Critically safe volume vacuum pickup for use in wet or dry cleanup of radioactive enclosures

DOEpatents

Zeren, J.D.

1993-12-28

A physical compact vacuum pickup device of critically safe volume and geometric shape is provided for use in radioactive enclosures, such as a small glove box, to facilitate manual cleanup of either wet or dry radioactive material. The device is constructed and arranged so as to remain safe when filled to capacity with plutonium-239 oxide. Two fine mesh filter bags are supported on the exterior of a rigid fine mesh stainless steel cup. This assembly is sealed within, and spaced from, the interior walls of a stainless steel canister. An air inlet communicates with the interior of the canister. A modified conventional vacuum head is physically connected to, and associated with, the interior of the mesh cup. The volume of the canister, as defined by the space between the mesh cup and the interior walls of the canister, forms a critically safe volume and geometric shape for dry radioactive particles that are gathered within the canister. A critically safe liquid volume is maintained by operation of a suction terminating float valve, and/or by operation of redundant vacuum check/liquid drain valves and placement of the air inlet. 5 figures.

Critically safe volume vacuum pickup for use in wet or dry cleanup of radioactive enclosures

DOEpatents

Zeren, Joseph D.

1993-12-28

A physical compact vacuum pickup device of critically safe volume and geometric shape is provided for use in radioactive enclosures, such as a small glove box, to facilitate manual cleanup of either wet or dry radioactive material. The device is constructed and arranged so as to remain safe when filled to capacity with plutonium-239 oxide. Two fine mesh filter bags are supported on the exterior of a rigid fine mesh stainless steel cup. This assembly is sealed within, and spaced from, the interior walls of a stainless steel canister. An air inlet communicates with the interior of the canister. A modified conventional vacuum head is physically connected to, and associated with, the interior of the mesh cup. The volume of the canister, as defined by the space between the mesh cup and the interior walls of the canister, forms a critically safe volume and geometric shape for dry radioactive particles that are gathered within the canister. A critically safe liquid volume is maintained by operation of a suction terminating float valve, and/or by operation of redundant vacuum check/liquid drain valves and placement of the air inlet.

Annual review of energy. Volume 5

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hollander, J.M.; Simmons, M.K.; Wood, D.O.

1980-01-01

The many continuing efforts around the world to deal with the issues of energy supply, demand, and environmental impact are reviewed. This volume carries reviews of recent developments in solar-photovoltaic technology and inertial-confinement fusion as long-term options. Progress in some important nearer-term energy-supply areas is reviewed by contributions in the fields of battery energy storage and coal clean-up technology. In the area of energy sociology, the interesting and poorly understood topic of public opinion about energy is reviewed. The subject of energy economics is represented by a review of the role of governmental incentives in energy production. Topics related tomore » the environmental aspects of energy technologies include coastal flooding from atmospheric carbon dioxide warming, risks of liquefied natural gas and petroleum gas, and the environmental impacts of renewable energy sources. Continuing the practice of earlier volumes to review the energy perspective of a particular region or country, Volume 5 carries a review of emerging energy technologies in island environments, typified by the case of Hawaii. Finally, the energy problem from the perspective of developing countries is reviewed by two papers, the first on renewable energy resources for developing countries, and the second on the problem of energy for the people of Asia and the Pacific. A separate abstract was prepared for each of the 12 reviews for the Energy Data Base (EDB); all will appear in Energy Abstracts for Policy Analysis (EAPA) and three in Energy Research Abstracts (ERA).« less

Environmental Learning Experiences for Grades Five and Six.

ERIC Educational Resources Information Center

Willoughby-Eastlake School District, Willoughby, OH.

The third of this series of three volumes on interdisciplinary environmental learning experiences for elementary students is aimed at grades 5 and 6 and deals with the comunity environment of the student. Titles of the eight units included in this volume are: Probleem Solving; How to Plan a Clean-up Campaign in the Local Community; Scars upon the…

Superfund: conscripting industry support for environmental cleanup

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gulick, T.E.

The Superfund is notable in its attempt to charge the costs of environmental damage to those commercial interests that contributed to the damage. The approach should appeal to the Reagan administration's fiscal austerity program. It realizes the attendant costs to the benefits of our technologically productive society and recognizes that those costs must be paid either as environmental precautions or as cleanup costs, property damage, and disease. This article examines the major problems addressed by Superfund, describing the major provisions of the Act, discussing previously available remedies, and considering some of the problems that may arise with implementation. 126 references.

All hazardous waste politics is local: Grass-roots advocacy and public participation in siting and cleanup decisions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lowry, R.C.

1998-12-31

The combined effects of federalism and interest group pluralism pose particularly difficult problems for hazardous waste siting and cleanup decisions. Most national environmental groups have only limited involvement in local hazardous waste politics, while local grass-roots advocates have very different interests and sometimes are pitted against one another. Both the Environmental protection Agency and the Department of energy recently have begun to use site-specific citizen advisory boards at cleanup sites. This approach appears to improve communications at some sites, but does not address the issues of ``not in my back yard`` politics and alleged inequitable exposure to hazardous wastes.

Cleanup/stimulation of a horizontal wellbore using propellants

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rougeot, J.E.; Lauterbach, K.A.

1993-01-01

This report documents the stimulation/cleanup of a horizontal well bore (Wilson 25) using propellants. The Wilson 25 is a Bartlesville Sand well located in the Flatrock Field, Osage County, Oklahoma. The Wilson 25 was drilled to determine if horizontal drilling could be used as a means to economically recover primary oil that had been left in place in a mostly abandoned oil field because of the adverse effects of water coning. Pump testing of the Wilson 25 horizontal well bore before cleanup or stimulation produced 6 barrels of oil and .84 barrels of water per day. The high percentage ofmore » daily oil production to total daily fluid production indicated that the horizontal well bore had accessed potentially economical oil reserves if the fluid production rate could be increased by performing a cleanup/stimulation treatment. Propellants were selected as an inexpensive means to stimulate and cleanup the near well bore area in a uniform manner. The ignition of a propellant creates a large volume of gas which penetrates the formation, creating numerous short cracks through which hydrocarbons can travel into the well bore. More conventional stimulation/cleanup techniques were either significantly more expensive, less likely to treat uniformly, or could not be confined to the near well bore area. Three different propellant torpedo designs were tested with a total of 304' of horizontal well bore being shot and producible. The initial test shot caused 400' of the horizontal well bore to become plugged off, and subsequently it could not be production tested. The second and third test shots were production tested, with the oil production being increased 458% and 349%, respectively, on a per foot basis. The Wilson 25 results indicate that a propellant shot treatment is an economically viable means to cleanup/stimulate a horizontal well bore.« less

Preconcentration for Improved Long-term Monitoring of Contaminants in Groundwater

DTIC Science & Technology

2014-04-10

Johnson of the US Army Corps of Engineers, Tulsa District (recently retired) provided sites in northeastern Oklahoma for field trials as well as...neighboring wildlife is also a concern. Long-term monitoring of sites undergoing remediation as well as sites that may eventually require cleanup is...Activated charcoal and peroxide cleanup steps offer potential avenues for addressing this problem. The materials may be of value in isotopic analysis of

Strategies for reducing ocean plastic debris should be diverse and guided by science

NASA Astrophysics Data System (ADS)

Rochman, Chelsea M.

2016-04-01

Studies suggest that trillions of microplastic particles are floating on the surface of the global oceans and that the total amount of plastic waste entering the ocean will increase by an order of magnitude by 2025. As such, this ever-increasing problem demands immediate mitigation and reduction. Diverse solutions have been proposed, ranging from source reduction to ocean-based cleanup. These solutions are most effective when guided by scientific evidence. A study published in Environmental Research Letters (Sherman and van Sebille 2016 Environ. Res. Lett. 11 014006) took a closer look at the potential effectiveness of ocean-based cleanup. They conclude that it will be most cost-effective and ecologically beneficial if clean-up efforts focus on the flux of microplastics from the coasts rather than in the center of the oceans where plastic accumulates in so called ‘garbage patches’. If followed, this example may become one of a series of examples where science has informed a solution to the complex problem of plastic pollution.

Report to Congress on the U.S. Department of Energy`s Environmental Management Science Program: Research funded and its linkages to environmental cleanup problems, and Environmental Management Science Program research award abstracts. Volume 2 of 3 -- Appendix B

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

The Department of Energy`s Environmental Management Science Program (EMSP) serves as a catalyst for the application of scientific discoveries to the development and deployment of technologies that will lead to reduction of the costs and risks associated with cleaning up the nation`s nuclear complex. Appendix B provides details about each of the 202 research awards funded by the EMSP. This information may prove useful to researchers who are attempting to address the Department`s environmental management challenges in their work, program managers who are planning, integrating, and prioritizing Environmental Management projects, and stakeholders and regulators who are interested in the Department`smore » environmental challenges. The research award information is organized by the state and institution in which the lead principal investigator is located. In many cases, the lead principal investigator is one of several investigators at a number of different institutions. In these cases, the lead investigator (major collaborator) at each of the additional institutions is listed. Each research award abstract is followed by a list of high cost projects that can potentially be impacted by the research results. High cost projects are Environmental Management projects that have total costs greater than $50 million from the year 2007 and beyond, based on the March 1998 Accelerating Cleanup: Paths to Closure Draft data, and have costs or quantities of material associated with an Environmental Management problem area. High cost projects which must remain active in the year 2007 and beyond to manage high risk are also identified. Descriptions of these potentially related high cost Environmental Management projects can be found in Appendix C. Additional projects in the same problem area as a research award can be located using the Index of High Cost Environmental Management Projects by Problem Area, at the end of Appendices B and C.« less

OIL SPILL RESPONSE SCENARIOS FOR REMOTE ARCTIC ENVIRONMENTS

EPA Science Inventory

Special problems occur during oil spill cleanup in remote inland areas in cold climates. In Alaska these problems result from the harsh climate, the unusual terrain features, and the special problems of spills along swift rivers. The analysis begins with a description of the envi...

CONTAMINANTS AND REMEDIAL OPTIONS AT PESTICIDE SITES

EPA Science Inventory

Many types of soils, sediments, and sludges are contaminated with a wide variety of pesticides. ite-specific characteristics such as volume to be treated, extent of contamination, and applicable cleanup goals differ greatly, and contaminant toxicity, migration pathways, persisten...

MANAGING ELECTRONIC DATA TRANSFER IN ENVIRONMENTAL CLEANUPS

EPA Science Inventory

The use of computers and electronic information poses a complex problem for potential litigation in space law. The problem currently manifests itself in at least two ways. First, the Environmental Protection Agency (EPA) enforcement of Comprehensive Environmental Response, Compen...

The Future Problem Solving Program.

ERIC Educational Resources Information Center

Crabbe, Anne B.

1989-01-01

Describes the Future Problem Solving Program, in which students from the U.S. and around the world are tackling some complex challenges facing society, ranging from acid rain to terrorism. The program uses a creative problem solving process developed for business and industry. A sixth-grade toxic waste cleanup project illustrates the process.…

Perioperative hair removal: A review of best practice and a practice improvement opportunity.

PubMed

Spencer, Maureen; Barnden, Marsha; Johnson, Helen Boehm; Fauerbach, Loretta Litz; Graham, Denise; Edmiston, Charles E

2018-06-01

The current practice of perioperative hair removal reflects research-driven changes designed to minimize the risk of surgical wound infection. An aspect of the practice which has received less scrutiny is the clean-up of the clipped hair. This process is critical. The loose fibers represent a potential infection risk because of the micro-organisms they can carry, but their clean-up can pose a logistical problem because of the time required to remove them. Research has demonstrated that the most commonly employed means of clean-up, the use of adhesive tape or sticky mitts, can be both ineffective and time-consuming in addition to posing an infection risk from cross-contamination. Recently published research evaluating surgical clippers fitted with a vacuum-assisted hair collection device highlights the potential for significant practice improvement in the perioperative hair removal clean-up process. These improvements include not only further mitigation of potential infection risk but also substantial OR time and cost savings.

Cleanup/stimulation of a horizontal wellbore using propellants. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rougeot, J.E.; Lauterbach, K.A.

1993-01-01

This report documents the stimulation/cleanup of a horizontal well bore (Wilson 25) using propellants. The Wilson 25 is a Bartlesville Sand well located in the Flatrock Field, Osage County, Oklahoma. The Wilson 25 was drilled to determine if horizontal drilling could be used as a means to economically recover primary oil that had been left in place in a mostly abandoned oil field because of the adverse effects of water coning. Pump testing of the Wilson 25 horizontal well bore before cleanup or stimulation produced 6 barrels of oil and .84 barrels of water per day. The high percentage ofmore » daily oil production to total daily fluid production indicated that the horizontal well bore had accessed potentially economical oil reserves if the fluid production rate could be increased by performing a cleanup/stimulation treatment. Propellants were selected as an inexpensive means to stimulate and cleanup the near well bore area in a uniform manner. The ignition of a propellant creates a large volume of gas which penetrates the formation, creating numerous short cracks through which hydrocarbons can travel into the well bore. More conventional stimulation/cleanup techniques were either significantly more expensive, less likely to treat uniformly, or could not be confined to the near well bore area. Three different propellant torpedo designs were tested with a total of 304` of horizontal well bore being shot and producible. The initial test shot caused 400` of the horizontal well bore to become plugged off, and subsequently it could not be production tested. The second and third test shots were production tested, with the oil production being increased 458% and 349%, respectively, on a per foot basis. The Wilson 25 results indicate that a propellant shot treatment is an economically viable means to cleanup/stimulate a horizontal well bore.« less

SITE TECHNOLOGY PROFILES, TENTH EDITION, VOLUME I - DEMONSTRATION PROGRAM

EPA Science Inventory

The Superfund Innovative Technology Evaluation (SITE) Program, now in its thirteenth year, is an integral part of EPA's research into alternative cleanup methods for hazardous waste sites around the nation. The SITE Program was created to encourage the development and routine us...

Crew appliance concepts. Volume 5, appendix C: Modular space station appliances supporting engineering data

NASA Technical Reports Server (NTRS)

Proctor, B. W.; Reysa, R. P.; Russell, D. J.

1975-01-01

Housekeeping, off-duty, and medical data concerning the appliances considered for the space station are presented. Appliance functions analyzed include: cleanup, collection, processing and storage of refuse; crew entertainment and physical exercise, and the autoclaves and ergometers.

SITE TECHNOLOGY PROFILES, TENTH EDITION, VOLUME 3 - MEASUREMENT AND MONITORING PROGRAM

EPA Science Inventory

The Superfund Innovative Technology Evaluation (SITE) Program, now in its thirteenth year, is an integral part of EPA's research into alternative cleanup methods for hazardous waste sites around the nation. The SITE Program was created to encourage the development and routine us...

SITE TECHNOLOGY PROFILES, TENTH EDITION, VOLUME 2 - EMERGING TECHNOLOGY PROGRAM

EPA Science Inventory

The Superfund Innovative Technology Evaluation (SITE) Program, now in its thirteenth year, is an integral part of EPA's research into alternative cleanup methods for hazardous waste sites around the nation. The SITE Program was created to encourage the development and routine us...

SITE TECHNOLOGY PROFILES - 11TH EDITION - DEMONSTRATION PROGRAM, VOLUME 1

EPA Science Inventory

The Superfund Innovative Technology Evaluation (SITE) Program, now in its eleventh year is an integral part of EPA's research into alternative cleanup methods for hazardous waste sites around the nation. The SITE Program was created to encourage the development and routine use o...

SITE TECHNOLOGY PROFILES - 11TH EDITION, EMERGING TECHNOLOGY PROGRAM, VOLUME 2

EPA Science Inventory

The Superfund Innovative Technology Evaluation (SITE) Program, now in its eleventh year is an integral part of EPA's research into alternative cleanup methods for hazardous waste sites around the nation. The SITE Program was created to encourage the development and routine use o...

SITE TECHNOLOGY PROFILES - 11TH EDITION, MEASUREMENT AND MONITORING PROGRAM, VOLUME 3

EPA Science Inventory

The Superfund Innovative Technology Evaluation (SITE) Program, now in its eleventh year is an integral part of EPA's research into alternative cleanup methods for hazardous waste sites around the nation. The SITE Program was created to encourage the development and routine use o...

Nonaqueous Phase Liquid Dissolution in Porous Media: Multi-Scale Effects of Multi-Component Dissolution Kinetics on Cleanup Time

DOE Office of Scientific and Technical Information (OSTI.GOV)

McNab, W; Ezzedine, S; Detwiler, R

2007-02-26

Industrial organic solvents such as trichloroethylene (TCE) and tetrachloroethylene (PCE) constitute a principal class of groundwater contaminants. Cleanup of groundwater plume source areas associated with these compounds is problematic, in part, because the compounds often exist in the subsurface as dense nonaqueous phase liquids (DNAPLs). Ganglia (or 'blobs') of DNAPL serve as persistent sources of contaminants that are difficult to locate and remediate (e.g. Fenwick and Blunt, 1998). Current understanding of the physical and chemical processes associated with dissolution of DNAPLs in the subsurface is incomplete and yet is critical for evaluating long-term behavior of contaminant migration, groundwater cleanup, andmore » the efficacy of source area cleanup technologies. As such, a goal of this project has been to contribute to this critical understanding by investigating the multi-phase, multi-component physics of DNAPL dissolution using state-of-the-art experimental and computational techniques. Through this research, we have explored efficient and accurate conceptual and numerical models for source area contaminant transport that can be used to better inform the modeling of source area contaminants, including those at the LLNL Superfund sites, to re-evaluate existing remediation technologies, and to inspire or develop new remediation strategies. The problem of DNAPL dissolution in natural porous media must be viewed in the context of several scales (Khachikian and Harmon, 2000), including the microscopic level at which capillary forces, viscous forces, and gravity/buoyancy forces are manifested at the scale of individual pores (Wilson and Conrad, 1984; Chatzis et al., 1988), the mesoscale where dissolution rates are strongly influenced by the local hydrodynamics, and the field-scale. Historically, the physico-chemical processes associated with DNAPL dissolution have been addressed through the use of lumped mass transfer coefficients which attempt to quantify the dissolution rate in response to local dissolved-phase concentrations distributed across the source area using a volume-averaging approach (Figure 1). The fundamental problem with the lumped mass transfer parameter is that its value is typically derived empirically through column-scale experiments that combine the effects of pore-scale flow, diffusion, and pore-scale geometry in a manner that does not provide a robust theoretical basis for upscaling. In our view, upscaling processes from the pore-scale to the field-scale requires new computational approaches (Held and Celia, 2001) that are directly linked to experimental studies of dissolution at the pore scale. As such, our investigation has been multi-pronged, combining theory, experiments, numerical modeling, new data analysis approaches, and a synthesis of previous studies (e.g. Glass et al, 2001; Keller et al., 2002) aimed at quantifying how the mechanisms controlling dissolution at the pore-scale control the long-term dissolution of source areas at larger scales.« less

Superfund: right-to-know and hazardous waste site cleanup. Hearing before the Subcommittee on Commerce, Transportation, and Tourism of the Committee on Energy and Commerce, House of Representatives, Ninety-Ninth Congress, First Session, December 20, 1985

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1985-01-01

Representatives of local and state offices and the congressional representative of St. Paul, Minnesota testified at a field hearing on the Superfund program. The focus of the hearing was on community right-to-know aspects and the cleanup of hazardous materials that were abandoned on federal sites. At issue was environmental problems at the 38 priority sites listed for Minnesota and the lack of information on health effects after over 20 years of environmental study of toxic substances. The proposed legislation would subject federal facilities and sites to the same standards, cleanup schedules, and oversite as private sites. A new enforcement billmore » would encourage citizen suits to force cleanup. Military arsenals that contribute to water and soil pollution were of particular concern. Witnesses discussed the need for a national right-to-know law so that businesses would not be tempted to relocate to avoid Minnesota's environmental policy. The hearing record covers the testimony of seven witnesses.« less

Automated multi-plug filtration cleanup for liquid chromatographic-tandem mass spectrometric pesticide multi-residue analysis in representative crop commodities.

PubMed

Qin, Yuhong; Zhang, Jingru; Zhang, Yuan; Li, Fangbing; Han, Yongtao; Zou, Nan; Xu, Haowei; Qian, Meiyuan; Pan, Canping

2016-09-02

An automated multi-plug filtration cleanup (m-PFC) method on modified QuEChERS (quick, easy, cheap, effective, rugged, and safe) extracts was developed. The automatic device was aimed to reduce labor-consuming manual operation workload in the cleanup steps. It could control the volume and the speed of pulling and pushing cycles accurately. In this work, m-PFC was based on multi-walled carbon nanotubes (MWCNTs) mixed with other sorbents and anhydrous magnesium sulfate (MgSO4) in a packed tip for analysis of pesticide multi-residues in crop commodities followed by liquid chromatography with tandem mass spectrometric (LC-MS/MS) detection. It was validated by analyzing 25 pesticides in six representative matrices spiked at two concentration levels of 10 and 100μg/kg. Salts, sorbents, m-PFC procedure, automated pulling and pushing volume, automated pulling speed, and pushing speed for each matrix were optimized. After optimization, two general automated m-PFC methods were introduced to relatively simple (apple, citrus fruit, peanut) and relatively complex (spinach, leek, green tea) matrices. Spike recoveries were within 83 and 108% and 1-14% RSD for most analytes in the tested matrices. Matrix-matched calibrations were performed with the coefficients of determination >0.997 between concentration levels of 10 and 1000μg/kg. The developed method was successfully applied to the determination of pesticide residues in market samples. Copyright © 2016 Elsevier B.V. All rights reserved.

Sludge reduction and water quality improvement in anaerobic lagoons through influent pre-treatment

USDA-ARS?s Scientific Manuscript database

Confined swine production generates large volumes of wastewater typically stored and treated in anaerobic lagoons. These lagoons may require cleanup and closure measures in the future. In practice, liquid and sludge need to be removed by pumping, usually at great expense of energy, and land applied ...

ADDENDUM TO SUPERFUND INNOVATIVE TECHNOLOGY EVALUATION PROGRAM TECHNOLOGY PROFILES, TENTH EDITION, VOLUME 1 - DEMONSTRATION PROGRAM

EPA Science Inventory

The Superfund Innovative Technology Evaluation (SITE) Program, now in its thirteenth year, is an integral part of EPA's research into alternative cleanup methods for hazardous waste sites around the nation. The SITE Program was created to encourage the development and routine us...

Automated Mini-Column Solid-Phase Extraction Cleanup for High-Throughput Analysis of Chemical Contaminants in Foods by Low-Pressure Gas Chromatography-Tandem Mass Spectrometry.

PubMed

Lehotay, Steven J; Han, Lijun; Sapozhnikova, Yelena

2016-01-01

This study demonstrated the application of an automated high-throughput mini-cartridge solid-phase extraction (mini-SPE) cleanup for the rapid low-pressure gas chromatography-tandem mass spectrometry (LPGC-MS/MS) analysis of pesticides and environmental contaminants in QuEChERS extracts of foods. Cleanup efficiencies and breakthrough volumes using different mini-SPE sorbents were compared using avocado, salmon, pork loin, and kale as representative matrices. Optimum extract load volume was 300 µL for the 45 mg mini-cartridges containing 20/12/12/1 (w/w/w/w) anh. MgSO 4 /PSA (primary secondary amine)/C 18 /CarbonX sorbents used in the final method. In method validation to demonstrate high-throughput capabilities and performance results, 230 spiked extracts of 10 different foods (apple, kiwi, carrot, kale, orange, black olive, wheat grain, dried basil, pork, and salmon) underwent automated mini-SPE cleanup and analysis over the course of 5 days. In all, 325 analyses for 54 pesticides and 43 environmental contaminants (3 analyzed together) were conducted using the 10 min LPGC-MS/MS method without changing the liner or retuning the instrument. Merely, 1 mg equivalent sample injected achieved <5 ng g -1 limits of quantification. With the use of internal standards, method validation results showed that 91 of the 94 analytes including pairs achieved satisfactory results (70-120 % recovery and RSD ≤ 25 %) in the 10 tested food matrices ( n  = 160). Matrix effects were typically less than ±20 %, mainly due to the use of analyte protectants, and minimal human review of software data processing was needed due to summation function integration of analyte peaks. This study demonstrated that the automated mini-SPE + LPGC-MS/MS method yielded accurate results in rugged, high-throughput operations with minimal labor and data review.

Summer Research Program (1992). Summer Faculty Research Program (SFRP) Reports. Volume 6. Arnold Engineering Development Center, Civil Engineering Laboratory, Frank J. Seiler Research Laboratory, Wilford Hall Medical Center

DTIC Science & Technology

1992-12-01

concentrations of DNT, its degradation intermediate 4-methyl 5- nitrocatechol, and TNT were determined by high pressure liquid chromatography (HPLC...to more cost-effective site characterization and cleanup. Many such studies have been performed using chromatography and/or liquid scintillation...volume set that summarizes the research accomplishments of faculty, graduate student, and high school participants in the 1992 AFOSR Summer Research

Space shuttle/food system study. Volume 2, appendix E: Alternate flight systems analysis

NASA Technical Reports Server (NTRS)

1974-01-01

The functional requirements of stowage, preparation, serving, consumption, and cleanup were applied to each of the five food mixes selected for study in terms of the overall design of the space shuttle food system. The analysis led to a definition of performance requirements for each food mix, along with a definition of equipment to meet those requirements. Weight and volume data for all five systems, in terms of food and packaging, support equipment, and galley installation penalties, are presented.

A Rinsing Effluent Evaporator for Dismantling Operations - 13271

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rives, Rachel; Asou-Pothet, Marielle; Chambon, Frederic

2013-07-01

Between 1958 and 1997, the UP1 plant at Marcoule - located in the south of France - reprocessed and recycled nearly 20,000 MT of used fuel from special defense applications reactors, as well as fuel from the first generation of electricity generating reactors in France (natural uranium fuel, CO{sub 2}-cooled, graphite-moderated). Decommissioning and Dismantling of the UP1 plant and its associated units started in 1998. Since 2005, the UP1 facility has been operated by AREVA as the Marcoule Management and Operation contractor for French Atomic Energy Commission (CEA). An important part of this decommissioning program deals with the vitrification facilitymore » of Marcoule. This facility includes 20 tanks devoted to interim storage of highly active solutions, prior to vitrification. In 2006, a rinsing program was defined as part of the tank cleanup strategy. The main objective of the rinsing phases was to decrease activity in order to limit the volume of 'long-life active' waste produced during the decommissioning operations, so the tanks can be dismantled without the need of remote operations. To enable this rinsing program, and anticipating large volumes of generated effluent, the construction of an evaporation unit proved to be essential. The main objective of this unit was to concentrate the effluent produced during tank rinsing operations by a factor of approximately 10, prior to it being treated by vitrification. The evaporator design phase was launched in September 2006. The main challenge for the Project team was the installation of this new unit within a nuclear facility still in operation and in existing compartments not initially designed for this purpose. Cold operating tests were completed in 2008, and in May 2009, the final connections to the process were activated to start the hot test phase. During the first hot test operations performed on the first batches of clean-up effluent, the evaporator had a major operating problem. Extremely large quantities of foam were produced, affecting the evaporator operation, and creating the risk of a reduction in its capacity and throughput performance. A task force of AREVA process, operations, and safety experts from Marcoule and the La Hague reprocessing complex was assembled. New operating parameters were defined and tested to improve the process. Since then, the evaporator has performed very satisfactorily. The foam buildup phenomenon has been brought under complete control. All the different types of effluents produced during cleanup operations have been concentrated, and the results obtained in terms of quality and throughput, have ensured a consistent supply to the vitrification unit. The evaporator was operated until the end of April 2012, and enabled the production of 500 cubic meters of very high activity effluent, concentrating the fission products rinsed from the storage tanks. The evaporator will now be deactivated and decommissioned, with the first rinsing and cleanup operations scheduled to begin in 2014. (authors)« less

Research on robotics by principal investigators of the Robotics Technology Development Program

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harrigan, R.W.

The U.S. Department of Energy`s Office of Technology Development has been developing robotics and automation technologies for the clean-up and handling of hazardous and radioactive waste through one of its major elements, Cross Cutting and Advanced Technology development. CC&AT university research and development programs recognize the strong technology, base resident in the university community and sponsor a focused technology research and development program which stresses close interaction between the university sector and the DOE community. This report contains a compilation of research articles by each of 14 principle investigators supported by CC&AT to develop robotics and automation technologies for themore » clean-up and handling of hazardous and radioactive waste. This research has led to innovative solutions for waste clean-up problems, and it has moved technology out of university laboratories into functioning systems which has allowed early evaluation by site technologists.« less

Finland's Cleanup Campaign

ERIC Educational Resources Information Center

Environmental Science and Technology, 1975

1975-01-01

Finland has received a $20 million loan from the World Bank to attack its pollution problems, mainly water. Improved quality of life, as well as resource conservation are both motives and goals of that country's environmental programs. (BT)

Utilizing the right mix of environmental cleanup technologies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Whitaker, Wade; Bergren, Chris; Flora, Mary

2007-07-01

The Savannah River Site (SRS) is a 310-square-mile United States Department of Energy nuclear facility located along the Savannah River near Aiken, South Carolina. During operations, which started in 1951, hazardous substances (chemicals and radionuclides) were released to the environment. The releases occurred as a result of inadvertent spills and waste disposal in unlined pits and basins which was common practice before environmental regulations existed. The hazardous substances have migrated to the vadose zone and groundwater in many areas of the SRS, resulting in 515 waste units that are required by environmental regulations, to undergo characterization and, if needed, remediation.more » In the initial years of the SRS environmental cleanup program (early 1990's), the focus was to use common technologies (such as pump and treat, air stripping, excavation and removal) that actively and tangibly removed contamination. Exclusive use of these technologies required continued and significant funding while often failing to meet acceptable clean-up goals and objectives. Recognizing that a more cost-effective approach was needed, SRS implemented new and complementary remediation methods focused on active and passive technologies targeted to solve specific remediation problems. Today, SRS uses technologies such as chemical / pH-adjusting injection, phyto-remediation, underground cutoff walls, dynamic underground stripping, soil fracturing, microbial degradation, baro-balls, electrical resistance heating, soil vapor extraction, and micro-blowers to more effectively treat contamination at lower costs. Additionally, SRS's remediation approach cost effectively maximizes cleanup as SRS works pro-actively with multiple regulatory agencies. Using GIS, video, animation, and graphics, SRS is able to provide an accurate depiction of the evolution of SRS groundwater and vadose zone cleanup activities to convince stakeholders and regulators of the effectiveness of various cleanup technologies. Remediating large, complex groundwater plumes using state of-the art technologies and approaches is a hallmark of years of experience and progress. Environmental restoration at SRS continues to be a challenging and dynamic process as new cleanup technologies and approaches are adopted. (authors)« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pierce, Eric M.; Freshley, Mark D.; Hubbard, Susan S.

In this report, we start by examining previous efforts at linking science and DOE EM research with cleanup activities. Many of these efforts were initiated by creating science and technology roadmaps. A recurring feature of successfully implementing these roadmaps into EM applied research efforts and successful cleanup is the focus on integration. Such integration takes many forms, ranging from combining information generated by various scientific disciplines, to providing technical expertise to facilitate successful application of novel technology, to bringing the resources and creativity of many to address the common goal of moving EM cleanup forward. Successful projects identify and focusmore » research efforts on addressing the problems and challenges that are causing “failure” in actual cleanup activities. In this way, basic and applied science resources are used strategically to address the particular unknowns that are barriers to cleanup. The brief descriptions of the Office of Science basic (Environmental Remediation Science Program [ERSP]) and EM’s applied (Groundwater and Soil Remediation Program) research programs in subsurface science provide context to the five “crosscutting” themes that have been developed in this strategic planning effort. To address these challenges and opportunities, a tiered systematic approach is proposed that leverages basic science investments with new applied research investments from the DOE Office of Engineering and Technology within the framework of the identified basic science and applied research crosscutting themes. These themes are evident in the initial portfolio of initiatives in the EM groundwater and soil cleanup multi-year program plan. As stated in a companion document for tank waste processing (Bredt et al. 2008), in addition to achieving its mission, DOE EM is experiencing a fundamental shift in philosophy from driving to closure to enabling the long-term needs of DOE and the nation.« less

Printable Version of Mold Remediation in Schools and Commercial Buildings

EPA Pesticide Factsheets

This document presents guidelines for the remediation/cleanup of mold and moisture problems in schools and commercial buildings; these guidelines include measures designed to protect the health of building occupants and remediators.

Approaches to sheltered-water oil spills

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jacobs, M.A.; Waldron, D.M.

Technology has produced more effective and efficient oil removal equipment for on-water cleanup in the past five years. Much of the innovation has been to increase recovery capacity to meet the planning volumes required to government regulations. However, more than 95 percent of the spills are relatively small. Large equipment, often requiring large platforms, is not very useful and is difficult/expensive to operate on small spills. In addition, damage from spills results when oil impacts shorelines. The emphasis on spill response should address the ability of the equipment to remove oil in a nearshore environment. Clean Seas has been attemptingmore » to address this need since the Avila Pipeline spill in 1992, in which a 180 barrel spill resulted in about $18 million damage/cleanup cost.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

Hazardous chemicals in the environment have received ever increasing attention in recent years. In response to ongoing problems with hazardous waste management, Congress enacted the Resource Conservation and Recovery Act (RCRA) in 1976. In 1980, Congress adopted the Comprehensive Environmental Response Compensation, and Liability Act (CERCLA), commonly called Superfund to provide for emergency spill response and to clean up closed or inactive hazardous waste sites. Scientists and engineers have begun to respond to the hazardous waste challenge with research and development on treatment of waste streams as well as cleanup of polluted areas. The magnitude of the problem is justmore » now beginning to be understood. The U.S. Environmental Protection Agency (USEPA) National Priorities List as of September 13 1985, contained 318 proposed sites and 541 final sites (USEPA, 1985). Estimates of up to 30,000 sites containing hazardous wastes (1,200 to 2,000 of which present a serious threat to public health) have been made (Public Law 96-150). In addition to the large number of sites, the costs of cleanup using available technology are phenomenal. For example, a 10-acre toxic waste site in Ohio is to be cleaned up by removing chemicals from the site and treating the contaminated groundwater. The federal government has already spent more than $7 million to remove the most hazardous wastes and the groundwater decontamination alone is expected to take at least 10 years and cost $12 million. Another example of cleanup costs comes from the State of California Commission for Economic Development which predicts a bright economic future for the state except for the potential outlay of $40 billion for hazardous waste cleanup mandated by federal and state laws.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Taylor, L.H.

In its beginning, the U.S. Department of Energy (DOE) Office of Environmental Management (EM) viewed private industry as lacking adequate technology know-how to meet demands of hazardous and radioactive waste problems at the DOE`s laboratories and nuclear weapons production facilities. In November 1989, EM`s Office of Technology Development (recently renamed the Office of Science and Technology) embarked on a bold program of developing and demonstrating {open_quotes}innovative{close_quotes} waste cleanup technologies that would be safer, faster, more effective, and less expensive than the {open_quotes}baseline{close_quotes} commercial methods. This program has engaged DOE sites, national laboratories, and universities to produce preferred solutions to the problems of handling and treating DOE wastes. More recently, much of this work has shifted to joint efforts with private industry partners to accelerate the use of newly developed technologies and to enhance existing commercial methods. To date, the total funding allocation to the Office of Science and Technology program has been aboutmore » $2.8 billion. If the technology applications` projects of the EM Offices of Environmental Restoration and Waste Management are included, the total funding is closer to $$4 billion. Yet, the environmental industry generally has not been very receptive to EM`s innovative technology offerings. And, essentially the same can be said for DOE sites. According to the U.S. General Accounting Office in an August 1994 report, {open_quotes}Although DOE has spent a substantial amount to develop waste cleanup technologies, little new technology finds its way into the agency`s cleanup actions{close_quotes}. The DOE Baseline Environmental Management Report estimated cleanups of DOE`s Cold War legacy of wastes to require the considerable cost of $$226 billion over a period of 75 years. 1 tab.« less

Crew appliance concepts. Volume 2, appendix B: Shuttle orbiter appliances supporting engineering data. [food management and personal hygiene

NASA Technical Reports Server (NTRS)

Proctor, B. W.; Reysa, R. P.; Russell, D. J.

1975-01-01

Technical data collected for the food management and personal hygiene appliances considered for the shuttle orbiter are presented as well as plotted and tabulated trade study results for each appliance. Food storage, food operation, galley cleanup, waste collection/transfer, body cleansing, and personal grooming were analyzed.

City Kids Go Green.

ERIC Educational Resources Information Center

Taylor, Tricia

1993-01-01

Describes Outward Bound Urban Resources Initiative, a six-week summer course whose goal is to work with urban youth to develop solutions for local environmental problems. Among the activities described include converting city lots into parks, neighborhood cleanup, and tree planting. (MDH)

Computer Models Used to Support Cleanup Decision Making at Hazardous and Radioactive Waste Sites

EPA Pesticide Factsheets

This report is a product of the Interagency Environmental Pathway Modeling Workgroup. This report will help bring a uniform approach to solving environmental modeling problems common to site remediation and restoration efforts.

HIGH-TEMPERATURE AND HIGH-PRESSURE PARTICULATE CONTROL REQUIREMENTS

EPA Science Inventory

The report reviews and evaluates high-temperature and high-pressure particulate cleanup requirements of existing and proposed energy processes. The study's aims are to define specific high-temperature and high-pressure particle removal problems, to indicate potential solutions, a...

Status of Environmental Management Initiatives to Accelerate the Reduction of Environmental Risks and Challenges Posed by the Legacy of the Cold War

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

2009-01-01

Fifty years of nuclear weapons production and energy research in the United States during the Cold War generated large amounts of radioactive wastes, spent nuclear fuel (SNF), excess plutonium and uranium, thousands of contaminated facilities, and contaminated soil and groundwater. During most of that half century, the Nation did not have the environmental regulatory structure or nuclear waste cleanup technologies that exist today. The result was a legacy of nuclear waste that was stored and disposed of in ways now considered unacceptable. Cleaning up and ultimately disposing of these wastes is the responsibility of the U.S. Department of Energy (DOE).more » In 1989, DOE established the Office of Environmental Management (EM) to solve the large scale and technically challenging risks posed by the world's largest nuclear cleanup. This required EM to build a new nuclear cleanup infrastructure, assemble and train a technically specialized workforce, and develop the technologies and tools required to safely decontaminate, disassemble, stabilize, disposition, and remediate unique radiation hazards. The sites where nuclear activities produced legacy waste and contamination include the original Manhattan Project sites--Los Alamos, New Mexico; Hanford, Washington; and Oak Ridge, Tennessee--as well as major Cold War sites, such as Savannah River Site, South Carolina; the Idaho National Laboratory, Idaho; Rocky Flats Plant, Colorado; and Fernald, Ohio. Today EM has responsibility for nuclear cleanup activities at 21 sites covering more than two million acres in 13 states, and employs more than 30,000 Federal and contractor employees, including scientists, engineers and hazardous waste technicians. This cleanup poses unique, technically complex problems, which must be solved under the most hazardous of conditions, and which will require billions of dollars a year for several more decades. The EM program focus during its first 10 years was on managing the most urgent risks and maintaining safety at each site while negotiating state and Federal environmental compliance agreements. The program also concentrated on characterizing waste and nuclear materials and assessing the magnitude and extent of environmental contamination. By the late 1990s, EM had made significant progress in identifying and characterizing the extent of contamination and cleanup required and began transitioning from primarily a characterization and stabilization program to an active cleanup and closure program. During that time, EM formulated multi-year cleanup and closure plans, which contributed to cleanup progress; however, reducing the overall environmental risk associated with the cleanup program remained a challenge. In response, the Secretary of Energy directed a review of the EM program be undertaken. The resulting 'Top-to Bottom Review' re-directed the program focus from managing risks to accelerating the reduction of these risks.« less

Determination of the effect of formation water on fracture-fluid cleanup

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1998-03-01

Understanding hydraulic-fracture cleanup is essential for improving well stimulation. Residual gel damages fracture conductivity, shortens effective fracture half-length, and limits well productivity. The drive to develop fluids, additives, and procedures that minimize this damage continues to be a dominant theme in fracture-fluid-development programs. Fracture cleanup is a complex problem, and many parameters (e.g., fluid system, job design, flowback procedure, and reservoir conditions) can influence polymer and fluid recovery efficiencies. Often, specific products and methods that work well in one reservoir have little effect in another. Systematic analysis of fluid and polymer returns after a treatment is completed is the onlymore » way to quantify fracture cleanup. This is referred to as flowback analysis. This paper discusses a flowback-analysis field study on large hydraulic-fracturing treatments in the Taylor zone of the Cotton Valley formation in east Texas. This is a low-permeability (approximately 0.01 md) tight gas formation. It is a heterogeneous zone with layers of productive sandstone interspersed with relatively impermeable layers of shale. A typical well in this field initially produces approximately 0.75 to 1.3 MMcf/D gas and 35 to 40 bbl of water/MMcf of gas. The returns from 10 wells in this field were analyzed thoroughly.« less

Airman Scholar Journal. Volume 15, Fall 2010

DTIC Science & Technology

2010-01-01

more. The titles emergent from his hand ranged from Astronomy to On Freedom From Pain. He directed one of the wonders of the ancient world, a...Military Education Adapt?.................................................................... 49 Col Thomas A. Drohan “ Ancient Alexandria...the process of removing radioactive materials from the site. What the nuclear attacks on Hiroshima and Nagasaki taught us is that nuclear clean-up

U-PLANT GEOGRAPHIC ZONE CLEANUP PROTOTYPE

DOE Office of Scientific and Technical Information (OSTI.GOV)

ROMINE, L.D.

2006-02-01

The U Plant geographic zone (UPZ) occupies 0.83 square kilometers on the Hanford Site Central Plateau (200 Area). It encompasses the U Plant canyon (221-U Facility), ancillary facilities that supported the canyon, soil waste sites, and underground pipelines. The UPZ cleanup initiative coordinates the cleanup of the major facilities, ancillary facilities, waste sites, and contaminated pipelines (collectively identified as ''cleanup items'') within the geographic zone. The UPZ was selected as a geographic cleanup zone prototype for resolving regulatory, technical, and stakeholder issues and demonstrating cleanup methods for several reasons: most of the area is inactive, sufficient characterization information is availablemore » to support decisions, cleanup of the high-risk waste sites will help protect the groundwater, and the zone contains a representative cross-section of the types of cleanup actions that will be required in other geographic zones. The UPZ cleanup demonstrates the first of 22 integrated zone cleanup actions on the Hanford Site Central Plateau to address threats to groundwater, the environment, and human health. The UPZ contains more than 100 individual cleanup items. Cleanup actions in the zone will be undertaken using multiple regulatory processes and decision documents. Cleanup actions will include building demolition, waste site and pipeline excavation, and the construction of multiple, large engineered barriers. In some cases, different cleanup actions may be taken at item locations that are immediately adjacent to each other. The cleanup planning and field activities for each cleanup item must be undertaken in a coordinated and cohesive manner to ensure effective execution of the UPZ cleanup initiative. The UPZ zone cleanup implementation plan (ZCIP) was developed to address the need for a fundamental integration tool for UPZ cleanup. As UPZ cleanup planning and implementation moves forward, the ZCIP is intended to be a living document that will provide a focal point for integrating UPZ actions, including field cleanup activities, waste staging and handling, and post-cleanup monitoring and institutional controls.« less

2005 Defense Base Closure and Realignment Commission Report. Volume 2

DTIC Science & Technology

2005-01-01

known as the Superfund, is the legal framework for the identification, restoration, and transfer of contaminated property. In 1986, CERCLA was revised...place and operating pursuant to an approved remedial design. This allows the transfer prior to complete remediation of contamination , (source: 2005...uncontaminated parcels at closing bases while long-term cleanup of contaminated parcels continues, (source: 2005 BRAC Commission) CERTIFIED DATA P.L

Transonic Symposium: Theory, Application and Experiment, volume 2

NASA Technical Reports Server (NTRS)

Foughner, Jerome T., Jr. (Compiler)

1989-01-01

Papers presented at the Transonic Symposium are compiled. The following subject areas are covered: National Transonic Facility status; transonic aerodynamics of slender wing-body configuration; laminar flow flight experiments; laminar flow wind tunnel experiments; computational support of X-29A flight experiment; transition location on a clean-up glove installed on a F-14 aircraft; and design studies for a laminar glove for the X-29 aircraft.

Three-dimensional analysis of enamel surface alteration resulting from orthodontic clean-up -comparison of three different tools.

PubMed

Janiszewska-Olszowska, Joanna; Tandecka, Katarzyna; Szatkiewicz, Tomasz; Stępień, Piotr; Sporniak-Tutak, Katarzyna; Grocholewicz, Katarzyna

2015-11-18

The present study aimed at 3D analysis of adhesive remnants and enamel loss following the debonding of orthodontic molar tubes and orthodontic clean-up to assess the effectiveness and safety of One-Step Finisher and Polisher and Adhesive Residue Remover in comparison to tungsten carbide bur. Thirty human molars were bonded with chemical-cure orthodontic adhesive (Unite, 3M, USA), stored 24 h in 0.9 % saline solution, debonded and cleaned using three methods (Three groups of ten): tungsten carbide bur (Dentaurum, Pforzheim, Germany), one-step finisher and polisher (One gloss, Shofu Dental, Kyoto, Japan) and Adhesive Residue Remover (Dentaurum, Pforzheim, Germany). Direct 3D scanning in blue-light technology to the nearest 2 μm was performed before etching and after adhesive removal. Adhesive remnant height and volume as well as enamel loss depth and volume were calculated. An index of effectiveness and safety was proposed and calculated for every tool; adhesive remnant volume and duplicated enamel lost volume were divided by a sum of multiplicands. Comparisons using parametric ANOVA or nonparametric ANOVA rank Kruskal-Wallis tests were used to compare between tools for adhesive remnant height and volume, enamel loss depth and volume as well as for the proposed index. No statistically significant differences in the volume (p = 0.35) or mean height (p = 0.24) of adhesive remnants were found (ANOVA rank Kruskal-Wallis test) between the groups of teeth cleaned using different tools. Mean volume of enamel loss was 2.159 mm(3) for tungsten carbide bur, 1.366 mm(3) for Shofu One Gloss and 0.659 mm(3) for Adhesive Residue Remover - (F = 2.816, p = 0.0078). A comparison of the proposed new index between tools revealed highly statistically significant differences (p = 0.0081), supporting the best value for Adhesive Residue Remover and the worst - for tungsten carbide bur. The evaluated tools were all characterized by similar effectiveness. The most destructive tool with regards to enamel was the tungsten carbide bur, and the least was Adhesive Residue Removal.

Report of the Interagency Task Force on Persistent Marine Debris, May 1988.

ERIC Educational Resources Information Center

Keeny, Timothy R. E.; Cottingham, David

1989-01-01

Provides a definition of the marine debris problem and a charge to the task force. Presents five general recommendations concerning: federal leadership, public awareness and education program, implementation of laws, research and monitoring, and beach clean-up and monitoring. (RT)

FIELD APPLICATIONS OF ROBOTIC SYSTEMS IN HAZARDOUS WASTE SITE OPERATIONS

EPA Science Inventory

The cleanup of hazardous waste sites is a challenging and complex field that offers numerous opportunities for the application of robotic technology. he contamination problem, long in the making, will take decades to resolve. ur ingenuity in developing robotic tools to assist in ...

Water Pollution Control Across the Nation

ERIC Educational Resources Information Center

Environmental Science and Technology, 1973

1973-01-01

Reviewed are accomplishments, problems, and frustrations faced by individual states in meeting requirements of P.L. 92-500, Federal Water Pollution Control Act Amendments of 1972. State Environmental officials complain the new law may be a hindrance to established cleanup programs. Statistics and charts are given. (BL)

CERCLIS Non-NPL Removal Sites in US EPA Region 3

EPA Pesticide Factsheets

This data layer contains point locations of waste sites throughout EPA Region 3 that have come under the jurisdiction of CERCLA. Congress passed the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA, also known as Superfund) in response to a growing national concern about the release of hazardous substances from abandoned waste sites. Under CERCLA, Congress gave the federal government broad authority to regulate hazardous substances, to respond to hazardous substance emergencies, and to develop long-term solutions for the Nation's most serious hazardous waste problems. The 1980 law requires the parties responsible for the contamination to conduct or pay for the cleanup. If the Environmental Protection Agency's (EPA's) efforts to take an enforcement action for the cleanup are not successful, the federal government can clean up a site using the CERCLA Trust Fund. If the Superfund program conducts the cleanup, the government can take court action against responsible parties to recover up to three times the cleanup costs. These sites do not meet the requirements for the National Priority List, but are still part of the CERCLA list. The National Priority List is intended primarily to guide the EPA in determining which sites warrant further investigation. Some of these waste sites are also known as removal sites, where waste and/or soils are transported away from the site. This point location data was extracted by US EPA Region 3 pe

Phytoremediation: novel approaches to cleaning up polluted soils.

PubMed

Krämer, Ute

2005-04-01

Environmental pollution with metals and xenobiotics is a global problem, and the development of phytoremediation technologies for the plant-based clean-up of contaminated soils is therefore of significant interest. Phytoremediation technologies are currently available for only a small subset of pollution problems, such as arsenic. Arsenic removal employs naturally selected hyperaccumulator ferns, which accumulate very high concentrations of arsenic specifically in above-ground tissues. Elegant two-gene transgenic approaches have been designed for the development of mercury or arsenic phytoremediation technologies. In a plant that naturally hyperaccumulates zinc in leaves, approximately ten key metal homeostasis genes are expressed at very high levels. This outlines the extent of change in gene activities needed in the engineering of transgenic plants for soil clean-up. Further analysis and discovery of genes for phytoremediation will benefit from the recent development of segregating populations for a genetic analysis of naturally selected metal hyperaccumulation in plants, and from comprehensive ionomics data--multi-element concentration profiles from a large number of Arabidopsis mutants.

Hazardous and Toxic Waste (HTW) Contracting Problems: A Study of the Contracting Problems Related to Surety Bonding in the HTW Cleanup Program

DTIC Science & Technology

1990-07-01

Fair value of solely owned real estate* $ b. All mortgages or other encumbrances on the real estate included in Line a c. Real estate equity (subtract...Line b from Line a) d. Fair value of all solely owned property other than real estate* e. Total of the amounts on Lines c and d f. All other

Early problem behavior among children from low-income, mother-headed families: a multiple risk perspective.

PubMed

Olson, Sheryl L; Ceballo, Rosario; Park, Curie

2002-12-01

Examined proximal and contextual factors most strongly related to externalizing behavior among young children growing up in low-income, mother-headed families. Participants were 50 low-income single mothers and their preschool-age children who were visited twice in the home setting. Measures of proximal (low levels of supportive parenting, high levels of punitive disciplinary practices, low levels of maternal emotional well-being) and contextual (low maternal support, high levels of family stress) risk were assessed in relation to maternal reports of child externalizing behavior and an index of negative child behavior during a clean-up task. Child defiance during the clean-up task was highly associated with punitive maternal control in the same situation but had no other direct correlates. However, multiple risk factors representing both proximal and contextual variables were associated with variations in children's behavior problem scores. Mothers of children with high behavior problem scores reported lower feelings of self-efficacy in handling child care and emotional stressors, more frequent use of punitive child disciplinary practices, and lower feelings of satisfaction with the quality of their supportive resources than others. Maternal self-evaluations of coping efficacy mediated the relation between perceived support and child behavior problems, suggesting that constructs of personal control are important to represent in future studies of highly stressed parents.

A novel polymer inclusion membrane based method for continuous clean-up of thiocyanate from gold mine tailings water.

PubMed

Cho, Youngsoo; Cattrall, Robert W; Kolev, Spas D

2018-01-05

Thiocyanate is present in gold mine tailings waters in concentrations up to 1000mgL -1 and this has a serious environmental impact by not allowing water reuse in the flotation of gold ore. This significantly increases the consumption of fresh water and the amount of wastewater discharged in tailings dams. At the same time thiocyanate in tailings waters often leads to groundwater contamination. A novel continuous membrane-based method for the complete clean-up of thiocyanate in concentrations as high as 1000mgL -1 from its aqueous solutions has been developed. It employs a flat sheet polymer inclusion membrane (PIM) of composition 70wt% PVC, 20wt% Aliquat 336 and 10wt% 1-tetradecanol which separates counter-current streams of a feed thiocyanate solution and a 1M NaNO 3 receiving solution. The PIM-based system has been operated continuously for 45days with 99% separation efficiency. The volume of the receiving solution has been drastically reduced by recirculating it and continuously removing thiocyanate by precipitating it with in-situ generated Cu(I). The newly developed PIM-based thiocyanate clean-up method is environmentally friendly in terms of reagent use and inexpensive with respect to both equipment and running costs. Copyright © 2017 Elsevier B.V. All rights reserved.

A re-evaluation of the taste and odour of methyl tertiary butyl ether (MTBE) in drinking water.

