Science.gov

Sample records for clay houses thoron-exposition

  1. Clay Houses

    ERIC Educational Resources Information Center

    Pedro, Cathy

    2011-01-01

    In this article, the author describes a project designed for fourth-graders that involves making clay relief sculptures of houses. Knowing the clay houses will become a family heirloom makes this lesson even more worth the time. It takes three classes to plan and form the clay, and another two to underglaze and glaze the final products.

  2. Thoron and thoron progeny measurements in German clay houses.

    PubMed

    Gierl, S; Meisenberg, O; Feistenauer, P; Tschiersch, J

    2014-07-01

    In recent years, elevated thoron concentrations were found in houses built of unfired clay. In this study experiments were carried out in 17 traditional and modern clay houses in Germany to obtain an overview of indoor thoron in such houses. Long-term measurements over an 8-week period were performed using a newly developed Unattended Battery-Operated Progeny Measurement Device (UBPM) for measuring thoron progeny. This instrument uses a high-voltage electric field to precipitate radon and thoron progeny on nuclear track detectors. Additional active and passive measurements of radon, thoron and their progeny were performed. The equilibrium equivalent thoron concentration was found to be between 2 and 10 Bq m(-3). Gas concentrations were found to be between 20 and 160 Bq m(-3) for radon and between 10 and 90 Bq m(-3) for thoron 20 cm from the wall. The thoron exposure contributes significantly to the inhalation dose of the dwellers (0.6-4 mSv a(-1)).

  3. Inventorying Toronto's single detached housing stocks to examine the availability of clay brick for urban mining.

    PubMed

    Ergun, Deniz; Gorgolewski, Mark

    2015-11-01

    This study examines the stocks of clay brick in Toronto's single detached housing, to provide parameters for city scale material reuse and recycling. Based on consensus from the literature and statistics on Toronto's single detached housing stocks, city scale reusable and recyclable stocks were estimated to provide an understanding of what volume could be saved from landfill and reintroduced into the urban fabric. On average 2523-4542 m(3) of brick was determined to be available annually for reuse, which would account for 20-36% of the volume of virgin brick consumed in new house construction in 2012. A higher volume, 6187 m(3) of brick, was determined to be available annually for recycling because more of the prevalence of cement-based mortar, which creates challenges for brick reuse in Toronto. The results demonstrated that older housing containing reusable brick were being mostly landfilled and replaced with housing that contained only recyclable brick.

  4. Ball clay

    USGS Publications Warehouse

    Virta, Robert L.

    2010-01-01

    The article reports on the global market performance of ball clay in 2009 and presents an outlook for its 2010 performance. Several companies mined ball call in the country including Old Hickey Clay Co., Kentucky-Tennessee Clay Co., and H.C. Spinks Clay Co. Information on the decline in ball clay imports and exports is also presented.

  5. Clays, specialty

    USGS Publications Warehouse

    Virta, R.L.

    1998-01-01

    Part of a special section on the state of industrial minerals in 1997. The state of the specialty clay industry worldwide for 1997 is discussed. The specialty clays mined in the U.S. are ball clay, fuller's earth, bentonite, fire clay, and kaolin. Sales of specialty clays in the U.S. were around 17 Mt in 1997. Approximately 53 kt of specialty clays were imported.

  6. Clay Play

    ERIC Educational Resources Information Center

    Rogers, Liz; Steffan, Dana

    2009-01-01

    This article describes how to use clay as a potential material for young children to explore. As teachers, the authors find that their dialogue about the potential of clay as a learning medium raises many questions: (1) What makes clay so enticing? (2) Why are teachers noticing different play and conversation around the clay table as compared to…

  7. Ball clay

    USGS Publications Warehouse

    Virta, R.L.

    2001-01-01

    Part of the 2000 annual review of the industrial minerals sector. A general overview of the ball clay industry is provided. In 2000, sales of ball clay reached record levels, with sanitary ware and tile applications accounting for the largest sales. Ball clay production, consumption, prices, foreign trade, and industry news are summarized. The outlook for the ball clay industry is also outlined.

  8. Ball clay

    USGS Publications Warehouse

    Virta, R.L.

    2007-01-01

    The article offers information on ball clay. Among the companies that mine ball clay in the U.S. are H.C. Spinks Clay, Kentucky-Tennessee Clay and Old Hickory Clay. In 2006, an estimated 1.2 million tons of the mineral was sold or used domestically and exported. Forty-percent of the total sales is accounted for ceramic floor and wall tile followed by sanitaryware and miscellaneous ceramics. Its average value was $ 45 per ton in 2006.

  9. Ball clay

    USGS Publications Warehouse

    Virta, R.L.

    2011-01-01

    The article discusses the latest developments in the global ball clay mining industry, particularly in the U.S., as of June 2011. It cites several firms that are involved in ball clay mining in the U.S., including HC Spins Clay Co. Inc., the Imerys Group and Old Hickory Clay Co. Among the products made from ball clay are ceramic tiles, sanitaryware, as well as fillers, extenders and binders.

  10. Ball clay

    USGS Publications Warehouse

    Virta, R.L.

    2013-01-01

    Four companies — H.C. Spinks Clay Co., Inc., Imerys, Old Hickory Clay Co. and Unimin Corp. — mined ball clay in five U.S. states in 2012. Production, on the basis of preliminary data, was 900 kt (992,000 st), with an estimated value of $42.3 million. This was a slight increase in tonnage from 886 kt (977,000 st), with a value of $40.9 million in 2011. Tennessee was the leading ball clay producing state, with 63 percent of domestic production, followed by Texas, Mississippi, Kentucky and Indiana. Reported ball clay production from Indiana probably was fire clay rather than ball clay. About 69 percent of total ball clay production was airfloat, 20 percent was crude and 11 percent was water-slurried.

  11. Fire clay

    USGS Publications Warehouse

    Virta, R.L.

    2011-01-01

    The article discusses the latest developments in the fire clay industry, particularly in the U.S., as of June 2011. It claims that the leading fire clay producer in the U.S. is the state of Missouri. The other major producers include California, Texas and Washington. It reports that the use of heavy clay products made of fire clay like brick, cement and lightweight aggregate has increased slightly in 2010.

  12. Clays, common

    USGS Publications Warehouse

    Virta, R.L.

    1998-01-01

    Part of a special section on the state of industrial minerals in 1997. The state of the common clay industry worldwide for 1997 is discussed. Sales of common clay in the U.S. increased from 26.2 Mt in 1996 to an estimated 26.5 Mt in 1997. The amount of common clay and shale used to produce structural clay products in 1997 was estimated at 13.8 Mt.

  13. Fire clay

    USGS Publications Warehouse

    Virta, R.L.

    2013-01-01

    Four companies mined fire clay in three states in 2012. Production, based on a preliminary survey of the fire clay industry, was estimated to be 230 kt (254,000 st) valued at $6.98 million, an increase from 215 kt (237,000 st) valued at $6.15 million in 2011. Missouri was the leading producing state, followed by Colorado and Texas, in decreasing order by quantity. The number of companies mining fire clay declined in 2012 because several common clay producers that occasionally mine fire clay indicated that they did not do so in 2012.

  14. Fire clay

    USGS Publications Warehouse

    Virta, R.L.

    2006-01-01

    In 2005, six companies mined fire clay in Missouri, Ohio and South Carolina. Production was estimate to be 300 kt with a value of $8.3 million. Missouri was the leading producer state followed by Ohio and South Carolina. For the third consecutive year, sales and use of fire clays have been relatively unchanged. For the next few years, sales of fire clay is forecasted to remain around 300 kt/a.

  15. Ball clay

    USGS Publications Warehouse

    Virta, R.L.

    2000-01-01

    Part of the 1999 Industrial Minerals Review. The state of the ball clay industry in 1999 is presented. Record highs in the sales and use of ball clay were attained in 1999 due to the continued strength of the U.S. economy. U.S. production was estimated at 1.25 million st for the year, with more than half of that amount mined in Tennessee. Details of the consumption, price, imports, and exports of ball clay in 1999 and the outlook for ball clay over the next few years are provided.

  16. Fire clay

    USGS Publications Warehouse

    Virta, R.L.

    2012-01-01

    Five companies mined fire clay in four states in 2011. Production, based on a preliminary survey of the fire clay industry, was estimated to be 240 kt (265,000 st), valued at $7.68 million, an increase from 216 kt (238,000 st), valued at $6.12 million in 2010. Missouri was the leading producing state, followed by Texas, Washington and Ohio, in decreasing order by quantity.

  17. Clay Minerals

    SciTech Connect

    Mueller, Karl T.; Sanders, Rebecca L.; Washton, Nancy M.

    2014-03-14

    Clay minerals are important components of the environment and are involved or implicated in processes such as the uptake of pollutants and the release of nutrients and as potential platforms for a number of chemical reactions. Owing to their small particle sizes (typically, on the order of microns or smaller) and mixing with a variety of other minerals and soil components, advanced characterization methods are needed to study their structures, dynamics, and reactivities. In this article, we describe the use of solid-state NMR methods to characterize the structures and chemistries of clay minerals. Early one-pulse magic-angle spinning (MAS) NMR studies of 27Al and 29Si have now been enhanced and extended with new studies utilizing advanced methodologies (such as Multiple Quantum MAS) as well as studies of less-sensitive nuclei. In additional work, the issue of reactivity of clay minerals has been addressed, including studies of reactive surface area in the environment. Utilizations of NMR-sensitive nuclides within the clay minerals themselves, and in molecules that react with specific sites on the clay mineral surfaces, have aided in understanding the reactivity of these complex aluminosilicate systems.

  18. Ball clay

    USGS Publications Warehouse

    Virta, R.L.

    2012-01-01

    Four companies — H.C. Spinks Clay Co., Inc., Imerys Group, Old Hickory Clay Co., and Unimin Corp. — mined ball clay in four states in 2011. Production, on the basis of preliminary data, was 940 kt (1.04 million st) with an estimated value of $44.2 million. This is a 3-percent increase in tonnage from 912 kt (1.01 million st) with a value of $41.3 million that was produced in 2010. Tennessee was the leading producing state with 63 percent of domestic production, followed by Texas, Mississippi and Kentucky. About 69 percent of production was airfloat, 20 percent was crude and 11 percent was water-slurried.

  19. Clay for Little Fingers.

    ERIC Educational Resources Information Center

    Koster, Joan Bouza

    1999-01-01

    Discusses the renewed interest in clay as a modeling compound in early childhood programs; describes the nature of clay and presents a working vocabulary. Suggests methods of working with clay, including introducing clay to children, discovering its uses, clean up, firing clay, and finishing baked clay. Includes activity suggestions and…

  20. Fire clay

    USGS Publications Warehouse

    Virta, R.L.

    2004-01-01

    Seven companies mined fire clay in four states during 2003. From 1984 to 1992, production declined to 383 kt (422,000 st) from a high of 1.04 Mt (1.14 million st) as markets for clay-based refractories declined. Since 1992, production levels have been erratic, ranging from 383 kt (422,000 st) in 1992 and 2001 to 583 kt (642,000 st) in 1995. Production in 2003, based on preliminary data, was estimated to be around 450 kt (496,000 st) with a value of about $10.5 million. This was about the same as in 2002. Missouri remained the leading producer state, followed by South Carolina, Ohio and California.

  1. Clay: The Forgotten Art.

    ERIC Educational Resources Information Center

    Martin, Doris Marie

    1995-01-01

    Discusses the tactile and kinesthetic areas of learning children experience when using clay. Includes practical tips for using and storing clay for preschool use and notes the differences between potters' clay and play dough. (HTH)

  2. Killer clays! Natural antibacterial clay minerals

    USGS Publications Warehouse

    Williams, L.B.; Holland, M.; Eberl, D.D.; Brunet, T.; De Courrsou, L. B.

    2004-01-01

    The clay chemical properties that may be important in medicine were investigated. It was found that natural clay minerals can have striking and very specific effects on microbial populations. The effects can range from potentially enhanced microbial growth to complete sterilization. This paper presents evidence that natural clay minerals can be effective antimicrobial agents.

  3. Imprinted Clay Coil Vessels

    ERIC Educational Resources Information Center

    Lohr, Tresa Rae

    2006-01-01

    The author teaches clay vessel construction in the fifth grade, and it is amazing what can be accomplished in one forty-five minute period when the expectations are clarified in the initial lesson. The author introduces clay coil vessels with a discussion of the sources of clay and how clay relates to fifth-grade science curriculum concepts such…

  4. Common clay and shale

    USGS Publications Warehouse

    Virta, R.L.

    2011-01-01

    The article discusses the latest developments in the global common clay and shale industry, particularly in the U.S. It claims that common clay and shale is mainly used in the manufacture of heavy clay products like brick, flue tile and sewer pipe. The main producing states in the U.S. include North Carolina, New York and Oklahoma. Among the firms that manufacture clay and shale-based products are Mid America Brick & Structural Clay Products LLC and Boral USA.

  5. 86. Photocopied August 1978. CLAY RAMMING EQUIPMENT IN OPERATION IN ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    86. Photocopied August 1978. CLAY RAMMING EQUIPMENT IN OPERATION IN THE POWER HOUSE IN 1910. A PILE OF CLAY USED TO FILL THE WASHED-OUT AREAS BENEATH THE FOUNDATIONS IS SHOWN IN THE CENTER OF THE ILLUSTRATION BESIDE THE FILLER PIPE. THE WEIGHT USED TO FORCE THE CLAY DOWN UNDER THE FOUNDATIONS IS SHOWN PRESSING ON THE PLUNGER PIPE. (542) - Michigan Lake Superior Power Company, Portage Street, Sault Ste. Marie, Chippewa County, MI

  6. Clays in prebiological chemistry

    NASA Technical Reports Server (NTRS)

    Rao, M.; Oro, J.; Odom, D. G.

    1980-01-01

    The ways in which clays have been utilized in studies of prebiological chemistry are reviewed, and an assessment is given of the possible role of clays in prebiological systems. The adsorption of organic molecules on clays has been demonstrated, as has the synthesis of bioorganic monomers in the presence of clays. For instance, amino acids, purines and pyrimidines have been obtained from carbon monoxide and nitric acid in the presence of clays at relatively high temperatures (250-325 C). The oligomerization of biochemical monomers, mediated by clays, has also been shown to result in the formation of polymer molecules basic to life. Clays have also been found to affect the condensation of mononucleotides to oligonucleotides.

  7. Permeability of Clay Concretes

    NASA Astrophysics Data System (ADS)

    Solomon, F.; Ekolu, S. O.

    2015-11-01

    This paper presents an investigation on the effect of clay addition on water permeability and air permeability of concretes. Clay concrete mixes consisted of 0 to 40% clay content incorporated as cement replacement. Flow methods using triaxial cells and air permeameters were used for measuring the injected water and air flows under pressure. It was found that the higher the clay content in the mixture, the greater the permeability. At higher water-cement ratios (w/c), the paste matrix is less dense and easily allows water to ingress into concrete. But at high clay contents of 30 to 40% clay, the variation in permeability was significantly diminished among different concrete mixtures. It was confirmed that air permeability results were higher than the corresponding water permeability values when all permeability coefficients were converted to intrinsic permeability values.

  8. Modified clay sorbents

    DOEpatents

    Fogler, H. Scott; Srinivasan, Keeran R.

    1990-01-01

    A novel modified clay sorbent and method of treating industrial effluents to remove trace pollutants, such as dioxins, biphenyls, and polyaromatics such as benzo(a)pyrene and pentachlorophenol. The novel clay sorbent has a composite structure in which the interlayer space of an expandable clay, such as smectite, is filled with polyvalent or multivalent inorganic cations which forces weaker surfactant cations to locate on the surface of the clay in such an orientation that the resulting composite is hydrophilic in nature. A specific example is cetylpyridinium-hydroxy aluminum-montmorillonite. In certain embodiments, a non-expanding clay, such as kaolinite, is used and surfactant cations are necessarily located on an external surface of the clay. A specific example is cetylpyridinium-kaolinite.

  9. Common clay and shale

    USGS Publications Warehouse

    Virta, R.L.

    2000-01-01

    Part of the 1999 Industrial Minerals Review. The clay and shale market in 1999 is reviewed. In the U.S., sales or use of clay and shale increased from 26.4 million st in 1998 to 27.3 million st in 1999, with an estimated 1999 value of production of $143 million. These materials were used to produce structural clay products, lightweight aggregates, cement, and ceramics and refractories. Production statistics for clays and shales and for their uses in 1999 are presented.

  10. Columns in Clay

    ERIC Educational Resources Information Center

    Leenhouts, Robin

    2010-01-01

    This article describes a clay project for students studying Greece and Rome. It provides a wonderful way to learn slab construction techniques by making small clay column capitols. With this lesson, students learn architectural vocabulary and history, understand the importance of classical architectural forms and their influence on today's…

  11. The Science of Clay

    ERIC Educational Resources Information Center

    Warwick, Sharon

    2005-01-01

    Students' natural curiosity provides a rich opportunity for teachers to make meaningful scientific connections between art and ceramics that will enhance the understanding of both natural forces and scientific aspects at work in the creation of clay artworks. This article discusses the scientific areas of study related to clay, which include…

  12. Clay Portrait Boxes

    ERIC Educational Resources Information Center

    Wilbert, Nancy Corrigan

    2009-01-01

    In an attempt to incorporate sculptural elements into her ceramics program, the author decided to try direct plaster casting of the face to make a plaster mold for clay. In this article, the author shares an innovative ceramics lesson that teaches students in making plaster casts and casting the face in clay. This project gives students the…

  13. Common clay and shale

    USGS Publications Warehouse

    Virta, R.L.

    2003-01-01

    Part of the 2002 industrial minerals review. The production, consumption, and price of shale and common clay in the U.S. during 2002 are discussed. The impact of EPA regulations on brick and structural clay product manufacturers is also outlined.

  14. Finicky clay divers

    NASA Astrophysics Data System (ADS)

    Cordry, Sean M.

    1998-02-01

    Clay spheres dropped into a dilute vinegar/baking-soda solution accumulate CO2 bubbles on their surfaces. Spheres below a certain size will then float, otherwise they remain sunken. Students must determine the maximum size that will float by considering the net density of the clay/bubble system.

  15. Clays as prebiotic photocatalysts

    NASA Technical Reports Server (NTRS)

    Coyne, L. M.; Lawless, J.; Lahav, N.; Sutton, S.; Sweeney, M.

    1981-01-01

    Clay minerals catalyze peptide bond formation in fluctuating environments. A number of plausible mechanisms have been proposed and tested. The possibility that clays may actually be energizing the reaction by means of electronic excitation, creating mobile or trapped holes and electrons in the lattice, is explored. It has been discovered that clays emit light upon dehydration. The correlation between dehydration-induced, or thermoluminescent, processes and the yield of glycine oligomers after treatments known to affect the luminescent yields is being tested, in an effort to understand the catalytic mechanism

  16. Common clay and shale

    USGS Publications Warehouse

    Virta, R.L.

    2004-01-01

    Part of the 2003 industrial minerals review. The legislation, production, and consumption of common clay and shale are discussed. The average prices of the material and outlook for the market are provided.

  17. Clay Mineral: Radiological Characterization

    SciTech Connect

    Cotomacio, J. G.; Silva, P. S. C.; Mazzilli, B. P

    2008-08-07

    Since the early days, clays have been used for therapeutic purposes. Nowadays, most minerals applied as anti-inflammatory, pharmaceutics and cosmetic are the clay minerals that are used as the active ingredient or, as the excipient, in formulations. Although their large use, few information is available in literature on the content of the radionuclide concentrations of uranium and thorium natural series and {sup 40}K in these clay minerals.The objective of this work is to determine the concentrations of {sup 238}U, {sup 232}Th, {sup 226}Ra, {sup 228}Ra, {sup 210}Pb and {sup 40}K in commercial samples of clay minerals used for pharmaceutical or cosmetic purposes. Two kinds of clays samples were obtained in pharmacies, named green clay and white clay.Measurement for the determination of {sup 238}U and {sup 232}Th activity concentration was made by alpha spectrometry and gamma spectrometry was used for {sup 226}Ra, {sup 228}Ra, {sup 210}Pb and {sup 40}K determination. Some physical-chemical parameters were also determined as organic carbon and pH. The average activity concentration obtained was 906{+-}340 Bq kg{sup -1} for {sup 40}K, 40{+-}9 Bq kg{sup -1} for {sup 226}Ra, 75{+-}9 Bq kg{sup -1} for {sup 228}Ra, 197{+-}38 Bq kg{sup -1} for {sup 210}Pb, 51{+-}26 Bq kg{sup -1} for {sup 238}U and 55{+-}24 Bq kg{sup -1} for {sup 232}Th, considering both kinds of clay.

  18. Common clay and shale

    USGS Publications Warehouse

    Virta, R.L.

    2006-01-01

    At present, 150 companies produce common clay and shale in 41 US states. According to the United States Geological Survey (USGS), domestic production in 2005 reached 24.8 Mt valued at $176 million. In decreasing order by tonnage, the leading producer states include North Carolina, Texas, Alabama, Georgia and Ohio. For the whole year, residential and commercial building construction remained the major market for common clay and shale products such as brick, drain tile, lightweight aggregate, quarry tile and structural tile.

  19. Dewatering of industrial clay wastes

    SciTech Connect

    Smelley, A.G.; Scheiner, B.J.; Zatko, J.R.

    1980-01-01

    As a part of research conducted to effect pollution a dewatering technique that allows for disposal of clay wastes, for reuse of water now lost with clays, and for reclamation of mined land was developed. The technique utilizes a high-molecular-weight nonionic polyethylene oxide polymer (PEO) that has the ability to flocculate and dewater materials containing clay wastes. In laboratory experiments, coal-clay waste, potash-clay brine slurry, phosphatic clay waste, uranium tailings, and talc tailings were successfully consolidated. Coal-clay waste was consolidated from 3.6 to 57%; potash-clay brine slurry was consolidated from 3.8 to 35%; phosphatic clay waste from 15.6 to 49%; uranium tailings from 15.4 to 67%; tailings from talc production from 9.7 to 53%; and an acidic TiO/sub 2/ slurr slurry from 1.68 to 30%.

  20. 4. J. E. HERMAN HOUSE, built 1899, of SOFT CLAYLIKE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    4. J. E. HERMAN HOUSE, built 1899, of SOFT CLAY-LIKE MATERIAL THAT WAS QUARRIED AND THEN HARDENED ON CONTACT WITH AIR AND SUNSHINE. IT HAS NO DOORWAY TO STREET. - Town of Liebenthal, Liebenthal, Rush County, KS

  1. Moving Along: Sporting Clay.

    ERIC Educational Resources Information Center

    Hiller, Peter

    2002-01-01

    Presents a junior high school student art project where three-dimensional art sculptures of surfing, snow boarding, or dirt biking were created. Discusses how the students created their three-dimensional works of art using a clay-slab technique. (CMK)

  2. Rattles of Clay.

    ERIC Educational Resources Information Center

    Banning, Donna

    1983-01-01

    Using the rattles of Native American cultures as inspiration, students used pinching, coiling, and slab and molding techniques to form the bodies of rattles and clay pellets for sound. Surface decoration included glazed and unglazed areas as well as added handles, feathers, and leather. (IS)

  3. Common clay and shale

    USGS Publications Warehouse

    Virta, R.L.

    2001-01-01

    Part of the 2000 annual review of the industrial minerals sector. A general overview of the common clay and shale industry is provided. In 2000, U.S. production increased by 5 percent, while sales or use declined to 23.6 Mt. Despite the slowdown in the economy, no major changes are expected for the market.

  4. Modeling in Ceramic Clay

    ERIC Educational Resources Information Center

    Miller, Louis J.

    1976-01-01

    Modeling is an additive process of building up a sculpture with some plastic material like clay. It affords the student an opportunity to work in three dimensions, a creative relief from the general two-dimensional drawing and design activities that occupy a large segment of time in the art curriculum. (Author/RK)

  5. Clay Animals and Their Habitats

    ERIC Educational Resources Information Center

    Adamson, Kay

    2010-01-01

    Creating clay animals and their habitats with second-grade students has long been one of the author's favorite classroom activities. Students love working with clay and they also enjoy drawing animal homes. In this article, the author describes how the students created a diorama instead of drawing their clay animal's habitat. This gave students…

  6. House calls.

    PubMed

    Unwin, Brian K; Tatum, Paul E

    2011-04-15

    House calls provide a unique perspective on patients' environment and health problems. The demand for house calls is expected to increase considerably in future decades as the U.S. population ages. Although study results have been inconsistent, house calls involving multidisciplinary teams may reduce hospital readmissions and long-term care facility stays. Common indications for house calls are management of acute or chronic illnesses, and palliative care. Medicare beneficiaries must meet specific criteria to be eligible for home health services. The INHOMESSS mnemonic provides a checklist for components of a comprehensive house call. In addition to performing a clinical assessment, house calls may involve observing the patient performing daily activities, reconciling medication discrepancies, and evaluating home safety. House calls can be integrated into practice with careful planning, including clustering house calls by geographic location and coordinating visits with other health care professionals and agencies.

  7. White House

    MedlinePlus

    ... to main content Jump to navigation the WHITE HOUSE President Donald J. Trump Get in Touch Home ... News Read the latest news from the White House Video Gallery View the most recent videos from ...

  8. Historic Houses.

    ERIC Educational Resources Information Center

    Curtis, Nancy

    1997-01-01

    Reviews some of the efforts of the Society for the Preservation of New England Antiquities (SPNEA) to preserve, conserve, and interpret historic houses to the public. Examines the history and some of the specific preservation problems concerning the Beauport Cottage, the Sayward-Wheeler House, and the Gropius House. (MJP)

  9. Substandard Housing.

    ERIC Educational Resources Information Center

    Milkove, Daniel L., Comp.

    1986-01-01

    Defines substandard housing and summarizes newly derived data from the 1980 Census showing that 7.5% of all rural occupied housing in the Nation was substandard. Points out regional and rural-urban differences. Notes effects on rural housing of poverty rates, percentage of nonwhite households, average household size, growth in county population,…

  10. Clay at Nili Fossae

    NASA Technical Reports Server (NTRS)

    2006-01-01

    This image of the Nili Fossae region of Mars was compiled from separate images taken by the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) and the High-Resolution Imaging Science Experiment (HiRISE), two instruments on NASA's Mars Reconnaissance Orbiter. The images were taken at 0730 UTC (2:30 a.m. EDT) on Oct. 4, 2006, near 20.4 degrees north latitude, 78.5 degrees east longitude. CRISM's image was taken in 544 colors covering 0.36 to 3.92 micrometers, and shows features as small as 18 meters (60 feet) across. HiRISE's image was taken in three colors, but its much higher resolution shows features as small as 30 centimeters (1 foot) across.

    CRISM's sister instrument on the Mars Express spacecraft, OMEGA, discovered that some of the most ancient regions of Mars are rich in clay minerals, formed when water altered the planet's volcanic rocks. From the OMEGA data it was unclear whether the clays formed at the surface during Mars' earliest history of if they formed at depth and were later exposed by impact craters or erosion of the overlying rocks. Clays are an indicator of wet, benign environments possibly suitable for biological processes, making Nili Fossae and comparable regions important targets for both CRISM and HiRISE.

    In this visualization of the combined data from the two instruments, the CRISM data were used to calculate the strengths of spectral absorption bands due to minerals present in the scene. The two major minerals detected by the instrument are olivine, a mineral characteristic of primitive igneous rocks, and clay. Areas rich in olivine are shown in red, and minerals rich in clay are shown in green. The derived colors were then overlayed on the HiRISE image.

    The area where the CRISM and HiRISE data overlap is shown at the upper left, and is about 5 kilometers (3 miles) across. The three boxes outlined in blue are enlarged to show how the different minerals in the scene match up with different landforms. In the image

  11. Why housing?

    PubMed

    Aidala, Angela A; Sumartojo, Esther

    2007-11-01

    Housing/lack of housing and HIV are powerfully linked. Housing occupies an important place in the causal chains linking poverty and inequality, and HIV risk and outcomes of infection. The articles in this Special Supplement of AIDS and Behavior confirm the impact of homelessness, and poor or unstable housing, on HIV/AIDS, and challenge scientists to test and policy makers to implement the promise of housing as an innovative response to the epidemic. In order to influence the development of policies on housing to benefit at-risk or HIV-infected persons, however, proponents must justify why this association exists, and how housing can help end the epidemic as well as improve the care and health of persons living with HIV/AIDS. We introduce this supplement with a discussion of the "why" question.

  12. Rental Housing.

    ERIC Educational Resources Information Center

    American Association of Retired Persons, Washington, DC. Consumer Housing Information Service for Seniors.

    This is one of a series of booklets prepared as a resource for trained Housing Information Volunteers to provide impartial information to older people who have questions of concern about how to find safe, comfortable, affordable housing; how to cut household expenses or use their homes to earn extra income; home maintenance and home improvement;…

  13. Housing Deprivation

    ERIC Educational Resources Information Center

    Atkinson, Reilly

    1975-01-01

    This testimony, before a public hearing of the New York City Commission on Human Rights in May 1974, summarizes the implications of a study done at the Joint Center for Urban Studies of the number and characteristics of families that will buy a house, and what kind of housing problems they have, for the relative status of blacks or whites or other…

  14. Analytical Characterization of Natural Clay

    NASA Astrophysics Data System (ADS)

    El-Sheikhy, Refat; Al-Shamrani, Mosleh

    2010-10-01

    The current paper introduces the study of morphology and electronic microscopy characterization of one type of the smectite Saudi nano clay montmorillonite type. During the last decade, nanotechnology achieved a recognized progress in many fields based mainly on synthesized materials. Much attention is devoted to produce natural nano particles. It was found that the clay is one of the rare materials which have platelets of nano scale size. The nano clay minerals are found in different types. It is investigated that the nano clay minerals have super properties which can not be found in the other materials. The Kingdom of Saudi Arabia has many zones having different types of good nano clays. These nano clays are found in certain mixtures with other different materials such as Mg, Ca, Fe and others. By developing an innovated technique we could extract Saudi Arabian nano clay with high grade purity. The results are very interesting. The produced nano clay particles are with good quality and super properties. It can be used in many fields of nanocomposites.

  15. Mineral resource of the Month: Clay

    USGS Publications Warehouse

    Virta, Robert L.

    2010-01-01

    Clays were one of the first mineral commodities used by people. Clay pottery has been found in archeological sites that are 12,000 years old, and clay figurines have been found in sites that are even older.

  16. House Rules.

    ERIC Educational Resources Information Center

    Hammel, Bette

    2001-01-01

    Discusses the "house" concept architectural design at Albert Lea High School (Minnesota) and how the design addresses the community's 21st Century educational goals. Photos and a floor plan are included. (GR)

  17. Clay energetics in chemical evolution

    NASA Technical Reports Server (NTRS)

    Coyne, L. M.

    1986-01-01

    Clays have been implicated in the origin of terrestrial life since the 1950's. Originally they were considered agents which aid in selecting, concentrating and promoting oligomerization of the organic monomeric substituents of cellular life forms. However, more recently, it has been suggested that minerals, with particular emphasis on clays, may have played a yet more fundamental role. It has been suggested that clays are prototypic life forms in themselves and that they served as a template which directed the self-assembly of cellular life. If the clay-life theory is to have other than conceptual credibility, clays must be shown by experiment to execute the operations of cellular life, not only individually, but also in a sufficiently concerted manner as to produce some semblance of the functional attributes of living cells. Current studies are focussed on the ability of clays to absorb, store and transfer energy under plausible prebiotic conditions and to use this energy to drive chemistry of prebiotic relevance. Conclusions of the work are applicable to the role of clays either as substrates for organic chemistry, or in fueling their own life-mimetic processes.

  18. Clay and pillard clay membranes: Synthesis, characterization and transport properties

    NASA Astrophysics Data System (ADS)

    Vercauteren, Sven

    In this work, the preparation and characterization of ceramic multilayer membranes with an Alsb2Osb3-pillared montmorillonite (Al-PILC) and a Laponite separating layer have been studied. Al-PILC is a pillared clay prepared by intercalation of polyoxo cations of aluminium between the montmorillonite clay sheets, followed by a thermal treatment (400sp°C) to obtain rigid oxide pillars. The free spacing between the clay plates is about 0.8 nm. Laponite is a synthetic clay with a pore structure formed by the stacking of very small clay plates. To deposit an Al-PILC top layer on a macro- or mesoporous aluminiumoxide support membrane, two preparation routes were considered. According to the standard preparation route of a pillared clay, the easiest way is to use a suspension of clay mixed with the pillaring solution in which the support membrane is dipped. However, it is not possible to deposit uniform and crack-free top layers in this way because of the formation of unstable suspensions. A second preparation route is based on an indirect pillaring procedure. By dipping a support membrane in a stable clay suspension, a thin clay film is deposited in a first step. Pillaring is achieved via immersion of the supported clay film in the pillaring solution in a second step. After a washing procedure, the membrane is dried and calcined at 400sp°C. Laponite membranes were simply prepared by dipping a support membrane in a suspension of this synthetic clay in water. Afterwards a drying at room temperature and a calcination at 400 ar 500sp°C is performed. Both membrane types were tested for gas separation and pervaporation purposes. Transport of permanent gases (He, N2) occurs by means of Knudsen diffusion. Diffusion is kinetically controlled and for a binary mixture, the maximum separation factor is determined by the difference in molecular weight of both components. From pervaporation experiments with water/alcohol mixtures it was found that Al-PILC membranes can be used for

  19. Scanning electron microscopy of clays and clay minerals

    USGS Publications Warehouse

    Bohor, B.F.; Hughes, R.E.

    1971-01-01

    The scanning electron microscope (SEM) proves to be ideally suited for studying the configuration, texture, and fabric of clay samples. Growth mechanics of crystalline units-interpenetration and interlocking of crystallites, crystal habits, twinning, helical growth, and topotaxis-also are uniquely revealed by the SEM. Authigenic kaolins make up the bulk of the examples because their larger crystallite size, better crystallinity, and open texture make them more suited to examination by the SEM than most other clay mineral types. ?? 1971.

  20. Tool for Taking Clay Impressions

    NASA Technical Reports Server (NTRS)

    Duncan, R. S.

    1984-01-01

    Clay impression of small parts taken with tool consisting of hollow tube closed at one end. Slots at other end admit part short distance into tube. Impression used to make silicone rubber mold for examination.

  1. Housing Projects.

    ERIC Educational Resources Information Center

    Schmalz, Georgann

    1985-01-01

    Building specifications for birdhouses (nesting boxes) are given for 11 species (chickadee, titmouse, nuthatch, Carolina wren, house wren, downy woodpecker, hairy woodpecker, flicker, bluebird, screech owl, and wood duck) including length, width, depth, entrance diameter, and height above the ground. Pointers for construction, materials, and…

  2. A review of WIPP (Waste Isolation Pilot Plant) repository clays and their relationship to clays of adjacent strata

    SciTech Connect

    Krumhansl, J.L.; Kimball, K.M.; Stein, C.L.

    1990-12-01

    The Salado Formation is a thick evaporite sequence located in the Permian Delaware Basin of southeastern New Mexico. This study focuses on the intense diagenetic alteration that has affected the small amounts of clay, feldspar, and quartz washed into the basin during salt deposition. These changes are of more than academic interest since this formation also houses the WIPP (Waste Isolation Pilot Plant). Site characterization concerns warrant compiling a detailed data base describing the clays in and around the facility horizon. An extensive sampling effort was undertaken to address these programmatic issues as well as to provide additional insight regarding diagenetic mechanisms in the Salado. Seventy-five samples were collected from argillaceous partings in halite at the stratigraphic level of the Waste Isolation Pilot Plant (WIPP). These were compared with twenty-eight samples from cores of the Vaca Triste member of the Salado, a thin clastic unit at the top of the McNutt potash zone, and with a clay-rich sample from the lower contact of the Culebra Dolomite (in the overlying Rustler Formation). These settings were compared to assess the influence of differences in brine chemistry (i.e., halite and potash facies, normal to hypersaline marine conditions) and sediment composition (clays, sandy silt, dolomitized limestone) on diagenetic processes. 44 refs., 11 figs., 5 tabs.

  3. Smart Houses

    NASA Technical Reports Server (NTRS)

    1987-01-01

    GWS takes plans for a new home and subjects them to intensive computerized analysis that does 10,000 calculations relative to expected heat loss and heat gain, then provides specifications designed specifically for each structure as to heating, cooling, ventilation and insulation. As construction progresses, GWS inspects the work of the electrical, plumbing and insulation contractors and installs its own Smart House Radiant Barrier. On completion of the home, GWS technicians use a machine that creates a vacuum in the house and enables computer calculation of the air exchanged, a measure of energy efficiency. Key factor is the radiant barrier, borrowed from the Apollo program. This is an adaptation of a highly effective aluminized heat shield as a radiation barrier holding in or keeping out heat, cold air and water vapor.

  4. Dietary clays alleviate diarrhea of weaned pigs.

    PubMed

    Song, M; Liu, Y; Soares, J A; Che, T M; Osuna, O; Maddox, C W; Pettigrew, J E

    2012-01-01

    Two experiments were conducted to determine whether 3 different clays in the nursery diet reduce diarrhea of weaned pigs experimentally infected with a pathogenic Escherichia coli. Weaned pigs (21 d old) were housed in individual pens of disease containment chambers for 16 d [4 d before and 12 d after the first challenge (d 0)]. The treatments were in a factorial arrangement: 1) with or without an E. coli challenge (F-18 E. coli strain; heat-labile, heat-stable, and Shiga-like toxins; 10(10) cfu/3 mL oral dose daily for 3 d from d 0) and 2) dietary treatments. The ADG, ADFI, and G:F were measured for each interval (d 0 to 6, 6 to 12, and 0 to 12). Diarrhea score (DS; 1 = normal; 5 = watery diarrhea) was recorded for each pig daily. Feces were collected on d 0, 3, 6, 9, and 12 and plated on blood agar to differentiate β-hemolytic coliforms (HC) from total coliforms (TC) and on MacConkey agar to verify E. coli. Their populations on blood agar were assessed visually using a score (0 = no growth; 8 = very heavy bacterial growth) and expressed as a ratio of HC to TC scores (RHT). Blood was collected on d 0, 6, and 12 to measure total and differential white blood cell (WBC) counts, packed cell volume (PCV), and total protein (TP). In Exp. 1 (8 treatments; 6 replicates), 48 pigs (6.9 ± 1.0 kg of BW) and 4 diets [a nursery control diet (CON), CON + 0.3% smectite (SM), CON + 0.6% SM, and CON until d 0 and then CON + 0.3% SM] were used. The SM treatments did not affect growth rate of the pigs for the overall period. In the E. coli challenged group, the SM treatments reduced DS for the overall period (1.77 vs. 2.01; P < 0.05) and RHT on d 6 (0.60 vs. 0.87; P < 0.05) and d 9 (0.14 vs. 0.28; P = 0.083), and altered differential WBC on d 6 (neutrophils, 48 vs. 39%, P = 0.092; lymphocytes, 49 vs. 58%, P = 0.082) compared with the CON treatment. In Exp. 2 (16 treatments; 8 replicates), 128 pigs (6.7 ± 0.8 kg of BW) and 8 diets [CON and 7 clay treatments (CON + 0.3% SM

  5. Clay minerals for advanced ceramics

    SciTech Connect

    Murray, H.H. )

    1989-11-01

    The author describes new and improved beneficiation techniques available to allow the production of clay minerals of exceptionally high purity. This is particularly true for kaolins and smectites. Wet processing techniques include particle size separation, high intensity magnetic separation, chemical leaching, flotation, and selective flocculation. The blending of clay minerals with other minerals provides opportunities to make special ceramic materials such as cordierite and other minerals that have very special ceramic properties including low heat expansion, high fired strength, low absorption, and other desired qualities.

  6. Boron enrichment in martian clay.

    PubMed

    Stephenson, James D; Hallis, Lydia J; Nagashima, Kazuhide; Freeland, Stephen J

    2013-01-01

    We have detected a concentration of boron in martian clay far in excess of that in any previously reported extra-terrestrial object. This enrichment indicates that the chemistry necessary for the formation of ribose, a key component of RNA, could have existed on Mars since the formation of early clay deposits, contemporary to the emergence of life on Earth. Given the greater similarity of Earth and Mars early in their geological history, and the extensive disruption of Earth's earliest mineralogy by plate tectonics, we suggest that the conditions for prebiotic ribose synthesis may be better understood by further Mars exploration.

  7. Boron Enrichment in Martian Clay

    PubMed Central

    Nagashima, Kazuhide; Freeland, Stephen J.

    2013-01-01

    We have detected a concentration of boron in martian clay far in excess of that in any previously reported extra-terrestrial object. This enrichment indicates that the chemistry necessary for the formation of ribose, a key component of RNA, could have existed on Mars since the formation of early clay deposits, contemporary to the emergence of life on Earth. Given the greater similarity of Earth and Mars early in their geological history, and the extensive disruption of Earth's earliest mineralogy by plate tectonics, we suggest that the conditions for prebiotic ribose synthesis may be better understood by further Mars exploration. PMID:23762242

  8. Biodegradable Pectin/clay Aerogels

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Biodegradable, foamlike materials based on renewable pectin and sodium montmorillonite clay were fabricated through a simple, environmentally friendly freeze-drying process. Addition of multivalent cations (Ca2+ and Al3+) resulted in apparent crosslinking of the polymer, and enhancement of aerogel p...

  9. ADSORPTION OF SURFACTANT ON CLAYS

    EPA Science Inventory

    Surfactants used to enhance remediation of soils by soil washing are often lost in the process. Neither the amount nor the cause of this loss is known. It is assumed that clays present in the soil are responsible for the loss of the surfactant. In this papere, adsorption prope...

  10. Picasso Masks: Cubism in Clay

    ERIC Educational Resources Information Center

    Daddino, Michelle

    2010-01-01

    This article describes an art project developed by the author which provides a way to further the children's understanding of Picasso's Cubism style in 3-D. Through this project, upper-elementary students learn a bit about the life and art of Picasso as they gain a firm understanding of the style of art known as Cubism, and apply clay techniques…

  11. Multifunctional epoxy composites with natural Moroccan clays

    NASA Astrophysics Data System (ADS)

    Monsif, M.; Zerouale, A.; Kandri, N. Idrissi; Allali, F.; Sgarbossa, P.; Bartolozzi, A.; Tamburini, S.; Bertani, R.

    2016-05-01

    Two natural Moroccan clays, here firstly completely characterized, have been used as fillers without modification in epoxy composites. Mechanical properties resulted to be improved and a significant antibacterial activity is exhibited by the epoxy composite containing the C2 clay.

  12. Stools - pale or clay-colored

    MedlinePlus

    ... gov/ency/article/003129.htm Stools - pale or clay-colored To use the sharing features on this page, please enable JavaScript. Stools that are pale, clay, or putty-colored may be due to problems ...

  13. Clay complexes support HDS catalyst.

    SciTech Connect

    Marshall, C. L.; Carrado, K.; Chemical Engineering

    2000-01-01

    Hydroprocessing represents a crucial component of petroleum refining operations both in terms of environmental and economic considerations. Regulations concerning maximum amount of sulfur content of gasoline and emissions of sulfur-oxide compounds upon combustion are becoming more and more stringent. One 1994-2000 focus of Argonne National Laboratory (ANL) has been the development of catalysts for hydrodesulfurization (HDS). Typical HDS catalysts are comprised of Co-Mo sulfides or Ni-Mo sulfides on an alumina support. Modification of the pore structure of the support has generated great attention among researchers. Most desulfurization test reactions have used dibenzothiophene (DBT) as the model compound to test various configurations of support material with Co-Mo-S and Ni-Mo-S catalysts. In this testing, the desired product would be biphenyl and hydrogen sulfide (H{sub 2}S). A competing reaction creates cyclohexylbenzene by saturating one aromatic ring prior to desulfurization. Ring saturation requires more costly hydrogen and is not desirable. Fortunately, a more effective catalyst for adding hydrogen at the sulfur site with hydrogenating the aromatic rings has been found. However, this has only been tested on DBT. HDS uses various types of catalysts to add hydrogen to reduce unwanted sulfur compounds. Typically this requires expensive, high-pressure, high-temperature equipment to produce the environmentally friendly low-sulfur fuels. ANL scientists identified several new desulfurization catalysts with improved HDS activity and selectivity. From these new catalysts, it may be possible to achieve HDS processing at lower temperature and pressure. The catalysts used for HDS at ANL are various clay complexes. Natural clays have a history of use in the hydroprocessing industry since they are abundant and inexpensive. ANL's approach is to create synthetic organo-clay complexes (SOCC). An advantage of SOCCs is that the pore size and distribution can be controlled by

  14. Mineral resource of the month: clays

    USGS Publications Warehouse

    Virta, Robert

    2004-01-01

    Clays represent one of the largest mineral commodities in the world in terms of mineral and rock production and use. Many people, however, do not recognize that clays are used in an amazingly wide variety of applications. Use continues to increase worldwide as populations and their associated needs increase. Robert Virta, clay and shale commodity specialist for the U.S. Geological Survey, has prepared the following information about clays.

  15. 21 CFR 186.1256 - Clay (kaolin).

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 3 2011-04-01 2011-04-01 false Clay (kaolin). 186.1256 Section 186.1256 Food and... Substances Affirmed as GRAS § 186.1256 Clay (kaolin). (a) Clay (kaolin) Al2O3.2SiO2.nH2O, Cas Reg. No. 1332-58-7) consists of hydrated aluminum silicate. The commercial products of clay (kaolin)...

  16. 21 CFR 186.1256 - Clay (kaolin).

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Clay (kaolin). 186.1256 Section 186.1256 Food and... Substances Affirmed as GRAS § 186.1256 Clay (kaolin). (a) Clay (kaolin) Al2O3.2SiO2.nH2O, Cas Reg. No. 1332-58-7) consists of hydrated aluminum silicate. The commercial products of clay (kaolin)...

  17. 21 CFR 186.1256 - Clay (kaolin).

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 3 2013-04-01 2013-04-01 false Clay (kaolin). 186.1256 Section 186.1256 Food and... Substances Affirmed as GRAS § 186.1256 Clay (kaolin). (a) Clay (kaolin) Al2O3.2SiO2.nH2O, Cas Reg. No. 1332-58-7) consists of hydrated aluminum silicate. The commercial products of clay (kaolin)...

  18. 21 CFR 186.1256 - Clay (kaolin).

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 3 2014-04-01 2014-04-01 false Clay (kaolin). 186.1256 Section 186.1256 Food and....1256 Clay (kaolin). (a) Clay (kaolin) Al2O3.2SiO2.nH2O, Cas Reg. No. 1332-58-7) consists of hydrated aluminum silicate. The commercial products of clay (kaolin) contain varying quantities of alkalies...

  19. 21 CFR 186.1256 - Clay (kaolin).

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 3 2012-04-01 2012-04-01 false Clay (kaolin). 186.1256 Section 186.1256 Food and... Substances Affirmed as GRAS § 186.1256 Clay (kaolin). (a) Clay (kaolin) Al2O3.2SiO2.nH2O, Cas Reg. No. 1332-58-7) consists of hydrated aluminum silicate. The commercial products of clay (kaolin)...

