Evaluating the co-production of a near real time Earthquake Aftershock forecasting tool for humanitarian risk assessment and emergency planning

NASA Astrophysics Data System (ADS)

Quinn, Keira; Hope, Max; McCloskey, John; NicBhloscaidh, Mairead; Jimenez, Abigail; Dunlop, Paul

2015-04-01

Concern Worldwide and the University of Ulster Geophysics Research Group are engaged in a project to co-produce a suite of software and mapping tools to assess aftershock hazard in near real-time during the emergency response phase of earthquake disaster, and inform humanitarian emergency planning and response activities. This paper uses a social learning approach to evaluate this co-production process. Following Wenger (1999) we differentiate between the earthquake science and humanitarian communities of practice (CoP) along three dimensions: enterprise (the purpose of CoPs and the problems participants are working to address), repertoire (knowledge, skills, language), and identity (values and boundaries). We examine the effectiveness of learning between CoP, focusing on boundary work and objects, and various organisational structures and aspects of the wider political economy of learning that enable and hinder the co-production process. We conclude by identifying a number of ways to more effectively integrate earthquake science into humanitarian decision-making, policy development and programme design.

Subsurface Characterization and Seismic Monitoring for the Southwest Partnerships Phase III Demonstration Project at Farnsworth Field, TX

NASA Astrophysics Data System (ADS)

Will, R. A.; Balch, R. S.

2015-12-01

The Southwest Partnership on Carbon Sequestration is performing seismic based characterization and monitoring activities at an active CO2 EOR project at Farnsworth Field, Texas. CO2 is anthropogenically sourced from a fertilizer and an ethanol plant. The field has 13 CO2 injectors and has sequestered 302,982 metric tonnes of CO2 since October 2013. The field site provides an excellent laboratory for testing a range of monitoring technologies in an operating CO2 flood since planned development is sequential and allows for multiple opportunities to record zero CO2 baseline data, mid-flood data, and fully flooded data. The project is comparing and contrasting several scales of seismic technologies in order to determine best practices for large scale commercial sequestration projects. Characterization efforts include an 85 km2 3D surface seismic survey, baseline and repeat 3D VSP surveys centered on injection wells, cross-well tomography baseline and repeat surveys between injector/producer pairs, and a borehole passive seismic array to monitor induced seismicity. All surveys have contributed to detailed geologic models which were then used for fluid flow and risk assessment simulations. 3D VSP and cross-well data with repeat surveys have allowed for direct comparisons of the reservoir prior to CO2 injection and at eight months into injection, with a goal of imaging the CO2 plume as it moves away from injection wells. Additional repeat surveys at regular intervals will continue to refine the plume. The goal of this work is to demonstrate seismic based technologies to monitor CO2 sequestration projects, and to contribute to best practices manuals for commercial scale CO2 sequestration projects. In this talk the seismic plan will be outlined, progress towards goals enumerated, and preliminary results from baseline and repeat seismic data will be discussed. Funding for this project is provided by the U.S. Department of Energy under Award No. DE-FC26-05NT42591.

Work reintegration after long-term sick leave: domains of influence on co-workers' ability to be supportive.

PubMed

Petersen, Kirsten Schultz; Labriola, Merete; Nielsen, Claus Vinther; Larsen, Eva Ladekjær

2016-09-01

The purpose of the study is to identify domains of influence on co-workers' ability to be supportive of returning worker during the work reintegration (WR) process. An ethnographic study design was chosen involving fieldwork at four different workplaces, at an emergency care service, a waste disposal company and at two nursing homes. Qualitative methods for inquiry were used including participant observation, individual- and group interviews of 30 participants. Data were coded and analysed according to a grounded theory approach. Four themes were identified related to domains of influence on co-workers' ability to be supportive of returning worker during the WR process: (1) organisation of work and level of interaction; (2) disruption of work routines, (3) relationship with returning worker and (4) attitudes towards sick leave. The WR process after long-term sick leave is not only influenced by the WR's arrangements made, but also by the co-workers' responses to the process. Work arrangements not only affect the returning worker's ability to return-to-work (RTW) successfully, but also the co-workers' ability to be supportive and their ability to take active part in the process. Implications for Rehabilitation The process of WR after long-term sick leave involves interaction with co-workers. Domains of influence is in the co-workers' perspective influencing their ability to be supportive during reintegration of a returning worker. Future WR management could benefit from integrating the conditions for co-worker support. We encourage co-workers to be involved in the RTW planning, monitoring and evaluation with particular focus on how the WR arrangements are influencing their work and their ability to be supportive.

The measurement of carbon dioxide levels in a city canyon

NASA Astrophysics Data System (ADS)

Boyd, Jenny; Budinov, Daniel; Robinson, Iain; Jack, James

2016-10-01

Cities today have two major environmental concerns - carbon emissions and air quality. Global carbon levels are increasing and cities require to show plans to tackle and reduce the amount of carbon which they are emitting. At present carbon emissions in urban areas are calculated rather than measured. In some cities where industrial activity is not carbon intensive, the major contributors are the burning of fuel for heating and the emissions from vehicles. Air quality levels have a direct impact on human health and cities are under increased pressure to demonstrate plans to control and reduce levels of air pollution. Of great importance is the way in which emissions, both carbon rich emissions and pollutants, disperse in a city environment. Little work has been reported on the movement of CO2 in the urban environment and the effect the structure of the environment exerts on the movement and dispersion. This paper describes an investigation into the dispersion of CO2 within an urban environment in the Old Town of the City of Edinburgh, using a hand carried low cost portable CO2 sensor.

Treatment plan comparison between Tri-Co-60 magnetic-resonance image-guided radiation therapy and volumetric modulated arc therapy for prostate cancer

PubMed Central

Park, Jong Min; Park, So-Yeon; Choi, Chang Heon; Chun, Minsoo; Kim, Jin Ho; Kim, Jung-In

2017-01-01

To investigate the plan quality of tri-Co-60 intensity-modulated radiation therapy (IMRT) with magnetic-resonance image-guided radiation therapy compared with volumetric-modulated arc therapy (VMAT) for prostate cancer. Twenty patients with intermediate-risk prostate cancer, who received radical VMAT were selected. Additional tri-Co-60 IMRT plans were generated for each patient. Both primary and boost plans were generated with tri-Co-60 IMRT and VMAT techniques. The prescription doses of the primary and boost plans were 50.4 Gy and 30.6 Gy, respectively. The primary and boost planning target volumes (PTVs) of the tri-Co-60 IMRT were generated with 3 mm margins from the primary clinical target volume (CTV, prostate + seminal vesicle) and a boost CTV (prostate), respectively. VMAT had a primary planning target volume (primary CTV + 1 cm or 2 cm margins) and a boost PTV (boost CTV + 0.7 cm margins), respectively. For both tri-Co-60 IMRT and VMAT, all the primary and boost plans were generated that 95% of the target volumes would be covered by the 100% of the prescription doses. Sum plans were generated by summation of primary and boost plans. In sum plans, the average values of V70 Gy of the bladder of tri-Co-60 IMRT vs. VMAT were 4.0% ± 3.1% vs. 10.9% ± 6.7%, (p < 0.001). Average values of V70 Gy of the rectum of tri-Co-60 IMRT vs. VMAT were 5.2% ± 1.8% vs. 19.1% ± 4.0% (p < 0.001). The doses of tri-Co-60 IMRT delivered to the bladder and rectum were smaller than those of VMAT while maintaining identical target coverage in both plans. PMID:29207634

Merging Expertise: Preparing Collaborative Educators

ERIC Educational Resources Information Center

Altieri, Elizabeth M.; Colley, Kenna M.; Daniel, Leslie S.; Dickenson, Kathie W.

2015-01-01

In this article, teacher education faculty of a medium-size university, historically grounded in teacher preparation within a rural context, describe their ongoing work to transform their practice in order to prepare special and general educators who co-plan, co-teach, and co-assess with their counterparts in the field. Follow-up research with…

A statistical test for the habitable zone concept

NASA Astrophysics Data System (ADS)

Checlair, J.; Abbot, D. S.

2017-12-01

Traditional habitable zone theory assumes that the silicate-weathering feedback regulates the atmospheric CO2 of planets within the habitable zone to maintain surface temperatures that allow for liquid water. There is some non-definitive evidence that this feedback has worked in Earth history, but it is untested in an exoplanet context. A critical prediction of the silicate-weathering feedback is that, on average, within the habitable zone planets that receive a higher stellar flux should have a lower CO2 in order to maintain liquid water at their surface. We can test this prediction directly by using a statistical approach involving low-precision CO2 measurements on many planets with future instruments such as JWST, LUVOIR, or HabEx. The purpose of this work is to carefully outline the requirements for such a test. First, we use a radiative-transfer model to compute the amount of CO2 necessary to maintain surface liquid water on planets for different values of insolation and planetary parameters. We run a large ensemble of Earth-like planets with different masses, atmospheric masses, inert atmospheric composition, cloud composition and level, and other greenhouse gases. Second, we post-process this data to determine the precision with which future instruments such as JWST, LUVOIR, and HabEx could measure the CO2. We then combine the variation due to planetary parameters and observational error to determine the number of planet measurements that would be needed to effectively marginalize over uncertainties and resolve the predicted trend in CO2 vs. stellar flux. The results of this work may influence the usage of JWST and will enhance mission planning for LUVOIR and HabEx.

11. Photographic copy of copy of Twin Lakes Outlet Works ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

11. Photographic copy of copy of Twin Lakes Outlet Works construction drawing dated January 15, 1951. Drawn by W.A. Doe for the Twin Lakes Reservoir and Canal Co. (copy in possession of Bureau of Reclamation, location of original unknown) 'AS CONSTRUCTED' PLANS OF 1949-1950, REHABILITATION OF TWIN LAKES RESERVOIR OUTLET WORKS, DETAILS OF UPSTREAM WING WALLS. - Twin Lakes Dam & Outlet Works, Beneath Twin Lakes Reservoir, T11S, R80W, S22, Twin Lakes, Lake County, CO

12. Photographic copy of copy of Twin Lakes Outlet Works ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

12. Photographic copy of copy of Twin Lakes Outlet Works construction drawing dated January 15, 1951. Drawn by W.A. Doe for the Twin Lakes Reservoir and Canal Co. (copy in possession of Bureau of Reclamation, location of original unknown) 'AS CONSTRUCTED' PLANS OF 1949-50, REHABILITATION OF TWIN LAKES RESERVOIR OUTLET WORKS, DETAILS OF DISCHARGE BASIN. - Twin Lakes Dam & Outlet Works, Beneath Twin Lakes Reservoir, T11S, R80W, S22, Twin Lakes, Lake County, CO

Step 2: Enter Baseline Energy Consumption Data | Climate Action Planning

Science.gov Websites

Scope 1: Emissions (Direct Combustion) T CO2e = Tonnes of Carbon Dioxide Equivalent* Gas (T CO2e) Oil (T CO2e) Coal (T CO2e) Fleet (T CO2e) Total (T CO2e) *Metric tons of CO2 equivalent or 2.204 lbs of CO2

Towards Combining Active and Passive Greenhouse Gas Remote Sensing from Space: Progress and Plans at the German Aerospace Center

NASA Astrophysics Data System (ADS)

Rapp, M.; Ehret, G.; Fix, A.; Wirth, M.; Amediek, A.; Kiemle, C.; Quatrevalet, M.; Butz, A.; Roiger, A.; Joeckel, P.

2017-12-01

For meeting the goals of the Paris agreement it is highly desirable to obtain objective global information on anthropogenic greenhouse gas emission rates. A promising approach for a space based observation system is the combination of active and passive remote sensing from satellites in Low Earth Orbit (LEO). While LIDAR techniques have the potential to yield low bias observations which are independent of solar illumination and hence also work during night and at polar winter latitudes, spectroscopic observations of scattered sunlight are suitable for imaging atmospheric concentrations at high spatial resolution. This presentation reviews progress and plans of work conducted at the German Aerospace Center (DLR). Regarding active remote sensing, DLR has developed the airborne Integrated Path Differential Absorption (IPDA)-Lidar CHARM-F (CO2 and CH4 Remote Monitoring—Flugzeug) for the quantification of carbon dioxide and methane column mixing ratios. CHARM-F has been deployed in an initial airborne field campaign in spring 2015 and results of strong anthropogenic sources detected during these flights will be presented. In addition, DLR is in the process of preparing an international airborne campaign (CoMet - Carbon Dioxide and Methane Mission for HALO) for April 2018 which will be supported by various in-situ, ground based, and modelling activities. These airborne field campaigns are important steps towards the German-French satellite mission MERLIN which also utilizes an IPDA-LIDAR. Also, DLR has started to further investigate concepts for a future space borne IPDA-Lidar for the quantification of strong anthropogenic CO2 point sources. Jointly with the latter, DLR is currently further studying the concept of a passive spectrometer for the observation of CO2 point emissions.

Comparison of high-pressure CO 2 sorption isotherms on Eastern and Western US coals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Romanov, V; Hur, T -B; Fazio, J

2013-10-01

Accurate estimation of carbon dioxide (CO 2) sorption capacity of coal is important for planning the CO 2 sequestration efforts. In this work, we investigated sorption and swelling behavior of several Eastern and Western US coal samples from the Central Appalachian Basin and from San Juan Basin. The CO 2 sorption isotherms have been completed at 55°C for as received and dried samples. The role of mineral components in coal, the coal swelling, the effects of temperature and moisture, and the error propagation have been analyzed. Changes in void volume due to dewatering and other factors such as temporary cagingmore » of carbon dioxide molecules in coal matrix were identified among the main factors affecting accuracy of the carbon dioxide sorption isotherms. The (helium) void volume in the sample cells was measured before and after the sorption isotherm experiments and was used to build the volume-corrected data plots.« less

The social interaction of return to work explored from co-workers experiences.

PubMed

Tjulin, Åsa; MacEachen, Ellen; Stiwne, Elinor Edvardsson; Ekberg, Kerstin

2011-01-01

The objective was to explore the role and contribution of co-workers in the return-to-work process. The social interaction of co-workers in the return-to-work process are analysed within the framework of the Swedish national and local employer organisational return-to-work policies. An exploratory qualitative method was used, consisting of open-ended interviews with 33 workplace actors across seven work units. Organisational return-to-work policies were collected from the three public sector employers. The key findings that emerged during analysis showed that some co-workers have a more work-task oriented approach towards the return-to-work process, whilst others had a more social relational approach. In both situations, the social relations worked hand in hand with job tasks (how task were allocated, and how returning workers were supported by others) and could make or break the return-to-work process. A suggestion for improvement of return-to-work models and policies is the need to take into account the social relations amongst workplace actors, especially involving co-workers when planning for return-to-work interventions. Otherwise the proper attention to work arrangements, social communication and the role of co-workers in the return-to-work process might not be seen.

It's A Gassy World: Middle School Students Investigate Climate Change

NASA Astrophysics Data System (ADS)

Romano, C.

2016-12-01

When middle school students are asked about our changing earth system, their responses likely include terms like global warming, climate change, and greenhouse gases. However, many students struggle to understand how it all fits together, and sometimes they hear conflicting information or myths about climate change. This activity allows students to explore the impacts of warming oceans and oceans' absorption of carbon dioxide (CO2) through a student planned and carried out investigation that begins with a pre-laboratory engagement and exploration piece, includes a laboratory component, and concludes with an explanation where students analyze their data and interpret their results through the claim-evidence-reasoning framework. It's a Gassy World was developed with three-dimensional instruction in mind to introduce middle school students to the relationship between warming oceans and changes in carbon dioxide (CO2) absorption in the oceans. Students explore disciplinary core ideas in the Earth and Space Sciences discipline of the Next Generation Science Standards (NGSS) using crosscutting concepts and science and engineering practices. Specifically, students study CO2 as a greenhouse gas and the effect of increased atmospheric CO2 levels on global climate change by planning and carrying out their own investigations. We structured this activity in a 5E format that can take place in four to five days during a climate change unit. After piloting this activity in over 20 formal classrooms and with 5 informal education groups, we have seen how It's a Gassy World helps support inquiry in the classroom and allows students to experience crosscutting concepts and science and engineering practices in NGSS. We found that students were engaged and actively learning throughout the activity. Student work and pilot teacher feedback indicated that, through this activity, many students increased their understanding of CO2 as a greenhouse gas and recognized that warmer oceans will absorb less CO2, resulting in more CO2 in the atmosphere.

ENHANCED PRACTICAL PHOTOSYNTHETIC CO2 MITIGATION

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dr. Gregory Kremer; Dr. David J. Bayless; Dr. Morgan Vis

2001-07-25

This quarterly report documents significant achievements in the Enhanced Practical Photosynthetic CO{sub 2} Mitigation project during the period from 4/03/2001 through 7/02/2001. Most of the achievements are milestones in our efforts to complete the tasks and subtasks that constitute the project objectives. Note that this version of the quarterly technical report is a revision to add the reports from subcontractors Montana State and Oak Ridge National Laboratories The significant accomplishments for this quarter include: Development of an experimental plan and initiation of experiments to create a calibration curve that correlates algal chlorophyll levels with carbon levels (to simplify future experimentalmore » procedures); Completion of debugging of the slug flow reactor system, and development of a plan for testing the pressure drop of the slug flow reactor; Design and development of a new bioreactor screen design which integrates the nutrient delivery drip system and the harvesting system; Development of an experimental setup for testing the new integrated drip system/harvesting system; Completion of model-scale bioreactor tests examining the effects of CO{sub 2} concentration levels and lighting levels on Nostoc 86-3 growth rates; Completion of the construction of a larger model-scale bioreactor to improve and expand testing capabilities and initiation of tests; Substantial progress on construction of a pilot-scale bioreactor; and Preliminary economic analysis of photobioreactor deployment. Plans for next quarter's work are included in the conclusions. A preliminary economic analysis is included as an appendix.« less

Public Works Department Maintenance Management Information System

DTIC Science & Technology

1976-06-01

Associates, Inc., 1974. 2. Ansoff , Igor H. , Corporate Strategy , McGraw-Hill Book Co., 1965. 3. Anthony, Robert N. , Planning and Control Systems, A...hierarchy of information systems. Ansoff describes management decision-making in three categories as strategic, administrative and operating decisions [Re...involve the firm’s goals, objectives, diversification, product-mix, markets, and growth. Ansoff also notes these other differences: 76 (1) operating

A comparison of mail-service and retail community pharmacy claims in 5 prescription benefit plans.

PubMed

Clark, Bartholomew E; Siracuse, Mark V; Garis, Robert I

2009-06-01

Little evidence has been presented to date that would either support or refute a widely held belief that mail-service pharmacy utilization routinely produces savings in drug benefit costs for prescription benefit plan sponsors. To present a comparative analysis of mail-service and community pharmacy service drug benefit costs for 5 employer-sponsored prescription drug benefit plans. A cross-sectional comparison of 17,725 matched transaction pairs of community and mail-service prescriptions from a data set comprised 484,987 prescription claims from a convenience sample of 5 employer-sponsored prescription benefit plans. Differences between community pharmacy and mail-service prescription transactions were examined at the per-unit level of analysis for drug ingredient costs, dispensing fees, co-payments, dollar amounts paid by plan sponsor, and total dollar amounts. Overall, the total cost of prescriptions was lower through mail-service pharmacies for all 5 plans studied. Two of 5 plans had co-payment incentives to use mail-service, yet plan sponsors paid more for mail-service drugs; respectively, 4.5% and 8.3% more overall, 25.0% and 21.4% more for generic medications; and 3.0% and 7.0% more for brand name medications. Mail-service co-payments were 48.9% and 51.7% lower. Mail-service utilization rates were 15.2% and 31.5% of the total number of prescriptions dispensed in the period studied. Three of 5 plans had no co-payment incentive to use mail-service and paid less for mail-service drugs; respectively, 18.7%, 6.6%, and 15.7% less overall; 17.4%, 15.6%, and 7.9% less for generic medications; and 18.8%, 5.2%, and 16.6% less for brand name medications. Mail-service co-payments were 10.5% more, 5.2% less, and 1.8% more than community pharmacy co-payments, respectively. Mail-service utilization rates were 0.8%, 1.2%, and 4.4%. Co-payment incentives to use mail-service pharmacies instead of community pharmacies were associated with higher mail-service utilization rates and with higher costs to plan sponsors. Absence of a co-payment incentive to use mail-service pharmacies was associated with lower mail-service utilization rates and with lower costs to plan sponsors.

A Multi-touch Tool for Co-creation

NASA Astrophysics Data System (ADS)

Ludden, Geke D. S.; Broens, Tom

Multi-touch technology provides an attractive way for knowledge workers to collaborate. Co-creation is an important collaboration process in which collecting resources, creating results and distributing these results is essential. We propose a wall-based multi-touch system (called CoCreate) in which these steps are made easy due to the notion of connected private spaces and a shared co-create space. We present our ongoing work, expert evaluation of interaction scenarios and future plans.

Pascagoula Harbor, Mississippi. Feasibility Report on Improvement of the Federal Deep-Draft Navigation Channel. Volume 2. Technical Appendices. Revision.

DTIC Science & Technology

1985-03-01

about half the time as the pipeline work, it would be logical for that work to begin about the middle of the period so all construction would finish ...d co)uld 𔃾’ -I to -rilch a plan i t c t C , . vy -;i- .: i m ’i, end o Iit coton . -p m -w 1u d ’if n;i ii 1 1in, ne, f e eco an .. i gil im 7" i

Co-creating Emotionally Safe Environments at Camp: Training Staff To Facilitate Adventure Activities.

ERIC Educational Resources Information Center

Brownlee, Matt; Yerkes, Rita

2003-01-01

An emotionally safe environment helps campers participate in adventure activities. Staff development tips for creating a safe environment include using cooperative goal setting; using parallel training processes; developing working lesson plans that outline facilitation techniques for creating emotionally safe environments; and using co-created…

Role of income in intergenerational co-residence: Evidence from selected African and Asian countries.

PubMed

Aziz, Nusrate; Hossain, Belayet; Emran, Masum

2018-06-01

The study investigates the macroeconomic determinants of co-residing arrangement between generations in selected developing countries with a focus on examining the effect of changing income level of the working generation. A reduced form model is specified for co-residence between the older generation and altruistic working generation. The fixed- and random-effects models are applied in two waves of data for 22 countries. Estimated results indicate that the income of the altruistic working generation has a negative effect on co-residence, suggesting that if the income of the working generation increases, co-residence decreases. This decrease is greater for older men compared with their female counterparts. Life expectancy, literacy and culture also have significant influences on co-residence. Co-residence is expected to fall in developing countries with economic growth over time. Consequently, a higher proportion of older citizens will be vulnerable in the future. Hence, governments of developing countries will face increasing pressure from their older people to provide appropriate planning and strategy to face this challenge. © 2018 AJA Inc.

Quantifying the benefit of wellbore leakage potential estimates for prioritizing long-term MVA well sampling at a CO2 storage site.

PubMed

Azzolina, Nicholas A; Small, Mitchell J; Nakles, David V; Glazewski, Kyle A; Peck, Wesley D; Gorecki, Charles D; Bromhal, Grant S; Dilmore, Robert M

2015-01-20

This work uses probabilistic methods to simulate a hypothetical geologic CO2 storage site in a depleted oil and gas field, where the large number of legacy wells would make it cost-prohibitive to sample all wells for all measurements as part of the postinjection site care. Deep well leakage potential scores were assigned to the wells using a random subsample of 100 wells from a detailed study of 826 legacy wells that penetrate the basal Cambrian formation on the U.S. side of the U.S./Canadian border. Analytical solutions and Monte Carlo simulations were used to quantify the statistical power of selecting a leaking well. Power curves were developed as a function of (1) the number of leaking wells within the Area of Review; (2) the sampling design (random or judgmental, choosing first the wells with the highest deep leakage potential scores); (3) the number of wells included in the monitoring sampling plan; and (4) the relationship between a well’s leakage potential score and its relative probability of leakage. Cases where the deep well leakage potential scores are fully or partially informative of the relative leakage probability are compared to a noninformative base case in which leakage is equiprobable across all wells in the Area of Review. The results show that accurate prior knowledge about the probability of well leakage adds measurable value to the ability to detect a leaking well during the monitoring program, and that the loss in detection ability due to imperfect knowledge of the leakage probability can be quantified. This work underscores the importance of a data-driven, risk-based monitoring program that incorporates uncertainty quantification into long-term monitoring sampling plans at geologic CO2 storage sites.

Application of Strategic Planning Process with Fleet Level Analysis Methods

NASA Technical Reports Server (NTRS)

Mavris, Dimitri N.; Pfaender, Holger; Jimenez, Hernando; Garcia, Elena; Feron, Eric; Bernardo, Jose

2016-01-01

The goal of this work is to quantify and characterize the potential system-wide reduction of fuel consumption and corresponding CO2 emissions, resulting from the introduction of N+2 aircraft technologies and concepts into the fleet. Although NASA goals for this timeframe are referenced against a large twin aisle aircraft we consider their application across all vehicle classes of the commercial aircraft fleet, from regional jets to very large aircraft. In this work the authors describe and discuss the formulation and implementation of the fleet assessment by addressing the main analytical components: forecasting, operations allocation, fleet retirement, fleet replacement, and environmental performance modeling.

Regression and statistical shape model based substitute CT generation for MRI alone external beam radiation therapy from standard clinical MRI sequences.

PubMed

Ghose, Soumya; Greer, Peter B; Sun, Jidi; Pichler, Peter; Rivest-Henault, David; Mitra, Jhimli; Richardson, Haylea; Wratten, Chris; Martin, Jarad; Arm, Jameen; Best, Leah; Dowling, Jason A

2017-10-27

In MR only radiation therapy planning, generation of the tissue specific HU map directly from the MRI would eliminate the need of CT image acquisition and may improve radiation therapy planning. The aim of this work is to generate and validate substitute CT (sCT) scans generated from standard T2 weighted MR pelvic scans in prostate radiation therapy dose planning. A Siemens Skyra 3T MRI scanner with laser bridge, flat couch and pelvic coil mounts was used to scan 39 patients scheduled for external beam radiation therapy for localized prostate cancer. For sCT generation a whole pelvis MRI (1.6 mm 3D isotropic T2w SPACE sequence) was acquired. Patients received a routine planning CT scan. Co-registered whole pelvis CT and T2w MRI pairs were used as training images. Advanced tissue specific non-linear regression models to predict HU for the fat, muscle, bladder and air were created from co-registered CT-MRI image pairs. On a test case T2w MRI, the bones and bladder were automatically segmented using a novel statistical shape and appearance model, while other soft tissues were separated using an Expectation-Maximization based clustering model. The CT bone in the training database that was most 'similar' to the segmented bone was then transformed with deformable registration to create the sCT component of the test case T2w MRI bone tissue. Predictions for the bone, air and soft tissue from the separate regression models were successively combined to generate a whole pelvis sCT. The change in monitor units between the sCT-based plans relative to the gold standard CT plan for the same IMRT dose plan was found to be [Formula: see text] (mean  ±  standard deviation) for 39 patients. The 3D Gamma pass rate was [Formula: see text] (2 mm/2%). The novel hybrid model is computationally efficient, generating an sCT in 20 min from standard T2w images for prostate cancer radiation therapy dose planning and DRR generation.

Regression and statistical shape model based substitute CT generation for MRI alone external beam radiation therapy from standard clinical MRI sequences

NASA Astrophysics Data System (ADS)

Ghose, Soumya; Greer, Peter B.; Sun, Jidi; Pichler, Peter; Rivest-Henault, David; Mitra, Jhimli; Richardson, Haylea; Wratten, Chris; Martin, Jarad; Arm, Jameen; Best, Leah; Dowling, Jason A.

2017-11-01

In MR only radiation therapy planning, generation of the tissue specific HU map directly from the MRI would eliminate the need of CT image acquisition and may improve radiation therapy planning. The aim of this work is to generate and validate substitute CT (sCT) scans generated from standard T2 weighted MR pelvic scans in prostate radiation therapy dose planning. A Siemens Skyra 3T MRI scanner with laser bridge, flat couch and pelvic coil mounts was used to scan 39 patients scheduled for external beam radiation therapy for localized prostate cancer. For sCT generation a whole pelvis MRI (1.6 mm 3D isotropic T2w SPACE sequence) was acquired. Patients received a routine planning CT scan. Co-registered whole pelvis CT and T2w MRI pairs were used as training images. Advanced tissue specific non-linear regression models to predict HU for the fat, muscle, bladder and air were created from co-registered CT-MRI image pairs. On a test case T2w MRI, the bones and bladder were automatically segmented using a novel statistical shape and appearance model, while other soft tissues were separated using an Expectation-Maximization based clustering model. The CT bone in the training database that was most ‘similar’ to the segmented bone was then transformed with deformable registration to create the sCT component of the test case T2w MRI bone tissue. Predictions for the bone, air and soft tissue from the separate regression models were successively combined to generate a whole pelvis sCT. The change in monitor units between the sCT-based plans relative to the gold standard CT plan for the same IMRT dose plan was found to be 0.3%+/-0.9% (mean  ±  standard deviation) for 39 patients. The 3D Gamma pass rate was 99.8+/-0.00 (2 mm/2%). The novel hybrid model is computationally efficient, generating an sCT in 20 min from standard T2w images for prostate cancer radiation therapy dose planning and DRR generation.

Our Changing Planet: The U.S. Climate Change Science Program for Fiscal Year 2006

DTIC Science & Technology

2005-11-01

any remaining uncertainties for the Amazon region of South America.These results are expected to greatly reduce errors and uncertainties concerning...changing the concentration of atmospheric CO2 are fossil -fuel burning, deforestation, land-use change, and cement production.These processes have...the initial phases of work on the remaining products. Specific plans for enhanced decision-support resources include: – Developing decision-support

40 CFR 93.109 - Criteria and procedures for determining conformity of transportation plans, programs, and...

Code of Federal Regulations, 2011 CFR

2011-07-01

...) through (k) of this section explain when the budget, interim emissions, and hot-spot tests are required... § 93.115 Project from a conforming plan and TIP § 93.116 CO, PM10, and PM2.5 hot-spots. § 93.117 PM10... Currently conforming plan and TIP § 93.116 CO, PM10, and PM2.5 hot-spots. § 93.117 PM10 and PM2.5 control...

40 CFR 93.109 - Criteria and procedures for determining conformity of transportation plans, programs, and...

Code of Federal Regulations, 2010 CFR

2010-07-01

...) through (k) of this section explain when the budget, interim emissions, and hot-spot tests are required... § 93.115 Project from a conforming plan and TIP § 93.116 CO, PM10, and PM2.5 hot-spots. § 93.117 PM10... Currently conforming plan and TIP § 93.116 CO, PM10, and PM2.5 hot-spots. § 93.117 PM10 and PM2.5 control...

Integrated Geophysical Monitoring Program to Study Flood Performance and Incidental CO2 Storage Associated with a CO2 EOR Project in the Bell Creek Oil Field

NASA Astrophysics Data System (ADS)

Burnison, S. A.; Ditty, P.; Gorecki, C. D.; Hamling, J. A.; Steadman, E. N.; Harju, J. A.

2013-12-01

The Plains CO2 Reduction (PCOR) Partnership, led by the Energy & Environmental Research Center, is working with Denbury Onshore LLC to determine the effect of a large-scale injection of carbon dioxide (CO2) into a deep clastic reservoir for the purpose of simultaneous CO2 enhanced oil recovery (EOR) and to study incidental CO2 storage at the Bell Creek oil field located in southeastern Montana. This project will reduce CO2 emissions by more than 1 million tons a year while simultaneously recovering an anticipated 30 million barrels of incremental oil. The Bell Creek project provides a unique opportunity to use and evaluate a comprehensive suite of technologies for monitoring, verification, and accounting (MVA) of CO2 on a large-scale. The plan incorporates multiple geophysical technologies in the presence of complementary and sometimes overlapping data to create a comprehensive data set that will facilitate evaluation and comparison. The MVA plan has been divided into shallow and deep subsurface monitoring. The deep subsurface monitoring plan includes 4-D surface seismic, time-lapse 3-D vertical seismic profile (VSP) surveys incorporating a permanent borehole array, and baseline and subsequent carbon-oxygen logging and other well-based measurements. The goal is to track the movement of CO2 in the reservoir, evaluate the recovery/storage efficiency of the CO2 EOR program, identify fluid migration pathways, and determine the ultimate fate of injected CO2. CO2 injection at Bell Creek began in late May 2013. Prior to injection, a monitoring and characterization well near the field center was drilled and outfitted with a distributed temperature-monitoring system and three down-hole pressure gauges to provide continuous real-time data of the reservoir and overlying strata. The monitoring well allows on-demand access for time-lapse well-based measurements and borehole seismic instrumentation. A 50-level permanent borehole array of 3-component geophones was installed in a second monitoring well. A pre-injection series of carbon-oxygen logging across the reservoir was acquired in 35 wells. The baseline 3-D surface seismic survey was acquired in September 2012. A 3-D VSP incorporating two wells and 2 square miles of overlapping seismic coverage in the middle of the field was acquired in May 2013. Initial iterations of geologic modeling and reservoir simulation of the field have been completed. Currently, passive seismic monitoring with the permanent borehole array is being conducted during injection. Interpretation results from the baseline surface 3-D survey and preliminary results from the baseline 3-D VSP are being evaluated and integrated into the reservoir model. The PCOR Partnership's philosophy is to combine site characterization, modeling, and monitoring strategies into an iterative process to produce descriptive integrated results. The comprehensive effort at Bell Creek will allow a comparison of the effectiveness of several complementary geophysical and well-based methods in meeting the goals of the deep subsurface monitoring effort.

Railroad Redevelopment Planning.

DTIC Science & Technology

1981-01-01

TEST CHART4A IONAL BUREAU’ Of STANDARDS- 1963-A -- m-ma REDQEVELcOPMENT PLANNIING *p W44 it -- 8 UNVRSITY OF C@O RAOO AT GENVER Tis docmr bpf Cr)o~d...officials began work on a set of guidelines in order to have some form of planned development u versus a piecemeal approach. According to a city...place. The city worked closely with various developers and their architects on the guidelines and the resulting ordinance was generally acceptable to

Soil respiration contributes substantially to urban carbon fluxes in the greater Boston area.

PubMed

Decina, Stephen M; Hutyra, Lucy R; Gately, Conor K; Getson, Jackie M; Reinmann, Andrew B; Short Gianotti, Anne G; Templer, Pamela H

2016-05-01

Urban areas are the dominant source of U.S. fossil fuel carbon dioxide (FFCO2) emissions. In the absence of binding international treaties or decisive U.S. federal policy for greenhouse gas regulation, cities have also become leaders in greenhouse gas reduction efforts through climate action plans. These plans focus on anthropogenic carbon flows only, however, ignoring a potentially substantial contribution to atmospheric carbon dioxide (CO2) concentrations from biological respiration. Our aim was to measure the contribution of CO2 efflux from soil respiration to atmospheric CO2 fluxes using an automated CO2 efflux system and to use these measurements to model urban soil CO2 efflux across an urban area. We find that growing season soil respiration is dramatically enhanced in urban areas and represents levels of CO2 efflux of up to 72% of FFCO2 within greater Boston's residential areas, and that soils in urban forests, lawns, and landscaped cover types emit 2.62 ± 0.15, 4.49 ± 0.14, and 6.73 ± 0.26 μmolCO2 m(-2) s(-1), respectively, during the growing season. These rates represent up to 2.2 times greater soil respiration than rates found in nearby rural ecosystems in central Massachusetts (MA), a potential consequence of imported carbon amendments, such as mulch, within a general regime of landowner management. As the scientific community moves rapidly towards monitoring, reporting, and verification of CO2 emissions using ground based approaches and remotely-sensed observations to measure CO2 concentrations, our results show that measurement and modeling of biogenic urban CO2 fluxes will be a critical component for verification of urban climate action plans. Copyright © 2016 Elsevier Ltd. All rights reserved.

Challenges in Evaluating Relationships Between Quantitative Data (Carbon Dioxide) and Qualitative Data (Self-Reported Visual Changes)

NASA Technical Reports Server (NTRS)

Mendez, C. M.; Foy, M.; Mason, S.; Wear, M. L.; Meyers, V.; Law, J.; Alexander, D.; Van Baalen, M.

2014-01-01

Understanding the nuances in clinical data is critical in developing a successful data analysis plan. Carbon dioxide (CO2) data are collected on board the International Space Station (ISS) in a continuous stream. Clinical data on ISS are primarily collected via conversations between individual crewmembers and NASA Flight Surgeons during weekly Private Medical Conferences (PMC). Law, et.al, 20141 demonstrated a statistically significant association between weekly average CO2 levels on ISS and self-reported headaches over the reporting period from March 14, 2001 to May 31, 2012. The purpose of this analysis is to describe the evaluation of a possible association between visual changes and CO2 levels on ISS and to discuss challenges in developing an appropriate analysis plan. METHODS & PRELIMINARY RESULTS: A first analysis was conducted following the same study design as the published work on CO2 and self-reported headaches1; substituting self-reported changes in visual acuity in place of self-reported headaches. The analysis demonstrated no statistically significant association between visual impairment characterized by vision symptoms self-reported during PMCs and ISS average CO2 levels over ISS missions. Closer review of the PMC records showed that vision outcomes are not well-documented in terms of clinical severity, timing of onset, or timing of resolution, perhaps due to the incipient nature of vision changes. Vision has been monitored in ISS crewmembers, pre- and post-flight, using standard optometry evaluations. In-flight visual assessments were limited early in the ISS program, primarily consisting of self-perceived changes reported by crewmembers. Recently, on-orbit capabilities have greatly improved. Vision data ranges from self-reported post-flight changes in visual acuity, pre- to postflight changes identified during fundoscopic examination, and in-flight progression measured by advanced on-orbit clinical imaging capabilities at predetermined testing intervals. In contrast, CO2 data are recorded in a continuous stream over time; however, for the initial analysis this data was categorized into weekly averages.

Carbon Capture and Sequestration from a Hydrogen Production Facility in an Oil Refinery

DOE Office of Scientific and Technical Information (OSTI.GOV)

Engels, Cheryl; Williams, Bryan, Valluri, Kiranmal; Watwe, Ramchandra

2010-06-21

The project proposed a commercial demonstration of advanced technologies that would capture and sequester CO2 emissions from an existing hydrogen production facility in an oil refinery into underground formations in combination with Enhanced Oil Recovery (EOR). The project is led by Praxair, Inc., with other project participants: BP Products North America Inc., Denbury Onshore, LLC (Denbury), and Gulf Coast Carbon Center (GCCC) at the Bureau of Economic Geology of The University of Texas at Austin. The project is located at the BP Refinery at Texas City, Texas. Praxair owns and operates a large hydrogen production facility within the refinery. Asmore » part of the project, Praxair would construct a CO2 capture and compression facility. The project aimed at demonstrating a novel vacuum pressure swing adsorption (VPSA) based technology to remove CO2 from the Steam Methane Reformers (SMR) process gas. The captured CO2 would be purified using refrigerated partial condensation separation (i.e., cold box). Denbury would purchase the CO2 from the project and inject the CO2 as part of its independent commercial EOR projects. The Gulf Coast Carbon Center at the Bureau of Economic Geology, a unit of University of Texas at Austin, would manage the research monitoring, verification and accounting (MVA) project for the sequestered CO2, in conjunction with Denbury. The sequestration and associated MVA activities would be carried out in the Hastings field at Brazoria County, TX. The project would exceed DOE?s target of capturing one million tons of CO2 per year (MTPY) by 2015. Phase 1 of the project (Project Definition) is being completed. The key objective of Phase 1 is to define the project in sufficient detail to enable an economic decision with regard to proceeding with Phase 2. This topical report summarizes the administrative, programmatic and technical accomplishments completed in Phase 1 of the project. It describes the work relative to project technical and design activities (associated with CO2 capture technologies and geologic sequestration MVA), and Environmental Information Volume. Specific accomplishments of this Phase include: 1. Finalization of the Project Management Plan 2. Development of engineering designs in sufficient detail for defining project performance and costs 3. Preparation of Environmental Information Volume 4. Completion of Hazard Identification Studies 5. Completion of control cost estimates and preparation of business plan During the Phase 1 detailed cost estimate, project costs increased substantially from the previous estimate. Furthermore, the detailed risk assessment identified integration risks associated with potentially impacting the steam methane reformer operation. While the Phase 1 work identified ways to mitigate these integration risks satisfactorily from an operational perspective, the associated costs and potential schedule impacts contributed to the decision not to proceed to Phase 2. We have concluded that the project costs and integration risks at Texas City are not commensurate with the potential benefits of the project at this time.« less

IMBER (Integrated Marine Biogeochemistry and Ecosystem Research: Support of Ocean Carbon Research

NASA Astrophysics Data System (ADS)

Rimetz-Planchon, J.; Gattuso, J.; Maddison, L.; Bakker, D. C.; Gruber, N.

2011-12-01

IMBER (Integrated Marine Biogeochemistry and Ecosystem Research), co-sponsored by SCOR (Scientific Committee on Oceanic Research) and IGBP (International Geosphere-Biosphere Programme), coordinates research that focuses on understanding and predicting changes in oceanic food webs and biogeochemical cycles that arise from global change. An integral part of this overall goal is to understand the marine carbon cycle, with emphasis on changes that may occur as a result of a changing climate, increased atmospheric CO2 levels and/or reduced oceanic pH. To address these key ocean carbon issues, IMBER and SOLAS (Surface Ocean Lower Atmosphere Study), formed the joint SOLAS-IMBER Carbon, or SIC Working Group. The SIC Working Group activities are organised into three sub-groups. Sub-group 1 (Surface Ocean Systems) focuses on synthesis, instrumentation and technology development, VOS (Voluntary Observing Ships) and mixed layer sampling strategies. The group contributed to the development of SOCAT (Surface Ocean CO2 Atlas, www.socat.info), a global compilation of underway surface water fCO2 (fugacity of CO2) data in common format. It includes 6.3 million measurements from 1767 cruises from 1968 and 2008 by more than 10 countries. SOCAT will be publically available and will serve a wide range of user communities. Its public release is planned for September 2011. SOCAT is strongly supported by IOCCP and CARBOOCEAN. Sub-group 2 (Interior Ocean Carbon Storage) covers inventory and observations, natural variability, transformation and interaction with modelling. It coordinated a review of vulnerabilities of the decadal variations of the interior ocean carbon and oxygen cycle. It has also developed a plan to add dissolved oxygen sensors to the ARGO float program in order to address the expected loss of oxygen as a result of ocean warming. The group also focuses on the global synthesis of ocean interior carbon observations to determine the oceanic uptake of anthropogenic CO2 since the mid 1990s. Sub-group 3 (SOLAS-IMBER Ocean Acidification or SIOA) coordinates international research efforts in ocean acidification and undertakes synthesis activities in ocean acidification at the international level. Several on-going synthesis activities, such as book projects and work by the Intergovernmental Panel on Climate Change (IPCC) are endorsed by this group. The SIOA developed a package of activities which it identified as critical to assess the effects of ocean acidification but are, for the most part, not funded at the national or regional levels and must be carried out at the international level. Among them is the promotion of international experiments, the sharing of experimental platforms, and the undertaking of inter-comparison exercises. The SIOA has submitted a proposal to launch an Ocean Acidification International Coordination Office in March 2011. This poster highlights some results from the SIC Working Group and indicates future challenges.

Analysis and Prospects of European Co-Operation in the Field of Regional Planning. Activity Report of the Committee of Senior Officials 1976-1978.

ERIC Educational Resources Information Center

Council of Europe, Strasbourg (France).

To guide future work, to provide an overall view of the program of technical cooperation in regional planning, and to form a basis for a Conference Ministerial Resolution, the report outlines the activities of the Committee of Senior Officials (CSO) of the Council of Europe's Conference of Ministers Responsible for Regional Planning during…

Breast Cancer Research Training Grant.

DTIC Science & Technology

1996-10-01

review the Program and its requirements and opportunities, and to answer questions and plan each student’s curriculum. Trainees are encouraged to...course requirements and plans to take the qualifying exmaination in summer, 1997. Yvette is an African- American. Laurie Hafer (BS, Microbiology...breast cancer research and plans to work with Dr. Fenton in studies of macrophage function. She was a co-author on Laurie Hafer’s poster at the AACR

Co-planning among science and special education teachers: How do different conceptual lenses help to make sense of the process?

NASA Astrophysics Data System (ADS)

Swanson, Lauren H.; Bianchini, Julie A.

2015-12-01

In this study, we investigated the process of teacher co-planning. We examined two teams of high school science and special education teachers brought together to co-plan inclusive, inquiry-oriented science units as part of a professional development effort. We used three conceptual lenses to help make sense of this process: (1) characteristics of collaboration, (2) small group interactions, and (3) community discourse. Using these lenses individually and collectively, we identified strengths and limitations in teachers' co-planning efforts. A strength was that all teachers, irrespective of discipline, shared ideas and helped make decisions about the content and activities included in unit and lesson plans. A limitation was that teachers, again irrespective of discipline, discussed science education topics in their teams more often than special education ones. We found this latter finding of note as it spoke to issues of parity among teachers during the professional development. In our discussion, we argue that each conceptual lens yielded both unique and common findings on co-planning. We also provide recommendations for professional developers and educational scholars intent on organizing and/or researching co-planning among science and special education teachers.

Uncertainty Quantification and Risk Mitigation of CO2 Leakage in Groundwater Aquifers

NASA Astrophysics Data System (ADS)

Sun, Y.; Tong, C.; Mansoor, K.; Carroll, S.

2013-12-01

The risk of CO2 leakage into shallow aquifers through various pathways such as faults and abandoned wells is a concern of CO2 geological sequestration. If a leak is detected in an aquifer system, a contingency plan is required to manage the CO2 storage and to protect the groundwater source. Among many remediation and mitigation strategies, the simplest is to stop CO2 leakage at a wellbore. Therefore, it is necessary to address whether and when the CO2 leaks should be sealed, and how much risk can be mitigated. In the presence of various uncertainties, including geological-structure uncertainty and parametric uncertainty, the risk of CO2 leakage into an aquifer needs to be assessed with probabilistic distributions of uncertain parameters. In this study, we developed an integrated model to simulate multiphase flow of CO2 and brine in a deep storage reservoir, through a leaky well at an uncertain location, and subsequently multicomponent reactive transport in a shallow aquifer. Each sub-model covers its domain-specific physics. Uncertainties of geological structure and parameters are considered together with decision variables (CO2 injection rate and mitigation time) for risk assessment of leakage-impacted aquifer volume. High-resolution and less-expensive reduced-order models (ROMs) of risk profiles are approximated as polynomial functions of decision variables and all uncertain parameters. These reduced-order models are then used in the place of computationally-expensive numerical models for future decision-making on if and when the leaky well is sealed. The tradeoff between CO2 storage capacity in the reservoir and the leakage-induced risk in the aquifer is evaluated. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under contract DE-AC52-07NA27344.

A New Method for Breath Capture Inside a Space Suit Helmet

NASA Technical Reports Server (NTRS)

Filburn, Tom; Dolder, Craig; Tufano, Brett; Paul, Heather L.

2007-01-01

This project investigates methods to capture an astronaut's exhaled carbon dioxide (CO2) before it becomes diluted with the high volumetric oxygen flow present within a space suit. Typical expired breath contains CO2 partial pressures (pCO2) in the range of 20-35 mm Hg. This research investigates methods to capture the concentrated CO2 gas stream prior to its dilution with the low pCO2 ventilation flow. Specifically this research is looking at potential designs for a collection cup for use inside the space suit helmet. The collection cup concept is not the same as a breathing mask typical of that worn by firefighters and pilots. It is well known that most members of the astronaut corps view a mask as a serious deficiency in any space suit helmet design. Instead, the collection cup is a non-contact device that will be designed using a detailed Computational Fluid Dynamic (CFD) analysis of the ventilation flow environment within the helmet. The CFD code, Fluent, provides modeling of the various gas species (CO2, water vapor, and oxygen (O2)) as they pass through a helmet. This same model will be used to numerically evaluate several different collection cup designs for this same CO2 segregation effort. A new test rig will be built to test the results of the CFD analyses and validate the collection cup designs. This paper outlines the initial results and future plans of this work.

CO2 Mitigation Measures of Power Sector and Its Integrated Optimization in China

PubMed Central

Dai, Pan; Chen, Guang; Zhou, Hao; Su, Meirong; Bao, Haixia

2012-01-01

Power sector is responsible for about 40% of the total CO2 emissions in the world and plays a leading role in climate change mitigation. In this study, measures that lower CO2 emissions from the supply side, demand side, and power grid are discussed, based on which, an integrated optimization model of CO2 mitigation (IOCM) is proposed. Virtual energy, referring to energy saving capacity in both demand side and the power grid, together with conventional energy in supply side, is unified planning for IOCM. Consequently, the optimal plan of energy distribution, considering both economic benefits and mitigation benefits, is figured out through the application of IOCM. The results indicate that development of demand side management (DSM) and smart grid can make great contributions to CO2 mitigation of power sector in China by reducing the CO2 emissions by 10.02% and 12.59%, respectively, in 2015, and in 2020. PMID:23213305

76 FR 9281 - Approval and Promulgation of Air Quality Implementation Plans; Massachusetts; Revised Carbon...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-02-17

... Massachusetts. This SIP submittal contains revisions to the carbon monoxide (CO) maintenance plan for Lowell... plan. The intended effect of this action is to propose approval of this revision to the Lowell CO..., 5 Post Office Square--Suite 100, (Mail code OEP05-2), Boston, MA 02109-3912. 5. Hand Delivery or...

78 FR 23524 - Approval and Promulgation of Implementation Plans; North Carolina: Deferral of Carbon Dioxide (CO2

Federal Register 2010, 2011, 2012, 2013, 2014

2013-04-19

... treatment, or manure management processes; CO 2 from fermentation during ethanol production or other industrial fermentation processes; CO 2 from combustion of the biological fraction of municipal solid waste...

Knowledge Co-production at the Research-Practice Interface: Embedded Case Studies from Urban Forestry

Treesearch

Lindsay K. Campbell; Erika S. Svendsen; Lara A. Roman

2016-01-01

Cities are increasingly engaging in sustainability efforts and investment in green infrastructure, including large-scale urban tree planting campaigns. In this context, researchers and practitioners are working jointly to develop applicable knowledge for planning and managing the urban forest. This paper presents three case studies of knowledge co-production in the...

Self-government of complex reading and writing brains informed by cingulo-opercular network for adaptive control and working memory components for language learning.

PubMed

Richards, Todd L; Abbott, Robert D; Yagle, Kevin; Peterson, Dan; Raskind, Wendy; Berninger, Virginia W

2017-01-01

To understand mental self-government of the developing reading and writing brain, correlations of clustering coefficients on fMRI reading or writing tasks with BASC 2 Adaptivity ratings (time 1 only) or working memory components (time 1 before and time 2 after instruction previously shown to improve achievement and change magnitude of fMRI connectivity) were investigated in 39 students in grades 4 to 9 who varied along a continuum of reading and writing skills. A Philips 3T scanner measured connectivity during six leveled fMRI reading tasks (subword-letters and sounds, word-word-specific spellings or affixed words, syntax comprehension-with and without homonym foils or with and without affix foils, and text comprehension) and three fMRI writing tasks-writing next letter in alphabet, adding missing letter in word spelling, and planning for composing. The Brain Connectivity Toolbox generated clustering coefficients based on the cingulo-opercular (CO) network; after controlling for multiple comparisons and movement, significant fMRI connectivity clustering coefficients for CO were identified in 8 brain regions bilaterally (cingulate gyrus, superior frontal gyrus, middle frontal gyrus, inferior frontal gyrus, superior temporal gyrus, insula, cingulum-cingulate gyrus, and cingulum-hippocampus). BASC2 Parent Ratings for Adaptivity were correlated with CO clustering coefficients on three reading tasks (letter-sound, word affix judgments and sentence comprehension) and one writing task (writing next letter in alphabet). Before instruction, each behavioral working memory measure (phonology, orthography, morphology, and syntax coding, phonological and orthographic loops for integrating internal language and output codes, and supervisory focused and switching attention) correlated significantly with at least one CO clustering coefficient. After instruction, the patterning of correlations changed with new correlations emerging. Results show that the reading and writing brain's mental government, supported by both CO Adaptive Control and multiple working memory components, had changed in response to instruction during middle childhood/early adolescence.

An Archeological Overview and Management Plan for the Harry Diamond Laboratories, Adelphi, Maryland.

DTIC Science & Technology

1985-07-01

WORK ON HARRY DIAMOND LABORATORY- ADELPHI, MARYLAND A number of prehistoric and historic sites have been reported in the vicinity of HDLA. Attempts...AD-Rftl 054 AN ARCHEOLOGICAL OVERVIEW AND NANAGENENT PLAN FOR THE Sui HARRY DIAMOND LABORATORIES ADELPHI NARYLRNDCU) U NLRSIFEDENYIROSPHERE CO NEW...An Archeological Overview and Management Plan r ifor the Harry Diamond Laboratories - Adelphi, Maryland Under Contract CX4000-3-0018 with the National

Fiber-Based Laser Transmitter at 1.57 Micrometers for Remote Sensing of Atmospheric Carbon Dioxide from Satellites

NASA Technical Reports Server (NTRS)

Yu, Anthony W.; Abshire, James B.; Stephen, Mark A.; Chen, Jeffrey R.; Wu, Stewart; Gonzalez, Brayler; Han, Lawrence; Numata, Kenji; Allan, Graham R.; Hasselbrack, William;

Center Planning and Development Student Engineer

NASA Technical Reports Server (NTRS)

Jenkins, Kenneth T.

2013-01-01

This fall I was the Student Trainee (Engineering) Pathways Intern (co-op) at the Kennedy Space Center (KSC) in the Center Planning Development (CPD) Directorate. CPD works with commercial companies who are interested using KSCs unique capabilities in spaceflight, spacecraft processing, ground systems and Research Development (RD) projects that fall in line with NASAs mission and goals. CPD is divided into four (4) groups: (1) AD-A, which works on the Master Planning for center, (2) AD-B (where I am), which works on project management and integration, (3) AD-C, which works on partnership development, and (4) AD-T, which works on the RD aspects of partnerships. CPDs main goal is to one day make KSC the worlds largest spaceport and maintain the center as a leader in space exploration. CPD is a very diverse group with employees having a wide knowledge of not only the Space Shuttle, but also that of the Apollo era. Our director of CPD, Scott Colloredo, is on the advisory board for Commercial Space Operations (CSO) and has a degree at ERAU. I worked on a number of different tasks for AD-B, as well as CPD, that includes, but not limited to: reviewing and reissuing engineering drawings from the Apollo and Shuttle eras, to supporting NASA rocket launches (MAVEN), and working on actual agreementsproposals that will be used in the partnership process with multiple partners. Most of the work I have done is sensitive information and cannot be disclosed.

Building Low Carbon Cities: Framework to Design and Evaluate Alternative Technologies and Policies for Land Use Planning

NASA Astrophysics Data System (ADS)

Hashimoto, S.; Hamano, H.; Fujita, T.; Hori, H.

2008-12-01

Annex I parties of the Kyoto Protocol are facing even greater pressures to fulfill their commitment for GHG reduction as they enter the first commitment period of the Kyoto Protocol 2008-2012. In Japanese context, one such challenge is to reduce CO2 emissions from the household and business sectors because CO2 emissions from the both sectors has increased by 12% and 20% respectively since 1990 while the industry has achieved 21% of CO2 emissions reduction. Land use planning, which, either directly or indirectly, controls appropriate uses for land within jurisdictions, might play very important roles to deal with CO2 reductions from the household and business sectors. In this research, aiming at effective reductions of air- conditioning energy consumption and resultant CO2 emissions from the household and business sectors, the framework to design and evaluate land use planning was developed. The design and evaluation processes embraced in this framework consist of GIS database, technology and policy inventory for planning, one- dimensional urban canopy model which evaluate urban climate at neighborhood level and air-conditioning load calculation procedure. The GIS database provides spatial information of target areas such as land use, building use and road networks, which, then, helps design alternative land use plans. The technology and policy inventory includes various planning options ranging from those for land over control to those for building energy control, which, combined with the GIS database, serves for planning process. The urban canopy model derives vertical profiles of local climate, such as temperature and humidity, using the information of land use, building height and so on, aided by the GIS database. Vertical profiles of the urban climate are then utilized to derive air-conditioning load and associated CO2 emissions for each building located in target areas. The framework developed was applied to the coastal district of Kawasaki, Japan, with an area of 40 square kilometers, for August 2006, to explore effective combinations of technologies and policies for land use planning. Six alternative land use policies were designed, including BaU in which current land use continues, and were, then, evaluated to seek more effective alternatives. Our findings suggested that about 541 MWh power and 204 tons of CO2 emission be saved at maximum by greening building sites, introducing water retentive pavement and installing energy-saving technologies for buildings in an appropriate manner.

15. Site plan, 1915, bottom half With CT214, photocopied from ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

15. Site plan, 1915, bottom half With CT-2-14, photocopied from an ozalid print, 'Map of Plant of Sentinel Manufacturing Co.,' Folio 2, EWC. The Sentinel Manufacturing Co. produced gas stoves. They leased the Whitney Armory buildings about 1915. - Eli Whitney Armory, West of Whitney Avenue, Armory Street Vicinity, Hamden, New Haven County, CT

75 FR 75059 - Mandatory Reporting of Greenhouse Gases: Injection and Geologic Sequestration of Carbon Dioxide

Federal Register 2010, 2011, 2012, 2013, 2014

2010-12-01

... monitoring will achieve detection and quantification of CO 2 in the event surface leakage occurs. The UIC... leakage detection monitoring system or technical specifications should also be described in the MRV plan... of injected CO 2 or from another cause (e.g. natural variability). The MRV plan leakage detection and...

Light Armored Reconnaissance: Misunderstood and Underemployed in Deep Operations

DTIC Science & Technology

2010-04-01

then CoB 2na LA! Bn deploys in support of Operation NIMROD DANCER in Panama Dec 1989 Co D, 2d LA! Bn deploys in support of Operation JUST CAUSE in...Marine Corns Long- Range Plan (MLRP) and U.S. Marine Corps Mid-Range Plan (MMRP). An analysis of the threat discussed in these documents reveals

Water Footprint and Water Consumption for the Main Crops and Biofuels Produced in Brazil

NASA Astrophysics Data System (ADS)

Sun, Y.; Tong, C.; Mansoor, K.; Carroll, S.

2011-12-01

The risk of CO2 leakage into shallow aquifers through various pathways such as faults and abandoned wells is a concern of CO2 geological sequestration. If a leak is detected in an aquifer system, a contingency plan is required to manage the CO2 storage and to protect the groundwater source. Among many remediation and mitigation strategies, the simplest is to stop CO2 leakage at a wellbore. Therefore, it is necessary to address whether and when the CO2 leaks should be sealed, and how much risk can be mitigated. In the presence of various uncertainties, including geological-structure uncertainty and parametric uncertainty, the risk of CO2 leakage into an aquifer needs to be assessed with probabilistic distributions of uncertain parameters. In this study, we developed an integrated model to simulate multiphase flow of CO2 and brine in a deep storage reservoir, through a leaky well at an uncertain location, and subsequently multicomponent reactive transport in a shallow aquifer. Each sub-model covers its domain-specific physics. Uncertainties of geological structure and parameters are considered together with decision variables (CO2 injection rate and mitigation time) for risk assessment of leakage-impacted aquifer volume. High-resolution and less-expensive reduced-order models (ROMs) of risk profiles are approximated as polynomial functions of decision variables and all uncertain parameters. These reduced-order models are then used in the place of computationally-expensive numerical models for future decision-making on if and when the leaky well is sealed. The tradeoff between CO2 storage capacity in the reservoir and the leakage-induced risk in the aquifer is evaluated. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under contract DE-AC52-07NA27344.

Supercritical Carbon Dioxide Power Generation System Definition: Concept Definition and Capital Cost Estimate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stoddard, Larry; Galluzzo, Geoff; Andrew, Daniel

The Department of Energy’s (DOE’s) Office of Renewable Power (ORP) has been tasked to provide effective program management and strategic direction for all of the DOE’s Energy Efficiency & Renewable Energy’s (EERE’s) renewable power programs. The ORP’s efforts to accomplish this mission are aligned with national energy policies, DOE strategic planning, EERE’s strategic planning, Congressional appropriation, and stakeholder advice. ORP is supported by three renewable energy offices, of which one is the Solar Energy Technology Office (SETO) whose SunShot Initiative has a mission to accelerate research, development and large scale deployment of solar technologies in the United States. SETO hasmore » a goal of reducing the cost of Concentrating Solar Power (CSP) by 75 percent of 2010 costs by 2020 to reach parity with base-load energy rates, and 30 percent further reductions by 2030. The SunShot Initiative is promoting the implementation of high temperature CSP with thermal energy storage allowing generation during high demand hours. The SunShot Initiative has funded significant research and development work on component testing, with attention to high temperature molten salts, heliostats, receiver designs, and high efficiency high temperature supercritical CO 2 (sCO2) cycles. DOE retained Black & Veatch to support SETO’s SunShot Initiative for CSP solar power tower technology in the following areas: 1. Concept definition, including costs and schedule, of a flexible test facility to be used to test and prove components in part to support financing. 2. Concept definition, including costs and schedule, of an integrated high temperature molten salt (MS) facility with thermal energy storage and with a supercritical CO 2 cycle generating approximately 10MWe. 3. Concept definition, including costs and schedule, of an integrated high temperature falling particle facility with thermal energy storage and with a supercritical CO 2 cycle generating approximately 10MWe. This report addresses the concept definition of the sCO2 power generation system, a sub-set of items 2 and 3 above. Other reports address the balance of items 1 to 3 above as well as the MS/sCO2 integrated 10MWe facility, Item 2.« less

Hydrogeology of the vicinity of Homestake mine, South Dakota, USA

NASA Astrophysics Data System (ADS)

Murdoch, Larry C.; Germanovich, Leonid N.; Wang, Herb; Onstott, T. C.; Elsworth, Derek; Stetler, Larry; Boutt, David

2012-02-01

The former Homestake mine in South Dakota (USA) cuts fractured metamorphic rock over a region several km2 in plan, and plunges to the SE to a depth of 2.4 km. Numerical simulations of the development and dewatering of the mine workings are based on idealizing the mine-workings system as two overlapping continua, one representing the open drifts and the other representing the host rock with hydrologic properties that vary with effective stress. Equating macroscopic hydrologic properties with characteristics of deformable fractures allows the number of parameters to be reduced, and it provides a physically based justification for changes in properties with depth. The simulations explain important observations, including the co-existence of shallow and deep flow systems, the total dewatering flow rate, the spatial distribution of in-flow, and the magnitude of porosity in the mine workings. The analysis indicates that a deep flow system induced by ~125 years of mining is contained within a surface-truncated ellipsoid roughly 8 km by 4 km in plan view and 5.5 km deep with its long-axis aligned to the strike of the workings. Groundwater flow into the southern side of the workings is characterized by short travel times from the ground surface, whereas flow into the northern side and at depth consists of old water removed from storage.