PubMed

Suffet, I H

2007-01-01

Methyl tertiary butyl ether (MTBE) is a gasoline additive that has been found in groundwater when an underground gasoline storage tank leaks. Although dependent on the clean-up standards that are applied, clean-up costs have been estimated in the US alone to be in the billions of dollars. MTBE is considered primarily a taste and odour concern and not a toxicity issue at concentrations found in drinking water. Thus, the clean-up of MTBE problems is controlled by the MTBE odour threshold concentration (OTC). The level of clean-up and associated differential of millions of dollars is a matter of concern for water purveyors and well owners. A 1993 study of nine OTC studies showed the OTC of MTBE in water to be between 0.04 and 0.06 microg/L, a level over two orders of magnitude less than eight other studies. This 1993 study was repeated at the original laboratory in 2004 and is reported in this paper. The laboratory's quality control programme and ability to repeat one of the eight other studies indicated the laboratory was qualified to repeat its original OTC study. The flavour and odour detection threshold range in the 1993 study, however, could not be confirmed by trained assessors repeating the original study in 2004. The inconsistencies in the data and the high detection on water blanks indicate that the dilution series of the test solutions for the 1993 study were mainly at subthreshold levels. Therefore, the original study of 1993 is not a valid OTC study for MTBE and should not be used to develop drinking water and clean-up standards. The OTC of MTBE is over 15 microg/L for the eight valid studies.

Environmental Law: Fundamentals for Schools.

ERIC Educational Resources Information Center

Day, David R.

This booklet outlines the environmental problems most likely to arise in schools. An overview provides a fundamental analysis of environmental issues rather than comprehensive analysis and advice. The text examines the concerns that surround superfund cleanups, focusing on the legal framework, and furnishes some practical pointers, such as what to…

Waste information management system: a web-based system for DOE waste forecasting

DOE Office of Scientific and Technical Information (OSTI.GOV)

Geisler, T.J.; Shoffner, P.A.; Upadhyay, U.

2007-07-01

The implementation of the Department of Energy (DOE) mandated accelerated cleanup program has created significant potential technical impediments that must be overcome. The schedule compression will require close coordination and a comprehensive review and prioritization of the barriers that may impede treatment and disposition of the waste streams at each site. Many issues related to site waste treatment and disposal have now become potential critical path issues under the accelerated schedules. In order to facilitate accelerated cleanup initiatives, waste managers at DOE field sites and at DOE headquarters in Washington, D.C., need timely waste forecast information regarding the volumes andmore » types of waste that will be generated by DOE sites over the next 25 years. Each local DOE site has historically collected, organized, and displayed site waste forecast information in separate and unique systems. However, waste information from all sites needs a common application to allow interested parties to understand and view the complete complex-wide picture. A common application would allow identification of total waste volumes, material classes, disposition sites, choke points, and technological or regulatory barriers to treatment and disposal. The Applied Research Center (ARC) at Florida International University (FIU) in Miami, Florida, has completed the development of this web-based forecast system. (authors)« less

A validated method for rapid determination of dibenzo-p-dioxins/furans (PCDD/Fs), polybrominated diphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs) in human milk: focus on utility of tandem solid phase extraction (SPE) cleanup.

PubMed

Lin, Yuanjie; Feng, Chao; Xu, Qian; Lu, Dasheng; Qiu, Xinlei; Jin, Yu'e; Wang, Guoquan; Wang, Dongli; She, Jianwen; Zhou, Zhijun

2016-07-01

An improved method based on tandem solid phase extraction (SPE) cleanup and gas chromatography-high resolution mass spectrometry (GC-HRMS) has been validated for a rapid determination of dibenzo-p-dioxins/furans (PCDD/Fs), dioxin-like polychlorinated biphenyls (PCBs), marker polychlorinated biphenyls (M-PCBs), and polybrominated diphenyl ethers (PBDEs) using a large volume (50 mL) of human milk. This method was well validated for the measurement of these analytes in human milk from the general population with low limits of detection (LODs, 0.004-0.12 ng/g lipid), satisfactory accuracy (75-120 % of recoveries), and precision [less than 10 % of relative standard deviations (RSDs)]. To comprehensively evaluate the performance of this method, a good, presently validated and routinely used method based on an automated sample clean-up system (ASCS, based on the commercial acid multilayer silica, basic alumina, and carbon columns) was used in parallel for comparison. Compared with the ASCS method, this method presented comparable specificity. Additionally, this method, in contrast to ASCS method, highly reduced consumption of solvents (40 mL versus 500 mL), which results in much lower background in the procedural blank, reduced time, and enhanced sample pretreatment throughput. This method was also applied in a pilot study to measure a batch of human milk samples with satisfactory results. Graphical Abstract Characteristics of the application of tandem SPE cleanup for determination of PCDD/Fs, DL-PCBs,M-PCBs and PBDEs in human milk.

ANALYSIS RESULTS FOR BUILDING 241 702-AZ A TRAIN

DOE Office of Scientific and Technical Information (OSTI.GOV)

DUNCAN JB; FRYE JM; COOKE CA

2006-12-13

This report presents the analyses results for three samples obtained under RPP-PLAN-28509, Sampling and Analysis Plan for Building 241 702-AZ A Train. The sampling and analysis was done in response to problem evaluation request number PER-2004-6139, 702-AZ Filter Rooms Need Radiological Cleanup Efforts.

Safety in the Chemical Laboratory: Flood Control.

ERIC Educational Resources Information Center

Pollard, Bruce D.

1983-01-01

Describes events leading to a flood in the Wehr Chemistry Laboratory at Marquette University, discussing steps taken to minimize damage upon discovery. Analyzes the problem of flooding in the chemical laboratory and outlines seven steps of flood control: prevention; minimization; early detection; stopping the flood; evaluation; clean-up; and…

Plutonium mining for cleanup.

PubMed

Bramlitt, E T

1988-08-01

Cleanup is the act of making a contaminated site relatively free of Pu so it may be used without radiological safety restrictions. Contaminated ground is the focus of major cleanups. Cleanup traditionally involves determining Pu content of soil, digging up soil in which radioactivity exceeds guidelines, and relocating excised soil to a waste-disposal site. Alternative technologies have been tested at Johnston Atoll (JA), where there is as much as 100,000 m3 of Pu-contaminated soil. A mining pilot plant operated for the first 6 mo of 1986 and made 98% of soil tested "clean", from more than 40 kBq kg-1 (1000 pCi g-1) to less than about 500 Bq kg-1 (15 pCi g-1) by concentrating Pu in 2% of the soil. The pilot plant is now installed at the U.S. Department of Energy Nevada Test Site for evaluating cleanup of other contaminated soils and refining cleanup effectiveness. A full-scale cleanup plant has been programmed for JA in 1988. In this paper, previous cleanups are reviewed, and the mining endeavor at JA is detailed. "True soil cleanup" is contrasted with the classical "soil relocation cleanup." The mining technology used for Pu cleanup has been in use for more than a century. Mining for cleanup, however, is unique. It is envisioned as being prominent for radiological and other cleanups in the future.

The P.A.C.E.S. Grading Rubric: Creating a Student-Owned Assessment Tool for Projects-The Design Brief Brings out All Kinds of "Out of the Box" Thinking, with Many Correct Answers to Solve the Problem

ERIC Educational Resources Information Center

Tufte, Robert B., Jr.

2005-01-01

P.A.C.E.S. stands for Participation, Appearance, Cleanup, Engineering, and Safety. The author has traditionally used design briefs to set the limits on processes and materials to solve a given problem. The design brief brings out all kinds of "out of the box" thinking, with many correct answers to solve the problem. The P.A.C.E.S. rubric ties the…

Rapid method for measuring rotenone in water at piscicidal concentrations

USGS Publications Warehouse

Dawson, V.K.; Harman, P.D.; Schultz, D.P.; Allen, J.L.

1983-01-01

A high-performance liquid chromatography (HPLC) procedure that is rapid, specific, and sensitive (limit of detection <0.005 mg/liter) was developed for monitoring application and degradation rates of rotenone. For analysis, a water sample is buffered to pH 5 and injected through a Sep Pak(R) C18 disposable cartridge. The cartridge adsorbs and retains the rotenone which then can be eluted quantitatively from the cartridge with a small volume of methanol. This step effectively concentrates the sample and provides sample cleanup. The methanol extract is analyzed directly by HPLC on an MCH 10 reverse-phase column; methanol: water (75:25, volume : volume) is the mobile phase and flow rate is 1.5 ml/minute. The rotenone is detected by ultraviolet spectrophotometry at a wavelength of 295 nm.

Processing plutonium-contaminated soil on Johnston Atoll

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moroney, K.; Moroney, J. III; Turney, J.

1994-07-01

This article describes a cleanup project to process plutonium- and americium-contaminated soil on Johnston Atoll for volume reduction. Thermo Analytical`s (TMA`s) segmented gate system (SGS) for this remedial operation has been in successful on-site operation since 1992. Topics covered include the basis for development, a description of the Johnston Atoll; the significance of results; the benefits of the technology; applicability to other radiologically contaminated sites. 7 figs., 1 tab.

River Corridor Cleanup Contract Fiscal Year 2006 Detailed Work Plan: D4 Project/Reactor ISS Closure Projects Field Remediation Project Waste Operations Project End State and Final Closure Project Mission/General Support, Volume 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Project Integration

2005-09-26

The Hanford Site contains many surplus facilities and waste sites that remain from plutonium production activities. These contaminated facilities and sites must either be stabilized and maintained, or removed, to prevent the escape of potentially hazardous contaminants into the environment and exposure to workers and the public.

Integrated preservation and sample clean up procedures for studying water ingestion by recreational swimmers via urinary biomarker determination.

PubMed

Cantú, Ricardo; Shoemaker, Jody A; Kelty, Catherine A; Wymer, Larry J; Behymer, Thomas D; Dufour, Alfred P; Magnuson, Matthew L

2017-08-22

The use of cyanuric acid as a biomarker for ingestion of swimming pool water may lead to quantitative knowledge of the volume of water ingested during swimming, contributing to a better understanding of disease resulting from ingestion of environmental contaminants. When swimming pool water containing chlorinated cyanurates is inadvertently ingested, cyanuric acid is excreted quantitatively within 24 h as a urinary biomarker of ingestion. Because the volume of water ingested can be quantitatively estimated by calculation from the concentration of cyanuric acid in 24 h urine samples, a procedure for preservation, cleanup, and analysis of cyanuric acid was developed to meet the logistical demands of large scale studies. From a practical stand point, urine collected from swimmers cannot be analyzed immediately, given requirements of sample collection, shipping, handling, etc. Thus, to maintain quality control to allow confidence in the results, it is necessary to preserve the samples in a manner that ensures as quantitative analysis as possible. The preservation and clean-up of cyanuric acid in urine is complicated because typical approaches often are incompatible with the keto-enol tautomerization of cyanuric acid, interfering with cyanuric acid sample preparation, chromatography, and detection. Therefore, this paper presents a novel integration of sample preservation, clean-up, chromatography, and detection to determine cyanuric acid in 24 h urine samples. Fortification of urine with cyanuric acid (0.3-3.0 mg/L) demonstrated accuracy (86-93% recovery) and high reproducibility (RSD < 7%). Holding time studies in unpreserved urine suggested sufficient cyanuric acid stability for sample collection procedures, while longer holding times suggested instability of the unpreserved urine. Preserved urine exhibited a loss of around 0.5% after 22 days at refrigerated storage conditions of 4 °C. Published by Elsevier B.V.

Cleanups in My Community Data

EPA Pesticide Factsheets

Cleanups in My Community (CIMC) enables you to map and list hazardous waste cleanup locations and grant areas, and drill down to details about those cleanups and grants and other, related information.

They've Seen Fire and They've Seen Rain.

ERIC Educational Resources Information Center

Chandler, Kurt

1998-01-01

Recounts what school district facilities managers learned from the flood and fire disaster in Grand Forks, North Dakota. Examines the clean-up effort, such as locating sufficient architectural and construction crews to meet repair demands, and unforeseen problems, such as toxic biological growth. Also describes the damage and repair expenses. (RJM)

Green PCB Remediation from Sediment Systems (GPRSS) Project

NASA Technical Reports Server (NTRS)

Falker, John; Thompson, Karen; Zeitlin, Nancy; Quinn, Jacqueline; Parrish, Lewis M.

2014-01-01

An ongoing problem facing the global environment community including NASA centers is the removal and remediation of polychlorinated biphenyls (PCBs). PCBs were commonly used in a variety of materials including paints, caulking, and adhesives due to the advantageous physical and chemical properties that PCBs imparted to these various materials. Unfortunately, these properties have made the treatment of sites contaminated with these chemicals extremely difficult to deal with, due to their inherent chemical stability. The remediation of sediments contaminated with PCBs is especially difficult, primarily due to the risk of releasing the contaminant into the environment during the treatment process. Traditional treatment options involve the use of dredging and incineration of the contaminated soils/sediments, in which the chance of releasing the contaminants is greatly increased. The purpose of this project is to develop cleanup technology capable of remediating contaminated sediments in-situ, with minimum intrusion. This allows for the minimization of any potential contaminant release during the treatment process, providing a safer method for cleanup operations (as opposed to dredging/incineration) and still treating the basic problem of PCB contamination (as opposed to capping).

Recent trends at the state and federal level in accelerating CERCLA clean-ups

DOE Office of Scientific and Technical Information (OSTI.GOV)

Clegg, B.

Efforts at accelerating remedial action at the federal level focus on the following: the Superfund accelerated clean-up model (SCAM); Brownfields economic redevelopment initiative; guidance documents and policies; and collaboration with state voluntary cleanup programs. At the state level efforts involved in accelerating clean-ups include voluntary clean-up programs and Brownfields initiatives.

Mold: Cleanup and Remediation

MedlinePlus

... National Center for Environmental Health (NCEH) Cleanup and Remediation Recommend on Facebook Tweet Share Compartir On This ... CDC and EPA on mold cleanup, removal and remediation. Cleanup information for you and your family Homeowner’s ...

Cleanups in My Community

EPA Pesticide Factsheets

Cleanups In My Community is a web app of hazardous waste cleanups for which EPA collects information, on maps and in lists, and to access additional information about those cleanups. This page describes and links to the application.

Investigation of post hydraulic fracturing well cleanup physics in the Cana Woodford Shale

NASA Astrophysics Data System (ADS)

Lu, Rong

Hydraulic fracturing was first carried out in the 1940s and has gained popularity in current development of unconventional resources. Flowing back the fracturing fluids is critical to a frac job, and determining well cleanup characteristics using the flowback data can help improve frac design. It has become increasingly important as a result of the unique flowback profiles observed in some shale gas plays due to the unconventional formation characteristics. Computer simulation is an efficient and effective way to tackle the problem. History matching can help reveal some mechanisms existent in the cleanup process. The Fracturing, Acidizing, Stimulation Technology (FAST) Consortium at Colorado School of Mines previously developed a numerical model for investigating the hydraulic fracturing process, cleanup, and relevant physics. It is a three-dimensional, gas-water, coupled fracture propagation-fluid flow simulator, which has the capability to handle commonly present damage mechanisms. The overall goal of this research effort is to validate the model on real data and to investigate the dominant physics in well cleanup for the Cana Field, which produces from the Woodford Shale in Oklahoma. To achieve this goal, first the early time delayed gas production was explained and modeled, and a simulation framework was established that included all three relevant damage mechanisms for a slickwater fractured well. Next, a series of sensitivity analysis of well cleanup to major reservoir, fracture, and operational variables was conducted; five of the Cana wells' initial flowback data were history matched, specifically the first thirty days' gas and water producing rates. Reservoir matrix permeability, net pressure, Young's modulus, and formation pressure gradient were found to have an impact on the gas producing curve's shape, in different ways. Some moderately good matches were achieved, with the outcome of some unknown reservoir information being proposed using the corresponding inputs from the history matching study. It was also concluded that extended shut-in durations after fracturing all the stages do not delay production in the overall situation. The success of history matching will further knowledge of well cleanup characteristics in the Cana Field, enable the future usage of this tool in other hydraulically fractured gas wells, and help operators optimize the flowback operations. Future improvements can be achieved by further developing the current simulator so that it has the capability of optimizing its grids setting every time the user changes the inputs, which will result in better stability when the relative permeability setting is modified.

The Success of a National Dialogue on Sustainable Military Range Management

ERIC Educational Resources Information Center

Siegel, Lenny

2003-01-01

Military munitions are the silent giant of hazardous waste management and cleanup in the United States. Toward the end of the first Clinton administration, the Navy and Air Force prevailed upon the Army--the armed service with the biggest ordnance problem--to consider co-sponsoring a formal dialogue on military munitions facilitated by the…

Fast-Track Cleanup at Closing DoD Installations

EPA Pesticide Factsheets

The Fast-Track Cleanup program strives to make parcels available for reuse as quickly as possible by the transfer of uncontaminated or remediated parcels, the lease of contaminated parcels where cleanup is underway, or the 'early transfer' of contaminated property undergoing cleanup.

Particulate Emission Abatement for Krakow Boilerhouses

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1998-09-14

Environmental cleanup and pollution control are considered the foremost national priorities in Poland. The target of this cleanup is the Polish coal industry, which supplies the fuel to generate over 78% of Poland`s primary energy production. This project addresses the problem of airborne dust and uncontrolled particulate emissions from boilerhouses, which represent a large fraction of the total in Poland. In Krakow alone, there are numerous uncontrolled boilers accounting for about half the total fuel use. The large number of low-capacity boilers poses both technical and economic challenges, since the cost of control equipment is a significant factor in themore » reduction of emissions. A new concept in dust collection, called a Core Separator, is proposed for this important application. The Core Separator is an advanced technology developed through research sponsored by the Department of Energy.« less

HANFORD SITE CENTRAL PLATEAU CLEANUP COMPLETION STRATEGY

DOE Office of Scientific and Technical Information (OSTI.GOV)

BERGMAN TB

2011-01-14

Cleanup of the Hanford Site is a complex and challenging undertaking. The U.S. Department of Energy (DOE) has developed a comprehensive vision for completing Hanford's cleanup mission including transition to post-cleanup activities. This vision includes 3 principle components of cleanup: the {approx}200 square miles ofland adjacent to the Columbia River, known as the River Corridor; the 75 square miles of land in the center of the Hanford Site, where the majority of the reprocessing and waste management activities have occurred, known as the Central Plateau; and the stored reprocessing wastes in the Central Plateau, the Tank Wastes. Cleanup of themore » River Corridor is well underway and is progressing towards completion of most cleanup actions by 2015. Tank waste cleanup is progressing on a longer schedule due to the complexity of the mission, with construction of the largest nuclear construction project in the United States, the Waste Treatment Plant, over 50% complete. With the progress on the River Corridor and Tank Waste, it is time to place increased emphasis on moving forward with cleanup of the Central Plateau. Cleanup of the Hanford Site has been proceeding under a framework defmed in the Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement). In early 2009, the DOE, the State of Washington Department of Ecology, and the U.S. Environmental Protection Agency signed an Agreement in Principle in which the parties recognized the need to develop a more comprehensive strategy for cleanup of the Central Plateau. DOE agreed to develop a Central Plateau Cleanup Completion Strategy as a starting point for discussions. This DOE Strategy was the basis for negotiations between the Parties, discussions with the State of Oregon, the Hanford Advisory Board, and other Stakeholder groups (including open public meetings), and consultation with the Tribal Nations. The change packages to incorporate the Central Plateau Cleanup Completion Strategy were signed by the Parties on October 26,2010, and are now in the process of being implemented.« less

Establishing Final Cleanup Decisions for the Hanford Site River Corridor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lerch, J.A.; Sands, J.P.

2007-07-01

A major challenge in the River Corridor Closure Contract is establishing final cleanup decisions for the source operable units in the Hanford Site river corridor. Cleanup actions in the river corridor began in 1994 and have been performed in accordance with a 'bias for action' approach adopted by the Tri-Parties - the U.S. Department of Energy, U.S. Environmental Protection Agency, and Washington State Department of Ecology. This approach enabled early application of cleanup dollars on actual remediation of contaminated waste sites. Consequently, the regulatory framework authorizing cleanup actions at source operable units in the river corridor consists largely of interimmore » action records of decision, which were supported by qualitative risk assessments. Obtaining final cleanup decisions for the source operable units is necessary to determine whether past cleanup actions in the river corridor are protective of human health and the environment and to identify any course corrections that may be needed to ensure that ongoing and future cleanup actions are protective. Because the cleanup actions are ongoing, it is desirable to establish the final cleanup decisions as early as possible to minimize the impacts of any identified course corrections to the present cleanup approach. Development of a strategy to obtain final cleanup decisions for the source operable units in a manner that is responsive to desires for an integrated approach with the groundwater and Columbia River components while maintaining the ability to evaluate each component on its own merit represents a significant challenge. There are many different options for grouping final cleanup decisions, and each involved party or stakeholder brings slightly different interests that shape the approach. Regardless of the selected approach, there are several specific challenges and issues to be addressed before making final cleanup decisions. A multi-agency and contractor working group has been established to address these issues and develop an endorsed strategy. Ultimately, it is anticipated that the Tri-Parties will establish a set of milestones to document pathway selection and define schedule requirements. (authors)« less

Psychological and perceived health effects of the Chernobyl disaster: a 20-year review.

PubMed

Bromet, Evelyn J; Havenaar, Johan M

2007-11-01

The mental health impact of Chernobyl is regarded by many experts as the largest public health problem unleashed by the accident to date. This paper reviews findings reported during the 20-y period after the accident regarding stress-related symptoms, effects on the developing brain, and cognitive and psychological impairments among highly exposed cleanup workers. With respect to stress-related symptoms, the rates of depressive, anxiety (especially post-traumatic stress symptoms), and medically unexplained physical symptoms are two to four times higher in Chernobyl-exposed populations compared to controls, although rates of diagnosable psychiatric disorders do not appear to be elevated. The symptom elevations were found as late as 11 y after the accident. Severity of symptomatology is significantly related to risk perceptions and being diagnosed with a Chernobyl-related health problem. In general, the morbidity patterns are consistent with the psychological impairments documented after other toxic events, such as the atomic bombings of Hiroshima and Nagasaki, the Three Mile Island accident, and Bhopal. With respect to the developing brain of exposed children who were in utero or very young when the accident occurred, the World Health Organization as well as American and Israeli researchers have found no significant associations of radiation exposure with cognitive impairments. Cognitive impairments in highly exposed cleanup workers have been reported by Ukrainian researchers, but these findings have not been independently confirmed. A seminal study found a significant excess death rate from suicide in cleanup workers, suggesting a sizable emotional toll. Given the magnitude and persistence of the adverse mental health effects on the general population, long-term educational and psychosocial interventions should be initiated that target primary care physicians, local researchers, and high risk populations, including participants in ongoing cohort studies.

Amounts and activity concentrations of radioactive wastes from the cleanup of large areas contaminated in nuclear accidents

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lehto, J.; Ikaeheimonen, T.K.; Salbu, B.

The fallout from a major nuclear accident at a nuclear plant may result in a wide-scale contamination of the environment. Cleanup of contaminated areas is of special importance if these areas are populated or cultivated. All cleanup measures generate high amounts of radioactive waste, which have to be treated and disposed of in a safe manner. Scenarios assessing the amounts and activity concentrations of radioactive wastes for various cleanup measures after severe nuclear accidents have been worked out for urban, forest and agricultural areas. These scenarios are based on contamination levels and ares of contaminated lands from a model accident,more » which simulates a worst case accident at a nuclear power plant. Amounts and activity concentrations of cleanup wastes are not only dependent on the contamination levels and areas of affected lands, but also on the type of deposition, wet or dry, on the time between the deposition and the cleanup work, on the season, at which the deposition took place, and finally on the level of cleanup work. In this study practically all types of cleanup wastes were considered, whether or not the corresponding cleanup measures are cost-effective or justified. All cleanup measures are shown to create large amounts of radioactive wastes, but the amounts, as well as the activity concentrations vary widely from case to case.« less

Robotics crosscutting program: Technology summary

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

The Office of Environmental Management (EM) is responsible for cleaning up the legacy of radioactive and chemically hazardous waste at contaminated sites and facilities throughout the U.S. Department of Energy (DOE) nuclear weapons complex, preventing further environmental contamination, and instituting responsible environmental management. Initial efforts to achieve this mission resulted in the establishment of environmental restoration and waste management programs. However, as EM began to execute its responsibilities, decision makers became aware that the complexity and magnitude of this mission could not be achieved efficiently, affordably, safely, or reasonably with existing technology. Once the need for advanced cleanup technologies becamemore » evident, EM established an aggressive, innovative program of applied research and technology development. The Office of Technology Development (OTD) was established in November 1989 to advance new and improved environmental restoration and waste management technologies that would reduce risks to workers, the public, and the environment; reduce cleanup costs; and devise methods to correct cleanup problems that currently have no solutions. In 1996, OTD added two new responsibilities - management of a Congressionally mandated environmental science program and development of risk policy, requirements, and guidance. OTD was renamed the Office of Science and Technology (OST). This documents presents information concerning robotics tank waste retrieval overview, robotic chemical analysis automation, robotics decontamination and dismantlement, and robotics crosscutting and advanced technology.« less

Geostatistical approach for assessing soil volumes requiring remediation: validation using lead-polluted soils underlying a former smelting works.

PubMed

Demougeot-Renard, Helene; De Fouquet, Chantal

2004-10-01

Assessing the volume of soil requiring remediation and the accuracy of this assessment constitutes an essential step in polluted site management. If this remediation volume is not properly assessed, misclassification may lead both to environmental risks (polluted soils may not be remediated) and financial risks (unexpected discovery of polluted soils may generate additional remediation costs). To minimize such risks, this paper proposes a geostatistical methodology based on stochastic simulations that allows the remediation volume and the uncertainty to be assessed using investigation data. The methodology thoroughly reproduces the conditions in which the soils are classified and extracted at the remediation stage. The validity of the approach is tested by applying it on the data collected during the investigation phase of a former lead smelting works and by comparing the results with the volume that has actually been remediated. This real remediated volume was composed of all the remediation units that were classified as polluted after systematic sampling and analysis during clean-up stage. The volume estimated from the 75 samples collected during site investigation slightly overestimates (5.3% relative error) the remediated volume deduced from 212 remediation units. Furthermore, the real volume falls within the range of uncertainty predicted using the proposed methodology.

Worldwide Emerging Environmental Issues Affecting the U.S. Military. November 2006 Report

DTIC Science & Technology

2006-11-01

should follow this development for potential improved environmental biological weapons surveillance systems. Source: Researchers use laser...Protocol V on Explosive Remnants of War (ERW) of the Convention on Certain Conventional Weapons came into force on 12 November 2006, almost three...potentials for nanotech weapons , create unique problems of proliferation, health effects, environmental impacts, and post-conflict cleanups that are

REGULATORY STRATEGIES TO MINIMIZE GENERATION OF REGULATED WASTES FROM CLEANUP, CONTINUED USE OR DECOMMISSIONING OF NUCLEAR FACILITIES CONTAMINATED WITH POLYCHLORINATED BIPHENYLS (PCBS) - 11198

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lowry, N.

Disposal costs for liquid PCB radioactive waste are among the highest of any category of regulated waste. The high cost is driven by the fact that disposal options are extremely limited. Toxic Substances Control Act (TSCA) regulations require most liquids with PCBs at concentration of {ge} 50 parts-per-million to be disposed by incineration or equivalent destructive treatment. Disposal fees can be as high as $200 per gallon. This figure does not include packaging and the cost to transport the waste to the disposal facility, or the waste generator's labor costs for managing the waste prior to shipment. Minimizing the generationmore » of liquid radioactive PCB waste is therefore a significant waste management challenge. PCB spill cleanups often generate large volumes of waste. That is because the removal of PCBs typically requires the liberal use of industrial solvents followed by a thorough rinsing process. In a nuclear facility, the cleanup process may be complicated by the presence of radiation and other occupational hazards. Building design and construction features, e.g., the presence of open grating or trenches, may also complicate cleanup. In addition to the technical challenges associated with spill cleanup, selection of the appropriate regulatory requirements and approach may be challenging. The TSCA regulations include three different sections relating to the cleanup of PCB contamination or spills. EPA has also promulgated a separate guidance policy for fresh PCB spills that is published as Subpart G of 40 CFR 761 although it is not an actual regulation. Applicability is based on the circumstances of each contamination event or situation. Other laws or regulations may also apply. Identification of the allowable regulatory options is important. Effective communication with stakeholders, particularly regulators, is just as important. Depending on the regulatory path that is taken, cleanup may necessitate the generation of large quantities of regulated waste. Allowable options must be evaluated carefully in order to reduce compliance risks, protect personnel, limit potential negative impacts on facility operations, and minimize the generation of wastes subject to TSCA. This paper will identify critical factors in selecting the appropriate TSCA regulatory path in order to minimize the generation of radioactive PCB waste and reduce negative impacts to facilities. The importance of communicating pertinent technical issues with facility staff, regulatory personnel, and subsequently, the public, will be discussed. Key points will be illustrated by examples from five former production reactors at the DOE Savannah River Site. In these reactors a polyurethane sealant was used to seal piping penetrations in the biological shield walls. During the intense neutron bombardment that occurred during reactor operation, the sealant broke down into a thick, viscous material that seeped out of the piping penetrations over adjacent equipment and walls. Some of the walls were painted with a PCB product. PCBs from the paint migrated into the degraded sealant, creating PCB 'spill areas' in some of these facilities. The regulatory cleanup approach selected for each facility was based on its operational status, e.g., active, inactive or undergoing decommissioning. The selected strategies served to greatly minimize the generation of radioactive liquid PCB waste. It is expected that this information would be useful to other DOE sites, DOD facilities, and commercial nuclear facilities constructed prior to the 1979 TSCA ban on most manufacturing and uses of PCBs.« less

Environmental Stewardship at the Savannah River Site: Generations of Success - 13212

DOE Office of Scientific and Technical Information (OSTI.GOV)

Looney, Brian B.; Bergren, Christopher L.; Gaughan, Thomas F.

2013-07-01

Approximately sixty years ago, the Savannah River Site (SRS) was built to produce nuclear materials. SRS production operations impacted air, soil, groundwater, ecology, and the local environment. Throughout its history, SRS has addressed these contamination issues directly and has maintained a commitment to environmental stewardship. The Site boasts many environmental firsts. Notably, SRS was the first major Department of Energy (DOE) facility to perform a baseline ecological assessment. This pioneering effort, by Ruth Patrick and the Philadelphia Academy of Sciences, was performed during SRS planning and construction in the early 1950's. This unique early generation of work set the stagemore » for subsequent efforts. Since that time, the scientists and engineers at SRS pro-actively identified environmental problems and developed and implemented effective and efficient environmental management and remediation solutions. This second generation, spanning the 1980's through the 2000's, is exemplified by numerous large and small cleanup actions to address metals and radionuclides, solvents and hydrocarbons, facility and area decommissioning, and ecological restoration. Recently, a third generation of environmental management was initiated as part of Enterprise SRS. This initiative to 'Develop and Deploy Next Generation Cleanup Technologies' formalizes and organizes the major technology matching, development, and implementation processes associated with historical SRS cleanup success as a resource to support future environmental management missions throughout DOE. The four elements of the current, third generation, effort relate to: 1) transition from active to passive cleanup, 2) in situ decommissioning of large nuclear facilities, 3) new long term monitoring paradigms, and 4) a major case study related to support for recovery and restoration of the Japanese Fukushima-Daiichi nuclear power plant and surrounding environment. (authors)« less

EPRR

Science.gov Websites

Electronic Public Reading Room Operational Reading Room & Environmental Cleanup through April 2018 Los Alamos Legacy Cleanup Electronic Public Reading Room Environmental Cleanup from May 2018

33 CFR 165.1329 - Regulated Navigation Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site...

Code of Federal Regulations, 2014 CFR

2014-07-01

... Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site, Commencement Bay, Tacoma, WA. 165.1329... Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site, Commencement Bay, Tacoma, WA... (EPA) and others in the Thea Foss and Wheeler-Osgood Waterways EPA superfund cleanup site. Vessels may...

33 CFR 165.1329 - Regulated Navigation Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site...

Code of Federal Regulations, 2011 CFR

2011-07-01

... Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site, Commencement Bay, Tacoma, WA. 165.1329... Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site, Commencement Bay, Tacoma, WA... (EPA) and others in the Thea Foss and Wheeler-Osgood Waterways EPA superfund cleanup site. Vessels may...

33 CFR 165.1329 - Regulated Navigation Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site...

Code of Federal Regulations, 2013 CFR

2013-07-01

... Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site, Commencement Bay, Tacoma, WA. 165.1329... Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site, Commencement Bay, Tacoma, WA... (EPA) and others in the Thea Foss and Wheeler-Osgood Waterways EPA superfund cleanup site. Vessels may...

33 CFR 165.1329 - Regulated Navigation Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site...

Code of Federal Regulations, 2012 CFR

2012-07-01

... Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site, Commencement Bay, Tacoma, WA. 165.1329... Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site, Commencement Bay, Tacoma, WA... (EPA) and others in the Thea Foss and Wheeler-Osgood Waterways EPA superfund cleanup site. Vessels may...

Waste is a Terrible Thing to Mind: Perspectives on the Cleanup of the United States Nuclear Weapons Complex

NASA Astrophysics Data System (ADS)

Bodde, David

1997-03-01

For the 50 years of the Cold War, the United States nuclear arsenal was the cornerstone of our national security. These weapons were designed, manufactured, and armed with fissionable materials in an industrial complex that, at its peak, included about 16 major facilities and vast tracts of land in Nevada, Idaho, Washington, and South Carolina. Included among these are such well-known sites as the Savannah River Plant, the Hanford, Oak Ridge, and the Idaho National Engineering Laboratory. The Cold War, that "long twilight struggle" in the evocative phrase of John Kennedy, left little time and few resources for understanding and managing the environmental consequences of nuclear weapons production. At the same time, perceptions of the special nature of the atom led to a concentration of governance in the Atomic Energy Commission and the Joint Committee on Atomic Energy. Thus, external feedback for the managers of the complex was heavily filtered. But the imperatives of the Cold War have waned, and our understanding of the implications for the environment and the health and safety of workers has grown. By 1995 the Department of Energy (DoE) had spent about 23 billion in identifying and characterizing its waste, managing it, and assessing the actions needed to clean up the 120 sites in 36 states. Yet the majority of the task appeared ahead. Estimates made in 1995 suggested a total cost ranging from 200-350 billion and a time to complete of 75 years. If these were true, the cleanup of the weapons complex would become the largest civil works project in the history of humankind. Over the past year or so, the DoE program has shifted its focus from studies to actual cleanup. A strategic plan has been proposed that would accomplish most of the needed work over ten years at a cost of about $85 billion. At the same time, the Department is proposing to transfer oversight to the Nuclear Regulatory Commission, the Environmental Protection Agency, and the states. This Invited Symposium will address this cleanup from the perspective of contemporary issues, rather than the mistakes of the past. Dr. David Bodde, currently Co-Chair of the Environmental Management Advisory Board, which advises the DoE on technical and policy issues pertaining to the cleanup, will chair the Symposium. Dr. Frank Parker, Distinguished Professor of Environmental and Water Resources Engineering at Vanderbilt University, will provide a general description of these problems and issues, including cultural and historical factors, a technical description of the wastes, and what is physically required for resolution. The Honorable Alvin Alm, Assistant Secretary of Energy for Environmental Management, will describe the current strategy for solving the problem, how this differs from approaches used in the past, what can realistically be accomplished and when and at what cost. Mr. Thomas Winston of the Ohio Environmental Protection Agency, will present the perspective of the affected localities. And Dr. Charles Powers, Executive Director of the Environmental and Occupational Health Sciences Institute, will speak to the current role and future prospects for risk analysis in improving the allocation of resources for cleanup.

Cleanups in My Community

EPA Pesticide Factsheets

Cleanups in My Community (CIMC) is a public web application that enables integrated access through maps, lists and search filtering to site-specific information EPA has across all cleanup programs. CIMC taps into data publicly available from EPA's EnviroFacts (RCRA Corrective Action facilities, Brownfields properties and grant areas, Superfund NPL sites, other facility data) and web services (water monitoring stations, impaired waters, emergency responses, tribal boundaries, congressional districts, etc.) and connects to other applications (e.g., Superfund's CPAD) to provide easy seamless access to site-specific cleanup information with explanatory text and within the context of related data. Data can be filtered by cleanup program, geography, environmental indicators, controls, and cleanup stage. CIMC also provides some web services that integrate these data for others to use in their applications.

Spill at the Butler Tunnel in Pittston, PA. Hearing before the Subcommittee on Commerce, Transportation, and Tourism of the Committee on Energy and Commerce, House of Representatives, Ninety-Ninth Congress, First Session, October 23, 1985

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1986-01-01

Over 100,000 gallons of toxic waste entered the Susquehanna River when Hurricane Gloria flooded a Superfund cleanup site near Pittston, Pennsylvania. A hearing to investigate why cleanup had not been done at the site focused on the Butler Tunnel, an underground mine drainage tunnel, and its potential threat to area drinking water. Witnesses represented the Environmental Protection Agency (EPA), citizen groups, and the State of Pennsylvania. Their testimony emphasized the continuing danger and the fear and anger which residents were experiencing. EPA officials described past actions to correct the problem and plans for future remedial work. Additional correspondence and materialmore » submitted for the record follows the testimony of the 10 witnesses.« less

Determination of perfluorinated compounds in mollusks by matrix solid-phase dispersion and liquid chromatography-tandem mass spectrometry.

PubMed

Villaverde-de-Sáa, Eugenia; Quintana, José Benito; Rodil, Rosario; Ferrero-Refojos, Raúl; Rubí, Elisa; Cela, Rafael

2012-01-01

Perfluorinated compounds (PFCs) have been used for over 40 years in different commercial and industrial applications mainly as surfactants and surface protectors and have become an important class of marine emerging pollutants. This study presents the development and validation of a new analytical method to determine the simultaneous presence of eight PFCs in different kinds of mollusks using matrix solid-phase dispersion (MSPD) followed by liquid chromatography-tandem mass spectrometry (LC-MS/MS). Simplicity of the analytical procedure, low volume of solvent and quantity of sample required, low global price, and integration of extraction and clean-up into a single step, are the most important advantages of the developed methodology. Solvent, solid support (dispersing agent), clean-up sorbent, and their amounts were optimized by means of an experimental design. In the final method, 0.5 g of sample are dispersed with 0.2 g of diatomaceous earth and transferred into a polypropylene syringe containing 4 g of silica as clean-up sorbent. Then, analytes are eluted with 20 mL of acetonitrile. The extract is finally concentrated to a final volume of 0.5 mL in methanol, avoiding extract dryness in order to prevent evaporation losses and injected in the LC-MS/MS. The combination of this MSPD protocol with LC-MS/MS afforded detection limits from 0.05 to 0.3 ng g(-1). Also, a good linearity was established for the eight PFCs in the range from limit of quantification (LOQ) to 500 ng mL(-1) with R(2) > 0.9917. The recovery of the method was studied with three types of spiked mollusk and was in the 64-126% range. Moreover, a mussel sample was spiked and aged for more than 1 month and analyzed by the developed method and a reference method, ion-pair extraction, for comparison, producing both methods statistically equal concentration values. The method was finally applied to the determination of PFCs in different kinds of mollusks revealing concentrations up to 8.3 ng g(-1) for perfluoroundecanoic acid.

Air quality during demolition and recovery activities in post-Katrina New Orleans.

PubMed

Ravikrishna, Raghunathan; Lee, Han-Woong; Mbuligwe, Stephen; Valsaraj, K T; Pardue, John H

2010-07-01

Air samples were collected during demolition and cleanup operations in the Lakeview district of New Orleans, Louisiana, USA, in late 2005 during the period immediately after Hurricane Katrina. Three different high-volume air samples were collected around waste collection areas that were created to temporarily hold the debris from the cleanup of residential properties in the area. Particulate concentrations were elevated and included crystalline fibers associated with asbestos. Metal concentrations on particulate matter resembled those measured in sediments deposited by floodwaters with the exception of Ba, which was elevated at all three locations. The highest organic contaminant concentration measured on particulates was the pesticide Ziram (Zinc, bis[diethylcarbamodithioato-S,S']-, [T-4]-) at 2,200 microg/g of particulate matter during sampling period 2. Ziram is used in latex paint, adhesives, caulking, and wallboard as a preservative. Fungal isolates developed from particulate air samples included species associated with disease including Aspergillus and Penicillium species. These data represent the most comprehensive assessment of demolition activities during the period immediately after Hurricane Katrina. Copyright (c) 2010 SETAC.

PFB Coal Fired Combined Cycle Development Program. Advanced hot gas cleanup concept evaluation (Task 4. 3). Volume A. Aerodyne cyclone evaluation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

This report summarizes the results of testing of a rotary flow cyclone, manufactured by Aerodyne Development Corporation under license by Siemens Kraftwerk Union. This cyclone was selected for evaluation due to the unusually high separative efficiencies claimed by the manufacturer (based on developer data), and relative lack of open literature data. The most significant finding of this work was the observation that electrostatic forces could enhance or, in fact, dominate the separation process. Separative efficiencies, with electrostatic forces present, were found to be substantially independent of flow rate and, by inference, could be independent of unit size. Hence this findingmore » offers a major hope that large cyclones employed in the hot gas cleanup train of the CFCC system may not suffer the performance degradation compared to small cyclones, as projected from conventional inertial theory. The separative efficiencies of the Aerodyne cyclone separator were found from both the cold flow and the hot flow tests to be disappointingly poorer than expectations (in agreement with Westinghouse results), and even poorer than conventional cyclones. (LTN)« less

The ecological impact of land restoration and cleanup. Technical report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1978-08-01

The report is concerned with the ecological impacts of specific cleanup treatment on the land where they were carried out. The cleanup procedures given apply equally to chemical or radioactive materials. Guidance is provided for cleanup procedures likely to be suggested by government, industry, or environmental groups. The basic types of cleanup procedures for removing or deactiving spilled contamination involve moving people and animals from the affected area, scraping and grading the contaminated soil into windrows, plowing the contamination under, or digging up the contamination and hauling it away. The report describes and evaluates the various land-type cleanup effects inmore » terms of impact of the techniques on the environment. Part I defines several natural ecosystems and some of their natural derivations. Part II presents managed ecosystems which are imposed on natural ecosystems and are no longer bound by the initial native ecosystem balances. Part III deals with avion and mammilian wild life displaced by cleanup.« less

Greener Cleanups

EPA Pesticide Factsheets

OSWER’s goal is to reduce the environmental footprint of cleanup activities at contaminated sites to the maximum extent possible. This website shares policies, tools and practices to achieve that goal across cleanup programs.

Investing in International Information Exchange Activities to Improve the Safety, Cost Effectiveness and Schedule of Cleanup - 13281

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seed, Ian; James, Paula; Mathieson, John

2013-07-01

With decreasing budgets and increasing pressure on completing cleanup missions as quickly, safely and cost-effectively as possible, there is significant benefit to be gained from collaboration and joint efforts between organizations facing similar issues. With this in mind, the US Department of Energy (DOE) and the UK Nuclear Decommissioning Authority (NDA) have formally agreed to share information on lessons learned on the development and application of new technologies and approaches to improve the safety, cost effectiveness and schedule of the cleanup legacy wastes. To facilitate information exchange a range of tools and methodologies were established. These included tacit knowledge exchangemore » through facilitated meetings, conference calls and Site visits as well as explicit knowledge exchange through document sharing and newsletters. A DOE web-based portal has been established to capture these exchanges and add to them via discussion boards. The information exchange is operating at the Government-to-Government strategic level as well as at the Site Contractor level to address both technical and managerial topic areas. This effort has resulted in opening a dialogue and building working relationships. In some areas joint programs of work have been initiated thus saving resource and enabling the parties to leverage off one another activities. The potential benefits of high quality information exchange are significant, ranging from cost avoidance through identification of an approach to a problem that has been proven elsewhere to cost sharing and joint development of a new technology to address a common problem. The benefits in outcomes significantly outweigh the costs of the process. The applicability of the tools and methods along with the lessons learned regarding some key issues is of use to any organization that wants to improve value for money. In the waste management marketplace, there are a multitude of challenges being addressed by multiple organizations and the effective pooling and exchange of knowledge and experience can only be of benefit to all participants to help complete the cleanup mission more quickly and more cost effectively. This paper examines in detail the tools and processes used to promote information exchange and the progress made to date. It also discusses the challenges and issues involved and proposes recommendations to others who are involved in similar activities. (authors)« less

A digital approach to fabricating an abutment replica to control cement volume in a cement-retained implant prosthesis.

PubMed

Lee, Ju-Hyoung; Park, In-Sook; Sohn, Dong-Seok

2016-07-01

If a cement-retained implant prosthesis is placed on an abutment, excess cement should be minimized or removed to prevent periimplant inflammation. Various methods for fabricating an abutment replica have been introduced to maintain tissue health and reduce clean-up time. The purpose of this article is to present an alternative technique for fabricating an abutment replica with computer-aided design/computer-aided manufacturing (CAD/CAM) technology. Copyright © 2016 Editorial Council for the Journal of Prosthetic Dentistry. Published by Elsevier Inc. All rights reserved.

Voluntary Guidelines for Methamphetamine Laboratory Cleanup - Document

EPA Pesticide Factsheets

provides technical guidance for state and local personnel responsible for meth lab cleanup, based on an extensive review of the best available science and practices, and addresses general cleanup activities, specific items/materials, sampling.

Transformations of inorganic coal constituents in combustion systems. Volume 1, sections 1--5: Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Helble, J.J.; Srinivasachar, S.; Wilemski, G.

1992-11-01

The inorganic constituents or ash contained in pulverized coal significantly increase the environmental and economic costs of coal utilization. For example, ash particles produced during combustion may deposit on heat transfer surfaces, decreasing heat transfer rates and increasing maintenance costs. The minimization of particulate emissions often requires the installation of cleanup devices such as electrostatic precipitators, also adding to the expense of coal utilization. Despite these costly problems, a comprehensive assessment of the ash formation and had never been attempted. At the start of this program, it was hypothesized that ash deposition and ash particle emissions both depended upon themore » size and chemical composition of individual ash particles. Questions such as: What determines the size of individual ash particles? What determines their composition? Whether or not particles deposit? How combustion conditions, including reactor size, affect these processes? remained to be answered. In this 6-year multidisciplinary study, these issues were addressed in detail. The ambitious overall goal was the development of a comprehensive model to predict the size and chemical composition distributions of ash produced during pulverized coal combustion. Results are described.« less

Analysis of Nonvolatile Residue (NVR) from Spacecraft Systems

NASA Technical Reports Server (NTRS)

Colony, J. A.

1985-01-01

Organic contamination on critical spacecraft surfaces can cause electronic problems, serious attenuation of various optical signals, thermal control changes, and adhesion problems. Such contaminants can be detected early by the controlled use of witness mirrors, witness plates, wipe sampling, or direct solvent extraction. Each method requires careful control of variables of technique and materials to attain the ultimate sensitivities inherent to that procedure. Subsequent chemical analysis of the contaminant sample by infrared and mass spectrometry identifies the components, gives semiquantitative estimates of contaminant thickness, indicates possible sources of the nonvolatile residue (NVR), and provides guidance for effective cleanup procedures.

Corrective Action Sites around the Nation

EPA Pesticide Factsheets

Provide info to the public/community orgs, local officials & consultants on nearby corrective action cleanups, the status of the cleanup and future plans. Links to the Natl Corrective Action, Cleanups in My Community & Cleaning Up Our Land, Water & Air

Green Remediation Best Management Practices: Overview of EPA's Methodology to Address the Environmental Footprint of Site Cleanup

EPA Pesticide Factsheets

Contaminated site cleanups involving complex activities may benefit from a detailed environmental footprint analysis to inform decision-making about application of suitable best management practices for greener cleanups.

Military Base Realignments and Closures: DOD Has Improved Environmental Cleanup Reporting but Should Obtain and Share More Information

DTIC Science & Technology

2017-01-01

the property, put final cleanup remedies in place before the property is transferred. However, under some circumstances the services may conduct an...early transfer before cleanup has been completed. When remedies are in place for addressing the contamination of a former installation or the...cleanup at BRAC installations will significantly increase due to the high cost of remediating emerging contaminants, primarily perfluorooctane

Not ''just'' pump and treat

DOE Office of Scientific and Technical Information (OSTI.GOV)

Angleberger, K; Bainer, R W

2000-12-12

The Lawrence Livermore National Laboratory (LLNL) has been consistently improving the site cleanup methods by adopting new philosophies, strategies and technologies to address constrained or declining budgets, lack of useable space due to a highly industrialized site, and significant technical challenges. As identified in the ROD, the preferred remedy at the LLNL Livermore Site is pump and treat, although LLNL has improved this strategy to bring the remediation of the ground water to closure as soon as possible. LLNL took the logical progression from a pump and treat system to the philosophy of ''Smart Pump and Treat'' coupled with themore » concepts of ''Hydrostratigraphic Unit Analysis,'' ''Engineered Plume Collapse,'' and ''Phased Source Remediation,'' which led to the development of new, more cost-effective technologies which have accelerated the attainment of cleanup goals significantly. Modeling is also incorporated to constantly develop new, cost-effective methodologies to accelerate cleanup and communicate the progress of cleanup to stakeholders. In addition, LLNL improved on the efficiency and flexibility of ground water treatment facilities. Ground water cleanup has traditionally relied on costly and obtrusive fixed treatment facilities. LLNL has designed and implemented various portable ground water treatment units to replace the fixed facilities; the application of each type of facility is determined by the amount of ground water flow and contaminant concentrations. These treatment units have allowed for aggressive ground water cleanup, increased cleanup flexibility, and reduced capital and electrical costs. After a treatment unit has completed ground water cleanup at one location, it can easily be moved to another location for additional ground water cleanup.« less

The National LUST Cleanup Backlog: A Study of Opportunities

EPA Pesticide Factsheets

To understand the makeup of UST releases remaining and why the pace of cleanups is slowing, EPA undertook a two-phase, data-driven analysis of the cleanups remaining as of 2006 (Phase 1) and 2009 (Phase 2).

A Short Assessment of Select Remediation Issues at the Russian Research Center-Kurchatov Institute, Moscow, Russia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gephart, Roy E.

At the invitation of the National Academies, Roy Gephart traveled to Russia with an eight-member U.S. team during June, 2008 to participate in a workshop hosted by the National Academies and the Russian Academy of Sciences on radiation contamination and remediation issues in the former Soviet Union. Cleanup problems were assessed by the American participants for six Russian sites: Kurchatov Institute, Lakes 10 and 11 at Mayak, Andreev Bay, Krasnokamensk Mining Enterprise (Siberia), Almaz Mining Enterprise (North Caucasus), and one site for testing peaceful nuclear explosions. Roy lead the Russian Research Center-Kurchatov Institute review session and wrote an assessment ofmore » key cleanup issues. Kurchatov is the leading institute in the Former Soviet Union devoted to military and civilian nuclear programs. Founded in 1943 in the outskirts of Moscow, this 100 hectare site of nearly undeveloped, prime real estate is now surrounded by densely populated urban and business districts. Today there are growing concerns over the public safety and environmental security of the site resulting from increasingly obsolete nuclear facilities and a legacy of inadequate waste management practices that resulted in contaminant releases and challenging remediation problems. In addition, there is growing concern over the presence of nuclear facilities within urban areas creating potential targets for terrorist attacks.« less

Environmental Management Science Program Workshop. Proceedings

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

1998-07-01

The Department of Energy Office of Environmental Management (EM), in partnership with the Office of Energy Research (ER), designed, developed, and implemented the Environmental Management Science Program as a basic research effort to fund the scientific and engineering understanding required to solve the most challenging technical problems facing the government's largest, most complex environmental cleanup program. The intent of the Environmental Management Science Program is to: (1) Provide scientific knowledge that will revolutionize technologies and cleanup approaches to significantly reduce future costs, schedules, and risks. (2) Bridge the gap between broad fundamental research that has wide-ranging applications such as thatmore » performed in the Department's Office of Energy Research and needs-driven applied technology development that is conducted in Environmental Management's Office of Science and Technology. (3) Focus the nation's science infrastructure on critical Department of Energy environmental problems. In an effort to share information regarding basic research efforts being funded by the Environmental Management Science Program and the Environmental Management/Energy Research Pilot Collaborative Research Program (Wolf-Broido Program), this CD includes summaries for each project. These project summaries, available in portable document format (PDF), were prepared in the spring of 1998 by the principal investigators and provide information about their most recent project activities and accomplishments.« less

Removal of Lipid from Serum Increases Coherence between Brucellosis Rapid Agglutination Test and Enzyme-linked Immunosorbent Assay in Bears in Alaska, USA.

PubMed

Godfroid, Jacques; Beckmen, Kimberlee; Helena Nymo, Ingebjørg

2016-10-01

In cases of chronic Brucella spp. infection, results of the rose bengal plate test (RBPT) and indirect enzyme-linked immunosorbent assay (ELISA) should be coherent, as reported in controlled conditions in the literature. We compared RBPT and ELISA results in 58 Alaska grizzly bears ( Ursus arctos horribilis), eight Kodiak brown bears ( Ursus arctos middendorffi), and six Alaska Peninsula brown bears ( Ursus arctos gyas). Of the 72 bears tested, 42 (58%) were ELISA positive and 53 (73%) were RBPT positive. However, the coherence between the tests was only fair (K=0.37, SE=0.11), suggesting that either the serologic results were not compatible with Brucella spp. infection or that there was a technical problem with the tests. To address a potential technical problem, we performed a 30-min chloroform/centrifugation cleanup. Following cleanup, the ELISA identified 43 positives (59%) and the RBPT identified 47 (65%), and the coherence between the tests was much improved (K=0.80, SE=0.07). We recommend cleaning wildlife sera with a high lipid content before performing RBPT and performing RBPT and ELISA in parallel to assess coherence. Our results suggest that Alaskan brown bears have been exposed to Brucella spp.