  20. Clay & Children: More than Making Pots.

    ERIC Educational Resources Information Center

    Kolbe, Ursula

    1997-01-01

    Working with clay enables young children to express, explore, and communicate their feelings and ideas. This resource booklet for early childhood practitioners and it promotes the clay table as a special place for shared discoveries, social interaction, and discussion. The booklet provides a glossary of terms used in clay work, as well as reasons…

  1. Clay Cuffman: A Cool, Calm, Relaxed Guy

    ERIC Educational Resources Information Center

    Booth, Gina

    2010-01-01

    This article describes Clay Cuffman, a simple clay-sculpture project that requires two or three sessions, and works for students from the upper-elementary level through high school. It takes about 1.5 pounds of clay per student--about the size of a small grapefruit. The Cuffman project is a great way for upper-elementary through high-school…

  2. The systems containing clays and clay minerals from modified drug release: a review.

    PubMed

    Rodrigues, Luís Alberto de Sousa; Figueiras, Ana; Veiga, Francisco; de Freitas, Rivelilson Mendes; Nunes, Lívio César Cunha; da Silva Filho, Edson Cavalcanti; da Silva Leite, Cleide Maria

    2013-03-01

    Clays are materials commonly used in the pharmaceutical industry, either as ingredients or as active ingredients. It was observed that when they are administered concurrently, they may interact with drugs reducing their absorption. Therefore, such interactions can be used to achieve technological and biopharmaceutical advantages, regarding the control of release. This review summarizes bibliographic (articles) and technological (patents) information on the use of systems containing clays and clay minerals in modified drug delivery. In this area, formulations such natural clay, commercial clay, synthetic clay, composites clay-polymers, nanocomposites clay-polymers, films and hidrogels composites clay-polymers are used to slow/extend or vectorize the release of drugs and consequently they increase their bioavailability. Finally, this review summarizes the fields of technology and biopharmaceutical applications, where clays are applied.

  3. Modeling Radionuclide Transport in Clays

    SciTech Connect

    Zheng, Liange; Li, Lianchong; Rutqvist, Jonny; Liu, Hui -Hai; Birkholzer, Jens

    2012-05-01

    Clay/shale has been considered as potential host rock for geological disposal of high-level nuclear waste throughout the world, because of its low permeability, low diffusion coefficient, high retention capacity for radionuclides, and capability to self-seal fractures induced by tunnel excavation. For example, Callovo-Oxfordian argillites at the Bure site, France (Fouche et al., 2004), Toarcian argillites at the Tournemire site, France (Patriarche et al., 2004), Opalinus Clay at the Mont Terri site, Switzerland (Meier et al., 2000), and Boom clay at the Mol site, Belgium (Barnichon and Volckaert, 2003) have all been under intensive scientific investigation (at both field and laboratory scales) for understanding a variety of rock properties and their relationships to flow and transport processes associated with geological disposal of nuclear waste. Clay/shale formations may be generally classified as indurated or plastic clays (Tsang and Hudson, 2010). The latter (including Boom clay) is a softer material without high cohesion; its deformation is dominantly plastic. During the lifespan of a clay repository, the repository performance is affected by complex thermal, hydrogeological, mechanical, chemical (THMC) processes, such as heat release due to radionuclide decay, multiphase flow, formation of damage zones, radionuclide transport, waste dissolution, and chemical reactions. All these processes are related to each other. An in-depth understanding of these coupled processes is critical for the performance assessment (PA) of the repository. These coupled processes may affect radionuclide transport by changing transport paths (e.g., formation and evolution of excavation damaged zone (EDZ)) and altering flow, mineral, and mechanical properties that are related to radionuclide transport. While radionuclide transport in clay formation has been studied using laboratory tests (e,g, Appelo et al. 2010, Garcia-Gutierrez et al., 2008, Maes et al., 2008), short-term field

  4. Credit WCT. Original 2'" x 2'" color negative is housed ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Credit WCT. Original 2-'" x 2-'" color negative is housed in the JPL Photography Laboratory, Pasadena, California. View shows small autoclave demonstrated by JPL staff member Milton Clay (JPL negative no. JPL-10286AC, 27 January 1989). - Jet Propulsion Laboratory Edwards Facility, Liner Laboratory, Edwards Air Force Base, Boron, Kern County, CA

  5. Energy conserving process for calcining clay

    SciTech Connect

    Baird, D.P.

    1990-08-14

    This patent describes an energy conversing process for calcining a clay. It comprises feeding a dry pulverized clay powder as feed material to a calciner to be calcined therein; passing the clay powder to be calcined through the calciner in direct heat exchange contact with a hot calcining gas passing therethrough whereby the clay powder is sufficiently heated to calcine substantially all the clay powder passing through the calciner and the hot calcining has is somewhat cooled; removing the calcined clay powder from the calciner and discharging the calcining from the calciner; subjecting the calciner discharge gas to electrostatic precipitation to clean the calciner discharge gas prior to venting the calciner discharge gas to the atmosphere whereby at least a substantial portion of calcined clay powder entrained in the calciner discharge gas is removed therefrom; collecting the hot calcined clay powder separated from the gas during electrostatic precipitation and mixing the collected hot calcined clay powder with the clay feed material being supplied to the calciner without substantially cooling the collected hot calcined clay powder prior to mixing with the feed material; and passing the calciner discharge has in heat exchange relationship with at least a portion of a cooling fluid prior to subjecting the calciner discharge gas to electrostatic precipitation.

  6. Contact micromechanics in granular media with clay

    SciTech Connect

    Ita, Stacey Leigh

    1994-08-01

    Many granular materials, including sedimentary rocks and soils, contain clay particles in the pores, grain contacts, or matrix. The amount and location of the clays and fluids can influence the mechanical and hydraulic properties of the granular material. This research investigated the mechanical effects of clay at grain-to-grain contacts in the presence of different fluids. Laboratory seismic wave propagation tests were conducted at ultrasonic frequencies using spherical glass beads coated with Montmorillonite clay (SWy-1) onto which different fluids were adsorbed. For all bead samples, seismic velocity increased and attenuation decreased as the contact stiffnesses increased with increasing stress demonstrating that grain contacts control seismic transmission in poorly consolidated and unconsolidated granular material. Coating the beads with clay added stiffness and introduced viscosity to the mechanical contact properties that increased the velocity and attenuation of the propagating seismic wave. Clay-fluid interactions were studied by allowing the clay coating to absorb water, ethyl alcohol, and hexadecane. Increasing water amounts initially increased seismic attenuation due to clay swelling at the contacts. Attenuation decreased for higher water amounts where the clay exceeded the plastic limit and was forced from the contact areas into the surrounding open pore space during sample consolidation. This work investigates how clay located at grain contacts affects the micromechanical, particularly seismic, behavior of granular materials. The need for this work is shown by a review of the effects of clays on seismic wave propagation, laboratory measurements of attenuation in granular media, and proposed mechanisms for attenuation in granular media.

  7. Hyperspectral analysis of clay minerals

    NASA Astrophysics Data System (ADS)

    Janaki Rama Suresh, G.; Sreenivas, K.; Sivasamy, R.

    2014-11-01

    A study was carried out by collecting soil samples from parts of Gwalior and Shivpuri district, Madhya Pradesh in order to assess the dominant clay mineral of these soils using hyperspectral data, as 0.4 to 2.5 μm spectral range provides abundant and unique information about many important earth-surface minerals. Understanding the spectral response along with the soil chemical properties can provide important clues for retrieval of mineralogical soil properties. The soil samples were collected based on stratified random sampling approach and dominant clay minerals were identified through XRD analysis. The absorption feature parameters like depth, width, area and asymmetry of the absorption peaks were derived from spectral profile of soil samples through DISPEC tool. The derived absorption feature parameters were used as inputs for modelling the dominant soil clay mineral present in the unknown samples using Random forest approach which resulted in kappa accuracy of 0.795. Besides, an attempt was made to classify the Hyperion data using Spectral Angle Mapper (SAM) algorithm with an overall accuracy of 68.43 %. Results showed that kaolinite was the dominant mineral present in the soils followed by montmorillonite in the study area.

  8. Thermophysical and mechanical characterization of clay bricks reinforced by alfa or straw fibers

    NASA Astrophysics Data System (ADS)

    Elhamdouni, Y.; Khabbazi, A.; Benayad, C.; Mounir, S.; Dadi, A.

    2017-03-01

    This work is part of the valuation of local materials such as clay (earth), alfa fiber and straw fiber. The goal is to use these materials as bricks in rural construction. These materials are abundant, natural, and renewable. The objective of this work is to study the thermal and mechanical behavior of a new material by mixing clay (chosen as the binder) with different mass percentages of alfa fiber (0.5%, 1%, 2%, 3%, 4%), and to compare these results with those of materials often used in the construction of individual houses in rural Morocco (clay + straw). The results obtained prove to us that using straw fibers can reduce the thermal conductivity compared to alfa fiber, which allows to have energy savings of 2% to 7%. By against, alfa fibers can improve the mechanical behavior of clay-based materials when compared to the clay + straw material (an increase of 8% to 17% in the tractive resistance by bending and 6% to 18% for compression resistance). These results also specify the optimal usage conditions of these fibers (alfa and straw) in the clay bricks.

  9. Clay particles - potential of positron annihilation lifetime spectroscopy (PALS) for studying interlayer spacing

    NASA Astrophysics Data System (ADS)

    Fong, N.; Guagliardo, P.; Williams, J.; Musumeci, A.; Martin, D.; Smith, S. V.

    2011-01-01

    Characterisation of clays is generally achieved by traditional methods, such as X-ray diffraction (XRD) and transmission electron microscopy (TEM). However, clays are often difficult to characterise due to lack of long-range order, thus these tools are not always reliable. Because interlayer spacing in clays can be adjusted to house molecules, there is growing interest to use these materials for drug delivery. Positron annihilation lifetime spectroscopy (PALS) was examined as an alternative tool to characterise a series of well-known clays. XRD of two layered double hydroxides; MgAl-LDH and MgGd-LDH, natural hectorite, fluoromica and laponite, and their PALS spectra were compared. XRD data was used to calculate the interlayer d- spacing in these materials and results show a decrease in interlayer spacing as the heavy metal ions are substituted for those of large ionic radii. Similar results were obtained for PALS data. This preliminary study suggests PALS has potential as a routine tool for characterising clay particles. Further work will examine the sensitivity and reliability of PALS to percent of metal doping and hydration in clay microstructure.

  10. Modernity and putty-clay

    NASA Astrophysics Data System (ADS)

    Ganesh, Trichur Kailas

    This dissertation addresses issues arising out of the problems of capital accumulation, productivity growth and 'putty-clay' technology. The concept of economic modernity occupies a central place in the subject-matter studied here in that it expresses both the incessant drive for newness that characterizes economic reality and the persistence of dated techniques that successfully resist replacement. This study examines the way in which an expansive development-theoretic 'putty-clay' framework may be employed to explain the historical processes behind both the avalanche of newness (innovations) and the conservatism of technology in the U.S. economy. The guiding link is the fixity of investments in physical capital equipment over time and space. The dilemma of fixed capital is studied in the context of the constant entrepreneurial search for flexibility and liquidity. The thesis advanced is that a development (Entwicklung)-theoretic 'putty-clay' conceptualization of the economic system adequately addresses the recurring problems of fixity, flexibility, and liquidity, and thereby permits important insights into the enigma surrounding the persistent productivity growth slowdown and 'stagflation' of the late sixties and seventies and the related phenomena of physical 'capital obsolescence' and the financial or 'speculative explosions' of our times. The notion of 'putty-clay' used here is an innovative one in that it departs from the growth-theoretic literature to re-appear as a Schumpeterian theory of modernity modified by a Veblenite view of an economic system directed by the exigencies of the 'machine-process'. The empirical aptitude of a macroeconomic 'putty-clay' model to explain capital obsolescence mediated by the energy 'crises' (supply shocks) of the seventies and eighties is examined in a separate chapter with results that differ markedly from the standard (Berndt and Wood) conclusions for the U.S. economy. The final chapter in the dissertation reverts to the

  11. Mars, clays and the origins of life

    NASA Technical Reports Server (NTRS)

    Hartman, Hyman

    1989-01-01

    To detect life in the Martian soil, tests were designed to look for respiration and photosynthesis. Both tests (labeled release, LR, and pyrolytic release, PR) for life in the Martian soils were positive. However, when the measurement for organic molecules in the soil of Mars was made, none were found. The interpretation given is that the inorganic constituents of the soil of Mars were responsible for these observations. The inorganic analysis of the soil was best fitted by a mixture of minerals: 60 to 80 percent clay, iron oxide, quartz, and soluble salts such as halite (NaCl). The minerals most successful in simulating the PR and LR experiments are iron-rich clays. There is a theory that considers clays as the first organisms capable of replication, mutation, and catalysis, and hence of evolving. Clays are formed when liquid water causes the weathering of rocks. The distribution of ions such as aluminum, magnesium, and iron play the role of bases in the DNA. The information was stored in the distribution of ions in the octahedral and tetrahedral molecules, but that they could, like RNA and DNA, replicate. When the clays replicated, each sheet of clay would be a template for a new sheet. The ion substitutions in one clay sheet would give rise to a complementary or similar pattern on the clay synthesized on its surface. It was theorized that it was on the surface of replicating iron-rich clays that carbon dioxide would be fixed in the light into organic acids such as formic or oxalic acid. If Mars had liquid water during a warm period in its past, clay formation would have been abundant. These clays would have replicated and evolved until the liquid water was removed due to cooling of Mars. It is entirely possible that the Viking mission detected life on Mars, but it was clay life that awaits the return of water to continue its evolution into life based on organic molecules.

  12. Selective Clay Placement Within a Silicate-Clay Epoxy Blend Nanocomposite

    NASA Technical Reports Server (NTRS)

    Miller, Sandi G (Inventor)

    2013-01-01

    A clay-epoxy nanocomposite may be prepared by dispersing a layered clay in an alkoxy epoxy, such as a polypropylene oxide based epoxide before combining the mixture with an aromatic epoxy to improve the nanocomposite's thermal and mechanical properties.

  13. Membrane behavior of clay liner materials

    NASA Astrophysics Data System (ADS)

    Kang, Jong Beom

    Membrane behavior represents the ability of porous media to restrict the migration of solutes, leading to the existence of chemico-osmosis, or the flow of liquid in response to a chemical concentration gradient. Membrane behavior is an important consideration with respect to clay soils with small pores and interactive electric diffuse double layers associated with individual particles, such as bentonite. The results of recent studies indicate the existence of membrane behavior in bentonite-based hydraulic barriers used in waste containment applications. Thus, measurement of the existence and magnitude of membrane behavior in such clay soils is becoming increasingly important. Accordingly, this research focused on evaluating the existence and magnitude of membrane behavior for three clay-based materials that typically are considered for use as liners for waste containment applications, such as landfills. The three clay-based liner materials included a commercially available geosynthetic clay liner (GCL) consisting of sodium bentonite sandwiched between two geotextiles, a compacted natural clay known locally as Nelson Farm Clay, and compacted NFC amended with 5% (dry wt.) of a sodium bentonite. The study also included the development and evaluation of a new flexible-wall cell for clay membrane testing that was used subsequently to measure the membrane behaviors of the three clay liner materials. The consolidation behavior of the GCL under isotropic states of stress also was evaluated as a preliminary step in the determination of the membrane behavior of the GCL under different effective consolidation stresses.

  14. Iodide uptake by negatively charged clay interlayers?

    PubMed

    Miller, Andrew; Kruichak, Jessica; Mills, Melissa; Wang, Yifeng

    2015-09-01

    Understanding iodide interactions with clay minerals is critical to quantifying risk associated with nuclear waste disposal. Current thought assumes that iodide does not interact directly with clay minerals due to electrical repulsion between the iodide and the negatively charged clay layers. However, a growing body of work indicates a weak interaction between iodide and clays. The goal of this contribution is to report a conceptual model for iodide interaction with clays by considering clay mineral structures and emergent behaviors of chemical species in confined spaces. To approach the problem, a suite of clay minerals was used with varying degrees of isomorphic substitution, chemical composition, and mineral structure. Iodide uptake experiments were completed with each of these minerals in a range of swamping electrolyte identities (NaCl, NaBr, KCl) and concentrations. Iodide uptake behaviors form distinct trends with cation exchange capacity and mineral structure. These trends change substantially with electrolyte composition and concentration, but do not appear to be affected by solution pH. The experimental results suggest that iodide may directly interact with clays by forming ion-pairs (e.g., NaI(aq)) which may concentrate within the interlayer space as well as the thin areas surrounding the clay particle where water behavior is more structured relative to bulk water. Ion pairing and iodide concentration in these zones is probably driven by the reduced dielectric constant of water in confined space and by the relatively high polarizability of the iodide species.

  15. Housing, Design, and Furnishings.

    ERIC Educational Resources Information Center

    Texas Tech Univ., Lubbock. Home Economics Curriculum Center.

    This document contains teacher's materials for a six-unit secondary education vocational home economics course on housing, design, and furnishings. The units cover: (1) the societal aspects of housing (including the relationship between housing and the economy, population trends, and culture-related housing characteristics); (2) family housing…

  16. Freeze-agglomeration: An alternative mechanism for clay film formation

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Oriented clay coatings (argillans, clay cutans, clay films, lamellae) are often interpreted to be caused by illuviation (pervection, lessivage) of fine clay particles. In montane meadow soils (Typic Humaquepts) of the northern Sierra Nevada Range, prominent clay cutans occur on ped faces of a paleos...

  17. Intercalated layered clay composites and their applications

    NASA Astrophysics Data System (ADS)

    Phukan, Anjali

    Supported inorganic reagents are rapidly emerging as new and environmentally acceptable reagents and catalysts. The smectite group of layered clay minerals, such as, Montmorillonite, provides promising character for adsorption, catalytic activity, supports etc. for their large surface area, swelling behavior and ion exchange properties. Aromatic compounds intercalated in layered clays are useful in optical molecular devices. Clay is a unique material for adsorption of heavy metals and various toxic substances. Clay surfaces are known to be catalytically active due to their surface acidity. Acid activated clays possess much improved surface areas and acidities and have higher pore volumes so that can absorb large molecules in the pores. The exchangeable cations in clay minerals play a key role in controlling surface acidity and catalytic activity. Recently, optically active metal-complex-Montmorillonite composites are reported to be active in antiracemization purposes. In view of the above, a research work, relating to the preparation of different modified clay composites and their catalytic applications were carried out. The different aspects and results of the present work have been reported in four major chapters. Chapter I: This is an introductory chapter, which contains a review of the literature regarding clay-based materials. Clay minerals are phyllosilicates with layer structure. Montmorillonite, a member of smectite group of clay, is 2:1 phyllosilicate, where a layer is composed of an octahedral sheet sandwiched by two tetrahedral sheets. Such clay shows cation exchange capacity (CEC) and is expressed in milli-equivalents per 100 gm of dry clay. Clays can be modified by interaction with metal ion, metal complexes, metal cluster and organic cations for various applications. Clays are also modified by treating with acid followed by impregnation with metal salts or ions. Montmorillonite can intercalate suitable metal complexes in excess of CEC to form double

  18. Sectioning Clay Models Makes Anatomy & Development Tangible

    ERIC Educational Resources Information Center

    Howell, Carina Endres; Howell, James Endres

    2010-01-01

    Clay models have proved to be useful teaching aids for many topics in biology that depend on three-dimensional reasoning. Students studying embryonic development struggle to mentally reconstruct the three-dimensional structure of embryos and larvae by observing prepared slides of cross-sectional slices. Students who build clay models of embryos…

  19. Clay smear: Review of mechanisms and applications

    NASA Astrophysics Data System (ADS)

    Vrolijk, Peter J.; Urai, Janos L.; Kettermann, Michael

    2016-05-01

    Clay smear is a collection of fault processes and resulting fault structures that form when normal faults deform layered sedimentary sections. These elusive structures have attracted deep interest from researchers interested in subsurface fluid flow, particularly in the oil and gas industry. In the four decades since the association between clay-smear structures and oil and gas accumulations was introduced, there has been extensive research into the fault processes that create clay smear and the resulting effects of that clay smear on fluid flow. We undertake a critical review of the literature associated with outcrop studies, laboratory and numerical modeling, and subsurface field studies of clay smear and propose a comprehensive summary that encompasses all of these elements. Important fault processes that contribute to clay smear are defined in the context of the ratio of rock strength and in situ effective stresses, the geometric evolution of fault systems, and the composition of the faulted section. We find that although there has been progress in all avenues pursued, progress has been uneven, and the processes that disrupt clay smears are mostly overlooked. We highlight those research areas that we think will yield the greatest benefit and suggest that taking these emerging results within a more process-based framework presented here will lead to a new generation of clay smear models.

  20. Surface geochemistry of the clay minerals

    PubMed Central

    Sposito, Garrison; Skipper, Neal T.; Sutton, Rebecca; Park, Sung-ho; Soper, Alan K.; Greathouse, Jeffery A.

    1999-01-01

    Clay minerals are layer type aluminosilicates that figure in terrestrial biogeochemical cycles, in the buffering capacity of the oceans, and in the containment of toxic waste materials. They are also used as lubricants in petroleum extraction and as industrial catalysts for the synthesis of many organic compounds. These applications derive fundamentally from the colloidal size and permanent structural charge of clay mineral particles, which endow them with significant surface reactivity. Unraveling the surface geochemistry of hydrated clay minerals is an abiding, if difficult, topic in earth sciences research. Recent experimental and computational studies that take advantage of new methodologies and basic insights derived from the study of concentrated ionic solutions have begun to clarify the structure of electrical double layers formed on hydrated clay mineral surfaces, particularly those in the interlayer region of swelling 2:1 layer type clay minerals. One emerging trend is that the coordination of interlayer cations with water molecules and clay mineral surface oxygens is governed largely by cation size and charge, similarly to a concentrated ionic solution, but the location of structural charge within a clay layer and the existence of hydrophobic patches on its surface provide important modulations. The larger the interlayer cation, the greater the influence of clay mineral structure and hydrophobicity on the configurations of adsorbed water molecules. This picture extends readily to hydrophobic molecules adsorbed within an interlayer region, with important implications for clay–hydrocarbon interactions and the design of catalysts for organic synthesis. PMID:10097044

  1. Uranium in clays of crystalline rocks

    SciTech Connect

    Simmons, G.; Caruso, L.

    1985-03-10

    Uraniferous clay aggregates in several granites have been examined in detail with a scanning electron microscope (SEM) equipped with a high resolution backscattered electron detector (BSE) and an energy dispersive x-ray system (EDS). The same polished sections used for the microscope observations were irradiated with thermal neutrons and the etched lexan detectors were then used to determine the location of uranium with a spatial resolution of a few microns. A set of 100 samples of the following granites were used for this study: Carnmenellis granite of southwestern England, Conway and Mount Osceola granites of central New Hampshire, Sherman granite of Wyoming and Colorado, Granite Mountains granite of Wyoming, several granites from central Maine, and the Graniteville granite of Missouri. These samples contain clay rich regions as large as a few millimeters that appear to consist entirely of clay when examined with the petrographic microscope. The clays are smectite, nontronite, or vermiculite. The fission track detectors show uranium to be present within the regions. Close examination with the BSE and EDS, however, shows in every instance that the host for the uranium is not clay but clay-sized grains of the following minerals: bastnesite group, hematite, siderite, secondary monazite, secondary thorite, and several different Y-bearing niobates. This finding may have severe implications for the long-term retention of uranium and transuranic elements adsorbed on clay. Perhaps the presence of clay is not significant for the long-term retention of radioisotopes. 22 refs., 7 figs.

  2. Using Clay Therapy To Change Negative Behaviors.

    ERIC Educational Resources Information Center

    Kahn, Victoria

    This manual describes a clay therapy program appropriate for use with students having a variety of exceptionalities and in an age range from 6 to 18 years. Organization and staffing are briefly discussed followed by a list of long range goals (affective, motoric, and aesthetic), suggestions for clay therapy implementation to achieve these goals,…

  3. Dehydration-induced luminescence in clay minerals

    NASA Technical Reports Server (NTRS)

    Coyne, L. M.; Lahav, N.; Lawless, J. G.

    1981-01-01

    Reports of triboluminescent phenomena in organic crystalline materials prompted a search for related processes in clay minerals. The reported extensive mechanical distortion produced on freezing and drying of montmorillonite was particularly interesting because of studies of condensation reactions in a wet/dry cycled reaction sequence. The discovery of an unusual luminescent process in several clay minerals is reported and its characteristics are described.

  4. The colloidal chemistry of ceramic clays

    NASA Technical Reports Server (NTRS)

    Phelps, G. W.

    1984-01-01

    The colloidal chemistry and mineralogy of two argil minerals were studied. Deposits of kaolin and of ceramic clays in the United States and England are discussed for the probable mechanism of formation. The structural modifications of the bed, original material associated with the clays and the proper use of flocculants are discussed.

  5. Active containment systems incorporating modified pillared clays

    SciTech Connect

    Lundie, P. |; McLeod, N.

    1997-12-31

    The application of treatment technologies in active containment systems provides a more advanced and effective method for the remediation of contaminated sites. These treatment technologies can be applied in permeable reactive walls and/or funnel and gate systems. The application of modified pillared clays in active containment systems provides a mechanism for producing permeable reactive walls with versatile properties. These pillared clays are suitably modified to incorporate reactive intercalatants capable of reacting with both a broad range of organic pollutants of varying molecular size, polarity and reactivity. Heavy metals can be removed from contaminated water by conventional ion-exchange and other reactive processes within the clay structure. Complex contamination problems can be addressed by the application of more than one modified clay on a site specific basis. This paper briefly describes the active containment system and the structure/chemistry of the modified pillared clay technology, illustrating potential applications of the in-situ treatment process for contaminated site remediation.

  6. Permeation properties of polymer/clay nanocomposites

    NASA Astrophysics Data System (ADS)

    Kalendova, A.; Merinska, D.; Gerard, J. F.

    2012-07-01

    The important characteristics of polymer/clay nanocomposites are stability, barrier properties and in the case of polyvinyl chloride also plasticizer migration into other materials. Therefore, the permeation properties of polymer/clay nanocomposites are discussed in this paper. The attention was focused to the polyethylene (PE) and polyvinyl chloride (PVC). Natural type of montmorillonite MMTNa+ and modified types of montmorillonite from Southern Clay Products were used as the inorganic phase. As the compounding machine, one screw Buss KO-kneader was employed. The principal aim is to fully exfoliate the clay into polymer matrix and enhanced the permeation properties. Prepared samples were tested for O2 and CO2 permeability. Polymer/clay nanocomposite structure was determined on the base of X-ray diffraction and electron microscopy (TEM).

  7. Multifaceted role of clay minerals in pharmaceuticals

    PubMed Central

    Khurana, Inderpreet Singh; Kaur, Satvinder; Kaur, Harpreet; Khurana, Rajneet Kaur

    2015-01-01

    The desirable physical and physiochemical properties of clay minerals have led them to play a substantial role in pharmaceutical formulations. Clay minerals like kaolin, smectite and palygorskite-sepiolite are among the world's most valuable industrial minerals and of considerable importance. The elemental features of clay minerals which caused them to be used in pharmaceutical formulations are high specific area, sorption capacity, favorable rheological properties, chemical inertness, swelling capacity, reactivity to acids and inconsiderable toxicity. Of course, these are highly cost effectual. This special report on clay minerals provides a bird's eye view of the chemical composition and structure of these minerals and their influence on the release properties of active medicinal agents. Endeavor has been made to rope in myriad applications depicting the wide acceptability of these clay minerals. PMID:28031881

  8. Release kinetics of volatiles from clay minerals

    NASA Astrophysics Data System (ADS)

    Clausen, Pascal

    2007-03-01

    Smectite clay minerals are known to have interesting sorption properties, but the prediction of the kinetics of desorption of volatile molecules from such clays remains a challenge. The aim of this work is to relate the isothermal rate of desorption of volatile molecules from cation exchanged smectite clays to the chemical structures and geometries of the interacting species (clay platelet surface, type of counter-ion, type of volatile). It is thought that the rate of desorption of the volatiles at a given time is governed by their instantaneous diffusion in the clay and in the gas phase, which in turns is dependent on the volatile's interaction with its chemical and geometrical environment. Therefore, in addition to isothermal desorption rate measurements by thermogravimetry, activation energies of desorption are measured and calculated and the interacting compounds are characterized in terms of their chemical structure and geometry.

  9. Clays and other minerals in prebiotic processes

    NASA Technical Reports Server (NTRS)

    Paecht-Horowitz, M.

    1984-01-01

    Clays and other minerals have been investigated in context with prebiotic processes, mainly in polymerization of amino acids. It was found that peptides adsorbed on the clay, prior to polymerization, influence the reaction. The ratio between the amount of the peptides adsorbed and that of the clay is important for the yield as well as for the degrees of polymerization obtained. Adsorption prior to reaction produces a certain order in the aggregates of the clay particles which might induce better reaction results. Excess of added peptides disturbs this order and causes lesser degrees of polymerization. In addition to adsorption, clays are also able to occlude between their layers substances out of the environment, up to very high concentrations.

  10. Effect of the local clay distribution on the effective electrical conductivity of clay rocks

    NASA Astrophysics Data System (ADS)

    Cosenza, P.; Prêt, D.; Zamora, M.

    2015-01-01

    The "local porosity theory" proposed by Hilfer was revisited to develop a "local clay theory" (LCT) that establishes a quantitative relationship between the effective electrical conductivity and clay distribution in clay rocks. This theory is primarily based on a "local simplicity" assumption; under this assumption, the complexity of spatial clay distribution can be captured by two local functions, namely, the local clay distribution and the local percolation probability, which are calculated from a partitioning of a mineral map. The local clay distribution provides information about spatial clay fluctuations, and the local percolation probability describes the spatial fluctuations in the clay connectivity. This LCT was applied to (a) a mineral map made from a Callovo-Oxfordian mudstone sample and (b) (macroscopic) electrical conductivity measurements performed on the same sample. The direct and inverse modeling shows two results. First, the textural and classical model assuming that the electrical anisotropy of clay rock is mainly controlled by the anisotropy of the sole clay matrix provides inconsistent inverted values. Another textural effect, the anisotropy induced by elongated and oriented nonclayey grains, should be considered. Second, the effective conductivity values depend primarily on the choice of the inclusion-based models used in the LCT. The impact of local fluctuations of clay content and connectivity on the calculated effective conductivity is lower.

  11. Interfacial interactions between polyethylene matrix and clay layers in polyethylene/clay nanocomposites

    NASA Astrophysics Data System (ADS)

    Abu-Zurayk, R.

    2015-10-01

    Polyethylene/clay nanocomposites were prepared as blown films using different formulae (clay contents (4 and 6 wt%) and compatibilizer/clay ratio (1/2, 1.0, 2.0)). Structure and mechanical behaviour were tested. It was found that blown film extrusion process decreased the tactoids size and consequently enhanced the exfoliation degree of the clay layers inside the polymer matrix, which is due to the elongational stress during extrusion. Addition of clay had some effects on mechanical behaviour. There was an increase of yield strength (max 32%). Yield strength is related to the interfacial interaction between the polymer and the clay layers in the nanocomposites, which would be enhanced by enhancing the compatibility between polymer and clay layers. Correlation analysis showed good correlation between compatibility and interfacial interaction parameters, and between parameters of interfacial interaction, structure and yield strength.

  12. 24 CFR 982.618 - Shared housing: Housing quality standards.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 24 Housing and Urban Development 4 2011-04-01 2011-04-01 false Shared housing: Housing quality standards. 982.618 Section 982.618 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING...

  13. 24 CFR 982.618 - Shared housing: Housing quality standards.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 24 Housing and Urban Development 4 2014-04-01 2014-04-01 false Shared housing: Housing quality standards. 982.618 Section 982.618 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING...

  14. 24 CFR 982.618 - Shared housing: Housing quality standards.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 24 Housing and Urban Development 4 2012-04-01 2012-04-01 false Shared housing: Housing quality standards. 982.618 Section 982.618 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING...

  15. 24 CFR 982.618 - Shared housing: Housing quality standards.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 24 Housing and Urban Development 4 2013-04-01 2013-04-01 false Shared housing: Housing quality standards. 982.618 Section 982.618 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING...

  16. Phosphates in some missouri refractory clays

    USGS Publications Warehouse

    Hall, R.B.; Foord, E.E.; Keller, D.J.; Keller, W.D.

    1997-01-01

    This paper describes in detail phosphate minerals occurring in refractory clays of Missouri and their effect on the refractory degree of the clays. The minerals identified include carbonate-fluorapatite (francolite), crandallite, goyazite, wavellite, variscite and strengite. It is emphasized that these phosphates occur only in local isolated concentrations, and not generally in Missouri refractory clays. The Missouri fireclay region comprises 2 districts, northern and southern, separated by the Missouri River In this region, clay constitutes a major part of the Lower Pennsylvanian Cheltenham Formation. The original Cheltenham mud was an argillic residue derived from leaching and dissolution of pre-Pennsylvanian carbonates. The mud accumulated on a karstic erosion surface truncating the pre-Cheltenham rocks. Fireclays of the northern district consist mainly of poorly ordered kaolinite, with variable but minor amounts of illite, chlorite and fine-grained detrital quartz. Clays of the southern district were subjected to extreme leaching that produced well-ordered kaolinite flint clays. Local desilication formed pockets of diaspora, or more commonly, kaolinite, with oolite-like nubs or burls of diaspore ("burley" clay). The phosphate-bearing materials have been studied by X-ray diffraction (XRD), scanning electron microscopy-energy dispersive spectral analysis (SEM-EDS) and chemical analysis. Calcian goyazite was identified in a sample of diaspore, and francolite in a sample of flint clay. A veinlet of wavellite occurs in flint clay at one locality, and a veinlet of variscite-strengite at another locality. The Missouri flint-clay-hosted francolite could not have formed in the same manner as marine francolite The evidence suggests that the Cheltenham francolite precipitated from ion complexes in pore water nearly simultaneously with crystallization of kaolinite flint clay from an alumina-silica gel. Calcian goyazite is an early diagenetic addition to its diaspore host

  17. Fine particle clay catalysts for coal liquefaction

    SciTech Connect

    Olson, E.S.

    1991-01-01

    The efficient production of environmentally acceptable distillate fuels requires catalysts for hydrogenation and cleavage of the coal macromolecules and removal of oxygen, nitrogen, and sulfur heteroatoms. The goal of the proposed research is to develop new catalysts for the direct liquefaction of coal. This type of catalyst consists of fine clay particles that have been treated with reagents which form pillaring structures between the aluminosilicate layers of the clay. The pillars not only hold the layers apart but also constitute the active catalytic sites for hydrogenation of the coal and the solvent used in the liquefaction. The pillaring catalytic sites are composed of pyrrhotite, which has been previously demonstrated to be active for coal liquefaction. The pyrrhotite sites are generated in situ by sulfiding the corresponding oxyiron species. The size of the catalyst will be less than 40 nm in order to promote intimate contact with the coal material. Since the clays and reagents for pillaring and activating the clays are inexpensive, the catalysts can be discarded after use, rather than regenerated by a costly process. The proposed work will evaluate methods for preparing the fine particle iron-pillared clay dispersions and for activating the particles to generate the catalysts. Characterization studies of the pillared clays and activated catalysts will be performed. The effectiveness of the pillared clay dispersion for hydrogenation and coal liquefaction will be determined in several types of testing.

  18. Fine particle clay catalysts for coal liquefaction

    SciTech Connect

    Olson, E.S.

    1991-01-01

    The efficient production of environmentally acceptable distillate fuels requires catalysts for hydrogenation and cleavage of the coal macromolecules and removal of oxygen, nitrogen, and sulfur heteroatoms. The goal of the proposed research is to develop new catalysts for the direct liquefaction of coal. This type of catalyst consists of fine clay particles that have been treated with reagents which form pillaring structures between the aluminosilicate layers of the clay. The pillars not only hold the layers apart but also constitute the active catalytic sites for hydrogenation of the coal and solvent used in the liquefaction. The pillaring catalytic sites are composed of pyrrhotite, which has been previously demonstrated to be active for coal liquefaction. The pyrrhotite sites are generated in situ by sulfiding the corresponding oxyiron species. The size of the catalyst will be less than 40 nm in order to promote intimate contact with the coal material. Since the clays and reagents for pillaring and activating the clays are inexpensive, the catalysts can be discarded after use, rather than regenerated by a costly process. The proposed work will evaluate methods for preparing the fine particle iron-pillared clay dispersions and for activating the particles to generate the catalysts. Characterization studies of the pillared clays and activated catalysts will performed. The effectiveness of the pillared clay dispersion for hydrogenation and coal liquefaction will be determined in several types of testing. 5 refs., 1 tab.

  19. Student-Initiated Housing

    ERIC Educational Resources Information Center

    Feild, Robert M.

    1973-01-01

    Summarizes a report that describes housing where student groups lease, purchase, or even develop their own living quarters. Considers the birth of the movement, federal student housing programs, and a view to future programs. (Author/DN)

  20. Insulator for laser housing

    DOEpatents

    Duncan, D.B.

    1992-12-29

    The present invention provides a heat-resistant electrical insulator adapted for joining laser housing portions, which insulator comprises: an annulus; a channel in the annulus traversing the circumference and length of the housing; at least two ports, each communicating with the channel and an outer surface of the housing; and an attachment for securely attaching each end of the annulus to a laser housing member. 3 figs.

  1. Insulator for laser housing

    DOEpatents

    Duncan, David B.

    1992-01-01

    The present invention provides a heat-resistant electrical insulator adapted for joining laser housing portions, which insulator comprises: an annulus; a channel in the annulus traversing the circumference and length of the housing; at least two ports, each communicating with the channel and an outer surface of the housing; and an attachment for securely attaching each end of the annulus to a laser housing member.

  2. 59. Photocopied August 1978. POWER HOUSE FROM WEST BANK OF ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    59. Photocopied August 1978. POWER HOUSE FROM WEST BANK OF FOREBAY, SEPTEMBER 11, 1901. AT THIS POINT MOST OF THE PENSTOCK STEELWORK WAS WAS COMPLETED. THE PENSTOCK WALLS ON THE RIGHT SIDE OF THE PHOTO HAVE BEEN COMPLETED. THE DUMP TRAIN IS PILING CLAY AGAINST THE FOREBAY WALL IN PREPARATION FOR THE CONSTRUCTION OF THE FOREBAY APRON. A SMALL PILE DRIVER IS DRIVING PILES FOR THIS STRUCTURE. (179) - Michigan Lake Superior Power Company, Portage Street, Sault Ste. Marie, Chippewa County, MI

  3. The Hispanic Housing Crisis.

    ERIC Educational Resources Information Center

    Dolbeare, Cushing N.; Canales, Judith A.

    This report examines the housing characteristics and needs of Hispanic households in the United States, drawing on information from the 1980 Census and the 1983 Annual Housing Survey. Among the conclusions are the following: (1) housing quality is a major problem for more than one in six Hispanic families; (2) among Hispanic subgroups, Puerto…

  4. [Accessible Rural Housing.

    ERIC Educational Resources Information Center

    Baker, Nick, Ed.

    1995-01-01

    This issue of the quarterly newsletter "Rural Exchange" provides information and resources on accessible rural housing for the disabled. "Accessible Manufactured Housing Could Increase Rural Home Supply" (Nick Baker) suggests that incorporation of access features such as lever door handles and no-step entries into manufactured housing could help…

  5. Photochemistry on, and Nature of Adsorbed Species on Colloidal Clay and Model Clay Systems.

    DTIC Science & Technology

    1987-09-25

    model system for clays, and also acts as a bridge between ionic organic micelle systems and colloidal clays. In the first instance a commercial...hexadecylpyridinium chloride, tend to cluster on the silica surface rather than disperse uniformly around it as with ionic micelles. We have also...alcohol as additives to the clay. Layers of organic material are formed by these additives in montmorillonite layers, and now non- ionic organic

  6. The Basics in Pottery: Clay and Tools.

    ERIC Educational Resources Information Center

    Larson, Joan

    1985-01-01

    Art teachers at the middle school or junior high school level usually find themselves in a program teaching ceramics. The most essential tools needed for a ceramics class are discussed. Different kinds of clay are also discussed. (RM)

  7. Natural Radioactivity of Boron Added Clay Samples

    SciTech Connect

    Akkurt, I.; Guenoglu, K.; Canakcii, H.; Mavi, B.

    2011-12-26

    Clay, consisting fine-grained minerals, is an interesting materials and can be used in a variety of different fields especially in dermatology application. Using clay such a field it is important to measure its natural radioactivity. Thus the purpose of this study is to measure {sup 226}Ra, {sup 232}Th and {sup 40}K concentration in clay samples enriched with boron. Three different types of clay samples were prepared where boron is used in different rate. The measurements have been determined using a gamma-ray spectrometry consists of a 3''x3'' NaI(Tl) detector. From the measured activity the radium equivalent activities (Ra{sub eq}), external hazard index (H{sub ex}), absorbed dose rate in air (D) and annual effective dose (AED) have also been obtained.

  8. Natural Radioactivity of Boron Added Clay Samples

    NASA Astrophysics Data System (ADS)

    Akkurt, I.; ćanakciı, H.; Mavi, B.; Günoǧlu, K.

    2011-12-01

    Clay, consisting fine-grained minerals, is an interesting materials and can be used in a variety of diferent fields especially in dermatology application. Using clay such a field it is important to measure its natural radioacitivty. Thus the purpose of this study is to measure 226Ra, 232Th and 40K concentration in clay samples enriched with boron. Three different types of clay samples were prepared where boron is used in different rate. The measurements have been determined using a gamma-ray spectrometry consists of a 3″×3″ NaI(Tl) detector. From the measured activity the radium equivalent activities (Raeq), external hazard index (Hex), absorbed dose rate in air (D) and annual effective dose (AED) have also been obtained.

  9. 12 CFR 1807.401 - Affordable housing-rental housing.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 12 Banks and Banking 9 2012-01-01 2012-01-01 false Affordable housing-rental housing. 1807.401... TREASURY CAPITAL MAGNET FUND Qualification as Affordable Housing § 1807.401 Affordable housing—rental housing. To qualify as Affordable Housing, a rental Multi-family housing project financed with a CMF...

  10. 12 CFR 1807.401 - Affordable housing-rental housing.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 12 Banks and Banking 7 2011-01-01 2011-01-01 false Affordable housing-rental housing. 1807.401... TREASURY CAPITAL MAGNET FUND Qualification as Affordable Housing § 1807.401 Affordable housing—rental housing. To qualify as Affordable Housing, a rental Multi-family housing project financed with a CMF...

  11. 12 CFR 1807.401 - Affordable housing-rental housing.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 12 Banks and Banking 9 2013-01-01 2013-01-01 false Affordable housing-rental housing. 1807.401... TREASURY CAPITAL MAGNET FUND Qualification as Affordable Housing § 1807.401 Affordable housing—rental housing. To qualify as Affordable Housing, a rental Multi-family housing project financed with a CMF...

  12. 12 CFR 1807.401 - Affordable housing-rental housing.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 12 Banks and Banking 10 2014-01-01 2014-01-01 false Affordable housing-rental housing. 1807.401... TREASURY CAPITAL MAGNET FUND Qualification as Affordable Housing § 1807.401 Affordable housing—rental housing. To qualify as Affordable Housing, a rental Multi-family housing project financed with a CMF...

  13. Clay-Bacteria Systems and Biofilm Production

    NASA Astrophysics Data System (ADS)

    Steiner, J.; Alimova, A.; Katz, A.; Steiner, N.; Rudolph, E.; Gottlieb, P.

    2007-12-01

    Soil clots and the aerosol transport of bacteria and spores are promoted by the formation of biofilms (bacteria cells in an extracellular polymeric matrix). Biofilms protect microorganisms by promoting adhesion to both organic and inorganic surfaces. Time series experiments on bacteria-clay suspensions demonstrate that biofilm growth is catalyzed by the presence of hectorite in minimal growth media for the studied species: Gram negatives (Pseudomonas syringae and Escherichia coli,) and Gram positives (Staphylococcus aureus and Bacillus subtilis). Soil organisms (P. syringae, B. subtilis) and organisms found in the human population (E. coli, S. aureus) are both used to demonstrate the general applicability of clay involvement. Fluorescent images of the biofilms are acquired by staining with propidium iodide, a component of the BacLightTM Live/Dead bacterial viability staining kit (Molecular Probes, Eugene, OR). The evolving polysaccharide-rich biofilm reacts with the clay interlayer site causing a complex substitution of the two-water hectorite interlayer with polysaccharide. The result is often a three-peak composite of the (001) x-ray diffraction maxima resulting from polysaccharide-expanded clays and an organic-driven contraction of a subset of the clays in the reaction medium. X-ray diffractograms reveal that the expanded set creates a broad maximum with clay subsets at 1.84 nm and 1.41 nm interlayer spacings as approximated by a least squares double Lorentzian fit, and a smaller shoulder at larger 2q, deriving from a contraction of the interlayer spacing. Washing with chlorox removes organic material from the contracted clay and creates a 1-water hectorite single peak in place of the double peak. The clay response can be used as an indirect indicator of biofilm in an environmental system.

  14. Cobalt sorption in silica-pillared clays.

    PubMed

    Sampieri, A; Fetter, G; Bosch, P; Bulbulian, S

    2006-01-03

    Silicon pillared samples were prepared following conventional and microwave irradiation methods. The samples were characterized and tested in cobalt sorption. Ethylenediammine was added before cobalt addition to improve the amount of cobalt retained. The amount of cobalt introduced in the original clay in the presence of ethylenediammine was the highest. In calcined pillared clays the cobalt retention with ethylenediammine was lower (ca. 40%). In all cases the presence of ethylenediammine increased twice the amount of cobalt sorption measured for aqueous solutions.

  15. Clay-mediated reactions of HCN oligomers - The effect of the oxidation state of the clay

    NASA Technical Reports Server (NTRS)

    Ferris, J. P.; Alwis, K. W.; Edelson, E. H.; Mount, N.; Hagan, W. J., Jr.

    1981-01-01

    Montmorillonite clays which contain Fe(III) inhibit the oligomerization of aqueous solutions of HCN. The inhibitory effect is due to the rapid oxidation of diaminomaleonitrile, a key intermediate in HCN oligomerization, by the Fe(III) incorporated into the aluminosilicate lattice of the clay. The Fe(III) oxidizes diaminomaleonitrile to diiminosuccinonitrile, a compound which is rapidly hydrolyzed to HCN and oxalic acid derivatives. Diaminomaleonitrile is not oxidized when Fe(III) in the montmorillonite is reduced with hydrazine. The oxidation state of the clay is an important variable in experiments designed to simulate clay catalysis on the primitive earth.

  16. What Makes a Natural Clay Antibacterial?

    PubMed Central

    Williams, Lynda B.; Metge, David W.; Eberl, Dennis D.; Harvey, Ronald W.; Turner, Amanda G.; Prapaipong, Panjai; Poret-Peterson, Amisha T.