A neural network-based exploratory learning and motor planning system for co-robots

PubMed Central

Galbraith, Byron V.; Guenther, Frank H.; Versace, Massimiliano

2015-01-01

Collaborative robots, or co-robots, are semi-autonomous robotic agents designed to work alongside humans in shared workspaces. To be effective, co-robots require the ability to respond and adapt to dynamic scenarios encountered in natural environments. One way to achieve this is through exploratory learning, or “learning by doing,” an unsupervised method in which co-robots are able to build an internal model for motor planning and coordination based on real-time sensory inputs. In this paper, we present an adaptive neural network-based system for co-robot control that employs exploratory learning to achieve the coordinated motor planning needed to navigate toward, reach for, and grasp distant objects. To validate this system we used the 11-degrees-of-freedom RoPro Calliope mobile robot. Through motor babbling of its wheels and arm, the Calliope learned how to relate visual and proprioceptive information to achieve hand-eye-body coordination. By continually evaluating sensory inputs and externally provided goal directives, the Calliope was then able to autonomously select the appropriate wheel and joint velocities needed to perform its assigned task, such as following a moving target or retrieving an indicated object. PMID:26257640

A neural network-based exploratory learning and motor planning system for co-robots.

PubMed

Galbraith, Byron V; Guenther, Frank H; Versace, Massimiliano

2015-01-01

Collaborative robots, or co-robots, are semi-autonomous robotic agents designed to work alongside humans in shared workspaces. To be effective, co-robots require the ability to respond and adapt to dynamic scenarios encountered in natural environments. One way to achieve this is through exploratory learning, or "learning by doing," an unsupervised method in which co-robots are able to build an internal model for motor planning and coordination based on real-time sensory inputs. In this paper, we present an adaptive neural network-based system for co-robot control that employs exploratory learning to achieve the coordinated motor planning needed to navigate toward, reach for, and grasp distant objects. To validate this system we used the 11-degrees-of-freedom RoPro Calliope mobile robot. Through motor babbling of its wheels and arm, the Calliope learned how to relate visual and proprioceptive information to achieve hand-eye-body coordination. By continually evaluating sensory inputs and externally provided goal directives, the Calliope was then able to autonomously select the appropriate wheel and joint velocities needed to perform its assigned task, such as following a moving target or retrieving an indicated object.

The effect of low ventilation rate with elevated bioeffluent concentration on work performance, perceived indoor air quality, and health symptoms.

PubMed

Maula, H; Hongisto, V; Naatula, V; Haapakangas, A; Koskela, H

2017-11-01

The aim of this laboratory experiment was to study the effects of ventilation rate, and related changes in air quality, predominantly bioeffluents, on work performance, perceived indoor air quality, and health symptoms in a typical conditions of modern open-plan office with low material and equipment emissions. In Condition A, outdoor air flow rate of 28.2 l/s person (CO 2 level 540 ppm) was applied and in Condition B, outdoor air flow rate was 2.3 l/s person (CO 2 level 2260 ppm). CO 2 concentration level was used as an indicator of bioeffluents. Performance was measured with seven different tasks which measure different cognitive processes. Thirty-six subjects participated in the experiment. The exposure time was 4 hours. Condition B had a weak negative effect on performance only in the information retrieval tasks. Condition B increased slightly subjective workload and perceived fatigue. No effects on health symptoms were found. The intensity of symptoms was low in both conditions. The experimental condition had an effect on perceived air quality and observed odor intensity only in the beginning of the session. Although the room temperature was controlled in both conditions, the heat was perceived to impair the performance more in Condition B. © 2017 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

“Don’t forget the migrants”: exploring preparedness and response strategies to combat the potential spread of MERS-CoV virus through migrant workers in Sri Lanka

PubMed Central

Agampodi, Suneth B

2013-01-01

From September 2012 to July 2013, 81 laboratory-confirmed cases of infection with Middle East respiratory syndrome coronavirus (MERS-CoV), including 45 deaths (a case fatality ratio of 55%) have been reported from eight countries. Human-to-human transmission is now confirmed showing potential for another pandemic of zoonotic disease, with an extremely high mortality rate. Effective surveillance strategies are required in countries with a high influx of migrants from the Middle East to mitigate the probable importation of MERS-CoV. We discuss here the risk of MERS-CoV in major labor sending countries and list the probable strategies for control and prevention of MERS-CoV using Sri Lanka as an example. It is conservatively estimated that 10% of Sri Lanka’s population work as international labor migrants (1.8 to 2 million workers), with 93% residing in the Middle East. An average of 720 workers depart each day, with the majority of these workers (71%) departing to the Kingdom of Saudi Arabia (the country with 81.5% of total MERS-CoV cases). We also describe other inbound migration categories such as tourists and resident visa holders relevant to the context of preparedness and planning. The importance of partnerships between public health authorities at national and regional levels with labor migration networks to establish institutional and/or policy mechanisms are highlighted for ensuring effective preparedness and response planning. Strategies that can be taken by public health authorities working in both labor sending and labor receiving counties are also described.  The strategies described here may be useful for other labor sending country contexts in Asia with a high frequency and volume of migrant workers to and from the Gulf region. PMID:24555078

Helicopter Surveys for Locating Wells and Leaking Oilfield Infrastructure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hammack, R.W.; Veloski, G.A.; Hodges, G.

2006-10-01

Prior to the injection of CO2 into geological formations, either for enhanced oil recovery or for CO2 sequestration, it is necessary to locate wells that perforate the target formation and are within the radius of influence for planned injection wells. Locating and plugging wells is necessary because improperly plugged well bores provide the most rapid route for CO2 escape to the surface. This paper describes the implementation and evaluation of helicopter and ground-based well detection strategies at a 100+ year old oilfield in Wyoming where a CO2 flood is planned. This project was jointly funded by the U.S. Department ofmore » Energy’s National Energy Technology Laboratory and Fugro Airborne Surveys« less

The Role of CO2 Clouds on the Stability of the Early Mars Atmosphere Against Collapse

NASA Astrophysics Data System (ADS)

Kahre, Melinda A.; Haberle, Robert; Steakley, Kathryn; Murphy, Jim; Kling, Alexandre

2017-10-01

The early Mars atmosphere was likely significantly more massive than it is today, given the growing body of evidence that liquid water flowed on the surface early in the planet’s history. Although the CO2 inventory was likely larger in the past, there is much we still do not understand about the state of that CO2. As surface pressure increases, the temperature at which CO2 condenses also increases, making it more likely that CO2 ice would form and persist on the surface when the atmospheric mass increases. An atmosphere that is stable against collapse must contain enough energy, distributed globally, to prohibit the formation of permanents CO2 ice reservoirs that lead to collapse. The presence of the “faint young sun” compounds this issue. Previous global climate model (GCM) investigations show that atmospheres within specific ranges of obliquities and atmospheric masses are stable against collapse. We use the NASA Ames Mars GCM to expand on these works by focusing specifically on the role of CO2 clouds in atmospheric stability. Two end member simulations are executed, one that includes CO2 cloud formation and one that does not. The simulation that explicitly includes CO2 clouds is stable, while the simulation without CO2 clouds collapses into permanent surface CO2 reservoirs. In both cases, significant atmospheric condensation is occurring in the atmosphere throughout the year. In the case without CO2 clouds, all atmospheric condensation (even if it occurs at altitude) leads directly to the accumulation of surface ice, whereas in the case with CO2 clouds, there is a finite settling timescale for the cloud particles. Depending on this timescale and the local conditions, the cloud particles could stay aloft or sublimate as they fall toward the surface. Thus, the striking difference between these two cases illustrates the important role of CO2 clouds. We plan to conduct and present further simulations to better understand how atmospheric stability depends on the details of CO2 cloud microphysical processes and assumptions.

[Company Wide Quality Control (total quality): methodological principles and intervention techniques for step-by-step improvement].

PubMed

Corbara, F; Di Cristofaro, E

1996-01-01

The concept of Quality is particularly up to date and not a new one for the Journal. The need for better Quality is a must also in Medical care. Quality doesn't mean additional costs and excessive burden for the co-workers. On the contrary, initial costs can be compensated for through a more rational utilisation of the resources. The consequent better service for the patient results in an ameliorated working environment, with high profits. Fundamental requirements for reaching concrete results are: 1) the convinced involvement in the idea of all levels (division, service, laboratory) in order to have the different groups act in synergism towards common goals; 2) the knowledge of appropriate methods. The Authors examine this last point with a deep analysis of the techniques involved in Company Wide Quality Control (C.W.Q.C.) or Total Quality. The improving process has to the continuous and proceed in small steps, each time being constituted by 4 different phases, represented by the PDCA cycle, or Demining wheel, where: P = PLAN, which means plan before acting; D = DO, perform what has been planned; C = CHECK, verify the results; A = ACT, standardize if the results are positive, repeat the process if negative. Each process of improvement implies a prior precise definition of a project, i.e. a problem whose solution has been planned. The project must always presume: a specific subject--a goal--one or more people to reach it--a limited time to work it out. The most effective way to ameliorate Quality is performing projects. Step by Step amelioration is synonymous of performance of many projects. A brilliant way to produce many projects remains their "industrialization", which can be reached by means of 6 basic criteria: 1) full involvement of the Direction; 2) potential co-working in the projects of all employees; 3) employment of simple instruments; 4) respect of a few procedural formalities; 5) rewarding of personnel; 6) continuous promotion of the concepts of quality and ongoing improvement. The Authors describe for each of the previous criteria approaching methods and best operative techniques, according C.W.Q.C.

Tally and geometry definition influence on the computing time in radiotherapy treatment planning with MCNP Monte Carlo code.

PubMed

Juste, B; Miro, R; Gallardo, S; Santos, A; Verdu, G

2006-01-01

The present work has simulated the photon and electron transport in a Theratron 780 (MDS Nordion) (60)Co radiotherapy unit, using the Monte Carlo transport code, MCNP (Monte Carlo N-Particle), version 5. In order to become computationally more efficient in view of taking part in the practical field of radiotherapy treatment planning, this work is focused mainly on the analysis of dose results and on the required computing time of different tallies applied in the model to speed up calculations.

Hydrogeologic Modeling for Monitoring, Reporting and Verification of Geologic Sequestration

NASA Astrophysics Data System (ADS)

Kolian, M.; De Figueiredo, M.; Lisa, B.

2011-12-01

In December 2010, EPA finalized Subpart RR of the Greenhouse Gas (GHG) Reporting Program, which requires facilities that conduct geologic sequestration (GS) of carbon dioxide (CO2) to report GHG data to EPA annually. The GHG Reporting Program requires reporting of GHGs and other relevant information from certain source categories in the United States, and information obtained through Subpart RR will inform Agency decisions under the Clean Air Act related to the use of carbon dioxide capture and sequestration for mitigating GHGs. This paper examines hydrogeologic modeling necessities and opportunities in the context of Subpart RR. Under Subpart RR, facilities that conduct GS by injecting CO2 for long-term containment in subsurface geologic formations are required to develop and implement an EPA-approved site-specific monitoring, reporting, and verification (MRV) plan; and report basic information on CO2 received for injection, annual monitoring activities and the amount of CO2 geologically sequestered using a mass balance approach. The major components of the MRV plan include: identification of potential surface leakage pathways for CO2 and the likelihood, magnitude, and timing, of surface leakage of CO2 through these pathways; delineation of the monitoring areas; strategy for detecting and quantifying any surface leakage of CO2; and the strategy for establishing the expected baselines for monitoring CO2 surface leakage. Hydrogeologic modeling is an integral aspect of the design of an MRV plan. In order to prepare an adequate monitoring program that addresses site specific risks over the full life of the project the MRV plan must reflect the full spatial extent of the free phase CO2 over time. Facilities delineate the maximum area that the CO2 plume is predicted to cover and how monitoring can be phased in over this area. The Maximum Monitoring Area (MMA) includes the extent of the free phase CO2 plume over the lifetime of the project plus a buffer zone of one-half mile. The Active Monitoring Area (AMA) is the area that will be monitored over a specified time interval chosen by the reporter, which must be greater than one year. All of the area in the MMA will eventually be covered by one or more AMAs. This allows operators to phase in monitoring so that during any given time interval, only that part of the MMA in which surface leakage might occur needs to be monitored. EPA designed the MRV plan approach to be site-specific, flexible, and adaptive to future technology developments. This approach allows the reporter to leverage the site characterization, modeling, and monitoring approaches (e.g. monitoring of injection pressures, injection well integrity, groundwater quality and geochemistry, and CO2 plume location, etc.) developed for their Underground Injection Control (UIC) permit. UIC requirements provide the foundation for the safe sequestration of CO2 by helping to ensure that injected fluids remain isolated in the subsurface and away from underground sources of drinking water, thereby serving to reduce the risk of CO2 leakage to the atmosphere.

Comparative evaluation of Kodak EDR2 and XV2 films for verification of intensity modulated radiation therapy.

PubMed

Dogan, Nesrin; Leybovich, Leonid B; Sethi, Anil

2002-11-21

Film dosimetry provides a convenient tool to determine dose distributions, especially for verification of IMRT plans. However, the film response to radiation shows a significant dependence on depth, energy and field size that compromise the accuracy of measurements. Kodak's XV2 film has a low saturation dose (approximately 100 cGy) and, consequently, a relatively short region of linear dose-response. The recently introduced Kodak extended range EDR2 film was reported to have a linear dose-response region extending to 500 cGy. This increased dose range may be particularly useful in the verification of IMRT plans. In this work, the dependence of Kodak EDR2 film's response on the depth, field size and energy was evaluated and compared with Kodak XV2 film. Co-60, 6 MV, 10 MV and 18 MV beams were used. Field sizes were 2 x 2, 6 x 6, 10 x 10, 14 x 14, 18 x 18 and 24 x 24 cm2. Doses for XV2 and EDR2 films were 80 cGy and 300 cGy, respectively. Optical density was converted to dose using depth-corrected sensitometric (Hurter and Driffield, or H&D) curves. For each field size, XV2 and EDR2 depth-dose curves were compared with ion chamber depth-dose curves. Both films demonstrated similar (within 1%) field size dependence. The deviation from the ion chamber for both films was small forthe fields ranging from 2 x 2 to 10 x 10 cm2: < or =2% for 6, 10 and 18 MV beams. No deviation was observed for the Co-60 beam. As the field size increased to 24 x 24 cm2, the deviation became significant for both films: approximately 7.5% for Co-60, approximately 5% for 6 MV and 10 MV, and approximately 6% for 18 MV. During the verification of IMRT plans, EDR2 film showed a better agreement with the calculated dose distributions than the XV2 film.

Analyzing the carbon cycle with the local ensemble transform Kalman filter, online transport model and real observation data

NASA Astrophysics Data System (ADS)

Maki, T.; Sekiyama, T. T.; Shibata, K.; Miyazaki, K.; Miyoshi, T.; Yamada, K.; Yokoo, Y.; Iwasaki, T.

2011-12-01

In the current carbon cycle analysis, inverse modeling plays an important role. However, it requires enormous computational resources when we deal with more flux regions and more observations. The local ensemble transform Kalman filter (LETKF) is an alternative approach to reduce such problems. We constructed a carbon cycle analysis system with the LETKF and MRI (Meteorological Research Institute) online transport model (MJ98-CDTM). In MJ98-CDTM, an off-line transport model (CDTM) is directly coupled with the MRI/JMA GCM (MJ98). We further improved vertical transport processes in MJ98-CDTM from previous study. The LETKF includes enhanced features such as smoother to assimilate future observations, adaptive inflation and bias correction scheme. In this study, we use CO2 observations of surface data (continuous and flask), aircraft data (CONTRAIL) and satellite data (GOSAT), although we plan to assimilate AIRS tropospheric CO2 data. We developed a quality control system. We estimated 3-day-mean CO2 flux at a resolution of T42. Here, only CO2 concentrations and fluxes are analyzed whereas meteorological fields are nudged by the Japanese reanalysis (JCDAS). The horizontal localization length scale and assimilation window are chosen to be 1000 km and 3 days, respectively. The results indicate that the assimilation system works properly, better than free transport model run when we validate with independent CO2 concentration observational data and CO2 analysis data.

Toward a Comprehensive Carbon Budget for North America: Potential Applications of Adjoint Methods with Diverse Datasets

NASA Technical Reports Server (NTRS)

Andrews, A.

2002-01-01

A detailed mechanistic understanding of the sources and sinks of CO2 will be required to reliably predict future COS levels and climate. A commonly used technique for deriving information about CO2 exchange with surface reservoirs is to solve an "inverse problem," where CO2 observations are used with an atmospheric transport model to find the optimal distribution of sources and sinks. Synthesis inversion methods are powerful tools for addressing this question, but the results are disturbingly sensitive to the details of the calculation. Studies done using different atmospheric transport models and combinations of surface station data have produced substantially different distributions of surface fluxes. Adjoint methods are now being developed that will more effectively incorporate diverse datasets in estimates of surface fluxes of CO2. In an adjoint framework, it will be possible to combine CO2 concentration data from long-term surface monitoring stations with data from intensive field campaigns and with proposed future satellite observations. A major advantage of the adjoint approach is that meteorological and surface data, as well as data for other atmospheric constituents and pollutants can be efficiently included in addition to observations of CO2 mixing ratios. This presentation will provide an overview of potentially useful datasets for carbon cycle research in general with an emphasis on planning for the North American Carbon Project. Areas of overlap with ongoing and proposed work on air quality/air pollution issues will be highlighted.

On the development of a methodology for extensive in-situ and continuous atmospheric CO2 monitoring

NASA Astrophysics Data System (ADS)

Wang, K.; Chang, S.; Jhang, T.

2010-12-01

Carbon dioxide is recognized as the dominating greenhouse gas contributing to anthropogenic global warming. Stringent controls on carbon dioxide emissions are viewed as necessary steps in controlling atmospheric carbon dioxide concentrations. From the view point of policy making, regulation of carbon dioxide emissions and its monitoring are keys to the success of stringent controls on carbon dioxide emissions. Especially, extensive atmospheric CO2 monitoring is a crucial step to ensure that CO2 emission control strategies are closely followed. In this work we develop a methodology that enables reliable and accurate in-situ and continuous atmospheric CO2 monitoring for policy making. The methodology comprises the use of gas filter correlation (GFC) instrument for in-situ CO2 monitoring, the use of CO2 working standards accompanying the continuous measurements, and the use of NOAA WMO CO2 standard gases for calibrating the working standards. The use of GFC instruments enables 1-second data sampling frequency with the interference of water vapor removed from added dryer. The CO2 measurements are conducted in the following timed and cycled manner: zero CO2 measurement, two standard CO2 gases measurements, and ambient air measurements. The standard CO2 gases are calibrated again NOAA WMO CO2 standards. The methodology is used in indoor CO2 measurements in a commercial office (about 120 people working inside), ambient CO2 measurements, and installed in a fleet of in-service commercial cargo ships for monitoring CO2 over global marine boundary layer. These measurements demonstrate our method is reliable, accurate, and traceable to NOAA WMO CO2 standards. The portability of the instrument and the working standards make the method readily applied for large-scale and extensive CO2 measurements.

Inclusive Smartphone Interface Design in Context: Co(Re)designing the PIS.

PubMed

Magee, Paul; Ward, Gillian; Moody, Louise; Roebuck, Annette

2017-01-01

User-context optimises smartphone interface-design. Neglect of user-context during development, delays or prevents marginalised-consumer benefit. Working with People with Learning Disability (PWLD) to develop interfaces refined by communication-need will improve User-Experience (UX). In research, a Participant Information Sheet (PIS) discloses planned study-activity. This paper explains co-creation of a PIS based on communication-need of PWLD.

Co-control of urban air pollutants and greenhouse gases in Mexico City.

PubMed

West, J Jason; Osnaya, Patricia; Laguna, Israel; Martínez, Julia; Fernández, Adrián

2004-07-01

This study addresses the synergies of mitigation measures to control urban air pollutant and greenhouse gas (GHG) emissions, in developing integrated "co-control" strategies for Mexico City. First, existing studies of emissions reduction measures--PROAIRE (the air quality plan for Mexico City) and separate GHG studies--are used to construct a harmonized database of options. Second, linear programming (LP) is developed and applied as a decision-support tool to analyze least-cost strategies for meeting co-control targets for multiple pollutants. We estimate that implementing PROAIRE measures as planned will reduce 3.1% of the 2010 metropolitan CO2 emissions, in addition to substantial local air pollutant reductions. Applying the LP, PROAIRE emissions reductions can be met at a 20% lower cost, using only the PROAIRE measures, by adjusting investments toward the more cost-effective measures; lower net costs are possible by including cost-saving GHG mitigation measures, but with increased investment. When CO2 emission reduction targets are added to PROAIRE targets, the most cost-effective solutions use PROAIRE measures for the majority of local pollutant reductions, and GHG measures for additional CO2 control. Because of synergies, the integrated planning of urban-global co-control can be beneficial, but we estimate that for Mexico City these benefits are often small.

Northern California CO 2 Reduction Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hymes, Edward

2010-06-16

C6 Resources LLC, a wholly owned subsidiary of Shell Oil Company, worked with the US Department of Energy (DOE) under a Cooperative Agreement to develop the Northern California CO 2 Reduction Project. The objective of the Project is to demonstrate the viability of using Carbon Capture and Sequestration (CCS) to reduce existing greenhouse gas emissions from industrial sources on a large-scale. The Project will capture more than 700,000 metric tonnes of CO 2 per year, which is currently being vented to the atmosphere from the Shell Martinez Refinery in Contra Costa County. The CO 2 will be compressed and dehydratedmore » at the refinery and then transported via pipeline to a sequestration site in a rural area in neighboring Solano County. The CO 2 will be sequestered into a deep saline formation (more than two miles underground) and will be monitored to assure secure, long-term containment. The pipeline will be designed to carry as much as 1,400,000 metric tonnes of CO 2 per year, so additional capacity will be available to accommodate CO 2 captured from other industrial sources. The Project is expected to begin operation in 2015. The Project has two distinct phases. The overall objective of Phase 1 was to develop a fully definitive design basis for the Project. The Cooperative Agreement with the DOE provided cost sharing for Phase 1 and the opportunity to apply for additional DOE cost sharing for Phase 2, comprising the design, construction and operation of the Project. Phase 1 has been completed. DOE co-funding is provided by the American Recovery and Reinvestment Act (ARRA) of 2009. As prescribed by ARRA, the Project will stimulate the local economy by creating manufacturing, transportation, construction, operations, and management jobs while addressing the need to reduce greenhouse gas emissions at an accelerated pace. The Project, which will also assist in meeting the CO 2 reduction requirements set forth in California's Climate Change law, presents a major opportunity for both the environment as well as the region. C6 Resources is conducting the Project in collaboration with federally-funded research centers, such as Lawrence Berkeley National Lab and Lawrence Livermore National Lab. C6 Resources and Shell have identified CCS as one of the critical pathways toward a worldwide goal of providing cleaner energy. C6 Resources, in conjunction with the West Coast Regional Carbon Sequestration Partnership (WESTCARB), has conducted an extensive and ongoing public outreach and CCS education program for local, regional and state-wide stakeholders. As part of a long term relationship, C6 Resources will continue to engage directly with community leaders and residents to ensure public input and transparency. This topical report summarizes the technical work from Phase 1 of the Project in the following areas; Surface Facility Preliminary Engineering: summarizes the preliminary engineering work performed for CO 2 capture, CO 2 compression and dehydration at the refinery, and surface facilities at the sequestration site; Pipeline Preliminary Engineering: summarizes the pipeline routing study and preliminary engineering design; Geologic Sequestration: summarizes the work to characterize, model and evaluate the sequestration site; and Monitoring, Verification and Accounting (MVA): summarizes the MVA plan to assure long-term containment of the sequestered CO 2.« less

Considerations of MCNP Monte Carlo code to be used as a radiotherapy treatment planning tool.

PubMed

Juste, B; Miro, R; Gallardo, S; Verdu, G; Santos, A

2005-01-01

The present work has simulated the photon and electron transport in a Theratron 780® (MDS Nordion)⁶⁰Co radiotherapy unit, using the Monte Carlo transport code, MCNP (Monte Carlo N-Particle). This project explains mainly the different methodologies carried out to speedup calculations in order to apply this code efficiently in radiotherapy treatment planning.

Interactive dose shaping part 2: proof of concept study for six prostate patients

NASA Astrophysics Data System (ADS)

Kamerling, Cornelis Ph; Ziegenhein, Peter; Sterzing, Florian; Oelfke, Uwe

2016-03-01

Recently we introduced interactive dose shaping (IDS) as a new IMRT planning strategy. This planning concept is based on a hierarchical sequence of local dose modification and recovery operations. The purpose of this work is to provide a feasibility study for the IDS planning strategy based on a small set of six prostate patients. The IDS planning paradigm aims to perform interactive local dose adaptations of an IMRT plan without compromising already established valuable dose features in real-time. Various IDS tools were developed in our in-house treatment planning software Dynaplan and were utilized to create IMRT treatment plans for six patients with an adeno-carcinoma of the prostate. The sequenced IDS treatment plans were compared to conventionally optimized clinically approved plans (9 beams, co-planar). For each patient, several IDS plans were created, with different trade-offs between organ sparing and target coverage. The reference dose distributions were imported into Dynaplan. For each patient, the IDS treatment plan with a similar or better trade-off between target coverage and OAR sparing was selected for plan evaluation, guided by a physician. For this initial study we were able to generate treatment plans for prostate geometries in 15-45 min. Individual local dose adaptations could be performed in less than one second. The average differences compared to the reference plans were for the mean dose: 0.0 Gy (boost) and 1.2 Gy (PTV), for {{D}98%}:-1.1 Gy and for {{D}2%}:1.1 Gy (both target volumes). The dose-volume quality indicators were well below the Quantec constraints. However, we also observed limitations of our currently implemented approach. Most prominent was an increase of the non-tumor integral dose by 16.4% on average, demonstrating that further developments of our planning strategy are required.

Evaluation of CO 2 -Fluid-Rock Interaction in Enhanced Geothermal Systems: Field-Scale Geochemical Simulations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pan, Feng; McPherson, Brian J.; Kaszuba, John

Recent studies suggest that using supercritical CO 2 (scCO 2 ) instead of water as a heat transmission fluid in Enhanced Geothermal Systems (EGS) may improve energy extraction. While CO 2 -fluid-rock interactions at “typical” temperatures and pressures of subsurface reservoirs are fairly well known, such understanding for the elevated conditions of EGS is relatively unresolved. Geochemical impacts of CO 2 as a working fluid (“CO 2 -EGS”) compared to those for water as a working fluid (H 2 O-EGS) are needed. The primary objectives of this study are (1) constraining geochemical processes associated with CO 2 -fluid-rock interactions undermore » the high pressures and temperatures of a typical CO 2 -EGS site and (2) comparing geochemical impacts of CO 2 -EGS to geochemical impacts of H 2 O-EGS. The St. John’s Dome CO 2 -EGS research site in Arizona was adopted as a case study. A 3D model of the site was developed. Net heat extraction and mass flow production rates for CO 2 -EGS were larger compared to H 2 O-EGS, suggesting that using scCO 2 as a working fluid may enhance EGS heat extraction. More aqueous CO 2 accumulates within upper- and lower-lying layers than in the injection/production layers, reducing pH values and leading to increased dissolution and precipitation of minerals in those upper and lower layers. Dissolution of oligoclase for water as a working fluid shows smaller magnitude in rates and different distributions in profile than those for scCO 2 as a working fluid. It indicates that geochemical processes of scCO 2 -rock interaction have significant effects on mineral dissolution and precipitation in magnitudes and distributions.« less

Evaluation of CO 2 -Fluid-Rock Interaction in Enhanced Geothermal Systems: Field-Scale Geochemical Simulations

DOE PAGES

Pan, Feng; McPherson, Brian J.; Kaszuba, John

2017-01-01

Recent studies suggest that using supercritical CO 2 (scCO 2 ) instead of water as a heat transmission fluid in Enhanced Geothermal Systems (EGS) may improve energy extraction. While CO 2 -fluid-rock interactions at “typical” temperatures and pressures of subsurface reservoirs are fairly well known, such understanding for the elevated conditions of EGS is relatively unresolved. Geochemical impacts of CO 2 as a working fluid (“CO 2 -EGS”) compared to those for water as a working fluid (H 2 O-EGS) are needed. The primary objectives of this study are (1) constraining geochemical processes associated with CO 2 -fluid-rock interactions undermore » the high pressures and temperatures of a typical CO 2 -EGS site and (2) comparing geochemical impacts of CO 2 -EGS to geochemical impacts of H 2 O-EGS. The St. John’s Dome CO 2 -EGS research site in Arizona was adopted as a case study. A 3D model of the site was developed. Net heat extraction and mass flow production rates for CO 2 -EGS were larger compared to H 2 O-EGS, suggesting that using scCO 2 as a working fluid may enhance EGS heat extraction. More aqueous CO 2 accumulates within upper- and lower-lying layers than in the injection/production layers, reducing pH values and leading to increased dissolution and precipitation of minerals in those upper and lower layers. Dissolution of oligoclase for water as a working fluid shows smaller magnitude in rates and different distributions in profile than those for scCO 2 as a working fluid. It indicates that geochemical processes of scCO 2 -rock interaction have significant effects on mineral dissolution and precipitation in magnitudes and distributions.« less

Associations of individual, household and environmental characteristics with carbon dioxide emissions from motorised passenger travel

PubMed Central

Brand, Christian; Goodman, Anna; Rutter, Harry; Song, Yena; Ogilvie, David

2013-01-01

Carbon dioxide (CO2) emissions from motorised travel are hypothesised to be associated with individual, household, spatial and other environmental factors. Little robust evidence exists on who contributes most (and least) to travel CO2 and, in particular, the factors influencing commuting, business, shopping and social travel CO2. This paper examines whether and how demographic, socio-economic and other personal and environmental characteristics are associated with land-based passenger transport and associated CO2 emissions. Primary data were collected from 3474 adults using a newly developed survey instrument in the iConnect study in the UK. The participants reported their past-week travel activity and vehicle characteristics from which CO2 emissions were derived using an adapted travel emissions profiling method. Multivariable linear and logistic regression analyses were used to examine what characteristics predicted higher CO2 emissions. CO2 emissions from motorised travel were distributed highly unequally, with the top fifth of participants producing more than two fifth of emissions. Car travel dominated overall CO2 emissions, making up 90% of the total. The strongest independent predictors of CO2 emissions were owning at least one car, being in full-time employment and having a home-work distance of more than 10 km. Income, education and tenure were also strong univariable predictors of CO2 emissions, but seemed to be further back on the causal pathway than having a car. Male gender, late-middle age, living in a rural area and having access to a bicycle also showed significant but weaker associations with emissions production. The findings may help inform the development of climate change mitigation policies for the transport sector. Targeting individuals and households with high car ownership, focussing on providing viable alternatives to commuting by car, and supporting planning and other policies that reduce commuting distances may provide an equitable and efficient approach to meeting carbon mitigation targets. PMID:24882922

Effect of a participatory ergonomics intervention on psychosocial factors at work in a randomised controlled trial.

PubMed

Haukka, Eija; Pehkonen, Irmeli; Leino-Arjas, Päivi; Viikari-Juntura, Eira; Takala, Esa-Pekka; Malmivaara, Antti; Hopsu, Leila; Mutanen, Pertti; Ketola, Ritva; Virtanen, Tuija; Holtari-Leino, Merja; Nykänen, Jaana; Stenholm, Sari; Ojajärvi, Anneli; Riihimäki, Hilkka

2010-03-01

To study the effect of a participatory ergonomics intervention on psychosocial factors among kitchen workers. A cluster randomised controlled trial. Four cities in Finland, 2002-2005. 504 workers in 119 municipal kitchens. Kitchens were randomised to intervention (n=59) and control (n=60) groups. The intervention lasted 11-14 months and was based on the workers' active participation in work analysis, planning and implementing the ergonomic changes aimed at decreasing the physical and mental workload. Mental stress, mental strenuousness of work, hurry, job satisfaction, job control, skill discretion, co-worker relationships and supervisor support. Data were collected by questionnaire at baseline, at the end of the intervention, and at a 12-month follow-up (PI(12)). At the end of the intervention, the OR of job dissatisfaction for the intervention group as compared with the control group was 3.0 (95% CI 1.1 to 8.5), of mental stress 2.3 (1.2 to 4.7) and of poor co-worker relationships 2.3 (1.0 to 5.2). At the PI(12), the OR of job dissatisfaction was 3.0 (1.2 to 7.8). Analysis of the independent and joint effects of the intervention and unconnected organisational reforms showed that adverse changes were accentuated among those with exposure to both. No favourable effects on psychosocial factors at work were found. The adverse changes were due to a joint effect of the intervention and the unconnected organisational reforms. The findings do not support the usefulness of this kind of intervention in changing unsatisfactory psychosocial working conditions.

An Experimental Study of Effects in Soils by Potential CO2 Seepage

NASA Astrophysics Data System (ADS)

Wei, Y.; Caramanna, G.; Nathanail, P.; Steven, M.; Maroto-Valer, M.

2011-12-01

Potential CO2 seepage during a CCS project will not only reduce its performing efficiency, but can also impact the local environment. Though scientists announce with confidence that CCS is a safe technology to store CO2 deep underground, it is essential to study the effects of CO2 seepage, to avoid any possible influences on soils. As a simplified environment, laboratory experiments can easily be controlled and vital to be studied to be compared with more complex natural analogues and modelling works. Recent research focuses on the effects on ecosystems of CO2 leakage. However, the impacts of long-term, low level exposure for both surface and subsurface ecosystems, as well as soil geochemistry changes are currently not clear. Moreover, previous work has focussed on pure CO2 leakage only and its impacts on the ecosystem. However, in a more realistic scenario the gas coming from a capture process may contain impurities, such as SO2, which are more dangerous than pure CO2 and could cause more severe consequences. Therefore, it is critical to assess the potential additional risks caused by CO2 leakage with impurities. Accordingly, both a batch and a continuous flow reactor were designed and used to study potential impacts caused by the CO2 seepage, focusing on soil geochemistry changes, due to different concentrations of CO2/SO2 mixtures. Stage 1- Batch experiments. In this stage, a soil sample was collected from the field and exposed to a controlled CO2/SO2 gas mixtures (100% CO2 and CO2:SO2=99:1). The water soluble fractions were measured before and after incubation. With 100% CO2 incubation it was found that: 1) the pH in the soil sample did not change significantly; 2) for soils with different moisture levels, greater moisture in the soil results in higher CO2 uptake during incubation; and 3) for sandy soils, small changes in CaCl2-exchangeable metal concentration, were observed after CO2 incubation. However, the increased concentration of toxic elements is still below plant tolerance limits. With a gas mixture of 99% CO2 and 1% SO2, it was found that: 1) pH changed significantly from 5.54 to ~3.00; 2) consistent but minor changes were found in some of the nutrients; and 3) high concentrations of the toxic element, Al, were found, at approximately ~200 mg/l compared to an initial value of <0.1 mg/l. Stage 2- A continuous flow reactor. At this stage, a continuous vertical flow reactor was designed and used to assess the impact in soil caused by different mixtures of CO2/SO2. With limestone sand and 100% CO2, it was found that: 1) pH dropped quickly at the first hour and stabilised around 6.10 until CO2 injecting was stopped; 2) limestone had strong buffering capacity but only after stopping CO2 injection; 3) a change was found for soil permeability and porosity during the gas injecting process; 4) with saturated soil, a dome was always formed at the top of the soil column at the end of each experiment. More experiments are planned in the near future.

Demonstration of Advanced CO 2 Capture Process Improvements for Coal-Fired Flue Gas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carroll, John

This document summarizes the activities of Cooperative Agreement DE-FE0026590, “Demonstration of Advanced CO 2 Capture Process Improvements for Coal-Fired Flue Gas” during the performance period of October 1, 2015 through May 31, 2017. This project was funded by the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL). Southern Company Services, Inc. (SCS) was the prime contractor and co-funder of the project. Mitsubishi Heavy Industries America (MHIA) and AECOM were project team members. The overall project objective was to improve costs, energy requirements, and performance of an existing amine-based CO 2 capture process. This will occur via improvements inmore » three areas: 1. Reboiler design – The first objective of the program was to demonstrate performance of an integrated stripper/reboiler (termed Built-in Reboiler, or BIR) to reduce footprint, capital costs, and integration issues of the current technology. 2. Particulate management – The second objective was to carry out a Particulate Matter Management (PMM) test. This has the potential to reduce operating costs and capital costs due to the reduced or eliminated need for mechanical filtration. 3. Solvent – The third objective was to carry out a new solvent test plan (referred to as NSL) to demonstrate a new solvent (termed New Solvent A), which is expected to reduce regeneration steam. The bulk price is also expected to be lower than KS-1, which is the current solvent used in this process. NSL testing would include baseline testing, optimization, long term testing, solvent reclamation testing, and final inspection. These combine to form the Advanced Carbon Capture (ACC) technology. Much of this work will be applicable to generic solvent processes, especially in regards to improved reboiler design, and focused to meet or exceed the DOE’s overall carbon capture performance goals of 90% CO 2 capture rate with 95% CO 2 purity at a cost of $40/tonne of CO 2 by 2025 and at a cost of electricity (COE) 30% less than baseline CO 2 capture approaches by 2030. This project was divided into two phases. Phase 1 is the planning phase, and Phase 2 is the construction, operations, testing, and analysis phase. A down select occurred after Phase 1. Phase 1 activities were carried out during this reporting period, and therefore, Phase 1 activities are solely considered in this report. The project was not selected for Phase 2 funding.« less

Quality of tri-Co-60 MR-IGRT treatment plans in comparison with VMAT treatment plans for spine SABR.

PubMed

Choi, Chang Heon; Park, So-Yeon; Kim, Jung-In; Kim, Jin Ho; Kim, Kyubo; Carlson, Joel; Park, Jong Min

2017-02-01

To investigate the plan quality of tri-Co-60 intensity-modulated radiation therapy (IMRT) plans for spine stereotactic ablative radiotherapy (SABR). A total of 20 patients with spine metastasis were retrospectively selected. For each patient, a tri-Co-60 IMRT plan and a volumetric-modulated arc therapy (VMAT) plan were generated. The spinal cords were defined based on MR images for the tri-Co-60 IMRT, while isotropic 1-mm margins were added to the spinal cords for the VMAT plans. The VMAT plans were generated with 10-MV flattening filter-free photon beams of TrueBeam STx ™ (Varian Medical Systems, Palo Alto, CA), while the tri-Co-60 IMRT plans were generated with the ViewRay ™ system (ViewRay inc., Cleveland, OH). The initial prescription dose was 18 Gy (1 fraction). If the tolerance dose of the spinal cord was not met, the prescription dose was reduced until the spinal cord tolerance dose was satisfied. The mean dose to the target volumes, conformity index and homogeneity index of the VMAT and tri-Co-60 IMRT were 17.8 ± 0.8 vs 13.7 ± 3.9 Gy, 0.85 ± 0.20 vs 1.58 ± 1.29 and 0.09 ± 0.04 vs 0.24 ± 0.19, respectively. The integral doses and beam-on times were 16,570 ± 1768 vs 22,087 ± 2.986 Gy cm 3 and 3.95 ± 1.13 vs 48.82 ± 10.44 min, respectively. The tri-Co-60 IMRT seems inappropriate for spine SABR compared with VMAT. Advances in knowledge: For spine SABR, the tri-Co-60 IMRT is inappropriate owing to the large penumbra, large leaf width and low dose rate of the ViewRay system.

Quality of tri-Co-60 MR-IGRT treatment plans in comparison with VMAT treatment plans for spine SABR

PubMed Central

Choi, Chang Heon; Park, So-Yeon; Kim, Jung-in; Kim, Jin Ho; Kim, Kyubo; Carlson, Joel

2017-01-01

Objective: To investigate the plan quality of tri-Co-60 intensity-modulated radiation therapy (IMRT) plans for spine stereotactic ablative radiotherapy (SABR). Methods: A total of 20 patients with spine metastasis were retrospectively selected. For each patient, a tri-Co-60 IMRT plan and a volumetric-modulated arc therapy (VMAT) plan were generated. The spinal cords were defined based on MR images for the tri-Co-60 IMRT, while isotropic 1-mm margins were added to the spinal cords for the VMAT plans. The VMAT plans were generated with 10-MV flattening filter-free photon beams of TrueBeam STx™ (Varian Medical Systems, Palo Alto, CA), while the tri-Co-60 IMRT plans were generated with the ViewRay™ system (ViewRay inc., Cleveland, OH). The initial prescription dose was 18 Gy (1 fraction). If the tolerance dose of the spinal cord was not met, the prescription dose was reduced until the spinal cord tolerance dose was satisfied. Results: The mean dose to the target volumes, conformity index and homogeneity index of the VMAT and tri-Co-60 IMRT were 17.8 ± 0.8 vs 13.7 ± 3.9 Gy, 0.85 ± 0.20 vs 1.58 ± 1.29 and 0.09 ± 0.04 vs 0.24 ± 0.19, respectively. The integral doses and beam-on times were 16,570 ± 1768 vs 22,087 ± 2.986 Gy cm3 and 3.95 ± 1.13 vs 48.82 ± 10.44 min, respectively. Conclusion: The tri-Co-60 IMRT seems inappropriate for spine SABR compared with VMAT. Advances in knowledge: For spine SABR, the tri-Co-60 IMRT is inappropriate owing to the large penumbra, large leaf width and low dose rate of the ViewRay system. PMID:27781486

Overview of Carbon Dioxide Control Issues During International Space Station/Space Shuttle Joint Docked Operations

NASA Technical Reports Server (NTRS)

Matty, Christopher M.

2010-01-01

Crewed space vehicles have a common requirement to remove the carbon dioxide (CO2) created by the metabolic processes of the crew. The space shuttle [Space Transportation System (STS)] and International Space Station (ISS) each have systems in place that allow control and removal of CO2 from the habitable cabin environment. During periods in which the space shuttle is docked to the ISS, known as "joint docked operations," the space shuttle and ISS share a common atmosphere environment. During this period, an elevated amount of CO2 is produced through the combined metabolic activity of the STS and ISS crews. This elevated CO2 production, together with the large effective atmosphere created by collective volumes of the docked vehicles, creates a unique set of requirements for CO2 removal. This paper will describe individual CO2 control plans implemented by STS and ISS engineering teams, as well as the integrated plans used when both vehicles are docked. The paper will also discuss some of the issues and anomalies experienced by both engineering teams.

Overview of Carbon Dioxide Control Issues During International Space Station/Space Shuttle Joint Docked Operations

NASA Technical Reports Server (NTRS)

Matty, Christopher M.; Hayley, Elizabeth P.

2009-01-01

Manned space vehicles have a common requirement to remove the Carbon Dioxide (CO2) created by the metabolic processes of the crew. The Space Shuttle and International Space Station (ISS) each have systems in place to allow control and removal of CO2 from the habitable cabin environment. During periods where the Space Shuttle is docked to ISS, known as joint docked operations, the Space Shuttle and ISS share a common atmosphere environment. During this period there is an elevated production of CO2 caused by the combined metabolic activity of the Space Shuttle and ISS crew. This elevated CO2 production, combined with the large effective atmosphere created by the collective volumes of the docked vehicles, creates a unique set of requirements for CO2 removal. This paper will describe the individual CO2 control plans implemented by the Space Shuttle and ISS engineering teams, as well as the integrated plans used when both vehicles are docked. In addition, the paper will discuss some of the issues and anomalies experienced by both engineering teams.

Hybrid Co-Evolutionary Motion Planning via Visibility-Based Repair

NASA Technical Reports Server (NTRS)

Dozier, Gerry; McCullough, Shaun; Brown, Edward, Jr.; Homaifar, Abdollah; Bikdash, Mar-wan

1997-01-01

This paper introduces a hybrid co-evolutionary system for global motion planning within unstructured environments. This system combines the concept of co-evolutionary search along with a concept that we refer to as the visibility-based repair to form a hybrid which quickly transforms infeasible motions into feasible ones. Also, this system makes use of a novel representation scheme for the obstacles within an environment. Our hybrid evolutionary system differs from other evolutionary motion planners in that (1) more emphasis is placed on repairing infeasible motions to develop feasible motions rather than using simulated evolution exclusively as a means of discovering feasible motions, (2) a continuous map of the environment is used rather than a discretized map, and (3) it develops global motion plans for multiple mobile destinations by co-evolving populations of sub-global motion plans. In this paper, we demonstrate the effectiveness of this system by using it to solve two challenging motion planning problems where multiple targets try to move away from a point robot.

Falling Particles: Concept Definition and Capital Cost Estimate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stoddard, Larry; Galluzzo, Geoff; Adams, Shannon

2016-06-30

The Department of Energy’s (DOE) Office of Renewable Power (ORP) has been tasked to provide effective program management and strategic direction for all of the DOE’s Energy Efficiency & Renewable Energy’s (EERE’s) renewable power programs. The ORP’s efforts to accomplish this mission are aligned with national energy policies, DOE strategic planning, EERE’s strategic planning, Congressional appropriation, and stakeholder advice. ORP is supported by three renewable energy offices, of which one is the Solar Energy Technology Office (SETO) whose SunShot Initiative has a mission to accelerate research, development and large scale deployment of solar technologies in the United States. SETO hasmore » a goal of reducing the cost of Concentrating Solar Power (CSP) by 75 percent of 2010 costs by 2020 to reach parity with base-load energy rates, and to reduce costs 30 percent further by 2030. The SunShot Initiative is promoting the implementation of high temperature CSP with thermal energy storage allowing generation during high demand hours. The SunShot Initiative has funded significant research and development work on component testing, with attention to high temperature molten salts, heliostats, receiver designs, and high efficiency high temperature supercritical CO 2 (sCO2) cycles.« less

Evaluation of simulated biospheric carbon dioxide fluxes and atmospheric concentrations using global in situ observations

NASA Astrophysics Data System (ADS)

Philip, S.; Johnson, M. S.; Potter, C. S.; Genovese, V. B.

2016-12-01

Atmospheric mixing ratios of carbon dioxide (CO2) are largely controlled by anthropogenic emission sources and biospheric sources/sinks. Global biospheric fluxes of CO2 are controlled by complex processes facilitating the exchange of carbon between terrestrial ecosystems and the atmosphere. These processes which play a key role in these terrestrial ecosystem-atmosphere carbon exchanges are currently not fully understood, resulting in large uncertainties in the quantification of biospheric CO2 fluxes. Current models with these inherent deficiencies have difficulties simulating the global carbon cycle with high accuracy. We are developing a new modeling platform, GEOS-Chem-CASA by integrating the year-specific NASA-CASA (National Aeronautics and Space Administration - Carnegie Ames Stanford Approach) biosphere model with the GEOS-Chem (Goddard Earth Observation System-Chemistry) chemical transport model to improve the simulation of atmosphere-terrestrial ecosystem carbon exchange. We use NASA-CASA to explicitly represent the exchange of CO2 between terrestrial ecosystem and atmosphere by replacing the baseline GEOS-Chem land net CO2 flux and forest biomass burning CO2 emissions. We will present the estimation and evaluation of these "bottom-up" land CO2 fluxes, simulated atmospheric mixing ratios, and forest disturbance changes over the last decade. In addition, we will present our initial comparison of atmospheric column-mean dry air mole fraction of CO2 predicted by the model and those retrieved from NASA's OCO-2 (Orbiting Carbon Observatory-2) satellite instrument and model-predicted surface CO2 mixing ratios with global in situ observations. This evaluation is the first step necessary for our future work planned to constrain the estimates of biospheric carbon fluxes through "top-down" inverse modeling, which will improve our understanding of the processes controlling atmosphere-terrestrial ecosystem greenhouse gas exchanges, especially over regions which lack in situ observations.

B33C-0612: Evaluation of Simulated Biospheric Carbon Dioxide Fluxes and Atmospheric Concentrations Using Global in Situ Observations

NASA Technical Reports Server (NTRS)

Philip, Sajeev; Johnson, Matthew S.; Potter, Christopher S.; Genovese, Vanessa

2016-01-01

Atmospheric mixing ratios of carbon dioxide (CO2) are largely controlled by anthropogenic emission sources and biospheric sources/sinks. Global biospheric fluxes of CO2 are controlled by complex processes facilitating the exchange of carbon between terrestrial ecosystems and the atmosphere. These processes which play a key role in these terrestrial ecosystem-atmosphere carbon exchanges are currently not fully understood, resulting in large uncertainties in the quantification of biospheric CO2 fluxes. Current models with these inherent deficiencies have difficulties simulating the global carbon cycle with high accuracy. We are developing a new modeling platform, GEOS-Chem-CASA by integrating the year-specific NASA-CASA (National Aeronautics and Space Administration - Carnegie Ames Stanford Approach) biosphere model with the GEOS-Chem (Goddard Earth Observation System-Chemistry) chemical transport model to improve the simulation of atmosphere-terrestrial ecosystem carbon exchange. We use NASA-CASA to explicitly represent the exchange of CO2 between terrestrial ecosystem and atmosphere by replacing the baseline GEOS-Chem land net CO2 flux and forest biomass burning CO2 emissions. We will present the estimation and evaluation of these "bottom-up" land CO2 fluxes, simulated atmospheric mixing ratios, and forest disturbance changes over the last decade. In addition, we will present our initial comparison of atmospheric column-mean dry air mole fraction of CO2 predicted by the model and those retrieved from NASA's OCO-2 (Orbiting Carbon Observatory-2) satellite instrument and model-predicted surface CO2 mixing ratios with global in situ observations. This evaluation is the first step necessary for our future work planned to constrain the estimates of biospheric carbon fluxes through "top-down" inverse modeling, which will improve our understanding of the processes controlling atmosphere-terrestrial ecosystem greenhouse gas exchanges, especially over regions which lack in situ observations.

The Effect of Considering Environmental Aspect to Distribution Planning: A Case in Logistics SME

NASA Astrophysics Data System (ADS)

Prambudia, Yudha; Andrian Nur, Andri

2016-01-01

Environmental aspect is often neglected in traditional distribution planning process of a product. Especially in small-medium enterprises (SME) of developing countries where cost efficiency is the predominant factor. Bearing in mind that there is a large number of SME's performing logistics activities, the consideration of environmental aspect in their distribution planning process would be beneficial to climate change mitigation efforts. The purpose of this paper is to show the impact of environmental aspect should it be considered as a contributing factor in distribution planning. In this research, an adoption of CO2-emission factor in an SME's distribution planning in Indonesia was simulated. The outputs of distribution planning with and without the factor consideration are then compared. The result shows that adoption of CO2-emission factor would change the priority of delivery route.

Center Planning and Development Student Engineer at KSC

NASA Technical Reports Server (NTRS)

Jenkins, Kenneth T., Jr.

2015-01-01

This summer I was the Student Trainee (Engineering) Pathways Intern (co-op) at the Kennedy Space Center (KSC) in the Center Planning & Development (CPD) Directorate. CPD works with commercial companies who are interested in using KSC's unique capabilities for spaceflight, spacecraft processing, ground systems and Research & Development (R&D) projects that fall in line with NASA's Mission and Vision. CPD is divided into three (3) groups: (1) AD-A, which works on the Master Planning for the center, (2) AD-B (where I am), which works on project control, management and integration, and (3) AD-C, which works on partnership development. CPD's main goal is to make KSC the world's preeminent multi-user spaceport and maintain the center as a leader in space exploration. CPD is a very diverse group of employees having a wide knowledge of not only the Space Shuttle, but also Expendable Launch Vehicles (ELV). The director of CPD, Scott Colloredo, is on the advisory board for Commercial Space Operations (CSO) and has a degree from ERAU. I worked on a number of different tasks for AD-B, as well as CPD, that includes, but not limited to: reviewing and reissuing engineering documents, weekly notes for CPD and senior management, engineering familiarizations with facilities at KSC, leading a tour for the Embry-Riddle Aeronautical University Career Services office, and working on actual agreements/proposals that will be used in the partnership process with multiple partners, along with other projects. Most of the work I have done is sensitive information and cannot be disclosed.

Strategic use of the underground for an energy mix plan, synergies among CO2 and CH4 Geological Storage and Geothermal Energy: Italian Energy review and Latium case study

NASA Astrophysics Data System (ADS)

Procesi, M.; Cantucci, B.; Buttinelli, M.; Armezzani, G.; Quattrocchi, F.

2012-04-01

Since the world-wide energy demand has been growing so much in the last years, it is necessary to develop a strategic mix-energy plan to supply low GHG (GreenHouseGas) emissions energy and solve the problem of CO2 emission increasing. A recent study published by European Commission shows that, if existing trends continue, by 2050 CO2 emissions will be unsustainably high: 900-1000 parts per million by volume. The European Commission in 2007 underline the necessity to elaborate, at European level, a Strategic Energy Technology Plan focused on non-carbon or reduced-carbon sources of energy, as renewable energies, CO2 capture and storage technologies, smart energy networks and energy efficiency and savings. Future scenarios for 2030 elaborated by the International Energy Agency (IEA) shows as a mix energy plan could reduce the global CO2 emissions from 27Gt to 23 Gt (about 15%). A strategic use of the underground in terms of: - development of CCS (Carbon dioxide Capture and Storage) associated to fossil fuel combustion; - increase of CH4 geological storage sites; - use of renewable energies as geothermic for power generation; could open a new energy scenario, according to the climate models published by IPCC. Nowadays CCS market is mainly developed in USA and Canada, but still not much accounted in Europe. In Italy there aren't active CCS projects, even if potential areas have been already identified. Many CH4 storage sites are located in Northern America, while other are present in Europe and Italy, but the number of sites is limited despite the huge underground potentiality. In Italy the power generation from geothermal energy comes exclusively from Tuscany (Larderello-Travale and Mt. Amiata geothermal fields) despite the huge potentiality of other regions as Latium, Campania and Sicily (Central and South Italy). The energy deficit and the relevant CO2 emissions represent a common status for many Italian regions, especially for the Latium Region. This suggests that a new energy plan to improve the efficiency and the environmental sustainability is necessary. The evaluations of potential areas suitable for CO2 and/or CH4 geological storage and geothermal energy in the Latium region, have been done through a revisiting of public data such as well composite logs and maps. For the selection has been taken in account too, exclusion criteria sites as well as presence of geological risks and natural protected areas. Then the storage capacity and geothermal potentiality have been estimated for the selected areas. Finally, considering the hypothesized energy mix plan, an evaluation of the potential CO2 emissions decrease has been done. Preliminary results are encouraging to extent this evaluation also in other regions to improve a National Energy Plan.

Modeling the key factors that could influence the diffusion of CO2 from a wellbore blowout in the Ordos Basin, China.

PubMed

Li, Qi; Shi, Hui; Yang, Duoxing; Wei, Xiaochen

2017-02-01

Carbon dioxide (CO 2 ) blowout from a wellbore is regarded as a potential environment risk of a CO 2 capture and storage (CCS) project. In this paper, an assumed blowout of a wellbore was examined for China's Shenhua CCS demonstration project. The significant factors that influenced the diffusion of CO 2 were identified by using a response surface method with the Box-Behnken experiment design. The numerical simulations showed that the mass emission rate of CO 2 from the source and the ambient wind speed have significant influence on the area of interest (the area of high CO 2 concentration above 30,000 ppm). There is a strong positive correlation between the mass emission rate and the area of interest, but there is a strong negative correlation between the ambient wind speed and the area of interest. Several other variables have very little influence on the area of interest, e.g., the temperature of CO 2 , ambient temperature, relative humidity, and stability class values. Due to the weather conditions at the Shenhua CCS demonstration site at the time of the modeled CO 2 blowout, the largest diffusion distance of CO 2 in the downwind direction did not exceed 200 m along the centerline. When the ambient wind speed is in the range of 0.1-2.0 m/s and the mass emission rate is in the range of 60-120 kg/s, the range of the diffusion of CO 2 is at the most dangerous level (i.e., almost all Grade Four marks in the risk matrix). Therefore, if the injection of CO 2 takes place in a region that has relatively low perennial wind speed, special attention should be paid to the formulation of pre-planned, emergency measures in case there is a leakage accident. The proposed risk matrix that classifies and grades blowout risks can be used as a reference for the development of appropriate regulations. This work may offer some indicators in developing risk profiles and emergency responses for CO 2 blowouts.

KSC-2011-7887

NASA Image and Video Library

2011-11-22

CAPE CANAVERAL, Fla. -- Andy Aldrin, director of business development for United Launch Alliance (ULA), talks to media about plans to launch NASA astronauts to the International Space Station in the Atlas Spaceflight Operations Center (ASOC) at Cape Canaveral Air Force Station in Florida. ULA is working to make its Atlas V rocket safe for humans for NASA's Commercial Crew Program (CCP) under the Commercial Crew Development Round 2 (CCDev2) activities. Part of those plans will be to design and test an emergency detection system and crew access capabilities. ULA also is working with other aerospace system providers developing spacecraft that would launch atop the company's Atlas V rocket, such as Blue Origin, Sierra Nevada and The Boeing Co. CCP, which is based at the adjacent NASA's Kennedy Space Center, is partnering with industry to take crews to the station or other low Earth orbit destinations. Aldrin explained that the goal of ULA will be to develop a human spaceflight capability without altering rocket's proven design and successful track record. It's the freedom to develop innovative solutions such as this that CCP hopes will drive down the cost of space travel as well as open up space to more people than ever before. Seven aerospace companies are maturing launch vehicle and spacecraft designs under CCDev2, including Alliant Techsystems Inc. (ATK) of Promontory, Utah, Blue Origin of Kent, Wash., The Boeing Co., of Houston, Excalibur Almaz Inc. of Houston, Sierra Nevada Corp. of Louisville, Colo., Space Exploration Technologies (SpaceX) of Hawthorne, Calif., and United Launch Alliance (ULA) of Centennial, Colo. For more information, visit www.nasa.gov/exploration/commercial Photo credit: Jim Grossmann

Optoacoustic measurements of human placenta and umbilical blood oxygenation

NASA Astrophysics Data System (ADS)

Nanovskaya, T. N.; Petrov, I. Y.; Petrov, Y.; Patrikeeva, S. L.; Ahmed, M. S.; Hankins, G. D. V.; Prough, D. S.; Esenaliev, R. O.

2016-03-01

Adequate oxygenation is essential for normal embryogenesis and fetal growth. Perturbations in the intrauterine oxidative environment during pregnancy are associated with several pathophysiological disorders such as pregnancy loss, preeclampsia, and intrauterine growth restriction. We proposed to use optoacoustic technology for monitoring placental and fetal umbilical blood oxygenation. In this work, we studied optoacoustic monitoring of oxygenation in placenta and umbilical cord blood ex vivo using technique of placenta perfusion. We used a medical grade, nearinfrared, tunable, optoacoustic system developed and built for oxygenation monitoring in blood vessels and in tissues. First, we calibrated the system for cord blood oxygenation measurements by using a CO-Oximeter (gold standard). Then we performed validation in cord blood circulating through the catheters localized on the fetal side of an isolated placental lobule. Finally, the oxygenation measurements were performed in the perfused placental tissue. To increase or decrease blood oxygenation, we used infusion of a gas mixture of 95% O2 + 5% CO2 and 95% N2 + 5% CO2, respectively. In placental tissue, up to four cycles of changes in oxygenation were performed. The optoacoustically measured oxygenation in circulating cord blood and in placental lobule closely correlated with the actual oxygenation data measured by CO-Oximeter. We plan to further test the placental and cord blood oxygenation monitoring with optoacoustics in animal and clinical studies.

40 CFR Appendix F to Part 112 - Facility-Specific Response Plan

Code of Federal Regulations, 2011 CFR

2011-07-01

... of Contents 1.0Model Facility-Specific Response Plan 1.1Emergency Response Action Plan 1.2Facility.... EC01MR92.015 1.1Emergency Response Action Plan Several sections of the response plan shall be co-located... sections shall be called the Emergency Response Action Plan. The Agency intends that the Action Plan...

40 CFR 98.448 - Geologic sequestration monitoring, reporting, and verification (MRV) plan.

Code of Federal Regulations, 2011 CFR

2011-07-01

... than 1 year. (2) Identification of potential surface leakage pathways for CO2 in the maximum monitoring area and the likelihood, magnitude, and timing, of surface leakage of CO2 through these pathways. (3) A...

40 CFR 98.448 - Geologic sequestration monitoring, reporting, and verification (MRV) plan.

Code of Federal Regulations, 2012 CFR

2012-07-01

... than 1 year. (2) Identification of potential surface leakage pathways for CO2 in the maximum monitoring area and the likelihood, magnitude, and timing, of surface leakage of CO2 through these pathways. (3) A...

Molten Salt: Concept Definition and Capital Cost Estimate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stoddard, Larry; Andrew, Daniel; Adams, Shannon

The Department of Energy’s (DOE’s) Office of Renewable Power (ORP) has been tasked to provide effective program management and strategic direction for all of the DOE’s Energy Efficiency & Renewable Energy’s (EERE’s) renewable power programs. The ORP’s efforts to accomplish this mission are aligned with national energy policies, DOE strategic planning, EERE’s strategic planning, Congressional appropriation, and stakeholder advice. ORP is supported by three renewable energy offices, of which one is the Solar Energy Technology Office (SETO) whose SunShot Initiative has a mission to accelerate research, development and large scale deployment of solar technologies in the United States. SETO hasmore » a goal of reducing the cost of Concentrating Solar Power (CSP) by 75 percent of 2010 costs by 2020 to reach parity with base-load energy rates, and to reduce costs 30 percent further by 2030. The SunShot Initiative is promoting the implementation of high temperature CSP with thermal energy storage allowing generation during high demand hours. The SunShot Initiative has funded significant research and development work on component testing, with attention to high temperature molten salts, heliostats, receiver designs, and high efficiency high temperature supercritical CO 2 (sCO2) cycles. DOE retained Black & Veatch to support SETO’s SunShot Initiative for CSP solar power tower technology in the following areas: 1. Concept definition, including costs and schedule, of a flexible test facility to be used to test and prove components in part to support financing. 2. Concept definition, including costs and schedule, of an integrated high temperature molten salt (MS) facility with thermal energy storage and with a supercritical CO 2 cycle generating approximately 10MWe. 3. Concept definition, including costs and schedule, of an integrated high temperature falling particle facility with thermal energy storage and with a supercritical CO 2 cycle generating approximately 10MWe. This report addresses the concept definition of the MS/sCO2 integrated 10MWe facility, Item No. 2 above. Other reports address Items No. 1 and No. 3 above.« less

The effectiveness of Concept Mapping Content Representation Lesson Study (ComCoReLS) model to improve skills of Creating Physics Lesson Plan (CPLP) for pre-service physics teacher

NASA Astrophysics Data System (ADS)

Purwaningsih, E.; Sutoyo, S.; Wasis; Prahani, B. K.