Central Plateau Cleanup at DOE's Hanford Site - 12504

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dowell, Jonathan

The discussion of Hanford's Central Plateau includes significant work in and around the center of the Hanford Site - located about 7 miles from the Columbia River. The Central Plateau is the area to which operations will be shrunk in 2015 when River Corridor cleanup is complete. This work includes retrieval and disposal of buried waste from miles of trenches; the cleanup and closure of massive processing canyons; the clean-out and demolition to 'slab on grade' of the high-hazard Plutonium Finishing Plant; installation of key groundwater treatment facilities to contain and shrink plumes of contaminated groundwater; demolition of all othermore » unneeded facilities; and the completion of decisions about remaining Central Plateau waste sites. A stated goal of EM has been to shrink the footprint of active cleanup to less than 10 square miles by 2020. By the end of FY2011, Hanford will have reduced the active footprint of cleanup by 64 percent exceeding the goal of 49 percent. By 2015, Hanford will reduce the active footprint of cleanup by more than 90 percent. The remaining footprint reduction will occur between 2015 and 2020. The Central Plateau is a 75-square-mile region near the center of the Hanford Site including the area designated in the Hanford Comprehensive Land Use Plan Environmental Impact Statement (DOE 1999) and Record of Decision (64 FR 61615) as the Industrial-Exclusive Area, a rectangular area of about 20 square miles in the center of the Central Plateau. The Industrial-Exclusive Area contains the 200 East and 200 West Areas that have been used primarily for Hanford's nuclear fuel processing and waste management and disposal activities. The Central Plateau also encompasses the 200 Area CERCLA National Priorities List site. The Central Plateau has a large physical inventory of chemical processing and support facilities, tank systems, liquid and solid waste disposal and storage facilities, utility systems, administrative facilities, and groundwater monitoring wells. As a companion to the Hanford Site Cleanup Completion Framework document, DOE issued its draft Central Plateau Cleanup Completion Strategy in September 2009 to provide an outline of DOE's vision for completion of cleanup activities across the Central Plateau. As major elements of the Hanford cleanup along the Columbia River Corridor near completion, DOE believed it appropriate to articulate the agency vision for the remainder of the cleanup mission. The Central Plateau Cleanup Completion Strategy and the Hanford Site Cleanup Completion Framework were provided to the regulatory community, the Tribal Nations, political leaders, the public, and Hanford stakeholders to promote dialogue on Hanford's future. The Central Plateau Cleanup Completion Strategy describes DOE's vision for completion of Central Plateau cleanup and outlines the decisions needed to achieve the vision. The Central Plateau strategy involves steps to: (1) contain and remediate contaminated groundwater, (2) implement a geographic cleanup approach that guides remedy selection from a plateau-wide perspective, (3) evaluate and deploy viable treatment methods for deep vadose contamination to provide long-term protection of the groundwater, and (4) conduct essential waste management operations in coordination with cleanup actions. The strategy will also help optimize Central Plateau readiness to use funding when it is available upon completion of River Corridor cleanup projects. One aspect of the Central Plateau strategy is to put in place the process to identify the final footprint for permanent waste management and containment of residual contamination within the 20-square-mile Industrial-Exclusive Area. The final footprint identified for permanent waste management and containment of residual contamination should be as small as practical and remain under federal ownership and control for as long as a potential hazard exists. Outside the final footprint, the remainder of the Central Plateau will be available for other uses consistent with the Hanford Comprehensive Land-Use Plan (DOE 1999), while maintained under federal ownership and control. (author)« less

[Relationship between atmospheric particles and rain water chemistry character].

PubMed

Huo, Ming-Qun; Sun, Qian; Xie, Peng; Bai, Yu-Hua; Liu, Zhao-Rong; Li, Ji-Long; Lu, Si-Hua

2009-11-01

Rain and atmospheric particle samples were collected in the rural area of Taian and Shenzhen in 2007, respectively. Rain sampling was carried out during the precipitation process and several samples were got from the beginning of one precipitation to the end. The chemical character changes during precipitation and the changes of concentration of particles before and after rain were studied in this research to understand the contribution of particles on the rain chemical character and the rain-out effect for particles. The volume-weighted mean pH of rainwater in Taian was 5.97 and the total concentration of ions was 1 187.96 microeq x L(-1). The mass concentration of PM10 in Taian was 131.76 microg/m3 and that of PM2.5 was 103.84 microg/m3. The volume-weighted mean pH of rainwater in Shenzhen was 4.72 and the total concentration of ions was 175.89 microeq x L(-1). The mass concentration of PM10 in Shenzhen was 56.66 microg/m3 and that of PM2.5 was 41.52 microg/m3. During precipitation process pH and ion concentration of rain decrease and it is shown the neutralizing effect happens. The difference between rainwater of Taian and Shenzhen is due to cloud water acidity, atmospheric particles character and atmospheric acid-basic gases concentration. The clean-up effect of Na+ and Ca2+ by rain is high and which of NH4+ and NO3- is low. The clean-up effect for mass concentration, ions concentration and element concentration of particles by rain are significant.

ENERGY CONSERVATION AND PRODUCTION AT WASTE CLEANUP SITES (ISSUE PAPER)

EPA Science Inventory

Saving energy used by hazardous waste cleanup remediation systems should interest those people working on waste cleanup sites. Presidential Executive Order 13123, "Greening the Government Through Efficient Energy Management", states that each agency shall strive to expand the us...

Brownfields Grants Information

EPA Pesticide Factsheets

This asset includes all types of information regarding Brownfields grant programs that subsidize/support Brownfield cleanup. This includes EPA's Brownfields Program grant funding for brownfields assessment, cleanup, revolving loans, and environmental job training. Assessment grants provide funding for a grant recipient to inventory, characterize, assess, and conduct planning and community involvement related to brownfield sites. Revolving Loan Fund Grants enable States, political subdivisions, and Indian tribes to make low interest loans to carryout cleanup activities at brownfields properties. Cleanup grants provide funding for a grant recipient to carry out cleanup activities at brownfield sites. Environmental Workforce Development and Job Training Grants are designed to provide funding to eligible entities, including nonprofit organizations, to recruit, train, and place predominantly low-income and minority, unemployed and under-employed residents of solid and hazardous waste-impacted communities with the skills needed to secure full-time, sustainable employment in the environmental field and in the assessment and cleanup work taking place in their communities. Training, Research, and Technical Assistance Grants provide funding to eligible organizations to provide training, research, and technical assistance to facilitate brownfields cleanup. Regulatory authority for the collection and use of this information is found in the Small Business Liability Relief

DOE Office of Scientific and Technical Information (OSTI.GOV)

Flynn, Karen; McCormick, Matt

Hanford's DOE offices are responsible for one of the largest nuclear cleanup efforts in the world, cleaning up the legacy of nearly five decades of nuclear weapons production. Nowhere in the DOE Complex is cleanup more challenging than at the Hanford Site in southeastern Washington. Hanford cleanup entails remediation of hundreds of large complex hazardous waste sites; disposition of nine production reactors and the preservation of one as a National Historic Landmark; demolition of hundreds of contaminated facilities including five enormous process canyons; remediation of billions of gallons of contaminated groundwater; disposition of millions of tons of low-level, mixed low-level,more » and transuranic waste; disposition of significant quantities of special nuclear material; storage and ultimate disposition of irradiated nuclear fuel; remediation of contamination deep in the soil that could impact groundwater; decontamination and decommissioning of hundreds of buildings and structures; and treatment of 56 million gallons of radioactive waste in 177 large underground tanks through the construction of a first-of-its-kind Waste Treatment Plant. Cleanup of the Hanford Site is a complex and challenging undertaking. The DOE Richland Operations Office has a vision and a strategy for completing Hanford's cleanup including the transition to post-cleanup activities. Information on the strategy is outlined in the Hanford Site Completion Framework. The framework describes three major components of cleanup - River Corridor, Central Plateau, and Tank Waste. It provides the context for individual cleanup actions by describing the key challenges and approaches for the decisions needed to complete cleanup. The U.S. Department of Energy (DOE), as regulated by the U.S. Environmental Protection Agency (EPA) and Washington State Department of Ecology (Ecology), is implementing a strategy to achieve final cleanup decisions for the River Corridor portion of the Hanford Site. The DOE Richland Operations Office (RL) and DOE Office of River Protection (ORP) have prepared this document to describe the strategy and to begin developing the approach for making cleanup decisions for the remainder of the Hanford Site. DOE's intent is that the Completion Framework document will facilitate dialogue among the Tri-Parties and with Hanford's diverse interest groups, including Tribal Nations, State of Oregon, Hanford Advisory Board, Natural Resource Trustees, and the public. Future cleanup decisions will be enhanced by an improved understanding of the challenges facing cleanup and a common understanding of the goals and approaches for cleanup completion. The overarching goals for cleanup are sevenfold. - Goal 1: Protect the Columbia River. - Goal 2: Restore groundwater to its beneficial use to protect human health, the environment, and the Columbia River. - Goal 3: Clean up River Corridor waste sites and facilities to: Protect groundwater and the Columbia River. Shrink the active cleanup footprint to the Central Plateau, and support anticipated future uses of the land. - Goal 4: Clean up Central Plateau waste sites, tank farms, and facilities to: Protect groundwater. Minimize the footprint of areas requiring long-term waste management activities. Support anticipated future uses of the land. - Goal 5: Safely manage and transfer legacy materials scheduled for off-site disposition including special nuclear material (including plutonium), spent nuclear fuel, transuranic waste, and immobilized high-level waste. - Goal 6: Consolidate waste treatment, storage, and disposal operations on the Central Plateau. - Goal 7: Develop and implement institutional controls and long-term stewardship activities that protect human health, the environment, and Hanford's unique cultural, historical and ecological resources after cleanup activities are completed. These goals embody more than 20 years of dialogue among the Tri-Party Agencies, Tribal Nations, State of Oregon, stakeholders, and the public. They carry forward key values captured in forums such as the Hanford Future Site Uses Working Group, Tank Waste Task Force, Hanford Summits, and Hanford Advisory Board Exposure Scenario Workshops, as well as more than 200 advice letters issued by the Hanford Advisory Board (http://www.hanford.gov/page.cfm/hab). These goals help guide all aspects of Hanford Site cleanup. Cleanup activities at various areas of the site support the achievement of one or more of these goals. These goals help set priorities to apply resources and sequence cleanup efforts for the greatest benefit. These goals reflect DOE's recognition that the Columbia River is a critical resource for the people and ecology of the Pacific Northwest. The 50-mile stretch of the river known as the Hanford Reach is home to the last free-flowing section of the river in the U.S. As one of the largest rivers in North America, its waters support a multitude of uses that are vital to the economic and environmental well being of the region and it is particularly important in sustaining the culture of Native Americans. Cleanup actions must protect this river. (authors)« less

Remediation System Design Optimization: Field Demonstration at the Umatilla Army Deport

NASA Astrophysics Data System (ADS)

Zheng, C.; Wang, P. P.

2002-05-01

Since the early 1980s, many researchers have shown that the simulation-optimization (S/O) approach is superior to the traditional trial-and-error method for designing cost-effective groundwater pump-and-treat systems. However, the application of the S/O approach to real field problems has remained limited. This paper describes the application of a new general simulation-optimization code to optimize an existing pump-and-treat system at the Umatilla Army Depot in Oregon, as part of a field demonstration project supported by the Environmental Security Technology Certification Program (ESTCP). Two optimization formulations were developed to minimize the total capital and operational costs under the current and possibly expanded treatment plant capacities. A third formulation was developed to minimize the total contaminant mass of RDX and TNT remaining in the shallow aquifer by the end of the project duration. For the first two formulations, this study produced an optimal pumping strategy that would achieve the cleanup goal in 4 years with a total cost of 1.66 million US dollars in net present value. For comparison, the existing design in operation was calculated to require 17 years for cleanup with a total cost of 3.83 million US dollars in net present value. Thus, the optimal pumping strategy represents a reduction of 13 years in cleanup time and a reduction of 56.6 percent in the expected total expenditure. For the third formulation, this study identified an optimal dynamic pumping strategy that would reduce the total mass remaining in the shallow aquifer by 89.5 percent compared with that calculated for the existing design. In spite of their intensive computational requirements, this study shows that the global optimization techniques including tabu search and genetic algorithms can be applied successfully to large-scale field problems involving multiple contaminants and complex hydrogeological conditions.

Hazardous Waste: Cleanup and Prevention.

ERIC Educational Resources Information Center

Vandas, Steve; Cronin, Nancy L.

1996-01-01

Discusses hazardous waste, waste disposal, unsafe exposure, movement of hazardous waste, and the Superfund clean-up process that consists of site discovery, site assessment, clean-up method selection, site clean up, and site maintenance. Argues that proper disposal of hazardous waste is everybody's responsibility. (JRH)

HANDBOOK ON THE BENEFITS, COSTS, AND IMPACTS OF LAND CLEANUP AND REUSE

EPA Science Inventory

Summarizes the theoretical and empirical literature addressing benefit-cost and impact assessment of the land cleanup and reuse scenario. When possible, recommendations are provided for conducting economic analysis of land cleanup and reuse sites and programs. The knowledge base ...

Analysis of state Superfund programs: 50 state study. 1998 update

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

States have remediated over 40,000 contaminated sites not on the federal Superfund list. ELI`s latest analysis of state Superfund programs examines the cleanup programs of all 50 states, Puerto Rico, and the District of Columbia. The study provides the most current data on state statutes, program organization, staffing, funding, expenditures, cleanup standards, and cleanup activities, voluntary cleanup programs and brownfields programs. State and federal policymakers and attorneys working on non-NPL sites should find this study useful.

Evaluation of surface roughness of enamel after various bonding and clean-up procedures on enamel bonded with three different bonding agents: An in-vitro study

PubMed Central

Goel, Amit; Singh, Atul; Gupta, Tarun

2017-01-01

Background The purpose of this study was to analyze and compare the enamel surface roughness before bonding and after debonding, to find correlation between the adhesive remnant index and its effect on enamel surface roughness and to evaluate which clean-up method is most efficient to provide a smoother enamel surface. Material and Methods 135 premolars were divided into 3 groups containing 45 premolars in each group. Group I was bonded by using moisture insensitive primer, Group II by using conventional orthodontic adhesive and Group III by using self-etching primer. Each group was divided into 3 sub-groups on the basis of type of clean-up method applied i,e scaling followed by polishing, tungsten carbide bur and Sof-Lex disc. Enamel surface roughness was measured and compared before bonding and after clean-up. Results Evaluation of pre bonding and post clean-up enamel surface roughness (Ra value) with the t test showed that Post clean-up Ra values were greater than Pre bonding Ra values in all the groups except in teeth bonded with self-etching primer cleaned with Sof-Lex disc. Reliability of ARI score taken at different time interval tested with Kruskal Wallis test suggested that all the readings were reliable. Conclusions No clean-up procedure was able to restore the enamel to its original smoothness. Self-etching primer and Sof-Lex disc clean-up method combination restored the enamel surface roughness (Ra value) closest to its pre-treatment value. Key words:Enamel surface roughness, clean-up method, adhesive remnant index. PMID:28512535

Review of State Soil Cleanup Levels for Dioxin (December 2009)

EPA Science Inventory

This final report summarizes a survey of state soil cleanup levels for dioxin and characterizes the science underlying these values. The objective of this project was to summarize existing state cleanup levels for dioxin in soil, together with their scientific bases where availa...

40 CFR 312.25 - Searches for recorded environmental cleanup liens.

Code of Federal Regulations, 2010 CFR

2010-07-01

... cleanup liens. 312.25 Section 312.25 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SUPERFUND, EMERGENCY PLANNING, AND COMMUNITY RIGHT-TO-KNOW PROGRAMS INNOCENT LANDOWNERS, STANDARDS FOR... cleanup liens. (a) All appropriate inquiries must include a search for the existence of environmental...

Successful implementation of property cleanup under the Ohio and the Texas voluntary programs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Roffman, A.

1999-07-01

Cleanups of two properties, one located in Ohio and the other in Texas were successfully implemented. The facilities were printing plants that manufactured printed material and forms for commercial and industrial use. Primary products and chemicals involved in the manufacturing of the forms included ink, petroleum products and cleaning solvents. The Ohio property underwent a successful cleanup under the Ohio EPA Voluntary Action Program (VAP). It met the Ohio EPA residential land use cleanup standards for soil and shallow groundwater. A No Further Action letter has been submitted to the state and it resulted in the issuance of a Covenantmore » Not to Sue. The Texas facility underwent a successful cleanup under the Texas Natural Resource Conservation Commission (TNRCC) Voluntary Cleanup Program (VCP). It resulted in the issuance of a Certificate of Completion (COC) for residential land use for soil, and a conditional COC for industrial land use for the shallow groundwater.« less

Liquid secondary waste. Waste form formulation and qualification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cozzi, A. D.; Dixon, K. L.; Hill, K. A.

The Hanford Site Effluent Treatment Facility (ETF) currently treats aqueous waste streams generated during Site cleanup activities. When the Hanford Tank Waste Treatment and Immobilization Plant (WTP) begins operations, a liquid secondary waste (LSW) stream from the WTP will need to be treated. The volume of effluent for treatment at the ETF will increase significantly. Washington River Protection Solutions is implementing a Secondary Liquid Waste Immobilization Technology Development Plan to address the technology needs for a waste form and solidification process to treat the increased volume of waste planned for disposal at the Integrated Disposal Facility IDF). Waste form testingmore » to support this plan is composed of work in the near term to demonstrate the waste form will provide data as input to a performance assessment (PA) for Hanford’s IDF.« less

Predictable pollution: an assessment of weather balloons and associated impacts on the marine environment--an example for the Great Barrier Reef, Australia.

PubMed

O'Shea, Owen R; Hamann, Mark; Smith, Walter; Taylor, Heidi

2014-02-15

Efforts to curb pollution in the marine environment are covered by national and international legislation, yet weather balloons are released into the environment with no salvage agenda. Here, we assess impacts associated with weather balloons in the Great Barrier Reef World Heritage Area (GBRWHA). We use modeling to assess the probability of ocean endpoints for released weather balloons and predict pathways post-release. In addition, we use 21 months of data from beach cleanup events to validate our results and assess the abundance and frequency of weather balloon fragments in the GBRWHA. We found between 65% and 70% of balloons land in the ocean and ocean currents largely determine final endpoints. Beach cleanup data revealed 2460 weather balloon fragments were recovered from 24 sites within the GBRWHA. This is the first attempt to quantify this problem and these data will add support to a much-needed mitigation strategy for weather balloon waste. Copyright © 2013 Elsevier Ltd. All rights reserved.

Environmental restoration and waste management: Five-year plan, Fiscal Years 1992--1996

DOE Office of Scientific and Technical Information (OSTI.GOV)

Middleman, L.I.

1990-06-01

This document reflects DOE's fulfillment of a major commitment of the Environmental Restoration and Waste Management Five-Year Plan: reorganization to create an Office of Environmental Restoration and Waste Management (EM) responsible for the consolidated environmental management of nuclear-related facilities and sites formerly under the Assistant Secretaries for Defense Programs and Nuclear Energy and the Director of the Office of Energy Research. The purposes of this Plan for FY 1992--1996 are to measure progress in meeting DOE's compliance, cleanup, and waste management agenda; to incorporate a revised and condensed version of the Draft Research Development, Demonstration, Testing, and Evaluation (RDDT E)more » Plan (November 1989) to describe DOE's process for developing the new technologies critically needed to solve its environmental problems; to show DOE's current strategy and planned activities through FY 1996, including reasons for changes required to meet compliance and cleanup commitments; and to increase the involvement of other agencies and the public in DOE's planning.« less

48 CFR 49.105-4 - Cleanup of construction site.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 48 Federal Acquisition Regulations System 1 2010-10-01 2010-10-01 false Cleanup of construction site. 49.105-4 Section 49.105-4 Federal Acquisition Regulations System FEDERAL ACQUISITION REGULATION CONTRACT MANAGEMENT TERMINATION OF CONTRACTS General Principles 49.105-4 Cleanup of construction site. In...

One-step selective electrokinetic removal of inorganic anions from small volumes and its application as sample clean-up for mass spectrometric techniques.

PubMed

Tubaon, Ria Marni; Haddad, Paul R; Quirino, Joselito P

2017-03-10

The presence of inorganic anions in a sample interferes with mass spectrometric (MS) analysis. Here, a simple method to remove these ions from a liquid sample in one-step is described. The inorganic anions present in a 50μL sample were extracted into a low pH solution inside a 200μm i.d.×33cm long capillary by the use of an electric field. The selective removal of unwanted anions and retention of target analytes was accomplished by control of the apparent electrophoretic velocities of anions and analytes at a boundary that separated the sample and extraction solution. No physical barrier (e.g., membrane) was required and with the boundary situated at the tip of the capillary, efficient removal of inorganic anions (e.g., >80% removal) and good recovery of target analytes (e.g., >80% recovery) were achieved. The time required for removal of the inorganic anions was found to depend on their initial concentrations. The removal process was investigated using different concentrations of bromide and nitrate (as potassium salts) and negatively chargeable drugs as target analytes. This micro-sample clean-up technique used no organic solvents and little consumables and was studied to the determination of 0.6μg/L arsenic and 8.3μg/L vanadium in 500mg/L sodium chloride using inductively coupled plasma MS and 50μM angiotensin I in 1000mg/L sodium chloride using electrospray ionisation MS. Micro-sample clean-up was performed for 45min at 3kV in both demonstrations. The calculated recoveries for the metals at trace levels were 110-130%, and for the peptide was 103.8%. Copyright © 2017 Elsevier B.V. All rights reserved.

Analysis of polycyclic aromatic hydrocarbons extracted from air particulate matter using a temperature programmable injector coupled to GC-C-IRMS.

PubMed

Mikolajczuk, Agnieszka; Przyk, Elzbieta Perez; Geypens, Benny; Berglund, Michael; Taylor, Philip

2010-03-01

Compound specific isotopic analysis (CSIA) can provide information about the origin of analysed compounds - in this case, polycyclic aromatic hydrocarbons (PAHs). In the study, PAHs were extracted from three dust samples: winter and summer filter dust and tunnel dust. The measurement was performed using the method validated in our laboratory using pure, solid compounds and EPA 610 reference assortment. CSIA required an appropriate clean-up method to avoid an unresolved complex in the gas chromatographic analysis usually found in the chromatography of PAHs. Extensive sample clean-up for this particular matrix was found to be necessary to obtain good gas chromatography-combustion-isotope ratio mass spectrometry analysis results. The sample purification method included two steps in which the sample is cleaned up and the aliphatic and aromatic hydrocarbons are separated. The concentration of PAHs in the measured samples was low; so a large volume injection technique (100 microl) was applied. The delta(VPDB)(13)C was measured with a final uncertainty smaller than 1 per thousand. Comparison of the delta(VPDB)(13)C signatures of PAHs extracted from different dust samples was feasible with this method and, doing so, significant differences were observed.

Combined extraction-cleanup column chromatographic procedure for determination of dicofol in avian eggs

USGS Publications Warehouse

Krynitsky, A.J.; Stafford, C.J.; Wiemeyer, Stanley N.

1988-01-01

Dicofol in avian eggs was completely oxidized to dichlorobenzophenone (DCBP) when a hexane Soxhlet extraction procedure was used. This degradation did not occur with other avian tissues (muscle and liver). For this reason, a combined extraction-cleanup column chromatographic procedure, without added heat, was developed for the determination of dicofol in avian eggs. Homogenized subsamples of eggs were mixed with sodium sulfate, and the mixture was added as the top layer on a column prepacked with Florisil. The dicofol and other compounds of interest were then eluted with ethyl ether-hexane. The extracts, relatively free from lipids, were quantitated on a gas chromatograph equipped with a 63Ni electron-capture detector and a methyl silicone capillary column. Recoveries from chicken eggs, fortified with dicofol and other DDT-related compounds, averaged 96%. Analysis of eggs of eastern screech-owls, fed a meat diet containing 10 ppm technical Kelthane, showed that both dicofol and DCBP were present. Results were confirmed by gas chromatography/mass spectrometry. This method is rapid and reliable, involves a minimum of sample handling, and is well suited for high volume determination of dicofol in eggs and other avian tissues.

Performance Analysis of Cofiring Densified Refuse Derived Fuel in a Military Boiler.

DTIC Science & Technology

1981-12-01

Derived Fuel 70 Design Considerations for Municipal Solid Waste Conveyors 71 Densification of Refuse -Derived Fuels: Preparation Properties and Systems...problems could be realized if the system were expanded and if operating demands were increased. 70 DESIGN CONSIDERATIONS FOR MUNICIPAL SOLID WASTE CONVEYORS ...cleanup might be very useful in order to determine the level at which a conveyor design is monetarily accep~table. A scan of conveying technologies for

Application of Modern Coal Technologies to Military Facilities. Volume II. Evaluation of the Applicability and Cost of Current and Emerging Coal Technologies for the Utilization of Coal as a Primary Energy Source

DTIC Science & Technology

1968-05-01

flue gas . Is one. The more popular method Is wet limestone scrubbing. In the limestone Injection system, ground limestone Is mixed with the coal and...is removed. The remainder must be eliminated from the flue gas as SO2 by wet scrubbing. Reduced boiler efficiency, due to ash accumulation on the...use of the fluldlzed-bed boiler, rather than a conventional coal-fired boiler requiring a flue gas cleanup system, will result In an

30 CFR 75.400-2 - Cleanup program.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Cleanup program. 75.400-2 Section 75.400-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-2 Cleanup...

30 CFR 75.400-2 - Cleanup program.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Cleanup program. 75.400-2 Section 75.400-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-2 Cleanup...

30 CFR 75.400-2 - Cleanup program.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Cleanup program. 75.400-2 Section 75.400-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-2 Cleanup...

30 CFR 75.400-2 - Cleanup program.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Cleanup program. 75.400-2 Section 75.400-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-2 Cleanup...

30 CFR 75.400-2 - Cleanup program.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Cleanup program. 75.400-2 Section 75.400-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-2 Cleanup...

Water-Based Pressure-Sensitive Paints

NASA Technical Reports Server (NTRS)

Jordan, Jeffrey D.; Watkins, A. Neal; Oglesby, Donald M.; Ingram, JoAnne L.

2006-01-01

Water-based pressure-sensitive paints (PSPs) have been invented as alternatives to conventional organic-solvent-based pressure-sensitive paints, which are used primarily for indicating distributions of air pressure on wind-tunnel models. Typically, PSPs are sprayed onto aerodynamic models after they have been mounted in wind tunnels. When conventional organic-solvent-based PSPs are used, this practice creates a problem of removing toxic fumes from inside the wind tunnels. The use of water-based PSPs eliminates this problem. The waterbased PSPs offer high performance as pressure indicators, plus all the advantages of common water-based paints (low toxicity, low concentrations of volatile organic compounds, and easy cleanup by use of water).

The green clean: The emerging field of phytoremediation takes root

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brown, K.S.

1995-10-01

A few plants can biologically accumulate toxic metals from surrounding soils, a situation that could revolutionize environmental cleanup. By breeding a planting metal-munchers like alpine pennycress, scientist plan to clease waste zones of toxic levels of zinc, nickel and lead. From soil loaded with metal to radionuclide-laden water, researcher hope phytoremediation will provide a cheap way to clean man-made messes at mining, nuclear, and industrial sites. This article describes developments in the area of phytoremediation, including sections on plants called hyperaccumulators, how phytoremediators function, problems transferring phytoremediators from hydroculture to soils and problems which might prevent use of phytoremediators.

Solutions Network Formulation Report. Landsat Data Continuity Mission Simulated Data Products for Bureau of Land Management and Environmental Protection Agency Abandoned Mine Lands Decision Support

NASA Technical Reports Server (NTRS)

Estep, Leland

2007-01-01

Presently, the BLM (Bureau of Land Management) has identified a multitude of abandoned mine sites in primarily Western states for cleanup. These sites are prioritized and appropriate cleanup has been called in to reclaim the sites. The task is great in needing considerable amounts of agency resources. For instance, in Colorado alone there exists an estimated 23,000 abandoned mines. The problem is not limited to Colorado or to the United States. Cooperation for reclamation is sought at local, state, and federal agency level to aid in identification, inventory, and cleanup efforts. Dangers posed by abandoned mines are recognized widely and will tend to increase with time because some of these areas are increasingly used for recreation and, in some cases, have been or are in the process of development. In some cases, mines are often vandalized once they are closed. The perpetrators leave them open, so others can then access the mines without realizing the danger posed. Abandoned mine workings often fill with water or oxygen-deficient air and dangerous gases following mining. If the workings are accidentally entered into, water or bad air can prove fatal to those underground. Moreover, mine residue drainage negatively impacts the local watershed ecology. Some of the major hazards that might be monitored by higher-resolution satellites include acid mine drainage, clogged streams, impoundments, slides, piles, embankments, hazardous equipment or facilities, surface burning, smoke from underground fires, and mine openings.

US DOE Perspectives on Advisory Board Effectiveness - 13539

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adler, David

2013-07-01

Federal missions on the Oak Ridge Reservation began with the Manhattan Project, and continues today with major facilities supporting the Nation's Science and National Security missions. While most of the land area on the Oak Ridge Reservation is free of environmental impacts from these activities, significant legacy contamination is associated with specific facilities and past waste management areas. In 1989, the Oak Ridge Reservation (ORR) was placed on National Priorities List, and DOE established its Office of Environmental Management that same year. Three years later, in 1992, the Federal Facility Agreement for the reservation was signed. Three years afterward, themore » Oak Ridge Site Specific Advisory Board was established to augment ongoing public involvement activities related to Oak Ridge Reservation cleanup activities. One of the early and most impactful decisions the board made was to organize the End Use Working Group. This broad-based group of board members, DOE representatives, and members of the public was formed in 1997 to study future uses for contaminated areas of the reservation. The group was instrumental in building consensus in the Oak Ridge community regarding the long-term end state of reservation lands. The group's recommendations were a fundamental input into Record's of Decision subsequently developed to establish cleanup requirements across the ORR, and they continue to influence decisions being made today. In developing its recommendations on end states, the End Use Working Group came to the realization that long-term stewardship of contaminated areas of the reservation would be necessary, in some cases in perpetuity. It was from this concept that the Oak Ridge SSAB's 15-year involvement in stewardship would begin. A stewardship committee formed by the End Use Working Group wrote Volume 1 of the Stakeholder Report on Stewardship. This document-and its companion Volume 2, which was written a year later-form a crucial foundation for stewardship planning in Oak Ridge and have been referenced around the DOE complex as other sites consider stewardship planning. From these two broad-based initiatives, the board's focus has evolved to increasingly hone in on more specific, project-based recommendations and initiatives. The Oak Ridge Reservation Site Specific Advisory Board has been a highly effective forum for soliciting community input on Oak Ridge Reservation cleanup. Experience in Oak Ridge indicates that the utility of Board recommendations is far higher when the Board is asked to focus on broad programmatic issues, and less useful when the Board attempts to provide advice and recommendations on matters related to technical or project management issues. In Oak Ridge the Board has helped shape the program on many levels including definition of end-state cleanup objectives, budget development, program sequencing, waste management, and decisions concerning preservation of history related to missions implemented on the Oak Ridge Reservation. (authors)« less

78 FR 50447 - Agency Information Collection Activities; Submission for OMB Review; Comment Request; Cleanup...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-19

... for OMB Review; Comment Request; Cleanup Program for Accumulations of Coal and Float Coal Dusts, Loose Coal, and Other Combustibles ACTION: Notice. SUMMARY: The Department of Labor (DOL) is submitting the... (ICR) proposal; titled, ``Cleanup Program for Accumulations of Coal and Float Coal Dusts, Loose Coal...

Brownfields to School Sites: How Can the State Facilitate Cleanup To Build Essential Schools?

ERIC Educational Resources Information Center

California State Legislature, Sacramento. Select Committee on Environmental Justice.

This document presents background information and testimony concerning the cleanup of potentially contaminated vacant or underutilized property for use as future school sites in low-income and minority communities. Various proposals are offered that would allow the state, where necessary, to facilitate the cleanup of these "brownfields"…

75 FR 76280 - Regulated Navigation Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-12-08

.../ Tideflats superfund cleanup remediation efforts. This RNA will prohibit activities that would disturb the.../Tideflats superfund cleanup remediation process in those waters. These caps consist of approximately three... remediation efforts of the U.S. Environmental Protection Agency (EPA) and others in the Thea Foss and Wheeler...

40 CFR 761.125 - Requirements for PCB spill cleanup.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) Additional pre- or post-cleanup sampling. (B) The estimated cost of the cleanup by man-hours, dollars, or... section are designed to be consistent with existing reporting requirements to the extent possible so as to...) by standard commercial wipe tests. (ii) All soil within the spill area (i.e., visible traces of soil...

40 CFR 761.125 - Requirements for PCB spill cleanup.

Code of Federal Regulations, 2014 CFR

2014-07-01

...) Additional pre- or post-cleanup sampling. (B) The estimated cost of the cleanup by man-hours, dollars, or... section are designed to be consistent with existing reporting requirements to the extent possible so as to...) by standard commercial wipe tests. (ii) All soil within the spill area (i.e., visible traces of soil...

40 CFR 761.125 - Requirements for PCB spill cleanup.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) Additional pre- or post-cleanup sampling. (B) The estimated cost of the cleanup by man-hours, dollars, or... section are designed to be consistent with existing reporting requirements to the extent possible so as to...) by standard commercial wipe tests. (ii) All soil within the spill area (i.e., visible traces of soil...

40 CFR 761.125 - Requirements for PCB spill cleanup.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) Additional pre- or post-cleanup sampling. (B) The estimated cost of the cleanup by man-hours, dollars, or... section are designed to be consistent with existing reporting requirements to the extent possible so as to...) by standard commercial wipe tests. (ii) All soil within the spill area (i.e., visible traces of soil...

40 CFR 761.125 - Requirements for PCB spill cleanup.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) Additional pre- or post-cleanup sampling. (B) The estimated cost of the cleanup by man-hours, dollars, or... section are designed to be consistent with existing reporting requirements to the extent possible so as to...) by standard commercial wipe tests. (ii) All soil within the spill area (i.e., visible traces of soil...

Quantification of Complex Polycyclic Aromatic Hydrocarbon Mixtures in Standard Reference Materials Using GC×GC/ToF-MS

PubMed Central

Manzano, Carlos; Hoh, Eunha; Massey Simonich, Staci L.

2014-01-01

This research is the first to quantify complex PAH mixtures in NIST SRMs using comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry (GC×GC/ToF-MS), with and without extract cleanup, and reports previously unidentified PAH isomers in the NIST SRMs. We tested a novel, high orthogonality GC column combination (LC-50×NSP-35), as well as with a commonly used column combination (Rtx-5ms×Rxi-17) for the quantification of a complex mixture of 85 different PAHs, including parent (PAHs), alkyl- (MPAHs), nitro- (NPAHs), oxy- (OPAHs), thio- (SPAHs), bromo- (BrPAHs), and chloro-PAHs (ClPAHs) in extracts from two standard reference materials: NIST SRM1650b (diesel particulate matter), with cleanup and NIST SRM1975 (diesel particulate extract), with and without extract cleanup. The LC-50×NSP-35 column combination resulted in an average absolute percent difference of 33.8%, 62.2% and 30.8% compared to the NIST certified PAH concentrations for NIST SRM1650b, NIST SRM1975 with cleanup and NIST SRM1975 without cleanup, while the Rtx-5ms×Rxi-17 resulted in an absolute percent difference of 38.6%, 67.2% and 79.6% for NIST SRM1650b, NIST SRM1975 with cleanup and NIST SRM1975 without cleanup, respectively. This GC×GC/ToF-MS method increases the number of PAHs detected and quantified in complex environmental extracts using a single chromatographic run. Without clean-up, 7 additional compounds were detected and quantified in NIST SRM1975 using the LC-50×NSP-35 column combination. These results suggest that the use of the LC-50×NSP-35 column combination in GC×GC/ToF-MS not only results in better chromatographic resolution and greater orthogonality for the separation of complex PAH mixtures, but can also be used for the accurate quantification of complex PAH mixtures in environmental extracts without cleanup. PMID:23932031

SUPERFUND CLEANUPS AND INFANT HEALTH.

PubMed

Currie, Janet; Greenstone, Michael; Moretti, Enrico

2011-05-01

We are the first to examine the effect of Superfund cleanups on infant health rather than focusing on proximity to a site. We study singleton births to mothers residing within 5km of a Superfund site between 1989-2003 in five large states. Our "difference in differences" approach compares birth outcomes before and after a site clean-up for mothers who live within 2,000 meters of the site and those who live between 2,000- 5,000 meters of a site. We find that proximity to a Superfund site before cleanup is associated with a 20 to 25% increase in the risk of congenital anomalies.

Cleanup procedure for water, soil, animal and plant extracts for the use of electron-capture detector in the gas chromatographic analysis of organophosphorus insecticide residues.

PubMed

Kadoum, A M

1968-07-01

A simple, aqueous acetonitrile partition cleanup method for analyses of some common organophosphorus insecticide residues is described. The procedure described is for cleanup and quantitative recovery of parathion, methyl parathion, diazinon, malathion and thimet from different extracts. Those insecticides in the purified extracts of ground water, grain, soil, plant and animal tissues can be detected quantitatively by gas chromatography with an electron capture-detector at 0.01 ppm. Cleanup is satisfactory for paper and thin-layer chromatography for further identification of individual insecticides in the extracts.

Novel Americium Treatment Process for Surface Water and Dust Suppression Water

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tiepel, E.W.; Pigeon, P.; Nesta, S.

2006-07-01

The Rocky Flats Environmental Technology Site (RFETS), a former nuclear weapons production plant, has been remediated under CERCLA and decommissioned to become a National Wildlife Refuge. The site conducted this cleanup effort under the Rocky Flats Cleanup Agreement (RFCA) that established limits for the discharge of surface and process waters from the site. At the end of 2004, while a number of process buildings were undergoing decommissioning, routine monitoring of a discharge pond (Pond A-4) containing approximately 28 million gallons of water was discovered to have been contaminated with a trace amount of Americium-241 (Am-241). While the amount of Am-241more » in the pond waters was very low (0.5 - 0.7 pCi/l), it was above the established Colorado stream standard of 0.15 pCi/l for release to off site drainage waters. The rapid successful treatment of these waters to the regulatory limit was important to the site for two reasons. The first was that the pond was approaching its hold-up limit. Without rapid treatment and release of the Pond A-4 water, typical spring run-off would require water management actions to other drainages onsite or a mass shuttling of water for disposal. The second reason was that this type of contaminated water had not been treated to the stringent stream standard at Rocky Flats before. Technical challenges in treatment could translate to impacts on water and secondary waste management, and ultimately, cost impacts. All of the technical challenges and specific site criteria led to the conclusion that a different approach to the treatment of this problem was necessary and a crash treatability program to identify applicable treatment techniques was undertaken. The goal of this program was to develop treatment options that could be implemented very quickly and would result in the generation of no high volume secondary waste that would be costly to dispose. A novel chemical treatment system was developed and implemented at the RFETS to treat Am-241 contaminated pond water, surface run-off and D and D dust suppression water during the later stages of the D and D effort at Rocky Flats. This novel chemical treatment system allowed for highly efficient, high-volume treatment of all contaminated waste waters to the very low stream standard of 0.15 pCi/1 with strict compliance to the RFCA discharge criteria for release to off-site surface waters. The rapid development and implementation of the treatment system avoided water management issues that would have had to be addressed if contaminated water had remained in Pond A-4 into the Spring of 2005. Implementation of this treatment system for the Pond A-4 waters and the D and D waters from Buildings 776 and 371 enabled the site to achieve cost-effective treatment that minimized secondary waste generation, avoiding the need for expensive off-site water disposal. Water treatment was conducted for a cost of less than $0.20/gal which included all development costs, capital costs and operational costs. This innovative and rapid response effort saved the RFETS cleanup program well in excess of $30 million for the potential cost of off-site transportation and treatment of radioactive liquid waste. (authors)« less

Fire suppression in human-crew spacecraft

NASA Technical Reports Server (NTRS)

Friedman, Robert; Dietrich, Daniel L.

1991-01-01

Fire extinguishment agents range from water and foam in early-design spacecraft (Halon 1301 in the present Shuttle) to carbon dioxide proposed for the Space Station Freedom. The major challenge to spacecraft fire extinguishment design and operations is from the micro-gravity environment, which minimizes natural convection and profoundly influences combustion and extinguishing agent effectiveness, dispersal, and post-fire cleanup. Discussed here are extinguishment in microgravity, fire-suppression problems anticipated in future spacecraft, and research needs and opportunities.

Health effects resulting from the Chernobyl accident.

PubMed

Sumner, David

2007-01-01

This article reviews the health effects of the Chernobyl accident. The clearest effect to be seen to date is the dramatic increase in thyroid cancer in children. The evidence for increased leukaemia is less clear, but there are indications of increased leukaemia incidence in Russian clean-up workers. There is also evidence of increases in breast cancer, cataract and cardiovascular disease. However, to date the largest public health problem caused by the accident is the mental health impact.

Waste Information Management System with 2012-13 Waste Streams - 13095

DOE Office of Scientific and Technical Information (OSTI.GOV)

Upadhyay, H.; Quintero, W.; Lagos, L.

2013-07-01

The Waste Information Management System (WIMS) 2012-13 was updated to support the Department of Energy (DOE) accelerated cleanup program. The schedule compression required close coordination and a comprehensive review and prioritization of the barriers that impeded treatment and disposition of the waste streams at each site. Many issues related to waste treatment and disposal were potential critical path issues under the accelerated schedule. In order to facilitate accelerated cleanup initiatives, waste managers at DOE field sites and at DOE Headquarters in Washington, D.C., needed timely waste forecast and transportation information regarding the volumes and types of radioactive waste that wouldmore » be generated by DOE sites over the next 40 years. Each local DOE site historically collected, organized, and displayed waste forecast information in separate and unique systems. In order for interested parties to understand and view the complete DOE complex-wide picture, the radioactive waste and shipment information of each DOE site needed to be entered into a common application. The WIMS application was therefore created to serve as a common application to improve stakeholder comprehension and improve DOE radioactive waste treatment and disposal planning and scheduling. WIMS allows identification of total forecasted waste volumes, material classes, disposition sites, choke points, technological or regulatory barriers to treatment and disposal, along with forecasted waste transportation information by rail, truck and inter-modal shipments. The Applied Research Center (ARC) at Florida International University (FIU) in Miami, Florida, developed and deployed the web-based forecast and transportation system and is responsible for updating the radioactive waste forecast and transportation data on a regular basis to ensure the long-term viability and value of this system. (authors)« less

Pollution control: utility ships adapt for spill cleanups

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1986-02-01

A practical and cost effective approach to oil spill cleanup is being undertaken by Dutch companies. The approach involves constructing and equipping multi-use ships for pollution control. Usually, these ships are maintained in another type of service and come into use for spill cleanup only when needed. The use of these ships in pollution control is discussed.

75 FR 30753 - Regulated Navigation Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-06-02

... superfund cleanup remediation efforts. To more effectively protect those efforts, the Coast Guard is... cleanup remediation process in those waters. These caps consist of approximately three feet of sand and... remediation efforts that underlie the whole concept of the proposed RNA, and we would consult with the City of...

Mental disorders among Chernobyl cleanup workers from Estonia: A clinical assessment.

PubMed

Laidra, Kaia; Rahu, Kaja; Kalaus, Katri-Evelin; Tekkel, Mare; Leinsalu, Mall

2017-08-01

To assess, at a clinical level, the mental health of former Chernobyl cleanup workers from Estonia by comparing them with same-age controls. The Mini International Neuropsychiatric Interview (MINI) was administered during 2011-2012 to 99 cleanup workers and 100 population-based controls previously screened for mental health symptoms. Logistic regression analysis showed that cleanup workers had higher odds of current depressive disorder (odds ratio [OR] = 3.07, 95% confidence interval [CI: 1.34, 7.01]), alcohol dependence (OR = 3.47, 95% CI [1.29, 9.34]), and suicide ideation (OR = 3.44, 95% CI [1.28, 9.21]) than did controls. Except for suicide ideation, associations with Chernobyl exposure became statistically nonsignificant when adjusted for education and ethnicity. A quarter of a century after the Chernobyl accident, Estonian cleanup workers were still at increased risk of mental disorders, which was partly attributable to sociodemographic factors. (PsycINFO Database Record (c) 2017 APA, all rights reserved).

From Cleanup to Stewardship. A companion report to Accelerating Cleanup: Paths to Closure and background information to support the scoping process required for the 1998 PEIS Settlement Study

DOE Office of Scientific and Technical Information (OSTI.GOV)

None, None

1999-10-01

Long-term stewardship is expected to be needed at more than 100 DOE sites after DOE's Environmental Management program completes disposal, stabilization, and restoration operations to address waste and contamination resulting from nuclear research and nuclear weapons production conducted over the past 50 years. From Cleanup to stewardship provides background information on the Department of Energy (DOE) long-term stewardship obligations and activities. This document begins to examine the transition from cleanup to long-term stewardship, and it fulfills the Secretary's commitment to the President in the 1999 Performance Agreement to provide a companion report to the Department's Accelerating Cleanup: Paths to Closuremore » report. It also provides background information to support the scoping process required for a study on long-term stewardship required by a 1998 Settlement Agreement.« less

Compendium of ordinances for groundwater protection

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1990-08-01

Groundwater is an extremely important resource in the Tennessee Valley. Nearly two-thirds of the Tennessee Valley's residents rely, at least in part, on groundwater supplies for drinking water. In rural areas, approximately ninety-five percent of residents rely on groundwater for domestic supplies. Population growth and economic development increase the volume and kinds of wastes requiring disposal which can lead to groundwater contamination. In addition to disposal which can lead to groundwater contamination. In addition to disposal problems associated with increases in conventional wastewater and solid waste, technological advancements in recent decades have resulted in new chemicals and increased usage inmore » agriculture, industry, and the home. Unfortunately, there has not been comparable progress in identifying the potential long-term effects of these chemicals, in managing them to prevent contamination of groundwater, or in developing treatment technologies for removing them from water once contamination has occurred. The challenge facing residence of the Tennessee Valley is to manage growth and economic and technological development in ways that will avoid polluting the groundwater resource. Once groundwater has been contaminated, cleanup is almost always very costly and is sometimes impractical or technically infeasible. Therefore, prevention of contamination -- not remedial treatment--is the key to continued availability of usable groundwater. This document discusses regulations to aid in this prevention.« less

Analysis of fusaric acid in maize using molecularly imprinted solid phase extraction (MISPE) clean-up and ion-pair LC with diode array UV detection

USDA-ARS?s Scientific Manuscript database

Fusaric acid is a phytotoxin and mycotoxin occasionally found in maize contaminated with Fusarium fungi. A selective sample clean-up procedure was developed to detect fusaric acid in maize using molecularly imprinted solid phase extraction (MISPE) clean-up coupled with ion-pair liquid chromatography...

Environmental Liabilities: DoD Training Range Cleanup Cost Estimates Are Likely Understated

DTIC Science & Technology

2001-04-01

1Federal accounting standards define environmental cleanup costs as...report will not be complete or accurate. Federal financial accounting standards have required that DOD report a liability for the estimated cost of...within the range is better than any other amount. SFFAS No. 6, Accounting for Property, Plant, and Equipment, further defines cleanup costs as costs for

Cleanup Verification Package for the 118-F-5 PNL Sawdust Pit

DOE Office of Scientific and Technical Information (OSTI.GOV)

L. D. Habel

2008-05-20

This cleanup verification package documents completion of remedial action, sampling activities, and compliance with cleanup criteria for the 118-F-5 Burial Ground, the PNL (Pacific Northwest Laboratory) Sawdust Pit. The 118-F-5 Burial Ground was an unlined trench that received radioactive sawdust from the floors of animal pens in the 100-F Experimental Animal Farm.

SUPERFUND CLEANUPS AND INFANT HEALTH

PubMed Central

Currie, Janet; Greenstone, Michael; Moretti, Enrico

2013-01-01

We are the first to examine the effect of Superfund cleanups on infant health rather than focusing on proximity to a site. We study singleton births to mothers residing within 5km of a Superfund site between 1989–2003 in five large states. Our “difference in differences” approach compares birth outcomes before and after a site clean-up for mothers who live within 2,000 meters of the site and those who live between 2,000– 5,000 meters of a site. We find that proximity to a Superfund site before cleanup is associated with a 20 to 25% increase in the risk of congenital anomalies. PMID:25152535

Improved automatic steam distillation combined with oscillation-type densimetry for determining alcoholic strength in spirits and liqueurs.

PubMed

Lachenmeier, Dirk W; Plato, Leander; Suessmann, Manuela; Di Carmine, Matthew; Krueger, Bjoern; Kukuck, Armin; Kranz, Markus

2015-01-01

The determination of the alcoholic strength in spirits and liqueurs is required to control the labelling of alcoholic beverages. The reference methodology prescribes a distillation step followed by densimetric measurement. The classic distillation using a Vigreux rectifying column and a West condenser is time consuming and error-prone, especially for liqueurs that may have problems with entrainment and charring. For this reason, this methodology suggests the use of an automated steam distillation device as alternative. The novel instrument comprises an increased steam power, a redesigned geometry of the condenser and a larger cooling coil with controllable flow, compared to previously available devices. Method optimization applying D-optimal and central composite designs showed significant influence of sample volume, distillation time and coolant flow, while other investigated parameters such as steam power, receiver volume, or the use of pipettes or flasks for sample measurement did not significantly influence the results. The method validation was conducted using the following settings: steam power 70 %, sample volume 25 mL transferred using pipettes, receiver volume 50 mL, coolant flow 7 L/min, and distillation time as long as possible just below the calibration mark. For four different liqueurs covering the typical range of these products between 15 and 35 % vol, the method showed an adequate precision, with relative standard deviations below 0.4 % (intraday) and below 0.6 % (interday). The absolute standard deviations were between 0.06 % vol and 0.08 % vol (intraday) and between 0.07 % vol and 0.10 % vol (interday). The improved automatic steam distillation devices offer an excellent alternative for sample cleanup of volatiles from complex matrices. A major advantage are the low costs for consumables per analysis (only distilled water is needed). For alcoholic strength determination, the method has become more rugged than before, and there are only few influences that would lead to incomplete distillation. Our validation parameters have shown that the performance of the method corresponds to the data presented for the reference method and we believe that automated steam distillation, can be used for the purpose of labelling control of alcoholic beverages.

Intergenerational equity and environmental restoration cleanup levels.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hocking, E. K.; Environmental Assessment

2001-01-01

The United States Department of Energy environmental restoration program faces difficult decisions about the levels of cleanup to be achieved at its many contaminated sites and has acknowledged the need for considering intergenerational equity in its decision making. Intergenerational equity refers to the fairness of access to resources across generations. Environmental restoration cleanup levels can have unintended and unfair consequences for future generations access to resources. The potentially higher costs associated with using low, non-risk-based cleanup levels for remediation may divert funding from other activities that could have a greater beneficial impact on future generations. Low, non-risk-based cleanup levels couldmore » also result in more damage to the nation's resources than would occur if a higher cleanup level were used. The loss or impairment of these resources could have an inequitable effect on future generations. However, intergenerational inequity could arise if sites are not completely restored and if access to and use of natural and cultural resources are unfairly limited as a result of residual contamination. In addition to concerns about creating possible intergenerational inequities related to selected cleanup levels, the tremendous uncertainties associated with sites and their restoration can lead site planners to rely on stewardship by default. An ill-conceived stewardship program can contribute to intergenerational inequity by limiting access to resources while passing on risks to future generations and not preparing them for those risks. This paper presents a basic model and process for designing stewardship programs that can achieve equity among generations.« less

Early decision framework for integrating sustainable risk management for complex remediation sites: Drivers, barriers, and performance metrics.

PubMed

Harclerode, Melissa A; Macbeth, Tamzen W; Miller, Michael E; Gurr, Christopher J; Myers, Teri S

2016-12-15

As the environmental remediation industry matures, remaining sites often have significant underlying technical challenges and financial constraints. More often than not, significant remediation efforts at these "complex" sites have not achieved stringent, promulgated cleanup goals. Decisions then have to be made about whether and how to commit additional resources towards achieving those goals, which are often not achievable nor required to protect receptors. Guidance on cleanup approaches focused on evaluating and managing site-specific conditions and risks, rather than uniformly meeting contaminant cleanup criteria in all media, is available to aid in this decision. Although these risk-based cleanup approaches, such as alternative endpoints and adaptive management strategies, have been developed, they are under-utilized due to environmental, socio-economic, and risk perception barriers. Also, these approaches are usually implemented late in the project life cycle after unsuccessful remedial attempts to achieve stringent cleanup criteria. In this article, we address these barriers by developing an early decision framework to identify if site characteristics support sustainable risk management, and develop performance metrics and tools to evaluate and implement successful risk-based cleanup approaches. In addition, we address uncertainty and risk perception challenges by aligning risk-based cleanup approaches with the concepts of risk management and sustainable remediation. This approach was developed in the context of lessons learned from implementing remediation at complex sites, but as a framework can, and should, be applied to all sites undergoing remediation. Copyright © 2016 Elsevier Ltd. All rights reserved.

The French Mess Nucleaire

DOE Office of Scientific and Technical Information (OSTI.GOV)

Davis, M.B.