    2011-01-01

    Natural clays have been used in ancient and modern medicine, but the mechanism(s) that make certain clays lethal against bacterial pathogens has not been identified. We have compared the depositional environments, mineralogies, and chemistries of clays that exhibit antibacterial effects on a broad spectrum of human pathogens including antibiotic resistant strains. Natural antibacterial clays contain nanoscale (<200 nm), illite-smectite and reduced iron phases. The role of clay minerals in the bactericidal process is to buffer the aqueous pH and oxidation state to conditions that promote Fe2+ solubility. Chemical analyses of E. coli killed by aqueous leachates of an antibacterial clay show that intracellular concentrations of Fe and P are elevated relative to controls. Phosphorus uptake by the cells supports a regulatory role of polyphosphate or phospholipids in controlling Fe2+. Fenton reaction products can degrade critical cell components, but we deduce that extracellular processes do not cause cell death. Rather, Fe2+ overwhelms outer membrane regulatory proteins and is oxidized when it enters the cell, precipitating Fe3+ and producing lethal hydroxyl radicals. PMID:21413758

  17. Soil clay content underlies prion infection odds

    USGS Publications Warehouse

    David, Walter W.; Walsh, D.P.; Farnsworth, Matthew L.; Winkelman, D.L.; Miller, M.W.

    2011-01-01

    Environmental factors-especially soil properties-have been suggested as potentially important in the transmission of infectious prion diseases. Because binding to montmorillonite (an aluminosilicate clay mineral) or clay-enriched soils had been shown to enhance experimental prion transmissibility, we hypothesized that prion transmission among mule deer might also be enhanced in ranges with relatively high soil clay content. In this study, we report apparent influences of soil clay content on the odds of prion infection in free-ranging deer. Analysis of data from prion-infected deer herds in northern Colorado, USA, revealed that a 1% increase in the clay-sized particle content in soils within the approximate home range of an individual deer increased its odds of infection by up to 8.9%. Our findings suggest that soil clay content and related environmental properties deserve greater attention in assessing risks of prion disease outbreaks and prospects for their control in both natural and production settings. ?? 2011 Macmillan Publishers Limited. All rights reserved.

  18. Dynamics of confined reactive water in smectite clay-zeolite composites

    SciTech Connect

    Pitman, Michael C.; Van Duin, Adri C. T.

    2012-01-01

    The dynamics of water confined to mesoporous regions in minerals such as swelling clays and zeolites is fundamental to a wide range of resource management issues impacting many processes on a global scale, including radioactive waste containment, desalination, and enhanced oil recovery. Large-scale atomic models of freely diffusing multilayer smectite particles at low hydration confined in a silicalite cage are used to investigate water dynamics in the composite environment with the ReaxFF reactive force field over a temperature range of 300 647 K. The reactive capability of the force field enabled a range of relevant surface chemistry to emerge, including acid/base equilibria in the interlayer calcium hydrates and silanol formation on the edges of the clay and inner surface of the zeolite housing. After annealing, the resulting clay models exhibit both mono- and bilayer hydration structures. Clay surface hydration redistributed markedly and yielded to silicalite water loading. We find that the absolute rates and temperature dependence of water dynamics compare well to neutron scattering data and pulse field gradient measures from relevant samples of Ca-montmorillonite and silicalite, respectively. Within an atomistic, reactive context, our results distinguish water dynamics in the interlayer Ca(OH)2 nH2O environment from water flowing over the clay surface, and from water diffusing within silicalite. We find that the diffusion of water when complexed to Ca hydrates is considerably slower than freely diffusing water over the clay surface, and the reduced mobility is well described by a difference in the Arrhenius pre-exponential factor rather than a change in activation energy.

  19. Dynamics of confined reactive water in Smectic clay-zeolite composites.

    SciTech Connect

    Pitman, Michael C.; Van Duin, Adri C. T.

    2012-01-01

    The dynamics of water confined to mesoporous regions in minerals such as swelling clays and zeolites is fundamental to a wide range of resource management issues impacting many processes on a global scale, including radioactive waste containment, desalination, and enhanced oil recovery. Large-scale atomic models of freely diffusing multilayer smectite particles at low hydration confined in a silicalite cage are used to investigate water dynamics in the composite environment with the ReaxFF reactive force field over a temperature range of 300 647 K. The reactive capability of the force field enabled a range of relevant surface chemistry to emerge, including acid/base equilibria in the interlayer calcium hydrates and silanol formation on the edges of the clay and inner surface of the zeolite housing. After annealing, the resulting clay models exhibit both mono- and bilayer hydration structures. Clay surface hydration redistributed markedly and yielded to silicalite water loading. We find that the absolute rates and temperature dependence of water dynamics compare well to neutron scattering data and pulse field gradient measures from relevant samples of Ca-montmorillonite and silicalite, respectively. Within an atomistic, reactive context, our results distinguish water dynamics in the interlayer Ca(OH)2 nH2O environment from water flowing over the clay surface, and from water diffusing within silicalite. We find that the diffusion of water when complexed to Ca hydrates is considerably slower than freely diffusing water over the clay surface, and the reduced mobility is well described by a difference in the Arrhenius pre-exponential factor rather than a change in activation energy.

  20. Dynamics of confined reactive water in smectite clay-zeolite composites.

    PubMed

    Pitman, Michael C; van Duin, Adri C T

    2012-02-15

    The dynamics of water confined to mesoporous regions in minerals such as swelling clays and zeolites is fundamental to a wide range of resource management issues impacting many processes on a global scale, including radioactive waste containment, desalination, and enhanced oil recovery. Large-scale atomic models of freely diffusing multilayer smectite particles at low hydration confined in a silicalite cage are used to investigate water dynamics in the composite environment with the ReaxFF reactive force field over a temperature range of 300-647 K. The reactive capability of the force field enabled a range of relevant surface chemistry to emerge, including acid/base equilibria in the interlayer calcium hydrates and silanol formation on the edges of the clay and inner surface of the zeolite housing. After annealing, the resulting clay models exhibit both mono- and bilayer hydration structures. Clay surface hydration redistributed markedly and yielded to silicalite water loading. We find that the absolute rates and temperature dependence of water dynamics compare well to neutron scattering data and pulse field gradient measures from relevant samples of Ca-montmorillonite and silicalite, respectively. Within an atomistic, reactive context, our results distinguish water dynamics in the interlayer Ca(OH)(2)·nH(2)O environment from water flowing over the clay surface, and from water diffusing within silicalite. We find that the diffusion of water when complexed to Ca hydrates is considerably slower than freely diffusing water over the clay surface, and the reduced mobility is well described by a difference in the Arrhenius pre-exponential factor rather than a change in activation energy.

  1. Pier-scour depths affected by clay in Mississippi

    USGS Publications Warehouse

    Wilson, K. Van

    1998-01-01

    This paper briefly presents pier-scour depths measured during 1943-94, that are thought to have been affected by consolidated cohesive materials (clay) in Mississippi. MDOT soil reports were available for 29 measured pier-scour depths thought to be affected by clay. The cohesion and friction angles were approximated for the clay, and using the soil borings where clay was overlain by sand and(or) gravel, the top of the clay stratum was approximated in order to determine the net scour through the clay. Eight additional measured pier-scour depths were thought to be affected by clay, but no MDOT soil reports or borings were available. The net pier-scour depth through the clay is a rough approximation where sand and (or) gravel overlie a clay stratum and, therefore, only represents part of the total pier-scour depth. Limited data indicate the pier-scour depth decreases as shear strength of the clay increases.

  2. NMR imaging and cryoporometry of swelling clays

    NASA Astrophysics Data System (ADS)

    Dvinskikh, Sergey V.; Szutkowski, Kosma; Petrov, Oleg V.; Furó, István.

    2010-05-01

    Compacted bentonite clay is currently attracting attention as a promising "self-sealing" buffer material to build in-ground barriers for the encapsulation of radioactive waste. It is expected to fill up the space between waste canister and surrounding ground by swelling and thus delay flow and migration from the host rock to the canister. In environmental sciences, evaluation and understanding of the swelling properties of pre-compacted clay are of uttermost importance for designing such buffers. Major goal of present study was to provide, in a non-invasive manner, a quantitative measure of bentonite distribution in extended samples during different physical processes in an aqueous environment such as swelling, dissolution, and sedimentation on the time scale from minutes to years. The propagation of the swelling front during clay expansion depending on the geometry of the confining space was also studied. Magnetic resonance imaging and nuclear magnetic resonance spectroscopy were adapted and used as main experimental techniques. With this approach, spatially resolved movement of the clay/water interface as well as clay particle distributions in gel phase can be monitored [1]. Bulk samples with swelling in a vertical tube and in a horizontal channel were investigated and clay content distribution profiles in the concentration range over five orders of magnitude and with sub-millimetre spatial resolution were obtained. Expansion rates for bulk swelling and swelling in narrow slits were compared. For sodium-exchanged montmorillonite in contact with de-ionised water, we observed a remarkable acceleration of expansion as compared to that obtained in the bulk. To characterize the porosity of the clay a cryoporometric study [2] has been performed. Our results have important implications to waste repository designs and for the assessment of its long-term performance. Further research exploring clay-water interaction over a wide variety of clay composition and water ionic

  3. Examination and Manipulation of Clay Aggregates - Initial Inquiry

    DTIC Science & Technology

    2011-06-06

    and the first conclusions in the examination and testing of clay aggregates composed of montmorillonite clay and a polysaccharide (xanthan gum, also...and the first conclusions in the examination and testing of clay aggregates composed of montmorillonite clay and a polysaccharide (xanthan gum, also...PSU and the X-gum content from 0% to 10% of the mineral content of the clay (by weight). Montmorillonite was used in all the suspensions prepared

  4. Effect of electrolytes on the microstructure and yielding of aqueous dispersions of colloidal clay.

    PubMed

    Ali, Samim; Bandyopadhyay, Ranjini

    2016-01-14

    Na-montmorillonite is a natural clay mineral and is available in abundance in nature. The aqueous dispersions of charged and anisotropic platelets of this mineral exhibit non-ergodic kinetically arrested states ranging from soft glassy phases dominated by interparticle repulsions to colloidal gels stabilized by salt induced attractive interactions. When the salt concentration in the dispersing medium is varied systematically, viscoelasticity and yield stress of the dispersion show non-monotonic behavior at a critical salt concentration, thus signifying a morphological change in the dispersion microstructures. We directly visualize the microscopic structures of these kinetically arrested phases using cryogenic scanning electron microscopy. We observe the existence of honeycomb-like network morphologies for a wide range of salt concentrations. The transition of the gel morphology, dominated by overlapping coin (OC) and house of cards (HoC) associations of clay particles at low salt concentrations to a new network structure dominated by face-face coagulation of platelets, is observed across the critical salt concentration. We further assess the stability of these gels under gravity using electroacoustics. This study, performed for concentrated clay dispersions for a wide concentration range of externally added salt, is useful in our understanding of many geophysical phenomena that involve the salt induced aggregation of natural clay minerals.

  5. Sampling outdoor, resting Anopheles gambiae and other mosquitoes (Diptera: Culicidae) in western Kenya with clay pots.

    PubMed

    Odiere, M; Bayoh, M N; Gimnig, J; Vulule, J; Irungu, L; Walker, E

    2007-01-01

    Clay pots were analyzed as devices for sampling the outdoor resting fraction of Anopheles gambiae Giles (Diptera: Culicidae) and other mosquito species in a rural, western Kenya. Clay pots (Anopheles gambiae resting pots, herein AgREPOTs), outdoor pit shelters, indoor pyrethrum spray collections (PSC), and Colombian curtain exit traps were compared in collections done biweekly for nine intervals from April to June 2005 in 20 housing compounds. Of 10,517 mosquitoes sampled, 4,668 An. gambiae s.l. were sampled in total of which 63% were An. gambiae s.s. (46% female) and 37% were An. arabiensis (66% female). The clay pots were useful and practical for sampling both sexes of An. gambiae s.l. Additionally, 617 An. funestus (58% female) and 5,232 Culex spp. (males and females together) were collected. Temporal changes in abundance of An. gambiae s.l. were similarly revealed by all four sampling methods, indicating that the clay pots could be used as devices to quantify variation in mosquito population density. Dispersion patterns of the different species and sexes fit well the negative binomial distribution, indicating that the mosquitoes were aggregated in distribution. Aside from providing a useful sampling tool, the AgREPOT also may be useful as a delivery vehicle for insecticides or pathogens to males and females that enter and rest in them.

  6. 75 FR 4100 - Affirmative Fair Housing, Marketing (AFHM) Plan-Multifamily Housing, Affirmative Fair Housing...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-01-26

    ... URBAN DEVELOPMENT Affirmative Fair Housing, Marketing (AFHM) Plan-Multifamily Housing, Affirmative Fair Housing Marketing (AFHM) Plan-Single Family Housing and Affirmative Fair Housing Marketing (AFHM) Plan... forms to describe their intent for marketing to ensure that they meet the Fair Housing...

  7. Thermal analysis of selected illite and smectite clay minerals. Part I. Illite clay specimens

    NASA Astrophysics Data System (ADS)

    Earnest, C. M.

    The characterization of illite clay minerals by the use of the technique of differential thermal analysis (DTA), thermogravimetry (TG) and derivative thermogravimetry (DTG) is presented. This presentation is offered not only as a review of the thermal characteristics of this important group of clay materials but suggestions relative to the application of the thermal analysis techniques to contaminated illitic specimens; i.e., mineral mixtures, are included. Two commonly referenced illitic clay specimens, which have been widely distributed, were studied here. These were the American Petroleum Institute Reference Clay Specimen from Fithian, Illinois (API #35) and the Clay Mineral Society's Source Clay Specimen from Silver Hill, Montana (CMS-IMt). These clay specimens were studied using a modern computerized differential thermal analyzer which also contained a DSC mode of operation for peak energy assignment. Representative DTA thermal curves using both DTA and computerized DSC modes are given for both clay specimens. The effect of the variation of heating rate and sample size on the observed peak temperatures and resolution is demonstrated for both illite specimens.

  8. Improved poultry house

    SciTech Connect

    1983-01-01

    The relationship of energy and poultry production was explored in three areas: methane production from litter, broiler house insulation, and broiler house HVAC systems. The findings show that while a methane plant would not be popular with individual American poultry producers; the pay back in fuel and fertilizer, if the plant was located in close proximinity to the processing plant, would be favorable. Broiler house insulation has been dramatically improved since the outset of this study. Presently, all new installations in the survey area are the Environmental houses which are fully insulated. HVAC systems have had to keep pace with the introduction of better insulation. The new Environmental houses HVAC systems are fully automated and operating on a positive atmosphere principal. Ammonia and other problems have been kept in check while reducing air changes per house from a high of 7 per hour to as little as 3 per hour.

  9. Enchanted Clays: 44th Annual Meeting of the Clay Minerals Society (June 2007)

    SciTech Connect

    Randall T. Cygan

    2007-06-01

    “Enchanted Clays: 44th Annual Meeting of the Clay Minerals Society” was held in early June 2007 in beautiful and historic Santa Fe, New Mexico, USA. Santa Fe provided an idyllic location in the southwestern United States for the attendees to enjoy technical and social sessions while soaking up the diverse culture and wonderful climate of New Mexico—The Land of Enchantment. The meeting included a large and varied group of scientists, sharing knowledge and ideas, benefitting from technical interactions, and enjoying the wonderful historic and enchanted environs of Santa Fe. Including significant number of international scientists, the meeting was attended by approximately two hundred participants. The meeting included three days of technical sessions (oral and poster presentations), three days of field trips to clay and geological sites of northern New Mexico, and a full day workshop on the stabilization of carbon by clays. Details can be found at the meeting web site: www.sandia.gov/clay.

  10. Office of Telecommunications Policy; The White House Role in Domestic Communication.

    ERIC Educational Resources Information Center

    Columbia Univ., New York, NY. Network Project.

    In 1970, President Nixon created the White House Office of Telecommunications Policy (OTP) and appointed Clay T. Whitehead as its first director. This young office has attained influential power in the broad field of telecommunications and, some say, has jeopardized the independence of the public's communications custodian, the Federal…

  11. NASA Tech House

    NASA Technical Reports Server (NTRS)

    1977-01-01

    The NASA Technology Utilization House, called Tech House, was designed and constructed at NASA's Langley Research Center in Hampton, Virginia, to demonstrate new technology that is available or will be available in the next several years and how the application of aerospace technology could help advance the homebuilding industry. Solar energy use, energy and water conservation, safety, security, and cost were major considerations in adapting the aerospace technology to the construction of Tech House.

  12. House Resolutions of Inquiry

    DTIC Science & Technology

    2003-05-12

    14 Two years later, the House made another change to its rules governing resolutions of inquiry, requiring not merely a day’s delay but also...of Government “does not necessarily belong to the province of legislation. It does not profess to be asked for that object.”42 Second, if the House ...recognized that the power of impeachment gives the House “the right to investigate the conduct of all public officers under the Government . This is

  13. Organic or organometallic template mediated clay synthesis

    SciTech Connect

    Gregar, K.C.; Winans, R.E.; Botto, R.E.

    1992-12-31

    A method is given for incorporating diverse varieties of intercalants or templates directly during hydrothermal synthesis of clays such as hectorite or montmorillonite-type layer-silicate clays. For a hectorite layer-silicate clay, refluxing a gel of silica sol, magnesium hydroxide sol and LiF for 2 days with an organic or organometallic intercalant or template results in crystalline products containing either (a) organic dye molecules such as ethyl violet and methyl green, (b) dye molecules such as alcian blue based on a Cu(II)-phthalocyannine complex, or (c) transition metal complexes such as Ru(II)phenanthroline and Co(III)sepulchrate or (d) water-soluble porphyrins and metalloporphyrins. Montmorillonite-type clays are made by the method taught by US patent No. 3,887,454 issued to Hickson, June 13, 1975; however, a variety of intercalants or templates may be introduced. The intercalants or templates should have water-solubility, positive charge, and thermal stability under moderately basic (pH 9-10) aqueous reflux conditions or hydrothermal pressurized conditions for the montmorillonite-type clays.

  14. Organic or organometallic template mediated clay synthesis

    DOEpatents

    Gregar, K.C.; Winans, R.E.; Botto, R.E.

    1994-05-03

    A method is described for incorporating diverse varieties of intercalates or templates directly during hydrothermal synthesis of clays such as hectorite or montmorillonite-type layer-silicate clays. For a hectorite layer-silicate clay, refluxing a gel of silica sol, magnesium hydroxide sol and lithium fluoride for two days in the presence of an organic or organometallic intercalate or template results in crystalline products containing either (a) organic dye molecules such as ethyl violet and methyl green, (b) dye molecules such as alcian blue that are based on a Cu(II)-phthalocyannine complex, or (c) transition metal complexes such as Ru(II)phenanthroline and Co(III)sepulchrate or (d) water-soluble porphyrins and metalloporphyrins. Montmorillonite-type clays are made by the method taught by U.S. Pat. No. 3,887,454 issued to Hickson, Jun. 13, 1975; however, a variety of intercalates or templates may be introduced. The intercalates or templates should have (i) water-solubility, (ii) positive charge, and (iii) thermal stability under moderately basic (pH 9-10) aqueous reflux conditions or hydrothermal pressurized conditions for the montmorillonite-type clays. 22 figures.

  15. Organic or organometallic template mediated clay synthesis

    DOEpatents

    Gregar, Kathleen C.; Winans, Randall E.; Botto, Robert E.

    1994-01-01

    A method for incorporating diverse Varieties of intercalants or templates directly during hydrothermal synthesis of clays such as hectorite or montmorillonite-type layer-silicate clays. For a hectorite layer-silicate clay, refluxing a gel of silica sol, magnesium hydroxide sol and lithium fluoride for two days in the presence of an organic or organometallic intercalant or template results in crystalline products containing either (a) organic dye molecules such as ethyl violet and methyl green, (b) dye molecules such as alcian blue that are based on a Cu(II)-phthalocyannine complex, or (c) transition metal complexes such as Ru(II)phenanthroline and Co(III)sepulchrate or (d) water-soluble porphyrins and metalloporphyrins. Montmorillonite-type clays are made by the method taught by U.S. Pat. No. 3,887,454 issued to Hickson, Jun. 13, 1975; however, a variety of intercalants or templates may be introduced. The intercalants or templates should have (i) water-solubility, (ii) positive charge, and (iii) thermal stability under moderately basic (pH 9-10) aqueous reflux conditions or hydrothermal pressurized conditions for the montmorillonite-type clays.

  16. Mineral Acquisition from Clay by Budongo Forest Chimpanzees

    PubMed Central

    Reynolds, Vernon; Lloyd, Andrew W.; English, Christopher J.; Lyons, Peter; Dodd, Howard; Hobaiter, Catherine; Newton-Fisher, Nicholas; Mullins, Caroline; Lamon, Noemie; Schel, Anne Marijke; Fallon, Brittany

    2015-01-01

    Chimpanzees of the Sonso community, Budongo Forest, Uganda were observed eating clay and drinking clay-water from waterholes. We show that clay, clay-rich water, and clay obtained with leaf sponges, provide a range of minerals in different concentrations. The presence of aluminium in the clay consumed indicates that it takes the form of kaolinite. We discuss the contribution of clay geophagy to the mineral intake of the Sonso chimpanzees and show that clay eaten using leaf sponges is particularly rich in minerals. We show that termite mound soil, also regularly consumed, is rich in minerals. We discuss the frequency of clay and termite soil geophagy in the context of the disappearance from Budongo Forest of a formerly rich source of minerals, the decaying pith of Raphia farinifera palms. PMID:26218593

  17. Mineral Acquisition from Clay by Budongo Forest Chimpanzees.

    PubMed

    Reynolds, Vernon; Lloyd, Andrew W; English, Christopher J; Lyons, Peter; Dodd, Howard; Hobaiter, Catherine; Newton-Fisher, Nicholas; Mullins, Caroline; Lamon, Noemie; Schel, Anne Marijke; Fallon, Brittany

    2015-01-01

    Chimpanzees of the Sonso community, Budongo Forest, Uganda were observed eating clay and drinking clay-water from waterholes. We show that clay, clay-rich water, and clay obtained with leaf sponges, provide a range of minerals in different concentrations. The presence of aluminium in the clay consumed indicates that it takes the form of kaolinite. We discuss the contribution of clay geophagy to the mineral intake of the Sonso chimpanzees and show that clay eaten using leaf sponges is particularly rich in minerals. We show that termite mound soil, also regularly consumed, is rich in minerals. We discuss the frequency of clay and termite soil geophagy in the context of the disappearance from Budongo Forest of a formerly rich source of minerals, the decaying pith of Raphia farinifera palms.

  18. Polymer based nanocomposites with nanofibers and exfoliated clay

    NASA Technical Reports Server (NTRS)

    Meador, Michael A.; Reneker, Darrell H.

    2005-01-01

    Polymer solutions, containing clay sheets, were electrospun into nanofibers and microfibers that contained clay sheets inside. Controllable removal of polymer by plasma etching from the surface of fibers revealed the arrangement of clay. The shape, flexibility, size distribution and arrangement of clay sheets were observed by transmission and scanning electron microscopy. The clay sheets were partially aligned in big fibers with normal direction of clay sheets perpendicular to fiber axis. Crumpling of clay sheets inside fibers was observed when the fiber diameter was comparable to the lateral size of clay sheets. Single sheets of clay were observed both by catching clay sheets dispersed in water with electrospun nanofiber mats and by the deliberate removal of most of the polymer in the fibers. Thin, flexible gas barrier films, that are reasonably strong, were assembled from clay sheets and polymer nanofibers. Structure of composite films was characterized with scanning electron microscopy. Continuous film of clay sheets were physically attached to the surface of fiber mats. Spincoating film of polymer and clay sheets was reinforced by electrospun fiber scaffold. Certain alignment of clay sheets was observed in the vicinity of fibers.

  19. 4. View of houses from Port Ludlow, houses no. 69 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    4. View of houses from Port Ludlow, houses no. 69 and 70, facing southwest. House no. 69 in foreground, house no. 70 in background. - Houses Moved from Port Ludlow, Various Addresses (moved from Port Ludlow, WA), Port Gamble, Kitsap County, WA

  20. Clay Improvement with Burned Olive Waste Ash

    PubMed Central

    Mutman, Utkan

    2013-01-01

    Olive oil is concentrated in the Mediterranean basin countries. Since the olive oil industries are incriminated for a high quantity of pollution, it has become imperative to solve this problem by developing optimized systems for the treatment of olive oil wastes. This study proposes a solution to the problem. Burned olive waste ash is evaluated for using it as clay stabilizer. In a laboratory, bentonite clay is used to improve olive waste ash. Before the laboratory, the olive waste is burned at 550°C in the high temperature oven. The burned olive waste ash was added to bentonite clay with increasing 1% by weight from 1% to 10%. The study consisted of the following tests on samples treated with burned olive waste ash: Atterberg Limits, Standard Proctor Density, and Unconfined Compressive Strength Tests. The test results show promise for this material to be used as stabilizer and to solve many of the problems associated with its accumulation. PMID:23766671

  1. Quality evaluation of processed clay soil samples

    PubMed Central

    Steiner-Asiedu, Matilda; Harrison, Obed Akwaa; Vuvor, Frederick; Tano-Debrah, Kwaku

    2016-01-01

    Introduction This study assessed the microbial quality of clay samples sold on two of the major Ghanaian markets. Methods The study was a cross-sectional assessing the evaluation of processed clay and effects it has on the nutrition of the consumers in the political capital town of Ghana. The items for the examination was processed clay soil samples. Results Staphylococcus spp and fecal coliforms including Klebsiella, Escherichia, and Shigella and Enterobacterspp were isolated from the clay samples. Samples from the Kaneshie market in Accra recorded the highest total viable counts 6.5 Log cfu/g and Staphylococcal count 5.8 Log cfu/g. For fecal coliforms, Madina market samples had the highest count 6.5 Log cfu/g and also recorded the highest levels of yeast and mould. For Koforidua, total viable count was highest in the samples from the Zongo market 6.3 Log cfu/g. Central market samples had the highest count of fecal coliforms 4.6 Log cfu/g and yeasts and moulds 6.5 Log cfu/g. “Small” market recorded the highest staphylococcal count 6.2 Log cfu/g. The water activity of the clay samples were low, and ranged between 0.65±0.01 and 0.66±0.00 for samples collected from Koforidua and Accra respectively. Conclusion The clay samples were found to contain Klebsiella spp. Escherichia, Enterobacter, Shigella spp. staphylococcus spp., yeast and mould. These have health implications when consumed. PMID:27642456

  2. Method of treating clay to improve its whiteness

    SciTech Connect

    Young, R. H.; Brooks, R. L.; Morris, H. H.

    1985-01-08

    A method of treating a clay to remove therefrom titanium mineral impurities comprising the steps of mixing an aqueous slurry of said clay having a high solids content with an activator and a collector for the titanium mineral impurities; conditioning the aqueous clay slurry at said high solids content for a time sufficient to dissipate therein at least 25 horsepower hours of energy per ton of solids; adding to the conditioned aqueous clay slurry a polyacrylate salt deflocculant; subjecting the conditioned aqueous clay slurry undiluted containing the polyacrylate salt deflocculant to a froth flotation process and removing the titanium impurities with the froth; and recovering clay having a reduced titanium minerals impurities content.

  3. Effect of aging on rheology of ball clay suspensions

    NASA Astrophysics Data System (ADS)

    Tonthai, Tienchai

    2002-01-01

    The behaviors of clay-water suspensions such as deflocculation or rheological properties are not constant but change with time. Aging has been recognized for changing the rheological properties of clay suspensions. This work provided information about the effects of the moisture contents in ball clay lumps and clay air exposure time on their processability. Dynamic oscillatory rheometry using a vane-in-cup geometry was used to characterize the rheological behavior of ball clay suspensions in terms of elastic modulus, viscous modulus and yield stress as a function of aging time. A light scattering size analyzer was used to examine the agglomerate size distribution of ball clay suspensions which affected the rheological behavior. Soluble ion release (both cations and anions) in the filtrate of suspensions was measured by ion chromatography. Low and high lignitic ball clay suspensions were dispersed with sodium silicate (Na2SiO3) or sodium polyacrylate at specific gravity 1.3 and 1.6 in two dispersion states: fully deflocculated (minimum viscosity) and under deflocculated. Suspensions prepared using freshly mined ball clays required more dispersant than suspensions prepared using dry ball clays to achieve minimum viscosity due to a difference in agglomerate size distribution. The agglomerate size distribution of suspensions prepared using dry clays was broader than that of suspensions prepared using freshly mined clays. In suspensions prepared using freshly mined clays, there were many uniformly small agglomerates having loose water inside, while in suspensions prepared using dry clays, the capillary effect and bonding between clay particles resulting from drying broke clay aggregates apart into agglomerate structures composed of a few to many clay particles. For suspensions prepared using dry clays after one day suspension aging, the elastic modulus and yield stress decreased due to the change in agglomerate size distribution of suspensions but increased for

  4. Ostwald ripening of clays and metamorphic minerals

    USGS Publications Warehouse

    Eberl, D.D.; Srodon, J.; Kralik, M.; Taylor, B.E.; Peterman, Z.E.

    1990-01-01

    Analyses of particle size distributions indicate that clay minerals and other diagenetic and metamorphic minerals commonly undergo recrystallization by Ostwald ripening. The shapes of their particle size distributions can yield the rate law for this process. One consequence of Ostwald ripening is that a record of the recrystallization process is preserved in the various particle sizes. Therefore, one can determine the detailed geologic history of clays and other recrystallized minerals by separating, from a single sample, the various particle sizes for independent chemical, structural, and isotopic analyses.

  5. Ostwald ripening of clays and metamorphic minerals.

    PubMed

    Eberl, D D; Sacuterodonacute, J; Kralik, M; Taylor, B E; Peterman, Z E

    1990-04-27

    Analyses of particle size distributions indicate that clay minerals and other diagenetic and metamorphic minerals commonly undergo recrystallization by Ostwald ripening. The shapes of their particle size distributions can yield the rate law for this process. One consequence of Ostwald ripening is that a record of the recrystallization process is preserved in the various particle sizes. Therefore, one can determine the detailed geologic history of clays and other recrystallized minerals by separating, from a single sample, the various particle sizes for independent chemical, structural, and isotopic analyses.

  6. Clay Fabric of Gassy Submarine Sediments

    DTIC Science & Technology

    1991-01-01

    28°54󈧑 ° 89°30󈧎" 38 125 11.9 39 559 81 *The Lambert coordinates of Core B- I A: X = 2,594,001; Y = 82,970. The Lambert coordinates of Core B-2... X = 2,585,823: Y = 90,832. Location fluid before critical point drying under equivalent in situ down- hole pressure, was constructed. The detailed...it appeared that Clay Fabric vs. Degassing ime with a specimen size of 7 x 7 x 20 mm the clay fabric in the central portion of a specimen will not

  7. Chlorination of alumina in kaolinitic clay

    NASA Astrophysics Data System (ADS)

    Grob, B.; Richarz, W.

    1984-09-01

    The chlorination of alumina in kaolinitic clay with Cl2 and CO gas mixtures was studied gravimetrically. The effects of the calcination method and of NaCl addition on the reactivity of the clay were examined. Fast reaction rates were achieved only with samples previously exposed to a sulfating treatment. Optimum conditions, with maximum yield and selectivity to A1C13 and minimum SiO2 conversion, were found between 770 and 970 K. At higher temperatures the SiCl4 formed poisons the reactive alumina surface by selective chemisorption with a marked decrease of the reaction rate.

  8. Numerical Modelling of Embankment on Soft Clay

    NASA Astrophysics Data System (ADS)

    Nujid, M. M.; Taha, M. R.

    2016-07-01

    This paper aims to predict deformation of embankment on soft clay of Muar. The prediction performance focusing on displacement at critical fill height of 5.5 m. The study was based on reported result in 1992. With the aid of computer intelligence, the advanced constitutive soil models could be adopted to analyze the soft clay behavior. The COMSOL Multiphysics (v4.4) has been used to simulate the problem with coupled physics available in the software. The vertical displacements are in good agreement close to published result.

  9. Quick clay and landslides of clayey soils.

    PubMed

    Khaldoun, Asmae; Moller, Peder; Fall, Abdoulaye; Wegdam, Gerard; De Leeuw, Bert; Méheust, Yves; Otto Fossum, Jon; Bonn, Daniel

    2009-10-30

    We study the rheology of quick clay, an unstable soil responsible for many landslides. We show that above a critical stress the material starts flowing abruptly with a very large viscosity decrease caused by the flow. This leads to avalanche behavior that accounts for the instability of quick clay soils. Reproducing landslides on a small scale in the laboratory shows that an additional factor that determines the violence of the slides is the inhomogeneity of the flow. We propose a simple yield stress model capable of reproducing the laboratory landslide data, allowing us to relate landslides to the measured rheology.

  10. Geotechnical characterization of mined clay from Appalachian Ohio: challenges and implications for the clay mining industry.

    PubMed

    Moran, Anthony R; Hettiarachchi, Hiroshan

    2011-07-01

    Clayey soil found in coal mines in Appalachian Ohio is often sold to landfills for constructing Recompacted Soil Liners (RSL) in landfills. Since clayey soils possess low hydraulic conductivity, the suitability of mined clay for RSL in Ohio is first assessed by determining its clay content. When soil samples are tested in a laboratory, the same engineering properties are typically expected for the soils originated from the same source, provided that the testing techniques applied are standard, but mined clay from Appalachian Ohio has shown drastic differences in particle size distribution depending on the sampling and/or laboratory processing methods. Sometimes more than a 10 percent decrease in the clay content is observed in the samples collected at the stockpiles, compared to those collected through reverse circulation drilling. This discrepancy poses a challenge to geotechnical engineers who work on the prequalification process of RSL material as it can result in misleading estimates of the hydraulic conductivity of the samples. This paper describes a laboratory investigation conducted on mined clay from Appalachian Ohio to determine how and why the standard sampling and/or processing methods can affect the grain-size distributions. The variation in the clay content was determined to be due to heavy concentrations of shale fragments in the clayey soils. It was also concluded that, in order to obtain reliable grain size distributions from the samples collected at a stockpile of mined clay, the material needs to be processed using a soil grinder. Otherwise, the samples should be collected through drilling.

  11. Reducing the Cation Exchange Capacity of Lithium Clay to Form Better Dispersed Polymer-Clay Nanocomposites

    NASA Technical Reports Server (NTRS)

    Liang, Maggie

    2004-01-01

    Polymer-clay nanocomposites have exhibited superior strength and thermo- oxidative properties as compared to pure polymers for use in air and space craft; however, there has often been difficulty completely dispersing the clay within the matrices of the polymer. In order to improve this process, the cation exchange capacity of lithium clay is first lowered using twenty-four hour heat treatments of no heat, 130 C, 150 C, or 170 C to fixate the lithium ions within the clay layers so that they are unexchangeable. Generally, higher temperatures have generated lower cation exchange capacities. An ion exchange involving dodecylamine, octadecylamine, or dimethyl benzidine (DMBZ) is then employed to actually expand the clay galleries. X-ray diffraction and transmission electron microscopy can be used to determine whether the clay has been successfully exfoliated. Finally, resins of DMBZ with clay are then pressed into disks for characterization using dynamic mechanical analyzer and oven- aging techniques in order to evaluate their glass transition, modulus strength, and thermal-oxidative stability in comparison to neat DMBZ. In the future, they may also be tested as composites for flexural and laminar shear strength.

  12. Housing Assistance Efficiency Act

    THOMAS, 113th Congress

    Rep. Peters, Scott H. [D-CA-52

    2013-07-23

    12/03/2014 Received in the Senate and Read twice and referred to the Committee on Banking, Housing, and Urban Affairs. (All Actions) Tracker: This bill has the status Passed HouseHere are the steps for Status of Legislation:

  13. Special Report: College Housing.

    ERIC Educational Resources Information Center

    Abramson, Paul

    2003-01-01

    Responses of chief housing officers of 118 4-year colleges and universities to a survey focusing on costs, security, policies, and preferences provide a picture of college housing. More than 67% of respondents say that their colleges are planning to build more residential space. (SLD)

  14. Multiple pump housing

    DOEpatents

    Donoho, II, Michael R.; Elliott, Christopher M.

    2010-03-23

    A fluid delivery system includes a first pump having a first drive assembly, a second pump having a second drive assembly, and a pump housing. At least a portion of each of the first and second pumps are located in the housing.

  15. More Than a House.

    ERIC Educational Resources Information Center

    Simonelli, Richard

    1996-01-01

    For 14 years, Mountain Outreach, a program at Cumberland College (Williamsburg, Kentucky), has enabled college students to participate in community service projects. Recently, 35 students traveled to New Mexico to build a house for a Navajo elder who was unable to obtain adequate housing. Participants discuss their learning experiences and their…

  16. Ndebele Inspired Houses

    ERIC Educational Resources Information Center

    Rice, Nicole

    2012-01-01

    The house paintings of the South African Ndebele people are more than just an attempt to improve the aesthetics of a community; they are a source of identity and significance for Ndebele women. In this article, the author describes an art project wherein students use the tradition of Ndebele house painting as inspiration for creating their own…

  17. Boltless Seal for Electronic Housings

    NASA Technical Reports Server (NTRS)

    Dawe, R. H.; Evans, J. T.

    1982-01-01

    Spring clips seal housings for electronic circuitry, preventing electromagnetic interference from entering or leaving housings. Clips also keep dust out of housing. Since no bolts are used, housing can be opened quickly; unlike bolts, clips can be used on thin-walled housing. Seal was developed for an X-band array amplifier.

  18. Housing Survey. Campus Housing: Finding the Balance

    ERIC Educational Resources Information Center

    O'Connor, Shannon

    2016-01-01

    Depending on where you look for statistics, the number of students enrolling in colleges or universities is increasing, decreasing or remaining the about the same. Regardless of those trends, campus housing is a marketing tool for institutions looking to draw students to and keep them on campus. Schools need to offer sufficient beds and…

  19. 1. HOUSE, VIEW TO NORTHEAST, SUMMER KITCHEN AND SMOKE HOUSE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. HOUSE, VIEW TO NORTHEAST, SUMMER KITCHEN AND SMOKE HOUSE ARE IN THE BACKGROUND - Kiel Farmstead, House, East side State Route 4, one half mile south of U.S. Route 64, Mascoutah, St. Clair County, IL

  20. Transport of Organic Solutes in Clay Formations

    EPA Science Inventory

    The research is a pilot investigation for the SERDP (Strategic Environmental Research and Development Program, DoD) founded project, Impact of Clay-DNAPL Interactions on Transport and Storage of Chlorinated Solvents in Low Permeability Zones, from 2010-2012. The report tries to s...

  1. Classroom Instruction: The Influences of Marie Clay

    ERIC Educational Resources Information Center

    McNaughton, Stuart

    2014-01-01

    Marie Clay's body of work has influenced classroom instruction in direct and indirect ways, through large overarching themes in our pedagogical content knowledge as well as specific smart practices. This paper focuses on her the contributions to our thinking about instruction which come from two broad theoretical concepts; emergent literacy…

  2. HYDRAULIC CONDUCTIVITY OF THREE GEOSYNTHETIC CLAY LINERS

    EPA Science Inventory

    The hydraulic conductivity of three 2.9 m2 (32 sq ft) geosynthetic clay liners (GCLs) was measured. Tests were performed on individual sheets of the GCLs, on overlapped pieces of GCLs, and on composite liners consisting of a punctured geomembrane overlying a GCL. Hyd...

  3. Diffusion in Clay Layers and Groundwater Remediation

    EPA Science Inventory

    In a collaborative SERDP-funded study, researchers from the Air Force Institute of Technology, the U.S. Environmental Protection Agency, and the University of Michigan developed a numerical model that simulates the enhanced transport of CAHs into and out of low permeability clay ...

  4. Bauxite washing for the removal of clay

    NASA Astrophysics Data System (ADS)

    Ahmad, Ishaq; Hartge, Ernst-Ulrich; Werther, Joachim; Wischnewski, Reiner

    2014-11-01

    Clay impurities associated with bauxite negatively affect the Bayer process for alumina production. These impurities should be removed as far as possible by a beneficiation technique before the ore is used as feed for the Bayer process. In this current investigation, bauxite washing was conducted in the laboratory. Bauxite washing is a physical process that causes the disintegration and deagglomeration of the clay matrix, and bauxite is liberated from the clay (mainly rich in silica). Subsequently, separation occurs with the assistance of wet screening at a predetermined cut size. Three techniques were investigated in the laboratory: drum washing, water-jet washing, and ultrasonic washing. Various operating parameters were investigated for drum washing and water-jet washing, including materials retention time, drum rotation speed, solid concentration, water-jet spray duration, pressure, and height. We concluded that the retention time of bauxite inside the drum at a solid concentration of 55wt% and a drum rotation speed of 31 r/min is the dominant parameter for the removal of clay from the bauxite surface.

  5. Palaeoceanographic approach to the Kimmeridge Clay Formation

    SciTech Connect

    Miller, R.G. )

    1988-08-01

    The Upper Jurassic/Lower Cretaceous Kimmeridge Clay Formation (KCF) is northern Europe's premier source rock and can be understood using a new but relatively simple oceanographic model. This explains or accommodates most current observations about the KCF and its depositional environment and draws upon paleogeographic, paleoclimatic, geochemical, sedimentological, and paleontological evidence.

  6. Calm, Cool, and Comfortable in Clay

    ERIC Educational Resources Information Center

    Stylianou, Xanthippi Cynthia

    2010-01-01

    The author's fourth-grade students had just finished a drawing unit that focused on the human figure. Projects included charcoal gesture drawings and chalk manikin drawings in chiaroscuro. She wanted to integrate a new medium for students to continue their study of the human figure. Since students are always excited to work with clay, making clay…

  7. Clay Corner: Recreating Chinese Bronze Vessels.

    ERIC Educational Resources Information Center

    Gamble, Harriet

    1998-01-01

    Presents a lesson where students make faux Chinese bronze vessels through slab or coil clay construction after they learn about the history, function, and design of these vessels. Utilizes a variety of glaze finishes in order to give the vessels an aged look. Gives detailed guidelines for creating the vessels. (CMK)

  8. Clay particle retention in small constructed wetlands.

    PubMed

    Braskerud, B C

    2003-09-01

    Constructed wetlands (CWs) can be used to mitigate non-point source pollution from arable fields. Previous investigations have shown that the relative soil particle retention in small CWs increases when hydraulic load increases. This paper investigates why this phenomenon occurs, even though common retention models predict the opposite, by studying clay and silt particle retention in two Norwegian CWs. Retention was measured with water flow proportional sampling systems in the inlet and outlet of the wetlands, and the texture of the suspended solids was analyzed. The surface area of the CWs was small compared to the watershed area (approximately 0.07%), giving high average hydraulic loads (1.1 and 2.0 md(-1)). One of the watersheds included only old arable land, whereas the other included areas with disturbed topsoil after artificial land leveling. Clay particle retention was 57% for the CW in the first watershed, and 22% for the CW in the disturbed watershed. The different behavior of the wetlands could be due to differences in aggregate size and stability of the particles entering the wetlands. Results showed that increased hydraulic loads did affect CW retention negatively. However, as runoff increased, soil particles/aggregates with higher sedimentation velocities entered the CWs (e.g., the clay particles behaved as silt particles). Hence, clay particle settling velocity is not constant as assumed in many prediction models. The net result was increased retention.

  9. Swelling transition of a clay induced by heating

    PubMed Central

    Hansen, E. L.; Hemmen, H.; Fonseca, D. M.; Coutant, C.; Knudsen, K. D.; Plivelic, T. S.; Bonn, D.; Fossum, J. O.

    2012-01-01

    Clays are of paramount importance for soil stability, but also in applications ranging from oil recovery to composites and hydrogels. Generically, clays are divided into two subclasses: macroscopically swelling, ‘active’ clays that have the capacity for taking up large amounts of water to form stable gels, and ‘passive’ or non-swelling clays; the former stabilize soils whereas the latter are known to lead to landslides. However, it has been unclear so far what mechanisms underlie clay swelling. Here, we report the first observation of a temperature-induced transition from a passive to an active, swelling clay. We propose a simple description of the swelling transition; while net attractive interactions are dominant at low temperatures so that the clay particles remain attached to each other in stacks, at higher temperatures it is energetically favourable for the clay to swell due to the entropy that is gained by counterions which are liberated during swelling. PMID:22943004

  10. HPLC Analysis of Colorants Migrated from Children's Modeling Clays.

    PubMed

    Kishi, Eri; Ozaki, Asako; Ooshima, Tomoko; Yamano, Tetsuo

    2016-01-01

    A method using high-performance liquid chromatograph (HPLC) was developed for the identification of colorants migrated from colored modeling clays, which are popular toys for children. Twelve permitted dyes and 25 non-permitted dyes were analyzed in 20 clays (10 wheat clays, 2 rice clays, 2 corn clays, 3 paper clays and 3 resin clays). As a result, 13 products which were labeled for children's use (under 6 years old) met the specifications of the Japanese Food Sanitation Law, while non-permitted colorants were eluted from 2 products. In additon, unknown colorants were eluted from 3 products for people over 6 years old, although these are not covered by the Japanese regulation. It was suggested that some type of clays contained pigments, which are generally used in printing ink and plastics.

  11. INTERIOR VIEW ON SEVENTH FLOOR AT CORNER OF CLAY AND ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    INTERIOR VIEW ON SEVENTH FLOOR AT CORNER OF CLAY AND 15TH STREETS. LARGE SECTIONS OF DEMOLISHED SHEET METAL CORNICE FROM BUILDING EXTERIOR VISIBLE FOREGROUND - John Breuner & Company Building, 1515 Clay Street, Oakland, Alameda County, CA

  12. INTERIOR VIEW ON MEZZANINE ALONG EAST (CLAY STREET) FRONT FACING ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    INTERIOR VIEW ON MEZZANINE ALONG EAST (CLAY STREET) FRONT FACING OAKLAND CITY HALL. TYPICAL INTERIOR CONDITIONS OF PARTIAL DEMOLITION; WINDOWS, WINDOW FRAMES, SUSPENDED CEILING, AND MOVABLE PARTITION WALLS REMOVED - John Breuner & Company Building, 1515 Clay Street, Oakland, Alameda County, CA

  13. Deformation mechanisms in experimentally deformed Boom Clay

    NASA Astrophysics Data System (ADS)

    Desbois, Guillaume; Schuck, Bernhard; Urai, Janos

    2016-04-01

    Bulk mechanical and transport properties of reference claystones for deep disposal of radioactive waste have been investigated since many years but little is known about microscale deformation mechanisms because accessing the relevant microstructure in these soft, very fine-grained, low permeable and low porous materials remains difficult. Recent development of ion beam polishing methods to prepare high quality damage free surfaces for scanning electron microscope (SEM) is opening new fields of microstructural investigation in claystones towards a better understanding of the deformation behavior transitional between rocks and soils. We present results of Boom Clay deformed in a triaxial cell in a consolidated - undrained test at a confining pressure of 0.375 MPa (i.e. close to natural value), with σ1 perpendicular to the bedding. Experiments stopped at 20 % strain. As a first approximation, the plasticity of the sample can be described by a Mohr-Coulomb type failure envelope with a coefficient of cohesion C = 0.117 MPa and an internal friction angle ϕ = 18.7°. After deformation test, the bulk sample shows a shear zone at an angle of about 35° from the vertical with an offset of about 5 mm. We used the "Lamipeel" method that allows producing a permanent absolutely plane and large size etched micro relief-replica in order to localize and to document the shear zone at the scale of the deformed core. High-resolution imaging of microstructures was mostly done by using the BIB-SEM method on key-regions identified after the "Lamipeel" method. Detailed BIB-SEM investigations of shear zones show the following: the boundaries between the shear zone and the host rock are sharp, clay aggregates and clastic grains are strongly reoriented parallel to the shear direction, and the porosity is significantly reduced in the shear zone and the grain size is smaller in the shear zone than in the host rock but there is no evidence for broken grains. Comparison of microstructures

  14. Housing And Mounting Structure

    DOEpatents

    Anderson, Gene R.; Armendariz, Marcelino G.; Baca, Johnny R.F.; Bryan, Robert P.; Carson, Richard F.; Duckett, III, Edwin B.; McCormick, Frederick B.; Miller, Gregory V.; Peterson, David W.; Smith, Terrance T.