2018-03-01

This research is aimed to analyse the effectiveness of ComCoReLS (Concept Mapping Content Representation Lesson Study) model towards the improvement skills of Creating Physics Lesson Plan (CPLP) for pre-service physics teacher. This research used one group pre-test and post-test design on 12 pre-service physics teacher at University of Malang State (Indonesia) in academic year 2016/2017. Data collection was conducted through test and interview. Skills of creating physics lesson plan for pre-service physics teacher measurement were conducted through Physics Lesson Plan Evaluation Sheet (PLPES). The data analysis technique was done by using paired t-test and n-gain. The CoMCoReLS model consists of 5 phases, including (1) Preparation, (2) Coaching, (3) Guided Practice, (4) Independent Practice, and (5) Evaluation. In the first, second, third and fifth phases are done at University of Malang State, while the fourth phase (Independent Practice) is done in SMAN 1 Singosari, SMAN 2 Malang, SMA Lab UM, MAN 3 Malang. The results showed that there was a significant increase in skills of creating physics lesson plan for pre-service physics teacher at α = 5% and n-gain average of high category. Thus, the ComCoReLS model is effective for improving skills of creating physics lesson plan for pre-service physics teacher.

Upward flow of supercritical CO2 with transition to gaseous conditions: Simulations for design of large-scale CO2 flow experiments at LUCI

NASA Astrophysics Data System (ADS)

Oldenburg, C. M.; Peters, C. A.; Dobson, P. F.; Doughty, C.

2010-12-01

Understanding the processes involved in large-scale upward flow of CO2 related to Geologic Carbon Sequestration (GCS) is critical to evaluating trapping mechanisms and potential impacts of CO2 leakage over long distances. The Laboratory for Underground CO2 Investigations (LUCI) is being planned to be built at DUSEL to host large-scale vertical CO2 and brine flow experiments. As conceived, LUCI would consist of a 500 m-long vertical raisebore approximately 3 m in diameter which will contain three suspended long-column pressure vessels. The long-column pressure vessels are planned to be 1 m in diameter with thermal control on the outer walls with a centralized inner fiberglass well for accommodating monitoring tools for determining phase saturation, porosity, temperature, and other properties of the flow region. The outer wall of the inner fiberglass well and the inner wall of the main vessel comprise the lateral boundaries of the long vertical annular regions that will be filled with porous media in which experiments investigating flow and transport, geochemical alterations of well cement, and biological processes involving injected CO2 will be performed. The large vertical extent of the column is needed to span the full range of CO2 conditions from supercritical (scCO2, P > 7.4 MPa, T > 31 °C) to gaseous CO2 that is believed to be significant as CO2 flows upwards. Here we consider the CO2-brine flow experiments in which the annular region will be pressurized at the top and bottom and contain brine-filled porous media through which scCO2 introduced at the bottom will flow upward. We are carrying out two-phase flow simulations of the buoyancy- and pressure-driven flow of CO2 and brine upward in the annular porous media region to further design the flow columns, e.g., to determine critical length and diameter requirements, as well as to plan the experiments to be performed. The simulations are carried out using TOUGH2/ECO2N, which models two-phase non-isothermal flow and transport of water, CO2, and NaCl in porous media. To treat important issues of drainage and imbibition at the leading and trailing edges of the CO2 slug, we employ hysteretic relative permeability functions. Simulation results will be presented showing flow rate, saturation, and temperature dependence on permeability, relative permeability parameters, size of initial CO2 slug, imposed upward flow rate, and different side boundary conditions (e.g., fully insulated and temperature equal to a constant geothermal gradient).

Maintaining Adequate Carbon Dioxide Washout for an Advanced Extravehicular Mobility Unit

NASA Technical Reports Server (NTRS)

Chullen, Cinda; Navarro, Moses; Conger, Bruce; Korona, Adam; McMillin, Summer; Norcross, Jason; Swickrath, Mike

2013-01-01

Over the past several years, NASA has realized tremendous progress in technology development that is aimed at the production of an Advanced Extravehicular Mobility Unit (AEMU). Of the many functions provided by the spacesuit and portable life support subsystem within the AEMU, delivering breathing gas to the astronaut along with removing the carbon dioxide (CO2) remains one of the most important environmental functions that the AEMU can control. Carbon dioxide washout is the capability of the ventilation flow in the spacesuit helmet to provide low concentrations of CO2 to the crew member to meet breathing requirements. CO2 washout performance is a critical parameter needed to ensure proper and sufficient designs in a spacesuit and in vehicle applications such as sleep stations and hygiene compartments. Human testing to fully evaluate and validate CO2 washout performance is necessary but also expensive due to the levied safety requirements. Moreover, correlation of math models becomes challenging because of human variability and movement. To supplement human CO2 washout testing, a breathing capability will be integrated into a suited manikin test apparatus to provide a safe, lower cost, stable, easily modeled alternative to human testing. Additionally, this configuration provides NASA Johnson Space Center (JSC) the capability to evaluate CO2 washout under off-nominal conditions that would otherwise be unsafe for human testing or difficult due to fatigue of a test subject. Testing has been under way in-house at JSC and analysis has been initiated to evaluate whether the technology provides sufficient performance in ensuring that the CO2 is removed sufficiently and the ventilation flow is adequate for maintaining CO2 washout in the AEMU spacesuit helmet of the crew member during an extravehicular activity. This paper will review recent CO2 washout testing and analysis activities, testing planned in-house with a spacesuit simulator, and the associated analytical work along with insights from the medical aspect on the testing.

48 CFR 1409.506 - Procedures.

Code of Federal Regulations, 2011 CFR

2011-10-01

... ACQUISITION PLANNING CONTRACTOR QUALIFICATIONS Organizational and Consultant Conflicts of Interest 1409.506 Procedures. If the CO determines that contractor performance of the contemplated work is likely to create an organizational conflict of interest, then the contracting officer shall refer the documentation of the potential...

Integrated, Geothermal-CO2 Storage: An Adaptable, Hybrid, Multi-Stage, Energy-Recovery Approach to Reduce Carbon Intensity and Environmental Risk

NASA Astrophysics Data System (ADS)

Buscheck, T. A.; Chen, M.; Lu, C.; Sun, Y.; Hao, Y.; Elliot, T. R.; Celia, M. A.; Bielicki, J. M.

2012-12-01

The challenges of mitigating climate change and generating sustainable renewable energy are inseparable and can be addressed by synergistic integration of geothermal energy production with secure geologic CO2 storage (GCS). Pressure buildup can be a limiting factor for GCS and geothermal reservoir operations, due to a number of concerns, including the potential for CO2 leakage and induced seismicity, while pressure depletion can limit geothermal energy recovery. Water-use demands can also be a limiting factor for GCS and geothermal operations, particularly where water resources are already scarce. Economic optimization of geothermal-GCS involves trade-offs of various benefits and risks, along with their associated costs: (1) heat extraction per ton of delivered CO2, (2) permanent CO2 storage, (3) energy recovery per unit well (and working-fluid recirculation) costs, and (4) economic lifetime of a project. We analyze a hybrid, multi-stage approach using both formation brine and injected CO2 as working fluids to attempt to optimize the benefits of sustainable energy production and permanent CO2 storage, while conserving water resources and minimizing environmental risks. We consider a range of well-field patterns and operational schemes. Initially, the fluid production is entirely brine. After CO2 breakthrough, the fraction of CO2 in production, which is called the CO2 "cut", increases with time. Thus, brine is the predominant working fluid for early time, with the contribution of CO2 to heat extraction increasing with CO2 cut (and time). We find that smaller well spacing between CO2 injectors and producers favors earlier CO2 breakthrough and a more rapid rise in CO2 cut, which increases the contribution of recirculated CO2, thereby improving the heat extraction per ton of delivered CO2. On the other hand, larger well spacing increases permanent CO2 storage, energy production per unit well cost, while reducing the thermal drawdown rate, which extends the economic lifetime of a project. For the range of cases considered, we were never able to eliminate the co-production of brine; thus, brine management is likely to be important for reservoir operations, whether or not brine is considered as a candidate working fluid. Future work will address site-specific reservoir conditions and infrastructure factors, such as proximity to potential CO2 sources. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

Review of Quantitative Monitoring Methodologies for Emissions Verification and Accounting for Carbon Dioxide Capture and Storage for California’s Greenhouse Gas Cap-and-Trade and Low-Carbon Fuel Standard Programs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oldenburg, Curtis M.; Birkholzer, Jens T.

The Cap-and-Trade and Low Carbon Fuel Standard (LCFS) programs being administered by the California Air Resources Board (CARB) include Carbon Dioxide Capture and Storage (CCS) as a potential means to reduce greenhouse gas (GHG) emissions. However, there is currently no universal standard approach that quantifies GHG emissions reductions for CCS and that is suitable for the quantitative needs of the Cap-and-Trade and LCFS programs. CCS involves emissions related to the capture (e.g., arising from increased energy needed to separate carbon dioxide (CO 2) from a flue gas and compress it for transport), transport (e.g., by pipeline), and storage of COmore » 2 (e.g., due to leakage to the atmosphere from geologic CO 2 storage sites). In this project, we reviewed and compared monitoring, verification, and accounting (MVA) protocols for CCS from around the world by focusing on protocols specific to the geologic storage part of CCS. In addition to presenting the review of these protocols, we highlight in this report those storage-related MVA protocols that we believe are particularly appropriate for CCS in California. We find that none of the existing protocols is completely appropriate for California, but various elements of all of them could be adopted and/or augmented to develop a rigorous, defensible, and practical surface leakage MVA protocol for California. The key features of a suitable surface leakage MVA plan for California are that it: (1) informs and validates the leakage risk assessment, (2) specifies use of the most effective monitoring strategies while still being flexible enough to accommodate special or site-specific conditions, (3) quantifies stored CO 2, and (4) offers defensible estimates of uncertainty in monitored properties. California’s surface leakage MVA protocol needs to be applicable to the main CO 2 storage opportunities (in California and in other states with entities participating in California’s Cap-and-Trade or LCFS programs), specifically CO 2-enhanced oil recovery (CO 2-EOR), CO 2 injection into depleted gas reservoirs (with or without CO 2-enhanced gas recovery (CO 2-EGR)), as well as deep saline storage. Regarding the elements of an effective surface leakage MVA protocol, our recommendations for California are that: (1) both CO 2 and methane (CH 4) surface leakage should be monitored, especially for enhanced recovery scenarios, (2) emissions from all sources not directly related to injection and geologic storage (e.g., from capture, or pipeline transport) should be monitored and reported under a plan separate from the surface leakage MVA plan that is included as another component of the quantification methodology (QM), (3) the primary objective of the surface leakage MVA plan should be to quantify surface leakage of CO 2 and CH 4 and its uncertainty, with consideration of best-practices and state-of-the-art approaches to monitoring including attribution assessment, (4) effort should be made to monitor CO 2 storage and migration in the subsurface to anticipate future surface leakage monitoring needs, (5) detailed descriptions of specific monitoring technologies and approaches should be provided in the MVA plan, (6) the main purpose of the CO 2 injection project (CO 2-EOR, CO 2-EGR, or pure geologic carbon sequestration (GCS)) needs to be stated up front, (7) approaches to dealing with missing data and quantifying uncertainty need to be described, and (8) post-injection monitoring should go on for a period consistent with or longer than that prescribed by the U.S. EPA.« less

Regenerative Life Support Evaluation

NASA Technical Reports Server (NTRS)

Kleiner, G. N.; Thompson, C. D.

1977-01-01

This paper describes the development plan and design concept of the Regenerative Life Support Evaluation (RLSE) planned for flight testing in the European Space Agency Spacelab. The development plan encompasses the ongoing advanced life support subsystem and a systems integration effort to evolve concurrently subsystem concepts that perform their function and can be integrated with other subsystems in a flight demonstration of a regenerative life support system. The design concept for RLSE comprises water-electrolysis O2 generation, electrochemically depolarized CO2 removal, and Sabatier CO2 reduction for atmosphere regeneration, urine vapor-compression distillation, and wash-water hyperfiltration for waste-water recovery. The flight demonstration by RLSE is an important step in qualifying the regenerative concepts for life support in space stations.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Doug Cathro

The Lake Charles CCS Project is a large-scale industrial carbon capture and sequestration (CCS) project which will demonstrate advanced technologies that capture and sequester carbon dioxide (CO{sub 2}) emissions from industrial sources into underground formations. Specifically the Lake Charles CCS Project will accelerate commercialization of large-scale CO{sub 2} storage from industrial sources by leveraging synergy between a proposed petroleum coke to chemicals plant (the LCC Gasification Project) and the largest integrated anthropogenic CO{sub 2} capture, transport, and monitored sequestration program in the U.S. Gulf Coast Region. The Lake Charles CCS Project will promote the expansion of EOR in Texas andmore » Louisiana and supply greater energy security by expanding domestic energy supplies. The capture, compression, pipeline, injection, and monitoring infrastructure will continue to sequester CO{sub 2} for many years after the completion of the term of the DOE agreement. The objectives of this project are expected to be fulfilled by working through two distinct phases. The overall objective of Phase 1 was to develop a fully definitive project basis for a competitive Renewal Application process to proceed into Phase 2 - Design, Construction and Operations. Phase 1 includes the studies attached hereto that will establish: the engineering design basis for the capture, compression and transportation of CO{sub 2} from the LCC Gasification Project, and the criteria and specifications for a monitoring, verification and accounting (MVA) plan at the Hastings oil field in Texas. The overall objective of Phase 2, provided a successful competitive down-selection, is to execute design, construction and operations of three capital projects: (1) the CO{sub 2} capture and compression equipment, (2) a Connector Pipeline from the LLC Gasification Project to the Green Pipeline owned by Denbury and an affiliate of Denbury, and (3) a comprehensive MVA system at the Hastings oil field.« less

Measurements and models of CO2 and CH4 Flux in the Baltimore/Washington area.

NASA Astrophysics Data System (ADS)

Dickerson, R. R.; Ren, X.; Salawitch, R. J.; Ahn, D.; Karion, A.; Shepson, P. B.; Whetstone, J. R.; Martin, C.

2017-12-01

Direct measurements of concentrations of pollutants such as CO2 and CH4 can be combined with wind fields to determine the flux of these species and to evaluate emissions inventories or models. The mass balance approach, assumng linear flow into and out of a volume set over a city, works best where wind fields are simplest. Over typical American east coast cities, upwind sources and complex circulation (e.g., the sea breeze) complicate such analyses. We will present findings from a coupled measurement and modeling project involving a network of surface-based tower measurements, aircraft observations, and remote sensing that constrain model calculations. Summer and winter scenarios are contrasted, and results help evaluate the emissions of short-lived pollutants. Determinations are compared to several emissions inventories and are being used to help States evaluate evaluate plans for pollution control.

75 FR 54805 - Approval and Promulgation of Air Quality Implementation Plans; Minnesota; Carbon Monoxide (CO...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-09-09

... Promulgation of Air Quality Implementation Plans; Minnesota; Carbon Monoxide (CO) Limited Maintenance Plan for... June 16, 2010, to revise the Minnesota State Implementation Plan (SIP) for carbon monoxide (CO) under the Clean Air Act (CAA). The State has submitted a limited maintenance plan for CO showing continued...

18. 'Erection Plan for 3 180'61/2' End Pins S. ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

18. 'Erection Plan for 3 - 180'-6-1/2' End Pins S. Track Thro. Spans, 10th, 11th & 13th Crossings of Sacramento River, Pacific Systems, Southern Pacific Co. Phoenix Bridge Co., C. O. #839, Drawing #9, Scale = 1/8' & 1' = 1 ft., Eng'r-Chas. Scheidl, Drafts. H. O. McG., April 16th, 1901.' - Southern Pacific Railroad Shasta Route, Bridge No. 310.58, Milepost 310.58, Sims, Shasta County, CA

11. 'Erection Plan, 1 208'101/2' C. to C. End ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

11. 'Erection Plan, 1 - 208'-10-1/2' C. to C. End Pins S. Tr. Thro. Skew Span, 6th Crossing Sacramento River, Pacific System, Southern Pacific Company, The Phoenix Bridge Co., C.O. 836D, Drawing No. 13, Scale 1/8' = 1'0', Engineer, B.M. Krohn, Draftsman, W.L. Clegg, Date, May 25th 1901' - Southern Pacific Railroad Shasta Route, Bridge No. 301.85, Milepost 301.85, Pollard Flat, Shasta County, CA

Relevant Studies for NERC’s Analysis of EPA's Clean Power Plan 111 (d) Compliance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ahlstrom, Mark; Smith, Charlie; Piwko, Dick

2015-06-12

The purpose of this paper is to describe multiple studies of wind and solar integration that have found CO 2 reductions of approximately 30%. These studies can be viewed in several ways, including as viable paths to compliance with the EPA rule, alternative ''bookend cases'' to compare to compliance based largely on natural gas, or something in between. The studies in this paper represent a body of work that can help inform the public discussion surrounding the cost and reliability impacts of complying with the proposed EPA CPP.

78 FR 45 - Approval and Promulgation of Implementation Plans; Georgia: New Source Review-Prevention of...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-01-02

... manure management processes; CO 2 from fermentation during ethanol production or other industrial fermentation processes; CO 2 from combustion of the biological fraction of municipal solid waste or biosolids...

Using the Bongwana natural CO2 release to understand leakage processes and develop monitoring

NASA Astrophysics Data System (ADS)

Jones, David; Johnson, Gareth; Hicks, Nigel; Bond, Clare; Gilfillan, Stuart; Kremer, Yannick; Lister, Bob; Nkwane, Mzikayise; Maupa, Thulani; Munyangane, Portia; Robey, Kate; Saunders, Ian; Shipton, Zoe; Pearce, Jonathan; Haszeldine, Stuart

2016-04-01

Natural CO2 leakage along the Bongwana Fault in South Africa is being studied to help understand processes of CO2 leakage and develop monitoring protocols. The Bongwana Fault crops out over approximately 80 km in KwaZulu-Natal province, South Africa. In outcrop the fault is expressed as a broad fracture corridor in Dwyka Tillite, with fractures oriented approximately N-S. Natural emissions of CO2 occur at various points along the fault, manifest as travertine cones and terraces, bubbling in the rivers and as gas fluxes through soil. Exposed rock outcrop shows evidence for Fe-staining around fractures and is locally extensively kaolinitised. The gas has also been released through a shallow water well, and was exploited commercially in the past. Preliminary studies have been carried out to better document the surface emissions using near surface gas monitoring, understand the origin of the gas through major gas composition and stable and noble gas isotopes and improve understanding of the structural controls on gas leakage through mapping. In addition the impact of the leaking CO2 on local water sources (surface and ground) is being investigated, along with the seismic activity of the fault. The investigation will help to build technical capacity in South Africa and to develop monitoring techniques and plans for a future CO2 storage pilot there. Early results suggest that CO2 leakage is confined to a relatively small number of spatially-restricted locations along the weakly seismically active fault. Fracture permeability appears to be the main method by which the CO2 migrates to the surface. The bulk of the CO2 is of deep origin with a minor contribution from near surface biogenic processes as determined by major gas composition. Water chemistry, including pH, DO and TDS is notably different between CO2-rich and CO2-poor sites. Soil gas content and flux effectively delineates the fault trace in active leakage sites. The fault provides an effective testing ground for field-based monitoring with results to date indicating the methods and technologies tested successfully detect leaking CO2. Further work will investigate the source of the CO2 and attempt to quantify CO2 flux rates and detection thresholds.

Spatial Variability of Trace Gases During DISCOVER-AQ: Planning for Geostationary Observations of Atmospheric Composition

NASA Technical Reports Server (NTRS)

Follette-Cook, Melanie B.; Pickering, K.; Crawford, J.; Appel, W.; Diskin, G.; Fried, A.; Loughner, C.; Pfister, G.; Weinheimer, A.

2015-01-01

Results from an in-depth analysis of trace gas variability in MD indicated that the variability in this region was large enough to be observable by a TEMPO-like instrument. The variability observed in MD is relatively similar to the other three campaigns with a few exceptions: CO variability in CA was much higher than in the other regions; HCHO variability in CA and CO was much lower; MD showed the lowest variability in NO2All model simulations do a reasonable job simulating O3 variability. For CO, the CACO simulations largely under over estimate the variability in the observations. The variability in HCHO is underestimated for every campaign. NO2 variability is slightly overestimated in MD, more so in CO. The TX simulation underestimates the variability in each trace gas. This is most likely due to missing emissions sources (C. Loughner, manuscript in preparation).Future Work: Where reasonable, we will use these model outputs to further explore the resolvability from space of these key trace gases using analyses of tropospheric column amounts relative to satellite precision requirements, similar to Follette-Cook et al. (2015).

The GGOS Bureau of Networks and Observations: an update on the Space Geodesy Network and the New Implementation Plan for 2017 -18

NASA Astrophysics Data System (ADS)

Pearlman, Michael R.; Ma, Chopo; Neilan, Ruth; Noll, Carey; Pavlis, Erricos; Saunier, Jérôme; Schoene, Tilo; Barzaghi, Riccardo; Thaller, Daniela; Bergstrand, Sten; Mueller, Juergen

2017-04-01

Working with the IAG geometric services (VLBI, SLR, GNSS, and DORIS) the Bureau continues to advocate for the expansion and upgrade of the space geodesy networks for the maintenance and improvement of the reference frame and other application, and for the extension and integration with other techniques. New sites are being established following the GGOS concept of "core" and co-location sites; new technologies are being implemented to enhance performance in data yield as well as accuracy. In particular, several groups are undertaking initiatives and seeking partnerships to update existing sites and expand the networks in geographic areas void of coverage. The Bureau continues to meet with organizations to discuss possibilities of new and expanded participation and to promote the concept of partnerships. The Bureau provides the opportunity for representatives from the services to meet and share progress and plans, and to discuss issues of common interest. The Bureau monitors the status and projects the evolution of the network based on information from the current and expected future participants. Of particular interest at the moment is the integration of gravity and tide gauge networks. The Committees and Joint Working Groups play an essential role in the Bureau activity. The Standing Committee on Performance Simulations and Architectural Trade-off (PLATO) uses simulation and analysis techniques to project future network capability and to examine trade-off options. The Committee on Data and Information is working on a strategy for a GGOS metadata system on a near term plan for data products and a more comprehensive longer-term plan for an all-inclusive system. The Committee on Satellite Missions is working to enhance communication with the space missions, to advocate for missions that support GGOS goals and to enhance ground systems support. The IERS Working Group on Site Survey and Co-location (also participating in the Bureau) is working to enhance standardization in procedures, outreach and to encourage new survey groups to participate, and improve procedures to determine systems reference points. The 2017-2018 Implementation Plan for the GGOS Bureau of Networks and Observations has been posted on the GGOS website. We will outline progress over the past two years and discuss the status of the network and updated plan.

Policy Choice for Urban Low-carbon transportation in Beijing: Scenario Analysis Based on LEAP model

NASA Astrophysics Data System (ADS)

Zhang, Yu

2016-04-01

Beijing is a fast developing megacity with serious traffic problems, such as high energy consumption, high CO2 emission and traffic congestion. The coming 13th Five-Year Plan for Beijing economic and social development will focus on the low-carbon transportation policy to achieve the urban traffic sustainable development. In order to improve the feasibility of urban low-carbon transportation policies, this paper analyzes the future trends of CO2 emissions from transportation of Beijing. Firstly, five policies scenarios are developed according to the coming Beijing 13th Five-Year Plan, including the "Business As Usual (BAU)", the "Public Transportation Priority(PTP)", the "New Energy Vehicle(NEV)", the "Active Transportation(AT)", the "Private Car Regulation(PCR)" and the "Hybrid Policy(HP)". Then the Long-range Energy Alternatives Planning System(LEAP model) framework is adopted to estimate CO2 emission under given policies scenarios up to year 2020 and analyze the implications. The results demonstrate that the low-carbon transportation policies can reduce CO2 emission effectively. Specifically, the "Hybrid Policy(HP)" has the best performance. In terms of single policy effect, the "Private Car Regulation(PCR)" comes first followed by the "Public Transportation Priority(PTP)".

Revitalizing communities together: the shared values, goals, and work of education, urban planning, and public health.

PubMed

Cohen, Alison Klebanoff; Schuchter, Joseph W

2013-04-01

Inequities in education, the urban environment, and health co-exist and mutually reinforce each other. Educators, planners, and public health practitioners share commitments to place-based, participatory, youth-focused, and equitable work. They also have shared goals of building community resilience, social capital, and civic engagement. Interdisciplinary programs that embody these shared values and work towards these shared goals are emerging, including school-based health centers, full-service community schools, community health centers, Promise Neighborhoods, and Choice Neighborhoods. The intersection of these three fields represents an opportunity to intervene on social determinants of health. More collaborative research and practice across public health, education, and planning should build from the shared values identified to continue to address these common goals.

Training Planning and Working Memory in Third Graders

ERIC Educational Resources Information Center

Goldin, Andrea Paula; Segretin, Maria Soledad; Hermida, Maria Julia; Paz, Luciano; Lipina, Sebastian Javier; Sigman, Mariano

2013-01-01

Working memory and planning are fundamental cognitive skills supporting fluid reasoning. We show that 2 games that train working memory and planning skills in school-aged children promote transfer to 2 different tasks: an attentional test and a fluid reasoning test. We also show long-term improvement of planning and memory capacities in…

40 CFR 52.123 - Approval status.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Urban Planning Area for O3. (e) The Administrator finds that the plan does not satisfy all the... pollutants listed in this paragraph. (1) Maricopa County Urban Planning Area for CO and TSP. (2) [Reserved... TSP, the portion of the Tucson TSP Air Planning Area falling both within the area described by...

40 CFR 52.123 - Approval status.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Urban Planning Area for O3. (e) The Administrator finds that the plan does not satisfy all the... pollutants listed in this paragraph. (1) Maricopa County Urban Planning Area for CO and TSP. (2) [Reserved... TSP, the portion of the Tucson TSP Air Planning Area falling both within the area described by...

Supersonic Post-Combustion Inertial CO 2 Extraction System Final Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Balepin, Vladimir

This report summarizes the effort carried out under NETL contract DE- FE0013122 from 1 October 2013 to 31 March 2017. As described in this document, technical challenges realized during the performance of this project resulted in completion of only the first two of three planned budget periods. Despite this outcome, substantial progress was made toward understanding and maturing the CO 2 capture technology under consideration and considerable future promise remains for applications requiring lower CO 2 capture and/or lower CO 2.

Carbon Flux Signal Detection for the ASCENDS mission

NASA Astrophysics Data System (ADS)

Hammerling, D.; Michalak, A. M.; Kawa, S. R.; Doney, S. C.; Schaefer, K. M.

2012-12-01

Emerging satellite observations of carbon dioxide (CO2) offer novel and distinctive opportunities for quantifying the carbon cycle, which is an important scientific and societal challenge with anthropogenic CO2 emissions and accumulation rates in the atmosphere still on the rise. One mission in the planning stage is the Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) mission, which is a laser CO2 sensing mission with an anticipated launch date around 2022. Notable features of this mission include the ability to sample at night and at high latitudes, which passive missions cannot do because of their reliance on reflected sunlight. In this work we present findings from signal detection studies, i.e. experiments that investigate if perturbations in carbon fluxes can be detected in the ASCENDS observations of atmospheric CO2 concentrations. The experiments employ a realistic synthetic-data setup using the PCTM/GEOS-5/CASA GFED CO2 flux and transport model in combination with CALIPSO and MODIS measurements. The signal detection approach applied uses a geostatistical mapping methodology that can leverage the information content of nearby observations, thereby potentially facilitating enhanced signal detection. The specific perturbation scenarios investigated are: carbon release from the melting of permafrost in the high Northern latitudes, the shifting of fossil fuel emissions from Europe to P.R. China, and natural variability in the CO2 fluxes in the Southern Ocean. Results indicate that the permafrost carbon release is comparatively easy to detect, while the Southern Ocean change is more challenging. The ability to detect a shift in fossil fuel emissions strongly depends on its magnitude: a 50% decrease in Europe is easily detectible, while a 20% decrease is only marginally so. A key conclusion is that the optimal signal detection strategy is intrinsically linked to how the carbon flux perturbations translate into atmospheric CO2 concentrations, which varies significantly among the investigated scenarios.

Impact of co-morbid attention-deficit and hyperactivity disorder on cognitive function in male children with Tourette syndrome: A controlled study.

PubMed

Termine, Cristiano; Luoni, Chiara; Fontolan, Stefania; Selvini, Claudia; Perego, Livia; Pavone, Francesca; Rossi, Giorgio; Balottin, Umberto; Cavanna, Andrea E

2016-09-30

Tourette syndrome (TS) and attention-deficit and hyperactivity disorder (ADHD) are co-morbid neurodevelopmental conditions affecting more commonly male patients. We set out to determine the impact of co-morbid ADHD on cognitive function in male children with TS by conducting a controlled study. Participants included four matched groups of unmedicated children (age range 6-15 years): TS (n=13), TS+ADHD (n=8), ADHD (n=39), healthy controls (n=66). Following clinical assessment, each participant completed a battery of tests from the Wechsler Intelligence Scale for Children-III, the Italian Battery for ADHD, the Tower of London test, the Corsi test, and the Digit Span test. All patient groups reported significantly lower scores than healthy controls across the neuropsychological tests involving executive functions. The TS+ADHD group was the most severely affected, followed by the ADHD group and the TS group, particularly in the tests assessing planning ability, inhibitory function, working memory and visual attention, but not auditory attention. Problems in executive functions are more common in patients with neurodevelopmental disorders than controls. Deficits in planning ability, inhibitory function, working memory and visual attention reported by children with TS appear to be more strongly related to the presence of co-morbid ADHD symptoms than core TS symptoms. Copyright © 2016 Elsevier Ireland Ltd. All rights reserved.

Implementation of a Fiber Raman Amplifier for CW-IM Measurements of Atmospheric Oxygen at 1.26 Microns

NASA Astrophysics Data System (ADS)

Dobler, J. T.; Nagel, J.; Temyanko, V.; Zaccheo, S.; Browell, E. V.; Kooi, S. A.

2011-12-01

Starting in February 2009 ITT, along with our partners at TIPD, AER and NASA LaRC, has been working to develop a fiber Raman amplifier at a wavelength near 1.26 microns, and evaluate its performance for measuring atmospheric O2 remotely. Two prototype amplifiers have been built and integrated into an existing continuous wave (CW) intensity modulated (IM) engineering development unit (EDU), developed at ITT for the measurement of CO2, in order to demonstrate the CW-IM measurement of atmospheric O2. The CO2 and O2 measurements are being evaluated for application to the active sensing of CO2 emissions over nights days and seasons (ASCENDS) mission described in the 2007 National Research Council's Decadal Survey. The O2 measurement takes advantage of the fact that O2 is a well mixed gas to allow the determination of the CO2 dry air mixing ratio, which is the required product for the ASCENDS mission. The Raman amplifier development has been focused on optimizing fiber designs to limit stimulated Brillouin scattering (SBS), which is a nonlinear process typically limiting this type of amplifier from generating high power narrow linewidth outputs. This work has centered around two approaches, varying the fiber core diameter to broaden the Brillouin gain curve and designing transverse fiber doping profiles which serve to separate the acoustic and optical wave overlap responsible for SBS. The most recent amplifier is producing 1.5 Watts of average power while maintaining the narrow linewidth of the seed laser (~3 MHz). The latest amplifier has been integrated with the CO2 EDU and initial ground testing was performed at the ITT ground test facility in New Haven, Indiana. The transmitter has subsequently been integrated into a NASA DC-8 rack and is currently being flown on the NASA DC-8. We discuss results from these ground and flight measurements in addition to the discussion of the amplifier design and our plans for scaling the design to space. This document is not subject to the controls of the International Traffic in Arms Regulations (ITAR) or the Export Administration Regulations (EAR).

77 FR 23178 - Approval and Promulgation of Air Quality Implementation Plans; Virginia; Deferral for CO2

Federal Register 2010, 2011, 2012, 2013, 2014

2012-04-18

... other than fossil fuels and mineral sources of carbon. Examples of ``biogenic CO 2 emissions'' include... biomass can be part of the national strategy to reduce dependence on fossil fuels. Efforts are underway at.... In that event, Virginia may revise its SIP accordingly. For stationary sources co-firing fossil fuel...

The Influence of CO2 Admixtures on the Product Composition in a Nitrogen-Methane Atmospheric Glow Discharge Used as a Prebiotic Atmosphere Mimic.

PubMed

Mazankova, V; Torokova, L; Krcma, F; Mason, N J; Matejcik, S

2016-11-01

This work extends our previous experimental studies of the chemistry of Titan's atmosphere by atmospheric glow discharge. The Titan's atmosphere seems to be similarly to early Earth atmospheric composition. The exploration of Titan atmosphere was initiated by the exciting results of the Cassini-Huygens mission and obtained results increased the interest about prebiotic atmospheres. Present work is devoted to the role of CO 2 in the prebiotic atmosphere chemistry. Most of the laboratory studies of such atmosphere were focused on the chemistry of N 2  + CH 4 mixtures. The present work is devoted to the study of the oxygenated volatile species in prebiotic atmosphere, specifically CO 2 reactivity. CO 2 was introduced to the standard N 2  + CH 4 mixture at different mixing ratio up to 5 % CH 4 and 3 % CO 2 . The reaction products were characterized by FTIR spectroscopy. This work shows that CO 2 modifies the composition of the gas phase with the detection of oxygenated compounds: CO and others oxides. There is a strong influence of CO 2 on increasing concentration other products as cyanide (HCN) and ammonia (NH 3 ).

In silico discovery of metal-organic frameworks for precombustion CO2 capture using a genetic algorithm

PubMed Central

Chung, Yongchul G.; Gómez-Gualdrón, Diego A.; Li, Peng; Leperi, Karson T.; Deria, Pravas; Zhang, Hongda; Vermeulen, Nicolaas A.; Stoddart, J. Fraser; You, Fengqi; Hupp, Joseph T.; Farha, Omar K.; Snurr, Randall Q.

2016-01-01

Discovery of new adsorbent materials with a high CO2 working capacity could help reduce CO2 emissions from newly commissioned power plants using precombustion carbon capture. High-throughput computational screening efforts can accelerate the discovery of new adsorbents but sometimes require significant computational resources to explore the large space of possible materials. We report the in silico discovery of high-performing adsorbents for precombustion CO2 capture by applying a genetic algorithm to efficiently search a large database of metal-organic frameworks (MOFs) for top candidates. High-performing MOFs identified from the in silico search were synthesized and activated and show a high CO2 working capacity and a high CO2/H2 selectivity. One of the synthesized MOFs shows a higher CO2 working capacity than any MOF reported in the literature under the operating conditions investigated here. PMID:27757420

Shaping a National Urban Agenda. The Role of the Association of Collegiate Schools of Planning. Subcommittee Report on a National Urban Policy. CAAS Special Publication Volume 9.

ERIC Educational Resources Information Center

California Univ., Los Angeles. Afro-American Studies Center.

A subcommittee of the Association of Collegiate Schools of Planning (ACSP) was charged with the task of developing a national agenda for America's cities and regions. This report consists of the working paper developed by the co-chairs of the subcommittee and the position papers committee members produced. It is intended to be a starting point for…

Optimizing and Quantifying CO 2 Storage Resource in Saline Formations and Hydrocarbon Reservoirs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bosshart, Nicholas W.; Ayash, Scott C.; Azzolina, Nicholas A.

In an effort to reduce carbon dioxide (CO 2) emissions from large stationary sources, carbon capture and storage (CCS) is being investigated as one approach. This work assesses CO 2 storage resource estimation methods for deep saline formations (DSFs) and hydrocarbon reservoirs undergoing CO 2 enhanced oil recovery (EOR). Project activities were conducted using geologic modeling and simulation to investigate CO 2 storage efficiency. CO 2 storage rates and efficiencies in DSFs classified by interpreted depositional environment were evaluated at the regional scale over a 100-year time frame. A focus was placed on developing results applicable to future widespread commercial-scalemore » CO 2 storage operations in which an array of injection wells may be used to optimize storage in saline formations. The results of this work suggest future investigations of prospective storage resource in closed or semiclosed formations need not have a detailed understanding of the depositional environment of the reservoir to generate meaningful estimates. However, the results of this work also illustrate the relative importance of depositional environment, formation depth, structural geometry, and boundary conditions on the rate of CO 2 storage in these types of systems. CO 2 EOR occupies an important place in the realm of geologic storage of CO 2, as it is likely to be the primary means of geologic CO 2 storage during the early stages of commercial implementation, given the lack of a national policy and the viability of the current business case. This work estimates CO 2 storage efficiency factors using a unique industry database of CO 2 EOR sites and 18 different reservoir simulation models capturing fluvial clastic and shallow shelf carbonate depositional environments for reservoir depths of 1219 and 2438 meters (4000 and 8000 feet) and 7.6-, 20-, and 64-meter (25-, 66,- and 209-foot) pay zones. The results of this work provide practical information that can be used to quantify CO 2 storage resource estimates in oil reservoirs during CO 2 EOR operations (as opposed to storage following depletion) and the uncertainty associated with those estimates.« less

78 FR 19522 - Notice of Public Meeting, Northwest Colorado Resource Advisory Council

Federal Register 2010, 2011, 2012, 2013, 2014

2013-04-01

... White River Field Office, 220 E. Market St., Meeker, CO. FOR FURTHER INFORMATION CONTACT: David Boyd... the BLM National Sage Grouse Conservation Strategy, working group reports, recreation, fire management... National Conservation Area, Kremmling Resource Management Plan revision and the White River Field Office...

Implications of MODIS impression of aerosol loading over urban and rural settlements in Nigeria: Possible links to energy consumption patterns in the country

NASA Astrophysics Data System (ADS)

Dom Onyeuwaoma, Nnaemeka

2016-07-01

A study of aerosol loading patterns in some selected cities in Nigeria was carried out using MODIS, TOMS/OMI AND AIRS satellite imageries for a period of 10 years. The results showed that an aerosol optical depth (AOD) loading obtained ranged from 0.02-0.9, UV aerosol index (AI) and carbon monoxide (CO) results ranged from 1.32- 2.43 and 2.22-2.6 molecule/cm2, respectively. The CO data was used to infer the presence of carbonecous aerosols from biomass, fossil combustion and industrial activities. This result indicates that areas with higher AOD and AI do not correspond in high CO loading. From the HYSPLIT and HAT analysis conducted it showed that advection plays important role in the dispersion of aerosols. This implies that aerosols can reside in a place remote from where they are generated. Also, the high concentration of CO aerosol in the southern cities suggests a high rate of industrial pollution as a result of fossil fuel burning, vehicular emissions, high population density and gas flaring. Therefore, emphasis should be on the need to switch to renewable energy options as an alternative to fossil fuel. Furthermore, plans for mitigations should not be limited to industrialized cities only but extended to other cities which might be bearing the real brunt of industrial emissions as shown in this work.

Measurement of Carbon Dioxide Column via Space Borne Laser Absorption

NASA Technical Reports Server (NTRS)

Heaps, WIlliam S.

2007-01-01

In order to better understand the budget of carbon dioxide in the Earth's atmosphere it is necessary to develop a global high precision understanding of the carbon dioxide column. In order to uncover the 'missing sink that is responsible for the large discrepancies in the budget as we presently understand it calculation has indicated that measurement accuracy on the order of 1 ppm is necessary. Because typical column average CO2 has now reached 380 ppm this represents a precision on the order of .25% for these column measurements. No species has ever been measured from space at such a precision. In recognition of the importance of understanding the CO2 budget in order to evaluate its impact on global warming the National Research Council in its decadal survey report to NASA recommended planning for a laser based total CO2 mapping mission in the near future. The extreme measurement accuracy requirements on this mission places very strong requirements on the laser system used for the measurement. This work presents an analysis of the characteristics necessary in a laser system used to make this measurement. Consideration is given to the temperature dependence, pressure broadening, and pressure shift of the CO2 lines themselves and how these impact the laser system characteristics Several systems for meeting these requirements that are under investigation at various institutions in the US as well as Europe will be discussed.

The planning of a passive seismic experiment: the Ketzin case

NASA Astrophysics Data System (ADS)

Rossi, G.; Petronio, L.

2009-04-01

In the last years, it has been recognized the importance of using microseismic activity data to gain information on the state and dynamics of a reservoir, notwithstanding the difficulties of recording, localizing the events, interpret them correctly, in terms of developing fractures, or thermal effects. The increasing number of CO2 storage experiments, with the necessity of providing efficient, economic, and long-term monitoring methods, both in the injection and post-injection phases, further encourage the development and improvement of recording and processing techniques. Microseismic signals are typically recorded with downhole sensors. Monitoring with surface sensors is problematic due to increased noise levels and signal attenuation particularly in the near surface. The actual detection distance depends on background noise conditions, seismic attenuation and the microseismic source strength. In the frame of the European project Co2ReMoVe and of the European Network of Excellence Co2GeoNet, a passive seismic experiment was planned in the Ketzin site for geological storage of CO2, a former gas store near Potsdam, object of the CO2SINK European project and inserted also in the European project Co2ReMoVe. Aim of the survey is to complement the CO2-SINK active seismic downhole experiments, adding precious information on the microseismicity induced by stress field changes at the reservoir level and in the overburden, due to the CO2 injection. The baseline survey was done in May 2008 by the Istituto Nazionale di Oceanografia e di Geofisica Sperimentale-OGS (Italy), with the support of the Deutsches GeoForschungsZentrum-GFZ (Germany) and the collaboration of the Institut für Geowissenschaftliche Gemeinschaftsaufgaben-GGA (Germany), shortly before the starting of the CO2 injection (June 30th 2008). A continuous monitoring (about 5 days) was performed by 2 downhole 3C geophones, and 3 surface 3C geophones located around the wells. This paper, based on the analysis of the baseline data, is focused on the design and planning of the next seismic passive surveys, optimizing the recording geometry and instrumentation, to record the microseismic events that could be induced by the redistribution of the stresses following the injection, and help the understanding of the injected CO2 behaviour.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Safigholi, H; Mashouf, S; Soliman, A

Purpose: To evaluate the improvement in plan quality when various combinations of 192Ir, 60Co, and 169Yb sources are used in combination with a novel direction modulated brachytherapy (DMBT) tandem applicator for high dose rate brachytherapy of cervical cancer. Methods: The proposed DMBT tandem applicator is designed for image-guided adaptive brachytherapy (IGABT), especially MRI, of cervical cancer. It has 6 peripheral holes of 1.3-mm width, grooved along a 5.4-mm diameter nonmagnetic tungsten alloy rod of density 18.0 g/cc, capable of generating directional dose profiles - leading to enhanced dose sculpting capacity through inverse planning. Monte Carlo simulations of the three HDRmore » sources individually inside the DMBT applicator were performed and imported into an in-house developed inverse optimization code. We then performed inverse planning with 14 cervical cancer patients enrolled in EMBRACE study. In all patients, 3D MRI-based planning was performed while utilizing 1) tandem-ring and needles attached-to-ring (7 patients) and 2) tandem-ring and needles both attached-to-ring and free-hand-loaded (7 patients), in accordance with the GEC-ESTRO recommendations. All plans were normalized to receive the same HRCTV D90 and DVH parameters were evaluated. Results: The DMBT tandem was used in all cases. Overall, the combined use of two sources (192Ir-60Co and 192Ir-169Yb, but not 60Co-169Yb) generally produced better quality plans than with the 192Ir source alone in terms of sparing OARs. For example, up to 3.5, 4.4, and 3.9% individual reductions in D2cc were observed for the bladder, rectum, and sigmoid, respectively, between 192Ir-60Co and 192Ir-only plans for patient cases in #1. While up to 5.5, 2.0, and 5.7% individual reductions were observed for patient cases in #2. Conclusion: We have demonstrated that, in addition to “directional modulation” of DMBT, use of multiple sources with sufficient differences in energy can be utilized to achieve additional improvement in plan quality for IGABT of cervical cancer.« less

IPPF Co-operative Information Service. February 1979.

ERIC Educational Resources Information Center

International Planned Parenthood Federation, London (England).

Bibliographic entries are classified into nine categories: (1) General Reference; (2) International Planned Parenthood Federation; (3) Family Planning; (4) Bio-Medical Research; (5) Social Sciences Related to Family Planning; (6) Education and Training; (7) Information and Communication; (8) International Organizations and Conferences; and (9)…

A Library of ATMO Forward Model Transmission Spectra for Hot Jupiter Exoplanets

NASA Technical Reports Server (NTRS)

Goyal, Jayesh M.; Mayne, Nathan; Sing, David K.; Drummond, Benjamin; Tremblin, Pascal; Amundsen, David S.; Evans, Thomas; Carter, Aarynn L.; Spake, Jessica; Baraffe, Isabelle;

A library of ATMO forward model transmission spectra for hot Jupiter exoplanets

NASA Astrophysics Data System (ADS)

Goyal, Jayesh M.; Mayne, Nathan; Sing, David K.; Drummond, Benjamin; Tremblin, Pascal; Amundsen, David S.; Evans, Thomas; Carter, Aarynn L.; Spake, Jessica; Baraffe, Isabelle; Nikolov, Nikolay; Manners, James; Chabrier, Gilles; Hebrard, Eric

2018-03-01

We present a grid of forward model transmission spectra, adopting an isothermal temperature-pressure profile, alongside corresponding equilibrium chemical abundances for 117 observationally significant hot exoplanets (equilibrium temperatures of 547-2710 K). This model grid has been developed using a 1D radiative-convective-chemical equilibrium model termed ATMO, with up-to-date high-temperature opacities. We present an interpretation of observations of 10 exoplanets, including best-fitting parameters and χ2 maps. In agreement with previous works, we find a continuum from clear to hazy/cloudy atmospheres for this sample of hot Jupiters. The data for all the 10 planets are consistent with subsolar to solar C/O ratio, 0.005 to 10 times solar metallicity and water rather than methane-dominated infrared spectra. We then explore the range of simulated atmospheric spectra for different exoplanets, based on characteristics such as temperature, metallicity, C/O ratio, haziness and cloudiness. We find a transition value for the metallicity between 10 and 50 times solar, which leads to substantial changes in the transmission spectra. We also find a transition value of C/O ratio, from water to carbon species dominated infrared spectra, as found by previous works, revealing a temperature dependence of this transition point ranging from ˜0.56 to ˜1-1.3 for equilibrium temperatures from ˜900 to ˜2600 K. We highlight the potential of the spectral features of HCN and C2H2 to constrain the metallicities and C/O ratios of planets, using James Webb Space Telescope (JWST) observations. Finally, our entire grid (˜460 000 simulations) is publicly available and can be used directly with the JWST simulator PandExo for planning observations.

Generating Co-Management at Kasha Katuwe Tent Rocks National Monument, New Mexico

NASA Astrophysics Data System (ADS)

Pinel, Sandra Lee; Pecos, Jacob

2012-03-01

Collaborative planning theory and co-management paradigms promise conflict prevention and the incorporation of indigenous knowledge into plans. Critics argue that without devolved power to culturally legitimate institutions, indigenous perspectives are marginalized. Co-management practice in North America is largely limited to treaty-protected fish and wildlife because federal agencies cannot devolve land management authority. This paper explores why the Pueblo de Cochiti, a federally recognized American Indian Tribe, and the U.S. Bureau of Land Management sustained an rare joint management agreement for the Kasha-Katuwe Tent Rocks National Monument in New Mexico despite a history of conflict over federal control of customary tribal lands that discouraged the Pueblo from working with federal agencies. Based on the participant interviews and documents, the case suggests that clear agreements, management attitudes, and the direct representation of indigenous forms of government helped achieve presumed co-management benefits. However, parties enter these agreements strategically. We should study, not assume, participant goals in collaborative processes and co-management institutions and pay special attention to the opportunities and constraints of federal laws and institutional culture for collaborative resource management with tribal and local communities.

Two-Stage, Integrated, Geothermal-CO2 Storage Reservoirs: An Approach for Sustainable Energy Production, CO2-Sequestration Security, and Reduced Environmental Risk

DOE Office of Scientific and Technical Information (OSTI.GOV)

Buscheck, T A; Chen, M; Sun, Y

2012-02-02

We introduce a hybrid two-stage energy-recovery approach to sequester CO{sub 2} and produce geothermal energy at low environmental risk and low cost by integrating geothermal production with CO{sub 2} capture and sequestration (CCS) in saline, sedimentary formations. Our approach combines the benefits of the approach proposed by Buscheck et al. (2011b), which uses brine as the working fluid, with those of the approach first suggested by Brown (2000) and analyzed by Pruess (2006), using CO{sub 2} as the working fluid, and then extended to saline-formation CCS by Randolph and Saar (2011a). During stage one of our hybrid approach, formation brine,more » which is extracted to provide pressure relief for CO{sub 2} injection, is the working fluid for energy recovery. Produced brine is applied to a consumptive beneficial use: feedstock for fresh water production through desalination, saline cooling water, or make-up water to be injected into a neighboring reservoir operation, such as in Enhanced Geothermal Systems (EGS), where there is often a shortage of a working fluid. For stage one, it is important to find economically feasible disposition options to reduce the volume of brine requiring reinjection in the integrated geothermal-CCS reservoir (Buscheck et al. 2012a). During stage two, which begins as CO{sub 2} reaches the production wells; coproduced brine and CO{sub 2} are the working fluids. We present preliminary reservoir engineering analyses of this approach, using a simple conceptual model of a homogeneous, permeable CO{sub 2} storage formation/geothermal reservoir, bounded by relatively impermeable sealing units. We assess both the CO{sub 2} sequestration capacity and geothermal energy production potential as a function of well spacing between CO{sub 2} injectors and brine/CO{sub 2} producers for various well patterns and for a range of subsurface conditions.« less

Minimize Solvent Oxidation with NO X Pre-Scrubbing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sexton, Andrew; Sachde, Darshan; Vance, Austyn

A novel method to remove nitrogen dioxide (NO 2) from the flue gas of coal-fired power plants with CO 2 capture was further developed for commercial implementation. The technology leverages the equipment and chemistry in an existing (sulfur dioxide) SO 2 polishing scrubber upstream of the main CO 2 capture unit to remove the NO 2, preventing degradation of the CO 2 capture solvent and formation of nitrosamines (environmental hazards). The research in this report focuses on further evaluation of the chemical additives and operating conditions associated with the NO 2 removal process to define conditions for commercial scale testingmore » and deployment. Experimental work systematically evaluated a series of potential additives to minimize the oxidation of sulfite in a representative SO 2 pre-scrubber solution (sulfite, in turn, absorbs NO 2). The additive combinations and concentrations were varied alongside important process conditions such as temperature, oxygen concentration, and metals present in solution to mimic the conditions expected in a commercial system. Important results of the parametric experimental work include identifying a new, potent sulfite oxidation inhibitor, revealing the importance of combining inhibitors with metal chelating agents, validation of a low-cost additive process, and development of a new semi-empirical model to represent mechanisms associated with sulfite oxidation. In addition, the experimental work reveled the impact of operating at higher temperatures (representative of a field test unit), which will guide the selection and concertation of additives as well. Engineering analysis found that waste solutions from the pre-scrubber with NO 2 additives may potentially be integrated with existing processes on site (e.g., flue gas desulfurization unit). In addition, techno-economic analysis identified potential net savings as large as $1.30/tonne CO 2 captured and quantified the potential benefit of low cost additive options actively being pursued by the development team. Finally, the experimental results and engineering analysis supported the development of a detailed field testing plan and protocol to evaluate the technology at near-commercial scale. The field test preparation included development of procedures to introduce chemical additives to an existing SO 2 polishing unit and identification of representative flue gas conditions based on a review of existing plants. These activities will have direct bearing on operation and design of commercial units.« less

School and Community Connections for Collaboration and Coteaching

ERIC Educational Resources Information Center

Kilker, Jean

2012-01-01

School librarians should consistently build relationships to foster collaborative work. For the school librarian, collaboration begins with both the business side of the library and personal interactions. True collaborations involve varied partnerships with shared planning and responsibilities. A co-teacher is expected to share in all aspects of…

Micro-Cycle Teaching Experiments as a Vehicle for Professional Development

ERIC Educational Resources Information Center

Billings, Esther M. H.; Kasmer, Lisa

2015-01-01

This study used design experiments, specifically micro-cycle teaching experiments (MTE) as a catalyst for practice-based professional development. The MTE incorporated research-based characteristics of effective professional development: it was embedded in the teachers' daily work of planning and enacting lessons, co-constructed with the…

Planning an Anti-Racism Initiative. Project Change.

ERIC Educational Resources Information Center

Batten Susan T.; Leiderman, Sally A.

Project Change was launched by the Levi Strauss Foundation in 1991 as an initiative to address racial prejudice and institutional racism in communities in which Levi Strauss & Co. had facilities. Working with multiracial coalitions in Albuquerque (New Mexico), El Paso (Texas), Valdosta (Georgia), and Knoxville (Tennessee), the Foundation and…

Electrochemical air revitalization system optimization investigation

NASA Technical Reports Server (NTRS)

Woods, R. R.; Schubert, F. H.; Hallick, T. M.

1975-01-01

A program to characterize a Breadboard of an Electrochemical Air Revitalization System (BEARS) was successfully completed. The BEARS is composed of three components: (1) a water vapor electrolysis module (WVEM) for O2 production and partial humidity control, (2) an electrochemical depolarized carbon dioxide concentrator module (EDCM) for CO2 control, and (3) a power-sharing controller, designed to utilize the power produced by the EDCM to partially offset the WVEM power requirements. It is concluded from the results of this work that the concept of electrochemical air revitalization with power-sharing is a viable solution to the problem of providing a localized topping force for O2 generation, CO2 removal and partial humidity control aboard manned spacecraft. Continued development of the EARS concept is recommended, applying the operational experience and limits identified during the BEARS program to testing of a one-man capacity system and toward the development of advanced system controls to optimize EARS operation for given interfaces and requirements. Successful completion of this development will produce timely technology necessary to plan future advanced environmental control and life support system programs and experiments.

The CarbFix Pilot Project in Iceland - CO2 capture and mineral storage in basaltic rocks

NASA Astrophysics Data System (ADS)

Sigurdardottir, H.; Sigfusson, B.; Aradottir, E. S.; Gunnlaugsson, E.; Gislason, S. R.; Alfredsson, H. A.; Broecker, W. S.; Matter, J. M.; Stute, M.; Oelkers, E.

2010-12-01

The overall objective of the CarbFix project is to develop and optimize a practical and cost-effective technology for capturing CO2 and storing it via in situ mineral carbonation in basaltic rocks, as well as to train young scientist to carry the corresponding knowledge into the future. The project consists of a field injection of CO2 charged water at the Hellisheidi geothermal power plant in SW Iceland, laboratory experiments, numerical reactive transport modeling, tracer tests, natural analogue and cost analysis. The CO2 injection site is situated about 3 km south of the Hellisheidi geothermal power plant. Reykjavik Energy operates the power plant, which currently produces 60,000 tons/year CO2 of magmatic origin. The produced geothermal gas mainly consists of CO2 and H2S. The two gases will be separated in a pilot gas treatment plant, and CO2 will be transported in a pipeline to the injection site. There, CO2 will be fully dissolved in 20 - 25°C water during injection at 25 - 30 bar pressure, resulting in a single fluid phase entering the storage formation, which consists of relatively fresh basaltic lavas. The CO2 charged water is reactive and will dissolve divalent cations from the rock, which will combine with the dissolved carbon to form solid thermodynamically stable carbonate minerals. The injection test is designed to inject 2200 tons of CO2 per year. In the past three years the CarbFix project has been addressing background fluid chemistries at the injection site and characterizing the target reservoir for the planned CO2 injection. Numerous groundwater samples have been collected and analysed. A monitoring and accounting plan has been developed, which integrates surface, subsurface and atmospheric monitoring. A weather station is operating at the injection site for continuous monitoring of atmospheric CO2 and to track all key parameters for the injection. Environmental authorities have granted licenses for the CO2 injection and the use of tracers, based on the monitoring plan. Pipelines, injection and monitoring wells have been installed and equipment test runs are in the final phase. A bailer has been constructed to be used to retrieve samples at reservoir conditions. Hydrological parameters of a three dimensional field model have been calibrated and reactive transport simulations are ongoing. The key risks that the project is currently facing are technical and financial. Until now the project has been facing incidences that have already impacted the time schedule in the CarbFix project. Furthermore the project is facing world-wide exchange rate uncertainty plus the inherited uncertainty that innovative research projects contain. However, the CarbFix group remains optimistic that injection will start in near future.

Maintaining Adequate CO2 Washout for an Advanced EMU via a New Rapid Cycle Amine Technology

NASA Technical Reports Server (NTRS)

Chullen, Cinda; Conger, Bruce

2012-01-01

Over the past several years, NASA has realized tremendous progress in Extravehicular Activity (EVA) technology development. This has been evidenced by the progressive development of a new Rapid Cycle Amine (RCA) system for the Advanced Extravehicular Mobility Unit (AEMU) Portable Life Support Subsystem (PLSS). The PLSS is responsible for the life support of the crew member in the spacesuit. The RCA technology is responsible for carbon dioxide (CO2) and humidity control. Another aspect of the RCA is that it is on-back vacuum-regenerable, efficient, and reliable. The RCA also simplifies the PLSS schematic by eliminating the need for a condensing heat exchanger for humidity control in the current EMU. As development progresses on the RCA, it is important that the sizing be optimized so that the demand on the PLSS battery is minimized. As well, maintaining the CO2 washout at adequate levels during an EVA is an absolute requirement of the RCA and associated ventilation system. Testing has been underway in-house at NASA Johnson Space Center and analysis has been initiated to evaluate whether the technology provides exemplary performance in ensuring that the CO2 is removed sufficiently and the ventilation flow is adequate for maintaining CO2 washout in the AEMU spacesuit helmet of the crew member during an EVA. This paper will review the recent developments of the RCA unit, testing planned in-house with a spacesuit simulator, and the associated analytical work along with insights from the medical aspect on the testing. 1

Fossil Energy Planning for Navajo Nation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Acedo, Margarita

This project includes fossil energy transition planning to find optimal solutions that benefit the Navajo Nation and stakeholders. The majority of the tribe’s budget currently comes from fossil energy-revenue. The purpose of this work is to assess potential alternative energy resources including solar photovoltaics and biomass (microalgae for either biofuel or food consumption). This includes evaluating carbon-based reserves related to the tribe’s resources including CO 2 emissions for the Four Corners generating station. The methodology for this analysis will consist of data collection from publicly available data, utilizing expertise from national laboratories and academics, and evaluating economic, health, and environmentalmore » impacts. Finally, this report will highlight areas of opportunities to implement renewable energy in the Navajo Nation by presenting the technology requirements, cost, and considerations to energy, water, and environment in an educational structure.« less

Heat recovery from sorbent-based CO.sub.2 capture

DOEpatents

Jamal, Aqil; Gupta, Raghubir P

2015-03-10

The present invention provides a method of increasing the efficiency of exothermic CO.sub.2 capture processes. The method relates to withdrawing heat generated during the exothermic capture of CO.sub.2 with various sorbents via heat exchange with a working fluid. The working fluid is provided at a temperature and pressure such that it is in the liquid state, and has a vaporization temperature in a range such that the heat arising from the reaction of the CO.sub.2 and the sorbent causes a phase change from liquid to vapor state in whole or in part and transfers heat from to the working fluid. The resulting heated working fluid may subsequently be used to generate power.

How to make the pitch for a part-time workload.

PubMed

Kennedy, M M

2001-01-01

Are you planning on moving from full-time to part-time hours? You'll need a game plan to negotiate what you want, including establishing a timeline and agreeing on productivity expectations. If you can agree on a reasonable timeframe that doesn't inconvenience anyone or endanger important results or relationships, you have a high probability of getting your boss' okay. If you and the boss can't agree on what you must produce, don't consider part-time work unless you thrive on combat. Once you negotiate your new schedule, consider the issue of managing co-worker resentment. Here are the best hints for keeping co-worker envy and resentment at a manageable level: Don't be secretive; keep a low profile; attend all office frolics; and ask for a trial period.

The Vida Verde Women's Co-Op: Brazilian Immigrants Organizing to Promote Environmental and Social Justice

PubMed Central

Siqueira, Eduardo; Goldberg, Julia S.; Galvão, Heloisa; Chianelli, Mônica; Pirie, Alex

2009-01-01

We reviewed the key steps in the launch of the Vida Verde Women's Co-Op among Brazilian immigrant housecleaners in Somerville, MA. The co-op provides green housecleaning products, encourages healthy work practices, and promotes a sense of community among its members. We conducted in-depth interviews with 8 of the first co-op members, who reported a reduction in symptoms associated with the use of traditional cleaning agents and a new sense of mutual support. Critical to the co-op's success have been the supportive roles of its academic partners (Tufts University and the University of Massachusetts, Lowell), effective media outreach, and a focus on advancing social justice. Next steps include implementing a formal business plan and assessing the appropriateness of cooperatives in other industries. PMID:19890146

The Vida Verde Women's Co-Op: Brazilian immigrants organizing to promote environmental and social justice.

PubMed

Gute, David M; Siqueira, Eduardo; Goldberg, Julia S; Galvão, Heloisa; Chianelli, Mônica; Pirie, Alex

2009-11-01

We reviewed the key steps in the launch of the Vida Verde Women's Co-Op among Brazilian immigrant housecleaners in Somerville, MA. The co-op provides green housecleaning products, encourages healthy work practices, and promotes a sense of community among its members. We conducted in-depth interviews with 8 of the first co-op members, who reported a reduction in symptoms associated with the use of traditional cleaning agents and a new sense of mutual support. Critical to the co-op's success have been the supportive roles of its academic partners (Tufts University and the University of Massachusetts, Lowell), effective media outreach, and a focus on advancing social justice. Next steps include implementing a formal business plan and assessing the appropriateness of cooperatives in other industries.

On the impact of CO{sub 2} emission-trading on power generation emissions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chappin, E.J.L.; Dijkema, G.P.J.

2009-03-15

In Europe one of the main policy instruments to meet the Kyoto reduction targets is CO{sub 2} emission-trading (CET), which was implemented as of January 2005. In this system, companies active in specific sectors must be in the possession of CO{sub 2} emission rights to an amount equal to their CO{sub 2} emission. In Europe, electricity generation accounts for one-third of CO{sub 2} emissions. Since the power generation sector has been liberalized, reregulated and privatized in the last decade, around Europe autonomous companies determine the sectors' CO{sub 2} emission. Short-term they adjust their operation, long-term they decide on (dis) investmentmore » in power generation facilities and technology selection. An agent-based model is presented to elucidate the effect of CET on the decisions of power companies in an oligopolistic market. Simulations over an extensive scenario-space show that there CET does have an impact. A long-term portfolio shift towards less-CO{sub 2} intensive power generation is observed. However, the effect of CET is relatively small and materializes late. The absolute emissions from power generation rise under most scenarios. This corresponds to the dominant character of current capacity expansion planned in the Netherlands (50%) and in Germany (68%), where companies have announced many new coal based power plants. Coal is the most CO{sub 2} intensive option available and it seems surprising that even after the introduction of CET these capacity expansion plans indicate a preference for coal. Apparently in power generation the economic effect of CO{sub 2} emission-trading is not sufficient to outweigh the economic incentives to choose for coal.« less

40 CFR 63.6625 - What are my monitoring, installation, collection, operation, and maintenance requirements?

Code of Federal Regulations, 2014 CFR

2014-07-01

..., operate, and maintain a CEMS to monitor CO and either O2 or CO2 according to the requirements in... program must be part of the maintenance plan for the engine. (j) If you own or operate a stationary SI...

