Sulphur isotopic compositions in SO2 and H2SO4 gas and particulate sulphate were measured and changes in the sulphur isotope composition of SO2 between the upwind and downwind measurement sites were used to determine the dominant SO2 chemical removal process occurring in the cloud. Changes in the isotopic composition of particulate sulphate revealed that transition metal catalysis pathway was the dominant SO2 oxidation pathway. This reaction occurred primarily on coarse mineral dust particles. Thus, sulphate produced due to in-cloud SO2 oxidation is removed relatively quickly from the atmosphere and has a minor climatic effect. The aerosol samples from the Amazonian rainforest, a pristine tropical environment, were collected during the rainy season. The samples were found to be dominated by SOA particles in the fine mode and primary biological aerosol particles in the coarse mode (Pöhlker et al. 2012). We applied STXM-NEXAFS analysis, SEM-EDX analysis and NanoSIMS analysis to investigate the morphology, chemical composition and isotopic composition of aerosol samples. Biogenic salt particles emitted from active biota in the rainforest were found to be enriched in the heavier sulphur isotope, whereas particles with a high organic mass fraction modified by condensation of VOC oxidation products and/or cloud processing were significantly depleted in the heavier sulphur isotope compared to the seed particles. This indicates either a depleted gas phase source of sulphur dioxide contributed to the sulphate formation via the H2O2, O3 or OH oxidation pathway or an unaccounted reaction pathway which depletes the heavier isotope in the product sulphate contributes to the secondary sulphate formation in the pristine Amazon rainforest. Harris, E., et al., Science 340, 727-730, 2013 Pöhlker, C., Science 337, 1075-1078, 2012
da SILVA, Juliana Paola Corrêa; de CASTILHO, Adriana Lígia; SARACENI, Cíntia Helena Couri; DÍAZ, Ingrit Elida Collantes; PACIÊNCIA, Mateus Luís Barradas; SUFFREDINI, Ivana Barbosa
2014-01-01
Caries is a global public health problem, whose control requires the introduction of low-cost treatments, such as strong prevention strategies, minimally invasive techniques and chemical prevention agents. Nature plays an important role as a source of new antibacterial substances that can be used in the prevention of caries, and Brazil is the richest country in terms of biodiversity. Objective In this study, the disk diffusion method (DDM) was used to screen over 2,000 Brazilian Amazon plant extracts against Streptococcus mutans. Material and Methods Seventeen active plant extracts were identified and fractionated. Extracts and their fractions, obtained by liquid-liquid partition, were tested in the DDM assay and in the microdilution broth assay (MBA) to determine their minimal inhibitory concentrations (MICs) and minimal bactericidal concentrations (MBCs). The extracts were also subjected to antioxidant analysis by thin layer chromatography. Results EB271, obtained from Casearia spruceana, showed significant activity against the bacterium in the DDM assay (20.67±0.52 mm), as did EB1129, obtained from Psychotria sp. (Rubiaceae) (15.04±2.29 mm). EB1493, obtained from Ipomoea alba, was the only extract to show strong activity against Streptococcus mutans (0.08 mg/mL
Béliveau, Annie; Lucotte, Marc; Davidson, Robert; Lopes, Luis Otávio do Canto; Paquet, Serge
2009-07-15
In the Brazilian Amazon, forest conversion to agricultural lands (slash-and-burn cultivation) contributes to soil mercury (Hg) release and to aquatic ecosystem contamination. Recent studies have shown that soil Hg loss occurs rapidly after deforestation, suggesting that Hg mobility could be related to the massive cation input resulting from biomass burning. The objective of this research was to determine the effects of the first year of slash-and-burn agriculture on soil Hg levels at the regional scale of the Tapajós River, in the state of Pará, Brazilian Amazon. A total of 429 soil samples were collected in 26 farms of five riparian communities of the Tapajós basin. In September 2004, soil samples were collected from primary forest sites planned for slash-and-burn cultivation. In August 2005, one year after the initial burning, a second campaign was held and the exact same sites were re-sampled. Our results showed that total Hg levels in soils did not change significantly during the first year following slash-and-burn, suggesting no immediate release of soil Hg at that point in time. However, an early Hg mobility was detected near the surface (0-5 cm), reflected by a significant shift in Hg distribution in soil fractions. Indeed, a transfer of Hg from fine to coarser soil particles was observed, indicating that chemical bonds between Hg and fine particles could have been altered. A correspondence analysis (CA) showed that this process could be linked to a chemical competition caused by cation enrichment. The regional dimension of the study highlighted the prevailing importance of soil types in Hg dynamics, as shown by differentiated soil responses following deforestation according to soil texture. Confirming an early Hg mobility and indicating an eventual Hg release out of the soil, our results reinforce the call for the development of more sustainable agricultural practices in the Amazon.
Effects of future land use on biogeography of aquatic ecosystems of Amazonia
NASA Astrophysics Data System (ADS)
Howard, E. A.; Coe, M. T.; Foley, J. A.; Costa, M. H.
2006-12-01
Amazonian ecosystems provide key ecosystem services, such as regulating the amount and timing of water and carbon flows through the Amazon Basin. Land use in these ecosystems affects regional water balance, which in turn affects biogeography of aquatic ecosystems, including wetlands and floodplains. We combined a hydrological model (Terrestrial Hydrology Model with Biogeochemistry, THMB), remote sensing observations (Hess et al. 2003), and empirical data to identify the distribution of aquatic biogeographic types throughout the central Amazon basin over time. We explored how future land-use scenarios for the Amazon Basin through 2030 (Soares-Filho et al. 2004) would modify the spatial and temporal patterns of aquatic ecosystems as compared to a baseline of natural potential vegetation cover under historical climate variability for the 20th century. We calibrated monthly simulation results with remotely sensed observations of flooded area and extent of different wetland categories for high and low water periods over a 1.7 million sq. km region of the central Amazon. Two additional dimensions of floodplain biogeography (river size and color) were added to provide insight into the geographic distribution of key ecosystem types and their flooding seasonality. For historical conditions, the model results reproduced regional differences in seasonal flood extent and timing north and south of the Amazon mainstem, reflecting the dominant climatic regimes. Black-water streams and medium-sized rivers, followed by large white-water rivers, were the most extensive types across the study region. However much of the black water was in areas likely to be influenced by white-water rivers while flooded. The monthly extent of flooded areas dominated by woody vegetation was consistently more strongly seasonal than non-woody areas. Also, the extent of flooding in muddy and semi-muddy rivers and floodplains tended to be more highly seasonal than in black- and clear-water areas. We discuss our efforts to use our simulation results to extrapolate and bound estimates and patterns of aquatic ecosystem extent in the Amazon River system under future land-use scenarios. Regional flooding variability has disproportionate effects on different ecosystem types, suggesting that persistent, long-term changes to flooding regimes may have long-lasting consequences for floodplain vegetation, wildlife, and human residents.
NASA Astrophysics Data System (ADS)
Beck, V.; Gerbig, C.; Koch, T.; Bela, M. M.; Longo, K. M.; Freitas, S. R.; Kaplan, J. O.; Prigent, C.; Bergamaschi, P.; Heimann, M.
2012-09-01
The Amazon region as a large source of methane (CH4) contributes significantly to the global annual CH4 budget. For the first time in the Amazon region, a forward and inverse modelling framework on regional scale for the purpose of assessing the CH4 budget of the Amazon region is implemented. Here, we present forward simulations of CH4 based on a modified version of the Weather Research and Forecasting model with chemistry that allows for passive tracer transport of CH4, carbon monoxide, and carbon dioxide (WRF-GHG), in combination with two different process-based bottom-up models of CH4 emissions from anaerobic microbial production in wetlands and additional datasets prescribing CH4 emissions from other sources such as biomass burning, termites, or other anthropogenic emissions. We compare WRF-GHG simulations on 10 km horizontal resolution to flask and continuous CH4 observations obtained during two airborne measurement campaigns within the Balanço Atmosférico Regional de Carbono na Amazônia (BARCA) project in November 2008 and May 2009. In addition, three different wetland inundation maps, prescribing the fraction of inundated area per grid cell, are evaluated. Our results indicate that the wetland inundation map with inundated area changing in time represents the observations best except for the northern part of the Amazon basin and the Manaus area. WRF-GHG was able to represent the observed CH4 mixing ratios best at days with less convective activity. After adjusting wetland emissions to match the averaged observed mixing ratios of flights with little convective activity, the monthly CH4 budget of the Amazon lowland region obtained from four different simulations ranges from 1.5 to 4.8 Tg for November 2008 and from 1.3 to 5.5 Tg for May 2009. This corresponds to an average CH4 flux of 9-31 mg m-2 d-1 for November 2008 and 8-36 mg m-2 d-1 for May 2009.
Jardine, Kolby J.; Chambers, Jeffrey Q.; Holm, Jennifer; Jardine, Angela B.; Fontes, Clarissa G.; Zorzanelli, Raquel F.; Meyers, Kimberly T.; de Souza, Vinicius Fernadez; Garcia, Sabrina; Gimenez, Bruno O.; de O. Piva, Luani R.; Higuchi, Niro; Artaxo, Paulo; Martin, Scot; Manzi, Antônio O.
2015-01-01
Prolonged drought stress combined with high leaf temperatures can induce programmed leaf senescence involving lipid peroxidation, and the loss of net carbon assimilation during early stages of tree mortality. Periodic droughts are known to induce widespread tree mortality in the Amazon rainforest, but little is known about the role of lipid peroxidation during drought-induced leaf senescence. In this study, we present observations of green leaf volatile (GLV) emissions during membrane peroxidation processes associated with the combined effects of high leaf temperatures and drought-induced leaf senescence from individual detached leaves and a rainforest ecosystem in the central Amazon. Temperature-dependent leaf emissions of volatile terpenoids were observed during the morning, and together with transpiration and net photosynthesis, showed a post-midday depression. This post-midday depression was associated with a stimulation of C5 and C6 GLV emissions, which continued to increase throughout the late afternoon in a temperature-independent fashion. During the 2010 drought in the Amazon Basin, which resulted in widespread tree mortality, green leaf volatile emissions (C6 GLVs) were observed to build up within the forest canopy atmosphere, likely associated with high leaf temperatures and enhanced drought-induced leaf senescence processes. The results suggest that observations of GLVs in the tropical boundary layer could be used as a chemical sensor of reduced ecosystem productivity associated with drought stress. PMID:27135346
Jardine, Kolby J; Chambers, Jeffrey Q; Holm, Jennifer; Jardine, Angela B; Fontes, Clarissa G; Zorzanelli, Raquel F; Meyers, Kimberly T; de Souza, Vinicius Fernadez; Garcia, Sabrina; Gimenez, Bruno O; Piva, Luani R de O; Higuchi, Niro; Artaxo, Paulo; Martin, Scot; Manzi, Antônio O
2015-09-15
Prolonged drought stress combined with high leaf temperatures can induce programmed leaf senescence involving lipid peroxidation, and the loss of net carbon assimilation during early stages of tree mortality. Periodic droughts are known to induce widespread tree mortality in the Amazon rainforest, but little is known about the role of lipid peroxidation during drought-induced leaf senescence. In this study, we present observations of green leaf volatile (GLV) emissions during membrane peroxidation processes associated with the combined effects of high leaf temperatures and drought-induced leaf senescence from individual detached leaves and a rainforest ecosystem in the central Amazon. Temperature-dependent leaf emissions of volatile terpenoids were observed during the morning, and together with transpiration and net photosynthesis, showed a post-midday depression. This post-midday depression was associated with a stimulation of C₅ and C₆ GLV emissions, which continued to increase throughout the late afternoon in a temperature-independent fashion. During the 2010 drought in the Amazon Basin, which resulted in widespread tree mortality, green leaf volatile emissions (C₆ GLVs) were observed to build up within the forest canopy atmosphere, likely associated with high leaf temperatures and enhanced drought-induced leaf senescence processes. The results suggest that observations of GLVs in the tropical boundary layer could be used as a chemical sensor of reduced ecosystem productivity associated with drought stress.
Freire, Jean Carlos A; Hauser-Davis, Rachel Ann; da Costa Lobato, Tarcísio; de Morais, Jefferson M; de Oliveira, Terezinha F; F Saraiva, Augusto Cesar
2017-05-01
Dam constructions in the Amazon have increased exponentially in the last decades, causing several environmental impacts and serious anthropogenic impacts in certain hydroelectric power plant reservoirs in the region have been identified. The assessment of the trophic status of these reservoirs is of interest to indicate man-made changes in the environment, but must take into account the hydrological cycle of the area. This can be relevant for environmental management actions, aiding in the identification of the ecological status of water bodies. In this context, physico-chemical parameters and eutrophication indicators were determined in a hydroelectric power plant reservoir in the Brazilian Amazon to assess trophic variations during the regional hydrological regime phases on the reservoir, namely dry, filling, full and emptying stages. The local hydrological regimes were shown to significantly influence TSS and turbidity, as well as NH 4 , NO 3 , PO 4 , with higher values consistently observed during the filling stage of the reservoir. In addition, differences among the sampling stations regarding land use, population and anthropogenic activities were reflected in the PO 4 3- values during the different hydrological phases.
Ramos, Márcio V; Brito, Daniel; Freitas, Cléverson D T; Gonçalves, José Francisco C; Porfirio, Camila T M N; Lobo, Marina D P; Monteiro-Moreira, Ana Cristina O; Souza, Luiz A C; Fernandes, Andreia V
2018-04-19
Seeds of native species from the rain forest (Amazon) are source of chitinases and their protein extracts exhibited strong and broad antifungal activity. Numerous plant species native to the Amazon have not yet been chemically studied. Studies of seeds are scarcer, since adversities in accessing study areas and seasonality pose constant hurdles to systematic research. In this study, proteins were extracted from seeds belonging to endemic Amazon species and were investigated for the first time. Proteolytic activity, peptidase inhibitors, and chitinases were identified, but chitinolytic activity predominated. Four proteins were purified through chromatography and identified as lectin and chitinases by MS/MS analyses. The proteins were examined for inhibition of a phytopathogen (Fusarium oxysporum). Analyses by fluorescence microscopy suggested binding of propidium iodide to DNA of fungal spores, revealing that spore integrity was lost when accessed by the proteins. Further structural and functional analyses of defensive proteins belonging to species facing highly complex ecosystems such as Amazonia should be conducted, since these could provide new insights into specificity and synergism involving defense proteins of plants submitted to a very complex ecosystem.
Transported African Dust to the Amazon: Physiochemical Properties and Associated Nutrients
NASA Astrophysics Data System (ADS)
Barkley, A.; Blackwelder, P. L.; Prospero, J. M.; Gaston, C.
2017-12-01
African dust plays an essential role in fertilizing both oceanic and terrestrial ecosystems by supplying vital biological nutrients such as iron and phosphorus. During Boreal winter, large quantities of African dust are transported across the Atlantic Ocean to the Amazon Basin. It is thought that the Bodélé Depression, part of Paleolake Mega Chad, serves as a major source of this dust, although its importance is debated. The soil in this topographical depression contains a distinctive blend of fluvial and diatomaceous sediments that are thought to supply the Amazon with the nutrients necessary to maintain soil fertility. However, the composition and physical properties of dust transported to the Amazon remain under-explored. Here we present measurements of the size, morphology, and chemical composition of transported dust collected in Cayenne, French Guiana and soil samples collected from the Bodélé Depression using scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). Inductively coupled plasma mass spectrometry and soluble phosphorus measurements were also performed to investigate the nutrient profiles of filters collected during different air mass transport conditions. In addition to mineral dust, SEM revealed the presence of whole and fragmented freshwater diatoms transported from the Bodélé Depression, or other ephemeral African paleolakes, that were mixed with dust containing iron oxides and micronutrient-rich authigenic clays. Interestingly, transported diatoms were found to the be the largest transported particles with diameters well above 10 μm (up to 70 μm). The low density and high surface-to-volume ratios of diatoms could allow a longer range transport than dust of a comparable size. Therefore, the diatoms could act as a vehicle by which higher micronutrient fluxes could be transported to the Amazon.
The evolution of organic matter along the lower Amazon River continuum - Óbidos to the ocean
NASA Astrophysics Data System (ADS)
Ward, N. D.; Keil, R. G.; Medeiros, P. M.; Brito, D.; Cunha, A.; Sawakuchi, H. O.; Moura, J. S.; Yager, P. L.; Krusche, A. V.; Richey, J. E.
2013-12-01
The influence of the Amazon River on global hydrologic and biogeochemical cycling is well recognized. The Amazon River provides roughly 16% of the global freshwater supply to the ocean and is a significant source of CO2 to the atmosphere, outgassing 0.5 Pg C y-1 to the atmosphere--a flux roughly equivalent to the amount of carbon 'sequestered' by the Amazon rainforest (Field et al, 1998; Richey et al., 2002; Malhi et al., 2008). However, much of our understanding of the flux of matter from the Amazon River into the Atlantic Ocean (and atmosphere) is limited to measurements made at and upstream of Óbidos, 900 km upstream from the actual river mouth. Further, there are few to no observations documenting the transformation of organic matter in a parcel of water as it travels downstream of Óbidos into the ocean. Here we explore the hydrological and biogeochemical evolution of the lower Amazon River continuum, from Óbidos to the Atlantic Ocean. A suite of dissolved and particulate organic matter (OM) parameters were measured during a series of five river expeditions with stations at Óbidos, the Tapajós tributary, the mouth of the Lago Grande de Curuai floodplain lake, both the north and south channels of the Amazon River mouth near Macapá, and the confluence of the Amazon and Tocantins Rivers near Belém. In addition to bulk carbon isotopic signatures, a suite of biomarkers including dissolved and particulate lignin-derived phenols were measured to trace the sources and degradation history of terrestrial vascular plant derived OM throughout the continuum. Dissolved and particulate lignin phenol concentrations both correlated positively with river discharge in the Amazon River mainstem, with variable export patterns from the tributaries and floodplains. As organic matter travels along the continuum it is degraded by microbial composition, fuelling gross respiration and CO2 outgassing. The flux of organic carbon to the ocean is chemically recalcitrant as a result of the constant biological processing of labile OM throughout the lower river. We estimate that 40% of the vascular plant-derived organic carbon sequestered by the terrestrial biosphere is degraded within soils, 55% is degraded along the river continuum, and less than 5% is delivered to the ocean (Ward et al., 2013) References Cited Field, C., M. Behrenfeld, J. Randerson, and P. Falkowski. 1998. Primary production of the biosphere: Integrating terrestrial and oceanic components. Science 281, 237-240. Malhi, Y., Roberts, J.T., Betts, R.A., Killeen, T.J., Li, W., Nobre, C.A. 2008. Climate change, deforestation, and the fate of the Amazon. Science 319, 169-172. Richey, J. E., Melack, J. M., Aufdenkampe, A. K., Ballester, V. M. & Hess, L. L. 2002. Outgassing from Amazonian rivers and wetlands as a large tropical source of atmospheric CO2. Nature 416, 617-620. Ward, N.D.; Keil, R.G.; Medeiros, P.M.; Brito, D.C.; Cunha, A.C.; Dittmar, T.; Yager, P.L.; Krusche, A.V.; Richey, J.E. 2013. Degradation of terrestrially derived macromolecules in the Amazon River. Nature Geoscience. doi: 10.1038/ngeo1817
NASA Astrophysics Data System (ADS)
Cook, K. H.; Vizy, E. K.
2007-05-01
A regional climate model with resolution of 60 km coupled with a potential vegetation model is used to simulate future vegetation distributions over South America. The coupled model, which produces an accurate representation of today's climate and vegetation, is forced with increasing atmospheric CO2 concentrations, sea surface temperature from a global model, and scenarios of future land use practices to predict climate and vegetation distributions for the last 2 decades of the 21st century. When only climate change is considered, under a business-as-usual scenario for global emissions, the extent of the Amazon rainforest is reduced by about 70 per cent by the end of this century, and the shrubland (caatinga) vegetation of Brazil's Nordeste region spreads westward and southward. Reductions in annual mean precipitation are widespread and rainfall becomes insufficient to support the rainforest in these regions, but some areas receive more precipitation. The length of the dry season increases in the central and southern Amazon in association with changes in the large-scale tropical circulation. Without this change in seasonality, local refugia of Amazon vegetation would be preserved and the retreat of the rainforest would be somewhat less extensive. Including various projections of future land use practices in addition to climate change may accelerate the unrecoverable demise of the rainforest and feedback to modify climate on regional space scales. The portions of the rainforest that are most vulnerable to climate change are the same as those that are under the most pressure from human activity, presenting a remarkable competition.
NASA Astrophysics Data System (ADS)
da Costa, Marcondes Lima; Sousa, Daniel José Lima; Angélica, Rômulo Simões
The eastern region of the Amazon is home to the most important kaolin bauxite producing district in Brazil, referred to as the Paragominas-Capim kaolin bauxite district, which has a reserve of at least 1.0 billion tons of high-quality kaolin used in the paper coating industry. The kaolin deposits are closely related to sedimentary rocks of the Parnaíba basin and their lateritic cover. Two large deposits are already being mined: IRCC (Ipixuna) and PPSA (Paragominas). The geology of the IRCC mine is comprised of the kaolin-bearing lower unit (truncated mature laterite succession derived from the Ipixuna/Itapecuru formation) and the upper unit (immature lateritized Barreiras formation). The lower kaolin unit is characterized by a sandy facies at the bottom and a soft (ore) with flint facies at the top. It is formed by kaolinite, quartz, some iron oxi-hydroxides, mica and several accessories and heavy minerals. The <2 μm kaolinite crystallites only correspond to 41.3-58.3% of the soft kaolin, and large booklets of 15-300 μm are common. The degree of structure order of kaolinite decreases towards the flint kaolin. The chemical composition of the soft kaolin is similar to the theoretical chemical composition of kaolinite, with low iron content, and can be well correlated to most kaolin deposits in the region. The distribution pattern of chemical elements from sandy to flint kaolin (lower unit) suggests a lateritic evolution and erosive truncation. This is quite distinct from the upper unit, which has a mineralogical and chemical pathway relating it to a complete immature lateritic profile. The geological evolution of the IRCC kaolin is similar to that of other deposits in the eastern Amazon region, being comprised of: parent rocks formed in an estuarine marine and fluvio-laccustrine environment during the early Cretaceous; establishment of mature lateritization with the formation of kaolin in the Eocene; marine transgression and regression - (Pirabas and Barreiras formation) with kaolin profile erosion and forward movement of deferruginization and flintization during the Miocene after partial mangrove covering; and immature lateritization - partial kaolin ferruginization during the Pleistocene.
Sensitivity of CO2 Simulation in a GCM to the Convective Transport Algorithms
NASA Technical Reports Server (NTRS)
Zhu, Z.; Pawson, S.; Collatz, G. J.; Gregg, W. W.; Kawa, S. R.; Baker, D.; Ott, L.
2014-01-01
Convection plays an important role in the transport of heat, moisture and trace gases. In this study, we simulated CO2 concentrations with an atmospheric general circulation model (GCM). Three different convective transport algorithms were used. One is a modified Arakawa-Shubert scheme that was native to the GCM; two others used in two off-line chemical transport models (CTMs) were added to the GCM here for comparison purposes. Advanced CO2 surfaced fluxes were used for the simulations. The results were compared to a large quantity of CO2 observation data. We find that the simulation results are sensitive to the convective transport algorithms. Overall, the three simulations are quite realistic and similar to each other in the remote marine regions, but are significantly different in some land regions with strong fluxes such as Amazon and Siberia during the convection seasons. Large biases against CO2 measurements are found in these regions in the control run, which uses the original GCM. The simulation with the simple diffusive algorithm is better. The difference of the two simulations is related to the very different convective transport speed.
Ribeiro, Rannyele Passos; Alves, Paulo Ricardo; de Almeida, Zafira da Silva; Ruta, Christine
2018-01-01
Abstract The polychaete fauna from the mangroves of the Amazon Coast in Maranhão state, Brazil, is reported in this study. Fourteen species are listed, namely Alitta succinea (Leuckart, 1847); Arabella (Arabella) iricolor Montagu, 1804; Capitella capitata (Fabricius, 1780) complex; Exogone (Exogone) breviantennata Hartmann-Schröder, 1959; Heteromastus filiformis (Claparède, 1864); Isolda pulchella Müller, 1858; Mediomastus californiensis Hartman, 1944; Namalycastis fauveli Nageswara Rao, 1981; Namalycastis geayi (Gravier, 1901); Namalycastis senegalensis (Saint-Joseph, 1901); Nephtys simoni Perkins, 1980; Paraonis amazonica sp. n.; Sigambra bassi (Hartman, 1945); and Sigambra grubii Müller, 1858. Among them, Namalycastis fauveli and Namalycastis geayi are recorded for the first time in Brazil. Paraonis amazonica sp. n. is a new species for science, characterized by a rounded prostomium, 4–8 pairs of foliaceous branchiae, absent eyes, and two types of modified neurochaetae, acicular and hook-shaped. PMID:29674886
NASA Astrophysics Data System (ADS)
Wolff, Stefan; Tsokankunku, Anywhere; Pöhlker, Christopher; Saturno, Jorge; Walter, David; Ditas, Florian; Könemann, Tobias; Ganzeveld, Laurens; Yañez-Serrano, Ana Maria; Souza, Rodrigo; Trebs, Ivonne; Sörgel, Matthias
2017-04-01
The ATTO (Amazon Tall Tower Observatory) site (02°08'38.8''S, 58°59'59.5''W) is located in the remote Amazon rainforest, allowing atmospheric and forest studies away from nearby anthropogenic emission sources. Starting with continuous measurements of vertical mixing ratio profiles of H2O, CO2 and O3 in April 2012 at 8 heights between 0.05 m and 80 m above ground, the longest continuous record of near surface O3 in the Amazon rainforest was established. Black carbon (BC), CO and micrometeorological measurements are available for the same period. During intensive campaigns, NOx was measured as well using the same profile system, and, therefore several month of simultaneous NOx measurements are available. During a period of about four months also direct flux measurements of O3 are available. Here, we analyze the long term and seasonal variability of near surface O3 mixing ratios with respect to air pollution, deposition and transport. The Central Amazon is characterized by a clear seasonal precipitation pattern (ca. 350 mm around March and ca. 80 mm around September), correlating strongly with ozone mixing ratios. Since 2012 deforestation rates have increased again in the Amazon, leading to higher air pollution especially during the drier season in the last years. For several strong pollution events we compared the effects of long and short distance biomass burning on O3 and NOx mixing ratios using back trajectories and satellite data. By comparing O3 mixing ratios with solar radiation, Bowen ratio, several trace gases and aerosol loads (Volatile Organic Compounds, CO and BC), different correlation patterns throughout the year that are linked to the sources (transport of O3 and precursors) and sinks (stomatal uptake and chemical reactions) are investigated. For example, the last months of 2015 were strongly influenced by an extraordinary El Niño phenomenon, leading to much drier conditions and enhanced biomass burning in the Amazon, which prolonged the period of increased O3 values. These exceptional dry conditions and a slight La Niña in 2016 have influenced the water availability, which in turn may have affected the O3 deposition.
Isoprene photochemistry over the Amazon rainforest.
Liu, Yingjun; Brito, Joel; Dorris, Matthew R; Rivera-Rios, Jean C; Seco, Roger; Bates, Kelvin H; Artaxo, Paulo; Duvoisin, Sergio; Keutsch, Frank N; Kim, Saewung; Goldstein, Allen H; Guenther, Alex B; Manzi, Antonio O; Souza, Rodrigo A F; Springston, Stephen R; Watson, Thomas B; McKinney, Karena A; Martin, Scot T
2016-05-31
Isoprene photooxidation is a major driver of atmospheric chemistry over forested regions. Isoprene reacts with hydroxyl radicals (OH) and molecular oxygen to produce isoprene peroxy radicals (ISOPOO). These radicals can react with hydroperoxyl radicals (HO2) to dominantly produce hydroxyhydroperoxides (ISOPOOH). They can also react with nitric oxide (NO) to largely produce methyl vinyl ketone (MVK) and methacrolein (MACR). Unimolecular isomerization and bimolecular reactions with organic peroxy radicals are also possible. There is uncertainty about the relative importance of each of these pathways in the atmosphere and possible changes because of anthropogenic pollution. Herein, measurements of ISOPOOH and MVK + MACR concentrations are reported over the central region of the Amazon basin during the wet season. The research site, downwind of an urban region, intercepted both background and polluted air masses during the GoAmazon2014/5 Experiment. Under background conditions, the confidence interval for the ratio of the ISOPOOH concentration to that of MVK + MACR spanned 0.4-0.6. This result implies a ratio of the reaction rate of ISOPOO with HO2 to that with NO of approximately unity. A value of unity is significantly smaller than simulated at present by global chemical transport models for this important, nominally low-NO, forested region of Earth. Under polluted conditions, when the concentrations of reactive nitrogen compounds were high (>1 ppb), ISOPOOH concentrations dropped below the instrumental detection limit (<60 ppt). This abrupt shift in isoprene photooxidation, sparked by human activities, speaks to ongoing and possible future changes in the photochemistry active over the Amazon rainforest.
Isoprene photochemistry over the Amazon rainforest
NASA Astrophysics Data System (ADS)
Liu, Yingjun; Brito, Joel; Dorris, Matthew R.; Rivera-Rios, Jean C.; Seco, Roger; Bates, Kelvin H.; Artaxo, Paulo; Duvoisin, Sergio; Keutsch, Frank N.; Kim, Saewung; Goldstein, Allen H.; Guenther, Alex B.; Manzi, Antonio O.; Souza, Rodrigo A. F.; Springston, Stephen R.; Watson, Thomas B.; McKinney, Karena A.; Martin, Scot T.
2016-05-01
Isoprene photooxidation is a major driver of atmospheric chemistry over forested regions. Isoprene reacts with hydroxyl radicals (OH) and molecular oxygen to produce isoprene peroxy radicals (ISOPOO). These radicals can react with hydroperoxyl radicals (HO2) to dominantly produce hydroxyhydroperoxides (ISOPOOH). They can also react with nitric oxide (NO) to largely produce methyl vinyl ketone (MVK) and methacrolein (MACR). Unimolecular isomerization and bimolecular reactions with organic peroxy radicals are also possible. There is uncertainty about the relative importance of each of these pathways in the atmosphere and possible changes because of anthropogenic pollution. Herein, measurements of ISOPOOH and MVK + MACR concentrations are reported over the central region of the Amazon basin during the wet season. The research site, downwind of an urban region, intercepted both background and polluted air masses during the GoAmazon2014/5 Experiment. Under background conditions, the confidence interval for the ratio of the ISOPOOH concentration to that of MVK + MACR spanned 0.4-0.6. This result implies a ratio of the reaction rate of ISOPOO with HO2 to that with NO of approximately unity. A value of unity is significantly smaller than simulated at present by global chemical transport models for this important, nominally low-NO, forested region of Earth. Under polluted conditions, when the concentrations of reactive nitrogen compounds were high (>1 ppb), ISOPOOH concentrations dropped below the instrumental detection limit (<60 ppt). This abrupt shift in isoprene photooxidation, sparked by human activities, speaks to ongoing and possible future changes in the photochemistry active over the Amazon rainforest.
Black carbon over the Amazon during SAMBBA: it gets everywhere
NASA Astrophysics Data System (ADS)
Morgan, W.; Allan, J. D.; Flynn, M.; Darbyshire, E.; Liu, D.; Szpek, K.; Langridge, J.; Johnson, B. T.; Haywood, J.; Longo, K.; Artaxo, P.; Coe, H.
2014-12-01
Biomass burning represents a major source of Black Carbon (BC) aerosol to the atmosphere, which can result in major perturbations to weather, climate and ecosystem development. Large uncertainties in these impacts prevail, particularly on regional scales. One such region is the Amazon Basin, where large, intense and frequent burning occurs on an annual basis during the dry season. Absorption by atmospheric aerosols is underestimated by models over South America, which points to significant uncertainties relating to BC aerosol properties. Results from the South American Biomass Burning Analysis (SAMBBA) field experiment, which took place during September and October 2012 over Brazil on-board the UK Facility for Airborne Atmospheric Measurement (FAAM) BAe-146 research aircraft, are presented here. Aerosol chemical composition was measured by a DMT Single Particle Soot Photometer (SP2) and an Aerodyne Aerosol Mass Spectrometer (AMS). The physical, chemical and optical properties of BC-containing particles across the region will be characterised, with particular emphasis on the vertical distribution. BC was ubiquitous across the region, with measurements extending from heavily deforested regions in the Western Amazon Basin, through to agricultural fires in the Cerrado (Savannah-like) region and more pristine areas over the Amazon Rainforest. Measurements in the vicinity of Manaus (a city located deep into the jungle) were also conducted. BC concentrations peaked within the boundary layer at a height of around 1.5km. BC-containing particles were found to be rapidly coated in the near-field, with little evidence for additional coating upon advection and dilution. Biomass burning layers within the free troposphere were routinely observed. BC-containing particles within such layers were typically associated with less coating than those within the boundary layer, suggestive of wet removal of more coated BC particles. The importance of such properties in relation to the optical properties of BC and its resultant impact will be investigated. The prevalence of elevated biomass burning layers above the frequent build-up of shallow cumulus clouds during the afternoon will also be characterised. This will provide improved constraint upon the highly uncertain impact of biomass burning aerosol over the region.
Virioplankton Assemblage Structure in the Lower River and Ocean Continuum of the Amazon
DOE Office of Scientific and Technical Information (OSTI.GOV)
Silva, Bruno S. de O.; Coutinho, Felipe H.; Gregoracci, Gustavo B.
ABSTRACT The Amazon River watershed and its associated plume comprise a vast continental and oceanic area. The microbial activities along this continuum contribute substantially to global carbon and nutrient cycling, and yet there is a dearth of information on the diversity, abundance, and possible roles of viruses in this globally important river. The aim of this study was to elucidate the diversity and structure of virus assemblages of the Amazon River-ocean continuum. Environmental viral DNA sequences were obtained for 12 locations along the river’s lower reach (n= 5) and plume (n= 7). Sequence assembly yielded 29,358 scaffolds, encoding 82,546 viralmore » proteins, with 15 new complete viral genomes. Despite the spatial connectivity mediated by the river, virome analyses and physical-chemical water parameters clearly distinguished river and plume ecosystems. Bacteriophages were ubiquitous in the continuum and were more abundant in the transition region. Eukaryotic viruses occurred mostly in the river, while the plume had more viruses of autotrophic organisms (Prochlorococcus,Synechococcus) and heterotrophic bacteria (Pelagibacter). The viral familiesMicroviridaeandMyoviridaewere the most abundant and occurred throughout the continuum. The major functions of the genes in the continuum involved viral structures and life cycles, and viruses from plume locations and Tapajós River showed the highest levels of functional diversity. The distribution patterns of the viral assemblages were defined not only by the occurrence of possible hosts but also by water physical and chemical parameters, especially salinity. The findings presented here help to improve understanding of the possible roles of viruses in the organic matter cycle along the river-ocean continuum. IMPORTANCEThe Amazon River forms a vast plume in the Atlantic Ocean that can extend for more than 1,000 km. Microbial communities promote a globally relevant carbon sink system in the plume. Despite the importance of viruses for the global carbon cycle, the diversity and the possible roles of viruses in the Amazon are poorly understood. The present work assesses, for the first time, the abundance and diversity of viruses simultaneously in the river and ocean in order to elucidate their possible roles. DNA sequence assembly yielded 29,358 scaffolds, encoding 82,546 viral proteins, with 15 new complete viral genomes from the 12 river and ocean locations. Viral diversity was clearly distinguished by river and ocean. Bacteriophages were the most abundant and occurred throughout the continuum. Viruses that infect eukaryotes were more abundant in the river, whereas phages appeared to have strong control over the host prokaryotic populations in the plume.« less
Virioplankton Assemblage Structure in the Lower River and Ocean Continuum of the Amazon.
Silva, Bruno S de O; Coutinho, Felipe H; Gregoracci, Gustavo B; Leomil, Luciana; de Oliveira, Louisi S; Fróes, Adriana; Tschoeke, Diogo; Soares, Ana Carolina; Cabral, Anderson S; Ward, Nicholas D; Richey, Jeffrey E; Krusche, Alex V; Yager, Patricia L; de Rezende, Carlos Eduardo; Thompson, Cristiane C; Thompson, Fabiano L
2017-01-01
The Amazon River watershed and its associated plume comprise a vast continental and oceanic area. The microbial activities along this continuum contribute substantially to global carbon and nutrient cycling, and yet there is a dearth of information on the diversity, abundance, and possible roles of viruses in this globally important river. The aim of this study was to elucidate the diversity and structure of virus assemblages of the Amazon River-ocean continuum. Environmental viral DNA sequences were obtained for 12 locations along the river's lower reach ( n = 5) and plume ( n = 7). Sequence assembly yielded 29,358 scaffolds, encoding 82,546 viral proteins, with 15 new complete viral genomes. Despite the spatial connectivity mediated by the river, virome analyses and physical-chemical water parameters clearly distinguished river and plume ecosystems. Bacteriophages were ubiquitous in the continuum and were more abundant in the transition region. Eukaryotic viruses occurred mostly in the river, while the plume had more viruses of autotrophic organisms ( Prochlorococcus , Synechococcus ) and heterotrophic bacteria ( Pelagibacter ). The viral families Microviridae and Myoviridae were the most abundant and occurred throughout the continuum. The major functions of the genes in the continuum involved viral structures and life cycles, and viruses from plume locations and Tapajós River showed the highest levels of functional diversity. The distribution patterns of the viral assemblages were defined not only by the occurrence of possible hosts but also by water physical and chemical parameters, especially salinity. The findings presented here help to improve understanding of the possible roles of viruses in the organic matter cycle along the river-ocean continuum. IMPORTANCE The Amazon River forms a vast plume in the Atlantic Ocean that can extend for more than 1,000 km. Microbial communities promote a globally relevant carbon sink system in the plume. Despite the importance of viruses for the global carbon cycle, the diversity and the possible roles of viruses in the Amazon are poorly understood. The present work assesses, for the first time, the abundance and diversity of viruses simultaneously in the river and ocean in order to elucidate their possible roles. DNA sequence assembly yielded 29,358 scaffolds, encoding 82,546 viral proteins, with 15 new complete viral genomes from the 12 river and ocean locations. Viral diversity was clearly distinguished by river and ocean. Bacteriophages were the most abundant and occurred throughout the continuum. Viruses that infect eukaryotes were more abundant in the river, whereas phages appeared to have strong control over the host prokaryotic populations in the plume.
Virioplankton Assemblage Structure in the Lower River and Ocean Continuum of the Amazon
Silva, Bruno S. de O.; Coutinho, Felipe H.; Gregoracci, Gustavo B.; Leomil, Luciana; de Oliveira, Louisi S.; Fróes, Adriana; Tschoeke, Diogo; Soares, Ana Carolina; Cabral, Anderson S.; Ward, Nicholas D.; Richey, Jeffrey E.; Krusche, Alex V.; Yager, Patricia L.; de Rezende, Carlos Eduardo; Thompson, Cristiane C.
2017-01-01
ABSTRACT The Amazon River watershed and its associated plume comprise a vast continental and oceanic area. The microbial activities along this continuum contribute substantially to global carbon and nutrient cycling, and yet there is a dearth of information on the diversity, abundance, and possible roles of viruses in this globally important river. The aim of this study was to elucidate the diversity and structure of virus assemblages of the Amazon River-ocean continuum. Environmental viral DNA sequences were obtained for 12 locations along the river’s lower reach (n = 5) and plume (n = 7). Sequence assembly yielded 29,358 scaffolds, encoding 82,546 viral proteins, with 15 new complete viral genomes. Despite the spatial connectivity mediated by the river, virome analyses and physical-chemical water parameters clearly distinguished river and plume ecosystems. Bacteriophages were ubiquitous in the continuum and were more abundant in the transition region. Eukaryotic viruses occurred mostly in the river, while the plume had more viruses of autotrophic organisms (Prochlorococcus, Synechococcus) and heterotrophic bacteria (Pelagibacter). The viral families Microviridae and Myoviridae were the most abundant and occurred throughout the continuum. The major functions of the genes in the continuum involved viral structures and life cycles, and viruses from plume locations and Tapajós River showed the highest levels of functional diversity. The distribution patterns of the viral assemblages were defined not only by the occurrence of possible hosts but also by water physical and chemical parameters, especially salinity. The findings presented here help to improve understanding of the possible roles of viruses in the organic matter cycle along the river-ocean continuum. IMPORTANCE The Amazon River forms a vast plume in the Atlantic Ocean that can extend for more than 1,000 km. Microbial communities promote a globally relevant carbon sink system in the plume. Despite the importance of viruses for the global carbon cycle, the diversity and the possible roles of viruses in the Amazon are poorly understood. The present work assesses, for the first time, the abundance and diversity of viruses simultaneously in the river and ocean in order to elucidate their possible roles. DNA sequence assembly yielded 29,358 scaffolds, encoding 82,546 viral proteins, with 15 new complete viral genomes from the 12 river and ocean locations. Viral diversity was clearly distinguished by river and ocean. Bacteriophages were the most abundant and occurred throughout the continuum. Viruses that infect eukaryotes were more abundant in the river, whereas phages appeared to have strong control over the host prokaryotic populations in the plume. PMID:28989970
NASA Astrophysics Data System (ADS)
Randerson, J. T.
2016-12-01
Recent work has established that year-to-year variability in drought and fire within the Amazon responds to a dual forcing from ocean-atmosphere interactions in the tropical Pacific and North Atlantic. Teleconnections between the Pacific and the Amazon are strongest between October and March, when El Niño contributes to below-average precipitation during the wet season. A reduced build-up of soil moisture during the wet season, in turn, may limit water availability and transpiration in tropical forests during the following dry season, lowering surface humidity, drying fuels, and allowing fires to spread more easily through the understory. The delayed influence of soil moisture through this land - atmosphere coupling provides a means to predict fire season severity 3-6 months before the onset of the dry season. With the aim of creating new opportunities for forest conservation, we have developed an experimental seasonal fire forecasting system for the Amazon. The 2016 fire season severity forecast, released in June by UCI and NASA, predicts unusually high risk across eastern Peru, northern Bolivia, and Brazil. Several surface and satellite data streams confirm that El Niño teleconnections had a significant impact on wet season hydrology within the Amazon. Rainfall observations from the Global Precipitation Climatology Centre provided evidence that cumulative precipitation deficits during August-April were 1 to 2 standard deviations below the long-term mean for most of the basin. These observations were corroborated by strong negative terrestrial water storage anomalies measured by the Gravity Recovery and Climate Experiment, and by fluorescence and vegetation index observations from other sensors that indicated elevated canopy stress. By August 3rd, satellite observations showed above average fire activity in most, but not all, forecast regions. Using additional satellite observations that become available later this year, we plan to describe the full spatial and temporal pattern of fires within the Amazon during the 2016 dry season and evaluate the success of our forecast. As a part of this analysis, we will compare fires from 2016 with other years of extreme drought (i.e., 2005 and 2010), and assess how trends in land use, including regional changes in deforestation, modify El Niño-driven fire risk.
Souto, R N P; Harada, A Y; Andrade, E H A; Maia, J G S
2012-12-01
Pepper plants in the genus Piper (Piperales: Piperaceae) are common in the Brazilian Amazon and many produce compounds with biological activity against insect pests. We evaluated the insecticidal effect of essential oils from Piper aduncum, Piper marginatum (chemotypes A and B), Piper divaricatum and Piper callosum against workers of the fire ant Solenopsis saevissima (Smith) (Hymenoptera: Formicidae), as well as their chemical composition by gas chromatography and gas chromatography-mass spectrometry. The lowest median lethal concentration (LC50) in 48 h was obtained with the oil of P. aduncum (58.4 mg/L), followed by the oils of P. marginatum types A (122.4 mg/L) and B (167.0 mg/L), P. divaricatum (301.7 mg/L), and P. callosum (312.6 mg/L). The major chemical constituents were dillapiole (64.4%) in the oil of P. aduncum; p-mentha-1(7),8-diene (39.0%), 3,4-methylenedioxypropiophenone (19.0%), and (E)-β-ocimene (9.8%) in P. marginatum chemotype A and (E)-isoosmorhizole (32.2%), (E)-anethole (26.4%), isoosmorhizole (11.2%), and (Z)-anethole (6.0%) in P. marginatum chemotype B; methyleugenol (69.2%) and eugenol (16.2%) in P. divaricatum; and safrole (69.2%), methyleugenol (8.6%), and β-pinene (6.2%) in P. callosum. These chemical constituents have been previously known to possess insecticidal properties.
Soil microbiome responses to the short-term effects of Amazonian deforestation.
Navarrete, Acacio A; Tsai, Siu M; Mendes, Lucas W; Faust, Karoline; de Hollander, Mattias; Cassman, Noriko A; Raes, Jeroen; van Veen, Johannes A; Kuramae, Eiko E
2015-05-01
Slash-and-burn clearing of forest typically results in increase in soil nutrient availability. However, the impact of these nutrients on the soil microbiome is not known. Using next generation sequencing of 16S rRNA gene and shotgun metagenomic DNA, we compared the structure and the potential functions of bacterial community in forest soils to deforested soils in the Amazon region and related the differences to soil chemical factors. Deforestation decreased soil organic matter content and factors linked to soil acidity and raised soil pH, base saturation and exchangeable bases. Concomitant to expected changes in soil chemical factors, we observed an increase in the alpha diversity of the bacterial microbiota and relative abundances of putative copiotrophic bacteria such as Actinomycetales and a decrease in the relative abundances of bacterial taxa such as Chlamydiae, Planctomycetes and Verrucomicrobia in the deforested soils. We did not observe an increase in genes related to microbial nutrient metabolism in deforested soils. However, we did observe changes in community functions such as increases in DNA repair, protein processing, modification, degradation and folding functions, and these functions might reflect adaptation to changes in soil characteristics due to forest clear-cutting and burning. In addition, there were changes in the composition of the bacterial groups associated with metabolism-related functions. Co-occurrence microbial network analysis identified distinct phylogenetic patterns for forest and deforested soils and suggested relationships between Planctomycetes and aluminium content, and Actinobacteria and nitrogen sources in Amazon soils. The results support taxonomic and functional adaptations in the soil bacterial community following deforestation. We hypothesize that these microbial adaptations may serve as a buffer to drastic changes in soil fertility after slash-and-burning deforestation in the Amazon region. © 2015 John Wiley & Sons Ltd.
Mantilla-Paredes, Andrea J; Cardona, Gladys I; Peña-Venegas, Clara P; Murcia, Uriel; Rodríguez, Mariana; Zambrano, Maria M
2009-12-01
Potentially nitrogen-fixing microaerobic and aerobic bacteria were isolated from several Colombian Amazon soils (forest, pastures and chagras) and two landscapes (floodable and non floodable areas). The abundance and distribution of bacteria were evaluated, as well as their relationship with soil physical and chemical characteristics. Landscape had a direct influence on the abundance of the microaerobic bacteria, with higher numbers in forest and pasture soils in non-floodable zones. The aerobic isolates (N=51) were grouped into 19 morphologies, with the highest numbers found in forest soil in floodable zones. A higher number of aerobic morphologies was shared among forest sites (Nonmetric Multidimensional Scaling and Analysis of Similarity p<0.05), and 40% of the distribution was explained by lime percentage and Al concentration.
Long-term observations of cloud condensation nuclei in the Amazon rain forest
NASA Astrophysics Data System (ADS)
Pöhlker, Mira L.; Pöhlker, Christopher; Ditas, Florian; Klimach, Thomas; Hrabe de Angelis, Isabella; Brito, Joel; Carbone, Samara; Cheng, Yafang; Martin, Scot T.; Moran-Zuloaga, Daniel; Rose, Diana; Saturno, Jorge; Su, Hang; Thalman, Ryan; Walter, David; Wang, Jian; Barbosa, Henrique; Artaxo, Paulo; Andreae, Meinrat O.; Pöschl, Ulrich
2017-04-01
Size-resolved long-term measurements of atmospheric aerosol and cloud condensation nuclei (CCN) concentrations and hygroscopicity were conducted at the remote Amazon Tall Tower Observatory (ATTO) in the central Amazon Basin over a full seasonal cycle (Mar 2014 - Feb 2015). The measurements provide a climatology of CCN properties characteristic of a remote central Amazonian rain forest site [1,2]. The CCN measurements were continuously cycled through 10 levels of supersaturation (S = 0.11 to 1.10 %) and span the aerosol particle size range from 20 to 245 nm. The particle hygroscopicity exhibits a pronounced size dependence with lower values for the Aitken mode (κAit = 0.14 ± 0.03), higher values for the accumulation mode (κAcc = 0.22 ± 0.05), and an overall mean value of κmean = 0.17 ± 0.06, consistent with high fractions of organic aerosol. The hygroscopicity parameter, κ, exhibits remarkably little temporal variability: no pronounced diurnal cycles, only weak seasonal trends, and few short-term variations during long-range transport events. In contrast, the CCN number concentrations exhibit a pronounced seasonal cycle, tracking the pollution-related seasonality in total aerosol concentration. We find that the variability in the CCN concentrations in the central Amazon is mostly driven by aerosol particle number concentration and size distribution, while variations in aerosol hygroscopicity and chemical composition matter only during a few episodes. For modelling purposes, we compare different approaches of predicting CCN number concentration and present a novel parameterization, which allows accurate CCN predictions based on a small set of input data. In addition, we analyzed the CCN short-term variability in relation to air mass changes as well as aerosol emission and transformation processes. The CCN short term variability is presented for selected case studies, which analyze particularly interesting and characteristic events/conditions in the Amazon region. References: [1] Andreae, M. O., et al. (2015), Atmos. Chem. Phys., 15, 10723-10776. [2] Pöhlker, M. L.., et al. (2016), Atmos. Chem. Phys., 16, 15709-15740.
Isoprene photochemistry over the Amazon rainforest
Liu, Yingjun; Brito, Joel; Dorris, Matthew R.; ...
2016-05-31
Isoprene photooxidation is a major driver of atmospheric chemistry over forested regions. Isoprene reacts with hydroxyl radicals (OH) and molecular oxygen to produce isoprene peroxy radicals (ISOPOO). These radicals can react with hydroperoxyl radicals (HO 2) to dominantly produce hydroxyhydroperoxides (ISOPOOH). They can also react with nitric oxide (NO) to largely produce methyl vinyl ketone (MVK) and methacrolein (MACR). Unimolecular isomerization and bimolecular reactions with organic peroxy radicals are also possible. There is uncertainty about the relative importance of each of these pathways in the atmosphere and possible changes because of anthropogenic pollution. Herein, measurements of ISOPOOH and MVK +more » MACR concentrations are reported over the central region of the Amazon basin during the wet season. The research site, downwind of an urban region, intercepted both background and polluted air masses during the GoAmazon2014/5 Experiment. Under background conditions, the confidence interval for the ratio of the ISOPOOH concentration to that of MVK + MACR spanned 0.4–0.6. This result implies a ratio of the reaction rate of ISOPOO with HO2 to that with NO of approximately unity. Also, a value of unity is significantly smaller than simulated at present by global chemical transport models for this important, nominally low-NO, forested region of Earth. Under polluted conditions, when the concentrations of reactive nitrogen compounds were high (>1 ppb), ISOPOOH concentrations dropped below the instrumental detection limit (<60 ppt). In conclusion, this abrupt shift in isoprene photooxidation, sparked by human activities, speaks to ongoing and possible future changes in the photochemistry active over the Amazon rainforest.« less
Isoprene photochemistry over the Amazon rainforest
Liu, Yingjun; Brito, Joel; Dorris, Matthew R.; Rivera-Rios, Jean C.; Seco, Roger; Bates, Kelvin H.; Artaxo, Paulo; Duvoisin, Sergio; Keutsch, Frank N.; Kim, Saewung; Goldstein, Allen H.; Guenther, Alex B.; Manzi, Antonio O.; Souza, Rodrigo A. F.; Springston, Stephen R.; Watson, Thomas B.; McKinney, Karena A.
2016-01-01
Isoprene photooxidation is a major driver of atmospheric chemistry over forested regions. Isoprene reacts with hydroxyl radicals (OH) and molecular oxygen to produce isoprene peroxy radicals (ISOPOO). These radicals can react with hydroperoxyl radicals (HO2) to dominantly produce hydroxyhydroperoxides (ISOPOOH). They can also react with nitric oxide (NO) to largely produce methyl vinyl ketone (MVK) and methacrolein (MACR). Unimolecular isomerization and bimolecular reactions with organic peroxy radicals are also possible. There is uncertainty about the relative importance of each of these pathways in the atmosphere and possible changes because of anthropogenic pollution. Herein, measurements of ISOPOOH and MVK + MACR concentrations are reported over the central region of the Amazon basin during the wet season. The research site, downwind of an urban region, intercepted both background and polluted air masses during the GoAmazon2014/5 Experiment. Under background conditions, the confidence interval for the ratio of the ISOPOOH concentration to that of MVK + MACR spanned 0.4–0.6. This result implies a ratio of the reaction rate of ISOPOO with HO2 to that with NO of approximately unity. A value of unity is significantly smaller than simulated at present by global chemical transport models for this important, nominally low-NO, forested region of Earth. Under polluted conditions, when the concentrations of reactive nitrogen compounds were high (>1 ppb), ISOPOOH concentrations dropped below the instrumental detection limit (<60 ppt). This abrupt shift in isoprene photooxidation, sparked by human activities, speaks to ongoing and possible future changes in the photochemistry active over the Amazon rainforest. PMID:27185928
Guerra, Denis L; Leidens, Victor L; Viana, Rúbia R; Airoldi, Claudio
2010-08-15
The compound N-[3-(trimethoxysilyl)propyl]diethylenetriamine (MPDET) was anchored onto Amazon kaolinite surface (KLT) by heterogeneous route. The modified and natural kaolinite clay samples were characterized by transmission electron microscopy (TEM), scanning electron microscopic (SEM), N(2) adsorption, powder X-ray diffraction, thermal analysis, ion exchange capacities, and nuclear magnetic nuclei of (29)Si and (13)C. The well-defined peaks obtained in the (13)C NMR spectrum in the 5.0-62.1 ppm region confirmed the attachment of organic functional groups as pendant chains bonded into the porous clay. The adsorption of uranyl on natural (KLT) and modified (KLT(MPDET)) kaolinite clays was investigated as a function of the solution pH, metal concentration, temperature, and ionic strength. The ability of these materials to remove U(VI) from aqueous solution was followed by a series of adsorption isotherms adjusted to a Sips equation at room temperature and pH 4.0. The maximum number of moles adsorbed was determined to be 8.37 x 10(-3) and 13.87 x 10(-3) mmol g(-1) for KLT and KLT(MPDET) at 298 K, respectively. The energetic effects (Delta(int)H, Delta(int)G, and Delta(int)S) caused by metal cations adsorption were determined through calorimetric titrations. Copyright 2010. Published by Elsevier B.V.
NASA Astrophysics Data System (ADS)
Beck, V.; Gerbig, C.; Koch, T.; Bela, M. M.; Longo, K. M.; Freitas, S. R.; Kaplan, J. O.; Prigent, C.; Bergamaschi, P.; Heimann, M.
2013-08-01
The Amazon region, being a large source of methane (CH4), contributes significantly to the global annual CH4 budget. For the first time, a forward and inverse modelling framework on regional scale for the purpose of assessing the CH4 budget of the Amazon region is implemented. Here, we present forward simulations of CH4 as part of the forward and inverse modelling framework based on a modified version of the Weather Research and Forecasting model with chemistry that allows for passive tracer transport of CH4, carbon monoxide, and carbon dioxide (WRF-GHG), in combination with two different process-based bottom-up models of CH4 emissions from anaerobic microbial production in wetlands and additional datasets prescribing CH4 emissions from other sources such as biomass burning, termites, or other anthropogenic emissions. We compare WRF-GHG simulations on 10 km horizontal resolution to flask and continuous CH4 observations obtained during two airborne measurement campaigns within the Balanço Atmosférico Regional de Carbono na Amazônia (BARCA) project in November 2008 and May 2009. In addition, three different wetland inundation maps, prescribing the fraction of inundated area per grid cell, are evaluated. Our results indicate that the wetland inundation maps based on remote-sensing data represent the observations best except for the northern part of the Amazon basin and the Manaus area. WRF-GHG was able to represent the observed CH4 mixing ratios best at days with less convective activity. After adjusting wetland emissions to match the averaged observed mixing ratios of flights with little convective activity, the monthly CH4 budget for the Amazon basin obtained from four different simulations ranges from 1.5 to 4.8 Tg for November 2008 and from 1.3 to 5.5 Tg for May 2009. This corresponds to an average CH4 flux of 9-31 mg m-2 d-1 for November 2008 and 8-36 mg m-2 d-1 for May 2009.
Submicron aerosol and trace gas composition near Manaus as observed during GoAmazon2014/5
NASA Astrophysics Data System (ADS)
Ferreira De Brito, J.; Wurm, F.; Liu, Y.; de Sá, S. S.; Carbone, S.; Rizzo, L. V.; Cirino, G. G.; Barbosa, H. M.; Souza, R. A. F. D.; Martin, S. T.; Artaxo, P.
2014-12-01
The Amazon Basin, during the wet season, has one of the lowest aerosol concentrations worldwide, with air masses covering thousands of kilometers of pristine forest with negligible human impact. The atmosphere in such regions is strongly coupled with the biosphere through primary biological aerosols, biogenic salts and secondary aerosols from oxidation of biogenic VOCs. The natural environment is strongly modified nearby urbanized areas, in particular Manaus, a city of nearly two million people. The urban pollution plume has high concentrations of oxides of nitrogen and sulfur, carbon monoxide, particle concentrations, and soot, among other pollutants, strongly contrasting with the clean air masses reaching the city. Such unique location provides the ideal laboratory to study the isolated urban emission, as well the pristine environment by perturbing it in a relatively known fashion. The GoAmazon experiment was designed with these questions in mind, combining remote sensing, in situand airborne measurements. This manuscript describes the measurements currently taking place at the T2 site, near Manaus, frequently impacted by relatively fresh emissions from the city. This presentation focuses on aerosol properties and trace gas composition at the T2 site. PM1 mass concentration from March up to July 2014 has been observed to be dominated by organics (1.51 μg m-3), followed by BC (0.83 μg m-3), SO4 (0.17 μg m-3), NO3 (0.08 μg m-3) and NH4 (0.06 μg m-3). Mean aerosol number concentration was 3600 cm-3, with a mean geometric diameter of 70 nm. As for the trace gases, initial estimates of isoprene average ambient concentration is 0.95 ppb, whereas MVK+MACR has been estimated to be 0.76 ppb. Average mixing ratios of toluene, benzene and C8 aromatics were 0.31 ppb, 0.16 ppb and 0.15 ppb, respectively, correlating relatively well with markers of anthropogenic activities, such as BC. Such measurements will carry on throughout GoAmazon 2014/5, providing a unique dataset to understand the aerosol life cycle and the impact of urban emission in the heart of the Amazon Forest.
Alves, Luiz C P S; Zappes, Camilah A; Oliveira, Rafael G; Andriolo, Artur; Azevedo, Alexandre de F
2013-01-01
Botos (Inia geoffrensis) are currently provisioned for use in tourist attractions in five sites in the Brazilian Amazon. Despite the known negative effects associated with human-wild dolphin interactions, this activity has been regulated and licensed in the Anavilhanas National Park in Novo Airão, Amazonas State, Brazil. We present an updated evaluation of the perception of the local community concerning the possible socioeconomic impacts of this tourism in Novo Airão. In April 2011, 45 interviews were conducted with inhabitants. A small segment of Novo Airão perceives currently itself as being economically dependent on the botos feeding tourism. Despite that, the economic benefits of this controversial activity apparently are not shared among most inhabitants, and botos feeding tourism is perceived as generating diverse negative effects. We conclude that if the activity was banned or modified into a less impacting tourist activity, this action would probably not majorly affect the lives of the general population.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kuang, C; Artaxo, P; Martin, S
Aerosol nucleation and initial growth were investigated during the Green Ocean Amazon (GoAmazon) 2014/15 campaign. Aerosol sampling occurred during the wet and dry seasons of 2014, and took place at the T3 measurement site, downwind of the city of Manaus, Brazil. Characterization of the aerosol size distribution from 10 to 500 nm was accomplished through the deployment of a conventional Scanning Mobility Particle Spectrometer (SMPS) and a fine condensation particle counter (> 10 nm). In order to directly measure aerosol nucleation and initial growth, a Nano SMPS (1.5-20 nm) was also deployed, consisting of a condensation particle counter-based electrical mobilitymore » spectrometer that was modified for the detection of sub-3 nm aerosol. Measurements of the aerosol size distribution from 1.5 nm to 10 nm were obtained during the first observational period, and from 3 nm to 15 nm during the second observational period. Routine, stable measurement in this size range was complicated due to persistent water condensation in the Nano SMPS and diffusional transport losses« less
NASA Astrophysics Data System (ADS)
dos Santos, F. C.; Guenther, A. B.; Longo, K.; Freitas, S. R.; Moreira, D. S.; Flávio, L.; Braz, R.; Brito, J.; Oram, D.; Forster, G.; Lee, J. D.; Bauguitte, S.
2015-12-01
Terrestrial vegetation, especially tropical forests, releases large amounts of biogenic volatile organic compounds (BVOC) into the atmosphere. The global emissions of BVOC (~1000 Tg C/year) are dominant in relation to anthropogenic volatile organic compounds (~100 Tg C/year), with biomass burning contributing close to 10 - 50 Tg C/year. Tropical trees cover about 18% of the global land surface but are estimated to be responsible for approximately 80% of terpenoid and 50% of other BVOCs emissions. Considering the importance of these emissions, the SAMBBA (South American Biomass Burning Analysis) experiment, which occurred during the dry season (September 2012) in the Amazon Rainforest, provided information about the chemical composition of the atmosphere through measurements on the aircraft FAAM BAE-146. Although primarily focused on biomass burning flights, the SAMBBA project carried out other flights providing indirect oxidative capacity data in different environments: natural emission dominated flights and biomass burning flights with fresh plumes (< 2 hours) and aged plumes (> 2 hours). Calculation of the [MVK+MACR]/[Isoprene] ratio enabled investigation of the impact of biomass burning on surface oxidation in comparison to the natural emission flights. During the morning (altitude < 500m), the [MVK+MACR]/[Isoprene] values for natural emission flights (1.0±0.4), fresh plume (1.9±0.6) and aged plume (1.4±0.6) suggest that biomass burning enhances BVOC oxidation in relation to the lifetime of the air mass. This study aims to improve the knowledge about the oxidative capacity of the atmosphere, which depends not only on chemical composition, but also other factors like the history of the air mass trajectories influencing the availability of these compounds, the NOx dependence of isoprene oxidation and whether the chemistry is dominated by OH or O3. A synergistic approach integrating observation and modeling, using 3D numerical model of chemical transport (CCATT-BRAMS) coupled with a natural emission model (MEGAN) has been applied to study the BVOC in the Amazon rainforest. The SAMBBA experiment provided a valuable database that is being included into a numerical model of air quality, developing a numerical model that incorporates the understanding needed to represent the observations.
Limited effect of anthropogenic nitrogen oxides on Secondary Organic Aerosol formation
NASA Astrophysics Data System (ADS)
Zheng, Y.; Unger, N.; Hodzic, A.; Emmons, L.; Knote, C.; Tilmes, S.; Lamarque, J.-F.; Yu, P.
2015-08-01
Globally, secondary organic aerosol (SOA) is mostly formed from emissions of biogenic volatile organic compounds (VOCs) by vegetation, but can be modified by human activities as demonstrated in recent research. Specifically, nitrogen oxides (NOx = NO + NO2) have been shown to play a critical role in the chemical formation of low volatility compounds. We have updated the SOA scheme in the global NCAR Community Atmospheric Model version 4 with chemistry (CAM4-chem) by implementing a 4-product Volatility Basis Set (VBS) scheme, including NOx-dependent SOA yields and aging parameterizations. The predicted organic aerosol amounts capture both the magnitude and distribution of US surface annual mean measurements from the Interagency Monitoring of Protected Visual Environments (IMPROVE) network by 50 %, and the simulated vertical profiles are within a factor of two compared to Aerosol Mass Spectrometer (AMS) measurements from 13 aircraft-based field campaigns across different region and seasons. We then perform sensitivity experiments to examine how the SOA loading responds to a 50 % reduction in anthropogenic nitric oxide (NO) emissions in different regions. We find limited SOA reductions of 0.9 to 5.6, 6.4 to 12.0 and 0.9 to 2.8 % for global, the southeast US and the Amazon NOx perturbations, respectively. The fact that SOA formation is almost unaffected by changes in NOx can be largely attributed to buffering in chemical pathways (low- and high-NOx pathways, O3 versus NO3-initiated oxidation) and to offsetting tendencies in the biogenic versus anthropogenic SOA responses.
Limited effect of anthropogenic nitrogen oxides on secondary organic aerosol formation
NASA Astrophysics Data System (ADS)
Zheng, Y.; Unger, N.; Hodzic, A.; Emmons, L.; Knote, C.; Tilmes, S.; Lamarque, J.-F.; Yu, P.
2015-12-01
Globally, secondary organic aerosol (SOA) is mostly formed from emissions of biogenic volatile organic compounds (VOCs) by vegetation, but it can be modified by human activities as demonstrated in recent research. Specifically, nitrogen oxides (NOx = NO + NO2) have been shown to play a critical role in the chemical formation of low volatility compounds. We have updated the SOA scheme in the global NCAR (National Center for Atmospheric Research) Community Atmospheric Model version 4 with chemistry (CAM4-chem) by implementing a 4-product volatility basis set (VBS) scheme, including NOx-dependent SOA yields and aging parameterizations. Small differences are found for the no-aging VBS and 2-product schemes; large increases in SOA production and the SOA-to-OA ratio are found for the aging scheme. The predicted organic aerosol amounts capture both the magnitude and distribution of US surface annual mean measurements from the Interagency Monitoring of Protected Visual Environments (IMPROVE) network by 50 %, and the simulated vertical profiles are within a factor of 2 compared to aerosol mass spectrometer (AMS) measurements from 13 aircraft-based field campaigns across different regions and seasons. We then perform sensitivity experiments to examine how the SOA loading responds to a 50 % reduction in anthropogenic nitric oxide (NO) emissions in different regions. We find limited SOA reductions of 0.9-5.6, 6.4-12.0 and 0.9-2.8 % for global, southeast US and Amazon NOx perturbations, respectively. The fact that SOA formation is almost unaffected by changes in NOx can be largely attributed to a limited shift in chemical regime, to buffering in chemical pathways (low- and high-NOx pathways, O3 versus NO3-initiated oxidation) and to offsetting tendencies in the biogenic versus anthropogenic SOA responses.
NASA Astrophysics Data System (ADS)
María Yáñez-Serrano, Ana; Nölscher, Anke Christine; Bourtsoukidis, Efstratios; Gomes Alves, Eliane; Ganzeveld, Laurens; Bonn, Boris; Wolff, Stefan; Sa, Marta; Yamasoe, Marcia; Williams, Jonathan; Andreae, Meinrat O.; Kesselmeier, Jürgen
2018-03-01
Speciated monoterpene measurements in rainforest air are scarce, but they are essential for understanding the contribution of these compounds to the overall reactivity of volatile organic compound (VOC) emissions towards the main atmospheric oxidants, such as hydroxyl radicals (OH), ozone (O3) and nitrate radicals (NO3). In this study, we present the chemical speciation of gas-phase monoterpenes measured in the tropical rainforest at the Amazon Tall Tower Observatory (ATTO, Amazonas, Brazil). Samples of VOCs were collected by two automated sampling systems positioned on a tower at 12 and 24 m height and analysed using gas chromatography-flame ionization detection. The samples were collected in October 2015, representing the dry season, and compared with previous wet and dry season studies at the site. In addition, vertical profile measurements (at 12 and 24 m) of total monoterpene mixing ratios were made using proton-transfer-reaction mass spectrometry. The results showed a distinctly different chemical speciation between day and night. For instance, α-pinene was more abundant during the day, whereas limonene was more abundant at night. Reactivity calculations showed that higher abundance does not generally imply higher reactivity. Furthermore, inter- and intra-annual results demonstrate similar chemodiversity during the dry seasons analysed. Simulations with a canopy exchange modelling system show simulated monoterpene mixing ratios that compare relatively well with the observed mixing ratios but also indicate the necessity of more experiments to enhance our understanding of in-canopy sinks of these compounds.