    2005-03-08

    This invention relates to an optical transmitter, receiver or transceiver module, and more particularly, to an apparatus for connecting a first optical connector to a second optical connector. The apparatus comprises: (1) a housing having at least a first end and at least a second end, the first end of the housing capable of receiving the first optical connector, and the second end of the housing capable of receiving the second optical connector; (2) a longitudinal cavity extending from the first end of the housing to the second end of the housing; and (3) an electromagnetic shield comprising at least a portion of the housing. This invention also relates to an apparatus for housing a flexible printed circuit board, and this apparatus comprises: (1) a mounting structure having at least a first surface and a second surface; (2) alignment ridges along the first and second surfaces of the mounting structure, the alignment ridges functioning to align and secure a flexible printed circuit board that is wrapped around and attached to the first and second surfaces of the mounting structure; and (3) a series of heat sink ridges adapted to the mounting structure, the heat sink ridges functioning to dissipate heat that is generated from the flexible printed circuit board.

  15. Glowing clay: Real time tracing using a suite of novel clay based fluorescent tracers

    NASA Astrophysics Data System (ADS)

    Hardy, Robert; Quinton, John; Pates, Jackie; Coogan, Mike

    2015-04-01

    Clay is one of the most mobile fractions of soil due to its small particle size. It is also known to sorb many chemicals, such as nutrients (notably phosphorus), agrochemicals and heavy metals. The movement of clay is therefore linked with the transport and fate of these substances. A novel fluorescent clay tracing suite has been produced, together with an imaging technique. This suite consists of qualitative clay tracers, using rhodamine based fluorophores, and quantitative clay tracers, using metal based fluorophores. Efforts have also been made to allow integration of commercially available tracers, which are silt and sand sized. The clay tracers exploit the high affinity that montmorillonite has for Rhodamine B and Ru(bpy)3. This allows for an extremely thin layer of the fluorophore to be sorbed onto the clay's surface, in much that same way as materials in the natural environment will bind to clay. The tracer that is produced retains key chemical and physical properties of clay, such as size, shape and density. The retention of these micro-properties results in the retention of macro-properties, such as tendency to aggregate and cracking on drying. Imaging techniques have been developed to analyse these tracers. The imaging system uses diffused laser light to excite the tracer and a modified DSLR camera to image the soil surface. The images have been compiled into a time lapse video showing the movement of clay over the course of a rainfall event. This is the first time that the quantitative movement of clay has been recorded over a soil surface in real time. 4D data can be extracted from the images allowing the spatial location and intensity of tracer to be monitored over time, with mm precision and on the timescale of seconds. As the system can also work with a commercial tracer it is possible to investigate the movement of particles of almost any size and over a range of scales from soil box to hillside. This allows users to access this technique without

  16. Altered phase model for polymer clay nanocomposites.

    PubMed

    Sikdar, Debashis; Pradhan, Shashindra M; Katti, Dinesh R; Katti, Kalpana S; Mohanty, Bedabibhas

    2008-05-20

    This paper describes a multiscale approach used to model polymer clay nanocomposites (PCNs) based on a new altered phase concept. Constant-force steered molecular dynamics (SMD) is used to evaluate nanomechanical properties of the constituents of intercalated clay units in PCNs, which were used in the finite element model. Atomic force microscopy and nanoindentation techniques provided additional input to the finite element method (FEM) model. FEM is used to construct a representative PCN model that simulates the composite response of intercalated clay units and the surrounding polymer matrix. From our simulations we conclude that, in order to accurately predict mechanical response of PCNs, it is necessary to take into account the molecular-level interactions between constituents of PCN, which are responsible for the enhanced nanomechanical properties of PCNs. This conclusion is supported by our previous finding that there is a change in crystallinity of polymeric phase due to the influence of intercalated clay units. The extent of altered polymeric phase is obtained from observations of a zone of the altered polymeric phase surrounding intercalated clay units in the "phase image" of PCN surface, obtained using an atomic force microscope (AFM). An accurate FEM model of PCN is constructed that incorporates the zone of the altered polymer. This model is used to estimate elastic modulus of the altered polymer. The estimated elastic modulus for the altered polymer is 4 to 5 times greater than that of pure polymer. This study indicates that it is necessary to take into account molecular interactions between constituents in nanocomposites due to the presence of altered phases, and furthermore provides us with a new direction for the modeling and design of nanocomposites.

  17. Clays and clay minerals in Bikaner: Sources, environment pollution and management

    NASA Astrophysics Data System (ADS)

    Gayatri, Sharma; Anu, Sharma

    2016-05-01

    Environmental pollution can also be caused by minerals which include natural as well as human activities. Rapid urbanization, consumerist life style, anthropogenic deeds are increasing environmental pollution day by day. Fluctuation in our ecosystem or polluted environment leads to many diseases and shows adverse effects on living organisms. The main aim of this paper is to highlight the environmental pollution from clays and clay minerals and their mitigation..

  18. Universal design in housing.

    PubMed

    Mace, R L

    1998-01-01

    Universal design in housing is a growing and beneficial concept. It is subtle in its differences from barrier-free, accessible, and industry standard housing. Accessibility standards and codes have not mandated universal design and do not apply to most housing. Universal design exceeds their minimum specifications for accessible design and results in homes that are usable by and marketable to almost everyone. Universal homes avoid use of special assistive technology devices and, instead, incorporate consumer products and design features that are easily usable and commonly available.

  19. Theoretical and experimental investigations on the structures of purified clay and acid-activated clay

    NASA Astrophysics Data System (ADS)

    Yang, Tao; Wen, Xiao-Dong; Li, Junfen; Yang, Liming

    2006-07-01

    The purified and acidified montmorillonite clay were characterized by XRD, BET and TPD. These results show that acidified clay is provided with more surface area and acid sites. For NH 3-TPD, molecular NH 3 desorption on purified clay and acidified clay occurs at temperatures with 873 and 1000 K, respectively. It is shown for the existence for strong acid sites. By two reactions of the tetrahydropyranylation of n-propanol and the esterification of cyclo-2-pentene with acetic acid, it is shown that the acidified clay displays better catalytic activity for above two organic reactions. By density-functional theory (DFT) method, we have analyzed the structures of different substituted montmorillonite and the effect sorption behavior of Na + in different montmorillonite models. The result shows that the process of substitution will occur apart from octahedral aluminums. The adsorption of NH 3 on clay surfaces have been investigated using TPD and DFT. This is shown that acid sites locate at round the octahedral aluminums, and substitution of Al 3+ for tetrahedral Si will be favorable to NH 3 adsorption.

  20. FACING NORTH ALONG CLAY STREET, SHOWING BUILDINGS ON THE WEST ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    FACING NORTH ALONG CLAY STREET, SHOWING BUILDINGS ON THE WEST SIDE OF CLAY STREET, FROM LEFT TO RIGHT: JOHN BREUNER AND COMPANY BUILDING (FOREGROUND), HOTEL TOURAINE (MIDDLE), AND THE PACIFIC GAS AND ELECTRIC CO. BUILDING - John Breuner & Company Building, 1515 Clay Street, Oakland, Alameda County, CA

  1. Life Cycle Greenhouse Gas Emissions and Energy Analysis of Passive House with Variable Construction Materials

    NASA Astrophysics Data System (ADS)

    Baďurová, Silvia; Ponechal, Radoslav; Ďurica, Pavol

    2013-11-01

    The term "passive house" refers to rigorous and voluntary standards for energy efficiency in a building, reducing its ecological footprint. There are many ways how to build a passive house successfully. These designs as well as construction techniques vary from ordinary timber constructions using packs of straw or constructions of clay. This paper aims to quantify environmental quality of external walls in a passive house, which are made of a timber frame, lightweight concrete blocks and sand-lime bricks in order to determine whether this constructional form provides improved environmental performance. Furthermore, this paper assesses potential benefit of energy savings at heating of houses in which their external walls are made of these three material alternatives. A two storey residential passive house, with floorage of 170.6 m2, was evaluated. Some measurements of air and surface temperatures were done as a calibration etalon for a method of simulation.

  2. Hood River Passive House

    SciTech Connect

    Hales, D.

    2013-03-01

    The Hood River Passive Project was developed by Root Design Build of Hood River Oregon using the Passive House Planning Package (PHPP) to meet all of the requirements for certification under the European Passive House standards. The Passive House design approach has been gaining momentum among residential designers for custom homes and BEopt modeling indicates that these designs may actually exceed the goal of the U.S. Department of Energy's (DOE) Building America program to reduce home energy use by 30%-50% (compared to 2009 energy codes for new homes). This report documents the short term test results of the Shift House and compares the results of PHPP and BEopt modeling of the project.

  3. Cinemicrographic specimen housing

    NASA Technical Reports Server (NTRS)

    Wilkins, J. R.

    1979-01-01

    Housing used to observe gravitation effects on specimens embedded in support media, such as agar, supports microbial specimens vertically for time-lapsed cinemicrographic studies. Procedure cannot be performed with conventional microscopes which see specimens in horizontal plane only.

  4. Gingerbread-House Geometry.

    ERIC Educational Resources Information Center

    Emenaker, Charles E.

    1999-01-01

    Describes a sixth-grade interdisciplinary geometry unit based on Charles Dickens's "A Christmas Carol". Focuses on finding area, volume, and perimeter, and working with estimation, decimals, and fractions in the context of making gingerbread houses. (ASK)

  5. Rotating housing turbine

    DOEpatents

    Allouche, Erez; Jaganathan, Arun P.

    2016-10-11

    The invention is a new turbine structure having a housing that rotates. The housing has a sidewall, and turbine blades are attached to a sidewall portion. The turbine may be completely open in the center, allowing space for solids and debris to be directed out of the turbine without jamming the spinning blades/sidewall. The turbine may be placed in a generator for generation of electrical current.

  6. 2. Keeper's house, light tower and oil house, view north, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. Keeper's house, light tower and oil house, view north, south and east sides of keeper's house, south side of tower and oil house - Owl's Head Light Station, Off State Highway 73 just east of Rockland on Owl's Head Bay, Owls Head, Knox County, ME

  7. 12. Fuel house and fog signal house, view northeast, southwest ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    12. Fuel house and fog signal house, view northeast, southwest side of fuel house, west and south sides of fog signal house - Cape Elizabeth Light Station, Near Two Lights State Park at end of Two Lights Road, off State Highway 77, Cape Elizabeth, Cumberland County, ME

  8. 7. Keeper's house, fog signal house and light tower, view ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    7. Keeper's house, fog signal house and light tower, view north northeast, west and south sides of keeper's house and tower, southwest and southeast sides of fog signal house - West Quoddy Head Light Station, At eastern tip of West Quaddy Head, Lubec, Washington County, ME

  9. 3. Bell house, light tower and keeper's house, view west, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. Bell house, light tower and keeper's house, view west, southeast side and northeast front of bell house, southeast sides of tower and keeper's house - Burnt Coat Harbor Light Station, At Hackamock Head on Swan's Island opposite Harbor Island at entrance to Burnt Coat Harbor, Swans Island, Hancock County, ME

  10. 1. General view, twoandahalf story house at left. (The house ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. General view, two-and-a-half story house at left. (The house next door is George McCraig House, HABS No. PA-1593). Photocopied from December 1957 photograph on file at Philadelphia Historical Commission - Henry Elwell House, 812 South Front Street, Philadelphia, Philadelphia County, PA

  11. Housing in Los Angeles: Affordable Housing for the Future.

    ERIC Educational Resources Information Center

    Los Angeles Blue Ribbon Committee for Affordable Housing, CA.

    A 1988 mayoral committee assessed the seriousness of Los Angeles (California) housing problems and found that the city's housing efforts were sufficient in the 1960s, when the Federal Government took primary responsibility for housing and the average wage was adequate to support the cost of the average house or apartment. However, the following…

  12. 91. VIEW NORTHWEST OF SCRAP HOUSE AND CAST HOUSE, BUILDINGS ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    91. VIEW NORTHWEST OF SCRAP HOUSE AND CAST HOUSE, BUILDINGS 101 AND 72; BUILDING 101 IN THE CENTER OF THE PHOTOGRAPH HOUSED SCRAP METAL CLEANING AND PROCESSING FACILITIES; BUILDING 72 AT RIGHT CENTER HOUSED MELTING FURNACES AND CONTINUOUS CASTING MACHINERY - Scovill Brass Works, 59 Mill Street, Waterbury, New Haven County, CT

  13. Clays causing adhesion with tool surfaces during mechanical tunnel driving

    NASA Astrophysics Data System (ADS)

    Spagnoli, G.; Fernández-Steeger, T.; Stanjek, H.; Feinendegen, M.; Post, C.; Azzam, R.

    2009-04-01

    During mechanical excavation with a tunnel boring machine (TBM) it is possible that clays stick to the cutting wheel and to other metal parts. The resulting delays in the progress of construction work, cause great economic damage and often disputes between the public awarding authorities and executing companies. One of the most important factors to reduce successfully the clay adhesion is the use of special polymers and foams. But why does the clay stick to the metal parts? A first step is to recognize which kind of clay mineralogy shows serious adhesion problems. The mechanical properties of clay and clay suspensions are primarily determined by surface chemistry and charge distribution at the interfaces, which in turn affect the arrangement of the clay structure. As we know, clay is a multi-phase material and its behaviour depends on numerous parameters such as: clay mineralogy, clay fraction, silt fraction, sand fraction, water content, water saturation, Atterberg limits, sticky limit, activity, cation exchange capacity, degree of consolidation and stress state. It is therefore likely that adhesion of clay on steel is also affected by these clay parameters. Samples of clay formations, which caused problems during tunnel driving, will be analyzed in laboratory. Mineralogical analyses (diffractometry, etc.) will be carried out to observe which minerals are responsible for adherence problems. To manipulate the physical properties, batch tests will be carried out in order to eliminate or reduce the adhesion on tool surfaces through variation of the zeta potential. Second step is the performance of vane shear tests on clay samples. Different pore fluid (distilled water, pure NaCl solution, ethanol and methanol) will be used to study the variation of the mechanical behaviour of clay depending on the dielectric constant of the fluids. This project is funded by the German Federal Ministry of Education and Research (BMBF) and the DFG (German Research Foundation) in the

  14. Housing and child health.

    PubMed

    Weitzman, Michael; Baten, Ahmareen; Rosenthal, David G; Hoshino, Risa; Tohn, Ellen; Jacobs, David E

    2013-09-01

    The connection between housing and health is well established. Physical, chemical, and biological aspects of the child's home, such as cleanliness, moisture, pests, noise, accessibility, injury risks, and other forms of housing environmental quality, all have the potential to influence multiple aspects of the health and development of children. Basic sanitation, reduced household crowding, other improvements in housing and expanded, and improved housing regulations have led to advances in children's health. For example, lead poisoning prevention policies have profoundly reduced childhood lead exposure in the United States. This and many other successes highlight the health benefits for families, particularly children, by targeting interventions that reduce or eliminate harmful exposures in the home. Additionally, parental mental health problems, food insecurity, domestic violence, and the presence of guns in children's homes all are largely experienced by children in their homes, which are not as yet considered part of the Healthy Homes agenda. There is a large movement and now a regulatory structure being put in place for healthy housing, which is becoming closely wedded with environmental health, public health, and the practice of pediatrics. The importance of homes in children's lives, history of healthy homes, asthma, and exposures to lead, carbon monoxide, secondhand/thirdhand smoke, radon, allergy triggers is discussed, as well as how changes in ambient temperature, increased humidity, poor ventilation, water quality, infectious diseases, housing structure, guns, electronic media, family structure, and domestic violence all affect children's health.

  15. Understanding Housing Delays and Relocations Within the Housing First Model.

    PubMed

    Zerger, Suzanne; Pridham, Katherine Francombe; Jeyaratnam, Jeyagobi; Hwang, Stephen W; O'Campo, Patricia; Kohli, Jaipreet; Stergiopoulos, Vicky

    2016-01-01

    This study explores factors contributing to delays and relocations during the implementation of the Housing First model in Toronto, Ontario. While interruptions in housing tenure are expected en route to recovery and housing stability, consumer and service provider views on finding and keeping housing remain largely unknown. In-person interviews and focus groups were conducted with 48 study participants, including 23 case managers or housing workers and 25 consumers. The following three factors contributed to housing delays and transfers: (1) the effectiveness of communication and collaboration among consumers and service providers, (2) consumer-driven preferences and ambivalence, and (3) provider prioritization of consumer choice over immediate housing access. Two strategies--targeted communications and consumer engagement in housing searches--supported the housing process. Several factors affect the timing and stability of housing. Communication between and among providers and consumers, and a shared understanding of consumer choice, can further support choice and recovery.

  16. Coatings and films derived from clay/wax nanocomposites

    DOEpatents

    Chaiko, David J.; Leyva, Argentina A.

    2006-11-14

    The invention provides methods for making clay/wax nanocomposites and coatings and films of same with improved chemical resistance and gas barrier properties. The invention further provides methods for making and using emulsions of such clay/wax nanocomposites. Typically, an organophillic clay is combined with a wax or wax/polymer blend such that the cohesion energy of the clay matches that of the wax or wax/polymer blend. Suitable organophilic clays include mica and phyllosilicates that have been surface-treated with edge or edge and surface modifying agents. The resulting nanocomposites have applications as industrial coatings and in protective packaging.

  17. Chemical disaggregation of kaolinitic claystones (tonsteins and flint clays)

    USGS Publications Warehouse

    Triplehorn, D.M.; Bohor, B.F.; Betterton, W.J.

    2002-01-01

    The coarse, non-clay fraction of many flint-like kaolinitic claystones often contains mineral grains diagnostic of the claystone's origin and, in the case of tonsteins (altered volcanic ashes), may also provide minerals suitable for radiometric dating. Separation of the non-clay mineral fraction is often difficult because flint clays and flint-like clays resist slaking in water and thus are difficult to disaggregate. Chemical disaggregation of resistant kaolinitic claystones may be achieved by immersion in either hydrazine monohydrate or DMSO for periods ranging from one day to several weeks. Generally, hydrazine monohydrate works more quickly and efficiently than DMSO to disaggregate most kaolinitic claystones and flint clays.

  18. GUARD HOUSE AND SOUTH FIRE HOUSE, VICINITY MAP. (Shows the ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    GUARD HOUSE AND SOUTH FIRE HOUSE, VICINITY MAP. (Shows the Guard House and Barracks, and South Fire House in relation to nearby roads, railroad tracks, and the piers). Navy Yard, Mare Island, California. P.W. Drawing No. C-1899, approved 1941; file no. 930-C-1. Scale one inch to forty feet. 72 cn x 97 cm. Ink on vellum - Mare Island Naval Shipyard, Guard House & Barracks, Railroad Avenue near Eighteenth Street, Vallejo, Solano County, CA

  19. Influence of clay mineral structure and surfactant nature on the adsorption capacity of surfactants by clays.

    PubMed

    Sánchez-Martín, M J; Dorado, M C; del Hoyo, C; Rodríguez-Cruz, M S

    2008-01-15

    Adsorption of three surfactants of different nature, Triton X-100 (TX100) (non-ionic), sodium dodecylsulphate (SDS) (anionic) and octadecyltrimethylammonium bromide (ODTMA) (cationic) by four layered (montmorillonite, illite, muscovite and kaolinite) and two non-layered (sepiolite and palygorskite) clay minerals was studied. The objective was to improve the understanding of surfactant behaviour in soils for the possible use of these compounds in remediation technologies of contaminated soils by toxic organic compounds. Adsorption isotherms were obtained using surfactant concentrations higher and lower than the critical micelle concentration (cmc). These isotherms showed different adsorption stages of the surfactants by the clay minerals, and were classified in different subgroups of the L-, S- or H-types. An increase in the adsorption of SDS and ODTMA by all clay minerals is observed up to the cmc of the surfactant in the equilibrium solution is reached. However, there was further TX100 adsorption when the equilibrium concentration was well above the cmc. Adsorption constants from Langmuir and Freundlich equations (TX100 and ODTMA) or Freundlich equation (SDS) were used to compare adsorption of different surfactants by clay minerals studied. These constants indicated the surfactant adsorption by clay minerals followed this order ODTMA>TX100>SDS. The adsorption of TX100 and ODTMA was higher by montmorillonite and illite, and the adsorption of SDS was found to be higher by kaolinite and sepiolite. Results obtained show the influence of clay mineral structure and surfactant nature on the adsorption capacity of surfactants by clays, and they indicate the interest to consider the soil mineralogical composition when one surfactant have to be selected in order to establish more efficient strategies for the remediation of soils and water contaminated by toxic organic pollutants.

  20. Dioxins in primary kaolin and secondary kaolinitic clays.

    PubMed

    Schmitz, Martin; Scheeder, Georg; Bernau, Sarah; Dohrmann, Reiner; Germann, Klaus

    2011-01-15

    Since 1996 dioxins have been repeatedly detected worldwide in Tertiary ball clays used as anticaking agent in the production of animal feed and a variety of other applications. The dioxins of these natural clays are very unlikely of anthropogenic source, but no model of dioxin enrichment has been established. A hypothetical model is presented which explains the highly variable dioxin loadings of the Tertiary kaolinitic clays by natural addition during clay-sedimentation. To prove this hypothesis, Tertiary primary nonsedimentary kaolin and sedimentary kaolinitic clays were collected at three profiles in Europe and analyzed for mineralogy, chemistry, organic carbon, and polychlorinated dibenzo-p-dioxins/-furans (PCDD/F). Primary kaolin, kaolinitic, and lignitic clays contained almost no PCDFs. PCDD concentration differed markedly between primary kaolin (3-91 pg/g) and secondary kaolinitic clay (711-45935 pg/g), respectively, lignitic clays (13513-1191120 pg/g). The dioxin loading of secondary kaolinitic and lignitic clays is approximately 10 to a few thousand times higher than in the primary kaolin or recent environmental settings. The dioxin concentrations decrease from octachlorodibenzo-p-dioxin to the tetrachlorodibenzo-p-dioxins and exhibit the "natural formation pattern". No correlation between PCDD/F concentration and bulk composition of clays was found. These findings support the hypothesis of the enrichment of dioxin in clays during sedimentation.

  1. [Mechanisms of removing red tide organisms by organo-clays].

    PubMed

    Cao, Xi-Hua; Song, Xiu-Xian; Yu, Zhi-Ming; Wang, Kui

    2006-08-01

    We tested the influence of the preparation conditions of the quaternary ammonium compounds (QACs) modified clays on their capacities to remove red tide organisms, then discussed the mechanisms of the organo-clays removing red tide organisms. Hexadecyltrimethylammonium (HDTMA) improved the capacity of clays to flocculate red tide algae, and the HDTMA in metastable state enhanced the toxicity of the clay complexes to algae. The capacities of the organo-clays correlated with the toxicity and the adsorbed amount of the QACs used in clays modification, but as the incubation time was prolonged the stability of the organo-clays was improved and the algal removal efficiencies of the clay complexes decreased. When the adsorbed HDTMA was arranged in different clays in which the spatial resistance was different, there was more HDTMA in metastable state in the three-layer montmorillonite. Because of the homo-ion effect the bivalent or trivalent metal ions induced more HDTMA in metastable state and the corresponding organo-clays had high capacities to remove red tide organisms. When the reaction temperature was 60 degrees C the adsorbed HDTMA was easily arranged on cation exchange sites, if the temperature rose or fell the metastable HDTMA would increase so that the capacity of the clays was improved.

  2. Clay-based geothermal drilling fluids

    SciTech Connect

    Guven, N.; Carney, L.L.; Lee, L.J.; Bernhard, R.P.

    1982-11-01

    The rheological properties of fluids based on fibrous clays such as sepiolite and attapulgite have been systematically examined under conditions similar to those of geothermal wells, i.e. at elevated temperatures and pressures in environments with concentrated brines. Attapulgite- and sepiolite-based fluids have been autoclaved at temperatures in the range from 70 to 800/sup 0/F with the addition of chlorides and hydroxides of Na, K, Ca, and Mg. The rheological properties (apparent and plastic viscosity, fluid loss, gel strength, yield point, and cake thickness) of the autoclaved fluids have been studied and correlated with the chemical and physical changes that occur in the clay minerals during the autoclaving process.

  3. Humidity Dependent Extinction of Clay Aerosols

    NASA Astrophysics Data System (ADS)

    Greenslade, M. E.; Attwood, A. R.

    2010-12-01

    Aerosols play an important role in the Earth’s radiative balance by directly scattering and absorbing radiation. The magnitude of aerosol forcing can be altered by changes in relative humidity which cause aerosol size, shape and refractive index to vary. To quantify these effects, a custom cavity ring down instrument operated at 532 nm with two sample channels measures aerosols extinction under dry conditions and at elevated humidity. The optical growth, fRH(ext), is determined as a ratio of the extinction cross section at high relative humidity to that under dry conditions. Three key clay components of mineral dust and mixtures of clay components with ammonium sulfate are investigated using this method. Experimentally obtained optical growth is compared with physical growth factors from the literature and our work determined using several different techniques. Further, Mie theory calculations based on published optical constants are compared with experimental results. Differences between theory and experiment will be discussed.

  4. Resin injection in clays with high plasticity

    NASA Astrophysics Data System (ADS)

    Nowamooz, Hossein

    2016-11-01

    Regarding the injection process of polyurethane resins in clays with high plasticity, this paper presents the experimental results of the pressuremeter and cone penetration tests before and after injection. A very important increase in pressure limit or in soil resistance can be observed for all the studied depths close to the injection points. An analytical analysis for cylindrical pore cavity expansion in cohesive frictional soils obeying the Mohr-Coulomb criterion was then used to reproduce the pressuremeter tests before and after injection. The model parameters were calibrated by maintaining constant the elasticity parameters as well as the friction angel before and after injection. A significant increase in cohesion was observed because of soil densification after resin expansion. The estimated undrained cohesions, derived from the parameters of the Mohr-Coulomb criterion, were also compared with the cone penetration tests. Globally, the model predictions show the efficiency of resin injection in clay soils with high plasticity.

  5. Atomic Force Microscope Studies of Synthetic Clays

    NASA Astrophysics Data System (ADS)

    Piner, Richard; Ruoff, Rodney

    2003-03-01

    Clays are a class of compounds made up of small crystals of layered silicates. They are chemically and structurely similar to mica, but the individual crystals have lateral dimensions of 1 micron. Once fully exfoliated, they are single sheets 1 nanometer thick. These sheets thus have an aspect ratio of 1000 or more. They show promise as a component in composite materials. We report on AFM studies of the fully exfoliated sheets. AFM reveals impurities that are difficult to detect any other way. We will also report on methods to manipulate the sheets and to clean them of the impurities. We are laying the groundwork for extensive studies of the nanomechanics of these sheets, and of the interactions of individual clay layers with polymer chains.

  6. Silt-clay aggregates on Mars

    NASA Technical Reports Server (NTRS)

    Greeley, R.

    1979-01-01

    Viking observations suggest abundant silt and clay particles on Mars. It is proposed that some of these particles agglomerate to form sand size aggregates that are redeposited as sandlike features such as drifts and dunes. Although the binding for the aggregates could include salt cementation or other mechanisms, electrostatic bonding is considered to be a primary force holding the aggregates together. Various laboratory experiments conducted since the 19th century, and as reported here for simulated Martian conditions, show that both the magnitude and sign of electrical charges on windblown particles are functions of particle velocity, shape and composition, atmospheric pressure, atmospheric composition and other factors. Electrical charges have been measured for saltating particles in the wind tunnel and in the field, on the surfaces of sand dunes, and within dust clouds on earth. Similar, and perhaps even greater, charges are proposed to occur on Mars, which could form aggregates of silt and clay size particles

  7. Clay mineral formation and transformation in rocks and soils

    USGS Publications Warehouse

    Eberl, D.D.

    1983-01-01

    Three mechanisms for clay mineral formation (inheritance, neoformation, and transformation) operating in three geological environments (weathering, sedimentary, and diagenetic-hydrothermal) yield nine possibilities for the origin of clay minerals in nature. Several of these possibilities are discussed in terms of the rock cycle. The mineralogy of clays neoformed in the weathering environment is a function of solution chemistry, with the most dilute solutions favoring formation of the least soluble clays. After erosion and transportation, these clays may be deposited on the ocean floor in a lateral sequence that depends on floccule size. Clays undergo little reaction in the ocean, except for ion exchange and the neoformation of smectite; therefore, most clays found on the ocean floor are inherited from adjacent continents. Upon burial and heating, however, dioctahedral smectite reacts in the diagenetic environment to yield mixed-layer illite-smectite, and finally illite. With uplift and weathering, the cycle begins again. Refs.

  8. Feasibility of classification of clay minerals by using PAS

    NASA Astrophysics Data System (ADS)

    Honda, Y.; Yoshida, Y.; Akiyama, Y.; Nishijima, S.

    2015-06-01

    After the nuclear power plant disaster, the evaluation of radioactive Cs kept in soil, especially in clay minerals and the elucidation of its movement are urgent subjects to promote decontamination. It is known that the extractable level of Cs depends on the sort of clay minerals. We tried to find the characteristics of clay minerals belonging to phillosilicate group using positron annihilation spectroscopy (PAS) and the relationship between the results of PAS and the amounts of substantially extracted Cs from the clay minerals. The results showed that each clay mineral was found to be distinguishable from other clay minerals by PAS and the extraction rate of Cs was different among those clay minerals, however the direct correlation between the results of PAS and the extraction rates of Cs was not found.

  9. Clay mineral type effect on bacterial enteropathogen survival in soil.

    PubMed

    Brennan, Fiona P; Moynihan, Emma; Griffiths, Bryan S; Hillier, Stephen; Owen, Jason; Pendlowski, Helen; Avery, Lisa M

    2014-01-15

    Enteropathogens released into the environment can represent a serious risk to public health. Soil clay content has long been known to have an important effect on enteropathogen survival in soil, generally enhancing survival. However, clay mineral composition in soils varies, and different clay minerals have specific physiochemical properties that would be expected to impact differentially on survival. This work investigated the effect of clay materials, with a predominance of a particular mineral type (montmorillonite, kaolinite, or illite), on the survival in soil microcosms over 96 days of Listeria monocytogenes, Salmonella Dublin, and Escherichia coli O157. Clay mineral addition was found to alter a number of physicochemical parameters in soil, including cation exchange capacity and surface area, and this was specific to the mineral type. Clay mineral addition enhanced enteropathogen survival in soil. The type of clay mineral was found to differentially affect enteropathogen survival and the effect was enteropathogen-specific.

  10. CLAY MINERALOGY OF INSOLUBLE RESIDUES IN MARINE EVAPORITES.

    USGS Publications Warehouse

    Bodine, Marc W.

    1985-01-01

    Insoluble residues from three sequences of Paleozoic marine evaporites (Retsof salt bed in western New York, Salado Formation in south-eastern New Mexico, and Paradox Member of the Hermosa Formation in southeastern Utah) are rich in trioctahedral clays. Chlorite (clinochlore), corrensite (mixed-layer chlorite-trioctahedral smectite), talc, and illite (the only dioctahedral clay) are the dominant clay minerals; serpentine, discrete trioctahedral smectite (saponite), and interstratified talc-trioctahedral smectite are sporadically abundant. These clay-mineral assemblages differ chemically and mineralogically from those observed in most continental and normal marine rocks, which commonly contain kaolinite, dioctahedral smectite (beidellite-montmorillonite), illite, mixed-layer illite-dioctahedral smectite, and, in most cases, no more than minor quantities of trioctahedral clay minerals. The distinctive clay mineralogy in these evaporite sequences suggests a largely authigenic origin. These clay minerals are thought to have formed during deposition and early diagenesis through interaction between argillaceous detritus and Mg-rich marine evaporite brines.

  11. Clay mineralogy in agrochernozems of western Ukraine

    NASA Astrophysics Data System (ADS)

    Papish, I. Ya.; Chizhikova, N. P.; Poznyak, S. P.; Varlamov, E. B.

    2016-10-01

    The mineralogy of clay fractions separated from deep low-humus deep-gleyic loamy typical agrochernozems on loess-like loams of the Upper Bug and Dniester uplands in the Central Russian loess province of Ukraine consists of complex disordered interstratifications with the segregation of mica- and smectite-type layers (hereafter, smectite phase), tri- and dioctahedral hydromicas, kaolinite, and chlorite. The distribution of the clay fraction is uniform. The proportions of the layered silicates vary significantly within the profile: a decrease in the content of the smectite phase and a relative increase in the content of hydromicas up the soil profile are recorded. In the upper horizons, the contents of kaolinite and chlorite increase, and some amounts of fine quartz, potassium feldspars, and plagioclases are observed. This tendency is observed in agrochernozems developed on the both Upper Bug and Dniester uplands. The differences include the larger amounts of quartz, potassium feldspars, and plagioclases in the clay material of the Upper Bug Upland, while the contents of the smectite phase in the soil profiles of the areas considered are similar. An analogous mineral association is noted in podzolized agrochernozems on loess-like deposits in the Cis-Carpathian region of the Southern Russian loess province developed on the Prut-Dniester and Syan-Dniester uplands. The distribution of particle-size fractions and the mineralogy of the clay fraction indicate the lithogenic heterogeneity of the soil-forming substrate. When the drifts change, the mineral association of the soils developed within the loess-like deposits gives place to minerals dominated by individual smectite with some mica-smectite inter stratifications, hydromicas, and chlorite.

  12. Clay stabilization in low-permeability formations

    SciTech Connect

    Himes, R.E.; Vinson, E.F.; Simon, D.E. )

    1991-08-01

    The most popular clay stabilizers used recently in well-treating solutions are classified as cationic organic polymers (COP's). This paper reports on studies that have shown these stabilizers to be ineffective in microdarcy to low-millidarcy sandstones. Recent research led to the development of a stabilizer applicable to formations with permeabilities of 0.010 md and higher that also provides enhanced load-water recovery and more efficient placement from gelled-water solutions.

  13. Toward Accurate Adsorption Energetics on Clay Surfaces

    PubMed Central

    2016-01-01

    Clay minerals are ubiquitous in nature, and the manner in which they interact with their surroundings has important industrial and environmental implications. Consequently, a molecular-level understanding of the adsorption of molecules on clay surfaces is crucial. In this regard computer simulations play an important role, yet the accuracy of widely used empirical force fields (FF) and density functional theory (DFT) exchange-correlation functionals is often unclear in adsorption systems dominated by weak interactions. Herein we present results from quantum Monte Carlo (QMC) for water and methanol adsorption on the prototypical clay kaolinite. To the best of our knowledge, this is the first time QMC has been used to investigate adsorption at a complex, natural surface such as a clay. As well as being valuable in their own right, the QMC benchmarks obtained provide reference data against which the performance of cheaper DFT methods can be tested. Indeed using various DFT exchange-correlation functionals yields a very broad range of adsorption energies, and it is unclear a priori which evaluation is better. QMC reveals that in the systems considered here it is essential to account for van der Waals (vdW) dispersion forces since this alters both the absolute and relative adsorption energies of water and methanol. We show, via FF simulations, that incorrect relative energies can lead to significant changes in the interfacial densities of water and methanol solutions at the kaolinite interface. Despite the clear improvements offered by the vdW-corrected and the vdW-inclusive functionals, absolute adsorption energies are often overestimated, suggesting that the treatment of vdW forces in DFT is not yet a solved problem. PMID:27917256

  14. Chemically-bonded brick production based on burned clay by means of semidry pressing

    NASA Astrophysics Data System (ADS)

    Voroshilov, Ivan; Endzhievskaya, Irina; Vasilovskaya, Nina

    2016-01-01

    We presented a study on the possibility of using the burnt rocks of the Krasnoyarsk Territory for production of chemically-bonded materials in the form of bricks which are so widely used in multistory housing and private house construction. The radiographic analysis of the composition of burnt rock was conducted and a modifier to adjust the composition uniformity was identified. The mixing moisture content was identified and optimal amount at 13-15% was determined. The method of semidry pressing has been chosen. The process of obtaining moldings has been theoretically proved; the advantages of chemically-bonded wall materials compared to ceramic brick were shown. The production of efficient artificial stone based on material burnt rocks, which is comparable with conventionally effective ceramic materials or effective with cell tile was proved, the density of the burned clay-based cell tile makes up to 1630-1785 kg m3, with compressive strength of 13.6-20.0 MPa depending on the compression ratio and cement consumption, frost resistance index is F50, and the thermal conductivity in the masonry is λ = 0,459-0,546 W m * °C. The clear geometric dimensions of pressed products allow the use of the chemically-bonded brick based on burnt clay as a facing brick.

  15. Chemically-bonded brick production based on burned clay by means of semidry pressing

    SciTech Connect

    Voroshilov, Ivan Endzhievskaya, Irina Vasilovskaya, Nina

    2016-01-15

    We presented a study on the possibility of using the burnt rocks of the Krasnoyarsk Territory for production of chemically-bonded materials in the form of bricks which are so widely used in multistory housing and private house construction. The radiographic analysis of the composition of burnt rock was conducted and a modifier to adjust the composition uniformity was identified. The mixing moisture content was identified and optimal amount at 13-15% was determined. The method of semidry pressing has been chosen. The process of obtaining moldings has been theoretically proved; the advantages of chemically-bonded wall materials compared to ceramic brick were shown. The production of efficient artificial stone based on material burnt rocks, which is comparable with conventionally effective ceramic materials or effective with cell tile was proved, the density of the burned clay-based cell tile makes up to 1630-1785 kg \\ m{sup 3}, with compressive strength of 13.6-20.0 MPa depending on the compression ratio and cement consumption, frost resistance index is F50, and the thermal conductivity in the masonry is λ = 0,459-0,546 W \\ m {sup *} °C. The clear geometric dimensions of pressed products allow the use of the chemically-bonded brick based on burnt clay as a facing brick.

  16. Infiltration tests on fractured compacted clay

    SciTech Connect

    McBrayer, M.C.; Mauldon, M.; Drumm, E.C.; Wilson, G.V.

    1997-05-01

    Desiccation and freeze-thaw of compacted clay barriers may result in cracks that serve as preferential flow paths. A series of infiltration tests on compacted kaolin samples was conducted to explore the importance of preferential flow paths during infiltration, and their effect on the infiltration rate. Clod size at the time of compaction was found to have a strong influence on both the rate and depth of infiltration. The authors suggest that flow and infiltration through fractured clay may be described in terms of two stages: an initial dynamic stage in which the infiltration rate is initially high but decreases rapidly due to the clay swelling and closing fractures, and a steady-state stage usually characterized by k{sub sat}, during which the infiltration rate is relatively constant. The study has shown that cracks do not fully heal upon hydration and readily reopen during subsequent dehydration. Infiltration rates during the dynamic stage of infiltration, while cracks are closing, are orders of magnitude higher than the steady-state rate used to estimate k{sub sat}, for barrier evaluation.

  17. Ceramic suitability of a Moroccan triassic clays

    NASA Astrophysics Data System (ADS)

    Khalfaoui, A.; Hajjaji, M.; Kacim, S.

    2005-03-01

    The drying behaviour, plasticity and firing properties (water absorption, shrinkage and bending strength) of two clays, RA and RO from the East and West of the high atlas (Morocco) respectively, were evaluated and discussed in view of the granulometric distribution and mineralogical compositions. It is found that the almost identical drying shrinkages is linked to the similar granulometry, and the higher Atterberg limits for RA are associated to the presence of chlorite (11 wt.%). In addition, it is established that, in spite of their different mineralogical compositions, the sintering process for both clays is controlled by melt flow and consequently the bending strengths at the maximum firing temperatures (1000 and 1075 ° C for RA and RO respectively) are similar (˜ 58 MPa). On the other hand, it is observed that RA sherds shrink more and absorb less water, likely because of the presence of chlorite which is considered as a highly fluxing compound. In all cases, the use of both clays for structural products manufacturing should be improved by the addition of fillers.

  18. Adsorption of bacteriophages on clay minerals

    USGS Publications Warehouse

    Chattopadhyay, Sandip; Puls, Robert W.

    1999-01-01

    The ability to predict the fate of microorganisms in soil is dependent on an understanding of the process of their sorption on soil and subsurface materials. Presently, we have focused on studying the thermodynamics of sorption of bacteriophages (T-2, MS-2, and φX-174) on clays (hectorite, saponite, kaolinite, and clay fraction of samples collected from a landfill site). The thermodynamic study not only determines the feasibility of the process but also provides information on the relative magnitudes of the different forces under a particular set of conditions. The total free energy of interaction during sorption of bacteriophages on clays (ΔG) has been assumed to be the summation of ΔGH (ΔG due to hydrophobic interactions) and ΔGEL (ΔG due to electrostatic interactions). The magnitude of ΔGH was determined from the different interfacial tensions (γ) present in the system, while ΔGEL was calculated from ζ-potentials of the colloidal particles. Calculated results show that surface hydrophobicities of the selected sorbents and sorbates dictate sorption. Among the selected bacteriophages, maximum sorption was observed with T-2, while hectorite has the maximum sorption capacity. Experimental results obtained from the batch adsorption studies also corroborated those obtained from the theoretical study.

  19. Role of bentonite clays on cell growth.

    PubMed

    Cervini-Silva, Javiera; Ramírez-Apan, María Teresa; Kaufhold, Stephan; Ufer, Kristian; Palacios, Eduardo; Montoya, Ascención

    2016-04-01

    Bentonites, naturally occurring clays, are produced industrially because of their adsorbent capacity but little is known about their effects on human health. This manuscript reports on the effect of bentonites on cell growth behaviour. Bentonites collected from India (Bent-India), Hungary (Bent-Hungary), Argentina (Bent-Argentina), and Indonesia (Bent-Indonesia) were studied. All four bentonites were screened in-vitro against two human cancer cell lines [U251 (central nervous system, glioblastoma) and SKLU-1 (lung adenocarcinoma)] supplied by the National Cancer Institute (USA). Bentonites induced growth inhibition in the presence of U251 cells, and growth increment in the presence of SKLU-1 cells, showing that interactions between bentonite and cell surfaces were highly specific. The proliferation response for U251 cells was explained because clay surfaces controlled the levels of metabolic growth components, thereby inhibiting the development of high-grade gliomas, particularly primary glioblastomas. On the other hand, the proliferation response for SKLU-1 was explained by an exacerbated growth favoured by swelling, and concomitant accumulation of solutes, and their hydration and transformation via clay-surface mediated reactions.

  20. Spectromicroscopy of Fe distributions in clay microcrystals

    SciTech Connect

    Grundl, T.; Cerasari, S.; Garcia, A.

    1997-04-01

    Clays are ubiquitous crystalline particles found in nature that are responsible for contributing to a wide range of chemical reactions in soils. The structure of these mineral particles changes when the particle is hydrated ({open_quotes}wet{close_quotes}), from that when it is dry. This makes a study of the microscopic distribution of chemical content of these nanocrystals difficult using standard techniques that require vacuum. In addition to large structural changes, it is likely that chemical changes accompany the drying process. As a result, spectroscopic measurements on dried clay particles may not accurately reflect the actual composition of the material as found in the environment. In this work, the authors extend the use of the ALS Spectromicroscopy Facility STXM to high spectral and spatial resolution studies of transition metal L-edges in environmental materials. The authors are studying mineral particles of montmorillonite, which is an Fe bearing clay which can be prepared with a wide distribution of Fe concentrations, and with Fe occupying different substitutional sites.

  1. Molecular interactions alter clay and polymer structure in polymer clay nanocomposites.

    PubMed

    Sikdar, Debashis; Katti, Kalpana S; Katti, Dinesh R

    2008-04-01

    In this work, using photoacoustic Fourier transform infrared spectroscopy (FTIR) we have studied the structural distortion of clay crystal structure in organically modified montmorillonite (OMMT) and polymer clay nanocomposites (PCN). To study the effect of organic modifiers on the distortion of crystal structure of clay, we have synthesized OMMTs and PCNs containing same polymer and clay but with three different organic modifiers (12-aminolauric acid, n-dodecylamine, and 1,12-diaminododecane), and conducted the FTIR study on these PCNs. Our previous molecular dynamics (MD) study on these PCNs reveals that significant nonbonded interactions (van der Waals, electrostatic interactions) exist between the different constituents (polymer, organic modifier, and clay) of nanocomposites. Previous work based on X-ray diffraction (XRD) and differential scanning calorimetry (DSC) on the same set of PCNs shows that crystallinity of polymer in PCNs have changed significantly in comparison to those in pristine polymer; and, the nonbonded interactions between different constituents of PCN are responsible for the change in crystal structure of polymer in PCN. In this work to evaluate the structural distortion of crystal structure of clay in OMMTs and PCNs, the positions of bands corresponding to different modes of vibration of Si-O bonds are determined from the deconvolution of broad Si-O bands in OMMTs and PCNs obtained from FTIR spectra. Intensity and area under the Si-O bands are indicative of orientation of clay crystal structures in OMMTs and PCNs. Significant changes in the Si-O bands are observed from each vibration mode in OMMTs and PCNs containing three different organic modifiers indicating that organic modifiers influence the structural orientation of silica tetrahedra in OMMTs and PCNs. Deconvolution of Si-O bands in OMMTs indicate a band at approximately 1200 cm(-1) that is orientation-dependent Si-O band. The specific changes in intensity and area under this band for

  2. Comparison of tetrachloromethane sorption to an alkylammonium-clay and an alkyldiammonium-clay

    USGS Publications Warehouse

    Smith, J.A.; Jaffe, P.R.

    1991-01-01

    The interlamellar space of Wyoming bentonite (clay) was modified by exchanging either decyltrimethyl-ammonium (DTMA) or decyltrimethyldiammonium (DTMDA) cations for inorganic ions, and tetrachloromethane sorption to the resulting two organoclays from water was studied at 10, 20, and 35??C. Only one end of the 10-carbon alkyl chain of the DTMA cation is attached to the silica surface of the clay mineral, and tetrachloromethane sorption of DTMA-clay is characterized by isotherm linearity, noncompetitive sorption, weak solute uptake, and a relatively low heat of sorption. Both ends of the 10-carbon chain of the DTMDA cation are attached to the silica surface of the clay mineral, and tetrachloromethane sorption to DTMDA-clay is characterized by nonlinear isotherms, competitive sorption, strong solute uptake, and a relatively high, exothermic heat of sorption that varies as a function of the mass of tetrachloromethane sorbed. Therefore, the attachment of both ends of the alkyl chain to the interlamellar mineral surface appears to change the sorption mechanism from a partition-dominated process to an adsorption-dominated process. ?? 1991 American Chemical Society.