DEVELOPING AN INTEGRATED MANAGEMENT SYSTEM FOR URBAN AND ENERGY PLANNING TOWARDS A LOW-CARBON CITY

NASA Astrophysics Data System (ADS)

Maeda, Hideto; Nakakubo, Toyohiko; Tokai, Akihiro

In this study, we developed an integrated management model that supports local government to make a promising energy saving measure on a block-scale combined with urban planning. We applied the model to Osaka city and estimated CO2 emissions from the residential and commercial buildings to 2050. The urban renewal cases selected in this study included advanced multipole accumulation case, normal multipole accumulation case, and actual trend continuation case. The energy saving options introduced in each case included all-electric HP system, micro grid system, and we also set the option where the greater CO2 reduction one is selected in each block. The results showed that CO2 emission in 2050 would be reduced by 54.8-57.6% relative to the actual condition by introducing the new energy system in all cases. In addition, the amount of CO2 reduction in actual trend continuation case was highest. The major factor was that the effect of CO2 emission reductions by installing the solar power generation panel was higher than the effect by utilizing heated water mutually on the high-density blocks in terms of total urban buildings' energy consumption.

Passenger transport and CO 2 emissions: What does the French transport survey tell us?

NASA Astrophysics Data System (ADS)

Nicolas, Jean-Pierre; David, Damien

The aim of this article is to analyse CO 2 emissions caused by passenger transport in France: which socio-demographic groups travel, for what kinds of journey (local or long distance), how and why? Research focusing on the analysis of individual travel can improve the understanding of CO 2 emissions by identifying upstream socio-economic factors, and also enable a better assessment of the potential social impact of measures introduced to limit greenhouse gases due to transport. Calculations are based on the latest French national transport survey (1994). Distances covered and CO 2 emissions were estimated for each journey and for each surveyed individual. A socio-demographic characteristic typology was built and results were obtained through this analysis. If equity and accessibility issues are to be taken into account, planned policies cannot be of the same type if linked to mobility segments. An environmental tax system to limit CO 2 emission increases appears appropriate for long-distance trips. Results are more varied for local journeys, which are often more of a necessity. Nevertheless, income brackets, and measures concerning urban planning or the growth of new car fleets, seem more pertinent.

International Space Station Earth Observations Working Group

NASA Technical Reports Server (NTRS)

Stefanov, William L.; Oikawa, Koki

2015-01-01

The multilateral Earth Observations Working Group (EOWG) was chartered in May 2012 in order to improve coordination and collaboration of Earth observing payloads, research, and applications on the International Space Station (ISS). The EOWG derives its authority from the ISS Program Science Forum, and a NASA representative serves as a permanent co-chair. A rotating co-chair position can be occupied by any of the international partners, following concurrence by the other partners; a JAXA representative is the current co-chair. Primary functions of the EOWG include, 1) the exchange of information on plans for payloads, from science and application objectives to instrument development, data collection, distribution and research; 2) recognition and facilitation of opportunities for international collaboration in order to optimize benefits from different instruments; and 3) provide a formal ISS Program interface for collection and application of remotely sensed data collected in response to natural disasters through the International Charter, Space and Major Disasters. Recent examples of EOWG activities include coordination of bilateral data sharing protocols between NASA and TsNIIMash for use of crew time and instruments in support of ATV5 reentry imaging activities; discussion of continued use and support of the Nightpod camera mount system by NASA and ESA; and review and revision of international partner contributions on Earth observations to the ISS Program Benefits to Humanity publication.

Gait planning for a quadruped robot with one faulty actuator

NASA Astrophysics Data System (ADS)

Chen, Xianbao; Gao, Feng; Qi, Chenkun; Tian, Xinghua

2015-01-01

Fault tolerance is essential for quadruped robots when they work in remote areas or hazardous environments. Many fault-tolerant gaits planning method proposed in the past decade constrained more degrees of freedom(DOFs) of a robot than necessary. Thus a novel method to realize the fault-tolerant walking is proposed. The mobility of the robot is analyzed first by using the screw theory. The result shows that the translation of the center of body(CoB) can be kept with one faulty actuator if the rotations of the body are controlled. Thus the DOFs of the robot body are divided into two parts: the translation of the CoB and the rotation of the body. The kinematic model of the whole robot is built, the algorithm is developed to actively control the body orientations at the velocity level so that the planned CoB trajectory can be realized in spite of the constraint of the faulty actuator. This gait has a similar generation sequence with the normal gait and can be applied to the robot at any position. Simulations and experiments of the fault-tolerant gait with one faulty actuator are carried out. The CoB errors and the body rotation angles are measured. Comparing to the traditional fault-tolerant gait they can be reduced by at least 50%. A fault-tolerant gait planning algorithm is presented, which not only realizes the walking of a quadruped robot with a faulty actuator, but also efficiently improves the walking performances by taking full advantage of the remaining operational actuators according to the results of the simulations and experiments.

Flight Planning Branch NASA Co-op Tour

NASA Technical Reports Server (NTRS)

Marr, Aja M.

2013-01-01

This semester I worked with the Flight Planning Branch at the NASA Johnson Space Center. I learned about the different aspects of flight planning for the International Space Station as well as the software that is used internally and ISSLive! which is used to help educate the public on the space program. I had the opportunity to do on the job training in the Mission Control Center with the planning team. I transferred old timeline records from the planning team's old software to the new software in order to preserve the data for the future when the software is retired. I learned about the operations of the International Space Station, the importance of good communication between the different parts of the planning team, and enrolled in professional development classes as well as technical classes to learn about the space station.

40 CFR 98.447 - Records that must be retained.

Code of Federal Regulations, 2014 CFR

2014-07-01

...) Quarterly records of CO2 received, including mass flow rate of contents of containers (mass or volumetric... specified for retention in your EPA-approved MRV plan. (b) You must complete your monitoring plans, as...

40 CFR 98.447 - Records that must be retained.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) Quarterly records of CO2 received, including mass flow rate of contents of containers (mass or volumetric... specified for retention in your EPA-approved MRV plan. (b) You must complete your monitoring plans, as...

40 CFR 98.447 - Records that must be retained.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) Quarterly records of CO2 received, including mass flow rate of contents of containers (mass or volumetric... specified for retention in your EPA-approved MRV plan. (b) You must complete your monitoring plans, as...

Low Work Function 2.81 eV Rb2CO3-Doped Polyethylenimine Ethoxylated for Inverted Organic Light-Emitting Diodes.

PubMed

Kim, Jeonggi; Kim, Hyo-Min; Jang, Jin

2018-06-06

We report a low work function (2.81 eV), Rb 2 CO 3 -doped polyethyleneimine ethoxylated (PEIE) which is used for highly efficient and long-lifetime, inverted organic light-emitting diodes (OLEDs). Doping Rb 2 CO 3 into PEIE decreases the work function of Li-doped ZnO (LZO) by 1.0 eV and thus significantly improves electron injection ability into the emission layer (EML). The inverted OLED with PEIE:Rb 2 CO 3 interfacial layer (IL) exhibits higher efficiency and longer operation lifetime than those of the device with a PEIE IL. It is found also that Mg-doped ZnO (MZO) can be used instead of LZO as electron transporting layer. Rb 2 CO 3 shows a low work function of 2.81 eV. The OLED with MZO/PEIE:Rb 2 CO 3 exhibits low operating voltage of 5.0 V at 1000 cd m -2 and low efficiency roll-off of 11.8% at high luminance of 10 000 cd m -2 . The results are due to the suppressed exciton quenching at the MZO/organic EML interface.

Circumpolar Biodiversity Monitoring Programme coastal biodiversity monitoring background paper

USGS Publications Warehouse

McLennan, Donald; Anderson, Rebecca D.; Wegeberg, S.; Pettersvik Arvnes, Maria; Sergienko, Liudmila; Behe, Carolina; Moss-Davies, Pitseolak; Fritz, S.; Markon, Carl J.; Christensen, T.; Barry, T.; Price, C.

2016-01-01

In 2014, the United States (U.S.) and Canada agreed to act as co-lead countries for the initial development of the Coastal Expert Monitoring Group (CEMG) as part of the Circumpolar Biodiversity Monitoring Program (CBMP, www. cbmp.is) under the Arctic Council’s Conservation of Arctic Flora and Fauna (CAFF, www.caff.is) working group. The CAFF Management Board approved Terms of Reference for the CEMG in the spring of 2014. The primary goal of the CEMG is to develop a long term, integrated, multi-disciplinary, circumpolar Arctic Coastal Biodiversity Monitoring Plan (the Coastal Plan) that relies on science and Traditional Knowledge, and has direct and relevant application for communities, industry, government decision makers, and other users. In addition to the monitoring plan, the CAFF working group has asked the CBMP, and thus the CEMG, to develop an implementation plan that identifies timeline, costs, organizational structure and partners. This background paper provides a platform for the guidance for the development of the Coastal Plan and is produced by the CEMG with assistance from a number of experts in multiple countries.

Observing System Simulations for ASCENDS: Synthesizing Science Measurement Requirements (Invited)

NASA Astrophysics Data System (ADS)

Kawa, S. R.; Baker, D. F.; Schuh, A. E.; Crowell, S.; Rayner, P. J.; Hammerling, D.; Michalak, A. M.; Wang, J. S.; Eluszkiewicz, J.; Ott, L.; Zaccheo, T.; Abshire, J. B.; Browell, E. V.; Moore, B.; Crisp, D.

2013-12-01

The measurement of atmospheric CO2 from space using active (lidar) sensing techniques has several potentially significant advantages in comparison to current and planned passive CO2 instruments. Application of this new technology aims to advance CO2 measurement capability and carbon cycle science into the next decade. The NASA Active Sensing of Carbon Emissions, Nights, Days, and Seasons (ASCENDS) mission has been recommended by the US National Academy of Sciences Decadal Survey for the next generation of space-based CO2 observing systems. ASCENDS is currently planned for launch in 2022. Several possible lidar instrument approaches have been demonstrated in airborne campaigns and the results indicate that such sensors are quite feasible. Studies are now underway to evaluate performance requirements for space mission implementation. Satellite CO2 observations must be highly precise and unbiased in order to accurately infer global carbon source/sink fluxes. Measurement demands are likely to further increase in the wake of GOSAT, OCO-2, and enhanced ground-based in situ and remote sensing CO2 data. The objective of our work is to quantitatively and consistently evaluate the measurement capabilities and requirements for ASCENDS in the context of advancing our knowledge of carbon flux distributions and their dependence on underlying physical processes. Considerations include requirements for precision, relative accuracy, spatial/temporal coverage and resolution, vertical information content, interferences, and possibly the tradeoffs among these parameters, while at the same time framing a mission that can be implemented within a constrained budget. Here, we attempt to synthesize the results of observing system simulation studies, commissioned by the ASCENDS Science Requirements Definition Team, into a coherent set of mission performance guidelines. A variety of forward and inverse model frameworks are employed to reduce the potential dependence of the results on model specifics. Sensitivity to key instrument design variables is explored and quantified. Global random error measurement scenarios show significant improvement in resolving CO2 fluxes and reducing uncertainties for expected lidar instrument error levels. The improvement beyond that expected for OCO-2 with random errors only, however, is limited for regions where passive sampling is not limited by lack of sunlight or heavy cloud cover. Simulations including prospective systematic (bias) errors, which are expected to be lesser for the lidar system, provide guidance for instrument design requirements as well as reinforcing the priority for a comprehensive calibration/validation component to the mission. The necessity of including coincident lidar measurements of the O2 column, in order to normalize the CO2 column to dry air mole fraction, will also be discussed. The results indicate that within reasonable technological assumptions for the system performance, high measurement quality and quantity can be obtained that will fulfill the nominal ASCENDS objectives and provide substantial improvement in our knowledge of global carbon cycle processes.

78 FR 13497 - Approval and Promulgation of Air Quality Implementation Plans; Maryland; Deferral for CO2

Federal Register 2010, 2011, 2012, 2013, 2014

2013-02-28

... defers until July 21, 2014 the application of the Prevention of Significant Deterioration (PSD... Other Biogenic Sources Under the Prevention of Significant Deterioration Program AGENCY: Environmental... July 21, 2014 the application of PSD permitting requirements to biogenic CO 2 emissions from bioenergy...

CO{sub 2} pellet decontamination technology at Westinghouse Hanford

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aldridge, T.L.; Aldrich, L.K. II; Bowman, E.V.

1995-03-01

Experimentation and testing with CO{sub 2} pellet decontamination technology is being conducted at Westinghosue Hanford Company (WHC), Richland, Washington. There are 1,100 known existing waste sites at Hanford. The sites specified by federal and state agencies are currently being studied to determine the appropriate cleanup methods best for each site. These sites are contaminated and work on them is in compliance with the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). There are also 63 treatment, storage, and disposal units, for example: groups of waste tanks or drums. In 1992, there were 100 planned activities scheduled to bring these unitsmore » into the Resource Conservation and Recovery Act (RCRA) compliance or close them after waste removal. Ninety-six of these were completed. The remaining four were delayed or are being negotiated with regulatory agencies. As a result of past defense program activities at Hanford a tremendous volume of materials and equipment have accumulated and require remediation.« less

Philosophy for Young Children: A Practical Guide

ERIC Educational Resources Information Center

Gaut, Berys; Gaut, Morag

2011-01-01

Co-written by a professor of philosophy and a practising primary school teacher, "Philosophy for Young Children" is a concise, practical guide for teachers. It contains detailed session plans for 36 philosophical enquiries--enough for a year's work--that have all been successfully tried, tested and enjoyed with young children from the age of three…

Real Time Control of CO2 Enrichment Experiments on the Sea Floor Enabled by the MARS Cabled Observatory

NASA Astrophysics Data System (ADS)

Brewer, P. G.; Mbari Foce Team

2010-12-01

We report on progress on FOCE (Free Ocean CO2 Enrichment) techniques designed to accomplish realistic (that is not contained within land-based aquaria) experiments on the response of deep-sea animals and biogeochemical cycles to ocean acidification. Such experiments have long been carried out on ecosystems on land, and the outcome has differed significantly from CO2 enrichment in enclosed greenhouse systems, thereby undoing much of the hope for an increase in the large-scale biosphere draw down of atmospheric CO2. It is a far bigger step if deep-sea animals and systems are removed from their cold, dark, high pressure and low oxygen native habitat. The equivalent problem in the ocean is far more difficult because of (1) the very different physical forcing; (2) the complex reaction rates between CO2 and water require delay times between addition and entry to the experimental space; (3) the lack of supporting infrastructure and of adequate sensors; and (4) the need for sophisticated and robust control techniques in both hardware and software. We have overcome almost all of these challenges, and related working systems have already been successfully deployed on the Great Barrier Reef coralline flats with Australian colleagues. We have used the MBARI MARS (Monterey Accelerated Research System) cabled observatory to carry out deep-ocean (880m depth) experiments. The basic experimental unit is a 1m x 1m x 50cm chamber with side arms of ~ 3m length to provide the required chemical delay times for the reaction between admixed CO2 enriched sea water and emergence of the flow into the main chamber. Controllable thrusters, operated by user commands, help maintain a steady flow of seawater through the experiment. The site is slightly below the depth of the O2 minimum where small changes in either O2 from ocean warming, or CO2 from ocean acidification can lead to the formation of dead zones. Shallow (near shore) experiments are now also in the late planning stages. We have developed extremely low noise pH sensors that show for the first time the scale and frequency of the tidally driven background pH fluctuations in the ocean. This helps establish the limits in background pH that deep-sea animals are adapted to. We have developed software to control this complex system in real time and to make control possible over the web. A graphical user interface allows operator observation of flow and background conditions, and full choice of experimental settings. CO2 enrichment is provided by ROV delivery of ~50-100 L of liquid CO2 which is contained by its buoyancy within a box set immediately above the side arm opening. The dissolution rate of liquid CO2 through the hydrate skin is ~0.5 μmol/cm2/sec thereby providing a working fluid in the reservoir which is drawn upon as needed. Experiments of 2-3 weeks duration are possible from a single filling. Figure 1. pH changes created in FOCE by a series of CO2 enriched sea water additions under varying flow conditions.

Electric Utility Generating Units: Repealing the Clean Power Plan

EPA Pesticide Factsheets

The Clean Power Plan established emission guidelines for states to follow in limiting carbon dioxide (CO2) emissions from existing power plants. EPA is proposing to repeal the CPP and rescind the accompanying legal memorandum.

40 CFR 52.1570 - Identification of plan.

Code of Federal Regulations, 2010 CFR

2010-07-01

... County 2.0 E. I. du Pont de Nemours & Co Deepwater, Salem County 1.5 Heinz-USA Salem City, Salem County 2... County 2.0 Atlantic City Electric Deepwater Station Penns Grove, Salem County 1.5 E. I. du Pont de... County 2.0 E. I. du Pont de Nemours & Co Deepwater, Salem County 1.5 Heinz-U.S.A Salem City, Salem County...

A Qualitative Study of Career Exploration among Young Adult Men with Psychosis and Co-occurring Substance Use Disorder

PubMed Central

Luciano, Alison; Carpenter-Song, Elizabeth A.

2015-01-01

Objective This article explores the meaning and importance of career exploration and career development in the context of integrated treatment for young adults with early psychosis and substance use disorders (i.e., co-occurring disorders). Methods Twelve young adult men (aged 18 to 35 years) with co-occurring disorders recruited from an integrated treatment center completed a series of three semi-structured in-depth qualitative interviews. Data were transcribed verbatim and analyzed using thematic analysis. Purposive sampling ensured participants represented a range of substance abuse treatment stages. Results Participants had a mean age of 26 (SD = 3) and identified as White. Two-thirds of participants (n = 8, 67%) were diagnosed with schizophrenia-spectrum disorders, three (25%) with bipolar disorder, and one (8%) with major depression; four (33%) also had a co-occurring anxiety disorder. The most common substance use disorders involved cannabis (n = 8, 67%), cocaine (n = 5, 42%), and alcohol (n = 5, 42%). These young adult men with co-occurring disorders described past jobs that did not align with future goals as frustrating and disempowering, rather than confidence building. Most young adult participants began actively developing their careers in treatment through future-oriented work or school placements. They pursued ambitious career goals despite sporadic employment and education histories. Treatment engagement and satisfaction appeared to be linked with career advancement prospects. Conclusions Integrating career planning into psychosocial treatment is a critical task for providers who serve young adults with co-occurring disorders. Whether integrating career planning within early intervention treatment planning will improve clinical, functional, or economic outcomes is a promising area of inquiry for rehabilitation researchers and clinicians. PMID:25391280

A qualitative study of career exploration among young adult men with psychosis and co-occurring substance use disorder.

PubMed

Luciano, Alison; Carpenter-Song, Elizabeth A

2014-01-01

This article explores the meaning and importance of career exploration and career development in the context of integrated treatment for young adults with early psychosis and substance use disorders (i.e., co-occurring disorders). Twelve young adult men (aged 18 to 35 years) with co-occurring disorders recruited from an integrated treatment center completed a series of three semi-structured in-depth qualitative interviews. Data were transcribed verbatim and analyzed using thematic analysis. Purposive sampling ensured participants represented a range of substance abuse treatment stages. Participants had a mean age of 26 (SD = 3) and identified as White. Two-thirds of participants (n = 8, 67%) had diagnosed schizophrenia-spectrum disorders, three (25%) had bipolar disorder, and one (8%) had major depression; four (33%) also had a co-occurring anxiety disorder. The most common substance use disorders involved cannabis (n = 8, 67%), cocaine (n = 5, 42%), and alcohol (n = 5, 42%). These young adult men with co-occurring disorders described past jobs that did not align with future goals as frustrating and disempowering, rather than confidence-building. Most young adult participants began actively developing their careers in treatment through future-oriented work or school placements. They pursued ambitious career goals despite sporadic employment and education histories. Treatment engagement and satisfaction appeared to be linked with career advancement prospects. Integrating career planning into psychosocial treatment is a critical task for providers who serve young adults with co-occurring disorders. Whether integrating career planning within early intervention treatment planning will improve clinical, functional, or economic outcomes is a promising area of inquiry for rehabilitation researchers and clinicians.

75 FR 35816 - Establishment of the Consumer Operated and Oriented Plan (CO-OP) Advisory Board

Federal Register 2010, 2011, 2012, 2013, 2014

2010-06-23

... (CO-OP) Advisory Board AGENCY: Department of Health and Human Services, Office of Consumer Information & Insurance Oversight. ACTION: Federal Register Notice. Authority: The Consumer Operated and Oriented Plan (CO... (PPACA) that calls for the establishment of the Consumer Operated and Oriented Plans (CO-OP) Program...

Ten Tips for Using Co-Planning Time More Efficiently

ERIC Educational Resources Information Center

Murawski, Wendy W.

2012-01-01

In this era of collaboration, educators are frequently expected to co-plan with one another on a regular basis. Unfortunately, the expectation of co-planning is not often accompanied by the time required or by the strategies necessary to plan effectively and efficiently for the inclusive classroom. This article provides 10 concrete tips for…

IPPF Co-operative Information Service (ICIS). May 1978.

ERIC Educational Resources Information Center

International Planned Parenthood Federation, London (England).

This annotated bibliography of documents on family planning is divided into nine sections: (1) family planning and bio-medical science; (2) social sciences related to family planning; (3) international conferences; (4) Africa; (5) Americas: (6) Asia; (7) Europe; (8) the Middle East; and (9) Oceania. Also included is a list of general reference…

Toward a Multi-Decadal Record of Satellite CO from MOPITT to Suomi NPP/CrIS: Overview and Initial Results

NASA Astrophysics Data System (ADS)

Francis, G. L.; Cady-Pereira, K.; Worden, H. M.; Shephard, M.; Fu, D.

2016-12-01

A prototype optimal estimation CO retrieval framework using CrIS thermal-IR spectra is being developed and undergoing initial testing and evaluation. The goal is construction of a multi- decadal climate-quality data record, consistent with MOPITT, extending into the post-EOS/Terra era, given the planned JPSS mission schedule. The EOS/MOPITT instrument has an ongoing and unprecedented record of CO retrievals since early 2000. CrIS CO offers the potential to significantly extend the MOPITT thermal-IR retrieval record, as well as providing expanded spatial coverage. We describe the prototype CrIS CO optimal estimation retrieval system. Test CO retrievals include data for the California Central Valley and the fires near Fort McMurray, Canada. We compare our results to other satellite datasets as well as available in-situ data. Directions for future work will be discussed.

A Full-Featured User Friendly CO 2-EOR and Sequestration Planning Software

DOE Office of Scientific and Technical Information (OSTI.GOV)

Savage, Bill

A Full-Featured, User Friendly CO 2-EOR and Sequestration Planning Software This project addressed the development of an integrated software solution that includes a graphical user interface, numerical simulation, visualization tools and optimization processes for reservoir simulation modeling of CO 2-EOR. The objective was to assist the industry in the development of domestic energy resources by expanding the application of CO 2-EOR technologies, and ultimately to maximize the CO 2} sequestration capacity of the U.S. The software resulted in a field-ready application for the industry to address the current CO 2-EOR technologies. The software has been made available to the publicmore » without restrictions and with user friendly operating documentation and tutorials. The software (executable only) can be downloaded from NITEC’s website at www.nitecllc.com. This integrated solution enables the design, optimization and operation of CO 2-EOR processes for small and mid-sized operators, who currently cannot afford the expensive, time intensive solutions that the major oil companies enjoy. Based on one estimate, small oil fields comprise 30% of the of total economic resource potential for the application of CO 2-EOR processes in the U.S. This corresponds to 21.7 billion barrels of incremental, technically recoverable oil using the current “best practices”, and 31.9 billion barrels using “next-generation” CO 2-EOR techniques. The project included a Case Study of a prospective CO 2-EOR candidate field in Wyoming by a small independent, Linc Energy Petroleum Wyoming, Inc. NITEC LLC has an established track record of developing innovative and user friendly software. The Principle Investigator is an experienced manager and engineer with expertise in software development, numerical techniques, and GUI applications. Unique, presently-proprietary NITEC technologies have been integrated into this application to further its ease of use and technical functionality.« less

Optimization of Perovskite Gas Sensor Performance: Characterization, Measurement and Experimental Design.

PubMed

Bertocci, Francesco; Fort, Ada; Vignoli, Valerio; Mugnaini, Marco; Berni, Rossella

2017-06-10

Eight different types of nanostructured perovskites based on YCoO 3 with different chemical compositions are prepared as gas sensor materials, and they are studied with two target gases NO 2 and CO. Moreover, a statistical approach is adopted to optimize their performance. The innovative contribution is carried out through a split-plot design planning and modeling, also involving random effects, for studying Metal Oxide Semiconductors (MOX) sensors in a robust design context. The statistical results prove the validity of the proposed approach; in fact, for each material type, the variation of the electrical resistance achieves a satisfactory optimized value conditional to the working temperature and by controlling for the gas concentration variability. Just to mention some results, the sensing material YCo 0 . 9 Pd 0 . 1 O 3 (Mt1) achieved excellent solutions during the optimization procedure. In particular, Mt1 resulted in being useful and feasible for the detection of both gases, with optimal response equal to +10.23% and working temperature at 312 ∘ C for CO (284 ppm, from design) and response equal to -14.17% at 185 ∘ C for NO 2 (16 ppm, from design). Analogously, for NO 2 (16 ppm, from design), the material type YCo 0 . 9 O 2 . 85 + 1 % Pd (Mt8) allows for optimizing the response value at - 15 . 39 % with a working temperature at 181 . 0 ∘ C, whereas for YCo 0 . 95 Pd 0 . 05 O 3 (Mt3), the best response value is achieved at - 15 . 40 % with the temperature equal to 204 ∘ C.

Optimization of Perovskite Gas Sensor Performance: Characterization, Measurement and Experimental Design

PubMed Central

Bertocci, Francesco; Fort, Ada; Vignoli, Valerio; Mugnaini, Marco; Berni, Rossella

2017-01-01

Eight different types of nanostructured perovskites based on YCoO3 with different chemical compositions are prepared as gas sensor materials, and they are studied with two target gases NO2 and CO. Moreover, a statistical approach is adopted to optimize their performance. The innovative contribution is carried out through a split-plot design planning and modeling, also involving random effects, for studying Metal Oxide Semiconductors (MOX) sensors in a robust design context. The statistical results prove the validity of the proposed approach; in fact, for each material type, the variation of the electrical resistance achieves a satisfactory optimized value conditional to the working temperature and by controlling for the gas concentration variability. Just to mention some results, the sensing material YCo0.9Pd0.1O3 (Mt1) achieved excellent solutions during the optimization procedure. In particular, Mt1 resulted in being useful and feasible for the detection of both gases, with optimal response equal to +10.23% and working temperature at 312∘C for CO (284 ppm, from design) and response equal to −14.17% at 185∘C for NO2 (16 ppm, from design). Analogously, for NO2 (16 ppm, from design), the material type YCo0.9O2.85+1%Pd (Mt8) allows for optimizing the response value at −15.39% with a working temperature at 181.0∘C, whereas for YCo0.95Pd0.05O3 (Mt3), the best response value is achieved at −15.40% with the temperature equal to 204∘C. PMID:28604587

Effect of work intensity on time delay in mediation of ventilation by arterial carbon dioxide during recovery from impulse exercise.

PubMed

Afroundeh, R; Arimitsu, T; Yamanaka, R; Lian, C S; Shirakawa, K; Yunoki, T; Yano, T

2014-01-01

Time delay in the mediation of ventilation (V(.)E) by arterial CO(2) pressure (PaCO(2)) was studied during recovery from short impulse-like exercises with different work loads of recovery. Subjects performed two tests including 10-s impulse like exercise with work load of 200 watts and 15-min recovery with 25 watts in test one and 50 watts in test two. V(.)E, end tidal CO(2) pressure (PETCO(2)) and heart rate (HR) were measured continuously during rest, warming up, exercise and recovery. PaCO(2) was estimated from PETCO(2) and tidal volume (V(T)). Results showed that predicted arterial CO(2) pressure (PaCO(2 pre)) increased during recovery in both tests. In both tests, V(.)E increased and peaked at the end of exercise. V(.)E decreased in the first few seconds of recovery but started to increase again. The highest correlation coefficient between PaCO(2 pre) and V(.)E was obtained in the time delay of 7 s (r=0.854) in test one and in time delays of 6 s (r=0.451) and 31 s (r=0.567) in test two. HR was significantly higher in test two than in test one. These results indicate that PaCO(2 pre) drives V(.)E with a time delay and that higher work intensity induces a shorter time delay.

Co-Production of Actionable Science: Recommendations to the Secretary of Interior and a San Francisco Case Study

NASA Astrophysics Data System (ADS)

Behar, D. H.; Pfeffer, W. T.; Beier, P.

2015-12-01

"Actionable Science provides data, analyses, projections, or tools that can support decisions regarding the management of the risks and impacts of climate change. It is ideally co-produced by scientists and decision makers and creates rigorous and accessible products to meet the needs of stakeholders. (Report to the Secretary of the Interior, Advisory Committee on Climate Change and Natural Resource Science (ACCCNRS), March 30, 2015)During one 17 month period ending in 2013, three major reports on sea level rise from three highly respected science providers produced three divergent estimates of sea level rise. These reports collectively flummoxed the lay reader seeking direction for adaptation planning. Guidance documents soon emerged from state entities which caused further confusion. The City and County of San Francisco began developing "Guidance for Incorporating Sea Level Rise into Capital Planning" in 2013 at the direction of San Francisco Mayor Edwin Lee (http://onesanfrancisco.org/staff-resources/sea-level-rise-guidance/). The first task in developing this Guidance was to convert these highly technical reports into "actionable science." This required extensive expert elicitation to tease out their meaning and use value for decision making. This process, which resulted in detailed guidance on the use of SLR science in planning, is increasingly being called "co-production."Co-production requires both scientist and decision-maker to hear the other's perspective, reflect upon the decision-maker's precise needs, and translate peer review science into lay language and practical advice for decision making. The co-production dynamic was the subject of extensive discussion in the federal Advisory Committee on Climate Change and Natural Resource Science. The ACCCNRS recommendations (https://nccwsc.usgs.gov/acccnrs) include not only the new definition of Actionable Science cited above, but also a "How-To-Guide" that outlines principles for successfully creating a co-production environment and case studies highlighting where this has worked to date.This talk will summarize our state of understanding of "actionable science" and this new "co-production" dynamic within climate change science and planning, with focused reference on recent case studies, particularly San Francisco.

Geant4 simulation of ion chambers response to 60Co spectrum of LNMRI/IRD Shepherd 81-14D Radiator

NASA Astrophysics Data System (ADS)

Queiroz Filho, P. P.; Da Silva, C. N. M.

2018-03-01

The National Ionizing Radiation Metrology Laboratory of the Radioprotection and Dosimetry Institute (LNMRI / IRD) has recently acquired a Shepherd 81-14D Radiator. In this work we simulate, using Geant4, the behavior with the inverse square law radiation for 3 models of PTW spherical chambers used in radioprotection, a relevant information to planning the measurements. We did the corrections for the attenuation and scattering in the air for each distance, where we used the 60Co spectrum simulated previously.

40 CFR 98.447 - Records that must be retained.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) Quarterly records of CO2 received, including mass flow rate of contents of containers (mass or volumetric... retention in your EPA-approved MRV plan. (b) You must complete your monitoring plans, as described in § 98.3...

Space Launch System Co-Manifested Payload Options for Habitation

NASA Technical Reports Server (NTRS)

Smitherman, David

2015-01-01

The Space Launch System (SLS) has a co-manifested payload capability that will grow over time as the launch vehicle matures and planned upgrades are implemented. The final configuration is planned to be capable of inserting a payload greater than 10 metric tons (mt) into a trans-lunar injection trajectory along with the crew in the Orion capsule and its service module. The co-manifested payload is located below the Orion and its service module in a 10 m high fairing similar to the way the Saturn launch vehicle carried the lunar lander below the Apollo command and service modules. Various approaches that utilize this comanifested payload capability to build up infrastructure in deep space have been explored in support of future asteroid, lunar, and Mars mission scenarios. This paper reports on the findings of the Advanced Concepts Office study team at NASA Marshall Space Flight Center (MSFC) working with the Advanced Exploration Systems Program on the Exploration Augmentation Module Project. It includes some of the possible options for habitation in the co-manifested payload volume of the SLS. Findings include a set of module designs that can be developed in 10 mt increments to support these co-manifested payload missions along with a comparison of this approach to a large-module payload flight configuration for the SLS.

77 FR 55171 - Approval and Promulgation of Air Quality Implementation Plans; Maryland; Deferral for CO2

Federal Register 2010, 2011, 2012, 2013, 2014

2012-09-07

... consider your comment. Electronic files should avoid the use of special characters, any form of encryption... copy form. Publicly available docket materials are available either electronically in www.regulations... biologically-based materials other than fossil fuels and mineral sources of carbon. Examples of ``biogenic CO 2...

Microclimatic performance of a free-air warming and CO2 enrichment experiment in windy Wyoming, USA

USDA-ARS?s Scientific Manuscript database

In order to predict and plan for global changing climate experiments are being conducted in many countries, but few have monitored the effects of the climate change treatments (warming, elevated CO2) on the ecologically critical experimental plot microclimate. During three years of an eight year stu...

Opportunities for increasing CO 2 storage in deep, saline formations by active reservoir management and treatment of extracted formation water: Case study at the GreenGen IGCC facility, Tianjin, PR China

DOE PAGES

Ziemkiewicz, Paul; Stauffer, Philip H.; Sullivan-Graham, Jeri; ...

2016-08-04

Carbon capture, utilization and storage (CCUS) seeks beneficial applications for CO 2 recovered from fossil fuel combustion. This study evaluated the potential for removing formation water to create additional storage capacity for CO 2, while simultaneously treating the produced water for beneficial use. Furthermore, the process would control pressures within the target formation, lessen the risk of caprock failure, and better control the movement of CO 2 within that formation. The project plans to highlight the method of using individual wells to produce formation water prior to injecting CO 2 as an efficient means of managing reservoir pressure. Because themore » pressure drawdown resulting from pre-injection formation water production will inversely correlate with pressure buildup resulting from CO 2 injection, it can be proactively used to estimate CO 2 storage capacity and to plan well-field operations. The project studied the GreenGen site in Tianjin, China where Huaneng Corporation is capturing CO 2 at a coal fired IGCC power plant. Known as the Tianjin Enhanced Water Recovery (EWR) project, local rock units were evaluated for CO 2 storage potential and produced water treatment options were then developed. Average treatment cost for produced water with a cooling water treatment goal ranged from 2.27 to 2.96 US$/m 3 (recovery 95.25%), and for a boiler water treatment goal ranged from 2.37 to 3.18 US$/m 3 (recovery 92.78%). Importance analysis indicated that water quality parameters and transportation are significant cost factors as the injection-extraction system is managed over time. Our study found that in a broad sense, active reservoir management in the context of CCUS/EWR is technically feasible. In addition, criteria for evaluating suitable vs. unsuitable reservoir properties, reservoir storage (caprock) integrity, a recommended injection/withdrawal strategy and cost estimates for water treatment and reservoir management are proposed.« less

Opportunities for increasing CO 2 storage in deep, saline formations by active reservoir management and treatment of extracted formation water: Case study at the GreenGen IGCC facility, Tianjin, PR China

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ziemkiewicz, Paul; Stauffer, Philip H.; Sullivan-Graham, Jeri

Carbon capture, utilization and storage (CCUS) seeks beneficial applications for CO 2 recovered from fossil fuel combustion. This study evaluated the potential for removing formation water to create additional storage capacity for CO 2, while simultaneously treating the produced water for beneficial use. Furthermore, the process would control pressures within the target formation, lessen the risk of caprock failure, and better control the movement of CO 2 within that formation. The project plans to highlight the method of using individual wells to produce formation water prior to injecting CO 2 as an efficient means of managing reservoir pressure. Because themore » pressure drawdown resulting from pre-injection formation water production will inversely correlate with pressure buildup resulting from CO 2 injection, it can be proactively used to estimate CO 2 storage capacity and to plan well-field operations. The project studied the GreenGen site in Tianjin, China where Huaneng Corporation is capturing CO 2 at a coal fired IGCC power plant. Known as the Tianjin Enhanced Water Recovery (EWR) project, local rock units were evaluated for CO 2 storage potential and produced water treatment options were then developed. Average treatment cost for produced water with a cooling water treatment goal ranged from 2.27 to 2.96 US$/m 3 (recovery 95.25%), and for a boiler water treatment goal ranged from 2.37 to 3.18 US$/m 3 (recovery 92.78%). Importance analysis indicated that water quality parameters and transportation are significant cost factors as the injection-extraction system is managed over time. Our study found that in a broad sense, active reservoir management in the context of CCUS/EWR is technically feasible. In addition, criteria for evaluating suitable vs. unsuitable reservoir properties, reservoir storage (caprock) integrity, a recommended injection/withdrawal strategy and cost estimates for water treatment and reservoir management are proposed.« less

Precision Column CO2 Measurement from Space Using Broad Band LIDAR

NASA Technical Reports Server (NTRS)

Heaps, William S.

2009-01-01

In order to better understand the budget of carbon dioxide in the Earth's atmosphere it is necessary to develop a global high precision understanding of the carbon dioxide column. To uncover the missing sink" that is responsible for the large discrepancies in the budget as we presently understand it, calculation has indicated that measurement accuracy of 1 ppm is necessary. Because typical column average CO2 has now reached 380 ppm this represents a precision on the order of 0.25% for these column measurements. No species has ever been measured from space at such a precision. In recognition of the importance of understanding the CO2 budget to evaluate its impact on global warming the National Research Council in its decadal survey report to NASA recommended planning for a laser based total CO2 mapping mission in the near future. The extreme measurement accuracy requirements on this mission places very strong constraints on the laser system used for the measurement. This work presents an overview of the characteristics necessary in a laser system used to make this measurement. Consideration is given to the temperature dependence, pressure broadening, and pressure shift of the CO2 lines themselves and how these impact the laser system characteristics. We are examining the possibility of making precise measurements of atmospheric carbon dioxide using a broad band source of radiation. This means that many of the difficulties in wavelength control can be treated in the detector portion of the system rather than the laser source. It also greatly reduces the number of individual lasers required to make a measurement. Simplifications such as these are extremely desirable for systems designed to operate from space.

76 FR 49391 - Approval, Disapproval and Promulgation of Air Quality Implementation Plans; Colorado; Smoke...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-08-10

..., Disapproval and Promulgation of Air Quality Implementation Plans; Colorado; Smoke, Opacity and Sulfur Dioxide... opacity, particulate, sulfur dioxide (SO 2 ), and carbon monoxide (CO) emissions from sources. EPA has... mean Nitrogen Dioxide and SO2 mean Sulfur Dioxide. (vii) The initials BACT mean Best Available Control...

Volcanic sulfur dioxide and carbon dioxide measurements using small unmanned aerial systems

NASA Astrophysics Data System (ADS)

Pieri, D. C.; Diaz, J. A.; Fladeland, M. M.; Bland, G.; Alan, A., Jr.; Alegria, O.; Buongiorno, M. F.; Christensen, L. E.; Corrales, E.; Linick, J.; Mouginis-Mark, P. J.; Ramsey, M. S.; Realmuto, V. J.; Schwandner, F. M.

2015-12-01

Volcanoes emit gases continuously with significant pre-post-eruption changes, mainly H2O and CO2, plus SO2, and others. The SO2/CO2 ratio changes within volcanic life cycles making it an indicator of oncoming eruption phases: it can dip weeks to months before eruptions, then increase, and decrease back to background after eruptions. Over the last five years, we have made an effort to develop small and inexpensive lighter-than-air and fixed wing unmanned aerial vehicle (UAV) platforms in Costa Rica at Turrialba Volcano. Turrialba is an appropriate natural laboratory to test and prove platforms and instrumentation in low-level steady state volcanogenic gas and aerosol emissions at moderate altitudes (<12Kft ASL), where good technical infrastructure exists, with good physical access to the volcano. Our program in Costa Rica includes: (1) systematic monitoring of Turrialba from orbit with the Advanced Spaceborne Thermal Emission and Reflection radiometer (ASTER), with its thermal infrared (TIR) camera for SO2 retrieval, and more recently with GOSAT and OCO-2 for CO2; (2) in situ observations from aerostats and UAVs during ASTER overpasses, and (3) reconciliation of the orbital results with in situ data to validate mass retrieval and transport models. As part of the NASA HyspIRI Preparatory Airborne Activities program, we will conduct similar observations at Kilauea volcano using small UAVs and for both SO2 and CO2 in situ. One of the salient characteristics of the long lived Kilauea eruptions since 1983 has been the emission of SO2 in significant amounts, generating environmental stresses on local inhabitants due to lowered air quality, and stress on vegetation. Kilauea volcanic plumes, as with Turrialba, are mainly gases and liquid--SO2 is hydrolyzed to H2SO4 and the resulting highly acidic liquid aerosol is termed "vog," an environmental health hazard. Measurement of the diffuse CO2 emissions at Kilauea will also be of interest. Such measurements at Turrialba, indicate summit CO2 concentrations of up to 4000ppmv, and flank CO2 values of up to1500ppmv. We will discuss our SO2 and CO2 results at Turrialba and in Italy, and plans for Hawaii. Work presented here was done, in part, under contract to the NASA Earth Surface and Interior Focus Area, at the Jet Propulsion Laboratory of the California Institute of Technology.

Predicting change over time in career planning and career exploration for high school students.

PubMed

Creed, Peter A; Patton, Wendy; Prideaux, Lee-Ann

2007-06-01

This study assessed 166 high school students in Grade 8 and again in Grade 10. Four models were tested: (a) whether the T1 predictor variables (career knowledge, indecision, decision-making self efficacy, self-esteem, demographics) predicted the outcome variable (career planning/exploration) at T1; (b) whether the T1 predictor variables predicted the outcome variable at T2; (c) whether the T1 predictor variables predicted change in the outcome variable from T1-T2; and (d) whether changes in the predictor variables from T1-T2 predicted change in the outcome variable from T1-T2. Strong associations (R(2)=34%) were identified for the T1 analysis (confidence, ability and paid work experience were positively associated with career planning/exploration). T1 variables were less useful predictors of career planning/exploration at T2 (R(2)=9%; having more confidence at T1 was associated with more career planning/exploration at T2) and change in career planning/exploration from T1-T2 (R(2)=11%; less confidence and no work experience were associated with change in career planning/exploration from T1-T2). When testing effect of changes in predictor variables predicting changes in outcome variable (R(2)=22%), three important predictors, indecision, work experience and confidence, were identified. Overall, results indicated important roles for self-efficacy and early work experiences in current and future career planning/exploration of high school students.

Mechanical changes caused by CO2-driven cement dissolution in the Morrow B Sandstone at reservoir conditions: Experimental observations

NASA Astrophysics Data System (ADS)

Wu, Z.; Luhmann, A. J.; Rinehart, A. J.; Mozley, P.; Dewers, T. A.

2017-12-01

Carbon Capture, Utilization and Storage (CCUS) in transmissive reservoirs is a proposed mechanism in reducing CO2 emissions. Injection of CO2 perturbs reservoir chemistry, and can modify porosity and permeability and alter mineralogy. However, little work has been done on the coupling of rock alteration by CO2 injection and the mechanical integrity of the reservoir. In this study, we perform flow-through experiments on calcite- and dolomite-cemented Pennsylvanian Morrow B Sandstone (West Texas, USA) cores. We hypothesize that poikilotopic calcite cement has a larger impact on chemo-mechanical alteration than disseminated dolomite cement given similar CO2 exposure. With one control brine flow-through experiment and two CO2-plus-brine flow-through experiments for each cement composition, flow rates of 0.1 and 0.01 ml/min were applied under 4200 psi pore fluid pressure and 5000 psi confining pressure at 71 °C. Fluid chemistry and permeability data enable monitoring of mineral dissolution. Ultrasonic velocities were measured pre-test using 1.2 MHz source-receiver pairs at 0.5 MPa axial load and show calcite-cemented samples with higher dynamic elastic moduli than dolomite-cemented samples. Velocities measured post-experiment will identify changes from fluid-rock interaction. We plan to conduct cylinder-splitting destructive mechanical test (Brazil test) to measure the pristine and altered tensile strength of different cemented sandstones. The experiments will identify extents to which cement composition and texture control chemo-mechanical degradation of CCUS reservoirs. Funding for this project is provided by the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL) through the Southwest Regional Partnership on Carbon Sequestration (SWP) under Award No. DE-FC26-05NT42591. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology and Engineering Solutions of Sandia LLC, a wholly owned subsidiary of Honeywell International Inc. for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-NA0003525.

7 CFR 25.403. - Ongoing 2-year work plan requirement.

Code of Federal Regulations, 2010 CFR

2010-01-01

... the start of the applicable 2-year period. (c) The 2-year work plan must include the following... Federal, State and local governments, non-profit organizations, foundations, private businesses, and any...

Pulsed 2-micron Laser Transmitter For Carbon Dioxide Sensing From Space

NASA Astrophysics Data System (ADS)

Singh, U. N.; Yu, J.; Bai, Y.; Petros, M.

2011-12-01

Carbon dioxide (CO2) has been recognized as one of the most important greenhouse gases. It is essential for the study of global warming to accurately measure the CO2 concentration in the atmosphere and continuously record its variation. Studies of the carbon cycle are limited by the tools available to precisely measure CO2 concentrations by remote sensing. Active sensing, using the Integrated Path Differential Absorption (IPDA) approach, permits measurements day and night, at all latitudes and seasons. The development of a high pulse energy 2-μm laser transmitter for high-precision CO2 measurements from space leverages years of NASA investment in solid-state laser technology. Under NASA Laser Risk Reduction Program, funded by Earth Science Technology Office, researchers at NASA Langley Research Center developed an injection seeded, high repetition rate, Q-switched Ho:YLF laser transmitter for CO2 Differential Absorption Lidar/IPDA (profile/column) measurements from ground and airborne platforms. This master-slave laser system has high optical-to-optical efficiency and seeding success rate. NASA LaRC's 2-micron pulsed laser transmitter possesses advantages over current passive and CW active sensors. First, the pulsed format provides a built-in means for determining range to the scattering target and effectively filtering out the scattering from thin clouds and aerosols, thus eliminating a source of measurement bias. Second, by concentrating the laser energy into a pulse, sufficient backscatter signal strength can be obtained from aerosol scattering rather than relying on a hard target at a known distance. Third, the absorption line at the 2.05 μm band is ideally suited for the CO2 concentration measurement. In particular, the weighting function of 2 μm is optimum for measurement in the lower troposphere where the sources and sinks of CO2 are located. The planned laser transmitter development will lead to a Tm:Fiber pumped Ho:YLF laser transmitter capable of delivering 65 mJ at 50 Hz at on-line wavelength and 50 mJ at 50 Hz at off-line wavelength. The planned laser technology development and performance capabilities are a major step forward in the laser transmitter requirements called out in recent comprehensive system studies, e.g., the European Space Agency (ESA) exploration mission studies, A-SCOPE, for future CO2 column density measurements from space. The planned laser technology development is relevant to NASA's earth science priorities, such as NASA ASCENDS mission for space-based CO2 column density measurements. This presentation will provide an overview of the current status of laser transmitter development and describe future technology development to meet the transmitter requirement for a space-based column averaged measurement of CO2 concentration.

EVALUATION OF ARG-1 SAMPLES PREPARED BY CESIUM CARBONATE DISSOLUTION DURING THE ISOLOK SME ACCEPTABILITY TESTING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Edwards, T.; Hera, K.; Coleman, C.

2011-12-05

Evaluation of Defense Waste Processing Facility (DWPF) Chemical Process Cell (CPC) cycle time identified several opportunities to improve the CPC processing time. The Mechanical Systems & Custom Equipment Development (MS&CED) Section of the Savannah River National Laboratory (SRNL) recently completed the evaluation of one of these opportunities - the possibility of using an Isolok sampling valve as an alternative to the Hydragard valve for taking DWPF process samples at the Slurry Mix Evaporator (SME). The use of an Isolok for SME sampling has the potential to improve operability, reduce maintenance time, and decrease CPC cycle time. The SME acceptability testingmore » for the Isolok was requested in Task Technical Request (TTR) HLW-DWPF-TTR-2010-0036 and was conducted as outlined in Task Technical and Quality Assurance Plan (TTQAP) SRNLRP-2011-00145. RW-0333P QA requirements applied to the task, and the results from the investigation were documented in SRNL-STI-2011-00693. Measurement of the chemical composition of study samples was a critical component of the SME acceptability testing of the Isolok. A sampling and analytical plan supported the investigation with the analytical plan directing that the study samples be prepared by a cesium carbonate (Cs{sub 2}CO{sub 3}) fusion dissolution method and analyzed by Inductively Coupled Plasma - Optical Emission Spectroscopy (ICP-OES). The use of the cesium carbonate preparation method for the Isolok testing provided an opportunity for an additional assessment of this dissolution method, which is being investigated as a potential replacement for the two methods (i.e., sodium peroxide fusion and mixed acid dissolution) that have been used at the DWPF for the analysis of SME samples. Earlier testing of the Cs{sub 2}CO{sub 3} method yielded promising results which led to a TTR from Savannah River Remediation, LLC (SRR) to SRNL for additional support and an associated TTQAP to direct the SRNL efforts. A technical report resulting from this work was issued that recommended that the mixed acid method be replaced by the Cs{sub 2}CO{sub 3} method for the measurement of magnesium (Mg), sodium (Na), and zirconium (Zr) with additional testing of the method by DWPF Laboratory being needed before further implementation of the Cs{sub 2}CO{sub 3} method at that laboratory. While the SME acceptability testing of the Isolok does not address any of the open issues remaining after the publication of the recommendation for the replacement of the mixed acid method by the Cs{sub 2}CO{sub 3} method (since those issues are to be addressed by the DWPF Laboratory), the Cs{sub 2}CO{sub 3} testing associated with the Isolok testing does provide additional insight into the performance of the method as conducted by SRNL. The performance is to be investigated by looking to the composition measurement data generated by the samples of a standard glass, the Analytical Reference Glass - 1 (ARG-1), that were prepared by the Cs{sub 2}CO{sub 3} method and included in the SME acceptability testing of the Isolok. The measurements of these samples were presented as part of the study results, but no statistical analysis of these measurements was conducted as part of those results. It is the purpose of this report to provide that analysis, which was supported using JMP Version 7.0.2.« less

CO2 capture from air by Chlorella vulgaris microalgae in an airlift photobioreactor.

PubMed

Sadeghizadeh, Aziz; Farhad Dad, Farid; Moghaddasi, Leila; Rahimi, Rahbar

2017-11-01

In this work, hydrodynamics and CO 2 biofixation study was conducted in an airlift bioreactor at the temperature of 30±2°C. The main objective of this work was to investigate the effect of high gas superficial velocity on CO 2 biofixation using Chlorella vulgaris microalgae and its growth. The study showed that Chlorella vulgaris in high input gas superficial velocity also had the ability to grow and remove the CO 2 by less than 80% efficiency. Copyright © 2017 Elsevier Ltd. All rights reserved.

MarCO CubeSat Engineers 2

NASA Image and Video Library

2016-01-20

Engineers for NASA's MarCO (Mars Cube One) technology demonstration inspect one of the two MarCO CubeSats. Cody Colley, MarCO integration and test deputy, left, and Andy Klesh, MarCO chief engineer, are on the team at NASA's Jet Propulsion Laboratory, Pasadena, California, preparing twin MarCO CubeSats. The briefcase-size MarCO twins were designed to ride along with NASA's next Mars lander, InSight. Its planned March 2016 launch was suspended. InSight -- an acronym for Interior Exploration using Seismic Investigations, Geodesy and Heat Transport -- will study the interior of Mars to improve understanding of the processes that formed and shaped rocky planets, including Earth. Note: After thorough examination, NASA managers have decided to suspend the planned March 2016 launch of the Interior Exploration using Seismic Investigations Geodesy and Heat Transport (InSight) mission. The decision follows unsuccessful attempts to repair a leak in a section of the prime instrument in the science payload. http://photojournal.jpl.nasa.gov/catalog/PIA20342

A multi-period optimization model for energy planning with CO(2) emission consideration.

PubMed

Mirzaesmaeeli, H; Elkamel, A; Douglas, P L; Croiset, E; Gupta, M

2010-05-01

A novel deterministic multi-period mixed-integer linear programming (MILP) model for the power generation planning of electric systems is described and evaluated in this paper. The model is developed with the objective of determining the optimal mix of energy supply sources and pollutant mitigation options that meet a specified electricity demand and CO(2) emission targets at minimum cost. Several time-dependent parameters are included in the model formulation; they include forecasted energy demand, fuel price variability, construction lead time, conservation initiatives, and increase in fixed operational and maintenance costs over time. The developed model is applied to two case studies. The objective of the case studies is to examine the economical, structural, and environmental effects that would result if the electricity sector was required to reduce its CO(2) emissions to a specified limit. Copyright 2009 Elsevier Ltd. All rights reserved.

Carbon dioxide assisted sustainability enhancement of pyrolysis of waste biomass: A case study with spent coffee ground.

PubMed

Cho, Dong-Wan; Cho, Seong-Heon; Song, Hocheol; Kwon, Eilhann E

2015-01-01

This work mainly presents the influence of CO2 as a reaction medium in the thermo-chemical process (pyrolysis) of waste biomass. Our experimental work mechanistically validated two key roles of CO2 in pyrolysis of biomass. For example, CO2 expedited the thermal cracking of volatile organic compounds (VOCs) evolved from the thermal degradation of spent coffee ground (SCG) and reacted with VOCs. This enhanced thermal cracking behavior and reaction triggered by CO2 directly led to the enhanced generation of CO (∼ 3000%) in the presence of CO2. As a result, this identified influence of CO2 also directly led to the substantial decrease (∼ 40-60%) of the condensable hydrocarbons (tar). Finally, the morphologic change of biochar was distinctive in the presence of CO2. Therefore, a series of the adsorption experiments with dye were conducted to preliminary explore the physico-chemical properties of biochar induced by CO2. Copyright © 2015 Elsevier Ltd. All rights reserved.

20 CFR 411.450 - What is an Individual Work Plan?

Code of Federal Regulations, 2011 CFR

2011-04-01

... 20 Employees' Benefits 2 2011-04-01 2011-04-01 false What is an Individual Work Plan? 411.450 Section 411.450 Employees' Benefits SOCIAL SECURITY ADMINISTRATION THE TICKET TO WORK AND SELF-SUFFICIENCY... work plan (IWP) is a required written document signed by an employment network (EN) (other than a State...

20 CFR 411.450 - What is an Individual Work Plan?

Code of Federal Regulations, 2010 CFR

2010-04-01

... 20 Employees' Benefits 2 2010-04-01 2010-04-01 false What is an Individual Work Plan? 411.450 Section 411.450 Employees' Benefits SOCIAL SECURITY ADMINISTRATION THE TICKET TO WORK AND SELF-SUFFICIENCY... work plan (IWP) is a required written document signed by an employment network (EN) (other than a State...

10. Photographic copy of copy of original construction drawing, dated ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

10. Photographic copy of copy of original construction drawing, dated 1899?. Original in possession of Twin Lakes Reservoir and Canal Company, Ordway, Colorado. PLAN OF DAM AND HEAD GATES FOR THE TWIN LAKES RESERVOIR. - Twin Lakes Dam & Outlet Works, Beneath Twin Lakes Reservoir, T11S, R80W, S22, Twin Lakes, Lake County, CO

Feasibility of magnetic resonance imaging-guided liver stereotactic body radiation therapy: A comparison between modulated tri-cobalt-60 teletherapy and linear accelerator-based intensity modulated radiation therapy.

PubMed

Kishan, Amar U; Cao, Minsong; Wang, Pin-Chieh; Mikaeilian, Argin G; Tenn, Stephen; Rwigema, Jean-Claude M; Sheng, Ke; Low, Daniel A; Kupelian, Patrick A; Steinberg, Michael L; Lee, Percy

2015-01-01

The purpose of this study was to investigate the dosimetric feasibility of liver stereotactic body radiation therapy (SBRT) using a teletherapy system equipped with 3 rotating (60)Co sources (tri-(60)Co system) and a built-in magnetic resonance imager (MRI). We hypothesized tumor size and location would be predictive of favorable dosimetry with tri-(60)Co SBRT. The primary study population consisted of 11 patients treated with SBRT for malignant hepatic lesions whose linear accelerator (LINAC)-based SBRT plans met all mandatory Radiation Therapy Oncology Group (RTOG) 1112 organ-at-risk (OAR) constraints. The secondary study population included 5 additional patients whose plans did not meet the mandatory constraints. Patients received 36 to 60 Gy in 3 to 5 fractions. Tri-(60)Co system SBRT plans were planned with ViewRay system software. All patients in the primary study population had tri-(60)Co SBRT plans that passed all RTOG constraints, with similar planning target volume coverage and OAR doses to LINAC plans. Mean liver doses and V10Gy to the liver, although easily meeting RTOG 1112 guidelines, were significantly higher with tri-(60)Co plans. When the 5 additional patients were included in a univariate analysis, the tri-(60)Co SBRT plans were still equally able to pass RTOG constraints, although they did have inferior ability to pass more stringent liver and kidney constraints (P < .05). A multivariate analysis found the ability of a tri-(60)Co SBRT plan to meet these constraints depended on lesion location and size. Patients with smaller or more peripheral lesions (as defined by distance from the aorta, chest wall, liver dome, and relative lesion volume) were significantly more likely to have tri-(60)Co plans that spared the liver and kidney as well as LINAC plans did (P < .05). It is dosimetrically feasible to perform liver SBRT with a tri-(60)Co system with a built-in MRI. Patients with smaller or more peripheral lesions are more likely to have optimal liver and kidney sparing, with the added benefit of MRI guidance, when receiving tri-(60)Co-based SBRT. Copyright © 2015 American Society for Radiation Oncology. Published by Elsevier Inc. All rights reserved.

Reflecting on Talk: A Mentor Teacher's Gradual Release in Co-Planning

ERIC Educational Resources Information Center

Pylman, Stacey

2016-01-01

The goal of this case study was to explore how a mentor teacher used video-recorded co-planning sessions to reflect on and improve one's mentoring practice. Findings reveal ways in which the mentor used talk in co-planning sessions to model one's thinking process and to gradually release planning responsibility to engage the intern in learning to…

Sexuality education on the job.

PubMed

1998-01-01

The Asociacion Demografica Salvadorena (ADS) has been working with the UN Population Fund (UNFPA) in El Salvador since November 1995 to provide sexual and reproductive health services to the country's working classes. UNFPA funding is provided through the Salvadoran government. ADS has entered the commercial and labor sectors to provide sexual and reproductive health services, and expand related public education programs to marginalized working class urban residents of El Salvador's Zona Central. The project has thus far created 25 Reproductive Health Units (UDESAR) in a number of companies, overseen by trained personnel who offer family planning and counseling services, including family planning methods, and the detection of cervical/uterine cancer, breast self-examination, HIV/STD prevention, and the determination of reproductive risk. Volunteers trained by ADS in sexual and reproductive health from a gender perspective, including decision-making and raising women's levels of self-esteem and decision-making capabilities in family planning, safe sex, and general sexual health, help project leaders by educating and motivating co-workers. ADS's involvement in promoting reproductive health in El Salvador has also given the organization an opportunity to broaden its relationship with international agencies.

Building a Leadership Pipeline: A Focus on Succession Planning with the Department of Veterans Affairs

DTIC Science & Technology

2015-06-12

Veterans Affairs 5d. PROJECT NUMBER 5e. TASK NUMBER 5f. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) U.S. Army...experience. Additionally, I would like to thank all of my co-workers at the department who supported me this past year and continued to work tirelessly...process claims and communicate with Veterans. Before the transformation initiative, the majority of VBA claims were in paper format with a small

Proceedings of the Annual Military Librarians’ Workshop (29th) Held in Colorado Springs, CO, on 9-11 October 1985

DTIC Science & Technology

1985-10-11

structure works merely because it is well- designed and looks good or. paper. They know form experience that the organizational system works well only...organizational communication doesn’t just happen; it needs to be planned for, designed , executed, and evaluated. The library manager who believes that...Communication) •: M.A., University of Colorado (Environmental Design ) A., University of Colorado (Communication) According to Dr. Rader, librarians, as keepers

Grupo de Trabajo Para la Preparacion del Proyecto Sobre el Desarrolo de Servicias de Bibliotecas y de Informacion Cientifica y Tecnica (Working Group for the Preparation of the Proposal on the Development of Library Services and Scientific and Technical Information).

ERIC Educational Resources Information Center

Oficina de Educacion Iberoamericana, Madrid (Spain).

The Office of Iberoamerican Education, an intergovernmental body based on educational and cultural cooperation for the purpose of disseminating information, documentation, advice, and assistance in the field of education, co-sponsors (with UNESCO) the work represented in this study of library and information planning and facilities in the Andean…

PlanWorks: A Debugging Environment for Constraint Based Planning Systems

NASA Technical Reports Server (NTRS)

Daley, Patrick; Frank, Jeremy; Iatauro, Michael; McGann, Conor; Taylor, Will

2005-01-01

Numerous planning and scheduling systems employ underlying constraint reasoning systems. Debugging such systems involves the search for errors in model rules, constraint reasoning algorithms, search heuristics, and the problem instance (initial state and goals). In order to effectively find such problems, users must see why each state or action is in a plan by tracking causal chains back to part of the initial problem instance. They must be able to visualize complex relationships among many different entities and distinguish between those entities easily. For example, a variable can be in the scope of several constraints, as well as part of a state or activity in a plan; the activity can arise as a consequence of another activity and a model rule. Finally, they must be able to track each logical inference made during planning. We have developed PlanWorks, a comprehensive system for debugging constraint-based planning and scheduling systems. PlanWorks assumes a strong transaction model of the entire planning process, including adding and removing parts of the constraint network, variable assignment, and constraint propagation. A planner logs all transactions to a relational database that is tailored to support queries for of specialized views to display different forms of data (e.g. constraints, activities, resources, and causal links). PlanWorks was specifically developed for the Extensible Universal Remote Operations Planning Architecture (EUROPA(sub 2)) developed at NASA, but the underlying principles behind PlanWorks make it useful for many constraint-based planning systems. The paper is organized as follows. We first describe some fundamentals of EUROPA(sub 2). We then describe PlanWorks' principal components. We then discuss each component in detail, and then describe inter-component navigation features. We close with a discussion of how PlanWorks is used to find model flaws.