1994-07-01

Nuclear weapons production has contaminated parts of France, and measures to counter this contamination may be as much cover-up as cleanup. The nuclear weapons industry is trying to remedy some of the problems it created. But until France lifts military secrecy from weapons production matters that affect the environment, the public has no way to gauge the cleanup. No institution outside the Atomic Energy Commission (CEA) and the Ministry of Defense has control over waste disposal, decontamination, and dismantlement at military nuclear sites. The major generators of weapons production waste in France are the CEA and Cogema, one of itsmore » many subsidiaries. Regular operations in military production sites produce environmental contamination. The authors also discuss some accidents causing further contamination. The clean-up measures that the industry is known to be taking, diluting the waste and minimizing the amount of waste, are suspect. The earth`s atmosphere has been considered a prime medium for diluting waste by open air burning of radioactive materials. Releases of mercury to the atmosphere, 260 kilograms per year as of 1984, contributed to water pollution as rain washed the mercury out of the air. Ocean dumping was the CEA`s answer to disposal of sold as well as liquid wastes. Injection liquids into the soil has been a temptation at sites not near substantial bodies of water. Burial of solid wastes has been common. The nuclear industry and the military must make public where and in what form wastes are stored. They must allow independent experts and institutions to examine their research, fabrication, and waste disposal sites. 48 refs.« less

Minimization of corrosion using activated sodium bromide in a medium-size cooling tower

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nalepa, C.J.; Moore, R.M.; Golson, G.L.

1996-07-01

The cooling tower at the Albermarle Process Development Center in Baton Rouge, Louisiana, historically used chlorine as a biocide in combination with phosphorus-based corrosion/scale inhibitors. Although this regimen provided biocontrol, sludge and iron buildup was a problem in low-velocity, small cross-sectional areas of piping. A general cleanup of the system was performed in April 1995. This cleanup was followed with a switch to a two-component corrosion inhibitor/dispersant package. Alternate biocides were evaluated at this time. Activated sodium bromide was found to be particularly effective in this tower, which operates at pH {approximately}8.4. Relative to chlorine, the use of activated sodiummore » bromide led to a decrease in general and pitting corrosion on mild steel. The reduced corrosion appears to be due to a combination of both chemical (less attack on passivated metal surfaces) and biological factors (better control of heterotrophic and sessile bacteria). These conclusions are supported by chemical analyses, corrosion meter and coupon data, dip slides, biological activity reaction tests, and visual observations of the tower sump and heat exchanger surfaces.« less

Integrated risk analysis of a heavy-metal-contaminated site in Taiwan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ching-Tsan Tsai; Wang, J.H.C.

1996-12-31

The Love Canal episode began the long battle on hazardous wastes in the United States. Obviously, the potential danger of hazardous wastes is one of the hottest issues among environmental professionals as well as the public. The problems of hazardous wastes in economically booming Taiwan are also alarming. Several farmlands in northern Taiwan were contaminated heavily by industrial effluents containing heavy metals (cadmium and lead) in the early 1980s. Regardless of the many studies that have been conducted about these polluted farmlands, there has not been any remediation - just a passive abandonment of farming activities with minimal compensation. Thismore » paper addresses a heavy-metal-contaminated fanning area. A pollution profile across time is delineated using information from the abundance of reports, and the contamination is modeled mathematically. The past, the present, and future exposures are also modeled. The results are presented in terms of societal impacts and health effects. Reasonable soil guidelines for cleanup are estimated, and recommendations for rational mitigation solutions are presented. The current strategies for cleanup actions are also described. 23 refs., 4 figs., 5 tabs.« less

Reactor water cleanup system

DOEpatents

Gluntz, Douglas M.; Taft, William E.

1994-01-01

A reactor water cleanup system includes a reactor pressure vessel containing a reactor core submerged in reactor water. First and second parallel cleanup trains are provided for extracting portions of the reactor water from the pressure vessel, cleaning the extracted water, and returning the cleaned water to the pressure vessel. Each of the cleanup trains includes a heat exchanger for cooling the reactor water, and a cleaner for cleaning the cooled reactor water. A return line is disposed between the cleaner and the pressure vessel for channeling the cleaned water thereto in a first mode of operation. A portion of the cooled water is bypassed around the cleaner during a second mode of operation and returned through the pressure vessel for shutdown cooling.

Clean-up and disposal process of polluted sediments from urban rivers.

PubMed

He, P J; Shao, L M; Gu, G W; Bian, C L; Xu, C

2001-10-01

In this paper, the discussion is concentrated on the properties of the polluted sediments and the combination of clean-up and disposal process for the upper layer heavily polluted sediments with good flowability. Based on the systematic analyses of various clean-up processes, a suitable engineering process has been evaluated and recommended. The process has been applied to the river reclamation in Yangpu District of Shanghai City, China. An improved centrifuge is used for dewatering the dredged sludge, which plays an important role in the combination of clean-up and disposal process. The assessment of the engineering process shows its environmental and technical economy feasibility, which is much better than that of traditional dredging-disposal processes.

ION COMPOSITION ELUCIDATION (ICE): A HIGH ...

EPA Pesticide Factsheets

Unidentified Organic Compounds. For target analytes, standards are purchased, extraction and clean-up procedures are optimized, and mass spectra and retention times for the chromatographic separation are obtained for comparison to the target compounds in environmental sample extracts. This is an efficient approach and selective extraction and clean-up can decrease detection limits for the target compounds relative to analyzing a raw extract containing compounds that yield mass interferences. But selection of a class of compounds for study ignores many potentially toxic compounds. All compounds should be considered, because even trace amounts of compounds found to be endocrine disrupting chemicals might influence embryonic development. Before the toxicology of the hundreds of compounds found in sewage treatment effluents and water reservoirs can be studied alone and in mixtures, they must first be identified. A given compound might be one of the 3800 high production volume chemicals used commercially, a human or microorganism metabolite of such a compound, a photochemical degradation, hydrolysis, or thermal decomposition product, a chlorination or ozonolysis byproduct for drinking water samples, or a naturally occurring compound. Numerous researchers targeting assorted classes of analytes could easily overlook or be unable to identify many of these compounds. Most non-targeted compounds will not be in mass spectral libraries and can seldom be tentatively identifi

Post-column infusion study of the 'dosing vehicle effect' in the liquid chromatography/tandem mass spectrometric analysis of discovery pharmacokinetic samples.

PubMed

Shou, Wilson Z; Naidong, Weng

2003-01-01

It has become increasingly popular in drug development to conduct discovery pharmacokinetic (PK) studies in order to evaluate important PK parameters of new chemical entities (NCEs) early in the discovery process. In these studies, dosing vehicles are typically employed in high concentrations to dissolve the test compounds in dose formulations. This can pose significant problems for the liquid chromatography/tandem mass spectrometric (LC/MS/MS) analysis of incurred samples due to potential signal suppression of the analytes caused by the vehicles. In this paper, model test compounds in rat plasma were analyzed using a generic fast gradient LC/MS/MS method. Commonly used dosing vehicles, including poly(ethylene glycol) 400 (PEG 400), polysorbate 80 (Tween 80), hydroxypropyl beta-cyclodextrin, and N,N-dimethylacetamide, were fortified into rat plasma at 5 mg/mL before extraction. Their effects on the sample analysis results were evaluated by the method of post-column infusion. Results thus obtained indicated that polymeric vehicles such as PEG 400 and Tween 80 caused significant suppression (> 50%, compared with results obtained from plasma samples free from vehicles) to certain analytes, when minimum sample cleanup was used and the analytes happened to co-elute with the vehicles. Effective means to minimize this 'dosing vehicle effect' included better chromatographic separations, better sample cleanup, and alternative ionization methods. Finally, a real-world example is given to illustrate the suppression problem posed by high levels of PEG 400 in sample analysis, and to discuss steps taken in overcoming the problem. A simple but effective means of identifying a 'dosing vehicle effect' is also proposed. Copyright 2003 John Wiley & Sons, Ltd.

Cleanups In My Community (CIMC) - Recovery Act Funded Cleanups, National Layer

EPA Pesticide Factsheets

This data layer provides access to Recovery Act Funded Cleanup sites as part of the CIMC web service. The American Recovery and Reinvestment Act was signed into law by President Obama on February 17th, 2009 and all reporting on ARRA for these 3 programs was complete as of 2013. Out of the five EPA programs that distributed recovery act funding, three of them were cleanup programs: Brownfields, Superfund and Leaking Underground Storage Tanks. CIMC provides information on site cleanups that received ARRA Recovery Act funding for Superfund and Brownfields, but not Leaking Underground Storage Tanks. Data for Brownfields came from the ACRES database. Data for Superfund came from the Comprehensive Environmental Response, Compensation, and Liability Information System (CERCLIS) database. Data in CIMC no longer need to be updated for the ARRA program. For information on all EPA Recovery Act funded work, please see: http://archive.epa.gov/recovery/web/html/ and http://epamap17.epa.gov/arra/.

Mature B-cell neoplasms in Chernobyl clean-up workers of 1986-1987: summary of cytomorphological and immunocytochemical study in 25 years after Chernobyl accident.

PubMed

Gluzman, D F; Sklyarenko, L M; Nadgornaya, V A; Zavelevich, M P

2011-03-01

The data on the verified cases of mature B-cell neoplasms (chronic lymphocytic leukemia - CLL, B-prolymphocytic leukemia, non-Hodgkin's lymphoma in leukemization phase and multiple myeloma - MM; 146 cases in total) in the consecutive group of Ukrainian clean-up workers within 10-25 years after Chernobyl accident are summarized. B-cell neoplasms represent the most prevalent group among all diagnosed neoplasms of hematopoietic and lymphoid tissues in clean-up worker patients under study (49.4%). MM percentage in the patients of Chernobyl clean-up worker group turned out to be significantly higher than in the patients of the general populations studied at the same period. While the percentage of B-CLL is similar in clean-up worker patients and patients of general population, the trend towards younger age of patients with mature B-cell neoplasms in clean-up worker group is evident. The current concepts on the possible association between mature B-cell neoplasms (mainly B-CLL) and radiation exposure are briefly outlined. Only the precise diagnosis of hematopoietic malignancies combining with large-scale analytical epidemiological studies with careful dose assessment and long-term follow-up may represent the basis for resolving the question whether mature B-cell neoplasms may be radiogenic.

Extent and Degree of Shoreline Oiling: Deepwater Horizon Oil Spill, Gulf of Mexico, USA

PubMed Central

Michel, Jacqueline; Owens, Edward H.; Zengel, Scott; Graham, Andrew; Nixon, Zachary; Allard, Teresa; Holton, William; Reimer, P. Doug; Lamarche, Alain; White, Mark; Rutherford, Nicolle; Childs, Carl; Mauseth, Gary; Challenger, Greg; Taylor, Elliott

2013-01-01

The oil from the 2010 Deepwater Horizon spill in the Gulf of Mexico was documented by shoreline assessment teams as stranding on 1,773 km of shoreline. Beaches comprised 50.8%, marshes 44.9%, and other shoreline types 4.3% of the oiled shoreline. Shoreline cleanup activities were authorized on 660 km, or 73.3% of oiled beaches and up to 71 km, or 8.9% of oiled marshes and associated habitats. One year after the spill began, oil remained on 847 km; two years later, oil remained on 687 km, though at much lesser degrees of oiling. For example, shorelines characterized as heavily oiled went from a maximum of 360 km, to 22.4 km one year later, and to 6.4 km two years later. Shoreline cleanup has been conducted to meet habitat-specific cleanup endpoints and will continue until all oiled shoreline segments meet endpoints. The entire shoreline cleanup program has been managed under the Shoreline Cleanup Assessment Technique (SCAT) Program, which is a systematic, objective, and inclusive process to collect data on shoreline oiling conditions and support decision making on appropriate cleanup methods and endpoints. It was a particularly valuable and effective process during such a complex spill. PMID:23776444

Major factors affecting in situ biodegradation rates of jet-fuel during large-scale biosparging project in sedimentary bedrock.

PubMed

Machackova, Jirina; Wittlingerova, Zdena; Vlk, Kvetoslav; Zima, Jaroslav

2012-01-01

Biodegradation of petroleum hydrocarbons (TPH), mainly jet fuel, had taken place at the former Soviet Army air base in the Czech Republic. The remediation of large-scale petroleum contamination of soil and groundwater has provided valuable information about biosparging efficiency in the sandstone sedimentary bedrock. In 1997 petroleum contamination was found to be present in soil and groundwater across an area of 28 hectares, divided for the clean-up purpose into smaller clean-up fields (several hectares). The total estimated quantity of TPH released to the environment was about 7,000 metric tons. Biosparging was applied as an innovative clean-up technology at the site and was operated over a 10-year period (1997-2008). Importance of a variety of factors that affect bacterial activity in unsaturated and saturated zones was widely studied on the site and influence of natural and technological factors on clean-up efficiency in heavily contaminates areas of clean-up fields (initial contaminant mass 111-452 metric ton/ha) was evaluated. Long-term monitoring of the groundwater temperature has shown seasonal rises and falls of temperature which have caused a fluctuation in biodegradation activity during clean-up. By contrast, an overall rise of average groundwater temperature was observed in the clean-up fields, most probably as a result of the biological activity during the clean-up process. The significant rise of biodegradation rates, observed after air sparging intensification, and strong linear correlation between the air injection rates and biodegradation activities have shown that the air injection rate is the principal factor in biodegradation efficiency in heavily contaminated areas. It has a far more important role for achieving a biodegradation activity than the contamination content which appeared to have had only a slight effect after the removal of about 75% of initial contamination.

NUCLEAR CLEANUP: Progress Made at Rocky Flats, but Closure by 2006 Is Unlikely, and Costs May Increase

DTIC Science & Technology

2001-02-01

liquids or residues from process pipes and tanks. The contractor also dismantled plutonium - processing furnaces, stripped out contaminated process...Soil Cleanup Levels on the Scope and Cost of the 903 Pad Cleanup 30 Figures Figure 1: Workers in Protective Clothing Handling Plutonium - Contaminated ...activities—shipping nuclear materials such as plutonium - contaminated metals and powders—is expected to be completed in 2002. Another activity

Reactor water cleanup system

DOEpatents

Gluntz, D.M.; Taft, W.E.

1994-12-20

A reactor water cleanup system includes a reactor pressure vessel containing a reactor core submerged in reactor water. First and second parallel cleanup trains are provided for extracting portions of the reactor water from the pressure vessel, cleaning the extracted water, and returning the cleaned water to the pressure vessel. Each of the cleanup trains includes a heat exchanger for cooling the reactor water, and a cleaner for cleaning the cooled reactor water. A return line is disposed between the cleaner and the pressure vessel for channeling the cleaned water thereto in a first mode of operation. A portion of the cooled water is bypassed around the cleaner during a second mode of operation and returned through the pressure vessel for shutdown cooling. 1 figure.

Method of and apparatus for preheating pressurized fluidized bed combustor and clean-up subsystem of a gas turbine power plant

DOEpatents

Cole, Rossa W.; Zoll, August H.

1982-01-01

In a gas turbine power plant having a pressurized fluidized bed combustor, gas turbine-air compressor subsystem and a gas clean-up subsystem interconnected for fluid flow therethrough, a pipe communicating the outlet of the compressor of the gas turbine-air compressor subsystem with the interior of the pressurized fluidized bed combustor and the gas clean-up subsystem to provide for flow of compressed air, heated by the heat of compression, therethrough. The pressurized fluidized bed combustor and gas clean-up subsystem are vented to atmosphere so that the heated compressed air flows therethrough and loses heat to the interior of those components before passing to the atmosphere.

Parent-child coregulation of parasympathetic processes varies by social context and risk for psychopathology.

PubMed

Lunkenheimer, Erika; Tiberio, Stacey S; Skoranski, Amanda M; Buss, Kristin A; Cole, Pamela M

2018-02-01

The parasympathetic nervous system supports social interaction and varies in relation to psychopathology. However, we know little about parasympathetic processes from a dyadic framework, nor in early childhood when parent-child social interactions become more complex and child psychopathology first emerges. We hypothesized that higher risk for psychopathology (maternal psychopathology symptoms and child problem behavior) would be related to weaker concordance of respiratory sinus arrhythmia (RSA) between mothers and children (M = 3½ years old; N = 47) and that these relations could vary by social contextual demands, comparing unstructured free play, semistructured cleanup, and structured teaching tasks. Multilevel coupled autoregressive models of RSA during parent-child interactions showed overall dynamic, positive concordance in mother-child RSA over time, but this concordance was weaker during the more structured teaching task. In contrast, higher maternal psychological aggression and child externalizing and internalizing problems were associated with weaker dyadic RSA concordance, which was weakest during unstructured free play. Higher maternal depressive symptoms were related to disrupted individual mother and child RSA but not to RSA concordance. Thus, risk for psychopathology was generally related to weaker dyadic mother-child RSA concordance in contexts with less complex structure or demands (free play, cleanup), as compared to the structured teaching task that showed weaker RSA concordance for all dyads. Implications for the meaning and utility of the construct of parent-child physiological coregulation are discussed. © 2017 Society for Psychophysiological Research.

CMPO purity tests in the TRUEX solvent using americium-241

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brewer, K.N.; Herbst, R.S.; Tranter, T.J.

1993-12-01

The Transuranic Extraction (TRUEX) Process was developed by E.P. Horwitz and coworkers at Argonne National Laboratory (ANL) to separate the +4, +6, and +3 actinides from acidic aqueous solutions of nuclear wastes. Octyl (phenyl)-N-N-diisobutyl-carbamoylmethylphosphine oxide (CMPO) is the active actinide complexant used in the TRUEX solvent. CMPO is combined with tributyl phosphate (TBP) in an organic diluent, typically n-dodecane, to form the TRUEX solvent. Small quantities of impurities in the CMPO resulting from: (1) synthesis, (2) acid hydrolysis, or (3) radiolysis can result in actinide stripping problems from the solvent. The impurity, octylphenylphosphinic acid (POPPA), ia a powerful extractant atmore » low acid concentrations which may be formed during CMPO synthesis. Consequently, commercial CMPO may contain sufficient quantities of POPPA to significantly impact the stripping of actinides from the TRUEX solvent. The purpose of these tests was to (1) determine if commercially available CMPO is sufficiently pure to alleviate actinide stripping problems from the TRUEX process and (2) to determine if solvent cleanup methods are sufficient to purify the commercially purchased CMPO. Extraction and solvent cleanup methodologies used by Horwitz and coworkers at ANL were used to determine CMPO purity with {sup 241}Am. The improvement of the americium distribution coefficient in dilute nitric acid resulting from further purifying this CMPO is not significant enough to warrant additional CMPO purifying steps. The commercially purchased CMPO is found to be acceptable to use, as received, in a full-scale TRUEX process.« less

THE POSITIVE IMPACTS OF AMERICAN REINVESTMENT AND RECOVERY ACT (ARRA) FUNDING TO THE WASTE MANAGEMENT PROGRAM ON HANFORD'S PLATEAU REMEDIATION PROJECT

DOE Office of Scientific and Technical Information (OSTI.GOV)

BLACKFORD LT

In April 2009, the Department of Energy (DOE) Richland Operations Office (RL) was allocated $1.6 billion (B) in ARRA funding to be applied to cleanup projects at the Hanford Site. DOE-RL selected projects to receive ARRA funding based on 3-criteria: creating/saving jobs, reducing the footprint of the Hanford Site, and reducing life-cycle costs for cleanup. They further selected projects that were currently covered under regulatory documents and existing prime contracts, which allowed work to proceed quickly. CH2M HILL Plateau Remediation Company (CHPRC) is a prime contractor to the DOE focused on the environmental cleanup of the DOE Hanford Site Centralmore » Plateau. CHPRC was slated to receive $1.36B in ARRA funding. As of January, 2010, CHPRC has awarded over $200 million (M) in subcontracts (64% to small businesses), created more that 1,100 jobs, and touched more than 2,300 lives - all in support of long-term objectives for remediation of the Central Plateau, on or ahead of schedule. ARRA funding is being used to accelerate and augment cleanup activities already underway under the baseline Plateau Remediation Contract (PRC). This paper details challenges and accomplishments using ARRA funding to meet DOE-RL objectives of creating/saving jobs, expediting cleanup, and reducing lifecycle costs for cleanup during the first months of implementation.« less

Approach for ochratoxin A fast screening in spices using clean-up tandem immunoassay columns with confirmation by high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS).

PubMed

Goryacheva, I Yu; De Saeger, S; Lobeau, M; Eremin, S A; Barna-Vetró, I; Van Peteghem, C

2006-09-01

An approach for ochratoxin A (OTA) fast cost-effective screening based on clean-up tandem immunoassay columns was developed and optimized for OTA detection with a cut-off level of 10 microg kg(-1) in spices. Two procedures were tested and applied for OTA detection. Column with bottom detection immunolayer was optimized for OTA determination in Capsicum ssp. spices. A modified clean-up tandem immunoassay procedure with top detection immunolayer was successfully applied for all tested spices. Its main advantages were decreasing of the number of analysis steps and quantity of antibody and also minimizing of matrix effects. The total duration of the extraction and analysis was about 40 min for six samples. Chilli, red pepper, pili-pili, cayenne, paprika, nutmeg, ginger, white pepper and black pepper samples were analyzed for OTA contamination by the proposed clean-up tandem immunoassay procedures. Clean-up tandem immunoassay results were confirmed by HPLC-MS/MS with immunoaffinity column clean-up. Among 17 tested Capsicum ssp. spices, 6 samples (35%) contained OTA in a concentration exceeding the 10 microg kg(-1) limit discussed by the European Commission. All tested nutmeg (n=8), ginger (n=5), white pepper (n=7) and black pepper (n=6) samples did not contain OTA above this action level.

Superfund Green Remediation

EPA Pesticide Factsheets

Green remediation is the practice of considering all environmental effects of site cleanup and incorporating options – like the use of renewable energy resources – to maximize the environmental benefits of cleanups.

Enrichment and low-level determination of glyphosate, aminomethylphosphonic acid and glufosinate in drinking water after cleanup by cation exchange resin.

PubMed

Küsters, Markus; Gerhartz, Michael

2010-04-01

For the determination of glyphosate, aminomethylphosphonic acid and glufosinate in drinking water, different procedures of enrichment and cleanup were examined using anion exchange or SPE. In many cases interactions of, e.g. alkaline earth metal ions especially calcium could be observed during enrichment and cleanup resulting in loss of analytes. For that reason, a novel cleanup and enrichment procedure for the determination of these phosphonic acid herbicides has been developed in drinking water using cation-exchange resin. In summary, the cleanup procedure with cation-exchange resin developed in this study avoids interactions as described above and is applicable to calcium-rich drinking water samples. After derivatization with 9-fluorenylmethylchloroformate followed by LC with fluorescence detection, LOD of 12, 14 and 12 ng/L and mean recoveries from real-world drinking water samples of 98+/-9, 100+/-16 and 101+/-11% were obtained for glyphosate, aminomethylphosphonic acid and glufosinate, respectively. The low LODs and the high precision permit the analysis of these phosphonic acid herbicides according to the guidelines of the European Commission.

Health complaints among subjects involved in oil cleanup operations during oil spillage from a Greek tanker "Tasman Spirit".

PubMed

Meo, Sultan Ayoub; Al-Drees, Abdul Majeed; Rasheed, Shahzad; Meo, Imran Mu; Al-Saadi, Muslim M; Ghani, Hamza A; Alkandari, Jasem Ramadan

2009-01-01

Oil spillage in the sea water is a disaster for marine life and humans in the vicinity. The study aimed at investigating health complaints among subjects involved in oil cleanup operations during a spillage from a Greek oil tanker "Tasman Spirit". The project was conducted under the supervision of the Department of Physiology, College of Medicine, King Khalid University Hospital, King Saud University, Riyadh, Saudi Arabia. The study concerned the respiratory and general health complaints in 50 apparently healthy, non-smoking male workers exposed to crude oil during oil cleanup operations. The exposed group was matched with a similar number of male, non-smoking controls. The health complaints were evaluated based on a comprehensive interview. The subjects involved in oil cleanup operations had significantly higher rates of health complaints including cough (38%), runny nose (36%), eye irritation/redness (32%), sore throat (28%), headache (28%), nausea (24%) and general illness (18%), compared to their matched controls. Air pollution due to crude oil spillage into sea water may cause respiratory and general health complaints in workers involved in oil cleanup operations.

An automated online turboflow cleanup LC/MS/MS method for the determination of 11 plasticizers in beverages and milk.

PubMed

Ates, Ebru; Mittendorf, Klaus; Senyuva, Hamide

2013-01-01

An automated sample preparation technique involving cleanup and analytical separation in a single operation using an online coupled TurboFlow (RP-LC system) is reported. This method eliminates time-consuming sample preparation steps that can be potential sources for cross-contamination in the analysis of plasticizers. Using TurboFlow chromatography, liquid samples were injected directly into the automated system without previous extraction or cleanup. Special cleanup columns enabled specific binding of target compounds; higher MW compounds, i.e., fats and proteins, and other matrix interferences with different chemical properties were removed to waste, prior to LC/MS/MS. Systematic stepwise method development using this new technology in the food safety area is described. Selection of optimum columns and mobile phases for loading onto the cleanup column followed by transfer onto the analytical column and MS detection are critical method parameters. The method was optimized for the assay of 10 phthalates (dimethyl, diethyl, dipropyl, butyl benzyl, diisobutyl, dicyclohexyl, dihexyl, diethylhexyl, diisononyl, and diisododecyl) and one adipate (diethylhexyl) in beverages and milk.

Development of comprehensive remediation standards at San Francisco International Airport

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grosso, A.; Lawler, M.; Meek, S.

1995-12-31

An ongoing expansion at the San Francisco International Airport (Airport) will result in a 35 percent increase in both terminal square footage and passenger handling capability. Facility relocation and construction are set to begin in October, 1995. Appropriate cleanup of contaminated soil and groundwater must be completed prior to this activity. Remedial goals for this major industrial facility must be protective of both human health and the environment. A risk-based strategy for the development of recommended cleanup objectives has been developed with the support of state regulatory agencies. This strategy includes Remediation Management Zones (RMZs), distinct regions at the Airportmore » with different remedial goals based on the associated risk to water quality, human health, and the environment. The RMZs and the final cleanup objectives for the Airport will be finalized by mid-1995, and will be used to govern future cleanup efforts at the site. This presentation will describe the history of the project, the determination of human health and ecological buffer zones, and the integration of these two concepts to produce cleanup objectives fully supported by the state regulatory authority.« less

Offshore oil in the Alaskan Arctic

NASA Technical Reports Server (NTRS)

Weeks, W. F.; Weller, G.

1984-01-01

Oil and gas deposits in the Alaskan Arctic are estimated to contain up to 40 percent of the remaining undiscovered crude oil and oil-equivalent natural gas within U.S. jurisdiction. Most (65 to 70 percent) of these estimated reserves are believed to occuur offshore beneath the shallow, ice-covered seas of the Alaskan continental shelf. Offshore recovery operations for such areas are far from routine, with the primary problems associated with the presence of ice. Some problems that must be resolved if efficient, cost-effective, environmentally safe, year-round offshore production is to be achieved include the accurate estimation of ice forces on offshore structures, the proper placement of pipelines beneath ice-produced gouges in the sea floor, and the cleanup of oil spills in pack ice areas.

Streamlining Site Cleanup in New York City

EPA Pesticide Factsheets

This joint effort, supported by the New York State Department of Environmental Conservation (NYS DEC), advances the environmental cleanup goals of PlaNYC 2030, the city's comprehensive sustainability plan.

TECHNICAL APPROACHES TO CHARACTERIZING AND ...

EPA Pesticide Factsheets

The document provides brownfields planners with an overview of the technical methods that can be used to achieve successful site assessment and cleanup which are two key components of the brownfields redevelopment process. No two brownfields sites are identical and planners will need to base assessment and cleanup activities on the conditions of the particular sites with which they are dealing. A site assessment strategy should address: the type and extent of contamination, if any, that is present, the types of data needed to adequately assess the site; appropriate sampling and analytical methods to characterize the contamination; acceptable level of uncertainty and cleanup technologies that contain or treat the types of wastes present.This document includes references to state agency roles including the Voluntary Cleanup Program, public involvement and other guidances that may be used. Information

High-throughput analytical techniques for multiresidue, multiclass determination of 653 pesticides and chemical pollutants in tea--Part III: Evaluation of the cleanup efficiency of an SPE cartridge newly developed for multiresidues in tea.

PubMed

Pang, Guo-Fang; Fan, Chun-Lin; Chang, Qiao-Ying; Li, Yan; Kang, Jian; Wang, Wen-Wen; Cao, Jing; Zhao, Yan-Bing; Li, Nan; Li, Zeng-Yin; Chen, Zong-Mao; Luo, Feng-Jian; Lou, Zheng-Yun

2013-01-01

A comparative study was conducted over three stages on the cleanup efficiency of SPE cartridge Cleanert TPT, newly developed for multigroups of pesticide residues in tea. In Stage I, different SPE cartridges C18, graphite carbon black (GCB), primary secondary amine (PSA), and amino (NH2) were purchased and combined into 12 different sequences. Through the comparative test on cleanup efficiency of 84 representative pesticides in tea, Envi-Carb GCB + PSA with a good cleanup effect was selected. In Stage II, GC/MS test results from the comparative study of the extraction efficiency of 201 pesticides spiked into green tea and Woolong tea with Cleanert TPT and Envi-Carb + PSA SPE showed that average recoveries fell within 70-110% and RSD <20% for 193 and 184 pesticides, respectively, for green tea, accounting for 96.0 and 91.0% of the total number, respectively. GC/MS/MS test results also found 193 and 184 pesticides, respectively, meeting the recovery and RSD conditions, accounting for 96.0 and 91.5%, respectively, of the total number. For Woolong tea samples, GC/MS results showed that with Cleanert TPT and Envi-Carb + PSA SPE for cleanup, there were 192 and 177 pesticides, respectively, meeting the conditions, accounting for 95.5 and 88.1% of the total number, respectively. GC/MS/MS results demonstrated that there were 195 and 184 pesticides, respectively, meeting the conditions, accounting for 97.0 and 91.5% of the total number, respectively. It was seen that Cleanert TPT was superior to Envi-Carb + PSA in cleanup efficiency, whether for green or Woolong tea samples, or GC/MS or GC/MS/MS determination. In Stage III, 61104 results of the average content value of pesticides and RSD (two teas xtwo Youden pair concentrations x two kinds of SPE cartridges x two instruments x 19 tests x 201 pesticides) were derived from the 19 times stability tests over 3 months by paralleling three samples every 5 days via two instruments with two kinds of SPE cartridges for cleanup, respectively, against Youden Pair samples of the 201 incurred pesticides from green and Woolong teas. The statistical analysis found that detected values from the target pesticides of the incurred Youden pair samples showed no marked differences with cleanup by either Cleanert TPT or Envi-Carb + PSA, whether for green or Woolong tea, or G/IMS or G/IM/IMS. The test results using the two aforementioned kinds of SPE cleanup for above 93% pesticides had a tolerance less than 15%, which testifies that both cartridge cleanups met the requirement for pesticide residue analysis.

Dyscirculatory encephalopathy in Chernobyl disaster clean-up workers (a 20-year study).

PubMed

Podsonnaya, I V; Shumakher, G I; Golovin, V A

2010-05-01

Results obtained over 20-years of following 536 Chernobyl clean-up workers and 436 control subjects are presented. Dyscirculatory encephalopathy developed more frequently in persons exposed to radiation at age 30 years. As compared with the control group, workers were characterized by early onset of disease, faster progression, stable symptomatology for 5-6 years, and further progression of disease in the form of autonomic dysfunction, psycho-organic syndrome, and epilepsy. Major strokes were also more common in clean-up workers.

The long-term problems of contaminated land: Sources, impacts and countermeasures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Baes, C.F. III

1986-11-01

This report examines the various sources of radiological land contamination; its extent; its impacts on man, agriculture, and the environment; countermeasures for mitigating exposures; radiological standards; alternatives for achieving land decontamination and cleanup; and possible alternatives for utilizing the land. The major potential sources of extensive long-term land contamination with radionuclides, in order of decreasing extent, are nuclear war, detonation of a single nuclear weapon (e.g., a terrorist act), serious reactor accidents, and nonfission nuclear weapons accidents that disperse the nuclear fuels (termed ''broken arrows'').

Applications of remote sensing to estuarine management

NASA Technical Reports Server (NTRS)

Munday, J. C., Jr.; Gordon, H. H.; Hennigar, H. F.

1977-01-01

Remote sensing was used in the resolution of estuarine problems facing federal and Virginia governmental agencies. A prototype Elizabeth River Surface Circulation Atlas was produced from photogrammetry to aid in oil spill cleanup and source identification. Aerial photo analysis twice led to selection of alternative plans for dredging and spoil disposal which minimized marsh damage. Marsh loss due to a mud wave from a highway dyke was measured on sequential aerial photographs. An historical aerial photographic sequence gave basis to a potential Commonwealth of Virginia legal claim to accreting and migrating coastal islands.

Memorandum of the Establishment of Cleanup Levels for CERCLA Sites with Radioactive Contamination

EPA Pesticide Factsheets

This memorandum presents clarifying guidance for establishing protective cleanup levels for radioactive contamination at Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) sites.

Improving Sampling, Analysis, and Data Management for Site Investigation and Cleanup

EPA Pesticide Factsheets

The United States Environmental Protection Agency (EPA) supports the adoption of streamlined approaches to sampling, analysis, and data management activities conducted during site assessment, characterization, and cleanup.

Increased leukemia risk in Chernobyl cleanup workers

Cancer.gov

A new study found a significantly elevated risk for chronic lymphocytic leukemia among workers who were engaged in recovery and clean-up activities following the Chernobyl power plant accident in 1986.

Radiation Dose to Post-Chernobyl Cleanup Workers

Cancer.gov

Radiation dose calculation for post-Chernobyl Cleanup Workers in Ukraine - both external radiation exposure due to fallout and internal doses due to inhalation (I131 intake) or ingestion of contaminated foodstuffs.

Johnston Atoll Plutonium Cleanup Project, plant modification and operation. Volume 1. Annual report option year 2. Technical report, 1 October 1992-24 May 1993

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moroney, K.S.; Moroney, J.D.; Johnson, N.R.

1995-04-01

This report continues the documentation of the operation of TMA/Eberline`s Segmented Gate System technology for removing mixed plutonium and americium contamination at DNA`s Johnston Atoll site. Contaminated feed is conveyed under arrays of radiation detectors coupled with sophisticated computer software developed by Eberline Instrument Corporation. Segmented gates (chutes) on pneumatically-driven pistons move forward when contamination is detected to remove only the contaminated portion from the main flow of feed material. Only about one pint of contaminant is removed during each diversion event. At the JA site, a 98% volume reduction has been achieved, with the remediated soil cleaned to DNA`smore » criteria for release for unrestricted use of 500 Bq/kg total tnansuranic alpha contamination and no hot particles of greater than 5000 Becquerrels. The low level waste concentrate is expected to be packaged for shipment to an approved defense waste disposal site.« less

Johnston Atoll Plutonium Cleanup Project. Plant modification and operation. Volume 2. Annual report option year 2. Appendix A. Technical report, 1 October 1992-24 May 1993

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moroney, K.S.; Moroney, J.D.; Johnson, N.R.

1995-04-01

This report continues the documentation of the operation of TMA/Eberline`s Segmented Gate System technology for removing mixed plutonium and americium contamination at DNA`s Johnston Atoll site. Contaminated feed is conveyed under arrays of radiation detectors coupled with sophisticated computer software developed by Eberline Instrument Corporation. Segmented gates (chutes) on pneumatically-driven pistons move forward when contamination is detected to remove only the contaminated portion from the main flow of feed material. Only about one pint of contaminant is removed during each diversion event. At the JA site, a 98% volume reduction has been achieved, with the remediated soil cleaned to DNA`smore » criteria for release for unrestricted use of 500 Bq/kg total transuranic alpha contamination and no hot particles of greater than 5000 Becquerrels. The low level waste concentrate is expected to be packaged for shipment to an approved defense waste disposal site.« less

Johnston Atoll Plutonium Cleanup Project, plant modification and operation. Volume 3. Annual report option year 2. Appendices b through h. Technical report, 1 October 1992-24 May 1993

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moroney, K.S.; Moroney, J.D.; Johnson, N.R.

1995-04-01

This report continues the documentation of the operation of TMA/Eberline`s Segmented Gate System technology for removing mixed plutonium and americium contamination at DNA`s Johnston Atoll site. Contaminated feed is conveyed under arrays of radiation detectors coupled with sophisticated computer software developed by Eberline Instrument Corporation. Segmented gates (chutes) on pneumatically-driven pistons move forward when contamination is detected to remove only the contaminated portion from the main flow of feed material. Only about one pint of contaminant is removed during each diversion event. At the JA site, a 98% volume reduction has been achieved, with the remediated soil cleaned to DNA`smore » criteria for release for unrestricted use of 500 Bq/kg total transuranic alpha contamination and no hot particles of greater than 5000 Becquerrels. The low level waste concentrate is expected to be packaged for shipment to an approved defense waste disposal site.« less

[Isolation, identification and characterization of a diethylstilbestrol-degrading bacterial strain Serratia sp].

PubMed

Xu, Ran-Fang; Sun, Min-Xia; Liu, Juan; Wang, Hong; Li, Xin; Zhu, Xue-Zhu; Ling, Wan-Ting

2014-08-01

Utilizing the diethylstilbestrol (DES)-degrading bacteria to biodegrade DES is a most reliable technique for cleanup of DES pollutants from the environment. However, little information is available heretofore on the isolation of DES-degrading bacteria and their DES removal performance in the environment. A novel bacterium capable of degrading DES was isolated from the activated sludge of a wastewater treatment plant. According to its morphology, physiochemical characteristics, and 16S rDNA sequence analysis, this strain was identified as Serratia sp.. The strain was an aerobic bacterium, and it could degrade 68.3% of DES (50 mg x L(-1)) after culturing for 7 days at 30 degrees C, 150 r x min(-1) in shaking flasks. The optimal conditions for DES biodegradation by the obtained strain were 30 degrees C, 40-60 mg x L(-1) DES, pH 7.0, 5% of inoculation volume, 0 g x L(-1) of added NaCl, and 10 mL of liquid medium volume in 100 mL flask.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

This report summarizes significant FY93 programmatic information and accomplishments relevant to the individual activities within the Office of Technology Development Program for Research, Development, Demonstration, Testing, and Evaluation (RDDT&E). A brief discussion of the mission of the Office of Environmental Restoration and Waste Management (EM) and the Office of Technology Development is presented. An overview is presented of the major problem areas confronting DOE. These problem areas include: groundwater and soils cleanup; waste retrieval and processing; and pollution prevention. The organizational elements within EM are highlighted. An EM-50 Funding Summary for FY92 and FY93 is also provided. RDDT&E programs aremore » discussed and their key problem areas are summarized. Three salient program-formulating concepts are explained. They are: Integrated Demonstrations, Integrated Programs, and the technology window of opportunity. Detailed information for each of the programs within RDDT&E is presented and includes a fact sheet, a list of technical task plans and an accomplishments and objectives section.« less

Nuclear radiation cleanup and uranium prospecting

DOEpatents

Mariella, Jr., Raymond P.; Dardenne, Yves M.

2016-02-02

Apparatus, systems, and methods for nuclear radiation cleanup and uranium prospecting include the steps of identifying an area; collecting samples; sample preparation; identification, assay, and analysis; and relating the samples to the area.

Nuclear radiation cleanup and uranium prospecting

DOEpatents

Mariella, Jr., Raymond P.; Dardenne, Yves M.

2017-01-03

Apparatus, systems, and methods for nuclear radiation cleanup and uranium prospecting include the steps of identifying an area; collecting samples; sample preparation; identification, assay, and analysis; and relating the samples to the area.

Cleanup Verification Package for the 300-18 Waste Site

DOE Office of Scientific and Technical Information (OSTI.GOV)

J. M. Capron

This cleanup verification package documents completion of remedial action for the 300-18 waste site. This site was identified as containing radiologically contaminated soil, metal shavings, nuts, bolts, and concrete.

Green Remediation Best Management Practices: Mining Sites

EPA Pesticide Factsheets

This fact sheet describes best management practices (BMPs) that can be used to reduce the environmental footprint of cleanup activities associated with common project components, cleanup phases, and implementation of remediation technologies.

Online Hazardous Waste Cleanup Technical Resources

EPA Pesticide Factsheets

This issue paper is intended to give the reader examples of some online technical resources that can assist with hazardous waste cleanups in the Superfund, Resource Conservation and Recovery Act (RCRA), and Brownfields programs.

A Citizen's Guide to Drycleaner Cleanup

EPA Pesticide Factsheets

The State Coalition for Remediation of Drycleaners (SCRD) has prepared an easy-to-read guide explaining the drycleaner cleanup process and describing the technologies that are most commonly used to clean up contaminated drycleaner sites.

Tribal Lands Cleanup and Spill Prevention Programs

EPA Pesticide Factsheets

EPA takes strides to prevent and cleanup contamination and contaminated sites located on or near Tribal lands. Our programs work hand-in-hand with tribes to ensure we protect their health and the environment.

Hazardous Waste: Cleanup and Prevention.

ERIC Educational Resources Information Center

Vandas, Steve; Cronin, Nancy L.

1996-01-01

Describes the Superfund, a federal cleanup program created in response to growing public concern over the health and environmental risks posed by hazardous waste sites. Discusses sources, disposal, and movement and risk of hazardous waste. (JRH)

Workplace Safety: Indoor Environmental Quality

MedlinePlus

... Cleanup Tuberculosis Follow NIOSH Facebook Flickr Pinterest Twitter YouTube NIOSH Homepage NIOSH A-Z Workplace Safety & Health ... Cleanup Tuberculosis Follow NIOSH Facebook Flickr Pinterest Twitter YouTube NIOSH Homepage NIOSH A-Z Workplace Safety & Health ...

Burbank performs the scheduled extensive cleanup of ventilation systems

NASA Image and Video Library

2012-02-22

ISS030-E-093414 (22 Feb. 2012) --- NASA astronaut Dan Burbank, Expedition 30 commander, performs the scheduled extensive cleanup of ventilation systems in the Columbus laboratory of the International Space Station.

43 CFR 3931.30 - Suspension of operations and production.

Code of Federal Regulations, 2012 CFR

2012-10-01

... environmental studies or analysis; (2) To ensure that necessary environmental remediation or cleanup is being... environmental remediation or cleanup is being performed as a result of unwarranted or unexpected actions. (c...

43 CFR 3931.30 - Suspension of operations and production.

Code of Federal Regulations, 2013 CFR

2013-10-01

... environmental studies or analysis; (2) To ensure that necessary environmental remediation or cleanup is being... environmental remediation or cleanup is being performed as a result of unwarranted or unexpected actions. (c...

43 CFR 3931.30 - Suspension of operations and production.

Code of Federal Regulations, 2011 CFR

2011-10-01

... environmental studies or analysis; (2) To ensure that necessary environmental remediation or cleanup is being... environmental remediation or cleanup is being performed as a result of unwarranted or unexpected actions. (c...

43 CFR 3931.30 - Suspension of operations and production.

Code of Federal Regulations, 2014 CFR

2014-10-01

... environmental studies or analysis; (2) To ensure that necessary environmental remediation or cleanup is being... environmental remediation or cleanup is being performed as a result of unwarranted or unexpected actions. (c...

Molds in the Environment

MedlinePlus

... visit this page: About CDC.gov . Mold Cleanup & Remediation Homeowner’s and Renter’s Guide to Mold Cleanup After ... Home or Building with Mold Damage Prevention and Remediation Strategies for the Control and Removal of Fungal ...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

This interim notice covers the following: extractable organic halides in solids, total organic halides, analysis by gas chromatography/Fourier transform-infrared spectroscopy, hexadecane extracts for volatile organic compounds, GC/MS analysis of VOCs, GC/MS analysis of methanol extracts of cryogenic vapor samples, screening of semivolatile organic extracts, GPC cleanup for semivolatiles, sample preparation for GC/MS for semi-VOCs, analysis for pesticides/PCBs by GC with electron capture detection, sample preparation for pesticides/PCBs in water and soil sediment, report preparation, Florisil column cleanup for pesticide/PCBs, silica gel and acid-base partition cleanup of samples for semi-VOCs, concentrate acid wash cleanup, carbon determination in solids using Coulometrics` CO{submore » 2} coulometer, determination of total carbon/total organic carbon/total inorganic carbon in radioactive liquids/soils/sludges by hot persulfate method, analysis of solids for carbonates using Coulometrics` Model 5011 coulometer, and soxhlet extraction.« less

Hazardous waste sites: voluntary industry cleanup proposed

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1984-02-27

A proposal that calls for the chemical industry to undertake voluntary cleanup of hazardous waste sites was presented recently to the Environmental Protection Agency and on Capitol Hill. And although still in draft form, the proposal has elicited a very favorable response. In its present form, the proposal calls for setting up a nonprofit holding company, supported by donations from the chemical industry, to plan and carry out cleanup operations. It is the result of nine months of discussion among representatives of industry, environmental groups, and former government personnel, carried out under the auspices of the Conservation Foundation to assessmore » what could be done to speed the cleanup of hazardous waste sites. Although still in draft form, the proposal already is getting excellent reviews. One Congressional staff member says that the idea of a voluntary program is excellent. And EPA sees it as a real opportunity to supplement its funds - which it has been saying are nowhere near adequte to clean up all the sites that it expects eventually to be placed on the national priorities list - and get the work done. All this, of course, would occur under the agency's watchful eye. Some in the environmental community fear that the mere discussion of a private cleanup exercise might be used as an argument for not reauthorizing Superfund or for not expanding the size of the fund. However, most see the voluntary cleanup as a supplement to, not a replacement for, the Superfund program.« less

Hybrid Sargassum-sand sorbent: a novel adsorbent in packed column to treat metal-bearing wastewaters from inductively coupled plasma-optical emission spectrometry.

PubMed

Vijayaraghavan, K; Joshi, U M

2013-01-01

Laboratory batch and column experiments were carried out to examine the efficiency of algal-based treatment technique to clean-up wastewaters emanating from inductively coupled plasma-optical emission spectrometry (ICP-OES). Chemical characterization revealed the extreme complexity of the wastewater, with the presence of 14 different metals under very low pH (pH = 1.1), high conductivity (6.98 mS/cm), total dissolved solid (4.46 g/L) and salinity (3.77). Batch experiments using Sargassum biomass indicated that it was possible to attain high removal efficiencies at optimum pH of 4.0. Efforts were also made to continuously treat ICP-OES wastewater using up-flow packed column. However, swelling of Sargassum biomass leads to stoppage of column. To address the problem, Sargassum was mixed with sand at a ratio of 40: 60 on volume basis. Remarkably, the hybrid Sargassum-sand sorbent showed very high removal efficiency towards multiple metal ions with the column able to operate for 11 h at a flow rate of 10 mL/min. Metal ions such as Cu, Cd, and Pb were only under trace levels in the treated water until 11 h. The results of the treatment process were compared with trade effluent discharge standards. Further the process evaluation and cost analysis were presented.

Patterns of hematological malignancies in Chernobyl clean-up workers (1996-2005).

PubMed

Gluzman, D; Imamura, N; Sklyarenko, L; Nadgornaya, V; Zavelevich, M; Machilo, V

2006-03-01

The question as to whether the incidence of leukemias and malignant lymphomas among the Chernobyl clean-up workers increased in 20 years after the catastrophe is still a point of much controversy. Precise diagnosis of the main forms of hematopoietic malignancies according to FAB classification and new WHO classification and comparison of these data with that in the general population will be helpful in estimating the relative contribution of the radiation factor to the overall incidence of such pathologies. The data on 218 consecutive cases of malignant diseases of hematopoietic and lymphoid tissues in Chernobyl clean-up workers diagnosed in 1996-2005 are given in comparison with the data of 2697 consecutive patients of general population of the same age group. The morphology and cytochemistry of bone marrow and peripheral blood cells were studied. Immunocytochemical techniques (APAAP, LSAB-AP) and the broad panel of monoclonal antibodies to lineage specific and differentiation antigens of leukocytes were employed for immunophenotyping leukemic cells. Various types of oncohematological diseases developing 10-20 years after Chernobyl accident were registered in a group of clean-up workers under study including myelodysplastic syndromes (MDS), acute leukemias (ALL and AML), chronic myelogenous leukemia (CML) and other chronic myeloproliferative diseases, chronic lymphocytic leukemia (B-CLL) and other chronic lymphoproliferative diseases of B and T cell origin. MDS percentage among patients of clean-up workers group tended to exceed MDS percentage in the group of patients representing the general population examined at the same period (4.58 vs. 3.70%). Among 34 AML cases, leukemia was preceded by MDS in seven patients. The relative contribution of CML to the total number of clean-up workers with leukemia was higher than the corresponding percentage value in general population examined at the same period (9.17 vs. 6.59%). B-CLL was a predominant form of hematopoietic malignancies in clean-up workers under study (25.68%). Nevertheless, B-CLL percentage in patients of clean-up workers group did not differ significantly from that in the patients of general population. The multiple myeloma percentage (7.79%) in the group of patients belonging to clean-up workers in our study turned out to be twice as much as in the patients of general population (4.0%). The verified diagnosis of tumors of hematopoietic and lymphoid tissue according to modern classification (EGIL, WHO) could be the prerequisite for further molecular genetic and analytical epidemiology study of leukemias that may be related to Chernobyl NPP accident consequences.

The selective cleanup of complex matrices and simultaneous separation of benzo[a]pyrene by solid-phase extraction with MgO microspheres as sorbents.

PubMed

Jin, Jing; Li, Yun; Zhang, Zhiping; Su, Fan; Qi, Peipei; Lu, Xianbo; Chen, Jiping

2011-12-23

A new method for the selective cleanup of complex matrices and simultaneous separation of benzo[a]pyrene (BaP) was developed in this study. This method was based on solid-phase extraction (SPE) using magnesium oxide microspheres as sorbents, and it eliminated interferences from various impurities, such as lipids, sulphur, pigments, halobenzenes, polychlorodibenzo-p-dioxins and polychlorodibenzofurans. Several parameters, including the volume of rinsing and eluting solvents, the type of loading solvents and SPE sorbents, were optimized systematically. The capability for impurity removal was verified by gel permeation chromatography, gas chromatography, and liquid chromatography. Compared to commercial sorbents (silica gel, florisil and alumina), MgO microspheres exhibited excellent performance in the selective isolation of BaP and removal of impurities. The proposed method was applied to detect BaP in complex samples (sediments, soils, fish, and porcine liver). The limit of quantification (LOQ) was 1.04 ngL(-1), and the resulting regression coefficient (r(2)) was greater than 0.999 over a broad concentration range (9.5-7600 ngL(-1)). In contrast to traditional methods, the proposed method can give rise to higher recovery (85.1-100.8%) and better selectivity with simpler operation and less consumption of organic solvents (20-40 mL). Copyright © 2011 Elsevier B.V. All rights reserved.

PFB coal fired combined cycle development program. Advanced hot gas cleanup concept evaluation (Task 4. 3). Volume A. Aerodyne cyclone evaluation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

This report summarizes the results of testing of a rotary flow cyclone, manufactured by Aerodyne Development Corporation under license by Siemens Kraftwerk Union. This cyclone was selected for evaluation due to the unusually high separative efficiencies claimed by the manufacturer (based on developer data), and relative lack of open literature data. The most significant finding of this work was the observation that electrostatic forces could enhance or, in fact, dominate the separation process. Separative efficiencies, with electrostatic forces present, were found to be substantially independent of flow rate and, by inference, could be independent of unit size. This finding suggestsmore » that large cyclones with natural or augmented electrostatic forces employed in the hot gas cleanup train of the CFCC system may not suffer the performance degradation compared to small cyclones, as projected from conventional inertial theory. This is of special importance since the use of many small cyclones in parallel, or multicyclones, commonly suffers from fouling and this approach is not recommended in the CFCC application. The original objective of this investigation was to assess the relative merits of the Aerodyne cyclone separator. It was found from both the cold flow and the hot flow tests that its separative efficiencies are disappointingly poorer than expectations (in agreement with Westinghouse results), and even poorer than conventional cyclones.« less

Green Remediation Best Management Practices: Integrating Renewable Energy into Site Cleanup

EPA Pesticide Factsheets

The U.S. Environmental Protection Agency (EPA) Principles for Greener Cleanups outline the Agency's policy for evaluating and minimizing the environmental 'footprint' of activities undertaken when cleaning up a contaminated site.

Using the Triad Approach to Streamline Brownfields Site Assessment and Cleanup

EPA Pesticide Factsheets

EPA's Brownfields Technology Support Center (BTSC) has prepared this document to provide an educational tool for site owners, project managers, and regulators to help streamline assessment and cleanup activities at brownfields sites.

76 FR 10018 - Environmental Management Site-Specific Advisory Board, Idaho National Laboratory

Federal Register 2010, 2011, 2012, 2013, 2014

2011-02-23

... Idaho's 2015 Cleanup Vision Government Budget Cycle American Recovery and Reinvestment Act Idaho Cleanup.... The Deputy Designated Federal Officer is empowered to conduct the meeting in a fashion that will...

Simultaneous determination of multiclass pesticide residues in human plasma using a mini QuEChERS method.