  3. Iodide Sorption to Clays and the Relationship to Surface Charge and Clay Texture - 12356

    SciTech Connect

    Miller, Andrew; Kruichiak, Jessica; Tellez, Hernesto; Wang, Yifeng

    2012-07-01

    Iodine is assumed to behave conservatively in clay barriers around nuclear waste repositories and in natural sediments. Batch experiments tend to show little to no sorption, while in column experiments iodine is often retarded relative to tritiated water. Current surface complexation theory cannot account for negatively charged ion sorption to a negatively charged clay particle. Surface protonation and iodide sorption to clay minerals were examined using surface titrations and batch sorption experiments with a suite of clay minerals. Surface titrations were completed spanning a range of both pH values and ionic strengths. For reference, similar titrations were performed on pure forms of an Al-O powder. The titration curves were deconvoluted to attain the pKa distribution for each material at each ionic strength. The pKa distribution for the Al-O shows two distinct peaks at 4.8 and 7.5, which are invariant with ionic strength. The pKa distribution of clays was highly variable between the different minerals and as a function of ionic strength. Iodide sorption experiments were completed at high solid:solution ratios to exacerbate sorption properties. Palygorskite and kaolinite had the highest amount of iodide sorption and montmorillonite had the least. (authors)

  4. Domotics Project Housing Block

    PubMed Central

    Morón, Carlos; Payán, Alejandro; García, Alfonso; Bosquet, Francisco

    2016-01-01

    This document develops the study of an implementation project of a home automation system in a housing placed in the town of Galapagar, Madrid. This house, which is going to be occupied by a four-member family, consists of 67 constructed square meters distributed in lounge, kitchen, three bedrooms, bath, bathroom and terrace, this being a common arrangement in Spain. Thus, this study will allow extracting conclusions about the adequacy of the home automation in a wide percentage of housing in Spain. In this document, three house automation proposals are developed based on the requirements of the client and the different home automation levels that the Spanish House and Building Automation Association has established, besides two parallel proposals relating to the safety and the technical alarms. The mentioned proposed systems are described by means of product datasheets and descriptions, distribution plans, measurements, budgets and flow charts that describe the functioning of the system in every case. An evaluation of each system is included, based on other studies conclusions on this matter, where expected energy savings from each design, depending on the current cost of lighting, water and gas, as well as the expected economic amortization period is evaluated. PMID:27223285

  5. Domotics Project Housing Block.

    PubMed

    Morón, Carlos; Payán, Alejandro; García, Alfonso; Bosquet, Francisco

    2016-05-23

    This document develops the study of an implementation project of a home automation system in a housing placed in the town of Galapagar, Madrid. This house, which is going to be occupied by a four-member family, consists of 67 constructed square meters distributed in lounge, kitchen, three bedrooms, bath, bathroom and terrace, this being a common arrangement in Spain. Thus, this study will allow extracting conclusions about the adequacy of the home automation in a wide percentage of housing in Spain. In this document, three house automation proposals are developed based on the requirements of the client and the different home automation levels that the Spanish House and Building Automation Association has established, besides two parallel proposals relating to the safety and the technical alarms. The mentioned proposed systems are described by means of product datasheets and descriptions, distribution plans, measurements, budgets and flow charts that describe the functioning of the system in every case. An evaluation of each system is included, based on other studies conclusions on this matter, where expected energy savings from each design, depending on the current cost of lighting, water and gas, as well as the expected economic amortization period is evaluated.

  6. The direct synthesis of organic-containing clays and thermal analysis of porphyrin-clay complexes

    SciTech Connect

    Carrado, K.A.; Anderson, K.B.; Grutkoski, P.S.

    1991-01-01

    Synthetic TMA-montmorillonites have now been made in conjunction with synthetic porphyrin-hectorites reported earlier. In order to help progress towards preparation of porphyrin-containing aluminosilicate clays, the thermal stability of porphyrin-clay systems has been examined in detail. Results from TGA and Py-GC-MS indicate that the porphyrin nucleus is extremely stable in the present of clay minerals. Substituents on the nucleus such as pyridinium or anilinium are, on the other hand, slightly destabilized. In addition, the presence of transition metals like Fe(III) in metalloporphyrins appears to catalyze decomposition of the porphyrin nucleus to some degree. The use of Py-GC-MS in conjunction with TGA results greatly clarified the assignment of weight loss peaks. 18 refs., 3 figs.

  7. Clay-catalyzed reactions of coagulant polymers during water chlorination

    USGS Publications Warehouse

    Lee, J.-F.; Liao, P.-M.; Lee, C.-K.; Chao, H.-P.; Peng, C.-L.; Chiou, C.T.

    2004-01-01

    The influence of suspended clay/solid particles on organic-coagulant reactions during water chlorination was investigated by analyses of total product formation potential (TPFP) and disinfection by-product (DBP) distribution as a function of exchanged clay cation, coagulant organic polymer, and reaction time. Montmorillonite clays appeared to act as a catalytic center where the reaction between adsorbed polymer and disinfectant (chlorine) was mediated closely by the exchanged clay cation. The transition-metal cations in clays catalyzed more effectively than other cations the reactions between a coagulant polymer and chlorine, forming a large number of volatile DBPs. The relative catalytic effects of clays/solids followed the order Ti-Mont > Fe-Mont > Cu-Mont > Mn-Mont > Ca-Mont > Na-Mont > quartz > talc. The effects of coagulant polymers on TPFP follow the order nonionic polymer > anionic polymer > cationic polymer. The catalytic role of the clay cation was further confirmed by the observed inhibition in DBP formation when strong chelating agents (o-phenanthroline and ethylenediamine) were added to the clay suspension. Moreover, in the presence of clays, total DBPs increased appreciably when either the reaction time or the amount of the added clay or coagulant polymer increased. For volatile DBPs, the formation of halogenated methanes was usually time-dependent, with chloroform and dichloromethane showing the greatest dependence. ?? 2003 Elsevier Inc. All rights reserved.

  8. Adsorption of dyes using different types of clay: a review

    NASA Astrophysics Data System (ADS)

    Adeyemo, Aderonke Ajibola; Adeoye, Idowu Olatunbosun; Bello, Olugbenga Solomon

    2015-09-01

    Increasing amount of dyes in the ecosystem particularly in wastewater has propelled the search for more efficient low-cost adsorbents. The effective use of the sorption properties (high surface area and surface chemistry, lack of toxicity and potential for ion exchange) of different clays as adsorbents for the removal of different type of dyes (basic, acidic, reactive) from water and wastewater as potential alternatives to activated carbons has recently received widespread attention because of the environmental-friendly nature of clay materials. Insights into the efficiencies of raw and modified/activated clay adsorbents and ways of improving their efficiencies to obtain better results are discussed. Acid-modified clay resulted in higher rate of dye adsorption and an increased surface area and porosity (49.05 mm2 and 53.4 %). Base-modified clay has lower adsorption capacities, while ZnCl2-modified clay had the least rate of adsorption with a surface area of 44.3 mm2 and porosity of 43.4 %. This review also explores the grey areas of the adsorption properties of the raw clays and the improved performance of activated/modified clay materials with particular reference to the effects of pH, temperature, initial dye concentration and adsorbent dosage on the adsorption capacities of the clays. Various challenges encountered in using clay materials are highlighted and a number of future prospects for the adsorbents are proposed.

  9. Geosynthetic clay liners shrinkage under simulated daily thermal cycles.

    PubMed

    Sarabadani, Hamid; Rayhani, Mohammad T

    2014-06-01

    Geosynthetic clay liners are used as part of composite liner systems in municipal solid waste landfills and other applications to restrict the escape of contaminants into the surrounding environment. This is attainable provided that the geosynthetic clay liner panels continuously cover the subsoil. Previous case histories, however, have shown that some geosynthetic clay liner panels are prone to significant shrinkage and separation when an overlying geomembrane is exposed to solar radiation. Experimental models were initiated to evaluate the potential shrinkage of different geosynthetic clay liner products placed over sand and clay subsoils, subjected to simulated daily thermal cycles (60°C for 8 hours and 22°C for 16 hours) modelling field conditions in which the liner is exposed to solar radiation. The variation of geosynthetic clay liner shrinkage was evaluated at specified times by a photogrammetry technique. The manufacturing techniques, the initial moisture content, and the aspect ratio (ratio of length to width) of the geosynthetic clay liner were found to considerably affect the shrinkage of geosynthetic clay liners. The particle size distribution of the subsoil and the associated suction at the geosynthetic clay liner-subsoil interface was also found to have significant effects on the shrinkage of the geosynthetic clay liner.

  10. Effective Removal of Heavy Metals from Wastewater Using Modified Clay.

    PubMed

    Song, Mun-Seon; Vijayarangamuthu, K; Han, EunJi; Jeon, Ki-Joon

    2016-05-01

    We report an economical and eco-friendly way to remove the heavy metal pollutant using modified clay. The modification of clay was done by calcining the natural clay from Kyushu region in Japan. Further, the removal efficiency for various pH and contact time was evaluated. The morphology of the clays was studied using the scanning electron microscopy (SEM). The structural and chemical analyses of modified clay were done by using X-ray diffraction (XRD), Raman spectroscopy, and Energy dispersion analysis (EDAX) to understand the properties related to the removal of heavy metal pollutant. Further, we studied the absorption efficiency of clay for various pH and contacting time using Ni polluted water. The modified clays show better removal efficiency for all pH with different saturation time. The adsorption follows pseudo-second order kinetics and the adsorption capacity of modified clay is 1.5 times larger than that of natural clay. The increase in the adsorption efficiency of modified clay was correlated to the increase in hematite phase along with increase in surface area due to surface morphological changes.

  11. Clay mineralogy of the Cretaceous-Tertiary boundary clay. [in search for asteroid ejecta

    NASA Technical Reports Server (NTRS)

    Rampino, M. R.; Reynolds, R. C.

    1983-01-01

    Cretaceous-Tertiary boundary layer clay samples from four localities were subjected to analyses which imply that they are neither mineralogically exotic nor distinct from locally derived clays above and below the boundary. The anomalous iridium-rich ejecta component predicted by the asteroid impact scenario of Alvarez et al (1980) was not detected. It is proposed that volcanic material be considered as an explanation of the geochemical anomalies of the Cretaceous-Tertiary boundary. A model which involves a period of intense volcanism at the end of the Cretaceous would generate a variety of climatic and biological effects consonant with the geologic history of that period.

  12. CO2 adsorption isotherm on clay minerals and the CO2 accessibility into the clay interlayer

    NASA Astrophysics Data System (ADS)

    Gensterblum, Yves; Bertier, Pieter; Busch, Andreas; Rother, Gernot; Krooß, Bernhard

    2013-04-01

    Large-scale CO2 storage in porous rock formations at 1-3 km depth is seen as a global warming mitigation strategy. In this process, CO2 is separated from the flue gas of coal or gas power plants, compressed, and pumped into porous subsurface reservoirs with overlying caprocks (seals). Good seals are mechanically and chemically stable caprocks with low porosity and permeability. They prevent leakage of buoyant CO2 from the reservoir. Caprocks are generally comprised of thick layers of shale, and thus mainly consist of clay minerals. These clays can be affected by CO2-induced processes, such as swelling or dissolution. The interactions of CO2 with clay minerals in shales are at present poorly understood. Sorption measurements in combination scattering techniques could provide fundamental insight into the mechanisms governing CO2-clay interaction. Volumetric sorption techniques have assessed the sorption of supercritical CO2 onto coal (Gensterblum et al., 2010; Gensterblum et al., 2009), porous silica (Rother et al., 2012a) and clays as a means of exploring the potential of large-scale storage of anthropogenic CO2 in geological reservoirs (Busch et al., 2008). On different clay minerals and shales, positive values of excess sorption were measured at gas pressures up to 6 MPa, where the interfacial fluid is assumed to be denser than the bulk fluid. However, zero and negative values were obtained at higher densities, which suggests the adsorbed fluid becomes equal to and eventually less dense than the corresponding bulk fluid, or that the clay minerals expand on CO2 charging. Using a combination of neutron diffraction and excess sorption measurements, we recently deduced the interlayer density of scCO2 in Na-montmorillonite clay in its single-layer hydration state (Rother et al., 2012b), and confirmed its low density, as well as the expansion of the basal spacings. We performed neutron diffraction experiments at the FRMII diffractometer on smectite, kaolinite and illite

  13. Investigation into the effect of some additives on the mechanical strength, quality and thermal conductivity of clay bricks

    NASA Astrophysics Data System (ADS)

    Zaid, Adnan I. O.; Qandil, A.; Qattous, M. A. A.

    2016-08-01

    It was repeatedly reported that the clay bricks industry in Jordan is facing both weak mechanical strength and poor quality which caused marketing problems where it is expected to serve the increasing demand of housing in the country especially after the political crises in the neighboring countries Iraq and Syria. It is therefore anticipated that improvement of the mechanical strength and quality of the produced clay evaluation of the brick industry in Jordan is worth investigating. In this paper, theoretical and experimental investigation obtained from field visits to the factories producing clay bricks were carried out. Furthermore, the effect of using some additives from locally available materials namely: Battn El-Ghoul Clay, Suweileh sand and Olive extracts on the mechanical strength, thermal conductivity and surface quality of the produced bricks is investigated and discussed. The experimental results indicated that thermal conductivity, color and durability were all enhanced and the ultimate compressive strength was reduced but remained higher than the acceptable value for brickwork.

  14. 5. Relationship of chicken house, privy, claim house, and residence ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    5. Relationship of chicken house, privy, claim house, and residence to each other and immediate surroundings, looking northeast - George Spangerberger Farmstead, 2012 West Illinois Avenue, South Hutchinson, Reno County, KS

  15. 10. Relationship of residence, claim house, chicken house, west tool ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    10. Relationship of residence, claim house, chicken house, west tool shed, and east tool shed to each other and immediate surroundings, looking west - George Spangerberger Farmstead, 2012 West Illinois Avenue, South Hutchinson, Reno County, KS

  16. SUMMER KITCHEN AND SMOKE HOUSE AND HOUSE, VIEW TO WEST/ ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    SUMMER KITCHEN AND SMOKE HOUSE AND HOUSE, VIEW TO WEST/ SOUTHWEST - Kiel Farmstead, Summer Kitchen & Smokehouse, East side State Route 4, one half mile south of U.S. Route 64, Mascoutah, St. Clair County, IL

  17. 2. Keeper's house, light tower and bell house, view east, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. Keeper's house, light tower and bell house, view east, west and south sides - Bass Harbor Head Light Station, At southwest tip of Mount Desert Island off State Route 102, Bass Harbor, Hancock County, ME

  18. 2. Oil house, fog signal house and light tower, view ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. Oil house, fog signal house and light tower, view southwest, east and north sides - Great Duck Island Light Station, At southern tip of Great Duck Island southeast of Bass Harbor & northeast of Frenchboro, Frenchboro, Hancock County, ME

  19. 1. Keeper's house, light tower and bell house, view northeast, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. Keeper's house, light tower and bell house, view northeast, northwest and southwest sides - Burnt Coat Harbor Light Station, At Hackamock Head on Swan's Island opposite Harbor Island at entrance to Burnt Coat Harbor, Swans Island, Hancock County, ME

  20. 5. Shed, keeper's house, boathouse, light tower and oil house, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    5. Shed, keeper's house, boathouse, light tower and oil house, view southeast, northwest and southwest sides - Goat Island Light Station, Goat Island, next to entrance to Cape Porpoise Harbor, just south of Trott Island, Cape Porpoise, York County, ME

  1. INTERIOR VIEW OF THE GENERATING HOUSE SHOWING THE 'HOUSE GENERATOR' ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    INTERIOR VIEW OF THE GENERATING HOUSE SHOWING THE 'HOUSE GENERATOR' AND GOVERNOR ASSEMBLY. - Wilson Dam & Hydroelectric Plant, Spanning Tennessee River at Wilson Dam Road (Route 133), Muscle Shoals, Colbert County, AL

  2. 24 CFR 982.618 - Shared housing: Housing quality standards.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... URBAN DEVELOPMENT SECTION 8 TENANT BASED ASSISTANCE: HOUSING CHOICE VOUCHER PROGRAM Special Housing..., sanitary facilities in accordance with § 982.401(b), and food preparation and refuse disposal facilities...

  3. 1. Keeper's house, light tower and boat house, view southwest, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. Keeper's house, light tower and boat house, view southwest, northeast and northwest sides - Pumpkin Island Light Station, Pumpkin Island, at northern end of Eggemoggin Beach, off northwest end of Little Deer Island, Eggemoggin, Hancock County, ME

  4. Diffusion of water in bentonite clay: Neutron scattering study

    NASA Astrophysics Data System (ADS)

    Sharma, V. K.; Prabhudesai, S. A.; Dessai, R. Raut; Erwin Desa, J. A.; Mitra, S.; Mukhopadhyay, R.

    2013-02-01

    Diffusion of water confined in natural bentonite clay is studied using the quasi-elastic neutron scattering (QENS) technique. X-ray diffraction shows a well-defined crystalline structure of the clay with an interlayer spacing of 13 Å. The QENS experiment has been carried out on hydrated as well as dehydrated clay at 300 K. Significant quasi-elastic broadening was observed in case of hydrated bentonite clay whereas dehydrated clay did not show any broadening over the instrument resolution. Analysis of QENS data reveals that diffusion of water occurs through jump diffusion characterized by random distribution of jump lengths. Diffusion of water in clay is found to be hindered vis a vis bulk water.

  5. Reinforced polyethylene/clay nanocomposites: influence of different silane

    NASA Astrophysics Data System (ADS)

    Yin, Ming; Zhang, Liying; Chen, Xuelong; Hu, Xiao

    2015-03-01

    Montmorillonite (MMT) was first cation exchanged by cetyltrimethyl ammonium bromide (CTAB) and then treated by short chain silane (methyltrimethoxylsilane) or different amount of long chain silane (dodecyltrimethoxylsilane). High density polyethylene (HDPE)/clay nanocomposites were prepared through twin screw extruder using these silane modified clays without any compatibilizer. Thermal gravimetric analysis (TGA) proved the successful grafting of silanes onto clay. The effects of the chain length and content of the silanes on the dispersion state of clay and properties of the composites were studied using X-ray diffraction (XRD), transmission electron microscope (TEM), mechanical tests, creep tests and so on. The results indicate that the grafting of long chain silanes at higher content could improve the compatibility between clay and PE, thus more efficiently enhancing mechanical and creep properties of the composites than other silane treated clays.

  6. Antimicrobial clay-based materials for wound care.

    PubMed

    Gaskell, Elsie E; Hamilton, Ashley R

    2014-04-01

    The historical use of clay minerals for the treatment of wounds and other skin ailments is well documented and continues within numerous human cultures the world over. However, a more scientific inquiry into the chemistry and properties of clay minerals emerged in the 19th century with work investigating their role within health gathering pace since the second half of the 20th century. This review gives an overview of clay minerals and how their properties can be manipulated to facilitate the treatment of infected wounds. Evidence of the antimicrobial and healing effects of some natural clay minerals is presented alongside a range of chemical modifications including metal-ion exchange, the formation of clay-drug composites and the development of various polymer-clay systems. While the evidence for applying these materials to infected wounds is limited, we contextualize and discuss the future of this research.

  7. Interphase vs confinement in starch-clay bionanocomposites.

    PubMed

    Coativy, Gildas; Chevigny, Chloé; Rolland-Sabaté, Agnès; Leroy, Eric; Lourdin, Denis

    2015-03-06

    Starch-clay bionanocomposites containing 1-10% of natural montmorillonite were elaborated by melt processing in the presence of water. A complex macromolecular dynamics behavior was observed: depending on the clay content, an increase of the glass transition temperature and/or the presence of two overlapped α relaxation peaks were detected. Thanks to a model allowing the prediction of the average interparticle distance, and its comparison with the average size of starch macromolecules, it was possible to associate these phenomena to different populations of macromolecules. In particular, it seems that for high clay content (10%), the slowdown of segmental relaxation due to confinement of the starch macromolecules between the clay tactoïds is the predominant phenomenon. While for lower clay contents (3-5%), a significant modification of chain relaxation seems to occur, due to the formation of an interphase by the starch macromolecules in the vicinity of clay nanoparticles coexisting with the bulk polymer.

  8. Determination of geomagnetic archaeomagnitudes from clay pipes

    NASA Astrophysics Data System (ADS)

    Games, K. P.; Baker, M. E.

    1981-02-01

    Archaeomagnitude determinations of a selection of clay pipes dateable to AD 1645+/-10 as well as studies of pottery samples from the same site and of the same age have been made. Values of the magnitude of the ancient magnetic field (Banc), were obtained from two pottery sherds, two pipe bowls and three pipe stems. The values from the sherds and bowls agree within 2% and compare well with the average value of the magnitude of the magnetic field for the seventeenth century as determined by other archaeomagnetic studies. However, the pipe stems give values of Banc which are significantly less than those from the bowls and pottery. We have not yet been able to explain this and thus we suggest that reliable archaeomagnitude determinations can be made from the bowls of clay pipes but not from the stems. Nevertheless, this result provides a new source of material for investigating variations in the geomagnetic field strength over the past 400 yr. Clay pipes have been manufactured in England since the end of the sixteenth century. In the firing process some pipes were broken and disposed of without ever having been smoked. One such collection, discovered at Rainford, Lancashire, in 1978, consisted of a series of discrete dumps including pipes, kiln debris and a small collection of contemporary used earthenware sherds. The internal consideration of the dumps suggested a very short period of activity and archaeologists (P. Davey, personal communication) ascribe all the material to the period 1645+/-10 yr. With such well-dated material, we set out to check whether or not reliable archaeomagnitudes could be obtained from the pipes.

  9. Hood River Passive House

    SciTech Connect

    Hales, David

    2014-01-01

    The Hood River Passive Project was developed by Root Design Build of Hood River Oregon using the Passive House Planning Package (PHPP) to meet all of the requirements for certification under the European Passive House standards. The Passive House design approach has been gaining momentum among residential designers for custom homes and BEopt modeling indicates that these designs may actually exceed the goal of the U.S. Department of Energy's (DOE) Building America program to "reduce home energy use by 30%-50% (compared to 2009 energy codes for new homes). This report documents the short term test results of the Shift House and compares the results of PHPP and BEopt modeling of the project. The design includes high R-Value assemblies, extremely tight construction, high performance doors and windows, solar thermal DHW, heat recovery ventilation, moveable external shutters and a high performance ductless mini-split heat pump. Cost analysis indicates that many of the measures implemented in this project did not meet the BA standard for cost neutrality. The ductless mini-split heat pump, lighting and advanced air leakage control were the most cost effective measures. The future challenge will be to value engineer the performance levels indicated here in modeling using production based practices at a significantly lower cost.

  10. Hood River Passive House

    SciTech Connect

    Hales, D.

    2014-01-01

    The Hood River Passive Project was developed by Root Design Build of Hood River Oregon using the Passive House Planning Package (PHPP) to meet all of the requirements for certification under the European Passive House standards. The Passive House design approach has been gaining momentum among residential designers for custom homes and BEopt modeling indicates that these designs may actually exceed the goal of the U.S. Department of Energy's (DOE) Building America program to reduce home energy use by 30%-50% (compared to 2009 energy codes for new homes). This report documents the short term test results of the Shift House and compares the results of PHPP and BEopt modeling of the project. The design includes high R-Value assemblies, extremely tight construction, high performance doors and windows, solar thermal DHW, heat recovery ventilation, moveable external shutters and a high performance ductless mini-split heat pump. Cost analysis indicates that many of the measures implemented in this project did not meet the BA standard for cost neutrality. The ductless mini-split heat pump, lighting and advanced air leakage control were the most cost effective measures. The future challenge will be to value engineer the performance levels indicated here in modeling using production based practices at a significantly lower cost.

  11. Interactive Mold House Tour

    EPA Pesticide Factsheets

    Get a quick glimpse of some of the most important ways to protect your home from mold by this interactive tour of the Mold House. Room-by-room, you'll learn about common mold issues and how to address them.

  12. Understanding Fair Housing.

    ERIC Educational Resources Information Center

    Commission on Civil Rights, Washington, DC.

    Few rights are as basic as acquiring a home of one's choice. The home and neighborhood are the environment in which families live and rear their children. For minorities, the home usually means housing vacated by whites, who, because of their race as well as ability to pay, are able to acquire a more desirable dwelling elsewhere. Congress, in…

  13. The Children's House

    ERIC Educational Resources Information Center

    Peller, Lili E.

    2013-01-01

    Lili Peller's "The Children's House" essay begins where Maria Montessori left off in her description of space articulations. Peller does not name Montessori specifically as she always had a desire to become independent in her own right as a neo-Freudian child analyst. But the Haus Der Kinder founded in summer of 1922 suggests a total…

  14. Student Housing Cost Study.

    ERIC Educational Resources Information Center

    California Univ., Berkeley. Univ. Residential Building System.

    Target costs for the University Residential Building System (URBS) Project of the University of California are presented. Findings depict the effectiveness of building design and material applications and should be useful in guiding future student housing design work, whether the design utilizes the URBS system or not. Ten recently constructed…

  15. Doll's House Physics

    ERIC Educational Resources Information Center

    Kibble, Bob

    2009-01-01

    School physics rarely stands still for long. Environmental physics is now an option in some post-16 courses in England. The physics of environments, and in particular the built environment, offers a recognizable context in which to see the applications of physics at work. This article considers how a model doll's house might be used to help…

  16. Haunted by Houses

    ERIC Educational Resources Information Center

    McNeece, Molly

    2009-01-01

    Two fourth-grade teachers presented the idea of using the author's art class to inspire the students to write creatively. The theme of scary stories needed an art project to match. The author immediately had a favorite lesson in mind. By putting a small twist on one of her standard "Frank Lloyd Wright House" projects, scary plans began to take…

  17. Keeping House in Memphis.

    ERIC Educational Resources Information Center

    Harrington-Lueker, Donna

    1994-01-01

    About two years into her first urban superintendency, Gerry House knows she cannot solve every problem on-on-one but has created a responsive system to handle parents' complaints. The Memphis school superintendent hopes to boost minority achievement, ensure that all children learn at high levels, bolster community confidence in the schooling…

  18. 24 CFR 1715.27 - Fair housing.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 24 Housing and Urban Development 5 2012-04-01 2012-04-01 false Fair housing. 1715.27 Section 1715.27 Housing and Urban Development Regulations Relating to Housing and Urban Development (Continued) OFFICE OF ASSISTANT SECRETARY FOR HOUSING-FEDERAL HOUSING COMMISSIONER, DEPARTMENT OF HOUSING AND...

  19. 24 CFR 248.147 - Housing standards.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 24 Housing and Urban Development 2 2011-04-01 2011-04-01 false Housing standards. 248.147 Section 248.147 Housing and Urban Development Regulations Relating to Housing and Urban Development (Continued) OFFICE OF ASSISTANT SECRETARY FOR HOUSING-FEDERAL HOUSING COMMISSIONER, DEPARTMENT OF HOUSING AND...

  20. 24 CFR 1715.27 - Fair housing.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 24 Housing and Urban Development 5 2010-04-01 2010-04-01 false Fair housing. 1715.27 Section 1715.27 Housing and Urban Development Regulations Relating to Housing and Urban Development (Continued) OFFICE OF ASSISTANT SECRETARY FOR HOUSING-FEDERAL HOUSING COMMISSIONER, DEPARTMENT OF HOUSING AND...

  1. 12 CFR 1281.15 - Housing plans.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 12 Banks and Banking 7 2011-01-01 2011-01-01 false Housing plans. 1281.15 Section 1281.15 Banks and Banking FEDERAL HOUSING FINANCE AGENCY HOUSING GOALS AND MISSION FEDERAL HOME LOAN BANK HOUSING GOALS Housing Goals § 1281.15 Housing plans. (a) Housing plan requirement. If the Director...

  2. 24 CFR 1715.27 - Fair housing.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 24 Housing and Urban Development 5 2011-04-01 2011-04-01 false Fair housing. 1715.27 Section 1715.27 Housing and Urban Development Regulations Relating to Housing and Urban Development (Continued) OFFICE OF ASSISTANT SECRETARY FOR HOUSING-FEDERAL HOUSING COMMISSIONER, DEPARTMENT OF HOUSING AND...

  3. 24 CFR 248.147 - Housing standards.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 24 Housing and Urban Development 2 2010-04-01 2010-04-01 false Housing standards. 248.147 Section 248.147 Housing and Urban Development Regulations Relating to Housing and Urban Development (Continued) OFFICE OF ASSISTANT SECRETARY FOR HOUSING-FEDERAL HOUSING COMMISSIONER, DEPARTMENT OF HOUSING AND...

  4. 12 CFR 1281.15 - Housing plans.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 12 Banks and Banking 10 2014-01-01 2014-01-01 false Housing plans. 1281.15 Section 1281.15 Banks and Banking FEDERAL HOUSING FINANCE AGENCY HOUSING GOALS AND MISSION FEDERAL HOME LOAN BANK HOUSING GOALS Housing Goals § 1281.15 Housing plans. (a) Housing plan requirement. If the Director...

  5. 24 CFR 1715.27 - Fair housing.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 24 Housing and Urban Development 5 2014-04-01 2014-04-01 false Fair housing. 1715.27 Section 1715.27 Housing and Urban Development Regulations Relating to Housing and Urban Development (Continued) OFFICE OF ASSISTANT SECRETARY FOR HOUSING-FEDERAL HOUSING COMMISSIONER, DEPARTMENT OF HOUSING AND...

  6. 24 CFR 248.147 - Housing standards.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 24 Housing and Urban Development 2 2013-04-01 2013-04-01 false Housing standards. 248.147 Section 248.147 Housing and Urban Development Regulations Relating to Housing and Urban Development (Continued) OFFICE OF ASSISTANT SECRETARY FOR HOUSING-FEDERAL HOUSING COMMISSIONER, DEPARTMENT OF HOUSING AND...

  7. 24 CFR 248.147 - Housing standards.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 24 Housing and Urban Development 2 2012-04-01 2012-04-01 false Housing standards. 248.147 Section 248.147 Housing and Urban Development Regulations Relating to Housing and Urban Development (Continued) OFFICE OF ASSISTANT SECRETARY FOR HOUSING-FEDERAL HOUSING COMMISSIONER, DEPARTMENT OF HOUSING AND...

  8. 24 CFR 248.147 - Housing standards.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 24 Housing and Urban Development 2 2014-04-01 2014-04-01 false Housing standards. 248.147 Section 248.147 Housing and Urban Development Regulations Relating to Housing and Urban Development (Continued) OFFICE OF ASSISTANT SECRETARY FOR HOUSING-FEDERAL HOUSING COMMISSIONER, DEPARTMENT OF HOUSING AND...

  9. 24 CFR 1715.27 - Fair housing.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 24 Housing and Urban Development 5 2013-04-01 2013-04-01 false Fair housing. 1715.27 Section 1715.27 Housing and Urban Development Regulations Relating to Housing and Urban Development (Continued) OFFICE OF ASSISTANT SECRETARY FOR HOUSING-FEDERAL HOUSING COMMISSIONER, DEPARTMENT OF HOUSING AND...

  10. 12 CFR 1281.15 - Housing plans.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 12 Banks and Banking 9 2012-01-01 2012-01-01 false Housing plans. 1281.15 Section 1281.15 Banks and Banking FEDERAL HOUSING FINANCE AGENCY HOUSING GOALS AND MISSION FEDERAL HOME LOAN BANK HOUSING GOALS Housing Goals § 1281.15 Housing plans. (a) Housing plan requirement. If the Director...

  11. 12 CFR 1281.15 - Housing plans.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 12 Banks and Banking 9 2013-01-01 2013-01-01 false Housing plans. 1281.15 Section 1281.15 Banks and Banking FEDERAL HOUSING FINANCE AGENCY HOUSING GOALS AND MISSION FEDERAL HOME LOAN BANK HOUSING GOALS Housing Goals § 1281.15 Housing plans. (a) Housing plan requirement. If the Director...

  12. What makes a natural clay antibacterial?

    USGS Publications Warehouse

    Williams, Lynda B.; Metge, David W.; Eberl, Dennis D.; Harvey, Ronald W.; Turner, Amanda G.; Prapaipong, Panjai; Port-Peterson, Amisha T.

    2011-01-01

    Chemical analyses of E. coli killed by aqueous leachates of an antibacterial clay show that intracellular concentrations of Fe and P are elevated relative to controls. Phosphorus uptake by the cells supports a regulatory role of polyphosphate or phospholipids in controlling Fe2+. Fenton reaction products can degrade critical cell components, but we deduce that extracellular processes do not cause cell death. Rather, Fe2+ overwhelms outer membrane regulatory proteins and is oxidized when it enters the cell, precipitating Fe3+ and producing lethal hydroxyl radicals.

  13. THE TOWER HOUSE, LOOKING WEST. The tower house provided a ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    THE TOWER HOUSE, LOOKING WEST. The tower house provided a water tank on the second floor that gravity fed water to the Kineth house and farm buildings. The one-story addition to the west of the tower provided workshop space. The hog shed is seen on the left of the image and the concrete foundation of the upright silo is in the foreground on the right. - Kineth Farm, Tower House, 19162 State Route 20, Coupeville, Island County, WA

  14. Dynamics of Water Confined in Synthetic Saponite Clays

    SciTech Connect

    Prabhudesai, S. A.; Sharma, V. K.; Mitra, S.; Mukhopadhyay, R.; Chakrabarty, D.; Vicente, Miguel A.

    2011-07-15

    The dynamics of water in two synthetic saponite clays (treated by microwave) with different interlayer spacing has been studied using the quasielastic neutron scattering technique. A model in which the molecules undergo random jump diffusion describes the dynamics of water in both clays. The dynamics of water confined in both saponite clays considered here is found to be hindered in comparison to the bulk phase. It is found that diffusivity increases for samples having higher interlayer spacing.

  15. Bentonite Clay Adsorption Procedure for Concentrating Enteroviruses from Water.

    DTIC Science & Technology

    1992-07-01

    AD-A255 305 _ TECHNICAL REPORT 9203 BENTONITE CLAY ADSORPTION PROCEDURE FOR CONCENTRATING ENTEROVIRUSES FROM WATER STEPHEN A. SCHAUB D T IC GORDON W...Bentonite Clay Adsorption Procedure for Concentrating Enteroviruses from Water 12. PERSONAL AUTHOR(S) S.A. Schaub, G.W. Taylor, C.A. Sorber, and W.E...number) L/ A method of adsorbing enteroviruses to bentonite clay was developed for use as a concentration technique designed to sample low levels of

  16. Clay exfoliation and polymer/clay aerogels by supercritical carbon dioxide

    PubMed Central

    Longo, Simona; Mauro, Marco; Daniel, Christophe; Galimberti, Maurizio; Guerra, Gaetano

    2013-01-01

    Supercritical carbon dioxide (scCO2) treatments of a montmorillonite (MMT) intercalated with ammonium cations bearing two long hydrocarbon tails (organo-modified MMT, OMMT) led to OMMT exfoliation, with loss of the long-range order in the packing of the hydrocarbon tails and maintenance of the long-range order in the clay layers. The intercalated and the derived exfoliated OMMT have been deeply characterized, mainly by X-ray diffraction analyses. Monolithic composite aerogels, with large amounts of both intercalated and exfoliated OMMT and including the nanoporous-crystalline δ form of syndiotactic polystyrene (s-PS), have been prepared, by scCO2 extractions of s-PS-based gels. Also for high OMMT content, the gel and aerogel preparation procedures occur without re-aggregation of the exfoliated clay, which is instead observed for other kinds of polymer processing. Aerogels with the exfoliated OMMT have more even dispersion of the clay layers, higher elastic modulus and larger surface area than aerogels with the intercalated OMMT. Extremely light materials with relevant transport properties could be prepared. Moreover, s-PS-based aerogels with exfoliated OMMT could be helpful for the handling of exfoliated clay minerals. PMID:24790956

  17. The influence of clay type on reduction of water repellency by applied clays: a review of some West Australian work

    NASA Astrophysics Data System (ADS)

    McKissock, I.; Walker, E. L.; Gilkes, R. J.; Carter, D. J.

    2000-05-01

    In Western Australia water repellency mostly occurs in soils with sandy texture; the severity of water repellency is influenced by very small changes in clay content. Additions of 1-2% clay can prevent water repellency and for some time clay amendments have been used by farmers to overcome water repellency. The aim of this study was to assess the effectiveness of clays in ameliorating water repellency. Clays were assessed for effectiveness in reducing water repellency by mixing with water repellent sands and measuring water drop penetration time (WDPT) on the resultant mixtures. WDPT was measured on the initial mixtures, a wetting and drying cycle was imposed and WDPT measured again. Two sets of clays were assessed: four simple clays containing kaolinite (2) or smectite (2) group minerals and a group of clayey subsoil materials which had been collected by farmers. For the simple clays, clay mineral type was the most significant factor in determining response. Kaolin was much more effective than smectite. Imposition of a wetting and drying cycle greatly reduced water repellency. The dominant exchangeable cation of the clays (sodium or calcium) had little effect on the ability of the clays to reduce water repellency. The factor that was most predictive of the effectiveness of clayey subsoils materials in reducing water repellency was texture: clay content ( r2=0.18) or clay+silt content ( r2=0.23). These properties were more predictive of water repellency values after the wetting and drying cycle treatment ( r2=0.36, r2=0.44). The proportion of the clay fraction that consisted of kaolinite was next most predictive in determining effectiveness which is again indicative of kaolin group minerals being more effective than smectite group minerals. The exchangeable sodium percentage and clay dispersibility had no systematic effect on the ability of these clays to reduce water repellency. These results provide a basis for developing a practical field procedure to enable

  18. Pair housing induced feeding suppression: individual housing not novelty.

    PubMed

    Lopak, V; Eikelboom, R

    Male rats that are moved from individual to pair housing suppress their feeding for a few days [O'Connor R, Eikelboom R. The effects of changes in housing on feeding and wheel running. Physiol Behav 2000;68:361-371]. The present study explored whether the suppression was a result of the period of individual housing or the novelty of the other animal. Two groups of 16 rats were pair-housed and one group of rats was individually housed for 21 days. The individually housed rats were then pair-housed (IP group) and rats in one of the pair-housed groups were re-housed with novel partners (NP group), while rats in the other pair-housed group remained with the same partner (SP group). Feeding was suppressed only for rats in the IP group, suggesting that the novelty of the partner did not suppress feeding, but rather, the change from individual to pair housing did. Water consumption was also measured, but was unaffected by the re-housing manipulation.

  19. Astronaut Clay Anderson Speaks With S.C. Students

    NASA Video Gallery

    From NASA's International Space Station Mission Control Center, NASA astronaut Clay Anderson participates in a Digital Learning Network (DLN) event with students at Crayton Middle School, Columbia,...

  20. Microbiological characterisation of southern African medicinal and cosmetic clays.

    PubMed

    Mpuchane, Sisai F; Ekosse, Georges-Ivo E; Gashe, Berhanu A; Morobe, Isaac; Coetzee, Stephan H

    2010-02-01

    The effects of traditionally used medicinal and cosmetic clays in southern Africa on selected microorganisms were studied using microbiological media. The clay pH, microchemical composition, kind of associated microorganisms and antimicrobial activity of clays against test microorganisms were determined. The clays contained varying numbers of microorganisms which ranged from 0 up to 105 CFU/g. Clay pH ranged from 2.3-8.9. Neither Escherichia coli, nor other faecal coliforms were detected. Clays of pH value of <4 displayed antimicrobial activities. Clays which were active against test microorganisms had Na(2)O, Al(2)O(3), SiO(2), SO(3), CuO or Cl(2)O as major components. Microbial activity of clays was attributed mainly to low pH but cations such as Cu, Al, S or Cl and various anions might have contributed to the microbicidal effects. No antimicrobial activity was established for many of the clays commonly used in the treatment of common ailments of microbial origin.

  1. Relationship between sediment clay minerals and total mercury.

    PubMed

    Kongchum, Manoch; Hudnall, Wayne H; DeLaune, R D

    2011-01-01

    A group of 262 sediment samples were collected from various lakes, rivers, reservoirs, and bayous of Louisiana. All samples were analyzed for total mercury. Twenty nine of the samples with total mercury content ranging from 11 to 401 ppb (μg/kg) were analyzed for clay minerals and other sediment physical and chemical properties. Clay content in sediments varied from 3 to 72%. Clay minerals were determined by X-ray diffraction (XRD) technique. Identification of clay minerals was determined by MacDiff software and quantification of clay minerals was obtained by Peak Height Percentage (PHP) calculation. The dominant clay mineral was Hydrated Interlayer Vermiculite (HIV), which represented 51-83% of the total clay mineral. Significant linear correlations were observed between Hg and total clay content (r=0.538**). However Smectite was the only individual clay type correlated (r=0.465**) with mercury in sediment. Cation exchange capacity (r=0.404*), organic matter (r=0.577**), and sulfur (r=0.676**) were also correlated significantly with mercury level in sediment.

  2. Recent advances in clay mineral-containing nanocomposite hydrogels.

    PubMed

    Zhao, Li Zhi; Zhou, Chun Hui; Wang, Jing; Tong, Dong Shen; Yu, Wei Hua; Wang, Hao

    2015-12-28

    Clay mineral-containing nanocomposite hydrogels have been proven to have exceptional composition, properties, and applications, and consequently have attracted a significant amount of research effort over the past few years. The objective of this paper is to summarize and evaluate scientific advances in clay mineral-containing nanocomposite hydrogels in terms of their specific preparation, formation mechanisms, properties, and applications, and to identify the prevailing challenges and future directions in the field. The state-of-the-art of existing technologies and insights into the exfoliation of layered clay minerals, in particular montmorillonite and LAPONITE®, are discussed first. The formation and structural characteristics of polymer/clay nanocomposite hydrogels made from in situ free radical polymerization, supramolecular assembly, and freezing-thawing cycles are then examined. Studies indicate that additional hydrogen bonding, electrostatic interactions, coordination bonds, hydrophobic interaction, and even covalent bonds could occur between the clay mineral nanoplatelets and polymer chains, thereby leading to the formation of unique three-dimensional networks. Accordingly, the hydrogels exhibit exceptional optical and mechanical properties, swelling-deswelling behavior, and stimuli-responsiveness, reflecting the remarkable effects of clay minerals. With the pivotal roles of clay minerals in clay mineral-containing nanocomposite hydrogels, the nanocomposite hydrogels possess great potential as superabsorbents, drug vehicles, tissue scaffolds, wound dressing, and biosensors. Future studies should lay emphasis on the formation mechanisms with in-depth insights into interfacial interactions, the tactical functionalization of clay minerals and polymers for desired properties, and expanding of their applications.

  3. Clays and Clay Minerals and their environmental application in Food Technology

    NASA Astrophysics Data System (ADS)

    del Hoyo Martínez, Carmen; Cuéllar Antequera, Jorge; Sánchez Escribano, Vicente; Solange Lozano García, Marina; Cutillas Díez, Raul

    2013-04-01

    The clay materials have led to numerous applications in the field of public health (del Hoyo, 2007; Volzone, 2007) having been demonstrated its effectiveness as adsorbents of all contaminants. Some biodegradable materials are used for for adsorption of chemical contaminants: lignins (Valderrabano et al., 2008) and also clays and clay minerals, whose colloidal properties, ease of generating structural changes, abundance in nature, and low cost make them very suitable for this kind of applications. Among the strategies used at present to preserve the quality of the water and this way to diminish the environmental risk that supposes the chemical pollution, stands out the use of adsorbents of under cost, already they are natural or modified, to immobilize these compounds and to avoid the pollution of the water with the consequent reduction of environmental and economic costs Thanks to the development of the science and the technology of the nourishment in the last 50 years, there have revealed itself several new substances that can fulfill beneficial functions in the food, and these substances, named food additives, are today within reach of all. The food additives recover a very important role in the complex nourishing supply. The additives fulfill several useful functions in the food, which often we give for sat. Nevertheless the widespread use of food additives in the food production also influences the public health. The food industries, which are very important for the economy, spill residues proved from its activity that they have to be controlled to evaluate the environmental impact and to offer the necessary information about the quantitative evaluation of the chemical risk of the use of food additives for the public health. We have studied the adsorption of several contaminants by natural or modified clays, searching their interaction mechanisms and the possible recycling of these materials for environmental purposes and prevention of the health. References

  4. Prions, Radionuclides and Clays: Impact of clay interlayer "acidity" on toxic compound speciation

    NASA Astrophysics Data System (ADS)

    Charlet, L.; Hureau, C.; Sobolev, O.; Cuello, G.; Chapron, Y.

    2007-05-01

    The physical and chemical processes that are the basis of contaminant retardation in clay rich medium, such as soil or nuclear waste repository, have been studied at the molecular level by a combination of molecular dynamics (MD), electron paramagnetic spectroscopy (EPR) and neutron diffraction with isotopic substitution (NDIS). The speciation of contaminants such as Sm, a radionuclide analogue, and Cu, bound to Prion protein (PrP), has been studied upon adsorption in clay interlayers. We used as molecular probe the P5-Cu(II) complex, where the P5 pentapeptide(92-96 PrP residues) represents one of the five Cu(II) binding site present in PrP, the key protein involved in diseases known as transmissible spongiform encephalopathies. In both cases, the pH of the interlayer has been inferred from the metal ion coordination, here used as a molecular reporter. In circum neutral pH waters, samarium is present as Sm(OH)3° species and should not be adsorbed in clay interlayer by "cation exchange" unless its hydrolysis is altered. Samarium NDIS results indicate that whether the number of oxygen nearest neighbours varies only from 8.5 to 7, as Sm penetrates the interlayer, the number of hydrogen nearest neighbours drops from 12 to 6. The high affinity of clay for Sm shows that a change in Sm hydrolysis occurs in the clay interlayer, but is directly followed by the formation of a surface complex with montmorillonite siloxane plane functional groups which prevents the determination of a "local pH". Conversely, has been found to be a much more sensitive interlayer water pH probe. and this peptide domain is involved in the misfolding of the protein,a transconformation which may lead to the pathogenic PrPSc form. We have therefore studied by EPR spectroscopy the adsorption of Cu(II)-P5 complexes on montmorillonite, and found the clay to have a large and selective adsorption capacity for the various [Cu(P5)H-n](2-n)+ complexes where n is the number of deprotonated amido function

  5. Lens window simplifies TDL housing

    NASA Technical Reports Server (NTRS)

    Robinson, D. M.; Rowland, C. W.

    1979-01-01

    Lens window seal in tunable-diode-laser housing replaces plan parallel window. Lens seals housing and acts as optical-output coupler, thus eliminating need for additional reimaging or collimating optics.

  6. Geosynthetic clay liners - slope stability field study

    SciTech Connect

    Carson, D.A.; Daniel, D.E.; Koerner, R.M.; Bonaparte, R.