Integrated CO2 capture-fixation chemistry via interfacial ionic liquid catalyst in laminar gas/liquid flow

NASA Astrophysics Data System (ADS)

Vishwakarma, Niraj K.; Singh, Ajay K.; Hwang, Yoon-Ho; Ko, Dong-Hyeon; Kim, Jin-Oh; Babu, A. Giridhar; Kim, Dong-Pyo

2017-03-01

Simultaneous capture of carbon dioxide (CO2) and its utilization with subsequent work-up would significantly enhance the competitiveness of CO2-based sustainable chemistry over petroleum-based chemistry. Here we report an interfacial catalytic reaction platform for an integrated autonomous process of simultaneously capturing/fixing CO2 in gas-liquid laminar flow with subsequently providing a work-up step. The continuous-flow microreactor has built-in silicon nanowires (SiNWs) with immobilized ionic liquid catalysts on tips of cone-shaped nanowire bundles. Because of the superamphiphobic SiNWs, a stable gas-liquid interface maintains between liquid flow of organoamines in upper part and gas flow of CO2 in bottom part of channel. The intimate and direct contact of the binary reagents leads to enhanced mass transfer and facilitating reactions. The autonomous integrated platform produces and isolates 2-oxazolidinones and quinazolines-2,4(1H,3H)-diones with 81-97% yields under mild conditions. The platform would enable direct CO2 utilization to produce high-valued specialty chemicals from flue gases without pre-separation and work-up steps.

Integrated CO2 capture-fixation chemistry via interfacial ionic liquid catalyst in laminar gas/liquid flow.

PubMed

Vishwakarma, Niraj K; Singh, Ajay K; Hwang, Yoon-Ho; Ko, Dong-Hyeon; Kim, Jin-Oh; Babu, A Giridhar; Kim, Dong-Pyo

2017-03-06

Simultaneous capture of carbon dioxide (CO 2 ) and its utilization with subsequent work-up would significantly enhance the competitiveness of CO 2 -based sustainable chemistry over petroleum-based chemistry. Here we report an interfacial catalytic reaction platform for an integrated autonomous process of simultaneously capturing/fixing CO 2 in gas-liquid laminar flow with subsequently providing a work-up step. The continuous-flow microreactor has built-in silicon nanowires (SiNWs) with immobilized ionic liquid catalysts on tips of cone-shaped nanowire bundles. Because of the superamphiphobic SiNWs, a stable gas-liquid interface maintains between liquid flow of organoamines in upper part and gas flow of CO 2 in bottom part of channel. The intimate and direct contact of the binary reagents leads to enhanced mass transfer and facilitating reactions. The autonomous integrated platform produces and isolates 2-oxazolidinones and quinazolines-2,4(1H,3H)-diones with 81-97% yields under mild conditions. The platform would enable direct CO 2 utilization to produce high-valued specialty chemicals from flue gases without pre-separation and work-up steps.

Integrated CO2 capture-fixation chemistry via interfacial ionic liquid catalyst in laminar gas/liquid flow

PubMed Central

Vishwakarma, Niraj K.; Singh, Ajay K.; Hwang, Yoon-Ho; Ko, Dong-Hyeon; Kim, Jin-Oh; Babu, A. Giridhar; Kim, Dong-Pyo

2017-01-01

Simultaneous capture of carbon dioxide (CO2) and its utilization with subsequent work-up would significantly enhance the competitiveness of CO2-based sustainable chemistry over petroleum-based chemistry. Here we report an interfacial catalytic reaction platform for an integrated autonomous process of simultaneously capturing/fixing CO2 in gas–liquid laminar flow with subsequently providing a work-up step. The continuous-flow microreactor has built-in silicon nanowires (SiNWs) with immobilized ionic liquid catalysts on tips of cone-shaped nanowire bundles. Because of the superamphiphobic SiNWs, a stable gas–liquid interface maintains between liquid flow of organoamines in upper part and gas flow of CO2 in bottom part of channel. The intimate and direct contact of the binary reagents leads to enhanced mass transfer and facilitating reactions. The autonomous integrated platform produces and isolates 2-oxazolidinones and quinazolines-2,4(1H,3H)-diones with 81–97% yields under mild conditions. The platform would enable direct CO2 utilization to produce high-valued specialty chemicals from flue gases without pre-separation and work-up steps. PMID:28262667

Wetlands Mitigation Banking Concepts

DTIC Science & Technology

1992-07-01

Naval Amphibious Bas Eslgrss Mit. Bank CA, San Diego Co. dredging & facilities Dept of the Navy SeaWorld Eelgras Mitigation Dank CA, San Diego Co...shore development, private projects SeaWorld 8 Table 2. WETLAND MITIGATION BANKS UNDER PLANNING, Institute for Water Resources Preliminary Survey Data

Observing System Simulations for the NASA ASCENDS Lidar CO2 Mission Concept: Substantiating Science Measurement Requirements

NASA Technical Reports Server (NTRS)

Kawa, Stephan R.; Baker, David Frank; Schuh, Andrew E.; Abshire, James Brice; Browell, Edward V.; Michalak, Anna M.

2012-01-01

The NASA ASCENDS mission (Active Sensing of Carbon Emissions, Nights, Days, and Seasons) is envisioned as the next generation of dedicated, space-based CO2 observing systems, currently planned for launch in about the year 2022. Recommended by the US National Academy of Sciences Decadal Survey, active (lidar) sensing of CO2 from space has several potentially significant advantages, in comparison to current and planned passive CO2 instruments, that promise to advance CO2 measurement capability and carbon cycle understanding into the next decade. Assessment and testing of possible lidar instrument technologies indicates that such sensors are more than feasible, however, the measurement precision and accuracy requirements remain at unprecedented levels of stringency. It is, therefore, important to quantitatively and consistently evaluate the measurement capabilities and requirements for the prospective active system in the context of advancing our knowledge of carbon flux distributions and their dependence on underlying physical processes. This amounts to establishing minimum requirements for precision, relative accuracy, spatial/temporal coverage and resolution, vertical information content, interferences, and possibly the tradeoffs among these parameters, while at the same time framing a mission that can be implemented within a constrained budget. Here, we present results of observing system simulation studies, commissioned by the ASCENDS Science Requirements Definition Team, for a range of possible mission implementation options that are intended to substantiate science measurement requirements for a laser-based CO2 space instrument.

Model quantification of the CO2 storage in the Los Páramos site (Duero basin, NE Spain)

NASA Astrophysics Data System (ADS)

Nardi, Albert; Grandia, Fidel; Abarca, Elena; Motis, Kilian; Molinero, Jorge

2013-04-01

The Duero basin in NW Spain is one the most promising basin for CO2 storage in the Iberian Peninsula due to the existence of favourable deep aquifers close to large CO2 emission point sources. A number of projects are presently active either for scientific research (e.g., the Hontomín site, OXI-CFB300 EPRR project) or commercial purposes (e.g., Sahagún and Los Páramos projects). The project called Los Páramos intends to assess the injection of CO2 in a group of dome-shaped structures with an estimated total capacity of 200 Mt (ranked 2nd in the Iberian Peninsula, IGME 2010). These domes were studied in the past for hydrocarbon exploration and a large body of information is available from seismic profiles (over 170 km) and 3 deep wells. The Los Páramos site is emplaced in the San Pedro Folded Band (SPFB) that consists mainly of thick-skinned thrusts of Mesozoic rocks (Triassic and Upper Cretaceous) sealed by a thick (1200-1500 m), undeformed cover of Tertiary claystones. Dome-like structures are related to thrusts leading to favourable reservoirs. The target horizon for CO2 storage is the Utrillas Fm sandstone with high porosity (13-20%) and thickness (225-250 m). In three of the domes, the Utrillas Fm is below -800m, allowing thus the storage of CO2(sc). This sandstone hosts an aquifer containing saline water, up to 50 g·L-1, according to the data from drill wells. The presence of saline groundwater is explained by water interaction with Triassic evaporite layers just underlying the Utrillas Fm sandstones. The CO2 storage at Los Paramos site is planned via injection of supercritical CO2 (CO2(sc)) in the Utrillas Fm. In general, the next four trapping mechanisms are expected, which are of increasing importance through time (1) structural, (2) residual saturation, (3) dissolution, and (4) mineral. The prediction of the mass of CO2 stored through time in any storage systems is an essential parameter in the pre-injection assessment of a geological storage. For safety reasons, it is relevant to know the mass of CO2 trapped under the different trapping mechanisms. In this work, storage quantification in the Dome B of Los Páramos site has been performed by using multiphase transport simulations with COMSOL Multiphysics. Model results predict well the amount of CO2 trapped as residual phase and the onset of the formation of CO2-rich brine fingers and their extent and evolution.

Modelling of Seismic and Resistivity Responses during the Injection of CO2 in Sandstone Reservoir

NASA Astrophysics Data System (ADS)

Omar, Muhamad Nizarul Idhafi Bin; Almanna Lubis, Luluan; Nur Arif Zanuri, Muhammad; Ghosh, Deva P.; Irawan, Sonny; Regassa Jufar, Shiferaw

2016-07-01

Enhanced oil recovery plays vital role in production phase in a producing oil field. Initially, in many cases hydrocarbon will naturally flow to the well as respect to the reservoir pressure. But over time, hydrocarbon flow to the well will decrease as the pressure decrease and require recovery method so called enhanced oil recovery (EOR) to recover the hydrocarbon flow. Generally, EOR works by injecting substances, such as carbon dioxide (CO2) to form a pressure difference to establish a constant productive flow of hydrocarbon to production well. Monitoring CO2 performance is crucial in ensuring the right trajectory and pressure differences are established to make sure the technique works in recovering hydrocarbon flow. In this paper, we work on computer simulation method in monitoring CO2 performance by seismic and resistivity model, enabling geoscientists and reservoir engineers to monitor production behaviour as respect to CO2 injection.

Co-Production at the Strategic Level: Co-Designing an Integrated Care System with Lay Partners in North West London, England

PubMed Central

Morton, Michael

2016-01-01

In North West London, health and social care leaders decided to design a system of integrated care with the aim of improving the quality of care and supporting people to maintain independence and participation in their community. Patients and carers, known as ‘lay partners,’ were to be equal partners in co-production of the system. Lay partners were recruited by sending a role profile to health, social care and voluntary organisations and requesting nominations. They formed a Lay Partners Advisory Group from which pairs were allocated to system design workstreams, such as which population to focus on, financial flow, information technology and governance. A larger and more diverse Lay Partners Forum provided feedback on the emerging plans. A key outcome of this approach was the development of an integration toolkit co-designed with lay partners. Lay partners provided challenge, encouraged innovation, improved communication, and held the actions of other partners to account to ensure the vision and aims of the emerging integrated care system were met. Key lessons from the North West London experience for effective co-production include: recruiting patients and carers with experience of strategic work; commitment to the vision; willingness to challenge and to listen; strong connections within the community being served; and enough time to do the work. Including lay partners in co-design from the start, and at every level, was important. Agreeing the principles of working together, providing support and continuously recruiting lay representatives to represent their communities are keys to effective co-production. PMID:27616958

Co-Production at the Strategic Level: Co-Designing an Integrated Care System with Lay Partners in North West London, England.

PubMed

Morton, Michael; Paice, Elisabeth

2016-05-03

In North West London, health and social care leaders decided to design a system of integrated care with the aim of improving the quality of care and supporting people to maintain independence and participation in their community. Patients and carers, known as 'lay partners,' were to be equal partners in co-production of the system. Lay partners were recruited by sending a role profile to health, social care and voluntary organisations and requesting nominations. They formed a Lay Partners Advisory Group from which pairs were allocated to system design workstreams, such as which population to focus on, financial flow, information technology and governance. A larger and more diverse Lay Partners Forum provided feedback on the emerging plans. A key outcome of this approach was the development of an integration toolkit co-designed with lay partners. Lay partners provided challenge, encouraged innovation, improved communication, and held the actions of other partners to account to ensure the vision and aims of the emerging integrated care system were met. Key lessons from the North West London experience for effective co-production include: recruiting patients and carers with experience of strategic work; commitment to the vision; willingness to challenge and to listen; strong connections within the community being served; and enough time to do the work. Including lay partners in co-design from the start, and at every level, was important. Agreeing the principles of working together, providing support and continuously recruiting lay representatives to represent their communities are keys to effective co-production.

Analysis of Required Supporting Systems for the Supercritical CO(2) Power Conversion System

DTIC Science & Technology

2007-09-01

been drawn to the viability of using S-C02 as a working fluid in modern reactor designs. Near the critical point, C02 has a rapid rise in density...viability of using S-CO2 as a working fluid in modern reactor designs. Near the critical point, CO2 has a rapid rise in density allowing a significant...32 Figure 2.2.3 Effect on Mass Transferred of Changing ICV Initial Temperature for emptying PCS ...................32 Figure 2.2.4 Effect

Large Pilot CAER Heat Integrated Post-combustion CO 2 Capture Technology for Reducing the Cost of Electricity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Kunlei; Nikolic, Heather; Placido, Andrew

The goal of this final project report is to comprehensively summarize the work conducted on project DE-FE0026497. In accordance with the Statement of Project Objectives (SOPO), the University of Kentucky Center for Applied Energy Research (UKy-CAER) (Recipient) has developed an advanced, versatile, 10 MWe post-combustion CO 2 capture system (CCS) for a coal-fired power plant, Louisville Gas and Electric Company’s Trimble County Generating Station, using a heat integrated process combined with two-stage stripping and any advanced solvent to enhance the CO 2 absorber performance. The proposed project (Phase 1 and 2) will involve the design, fabrication, installation and testing ofmore » a large pilot scale facility that will demonstrate the UKy-CAER innovative carbon capture system integrated with an operating supercritical power plant. Specifically during Phase 1, the Recipient has provided all necessary documentation to support its Phase 2 down-selection including: the Project Narrative, the updated Project Management Plan (PMP), the preliminary engineering design, the Technical and Economic Analysis report (TEA) (including the Case 12 – Major Equipment List and submitted as a Topical Report), a Phase 1 Technology Gap Analysis (TGA), an Environmental Health and Safety (EH&S) Assessment on the 10 MWe unit, and updated Phase 2 cost estimates (including the detailed design, procurement, construction, operation, and decommissioning costs) with a budget justification. Furthermore, the Recipient has proposed a combined modular and freestanding column configuration with an advanced absorber gas/liquid distribution system, an advanced solvent, with the integration of discrete packing, a smart cross-over heat exchanger, and a load and ambient condition following control strategy, all to address ten of 12 technology gaps identified during the Phase I work. If successful, the proposed heat integrated post-combustion CCS will pave the way to achieve the United States Department of Energy National Energy Technology Laboratory (U.S. DOE NETL) CO 2 capture performance and cost target, as indicated in the submitted TEA and summarized in this report.« less

Interactive dose shaping part 2: proof of concept study for six prostate patients

PubMed Central

Ph Kamerling, Cornelis; Ziegenhein, Peter; Sterzing, Florian; Oelfke, Uwe

2016-01-01

Abstract Recently we introduced interactive dose shaping (IDS) as a new IMRT planning strategy. This planning concept is based on a hierarchical sequence of local dose modification and recovery operations. The purpose of this work is to provide a feasibility study for the IDS planning strategy based on a small set of six prostate patients. The IDS planning paradigm aims to perform interactive local dose adaptations of an IMRT plan without compromising already established valuable dose features in real-time. Various IDS tools were developed in our in-house treatment planning software Dynaplan and were utilized to create IMRT treatment plans for six patients with an adeno-carcinoma of the prostate. The sequenced IDS treatment plans were compared to conventionally optimized clinically approved plans (9 beams, co-planar). For each patient, several IDS plans were created, with different trade-offs between organ sparing and target coverage. The reference dose distributions were imported into Dynaplan. For each patient, the IDS treatment plan with a similar or better trade-off between target coverage and OAR sparing was selected for plan evaluation, guided by a physician. For this initial study we were able to generate treatment plans for prostate geometries in 15–45 min. Individual local dose adaptations could be performed in less than one second. The average differences compared to the reference plans were for the mean dose: 0.0 Gy (boost) and 1.2 Gy (PTV), for \\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{upgreek} \\usepackage{mathrsfs} \\setlength{\\oddsidemargin}{-69pt} \\begin{document} }{}${{D}_{98\\%}}:-1.1$ \\end{document}D98%:−1.1 Gy and for \\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{upgreek} \\usepackage{mathrsfs} \\setlength{\\oddsidemargin}{-69pt} \\begin{document} }{}${{D}_{2\\%}}:1.1$ \\end{document}D2%:1.1 Gy (both target volumes). The dose-volume quality indicators were well below the Quantec constraints. However, we also observed limitations of our currently implemented approach. Most prominent was an increase of the non-tumor integral dose by 16.4% on average, demonstrating that further developments of our planning strategy are required. PMID:26948274

Measuring the Absorption Rate of CO 2 in Nonaqueous CO 2 -Binding Organic Liquid Solvents with a Wetted-Wall Apparatus

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mathias, Paul M.; Zheng, Feng; Heldebrant, David J.

2015-09-17

The kinetics of the absorption of CO 2 into two nonaqueous CO 2-binding organic liquid (CO 2BOL) solvents were measured at T=35, 45, and 55 °C with a wetted-wall column. Selected CO 2 loadings were run with a so-called “first-generation” CO 2BOL, comprising an independent base and alcohol, and a “second-generation” CO 2BOL, in which the base and alcohol were conjoined. Liquid-film mass-transfer coefficient (k'g) values for both solvents were measured to be comparable to values for monoethanolamine and piperazine aqueous solvents under a comparable driving force, in spite of far higher solution viscosities. An inverse temperature dependence of themore » k'g value was also observed, which suggests that the physical solubility of CO 2 in organic liquids may be making CO 2 mass transfer faster than expected. Aspen Plus software was used to model the kinetic data and compare the CO 2 absorption behavior of nonaqueous solvents with that of aqueous solvent platforms. This work continues our development of the CO2BOL solvents. Previous work established the thermodynamic properties related to CO 2 capture. The present paper quantitatively studies the kinetics of CO 2 capture and develops a rate-based model.« less

Early stages of epitaxial CoSi 2 formation on Si(111) surface as investigated by ARUPS, XPS, LEED and work function variation

NASA Astrophysics Data System (ADS)

Pirri, C.; Peruchetti, J. C.; Gewinner, G.; Derrien, J.

1985-04-01

We performed the CoSi 2 formation on a clean (7 × 7) Si(111) surface under UHV conditions. The used techniques were angle resolved UV photoemission, X-ray photoemission, work function change and low energy electron diffraction in order to study the electronic and structural properties of the interface during its formation. At room temperature, a small amount of Co reacts strongly with Si to form an interfacial and very thin cobalt suicide. The ultraviolet photoelectron spectrum displays already two features corresponding respectively to the Co 3d and Si 3p electron bonding states and the Co 3d non-bonding states. With increasing coverage ( θ ≳ 4 ML) it seems that the interfacial suicide prevents further Co-Si interdiffusion to achieve the suicide reaction and a metal rich film is found. At high temperature (˜ 600°C) and in the first monolayer range, several superstructures are found (√7 × √7, and 2 × 2). They are induced by a Co-Si bidimensional compound where the Co atoms are not yet completely surrounded by Si atoms as in their bulk CoSi 2 structure. With increasing coverage, a CoSi 2-like photoemission spectrum is observed reflecting the formation of the disilicide. The LEED pattern testifies an epitaxial growth displaying a (1 × 1) CoSi 2 diagram. The work function change technique also reflects faithfully this growth.

Increasing work-time influence: consequences for flexibility, variability, regularity and predictability.

PubMed

Nabe-Nielsen, Kirsten; Garde, Anne Helene; Aust, Birgit; Diderichsen, Finn

2012-01-01

This quasi-experimental study investigated how an intervention aiming at increasing eldercare workers' influence on their working hours affected the flexibility, variability, regularity and predictability of the working hours. We used baseline (n = 296) and follow-up (n = 274) questionnaire data and interviews with intervention-group participants (n = 32). The work units in the intervention group designed their own intervention comprising either implementation of computerised self-scheduling (subgroup A), collection of information about the employees' work-time preferences by questionnaires (subgroup B), or discussion of working hours (subgroup C). Only computerised self-scheduling changed the working hours and the way they were planned. These changes implied more flexible but less regular working hours and an experience of less predictability and less continuity in the care of clients and in the co-operation with colleagues. In subgroup B and C, the participants ended up discussing the potential consequences of more work-time influence without actually implementing any changes. Employee work-time influence may buffer the adverse effects of shift work. However, our intervention study suggested that while increasing the individual flexibility, increasing work-time influence may also result in decreased regularity of the working hours and less continuity in the care of clients and co-operation with colleagues.

Integrated Monitoring and Modeling of Carbon Dioxide Leakage Risk Using Remote Sensing, Ground-Based Monitoring, Atmospheric Models and Risk-Indexing Tools

NASA Astrophysics Data System (ADS)

Burton, E. A.; Pickles, W. L.; Gouveia, F. J.; Bogen, K. T.; Rau, G. H.; Friedmann, J.

2006-12-01

Correct assessment of the potential for CO2 leakage to the atmosphere or near surface is key to managing the risk associated with CO2 storage. Catastrophic, point-source leaks, diffuse seepage, and low leakage rates all merit assessment. Smaller leaks may be early warnings of catastrophic failures, and may be sufficient to damage natural vegetation or crops. Small leaks also may lead to cumulative build-up of lethal levels of CO2 in enclosed spaces, such as basements, groundwater-well head spaces, and caverns. Working with our ZERT partners, we are integrating a variety of monitoring and modeling approaches to understand how to assess potential health, property and environmental risks across this spectrum of leakage types. Remote sensing offers a rapid technique to monitor large areas for adverse environmental effects. If it can be deployed prior to the onset of storage operations, remote sensing also can document baseline conditions against which future claims of environmental damage can be compared. LLNL has been using hyperspectral imaging to detect plant stress associated with CO2 gas leakage, and has begun investigating use of NASA's new satellite or airborne instrumentation that directly measures gas compositions in the atmosphere. While remote sensing techniques have been criticized as lacking the necessary resolution to address environmental problems, new instruments and data processing techniques are demonstrated to resolve environmental changes at the scale associated with gas-leakage scenarios. During the shallow low-flow- CO2 release field experiments planned by ZERT, for the first time, we will have the opportunity to ground- truth hyperspectral data by simultaneous measurement of changes in hyperspectral readings, soil and root zone microbiology, ambient air, soil and aquifer CO2 concentrations. When monitoring data appear to indicate a CO2 leakage event, risk assessment and mitigation of that event requires a robust and nearly real-time method for estimating its associated risk, spatially and temporally. This requires integration of subsurface, surface and atmospheric data and models. To date, we have developed techniques to map risk based on predicted atmospheric plumes and GIS/MT (meteorologic- topographic) risk-indexing tools. This methodology was derived from study of large CO2 releases from an abandoned well penetrating a natural CO2 reservoir at Crystal Geyser, Utah. This integrated approach will provide a powerful tool to screen for high-risk zones at proposed sequestration sites, to design and optimize surface networks for site monitoring and/or to guide setting science-based regulatory compliance requirements for monitoring sequestration sites, as well as to target critical areas for first responders should a catastrophic-release event occur. This work was performed under the auspices of the U.S. Dept. of Energy by University of California, Lawrence Livermore National Laboratory under Contract W-7405-Eng-48.

SU-F-J-125: Effects of Couch Position Variability On Dosimetric Accuracy with An MRI-Guided Co-60 Radiation Therapy Machine

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chow, P; Thomas, D; Agazaryan, N

2016-06-15

Purpose: Magnetic resonance imaging (MRI) guidance in radiation therapy brings real-time imaging and adaptive planning into the treatment vault where it can account for interfraction and intrafraction movement of soft tissue. The only commercially-available MRI-guided radiation therapy device is a three-head 60Co and MRI system with an integrated treatment planning system (TPS). An up to 20% attenuation of the beam by the couch is well modeled in the TPS. However, variations in the patient’s day-to-day position introduce discrepancies in the actual couch position relative its location as modeled in the treatment plan. For this reason, our institution avoids plans withmore » beams that pass through or near the couch edges. This study looks at plans without restriction on beam angles and investigates the effects of couch shift by simulating shifts of the couch relative to the patient, in order to determine whether couch edge avoidance restrictions can be lifted. Methods: A total of 27 plans from 23 patients were investigated. Couch shifts of 1 and 2 cm were introduced in combinations of lateral and vertical direction to simulate variations in patient positioning on the couch giving 16 shifted plans per reference plan. The shift values of 1 and 2 cm were based on shifts recorded in 320 treatment fractions. Results: Measured couch attenuation versus TPS modeled agreed within 2.1%. Planning Target Volume (PTV) D95 changed less than 1% for 1 and 2 cm couch shifts in only the x-direction and less than 3% for all directions. Conclusion: The dosimetry of all plans with shifts up to ±2 cm was within reasonable clinical tolerances. Robustness of a plan to couch shifts can be tested in the TPS. Inclusion of beams traversing the couch edges should be considered if an improvement in plan quality or delivery time can be achieved.« less

Technical Note: Dosimetric effects of couch position variability on treatment plan quality with an MRI-guided Co-60 radiation therapy machine

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chow, Phillip E., E-mail: pechow@mednet.ucla.edu

2016-08-15

Purpose: Magnetic resonance imaging (MRI) guidance in radiation therapy brings real-time imaging and adaptive planning into the treatment vault where it can account for interfraction and intrafraction movement of soft tissue. The only commercially available MRI-guided radiation therapy device is a three-head {sup 60}Co and MRI system with an integrated treatment planning system (TPS). Couch attenuation of the beam of up to 20% is well modeled in the TPS. Variations in the patient’s day-to-day position introduce discrepancies in the actual couch attenuation as modeled in the treatment plan. For this reason, the authors’ institution avoids plans with beams that passmore » through or near the couch edges. This study investigates the effects of differential beam attenuation by the couch due to couch shifts in order to determine whether couch edge avoidance restrictions can be lifted. Couch shifts were simulated using a Monte Carlo treatment planning system and ion chamber measurements performed for validation. Methods: A total of 27 plans from 23 patients were investigated. Couch shifts of 1 and 2 cm were introduced in combinations of lateral and vertical directions to simulate patient position variations giving 16 shifted plans per reference plan. The 1 and 2 cm shifts were based on shifts recorded in 320 treatment fractions. Results: Following TG176 recommendations for measurement methods, couch attenuation measurements agreed with TPS modeled attenuation to within 2.1%. Planning target volume D95 changed less than 1% for 1 and 2 cm couch shifts in only the x-direction and less than 3% for all directions. Conclusions: Dosimetry of all plans tested was robust to couch shifts up to ±2 cm. In general, couch shifts resulted in clinically insignificant dosimetric deviations. It is conceivable that in certain cases with large systematic couch shifts and plans that are particularly sensitive to shifts, dosimetric changes might rise to a clinically significant level.« less

Studies of Cobalt-Mediated Electrocatalytic CO2 Reduction Using a Redox-Active Ligand

PubMed Central

2015-01-01

The cobalt complex [CoIIIN4H(Br)2]+ (N4H = 2,12-dimethyl-3,7,11,17-tetraazabicyclo-[11.3.1]-heptadeca-1(7),2,11,13,15-pentaene) was used for electrocatalytic CO2 reduction in wet MeCN with a glassy carbon working electrode. When water was employed as the proton source (10 M in MeCN), CO was produced (fCO= 45% ± 6.4) near the CoI/0 redox couple for [CoIIIN4H(Br)2]+ (E1/2 = −1.88 V FeCp2+/0) with simultaneous H2 evolution (fH2= 30% ± 7.8). Moreover, we successfully demonstrated that the catalytically active species is homogeneous through the use of control experiments and XPS studies of the working glassy-carbon electrodes. As determined by cyclic voltammetry, CO2 catalysis occurred near the formal CoI/0redox couple, and attempts were made to isolate the triply reduced compound (“[Co0N4H]”). Instead, the doubly reduced (“CoI”) compounds [CoN4] and [CoN4H(MeCN)]+ were isolated and characterized by X-ray crystallography. Their molecular structures prompted DFT studies to illuminate details regarding their electronic structure. The results indicate that reducing equivalents are stored on the ligand, implicating redox noninnocence in the ligands for H2 evolution and CO2 reduction electrocatalysis. PMID:24773584

2D Seismic Velocity Modelling in the Southeastern Romanian Carpathians and its Foreland (Vrancea Zone and Focsani Basin)

NASA Astrophysics Data System (ADS)

Stephenson, R.; Bocin, A.; Tryggvason, A.

2003-12-01

The DACIA-PLAN (Danube and Carpathian Integrated Action on Processes in the Lithosphere and Neotectonics) deep seismic reflection survey was performed in August-September 2001, with the objective of obtaining of new information on the deep structure of the external Carpathians nappes and the architecture of Tertiary/Quaternary basins developed within and adjacent to the seismically-active Vrancea Zone, including the rapidly subsiding Focsani Basin. The DACIA-PLAN profile is about 140 km long, having a roughly NW-SE direction, from near the southeast Transylvanian Basin, across the mountainous southeastern Carpathians and their foreland to near the Danube Dalta. A high resolution 2D velocity model of the upper crust along the seismic profile has been determined from a first-arrival tomographic inversion of the DACIA-PLAN data. The shallowing of Palaeozoic-Mesozoic basement, and related structural heterogeneity within it, beneath the eastern flank of the Focsani Basin is clearly seen. Velocity heterogeneity within the Carpathian nappe belt is also evident and is indicative of internal structural complexity, including the presence of salt bodies and basement involvement in thrusting, thus favouring some current geological models over others. The presence of basement involvement implies the compressional reactivation of pre-existing basement normal faults. Members of the DACIA-PLAN/TomoSeis Working Group (see poster) should be considered as co-authors of this presentation.

Low-CO(2) electricity and hydrogen: a help or hindrance for electric and hydrogen vehicles?

PubMed

Wallington, T J; Grahn, M; Anderson, J E; Mueller, S A; Williander, M I; Lindgren, K

2010-04-01

The title question was addressed using an energy model that accounts for projected global energy use in all sectors (transportation, heat, and power) of the global economy. Global CO(2) emissions were constrained to achieve stabilization at 400-550 ppm by 2100 at the lowest total system cost (equivalent to perfect CO(2) cap-and-trade regime). For future scenarios where vehicle technology costs were sufficiently competitive to advantage either hydrogen or electric vehicles, increased availability of low-cost, low-CO(2) electricity/hydrogen delayed (but did not prevent) the use of electric/hydrogen-powered vehicles in the model. This occurs when low-CO(2) electricity/hydrogen provides more cost-effective CO(2) mitigation opportunities in the heat and power energy sectors than in transportation. Connections between the sectors leading to this counterintuitive result need consideration in policy and technology planning.

Future In-Space Operations (FISO): A Working Group and Community Engagement

NASA Technical Reports Server (NTRS)

Thronson, Harley; Lester, Dan

2013-01-01

Long-duration human capabilities beyond low Earth orbit (LEO), either in support of or as an alternative to lunar surface operations, have been assessed at least since the late 1960s. Over the next few months, we will present short histories of concepts for long-duration, free-space human habitation beyond LEO from the end of the Apollo program to the Decadal Planning Team (DPT)/NASA Exploration Team (NExT), which was active in 1999 2000 (see Forging a vision: NASA s Decadal Planning Team and the origins of the Vision for Space Exploration , The Space Review, December 19, 2005). Here we summarize the brief existence of the Future In-Space Operations (FISO) working group in 2005 2006 and its successor, a telecon-based colloquium series, which we co-moderate.

Facile formation of 2D Co2P@Co3O4 microsheets through in-situ toptactic conversion and surface corrosion: Bifunctional electrocatalysts towards overall water splitting

NASA Astrophysics Data System (ADS)

Yao, Lihua; Zhang, Nan; Wang, Yin; Ni, Yuanman; Yan, Dongpeng; Hu, Changwen

2018-01-01

Exploring efficient non-precious electrocatalysts for both the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is crucial for many renewable energy conversion processes. In this work, we report that 2D Co2P@Co3O4 microsheets can be prepared through an in-situ toptactic conversion from single-crystal β-Co(OH)2 microplatelets, associated with a surface phosphatization and corrosion process. The resultant Co2P@Co3O4 2D hybrid materials can further serve as self-supported bifunctional catalytic electrodes to drive the overall water splitting for HER and OER simultaneously, with low overpotentials and high long-term stability. Furthermore, a water electrolyzer based on Co2P@Co3O4 hybrid as both anode and cathode is fabricated, which achieves 10 mA cm-2 current at only 1.57 V during water splitting process. Therefore, this work provides a facile strategy to obtain 2D Co2P-based micro/nanostructures, which act as low-cost and highly active electrocatalysts towards overall water splitting application.

Modeling syngas-fired gas turbine engines with two dilutants

NASA Astrophysics Data System (ADS)

Hawk, Mitchell E.

2011-12-01

Prior gas turbine engine modeling work at the University of Wyoming studied cycle performance and turbine design with air and CO2-diluted GTE cycles fired with methane and syngas fuels. Two of the cycles examined were unconventional and innovative. The work presented herein reexamines prior results and expands the modeling by including the impacts of turbine cooling and CO2 sequestration on GTE cycle performance. The simple, conventional regeneration and two alternative regeneration cycle configurations were examined. In contrast to air dilution, CO2 -diluted cycle efficiencies increased by approximately 1.0 percentage point for the three regeneration configurations examined, while the efficiency of the CO2-diluted simple cycle decreased by approximately 5.0 percentage points. For CO2-diluted cycles with a closed-exhaust recycling path, an optimum CO2-recycle pressure was determined for each configuration that was significantly lower than atmospheric pressure. Un-cooled alternative regeneration configurations with CO2 recycling achieved efficiencies near 50%, which was approximately 3.0 percentage points higher than the conventional regeneration cycle and simple cycle configurations that utilized CO2 recycling. Accounting for cooling of the first two turbine stages resulted in a 2--3 percentage point reduction in un-cooled efficiency, with air dilution corresponding to the upper extreme. Additionally, when the work required to sequester CO2 was accounted for, cooled cycle efficiency decreased by 4--6 percentage points, and was more negatively impacted when syngas fuels were used. Finally, turbine design models showed that turbine blades are shorter with CO2 dilution, resulting in fewer design restrictions.

Pattern-based information portal for business plan co-creation

NASA Astrophysics Data System (ADS)

Bontchev, Boyan; Ruskov, Petko; Tanev, Stoyan

2011-03-01

Creation of business plans helps entrepreneurs in managing identification of business opportunities and committing necessary resources for process evolution. Applying patterns in business plan creation facilitates the identification of effective solutions that were adopted in the past and may provide a basis for adopting similar solutions in the future within given business context. The article presents the system design of an information portal for business plan co-creation based on patterns. The portal is going to provide start-up and entrepreneurs with ready-to-modify business plan patterns in order to help them in development of effective and efficient business plans. It will facilitate entrepreneurs in co-experimenting and co-learning more frequently and faster. Moreover, the paper focuses on the software architecture of the pattern based portal and explains the functionality of its modules, namely the pattern designer, pattern repository services and agent-based pattern implementers. It explains their role for business process co-creation, storing and managing patterns described formally, and selecting patterns best suited for specific business case. Thus, innovative entrepreneurs will be guided by the portal in co-writing winning business plans and staying competitive in the present day dynamic globalized environment.

Pattern-based information portal for business plan co-creation

NASA Astrophysics Data System (ADS)

Bontchev, Boyan; Ruskov, Petko; Tanev, Stoyan

2010-10-01

Creation of business plans helps entrepreneurs in managing identification of business opportunities and committing necessary resources for process evolution. Applying patterns in business plan creation facilitates the identification of effective solutions that were adopted in the past and may provide a basis for adopting similar solutions in the future within given business context. The article presents the system design of an information portal for business plan co-creation based on patterns. The portal is going to provide start-up and entrepreneurs with ready-to-modify business plan patterns in order to help them in development of effective and efficient business plans. It will facilitate entrepreneurs in co-experimenting and co-learning more frequently and faster. Moreover, the paper focuses on the software architecture of the pattern based portal and explains the functionality of its modules, namely the pattern designer, pattern repository services and agent-based pattern implementers. It explains their role for business process co-creation, storing and managing patterns described formally, and selecting patterns best suited for specific business case. Thus, innovative entrepreneurs will be guided by the portal in co-writing winning business plans and staying competitive in the present day dynamic globalized environment.

The distribution and co-occurrence of physical and psychosocial risk factors for musculoskeletal disorders in a general working population.

PubMed

Kausto, Johanna; Miranda, Helena; Pehkonen, Irmeli; Heliövaara, Markku; Viikari-Juntura, Eira; Solovieva, Svetlana

2011-10-01

There is growing evidence that physical and psychosocial exposures at work increase the risk of musculoskeletal disorders. The aim of this study was to describe the distribution and co-occurrence of these risk factors in the working population. We used data from the Health 2000 survey carried out in Finland in 2000-2001. The sample of our study consisted of 2,491 men and 2,613 women who had been actively working during the year preceding the survey. Logistic regression and exploratory factor analysis were used to analyze the co-occurrence of the work-related risk factors. Exposure to high physical work load and several co-occurring work load factors was more prevalent among men than women. In women, as opposed to men, the highest exposure to most physical work load factors was found in their later work life. Gender and age showed weak associations with psychosocial work load factors. Low socioeconomic position, in both genders, was related to an increased risk of being exposed to several co-occurring physical or psychosocial factors. Physical exposures most frequently co-occurred with high job demands and low job control in men. Among women, physical exposures were found to co-occur with high job demands, low job control and job insecurity. This study provides novel information on the occupational exposures in general working population. It appears that co-occurrence of physical and psychosocial exposures should be considered in research and prevention of musculoskeletal disorders. In addition, a broader set of occupational factors, e.g., work organization, are suggested to be included in future studies to cover all the relevant determinants.

An Integrated Assessment Model for Helping the United States Sea Scallop (Placopecten magellanicus) Fishery Plan Ahead for Ocean Acidification and Warming

PubMed Central

2015-01-01

Ocean acidification, the progressive change in ocean chemistry caused by uptake of atmospheric CO2, is likely to affect some marine resources negatively, including shellfish. The Atlantic sea scallop (Placopecten magellanicus) supports one of the most economically important single-species commercial fisheries in the United States. Careful management appears to be the most powerful short-term factor affecting scallop populations, but in the coming decades scallops will be increasingly influenced by global environmental changes such as ocean warming and ocean acidification. In this paper, we describe an integrated assessment model (IAM) that numerically simulates oceanographic, population dynamic, and socioeconomic relationships for the U.S. commercial sea scallop fishery. Our primary goal is to enrich resource management deliberations by offering both short- and long-term insight into the system and generating detailed policy-relevant information about the relative effects of ocean acidification, temperature rise, fishing pressure, and socioeconomic factors on the fishery using a simplified model system. Starting with relationships and data used now for sea scallop fishery management, the model adds socioeconomic decision making based on static economic theory and includes ocean biogeochemical change resulting from CO2 emissions. The model skillfully reproduces scallop population dynamics, market dynamics, and seawater carbonate chemistry since 2000. It indicates sea scallop harvests could decline substantially by 2050 under RCP 8.5 CO2 emissions and current harvest rules, assuming that ocean acidification affects P. magellanicus by decreasing recruitment and slowing growth, and that ocean warming increases growth. Future work will explore different economic and management scenarios and test how potential impacts of ocean acidification on other scallop biological parameters may influence the social-ecological system. Future empirical work on the effect of ocean acidification on sea scallops is also needed. PMID:25945497

An Integrated Assessment Model for Helping the United States Sea Scallop (Placopecten magellanicus) Fishery Plan Ahead for Ocean Acidification and Warming.

PubMed

Cooley, Sarah R; Rheuban, Jennie E; Hart, Deborah R; Luu, Victoria; Glover, David M; Hare, Jonathan A; Doney, Scott C

2015-01-01

Ocean acidification, the progressive change in ocean chemistry caused by uptake of atmospheric CO2, is likely to affect some marine resources negatively, including shellfish. The Atlantic sea scallop (Placopecten magellanicus) supports one of the most economically important single-species commercial fisheries in the United States. Careful management appears to be the most powerful short-term factor affecting scallop populations, but in the coming decades scallops will be increasingly influenced by global environmental changes such as ocean warming and ocean acidification. In this paper, we describe an integrated assessment model (IAM) that numerically simulates oceanographic, population dynamic, and socioeconomic relationships for the U.S. commercial sea scallop fishery. Our primary goal is to enrich resource management deliberations by offering both short- and long-term insight into the system and generating detailed policy-relevant information about the relative effects of ocean acidification, temperature rise, fishing pressure, and socioeconomic factors on the fishery using a simplified model system. Starting with relationships and data used now for sea scallop fishery management, the model adds socioeconomic decision making based on static economic theory and includes ocean biogeochemical change resulting from CO2 emissions. The model skillfully reproduces scallop population dynamics, market dynamics, and seawater carbonate chemistry since 2000. It indicates sea scallop harvests could decline substantially by 2050 under RCP 8.5 CO2 emissions and current harvest rules, assuming that ocean acidification affects P. magellanicus by decreasing recruitment and slowing growth, and that ocean warming increases growth. Future work will explore different economic and management scenarios and test how potential impacts of ocean acidification on other scallop biological parameters may influence the social-ecological system. Future empirical work on the effect of ocean acidification on sea scallops is also needed.

Guidelines and Data to Support Plans for Reallocating Food during Crisis Relocation. Regional Appendix. FEMA Region IV,

DTIC Science & Technology

1982-09-01

STORES INC JACKSON MS 2 0 0 1 1 0 8,000 LEK:IS BEAR CO INC PFI;SAUOLA FL I 1 0 0 0 0 750 LEWIS cPCCER CO INDI , NOLA IS 2 1 1 0 0 0 2,2-ro MALONE AND...SON LEWIS GROCER CO INDI;’ NOLA MS . 0 0 0 0 0 3,000 M-.LONE AND HYDE INC MO.ROE LA I 0 I 0 0 0 1,500 COUNTY TOTAL: 3 0 3 0 0 0 4,500 WINSTON GCAVES CO...SIC’PES INC RALEIGH NC I 0 0 0 1 0 5.000 SMALL SUPPLIERS I I 0 0 0 0 750 CO’NITY TOTAL: 10 I 4 3 0 30,750 PENDER QUIN; WHOLESALE CO INC WARSAW NC 0 1 0 1

Modulated exchange bias in NiFe/CoO/α-Fe2O3 trilayers and NiFe/CoO bilayers

NASA Astrophysics Data System (ADS)

Li, X.; Lin, K.-W.; Yeh, W.-C.; Desautels, R. D.; van Lierop, J.; Pong, Philip W. T.

2017-02-01

While the exchange bias in ferromagnetic/antiferromagnetic (FM/AF) bilayer and FM1/AF/FM2 trilayer configurations has been widely investigated, the role of an AF2 layer in FM/AF1/AF2 trilayer configurations is still not well understood. In this work, the magnetic properties of NiFe/CoO, NiFe/α-Fe2O3 bilayers, and NiFe/CoO/α-Fe2O3 trilayer were studied comparatively. The microstructure and chemical composition were characterized. Temperature dependent magnetometry reveals increased irreversibility temperature in NiFe/CoO/α-Fe2O3 trilayer compared with NiFe/CoO bilayer. The magnetic hysteresis loops show that the exchange bias (Hex) and coercivity (Hc) depend strongly on the anisotropy of AF layer (CoO, α-Fe2O3 and CoO/α-Fe2O3). Our work shows that the AF1/AF2 interfacial interactions can be used effectively for tuning the exchange bias in FM/AF1/AF2 trilayers.

Active CO2 Reservoir Management: A Strategy for Controlling Pressure, CO2 and Brine Migration in Saline-Formation CCS

NASA Astrophysics Data System (ADS)

Buscheck, T. A.; Sun, Y.; Hao, Y.; Court, B.; Celia, M. A.; Wolery, T.; Tompson, A. F.; Aines, R. D.; Friedmann, J.

2010-12-01

CO2 capture and sequestration (CCS) in deep geological formations is regarded as a promising means of lowering the amount of CO2 emitted to the atmosphere and thereby mitigate global warming. The most promising systems for CCS are depleted oil reservoirs, particularly those suited to CO2-based Enhanced Oil Recovery (CCS-EOR), and deep saline formations, both of which are well separated from the atmosphere. For conventional, industrial-scale, saline-formation CCS, pressure buildup can have a limiting effect on CO2 storage capacity. To address this concern, we analyze Active CO2 Reservoir Management (ACRM), which combines brine extraction and residual-brine reinjection with CO2 injection, comparing it with conventional saline-formation CCS. We investigate the influence of brine extraction on pressure response and CO2 and brine migration using the NUFT code. By extracting brine from the lower portion of the storage formation, from locations progressively further from the center of injection, we can counteract buoyancy that drives CO2 to the top of the formation, which is useful in dipping formations. Using “push-pull” manipulation of the CO2 plume, we expose less of the caprock seal to CO2 and more of the storage formation to CO2, with more of the formation utilized for trapping mechanisms. Plume manipulation can also counteract the influence of heterogeneity. We consider the impact of extraction ratio, defined as net extracted brine volume (extraction minus reinjection) divided by injected CO2 volume. Pressure buildup is reduced with increasing extraction ratio, which reduces CO2 and brine migration, increases CO2 storage capacity, and reduces other risks, such as leakage up abandoned wells, caprock fracturing, fault activation, and induced seismicity. For a 100-yr injection period, a 10-yr delay in brine extraction does not diminish the magnitude of pressure reduction. Moreover, it is possible to achieve pressure management with just a few brine-extraction wells, located far from the injection zone. For an extraction ratio of 1, pressure buildup is minimized, greatly reducing the Area of Review, as well as the area required for securing mineral rights. For an extraction ratio of 1, CO2 and brine migration are unaffected by neighboring CO2 operations, which allows planning, assessing, and conducting of each operation to be carried out independently; thus, permits could be granted on a single-site basis. Brine-extraction wells will be useful during monitoring, providing information for system calibration and history matching. One of several key aspects that ACRM has in common with CCS-EOR is the possibility of generating revenue from the extracted fluids; namely, fresh water produced via brine desalination, using technologies such as Reverse Osmosis. These benefits can offset brine extraction and treatment costs, streamline permitting, and help gain public acceptance. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

Committed emissions from existing and planned power plants and asset stranding required to meet the Paris Agreement

NASA Astrophysics Data System (ADS)

Pfeiffer, Alexander; Hepburn, Cameron; Vogt-Schilb, Adrien; Caldecott, Ben

2018-05-01

Over the coming decade, the power sector is expected to invest ~7.2 trillion USD in power plants and grids globally, much of it into CO2-emitting coal and gas plants. These assets typically have long lifetimes and commit large amounts of (future) CO2 emissions. Here, we analyze the historic development of emission commitments from power plants and compare the emissions committed by current and planned plants with remaining carbon budgets. Based on this comparison we derive the likely amount of stranded assets that would be required to meet the 1.5 °C–2 °C global warming goal. We find that even though the growth of emission commitments has slowed down in recent years, currently operating generators still commit us to emissions (~300 GtCO2) above the levels compatible with the average 1.5 °C–2 °C scenario (~240 GtCO2). Furthermore, the current pipeline of power plants would add almost the same amount of additional commitments (~270 GtCO2). Even if the entire pipeline was cancelled, therefore, ~20% of global capacity would need to be stranded to meet the climate goals set out in the Paris Agreement. Our results can help companies and investors re-assess their investments in fossil-fuel power plants, and policymakers strengthen their policies to avoid further carbon lock-in.

76 FR 77392 - Patient Protection and Affordable Care Act; Establishment of Consumer Operated and Oriented Plan...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-12-13

... to protect CO-OP members against insurance industry involvement and interference. To ensure consumer... Protection and Affordable Care Act; Establishment of Consumer Operated and Oriented Plan (CO-OP) Program... the Consumer Operated and Oriented Plan (CO-OP) program, which provides loans to foster the creation...

78 FR 12267 - Approval and Promulgation of Air Quality Implementation Plans; Charlotte, Raleigh/Durham and...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-02-22

... maintenance plan update is for the Charlotte, Raleigh/Durham and Winston-Salem carbon monoxide (CO) maintenance areas. Specifically, the State submitted a limited maintenance plan update for CO, showing continued attainment of the 8-hour CO National Ambient Air Quality Standard for the Charlotte, Raleigh...

A Multi-Institutional Big Data Collaboration to Estimate Long Term Terrestrial Net Carbon Uptake from Remote Sensing and Hydrological Modeling

NASA Astrophysics Data System (ADS)

Halem, M.; Dorband, J.; Rao, R.; Lomonaco, S.; Chapman, D. R.; LeMoigne, J.; Nearing, G. S.; Pelissier, C. S.; Simpson, D. G.; Clune, T.

2014-12-01

Recent aircraft measurements from scattered records have shown long-term, global, seasonal photosynthetic CO2 uptake over land accelerating over the past 50 years. The successful launch of the sun-synchronous Orbiting Carbon Observatory 2 (OCO-2) on July 2, 2014 is expected to provide global, high spatial and spectral resolution datasets of vertical CO2 concentrations with surface spectral resolutions capable of yielding accurate CO2 flux profiles. It is unclear whether the biosphere will continue to act as a sink for anthropogenic CO2 loading of the atmosphere. Since current climate models with detailed terrestrial ecosystems are unable to simulate the observed increase in net ecosystem production (NEP), we will conduct assimilation studies with the derived CO2 fluxes in the GSFC Land Information System hydrological model to validate the generated NEP uptake. Further, we plan to use the OCO-2 CO2 concentrations to train a neural network to enable the calculation of long term trends from a decade of AIRS CO2 concentration data to produce regional NEP. To address this important Big Data science issue, a multi-institutional collaboration was formed to leverage their combined resources and the expertise of the researchers at the NASA GSFC, the Lamont Doherty Earth Observatory and UMBC. We will employ a high speed 10Gb network to connect the collaborating researchers and provide them with remote access to dedicated computational hybrid multicore resources at UMBC, as well as access to an archive containing more than a decade of readily accessible continuous daily gridded AIRS data and ten years of daily MODIS data for each September. The status of the following research efforts is planned to be presented; (i) acquisition and processing of the expected CO2 profile data from OCO-2 for two test sites, a low latitude region over the Amazon and a Boral forest at high latitude, (ii) initial impact of 3-D data assimilation of CO2 fluxes with the advanced Goddard LIS hydrological surface model, (iii) preliminary results in training AIRS CO2 data. In addition, early results of innovative exploration on quantum annealing optimization for 3-D data assimilation, image registration and a Hopfield neural network for training the AIRS CO2 spectral data through UMBC remote access to the D-Wave system in Vancouver, CA, will be introduced.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alptekin, Gokhan

The overall objective of the proposed research is to develop a low cost, high capacity CO{sub 2} sorbent and demonstrate its technical and economic viability for pre-combustion CO{sub 2} capture. The specific objectives supporting our research plan were to optimize the chemical structure and physical properties of the sorbent, scale-up its production using high throughput manufacturing equipment and bulk raw materials and then evaluate its performance, first in bench-scale experiments and then in slipstream tests using actual coal-derived synthesis gas. One of the objectives of the laboratory-scale evaluations was to demonstrate the life and durability of the sorbent for overmore » 10,000 cycles and to assess the impact of contaminants (such as sulfur) on its performance. In the field tests, our objective was to demonstrate the operation of the sorbent using actual coal-derived synthesis gas streams generated by air-blown and oxygen-blown commercial and pilot-scale coal gasifiers (the CO{sub 2} partial pressure in these gas streams is significantly different, which directly impacts the operating conditions hence the performance of the sorbent). To support the field demonstration work, TDA collaborated with Phillips 66 and Southern Company to carry out two separate field tests using actual coal-derived synthesis gas at the Wabash River IGCC Power Plant in Terre Haute, IN and the National Carbon Capture Center (NCCC) in Wilsonville, AL. In collaboration with the University of California, Irvine (UCI), a detailed engineering and economic analysis for the new CO{sub 2} capture system was also proposed to be carried out using Aspen PlusTM simulation software, and estimate its effect on the plant efficiency.« less

Initial assessment of Ni-base alloy performance in 0.1 MPa and supercritical CO 2

DOE PAGES

Pint, B. A.; Keiser, J. R.

2015-09-25

There is considerable interest in increasing the working temperature of both open and closed supercritical CO 2 (sCO 2) cycles to ≥700 °C. At these temperatures, it is unlikely that any Fe-base alloys have suitable strength and therefore the focus is on Ni-base alloys for this application. To begin addressing the lack of compatibility data under these conditions, initial work exposed a wide range of candidate alloys in 500-h exposures at 20 MPa (200 bar) CO 2 at 650 -750 °C in high purity CO 2. In general, the reaction products were thin and protective in these exposures. A smallermore » group of alloy coupons focusing on chromia- and alumina-forming alloys was exposed for 500h in 0.1 MPa (1bar) air, CO 2, CO 2+O 2 and CO 2+H 2O for comparison. Thus, the thin surface oxides formed were very similar to those formed at high pressure and no clear detrimental effect of CO 2 oxidation or O 2 or H 2O impurities could be observed in these exposures.« less

40 CFR 62.9110 - Identification of sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

... Sulfuric Acid Mist from Existing Sulfuric Acid Plants § 62.9110 Identification of sources. (a) Identification of sources. The plan includes the following sulfuric acid production plants. (1) National Zinc Co. in Bartlesville, Oklahoma. (2) Tulsa Chemical Co. in Tulsa, Oklahoma. [52 FR 3230, Feb. 3, 1987...

40 CFR 62.9110 - Identification of sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

... Sulfuric Acid Mist from Existing Sulfuric Acid Plants § 62.9110 Identification of sources. (a) Identification of sources. The plan includes the following sulfuric acid production plants. (1) National Zinc Co. in Bartlesville, Oklahoma. (2) Tulsa Chemical Co. in Tulsa, Oklahoma. [52 FR 3230, Feb. 3, 1987...

40 CFR 62.9110 - Identification of sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

... Sulfuric Acid Mist from Existing Sulfuric Acid Plants § 62.9110 Identification of sources. (a) Identification of sources. The plan includes the following sulfuric acid production plants. (1) National Zinc Co. in Bartlesville, Oklahoma. (2) Tulsa Chemical Co. in Tulsa, Oklahoma. [52 FR 3230, Feb. 3, 1987...

In Search of Joy in Practice: A Report of 23 High-Functioning Primary Care Practices

PubMed Central

Sinsky, Christine A.; Willard-Grace, Rachel; Schutzbank, Andrew M.; Sinsky, Thomas A.; Margolius, David; Bodenheimer, Thomas

2013-01-01

We highlight primary care innovations gathered from high-functioning primary care practices, innovations we believe can facilitate joy in practice and mitigate physician burnout. To do so, we made site visits to 23 high-performing primary care practices and focused on how these practices distribute functions among the team, use technology to their advantage, improve outcomes with data, and make the job of primary care feasible and enjoyable as a life’s vocation. Innovations identified include (1) proactive planned care, with previsit planning and previsit laboratory tests; (2) sharing clinical care among a team, with expanded rooming protocols, standing orders, and panel management; (3) sharing clerical tasks with collaborative documentation (scribing), nonphysician order entry, and streamlined prescription management; (4) improving communication by verbal messaging and in-box management; and (5) improving team functioning through co-location, team meetings, and work flow mapping. Our observations suggest that a shift from a physician-centric model of work distribution and responsibility to a shared-care model, with a higher level of clinical support staff per physician and frequent forums for communication, can result in high-functioning teams, improved professional satisfaction, and greater joy in practice. PMID:23690328

Detecting potential impacts of deep subsurface CO2 injection on shallow drinking water

NASA Astrophysics Data System (ADS)

Smyth, R. C.; Yang, C.; Romanak, K.; Mickler, P. J.; Lu, J.; Hovorka, S. D.

2012-12-01

Presented here are results from one aspect of collective research conducted at Gulf Coast Carbon Center, BEG, Jackson School at UT Austin. The biggest hurdle to public acceptance of CCS is to show that drinking water resources will not be impacted. Since late 1990s our group has been supported by US DOE NETL and private industry to research how best to detect potential impacts to shallow (0 to ~0.25 km) subsurface drinking water from deep (~1 to 3.5 km) injection of CO2. Work has and continues to include (1) field sampling and testing, (2) laboratory batch experiments, (3) geochemical modeling. The objective has been to identify the most sensitive geochemical indicators using data from research-level investigations, which can be economically applied on an industrial-scale. The worst-case scenario would be introduction of CO2 directly into drinking water from a leaking wellbore at a brownfield site. This is unlikely for a properly screened and/or maintained site, but needs to be considered. Our results show aquifer matrix (carbonate vs. clastic) to be critical to interpretation of pH and carbonate (DIC, Alkalinity, and δ13C of DIC) parameters because of the influence of water-rock reaction (buffering vs. non-buffering) on aqueous geochemistry. Field groundwater sampling sites to date are Cranfield, MS and SACROC, TX CO2-EOR oilfields. Two major aquifer types are represented, one dominated by silicate (Cranfield) and the other by carbonate (SACROC) water-rock reactions. We tested sensitivity of geochemical indicators (pH, DIC, Alkalinity, and δ13C of DIC) by modeling the effects of increasing pCO2 on aqueous geochemistry, and laboratory batch experiments, both with partial pressure of CO2 gas (pCO2) at 1x105 Pa (1 atm). Aquifer matrix and groundwater data provided constraints for the geochemical models. We used results from modeling and batch experiments to rank geochemical parameter sensitivity to increased pCO2 into weakly, mildly and strongly sensitive categories for both aquifer systems. DIC concentration is strongly sensitive to increased pCO2 for both aquifers; however, CO2 outgassing during sampling complicates direct field measurement of DIC. Interpretation of data from in-situ push-pull aquifer tests is ongoing and will be used to augment results summarized here. We are currently designing groundwater monitoring plans for two additional industrial-scale sites where we will further test the sensitivity and utility of our sampling approach.

WAG 2 remedial investigation and site investigation site-specific work plan/health and safety checklist for the soil and sediment task. Environmental Restoration Program

DOE Office of Scientific and Technical Information (OSTI.GOV)

Holt, V.L.; Burgoa, B.B.

1993-12-01

This document is a site-specific work plan/health and safety checklist (WP/HSC) for a task of the Waste Area Grouping 2 Remedial Investigation and Site Investigation (WAG 2 RI&SI). Title 29 CFR Part 1910.120 requires that a health and safety program plan that includes site- and task-specific information be completed to ensure conformance with health- and safety-related requirements. To meet this requirement, the health and safety program plan for each WAG 2 RI&SI field task must include (1) the general health and safety program plan for all WAG 2 RI&SI field activities and (2) a WP/HSC for that particular field task.more » These two components, along with all applicable referenced procedures, must be kept together at the work site and distributed to field personnel as required. The general health and safety program plan is the Health and Safety Plan for the Remedial Investigation and Site Investigation of Waste Area Grouping 2 at the Oak Ridge National Laboratory, Oak Ridge, Tennessee (ORNL/ER-169). The WP/HSCs are being issued as supplements to ORNL/ER-169.« less

Space Launch System Co-Manifested Payload Options for Habitation

NASA Technical Reports Server (NTRS)

Smitherman, David

2015-01-01

The Space Launch System (SLS) has a co-manifested payload capability that will grow over time as the rocket matures and planned upgrades are implemented. The final configuration is planned to be capable of inserting a payload greater than 10 metric tons (mt) into a trans-lunar injection trajectory along with the crew in the Orion capsule and the service module. The co-manifested payload is located below the Orion and its service module in a 10-meter high fairing similar to the way the Saturn launch vehicle carried the lunar lander below the Apollo command and service modules. A variety of approaches have been explored that utilizes this co-manifested payload capability to build up infrastructure in deep space in support of future asteroid, lunar, and Mars mission scenarios. This paper is a report on the findings from the Advanced Concepts Office study team at the NASA Marshall Space Flight Center, working with the Advanced Exploration Systems Program on the Exploration Augmentation Module Project. It includes some of the possible options for habitation in the co-manifested payload volume on SLS. Findings include module designs that can be developed in 10mt increments to support these missions, including overall conceptual layouts, mass properties, and approaches for integration into various scenarios for near-term support of deep space habitat research and technology development, support to asteroid exploration, and long range support for Mars transfer flights.

From crisis to development--analysis of air traffic control work processes.

PubMed

Teperi, Anna-Maria; Leppänen, Anneli

2011-03-01

In this study an intervention to improve work processes in air traffic control (ATC) is evaluated. The background was the Finnish air traffic controllers' strike of 1999. The old ways of thinking and acting did not support development of ATC prompting a need for a new kind of working culture in the organisation. Several actions were started. In one of these, ATC work processes were modelled by personnel and development plans concerning work were delivered to top management. Different actors (management, trade union, stakeholders) were interviewed before (n=16) and after the project (n=7). The intervention supported systematic co-operation between different actors in the organisation. However, a follow-up revealed that only a few participants had adopted the idea of continuous work development. Mastery of human factors is crucial in a high reliability work environment such as ATC. But how is the analytical and co-operative aspect kept alive in an organisation that is run by strict international regulation and has a strong technical competence, but is not that strong in collaborative and human aspects? Copyright © 2010 Elsevier Ltd and The Ergonomics Society. All rights reserved.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Park, J; Kim, J; Park, S

Purpose: To investigate exposure outside the treatment field when treating breast cancer with tri-Co-60 magnetic resonance (MR) image guided radiation therapy (IGRT) system. Methods: A total of 7 patients who treated with accelerated partial breast irradiation (APBI) technique were selected prospectively for this study (prescription dose = 38.5 Gy in 10 fractions). Every patient treated with two plans, one was an initial plan and the other was an adaptive plan generated after finishing 5 fractions (a total of 14 plans). Every plan was calculated with and without magnetic field in the treatment planning system. The EBT3 films were attached onmore » the front and the back of 1 cm bolus, and then it was placed on the patient body vertically to cover patient’s jaw and shoulder. After measurements, the maximum point dose and the mean dose of whole area of EBT3 film were acquired. Results: In the treatment plan with magnetic field, low dose stream outside the patient body was observed, almost reaching the patient’s jaw or shoulder, while it was not observed without magnetic field. The average values of the measured maximum and mean doses at the front of bolus were 30.1 ± 11.1 cGy (7.8% of the daily dose) and 14.7 ± 3.3 cGy (3.8%), respectively. At the back of bolus, those values were 6.0 ± 1.9 cGy (1.6%) and 5.1 ± 1.6 cGy (1.3%), respectively. The largest maximum dose at the front was 54.2 cGy (14.1%) while it was 20.7 cGy (5.4%) at the back. The average decrease of the maximum dose by the bolus was 24.0 ± 11.0 cGy. Conclusion: Due to magnetic field, dose stream outside the patient body can be generated during breast cancer treatment with the tri-Co-60 MR-IGRT system. Since this dose stream irradiated skin outside the treatment field, it should be shielded. This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP) (No. 2015R1C1A1A01054192).« less

Constructing a sustainable power sector in China: current and future emissions of coal-fired power plants from 2010 to 2030

NASA Astrophysics Data System (ADS)

Tong, D.; Zhang, Q.