Boverhof's App Earns Honorable Mention in Amazon's Web Services
» Boverhof's App Earns Honorable Mention in Amazon's Web Services Competition News & Publications News Publications Facebook Google+ Twitter Boverhof's App Earns Honorable Mention in Amazon's Web Services by Amazon Web Services (AWS). Amazon officially announced the winners of its EC2 Spotathon on Monday
Chemically modified carbonic anhydrases useful in carbon capture systems
Novick, Scott; Alvizo, Oscar
2013-01-15
The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.
Chemically modified carbonic anhydrases useful in carbon capture systems
Novick, Scott J; Alvizo, Oscar
2013-10-29
The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.
Amazon River dissolved load: temporal dynamics and annual budget from the Andes to the ocean.
Moquet, Jean-Sébastien; Guyot, Jean-Loup; Crave, Alain; Viers, Jérôme; Filizola, Naziano; Martinez, Jean-Michel; Oliveira, Tereza Cristina; Sánchez, Liz Stefanny Hidalgo; Lagane, Christelle; Casimiro, Waldo Sven Lavado; Noriega, Luis; Pombosa, Rodrigo
2016-06-01
The aim of the present study is to estimate the export fluxes of major dissolved species at the scale of the Amazon basin, to identify the main parameters controlling their spatial distribution and to identify the role of discharge variability in the variability of the total dissolved solid (TDS) flux through the hydrological cycle. Data are compiled from the monthly hydrochemistry and daily discharge database of the "Programa Climatologico y Hidrologico de la Cuenca Amazonica de Bolivia" (PHICAB) and the HYBAM observatories from 34 stations distributed over the Amazon basin (for the 1983-1992 and 2000-2012 periods, respectively). This paper consists of a first global observation of the fluxes and temporal dynamics of each geomorphological domain of the Amazon basin. Based on mean interannual monthly flux calculations, we estimated that the Amazon basin delivered approximately 272 × 10(6) t year(-1) (263-278) of TDS during the 2003-2012 period, which represents approximately 7 % of the continental inputs to the oceans. This flux is mainly made up by HCO3, Ca and SiO2, reflecting the preferential contributions of carbonate and silicate chemical weathering to the Amazon River Basin. The main tributaries contributing to the TDS flux are the Marañon and Ucayali Rivers (approximately 50 % of the TDS production over 14 % of the Amazon basin area) due to the weathering of carbonates and evaporites drained by their Andean tributaries. An Andes-sedimentary area-shield TDS flux (and specific flux) gradient is observed throughout the basin and is first explained by the TDS concentration contrast between these domains, rather than variability in runoff. This observation highlights that, under tropical context, the weathering flux repartition is primarily controlled by the geomorphological/geological setting and confirms that sedimentary areas are currently active in terms of the production of dissolved load. The log relationships of concentration vs discharge have been characterized over all the studied stations and for all elements. The analysis of the slope of the relationship within the selected contexts reveals that the variability in TDS flux is mainly controlled by the discharge variability throughout the hydrological year. At the outlet of the basin, a clockwise hysteresis is observed for TDS concentration and is mainly controlled by Ca and HCO3 hysteresis, highlighting the need for a sampling strategy with a monthly frequency to accurately determine the TDS fluxes of the basin. The evaporite dissolution flux tends to be constant, whereas dissolved load fluxes released from other sources (silicate weathering, carbonate weathering, biological and/or atmospheric inputs) are mainly driven by variability in discharge. These results suggest that past and further climate variability had or will have a direct impact on the variability of dissolved fluxes in the Amazon. Further studies need to be performed to better understand the processes controlling the dynamics of weathering fluxes and their applicability to present-day concentration-discharge relationships at longer timescales.
Amazon Forests Response to Droughts: A Perspective from the MAIAC Product
NASA Technical Reports Server (NTRS)
Bi, Jian; Myneni, Ranga; Lyapustin, Alexei; Wang, Yujie; Park, Taejin; Chi, Chen; Yan, Kai; Knyazikhin, Yuri
2016-01-01
Amazon forests experienced two severe droughts at the beginning of the 21st century: one in 2005 and the other in 2010. How Amazon forests responded to these droughts is critical for the future of the Earth's climate system. It is only possible to assess Amazon forests' response to the droughts in large areal extent through satellite remote sensing. Here, we used the Multi-Angle Implementation of Atmospheric Correction (MAIAC) Moderate Resolution Imaging Spectroradiometer (MODIS) vegetation index (VI) data to assess Amazon forests' response to droughts, and compared the results with those from the standard (Collection 5 and Collection 6) MODIS VI data. Overall, the MAIAC data reveal more realistic Amazon forests inter-annual greenness dynamics than the standard MODIS data. Our results from the MAIAC data suggest that: (1) the droughts decreased the greenness (i.e., photosynthetic activity) of Amazon forests; (2) the Amazon wet season precipitation reduction induced by El Niño events could also lead to reduced photosynthetic activity of Amazon forests; and (3) in the subsequent year after the water stresses, the greenness of Amazon forests recovered from the preceding decreases. However, as previous research shows droughts cause Amazon forests to reduce investment in tissue maintenance and defense, it is not clear whether the photosynthesis of Amazon forests will continue to recover after future water stresses, because of the accumulated damages caused by the droughts.
NASA Astrophysics Data System (ADS)
Andreae, M. O.; Afchine, A.; Albrecht, R. I.; Artaxo, P.; Borrmann, S.; Cecchini, M. A.; Costa, A.; Dollner, M.; Fütterer, D.; Järvinen, E.; Klimach, T.; Konemann, T.; Kraemer, M.; Krüger, M. L.; Machado, L.; Mertes, S.; Pöhlker, C.; Poeschl, U.; Sauer, D. N.; Schnaiter, M.; Schneider, J.; Schulz, C.; Spanu, A.; Walser, A.; Weinzierl, B.; Wendisch, M.
2015-12-01
The German-Brazilian cooperative aircraft campaign ACRIDICON-CHUVA (Aerosol, Cloud, Precipitation, and Radiation Interactions and Dynamics of Convective Cloud Systems) on the German research aircraft HALO took place over the Amazon Basin in September/October 2014, with the objective of studying tropical deep convective clouds over the Amazon rainforest and their interactions with trace gases, aerosol particles, and atmospheric radiation. The aircraft was equipped with about 30 remote sensing and in-situ instruments for meteorological, trace gas, aerosol, cloud, precipitation, and solar radiation measurements. Fourteen research flights were conducted during this campaign. Observations during ACRIDICON-CHUVA showed high aerosol concentrations in the upper troposphere (UT) over the Amazon Basin, with concentrations after normalization to standard conditions often exceeding those in the boundary layer (BL). This behavior was consistent between several aerosol metrics, including condensation nuclei (CN), cloud condensation nuclei (CCN), and chemical species mass concentrations. These UT aerosols were different in their composition and size distribution from the aerosol in the BL, making convective transport of particles unlikely as a source. The regions in the immediate outflow of deep convective clouds were found to be depleted in aerosol particles, whereas enhanced aerosol number and mass concentrations were found in UT regions that had experienced outflow from deep convection in the preceding 24-48 hours. This suggests that aerosol production takes place in the UT based on volatile and condensable material brought up by deep convection. Subsequently, downward mixing and transport of upper tropospheric aerosol may be a source of particles to the BL, where they increase in size by the condensation of biogenic volatile organic carbon (BVOC) oxidation products. This may be an important source of aerosol particles in the Amazonian BL, where aerosol nucleation and new particle formation has not been observed.
Aircraft measurements of aerosol properties during GoAmazon - G1 and HALO inter-comparison
NASA Astrophysics Data System (ADS)
Mei, F.; Cecchini, M. A.; Wang, J.; Tomlinson, J. M.; Comstock, J. M.; Hubbe, J. M.; Pekour, M. S.; Machado, L.; Wendisch, M.; Longo, K.; Martin, S. T.; Schmid, B.; Weinzierl, B.; Krüger, M. L.; Zöger, M.
2015-12-01
Currently, the indirect effects of atmospheric aerosols remain the most uncertain components in forcing of climate change over the industrial period (IPCC, 2013). This large uncertainty is partially a result of our incomplete understanding of the ability of particles to form cloud droplets under atmospherically relevant supersaturations. One objective of the US Department of Energy (DOE) Green Ocean Amazon Project (GoAmazon2014/5) is to understand the influence of the emission from Manaus, a tropical megacity, on aerosol size, concentration, and chemical composition, and their impact on cloud condensation nuclei (CCN) spectrum. The GoAmazon2014/5 study was an international campaign with the collaboration efforts from US, Brazil and Germany. During the intensive operation period, in the dry season (Sep. 1st - Oct. 10th, 2014), aerosol concentration, size distributions, and CCN spectra, both under pristine conditions and inside the Manaus plume, were characterized in-situ from the DOE Gulfstream-1 (G-1) research aircraft and German HALO aircraft during 4 coordinated flights on Sep. 9th, Sep. 16th, Sep 21st and Oct. 1st, 2014. During those four flights, aerosol number concentrations and CCN concentrations at two supersaturations (0.25% and 0.5%) were measured by condensation particle counters (CPCs) and a DMT dual column CCN counter onboard both G-1 and HALO. Aerosol size distribution was also measured by a Fast Integrated Mobility Spectrometer (FIMS) aboard the G-1 and is compared with the size distribution from Ultra High Sensitivity Aerosol Spectrometer - Airborne (UHSAS-A, DMT), which were deployed both on the G-1 and the HALO. Good agreement between the aerosol properties measured from the two aircraft has been achieved. The vertical profiles of aerosol size distribution and CCN spectrum will be discussed.
Confluence of the Amazon and Topajos Rivers, Brazil, South America
1991-08-11
This view shows the confluence of the Amazon and the Topajos Rivers at Santarem, Brazil (2.0S, 55.0W). The Am,azon flows from lower left to upper right of the photo. Below the river juncture of the Amazon and Tapajos, there is considerable deforestation activity along the Trans-Amazon Highway.
2010-06-01
Woods Hole, MA 02543, USA 3 Raytheon Intelligence and Information Systems, Aurora , CO 80011, USA 4 Scripps Institution of Oceanography, La Jolla...Amazon.com, Amazon Web Services for the Amazon Elastic Compute Cloud ( Amazon EC2). http://aws.amazon.com/ec2/. [4] M. Arrott, B. Demchak, V. Ermagan, C
Relationship of tooth wear to chronological age among indigenous Amazon populations.
Vieira, Elma Pinto; Barbosa, Mayara Silva; Quintão, Cátia Cardoso Abdo; Normando, David
2015-01-01
In indigenous populations, age can be estimated based on family structure and physical examination. However, the accuracy of such methods is questionable. The aim of this cross-sectional study was to evaluate occlusal tooth wear related to estimated age in the remote indigenous populations of the Xingu River, Amazon. Two hundred and twenty three semi-isolated indigenous subjects with permanent dentition from the Arara (n = 117), Xicrin-Kayapó (n = 60) and Assurini (n = 46) villages were examined. The control group consisted of 40 non-indigenous individuals living in an urban area in the Amazon basin (Belem). A modified tooth wear index was applied and then associated with chronological age by linear regression analysis. A strong association was found between tooth wear and chronological age in the indigenous populations (p <0.001). Tooth wear measurements were able to explain 86% of the variation in the ages of the Arara sample, 70% of the Xicrin-Kaiapó sample and 65% of the Assurini sample. In the urban control sample, only 12% of ages could be determined by tooth wear. These findings suggest that tooth wear is a poor estimator of chronological age in the urban population; however, it has a strong association with age for the more remote indigenous populations. Consequently, these findings suggest that a simple tooth wear evaluation method, as described and applied in this study, can be used to provide a straightforward and efficient means to assist in age determination of newly contacted indigenous groups.
Relationship of Tooth Wear to Chronological Age among Indigenous Amazon Populations
Vieira, Elma Pinto; Barbosa, Mayara Silva; Quintão, Cátia Cardoso Abdo; Normando, David
2015-01-01
In indigenous populations, age can be estimated based on family structure and physical examination. However, the accuracy of such methods is questionable. The aim of this cross-sectional study was to evaluate occlusal tooth wear related to estimated age in the remote indigenous populations of the Xingu River, Amazon. Two hundred and twenty three semi-isolated indigenous subjects with permanent dentition from the Arara (n = 117), Xicrin-Kayapó (n = 60) and Assurini (n = 46) villages were examined. The control group consisted of 40 non-indigenous individuals living in an urban area in the Amazon basin (Belem). A modified tooth wear index was applied and then associated with chronological age by linear regression analysis. A strong association was found between tooth wear and chronological age in the indigenous populations (p <0.001). Tooth wear measurements were able to explain 86% of the variation in the ages of the Arara sample, 70% of the Xicrin-Kaiapó sample and 65% of the Assurini sample. In the urban control sample, only 12% of ages could be determined by tooth wear. These findings suggest that tooth wear is a poor estimator of chronological age in the urban population; however, it has a strong association with age for the more remote indigenous populations. Consequently, these findings suggest that a simple tooth wear evaluation method, as described and applied in this study, can be used to provide a straightforward and efficient means to assist in age determination of newly contacted indigenous groups. PMID:25602501
NASA Astrophysics Data System (ADS)
Carbone, S.; Ferreira De Brito, J.; Cirino, G. G.; Rizzo, L. V.; Holanda, B. A.; Barbosa, H. M.; Ditas, F.; Pöhlker, C.; Chi, X.; Krüger, M. L.; Moran, D.; Saturno, J.; Andreae, M. O.; de Sá, S. S.; Liu, Y.; Martin, S. T.; Souza, R. A. F. D.; Wang, J.; Palm, B. B.; Jimenez, J. L.; Artaxo, P.
2015-12-01
The Amazon Basin during the wet season has one of the lowest aerosol concentrations worldwide, with air masses with negligible human impact covering thousands of kilometers of pristine forest. The natural environment is strongly modified near urbanized areas, in particular Manaus, a city of nearly two million people. This unique location provides the ideal laboratory to study isolated urban emissions as well the pristine environment by perturbing it in a relatively known fashion. The GoAmazon2014/5 experiment was designed with these questions in mind, combining remote sensing, in situ, and airborne measurements. This manuscript describes the measurements taken at the T0 site, upwind of Manaus, (the Amazonian Tall Tower Observatory, ATTO site), at the T2 site, near Manaus, frequently impacted by relatively fresh emissions from the city and at T3, 60 km downwind of Manaus. This work relates the aerosol dynamics of the mixture of anthropogenic emissions from Manaus and the biogenic air masses, and how it evolves from T2 to T3 under different atmospheric conditions. Focus is on the aerosol size distribution, supported by aerosol mass spectrometry and gas-phase composition, in particular at the T2 site. At T0, the aerosol number concentration has been observed to increase from an average of 380 cm-3 to 1750 cm-3 from the wet to the dry season. The mean geometric diameter increased as well, from 95 nm to 145 nm. Interestingly, at the T2 site no significant difference was observed in number concentration between wet and dry seasons (approximately 4300 cm-3) with an average diameter of 60 nm during the former and 97 nm in the latter. Such measurements provide a unique dataset to understand the aerosol life cycle and the impact of urban emissions in the heart of the Amazon Forest.
Basin-wide variations in Amazon forest structure and function are mediated by both soils and climate
NASA Astrophysics Data System (ADS)
Quesada, C. A.; Phillips, O. L.; Schwarz, M.; Czimczik, C. I.; Baker, T. R.; Patiño, S.; Fyllas, N. M.; Hodnett, M. G.; Herrera, R.; Almeida, S.; Alvarez Dávila, E.; Arneth, A.; Arroyo, L.; Chao, K. J.; Dezzeo, N.; Erwin, T.; di Fiore, A.; Higuchi, N.; Honorio Coronado, E.; Jimenez, E. M.; Killeen, T.; Lezama, A. T.; Lloyd, G.; López-González, G.; Luizão, F. J.; Malhi, Y.; Monteagudo, A.; Neill, D. A.; Núñez Vargas, P.; Paiva, R.; Peacock, J.; Peñuela, M. C.; Peña Cruz, A.; Pitman, N.; Priante Filho, N.; Prieto, A.; Ramírez, H.; Rudas, A.; Salomão, R.; Santos, A. J. B.; Schmerler, J.; Silva, N.; Silveira, M.; Vásquez, R.; Vieira, I.; Terborgh, J.; Lloyd, J.
2012-06-01
Forest structure and dynamics vary across the Amazon Basin in an east-west gradient coincident with variations in soil fertility and geology. This has resulted in the hypothesis that soil fertility may play an important role in explaining Basin-wide variations in forest biomass, growth and stem turnover rates. Soil samples were collected in a total of 59 different forest plots across the Amazon Basin and analysed for exchangeable cations, carbon, nitrogen and pH, with several phosphorus fractions of likely different plant availability also quantified. Physical properties were additionally examined and an index of soil physical quality developed. Bivariate relationships of soil and climatic properties with above-ground wood productivity, stand-level tree turnover rates, above-ground wood biomass and wood density were first examined with multivariate regression models then applied. Both forms of analysis were undertaken with and without considerations regarding the underlying spatial structure of the dataset. Despite the presence of autocorrelated spatial structures complicating many analyses, forest structure and dynamics were found to be strongly and quantitatively related to edaphic as well as climatic conditions. Basin-wide differences in stand-level turnover rates are mostly influenced by soil physical properties with variations in rates of coarse wood production mostly related to soil phosphorus status. Total soil P was a better predictor of wood production rates than any of the fractionated organic- or inorganic-P pools. This suggests that it is not only the immediately available P forms, but probably the entire soil phosphorus pool that is interacting with forest growth on longer timescales. A role for soil potassium in modulating Amazon forest dynamics through its effects on stand-level wood density was also detected. Taking this into account, otherwise enigmatic variations in stand-level biomass across the Basin were then accounted for through the interacting effects of soil physical and chemical properties with climate. A hypothesis of self-maintaining forest dynamic feedback mechanisms initiated by edaphic conditions is proposed. It is further suggested that this is a major factor determining endogenous disturbance levels, species composition, and forest productivity across the Amazon Basin.
Kelvin Wave Influence on the Shallow-to-Deep Transition Over the Amazon
NASA Astrophysics Data System (ADS)
Rowe, A.; Serra, Y. L.
2017-12-01
The suite of observations from GOAmazon and CHUVA offers a unique opportunity to examine land-based convective processes in the tropics, including the poorly represented shallow-to-deep transition. This study uses these data to investigate impacts of Kelvin waves on the the shallow-to-deep transition over the Central Amazon. The Kelvin waves that propagate over the region often originate over the tropical central and east Pacific, with local generation over the Andes also observed. The observed 15 m s-1 phase speed and 4500 km wave length during the two-year campaign are in agreement with previously published studies of these waves across the tropics. Also in agreement with previous studies, we find the waves are most active during the wet season (November-May) for this region. Using four separate convective event classes (clear-sky, nonprecipitating cumulus congestus, afternoon deep convection, and mesoscale convective systems), we examine how the convection preferentially develops for different phases of the Kelvin waves seen during GOAmazon. We additionally examine surface meteorological variables, the vertical thermodynamic and dynamic structure of the troposphere, vertical moist static stability, integrated column water vapor and liquid water, and surface energy fluxes within the context of these convective classes to identify the important environmental factors contributing to observed periods of enhanced deep convection related to the waves. Results suggest that the waves significantly modify the local environment, such as creating a deep layer of moisture throughout the troposphere, favoring more organized convection in the active than in the suppressed phase of the wave. The significance of wave-related environmental modifications are assessed by comparing local rainfall accumulations during Kelvin wave activity to that when the waves are not present. Future work will further explore the shallow-to-deep transition and its modulation by Kelvin wave activity over the Central Amazon in both global and regional model simulations with differing resolution and choice of convective parameterization. This work will test the hypothesis that when the environment is strongly modified by a Kelvin wave, model shallow-to-deep transition will be better simulated than when this forcing is not present.
Flow Estimate of Carbon Dioxide in a Amazon River Hydrological Station
NASA Astrophysics Data System (ADS)
Moura, J. M. S.; Ferreira, R. B., Jr.; Tapajós, R. P.
2014-12-01
Recent measurements in the Amazon suggest that the flow of CO2 in surface waters may reach the order of 1GT per year and isotopic analyzes suggest that this carbon is a direct result of organic matter degradation (OMD) in rivers and the measured concentration exceeds the value expected for there to be equilibrium with the atmosphere (Richey et al, 2002). This study aimed to measure and check the seasonal variability of CO2 fluxes in a range of six months (September 2013-February 2014) in the Strait Óbidos hydrological station located geographically in the coordinates 55 ° 1 '4 "S and 55 ° 31' 4" W. In addiction, it is intended to correlate the data with physical-chemical water parameters pH, dissolved oxygen (DO), and temperature and humidity. The method used for the measurement of CO2 concentration in the atmosphere-water interface is the floating chamber liked with an infrared gas analyzer (IRGA- Infrared Gas Analyzer). The physical-chemical parameters of water were measured using a multiparameter probe YSI Professional Plus model. The preliminary results shows values average CO2 flux was approximately 15.65 1,01ppm / m2s-1 for the months of September and October and between the months of November, 2013 and February 2014 the CO2 flux average was 4.40 + 1.94 ppm / m2s-1. In addiction to the high temperature in dry season, in the water column there is sufficient convection for the existence of gases transport from water to atmosphere, resulting in increase of exchange. Thus, the decreased amount of radiation and consequently the low temperatures in the humid period (on average 27.2 ° C) should affect the OMD in the river, responsible for the production of dissolved CO2. Keywords: CO2 flux, seasonal variability, amazon river
Nery, José Reinaldo Cardoso; Bonotto, Daniel Marcos
2011-04-01
Activity profiles of excess (210)Pb determined in three sediment cores from Amazon River mouth, Macapá city, Brazil, provided the evaluation of sedimentation rates, contributing to a better knowledge of the hydrological conditions in the site that is the capital of Amapá State and is drained by the waters of the huge Amazon River. Chemical data were also determined in the sediments, allowing identify signatures coupled to anthropogenic inputs held in the past in Amapá State. Significant direct relationships between LOI (loss on ignition) and organic matter were found for all sediments profiles. Silica was found to be inversely related to organic matter in the three profiles; its decrease accompanied an increase on the specific surface of the sediments. This relationship was confirmed by a great number of inverse significant correlations among silica and oxides Na(2)O, K(2)O, CaO, MgO, Al(2)O(3), P(2)O(5), Fe(2)O(3) and MnO. It was possible to identify the role of organic matter on adsorption of several oxides in the core sediments profiles. Apparent sediment mass accumulation rates corresponding to values between 450 and 2510 mg cm(-2)yr(-1) were obtained, and are compatible with the results of others studies. The (210)Pb activities in one sampling point suggested the occurrence of anthropogenic inputs related to the initial period of the mining activities conducted in Serra do Navio, Amapá State, for the commercialization of Mn ores. This was reinforced by the abrupt fluctuations in chemical data obtained for the sediments and composition of the interstitial waters occurring there. The Atlantic hurricane activity also appeared to affect the sedimentation rates in the area, as two different values were recorded in each profile. Copyright © 2011 Elsevier Ltd. All rights reserved.
GoAmazon2014/5 campaign points to deep-inflow approach to deep convection across scales
Schiro, Kathleen A.; Ahmed, Fiaz; Giangrande, Scott E.; ...
2018-04-17
Representations of strongly precipitating deep-convective systems in climate models are among the most important factors in their simulation. Parameterizations of these motions face the dual challenge of unclear pathways to including mesoscale organization and high sensitivity of convection to approximations of turbulent entrainment of environmental air. Ill-constrained entrainment processes can even affect global average climate sensitivity under global warming. Multiinstrument observations from the Department of Energy GoAmazon2014/5 field campaign suggest that an alternative formulation from radar-derived dominant updraft structure yields a strong relationship of precipitation to buoyancy in both mesoscale and smaller-scale convective systems. This simultaneously provides a key stepmore » toward representing the influence of mesoscale convection in climate models and sidesteps a problematic dependence on traditional entrainment rates. A substantial fraction of precipitation is associated with mesoscale convective systems (MCSs), which are currently poorly represented in climate models. Convective parameterizations are highly sensitive to the assumptions of an entraining plume model, in which high equivalent potential temperature air from the boundary layer is modified via turbulent entrainment. Here we show, using multiinstrument evidence from the Green Ocean Amazon field campaign (2014–2015; GoAmazon2014/5), that an empirically constrained weighting for inflow of environmental air based on radar wind profiler estimates of vertical velocity and mass flux yields a strong relationship between resulting buoyancy measures and precipitation statistics. This deep-inflow weighting has no free parameter for entrainment in the conventional sense, but to a leading approximation is simply a statement of the geometry of the inflow. The structure further suggests the weighting could consistently apply even for coherent inflow structures noted in field campaign studies for MCSs over tropical oceans. For radar precipitation retrievals averaged over climate model grid scales at the GoAmazon2014/5 site, the use of deep-inflow mixing yields a sharp increase in the probability and magnitude of precipitation with increasing buoyancy. Furthermore, this applies for both mesoscale and smaller-scale convection. Results from reanalysis and satellite data show that this holds more generally: Deep-inflow mixing yields a strong precipitation–buoyancy relation across the tropics. Lastly, deep-inflow mixing may thus circumvent inadequacies of current parameterizations while helping to bridge the gap toward representing mesoscale convection in climate models.« less
GoAmazon2014/5 campaign points to deep-inflow approach to deep convection across scales
DOE Office of Scientific and Technical Information (OSTI.GOV)
Schiro, Kathleen A.; Ahmed, Fiaz; Giangrande, Scott E.
Representations of strongly precipitating deep-convective systems in climate models are among the most important factors in their simulation. Parameterizations of these motions face the dual challenge of unclear pathways to including mesoscale organization and high sensitivity of convection to approximations of turbulent entrainment of environmental air. Ill-constrained entrainment processes can even affect global average climate sensitivity under global warming. Multiinstrument observations from the Department of Energy GoAmazon2014/5 field campaign suggest that an alternative formulation from radar-derived dominant updraft structure yields a strong relationship of precipitation to buoyancy in both mesoscale and smaller-scale convective systems. This simultaneously provides a key stepmore » toward representing the influence of mesoscale convection in climate models and sidesteps a problematic dependence on traditional entrainment rates. A substantial fraction of precipitation is associated with mesoscale convective systems (MCSs), which are currently poorly represented in climate models. Convective parameterizations are highly sensitive to the assumptions of an entraining plume model, in which high equivalent potential temperature air from the boundary layer is modified via turbulent entrainment. Here we show, using multiinstrument evidence from the Green Ocean Amazon field campaign (2014–2015; GoAmazon2014/5), that an empirically constrained weighting for inflow of environmental air based on radar wind profiler estimates of vertical velocity and mass flux yields a strong relationship between resulting buoyancy measures and precipitation statistics. This deep-inflow weighting has no free parameter for entrainment in the conventional sense, but to a leading approximation is simply a statement of the geometry of the inflow. The structure further suggests the weighting could consistently apply even for coherent inflow structures noted in field campaign studies for MCSs over tropical oceans. For radar precipitation retrievals averaged over climate model grid scales at the GoAmazon2014/5 site, the use of deep-inflow mixing yields a sharp increase in the probability and magnitude of precipitation with increasing buoyancy. Furthermore, this applies for both mesoscale and smaller-scale convection. Results from reanalysis and satellite data show that this holds more generally: Deep-inflow mixing yields a strong precipitation–buoyancy relation across the tropics. Lastly, deep-inflow mixing may thus circumvent inadequacies of current parameterizations while helping to bridge the gap toward representing mesoscale convection in climate models.« less
Lemos, Leandro Nascimento; de Souza, Rosineide Cardoso; de Souza Cannavan, Fabiana; Patricio, André; Pylro, Victor Satler; Hanada, Rogério Eiji; Mui, Tsai Siu
2016-12-01
The Anthropogenic Amazon Dark Earth soil is considered one of the world's most fertile soils. These soils differs from conventional Amazon soils because its higher organic content concentration. Here we describe the metagenome sequencing of microbial communities of two sites of Anthropogenic Amazon Dark Earth soils from Amazon Rainforest, Brazil. The raw sequence data are stored under Short Read Accession number: PRJNA344917.
40 CFR 721.6498 - Modified polyisocyanates (generic).
Code of Federal Regulations, 2010 CFR
2010-07-01
... SUBSTANCES CONTROL ACT SIGNIFICANT NEW USES OF CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.6498 Modified polyisocyanates (generic). (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as modified polyisocyanates (PMN P...
40 CFR 721.6498 - Modified polyisocyanates (generic).
Code of Federal Regulations, 2012 CFR
2012-07-01
... SUBSTANCES CONTROL ACT SIGNIFICANT NEW USES OF CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.6498 Modified polyisocyanates (generic). (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as modified polyisocyanates (PMN P...
40 CFR 721.6498 - Modified polyisocyanates (generic).
Code of Federal Regulations, 2011 CFR
2011-07-01
... SUBSTANCES CONTROL ACT SIGNIFICANT NEW USES OF CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.6498 Modified polyisocyanates (generic). (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as modified polyisocyanates (PMN P...
Unraveling the antibacterial mode of action of a clay from the Colombian Amazon.
Londono, Sandra Carolina; Williams, Lynda B
2016-04-01
Natural antibacterial clays can inhibit growth of human pathogens; therefore, understanding the antibacterial mode of action may lead to new applications for health. The antibacterial modes of action have shown differences based on mineralogical constraints. Here we investigate a natural clay from the Colombian Amazon (AMZ) known to the Uitoto natives as a healing clay. The physical and chemical properties of the AMZ clay were compared to standard reference materials: smectite (SWy-1) and kaolinite (API #5) that represent the major minerals in AMZ. We tested model Gram-negative (Escherichia coli ATCC #25922) and Gram-positive (Bacillus subtilis ATCC #6633) bacteria to assess the clay's antibacterial effectiveness against different bacterial types. The chemical and physical changes in the microbes were examined using bioimaging and mass spectrometry of clay digests and aqueous leachates. Results indicate that a single dose of AMZ clay (250 mg/mL) induced a 4-6 order of magnitude reduction in cell viability, unlike the reference clays that did not impact bacterial survival. AMZ clay possesses a relatively high specific surface area (51.23 m(2)/g) and much higher total surface area (278.82 m(2)/g) than the reference clays. In aqueous suspensions (50 mg clay/mL water), soluble metals are released and the minerals buffer fluid pH between 4.1 and 4.5. We propose that the clay facilitates chemical interactions detrimental to bacteria by absorbing nutrients (e.g., Mg, P) and potentially supplying metals (e.g., Al) toxic to bacteria. This study demonstrates that native traditional knowledge can direct scientific studies.
Johnston, Matthew S; Thode, Henry P; Ehrhart, Nicole P
2008-03-01
A yellow-naped Amazon parrot (Amazona ochrocephala auropalliata) was presented 5 months after a traumatic fracture of its left tibiotarsus. Fixation of the simple, closed, mid-diaphyseal fracture was originally with an intramedullary pin and external coaptation with a modified Robert-Jones bandage. During the subsequent 5 months, the bone became osteopenic, and the middle third of the tibiotarsus exhibited probable avascular necrosis. After various fixation attempts failed, the parrot was fitted with a ring fixator device, and bone transport osteogenesis was attempted. Within 7 weeks, the left tibiotarsus had regrown to full length, but the docking site at the proximal fracture line had not healed. After 2 more surgeries to debride bone ends to stimulate healing, the leg in this parrot became functional. This is the first reported clinical use of bone transport osteogenesis in a pet bird. Materials and techniques were applied successfully to this parrot, which suggests that bone transport osteogenesis deserves further study for the repair of large bone defects in birds.
Aston, Emily J.; Mayor, Pedro; Bowman, Dwight D.; Mohammed, Hussni O.; Liotta, Janice L.; Kwok, Oliver; Dubey, J.P.
2013-01-01
Toxoplasmosis is a zoonosis caused by the protozoan Toxoplasma gondii, and it is found worldwide. To determine whether ungulates are reservoirs of T. gondii in an isolated and remote region of the northeastern Peruvian Amazon, antibodies to T. gondii were determined in 5 species of ungulates by the modified agglutination test (MAT). These animals were hunted by subsistence hunters along the Yavarí-Mirín River, in the northeastern Peruvian Amazon. Blood samples were collected by hunters on filter papers. For determination of T. gondii antibodies, blood was eluted from filter papers, and a titer of 1:25 was considered indicative of exposure to T. gondii. Antibodies to T. gondii were found in 26 (31.0%) peccaries (Pecari tajacu, Tayassu pecari), six (17.1%) brocket deer (Mazama americana, Mazama gouazoubira), and four (40.0%) lowland tapir (Tapirus terrestris). We also introduced a modification to the MAT protocol that allows the extraction of fluid samples from several types of laboratory-grade filter paper, thus enabling researchers to easily adapt their approaches to the materials presented to them. PMID:24918073
Multi-model analysis of the Atlantic influence on Southern Amazon rainfall
Yoon, Jin -Ho
2015-12-07
Amazon rainfall is subject to year-to-year fluctuation resulting in drought and flood in various intensities. A major climatic driver of the interannual variation of the Amazon rainfall is El Niño/Southern Oscillation. Also, the Sea Surface Temperature over the Atlantic Ocean is identified as an important climatic driver on the Amazon water cycle. Previously, observational datasets were used to support the Atlantic influence on Amazon rainfall. Furthermore, it is found that multiple global climate models do reproduce the Atlantic-Amazon link robustly. However, there exist differences in rainfall response, which primarily depends on the climatological rainfall amount.
2009-06-03
the Amazon falls within Brazilian borders, making Brazil home to 40% of the world’s remaining tropical forests.96 The Brazilian Amazon was largely...20 Amazon Conservation......................................................................................................... 20 Domestic Efforts...independence in 1822, Brazil occupies almost half of the continent of South America and boasts immense biodiversity, including the vast Amazon
Limited effect of anthropogenic nitrogen oxides on Secondary Organic Aerosol formation
Zheng, Y.; Unger, N.; Hodzic, A.; ...
2015-08-28
Globally, secondary organic aerosol (SOA) is mostly formed from emissions of biogenic volatile organic compounds (VOCs) by vegetation, but can be modified by human activities as demonstrated in recent research. Specifically, nitrogen oxides (NO x = NO + NO 2) have been shown to play a critical role in the chemical formation of low volatility compounds. We have updated the SOA scheme in the global NCAR Community Atmospheric Model version 4 with chemistry (CAM4-chem) by implementing a 4-product Volatility Basis Set (VBS) scheme, including NO x-dependent SOA yields and aging parameterizations. The predicted organic aerosol amounts capture both the magnitudemore » and distribution of US surface annual mean measurements from the Interagency Monitoring of Protected Visual Environments (IMPROVE) network by 50 %, and the simulated vertical profiles are within a factor of two compared to Aerosol Mass Spectrometer (AMS) measurements from 13 aircraft-based field campaigns across different region and seasons. We then perform sensitivity experiments to examine how the SOA loading responds to a 50 % reduction in anthropogenic nitric oxide (NO) emissions in different regions. We find limited SOA reductions of 0.9 to 5.6, 6.4 to 12.0 and 0.9 to 2.8 % for global, the southeast US and the Amazon NO x perturbations, respectively. The fact that SOA formation is almost unaffected by changes in NO x can be largely attributed to buffering in chemical pathways (low- and high-NO x pathways, O 3 versus NO 3-initiated oxidation) and to offsetting tendencies in the biogenic versus anthropogenic SOA responses.« less
NASA Astrophysics Data System (ADS)
Lambs, Luc; Muller, Etienne; Fromard, F.
2007-08-01
SummaryFrench Guiana is notable for the extent of its rain forests, which occupy 97% of the country, and the influence of the Amazon along its shores. In fact, the shores and estuaries support a mangrove forest typical of saline conditions. This paper reports the chemical characteristics, conductivity and salinity and the stable isotopes (oxygen and deuterium) of the rivers and shores between the Cayenne area and the border with Surinam. The results show a quite homogenous freshwater pool over the country. However, the low slope of the coast, a result of the wide mud banks deposited by the Amazonian plume, have turned the mouths of the smaller rivers to the northwest, creating large salty areas where mangroves grow several kilometers inland. Despite the large amount of Amazonian water, the Guianan coast exhibits high salinity. In fact, the freshwater itself remains far from the shore, following the north Brazilian current, while only the mud plume arrives at the coast, creating this paradox.
Business as Usual: Amazon.com and the Academic Library
ERIC Educational Resources Information Center
Van Ullen, Mary K.; Germain, Carol Anne
2002-01-01
In 1999, Steve Coffman proposed that libraries form a single interlibrary loan based entity patterned after Amazon.com. This study examined the suitability of Amazon.com's Web interface and record enhancements for academic libraries. Amazon.com could not deliver circulating monographs in the University at Albany Libraries' collection quickly…
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kim, Saewung
The University of California, Irvine, science team (Dr. Saewung Kim, Dr. Roger Seco, Dr. Alex Guenther, and Dr. Jim Smith) deployed a chemical ionization mass spectrometer system for hydroxyl radical (OH) and sulfuric acid quantifications. As part of the GoAmazon 2014/15 field campaign. Hydroxyl radical determines tropospheric oxidation capacity and had been expected to be very low in the pristine rain forest region such as the Brazilian Amazon because of the presence of significant levels of highly reactive biogenic volatile organic compounds and very low levels of NO, which is an OH recycling agent. However, several recent in situ OHmore » observations provided by a laser-induced fluorescence system reported unaccountably high OH concentrations. To address this discrepancy, a series of laboratory and theoretical studies has postulated chemical reaction mechanisms of isoprene that may regenerate OH in photo-oxidation processes. Along with these efforts, potential artifacts on the laser induced fluorescence system from isoprene and its oxidation products also have been explored. Therefore, the first chemical ionization mass spectrometer observations at the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Climate Research Facility’s T3 site in Manacapuru, Brazil, are expected to provide a critical experimental constraint to address uncertainty in constraining oxidation capacity over pristine rain forest environments. In addition, we deployed a National Center for Atmospheric Research (NCAR) proton transfer reaction time-of-flight mass spectrometer to characterize atmospheric volatile organic compound levels, especially isoprene and its oxidation products, which are critical input parameters for box modeling to simulate OH with different isoprene photo-oxidation schemes. As there has been no report on noticeable new particle formation events, our first in situ sulfuric acid observations in the Amazon rain forest were expected to constrain the reasons behind such observations. The planned field observations during Intensive Observational Periods I and II, post-field campaign calibrations, and preliminary data reports have been completed. We presented preliminary data analysis results at the 2014 American Geophysical Union Fall meeting and the GOAmazon Science Meeting in Boston (May 2015). We are in the process of submitting two more abstracts to the 2015 American Geophysical Union fall meeting while we are preparing two manuscripts to be submitted to (tentatively) the GOAmazon special issue of Atmospheric Chemistry and Physics.« less
What We Can Learn from Amazon for Clinical Decision Support Systems.
Abid, Sidra; Keshavjee, Karim; Karim, Arsalan; Guergachi, Aziz
2017-01-01
Health care continue to lag behind other industries, such as retail and financial services, in the use of decision-support-like tools. Amazon is particularly prolific in the use of advanced predictive and prescriptive analytics to assist its customers to purchase more, while increasing satisfaction, retention, repeat-purchases and loyalty. How can we do the same in health care? In this paper, we explore various elements of the Amazon website and Amazon's data science and big data practices to gather inspiration for re-designing clinical decision support in the health care sector. For each Amazon element we identified, we present one or more clinical applications to help us better understand where Amazon's.
Brilhante, Andreia Fernandes; de Ávila, Márcia Moreira; de Souza, Jailson Ferreira; Medeiros-Sousa, Antônio Ralph; Sábio, Priscila Bassan; de Paula, Marcia Bicudo; Godoy, Rodrigo Espindola; Melchior, Leonardo Augusto Kohara; Nunes, Vânia Lúcia Brandão; de Oliveira Cardoso, Cristiane; Galati, Eunice Aparecida Bianchi
2017-01-01
In the Amazon region the phlebotomine fauna is considered one of the most diverse in the world. The use of Shannon traps may provide information on the anthropophily of the species and improve the traps’ performance in terms of diversity and quantity of insects collected when white and black colored traps are used together. This study sought to verify the attractiveness of the traps to the phlebotomine species of the Brazilian Amazon basin using Shannon traps under these conditions. The insects were collected using two Shannon traps installed side by side, one white and the other black, in a primary forest area of the municipality of Xapuri, Acre, Brazil. Samples were collected once a month during the period August 2013 to July 2015. A sample of females was dissected to test for natural infection by flagellates. A total of 6,309 (864 males and 5,445 females) specimens (36 species) were collected. Psychodopygus carrerai carrerai (42%), Nyssomyia shawi (36%), and Psychodopygus davisi (13%), together represented 90% of the insects collected. Nyssomyia shawi and Psychodopygus davisi were more attracted by the white color. Specimens of Nyssomyia shawi, Nyssomyia whitmani, and Psychodopygus hirsutus hirsutus were found naturally infected by flagellates in the mid and hindgut. This is the first study in Acre state using and comparing both black and white Shannon traps, demonstrating the richness, diversity, and anthropophilic behavior of the phlebotomine species and identifying proven and putative vectors of the etiological agents of leishmaniasis. PMID:28593838
Seroprevalence of Toxoplasma gondii antibodies in cats and pigs from rural Western Amazon, Brazil.
Cavalcante, G T; Aguiar, D M; Chiebao, D; Dubey, J P; Ruiz, V L A; Dias, R A; Camargo, L M A; Labruna, M B; Gennari, S M
2006-08-01
Antibodies to Toxoplasma gondii were assayed in sera of 63 cats and 80 pigs from 71 farms located at Rondônia State, Western Amazon, Brazil, by the modified agglutination test (MAT) and the indirect immunofluorescent antibody test (IFAT). Antibodies (MAT > or = 1: 25) were found in 55 of 63 cats (87.3%) with titers of 1:25 in 2, 1:50 in 2, 1:100 in 7, 1:200 in 1, 1:400 in 2, 1:800 in 9, 1:1,600 in 6, and 1:3,200 or higher in 26 cats. By IFAT, antibodies were found in 55 cats (87.3%) with titers of 1:25 in 2, 1:50 in 1, 1:100 in 4, 1:200 in 4, 1: 400 in 1, 1:800 in 13, 1:1,600 in 12, and 1:3,200 or higher in 18 cats. In pig sera, by MAT, antibodies were found in 30 of 80 pigs (37.5%) with titers of 1:25 in 2, 1:50 in 3, 1:100 in 2, 1:200 in 8, 1:400 in 3, 1:800 in 5, 1:1,600 in 3, and 1:3,200 or higher in 4 pigs. By using the IFAT (titers > or = 1:64), antibodies were found in 35 (43.7%) pigs. The ingestion of undercooked tissues of infected pigs can be a source of T. gondii infection for humans and cats. However, the high seroprevalence of T. gondii in cats from the Amazon seems most likely to be indicative of high contamination of the environment by oocysts.
Arsenic, manganese and aluminum contamination in groundwater resources of Western Amazonia (Peru).
de Meyer, Caroline M C; Rodríguez, Juan M; Carpio, Edward A; García, Pilar A; Stengel, Caroline; Berg, Michael
2017-12-31
This paper presents a first integrated survey on the occurrence and distribution of geogenic contaminants in groundwater resources of Western Amazonia in Peru. An increasing number of groundwater wells have been constructed for drinking water purposes in the last decades; however, the chemical quality of the groundwater resources in the Amazon region is poorly studied. We collected groundwater from the regions of Iquitos and Pucallpa to analyze the hydrochemical characteristics, including trace elements. The source aquifer of each well was determined by interpretation of the available geological information, which identified four different aquifer types with distinct hydrochemical properties. The majority of the wells in two of the aquifer types tap groundwater enriched in aluminum, arsenic, or manganese at levels harmful to human health. Holocene alluvial aquifers along the main Amazon tributaries with anoxic, near pH-neutral groundwater contained high concentrations of arsenic (up to 700μg/L) and manganese (up to 4mg/L). Around Iquitos, the acidic groundwater (4.2≤pH≤5.5) from unconfined aquifers composed of pure sand had dissolved aluminum concentrations of up to 3.3mg/L. Groundwater from older or deeper aquifers generally was of good chemical quality. The high concentrations of toxic elements highlight the urgent need to assess the groundwater quality throughout Western Amazonia. Copyright © 2017 Elsevier B.V. All rights reserved.
Morphology and composition of gold in a lateritic profile, Fazenda Pison “Garimpo”, Amazon, Brazil
NASA Astrophysics Data System (ADS)
Larizzatti, J. H.; Oliveira, S. M. B.; Butt, C. R. M.
2008-05-01
This study describes the morphological evolution of gold grains in a lateritic weathering profile in an equatorial rainforest climate. Primary sources of gold are quartz veins associated with shallow granophyric intrusion. Gold grains were found in fresh ore, saprolite, transition zones, ferruginous duricrust, red latosol, and yellow latosol. Irregularly shaped grains predominate, with smaller proportions of dendritic and prismatic forms. Gold grains are weathered in the uppermost 10 m of the regolith. Mean gold grain size is maximum in the duricrust (>125 μm) and decreases progressively upward into the yellow latosol (<90 μm). Voids and corrosion pits appear on grain surfaces, and progressive rounding is observed from the bottom of the profile to the top. Gold grains can be classified as either homogeneous or zoned with respect to their chemical composition. Homogeneous grains contain 2-15% Ag (mean 8.3%). Zoned grains have more variable Ag contents; grain cores have means of approximately 10% or 23% Ag, with Ag-poor zones of approximately 3.7% Ag along internal discontinuities and/or outer rims. Formation of Ag-poor rims is due to preferential depletion of silver. Processes responsible for duricrust formation may preserve some grains as large aggregates, but subsequent transformation into latosol further modifies them.
Vulnerability of Amazon forests to storm-driven tree mortality
NASA Astrophysics Data System (ADS)
Negrón-Juárez, Robinson I.; Holm, Jennifer A.; Magnabosco Marra, Daniel; Rifai, Sami W.; Riley, William J.; Chambers, Jeffrey Q.; Koven, Charles D.; Knox, Ryan G.; McGroddy, Megan E.; Di Vittorio, Alan V.; Urquiza-Muñoz, Jose; Tello-Espinoza, Rodil; Alegria Muñoz, Waldemar; Ribeiro, Gabriel H. P. M.; Higuchi, Niro
2018-05-01
Tree mortality is a key driver of forest community composition and carbon dynamics. Strong winds associated with severe convective storms are dominant natural drivers of tree mortality in the Amazon. Why forests vary with respect to their vulnerability to wind events and how the predicted increase in storm events might affect forest ecosystems within the Amazon are not well understood. We found that windthrows are common in the Amazon region extending from northwest (Peru, Colombia, Venezuela, and west Brazil) to central Brazil, with the highest occurrence of windthrows in the northwest Amazon. More frequent winds, produced by more frequent severe convective systems, in combination with well-known processes that limit the anchoring of trees in the soil, help to explain the higher vulnerability of the northwest Amazon forests to winds. Projected increases in the frequency and intensity of convective storms in the Amazon have the potential to increase wind-related tree mortality. A forest demographic model calibrated for the northwestern and the central Amazon showed that northwestern forests are more resilient to increased wind-related tree mortality than forests in the central Amazon. Our study emphasizes the importance of including wind-related tree mortality in model simulations for reliable predictions of the future of tropical forests and their effects on the Earth’ system.
NASA Astrophysics Data System (ADS)
Tang, Wenfu; Arellano, Avelino. F.; Raman, Aishwarya
2015-04-01
Tropical forest fires significantly impact atmospheric composition and regional and global climate. In particular, fires in Equatorial Southern Africa (ESA) and Amazon comprise the two largest contributors to fire emissions of chemically and radiatively-active atmospheric constituents (such as CO, BC, CO2) across the globe. Here, we investigate the spatiotemporal trends in fire characteristics between these regions using combustion signatures observed from space. Our main goals are: 1) To identify key relationships between the trends in co-emitted constituents across these regions, and, 2) To explore linkages of the observed trends in fire characteristics with the main drivers of change such as meteorology, fire practice, development patterns, and ecosystem feedbacks. We take advantage of the similarity in latitude and land area between these regions in understanding some of these drivers. Our approach begins with a multi-species analysis of trends in the observed abundance of CO, NO2, and aerosols over these regions and across the time period 2004 to 2014. We use multi-spectral retrievals of CO from Measurements Of Pollution In The Troposphere (MOPITT), tropospheric column retrievals of NO2 from Ozone Monitoring Instrument (OMI), and aerosol optical depth retrievals from Moderate Resolution Imaging Spectroradiometer (MODIS) instrument. The long records from these retrievals provide a unique opportunity to study atmospheric composition across the most recent decade. While several studies in the past have reported trends over these regions, most of these studies have focused on a particular constituent. A unique aspect of this work involves understanding covariations in co-emitted constituents to provide a more comprehensive look at fire characteristics and behavior, which are yet to be fully understood. Our initial results show that the annual average of CO for ESA (~115 ppbv) is greater than that of Amazon (110 ppbv). This pattern is also seen in NO2 (ESA : ~215 pptv ; Amazon : ~155 pptv). The standard deviation of CO is higher in Amazon (50 ppbv) when compared to ESA (35 ppbv) whereas NO2 shows similar standard deviation in Amazon and ESA (70-90 pptv). We also find changes in the timing patterns of the large fire events across these regions. Since this has important implications to changes in fire behavior (smoldering and flaming phase), we also investigated retrievals of fire radiative power (FRP) from MODIS and information on land cover change and deforestation. We find FRP patterns consistent with our results. Finally, we will explore other measurements available during this period (aircraft field campaigns and in-situ observations) and compare with current fire emission models, such as the Global Fire Emission Database (GFED) to test the robustness of our findings. We note that this exploratory work provides a unique perspective of fire characteristics that will be useful to improve predictive capability of fire emission and atmospheric models for the Amazon and ESA.
NASA Astrophysics Data System (ADS)
Ringeval, B.; Houweling, S.; van Bodegom, P. M.; Spahni, R.; van Beek, R.; Joos, F.; Röckmann, T.
2014-03-01
Tropical wetlands are estimated to represent about 50% of the natural wetland methane (CH4) emissions and explain a large fraction of the observed CH4 variability on timescales ranging from glacial-interglacial cycles to the currently observed year-to-year variability. Despite their importance, however, tropical wetlands are poorly represented in global models aiming to predict global CH4 emissions. This publication documents a first step in the development of a process-based model of CH4 emissions from tropical floodplains for global applications. For this purpose, the LPX-Bern Dynamic Global Vegetation Model (LPX hereafter) was slightly modified to represent floodplain hydrology, vegetation and associated CH4 emissions. The extent of tropical floodplains was prescribed using output from the spatially explicit hydrology model PCR-GLOBWB. We introduced new plant functional types (PFTs) that explicitly represent floodplain vegetation. The PFT parameterizations were evaluated against available remote-sensing data sets (GLC2000 land cover and MODIS Net Primary Productivity). Simulated CH4 flux densities were evaluated against field observations and regional flux inventories. Simulated CH4 emissions at Amazon Basin scale were compared to model simulations performed in the WETCHIMP intercomparison project. We found that LPX reproduces the average magnitude of observed net CH4 flux densities for the Amazon Basin. However, the model does not reproduce the variability between sites or between years within a site. Unfortunately, site information is too limited to attest or disprove some model features. At the Amazon Basin scale, our results underline the large uncertainty in the magnitude of wetland CH4 emissions. Sensitivity analyses gave insights into the main drivers of floodplain CH4 emission and their associated uncertainties. In particular, uncertainties in floodplain extent (i.e., difference between GLC2000 and PCR-GLOBWB output) modulate the simulated emissions by a factor of about 2. Our best estimates, using PCR-GLOBWB in combination with GLC2000, lead to simulated Amazon-integrated emissions of 44.4 ± 4.8 Tg yr-1. Additionally, the LPX emissions are highly sensitive to vegetation distribution. Two simulations with the same mean PFT cover, but different spatial distributions of grasslands within the basin, modulated emissions by about 20%. Correcting the LPX-simulated NPP using MODIS reduces the Amazon emissions by 11.3%. Finally, due to an intrinsic limitation of LPX to account for seasonality in floodplain extent, the model failed to reproduce the full dynamics in CH4 emissions but we proposed solutions to this issue. The interannual variability (IAV) of the emissions increases by 90% if the IAV in floodplain extent is accounted for, but still remains lower than in most of the WETCHIMP models. While our model includes more mechanisms specific to tropical floodplains, we were unable to reduce the uncertainty in the magnitude of wetland CH4 emissions of the Amazon Basin. Our results helped identify and prioritize directions towards more accurate estimates of tropical CH4 emissions, and they stress the need for more research to constrain floodplain CH4 emissions and their temporal variability, even before including other fundamental mechanisms such as floating macrophytes or lateral water fluxes.
USDA-ARS?s Scientific Manuscript database
Cacao (Theobroma cacao L.) is indigenous to the Amazon region of South America. The Peruvian Amazon harbors a large number of diverse cacao populations. Since the 1930s, several numbers of populations have been collected from the Peruvian Amazon and maintained as ex situ germplasm repositories in ...
DOE Office of Scientific and Technical Information (OSTI.GOV)
Yoon, Jin -Ho
Amazon rainfall is subject to year-to-year fluctuation resulting in drought and flood in various intensities. A major climatic driver of the interannual variation of the Amazon rainfall is El Niño/Southern Oscillation. Also, the Sea Surface Temperature over the Atlantic Ocean is identified as an important climatic driver on the Amazon water cycle. Previously, observational datasets were used to support the Atlantic influence on Amazon rainfall. Furthermore, it is found that multiple global climate models do reproduce the Atlantic-Amazon link robustly. However, there exist differences in rainfall response, which primarily depends on the climatological rainfall amount.
Reconstruction of the Amazon Basin effective moisture availability over the past 14,000 years.
Maslin, M A; Burns, S J
2000-12-22
Quantifying the moisture history of the Amazon Basin is essential for understanding the cause of rain forest diversity and its potential as a methane source. We reconstructed the Amazon River outflow history for the past 14,000 years to provide a moisture budget for the river drainage basin. The oxygen isotopic composition of planktonic foraminifera recovered from a marine sediment core in a region of Amazon River discharge shows that the Amazon Basin was extremely dry during the Younger Dryas, with the discharge reduced by at least 40% as compared with that of today. After the Younger Dryas, a meltwater-driven discharge event was followed by a steady increase in the Amazon Basin effective moisture throughout the Holocene.
Trace gas exchanges and transports over the Amazonian rain forest
NASA Technical Reports Server (NTRS)
Garstang, Michael; Greco, Steve; Scala, John; Harriss, Robert; Browell, Edward; Sachse, Glenn; Simpson, Joanne; Tao, Wei-Kuo; Torres, Arnold
1986-01-01
Early results are presented from a program to model deep convective transport of chemical species by means of in situ data collection and numerical models. Data were acquired during the NASA GTE Amazon Boundary Layer Experiment in July-August 1985. Airborne instrumentation, including a UV-DIAL system, collected data on the O3, CO, NO, temperature and water vapor profiles from the surface to 400 mb altitude, while GOES imagery tracked convective clouds over the study area. A two-dimensional cloud model with small amplitude random temperature fluctuations at low levels, which simulated thermals, was used to describe the movements of the chemical species sensed in the convective atmosphere. The data was useful for evaluating the accuracy of the cloud model, which in turn was effective in describing the circulation of the chemical species.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Pöhlker, Mira L.; Pöhlker, Christopher; Ditas, Florian
Size-resolved long-term measurements of atmospheric aerosol and cloud condensation nuclei (CCN) concentrations and hygroscopicity were conducted at the remote Amazon Tall Tower Observatory (ATTO) in the central Amazon Basin over a 1-year period and full seasonal cycle (March 2014–February 2015). Our measurements provide a climatology of CCN properties characteristic of a remote central Amazonian rain forest site.The CCN measurements were continuously cycled through 10 levels of supersaturation ( S=0.11 to 1.10 %) and span the aerosol particle size range from 20 to 245 nm. The mean critical diameters of CCN activation range from 43 nm at S = 1.10 % to 172more » nm at S = 0.11 %. Furthermore, the particle hygroscopicity exhibits a pronounced size dependence with lower values for the Aitken mode ( κ Ait = 0.14 ± 0.03), higher values for the accumulation mode ( κ Acc = 0.22 ± 0.05), and an overall mean value of κ mean = 0.17 ± 0.06, consistent with high fractions of organic aerosol.The hygroscopicity parameter, κ, exhibits remarkably little temporal variability: no pronounced diurnal cycles, only weak seasonal trends, and few short-term variations during long-range transport events. In contrast, the CCN number concentrations exhibit a pronounced seasonal cycle, tracking the pollution-related seasonality in total aerosol concentration. Here, we find that the variability in the CCN concentrations in the central Amazon is mostly driven by aerosol particle number concentration and size distribution, while variations in aerosol hygroscopicity and chemical composition matter only during a few episodes.For modeling purposes, we compare different approaches of predicting CCN number concentration and present a novel parametrization, which allows accurate CCN predictions based on a small set of input data.« less
Pöhlker, Mira L.; Pöhlker, Christopher; Ditas, Florian; ...
2016-12-20
Size-resolved long-term measurements of atmospheric aerosol and cloud condensation nuclei (CCN) concentrations and hygroscopicity were conducted at the remote Amazon Tall Tower Observatory (ATTO) in the central Amazon Basin over a 1-year period and full seasonal cycle (March 2014–February 2015). Our measurements provide a climatology of CCN properties characteristic of a remote central Amazonian rain forest site.The CCN measurements were continuously cycled through 10 levels of supersaturation ( S=0.11 to 1.10 %) and span the aerosol particle size range from 20 to 245 nm. The mean critical diameters of CCN activation range from 43 nm at S = 1.10 % to 172more » nm at S = 0.11 %. Furthermore, the particle hygroscopicity exhibits a pronounced size dependence with lower values for the Aitken mode ( κ Ait = 0.14 ± 0.03), higher values for the accumulation mode ( κ Acc = 0.22 ± 0.05), and an overall mean value of κ mean = 0.17 ± 0.06, consistent with high fractions of organic aerosol.The hygroscopicity parameter, κ, exhibits remarkably little temporal variability: no pronounced diurnal cycles, only weak seasonal trends, and few short-term variations during long-range transport events. In contrast, the CCN number concentrations exhibit a pronounced seasonal cycle, tracking the pollution-related seasonality in total aerosol concentration. Here, we find that the variability in the CCN concentrations in the central Amazon is mostly driven by aerosol particle number concentration and size distribution, while variations in aerosol hygroscopicity and chemical composition matter only during a few episodes.For modeling purposes, we compare different approaches of predicting CCN number concentration and present a novel parametrization, which allows accurate CCN predictions based on a small set of input data.« less
Biogenic nonmethane hydrocarbon emissions estimated from tethered balloon observations
NASA Technical Reports Server (NTRS)
Davis, K. J.; Lenschow, D. H.; Zimmerman, P. R.
1994-01-01
A new technique for estimating surface fluxes of trace gases, the mixed-layer gradient technique, is used to calculate isoprene and terpene emissions from forests. The technique is applied to tethered balloon measurements made over the Amazon forest and a pine-oak forest in Alabama at altitudes up to 300 m. The observations were made during the dry season Amazon Boundary Layer Experiment (ABLE 2A) and the Rural Oxidants in the Southern Environment 1990 experiment (ROSE I). Results from large eddy simulations of scalar transport in the clear convective boundary layer are used to infer fluxes from the balloon profiles. Profiles from the Amazon give a mean daytime emission of 3630 +/- 1400 micrograms isoprene sq m/h, where the uncertainty represents the standard deviation of the mean of eight flux estimates. Twenty profiles from Alabama give emissions of 4470 +/- 3300 micrograms isoprene sq m/h, 1740 +/- 1060 micrograms alpha-pinene sq m/h, and 790 +/- 560 micrograms beta-pinene sq m/h, respectively. These results are in agreement with emissions derived from chemical budgets. The emissions may be overestimated because of uncertainty about how to incorporate the effects of the canopy on the mixed-layer gradients. The large variability in these emission estimates is probably due to the relatively short sampling times of the balloon profiles, though spatially heterogeneous emissions may also play a role. Fluxes derived using this technique are representative of an upwind footprint of several kilometers and are independent of hydrocarbon oxidation rate and mean advection.
NASA Astrophysics Data System (ADS)
Ribeiro, A. I.; Mello, G. F.; Longo, R. M.; Fengler, F. H.; Peche Filho, A., Sr.
2017-12-01
One of the greatest natural riches of Brazil is the Amazon rainforest. The Amazon region is known for its abundance of mineral resources, and may include topaz, oil, and especially cassiterite. In this scope, the mining sector in Brazil has great strategic importance because it accounts for approximately 30% of the country's exports with a mineral production of 40 billion dollars (Brazilian Mining Institute, 2015). In this scenario, as a consequence of mining, the Amazonian ecosystem has been undergoing a constant process of degradation. An important artifice in the exploitation of mineral resources is the rehabilitation and/or recovery of degraded areas. This recovery requires the establishment of degradation indicators and also the quality of the soil associated with its biota, since the Amazonian environment is dynamic, heterogeneous and complex in its physical, chemical and biological characteristics. In this way, this work presupposes that it is possible to characterize the different stages of recovery of tillage floor areas in deactivated cassiterite mines, within the Amazonian forest, in order to evaluate the interactions between the level of biological activity (Serrapilheira Height, Coefficient Metabolic, Basal Breath) and physical soil characteristics (aggregate DMG, Porosity, Total Soil Density, Moisture Content), through canonical correlation analysis. The results present correlations between the groups of indicators. Thus, from the use of the groups defined by canonical correlations, it was possible to identify the response of the set of physical and biological variables to the areas at different stages of recovery.
The Amazon Region; A Vision of Sovereignty
1998-04-06
and SPOT remote sensing satellites images, about 90% of the Amazon jungle remains almost untouched9. This 280 million hectares of vegetation hold...increasing energy needs, remain unanswered. Indian rights Has the Indian population been jeopardized by the development of the Amazon Region...or government agency. STRATEGY RESEARCH PROJECT THE AMAZON REGION; A VISION OF SOVEREIGNTY BY LIEUTENANT COLONEL EDUARDO JOSE BARBOSA
Self-amplified Amazon forest loss due to vegetation-atmosphere feedbacks.
Zemp, Delphine Clara; Schleussner, Carl-Friedrich; Barbosa, Henrique M J; Hirota, Marina; Montade, Vincent; Sampaio, Gilvan; Staal, Arie; Wang-Erlandsson, Lan; Rammig, Anja
2017-03-13
Reduced rainfall increases the risk of forest dieback, while in return forest loss might intensify regional droughts. The consequences of this vegetation-atmosphere feedback for the stability of the Amazon forest are still unclear. Here we show that the risk of self-amplified Amazon forest loss increases nonlinearly with dry-season intensification. We apply a novel complex-network approach, in which Amazon forest patches are linked by observation-based atmospheric water fluxes. Our results suggest that the risk of self-amplified forest loss is reduced with increasing heterogeneity in the response of forest patches to reduced rainfall. Under dry-season Amazonian rainfall reductions, comparable to Last Glacial Maximum conditions, additional forest loss due to self-amplified effects occurs in 10-13% of the Amazon basin. Although our findings do not indicate that the projected rainfall changes for the end of the twenty-first century will lead to complete Amazon dieback, they suggest that frequent extreme drought events have the potential to destabilize large parts of the Amazon forest.
Self-amplified Amazon forest loss due to vegetation-atmosphere feedbacks
NASA Astrophysics Data System (ADS)
Zemp, Delphine Clara; Schleussner, Carl-Friedrich; Barbosa, Henrique M. J.; Hirota, Marina; Montade, Vincent; Sampaio, Gilvan; Staal, Arie; Wang-Erlandsson, Lan; Rammig, Anja
2017-03-01
Reduced rainfall increases the risk of forest dieback, while in return forest loss might intensify regional droughts. The consequences of this vegetation-atmosphere feedback for the stability of the Amazon forest are still unclear. Here we show that the risk of self-amplified Amazon forest loss increases nonlinearly with dry-season intensification. We apply a novel complex-network approach, in which Amazon forest patches are linked by observation-based atmospheric water fluxes. Our results suggest that the risk of self-amplified forest loss is reduced with increasing heterogeneity in the response of forest patches to reduced rainfall. Under dry-season Amazonian rainfall reductions, comparable to Last Glacial Maximum conditions, additional forest loss due to self-amplified effects occurs in 10-13% of the Amazon basin. Although our findings do not indicate that the projected rainfall changes for the end of the twenty-first century will lead to complete Amazon dieback, they suggest that frequent extreme drought events have the potential to destabilize large parts of the Amazon forest.
Fragmentation of Andes-to-Amazon connectivity by hydropower dams
Anderson, Elizabeth P.; Jenkins, Clinton N.; Heilpern, Sebastian; Maldonado-Ocampo, Javier A.; Carvajal-Vallejos, Fernando M.; Encalada, Andrea C.; Rivadeneira, Juan Francisco; Hidalgo, Max; Cañas, Carlos M.; Ortega, Hernan; Salcedo, Norma; Maldonado, Mabel; Tedesco, Pablo A.
2018-01-01
Andes-to-Amazon river connectivity controls numerous natural and human systems in the greater Amazon. However, it is being rapidly altered by a wave of new hydropower development, the impacts of which have been previously underestimated. We document 142 dams existing or under construction and 160 proposed dams for rivers draining the Andean headwaters of the Amazon. Existing dams have fragmented the tributary networks of six of eight major Andean Amazon river basins. Proposed dams could result in significant losses in river connectivity in river mainstems of five of eight major systems—the Napo, Marañón, Ucayali, Beni, and Mamoré. With a newly reported 671 freshwater fish species inhabiting the Andean headwaters of the Amazon (>500 m), dams threaten previously unrecognized biodiversity, particularly among endemic and migratory species. Because Andean rivers contribute most of the sediment in the mainstem Amazon, losses in river connectivity translate to drastic alteration of river channel and floodplain geomorphology and associated ecosystem services. PMID:29399629
Fragmentation of Andes-to-Amazon connectivity by hydropower dams.
Anderson, Elizabeth P; Jenkins, Clinton N; Heilpern, Sebastian; Maldonado-Ocampo, Javier A; Carvajal-Vallejos, Fernando M; Encalada, Andrea C; Rivadeneira, Juan Francisco; Hidalgo, Max; Cañas, Carlos M; Ortega, Hernan; Salcedo, Norma; Maldonado, Mabel; Tedesco, Pablo A
2018-01-01
Andes-to-Amazon river connectivity controls numerous natural and human systems in the greater Amazon. However, it is being rapidly altered by a wave of new hydropower development, the impacts of which have been previously underestimated. We document 142 dams existing or under construction and 160 proposed dams for rivers draining the Andean headwaters of the Amazon. Existing dams have fragmented the tributary networks of six of eight major Andean Amazon river basins. Proposed dams could result in significant losses in river connectivity in river mainstems of five of eight major systems-the Napo, Marañón, Ucayali, Beni, and Mamoré. With a newly reported 671 freshwater fish species inhabiting the Andean headwaters of the Amazon (>500 m), dams threaten previously unrecognized biodiversity, particularly among endemic and migratory species. Because Andean rivers contribute most of the sediment in the mainstem Amazon, losses in river connectivity translate to drastic alteration of river channel and floodplain geomorphology and associated ecosystem services.