    1997-12-31

    A field research project was developed to examine the internal shear performance of geosynthetic clay liners (GCLs). Several combinations of cross sections were assembled using GCL materials that were available at the time of project initiation. The cross sections utilized were intended to simulate landfill cover applications. Thirteen (13) resulting test plots were constructed on two different slope angles, and each plot is instrumented for physical displacement and soil moisture characteristics. Test plots were constructed in a manner that dictated the shear plane in the clay portion of the GCL product. The project purpose is to assess field performance and to verify design parameters associated with the application of GCLs in waste containment applications. Interim research data shows that test slopes on 2H:1V show global deformation, but little internal shear evidence, and the 3H:1V slopes show little deformation at approximately 650 days. The research is ongoing, and this paper presents the most recent information available from the project.

  7. Can clays ensure nuclear waste repositories?

    PubMed Central

    Zaoui, A.; Sekkal, W.

    2015-01-01

    Research on argillite as a possible host rock for nuclear waste disposal is still an open subject since many issues need to be clarified. In the Underground Research Laboratories constructed for this purpose, a damaged zone around the excavation has been systematically observed and characterized by the appearance of micro-fissures. We analyse here -at nanoscale level- the calcite/clay assembly, the main constituents of argillite, under storage conditions and show the fragility of the montmorillonite with respect to calcite. Under anisotropic stress, we have observed a shear deformation of the assembly with the presence of broken bonds in the clay mineral, localised in the octahedral rather than the tetrahedral layers. The stress/strain curve leads to a failure strength point at 18.5 MPa. The obtained in-plane response of the assembly to perpendicular deformation is characterized by smaller perpendicular moduli Ez = 48.28 GPa compared to larger in-plane moduli Ex = 141.39 GPa and Ey = 134.02 GPa. Our calculations indicate the instability of the assembly without water molecules at the interface in addition to an important shear deformation. PMID:25742950

  8. A structural analysis model for clay caps

    SciTech Connect

    Wu, Tsu-te; Yau, Wen Foo

    1993-12-31

    This paper presents a structural analysis model for clay caps used in the landfill of low-level nuclear waste to minimize the migration of fluid through the soil. The clay cap resting on the soil foundation is treated as an axially symmetric elastic plate supported by an elastic foundation. A circular hole (concentric with the plate) in the elastic foundation represents an underlying cavity formed in the landfill due to waste decomposition and volume reduction. Unlike the models that commonly represent the soil foundation with equivalent springs, this model treats the foundation as a semi-infinite space and accounts for the work done by both compression and shear stresses in the foundation. The governing equation of the plate is based upon the classical theory of plate bending, whereas the governing equation derived by using Vlasov`s general variational method describes the soil foundation. The solutions are expressed in terms of Basset functions. A FORTRAN program was written to carry out the numerical calculations.

  9. The washability of lignites for clay removal

    SciTech Connect

    Oteyaka, B.; Yamik, A.; Ucar, A.; Sahbaz, O.; Demir, U.

    2008-07-01

    In the washability research of the Seyitomer Lignites (Kutahya-Turkey), with lower calorific value (1,863 kcal/kg) and high ash content (51.91%), by heavy medium separation, it was found out that middling clay in the coal had an effect to change the medium density. To prevent this problem, a trommel sieve with 18 and 5 mm aperture diameter was designed, and the clay in the coal was tried to be removed using it before the coal was released to heavy medium. Following that, the obtained coal in -100 + 18 mm and -18 + 5 mm fractions was subjected to sink and float test having 1.4 gcm{sup -3} and 1.7 gcm{sup -3} medium densities (-5 mm fraction will be evaluated in a separate work). Depending on the raw coal, with the floating of -100 + 18 mm and -18 + 5 mm size fraction in 1.4 gcm{sup -3} medium density, clean coal with 60.10% combustible matter recovery, 19.12% ash, and 3,150 kcal/kg was obtained. Also floating of the samples sinking in 1.4 gcm{sup -3} in the medium density (1.7 gcm{sup -3}), middling with 18.70% combustible matter recovery, 41.93% ash, 2,150 kcal/kg, and tailing having 78.31% ash were obtained.

  10. Can clays ensure nuclear waste repositories?

    NASA Astrophysics Data System (ADS)

    Zaoui, A.; Sekkal, W.

    2015-03-01

    Research on argillite as a possible host rock for nuclear waste disposal is still an open subject since many issues need to be clarified. In the Underground Research Laboratories constructed for this purpose, a damaged zone around the excavation has been systematically observed and characterized by the appearance of micro-fissures. We analyse here -at nanoscale level- the calcite/clay assembly, the main constituents of argillite, under storage conditions and show the fragility of the montmorillonite with respect to calcite. Under anisotropic stress, we have observed a shear deformation of the assembly with the presence of broken bonds in the clay mineral, localised in the octahedral rather than the tetrahedral layers. The stress/strain curve leads to a failure strength point at 18.5 MPa. The obtained in-plane response of the assembly to perpendicular deformation is characterized by smaller perpendicular moduli Ez = 48.28 GPa compared to larger in-plane moduli Ex = 141.39 GPa and Ey = 134.02 GPa. Our calculations indicate the instability of the assembly without water molecules at the interface in addition to an important shear deformation.

  11. Caffeine and performance in clay target shooting.

    PubMed

    Share, Bianca; Sanders, Nick; Kemp, Justin

    2009-04-01

    Controversy surrounds the influence that caffeine has on accuracy and cognitive performance in precision activities such as shooting and archery. The aim of this study was to assess the effects of two doses of caffeine on shooting performance, reaction time, and target tracking times in the sport of clay target shooting. A randomized, double-blind, placebo-controlled design was undertaken by seven elite male shooters from the double-trap discipline. Three intervention trials (2 mg caffeine . kg(-1) body mass (BM); 4 mg caffeine . kg(-1) BM; placebo) were undertaken, in which shooters completed four rounds per trial of 50 targets per round. Performance accuracy (score) and digital video footage (for determination of reaction time and target tracking times) were gathered during competition. Data were analysed using repeated-measures analysis of variance. No differences in shooting accuracy, reaction time or target tracking times among the three intervention trials or across the four rounds within each intervention were observed (P > 0.05). The results indicate that ingestion of < or =4 mg caffeine . kg(-1) BM does not provide performance benefits to elite performers of clay target shooting in the double-trap discipline.

  12. Naphthene upgrading with pillared synthetic clay catalysts

    SciTech Connect

    Sharma, R.K.; Olson, E.S.

    1995-12-31

    Catalytic hydrotreatment of methylcyclohexane was investigated to model upgrading of coal-derived naphthenes. Nickel-substituted synthetic mica montmorillonite (NiSMM), alumina-pillared NiSMM and Zirconia-pillared NiSMM were prepared and tested for hydrocracking and hydroisomerization of methylcyclohexane. Infrared and thermal desorption studies of the pyridine-adsorbed catalysts indicated the presence of Lewis and Bronsted acid sites. Total acidity and surface area increased with pillaring of NiSMM with polyoxy aluminum and polyoxy zirconium cations. Methylcyclohexane was reacted with these catalysts under a variety of conditions. Pillared clays gave higher gas yields and higher hydrocracking but lower hydroisomerization activity than nonpillared clay. The majority of the products were branched alkanes (isoparaffinic). These catalysts effectively use hydrogen as indicated by the minimal formation of aromatic hydrocarbons, coke, or other oligomeric materials. The effect of various operating conditions, i.e., reaction temperature, contact time, H{sub 2} pressure, and catalyst, on the product distribution will be described.

  13. Can clays ensure nuclear waste repositories?

    PubMed

    Zaoui, A; Sekkal, W

    2015-03-06

    Research on argillite as a possible host rock for nuclear waste disposal is still an open subject since many issues need to be clarified. In the Underground Research Laboratories constructed for this purpose, a damaged zone around the excavation has been systematically observed and characterized by the appearance of micro-fissures. We analyse here -at nanoscale level- the calcite/clay assembly, the main constituents of argillite, under storage conditions and show the fragility of the montmorillonite with respect to calcite. Under anisotropic stress, we have observed a shear deformation of the assembly with the presence of broken bonds in the clay mineral, localised in the octahedral rather than the tetrahedral layers. The stress/strain curve leads to a failure strength point at 18.5 MPa. The obtained in-plane response of the assembly to perpendicular deformation is characterized by smaller perpendicular moduli Ez = 48.28 GPa compared to larger in-plane moduli Ex = 141.39 GPa and Ey = 134.02 GPa. Our calculations indicate the instability of the assembly without water molecules at the interface in addition to an important shear deformation.

  14. Quantum-chemical modeling of smectite clays

    NASA Technical Reports Server (NTRS)

    Aronowitz, S.; Coyne, L.; Lawless, J.; Rishpon, J.

    1982-01-01

    A self-consistent charge extended Hueckel program is used in modeling isomorphic substitution of Al(3+) by Na(+), K(+), Mg(2+), Fe(2+), and Fe(3+) in the octahedral layer of a dioctahedral smectite clay, such as montmorillonite. Upon comparison of the energies involved in the isomorphic substitution, it is found that the order for successful substitution is as follows: Al(3+), Fe(3+), Mg(2+), Fe(2+), Na(+), which is equivalent to Ca(2+), and then K(+). This ordering is found to be consistent with experimental observation. The calculations also make it possible to determine the possible penetration of metal ions into the clay's 2:1 crystalline layer. For the cases studied, this type of penetration can occur at elevated temperatures into regions where isomorphic substitution has occurred with metal ions that bear a formal charge of less than 3+. The computed behavior of the electronic structure in the presence of isomorphic substitution is found to be similar to behavior associated with semiconductors.

  15. Credit WCT. Original 21/4"x21/4" color negative is housed in the ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Credit WCT. Original 2-1/4"x2-1/4" color negative is housed in the JPL Photography Laboratory, Pasadena, California. At one time, Building 4285/E-86 accommodated tensile testing of propellant samples. This view shows a tensile strength tester set up for propellant tests, under the supervision of JPL staff member Milton Clay (JPL negative no. JPL-10291AC, 27 January 1989) - Jet Propulsion Laboratory Edwards Facility, Casting & Curing Building, Edwards Air Force Base, Boron, Kern County, CA

  16. Housing for Migrant Agricultural Workers.

    ERIC Educational Resources Information Center

    Simons, J. W.; And Others

    Intended to assist the producer in meeting the housing regulations of Federal, state, and local governments for migratory workers and thereby to attract better labor through adequate housing, this agricultural handbook contains discussions of the migrant-labor situation; regulations and standards; general housing considerations (i.e., length of…

  17. College and University Apartment Housing.

    ERIC Educational Resources Information Center

    Casey-Powell, Deborah, Ed.

    The purpose of this book is to update housing professionals on the current issues and future trends facing college and university apartment operations in the 21st century. Its chapters are: (1) "The History of Apartment Housing" (Rena Buchan); (2) "Research in Apartment Housing" (Donald Whalen); (3) "Community Services and…

  18. Literacy Mediation in Neighbourhood Houses

    ERIC Educational Resources Information Center

    Thompson, Sally

    2015-01-01

    Interactions between staff in Neighbourhood Houses, and the socially and educationally disadvantaged community members who visit Neighbourhood Houses, have been viewed through many lenses, including community development, social support, caring and compassion. This paper looks at Neighbourhood Houses as sites of pedagogical practice. More…

  19. Passive retrofits for Navy housing

    SciTech Connect

    Hibbert, R.; Miles, C.; Jones, R.; Peck, C.; Anderson, J.; Jacobson, V.; Dale, A.M.

    1985-01-01

    A project to assess and initiate passive solar energy retrofits to US Navy family housing is described. The current data base for Navy housing (ECOP), and its enhancement for passive solar purposes options proposed for Navy housing are explained. The analysis goals and methods to evaluate the retrofits are discussed. An educational package to explain the retrofits is described.

  20. Thermal Impact on Damaged Boom Clay and Opalinus Clay: Permeameter and Isostatic Tests with μCT Scanning

    NASA Astrophysics Data System (ADS)

    Chen, G. J.; Maes, T.; Vandervoort, F.; Sillen, X.; Van Marcke, P.; Honty, M.; Dierick, M.; Vanderniepen, P.

    2014-01-01

    Within the framework of the TIMODAZ project, permeameter tests and isostatic tests were performed on Boom Clay and Opalinus Clay in order to assess the impact of temperature, pore water composition, and confining stress on the sealing of damaged samples of Boom Clay and Opalinus Clay. A microfocus X-ray computed tomography technique was used to visualize the evolution of the sealing process. Compared to the fast sealing of Boom Clay, the sealing of Opalinus Clay was much slower. The heating showed a significant, favorable impact on the sealing behavior of Opalinus Clay under permeameter test conditions, while the sealing behavior of Boom Clay appeared to be unaffected. Tests performed under isostatic conditions did not reveal a significant influence of a heating-cooling cycle on the sealing behavior of these clays. The reappearance of the fractures or holes in the samples after dismantling confirms earlier observations which showed that after sealing, the original mechanical properties are not recovered. In other words, a heating cycle does not seem to induce healing.

  1. Toxicological evaluation of clay minerals and derived nanocomposites: a review.

    PubMed

    Maisanaba, Sara; Pichardo, Silvia; Puerto, María; Gutiérrez-Praena, Daniel; Cameán, Ana M; Jos, Angeles

    2015-04-01

    Clays and clay minerals are widely used in many facets of our society. This review addresses the main clays of each phyllosilicate groups, namely, kaolinite, montmorillonite (Mt) and sepiolite, placing special emphasis on Mt and kaolinite, which are the clays that are more frequently used in food packaging, one of the applications that are currently exhibiting higher development. The improvements in the composite materials obtained from clays and polymeric matrices are remarkable and well known, but the potential toxicological effects of unmodified or modified clay minerals and derived nanocomposites are currently being investigated with increased interest. In this sense, this work focused on a review of the published reports related to the analysis of the toxicological profile of commercial and novel modified clays and derived nanocomposites. An exhaustive review of the main in vitro and in vivo toxicological studies, antimicrobial activity assessments, and the human and environmental impacts of clays and derived nanocomposites was performed. From the analysis of the scientific literature different conclusions can be derived. Thus, in vitro studies suggest that clays in general induce cytotoxicity (with dependence on the clay, concentration, experimental system, etc.) with different underlying mechanisms such as necrosis/apoptosis, oxidative stress or genotoxicity. However, most of in vivo experiments performed in rodents showed no clear evidences of systemic toxicity even at doses of 5000mg/kg. Regarding to humans, pulmonary exposure is the most frequent, and although clays are usually mixed with other minerals, they have been reported to induce pneumoconiosis per se. Oral exposure is also common both intentionally and unintentionally. Although they do not show a high toxicity through this pathway, toxic effects could be induced due to the increased or reduced exposure to mineral elements. Finally, there are few studies about the effects of clay minerals on

  2. [Mechanism of tritium persistence in porous media like clay minerals].

    PubMed

    Wu, Dong-Jie; Wang, Jin-Sheng; Teng, Yan-Guo; Zhang, Ke-Ni

    2011-03-01

    To investigate the mechanisms of tritium persistence in clay minerals, three types of clay soils (montmorillonite, kaolinite and illite) and tritiated water were used in this study to conduct the tritium sorption tests and the other related tests. Firstly, the ingredients, metal elements and heat properties of clay minerals were studied with some instrumental analysis methods, such as ICP and TG. Secondly, with a specially designed fractionation and condensation experiment, the adsorbed water, the interlayer water and the structural water in the clay minerals separated from the tritium sorption tests were fractionated for investigating the tritium distributions in the different types of adsorptive waters. Thirdly, the location and configuration of tritium adsorbed into the structure of clay minerals were studied with infrared spectrometry (IR) tests. And finally, the forces and mechanisms for driving tritium into the clay minerals were analyzed on the basis of the isotope effect of tritium and the above tests. Following conclusions have been reached: (1) The main reason for tritium persistence in clay minerals is the entrance of tritium into the adsorbed water, the interlayer water and the structural water in clay minerals. The percentage of tritium distributed in these three types of adsorptive water are in the range of 13.65% - 38.71%, 0.32% - 5.96%, 1.28% - 4.37% of the total tritium used in the corresponding test, respectively. The percentages are different for different types of clay minerals. (2) Tritium adsorbed onto clay minerals are existed in the forms of the tritiated hydroxyl radical (OT) and the tritiated water molecule (HTO). Tritium mainly exists in tritiated water molecule for adsorbed water and interlayer water, and in tritiated hydroxyl radical for structural water. (3) The forces and effects driving tritium into the clay minerals may include molecular dispersion, electric charge sorption, isotope exchange and tritium isotope effect.

  3. Impact-Induced Clay Mineral Formation and Distribution on Mars

    NASA Technical Reports Server (NTRS)

    Rivera-Valentin, E. G.; Craig, P. I.

    2015-01-01

    Clay minerals have been identified in the central peaks and ejecta blankets of impact craters on Mars. Several studies have suggested these clay minerals formed as a result of impact induced hydrothermalism either during Mars' Noachian era or more recently by the melting of subsurface ice. Examples of post-impact clay formation is found in several locations on Earth such as the Mjolnir and Woodleigh Impact Structures. Additionally, a recent study has suggested the clay minerals observed on Ceres are the result of impact-induced hydrothermal processes. Such processes may have occurred on Mars, possibly during the Noachian. Distinguishing between clay minerals formed preor post-impact can be accomplished by studying their IR spectra. In fact, showed that the IR spectra of clay minerals is greatly affected at longer wavelengths (i.e. mid-IR, 5-25 micron) by impact-induced shock deformation while the near-IR spectra (1.0-2.5 micron) remains relatively unchanged. This explains the discrepancy between NIR and MIR observations of clay minerals in martian impact craters noted. Thus, it allows us to determine whether a clay mineral formed from impact-induced hydrothermalism or were pre-existing and were altered by the impact. Here we study the role of impacts on the formation and distribution of clay minerals on Mars via a fully 3-D Monte Carlo cratering model, including impact- melt production using results from modern hydrocode simulations. We identify regions that are conducive to clay formation and the location of clay minerals post-bombardment.

  4. Supportive housing in Brooklyn.

    PubMed

    Burke, Natasha

    2005-01-01

    Since 1977, Saint Vincent Catholic Medical Centers of New York City has been creating and maintaining supportive housing offerings for at-risk populations, such as individuals with HIV/AIDS, those with substance abuse challenges, and the mentally ill. By providing a continuum of medical and social services, the organization aims to help residents stabilize and rebuild their lives. Saint Vincent sees empowerment as a key step toward helping individuals maintain their health, re-enter the community, seek employment, and pursue other goals. Some of the supportive services Saint Vincent offers in its housing communities are care coordination, counseling, peer support networks, self-help groups, leisure activities, help with finances, and referrals to community agencies offering other resources. Recognizing the importance of job training and assistance, the system also offers a unique program in which mentally ill individuals are able to work in a recycling center or office cleaning business, both of which are owned by Saint Vincent.

  5. Housing characteristics 1993

    SciTech Connect

    1995-06-01

    This report, Housing Characteristics 1993, presents statistics about the energy-related characteristics of US households. These data were collected in the 1993 Residential Energy Consumption Survey (RECS) -- the ninth in a series of nationwide energy consumption surveys conducted since 1978 by the Energy Information Administration of the US Department of Energy. Over 7 thousand households were surveyed, representing 97 million households nationwide. A second report, to be released in late 1995, will present statistics on residential energy consumption and expenditures.

  6. Doll's house physics

    NASA Astrophysics Data System (ADS)

    Kibble, Bob

    2009-03-01

    School physics rarely stands still for long. Environmental physics is now an option in some post-16 courses in England. The physics of environments, and in particular the built environment, offers a recognizable context in which to see the applications of physics at work. This article considers how a model doll's house might be used to help learners understand energy transfer, thermal equilibrium, energy management, and responsible citizenship.

  7. House bat management

    USGS Publications Warehouse

    Greenhall, Arthur M.

    1982-01-01

    The soundest long-term solution for the management of bats that enter buildings and cause a nuisance problem or present a public health hazard is by batproofing the structure. Chemical toxicants do not solve house bat problems and may create worse ones. This manual describes batproofing techniques that will provide effective and acceptable alternatives for dealing with house bat problems and hazards. Recent declines in bat populations and greater appreciation of the ecological importance of bats have identified the need for sound management strategies that will encourage bat conservation while protecting human health and solving nuisance problems. One of the best deterrents against house bats is to improve the energy efficiency of the structure since bats may enter holes through which heat is lost. Heat conservation methods used for batproofing will also be eligible for Federal residential energy tax credits. The manual should be useful to homeowners, public health officials, physicians, veterinarians, conservationists, and others interested or concerned about bat interactions with humans.

  8. Farmworker Housing Quality and Health.

    PubMed

    Arcury, Thomas A; Jacobs, Ilene J; Ruiz, Virginia

    2015-11-01

    On 11 November 2014, Farmworker Housing Quality and Health: A Transdisciplinary Conference was convened to draw together experts from the variety of disciplines who contribute to research and practice focused on farmworker housing and health in order to delineate current knowledge and propose next steps. The conference addressed three specific aims: (1) to consolidate current knowledge on characteristics and quality of housing provided for farmworkers; (2) to delineate pertinent directions and areas for farmworker housing health and safety research and policy; and (3) to facilitate the development of working groups to support the implementation of research, education, and engineering projects to improve farmworker housing. This article provides an overview of the conference.

  9. INTERACTIONS BETWEEN ORGANIC COMPOUNDS AND CYCLODEXTRIN-CLAY SYSTEMS

    EPA Science Inventory

    Computational and experimental techniques are combined in order to better understand interactions involving organic compounds and cyclodextrin (CD)-clay systems. CD-clay systems may have great potential in the containment of organic contaminants in the environment. This study w...

  10. Adsorption coefficients for TNT on soil and clay minerals

    NASA Astrophysics Data System (ADS)

    Rivera, Rosángela; Pabón, Julissa; Pérez, Omarie; Muñoz, Miguel A.; Mina, Nairmen

    2007-04-01

    To understand the fate and transport mechanisms of TNT from buried landmines is it essential to determine the adsorption process of TNT on soil and clay minerals. In this research, soil samples from horizons Ap and A from Jobos Series at Isabela, Puerto Rico were studied. The clay fractions were separated from the other soil components by centrifugation. Using the hydrometer method the particle size distribution for the soil horizons was obtained. Physical and chemical characterization studies such as cation exchange capacity (CEC), surface area, percent of organic matter and pH were performed for the soil and clay samples. A complete mineralogical characterization of clay fractions using X-ray diffraction analysis reveals the presence of kaolinite, goethite, hematite, gibbsite and quartz. In order to obtain adsorption coefficients (K d values) for the TNT-soil and TNT-clay interactions high performance liquid chromatography (HPLC) was used. The adsorption process for TNT-soil was described by the Langmuir model. A higher adsorption was observed in the Ap horizon. The Freundlich model described the adsorption process for TNT-clay interactions. The affinity and relative adsorption capacity of the clay for TNT were higher in the A horizon. These results suggest that adsorption by soil organic matter predominates over adsorption on clay minerals when significant soil organic matter content is present. It was found that, properties like cation exchange capacity and surface area are important factors in the adsorption of clayey soils.

  11. The Politics of Clay: The American-Soviet Mural Project.

    ERIC Educational Resources Information Center

    Preston, Lynn

    1990-01-01

    Describes a U.S.-Soviet mural project where citizens from Milwaukee, Wisconsin and citizens from Leningrad created two peace murals--one in the United States and the other in the Soviet Union. The murals were exchanged. Participants made their own clay using dry clay and water before creating their impressions of peace and friendship. (KM)

  12. Learning of Cross-Sectional Anatomy Using Clay Models

    ERIC Educational Resources Information Center

    Oh, Chang-Seok; Kim, Ji-Young; Choe, Yeon Hyeon

    2009-01-01

    We incorporated clay modeling into gross anatomy and neuro-anatomy courses to help students understand cross-sectional anatomy. By making clay models, cutting them and comparing cut surfaces to CT and MR images, students learned how cross-sectional two-dimensional images were created from three-dimensional structure of human organs. Most students…

  13. Clay and Magnetite Formation at Yellowknife Bay, Mars

    NASA Astrophysics Data System (ADS)

    Bridges, J. C.; Schwenzer, S. P.; Leveille, R.; Westall, F.; Wiens, R. C.; Mangold, N.; Bristow, T.; Edwards, P.; Berger, G.

    2014-09-01

    Sheepbed mudstone contains a clay-magnetite assemblage formed by dissolution of approximately 70% amorphous phase, 20% olivine, 10% host rock mixture, by a pore fluid at moderate W/R ratio. The clay is similar to Lafayette's ferric saponite and gel.

  14. Clay Minerals as Solid Acids and Their Catalytic Properties.

    ERIC Educational Resources Information Center

    Helsen, J.

    1982-01-01

    Discusses catalytic properties of clays, attributed to acidity of the clay surface. The formation of carbonium ions on montmorillonite is used as a demonstration of the presence of surface acidity, the enhanced dissociation of water molecules when polarized by cations, and the way the surface can interact with organic substances. (Author/JN)

  15. Mechanical Properties of Composite Material Using Coal Ash and Clay

    NASA Astrophysics Data System (ADS)

    Fukumoto, Isao; Kanda, Yasuyuki

    Coal ash is industry waste exhausted lots of amount by electric power plant. The particle sizes of coal ash, especially coal fly ash are very fine, and the chemical component are extremely resemble with Okinawa-Kucha clay. From the point of view that clay is composed of particles of micro meter size in diameter, we should try the application for fabrication of composite material using coal fly ash and clay. The comparison of the mechanical properties of composite material using coal fly ash and clay were performed during electric furnace burning and spark plasma sintering. As a result, the bending strength of composite material containing the coal ash 10% and fired at 1423K using the electric furnace after press forming at 30 MPa showed the highest value of 47 MPa. This phenomenon suggests a reinforcement role of coal ash particles to clay base material. In spark plasma sintering process, the bending strength of the composite material containing the clay 5-10% to fly ash base material fired at 1473K and pressured at 20 MPa showed the highest value of 88 MPa. This result indicates a binder effect of clay according to the liquid phase sintering of melted clay surrounding around coal fly ash particles surface.

  16. Slopes in Stiff-fissured Clays and Shales

    DTIC Science & Technology

    1968-06-01

    shown that the Cucaracha and Culebra clay shales from the Panama Canal Zone, C and the Pierre shale from the Oahe damsite in South Dakota all exhibit...rapidly conducted tests, and in tests of 30 days duration the strength was about 22% less. The strength loss for Cucaracha clay shale was even more

  17. INTERIOR VIEW ON SEVENTH FLOOR ALONG EAST (CLAY STREET) FRONT. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    INTERIOR VIEW ON SEVENTH FLOOR ALONG EAST (CLAY STREET) FRONT. TYPICAL INTERIOR CONDITIONS OF PARTIAL DEMOLITION; SUSPENDED CEILING AND MOVABLE PARTITION WALLS REMOVED, REMAINS OF DEMOLISHED SHEET METAL CORNICE FROM BUILDING EXTERIOR VISIBLE ON FLOOR - John Breuner & Company Building, 1515 Clay Street, Oakland, Alameda County, CA

  18. Adsorption of zearalenone to Japanese acid clay and influencing factors.

    PubMed

    Sasaki, Risa; Takahashi, Noriyuki; Sakao, Kazunori; Goto, Tetsuhisa

    2014-02-01

    Zearalenone (ZEA) mainly contaminates grains such as corn and wheat, causing damage to livestock through ingestion of contaminated feed. Recently, various clays have been added to the feed to adsorb mycotoxins and to prevent mycotoxicosis of animals fed contaminated feeds. However the adsorption mechanism of the mycotoxin to clay is not well understood. In this study, a method to analyze the level of adsorption of ZEA to clay was developed using Japanese acid clay. Changes to the amount of the clay, concentration of ZEA, shaking time, and other parameters were evaluated to determine their influence on adsorption. The adsorption isotherms were also developed. Under conditions that mimic the gastrointestinal tract of swine, 100 % of ZEA was adsorbed to clay at a pH equivalent to the stomach, while the level of desorption under intestinal basic conditions was 1.8 %. Thus Japanese acid clay has a high ability to absorb ZEA with very little desorption under gastrointestinal conditions of the swine. Isothermal analysis suggests that the Japanese acid clay is potentially highly efficacious as a ZEA adsorbent.

  19. Environmental Health Disparities in Housing

    PubMed Central

    2011-01-01

    The physical infrastructure and housing make human interaction possible and provide shelter. How well that infrastructure performs and which groups it serves have important implications for social equity and health. Populations in inadequate housing are more likely to have environmental diseases and injuries. Substantial disparities in housing have remained largely unchanged. Approximately 2.6 million (7.5%) non-Hispanic Blacks and 5.9 million Whites (2.8%) live in substandard housing. Segregation, lack of housing mobility, and homelessness are all associated with adverse health outcomes. Yet the experience with childhood lead poisoning in the United States has shown that housing-related disparities can be reduced. Effective interventions should be implemented to reduce environmental health disparities related to housing. PMID:21551378

  20. Decomposition of nitrous oxide on pillared clays.

    PubMed

    De Stefanis, A; Dondi, M; Perez, G; Tomlinson, A A

    2000-10-01

    Alumina-pillared smectites have been found to abate nitrous oxide in the presence of methane. The results indicate that the yield of the reaction (N20 --> N2 + (1/2)O2) increases when pillared clays are exchanged with transition metals, single-pass conversion rates of >70% being attainable. In particular, when double exchanged (calcium and subsequently copper) alumina pillared montmorillonite/beidellite is used as a catalyst, de-N2O activity reaches a maximum, which is maintained even after 4 h of work at a space velocity of 5.5 h(-1). A mechanism for the reaction is suggested, which implies that N2O is first adsorbed by the catalyst and then decomposes through two different paths: catalyst oxidation and catalyst reduction. Such a redox process explains the kinetic data.

  1. Physical Properties of Cullet-Clay Ceramic

    NASA Astrophysics Data System (ADS)

    Razi, Munirah Mohd; Sahar, Md. Rahim; Md Yusuf, Mohd Nor

    2011-03-01

    A series of ceramic based on (x) cullet-(l00-x) clay has successfully been made by slip casting followed by sintering at 800° C. The sample density has been determined using the Archimedes method while their hardness by the Vickers Hardness Test. Meanwhile, the thermal shrinkage has been measured at 900° C. It is found that the density is in the range of 2.03-2.27 gem-3, increases as the amount of cullet is increased. Meanwhile their hardness up to 0.38 GPa can easily be obtained. The thermal shrinkage is found to be 2.9-11.9%, increases with the increasing of cullet content up to 60 wt%.

  2. Directional plasticity of clay showing instability

    NASA Astrophysics Data System (ADS)

    Fortuna, Sonia

    2010-06-01

    A graphical approach is used to sketch the field of small plastic strains (epsilon < 0.1 %) of Pisa clay along different axi-symmetric stress paths associated to a partial confining stress reduction. Within the classic framework of elasto-plasticity, volumetric and deviatoric plastic strains contours are determined from data obtained from triaxial tests, assuming a cross-anisotropic hypo-elastic formulation calibrated on a wide set of tests and with non linear evolution of the elastic moduli calibrated along a quasi-1D swelling stress path. The evolutions of the plastic strains and of the plastic strain vectors are shown along the stress path directly explored with tests and along virtual paths interpolated from the actual data along intermediate directions at various strain levels.

  3. Synthetic polymer-layer silicate clay composites

    SciTech Connect

    Carrado, K.A.; Elder, D.L.; Thiyagarajan, P.

    1995-07-01

    Synthetic hectorites were hydrothermally crystallized with direct incorporation of water-soluble polyvinyl alcohol (PVA), a cationic polymer poly(dimethyl diallyl ammonium chloride) (PDDA), and two cellulosic polymers: hydroxypropyl methylcellulose (HPMC) and hydroxyethyl cellulose (HEC). The molecular weight of polyvinyl alcohols had little effect on the success of hydrothermal hectorite synthesis, d-spacing, or amount of polymer incorporated; the basal spacings range from 19.5 {angstrom} to 20.8 {angstrom} and the percent of polymer incorporated ranges from 20.4 wt% to 23.0 wt%. Synthetic PDDA-hectorite displays the lowest d-spacing at 15.8 {angstrom}, and less cationic PDDA is incorporated into hectorite (7.8 wt% organic) than the other neutral polymers (17.8-23.0 wt% organic). The basal spacing for synthetic HPMC-hectorite is the largest at 25.2 {angstrom}. Small angle neutron scattering was used to further examine the PVA-clay systems.

  4. Prolonged triboluminescence in clays and other minerals

    NASA Technical Reports Server (NTRS)

    Lahav, N.; Coyne, L. M.; Lawless, J. G.

    1982-01-01

    Samples of various clays and minerals were ground or fractured and monitored with a liquid scintillation spectrometer in order to obtain triboluminescent decay curves. Kaolinite samples displayed several million counts/min after grinding, with a surface area emission estimated at tens of billions of photons/sq cm of surface. The photon production rates varied with the origin of the sample, and kaolinite continually yielded higher production rates than bentonite. The addition of water to the samples slightly increased the count rate of emitted light, while the addition of the fluorescent molecule substance tryptofan significantly enhanced the count rate. Freezing smears of kaolinite and montmorillonite in liquid nitrogen and in a salt ice mixture also induced triboluminescence in the montmorillonite. A possible connection between powdery triboluminescent materials formed in mining industries and respiratory disorders among miners is suggested.

  5. Organic/Inorganic Hybrid Polymer/Clay Nanocomposites

    NASA Technical Reports Server (NTRS)

    Park, Cheol; Connell, John W.; Smith, Joseph G., Jr.

    2003-01-01

    A novel class of polymer/clay nanocomposites has been invented in an attempt to develop transparent, lightweight, durable materials for a variety of aerospace applications. As their name suggests, polymer/ clay nanocomposites comprise organic/ inorganic hybrid polymer matrices containing platelet-shaped clay particles that have sizes of the order of a few nanometers thick and several hundred nanometers long. Partly because of their high aspect ratios and high surface areas, the clay particles, if properly dispersed in the polymer matrix at a loading level of 1 to 5 weight percent, impart unique combinations of physical and chemical properties that make these nanocomposites attractive for making films and coatings for a variety of industrial applications. Relative to the unmodified polymer, the polymer/ clay nanocomposites may exhibit improvements in strength, modulus, and toughness; tear, radiation, and fire resistance; and lower thermal expansion and permeability to gases while retaining a high degree of optical transparency.

  6. Mapping and Quantifying Surface Charges on Clay Nanoparticles.

    PubMed

    Liu, Jun; Gaikwad, Ravi; Hande, Aharnish; Das, Siddhartha; Thundat, Thomas

    2015-09-29

    Understanding the electrical properties of clay nanoparticles is very important since they play a crucial role in every aspect of oil sands processing, from bitumen extraction to sedimentation in mature fine tailings (MFT). Here, we report the direct mapping and quantification of surface charges on clay nanoparticles using Kelvin probe force microscopy (KPFM) and electrostatic force microscopy (EFM). The morphology of clean kaolinite clay nanoparticles shows a layered structure, while the corresponding surface potential map shows a layer-dependent charge distribution. More importantly, a surface charge density of 25 nC/cm(2) was estimated for clean kaolinite layers by using EFM measurements. On the other hand, the EFM measurements show that the clay particles obtained from the tailings demonstrate a reduced surface charge density of 7 nC/cm(2), which may be possibly attributed to the presence of various bituminous compounds residing on the clay surfaces.

  7. Late Precambrian oxygenation; inception of the clay mineral factory.

    PubMed

    Kennedy, Martin; Droser, Mary; Mayer, Lawrence M; Pevear, David; Mrofka, David

    2006-03-10

    An enigmatic stepwise increase in oxygen in the late Precambrian is widely considered a prerequisite for the expansion of animal life. Accumulation of oxygen requires organic matter burial in sediments, which is largely controlled by the sheltering or preservational effects of detrital clay minerals in modern marine continental margin depocenters. Here, we show mineralogical and geochemical evidence for an increase in clay mineral deposition in the Neoproterozoic that immediately predated the first metazoans. Today most clay minerals originate in biologically active soils, so initial expansion of a primitive land biota would greatly enhance production of pedogenic clay minerals (the "clay mineral factory"), leading to increased marine burial of organic carbon via mineral surface preservation.

  8. Boom clay borehole water, home of a diverse bacterial community

    SciTech Connect

    Wouters, Katinka; Moors, Hugo; Leys, Natalie

    2013-07-01

    For over two decades, Boom Clay has been studied in the framework of geological disposal of nuclear waste thereby mainly addressing its geochemical properties. Today, also the microbiological properties and the possibility of microbes interacting with radionuclides or repository components including the waste form, in a host formation like Boom Clay are considered [2,3]. In the past, a reference composition for synthetic Boom Clay pore water (BCPW) was derived, based on interstitial water sampled from different layers within the Boom clay [1]. Similarly, the primary aim of this microbiological study was to determine the core BCPW bacterial community and identify representative water samples for future microbial directed lab experiments. In this respect, BCPW was sampled from different Boom Clay layers using the Morpheus piezometer and subsequently analysed by microscopy and molecular techniques, in search for overall shared and abundant micro-organisms. (authors)

  9. 24 CFR 1006.210 - Housing services.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 24 Housing and Urban Development 4 2012-04-01 2012-04-01 false Housing services. 1006.210 Section 1006.210 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN...

  10. 20 CFR 654.407 - Housing.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 20 Employees' Benefits 3 2014-04-01 2014-04-01 false Housing. 654.407 Section 654.407 Employees... EMPLOYMENT SERVICE SYSTEM Housing for Agricultural Workers Housing Standards § 654.407 Housing. (a) Housing... occupants against the elements. (b) Housing shall have flooring constructed of rigid materials,...

  11. 24 CFR 982.619 - Cooperative housing.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 24 Housing and Urban Development 4 2011-04-01 2011-04-01 false Cooperative housing. 982.619 Section 982.619 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND...

  12. 24 CFR 982.619 - Cooperative housing.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 24 Housing and Urban Development 4 2010-04-01 2010-04-01 false Cooperative housing. 982.619 Section 982.619 Housing and Urban Development Regulations Relating to Housing and Urban Development (Continued) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND...

  13. 24 CFR 1007.20 - Eligible housing.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 24 Housing and Urban Development 4 2014-04-01 2014-04-01 false Eligible housing. 1007.20 Section 1007.20 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN...

  14. 24 CFR 983.52 - Housing type.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 24 Housing and Urban Development 4 2010-04-01 2010-04-01 false Housing type. 983.52 Section 983.52 Housing and Urban Development Regulations Relating to Housing and Urban Development (Continued) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN DEVELOPMENT...

  15. 24 CFR 983.52 - Housing type.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 24 Housing and Urban Development 4 2013-04-01 2013-04-01 false Housing type. 983.52 Section 983.52 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN DEVELOPMENT...

  16. 24 CFR 9.155 - Housing adjustments.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 24 Housing and Urban Development 1 2011-04-01 2011-04-01 false Housing adjustments. 9.155 Section 9.155 Housing and Urban Development Office of the Secretary, Department of Housing and Urban... THE DEPARTMENT OF HOUSING AND URBAN DEVELOPMENT § 9.155 Housing adjustments. (a) The agency...

  17. 24 CFR 9.155 - Housing adjustments.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 24 Housing and Urban Development 1 2010-04-01 2010-04-01 false Housing adjustments. 9.155 Section 9.155 Housing and Urban Development Office of the Secretary, Department of Housing and Urban... THE DEPARTMENT OF HOUSING AND URBAN DEVELOPMENT § 9.155 Housing adjustments. (a) The agency...

  18. 24 CFR 983.52 - Housing type.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 24 Housing and Urban Development 4 2011-04-01 2011-04-01 false Housing type. 983.52 Section 983.52 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN DEVELOPMENT...

  19. 24 CFR 81.22 - Housing plans.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 24 Housing and Urban Development 1 2013-04-01 2013-04-01 false Housing plans. 81.22 Section 81.22 Housing and Urban Development Office of the Secretary, Department of Housing and Urban Development THE... LOAN MORTGAGE CORPORATION (FREDDIE MAC) Housing Goals § 81.22 Housing plans. (a) If the...

  20. 20 CFR 654.407 - Housing.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 20 Employees' Benefits 3 2013-04-01 2013-04-01 false Housing. 654.407 Section 654.407 Employees... EMPLOYMENT SERVICE SYSTEM Housing for Agricultural Workers Housing Standards § 654.407 Housing. (a) Housing... occupants against the elements. (b) Housing shall have flooring constructed of rigid materials,...

  1. 24 CFR 1006.210 - Housing services.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 24 Housing and Urban Development 4 2010-04-01 2010-04-01 false Housing services. 1006.210 Section 1006.210 Housing and Urban Development Regulations Relating to Housing and Urban Development (Continued) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN...

  2. 12 CFR 1282.21 - Housing plans.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 12 Banks and Banking 7 2011-01-01 2011-01-01 false Housing plans. 1282.21 Section 1282.21 Banks and Banking FEDERAL HOUSING FINANCE AGENCY HOUSING GOALS AND MISSION ENTERPRISE HOUSING GOALS AND MISSION Housing Goals § 1282.21 Housing plans. (a) General. If the Director determines that an...

  3. 12 CFR 1282.22 - Housing plans.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 12 Banks and Banking 7 2010-01-01 2010-01-01 false Housing plans. 1282.22 Section 1282.22 Banks and Banking FEDERAL HOUSING FINANCE AGENCY HOUSING GOALS AND MISSION ENTERPRISE HOUSING GOALS AND MISSION Housing Goals § 1282.22 Housing plans. (a) If the Director determines, under § 1282.21, that...

  4. 24 CFR 1006.210 - Housing services.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 24 Housing and Urban Development 4 2014-04-01 2014-04-01 false Housing services. 1006.210 Section 1006.210 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN...

  5. 24 CFR 982.352 - Eligible housing.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 24 Housing and Urban Development 4 2010-04-01 2010-04-01 false Eligible housing. 982.352 Section 982.352 Housing and Urban Development Regulations Relating to Housing and Urban Development (Continued) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN...

  6. 24 CFR 81.22 - Housing plans.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 24 Housing and Urban Development 1 2012-04-01 2012-04-01 false Housing plans. 81.22 Section 81.22 Housing and Urban Development Office of the Secretary, Department of Housing and Urban Development THE... LOAN MORTGAGE CORPORATION (FREDDIE MAC) Housing Goals § 81.22 Housing plans. (a) If the...

  7. 12 CFR 1282.21 - Housing plans.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 12 Banks and Banking 9 2013-01-01 2013-01-01 false Housing plans. 1282.21 Section 1282.21 Banks and Banking FEDERAL HOUSING FINANCE AGENCY HOUSING GOALS AND MISSION ENTERPRISE HOUSING GOALS AND MISSION Housing Goals § 1282.21 Housing plans. (a) General. If the Director determines that an...

  8. 24 CFR 9.155 - Housing adjustments.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 24 Housing and Urban Development 1 2013-04-01 2013-04-01 false Housing adjustments. 9.155 Section 9.155 Housing and Urban Development Office of the Secretary, Department of Housing and Urban... THE DEPARTMENT OF HOUSING AND URBAN DEVELOPMENT § 9.155 Housing adjustments. (a) The agency...

  9. 24 CFR 9.155 - Housing adjustments.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 24 Housing and Urban Development 1 2012-04-01 2012-04-01 false Housing adjustments. 9.155 Section 9.155 Housing and Urban Development Office of the Secretary, Department of Housing and Urban... THE DEPARTMENT OF HOUSING AND URBAN DEVELOPMENT § 9.155 Housing adjustments. (a) The agency...

  10. 24 CFR 81.22 - Housing plans.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 24 Housing and Urban Development 1 2014-04-01 2014-04-01 false Housing plans. 81.22 Section 81.22 Housing and Urban Development Office of the Secretary, Department of Housing and Urban Development THE... LOAN MORTGAGE CORPORATION (FREDDIE MAC) Housing Goals § 81.22 Housing plans. (a) If the...

  11. 24 CFR 1007.20 - Eligible housing.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 24 Housing and Urban Development 4 2013-04-01 2013-04-01 false Eligible housing. 1007.20 Section 1007.20 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN...

  12. 20 CFR 654.407 - Housing.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 20 Employees' Benefits 3 2012-04-01 2012-04-01 false Housing. 654.407 Section 654.407 Employees... EMPLOYMENT SERVICE SYSTEM Housing for Agricultural Workers Housing Standards § 654.407 Housing. (a) Housing... occupants against the elements. (b) Housing shall have flooring constructed of rigid materials,...

  13. 24 CFR 954.103 - Housing strategy.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 24 Housing and Urban Development 4 2010-04-01 2010-04-01 false Housing strategy. 954.103 Section 954.103 Housing and Urban Development Regulations Relating to Housing and Urban Development (Continued) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN...

  14. 24 CFR 9.155 - Housing adjustments.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 24 Housing and Urban Development 1 2014-04-01 2014-04-01 false Housing adjustments. 9.155 Section 9.155 Housing and Urban Development Office of the Secretary, Department of Housing and Urban... THE DEPARTMENT OF HOUSING AND URBAN DEVELOPMENT § 9.155 Housing adjustments. (a) The agency...

  15. 12 CFR 1282.21 - Housing plans.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 12 Banks and Banking 10 2014-01-01 2014-01-01 false Housing plans. 1282.21 Section 1282.21 Banks and Banking FEDERAL HOUSING FINANCE AGENCY HOUSING GOALS AND MISSION ENTERPRISE HOUSING GOALS AND MISSION Housing Goals § 1282.21 Housing plans. (a) General. If the Director determines that an...

  16. 24 CFR 982.619 - Cooperative housing.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 24 Housing and Urban Development 4 2012-04-01 2012-04-01 false Cooperative housing. 982.619 Section 982.619 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND...

  17. 12 CFR 1282.21 - Housing plans.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 12 Banks and Banking 9 2012-01-01 2012-01-01 false Housing plans. 1282.21 Section 1282.21 Banks and Banking FEDERAL HOUSING FINANCE AGENCY HOUSING GOALS AND MISSION ENTERPRISE HOUSING GOALS AND MISSION Housing Goals § 1282.21 Housing plans. (a) General. If the Director determines that an...

  18. 24 CFR 81.22 - Housing plans.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 24 Housing and Urban Development 1 2010-04-01 2010-04-01 false Housing plans. 81.22 Section 81.22 Housing and Urban Development Office of the Secretary, Department of Housing and Urban Development THE... LOAN MORTGAGE CORPORATION (FREDDIE MAC) Housing Goals § 81.22 Housing plans. (a) If the...

  19. 24 CFR 982.619 - Cooperative housing.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 24 Housing and Urban Development 4 2013-04-01 2013-04-01 false Cooperative housing. 982.619 Section 982.619 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND...

  20. 24 CFR 1006.210 - Housing services.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 24 Housing and Urban Development 4 2013-04-01 2013-04-01 false Housing services. 1006.210 Section 1006.210 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN...

  1. 24 CFR 81.22 - Housing plans.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 24 Housing and Urban Development 1 2011-04-01 2011-04-01 false Housing plans. 81.22 Section 81.22 Housing and Urban Development Office of the Secretary, Department of Housing and Urban Development THE... LOAN MORTGAGE CORPORATION (FREDDIE MAC) Housing Goals § 81.22 Housing plans. (a) If the...

  2. 24 CFR 983.52 - Housing type.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 24 Housing and Urban Development 4 2014-04-01 2014-04-01 false Housing type. 983.52 Section 983.52 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN DEVELOPMENT...