2017-12-01

As the largest energy infrastructure in China, power sector consumed more coal than any other sector and threatened air quality and greenhouse gas (GHG) abatement target. In this work, we assessed the evolution of coal-fired power plants in China during 2010-2030 and the evolution of associated emissions for the same period by using a unit-based emission projection model which integrated the historical power plants information, turnover of the future power plant fleet, and the evolution of end-of-pipe control technologies. We found that, driven by the stringent environmental legislation, SO2, NOx, and PM2.5 emissions from China's coal-fired power plants decreased by 49%, 45%, and 24% respectively during 2010-2015, comparing to 14% increase of coal consumption and 15% increase in CO2 emissions. We estimated that under current national energy development planning, coal consumption and CO2 emissions from coal-fired power plants will continue to increase until 2030, in which against the China's Intended Nationally Determined Contributions (INDCs) targets. Early retirement of old and low-efficient power plants will cumulatively reduce 2.2 Pg CO2 emissions from the baseline scenario during 2016-2030, but still could not curb CO2 emissions from the peak before 2030. Owing to the implementation of "near zero" emission control policy, we projected that emissions of air pollutants will significantly decrease during the same period under all scenarios, indicating the decoupling trends of air pollutants and CO2 emissions. Although with limited direct emission reduction benefits, increasing operating hours of power plants could avoid 236 GW of new power plants construction, which could indirectly reduce emissions embodied in the construction activity. Our results identified a more sustainable pathway for China's coal-fired power plants, which could reduce air pollutant emissions, improve the energy efficiency, and slow down the construction of new units. However, continuous construction of new coal-fired power plants driven by increased electricity demand would pose a potential threat to climate change mitigation and China's peak carbon pledge, and more aggressive CO2 emission reduction policy should be implemented in the future.

Primary, secondary, and tertiary amines for CO2 capture: designing for mesoporous CO2 adsorbents.

PubMed

Ko, Young Gun; Shin, Seung Su; Choi, Ung Su

2011-09-15

CO(2) emissions, from fossil-fuel-burning power plants, the breathing, etc., influence the global worming on large scale and the man's work efficiency on small scale. The reversible capture of CO(2) is a prominent feature of CO(2) organic-inorganic hybrid adsorbent to sequester CO(2). Herein, (3-aminopropyl) trimethoxysilane (APTMS), [3-(methylamino)propyl] trimethoxysilane (MAPTMS), and [3-(diethylamino) propyl] trimethoxysilane (DEAPTMS) are immobilized on highly ordered mesoporous silicas (SBA-15) to catch CO(2) as primary, secondary, and tertiary aminosilica adsorbents. X-ray photoelectron spectroscopy was used to analyze the immobilized APTMS, MAPTMS, and DEAPTMS on the SBA-15. We report an interesting discovery that the CO(2) adsorption and desorption on the adsorbent depend on the amine type of the aminosilica adsorbent. The adsorbed CO(2) was easily desorbed from the adsorbent with the low energy consumption in the order of tertiary, secondary, and primary amino-adsorbents while the adsorption amount and the bonding-affinity increased in the reverse order. The effectiveness of amino-functionalized (1(o), 2(o), and 3(o) amines) SBA-15s as a CO(2) capturing agent was investigated in terms of adsorption capacity, adsorption-desorption kinetics, and thermodynamics. This work demonstrates apt amine types to catch CO(2) and regenerate the adsorbent, which may open new avenues to designing "CO(2) basket". Copyright © 2011. Published by Elsevier Inc.

Analysis of CO2 convection mechanisms associated to surface heating, by combining remote sensing data and in situ measurements

NASA Astrophysics Data System (ADS)

Tello, Marivi; Curcoll, Roger; Font, Anna; Morgu, Josep Anton; Rod, Xavier

Assessing the mechanisms involved in the variability of carbon fluxes is crucial for the under-standing of the changing earth dynamics. In that sense, the aim of this work is to analyze CO2 convection mechanisms at a regional scale in the boundary layer and the lower troposphere by means of cross correlation of land surface temperature data, radio-soundings, wind speeds and in situ measurements of CO2 atmospheric mixing ratios. Since data is easier to acquire, ground level horizontal CO2 fluxes have been widely studied. In the contrary, vertical ones are still subject to uncertainties, even if they are necessary to understand 3D CO2 variability in the atmosphere. In particular, this paper focuses on the relationship between surface heating, convection and CO2 concentrations at different heights and, more generally, on the energy transfer between the surface and the air. The monitored area corresponds to a region on the North Eastern Iberian Peninsula, mainly devoted to agricultural activities. Different types of land covers are observed. On the one hand, in situ data has been collected by several flights during 2007 along the parallel 42o N following the "Crown" aircraft sampling approach [1] that integrates CO2 data obtained through horizontal transects and vertical profiles. This particular configuration is especially well suited for the evaluation of both horizontal and vertical CO2 fluxes. On the other hand, the radiometric land surface temperatures are obtained from the MODIS instrument onboard the Terra and the Aqua satellites. Besides, a flight campaign with an airborne sensor along the same transect in the parallel 42o N has been proposed in the scope of the MIDAS-6 project recently submitted. This project plans to improve soil moisture and ocean salinity products of the SMOS sensor recently launched and to demonstrate its applications. This will allow the study of moisture patterns in the monitored area at two different scales: that of the data collected by the airborne sensor and the coarser one of the data from spaceborne radiometer. Since soil moisture intervenes in the evaporation rate, it is closely related to the sensible heat flux. Hence, the availability of surface soil moisture data will permit a deeper knowledge of the mechanisms involved in the CO2 vertical gradients in the lower troposphere. [1] Font, A., J. A. Morgué X. Rodé (2008), Atmospheric CO2 in situ measurements: Two ı, examples of Crown Design flights in NE Spain, J. Geophys. Research, 113, D12308.

Applying Unmanned Airborne Sampling Technology to Active Volcanoes: Successes, Challenges, and Plans

NASA Astrophysics Data System (ADS)

Pieri, D. C.; Diaz, J. A.; Buongiorno, M. F.

2016-12-01

Over the last three years, we have conducted in situ sampling of airborne volcanic emissions for the calibration and validation of remote sensing data and derivative ash and gas transport models, as well as for proximal and distal hazard evaluations. We are collaboratively operating currently in three main locales: (a) Costa Rica: Turrialba Volcano; (b) Italy: Vulcano Island and La Sofatara Crater; and (c) the United States: Kilauea Volcano and the Salton Sea Geothermal Zone. During 2014-2016 we systematically deployed fixed wing UAVs and aerostats into the phreato-magmatic plume at Turrialba Volcano in Costa Rica, for time-series 3D SO2 profiles during overpasses of the ASTER radiometer onboard the NASA Terra platform. To date we have completed more than 50 aerostat and/or unmanned fixed and/or rotary wing sampling missions. Preliminary science results have been published by Pieri and Diaz (2015; DyDESS), Diaz et al. (2015; JASMS), and Xi et al. (2016, JVGR). We conducted field measurements of H2S, CO2, and SO2 and other species with INGV quad-copters to lift a UCR Multi-gas sensor into the phreatic gas jet at La Sofatara Crater, Pozzuoli, Italy in October 2014 and at Isole Vulcano in August 2015. At La Solfatara, our results documented 8000ppmv (max) up to 200 ft above the vent, and at Vulcano we noted CO2 concentrations approximately 2x ambient up to 100ft above the main crater. Deployment of the ARC SIERRA-B UAV and Dragon Eye mini-UAVs is now planned for the Salton Sea Geothermal Field in October 2016. We have integrated the UCR 20kg mass-spectrometer into SIERRA-B for flight certification in August 2016. We will also conduct near simultaneous airborne sensor-web observations with Dragon Eye UAVs using targeted electrochemical sensors, including sensors for SO2, H2S, CO2, and NH3, along with simultaneous aerostat (tethered balloon/kite-borne) observations using electrochemical sensors, focused on gas emissions from sub-aerial mud volcano fields. Finally, we will deploy Dragon Eye over Kilauea Volcano in January-February 2017 to measure volcanogenic SO2 emissions, the rate of SO2 to H2SO4 hydrolysis, and the emission of CO2This work was carried out in part at the Jet Propulsion Laboratory of CA Institute of Technology, under contract to the Earth Surface & Interior Focus Area within the NASA Science Mission Directorate.

Imaging Depression in Adults with ASD

DTIC Science & Technology

2017-10-01

collected temporally close enough to imaging data in Phase 2 to be confidently incorporated in the planned statistical analyses, and (b) not unduly risk...Phase 2 to be confidently incorporated in the planned statistical analyses, and (b) not unduly risk attrition between Phase 1 and 2, we chose to hold...supervision is ongoing (since 9/2014). • Co-l Dr. Lerner’s 2nd year Clinical Psychology PhD students have participated in ADOS- 2 Introductory Clinical

SU-F-T-205: Effectiveness of Robust Treatment Planning to Account for Inter- Fractional Variation in Intensity Modulated Proton Therapy for Head Neck Cancer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, X; Zhang, J; Qin, A

2016-06-15

Purpose: To evaluate the potential benefits of robust optimization in intensity modulated proton therapy(IMPT) treatment planning to account for inter-fractional variation for Head Neck Cancer(HNC). Methods: One patient with bilateral HNC previous treated at our institution was used in this study. Ten daily CBCTs were selected. The CT numbers of the CBCTs were corrected by mapping the CT numbers from simulation CT via Deformable Image Registration. The planning target volumes(PTVs) were defined by a 3mm expansion from clinical target volumes(CTVs). The prescription was 70Gy, 54Gy to CTV1, CTV2, and PTV1, PTV2 for robust optimized(RO) and conventionally optimized(CO) plans respectively. Bothmore » techniques were generated by RayStation with the same beam angles: two anterior oblique and two posterior oblique angles. The similar dose constraints were used to achieve 99% of CTV1 received 100% prescription dose while kept the hotspots less than 110% of the prescription. In order to evaluate the dosimetric result through the course of treatment, the contours were deformed from simulation CT to daily CBCTs, modified, and approved by a radiation oncologist. The initial plan on the simulation CT was re-replayed on the daily CBCTs followed the bony alignment. The target coverage was evaluated using the daily doses and the cumulative dose. Results: Eight of 10 daily deliveries with using RO plan achieved at least 95% prescription dose to CTV1 and CTV2, while still kept maximum hotspot less than 112% of prescription compared with only one of 10 for the CO plan to achieve the same standards. For the cumulative doses, the target coverage for both RO and CO plans was quite similar, which was due to the compensation of cold and hot spots. Conclusion: Robust optimization can be effectively applied to compensate for target dose deficit caused by inter-fractional target geometric variation in IMPT treatment planning.« less

Ion-beam mixed ultra-thin cobalt suicide (CoSi2) films by cobalt sputtering and rapid thermal annealing

NASA Astrophysics Data System (ADS)

Kal, S.; Kasko, I.; Ryssel, H.

1995-10-01

The influence of ion-beam mixing on ultra-thin cobalt silicide (CoSi2) formation was investigated by characterizing the ion-beam mixed and unmixed CoSi2 films. A Ge+ ion-implantation through the Co film prior to silicidation causes an interface mixing of the cobalt film with the silicon substrate and results in improved silicide-to-silicon interface roughness. Rapid thermal annealing was used to form Ge+ ion mixed and unmixed thin CoSi2 layer from 10 nm sputter deposited Co film. The silicide films were characterized by secondary neutral mass spectroscopy, x-ray diffraction, tunneling electron microscopy (TEM), Rutherford backscattering, and sheet resistance measurements. The experi-mental results indicate that the final rapid thermal annealing temperature should not exceed 800°C for thin (<50 nm) CoSi2 preparation. A comparison of the plan-view and cross-section TEM micrographs of the ion-beam mixed and unmixed CoSi2 films reveals that Ge+ ion mixing (45 keV, 1 × 1015 cm-2) produces homogeneous silicide with smooth silicide-to-silicon interface.

Planning Without History or Cultural Perspective

DTIC Science & Technology

2015-05-21

8217, News.Bbc.Co.Uk, last modified 2015, accessed January 20, 2015, http://news.bbc.co.uk/2/hi/middle_east/3557446.stm. 119 Nimrod Raphaeli, “Understanding...pubs/monographs/2008/RAND_MG595.3.pdf. Raphaeli, Nimrod . “Understanding Muqtada al-Sadr.” Middle East Quarterly (Fall 2004): 33-42. Rathmell, Andrew

Co-creating possibilities for patients in palliative care to reach vital goals--a multiple case study of home-care nursing encounters.

PubMed

Bergdahl, Elisabeth; Benzein, Eva; Ternestedt, Britt-Marie; Elmberger, Eva; Andershed, Birgitta

2013-12-01

The patient's home is a common setting for palliative care. This means that we need to understand current palliative care philosophy and how its goals can be realized in home-care nursing encounters (HCNEs) between the nurse, patient and patient's relatives. The existing research on this topic describes both a negative and a positive perspective. There has, however, been a reliance on interview and descriptive methods in this context. The aim of this study was to explore planned HCNEs in palliative care. The design was a multiple case study based on observations. The analysis includes a descriptive and an explanation building phase. The results show that planned palliative HCNEs can be described as a process of co-creating possibilities for the patient to reach vital goals through shared knowledge in a warm and caring atmosphere, based on good caring relations. However, in some HCNEs, co-creation did not occur: Wishes and needs were discouraged or made impossible and vital goals were not reached for the patients or their relatives. Further research is needed to understand why. The co-creative process presented in this article can be seen as a concretization of the palliative care ideal of working with a person-centered approach. © 2013 John Wiley & Sons Ltd.

Intimate partner violence, depression, PTSD, and use of mental health resources among ethnically diverse black women.

PubMed

Sabri, Bushra; Bolyard, Richelle; McFadgion, Akosoa L; Stockman, Jamila K; Lucea, Marguerite B; Callwood, Gloria B; Coverston, Catherine R; Campbell, Jacquelyn C

2013-01-01

This study examined exposure to violence and risk for lethality in intimate partner relationships as factors related to co-occurring MH problems and use of mental health (MH) resources among women of African descent. Black women with intimate partner violence (IPV) experiences (n = 431) were recruited from primary care, prenatal or family planning clinics in the United States and the U.S. Virgin Islands. Severity of IPV was significantly associated with co-occurring MH problems, but was not associated with the use of MH resources among African-American women. Risk for lethality and co-occurring problems were also not significantly related to the use of resources. African Caribbean women with severe physical abuse experiences were significantly less likely to use resources. In contrast, severity of physical abuse was positively associated with the use of resources among Black women with mixed ethnicity. Severe IPV experiences are risk factors for co-occurring MH problems, which in turn, increases the need for MH services. However, Black women may not seek help for MH problems. Thus, social work practitioners in health care settings must thoroughly assess women for their IPV experiences and develop tailored treatment plans that address their abuse histories and MH needs.

Thermodynamic analysis of performance improvement by reheat on the CO2 transcritical power cycle

NASA Astrophysics Data System (ADS)

Tuo, Hanfei

2012-06-01

The CO2 transcritical rankine power cycle has been widely investigated recently, because of its better temperature glide matching between sensible heat source and working fluid in vapor generator, and its desirable qualities, such as moderate critical point, little environment impact and low cost. A reheat CO2 transcritical power cycle with two stage expansion is presented to improve baseline cycle performance in this paper. Energy and exergy analysis are carried out to investigate effects of important parameters on cycle performance. The main results show that reheat cycle performance is sensitive to the variation of medium pressures and the optimum medium pressures exist for maximizing work output and thermal efficiency, respectively. Reheat cycle is compared to baseline cycle under the same conditions. More significant improvements by reheat are obtained at lower turbine inlet temperatures and larger high cycle pressure. Work output improvement is much higher than thermal efficiency improvement, because extra waste heat is required to reheat CO2. Based on second law analysis, exergy efficiency of reheat cycle is also higher than that of baseline cycle, because more useful work is converted from waste heat. Reheat with two stage expansion has great potential to improve thermal efficiency and especially net work output of a CO2 transcritical power cycle using a low-grade heat source.

Synthesis of a proline-modified acrylic acid copolymer in supercritical CO2 for glass-ionomer dental cement applications.

PubMed

Moshaverinia, Alireza; Roohpour, Nima; Darr, Jawwad A; Rehman, Ihtesham U

2009-06-01

Supercritical (sc-) fluids (such as sc-CO(2)) represent interesting media for the synthesis of polymers in dental and biomedical applications. Sc-CO(2) has several advantages for polymerization reactions in comparison to conventional organic solvents. It has several advantages in comparison to conventional polymerization solvents, such as enhanced kinetics, being less harmful to the environment and simplified solvent removal process. In our previous work, we synthesized poly(acrylic acid-co-itaconic acid-co-N-vinylpyrrolidone) (PAA-IA-NVP) terpolymers in a supercritical CO(2)/methanol mixture for applications in glass-ionomer dental cements. In this study, proline-containing acrylic acid copolymers were synthesized, in a supercritical CO(2) mixture or in water. Subsequently, the synthesized polymers were used in commercially available glass-ionomer cement formulations (Fuji IX commercial GIC). Mechanical strength (compressive strength (CS), diametral tensile strength (DTS) and biaxial flexural strength (BFS)) and handling properties (working and setting time) of the resulting modified cements were evaluated. It was found that the polymerization reaction in an sc-CO(2)/methanol mixture was significantly faster than the corresponding polymerization reaction in water and the purification procedures were simpler for the former. Furthermore, glass-ionomer cement samples made from the terpolymer prepared in sc-CO(2)/methanol exhibited higher CS and DTS and comparable BFS compared to the same polymer synthesized in water. The working properties of glass-ionomer formulations made in sc-CO(2)/methanol were comparable and better than the values of those for polymers synthesized in water.

Surface chemistry of carbon dioxide revisited

NASA Astrophysics Data System (ADS)

Taifan, William; Boily, Jean-François; Baltrusaitis, Jonas

2016-12-01

This review discusses modern developments in CO2 surface chemistry by focusing on the work published since the original review by H.J. Freund and M.W. Roberts two decades ago (Surface Science Reports 25 (1996) 225-273). It includes relevant fundamentals pertaining to the topics covered in that earlier review, such as conventional metal and metal oxide surfaces and CO2 interactions thereon. While UHV spectroscopy has routinely been applied for CO2 gas-solid interface analysis, the present work goes further by describing surface-CO2 interactions under elevated CO2 pressure on non-oxide surfaces, such as zeolites, sulfides, carbides and nitrides. Furthermore, it describes additional salient in situ techniques relevant to the resolution of the interfacial chemistry of CO2, notably infrared spectroscopy and state-of-the-art theoretical methods, currently used in the resolution of solid and soluble carbonate species in liquid-water vapor, liquid-solid and liquid-liquid interfaces. These techniques are directly relevant to fundamental, natural and technological settings, such as heterogeneous and environmental catalysis and CO2 sequestration.

Advance care planning: the impact of Ceiling of Treatment plans in patients with Coordinate My Care.

PubMed

Broadhurst, Helen Lucy; Droney, Joanne; Callender, Tom; Shaw, Amanda; Riley, Julia

2018-03-22

The aim of this evaluation is to describe the components and results of urgent care planning in Coordinate My Care (CMC), a digital clinical service for patients with life-limiting illness, for use if a patient is unable to make or express choices. Ceiling of treatment (CoT) plans were created detailing where the patient would like to receive their care and how aggressive medical interventions should be. A retrospective service evaluation was completed of all CMC records created between December 2015 and September 2016 (n=6854). CMC records were divided into two cohorts: those with a CoT plan and those without. The factors associated with these cohorts were reviewed including age, diagnosis, resuscitation status and preferences for place of death (PPD). Analysis of the non-mandatory free text section was carried out. Two-thirds of patients had recorded decisions about CoT. Regardless of which CoT option was chosen, for most patients, PPD was home or care home. Patients with a CoT plan were more likely to have a documented resuscitation status.Patients with a CoT were more likely to die in their PPD (82%vs71%, OR 1.79, p<0.0001). A higher proportion of patients with a CoT decision died outside hospital. This analysis demonstrates that a substantial proportion of patients are willing to engage in urgent care planning. Three facets of urgent care planning identified include PPD, CoT and resuscitation status. © Article author(s) (or their employer(s) unless otherwise stated in the text of the article) 2018. All rights reserved. No commercial use is permitted unless otherwise expressly granted.

IPPF Co-operative Information Service (ICIS). November 1977.

ERIC Educational Resources Information Center

International Planned Parenthood Federation, London (England).

This ICIS bulletin replaces the formal Library Bulletin of the International Planned Parenthood Federation (IPPF). It represents the integration of a bibliographic information network. Entries in ICIS are classified according to the following nine categories: (0) General Reference; (1) IPPF; (2) Family Planning and Health Care; (3) Biomedical…

When daily planning improves employee performance: The importance of planning type, engagement, and interruptions.

PubMed

Parke, Michael R; Weinhardt, Justin M; Brodsky, Andrew; Tangirala, Subrahmaniam; DeVoe, Sanford E

2018-03-01

Does planning for a particular workday help employees perform better than on other days they fail to plan? We investigate this question by identifying 2 distinct types of daily work planning to explain why and when planning improves employees' daily performance. The first type is time management planning (TMP)-creating task lists, prioritizing tasks, and determining how and when to perform them. We propose that TMP enhances employees' performance by increasing their work engagement, but that these positive effects are weakened when employees face many interruptions in their day. The second type is contingent planning (CP) in which employees anticipate possible interruptions in their work and plan for them. We propose that CP helps employees stay engaged and perform well despite frequent interruptions. We investigate these hypotheses using a 2-week experience-sampling study. Our findings indicate that TMP's positive effects are conditioned upon the amount of interruptions, but CP has positive effects that are not influenced by the level of interruptions. Through this study, we help inform workers of the different planning methods they can use to increase their daily motivation and performance in dynamic work environments. (PsycINFO Database Record (c) 2018 APA, all rights reserved).

Communication Simulations for Power System Applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fuller, Jason C.; Ciraci, Selim; Daily, Jeffrey A.

2013-05-29

New smart grid technologies and concepts, such as dynamic pricing, demand response, dynamic state estimation, and wide area monitoring, protection, and control, are expected to require considerable communication resources. As the cost of retrofit can be high, future power grids will require the integration of high-speed, secure connections with legacy communication systems, while still providing adequate system control and security. While considerable work has been performed to create co-simulators for the power domain with load models and market operations, limited work has been performed in integrating communications directly into a power domain solver. The simulation of communication and power systemsmore » will become more important as the two systems become more inter-related. This paper will discuss ongoing work at Pacific Northwest National Laboratory to create a flexible, high-speed power and communication system co-simulator for smart grid applications. The framework for the software will be described, including architecture considerations for modular, high performance computing and large-scale scalability (serialization, load balancing, partitioning, cross-platform support, etc.). The current simulator supports the ns-3 (telecommunications) and GridLAB-D (distribution systems) simulators. Ongoing and future work will be described, including planned future expansions for a traditional transmission solver. A test case using the co-simulator, utilizing a transactive demand response system created for the Olympic Peninsula and AEP gridSMART demonstrations, requiring two-way communication between distributed and centralized market devices, will be used to demonstrate the value and intended purpose of the co-simulation environment.« less

Subsurface Monitoring of CO2 Sequestration - A Review and Look Forward

NASA Astrophysics Data System (ADS)

Daley, T. M.

2012-12-01

The injection of CO2 into subsurface formations is at least 50 years old with large-scale utilization of CO2 for enhanced oil recovery (CO2-EOR) beginning in the 1970s. Early monitoring efforts had limited measurements in available boreholes. With growing interest in CO2 sequestration beginning in the 1990's, along with growth in geophysical reservoir monitoring, small to mid-size sequestration monitoring projects began to appear. The overall goals of a subsurface monitoring plan are to provide measurement of CO2 induced changes in subsurface properties at a range of spatial and temporal scales. The range of spatial scales allows tracking of the location and saturation of the plume with varying detail, while finer temporal sampling (up to continuous) allows better understanding of dynamic processes (e.g. multi-phase flow) and constraining of reservoir models. Early monitoring of small scale pilots associated with CO2-EOR (e.g., the McElroy field and the Lost Hills field), developed many of the methodologies including tomographic imaging and multi-physics measurements. Large (reservoir) scale sequestration monitoring began with the Sleipner and Weyburn projects. Typically, large scale monitoring, such as 4D surface seismic, has limited temporal sampling due to costs. Smaller scale pilots can allow more frequent measurements as either individual time-lapse 'snapshots' or as continuous monitoring. Pilot monitoring examples include the Frio, Nagaoka and Otway pilots using repeated well logging, crosswell imaging, vertical seismic profiles and CASSM (continuous active-source seismic monitoring). For saline reservoir sequestration projects, there is typically integration of characterization and monitoring, since the sites are not pre-characterized resource developments (oil or gas), which reinforces the need for multi-scale measurements. As we move beyond pilot sites, we need to quantify CO2 plume and reservoir properties (e.g. pressure) over large scales, while still obtaining high resolution. Typically the high-resolution (spatial and temporal) tools are deployed in permanent or semi-permanent borehole installations, where special well design may be necessary, such as non-conductive casing for electrical surveys. Effective utilization of monitoring wells requires an approach of modular borehole monitoring (MBM) were multiple measurements can be made. An example is recent work at the Citronelle pilot injection site where an MBM package with seismic, fluid sampling and distributed fiber sensing was deployed. For future large scale sequestration monitoring, an adaptive borehole-monitoring program is proposed.

Predation of freshwater fish in environments with elevated carbon dioxide

USGS Publications Warehouse

Midway, Stephen R.; Hasler, Caleb T.; Wagner, Tyler; Suski, Cory D.

2017-01-01

Carbon dioxide (CO2) in fresh-water environments is poorly understood, yet in marine environments CO2 can affect fish behaviour, including predator–prey relationships. To examine changes in predator success in elevated CO2, we experimented with predatory Micropterus salmoides and Pimephales promelas prey. We used a two-factor fully crossed experimental design; one factor was 4-day (acclimation) CO2 concentration and the second factor CO2 concentration during 20-min predation experiments. Both factors had three treatment levels, including ambient partial pressure of CO2(pCO2; 0–1000 μatm), low pCO2 (4000–5000 μatm) and high pCO2 (8000–10 000 μatm). Micropterus salmoides was exposed to both factors, whereas P. promelas was not exposed to the acclimation factor. In total, 83 of the 96 P. promelas were consumed (n = 96 trials) and we saw no discernible effect of CO2 on predator success or time to predation. Failed strikes and time between failed strikes were too infrequent to model. Compared with marine systems, our findings are unique in that we not only saw no changes in prey capture success with increasing CO2, but we also used CO2 treatments that were substantially higher than those in past experiments. Our work demonstrated a pronounced resiliency of freshwater predators to elevated CO2 exposure, and a starting point for future work in this area.

GGOS working group on ground networks and communications

NASA Technical Reports Server (NTRS)

Pearlman, M.; Altamimi, Z.; Beck, N.; Forsberg, R.; Gurtner, W.; Kenyon, S.; Behrend, D.; Lemoine, F. G.; Ma, C.; Noll, C. E.;

An Activist Approach to Sport Meets Youth From Socially Vulnerable Backgrounds: Possible Learning Aspirations.

PubMed

Luguetti, Carla; Oliver, Kimberly L; Dantas, Luiz Eduardo Pinto Basto Tourinho; Kirk, David

2017-03-01

This study was a 2-phase activist research project aimed at co-creating a prototype pedagogical model for working with youth from socially vulnerable backgrounds in a sport context. This article addresses the learning aspirations (learning outcomes) that emerged when we created spaces for youth to develop strategies to manage the risks they face in their community. This study took place in a socially and economically disadvantaged neighborhood in a Brazilian city where we worked with a group of 17 boys aged 13 to 15 years old, 4 coaches, a pedagogic coordinator, and a social worker. During a 6-month period, we collected multiple sources of data including field journal entries/observations (38) and audio records of youth work sessions (18), coaches' work sessions (16), combined coaches and youth work sessions (3), and meetings between the lead and the 2nd author for debriefing and planning sessions (36). By using an activist approach, 4 learning aspirations emerged: becoming responsible/committed, learning from mistakes, valuing each other's knowledge, and communicating with others. Findings suggest there is a need for more sports programs that start from young people's concrete needs and life situations and look to create places for youth to see alternative possibilities and take action.

Toward verifying fossil fuel CO2 emissions with the CMAQ model: motivation, model description and initial simulation.

PubMed

Liu, Zhen; Bambha, Ray P; Pinto, Joseph P; Zeng, Tao; Boylan, Jim; Huang, Maoyi; Lei, Huimin; Zhao, Chun; Liu, Shishi; Mao, Jiafu; Schwalm, Christopher R; Shi, Xiaoying; Wei, Yaxing; Michelsen, Hope A

2014-04-01

Motivated by the question of whether and how a state-of-the-art regional chemical transport model (CTM) can facilitate characterization of CO2 spatiotemporal variability and verify CO2 fossil-fuel emissions, we for the first time applied the Community Multiscale Air Quality (CMAQ) model to simulate CO2. This paper presents methods, input data, and initial results for CO2 simulation using CMAQ over the contiguous United States in October 2007. Modeling experiments have been performed to understand the roles of fossil-fuel emissions, biosphere-atmosphere exchange, and meteorology in regulating the spatial distribution of CO2 near the surface over the contiguous United States. Three sets of net ecosystem exchange (NEE) fluxes were used as input to assess the impact of uncertainty of NEE on CO2 concentrations simulated by CMAQ. Observational data from six tall tower sites across the country were used to evaluate model performance. In particular, at the Boulder Atmospheric Observatory (BAO), a tall tower site that receives urban emissions from Denver CO, the CMAQ model using hourly varying, high-resolution CO2 fossil-fuel emissions from the Vulcan inventory and Carbon Tracker optimized NEE reproduced the observed diurnal profile of CO2 reasonably well but with a low bias in the early morning. The spatial distribution of CO2 was found to correlate with NO(x), SO2, and CO, because of their similar fossil-fuel emission sources and common transport processes. These initial results from CMAQ demonstrate the potential of using a regional CTM to help interpret CO2 observations and understand CO2 variability in space and time. The ability to simulate a full suite of air pollutants in CMAQ will also facilitate investigations of their use as tracers for CO2 source attribution. This work serves as a proof of concept and the foundation for more comprehensive examinations of CO2 spatiotemporal variability and various uncertainties in the future. Atmospheric CO2 has long been modeled and studied on continental to global scales to understand the global carbon cycle. This work demonstrates the potential of modeling and studying CO2 variability at fine spatiotemporal scales with CMAQ, which has been applied extensively, to study traditionally regulated air pollutants. The abundant observational records of these air pollutants and successful experience in studying and reducing their emissions may be useful for verifying CO2 emissions. Although there remains much more to further investigate, this work opens up a discussion on whether and how to study CO2 as an air pollutant.

Strategic and Unpressured Within-Task Planning and Their Associations with Working Memory

ERIC Educational Resources Information Center

Li, Shaofeng; Fu, Mengxia

2018-01-01

This study investigated the comparative effects of strategic and unpressured within-task planning on second language (L2) Chinese oral production and the role of working memory in mediating the effects of the two types of planning. Twenty-nine L2 Chinese learners at a large New Zealand university performed a narrative task after watching a…

Engineering few-layer MoTe2 devices by Co/hBN tunnel contacts

NASA Astrophysics Data System (ADS)

Zhu, Mengjian; Luo, Wei; Wu, Nannan; Zhang, Xue-ao; Qin, Shiqiao

2018-04-01

2H phase Molybdenum ditelluride (MoTe2) is a layered two-dimensional (2D) semiconductor that has recently gained extensive attention for its intriguing properties, demonstrating great potential for nanoelectronics and optoelectronics. Optimizing the electric contacts to MoTe2 is a critical step for realizing high performance devices. Here, we demonstrate Co/hBN tunnel contacts to few-layer MoTe2. In sharp contrast to the p-type conduction of Co contacted MoTe2, Co/hBN tunnel contacted MoTe2 devices show clear n-type transport properties. Our first principles calculation reveals that the inserted few-layer hBN strongly interacts with Co and significantly reduces its work-function by ˜1.2 eV, while MoTe2 itself has a much weaker influence on the work-function of Co. This allows us to build MoTe2 diodes using the mixed Co/hBN and Co contact architecture, which can be switched from p-n type to n-p type by changing the gate-voltage, paving the way for engineering multi-functional devices based on atomically thin 2D semiconductors.

Medical students' research productivity and career preferences; a 2-year prospective follow-up study.

PubMed

Möller, Riitta; Shoshan, Maria

2017-03-03

Linking undergraduate medical education to scientific research is necessary for the quality of future health care, and students´ individual research projects are one way to do so. Assessment of the impact of such projects is of interest for both educational and research-oriented segments of medical schools. Here, we examined the scholarly products and medical students' career preferences 2 years after a mandatory research project course. A prospective cross-sectional questionnaire study. All 581 students registered on a 20-week research project course between September 2010 through September 2012 were e-mailed a questionnaire 2 years after completing the course. In total, 392 students (mean age 27 years; 60% females) responded (67% response rate). 59 students (15%) were co-authors on a scientific paper published in an international journal, 6 students had published in a national journal, and 57 students had co-authored a paper submitted for publication. Totally, 122 scientific papers had been submitted. Moreover, 67 (17%) students had given 107 oral or poster presentations nationally or internationally during the follow-up. Career-wise, 36 students (9%) had been registered as PhD students and an additional 127 students (34%) were planning to register. Those who did not plan doctoral studies were significantly older (p = 0.013) than those who did. However, 35% reported that they would in the coming 5 years prefer to work as clinicians only, and this group was significantly younger than those who envisaged participation in research. There were no significant gender differences. Approximately a third of the students had authored papers and/or public presentations, and a similar fraction had career plans involving a PhD degree. The results indicate that the project course had a positive impact on continued supervisor-student collaboration on a professional level, but also that strategies to encourage young doctors to perform clinical research may be needed.

Respiratory Emergencies and Management of Mining Accidents

PubMed Central

Özmen, İpek; Aksoy, Emine

2015-01-01

The rapid detection of the reasons for mining accidents that lead to emergency situations is vital for search and rescue work. The control of fire and gas leakage provides an immediate approach for rescue works for deaths or injuries and the detection of who needs resuscitation outside of the mine. The evacuation and recovery operations should be directed by continuous monitoring of the mine environment due to fire and explosion risks. The main toxic gases in mines are carbon monoxide (CO) and carbon dioxide (CO2); the flammable gases are methane (CH4), CO, and hydrogen (H2); the suffocating gases are CO2, nitrogen (N20), and CH4; and the toxic gases are CO, nitrogen oxides (NOx), and hydrogen sulfide (H2S). PMID:29404110

Ultraviolet-Optical Space Astronomy Beyond HST Conference (Origins Conference and UV-Optical Working Group Support)

NASA Technical Reports Server (NTRS)

Shull, J. Michael; Morse, Jon

2001-01-01

This grant supported three major activities, from 1997-2001. (1) Origins Conference. The funds from this grant were used, initially, to support a Conference on "Origins", held May 19-23, 1997 at Estes Park, CO and attended by a wide range of astronomers, planetary scientists, and astrobiologists. The scientific proceedings of this meeting were published in 1998 by the Astronomical Society of the Pacific: "Origins" (1998) "Proceedings of the International Origins Conference". (2) UV-Optical Space Astronomy. Conference Additional funds provided by the NASA Office of Space Science were used to support a meeting held August 5-7, 1998 at Boulder, CO and attended by ultraviolet and optical astronomers and instrumentalists interested in a UV-O successor to the Hubble Space Telescope. The scientific proceedings of this meeting were published in 1999: "Ultraviolet-Optical Space Astronomy Beyond the Hubble Space Telescope" (1999), NASA provided funds and commissioned the UVOWG (Ultraviolet-Optical Working Group), charged with recommending a set of fundamental scientific problems and new space missions in the UV/Optical wavelength bands. The working group was chaired by J. M. Shull, and included ten other astrophysicists. Their report was published as a "White Paper" (Nov. 1999) entitled "The Emergence of the Modern Universe: Tracing the Cosmic Web" available. The results of this report were used in the NASA Strategic Planning ("Roadmap") exercise and by the NRC Astronomy/Astrophysics Decade Committee.

PLANS & ELEVATIONS. United Engineering Company Ltd., Alameda Shipyard. Also ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

PLANS & ELEVATIONS. United Engineering Company Ltd., Alameda Shipyard. Also includes door schedule and a small scale plot plan. No architect noted. Drawn by W.H.H. Plan no. 2-N-5 (U.E. Co. plan no. 10,523). Scale 1/8 inch to the foot. March 10, 1942, last revised 10/6/43. U.S. Navy, Bureau of Yards & Docks, Contract no. bs 76, item no. 22A. Approved for construction October 9, 1943. blueprint - United Engineering Company Shipyard, Warehouse, 2900 Main Street, Alameda, Alameda County, CA

Educational and intervention strategies for improving a shift system: an experience in a disabled persons' facility.

PubMed

Sakai, K; Watanabe, A; Kogi, K

1993-01-01

The improvement of an irregular three-shift system with anti-clockwise rotation of workers of a disabled persons' facility covering 42 h a week was a subject for management-labour debate. Workers were complaining of physical fatigue, high prevalence of low back pain, sleep shortages associated with short inter-shift intervals, and irregular holidays. With the co-operation of trade union members, an educational and intervention programme was designed to analyse, plan, and implement improved shift rotation schemes. The programme consisted of (a) a group study on the existing system and effects on health and working life; (b) joint planning of potential schemes; (c) communication and feedback (d) testing and evaluation; and (e) agreement on an improved system. The group study was undertaken by means of time study, questionnaire and physiological methods, and the results were jointly discussed. This led to the planning of alternative shift schemes incorporating more regular, clockwise rotation. It was agreed to stage a trial period with a view to shorter working hours. This experience indicated the importance of a stepwise intervention strategy with frequent dialogues and a participatory process focusing on the broad range of working life and health issues.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brian McPherson

The Southwest Partnership on Carbon Sequestration completed its Phase I program in December 2005. The main objective of the Southwest Partnership Phase I project was to evaluate and demonstrate the means for achieving an 18% reduction in carbon intensity by 2012. Many other goals were accomplished on the way to this objective, including (1) analysis of CO{sub 2} storage options in the region, including characterization of storage capacities and transportation options, (2) analysis and summary of CO{sub 2} sources, (3) analysis and summary of CO{sub 2} separation and capture technologies employed in the region, (4) evaluation and ranking of themore » most appropriate sequestration technologies for capture and storage of CO{sub 2} in the Southwest Region, (5) dissemination of existing regulatory/permitting requirements, and (6) assessing and initiating public knowledge and acceptance of possible sequestration approaches. Results of the Southwest Partnership's Phase I evaluation suggested that the most convenient and practical ''first opportunities'' for sequestration would lie along existing CO{sub 2} pipelines in the region. Action plans for six Phase II validation tests in the region were developed, with a portfolio that includes four geologic pilot tests distributed among Utah, New Mexico, and Texas. The Partnership will also conduct a regional terrestrial sequestration pilot program focusing on improved terrestrial MMV methods and reporting approaches specific for the Southwest region. The sixth and final validation test consists of a local-scale terrestrial pilot involving restoration of riparian lands for sequestration purposes. The validation test will use desalinated waters produced from one of the geologic pilot tests. The Southwest Regional Partnership comprises a large, diverse group of expert organizations and individuals specializing in carbon sequestration science and engineering, as well as public policy and outreach. These partners include 21 state government agencies and universities, five major electric utility companies, seven oil, gas and coal companies, three federal agencies, the Navajo Nation, several NGOs, and the Western Governors Association. This group is continuing its work in the Phase II Validation Program, slated to conclude in 2009.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hite, Roger

The project site is located in Livingston Parish, Louisiana, approximately 26 miles due east of Baton Rouge. This project proposed to evaluate an early Eocene-aged Wilcox oil reservoir for permanent storage of CO 2. Blackhorse Energy, LLC planned to conduct a parallel CO 2 oil recovery project in the First Wilcox Sand. The primary focus of this project was to examine and prove the suitability of South Louisiana geologic formations for large-scale geologic sequestration of CO 2 in association with enhanced oil recovery applications. This was to be accomplished through the focused demonstration of small-scale, permanent storage of CO 2more » in the First Wilcox Sand. The project was terminated at the request of Blackhorse Energy LLC on October 22, 2014.« less

ARM Airborne Carbon Measurements VI (ACME VI) Science Plan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Biraud, S

2015-12-01

From October 1 through September 30, 2016, the Atmospheric Radiation Measurement (ARM) Aerial Facility will deploy the Cessna 206 aircraft over the Southern Great Plains (SGP) site, collecting observations of trace-gas mixing ratios over the ARM’s SGP facility. The aircraft payload includes two Atmospheric Observing Systems, Inc., analyzers for continuous measurements of CO2 and a 12-flask sampler for analysis of carbon cycle gases (CO2, CO, CH4, N2O, 13CO2, 14CO2, carbonyl sulfide, and trace hydrocarbon species, including ethane). The aircraft payload also includes instrumentation for solar/infrared radiation measurements. This research is supported by the U.S. Department of Energy’s ARM Climate Researchmore » Facility and Terrestrial Ecosystem Science Program and builds upon previous ARM Airborne Carbon Measurements (ARM-ACME) missions. The goal of these measurements is to improve understanding of 1) the carbon exchange at the SGP site, 2) how CO2 and associated water and energy fluxes influence radiative forcing, convective processes and CO2 concentrations over the SGP site, and 3) how greenhouse gases are transported on continental scales.« less

Recommendations and Proposed Strategic Plan: Water Sector Decontamination Priorities

DTIC Science & Technology

2008-10-01

safety and health issues of the utility personnel that may be exposed to treatment processes down stream from the treatment Conducting research on...Government Coordinating Council (GCC). This letter serves as our official transmittal of the Work Group’s final product . As the Co-Chairs...Priorities Page xv LIST OF ACRONYMS ACEIH American Council of Education on Industrial Hygiene AMWA Association of Metropolitan Water Agencies ANSI

Characteristics of greenhouse gas concentrations derived from ground-based FTS spectra at Anmyeondo, South Korea

NASA Astrophysics Data System (ADS)

Oh, Young-Suk; Takele Kenea, S.; Goo, Tae-Young; Chung, Kyu-Sun; Rhee, Jae-Sang; Ou, Mi-Lim; Byun, Young-Hwa; Wennberg, Paul O.; Kiel, Matthäus; DiGangi, Joshua P.; Diskin, Glenn S.; Velazco, Voltaire A.; Griffith, David W. T.

2018-04-01

Since the late 1990s, the meteorological observatory established in Anmyeondo (36.5382° N, 126.3311° E, and 30 m above mean sea level) has been monitoring several greenhouse gases such as CO2, CH4, N2O, CFCs, and SF6 as a part of the Global Atmosphere Watch (GAW) Program. A high resolution ground-based (g-b) Fourier transform spectrometer (FTS) was installed at this observation site in 2013 and has been operated within the frame work of the Total Carbon Column Observing Network (TCCON) since August 2014. The solar spectra recorded by the g-b FTS cover the spectral range 3800 to 16 000 cm-1 at a resolution of 0.02 cm-1. In this work, the GGG2014 version of the TCCON standard retrieval algorithm was used to retrieve total column average CO2 and CH4 dry mole fractions (XCO2, XCH4) and from the FTS spectra. Spectral bands of CO2 (at 6220.0 and 6339.5 cm-1 center wavenumbers, CH4 at 6002 cm-1 wavenumber, and O2 near 7880 cm-1 ) were used to derive the XCO2 and XCH4. In this paper, we provide comparisons of XCO2 and XCH4 between the aircraft observations and g-b FTS over Anmyeondo station. A comparison of 13 coincident observations of XCO2 between g-b FTS and OCO-2 (Orbiting Carbon Observatory) satellite measurements are also presented for the measurement period between February 2014 and November 2017. OCO-2 observations are highly correlated with the g-b FTS measurements (r2 = 0.884) and exhibited a small positive bias (0.189 ppm). Both data set capture seasonal variations of the target species with maximum and minimum values in spring and late summer, respectively. In the future, it is planned to further utilize the FTS measurements for the evaluation of satellite observations such as Greenhouse Gases Observing Satellite (GOSAT, GOSAT-2). This is the first report of the g-b FTS observations of XCO2 species over the Anmyeondo station.

Active CO2 Reservoir Management for Carbon Capture, Utilization, and Sequestration: Impact on Permitting, Monitoring, and Public Acceptance

NASA Astrophysics Data System (ADS)

Buscheck, T. A.; Chen, M.; Sun, Y.; Hao, Y.; Court, B.; Celia, M. A.; Wolery, T.; Aines, R. D.

2011-12-01

CO2 capture and sequestration (CCS) integrated with geothermal energy production in deep geological formations can play an important role in reducing CO2 emissions to the atmosphere and thereby mitigate global climate change. For industrial-scale CO2 injection in saline formations, pressure buildup can limit storage capacity and security. Active CO2 Reservoir Management (ACRM) combines brine production with CO2 injection to relieve pressure buildup, increase injectivity, manipulate CO2 migration, constrain brine leakage, and enable beneficial utilization of produced brine. Therefore, ACRM can be an enabler of carbon capture, utilization, and sequestration (CCUS). Useful products may include freshwater, cooling water, make-up water for pressure support in oil, gas, and geothermal reservoir operations, and geothermal energy production. Implementation barriers to industrial-scale CCS include concerns about (1) CO2 sequestration security and assurance, (2) pore-space competition with neighboring subsurface activities, (3) CO2 capture costs, and (4) water-use demands imposed by CCS operations, which is particularly important where water resources are already scarce. CCUS, enabled by ACRM, has the potential of addressing these barriers. Pressure relief from brine production can substantially reduce the driving force for potential CO2 and brine migration, as well as minimize interference with neighboring subsurface activities. Electricity generated from geothermal energy can offset a portion of the parasitic energy and financial costs of CCS. Produced brine can be used to generate freshwater by desalination technologies, such as RO, provide a source for saltwater cooling systems or be used as make-up water for oil, gas, or geothermal reservoir operations, reducing the consumption of valuable freshwater resources. We examine the impact of brine production on reducing CO2 and brine leakage. A volumetric balance between injected and produced fluids minimizes the spatial extent of the pressure perturbation, substantially reducing both the Area of Review (AoR) and interactions with neighboring subsurface activities. This will reduce pore-space competition between neighboring subsurface activities, allowing for independent planning, assessment, and permitting. Because post-injection pressure buildup is virtually eliminated, this could have a major impact on post-injection monitoring requirements. Reducing the volume of rock over which brine can migrate may significantly affect site characterization requirements, as well as the impact of parametric and conceptual model uncertainties, such as those related to abandoned wells. ACRM-CCUS has the potential of playing a beneficial role in site-characterization, permitting, and monitoring activities, and in gaining public acceptance. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

The Effect of Ambient Carbon Dioxide on Anion-Exchange Membrane Fuel Cells.

PubMed

Ziv, Noga; Mustain, William E; Dekel, Dario R

2018-04-09

Over the past 10 years, there has been a surge of interest in anion-exchange membrane fuel cells (AEMFCs) as a potentially lower cost alternative to proton-exchange membrane fuel cells (PEMFCs). Recent work has shown that AEMFCs achieve nearly identical performance to that of state-of-the-art PEMFCs; however, much of that data has been collected while feeding CO 2 -free air or pure oxygen to the cathode. Usually, removing CO 2 from the oxidant is done to avoid the detrimental effect of CO 2 on AEMFC performance, through carbonation, whereby CO 2 reacts with the OH - anions to form HCO 3 - and CO 3 2- . In spite of the crucial importance of this topic for the future development and commercialization of AEMFCs, unfortunately there have been very few investigations devoted to this phenomenon and its effects. Much of the data available is widely spread out and there currently does not exist a resource that researchers in the field, or those looking to enter the field, can use as a reference text that explains the complex influence of CO 2 and HCO 3 - /CO 3 2- on all aspects of AEMFC performance. The purpose of this Review is to summarize the experimental and theoretical work reported to date on the effect of ambient CO 2 on AEMFCs. This systematic Review aims to create a single comprehensive account of what is known regarding how CO 2 behaves in AEMFCs, to date, as well as identify the most important areas for future work in this field. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Analysis of the U.S. Navy Food Service Recruiting Program. Part 1. Attitudes and Reenlistment Plans of Food Service Enlistees

DTIC Science & Technology

1984-05-01

the Navy? (PLEASE CHECK ALL THAT APPLY TO WHERE YOU WORKED) FAST FOOD FRANCHISE CAFETERIA • BAKERY DELICATESSEN _ARANT NONE COFFEE SHOP 26. Was any...service equipment (item 20), working conditions in the galley and bakery (item 17), the quality of an MS’s co-workers (item 12), the chances for MS’s to... bakery 4.5 14.3 6.0 79.7 18. Food service work is routine and boring 3.7 5.6 16.3 78.1 19. You’d have lots of adventure 5.0 66.9 1.3 31.8 20. Food

A Regional Atmospheric Continuous CO2 Network In The Rocky Mountains (Rocky RACCOON)

NASA Astrophysics Data System (ADS)

Stephens, B.; de Wekker, S.; Watt, A.; Schimel, D.

2005-12-01

We have established a continuous CO2 observing network in the Rocky Mountains, building on technological and modeling advances made during the Carbon in the Mountains Experiment (CME), to improve our understanding of regional carbon fluxes and to fill key gaps in the North American Carbon Program (NACP). We will present a description of the Rocky RACCOON network and early results from the first three sites. There are strong scientific and societal motivations for determining CO2 exchanges on regional scales. NACP aims to address these concerns through a dramatic expansion in observations and modeling capabilities over North America. Mountain forests in particular represent a significant potential net CO2 sink in the U.S. and are highly sensitive to land-use practices and climate change. However, plans for new continuous CO2 observing sites have omitted the mountain west. This resulted from expensive instrumentation in the face of limited resources, and a perception that current atmospheric transport models are not sophisticated enough to interpret CO2 measurements made in complex terrain. Through our efforts in CME, we have a new autonomous, inexpensive, and robust CO2 analysis system and are developing mountain CO2 modeling tools that will help us to overcome these obstacles. Preliminary observational and modeling results give us confidence that continuous CO2 observations from mountain top observatories will provide useful constraints on regional carbon cycling and will be valuable in the continental inverse modeling efforts planned for NACP. We began at three Colorado sites in August 2005 and hope to add three to six sites in other western states in subsequent years, utilizing existing observatories to the maximum extent possible. The first three sites are at Niwot Ridge, allowing us to have an ongoing intercomparison with flask measurements made by NOAA CMDL; at Storm Peak Laboratory near Steamboat Springs, allowing us to investigate comparisons between these two relatively nearby sites; and at Fraser Experimental Forest, allowing us to investigate nocturnal respiration rates across a large intermountain valley. Our data are available to the public on the internet in near real time to support quality control, local science, and larger scale synthesis efforts.

Perpendicular magnetic anisotropy in Mn2CoAl thin film

NASA Astrophysics Data System (ADS)

Sun, N. Y.; Zhang, Y. Q.; Fu, H. R.; Che, W. R.; You, C. Y.; Shan, R.

2016-01-01

Heusler compound Mn2CoAl (MCA) is attracting more attentions due to many novel properties, such as high resistance, semiconducting behavior and suggestion as a spin-gapless material with a low magnetic moment. In this work, Mn2CoAl epitaxial thin film was prepared on MgO(100) substrate by magnetron sputtering. The transport property of the film exhibits a semiconducting-like behavior. Moreover, our research reveals that perpendicular magnetic anisotropy (PMA) can be induced in very thin Mn2CoAl films resulting from Mn-O and Co-O bonding at Mn2CoAl/MgO interface, which coincides with a recent theoretical prediction. PMA and low saturation magnetic moment could lead to large spin-transfer torque with low current density in principle, and thus our work may bring some unanticipated Heusler compounds into spintronics topics such as the domain wall motion and the current-induced magnetization reversal.

Design Construction and Operation of a Supercritical Carbon Dioxide (sCO 2) Loop for Investigation of Dry Cooling and Natural Circulation Potential for Use in Advanced Small Modular Reactors Utilizing sCO 2 Power Conversion Cycles.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Middleton, Bobby D.; Rodriguez, Salvador B.; Carlson, Matthew David

This report outlines the work completed for a Laboratory Directed Research and Development project at Sandia National Laboratories from October 2012 through September 2015. An experimental supercritical carbon dioxide (sCO 2 ) loop was designed, built, and o perated. The experimental work demonstrated that sCO 2 can be uti lized as the working fluid in an air - cooled, natural circulation configuration to transfer heat from a source to the ultimate heat sink, which is the surrounding ambient environment in most ca ses. The loop was also operated in an induction - heated, water - cooled configuration that allows formore » measurements of physical parameters that are difficult to isolate in the air - cooled configuration. Analysis included the development of two computational flu id dynamics models. Future work is anticipated to answer questions that were not covered in this project.« less

Space Launch System Trans Lunar Payload Delivery Capability

NASA Technical Reports Server (NTRS)

Jackman, A. L.; Smith, D. A.

2016-01-01

NASA Marshall Space Flight Center (MSFC) has successfully completed the Critical Design Review (CDR) of the heavy lift Space Launch System (SLS) and is working towards first flight of the vehicle in 2018. SLS will begin flying crewed missions with an Orion to a lunar vicinity every year after the first 2 flights starting in the early 2020's. So as early as 2021 these Orion flights will deliver ancillary payload, termed "Co-Manifested Payload", with a mass of at least 5.5 metric tons and volume up to 280 cubic meters to a cis-lunar destination. Later SLS flights have a goal of delivering as much as 10 metric tons to a cis-lunar destination. This presentation will describe the ground and flight accommodations, interfaces, and resources planned to be made available to Co-Manifested Payload providers as part of the SLS system. An additional intention is to promote a two-way dialogue between vehicle developers and potential payload users in order to most efficiently evolve required SLS capabilities to meet diverse payload requirements.

Mars Atmospheric In Situ Resource Utilization Projects at the Kennedy Space Center

NASA Technical Reports Server (NTRS)

Muscatello, A. C.; Hintze, P. E.; Caraccio, A. J.; Bayliss, J. A.; Karr, L. J.; Paley, M. S.; Marone, M. J.; Gibson, T. L.; Surma, J. M.; Mansell, J. M.;

Mars Atmospheric In Situ Resource Utilization Projects at the Kennedy Space Center

NASA Technical Reports Server (NTRS)

Muscatello, Anthony; Hintze, Paul; Meier, Anne; Bayliss, Jon; Karr, Laurel; Paley, Steve; Marone, Matt; Gibson, Tracy; Surma, Jan; Mansell, Matt;

Numerical modeling of time-lapse monitoring of CO2 sequestration in a layered basalt reservoir

USGS Publications Warehouse

Khatiwada, M.; Van Wijk, K.; Clement, W.P.; Haney, M.

2008-01-01

As part of preparations in plans by The Big Sky Carbon Sequestration Partnership (BSCSP) to inject CO2 in layered basalt, we numerically investigate seismic methods as a noninvasive monitoring technique. Basalt seems to have geochemical advantages as a reservoir for CO2 storage (CO2 mineralizes quite rapidly while exposed to basalt), but poses a considerable challenge in term of seismic monitoring: strong scattering from the layering of the basalt complicates surface seismic imaging. We perform numerical tests using the Spectral Element Method (SEM) to identify possibilities and limitations of seismic monitoring of CO2 sequestration in a basalt reservoir. While surface seismic is unlikely to detect small physical changes in the reservoir due to the injection of CO2, the results from Vertical Seismic Profiling (VSP) simulations are encouraging. As a perturbation, we make a 5%; change in wave velocity, which produces significant changes in VSP images of pre-injection and post-injection conditions. Finally, we perform an analysis using Coda Wave Interferometry (CWI), to quantify these changes in the reservoir properties due to CO2 injection.

45 CFR 287.70 - What are the plan requirements for the NEW Program?

Code of Federal Regulations, 2010 CFR

2010-10-01

... Tribe will deliver work activities and services. (d) The format is left to the discretion of each NEW... 45 Public Welfare 2 2010-10-01 2010-10-01 false What are the plan requirements for the NEW Program... SERVICES THE NATIVE EMPLOYMENT WORKS (NEW) PROGRAM Plan Requirements § 287.70 What are the plan...

45 CFR 287.70 - What are the plan requirements for the NEW Program?

Code of Federal Regulations, 2011 CFR

2011-10-01

... Tribe will deliver work activities and services. (d) The format is left to the discretion of each NEW... 45 Public Welfare 2 2011-10-01 2011-10-01 false What are the plan requirements for the NEW Program... SERVICES THE NATIVE EMPLOYMENT WORKS (NEW) PROGRAM Plan Requirements § 287.70 What are the plan...

Effect of Long Selenization Time on Co Films under a Low Temperature of 300 °C to Synthesize a Nanostructure CoSe2 and Optical Properties

NASA Astrophysics Data System (ADS)

Wu, Po-Feng; Shi, Jen-Bin; Cheng, Bo-Ci; Wu, Cheng-Han; Lee, Hsuan-Wei; Lin, Hsien-Sheng; Cheng, Fu-Chou; Chen, Kuan-Ping

2018-05-01

This work investigates a simple and non-toxic method to transform pre-deposited amorphous Co film into CoSe2 films at a fixed, low temperature of 300 °C. Single CoSe2-phase films having good crystallinity were obtained at a selenisation time ≧ 24 hours. A nanostructure CoSe2 having two different nano-morphological layers was observed. The CoSe2 films (72 hours) observed a large absorption and a direct band gap.

Geochemical modelling of worst-case leakage scenarios at potential CO2-storage sites - CO2 and saline water contamination of drinking water aquifers

NASA Astrophysics Data System (ADS)

Szabó, Zsuzsanna; Edit Gál, Nóra; Kun, Éva; Szőcs, Teodóra; Falus, György

2017-04-01

Carbon Capture and Storage is a transitional technology to reduce greenhouse gas emissions and to mitigate climate change. Following the implementation and enforcement of the 2009/31/EC Directive in the Hungarian legislation, the Geological and Geophysical Institute of Hungary is required to evaluate the potential CO2 geological storage structures of the country. Basic assessment of these saline water formations has been already performed and the present goal is to extend the studies to the whole of the storage complex and consider the protection of fresh water aquifers of the neighbouring area even in unlikely scenarios when CO2 injection has a much more regional effect than planned. In this work, worst-case scenarios are modelled to understand the effects of CO2 or saline water leaks into drinking water aquifers. The dissolution of CO2 may significantly change the pH of fresh water which induces mineral dissolution and precipitation in the aquifer and therefore, changes in solution composition and even rock porosity. Mobilization of heavy metals may also be of concern. Brine migration from CO2 reservoir and replacement of fresh water in the shallower aquifer may happen due to pressure increase as a consequence of CO2 injection. The saline water causes changes in solution composition which may also induce mineral reactions. The modelling of the above scenarios has happened at several methodological levels such as equilibrium batch, kinetic batch and kinetic reactive transport simulations. All of these have been performed by PHREEQC using the PHREEQC.DAT thermodynamic database. Kinetic models use equations and kinetic rate parameters from the USGS report of Palandri and Kharaka (2004). Reactive transport modelling also considers estimated fluid flow and dispersivity of the studied formation. Further input parameters are the rock and the original ground water compositions of the aquifers and a range of gas-phase CO2 or brine replacement ratios. Worst-case scenarios at seven potential CO2-storage areas have been modelled. The visualization of results has been automatized by R programming. The three types of models (equilibrium, kinetic batch and reactive transport) provide different type but overlapping information. All modelling output of both scenarios (CO2/brine) indicate the increase of ion-concentrations in the fresh water, which might exceed drinking water limit values. Transport models provide a possibility to identify the most suitable chemical parameter in the fresh water for leakage monitoring. This indicator parameter may show detectable and early changes even far away from the contamination source. In the CO2 models potassium concentration increase is significant and runs ahead of the other parameters. In the rock, the models indicate feldspar, montmorillonite, dolomite and illite dissolution whereas calcite, chlorite, kaolinite and silica precipitates, and in the case of CO2-inflow models, dawsonite traps a part of the leaking gas.

Be Bold : An Alternative Plan for Fusion Research

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wurden, Glen Anthony

Government sponsored magnetic fusion energy research in the USA has been on downward trajectory since the early 1990’s. The present path is unsustainable. Indeed, our research community and national research facilities are withering from old-age and lack of investment. The present product (tokamak-centric production of electricity) does not yet work, will not be economic, and is clearly not valued or needed by our society. Even if a prototype existed at any cost, DT-based fusion energy would come too late to significantly impact the reduction of CO 2 emissions in this century. This white paper outlines what “being bold” could meanmore » with respect to the invention and application of nuclear fusion technologies, and how the USA could once again set a visionary example for the world. I present the discussion in two parts, reflecting on the NAS panel two-part assignment of a plan “with” and “without” ITER.« less

Atmospheric Processing Module for Mars Propellant Production

NASA Technical Reports Server (NTRS)

Muscatello, Anthony C.

2014-01-01

The multi-NASA center Mars Atmosphere and Regolith COllectorPrOcessor for Lander Operations (MARCO POLO) project was established to build and demonstrate a methaneoxygen propellant production system in a Mars analog environment. Work at the Kennedy Space Center (KSC) Applied Chemistry Laboratory is focused on the Atmospheric Processing Module (APM). The purpose of the APM is to freeze carbon dioxide from a simulated Martian atmosphere containing the minor components nitrogen, argon, carbon monoxide, and water vapor at Martian pressures (8 torr) by using dual cryocoolers with alternating cycles of freezing and sublimation. The resulting pressurized CO(sub 2) is fed to a methanation subsystem where it is catalytically combined with hydrogen in a Sabatier reactor supplied by the Johnson Space Center (JSC) to make methane and water vapor. We first used a simplified once-through setup and later employed a H(sub 2)CO(sub 2) recycling system to improve process efficiency. This presentation and paper will cover (1) the design and selection of major hardware items, such as the cryocoolers, pumps, tanks, chillers, and membrane separators, (2) the determination of the optimal cold head design and flow rates needed to meet the collection requirement of 88 g CO(sub 2) hr for 14 hr, (3) the testing of the CO(sub 2) freezer subsystem, and (4) the integration and testing of the two subsystems to verify the desired production rate of 31.7 g CH(sub 4) hr and 71.3 g H(sub 2)O hr along with verification of their purity. The resulting 2.22 kg of CH(sub 2)O(sub 2) propellant per 14 hr day (including O(sub 2) from electrolysis of water recovered from regolith, which also supplies the H(sub 2) for methanation) is of the scale needed for a Mars Sample Return mission. In addition, the significance of the project to NASAs new Mars exploration plans will be discussed.

Atmospheric Processing Module for Mars Propellant Production

NASA Technical Reports Server (NTRS)

Muscatello, A.; Devor, R.; Captain, J.