Self-amplified Amazon forest loss due to vegetation-atmosphere feedbacks
Zemp, Delphine Clara; Schleussner, Carl-Friedrich; Barbosa, Henrique M. J.; Hirota, Marina; Montade, Vincent; Sampaio, Gilvan; Staal, Arie; Wang-Erlandsson, Lan; Rammig, Anja
2017-01-01
Reduced rainfall increases the risk of forest dieback, while in return forest loss might intensify regional droughts. The consequences of this vegetation–atmosphere feedback for the stability of the Amazon forest are still unclear. Here we show that the risk of self-amplified Amazon forest loss increases nonlinearly with dry-season intensification. We apply a novel complex-network approach, in which Amazon forest patches are linked by observation-based atmospheric water fluxes. Our results suggest that the risk of self-amplified forest loss is reduced with increasing heterogeneity in the response of forest patches to reduced rainfall. Under dry-season Amazonian rainfall reductions, comparable to Last Glacial Maximum conditions, additional forest loss due to self-amplified effects occurs in 10–13% of the Amazon basin. Although our findings do not indicate that the projected rainfall changes for the end of the twenty-first century will lead to complete Amazon dieback, they suggest that frequent extreme drought events have the potential to destabilize large parts of the Amazon forest. PMID:28287104
2015-07-01
sharing, the Pathosphere.org open-system architecture is now deployed and available on the Amazon cloud . The site has over 100 users from...SUPPLEMENTARY NOTES 14. ABSTRACT: To generate accurate and actionable disease data that can be integrated into the broader Department of Defense...PREFACE The work described in this report was authorized under the Joint United States Forces Korea Portal and Integrated Threat Recognition
NASA Astrophysics Data System (ADS)
Sun, Shuwen; Schefuß, Enno; Mulitza, Stefan; Chiessi, Cristiano M.; Sawakuchi, André O.; Zabel, Matthias; Baker, Paul A.; Hefter, Jens; Mollenhauer, Gesine
2017-05-01
The Amazon River transports large amounts of terrestrial organic carbon (OCterr) from the Andean and Amazon neotropical forests to the Atlantic Ocean. In order to compare the biogeochemical characteristics of OCterr in the fluvial sediments from the Amazon drainage basin and in the adjacent marine sediments, we analysed riverbed sediments from the Amazon mainstream and its main tributaries as well as marine surface sediments from the Amazon shelf and fan for total organic carbon (TOC) content, organic carbon isotopic composition (δ13CTOC), and lignin phenol compositions. TOC and lignin content exhibit positive correlations with Al / Si ratios (indicative of the sediment grain size) implying that the grain size of sediment discharged by the Amazon River plays an important role in the preservation of TOC and leads to preferential preservation of lignin phenols in fine particles. Depleted δ13CTOC values (-26.1 to -29.9 ‰) in the main tributaries consistently correspond with the dominance of C3 vegetation. Ratios of syringyl to vanillyl (S / V) and cinnamyl to vanillyl (C / V) lignin phenols suggest that non-woody angiosperm tissues are the dominant source of lignin in the Amazon basin. Although the Amazon basin hosts a rich diversity of vascular plant types, distinct regional lignin compositions are not observed. In the marine sediments, the distribution of δ13CTOC and Λ8 (sum of eight lignin phenols in organic carbon (OC), expressed as mg/100 mg OC) values implies that OCterr discharged by the Amazon River is transported north-westward by the North Brazil Current and mostly deposited on the inner shelf. The lignin compositions in offshore sediments under the influence of the Amazon plume are consistent with the riverbed samples suggesting that processing of OCterr during offshore transport does not change the encoded source information. Therefore, the lignin compositions preserved in these offshore sediments can reliably reflect the vegetation in the Amazon River catchment. In sediments from the Amazon fan, low lignin content, relatively depleted δ13CTOC values and high (Ad / Al)V ratios indicating highly degraded lignin imply that a significant fraction of the deposited OCterr is derived from petrogenic (sourced from ancient rocks) sources.
Soriano, Marlene; Mohren, Frits; Ascarrunz, Nataly; Dressler, Wolfram; Peña-Claros, Marielos
2017-01-01
The Bolivian Amazon holds a complex configuration of people and forested landscapes in which communities hold secure tenure rights over a rich ecosystem offering a range of livelihood income opportunities. A large share of this income is derived from Amazon nut (Bertholletia excelsa). Many communities also have long-standing experience with community timber management plans. However, livelihood needs and desires for better living conditions may continue to place these resources under considerable stress as income needs and opportunities intensify and diversify. We aim to identify the socioeconomic and biophysical factors determining the income from forests, husbandry, off-farm and two keystone forest products (i.e., Amazon nut and timber) in the Bolivian Amazon region. We used structural equation modelling tools to account for the complex inter-relationships between socioeconomic and biophysical factors in predicting each source of income. The potential exists to increase incomes from existing livelihood activities in ways that reduce dependency upon forest resources. For example, changes in off-farm income sources can act to increase or decrease forest incomes. Market accessibility, social, financial, and natural and physical assets determined the amount of income community households could derive from Amazon nut and timber. Factors related to community households' local ecological knowledge, such as the number of non-timber forest products harvested and the number of management practices applied to enhance Amazon nut production, defined the amount of income these households could derive from Amazon nut and timber, respectively. The (inter) relationships found among socioeconomic and biophysical factors over income shed light on ways to improve forest-dependent livelihoods in the Bolivian Amazon. We believe that our analysis could be applicable to other contexts throughout the tropics as well.
Ribeiro, Igor Oliveira; Andreoli, Rita Valéria; Kayano, Mary Toshie; de Sousa, Thaiane Rodrigues; Medeiros, Adan Sady; Guimarães, Patrícia Costa; Barbosa, Cybelli G G; Godoi, Ricardo H M; Martin, Scot T; de Souza, Rodrigo Augusto Ferreira
2018-05-15
The present study examines the spatiotemporal variability and interrelations of the atmospheric methane (CH 4 ), carbon monoxide (CO) and biomass burning (BB) outbreaks retrieved from satellite data over the Amazon region during the 2003-2012 period. In the climatological context, we found consistent seasonal cycles of BB outbreaks and CO in the Amazon, both variables showing a peak during the dry season. The dominant CO variability mode features the largest positive loadings in the southern Amazon, and describes the interannual CO variations related to BB outbreaks along the deforestation arc during the dry season. In line with CO variability and BB outbreaks, the results show strong correspondence with the spatiotemporal variability of CH 4 in the southern Amazon during years of intense drought. Indeed, the areas with the largest positive CH 4 anomalies in southern Amazon overlap the areas with high BB outbreaks and positive CO anomalies. The analyses also showed that high (low) BB outbreaks in the southern Amazon occur during dry (wet) years. In consequence, the interannual climate variability modulates the BB outbreaks in the southern Amazon, which in turn have considerable impacts on CO and CH 4 interannual variability in the region. Therefore, the BB outbreaks might play a major role in modulating the CH 4 and CO variations, at least in the southern Amazon. This study also provides a comparison between the estimate of satellite and aircraft measurements for the CH 4 over the southern Amazon, which indicates relatively small differences from the aircraft measurements in the lower troposphere, with errors ranging from 0.18% to 1.76%. Copyright © 2017 Elsevier B.V. All rights reserved.
Buss de Souza, Ronald; Freire, Juan; Isaac, Victoria Judith
2016-01-01
This paper aims to describe the spatial-temporal variability in catch of the main fishery resources of the Amazon River and floodplain lakes of the Lower Amazon, as well as relating the Catch per Unit of Effort with anomalies of some of the Amazon River, atmosphere and Atlantic Ocean system variables, determining the influence of the environment on the Amazonian fishery resources. Finfish landings data from the towns and villages of the Lower Amazon for the fisheries of three sites (Óbidos, Santarém and Monte Alegre), were obtained for the period between January 1993 and December 2004. Analysis of variance, detrended correspondence analysis, redundancy analysis and multiple regression techniques were used for the statistical analysis of the distinct time series. Fisheries production in the Lower Amazon presents differences between the Amazon River and the floodplain lakes. Production in the Amazon River is approximately half of the one of the floodplain lakes. This variability occurs both along the Lower Amazon River region (longitudinal gradient) and laterally (latitudinal gradient) for every fishing ground studied here. The distinct environmental variables alone or in association act differently on the fishery stocks and the success of catches in each fishery group studied here. Important variables are the flooding events; the soil the sea surface temperatures; the humidity; the wind and the occurence of El Niño-Southern Oscillation events. Fishery productivity presents a large difference in quantity and distribution patterns between the river and floodplain lakes. This variability occurs in the region of the Lower Amazon as well as laterally for each fishery group studied, being dependent on the ecological characteristics and life strategies of each fish group considered here. PMID:27314951
Mohren, Frits; Ascarrunz, Nataly; Dressler, Wolfram; Peña-Claros, Marielos
2017-01-01
The Bolivian Amazon holds a complex configuration of people and forested landscapes in which communities hold secure tenure rights over a rich ecosystem offering a range of livelihood income opportunities. A large share of this income is derived from Amazon nut (Bertholletia excelsa). Many communities also have long-standing experience with community timber management plans. However, livelihood needs and desires for better living conditions may continue to place these resources under considerable stress as income needs and opportunities intensify and diversify. We aim to identify the socioeconomic and biophysical factors determining the income from forests, husbandry, off-farm and two keystone forest products (i.e., Amazon nut and timber) in the Bolivian Amazon region. We used structural equation modelling tools to account for the complex inter-relationships between socioeconomic and biophysical factors in predicting each source of income. The potential exists to increase incomes from existing livelihood activities in ways that reduce dependency upon forest resources. For example, changes in off-farm income sources can act to increase or decrease forest incomes. Market accessibility, social, financial, and natural and physical assets determined the amount of income community households could derive from Amazon nut and timber. Factors related to community households’ local ecological knowledge, such as the number of non-timber forest products harvested and the number of management practices applied to enhance Amazon nut production, defined the amount of income these households could derive from Amazon nut and timber, respectively. The (inter) relationships found among socioeconomic and biophysical factors over income shed light on ways to improve forest-dependent livelihoods in the Bolivian Amazon. We believe that our analysis could be applicable to other contexts throughout the tropics as well. PMID:28235090
East of the Andes: The genetic profile of the Peruvian Amazon populations.
Di Corcia, T; Sanchez Mellado, C; Davila Francia, T J; Ferri, G; Sarno, S; Luiselli, D; Rickards, O
2017-06-01
Assuming that the differences between the Andes and the Amazon rainforest at environmental and historical levels have influenced the distribution patterns of genes, languages, and cultures, the maternal and paternal genetic reconstruction of the Peruvian Amazon populations was used to test the relationships within and between these two extreme environments. We analyzed four Peruvian Amazon communities (Ashaninka, Huambisa, Cashibo, and Shipibo) for both Y chromosome (17 STRs and 8 SNPs) and mtDNA data (control region sequences, two diagnostic sites of the coding region, and one INDEL), and we studied their variability against the rest of South America. We detected a high degree of genetic diversity in the Peruvian Amazon people, both for mtDNA than for Y chromosome, excepting for Cashibo people, who seem to have had no exchanges with their neighbors, in contrast with the others communities. The genetic structure follows the divide between the Andes and the Amazon, but we found a certain degree of gene flow between these two environments, as particularly emerged with the Y chromosome descent cluster's (DCs) analysis. The Peruvian Amazon is home to an array of populations with differential rates of genetic exchanges with their neighbors and with the Andean people, depending on their peculiar demographic histories. We highlighted some successful Y chromosome lineages expansions originated in Peru during the pre-Columbian history which involved both Andeans and Amazon Arawak people, showing that at least a part of the Amazon rainforest did not remain isolated from those exchanges. © 2017 Wiley Periodicals, Inc.
Amazon Forest Responses to Drought and Fire
NASA Astrophysics Data System (ADS)
Morton, D. C.
2015-12-01
Deforestation and agricultural land uses provide a consistent source of ignitions along the Amazon frontier during the dry season. The risk of understory fires in Amazon forests is amplified by drought conditions, when fires at the forest edge may spread for weeks before rains begin. Fire activity also impacts the regional response of intact forests to drought through diffuse light effects and nutrient redistribution, highlighting the complexity of feedbacks in this coupled human and natural system. This talk will focus on recent advances in our understanding of fire-climate feedbacks in the Amazon, building on research themes initiated under NASA's Large-scale Biosphere-Atmosphere Experiment in Amazonia (LBA). NASA's LBA program began in the wake of the 1997-1998 El Niño, a strong event that exposed the vulnerability of Amazon forests to drought and fire under current climate and projections of climate change. With forecasts of another strong El Niño event in 2015-2016, this talk will provide a multi-scale synthesis of Amazon forest responses to drought and fire based on field measurements, airborne lidar data, and satellite observations of fires, rainfall, and terrestrial water storage. These studies offer new insights into the mechanisms governing fire season severity in the southern Amazon and regional variability in carbon losses from understory fires. The contributions from remote sensing to our understanding of drought and fire in Amazon forests reflect the legacy of NASA's LBA program and the sustained commitment to interdisciplinary research across the Amazon region.
Limited effect of anthropogenic nitrogen oxides on secondary organic aerosol formation
Zheng, Y.; Unger, N.; Hodzic, A.; ...
2015-12-08
Globally, secondary organic aerosol (SOA) is mostly formed from emissions of biogenic volatile organic compounds (VOCs) by vegetation, but it can be modified by human activities as demonstrated in recent research. Specifically, nitrogen oxides (NO x = NO + NO 2) have been shown to play a critical role in the chemical formation of low volatility compounds. We have updated the SOA scheme in the global NCAR (National Center for Atmospheric Research) Community Atmospheric Model version 4 with chemistry (CAM4-chem) by implementing a 4-product volatility basis set (VBS) scheme, including NO x-dependent SOA yields and aging parameterizations. Small differences aremore » found for the no-aging VBS and 2-product schemes; large increases in SOA production and the SOA-to-OA ratio are found for the aging scheme. The predicted organic aerosol amounts capture both the magnitude and distribution of US surface annual mean measurements from the Interagency Monitoring of Protected Visual Environments (IMPROVE) network by 50 %, and the simulated vertical profiles are within a factor of 2 compared to aerosol mass spectrometer (AMS) measurements from 13 aircraft-based field campaigns across different regions and seasons. We then perform sensitivity experiments to examine how the SOA loading responds to a 50 % reduction in anthropogenic nitric oxide (NO) emissions in different regions. We find limited SOA reductions of 0.9–5.6, 6.4–12.0 and 0.9–2.8 % for global, southeast US and Amazon NO x perturbations, respectively. The fact that SOA formation is almost unaffected by changes in NO x can be largely attributed to a limited shift in chemical regime, to buffering in chemical pathways (low- and high-NO x pathways, O 3 versus NO 3-initiated oxidation) and to offsetting tendencies in the biogenic versus anthropogenic SOA responses.« less
NASA Astrophysics Data System (ADS)
Ringeval, B.; Houweling, S.; van Bodegom, P. M.; Spahni, R.; van Beek, R.; Joos, F.; Röckmann, T.
2013-10-01
Tropical wetlands are estimated to represent about 50% of the natural wetland emissions and explain a large fraction of the observed CH4 variability on time scales ranging from glacial-interglacial cycles to the currently observed year-to-year variability. Despite their importance, however, tropical wetlands are poorly represented in global models aiming to predict global CH4 emissions. This study documents the first regional-scale, process-based model of CH4 emissions from tropical floodplains. The LPX-Bern Dynamic Global Vegetation Model (LPX hereafter) was modified to represent floodplain hydrology, vegetation and associated CH4 emissions. The extent of tropical floodplains was prescribed using output from the spatially-explicit hydrology model PCR-GLOBWB. We introduced new Plant Functional Types (PFTs) that explicitly represent floodplain vegetation. The PFT parameterizations were evaluated against available remote sensing datasets (GLC2000 land cover and MODIS Net Primary Productivity). Simulated CH4 flux densities were evaluated against field observations and regional flux inventories. Simulated CH4 emissions at Amazon Basin scale were compared to model simulations performed in the WETCHIMP intercomparison project. We found that LPX simulated CH4 flux densities are in reasonable agreement with observations at the field scale but with a~tendency to overestimate the flux observed at specific sites. In addition, the model did not reproduce between-site variations or between-year variations within a site. Unfortunately, site informations are too limited to attest or disprove some model features. At the Amazon Basin scale, our results underline the large uncertainty in the magnitude of wetland CH4 emissions. In particular, uncertainties in floodplain extent (i.e., difference between GLC2000 and PCR-GLOBWB output) modulate the simulated emissions by a factor of about 2. Our best estimates, using PCR-GLOBWB in combination with GLC2000, lead to simulated Amazon-integrated emissions of 44.4 ± 4.8 Tg yr-1. Additionally, the LPX emissions are highly sensitive to vegetation distribution. Two simulations with the same mean PFT cover, but different spatial distributions of grasslands within the basin modulated emissions by about 20%. Correcting the LPX simulated NPP using MODIS reduces the Amazon emissions by 11.3%. Finally, due to an intrinsic limitation of LPX to account for seasonality in floodplain extent, the model failed to reproduce the seasonality in CH4 emissions. The Inter Annual Variability (IAV) of the emissions increases by 90% if the IAV in floodplain extent is account for, but still remains lower than in most of WETCHIMP models. While our model includes more mechanisms specific to tropical floodplains, we were unable to reduce the uncertainty in the magnitude of wetland CH4 emissions of the Amazon Basin. Our results stress the need for more research to constrain floodplain CH4 emissions and their temporal variability.
Modern Environmental Changes on Amapa Coastal Plain under Amazon River Influence
NASA Astrophysics Data System (ADS)
Santos, V. F.; Figueiredo, A. G.; Silveira, O. M.; Polidori, L.
2007-05-01
The Amazonian coastal environment is very dynamic compared to other coasts. It is situated at the edge of the Earth's largest forest, and is segmented by fluvial systems, with the biggest being the Amazon River. The rivers are particularly influenced by the Intertropical Convergence Zone (ITCZ), which controls the water and particle discharge, and the flooding regime. Moderate and strong El Nino conditions correlate with low-precipitation periods, and La Nina events cause precipitation to increase. These variables and others related to the Amazon dispersal system create an interesting area for the study of global and regional environmental changes. The Araguari River floodplain on the Amapa coast is influenced by natural processes of global scale such as ENSO events and ITCZ, and by local processes such as Amazon River discharge, tides and tidal bore (pororoca). Anthropogenic processes such as extensive water-buffalo farming also promote environmental changes. Time- series analyses of remote sensing images and suspended sediment have shown that the maximum turbidity zone inside Araguari River is related to the pororoca phenomenon. The pororoca remobilizes sediment from the river bottom and margins, developing sediment suspension >15 g/l as it passes - creating fluid muds. The pororoca also introduces Amazon- and shelf-derived sediment into the Araguari estuary. Measurements during eight spring-tide cycles indicate erosion of 3 cm of consolidated mud and deposition of 1 cm. The pororoca also influences the remobilization and cycling of nutrients and consequently affects the distribution of benthic organisms, including benthonic foraminifera and thecamoebians. For more than a century, the coastal plain has had water-buffalo farming (>42,000 animals today), which modifies the drainage system and affects sedimentary processes. Areas with more buffalo trails have higher suspended-sediment concentration (SSC) during the dry season and lower SSC during the rainy season. This relationship is reversed in drainages without the influence of the herd. The development of small channels, one meter deep by one meter wide, induced by the buffalos can evolve into a large drainage network in a short period of time. The Santana Creek started as a buffalo trail and in three decades it evolved into a network with a main channel 200 m wide and 6 km long. Despite the Amazon River having the largest influence in the region, the Araguari River also has a considerable water discharge of 2.4x103 m3/s and particulate discharge of 7x105 tons/y, and is able to impose changes to the Amapa coastal environments and inner shelf. The natural closure of the Araguari north arm during middle of the 19th century has induced the development of a wide coastal plain in the Cape Norte region, and decreased fresh water to the Carapaporis channel. On the other hand, deforestation for farm development and buffalo farming has influenced the hydrologic regime, sediment and nutrient balance.
Plasmodium malariae in the Colombian Amazon region: you don't diagnose what you don't suspect.
Niño, Carlos Hernando; Cubides, Juan Ricardo; Camargo-Ayala, Paola Andrea; Rodríguez-Celis, Carlos Arturo; Quiñones, Teódulo; Cortés-Castillo, Moisés Tomás; Sánchez-Suárez, Lizeth; Sánchez, Ricardo; Patarroyo, Manuel Elkin; Patarroyo, Manuel Alfonso
2016-11-29
Malaria is a worldwide public health problem; parasites from the genus Plasmodium spp. are the aetiological agent of this disease. The parasite is mainly diagnosed by microscope-based techniques. However, these have limited sensitivity. Many asymptomatic infections are sub-microscopic and can only be detected by molecular methods. This study was aimed at comparing nested PCR results to those obtained by microscope for diagnosing malaria and to present epidemiological data regarding malaria in Colombia's Amazon department. A total of 1392 blood samples (taken by venepuncture) from symptomatic patients in Colombia's Amazon department were analysed in parallel by thick blood smear (TBS) test and nested PCR for determining Plasmodium spp. infection and identifying infecting species, such as Plasmodium vivax, Plasmodium malariae and/or Plasmodium falciparum. Descriptive statistics were used for comparing the results from both tests regarding detection of the disease, typing infecting species and their prevalence in the study region. Bearing the microscope assay in mind as gold standard, PCR diagnosis performance was evaluated by statistical indicators. The present study revealed great differences between both diagnostic tests, as well as suggesting high P. malariae prevalence from a molecular perspective. This differed profoundly from previous studies in this region of Colombia, usually based on the TBS test, suggesting that diagnosis by conventional techniques could lead to underestimating the prevalence of certain Plasmodium spp. having high circulation in this area. The present results highlight the need for modifying state malaria surveillance schemes for more efficient strategies regarding the detection of this disease in endemic areas. The importance of PCR as a back-up test in cases of low parasitaemia or mixed infection is also highlighted.
Assessing the impact of Amazonia logging with a new ecosystem model
NASA Astrophysics Data System (ADS)
Huang, M.; Asner, G. P.; Keller, M.; Berry, J. A.; Bustamante, M. M.
2006-12-01
Old-growth Amazonian forests play a fundamental role in the global climate and carbon cycle. Land use in old- growth tropical forests contributes to the accumulation of CO2 in the atmosphere and can alter the hydrological cycle, locally, regionally, and globally. Although deforestation, largely for the conversion of land to food crops or pastures, is the major destructive force in tropical forests worldwide (Houghton et al., 2000), other forest disturbances such as the selective logging have also increased in frequency and extent. Selective logging causes widespread collateral damage to remaining trees, sub-canopy vegetation, and soils, with impacts on hydrological processes, erosion, fire, carbon storage, and plant and animal species. In this study, the impact of selective logging on the carbon budget of the Brazil Amazon region is assessed with a new 3-D version of the Carnegie-Ames-Stanford Approach (CASA) ecosystem model, which features: (1) an alternative way of estimating absorbed photosynthetically-active radiation (APAR) by taking advantage of new high-resolution maps of forest canopy gap fraction; (2) a pulse disturbance module to realistically modify the carbon pools after timber harvest; (3) a regrowth module considering changes in community composition; and (4) a radiative transfer module for charactering the dynamic 3-D light environment above the canopy and within gaps after logging. The model was calibrated and validated with field observations from the Large-scale Biosphere Atmosphere Experiment (LBA) and its sensitivity was evaluated with Monte Carlo simulations. The impacts of selected logging on regional carbon budget of the Brazilian Amazon were then assessed under different future climate change scenarios. Results from this study quantify the gross and net carbon storage effects of widespread logging practices throughout the Brazilian Amazon.
NASA Astrophysics Data System (ADS)
dos Santos, F. C.; Longo, K.; Guenther, A. B.; Freitas, S. R.; Moreira, D. S.; Flávio, L.; Braz, R.; Oram, D.; Lee, J. D.; Bauguitte, S.
2016-12-01
Emitted by vegetation, isoprene (2-methyl-1,3-butadiene) is the most abundant non-methane hydrocarbons, with an annual global emission calculated ranging from 440 to 660Tg carbon, depending on the driving variables like temperature, solar radiation, leaf area index and plant functional type. It is estimated, for example, that the natural compounds like isoprene and terpenes present in the troposphere are about 90% and 50%, respectively, removed from the atmosphere by oxidation performed by hydroxyl radical (OH). Furthermore, the oxidation products of isoprene may contribute to secondary organic aerosol (SOA) formation, affecting the climate and altering the properties and lifetimes of clouds. Considering the importance of these emissions and the hydroxyl radical reaction in the atmosphere, the SAMBBA (South American Biomass Burning Analysis) experiment, which occurred during the dry season (September 2012) in the Amazon Rainforest, provided information about the chemical composition of the atmosphere through airborne observations. Although primarily focused on biomass burning flights, the SAMBBA project carried out other flights providing indirect oxidative capacity data in different environments: natural emission dominated flights and biomass-burning flights with fresh plumes and aged plumes. In this study, we evaluate the oxidative capacity of the Amazon rainforest in different environments, both for the unpolluted and biomass-burning disturbed atmosphere using the ratio [MVK + MACR]/[Isoprene]. Beyond that, we propose an improvement on the formulation of indirect OH density calculation, using the photochemical aging [O3]/[CO] as a parameter. During the day (11am-8pm - local time), the [OH] values for natural emission flights (8.1 x 106 molecules/cm3) and biomass-burning (9.4 x 106 molecules/cm3) are comparable with GABRIEL-2015 field campaign along Guyanas tropical rainforest and suggest that biomass-burning increase the oxidative capacity around 18% in average (altitude < 2000 meters). This study aims to improve the knowledge about the oxidative capacity of the atmosphere and a synergistic approach integrating observation and modeling, using 3D numerical model of chemical transport (CCATT-BRAMS) coupled with a natural emission model (MEGAN) has been applied.
Security of the Brazilian Amazon Area
1992-04-01
effect in Amazonia". Brazil’s Institute for Space Research. Sio Paulo, April 1991: 5-6. Thompson, Dick. "A Global Agenda for the Amazon." Time, 18...to be overcome as Brazil pursues settlement and development of the Amazon. The natural ecologic systems of the Amazon must be defended with...agricultural techniques appropriate to the region and developed within the context of a comprehensive, responsible program that meets Brazil’s needs for
DOE Office of Scientific and Technical Information (OSTI.GOV)
Giangrande, Scott E.; Feng, Zhe; Jensen, Michael P.
Routine cloud, precipitation and thermodynamic observations collected by the Atmospheric Radiation Measurement (ARM) Mobile Facility (AMF) and Aerial Facility (AAF) during the 2-year US Department of Energy (DOE) ARM Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5) campaign are summarized. These observations quantify the diurnal to large-scale thermodynamic regime controls on the clouds and precipitation over the undersampled, climatically important Amazon basin region. The extended ground deployment of cloud-profiling instrumentation enabled a unique look at multiple cloud regimes at high temporal and vertical resolution. This longer-term ground deployment, coupled with two short-term aircraft intensive observing periods, allowed new opportunitiesmore » to better characterize cloud and thermodynamic observational constraints as well as cloud radiative impacts for modeling efforts within typical Amazon wet and dry seasons.« less
An explicit GIS-based river basin framework for aquatic ecosystem conservation in the Amazon
NASA Astrophysics Data System (ADS)
Venticinque, Eduardo; Forsberg, Bruce; Barthem, Ronaldo; Petry, Paulo; Hess, Laura; Mercado, Armando; Cañas, Carlos; Montoya, Mariana; Durigan, Carlos; Goulding, Michael
2016-11-01
Despite large-scale infrastructure development, deforestation, mining and petroleum exploration in the Amazon Basin, relatively little attention has been paid to the management scale required for the protection of wetlands, fisheries and other aspects of aquatic ecosystems. This is due, in part, to the enormous size, multinational composition and interconnected nature of the Amazon River system, as well as to the absence of an adequate spatial model for integrating data across the entire Amazon Basin. In this data article we present a spatially uniform multi-scale GIS framework that was developed especially for the analysis, management and monitoring of various aspects of aquatic systems in the Amazon Basin. The Amazon GIS-Based River Basin Framework is accessible as an ESRI geodatabase at doi:10.5063/F1BG2KX8.
Deforestation effects on Amazon forest resilience
NASA Astrophysics Data System (ADS)
Zemp, D. C.; Schleussner, C.-F.; Barbosa, H. M. J.; Rammig, A.
2017-06-01
Through vegetation-atmosphere feedbacks, rainfall reductions as a result of Amazon deforestation could reduce the resilience on the remaining forest to perturbations and potentially lead to large-scale Amazon forest loss. We track observation-based water fluxes from sources (evapotranspiration) to sinks (rainfall) to assess the effect of deforestation on continental rainfall. By studying 21st century deforestation scenarios, we show that deforestation can reduce dry season rainfall by up to 20% far from the deforested area, namely, over the western Amazon basin and the La Plata basin. As a consequence, forest resilience is systematically eroded in the southwestern region covering a quarter of the current Amazon forest. Our findings suggest that the climatological effects of deforestation can lead to permanent forest loss in this region. We identify hot spot regions where forest loss should be avoided to maintain the ecological integrity of the Amazon forest.
Giangrande, Scott E.; Feng, Zhe; Jensen, Michael P.; ...
2017-12-06
Routine cloud, precipitation and thermodynamic observations collected by the Atmospheric Radiation Measurement (ARM) Mobile Facility (AMF) and Aerial Facility (AAF) during the 2-year US Department of Energy (DOE) ARM Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5) campaign are summarized. These observations quantify the diurnal to large-scale thermodynamic regime controls on the clouds and precipitation over the undersampled, climatically important Amazon basin region. The extended ground deployment of cloud-profiling instrumentation enabled a unique look at multiple cloud regimes at high temporal and vertical resolution. This longer-term ground deployment, coupled with two short-term aircraft intensive observing periods, allowed new opportunitiesmore » to better characterize cloud and thermodynamic observational constraints as well as cloud radiative impacts for modeling efforts within typical Amazon wet and dry seasons.« less
Simioni, Síntia Carla Corrêa; Tovar, Diego Mercado; Rodrigues, Jéssica Ferreira; de Souza, Vanessa Rios; Nunes, Cleiton Antônio; Vietoris, Vladimir; Pinheiro, Ana Carla Marques
2018-02-01
Brazilians and Slovakians evaluated the temporal profile and the acceptability of cachaça stored with different woods (Cumarurana (CM), Jatobá (JT) and, Louro-vermelho (LV), which are found in the Amazon rainforest, and also oak), with the aim of performing a cross-cultural comparison of the dynamic profile of the attributes perceived in the cachaças and the sensorial acceptance of the samples. Important differences were observed between the temporal sensorial profiles generated by the two groups and their preferences. Brazilians preferred cachaças stored with the traditional wood, oak, followed by those stored with JT and CM. In contrast, Slovakians preferred cachaças stored with JT, followed by those stored with LV and oak. For both countries, the dominance of wood flavor and vanilla attributes at the end of the analysis time was positively associated with acceptance, while the dominance of off-flavors and the wood flavor attribute at the beginning of the analysis time was negatively associated with acceptance for Brazilians and Slovakians, respectively. Brazilians preferred cachaça stored with oak wood, and Slovakians preferred cachaça stored with JT wood, with acceptability being strongly associated with the dominance of wood flavor and vanilla attributes at the end of the evaluation time. © 2018 Society of Chemical Industry. © 2018 Society of Chemical Industry.
NASA Astrophysics Data System (ADS)
Holanda, Bruna; Pöhlker, Mira; Klimach, Thomas; Saturno, Jorge; Ditas, Florian; Ditas, Jeannine; Ma, Nan; Zhang, Yuxuan; Cheng, Yafang; Wendisch, Manfred; Machado, Luiz; Barbosa, Henrique; Pöhlker, Christopher; Artaxo, Paulo; Pöschl, Ulrich; Andreae, Meinrat
2017-04-01
Black carbon (BC) particles are emitted directly into the atmosphere by processes of incomplete combustion and therefore can be used as a tracer of atmospheric pollution. BC is considered one of the drivers of global warming due to its efficient absorption of solar and infra-red radiation (Bond et al., 2013). Depending on abundance and size, aerosols can also modify the characteristics of clouds and enhance or suppress precipitation (Pöschl et al., 2010). The BC particles can gain surface coatings by condensation of low and semi-volatile compounds, coagulation, and cloud processing. The inclusion of a non-absorbing coating influences the way that BC particles act as cloud nuclei and may increase their absorption through the lensing effect (Fuller et al., 1999). These aging processes change significantly the optical, chemical and physical properties of the particles, as well as their atmospheric lifetime, making BC a source of large uncertainties in current atmospheric models. Taking into account the complex dynamics of BC particles in the atmosphere, we are analyzing data from the ACRIDICON-CHUVA aircraft campaign, which took place in the Amazon basin, Brazil, during the dry season of 2014 (Wendisch et al., 2016). A detailed characterization of BC particles was done using the Single Particle Soot Photometer (SP2) instrument, which directly measures the mass of individual refractory BC particles (rBC). Additionally, the SP2 provides information about the size distribution of rBC cores and their associated coatings. These properties were measured covering a wide geographic area with different pollution conditions and at several levels of the atmosphere at high time resolution. The rBC concentrations change significantly with altitude and with the source of pollution, being a few nanograms per cubic meter for altitudes higher that 5 km. In the surroundings of Manaus city, the mean BC concentration was 0.7 μg/m3, with core sizes peaking at 180 nm. The highest BC mass values were observed over fresh biomass burning plumes (6 μg/m3) with smaller core sizes ( 150 nm). Moreover, in a specific flight (AC19) we identified an extended layer of pollution at 4 km altitude. Backward trajectories calculated using FLEXPART suggest that this pollution layer originated in Africa and has aged few days during its travel over the Atlantic. Similarities in the properties of rBC particles within the pollution and boundary layers suggest that the long range transport of pollution from Africa can be an important source of BC to the Amazonian atmosphere. Here we present first results from our analyses that characterize the various pollution aerosols and their properties in the Amazon basin. References Bond, T.C. et al., 2013. Bounding the role of black carbon in the climate system: A scientific assessment. Journal of Geophysical Research: Atmospheres, 118(11), pp.5380-5552. Fuller, K. A. et al., 1999. Effects of mixing on extinction by carbonaceous particles. Journal of Geophysical Research: Atmospheres, 104(D13), 15941-15954. Pöschl, U. et al., 2010. Rainforest aerosols as biogenic nuclei of clouds and precipitation in the Amazon. Science 329, 1513. Wendisch, M. et al., 2016. The ACRIDICON-CHUVA campaign: Studying tropical deep convective clouds and precipitation over Amazonia using the new German research aircraft HALO. Bull. Amer. Meteor. Soc.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Godoi, R. H.M.; Barbosa, C. G.G.; Kurzlop, P.
Because of their proven adverse effects on human health and vegetation, and also considering their influence over the local and regional climate, inhalable fine particles (PM2.5) and NO 2, SO 2, and O 3 have been collected at the ARM site located in Manacapuru, Amazon, Brazil, as a part of the GoAmazon 2014/5 project. PM2.5 samples were analyzed through gravimetry, black carbon transmittance, elemental composition by energy dispersive x-ray fluorescence, and ionic concentration (cations) by ion chromatography. NO 2 and SO 2 samples were analyzed by ion chromatography, whereas O3 samples were analyzed through ultraviolet-vis spectrophotometry. Sampling of both particulatemore » and gaseous pollutants took place during the two intensive operation periods (IOP1 from February to March 2014, and IOP2 from August to October 2014). Results are interpreted both separately and as a whole with the specific goal of identifying compounds that could affect the population’s health and/or could act as cloud condensation nuclei. Chemical analysis supports the elucidation of the possible origins, transport mechanisms, health effects, and main effects of the assessed pollutants in those environments« less
NASA Astrophysics Data System (ADS)
Meador, Travis B.; Aluwihare, Lihini I.
2014-10-01
In North Atlantic waters impacted by discharges from the Amazon and Orinoco Rivers, where planktonic diatom-diazotroph associations (DDA) were active, we observed that an average (± standard deviation) of 61 ± 12% of the biological drawdown of dissolved inorganic carbon (DIC) was partitioned into the accumulating total organic carbon pool, representing a flux of up to 9 ± 4 Tg C yr-1. This drawdown corresponded with chemical alteration of ultrafiltered dissolved organic matter (UDOM), including increases in stable C isotopic composition (δ13C) and C:N. The dissolved carbohydrate component of UDOM also increased with biological DIC drawdown and diatom-associated diazotroph (i.e., Richelia) abundance. New carbohydrates could be distinguished by distinctively high relative abundances of deoxy sugars (up to 55% of monosaccharides), which may promote aggregate formation and enhance vertical carbon export. The identified production of non-Redfieldian, C-enriched UDOM thus suggests a mechanism to explain enhanced C sequestration associated with DDA N2 fixation, which may be widespread in mesohaline environments.
Federal Register 2010, 2011, 2012, 2013, 2014
2012-07-06
...''); Amazon.com , Inc. of Seattle, Washington (``Amazon''); Nokia Corporation of Espoo, Finland, Nokia Inc. of..., Motorola, Samsung, Sony, Amazon, and Pantech filed a joint motion under Commission Rule 210.21(a)(2) to...
Measuring Water Storage in the Amazon
2010-07-07
This image is from data taken by NASA Gravity Recovery and Climate Experiment showing the Amazon basin in South America. The amount of water stored in the Amazon basin varies from month to month. Animations are available at the Photojournal.
NASA Astrophysics Data System (ADS)
Fu, Rong; Dickinson, Robert E.; Chen, Mingxuan; Wang, Hui
2001-10-01
Although the correlation between precipitation over tropical South America and sea surface temperatures (SSTs) over the Pacific and Atlantic has been documented since the early twentieth century, the impact of each ocean on the timing and intensity of the wet season over tropical South America and the underlying mechanisms have remained unclear. Numerical experiments have been conducted using the National Center for Atmospheric Research Community Climate Model Version 3 to explore these impacts. The results suggest the following.1)Seasonality of SSTs in the tropical Pacific and Atlantic has an important influence on precipitation in the eastern Amazon during the equinox seasons. The eastern side of the Amazon is influenced both by the direct thermal circulation of the Atlantic intertropical convergence zone (ITCZ) and by Rossby waves. These processes are enhanced by the seasonal cycles of SSTs in the tropical Atlantic and Pacific. SSTs affect Amazon precipitation much less during the solstice seasons and in the western Amazon.2)The seasonality of SSTs in the Atlantic more strongly affects Amazon rainfall than does that of the Pacific. Without the former, austral spring in the eastern equatorial Amazon would be a wet season, rather than the observed dry season. As a consequence of the lag at that time of the southward seasonal migration of the Atlantic SSTs behind that of the insolation, the Atlantic ITCZ centers itself near 10°N, instead of at the equator, imposing subsidence and low-level anticyclonic flow over the eastern equatorial Amazon, thus drying the air above the planetary boundary layer and reducing the low-level moisture convergence. Consequently, convection in the eastern Amazon is suppressed despite strong surface heating.3)Seasonality of the SSTs in the tropical Pacific also tends to reduce precipitation in the eastern Amazon during both spring and fall. In spring, subsidence is enhanced not only through a zonal direct circulation, but also through Rossby waves propagating from the extratropical South Pacific to subtropical South America. This teleconnection strengthens the South Atlantic convergence zone (SACZ) and the Nordeste low, in both cases reducing precipitation in the eastern Amazon. A direct thermal response to the Pacific SSTs enhances lower-level divergence and reduces precipitation from the northern tropical Atlantic to the northeastern Amazon.
Chemically modified graphite for electrochemical cells
Greinke, R.A.; Lewis, I.C.
1998-05-26
This invention relates to chemically modified graphite particles: (a) that are useful in alkali metal-containing electrode of a electrochemical cell comprising: (1) the electrode, (2) a non-aqueous electrolytic solution comprising an organic aprotic solvent which solvent tends to decompose when the electrochemical cell is in use, and an electrically conductive salt of an alkali metal, and (3) a counter electrode; and (b) that are chemically modified with fluorine, chlorine, iodine or phosphorus to reduce such decomposition. This invention also relates to electrodes comprising such chemically modified graphite and a binder and to electrochemical cells containing such electrodes. 3 figs.
Chemically modified graphite for electrochemical cells
Greinke, Ronald Alfred; Lewis, Irwin Charles
1998-01-01
This invention relates to chemically modified graphite particles: (a) that are useful in alkali metal-containing electrode of a electrochemical cell comprising: (i) the electrode, (ii) a non-aqueous electrolytic solution comprising an organic aprotic solvent which solvent tends to decompose when the electrochemical cell is in use, and an electrically conductive salt of an alkali metal, and (iii) a counterelectrode; and (b) that are chemically modified with fluorine, chlorine, iodine or phosphorus to reduce such decomposition. This invention also relates to electrodes comprising such chemically modified graphite and a binder and to electrochemical cells containing such electrodes.
DoD Global Emerging Infections System Annual Report, Fiscal Year 2000
2000-01-01
partners in Peru , Bolivia, and Suriname and was conducted largely under the supervision of a CDC officer assigned to NMRCD. Surveillance in the Amazon ...pyrimethamine on the north coast of Peru . In the Amazon basin, resistance to both chloroquine and sulfadoxine-pyrimethamine is noted in the central Amazon ...the north coast and in the Amazon region, respectively.As a result of this work, Peru now has better and more up-to-date information on antimalarial
Living Rivers: Importance of Andes-Amazon Connectivity and Consequences of Hydropower Development
NASA Astrophysics Data System (ADS)
Anderson, E.
2016-12-01
The inherent dynamism of rivers along elevational and longitudinal gradients underpins freshwater biodiversity, ecosystem function, and ecosystem services in the Andean-Amazon. While this region covers only a small part of the entire Amazon Basin, its influences on downstream ecology, biogeochemistry, and human wellbeing are disproportionate with its relative small size. Seasonal flow pulses from Andean rivers maintain habitat, signal migratory fishes, and export sediment, nutrients, and organic matter to distant ecosystems—like lowland Amazonia and the Atlantic coast of Brazil. Rivers are key transportation routes, and freshwater fisheries are a primary protein source for the >30 million people that inhabit the Amazon Basin. Numerous cultural traditions depend on free-flowing Andean rivers; examples include Kukama beliefs in the underwater cities of the Marañon River, where people who have drowned in rivers whose bodies are not recovered go to live, or the pre-dawn bathing rituals of the Peruvian Shawi, who gain energy and connect with ancestors in cold, fast-flowing Andean waters. Transformations in the Andean-Amazon landscape—in particular from dams—threaten to compromise flows critical for human and ecosystem wellbeing. Presently, at least 250 hydropower dams are in operation, under construction, or proposed for Andean-Amazon rivers. This presentation will discuss regional trends in hydropower development, quantify effects of existing and proposed dams on Andean-Amazon connectivity, and examine the social and cultural importance of free-flowing Andean-Amazon rivers.
Composition and formation of organic aerosol particles in the Amazon
NASA Astrophysics Data System (ADS)
Pöhlker, C.; Wiedemann, K.; Sinha, B.; Shiraiwa, M.; Gunthe, S. S.; Artaxo, P.; Gilles, M. K.; Kilcoyne, A. L. D.; Moffet, R. C.; Smith, M.; Weigand, M.; Martin, S. T.; Pöschl, U.; Andreae, M. O.
2012-04-01
We applied scanning transmission X-ray microscopy with near edge X-ray absorption fine structure (STXM-NEXAFS) analysis to investigate the morphology and chemical composition of aerosol samples from a pristine tropical environment, the Amazon Basin. The samples were collected in the Amazonian rainforest during the rainy season and can be regarded as a natural background aerosol. The samples were found to be dominated by secondary organic aerosol (SOA) particles in the fine and primary biological aerosol particles (PBAP) in the coarse mode. Lab-generated SOA-samples from isoprene and terpene oxidation as well as pure organic compounds from spray-drying of aqueous solution were measured as reference samples. The aim of this study was to investigate the microphysical and chemical properties of a tropical background aerosol in the submicron size range and its internal mixing state. The lab-generated SOA and pure organic compounds occurred as spherical and mostly homogenous droplet-like particles, whereas the Amazonian SOA particles comprised a mixture of homogeneous droplets and droplets having internal structures due to atmospheric aging. In spite of the similar morphological appearance, the Amazon samples showed considerable differences in elemental and functional group composition. According to their NEXAFS spectra, three chemically distinct types of organic material were found and could be assigned to the following three categories: (1) particles with a pronounced carboxylic acid (COOH) peak similar to those of laboratory-generated SOA particles from terpene oxidation; (2) particles with a strong hydroxy (COH) signal similar to pure carbohydrate particles; and (3) particles with spectra resembling a mixture of the first two classes. In addition to the dominant organic component, the NEXAFS spectra revealed clearly resolved potassium (K) signals for all analyzed particles. During the rainy season and in the absence of anthropogenic influence, active biota is regarded to be the major potassium source. In addition a strong size dependence of the K mass fraction in the SOA particles has been found, with highest K content in small particles. We suggest that K-rich biogenic salts act as a template for condensational growth by low-volatility organic compounds from atmospheric isoprene and terpene oxidation. The presence of K-rich salts in SOA particles has been confirmed by scanning electron microscopy (SEM) and secondary ion mass spectrometry (nanoSIMS) techniques. Seeding of SOA particles by biogenic salts may explain the absence of new particle formation events in pristine boundary layer air over the Amazonian rainforest.
40 CFR 721.9513 - Modified magnesium silicate polymer (generic).
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Modified magnesium silicate polymer... Specific Chemical Substances § 721.9513 Modified magnesium silicate polymer (generic). (a) Chemical... as modified magnesium silicate polymer (PMN P-98-604) is subject to reporting under this section for...
40 CFR 721.9513 - Modified magnesium silicate polymer (generic).
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Modified magnesium silicate polymer... Specific Chemical Substances § 721.9513 Modified magnesium silicate polymer (generic). (a) Chemical... as modified magnesium silicate polymer (PMN P-98-604) is subject to reporting under this section for...
40 CFR 721.10504 - Surface modified magnesium hydroxide (generic).
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Surface modified magnesium hydroxide... Specific Chemical Substances § 721.10504 Surface modified magnesium hydroxide (generic). (a) Chemical... as surface modified magnesium hydroxide (PMN P-06-682) is subject to reporting under this section for...
40 CFR 721.10504 - Surface modified magnesium hydroxide (generic).
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Surface modified magnesium hydroxide... Specific Chemical Substances § 721.10504 Surface modified magnesium hydroxide (generic). (a) Chemical... as surface modified magnesium hydroxide (PMN P-06-682) is subject to reporting under this section for...
40 CFR 721.10119 - Siloxane modified silica nanoparticles (generic).
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Siloxane modified silica nanoparticles... Specific Chemical Substances § 721.10119 Siloxane modified silica nanoparticles (generic). (a) Chemical... as siloxane modified silica nanoparticles (PMN P-05-673) is subject to reporting under this section...
40 CFR 721.10119 - Siloxane modified silica nanoparticles (generic).
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Siloxane modified silica nanoparticles... Specific Chemical Substances § 721.10119 Siloxane modified silica nanoparticles (generic). (a) Chemical... as siloxane modified silica nanoparticles (PMN P-05-673) is subject to reporting under this section...
40 CFR 721.10119 - Siloxane modified silica nanoparticles (generic).
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Siloxane modified silica nanoparticles... Specific Chemical Substances § 721.10119 Siloxane modified silica nanoparticles (generic). (a) Chemical... as siloxane modified silica nanoparticles (PMN P-05-673) is subject to reporting under this section...
40 CFR 721.10119 - Siloxane modified silica nanoparticles (generic).
Code of Federal Regulations, 2012 CFR
2012-07-01
... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Siloxane modified silica nanoparticles... Specific Chemical Substances § 721.10119 Siloxane modified silica nanoparticles (generic). (a) Chemical... as siloxane modified silica nanoparticles (PMN P-05-673) is subject to reporting under this section...
40 CFR 721.10119 - Siloxane modified silica nanoparticles (generic).
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Siloxane modified silica nanoparticles... Specific Chemical Substances § 721.10119 Siloxane modified silica nanoparticles (generic). (a) Chemical... as siloxane modified silica nanoparticles (PMN P-05-673) is subject to reporting under this section...
40 CFR 721.9513 - Modified magnesium silicate polymer (generic).
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Modified magnesium silicate polymer... Specific Chemical Substances § 721.9513 Modified magnesium silicate polymer (generic). (a) Chemical... as modified magnesium silicate polymer (PMN P-98-604) is subject to reporting under this section for...
40 CFR 721.9513 - Modified magnesium silicate polymer (generic).
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Modified magnesium silicate polymer... Specific Chemical Substances § 721.9513 Modified magnesium silicate polymer (generic). (a) Chemical... as modified magnesium silicate polymer (PMN P-98-604) is subject to reporting under this section for...
40 CFR 721.9513 - Modified magnesium silicate polymer (generic).
Code of Federal Regulations, 2012 CFR
2012-07-01
... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Modified magnesium silicate polymer... Specific Chemical Substances § 721.9513 Modified magnesium silicate polymer (generic). (a) Chemical... as modified magnesium silicate polymer (PMN P-98-604) is subject to reporting under this section for...
40 CFR 721.5908 - Modified phenolic resin (generic).
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Modified phenolic resin (generic). 721... Substances § 721.5908 Modified phenolic resin (generic). (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as modified phenolic resin (PMN P...
40 CFR 721.5905 - Modified phenolic resin (generic).
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Modified phenolic resin (generic). 721... Substances § 721.5905 Modified phenolic resin (generic). (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as a modified phenolic resin (PMN...
[Adsorption of phenol chemicals by surfactant-modified zeolites].
Xie, Jie; Wang, Zhe; Wu, De-Yi; Li, Chun-Jie
2012-12-01
Two kinds of zeolites were prepared from fly ash and modified by surfactant subsequently. Surfactant-modified zeolites were studied for adsorption of phenol chemicals (phenol, p-chlorphenol, bisphenol A). It showed that the adsorption affinity of zeolite to phenol chemicals was significantly improved after surfactant modification. The adsorption isotherms of phenol chemicals were well fitted by the Langmuir isotherm. For the two surfactant-surfactant modified zeolites, the maximum adsorption amounts of phenol, p-chlorphenol, and bisphenol A calculated from the Langmuir equation were 37.7, 52.36, 90.9 mg x g(-1) and 10.7, 22.83, 56.8 mg x g(-1), respectively. When pH values of solutions were higher than the pK(a) values of phenol chemicals, the removal efficiencies were getting higher with the increase of pH values. The octanol/water partition coefficient (K(ow)) was also found to be an important factor affecting adsorption of phenol chemicals by the modified zeolites. Higher K(ow) value, which means the greater hydrophobicity of the chemicals, resulted in a higher removal.
40 CFR 721.2540 - Diphenylmethane diisocyanate (MDI) modified.
Code of Federal Regulations, 2010 CFR
2010-07-01
...) TOXIC SUBSTANCES CONTROL ACT SIGNIFICANT NEW USES OF CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.2540 Diphenylmethane diisocyanate (MDI) modified. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as a...
Patterns of Bacterial and Archaeal Gene Expression through the Lower Amazon River
DOE Office of Scientific and Technical Information (OSTI.GOV)
Satinsky, Brandon M.; Smith, Christa B.; Sharma, Shalabh
Analysis of metatranscriptomic and metagenomic datasets from the lower reaches of the Amazon River between Obidos and the river mouth revealed microbial transcript and gene pools dominated by Actinobacteria, Thaumarchaeota, Bacteroidetes, Acidobacteria, Betaproteobacteria, and Planctomycetes. Three mainstem stations spanning a 625 km reach had similar gene expression patterns (transcripts gene copy-1) across a diverse suite of element cycling genes, but two tributary-influenced stations at the mouth of the Tapajos River and near the Tocantins River at Belem had distinct transcriptome composition and expression ratios, particularly for genes encoding light-related energy capture (higher) and iron acquisition and ammonia oxidation (lower). Environmentalmore » parameters that were useful predictors of gene expression ratios included concentrations of lignin phenols, suspended sediments, nitrate, phosphate, and particulate organic carbon and nitrogen. Similar to the gene expression data, these chemical properties reflected highly homogeneous mainstem stations punctuated by distinct tributary- influenced stations at Tapajos and Belem. Although heterotrophic processes were expected to dominate in the lower Amazon, transcripts from photosynthetic bacteria were abundant in tributary-influenced regions, and transcripts from Thaumarcheota taxa genetically capable of chemosynthetic ammonia oxidation accounted for up to 21% of the transcriptome at others. Based on regressions of transcript numbers against gene numbers, expression ratios of Thaumarchaeota populations were largely unchanged within the mainstem, suggesting a relatively minor role for gene regulation. These quantitative gene and transcript inventories detail a diverse array of energy acquisition strategies and metabolic capabilities for bacteria and archaea populations of the world’s largest river system.« less
Vieira, Miguel; Bernardi, José V E; Dórea, José G; Rocha, Bruno C P; Ribeiro, Romulo; Zara, Luis F
2018-04-01
Waters from the Amazon Basin have distinct physicochemical characteristics that can be optically classified as "black", "clear" and "white". We studied the distribution of total-Hg (THg) and methyl-Hg (MeHg) in these waters and respective suspended solids, sediment, phytoplankton, zooplankton, and benthic macroinvertebrates (BM) in the Madeira River Basin. Compared with the other types of water, the more acidic "black" kind had the highest THg and MeHg concentrations. The trend (black > clear > white) occurred for the concentrations of THg and MeHg in sediments and in the biotic compartment (plankton, macroinvertebrates). Organic Hg accounted for a small percentage (0.6-0.4%) of the THg in sediments but was highest in water (17-15%). For plankton and BM, the biota sediment accumulation factor (BSAFs) of MeHg (53-125) were greater than those of THg (4.5-15); however, the BSAF trend according to water type (black > clear > white) was only significant for MeHg. Sediment THg is correlated with all forms of Hg in biotic and abiotic matrices. The results indicate that water acidity in the Amazon is an important chemical characteristic in assessing Hg contamination of sediments and bioaccumulation in the aquatic food web. The differences in the BSAFs between THg and MeHg support the use of this factor for evaluating the bioaccumulation potential of sediment-bound Hg. The results add information critical to assessing environmental and health risks related to Hg methylation and potential fish-MeHg contamination, especially in tropical aquatic environments. Copyright © 2018 Elsevier Ltd. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Liu, Yingjun; Brito, Joel; Dorris, Matthew R.
Isoprene photooxidation is a major driver of atmospheric chemistry over forested regions. Isoprene reacts with hydroxyl radicals (OH) and molecular oxygen to produce isoprene peroxy radicals (ISOPOO). These radicals can react with hydroperoxyl radicals (HO 2) to dominantly produce hydroxyhydroperoxides (ISOPOOH). They can also react with nitric oxide (NO) to largely produce methyl vinyl ketone (MVK) and methacrolein (MACR). Unimolecular isomerization and bimolecular reactions with organic peroxy radicals are also possible. There is uncertainty about the relative importance of each of these pathways in the atmosphere and possible changes because of anthropogenic pollution. Herein, measurements of ISOPOOH and MVK +more » MACR concentrations are reported over the central region of the Amazon basin during the wet season. The research site, downwind of an urban region, intercepted both background and polluted air masses during the GoAmazon2014/5 Experiment. Under background conditions, the confidence interval for the ratio of the ISOPOOH concentration to that of MVK + MACR spanned 0.4–0.6. This result implies a ratio of the reaction rate of ISOPOO with HO2 to that with NO of approximately unity. Also, a value of unity is significantly smaller than simulated at present by global chemical transport models for this important, nominally low-NO, forested region of Earth. Under polluted conditions, when the concentrations of reactive nitrogen compounds were high (>1 ppb), ISOPOOH concentrations dropped below the instrumental detection limit (<60 ppt). In conclusion, this abrupt shift in isoprene photooxidation, sparked by human activities, speaks to ongoing and possible future changes in the photochemistry active over the Amazon rainforest.« less
NASA Technical Reports Server (NTRS)
Morton, Douglas C.; Nagol, Jyoteshwar; Carabajal, Claudia C.; Rosette, Jacqueline; Palace, Michael; Cook, Bruce D.; Vermote, Eric F.; Harding, David J.; North, Peter R. J.
2016-01-01
Multiple mechanisms could lead to up-regulation of dry-season photosynthesis in Amazon forests, including canopy phenology and illumination geometry. We specifically tested two mechanisms for phenology-driven changes in Amazon forests during dry-season months, and the combined evidence from passive optical and lidar satellite data was incompatible with large net changes in canopy leaf area or leaf reflectance suggested by previous studies. We therefore hypothesized that seasonal changes in the fraction of sunlit and shaded canopies, one aspect of bidirectional reflectance effects in Moderate Resolution Imaging Spectroradiometer (MODIS) data, could alter light availability for dry-season photosynthesis and the photosynthetic capacity of Amazon forests without large net changes in canopy composition. Subsequent work supports the hypothesis that seasonal changes in illumination geometry and diffuse light regulate light saturation in Amazon forests. These studies clarify the physical mechanisms that govern light availability in Amazon forests from seasonal variability in direct and diffuse illumination. Previously, in the debate over light limitation of Amazon forest productivity, seasonal changes in the distribution of light within complex Amazon forest canopies were confounded with dry-season increases in total incoming photosynthetically active radiation. In the accompanying Comment, Saleska et al. do not fully account for this confounding effect of forest structure on photosynthetic capacity.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Goldstein, A. H.; Yee, L. D.; Issacman-VanWertz, G.
In areas where biogenic emissions are oxidized in the presence of anthropogenic pollutants such as SO2, NOx, and black carbon, it has become increasingly apparent that secondary organic aerosol (SOA) formation from biogenic volatile organic compounds (VOCs) is substantially enhanced. Research is urgently needed to elucidate fundamental processes of natural and anthropogenically influenced VOC oxidation and the contribution of these processes to SOA formation. GoAmazon 2014/15 afforded study of the chemical transformations in the region downwind of Manaus, Brazil, where local biogenic VOC emissions are high, and their chemical oxidation can be studied both inside and outside of the urbanmore » plume to differentiate the role of anthropogenic influence on secondary aerosol formation during oxidation of these natural VOC emissions. To understand the connection between primary biogenic VOC emissions and their secondary products that form aerosols, we made time-resolved molecular level measurements by deploying a Semi-Volatile Thermal Desorption Aerosol Gas Chromatograph (SV-TAG) and a sequential filter sampler during two intensive operational periods (IOPs) of the GoAmazon 2014/15 field campaign. The SV-TAG measured semi-volatile organic compounds in both the gas and particle phases and the sequential filter sampler collected aerosols on quartz fiber filters in four-hour increments used for offline analysis. SV-TAG employed novel online derivatization that provided chemical speciation of highly oxygenated or functionalized compounds that comprise a substantial fraction of secondary organic aerosols, yet are poorly characterized. It also provided partitioning of these compounds between the vapor and particle phases at sufficient time resolution to define the importance of competing atmospheric processes. These measurements were supported by offline analysis of the filters using two-dimensional gas chromatography (GC x GC) with high-resolution time-of-flight mass spectrometry (HR-TOF-MS) using both electron impact (EI) and soft vacuum ultraviolet (VUV) ionization with derivatization. Speciated chemical data from SV-TAG and filter measurements were used to elucidate the relative importance of potential oxidation pathways by providing detailed information on the product distribution from atmospheric reactions and the quantification of known tracers for various oxidation pathways. Together, these techniques provided unequivocal molecular identification of a wide range of atmospheric organic compounds spanning the volatile, semi-volatile, and non-volatile phases. This level of chemical characterization provided insight into the chemical and physical processes that control the atmospheric oxidation of biogenic VOC and subsequent formation of SOA.« less
40 CFR 721.3135 - Phosphorous modified epoxy resin (generic).
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Phosphorous modified epoxy resin... Specific Chemical Substances § 721.3135 Phosphorous modified epoxy resin (generic). (a) Chemical substance... phosphorous modified epoxy resin (PMNs P-00-992 and P-01-471) is subject to reporting under this section for...
40 CFR 721.3135 - Phosphorous modified epoxy resin (generic).
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Phosphorous modified epoxy resin... Specific Chemical Substances § 721.3135 Phosphorous modified epoxy resin (generic). (a) Chemical substance... phosphorous modified epoxy resin (PMNs P-00-992 and P-01-471) is subject to reporting under this section for...
40 CFR 721.3135 - Phosphorous modified epoxy resin (generic).
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Phosphorous modified epoxy resin... Specific Chemical Substances § 721.3135 Phosphorous modified epoxy resin (generic). (a) Chemical substance... phosphorous modified epoxy resin (PMNs P-00-992 and P-01-471) is subject to reporting under this section for...
40 CFR 721.3135 - Phosphorous modified epoxy resin (generic).
Code of Federal Regulations, 2012 CFR
2012-07-01
... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Phosphorous modified epoxy resin... Specific Chemical Substances § 721.3135 Phosphorous modified epoxy resin (generic). (a) Chemical substance... phosphorous modified epoxy resin (PMNs P-00-992 and P-01-471) is subject to reporting under this section for...
40 CFR 721.3135 - Phosphorous modified epoxy resin (generic).
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Phosphorous modified epoxy resin... Specific Chemical Substances § 721.3135 Phosphorous modified epoxy resin (generic). (a) Chemical substance... phosphorous modified epoxy resin (PMNs P-00-992 and P-01-471) is subject to reporting under this section for...
40 CFR 721.10082 - Amine modified monomer acrylate (generic).
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Amine modified monomer acrylate... Specific Chemical Substances § 721.10082 Amine modified monomer acrylate (generic). (a) Chemical substance... amine modified monomer acrylate (PMN P-06-29) is subject to reporting under this section for the...
40 CFR 721.10082 - Amine modified monomer acrylate (generic).
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Amine modified monomer acrylate... Specific Chemical Substances § 721.10082 Amine modified monomer acrylate (generic). (a) Chemical substance... amine modified monomer acrylate (PMN P-06-29) is subject to reporting under this section for the...
40 CFR 721.3710 - Polyether modified fatty acids (generic).
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Polyether modified fatty acids... Specific Chemical Substances § 721.3710 Polyether modified fatty acids (generic). (a) Chemical substance... Polyether modified fatty acids (PMN P-99-0435) is subject to reporting under this section for the...
40 CFR 721.10089 - Modified salicylic acid, zirconium complex (generic).
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Modified salicylic acid, zirconium... Specific Chemical Substances § 721.10089 Modified salicylic acid, zirconium complex (generic). (a) Chemical... as modified salicylic acid, zirconium complex (PMN P-00-552) is subject to reporting under this...
40 CFR 721.10089 - Modified salicylic acid, zirconium complex (generic).
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Modified salicylic acid, zirconium... Specific Chemical Substances § 721.10089 Modified salicylic acid, zirconium complex (generic). (a) Chemical... as modified salicylic acid, zirconium complex (PMN P-00-552) is subject to reporting under this...
40 CFR 721.4380 - Modified hydrocarbon resin.
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Modified hydrocarbon resin. 721.4380... Substances § 721.4380 Modified hydrocarbon resin. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as a modified hydrocarbon resin (P-91-1418) is...
40 CFR 721.3710 - Polyether modified fatty acids (generic).
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Polyether modified fatty acids... Specific Chemical Substances § 721.3710 Polyether modified fatty acids (generic). (a) Chemical substance... Polyether modified fatty acids (PMN P-99-0435) is subject to reporting under this section for the...
Mouths of the Amazon River, Brazil, South America
NASA Technical Reports Server (NTRS)
1992-01-01
In this view of the Amazon River Mouth (0.0, 51.0W), a large sediment plume can be seen expanding outward into the Atlantic Ocean. The sediment plume can be seen hugging the coast north of the delta as a result of the northwest flowing coastal Guyana Current. In recent years, the flow of the Amazon has become heavily laden with sediment as soil runoff from the denuded landscape of the interior enters the Amazon River (and other rivers) drainage system.
2010-01-01
MediCine and Hyg1cne Epidemiology of Spotted Fever Group and Typhus Group Rickettsial Infection in the Amazon Basin of Peru Brett M. Forshey, Allison...approximately 4% of acute febrile episodes detected in Iquitos, a city located in the Amazon region of northeast- ern Peru , could be attributed to SFGR...2010 to 00-00-2010 4. TITLE AND SUBTITLE Epidemiology Of Spotted Fever Group And Typhus Group Rickettsial Infection In The Amazon Basin Of Peru 5a
DoD Global Emerging Infections System Annual Report, Fiscal Year 1999
1999-01-01
findings provided the impetus to the government of Peru to change national drug policy regarding treatment of malaria in the Peruvian Amazon . As soon as...feasible, a 13 14 Malaria Emerges in the Amazon Basin of Peru (Department of Loreto) 1992-1997 During the last 10-15 years, malaria has emerged as a major...public health problem in the Amazon basin of South America. In Peru the total number of malaria cases reported annually from the Peruvian Amazon
Act No. 24994 of 19 January 1989. Basic Law on the Rural Development of the Peruvian Amazon Region.
1989-01-01
This Act sets forth the government's policy on rural development of the Peruvian Amazon region. Major objectives of the Act include the promotion of new rural settlements in the Amazon region, the promotion of migration from the Andes to the Amazon region, and the stimulation of agriculture, livestock, and forestry activities in the Amazon region. The following are the means that the government will use, among others, to attain these goals: 1) the development of Population Displacement Programmes, which will give individual persons and families economic and logistic support in moving; 2) the establishment of Civic Colonizing Services, temporary mobile units, which will offer settlers health services, education services, technical assistance with respect to agriculture and livestock, and promotional credits; 3) the creation of the Council for Amazon River Transport to coordinate and recommend activities to improve river transport; 4) the granting to settlers of land, free education for their children, medical care, technical training and assistance with respect to agriculture, and a supply of seeds; 5) the exemption of certain investors from payment of income taxes; and 6) the granting of a wide range of incentives for agricultural production. The Act also creates a Council for Planning and Development in the Amazon Region to draw up and approve a Plan for the Development of the Amazon Region. It calls for the rational use of the natural resources of the Amazon Region in the framework of preserving the ecosystem and preventing its ruin and delegates to the regional governments the authority to enter into contracts on the use of forest materials and to undertake reforestation programs. Finally, the Act provides various guarantees for the native population, including guarantees with respect to land and preservation of ethnic and social identity.
40 CFR 372.20 - Process for modifying covered chemicals and facilities.
Code of Federal Regulations, 2013 CFR
2013-07-01
... chemicals and facilities. 372.20 Section 372.20 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SUPERFUND, EMERGENCY PLANNING, AND COMMUNITY RIGHT-TO-KNOW PROGRAMS TOXIC CHEMICAL RELEASE REPORTING: COMMUNITY RIGHT-TO-KNOW Reporting Requirements § 372.20 Process for modifying covered chemicals...
NASA Astrophysics Data System (ADS)
Chen, Yang; Randerson, James T.; Morton, Douglas C.
2015-08-01
We describe a climate mode synchronizing forest carbon losses from North and South America by analyzing time series of tropical North Atlantic sea surface temperatures (SSTs), landfall hurricanes and tropical storms, and Amazon fires during 1995-2013. Years with anomalously high tropical North Atlantic SSTs during March-June were often followed by a more active hurricane season and a larger number of satellite-detected fires in the southern Amazon during June-November. The relationship between North Atlantic tropical cyclones and southern Amazon fires (r = 0.61, p < 0.003) was stronger than links between SSTs and either cyclones or fires alone, suggesting that fires and tropical cyclones were directly coupled to the same underlying atmospheric dynamics governing tropical moisture redistribution. These relationships help explain why seasonal outlook forecasts for hurricanes and Amazon fires both failed in 2013 and may enable the design of improved early warning systems for drought and fire in Amazon forests.
Biological resistance of polyethylene composites made with chemically modified fiber or flour
Rebecca E. Ibach; Craig M. Clemons
2002-01-01
The role of moisture in the biological decay of wood-plastic composites was investigated. Southern pine wood fiber and ponderosa pine wood flour were chemically modified using either acetic anhydride (AA), butylene oxide (BO), or propylene oxide (PO). A 50:50 mixture of high density polyethylene and either chemically modified fiber or flour, or untreated fiber or flour...
Artificial specific binders directly recovered from chemically modified nucleic acid libraries.