  3. 24 CFR 983.52 - Housing type.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 24 Housing and Urban Development 4 2012-04-01 2012-04-01 false Housing type. 983.52 Section 983.52 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN DEVELOPMENT...

  4. 24 CFR 982.619 - Cooperative housing.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 24 Housing and Urban Development 4 2014-04-01 2014-04-01 false Cooperative housing. 982.619 Section 982.619 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND...

  5. 24 CFR 1006.210 - Housing services.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 24 Housing and Urban Development 4 2011-04-01 2011-04-01 false Housing services. 1006.210 Section 1006.210 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN...

  6. 24 CFR 954.103 - Housing strategy.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 24 Housing and Urban Development 4 2011-04-01 2011-04-01 false Housing strategy. 954.103 Section 954.103 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN...

  7. 24 CFR 1007.20 - Eligible housing.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 24 Housing and Urban Development 4 2011-04-01 2011-04-01 false Eligible housing. 1007.20 Section 1007.20 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN...

  8. 24 CFR 982.352 - Eligible housing.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 24 Housing and Urban Development 4 2014-04-01 2014-04-01 false Eligible housing. 982.352 Section 982.352 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN...

  9. 24 CFR 982.352 - Eligible housing.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 24 Housing and Urban Development 4 2011-04-01 2011-04-01 false Eligible housing. 982.352 Section 982.352 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN...

  10. 24 CFR 1007.20 - Eligible housing.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 24 Housing and Urban Development 4 2012-04-01 2012-04-01 false Eligible housing. 1007.20 Section 1007.20 Housing and Urban Development REGULATIONS RELATING TO HOUSING AND URBAN DEVELOPMENT (CONTINUED) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN...

  11. 24 CFR 1007.20 - Eligible housing.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 24 Housing and Urban Development 4 2010-04-01 2010-04-01 false Eligible housing. 1007.20 Section 1007.20 Housing and Urban Development Regulations Relating to Housing and Urban Development (Continued) OFFICE OF ASSISTANT SECRETARY FOR PUBLIC AND INDIAN HOUSING, DEPARTMENT OF HOUSING AND URBAN...

  12. Complex resistivity signatures of ethanol in sand-clay mixtures

    NASA Astrophysics Data System (ADS)

    Personna, Yves Robert; Slater, Lee; Ntarlagiannis, Dimitrios; Werkema, Dale; Szabo, Zoltan

    2013-06-01

    We performed complex resistivity (CR) measurements on laboratory columns to investigate changes in electrical properties as a result of varying ethanol (EtOH) concentration (0% to 30% v/v) in a sand-clay (bentonite) matrix. We applied Debye decomposition, a phenomenological model commonly used to fit CR data, to determine model parameters (time constant: τ, chargeability: m, and normalized chargeability: mn). The CR data showed a significant (P ≤ 0.001) time-dependent variation in the clay driven polarization response (~ 12 mrad) for 0% EtOH concentration. This temporal variation probably results from the clay-water reaction kinetics trending towards equilibrium in the sand-clay-water system. The clay polarization is significantly suppressed (P ≤ 0.001) for both measured phase (ϕ) and imaginary conductivity (σ″) with increasing EtOH concentration. Normalized chargeability consistently decreases (by up to a factor of ~ 2) as EtOH concentration increases from 0% to 10% and 10 to 20%, respectively. We propose that such suppression effects are associated with alterations in the electrical double layer (EDL) at the clay-fluid interface due to (a) strong EtOH adsorption on clay, and (b) complex intermolecular EtOH-water interactions and subsequent changes in ionic mobility on the surface in the EDL. Changes in the CR data following a change of the saturating fluid from EtOH 20% to plain water indicate strong hysteresis effects in the electrical response, which we attribute to persistent EtOH adsorption on clay. Our results demonstrate high sensitivity of CR measurements to clay-EtOH interactions in porous media, indicating the potential application of this technique for characterization and monitoring of ethanol contamination in sediments containing clays.

  13. Fractal dimensions of flocs between clay particles and HAB organisms

    NASA Astrophysics Data System (ADS)

    Wang, Hongliang; Yu, Zhiming; Cao, Xihua; Song, Xiuxian

    2011-05-01

    The impact of harmful algal blooms (HABs) on public health and related economics have been increasing in many coastal regions of the world. Sedimentation of algal cells through flocculation with clay particles is a promising strategy for controlling HABs. Previous studies found that removal efficiency (RE) was influenced by many factors, including clay type and concentration, algal growth stage, and physiological aspects of HAB cells. To estimate the effect of morphological characteristics of the aggregates on HAB cell removal, fractal dimensions were measured and the RE of three species of HAB organism, Heterosigma akashiwo, Alexandrium tamarense, and Skeletonema costatum, by original clay and modified clay, was determined. For all HAB species, the modified clay had a higher RE than original clay. For the original clay, the two-dimensional fractal dimension ( D 2) was 1.92 and three-dimensional fractal dimension ( D 3) 2.81, while for the modified clay, D 2 was 1.84 and D 3 was 2.50. The addition of polyaluminum chloride (PACl) lead to a decrease of the repulsive barrier between clay particles, and resulted in lower D 2 and D 3. Due to the decrease of D 3, and the increase of the effective sticking coefficient, the flocculation rate between modified clay particles and HAB organisms increased, and thus resulted in a high RE. The fractal dimensions of flocs differed in HAB species with different cell morphologies. For example, Alexandrium tamarense cells are ellipsoidal, and the D 3 and D 2 of flocs were the highest, while for Skeletonema costatum, which has filamentous cells, the D 3 and D 2 of flocs were the lowest.

  14. Heteroaggregation of titanium dioxide nanoparticles with natural clay colloids.

    PubMed

    Labille, Jérôme; Harns, Carrie; Bottero, Jean-Yves; Brant, Jonathan

    2015-06-02

    To better understand and predict the fate of engineered nanoparticles in the water column, we assessed the heteroaggregation of TiO2 nanoparticles with a smectite clay as analogues for natural colloids. Heteroaggregation was evaluated as a function of water salinity (10(-3) and 10(-1) M NaCl), pH (5 and 8), and selected nanoparticle concentration (0-4 mg/L). Time-resolved laser diffraction was used, coupled to an aggregation model, to identify the key mechanisms and variables that drive the heteroaggregation of the nanoparticles with colloids. Our data show that, at a relevant concentration, nanoparticle behavior is mainly driven by heteroaggregation with colloids, while homoaggregation remains negligible. The affinity of TiO2 nanoparticles for clay is driven by electrostatic interactions. Opposite surface charges and/or high ionic strength favored the formation of primary heteroaggregates via the attachment of nanoparticles to the clay. The initial shape and dispersion state of the clay as well as the nanoparticle/clay concentration ratio also affected the nature of the heteroaggregation mechanism. With dispersed clay platelets (10(-3) M NaCl), secondary heteroaggregation driven by bridging nanoparticles occurred at a nanoparticle/clay number ratio of greater than 0.5. In 10(-1) M NaCl, the clay was preaggregated into larger and more spherical units. This favored secondary heteroaggregation at lower nanoparticle concentration that correlated to the nanoparticle/clay surface area ratio. In this latter case, a nanoparticle to clay sticking efficiency could be determined.

  15. Complex resistivity signatures of ethanol in sand-clay mixtures.

    PubMed

    Personna, Yves Robert; Slater, Lee; Ntarlagiannis, Dimitrios; Werkema, Dale; Szabo, Zoltan

    2013-06-01

    We performed complex resistivity (CR) measurements on laboratory columns to investigate changes in electrical properties as a result of varying ethanol (EtOH) concentration (0% to 30% v/v) in a sand-clay (bentonite) matrix. We applied Debye decomposition, a phenomenological model commonly used to fit CR data, to determine model parameters (time constant: τ, chargeability: m, and normalized chargeability: mn). The CR data showed a significant (P≤0.001) time-dependent variation in the clay driven polarization response (~12 mrad) for 0% EtOH concentration. This temporal variation probably results from the clay-water reaction kinetics trending towards equilibrium in the sand-clay-water system. The clay polarization is significantly suppressed (P≤0.001) for both measured phase (ϕ) and imaginary conductivity (σ″) with increasing EtOH concentration. Normalized chargeability consistently decreases (by up to a factor of ~2) as EtOH concentration increases from 0% to 10% and 10 to 20%, respectively. We propose that such suppression effects are associated with alterations in the electrical double layer (EDL) at the clay-fluid interface due to (a) strong EtOH adsorption on clay, and (b) complex intermolecular EtOH-water interactions and subsequent changes in ionic mobility on the surface in the EDL. Changes in the CR data following a change of the saturating fluid from EtOH 20% to plain water indicate strong hysteresis effects in the electrical response, which we attribute to persistent EtOH adsorption on clay. Our results demonstrate high sensitivity of CR measurements to clay-EtOH interactions in porous media, indicating the potential application of this technique for characterization and monitoring of ethanol contamination in sediments containing clays.

  16. Studies of clays and clay minerals using x-ray powder diffraction and the Rietveld method

    SciTech Connect

    Bish, D.L.

    1993-09-01

    The Rietveld method was originally developed (Rietveld, 1967, 1969) to refine crystal structures using neutron powder diffraction data. Since then, the method has been increasingly used with X-ray powder diffraction data, and today it is safe to say that this is the most common application of the method. The method has been applied to numerous natural and synthetic materials, most of which do not usually form crystals large enough for study with single-crystal techniques. It is the ability to study the structures of materials for which sufficiently large single crystals do not exist that makes the method so powerful and popular. It would thus appear that the method is ideal for studying clays and clay minerals. In many cases this is true, but the assumptions implicit in the method and the disordered nature of many clay minerals can limit titsapplicability. This chapter will describe the Rietveld method, emphasizing the assumptions important for the study of disordered materials, and it will outline the potential applications of the method to these minerals. These applications include, in addition to the refinement of crystal structures, quantitative analysis of multicomponent mixtures, analysis of peak broadening, partial structure solution, and refinement of unit-cell parameters.

  17. House to house, shelter to shelter: experiences of black women seeking housing after leaving abusive relationships.

    PubMed

    Wilson, Patty R; Laughon, Kathryn

    2015-01-01

    Locating safe and affordable housing is a vital step for women who decide to leave their abuser. Without housing, many women, particularly those who live in poverty, are forced to remain in abusive relationships, accept inadequate or unsafe housing, or become homeless (Menard, 2001; Moses, 2010). Women who choose to leave their abusers are faced with multiple barriers in establishing their independence such as limited financial resources, mental illness, and the lack of affordable housing (Botein & Hetling, 2010), putting them at risk of revictimization. This pilot study explores the narratives of Black mothers currently residing at an emergency intimate partner violence shelter to discover their experiences in seeking housing after leaving abusive relationships with a focus on housing instability and mental health. Utilizing a qualitative descriptive design, four major themes emerged: (a) unstable/insecure housing over time, (b) limited support,

  18. Cleaning up the House

    SciTech Connect

    Hogue, C.

    2007-12-15

    Under the new 'Green the Capital' initiative, measures are making the House of Representatives a more energy efficient workplace. The Capital power plant, which burns mostly coal and natural gas to heat seven boilers, must operate in a carbon-neutral fashion by the end of 2008, by increasing energy efficiency and fuel switching. Roughly 103,000 MW hours of electricity will be bought each year from solar and wind-powered sources. Other measures being implemented are use of fluorescent light bulbs and recycled paper, and a boost in recycling of materials. 4 photos.

  19. Microbe-Clay Mineral Reactions and Characterization Techniques

    NASA Astrophysics Data System (ADS)

    Dong, H.; Zhang, G.; Ji, S.; Jaisi, D.; Kim, J.

    2008-12-01

    Clays and clay minerals are ubiquitous in soils, sediments, and sedimentary rocks. They play an important role in environmental processes such as nutrient cycling, plant growth, contaminant migration, organic matter maturation, and petroleum production. The changes in the oxidation state of the structural iron in clay minerals, in part, control their physical and chemical properties in natural environments, such as clay particle flocculation, dispersion, swelling, hydraulic conductivity, surface area, cation and anion exchange capacity, and reactivity towards organic and inorganic contaminants. The structural ferric iron [Fe(III)] in clay minerals can be reduced either chemically or biologically. Many different chemical reductants have been tried, but the most commonly used agent is dithionite. Biological reductants are bacteria, including dissimilatory iron reducing prokaryotes (DIRP) and sulfate-reducing bacteria (SRB). A wide variety of DIRP have been used to reduce ferric iron in clay minerals, including mesophilic, thermophilic, and hyperthermophilic prokaryotes. Multiple clay minerals have been used for microbial reduction studies, including smectite, nontronite (iron-rich smectite variety), illite, illite/smectite, chlorite, and their various mixtures. All these clay minerals are reducible by microorganisms under various conditions with smectite (nontronite) being the most reducible. The reduction extent and rate of ferric iron in clay minerals are measured by wet chemistry, and the reduced clay mineral products are typically characterized with chemical methods, X-ray diffraction, scanning and transmission electron microscopy, Mössbauer spectroscopy, Fourier Transform Infrared Spectroscopy (FTIR), UV-vis spectroscopy, and synchrotron-based techniques (such as EXAFS). Microbially reduced smectites (nontronites) have been found to be reactive in reducing a variety of organic and inorganic contaminants. Degradable organic contaminants include pesticides

  20. Microbial processes for removal of suspended clays from selected industrial wastewaters

    SciTech Connect

    Brierley, C.L.; Lanza, G.R.; Scheiner, B.

    1981-01-01

    Finely divided clays, generated by beneficiating phosphate, are impounded for up to several decades to effect dewatering. Under contract to the Interior Department's Bureau of Mines, several microbiological processes were tested for aggregating suspended clays. Polymers, isolated from Leuconostoc mesenteroides, Xanthomonas sp., and Beijerinckia indica, flocculated dilute phosphatic clay-slime at a rate comparable to polyethylene oxide; however, biopolymer-flocculated clays produced turbid supernatants. Cladosporium cladosporioides, enriched from phosphatic clay-slimes, produced a bioflocculant, and agitated incubation of C. Cladosporioides spores, sugar, and yeast extract with phosphatic clay-slimes induced clay-fungus pelletization. Microbiologically mediated clay removal may have application in industrial wastewater clarification.

  1. Thermo Gravimetric and Differential Thermal Analysis of Clay of Western Rajasthan (india)

    NASA Astrophysics Data System (ADS)

    Shekhawat, M. S.

    The paper presents the study of thermo gravimetric and differential thermal analysis of blended clay. Western part of Rajasthan (India) is rich resource of Ball clays and it is mainly used by porcelain, sanitary ware, and tile industry. The quality and grade of clay available in the region vary from one deposit to other. To upgrade the fired colour and strength properties, different variety of clays may be blended together. The paper compares the results of thermal analysis one of blended clay B2 with reference clay of Ukraine which is imported by industries owners. The result revealed that the blended clay is having mineral kaolinite while the Ukrainian clay is Halloysite.

  2. Reversibility of soil forming clay mineral reactions induced by plant - clay interactions

    NASA Astrophysics Data System (ADS)

    Barré, P.; Velde, B.

    2012-04-01

    Recent data based upon observations of field experiments and laboratory experiments suggest that changes in phyllosilicate mineralogy, as seen by X-ray diffraction analysis, which is induced by plant action can be reversed in relatively short periods of time. Changes from diagenetic or metamorphic mineral structures (illite and chlorite) to those found in soils (mixed layered minerals in the smectite, hydroxy-interlayer mineral and illites) observed in Delaware Bay salt marsh sediments in periods of tens of years and observed under different biologic (mycorhize) actions in coniferous forests in the soil environment can be found to be reversed under other natural conditions. Reversal of this process (chloritisation of smectitic minerals in soils) has been observed in natural situations over a period of just 14 years under sequoia gigantia. Formation of smectite minerals from illite (potassic mica-like minerals) has been observed to occur under intensive agriculture conditions over periods of 80 years or so under intensive zea mais production. Laboratory experiments using rye grass show that this same process can be accomplished to a somewhat lesser extent after one growing season. However experiments using alfalfa for 30 year growing periods show that much of the illite content of a soil can be reconstituted or even increased. Observations on experiments using zea mais under various fertilizer and mycorhize treatments indicate that within a single growing season potassium can be extracted from the clay (illite layers) but at the end of the season the potassium can be restored to the clay structures and more replaced that extracted. Hence it is clear that the change in clay mineralogy normally considered to be irreversible, illite to smectite or chlorite to smectite observed in soils, is a reversible process where plant systems control the soil chemistry and the soil mineralogy. The changes in clay mineralogy concern mostly the chemical composition of the interlayer

  3. SAXS Study of Reversibly Crosslinked Isotactic Polypropylene/clay Nanocomposites

    SciTech Connect

    Bouhelal, S.; Cagiao, M; Benachour, D; Djellouli, B; Rong, L; Hsiao, B; Baltá-Calleja, F

    2010-01-01

    A new route based on reversibly crosslinking reactive extrusion is applied for the development of iPP/clay nanocomposites. Analysis of small-angle X-ray scattering (SAXS) reflections of isotactic polypropylene (iPP)/clay nanocomposites, prepared by two different mixing and chemical crosslinking methods (i.e., conventional and in situ), is presented and results are compared with preceding wide-angle X-ray diffraction (WAXD) results. It is shown that the presence of clay significantly affects the value of long spacing in iPP, as well as the coherence length of lamellar stacks. Results show that the size of the coherently diffracting nanodomains decreases in two stages, first rapidly and then slowly as a function of increasing clay content. This can be attributed to the influence of confined iPP lamellae under the effect of rising number of clay particles. The appearance of the {gamma}-crystalline form in the crosslinked iPP/clay nanocomposites is related with the difficulty in chain folding of iPP chains introduced by the chemical crosslinking process, as well as by the presence of clay particles.

  4. An ion diffusion model in semi-permeable clay materials.

    PubMed

    Liu, Chongxuan

    2007-08-01

    Clay materials typically contain negative surface charges that induce electrostatic fields (or diffuse double layers) in electrolytes. During ion diffusion in a porous medium of clay materials, ions dynamically interact with the electrostatic fields associated with individual clay grains by depressing or expanding the electrostatic double layers, which subsequently affects ionic fluxes. Current theory of ion transport in porous media, however, cannot explicitly account for the dynamic interactions. Here we proposed a model by coupling electrodynamics and nonequilibrium thermodynamics (EDNT) to describe ion diffusion in clay materials as a complex function of factors including clay surface charge density, tortuosity, porosity, chemicoosmotic coefficient, and ion self-diffusivity. The model was validated by comparing the calculated and measured apparent ion diffusion coefficients in clay materials as a function of ionic strength. At transitional states, ion diffusive fluxes are dynamically related to the electrostatic fields, which shrink or expand as ion diffusion occurs. At steady states, the electrostatic fields are time-invariant and ion diffusive fluxes conform to flux and concentration gradient relationships; and apparent diffusivity can be approximated by the ion diffusivity in bulk electrolytes corrected by a tortuosity factor and macroscopic concentration discontinuities at the interfaces between clay materials and bulk solutions.

  5. Light reflection visualization to determine solute diffusion into clays.

    PubMed

    Yang, Minjune; Annable, Michael D; Jawitz, James W

    2014-06-01

    Light reflection visualization (LRV) experiments were performed to investigate solute diffusion in low-permeability porous media using a well-controlled two-dimensional flow chamber with a domain composed of two layers (one sand and one clay). Two different dye tracers (Brilliant Blue FCF and Ponceau 4R) and clay domains (kaolinite and montmorillonite) were used. The images obtained through the LRV technique were processed to monitor two-dimensional concentration distributions in the low-permeability zone by applying calibration curves that related light intensity to equilibrium concentrations for each dye tracer in the clay. One dimensional experimentally-measured LRV concentration profiles in the clay were found to be in very good agreement with those predicted from a one-dimensional analytical solution, with coefficient of efficiency values that exceeded 0.97. The retardation factors (R) for both dyes were relatively large, leading to slow diffusive penetration into the clays. At a relative concentration C/C0=0.1, Brilliant Blue FCF in kaolinite (R=11) diffused approximately 10 mm after 21 days of source loading, and Ponceau 4R in montmorillonite (R=7) diffused approximately 12 mm after 23 days of source loading. The LRV experimentally-measured two-dimensional concentration profiles in the clay were also well described by a simple analytical solution. The results from this study demonstrate that the LRV approach is an attractive non-invasive tool to investigate the concentration distribution of dye tracers in clays in laboratory experiments.

  6. Clay-Enriched Silk Biomaterials for Bone Formation

    PubMed Central

    Mieszawska, Aneta J.; Llamas, Jabier Gallego; Vaiana, Christopher A.; Kadakia, Madhavi P.; Naik, Rajesh R.; Kaplan, David L.

    2011-01-01

    The formation of silk protein/clay composite biomaterials for bone tissue formation is described. Silk fibroin serves as an organic scaffolding material offering mechanical stability suitable for bone specific uses. Clay montmorillonite (Cloisite ® Na+) and sodium silicate are sources of osteoinductive silica-rich inorganic species, analogous to bioactive bioglass-like bone repair biomaterial systems. Different clay particle-silk composite biomaterial films were compared to silk films doped with sodium silicate as controls for support of human bone marrow derived mesenchymal stem cells (hMSCs) in osteogenic culture. The cells adhered and proliferated on the silk/clay composites over two weeks. Quantitative real-time RT-PCR analysis revealed increased transcript levels for alkaline phosphatase (ALP), bone sialoprotein (BSP), and collagen type 1 (Col I) osteogenic markers in the cells cultured on the silk/clay films in comparison to the controls. Early evidence for bone formation based on collagen deposition at the cell-biomaterial interface was also found, with more collagen observed for the silk films with higher contents of clay particles. The data suggest that the silk/clay composite systems may be useful for further study toward bone regenerative needs. PMID:21549864

  7. Unsaturated properties for non-Darcian water flow in clay

    NASA Astrophysics Data System (ADS)

    Liu, Hui-Hai; Li, Lianchong; Birkholzer, Jens

    2012-04-01

    SummaryClay rock formations, and compacted clay (e.g., bentonite) used as backfill within disposal drifts, have been considered as natural and engineered barriers, respectively, for isolating high-level nuclear wastes in mined geologic repositories. Accurately modeling unsaturated flow in those clay materials is important for assessing the performance of a geological repository. While the non-Darcian behavior of water flow in clay materials has been demonstrated in the literature, a systematic study of modeling unsaturated non-Darcian flow is still lacking. Based on a hypothesis that pore water in clay becomes non-Newtonian as a result of water-clay interaction, we propose new constitutive relationships for unsaturated flow, including a relationship between water flux and hydraulic gradient and those among capillary pressure, water saturation, and hydraulic conductivity. An evaluation based on a set of laboratory experimental observations supports the usefulness of the proposed relationships. More experimental studies are desirable for further confirming the non-Newtonian water flow behavior in clay materials and evaluating the proposed relationships.

  8. Chemical effects on clay farbric and hydraulic conductivity

    NASA Astrophysics Data System (ADS)

    Madsen, Fritz T.; Mitchell, James K.

    Hydraulic conductivity and its susceptibility to changes with time or exposure to chemicals are major factors in selection of clay for use in waste containment barriers. Available concepts of clay-chemical interactions and data permit development of conclusions useful for prediction of clay barrier performance in waste containment applications. Among the most important conclusions are that (1) the influences of the many factors that can cause changes in hydraulic conductivity can be understood from the perspective of their effects on the soil fabric, (2) the influences of chemicals on high water content clays, such as in slurry walls, are likely to be much greater than on lower water content compacted clays, (3) the effects of inorganic chemicals are consistent with their effects on particle surface double layers, their effects on surface and edge charges, and on pH, and (4) the effects of organic chemicals are influenced primarily by their water solubility, their dielectric constant, their polarity, and whether the clay is exposed to the pure chemical or a dilute solution. The type of test used may have a very significant effect on the values of hydraulic conductivity that are measured. In almost all cases pure organic liquids will interact adversely with clays by causing some shrinking and cracking, with concurrent large hydraulic conductivity increases; however, dilute solutions of organics have essentially no effect.

  9. Anatomy of a Smart house

    SciTech Connect

    Kennedy, L.

    1988-07-01

    The author describes the Gas Laboratory House in Bowie, MD. It is being built as a SMART HOUSE. This means it will contain a whole-house control system made up of communication chips, computer programs and microprocessor-based controllers. A single cable carries signals from the chips to many different types of appliances. Flexible gas piping forms a ''circulatory system'' that makes the house completely compatible with natural gas appliances. The SMART HOUSE is fully programmable so that appliances can be told when to turn on and off. It can also have a zoned space-conditioning system, allowing sections of the house to be heated or cooled independently. The authors explains how the system works and the project's development schedule.

  10. Induced polarization of clay-sand mixtures. Experiments and modelling.

    NASA Astrophysics Data System (ADS)

    Okay, G.; Leroy, P.

    2012-04-01

    The complex conductivity of saturated unconsolidated sand-clay mixtures was experimentally investigated using two types of clay minerals, kaolinite and smectite (mainly Na-Montmorillonite) in the frequency range 1.4 mHz - 12 kHz. The experiments were performed with various clay contents (1, 5, 20, and 100 % in volume of the sand-clay mixture) and salinities (distilled water, 0.1 g/L, 1 g/L, and 10 g/L NaCl solution). Induced polarization measurements were performed with a cylindrical four-electrode sample-holder associated with a SIP-Fuchs II impedance meter and non-polarizing Cu/CuSO4 electrodes. The results illustrate the strong impact of the CEC of the clay minerals upon the complex conductivity. The quadrature conductivity increases steadily with the clay content. We observe that the dependence on frequency of the quadrature conductivity of sand-kaolinite mixtures is more important than for sand-bentonite mixtures. For both types of clay, the quadrature conductivity seems to be fairly independent on the pore fluid salinity except at very low clay contents. The experimental data show good agreement with predicted values given by our SIP model. This complex conductivity model considers the electrochemical polarization of the Stern layer coating the clay particles and the Maxwell-Wagner polarization. We use the differential effective medium theory to calculate the complex conductivity of the porous medium constituted of the grains and the electrolyte. The SIP model includes also the effect of the grain size distribution upon the complex conductivity spectra.

  11. Privatization of Military Family Housing

    DTIC Science & Technology

    2007-11-02

    Rev. 2-89) (EG) Proscribed by ANSI S IU . 239,1 PRIVATIZATION OF MILITARY FAMILY HOUSING MAJOR PATRICK W. MOUDY* * Major Patrick W. Moudy, United...amendments for Development of Private Sector Housing, Corpus Christi, Texas.29 Landmark Residential, LLC (Landmark) was the successful offeror for the...office, the JAG office, the Civil Engineering office, the Comptroller office, the environmental experts, and the housing office, as well as the command

  12. In-House EVM Workshop

    DTIC Science & Technology

    2007-11-02

    Government Accounting • Management Information System • Workshop Recommendations EVM In- House Workshop Findings • EVM implementation within DoD...Management Command Mr. William “Bill” Gibson Mr. Dominic A. “Chip” Thomas IN- HOUSE ( GOVERNMENT ) EVMS WORKSHOP VALIDATION & SURVEILLANCE D:\\PPT...2Defense Contract Management Command IN- HOUSE ( GOVERNMENT ) EVMS WORKSHOP VALIDATION • WHY VALIDATE/CERTIFY • WHO PAYS THE COST • FACILITY

  13. Gas flow modelling through clay and claystones

    NASA Astrophysics Data System (ADS)

    Alonso, E.

    2012-12-01

    Large scale gas flow experiments conducted in connection with nuclear waste disposal research have shown the dominant effect of "minor" details such as interfaces, contacts and layer boundaries. Even if the scale of the analysis is highly reduced, in search of homogeneous point-like conditions, a systematic development of preferential paths is very often reported. Small size samples become boundary value problems. Preferential paths, when their thickness is modified by the stress-strain response of the media, under the combined action of stress and fluid pressure changes, become highly conductive features for gas flow. The development of preferential paths for fluid flow has been approached in a simple manner by embedding a discontinuity feature into an otherwise continuous element which models clay or claystone matrix behavior. The joint is activated when tensile strains develop in the continuous element. Then, hydraulic properties (permeability, retention behavior) are modified by means of laws derived from the physics of flow in discontinuities. The outlined idea was incorporated into a full Thermo-Hydro-Mechanical finite element code (CODE_BRIGHT) which has a wide range of capabilities for the modeling of two-phase flow in elasto-viscoplastic porous materials. A particular aspect which required attention is the modeling of expansive and shrinkage behavior induced by suction changes. In this way, healing effects during re-saturation may be simulated. Two experimental programs on clay shale samples, performed under triaxial stress conditions will be discussed. In the first case samples of Opalinus shale were subjected to a series of gas pulse decay tests during the application of stress paths involving a particular sequence of confining stress and shearing up to failure. In the second experimental program, performed on a tertiary mudstone from the Norwegian shelf, attention was paid to the effect of bedding-induced anisotropy. Experimental results will be

  14. Housing Policies and Health Inequalities.

    PubMed

    Marí-Dell'Olmo, Marc; Novoa, Ana M; Camprubí, Lluís; Peralta, Andrés; Vásquez-Vera, Hugo; Bosch, Jordi; Amat, Jordi; Díaz, Fernando; Palència, Laia; Mehdipanah, Roshanak; Rodríguez-Sanz, Maica; Malmusi, Davide; Borrell, Carme

    2017-04-01

    A large body of literature shows the link between inadequate housing conditions and poor physical and mental health. The aim of this paper is to summarize the research on the impact of local housing policies on health inequalities, focusing on the issues of access to housing and fuel poverty as studied in the SOPHIE project. Our case studies in Spain showed that people facing housing insecurity, experienced intense levels of mental distress. We found that access to secure and adequate housing can improve the health of these populations, therefore, public policies that address housing instability and their consequences are urgently needed. Housing conditions related to fuel poverty are associated with poorer health and are unevenly distributed across Europe. We found possible positive effects of façade insulation interventions on cold-related mortality in women living in social housing; but not in men. Policies on housing energy efficiency can reduce the health consequences of fuel poverty, but need to be free to users, target the most vulnerable groups and be adaptable to their needs.

  15. Farmworker Housing: A Photo Essay.

    PubMed

    Arcury, Thomas A; Summers, Phillip

    2015-11-01

    Migrant and seasonal farmworkers often reside in poor housing conditions which expose them to numerous hazards. These housing conditions are an issue of environmental health and justice. The photographs in this essay illustrate the living conditions confronted by farmworkers, offering a visual context for the reviews published in this issue of New Solutions. Farmworker housing conditions are often shocking to those who have not visited farmworker communities. Continued research is needed to document these conditions, how they affect the health of farmworkers, and provide leverage in the struggle to improve farmworker housing conditions.

  16. Films, Buckypapers and Fibers from Clay, Chitosan and Carbon Nanotubes

    PubMed Central

    Higgins, Thomas M.; Warren, Holly; Panhuis, Marc in het

    2011-01-01

    The mechanical and electrical characteristics of films, buckypapers and fiber materials from combinations of clay, carbon nanotubes (CNTs) and chitosan are described. The rheological time-dependent characteristics of clay are maintained in clay–carbon nanotube–chitosan composite dispersions. It is demonstrated that the addition of chitosan improves their mechanical characteristics, but decreases electrical conductivity by three-orders of magnitude compared to clay–CNT materials. We show that the electrical response upon exposure to humid atmosphere is influenced by clay-chitosan interactions, i.e., the resistance of clay–CNT materials decreases, whereas that of clay–CNT–chitosan increases.

  17. Inter-layered clay stacks in Jurassic shales

    NASA Technical Reports Server (NTRS)

    Pye, K.; Krinsley, D. H.

    1983-01-01

    Scanning electron microscopy in the backscattered electron mode is used together with energy-dispersive X-ray microanalysis to show that Lower Jurassic shales from the North Sea Basin contain large numbers of clay mineral stacks up to 150 microns in size. Polished shale sections are examined to determine the size, shape orientation, textural relationships, and internal compositional variations of the clays. Preliminary evidence that the clay stacks are authigenic, and may have formed at shallow burial depths during early diagenesis, is presented.

  18. Polymer-clay nanocomposites as precursors of nanostructured carbon materials for electrochemical devices: templating effect of clays.

    PubMed

    Fernández-Saavedra, Rocío; Darder, Margarita; Gómez-Avilés, Almudena; Aranda, Pilar; Ruiz-Hitzky, Eduardo

    2008-04-01

    The present work introduces a comparative study on the use of polymer nanocomposites containing clay minerals of different structure, such as montmorillonite and sepiolite as host solids for the templating synthesis of carbon-like materials from different organic precursors. Carbon-clay nanocomposites were obtained by polymerization of either acrylonitrile or sucrose previously inserted in the pores of the clay minerals, followed by their further thermal transformation in carbon-like compounds. Acid treatment of the resulting carbon-clay nanocomposites removes the inorganic templates giving carbon-like materials with different textural features. Polymer-clay, carbon-clay and carbon-like materials have been characterized by applying spectroscopic techniques as FTIR and in situ EIS (electrochemical impedance spectroscopy) and other structural, textural and analytical tools (chemical analysis, XRD, SEM-EDX, TEM-EDX, N2 adsorption isotherms,...). Electrochemical properties of these carbon-clay nanocomposites, as well as their templated carbonaceous materials and their use as electrode materials of different electrochemical devices such as rechargeable Li-batteries, supercapacitors and electrochemical sensors, are also discussed.

  19. Crude oil polycyclic aromatic hydrocarbons removal via clay-microbe-oil interactions: Effect of acid activated clay minerals.

    PubMed

    Ugochukwu, Uzochukwu C; Fialips, Claire I

    2017-03-09

    Acid treatment of clay minerals is known to modify their properties such as increase their surface area and surface acidity, making them suitable as catalysts in many chemical processes. However, the role of these surface properties during biodegradation processes of polycyclic aromatic hydrocarbons (PAHs) is only known for mild acid (0.5 M Hydrochloric acid) treated clays. Four different clay minerals were used for this study: a montmorillonite, a saponite, a palygorskite and a kaolinite. They were treated with 3 M hydrochloric acid to produce acid activated clay minerals. The role of the acid activated montmorillonite, saponite, palygorskite and kaolinite in comparison with the unmodified clay minerals in the removal of PAHs during biodegradation was investigated in microcosm experiments. The microcosm experiments contained micro-organisms, oil, and clays in aqueous medium with a hydrocarbon degrading microorganism community predominantly composed of Alcanivorax spp. Obtained results indicated that acid activated clays and unmodified kaolinite did not enhance the biodegradation of the PAHs whereas unmodified montmorillonite, palygorskite and saponite enhanced their biodegradation. In addition, unmodified palygorskite adsorbed the PAHs significantly due to its unique channel structure.

  20. Influence of herbicide structure, clay acidity, and humic acid coating on acetanilide herbicide adsorption on homoionic clays.

    PubMed

    Liu, Weiping; Gan, Jianying; Yates, Scott R

    2002-07-03

    Adsorption of chloroacetanilide herbicides on homoionic montmorillonite was studied by coupling batch equilibration and FT-IR analysis. Adsorption decreased in the order metolachlor > acetochlor > alachlor > propachlor on Ca(2+)- or Mg(2+)-saturated clays and in the order metolachlor > alachlor > acetachlor > propachlor on Al(3+)- or Fe(3+)-saturated clays. FT-IR spectra showed that the carbonyl group of the herbicide molecule was involved in bonding. For the same herbicide, adsorption of alachlor, acetachlor, and metolachlor on clay followed the order Ca(2+) approximately Mg(2+) < Al(3+) < or = Fe(3+), which coincided with the increasing acidity of homoionic clays. Adsorption of propachlor, however, showed an opposite dependence, suggesting a different governing interaction. In clay and humic acid mixtures, herbicide adsorption was less than that expected from independent additive adsorption by the individual constituents, and the deviation was dependent on the clay-to-humic acid ratio, with the greatest deviation consistently occurring at a 60:40 clay-to-humic acid ratio.

  1. 1. Oil house, keeper's house, Southern Light Tower and Northern ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. Oil house, keeper's house, Southern Light Tower and Northern Light Tower, view northwest, south and east sides - Kennebec River Light Station, South side of Doubling Point Road, off State Highway 127, 1.8 miles south of U.S. Route 1, Arrowsic, Sagadahoc County, ME

  2. Housing in America 1985/86. Current Housing Report.

    ERIC Educational Resources Information Center

    Current Housing Report, 1989

    1989-01-01

    A wide variety of data, collected in 1985 and 1986, is presented in this first biennial report that deals with U.S. housing and the demographic, social, and economic characteristics of its occupants. The U.S. Census American Housing Survey of 1985 is the primary database for the report, which provides an excellent resource for teacher background…

  3. Subsidized Housing, Public Housing, and Adolescent Violence and Substance Use

    ERIC Educational Resources Information Center

    Leech, Tamara G. J.

    2012-01-01

    This study examines the separate relationships of public housing residence and subsidized housing residence to adolescent health risk behavior. Data include 2,530 adolescents aged 14 to 19 who were children of the National the Longitudinal Study of Youth. The author used stratified propensity methods to compare the behaviors of each…

  4. Mineralogy of subducted clay and clay restite in the lower mantle

    NASA Astrophysics Data System (ADS)

    Armstrong, L.; Skora, S. E.; Walter, M. J.

    2012-12-01

    Seismic tomography indicates that subducting oceanic lithosphere often penetrates the transition zone and eventually the lower mantle [e.g. 1, 2]. While mineralogical changes in the mafic and ultramafic portions of slabs have been well documented experimentally, the phase relations of overlying sediments at pressures above 25 GPa remain poorly studied. This is in part because sediments are expected to partially melt at sub-arc depth (P~2.5-4.5 GPa), and contribute to the genesis of arc magmas. Sediment restites left behind after the extraction of low pressure melts undergo major chemical changes, according to the melting reaction: Coe+Phen+Cpx+H2O = Grt+Ky+Melt [3]. However, sediments may not always melt depending on the thermal regime and volatile availability and composition [3]. Hence, chemically unmodified sediments as well as restites may be entrained to greater depths and contribute to compositional heterogeneity in the deep mantle. Indeed, mineral inclusions with compositions indicative of subducted sedimentary protoliths (CAS-phase; K-hollandite; stishovite) have been reported in 'ultradeep' diamonds and suggest that deep subduction and survival of sediments occurs to at least transition zone depths [4]. With this in mind, we have performed laser heated diamond anvil cell experiments at pressures of 8-80 GPa on two anhydrous glass starting materials: a marine clay and the restite that is left after 50% melt extraction of this clay at 3 GPa and 800 °C [3]. We chose to work with an anhydrous version of the marine clay given that the investigated pressure range exceeds that of phengite stability [5], and phengite is the only hydrous phase in subducted sediments at UHP conditions. The clay was heated along a P-T path representative of a cold subduction geotherm, whereas the clay restite was heated along a hotter subduction geotherm consistent with low pressure melting. Phases were identified by synchrotron X-ray micro-diffraction at beamline I15 of the Diamond

  5. Sorption of tylosin on clay minerals.

    PubMed

    Zhang, Qian; Yang, Chen; Huang, Weilin; Dang, Zhi; Shu, Xiaohua

    2013-11-01

    The equilibrium sorption of tylosin (TYL) on kaolinite and montmorillonite was measured at different solution pH using batch reactor systems. The results showed that all the sorption isotherms were nonlinear and that the nonlinearity decreased as the solution pH increased for a given clay. At a specific aqueous concentration, the single-point sorption distribution coefficient (KD) of TYL decreased rapidly as the solution pH increased. A speciation-dependent sorption model that accounted for the contributions of the cationic and neutral forms of TYL fit the data well, suggesting that the sorption may be dominated by both ion exchange and hydrophobic interactions. The isotherm data also fit well to a dual mode model that quantifies the contributions of a site-limiting Langmuir component (ion exchange) and a non-specific linear partitioning component (hydrophobic interactions). X-ray diffraction analyses revealed that the interlayers of montmorillonite were expanded due to the uptake of TYL. TYL molecules likely form a monolayer surface coverage.

  6. Using solar dryers to dry clay bricks

    SciTech Connect

    Bernal, J.A.; Wicker, R.B.

    1996-12-31

    Experiments using a small-scale solar dryer have been performed to determine the effect of incorporating solar dryers in the pre-firing stage of clay brick production. A comparison of brick moisture content over time is presented for dry bricks that underwent additional drying either naturally through direct exposure, in convection ovens set at 65.6 C and 104 C, in the solar dryer, or sealed in plastic bags. The ambient temperature and relative humidity were monitored along with the solar dryer temperature. Results indicated the solar dryer removed from one to two percent more moisture than natural drying, but removed less moisture than did the ovens. A similar comparison of wet bricks naturally dried, oven dried, and placed in the solar dryer for periods of five and seven days is also presented. The solar dryer reduced the amount of time required for bricks to be dried to a specified moisture content and increased the amount of moisture removed for a given amount of time.

  7. Clay nanotube composites for antibacterial nanostructured coatings

    NASA Astrophysics Data System (ADS)

    Boyer, Christen J.

    A surging demand for the development of new antimicrobial nanomaterials exists due to the frequency of medical device-associated infections and the transfer of pathogens from highly touched objects. Naturally occurring halloysite clay nanotubes (HNTs) have shown to be ideal particles for polymer reinforcement, time-release drug delivery, nano-reactor synthesis, and as substrate material for nanostructured coatings. This research demonstrates the feasibility of a novel method for coating HNTs with metals for antibacterial applications. The first ever ability to coat HNTs through electrolysis was developed for customizable and multi-functional antibacterial nanoparticle platforms. HNTs were investigated as substrate for the deposition of copper (Cu) and silver (Ag) metal nanoparticles through electrochemical syntheses, and as a platform for nano-structured antibacterial polymer composites. Characterization of interfacial and material properties demonstrated the feasibility of electrolysis as a new efficient and replicable nano-scale surface modification route. Methods of encapsulating HNTs in nanofibers, three-dimensional printer filaments, and multifunctional polymer rubbers were also realized. The nanofabrication methods, nanoparticles, and polymer composites created in this work were novel, scalable, easy-to-replicate, and displayed antibacterial features with tunable properties.

  8. Sedimentation of athermal particles in clay suspensions

    NASA Astrophysics Data System (ADS)

    Clotet, Xavier; Kudrolli, Arshad

    2015-03-01

    We discuss sedimentation of athermal particles in dense clay suspensions which appear liquid-like to glass-like. These studies are motivated by the physics important to a diverse range of problems including remediation of oil sands after the extraction of hydrocarbons, and formation of filter cakes in bore wells. We approach this problem by first considering collective sedimentation of athermal spherical particles in a viscous liquid in quasi-two dimensional and three dimensional containers. We examine the system using optical and x-ray tomography techniques which gives particle level information besides global information on the evolution of the volume fraction. Unlike sediments in the dilute limit - which can be modeled as isolated particles that sediment with a constant velocity and slow down exponentially as they approach the bottom of the container - we find interaction between the particles through the viscous fluids leads to qualitatively differences. We find significant avalanching behavior and cooperative motion as the grains collectively settle, and non-exponential increase in settling time. We discuss the effect of stirring caused by the sedimenting particles on their viscosity and consequently the sedimentation rates as a function of particle concentration. Supported by Petroleum Research Fund Grant PRF # 54045-ND9.

  9. Development of a Measure of Housing and Housing Services.

    PubMed

    Clark, Colleen; Young, M Scott; Teague, Gregory; Rynearson-Moody, Sarah

    2016-01-01

    The Housing Program Measure (HPM) was designed to document critical elements of a range of housing program types and associated services. Qualitative methods, including literature review and open-ended interviews, were used to determine pertinent HPM domains and to develop the pool of items. The measure was pre-tested, and reliability and validity analyses were applied to revise and strengthen the measure. The resulting measure furthers homelessness research by providing a tool that can be used to define housing and housing services interventions across diverse projects and disciplines, to facilitate program management by matching housing resources to the needs of homeless individuals, and to support model development by measuring progress to goals.

  10. Preparation and thermal properties of Zr-intercalated clays

    SciTech Connect

    Figueras, F.; Mattrod-Bashi, A.; Fetter, G.; Thrierr, A. ); Zanchetta, J.V. )

    1989-09-01

    Montmorillonites intercalated by zirconium macrocations have been prepared. Diffusion of the Zr cations within the particles of clay controls the rate of ion exchange, and hence the distribution of the Zr pillars. This effect accounts for the influence of particle size on the degree of exchange, the surface area, and the thermal stability of the pillared clay. The thermal stability of the Zr clays prepared under these conditions is limited to 973 K in dry air. The changes in microporosity, evaluated from nitrogen adsorption using the equation of Dubinin, show that collapse of the structure occurs by sintering of the pillars. This sintering can be decreased by doping the pillars with rare earth cations. The resulting material then retains a surface area of 180 m{sup 2}/g after calcination at 1023 K in dry air, and is more acidic than the corresponding Zr-clay.

  11. Modeling Coupled Processes in Clay Formations for Radioactive Waste Disposal

    SciTech Connect

    Liu, Hui-Hai; Rutqvist, Jonny; Zheng, Liange; Sonnenthal, Eric; Houseworth, Jim; Birkholzer, Jens

    2010-08-31

    As a result of the termination of the Yucca Mountain Project, the United States Department of Energy (DOE) has started to explore various alternative avenues for the disposition of used nuclear fuel and nuclear waste. The overall scope of the investigation includes temporary storage, transportation issues, permanent disposal, various nuclear fuel types, processing alternatives, and resulting waste streams. Although geologic disposal is not the only alternative, it is still the leading candidate for permanent disposal. The realm of geologic disposal also offers a range of geologic environments that may be considered, among those clay shale formations. Figure 1-1 presents the distribution of clay/shale formations within the USA. Clay rock/shale has been considered as potential host rock for geological disposal of high-level nuclear waste throughout the world, because of its low permeability, low diffusion coefficient, high retention capacity for radionuclides, and capability to self-seal fractures induced by tunnel excavation. For example, Callovo-Oxfordian argillites at the Bure site, France (Fouche et al., 2004), Toarcian argillites at the Tournemire site, France (Patriarche et al., 2004), Opalinus clay at the Mont Terri site, Switzerland (Meier et al., 2000), and Boom clay at Mol site, Belgium (Barnichon et al., 2005) have all been under intensive scientific investigations (at both field and laboratory scales) for understanding a variety of rock properties and their relations with flow and transport processes associated with geological disposal of nuclear waste. Clay/shale formations may be generally classified as indurated and plastic clays (Tsang et al., 2005). The latter (including Boom clay) is a softer material without high cohesion; its deformation is dominantly plastic. For both clay rocks, coupled thermal, hydrological, mechanical and chemical (THMC) processes are expected to have a significant impact on the long-term safety of a clay repository. For

  12. Studies on structural properties of clay magnesium ferrite nano composite

    NASA Astrophysics Data System (ADS)

    Kaur, Manpreet; Singh, Mandeep; Jeet, Kiran; Kaur, Rajdeep

    2015-08-01

    Magnesium ferrite-bentonite clay composite was prepared by sol-gel combustion method employing citric acid as complexing agent and fuel. The effect of clay on the structural properties was studied with X-ray diffraction (XRD), Fourier transform infrared (FT-IR) Spectroscopy, Scanning electron microscopy (SEM), SEM- Energy dispersive Spectroscope (EDS) and BET surface area analyzer. Decrease in particle size and density was observed on addition of bentonite clay. The BET surface area of nano composite containing just 5 percent clay was 74.86 m2/g. Whereas porosity increased from 40.5 per cent for the pure magnesium ferrite to 81.0 percent in the composite showing that nano-composite has potential application as an adsorbent.