2014-01-01

The multi-NASA center Mars Atmosphere and Regolith COllector/PrOcessor for Lander Operations (MARCO POLO) project was established to build and demonstrate a methaneoxygen propellant production system in a Mars analog environment. Work at the Kennedy Space Center (KSC) Applied Chemistry Laboratory is focused on the Atmospheric Processing Module (APM). The purpose of the APM is to freeze carbon dioxide from a simulated Martian atmosphere containing the minor components nitrogen, argon, carbon monoxide, and water vapor at Martian pressures (approx. 8 torr) by using dual cryocoolers with alternating cycles of freezing and sublimation. The resulting pressurized CO(sub 2) is fed to a methanation subsystem where it is catalytically combined with hydrogen in a Sabatier reactor supplied by the Johnson Space Center (JSC) to make methane and water vapor. We first used a simplified once-through setup and later employed a H(sub 2)CO(sub 2) recycling system to improve process efficiency. This presentation and paper will cover (1) the design and selection of major hardware items, such as the cryocoolers, pumps, tanks, chillers, and membrane separators, (2) the determination of the optimal cold head design and flow rates needed to meet the collection requirement of 88 g CO(sub 2) hr for 14 hr, (3) the testing of the CO(sub 2) freezer subsystem, and (4) the integration and testing of the two subsystems to verify the desired production rate of 31.7 g CH(sub 4) hr and 71.3 g H(sub 2)O hr along with verification of their purity. The resulting 2.22 kg of CH(sub 2)O(sub 2) propellant per 14 hr day (including O(sub 2) from electrolysis of water recovered from regolith, which also supplies the H(sub 2) for methanation) is of the scale needed for a Mars Sample Return mission. In addition, the significance of the project to NASAs new Mars exploration plans will be discussed.

A database and probabilistic assessment methodology for carbon dioxide enhanced oil recovery and associated carbon dioxide retention in the United States

USGS Publications Warehouse

Warwick, Peter D.; Verma, Mahendra K.; Attanasi, Emil; Olea, Ricardo A.; Blondes, Madalyn S.; Freeman, Philip; Brennan, Sean T.; Merrill, Matthew; Jahediesfanjani, Hossein; Roueche, Jacqueline; Lohr, Celeste D.

2017-01-01

The U.S. Geological Survey (USGS) has developed an assessment methodology for estimating the potential incremental technically recoverable oil resources resulting from carbon dioxide-enhanced oil recovery (CO2-EOR) in reservoirs with appropriate depth, pressure, and oil composition. The methodology also includes a procedure for estimating the CO2 that remains in the reservoir after the CO2-EOR process is complete. The methodology relies on a reservoir-level database that incorporates commercially available geologic and engineering data. The mathematical calculations of this assessment methodology were tested and produced realistic results for the Permian Basin Horseshoe Atoll, Upper Pennsylvanian-Wolfcampian Play (Texas, USA). The USGS plans to use the new methodology to conduct an assessment of technically recoverable hydrocarbons and associated CO2 sequestration resulting from CO2-EOR in the United States.

Studies of long-life pulsed CO2 laser with Pt/SnO2 catalyst

NASA Technical Reports Server (NTRS)

Sidney, Barry D.

1987-01-01

Closed-cycle CO2 laser testing with and without a catalyst and with and without CO addition indicate that a catalyst is necessary for long-term operation. Initial results indicate that CO addition with a catalyst may prove optimal, but a precise gas mix has not yet been determined. A long-term run of 10 to the 6th power pulses using 1.3% added CO and a 2% Pt on SnO2 catalyst yields an efficiency of about 95% of open-cycle steady-state power. A simple mathematical analysis yields results which may be sufficient for determining optimum running conditions. Future plans call for testing various catalysts in the laser and longer tests, 10 to the 7th power pulses. A Gas Chromatograph will be installed to measure gas species concentration and the analysis will be slightly modified to include neglected but possibly important parameters.

Numerical Comparison of NASA's Dual Brayton Power Generation System Performance Using CO2 or N2 as the Working Fluid

NASA Technical Reports Server (NTRS)

Ownens, Albert K.; Lavelle, Thomas M.; Hervol, David S.

2010-01-01

A Dual Brayton Power Conversion System (DBPCS) has been tested at the NASA Glenn Research Center using Nitrogen (N2) as the working fluid. This system uses two closed Brayton cycle systems that share a common heat source and working fluid but are otherwise independent. This system has been modeled using the Numerical Propulsion System Simulation (NPSS) environment. This paper presents the results of a numerical study that investigated system performance changes resulting when the working fluid is changed from gaseous (N2) to gaseous carbon dioxide (CO2).

NHS plans to lead on carbon cutting.

PubMed

Pearson, Susan

2008-10-01

While the UK's Climate Change Bill is debated in Parliament, the NHS has been putting in place its plans to lead the way in public sector carbon cutting, which aim for a 60% reduction in CO2 emissions by 2050. Susan Pearson talks to Dr David Pencheon, director of the new NHS Sustainable Development Unit.

TSCA Work Plan: 2012 Scoring of Potential Candidate Chemicals Entering Step 2

EPA Pesticide Factsheets

In 2012, EPA scored these chemicals based on hazard, exposure and persistence/bioaccumulation criteria as part of Step 2 in the Work Plan methodology in order to identify candidate chemicals for near-term review and assessment under TSCA.

Environmental CO2 inhibits Caenorhabditis elegans egg-laying by modulating olfactory neurons and evokes widespread changes in neural activity

PubMed Central

Fenk, Lorenz A.; de Bono, Mario

2015-01-01

Carbon dioxide (CO2) gradients are ubiquitous and provide animals with information about their environment, such as the potential presence of prey or predators. The nematode Caenorhabditis elegans avoids elevated CO2, and previous work identified three neuron pairs called “BAG,” “AFD,” and “ASE” that respond to CO2 stimuli. Using in vivo Ca2+ imaging and behavioral analysis, we show that C. elegans can detect CO2 independently of these sensory pathways. Many of the C. elegans sensory neurons we examined, including the AWC olfactory neurons, the ASJ and ASK gustatory neurons, and the ASH and ADL nociceptors, respond to a rise in CO2 with a rise in Ca2+. In contrast, glial sheath cells harboring the sensory endings of C. elegans’ major chemosensory neurons exhibit strong and sustained decreases in Ca2+ in response to high CO2. Some of these CO2 responses appear to be cell intrinsic. Worms therefore may couple detection of CO2 to that of other cues at the earliest stages of sensory processing. We show that C. elegans persistently suppresses oviposition at high CO2. Hermaphrodite-specific neurons (HSNs), the executive neurons driving egg-laying, are tonically inhibited when CO2 is elevated. CO2 modulates the egg-laying system partly through the AWC olfactory neurons: High CO2 tonically activates AWC by a cGMP-dependent mechanism, and AWC output inhibits the HSNs. Our work shows that CO2 is a more complex sensory cue for C. elegans than previously thought, both in terms of behavior and neural circuitry. PMID:26100886

Psychotherapeutic and work-oriented interventions: employment outcomes among young adults with work disability due to a mental disorder.

PubMed

Mattila-Holappa, Pauliina; Joensuu, Matti; Ahola, Kirsi; Koskinen, Aki; Tuisku, Katinka; Ervasti, Jenni; Virtanen, Marianna

2016-01-01

We examined the extent to which psychotherapeutic and work-oriented interventions were included in a medical treatment and rehabilitation plan and whether they predicted future employment among young adults with work disability due to a mental disorder. Data were obtained from the treatment and rehabilitation plans of 1163 young adults aged 18‒34 years, who in 2008 were granted fixed-term work disability compensation due to a mental disorder and were followed for 5 years. Forty-six percent had no proposal for psychotherapy or a work-oriented intervention in their treatment and rehabilitation plan, 22 % had a plan for only a psychotherapeutic intervention, 23 % had a plan for only a work-oriented intervention, and 10 % had both types of interventions planned. Having a planned psychotherapeutic intervention (HR = 1.35, 95 % CI 1.07-1.69) and of the work-oriented interventions, planned rehabilitative courses and training (HR = 1.34, 95 % CI 1.03-1.70) predicted quicker entry into competitive employment. Having a plan for both a psychotherapeutic and work-oriented intervention was associated with being employed at the end of the follow-up (OR = 1.77, 95 % CI 1.07-2.95). Young adults with a long-term psychiatric work disability episode rarely have a recorded plan for rehabilitation in their treatment and rehabilitation plan although psychotherapeutic interventions and a combination of a psychotherapeutic and work-oriented intervention might help them gain employment.

Developing a monitoring and verification plan with reference to the Australian Otway CO2 pilot project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dodds, K.; Daley, T.; Freifeld, B.

2009-05-01

The Australian Cooperative Research Centre for Greenhouse Gas Technologies (CO2CRC) is currently injecting 100,000 tons of CO{sub 2} in a large-scale test of storage technology in a pilot project in southeastern Australia called the CO2CRC Otway Project. The Otway Basin, with its natural CO{sub 2} accumulations and many depleted gas fields, offers an appropriate site for such a pilot project. An 80% CO{sub 2} stream is produced from a well (Buttress) near the depleted gas reservoir (Naylor) used for storage (Figure 1). The goal of this project is to demonstrate that CO{sub 2} can be safely transported, stored underground, andmore » its behavior tracked and monitored. The monitoring and verification framework has been developed to monitor for the presence and behavior of CO{sub 2} in the subsurface reservoir, near surface, and atmosphere. This monitoring framework addresses areas, identified by a rigorous risk assessment, to verify conformance to clearly identifiable performance criteria. These criteria have been agreed with the regulatory authorities to manage the project through all phases addressing responsibilities, liabilities, and to assure the public of safe storage.« less

Broadcasting satellite feeder links - Characteristics and planning

NASA Technical Reports Server (NTRS)

Kiebler, J. W.

1982-01-01

The paper presents the results of recent studies by the Feeder Link Sub-Working Group of the FCC Advisory Committee for the 1983 Regional Administrative Radio Conference (RARC). These studies conclude that specification of a few key parameters will make feeder link planning relatively straightforward. Feeder links can be located anywhere within a country if satellite orbit locations are separated by 10 deg for adjacent service areas and key parameter values presented in the paper are adopted. Colocated satellites serving a common service area need special attention to attain sufficient isolation between a desired channel and its adjacent cross-polarized channels and alternate co-polarized channels. In addition to presenting planning conclusions by the Advisory Committee, the paper presents and analyzes actions of the International Radio Consultative Committee's Conference Planning Meeting (CPM) concerning feeder links. The CPM reached conclusions similar to, and compatible with, those of the Advisory Committee.

Molecular simulation of separation of CO{sub 2} from flue gases in Cu-BTC metal-organic framework

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Q.Y.; Xue, C.Y.; Zhong, C.L.

2007-11-15

In this work, a computational study was performed on the adsorption separation of CO{sub 2} from flue gases (mixtures of CO{sub 2}/N{sub 2}/O{sub 2}) in Cu-BTC metal-organic framework (MOF) to investigate the applicability of MOFs to this important industrial system. The computational results showed that Cu-BTC is a promising material for separation of CO{sub 2} from flue gases, and the macroscopic separation behaviors of the MOF were elucidated at a molecular level to give insight into the underlying mechanisms. The present work not only provided useful information for understanding the separation characteristics of MOFs, but also showed their potential applicationsmore » in chemical industry.« less

Blood parameters in draught oxen during work: relationship to physical fitness.

PubMed

Zanzinger, J; Becker, K

1992-08-01

1. Four Zebu and four Simmental oxen were submitted to moderate and exhaustive work. Venous blood samples were taken before, immediately after and 30 min after work and assayed for several blood parameters. 2. Draught work led to a decrease in carbon dioxide (pvCO2) and increases in pH, oxygen (pvO2), triglycerides, free fatty acids (FFA) and lactate. 3. Zebu oxen had higher pvCO2 and FFA and lower pH, pvO2 and lactate in response to exercise. 4. Ratios of individual draught power output and values of pvO2 and lactate after work enable the identification of fit and/or weak individuals.

A comparison of Canadian pediatric resident career plans in 1998 and 2006.

PubMed

Shamseer, Larissa; Roth, Daniel E; Tallett, Susan; Hilliard, Robert; Vohra, Sunita

2008-12-01

Studies of pediatric resident career plans and preferences help to forecast changes in the demographic profile and practice patterns of North American pediatricians, providing insights that can guide child health care and medical education policy making. With this study we aimed to compare 4 aspects of Canadian pediatric resident career plans in 1998 and 2006: (1) weekly work hours; (2) scope of practice; (3) professional activities; and (4) community size. Canadian pediatric residents were invited to participate in a national cross-sectional survey to explore career plans and preferences in 1998 (mailing) and 2006 (on-line). Response rates were 69% in 1998 and 52% in 2006. In both survey years, the majority of respondents were female (69% and 73%, respectively). Overall, residents planned to work a similar number of weekly hours in both survey years (47.8 vs 48.8). Women planned to work significantly fewer hours than men; this gap was wider in 2006 than in 1998 (1998: 2.8 fewer hours; 2006: 7.8 fewer hours). After adjusted analysis, the association between proportion of time in primary care and study year became significant; however, time in consultant general or subspecialty pediatrics remained nonsignificantly changed. Residents planned to spend less time in clinical work in 2006 than 1998 (64.4% vs 58.1%), and more planned to work and reside in metropolitan areas (68% vs 78% of decided respondents). Between 1998 and 2006, there was no overall change in the number of hours that Canadian pediatric residents planned to work, but the gender gap widened because of an increase in planned weekly work hours among men. The results also suggest that new strategies may be needed to improve future pediatrician availability in small communities by addressing barriers to nonmetropolitan practice, especially for women.

Heteromorphic NiCo2S4/Ni3S2/Ni Foam as a Self-Standing Electrode for Hydrogen Evolution Reaction in Alkaline Solution.

PubMed

Liu, Hui; Ma, Xiao; Rao, Yuan; Liu, Yang; Liu, Jialiang; Wang, Luyang; Wu, Mingbo

2018-04-04

Considerable works have been devoted on developing high-efficiency nonplatinum electrocatalysts for hydrogen evolution reaction (HER). Herein, 3D heteromorphic NiCo 2 S 4 /Ni 3 S 2 nanosheets network has been constructed on Ni foam (denoted as NiCo 2 S 4 /Ni 3 S 2 /NF) serving as a self-standing electrocatalyst through directly thermal sulfurization of a single-source NiCo-layered double hydroxide precursor. The resultant NiCo 2 S 4 /Ni 3 S 2 /NF electrode exhibits outstanding electrocatalytic HER performance with an extremely low onset overpotential of 15 mV and long-term durability in alkaline solution. Such enhanced HER performance can be credited to (1) the massive exposed active sites provided by mixed transition metal chalcogenides (NiCo 2 S 4 and Ni 3 S 2 ), (2) the strong interfacial interaction at NiCo 2 S 4 /Ni 3 S 2 heterojunction interfaces with the strengthened H binding, and (3) the porous highly conductive Ni foam substrate with accelerated electron transfer. This work opens up a new direction to fabricate effective and non-noble-metal electrodes for water splitting and hydrogen generation.

Drilling and completion of the three CO2SINK boreholes in Europe's pilot CO2 storage and verification project in an onshore saline aquifer

NASA Astrophysics Data System (ADS)

Prevedel, P.,; Wohlgemuth, L.; Legarth, B.; Henninges, J.; Schütt, H.; Schmidt-Hattenberger, C.; Norden, B.; Förster, A.; Hurter, S.

2009-04-01

This paper reports the CO2SINK drilling and permanent monitoring completions, as well as the well testing techniques applied in Europe's first scientific carbon dioxide onshore storage test in a saline aquifer near the town of Ketzin, 40 km east of Berlin/Germany. Three boreholes, one injection and two observation wells have been drilled in 2007 to a total depth of about 800 m. The wells were completed as "smart" wells containing a variety of permanently installed down-hole sensors, which have successfully proven their functionality during over their first injection year and are the key instruments for the continuous monitoring of the CO2 inside the reservoir during the storage phase. Constructing three wells in close proximity of 50 to 100m distance to each other with a dense sensor and monitoring cable population requires detailed planning and employment of high-end project management tools. All wells were cased with stainless final casings equipped with pre-perforated sand filters in the pay-zone and wired on the outside with two fibre-optical, one multi-conductor copper, and a PU-heating cable to the surface. The reservoir casing section is externally coated with a fibre-glass-resin wrap for electrical insulation of the 15 geo-electrical toroid antennas in the open hole section. A staged cementation program was selected in combination with the application of a newly developed swellable rubber packer technology and specialized cementation down-hole tools. This technology was given preference over perforation work inside the final casing at the reservoir face, which would have created unmanageable risks of potential damage of the outside casing cables. Prior to the start of the injection phase, an extensive production and injection well test program as well as well-to-well interference tests were performed in order to determine the optimum CO2 injection regime.

Developing Elementary Science PCK for Teacher Education: Lessons Learned from a Second Grade Partnership

NASA Astrophysics Data System (ADS)

Bradbury, Leslie U.; Wilson, Rachel E.; Brookshire, Laura E.

2017-06-01

In this self-study, two science educators partnered with two elementary teachers to plan, implement, and reflect on a unit taught in second grade classrooms that integrated science and language arts. The researchers hoped to increase their pedagogical content knowledge (PCK) for elementary science teaching so that they might use their experiences working in an elementary context to modify their practices in their elementary science method instruction. The research question guiding the study was: What aspects of our PCK for elementary science teaching do we as science educators develop by co-planning, co-teaching, and reflecting with second grade teachers? Data include transcripts of planning meetings, oral reflections about the experience, and videos of the unit being enacted. Findings indicate that managing resources for science teaching, organizing students for science learning, and reflecting on science teaching were themes prevalent in the data. These themes were linked to the model of PCK developed by Park and Oliver (Research in Science Education, 38, 261-284, 2008) and demonstrate that we developed PCK for elementary science teaching in several areas. In our discussion, we include several proposed changes for our elementary science methods course based on the outcomes of the study.

Dissecting the steps of CO2 reduction: 1. The interaction of CO and CO2 with γ-Al2O3: an in situ FTIR study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Szanyi, Janos; Kwak, Ja Hun

2014-08-07

The adsorption of CO2 and CO was investigated on a pure γ-Al2O3 support material that has been used for the preparation of Pd and Ru catalysts for the catalytic reduction of CO2. The adsorption of CO2 resulted in the formation of carbonates, bicarbonates and linearly adsorbed CO2 species. The amount and the nature of the adsorbed species were dependent on the annealing temperature of the alumina support. On γ-Al2O3 annealed at 473 K mostly bicarbonates formed, while no adsorbed CO2 was seen on this highly hydroxylated surface. With increasing calcinations temperature, i.e., increasing extent of dehydroxylation, the amounts of bothmore » surface nitrates and linear adsorbed CO2 increased, but still the most abundant surface species were bicarbonates. Surface carbonates and adsorbed CO2 can readily be removed from the alumina surface, while bicarbonates are stable to elevated temperatures. The interaction of CO with γ-Al2O3 is much weaker than that of CO2. At room temperatures CO adsorbs only on Lewis acid sites, and can be readily removed by evacuation. At 100 K CO can probe different defect sites on the alumina surface (both Lewis acid sites and surface hydroxyls). Under no conditions we have observed the formation of any carbonates or bicarbonates upon the interaction of CO with the pure alumina support. In co-adsorption experiments CO competes for adsorption sites with the linearly adsorbed CO2 on the 773 K-annealed γ-Al2O3 surface; but it does not result in the desorption of CO2, rather in the increase of weakly-held carbonate production. After the removal of adsorbed CO, CO2 moves back to its original adsorption sites, i.e., Lewis acidic Al3+ centers. The exposure of a CO2-saturated γ-Al2O3 to H2O did not affect any of the adsorbed surface species. The findings of this study will be used to rationalize the results of our ongoing in situ and in operando studies on the reduction of CO2 on supported Pd and Ru catalysts. Acknowledgements: We gratefully acknowledge the US Department of Energy Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences for the support of this work. The synthesis and catalyst pre-treatment portion of the work described in this manuscript was supported by a Laboratory Directed Research and Development (LDRD) project at the Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle Memorial Institute. J.H.K. also acknowledges the support of this work by the 2013 Research Fund of UNIST (Ulsan National Institute of Science and Technology, Ulsan, Korea).« less

Carbon in Underland (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum

ScienceCinema

DePaolo, Donald J. (Director, Center for Nanoscale Control of Geologic CO2); NCGC Staff

2017-12-09

'Carbon in Underland' was submitted by the Center for Nanoscale Control of Geologic CO2 (NCGC) to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. This video was selected as one of five winners by a distinguished panel of judges for its 'entertaining animation and engaging explanations of carbon sequestration'. NCGC, an EFRC directed by Donald J. DePaolo at Lawrence Berkeley National Laboratory is a partnership of scientists from seven institutions: LBNL (lead) Massachusetts Institute of Technology, Lawrence Livermore National Laboratory, Oak Ridge National Laboratory, University of California, Davis, Ohio State University, and Washington University in St. Louis. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of the Center for Nanoscale Control of Geologic CO{sub 2} is 'to use new investigative tools, combined with experiments and computer simulations, to build a fundamental understanding of molecular-to-pore-scale processes in fluid-rock systems, and to demonstrate the ability to control critical aspects of flow, transport, and mineralization in porous rock media as applied to geologic sequestration of CO{sub 2}. Research topics are: bio-inspired, CO{sub 2} (store), greenhouse gas, and interfacial characterization.

Progress in Measurement of Carbon Dioxide Using a Broadband Lidar

NASA Technical Reports Server (NTRS)

Heaps, William S.

2010-01-01

In order to better understand the budget of carbon dioxide in the Earth's atmosphere it is necessary to develop a global high precision understanding of the carbon dioxide column. In order to uncover the 'missing sink" that is responsible for the large discrepancies in the budget as we presently understand it calculation has indicated that measurement accuracy on the order of 1 ppm is necessary. Because typical column average CO2 has now reached 380 ppm this represents a precision on the order of .25% for these column measurements. No species has ever been measured from space at such a precision. In recognition of the importance of understanding the CO2 budget in order to evaluate its impact on global warming the National Research Council in its decadal survey report to NASA recommended planning for a laser based total CO2 mapping mission in the near future. The extreme measurement accuracy requirements on this mission places very strong requirements on the laser system used for the measurement. This work presents an overview of the characteristics necessary in a laser system used to make this measurement. Consideration is given to the temperature dependence, pressure broadening, and pressure shift of the CO2 lines themselves and how these impact the laser system characteristics We have been examining the possibility of making precise measurements of atmospheric carbon dioxide using broad band source of radiation. This means that many of the difficulties in wavelength control can be treated in the detector portion of the system rather than the laser source. It also greatly reduces the number of individual lasers required to make a measurement. Simplifications such as these are extremely desirable for systems designed to operate from space.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miller, Jeff

"Carbon in Underland" was submitted by the Center for Nanoscale Controls on Geologic CO2 (NCGC) to the "Life at the Frontiers of Energy Research" video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. This video was selected as one of five winners by a distinguished panel of judges for its "entertaining animation and engaging explanations of carbon sequestration". NCGC, an EFRC directed by Donald J. DePaolo at Lawrence Berkeley National Laboratory is a partnership of scientists from sevenmore » institutions: LBNL (lead) Massachusetts Institute of Technology, Lawrence Livermore National Laboratory, Oak Ridge National Laboratory, University of California, Davis, Ohio State University, and Washington University in St. Louis. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of the Center for Nanoscale Control of Geologic CO2 is 'to use new investigative tools, combined with experiments and computer simulations, to build a fundamental understanding of molecular-to-pore-scale processes in fluid-rock systems, and to demonstrate the ability to control critical aspects of flow, transport, and mineralization in porous rock media as applied to geologic sequestration of CO2. Research topics are: bio-inspired, CO2 (store), greenhouse gas, and interfacial characterization.« less

Effects of urban density on carbon dioxide exchanges: Observations of dense urban, suburban and woodland areas of southern England.

PubMed

Ward, H C; Kotthaus, S; Grimmond, C S B; Bjorkegren, A; Wilkinson, M; Morrison, W T J; Evans, J G; Morison, J I L; Iamarino, M

2015-03-01

Anthropogenic and biogenic controls on the surface-atmosphere exchange of CO2 are explored for three different environments. Similarities are seen between suburban and woodland sites during summer, when photosynthesis and respiration determine the diurnal pattern of the CO2 flux. In winter, emissions from human activities dominate urban and suburban fluxes; building emissions increase during cold weather, while traffic is a major component of CO2 emissions all year round. Observed CO2 fluxes reflect diurnal traffic patterns (busy throughout the day (urban); rush-hour peaks (suburban)) and vary between working days and non-working days, except at the woodland site. Suburban vegetation offsets some anthropogenic emissions, but 24-h CO2 fluxes are usually positive even during summer. Observations are compared to estimated emissions from simple models and inventories. Annual CO2 exchanges are significantly different between sites, demonstrating the impacts of increasing urban density (and decreasing vegetation fraction) on the CO2 flux to the atmosphere. Copyright © 2015 The Authors. Published by Elsevier Ltd.. All rights reserved.

The costs of changing an intended action: movement planning, but not execution, interferes with verbal working memory.

PubMed

Spiegel, M A; Koester, D; Weigelt, M; Schack, T

2012-02-16

How much cognitive effort does it take to change a movement plan? In previous studies, it has been shown that humans plan and represent actions in advance, but it remains unclear whether or not action planning and verbal working memory share cognitive resources. Using a novel experimental paradigm, we combined in two experiments a grasp-to-place task with a verbal working memory task. Participants planned a placing movement toward one of two target positions and subsequently encoded and maintained visually presented letters. Both experiments revealed that re-planning the intended action reduced letter recall performance; execution time, however, was not influenced by action modifications. The results of Experiment 2 suggest that the action's interference with verbal working memory arose during the planning rather than the execution phase of the movement. Together, our results strongly suggest that movement planning and verbal working memory share common cognitive resources. Copyright © 2011 Elsevier Ireland Ltd. All rights reserved.

Site planning and integration fiscal year 1999 multi-year work plan (MYWP) update for WBS 1.8.2.1

DOE Office of Scientific and Technical Information (OSTI.GOV)

SCHULTZ, E.A.

The primary mission of the Site Planning and Integration (SP and I) project is to assist Fluor Daniel Project Direction to ensure that all work performed under the Project Hanford Management Contract (PHMC) is adequately planned, executed, controlled, and that performance is measured and reported in an integrated fashion. Furthermore, SP and I is responsible for the development, implementation, and management of systems and processes that integrate technical, schedule, and cost baselines for PHMC work.

Environmental considerations for 3D seismic in Louisianna wetlands

DOE Office of Scientific and Technical Information (OSTI.GOV)

Browning, G.; Dillane, T.; Baaren, P. van

1996-11-01

Louisiana swamps have been host to seismic crews for many years. Results from recent 3D surveys indicate that well planned and executed seismic operations have a minimal and short term impact in these environmentally sensitive wetlands. Pre-planning identifies challenges that require use of improved technology and work procedures. These include multi-channel radio telemetry recording systems, ramming of dynamite and hydrophones as opposed to drilling, DGPS positioning and coordinated use of Airboats, buggies and helicopters. In addition to minimal environmental impact, increased data quality, reduced cost and shorter project duration have been achieved as a result of these efforts. Unlike 2Dmore » surveys, where profile positioning is flexible, 3D surveys involve high density coverage over many square miles operated by numerous personnel. Survey design includes minimizing repeated traffic and crossing points. Survey operations require environmental participation and commitment from every person involved in the project. This includes a thorough orientation and training program with strong emphasis on environmental sensitivity and awareness. Close co-ordination between regulatory agencies, clients and the contractor is a key factor in all aspects of the survey planning and operation. Benefits from these efforts are significant, measurable and continue to improve.« less

SU-F-T-347: An Absolute Dose-Volume Constraint Based Deterministic Optimization Framework for Multi-Co60 Source Focused Radiotherapy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liang, B; Liu, B; Li, Y

2016-06-15

Purpose: Treatment plan optimization in multi-Co60 source focused radiotherapy with multiple isocenters is challenging, because dose distribution is normalized to maximum dose during optimization and evaluation. The objective functions are traditionally defined based on relative dosimetric distribution. This study presents an alternative absolute dose-volume constraint (ADC) based deterministic optimization framework (ADC-DOF). Methods: The initial isocenters are placed on the eroded target surface. Collimator size is chosen based on the area of 2D contour on corresponding axial slice. The isocenter spacing is determined by adjacent collimator sizes. The weights are optimized by minimizing the deviation from ADCs using the steepest descentmore » technique. An iterative procedure is developed to reduce the number of isocenters, where the isocenter with lowest weight is removed without affecting plan quality. The ADC-DOF is compared with the genetic algorithm (GA) using the same arbitrary shaped target (254cc), with a 15mm margin ring structure representing normal tissues. Results: For ADC-DOF, the ADCs imposed on target and ring are (D100>10Gy, D50,10, 0<12Gy, 15Gy and 20Gy) and (D40<10Gy). The resulting D100, 50, 10, 0 and D40 are (9.9Gy, 12.0Gy, 14.1Gy and 16.2Gy) and (10.2Gy). The objectives of GA are to maximize 50% isodose target coverage (TC) while minimize the dose delivered to the ring structure, which results in 97% TC and 47.2% average dose in ring structure. For ADC-DOF (GA) techniques, 20 out of 38 (10 out of 12) initial isocenters are used in the final plan, and the computation time is 8.7s (412.2s) on an i5 computer. Conclusion: We have developed a new optimization technique using ADC and deterministic optimization. Compared with GA, ADC-DOF uses more isocenters but is faster and more robust, and achieves a better conformity. For future work, we will focus on developing a more effective mechanism for initial isocenter determination.« less

Effects of a holiday week on urban soil CO2 flux: an intensive study in Xiamen, southeastern China

NASA Astrophysics Data System (ADS)

Ye, H.; Wang, K.; Chen, F.

2012-12-01

To study the effects of a holiday period on urban soil CO2 flux, CO2 efflux from grassland soil in a traditional park in the city of Xiamen was measured hourly from 28th Sep to 11th Oct, a period that included China's National Day holiday week in 2009. The results of this study revealed that: a) The urban soil CO2 emissions were higher before and after the holiday week and lower during the National Day holiday reflecting changes in the traffic cycles; b) A diurnal cycle where the soil CO2 flux decreased from early morning to noon was associated with CO2 uptake by vegetation which strongly offset vehicle CO2 emissions. The soil CO2 flux increased from night to early morning, associated with reduced CO2 uptake by vegetation; c) During the National Day holiday week in 2009, lower rates of soil respiration were measured after Mid-Autumn Day than earlier in the week, and this was related to a reduced level of human activities and vehicle traffic, reducing the CO2 concentration in the air. Urban holidays have a clear effect on soil CO2 flux through the interactions between vehicle, visitor and vegetation CO2 emissions which indirectly control the use of carbon by plant roots, the rhizosphere and soil microorganisms. Consequently, appropriate traffic controls and tourism travel plans can have positive effects on the soil carbon store and may improve local air quality.

Work Plan for Comprehensive Groundwater Sampling (Operable Unit 2) April 2012

EPA Pesticide Factsheets

April 27, 2012 cover letter from Kirk Kessler, EPS, to Galo Jackson, EPA Region 4 and two OU2-related work plans for sampling at the LCP Chemicals Superfund Site, GA. Region ID: 04 DocID: 10922560, DocDate: 04-27-2012

A model for the evolution of CO2 on Mars

NASA Technical Reports Server (NTRS)

Haberle, Robert M.; Tyler, D.; Mckay, C. P.; Davis, W. L.

1993-01-01

Our MSATT work has focused on the evolution of CO2 on Mars. We have constructed a model that predicts the evolution of CO2 on Mars from a specified initial amount at the end of the heavy bombardment to the present. The model draws on published estimates of the main process believed to affect the fate of CO2 during this period: chemical weathering, regolith uptake, polar cap formation, and atmospheric escape. Except for escape, the rate at which these processes act is controlled by surface temperatures that we calculate using a modified version of the Gierasch and Toon energy balance model. Various aspects of this work are covered.

Life problems of dc and RF-excited low-power CW CO2 waveguide lasers

NASA Technical Reports Server (NTRS)

Hochuli, U. E.; Haldemann, P. R.

1986-01-01

A number of different, RF-excited 3-W CW CO2 waveguide lasers have been built. Four of these lasers, after continuously working for 15,000-30,000 h, still yield about 70 percent of their original power output. The design variations cover N2and CO-bearing gas mixtures, as well as internal- and external-capacitively coupled excitation electrodes. A similar laser survived 50,000 5-min-ON/5-min-OFF cycles without significant mirror damage. It was not possible to find suitable cold cathodes that allow the building of longitudinally dc-excited CW CO2 waveguide lasers that work for such extended periods of time.

Atmospheric Processing Module for Mars Propellant Production

NASA Technical Reports Server (NTRS)

Muscatello, Anthony; Gibson, Tracy; Captain, James; Athman, Robert; Nugent, Matthew; Parks, Steven; Devor, Robert

2013-01-01

The multi-NASA center Mars Atmosphere and Regolith COllector/PrOcessor for Lander Operations (MARCO POLO) project was established to build and demonstrate a methane/oxygen propellant production system in a Mars analog environment. Work at the Kennedy Space Center (KSC) Applied Chemistry Laboratory is focused on the Atmospheric Processing Module (APM). The purpose of the APM is to freeze carbon dioxide from a simulated Martian atmosphere containing the minor components nitrogen, argon, carbon monoxide, and water vapor at Martian pressures (approx.8 torr) by using dual cryocoolers with alternating cycles of freezing and sublimation. The resulting pressurized CO2 is fed to a methanation subsystem where it is catalytically combined with hydrogen in a Sabatier reactor supplied by the Johnson Space Center (JSC) to make methane and water vapor. We first used a simplified once-through setup and later employed a HiCO2 recycling system to improve process efficiency. This presentation and paper will cover (1) the design and selection of major hardware items, such as the cryocoolers, pumps, tanks, chillers, and membrane separators, (2) the determination of the optimal cold head design and flow rates needed to meet the collection requirement of 88 g CO2/hr for 14 hr, (3) the testing of the CO2 freezer subsystem, and (4) the integration and testing of the two subsystems to verify the desired production rate of 31.7 g CH4/hr and 71.3 g H2O/hr along with verification of their purity. The resulting 2.22 kg of CH4/O2 propellant per 14 hr day (including O2 from electrolysis of water recovered from regolith, which also supplies the H2 for methanation) is of the scale needed for a Mars Sample Return mission. In addition, the significance of the project to NASA's new Mars exploration plans will be discussed.

MarCO Flight Hardware 2

NASA Image and Video Library

2016-01-20

One of the two MarCO (Mars Cube One) CubeSat spacecraft is seen at NASA's Jet Propulsion Laboratory, Pasadena, California. The briefcase-size MarCO twins were designed to ride along with NASA's next Mars lander, InSight. Its planned March 2016 launch was suspended. InSight -- an acronym for Interior Exploration using Seismic Investigations, Geodesy and Heat Transport -- will study the interior of Mars to improve understanding of the processes that formed and shaped rocky planets, including Earth. Note: After thorough examination, NASA managers have decided to suspend the planned March 2016 launch of the Interior Exploration using Seismic Investigations Geodesy and Heat Transport (InSight) mission. The decision follows unsuccessful attempts to repair a leak in a section of the prime instrument in the science payload. http://photojournal.jpl.nasa.gov/catalog/PIA20346

Analysis of the Impacts of the Clean Power Plan

EIA Publications

2015-01-01

This report responds to an August 2014 request to the U.S. Energy Information Administration (EIA) from Representative Lamar Smith, Chairman of the U.S. House of Representatives Committee on Science, Space, and Technology, for an analysis of the Environmental Protection Agency's (EPA) proposed Clean Power Plan under which states would be required to develop plans to reduce carbon dioxide (CO2) emissions rates from existing fossil-fired electricity generating units.

Civil Engineering Work Information Management System (WIMS) Planning Guide,

DTIC Science & Technology

1985-04-01

WORK INFORMATION MANAGEMENT SYSTEM PLANNING GUIDE l-!O L~ JAUG 0)12 13 "’ ’’’ " " 𔄂 5 7 2 2 0 0 9 W WTVF--- DISCLAIMER The views and conclusions...y CHAPTER PAGE I INTRODUCTION What is WIMS? --------------------------------- 1I Why Do We Need A WIMS Planning Guide? ------------ I The Target...Administrator ------------------ 21 6 EQUIPMENT AND SUPPLIES Introduction ------------------------------- 22 Magnetic Media Supplies

Issues in Adaptive Planning

DTIC Science & Technology

1986-06-30

approach to the application of theorem proving to problem solving, Aritificial Intelligence 2 (1Q71), 18Q- 208. 4. Fikes, R., Hart, P. and Nilsson, N...by emphasizing the structure of knowledge. 1.2. Planning Literature The earliest work in planning in Artificial Intelligence grew out of the work on...References 1. Newell, A., Artificial Intelligence and the concept of mind, in Computer models of thought and language, Schank, R. and Colby, K. (editor

A faculty created strategic plan for excellence in nursing education.

PubMed

Evans, Connie Joan; Francis Shackell, Eileen; Jean Kerr-Wilson, Selma; Joan Doyle, Glynda; McCutcheon, Jodie Anita; Budz, Bernice

2014-02-08

Strategic planning for nursing education, when seen through a faculty lens creates a deeper, more meaningful critical analysis of effective program development. New strategies are required for academic institutions to transform their curricula to meet the needs of a dynamic healthcare and changing global environment to provide quality education for students. In this article, an evidence-informed process is presented that was progressively co-created by the faculty and facilitators. Seminal business frameworks, leadership development philosophies, and innovative interventions enabled faculty to become engaged and developed as they created a strategic plan for a future-driven nursing program. Phase One presents the process of developing a strategic plan for excellence in nursing education by leveraging faculty potential and preparing for an upcoming accreditation. In Phase Two, four team members from Phase One continue as part of Phase Two team serving as the collective memory for this initial work. This method of strategic planning encouraged faculty engagement and leadership and laid the groundwork for a positive culture change among nursing faculty.

Combustion of Metals in Reduced-Gravity and Extraterrestrial Environments

NASA Technical Reports Server (NTRS)

Branch, M. C.; Abbud-Madrid, A.; Daily, J. W.

2001-01-01

As a result of the ongoing exploration of Mars and the several unmanned and possibly manned missions planned for the near future, increased attention has been given to the use of the natural resources of the planet for rocket propellant production and energy generation. Since the atmosphere of Mars consists of approximately 95% carbon dioxide (CO2), this gas is the resource of choice to be employed for these purposes. Since many metals burn vigorously with CO2, these may be used as an energy source or as propellants for a research vehicle on the surface of Mars. Shafirovich and Goldshleger conducted experiments with spherical particles up to 2.5 mm in diameter and found that the burning process was controlled by diffusion and that the particles exhibited pulsating combustion due to superheating of the Mg vapor trapped inside a protective oxide shell. They also proposed a reaction mechanism based on the gas-phase reaction, Mg + CO2 yields MgO + CO and the heterogeneous reaction Mg + CO yields MgO + C occurring on the sample surface. In all the above studies with large Mg particles, the burning process is invariably influenced by strong convective currents that accelerate the combustion reaction and shorten the burning times. Although these currents are nearly absent in the burning of small particles, the high emissivity of the flames, rapid reaction, and small length scales make the gathering of any useful information on burning rates and flame structure very difficult. The goal of this investigation is to provide a detailed study of flame structure by taking advantage of large, free-floating spherical metal samples and their corresponding long burning times available in a weightless environment. The use of reduced gravity is essential to eliminate the intrusive buoyant flows that plague high temperature metal reactions, to remove the destructive effect of gravity on the shape of molten metal samples, and to study the combustion behavior of metals in the presence of solid oxides undisturbed by natural convection. This work presents the most complete modeling of metal particle burning to date for Mg with CO2 and O2.

Dual phase high-temperature membranes for CO2 separation - performance assessment in post- and pre-combustion processes.

PubMed

Anantharaman, Rahul; Peters, Thijs; Xing, Wen; Fontaine, Marie-Laure; Bredesen, Rune

2016-10-20

Dual phase membranes are highly CO 2 -selective membranes with an operating temperature above 400 °C. The focus of this work is to quantify the potential of dual phase membranes in pre- and post-combustion CO 2 capture processes. The process evaluations show that the dual phase membranes integrated with an NGCC power plant for CO 2 capture are not competitive with the MEA process for post-combustion capture. However, dual phase membrane concepts outperform the reference Selexol technology for pre-combustion CO 2 capture in an IGCC process. The two processes evaluated in this work, post-combustion NGCC and pre-combustion IGCC, represent extremes in CO 2 partial pressure fed to the separation unit. Based on the evaluations it is expected that dual phase membranes could be competitive for post-combustion capture from a pulverized coal fired power plant (PCC) and pre-combustion capture from an Integrated Reforming Cycle (IRCC).

76 FR 14042 - San Luis Valley National Wildlife Refuge Complex, Alamosa, CO; Comprehensive Conservation Plan...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-15

... the subject line of the message. Fax: Attn: Laurie Shannon, Planning Team Leader, 303/236-4792. U.S. Mail: Laurie Shannon, Planning Team Leader, Division of Refuge Planning, P.O. Box 25486, Denver, CO 80225-0486. In-Person Drop-off: You may drop off comments during regular business hours at the above...

A Comparison of Academic Achievement Between Cooperative Education Students and Non-Cooperative Education Students at College of the Mainland.

ERIC Educational Resources Information Center

McNutt, Dorothy E.

College of the Mainland (COM) has supported a cooperative education program for business majors since 1969. This program is a one-, two-, or three-semester plan that offers a student work in the community during his studies at COM. Each of the three co-op courses offers four hours credit for exploratory, career preparatory, or career retraining or…

Structure, spectroscopy and dynamics of layered H2O and CO2 ices

USGS Publications Warehouse

,; Plattner, Nuria; Meuwly, Markus

2012-01-01

Molecular dynamics simulations of structural, spectroscopic and dynamical properties of mixed water–carbon dioxide (H2O–CO2) ices are discussed over temperature ranges relevant to atmospheric and astrophysical conditions. The simulations employ multipolar force fields to represent electrostatic interactions which are essential for spectroscopic and dynamical investigations. It is found that at the water/CO2 interface the water surface acts as a template for the CO2 component. The rotational reorientation times in both bulk phases agree well with experimental observations. A pronounced temperature effect on the CO2 reorientation time is observed between 100 K and 200 K. At the interface, water reorientation times are nearly twice as long compared to water in the bulk. The spectroscopy of such ices is rich in the far-infrared region of the spectrum and can be related to translational and rotational modes. Furthermore, spectroscopic signatures mediated across the water/CO2 interface are found in this frequency range (around 440 cm−1). These results will be particularly important for new airborne experiments such as planned for SOFIA.

Atmospheric Processing Module for Mars Propellant Production

NASA Technical Reports Server (NTRS)

Muscatello, Anthony; Gibson, Tracy; Captain, James; Athman, Robert; Nugent, Matthew; Parks, Steven; Devor, Robert

2013-01-01

The multi-NASA center Mars Atmosphere and Regolith COllector/PrOcessor for Lander Operations (MARCO POLO) project was established to build and demonstrate a methane/oxygen propellant production system in a Mars analog environment. Work at the Kennedy Space Center (KSC) Applied Chemistry Laboratory is focused on the Atmospheric Processing Module (APM). The purpose of the APM is to freeze carbon dioxide from a simulated Martian atmosphere containing the minor components nitrogen, argon, carbon monoxide, and water vapor at Martian pressures (8 torr) by using dual cryocoolers with alternating cycles of freezing and sublimation. The resulting pressurized CO2 is fed to a methanation subsystem where it is catalytically combined with hydrogen in a Sabatier reactor supplied by the Johnson Space Center (JSC) to make methane and water vapor. We first used a simplified once-through setup and later employed a HiCO2 recycling system to improve process efficiency. This presentation and paper will cover (1) the design and selection of major hardware items, such as the cryocoolers, pumps, tanks, chillers, and membrane separators, (2) the determination of the optimal cold head design and flow rates needed to meet the collection requirement of 88 g CO2/hr for 14 hr, (3) the testing of the CO2 freezer subsystem, and (4) the integration and testing of the two subsystems to verify the desired production rate of 31.7 g CH4/hr and 71.3 g H20/hr along with verification of their purity. The resulting 2.22 kg of CH4/O2 propellant per 14 hr day (including O2 from electrolysis of water recovered from regolith, which also supplies the H2 for methanation) is of the scale needed for a Mars Sample Return mission. In addition, the significance of the project to NASA's new Mars exploration plans will be discussed.

Dosimetric feasibility of magnetic resonance imaging-guided tri-cobalt 60 preoperative intensity modulated radiation therapy for soft tissue sarcomas of the extremity.

PubMed

Kishan, Amar U; Cao, Minsong; Mikaeilian, Argin G; Low, Daniel A; Kupelian, Patrick A; Steinberg, Michael L; Kamrava, Mitchell

2015-01-01

The purpose of this study was to investigate the dosimetric differences of delivering preoperative intensity modulated radiation therapy (IMRT) to patients with soft tissue sarcomas of the extremity (ESTS) with a teletherapy system equipped with 3 rotating (60)Co sources and a built-in magnetic resonance imaging and with standard linear accelerator (LINAC)-based IMRT. The primary study population consisted of 9 patients treated with preoperative radiation for ESTS between 2008 and 2014 with LINAC-based static field IMRT. LINAC plans were designed to deliver 50 Gy in 25 fractions to 95% of the planning target volume (PTV). Tri-(60)Co system IMRT plans were designed with ViewRay system software. Tri-(60)Co-based IMRT plans achieved equivalent target coverage and dosimetry for organs at risk (long bone, skin, and skin corridor) compared with LINAC-based IMRT plans. The maximum and minimum PTV doses, heterogeneity indices, and ratio of the dose to 50% of the volume were equivalent for both planning systems. One LINAC plan violated the maximum bone dose constraint, whereas none of the tri-(60)Co plans did. Using a tri-(60)Co system, we were able to achieve equivalent dosimetry to the PTV and organs at risk for patients with ESTS compared with LINAC-based IMRT plans. The tri-(60)Co system may be advantageous over current treatment platforms by allowing PTV reduction and by elimination of the additional radiation dose associated with daily image guidance, but this needs to be evaluated prospectively. Copyright © 2015 American Society for Radiation Oncology. Published by Elsevier Inc. All rights reserved.

7 CFR 25.403. - Ongoing 2-year work plan requirement.

Code of Federal Regulations, 2013 CFR

2013-01-01

... 25.403. Agriculture Office of the Secretary of Agriculture RURAL EMPOWERMENT ZONES AND ENTERPRISE COMMUNITIES Post-Designation Requirements § 25.403. Ongoing 2-year work plan requirement. (a) Each Empowerment... conditional upon the designation of the community as an Empowerment Zone; and (iv) Documentation of...

7 CFR 25.403. - Ongoing 2-year work plan requirement.

Code of Federal Regulations, 2012 CFR

2012-01-01

... 25.403. Agriculture Office of the Secretary of Agriculture RURAL EMPOWERMENT ZONES AND ENTERPRISE COMMUNITIES Post-Designation Requirements § 25.403. Ongoing 2-year work plan requirement. (a) Each Empowerment... conditional upon the designation of the community as an Empowerment Zone; and (iv) Documentation of...

7 CFR 25.403. - Ongoing 2-year work plan requirement.

Code of Federal Regulations, 2014 CFR

2014-01-01

... 25.403. Agriculture Office of the Secretary of Agriculture RURAL EMPOWERMENT ZONES AND ENTERPRISE COMMUNITIES Post-Designation Requirements § 25.403. Ongoing 2-year work plan requirement. (a) Each Empowerment... conditional upon the designation of the community as an Empowerment Zone; and (iv) Documentation of...

7 CFR 25.403. - Ongoing 2-year work plan requirement.

Code of Federal Regulations, 2011 CFR

2011-01-01

... 25.403. Agriculture Office of the Secretary of Agriculture RURAL EMPOWERMENT ZONES AND ENTERPRISE COMMUNITIES Post-Designation Requirements § 25.403. Ongoing 2-year work plan requirement. (a) Each Empowerment... conditional upon the designation of the community as an Empowerment Zone; and (iv) Documentation of...

Effective Decision Maker-Scientist Engagement:Climate Change Vulnerability Analysis of California's Water System to Using Decision Scaling.

NASA Astrophysics Data System (ADS)

Schwarz, A. M.; Ray, P.; Brown, C.; Wi, S.

2016-12-01

For nearly 2 years the California Department of Water Resources (CDWR) has been working with the University of Massachusetts Amherst (UMass) to evaluate climate change vulnerabilities to the California State Water Project. Working cooperatively, the team has developed tools and methods to employ a decision scaling approach to CDWR's existing water system model (CalSim-II/CalLite 3.0). This presentation will discuss how and why this partnership came to be, the co-production model the team has developed to share expertise, the new understanding of the system that has been gained through the process, and current and future efforts to influence planning and investments based on the findings of the work. This cooperative decision-maker-with-scientist engagement is unique in that CDWR has not outsourced the application of the science to their systems, and instead has worked directly with UMass researchers to develop the process, produce results, and interpret findings. Further, CDWR staff has worked with UMass researchers to present results in ways that are more useable and actionable for decision-makers. As will be shown, many of these graphics allow the team to use the science differently to improve decision making.

Assessment of long-term and large-scale even-odd license plate controlled plan effects on urban air quality and its implication

NASA Astrophysics Data System (ADS)

Zhao, Suping; Yu, Ye; Qin, Dahe; Yin, Daiying; He, Jianjun

2017-12-01

To solve traffic congestion and to improve urban air quality, long-lasting and large-scale even-odd license plate controlled plan was implemented by local government during 20 November to 26 December 2016 in urban Lanzhou, a semi-arid valley city of northwest China. The traffic control measures provided an invaluable opportunity to evaluate its effects on urban air quality in less developed cities of northwest China. Based on measured simultaneously air pollutants and meteorological parameters, the abatement of traffic-related pollutants induced by the implemented control measures such as CO, PM2.5 and PM10 (the particulate matter with diameter less than 2.5 μm and 10 μm) concentrations were firstly quantified by comparing the air quality data in urban areas with those in rural areas (uncontrolled zones). The concentrations of CO, NO2 from motor vehicles and fine particulate matter (PM2.5) were shown to have significant decreases of 15%-23% during traffic control period from those measured before control period with hourly maximum CO, PM2.5, and NO2/SO2 reduction of 43%, 35% and 141.4%, respectively. The influence of the control measures on AQI (air quality index) and ozone was less as compared to its effect on other air pollutants. Therefore, to alleviate serious winter haze pollution in China and to protect human health, the stringent long-term and large-scale even-odd license plate controlled plan should be implemented aperiodically in urban areas, especially for the periods with poor diffusion conditions.

Lung density change after SABR: A comparative study between tri-Co-60 magnetic resonance-guided system and linear accelerator

PubMed Central

Kim, Eunji; Wu, Hong-Gyun; Park, Jong Min; Kim, Jung-in; Kim, Hak Jae

2018-01-01

Radiation-induced lung damage is an important treatment-related toxicity after lung stereotactic ablative radiotherapy (SABR). After implementing a tri-60Co magnetic-resonance image guided system, ViewRayTM, we compared the associated early radiological lung density changes to those associated with a linear accelerator (LINAC). Eight patients treated with the tri-60Co system were matched 1:1 with patients treated with LINAC. Prescription doses were 52 Gy or 60 Gy in four fractions, and lung dose-volumetric parameters were calculated from each planning system. The first two follow-up computed tomography (CT) were co-registered with the planning CT through deformable registration software, and lung density was measured by isodose levels. Tumor size was matched between the two groups, but the planning target volume of LINAC was larger than that of the tri-60Co system (p = 0.036). With regard to clinically relevant dose-volumetric parameters in the lungs, the ipsilateral lung mean dose, V10Gy and V20Gy were significantly poorer in tri-60Co plans compared to LINAC plans (p = 0.012, 0.036, and 0.017, respectively). Increased lung density was not observed in the first follow-up scan compared to the planning scan. A significant change of lung density was shown in the second follow-up scan and there was no meaningful difference between the tri-60Co system and LINAC for all dose regions. In addition, no patient developed clinical radiation pneumonitis until the second follow-up scan. Therefore, there was no significant difference in the early radiological lung damage between the tri-60Co system and LINAC for lung SABR despite of the inferior plan quality of the tri-60Co system compared to that of LINAC. Further studies with a longer follow-up period are needed to confirm our findings. PMID:29608606

High-Performance Asymmetric Supercapacitors of MnCo2O4 Nanofibers and N-Doped Reduced Graphene Oxide Aerogel.

PubMed

Pettong, Tanut; Iamprasertkun, Pawin; Krittayavathananon, Atiweena; Sukha, Phansiri; Sirisinudomkit, Pichamon; Seubsai, Anusorn; Chareonpanich, Metta; Kongkachuichay, Paisan; Limtrakul, Jumras; Sawangphruk, Montree

2016-12-14

The working potential of symmetric supercapacitors is not so wide because one type of material used for the supercapacitor electrodes prefers either positive or negative charge to both charges. To address this problem, a novel asymmetrical supercapacitor (ASC) of battery-type MnCo 2 O 4 nanofibers (NFs)//N-doped reduced graphene oxide aerogel (N-rGO AE ) was fabricated in this work. The MnCo 2 O 4 NFs at the positive electrode store the negative charges, i.e., solvated OH - , while the N-rGO AE at the negative electrode stores the positive charges, i.e., solvated K + . An as-fabricated aqueous-based MnCo 2 O 4 //N-rGO AE ASC device can provide a wide operating potential of 1.8 V and high energy density and power density at 54 W h kg -1 and 9851 W kg -1 , respectively, with 85.2% capacity retention over 3000 cycles. To understand the charge storage reaction mechanism of the MnCo 2 O 4 , the synchrotron-based X-ray absorption spectroscopy (XAS) technique was also used to determine the oxidation states of Co and Mn at the MnCo 2 O 4 electrode after being electrochemically tested. The oxidation number of Co is oxidized from +2.76 to +2.85 after charging and reduced back to +2.75 after discharging. On the other hand, the oxidation state of Mn is reduced from +3.62 to +3.44 after charging and oxidized to +3.58 after discharging. Understanding in the oxidation states of Co and Mn at the MnCo 2 O 4 electrode here leads to the awareness of the uncertain charge storage mechanism of the spinel-type oxide materials. High-performance ASC here in this work may be practically used in high-power applications.

Innovative Field Experiences in Teacher Education: Student-Teachers and Mentors as Partners in Teaching

ERIC Educational Resources Information Center

Baeten, Marlies; Simons, Mathea

2016-01-01

This study investigates team teaching between student teachers and mentors during student teachers' field experiences. A systematic literature search was conducted, which resulted into a narrative review. Three team teaching models could be distinguished: (1) the co-planning and co-evaluation model, (2) the assistant teaching model, and (3) the…

Geostationary Carbon Process Mapper (GCPM)

NASA Technical Reports Server (NTRS)

Key, Richard; Sander, Stanley; Eldering, Annmarie; Miller, Charles; Frankenberg, Christian; Natraj, Vijay; Rider, David; Blavier, Jean-Francois; Bekker, Dmitriy; Wu, Yen-Hung

2012-01-01

Geostationary Carbon Process Mapper (GCPM) is an earth science mission to measure key atmospheric trace gases related to climate change and human activity.Understanding of sources and sinks of CO2 is currently limited by frequency of observations and uncertainty in vertical transport. GCPM improves this situation by making simultaneous high resolution measurements of CO2, CH4, CF, and CO in near-IR, many times per day. GCPM is able to investigate processes with time scales of minutes to hours. CO2, CH4, CF, Co selected because their combination provides information needed to disentangle natural and anthropogenic sources/sinks. Quasi-continuous monitoring effectively eliminates atmospheric transport uncertainties from source/sink inversion modeling. will have one instrument (GeoFTS), hosted on a commercial communications satellite, planned for two years operation. GCPM will affordably advance the understanding of observed cycle variability improving future climate projections.

Atmospheric Carbon Dioxide Record from In Situ Measurements at Mt. Cimone (1979-1997)

DOE Data Explorer

Colombo, Tiziano [Italian Meteorological Service, Sestola (MO), Italy; Santaguida, Riccardo

1998-01-01

Continuous atmospheric CO2 measurements have been carried out at Mt. Cimone since 1979. Since December 1988, air samples have also been collected approximately once per week in a pair of 2-L, electropolished, stainless steel cylindrical flasks. From 1979 until December 1988, a Hartmann and Braun URAS-2T NDIR gas analyzer was used for CO2 determinations. Currently, CO2 determinations are made through the use of a Siemens Ultramat-5E NDIR gas analyzer. Water vapor is eliminated by passing the air through a U-tube placed in an alcohol bath at -600°C. Calibration of the Ultramat-5E is accomplished by using two CO2-in-air working standard gases. These working standard gas concentrations are checked 10 days apart against three CO2-in-air mixtures that serve as secondary standards. The secondary standards are checked every 6 months against five other CO2-in-air primary standards. Hourly CO2 values are routinely plotted together with wind data. Anomalous concentrations and those affected by instrument failures or local sources are rejected. Atmospheric CO2 concentrations from Mt. Cimone are reported in the 1993 WMO/Scripps mole fraction scale. For further details on the measurement apparatus and sampling techniques used at Mt. Cimone, see Cundari et al. (1990).

Co-registration of cone beam CT and planning CT in head and neck IMRT dose estimation: a feasible adaptive radiotherapy strategy

PubMed Central

Yip, C; Thomas, C; Michaelidou, A; James, D; Lynn, R; Lei, M

2014-01-01

Objective: To investigate if cone beam CT (CBCT) can be used to estimate the delivered dose in head and neck intensity-modulated radiotherapy (IMRT). Methods: 15 patients (10 without replan and 5 with replan) were identified retrospectively. Weekly CBCT was co-registered with original planning CT. Original high-dose clinical target volume (CTV1), low-dose CTV (CTV2), brainstem, spinal cord, parotids and external body contours were copied to each CBCT and modified to account for anatomical changes. Corresponding planning target volumes (PTVs) and planning organ-at-risk volumes were created. The original plan was applied and calculated using modified per-treatment volumes on the original CT. Percentage volumetric, cumulative (planned dose delivered prior to CBCT + adaptive dose delivered after CBCT) and actual delivered (summation of weekly adaptive doses) dosimetric differences between each per-treatment and original plan were calculated. Results: There was greater volumetric change in the parotids with an average weekly difference of between −4.1% and −27.0% compared with the CTVs/PTVs (−1.8% to −5.0%). The average weekly cumulative dosimetric differences were as follows: CTV/PTV (range, −3.0% to 2.2%), ipsilateral parotid volume receiving ≥26 Gy (V26) (range, 0.5–3.2%) and contralateral V26 (range, 1.9–6.3%). In patients who required replan, the average volumetric reductions were greater: CTV1 (−2.5%), CTV2 (−6.9%), PTV1 (−4.7%), PTV2 (−11.5%), ipsilateral (−10.4%) and contralateral parotids (−12.1%), but did not result in significant dosimetric changes. Conclusion: The dosimetric changes during head and neck simultaneous integrated boost IMRT do not necessitate adaptive radiotherapy in most patients. Advances in knowledge: Our study shows that CBCT could be used for dose estimation during head and neck IMRT. PMID:24288402

R744 ejector technology future perspectives

NASA Astrophysics Data System (ADS)

Hafner, Armin; Banasiak, Krzysztof

2016-09-01

Carbon Dioxide, CO2 (R744) was one of the first commonly applied working fluids in the infancy of refrigeration more than 100 years ago. In contrast to ammonia it mainly disappeared after the first generation of synthetic refrigerants have been introduced to the market after 1930. One reason was that the transition from low-rpm belt driven compressors towards the direct electrical motor driven compressors (50-60 Hz) was not performed for CO2 compressors before the revival introduced by Gustav Lorentzen in the 90is of last century. Since 1988 an enormous R & D effort has been made to further develop CO2 refrigeration technology in spite of the opposition from the chemical industry. Today CO2 refrigeration and heat pumping technologies are accepted as viable and sustainable alternatives for several applications like commercial refrigeration, transport refrigeration, vehicle air conditioning & heat pumping, domestic hot water heat pumps and industrial applications. For some applications, the current threshold to introduce R744 technology can be overcome when the system design takes into account the advantage of the thermo dynamical- and fluid properties of CO2. I.e. the system is designed for transcritical operation with all it pros and cons and takes into consideration how to minimize the losses, and to apply the normally lost expansion work. Shortcut-designs, i.e. drop in solutions, just replacing the H(C)FC refrigeration unit with an CO2 systems adapted for higher system pressures will not result in energy efficient products. CO2 systems do offer the advantage of enabling flooded evaporators supported with adapted ejector technology. These units offer high system performances at low temperature differences and show low temperature air mal-distributions across evaporators. This work gives an overview for the development possibilities for several applications during the next years. Resulting in a further market share increase of CO2 refrigeration and heat pump systems, as energy efficient alternatives to current systems not applying natural working fluids.

INFOMAR - Ireland's National Seabed Mapping Programme: A Tool For Marine Spatial Planning

NASA Astrophysics Data System (ADS)

Furey, T. M.

2016-02-01

INFOMAR is Ireland's national seabed mapping programme and is a key action in the national integrated marine plan, Harnessing Our Ocean Wealth. It comprises a multi-platform approach to delivering marine integrated mapping in 2 phases, over a projected 20 year timeline (2006-2026). The programme has three work strands; Data Acquisition, Data Exchange and Integration, and Value Added Exploitation. The Data Acquisition strand includes collection of hydrographic, oceanographic, geological, habitat and heritage datasets that will underpin future sustainable development and management of Ireland's marine resource. INFOMAR outputs are delivered through the Data Exchange and Integration strand. Uses of these outputs are wide ranging and multipurpose, from management plans for fisheries, aquaculture and coastal protection works, to environmental impact assessments, ocean renewable development and integrated coastal zone management. In order to address the evolution and diversification of maritime user requirements, the programme has realigned and developed outputs and new products, in part, through an innovative research funding initiative. Development is also fostered through the Value Added Exploitation strand. INFOMAR outputs and products serve to underpin delivery of Ireland's statutory obligations and enhance compliance with EU and national legislation. This is achieved through co-operation with the agencies responsible for supporting Ireland's international obligations and for the implementation of marine spatial planning. A strategic national seabed mapping programme such as INFOMAR, provides a critical baseline dataset which underpins development of the marine economy, and improves our understanding of the response of marine systems to pressures, and the effect of cumulative impacts. This paper will focus on the evolution and scope of INFOMAR, and look at examples of outputs being harnessed to serve approaches to the management of activities having an impact on the marine environment.

Co-researching with people who have intellectual disabilities: insights from a national survey.