Kasahara, Yuuya; Kuwahara, Masayasu
2012-01-01
Specific binders comprised of nucleic acids, that is, RNA/DNA aptamers, are attractive functional biopolymers owing to their potential broad application in medicine, food hygiene, environmental analysis, and biological research. Despite the large number of reports on selection of natural DNA/RNA aptamers, there are not many examples of direct screening of chemically modified nucleic acid aptamers. This is because of (i) the inferior efficiency and accuracy of polymerase reactions involving transcription/reverse-transcription of modified nucleotides compared with those of natural nucleotides, (ii) technical difficulties and additional time and effort required when using modified nucleic acid libraries, and (iii) ambiguous efficacies of chemical modifications in binding properties until recently; in contrast, the effects of chemical modifications on biostability are well studied using various nucleotide analogs. Although reports on the direct screening of a modified nucleic acid library remain in the minority, chemical modifications would be essential when further functional expansion of nucleic acid aptamers, in particular for medical and biological uses, is considered. This paper focuses on enzymatic production of chemically modified nucleic acids and their application to random screenings. In addition, recent advances and possible future research are also described.
Feio, Claudine A; Izar, Maria C; Ihara, Silvia S; Kasmas, Soraia H; Martins, Celma M; Feio, Max N; Maués, Luís A; Borges, Ney C; Moreno, Ronilson A; Póvoa, Rui M; Fonseca, Francisco A
2012-01-01
Euterpe Oleracea (açai) is a fruit from the Amazon region whose chemical composition may be beneficial for individuals with atherosclerosis. We hypothesized that consumption of Euterpe Oleracea would reduce atherosclerosis development by decreasing cholesterol absorption and synthesis. Male New Zealand rabbits were fed a cholesterol-enriched diet (0.5%) for 12 weeks, when they were randomized to receive Euterpe Oleracea extract (n = 15) or water (n = 12) plus a 0.05% cholesterol-enriched diet for an additional 12 weeks. Plasma phytosterols and desmosterol were determined by ultra-performance liquid chromatography and mass spectrometry. Atherosclerotic lesions were estimated by computerized planimetry and histomorphometry. At sacrifice, animals treated with Euterpe Oleracea had lower levels of total cholesterol (p =0.03), non-HDL-cholesterol (p = 0.03) and triglycerides (p = 0.02) than controls. These animals had smaller atherosclerotic plaque area in their aortas (p = 0.001) and a smaller intima/media ratio (p = 0.002) than controls, without differences in plaque composition. At the end of the study, campesterol, β-sitosterol, and desmosterol plasma levels did not differ between groups; however, animals treated with Euterpe Oleracea showed lower desmosterol/campesterol (p = 0.026) and desmosterol/ β-sitosterol (p =0.006) ratios than controls. Consumption of Euterpe Oleracea extract markedly improved the lipid profile and attenuated atherosclerosis. These effects were related in part to a better balance in the synthesis and absorption of sterols.
Plasma chemistry references values in psittaciformes.
Lumeij, J T; Overduin, L M
1990-04-01
Reference values for 17 plasma chemical variables in African greys. Amazons, cockatoos and macaws were established for use in avian clinical practice. The inner limits are given for the percentiles P(2.5) and P(97.5) with a probability of 90%. The following variables were studied: urea, creatinine, uric acid, urea/uric acid ratio, osmolality, sodium, potassium, calcium, glucose, aspartate aminotransferase, alanine aminotransferase, gamma glutamyltransferase, lactate dehydrogenase, creatine kinase, bile acids, total protein, albumin/globulin ratio. Differences between methods used and values found in this study and those reported previously are discussed.
R.C. Oliveira Junior; M. Keller; J. F. da F. Ramos; T.P. Beldini; P.M Crill; P.B. de Camargo; J. van Haren
2015-01-01
The Tapajós National Forest (FLONA Tapajós) has 600,000 hectares of protected forest, and is situated 50 km south of the city of Santarém, Pará, Brazil, a port city of 250,000 inhabitants that is located at the confluence of the Tapajós and Amazon Rivers. There is a lot of farmland in the region, which offers many opportunities to study changes in land use. Selective...
Pinheiro, Eduardo A A; Carvalho, Josiwander M; Santos, Diellem C P dos; Feitosa, André O; Marinho, Patrícia S B; Guilhon, Giselle Maria S P; Santos, Lourivaldo S; Souza, Afonso L D de; Marinho, Andrey M R
2013-01-01
The present work reports the isolation of five compounds from Aspergillus sp EJC08 isolated as endophytic from Bauhinia guianensis, a tipical plant of the Amazon. The compounds ergosterol (1), ergosterol peroxide (2), mevalolactone (3), monomethylsulochrin (4) and trypacidin A (5) were isolated by chromatographic procedures and identified by spectral methods of 1D and 2D NMR and MS. Compounds 3, 4 and 5 were tested against Escherichia coli, Pseudomonas aeruginosa, Bacillus subtilis and Staphylococcus aureus and showed good activity.
Ragusa-Netto, J
2014-11-01
Seed predation has major effects on the reproductive success of individuals, spatial patterns of populations, genetic variability, interspecific interactions and ultimately in the diversity of tree communities. At a Brazilian savanna, I evaluated the proportional crop loss of Eriotheca gracilipes due the Blue-Fronted Amazon (Amazona aestiva) during a fruiting period. Also, I analyzed the relationship between proportional crop loss to Amazons and both fruit crop size and the distance from the nearest damaged conspecific. Trees produced from 1 to 109 fruits, so that Amazons foraged more often on trees bearing larger fruit crop size, while seldom visited less productive trees. Moreover, the relationship between fruit crop sizes and the number of depredated fruits was significant. However, when only damaged trees were assessed, I found a negative and significant relation between fruit crop size and proportional crop loss to Blue-Fronted Amazons. Taking into account this as a measure more directly related to the probability of seed survival, a negative density dependent effect emerged. Also, Amazons similarly damaged the fruit crops of either close or distant neighboring damaged trees. Hence, in spite of Blue-Fronted Amazons searched for E. gracilipes bearing large fruit crops, they were swamped due to the presence of more fruits than they could eat. Moderate seed predation by Blue-Fronted Amazons either at trees with large fruit crops or in areas where fruiting trees were aggregated implies in an enhanced probability of E. gracilipes seed survival and consequent regeneration success.
Lipi, Farhana; Chen, Suxiang; Chakravarthy, Madhuri; Rakesh, Shilpa; Veedu, Rakesh N
2016-12-01
Nucleic acid aptamers are single-stranded DNA or RNA oligonucleotide sequences that bind to a specific target molecule with high affinity and specificity through their ability to adopt 3-dimensional structure in solution. Aptamers have huge potential as targeted therapeutics, diagnostics, delivery agents and as biosensors. However, aptamers composed of natural nucleotide monomers are quickly degraded in vivo and show poor pharmacodynamic properties. To overcome this, chemically-modified nucleic acid aptamers are developed by incorporating modified nucleotides after or during the selection process by Systematic Evolution of Ligands by EXponential enrichment (SELEX). This review will discuss the development of chemically-modified aptamers and provide the pros and cons, and new insights on in vitro aptamer selection strategies by using chemically-modified nucleic acid libraries.
Chen, Suxiang; Chakravarthy, Madhuri; Rakesh, Shilpa; Veedu, Rakesh N.
2016-01-01
ABSTRACT Nucleic acid aptamers are single-stranded DNA or RNA oligonucleotide sequences that bind to a specific target molecule with high affinity and specificity through their ability to adopt 3-dimensional structure in solution. Aptamers have huge potential as targeted therapeutics, diagnostics, delivery agents and as biosensors. However, aptamers composed of natural nucleotide monomers are quickly degraded in vivo and show poor pharmacodynamic properties. To overcome this, chemically-modified nucleic acid aptamers are developed by incorporating modified nucleotides after or during the selection process by Systematic Evolution of Ligands by EXponential enrichment (SELEX). This review will discuss the development of chemically-modified aptamers and provide the pros and cons, and new insights on in vitro aptamer selection strategies by using chemically-modified nucleic acid libraries. PMID:27715478
40 CFR 721.10044 - Metal oxide, modified with alkyl and vinyl terminated polysiloxanes (generic).
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Metal oxide, modified with alkyl and... SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.10044 Metal oxide, modified with alkyl... to reporting. (1) The chemical substance identified generically as metal oxide, modified with alkyl...
40 CFR 721.8658 - Modified polymer of vinyl acetate and quaternary ammonium compound (generic).
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Modified polymer of vinyl acetate and... Significant New Uses for Specific Chemical Substances § 721.8658 Modified polymer of vinyl acetate and.... (1) The chemical substance identified generically as modified polymer of vinyl acetate and quaternary...
40 CFR 721.8658 - Modified polymer of vinyl acetate and quaternary ammonium compound (generic).
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Modified polymer of vinyl acetate and... Significant New Uses for Specific Chemical Substances § 721.8658 Modified polymer of vinyl acetate and.... (1) The chemical substance identified generically as modified polymer of vinyl acetate and quaternary...
40 CFR 721.8658 - Modified polymer of vinyl acetate and quaternary ammonium compound (generic).
Code of Federal Regulations, 2012 CFR
2012-07-01
... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Modified polymer of vinyl acetate and... Significant New Uses for Specific Chemical Substances § 721.8658 Modified polymer of vinyl acetate and.... (1) The chemical substance identified generically as modified polymer of vinyl acetate and quaternary...
40 CFR 721.8658 - Modified polymer of vinyl acetate and quaternary ammonium compound (generic).
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Modified polymer of vinyl acetate and... Significant New Uses for Specific Chemical Substances § 721.8658 Modified polymer of vinyl acetate and.... (1) The chemical substance identified generically as modified polymer of vinyl acetate and quaternary...
40 CFR 721.8658 - Modified polymer of vinyl acetate and quaternary ammonium compound (generic).
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Modified polymer of vinyl acetate and... Significant New Uses for Specific Chemical Substances § 721.8658 Modified polymer of vinyl acetate and.... (1) The chemical substance identified generically as modified polymer of vinyl acetate and quaternary...
Cloud draft structure and trace gas transport
NASA Technical Reports Server (NTRS)
Scala, John R.; Tao, Wei-Kuo; Thompson, Anne M.; Simpson, Joanne; Garstang, Michael; Pickering, Kenneth E.; Browell, Edward V.; Sachse, Glen W.; Gregory, Gerald L.; Torres, Arnold L.
1990-01-01
During the second Amazon Boundary Layer Experiment (ABLE 2B), meteorological observations, chemical measurements, and model simulations are utilized in order to interpret convective cloud draft structure and to analyze its role in transport and vertical distribution of trace gases. One-dimensional photochemical model results suggest that the observed poststorm changes in ozone concentration can be attributed to convective transports rather than photochemical production and the results of a two-dimensional time-dependent cloud model simulation are presented for the May 6, 1987 squall system. The mesoscale convective system exhibited evidence of significant midlevel detrainment in addition to transports to anvil heights. Chemical measurements of O3 and CO obtained in the convective environment are used to predict photochemical production within the troposphere and to corroborate the cloud model results.
USDA-ARS?s Scientific Manuscript database
Toxoplasma gondii is an important pathogen in aquatic mammals and its presence in these animals may indicate water contamination of aquatic environment by oocysts. Serum samples from 95 dolphins from free-living Amazon River dolphins (Inia geoffrensis) from Sustainable Development Reserve Mamirauá (...
USDA-ARS?s Scientific Manuscript database
Toxoplasma gondii is an important pathogen in aquatic mammals and its presence in these animals may indicate water contamination of aquatic environment by oocysts. Serum samples from 95 dolphins from free-living Amazon River dolphins (Inia geoffrensis) from Sustainable Development Reserve Mamirauá (...
Amazon River investigations, reconnaissance measurements of July 1963
Oltman, Roy Edwin; Sternberg, H. O'R.; Ames, F.C.; Davis, L.C.
1964-01-01
The first measurements of the flow of the Amazon River were made in July 1963 as a joint project of the University of Brazil, the Brazilian Navy, and the U.S. Geological Survey. The discharge of the Amazon River at Obidos was 7,640,000 cfs at an annual flood stage somewhat lower than the average. For comparison the maximum known discharge of the Mississippi River at Vicksburg is about 2,300,000 cfs. Dissolved-solids concentrations and sediment loads of the Amazon River and of several major tributaries were found to be low.
Spectrometry of Pasture Condition and Biogeochemistry in the Central Amazon
NASA Technical Reports Server (NTRS)
Asner, Gregory P.; Townsend, Alan R.; Bustamante, Mercedes M. C.
1999-01-01
Regional analyses of Amazon cattle pasture biogeochemistry are difficult due to the complexity of human, edaphic, biotic and climatic factors and persistent cloud cover in satellite observations. We developed a method to estimate key biophysical properties of Amazon pastures using hyperspectral reflectance data and photon transport inverse modeling. Remote estimates of live and senescent biomass were strongly correlated with plant-available forms of soil phosphorus and calcium. These results provide a basis for monitoring pasture condition and biogeochemistry in the Amazon Basin using spaceborne hyperspectral sensors.
Forest-rainfall cascades buffer against drought across the Amazon
NASA Astrophysics Data System (ADS)
Staal, Arie; Tuinenburg, Obbe A.; Bosmans, Joyce H. C.; Holmgren, Milena; van Nes, Egbert H.; Scheffer, Marten; Zemp, Delphine Clara; Dekker, Stefan C.
2018-06-01
Tree transpiration in the Amazon may enhance rainfall for downwind forests. Until now it has been unclear how this cascading effect plays out across the basin. Here, we calculate local forest transpiration and the subsequent trajectories of transpired water through the atmosphere in high spatial and temporal detail. We estimate that one-third of Amazon rainfall originates within its own basin, of which two-thirds has been transpired. Forests in the southern half of the basin contribute most to the stability of other forests in this way, whereas forests in the south-western Amazon are particularly dependent on transpired-water subsidies. These forest-rainfall cascades buffer the effects of drought and reveal a mechanism by which deforestation can compromise the resilience of the Amazon forest system in the face of future climatic extremes.
Coura, José Rodrigues; Junqueira, Angela CV
2015-01-01
We refer to Oswaldo Cruz's reports dating from 1913 about the necessities of a healthcare system for the Brazilian Amazon Region and about the journey of Carlos Chagas to 27 locations in this region and the measures that would need to be adopted. We discuss the risks of endemicity of Chagas disease in the Amazon Region. We recommend that epidemiological surveillance of Chagas disease in the Brazilian Amazon Region and Pan-Amazon region should be implemented through continuous monitoring of the human population that lives in the area, their housing, the environment and the presence of triatomines. The monitoring should be performed with periodic seroepidemiological surveys, semi-annual visits to homes by health agents and the training of malaria microscopists and healthcare technicians to identify Trypanosoma cruzi from patients' samples and T. cruzi infection rates among the triatomines caught. We recommend health promotion and control of Chagas disease through public health policies, especially through sanitary education regarding the risk factors for Chagas disease. Finally, we propose a healthcare system through base hospitals, intermediate-level units in the areas of the Brazilian Amazon Region and air transportation, considering the distances to be covered for medical care. PMID:26560976
The effect on biological and moisture resistance of epichlorohydrin chemically modified wood
Rebecca E. Ibach; Beom-Goo Lee
2002-01-01
Southern pine solid wood and fiber were chemically modified with epichlorohydrin to help in understanding the role of moisture in the mechanism of biological effectiveness of chemically modified wood. The solid wood had weight gains from 11% to 34%, while the fiber had weight gains from 9% to 75%. After modification, part of the specimens were water leached for 2 weeks...
NASA Astrophysics Data System (ADS)
Liptak, J.; Keppel-Aleks, G.
2016-12-01
Amazon forests store an estimated 25% percent of global terrestrial carbon per year1, 2, but the responses of Amazon carbon uptake to climate change is highly uncertain. One source of this uncertainty is tropical sea surface temperature variability driven by teleconnections. El Nino-Southern Oscillation (ENSO) is a key driver of year-to-year Amazon carbon exchange, with associated temperature and precipitation changes favoring net carbon storage in La Nina years, and net carbon release during El Nino years3. To determine how Amazon climate and terrestrial carbon fluxes react to ENSO alone and in concert with other SST-driven teleconnections such as the Atlantic Multidecadal Oscillation (AMO), we force the atmosphere (CAM5) and land (CLM4) components of the CESM(BGC) with prescribed monthly SSTs over the period 1950—2014 in a Historical control simulation. We then run an experiment (PAC) with time-varying SSTs applied only to the tropical equatorial Pacific Ocean, and repeating SST seasonal cycle climatologies elsewhere. Limiting SST variability to the equatorial Pacific indicates that other processes enhance ENSO-driven Amazon climate anomalies. Compared to the Historical control simulation, warming, drying and terrestrial carbon loss over the Amazon during El Nino periods are lower in the PAC simulation, especially prior to 1990 during the cool phase of the AMO. Cooling, moistening, and net carbon uptake during La Nina periods are also reduced in the PAC simulation, but differences are greater after 1990 during the warm phase of the AMO. By quantifying the relationships among climate drivers and carbon fluxes in the Historical and PAC simulations, we both assess the sensitivity of these relationships to the magnitude of ENSO forcing and quantify how other teleconnections affect ENSO-driven Amazon climate feedbacks. We expect that these results will help us improve hypotheses for how Atlantic and Pacific climate trends will affect future Amazon carbon carbon cycling. Pan, Y. et al. A large and persistent carbon sink in the world's forests. Science 333, 988-993 (2011) Brienen, Roel J. W. et al. Long-term decline of the Amazon carbon sink. Nature 519, 344-348 (2015) Botta, A. et al. Long-term variations of climate and carbon fluxes over the Amazon basin. Geophys. Res. Lett. 29 (2002)
NASA Astrophysics Data System (ADS)
Jung, H.; Alsdorf, D.
2006-12-01
Monitoring discharge in the main channels of rivers and upland tributaries as well as storage changes in floodplain lakes is necessary for understanding flooding hazards, methane production, sediment transport, and nutrient exchange. Interferometric processing of synthetic aperture radar (SAR) data may enable hydrologists to detect environmental and ecological changes in hydrological systems over space and time. An aim of our experiments is to characterize interferometric SAR coherence variations that occur in Amazon aquatic habitats. We analyze coherence variations in JERS-1 data at three central Amazon sites; Lake Balbina, the Cabaliana floodplain, and the confluence of the Purus and Amazon rivers. Because radar pulse interactions with inundated vegetation typically follow a double-bounce travel path which returns energy to the antenna, coherence will vary with vegetation type, physical baseline, and temporal baseline. Balbina's vegetation consists mostly of forest and inundated trunks of dead, leafless trees as opposed to Cabaliana and Amazon- Purus (dominated by flooded forests), thus it serves to isolate the vegetation signal. Coherence variations with baselines were determined from 253 interferograms at Balbina, 210 at Calbaliana, and 153 at Purus. The average temporal and perpendicular baselines (mean std.) are 574 394 days and 1708 1159 m at Balbina, 637 435 days and 1381 981 m at Cabaliana, and 587 425 days and 1430 964 m at Purus. Balbina has a stronger coherence than either Cabaliana or Amazon-Purus. With results of Mann-Whitney statistical tests, Balbina has a difference between terre-firme and flooded coherence values plotted with perpendicular baseline but Cabaliana and Amazon-Purus do not show this difference. Balbina has a linearly decreasing trend in coherence plotted with temporal baseline whereas Cabaliana and Amazon-Purus have a steep drop-off, non- linear change. A strong annual periodicity is evident on power spectrums of the coherence values for Cabaliana and Amazon-Purus, but not in Balbina and is likely an indicator of the annual Amazon flood wave. Each ecological habitat is delineated in the Balbina coherence values plotted with temporal baseline, but only during high water and time-periods less than 2 years is such delineation visible in the Cabaliana and Amazon-Purus regions. Taken together, these observations suggest terre-firme does not have a seasonal variation whereas flooded areas vary with the season.
NASA Astrophysics Data System (ADS)
Andreae, M. O.; Afchine, A.; Albrecht, R. I.; Artaxo, P.; Borrmann, S.; Cecchini, M. A.; Costa, A.; Fütterer, D.; Järvinen, E.; Klimach, T.; Konemann, T.; Kraemer, M.; Machado, L.; Mertes, S.; Pöhlker, C.; Pöhlker, M. L.; Poeschl, U.; Sauer, D. N.; Schnaiter, M.; Schneider, J.; Schulz, C.; Spanu, A.; Walser, A.; Wang, J.; Weinzierl, B.; Wendisch, M.
2016-12-01
Observations during ACRIDICON-CHUVA showed high aerosol concentrations in the upper troposphere (UT) over the Amazon Basin, with aerosol number concentrations after normalization to STP often exceeding those in the boundary layer (BL) by one or two orders of magnitude. The measurements were made during the German-Brazilian cooperative aircraft campaign ACRIDICON-CHUVA (Aerosol, Cloud, Precipitation, and Radiation Interactions and Dynamics of Convective Cloud Systems) on the German research aircraft HALO. The campaign took place over the Amazon Basin in September/October 2014, with the objective of studying tropical deep convective clouds over the Amazon rainforest and their interactions with trace gases, aerosol particles, and atmospheric radiation. Aerosol enhancements were consistently observed on all flights, using several aerosol metrics, including condensation nuclei (CN), cloud condensation nuclei (CCN), and chemical species mass concentrations. These UT aerosols were different in their composition and size distribution from the aerosol in the BL, making convective transport of particles unlikely as a source. The regions in the immediate outflow of deep convective clouds were depleted in aerosol particles, whereas dramatically enhanced small (<90 nm diameter) aerosol number concentrations were found in UT regions that had experienced outflow from deep convection in the preceding 24-48 hours. We also found elevated concentrations of larger (>90 nm) particles in the UT, which consisted mostly of organic matter and nitrate and were very effective CCN. Our findings suggest that aerosol production takes place in the UT from volatile material brought up by deep convection, which is converted to condensable species in the UT. Subsequently, downward mixing and transport of upper tropospheric aerosol may be a source of particles to the BL, where they increase in size by the condensation of biogenic volatile organic carbon (BVOC) oxidation products. This may be an important source of aerosol particles in the Amazonian BL, where aerosol nucleation and new particle formation has not been observed. We propose that this may have been the dominant process supplying secondary aerosols in the pristine atmosphere, making clouds the dominant control of both removal and production of atmospheric particles.
siRNAmod: A database of experimentally validated chemically modified siRNAs.
Dar, Showkat Ahmad; Thakur, Anamika; Qureshi, Abid; Kumar, Manoj
2016-01-28
Small interfering RNA (siRNA) technology has vast potential for functional genomics and development of therapeutics. However, it faces many obstacles predominantly instability of siRNAs due to nuclease digestion and subsequently biologically short half-life. Chemical modifications in siRNAs provide means to overcome these shortcomings and improve their stability and potency. Despite enormous utility bioinformatics resource of these chemically modified siRNAs (cm-siRNAs) is lacking. Therefore, we have developed siRNAmod, a specialized databank for chemically modified siRNAs. Currently, our repository contains a total of 4894 chemically modified-siRNA sequences, comprising 128 unique chemical modifications on different positions with various permutations and combinations. It incorporates important information on siRNA sequence, chemical modification, their number and respective position, structure, simplified molecular input line entry system canonical (SMILES), efficacy of modified siRNA, target gene, cell line, experimental methods, reference etc. It is developed and hosted using Linux Apache MySQL PHP (LAMP) software bundle. Standard user-friendly browse, search facility and analysis tools are also integrated. It would assist in understanding the effect of chemical modifications and further development of stable and efficacious siRNAs for research as well as therapeutics. siRNAmod is freely available at: http://crdd.osdd.net/servers/sirnamod.
Biogenic cloud nuclei in the central Amazon during the transition from wet to dry season
NASA Astrophysics Data System (ADS)
Whitehead, James D.; Darbyshire, Eoghan; Brito, Joel; Barbosa, Henrique M. J.; Crawford, Ian; Stern, Rafael; Gallagher, Martin W.; Kaye, Paul H.; Allan, James D.; Coe, Hugh; Artaxo, Paulo; McFiggans, Gordon
2016-08-01
The Amazon basin is a vast continental area in which atmospheric composition is relatively unaffected by anthropogenic aerosol particles. Understanding the properties of the natural biogenic aerosol particles over the Amazon rainforest is key to understanding their influence on regional and global climate. While there have been a number of studies during the wet season, and of biomass burning particles in the dry season, there has been relatively little work on the transition period - the start of the dry season in the absence of biomass burning. As part of the Brazil-UK Network for Investigation of Amazonian Atmospheric Composition and Impacts on Climate (BUNIAACIC) project, aerosol measurements, focussing on unpolluted biogenic air masses, were conducted at a remote rainforest site in the central Amazon during the transition from wet to dry season in July 2013. This period marks the start of the dry season but before significant biomass burning occurs in the region. Median particle number concentrations were 266 cm-3, with size distributions dominated by an accumulation mode of 130-150 nm. During periods of low particle counts, a smaller Aitken mode could also be seen around 80 nm. While the concentrations were similar in magnitude to those seen during the wet season, the size distributions suggest an enhancement in the accumulation mode compared to the wet season, but not yet to the extent seen later in the dry season, when significant biomass burning takes place. Submicron nonrefractory aerosol composition, as measured by an aerosol chemical speciation monitor (ACSM), was dominated by organic material (around 81 %). Aerosol hygroscopicity was probed using measurements from a hygroscopicity tandem differential mobility analyser (HTDMA), and a quasi-monodisperse cloud condensation nuclei counter (CCNc). The hygroscopicity parameter, κ, was found to be low, ranging from 0.12 for Aitken-mode particles to 0.18 for accumulation-mode particles. This was consistent with previous studies in the region, but lower than similar measurements conducted in Borneo, where κ ranged 0.17-0.37. A wide issue bioaerosol sensor (WIBS-3M) was deployed at ground level to probe the coarse mode, detecting primary biological aerosol by fluorescence (fluorescent biological aerosol particles, or FBAPs). The mean FBAP number concentration was 400 ± 242 L-1; however, this ranged from around 200 L-1 during the day to as much as 1200 L-1 at night. FBAPs dominated the coarse-mode particles, comprising between 55 and 75 % of particles during the day to more than 90 % at night. Non-FBAPs did not show a strong diurnal pattern. Comparison with previous FBAP measurements above canopy at the same location suggests there is a strong vertical gradient in FBAP concentrations through the canopy. Cluster analysis of the data suggests that FBAPs were dominated (around 70 %) by fungal spores. Further, long-term measurements will be required in order to fully examine the seasonal variability and distribution of primary biological aerosol particles through the canopy. This is the first time that such a suite of measurements has been deployed at this site to investigate the chemical composition and properties of the biogenic contributions to Amazonian aerosol during the transition period from the wet to the dry season, and thus provides a unique comparison to the aerosol properties observed during the wet season in previous similar campaigns. This was also the first deployment of a WIBS in the Amazon rainforest to study coarse-mode particles, particularly primary biological aerosol particles, which are likely to play an important role as ice nuclei in the region.
Nobre, Carlos A.; Sampaio, Gilvan; Borma, Laura S.; Castilla-Rubio, Juan Carlos; Silva, José S.; Cardoso, Manoel
2016-01-01
For half a century, the process of economic integration of the Amazon has been based on intensive use of renewable and nonrenewable natural resources, which has brought significant basin-wide environmental alterations. The rural development in the Amazonia pushed the agricultural frontier swiftly, resulting in widespread land-cover change, but agriculture in the Amazon has been of low productivity and unsustainable. The loss of biodiversity and continued deforestation will lead to high risks of irreversible change of its tropical forests. It has been established by modeling studies that the Amazon may have two “tipping points,” namely, temperature increase of 4 °C or deforestation exceeding 40% of the forest area. If transgressed, large-scale “savannization” of mostly southern and eastern Amazon may take place. The region has warmed about 1 °C over the last 60 y, and total deforestation is reaching 20% of the forested area. The recent significant reductions in deforestation—80% reduction in the Brazilian Amazon in the last decade—opens up opportunities for a novel sustainable development paradigm for the future of the Amazon. We argue for a new development paradigm—away from only attempting to reconcile maximizing conservation versus intensification of traditional agriculture and expansion of hydropower capacity—in which we research, develop, and scale a high-tech innovation approach that sees the Amazon as a global public good of biological assets that can enable the creation of innovative high-value products, services, and platforms through combining advanced digital, biological, and material technologies of the Fourth Industrial Revolution in progress. PMID:27638214
Nobre, Carlos A; Sampaio, Gilvan; Borma, Laura S; Castilla-Rubio, Juan Carlos; Silva, José S; Cardoso, Manoel
2016-09-27
For half a century, the process of economic integration of the Amazon has been based on intensive use of renewable and nonrenewable natural resources, which has brought significant basin-wide environmental alterations. The rural development in the Amazonia pushed the agricultural frontier swiftly, resulting in widespread land-cover change, but agriculture in the Amazon has been of low productivity and unsustainable. The loss of biodiversity and continued deforestation will lead to high risks of irreversible change of its tropical forests. It has been established by modeling studies that the Amazon may have two "tipping points," namely, temperature increase of 4 °C or deforestation exceeding 40% of the forest area. If transgressed, large-scale "savannization" of mostly southern and eastern Amazon may take place. The region has warmed about 1 °C over the last 60 y, and total deforestation is reaching 20% of the forested area. The recent significant reductions in deforestation-80% reduction in the Brazilian Amazon in the last decade-opens up opportunities for a novel sustainable development paradigm for the future of the Amazon. We argue for a new development paradigm-away from only attempting to reconcile maximizing conservation versus intensification of traditional agriculture and expansion of hydropower capacity-in which we research, develop, and scale a high-tech innovation approach that sees the Amazon as a global public good of biological assets that can enable the creation of innovative high-value products, services, and platforms through combining advanced digital, biological, and material technologies of the Fourth Industrial Revolution in progress.
NASA Astrophysics Data System (ADS)
Nobre, Carlos A.; Sampaio, Gilvan; Borma, Laura S.; Castilla-Rubio, Juan Carlos; Silva, José S.; Cardoso, Manoel
2016-09-01
For half a century, the process of economic integration of the Amazon has been based on intensive use of renewable and nonrenewable natural resources, which has brought significant basin-wide environmental alterations. The rural development in the Amazonia pushed the agricultural frontier swiftly, resulting in widespread land-cover change, but agriculture in the Amazon has been of low productivity and unsustainable. The loss of biodiversity and continued deforestation will lead to high risks of irreversible change of its tropical forests. It has been established by modeling studies that the Amazon may have two “tipping points,” namely, temperature increase of 4 °C or deforestation exceeding 40% of the forest area. If transgressed, large-scale “savannization” of mostly southern and eastern Amazon may take place. The region has warmed about 1 °C over the last 60 y, and total deforestation is reaching 20% of the forested area. The recent significant reductions in deforestation—80% reduction in the Brazilian Amazon in the last decade—opens up opportunities for a novel sustainable development paradigm for the future of the Amazon. We argue for a new development paradigm—away from only attempting to reconcile maximizing conservation versus intensification of traditional agriculture and expansion of hydropower capacity—in which we research, develop, and scale a high-tech innovation approach that sees the Amazon as a global public good of biological assets that can enable the creation of innovative high-value products, services, and platforms through combining advanced digital, biological, and material technologies of the Fourth Industrial Revolution in progress.
Holocene palaeoenvironmental history of the Amazonian mangrove belt
NASA Astrophysics Data System (ADS)
Cohen, Marcelo Cancela Lisboa; Pessenda, Luiz Carlos Ruiz; Behling, Hermann; de Fátima Rossetti, Dilce; França, Marlon Carlos; Guimarães, José Tasso Felix; Friaes, Yuri; Smith, Clarisse Beltrão
2012-11-01
Wetland dynamic in the northern Brazilian Amazon region during the Holocene was reviewed using palynological, carbon and nitrogen isotopes records, and C/N ratio previously published. The integration of 72 radiocarbon dates recorded in 34 sediment cores sampled along the marine and fluvial littoral, and mainly influenced by the Amazon River, reveals that marine influence and mangrove vegetation were wider than today on the mouth of Amazon River between >8990-8690 and 2300-2230 cal yr BP, forming a continuous mangrove belt along the northern Brazilian Amazon littoral. The establishment of this mangrove strip is a direct consequence of the marine incursion caused by post-glacial sea-level rise possibly associated with tectonic subsidence during the Early and Middle Holocene. In the Late Holocene, in areas influenced by the Amazon River discharge, the mangroves were replaced by freshwater vegetation, and the coast morphology evolved from an estuarine dominated into a rectilinear coast due to coastal progradation. Nevertheless, the marine-influenced littoral, which is currently dominated by mangroves and salt-marsh vegetation, has persistently had brackish water vegetation over tidal mud flats throughout the entire Holocene. Likely, the fragmentation of this continuous mangrove line during the Late Holocene was caused by the increase of river freshwater discharge associated to the change from dry into wet climates in the Late Holocene. This caused a significant decrease of tidal water salinity in areas near the mouth of Amazon River. These changes in the Amazon discharge are probably associated with dry and wet periods in the northern Amazon region during the Holocene.
NASA Astrophysics Data System (ADS)
Morgan, William; Allan, James; Flynn, Michael; Darbyshire, Eoghan; Hodgson, Amy; Liu, Dantong; O'shea, Sebastian; Bauguitte, Stephane; Szpek, Kate; Langridge, Justin; Johnson, Ben; Haywood, Jim; Longo, Karla; Artaxo, Paulo; Coe, Hugh
2014-05-01
Biomass burning represents one of the largest sources of particulate matter to the atmosphere, resulting in a significant perturbation to the Earth's radiative balance coupled with serious impacts on public health. Globally, biomass burning aerosols are thought to exert a small warming effect but with the uncertainty being 4 times greater than the central estimate. On regional scales, the impact is substantially greater, particularly in areas such as the Amazon Basin where large, intense and frequent burning occurs on an annual basis for several months. Absorption by atmospheric aerosols is underestimated by models over South America, which points to significant uncertainties relating to Black Carbon (BC) aerosol properties. Initial results from the South American Biomass Burning Analysis (SAMBBA) field experiment, which took place during September and October 2012 over Brazil on-board the UK Facility for Airborne Atmospheric Measurement (FAAM) BAe-146 research aircraft, are presented here. Aerosol chemical composition was measured by an Aerodyne Aerosol Mass Spectrometer (AMS) and a DMT Single Particle Soot Photometer (SP2). The physical, chemical and optical properties of the aerosols across the region will be characterized in order to establish the impact of biomass burning on regional air quality, weather and climate. The aircraft sampled a range of conditions including sampling of pristine Rainforest, fresh biomass burning plumes, regional haze and elevated biomass burning layers within the free troposphere. The aircraft sampled biomass burning aerosol across the southern Amazon in the states of Rondonia and Mato Grosso, as well as in a Cerrado (Savannah-like) region in Tocantins state. This presented a range of fire conditions, both in terms of their number, intensity, vegetation-type and their combustion efficiencies. Near-source sampling of fires in Rainforest environments suggested that smouldering combustion dominated, while flaming combustion dominated in the Cerrado. This led to significant differences in aerosol chemical composition, particularly in terms of the BC content, with BC being enhanced in the Cerrado region compared with the Rainforest environment. This was reflected in the single scattering albedo of the regional smoke haze, with values of 0.9 observed in the Rainforest environments compared with a value of 0.8 in the Cerrado region. This contrast results in a net cooling and warming respectively in terms of the aerosol direct radiative effect. BC-containing particles were found to be rapidly coated in the near-field, while the organic aerosol component was observed to oxidise rapidly upon advection and dilution downwind of major smoke plumes. Significant differences in the coating thickness of the BC-containing particles were observed when comparing the Rainforest and Cerrado environments. Such properties have important implications for the life cycle and formation of particulate material, as well as their optical and radiative properties. The results presented enhance our knowledge of biomass burning aerosol in a sensitive region of the globe, where relatively few measurement campaigns have taken place previously.
NASA Astrophysics Data System (ADS)
Morgan, W.; Allan, J. D.; Flynn, M.; Darbyshire, E.; Hodgson, A.; Liu, D.; O'Shea, S.; Bauguitte, S.; Szpek, K.; Johnson, B.; Haywood, J.; Longo, K.; Artaxo, P.; Coe, H.
2013-12-01
Biomass burning represents one of the largest sources of particulate matter to the atmosphere, resulting in a significant perturbation to the Earth's radiative balance coupled with serious impacts on public health. On regional scales, the impacts are substantial, particularly in areas such as the Amazon Basin where large, intense and frequent burning occurs on an annual basis for several months. Absorption by atmospheric aerosols is underestimated by models over South America, which points to significant uncertainties relating to Black Carbon (BC) aerosol properties. Initial results from the South American Biomass Burning Analysis (SAMBBA) field experiment, which took place during September and October 2012 over Brazil on-board the UK Facility for Airborne Atmospheric Measurement (FAAM) BAe-146 research aircraft, are presented here. Aerosol chemical composition was measured by an Aerodyne Aerosol Mass Spectrometer (AMS) and a DMT Single Particle Soot Photometer (SP2). The physical, chemical and optical properties of the aerosols across the region will be characterized in order to establish the impact of biomass burning on regional air quality, weather and climate. The aircraft sampled a range of conditions including sampling of pristine Rainforest, fresh biomass burning plumes, regional haze and elevated biomass burning layers within the free troposphere. The aircraft sampled biomass burning aerosol across the southern Amazon in the states of Rondonia and Mato Grosso, as well as in a Cerrado (Savannah-like) region in Tocantins state. This presented a range of fire conditions, in terms of their number, intensity, vegetation-type and their combustion efficiencies. Near-source sampling of fires in Rainforest environments suggested that smouldering combustion dominated, while flaming combustion dominated in the Cerrado. This led to significant differences in aerosol chemical composition, particularly in terms of the BC content, with BC being enhanced in the Cerrado region compared with the Rainforest environment. This was reflected in the single scattering albedo of the regional smoke haze, with values of 0.9 observed in the Rainforest environments compared with a value of 0.8 in the Cerrado region. This contrast results in a net cooling and warming respectively in terms of the aerosol direct radiative effect. BC-containing particles were found to be rapidly coated in the near-field, with little evidence for additional coating upon advection and dilution. This is consistent with organic aerosol mass being approximately constant when accounting for dilution both close to source and on the regional scale. However, the bulk organic aerosol composition became increasingly oxidised with distance from source. Such properties have important implications for the life cycle and formation of particulate material, which governs its subsequent impacts. Biomass burning layers were observed aloft in the free troposphere, which has potential implications for atmospheric stability profiles and cloud formation. The results presented enhance our knowledge of biomass burning aerosol in a sensitive region of the globe, where relatively few measurement campaigns have taken place previously.
40 CFR 721.10151 - Modified styrene, divinylbenzene polymer (generic).
Code of Federal Regulations, 2010 CFR
2010-07-01
... polymer (generic). 721.10151 Section 721.10151 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Specific Chemical Substances § 721.10151 Modified styrene, divinylbenzene polymer (generic). (a) Chemical... as modified styrene, divinylbenzene polymer (PMN P-07-642) is subject to reporting under this section...
40 CFR 721.10151 - Modified styrene, divinylbenzene polymer (generic).
Code of Federal Regulations, 2011 CFR
2011-07-01
... polymer (generic). 721.10151 Section 721.10151 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Specific Chemical Substances § 721.10151 Modified styrene, divinylbenzene polymer (generic). (a) Chemical... as modified styrene, divinylbenzene polymer (PMN P-07-642) is subject to reporting under this section...
40 CFR 721.10120 - Siloxane modified alumina nanoparticles (generic).
Code of Federal Regulations, 2010 CFR
2010-07-01
... nanoparticles (generic). 721.10120 Section 721.10120 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Specific Chemical Substances § 721.10120 Siloxane modified alumina nanoparticles (generic). (a) Chemical... as siloxane modified alumina nanoparticles (PMN P-05-687) is subject to reporting under this section...
40 CFR 721.10120 - Siloxane modified alumina nanoparticles (generic).
Code of Federal Regulations, 2014 CFR
2014-07-01
... nanoparticles (generic). 721.10120 Section 721.10120 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Specific Chemical Substances § 721.10120 Siloxane modified alumina nanoparticles (generic). (a) Chemical... as siloxane modified alumina nanoparticles (PMN P-05-687) is subject to reporting under this section...
40 CFR 721.10120 - Siloxane modified alumina nanoparticles (generic).
Code of Federal Regulations, 2012 CFR
2012-07-01
... nanoparticles (generic). 721.10120 Section 721.10120 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Specific Chemical Substances § 721.10120 Siloxane modified alumina nanoparticles (generic). (a) Chemical... as siloxane modified alumina nanoparticles (PMN P-05-687) is subject to reporting under this section...
40 CFR 721.10120 - Siloxane modified alumina nanoparticles (generic).
Code of Federal Regulations, 2011 CFR
2011-07-01
... nanoparticles (generic). 721.10120 Section 721.10120 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Specific Chemical Substances § 721.10120 Siloxane modified alumina nanoparticles (generic). (a) Chemical... as siloxane modified alumina nanoparticles (PMN P-05-687) is subject to reporting under this section...
40 CFR 721.10120 - Siloxane modified alumina nanoparticles (generic).
Code of Federal Regulations, 2013 CFR
2013-07-01
... nanoparticles (generic). 721.10120 Section 721.10120 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Specific Chemical Substances § 721.10120 Siloxane modified alumina nanoparticles (generic). (a) Chemical... as siloxane modified alumina nanoparticles (PMN P-05-687) is subject to reporting under this section...
40 CFR 721.10151 - Modified styrene, divinylbenzene polymer (generic).
Code of Federal Regulations, 2012 CFR
2012-07-01
... polymer (generic). 721.10151 Section 721.10151 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Specific Chemical Substances § 721.10151 Modified styrene, divinylbenzene polymer (generic). (a) Chemical... as modified styrene, divinylbenzene polymer (PMN P-07-642) is subject to reporting under this section...
40 CFR 721.10151 - Modified styrene, divinylbenzene polymer (generic).
Code of Federal Regulations, 2014 CFR
2014-07-01
... polymer (generic). 721.10151 Section 721.10151 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Specific Chemical Substances § 721.10151 Modified styrene, divinylbenzene polymer (generic). (a) Chemical... as modified styrene, divinylbenzene polymer (PMN P-07-642) is subject to reporting under this section...
40 CFR 721.10151 - Modified styrene, divinylbenzene polymer (generic).
Code of Federal Regulations, 2013 CFR
2013-07-01
... polymer (generic). 721.10151 Section 721.10151 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Specific Chemical Substances § 721.10151 Modified styrene, divinylbenzene polymer (generic). (a) Chemical... as modified styrene, divinylbenzene polymer (PMN P-07-642) is subject to reporting under this section...
Introduction: Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5)
NASA Astrophysics Data System (ADS)
Martin, S. T.; Artaxo, P.; Machado, L. A. T.; Manzi, A. O.; Souza, R. A. F.; Schumacher, C.; Wang, J.; Andreae, M. O.; Barbosa, H. M. J.; Fan, J.; Fisch, G.; Goldstein, A. H.; Guenther, A.; Jimenez, J. L.; Pöschl, U.; Silva Dias, M. A.; Smith, J. N.; Wendisch, M.
2016-04-01
The Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5) Experiment was carried out in the environs of Manaus, Brazil, in the central region of the Amazon basin for 2 years from 1 January 2014 through 31 December 2015. The experiment focused on the complex interactions among vegetation, atmospheric chemistry, and aerosol production on the one hand and their connections to aerosols, clouds, and precipitation on the other. The objective was to understand and quantify these linked processes, first under natural conditions to obtain a baseline and second when altered by the effects of human activities. To this end, the pollution plume from the Manaus metropolis, superimposed on the background conditions of the central Amazon basin, served as a natural laboratory. The present paper, as the introduction to the special issue of GoAmazon2014/5, presents the context and motivation of the GoAmazon2014/5 Experiment. The nine research sites, including the characteristics and instrumentation of each site, are presented. The sites range from time point zero (T0) upwind of the pollution, to T1 in the midst of the pollution, to T2 just downwind of the pollution, to T3 furthest downwind of the pollution (70 km). In addition to the ground sites, a low-altitude G-159 Gulfstream I (G-1) observed the atmospheric boundary layer and low clouds, and a high-altitude Gulfstream G550 (HALO) operated in the free troposphere. During the 2-year experiment, two Intensive Operating Periods (IOP1 and IOP2) also took place that included additional specialized research instrumentation at the ground sites as well as flights of the two aircraft. GoAmazon2014/5 IOP1 was carried out from 1 February to 31 March 2014 in the wet season. GoAmazon2014/5 IOP2 was conducted from 15 August to 15 October 2014 in the dry season. The G-1 aircraft flew during both IOP1 and IOP2, and the HALO aircraft flew during IOP2. In the context of the Amazon basin, the two IOPs also correspond to the clean and biomass burning seasons, respectively. The Manaus plume is present year-round, and it is transported by prevailing northeasterly and easterly winds in the wet and dry seasons, respectively. This introduction also organizes information relevant to many papers in the special issue. Information is provided on the vehicle fleet, power plants, and industrial activities of Manaus. The mesoscale and synoptic meteorologies relevant to the two IOPs are presented. Regional and long-range transport of emissions during the two IOPs is discussed based on satellite observations across South America and Africa. Fire locations throughout the airshed are detailed. In conjunction with the context and motivation of GoAmazon2014/5 as presented in this introduction, research articles including thematic overview articles are anticipated in this special issue to describe the detailed results and findings of the GoAmazon2014/5 Experiment.
Disease Vector Ecology Profile: Colombia
1998-12-01
the Amazon Basin. Unknown. Unknown. Culex gnomatus VEE (Ecuador, Peru ) Many mammals and birds, but equines are key reservoirs with high...Arboviruses other than Dengue or Yellow Fever in the Amazon Basin and Associated Northwestern Regions of South America...widespread (Amazonia, Orinoquia, Cauca Valley, Caribbean regions), and to mefloquine and amodiaquine ( Amazon Basin). Plasmodium vivax resistance
Selective logging in the Brazilian Amazon.
G. P. Asner; D. E. Knapp; E. N. Broadbent; P. J. C. Oliveira; M Keller; J. N. Silva
2005-01-01
Amazon deforestation has been measured by remote sensing for three decades. In comparison, selective logging has been mostly invisible to satellites. We developed a large-scale, high-resolution, automated remote-sensing analysis of selective logging in the top five timber-producing states of the Brazilian Amazon. Logged areas ranged from 12,075 to 19,823 square...
The Green Ocean: Precipitation Insights from the GoAmazon2014/5 Experiment
Wang, Die; Giangrande, Scott E.; Bartholomew, Mary Jane; ...
2018-02-07
This study summarizes the precipitation properties collected during the GoAmazon2014/5 campaign near Manaus in central Amazonia, Brazil. Precipitation breakdowns, summary radar rainfall relationships and self-consistency concepts from a coupled disdrometer and radar wind profiler measurements are presented. The properties of Amazon cumulus and associated stratiform precipitation are discussed, including segregations according to seasonal (Wet/Dry regime) variability, cloud echo-top height and possible aerosol influences on the apparent oceanic characteristics of the precipitation drop size distributions. Overall, we observe that the Amazon precipitation straddles behaviors found during previous U.S. Department of Energy Atmospheric Radiation Measurements program (ARM) tropical deployments, with distributions favoringmore » higher concentrations of smaller drops than ARM continental examples. Oceanic type precipitation characteristics are predominantly observed during the Amazon Wet seasons. Finally, an exploration of the controls on Wet season precipitation properties reveals that wind direction, as compared with other standard radiosonde thermodynamic parameters or aerosol count/regime classifications performed at the ARM site, provides a good indicator for those Wet season Amazon events having an oceanic character for their precipitation drop size distributions.« less
The Green Ocean: Precipitation Insights from the GoAmazon2014/5 Experiment
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wang, Die; Giangrande, Scott E.; Bartholomew, Mary Jane
This study summarizes the precipitation properties collected during the GoAmazon2014/5 campaign near Manaus in central Amazonia, Brazil. Precipitation breakdowns, summary radar rainfall relationships and self-consistency concepts from a coupled disdrometer and radar wind profiler measurements are presented. The properties of Amazon cumulus and associated stratiform precipitation are discussed, including segregations according to seasonal (Wet/Dry regime) variability, cloud echo-top height and possible aerosol influences on the apparent oceanic characteristics of the precipitation drop size distributions. Overall, we observe that the Amazon precipitation straddles behaviors found during previous U.S. Department of Energy Atmospheric Radiation Measurements program (ARM) tropical deployments, with distributions favoringmore » higher concentrations of smaller drops than ARM continental examples. Oceanic type precipitation characteristics are predominantly observed during the Amazon Wet seasons. Finally, an exploration of the controls on Wet season precipitation properties reveals that wind direction, as compared with other standard radiosonde thermodynamic parameters or aerosol count/regime classifications performed at the ARM site, provides a good indicator for those Wet season Amazon events having an oceanic character for their precipitation drop size distributions.« less
Precipitation Based Malaria Patterns in the Amazon -- Will Deforestation Alter Risk?
NASA Astrophysics Data System (ADS)
Olson, S. H.; Durieux, L.; Elguero, E.; Foley, J.; Gagnon, R.; Guegan, J.; Patz, J.
2007-12-01
The World Health Organization, estimates that forty-two percent of malaria cases are "associated with policies and practices regarding land use, deforestation, water resource management, settlement siting and modified house design". This estimate was drawn from expert opinion and studies performed at local scales, but little research has investigated the cumulative impacts of land use and land cover changes occurring in the Amazon Basin on malaria. Much less is understood about the impact of changing land use and subsequent precipitation regimes on malaria risk. To understand how land use practices may alter malaria patterns in the Basin we present an analysis of municipio (n=755) malaria case data and monthly precipitation patterns between 1996 and 1999. Climate data originated from the CRU TS 2.1 half-degree grid resolution climate data set. We present a hierarchical (random coefficients) log-linear Poisson model relating malaria incidence to precipitation for both municipos and states. At the Basin scale precipitation and cases show strong relationships. Precipitation and cases are asynchronous across the period of observation, but detailed inspection of states and individual municipios reveal geographic dependencies of precipitation and malaria incidence. Future research will link the patterns of precipitation and malaria to anticipated changes in climate from deforestation in the Basin.
A delicate adjustment: Wallace and Bates on the Amazon and "the problem of the origin of species".
van Wyhe, John
2014-01-01
For over a century it has been believed that Alfred Russel Wallace and Henry Walter Bates set out for the Amazon in 1848 with the aim of "solving the problem of the origin of species". Yet this enticing story is based on only one sentence. Bates claimed in the preface to his 1863 book that Wallace stated this was the aim of their expedition in an 1847 letter. Bates gave a quotation from the letter. But Wallace himself never endorsed or repeated this story. Many writers have acknowledged that this letter still survives. Yet the wording is different from that quoted by Bates and the letter says nothing of an expedition. It is argued that the sentence given by Bates is not a genuine quotation from this or any other Wallace letter but was modified by Bates to promote his own reputation. More significantly, this leads to the conclusion that there was a very sudden and dramatic shift in the way species were thought of and discussed after Darwin's Origin of species appeared. Something called "the problem of the origin of species" (and similar variants) never occurred before Darwin's book but exploded in frequency immediately after it. A profound change in how species origins were discussed happened which no one seemed to notice.
Cloud CPFP: a shotgun proteomics data analysis pipeline using cloud and high performance computing.
Trudgian, David C; Mirzaei, Hamid
2012-12-07
We have extended the functionality of the Central Proteomics Facilities Pipeline (CPFP) to allow use of remote cloud and high performance computing (HPC) resources for shotgun proteomics data processing. CPFP has been modified to include modular local and remote scheduling for data processing jobs. The pipeline can now be run on a single PC or server, a local cluster, a remote HPC cluster, and/or the Amazon Web Services (AWS) cloud. We provide public images that allow easy deployment of CPFP in its entirety in the AWS cloud. This significantly reduces the effort necessary to use the software, and allows proteomics laboratories to pay for compute time ad hoc, rather than obtaining and maintaining expensive local server clusters. Alternatively the Amazon cloud can be used to increase the throughput of a local installation of CPFP as necessary. We demonstrate that cloud CPFP allows users to process data at higher speed than local installations but with similar cost and lower staff requirements. In addition to the computational improvements, the web interface to CPFP is simplified, and other functionalities are enhanced. The software is under active development at two leading institutions and continues to be released under an open-source license at http://cpfp.sourceforge.net.
Chemically modified graphene based supercapacitors for flexible and miniature devices
NASA Astrophysics Data System (ADS)
Ghosh, Debasis; Kim, Sang Ouk
2015-09-01
Rapid progress in the portable and flexible electronic devises has stimulated supercapacitor research towards the design and fabrication of high performance flexible devices. Recent research efforts for flexible supercapacitor electrode materials are highly focusing on graphene and chemically modified graphene owing to the unique properties, including large surface area, high electrical and thermal conductivity, excellent mechanical flexibility, and outstanding chemical stability. This invited review article highlights current status of the flexible electrode material research based on chemically modified graphene for supercapacitor application. A variety of electrode architectures prepared from chemically modified graphene are summarized in terms of their structural dimensions. Novel prototypes for the supercapacitor aiming at flexible miniature devices, i.e. microsupercapacitor with high energy and power density are highlighted. Future challenges relevant to graphene-based flexible supercapacitors are also suggested. [Figure not available: see fulltext.
Dórea, José G
2010-09-01
The neurotoxic effects of fish-methylmercury (meHg) consumed regularly are considered hazardous to fetuses and newborn infants; as a result fish consumption advisories are an important asset to control meHg exposure in affluent societies. These concerns are now part of health promotion programs for Amazon subsistence villagers. While urban dwellers in affluent societies can choose an alternative nutritious diet, traditional and subsistence communities are caught up in controversial issues and lifestyle changes with unintended health consequences. Traditional fish-eating populations of industrialized and non-industrialized regions may be exposed to different neurotoxic substances: man-made pollutants and environmentally occurring meHg. Additionally, in non-industrialized countries, pregnant women and infants are still being immunized with thimerosal-containing vaccines (TCVs) which degrade to ethylmercury (etHg). Therefore, the complexity involving fish-meHg associated with wild-fish choices and Hg exposure derived from TCVs is difficult to disentangle and evaluate: are villagers able to distinguish exposure to differently hazardous chemical forms of Hg (inorganic, fish-meHg, and injected etHg)? Is it possible that instead of helping to prevent a plausible (unperceived) fish-meHg associated neurocognitive delay we may inadvertently arouse panic surrounding Hg exposure and disrupt subsistence fish-eating habits (necessary for survival) and life-saving vaccination programs (required by public health authorities)? These questions characterize the incompleteness of information related on the various chemical forms of Hg exposure and the need to convey messages that do not disrupt nutritional balance and disease prevention policies directed at Amazonian subsistence communities.
Maracahipes-Santos, L; Lenza, E; Santos, J O; Mews, H A; Oliveira, B
2017-11-01
The Cerrado Biome is considered one of the world's biodiversity hotspots because of its rich biodiversity, the high level of endemism and the increasing threat. The Cerrado is composed by a mosaic of different vegetation types, including physiognomies that vary from grasslands (campo limpo) to savannas (typical cerrado or cerrado sensu stricto) and cerrado woodlands (cerradão). However, the factors that determine the composition of the Cerrado's flora and the structure of the physiognomies that compose this biome are still poorly understood. Here, we investigate the influence of the chemical and granulometric properties of the soil and the effect of geographic distance on the occurrence and abundance of woody species in three Cerrado phytophysiognomies - cerrado woodland (cerradão), dense cerrado savanna and typical cerrado savanna - in the Cerrado-Amazon transition. We tested the hypothesis that the edaphic characteristics and geographic space determine the species composition and the structure of the woody vegetation of these three phytophysiognomies. We demonstrate that the dissimilarities in the structure and composition of the three sites were determined more by space (13% of explanation) than edaphic properties (1%), but primarily by the interaction between these two factors (26%). We conclude that, in situations where the chemical and granulometric properties of the soil are relatively homogeneous, as we found in the present study, geographic distance between sites has a greater influence than variation in the substrate's properties on modelling the occurrence and abundance of the woody plant species in the Cerrado.
Aqua-planet simulations of the formation of the South Atlantic convergence zone
NASA Technical Reports Server (NTRS)
Nieto Ferreira, Rosana; Chao, Winston C.
2013-01-01
The impact of Amazon Basin convection and cold fronts on the formation and maintenance of the South Atlantic convergence zone (SACZ) is studied using aqua-planet simulations with a general circulation model. In the model, a circular patch of warm sea-surface temperature (SST) is used to mimic the effect of the Amazon Basin on South American monsoon convection. The aqua-planet simulations were designed to study the effect of the strength and latitude of Amazon Basin convection on the formation of the SACZ. The simulations indicate that the strength of the SACZ increases as the Amazon convection intensifies and is moved away from the equator. Of the two controls studied here, the latitude of the Amazon convection exerts the strongest effect on the strength of the SACZ. An analysis of the synoptic-scale variability in the simulations shows the importance of frontal systems in the formation of the aqua-planet SACZ. Composite time series of frontal systems that occurred in the simulations show that a robust SACZ occurs when fronts penetrate into the subtropics and become stationary there as they cross eastward of the longitude of the Amazon Basin. Moisture convergence associated with these frontal systems produces rainfall not along the model SACZ region and along a large portion of the northern model Amazon Basin. Simulations in which the warm SST patch was too weak or too close to the equator did not produce frontal systems that extended into the tropics and became stationary, and did not form a SACZ. In the model, the SACZ forms as Amazon Basin convection strengthens and migrates far enough southward to allow frontal systems to penetrate into the tropics and stall over South America. This result is in agreement with observations that the SACZ tends to form after the onset of the monsoon season in the Amazon Basin.
The economic value of the climate regulation ecosystem service provided by the Amazon rainforest
NASA Astrophysics Data System (ADS)
Heil Costa, Marcos; Pires, Gabrielle; Fontes, Vitor; Brumatti, Livia
2017-04-01
The rainy Amazon climate allowed important activities to develop in the region as large rainfed agricultural lands and hydropower plants. The Amazon rainforest is an important source of moisture to the regional atmosphere and helps regulate the local climate. The replacement of forest by agricultural lands decreases the flux of water vapor into the atmosphere and changes the precipitation patterns, which may severely affect such economic activities. Assign an economic value to this ecosystem service may emphasize the significance to preserve the Amazon rainforest. In this work, we provide a first approximation of the quantification of the climate regulation ecosystem service provided by the Amazon rainforest using the marginal production method. We use climate scenarios derived from Amazon deforestation scenarios as input to crop and runoff models to assess how land use change would affect agriculture and hydropower generation. The effects of forest removal on soybean production and on cattle beef production can both be as high as US 16 per year per ha deforested, and the effects on hydropower generation can be as high as US 8 per year per ha deforested. We consider this as a conservative estimate of a permanent service provided by the rainforest. Policy makers and other Amazon agriculture and energy businesses must be aware of these numbers, and consider them while planning their activities.
NASA Astrophysics Data System (ADS)
Sakaguchi, Koichi; Zeng, Xubin; Christoffersen, Bradley J.; Restrepo-Coupe, Natalia; Saleska, Scott R.; Brando, Paulo M.
2011-03-01
Recent development of general circulation models involves biogeochemical cycles: flows of carbon and other chemical species that circulate through the Earth system. Such models are valuable tools for future projections of climate, but still bear large uncertainties in the model simulations. One of the regions with especially high uncertainty is the Amazon forest where large-scale dieback associated with the changing climate is predicted by several models. In order to better understand the capability and weakness of global-scale land-biogeochemical models in simulating a tropical ecosystem under the present day as well as significantly drier climates, we analyzed the off-line simulations for an east central Amazon forest by the Community Land Model version 3.5 of the National Center for Atmospheric Research and its three independent biogeochemical submodels (CASA', CN, and DGVM). Intense field measurements carried out under Large Scale Biosphere-Atmosphere Experiment in Amazonia, including forest response to drought from a throughfall exclusion experiment, are utilized to evaluate the whole spectrum of biogeophysical and biogeochemical aspects of the models. Our analysis shows reasonable correspondence in momentum and energy turbulent fluxes, but it highlights three processes that are not in agreement with observations: (1) inconsistent seasonality in carbon fluxes, (2) biased biomass size and allocation, and (3) overestimation of vegetation stress to short-term drought but underestimation of biomass loss from long-term drought. Without resolving these issues the modeled feedbacks from the biosphere in future climate projections would be questionable. We suggest possible directions for model improvements and also emphasize the necessity of more studies using a variety of in situ data for both driving and evaluating land-biogeochemical models.
Guarana: revisiting a highly caffeinated plant from the Amazon.
Schimpl, Flávia Camila; da Silva, José Ferreira; Gonçalves, José Francisco de Carvalho; Mazzafera, Paulo
2013-10-28
Guarana (Paullinia cupana Kunth var. sorbilis (Mart.) Ducke) has been traditionally consumed by indigenous communities of the Amazon region. It is valued mainly for its stimulant property because of its high content of caffeine, which can be up to 6% in the seeds. The purpose of this review is to revisit this typically Brazilian plant, addressing economic considerations, the chemical makeup of the seeds and pharmacological properties so far investigated. Guarana is primarily produced in the Brazilian states of Amazonas and Bahia, and approximately 70% of the production is used by the industry of soft and energy drinks. The other 30% becomes guarana powder for direct consumption in capsules or dilution in water, or it serves as a raw material for the pharmaceutical and cosmetics industries. In addition to its stimulant property, guarana has other therapeutic properties, which have aroused the interest of the scientific community. This review shows that other guarana properties may be explored and how scarce are the studies regarding agronomic, plant pathology, physiology and breeding. So far, caffeine has been the main reason to study guarana and still will lead the researches because the demand for this alkaloid by food and pharmaceutical industry, and a strongly growing market related with beauty products. However, guarana has other components and there is great interest in studies designed to elucidate the effects of guarana's bioactive components and their potential pharmacological applications. Significant part of the guarana production in Brazil still comes from Indians tribes in the Amazon State, and any improvement in this plant, in any aspect, may propitiate a positive economic impact in their lives. © 2013 Elsevier Ireland Ltd. All rights reserved.
Chemodiversity of dissolved organic matter in the Amazon Basin
NASA Astrophysics Data System (ADS)
Gonsior, Michael; Valle, Juliana; Schmitt-Kopplin, Philippe; Hertkorn, Norbert; Bastviken, David; Luek, Jenna; Harir, Mourad; Bastos, Wanderley; Enrich-Prast, Alex
2016-07-01
Regions in the Amazon Basin have been associated with specific biogeochemical processes, but a detailed chemical classification of the abundant and ubiquitous dissolved organic matter (DOM), beyond specific indicator compounds and bulk measurements, has not yet been established. We sampled water from different locations in the Negro, Madeira/Jamari and Tapajós River areas to characterize the molecular DOM composition and distribution. Ultrahigh-resolution Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) combined with excitation emission matrix (EEM) fluorescence spectroscopy and parallel factor analysis (PARAFAC) revealed a large proportion of ubiquitous DOM but also unique area-specific molecular signatures. Unique to the DOM of the Rio Negro area was the large abundance of high molecular weight, diverse hydrogen-deficient and highly oxidized molecular ions deviating from known lignin or tannin compositions, indicating substantial oxidative processing of these ultimately plant-derived polyphenols indicative of these black waters. In contrast, unique signatures in the Madeira/Jamari area were defined by presumably labile sulfur- and nitrogen-containing molecules in this white water river system. Waters from the Tapajós main stem did not show any substantial unique molecular signatures relative to those present in the Rio Madeira and Rio Negro, which implied a lower organic molecular complexity in this clear water tributary, even after mixing with the main stem of the Amazon River. Beside ubiquitous DOM at average H / C and O / C elemental ratios, a distinct and significant unique DOM pool prevailed in the black, white and clear water areas that were also highly correlated with EEM-PARAFAC components and define the frameworks for primary production and other aspects of aquatic life.
Chemically-modified cellulose paper as a microstructured catalytic reactor.
Koga, Hirotaka; Kitaoka, Takuya; Isogai, Akira
2015-01-15
We discuss the successful use of chemically-modified cellulose paper as a microstructured catalytic reactor for the production of useful chemicals. The chemical modification of cellulose paper was achieved using a silane-coupling technique. Amine-modified paper was directly used as a base catalyst for the Knoevenagel condensation reaction. Methacrylate-modified paper was used for the immobilization of lipase and then in nonaqueous transesterification processes. These catalytic paper materials offer high reaction efficiencies and have excellent practical properties. We suggest that the paper-specific interconnected microstructure with pulp fiber networks provides fast mixing of the reactants and efficient transport of the reactants to the catalytically-active sites. This concept is expected to be a promising route to green and sustainable chemistry.
Metagenomics Analysis of Microorganisms in Freshwater Lakes of the Amazon Basin.
Toyama, Danyelle; Kishi, Luciano Takeshi; Santos-Júnior, Célio Dias; Soares-Costa, Andrea; de Oliveira, Tereza Cristina Souza; de Miranda, Fernando Pellon; Henrique-Silva, Flávio
2016-12-22
The Amazon Basin is the largest hydrographic basin on the planet, and the dynamics of its aquatic microorganisms strongly impact global biogeochemical cycles. However, it remains poorly studied. This metagenome project was performed to obtain a snapshot of prokaryotic microbiota from four important lakes in the Amazon Basin. Copyright © 2016 Toyama et al.
Correlation between dynamic wetting behavior and chemical components of thermally modified wood
NASA Astrophysics Data System (ADS)
Wang, Wang; Zhu, Yuan; Cao, Jinzhen; Sun, Wenjing
2015-01-01
In order to investigate the dynamic wetting behavior of thermally modified wood, Cathay poplar (Populus cathayana Rehd.) and Scots pine (Pinus sylvestris L.) samples were thermally modified in an oven at 160, 180, 200, 220 or 240 °C for 4 h in this study. The dynamic contact angles and droplet volumes of water droplets on modified and unmodified wood surfaces were measured by sessile drop method, and their changing rates (expression index: K value and wetting slope) calculated by wetting models were illustrated for mapping the dynamic wetting process. The surface chemical components were also measured by X-ray photoelectron spectroscopy analysis (XPS), thus the relationship between dynamic wetting behavior and chemical components of thermally modified wood were determined. The results indicated that thermal modification was capable of decreasing the dynamic wettability of wood, expressed in lowing spread and penetration speed of water droplets on wood surfaces. This change was more obvious with the increased heating temperature. The K values varied linearly with the chemical components parameter (mass loss, O/C ratio, and C1/C2 ratio), indicating a strong correlation between dynamic wetting behavior and chemical components of thermally modified wood.
40 CFR 721.10533 - Amine-modified urea-formaldehyde polymer (generic).
Code of Federal Regulations, 2014 CFR
2014-07-01
... polymer (generic). 721.10533 Section 721.10533 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Specific Chemical Substances § 721.10533 Amine-modified urea-formaldehyde polymer (generic). (a) Chemical... as amine-modified urea-formaldehyde polymer (PMN P-12-182) is subject to reporting under this section...
40 CFR 721.10533 - Amine-modified urea-formaldehyde polymer (generic).
Code of Federal Regulations, 2013 CFR
2013-07-01
... polymer (generic). 721.10533 Section 721.10533 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Specific Chemical Substances § 721.10533 Amine-modified urea-formaldehyde polymer (generic). (a) Chemical... as amine-modified urea-formaldehyde polymer (PMN P-12-182) is subject to reporting under this section...
Finer, Matt; Jenkins, Clinton N; Pimm, Stuart L; Keane, Brian; Ross, Carl
2008-08-13
The western Amazon is the most biologically rich part of the Amazon basin and is home to a great diversity of indigenous ethnic groups, including some of the world's last uncontacted peoples living in voluntary isolation. Unlike the eastern Brazilian Amazon, it is still a largely intact ecosystem. Underlying this landscape are large reserves of oil and gas, many yet untapped. The growing global demand is leading to unprecedented exploration and development in the region. We synthesized information from government sources to quantify the status of oil development in the western Amazon. National governments delimit specific geographic areas or "blocks" that are zoned for hydrocarbon activities, which they may lease to state and multinational energy companies for exploration and production. About 180 oil and gas blocks now cover approximately 688,000 km(2) of the western Amazon. These blocks overlap the most species-rich part of the Amazon. We also found that many of the blocks overlap indigenous territories, both titled lands and areas utilized by peoples in voluntary isolation. In Ecuador and Peru, oil and gas blocks now cover more than two-thirds of the Amazon. In Bolivia and western Brazil, major exploration activities are set to increase rapidly. Without improved policies, the increasing scope and magnitude of planned extraction means that environmental and social impacts are likely to intensify. We review the most pressing oil- and gas-related conservation policy issues confronting the region. These include the need for regional Strategic Environmental Impact Assessments and the adoption of roadless extraction techniques. We also consider the conflicts where the blocks overlap indigenous peoples' territories.