PubMed

Srivastava, Anshuman; Rai, Satyajeet; Kumar Sonker, Ashish; Karsauliya, Kajal; Pandey, Chandra Prabha; Singh, Sheelendra Pratap

2017-06-01

Blood is one of the most assessable matrices for the determination of pesticide residue exposure in humans. Effective sample preparation/cleanup of biological samples is very important in the development of a sensitive, reproducible, and robust method. In the present study, a simple, cost-effective, and rapid gas chromatography-tandem mass spectrometry method has been developed and validated for simultaneous analysis of 31 multiclass (organophosphates, organochlorines, and synthetic pyrethroids) pesticide residues in human plasma by means of a mini QuEChERS (quick, easy, cheap, effective, rugged, and safe) method. We have adopted a modified version of the QuEChERS method, which is primarily used for pesticide residue analysis in food commodities. The QuEChERS method was optimized by use of different extraction solvents and different amounts and combinations of salts and sorbents (primary-secondary amines and C 18 ) for the dispersive solid-phase extraction step. The results show that a combination of ethyl acetate with 2% acetic acid, magnesium sulfate (0.4 g), and solid-phase extraction for sample cleanup with primary-secondary amines (50 mg) per 1-mL volume of plasma is the most suitable for generating acceptable results with high recoveries for all multiclass pesticides from human plasma. The mean recovery ranged from 74% to 109% for all the analytes. The limit of quantification and limit of detection of the method ranged from 0.12 to 13.53 ng mL -1 and from 0.04 to 4.10 ng mL -1 respectively. The intraday precision and the interday precision of the method were 6% or less and 11% or less respectively. This method would be useful for the analysis of a wide range of pesticides of interest in a small volume of clinical and/or forensic samples to support biomonitoring and toxicological applications. Graphical Abstract Pesticide residues analysis in human plasma using mini QuEChERS method.

Pesticide analysis in coffee leaves using a quick, easy, cheap, effective, rugged and safe approach and liquid chromatography tandem mass spectrometry: Optimization of the clean-up step.

PubMed

Trevisan, Maria Teresa Salles; Owen, Robert Wyn; Calatayud-Vernich, Pau; Breuer, Andrea; Picó, Yolanda

2017-08-25

An analytical method using a quick, easy, cheap, effective, rugged and safe (QuEChERS) procedure for multi-residue determination of 52 pesticides in coffee leaf extractshas been developed and validated according to SANTE/11945/2015 guidelines. Different sorbent combinations for dispersive solid phase extraction (d-SPE) clean-up as well as dispersive liquid-liquid microextraction (DLLME) were tested. The relative standard deviations (RSDs) for the recovery of 87-94% of pesticides added to coffee leaf extracts,was ≤20% for samples spiked at concentrations up to 50ng*g -1 depending on the clean-up procedures. However, samples spiked with a 100ng*g -1 pesticide mixture gave RSDs>20% for most pesticides when d-SPE was carried out adding Supelclean ENVI-Carb 120/400. To explain this fact,the secondary metabolic profile was analyzed in all the extraction and clean-up procedures. Only in the clean-up procedure with the addition of Supel QuE Z-Sep+, does caffeine show a constant adsorption between blank and spiked samples. In other clean-up procedures, the amount of caffeine was higher in those samples spiked with pesticides. This indicates competition between caffeine and pesticides for adsorption to the sorbent. Addition of Supel QuE Z-Sep+ to the procedure revealed only a 32% matrix effect, whereas using PSA+ C18 the matrix effect was close to 97%. The process efficiency is up to 54% with the addition of Supel QuE Z-Sep+ and just up to 7% for the other clean-up procedures. The method was successfully tested in coffee leaves from different types of cultivars. Pesticides were not detected in organic coffee leaf extracts, but thiametoxan was clearly detected in 50% of coffee leaf extracts harvested from coffee trees grown under traditional conditions as determined by UHPLC-TOFMSLC/QqTOF-MS/MS. Copyright © 2017 Elsevier B.V. All rights reserved.

Multi-class multi-residue analysis of veterinary drugs in meat using enhanced matrix removal lipid cleanup and liquid chromatography-tandem mass spectrometry.

PubMed

Zhao, Limian; Lucas, Derick; Long, David; Richter, Bruce; Stevens, Joan

2018-05-11

This study presents the development and validation of a quantitation method for the analysis of multi-class, multi-residue veterinary drugs using lipid removal cleanup cartridges, enhanced matrix removal lipid (EMR-Lipid), for different meat matrices by liquid chromatography tandem mass spectrometry detection. Meat samples were extracted using a two-step solid-liquid extraction followed by pass-through sample cleanup. The method was optimized based on the buffer and solvent composition, solvent additive additions, and EMR-Lipid cartridge cleanup. The developed method was then validated in five meat matrices, porcine muscle, bovine muscle, bovine liver, bovine kidney and chicken liver to evaluate the method performance characteristics, such as absolute recoveries and precision at three spiking levels, calibration curve linearity, limit of quantitation (LOQ) and matrix effect. The results showed that >90% of veterinary drug analytes achieved satisfactory recovery results of 60-120%. Over 97% analytes achieved excellent reproducibility results (relative standard deviation (RSD) < 20%), and the LOQs were 1-5 μg/kg in the evaluated meat matrices. The matrix co-extractive removal efficiency by weight provided by EMR-lipid cartridge cleanup was 42-58% in samples. The post column infusion study showed that the matrix ion suppression was reduced for samples with the EMR-Lipid cartridge cleanup. The reduced matrix ion suppression effect was also confirmed with <15% frequency of compounds with significant quantitative ion suppression (>30%) for all tested veterinary drugs in all of meat matrices. The results showed that the two-step solid-liquid extraction provides efficient extraction for the entire spectrum of veterinary drugs, including the difficult classes such as tetracyclines, beta-lactams etc. EMR-Lipid cartridges after extraction provided efficient sample cleanup with easy streamlined protocol and minimal impacts on analytes recovery, improving method reliability and consistency. Copyright © 2018 Elsevier B.V. All rights reserved.

Engineering Forum Issue Paper: Online Hazardous Waste Cleanup Technical Resources

EPA Pesticide Factsheets

This issue paper is intended to give the reader examples of some online technical resources that can assist with hazardous waste cleanups in the Superfund, Resource Conservation and Recovery Act (RCRA), and Brownfields programs.

24 CFR 598.215 - What are the purpose and content of the strategic plan?

Code of Federal Regulations, 2014 CFR

2014-04-01

... preserve the environment and historic landmarks, address “brownfields” clean-up and redevelopment, explore..., Environmental Cleanup Cost Deduction (i.e., “Brownfields Tax Incentive”), and the Work Opportunity Tax Credit...

24 CFR 598.215 - What are the purpose and content of the strategic plan?

Code of Federal Regulations, 2013 CFR

2013-04-01

... preserve the environment and historic landmarks, address “brownfields” clean-up and redevelopment, explore..., Environmental Cleanup Cost Deduction (i.e., “Brownfields Tax Incentive”), and the Work Opportunity Tax Credit...

24 CFR 598.215 - What are the purpose and content of the strategic plan?

Code of Federal Regulations, 2012 CFR

2012-04-01

... preserve the environment and historic landmarks, address “brownfields” clean-up and redevelopment, explore..., Environmental Cleanup Cost Deduction (i.e., “Brownfields Tax Incentive”), and the Work Opportunity Tax Credit...

EPA Completes Reviews of 14 New England Site Cleanups during FY’ 2017

EPA Pesticide Factsheets

EPA has completed comprehensive reviews of site cleanups at 14 National Priorities List Sites (Superfund Sites), including four Federal Facilities, across New England by performing required Five-Year Reviews of each site.

Report: EPA Needs to Track Compliance with Superfund Cleanup Requirements

EPA Pesticide Factsheets

Report #08-P-0141, April 28, 2008. According to EPA’s Superfund information system, there were 3,397 active Superfund enforcement instruments to ensure cleanups at National Priorities List sites as of September 30, 2007.

Introduction to Energy Conservation and Production at Waste Cleanup Sites

EPA Pesticide Factsheets

This issue paper, prepared by EPA's Engineering Forum under the Technical Support Project, provides an overview on the considerations for energy conservation and production during the design and (O&M) phases of waste cleanup projects.

EPA Begins Reviews of 24 New England Site Cleanups during Current Fiscal Year

EPA Pesticide Factsheets

EPA plans to conduct comprehensive reviews of site cleanups at 24 National Priorities List Sites (Superfund Sites), including two Federal Facilities, across New England by performing required Five-Year Reviews of sites.

Trace analysis of glyphosate in water by capillary electrophoresis on a chip with high sample volume loadability.

PubMed

Horčičiak, Michal; Masár, Marián; Bodor, Róbert; Danč, Ladislav; Bel, Peter

2012-03-01

A new method for the determination of trace glyphosate (GLYP), non-selective pesticide, by CZE with online ITP pre-treatment of drinking waters on a column-coupling (CC) chip has been developed. CC chip was equipped with two injection channels of 0.9 and 9.9 μL volumes, two separation channels of 9.3 μL total volume and a pair of conductivity detectors. A very effective ITP sample clean-up performed in the first channel at low pH (3.2) was introduced for quick CZE resolution and detection of GLYP carried out at higher pH (6.1) in the second channel on the CC chip. The LOD for GLYP was estimated at 2.5 μg/L (15 nmol/L) using a 9.9 |mL volume of the injection channel. ITP-CZE analyses of model and real samples have provided very favorable intra-day (0.1-1.2% RSD) and inter-day (2.9% RSD) repeatabilities of the migration time for GLYP while 0.2-6.9% RSD values were typical for the peak area data. Recoveries of GLYP in spiked drinking water varied in the range of 99-109%. A minimum pre-treatment of drinking water (degassing and dilution) and a short analysis time (ca. 10 min) were distinctive features of ITP-CZE determinations of GLYP on the CC chip with high sample volume loaded, as well. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Risk-Based Decision Making Case Study: Application at a Superfund Cleanup.

ERIC Educational Resources Information Center

Blacker, Stanley; Goodman, Daniel

1994-01-01

Describes a case study comparing an integrated approach to Superfund cleanup with traditional approaches at a particular Superfund site. Emphasizes ways to save time and money while still achieving the desired risk reduction level. (LZ)

IMMUNOASSAY ANALYSIS FOR CHLORPYRIFOS IN FOODS

EPA Science Inventory

Chlorpyrifos is widely used in agriculture on fruits and vegetables. The tolerances for chlorpyrifos on produce range from 0.1-8.0 ppm. Residue detection is commonly performed by gas chromatography following various cleanup procedures. However, the required cleanup can make ...

Considering Traditional Ecological Knowledge (TEK) During the Cleanup Process

EPA Pesticide Factsheets

This memorandum provides direction to improve the decision-making process as it relates to site assessment, characterization, and cleanup activities, to ensure EPA's Office of Land and Emergency Management is considering TEK when tribes provide it to EPA.

Risk Assessment Approach for the Hanford Site River Corridor Closure Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thomson, J.E.; Weiss, S.G.; Sands, J.P.

2007-07-01

The river corridor portion of the U.S. Department of Energy's (DOE) Hanford Site includes the 100 Area and 300 Area, which border the Columbia River and cover 565 km{sup 2} (218 mi{sup 2}). The River Corridor Closure (RCC) Project scope of work includes 486 contaminated facilities, 4 of 9 deactivated plutonium production reactors, and 370 waste disposal sites. DOE's cleanup actions in the river corridor were initiated in 1994 under the Comprehensive Environmental Response, Compensation, and Liability Act of 1981 (42 U.S.C. 9601, et seq.) (CERCLA) and included source and groundwater operable units (OUs). DOE's RCC Project, awarded to Washingtonmore » Closure Hanford (WCH) in 2005, focuses on source OUs and has allowed cleanup actions to continue in the 100 and 300 Areas with completion by 2013. The regulatory authorization for cleanup actions at source OUs in the river corridor consists primarily of interim action records of decision (RODs), which were supported by qualitative risk assessments and limited field investigations. A key to establishing final cleanup decisions and proceeding toward final CERCLA closeout is completion of quantitative baseline risk assessment activities. Baseline risk assessment is necessary to determine whether cleanup actions are protective of human health and the environment and to identify any course corrections needed to ensure that current and future cleanup actions are protective. Because cleanup actions are ongoing under interim action RODs, it is desirable to establish the final cleanup decision bases as early as possible to minimize the impacts of any identified course corrections to the cleanup approach. Risk assessment is being performed by WCH as the River Corridor Baseline Risk Assessment (RCBRA). The RCBRA uses a multi-step process that summarizes existing data; uses the data quality objectives process to identify both data gaps and unresolved issues through public workshops; and solicits input from regulators, trustees, and stakeholders. Sampling and analysis plans are then developed to document quality requirements and identify field sample collection approaches. After required data are collected, the risks to human health and the environment are assessed. Sampling of upland, riparian, and near-shore environments for the 100/300 Area Component was performed in 2005 and 2006. The 100/300 Area Component includes former operational/reactor areas. The results of these efforts will be incorporated into a mid-2007 draft risk assessment report for the 100/300 Area Component of the RCBRA. Adapting methodology developed from the 100/300 Area Component, the Inter-Areas risk assessment will be conducted for the riparian and near-shore environments. The Inter-Areas Component includes shoreline areas between former operational areas addressed in the 100/300 Area Component. The Inter-Areas risk assessment will supplement results from the 100/300 Area Component to provide a more complete analysis of residual risks in the river corridor. Plans for the final element of the RCBRA, the Columbia River Component, are being developed by DOE and currently is not part of the RCC Project. The Columbia River Component includes the reach of the Columbia River located adjacent to the Hanford Site and reaches downstream to an undetermined boundary. Recommendations for final cleanup decisions at source units within the river corridor, based in part on the risk assessment results, will be presented for future public review in a River Corridor Source Unit Proposed Plan. To form an integrated cleanup approach for the river corridor, the RCBRA results for the source units require integration with risk assessment results from groundwater cleanup actions managed by other contractors. WCH's risk assessment task includes development of an integration strategy for activities leading up to the final regulatory decisions for all OUs in the river corridor. (authors)« less

Risk assessment guidance for Superfund: Volume 1 -- Human health evaluation manual. Supplement to Part A: Community involvement in Superfund risk assessments

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1999-03-01

The purpose of the guidance document is to provide the site team--risk assessor, remedial project manager (RPM), and community involvement coordinator--with information to improve community involvement in the Superfund risk assessment process. Specifically, the document: provides suggestions for how Superfund staff and community members can work together during the early stages of Superfund cleanup; identifies where, within the framework of the human health risk assessment methodology, community input can augment and improve EPA`s estimates of exposure and risk; recommends questions the site team should ask the community; and illustrates why community involvement is valuable during the human health assessment atmore » Superfund sites.« less

Hazardous Waste Clean-Up Information (CLU-IN) On-line Characterization and Remediation Databases Fact Sheet

EPA Pesticide Factsheets

This fact sheet provides an overview of the 10 on-line characterization and remediation databases available on the Hazardous Waste Clean-Up Information (CLU-IN) website sponsored by the U.S. Environmental Protection Agency.

Report: Some States Cannot Address Assessment Needs and Face Limitations in Meeting Future Superfund Cleanup Requirements

EPA Pesticide Factsheets

Report #2004-P-00027, September 1, 2004. The five States have established hazardous waste site cleanup programs that address contaminated sites posing human health and environmental risks ranging from low to high.

40 CFR 761.366 - Cleanup equipment.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Cleanup equipment. 761.366 Section 761.366 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT POLYCHLORINATED BIPHENYLS (PCBs) MANUFACTURING, PROCESSING, DISTRIBUTION IN COMMERCE, AND USE PROHIBITIONS Double...

CONTAMINANTS AND REMEDIAL OPTIONS AT SELECTED METAL-CONTAMINATED SITES

EPA Science Inventory

This document provides information that facilitates characterization of the site and selection of treatment technologies at metals-contaminated sites that would be capable of meeting site-specific cleanup levels. he document does not facilitate the determination of cleanup levels...

40 CFR 761.120 - Scope.

Code of Federal Regulations, 2010 CFR

2010-07-01

... with the particular spill. These factors may mitigate expected exposures and risks or make cleanup to... spill situations in which site-specific risk factors may warrant additional cleanup to more stringent... numerical decontamination levels is clearly unwarranted because of risk-mitigating factors, that compliance...

40 CFR 761.120 - Scope.

Code of Federal Regulations, 2011 CFR

2011-07-01

... with the particular spill. These factors may mitigate expected exposures and risks or make cleanup to... spill situations in which site-specific risk factors may warrant additional cleanup to more stringent... numerical decontamination levels is clearly unwarranted because of risk-mitigating factors, that compliance...

Notification: CTS Asheville Superfund Site Update: Sampling, Monitoring, Communication and Opportunities for Cleanup Efficiencies

EPA Pesticide Factsheets

Project #OPE-FY14-0044, July 22, 2014. The EPA OIG plans to begin preliminary research of the EPA's sampling, monitoring, communication and opportunities for cleanup efficiencies for the CTS Asheville Superfund Site, North Carolina.

Plating Inc. Site Fact Sheet: EPA to Begin Cleanup of Hazardous Waste

EPA Pesticide Factsheets

Hazardous waste cleanup and local community outreach around the Plating Inc. site at 888 N. Prior Ave.in St. Paul. The former industrial facility specialized in zinc and chromate plating of aluminum and is now abandoned.

48 CFR 970.1504-1-9 - Special considerations: Cost-plus-award-fee.

Code of Federal Regulations, 2012 CFR

2012-10-01

....e., nuclear energy processing, industrial environmental cleanup); (iii) Construction of facilities... industrial/DOE settings (i.e., nuclear energy, chemical or petroleum processing, industrial environmental... industrial/DOE settings (i.e., nuclear energy, chemical processing, industrial environmental cleanup); (ii...

48 CFR 970.1504-1-9 - Special considerations: Cost-plus-award-fee.

Code of Federal Regulations, 2014 CFR

2014-10-01

....e., nuclear energy processing, industrial environmental cleanup); (iii) Construction of facilities... industrial/DOE settings (i.e., nuclear energy, chemical or petroleum processing, industrial environmental... industrial/DOE settings (i.e., nuclear energy, chemical processing, industrial environmental cleanup); (ii...

48 CFR 970.1504-1-9 - Special considerations: Cost-plus-award-fee.

Code of Federal Regulations, 2013 CFR

2013-10-01

....e., nuclear energy processing, industrial environmental cleanup); (iii) Construction of facilities... industrial/DOE settings (i.e., nuclear energy, chemical or petroleum processing, industrial environmental... industrial/DOE settings (i.e., nuclear energy, chemical processing, industrial environmental cleanup); (ii...

A Decision-Making Framework for Cleanup of Sites Impacted with Light Non-Aqueous Phase Liquids (LNAPL)

EPA Pesticide Factsheets

This document has been prepared by the Remediation Technologies Development Forum (RTDF) NAPL Cleanup Alliance to provide a guide to practicable and reasonable approaches for management of LNAPL petroleum hydrocarbons in the subsurface.

48 CFR 970.1504-1-9 - Special considerations: Cost-plus-award-fee.

Code of Federal Regulations, 2010 CFR

2010-10-01

....e., nuclear energy processing, industrial environmental cleanup); (iii) Construction of facilities... industrial/DOE settings (i.e., nuclear energy, chemical or petroleum processing, industrial environmental... industrial/DOE settings (i.e., nuclear energy, chemical processing, industrial environmental cleanup); (ii...

48 CFR 970.1504-1-9 - Special considerations: Cost-plus-award-fee.

Code of Federal Regulations, 2011 CFR

2011-10-01

....e., nuclear energy processing, industrial environmental cleanup); (iii) Construction of facilities... industrial/DOE settings (i.e., nuclear energy, chemical or petroleum processing, industrial environmental... industrial/DOE settings (i.e., nuclear energy, chemical processing, industrial environmental cleanup); (ii...

Glufosinate ammonium clean-up procedure from water samples using SPE

NASA Astrophysics Data System (ADS)

Tayeb M., A.; Ismail B., S.; Mardiana-Jansar, K.; Ta, Goh Choo; Agustar, Hani Kartini

2015-09-01

For the determination of glufosinate ammonium residue in soil and water samples, different solid phase extraction (SPE) sorbent efficiency was studied. Four different SPE sorbents i.e.: CROMABOND PS-H+, CROMABOND PS-OH-, ISOLUTE ENV+, Water Sep-Pak and OASIS HLB were used. Sample clean-up performance was evaluated using high performance liquid chromatography (Agilent 1220 infinity LC) with fluorescence detector. Detection of FMO-derivatives was done at λ ex = 260 nm and λ em= 310 nm. OASIS HLB column was the most suitable for the clean-up in view of the overall feasibility of the analysis.

[Genomic disorders in the mononuclear blood cells of those who worked in the cleanup of the accident at the Chernobyl Atomic Electric Power Station].

PubMed

Butenko, Z A; Smirnova, I A; Zak, K P; Mikhaĭlovskaia, E V; Ianok, E A; Kishinskaia, E G

1998-01-01

The results of molecular investigations of blood mononuclears from 120 clean-up workers after 7-9 years of Chernobyl accident with the total exposure radiation doses ranging from 5 to 76 cGr are presented. Structural polymorphism of the leukemia associated bcr and ribosomal RNA (rRNA) genes were studied using Southern blot hybridization. Allelic polymorphism of bcr gene with characteristic for leukemia allele distribution was detected in 16.6%. Rearrangements of rRNA genes were observed in 13% of Chernobyl accident clean-up workers.

Hebei Spirit Oil Spill Exposure and Subjective Symptoms in Residents Participating in Clean-Up Activities

PubMed Central

Cheong, Hae-Kwan; Lee, Jong Seong; Kwon, Hojang; Ha, Eun-Hee; Hong, Yun-Chul; Choi, Yeyong; Jeong, Woo-Chul; Hur, Jongil; Lee, Seung-Min; Kim, Eun-Jung; Im, Hosub

2011-01-01

Objectives This study was conducted to examine the relationship between crude oil exposure and physical symptoms among residents participating in clean-up work associated with the Hebei Spirit oil spill, 2007 in Korea. Methods A total of 288 residents responded to a questionnaire regarding subjective physical symptoms, sociodemographic characteristics and clean-up activities that occurred between two and eight weeks after the accident. Additionally, the urine of 154 of the respondents was analyzed for metabolites of volatile organic compounds (VOCs) and polycyclic aromatic hydrocarbons (PAHs) and heavy metals. To compare the urinary levels of exposure biomarkers, the urine of 39 inland residents who were not directly exposed to the oil spill were analyzed. Results Residents exposed to oil remnants through clean-up work showed associations between physical symptoms and the exposure levels defined in various ways, including days of work, degree of skin contamination, and levels of some urinary exposure biomarkers of VOCs, metabolites and metals, although no major abnormalities in urinary exposure biomarkers were observed. Conclusions This study provides evidence of a relationship between crude oil exposure and acute human health effects and suggests the need for follow-up to evaluate the exposure status and long-term health effects of clean-up participants. PMID:22125768

Impact of pH on the stability and the cross-reactivity of ochratoxin A and citrinin.

PubMed

Bazin, Ingrid; Faucet-Marquis, Virginie; Monje, Marie-Carmen; El Khoury, Micheline; Marty, Jean-Louis; Pfohl-Leszkowicz, Annie

2013-11-28

Mycotoxins are secondary metabolites produced by several fungi contaminating crops. In several countries, the maximum permitted levels of mycotoxins are found in foodstuffs and feedstuffs. The common strategy of mycotoxin analysis involves extraction, clean-up and quantification by chromatography. In this paper, we analyzed the reasons of underestimation of ochratoxin A (OTA) content in wine, and overestimation of OTA in wheat, depending on the pH of the clean-up step and the simultaneous presence of citrinin (CIT). We demonstrated that the increase of pH by adding polyethylene glycol (PEG) to wine led to an underestimation of OTA by conversion of OTA into open ring ochratoxin A OP-OA. In comparing three methods of extraction and clean-up for the determination of OTA and CIT in wheat--(i) an inter-laboratory validated method for OTA in cereals using immunoaffinity column clean-up (IAC) and extraction by acetonitrile/water; (ii) a validated method using IAC and extraction with 1% bicarbonate Na; and (iii) an in-house validated method based on acid liquid/liquid extraction--we observed an overestimation of OTA after immunoaffinity clean-up when CIT is also present in the sample, whereas an underestimation was observed when OTA was alone. Under neutral and alkaline conditions, CIT was partially recognized by OTA antibodies.

EPA waiver of ground water cleanup standards in NY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hess, A.A.

1995-11-01

EPA may invoke a technical impracticability (TI) waiver at a site when the Agency determines that it is technically impracticable from an engineering perspective to attain cleanup standards within a reasonable time period. The October 6, 1994 TI waiver of ground water cleanup standards at the G.E./Moreau Superfund Site in New York is the first post-Record of Decision (ROD) TI waiver granted by EPA since issuance of the September 1993 guidance on technical impracticability of ground water restoration. In the 1987 ROD, EPA selected natural gradient flushing and treatment as the ground water remedy and estimated that TCE-contaminated ground watermore » within the unconsolidated aquifer at the Site would be restored to drinking water quality within decades. EPA`s subsequent reevaluation showed that cleanup of the ground water would take 200 years or more, regardless of the remedial technology employed, due to the presence of site-specific physical and chemical factors that limit the effectiveness of ground water remediation technologies. Following public participation activities, EPA issued the TI waiver as an Explanation of Significant Differences (ESD) to the ROD. The ESD revised the time frame expected for ground water restoration but did not reduce or change any of the required cleanup actions.« less

Impact of pH on the Stability and the Cross-Reactivity of Ochratoxin A and Citrinin

PubMed Central

Bazin, Ingrid; Faucet-Marquis, Virginie; Monje, Marie-Carmen; El Khoury, Micheline; Marty, Jean-Louis; Pfohl-Leszkowicz, Annie

2013-01-01

Mycotoxins are secondary metabolites produced by several fungi contaminating crops. In several countries, the maximum permitted levels of mycotoxins are found in foodstuffs and feedstuffs. The common strategy of mycotoxin analysis involves extraction, clean-up and quantification by chromatography. In this paper, we analyzed the reasons of underestimation of ochratoxin A (OTA) content in wine, and overestimation of OTA in wheat, depending on the pH of the clean-up step and the simultaneous presence of citrinin (CIT). We demonstrated that the increase of pH by adding polyethylene glycol (PEG) to wine led to an underestimation of OTA by conversion of OTA into open ring ochratoxin A OP-OA. In comparing three methods of extraction and clean-up for the determination of OTA and CIT in wheat—(i) an inter-laboratory validated method for OTA in cereals using immunoaffinity column clean-up (IAC) and extraction by acetonitrile/water; (ii) a validated method using IAC and extraction with 1% bicarbonate Na; and (iii) an in-house validated method based on acid liquid/liquid extraction—we observed an overestimation of OTA after immunoaffinity clean-up when CIT is also present in the sample, whereas an underestimation was observed when OTA was alone. Under neutral and alkaline conditions, CIT was partially recognized by OTA antibodies. PMID:24287570

Large-Scale Urban Decontamination; Developments, Historical Examples and Lessons Learned

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rick Demmer

2007-02-01

Recent terrorist threats and actual events have lead to a renewed interest in the technical field of large scale, urban environment decontamination. One of the driving forces for this interest is the real potential for the cleanup and removal of radioactive dispersal device (RDD or “dirty bomb”) residues. In response the U. S. Government has spent many millions of dollars investigating RDD contamination and novel decontamination methodologies. Interest in chemical and biological (CB) cleanup has also peaked with the threat of terrorist action like the anthrax attack at the Hart Senate Office Building and with catastrophic natural events such asmore » Hurricane Katrina. The efficiency of cleanup response will be improved with these new developments and a better understanding of the “old reliable” methodologies. Perhaps the most interesting area of investigation for large area decontamination is that of the RDD. While primarily an economic and psychological weapon, the need to cleanup and return valuable or culturally significant resources to the public is nonetheless valid. Several private companies, universities and National Laboratories are currently developing novel RDD cleanup technologies. Because of its longstanding association with radioactive facilities, the U. S. Department of Energy National Laboratories are at the forefront in developing and testing new RDD decontamination methods. However, such cleanup technologies are likely to be fairly task specific; while many different contamination mechanisms, substrate and environmental conditions will make actual application more complicated. Some major efforts have also been made to model potential contamination, to evaluate both old and new decontamination techniques and to assess their readiness for use. Non-radioactive, CB threats each have unique decontamination challenges and recent events have provided some examples. The U. S. Environmental Protection Agency (EPA), as lead agency for these emergency cleanup responses, has a sound approach for decontamination decision-making that has been applied several times. The anthrax contamination at the U. S. Hart Senate Office Building and numerous U. S. Post Office facilities are examples of employing novel technical responses. Decontamination of the Hart Office building required development of a new approach for high level decontamination of biological contamination as well as techniques for evaluating the technology effectiveness. The World Trade Center destruction also demonstrated the need for, and successful implementation of, appropriate cleanup methodologies. There are a number of significant lessons that can be gained from a look at previous large scale cleanup projects. Too often we are quick to apply a costly “package and dispose” method when sound technological cleaning approaches are available. Understanding historical perspectives, advanced planning and constant technology improvement are essential to successful decontamination.« less

Progress on Footprint Reduction at the Hanford Site - 12406

DOE Office of Scientific and Technical Information (OSTI.GOV)

McKenney, Dale E.; Seeley, Paul; Farabee, Al

2012-07-01

The Department of Energy (DOE) Office of Environmental Management (EM) continues to reduce the footprint of legacy sites throughout the EM complex. Footprint reduction is being accomplished by focusing cleanup activities on decontamination and demolition of excess contaminated facilities, soil and groundwater remediation, and solid waste disposition. All of these initiatives are being accomplished with established technologies in proven regulatory frameworks. Ultimately, completion of these environmental cleanup activities will reduce the monitoring and maintenance costs associated with managing large federal facilities, allowing EM to place more focus on other high priority cleanup efforts and facilitate a successful transition to land-termmore » stewardship of these sites. Through the American Recovery and Reinvestment Act (ARRA) investment, the Department's cleanup footprint has been reduced by 45 percent to date, from 2411 km{sup 2} (931 mi{sup 2}) to 1336 km{sup 2} (516 mi{sup 2}s). With this significant progress on footprint reduction, the Department is on track towards their goal to reduce its overall footprint by approximately 90 percent by 2015. In addition, some areas cleaned up may become available for alternate uses (i.e. recreation, conservation, preservation, industrialization or development). Much of the work to reduce the complex's footprint occurred at the Savannah River Site in South Carolina and the Hanford Site in Washington, but cleanup continues across the complex. Footprint reduction is progressing well at the Hanford Site, supported predominantly through ARRA investment. To date, 994 km{sup 2} (384 mi{sup 2}) (65%) of footprint reduction have been achieved at Hanford, with a goal to achieve a 90% reduction by Fiscal Year 2015. The DOE EM and DOE Richland Operations Office, continue to make great progress to reduce the legacy footprint of the Hanford Site. Footprint reduction is being accomplished by focusing cleanup activities on decontamination and demolition of excess facilities, both contaminated and uncontaminated, waste site cleanup activities, and debris pile removal. All of these activities can be accomplished with proven technologies and within established regulatory frameworks. Footprint reduction goals for Fiscal Year 2011 were exceeded, largely with the help of ARRA funding. As cleanup projects are completed and the total area requiring cleanup shrinks, overall costs for surveillance and maintenance operations and infrastructure services decrease. This work completion and decrease in funding requirements to maintain waste sites and antiquated facilities allows more focus on high priority site missions (i.e. groundwater remediation, tank waste disposition, etc.) and moves Site areas closer to transition from EM to the Legacy Management program. The progress in the Hanford footprint reduction effort will help achieve success in these other important mission areas. (authors)« less

40 CFR 761.61 - PCB remediation waste.

Code of Federal Regulations, 2012 CFR

2012-07-01

... care centers, endangered species habitats, estuaries, wetlands, national parks, national wildlife... ACT POLYCHLORINATED BIPHENYLS (PCBs) MANUFACTURING, PROCESSING, DISTRIBUTION IN COMMERCE, AND USE... least 30 days prior to the date that the cleanup of a site begins, the person in charge of the cleanup...

77 FR 10485 - Environmental Management Site-Specific Advisory Board, Idaho National Laboratory

Federal Register 2010, 2011, 2012, 2013, 2014

2012-02-22

... Status EM/National Nuclear Security Administration Integration Ecological Surveys Ground Water Waste Area... and site management in the areas of environmental restoration, waste management, and related... Idaho Cleanup Project (ICP) Workforce Reductions Advanced Mixed Waste Cleanup Project (AMWTP) Workforce...

Private-Sector Cleanup Expenditures and Transaction Costs at 18 Superfund Sites (1993)

EPA Pesticide Factsheets

Superfund allows the government either to clean up a site and recover its cost from the potentially responsible parties (PRPs) or to require the PRPs to undertake the cleanup themselves. This study examines private-sector expenditures and transaction-costs

40 CFR 147.3015 - Information to be considered for Class III wells.

Code of Federal Regulations, 2011 CFR

2011-07-01

... PROGRAMS Lands of the Navajo, Ute Mountain Ute, and All Other New Mexico Tribes § 147.3015 Information to... quality as required for aquifer cleanup by § 147.3011 of this subpart. (3) An aquifer cleanup plan if...

40 CFR 147.3015 - Information to be considered for Class III wells.

Code of Federal Regulations, 2010 CFR

2010-07-01

... PROGRAMS Lands of the Navajo, Ute Mountain Ute, and All Other New Mexico Tribes § 147.3015 Information to... quality as required for aquifer cleanup by § 147.3011 of this subpart. (3) An aquifer cleanup plan if...

An Introduction to the Cost of Engineering and Institutional Controls at Brownfield Properties

EPA Pesticide Factsheets

This fact sheet introduces and explores the costs of site cleanup and, where cleanup leaves site contamination that restricts reuse, outlines the engineering and institutional controls and their monitoring and maintenance costs over a longer time frame.

EPA Science Matters Newsletter: Greener Cleanups at Hazardous Waste Sites (Published August 2013)

EPA Pesticide Factsheets

Read about the EPA’s Smart Energy Resources Guide (SERG). The guide covers techniques for superfund managers to reduce cleanup emissions in a process called green remediation, and can be used by any site remediation and redevelopment manager.

Epidemiology of Late Health Effects in Ukrainian Chornobyl Cleanup Workers.

PubMed

Bazyka, Dimitry; Prysyazhnyuk, Anatoly; Gudzenko, Natalya; Dyagil, Iryna; Belyi, David; Chumak, Vadim; Buzunov, Volodymyr

2018-07-01

This article summarizes the results of 30 y of follow-up of cancer and noncancer effects in Ukrainian cleanup workers after the Chornobyl accident. The number of power plant employees and first responders with acute radiation syndrome under follow-up by the National Research Center for Radiation Medicine decreased from 179 in 1986-1991 to 105 in 2011-2015. Cancers and leukemia (19) and cardiovascular diseases (21) were the main causes of deaths among acute radiation syndrome survivors (54) during the postaccident period. Increased radiation risks of leukemia in the Ukrainian cohort of 110,645 cleanup workers exposed to low doses are comparable to those among survivors of the atomic bomb explosions in Japan in 1945. Additionally, an excess of chronic lymphocytic leukemia was demonstrated in the cleanup workers cohort for 26 y after the exposure. A significant excess of multiple myeloma incidence [standardized incidence rate (SIR) 1.61 %, 95% confidence interval (CI) 1.01-2.21], thyroid cancer (SIR 4.18, 95% CI 3.76-4.59), female breast cancer (SIR 1.57 CI 1.40-1.73), and all cancers combined (SIR 1.07; 95% CI 1.05-1.09) was registered. High prevalence was demonstrated for cardio- and cerebrovascular diseases and mental health changes. However, the reasons for the increases require further investigation. To monitor other possible late effects of radiation exposure in Chornobyl cleanup workers, analytical cohort and case-control studies need to include cardiovascular pathology, specifically types of potentially radiogenic cancers using a molecular epidemiology approach. Possible effects for further study include increased rates of thyroid, breast, and lung cancers and multiple myeloma; reduction of radiation risks of leukemia to population levels; and increased morbidity and mortality of cleanup workers from cardio- and cerebrovascular pathology.

Content Analysis of Vomit and Diarrhea Cleanup Procedures To Prevent Norovirus Infections in Retail and Food Service Operations.

PubMed

Chao, Morgan G; Dubé, Anne-Julie; Leone, Cortney M; Moore, Christina M; Fraser, Angela M

2016-11-01

Human noroviruses are the leading cause of foodborne disease in the United States, sickening 19 to 21 million Americans each year. Vomit and diarrhea are both highly concentrated sources of norovirus particles. For this reason, establishing appropriate cleanup procedures for these two substances is critical. Food service establishments in states that have adopted the 2009 or 2013 U.S. Food and Drug Administration Food Code are required to have a program detailing specific cleanup procedures. The aim of our study was to determine the alignment of existing vomit and diarrhea cleanup procedures with the 11 elements recommended in Annex 3 of the 2011 Supplement to the 2009 Food Code and to determine their readability and clarity of presentation. In July 2015, we located vomit and diarrhea cleanup procedures by asking Norovirus Collaborative for Outreach, Research, and Education stakeholders for procedures used by their constituency groups and by conducting a Google Advanced Search of the World Wide Web. We performed content analysis to determine alignment with the recommendations in Annex 3. Readability and clarity of presentation were also assessed. A total of 38 artifacts were analyzed. The mean alignment score was 7.0 ± 1.7 of 11 points; the mean clarity score was 6.7 ± 2.5 of 17 points. Only nine artifacts were classified as high clarity, high alignment. Vomit and diarrhea cleanup procedures should align with Annex 3 in the Food Code and should, as well, be clearly presented; yet, none of the artifacts completely met both conditions. To reduce the spread of norovirus infections in food service establishments, editable guidelines are needed that are aligned with Annex 3 and are clearly written, into which authors could insert their facility-specific information.

Acetonitrile extraction and dual-layer solid phase extraction clean-up for pesticide residue analysis in propolis.

PubMed

Oellig, Claudia

2016-05-06

Propolis is a very complex mixture of substances that is produced by honey bees and is known to be a rather challenging matrix for residue analysis. Besides resins, flavonoids and phenols, high amount of wax is co-extracted resulting in immense matrix effects. Therefore a suitable clean-up is crucial and indispensable. In this study, a reliable solid phase extraction (SPE) clean-up was developed for pesticide residue analysis in propolis. The clean-up success was quickly and easily monitored by high-performance thin-layer chromatography with different detection possibilities. The final method consists of the extraction of propolis with acetonitrile according to the QuEChERS method followed by an effective extract purification on dual-layer SPE cartridges with spherical hydrophobic polystyrene-divinylbenzene resin/primary secondary amine as sorbent and a mixture of toluene/acetone (95:5, v/v) for elution. Besides fat-soluble components like waxes, flavonoids, and terpenoids, more polar compounds like organic acids, fatty acids, sugars and anthocyanins were also removed to large extent. Method performance was assessed by recovery experiments at spiking levels of 0.5 and 1mg/kg (n=5) for fourteen pesticides that are relevant for propolis. Mean recoveries determined by HPLC-MS against solvent standards were between 40 and 101%, while calculation against matrix-matched standards provided recoveries of 79-104%. Precision of recovery, assessed by relative standard deviations, were below 9%. Thus, the developed dual-layer SPE clean-up enables the reliable pesticide residue analysis in propolis and provides a suitable alternative to time-consuming clean-up procedures proposed in literature. Copyright © 2016 Elsevier B.V. All rights reserved.

Structured parenting of toddlers at high versus low genetic risk: two pathways to child problems.

PubMed

Leve, Leslie D; Harold, Gordon T; Ge, Xiaojia; Neiderhiser, Jenae M; Shaw, Daniel; Scaramella, Laura V; Reiss, David

2009-11-01

Little is known about how parenting might offset genetic risk to prevent the onset of child problems during toddlerhood. We used a prospective adoption design to separate genetic and environmental influences and test whether associations between structured parenting and toddler behavior problems were conditioned by genetic risk for psychopathology. The sample included 290 linked sets of adoptive families and birth mothers and 95 linked birth fathers. Genetic risk was assessed via birth mother and birth father psychopathology (anxiety, depression, antisociality, and drug use). Structured parenting was assessed via microsocial coding of adoptive mothers' behavior during a cleanup task. Toddler behavior problems were assessed with the Child Behavior Checklist. Controlling for temperamental risk at 9 months, there was an interaction between birth mother psychopathology and adoptive mothers' parenting on toddler behavior problems at 18 months. The interaction indicated two pathways to child problems: structured parenting was beneficial for toddlers at high genetic risk but was related to behavior problems for toddlers at low genetic risk. This crossover interaction pattern was replicated with birth father psychopathology as the index of genetic risk. The effects of structured parenting on toddler behavior problems varied as a function of genetic risk. Children at genetic risk might benefit from parenting interventions during toddlerhood that enhance structured parenting.

EPA Handbook on the Benefits, Costs, and Impacts of Land Cleanup and Reuse (2011)

EPA Pesticide Factsheets

This Handbook describes EPA‘s land cleanup and reuse programs and outlines some of the unique aspects that have complicated efforts to develop suitable methods for estimating benefits. It clarifies the differences between types of economic analyses—specif

EPA Uses Greener Cleanup Practices to Reduce Environmental Footprint at Telles Ranch UST Site, Colorado River Indian Tribes Reservation

EPA Pesticide Factsheets

Learn about the work of EPA’s Pacific Southwest Underground Storage Tank (UST) program to reduce its environmental footprint by using greener cleanup practices at the Telles Ranch leaking UST site in Arizona.

Frequently Asked Questions (FAQs) for Fiscal Year (FY) 14 Brownfields Assessment, Revolving Loan Fund and Cleanup Grants

EPA Pesticide Factsheets

EPA prepared these Frequently Asked Questions and Answers to assist prospective applicants with preparing Brownfields Assessment, Revolving Loan Fund and Cleanup grant proposals for the FY14 competition. Please review the FY 2014 proposal guidelines/Reques

PHYTOREMEDIATION: USING PLANTS TO CLEAN UP CONTAMINATED SOIL, GROUNDWATER, AND WASTEWATER

EPA Science Inventory

Phytoremediation is an emerging cleanup technology for contaminated soils, groundwater, and wastewater that is both low-tech and low-cost. The cleanup technology is defined as the use of green plants to remove, contain, or render harmless such environmental contaminants as heavy ...

33 CFR 137.55 - Searches for recorded environmental cleanup liens.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Searches for recorded environmental cleanup liens. 137.55 Section 137.55 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE POLLUTION FINANCIAL RESPONSIBILITY AND COMPENSATION OIL SPILL...

33 CFR 137.55 - Searches for recorded environmental cleanup liens.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Searches for recorded environmental cleanup liens. 137.55 Section 137.55 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE POLLUTION FINANCIAL RESPONSIBILITY AND COMPENSATION OIL SPILL...

33 CFR 137.55 - Searches for recorded environmental cleanup liens.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Searches for recorded environmental cleanup liens. 137.55 Section 137.55 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE POLLUTION FINANCIAL RESPONSIBILITY AND COMPENSATION OIL SPILL...

33 CFR 137.55 - Searches for recorded environmental cleanup liens.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Searches for recorded environmental cleanup liens. 137.55 Section 137.55 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE POLLUTION FINANCIAL RESPONSIBILITY AND COMPENSATION OIL SPILL...

33 CFR 137.55 - Searches for recorded environmental cleanup liens.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Searches for recorded environmental cleanup liens. 137.55 Section 137.55 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE POLLUTION FINANCIAL RESPONSIBILITY AND COMPENSATION OIL SPILL...

40 CFR 761.243 - Standard wipe sample method and size.

Code of Federal Regulations, 2010 CFR

2010-07-01

..., AND USE PROHIBITIONS Determining a PCB Concentration for Purposes of Abandonment or Disposal of Natural Gas Pipeline: Selecting Sample Sites, Collecting Surface Samples, and Analyzing Standard PCB Wipe.../Rinse Cleanup as Recommended by the Environmental Protection Agency PCB Spill Cleanup Policy,” dated...

Dynamics of the Genetic Diversity of Subsurface Microbial Communities and Their Applications to Contaminated Site Cleanups

EPA Science Inventory

When compared to traditional approaches, the utilization of molecular and genomic techniques to soil and groundwater cleanup investigations can reduce inherent parameter variability when conducting bench and pilot-scale investigations or carrying out full-scale field applications...

Evaluation of beach cleanup effects using linear system analysis.

PubMed

Kataoka, Tomoya; Hinata, Hirofumi

2015-02-15

We established a method for evaluating beach cleanup effects (BCEs) based on a linear system analysis, and investigated factors determining BCEs. Here we focus on two BCEs: decreasing the total mass of toxic metals that could leach into a beach from marine plastics and preventing the fragmentation of marine plastics on the beach. Both BCEs depend strongly on the average residence time of marine plastics on the beach (τ(r)) and the period of temporal variability of the input flux of marine plastics (T). Cleanups on the beach where τ(r) is longer than T are more effective than those where τ(r) is shorter than T. In addition, both BCEs are the highest near the time when the remnants of plastics reach the local maximum (peak time). Therefore, it is crucial to understand the following three factors for effective cleanups: the average residence time, the plastic input period and the peak time. Copyright © 2014 Elsevier Ltd. All rights reserved.

Superfund at work: Hazardous waste cleanup efforts nationwide, Spring 1993 (Harvey and Knott Drum Site, New Castle County, Delaware)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

From 1963 to 1969, two acres of the Harvey and Knott Drum site in New Castle County, Delaware served as an open dump and burning area for sanitary, municipal, and industrial wastes. Sludge, paint pigment, and solvents contaminated the site until the State of Delaware and the US Environmental Protection Agency (EPA) intervened in 1981. Site conditions required a combination of traditional cleanup measures. After the immediate health threats posed by the site were eliminated, EPA reached an innovative, mixed funding settlement for long-term cleanup with two parties responsible for the site contamination. The following actions highlight the success ofmore » the Superfund program: An emergency removal of contaminants reduced immediate environmental and public health effects; A rapid assessment of ground water safeguarded drinking water supplies; and The full cooperation of General Motors (GM) expedited implementation of the cleanup, valued at $3.2 million.« less

Daubert v. Merrell: Opening floodgates of scientific uncertainty?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bibko, P.N.

1994-12-31

At last year`s plenary session on May 27, 1993, Col. John Glass, Deputy Director of the Army`s environmental program, acknowledged public pressure to expedite site restoration. A few days later, Gary Vest, Deputy Assistant Secretary for the Air Force told a Senate committee that clean-up levels should be relaxed depending upon intended land use. Soon after, EPA publicly announced support for relaxed clean-up levels depending upon use after restoration. Ironically, also on May 27, 1993, while EPA and the Department of Defense were considering the stringency of clean-up levels, the Environmental Defense Fund and Physicians for Social Responsibility were warningmore » the White House of the increasing health risks due to environmental contamination. The author emphasizes the need to set clean-up standards at levels that will assure protection of public health, and at the same time minimize the legal liability of those involved with the disposal or storage of hazardous waste.« less

Doses of Ukrainian female clean-up workers with diagnosed breast cancer.

PubMed

Chumak, Vadim V; Klymenko, Sergiy V; Zitzelsberger, Horst; Wilke, Christina; Rybchenko, Lyudmila A; Bakhanova, Elena V

2018-05-01

The Chernobyl reactor accident in 1986 has caused significant exposure to ionizing radiation of the Ukrainian population, in particular clean-up workers and evacuees from the exclusion zones. A study aiming at the discovery of radiation markers of the breast cancer was conducted from 2008 to 2015 within a collaborative project by HZM, LMU, and NRCRM. In this study, post-Chernobyl breast cancer cases both in radiation-exposed female patients diagnosed at age less than 60 from 1992 to 2014 and in non-exposed controls matched for residency, tumor type, age at diagnosis, TNM classification as well as tumor grading were investigated for molecular changes with special emphasis to copy number alterations and miRNA profiles. Cancer registry and clinical archive data were used to identify 435 breast cancer patients among female clean-up workers and 14 among evacuees from highly contaminated territories as candidates for the study. Of these, 129 breast cancer patients fit study inclusion criteria and were traced for individual reconstruction of the target organ (breast) doses. The doses were estimated for 71 exposed cases (clean-up workers and evacuees from which biomaterial was available for molecular studies and who agreed to participate in a dosimetric interview) by the use of the well-established RADRUE method, which was adjusted specifically for the assessment of breast doses. The results of 58 female clean-up workers showed a large inter-individual variability of doses in a range of about five orders of magnitude: from 0.03 to 929 mGy, with median of 5.8 mGy. The study provides the first quantitative estimate of exposures received by female clean-up workers, which represent a limited but very important group of population affected by the Chernobyl accident. The doses of 13 women evacuated after the accident who did not take part in the clean-up activities (from 4 to 45 mGy with median of 19 mGy) are in line with the previous estimates for the evacuees from Pripyat and the 30-km zone.

Challenges Achieved By Innovative Technologies Our Link to a Safer, Cleaner, Healthier Tomorrow - 12369

DOE Office of Scientific and Technical Information (OSTI.GOV)

Henderson, Heidi; Shoffner, Peggy; Lagos, Leonel E.

2012-07-01

The River Corridor Closure Project is the nation's largest environmental cleanup closure project where innovative technologies are being utilized to overcome DOE's environmental clean-up challenges. DOE provides a Technology Needs Statement that specifies their on-site challenges and the criteria to overcome those challenges. This allows for both the private sector and federally funded organizations to respond with solutions that meet their immediate needs. DOE selects the company based on their ability to reduce risk to human health and the environment, improve efficiency of the cleanup, and lower costs. These technologies are our link to a cleaner, safer, healthier tomorrow. (authors)

Evaluation of New Cleanup Agents for Analysis of Pesticide Residues in Tea.

PubMed

Ueda, Yuko; Honda, Katsuhisa

2017-01-01

We evaluated the effectiveness of new cleanup agents (S-NH 2 and S-Si) compared with other previously reported cleanup agents (octadecylsilane, graphitized carbon, aminopropyl and silica gel) for removal of interfering substances such as catechin and caffeine prior to analysis of pesticide residues in tea. S-NH 2 and S-Si were highly efficient in removal of catechin and caffeine, respectively. Recoveries of 80 pesticides using S-NH 2 and S-Si were tested, and more than 70% of pesticides showed recovery greater than 70%. These results indicate that S-NH 2 and S-Si agents will be useful for analysis of pesticide residues in tea.

Quick, easy, cheap, effective, rugged, and safe sample preparation approach for pesticide residue analysis using traditional detectors in chromatography: A review.

PubMed

Rahman, Md Musfiqur; Abd El-Aty, A M; Kim, Sung-Woo; Shin, Sung Chul; Shin, Ho-Chul; Shim, Jae-Han

2017-01-01

In pesticide residue analysis, relatively low-sensitivity traditional detectors, such as UV, diode array, electron-capture, flame photometric, and nitrogen-phosphorus detectors, have been used following classical sample preparation (liquid-liquid extraction and open glass column cleanup); however, the extraction method is laborious, time-consuming, and requires large volumes of toxic organic solvents. A quick, easy, cheap, effective, rugged, and safe method was introduced in 2003 and coupled with selective and sensitive mass detectors to overcome the aforementioned drawbacks. Compared to traditional detectors, mass spectrometers are still far more expensive and not available in most modestly equipped laboratories, owing to maintenance and cost-related issues. Even available, traditional detectors are still being used for analysis of residues in agricultural commodities. It is widely known that the quick, easy, cheap, effective, rugged, and safe method is incompatible with conventional detectors owing to matrix complexity and low sensitivity. Therefore, modifications using column/cartridge-based solid-phase extraction instead of dispersive solid-phase extraction for cleanup have been applied in most cases to compensate and enable the adaptation of the extraction method to conventional detectors. In gas chromatography, the matrix enhancement effect of some analytes has been observed, which lowers the limit of detection and, therefore, enables gas chromatography to be compatible with the quick, easy, cheap, effective, rugged, and safe extraction method. For liquid chromatography with a UV detector, a combination of column/cartridge-based solid-phase extraction and dispersive solid-phase extraction was found to reduce the matrix interference and increase the sensitivity. A suitable double-layer column/cartridge-based solid-phase extraction might be the perfect solution, instead of a time-consuming combination of column/cartridge-based solid-phase extraction and dispersive solid-phase extraction. Therefore, replacing dispersive solid-phase extraction with column/cartridge-based solid-phase extraction in the cleanup step can make the quick, easy, cheap, effective, rugged, and safe extraction method compatible with traditional detectors for more sensitive, effective, and green analysis. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Multi-contaminant analysis of organophosphate and halogenated flame retardants in food matrices using ultrasonication and vacuum assisted extraction, multi-stage cleanup and gas chromatography-mass spectrometry.