  13. Thermodynamically coupled mass transport processes in a saturated clay

    SciTech Connect

    Carnahan, C.L.

    1984-11-01

    Gradients of temperature, pressure, and fluid composition in saturated clays give rise to coupled transport processes (thermal and chemical osmosis, thermal diffusion, ultrafiltration) in addition to the direct processes (advection and diffusion). One-dimensional transport of water and a solute in a saturated clay subjected to mild gradients of temperature and pressure was simulated numerically. When full coupling was accounted for, volume flux (specific discharge) was controlled by thermal osmosis and chemical osmosis. The two coupled fluxes were oppositely directed, producing a point of stagnation within the clay column. Solute flows were dominated by diffusion, chemical osmosis, and thermal osmosis. Chemical osmosis produced a significant flux of solute directed against the gradient of solute concentration; this effect reduced solute concentrations relative to the case without coupling. Predictions of mass transport in clays at nuclear waste repositories could be significantly in error if coupled transport processes are not accounted for. 14 references, 8 figures, 1 table.

  14. Evaluation of modified clay coagulant for sewage treatment.

    PubMed

    Jiang, Jia-Qian; Zeng, Zhiqiang; Pearce, Pete

    2004-07-01

    The use of modified clays as coagulants for sewage treatment was investigated in this study. The raw clays were montmorillonites K10 and KSF, and were modified by polymeric Al or Fe and/or Al/Fe mixing polymeric species. The comparative performance of modified clays and aluminium sulphate and ferric sulphate were evaluated in terms of the removal of turbidity, suspended solids, UV(254)-abs, colour, and total and soluble CODs. The results demonstrated that after being modified with mixing polymeric Al/Fe species, two montmorillonite clays possess greater properties to remove the particles (as suspended solids) and organic pollutants (as COD and UV(254)-abs) from the sewage and to enhance the particle settling rate significantly.

  15. Mechanism of fatigue failure of clay-epoxy nanocomposites.

    PubMed

    Juwono, Ariadne; Edward, Graham

    2006-12-01

    This work investigates the fatigue behaviour and the mechanism of fatigue failure of an epoxy resin with a dispersion of modified layered silicates in the polymer matrix. The fatigue properties are very important for structural application of nanocomposite materials. Clay-epoxy nanocomposites were successfully synthesized with a commercially available 1-Methylimidazole curing agent. The XRD and TEM findings demonstrated a pattern of clay morphology typically found in nanocomposite systems. The fatigue performance and fatigue failure mechanism of the clay-epoxy materials were studied under repetitive bending loads. The results showed that the fatigue life of filled epoxy improved significantly at strain amplitudes below a threshold value. The E-SEM observations of the epoxy and the clay-epoxy fracture surfaces showed different patterns. In conclusion, the addition of silicate strongly determines the fracture mechanism and enhances the fatigue performance.

  16. A simple approach for calculating pile skin friction in clays

    SciTech Connect

    Mirza, U.A.A.

    1995-12-31

    A simple method is presented for calculating static shaft resistance of a pile driven into clay. The method is based on correlations established for North Sea clays between index properties and strengths. Application of the method to half a dozen full scale pile load tests which are part of the API RP2A`s data base and include a wide range of plasticity properties, overconsolidation ratios and strengths, is described. Except for short piles in very stiff to hard clays, the predictions agree very well with the measurements. The correlations presented allows an assessment of residual skin friction and indicate the importance of the liquidity index of the clay in static capacity calculations.

  17. Kinetics of plutonium and americium sorption to natural clay.

    PubMed

    Lujanienė, Galina; Beneš, Petr; Štamberg, Karel; Ščiglo, Tomas

    2012-06-01

    Kinetics of Pu(IV) and Am(III) sorption from natural groundwater to three types of clays were studied at trace concentrations of the elements. Higher K(d) values were determined for sorption of Pu than of Am, and no clear dependence of the K(d) values and the kinetic coefficients on the composition of the clays can be deduced. Kinetic data evaluated by models for six different control processes indicated a sorption mechanism controlled by Pu or Am diffusion in the inert layer on the surface of the clays. Apart from the kinetics of the elements sorption, time-dependent changes in their bonding nature were also studied using a sequential extraction. It was found that Pu(IV) was predominantly associated with amorphous and crystalline Fe oxides as well as natural organic matter sites on the clays, whereas in the case of Am(III) the exchangeable and carbonate sites played the principal role.

  18. Clay mineralogy of weathering profiles from the Carolina Piedmont.

    USGS Publications Warehouse

    Loferski, P.J.

    1981-01-01

    Saprolite profiles (12) that formed over various crystalline rocks from the Charlotte 1o X 2o quadrangle showed overall similarity in their clay mineralogy to depths of 6 to 45 m indicating control by weathering processes rather than by rock type. Most saprolite contained 10-25% clay, and ranged 3 to 70%. Kaolinite and halloysite composed = or >75% of the clay fraction of most samples. The ratio kaolinite:halloysite ranged widely, from 95% kaolinite to 90% halloysite, independent of depth. Clay-size mica was present in all profiles, and ranged 5-75% over a sericite schist. Mixed-layer mica-smectite and mica-vermiculite were subordinate; discrete smectite and vermiculite were rare. The abundance of halloysite indicates a continuously humid environment since the time of profile formation, because of the rapidity with which halloysite dehydrates irreversibly. -R.S.M.

  19. Intercalation of Trichloroethene by Sediment-Associated Clay Minerals

    SciTech Connect

    Matthieu, Donald E.; Brusseau, Mark; Johnson, G. R.; Artiola, J. L.; Bowden, Mark E.; Curry, J. E.

    2013-01-01

    The objective of this research was to examine the potential for intercalation of trichloroethene (TCE) by clay minerals associated with aquifer sediments. Sediment samples were collected from a field site inTucson, AZ. Two widely used Montmorillonite specimen clays were employed as controls. X-ray diffraction, conducted with a controlled-environment chamber, was used to characterize smectite interlayer dspacing for three treatments (bulk air-dry sample, sample mixed with synthetic groundwater, sample mixed with TCE-saturated synthetic groundwater). The results show that the d-spacing measured for the samples treated with TCE-saturated synthetic groundwater are larger (*26%) than those of the untreated samples for all field samples as well as the specimen clays. These results indicate that TCE was intercalated by the clay minerals, which may have contributed to the extensive elution tailing observed in prior miscible-displacement experiments conducted with this sediment.

  20. Characterization of low-purity clays for geopolymer binder formulation

    NASA Astrophysics Data System (ADS)

    Mostafa, Nasser Y.; Mohsen, Q.; El-maghraby, A.

    2014-06-01

    The production of geopolymer binders from low-purity clays was investigated. Three low-purity clays were calcined at 750°C for 4 h. The calcined clays were chemically activated by the alkaline solutions of NaOH and Na2SiO3. The compressive strength was measured as a function of curing time at room temperature and 85°C. The results were compared with those of a pure kaolin sample. An amorphous aluminosilicate polymer was formed in all binders at both processing temperatures. The results show that, the mechanical properties depend on the type and amount of active aluminum silicates in the starting clay material, the impurities, and the processing temperature.

  1. Studies on structural properties of clay magnesium ferrite nano composite

    SciTech Connect

    Kaur, Manpreet Singh, Mandeep; Jeet, Kiran Kaur, Rajdeep

    2015-08-28

    Magnesium ferrite-bentonite clay composite was prepared by sol-gel combustion method employing citric acid as complexing agent and fuel. The effect of clay on the structural properties was studied with X-ray diffraction (XRD), Fourier transform infrared (FT-IR) Spectroscopy, Scanning electron microscopy (SEM), SEM- Energy dispersive Spectroscope (EDS) and BET surface area analyzer. Decrease in particle size and density was observed on addition of bentonite clay. The BET surface area of nano composite containing just 5 percent clay was 74.86 m{sup 2}/g. Whereas porosity increased from 40.5 per cent for the pure magnesium ferrite to 81.0 percent in the composite showing that nano-composite has potential application as an adsorbent.

  2. Common clay and shale: a look at 2009 activity

    USGS Publications Warehouse

    Virta, R.L.

    2010-01-01

    An overview of clay and shale production, consumption, and prices in 2009 is presented. The industry has seen 15 to 20 percent declines during the past two years, yet producers still expect sales to decline in 2010.

  3. [Kinetics and mechanism of removing Microcystis aeruginosa using clay flocculation].

    PubMed

    Pan, Gang; Zhang, Mingming; Yan, Hai; Zou, Hua; Chen, Hao

    2003-09-01

    Twenty-six natural clays were studied for their kinetics of flocculating and removing algal cells of Microcystis aeruginosa. According to the 8 h equilibrium removal efficiencies and removal rates at a clay-loading of 0.7 g.L-1, all the 26 clays were classified into three categories. Type-I clay, which includes talc, ferric oxide, sepiolite, ferroferric oxide, and kaolinite, has an equilibrium removal efficiency greater than 90%, a t50 (time needed to remove 50% of the algae) of less than 30 min, and a t80 (time needed to remove 80% of the algae) of less than 2.5 h. Type-II clay, which includes argillanceous rocks, attapulgite, rectorite, illite, and argil, etc., has an equilibrium removal efficiency of 50%-80%, a t50 of less than 2.5 h, and a t80 of more than 5 h. Type-III clay consists of 14 minerals, including laterite, zeolite, mica, clinoptilolite, pumice, tripoli, feldspar and quartz, etc. with the removal efficiency less than 50%, and t50 > > 8 h. When the clay loading was decreased to 0.1-0.2 g.L-1, the 8 h equilibrium removal efficiencies for 25 clays declined to below 60%, except for sepiolite, a Type-I clay, which maintained around 90%. After the sepiolite was modified with Fe3+ to increase its surface charge (Zeta potential from -24.0 mV to +0.43 mV at pH 7.4), the initial removal rate was increased remarkably although its 8 h equilibrium removal efficiency was not improved substantially. As a comparison, the 8 h equilibrium removal efficiency of PAC was no greater than 40% at loadings of 0.02-0.2 g.L-1. Following the analysis of the flocculation mechanism it was concluded that the effect of bridging and netting may play a key role in the clay-algae flocculation processes, which may be important for selecting and modifying clays to improve significantly the removal efficiency.

  4. Lead removal from aqueous solutions by a Tunisian smectitic clay.

    PubMed

    Chaari, Islem; Fakhfakh, Emna; Chakroun, Salima; Bouzid, Jalel; Boujelben, Nesrine; Feki, Mongi; Rocha, Fernando; Jamoussi, Fakher

    2008-08-15

    The adsorption of Pb(2+) ions onto Tunisian smectite-rich clay in aqueous solution was studied in a batch system. Four samples of clay (AYD, AYDh, AYDs, AYDc) were used. The raw AYD clay was sampled in the Coniacian-Early Campanian of Jebel Aïdoudi in El Hamma area (South of Tunisia). AYDh and AYDs corresponds to AYD activated by 2.5 mol/l hydrochloric acid and 2.5 mol/l sulphuric acid, respectively. AYDc corresponds to AYD calcined at different temperatures (100, 200, 300, 400, 500 and 600 degrees C). The raw AYD clay was characterized by X-ray diffraction, chemical analysis, infrared spectroscopy and coupled DTA-TGA. Specific surface area of all the clay samples was determined from nitrogen adsorption isotherms. Preliminary adsorption tests showed that sulphuric acid and hydrochloric acid activation of raw AYD clay enhanced its adsorption capacity for Pb(2+) ions. However, the uptake of Pb(2+) by AYDs was very high compared to that by AYDh. This fact was attributed to the greater solubility of clay minerals in sulphuric acid compared to hydrochloric acid. Thermic activation of AYD clay reduced the Pb(2+) uptake as soon as calcination temperature reaches 200 degrees C. All these preliminary results were well correlated to the variation of the specific surface area of the clay samples. The ability of AYDs sample to remove Pb(2+) from aqueous solutions has been studied at different operating conditions: contact time, adsorbent amount, metal ion concentration and pH. Kinetic experiments showed that the sorption of lead ions on AYDs was very fast and the equilibrium was practically reached after only 20 min. The results revealed also that the adsorption of lead increases with an increase in the solution pH from 1 to 4.5 and then decreases, slightly between pH 4.5 and 6, and rapidly at pH 6.5 due to the precipitation of some Pb(2+) ions. The equilibrium data were analysed using Langmuir isotherm model. The maximum adsorption capacity (Q(0)) increased from 25 to 25

  5. Heteroaggregation of Silver Nanoparticles with Clay Minerals in Aqueous System

    NASA Astrophysics Data System (ADS)

    Liu, J.; Burrow, E.; Hwang, Y.; Lenhart, J.

    2013-12-01

    Nanoparticles are increasingly being used in industrial processes and consumer products that exploit their beneficial properties and improve our daily lives. Nevertheless, they also attract attention when released into natural environment due to their potential for causing adverse effects. The fate and transport of nanoparticles in aqueous systems have been the focus of intense study. However, their interactions with other natural particles have received only limited attention. Clay minerals are ubiquitous in most aquatic systems and their variably charged surfaces can act as deposition sites that can alter the fate and transport of nanoparticles in natural aqueous environments. In this study, we investigated the homoaggregation of silver nanoparticles with different coating layers and their heteroaggregation behavior with clay minerals (illite, kaolinite, montmorillonite) in neutral pH solutions. Silver nanoparticles with a nominal diameter of 80 nm were synthesized with three different surface coating layers: uncoated, citrate-coated and Tween-coated. Illite (IMt-2), kaolinite (KGa-2), and montmorillonite (SWy-2) were purchased from the Clay Mineral Society (Indiana) and pretreated to obtain monocationic (Na-clay) and dicationic (Ca-clay) suspensions before the experiments. The change in hydrodynamic diameter as a function of time was monitored using dynamic light scattering (DLS) measurements in order to evaluate early stage aggregation as a function of electrolyte concentration in both the homo- and heteroaggregation scenarios. A shift in the critical coagulation concentration (CCC) values to lower electrolyte concentrations was observed in binary systems, compared to single silver nanoparticle and clay systems. The results also suggest more rapid aggregation in binary system during the early aggregation stage when compared to the single-particle systems. The behavior of citrate-coated silver nanoparticles was similar to that of the bare particles, while the

  6. Housing for Moderate Income Households.

    ERIC Educational Resources Information Center

    Brannigan, Vincent M.; Meeks, Carol B.

    1991-01-01

    Describes equity leasing, a program that enables people to acquire housing without an up-front investment but with an incentive to maintain and improve the property. Under this proposal, lessees would acquire a leasehold interest in a house and own the right to use the property for a continuously extended lease term. (JOW)

  7. Welcome to the House System

    ERIC Educational Resources Information Center

    Green, Daniel G.

    2006-01-01

    Searching for ways to help students feel more connected to one another and to the school community as a whole, a junior high school implemented the social house approach. Social houses divide students into multiple social units, rather than into separate academic entities. Each unit has its own identity and theme.The different groups mix during…

  8. The Philosophy of University Housing

    ERIC Educational Resources Information Center

    Wallace, James A.

    2012-01-01

    This article examines a stated philosophy of university housing and the philosophy's effect on the facilitation of the personal and intellectual growth of students residing in the residence halls and the development of a sense of community. This particular philosophy governs the housing operations at Southern Illinois University at Carbondale.…

  9. Smart Houses and Uncomfortable Homes.

    PubMed

    Alm, Norman; Arnott, John

    2015-01-01

    In order for smart houses to achieve acceptance from potential beneficiaries they will need to match the users' expectation that their house is also their home, with the sense of privacy and control that this implies. Designers of this technology will need to be aware of findings in this regard from fields such as architecture and design ethnography.

  10. Urban Decline and Durable Housing.

    ERIC Educational Resources Information Center

    Glaeser, Edward L.; Gyourko, Joseph

    2005-01-01

    Urban decline is not the mirror image of growth, and durable housing is the primary reason the nature of decline is so different. This paper presents a model of urban decline with durable housing and verifies these implications of the model: (1) city growth rates are skewed so that cities grow more quickly than they decline; (2) urban decline is…

  11. New Trends in Student Housing.

    ERIC Educational Resources Information Center

    Koch, David; Wesse, David; Stickney, Robert

    1999-01-01

    Discusses the influence of residence halls in supporting a college's admissions and recruiting process for attracting highly qualified students. It explores the trends in student housing needs and how a school can meet those needs, and examines possible funding solutions for dormitory renovations. Recommendations for developing housing strategies…

  12. Chemical reactions of organic compounds on clay surfaces.

    PubMed Central

    Soma, Y; Soma, M

    1989-01-01

    Chemical reactions of organic compounds including pesticides at the interlayer and exterior surfaces of clay minerals and with soil organic matter are reviewed. Representative reactions under moderate conditions possibly occurring in natural soils are described. Attempts have been made to clarify the importance of the chemical nature of molecules, their structures and their functional groups, and the Brönsted or Lewis acidity of clay minerals. PMID:2533556

  13. Mössbauer Spectra of Clays and Ceramics

    NASA Astrophysics Data System (ADS)

    Wagner, F. E.; Wagner, U.

    2004-06-01

    The physical, chemical and mineralogical aspects of the use of Mössbauer spectroscopy in studies of clay-based ceramics are described. Mössbauer spectra of pottery clays fired under oxidising, reducing and changing conditions are explained, and the possibilities of using Mössbauer spectra to derive information on the firing temperatures and the kiln atmosphere during firing in antiquity are discussed and illustrated by examples.

  14. Self-affinity and Crossover of A Clay Deposit

    NASA Astrophysics Data System (ADS)

    Fossum, J. O.; Huru Bergene, H.; Hansen, A.; Manificat, G.

    Self-affine dehydrated colloidal deposits on fresh mica surfaces of the synthetic 2:1 smectite clay laponite have been studied by means of Atomic Force Microscopy. AFM images of these prepared assemblies of sol and gel aggregates have been analyzed both by means of standard AFM software, and wavelet methods. The deposited surfaces show an anti-persistent to persistent crossover with a clay concentration dependent crossover length. It is thus concluded that the investigated electrolyte concentrations play a minor role

  15. Experimental study of Human Adenoviruses interactions with clays

    NASA Astrophysics Data System (ADS)

    Bellou, Maria; Syngouna, Vasiliki; Paparrodopoulos, Spyros; Vantarakis, Apostolos; Chrysikopoulos, Constantinos

    2014-05-01

    Clays are used to establish low permeability liners in landfills, sewage lagoons, water retention ponds, golf course ponds, and hazardous waste sites. Human adenoviruses (HAdVs) are waterborne viruses which have been used as viral indicators of fecal pollution. The objective of this study was to investigate the survival of HAdV in static and dynamic clay systems. The clays used as a model were crystalline aluminosilicates: kaolinite and bentonite. The adsorption and survival of HAdVs onto these clays were characterized at two different controlled temperatures (4 and 25o C) under static and dynamic batch conditions. Control tubes, in the absence of clay, were used to monitor virus inactivation due to factors other than adsorption to clays (e.g. inactivation or sorption onto the tubes walls). For both static and dynamic batch experiments, samples were collected for a maximum period of seven days. This seven day time - period was determined to be sufficient for the virus-clay systems to reach equilibrium. To infer the presence of infectious HAdV particles, all samples were treated with Dnase and the extraction of viral nucleid acid was performed using a commercial viral RNA kit. All samples were analyzed by Real - Time PCR which was used to quantify viral particles in clays. Samples were also tested for virus infectivity by A549 cell cultures. Exposure time intervals in the range of seven days (0.50-144 hours) resulted in a load reduction of 0.74 to 2.96 logs for kaolinite and a reduction of 0.89 to 2.92 for bentonite. Furthermore, virus survival was higher onto bentonite than kaolinite (p

  16. Fiber Reinforcement for Rapid Stabilization of Soft Clay Soils

    DTIC Science & Technology

    2006-11-01

    AFRL-RX-TY-TP-2009-4603 FIBER REINFORCEMENT FOR RAPID STABILIZATION OF SOFT CLAY SOILS Susan D. Rafalko, Thomas L. Brandon...Include area code) 14-NOV-2006 Technical Paper 11-AUG-2006 -- 14-NOV-2006 Fiber Reinforcement for Rapid Stabilization of Soft Clay Soils FA8651-04-C...military has sought methods for rapid stabilization of weak soils for support of its missions worldwide. Over the past 60 years, cement and lime have

  17. Physical Components of the Shear Strength of Saturated Clays.

    DTIC Science & Technology

    1961-01-01

    with minor modifications and limitations to undisturbed clays, but the coefficients entering these relations may be quite different for re- molded and...dupli- cating those existing during the test in which the values of the coefficients were determined. A failure criterion of greater general...fully saturated clays; but the coefficients in this function vary with the soil constituents, including the ions in the pore water or adsorbed on the

  18. Identification of clay minerals in reservoir rocks by FTIR spectroscopy

    NASA Astrophysics Data System (ADS)

    Cong Khang, Vu; Korovkin, Mikhail V.; Ananyeva, Ludmila G.

    2016-09-01

    Clay minerals including kaolinite, montmorillonite and bentonite in oil and gas reservoir rocks are identified by absorption spectra obtained via Fourier Transform Infrared (FTIR) spectroscopy. Bands around 3695, 3666, 3650 and 3630 cm-1 and bands around 3620 and 3400 cm-1 are the most diagnostically reliable for kaolinite and montmorillonite, respectively; also absorption bands in the region of 1200...955 cm-1 are equally diagnostic for all the clay minerals studied.

  19. Painting with Clay: A Study of the Masters

    ERIC Educational Resources Information Center

    Skophammer, Karen

    2010-01-01

    Plasticine clay is a bendable material that is easily manipulated by students of all ages. It is a great material to work with because it does not dry out from day to day, so high-school students can work on an extended project. They do not have to worry about the clay drying and cracking, and the entire work of art does not have to be completed…

  20. 24 CFR 8.33 - Housing adjustments.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 24 Housing and Urban Development 1 2012-04-01 2012-04-01 false Housing adjustments. 8.33 Section 8.33 Housing and Urban Development Office of the Secretary, Department of Housing and Urban Development NONDISCRIMINATION BASED ON HANDICAP IN FEDERALLY ASSISTED PROGRAMS AND ACTIVITIES OF THE DEPARTMENT OF HOUSING...

  1. 45 CFR 605.45 - Housing.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 45 Public Welfare 3 2011-10-01 2011-10-01 false Housing. 605.45 Section 605.45 Public Welfare... § 605.45 Housing. (a) Housing provided by the recipient. A recipient that provides housing to its nonhandicapped students shall provide comparable, convenient, and accessible housing to handicapped students...

  2. 34 CFR 104.45 - Housing.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 34 Education 1 2011-07-01 2011-07-01 false Housing. 104.45 Section 104.45 Education Regulations of... Postsecondary Education § 104.45 Housing. (a) Housing provided by the recipient. A recipient that provides housing to its nonhandicapped students shall provide comparable, convenient, and accessible housing...

  3. 38 CFR 18.445 - Housing.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 38 Pensions, Bonuses, and Veterans' Relief 2 2010-07-01 2010-07-01 false Housing. 18.445 Section....445 Housing. (a) Housing provided by a recipient. A recipient that provides housing to its nonhandicapped students shall provide comparable, convenient, and accessible housing to qualified...

  4. 24 CFR 8.33 - Housing adjustments.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 24 Housing and Urban Development 1 2013-04-01 2013-04-01 false Housing adjustments. 8.33 Section 8.33 Housing and Urban Development Office of the Secretary, Department of Housing and Urban Development NONDISCRIMINATION BASED ON HANDICAP IN FEDERALLY ASSISTED PROGRAMS AND ACTIVITIES OF THE DEPARTMENT OF HOUSING...

  5. 45 CFR 605.45 - Housing.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 45 Public Welfare 3 2013-10-01 2013-10-01 false Housing. 605.45 Section 605.45 Public Welfare... § 605.45 Housing. (a) Housing provided by the recipient. A recipient that provides housing to its nonhandicapped students shall provide comparable, convenient, and accessible housing to handicapped students...

  6. 34 CFR 104.45 - Housing.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 34 Education 1 2010-07-01 2010-07-01 false Housing. 104.45 Section 104.45 Education Regulations of... Postsecondary Education § 104.45 Housing. (a) Housing provided by the recipient. A recipient that provides housing to its nonhandicapped students shall provide comparable, convenient, and accessible housing...

  7. 24 CFR 8.33 - Housing adjustments.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 24 Housing and Urban Development 1 2010-04-01 2010-04-01 false Housing adjustments. 8.33 Section 8.33 Housing and Urban Development Office of the Secretary, Department of Housing and Urban Development NONDISCRIMINATION BASED ON HANDICAP IN FEDERALLY ASSISTED PROGRAMS AND ACTIVITIES OF THE DEPARTMENT OF HOUSING...

  8. 24 CFR 3.405 - Housing.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 24 Housing and Urban Development 1 2010-04-01 2010-04-01 false Housing. 3.405 Section 3.405 Housing and Urban Development Office of the Secretary, Department of Housing and Urban Development... Discrimination on the Basis of Sex in Education Programs or Activities Prohibited § 3.405 Housing. (a)...

  9. 24 CFR 3.405 - Housing.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 24 Housing and Urban Development 1 2011-04-01 2011-04-01 false Housing. 3.405 Section 3.405 Housing and Urban Development Office of the Secretary, Department of Housing and Urban Development... Discrimination on the Basis of Sex in Education Programs or Activities Prohibited § 3.405 Housing. (a)...

  10. 38 CFR 18.445 - Housing.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 38 Pensions, Bonuses, and Veterans' Relief 2 2011-07-01 2011-07-01 false Housing. 18.445 Section....445 Housing. (a) Housing provided by a recipient. A recipient that provides housing to its nonhandicapped students shall provide comparable, convenient, and accessible housing to qualified...

  11. 24 CFR 3.405 - Housing.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 24 Housing and Urban Development 1 2013-04-01 2013-04-01 false Housing. 3.405 Section 3.405 Housing and Urban Development Office of the Secretary, Department of Housing and Urban Development... Discrimination on the Basis of Sex in Education Programs or Activities Prohibited § 3.405 Housing. (a)...

  12. 20 CFR 654.404 - Housing site.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 20 Employees' Benefits 3 2010-04-01 2010-04-01 false Housing site. 654.404 Section 654.404... THE EMPLOYMENT SERVICE SYSTEM Housing for Agricultural Workers Housing Standards § 654.404 Housing site. (a) Housing sites shall be well drained and free from depressions in which water may...

  13. 38 CFR 18.445 - Housing.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 38 Pensions, Bonuses, and Veterans' Relief 2 2014-07-01 2014-07-01 false Housing. 18.445 Section....445 Housing. (a) Housing provided by a recipient. A recipient that provides housing to its nonhandicapped students shall provide comparable, convenient, and accessible housing to qualified...

  14. 24 CFR 3.405 - Housing.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 24 Housing and Urban Development 1 2014-04-01 2014-04-01 false Housing. 3.405 Section 3.405 Housing and Urban Development Office of the Secretary, Department of Housing and Urban Development... Discrimination on the Basis of Sex in Education Programs or Activities Prohibited § 3.405 Housing. (a)...

  15. 45 CFR 605.45 - Housing.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 45 Public Welfare 3 2010-10-01 2010-10-01 false Housing. 605.45 Section 605.45 Public Welfare... § 605.45 Housing. (a) Housing provided by the recipient. A recipient that provides housing to its nonhandicapped students shall provide comparable, convenient, and accessible housing to handicapped students...

  16. 20 CFR 654.404 - Housing site.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 20 Employees' Benefits 3 2013-04-01 2013-04-01 false Housing site. 654.404 Section 654.404... THE EMPLOYMENT SERVICE SYSTEM Housing for Agricultural Workers Housing Standards § 654.404 Housing site. (a) Housing sites shall be well drained and free from depressions in which water may...

  17. 38 CFR 18.445 - Housing.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 38 Pensions, Bonuses, and Veterans' Relief 2 2013-07-01 2013-07-01 false Housing. 18.445 Section....445 Housing. (a) Housing provided by a recipient. A recipient that provides housing to its nonhandicapped students shall provide comparable, convenient, and accessible housing to qualified...

  18. 45 CFR 605.45 - Housing.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 45 Public Welfare 3 2012-10-01 2012-10-01 false Housing. 605.45 Section 605.45 Public Welfare... § 605.45 Housing. (a) Housing provided by the recipient. A recipient that provides housing to its nonhandicapped students shall provide comparable, convenient, and accessible housing to handicapped students...

  19. 34 CFR 104.45 - Housing.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 34 Education 1 2013-07-01 2013-07-01 false Housing. 104.45 Section 104.45 Education Regulations of... Postsecondary Education § 104.45 Housing. (a) Housing provided by the recipient. A recipient that provides housing to its nonhandicapped students shall provide comparable, convenient, and accessible housing...

  20. 45 CFR 605.45 - Housing.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 45 Public Welfare 3 2014-10-01 2014-10-01 false Housing. 605.45 Section 605.45 Public Welfare... § 605.45 Housing. (a) Housing provided by the recipient. A recipient that provides housing to its nonhandicapped students shall provide comparable, convenient, and accessible housing to handicapped students...

  1. 34 CFR 104.45 - Housing.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 34 Education 1 2014-07-01 2014-07-01 false Housing. 104.45 Section 104.45 Education Regulations of... Postsecondary Education § 104.45 Housing. (a) Housing provided by the recipient. A recipient that provides housing to its nonhandicapped students shall provide comparable, convenient, and accessible housing...

  2. 20 CFR 654.404 - Housing site.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 20 Employees' Benefits 3 2011-04-01 2011-04-01 false Housing site. 654.404 Section 654.404... THE EMPLOYMENT SERVICE SYSTEM Housing for Agricultural Workers Housing Standards § 654.404 Housing site. (a) Housing sites shall be well drained and free from depressions in which water may...

  3. 24 CFR 3.405 - Housing.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 24 Housing and Urban Development 1 2012-04-01 2012-04-01 false Housing. 3.405 Section 3.405 Housing and Urban Development Office of the Secretary, Department of Housing and Urban Development... Discrimination on the Basis of Sex in Education Programs or Activities Prohibited § 3.405 Housing. (a)...

  4. 24 CFR 8.33 - Housing adjustments.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 24 Housing and Urban Development 1 2011-04-01 2011-04-01 false Housing adjustments. 8.33 Section 8.33 Housing and Urban Development Office of the Secretary, Department of Housing and Urban Development NONDISCRIMINATION BASED ON HANDICAP IN FEDERALLY ASSISTED PROGRAMS AND ACTIVITIES OF THE DEPARTMENT OF HOUSING...

  5. 24 CFR 8.33 - Housing adjustments.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 24 Housing and Urban Development 1 2014-04-01 2014-04-01 false Housing adjustments. 8.33 Section 8.33 Housing and Urban Development Office of the Secretary, Department of Housing and Urban Development NONDISCRIMINATION BASED ON HANDICAP IN FEDERALLY ASSISTED PROGRAMS AND ACTIVITIES OF THE DEPARTMENT OF HOUSING...

  6. 34 CFR 104.45 - Housing.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 34 Education 1 2012-07-01 2012-07-01 false Housing. 104.45 Section 104.45 Education Regulations of... Postsecondary Education § 104.45 Housing. (a) Housing provided by the recipient. A recipient that provides housing to its nonhandicapped students shall provide comparable, convenient, and accessible housing...

  7. 38 CFR 18.445 - Housing.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 38 Pensions, Bonuses, and Veterans' Relief 2 2012-07-01 2012-07-01 false Housing. 18.445 Section....445 Housing. (a) Housing provided by a recipient. A recipient that provides housing to its nonhandicapped students shall provide comparable, convenient, and accessible housing to qualified...

  8. 20 CFR 654.404 - Housing site.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 20 Employees' Benefits 3 2014-04-01 2014-04-01 false Housing site. 654.404 Section 654.404... THE EMPLOYMENT SERVICE SYSTEM Housing for Agricultural Workers Housing Standards § 654.404 Housing site. (a) Housing sites shall be well drained and free from depressions in which water may...

  9. 20 CFR 654.404 - Housing site.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 20 Employees' Benefits 3 2012-04-01 2012-04-01 false Housing site. 654.404 Section 654.404... THE EMPLOYMENT SERVICE SYSTEM Housing for Agricultural Workers Housing Standards § 654.404 Housing site. (a) Housing sites shall be well drained and free from depressions in which water may...

  10. Octachlorodibenzodioxin formation on Fe(III)-montmorillonite clay.

    PubMed

    Gu, Cheng; Li, Hui; Teppen, Brian J; Boyd, Stephen A

    2008-07-01

    Polychlorinated dibenzo-p-dioxins (PCDDs) are ubiquitous and highly toxic environmental contaminants found in surface and subsurface soils and in clay deposits. Interestingly, the congener profiles of such PCDDs are inexplicably dissimilar to those of known anthropogenic (e.g., pesticide manufacture, waste incineration) or natural (e.g., forest fire) sources. Characteristic features of soil or clay-associated PCDDs are the dominance of octachlorodibenzo-p-dioxin (OCDD) as the most abundant congener and very low levels of polychlorinated dibenzofurans (PCDFs). These propensities led to the hypothesis of in situ PCDD formation in soils and geologic clay deposits. In this study, we demonstrate the formation of OCDD on the naturally occurring and widely distributed clay mineral montmorillonite under environmentally relevant conditions. When pentachlorophenol (PCP)was mixed with Fe(III)-montmorillonite, significant amounts of OCDD were rapidly (minutes to days) formed (approximately 5 mg OCDD/kg clay) at ambient temperature in the presence of water. This reaction is initiated by single electron transfer from PCP to Fe(III)-montmorillonite thereby forming the PCP radical cation. Subsequent dimerization, dechlorination, and ring closure reactions result in formation of OCDD. This study provides the first direct evidence for clay-catalyzed formation of OCDD supporting the plausibility of its in situ formation in soils.

  11. Porous networks derived from synthetic polymer-clay complexes

    SciTech Connect

    Carrado, K.A.; Thiyagarajan, P.; Elder, D.L.

    1995-05-12

    Synthetic hectorites were hydrothermally crystallized with direct incorporation of a cationic polymer poly(dimethyl diallyl ammonium chloride) (PDDA), and two neutral cellulosic polymers hydroxypropyl methylcellulose (HPMC) and hydroxyethyl cellulose (HEC). Synthetic PDDA-hectorite displays the lowest d-spacing at 15.8 {Angstrom} along with less polymer incorporation (7.8 wt % organic) than the neutral polymers (18--22 wt % organic). Thermal analysis and small angle neutron scattering were used to further examine the polymer-clay systems. Clay platelets of the largest size and best stacking order occur when cationic PDDA polymer is used. PDDA also enhances these properties over the crystallites prepared for a control mineral, where no polymer is used. HEC acts to aggregate the silica, leaving less to react to form clay. The clay platelets which result from HEC are small, not stacked to a large degree, and oriented randomly. Neutral HPMC acts more like cationic PDDA in that larger clay platelets are allowed to form. The extended microstructure of the clay network remains undisturbed after polymer is removed by calcination. When no polymer is used, the synthetic hectorite has a N{sub 2} BET surface area of 200 M{sup 2}/gm, even after calcination. This increases by 20--50% for the synthetic polymer-hectorites after the polymer is removed by calcination.

  12. Fluoride content of clay minerals and argillaceous earth materials

    USGS Publications Warehouse

    Thomas, J.; Glass, H.D.; White, W.A.; Trandel, R.M.

    1977-01-01

    A reliable method, utilizing a fluoride ion-selective electrode, is described for the determination of fluoride in clays and shales. Interference by aluminum and iron is minimal. The reproducibility of the method is about ??5% at different levels of fluoride concentration. Data are presented for various clay minerals and for the <2-??m fractions of marine and nonmarine clays and shales. Fluoride values range from 44 ppm (0.0044%) for nontronite from Colfax, WA, to 51,800 ppm (5.18%) for hectorite from Hector, CA. In general, clays formed under hydrothermal conditions are relatively high in fluoride content, provided the hydrothermal waters are high in fluoride content. Besides hectorite, dickite from Ouray, CO, was found to contain more than 50 times as much fluoride (6700 ppm) as highly crystalline geode kaolinite (125 ppm). The clay stratum immediately overlying a fluorite mineralized zone in southern Illinois was found to have a higher fluoride content than the same stratum in a nonmineralized zone approximately 1 mile away. Nonmarine shales in contact with Australian coals were found to be lower in fluoride content than were marine shales in contact with Illinois coals. It is believed that, in certain instances, peak shifts on DTA curves of similar clay minerals are the result of significant differences in their fluoride content. ?? 1977.

  13. Characterization of clay scales forming in Philippine geothermal wells

    SciTech Connect

    Reyes, A.G. ); Cardile, C.M. )

    1989-01-01

    Smectite scales occur in 24 out of the 36 blocked wells located in Tongonan, Palinpinon and Bacon-Manito. These comprise 2-85% of the well scales and form at depths of 33-2620 m, where measured and fluid inclusion temperatures are 40-320{sup 0}C. Most, however, occur below the production casing show where temperatures are {ge}230{sup 0}C, often at depths coinciding with aquifers. The clay scales are compositionally and structurally different from the bentonite used in drilling, which is essentially sodium-rich montmorillonite. The clay deposits are expanding, generally disordered, and combine the characteristics of a montmorillonite, saponite and vermiculite in terms of reaction to cationic exchange treatments, structure and composition. Six types of clay scales are identified, but the predominant one, comprising 60-100% of the clay deposits in a well, is Mg- and Fe-rich and referred to as a vermiculitic species. The crystallinity, degree of disorder, textures, optical characteristics, structure and relative amounts of structural Al, Mg and Fe vary with time, temperature and fluid composition, but not with depth and measured pressure. Despite its variance from bentonite characteristics, one of the dominant suggested mechanisms of clay scale formation uses the drilling mud in the well as a substrate, from which the Mg- and Fe-rich clay evolves.

  14. Bacterial diversity in a deep-subsurface clay environment.

    PubMed Central

    Boivin-Jahns, V; Ruimy, R; Bianchi, A; Daumas, S; Christen, R

    1996-01-01

    The presence of bacteria in a deep clay sediment was analyzed in a 20-m-long core horizontally drilled from a mine gallery at a depth of 224 m in the Boom clay formation (Mol, Belgium). This clay deposit is the result of a marine sedimentary process that occurred 35 million years ago. Bacterial activities were estimated by measuring respiration on [14C]glucose. Using the same samples, universal primers for the genes coding for eubacterial 16S rRNA were used to amplify extracted DNA. PCR products were then cloned, sequenced, and analyzed by molecular phylogeny. Our data showed a decrease in bacterial densities as a function of distance from the gallery, with few bacteria detectable by culture at more than 80 cm from the gallery wall. PCR experiments showed the presence of bacteria in all samples, and phylogenetic analyses were then used to tentatively identify these organisms. Because of low bacterial densities in deep clay samples, direct counts and enumeration of viable bacteria on diverse culture media remained negative. All experiments, both cultures and PCR, demonstrated the difficulty of analyzing samples that contain only a few poorly active bacteria as it is difficult to avoid a small contamination by active bacteria during sampling. Since the porosity of the Boom clay formation is less than the expected size of bacteria, it is possible that some of the bacteria present in this 35-million-year-old deep clay deposit derive from cells initially trapped during the sedimentation process. PMID:8795233

  15. The composition and origin of Ghana medicine clays

    PubMed Central

    van Dongen, Bart E.; Fraser, Sharon E.; Insoll, Timothy

    2011-01-01

    The mineral, organic and elemental composition of medicine clays from three shrines in the Tong Hills in northern Ghana (Gbankil, Kusanaab, and Yaane) are assessed to ascertain what additives they might contain and the implications for their recognition, for example in archaeological contexts. These are clays that are widely used for healing purposes being perceived efficacious in curing multiple ailments and which are given a divine provenance, but their collection is ascribed human agency. The Yaane clay is also supplied as part of the process of obtaining the right to operate the shrine elsewhere making it widely dispersed. Organic geochemical analyses revealed a predominance of plant-derived material with a substantial contribution of microbial origin. Based on these (supported by elemental and mineral analyses), no unnatural organic material could be detected, making an exogenous contribution to these clays unlikely. The implications are that these are wholly natural medicinal substances with no anthropogenic input into their preparation, as the traditions suggest. The very similar mineralogy of all the clays, including a non-medicine clay sampled, suggests that, unless the geology radically differed, differentiating between them analytically in an archaeological contexts would be doubtful. PMID:21810043

  16. Controlling harmful algae blooms using aluminum-modified clay.

    PubMed

    Liu, Yang; Cao, Xihua; Yu, Zhiming; Song, Xiuxian; Qiu, Lixia

    2016-02-15

    The performances of aluminum chloride modified clay (AC-MC), aluminum sulfate modified clay (AS-MC) and polyaluminum chloride modified clay (PAC-MC) in the removal of Aureococcus anophagefferens were compared, and the potential mechanisms were analyzed according to the dispersion medium, suspension pH and clay surface charges. The results showed that AC-MC and AS-MC had better efficiencies in removing A.anophagefferens than PAC-MC. The removal mechanisms of the three modified clays varied. At optimal coagulation conditions, the hydrolysates of AC and AS were mainly monomers, and they transformed into Al(OH)3(am) upon their addition to algae culture, with the primary mechanism being sweep flocculation. The PAC mainly hydrolyzed to the polyaluminum compounds, which remained stable when added to the algae culture, and the flocculation mainly occurred through polyaluminum compounds. The suspension pH significantly influenced the aluminum hydrolysate and affected the flocculation between the modified clay and algae cells.

  17. Degradation of Nylon-6/Clay Nanocomposites in NO(x)

    NASA Astrophysics Data System (ADS)

    Shelley, J. S.; Devries, K. L.

    2000-04-01

    Nylon-6 is an important engineering polymer that, in its fully spherulitic (bulk) form, has many applications in gears, rollers, and other long life cycle components. In 1993, Toyota commercialized a nylon-6/clay nanocomposite out of which it produced the timing belt cover for the 1993 Camry. Although these hybrid nanocomposites show significant improvements in their mechanical response characteristics, including yield strength and heat distortion temperature, little is known about the degradation of these properties due to environmental pollutants like NOx. Nylon-6 fibers are severely degraded by interaction with NOx and other pollutants, showing a strong synergism between applied load and environmental degradation. While the nanocomposites show a significant reduction in permeability of gases and water due to the incorporation of lamellar clay, their susceptibility to non-diffusional mechano-chemical degradation is unknown. The fracture toughness of these nylon-6/day nanocomposites increases, not as a function of clay content, but as a function of the volume of nylon-6 polymer chains influenced by the clay lamellar surfaces. Both the clay and the constrained volume offer the nanocomposites some protection from the deleterious effects of NOx. The time-to-failure at a given stress intensity factor as a function of clay content and constrained volume will be discussed along with fracture toughness of the materials.

  18. Cyclic voltammetry of aquocobalamin on clay-modified electrodes

    SciTech Connect

    Borek, V.; Morra, M.J.

    1998-07-15

    Halogenated synthetic compounds are widespread contaminants of the environment. Although corrinoids reductively dehalogenate synthetic contaminants in solution, the redox behavior of sorbed tetrapyrroles has received limited attention. Colloidal clay suspensions were prepared as Ca{sup 2+} forms of hectorite (SHCa-1), montmorillonite (SWy-1, Syn-1, and SAz-1), and vermiculite (VTx-1) and spin coated on platinum electrodes. Cyclic voltammetry was performed with the clay-modified electrodes immersed in buffered solutions containing 1.0 mM aquocobalamin. Aquocobalamin in the presence of vermiculite-coated electrodes displayed the same cathodic and anodic peak potentials as unmodified electrodes immersed in aquocobalamin solutions. All other clay-modified electrodes shifted cathodic peaks to more negative values, while anodic peak shifts varied with the clay. Hectorite caused the largest shift in formal redox potential as compared to aquocobalamin in solution. The redox behavior of aquocobalamin as modified by sorption to clay minerals potentially affects dehalogenation rates of synthetic organic compounds in the environment. Clays lowering the formal redox potential of the tetrapyrrole create a potentially more efficient catalyst for pollutant degradation. However, thermodynamic data as obtained using cyclic voltammetry cannot be used to make definitive predictions about the kinetics of contaminant dehalogenation. Reductive dehalogenation will be a function of altered electrochemical properties of the tetrapyrrole as well as rates of contaminant diffusion to the site of tetrapyrrole sorption.

  19. Biodegradation of crude oil saturated fraction supported on clays.

    PubMed

    Ugochukwu, Uzochukwu C; Jones, Martin D; Head, Ian M; Manning, David A C; Fialips, Claire I

    2014-02-01

    The role of clay minerals in crude oil saturated hydrocarbon removal during biodegradation was investigated in aqueous clay/saturated hydrocarbon microcosm experiments with a hydrocarbon degrading microorganism community. The clay minerals used for this study were montmorillonite, palygorskite, saponite and kaolinite. The clay mineral samples were treated with hydrochloric acid and didecyldimethylammonium bromide to produce acid activated- and organoclays respectively which were used in this study. The production of organoclay was restricted to only montmorillonite and saponite because of their relative high CEC. The study indicated that acid activated clays, organoclays and unmodified kaolinite, were inhibitory to biodegradation of the hydrocarbon saturates. Unmodified saponite was neutral to biodegradation of the hydrocarbon saturates. However, unmodified palygorskite and montmorillonite were stimulatory to biodegradation of the hydrocarbon saturated fraction and appears to do so as a result of the clays' ability to provide high surface area for the accumulation of microbes and nutrients such that the nutrients were within the 'vicinity' of the microbes. Adsorption of the saturated hydrocarbons was not significant during biodegradation.

  20. [Extinguishment of harmful algae by organo-clay].

    PubMed

    Cao, Xihua; Yu, Zhiming

    2003-07-01

    Periodic and widespread algal blooms have caused a variety of problems for aquatic life and human activity throughout the world. Currently, the only remedial practice employed for removing algal blooms is to spread clay on the surface of the water. But, the algal removal efficiency by the crude minerals are not really ideal, and how to improve the capability of clays to remove algae is now the technological focus, which also is fatal to the practical value of clays. In this study, hexadecyltrimethyleamine bromide (HDTMAB), one kind of cationic organo-surfactants, was chosen to improve kaolin by surface sorption and cationic exchange, and was tested to remove Prorocentrum donghaiense, a red tide organism in Donghai Sea. The results indicated that organo-clay had an excellent ability to extinguish red tide organisms, even under the application of 0.01 g.L-1, and could subside more than 95% red tide organisms in 24 h. The efficient algae removal by organo-clay might be from the reversal of the surface electric charge on clay particles, the "net capture" by the long lipoid chains of HDTMAB, and the local high density of HDTMAB on particles surface, which could effectively kill algal cells.