NASA Astrophysics Data System (ADS)
Latrubesse, E. M.; Park, E.
2017-12-01
In a recent study, Latrubesse et al., (2017) demonstrated that the accumulated negative environmental effects of more than one hundred existing dams and at least 288 proposed dams, if constructed, will trigger massive hydrophysical and biotic disturbances that will affect the Amazon basin's floodplains, estuary and sediment plume. The authors introduced a Dam Environmental Vulnerability Index (DEVI) to quantify the current and potential impacts of dams in the basin. The current and potential vulnerabilities of different regions of the Amazon basin was assessed, and the results highlighted the need for a more efficient and integrative legal framework involving all nine countries of the basin in an anticipatory assessment to minimize the negative socio-environmental and biotic impacts of hydropower developments. Here we present expanded information on the potential impacts of dams in the lower Amazon and the northeast Atlantic coast of South America, and revisit our proposed integrative strategies for basin management which are based on the adaptation and functionality of the institutional and legal framework already existing in the Amazon countries. Participative strategies involving members from the Amazon Cooperation Treaty Organization (ACTO) countries, and additional members (for example, France), such as the creation of a basin committee -as defined by the Brazilian Law of Waters of Brazil-, and the creation of an Amazon Basin Panel allowing the participation of scientists that could have a policy-relevant role but should be not policy-prescriptive, are also discussed. ReferencesLatrubesse, E., Arima E. Dunne T., Park E., Baker V, Horta F.,Wight, C., Wittmann F., Zuanon, J., Baker P., Ribas C, Norgaard R., Filizola N., Ansar A., Flyvbjerg B., Stevaux, J. 2017. Damming the rivers of the Amazon basin. Nature, 546, 363-369.
Finer, Matt; Jenkins, Clinton N.; Pimm, Stuart L.; Keane, Brian; Ross, Carl
2008-01-01
Background The western Amazon is the most biologically rich part of the Amazon basin and is home to a great diversity of indigenous ethnic groups, including some of the world's last uncontacted peoples living in voluntary isolation. Unlike the eastern Brazilian Amazon, it is still a largely intact ecosystem. Underlying this landscape are large reserves of oil and gas, many yet untapped. The growing global demand is leading to unprecedented exploration and development in the region. Methodology/Principal Findings We synthesized information from government sources to quantify the status of oil development in the western Amazon. National governments delimit specific geographic areas or “blocks” that are zoned for hydrocarbon activities, which they may lease to state and multinational energy companies for exploration and production. About 180 oil and gas blocks now cover ∼688,000 km2 of the western Amazon. These blocks overlap the most species-rich part of the Amazon. We also found that many of the blocks overlap indigenous territories, both titled lands and areas utilized by peoples in voluntary isolation. In Ecuador and Peru, oil and gas blocks now cover more than two-thirds of the Amazon. In Bolivia and western Brazil, major exploration activities are set to increase rapidly. Conclusions/Significance Without improved policies, the increasing scope and magnitude of planned extraction means that environmental and social impacts are likely to intensify. We review the most pressing oil- and gas-related conservation policy issues confronting the region. These include the need for regional Strategic Environmental Impact Assessments and the adoption of roadless extraction techniques. We also consider the conflicts where the blocks overlap indigenous peoples' territories. PMID:18716679
Earth Observations taken by the Expedition 17 Crew
2008-08-19
ISS017-E-013856 (19 Aug. 2008) --- Amazon River, Brazil is featured in this image photographed by an Expedition 17 crewmember on the International Space Station. This image shows the huge sunglint zone, common to oblique views from space, of the setting sun shining off the Amazon River and numerous lakes on its floodplain. About 150 kilometers of the sinuous Amazon course is shown here, as it appears about 1,000 kilometers from the Atlantic Ocean. The Uatuma River enters on the north side of the Amazon (top). A small side channel of the very large Madeira River enters the view from the left. Tupinambarama Island occupies the swampy wetlands between the Amazon and Madeira rivers. Sunglint images reveal great detail in waterbodies -- in this case the marked difference between the smooth outline of the Amazon and the jagged shoreline of the Uatuma River. The jagged shoreline results from valley sides being eroded in relatively hard rocks. The Uatuma River has since been dammed up by the sediment mass of the Amazon floodplain. Because the Amazon flows in its own soft sediment, its huge water discharge smooths the banks. Another dammed valley (known as a ria) is visible beneath the cirrus cloud of a storm (bottom). Although no smoke plumes from forest fires are visible in the view, two kinds of evidence show that there is smoke in the atmosphere. The coppery color of the sunglint is typically produced by smoke particles and other aerosols scattering yellow and red light. Second, a small patch of cloud (top right) casts a distinct shadow. The shadow, say scientists, is visible because so many particles in the surrounding sunlit parts of the atmosphere reflect light to the camera.
Ion exchanger from chemically modified banana leaves.
El-Gendy, Ahmed A; Mohamed, Samar H; Abd-Elkader, Amal H
2013-07-25
Cation exchangers from chemically modified banana leaves have been prepared. Banana leaves were treated with different molarities of KMnO4 and cross linked with epichlorohydrin and their effect on metal ion adsorption was investigated. Phosphorylation of chemically modified banana leaves was also studied. The metal ion uptake by these modified banana leaves was clarified. Effect of different varieties, e.g. activation of produced cation exchanger, concentration of metal ions was also investigated. Characterization of the prepared ion exchangers by using infrared and thermal analysis was also taken in consideration. Copyright © 2013 Elsevier Ltd. All rights reserved.
Guèze, Maximilien; Luz, Ana Catarina; Paneque-Gálvez, Jaime; Macía, Manuel J; Orta-Martínez, Martí; Pino, Joan; Reyes-García, Victoria
2014-03-01
Researchers have argued that indigenous peoples preferably use the most apparent plant species, particularly for medicinal uses. However, the association between the ecological importance of a species and its usefulness remains unclear. In this paper we quantify such association for six use categories (firewood, construction, materials, food, medicines and other uses). We collected data on the uses of 58 tree species, as reported by 93 informants in 22 villages in the Tsimane' territory (Bolivian Amazon). We calculated the ecological importance of the same species by deriving their importance value index (IVI) in 48 0.1-ha old-growth forest plots. Matching both data sets, we found a positive relation between the IVI of a species and its overall use value (UV) as well as with its UV for construction and materials. We found a negative relation between IVI and UV for species that were reportedly used for medicine and food uses, and no clear pattern for the other categories. We hypothesize that species used for construction or crafting purposes because of their physical properties are more easily substitutable than species used for medicinal or edible purposes because of their chemical properties.
Guèze, Maximilien; Luz, Ana Catarina; Paneque-Gálvez, Jaime; Macía, Manuel J.; Orta-Martínez, Martí; Pino, Joan; Reyes-García, Victoria
2015-01-01
Researchers have argued that indigenous peoples preferably use the most apparent plant species, particularly for medicinal uses. However, the association between the ecological importance of a species and its usefulness remains unclear. In this paper we quantify such association for six use categories (firewood, construction, materials, food, medicines and other uses). We collected data on the uses of 58 tree species, as reported by 93 informants in 22 villages in the Tsimane’ territory (Bolivian Amazon). We calculated the ecological importance of the same species by deriving their importance value index (IVI) in 48 0.1-ha old-growth forest plots. Matching both data sets, we found a positive relation between the IVI of a species and its overall use value (UV) as well as with its UV for construction and materials. We found a negative relation between IVI and UV for species that were reportedly used for medicine and food uses, and no clear pattern for the other categories. We hypothesize that species used for construction or crafting purposes because of their physical properties are more easily substitutable than species used for medicinal or edible purposes because of their chemical properties. PMID:26097243
Lima, Andriele M; Gonçalves, Evonnildo C; Andrade, Soraya S; Barbosa, Maria S R; Barroso, Karla F P; de Sousa, Mayara B; Borges, Larissa; Vieira, Jozé L F; Teixeira, Francisco M
2013-03-15
One difficulty of self-sustainability is the quality assurance of native products. This research was designed to study the risks and critical control points in the collection, handling and marketing of Brazil nuts from native forests and urban fairs in the Brazilian Amazon by characterisation of morphological aspects of fungi and posterior identification by molecular biology and determination of aflatoxins by high-performance liquid chromatography. Several corrective actions to improve product quality were found to be necessary in both sites. Growth of fungi was observed in 95% of fragments of Brazil nuts from both sites during the between-harvest period. Aflatoxin levels indicated that, although fungal growth was observed in both sites, only Brazil nuts from the native forest showed a high risk to human health (total aflatoxin level of 471.69 µg kg(-1)). This study has shown the main issues related to the process design of Brazil nuts, supporting the necessity for research on new strategies to improve the quality of nuts. Also, the habit of eating Brazil nuts stored throughout the year may represent a risk to farmers. © 2012 Society of Chemical Industry.
Maruenda, Helena; Vico, Maria del Lujan; Householder, J Ethan; Janovec, John P; Cañari, Cristhian; Naka, Angelica; Gonzalez, Ana E
2013-05-01
This study provides the first chemical investigation of wild-harvested fruits of Vanilla pompona ssp. grandiflora (Lindl.) Soto-Arenas developed in their natural habitat in the Peruvian Amazon. Flowers were hand-pollinated and the resulting fruits were analysed at different developmental stages using an HPLC-DAD method validated for the quantification of glucovanillin and seven other compounds. The method showed satisfactory linearity (r(2)>0.9969), precision (coefficient of variation <2%), recoveries (70-100%), limit of detection (0.008-0.212 μg/ml), and limit of quantification (0.027-0.707 μg/ml). The evaluation of crude and enzyme-hydrolyzed Soxhlet-extracted samples confirmed the leading role of glucosides in fruit development. LC-ESI-MS studies corroborated the identities of four glucosides and seven aglycones, among them vanillin (5.7/100 g), 4-hydroxybenzyl alcohol (3.6/100 g), and anisyl alcohol (7.1/100 g) were found in high concentrations. The attractive flavor/aroma profile exhibited by wild V. pompona fruits supports studies focused on the development of this species as a specialty crop. Copyright © 2012 Elsevier Ltd. All rights reserved.
The Climate Effects of Deforestation the Amazon Rainforest under Global Warming Conditions
NASA Astrophysics Data System (ADS)
Werth, D.; Avissar, R.
2006-12-01
Replacement of tropical rainforests has been observed to have a strong drying effect in Amazon simulations, with effects reaching high into the atmospheric column and into the midlatitudes. The drying effects of deforestation, however, can be moderated by the effects of global warming, which should accelerate the hydrologic cycle of the Amazon. The effects of a prescribed, time-varying Amazon deforestation done in conjunction with a steady, moderate increase in CO2 concentrations are determined using a climate model. The model agrees with previous studies when each forcing is applied individually - compared to a control run, Amazon deforestation decreases the local precipitation and global warming increases it. When both are applied, however, the precipitation and other hydrologic variables decrease, but to a lesser extent than when deforestation alone was applied. In effect, the two effects act opposite to one another and bring the simulated climate closer to that of the control.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Woodhead, A.D.; Setlow, R.B.; Hart, R.W.
1977-01-01
It is suggested that the viviparous teleost, Poecilia formosa, (Amazon molly) may have wide potential use for aquatic radiation studies. The Amazon molly is a naturally occurring gynogenetic species, in which the eggs are activated after mating with the males of closely related species, without the subsequent genetic contribution from the male. The offspring of a single original female constitute a clone, having identical genotypes. Clones of the genetically homogeneous Amazon molly may prove to be equally as valuable to aquatic radiobiologists as the inbred rodent lines have been to mammalian studies. In many other respects the Amazon molly ismore » a satisfactory laboratory animal. It is robust, easy to rear, and has large broods of young when fully grown. Maintenance costs are low. Details are given of the conditions under which colonies reproduce.« less
Introduction: Observations and modeling of the Green Ocean Amazon (GoAmazon2014/5)
DOE Office of Scientific and Technical Information (OSTI.GOV)
Martin, S. T.; Artaxo, P.; Machado, L. A. T.
The Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5) Experiment was carried out in the environs of Manaus, Brazil, in the central region of the Amazon basin for 2 years from 1 January 2014 through 31 December 2015. The experiment focused on the complex interactions among vegetation, atmospheric chemistry, and aerosol production on the one hand and their connections to aerosols, clouds, and precipitation on the other. The objective was to understand and quantify these linked processes, first under natural conditions to obtain a baseline and second when altered by the effects of human activities. To this end, the pollution plume from themore » Manaus metropolis, superimposed on the background conditions of the central Amazon basin, served as a natural laboratory. The present paper, as the introduction to the special issue of GoAmazon2014/5, presents the context and motivation of the GoAmazon2014/5 Experiment. The nine research sites, including the characteristics and instrumentation of each site, are presented. The sites range from time point zero (T0) upwind of the pollution, to T1 in the midst of the pollution, to T2 just downwind of the pollution, to T3 furthest downwind of the pollution (70 km). In addition to the ground sites, a low-altitude G-159 Gulfstream I (G-1) observed the atmospheric boundary layer and low clouds, and a high-altitude Gulfstream G550 (HALO) operated in the free troposphere. During the 2-year experiment, two Intensive Operating Periods (IOP1 and IOP2) also took place that included additional specialized research instrumentation at the ground sites as well as flights of the two aircraft. GoAmazon2014/5 IOP1 was carried out from 1 February to 31 March 2014 in the wet season. GoAmazon2014/5 IOP2 was conducted from 15 August to 15 October 2014 in the dry season. In addition, the G-1 aircraft flew during both IOP1 and IOP2, and the HALO aircraft flew during IOP2. In the context of the Amazon basin, the two IOPs also correspond to the clean and biomass burning seasons, respectively. The Manaus plume is present year-round, and it is transported by prevailing northeasterly and easterly winds in the wet and dry seasons, respectively. This introduction also organizes information relevant to many papers in the special issue. Information is provided on the vehicle fleet, power plants, and industrial activities of Manaus. The mesoscale and synoptic meteorologies relevant to the two IOPs are presented. Regional and long-range transport of emissions during the two IOPs is discussed based on satellite observations across South America and Africa. Fire locations throughout the airshed are detailed. In conjunction with the context and motivation of GoAmazon2014/5 as presented in this introduction, research articles including thematic overview articles are anticipated in this special issue to describe the detailed results and findings of the GoAmazon2014/5 Experiment.« less
Introduction: Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5)
NASA Astrophysics Data System (ADS)
Martin, S. T.; Artaxo, P.; Machado, L. A. T.; Manzi, A. O.; Souza, R. A. F.; Schumacher, C.; Wang, J.; Andreae, M. O.; Barbosa, H. M. J.; Fan, J.; Fisch, G.; Goldstein, A. H.; Guenther, A.; Jimenez, J. L.; Pöschl, U.; Silva Dias, M. A.; Smith, J. N.; Wendisch, M.
2015-11-01
The Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5) Experiment was carried out in the environs of Manaus, Brazil, in the central region of the Amazon basin during two years from 1 January 2014 through 31 December 2015. The experiment focused on the complex interactions among vegetation, atmospheric chemistry, and aerosol production on the one hand and their connections to aerosols, clouds, and precipitation on the other. The objective was to understand and quantify these linked processes, first under natural conditions to obtain a baseline and second when altered by the effects of human activities. To this end, the pollution plume from the Manaus metropolis, superimposed on the background conditions of the central Amazon basin, served as a natural laboratory. The present paper, as the Introduction to the GoAmazon2014/5 Special Issue, presents the context and motivation of the GoAmazon2014/5 Experiment. The nine research sites, including the characteristics and instrumentation of each site, are presented. The sites range from time point zero (T0) upwind of the pollution, to T1 in the midst of the pollution, to T2 just downwind of the pollution, to T3 furthest downwind of the pollution (70 km). In addition to the ground sites, a low-altitude G-159 Gulfstream I (G1) observed the atmospheric boundary layer and low clouds, and a high-altitude Gulfstream G550 (HALO) operated in the free troposphere. During the two-year experiment, two Intensive Operating Periods (IOP1 and IOP2) also took place that included additional specialized research instrumentation at the ground sites as well as flights of the two aircraft. GoAmazon2014/5 IOP1 was carried out from 1 February to 31 March 2014 in the wet season. GoAmazon2014/5 IOP2 was conducted from 15 August to 15 October 2014 in the dry season. The G1 aircraft flew during both IOP1 and IOP2, and the HALO aircraft flew during IOP2. In the context of the Amazon basin, the two IOPs also correspond to the clean and biomass burning seasons, respectively. The Manaus plume is present year round, and it is transported by prevailing northeasterly and easterly winds in the wet and dry seasons, respectively. This Introduction also organizes information relevant to many papers in the Special Issue. Information is provided on the vehicle fleet, power plants, and industrial activities of Manaus. The mesoscale and synoptic meteorologies relevant to the two IOPs are presented. Regional and long-range transport of emissions during the two IOPs is discussed based on satellite observations across South America and Africa. Fire locations throughout the airshed are detailed. In conjunction with the context and motivation of GoAmazon2014/5, as presented herein in this Introduction, research articles published in this Special Issue are anticipated in the near future to describe the detailed results and findings of the GoAmazon2014/5 Experiment.
Introduction: Observations and modeling of the Green Ocean Amazon (GoAmazon2014/5)
Martin, S. T.; Artaxo, P.; Machado, L. A. T.; ...
2016-04-19
The Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5) Experiment was carried out in the environs of Manaus, Brazil, in the central region of the Amazon basin for 2 years from 1 January 2014 through 31 December 2015. The experiment focused on the complex interactions among vegetation, atmospheric chemistry, and aerosol production on the one hand and their connections to aerosols, clouds, and precipitation on the other. The objective was to understand and quantify these linked processes, first under natural conditions to obtain a baseline and second when altered by the effects of human activities. To this end, the pollution plume from themore » Manaus metropolis, superimposed on the background conditions of the central Amazon basin, served as a natural laboratory. The present paper, as the introduction to the special issue of GoAmazon2014/5, presents the context and motivation of the GoAmazon2014/5 Experiment. The nine research sites, including the characteristics and instrumentation of each site, are presented. The sites range from time point zero (T0) upwind of the pollution, to T1 in the midst of the pollution, to T2 just downwind of the pollution, to T3 furthest downwind of the pollution (70 km). In addition to the ground sites, a low-altitude G-159 Gulfstream I (G-1) observed the atmospheric boundary layer and low clouds, and a high-altitude Gulfstream G550 (HALO) operated in the free troposphere. During the 2-year experiment, two Intensive Operating Periods (IOP1 and IOP2) also took place that included additional specialized research instrumentation at the ground sites as well as flights of the two aircraft. GoAmazon2014/5 IOP1 was carried out from 1 February to 31 March 2014 in the wet season. GoAmazon2014/5 IOP2 was conducted from 15 August to 15 October 2014 in the dry season. In addition, the G-1 aircraft flew during both IOP1 and IOP2, and the HALO aircraft flew during IOP2. In the context of the Amazon basin, the two IOPs also correspond to the clean and biomass burning seasons, respectively. The Manaus plume is present year-round, and it is transported by prevailing northeasterly and easterly winds in the wet and dry seasons, respectively. This introduction also organizes information relevant to many papers in the special issue. Information is provided on the vehicle fleet, power plants, and industrial activities of Manaus. The mesoscale and synoptic meteorologies relevant to the two IOPs are presented. Regional and long-range transport of emissions during the two IOPs is discussed based on satellite observations across South America and Africa. Fire locations throughout the airshed are detailed. In conjunction with the context and motivation of GoAmazon2014/5 as presented in this introduction, research articles including thematic overview articles are anticipated in this special issue to describe the detailed results and findings of the GoAmazon2014/5 Experiment.« less
ERIC Educational Resources Information Center
Galeano, Rebecca
2013-01-01
Despite international attention and attempts to preserve the environmental diversity of the Amazon, it is an accepted fact that those who inhabit the forest must be the ones who preserve it. This article presents an analysis of how children in small rural riverine communities along the Amazon understand the importance of environmental preservation…
Comparative Phylogeography of Neotropical Birds
2009-05-01
of lowland Neotropical rainforest birds that have populations isolated on either side of the Andes, Amazon River, and Madeira River. I found widely...Unlike canopy species, understory birds were structured at smaller spatial scales, particularly across riverine barriers of the Amazon basin...expansive complementary forest of the Amazon Basin. This divide is relatively young as the northern Andes were only half their present elevation
NASA Technical Reports Server (NTRS)
Dejesusparada, N. (Principal Investigator); Tardin, A. T.; Dossantos, A. P.; Lee, D. C. L.; Soaresmaia, F. C.; Mendonca, F. J.; Assuncao, G. V.; Rodrigues, J. E.; Demouraabdon, M.; Novaes, R. A.
1979-01-01
LANDSAT imagery was used to determine the amount of deforestation in a study area comprising 55 million hectares of the Amazon region. Results show that more than 4 million hectares were deforested. Maps and pictures of the deforested area in relation to the total area of the Amazon are included.
The SE US and the Amazon have large sources of biogenic VOCs, varying anthropogenic pollution impacts, and often poor organic aerosol (OA) model performance. Recent results on the sources, properties, aging, and impact of anthropogenic pollution on OA and secondary OA (SOA) over ...
Damming the rivers of the Amazon basin
NASA Astrophysics Data System (ADS)
Latrubesse, Edgardo M.; Arima, Eugenio Y.; Dunne, Thomas; Park, Edward; Baker, Victor R.; D'Horta, Fernando M.; Wight, Charles; Wittmann, Florian; Zuanon, Jansen; Baker, Paul A.; Ribas, Camila C.; Norgaard, Richard B.; Filizola, Naziano; Ansar, Atif; Flyvbjerg, Bent; Stevaux, Jose C.
2017-06-01
More than a hundred hydropower dams have already been built in the Amazon basin and numerous proposals for further dam constructions are under consideration. The accumulated negative environmental effects of existing dams and proposed dams, if constructed, will trigger massive hydrophysical and biotic disturbances that will affect the Amazon basin’s floodplains, estuary and sediment plume. We introduce a Dam Environmental Vulnerability Index to quantify the current and potential impacts of dams in the basin. The scale of foreseeable environmental degradation indicates the need for collective action among nations and states to avoid cumulative, far-reaching impacts. We suggest institutional innovations to assess and avoid the likely impoverishment of Amazon rivers.
Damming the rivers of the Amazon basin.
Latrubesse, Edgardo M; Arima, Eugenio Y; Dunne, Thomas; Park, Edward; Baker, Victor R; d'Horta, Fernando M; Wight, Charles; Wittmann, Florian; Zuanon, Jansen; Baker, Paul A; Ribas, Camila C; Norgaard, Richard B; Filizola, Naziano; Ansar, Atif; Flyvbjerg, Bent; Stevaux, Jose C
2017-06-14
More than a hundred hydropower dams have already been built in the Amazon basin and numerous proposals for further dam constructions are under consideration. The accumulated negative environmental effects of existing dams and proposed dams, if constructed, will trigger massive hydrophysical and biotic disturbances that will affect the Amazon basin's floodplains, estuary and sediment plume. We introduce a Dam Environmental Vulnerability Index to quantify the current and potential impacts of dams in the basin. The scale of foreseeable environmental degradation indicates the need for collective action among nations and states to avoid cumulative, far-reaching impacts. We suggest institutional innovations to assess and avoid the likely impoverishment of Amazon rivers.
Modelling conservation in the Amazon basin.
Soares-Filho, Britaldo Silveira; Nepstad, Daniel Curtis; Curran, Lisa M; Cerqueira, Gustavo Coutinho; Garcia, Ricardo Alexandrino; Ramos, Claudia Azevedo; Voll, Eliane; McDonald, Alice; Lefebvre, Paul; Schlesinger, Peter
2006-03-23
Expansion of the cattle and soy industries in the Amazon basin has increased deforestation rates and will soon push all-weather highways into the region's core. In the face of this growing pressure, a comprehensive conservation strategy for the Amazon basin should protect its watersheds, the full range of species and ecosystem diversity, and the stability of regional climates. Here we report that protected areas in the Amazon basin--the central feature of prevailing conservation approaches--are an important but insufficient component of this strategy, based on policy-sensitive simulations of future deforestation. By 2050, current trends in agricultural expansion will eliminate a total of 40% of Amazon forests, including at least two-thirds of the forest cover of six major watersheds and 12 ecoregions, releasing 32 +/- 8 Pg of carbon to the atmosphere. One-quarter of the 382 mammalian species examined will lose more than 40% of the forest within their Amazon ranges. Although an expanded and enforced network of protected areas could avoid as much as one-third of this projected forest loss, conservation on private lands is also essential. Expanding market pressures for sound land management and prevention of forest clearing on lands unsuitable for agriculture are critical ingredients of a strategy for comprehensive conservation.
Hydrologic resilience and Amazon productivity.
Ahlström, Anders; Canadell, Josep G; Schurgers, Guy; Wu, Minchao; Berry, Joseph A; Guan, Kaiyu; Jackson, Robert B
2017-08-30
The Amazon rainforest is disproportionately important for global carbon storage and biodiversity. The system couples the atmosphere and land, with moist forest that depends on convection to sustain gross primary productivity and growth. Earth system models that estimate future climate and vegetation show little agreement in Amazon simulations. Here we show that biases in internally generated climate, primarily precipitation, explain most of the uncertainty in Earth system model results; models, empirical data and theory converge when precipitation biases are accounted for. Gross primary productivity, above-ground biomass and tree cover align on a hydrological relationship with a breakpoint at ~2000 mm annual precipitation, where the system transitions between water and radiation limitation of evapotranspiration. The breakpoint appears to be fairly stable in the future, suggesting resilience of the Amazon to climate change. Changes in precipitation and land use are therefore more likely to govern biomass and vegetation structure in Amazonia.Earth system model simulations of future climate in the Amazon show little agreement. Here, the authors show that biases in internally generated climate explain most of this uncertainty and that the balance between water-saturated and water-limited evapotranspiration controls the Amazon resilience to climate change.
Carbon Emissions from Deforestation in the Brazilian Amazon Region
NASA Technical Reports Server (NTRS)
Potter, C.; Klooster, S.; Genovese, V.
2009-01-01
A simulation model based on satellite observations of monthly vegetation greenness from the Moderate Resolution Imaging Spectroradiometer (MODIS) was used to estimate monthly carbon fluxes in terrestrial ecosystems of Brazilian Amazon and Cerrado regions over the period 2000-2002. The NASA-CASA (Carnegie Ames Stanford Approach) model estimates of annual forest production were used for the first time as the basis to generate a prediction for the standing pool of carbon in above-ground biomass (AGB; gC/sq m) for forested areas of the Brazilian Amazon region. Plot-level measurements of the residence time of carbon in wood in Amazon forest from Malhi et al. (2006) were interpolated by inverse distance weighting algorithms and used with CASA to generate a new regional map of AGB. Data from the Brazilian PRODES (Estimativa do Desflorestamento da Amazonia) project were used to map deforested areas. Results show that net primary production (NPP) sinks for carbon varied between 4.25 Pg C/yr (1 Pg=10(exp 15)g) and 4.34 Pg C for the region and were highest across the eastern and northern Amazon areas, whereas deforestation sources of CO2 flux from decomposition of residual woody debris were higher and less seasonal in the central Amazon than in the eastern and southern areas. Increased woody debris from past deforestation events was predicted to alter the net ecosystem carbon balance of the Amazon region to generate annual CO2 source fluxes at least two times higher than previously predicted by CASA modeling studies. Variations in climate, land cover, and forest burning were predicted to release carbon at rates of 0.5 to 1 Pg C/yr from the Brazilian Amazon. When direct deforestation emissions of CO2 from forest burning of between 0.2 and 0.6 Pg C/yr in the Legal Amazon are overlooked in regional budgets, the year-to-year variations in this net biome flux may appear to be large, whereas our model results implies net biome fluxes had actually been relatively consistent from year to year during the period 2000-2002. This is the first study to use MODIS data to model all carbon pools (wood, leaf, root) dynamically in simulations of Amazon forest deforestation from clearing and burning of all kinds.
Biomass burning in the Amazon-fertilizer for the mountaineous rain forest in Ecuador.
Fabian, Peter; Kohlpaintner, Michael; Rollenbeck, Ruetger
2005-09-01
Biomass burning is a source of carbon, sulfur and nitrogen compounds which, along with their photochemically generated reaction products, can be transported over very long distances, even traversing oceans. Chemical analyses of rain and fogwater samples collected in the mountaineous rain forest of south Ecuador show frequent episodes of high sulfate and nitrate concentration, from which annual deposition rates are derived comparable to those found in polluted central Europe. As significant anthropogenic sources are lacking at the research site it is suspected that biomass burning upwind in the Amazon basin is the major source of the enhanced sulfate and nitrate imput. Regular rain and fogwater sampling along an altitude profile between 1800 and 3185 m has been carried out in the Podocarpus National Park close to the Rio SanFrancisco (3 degrees 58'S, 79 degrees 5'W) in southern Ecuador. pH values, electrical conductivity and chemical ion composition were measured at the TUM-WZW using standard methods. Results reported cover over one year from March 2002 until May 2003. Annual deposition rates of sulfate were calculated ranging between 4 and 13 kg S/ha year, almost as high as in polluted central Europe. Nitrogen deposition via ammonia (1.5-4.4 kg N/ha year) and nitrate (0.5-0.8 kg N/ha year) was found to be lower but still much higher than to be expected in such pristine natural forest environment. By means of back trajectory analyses it can be shown that most of the enhanced sulfur and nitrogen deposition is most likely due to forest fires far upwind of the ecuadorian sampling site, showing a seasonal variation, with sources predominantly found in the East/North East during January-March (Colombia, Venezuala, Northern Brazil) and East/SouthEast during July-September (Peru, Brazil). Our results show that biomass burning in the Amazon basin is the predominant source of sulfur and nitrogen compounds that fertilize the mountaineous rain forest in south Ecuador. The mountaineous rain forest in south Ecuador has developed on poor and acid soils, with low nutrient availability. The additional ferilization resulting from anthropogenic biomass burning constitutes a significant disturbance of this ecosystem, its functioning and biodiversity. Thus it is planned to employ isotope analyses for quantifying the pathways. of nitrate and sulfate deposition in these natural forests.
de Souza, Eleane M C; da Silva, Ellon L; Marinho, Andrey M R; Marinho, Patrícia S B
2016-03-01
The present work reports the isolation of eight compounds fromPestalotiopsis sp. EJC07 isolated as endophytic fromBauhinia guianensis, a tipical plant of the Amazon. The compounds (4S)-4,8-dihydroxy-1-tetralone (1), uracil (2), uridin (3), p-hydroxybenzoic acid (4), ergosterol (5), ergosterol peroxide (6), cerevisterol (7) and ducitol (8) were isolated by chromatographic procedures and identified by spectral methods of 1D and 2D NMR and MS. The compound 1 is being reported for the first time in the genusPestalotiopsis.
Shifts in the Budyko curve over the past decade in the Amazon basin
NASA Astrophysics Data System (ADS)
Maeda, E. E.; Ma, X.; Liu, Y.; Huete, A. R.
2017-12-01
The Amazon basin has experienced extensive forest loss during the past decades. These changes can exert significant impact on regional water and energy budget, as well as other environmental processes. Here we evaluated how forest loss in the Madeira and Tapajós River basins, between 2002 and 2015, affected the Budyko relationship. The Budyko framework describes the links between climate and hydrological components, where evapotranspiration (ET) is limited by the supply of either water or energy. The framework is composed by two components, the dryness index (DI) and the evaporative index (EI). The DI determines the type and degree of limitation, with values lower than 1 represent energy-limited condition and values higher than 1, water-limited. The EI describes the partitioning of rainfall (P) into ET and runoff (R), with higher values indicating a larger proportion of ET. In this study, we use a modified version of the Budyko framework, which accounts for intra-annual changes in water storage (dS). Hence, the effective rainfall is represented by P-dS, so that EI=ET/(P-dS) and the DI= PET/(P-dS). We show that the Madeira and Tapajós River basins have lost approximately 60000 km2 and 50000km2 of forested area by 2015, respectively. Our results indicate that these changes caused a subtle shift in the Budyko curve in both basins. At the Madeira basin, a reduction in the DI indicate a shift towards lower water limitation, while decreasing EI indicate that a higher proportion of P is being converted into runoff. At the Tapajós basin, we also observe an overall decrease in the DI, but no significant trends in the evaporative index was observed. We expect that the observed shifts provide a new insight on the Amazon forest responses to changes in climate and land use. Further studies will focus in identifying the biophysical mechanisms driving these shifts, as well as seasonal aspects of the changes.
Chemical and Biological Tools for the Preparation of Modified Histone Proteins
Howard, Cecil J.; Yu, Ruixuan R.; Gardner, Miranda L.; Shimko, John C.; Ottesen, Jennifer J.
2016-01-01
Eukaryotic chromatin is a complex and dynamic system in which the DNA double helix is organized and protected by interactions with histone proteins. This system is regulated through, a large network of dynamic post-translational modifications (PTMs) exists to ensure proper gene transcription, DNA repair, and other processes involving DNA. Homogenous protein samples with precisely characterized modification sites are necessary to better understand the functions of modified histone proteins. Here, we discuss sets of chemical and biological tools that have been developed for the preparation of modified histones, with a focus on the appropriate choice of tool for a given target. We start with genetic approaches for the creation of modified histones, including the incorporation of genetic mimics of histone modifications, chemical installation of modification analogs, and the use of the expanded genetic code to incorporate modified amino acids. Additionally, we will cover the chemical ligation techniques that have been invaluable in the generation of complex modified histones that are indistinguishable from the natural counterparts. Finally, we will end with a prospectus on future directions of synthetic chromatin in living systems. PMID:25863817
Modified Surface Having Low Adhesion Properties to Mitigate Insect Residue Adhesion
NASA Technical Reports Server (NTRS)
Wohl, Christopher J., Jr. (Inventor); Smith, Joseph G., Jr. (Inventor); Siochi, Emilie J. (Inventor); Penner, Ronald K. (Inventor)
2016-01-01
A process to modify a surface to provide reduced adhesion surface properties to mitigate insect residue adhesion. The surface may include the surface of an article including an aircraft, an automobile, a marine vessel, all-terrain vehicle, wind turbine, helmet, etc. The process includes topographically and chemically modifying the surface by applying a coating comprising a particulate matter, or by applying a coating and also topographically modifying the surface by various methods, including but not limited to, lithographic patterning, laser ablation and chemical etching, physical vapor phase deposition, chemical vapor phase deposition, crystal growth, electrochemical deposition, spin casting, and film casting.
Mouths of the Amazon River, Brazil, South America
1992-08-08
STS046-80-009 (31 July-8 Aug. 1992) --- A view of the mouth of the Amazon River and the Amazon Delta shows a large sediment plume expanding outward into the Atlantic Ocean. The sediment plume can be seen hugging the coast north of the Delta. This is caused by the west-northwest flowing Guyana Current. The large island of Marajo is partially visible through the clouds.
The dispersal of the Amazon's water
NASA Technical Reports Server (NTRS)
Muller-Karger, Frank E.; Mcclain, Charles R.; Richardson, Philip L.
1988-01-01
New information obtained with NASA's Coastal Zone Color Scanner and with drifting buoys reveals that the discharge of the Amazon is carried offshore around a retroflection of the North Brazil Current and into the North Equatorial Countercurrent towards Africa between June and January each year. From about February to May, the countercurrent and the retroflection weaken or vanish, and Amazon water flows northwestward toward the Caribbean Sea.
Atmospheric correction analysis on LANDSAT data over the Amazon region. [Manaus, Brazil
NASA Technical Reports Server (NTRS)
Parada, N. D. J. (Principal Investigator); Dias, L. A. V.; Dossantos, J. R.; Formaggio, A. R.
1983-01-01
The Amazon Region natural resources were studied in two ways and compared. A LANDSAT scene and its attributes were selected, and a maximum likelihood classification was made. The scene was atmospherically corrected, taking into account Amazonic peculiarities revealed by (ground truth) of the same area, and the subsequent classification. Comparison shows that the classification improves with the atmospherically corrected images.
Michael Palace; Michael Keller; Gregory P. Asner; Stephen Hagen; Bobby Braswell
2008-01-01
We developed an automated tree crown analysis algorithm using 1-m panchromatic IKONOS satellite images to examine forest canopy structure in the Brazilian Amazon. The algorithm was calibrated on the landscape level with tree geometry and forest stand data at the Fazenda Cauaxi (3.75◦ S, 48.37◦ W) in the eastern Amazon, and then compared with forest...
Amazon Surveillance System (SIVAM): U.S. and Brazilian Cooperation
1999-12-01
Controle de Träfe go Aereo) Clutter Effects Model Parliamentary Investigation Commission (Comissäo Parlamentär de Inqutrito) Weather Forecasting...de Pesquisas Espaciais) INPA National Institute of Amazon Research (Instituto Nacional de Pesquisas da Amazonia ) IR Infrared KW Kilowatt (a...VSAT System for Surveillance of the Amazon (Sistema de Vigiläncia da Amazonia ) Brazilian Intelligence Agency (Subsecretaria de Inteligencia
Isolation of high-quality total RNA from leaves of Myrciaria dubia "CAMU CAMU".
Gómez, Juan Carlos Castro; Reátegui, Alina Del Carmen Egoavil; Flores, Julián Torres; Saavedra, Roberson Ramírez; Ruiz, Marianela Cobos; Correa, Sixto Alfredo Imán
2013-01-01
Myrciaria dubia is a main source of vitamin C for people in the Amazon region. Molecular studies of M. dubia require high-quality total RNA from different tissues. So far, no protocols have been reported for total RNA isolation from leaves of this species. The objective of this research was to develop protocols for extracting high-quality total RNA from leaves of M. dubia. Total RNA was purified following two modified protocols developed for leaves of other species (by Zeng and Yang, and by Reid et al.) and one modified protocol developed for fruits of the studied species (by Silva). Quantity and quality of purified total RNA were assessed by spectrophotometric and electrophoretic analysis. Additionally, quality of total RNA was evaluated with reverse-transcription polymerase chain reaction (RT-PCR). With these three modified protocols we were able to isolate high-quality RNA (A260nm/A280nm >1.9 and A260nm/A230nm >2.0). Highest yield was produced with the Zeng and Yang modified protocol (384±46µg ARN/g fresh weight). Furthermore, electrophoretic analysis showed the integrity of isolated RNA and the absence of DNA. Another proof of the high quality of our purified RNA was the successful cDNA synthesis and amplification of a segment of the M. dubia actin 1 gene. We report three modified protocols for isolation total RNA from leaves of M. dubia. The modified protocols are easy, rapid, low in cost, and effective for high-quality and quantity total RNA isolation suitable for cDNA synthesis and polymerase chain reaction.
Chemical modification of citrus pectin: Structural, physical and rheologial implications.
Fracasso, Aline Francielle; Perussello, Camila Augusto; Carpiné, Danielle; Petkowicz, Carmen Lúcia de Oliveira; Haminiuk, Charles Windson Isidoro
2018-04-01
The present study aimed to investigate the physical, structural and rheological modifications caused by the chemical modification process of citrus pectin. Therefore, three commercial citrus pectins with different degree of esterification were chemically modified by sequential alkali and acidic hydrolytic process to produce modified citrus pectins (MCP) with special properties. The molar mass (M w ), degree of esterification (DE), monosaccharide composition, 13 C NMR spectra, homogeneity, morphology (SEM) and rheological behavior of both native and modified citrus pectins (MCP) were investigated. The chemical modification reduced the acid uronic content (up to 28.3%) and molar mass (up to 29.98%), however, showed little influence on the degree of esterification of native pectins. Modified citrus pectins presented higher amounts of neutral monosaccharides, mainly galactose, arabinose and rhamnose, typical of the Ramnogalacturonana-I (RG-I) region. Rheological tests indicated that the native and modified citrus pectins presented pseudoplastic behavior, however, the MCP samples were less viscous, compared to the native ones. Modified samples presented better dissolution in water and less strong gels, with good stability during oscillatory shearing at 25°C. This study aims to better understand the implications that chemical modifications may impose on the structure of citrus pectins. Copyright © 2017 Elsevier B.V. All rights reserved.
Tinbergen, Jan; Wilts, Bodo D; Stavenga, Doekele G
2013-12-01
The feathers of Amazon parrots are brightly coloured. They contain a unique class of pigments, the psittacofulvins, deposited in both barbs and barbules, causing yellow or red coloured feathers. In specific feather areas, spongy nanostructured barb cells exist, reflecting either in the blue or blue-green wavelength range. The blue-green spongy structures are partly enveloped by a blue-absorbing, yellow-colouring pigment acting as a spectral filter, thus yielding a green coloured barb. Applying reflection and transmission spectroscopy, we characterized the Amazons' pigments and spongy structures, and investigated how they contribute to the feather coloration. The reflectance spectra of Amazon feathers are presumably tuned to the sensitivity spectra of the visual photoreceptors.
Boundary layer ozone - An airborne survey above the Amazon Basin
NASA Technical Reports Server (NTRS)
Gregory, Gerald L.; Browell, Edward V.; Warren, Linda S.
1988-01-01
Ozone data obtained over the forest canopy of the Amazon Basin during July and August 1985 in the course of NASA's Amazon Boundary Layer Experiment 2A are discussed, and ozone profiles obtained during flights from Belem to Tabatinga, Brazil, are analyzed to determine any cross-basin effects. The analyses of ozone data indicate that the mixed layer of the Amazon Basin, for the conditions of undisturbed meteorology and in the absence of biomass burning, is a significant sink for tropospheric ozone. As the coast is approached, marine influences are noted at about 300 km inland, and a transition from a forest-controlled mixed layer to a marine-controlled mixed layer is noted.
Ribeiro Castro, Mariane Albuquerque Lima; de Souza Castro, Gabriela Vieira; de Souza, Janis Lunier; de Souza, Cláudio Rodrigues; Ramos, Leandro José; de Oliveira, Jader; da Rosa, João Aristeu; Aranha Camargo, Luis Marcelo; Meneguetti, Dionatas Ulises de Oliveira
2018-06-01
This article reports, for the first time, the occurrence of Panstrongylus megistus in the Brazilian Western Amazon. Specimens of P. megistus were collected in the cities of Rio Branco, Acre and Extrema, Rondônia. The number of triatomine species in the State of Acre increased from eight to nine and in Rondônia from seven to eight. This was also the first report of P. megistus in the Brazilian Western Amazon. The occurrence of P. megistus in the Western Amazon evidences an epidemiological alert, since it is an important vector of T. cruzi. Copyright © 2018 Elsevier B.V. All rights reserved.
Lipid Panel Reference Intervals for Amazon Parrots (Amazona species).
Ravich, Michelle; Cray, Carolyn; Hess, Laurie; Arheart, Kristopher L
2014-09-01
The lipoprotein panel is a useful diagnostic tool that allows clinicians to evaluate blood lipoprotein fractions. It is a standard diagnostic test in human medicine but is poorly understood in avian medicine. Amazon parrots (Amazona species) are popular pets that frequently lead a sedentary lifestyle and are customarily fed high-fat diets. Similar to people with comparable diets and lifestyles, Amazon parrots are prone to obesity and atherosclerosis. In human medicine, these conditions are typically correlated with abnormalities in the lipoprotein panel. To establish reference intervals for the lipoprotein panel in Amazon parrots, plasma samples from 31 captive Amazon parrots were analyzed for concentrations of cholesterol, triglycerides, high-density lipoprotein (HDL), low-density lipoprotein (LDL), and very low-density lipoprotein (VLDL). The data were also grouped according to sex, diet, body condition score, and age. Aside from HDL levels, which were significantly different between male and female parrots, no intergroup differences were found for any of the lipoprotein fractions.
NASA Astrophysics Data System (ADS)
Fernandes, Katia; Giannini, Alessandra; Verchot, Louis; Baethgen, Walter; Pinedo-Vasquez, Miguel
2015-08-01
The unusual severity and return time of the 2005 and 2010 dry-season droughts in western Amazon is attributed partly to decadal climate fluctuations and a modest drying trend. Decadal variability of western Amazon hydroclimate is highly correlated to the Atlantic sea surface temperature (SST) north-south gradient (NSG). Shifts of dry and wet events frequencies are also related to the NSG phase, with a 66% chance of 3+ years of dry events per decade when NSG > 0 and 19% when NSG < 0. The western Amazon and NSG decadal covariability is well reproduced in general circulation models (GCMs) historical (HIST) and preindustrial control (PIC) experiments of the Coupled Model Intercomparison Project Phase 5 (CMIP5). The HIST and PIC also reproduce the shifts in dry and wet events probabilities, indicating potential for decadal predictability based on GCMs. Persistence of the current NSG positive phase favors above normal frequency of western Amazon dry events in coming decades.
Backwater effects in the Amazon River basin of Brazil
Meade, R.H.; Rayol, J.M.; Da Conceicao, S.C.; Natividade, J.R.G.
1991-01-01
The Amazon River mainstem of Brazil is so regulated by differences in the timing of tributary inputs and by seasonal storage of water on floodplains that maximum discharges exceed minimum discharges by a factor of only 3. Large tributaries that drain the southern Amazon River basin reach their peak discharges two months earlier than does the mainstem. The resulting backwater in the lowermost 800 km of two large southern tributaries, the Madeira and Puru??s rivers, causes falling river stages to be as much as 2-3 m higher than rising stages at any given discharge. Large tributaries that drain the northernmost Amazon River basin reach their annual minimum discharges three to four months later than does the mainstem. In the lowermost 300-400 km of the Negro River, the largest northern tributary and the fifth largest river in the world, the lowest stages of the year correspond to those of the Amazon River mainstem rather than to those in the upstream reaches of the Negro River. ?? 1991 Springer-Verlag New York Inc.
NASA Astrophysics Data System (ADS)
Oyler, Benjamin L.; Khan, Mohd M.; Smith, Donald F.; Harberts, Erin M.; Kilgour, David P. A.; Ernst, Robert K.; Cross, Alan S.; Goodlett, David R.
2018-04-01
In the preceding article "Top Down Tandem Mass Spectrometric Analysis of a Chemically Modified Rough-Type Lipopolysaccharide Vaccine Candidate" by Oyler et al., an error in the J5 E. coli LPS chemical structure (Figs. 2 and 4) was introduced and propagated into the final revision.
Analysis and Evaluation of the Reconfigured Exponential Troposphere Model (ETM)
2006-05-10
Southeast Asia, Northeast Asia, Amazon Rainforest , Sahara Desert, and Australia) have been selected for comparison based on their climate extremes, such as...of Appendix B Appendix B presents angle errors for the Middle East, the Amazon Rainforest , Northeast Asia, and Southeast Asia using the ETM Monthly...and calibration should be carefully implemented in this region for RF communication, application, and operation. For the Amazon Rainforest region, data
Peru: Current Conditions and U.S. Relations
2009-07-21
to development and poverty reduction. Of Peru’s 173 million acres of rainforest in the Amazon basin, about 70% has been granted or offered as...investment that will benefit the country as a whole. Indigenous peoples of the Amazon rainforest counter that the government is ignoring and/or...sent police to break up blockades set up by thousands of indigenous protesters in the Amazon . The deadly clash between the indigenous protesters and
A Strategic Market Analysis of the Open Market Corridor
2003-06-01
flourish. Amazon.com CEO, Jeff Bezos , initially considered a genius (when Amazon.com stock was selling for $113, is now facing a depressed economy...annual revenue exceeding one million dollars (Afuah, p. 339). In an extraordinary focus to “put customers first,” founder Jeff Bezos introduced...Accordingly, when faced with a paradoxically successful business model, and a rather amorphous market medium, Jeff Bozos and Amazon.com have taken a
NASA Astrophysics Data System (ADS)
Gehrcke, Jan-Philip; Kluth, Stefan; Stonjek, Stefan
2010-04-01
We show how the ATLAS offline software is ported on the Amazon Elastic Compute Cloud (EC2). We prepare an Amazon Machine Image (AMI) on the basis of the standard ATLAS platform Scientific Linux 4 (SL4). Then an instance of the SLC4 AMI is started on EC2 and we install and validate a recent release of the ATLAS offline software distribution kit. The installed software is archived as an image on the Amazon Simple Storage Service (S3) and can be quickly retrieved and connected to new SL4 AMI instances using the Amazon Elastic Block Store (EBS). ATLAS jobs can then configure against the release kit using the ATLAS configuration management tool (cmt) in the standard way. The output of jobs is exported to S3 before the SL4 AMI is terminated. Job status information is transferred to the Amazon SimpleDB service. The whole process of launching instances of our AMI, starting, monitoring and stopping jobs and retrieving job output from S3 is controlled from a client machine using python scripts implementing the Amazon EC2/S3 API via the boto library working together with small scripts embedded in the SL4 AMI. We report our experience with setting up and operating the system using standard ATLAS job transforms.
Revisiting the hierarchy of urban areas in the Brazilian Amazon: a multilevel approach
Costa, Sandra; Brondízio, Eduardo
2012-01-01
The Legal Brazilian Amazon, while the largest rainforest in the world, is also a region where most residents are urban. Despite close linkages between rural and urban processes in the region, rural areas have been the predominant focus of Amazon-based population-environment scholarship. Offering a focus on urban areas within the Brazilian Amazon, this paper examines the emergence of urban hierarchies within the region. Using a combination of nationally representative data and community based surveys, applied to a multivariate cluster methodology (Grade of Membership), we observe the emergence of sub-regional urban networks characterized by economic and political inter-dependency, population movement, and provision of services. These networks link rural areas, small towns, and medium and large cities. We also identify the emergence of medium-size cities as important nodes at a sub-regional level. In all, the work provides insight on the proposed model of ‘disarticulated urbanization’ within the Amazon by calling attention to the increasing role of regional and sub-regional urban networks in shaping the future expansion of land use and population distribution in the Amazon. We conclude with a discussion of implications for increasing intra-regional connectivity and fragmentation of conservation areas and ecosystems in the region. PMID:23129877
NASA Astrophysics Data System (ADS)
Agudelo, Jhoana; Arias, Paola A.; Vieira, Sara C.; Martínez, J. Alejandro
2018-06-01
Several studies have identified a recent lengthening of the dry season over the southern Amazon during the last three decades. Some explanations to this lengthening suggest the influence of changes in the regional circulation over the Atlantic and Pacific oceans, whereas others point to the influence of vegetation changes over the Amazon rainforest. This study aims to understand the implications of more frequent long dry seasons in this forest on atmospheric moisture transport toward northern South America and the Caribbean region. Using a semi-Langrangian model for water vapor tracking, results indicate that longer dry seasons in the southern Amazon relate to reductions of water vapor content over the southern and eastern Amazon basin, due to significant reductions of evaporation and recycled precipitation rates in these regions, especially during the transition from dry to wet conditions in the southern Amazon. On the other hand, longer dry seasons also relate to enhanced atmospheric moisture content over the Caribbean and northern South America regions, mainly due to increased contributions of water vapor from oceanic regions and the increase of surface moisture convergence over the equatorial region. This highlights the importance of understanding the relative role of regional circulation and local surface conditions on modulating water vapor transport toward continental regions.
Methane airborne measurements and comparison to global models during BARCA
NASA Astrophysics Data System (ADS)
Beck, Veronika; Chen, Huilin; Gerbig, Christoph; Bergamaschi, Peter; Bruhwiler, Lori; Houweling, Sander; Röckmann, Thomas; Kolle, Olaf; Steinbach, Julia; Koch, Thomas; Sapart, Célia J.; van der Veen, Carina; Frankenberg, Christian; Andreae, Meinrat O.; Artaxo, Paulo; Longo, Karla M.; Wofsy, Steven C.
2012-08-01
Tropical regions, especially the Amazon region, account for large emissions of methane (CH4). Here, we present CH4 observations from two airborne campaigns conducted within the BARCA (Balanço Atmosférico Regional de Carbono na Amazônia) project in the Amazon basin in November 2008 (end of the dry season) and May 2009 (end of the wet season). We performed continuous measurements of CH4 onboard an aircraft for the first time in the Amazon region, covering the whole Amazon basin with over 150 vertical profiles between altitudes of 500 m and 4000 m. The observations support the finding of previous ground-based, airborne, and satellite measurements that the Amazon basin is a large source of atmospheric CH4. Isotope analysis verified that the majority of emissions can be attributed to CH4 emissions from wetlands, while urban CH4 emissions could be also traced back to biogenic origin. A comparison of five TM5 based global CH4 inversions with the observations clearly indicates that the inversions using SCIAMACHY observations represent the BARCA observations best. The calculated CH4 flux estimate obtained from the mismatch between observations and TM5-modeled CH4 fields ranges from 36 to 43 mg m-2 d-1 for the Amazon lowland region.
Future drying of the southern Amazon and central Brazil
NASA Astrophysics Data System (ADS)
Yoon, J.; Zeng, N.; Cook, B.
2008-12-01
Recent climate modeling suggests that the Amazon rainforest could exhibit considerable dieback under future climate change, a prediction that has raised considerable interest as well as controversy. To determine the likelihood and causes of such changes, we analyzed the output of 15 models from the Intergovernmental Panel on Climate Change Fourth Assessment Report (IPCC/AR4) and a dynamic vegetation model VEGAS driven by these climate output. Our results suggest that the core of the Amazon rainforest should remain largely stable. However, the periphery, notably the southern edge, is in danger of drying out, driven by two main processes. First, a decline in precipitation of 24% in the southern Amazon lengthens the dry season and reduces soil moisture, despite of an increase in precipitation during the wet season, due to the nonlinear response in hydrology and ecosystem dynamics. Two dynamical mechanisms may explain the lower dry season precipitation: (1) a stronger north-south tropical Atlantic sea surface temperature gradient; (2) a general subtropical drying under global warming when the dry season southern Amazon is under the control of the subtropical high pressure. Secondly, evaporation will increase due to the general warming, thus also reducing soil moisture. As a consequence, the median of the models projects a reduction of vegetation by 20%, and enhanced fire carbon flux by 10-15% in the southern Amazon, central Brazil, and parts of the Andean Mountains. Because the southern Amazon is also under intense human influence, the double pressure of deforestation and climate change may subject the region to dramatic changes in the 21st century.
Projections of future meteorological drought and wet periods in the Amazon
Duffy, Philip B.; Brando, Paulo; Asner, Gregory P.; Field, Christopher B.
2015-01-01
Future intensification of Amazon drought resulting from climate change may cause increased fire activity, tree mortality, and emissions of carbon to the atmosphere across large areas of Amazonia. To provide a basis for addressing these issues, we examine properties of recent and future meteorological droughts in the Amazon in 35 climate models participating in the Coupled Model Intercomparison Project Phase 5 (CMIP5). We find that the CMIP5 climate models, as a group, simulate important properties of historical meteorological droughts in the Amazon. In addition, this group of models reproduces observed relationships between Amazon precipitation and regional sea surface temperature anomalies in the tropical Pacific and the North Atlantic oceans. Assuming the Representative Concentration Pathway 8.5 scenario for future drivers of climate change, the models project increases in the frequency and geographic extent of meteorological drought in the eastern Amazon, and the opposite in the West. For the region as a whole, the CMIP5 models suggest that the area affected by mild and severe meteorological drought will nearly double and triple, respectively, by 2100. Extremes of wetness are also projected to increase after 2040. Specifically, the frequency of periods of unusual wetness and the area affected by unusual wetness are projected to increase after 2040 in the Amazon as a whole, including in locations where annual mean precipitation is projected to decrease. Our analyses suggest that continued emissions of greenhouse gases will increase the likelihood of extreme events that have been shown to alter and degrade Amazonian forests. PMID:26460046
NASA Technical Reports Server (NTRS)
Ferreira, Rosana Nieto; Suarez, Max J.; Nigam, Sumant; Einaudi, Franco (Technical Monitor)
2001-01-01
The South Atlantic Convergence Zone (SACZ) is a NW-SE oriented, stationary region of enhanced convergence and convection that extends southeastward from the ITCZ convection anchored over the Amazon region. On daily satellite images each SACZ episode is seen as a progression of one or several midlatitude cold fronts that intrude into the subtropics and tropics, becoming stationary over southeastern Brazil for a few days. Previous studies have shown that while Amazon convection plays a fundamental role in the formation of the SACZ, Atlantic sea surface temperatures and the Andes Mountains play a relatively minor role in the strength and location of the SACZ. The role of interactions between Amazon convection and midlatitude baroclinic waves in establishing the origin, position, and maintenance of the SACZ is studied here using idealized dry, multilayer global model simulations that do not include the effects of topography. The model simulations produce SACZ-like regions of low-level convergence in the presence of Amazon convection embedded in a mean-flow that contains propagating baroclinic waves. The results of these simulations indicate that Amazon convection plays two fundamental roles in the formation and location of the SACZ. First, it produces a NW-SE oriented region of low-level convergence to the SE of Amazon convection. Second, it produces a storm-track region and accompanying stronger midlatitude baroclinic waves in the region of the SACZ. It is suggested that in the presence of moist effects, the 'seedling' SACZ regions produced in these simulations can be enhanced to produce the observed SACZ.
NASA Astrophysics Data System (ADS)
Campbell, K.
2016-12-01
The Belterra Clay is a sedimentary deposit that covers much of the eastern Amazon Basin in Brazil. It is notable in forming a very flat plain that occurs on both sides of the Amazon River, the Tapajos River, the Xingu River, and many smaller, tributary rivers east of 56° 32' W. The origin of the Belterra Clay is very controversial, with proponents of both allochthonous and autochthonous means of formation. There is little agreement as to its age. The fact that it occurs on both sides of the Amazon River indicates that its origin predates the formation of the modern Amazon River system, the timing of origin of which is itself highly controversial, with age estimates given for the river system formation that extend from the late Miocene, or 10 mya, to the late Pleistocene. From the time of origin of the Belterra Clay deposit until the modern Amazon River evolved, it formed an unbroken, terrestrial connection between the Brazilian Shield to the south and the Guiana Shield to the north, as well as east-west connections across what are today major river valleys, such as the Tapajos River and Xingu River. The formation and later severing of this once unbroken plain are predicted to have had major impacts on the distribution and evolutionary pathways of biotas inhabiting the region as once disparate communities were joined and later separated once again. Molecular clock ages for sister taxa north and south of the Amazon River have the potential of dating the time of formation of the Amazon River.
NASA Astrophysics Data System (ADS)
Yu, H.; Chin, M.; Yuan, T.; Bian, H.; Prospero, J. M.; Omar, A. H.; Remer, L. A.; Winker, D. M.; Yang, Y.; Zhang, Y.; Zhang, Z.
2014-12-01
The productivity of Amazon rainforest is constrained by the availability of nutrients, in particular phosphorus (P). Deposition of transported African dust in boreal winter and spring is considered an important nutrient input for the Amazon Basin, though its magnitude is not well qunatified. This study provides a remote sensing observation-based estimate of dust deposition in the Amazon Basin using a 7-year (2007-2013) record of three dimensional (3D) distributions of aerosol in both cloud-free and above-cloud conditions from the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP). It is estimated that the 7-year average of dust deposition into the Amazon Basin amounts to 15.1 ~ 32.1 Tg a-1 (Tg = 1012 g). This imported dust could provide 0.012 ~ 0.025 Tg P a-1 or equivalent to 12 ~ 26 g P ha-1 a-1 to fertilize the Amazon rainforest, which largely compensates the hydrological loss of P. The CLAIOP-based estimate agrees better with estimates from in-situ measurements and model simulations than what has been reported in literature. The closer agreement benefits from a more realistic geographic definition of the Amazon Basin and inclusion of meridional dust transport calculation in addition to the 3D nature of CALIOP aerosol measurements. The trans-Atlantic transport and deposition of dust shows strong interannual variations that are found to correlate with the North Atlantic Oscillation index in the winter season and anticorrelate with the prior-year Sahel Precipitation Index on an annual basis. Uncertainties associated with the estimate will also be discussed.
NASA Astrophysics Data System (ADS)
Li, Xing; Xiao, Jingfeng; He, Binbin
2018-04-01
Amazon forests play an important role in the global carbon cycle and Earth’s climate. The vulnerability of Amazon forests to drought remains highly controversial. Here we examine the impacts of the 2015 drought on the photosynthesis of Amazon forests to understand how solar radiation and precipitation jointly control forest photosynthesis during the severe drought. We use a variety of gridded vegetation and climate datasets, including solar-induced chlorophyll fluorescence (SIF), photosynthetic active radiation (PAR), the fraction of absorbed PAR (APAR), leaf area index (LAI), precipitation, soil moisture, cloud cover, and vapor pressure deficit (VPD) in our analysis. Satellite-derived SIF observations provide a direct diagnosis of plant photosynthesis from space. The decomposition of SIF to SIF yield (SIFyield) and APAR (the product of PAR and fPAR) reveals the relative effects of precipitation and solar radiation on photosynthesis. We found that the drought significantly reduced SIFyield, the emitted SIF per photon absorbed. The higher APAR resulting from lower cloud cover and higher LAI partly offset the negative effects of water stress on the photosynthesis of Amazon forests, leading to a smaller reduction in SIF than in SIFyield and precipitation. We further found that SIFyield anomalies were more sensitive to precipitation and VPD anomalies in the southern regions of the Amazon than in the central and northern regions. Our findings shed light on the relative and combined effects of precipitation and solar radiation on photosynthesis, and can improve our understanding of the responses of Amazon forests to drought.
Salinero, María Celeste; Michalski, Fernanda
2016-01-01
The quantity of wildlife extracted from the Amazon has increased in the past decades as a consequence of an increase in human population density and income growth. To evaluate the spatial distribution of studies on subsistence and/or commercial hunting conducted in the Brazilian Amazon, we selected eight mid-sized and large-bodied aquatic vertebrate species with a history of human exploitation in the region. We used a combination of searches in the gray and scientific literature from the past 24 years to provide an updated distributional map of studies on the target species. We calculated the distances between the study sites and the locations of the research institutes/universities that the first and last authors of the same study were affiliated to. For the period of 1990 to 2014, we found 105 studies on the subsistence and/or commercial hunting of aquatic vertebrates in the Brazilian Amazon in 271 locations that involved 43 institutions (37 Brazilian and 6 international). The spatial distribution of the studies across the Brazilian Amazon varied, but over 80% took place in the northeast and central Amazon, encompassing three States of the Legal Brazilian Amazon (Amazonas, 51.42%; Pará, 19.05%; and Amapá, 16.19%). Over half of the research study sites (52.91%) were within 500 km of the research institute/university of the first or last authors. Some research institutes/universities did not have any inter-institutional collaborations, while others collaborated with eight or more institutes. Some research institutes/universities conducted many studies, had an extensive collaboration network, and contributed greatly to the network of studies on Amazonian aquatic vertebrates. Our research contributes to the knowledge of studies on the subsistence and/or commercial hunting of the most exploited aquatic vertebrates of the Brazilian Amazon, illustrates the impact that collaboration networks have on research, and highlights potential areas for improvement and the generation of new collaborations.
NASA Astrophysics Data System (ADS)
Potter, Christopher; Brooks Genovese, Vanessa; Klooster, Steven; Bobo, Matthew; Torregrosa, Alicia
To produce a new daily record of gross carbon emissions from biomass burning events and post-burning decomposition fluxes in the states of the Brazilian Legal Amazon (Instituto Brasileiro de Geografia e Estatistica (IBGE), 1991. Anuario Estatistico do Brasil, Vol. 51. Rio de Janeiro, Brazil pp. 1-1024). We have used vegetation greenness estimates from satellite images as inputs to a terrestrial ecosystem production model. This carbon allocation model generates new estimates of regional aboveground vegetation biomass at 8-km resolution. The modeled biomass product is then combined for the first time with fire pixel counts from the advanced very high-resolution radiometer (AVHRR) to overlay regional burning activities in the Amazon. Results from our analysis indicate that carbon emission estimates from annual region-wide sources of deforestation and biomass burning in the early 1990s are apparently three to five times higher than reported in previous studies for the Brazilian Legal Amazon (Houghton et al., 2000. Nature 403, 301-304; Fearnside, 1997. Climatic Change 35, 321-360), i.e., studies which implied that the Legal Amazon region tends toward a net-zero annual source of terrestrial carbon. In contrast, our analysis implies that the total source fluxes over the entire Legal Amazon region range from 0.2 to 1.2 Pg C yr -1, depending strongly on annual rainfall patterns. The reasons for our higher burning emission estimates are (1) use of combustion fractions typically measured during Amazon forest burning events for computing carbon losses, (2) more detailed geographic distribution of vegetation biomass and daily fire activity for the region, and (3) inclusion of fire effects in extensive areas of the Legal Amazon covered by open woodland, secondary forests, savanna, and pasture vegetation. The total area of rainforest estimated annually to be deforested did not differ substantially among the previous analyses cited and our own.
Sediment supply as a driver of river evolution in the Amazon Basin
NASA Astrophysics Data System (ADS)
Ahmed, Joshua; Constantine, José Antonio; Dunne, Thomas; Legleiter, Carl; Lazarus, Eli D.
2015-04-01
The Amazon represents the only large river basin in the world where there is a sufficient range of sediment supplies and a lack of engineering controls to assess how sediment supply drives the evolution of meandering rivers. Despite recent analytical advances (Asahi et al., 2013; Pittaluga and Seminara, 2011), modern theory does not yet identify or explain the effects of externally imposed sediment supplies, a fundamental river characteristic, on meandering river evolution. These sediment supplies would be radically reduced by the construction of large dams proposed for the Amazon Basin (Finer and Jenkins, 2012). Here, we demonstrate that the sediment loads imposed by their respective drainage basins determine planform changes in lowland rivers across the Amazon. Our analysis, based on Landsat image sequences, indicates that rivers with high sediment loads draining the Andes and associated foreland basin experience annual migration rates that are on average four times faster than rivers with lower sediment loads draining the Central Amazon Trough and shields. Incidents of meander cutoff also occur more frequently along the rivers of the Andes and foreland basin, where the number of oxbows in the floodplains is more than twice that observed in the floodplains of the Central Amazon Trough and shields. Our results, which cannot be explained by differences in channel slope or hydrology, highlight the importance of sediment supply in modulating the ability of meandering alluvial rivers to reshape the floodplain environment through river migration. Asahi, K., Shimizu, Y., Nelson, J., Parker, G., 2013. Numerical simulation of river meandering with self-evolving banks. Journal of Geophysical Research: Earth Surface, 118(4), 2013JF002752. Finer, M., Jenkins, C.N., 2012. Proliferation of hydroelectric dams in the Andean Amazon and implications for Andes-Amazon connectivity. PLOS One, 7(4), e35126. Pittaluga, M.B., Seminara, G., 2011. Nonlinearity and unsteadiness in river meandering: a review of progress in theory and modelling. Earth Surface Processes and Landforms, 36(1), 20-38.