PubMed

Xu, Fuchao; García-Bermejo, Ángel; Malarvannan, Govindan; Gómara, Belén; Neels, Hugo; Covaci, Adrian

2015-07-03

A multi-residue analytical method was developed for the determination of a range of flame retardants (FRs), including polybrominated diphenyl ethers (PBDEs), emerging halogenated FRs (EFRs) and organophosphate FRs (PFRs), in food matrices. An ultrasonication and vacuum assisted extraction (UVAE), followed by a multi-stage clean-up procedure, enabled the removal of up to 1g of lipid from 2.5 g of freeze-dried food samples and significantly reduce matrix effects. UVAE achieves a waste factor (WF) of about 10%, while the WFs of classical QuEChERS methods range usually between 50 and 90%. The low WF of UVAE leads to a dramatic improvement in the sensitivity along with saving up to 90% of spiking (internal) standards. Moreover, a two-stage clean-up on Florisil and aminopropyl silica was introduced after UVAE, for an efficient removal of pigments and residual lipids, which led to cleaner extracts than normally achieved by dispersive solid phase extraction (d-SPE). In this way, the extracts could be concentrated to low volumes, e.g. <100 μL and the equivalent matrix concentrations were up to 100g ww/mL. The final analysis of PFRs was performed on GC-EI-MS, while PBDEs and EFRs were measured by GC-ECNI-MS. Validation tests were performed with three food matrices (lean beef, whole chicken egg and salmon filet), obtaining acceptable recoveries (66-135%) with good repeatability (RSD 1-24%, mean 7%). Method LOQs ranged between 0.008 and 0.04 ng/g dw for PBDEs, between 0.08 and 0.20 ng/g dw for EFRs, and between 1.4 and 3.6 ng/g dw for PFRs. The method was further applied to eight types of food samples (including meat, eggs, fish, and seafood) with lipid contents ranging from 0.1 to 22%. Various FRs were detected above MLOQ levels, demonstrating the wide-range applicability of our method. To the best of our knowledge, this is the first method reported for simultaneous analysis of brominated and organophosphate FRs in food matrices. Copyright © 2015 Elsevier B.V. All rights reserved.

Influence of pre-treatment process on matrix effect for the determination of musk fragrances in fish and mussel.

PubMed

Vallecillos, Laura; Pocurull, Eva; Borrull, Francesc

2015-03-01

Musk compounds are widely used as fragrances in personal care products. On account of their widespread use and their low biodegradation, they can be found in environmental samples. In our study two extraction methodologies were compared and different clean-up strategies were also studied in order to develop a reliable analytical method, with minimum matrix effect and good detection limits, to determine synthetic musk fragrances- six polycyclic musks, three nitro musks and the degradation product of one polycyclic musk- in fish and mussel samples. The first extraction technique involves a QuEChERS extraction, a consolidate extraction methodology in the field of food analysis of growing interest over recent years, followed by a dispersive solid-phase extraction (dSPE) as clean-up strategy. The second extraction technique consists of a conventional pressurised liquid extraction (PLE) with dichloromethane and an in-cell clean-up to decrease the matrix effect and remove the undesired components(⁎)present in PLE extracts. Large volume injection (LVI) followed by gas chromatography-ion trap-tandem mass spectrometry (GC-IT-MS/MS) was chosen as the separation and detection technique. Validation parameters, such as method detection limits and method quantification limits were found at ng g(-1) levels for both fish and mussel matrices. Good levels of intra-day and inter-day repeatabilities were obtained analysing fish and mussel samples spiked at 50 ng g(-1) (d.w.) (n=5, RSDs<17%). The developed PLE/GC-IT-MS/MS method was successfully applied to determine the target musk fragrances present in fish and mussel samples from the local market in Tarragona and fish samples from the Ebro River. The results showed the presence of galaxolide (2.97-18.04 ng g(-1) (d.w.)) and tonalide (1.17-8.42 ng g(-1) (d.w.)) in all the samples analysed, while the remaining polycyclic musks such as cashmeran, celestolide and phantolide, were only detected in some of the fish samples analysed. None of the samples analysed contained detectable traces of the nitro musks studied. Copyright © 2014 Elsevier B.V. All rights reserved.

Report: Backlog of Leaking Underground Storage Tank Cleanups in Indian Country Has Been Reduced, but EPA Needs to Demonstrate Compliance With Requirements

EPA Pesticide Factsheets

Report #17-P-0118, March 6, 2017. Without documentation and controls for the prioritization of UST cleanups in Indian country, the sites with the greatest health and environmental risks may not be addressed.

EPA Recommends Modifications to Part of Industri-plex Superfund Cleanup in Woburn, Mass.

EPA Pesticide Factsheets

The U.S. Environmental Protection Agency (EPA) proposes recommended modifications to part of the cleanup of the Industri-plex Superfund Site in Woburn, Mass. Beginning today (May 3, 2018), there will be a 14-day public comment period on EPA’s proposal.

Cleanup Verification Package for the 300 VTS Waste Site

DOE Office of Scientific and Technical Information (OSTI.GOV)

S. W. Clark and T. H. Mitchell

2006-03-13

This cleanup verification package documents completion of remedial action for the 300 Area Vitrification Test Site, also known as the 300 VTS site. The site was used by Pacific Northwest National Laboratory as a field demonstration site for in situ vitrification of soils containing simulated waste.

Multiresidue analysis of endocrine-disrupting compounds and perfluorinated sulfates and carboxylic acids in sediments by ultra-high-performance liquid chromatography-tandem mass spectrometry.

PubMed

Cavaliere, Chiara; Capriotti, Anna Laura; Ferraris, Francesca; Foglia, Patrizia; Samperi, Roberto; Ventura, Salvatore; Laganà, Aldo

2016-03-18

A multiresidue analytical method for the determination of 11 perfluorinated compounds and 22 endocrine-disrupting compounds (ECDs) including 13 natural and synthetic estrogens (free and conjugated forms), 2 alkylphenols, 1 plasticiser, 2 UV-filters, 1 antimicrobial, and 2 organophosphorus compounds in sediments has been developed. Ultrasound-assisted extraction followed by solid phase extraction (SPE) with graphitized carbon black (GCB) cartridge as clean-up step were used. The extraction process yield was optimized in terms of solvent composition. Then, a 3(2) experimental design was used to optimize solvent volume and sonication time by response surface methodology, which simplifies the optimization procedure. The final extract was analyzed by ultra-high performance liquid chromatography coupled with tandem mass spectrometry. The optimized sample preparation method is simple and robust, and allows recovery of ECDs belonging to different classes in a complex matrix such as sediment. The use of GCB for SPE allowed to obtain with a single clean-up procedure excellent recoveries ranging between 75 and 110% (relative standard deviation <16%). The developed methodology has been successfully applied to the analysis of ECDs in sediments from different rivers and lakes of the Lazio Region (Italy). These analyses have shown the ubiquitous presence of chloro-substituted organophosphorus flame retardants and bisphenol A, while other analyzed compounds were occasionally found at concentration between the limit of detection and quantification. Copyright © 2016 Elsevier B.V. All rights reserved.

Determination of polychlorinated biphenyls in fish: optimisation and validation of a method based on accelerated solvent extraction and gas chromatography-mass spectrometry.

PubMed

Ottonello, Giuliana; Ferrari, Angelo; Magi, Emanuele

2014-01-01

A simple and robust method for the determination of 18 polychlorinated biphenyls (PCBs) in fish was developed and validated. A mixture of acetone/n-hexane (1:1, v/v) was selected for accelerated solvent extraction (ASE). After the digestion of fat, the clean-up was carried out using solid phase extraction silica cartridges. Samples were analysed by GC-MS in selected ion monitoring (SIM) using three fragment ions for each congener (one quantifier and two qualifiers). PCB 155 and PCB 198 were employed as internal standards. The lowest limit of detection was observed for PCB 28 (0.4ng/g lipid weight). The accuracy of the method was verified by means of the Certified Reference Material EDF-2525 and good results in terms of linearity (R(2)>0.994) and recoveries (80-110%) were also achieved. Precision was evaluated by spiking blank samples at 4, 8 and 12ng/g. Relative standard deviation values for repeatability and reproducibility were lower than 8% and 16%, respectively. The method was applied to the determination of PCBs in 80 samples belonging to four Mediterranean fish species. The proposed procedure is particularly effective because it provides good recoveries with lowered extraction time and solvent consumption; in fact, the total time of extraction is about 12min per sample and, for the clean-up step, a total solvent volume of 13ml is required. Copyright © 2013 Elsevier Ltd. All rights reserved.

Buying time: Franchising hazardous and nuclear waste cleanup

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hale, D.R.

This paper describes a private franchise approach to long-term custodial care, monitoring and eventual cleanup of hazardous and nuclear waste sites. The franchise concept could be applied to Superfund sites, decommissioning commercial reactors and safeguarding their wastes and to Department of Energy sites. Privatization would reduce costs by enforcing efficient operations and capital investments during the containment period, by providing incentives for successful innovation and by sustaining containment until the cleanup`s net benefits exceed its costs. The franchise system would also permit local governments and citizens to demand and pay for more risk reduction than provided by the federal government.more » In principle, they would have the option of taking over site management. The major political drawback of the idea is that it requires society to be explicit about what it is willing to pay for now to protect current and future generations. Hazardous waste sites are enduring legacies of energy development. Abandoned mines, closed refineries, underground storage tanks and nuclear facilities have often become threats to human health and water quality. The policy of the United States government is that such sites should quickly be made nonpolluting and safe for unrestricted use. That is, the policy of the United States is prompt cleanup. Orphaned commercial hazardous waste sites are addressed by the US Environmental Protection Agency`s Superfund program. 17 refs., 2 tabs.« less

Decontamination issues for chemical and biological warfare agents: how clean is clean enough?

PubMed

Raber, E; Jin, A; Noonan, K; McGuire, R; Kirvel, R D

2001-06-01

The objective of this assessment is to determine what level of cleanup will be required to meet regulatory and stakeholder needs in the case of a chemical and/or biological incident at a civilian facility. A literature review for selected, potential chemical and biological warfare agents shows that dose information is often lacking or controversial. Environmental regulatory limits or other industrial health guidelines that could be used to help establish cleanup concentration levels for such agents are generally unavailable or not applicable for a public setting. Although dose information, cleanup criteria, and decontamination protocols all present challenges to effective planning, several decontamination approaches are available. Such approaches should be combined with risk-informed decision making to establish reasonable cleanup goals for protecting health, property, and resources. Key issues during a risk assessment are to determine exactly what constitutes a safety hazard and whether decontamination is necessary or not for a particular scenario. An important conclusion is that cleanup criteria are site dependent and stakeholder specific. The results of a modeling exercise for two outdoor scenarios are presented to reinforce this conclusion. Public perception of risk to health, public acceptance of recommendations based on scientific criteria, political support, time constraints, and economic concerns must all be addressed in the context of a specific scenario to yield effective and acceptable decontamination.

Comparison of Clean-Up Methods for Ochratoxin A on Wine, Beer, Roasted Coffee and Chili Commercialized in Italy

PubMed Central

Prelle, Ambra; Spadaro, Davide; Denca, Aleksandra; Garibaldi, Angelo; Gullino, Maria Lodovica

2013-01-01

The most common technique used to detect ochratoxin A (OTA) in food matrices is based on extraction, clean-up, and chromatography detection. Different clean-up cartridges, such as immunoaffinity columns (IAC), molecular imprinting polymers (MIP), Mycosep™ 229, Mycospin™, and Oasis® HLB (Hydrophilic Lipophilic balance) as solid phase extraction were tested to optimize the purification for red wine, beer, roasted coffee and chili. Recovery, reproducibility, reproducibility, limit of detection (LOD) and limit of quantification (LOQ) were calculated for each clean-up method. IAC demonstrated to be suitable for OTA analysis in wine and beer with recovery rate >90%, as well as Mycosep™ for wine and chili. On the contrary, MIP columns were the most appropriate to clean up coffee. A total of 120 samples (30 wines, 30 beers, 30 roasted coffee, 30 chili) marketed in Italy were analyzed, by applying the developed clean-up methods. Twenty-seven out of 120 samples analyzed (22.7%: two wines, five beers, eight coffees, and 12 chili) resulted positive to OTA. A higher incidence of OTA was found in chili (40.0%) more than wine (6.6%), beers (16.6%) and coffee (26.6%). Moreover, OTA concentration in chili was the highest detected, reaching 47.8 µg/kg. Furthermore, three samples (2.5%), two wines and one chili, exceeded the European threshold. PMID:24152987

Why Does Disaster Recovery Work Influence Mental Health?: Pathways through Physical Health and Household Income.

PubMed

Lowe, Sarah R; Kwok, Richard K; Payne, Julianne; Engel, Lawrence S; Galea, Sandro; Sandler, Dale P

2016-12-01

Disaster recovery work increases risk for mental health problems, yet the mechanisms underlying this association are unclear. We explored links from recovery work to post-traumatic stress (PTS), major depression (MD), and generalized anxiety disorder (GAD) symptoms through physical health symptoms and household income in the aftermath of the Deepwater Horizon oil spill. As part of the NIEHS GuLF STUDY, participants (N = 10,141) reported on cleanup work activities, spill-related physical health symptoms, and household income at baseline, and mental health symptoms an average of 14.69 weeks (SD = 16.79) thereafter. Cleanup work participation was associated with higher physical health symptoms, which in turn were associated with higher PTS, MD, and GAD symptoms. Similar pattern of results were found in models including workers only and investigating the influence of longer work duration and higher work-related oil exposure on mental health symptoms. In addition, longer worker duration and higher work-related oil exposure were associated with higher household income, which in turn was associated with lower MD and GAD symptoms. These findings suggest that physical health symptoms contribute to workers' risk for mental health symptoms, while higher household income, potentially from more extensive work, might mitigate risk. © Society for Community Research and Action 2016.

Screening of pollution control and clean-up materials for river chemical spills using the multiple case-based reasoning method with a difference-driven revision strategy.

PubMed

Liu, Rentao; Jiang, Jiping; Guo, Liang; Shi, Bin; Liu, Jie; Du, Zhaolin; Wang, Peng

2016-06-01

In-depth filtering of emergency disposal technology (EDT) and materials has been required in the process of environmental pollution emergency disposal. However, an urgent problem that must be solved is how to quickly and accurately select the most appropriate materials for treating a pollution event from the existing spill control and clean-up materials (SCCM). To meet this need, the following objectives were addressed in this study. First, the material base and a case base for environment pollution emergency disposal were established to build a foundation and provide material for SCCM screening. Second, the multiple case-based reasoning model method with a difference-driven revision strategy (DDRS-MCBR) was applied to improve the original dual case-based reasoning model method system, and screening and decision-making was performed for SCCM using this model. Third, an actual environmental pollution accident from 2012 was used as a case study to verify the material base, case base, and screening model. The results demonstrated that the DDRS-MCBR method was fast, efficient, and practical. The DDRS-MCBR method changes the passive situation in which the choice of SCCM screening depends only on the subjective experience of the decision maker and offers a new approach to screening SCCM.

Hispanic health disparities after a flood disaster: results of a population-based survey of individuals experiencing home site damage in El Paso (Texas, USA).

PubMed

Collins, Timothy W; Jimenez, Anthony M; Grineski, Sara E

2013-04-01

In 2006, El Paso County, a predominantly Hispanic urban area, was affected by a flood disaster; 1,500 homes were damaged. We assessed the health impacts of the disaster upon 475 individuals whose homes were flood-damaged using mail survey data and logistic regression. Substantial proportions of individuals had one or more physical (43 %) or mental (18 %) health problem in the four months following the floods; 28 % had one or more injury or acute effect related to post-flood cleanup. Adverse event experiences, older age, and lower socioeconomic status were significantly associated with negative post-flood health outcomes in all three logistic regression models. A lack of access to healthcare, non-US citizenship, and English proficiency were significant predictors of negative outcomes in both the physical and mental health models, while Hispanic ethnicity (physical), native-birth (mental), and more serious home damage (cleanup) were significant predictors in one model each. The disaster had disproportionate negative health impacts on those who were more exposed, poorer, older, and with constrained resource-access. While a lack of US citizenship and Hispanic ethnicity were associated with higher risks, being less acculturated (i.e., English-deficient, foreign-born) may have protected against health impacts.

Proceedings from the Workshop on Phytoremediation of Inorganic Contaminants

DOE Office of Scientific and Technical Information (OSTI.GOV)

J. T. Brown; G. Matthern; A. Glenn

The Metals and Radionuclides Product Line of the US Department of Energy (DOE) Subsurface Contaminants Focus Area (SCFA) is responsible for the development of technologies and systems that reduce the risk and cost of remediation of radionuclide and hazardous metal contamination in soils and groundwater. The rapid and efficient remediation of these sites and the areas surrounding them represents a technological challenge. Phytoremediation, the use of living plants to cleanup contaminated soils, sediments, surface water and groundwater, is an emerging technology that may be applicable to the problem. The use of phytoremediation to cleanup organic contamination is widely accepted andmore » is being implemented at numerous sites. This workshop was held to initiate a discussion in the scientific community about whether phytoremediation is applicable to inorganic contaminants, such as metals and radionuclides, across the DOE complex. The Workshop on Phytoremediation of Inorganic Contaminants was held at Argonne National Laboratory from November 30 through December 2, 1999. The purpose of the workshop was to provide SCFA and the DOE Environmental Restoration Program with an understanding of the status of phytoremediation as a potential remediation technology for DOE sites. The workshop was expected to identify data gaps, technologies ready for demonstration and deployment, and to provide a set of recommendations for the further development of these technologies.« less

Successive equimarginal approach for optimal design of a pump and treat system

NASA Astrophysics Data System (ADS)

Guo, Xiaoniu; Zhang, Chuan-Mian; Borthwick, John C.

2007-08-01

An economic concept-based optimization method is developed for groundwater remediation design. Design of a pump and treat (P&T) system is viewed as a resource allocation problem constrained by specified cleanup criteria. An optimal allocation of resources requires that the equimarginal principle, a fundamental economic principle, must hold. The proposed method is named successive equimarginal approach (SEA), which continuously shifts a pumping rate from a less effective well to a more effective one until equal marginal productivity for all units is reached. Through the successive process, the solution evenly approaches the multiple inequality constraints that represent the specified cleanup criteria in space and in time. The goal is to design an equal protection system so that the distributed contaminant plumes can be equally contained without bypass and overprotection is minimized. SEA is a hybrid of the gradient-based method and the deterministic heuristics-based method, which allows flexibility in dealing with multiple inequality constraints without using a penalty function and in balancing computational efficiency with robustness. This method was applied to design a large-scale P&T system for containment of multiple plumes at the former Blaine Naval Ammunition Depot (NAD) site, near Hastings, Nebraska. To evaluate this method, the SEA results were also compared with those using genetic algorithms.

Case study: Minimization of corrosion using activated sodium bromide in a medium-size cooling tower

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nalepa, C.J.; Moore, R.M.; Golson, G.L.

1996-10-01

The process loop cooling tower at the Albemarle Process Development Center in Baton Rouge, LA has historically used chlorine as the biocide together with industry accepted phosphorus-based corrosion/scale inhibitors. Although this regimen provided biocontrol, sludge and iron build-up was a recurring problem, especially in low-velocity, small cross-sectional areas of piping. A general clean-up of the system was performed in April, 1995. This clean-up was followed with a switch to a two-component corrosion inhibitor/dispersant package. It was decided to study alternate biocides as well at this time. Activated sodium bromide was found to be particularly effective in this tower, which operatesmore » at pH {approximately}8.4. Relative to chlorine, the use of activated sodium bromide led to a decrease in general and pitting corrosion on mild steel while maintaining prior performance on admiralty brass. The reduced corrosion appears to be due to a combination of both chemical (less attack on passivated metal surfaces) and biological factors (better control of heterotrophic and sessile bacteria). These conclusions are supported by chemical analyses, corrosion meter and coupon data, dip slides, BART (biological activity reaction test) tests, and visual observations of the tower sump and heat exchanger surfaces.« less

[Determination of short-chain chlorinated paraffins in ambient air using high-volume sampling combined with high resolutimi gas chromatography-electron capture negative ion-low resolution mass spectrometry].

PubMed

Shi, Loimeng; Gao, Yuan; Hou, Xiaohong; Zhang, Haijun; Zhang, Yichi; Chen, Jiping

2016-02-01

An analytical method for quantifying short-chain chlorinated paraffins (SCCPs) in ambient air using high-volume sampling combined with high resolution gas chromatography-electron capture negative ion-low resolution mass spectrometry ( HRGC-ECNI-LRMS) was developed. An acidified silica gel column and a basic alumina column were used to optimize the cleanup procedures. The results showed a good linearity (R2>0. 99) between the total response factors and the degree of chlorination of SCCPs in the content range of 58. 1%-63. 3%. The limits of detection (S/N ≥3) and the limits of quantification (S/N ≥ 10) were 4. 2 and 12 µg, respectively. The method detection limit (MDL) for SCCPs was 0. 34 ng/m3 (n = 7). The recoveries of SCCPs in air samples were in the range of 81. 9% to 94. 2%. It is demonstrated that the method is suitable for the quantitative analysis of SCCPs in air samples.

Architectural Framework for Addressing Legacy Waste from the Cold War - 13611

DOE Office of Scientific and Technical Information (OSTI.GOV)

Love, Gregory A.; Glazner, Christopher G.; Steckley, Sam

We present an architectural framework for the use of a hybrid simulation model of enterprise-wide operations used to develop system-level insight into the U.S. Department of Energy's (DOE) environmental cleanup of legacy nuclear waste at the Savannah River Site. We use this framework for quickly exploring policy and architectural options, analyzing plans, addressing management challenges and developing mitigation strategies for DOE Office of Environmental Management (EM). The socio-technical complexity of EM's mission compels the use of a qualitative approach to complement a more a quantitative discrete event modeling effort. We use this model-based analysis to pinpoint pressure and leverage pointsmore » and develop a shared conceptual understanding of the problem space and platform for communication among stakeholders across the enterprise in a timely manner. This approach affords the opportunity to discuss problems using a unified conceptual perspective and is also general enough that it applies to a broad range of capital investment/production operations problems. (authors)« less

Influence of waste management policy on the characteristics of beach litter in Kaohsiung, Taiwan.

PubMed

Liu, Ta-Kang; Wang, Meng-Wei; Chen, Ping

2013-07-15

Marine debris is a ubiquitous problem that poses a serious threat to the global oceans; it has motivated public participation in clean-up campaigns, as well as governmental involvement in developing mitigation strategies. While it is known that the problem of marine litter may be affected by waste management practices on land, beach survey results have seldom been compared with them. In this study, marine litter surveys on four beaches of Cijin Island were conducted to explore the effects of waste management and policy implications. Indirect evidence shows that chances for land-based litter, such as plastic bags and bottles, entering the marine environment can be greatly decreased if they can be properly reduced, reused and recycled. We suggest that mitigation measures should focus on source reduction, waste recycling and management, utilizing effective economic instruments, and pursuing a long-term public education campaign to raise the public awareness of this problem. Copyright © 2013 Elsevier Ltd. All rights reserved.

Mental health service use by cleanup workers in the aftermath of the Deepwater Horizon oil spill.

PubMed

Lowe, Sarah R; Kwok, Richard K; Payne, Julianne; Engel, Lawrence S; Galea, Sandro; Sandler, Dale P

2015-04-01

High rates of mental health (MH) problems have been documented among disaster relief workers. However, few workers utilize MH services, and predictors of service use among this group remain unexplored. The purpose of this study was to explore associations between predisposing, illness-related, and enabling factors from Andersen's behavioral model of treatment-seeking and patterns of service use among participants who completed at least one full day of cleanup work after the Deepwater Horizon oil spill and participated in home visits for the NIEHS GuLF STUDY (N = 8931). Workers reported on MH symptoms and whether they had used counseling or medication for MH problems since the oil spill. Hierarchical logistic regression models explored associations between predictors and counseling and medication use in the full sample, and type of use (counseling only, medication only, both) among participants who used either service. Analyses were replicated for subsamples of participants with and without symptom inventory scores suggestive of probable post-disaster mental illness. Having a pre-spill MH diagnosis, pre-spill service use, more severe post-spill MH symptoms, and healthcare coverage were positively associated with counseling and medication use in the full sample. Among participants who used either service, non-Hispanic Black race, pre-spill counseling, lower depression, and not identifying a personal doctor or healthcare provider were predictive of counseling only, whereas older age, female gender and pre-spill medication were predictive of medication only. The results were generally consistent among participants with and without probable post-disaster mental illness. The results suggest variability in which factors within Andersen's behavioral model are predictive of different patterns of service use among disaster relief workers. Copyright © 2015 Elsevier Ltd. All rights reserved.

Mental Health Service Use by Cleanup Workers in the Aftermath of the Deepwater Horizon Oil Spill

PubMed Central

Lowe, Sarah R.; Kwok, Richard K.; Payne, Julianne; Engel, Lawrence S.; Galea, Sandro; Sandler, Dale P.

2015-01-01

High rates of mental health (MH) problems have been documented among disaster relief workers. However, few workers utilize MH services, and predictors of service use among this group remain unexplored. The purpose of this study was to explore associations between predisposing, illness-related, and enabling factors from Andersen’s behavioral model of treatment-seeking and patterns of service use among participants who completed at least one full day of cleanup work after the Deepwater Horizon oil spill and participated in home visits for the NIEHS GuLF STUDY (N = 8,931). Workers reported on MH symptoms and whether they had used counseling or medication for MH problems since the oil spill. Hierarchical logistic regression models explored associations between predictors and counseling and medication use in the full sample, and type of use (counseling only, medication only, both) among participants who used either service. Analyses were replicated for subsamples of participants with and without symptom inventory scores suggestive of probable post-disaster mental illness. Having a pre-spill MH diagnosis, pre-spill service use, more severe post-spill MH symptoms, and healthcare coverage were positively associated with counseling and medication use in the full sample. Among participants who used either service, non-Hispanic Black race, pre-spill counseling, lower depression, and not identifying a personal doctor or healthcare provider were predictive of counseling only, whereas older age, female gender and pre-spill medication were predictive of medication only. The results were generally consistent among participants with and without probable post-disaster mental illness. The results suggest variability in which factors within Andersen’s behavioral model are predictive of different patterns of service use among disaster relief workers. PMID:25697635

A Review of Youth Employment Problems, Programs & Policies: Volume 2. Special Needs and Concentrated Problems.

ERIC Educational Resources Information Center

Vice President's Task Force on Youth Employment, Washington, DC.

This series of nine reports reviews available information on the special needs and concentrated problems of youth employment. (It constitutes the second of a three-volume compendium; other volumes examine causes and dimensions of youth employment problems and analyze program experience--see note.) The effects of discrimination on minority youth…

Determination of fusaric acid in maize using molecularly imprinted SPE clean-up

USDA-ARS?s Scientific Manuscript database

A new liquid chromatography method to detect fusaric acid in maize is reported based on molecularly imprinted polymer solid phase extraction clean-up (MISPE) using mimic-templated molecularly-imprinted polymers. Picolinic acid was used as a toxin analog for imprinting polymers during a thermolytic s...

SW-846 Test Method 4025: Screening for Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans (PCDD/PCDFs) by Immunoassay

EPA Pesticide Factsheets

a procedure for the analysis of (PCDDs/PCDFs) in soil at 500 ppt (pg/g) using a simple onestep liquid phase oxidative cleanup or, at mid to low ppt levels, using a two step coupled column cleanup (oxidation and activated carbon binding)

Report: Progress Made, but Improvements Needed at CTS of Asheville Superfund Site in North Carolina to Advance Cleanup Pace and Reduce Potential Exposure

EPA Pesticide Factsheets

Report #16-P-0296, August 31, 2016. EPA Region 4 can accelerate the cleanup and completeness of work, and improve public communications, to better control human exposure to unsafe industrial contamination at the CTS site.

Celebrating Success: EPA Region 3 Greener Cleanup and Sustainable Reuse Award Winner: Aberdeen Proving Ground Federal Facility Superfund Site

EPA Pesticide Factsheets

Greener Cleanup practices were implemented as part of a successful Time-Critical Removal Action (TCRA) completed at the APG Former NIKE Missile Site which has resulted in a reduced environmental footprint, accelerated site closure, and a cost savings.

(Review Draft) Radiation Site Cleanup Regulations: Technical Support Document For The Development Of Radionuclide Cleanup Levels For Soil

EPA Pesticide Factsheets

This document describes parts of the technical analysis being undertaken in support of standards that ensure certain sites are cleaned up to a level that is protective of human health and the environment before they are released for public use.

Report: Ombudsman Review of Bunker Hill and Coeur d’Alene Basin Superfund Actions

EPA Pesticide Factsheets

Report #2004-P-00009, March 24, 2004. EPA made a logical decision to first do cleanup work in the Bunker Hill Box and then later study areas outside the Box and pursue further cleanup work on specific targeted areas in the Coeur d'Alene Basin.

LITERATURE REVIEW ON THE USE OF COMMERCIAL BIOREMEDIATION AGENTS FOR CLEAN-UP OF OIL-CONTAMINATED ESTUARINE ENVIRONMENTS

EPA Science Inventory

The objective of this document is to conduct a comprehensive review of the use of commercial bioremediation products treating oil spills in all environments, Literature assessed includes peer-reviewed articles, company reports, government reports, and reports by cleanup contracto...

Cleanup Verification Package for the 100-F-20, Pacific Northwest Laboratory Parallel Pits

DOE Office of Scientific and Technical Information (OSTI.GOV)

M. J. Appel

2007-01-22

This cleanup verification package documents completion of remedial action for the 100-F-20, Pacific Northwest Laboratory Parallel Pits waste site. This waste site consisted of two earthen trenches thought to have received both radioactive and nonradioactive material related to the 100-F Experimental Animal Farm.

Use of fluorinated polybrominated diphenyl ethers and simplified cleanup for the analysis of polybrominated diphenyl ethers in house dust

EPA Science Inventory

A simple, cost-effective method is described for the analysis of polybrominated diphenyl ethers (PBDEs) in house dust using pressurized fluid extraction, cleanup with modified silica solid phase extraction tubes, and fluorinated internal standards. There are 14 PBDE congeners inc...

76 FR 45738 - Regulated Navigation Area; Pacific Sound Resources and Lockheed Shipyard EPA Superfund Cleanup...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-08-01

... Shipyard superfund cleanup remediation efforts. This RNA would prohibit activities that would disturb the... sediment caps installed in the designated regulated navigation area, pursuant to the remediation efforts of... persons engaged in activities associated with remediation efforts in the superfund sites, provided that...

40 CFR 61.182 - Standard for new and existing sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

... impacts in other environmental media: (i) Clean-up and proper disposal, wet-down, or chemical... inorganic arsenic content greater than 2 percent that accumulates on any surface within the plant boundaries outside of a dust-tight enclosure. (ii) Immediate clean-up and proper disposal, wet-down, or chemical...

40 CFR 61.182 - Standard for new and existing sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

... impacts in other environmental media: (i) Clean-up and proper disposal, wet-down, or chemical... inorganic arsenic content greater than 2 percent that accumulates on any surface within the plant boundaries outside of a dust-tight enclosure. (ii) Immediate clean-up and proper disposal, wet-down, or chemical...

40 CFR 61.182 - Standard for new and existing sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... impacts in other environmental media: (i) Clean-up and proper disposal, wet-down, or chemical... inorganic arsenic content greater than 2 percent that accumulates on any surface within the plant boundaries outside of a dust-tight enclosure. (ii) Immediate clean-up and proper disposal, wet-down, or chemical...

40 CFR 61.182 - Standard for new and existing sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

... impacts in other environmental media: (i) Clean-up and proper disposal, wet-down, or chemical... inorganic arsenic content greater than 2 percent that accumulates on any surface within the plant boundaries outside of a dust-tight enclosure. (ii) Immediate clean-up and proper disposal, wet-down, or chemical...

40 CFR 61.182 - Standard for new and existing sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

... impacts in other environmental media: (i) Clean-up and proper disposal, wet-down, or chemical... inorganic arsenic content greater than 2 percent that accumulates on any surface within the plant boundaries outside of a dust-tight enclosure. (ii) Immediate clean-up and proper disposal, wet-down, or chemical...

46 CFR 68.27 - Definitions for purposes of this subpart.

Code of Federal Regulations, 2014 CFR

2014-10-01

... Vessels for Oil Spill Cleanup § 68.27 Definitions for purposes of this subpart. Certificate of... Socialist Republics on the Maritime Boundary, signed June 1, 1990. Not-for-profit oil spill response... purposes of training for, carrying out, and supporting oil spill cleanup operations or related research...

46 CFR 68.27 - Definitions for purposes of this subpart.

Code of Federal Regulations, 2013 CFR

2013-10-01

... Vessels for Oil Spill Cleanup § 68.27 Definitions for purposes of this subpart. Certificate of... Socialist Republics on the Maritime Boundary, signed June 1, 1990. Not-for-profit oil spill response... purposes of training for, carrying out, and supporting oil spill cleanup operations or related research...

46 CFR 68.27 - Definitions for purposes of this subpart.

Code of Federal Regulations, 2012 CFR

2012-10-01

... Vessels for Oil Spill Cleanup § 68.27 Definitions for purposes of this subpart. Certificate of... Socialist Republics on the Maritime Boundary, signed June 1, 1990. Not-for-profit oil spill response... purposes of training for, carrying out, and supporting oil spill cleanup operations or related research...

Environmental projects. Volume 5, part 1: Study of subsurface contamination. Part 2: Guide to implement environmental compliance programs

NASA Technical Reports Server (NTRS)

Bengelsdorf, I.

1988-01-01

In support of the national goal for the preservation of the environment and the protection of human health and safety, NASA, the Jet Propulsion Laboratory, and the Goldstone Deep Space Communications Complex have adopted the position that their operating installations shall maintain a high level of compliance in regard to regulations concerning environmental hazards. An investigation carried out by Engineering Science, Inc. focused on possible underground contamination that may have resulted from leaks and/or spills from storage facilities at the Goldstone Communications Complex. It also involved the cleanup of a non-hazardous waste dumpsite at the Mojave Base Site at the Goldstone complex. The report also includes details of the management duties and responsibilities needed to maintain compliance with environmental laws and regulations.

Environmental and medical geochemistry in urban disaster response and preparedness

USGS Publications Warehouse

Plumlee, Geoffrey S.; Morman, Suzette A.; Cook, A.

2012-01-01

History abounds with accounts of cities that were destroyed or significantly damaged by natural or anthropogenic disasters, such as volcanic eruptions, earthquakes, wildland–urban wildfires, hurricanes, tsunamis, floods, urban firestorms, terrorist attacks, and armed conflicts. Burgeoning megacities place ever more people in the way of harm from future disasters. In addition to the physical damage, casualties, and injuries they cause, sudden urban disasters can also release into the environment large volumes of potentially hazardous materials. Environmental and medical geochemistry investigations help us to (1) understand the sources and environmental behavior of disaster materials, (2) assess potential threats the materials pose to the urban environment and health of urban populations, (3) develop strategies for their cleanup/disposal, and (4) anticipate and mitigate potential environmental and health effects from future urban disasters.

Expediting contaminated site cleanup in California

DOE Office of Scientific and Technical Information (OSTI.GOV)

Newman, B.S.; Conlan, J.T.

California generally has been considered a leader in the advocacy of policies for the cleanup and abatement of environmental pollution. Many of the more innovative programs and policies were developed within the broad framework of California`s Brownfields Initiative. Because both the public and private sectors recognize that environmental cleanup and reuse of California`s industrial properties are major components of economic revitalization, the state has used administrative and legislative tools to provide incentives for redeveloping brownfields contaminated by leaking underground storage tanks (USTs) and other industrial operations. However, it is the broader reach of various state and local policies, programs, agreementsmore » and management communication that provide benefits to the majority of the regulated community.« less

Reducing Contingency through Sampling at the Luckey FUSRAP Site - 13186

DOE Office of Scientific and Technical Information (OSTI.GOV)

Frothingham, David; Barker, Michelle; Buechi, Steve

2013-07-01

Typically, the greatest risk in developing accurate cost estimates for the remediation of hazardous, toxic, and radioactive waste sites is the uncertainty in the estimated volume of contaminated media requiring remediation. Efforts to address this risk in the remediation cost estimate can result in large cost contingencies that are often considered unacceptable when budgeting for site cleanups. Such was the case for the Luckey Formerly Utilized Sites Remedial Action Program (FUSRAP) site near Luckey, Ohio, which had significant uncertainty surrounding the estimated volume of site soils contaminated with radium, uranium, thorium, beryllium, and lead. Funding provided by the American Recoverymore » and Reinvestment Act (ARRA) allowed the U.S. Army Corps of Engineers (USACE) to conduct additional environmental sampling and analysis at the Luckey Site between November 2009 and April 2010, with the objective to further delineate the horizontal and vertical extent of contaminated soils in order to reduce the uncertainty in the soil volume estimate. Investigative work included radiological, geophysical, and topographic field surveys, subsurface borings, and soil sampling. Results from the investigative sampling were used in conjunction with Argonne National Laboratory's Bayesian Approaches for Adaptive Spatial Sampling (BAASS) software to update the contaminated soil volume estimate for the site. This updated volume estimate was then used to update the project cost-to-complete estimate using the USACE Cost and Schedule Risk Analysis process, which develops cost contingencies based on project risks. An investment of $1.1 M of ARRA funds for additional investigative work resulted in a reduction of 135,000 in-situ cubic meters (177,000 in-situ cubic yards) in the estimated base volume estimate. This refinement of the estimated soil volume resulted in a $64.3 M reduction in the estimated project cost-to-complete, through a reduction in the uncertainty in the contaminated soil volume estimate and the associated contingency costs. (authors)« less

40 CFR 280.65 - Investigations for soil and ground-water cleanup.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 28 2012-07-01 2012-07-01 false Investigations for soil and ground... Containing Petroleum or Hazardous Substances § 280.65 Investigations for soil and ground-water cleanup. (a) In order to determine the full extent and location of soils contaminated by the release and the...

40 CFR 280.65 - Investigations for soil and ground-water cleanup.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 27 2011-07-01 2011-07-01 false Investigations for soil and ground... Containing Petroleum or Hazardous Substances § 280.65 Investigations for soil and ground-water cleanup. (a) In order to determine the full extent and location of soils contaminated by the release and the...

40 CFR 280.65 - Investigations for soil and ground-water cleanup.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 27 2014-07-01 2014-07-01 false Investigations for soil and ground... Containing Petroleum or Hazardous Substances § 280.65 Investigations for soil and ground-water cleanup. (a) In order to determine the full extent and location of soils contaminated by the release and the...

40 CFR 280.65 - Investigations for soil and ground-water cleanup.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 28 2013-07-01 2013-07-01 false Investigations for soil and ground... Containing Petroleum or Hazardous Substances § 280.65 Investigations for soil and ground-water cleanup. (a) In order to determine the full extent and location of soils contaminated by the release and the...

40 CFR 280.65 - Investigations for soil and ground-water cleanup.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Investigations for soil and ground... Containing Petroleum or Hazardous Substances § 280.65 Investigations for soil and ground-water cleanup. (a) In order to determine the full extent and location of soils contaminated by the release and the...

Marine Debris Clean-Ups as Meaningful Science Learning

ERIC Educational Resources Information Center

Stepath, Carl M.; Bacon, Joseph Scott

2010-01-01

This seven to eight week hands-on Marine Debris Clean-up Project used a service project to provide an introduction of marine science ecology, watershed interrelationships, the scientific method, and environmental stewardship to 8th grade middle school students. It utilized inquiry based learning to introduce marine debris sources and impacts to…

32 CFR 536.35 - Unique issues related to environmental claims.

Code of Federal Regulations, 2010 CFR

2010-07-01

... the United States based on contamination by toxic substances found in the air or the ground must be... geographical jurisdiction over the claim and USARCS. Claims for personal injury from contamination frequently arise at an area that is the subject of claims for cleanup of the contamination site. The cleanup claims...

EPA Extends Comment Period for Proposed Cleanup Plan for the Wells G&H Superfund Site in Woburn Massachusetts

EPA Pesticide Factsheets

The U.S. Environmental Protection Agency has proposed a cleanup plan for the Wells G&H Superfund Site, Southwest Properties, Operable Unit (OU4). The comment period will now be a total of 62 days and be open until September 13, 2017.

40 CFR 761.283 - Determination of the number of samples to collect and sample collection locations.

Code of Federal Regulations, 2013 CFR

2013-07-01

... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT POLYCHLORINATED BIPHENYLS (PCBs...-Implementing Cleanup and On-Site Disposal of Bulk PCB Remediation Waste and Porous Surfaces in Accordance With... locations for bulk PCB remediation waste and porous surfaces destined to remain at a cleanup site after...

40 CFR 761.283 - Determination of the number of samples to collect and sample collection locations.

Code of Federal Regulations, 2014 CFR

2014-07-01

... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT POLYCHLORINATED BIPHENYLS (PCBs...-Implementing Cleanup and On-Site Disposal of Bulk PCB Remediation Waste and Porous Surfaces in Accordance With... locations for bulk PCB remediation waste and porous surfaces destined to remain at a cleanup site after...

77 FR 21433 - Regulated Navigation Area; Pacific Sound Resources and Lockheed Shipyard EPA Superfund Cleanup...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-04-10

... superfund cleanup remediation efforts. This RNA will prohibit activities that would disturb the seabed, such... installed in the designated regulated navigation area, pursuant to the remediation efforts of the U.S... activities associated with remediation efforts in the superfund sites, provided that the Captain of the Port...

Young Children's Views Concerning Distribution of Clean-Up Duties in the Classroom: Responsibility and Self-Interest

ERIC Educational Resources Information Center

Penderi, Efthymia; Rekalidou, Galini

2016-01-01

The preschool setting offers many opportunities to promote development of responsibility in young children. Clean-up routines may support children's distributional judgments, and reveal their sense of responsibility about classroom duties. Although there is a large number of studies regarding children's views about resource distribution,…

CRADA opportunities with METC`s gasification and hot gas cleanup facility

DOE Office of Scientific and Technical Information (OSTI.GOV)

Galloway, E N; Rockey, J M; Tucker, M S

1995-06-01

Opportunities exist for Cooperative Research and Development Agreements (CRADA) at the Morgantown Energy Technology Center (METC) to support commercialization of IGCC power systems. METC operates an integrated gasifier and hot gas cleanup facility for the development of gasification and hot gas cleanup technologies. The objective of our program is to gather performance data on gasifier operation, particulate removal, desulfurization and regeneration technologies. Additionally, slip streams are provided for developing various technologies such as; alkali monitoring, particulate measuring, chloride removal, and contaminate recovery processes. METC`s 10-inch diameter air blown Fluid Bed Gasifier (FBG) provides 300 lb/hr of coal gas at 1100{degrees}Fmore » and 425 psig. The particulate laden gas is transported to METC`s Modular Gas Cleanup Rig (MGCR). The gas pressure is reduced to 285 psig before being fed into a candle filter vessel. The candle filter vessel houses four candle filters and multiple test coupons. The particulate free gas is then desulfurized in a sorbent reactor. Starting in 1996 the MGCR system will be able to regenerate the sorbent in the same vessel.« less

NAPL source zone depletion model and its application to railroad-tank-car spills.

PubMed

Marruffo, Amanda; Yoon, Hongkyu; Schaeffer, David J; Barkan, Christopher P L; Saat, Mohd Rapik; Werth, Charles J

2012-01-01

We developed a new semi-analytical source zone depletion model (SZDM) for multicomponent light nonaqueous phase liquids (LNAPLs) and incorporated this into an existing screening model for estimating cleanup times for chemical spills from railroad tank cars that previously considered only single-component LNAPLs. Results from the SZDM compare favorably to those from a three-dimensional numerical model, and from another semi-analytical model that does not consider source zone depletion. The model was used to evaluate groundwater contamination and cleanup times for four complex mixtures of concern in the railroad industry. Among the petroleum hydrocarbon mixtures considered, the cleanup time of diesel fuel was much longer than E95, gasoline, and crude oil. This is mainly due to the high fraction of low solubility components in diesel fuel. The results demonstrate that the updated screening model with the newly developed SZDM is computationally efficient, and provides valuable comparisons of cleanup times that can be used in assessing the health and financial risk associated with chemical mixture spills from railroad-tank-car accidents. © 2011, The Author(s). Ground Water © 2011, National Ground Water Association.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnson, J.

Kaufman believes the Environmental Protection Agency is missing the chance of a lifetime to mine a vein so rich it could help fund the cleanup of old hazardous waste sites and force industry to manage its waste more carefully in the future. Kaufman helped write the Comprehensive Environmental Response, Compensation, and Liability Act, better known as Superfund. Superfund, passed in 1980 and amended in 1986, gives the agency the legal tools it needs to go after companies that refuse to pay to clean up hazardous waste sites they have created. If a company refuses to pay, the agency can beginmore » cleanup immediately by tapping the money Congress appropriated when it passed the law and then seek treble damages later. But the law has never been fully enforced: The EPA has begun treble-damage proceedings in just six cases, with none going to trial, and has only reluctantly began suits under Superfund's other legal provisions. As a result, according to a House Appropriations Committee report released last spring, the government is footing the bill for 70 percent of the EPA's Superfund cleanup studies and 55 percent of its cleanups. At this rate, the Superfund will easily be exhausted long before even half of the nearly 1,200 sites on today's National Priorities List are cleaned up. Meanwhile, dangerous wastes are still dumped illegally; most sites still don't get cleaned up; the EPA still doesn't force companies to pay for cleanups and Kaufman is still mad.« less

Warm Cleanup of Coal-Derived Syngas: Multicontaminant Removal Process Demonstration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Spies, Kurt A.; Rainbolt, James E.; Li, Xiaohong S.

Warm cleanup of coal- or biomass-derived syngas requires sorbent and catalytic beds to protect downstream processes and catalysts from fouling. Sulfur is particularly harmful because even parts-per-million amounts are sufficient to poison downstream synthesis catalysts. Zinc oxide (ZnO) is a conventional sorbent for sulfur removal; however, its operational performance using real gasifier-derived syngas and in an integrated warm cleanup process is not well reported. In this paper, we report the optimal temperature for bulk desulfurization to be 450oC, while removal of sulfur to parts-per-billion levels requires a lower temperature of approximately 350oC. Under these conditions, we found that sulfur inmore » the form of both hydrogen sulfide and carbonyl sulfide could be absorbed equally well using ZnO. For long-term operation, sorbent regeneration is desirable to minimize process costs. Over the course of five sulfidation and regeneration cycles, a ZnO bed lost about a third of its initial sulfur capacity, however sorbent capacity stabilized. Here, we also demonstrate, at the bench-scale, a process and materials used for warm cleanup of coal-derived syngas using five operations: 1) Na2CO3 for HCl removal, 2) regenerable ZnO beds for bulk sulfur removal, 3) a second ZnO bed for trace sulfur removal, 4) a Ni-Cu/C sorbent for multi-contaminant inorganic removal, and 5) a Ir-Ni/MgAl2O4 catalyst employed for ammonia decomposition and tar and light hydrocarbon steam reforming. Syngas cleanup was demonstrated through successful long-term performance of a poison-sensitive, Cu-based, water-gas-shift catalyst placed downstream of the cleanup process train. The tar reformer is an important and necessary operation with this particular gasification system; its inclusion was the difference between deactivating the water-gas catalyst with carbon deposition and successful 100-hour testing using 1 LPM of coal-derived syngas.« less

Clinical aspects of the health disturbances in Chernobyl Nuclear Power Plant accident clean-up workers (liquidators) from Latvia.

PubMed

Eglite, M E; Zvagule, T J; Rainsford, K D; Reste, J D; Curbakova, E V; Kurjane, N N

2009-06-01

The health status of some 6,000 workers from Latvia who went to clean-up the Chernobyl Nuclear Power Plant (CNPP) site following the explosion on 26 April 1986 has been analyzed. The data on these workers have been recorded in the Latvian State Register of Occupational disease patients and people exposed to ionizing radiation due to Chernobyl NPP accident (Latvian State Register) that was established in 1994. From these data, estimates have been made of external ionizing radiation to which these workers were exposed together with observations on the impact of exposure to heavy metals (especially lead and zinc) and radioactive isotopes released during the reactor 'meltdown'. These factors along with psycho-emotional and social-economic stresses account for a marked excess of mortality and morbidity in the group of CNPP accident clean-up workers compared with that of the non-exposed normal Latvian population adjusted for age and sex. The number of diseases or conditions in the CNPP accident clean-up workers has progressively risen from an average of 1.3 in 1986 to 10.9 in 2007. This exceeds for the Latvian population when adjusted for age and sex. The most serious conditions affect the nervous, digestive, respiratory, cardiovascular, endocrine (especially thyroid) and immunological systems. While the morbidity associated with diseases of the respiratory and digestive systems has decreased in recent years that in the other systems is increasing. In recent years, there has been an increased occurrence of cancers affecting the thyroid, prostate and stomach. Clinical and laboratory investigations suggest that surviving CNPP accident clean-up workers exhibit signs of immuno-inflammatory reactions causing premature aging with evidence of autoimmune diseases and immunological deficiencies or abnormalities. It is suggested that the CNPP accident clean-up workers may have a specific syndrome, the 'Chernobyl post-radiation neurosomatic polypathy', due to sustained oxidant stress injury, as a result of exposure to radiation and lead.

LONG-TERM STEWARDSHIP AT DOE HANFORD SITE - 12575

DOE Office of Scientific and Technical Information (OSTI.GOV)

MOREN RJ; GRINDSTAFF KD

2012-01-11

The U.S. Department of Energy's (DOE) Hanford Site is located in southeast Washington and consists of 1,518 square kilometers (586 square miles) of land. Established in 1943 as part of the Manhattan Project, Hanford workers produced plutonium for our nation's nuclear defense program until the mid 1980's. Since then, the site has been in cleanup mode that is being accomplished in phases. As we achieve remedial objectives and complete active cleanup, DOE will manage Hanford land under the Long-Term Stewardship (LTS) Program until completion of cleanup and the site becomes ready for transfer to the post cleanup landlord - currentlymore » planned for DOE's Office of Legacy Management (LM). We define Hanford's LTS Program in the ''Hanford Long-Term Stewardship Program Plan,'' (DOE/RL-201 0-35)[1], which describes the scope including the relationship between the cleanup projects and the LTS Program. DOE designed the LTS Program to manage and provide surveillance and maintenance (S&M) of institutional controls and associated monitoring of closed waste sites to ensure the protection of human health and the environment. DOE's Richland Operations Office (DOE-RL) and Hanford cleanup and operations contractors collaboratively developed this program over several years. The program's scope also includes 15 key activities that are identified in the DOE Program Plan (DOE/RL-2010-35). The LTS Program will transition 14 land segments through 2016. The combined land mass is approximately 570 square kilometers (220 square miles), with over 1,300 active and inactive waste sites and 3,363 wells. Land segments vary from buffer zone property with no known contamination to cocooned reactor buildings, demolished support facilities, and remediated cribs and trenches. DOE-RL will transition land management responsibilities from cleanup contractors to the Mission Support Contract (MSC), who will then administer the LTS Program for DOE-RL. This process requires an environment of cooperation between the contractors and DOE-RL. Information Management (IM) is a key part of the LTS program. The IM Program identifies, locates, stores, protects and makes accessible Hanford LTS records and data to support the transfer of property ultimately to LM. As such, DOE-RL manages the Hanford LTS Program in a manner consistent with LM's goals, policies, and procedures.« less

Individualized Math Problems in Volume. Oregon Vo-Tech Mathematics Problem Sets.

ERIC Educational Resources Information Center

Cosler, Norma, Ed.

This is one of eighteen sets of individualized mathematics problems developed by the Oregon Vo-Tech Math Project. Each of these problem packages is organized around a mathematical topic and contains problems related to diverse vocations. Solutions are provided for all problems. Problems in this booklet require the computation of volumes of solids,…

Optimization-based mesh correction with volume and convexity constraints

DOE PAGES

D'Elia, Marta; Ridzal, Denis; Peterson, Kara J.; ...

2016-02-24

In this study, we consider the problem of finding a mesh such that 1) it is the closest, with respect to a suitable metric, to a given source mesh having the same connectivity, and 2) the volumes of its cells match a set of prescribed positive values that are not necessarily equal to the cell volumes in the source mesh. This volume correction problem arises in important simulation contexts, such as satisfying a discrete geometric conservation law and solving transport equations by incremental remapping or similar semi-Lagrangian transport schemes. In this paper we formulate volume correction as a constrained optimizationmore » problem in which the distance to the source mesh defines an optimization objective, while the prescribed cell volumes, mesh validity and/or cell convexity specify the constraints. We solve this problem numerically using a sequential quadratic programming (SQP) method whose performance scales with the mesh size. To achieve scalable performance we develop a specialized multigrid-based preconditioner for optimality systems that arise in the application of the SQP method to the volume correction problem. Numerical examples illustrate the importance of volume correction, and showcase the accuracy, robustness and scalability of our approach.« less

78 FR 28242 - Proposed Information Collection; Cleanup Program for Accumulations of Coal and Float Coal Dusts...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-14

... Program for Accumulations of Coal and Float Coal Dusts, Loose Coal, and Other Combustibles AGENCY: Mine... collection for developing and updating a cleanup program for accumulations of coal and float coal dusts, loose coal, and other combustibles in underground coal mines. DATES: All comments must be postmarked or...

Separation and determination of citrinin in corn using HPLC fluorescence detection assisted by molecularly imprinted solid phase extraction clean-up

USDA-ARS?s Scientific Manuscript database

A liquid chromatography based method to detect citrinin in corn was developed using molecularly imprinted solid phase extraction (MISPE) sample clean-up. Molecularly imprinted polymers were synthesized using 1,4-dihydroxy-2-naphthoic acid as the template and an amine functional monomer. Density func...

Cleanup Verification Package for the 600-47 Waste Site

DOE Office of Scientific and Technical Information (OSTI.GOV)

M. J. Cutlip

This cleanup verification package documents completion of interim remedial action for the 600-47 waste site. This site consisted of several areas of surface debris and contamination near the banks of the Columbia River across from Johnson Island. Contaminated material identified in field surveys included four areas of soil, wood, nuts, bolts, and other metal debris.

DNA strand displacement reaction for programmable release of biomolecules.

PubMed

Ramezani, Hamid; Jed Harrison, D

2015-05-14

Sample cleanup is a major processing step in many analytical assays. Here, we propose an approach to capture-and-release of analytes based on the DNA strand displacement reaction (SDR) and demonstrate its application to a fluoroimmunoassay on beads for a thyroid cancer biomarker, thyroglobulin. The SDR-based cleanup showed no interference from matrix molecules in serum.

A Comparative Study of American, Japanese, and Taiwanese Early Childhood Teachers' Perceptions of Clean-Up Time

ERIC Educational Resources Information Center

Izumi-Taylor, Satomi; Ito, Yoko; Lin, Chia-Hui; Akita, Kiyomi

2017-01-01

The purpose of this study was to examine similarities and differences of American, Japanese, and Taiwanese kindergarten teachers' perspectives about clean-up time. The participants consisted of two female American kindergarten teachers in the southeastern US, two female Japanese kindergarten teachers on the main island, and two female Taiwanese…

DEVELOPMENT AND APPLICATION OF IMMUNOAFFINITY COLUMN CHROMATOGRAPHY AS A CLEANUP METHOD FOR THE DETERMINATION OF ATRAZINE IN COMPLEX ENVIRONMENTAL SAMPLE MEDIA

EPA Science Inventory

A rabbit antibody immunoaffinity (IA) column procedure was evaluated as a cleanup method for the determination of atrazine in soil, sediment, and food. Four IA columns were prepared by immobilizing a polyclonal rabbit anti-atrazine antibody solution to HiTrap Sepharose columns. A...

Reedy Creek Cleanup: The Evolution of a University Geography Service-Learning Project

ERIC Educational Resources Information Center

Parece, Tammy E.; Aspaas, Helen Ruth

2007-01-01

Service-learning courses within a university setting help students to better understand their roles as members of civil society. This article examines the evolution of an urban stream cleanup project that has been part of a world regions geography course for six years. After connecting course goals with the current best practice literature on…

Cleanup Verification Package for the 118-F-7, 100-F Miscellaneous Hardware Storage Vault

DOE Office of Scientific and Technical Information (OSTI.GOV)

M. J. Appel

2006-11-02

This cleanup verification package documents completion of remedial action for the 118-F-7, 100-F Miscellaneous Hardware Storage Vault. The site consisted of an inactive solid waste storage vault used for temporary storage of slightly contaminated reactor parts that could be recovered and reused for the 100-F Area reactor operations.

Female adolescents with severe substance and conduct problems have substantially less brain gray matter volume.

PubMed

Dalwani, Manish S; McMahon, Mary Agnes; Mikulich-Gilbertson, Susan K; Young, Susan E; Regner, Michael F; Raymond, Kristen M; McWilliams, Shannon K; Banich, Marie T; Tanabe, Jody L; Crowley, Thomas J; Sakai, Joseph T

2015-01-01

Structural neuroimaging studies have demonstrated lower regional gray matter volume in adolescents with severe substance and conduct problems. These research studies, including ours, have generally focused on male-only or mixed-sex samples of adolescents with conduct and/or substance problems. Here we compare gray matter volume between female adolescents with severe substance and conduct problems and female healthy controls of similar ages. Female adolescents with severe substance and conduct problems will show significantly less gray matter volume in frontal regions critical to inhibition (i.e. dorsolateral prefrontal cortex and ventrolateral prefrontal cortex), conflict processing (i.e., anterior cingulate), valuation of expected outcomes (i.e., medial orbitofrontal cortex) and the dopamine reward system (i.e. striatum). We conducted whole-brain voxel-based morphometric comparison of structural MR images of 22 patients (14-18 years) with severe substance and conduct problems and 21 controls of similar age using statistical parametric mapping (SPM) and voxel-based morphometric (VBM8) toolbox. We tested group differences in regional gray matter volume with analyses of covariance, adjusting for age and IQ at p<0.05, corrected for multiple comparisons at whole-brain cluster-level threshold. Female adolescents with severe substance and conduct problems compared to controls showed significantly less gray matter volume in right dorsolateral prefrontal cortex, left ventrolateral prefrontal cortex, medial orbitofrontal cortex, anterior cingulate, bilateral somatosensory cortex, left supramarginal gyrus, and bilateral angular gyrus. Considering the entire brain, patients had 9.5% less overall gray matter volume compared to controls. Female adolescents with severe substance and conduct problems in comparison to similarly aged female healthy controls showed substantially lower gray matter volume in brain regions involved in inhibition, conflict processing, valuation of outcomes, decision-making, reward, risk-taking, and rule-breaking antisocial behavior.

Myelodysplastic syndromes in Chernobyl clean-up workers.

PubMed

Gluzman, Daniil F; Sklyarenko, Lilia M; Koval, Stella V; Rodionova, Nataliia K; Zavelevich, Michael P; Ivanivskaya, Tetiana S; Poludnenko, Liudmyla Yu; Ukrainskaya, Nataliia I

2015-10-01

The studies of the recent decades posed the question of the association between radiation exposure and myelodysplastic syndromes (MDS). This association has been proved in secondary MDS originating upon exposure to chemotherapeutics and/or radiation therapy. The long-term study in Japanese atomic (A)-bomb survivors demonstrated the significant linear dose-response for MDS confirming the link between radiation exposure and this form of hematopoietic malignancies. All these findings provide the strong basis for studying MDS in the persons exposed to radiation following the Chernobyl disaster, especially those in the cohort of Chernobyl clean-up workers of 1986-1987. The data on MDS among Chernobyl clean-up workers (1986-1987) diagnosed in 1996-2012 at the reference laboratory of RE Kavetsky Institute of Experimental Pathology, Oncology and Radiobiology are summarized. MDS cases were diagnosed in 23 persons (21 males and 2 females) having been exposed to radiation as clean-up workers of 1986-1987. Refractory anemia (RA) has been detected in 13, refractory anemia with ring sideroblasts (RARS)-in 2, and refractory anemia with excess blasts (RAEB)-in 8 patients. The median age of those MDS patients was 62.0 years. In addition, 5 cases of chronic myelomonocytic leukemia (CMML) were recorded in the group of Chernobyl clean-up workers with the median time of 14.8 years from 1986-1987 to diagnosis. The association between radiation exposure and MDS is discussed. The suggested life-long risk for myelodysplastic syndromes among A-bomb survivors in Japan highlights the importance of the continuing follow-up studies in the affected populations in the post-Chernobyl period.

Coupling of headspace solid phase microextraction with ultrasonic extraction for the determination of chlorinated pesticides in bird livers using gas chromatography.

PubMed

Lambropoulou, Dimitra A; Konstantinou, Ioannis K; Albanis, Triantafyllos A

2006-07-28

In the present study a combined analytical method involving ultrasonic extraction (USE), sulfuric acid clean-up and headspace solid-phase microextraction (HS-SPME) was developed for the determination of chlorinated pesticides (CPs) in bird livers. Extraction of CPs from 1g of liver was performed by ultrasonication for 30 min using 20 mL of solvent mixture (n-hexane:acetone (4:1, v/v)). The extract was subsequently subjected to a clean-up step for lipid removal. A comparative study on several clean-up procedures prior to the HS-SPME enrichment step was performed in order to achieve maximum recovery and optimal clean-up efficiency, which would provide suitable limits of detection in the gas chromatographic analysis. For this purpose, destructive (sulfuric acid or sodium hydroxide treatment) and non-destructive (alumina column) clean-up procedures has been assayed. The treatment of the extract with 40% (v/v) H2SO4 prior to HS-SPME process showed the best performance since lower detection limits and higher extraction efficiencies were obtained. The method detection limit ranged from 0.5 to 1.0 ng g(-1) wet weight and peak areas were proportional to analyte concentrations (r2>0.990) in the range of 5-500 ng g(-1) wet wt. The method was found to be reproducible (R.S.D.<10%) and effective under the operational conditions proposed and was applied successfully to the analysis of CPs in liver tissues of various bird species from Greece.

Demonstration of Spacecraft Fire Safety Technology

NASA Technical Reports Server (NTRS)

Ruff, Gary A.; Urban, David L.

2012-01-01

During the Constellation Program, the development of spacecraft fire safety technologies were focused on the immediate questions related to the atmosphere of the habitable volume and implementation of fire detection, suppression, and postfire clean-up systems into the vehicle architectures. One of the difficulties encountered during the trade studies for these systems was the frequent lack of data regarding the performance of a technology, such as a water mist fire suppression system or an optically-based combustion product monitor. Even though a spacecraft fire safety technology development project was being funded, there was insufficient time and funding to address all the issues as they were identified. At the conclusion of the Constellation Program, these knowledge gaps formed the basis for a project proposed to the Advanced Exploration Systems (AES) Program. This project, subsequently funded by the AES Program and in operation since October 2011, has as its cornerstone the development of an experiment to be conducted on an ISS resupply vehicle, such as the European Space Agency (ESA) Automated Transfer Vehicle (ATV) or Orbital Science s Cygnus vehicle after it leaves the ISS and before it enters the atmosphere. The technology development efforts being conducted in this project include continued quantification of low- and partial-gravity maximum oxygen concentrations of spacecraft-relevant materials, development and verification of sensors for fire detection and post-fire monitoring, development of standards for sizing and selecting spacecraft fire suppression systems, and demonstration of post-fire cleanup strategies. The major technology development efforts are identified in this paper but its primary purpose is to describe the spacecraft fire safety demonstration being planned for the reentry vehicle.

[Analysis of sulfonamide residues in pork and chicken by high performance liquid chromatography coupled with solid-phase extraction using multiwalled carbon nanotubes as adsorbent].

PubMed

Zhao, Haixiang; Liu, Haiping; Yan, Zaoying

2014-03-01

A multi-residue analytical method based on solid-phase extraction (SPE) with multiwalled carbon nanotubes (MWCNTs) as sorbent was developed. The determination of the sulfonamides (SAs) in pork and chicken was carried out by high performance liquid chromatography-ultraviolet detection (HPLC-UV). The clean-up conditions were optimized. The analytes were extracted by acetonitril and cleaned-up by MWCNTs SPE cartridge. The extract was redissolved with the Na2HPO4 buffer (pH 5.5-6.0) for loading, and was washed with acetone-hexane (5:95, v/v), then eluted with acetone-dichloromethane (1:1, v/v) from the column. The mobile phase used in the chromatographic separation consisted of a binary mixture of acetonitrile and 50 mmol/L NaH2PO4 with the volume ratio of 7:3. A wide linear range was 0.01-1.00 mg/L with the correlation coefficients above 0.998. The limits of detection (S/N = 3) were 0.003 mg/L, and the limits of quantification (S/N = 10) were 0.01 mg/L. The average recoveries were over 70% for the nine SAs in the spiked range of 0.02-0.2 mg/kg, with the relative standard deviations (RSDs) lower than 8%. This study indicated that the MWCNTs SPE cartridge is efficient for the clean-up of the SAs in animal tissues or products, and the method is simple, accurate and suitable for the quantification of the SAs residues.

Automated mini-column solid-phase extraction cleanup for high-throughput analysis of chemical contaminants in foods by low-pressure gas chromatography – tandem mass spectrometry

USDA-ARS?s Scientific Manuscript database

This study demonstrated the application of an automated high-throughput mini-cartridge solid-phase extraction (mini-SPE) cleanup for the rapid low-pressure gas chromatography – tandem mass spectrometry (LPGC-MS/MS) analysis of pesticides and environmental contaminants in QuEChERS extracts of foods. ...

IED Cleanup: A Cooperative Classroom Robotics Challenge--The Benefits and Execution of a Cooperative Classroom Robotics Challenge

ERIC Educational Resources Information Center

Piotrowski, Mark; Kressly, Rich

2009-01-01

This article describes a cooperative classroom robotics challenge named "IED Cleanup". This classroom challenge was created to incorporate a humanitarian project with the use of a robotics design system in order to remove simulated IEDs (Improvised Explosive Devices) to a detonation zone within a specified amount of time. Throughout the activity,…

Renewable Natural Gas Clean-up Challenges and Applications

DTIC Science & Technology

2011-01-13

produced from digesters ─ Animal manure (dairy cows, swine) ─ Waste water treatment facilities > Methane from Landfills > RNG produced from...AGR used in process • Two stage + trim methanation reactor • Dehydration to achieve gas pipeline specifications ~ 70% conversion efficiency 21... digestion of agricultural waste for on-site electricity generation ─Altamont Landfill—Landfill gas (LFG) cleanup for production of liquefied natural gas

Cleanup Verification Package for the 618-2 Burial Ground

DOE Office of Scientific and Technical Information (OSTI.GOV)

W. S. Thompson

2006-12-28

This cleanup verification package documents completion of remedial action for the 618-2 Burial Ground, also referred to as Solid Waste Burial Ground No. 2; Burial Ground No. 2; 318-2; and Dry Waste Burial Site No. 2. This waste site was used primarily for the disposal of contaminated equipment, materials and laboratory waste from the 300 Area Facilities.

Cleanup Verification Package for the 118-C-1, 105-C Solid Waste Burial Ground

DOE Office of Scientific and Technical Information (OSTI.GOV)

M. J. Appel and J. M. Capron

2007-07-25

This cleanup verification package documents completion of remedial action for the 118-C-1, 105-C Solid Waste Burial Ground. This waste site was the primary burial ground for general wastes from the operation of the 105-C Reactor and received process tubes, aluminum fuel spacers, control rods, reactor hardware, spent nuclear fuel and soft wastes.

Military Base Closures: Opportunities Exist to Improve Environmental Cleanup Cost Reporting and to Expedite Transfer of Unneeded Property

DTIC Science & Technology

2007-01-01

substances released after 1986 and munitions released after 2002 are not eligible for DERP funds. These cleanups are generally referred to as non -DERP...relocating functions from one installation to...requirements during the process of property disposal and during the process of relocating functions from one installation to another. The National

Department of Defense Environmental Cleanup Cost Allowability Policy.

DTIC Science & Technology

1994-12-01

The environment is directly affected by the industrial requirements and manufacturing processes necessary to provide those goods and services. As...and the industrial base. To begin the process , DCMC initiated the Environmental Initiatives Task Force Pilot Cost Allowance Program at five locations...policy covering environmental cleanup costs. Information will be provided to assist in the decision making process regarding the factors affecting the

Personal hygienic concerns in long term space flight

NASA Technical Reports Server (NTRS)

1973-01-01

Data from numerous experiments and hardware inventories were scanned for Skylab personal hygiene use. A computer program was formulated for predicting the degree of man's involvement with personal hygiene needs. A tabulation was kept for such events as water intake, frequency of urination and defecation, accidents or events requiring clean-up, methods of clean-up, microbiological environment and shower water contamination.

Hantavirus Prevention: Cleanup of Rodent Contamination

DTIC Science & Technology

2008-09-01

Hantaviruses in the Americas may cause human disease involving the lungs, hence the name " hantavirus pulmonary syndrome" (HPS). Since May 1993, a...humans are also found in other rodents, but the number of cases stemming from these hantaviruses is small when compared to SNV. Hantavirus is shed in... HANTAVIRUS PREVENTION: CLEANUP OF RODENT CONTAMINATION Technical Information Paper 18-001-0306

Military Base Realignments and Closures: DOD has Improved Environmental Cleanup Reporting but Should Obtain and Share More Information

DTIC Science & Technology

2017-01-01

Defense (DOD) has captured and reported more comprehensive cost information in its environmental cost reporting for installations closed under the...Letter 1 Background 4 DOD’s Latest Report to Congress Captures More- Comprehensive Environmental Cleanup Cost Information, but Omits Emerging...22 Abbreviations BRAC Base Realignment and Closure CERCLA Comprehensive Environmental Response, Compensation, and

Experimental design for extraction and quantification of phenolic compounds and organic acids in white "Vinho Verde" grapes.

PubMed

Dopico-García, M S; Valentão, P; Guerra, L; Andrade, P B; Seabra, R M

2007-01-30

An experimental design was applied for the optimization of extraction and clean-up processes of phenolic compounds and organic acids from white "Vinho Verde" grapes. The developed analytical method consisted in two steps: first a solid-liquid extraction of both phenolic compounds and organic acids and then a clean-up step using solid-phase extraction (SPE). Afterwards, phenolic compounds and organic acids were determined by high-performance liquid chromatography (HPLC) coupled to a diode array detector (DAD) and HPLC-UV, respectively. Plackett-Burman design was carried out to select the significant experimental parameters affecting both the extraction and the clean-up steps. The identified and quantified phenolic compounds were: quercetin-3-O-glucoside, quercetin-3-O-rutinoside, kaempferol-3-O-rutinoside, isorhamnetin-3-O-glucoside, quercetin, kaempferol and epicatechin. The determined organic acids were oxalic, citric, tartaric, malic, shikimic and fumaric acids. The obtained results showed that the most important variables were the temperature (40 degrees C) and the solvent (acid water at pH 2 with 5% methanol) for the extraction step and the type of sorbent (C18 non end-capped) for the clean-up step.

Multivariate methods for evaluating the efficiency of electrodialytic removal of heavy metals from polluted harbour sediments.

PubMed

Pedersen, Kristine Bondo; Kirkelund, Gunvor M; Ottosen, Lisbeth M; Jensen, Pernille E; Lejon, Tore

2015-01-01

Chemometrics was used to develop a multivariate model based on 46 previously reported electrodialytic remediation experiments (EDR) of five different harbour sediments. The model predicted final concentrations of Cd, Cu, Pb and Zn as a function of current density, remediation time, stirring rate, dry/wet sediment, cell set-up as well as sediment properties. Evaluation of the model showed that remediation time and current density had the highest comparative influence on the clean-up levels. Individual models for each heavy metal showed variance in the variable importance, indicating that the targeted heavy metals were bound to different sediment fractions. Based on the results, a PLS model was used to design five new EDR experiments of a sixth sediment to achieve specified clean-up levels of Cu and Pb. The removal efficiencies were up to 82% for Cu and 87% for Pb and the targeted clean-up levels were met in four out of five experiments. The clean-up levels were better than predicted by the model, which could hence be used for predicting an approximate remediation strategy; the modelling power will however improve with more data included. Copyright © 2014 Elsevier B.V. All rights reserved.

Persistent marine litter: small plastics and cigarette butts remain on beaches after organized beach cleanups.

PubMed

Loizidou, Xenia I; Loizides, Michael I; Orthodoxou, Demetra L

2018-06-20

Cyprus is an island country in the Eastern Mediterranean whose economy is largely dependent on coastal tourism. It boasts some of the cleanest waters in Europe and has the largest number of Blue Flag awarded beaches per capita in the world. These beaches are managed by local authorities and are regularly cleaned, throughout the year, at least once per day. This paper presents findings from cleanups that were organized over the summers of 2016 and 2017 on nine Blue Flag beaches around the island of Cyprus, after the beaches were cleaned by the responsible authorities. The aim was to answer the following questions: 'Are regular beach cleanups by local authorities efficient?' and 'What is left on a "clean" beach?' The results suggest that local authority cleanup efforts are quite successful at collecting larger pieces of marine litter, leaving the beach seemingly clean. However, small pieces of litter, such as cigarette butts and small pieces of plastic items related to recreational activities, remain on the beach. They likely accumulate or are buried over time, with some items becoming a nuisance to beach goers and a potential source of marine litter.

Determination of mycotoxins produced by Fusarium isolates from banana fruits by capillary gas chromatography and high-performance liquid chromatography.

PubMed

Jiménez, M; Mateo, R

1997-08-22

A method of analysis for trichothecenes (nivalenol, deoxynivalenol, 3- and 15-acetyldeoxynivalenol, diacetoxyscirpenol, neosolaniol, T-2 tetraol, T-2 and HT-2 toxins), zearalenone and zearalenols, and another method for determination of fumonisin B1 are described and applied to cultures of Fusarium isolated from bananas. Both methods were adapted from different techniques of extraction, clean-up and determination of these mycotoxins. The first method involves extraction with methanol-1% aqueous sodium chloride, clean-up of extracts by partition with hexane and dichloromethane, additional solid reversed-phase clean-up and analysis of two eluates by both high-performance liquid chromatography with ultraviolet detection and capillary gas chromatography. The method for fumonisin B1 implies extraction with aqueous methanol, concentration, clean-up with water and methanol on Amberlite XAD-2 column, formation of a fluorescent 4-fluoro-7-nitrobenzofurazan derivative and analysis by high-performance liquid chromatography with fluorescence detection. Both procedures give good limits of detection and recoveries, and are considered suitable for the detection and quantification of the studied toxins in corn and rice cultures of Fusarium spp. isolated from banana fruits.

Recent advances in analytical methods for the determination of 4-alkylphenols and bisphenol A in solid environmental matrices: A critical review.

PubMed

Salgueiro-González, N; Castiglioni, S; Zuccato, E; Turnes-Carou, I; López-Mahía, P; Muniategui-Lorenzo, S

2018-09-18

The problem of endocrine disrupting compounds (EDCs) in the environment has become a worldwide concern in recent decades. Besides their toxicological effects at low concentrations and their widespread use in industrial and household applications, these pollutants pose a risk for non-target organisms and also for public safety. Analytical methods to determine these compounds at trace levels in different matrices are urgently needed. This review critically discusses trends in analytical methods for well-known EDCs like alkylphenols and bisphenol A in solid environmental matrices, including sediment and aquatic biological samples (from 2006 to 2018). Information about extraction, clean-up and determination is covered in detail, including analytical quality parameters (QA/QC). Conventional and novel analytical techniques are compared, with their advantages and drawbacks. Ultrasound assisted extraction followed by solid phase extraction clean-up is the most widely used procedure for sediment and aquatic biological samples, although softer extraction conditions have been employed for the latter. The use of liquid chromatography followed by tandem mass spectrometry has greatly increased in the last five years. The majority of these methods have been employed for the analysis of river sediments and bivalve molluscs because of their usefulness in aquatic ecosystem (bio)monitoring programs. Green, simple, fast analytical methods are now needed to determine these compounds in complex matrices. Copyright © 2018 Elsevier B.V. All rights reserved.

The precautionary principle and chemicals management: The example of perfluoroalkyl acids in groundwater.

PubMed

Cousins, Ian T; Vestergren, Robin; Wang, Zhanyun; Scheringer, Martin; McLachlan, Michael S

2016-09-01

Already in the late 1990s microgram-per-liter levels of perfluorooctane sulfonate (PFOS) were measured in water samples from areas where fire-fighting foams were used or spilled. Despite these early warnings, the problems of groundwater, and thus drinking water, contaminated with perfluoroalkyl and polyfluoroalkyl substances (PFASs) including PFOS are only beginning to be addressed. It is clear that this PFAS contamination is poorly reversible and that the societal costs of clean-up will be high. This inability to reverse exposure in a reasonable timeframe is a major motivation for application of the precautionary principle in chemicals management. We conclude that exposure can be poorly reversible; 1) due to slow elimination kinetics in organisms, or 2) due to poorly reversible environmental contamination that leads to continuous exposure. In the second case, which is relevant for contaminated groundwater, the reversibility of exposure is not related to the magnitude of a chemical's bioaccumulation potential. We argue therefore that all PFASs entering groundwater, irrespective of their perfluoroalkyl chain length and bioaccumulation potential, will result in poorly reversible exposures and risks as well as further clean-up costs for society. To protect groundwater resources for future generations, society should consider a precautionary approach to chemicals management and prevent the use and release of highly persistent and mobile chemicals such as PFASs. Copyright © 2016 Elsevier Ltd. All rights reserved.

Analysis of medical treatment at a field hospital following Hurricane Andrew, 1992.

PubMed

Alson, R; Alexander, D; Leonard, R B; Stringer, L W

1993-11-01

To determine what medical care was required of a special operations response team by a community devastated by a major hurricane. Retrospective analysis of 1,544 patient encounter forms generated at a field hospital set up in Homestead, Florida, after Hurricane Andrew in August 1992 and staffed by the special operations response team from Forsyth County, North Carolina. All persons presenting for treatment. One thousand two hundred three adult patients and 336 pediatric patients were seen by the special operations response team. Only five of the injuries treated were due directly to the hurricane, whereas 285 of the treated injuries were sustained during clean-up activities. Most of the care provided was routine medical care denied the citizens due to the loss of their physicians' offices and clinics. Supplies of tetanus toxoid, antibiotics, and insulin were depleted in 24 hours. Resupplying these items and acquiring other medication to refill prescriptions constituted a pressing problem. The primary function of medical personnel responding to an area hit by a major hurricane will be to provide general medical care. Any trauma encountered will be primarily due to clean-up activities and not due to the hurricane itself. Responding medical personnel should plan on providing their own food and water for the first 72 hours and be well stocked with antibiotics, tetanus toxoid, and insulin.

Legacy Code Modernization

NASA Technical Reports Server (NTRS)

Hribar, Michelle R.; Frumkin, Michael; Jin, Haoqiang; Waheed, Abdul; Yan, Jerry; Saini, Subhash (Technical Monitor)

1998-01-01

Over the past decade, high performance computing has evolved rapidly; systems based on commodity microprocessors have been introduced in quick succession from at least seven vendors/families. Porting codes to every new architecture is a difficult problem; in particular, here at NASA, there are many large CFD applications that are very costly to port to new machines by hand. The LCM ("Legacy Code Modernization") Project is the development of an integrated parallelization environment (IPE) which performs the automated mapping of legacy CFD (Fortran) applications to state-of-the-art high performance computers. While most projects to port codes focus on the parallelization of the code, we consider porting to be an iterative process consisting of several steps: 1) code cleanup, 2) serial optimization,3) parallelization, 4) performance monitoring and visualization, 5) intelligent tools for automated tuning using performance prediction and 6) machine specific optimization. The approach for building this parallelization environment is to build the components for each of the steps simultaneously and then integrate them together. The demonstration will exhibit our latest research in building this environment: 1. Parallelizing tools and compiler evaluation. 2. Code cleanup and serial optimization using automated scripts 3. Development of a code generator for performance prediction 4. Automated partitioning 5. Automated insertion of directives. These demonstrations will exhibit the effectiveness of an automated approach for all the steps involved with porting and tuning a legacy code application for a new architecture.

Determination of Total Biotin by Liquid Chromatography Coupled with Immunoaffinity Column Cleanup Extraction: Multilaboratory Testing, Final Action 2016.02.

PubMed

Joseph, George; Devi, Ranjani; Marley, Elaine C; Leeman, David

2018-05-01

Single- and multilaboratory testing data have provided systematic scientific evidence that a simple, selective, accurate, and precise method can be used as a potential candidate reference method for dispute resolution in determining total biotin in all forms of infant, adult, and/or pediatric formula. Using LC coupled with immunoaffinity column cleanup extraction, the method fully meets the intended purpose and applicability statement in AOAC Standard Method Performance Requirement 2014.005. The method was applied to a cross-section of infant formula and adult nutritional matrixes, and acceptable precision and accuracy were established. The analytical platform is inexpensive, and the method can be used in almost any laboratory worldwide with basic facilities. The immunoaffinity column cleanup extraction is the key step to successful analysis.

Brownfields and Land Revitalization Programmatic Information

EPA Pesticide Factsheets

This asset contains resources provided by EPA's Brownfields and Land Revitalization program that can be used for the assessment, cleanup, and redevelopment of brownfields sites and land revitalization activities. To help implement the program, EPA provides information on the Brownfields law, success stories from Brownfields grantees, technical information and resources to aid in the assessment and cleanup of brownfields properties, partnerships to promote the cleanup and reuse of Brownfields, and initiatives that explore sector-based solutions, enhance environmental quality, spur economic development, and revitalize communities. This asset includes fact sheets, success stories, training, policy, and guidance documents. Regulatory authority for the collection and use of this information is found in the Small Business Liability Relief and Brownfields Revitalization Act of 2002 (the Brownfields Law), which amended the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) of 1980.

Mental health indicators associated with oil spill response and clean-up: cross-sectional analysis of the GuLF STUDY cohort.

PubMed

Kwok, Richard K; McGrath, John A; Lowe, Sarah R; Engel, Lawrence S; Jackson, W Braxton; Curry, Matthew D; Payne, Julianne; Galea, Sandro; Sandler, Dale P

2017-12-01

Adverse mental health effects have been reported following oil spills but few studies have identified specific responsible attributes of the clean-up experience. We aimed to analyse the effects of the 2010 Deepwater Horizon (Gulf of Mexico) disaster on the mental health of individuals involved in oil spill response and clean-up. We used data from the Gulf Long-term Follow-up Study, a cohort of workers and volunteers involved in oil spill clean-up after the Deepwater Horizon disaster. We included 8968 workers (hired after completing training for oil spill response and clean-up) and 2225 non-workers (completed training but were not hired) who completed a Patient Health Questionnaire-8 and four-item Primary Care PTSD Screen to assess for probable depression and post-traumatic stress disorder (PTSD) indicators. Participants were recruited between March 28, 2011, and March 29, 2013. The mental health indicators were assessed at home visits done between May 12, 2011, and May 15, 2013. We used regression models to analyse the effect of potentially stressful job experiences, job type, and total hydrocarbon exposure on mental health indicators. Oil spill response and clean-up work was associated with increased prevalence of depression (prevalence ratio [PR] 1·22, 95% CI 1·08-1·37) and PTSD (PR 1·35, 95% CI 1·07-1·71). Among workers, individuals who reported smelling oil, dispersants, or cleaning chemicals had an elevated prevalence of depression (1·56, 1·37-1·78) and PTSD (2·25, 1·71-2·96). Stopping work because of the heat was also associated with depression (1·37, 1·23-1·53) and PTSD (1·41, 1·15-1·74), as was working as a commercial fisherman before the spill (1·38, 1·21-1·57; and 2·01, 1·58-2·55, respectively). An increase in exposure to total hydrocarbons appeared to be associated with depression and PTSD, but after taking into account oil spill job experiences, only the association between the highest amount of total hydrocarbons and PTSD remained (1·75, 1·11-2·76). Oil spill clean-up workers with high amounts of total hydrocarbon exposure or potentially stressful job experiences had an increased prevalence of depression and PTSD. These findings provide evidence that response and clean-up work is associated with adverse psychological effects and suggest the need for mental health services both before and after the event. National Institutes of Health (NIH) Common Fund and the Intramural Research Program of the NIH, National Institute of Environmental Health Sciences. Copyright © 2017 The Author(s). Published by Elsevier Ltd. This is an Open Access article under the CC BY 4.0 license. Published by Elsevier Ltd.. All rights reserved.

Paternal Alcoholism and Toddler Noncompliance

PubMed Central

Eiden, Rina Das; Leonard, Kenneth E.; Morrisey, Sean

2009-01-01

Background This study examined the effect of fathers’ alcoholism and associated risk factors on toddler compliance with parental directives at 18 and 24 months of age. Methods Participants were 215 families with 12-month-old children, recruited through birth records, who completed assessments of parental substance use, family functioning, and parent-child interactions at 12, 18, and 24 months of child age. Of these families, 96 were in the control group, 89 families were in the father-alcoholic-only group, and 30 families were in the group with two alcohol-problem parents. Child compliance with parents during cleanup situations after free play was measured at 18 and 24 months. The focus of this paper is on four measures of compliance: committed compliance, passive noncompliance, overt resistance, and defiance. Results Sons of alcohol-problem parents exhibited higher rates of noncompliance compared with sons of nonalcoholic parents. Sons in the two-alcohol-problem parent group seemed to be following a trajectory toward increasing rates of noncompliance. Daughters in the two-alcohol-problem parent group followed an opposite pattern. Other risk factors associated with parental alcohol problems also predicted compliance, but in unexpected ways. Conclusions Results indicate that early risk for behavioral undercontrol is present in the toddler period among sons of alcoholic fathers, but not among daughters. PMID:11707637

Miniature Fuel Processors for Portable Fuel Cell Power Supplies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Holladay, Jamie D.; Jones, Evan O.; Palo, Daniel R.

2003-06-02

Miniature and micro-scale fuel processors are discussed. The enabling technologies for these devices are the novel catalysts and the micro-technology-based designs. The novel catalyst allows for methanol reforming at high gas hourly space velocities of 50,000 hr-1 or higher, while maintaining a carbon monoxide levels at 1% or less. The micro-technology-based designs enable the devices to be extremely compact and lightweight. The miniature fuel processors can nominally provide between 25-50 watts equivalent of hydrogen which is ample for soldier or personal portable power supplies. The integrated processors have a volume less than 50 cm3, a mass less than 150 grams,more » and thermal efficiencies of up to 83%. With reasonable assumptions on fuel cell efficiencies, anode gas and water management, parasitic power loss, etc., the energy density was estimated at 1700 Whr/kg. The miniature processors have been demonstrated with a carbon monoxide clean-up method and a fuel cell stack. The micro-scale fuel processors have been designed to provide up to 0.3 watt equivalent of power with efficiencies over 20%. They have a volume of less than 0.25 cm3 and a mass of less than 1 gram.« less

Environmental trends

DOE Office of Scientific and Technical Information (OSTI.GOV)

Levin, M.; Smith, K.W.

1990-05-01

This article discusses Superfund's Amendments and Reauthorization Act of 1986; specifically, the provisions for release from liability for cleanup of contaminated property. These provisions are based on proof of innocence of prior knowledge before acquisition of the property. However, it appears that there are real problems in the determination of the level of inquiry necessary in good-faith site audits. Criminal penalties for knowing violations of permits or knowing releases of certain air emissions in the pending Clean Air Act may discourage sources from acquiring corrective knowledge through environmental audits. EPA's developing Enforcement for the 1990's project may seek to makemore » the absence of audit systems evidence of bad faith for general penalty purposes under the Agency's statutes.« less

Simultaneous Solid Phase Extraction and Derivatization of Aliphatic Primary Amines Prior to Separation and UV-Absorbance Detection

PubMed Central

Felhofer, Jessica L.; Scida, Karen; Penick, Mark; Willis, Peter A.; Garcia, Carlos D.

2013-01-01

To overcome the problem of poor sensitivity of capillary electrophoresis-UV absorbance for the detection of aliphatic amines, a solid phase extraction and derivatization scheme was developed. This work demonstrates successful coupling of amines to a chromophore immobilized on a solid phase and subsequent cleavage and analysis. Although the analysis of many types of amines is relevant for myriad applications, this paper focuses on the derivatization and separation of amines with environmental relevance. This work aims to provide the foundations for future developments of an integrated sample preparation microreactor capable of performing simultaneous derivatization, preconcentration, and sample cleanup for sensitive analysis of primary amines. PMID:24054648

DOE Office of Scientific and Technical Information (OSTI.GOV)

Palmer, P.A.

The Lasagna project is the first of what we expect will be several large cooperative projects between industry consortia and government to develop improved remediation technologies. In 1992, Monsanto Company began contacting other major corporations to see if they were experiencing similar difficulties in applying cost-effective, or even workable technologies for industrial site remediation. Both General Electric and DuPont were early participants in the effort to develop a meeting with the EPA to discuss technical problems faced in cleanup, research needs, and ways to accelerate development of more cost-effective techniques. This paper provides some background on how this cooperative processmore » came to reality, what the Lasagna process is and how the cooperative arrangements and financing are structured.« less

CSTT Update: Fuel Quality Analyzer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brosha, Eric L.; Lujan, Roger W.; Mukundan, Rangachary

These are slides from a presentation. The following topics are covered: project background (scope and approach), developing the prototype (timeline), update on intellectual property, analyzer comparisons (improving humidification, stabilizing the baseline, applying clean-up strategy, impact of ionomer content and improving clean-up), proposed operating mode, considerations for testing in real-world conditions (Gen 1 analyzer electronics development, testing partner identified, field trial planning), summary, and future work.

Streamlined sample cleanup using combined dispersive solid-phase extraction and in-vial filtration for analysis of pesticides and environmental pollutants in shrimp

USDA-ARS?s Scientific Manuscript database

A new method of sample preparation was developed and is reported for the first time. The approach combines in-vial filtration with dispersive solid-phase extraction (d-SPE) in a fast and convenient cleanup of QuEChERS (quick, easy, cheap, effective, rugged, and safe) extracts. The method was appli...

Evaluation of a new carbon/zirconia-based sorbent for the cleanup of food extracts in multiclass analysis of pesticides and environmental contaminants

USDA-ARS?s Scientific Manuscript database

A novel carbon/zirconia based material, SupelTM QuE Verde (Verde), was evaluated in a filter-vial dispersive solid phase extraction (d-SPE) cleanup of QuEChERS extracts of pork, salmon, kale, and avocado for residual analysis of pesticides and environmental contaminants. Low pressure (LP) GC-MS/MS w...

Cleanup Verification Package for the 118-F-6 Burial Ground

DOE Office of Scientific and Technical Information (OSTI.GOV)

H. M. Sulloway

2008-10-02

This cleanup verification package documents completion of remedial action for the 118-F-6 Burial Ground located in the 100-FR-2 Operable Unit of the 100-F Area on the Hanford Site. The trenches received waste from the 100-F Experimental Animal Farm, including animal manure, animal carcasses, laboratory waste, plastic, cardboard, metal, and concrete debris as well as a railroad tank car.

A LC/UV/Vis method for determination of cyanocobalamin in multivitamin dietary supplements with on-line sample clean-up

USDA-ARS?s Scientific Manuscript database

A HPLC-UV method using a two-column strategy with a switching valve for on-line sample clean-up was developed for the determination of cyanocobalamin (CN-CBL-vitamin B12, in dietary supplements. The method uses two columns, an Agilent Zorbax C8 (150 mm x 4.6 mm, 5 um particle) reversed-phase column...

Ecological Indication, Bioaccumulation, and Phytoremediation as Tools for Environmental Quality Management

DTIC Science & Technology

2004-12-01

ECOLOGICAL INDICATION, BIOACCUMULATION, AND PHYTOREMEDIATION AS TOOLS FOR ENVIRONMENTAL QUALITY MANAGEMENT ELLY P. H. BEST1, HENRY E. TATEM1...subsequent transport to shoots, and degradation, or prevent contaminants from leaving the site in whatever form, such as leachate , runoff, trophic...transfer ( phytoremediation ). We use risk assessment to evaluate the toxicity and need for cleanup. Cleanup costs are expected to greatly exceed the cost

Development and Testing of Geo-Processing Models for the Automatic Generation of Remediation Plan and Navigation Data to Use in Industrial Disaster Remediation

NASA Astrophysics Data System (ADS)

Lucas, G.; Lénárt, C.; Solymosi, J.

2015-08-01

This paper introduces research done on the automatic preparation of remediation plans and navigation data for the precise guidance of heavy machinery in clean-up work after an industrial disaster. The input test data consists of a pollution extent shapefile derived from the processing of hyperspectral aerial survey data from the Kolontár red mud disaster. Three algorithms were developed and the respective scripts were written in Python. The first model aims at drawing a parcel clean-up plan. The model tests four different parcel orientations (0, 90, 45 and 135 degree) and keeps the plan where clean-up parcels are less numerous considering it is an optimal spatial configuration. The second model drifts the clean-up parcel of a work plan both vertically and horizontally following a grid pattern with sampling distance of a fifth of a parcel width and keep the most optimal drifted version; here also with the belief to reduce the final number of parcel features. The last model aims at drawing a navigation line in the middle of each clean-up parcel. The models work efficiently and achieve automatic optimized plan generation (parcels and navigation lines). Applying the first model we demonstrated that depending on the size and geometry of the features of the contaminated area layer, the number of clean-up parcels generated by the model varies in a range of 4% to 38% from plan to plan. Such a significant variation with the resulting feature numbers shows that the optimal orientation identification can result in saving work, time and money in remediation. The various tests demonstrated that the model gains efficiency when 1/ the individual features of contaminated area present a significant orientation with their geometry (features are long), 2/ the size of pollution extent features becomes closer to the size of the parcels (scale effect). The second model shows only 1% difference with the variation of feature number; so this last is less interesting for planning optimization applications. Last model rather simply fulfils the task it was designed for by drawing navigation lines.

An updated ciguatoxin extraction method and silica cleanup for use with HPLC-MS/MS for the analysis of P-CTX-1, PCTX-2 and P-CTX-3.

PubMed

Meyer, Lauren; Carter, Steve; Capper, Angela

2015-12-15

Ciguatera fish poisoning is a debilitating human neuro-intoxication caused by consumption of tropical marine organisms, contaminated with bioaccumulated ciguatoxins (CTXs). The growing number of cases coupled with the high toxicity of CTXs makes their reliable detection and quantification of paramount importance. Three commonly occurring ciguatoxins, P-CTX-1, 2 and 3 from five different ciguatoxic Spanish mackerel (Scomberomorus commerson), were used to assess the effectiveness of different extraction techniques: homogenization (high powered blending vs. ultrasonication); C-18 column sizes (500 mg vs. 900 mg); and a novel HILIC SPE cleanup. Despite minor differences, blending and sonication proved equally effective. Larger 900 mg columns offered a greater extraction efficiency, increasing detected P-CTX-1 by 37% (P < 0.001). The newly adapted cleanup was highly effective at reducing co-eluting phospholipids thereby reducing matrix effects and increasing detectable CTXs by HPLC-MS/MS. Silica cleanup extraction efficiencies were also compared between the highly effective and validated ciguatoxin rapid extraction method (CREM) and current best practice extraction method employed by Queensland Health (QH). Overall, the QH protocol proved more effective, especially when paired with the newly adapted cleanup, as this increased the amount of extracted P-CTX-1 by 46% (P < 0.01), P-CTX-2 by 10% and P-CTX-3 by 71% (P = 0.001). This study suggests the QH protocol utilizing a 900 mg C-18 column and newly adapted HILIC SPE cleanup was most effective at extracting P-CTX-1, -2, -3. Specifically P-CTX-1, the primary ciguatoxin congener of concern due to its extremely high potency and an ability to cause CFP at 0.1 μg/kg following consumption of carnivorous fish flesh. Despite being more time intensive (an additional 85 min per batch of 12 samples), this will be especially effective for assessing lower toxin burdens, which may be near the limit of detection. Copyright © 2015 Elsevier Ltd. All rights reserved.

Efficiency of different protocols for enamel clean-up after bracket debonding: an in vitro study

PubMed Central

Sigilião, Lara Carvalho Freitas; Marquezan, Mariana; Elias, Carlos Nelson; Ruellas, Antônio Carlos; Sant'Anna, Eduardo Franzotti

2015-01-01

Objective: This study aimed to assess the efficiency of six protocols for cleaning-up tooth enamel after bracket debonding. Methods: A total of 60 premolars were divided into six groups, according to the tools used for clean-up: 12-blade bur at low speed (G12L), 12-blade bur at high speed (G12H), 30-blade bur at low speed (G30L), DU10CO ORTHO polisher (GDU), Renew System (GR) and Diagloss polisher (GD). Mean roughness (Ra) and mean roughness depth (Rz) of enamel surface were analyzed with a profilometer. Paired t-test was used to assess Ra and Rz before and after enamel clean-up. ANOVA/Tukey tests were used for intergroup comparison. The duration of removal procedures was recorded. The association between time and variation in enamel roughness (∆Ra, ∆Rz) were evaluated by Pearson's correlation test. Enamel topography was assessed by scanning electron microscopy (SEM). Results: In Groups G12L and G12H, original enamel roughness did not change significantly. In Groups G30L, GDU, GR and GD, a smoother surface (p < 0.05) was found after clean-up. In Groups G30L and GD, the protocols used were more time-consuming than those used in the other groups. Negative and moderate correlation was observed between time and (∆Ra, ∆Rz); Ra and (∆Ra, ∆Rz); Rz (r = - 0.445, r = - 0.475, p < 0.01). Conclusion: All enamel clean-up protocols were efficient because they did not result in increased surface roughness. The longer the time spent performing the protocol, the lower the surface roughness. PMID:26560825

Chronic Lymphocytic Leukemia in Chornobyl Cleanup Workers.

PubMed

Bazyka, Dimitry; Gudzenko, Natalya; Dyagil, Iryna; Goroh, Eugeny; Polyschuk, Oksana; Trotsuk, Natalya; Babkina, Nataly; Romanenko, Anatoly

2016-08-01

This paper describes the chronic lymphocytic leukemia (CLL) incidence in a cohort of 110,645 (enlarged later to 152,520) male Ukrainian cleanup workers of the Chornobyl (Chernobyl) accident who were exposed to a range of radiation doses over the 1986-1990 time period. The standardized incidence rates are presented for a 27-y period after the exposure. For 2007-2012 period, the authors have identified the incident CLL cases in an enlarged cohort of 152,520 persons by linkage of the cohort file with the Ukrainian National Cancer Registry (NCRU). CLL data for the previous period (1987-2006) were identified in a frame of the Ukrainian-American leukemia study in the original cohort of 110,645 male clean-up workers. A significant CLL incidence excess was shown for the entire study period 1987-2012, with more prominent levels for the earliest years (1987-1996) when the standardized incidence rate (SIR) value was estimated to be 3.61 with 95% confidence interval from 2.32 to 4.91. In 2007-2012, the CLL incidence decreased substantially but still exceeded the national level although not significantly. In parallel, the several studies were performed at the National Research Center for Radiation Medicine (NRCRM) to explore if any clinical and cytogenetic features of CLL existed in the clean-up workers. The clinical study included 80 exposed and 70 unexposed CLL cases. Among the major clinical differences of the CLL course in the clean-up workers were a shorter period of white blood cells (WBC) doubling (10.7 vs. 18.0; p<0.001), frequent infectious episodes, lymphoadenopathy and hepatosplenomegaly (37 vs. 16), higher expression for CD38, and lower expression for ZAP-70 antigen.

Measurement of fumonisins in corn with a fiber optic fluoroimmunosensor

NASA Astrophysics Data System (ADS)

Thompson, Vicki S.; Maragos, Chris M.

1997-05-01

A fiber-optic immunosensor was used to determine concentrations of the mycotoxin fumonisin B1(FB1) in both spiked and naturally contaminated corn samples. Samples were extracted with a mixture of methanol/water. Two methods were used to prepare the methanolic corn extracts before introduction to the immunosensor: (1) simple dilution of the methanolic corn extract; or (2) affinity column cleanup. The sensor displayed an IC50 of 70 ng FB1/mL when toxin was introduced in phosphate buffered saline. Simple dilution of methanolic corn extracts yielded an assay with an IC50 equivalent to 25 (mu) gFB1/g corn and a limit of detection of 3.2 (mu) g/g corn, while affinity cleanup of corn extracts yielded an assay with an IC50 of 5 (mu) gFB1/g corn and a limit of detection of 0.4 (mu) gFB1/g corn. The difference in sensitivity between the two cleanup techniques was due to concentration of fumonisins obtained from the affinity cleanup procedure. Naturally contaminated corn samples were also analyzed after either simple dilution or affinity column cleanup. For comparison the naturally contaminated corn samples were analyzed with an HPLC method after isolation of the fumonisins with strong anion exchange (SAX) solid phase extraction cartridges. The SAX/HPLC method and the immunosensor method agreed well except when large amounts of other fumonisins (i.e. fumonisin B2) were present. This was due in part to the cross-reactivity of the monoclonal antibody with other fumonisins. The immunosensor has the potential to screen individual corn samples for fumonisins within six minutes, and is among the fastest of the currently available FB1 detection methods.

Determination of vitamins D2 and D3 in selected food matrices by online high-performance liquid chromatography-gas chromatography-mass spectrometry (HPLC-GC-MS).

PubMed

Nestola, Marco; Thellmann, Andrea

2015-01-01

An online normal-phase liquid chromatography-gas chromatography-mass spectrometry (HPLC-GC-MS) method was developed for the determination of vitamins D2 and D3 in selected food matrices. Transfer of the sample from HPLC to GC was realized by large volume on-column injection; detection was performed with a time-of-flight mass spectrometer (TOF-MS). Typical GC problems in the determination of vitamin D such as sample degradation or sensitivity issues, previously reported in the literature, were not observed. Determination of total vitamin D content was done by quantitation of its pyro isomer based on an isotopically labelled internal standard (ISTD). Extracted ion traces of analyte and ISTD showed cross-contribution, but non-linearity of the calibration curve was not determined inside the chosen calibration range by selection of appropriate quantifier ions. Absolute limits of detection (LOD) and quantitation (LOQ) for vitamins D2 and D3 were calculated as approximately 50 and 150 pg, respectively. Repeatability with internal standard correction was below 2 %. Good agreement between quantitative results of an established high-performance liquid chromatography with UV detection (HPLC-UV) method and HPLC-GC-MS was found. Sterol-enriched margarine was subjected to HPLC-GC-MS and HPLC-MS/MS for comparison, because HPLC-UV showed strong matrix interferences. HPLC-GC-MS produced comparable results with less manual sample cleanup. In summary, online hyphenation of HPLC and GC allowed a minimization in manual sample preparation with an increase of sample throughput.

Campaigning for bioremediation. [Pencillium citrinum, Acremonium falciforme, Alternaria alternata, Ulocladium tuberculatum, Fusarium sp

DOE Office of Scientific and Technical Information (OSTI.GOV)

Frankenberger, W.T. Jr.; Karlson, U.

Coaxing indigenous soil microorganisms to munch on toxics may prove the only permanent, cost-effective, and safe technique for cleanup of noxious pollutants like selenium, a widespread environmental contaminant in the western United States. The process from innovation in the laboratory to application in the field has taken more than bioremediation know-how. Media exposure and political and bureaucratic support have been necessary partners with sound science to bring Se cleanup technology as far along as it is today. Before describing their patented Se bioremediation process and chronicling the events that led to environmental cleanup in California, the authors give some backgroundmore » about Se, its geochemistry, and its biochemical and environmental behavior. The bioremediation process optimizes field conditions that allow soil fungi to methylate toxic Se compound to dimethylselenide, a non-toxic gas.« less

State of the states on brownfields programs for cleanup and reuse of contaminated sites

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

Brownfields consist of land and/or buildings that are abandoned or underutilized where expansion or redevelopment is complicated, in part, because of the threat of known or potential contamination. Federal and state laws governing the treatment of these sites may require remediation (cleanup) of property before redevelopment and can contribute to uncertain liability for property owners or users. Congress, in considering the reauthorization of the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA), commonly known as Superfund, is interested in the issue of brownfields and in their potential return to productive use. As a result, the House Subcommittee on Commerce, Trademore » and Hazardous Materials of the Committee on Commerce requested the Office of Technology Assessment (OTA) to prepare a background paper on issues surrounding cleanup and redevelopment of brownfields.« less

Environmental liability protection and other advantages of voluntary cleanup programs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bost, R.C.; Linton, K.E.

Historically, regulatory agencies have required that contaminated sites be returned to pristine conditions, often at very high costs. Fear of these enormous environmental liabilities has resulted in abandonment of many industrial and commercial properties, referred to as brownfields. The development of Risk-Based Corrective Action programs has provided a means for regulatory agencies to evaluate contaminated sites based on risk to human health and the environment, resulting in more reasonable remedial measures and costs. Governmental bodies have created a more flexible means of addressing contaminated sites using Risk-Based Corrective Action and other incentives to encourage the redevelopment of sites through Voluntarymore » Cleanup Programs. This study describes the development of Voluntary Cleanup Programs, and the successful implementation of Risk-Based Corrective Action with a focus on the states of Texas, Louisiana, and Oklahoma.« less

Groundwater cleanup demonstrations at Complex 34, CCAS

NASA Technical Reports Server (NTRS)

2000-01-01

At Launch Complex 34, Greg Beyke, with Current Environmental Solutions, talks to representatives from environmental and federal agencies about the environmental research project that involves the Department of Defense, Environmental Protection Agency, Department of Energy and NASA in a groundwater cleanup effort. Concentrations of trichloroethylene solvent have been identified in the soil at the complex as a result of cleaning methods for rocket parts during the Apollo Program, which used the complex, in the 60s. The group formed the Interagency NDAPL Consortium (IDC) to study three contamination cleanup technologies: Six Phase Soil Heating, Steam Injection and In Situ Oxidation with Potassium Permanganate. All three methods may offer a way to remove the contaminants in months instead of decades. KSC hosted a two-day conference that presented information and demonstrations of the three technologies being tested at the site.

Groundwater cleanup demonstrations at Complex 34, CCAS

NASA Technical Reports Server (NTRS)

2000-01-01

At Launch Complex 34, the Six-Phase Soil Heating site that is involved in a groundwater cleanup project can be seen. The project involves the Department of Defense, Environmental Protection Agency, Department of Energy and NASA. Concentrations of trichloroethylene solvent have been identified in the soil at the complex as a result of cleaning methods for rocket parts during the Apollo Program, which used the complex, in the 60s. The group formed the Interagency NDAPL Consortium (IDC) to study three contamination cleanup technologies: Six-Phase Soil Heating, Steam Injection and In Situ Oxidation with Potassium Permanganate. All three methods may offer a way to remove the contaminants in months instead of decades. In the background is the block house for the complex. KSC hosted a two-day conference that presented information and demonstrations of the three technologies being tested at the site.