Salinero, María Celeste; Michalski, Fernanda
2016-01-01
The quantity of wildlife extracted from the Amazon has increased in the past decades as a consequence of an increase in human population density and income growth. To evaluate the spatial distribution of studies on subsistence and/or commercial hunting conducted in the Brazilian Amazon, we selected eight mid-sized and large-bodied aquatic vertebrate species with a history of human exploitation in the region. We used a combination of searches in the gray and scientific literature from the past 24 years to provide an updated distributional map of studies on the target species. We calculated the distances between the study sites and the locations of the research institutes/universities that the first and last authors of the same study were affiliated to. For the period of 1990 to 2014, we found 105 studies on the subsistence and/or commercial hunting of aquatic vertebrates in the Brazilian Amazon in 271 locations that involved 43 institutions (37 Brazilian and 6 international). The spatial distribution of the studies across the Brazilian Amazon varied, but over 80% took place in the northeast and central Amazon, encompassing three States of the Legal Brazilian Amazon (Amazonas, 51.42%; Pará, 19.05%; and Amapá, 16.19%). Over half of the research study sites (52.91%) were within 500 km of the research institute/university of the first or last authors. Some research institutes/universities did not have any inter-institutional collaborations, while others collaborated with eight or more institutes. Some research institutes/universities conducted many studies, had an extensive collaboration network, and contributed greatly to the network of studies on Amazonian aquatic vertebrates. Our research contributes to the knowledge of studies on the subsistence and/or commercial hunting of the most exploited aquatic vertebrates of the Brazilian Amazon, illustrates the impact that collaboration networks have on research, and highlights potential areas for improvement and the generation of new collaborations. PMID:27352247
NASA Astrophysics Data System (ADS)
Ronchail, Josyane; Cochonneau, Gérard; Molinier, Michel; Guyot, Jean-Loup; Chaves, Adriana Goretti De Miranda; Guimarães, Valdemar; de Oliveira, Eurides
2002-11-01
Rainfall variability in the Amazon basin is studied in relation to sea-surface temperatures (SSTs) in the equatorial Pacific and the northern and southern tropical Atlantic during the 1977-99 period, using the HiBAm original rainfall data set and complementary cluster and composite analyses.The northeastern part of the basin, north of 5 °S and east of 60 °W, is significantly related with tropical SSTs: a rainier wet season is observed when the equatorial Pacific and the northern (southern) tropical Atlantic are anomalously cold (warm). A shorter and drier wet season is observed during El Niño events and negative rainfall anomalies are also significantly associated with a warm northern Atlantic in the austral autumn and a cold southern Atlantic in the spring. The northeastern Amazon rainfall anomalies are closely related with El Niño-southern oscillation during the whole year, whereas the relationships with the tropical Atlantic SST anomalies are mainly observed during the autumn. A time-space continuity is observed between El Niño-related rainfall anomalies in the northeastern Amazon, those in the northern Amazon and south-eastern Amazon, and those in northern South America and in the Nordeste of Brazil.A reinforcement of certain rainfall anomalies is observed when specific oceanic events combine. For instance, when El Niño and cold SSTs in the southern Atlantic are associated, very strong negative anomalies are observed in the whole northern Amazon basin. Nonetheless, the comparison of the cluster and the composite analyses results shows that the rainfall anomalies in the northeastern Amazon are not always associated with tropical SST anomalies.In the southern and western Amazon, significant tropical SST-related rainfall anomalies are very few and spatially variable. The precipitation origins differ from those of the northeastern Amazon: land temperature variability, extratropical perturbations and moisture advection are important rainfall factors, as well as SSTs. This could partially explain why: (a) the above-mentioned signals weaken or disappear, with the exception of the relative dryness that is observed at the peak of an El Niño event and during the dry season when northern Atlantic SSTs are warmer than usual; (b) rainfall anomalies tend to resemble those of southeastern South America, noticeably at the beginning and the end of El Niño and La Niña events; (c) some strong excesses of rain are not associated with any SST anomalies and merit further investigation.
NASA Astrophysics Data System (ADS)
Ganesh, V.; Muthurasu, A.
2012-04-01
In this paper, we propose various strategies for an enzyme immobilization on electrodes (both metal and semiconductor electrodes). In general, the proposed methodology involves two critical steps viz., (1) chemical modification of substrates using functional monolayers [Langmuir - Blodgett (LB) films and/or self-assembled monolayers (SAMs)] and (2) anchoring of a target enzyme using specific chemical and physical interactions by attacking the terminal functionality of the modified films. Basically there are three ways to immobilize an enzyme on chemically modified electrodes. First method consists of an electrostatic interaction between the enzyme and terminal functional groups present within the chemically modified films. Second and third methods involve the introduction of nanomaterials followed by an enzyme immobilization using both the physical and chemical adsorption processes. As a proof of principle, in this work we demonstrate the sensing and catalytic activity of horseradish peroxidase (HRP) anchored onto SAM modified indium tin oxide (ITO) electrodes towards hydrogen peroxide (H2O2). Structural characterization of such modified electrodes is performed using X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and contact angle measurements. The binding events and the enzymatic reactions are monitored using electrochemical techniques mainly cyclic voltammetry (CV).
Effects of selective logging on bat communities in the southeastern Amazon.
Peters, Sandra L; Malcolm, Jay R; Zimmerman, Barbara L
2006-10-01
Although extensive areas of tropical forest are selectively logged each year, the responses of bat communities to this form of disturbance have rarely been examined. Our objectives were to (1) compare bat abundance, species composition, and feeding guild structure between unlogged and low-intensity selectively logged (1-4 logged stems/ha) sampling grids in the southeastern Amazon and (2) examine correlations between logging-induced changes in bat communities and forest structure. We captured bats in understory and canopy mist nets set in five 1-ha study grids in both logged and unlogged forest. We captured 996 individuals, representing 5 families, 32 genera, and 49 species. Abundances of nectarivorous and frugivorous taxa (Glossophaginae, Lonchophyllinae, Stenodermatinae, and Carolliinae) were higher at logged sites, where canopy openness and understory foliage density were greatest. In contrast, insectivorous and omnivorous species (Emballonuridae, Mormoopidae, Phyllostominae, and Vespertilionidae) were more abundant in unlogged sites, where canopy foliage density and variability in the understory stratum were greatest. Multivariate analyses indicated that understory bat species composition differed strongly between logged and unlogged sites but provided little evidence of logging effects for the canopy fauna. Different responses among feeding guilds and taxonomic groups appeared to be related to foraging and echolocation strategies and to changes in canopy cover and understory foliage densities. Our results suggest that even low-intensity logging modifies habitat structure, leading to changes in bat species composition.
Seroprevalence of Toxoplasma gondii antibodies in humans from rural Western Amazon, Brazil.
Cavalcante, G T; Aguilar, D M; Camargo, L M A; Labruna, M B; de Andrade, H F; Meireles, L R; Dubey, J P; Thulliez, P; Dias, R A; Gennari, S M
2006-06-01
Antibodies to Toxoplasma gondii were assayed in sera of 266 humans from 71 farms located at Rondônia State, Western Amazon, Brazil, by the modified agglutination test (MAT) and the indirect immunofluorescent antibody test (IFAT). Antibodies were found in 195 humans (73.3%), with MAT titers of 1:25 in 11, 1:50 in 11, 1:100 in 16, 1:200 in 27, 1:400 in 38, 1:800 in 37, 1:1,600 in 22, and 1:3,200 or higher in 33. From the 71 farms visited, 69 had seropositive humans. Prevalence of anti-T. gondii antibodies increased with age of the people (P < 0.05), and no difference was observed in the occurrence by gender (P > 0.05). A sanitary questionnaire was applied in each farm, and statistical association between the serologic status and several variables were analyzed. Home-grown vegetable consumption and origin of drinking water (well or river) were the independent variables that displayed significant association (P = 0.002 and 0.02, respectively). Higher values of occurrence were found in people with consumption of home-grown vegetables (76.1%) and people that drink well water (75.4%) compared with people that did not consume this type of food (61.9%) and drink river water (55.2%). By IFAT (> or = 1:16), 194 of 266 (73%) humans were seropositive and there was a good correlation between MAT and IFAT.
Guerra, Denis L; Batista, Adriano C; da Costa, Paulo C Corrêa; Viana, Rúbia R; Airoldi, Claudio
2010-06-01
The original sepiolite clay mineral has been collected from Amazon region, Brazil. The compound 2-aminomethylpyridine (AMP) was anchored onto Amazon sepiolite surface by heterogeneous route. The natural (SPT) and modified (SPT(AMP)) sepiolite samples were characterized by elemental analysis, SEM, N(2) adsorption, and nuclear magnetic nuclei of (29)Si and (13)C. The well-defined peaks obtained in the (13)C NMR spectrum in the 0-160 ppm region confirmed the attachment of organic functional groups as pendant chains bonded into the porous clay. The ability of these materials to remove As(V) from aqueous solution was followed by a series of adsorption isotherms at room temperature and pH 4.0. The maximum number of moles adsorbed was determined to be 7.26×10(-2) and 11.70×10(-2) mmol g(-1) for SPT and SPT(AMP), respectively. In order to evaluate the clay samples as adsorbents in dynamic system, a glass column was fulfilled with clay samples (1.0 g) and it was fed with 2.0×10(-2) mmol dm(-3) As(V) at pH 4.0. The energetic effects caused by metal cations adsorption were determined through calorimetric titrations. Thermodynamics indicated the existence of favorable conditions for such As(V)-nitrogen interactions. Copyright © 2010. Published by Elsevier Inc.
Ancient human disturbances may be skewing our understanding of Amazonian forests.
McMichael, Crystal N H; Matthews-Bird, Frazer; Farfan-Rios, William; Feeley, Kenneth J
2017-01-17
Although the Amazon rainforest houses much of Earth's biodiversity and plays a major role in the global carbon budget, estimates of tree biodiversity originate from fewer than 1,000 forest inventory plots, and estimates of carbon dynamics are derived from fewer than 200 recensus plots. It is well documented that the pre-European inhabitants of Amazonia actively transformed and modified the forest in many regions before their population collapse around 1491 AD; however, the impacts of these ancient disturbances remain entirely unaccounted for in the many highly influential studies using Amazonian forest plots. Here we examine whether Amazonian forest inventory plot locations are spatially biased toward areas with high probability of ancient human impacts. Our analyses reveal that forest inventory plots, and especially forest recensus plots, in all regions of Amazonia are located disproportionately near archaeological evidence and in areas likely to have ancient human impacts. Furthermore, regions of the Amazon that are relatively oversampled with inventory plots also contain the highest values of predicted ancient human impacts. Given the long lifespan of Amazonian trees, many forest inventory and recensus sites may still be recovering from past disturbances, potentially skewing our interpretations of forest dynamics and our understanding of how these forests are responding to global change. Empirical data on the human history of forest inventory sites are crucial for determining how past disturbances affect modern patterns of forest composition and carbon flux in Amazonian forests.
The ticks (Acari: Ixodida: Argasidae, Ixodidae) of Paraguay
2007-01-01
comprises the Amazonic and Chaco domains. The Amazonic domain is represented by the Cerrado phyto–geographical province (CePP) in the north–east and by the...geographical provinces of Cerrado and Paranaense belong to the Amazonic domain whereas Chaco province is within the Chaco domain. 258 NAVA ET AL. RESULTS...Ecuador, Panama, Peru and Venezuela. Ornithodoros talaje (Guérin-Méneville)/ Ornithodoros puertoricensis Fox. Cordero et al. (1928) found adults of Orn
Enhanced Methane Emissions during Amazonian Drought by Biomass Burning
Ito, Akihiko; Yokota, Tatsuya; Maksyutov, Shamil
2016-01-01
The Amazon is a significant source of atmospheric methane, but little is known about the source response to increasing drought severity and frequency. We investigated satellite observations of atmospheric column-averaged methane for the 2010 drought and subsequent 2011 wet year in the Amazon using an atmospheric inversion scheme. Our analysis indicates an increase in atmospheric methane over the southern Amazon region during the drought, representing an increase in annual emissions relative to the wet year. We attribute the increase to emissions from biomass burning driven by intense drought, combined with carbon monoxide showing seasonal variations corresponding to methane variations. We show that there is probably a strong correspondence between drought and methane emissions in the Amazon. PMID:27851783
Process for derivatizing carbon nanotubes with diazonium species and compositions thereof
NASA Technical Reports Server (NTRS)
Bahr, Jeffrey L. (Inventor); Tour, James M. (Inventor); Yang, Jiping (Inventor)
2011-01-01
Methods for the chemical modification of carbon nanotubes involve the derivatization of multi- and single-wall carbon nanotubes, including small diameter (ca. 0.7 nm) single-wall carbon nanotubes, with diazonium species. The method allows the chemical attachment of a variety of organic compounds to the side and ends of carbon nanotubes. These chemically modified nanotubes have applications in polymer composite materials, molecular electronic applications, and sensor devices. The methods of derivatization include electrochemical induced reactions, thermally induced reactions, and photochemically induced reactions. Moreover, when modified with suitable chemical groups, the derivatized nanotubes are chemically compatible with a polymer matrix, allowing transfer of the properties of the nanotubes (such as, mechanical strength or electrical conductivity) to the properties of the composite material as a whole. Furthermore, when modified with suitable chemical groups, the groups can be polymerized to form a polymer that includes carbon nanotubes.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Martin, Scot T.
The Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5) Experiment was carried out in the environs of Manaus, Brazil, in the central region of the Amazon basin during two years from 1 January 2014 through 31 December 2015. The experiment focused on the complex interactions among vegetation, atmospheric chemistry, and aerosol production on the one hand and their connections to aerosols, clouds, and precipitation on the other. The objective was to understand and quantify these linked processes, first under natural conditions to obtain a baseline and second when altered by the effects of human activities. To this end, themore » pollution plume from the Manaus metropolis, superimposed on the background conditions of the central Amazon basin, served as a natural laboratory. The present paper, as Introduction to the GoAmazon2014/5 Special Issue, presents the context and motivation of the GoAmazon2014/5 Experiment. The nine research sites, including the characteristics and instrumentation of each site, are presented. The sites range from time point zero (T0) upwind of the pollution, to T1 in the midst of the pollution, to T2 just downwind of the pollution, to T3 furthest downwind of the pollution (70 km). In addition to the ground sites, a low-altitude G-159 Gulfstream I (G1) observed the atmospheric boundary layer and low clouds, and a high-altitude Gulfstream G550 (HALO) operated in the free troposphere. During the two-year experiment, two Intensive Operating Periods (IOP1 and IOP2) also took place that included additional specialized research instrumentation at the ground sites as well as flights of the two aircraft. GoAmazon2014/5 IOP1 was carried out from 1 February to 31 March 2014 in the wet season. GoAmazon2014/5 IOP2 was conducted from 15 August to 15 October 2014 in the dry season. The G1 aircraft flew during both IOP1 and IOP2, and the HALO aircraft flew during IOP2. In the context of the Amazon basin, the two IOPs also correspond to the clean and biomass burning seasons, respectively. The Manaus plume is present year round, and it is transported by prevailing northeasterly and easterly winds in the wet and dry seasons, respectively. This Introduction also organizes information relevant to many papers in the Special Issue. Information is provided on the vehicle fleet, power plants, and industrial activities of Manaus. The mesoscale and synoptic meteorology relevant to the two IOPs is presented. Regional and long-range transport of emissions for the two IOPs is discussed based on satellite observations across South America and Africa. Fire locations throughout the airshed are detailed. In conjunction with the context and motivation of GoAmazon2014/5, as presented herein in this Introduction, research articles published in this Special Issue are anticipated in the near future to describe the detailed results and findings of GoAmazon2014/5.« less
NASA Astrophysics Data System (ADS)
Boers, Niklas; Marwan, Norbert; Barbosa, Henrique; Kurths, Jürgen
2015-04-01
A key driver of South American climate are the low-level trade winds from the tropical Atlantic Ocean towards the continent. After crossing the Amazon Basin, they are blocked by the Andes mountain range, and forced southward to the subtropics. These winds are crucial for the atmospheric moisture supply in most parts of South America. In particular, the hydrology of the two largest river basins of the Continent, namely the Amazon and the La Plata Basins, strongly depend on the moisture inflow provided by the trade winds. In turn, the Amazon rainforest can be assumed to have a strong influence on this low-level moisture circulation over South America by exchanging moisture with the atmosphere through precipitation and evapotranspiration. A pronounced positive feedback in this context is established through precipitation-induced release of latent heat over the Amazon Basin, which significantly enhances the moisture inflow from the tropical Atlantic Ocean toward the continent and can thus be considered to be crucial for the existence of today's South American climate. Ongoing deforestation and resulting reduction in evapotranspiration rates in particular in the eastern Amazon carry the risk of a strongly nonlinear response in these interactions with the low-level atmosphere. We propose a simple differential transport model describing the cascading moisture transport from the eastern coast of South America across the Amazon Basin to the Andes, taking into account the nonlinearity associated with the release of latent heat. The results of the model suggest that the system is indeed very sensitive to relatively small reductions of the evapotranspiration rates in the eastern Amazon Basin. These reductions increase river runoff, but limit the moisture availability farther west. This leads to a reduction in precipitation rates and thereby diminishes the release of latent heat which, in turn, reduces the overall moisture inflow. We show that, according to our model, there exist critical thresholds on the spatial extents and intensities of deforestation. Beyond these thresholds, the positive feedback between the Amazon rainforest and the low-level circulation would collapse, resulting in substantial reductions in moisture available for precipitation in the western part of the Amazon Basin and further downstream of the low-level flow, including most of subtropical South America.
NASA Astrophysics Data System (ADS)
Thonicke, K.; Rammig, A.; Gumpenberger, M.; Vohland, K.; Poulter, B.; Cramer, W.
2009-04-01
The Amazon rainforest is threatened by deforestation due to wood extraction and agricultural production leading to increasing forest fragmentation and forest degradation. These changes in land surface characteristics and water fluxes are expected to further reduce convective precipitation. Under future climate change the stability of the Amazon rainforest is likely to decrease thus leading to forest dieback (savannization) or forest degradation (secondarization). This puts the Amazon rainforest at risk to reduce the generation of precipitation, to act as a carbon sink and biodiversity hotspot. Fires increased in the past during drought years and in open vegetation thereby further accelerating forest degradation. Deforestation as a result of socioeconomic development in the Amazon basin is projected to further increase in the 21st century and brings climate-induced changes forward. Combined effects of deforestation vs. climate change on the stability of the Amazon rainforest and the role of fire in this system need to be quantified in an integrated study. We present simulation results from future climate (AR4) and deforestation (SimAmazon) experiments using the LPJmL-SPITFIRE vegetation model. Land use change is the main driving factor of forest degradation before 2050, whereas extreme climate change scenarios lead to forest degradation by the end of 2100. Forest fires increase with increasing drought conditions during the 21st century. The resulting effects on vegetation secondarization and savannization and their feedbacks on fire spread and emissions will be presented. The effect of wildfires and intentional burning on forest degradation under future climate and socioeconomic change will be discussed, and recommendations for an integrated land use and fire management are given.
Tree-Ring Reconstruction of Wet Season Rainfall Totals in the Amazon
NASA Astrophysics Data System (ADS)
Stahle, D. W.; Lopez, L.; Granato-Souza, D.; Barbosa, A. C. M. C.; Torbenson, M.; Villalba, R.; Pereira, G. D. A.; Feng, S.; Schongart, J.; Cook, E. R.
2017-12-01
The Amazon Basin is a globally important center of deep atmospheric convection, energy balance, and biodiversity, but only a handful of weather stations in this vast Basin have recorded rainfall measurements for at least 50 years. The available rainfall and river level observations suggest that the hydrologic cycle in the Amazon may have become amplified in the last 40-years, with more extreme rainfall and streamflow seasonality, deeper droughts, and more severe flooding. These changes in the largest hydrological system on earth may be early evidence of the expected consequences of anthropogenic climate change and deforestation in the coming century. Placing these observed and simulated changes in the context of natural climate variability during the late Holocene is a significant challenge for high-resolution paleoclimatology. We have developed exactly dated and well-replicated annual tree-ring chronologies from two native Amazonian tree species (Cedrela sp and Centrolobium microchaete). These moisture sensitive chronologies have been used to compute two reconstructions of wet season rainfall totals, one in the southern Amazon based on Centrolobium and another in the eastern equatorial Amazon using Cedrela. Both reconstructions are over 200-years long and extend the available instrumental observations in each region by over 150-years. These reconstructions are well correlated with the same regional and large-scale climate dynamics that govern the inter-annual variability of the instrumental wet season rainfall totals. Increased multi-decadal variability is reconstructed after 1950 with the Centrolobium chronologies in the southern Amazon. The Cedrela reconstruction from the eastern Amazon exhibits changes in the spatial pattern of correlation with regional rainfall stations and the large-scale sea surface temperature field after 1990 that may be consistent with recent changes in the mean position of the Inter-Tropical Convergence Zone in March over the western Atlantic and South American sector.
NASA Astrophysics Data System (ADS)
Saleska, S.; Goncalves, L. G.; Baker, I.; Costa, M.; Poulter, B.; Christoffersen, B.; Da Rocha, H. R.; Didan, K.; Huete, A.; Imbuziero, H.; Kruijt, B.; Manzi, A.; von Randow, C.; Restrepo-Coupe, N.; Silva, R.; Tota, J.; Denning, S.; Gulden, L.; Rosero, E.; Zeng, X.
2008-12-01
Amazon forests play an important and complex role in the global carbon cycle, and important advances have been made in understanding Amazon processes in recent years. However, reconciling modeled mechanisms of carbon cycling with observations across scales remains a challenge. To better address this challenge, we initiated a Model intercomparison Project for the 'Large-Scale Biosphere Atmosphere Experiment in Amazonia' (LBA-MIP) to integrate modeling and observational studies for improved understanding of Amazon basin carbon cycling. Here, we report on the initial results of this project, which used the network of meteorological and climate data (sunlight, radiation, precipitation) from Amazon tower sites in forest and converted lands to drive a suite of 20 ecosystem models that simulate energy, water and CO2 fluxes. We compared model mechanisms to each other and to the relevant flux observations from those towers, as well as from satellite data from the Moderate Resolution Imaging Spectroradiometer (MODIS). Remote sensing and flux tower observations tend to show higher primary forest photosynthetic activity in the dry season than in the wet season in central Amazon, a broad pattern that is now captured in many models, but for different reasons. A reversal from the primary forest pattern was observed in areas converted to pasture, agriculture, or secondary forests, likely a consequence of the elimination of deep root access to deep soil waters which often persist through the dry season. Testing the models with observed fluxes under different land use patterns, and across different spatial scales with remote sensing, is enabling us to distinguish correct vs. incorrect model mechanisms and improve understanding of Amazon processes.
A geomorphological assessments of the distribution of sediment sinks along the lower Amazon River
NASA Astrophysics Data System (ADS)
Park, E.; Latrubesse, E. M.
2017-12-01
Floodplain sediment storage budget is examined along the 1,000 km reach of the lower Amazon River based on extensive sets of remote sensing data and field measurements. Incorporating the washload discharges at gauge stations at the main channel and major tributaries, we analyzed the roles of vast floodplain on the Amazon River seasonal variability in sediment discharges. Annual washload accumulation rate on floodplain along the reach in between Manacapuru and Obidos of is estimated to be 79 Mt over inter-annual average. Period that the net loss over to the floodplain of washload coincide with discharge rising phase of the Amazon River at Obidos, when the river water level rises to make hydrologic connections to floodplain. Only during the early falling phase (July-August), 3.6 Mt of washload net gain occurred in a year, which was less than 5% of the annual net loss to the floodplain. To assess the spatial distribution of sediment sinks along the lower Amazon, we incorporated various hydro-geomorphic factors regarding floodplain geomorphic styles and morphometric parameters, such floodplain width, levee heights, water-saturated area, suspended sediment distribution over floodplain and distribution of impeded floodplain. Impeded floodplain that contains numerous large rounded lakes is the definition of active sediment sinks along the lower Amazon, which seasonally stores most of the water and traps sediment from the river. The results of these hydro-geomorphic factors collectively indicate that the extent and magnitudes of sediment sinks becomes larger downstream (from Manacapuru to Monte Alegre), which is proportionally related to the development of the water-saturated floodplain. This indicates the nonlinear geomorphic evolution of the Amazon floodplain through its longitudinal profile since the late Holocene that downstream reaches are still to be infilled with sediments (incomplete floodplain) thus acting as sediment sinks.
Evapotranspiration seasonality across the Amazon Basin
NASA Astrophysics Data System (ADS)
Eiji Maeda, Eduardo; Ma, Xuanlong; Wagner, Fabien Hubert; Kim, Hyungjun; Oki, Taikan; Eamus, Derek; Huete, Alfredo
2017-06-01
Evapotranspiration (ET) of Amazon forests is a main driver of regional climate patterns and an important indicator of ecosystem functioning. Despite its importance, the seasonal variability of ET over Amazon forests, and its relationship with environmental drivers, is still poorly understood. In this study, we carry out a water balance approach to analyse seasonal patterns in ET and their relationships with water and energy drivers over five sub-basins across the Amazon Basin. We used in situ measurements of river discharge, and remotely sensed estimates of terrestrial water storage, rainfall, and solar radiation. We show that the characteristics of ET seasonality in all sub-basins differ in timing and magnitude. The highest mean annual ET was found in the northern Rio Negro basin (˜ 1497 mm year-1) and the lowest values in the Solimões River basin (˜ 986 mm year-1). For the first time in a basin-scale study, using observational data, we show that factors limiting ET vary across climatic gradients in the Amazon, confirming local-scale eddy covariance studies. Both annual mean and seasonality in ET are driven by a combination of energy and water availability, as neither rainfall nor radiation alone could explain patterns in ET. In southern basins, despite seasonal rainfall deficits, deep root water uptake allows increasing rates of ET during the dry season, when radiation is usually higher than in the wet season. We demonstrate contrasting ET seasonality with satellite greenness across Amazon forests, with strong asynchronous relationships in ever-wet watersheds, and positive correlations observed in seasonally dry watersheds. Finally, we compared our results with estimates obtained by two ET models, and we conclude that neither of the two tested models could provide a consistent representation of ET seasonal patterns across the Amazon.
Cancer mortality and oil production in the Amazon Region of Ecuador, 1990-2005.
Kelsh, Michael A; Morimoto, Libby; Lau, Edmund
2009-02-01
To compare cancer mortality rates in Amazon cantons (counties) with and without long-term oil exploration and extraction activities. Mortality (1990 through 2005) and population census (1990 and 2001) data for cantons in the provinces of the northern Amazon Region (Napo, Orellana, Sucumbios, and Pastaza), as well as the province with the capital city of Quito (Pichincha province) were obtained from the National Statistical Office of Ecuador, Instituto Nacional del Estadistica y Censos (INEC). Age- and sex-adjusted mortality rate ratios (RR) and 95% confidence intervals (CI) were estimated to evaluate total and cause-specific mortality in the study regions. Among Amazon cantons with long-term oil extraction, activities there was no evidence of increased rates of death from all causes (RR = 0.98; 95% CI = 0.95-1.01) or from overall cancer (RR = 0.82; 95% CI = 0.73-0.92), and relative risk estimates were also lower for most individual site-specific cancer deaths. Mortality rates in the Amazon provinces overall were significantly lower than those observed in Pichincha for all causes (RR = 0.82; 95% CI = 0.81-0.83), overall cancer (RR = 0.46; 95% CI = 0.43-0.49), and for all site-specific cancers. In regions with incomplete cancer registration, mortality data are one of the few sources of information for epidemiologic assessments. However, epidemiologic assessments in this region of Ecuador are limited by underreporting, exposure and disease misclassification, and study design limitations. Recognizing these limitations, our analyses of national mortality data of the Amazon Region in Ecuador does not provide evidence for an excess cancer risk in regions of the Amazon with long-term oil production. These findings were not consistent or supportive of earlier studies in this region that suggested increased cancer risks.
A century of Amazon burning driven by Atlantic climate
NASA Astrophysics Data System (ADS)
Makou, M.; Thompson, L. G.; Davis, M. E.; Eglinton, T. I.
2011-12-01
Very little is known about annual burning trends in the Amazon Basin prior to remote sensing of fires beginning in the late 1970's. Fires reduce Amazon forest biomass and species richness, release pollutant aerosols, and impact the carbon cycle, compelling further investigation of fire-climate dynamics. We measured organic compounds derived from vegetation burning in ice core samples from the Quelccaya Ice Cap in Peru at better than annual resolution to reconstruct wet and dry season burning throughout the Twentieth Century. Variations in the abundance of methyl hexadecanoate, which is produced by thermal alteration of vascular plant alkanoic acids, were used as a proxy for past fire activity. Concentrations of this compound in Quelccaya ice varied strongly on seasonal, interannual, and decadal time scales over the last 100 years, with high-amplitude dry season variability and muted, decadal-scale changes in wet season fire activity. Decade-long periods of repeatedly enhanced burning occurred during the 1930's and 1960's when dry season precipitation was perpetually reduced, as evidenced by low stages of the Rio Negro. These decadal trends suggest that changes in dry season precipitation drive fire activity in the western Amazon and highlight the potential of Amazon forests to undergo repeated strong burning. Fires occurred during years when sea surface temperatures (SSTs) in the north tropical Atlantic were elevated and the north-south tropical Atlantic SST gradient was enhanced; this SST pattern likely displaced the intertropical convergence zone northward, driving subsidence and drought in the western and southern Amazon basin. Thus, our novel ice core record suggests that Amazon forest fire activity during the Twentieth Century was driven primarily by Atlantic climate processes, and future forest health will depend heavily on the evolution of tropical climate.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Burleyson, Casey D.; Feng, Zhe; Hagos, Samson M.
The Amazon rainforest is one of a few regions of the world where continental tropical deep convection occurs. The Amazon’s isolation makes it challenging to observe, but also creates a unique natural laboratory to study anthropogenic impacts on clouds and precipitation in an otherwise pristine environment. Extensive measurements were made upwind and downwind of the large city of Manaus, Brazil during the Observations and Modeling of the Green Ocean Amazon 2014-2015 (GoAmazon2014/5) field campaign. In this study, 15 years of high-resolution satellite data are analyzed to examine the spatial and diurnal variability of convection occurring around the GoAmazon2014/5 sites. Interpretationmore » of anthropogenic differences between the upwind (T0) and downwind (T1-T3) sites is complicated by naturally-occurring spatial variability between the sites. During the rainy season, the inland propagation of the previous day’s sea-breeze front happens to be in phase with the background diurnal cycle near Manaus, but is out of phase elsewhere. Enhanced convergence between the river-breezes and the easterly trade winds generates up to 10% more frequent deep convection at the GoAmazon2014/5 sites east of the river (T0a, T0t/k, and T1) compared to the T3 site which was located near the western bank. In general, the annual and diurnal cycles during 2014 were representative of the 2000-2013 distributions. The only exceptions were in March when the monthly mean rainrate was above the 95th percentile and September when both rain frequency and intensity were suppressed. The natural spatial variability must be accounted for before interpreting anthropogenically-induced differences among the GoAmazon2014/5 sites.« less
Evaluation of Amazon fruits: chemical and nutritional studies on Borojoa sorbilis.
Rabelo Rodrigues, Francimilton; de Souza Ramos, Aline; Fernandes Amaral, Ana Claudia; Pinto Ferreira, José Luiz; da Silva Carneiro, Carla; Rocha de Andrade Silva, Jefferson
2018-01-31
Borojoa sorbilis (Ducke) is an Amazonian species with edible fruits that are widely consumed by the local population, but little studied and not yet economically explored. Thus the aim of this study was to describe the chemical composition, volatile compounds, nutritional aspects and antioxidant activity of the fruit pulp and peel of B. sorbilis. Headspace solid-phase microextraction, using polydimethylsiloxane-divinylbenzene (PDMS-DVB) fiber, resulted in the identification of 59 substances in the pulp and peel of B. sorbilis fruits after analysis of the chromatograms obtained by gas chromatography-mass spectrometry using polar and nonpolar columns. Esters were the most abundant. Moisture, lipids, protein, dietary fiber, ash, carbohydrate, total energy value, titratable acid, soluble solids and pH were measured. Protein amount, fat content and antioxidant activity were low in both pulp and peel. Carbohydrate content was 179.2 and 134.9 g kg -1 in pulp and peel, respectively. This is the first report on the chemical characteristics, flavor and nutritional aspects of B. sorbilis fruit, which is essential to its economic exploitation. The high energy value associated with the carbohydrate content, plus the low fat content, contribute to a possible use of B. sorbilis fruits as a food supplement. © 2018 Society of Chemical Industry. © 2018 Society of Chemical Industry.
Susceptibility of Peruvian Mosquitoes to Eastern Equine Encephalitis virus
2008-07-01
the Amazon Basin, near Iquitos, Peru , and used in experimental studies to evaluate their susceptibility to strains of eastern equine encephalitis virus...the repeated isolation of strains of EEEV from Cx. pedroi captured in the Amazon Basin region of Peru , suggests that Cx. pedroi may be the primary...in the Amazon Basin region in Peru , mosquitoes were cap- tured and identiÞed and tested for arboviruses (Pecor et al. 2000, Jones et al. 2004, Turell
2008-11-01
and malarial activity in the Amazon Basin, Loreto Department, Peru , to determine the relative abundance, species diversity, and seasonal and vertical...populations. KEY WORDS Anopheles, bionomics, mosquito ecology, Amazon Basin, Peru Malaria and other arthropod-vectored diseases are on the increase...in the Amazon Basin region of Peru to date. The Puerto Almendra area was selected because human cases of dengue, malaria, Mayaro, Oropouche
2007-06-15
Jeff Bezos , at Jeff @Amazon.com. Ultimately, this exchange produced no verification of the information I was able to garner from the Internet, to...that conventional brick-and-mortar and mail-order bookstores could. Jeff Bezos , President, Chief Executive Officer and Chairman of the Board...was aptly chosen and has truly become synonymous with voluminous Amazon River. Jeff Bezos , Amazon.com President and CEO, changed the name from
Nepstad, Daniel C; Stickler, Claudia M; Filho, Britaldo Soares-; Merry, Frank
2008-05-27
Some model experiments predict a large-scale substitution of Amazon forest by savannah-like vegetation by the end of the twenty-first century. Expanding global demands for biofuels and grains, positive feedbacks in the Amazon forest fire regime and drought may drive a faster process of forest degradation that could lead to a near-term forest dieback. Rising worldwide demands for biofuel and meat are creating powerful new incentives for agro-industrial expansion into Amazon forest regions. Forest fires, drought and logging increase susceptibility to further burning while deforestation and smoke can inhibit rainfall, exacerbating fire risk. If sea surface temperature anomalies (such as El Niño episodes) and associated Amazon droughts of the last decade continue into the future, approximately 55% of the forests of the Amazon will be cleared, logged, damaged by drought or burned over the next 20 years, emitting 15-26Pg of carbon to the atmosphere. Several important trends could prevent a near-term dieback. As fire-sensitive investments accumulate in the landscape, property holders use less fire and invest more in fire control. Commodity markets are demanding higher environmental performance from farmers and cattle ranchers. Protected areas have been established in the pathway of expanding agricultural frontiers. Finally, emerging carbon market incentives for reductions in deforestation could support these trends.
The Amazons and an analysis of breast mutilation from a plastic surgeon's perspective.
Karacalar, Ahmet
2007-03-01
The Amazon philosophy has been increasing in popularity because of the evolving status of women in society. Many references point to Themiscrya on the southern coast of the Black Sea in Anatolia as the Amazon homeland. The primary objective of this article is to discuss the different femininity of the Amazons and their breast mutilation from the perspective of a plastic surgeon who has been living in this region that the Amazons inhabited. Findings from archaeology, linguistics, anthropology, medicine, history, psychology, and the fine arts were integrated. The hypotheses that have been proposed to explain the method of breast mutilation include amputation, cauterization, breast searing, and breast pinching. It is generally believed that the primary purpose was to facilitate the efficient use of a bow. Another explanation would be that breast mutilation was performed for medical reasons, including the prevention of breast pain, the development of a tender lump, or cancer. There is another school of thought on this involving religious and sociological reasons that breast mutilation was a badge of honor for warrior women and a sign that a woman had become a real warrior and a sacrifice to Artemis as a sign of service. Much indirect proof and archaeological evidence point to their historical existence. The Amazons, who lived in an autonomous and original social model, changed their image and function to suit the needs of the society and the times.
Longo, Marcos; Knox, Ryan G; Levine, Naomi M; Alves, Luciana F; Bonal, Damien; Camargo, Plinio B; Fitzjarrald, David R; Hayek, Matthew N; Restrepo-Coupe, Natalia; Saleska, Scott R; da Silva, Rodrigo; Stark, Scott C; Tapajós, Raphael P; Wiedemann, Kenia T; Zhang, Ke; Wofsy, Steven C; Moorcroft, Paul R
2018-05-22
The impact of increases in drought frequency on the Amazon forest's composition, structure and functioning remain uncertain. We used a process- and individual-based ecosystem model (ED2) to quantify the forest's vulnerability to increased drought recurrence. We generated meteorologically realistic, drier-than-observed rainfall scenarios for two Amazon forest sites, Paracou (wetter) and Tapajós (drier), to evaluate the impacts of more frequent droughts on forest biomass, structure and composition. The wet site was insensitive to the tested scenarios, whereas at the dry site biomass declined when average rainfall reduction exceeded 15%, due to high mortality of large-sized evergreen trees. Biomass losses persisted when year-long drought recurrence was shorter than 2-7 yr, depending upon soil texture and leaf phenology. From the site-level scenario results, we developed regionally applicable metrics to quantify the Amazon forest's climatological proximity to rainfall regimes likely to cause biomass loss > 20% in 50 yr according to ED2 predictions. Nearly 25% (1.8 million km 2 ) of the Amazon forests could experience frequent droughts and biomass loss if mean annual rainfall or interannual variability changed by 2σ. At least 10% of the high-emission climate projections (CMIP5/RCP8.5 models) predict critically dry regimes over 25% of the Amazon forest area by 2100. © 2018 The Authors. New Phytologist © 2018 New Phytologist Trust.
NASA Astrophysics Data System (ADS)
Baker, P. A.; Fritz, S. C.; Silva, C. G.; Rigsby, C. A.; Absy, M. L.; Almeida, R. P.; Caputo, M.; Chiessi, C. M.; Cruz, F. W.; Dick, C. W.; Feakins, S. J.; Figueiredo, J.; Freeman, K. H.; Hoorn, C.; Jaramillo, C.; Kern, A. K.; Latrubesse, E. M.; Ledru, M. P.; Marzoli, A.; Myrbo, A.; Noren, A.; Piller, W. E.; Ramos, M. I. F.; Ribas, C. C.; Trnadade, R.; West, A. J.; Wahnfried, I.; Willard, D. A.
2015-12-01
This article presents the scientific rationale for an ambitious ICDP drilling project to continuously sample Late Cretaceous to modern sediment in four different sedimentary basins that transect the equatorial Amazon of Brazil, from the Andean foreland to the Atlantic Ocean. The goals of this project are to document the evolution of plant biodiversity in the Amazon forests and to relate biotic diversification to changes in the physical environment, including climate, tectonism, and the surface landscape. These goals require long sedimentary records from each of the major sedimentary basins across the heart of the Brazilian Amazon, which can only be obtained by drilling because of the scarcity of Cenozoic outcrops. The proposed drilling will provide the first long, nearly continuous regional records of the Cenozoic history of the forests, their plant diversity, and the associated changes in climate and environment. It also will address fundamental questions about landscape evolution, including the history of Andean uplift and erosion as recorded in Andean foreland basins and the development of west-to-east hydrologic continuity between the Andes, the Amazon lowlands, and the equatorial Atlantic. Because many modern rivers of the Amazon basin flow along the major axes of the old sedimentary basins, we plan to locate drill sites on the margin of large rivers and to access the targeted drill sites by navigation along these rivers.
Baker, P.A.; Fritz, S.C.; Silva, C.G.; Rigsby, C.A.; Absy, M.L.; Almeida, R.P.; Caputo, Maria C.; Chiessi, C.M.; Cruz, F.W.; Dick, C.W.; Feakins, S.J.; Figueiredo, J.; Freeman, K.H.; Hoorn, C.; Jaramillo, C.A.; Kern, A.; Latrubesse, E.M.; Ledru, M.P.; Marzoli, A.; Myrbo, A.; Noren, A.; Piller, W.E.; Ramos, M.I.F.; Ribas, C.C.; Trinadade, R.; West, A.J.; Wahnfried, I.; Willard, Debra A.
2015-01-01
This article presents the scientific rationale for an ambitious ICDP drilling project to continuously sample Late Cretaceous to modern sediment in four different sedimentary basins that transect the equatorial Amazon of Brazil, from the Andean foreland to the Atlantic Ocean. The goals of this project are to document the evolution of plant biodiversity in the Amazon forests and to relate biotic diversification to changes in the physical environment, including climate, tectonism, and the surface landscape. These goals require long sedimentary records from each of the major sedimentary basins across the heart of the Brazilian Amazon, which can only be obtained by drilling because of the scarcity of Cenozoic outcrops. The proposed drilling will provide the first long, nearly continuous regional records of the Cenozoic history of the forests, their plant diversity, and the associated changes in climate and environment. It also will address fundamental questions about landscape evolution, including the history of Andean uplift and erosion as recorded in Andean foreland basins and the development of west-to-east hydrologic continuity between the Andes, the Amazon lowlands, and the equatorial Atlantic. Because many modern rivers of the Amazon basin flow along the major axes of the old sedimentary basins, we plan to locate drill sites on the margin of large rivers and to access the targeted drill sites by navigation along these rivers.
Richards, Peter D.; Walker, Robert T.; Arima, Eugenio Y.
2014-01-01
Soybean farming has brought economic development to parts of South America, as well as environmental hopes and concerns. A substantial hope resides in the decoupling of Brazil's agricultural sector from deforestation in the Amazon region, in which case expansive agriculture need not imply forest degradation. However, concerns have also been voiced about the potential indirect effects of agriculture. This article addresses these indirect effects forthe case of the Brazilian Amazon since 2002. Our work finds that as much as thirty-two percent of deforestation, or the loss of more than 30,000 km2 of Amazon forest, is attributable, indirectly, to Brazil's soybean sector. However, we also observe that the magnitude of the indirect impact of the agriculture sector on forest loss in the Amazon has declined markedly since 2006. We also find a shift in the underlying causes of indirect land use change in the Amazon, and suggest that land appreciation in agricultural regions has supplanted farm expansions as a source of indirect land use change. Our results are broadly congruent with recent work recognizing the success of policy changes in mitigating the impact of soybean expansion on forest loss in the Amazon. However, they also caution that the soybean sector may continue to incentivize land clearings through its impact on regional land markets. PMID:25492993
Satellite Observation of El Nino Effects on Amazon Forest Phenology and Productivity
NASA Technical Reports Server (NTRS)
Asner, Gregory P.; Townsend, Alan R.; Braswell, Bobby H.
2000-01-01
Climate variability may affect the functioning of Amazon moist tropical forests, and recent modeling analyses suggest that the carbon dynamics of the region vary interannually in response to precipitation and temperature anomalies. However, due to persistent orbital and atmospheric artifacts in the satellite record, remote sensing observations have not provided quantitative evidence that climate variation affects Amazon forest phenology or productivity, We developed a method to minimize and quantify non-biological artifacts in NOAA AVHRR satellite data, providing a record of estimated forest phenological variation from 1982-1993. The seasonal Normalized Difference Vegetation Index (NDVI) amplitude (a proxy for phenology) increased throughout much of the basin during El Nino periods when rainfall was anomalously low. Wetter La Nina episodes brought consistently smaller NDVI amplitudes. Using radiative transfer and terrestrial biogeochemical models driven by these satellite data, we estimate that canopy-energy absorption and net primary production of Amazon forests varied interannually by as much as 21% and 18%, respectively. These results provide large-scale observational evidence for interannual sensitivity to El Nino of plant phenology and carbon flux in Amazon forests.
Spatial Pattern of Standing Timber Value across the Brazilian Amazon
Ahmed, Sadia E.; Ewers, Robert M.
2012-01-01
The Amazon is a globally important system, providing a host of ecosystem services from climate regulation to food sources. It is also home to a quarter of all global diversity. Large swathes of forest are removed each year, and many models have attempted to predict the spatial patterns of this forest loss. The spatial patterns of deforestation are determined largely by the patterns of roads that open access to frontier areas and expansion of the road network in the Amazon is largely determined by profit seeking logging activities. Here we present predictions for the spatial distribution of standing value of timber across the Amazon. We show that the patterns of timber value reflect large-scale ecological gradients, determining the spatial distribution of functional traits of trees which are, in turn, correlated with timber values. We expect that understanding the spatial patterns of timber value across the Amazon will aid predictions of logging movements and thus predictions of potential future road developments. These predictions in turn will be of great use in estimating the spatial patterns of deforestation in this globally important biome. PMID:22590520
Amazon Forests Maintain Consistent Canopy Structure and Greenness During the Dry Season
NASA Technical Reports Server (NTRS)
Morton, Douglas C.; Nagol, Jyoteshwar; Carabajal, Claudia C.; Rosette, Jacqueline; Palace, Michael; Cook, Bruce D.; Vermote, Eric F.; Harding, David J.; North, Peter R. J.
2014-01-01
The seasonality of sunlight and rainfall regulates net primary production in tropical forests. Previous studies have suggested that light is more limiting than water for tropical forest productivity, consistent with greening of Amazon forests during the dry season in satellite data.We evaluated four potential mechanisms for the seasonal green-up phenomenon, including increases in leaf area or leaf reflectance, using a sophisticated radiative transfer model and independent satellite observations from lidar and optical sensors. Here we show that the apparent green up of Amazon forests in optical remote sensing data resulted from seasonal changes in near-infrared reflectance, an artefact of variations in sun-sensor geometry. Correcting this bidirectional reflectance effect eliminated seasonal changes in surface reflectance, consistent with independent lidar observations and model simulations with unchanging canopy properties. The stability of Amazon forest structure and reflectance over seasonal timescales challenges the paradigm of light-limited net primary production in Amazon forests and enhanced forest growth during drought conditions. Correcting optical remote sensing data for artefacts of sun-sensor geometry is essential to isolate the response of global vegetation to seasonal and interannual climate variability.
Amazon forests maintain consistent canopy structure and greenness during the dry season.
Morton, Douglas C; Nagol, Jyoteshwar; Carabajal, Claudia C; Rosette, Jacqueline; Palace, Michael; Cook, Bruce D; Vermote, Eric F; Harding, David J; North, Peter R J
2014-02-13
The seasonality of sunlight and rainfall regulates net primary production in tropical forests. Previous studies have suggested that light is more limiting than water for tropical forest productivity, consistent with greening of Amazon forests during the dry season in satellite data. We evaluated four potential mechanisms for the seasonal green-up phenomenon, including increases in leaf area or leaf reflectance, using a sophisticated radiative transfer model and independent satellite observations from lidar and optical sensors. Here we show that the apparent green up of Amazon forests in optical remote sensing data resulted from seasonal changes in near-infrared reflectance, an artefact of variations in sun-sensor geometry. Correcting this bidirectional reflectance effect eliminated seasonal changes in surface reflectance, consistent with independent lidar observations and model simulations with unchanging canopy properties. The stability of Amazon forest structure and reflectance over seasonal timescales challenges the paradigm of light-limited net primary production in Amazon forests and enhanced forest growth during drought conditions. Correcting optical remote sensing data for artefacts of sun-sensor geometry is essential to isolate the response of global vegetation to seasonal and interannual climate variability.
Chemical modification of semiconductor surfaces
NASA Technical Reports Server (NTRS)
Finklea, H. O.
1981-01-01
Results of research on the chemical modification of TiO2 powders in the gas phase and the examination of the modified powders by infrared absorption spectroscopy are comprehensively summarized. The range of information obtainable by IR spectroscopy of chemically modified semiconductors, and a definition of the optimum reaction conditions for synthesizing a monolayer of methylsilanes using vapor phase reaction conditions were considered.
Chemical variation in Piper aduncum and biological properties of its dillapiole-rich essential oil.
de Almeida, Roseli R P; Souto, Raimundo N P; Bastos, Cleber N; da Silva, Milton H L; Maia, José G S
2009-09-01
The essential oils of the specimens of Piper aduncum that occur in deforested areas of Brazilian Amazon, North Brazil, are rich in dillapiole (35-90%), a derivative of phenylpropene, to which are attributed biological properties. On the other hand, the oils of the specimens with occurrence in the Atlantic Forest, and Northeastern and Southeastern Brazil, do not contain dillapiole, but only terpene compounds such as (E)-nerolidol and linalool. One specimen existing in the Amazon was hydrodistilled. The obtained oil was fractioned on a silica chromatographic column, resulting in fractions rich in dillapiole (95.0-98.9%) utilized for analyses by GC and GC/MS, structural characterization by NMR, confirmation of their biological properties, and to obtain the isomer isodillapiole. Dillapiole showed a fungicide action against the fungus Clinipellis perniciosa (witches' broom) by inhibition of its basidiospores, in concentrations ranging from 0.6 to 1.0 ppm. The larvicide and insecticide actions of dillapiole were tested against the larvae and the adult insects of Anopheles marajoara and Aedes aegypti (malaria and dengue mosquitoes), resulting in mortality of the larvae (48 h, 100%) at a concentration of 100 ppm, and mortality of the insects (30 min, 100%) at a concentration of 600 ppm. The isomeric isodillapiole showed no significant activity in the same biological tests.
Multi-scale assessment of human-induced changes to ...
Context: Land use change and forest degradation have myriad effects on tropical ecosystems. Yet their consequences for low-order streams remain very poorly understood, including in the world´s largest freshwater basin, the Amazon.Objectives: Determine the degree to which physical and chemical characteristics of the instream habitat of low-order Amazonian streams change in response to past local- and catchment-level anthropogenic disturbances. Methods: To do so, we collected field instream habitat (i.e., physical habitat and water quality) and landscape data from 99 stream sites in two eastern Brazilian Amazon regions. We used random forest regression trees to assess the relative importance of different predictor variables in determining changes in instream habitat response variables. Adaptations the USEPA’s National Aquatic Resource Survey (NARS) designs, field methods, and approaches for assessing ecological condition have been applied in state and basin stream surveys throughout the U.S., and also in countries outside of the U.S. These applications not only provide valuable tests of the NARS approaches, but generate new understandings of natural and anthropogenic controls on biota and physical habitat in streams. Results from applications in Brazil, for example, not only aid interpretation of the condition of Brazilian streams, but also refine approaches for interpreting aquatic resource surveys in the U.S. and elsewhere. In this article, the authors des
Towards Efficient Scientific Data Management Using Cloud Storage
NASA Technical Reports Server (NTRS)
He, Qiming
2013-01-01
A software prototype allows users to backup and restore data to/from both public and private cloud storage such as Amazon's S3 and NASA's Nebula. Unlike other off-the-shelf tools, this software ensures user data security in the cloud (through encryption), and minimizes users operating costs by using space- and bandwidth-efficient compression and incremental backup. Parallel data processing utilities have also been developed by using massively scalable cloud computing in conjunction with cloud storage. One of the innovations in this software is using modified open source components to work with a private cloud like NASA Nebula. Another innovation is porting the complex backup to- cloud software to embedded Linux, running on the home networking devices, in order to benefit more users.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Giangrande, Scott E.; Feng, Zhe; Jensen, Michael P.
Routine cloud, precipitation and thermodynamic observations collected by the Atmospheric Radiation Measurement (ARM) Mobile Facility (AMF) and Aerial Facility (AAF) during the 2-year US Department of Energy (DOE) ARM Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5) campaign are summarized. These observations quantify the diurnal to large-scale thermodynamic regime controls on the clouds and precipitation over the undersampled, climatically important Amazon basin region. The extended ground deployment of cloud-profiling instrumentation enabled a unique look at multiple cloud regimes at high temporal and vertical resolution. This longer-term ground deployment, coupled with two short-term aircraft intensive observing periods, allowed new opportunitiesmore » to better characterize cloud and thermodynamic observational constraints as well as cloud radiative impacts for modeling efforts within typical Amazon wet and dry seasons.« less
2005-01-01
Quinnan Jr. M.D., PMB Malaria in South America is a major public health problem. In Brazil, most of the cases occur in the Amazon Region...chain reaction products from DNA extracted from blood smears collected from patients with malaria in the Amazon Region in the 1970s 62 Figure 17...267 1 Hypothesis and Specific Aims In Brazil, malaria is largely restricted to the Amazon Region, and is particularly prevalent in
2006-03-01
Amazon Basin, near Iquitos, Peru , for their suscep- tibility to a subtype IIIC strain of the Venezuelan equine encephalomyelitis complex. This virus...As part of a field ecology study of mosquitoes in the Amazon Basin region of Peru (Jones et al. 2004), over 160 virus isolations were made from...distribution unlimited 13. SUPPLEMENTARY NOTES 14. ABSTRACT We evaluated mosquitoes collected in the Amazon Basin, near Iquitos, Peru , for their
2010-12-14
Parasitology in the Amazon city of Iquitos, Peru , where NAMRU-6 has 90 permanent field and laboratory staff. Over 10 years of research have focused on...laboratory in Iquitos, Peru , a city of approximately 380,000 people (INEI 2008) in the Amazon Basin (Figures 3 and 4). The mission of NAMRU-6 is... Amazon Malaria Initiative and a military-to-military training program in Peru , Ecuador, and Colombia (Figure 5). NAMRU-6 Entomology has been
2009-08-01
therapeutic efficacy of SP in two locations in the Amazon rainforest region of Peru, and to correlate the presence of molecular markers associated with...pyrimethamine at two locations in the Peruvian Amazon enrolling 99 patients of which, 86 patients completed the protocol specified 28 day follow up. Our...the Amazon basin, it may be possible to predict treatment failure with sulfadoxine- pyrimethamine equally well by determination of either of the
The Amazon, measuring a mighty river
,
1967-01-01
The Amazon, the world's largest river, discharges enough water into the sea each day to provide fresh water to the City of New York for over 9 years. Its flow accounts for about 15 percent of all the fresh water discharged into the oceans by all the rivers of the world. By comparison, the Amazon's flow is over 4 times that of the Congo River, the world's second largest river. And it is 10 times that of the Mississippi, the largest river on the North American Continent.
Hallux amputation after a freshwater stingray injury in the Brazilian Amazon.
Monteiro, Wuelton Marcelo; Oliveira, Sâmella Silva de; Sachett, Jacqueline de Almeida Gonçalves; Silva, Iran Mendonça da; Ferreira, Luiz Carlos de Lima; Lacerda, Marcus Vinícius Guimarães
2016-01-01
Freshwater stingray injuries are a common problem in the Brazilian Amazon, affecting mostly riverine and indigenous populations. These injuries cause severe local and regional pain, swelling and erythema, as well as complications, such as local necrosis and bacterial infection. Herein, we report a case of bacterial infection and hallux necrosis, after a freshwater stingray injury in the Brazilian Amazon, which eventually required amputation. Different antimicrobial regimens were administered at different stages of the disease; however, avoiding amputation through effective treatment was not achieved.
Climatic and ecological future of the Amazon: likelihood and causes of change
NASA Astrophysics Data System (ADS)
Cook, B.; Zeng, N.; Yoon, J.-H.
2010-05-01
Some recent climate modeling results suggested a possible dieback of the Amazon rainforest under future climate change, a prediction that raised considerable interest as well as controversy. To determine the likelihood and causes of such changes, we analyzed the output of 15 models from the Intergovernmental Panel on Climate Change Fourth Assessment Report (IPCC/AR4) and a dynamic vegetation model VEGAS driven by these climate output. Our results suggest that the core of the Amazon rainforest should remain largely stable as rainfall is projected to increase in nearly all models. However, the periphery, notably the southern edge of the Amazon and further south in central Brazil, are in danger of drying out, driven by two main processes. Firstly, a decline in precipitation of 22% in the southern Amazon's dry season (May-September) reduces soil moisture, despite an increase in precipitation during the wet season, due to nonlinear responses in hydrology and ecosystem dynamics. Two dynamical mechanisms may explain the lower dry season rainfall: (1) a general subtropical drying under global warming when the dry season southern Amazon is under the control of the subtropical high pressure; (2) a stronger north-south tropical Atlantic sea surface temperature gradient, and to lesser degree a warmer eastern equatorial Pacific. Secondly, evaporation demand will increase due to the general warming, further reducing soil moisture. In terms of ecosystem response, higher maintenance cost and reduced productivity under warming may also have additional adverse impact. The drying corresponds to a lengthening of the dry season by 11 days. As a consequence, the median of the models projects a reduction of 20% in vegetation carbon stock in the southern Amazon, central Brazil, and parts of the Andean Mountains. Further, VEGAS predicts enhancement of fire risk by 10-15%. The increase in fire is primarily due to the reduction in soil moisture, and the decrease in dry season rainfall, which is when fire danger reaches its peak. Because the southern Amazon is also under intense human influence as a result of deforestation and land use, added pressure to the region's ecosystems from climate change may subject the region to profound changes in the 21st century.
Carbon uptake by mature Amazon forests has mitigated Amazon nations' carbon emissions.
Phillips, Oliver L; Brienen, Roel J W
2017-12-01
Several independent lines of evidence suggest that Amazon forests have provided a significant carbon sink service, and also that the Amazon carbon sink in intact, mature forests may now be threatened as a result of different processes. There has however been no work done to quantify non-land-use-change forest carbon fluxes on a national basis within Amazonia, or to place these national fluxes and their possible changes in the context of the major anthropogenic carbon fluxes in the region. Here we present a first attempt to interpret results from ground-based monitoring of mature forest carbon fluxes in a biogeographically, politically, and temporally differentiated way. Specifically, using results from a large long-term network of forest plots, we estimate the Amazon biomass carbon balance over the last three decades for the different regions and nine nations of Amazonia, and evaluate the magnitude and trajectory of these differentiated balances in relation to major national anthropogenic carbon emissions. The sink of carbon into mature forests has been remarkably geographically ubiquitous across Amazonia, being substantial and persistent in each of the five biogeographic regions within Amazonia. Between 1980 and 2010, it has more than mitigated the fossil fuel emissions of every single national economy, except that of Venezuela. For most nations (Bolivia, Colombia, Ecuador, French Guiana, Guyana, Peru, Suriname) the sink has probably additionally mitigated all anthropogenic carbon emissions due to Amazon deforestation and other land use change. While the sink has weakened in some regions since 2000, our analysis suggests that Amazon nations which are able to conserve large areas of natural and semi-natural landscape still contribute globally-significant carbon sequestration. Mature forests across all of Amazonia have contributed significantly to mitigating climate change for decades. Yet Amazon nations have not directly benefited from providing this global scale ecosystem service. We suggest that better monitoring and reporting of the carbon fluxes within mature forests, and understanding the drivers of changes in their balance, must become national, as well as international, priorities.
Soluble iron nutrients in Saharan dust over the central Amazon rainforest
NASA Astrophysics Data System (ADS)
Rizzolo, Joana A.; Barbosa, Cybelli G. G.; Borillo, Guilherme C.; Godoi, Ana F. L.; Souza, Rodrigo A. F.; Andreoli, Rita V.; Manzi, Antônio O.; Sá, Marta O.; Alves, Eliane G.; Pöhlker, Christopher; Angelis, Isabella H.; Ditas, Florian; Saturno, Jorge; Moran-Zuloaga, Daniel; Rizzo, Luciana V.; Rosário, Nilton E.; Pauliquevis, Theotonio; Santos, Rosa M. N.; Yamamoto, Carlos I.; Andreae, Meinrat O.; Artaxo, Paulo; Taylor, Philip E.; Godoi, Ricardo H. M.
2017-02-01
The intercontinental transport of aerosols from the Sahara desert plays a significant role in nutrient cycles in the Amazon rainforest, since it carries many types of minerals to these otherwise low-fertility lands. Iron is one of the micronutrients essential for plant growth, and its long-range transport might be an important source for the iron-limited Amazon rainforest. This study assesses the bioavailability of iron Fe(II) and Fe(III) in the particulate matter over the Amazon forest, which was transported from the Sahara desert (for the sake of our discussion, this term also includes the Sahel region). The sampling campaign was carried out above and below the forest canopy at the ATTO site (Amazon Tall Tower Observatory), a near-pristine area in the central Amazon Basin, from March to April 2015. Measurements reached peak concentrations for soluble Fe(III) (48 ng m-3), Fe(II) (16 ng m-3), Na (470 ng m-3), Ca (194 ng m-3), K (65 ng m-3), and Mg (89 ng m-3) during a time period of dust transport from the Sahara, as confirmed by ground-based and satellite remote sensing data and air mass backward trajectories. Dust sampled above the Amazon canopy included primary biological aerosols and other coarse particles up to 12 µm in diameter. Atmospheric transport of weathered Saharan dust, followed by surface deposition, resulted in substantial iron bioavailability across the rainforest canopy. The seasonal deposition of dust, rich in soluble iron, and other minerals is likely to assist both bacteria and fungi within the topsoil and on canopy surfaces, and especially benefit highly bioabsorbent species. In this scenario, Saharan dust can provide essential macronutrients and micronutrients to plant roots, and also directly to plant leaves. The influence of this input on the ecology of the forest canopy and topsoil is discussed, and we argue that this influence would likely be different from that of nutrients from the weathered Amazon bedrock, which otherwise provides the main source of soluble mineral nutrients.
The Amazon forest-rainfall feedback: the roles of transpiration and interception
NASA Astrophysics Data System (ADS)
Dekker, Stefan; Staal, Arie; Tuinenburg, Obbe
2017-04-01
In the Amazon, deep-rooted trees increase local transpiration and high tree cover increase local interception evaporation. These increased local evapotranspiration fluxes to the atmosphere have both positive effects on forests down-wind, as they stimulate rainfall. Although important for the functioning of the Amazon, we have an inadequate assessment on the strength and the timing of these forest-rainfall feedbacks. In this study we (i) estimate local forest transpiration and local interception evaporation, (ii) simulate the trajectories of these moisture flows through the atmosphere and (iii) quantify their contributions to the forest-rainfall feedback for the whole Amazon basin. To determine the atmospheric moisture flows in tropical South America we use a Lagrangian moisture tracking algorithm on 0.25° (c. 25 km) resolution with eight atmospheric layers on a monthly basis for the period 2003-2015. With our approach we account for multiple re-evaporation cycles of this moisture. We also calculate for each month the potential effects of forest loss on evapotranspiration. Combined, these calculations allow us to simulate the effects of land-cover changes on rainfall in downwind areas and estimate the effect on the forest. We found large regional and temporal differences in the importance how forest contribute to rainfall. The transpiration-rainfall feedback is highly important during the dry season. Between September-November, when large parts of the Amazon are at the end of the dry season, more than 50% of the rainfall is caused by the forests upstream. This means that droughts in the Amazon are alleviated by the forest. Furthermore, we found that much moisture cycles several times during its trajectory over the Amazon. After one evapotranspiration-rainfall cycle, more than 40% of the moisture is re-evaporated again. The interception-evaporation feedback is less important during droughts. Finally from our analysis, we show that the forest-rainfall feedback is essential for the resilience of the south-western and northern parts of the Amazon forest. Without the forest-rainfall feedbacks, these forest wouldn't exist.
Remote sensing in forestry: Application to the Amazon region
NASA Technical Reports Server (NTRS)
Dejesusparada, N. (Principal Investigator); Tardin, A. T.; Dossantos, A.; Filho, P. H.; Shimabukuro, Y. E.
1981-01-01
The utilization of satellite remote sensing in forestry is reviewed with emphasis on studies performed for the Brazilian Amazon Region. Timber identification, deforestation, and pasture degradation after deforestation are discussed.
2014-02-20
spectroscopy was applied to investigate such structures of peptides immobilized on self-assembled monolayers (SAMs). Here cysteine-modified antimicrobial ...modified antimicrobial peptide cecropin P1 (CP1) was chemically immobilized onto SAM with a maleimide terminal group. Two important characteristics...applied to investigate such structures of peptides immobilized on self-assembled monolayers (SAMs). Here cysteine-modified antimicrobial peptide cecropin
Thin-film chemical sensors based on electron tunneling
NASA Technical Reports Server (NTRS)
Khanna, S. K.; Lambe, J.; Leduc, H. G.; Thakoor, A. P.
1985-01-01
The physical mechanisms underlying a novel chemical sensor based on electron tunneling in metal-insulator-metal (MIM) tunnel junctions were studied. Chemical sensors based on electron tunneling were shown to be sensitive to a variety of substances that include iodine, mercury, bismuth, ethylenedibromide, and ethylenedichloride. A sensitivity of 13 parts per billion of iodine dissolved in hexane was demonstrated. The physical mechanisms involved in the chemical sensitivity of these devices were determined to be the chemical alteration of the surface electronic structure of the top metal electrode in the MIM structure. In addition, electroreflectance spectroscopy (ERS) was studied as a complementary surface-sensitive technique. ERS was shown to be sensitive to both iodine and mercury. Electrolyte electroreflectance and solid-state MIM electroreflectance revealed qualitatively the same chemical response. A modified thin-film structure was also studied in which a chemically active layer was introduced at the top Metal-Insulator interface of the MIM devices. Cobalt phthalocyanine was used for the chemically active layer in this study. Devices modified in this way were shown to be sensitive to iodine and nitrogen dioxide. The chemical sensitivity of the modified structure was due to conductance changes in the active layer.
NASA Astrophysics Data System (ADS)
Guerra, Denis L.; Leidens, Victor L.; Viana, Rúbia R.; Airoldi, Claudio
2010-05-01
The compound N 1-[3-(trimethoxysilyl)propyl]diethylenetriamine was anchored onto Amazon kaolinite surface by heterogeneous route. The modified and natural kaolinite samples were characterized by transmission electron microscopy, scanning electron microscopic, X-ray diffraction, and nuclear magnetic nuclei of 29Si and 13C. The well-defined peaks obtained in the 13C NMR spectrum in the 5.0-62.1 ppm region confirmed the attachment of organic functional groups as pendant chains bonded into the porous clay. The ability of these materials to remove U(VI) from aqueous solution was followed by a series of adsorption isotherms adjusted to a Sips equation at room temperature and pH 4.0. The kinetic parameters analyzed by the Lagergren and Elovich models gave a good fit for a pseudo-second order reaction with k2 values 16.0 and 25.1 mmol g -1 min -1 ranges for natural and modified kaolinite clays, respectively. The energetic effects caused by metal ion adsorption were determined through calorimetric titrations.
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From where does the Amazon forest gets its water?
NASA Astrophysics Data System (ADS)
Miguez-Macho, G.; Fan, Y.
2016-12-01
The Amazon receives abundant annual rainfall but parts of it experience a multi-month dry season. Here we ask: what is the water source that sustains the dry-season ET? Where over the Amazon it is largely local and recent rain (hence ET shutting down in dry season), or past rain that is stored in the deep soils and the groundwater (deep roots tapping deep reservoirs sustaining ET), or is it rain that fell on higher grounds (through topography-driven lateral convergence)? Using synthesis of isotope and other tracer observations and basin-wide inverse modeling (shallow soil, deep soil, with and without groundwater, with and without dynamic rooting depth), we attempt to tease out these components. The results shed light on likely ET sources and how future global change may preferentially impact Amazon ecosystem functioning.
Tucker Lima, Joanna M; Valle, Denis; Moretto, Evandro Mateus; Pulice, Sergio Mantovani Paiva; Zuca, Nadia Lucia; Roquetti, Daniel Rondinelli; Beduschi, Liviam Elizabeth Cordeiro; Praia, Amanda Salles; Okamoto, Claudia Parucce Franco; da Silva Carvalhaes, Vinicius Leite; Branco, Evandro Albiach; Barbezani, Bruna; Labandera, Emily; Timpe, Kelsie; Kaplan, David
2016-08-30
Recognized as one of the world's most vital natural and cultural resources, the Amazon faces a wide variety of threats from natural resource and infrastructure development. Within this context, rigorous scientific study of the region's complex social-ecological system is critical to inform and direct decision-making toward more sustainable environmental and social outcomes. Given the Amazon's tightly linked social and ecological components and the scope of potential development impacts, effective study of this system requires an easily accessible resource that provides a broad and reliable data baseline. This paper brings together multiple datasets from diverse disciplines (including human health, socio-economics, environment, hydrology, and energy) to provide investigators with a variety of baseline data to explore the multiple long-term effects of infrastructure development in the Brazilian Amazon.
Flooding dynamics on the lower Amazon floodplain
NASA Astrophysics Data System (ADS)
Rudorff, C.; Melack, J. M.; Bates, P. D.
2013-05-01
We analyzed flooding dynamics of a large floodplain lake in the lower reach of the Amazon River for the period between 1995 through 2010. Floodplain inundation was simulated using the LISFLOOD-FP model, which combines one-dimensional river routing with two-dimensional overland flow, and a local hydrological model. Accurate representation of floodplain flows and inundation extent depends on the quality of the digital elevation model (DEM). We combined digital topography (derived from the Shuttle Radar Topography Mission) with extensive floodplain echo-sounding data to generate a hydraulically sound DEM. Analysis of daily water balances revealed that the dominant source of inflow alternated seasonally among direct rain and local runoff (October through January), Amazon River (March through August), and seepage (September). As inflows from the Amazon River increase during the rising limb of the hydrograph, regional floodwaters encounter the floodplain partially inundated from local hydrological inputs. At peak flow the floodplain routes, on average, 2.5% of the total discharge for this reach. The falling limb of the hydrograph coincides with the locally dry period, allowing seepage of water stored in sediments to become a dominant source. The average annual inflow from the Amazon River was 58.8 km3 (SD = 33.5), representing more than three thirds (80%) of inputs from all sources, with substantial inter-annual variability. The average annual net export of water from the floodplain to the Amazon River was 7.9 km3 (SD = 2.7).