Groundwater cleanup demonstrations at Complex 34, CCAS

NASA Technical Reports Server (NTRS)

2000-01-01

At Launch Complex 34, representatives from environmental and Federal agencies head for the block house during presentations about the environmental research project that involves the Department of Defense, Environmental Protection Agency, Department of Energy and NASA in a groundwater cleanup effort. Concentrations of trichloroethylene solvent have been identified in the soil at the complex as a result of cleaning methods for rocket parts during the Apollo Program, which used the complex, in the 60s. The group formed the Interagency NDAPL Consortium (IDC) to study three contamination cleanup technologies: Six Phase Soil Heating, Steam Injection and In Situ Oxidation with Potassium Permanganate. All three methods may offer a way to remove the contaminants in months instead of decades. KSC hosted a two-day conference that presented information and demonstrations of the three technologies being tested at the site.

Trouble Shooting Guide: Index to Problems and Solutions. Successful Schools: Guidebooks to Effective Educational Leadership. Volume 10.

ERIC Educational Resources Information Center

English, Fenwick W., Ed.

An index to the problems and solutions discussed in the the first 9 volumes of the 10-volume series, Successful Schools: Guidebooks to Effective Educational Leadership, is provided in this handbook. This "troubleshooting guide" lists topics in alphabetical order, describes the issue, and lists the corresponding volume and page number. (LMI)

Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases

DOEpatents

Ayala, Raul E.

1993-01-01

This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

Phase Aberrations And Beam Cleanup Techniques In Carbon-Dioxide Laser Fusion Systems

NASA Astrophysics Data System (ADS)

Viswanathan, V. K.

1981-12-01

This paper describes the various carbon dioxide laser fusion systems at Los Alamos from the point of view of an optical designer. The types of phase aberrations present in these systems, as well as the beam cleanup techniques that can be used to improve the beam optical quality, are discussed. As this is a review article, some previously published results are also used where relevant.

State Summary of Soil and Groundwater Cleanup Standards for Hydrocarbons

DTIC Science & Technology

1993-11-15

821096-01 November 15, 1993 19970425 057 !DISTfRIBUTI STýA-TEM,_ Approved for public release; Distribution Unlbfited Product - Paranmeter/ Lab Test ...Env-mmenal Mantagemen, 20-270-5613 Product Parameter/ Lab Test Protocol Detection Notification Action Clean-up Level Constituent & Number Level Level...Envi-mnentai Managament, 205-270-.5613 Su m r of Alsk Clanu Sadr s fo Hyrcro Cotmiae Groundwater Product- - Parameter/ Lab Test Protocol ’Detection

The mating dance in cleanup recoveries: How to court responsible parties and in what court to do it

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meyer, G.A.

1995-12-31

This article discusses the legalities which pertain specifically to hazardous waste cleanup. Topics of discussion include the following: threshold decisions: litigate or negotiate; forum issues--Federal or state court; claims in state court; and different types of damages and recovery. CERCLA is not the only grounds for recovery in environmental contamination cases. Common law and RCRA are also attractive.

National priorities list sites: North Carolina, 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1995-05-01

The fact sheets describe hazardous waste sites on the NPL and their locations, as well as the conditions leading to their listing (Site Description). The summaries list the types of contaminants that have been discovered and related threats to public and ecological health (Threats and Contaminants). Cleanup Approach presents an overview of the cleanup activities completed, underway, or planned. The fact sheets are arranged in alphabetical order by site name.

Cleanup Verification Package for the 618-8 Burial Ground

DOE Office of Scientific and Technical Information (OSTI.GOV)

M. J. Appel

2006-08-10

This cleanup verification package documents completion of remedial action for the 618-8 Burial Ground, also referred to as the Solid Waste Burial Ground No. 8, 318-8, and the Early Solid Waste Burial Ground. During its period of operation, the 618-8 site is speculated to have been used to bury uranium-contaminated waste derived from fuel manufacturing, and construction debris from the remodeling of the 313 Building.

Influence of orthodontic adhesives and clean-up procedures on the stain susceptibility of enamel after debonding.

PubMed

Joo, Hyun-Jin; Lee, Yong-Keun; Lee, Dong-Yul; Kim, Yae-Jin; Lim, Yong-Kyu

2011-03-01

To determine the influence of the type of orthodontic adhesive system, such as conventional acid-etching (CE) and self-etching primers (SEPs), on the stain susceptibility of enamel surface after debonding. Effects of clean-up procedures on the enamel surface were also determined. Two types and four brands of adhesive systems were investigated using 135 human premolars. Unbonded teeth were used as controls. Three-dimensional scanning of the enamel surface was performed before bracket bonding, after debonding, and after clean-up procedures. The color of each tooth was measured before bracket bonding and again after debonding and clean-up procedures. This was followed by methylene blue staining. The stain susceptibility of the enamel surface was measured after finishing only (F-condition) and after finishing/polishing (FP-condition). After debonding, the amount of residual adhesive resins in CE materials was greater than that in SEP materials. For the F-condition, staining color change in SEP materials was significantly higher than that in CE materials. For the FP-condition, staining color change in both CE and SEP materials was not different from those of the control. The SEP system would show less stain susceptibility if the thin residual adhesive resin layer after debonding is removed by polishing.

Brownfield site development -- The Ontario context

DOE Office of Scientific and Technical Information (OSTI.GOV)

Phillips, D.B.

The provincial government of Ontario recently promulgated new guidelines to deal with contamination on sites. One of the purposes of the guideline was to bolster development of contaminated sites by clarifying the regulatory process for redeveloping a contaminated site and to provide several clean-up options based on newer scientific information. These clean-up options include stratified clean-ups and site specific risk based criteria. The applications of the previous guideline were at times cumbersome for industries and land developers which may have impeded development of the Brownfield. This paper compares the changes between the old and the new regulatory clean-up guidelines andmore » presents the differences in approach. This paper also presents the results from interviews with several industries and property developers and assesses their view on the regulatory change as well as their desire to develop Brownfields in Ontario. This information determines if the change in regulatory process has really encouraged development. Results from the interviews with proponents indicated that the new guidelines are a much better approach but still contain barriers such as liability issues. Furthermore, the regulatory approval process has been transferred from the provincial government to the local governments. As a result the local governments are applying the guidelines differently across the province.« less

Novel fracture technology proves marginal Viking prospect economic, part II: Well clean-up, flowback and testing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Haidar, S.; Rylance, M.; Tybero, G.

1996-12-31

Having completed both fracture treatments as discussed in a companion paper, this paper continues on to describe the post fracture shut-in, clean-up and well testing operations that took place on the Viking Wx exploration well 49/17-12. These operations involved the removal of Resin Coated Proppant (RCP) from the wellbore, via Coiled Tubing (CT), through the use of a specially designed jetting nozzle. The RCP pack stability at a concentration of 3.0 lb/ft{sup 2} (as per planned design) had already been tested in a flowback cell. The use of a Surface Read-Out (SRO) gauge, combined with gas, water and proppant flowmore » rates as well as the viscosity of fracturing fluids returns, enabled real time calculation of the drag forces, on the proppant pack, during clean-up. The flow rate, in the field, was controlled such that the calculated drag forces remained below those observed in the laboratory. Following the clean-up a flow and build-up test was conducted, to evaluate the fracture half length and fracture conductivity, from which a Pseudo-radial skin was calculated. The Non-Darcy effects in the fracture were also evaluated, and finally the short term and long term well deliverabilities were assessed.« less

The Estonian study of Chernobyl cleanup workers: II. Incidence of cancer and mortality

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rahu, M.; Tekkel, M.; Veidebaum, T.

A cohort of 4,472 men from Estonia who had participated in the cleanup activities in the Chernobyl area sometime between 1986 and 1991 and were followed through 1993 was analyzed with respect to the incidence of cancer and mortality. Incidence and mortality in the cleanup workers were assessed relative to national rates. No increases were found in all cancers (25 incident cases compared to 26.5 expected) or in leukemia (no cases observed, 1.0 expected). Incidence did not differ statistically significantly from expectation for any individual cancer site or type, though lung cancer and non-Hodgkin`s lymphoma both occurred slightly more oftenmore » than expected. A total of 144 deaths were observed [standardized mortality ratio (SMR) = 0.98; 95% confidence interval (CI) = 0.82-1.14] during an average of 6.5 years of follow-up. Twenty-eight deaths (19.4%) were suicides (SMR = 1.52; 95% CI = 1.01-2.19). Exposure to ionizing radiation while at Chernobyl has not caused a detectable increase in the incidence of cancer among cleanup workers from Estonia. At least for the short follow-up period, diseases directly attributable to radiation appear to be of relatively minor importance when compared with the substantial excess of deaths due to suicide. 28 refs., 3 tabs.« less

Citizen Contributions to the Closure of High-Level Waste (HLW) Tanks 18 and 19 at the Department of Energy's (DOE) Savannah River Site (SRS) - 13448

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lawless, W.F.

2013-07-01

Citizen involvement in DOE's decision-making for the environmental cleanup from DOE's management of its nuclear wastes across the DOE complex has had a positive effect on the cleanup of its SRS site, characterized by an acceleration of cleanup not only for the Transuranic wastes at SRS, but also for DOE's first two closures of HLW tanks, both of which occurred at SRS. The Citizens around SRS had pushed successfully for the closures of Tanks 17 and 20 in 1997, becoming the first closures of HLW tanks under regulatory guidance in the USA. However, since then, HLW tank closures ceased duemore » to a lawsuit, the application of new tank clean-up technology, interagency squabbling between DOE and NRC over tank closure criteria, and finally and almost fatally, from budget pressures. Despite an agreement with its regulators for the closure of Tanks 18 and 19 by the end of calendar year 2012, the outlook in Fall 2011 to close these two tanks had dimmed. It was at this point that the citizens around SRS became reengaged with tank closures, helping DOE to reach its agreed upon milestone. (authors)« less

Immunoaffinity column as clean-up tool for determination of trace amounts of microcystins in tap water.

PubMed

Tsutsumi, T; Nagata, S; Hasegawa, A; Ueno, Y

2000-07-01

Trace amounts of microcystins (MCs) in drinking water should be monitored because of their potential hazard for human health as an environmental tumor promoter. We describe here a new clean-up tool with immunoaffinity column (IAC) for determination of trace amounts of MCs (from pg to microg/litre) in tap water. The water samples were concentrated with IAC clean-up and MCs levels were determined by HPLC with UV detection or enzyme-linked immunosorbent assay (ELISA). In the combination with HPLC analysis, mean recovery of microcystin-LR (MCLR),-RR and-YR spiked to tap water were 91.8%, 77.3% and 86.4%, respectively, in the range 2.5-100 microg/litre. The chromatogram of MCs-spiked tap water sample cleaned up with IAC showed effective elimination of the impurities compared to that with octadecyl silanized cartridge, which had been cleaned up with a conventional method. Also, in the combination with highly sensitive ELISA, mean recovery of MCLR spiked to tap water was 80% in the range 0.1-1000 ng/litre. The combined methods developed here can detect pg to microg/litre of MCs in tap water. The overall results indicated that IAC will be suitable as a clean-up tool for trace amounts of MCs in tap water.

Microstructures of superhydrophobic plant leaves - inspiration for efficient oil spill cleanup materials.

PubMed

Zeiger, Claudia; Rodrigues da Silva, Isabelle C; Mail, Matthias; Kavalenka, Maryna N; Barthlott, Wilhelm; Hölscher, Hendrik

2016-08-16

The cleanup of accidental oil spills in water is an enormous challenge; conventional oil sorbents absorb large amounts of water in addition to oil and other cleanup methods can cause secondary pollution. In contrast, fresh leaves of the aquatic ferns Salvinia are superhydrophobic and superoleophilic, and can selectively absorb oil while repelling water. These selective wetting properties are optimal for natural oil absorbent applications and bioinspired oil sorbent materials. In this paper we quantify the oil absorption capacity of four Salvinia species with different surface structures, water lettuce (Pistia stratiotes) and Lotus leaves (Nelumbo nucifera), and compare their absorption capacity to artificial oil sorbents. Interestingly, the oil absorption capacities of Salvinia molesta and Pistia stratiotes leaves are comparable to artificial oil sorbents. Therefore, these pantropical invasive plants, often considered pests, qualify as environmentally friendly materials for oil spill cleanup. Furthermore, we investigated the influence of oil density and viscosity on the oil absorption, and examine how the presence and morphology of trichomes affect the amount of oil absorbed by their surfaces. Specifically, the influence of hair length and shape is analyzed by comparing different hair types ranging from single trichomes of Salvinia cucullata to complex eggbeater-shaped trichomes of Salvinia molesta to establish a basis for improving artificial bioinspired oil absorbents.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stewart, Charles W.

Radioactive waste tank SY-101 is one of 177 big underground tanks that store waste from decades of plutonium production at the Hanford Nuclear Reservation in central Washington State. The chemical reactions and radioactivity in all the tanks make bubbles of flammable gas, mainly hydrogen along with a little methane and ammonia. But SY-101 was the most potent gas producer of all. Every few months the gas built up in the million gallons of extra-thick slurry until it suddenly came up in great rushing ''burps''. A few of the tank's larger burps let off enough gas to make the air spacemore » at the top of the tank flammable for a few hours. This flammable gas hazard became a dominating force in DOE nuclear waste management politics in the last two decades of the 20th century. It demanded the toil of scientists, managers, and officials from the time it was filled in 1980, until it was finally declared safe in January 2001. The tank seemed almost a personality--acting with violence and apparent malice, hiding information about itself, deceiving us with false indications, and sometimes lulling us into complacency only to attack in a new way. From 1990 through 1993, SY-101's flammable gas troubles were acknowledged as the highest priority safety issue in the entire DOE complex. Uncontrolled crust growth demanded another high-priority remedial effort from 1998 through April 2000. The direct cost of the bubbles, toils, and troubles was high. Overall, the price of dealing with the real and imagined hazards in SY-101 may have reached $250 million. The indirect cost was also high. Spending all this money fighting SY-101?s safety issues only stirred radioactive waste up and moved it around, but accomplished no cleanup whatever. Worse yet, the flammable gas problem spawned suspicions of a much wider danger that impeded and complicated cleanup in other 176 waste tanks for a decade. The real cleanup job has yet to be done. The SY-101 story is really about the collective experience of people, from pervasive misconception to grand insight, near miss to sweeping success, meddling interference to close teamwork, all on an uncommonly large scale. It was a necessary catharsis that transformed the entire Hanford culture from a closed defense production operation to an open environmental cleanup project. Its tight project discipline and close teamwork became the Hanford standard. The final remediation of SY-101 placed second in an international ''project of the year'' competition. Many consider SY-101 work the peak of their careers and measure all other experience by it. SY-101 defines some of the worst and the best of Hanford history. This book attempts to narrate and explain the whole vast story.« less

Comparison between Hydrogen, Methane and Ethylene Fuels in a 3-D Scramjet at Mach 8

DTIC Science & Technology

2016-06-24

characteristics in air. The disadvantage of hydrogen is its low density, which is a particular problem for small vehicles with significant internal...characteristics in air. The disadvantage of hydrogen is its low density, which is a particular problem for small vehicles with significant internal volume...The low energy per unit volume of gaseous hydrogen, however, is a significant problem for small vehicles with internal volume constraints, in addition

Cosmological measure with volume averaging and the vacuum energy problem

NASA Astrophysics Data System (ADS)

Astashenok, Artyom V.; del Popolo, Antonino

2012-04-01

In this paper, we give a possible solution to the cosmological constant problem. It is shown that the traditional approach, based on volume weighting of probabilities, leads to an incoherent conclusion: the probability that a randomly chosen observer measures Λ = 0 is exactly equal to 1. Using an alternative, volume averaging measure, instead of volume weighting can explain why the cosmological constant is non-zero.

Pushing the polymer envelope

NASA Astrophysics Data System (ADS)

Tolley, Paul R.

2005-09-01

The pressure to "push the polymer envelope" is clear, given the exploding range of demanding applications with optical components. There are two keys to success: 1. Expanded range of polymers with suitable optical properties. 2. Sophisticated manufacturing process options with an overall system perspective: -Tolerances and costs established relative to need (proof-of-concept, prototype, low to high volume production). -Designed to integrate into an assembly that meets all environmental constraints, not just size and weight, which are natural polymer advantages. (Withstanding extreme temperatures and chemical exposure is often critical, as are easy clean-up and general resistance to surface damage.) -Highly repeatable. The thesis of this paper is that systematically innovating processes we already understand on materials we already know can deliver big returns. To illustrate, we introduce HRDT1, High Refraction Diamond Turning, a patent-pending processing option to significantly reduce total costs for high index, high thermal applications.

A design study for a medium-scale field demonstration of the viscous barrier technology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moridis, G.; Yen, P.; Persoff, P.

1996-09-01

This report is the design study for a medium-scale field demonstration of Lawrence Berkeley National Laboratory`s new subsurface containment technology for waste isolation using a new generation of barrier liquids. The test site is located in central California in a quarry owned by the Los Banos Gravel Company in Los Banos, California, in heterogeneous unsaturated deposits of sand, silt, and -ravel typical of many of the and DOE cleanup sites and particularly analogous to the Hanford site. The coals of the field demonstration are (a) to demonstrate the ability to create a continuous subsurface barrier isolating a medium-scale volume (30more » ft long by 30 ft wide by 20 ft deep, i.e. 1/10th to 1/8th the size of a buried tank at the Hanford Reservation) in the subsurface, and (b) to demonstrate the continuity, performance, and integrity of the barrier.« less

Remedial investigation report on Waste Area Grouping 5 at Oak Ridge National Laboratory, Oak Ridge, Tennessee. Volume 1: Technical summary

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1995-09-01

A remedial investigation (RI) was performed to support environmental restoration activities for Waste Area Grouping (WAG) 5 at the Oak Ridge National Laboratory (ORNL) in Oak Ridge, Tennessee. The WAG 5 RI made use of the observational approach, which concentrates on collecting only information needed to assess site risks and support future cleanup work. This information was interpreted and is presented using the framework of the site conceptual model, which relates contaminant sources and release mechanisms to migration pathways and exposure points that are keyed to current and future environmental risks for both human and ecological receptors. The site conceptualmore » model forms the basis of the WAG 5 remedial action strategy and remedial action objectives. The RI provided the data necessary to verify this model and allows recommendations to be made to accomplish those objectives.« less

Optimal groundwater remediation design of pump and treat systems via a simulation-optimization approach and firefly algorithm

NASA Astrophysics Data System (ADS)

Javad Kazemzadeh-Parsi, Mohammad; Daneshmand, Farhang; Ahmadfard, Mohammad Amin; Adamowski, Jan; Martel, Richard

2015-01-01

In the present study, an optimization approach based on the firefly algorithm (FA) is combined with a finite element simulation method (FEM) to determine the optimum design of pump and treat remediation systems. Three multi-objective functions in which pumping rate and clean-up time are design variables are considered and the proposed FA-FEM model is used to minimize operating costs, total pumping volumes and total pumping rates in three scenarios while meeting water quality requirements. The groundwater lift and contaminant concentration are also minimized through the optimization process. The obtained results show the applicability of the FA in conjunction with the FEM for the optimal design of groundwater remediation systems. The performance of the FA is also compared with the genetic algorithm (GA) and the FA is found to have a better convergence rate than the GA.

Johnston Atoll Plutonium Cleanup Project. Contract bridge report. Technical report, 1 June-5 August 1993

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hellier, C.L.; Doane, R.W.

1995-04-01

This report continues the documentation of the operation of TMA/Eberline`s Segmented Gate System technology for removing mixed plutonium and americium contamination at DNA`s Johnston Atoll site. Contaminated feed is conveyed under arrays of radiation detectors coupled with sophisticated computer software developed by Eberline Instrument Corporation. Segmented gates (chutes) on pneumatically-driven pistons move forward when contamination is detected to remove only the contaminated portion from the main flow of feed material. Only about one pint of contaminant is removed during each diversion event. At the JA site, a 98% volume reduction has been achieved, with the remediated soil cleaned to DNA`smore » criteria for release for unrestricted use of 500 Bq/kg total transuranic alpha contamination and no hot particles of greater than 5000 Becquerrels. The low level waste concentrate is expected to be packaged for shipment to an approved defense waste disposal site.« less

A rapid high-performance liquid-chromatographic method for simultaneously determining the concentrations of TFM and Bayer 73 in water during lampricide treatments

USGS Publications Warehouse

Dawson, V.K.

1982-01-01

The high-performance liquid-chromatography (HPLC) procedure requires only minutes per sample, is specific, and is relatively sensitive (limit of detection 18 disposable cartridge. The cartridge adsorbs and retains both the lampricides and the internal standard. The quantitative elution of the three chemicals from the cartridge with a small volume of methanol effectively concentrates the sample and provides sample cleanup. The methanol extract is then analyzed directly by HPLC on an MCH 10 reverse phase column by using a methanol:0.01 mol/L acetate buffer (87:13, v:v) as the mobile phase at 2 mL/min and detected by ultraviolet spectrophotometry at 330 (or 254) nm. A microprocessor data system further facilitates the procedure by quantifying off-scale peaks and yielding results directly in units of concentration (mg/L).

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

This volume contains the interim change notice for sample preparation methods. Covered are: acid digestion for metals analysis, fusion of Hanford tank waste solids, water leach of sludges/soils/other solids, extraction procedure toxicity (simulate leach in landfill), sample preparation for gamma spectroscopy, acid digestion for radiochemical analysis, leach preparation of solids for free cyanide analysis, aqueous leach of solids for anion analysis, microwave digestion of glasses and slurries for ICP/MS, toxicity characteristic leaching extraction for inorganics, leach/dissolution of activated metal for radiochemical analysis, extraction of single-shell tank (SST) samples for semi-VOC analysis, preparation and cleanup of hydrocarbon- containing samples for VOCmore » and semi-VOC analysis, receiving of waste tank samples in onsite transfer cask, receipt and inspection of SST samples, receipt and extrusion of core samples at 325A shielded facility, cleaning and shipping of waste tank samplers, homogenization of solutions/slurries/sludges, and test sample preparation for bioassay quality control program.« less

Site Remediation Technology InfoBase: A Guide to Federal Programs, Information Resources, and Publications on Contaminated Site Cleanup Technologies. First Edition

NASA Technical Reports Server (NTRS)

1998-01-01

Table of Contents: Federal Cleanup Programs; Federal Site Remediation Technology Development Assistance Programs; Federal Site Remediation Technology Development Electronic Data Bases; Federal Electronic Resources for Site Remediation Technology Information; Other Electronic Resources for Site Remediation Technology Information; Other Electronic Resources for Site Remediation Technology Information; Selected Bibliography: Federal Publication on Alternative and Innovative Site Remediation; and Appendix: Technology Program Contacts.

Regression Analysis as a Cost Estimation Model for Unexploded Ordnance Cleanup at Former Military Installations

DTIC Science & Technology

2002-06-01

fits our actual data . To determine the goodness of fit, statisticians typically use the following four measures: R2 Statistic. The R2 statistic...reviewing instruction, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of...mathematical model is developed to better estimate cleanup costs using historical cost data that could be used by the Defense Department prior to placing

Air Force Groundwater Contamination Cleanup: An Evaluation of the Pump- and-Treat Method.

DTIC Science & Technology

1988-09-01

Other contaminants commonly detected at Air Force installations are benzene, mercury , pesticides, polychlori- nated biphenyls (PCBs), and Toxaphene...the air base experienced a 3000 gallon fuel (JP-4) spill at Fire Training Area 5 and contracted the DETOX company to conduct cleanup operations. After...several months of pumping, DETOX estimated that only 300 gallons of the fuel had been recovered. Wright-Patterson Air Force Base, unsatisfied with

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

2016 accomplishments and primary areas of focus for the Department of Energy's (DOE's) Office of Environmental Management and EM sites are presented. For DOE EM, these include Focusing on the Field, Teaming with Cleanup Partners, Developing New Technology, and Maximizing Cleanup Dollars. Major 2016 achievements are highlighted for EM, Richland Operations Office, Office of River Protection, Savannah River Site, Oak Ridge, Idaho, Waste Isolation Pilot Plant, Los Alamos, Portsmouth, Paducah, West Valley Demonstration Project, and the Nevada National Security Site,

Characterization and reclamation assessment for the Central Shops Diesel Storage Facility, Savannah River Site, Aiken, South Carolina

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fliermans, C.B.; Hazen, T.C.; Bledsoe, H.

1993-10-01

The contamination of subsurface terrestrial environments by organic contaminants is a global phenomenon. The remediation of such environments requires innovative assessment techniques and strategies for successful clean-ups. Central Shops Diesel Storage Facility at Savannah River Site was characterized to determine the extent of subsurface diesel fuel contamination using innovative approaches and effective bioremediation techniques for clean-up of the contaminant plume have been established.

EPA Superfund Records of Decision (RODs) for Region 7: Iowa, Kansas, Missouri, and Nebraska

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1999-03-01

The purpose of an EPA Record of Decision is to evaluate a Superfund Site with the goal of protecting human health and the environment while ensuring consistency of evaluations in contamination and clean-up of all Superfund sites. The ROD is a public document signed by the appropriate Regional Administrator which details cleanup, cost estimates, and EPA`s responsiveness to the public comment summary. The ROD may be litigated, thus it is important to have all current updates to the signed EPA decision. The ROD may be amended with an Amendment or supplemented by an Explanation of Significant Difference (ESD). A Superfundmore » Site may have multiple RODs, as each Superfund Site may be further redefined as Operable Units and Events. This allows EPA`s decisions to evolve as new technology presents itself. Average clean-up time for a Superfund Site can range from 12 to 100 years.« less

EPA Superfund Records of Decision (RODs) for Region 10: Alaska, Idaho, Oregon, and Washington

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1999-03-01

The purpose of an EPA Record of Decision is to evaluate a Superfund Site with the goal of protecting human health and the environment while ensuring consistency of evaluations in contamination and clean-up of all Superfund sites. The ROD is a public document signed by the appropriate Regional Administrator which details cleanup, cost estimates, and EPA`s responsiveness to the public comment summary. The ROD may be litigated, thus it is important to have all current updates to the signed EPA decision. The ROD may be amended with an Amendment or supplemented by an Explanation of Significant Difference (ESD). A Superfundmore » Site may have multiple RODs, as each Superfund Site may be further redefined as Operable Units and Events. This allows EPA`s decisions to evolve as new technology presents itself. Average clean-up time for a Superfund Site can range from 12 to 100 years.« less

Groundwater cleanup demonstrations at Complex 34, CCAS

NASA Technical Reports Server (NTRS)

2000-01-01

At Launch Complex 34, Cape Canaveral Air Station, several studies are under way for groundwater cleanup of trichloroethylene at the site. Shown here is monitoring equipment for one of the methods, potassium permanganate oxidation. Concentrations of trichloroethylene solvent have been identified in the soil at the complex as a result of cleaning methods for rocket parts during the Apollo Program in the 60s. The environmental research project involves the Department of Defense, Environmental Protection Agency, Department of Energy and NASA, who formed the Interagency NDAPL Consortium (IDC), to study three contamination cleanup technologies: Six Phase Soil Heating, Steam Injection and In Situ Oxidation with Potassium Permanganate. All three methods may offer a way to remove the contaminants in months instead of decades. KSC hosted a two-day conference that presented information and demonstrations of the three technologies for representatives from environmental and federal agencies.

DNA typing for personal identification of urine after long-term preservation for testing in doping control.

PubMed

Aoki, Kimiko; Tanaka, Hiroyuki; Ueki, Makoto

2017-08-01

When the tampering of a urine sample is suspected in doping control, personal identification of the sample needs to be determined by short tandem repeat (STR) analysis using DNA. We established a method for extracting DNA from urine samples stored at -20 °C without using any additives or procedures, which is consistent with how samples are required to be managed for doping control. The method, using the Puregene® Blood Core kit followed by NucleoSpin® gDNA Clean-up or NucleoSpin® gDNA Clean-up XS kit, does not need any special instrument and can provide a purified extract with high-quality DNA from up to 40 mL of urine suitable for STR analysis using an AmpFlSTR® Identifiler® PCR amplification kit. Storing urine at -20 °C is detrimental to the stability of DNA. The DNA concentration of preserved urine could not be predicted by specific gravity or creatinine level at the time of urine collection. The DNA concentration of a purified extract (10 μL) was required to be >0.06 ng/μL to ensure a successful STR analysis. Thus, the required extraction volumes of urine preserved for 3-7 years at -20 °C were estimated to be 30 mL and 20 mL to succeed in at least 86% of men and 91% of women, respectively. Considering the long half-life of DNA during long-term preservation, our extraction method is applicable to urine samples stored even for 10 years, which is currently the storage duration allowed (increased from 8 years) before re-examination in doping control. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.

Simulation of a 250 kW diesel fuel processor/PEM fuel cell system

NASA Astrophysics Data System (ADS)

Amphlett, J. C.; Mann, R. F.; Peppley, B. A.; Roberge, P. R.; Rodrigues, A.; Salvador, J. P.

Polymer-electrolyte membrane (PEM) fuel cell systems offer a potential power source for utility and mobile applications. Practical fuel cell systems use fuel processors for the production of hydrogen-rich gas. Liquid fuels, such as diesel or other related fuels, are attractive options as feeds to a fuel processor. The generation of hydrogen gas for fuel cells, in most cases, becomes the crucial design issue with respect to weight and volume in these applications. Furthermore, these systems will require a gas clean-up system to insure that the fuel quality meets the demands of the cell anode. The endothermic nature of the reformer will have a significant affect on the overall system efficiency. The gas clean-up system may also significantly effect the overall heat balance. To optimize the performance of this integrated system, therefore, waste heat must be used effectively. Previously, we have concentrated on catalytic methanol-steam reforming. A model of a methanol steam reformer has been previously developed and has been used as the basis for a new, higher temperature model for liquid hydrocarbon fuels. Similarly, our fuel cell evaluation program previously led to the development of a steady-state electrochemical fuel cell model (SSEM). The hydrocarbon fuel processor model and the SSEM have now been incorporated in the development of a process simulation of a 250 kW diesel-fueled reformer/fuel cell system using a process simulator. The performance of this system has been investigated for a variety of operating conditions and a preliminary assessment of thermal integration issues has been carried out. This study demonstrates the application of a process simulation model as a design analysis tool for the development of a 250 kW fuel cell system.

Approaches for enhanced phytoextraction of heavy metals.

PubMed

Bhargava, Atul; Carmona, Francisco F; Bhargava, Meenakshi; Srivastava, Shilpi

2012-08-30

The contamination of the environment with toxic metals has become a worldwide problem. Metal toxicity affects crop yields, soil biomass and fertility. Soils polluted with heavy metals pose a serious health hazard to humans as well as plants and animals, and often requires soil remediation practices. Phytoextraction refers to the uptake of contaminants from soil or water by plant roots and their translocation to any harvestable plant part. Phytoextraction has the potential to remove contaminants and promote long-term cleanup of soil or wastewater. The success of phytoextraction as a potential environmental cleanup technology depends on factors like metal availability for uptake, as well as plants ability to absorb and accumulate metals in aerial parts. Efforts are ongoing to understand the genetics and biochemistry of metal uptake, transport and storage in hyperaccumulator plants so as to be able to develop transgenic plants with improved phytoremediation capability. Many plant species are being investigated to determine their usefulness for phytoextraction, especially high biomass crops. The present review aims to give an updated version of information available with respect to metal tolerance and accumulation mechanisms in plants, as well as on the environmental and genetic factors affecting heavy metal uptake. The genetic tools of classical breeding and genetic engineering have opened the door to creation of 'remediation' cultivars. An overview is presented on the possible strategies for developing novel genotypes with increased metal accumulation and tolerance to toxicity. Copyright © 2012 Elsevier Ltd. All rights reserved.

Determination of organophosphate flame retardants in soil and fish using ultrasound-assisted extraction, solid-phase clean-up, and liquid chromatography with tandem mass spectrometry.

PubMed

Lorenzo, María; Campo, Julián; Picó, Yolanda

2018-03-22

A solid-liquid extraction method in combination with high-performance liquid chromatography and tandem mass spectrometry was developed and optimized for extraction and analysis of organophosphorus flame retardants in soil and fish. Methanol was chosen as the optimum extraction solvent, not only in terms of extraction efficiency, but also for its broader analyte coverage. The subsequent clean-up by solid-phase extraction is required to eliminate matrix coextractives and reduce matrix effects. Recoveries of the optimized method were 50-121% for soil and 47-123% for biota, both with high precision (RSDs <12% in soil and <23% in biota). The method limits of detection ranged from 0.06 to 0.20 ng/g dry weight and between 0.02 and 0.30 ng/g wet weight for soil and biota samples, respectively. However, samples with a high lipid content produce several problems as solid-phase extraction cartridge clogging that increase variability and analysis time. The method was successfully applied for the determination of organophosphorus flame retardants in soil and fish from L'Albufera Natural Park (Valencia, Spain). Target compounds were detected in all soil and fish samples with values varying from 13.8 to 89.7 ng/g dry weight and from 3.3 to 53.0 ng/g wet weight, respectively. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Child Abuse and Neglect: The Problem and Its Management. Volume 1: An Overview of the Problem.

ERIC Educational Resources Information Center

National Center on Child Abuse and Neglect (DHEW/OHD), Washington, DC.

This booklet, first of a three-volume series, presents an overview of the problems of child abuse and neglect. Discussions focus on child maltreatment from various perspectives, including characteristics of the parents and children, effects of abuse and neglect, a phychiatrist's view of the problem, and a discussion of state reporting laws. The…

Life Skills Coach Training Manual.

ERIC Educational Resources Information Center

Saskatchewan NewStart, Inc., Prince Albert.

Ways of helping coaches to counsel unemployed adults in the solving of their personal problems are explored in this manual. Originally printed as two separate volumes, this reprinting of the study has bound the two together. Volume I involves a general discussion of life's problems and of the need to solve them. This volume contains four parts.…

An Example Emphasizing Mass-Volume Relationships for Problem Solving in Soils

ERIC Educational Resources Information Center

Heitman, J. L.; Vepraskas, M. J.

2009-01-01

Mass-volume relationships are a useful tool emphasized for problem solving in many geo-science and engineering applications. These relationships also have useful applications in soil science. Developing soils students' ability to utilize mass-volume relationships through schematic diagrams of soil phases (i.e., air, water, and solid) can help to…

ReOpt[trademark] V2.0 user guide

DOE Office of Scientific and Technical Information (OSTI.GOV)

White, M K; Bryant, J L

1992-10-01

Cleaning up the large number of contaminated waste sites at Department of Energy (DOE) facilities in the US presents a large and complex problem. Each waste site poses a singular set of circumstances (different contaminants, environmental concerns, and regulations) that affect selection of an appropriate response. Pacific Northwest Laboratory (PNL) developed ReOpt to provide information about the remedial action technologies that are currently available. It is an easy-to-use personal computer program and database that contains data about these remedial technologies and auxiliary data about contaminants and regulations. ReOpt will enable engineers and planners involved in environmental restoration efforts to quicklymore » identify potentially applicable environmental restoration technologies and access corresponding information required to select cleanup activities for DOE sites.« less

Potential occupational exposures in the Reiss-Engelhorn-Museen Mannheim/Germany.

PubMed

Musshoff, Frank; Gottsmann, Sandra; Mitschke, Sylvia; Rosendahl, Wilfried; Madea, Burkhard

2010-12-01

The Reiss-Engelhorn-Museen in Mannheim, Germany requested support from a toxicological laboratory in evaluating occupational exposures before a cleanup and renovation period in 2006. Samples of dust and dirt and scrapings of exhibits were collected from several locations. Following toxicologically relevant compounds could be identified by gas chromatography - mass spectrometry (GC/MS) by comparison with a mass spectra library: dichlorodiphenyl trichloroethane (DDT) and its breakdown product dichlorodiphenyl dichloroethane (DDD) as well as dichlorodiphenyl dichlorethylene (DDE), methoxychlor, nicotine, and camphor. In recent times various insecticides have been used to protect museum artefacts against moths, woodborers and other insect pests. Caution has to be made because the presence of hazardous compounds can result in security problems for museum staff as well as for visitors.

Thermal treatment wall

DOEpatents

Aines, Roger D.; Newmark, Robin L.; Knauss, Kevin G.

2000-01-01

A thermal treatment wall emplaced to perform in-situ destruction of contaminants in groundwater. Thermal destruction of specific contaminants occurs by hydrous pyrolysis/oxidation at temperatures achievable by existing thermal remediation techniques (electrical heating or steam injection) in the presence of oxygen or soil mineral oxidants, such as MnO.sub.2. The thermal treatment wall can be installed in a variety of configurations depending on the specific objectives, and can be used for groundwater cleanup, wherein in-situ destruction of contaminants is carried out rather than extracting contaminated fluids to the surface, where they are to be cleaned. In addition, the thermal treatment wall can be used for both plume interdiction and near-wellhead in-situ groundwater treatment. Thus, this technique can be utilized for a variety of groundwater contamination problems.

Soft interactions and volume exclusion by polymeric crowders can stabilize or destabilize transient structure in disordered proteins depending on polymer concentration.

PubMed

Rusinga, Farai I; Weis, David D

2017-08-01

The effects of macromolecular crowding on the transient structure of intrinsically disordered proteins is not well-understood. Crowding by biological molecules inside cells could modulate transient structure and alter IDP function. Volume exclusion theory and observations of structured proteins suggest that IDP transient structure would be stabilized by macromolecular crowding. Amide hydrogen exchange (HX) of IDPs in highly concentrated polymer solutions would provide valuable insights into IDP transient structure under crowded conditions. Here, we have used mass spectrometry to measure HX by a transiently helical random coil domain of the activator of thyroid and retinoid receptor (ACTR) in solutions containing 300 g L -1 and 400 g L -1 of Ficoll, a synthetic polysaccharide, using a recently-developed strong cation exchange-based cleanup method [Rusinga, et al., Anal Chem 2017;89:1275-1282]. Transiently helical regions of ACTR exchanged faster in 300 g L -1 Ficoll than in dilute buffer. In contrast, one transient helix exchanged more slowly in 400 g L -1 Ficoll. Nonspecific interactions destabilize ACTR helicity in 300 g L -1 Ficoll because ACTR engages with the Ficoll polymer mesh. In contrast, 400 g L -1 Ficoll is a semi-dilute solution where ACTR cannot engage the Ficoll mesh. At this higher concentration, volume exclusion stabilizes ACTR helicity because ACTR is compacted in interstitial spaces between Ficoll molecules. Our results suggest that the interplay between nonspecific interactions and volume exclusion in different cellular compartments could modulate IDP function by altering the stability of IDP transient structures. Proteins 2017; 85:1468-1479. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dowell, Jonathan; Franco, Joe

The discussion of Hanford's River Corridor will cover work that has already been completed plus the work remaining to be done. This includes the buildings, waste sites, and groundwater plumes in the 300 Area; large-scale burial ground remediation in the 600 Area; plutonium production reactor dismantling and 'cocooning' along the river; preservation of the world's first full-scale plutonium production reactor; removal of more than 14 million tons of contaminated soil and debris along the Columbia River shoreline and throughout the River Corridor; and the excavation of buried waste sites in the river shore area. It also includes operating an EPA-permittedmore » low-level waste disposal facility in the central portion of the site. At the completions of cleanup in 2015, Hanford's River Corridor will be the largest closure project ever completed by the Department of Energy. Cleanup of the River Corridor has been one of Hanford's top priorities since the early 1990's. This urgency has been due to the proximity of hundreds of waste sites to the Columbia River. In addition, removal of the sludge from K West Basin, near the river, remains a high priority. This 220-square-mile area of the Hanford Site sits on the edge of the last free-flowing stretch of the Columbia River. The River Corridor portion of the Hanford Site includes the 100 and 300 Areas along the south shore of the Columbia River. The 100 Areas contain nine retired plutonium production reactors. These areas are also the location of numerous support facilities and solid and liquid waste disposal sites that have contaminated groundwater and soil. The 300 Area, located just north of the city of Richland, contains fuel fabrication facilities, nuclear research and development facilities, and their associated solid and liquid waste disposal sites that have contaminated groundwater and soil. In order to ensure that cleanup actions address all threats to human health and the environment, the River Corridor includes the adjacent areas that extend from the 100 Area and 300 Area to the Central Plateau. For sites in the River Corridor, remedial actions are expected to restore groundwater to drinking water standards and ensure that aquatic life in the Columbia River is protected by achieving ambient water quality standards. It is intended that these objectives be achieved, unless technically impracticable, within a reasonable timeframe. In those instances where remedial action objectives are not achievable in a reasonable time frame, or are determined to be technically impracticable, programs are being implemented to contain the plume, prevent exposure to contaminated groundwater, and evaluate further risk reduction opportunities as new technologies become available. River Corridor cleanup work also removes potential sources of contamination, which are close to the Columbia River, and places them on the Central Plateau for final disposal. The intent is to shrink the footprint of active cleanup to within the 75-square- mile area of the Central Plateau by removing excess facilities and remediating waste sites. Cleanup actions are supporting anticipated future land uses consistent with the Hanford Reach National Monument, where applicable, and the Hanford Comprehensive Land- Use Plan (DOE 1999). The River Corridor has been divided into six geographic decision areas to achieve source and groundwater remedy decisions. These decisions will provide comprehensive coverage for all areas within the River Corridor and will incorporate ongoing interim action cleanup activities. Cleanup levels will be achieved in order to support anticipated future land uses of conservation and preservation for most of this area and industrial use for the 300 Area. At the conclusion of cleanup actions, the federal government will implement long-term stewardship activities to ensure protection of human health and the environment. (authors)« less

Base Realignment and Closure (BRAC) Cleanup Plan, Ford Ord, Monterey, California

DTIC Science & Technology

1994-03-25

2,036.39 1 10 Maria Antonia Field 563.19 1 11 Stephen Joseph Field 1,018.02 1 April 1944 Key: I = Undocumented o45.sj Fort Ord, California - 25 March 1994...geophysical anomalies Further investigation of canal containoc .etroleum hydrocarbons discharge area which depending on and vanous organic compounds...detected at various areas. Concentration below TPH cleanup standard. Canal discharge area soil contained Pb, Sb, and Cr at concentration of concern. For

Groundwater Contamination: DOD Uses and Develops a Range of Remediation Technologies to Clean Up Military Sites

DTIC Science & Technology

2005-06-01

relative cost -effectiveness of a technology for a given site. DOD has identified a number of contaminants of concern at its facilities, each of...to contain or eliminate hazardous contaminants in groundwater. However, the long cleanup times and high costs of using pump-and- treat technologies...environment. DOD estimates that cleanup of its contaminated sites will cost billions of dollars and may take decades to complete because of the

Drivers and applications of integrated clean-up technologies for surfactant-enhanced remediation of environments contaminated with polycyclic aromatic hydrocarbons (PAHs).

PubMed

Liang, Xujun; Guo, Chuling; Liao, Changjun; Liu, Shasha; Wick, Lukas Y; Peng, Dan; Yi, Xiaoyun; Lu, Guining; Yin, Hua; Lin, Zhang; Dang, Zhi

2017-06-01

Surfactant-enhanced remediation (SER) is considered as a promising and efficient remediation approach. This review summarizes and discusses main drivers on the application of SER in removing polycyclic aromatic hydrocarbons (PAHs) from contaminated soil and water. The effect of PAH-PAH interactions on SER efficiency is, for the first time, illustrated in an SER review. Interactions between mixed PAHs could enhance, decrease, or have no impact on surfactants' solubilization power towards PAHs, thus affecting the optimal usage of surfactants for SER. Although SER can transfer PAHs from soil/non-aqueous phase liquids to the aqueous phase, the harmful impact of PAHs still exists. To decrease the level of PAHs in SER solutions, a series of SER-based integrated cleanup technologies have been developed including surfactant-enhanced bioremediation (SEBR), surfactant-enhanced phytoremediation (SEPR) and SER-advanced oxidation processes (SER-AOPs). In this review, the general considerations and corresponding applications of the integrated cleanup technologies are summarized and discussed. Compared with SER-AOPs, SEBR and SEPR need less operation cost, yet require more treatment time. To successfully achieve the field application of surfactant-based technologies, massive production of the cost-effective green surfactants (i.e. biosurfactants) and comprehensive evaluation of the drivers and the global cost of SER-based cleanup technologies need to be performed in the future. Copyright © 2017. Published by Elsevier Ltd.

Health investigations of depleted-uranium clean-up workers.

PubMed

Milacic, Snezana

2008-01-01

The soil contaminated by depleted uranium (238U) ammunition during the NATO bombing of Serbia and Montenegro was cleaned-up for four months in 2002. A team of 11 clean-up workers (expert members) were medically examined three times: before decontamination as a preliminary medical check-up, immediately after decontamination, and four years after cleaning up contaminated ground. This short report presents investigations and health risk assessments of clean-up workers in radioactive decontamination operations and an assessment of the environmental health perspectives for citizens living in surrounding areas. The method of initial health disorders was used, analyzing the most sensitive biological materials, such as blood cells or chromosome damage, DNA strand breaks, radio-toxicological examination of urine. The total number of blood cells did not change, but variations of the relative number (percentage) of cells in the leukocyte formula were observed. The total number of DNA alterations was higher immediately after decontamination than before decontamination. Four years after decontamination the number of DNA alterations had decreased. However, the number of damaged cells (lymphocytes containing chromosome lesions) was higher in both medical examinations, immediately after and four years after decontamination. Disease or tumours due to 238U did not develop in the group of depleted uranium clean-up workers during the investigation period of four years. Further monitoring of haematological and chromosomal effects and the health condition of workers is necessary.

Potential Environmental and Environmental-Health Implications of the SAFRR Tsunami Scenario in California: Chapter F in The SAFRR (Science Application for Risk Reduction) Tsunami Scenario

USGS Publications Warehouse

Plumlee, Geoffrey S.; Morman, Suzette A.; San Juan, Carma

2013-01-01

If human populations are successfully evacuated prior to the tsunami arrival, there would be no or limited numbers of drownings, other casualties, or related injuries, wounds, and infections. Immediately after the tsunami, human populations away from the inundation zone could be transiently exposed to airborne gases, smoke, and ash from tsunamigenic fires. Cleanup and disposal, particularly of hazardous materials, would pose substantial logistical challenges and economic costs. Given the high value of the coastal residential and commercial properties in the inundation zone, it can be postulated that there would be substantial insurance claims for environmental restoration, mold mitigation, disposal of debris that contains hazardous materials, and costs of litigation related to environmental liability. Post-tsunami cleanup, if done with appropriate mitigation (for example, dust control), personal protection, and disposal measures, would help reduce the potential for cleanup-worker and resident exposures to toxicants and pathogens in harbor waters, debris, soils, ponded waters, and buildings. A number of other steps can be taken by governments, businesses, and residents to help reduce the environmental impacts of tsunamis and to recover more quickly from these environmental impacts. For example, development of State and local policies that foster rapid assessment of potential contamination, as well as rapid decision making for disposal options should hazardous debris or sediment be identified, would help enhance recovery by speeding cleanup.

Cleanups In My Community (CIMC) - Federal Facility RCRA Sites, National Layer

EPA Pesticide Factsheets

Federal facilities are properties owned by the federal government. This data layer provides access to Federal facilities that are Resource Conservation and Recovery Act (RCRA) sites as part of the CIMC web service. The Resource Conservation and Recovery Act, among other things, helps ensure that wastes are managed in an environmentally sound manner so as to protect human health and the environment from the potential hazards of waste disposal.In particular, RCRA tightly regulates all hazardous waste from cradle to grave. In general, all generators, transporters, treaters, storers, and disposers of hazardous waste are required to provide information about their activities to state environmental agencies. These agencies, in turn pass on the information to regional and national EPA offices. Accidents or other activities at facilities that treat, store or dispose of hazardous wastes have sometimes led to the release of hazardous waste or hazardous constituents into soil, ground water, surface water, or air. When that happens, the RCRA Corrective Action program is one program that may be used to accomplish the necessary cleanup.In Cleanups in My Community, you can map or list RCRA Corrective Action sites that are currently undergoing corrective action, sites for which a remedy has been selected, sites for which construction has been completed, and sites where the corrective action cleanup is complete. This data layer shows those RCRA sites that are located at Federa

The Potential for Human Resources and Economic Growth in a Declining Local Community, A Socio-Economic Study of the Johnstown, Pennsylvania Economy, Volume II.

ERIC Educational Resources Information Center

Levine, Louis; And Others

The data provided in the second volume of this two-volume report are interpreted within the context of the social and economic problems identified in the first volume. With its lack of diversified industry, Johnstown, Pennsylvania was found to have the revenue problems typical of a depressed economy, accentuated by a decline in markets for its…

Two volume integral equations for the inhomogeneous and anisotropic forward problem in electroencephalography

NASA Astrophysics Data System (ADS)

Rahmouni, Lyes; Mitharwal, Rajendra; Andriulli, Francesco P.

2017-11-01

This work presents two new volume integral equations for the Electroencephalography (EEG) forward problem which, differently from the standard integral approaches in the domain, can handle heterogeneities and anisotropies of the head/brain conductivity profiles. The new formulations translate to the quasi-static regime some volume integral equation strategies that have been successfully applied to high frequency electromagnetic scattering problems. This has been obtained by extending, to the volume case, the two classical surface integral formulations used in EEG imaging and by introducing an extra surface equation, in addition to the volume ones, to properly handle boundary conditions. Numerical results corroborate theoretical treatments, showing the competitiveness of our new schemes over existing techniques and qualifying them as a valid alternative to differential equation based methods.

N-doped carbon nanotubes-reinforced hollow fiber solid-phase microextraction coupled with high performance liquid chromatography for the determination of phytohormones in tomatoes.

PubMed

Han, Xiao-Fei; Chen, Juan; Shi, Yan-Ping

2018-08-01

A N-doped carbon nanotubes-reinforced hollow fiber solid-phase microextraction (N-doped CNTs-HF-SPME) method was developed for determination of two naphthalene-derived phytohormones, 1-naphthalene acetic acid (NAA) and 2-naphthoxyacetic acid (2-NOA), at trace levels in tomatoes. N-doped CNTs were dispersed in ultrapure water with the assistance of surfactant, and then immobilized into the pores of hollow fiber by capillary forces and sonification. The resultant N-doped CNTs-HF was wetted with 1-octanol, subsequently immersed into the tomato samples to extract the target analytes under a magnetic stirring, and then desorbed with methanol by sonication prior to chromatographic analysis. Compared with CNTs, the surface hydrophilicity of N-doped CNTs was improved owing to the doping of nitrogen atoms, and a uniform dispersion was formed, thus greatly simplifying the preparation process and reducing waste of materials. In addition, N-doped CNTs-HF exhibits a more effective extraction performance for NAA and 2-NOA on account of the introduction of Lewis-basic nitrogen. It is worth to mention that owing to the clean-up function of HF, there are not any complicated sample pretreatment procedures prior to the microextraction. To achieve the highest extraction efficiency, important microextraction parameters including the length and the concentration level of N-doped CNTs in surfactant solution, extraction time, desorption conditions such as the type and volume of solvents, pH value, stirring rate and volume of the donor phase were thoroughly investigated and optimized. Under the optimal conditions, the method showed 165- and 123-fold enrichment factors of NAA and 2-NOA, good inter-fiber repeatability and batch-to-batch reproducibility, good linearity with correlation coefficients higher than 0.9990, low limits of detection and quantification (at ng g -1 levels), and satisfactory recoveries in the range of 83.10-108.32% at three spiked levels. The proposed method taking advantages of both excellent adsorption performance of N-doped CNTs and the clean-up function of HF, was a simple, green, efficient and cost-effective enrichment procedure for the determination of trace NAA and 2-NOA in tomatoes. Copyright © 2018 Elsevier B.V. All rights reserved.

Acute Health Effects Among Military Personnel Participating in the Cleanup of the Hebei Spirit Oil Spill, 2007, in Taean County, Korea

PubMed Central

Gwack, Jin; Lee, Ju Hyung; Kang, Young Ah; Chang, Kyu-jin; Lee, Moo Sik; Hong, Jee Young

2012-01-01

Objectives This study was conducted to investigate acute health effects and its related factors among military personnel participating in the cleanup of the 2007 Hebei Spirit oil spill accident in Taean county, Korea. Methods We collected data on acute symptoms during the cleanup and their predictors using a self-administered questionnaire to 2624 military personnel. Selfreported symptoms included six neurologic symptoms, five respiratory symptoms, two dermatologic symptoms, three ophthalmic symptoms, and three general symptoms. Independent variables were demographic factors (gender, age, education level, and rank), health behavioral factors (smoking history and usage of the personal protective equipment such as masks and gloves), and occupational history such as where and for how long individuals participated in cleanup. Results The duration of work days was significantly associated with 17 acute symptoms except for itchiness and red skin.Working in Taean county also increased the risk of most acute symptoms except headache and back pain. In regard to personal protective equipment, wearing masks was mainly related to the development of respiratory symptoms such as sore throat and wearing other protective equipment was related to the development of sore throat, back pain, headache, and cough. Military personnel younger than 25 years reported 4.66 times more hot flushing and 5.39 times more itchiness than those older than 25 years. Conclusion It should be emphasized that for early-stage cleanup the number of workers should be minimized, sufficient personal protective equipment with approved quality for blocking noxious gas should be supplied, and systematic health care for the workers should be provided. Health effects could be diminished by providing adequate education regarding the appropriate use of protective equipment, especially to nonprofessionals such as residents and volunteers. To make disaster response expeditious, a national and regional preparedness plans and a professional response team for emergency environmental assessment and emergency action should be established beforehand to make prompt decisions. PMID:24159516