Impacts of land-use and land-cover change on stream hydrochemistry in the Cerrado and Amazon biomes.
Nóbrega, Rodolfo L B; Guzha, Alphonce C; Lamparter, Gabriele; Amorim, Ricardo S S; Couto, Eduardo G; Hughes, Harold J; Jungkunst, Hermann F; Gerold, Gerhard
2018-09-01
Studies on the impacts of land-use and land-cover change on stream hydrochemistry in active deforestation zones of the Amazon agricultural frontier are limited and have often used low-temporal-resolution datasets. Moreover, these impacts are not concurrently assessed in well-established agricultural areas and new deforestations hotspots. We aimed to identify these impacts using an experimental setup to collect high-temporal-resolution hydrological and hydrochemical data in two pairs of low-order streams in catchments under contrasting land use and land cover (native vegetation vs. pasture) in the Amazon and Cerrado biomes. Our results indicate that the conversion of natural landscapes to pastures increases carbon and nutrient fluxes via streamflow in both biomes. These changes were the greatest in total inorganic carbon in the Amazon and in potassium in the Cerrado, representing a 5.0- and 5.5-fold increase in the fluxes of each biome, respectively. We found that stormflow, which is often neglected in studies on stream hydrochemistry in the tropics, plays a substantial role in the carbon and nutrient fluxes, especially in the Amazon biome, as its contributions to hydrochemical fluxes are mostly greater than the volumetric contribution to the total streamflow. These findings demonstrate that assessments of the impacts of deforestation in the Amazon and Cerrado biomes should also take into account rapid hydrological pathways; however, this can only be achieved through collection of high-temporal-resolution data. Copyright © 2018 Elsevier B.V. All rights reserved.
Deforestation, fire susceptibility, and potential tree responses to fire in the eastern Amazon
DOE Office of Scientific and Technical Information (OSTI.GOV)
Uhl, C.; Kauffman, J.B.
1990-04-01
In the state of Para, Brazil, in the eastern Amazon, the authors studied the potential for sustained fire events within four dominant vegetation cover types (undisturbed rain forest, selectively logged forest, second-growth forest, and open pasture), by measuring fuel availability, microclimate, and rates of fuel moisture loss. They also estimated the potential tree mortality that might result from a wide-scale Amazon forest fire by measuring the thermal properties of bark for all trees in a 5-ha stand of mature forest, followed by measurements of heat flux through bark during simulated fires. In pastures the average midday temperature was almost 10{degree}Cmore » greater and the average midday relative humidity was 30% lower than in primary forest. The most five-prone ecosystem was the open pasture followed by selectively logged forest, second growth forest, and undisturbed rain forest in which sustained combustion was not possible even after prolonged rainless periods. Even though the autogenic factors in primary forest of the eastern Amazon create a microclimate that virtually eliminates the probability of fire, they are currently a common event in disturbed areas of Amazonia. As many as 8 {times} 10{sup 6} ha burned in the Amazon Basin of Brazil in 1987 alone. In terms of current land-use patterns, altered microclimates, and fuel mass, there are also striking similarities between the eastern Amazon and East Kalimantan, Indonesia (the site of recent rain forest wildfires that burned 3.5 {times} 10{sup 6} ha).« less
NASA Astrophysics Data System (ADS)
Gerken, T.; Chamecki, M.; Fuentes, J. D.; Stoy, P. C.; Trowbridge, A.; Wei, D.
2016-12-01
The Amazon rainforest and other rainforests emit large quantities of biogenic volatile organic compounds (BVOCs), including isoprene and monoterpenes, which react with and produce atmospheric oxidants such as ozone and the hydroxyl radical. Some of the resulting reaction products condense to form secondary organic aerosols, which due to the typically clean tropical air can make up a large portion of the total atmospheric aerosols and may thus impact cloud development and regional climate. To better understand the role of tropical forests on cloud development and climate, it is necessary to quantify not only BVOC emissions, but also turbulent transport and the resulting atmospheric chemistry within both the forest canopy and atmospheric boundary-layer. To date, most research has ignored within-canopy chemical processes that are typically not resolved in regional models that treat the forest as a lower boundary condition. We use canopy-resolving Large Eddy Simulation (LES) to study the role of turbulence and chemistry in the isoprene lifetime under conditions observed during a 2014 field campaign in central Amazonia. The LES includes a simple chemical mechanism for the oxidation of isoprene and aggregated monoterpenes (34 reactions), which we use to quantify the impact of within-canopy and boundary-layer processes on the transport and air chemistry of isoprene, monoterpenes, and primary reaction products on their export at the top of the boundary layer. LES results show air parcel residence times in the dense Amazon rainforest, which govern the time available for in-canopy reactions, to range from a few seconds near the canopy top to 30 minutes near the ground. Such residence times are comparable to chemical lifetimes of many reactive species and the convective eddy turnover timescale. Additionally, monoterpene oxidation with ambient ozone levels can increase within-canopy hydroxyl radical concentrations from 5 x 104 to 3 x 105 radicals cm-3, thus greatly increasing the oxidative capacity of the near surface air; within-canopy oxidation is significant for isoprene (5%) and monoterpene chemistry (25%). Results demonstrate that monoterpene chemistry - in addition to isoprene chemistry - needs to be considered when investigating the role of BVOCs to surface-atmosphere interactions in tropical rainforests.
Chemical treatment of the intra-canal dentin surface: a new approach to modify dentin hydrophobicity
GAITAN-FONSECA, Cesar; COLLART-DUTILLEUL, Pierre-Yves; SEMETEY, Vincent; ROMIEU, Olivier; CRUZ, Roel; FLORES, Hector; CUISINIER, Frédéric; PÉREZ, Elías; POZOS-GUILLEN, Amaury
2013-01-01
Objective: This study evaluated the hydrophobicity of dentin surfaces that were modified through chemical silanization with octadecyltrichlorosilane (OTS). Material and Methods: An in vitro experimental study was performed using 40 human permanent incisors that were divided into the following two groups: non-silanized and silanized. The specimens were pretreated and chemically modified with OTS. After the chemical modification, the dentin hydrophobicity was examined using a water contact angle measurement (WCA). The effectiveness of the modification of hydrophobicity was verified by the fluid permeability test (FPT). Results and Conclusions: Statistically significant differences were found in the values of WCA and FPT between the two groups. After silanization, the hydrophobic intraradicular dentin surface exhibited in vitro properties that limit fluid penetration into the sealed root canal. This chemical treatment is a new approach for improving the sealing of the root canal system. PMID:23559114
Macedo, Rodrigo S; Teixeira, Wenceslau G; Corrêa, Marcelo M; Martins, Gilvan C; Vidal-Torrado, Pablo
2017-01-01
Anthrosols known as Amazonian Dark Earth (ADE) have borne witness to the intensification of sedentary patterns and the demographic increase in Central Amazon. As a result, a recurring pattern has been observed of mounds with ADE arising from domestic activities and the disposal of waste. The objective of this research was to demonstrate the relationship of these anthropic activities with pedogenetic formation processes of ADE in the municipality of Iranduba, Brazil. Disturbed and undisturbed soil samples were taken from two areas of ADE (pretic horizon) and from a non-anthropic pedon. Physical, chemical, micromorphological and SEM-EDS analyses were performed. The coarse material of the pretic horizons consisted predominantly of quartz, iron nodules, ceramics and charcoal fragments, and the fine material is organo-mineral. There was a direct relationship between the color of pretic horizons and the number of charcoal fragments. The thickness of the ADE results from the redistribution of charcoal at depth through bioturbation, transforming subsurface horizons into anthropic horizons. ADE presents granular microaggregates of geochemical and zoogenetic origin. Degradation of iron nodules is intensified in pretic horizons, promoting a reverse pedogenic process contributing to the xanthization process. Surprisingly the anthropic activities also favor clay dispersion and argilluviation; clay coatings on the ceramic fragments and in the pores demonstrate that this is a current process. Processes identified as contributing to ADE genesis included: i) addition of organic residues and ceramic artifacts (cumulization) with the use of fire; ii) mechanical action of humans, roots and macrofauna (bioturbation); iii) melanization of deeper horizons as a result of bioturbation; iv) argilluviation and degradation of iron nodules. This study offers new support to archaeological research in respect to ADE formation processes in Central Amazon and confirmed the hypothesis that ancient anthropic activities may trigger and/or accelerate pedogenetic processes previously credited only to natural causes.
NASA Astrophysics Data System (ADS)
Goes, Joaquim I.; Gomes, Helga do Rosario; Chekalyuk, Alexander M.; Carpenter, Edward J.; Montoya, Joseph P.; Coles, Victoria J.; Yager, Patricia L.; Berelson, William M.; Capone, Douglas G.; Foster, Rachel A.; Steinberg, Deborah K.; Subramaniam, Ajit; Hafez, Mark A.
2014-01-01
An Advanced Laser Fluorometer (ALF) capable of discriminating several phytoplankton pigment types was utilized in conjunction with microscopic data to map the distribution of phytoplankton communities in the Amazon River plume in May-June-2010, when discharge from the river was at its peak. Cluster analysis and Non-metric Multi-Dimensional Scaling (NMDS) helped distinguish three distinct biological communities that separated largely on the basis of salinity gradients across the plume. These three communities included an "estuarine type" comprised of a high biomass mixed population of diatoms, cryptophytes and green-water Synechococcus spp. located upstream of the plume, a "mesohaline type" made up largely of communities of Diatom-Diazotroph Associations (DDAs) and located in the northwestern region of the plume and an "oceanic type" in the oligotrophic waters outside of the plume made up of Trichodesmium and Synechococcus spp. Although salinity appeared to have a substantial influence on the distribution of different phytoplankton groups, ALF and microscopic measurements examined in the context of the hydro-chemical environment of the river plume, helped establish that the phytoplankton community structure and distribution were strongly controlled by inorganic nitrate plus nitrite (NO3 + NO2) availability whose concentrations were low throughout the plume. Towards the southern, low-salinity region of the plume, NO3 + NO2 supplied by the onshore flow of subsurface (∼80 m depth) water, ensured the continuous sustenance of the mixed phytoplankton bloom. The large drawdown of SiO3 and PO4 associated with this "estuarine type" mixed bloom at a magnitude comparable to that observed for DDAs in the mesohaline waters, leads us to contend that, diatoms, cryptophytes and Synechococcus spp., fueled by the offshore influx of nutrients also play an important role in the cycling of nutrients in the Amazon River plume.
Aerosol profiling with lidar in the Amazon Basin during the wet and dry season
NASA Astrophysics Data System (ADS)
Baars, H.; Ansmann, A.; Althausen, D.; Engelmann, R.; Heese, B.; Müller, D.; Artaxo, P.; Paixao, M.; Pauliquevis, T.; Souza, R.
2012-11-01
For the first time, multiwavelength polarization Raman lidar observations of optical and microphysical particle properties over the Amazon Basin are presented. The fully automated advanced Raman lidar was deployed 60 km north of Manaus, Brazil (2.5°S, 60°W) in the Amazon rain forest from January to November 2008. The measurements thus cover both the wet season (Dec-June) and the dry or burning season (July-Nov). Two cases studies of young and aged smoke plumes are discussed in terms of spectrally resolved optical properties (355, 532, and 1064 nm) and further lidar products such as particle effective radius and single-scattering albedo. These measurement examples confirm that biomass burning aerosols show a broad spectrum of optical, microphysical, and chemical properties. The statistical analysis of the entire measurement period revealed strong differences between the pristine wet and the polluted dry season. African smoke and dust advection frequently interrupt the pristine phases during the wet season. Compared to pristine wet season conditions, the particle scattering coefficients in the lowermost 2 km of the atmosphere were found to be enhanced, on average, by a factor of 4 during periods of African aerosol intrusion and by a factor of 6 during the dry (burning) season. Under pristine conditions, the particle extinction coefficients and optical depth for 532 nm wavelength were frequently as low as 10-30 Mm-1 and <0.05, respectively. During the dry season, biomass burning smoke plumes reached to 3-5 km height and caused a mean optical depth at 532 nm of 0.26. On average during that season, particle extinction coefficients (532 nm) were of the order of 100 Mm-1 in the main pollution layer (up to 2 km height). Ångström exponents were mainly between 1.0 and 1.5, and the majority of the observed lidar ratios were between 50-80 sr.
Roumy, Vincent; Gutierrez-Choquevilca, Andréa-Luz; Lopez Mesia, Jean Pierre; Ruiz, Lastenia; Ruiz Macedo, Juan Celidonio; Abedini, Amin; Landoulsi, Ameni; Samaillie, Jennifer; Hennebelle, Thierry; Rivière, Céline; Neut, Christel
2015-01-01
Context: Our survey was performed near Iquitos (Peruvian Amazon) and its surroundings and leads us to consider Mestizo ethnomedical practices. The plant species reported here are traditionally used for ailments related to microbial infections. Inhabitants of various ethnic origins were interviewed, and 52 selected plants extracts were evaluated for their antimicrobial properties against a panel of 36 sensitive and multi-resistant bacteria or yeast. The study aimed at providing information on antimicrobial plant extract activities and the ethnomedical context of Mestizo riverine populations from Loreto (Peru). Material and Method: The minimum inhibitory concentrations (MICs) of the plant crude extracts were carried out using the agar dilution method and ranged between 0.075 and 5.0 mg/ml. Results: Of the 40 plants analyzed, 9 species showed MIC ≤0.3 mg/ml (Anacardium occidentale, Couroupita guianensis, Croton lechleri, Davilla rugosa, Erythrina amazonica, Jacaranda copaia subsp. Spectabilis, Oenocarpus bataua, Peperomia macrostachya, and Phyllanthus urinaria) for one or several of the 36 microorganisms and only 6 drug extracts were inactive. Among the 40 plants, 13 were evaluated for the first time for an antibacterial activity. Conclusion: This evaluation of the antimicrobial activity of 40 plants using an approved standard methodology allowed comparing those activities against various microbes to establish antimicrobial spectra of standardized plant extracts, and give support to the traditional use of these plants. It may also help discovering new chemical classes of antimicrobial agents that could serve against multi-resistant bacteria. SUMMARY This study leads us to consider Mestizo ethnomedical practices near Iquitos (Peruvian Amazon) and its surroundings. The plant species reported here are traditionally used for ailments related to microbial infections. 52 selected plants extracts were evaluated for their antimicrobial properties against a panel of 36 sensitive and multi resistant bacteria or yeast. The study aimed at providing information on antimicrobial plant extract activities and the ethnomedical context of Mestizo riverine populations from Loreto. PMID:27013805
Roumy, Vincent; Gutierrez-Choquevilca, Andréa-Luz; Lopez Mesia, Jean Pierre; Ruiz, Lastenia; Ruiz Macedo, Juan Celidonio; Abedini, Amin; Landoulsi, Ameni; Samaillie, Jennifer; Hennebelle, Thierry; Rivière, Céline; Neut, Christel
2015-10-01
Our survey was performed near Iquitos (Peruvian Amazon) and its surroundings and leads us to consider Mestizo ethnomedical practices. The plant species reported here are traditionally used for ailments related to microbial infections. Inhabitants of various ethnic origins were interviewed, and 52 selected plants extracts were evaluated for their antimicrobial properties against a panel of 36 sensitive and multi-resistant bacteria or yeast. The study aimed at providing information on antimicrobial plant extract activities and the ethnomedical context of Mestizo riverine populations from Loreto (Peru). The minimum inhibitory concentrations (MICs) of the plant crude extracts were carried out using the agar dilution method and ranged between 0.075 and 5.0 mg/ml. Of the 40 plants analyzed, 9 species showed MIC ≤0.3 mg/ml (Anacardium occidentale, Couroupita guianensis, Croton lechleri, Davilla rugosa, Erythrina amazonica, Jacaranda copaia subsp. Spectabilis, Oenocarpus bataua, Peperomia macrostachya, and Phyllanthus urinaria) for one or several of the 36 microorganisms and only 6 drug extracts were inactive. Among the 40 plants, 13 were evaluated for the first time for an antibacterial activity. This evaluation of the antimicrobial activity of 40 plants using an approved standard methodology allowed comparing those activities against various microbes to establish antimicrobial spectra of standardized plant extracts, and give support to the traditional use of these plants. It may also help discovering new chemical classes of antimicrobial agents that could serve against multi-resistant bacteria. This study leads us to consider Mestizo ethnomedical practices near Iquitos (Peruvian Amazon) and its surroundings. The plant species reported here are traditionally used for ailments related to microbial infections. 52 selected plants extracts were evaluated for their antimicrobial properties against a panel of 36 sensitive and multi resistant bacteria or yeast. The study aimed at providing information on antimicrobial plant extract activities and the ethnomedical context of Mestizo riverine populations from Loreto.
Macedo, Rodrigo S.; Teixeira, Wenceslau G.; Corrêa, Marcelo M.; Martins, Gilvan C.
2017-01-01
Anthrosols known as Amazonian Dark Earth (ADE) have borne witness to the intensification of sedentary patterns and the demographic increase in Central Amazon. As a result, a recurring pattern has been observed of mounds with ADE arising from domestic activities and the disposal of waste. The objective of this research was to demonstrate the relationship of these anthropic activities with pedogenetic formation processes of ADE in the municipality of Iranduba, Brazil. Disturbed and undisturbed soil samples were taken from two areas of ADE (pretic horizon) and from a non-anthropic pedon. Physical, chemical, micromorphological and SEM-EDS analyses were performed. The coarse material of the pretic horizons consisted predominantly of quartz, iron nodules, ceramics and charcoal fragments, and the fine material is organo-mineral. There was a direct relationship between the color of pretic horizons and the number of charcoal fragments. The thickness of the ADE results from the redistribution of charcoal at depth through bioturbation, transforming subsurface horizons into anthropic horizons. ADE presents granular microaggregates of geochemical and zoogenetic origin. Degradation of iron nodules is intensified in pretic horizons, promoting a reverse pedogenic process contributing to the xanthization process. Surprisingly the anthropic activities also favor clay dispersion and argilluviation; clay coatings on the ceramic fragments and in the pores demonstrate that this is a current process. Processes identified as contributing to ADE genesis included: i) addition of organic residues and ceramic artifacts (cumulization) with the use of fire; ii) mechanical action of humans, roots and macrofauna (bioturbation); iii) melanization of deeper horizons as a result of bioturbation; iv) argilluviation and degradation of iron nodules. This study offers new support to archaeological research in respect to ADE formation processes in Central Amazon and confirmed the hypothesis that ancient anthropic activities may trigger and/or accelerate pedogenetic processes previously credited only to natural causes. PMID:28542442
Aerosol characteristics and particle production in the upper troposphere over the Amazon Basin
NASA Astrophysics Data System (ADS)
Andreae, Meinrat O.; Afchine, Armin; Albrecht, Rachel; Amorim Holanda, Bruna; Artaxo, Paulo; Barbosa, Henrique M. J.; Borrmann, Stephan; Cecchini, Micael A.; Costa, Anja; Dollner, Maximilian; Fütterer, Daniel; Järvinen, Emma; Jurkat, Tina; Klimach, Thomas; Konemann, Tobias; Knote, Christoph; Krämer, Martina; Krisna, Trismono; Machado, Luiz A. T.; Mertes, Stephan; Minikin, Andreas; Pöhlker, Christopher; Pöhlker, Mira L.; Pöschl, Ulrich; Rosenfeld, Daniel; Sauer, Daniel; Schlager, Hans; Schnaiter, Martin; Schneider, Johannes; Schulz, Christiane; Spanu, Antonio; Sperling, Vinicius B.; Voigt, Christiane; Walser, Adrian; Wang, Jian; Weinzierl, Bernadett; Wendisch, Manfred; Ziereis, Helmut
2018-01-01
Airborne observations over the Amazon Basin showed high aerosol particle concentrations in the upper troposphere (UT) between 8 and 15 km altitude, with number densities (normalized to standard temperature and pressure) often exceeding those in the planetary boundary layer (PBL) by 1 or 2 orders of magnitude. The measurements were made during the German-Brazilian cooperative aircraft campaign ACRIDICON-CHUVA, where ACRIDICON stands for Aerosol, Cloud, Precipitation, and Radiation Interactions and Dynamics of Convective Cloud Systems
and CHUVA is the acronym for Cloud Processes of the Main Precipitation Systems in Brazil: A Contribution to Cloud Resolving Modeling and to the GPM (global precipitation measurement)
, on the German High Altitude and Long Range Research Aircraft (HALO). The campaign took place in September-October 2014, with the objective of studying tropical deep convective clouds over the Amazon rainforest and their interactions with atmospheric trace gases, aerosol particles, and atmospheric radiation. Aerosol enhancements were observed consistently on all flights during which the UT was probed, using several aerosol metrics, including condensation nuclei (CN) and cloud condensation nuclei (CCN) number concentrations and chemical species mass concentrations. The UT particles differed sharply in their chemical composition and size distribution from those in the PBL, ruling out convective transport of combustion-derived particles from the boundary layer (BL) as a source. The air in the immediate outflow of deep convective clouds was depleted of aerosol particles, whereas strongly enhanced number concentrations of small particles (< 90 nm diameter) were found in UT regions that had experienced outflow from deep convection in the preceding 5-72 h. We also found elevated concentrations of larger (> 90 nm) particles in the UT, which consisted mostly of organic matter and nitrate and were very effective CCN. Our findings suggest a conceptual model, where production of new aerosol particles takes place in the continental UT from biogenic volatile organic material brought up by deep convection and converted to condensable species in the UT. Subsequently, downward mixing and transport of upper tropospheric aerosol can be a source of particles to the PBL, where they increase in size by the condensation of biogenic volatile organic compound (BVOC) oxidation products. This may be an important source of aerosol particles for the Amazonian PBL, where aerosol nucleation and new particle formation have not been observed. We propose that this may have been the dominant process supplying secondary aerosol particles in the pristine atmosphere, making clouds the dominant control of both removal and production of atmospheric particles.
Aerosol characteristics and particle production in the upper troposphere over the Amazon Basin
Andreae, Meinrat O.; Afchine, Armin; Albrecht, Rachel; ...
2018-01-25
Airborne observations over the Amazon Basin showed high aerosol particle concentrations in the upper troposphere (UT) between 8 and 15 km altitude, with number densities (normalized to standard temperature and pressure) often exceeding those in the planetary boundary layer (PBL) by 1 or 2 orders of magnitude. The measurements were made during the German–Brazilian cooperative aircraft campaign ACRIDICON–CHUVA, where ACRIDICON stands for Aerosol, Cloud, Precipitation, and Radiation Interactions and Dynamics of Convective Cloud Systems and CHUVA is the acronym for Cloud Processes of the Main Precipitation Systems in Brazil: A Contribution to Cloud Resolving Modeling and to the GPM (globalmore » precipitation measurement), on the German High Altitude and Long Range Research Aircraft (HALO). The campaign took place in September–October 2014, with the objective of studying tropical deep convective clouds over the Amazon rainforest and their interactions with atmospheric trace gases, aerosol particles, and atmospheric radiation. Aerosol enhancements were observed consistently on all flights during which the UT was probed, using several aerosol metrics, including condensation nuclei (CN) and cloud condensation nuclei (CCN) number concentrations and chemical species mass concentrations. The UT particles differed sharply in their chemical composition and size distribution from those in the PBL, ruling out convective transport of combustion-derived particles from the boundary layer (BL) as a source. The air in the immediate outflow of deep convective clouds was depleted of aerosol particles, whereas strongly enhanced number concentrations of small particles (< 90 nm diameter) were found in UT regions that had experienced outflow from deep convection in the preceding 5–72 h. We also found elevated concentrations of larger (> 90 nm) particles in the UT, which consisted mostly of organic matter and nitrate and were very effective CCN. Our findings suggest a conceptual model, where production of new aerosol particles takes place in the continental UT from biogenic volatile organic material brought up by deep convection and converted to condensable species in the UT. Subsequently, downward mixing and transport of upper tropospheric aerosol can be a source of particles to the PBL, where they increase in size by the condensation of biogenic volatile organic compound (BVOC) oxidation products. This may be an important source of aerosol particles for the Amazonian PBL, where aerosol nucleation and new particle formation have not been observed. We propose that this may have been the dominant process supplying secondary aerosol particles in the pristine atmosphere, making clouds the dominant control of both removal and production of atmospheric particles.« less
Aerosol characteristics and particle production in the upper troposphere over the Amazon Basin
DOE Office of Scientific and Technical Information (OSTI.GOV)
Andreae, Meinrat O.; Afchine, Armin; Albrecht, Rachel
Airborne observations over the Amazon Basin showed high aerosol particle concentrations in the upper troposphere (UT) between 8 and 15 km altitude, with number densities (normalized to standard temperature and pressure) often exceeding those in the planetary boundary layer (PBL) by 1 or 2 orders of magnitude. The measurements were made during the German–Brazilian cooperative aircraft campaign ACRIDICON–CHUVA, where ACRIDICON stands for Aerosol, Cloud, Precipitation, and Radiation Interactions and Dynamics of Convective Cloud Systems and CHUVA is the acronym for Cloud Processes of the Main Precipitation Systems in Brazil: A Contribution to Cloud Resolving Modeling and to the GPM (globalmore » precipitation measurement), on the German High Altitude and Long Range Research Aircraft (HALO). The campaign took place in September–October 2014, with the objective of studying tropical deep convective clouds over the Amazon rainforest and their interactions with atmospheric trace gases, aerosol particles, and atmospheric radiation. Aerosol enhancements were observed consistently on all flights during which the UT was probed, using several aerosol metrics, including condensation nuclei (CN) and cloud condensation nuclei (CCN) number concentrations and chemical species mass concentrations. The UT particles differed sharply in their chemical composition and size distribution from those in the PBL, ruling out convective transport of combustion-derived particles from the boundary layer (BL) as a source. The air in the immediate outflow of deep convective clouds was depleted of aerosol particles, whereas strongly enhanced number concentrations of small particles (< 90 nm diameter) were found in UT regions that had experienced outflow from deep convection in the preceding 5–72 h. We also found elevated concentrations of larger (> 90 nm) particles in the UT, which consisted mostly of organic matter and nitrate and were very effective CCN. Our findings suggest a conceptual model, where production of new aerosol particles takes place in the continental UT from biogenic volatile organic material brought up by deep convection and converted to condensable species in the UT. Subsequently, downward mixing and transport of upper tropospheric aerosol can be a source of particles to the PBL, where they increase in size by the condensation of biogenic volatile organic compound (BVOC) oxidation products. This may be an important source of aerosol particles for the Amazonian PBL, where aerosol nucleation and new particle formation have not been observed. We propose that this may have been the dominant process supplying secondary aerosol particles in the pristine atmosphere, making clouds the dominant control of both removal and production of atmospheric particles.« less
NASA Astrophysics Data System (ADS)
Häggi, Christoph; Sawakuchi, André O.; Chiessi, Cristiano M.; Mulitza, Stefan; Mollenhauer, Gesine; Sawakuchi, Henrique O.; Baker, Paul A.; Zabel, Matthias; Schefuß, Enno
2016-11-01
Paleoenvironmental studies based on terrigenous biomarker proxies from sediment cores collected close to the mouth of large river systems rely on a proper understanding of the processes controlling origin, transport and deposition of biomarkers. Here, we contribute to the understanding of these processes by analyzing long-chain n-alkanes from the Amazon River system. We use the δD composition of long-chain n-alkanes from river bed sediments from the Amazon River and its major tributaries, as well as marine core-top samples collected off northeastern South America as tracers for different source areas. The δ13C composition of the same compounds is used to differentiate between long-chain n-alkanes from modern forest vegetation and petrogenic organic matter. Our δ13C results show depleted δ13C values (-33 to -36‰) in most samples, indicating a modern forest source for most of the samples. Enriched values (-31 to -33‰) are only found in a few samples poor in organic carbon indicating minor contributions from a fossil petrogenic source. Long-chain n-alkane δD analyses show more depleted values for the western tributaries, the Madeira and Solimões Rivers (-152 to -168‰), while n-alkanes from the lowland tributaries, the Negro, Xingu and Tocantins Rivers (-142 to -154‰), yield more enriched values. The n-alkane δD values thus reflect the mean annual isotopic composition of precipitation, which is most deuterium-depleted in the western Amazon Basin and more enriched in the eastern sector of the basin. Samples from the Amazon estuary show a mixed long-chain n-alkane δD signal from both eastern lowland and western tributaries. Marine core-top samples underlying the Amazon freshwater plume yield δD values similar to those from the Amazon estuary, while core-top samples from outside the plume showed more enriched values. Although the variability in the river bed data precludes quantitative assessment of relative contributions, our results indicate that long-chain n-alkanes from the Amazon estuary and plume represent an integrated signal of different regions of the onshore basin. Our results also imply that n-alkanes are not extensively remineralized during transport and that the signal at the Amazon estuary and plume includes refractory compounds derived from the western sector of the Basin. These findings will aid in the interpretation of plant wax-based records of marine sediment cores collected from the adjacent ocean.
Rainfall trends in the Brazilian Amazon Basin in the past eight decades
NASA Astrophysics Data System (ADS)
Satyamurty, Prakki; de Castro, Aline Anderson; Tota, Julio; da Silva Gularte, Lucia Eliane; Manzi, Antonio Ocimar
2010-01-01
Rainfall series at 18 stations along the major rivers of the Brazilian Amazon Basin, having data since 1920s or 1930s, are analyzed to verify if there are appreciable long-term trends. Annual, rainy-season, and dry-season rainfalls are individually analyzed for each station and for the region as a whole. Some stations showed positive trends and some negative trends. The trends in the annual rainfall are significant at only six stations, five of which reporting increasing trends (Barcelos, Belem, Manaus, Rio Branco, and Soure stations) and just one (Itaituba station) reporting decreasing trend. The climatological values of rainfall before and after 1970 show significant differences at six stations (Barcelos, Belem, Benjamin Constant, Iaurete, Itaituba, and Soure). The region as a whole shows an insignificant and weak downward trend; therefore, we cannot affirm that the rainfall in the Brazilian Amazon basin is experiencing a significant change, except at a few individual stations. Subregions with upward and downward trends are interspersed in space from the far eastern Amazon to western Amazon. Most of the seasonal trends follow the annual trends, thus, indicating a certain consistency in the datasets and analysis.
Richards, Peter; VanWey, Leah
2015-07-01
Developing the Amazon into a major provider of internationally traded mineral and food commodities has dramatically transformed broad expanses of tropical forests to farm and pasturelands, and to mining sites. The environmental impacts of this transformation, as well as the drivers underlying the process, have already been well documented. In this article we turn our analytical lenses to another, less examined effect of Amazon land use and environmental change, namely the creation and development of new urban areas. Here we argue that urban growth in the Amazon is a direct residual of international interest in the production of traded commodities, and of the capacity of local urban residents to capture capital and value before it is extracted from the region. Specifically, we suggest that urban growth is occurring fastest where cities have access to both rural export commodities and export corridors. We also show correlations between urban growth and lower rural population density, and cities' capacities to draw migrants from beyond their immediate rural surroundings. More broadly, we argue that urbanization in the Amazon is better interpreted as a symptom rather than a driver of the region's land use and land cover change.
Methylmercury Modulation in Amazon Rivers Linked to Basin Characteristics and Seasonal Flood-Pulse.
Kasper, Daniele; Forsberg, Bruce R; Amaral, João H F; Py-Daniel, Sarah S; Bastos, Wanderley R; Malm, Olaf
2017-12-19
We investigated the impact of the seasonal inundation of wetlands on methylmercury (MeHg) concentration dynamics in the Amazon river system. We sampled 38 sites along the Solimões/Amazon and Negro rivers and their tributaries during distinct phases of the annual flood-pulse. MeHg dynamics in both basins was contrasted to provide insight into the factors controlling export of MeHg to the Amazon system. The export of MeHg by rivers was substantially higher during high-water in both basins since elevated MeHg concentrations and discharge occurred during this time. MeHg concentration was positively correlated to %flooded area upstream of the sampling site in the Solimões/Amazon Basin with the best correlation obtained using 100 km buffers instead of whole basin areas. The lower correlations obtained with the whole basin apparently reflected variable losses of MeHg exported from upstream wetlands due to demethylation, absorption, deposition, and degradation before reaching the sampling site. A similar correlation between %flooded area and MeHg concentrations was not observed in the Negro Basin probably due to the variable export of MeHg from poorly drained soils that are abundant in this basin but not consistently flooded.
Amazon boundary layer aerosol concentration sustained by vertical transport during rainfall
Wang, Jian; Krejci, Radovan; Giangrande, Scott; ...
2016-10-24
The nucleation of atmospheric vapours is an important source of new aerosol particles that can subsequently grow to form cloud condensation nuclei in the atmosphere. Most field studies of atmospheric aerosols over continents are influenced by atmospheric vapours of anthropogenic origin and, in consequence, aerosol processes in pristine, terrestrial environments remain poorly understood. The Amazon rainforest is one of the few continental regions where aerosol particles and their precursors can be studied under near-natural conditions, but the origin of small aerosol particles that grow into cloud condensation nuclei in the Amazon boundary layer remains unclear. Here we present aircraft- andmore » ground-based measurements under clean conditions during the wet season in the central Amazon basin. We find that high concentrations of small aerosol particles (with diameters of less than 50 nanometres) in the lower free troposphere are transported from the free troposphere into the boundary layer during precipitation events by strong convective downdrafts and weaker downward motions in the trailing stratiform region. Lastly, this rapid vertical transport can help to maintain the population of particles in the pristine Amazon boundary layer, and may therefore influence cloud properties and climate under natural conditions.« less
Amazon boundary layer aerosol concentration sustained by vertical transport during rainfall
NASA Astrophysics Data System (ADS)
Wang, Jian; Krejci, Radovan; Giangrande, Scott; Kuang, Chongai; Barbosa, Henrique M. J.; Brito, Joel; Carbone, Samara; Chi, Xuguang; Comstock, Jennifer; Ditas, Florian; Lavric, Jost; Manninen, Hanna E.; Mei, Fan; Moran-Zuloaga, Daniel; Pöhlker, Christopher; Pöhlker, Mira L.; Saturno, Jorge; Schmid, Beat; Souza, Rodrigo A. F.; Springston, Stephen R.; Tomlinson, Jason M.; Toto, Tami; Walter, David; Wimmer, Daniela; Smith, James N.; Kulmala, Markku; Machado, Luiz A. T.; Artaxo, Paulo; Andreae, Meinrat O.; Petäjä, Tuukka; Martin, Scot T.
2016-11-01
The nucleation of atmospheric vapours is an important source of new aerosol particles that can subsequently grow to form cloud condensation nuclei in the atmosphere. Most field studies of atmospheric aerosols over continents are influenced by atmospheric vapours of anthropogenic origin (for example, ref. 2) and, in consequence, aerosol processes in pristine, terrestrial environments remain poorly understood. The Amazon rainforest is one of the few continental regions where aerosol particles and their precursors can be studied under near-natural conditions, but the origin of small aerosol particles that grow into cloud condensation nuclei in the Amazon boundary layer remains unclear. Here we present aircraft- and ground-based measurements under clean conditions during the wet season in the central Amazon basin. We find that high concentrations of small aerosol particles (with diameters of less than 50 nanometres) in the lower free troposphere are transported from the free troposphere into the boundary layer during precipitation events by strong convective downdrafts and weaker downward motions in the trailing stratiform region. This rapid vertical transport can help to maintain the population of particles in the pristine Amazon boundary layer, and may therefore influence cloud properties and climate under natural conditions.
Amazon boundary layer aerosol concentration sustained by vertical transport during rainfall.
Wang, Jian; Krejci, Radovan; Giangrande, Scott; Kuang, Chongai; Barbosa, Henrique M J; Brito, Joel; Carbone, Samara; Chi, Xuguang; Comstock, Jennifer; Ditas, Florian; Lavric, Jost; Manninen, Hanna E; Mei, Fan; Moran-Zuloaga, Daniel; Pöhlker, Christopher; Pöhlker, Mira L; Saturno, Jorge; Schmid, Beat; Souza, Rodrigo A F; Springston, Stephen R; Tomlinson, Jason M; Toto, Tami; Walter, David; Wimmer, Daniela; Smith, James N; Kulmala, Markku; Machado, Luiz A T; Artaxo, Paulo; Andreae, Meinrat O; Petäjä, Tuukka; Martin, Scot T
2016-11-17
The nucleation of atmospheric vapours is an important source of new aerosol particles that can subsequently grow to form cloud condensation nuclei in the atmosphere. Most field studies of atmospheric aerosols over continents are influenced by atmospheric vapours of anthropogenic origin (for example, ref. 2) and, in consequence, aerosol processes in pristine, terrestrial environments remain poorly understood. The Amazon rainforest is one of the few continental regions where aerosol particles and their precursors can be studied under near-natural conditions, but the origin of small aerosol particles that grow into cloud condensation nuclei in the Amazon boundary layer remains unclear. Here we present aircraft- and ground-based measurements under clean conditions during the wet season in the central Amazon basin. We find that high concentrations of small aerosol particles (with diameters of less than 50 nanometres) in the lower free troposphere are transported from the free troposphere into the boundary layer during precipitation events by strong convective downdrafts and weaker downward motions in the trailing stratiform region. This rapid vertical transport can help to maintain the population of particles in the pristine Amazon boundary layer, and may therefore influence cloud properties and climate under natural conditions.
VanWey, Leah
2015-01-01
Developing the Amazon into a major provider of internationally traded mineral and food commodities has dramatically transformed broad expanses of tropical forests to farm and pasturelands, and to mining sites. The environmental impacts of this transformation, as well as the drivers underlying the process, have already been well documented. In this article we turn our analytical lenses to another, less examined effect of Amazon land use and environmental change, namely the creation and development of new urban areas. Here we argue that urban growth in the Amazon is a direct residual of international interest in the production of traded commodities, and of the capacity of local urban residents to capture capital and value before it is extracted from the region. Specifically, we suggest that urban growth is occurring fastest where cities have access to both rural export commodities and export corridors. We also show correlations between urban growth and lower rural population density, and cities’ capacities to draw migrants from beyond their immediate rural surroundings. More broadly, we argue that urbanization in the Amazon is better interpreted as a symptom rather than a driver of the region’s land use and land cover change. PMID:26985079
Following Saharan Dust Outbreak Toward The Amazon Basin
NASA Astrophysics Data System (ADS)
Ben Ami, Y.; Koren, I.; Rudich, Y.; Flores, M.
2008-12-01
The role of the Amazon rainforest on earth climatic system is well recognized. To keep forest wellbeing and the fragile balance between the rainforest and the atmosphere, the Amazon must contain a satisfactory amount of nutrients to support the plants. The extensive rain and floods wash most of the soluble nutrients from the rainforest soil, leaving behind acidic kaolinite clay or sandy soil, with limited minerals for plant growth. It was suggested that lack of mineral in the soil may be replenished by deposition of Saharan mineral dust. Using remote sensing data (from the A-train satellites constellation) following with in-situ measurements (as part of the AMazonian Aerosol CharacteriZation Experiment (AMZE) campaign), ground-based data (from AErosol RObotic NETwork (AERONET)) and back trajectory calculations, we analyzed Saharan dust transport toward the Amazon basin during the AMZE period (Feb 7 to Mar 14, 2008). Dust mass, sink, vertical distribution and surface wind speeds were analyzed over the Bodele depression (located in Chad), where most of the dust is emitted, along the Atlantic Ocean and near the Brazilian coastline. Using an integrated data analysis approach we followed dust packages from their emission in the Sahara to their sink in the Amazon forest.
Long-term decline of the Amazon carbon sink.
Brienen, R J W; Phillips, O L; Feldpausch, T R; Gloor, E; Baker, T R; Lloyd, J; Lopez-Gonzalez, G; Monteagudo-Mendoza, A; Malhi, Y; Lewis, S L; Vásquez Martinez, R; Alexiades, M; Álvarez Dávila, E; Alvarez-Loayza, P; Andrade, A; Aragão, L E O C; Araujo-Murakami, A; Arets, E J M M; Arroyo, L; Aymard C, G A; Bánki, O S; Baraloto, C; Barroso, J; Bonal, D; Boot, R G A; Camargo, J L C; Castilho, C V; Chama, V; Chao, K J; Chave, J; Comiskey, J A; Cornejo Valverde, F; da Costa, L; de Oliveira, E A; Di Fiore, A; Erwin, T L; Fauset, S; Forsthofer, M; Galbraith, D R; Grahame, E S; Groot, N; Hérault, B; Higuchi, N; Honorio Coronado, E N; Keeling, H; Killeen, T J; Laurance, W F; Laurance, S; Licona, J; Magnussen, W E; Marimon, B S; Marimon-Junior, B H; Mendoza, C; Neill, D A; Nogueira, E M; Núñez, P; Pallqui Camacho, N C; Parada, A; Pardo-Molina, G; Peacock, J; Peña-Claros, M; Pickavance, G C; Pitman, N C A; Poorter, L; Prieto, A; Quesada, C A; Ramírez, F; Ramírez-Angulo, H; Restrepo, Z; Roopsind, A; Rudas, A; Salomão, R P; Schwarz, M; Silva, N; Silva-Espejo, J E; Silveira, M; Stropp, J; Talbot, J; ter Steege, H; Teran-Aguilar, J; Terborgh, J; Thomas-Caesar, R; Toledo, M; Torello-Raventos, M; Umetsu, R K; van der Heijden, G M F; van der Hout, P; Guimarães Vieira, I C; Vieira, S A; Vilanova, E; Vos, V A; Zagt, R J
2015-03-19
Atmospheric carbon dioxide records indicate that the land surface has acted as a strong global carbon sink over recent decades, with a substantial fraction of this sink probably located in the tropics, particularly in the Amazon. Nevertheless, it is unclear how the terrestrial carbon sink will evolve as climate and atmospheric composition continue to change. Here we analyse the historical evolution of the biomass dynamics of the Amazon rainforest over three decades using a distributed network of 321 plots. While this analysis confirms that Amazon forests have acted as a long-term net biomass sink, we find a long-term decreasing trend of carbon accumulation. Rates of net increase in above-ground biomass declined by one-third during the past decade compared to the 1990s. This is a consequence of growth rate increases levelling off recently, while biomass mortality persistently increased throughout, leading to a shortening of carbon residence times. Potential drivers for the mortality increase include greater climate variability, and feedbacks of faster growth on mortality, resulting in shortened tree longevity. The observed decline of the Amazon sink diverges markedly from the recent increase in terrestrial carbon uptake at the global scale, and is contrary to expectations based on models.
Social and health dimensions of climate change in the Amazon.
Brondízio, Eduardo S; de Lima, Ana C B; Schramski, Sam; Adams, Cristina
2016-07-01
The Amazon region has been part of climate change debates for decades, yet attention to its social and health dimensions has been limited. This paper assesses literature on the social and health dimensions of climate change in the Amazon. A conceptual framework underscores multiple stresses and exposures created by interactions between climate change and local social-environmental conditions. Using the Thomson-Reuter Web of Science, this study bibliometrically assessed the overall literature on climate change in the Amazon, including Physical Sciences, Social Sciences, Anthropology, Environmental Science/Ecology and Public, Environmental/Occupational Health. From this assessment, a relevant sub-sample was selected and complemented with literature from the Brazilian database SciELO. This sample discusses three dimensions of climate change impacts in the region: livelihood changes, vector-borne diseases and microbial proliferation, and respiratory diseases. This analysis elucidates imbalance and disconnect between ecological, physical and social and health dimensions of climate change and between continental and regional climate analysis, and sub-regional and local levels. Work on the social and health implications of climate change in the Amazon falls significantly behind other research areas, limiting reliable information for analytical models and for Amazonian policy-makers and society at large. Collaborative research is called for.
Lidar observed seasonal variation of vertical canopy structure in the Amazon evergreen forests
NASA Astrophysics Data System (ADS)
Tang, H.; Dubayah, R.
2017-12-01
Both light and water are important environmental factors governing tree growth. Responses of tropical forests to their changes are complicated and can vary substantially across different spatial and temporal scales. Of particular interest is the dry-season greening-up of Amazon forests, a phenomenon undergoing considerable debates whether it is real or a "light illusion" caused by artifacts of passive optical remote sensing techniques. Here we analyze seasonal dynamic patterns of vertical canopy structure in the Amazon forests using lidar observations from NASA's Ice, Cloud, and and land Elevation Satellite (ICESat). We found that the net greening of canopy layer coincides with the wet-to-dry transition period, and its net browning occurs mostly at the late dry season. The understory also shows a seasonal cycle, but with an opposite variation to canopy and minimal correlation to seasonal variations in rainfall or radiation. Our results further suggest a potential interaction between canopy layers in the light regime that can optimize the growth of Amazon forests during the dry season. This light regime variability that exists in both spatial and temporal domains can better reveal the dry-season greening-up phenomenon, which appears less obvious when treating the Amazon forests as a whole.
2001-02-07
Flowing over 6450 kilometers eastward across Brazil, the Amazon River originates in the Peruvian Andes as tiny mountain streams that eventually combine to form one of the world mightiest rivers as shown in this image from NASA Terra satellite.
Assembly of Oriented Virus Arrays by Chemo-Selective Ligation Methods and Nanolithography Techniques
DOE Office of Scientific and Technical Information (OSTI.GOV)
Camarero, J A; Cheung, C L; Lin, T
2002-12-02
The present work describes our ongoing efforts towards the creation of nano-scaled ordered arrays of protein/virus covalently attached to site-specific chemical linkers patterned by different nanolithograpy techniques. We will present a new and efficient solid-phase approach for the synthesis of chemically modified long alkyl-thiols. These compounds can be used to introduce chemoselective reacting groups onto gold and silicon-based surfaces. Furthermore, these modified thiols have been used to create nanometric patterns by using different nanolithography techniques. We will show that these patterns can react chemoselectively with proteins and/or virus which have been chemically or recombinantly modified to contain complementary chemical groupsmore » at specific positions thus resulting in the oriented attachment of the protein or virus to the surface.« less
Sensitive And Selective Chemical Sensor With Nanostructured Surfaces.
Pipino, Andrew C. R.
2003-02-04
A chemical sensor is provided which includes an optical resonator including a nanostructured surface comprising a plurality of nanoparticles bound to one or more surfaces of the resonator. The nanoparticles provide optical absorption and the sensor further comprises a detector for detecting the optical absorption of the nanoparticles or their environment. In particular, a selective chemical interaction is provided which modifies the optical absorption of the nanoparticles or their environment, and an analyte is detected based on the modified optical absorption. A light pulse is generated which enters the resonator to interrogate the modified optical absorption and the exiting light pulse is detected by the detector.
Chemical and Conformational Diversity of Modified Nucleosides Affects tRNA Structure and Function.
Väre, Ville Y P; Eruysal, Emily R; Narendran, Amithi; Sarachan, Kathryn L; Agris, Paul F
2017-03-16
RNAs are central to all gene expression through the control of protein synthesis. Four major nucleosides, adenosine, guanosine, cytidine and uridine, compose RNAs and provide sequence variation, but are limited in contributions to structural variation as well as distinct chemical properties. The ability of RNAs to play multiple roles in cellular metabolism is made possible by extensive variation in length, conformational dynamics, and the over 100 post-transcriptional modifications. There are several reviews of the biochemical pathways leading to RNA modification, but the physicochemical nature of modified nucleosides and how they facilitate RNA function is of keen interest, particularly with regard to the contributions of modified nucleosides. Transfer RNAs (tRNAs) are the most extensively modified RNAs. The diversity of modifications provide versatility to the chemical and structural environments. The added chemistry, conformation and dynamics of modified nucleosides occurring at the termini of stems in tRNA's cloverleaf secondary structure affect the global three-dimensional conformation, produce unique recognition determinants for macromolecules to recognize tRNAs, and affect the accurate and efficient decoding ability of tRNAs. This review will discuss the impact of specific chemical moieties on the structure, stability, electrochemical properties, and function of tRNAs.
Ozone measurements in the Amazon
NASA Astrophysics Data System (ADS)
Kirchhoff, V. W. J. H.
Several scientists of the Brazilian Institute for Space Research (Instituto de Pesquisas Espacias, or INPE; headquarters at Sāo Jose dos Campos, Sao Paulo) went to Manaus (3°S, 60°W), in the central region of the Amazon forest during July-August 1985 to study the atmosphere of the equatorial rainforest. The expedition to the Amazon was part of a large binational atmospheric chemistry field campaign that was organized to measure several atmospheric gases of the forest environment. This was definitely the largest scientific field expedition in this field ever performed on Brazilian territory.
Osteoma in a blue-fronted Amazon parrot (Amazona aestiva).
Cardoso, João Felipe Rito; Levy, Marcelo Guilherme Bezerra; Liparisi, Flavia; Romão, Mario Antonio Pinto
2013-09-01
Osteoma is an uncommon bone formation documented in avian species and other animals. A blue-fronted Amazon parrot (Amazona aestiva) with clinical respiratory symptoms was examined because of a hard mass present on the left nostril. Radiographs suggested a bone tumor, and the mass was surgically excised. Histopathologic examination revealed features of an osteoma. To our knowledge, this is the first description of an osteoma in a blue-fronted Amazon parrot. Osteoma should be considered as a differential diagnosis in birds with respiratory distress and swelling of the nostril.
Schmidt, Elizabeth Moreira dos Santos; Lange, Rogério Ribas; Ribas, Janaciara Moreira; Daciuk, Bárbara Maria; Montiani-Ferreira, Fabiano; Paulillo, Antonio Carlos
2009-03-01
Preliminary reference intervals for hematologic and total plasma protein profiles were determined for nine adult Red-capped parrots (Pionopsitta pileata) (six males and three females) and six Vinaceous Amazon parrots (Amazona vinacea) (two adult males, two adult females, one juvenile, and one nonsexed) from the Curitiba Zoo, Paraná, Brazil. For both Red-capped parrots and Vinaceous Amazon parrots, adult males had higher red blood cell counts than adult females. Regarding white blood cell distribution, differences due to gender were also found for both species of parrots.
Da Silva Sovano, Rafael S; Cadena-Castañeda, Oscar J
2015-03-26
A regional study is performed for the Amazonian species of the genus Microcentrum Scudder, 1862, its proposed Microcentrum punctifrons Brunner von Wattenwyl, 1891 as nomen dubium n. stat. and two new species are described: Microcentrum amacayacu Cadena-Casteñada, Sovano n. sp. and Microcentrum xavieri Sovano, Cadena-Casteñada n. sp. the Colombian and Brazilian Amazon, respectively. A list and a key to the Amazonian species are also provided, along with a discussion on their distribution, according to endemism areas established to Amazon rainforest.
40 CFR 721.10029 - Isocyanate compound, modified with methoxysilane (generic).
Code of Federal Regulations, 2010 CFR
2010-07-01
... to those contained in the corresponding section 5(e) consent order. (ii) Hazard communication program...) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as isocyanate compound, modified with methoxysilane (PMN P-01-918) is subject to reporting under...
40 CFR 721.10150 - Carbon black, (4-methylphenyl)-modified, substituted (generic).
Code of Federal Regulations, 2011 CFR
2011-07-01
... PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT SIGNIFICANT NEW USES OF CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.10150 Carbon black, (4-methylphenyl)-modified... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Carbon black, (4-methylphenyl...
40 CFR 721.10149 - Carbon black, (3-methylphenyl)-modified, substituted (generic).
Code of Federal Regulations, 2011 CFR
2011-07-01
... PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT SIGNIFICANT NEW USES OF CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.10149 Carbon black, (3-methylphenyl)-modified... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Carbon black, (3-methylphenyl...
NASA Astrophysics Data System (ADS)
De Linage, C.; Famiglietti, J. S.; Randerson, J. T.
2013-12-01
Floods and droughts frequently affect the Amazon River basin, impacting the transportation, river navigation, agriculture, economy and the carbon balance and biodiversity of several South American countries. The present study aims to find the main variables controlling the natural interannual variability of terrestrial water storage in the Amazon region and to propose a modeling framework for flood and drought forecasting. We propose three simple empirical models using a linear combination of lagged spatial averages of central Pacific (Niño 4 index) and tropical North Atlantic (TNAI index) sea surface temperatures (SST) to predict a decade-long record of 3°, monthly terrestrial water storage anomalies (TWSA) observed by the Gravity Recovery And Climate Experiment (GRACE) mission. In addition to a SST forcing term, the models included a relaxation term to simulate the memory of water storage anomalies in response to external variability in forcing. Model parameters were spatially-variable and individually optimized for each 3° grid cell. We also investigated the evolution of the predictive capability of our models with increasing minimum lead times for TWSA forecasts. TNAI was the primary external forcing for the central and western regions of the southern Amazon (35% of variance explained with a 3-month forecast), whereas Niño 4 was dominant in the northeastern part of the basin (61% of variance explained with a 3-month forecast). Forcing the model with a combination of the two indices improved the fit significantly (p<0.05) for at least 64% of the grid cells, compared to models forced solely with Niño 4 or TNAI. The combined model was able to explain 43% of the variance in the Amazon basin as a whole with a 3-month lead time. While 66% of the observed variance was explained in the northeastern Amazon, only 39% of the variance was captured by the combined model in the central and western regions, suggesting that other, more local, forcing sources were important in these regions. The predictive capability of the combined model was monotonically degraded with increasing lead times. Degradation was smaller in the northeastern Amazon (where 49% of the variance was explained using a 8-month lead time versus 69% for a 1 month lead time) compared to the western and central regions of southern Amazon (where 22% of the variance was explained at 8 months versus 43% at 1 month). Our model may provide early warning information about flooding in the northeastern region of the Amazon basin, where floodplain areas are extensive and the sensitivity of floods to external SST forcing was shown to be high. This work also strengthens our understanding of the mechanisms regulating interannual variability in Amazon fires, as TWSA deficits may subsequently lead to atmospheric water vapor deficits and reduced cloudiness via water-limited evapotranspiration. Finally, this work helps to bridge the gap between the current GRACE mission and the follow-on gravity mission.
Annual Carbon Emissions from Deforestation in the Amazon Basin between 2000 and 2010.
Song, Xiao-Peng; Huang, Chengquan; Saatchi, Sassan S; Hansen, Matthew C; Townshend, John R
2015-01-01
Reducing emissions from deforestation and forest degradation (REDD+) is considered one of the most cost-effective strategies for mitigating climate change. However, historical deforestation and emission rates-critical inputs for setting reference emission levels for REDD+-are poorly understood. Here we use multi-source, time-series satellite data to quantify carbon emissions from deforestation in the Amazon basin on a year-to-year basis between 2000 and 2010. We first derive annual deforestation indicators by using the Moderate Resolution Imaging Spectroradiometer Vegetation Continuous Fields (MODIS VCF) product. MODIS indicators are calibrated by using a large sample of Landsat data to generate accurate deforestation rates, which are subsequently combined with a spatially explicit biomass dataset to calculate committed annual carbon emissions. Across the study area, the average deforestation and associated carbon emissions were estimated to be 1.59 ± 0.25 M ha•yr(-1) and 0.18 ± 0.07 Pg C•yr(-1) respectively, with substantially different trends and inter-annual variability in different regions. Deforestation in the Brazilian Amazon increased between 2001 and 2004 and declined substantially afterwards, whereas deforestation in the Bolivian Amazon, the Colombian Amazon, and the Peruvian Amazon increased over the study period. The average carbon density of lost forests after 2005 was 130 Mg C•ha(-1), ~11% lower than the average carbon density of remaining forests in year 2010 (144 Mg C•ha(-1)). Moreover, the average carbon density of cleared forests increased at a rate of 7 Mg C•ha(-1)•yr(-1) from 2005 to 2010, suggesting that deforestation has been progressively encroaching into high-biomass lands in the Amazon basin. Spatially explicit, annual deforestation and emission estimates like the ones derived in this study are useful for setting baselines for REDD+ and other emission mitigation programs, and for evaluating the performance of such efforts.
Annual Carbon Emissions from Deforestation in the Amazon Basin between 2000 and 2010
Song, Xiao-Peng; Huang, Chengquan; Saatchi, Sassan S.; Hansen, Matthew C.; Townshend, John R.
2015-01-01
Reducing emissions from deforestation and forest degradation (REDD+) is considered one of the most cost-effective strategies for mitigating climate change. However, historical deforestation and emission rates―critical inputs for setting reference emission levels for REDD+―are poorly understood. Here we use multi-source, time-series satellite data to quantify carbon emissions from deforestation in the Amazon basin on a year-to-year basis between 2000 and 2010. We first derive annual deforestation indicators by using the Moderate Resolution Imaging Spectroradiometer Vegetation Continuous Fields (MODIS VCF) product. MODIS indicators are calibrated by using a large sample of Landsat data to generate accurate deforestation rates, which are subsequently combined with a spatially explicit biomass dataset to calculate committed annual carbon emissions. Across the study area, the average deforestation and associated carbon emissions were estimated to be 1.59 ± 0.25 M ha•yr−1 and 0.18 ± 0.07 Pg C•yr−1 respectively, with substantially different trends and inter-annual variability in different regions. Deforestation in the Brazilian Amazon increased between 2001 and 2004 and declined substantially afterwards, whereas deforestation in the Bolivian Amazon, the Colombian Amazon, and the Peruvian Amazon increased over the study period. The average carbon density of lost forests after 2005 was 130 Mg C•ha−1, ~11% lower than the average carbon density of remaining forests in year 2010 (144 Mg C•ha−1). Moreover, the average carbon density of cleared forests increased at a rate of 7 Mg C•ha−1•yr−1 from 2005 to 2010, suggesting that deforestation has been progressively encroaching into high-biomass lands in the Amazon basin. Spatially explicit, annual deforestation and emission estimates like the ones derived in this study are useful for setting baselines for REDD+ and other emission mitigation programs, and for evaluating the performance of such efforts. PMID:25951328
Finer, Matt; Jenkins, Clinton N.
2012-01-01
Due to rising energy demands and abundant untapped potential, hydropower projects are rapidly increasing in the Neotropics. This is especially true in the wet and rugged Andean Amazon, where regional governments are prioritizing new hydroelectric dams as the centerpiece of long-term energy plans. However, the current planning for hydropower lacks adequate regional and basin-scale assessment of potential ecological impacts. This lack of strategic planning is particularly problematic given the intimate link between the Andes and Amazonian flood plain, together one of the most species rich zones on Earth. We examined the potential ecological impacts, in terms of river connectivity and forest loss, of the planned proliferation of hydroelectric dams across all Andean tributaries of the Amazon River. Considering data on the full portfolios of existing and planned dams, along with data on roads and transmission line systems, we developed a new conceptual framework to estimate the relative impacts of all planned dams. There are plans for 151 new dams greater than 2 MW over the next 20 years, more than a 300% increase. These dams would include five of the six major Andean tributaries of the Amazon. Our ecological impact analysis classified 47% of the potential new dams as high impact and just 19% as low impact. Sixty percent of the dams would cause the first major break in connectivity between protected Andean headwaters and the lowland Amazon. More than 80% would drive deforestation due to new roads, transmission lines, or inundation. We conclude with a discussion of three major policy implications of these findings. 1) There is a critical need for further strategic regional and basin scale evaluation of dams. 2) There is an urgent need for a strategic plan to maintain Andes-Amazon connectivity. 3) Reconsideration of hydropower as a low-impact energy source in the Neotropics. PMID:22529979
Basin-Wide Amazon Forest Tree Mortality From a Large 2005 Storm
NASA Astrophysics Data System (ADS)
Negron Juarez, R. I.; Chambers, J. Q.; Guimaraes, G.; Zeng, H.; Raupp, C.; Marra, D. M.; Ribeiro, G.; Saatchi, S. S.; Higuchi, N.
2010-12-01
Blowdowns are a recurrent characteristic of Amazon forests and are produced, among others, by squall lines. Squall lines are aligned clusters (typical length of 1000 km, width of 200 km) of deep convective cells that produce heavy rainfall during the dry season and significant rainfall during the wet season. These squall lines (accompanied by intense downbursts from convective cells) have been associated with large blowdowns characterized by uprooted, snapped trees, and trees being dragged down by other falling trees. Most squall lines in Amazonia form along the northeastern coast of South America as sea breeze-induced instability lines and propagate inside the continent. They occur frequently (~4 times per month), and can reach the central and even extreme western parts of Amazonia. Squall lines can also be generated inside the Amazon and propagate toward the equator. In January 2005 a squall line propagated from south to north across the entire Amazon basin producing widespread forest tree mortality and contributed to the elevated mortality observed that year. Over the Manaus region (3.4 x104 km2), disturbed forest patches generated by the squall produced a mortality of 0.3-0.5 million trees, equivalent to 30% of the observed annual deforestation reported in 2005 over the same area. The elevated mortality observed in the Central Amazon in 2005 is unlikely to be related to the 2005 Amazon drought since drought did not affect Central or Eastern Amazonia. Assuming a similar rate of forest mortality across the basin, the squall line could have potentially produced tree mortality estimated at 542 ± 121 million trees, equivalent to 23% of the mean annual biomass accumulation estimated for these forests. Our results highlight the vulnerability of Amazon trees to wind-driven mortality associated with convective storms. This vulnerability is likely to increase in a warming climate with models projecting an increase in storm intensity.
Finer, Matt; Jenkins, Clinton N
2012-01-01
Due to rising energy demands and abundant untapped potential, hydropower projects are rapidly increasing in the Neotropics. This is especially true in the wet and rugged Andean Amazon, where regional governments are prioritizing new hydroelectric dams as the centerpiece of long-term energy plans. However, the current planning for hydropower lacks adequate regional and basin-scale assessment of potential ecological impacts. This lack of strategic planning is particularly problematic given the intimate link between the Andes and Amazonian flood plain, together one of the most species rich zones on Earth. We examined the potential ecological impacts, in terms of river connectivity and forest loss, of the planned proliferation of hydroelectric dams across all Andean tributaries of the Amazon River. Considering data on the full portfolios of existing and planned dams, along with data on roads and transmission line systems, we developed a new conceptual framework to estimate the relative impacts of all planned dams. There are plans for 151 new dams greater than 2 MW over the next 20 years, more than a 300% increase. These dams would include five of the six major Andean tributaries of the Amazon. Our ecological impact analysis classified 47% of the potential new dams as high impact and just 19% as low impact. Sixty percent of the dams would cause the first major break in connectivity between protected Andean headwaters and the lowland Amazon. More than 80% would drive deforestation due to new roads, transmission lines, or inundation. We conclude with a discussion of three major policy implications of these findings. 1) There is a critical need for further strategic regional and basin scale evaluation of dams. 2) There is an urgent need for a strategic plan to maintain Andes-Amazon connectivity. 3) Reconsideration of hydropower as a low-impact energy source in the Neotropics.
NASA Technical Reports Server (NTRS)
Alencar, A.; Nepstad, D.; Ver-Diaz, M. Del. C.
2004-01-01
"Understory fires" that burn the floor of standing forests are one of the most important types of forest impoverishment in the Amazon, especially during the severe droughts of El Nino Southern Oscillation (ENSO) episodes. However, we are aware of no estimates of the areal extent of these fires for the Brazilian Amazon and, hence, of their contribution to Amazon carbon fluxes to the atmosphere. We calculated the area of forest understory fires for the Brazilian Amazon region during an El Nino (1998) and a non El Nino (1995) year based on forest fire scars mapped with satellite images for three locations in eastern and southern Amazon, where deforestation is concentrated. The three study sites represented a gradient of both forest types and dry season severity. The burning scar maps were used to determine how the percentage of forest that burned varied with distance from agricultural clearings. These spatial functions were then applied to similar forest/climate combinations outside of the study sites to derive an initial estimate for the Brazilian Amazon. Ninety-one percent of the forest area that burned in the study sites was within the first kilometer of a clearing for the non ENSO year and within the first four kilometers for the ENSO year. The area of forest burned by understory forest fire during the severe drought (ENSO) year (3.9 millions of hectares) was 13 times greater than the area burned during the average rainfall year (0.2 million hectares), and twice the area of annual deforestation rate. Dense forest was, proportionally, the forest area most affected by understory fires during the El Nino year, while understory fires were concentrated in transitional forests during the year of average rainfall. Our estimate of aboveground tree biomass killed by fire ranged from 0.06 Pg to 0.38 Pg during the ENSO and from 0,004 Pg to 0,024 Pg during the non ENSO.
The spatial extent of change in tropical forest ecosystem services in the Amazon delta
NASA Astrophysics Data System (ADS)
de Araujo Barbosa, C. C.; Atkinson, P.; Dearing, J.
2014-12-01
Deltas hold major economic potential due their strategic location, close to seas and inland waterways, thereby supporting intense economic activity. The increasing pace of human development activities in coastal deltas over the past five decades has also strained environmental resources and produced extensive economic and sociocultural impacts. The Amazon delta is located in the Amazon Basin, North Brazil, the largest river basin on Earth and also one of the least understood. A considerable segment of the population living in the Amazon delta is directly dependent on the local extraction of natural resources for their livelihood. Areas sparsely inhabited may be exploited with few negative consequences for the environment. However, increasing pressure on ecosystem services is amplified by large fluxes of immigrants from other parts of the country, especially from the semi-arid zone in Northeast Brazil to the lowland forests of the Amazon delta. Here we present partial results from a bigger research project. Therefore, the focus will be on presenting an overview of the current state, and the extent of changes on forest related ecosystem services in the Amazon delta over the last three decades. We aggregated a multitude of datasets, from a variety of sources, for example, from satellite imagery such as the Advanced Very High Resolution Radiometer (AVHRR), the Global Inventory Modelling and Mapping Studies (GIMMS), the Moderate Resolution Imaging Spectroradiometer (MODIS), and climate datasets at meteorological station level from the Brazilian National Institute of Meteorology (INMET) and social and economic statistics data from the Brazilian Institute of Geography and Statistics (IBGE) and from the Brazilian Institute of Applied Economic Research (IPEA). Through analysis of socioeconomic and satellite earth observation data we were able to produce and present spatially-explicit information with the current state and transition in forest cover and its impacts to forest ecosystem services providing units in the Amazon delta.
Plachá, Daniela; Rosenbergová, Kateřina; Slabotínský, Jiří; Kutláková, Kateřina Mamulová; Studentová, Soňa; Martynková, Gražyna Simha
2014-04-30
Sorption efficiencies of modified montmorillonite and vermiculite of their mono ionic Na and organic HDTMA and HDP forms were studied against chemical and biological warfare agents such as yperite and selected bacterial strains. Yperite interactions with modified clay minerals were observed through its capture in low-density polyethylene foil-modified clay composites by measuring yperite gas permeation with using chemical indication and gas chromatography methods. The antibacterial activities of synthetized organoclays were tested against selected Gram-positive and Gram-negative bacterial species in minimum inhibitory concentration tests. The obtained results showed a positive influence of modified clay minerals on the significant yperite breakthrough-time increase. The most effective material was the polyethylene-Na form montmorillonite, while the polyethylene-Na form vermiculite showed the lowest efficiency. With increasing organic cations loading in the interlayer space the montmorillonite efficiency decreased, and in the case of vermiculite an opposite effect was observed. Generally the modified montmorillonites were more effective than modified vermiculites. The HDP cations seem to be more effective compare to the HDTMA. The antibacterial activity tests confirmed efficiency of all organically modified clay minerals against Gram-positive bacteria. The confirmation of antibacterial activity against Y. pestis, plague bacteria, is the most interesting result of this part of the study. Copyright © 2014 Elsevier B.V. All rights reserved.
Changes in the Carbon Cycle of Amazon Ecosystems During the 2010 Drought
NASA Technical Reports Server (NTRS)
Potter, Christophera; Klooster, Steven; Hiatt, Cyrus; Genovese, Vanessa; Castilla-Rubino, Juan Carlos
2011-01-01
Satellite remote sensing was combined with the NASA-CASA carbon cycle simulation model to evaluate the impact of the 2010 drought (July through September) throughout tropical South America. Results indicated that net primary production (NPP) in Amazon forest areas declined by an average of 7% in 2010 compared to 2008. This represented a loss of vegetation CO2 uptake and potential Amazon rainforest growth of nearly 0.5 Pg C in 2010. The largest overall decline in ecosystem carbon gains by land cover type was predicted for closed broadleaf forest areas of the Amazon River basin, including a large fraction of regularly flooded forest areas. Model results support the hypothesis that soil and dead wood carbon decomposition fluxes of CO2 to the atmosphere were elevated during the drought period of 2010 in periodically flooded forest areas, compared to forests outside the main river floodplains.
Prevalence of myopia in an adult population of two different ethnic groups in the Ecuadorian Amazon.
Jiménez, José Ramón; Bermúdez, Javier; Rubiño, Manuel; Gómez, Luis; Anera, Rosario González
2004-01-01
To determine the prevalence of myopia in the adult populations of two different ethnic communities in the Ecuadorian Amazon. Refraction with retinoscopy after cycloplegia was performed for 507 Naporuna (an ethnic group indigenous to the jungles of the Ecuadorian Amazon) and for 776 settlers (white-mestizos from the Andes, now living in the Amazon and working for the petroleum industry). Ages ranged from 18 to 45 years. All subjects had little or no formal education. The prevalence of myopia was 4.7% among the Naporuna and 5.5% among the settlers; the prevalence of hyperopia was higher, at 17.8% and 36.0%, respectively. The prevalence of myopia in the two communities studied agrees with the results of other studies showing a low prevalence of myopia among groups with low levels of formal education or groups living a nonurban lifestyle.
Diaz, Gonzalo J; Krska, Rudolf; Sulyok, Michael
2015-01-01
A study was conducted to determine the incidence and levels of mycotoxins in the main staple foods of three indigenous people of the Colombian Amazon. A total of 20 corn, 24 rice and 59 cassava samples were analysed by a multi-analyte liquid chromatography-tandem mass spectrometry method covering the major classes of mycotoxins. In addition, cassava samples were also analysed for cyanogenic glycosides. The indigenous Amazon communities tested are exposed to potentially carcinogenic mycotoxins (particularly aflatoxins), as well as other mycotoxins, mainly through the intake of locally grown corn. Citrinin content in this corn was unusually high and has not been reported elsewhere. Two cassava samples contained high levels of cyanogenic glycosides. It is strongly recommended not to grow corn in the Amazon but instead purchase it from vendors capable of guaranteeing mycotoxin levels below the maximum allowable concentration in Colombia.
Accord No. 334 of 18 August 1989.
1989-01-01
This Accord creates the Programme for Forestation and Reforestation of the Amazon Region of Ecuador with Native Species, under the control of the National Forestry Directorate. The preamble to the Accord states that the Programme has been created, in part, to stop the indiscriminate exploitation of natural trees. Accord No. 332 of 18 August 1989, issued by the Ministry of Agriculture and Livestock, creates under the Regional Subsecretariat for the Amazon the Agency of Natural Resources of the Amazon Region of Ecuador to coordinate activities taking place in that area with the Institute for Settlement of the Amazon Region of Ecuador and relevant state organizations. The preamble to the Accord states that the Agency has been created, in part, to ensure the rational and harmonic development of the region and to preserve the region's natural resources. See Registro Oficial, No. 262, 28 August 1989, p. 2.
NASA Astrophysics Data System (ADS)
Baker, J. C. A.; Gloor, M.; Boom, A.; Neill, D. A.; Cintra, B. B. L.; Clerici, S. J.; Brienen, R. J. W.
2018-02-01
It was suggested in a recent article that sunspots drive decadal variation in Amazon River flow. This conclusion was based on a novel time series decomposition method used to extract a decadal signal from the Amazon River record. We have extended this analysis back in time, using a new hydrological proxy record of tree ring oxygen isotopes (δ18OTR). Consistent with the findings of Antico and Torres, we find a positive correlation between sunspots and the decadal δ18OTR cycle from 1903 to 2012 (
The changing hydrology of a dammed Amazon
Timpe, Kelsie; Kaplan, David
2017-01-01
Developing countries around the world are expanding hydropower to meet growing energy demand. In the Brazilian Amazon, >200 dams are planned over the next 30 years, and questions about the impacts of current and future hydropower in this globally important watershed remain unanswered. In this context, we applied a hydrologic indicator method to quantify how existing Amazon dams have altered the natural flow regime and to identify predictors of alteration. The type and magnitude of hydrologic alteration varied widely by dam, but the largest changes were to critical characteristics of the flood pulse. Impacts were largest for low-elevation, large-reservoir dams; however, small dams had enormous impacts relative to electricity production. Finally, the “cumulative” effect of multiple dams was significant but only for some aspects of the flow regime. This analysis is a first step toward the development of environmental flows plans and policies relevant to the Amazon and other megadiverse river basins. PMID:29109972
Impact of functional determinants on 5.5-year mortality in Amazon riparian elderly.
Antonini, Tiago C; de Paz, Jose A; Ribeiro, Euler E; Brito, Elorídes; Mota, Kennya S; Silva, Terezinha L; Cristi-Monteiro, Carlos; Jung, Pedro V C; da Cruz, Ivana B M
2016-08-01
Objective To ascertain whether modifiable physical performance-based measurements predicted 5.5-year mortality in a riparian elderly cohort in the Amazon rainforest region. Methods A longitudinal study evaluating the impact of functional determinants on 5.5-year mortality in a riparian elderly cohort from Maués City in the state of Amazonas, Brazil, was performed. The study was a follow-up of a previous observational investigation that evaluated various fitness tests in 630 Amazonian riparian elderly (291 males and 339 females) aged 72.3 ± 8.0 (60-99) years old. The cohort was selected for its adverse environmental conditions, which increased the risk of falls yet required maintenance of good physical condition for carrying out relatively rigorous daily activities, and restricted access to specialized health services. Official death records were obtained from the Maués Municipal Health Department. Results A total of 80 study participants (12.7%) died over the 5.5-year study period. Kaplan-Meier regression analysis showed significant association between Timed Up and Go (TUG) test scores ≥ 14 seconds and mortality risk, independent of sex, age, and other health variables. Conclusions The study results suggest that the TUG test can be used as an indicator for initiating therapeutic and preventive actions, including conducting exercises or physical activities adapted to the health and functional conditions of the elderly, by identifying elderly people with a higher relative risk of mortality.
Ancient human disturbances may be skewing our understanding of Amazonian forests
McMichael, Crystal N. H.; Matthews-Bird, Frazer; Farfan-Rios, William; Feeley, Kenneth J.
2017-01-01
Although the Amazon rainforest houses much of Earth’s biodiversity and plays a major role in the global carbon budget, estimates of tree biodiversity originate from fewer than 1,000 forest inventory plots, and estimates of carbon dynamics are derived from fewer than 200 recensus plots. It is well documented that the pre-European inhabitants of Amazonia actively transformed and modified the forest in many regions before their population collapse around 1491 AD; however, the impacts of these ancient disturbances remain entirely unaccounted for in the many highly influential studies using Amazonian forest plots. Here we examine whether Amazonian forest inventory plot locations are spatially biased toward areas with high probability of ancient human impacts. Our analyses reveal that forest inventory plots, and especially forest recensus plots, in all regions of Amazonia are located disproportionately near archaeological evidence and in areas likely to have ancient human impacts. Furthermore, regions of the Amazon that are relatively oversampled with inventory plots also contain the highest values of predicted ancient human impacts. Given the long lifespan of Amazonian trees, many forest inventory and recensus sites may still be recovering from past disturbances, potentially skewing our interpretations of forest dynamics and our understanding of how these forests are responding to global change. Empirical data on the human history of forest inventory sites are crucial for determining how past disturbances affect modern patterns of forest composition and carbon flux in Amazonian forests. PMID:28049821
New Italian guidelines for malaria prophylaxis in travellers to endemic areas.
Calleri, G; Castelli, F; El Hamad, I; Gobbi, F; Matteelli, A; Napoletano, G; Romi, R; Rossanese, A; Italian Society of Tropical Medicine
2014-02-01
As a consequence of the rapid evolution of malaria prophylaxis recommendations throughout the world, the Italian Society of Tropical Medicine (SIMET-Società Italiana di Medicina Tropicale) has set up a working group in charge of preparing a new national guideline. Other scientific societies interested in the topic were also involved in the project. The group stated that awareness about malaria risk and characteristics, as well as protection from mosquito bites, are recommended for all travellers visiting malaria-endemic countries. The risk and benefit of malaria chemoprophylaxis must be carefully balanced before prescribing drugs: the disease-related risk must outweigh the possibility of drugs' side effects. As a general rule, malaria pills are the first choice for travellers to high-risk areas, such as sub-Saharan Africa, Eastern India, Myanmar, Eastern Indonesia, Papua New Guinea and, with some limitations, South-East Asia, and the Amazon part of Venezuela, Guyana and French Guyana. However, several other factors, such as itinerary, season, duration of trip, availability of insect bite protection, pre-existing conditions and compliance, must be taken into account. In low-risk areas, stand-by emergency treatment is the first option. In minimal-risk areas and in Plasmodium vivax areas, a prompt diagnosis only is advised (Central America, South America outside the Amazon basin, Middle East, China, Thailand, Nepal). Recommendations may be modified when particular groups of travellers are concerned, such as long-term residents, visiting friends and relatives, patients with pre-existing conditions, pregnant women and children.
40 CFR 721.10149 - Carbon black, (3-methylphenyl)-modified, substituted (generic).
Code of Federal Regulations, 2012 CFR
2012-07-01
... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Carbon black, (3-methylphenyl)-modified, substituted (generic). 721.10149 Section 721.10149 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT SIGNIFICANT NEW USES OF CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substance...
40 CFR 721.10149 - Carbon black, (3-methylphenyl)-modified, substituted (generic).
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Carbon black, (3-methylphenyl)-modified, substituted (generic). 721.10149 Section 721.10149 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT SIGNIFICANT NEW USES OF CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substance...
40 CFR 721.10150 - Carbon black, (4-methylphenyl)-modified, substituted (generic).
Code of Federal Regulations, 2012 CFR
2012-07-01
... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Carbon black, (4-methylphenyl)-modified, substituted (generic). 721.10150 Section 721.10150 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT SIGNIFICANT NEW USES OF CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substance...
40 CFR 721.10150 - Carbon black, (4-methylphenyl)-modified, substituted (generic).
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Carbon black, (4-methylphenyl)-modified, substituted (generic). 721.10150 Section 721.10150 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT SIGNIFICANT NEW USES OF CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substance...
40 CFR 721.9514 - Ethyl silicate, reaction products with modified alkoxysilane salt (generic).
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Ethyl silicate, reaction products with... Significant New Uses for Specific Chemical Substances § 721.9514 Ethyl silicate, reaction products with.... (1) The chemical substance identified generically as Ethyl silicate, reaction products with modified...
40 CFR 721.9514 - Ethyl silicate, reaction products with modified alkoxysilane salt (generic).
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Ethyl silicate, reaction products with... Significant New Uses for Specific Chemical Substances § 721.9514 Ethyl silicate, reaction products with.... (1) The chemical substance identified generically as Ethyl silicate, reaction products with modified...
21 CFR 178.3790 - Polymer modifiers in semirigid and rigid vinyl chloride plastics.
Code of Federal Regulations, 2012 CFR
2012-04-01
... chemical reactions, other than addition reactions, occur when they are mixed. (2) Polymers identified in...; provided that no chemical reactions, other than addition reactions, occur when they are combined. Such..., other than addition reactions, occur among the vinyl chloride polymers and the modifying polymers...
21 CFR 178.3790 - Polymer modifiers in semirigid and rigid vinyl chloride plastics.
Code of Federal Regulations, 2013 CFR
2013-04-01
... chemical reactions, other than addition reactions, occur when they are mixed. (2) Polymers identified in...; provided that no chemical reactions, other than addition reactions, occur when they are combined. Such..., other than addition reactions, occur among the vinyl chloride polymers and the modifying polymers...
Optoelectronic investigation of nanodiamond interactions with human blood
NASA Astrophysics Data System (ADS)
Ficek, M.; Wróbel, M. S.; Wasowicz, M.; Jedrzejewska-Szczerska, M.
2016-03-01
We present optoelectronic investigation of in vitro interactions of whole human blood with different nanodiamond biomarkers. Plasmo-chemical modifications of detonation nanodiamond particles gives the possibility for controlling their surface for biological applications. Optical investigations reveal the biological activity of nanodiamonds in blood dependent on its surface termination. We compare different types of nanodiamonds: commercial non-modified detonation nanodiamonds, and nanodiamonds modified by MW PACVD method with H2-termination, and chemically modified nanodiamond with O2-termination. The absorption spectra, and optical microscope investigations were conducted. The results indicate haemocompatibility of non-modified detonation nanodiamond as well as modified nanodiamonds, which enables their application for drug delivery, as well as sensing applications.
Evaluating Zeolite-Modified Sensors: towards a faster set of chemical sensors
NASA Astrophysics Data System (ADS)
Berna, A. Z.; Vergara, A.; Trincavelli, M.; Huerta, R.; Afonja, A.; Parkin, I. P.; Binions, R.; Trowell, S.
2011-09-01
The responses of zeolite-modified sensors, prepared by screen printing layers of chromium titanium oxide (CTO), were compared to unmodified tin oxide sensors using amplitude and transient responses. For transient responses we used a family of features, derived from the exponential moving average (EMA), to characterize chemo-resistive responses. All sensors were tested simultaneously against 20 individual volatile compounds from four chemical groups. The responses of the two types of sensors showed some independence. The zeolite-modified CTO sensors discriminated compounds better using either amplitude response or EMA features and CTO-modified sensors also responded three times faster.
The Amazon hydrometeorology: Climatology, variability and links to changes in weather patterns
NASA Astrophysics Data System (ADS)
Fernandes, Katia De Avila
My thesis focuses on improving the quantification of the hydrological cycle and understanding the atmospheric processes that link weather to climate in the Amazon River basin. By using ERA40 and independent observations, I assess how well we can estimate the surface water budget in the Amazon River basin. I find that ERA40 basin wide annual precipitation (P) overall agrees with observations showing a slight underestimation of 10% in average, whereas runoff (R) is underestimated by a larger margin (˜25%). Observed residual of precipitation and runoff (denoted as P-R) is better estimated by ERA40 P-R than actual ET which includes soil moisture nudging. The causes for said discrepancies were found to partly relate to soil moisture nudging that needs to be applied during the dry season to produce realistic ET and compensate for the low soil moisture recharge during the previous wet season. Insufficient recharge may in part be caused by underestimation of rainfall amount and intensity; moreover the shallow root layer in the model does not represent the deep soil water reservoir characteristic of the Amazonian forest. Whether the hydrological cycle and weather patterns in the Amazon have changed during the past few decades is a highly debatable but central question for detecting climate change in the region. The second part of my thesis focus on the physical links between rainfall changes detected in observations, and changes of synoptic scale systems as represented by ERA40. My results suggest that an observed delayed wet season onset is consistent with a decreasing number of cold air incursion (CAI) days in southern Amazon for the period 1979--2001. The variability of CAI into southern Amazon is related to the variability of SST upstream of South America in the tropical Pacific and Indian Oceans. A Singular Value Decomposition Analysis (SVD) between CAI days and global SST reveal three main modes of co-variability. The first mode describes the effect of the El Nino-Southern Oscillation. During El Nino (La Nina) a strong (weak) subtropical jet stream over South America tends to prevent transient systems from moving to southern Amazon, resulting in decreased (increased) CAI days during SON. The second mode of co-variability shows an anomalously warm western Indian Ocean also related to strong subtropical jet stream, except the jet is positioned farther north in South America, which along with the absence of a well defined subpolar jet stream, favors the northward displacement of transient waves into central South America, but show little response in southern Amazon. The CAI days reconstructed from the first and second modes do not present any significant trend in southern Amazon. CAI days reconstructed from the third mode of co-variability on the other hand, reproduces the SON observed trend in almost its entirety. The third mode of co-variability describes negative (positive) anomalies in CAI days associated with cold (warm) SST anomalies in the eastern tropical Pacific, anomalous wavetrain in the Southern Hemisphere and Walker Cell displacement that are unfavorable (favorable) to the incursion of CAI into southern Amazon. The temporal evolution of this mode correlates negatively with the Pacific Decadal Oscillation, suggesting that the recent gradual shift in PDO polarity reflected on the interannual response of Southern Pacific atmospheric patterns, hence on the behavior of transients propagation. The negative PDO index and its related atmospheric patterns are in agreement with the reduced observed CAI days, which also related to a delayed wet season onset in the southern Amazon.
The ambiguity of drought events, a bottleneck for Amazon forest drought response modelling
NASA Astrophysics Data System (ADS)
De Deurwaerder, Hannes; Verbeeck, Hans; Baker, Timothy; Christoffersen, Bradley; Ciais, Philippe; Galbraith, David; Guimberteau, Matthieu; Kruijt, Bart; Langerwisch, Fanny; Meir, Patrick; Rammig, Anja; Thonicke, Kirsten; Von Randow, Celso; Zhang, Ke
2016-04-01
Considering the important role of the Amazon forest in the global water and carbon cycle, the prognosis of altered hydrological patterns resulting from climate change provides strong incentive for apprehending the direct implications of drought on the vegetation of this ecosystem. Dynamic global vegetation models have the potential of providing a useful tool to study drought impacts on various spatial and temporal scales. This however assumes the models being able to properly represent drought impact mechanisms. But how well do the models succeed in meeting this assumption? Within this study meteorological driver data and model output data of 4 different DGVMs, i.e. ORCHIDEE, JULES, INLAND and LPGmL, are studied. Using the palmer drought severity index (PDSI) and the mean cumulative water deficit (MWD), temporal and spatial representation of drought events are studied in the driver data and are referenced to historical extreme drought events in the Amazon. Subsequently, within the resulting temporal and spatial frame, we studied the drought impact on the above ground biomass (AGB) and gross primary production (GPP) fluxes. Flux tower data, field inventory data and the JUNG data-driven GPP product for the Amazon region are used for validation. Our findings not only suggest that the current state of the studied DGVMs is inadequate in representing Amazon droughts in general, but also highlights strong inter-model differences in drought responses. Using scatterplot-studies and input-output correlations, we provide insight in the origin of these encountered inter-model differences. In addition, we present directives of model development and improvement in scope of Amazon forest drought response modelling.
Amazon Basin climate under global warming: the role of the sea surface temperature.
Harris, Phil P; Huntingford, Chris; Cox, Peter M
2008-05-27
The Hadley Centre coupled climate-carbon cycle model (HadCM3LC) predicts loss of the Amazon rainforest in response to future anthropogenic greenhouse gas emissions. In this study, the atmospheric component of HadCM3LC is used to assess the role of simulated changes in mid-twenty-first century sea surface temperature (SST) in Amazon Basin climate change. When the full HadCM3LC SST anomalies (SSTAs) are used, the atmosphere model reproduces the Amazon Basin climate change exhibited by HadCM3LC, including much of the reduction in Amazon Basin rainfall. This rainfall change is shown to be the combined effect of SSTAs in both the tropical Atlantic and the Pacific, with roughly equal contributions from each basin. The greatest rainfall reduction occurs from May to October, outside of the mature South American monsoon (SAM) season. This dry season response is the combined effect of a more rapid warming of the tropical North Atlantic relative to the south, and warm SSTAs in the tropical east Pacific. Conversely, a weak enhancement of mature SAM season rainfall in response to Atlantic SST change is suppressed by the atmospheric response to Pacific SST. This net wet season response is sufficient to prevent dry season soil moisture deficits from being recharged through the SAM season, leading to a perennial soil moisture reduction and an associated 30% reduction in annual Amazon Basin net primary productivity (NPP). A further 23% NPP reduction occurs in response to a 3.5 degrees C warmer air temperature associated with a global mean SST warming.
NASA Astrophysics Data System (ADS)
Li, Wenhong; Fu, Rong; Dickinson, Robert E.
2006-01-01
The global climate models for the Intergovernmental Panel on Climate Change Fourth Assessment Report (IPCC AR4) predict very different changes of rainfall over the Amazon under the SRES A1B scenario for global climate change. Five of the eleven models predict an increase of annual rainfall, three models predict a decrease of rainfall, and the other three models predict no significant changes in the Amazon rainfall. We have further examined two models. The UKMO-HadCM3 model predicts an El Niño-like sea surface temperature (SST) change and warming in the northern tropical Atlantic which appear to enhance atmospheric subsidence and consequently reduce clouds over the Amazon. The resultant increase of surface solar absorption causes a stronger surface sensible heat flux and thus reduces relative humidity of the surface air. These changes decrease the rate and length of wet season rainfall and surface latent heat flux. This decreased wet season rainfall leads to drier soil during the subsequent dry season, which in turn can delay the transition from the dry to wet season. GISS-ER predicts a weaker SST warming in the western Pacific and the southern tropical Atlantic which increases moisture transport and hence rainfall in the Amazon. In the southern Amazon and Nordeste where the strongest rainfall increase occurs, the resultant higher soil moisture supports a higher surface latent heat flux during the dry and transition season and leads to an earlier wet season onset.
NASA Astrophysics Data System (ADS)
Nace, T.; Baker, P. A.; Dwyer, G. S.; Hollander, D. J.; Silva, C. G.
2010-12-01
Throughout the late Quaternary the Amazon Basin has been influenced by abrupt North-South climate forcing and has undergone several large climate variations as recorded in previously reported speleothem records. Despite its importance in the global carbon cycle there are few continuous, high-resolution records of the Amazon Basin that date back to and beyond the last glacial period. In this study, we report the first results of a marine geological expedition to the Amazon continental shelf and fan region. During this expedition we collected eight ~30 meter piston cores along with gravity, box and multicores. At both sites we undertook complementary multibeam and high resolution seismic reflection profiling. Analyses will be presented from two sets of box/gravity/piston cores. One core (32m) is from a high sedimentation site on the northern flank of the main submarine canyon within the Amazon Fan complex at 1700m water depth. The other core (30m) is located on a seamount to the south of the Amazon Fan complex at 3100m water depth. A mixed assemblage of foraminifera is used for 14C dating to obtain an age model and bulk organic geochemistry is analyzed to determine percent organic carbon, C/N ratios, δ13C and δ15N. The cores were continuously measured shipboard for magnetic susceptibility and gamma density using a GEOTEK logger. These findings uncover the contribution of pelagic and terrestrial organic matter, whether the terrigenous carbon is derived from C3 versus C4 vegetation, and whether the marine organic matter is composed of phytoplankton or marine algae.
NASA Technical Reports Server (NTRS)
Yu, Hongbin; Chin, Mian; Yuan, Tianle; Bian, Huisheng; Remer, Lorraine A.; Prospero, Joseph M.; Omar, Ali; Winker, David; Yang, Yuekui; Zhang, Yan;
2015-01-01
The productivity of the Amazon rainforest is constrained by the availability of nutrients, in particular phosphorus (P). Deposition of long-range transported African dust is recognized as a potentially important but poorly quantified source of phosphorus. This study provides a first multiyear satellite-based estimate of dust deposition into the Amazon Basin using three dimensional (3D) aerosol measurements over 2007-2013 from the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP). The 7-year average of dust deposition into the Amazon Basin is estimated to be 28 (8 to approximately 48) Tg a(exp -1) or 29 (8 to approximately 50) kg ha(exp -1) a(exp -1). The dust deposition shows significant interannual variation that is negatively correlated with the prior-year rainfall in the Sahel. The CALIOP-based multi-year mean estimate of dust deposition matches better with estimates from in-situ measurements and model simulations than a previous satellite-based estimate does. The closer agreement benefits from a more realistic geographic definition of the Amazon Basin and inclusion of meridional dust transport calculation in addition to the 3D nature of CALIOP aerosol measurements. The imported dust could provide about 0.022 (0.0060.037) Tg P of phosphorus per year, equivalent to 23 (7 to approximately 39) g P ha(exp -1) a(exp -1) to fertilize the Amazon rainforest. This out-of-Basin P input largely compensates the hydrological loss of P from the Basin, suggesting an important role of African dust in preventing phosphorus depletion on time scales of decades to centuries.
Phylogeography of the dark fruit-eating bat Artibeus obscurus in the Brazilian Amazon.
Ferreira, Wallax Augusto Silva; Borges, Bárbara do Nascimento; Rodrigues-Antunes, Symara; de Andrade, Fernanda Atanaena Gonçalves; Aguiar, Gilberto Ferreira de Souza; de Sousa e Silva-Junior, José; Marques-Aguiar, Suely Aparecida; Harada, Maria Lúcia
2014-01-01
Artibeus obscurus (Mammalia: Chiroptera) is endemic to South America, being found in at least 18 Brazilian states. Recent studies revealed that different populations of this genus present distinct phylogeographic patterns; however, very little is known on the population genetics structure of A. obscurus in the Amazon rainforest. Here, using a fragment (1010bp) of the mitochondrial gene cytochrome b from 87 samples, we investigated patterns of genetic divergence among populations of A. obscurus from different locations in the Brazilian Amazon rainforest and compared them with other Brazilian and South American regions. Analysis of molecular variance (AMOVA), fixation index (Fst) analysis, and phylogeographic patterns showed divergence between two major monophyletic groups, each one corresponding to a geographic region associated with the Atlantic and Amazon forest biomes. The Atlantic forest clusters formed a monophyletic group with a high bootstrap support and a fragmented distribution that follows the pattern predicted by the Refuge Theory. On the other hand, a different scenario was observed for the Amazon forest, where no fragmentation was identified. The AMOVA results revealed a significant geographic heterogeneity in the distribution of genetic variation, with 70% found within populations across the studied populations (Fst values ranging from 0.05864 to 0.09673; φST = 0.55). The intrapopulational analysis revealed that one population (Bragança) showed significant evidence of population expansion, with the formation of 2 distinct phylogroups, suggesting the occurrence of a subspecies or at least a different population in this region. These results also suggest considerable heterogeneity for A. obscurus in the Amazon region.
NASA Astrophysics Data System (ADS)
Yu, Hongbin; Chin, Mian; Yuan, Tianle; Bian, Huisheng; Remer, Lorraine A.; Prospero, Joseph M.; Omar, Ali; Winker, David; Yang, Yuekui; Zhang, Yan; Zhang, Zhibo; Zhao, Chun
2015-03-01
The productivity of the Amazon rainforest is constrained by the availability of nutrients, in particular phosphorus (P). Deposition of long-range transported African dust is recognized as a potentially important but poorly quantified source of phosphorus. This study provides a first multiyear satellite-based estimate of dust deposition into the Amazon Basin using three-dimensional (3-D) aerosol measurements over 2007-2013 from the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP). The 7 year average of dust deposition into the Amazon Basin is estimated to be 28 (8-48) Tg a-1 or 29 (8-50) kg ha-1 a-1. The dust deposition shows significant interannual variation that is negatively correlated with the prior-year rainfall in the Sahel. The CALIOP-based multiyear mean estimate of dust deposition matches better with estimates from in situ measurements and model simulations than a previous satellite-based estimate does. The closer agreement benefits from a more realistic geographic definition of the Amazon Basin and inclusion of meridional dust transport calculation in addition to the 3-D nature of CALIOP aerosol measurements. The imported dust could provide about 0.022 (0.006-0.037) Tg P of phosphorus per year, equivalent to 23 (7-39) g P ha-1 a-1 to fertilize the Amazon rainforest. This out-of-basin phosphorus input is comparable to the hydrological loss of phosphorus from the basin, suggesting an important role of African dust in preventing phosphorus depletion on timescales of decades to centuries.
Amazon water lenses and the influence of the North Brazil Current on the continental shelf
NASA Astrophysics Data System (ADS)
Prestes, Yuri O.; Silva, Alex Costa da; Jeandel, Catherine
2018-05-01
The exchange processes on the Amazon continental shelf in northern Brazil are subject to complex interactions that involve forcings derived from distinct sources. The Amazon shelf is a unique and highly dynamic environment in which considerable discharge of freshwater enters the Atlantic Ocean, producing extensive Amazon Water Lenses (AWL). In addition to the presence of the AWL, the shelf is influenced by the semidiurnal oscillations of the tides and the strong North Brazil Current (NBC), a boundary current of the western Atlantic. The present study was based primarily on the influence of the freshwater input and the NBC on the shelf and the Amazon Shelf Break (ASB) off the mouth of the Pará River. For this purpose, hydrographic and hydrodynamic data were obtained by moorings of the AMANDES Project (April-July 2008), located on the Amazon shelf and the ASB. Spectral analysis and the continuous wavelet transform were applied to define tidal (high frequency/short period) and subtidal (low frequency/long period) signals. The results indicated that on both the shelf and the break, the semidiurnal tides are responsible for the residual landward transport and are predominantly across-shelf. Low-frequency motions in the synoptic bands and the AWL are related to spatial changes in the velocity field, mainly on the ASB in the along-shelf direction. The flow of the NBC can be interpreted as an along-shelf low-frequency oscillation capable of altering the spatial configuration of the velocity field, although its influence is perceived only in the absence of the AWL.
Kwon, Jung-Hwan; Escher, Beate I
2008-03-01
Low cost in vitro tools are needed at the screening stage of assessment of bioaccumulation potential of new and existing chemicals because the number of chemical substances that needs to be tested highly exceeds the capacity of in vivo bioconcentration tests. Thus, the parallel artificial membrane permeability assay (PAMPA) system was modified to predict passive uptake/ elimination rate in fish. To overcome the difficulties associated with low aqueous solubility and high membrane affinity of highly hydrophobic chemicals, we measured the rate of permeation from the donor poly(dimethylsiloxane)(PDMS) disk to the acceptor PDMS disk through aqueous and PDMS membrane boundary layers and term the modified PAMPA system "PDMS-PAMPA". Twenty chemicals were selected for validation of PDMS-PAMPA. The measured permeability is proportional to the passive elimination rate constant in fish and was used to predict the "minimum" in vivo elimination rate constant. The in vivo data were very close to predicted values except for a few polar chemicals and metabolically active chemicals, such as pyrene and benzo[a]pyrene. Thus, PDMS-PAMPA can be an appropriate in vitro system for nonmetabolizable chemicals. Combination with metabolic clearance rates using a battery of metabolic degradation assays would enhance the applicability for metabolizable chemicals.
NASA Technical Reports Server (NTRS)
Butler, C.
1986-01-01
Software development for the Trospheric Air Motion Measurement Systems (TAMMS) is documented. In July/August the TAMMS was flown on the NASA/Goddard Flight Center Electra aircraft for 19 mission for the ABLE-2A (Amazon Boundary Layer Experiment) in Brazil. In December 1985, several flights were performed to assess the contamination and boundary layer of the Electra. Position data, flow angles, pressure transducer measurements were recorded. The programs written for the ABLE-2A were modified due to timing considerations for this particular program. The 3-step programs written for EBLE (Electra Boundary Layer Experiment) are described. Power up and log-on procedures are discussed. A few editing techniques are described for modification of the programs.
Sparse pre-Columbian human habitation in western Amazonia.
McMichael, C H; Piperno, D R; Bush, M B; Silman, M R; Zimmerman, A R; Raczka, M F; Lobato, L C
2012-06-15
Locally extensive pre-Columbian human occupation and modification occurred in the forests of the central and eastern Amazon Basin, but whether comparable impacts extend westward and into the vast terra firme (interfluvial) zones, remains unclear. We analyzed soils from 55 sites across central and western Amazonia to assess the history of human occupation. Sparse occurrences of charcoal and the lack of phytoliths from agricultural and disturbance species in the soils during pre-Columbian times indicated that human impacts on interfluvial forests were small, infrequent, and highly localized. No human artifacts or modified soils were found at any site surveyed. Riverine bluff areas also appeared less heavily occupied and disturbed than similar settings elsewhere. Our data indicate that human impacts on Amazonian forests were heterogeneous across this vast landscape.
Zhou, Xiahui; Chen, Xiaocheng; Wu, Xin; Cao, Gang; Zhang, Junjie
2016-04-01
In this study, high-performance liquid chromatography coupled with amaZon SL high-performance ion trap mass spectrometry was used to analyze the target components in white chrysanthemum flowers of Hangzhou. Twenty-one components were detected and identified in both white chrysanthemum flowers of Hangzhou samples by using target compound analysis. Furthermore, seven new compounds in white chrysanthemum flowers of Hangzhou were found and identified by analyzing the fragment ion behavior in the mass spectra. The established method can be expedient for the global quality investigation of complex components in herbal medicines and food. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Antibiotic Algae by Chemical Surface Engineering.
Kerschgens, Isabel P; Gademann, Karl
2018-03-02
Chemical cell-surface engineering is a tool for modifying and altering cellular functions. Herein, we report the introduction of an antibiotic phenotype to the green alga Chlamydomonas reinhardtii by chemically modifying its cell surface. Flow cytometry and confocal microscopy studies demonstrated that a hybrid of the antibiotic vancomycin and a 4-hydroxyproline oligomer binds reversibly to the cell wall without affecting the viability or motility of the cells. The modified cells were used to inhibit bacterial growth of Gram-positive Bacillus subtilis cultures. Delivery of the antibiotic from the microalgae to the bacterial cells was verified by microscopy. Our studies provide compelling evidence that 1) chemical surface engineering constitutes a useful tool for the introduction of new, previously unknown functionality, and 2) living microalgae can serve as new platforms for drug delivery. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
NASA Astrophysics Data System (ADS)
Colinvaux, P. A.; De Oliveira, P. E.; Bush, M. B.
2000-01-01
Plants respond to Pleistocene climatic change as species, not as associations or biomes. This has been demonstrated unequivocally by paleobotanical data for temperate latitudes. In the far richer vegetations of the tropics species populations also fluctuated independently in response to climatic forcing, from their longlasting glacial states to the patterns of brief interglacials like the present and back again. We use pollen data to reconstruct the vegetation of the Amazon basin in oxygen isotope stages 3 and 2 of the last glaciation in order to measure how the plant populations of the Amazon responded to the global warming at the onset of the Holocene. We find that plant communities of the neotropics vent copious pollen to lake sediments and that this pollen yields powerful signals for community composition. Three continuous sedimentary records reaching through oxygen isotope stage 2 are available from the Amazon lowlands, those from Carajas, Lake Pata and marine deposits off the mouth of the Amazon River. All three records yield pollen histories of remarkable constancy and stability. By comparing them with deposits of equal antiquity from the cerrado (savanna) of central Brazil, we show that most of the Amazon lowlands remained under forest throughout a glacial cycle. This forest was never fragmented by open vegetation as postulated by the refugia hypothesis. Instead the intact forest of glacial times included significant populations of plants that are now montane, suggesting that the global warming of the early Holocene resulted in the expulsion of heat intolerant plants from the lowland forest. Pollen data from the Amazonian flank of the Andes and from Pacific Panama provide evidence that populations of these heat intolerant plants survive the heat of interglacials in part by maintaining large populations at cooler montane altitudes. Our conclusion that the Amazon lowlands were forested in glacial times specifically refutes the hypothesis of Amazonian glacial aridity. Accordingly we examine the geomorphological evidence for glacial aridity and find it wanting. Of the three paleodune systems reported for tropical South America, that of NE Brazil was active in the Holocene as well as the Pleistocene. Parts of NE Brazil were actually moister than now in late-glacial times. Paleodunes in the Pantanal have never been seen on the ground, and those in the Orinoco Llanos are undated and may be of any age since the Tertiary. Arkosic sands in the Amazon fan deposits came from the Andean foothills or from down cutting by rivers and cannot be evidence of a former arid land surface. White sands of Amazonia formed as podzols, not by aeolian activity. Such Amazonian stone lines as have received critical scrutiny are concretionary pisolites in stratigraphic formations that are more than ten million years old. Although the Amazon was never arid, modeling cooler glacial tropics gives plausibility to a somewhat drier Amazon in glacial times, a concept given substance by pollen data for the movement of ecotones in Rondonia, by stream histories in the Bolivian Andes, and by evidence for lowered lake levels at Carajas and Lake Pata. But this reduced precipitation was never enough to fragment the forest in the Amazon lowlands themselves. Pleistocene mammals of the Napo river valley in Ecuador were able to live along the river system in a forested landscape. Our data suggest that the Amazon forests have been stable since the start of the Pleistocene, a fact that has contributed to the storage of vast diversity. The coming anthropogenic global warming and CO 2 enrichment will add to the global warming already endured by Amazon biota in the Holocene. We think it possible that the expulsion from the lowland forests of heat intolerant species is already complete and that the forest property of maintaining its own microhabitat will allow the high species richness to survive more global warming, provided large enough tracts of forest are preserved.
Chronic chagasic cardiopathy in Amazon region: an etiology to remember.
Ferreira, João Marcos Bemfica Barbosa; Guerra, Jorge Augusto de Oliveira; Magalhães, Belisa Maria Lopes; Coelho, Leíla I A R C; Maciel, Marcel Gonçalves; Barbosa, Maria das Graças Vale
2009-12-01
This study assessed the frequency of chronic chagasic cardiopathy (CCC) in 37 autochthonus patients from Amazon region with left ventricular systolic dysfunction of undefined etiology. Three cases were diagnosed in the studied sample, with an 8.1% frequency.
Environment Industry, Industry Study, Spring 2008
2008-01-01
challenge is deforestation of the Amazon rainforest due to illegal logging, cattle ranching, commercial agriculture and settlement/ subsistence farming...Since the Amazon accounts for thirty percent of all remaining tropical forest in the world, the challenge is immense.24 Understandably, Brazil is a
Federal Register 2010, 2011, 2012, 2013, 2014
2011-04-11
... 03/23/2011 20110137 G Amazon.com , Inc.; Quidsi, Inc.; Amazon.com , Inc. 20110603 G Ares Corporate Opportunities Fund III, L.P.; Global Defense Technology & Systems, Inc.; Ares Corporate Opportunities Fund III...
Granular cell tumor in an endangered Puerto Rican Amazon parrot (Amazon vittata)
Quist, C.F.; Latimer, K.S.; Goldade, S.L.; Rivera, A.; Dein, F.J.
1999-01-01
A 3 cm diameter mass from the metacarpus of a Puerto Rican Amazon parrot was diagnosed as a granular cell tumour based on light microscopy. The cytoplasmic granules were periodic-acid Schiff positive and diastase resistant. Ultrastructural characteristics of the cells included convoluted nuclei and the presence of numerous cytoplasmic tertiary lysosomes. This is only the second granular cell tumour reported in a bird. We speculate that most granular cell tumours are derived from cells that are engaged in some type of cellular degradative process, creating a similar morphologic appearance, but lacking a uniform histogenesis.
Condition and fate of logged forests in the Brazilian Amazon.
Asner, Gregory P; Broadbent, Eben N; Oliveira, Paulo J C; Keller, Michael; Knapp, David E; Silva, José N M
2006-08-22
The long-term viability of a forest industry in the Amazon region of Brazil depends on the maintenance of adequate timber volume and growth in healthy forests. Using extensive high-resolution satellite analyses, we studied the forest damage caused by recent logging operations and the likelihood that logged forests would be cleared within 4 years after timber harvest. Across 2,030,637 km2 of the Brazilian Amazon from 1999 to 2004, at least 76% of all harvest practices resulted in high levels of canopy damage sufficient to leave forests susceptible to drought and fire. We found that 16+/-1% of selectively logged areas were deforested within 1 year of logging, with a subsequent annual deforestation rate of 5.4% for 4 years after timber harvests. Nearly all logging occurred within 25 km of main roads, and within that area, the probability of deforestation for a logged forest was up to four times greater than for unlogged forests. In combination, our results show that logging in the Brazilian Amazon is dominated by highly damaging operations, often followed rapidly by deforestation decades before forests can recover sufficiently to produce timber for a second harvest. Under the management regimes in effect at the time of our study in the Brazilian Amazon, selective logging would not be sustained.
The Expansion of the Economic Frontier and the Diffusion of Violence in the Amazon
Souza, Patrícia Feitosa; Xavier, Diego Ricardo; Rican, Stephane; de Matos, Vanderlei Pascoal; Barcellos, Christovam
2015-01-01
Over the last few decades, the occupation of the Amazon and the expansion of large-scale economic activities have exerted a significant negative impact on the Amazonian environment and on the health of the Amazon’s inhabitants. These processes have altered the context of the manifestation of health problems in time and space and changed the characteristics of the spatial diffusion of health problems in the region. This study analyzed the relationships between the various economic processes of territorial occupation in the Amazon and the spatial diffusion of homicidal violence through the configuration of networks of production, as well as the movements of population and merchandise. Statistical data on violence, deforestation, the production of agricultural items, and socio-economic variables, georeferenced and available for the 771 municipalities of the Legal Amazon were used in this study. The results suggest that the diffusion of violence closely follows the economic expansion front, which is related to deforestation and livestock production but has little relation to grain production, demonstrating steps and typologies of recent occupation in the Amazon that promote violence. These spatial patterns reveal environmental and socio-economic macro-determinants that materialize in geographic space through the construction of highways and the formation of city networks. PMID:26024359
Condition and fate of logged forests in the Brazilian Amazon
Asner, Gregory P.; Broadbent, Eben N.; Oliveira, Paulo J. C.; Keller, Michael; Knapp, David E.; Silva, José N. M.
2006-01-01
The long-term viability of a forest industry in the Amazon region of Brazil depends on the maintenance of adequate timber volume and growth in healthy forests. Using extensive high-resolution satellite analyses, we studied the forest damage caused by recent logging operations and the likelihood that logged forests would be cleared within 4 years after timber harvest. Across 2,030,637 km2 of the Brazilian Amazon from 1999 to 2004, at least 76% of all harvest practices resulted in high levels of canopy damage sufficient to leave forests susceptible to drought and fire. We found that 16 ± 1% of selectively logged areas were deforested within 1 year of logging, with a subsequent annual deforestation rate of 5.4% for 4 years after timber harvests. Nearly all logging occurred within 25 km of main roads, and within that area, the probability of deforestation for a logged forest was up to four times greater than for unlogged forests. In combination, our results show that logging in the Brazilian Amazon is dominated by highly damaging operations, often followed rapidly by deforestation decades before forests can recover sufficiently to produce timber for a second harvest. Under the management regimes in effect at the time of our study in the Brazilian Amazon, selective logging would not be sustained. PMID:16901980
Tree rings and rainfall in the equatorial Amazon
NASA Astrophysics Data System (ADS)
Granato-Souza, Daniela; Stahle, David W.; Barbosa, Ana Carolina; Feng, Song; Torbenson, Max C. A.; de Assis Pereira, Gabriel; Schöngart, Jochen; Barbosa, Joao Paulo; Griffin, Daniel
2018-05-01
The Amazon basin is a global center of hydroclimatic variability and biodiversity, but there are only eight instrumental rainfall stations with continuous records longer than 80 years in the entire basin, an area nearly the size of the coterminous US. The first long moisture-sensitive tree-ring chronology has been developed in the eastern equatorial Amazon of Brazil based on dendrochronological analysis of Cedrela cross sections cut during sustainable logging operations near the Rio Paru. The Rio Paru chronology dates from 1786 to 2016 and is significantly correlated with instrumental precipitation observations from 1939 to 2016. The strength and spatial scale of the precipitation signal vary during the instrumental period, but the Rio Paru chronology has been used to develop a preliminary reconstruction of February to November rainfall totals from 1786 to 2016. The reconstruction is related to SSTs in the Atlantic and especially the tropical Pacific, similar to the stronger pattern of association computed for the instrumental rainfall data from the eastern Amazon. The tree-ring data estimate extended drought and wet episodes in the mid- to late-nineteenth century, providing a valuable, long-term perspective on the moisture changes expected to emerge over the Amazon in the coming century due to deforestation and anthropogenic climate change.
Amazon Deforestation Fires Increase Plant Productivity through Changes in Diffuse Radiation
NASA Astrophysics Data System (ADS)
Rap, A.; Reddington, C.; Spracklen, D. V.; Mercado, L.; Haywood, J. M.; Bonal, D.; Butt, N.; Phillips, O.
2013-12-01
Over the past few decades a large increase in carbon storage has been observed in undisturbed forests across Amazonia. The reason for such a sink is unclear, although many possible mechanisms have been suggested, including changes in temperature, carbon dioxide, precipitation, clouds, and solar radiation. In this work we focus on one such mechanism, namely the increase in plant photosynthesis due to changes in diffuse radiation caused by atmospheric aerosols from large-scale deforestation fires that now occur throughout the Amazon region. We estimate that this mechanism has increased dry season (August-September) net primary productivity (NPP) by up to 30% across wide regions of the Amazon. We conclude that aerosol from deforestation fires may be responsible for a substantial fraction of the Amazon carbon sink that has been observed. Our approach is based on the combined use of three models: (i) the Global Model of Aerosol Processes (GLOMAP), (ii) the Edwards-Slingo radiation model, and (iii) the UK Met Office JULES land-surface scheme, constrained against in-situ aerosol and radiation observation datasets from several Amazonian sites. A 10 year (1999-2008) GLOMAP simulation using GFED3 biomass burning emissions is first evaluated against aerosol observations, indicating that the model is able to capture the Amazon aerosol seasonality, with enhanced concentrations during the dry season driven by biomass burning. The radiation scheme is then shown to be in good agreement with total and diffuse radiation in-situ observations, the model being able to capture the high total and low diffuse radiation flux in the dry season, as well as the low total and high diffuse radiation flux in the wet season. We then use our modelling framework to quantify the contribution of deforestation fires to diffuse/direct radiation fraction and forest productivity. We calculate that deforestation fires increase dry season diffuse radiation by up to 60% or 30 Wm-2. Finally, we use the JULES model to show that this increase in diffuse radiation is responsible for a substantial growth in gross primary productivity (GPP), enhancing Amazon-wide dry-season GPP by 5% with local increases of up to 15%. Most of this GPP response results in an increase in NPP, estimated in the dry season at 10% across the Amazon with local increases as large as 30%. This substantial NPP enhancement spatially matches observed increases in forest biomass storage across the Amazon. We thus suggest that deforestation fires have an important impact on the Amazon carbon budget and attempt to estimate the fraction of the observed forest carbon sink that can be attributed to this mechanism. Change [%] in diffuse radiation due to deforestation
Salzman, Sivan; Romanofsky, Henry J; Giannechini, Lucca J; Jacobs, Stephen D; Lambropoulos, John C
2016-02-20
We describe the anisotropy in the material removal rate (MRR) of the polycrystalline, chemical-vapor deposited zinc sulfide (ZnS). We define the polycrystalline anisotropy via microhardness and chemical erosion tests for four crystallographic orientations of ZnS: (100), (110), (111), and (311). Anisotropy in the MRR was studied under magnetorheological finishing (MRF) conditions. Three chemically and mechanically modified magnetorheological (MR) fluids at pH values of 4, 5, and 6 were used to test the MRR variations among the four single-crystal planes. When polishing the single-crystal planes and the polycrystalline with pH 5 and pH 6 MR fluids, variations were found in the MRR among the four single-crystal planes and surface artifacts were observed on the polycrystalline material. When polishing the single-crystal planes and the polycrystalline with the modified MR fluid at pH 4, however, minimal variation was observed in the MRR among the four orientations and a reduction in surface artifacts was achieved on the polycrystalline material.
Expanding the chemical toolbox for the synthesis of large and uniquely modified proteins
NASA Astrophysics Data System (ADS)
Bondalapati, Somasekhar; Jbara, Muhammad; Brik, Ashraf
2016-05-01
Methods to prepare proteins that include a specific modification at a desired position are essential for understanding their cellular functions and physical properties in living systems. Chemical protein synthesis, which relies on the chemoselective ligation of unprotected peptides, enables the preparation of modified proteins that are not easily fabricated by other methods. In contrast to recombinant approaches, chemical synthesis can be used to prepare protein analogues such as D-proteins, which are useful in protein structure determination and the discovery of novel therapeutics. Post-translationally modifying proteins is another example where chemical protein synthesis proved itself as a powerful approach for preparing samples with high homogeneity and in workable quantities. In this Review, we discuss the basic principles of the field, focusing on novel chemoselective peptide ligation approaches such as native chemical ligation and the recent advances based on this method with a proven record of success in the synthesis of highly important protein targets.
Use of intertidal areas by shrimps (Decapoda) in a Brazilian Amazon estuary.
Sampaio, Hebert A; Martinelli-Lemos, Jussara M
2014-03-01
The present work investigated the occupation and the correlation of the shrimp abundance in relation to environmental variables in different habitats (mangroves, salt marshes and rocky outcrops) in an Amazon estuary. The collections were made in August and November 2009, at low syzygy tide on Areuá Beach, situated in the Extractive Reserve of Mãe Grande de Curuçá, Pará, Brazil totaling 20 pools. In each environment, we recorded the physical-chemical factors (pH, salinity, and temperature) and measured the area (m2) and volume (m3) of every pool through bathymetry. The average pH, salinity, temperature, area and volume of tide pools were 8.75 (± 0.8 standard deviation), 35.45 (± 3), 29.49 °C (± 2.32), 27.41 m2 (± 41.18), and 5.19 m3 (± 8.01), respectively. We caught a total of 4,871 shrimps, distributed in three families and four species: Farfantepenaeus subtilis (98.36%) (marine) followed by Alpheus pontederiae (0.76%) (estuarine), Macrobrachium surinamicum (0.45%) and Macrobrachium amazonicum (0.43%) predominantly freshwater. The species F. subtilis and A. pontederiae occurred in the three habitats, whereas M. surinamicum occurred in salt marsh and rocky outcrop and M. amazonicum only in marisma. Temperature and pH were the most important environmental descriptors that significantly affected the density and biomass of shrimps.
Nutritional composition and vitamin C stability in stored camu-camu (Myrciaria dubia) pulp.
Justi, K C; Visentainer, J V; Evelázio de Souza, N; Matsushita, M
2000-12-01
Camu-camu (Myrciaria dubia), a native fruit of the Amazon region, is one of the richest sources of vitamin C (2.4 to 3.0 g/100 g in the pulp) found in Brazil. The purpose of this work was the physical-chemical characterization of some nutrients and the valuation of vitamin C stability in stored camu-camu pulp, produced by the Agronomic Institute of Paraná (IAPAR), Paraná State, Brazil. The vitamin C determination was made by titration with potassium iodate. The fruit produced in Paraná State, presented a lower content of vitamin C than the one native of the amazon region, possibly due to the different development conditions of the plant, and consequently of the fruit, as well as the climatic variation, the humidity and the characteristics of the soil. Regarding the vitamin C stability in stored (-18 degrees C) camu-camu pulp, a considerable decrease in its concentration until the 28th day was observed lost 23% (from 1.57 to 1.21 g/100 g), staying approximately the same until the end of the experiment. After 335 days of storage, the content found was of approximately 1.16 g/100 g of pulp, the ascorbic acid losses amounted to 26%. This content was still higher than the one found for most fruits that are good sources of this vitamin.
NASA Astrophysics Data System (ADS)
Asner, Gregory P.; Anderson, Christopher B.; Martin, Roberta E.; Tupayachi, Raul; Knapp, David E.; Sinca, Felipe
2015-07-01
Tropical forest functional diversity, which is a measure of the diversity of organismal interactions with the environment, is poorly understood despite its importance for linking evolutionary biology to ecosystem biogeochemistry. Functional diversity is reflected in functional traits such as the concentrations of different compounds in leaves or the density of leaf mass, which are related to plant activities such as plant defence, nutrient cycling, or growth. In the Amazonian lowlands, river movement and microtopography control nutrient mobility, which may influence functional trait distributions. Here we use airborne laser-guided imaging spectroscopy to develop maps of 16 forest canopy traits, throughout four large landscapes that harbour three common forest community types on the Madre de Dios and Tambopata rivers in southwestern Amazonia. Our maps, which are based on quantitative chemometric analysis of forest canopies with visible-to-near infrared (400-2,500 nm) spectroscopy, reveal substantial variation in canopy traits and their distributions within and among forested landscapes. Forest canopy trait distributions are arranged in a nested pattern, with location along rivers controlling trait variation between different landscapes, and microtopography controlling trait variation within landscapes. We suggest that processes of nutrient deposition and depletion drive increasing phosphorus limitation, and a corresponding increase in plant defence, in an eastward direction from the base of the Andes into the Amazon Basin.
A Comprehensive Evaluation of H2SO4 formation from OH and sCI pathways in high BVOC environments
NASA Astrophysics Data System (ADS)
Kim, S.; Seco, R.; Park, J. H.; Guenther, A. B.; Smith, J. N.; Kuang, C.; Bustillos, J. O. V.; Tota, J.; Souza, R. A. F. D.
2014-12-01
The recently highlighted importance of stabilized Criegee intermediates (sCI) as an oxidant for atmospheric SO2 triggered a number of studies to assess the atmospheric implications of H2SO4 formation from the sCI reaction pathway. In addition, it has not been clear why new particle formation events are not observed in the Amazon rain forest. The mostly widely speculated reason has been a very low H2SO4 level. We will present quantitative assessments of SO2 oxidation by sCI leading to the H2SO4 production using a comprehensive observational dataset from a tropical rainforest study during the GOAmazon field campaign at the T3 site in Manacapuru, Amazonas, Brazil. To our best knowledge, this is the first observation of H2SO4 and OH in Amazon and is unique for all tropical sites due to the accompanying comprehensive gas and aerosol observations such as CO, NOX, SO2, VOCs, and physical and chemical characteristics of aerosols. We will discuss observed H2SO4 levels during the GOAmazon field campaigns to demonstrate 1) H2SO4 formation potential from OH and sCI oxidation pathways by contrasting extremely clean and relatively polluted air masses and 2) the Implications of the observed H2SO4 levels in new particle formation and particle growth events.
Modified NASA-Lewis chemical equilibrium code for MHD applications
NASA Technical Reports Server (NTRS)
Sacks, R. A.; Geyer, H. K.; Grammel, S. J.; Doss, E. D.
1979-01-01
A substantially modified version of the NASA-Lewis Chemical Equilibrium Code was recently developed. The modifications were designed to extend the power and convenience of the Code as a tool for performing combustor analysis for MHD systems studies. The effect of the programming details is described from a user point of view.
40 CFR 721.630 - Salt of a modified tallow alkylenediamine (generic).
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Salt of a modified tallow alkylenediamine (generic). 721.630 Section 721.630 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT SIGNIFICANT NEW USES OF CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.630 Sal...
Dias, V M C; Cardoso, A S B
2006-05-01
Reference methods for determining lead in food are usually time-consuming. This paper reports a straightforward procedure using electrothermal atomic absorption spectrometry (ETAAS), to determine lead (Pb) in fat-free sweets. Several chemical modifiers were examined and results showed that it is not necessary to digest the samples, when a rhodium (Rh) modifier was used. The samples were dissolved in nitric acid and the determination of Pb was performed by ETAAS, using Rh chemical modifier at a pyrolysis temperature of 900 degrees C and an atomization temperature of 1,500 degrees C. No ashing step was employed and aqueous standards were used, in the range 2-10 microg l(-1). The limit of quantification was 0.095 mg kg(-1), and the accuracy of the method was verified by analysing certified reference materials.
Total chemical synthesis of modified histones
NASA Astrophysics Data System (ADS)
Qi, Yun-Kun; Ai, Hua-Song; Li, Yi-Ming; Yan, Baihui
2018-02-01
In the post-genome era, epigenetics has received increasing attentions in recent years. The post-translational modifications (PTMs) of four core histones play central roles in epigenetic regulation of eukaryotic genome by either directly altering the biophysical properties of nucleosomes or by recruiting other effector proteins. In order to study the biological functions and structural mechanisms of these histone PTMs, an obligatory step is to prepare a sufficient amount of homogeneously modified histones. This task cannot be fully accomplished either by recombinant technology or enzymatic modification. In this context, synthetic chemists have developed novel protein synthetic tools and state-of-the-art chemical ligation strategies for the preparation of homologous modified histones. In this review, we summarize the recent advances in the preparation of modified histones, focusing on the total chemical synthesis strategies. The importance and potential of synthetic chemistry for the study of histone code will be also discussed.
Chirinos, Rosana; Pedreschi, Romina; Domínguez, Gilberto; Campos, David
2015-04-15
A physico-chemical and phytochemical characterisation of the oil of two rich sources of polyunsaturated fatty acids, tocopherols and phytosterols is presented for two close species of Plukenetia, endemic to the Amazon Region of Peru. Plukenetia huayllabambana presented approximately 9% more oil yield than Plukenetia volubilis. Fatty acid profiles were pretty similar for both species but P. huayllabambana presented a significantly higher content of α-linolenic acid than P. volubilis (51.3 and 45.6 g/100 g oil, respectively). Important contents of γ- and δ-tocopherol were evidenced in both oils (127.6 and 84.0 and, 93.3 and 47.5 mg/100 g oil, for P. volubilis and P. huayllabambana, respectively). β-Sitosterol was the most important and representative phytosterol in both oils (∼127 mg/100 g oil). The results of this study indicate P. huayllabambana as an important dietary source of health promoting phytochemicals. Copyright © 2014 Elsevier Ltd. All rights reserved.
Risley, Jessica May; Chen, David Da Yong
2017-06-01
Post-column chemical environment modification can affect detection sensitivity and signal appearance when capillary electrophoresis is coupled through electrospray ionization to mass spectrometry (CE-ESI-MS). In this study, changes in the signal intensity and peak shape of N-Acetylneuraminic acid (Neu5Ac) were examined when the modifier solution used in a flow-through microvial interface for CE-ESI-MS was prepared using an acidic or basic background electrolyte (BGE) composition. The use of a basic modifier resulted in improved detection compared to the results obtained when an acidic modifier was used in negative ion mode. Increased sensitivity and more symmetrical peak shape were obtained. Using an acidic modifier, the LOD of Neu5Ac was 47.7 nM, whereas for a basic modifier, the LOD of Neu5Ac was 5.20 nM. The calculated asymmetry factor at 100 nM of Neu5Ac ranged from 0.71 to 1.5 when an acidic modifier was used, while the factor ranged from 1.0 to 1.1 when a basic modifier was used. Properly chosen post-column chemical modification can have a significant effect on the performance of the CE-MS system. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
[Cardiac involvement in Acute Chagas' Disease cases in the Amazon region].
Barbosa-Ferreira, João Marcos; Guerra, Jorge Augusto de Oliveira; Santana Filho, Franklin Simões de; Magalhães, Belisa Maria Lopes; Coelho, Leíla I A R C; Barbosa, Maria das Graças Vale
2010-06-01
The cardiac involvement of five patients from the Amazon region with Acute Chagas' Disease (ACD) is described. Four of these patients presented probable oral transmission. All of them presented some degree of cardiac involvement, but there were no deaths.
Insight on the Peruvian Amazon River: A Planform Metric Characterization of its Morphodynamics
NASA Astrophysics Data System (ADS)
Garcia, A. M. P.; Ortals, C.; Frias, C. E.; Abad, J. D.; Vizcarra, J.
2014-12-01
Starting in Peru, the Amazon River flows through Colombia and Brazil; additionally, tributaries from Bolivia, Venezuela, and Ecuador contribute to the massive river and its unique geomorphic features. Accordingly, the Amazon Basin has become an important aspect of South America; it is an area of extraordinary biodiversity, rich resources, and unique cultures. However, due to the sheer magnitude and exceptionality of the Amazon River, research regarding the morphodynamic processes that shape and define the river has been difficult. Consequently, current research has not completely understood the planform dynamics of some portions of this river that present a main channel and secondary channels known as "anabranching structures". The purpose of this research was to gain an understanding of the geomorphology of the upper Amazon, the Peruvian section, by obtaining migration rates and planform metrics, including channel count, length, width, and sinuosity, as well as island count, area, and shape. With this data, the morphodynamics of the Peruvian Amazon, especially the relationship between the main channel and its secondary channels in each "anabranching structure" along the river, could be analyzed according to correlations found between various metrics. This analysis was carried out for 5-year time spans over a period of 25 years. Preliminary results showed that the average migration rate versus channel bend radius envelope peak is lower for the secondary channels than for the main channel. However, the maximum migration rate was not always found in the main channel; for several structures, the most dynamic channels were the secondary ones. This implies a certain periodicity to the river's migratory patterns that could be related to the valley boundaries, the local channel sinuosity or geological formations in the study area.
Applying NASA Imaging Radar Datasets to Investigate the Geomorphology of the Amazon's Planalto
NASA Astrophysics Data System (ADS)
McDonald, K. C.; Campbell, K.; Islam, R.; Alexander, P. M.; Cracraft, J.
2016-12-01
The Amazon basin is a biodiversity rich biome and plays a significant role into shaping Earth's climate, ocean and atmospheric gases. Understanding the history of the formation of this basin is essential to our understanding of the region's biodiversity and its response to climate change. During March 2013, the NASA/JPL L-band polarimetric airborne imaging radar, UAVSAR, conducted airborne studies over regions of South America including portions of the western Amazon basin. We utilize UAVSAR imagery acquired during that time over the Planalto, in the Madre de Dios region of southeastern Peru in an assessment of the underlying geomorphology, its relationship to the current distribution of vegetation, and its relationship to geologic processes through deep time. We employ UAVSAR data collections to assess the utility of these high quality imaging radar data for use in identifying geomorphologic features and vegetation communities within the context of improving the understanding of evolutionary processes, and their utility in aiding interpretation of datasets from Earth-orbiting satellites to support a basin-wide characterization across the Amazon. We derive maps of landcover and river branching structure from UAVSAR imagery. We compare these maps to those derived using imaging radar datasets from the Japanese Space Agency's ALOS PALSAR and Digital Elevation Models (DEMs) from NASA's Shuttle Radar Topography Mission (SRTM). Results provide an understanding of the underlying geomorphology of the Amazon planalto as well as its relationship to geologic processes and will support interpretation of the evolutionary history of the Amazon Basin. Portions of this work have been carried out within the framework of the ALOS Kyoto & Carbon Initiative. PALSAR data were provided by JAXA/EORC and the Alaska Satellite Facility.This work is carried out with support from the NASA Biodiversity Program and the NSF DIMENSIONS of Biodiversity Program.
El Niño Could Drive Intense Season for Amazon Fires
2017-12-08
El Niño conditions in 2015 and early 2016 altered rainfall patterns around the world. In the Amazon, El Niño reduced rainfall during the wet season, leaving the region drier at the start of the 2016 dry season than any year since 2002, according to NASA satellite data. Wildfire risk for the dry season months of July to October this year now exceeds fire risk in 2005 and 2010, drought years when wildfires burned large areas of Amazon rainforest, said Doug Morton, an Earth scientist at NASA’s Goddard Space Flight Center who helped create the fire forecast. "Severe drought conditions at the start of the dry season set the stage for extreme fire risk in 2016 across the southern Amazon," Morton said. The Amazon fire forecast uses the relationship between climate and active fire detections from NASA satellites to predict fire season severity during the region’s dry season. Developed in 2011 by scientists at University of California, Irvine and NASA’s Goddard Space Flight Center, the forecast model is focused particularly on the link between sea surface temperatures and fire activity. Warmer sea surface temperatures in the tropical Pacific (El Niño) and Atlantic oceans shift rainfall away from the Amazon region, increasing the risk of fires during dry season months. Read more: go.nasa.gov/2937ADt NASA image use policy. NASA Goddard Space Flight Center enables NASA’s mission through four scientific endeavors: Earth Science, Heliophysics, Solar System Exploration, and Astrophysics. Goddard plays a leading role in NASA’s accomplishments by contributing compelling scientific knowledge to advance the Agency’s mission. Follow us on Twitter Like us on Facebook Find us on Instagram
NASA Astrophysics Data System (ADS)
Papastefanou, P.; Fleischer, K.; Hickler, T.; Grams, T.; Lapola, D.; Quesada, C. A.; Zang, C.; Rammig, A.
2017-12-01
The Amazon basin was recently hit by severe drought events that were unprecedented in their severity and spatial extent, e.g. during 2005, 2010 and 2015/2016. Significant amounts of biomass were lost, turning large parts of the rainforest from a carbon sink into a carbon source. It is assumed that drought-induced tree mortality from hydraulic failure played an important role during these events and may become more frequent in the Amazon region in the future. Many state-of-the-art dynamic vegetation models do not include plant hydraulic processes and fail to reproduce observed rainforest responses to drought events, such as e.g. increased tree mortality. We address this research gap by developing a simple plant-hydraulic module for the dynamic vegetation model LPJ-GUESS. This plant-hydraulic module uses leaf water potential and cavitation as baseline processes to simulate tree mortality under drought stress. Furthermore, we introduce different plant strategies in the model, which describe e.g. differences in the stomatal regulation under drought stress. To parameterize and evaluate our hydraulic module, we use a set of available observational data from the Amazon region. We apply our model to the Amazon Basin and highlight similarities and differences across other measured and predicted drought responses, e.g. extrapolated observations and data derived from satellite measurements. Our results highlight the importance of including plant hydraulic processes in dynamic vegetation models to correctly predict vegetation dynamics under drought stress and show major differences on the vegetation dynamics depending on the selected plant strategies. We also identify gaps in process understanding of the triggering factors, the extent and the consequences of drought responses that hampers our ability to predict potential impact of future drought events on the Amazon rainforest.
Scliar, Marilia O; Gouveia, Mateus H; Benazzo, Andrea; Ghirotto, Silvia; Fagundes, Nelson J R; Leal, Thiago P; Magalhães, Wagner C S; Pereira, Latife; Rodrigues, Maira R; Soares-Souza, Giordano B; Cabrera, Lilia; Berg, Douglas E; Gilman, Robert H; Bertorelle, Giorgio; Tarazona-Santos, Eduardo
2014-09-30
Archaeology reports millenary cultural contacts between Peruvian Coast-Andes and the Amazon Yunga, a rainforest transitional region between Andes and Lower Amazonia. To clarify the relationships between cultural and biological evolution of these populations, in particular between Amazon Yungas and Andeans, we used DNA-sequence data, a model-based Bayesian approach and several statistical validations to infer a set of demographic parameters. We found that the genetic diversity of the Shimaa (an Amazon Yunga population) is a subset of that of Quechuas from Central-Andes. Using the Isolation-with-Migration population genetics model, we inferred that the Shimaa ancestors were a small subgroup that split less than 5300 years ago (after the development of complex societies) from an ancestral Andean population. After the split, the most plausible scenario compatible with our results is that the ancestors of Shimaas moved toward the Peruvian Amazon Yunga and incorporated the culture and language of some of their neighbors, but not a substantial amount of their genes. We validated our results using Approximate Bayesian Computations, posterior predictive tests and the analysis of pseudo-observed datasets. We presented a case study in which model-based Bayesian approaches, combined with necessary statistical validations, shed light into the prehistoric demographic relationship between Andeans and a population from the Amazon Yunga. Our results offer a testable model for the peopling of this large transitional environmental region between the Andes and the Lower Amazonia. However, studies on larger samples and involving more populations of these regions are necessary to confirm if the predominant Andean biological origin of the Shimaas is the rule, and not the exception.
Holocene provenance shift of suspended particulate matter in the Amazon River basin
NASA Astrophysics Data System (ADS)
Höppner, Natalie; Lucassen, Friedrich; Chiessi, Cristiano M.; Sawakuchi, André O.; Kasemann, Simone A.
2018-06-01
The strontium (Sr), neodymium (Nd) and lead (Pb) isotope signatures of suspended particulate matter (SPM) in rivers reflect the radiogenic isotope signatures of the rivers' drainage basin. These signatures are not significantly affected by weathering, transport or depositional cycles, but document the sedimentary contributions of the respective sources. We report new Sr, Nd and Pb isotope ratios and element concentrations of modern SPM from the Brazilian Amazon River basin and document the past evolution of the basin by analyzing radiogenic isotopes of a marine sediment core from the slope off French Guiana archiving the last 40 kyr of Amazon River SPM, and the Holocene section of sediment cores raised between the Amazon River mouth and the slope off French Guiana. The composition of modern SPM confirms two main source areas, the Andes and the cratonic Shield. In the marine sediment core notable changes occurred during the second phase of Heinrich Stadial 1 (i.e. increased proportion of Shield rivers SPM) and during the last deglaciation (i.e. increased proportion of Madeira River SPM) together with elsewhere constant source contributions. Furthermore, we report a prominent offset in Sr and Nd isotopic composition between the average core value (εNd: -11.7 ± 0.9 (2SD), 87Sr/86Sr: 0.7229 ± 0.0016 (2SD)) and the average modern Amazon River SPM signal (εNd: -10.5 ± 0.5 (2SD), 87Sr/86Sr: 0.7213 ± 0.0036 (2SD)). We suggest that a permanent change in the Amazon River basin sediment supply during the late Holocene to a more Andean dominated SPM was responsible for the offset.