PubMed

O'Brien, Patricia; McConkey, Roy; García-Iriarte, Edurne

2014-01-01

Inclusive research with people with intellectual disabilities is growing internationally but with few studies examining its feasibility. In undertaking a national study exploring what life was like in Ireland for people with intellectual disabilities, a community of practice was developed involving a core group of co-researchers: five people with intellectual disabilities, four university researchers and three service support staff. An additional cadre of 15 co-researchers with intellectual disabilities was recruited to undertake data gathering and analysis with 23 focus groups involving 168 participants. The research experience was documented through oral feedback, progress reports, minutes and a project review. The key learning is documented arising from the setting up of an inclusive advisory group and implementation of each of six research steps. The study demonstrates feasibility and the added value of university co-researchers recruiting and developing skills together with co-researchers with intellectual disabilities. Topics for further research and development are identified. This paper tells you about how people with intellectual disabilities worked with a group of university researchers. Both groups were called co-researchers and together they ran 23 focus groups across Ireland. People with intellectual disabilities talked about their lives and what could make them better. They said they needed to have a good place to live; a job; enough money; relationships; and acceptance as respected citizens. The university co-researchers wrote about what it was like doing research together and how people with intellectual disabilities joined the advisory group; decided on the questions; ran focus groups; and presented findings. Together they grew into a community of researchers where the university co-researchers shared their research skills and people with intellectual disabilities shared what it was like living with a disability. They both saw great value in working together and plan to work more to make this type of research happen. © 2013 John Wiley & Sons Ltd.

Nanoscale Materials for Human Space Exploration: Regenerable CO2 Removal

NASA Technical Reports Server (NTRS)

Arepalli, Sivaram; Nikolaev, Pasha; Gorelik, Olga; Huffman, Chad; Moloney, Padraig; Allada, Ram; Yowell, Leonard

2005-01-01

This viewgraph presentation reviews the use of Nanoscale materials in CO2 removal. It presented the background and review work on regenerable CO2 removal for spaceflight application. It demonstrated a new strategy for developing solid-supported amine absorbents based on carbon nanotube materials.

CO2 Data Distribution and Support from the Goddard Earth Science Data and Information Services Center (GES-DISC)

NASA Technical Reports Server (NTRS)

Hearty, Thomas; Savtchenko, Andrey; Vollmer, Bruce; Albayrak, Arif; Theobald, Mike; Esfandiari, Ed; Wei, Jennifer

2015-01-01

This talk will describe the support and distribution of CO2 data products from OCO-2, AIRS, and ACOS, that are archived and distributed from the Goddard Earth Sciences Data and Information Services Center. We will provide a brief summary of the current online archive and distribution metrics for the OCO-2 Level 1 products and plans for the Level 2 products. We will also describe collaborative data sets and services (e.g., matchups with other sensors) and solicit feedback for potential future services.

Replacement of Chromium Electroplating on Gas Turbine Engine Components Using Thermal Spray Coatings

DTIC Science & Technology

2005-07-20

Composition, Wgt % Powder Composition, Wgt % Powder WC/17Co Diamalloy 2005 WC/17Co Metco 73F-NS-1 Cr3C2-20 (Ni,Cr) Amdry 5260/Diam 3007 Co-28 Mo - 8 Cr-2...Si** Metco 66F-NS Co-28 Mo -17 Cr-3 Si* Diamalloy 3001 Co-28 Mo - 8 Cr-2 Si** Diamalloy 3002 * Tribaloy 800 ** Tribaloy 400 20 4.4. Coating...Work WC/17Co Diamalloy 2005 Yes -- Cr3C2-20 (Ni,Cr) Amdry 5260/Diam 3007 -- Yes Co-28 Mo -17 Cr-3 Si* Diamalloy 3001 -- Yes Co-28 Mo - 8 Cr-2 Si

Technology Advancements for Active Remote Sensing of Carbon Dioxide from Space using the Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) CarbonHawk Experiment Simulator

NASA Astrophysics Data System (ADS)

Obland, Michael D.; Campbell, Joel; Kooi, Susan; Fan, Tai-Fang; Carrion, William; Hicks, Jonathan; Lin, Bing; Nehrir, Amin R.; Browell, Edward V.; Meadows, Byron; Davis, Kenneth J.

2018-04-01

This work describes advances in critical lidar technologies and techniques developed as part of the NASA Active Sensing of CO2 Emissions over Nights, Days, and Seasons CarbonHawk Experiment Simulator system for measuring atmospheric column carbon dioxide (CO2) mixing ratios. This work provides an overview of these technologies and results from recent test flights during the NASA Atmospheric Carbon and Transport - America (ACT-America) Earth Venture Suborbital summer 2016 flight campaign.

Planning Under Continuous Time and Resource Uncertainty: A Challenge for AI

NASA Technical Reports Server (NTRS)

Bresina, John; Dearden, Richard; Meuleau, Nicolas; Smith, David; Washington, Rich; Clancy, Daniel (Technical Monitor)

2002-01-01

There has been considerable work in Al on decision-theoretic planning and planning under uncertainty. Unfortunately, all of this work suffers from one or more of the following limitations: 1) it relies on very simple models of actions and time, 2) it assumes that uncertainty is manifested in discrete action outcomes, and 3) it is only practical for very small problems. For many real world problems, these assumptions fail to hold. A case in point is planning the activities for a Mars rover. For this domain none of the above assumptions are valid: 1) actions can be concurrent and have differing durations, 2) there is uncertainty concerning action durations and consumption of continuous resources like power, and 3) typical daily plans involve on the order of a hundred actions. We describe the rover problem, discuss previous work on planning under uncertainty, and present a detailed. but very small, example illustrating some of the difficulties of finding good plans.

Formation of crystalline phase in the glass matrix of Zr-Co-Al glass-matrix composites and its effect on their mechanical properties

NASA Astrophysics Data System (ADS)

Kim, Woo Chul; Kim, Kang Chul; Na, Min Young; Jeong, Seok Hoan; Kim, Won Tae; Kim, Do Hyang

2017-11-01

The microstructural evolution and mechanical properties of Zr-Co-Al alloys, with compositions of (Zr50Co50)x (Zr56Co26Al18)1-x (x = 1/6, 2/6, 3/6, 4/6, 5/6, 1) and Zr54Co35Al11, (referred to as Z1, Z2, Z3, Z4, Z5, Z6, and Z4.5), were investigated. Alloys Z1-Z3 consisted of crystalline phases, while alloys Z4 and Z4.5 consisted of crystalline phase particles ( 3 vol% and 35 vol%, respectively) embedded within the glassy matrix. Alloys Z5 and Z6 consisted of a monolithic glass phase. The crystalline phase of alloys Z1-Z4.5 consisted of primary B2-ZrCo dendrite and an interdendritic B2-ZrCo/Zr6CoAl2 eutectic phase. The B2-ZrCo dendritic phase exhibited a high work-hardening rate, which originated from the deformation-induced B2-to-B33 martensitic transformation. However, when the brittle interdendritic B2-ZrCo/Zr6CoAl2 eutectic phase fraction increased, the work-hardening rate significantly decreased. The ductility of the glass-matrix composites was significantly impaired by the presence of the interdendritic eutectic phase in the crystalline phase. The results indicate that the design of the crystalline particle microstructure is important with regard to enhancing the plasticity of glass-matrix composites.

Design of Stratified Functional Nanoporous Materials for CO 2 Capture and Conversion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnson, J. Karl; Ye, Jingyun

The objective of this project is to develop novel nanoporous materials for CO 2 capture and conversion. The motivation of this work is that capture of CO 2 from flue gas or the atmosphere coupled with catalytic hydrogenation of CO 2 into valuable chemicals and fuels can reduce the net amount of CO 2 in the atmosphere while providing liquid transportation fuels and other commodity chemicals. One approach to increasing the economic viability of carbon capture and conversion is to design a single material that can be used for both the capture and catalytic conversion of CO 2, because suchmore » a material could increase efficiency through process intensification. We have used density functional theory (DFT) methods to design catalytic moieties that can be incorporated into various metal organic framework (MOF) materials. We chose to work with MOFs because they are highly tailorable, can be functionalized, and have been shown to selectively adsorb CO 2 over N 2, which is a requirement for CO 2 capture from flue gas. Moreover, the incorporation of molecular catalytic moieties into MOF, through covalent bonding, produces a heterogeneous catalytic material having activities and selectivities close to those of homogeneous catalysts, but without the draw-backs associated with homogeneous catalysis.« less

Tailoring gas-phase CO2 electroreduction selectivity to hydrocarbons at Cu nanoparticles

NASA Astrophysics Data System (ADS)

Merino-Garcia, I.; Albo, J.; Irabien, A.

2018-01-01

Copper-based surfaces appear as the most active catalysts for CO2 electroreduction to hydrocarbons, even though formation rates and efficiencies still need to be improved. The aim of the present work is to evaluate the continuous gas-phase CO2 electroreduction to hydrocarbons (i.e. ethylene and methane) at copper nanoparticulated-based surfaces, paying attention to particle size influence (ranging from 25-80 nm) on reaction productivity, selectivity, and Faraday efficiency (FE) for CO2 conversion. The effect of the current density and the presence of a microporous layer within the working electrode are then evaluated. Copper-based gas diffusion electrodes are prepared by airbrushing the catalytic ink onto carbon supports, which are then coupled to a cation exchange membrane (Nafion) in a membrane electrode assembly. The results show that the use of smaller copper nanoparticles (25 nm) leads to a higher ethylene production (1148 μmol m-2 s-1) with a remarkable high FE (92.8%), at the same time, diminishing the competitive hydrogen evolution reaction in terms of FE. This work demonstrates the importance of nanoparticle size on reaction selectivity, which may be of help to design enhanced electrocatalytic materials for CO2 valorization to hydrocarbons.

Insights into the relationship between CO₂ switchability and basicity: examples of melamine and its derivatives.

PubMed

Yin, Hongyao; Feng, Yujun; Liu, Hanbin; Mu, Meng; Fei, Chenhong

2014-08-26

Owing to its wide availability, nontoxicity, and low cost, CO2 working as a trigger to reversibly switch material properties, including polarity, ionic strength, hydrophilicity, viscosity, surface charge, and degree of polymerization or cross-linking, has attracted an increasing attention in recent years. However, a quantitative correlation between basicity of these materials and their CO2 switchability has been less documented though it is of great importance for fabricating switchable system. In this work, the "switch-on" and "switch-off" abilities of melamine and its amino-substituted derivatives by introducing and removing CO2 are studied, and then their quantitative relationship with basicity is established, so that performances of other organobases can be quantitatively predicted. These findings are beneficial for forecasting the CO2 stimuli-responsive behavior of other organobases and the design of CO2-switchable materials.

Perpendicular magnetic anisotropy in Mn{sub 2}CoAl thin film

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sun, N. Y.; Zhang, Y. Q.; Che, W. R.

Heusler compound Mn{sub 2}CoAl (MCA) is attracting more attentions due to many novel properties, such as high resistance, semiconducting behavior and suggestion as a spin-gapless material with a low magnetic moment. In this work, Mn{sub 2}CoAl epitaxial thin film was prepared on MgO(100) substrate by magnetron sputtering. The transport property of the film exhibits a semiconducting-like behavior. Moreover, our research reveals that perpendicular magnetic anisotropy (PMA) can be induced in very thin Mn{sub 2}CoAl films resulting from Mn-O and Co-O bonding at Mn{sub 2}CoAl/MgO interface, which coincides with a recent theoretical prediction. PMA and low saturation magnetic moment could leadmore » to large spin-transfer torque with low current density in principle, and thus our work may bring some unanticipated Heusler compounds into spintronics topics such as the domain wall motion and the current-induced magnetization reversal.« less

The electrochemical selective reduction of NO using CoSe2@CNTs hybrid.

PubMed

Liu, Hui; Xiang, Kaisong; Yang, Bentao; Xie, Xiaofeng; Wang, Dongli; Zhang, Cong; Liu, Zhilou; Yang, Shu; Liu, Cao; Zou, Jianping; Chai, Liyuan

2017-06-01

Converting the NO from gaseous pollutant into NH 4 + through electrocatalytical reduction using cost-effective materials holds great promise for pollutant purifying and resources recycling. In this work, we developed a highly selective and stable catalyst CoSe 2 nanoparticle hybridized with carbon nanotubes (CoSe 2 @CNTs). The CoSe 2 @CNTs hybrid catalysts performed an extraordinary high selectivity for NH 4 + formation in NO electroreduction with minimal N 2 O production and H 2 evolution. The specific spatial structure of CoSe 2 is conductive to the predominant formation of N-H bond between the N from adsorbed NO and H and inhibition of N-N formation from adjacent adsorbed NO. It was also the first time to convert the coordinated NO into NH 4 + using non-noble metal catalysis. Moreover, the original concept of employing CoSe 2 as eletrocatalyst for NO hydrogenation presented in this work can broaden horizons and provide new dimensions in the design of new highly efficient catalysts for NH 4 + synthesis in aqueous solution.

The Technical Work Plan Tracking Tool

NASA Technical Reports Server (NTRS)

Chullen, Cinda; Leighton, Adele; Weller, Richard A.; Woodfill, Jared; Parkman, William E.; Ellis, Glenn L.; Wilson, Marilyn M.

2003-01-01

The Technical Work Plan Tracking Tool is a web-based application that enables interactive communication and approval of contract requirements that pertain to the administration of the Science, Engineering, Analysis, and Test (SEAT) contract at Johnson Space Center. The implementation of the application has (1) shortened the Technical Work Plan approval process, (2) facilitated writing and documenting requirements in a performance-based environment with associated surveillance plans, (3) simplified the contractor s estimate of the cost for the required work, and (4) allowed for the contractor to document how they plan to accomplish the work. The application is accessible to over 300 designated NASA and contractor employees via two Web sites. For each employee, the application regulates access according to the employee s authority to enter, view, and/or print out diverse information, including reports, work plans, purchase orders, and financial data. Advanced features of this application include on-line approval capability, automatic e-mail notifications requesting review by subsequent approvers, and security inside and outside the firewall.

Active-site models for the nickel-iron hydrogenases: effects of ligands on reactivity and catalytic properties.

PubMed

Carroll, Maria E; Barton, Bryan E; Gray, Danielle L; Mack, Amanda E; Rauchfuss, Thomas B

2011-10-03

Described are new derivatives of the type [HNiFe(SR)(2)(diphosphine)(CO)(3)](+), which feature a Ni(diphosphine) group linked to a Fe(CO)(3) group by two bridging thiolate ligands. Previous work had described [HNiFe(pdt)(dppe)(CO)(3)](+) ([1H](+)) and its activity as a catalyst for the reduction of protons (J. Am. Chem. Soc. 2010, 132, 14877). Work described in this paper focuses on the effects on properties of NiFe model complexes of the diphosphine attached to nickel as well as the dithiolate bridge, 1,3-propanedithiolate (pdt) vs 1,2-ethanedithiolate (edt). A new synthetic route to these Ni-Fe dithiolates is described, involving reaction of Ni(SR)(2)(diphosphine) with FeI(2)(CO)(4) followed by in situ reduction with cobaltocene. Evidence is presented that this route proceeds via a metastable μ-iodo derivative. Attempted isolation of such species led to the crystallization of NiFe(Me(2)pdt)(dppe)I(2), which features tetrahedral Fe(II) and square planar Ni(II) centers (H(2)Me(2)pdt = 2,2-dimethylpropanedithiol). The new tricarbonyls prepared in this work are NiFe(pdt)(dcpe)(CO)(3) (2, dcpe = 1,2-bis(dicyclohexylphosphino)ethane), NiFe(edt)(dppe)(CO)(3) (3), and NiFe(edt)(dcpe)(CO)(3) (4). Attempted preparation of a phenylthiolate-bridged complex via the FeI(2)(CO)(4) + Ni(SPh)(2)(dppe) route gave the tetrametallic species [(CO)(2)Fe(SPh)(2)Ni(CO)](2)(μ-dppe)(2). Crystallographic analysis of the edt-dcpe compund [2H]BF(4) and the edt-dppe compound [3H]BF(4) verified their close resemblance. Each features pseudo-octahedral Fe and square pyramidal Ni centers. Starting from [3H]BF(4) we prepared the PPh(3) derivative [HNiFe(edt)(dppe)(PPh(3))(CO)(2)]BF(4) ([5H]BF(4)), which was obtained as a ∼2:1 mixture of unsymmetrical and symmetrical isomers. Acid-base measurements indicate that changing from Ni(dppe) (dppe = Ph(2)PCH(2)CH(2)PPh(2)) to Ni(dcpe) decreases the acidity of the cationic hydride complexes by 2.5 pK(a)(PhCN) units, from ∼11 to ∼13.5 (previous work showed that substitution at Fe leads to more dramatic effects). The redox potentials are more strongly affected by the change from dppe to dcpe, for example the [2](0/+) couple occurs at E(1/2) = -820 for [2](0/+) vs -574 mV (vs Fc(+/0)) for [1](0/+). Changes in the dithiolate do not affect the acidity or the reduction potentials of the hydrides. The acid-independent rate of reduction of CH(2)ClCO(2)H by [2H](+) is about 50 s(-1) (25 °C), twice that of [1H](+). The edt-dppe complex [2H](+) proved to be the most active catalyst, with an acid-independent rate of 300 s(-1).

A Reliability Simulator for Radiation-Hard Microelectronics Development

DTIC Science & Technology

1991-07-01

1 3.0 PHASE II WORK PLANS ................................................................ 2... plan . The correlation experimental details including the devices utilized, the hot-carrier stressing and the wafer-level radiation correlation procedure...channel devices, and a new lifetime extrapolation method is demonstrated for p-channel devices. 3.0 PHASE II WORK PLANS The Phase 1I program consisted of

EGS rock reactions with Supercritical CO2 saturated with water and water saturated with Supercritical CO2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Earl D. Mattson; Travis L. McLing; William Smith

2013-02-01

EGS using CO2 as a working fluid will likely involve hydro-shearing low-permeability hot rock reservoirs with a water solution. After that process, the fractures will be flushed with CO2 that is maintained under supercritical conditions (> 70 bars). Much of the injected water in the main fracture will be flushed out with the initial CO2 injection; however side fractures, micro fractures, and the lower portion of the fracture will contain connate water that will interact with the rock and the injected CO2. Dissolution/precipitation reactions in the resulting scCO2/brine/rock systems have the potential to significantly alter reservoir permeability, so it ismore » important to understand where these precipitates form and how are they related to the evolving ‘free’ connate water in the system. To examine dissolution / precipitation behavior in such systems over time, we have conducted non-stirred batch experiments in the laboratory with pure minerals, sandstone, and basalt coupons with brine solution spiked with MnCl2 and scCO2. The coupons are exposed to liquid water saturated with scCO2 and extend above the water surface allowing the upper portion of the coupons to be exposed to scCO2 saturated with water. The coupons were subsequently analyzed using SEM to determine the location of reactions in both in and out of the liquid water. Results of these will be summarized with regard to significance for EGS with CO2 as a working fluid.« less

Alteration by hyperoxia of ventilatory dynamics during sinusoidal work.

PubMed

Casaburi, R; Stremel, R W; Whipp, B J; Beaver, W L; Wasserman, K

1980-06-01

The effects of hyperoxia on ventilatory and gas exchange dynamics were studied utilizing sinusoidal work rate forcings. Five subjects exercised on 14 occasions on a cycle ergometer for 30 min with a sinusoidally varying work load. Tests were performed at seven frequencies of work load during air or 100% O2 inspiration. From the breath-by-breath responses to these tests, dynamic characteristics were analyzed by extracting the mean level, amplitude of oscillation, and phase lag for each six variables with digital computer techniques. Calculation of the time constant (tau) of the ventilatory responses demonstrated that ventilatory kinetics were slower during hyperoxia than during normoxia (P less than 0.025; avg 1.56 and 1.13 min, respectively). Further, for identical work rate fluctuations, end-tidal CO2 tension fluctuations were increased by hyperpoxia. Ventilation during hyperoxia is slower to respond to variations in the level of metabolically produced CO2, presumably because hyperoxia attenuates carotid body output; the arterial CO2 tension is consequently less tightly regulated.

Dissecting the steps of CO2 reduction: 2. The interaction of CO and CO2 with Pd/γ-Al2O3: an in situ FTIR study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Szanyi, Janos; Kwak, Ja Hun

2014-08-07

Alumina supported Pd catalysts with metal loadings of 0.5, 2.5 and 10 wt% were investigated by in situ FTIR spectroscopy in order to understand the nature of adsorbed species formed during their exposure to CO2 and CO. Exposing the annealed samples to CO2 at 295 K resulted in the formation of alumina support-bound surface species only: linear adsorbed CO2, bidentate carbonates and bicarbonates. Room temperature exposure of all three samples to CO produced IR features characteristic of both ionic and metallic Pd, as well as bands we observed upon CO2 adsorption (alumina support-bound species). Low temperature (100 K) adsorption ofmore » CO on the three samples provided information about the state of Pd after oxidation and reduction. Oxidized samples contained exclusively ionic Pd, while mostly metallic Pd was present in the reduced samples. Subsequent annealing of the CO-saturated samples revealed the facile (low temperature) reduction of PdOx species by adsorbed CO. This process was evidenced by the variations in IR bands characteristic of ionic and metallic Pd-bound CO, as well as by the appearance of IR bands associated with CO2 adsorption as a function of annealing temperature. Samples containing oxidized Pd species (oxidized, annealed or reduced) always produced CO2 upon their exposure to CO, while CO2-related surface entities were observed on samples having only fully reduced (metallic) Pd. Acknowledgements: The catalyst preparation was supported by a Laboratory Directed Research and Development (LDRD) project. This work was supported by the US Department of Energy Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy. JHK also acknowledges the support of this work by the 2013 Research Fund of UNIST (Ulsan National Institute of Science and Technology, Ulsan, Korea).« less

The Ketzin Project, Germany - Status and Future of the First European on-shore CO2 Storage Site

NASA Astrophysics Data System (ADS)

Kuehn, M.; Martens, S.; Moeller, F.; Lueth, S.; Liebscher, A.; Kempka, T.; Ketzin Group

2010-12-01

At the Ketzin site close to Berlin, the German Research Centre for Geosciences operates Europe’s first on-shore CO2 storage site with the aim of increasing the understanding of geological storage of CO2 in saline aquifers. Following site characterization and drilling of three wells, the in-situ field laboratory is fully in use since the CO2 injection started in June 2008. Our presentation summarizes key results from the first (Schilling et al. 2009) and second year (Martens et al. 2010) of injection and outlines future activities. Focus of the research is on interdisciplinary monitoring and modeling approaches. Since start of the CO2 injection on June 30, 2008, the injection facility has been reliably and safely operated. By the end of August 2010, about 37,700 tons of food grade CO2 have been injected into a sandstone aquifer of the Triassic Stuttgart Formation at a depth of about 630 to 700 m. The new project CO2MAN (CO2 Reservoir Management) is planned to succeed the EU-funded CO2SINK project which ended in March 2010 and further nationally funded projects. Our interdisciplinary monitoring concept for the Ketzin site integrates geophysical, geochemical and microbial investigations. Following baseline measurements prior to the injection, repeat measurements have been carried out for a comprehensive characterization of the reservoir and the developing CO2 plume. CO2MAN aims at continuing the injection up to a maximum of 100,000 tons of CO2, advancing the monitoring concept and further integrating numerical modeling. Planned activities include the installation of a third and a fourth observation well and the testing of well abandonment procedures. All data available from the Ketzin wells and the different monitoring techniques are going to be compiled into an integral geological model of the site. Such a geological model is the prerequisite for any holistic approach and understanding of CO2 storage not only at Ketzin. A variety of seismic methods, including cross-hole measurement between both observation wells, surface-downhole observations, and 2D and 3D surface surveys have been used in order to cover the near-injection to regional scale. In addition, geoelectric methods including cross-hole measurements between the wells and additional surface and surface-downhole electrical resistivity tomography have been applied to monitor the CO2 migration process. Geological modeling and dynamic flow modeling is conducted in different phases, including pre-existing data, information obtained from drilling and subsequent CO2 injection. On-going modeling also integrates recent geophysical monitoring data in order to improve the understanding of geological heterogeneities at the Ketzin site and their impact on the CO2 plume distribution. Martens S., Liebscher A., Möller F., Würdemann H, Schilling F., Kühn M., and Ketzin Group (2010) Progress Report on the First European on-shore CO2 Storage Site at Ketzin (Germany) - Second Year of Injection, GHGT 10, subm. Schilling F., Borm G., Würdemann H., Möller F., Kühn M., CO2SINK Group (2009) Status Report on the First European on-shore CO2 Storage Site at Ketzin (Germany). GHGT 9, Energy Procedia 1(1) 2029-2035, doi: 10.1016/j.egypro.2009.01.264

Catalytic Ring Hydrogenation of Benzoic Acid with Supported Transition Metal Catalysts in scCO2

PubMed Central

Wang, Hongjun; Zhao, Fengyu

2007-01-01

The ring hydrogenation of benzoic acid to cyclohexanecarboxylic acid over charcoal-supported transition metal catalysts in supercritical CO2 medium has been studied in the present work. The cyclohexanecarboxylic acid can be produced efficiently in supercritical CO2 at the low reaction temperature of 323 K. The presence of CO2 increases the reaction rate and several parameters have been discussed.

Reevaluation of the NOAA/CMDL carbon monoxide reference scale and comparisons with CO reference gases at NASA-Langley and the Fraunhofer Institut

NASA Technical Reports Server (NTRS)

Novelli, P. C.; Collins, J. E., Jr.; Myers, R. C.; Sachse, G. W.; Scheel, H. E.

1994-01-01

The carbon monoxide (CO) reference scale created by the National Oceanic and Atmospheric Administration/Climate Monitoring and Diagnostics Laboratory (NOAA/CMDL) is used to quantify measurements of CO in the atmosphere, calibrate standards of other laboratories and to otherwise provide reference gases to the community measuring atmospheric CO. This reference scale was created based upon a set of primary standards prepared by gravimetric methods at CMDL and has been propagated to a set of working standards. In this paper we compare CO mixing ratios assigned to the working standards by three approaches: (1) calibration against the original gravimetric standards, (2) calibration using only working standards as the reference gas, and (3) calibration against three new gravimetric standards prepared to CMDL. The agreement between these values was typically better than 1%. The calibration histories of CMDL working standards are reviewed with respect to expected rates of CO change in the atmosphere. Using a Monte Carlo approach to simulate the effect of drifting standards on calculated mixing ratios, we conclude that the error solely associated with the maintenance of standards will limit the ability to detect small CO changes in the atmosphere. We also report results of intercalibration experiments conducted between CMDL and the Diode Laser Sensor Group (DACOM) at the NASA Langley Research Center (Hampton, Virginia), and CMDL and the Fraunhofer-Institut (Garmisch-Partenkirchen, Germany). Each laboratory calibrated several working standards for CO using their reference gases, and these results were compared to calibrations conducted by CMDL. The intercomparison of eight standards (CO concentrations between approximately 100 and approximately 165 ppb) by CMDL and NASA agreed to better than +/- 2%. The calibration of six standards (CO concentrations between approximately 50 and approximately 210 ppb) by CMDL and the Fraunhofer-Institut agreed to within +/- 2% for four standards, and to within +/- 5% for all six standards.

Valorisation of CO2-rich off-gases to biopolymers through biotechnological process.

PubMed

Garcia-Gonzalez, Linsey; De Wever, Heleen

2017-11-01

As one of the key enabling technologies, industrial biotechnology has a high potential to tackle harmful CO2 emissions and to turn CO2 into a valuable commodity. So far, experimental work mainly focused on the bioconversion of pure CO2 to chemicals and plastics and little is known about the tolerance of the bioprocesses to the presence of impurities. This work is the first to investigate the impact of real CO2-rich off-gases on autotrophic production of polyhydroxybutyrate. To this end, two-phase heterotrophic-autotrophic fermentation experiments were set up, consisting of heterothrophic cell mass growth using glucose as substrate followed by autotrophic biopolymer production using either pure synthetic CO2 or industrial off-gases sampled at two point sources. The use of real off-gases did not affect the bacterial performance. High biopolymer content (up to 73%) and productivities (up to 0.227 g/lh) were obtained. Characterisation of the polymers showed that all biopolymers had similar properties, independent of the CO2 source. Moreover, the CO2-derived biopolymers' properties were comparable to commercial ones and biopolymers reported in literature, which are all produced from organic carbon sources. © FEMS 2017. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

Parametric analysis of a novel cryogenic CO2 capture system based on Stirling coolers.

PubMed

Song, Chun Feng; Kitamura, Yutaka; Li, Shu Hong; Jiang, Wei Zhong

2012-11-20

CO(2) capture and storage (CCS) is an important alternative to control greenhouse gas (GHG) effects. In previous work, a novel desublimation CO(2) capture process has been exploited making use of three free piston Stirling coolers (namely, SC-1, SC-2, and SC-3, respectively). Based on the developed system, moisture and CO(2) in the flue gas can condense and desublimate in the prefreezing and main-freezing towers, respectively. Meanwhile, the storage column is chilled by SC-3 to preserve the frosted CO(2), and permanent gas (such as N(2)) passes through the system without phase change. The whole process can be implemented at atmospheric pressure and reduce the energy penalty (e.g., solvent regeneration and pressure drop) in other technologies. In this work, the influence of process parameters has been investigated in detail. The optimal conditions for the system are as follows: idle operating time is 240 min, flow rate is 5 L/min, vacuum degree of the interlayer is 2.2 × 10(3) Pa, and temperatures of SC-1, -2, and -3 are -30, -120, and -120 °C, respectively. Under these conditions, the energy consumption of the system is around 0.5 MJ(electrical)/kg CO(2) with above 90% CO(2) recovery.

Efficient Conversion of CO 2 to CO Using Tin and Other Inexpensive and Easily Prepared Post-Transition Metal Catalysts

DOE PAGES

Medina-Ramos, Jonnathan; Pupillo, Rachel C.; Keane, Thomas P.; ...

2015-02-19

The development of affordable electrocatalysts that can drive the reduction of CO 2 to CO with high selectivity, efficiency, and large current densities is a critical step on the path to production of liquid carbon-based fuels. In this work, we show that inexpensive triflate salts of Sn 2+, Pb 2+, Bi 3+, and Sb 3+ can be used as precursors for the electrodeposition of CO 2 reduction cathode materials from MeCN solutions, providing a general and facile electrodeposition strategy, which streamlines catalyst synthesis. The ability of these four platforms to drive the formation of CO from CO 2 in themore » presence of [BMIM]OTf was probed. The electrochemically prepared Sn and Bi catalysts proved to be highly active, selective, and robust platforms for CO evolution, with partial current densities of j CO = 5-8 mA/cm 2 at applied overpotentials of η < 250 mV. By contrast, the electrodeposited Pb and Sb catalysts do not promote rapid CO generation with the same level of selectivity. The Pb material is only ~10% as active as the Sn and Bi systems at an applied potential of E = -1.95 V and is rapidly passivated during catalysis. The Sb-comprised cathode material shows no activity for conversion of CO 2 to CO under analogous conditions. When taken together, this work demonstrates that 1,3-dialkylimidazoliums can promote CO production, but only when used in combination with an appropriately chosen electrocatalyst material. More broadly, these results suggest that the interactions between CO 2, the imidazolium promoter, and the cathode surface are all critical to the observed catalysis.« less

Planning Documents Known Releases SWMUs Tooele Army Depot Tooele, Utah. Volume 1: Corrective Measures Study Work Plan

DTIC Science & Technology

2000-02-01

1-4 1.2 .2 .3 S oil ... oil ...................................................................................................... 5-2 5.2.3 Surface W ater...S oil ............................................................................................................. 6-2 6.2.2 G roundw ater

Volcanic Hazard Maps; the results and progress made by the IAVCEI Hazard Map working group

NASA Astrophysics Data System (ADS)

Calder, Eliza; Lindsay, Jan; Wright, Heather

2017-04-01

The IAVCEI Commission on Volcanic Hazards and Risk set up a working group on Hazard Maps in 2014. Since then, the group has led or co-organised three major workshops, and organized two thematic conference sessions. In particular we have initiated a series of workshops, named the "State of the Hazard Map" which we plan to continue (the first was held at COV8 (State of the Hazard Map 1) and second at COV9 (State of the Hazard Map 2) and the third will be held at IAVCEI General Assembly in Portland. The broad aim of these activities is to work towards an IAVCEI-endorsed considerations or guidelines document for volcanic hazard map generation. The workshops have brought together people from around the world working on volcanic hazard maps, and have had four primary objectives: 1) to review (and collect further data on) the diverse variety of methods and rationales currently used to develop maps; 2) to openly discuss approaches and experiences regarding how hazard maps are interpreted and used by different groups; 3) to discuss and prepare the IAVCEI Guidelines document; and lastly, 4) Discuss options for finalizing, publishing and disseminating the Guidelines document (e.g. wiki, report, open-source publication). This presentation will provide an update of the results and outcomes of those initiatives. This includes brief outcomes of the reviews undertaken, a survey that has been constructed in order to gather additional data, the planned structure for the guidelines documents and a summary of the key findings to date. The majority of the participants of these activities so far have come from volcano observatories or geological surveys, as these institutions commonly have primary responsibility for making operational hazard map. It is important however that others in the scientific community that work on quantification of volcanic hazard contribute to these guidelines. We therefore invite interested parties to become involved.

Synergistic mechanism of Ag+-Zn2+ in anti-bacterial activity against Enterococcus faecalis and its application against dentin infection.

PubMed

Fan, Wei; Sun, Qing; Li, Yanyun; Tay, Franklin R; Fan, Bing

2018-01-31

Ag + and Zn 2+ have already been used in combinations to obtain both enhanced antibacterial effect and low cytotoxicity. Despite this, it is still unclear how the Zn 2+ co-works with Ag + in the synergistic antibacterial activity. The main purposes of this study were to investigate the co-work pattern and optimum ratio between Ag + and Zn 2+ in their synergistic antibacterial activity against E. faecalis, the possible mechanisms behind this synergy and the primary application of optimum Ag + -Zn 2+ co-work pattern against the E. faecalis biofilm on dentin. A serial of Ag + -Zn 2+ atomic combination ratios were tested on both planktonic and biofilm-resident E. faecalis on dentin, their antibacterial efficiency was calculated and optimum ratio determined. And the cytotoxicity of various Ag + -Zn 2+ atomic ratios was tested on MC3T3-E1 Cells. The role of Zn 2+ in Ag + -Zn 2+ co-work was evaluated using a Zn 2+ pretreatment study and membrane potential-permeability measurement. The results showed that the synergistically promoted antibacterial effect of Ag + -Zn 2+ combinations was Zn 2+ amount-dependent with the 1:9 and 1:12 Ag + -Zn 2+ atomic ratios showing the most powerful ability against both planktonic and biofilm-resident E. faecalis. This co-work could likely be attributed to the depolarization of E. faecalis cell membrane by the addition of Zn 2+ . The cytotoxicity of the Ag + -Zn 2+ atomic ratios of 1:9 and 1:12 was much lower than 2% chlorhexidine. The Ag + -Zn 2+ atomic ratios of 1:9 and 1:12 demonstrated similar strong ability against E. faecalis biofilm on dentin but much lower cytotoxicity than 2% chlorhexidine. New medications containing optimum Ag + -Zn 2+ atomic ratios higher than 1:6, such as 1:9 or 1:12, could be developed against E. faecalis infection in root canals of teeth or any other parts of human body.

Active-Site Models for the Nickel-Iron Hydrogenases: Effects of Ligands on Reactivity and Catalytic Properties

PubMed Central

Carroll, Maria E.; Barton, Bryan E.; Gray, Danielle L.; Mack, Amanda E.; Rauchfuss, Thomas B.

2011-01-01

Described are new derivatives of the type [HNiFe(SR)2(diphosphine)(CO)3]+, which feature a Ni(diphosphine) group linked to a Fe(CO)3 group via two bridging thiolate ligands. Previous work had described [HNiFe(pdt)(dppe)(CO)3]+ ([1H]+) and its activity as a catalyst for the reduction of protons. Work described in this paper focused on the effects of the diphosphine attached to nickel as well as the dithiolate bridge, 1,3-propanedithiolate (pdt) vs 1,2-ethanedithiolate (edt). A new synthetic route to these Ni-Fe dithiolates is described, involving reaction of Ni(SR)2(diphosphine) with FeI2(CO)4 followed by in situ reduction with cobaltocene. Evidence is presented that this route proceeds via metastable μ-iodo derivatives. Attempted isolation of such species led to the crystallization of NiFe(Me2pdt)(dppe)I2, which features tetrahedral Fe(II) and square planar Ni(II) centers (Me2pdt = 2,2-dimethylpropanedithiol). The new tricarbonyls prepared in this work are NiFe(pdt)(dcpe)(CO)3 (2, dcpe = 1,2-bis(dicyclohexylphosphino)ethane), NiFe(edt)(dppe)(CO)3 (3), and NiFe(edt)(dcpe)(CO)3 (4). Attempted preparation of a phenylthiolate-bridged complex via the FeI2(CO)4 + Ni(SPh)2(dppe) route gave the tetrametallic species [(CO)2Fe(SPh)2Ni(CO)]2(μ-dppe)2. Crystallographic analysis of the edt-dcpe compund [2H]BF4 and the edt-dppe compound [3H]BF4 verified their close resemblance. Each features pseudo-octahedral Fe and square pyramidal Ni centers. Starting from [4H]BF4 we prepared the PPh3 derivative [HNiFe(edt)(dppe)(PPh3)(CO)2]BF4 ([5H]BF4), which was obtained as a ~2:1 mixture of unsymmetrical and symmetrical isomers. Acid-base measurements indicate that changing from Ni(dppe) to Ni(dcpe) decreases the acidity of the cationic hydride complexes by 2.5 pKaMeCN units, from ~11 to ~13.5 (previous work showed that substitution at Fe leads to more dramatic effects). The redox potentials are more strongly affected by the change from dppe to dcpe, for example the [2]0/+ couple occurs at E1/2 = −820 for [2]0/+ vs −574 mV (vs Fc+/0) for [1]0/+. Changes in the dithiolate do not affect the acidity or the reduction potentials of the hydrides. The acid-independent rate of reduction of CH2ClCO2H by [2H]+ is ca. 50 s−1 (25 °C), twice that of [1H]+. The edt-dppe complex [2H]+ proved to be the most active catalyst, with an acid-independent rate of 300 s−1. PMID:21866886

2. AERIAL VIEW LOOKING WEST SOUTHWEST SHOWING DOLPHIN MANUFACTURING CO., ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. AERIAL VIEW LOOKING WEST SOUTHWEST SHOWING DOLPHIN MANUFACTURING CO., BARBOUR FLAX SPINNING CO. -- SPRUCE ST. MILL, ROGERS LOCOMOTIVE AND MACHINE WORKS -- MILLWRIGHT SHOP AND FITTING SHOP. - Great Falls S. U. M. Historic District, Oliver Street, Paterson, Passaic County, NJ

Surfactant-assisted hydrothermal crystallization of nanostructured lithium metasilicate (Li{sub 2}SiO{sub 3}) hollow spheres: II-Textural analysis and CO{sub 2}-H{sub 2}O sorption evaluation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ortiz-Landeros, Jose; Gomez-Yanez, Carlos; Pfeiffer, Heriberto, E-mail: pfeiffer@iim.unam.mx

In a previous work, the synthesis and structural-microstructural characterization of different nanocrystalline lithium metasilicate (Li{sub 2}SiO{sub 3}) samples were performed. Then, in this work, initially, a textural analysis was performed over the same samples. Li{sub 2}SiO{sub 3} samples prepared with a non-ionic surfactant (TRITON X-114) presented the best textural properties. Therefore, this sample was selected to evaluate its water vapor (H{sub 2}O) and carbon dioxide (CO{sub 2}) sorption properties. Sorption experiments were performed at low temperatures (30-80 deg. C) in presence of water vapor using N{sub 2} or CO{sub 2} as carrier gases. Results clearly evidenced that CO{sub 2} sorptionmore » on these materials is highly improved by H{sub 2}O vapor, and of course, textural properties enhanced the H{sub 2}O-CO{sub 2} sorption efficiency, in comparison with the solid-state reference sample. - Graphical abstract: Li{sub 2}SiO{sub 3} varied significantly its capacity of CO{sub 2} absorption as a function of the microstructural properties and by the water presence. Highlights: > We studied the CO{sub 2} absorption on different Li{sub 2}SiO{sub 3} samples in presence of H{sub 2}O vapor. > It was proved that CO{sub 2} absorption on Li{sub 2}SiO{sub 3} is controlled by different factors. > Li{sub 2}SiO{sub 3} with a porous microstructure produces a higher CO{sub 2} absorption. > H{sub 2}O vapor favors the CO{sub 2} absorption on Li{sub 2}SiO{sub 3} due to a surface hydroxylation.« less

The special programme of research in human reproduction: forty years of activities to achieve reproductive health for all.

PubMed

Benagiano, Giuseppe; d'Arcangues, Catherine; Harris Requejo, Jennifer; Schafer, Alessandra; Say, Lale; Merialdi, Mario

2012-01-01

The Special Programme of Research in Human Reproduction (HRP), co-sponsored by the UNDP, UNFPA, WHO, and the World Bank, is celebrating 40 years of activities with an expansion of its mandate and new co-sponsors. When it began, in 1972, the main focus was on evaluating the acceptability, effectiveness, and safety of existing fertility-regulating methods, as well as developing new, improved modalities for family planning. In 1994, HRP not only made major contributions to the Plan of Action of the International Conference on Population and Development (ICPD); it also broadened its scope of work to include other aspects of health dealing with sexuality and reproduction, adding a specific perspective on gender issues and human rights. In 2002, HRP's mandate was once again broadened to include sexually transmitted infections and HIV/AIDS and in 2003 it was further expanded to research activities on preventing violence against women and its many dire health consequences. Today, the work of the Programme includes research on: the sexual and reproductive health of adolescents, women, and men; maternal and perinatal health; reproductive tract and sexually transmitted infections (including HIV/AIDS); family planning; infertility; unsafe abortion; sexual health; screening for cancer of the cervix in developing countries, and gender and reproductive rights. Additional activities by the Programme have included: fostering international cooperation in the field of human reproduction; the elaboration of WHO's first Global Reproductive Health Strategy; work leading to the inclusion of ICPD's goal 'reproductive health for all by 2015' into the Millennium Development Goal framework; the promotion of critical interagency statements on the public health, legal, and human rights implications of female genital mutilation and gender-biased sex selection. Finally, HRP has been involved in the creation of guidelines and tools, such as the 'Medical eligibility criteria for contraceptive use', the 'Global handbook for family planning providers', the 'Definition of core competencies in primary health care', and designing tools for operationalizing a human rights approach to sexual and reproductive health programmes. Copyright © 2012 S. Karger AG, Basel.

A non-linear optimization programming model for air quality planning including co-benefits for GHG emissions.

PubMed

Turrini, Enrico; Carnevale, Claudio; Finzi, Giovanna; Volta, Marialuisa

2018-04-15

This paper introduces the MAQ (Multi-dimensional Air Quality) model aimed at defining cost-effective air quality plans at different scales (urban to national) and assessing the co-benefits for GHG emissions. The model implements and solves a non-linear multi-objective, multi-pollutant decision problem where the decision variables are the application levels of emission abatement measures allowing the reduction of energy consumption, end-of pipe technologies and fuel switch options. The objectives of the decision problem are the minimization of tropospheric secondary pollution exposure and of internal costs. The model assesses CO 2 equivalent emissions in order to support decision makers in the selection of win-win policies. The methodology is tested on Lombardy region, a heavily polluted area in northern Italy. Copyright © 2017 Elsevier B.V. All rights reserved.

Forest management under changing climate conditions: Is timing a tool for Sustainable Forest Management? Relevant questions for research development

NASA Astrophysics Data System (ADS)

D'Aprile, Fabrizio; McShane, Paul; Tapper, Nigel

2013-04-01

Change of climate conditions influence energy fluxes applicable to forest ecosystems. These affect cycles of nutrients and materials, primary productivity of the ecosystem, biodiversity, ecological functionality and, consequently, carbon equilibria of the forest ecosystem. Temporal factors influence physical, biological, ecological, and climatic processes and functions. For example, seasonality, cycles, periodicity, and trends in climate variables; tree growth, forest growth, and forest metabolic activities (i.e., photosynthesis and respiration) are commonly known to be time-related. In tropical forests, the impacts of changing climate conditions may exceed temperature and/or precipitation thresholds critical to forest tree growth or health. Historically, forest management emphasises growth rates and financial returns as affected by species and site. Until recently, the influence of climate variability on growth dynamics has not been influential in forest planning and management. Under this system, especially in climatic and forest regions where most of species are stenoecious, periodical wood harvesting may occur in any phase of growth (increasing, decreasing, peak, and trough). This scenario presents four main situations: a) harvesting occurs when the rate of growth is decreasing: future productivity is damaged; the minimum biomass capital may be altered, and CO2 storage is negatively affected; b) harvesting occurs during a trough of the rate of growth: the minimum biomass capital necessary to preserve the resilience of the forest is damaged; the damage can be temporary (decades) or permanent; CO2 storage capacity is deficient - which may be read as an indirect emission of CO2 since the balance appears negative; c) harvesting occurs when the rate of growth is increasing: the planned wood mass can be used without compromising the resilience and recovery of the forest; CO2 storage remains increasing; d) harvesting occurs during a peak period of growth: the wood mass harvested can be even higher than planned, and the rate of CO2 storage can be above the average. A real risk for SFM under changing climatic conditions is that negative effects may be amplified; critical thresholds of temperature and/or rainfall for tree growth and stress may be exceeded with impacts on growth response, resilience, and CO2 balance that are not completely known. Furthermore, temporal changes in silvicultural and harvesting operations may lead to increased carbon emissions. Under this scenario and the consequent risks to SFM forestry operations should be planned or scheduled in periods when climate variables influencing tree growth and stress are within the relative thresholds. In this way, silvicultural operations and harvesting are going to be optimised to climate variability and forest growth responses, rather than just forest timber production.

Valorization of biogas into liquid hydrocarbons in plasma-catalyst reactor

NASA Astrophysics Data System (ADS)

Nikravech, Mehrdad; Rahmani, Abdelkader; Labidi, Sana; Saintini, Noiric

2016-09-01

Biogas represents an important source of renewable energy issued from biological degradation of biomass. It is planned to produce in Europe the amount of biogas equivalent to 6400 kWh electricity and 4500 kteo (kilo tons equivalent oil) in 2020. Currently the biogas is used in cogeneration engines to produce heat and electricity directly in farms or it is injected in gas networks after purification and odorisation. The aim of this work is to propose a third option that consists of valorization of biogas by transformation into liquid hydrocarbons like acetone, methanol, ethanol, acetic acid etc. These chemicals, among the most important feed materials for chemical industries, retain CO2 molecules participating to reduce the greenhouse gas emissions and have high storage energy capacity. We developed a low temperature atmospheric plasma-catalyst reactor (surface dielectric barrier discharge) to transform biogas into chemicals. The conversion rates of CH4 and CO2 are respectively about 50% and 30% depending on operational conditions. The energetic cost is 25 eV/molecule. The yields of liquid hydrocarbon reaches currently 10% wt. More the 11 liquid chemicals are observed in the liquid fraction. Acknowledgements are due to SPC Programme Energie de demain.

Applying the Theory of Constraints to a Base Civil Engineering Operations Branch

DTIC Science & Technology

1991-09-01

Figure Page 1. Typical Work Order Processing . .......... 7 2. Typical Job Order Processing . .......... 8 3. Typical Simplified In-Service Work Plan for...Customers’ Customer Request Service Planning Unit Production] Control Center Material Control Scheduling CE Shops Figure 1.. Typical Work Order Processing 7

Motion Planning and Synthesis of Human-Like Characters in Constrained Environments

NASA Astrophysics Data System (ADS)

Zhang, Liangjun; Pan, Jia; Manocha, Dinesh

We give an overview of our recent work on generating naturally-looking human motion in constrained environments with multiple obstacles. This includes a whole-body motion planning algorithm for high DOF human-like characters. The planning problem is decomposed into a sequence of low dimensional sub-problems. We use a constrained coordination scheme to solve the sub-problems in an incremental manner and a local path refinement algorithm to compute collision-free paths in tight spaces and satisfy the statically stable constraint on CoM. We also present a hybrid algorithm to generate plausible motion by combing the motion computed by our planner with mocap data. We demonstrate the performance of our algorithm on a 40 DOF human-like character and generate efficient motion strategies for object placement, bending, walking, and lifting in complex environments.

Waste flow analysis and life cycle assessment of integrated waste management systems as planning tools: Application to optimise the system of the City of Bologna.

PubMed

Tunesi, Simonetta; Baroni, Sergio; Boarini, Sandro

2016-09-01

The results of this case study are used to argue that waste management planning should follow a detailed process, adequately confronting the complexity of the waste management problems and the specificity of each urban area and of regional/national situations. To support the development or completion of integrated waste management systems, this article proposes a planning method based on: (1) the detailed analysis of waste flows and (2) the application of a life cycle assessment to compare alternative scenarios and optimise solutions. The evolution of the City of Bologna waste management system is used to show how this approach can be applied to assess which elements improve environmental performance. The assessment of the contribution of each waste management phase in the Bologna integrated waste management system has proven that the changes applied from 2013 to 2017 result in a significant improvement of the environmental performance mainly as a consequence of the optimised integration between materials and energy recovery: Global Warming Potential at 100 years (GWP100) diminishes from 21,949 to -11,169 t CO2-eq y(-1) and abiotic resources depletion from -403 to -520 t antimony-eq. y(-1) This study analyses at great detail the collection phase. Outcomes provide specific operational recommendations to policy makers, showing the: (a) relevance of the choice of the materials forming the bags for 'door to door' collection (for non-recycled low-density polyethylene bags 22 kg CO2-eq (tonne of waste)(-1)); (b) relatively low environmental impacts associated with underground tanks (3.9 kg CO2-eq (tonne of waste)(-1)); (c) relatively low impact of big street containers with respect to plastic bags (2.6 kg CO2-eq. (tonne of waste)(-1)). © The Author(s) 2016.

Climate stabilization wedges in action: a systems approach to energy sustainability for Hawaii Island.

PubMed

Johnson, Jeremiah; Chertow, Marian

2009-04-01

Pacala and Socolow developed a framework to stabilize global greenhouse gas levels for the next fifty years using wedges of constant size representing an increasing use of existing technologies and approaches for energy efficiency, carbon free generation, renewables, and carbon storage. The research presented here applies their approach to Hawaii Island, with modifications to support local scale analysis and employing a "bottom-up" methodology that allows for wedges of various sizes. A discretely bounded spatial unit offers a testing ground for a holistic approach to improving the energy sector with the identification of local options and limitations to the implementation of a comprehensive energy strategy. Nearly 80% of total primary energy demand across all sectors for Hawaii Island is currently met using petroleum-based fuels.The Sustainable Energy Plan scenario included here presents an internally consistent set of recommendations bounded by local constraints in areas such as transportation efficiency, centralized renewable generation (e.g., geothermal, wind), reduction in transmission losses, and improved building efficiency. This scenario shows thatthe demand for primary energy in 2030 could be reduced by 23% through efficiency measures while 46% could be met by renewable generation, resulting in only 31% of the projected demand being met by fossil fuels. In 2030, the annual releases of greenhouse gases would be 3.2 Mt CO2-eq/year under the Baseline scenario, while the Sustainable Energy Plan would reduce this to 1.2 Mt CO2-eq/year--an annual emissions rate 40% below 2006 levels and 10% below 1990 levels. The total for greenhouse gas emissions during the 24-year study period (2007 to 2030) is 59.9 Mt CO2-eq under the Baseline scenario and 32.5 Mt CO2-eq under the Sustainable Energy Plan scenario. Numerous combinations of efficiency and renewable energy options can be employed in a manner that stabilizes the greenhouse gas emissions of Hawaii Island.

New 'PropCo' chief sets out goals.

PubMed

Baillie, Jonathan

2013-02-01

Plans now well into implementation, to transfer ownership, this April, of the assets and buildings formerly owned by Primary Care Trusts on their abolition to a new limited company, NHS Property Services, have naturally aroused considerable interest across the healthcare estates community. At last October's Healthcare Estates 2012 conference, Simon Holden, who was appointed Chief Executive of the new Government-owned company in August 2012, explained 'how the organisation will work in practice'.

SU-F-T-287: A Preliminary Study On Patient Specific VMAT Verification Using a Phosphor-Screen Based Geometric QA System (Raven QA)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, M; Yi, B; Wong, J

Purpose: The RavenQA system (LAP Laser, Germany) is a QA device with a phosphor screen detector for performing the QA tasks of TG-142. This study tested if it is feasible to use the system for the patient specific QA of the Volumetric Modulated Arc Therapy (VMAT). Methods: Water equivalent material (5cm) is attached to the front of the detector plate of the RavenQA for dosimetry purpose. Then the plate is attached to the gantry to synchronize the movement between the detector and the gantry. Since the detector moves together with gantry, The ’Reset gantry to 0’ function of the Eclipsemore » planning system (Varian, CA) is used to simulate the measurement situation when calculating dose of the detector plate. The same gantry setup is used when delivering the treatment beam for feasibility test purposes. Cumulative dose is acquired for each arc. The optical scatter component of each captured image from the CCD camera is corrected by deconvolving the 2D spatial invariant optical scatter kernel (OSK). We assume that the OSK is a 2D isotropic point spread function with inverse-squared decrease as a function of radius from the center. Results: Three cases of VMAT plans including head & neck, whole pelvis and abdomen-pelvis are tested. Setup time for measurements was less than 5 minutes. Passing rates of absolute gamma were 99.3, 98.2, 95.9 respectively for 3%/3mm criteria and 96.2, 97.1, 86.4 for 2%/2mm criteria. The abdomen-pelvis field has long treatment fields, 37cm, which are longer than the detector plate (25cm). This plan showed relatively lower passing rate than other plans. Conclusion: An algorithm for IMRT/VMAT verification using the RavenQA has been developed and tested. The model of spatially invariant OSK works well for deconvolution purpose. It is proved that the RavenQA can be used for the patient specific verification of VMAT. This work is funded in part by a Maryland Industrial Partnership Program grant to University of Maryland and to JPLC who owns the Raven technology. John Wong is a co-founder of JPLC.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rapko, Brian M.; Bryan, Samuel A.; Chatterjee, Sayandev

This report summarizes work accomplished in fiscal year (FY) 2013, exploring the chemistry of a low-valence technetium(I) species, [Tc(CO) 3(H 2O) 3] +, a compound of interest due to its implication in the speciation of alkaline-soluble technetium in several Hanford tank waste supernatants. Various aspects of FY 2013’s work were sponsored both by Washington River Protection Solutions and the U.S. Department of Energy’s Office of River Protection; because of this commonality, both sponsors’ work is summarized in this report. There were three tasks in this FY 2013 study. The first task involved examining the speciation of [(CO) 3Tc(H 2O) 3]more » + in alkaline solution by 99Tc nuclear magnetic resonance spectroscopy. The second task involved the purchase and installation of a microcalorimeter suitable to study the binding affinity of [(CO) 3Tc(H 2O) 3] + with various inorganic and organic compounds relevant to Hanford tank wastes, although the actual measure of such binding affinities is scheduled to occur in future FYs. The third task involved examining the chemical reactivity of [(CO) 3Tc(H 2O) 3] + as relevant to the development of a [(CO) 3Tc(H 2O) 3] + spectroelectrochemical sensor based on fluorescence spectroscopy.« less

Valine radiolysis by MeV ions

NASA Astrophysics Data System (ADS)

Da Silveira, Enio

2016-07-01

Valine, (CH3)2 CHCH (NH2) COOH, is a protein amino acid that has been identified in extraterrestrial environments and in the Murchison meteorite [1]. The knowledge of half-lives of small organic molecules under ionizing radiation is important for the setup of models describing the spread out of prebiotics across the Solar System or the Galaxy. We have investigated typical effects of MeV cosmic ray ions on prebiotic molecules in laboratory by impinging ions produced by the PUC-Rio Van de Graaff accelerator. Pure valine films, deposited by evaporation on KBr substrates, were irradiated by H ^{+}, He ^{+} and N ^{+} ion beams, from 0.5 to 1.5 MeV and up to a fluence of 10 ^{15} projectiles/cm ^{2}. The sample temperature was varied from 10 K to 300 K. The irradiation was interrupted several times for Mid-FTIR analysis of the sample. The main findings are: 1- The column density of the valine decreases exponentially with fluence. 2- In some cases, a second exponential appears in the beginning of irradiation; this feature has been attributed to sample compaction by the ion beam [2]. 3- Destruction cross sections of valine are in the 10 ^{-15} cm ^{2} range, while compaction cross sections are in the 10 ^{-14} cm ^{2} range. 4- Destruction cross section increases with the stopping power of the beam and also with the sample temperature. 5- Surprisingly, during the radiolysis of valine, just CO _{2} is seen by as a daughter molecule formed in the bulk. 6- After long beam fluence, also a CO peak appears in the infrared spectrum; this species is however interpreted as a fragment of the formed CO2 molecules. 7- Considering the flux ratio between laboratory experiments and actual galactic cosmic rays, half-life of valine is predicted for ISM conditions [3]. This work on pure valine is the first measurement of a series. New experiments are planned for determining cross sections of valine dissolved in H _{2}O or CO _{2}, inspired by the study performed for glycine [4]. [1] P. Ehrenfreund and S. B. Charnley, Annu. Rev. Astron. Astrophys. 2000. 38:427. [2] C. Mejía et al., Icarus 250 (2015) 222. [3] D. P. P. Andrade et al., Mon. Not. R. Astron. Soc. 430 (2013) 787. [4] P. A. Gerakines and R. L. Hudson, Icarus 252 (2015) 466. Acknowledgments. The agencies CNPq (INEspaço) and FAPERJ are acknowledged for partial support to this work.

Exceptional CO2 working capacity in a heterodiamine-grafted metal–organic framework† †Electronic supplementary information (ESI) available: Additional structural, sorption, TGA, and in situ IR data. See DOI: 10.1039/c5sc01191d

PubMed Central

Lee, Woo Ram; Jo, Hyuna; Yang, Li-Ming; Lee, Hanyeong; Ryu, Dae Won; Lim, Kwang Soo; Song, Jeong Hwa; Min, Da Young; Han, Sang Soo; Seo, Jeong Gil; Park, Yong Ki; Moon, Dohyun

2015-01-01

An amine-functionalized metal–organic framework (MOF), dmen-Mg2(dobpdc) (dmen = N,N-dimethylethylenediamine), which contains a heterodiamine with both primary and tertiary amines, was prepared via a post-synthetic method. This material exhibits a significant selectivity factor for CO2 over N2 that is commensurate with top-performing MOFs. It is remarkable that the solid is fully regenerated under vacuum or flowing Ar at low desorption temperatures, and following this can take up CO2 at more than 13 wt%. An exceptionally high working capacity is achieved at low regeneration temperatures and after exposure to humid conditions, which are important parameters for a real post-combustion CO2 capture process. PMID:28706716

Airborne Detection and Tracking of Geologic Leakage Sites

NASA Astrophysics Data System (ADS)

Jacob, Jamey; Allamraju, Rakshit; Axelrod, Allan; Brown, Calvin; Chowdhary, Girish; Mitchell, Taylor

2014-11-01

Safe storage of CO2 to reduce greenhouse gas emissions without adversely affecting energy use or hindering economic growth requires development of monitoring technology that is capable of validating storage permanence while ensuring the integrity of sequestration operations. Soil gas monitoring has difficulty accurately distinguishing gas flux signals related to leakage from those associated with meteorologically driven changes of soil moisture and temperature. Integrated ground and airborne monitoring systems are being deployed capable of directly detecting CO2 concentration in storage sites. Two complimentary approaches to detecting leaks in the carbon sequestration fields are presented. The first approach focuses on reducing the requisite network communication for fusing individual Gaussian Process (GP) CO2 sensing models into a global GP CO2 model. The GP fusion approach learns how to optimally allocate the static and mobile sensors. The second approach leverages a hierarchical GP-Sigmoidal Gaussian Cox Process for airborne predictive mission planning to optimally reducing the entropy of the global CO2 model. Results from the approaches will be presented.

Defined contribution health care: future direction or fantasy?

PubMed

Ostuw, R

2000-01-01

Will payers embrace defined contribution plans as an alternative to traditional health insurance or is this new approach a pipe dream? Are consumers truly ready to make informed decisions on purchasing their own health care? This article explores barriers to defined contribution health plans, including consumer reluctance to take ownership of buying insurance and a preference for the cost predictability of liberal coverage in employer-sponsored programs versus MSAs or higher co-payment arrangements. For the ultimate form of defined contribution health care to work, several tax and insurance barriers must be overcome. As a practical matter, the author argues that the current employer-sponsored approach is the most efficient system for large employers.

77 FR 68721 - Approval and Promulgation of Air Quality Implementation Plans; Maryland; Deferral for CO2

Federal Register 2010, 2011, 2012, 2013, 2014

2012-11-16

... Implementation Plan (SIP) that would incorporate EPA's ``Biomass Deferral'' into the Maryland SIP. At the request... comments. B. Email: cox[email protected] . C. Mail: EPA-R03-OAR-2012-0305, Ms. Kathleen Cox, Associate Director, Office of Permits and Air Toxics, Mailcode 3AP10, U.S. Environmental Protection Agency, Region...

Fuels planning: science synthesis and integration; environmental consequences fact sheet 05: prescriptions and fire effects

Treesearch

Melanie Miller

2004-01-01

Fuels planning: science synthesis and integration; environmental consequences fact sheet 5: prescriptions and fire effects. Miller, Melanie. 2004. Res. Note RMRS-RN-23-5-WWW. Fort Collins, CO: U.S. Department of Agriculture, Forest Service, Rocky Mountain Research Station. 2 p. While our understanding of the causes for variation in postfire effects is increasing, burn...

Development of Fly Ash-Based Sorbent to Capture CO2 from Flue Gas

NASA Astrophysics Data System (ADS)

Majchrzak-Kucęba, I.; Nowak, W.

In the present work the thermogravimetric characterization of the sorption of carbon dioxide on polymer-modifiedmesoporous materials (MCM-41) from fly ashes is described. In order to obtain MCM-41 materials from three different types fly ashes,(including CFB fly ash) hydrothermal processesusing the supernatantsof coal fly ashes and surfactantsas the structure-directing agents,have been carried out. The obtained mesoporous materials were subjected to polyethylenimine (PEI) modification by their impregnation to obtain samples with PEl contents of 30, 50 and 70%, respectively. CO2 sorption/desorption tests on loaded PEl samples were carried out in a flow of a mixture of gasses (CO2-1O%, O2-10%, N2-80%) at different temperatures: 25 and 75°C. The highest CO2 sorption value was obtained for the sample that contained the best-quality MCM-41 and was impregnatedwith PEI in the amount of 50%. This sample at a temperatureof 75°C can take CO2 in an amount equivalent to 111.7 mgCO2/g sample weight. Under the same conditions, but without PEI impregnation, this sample can take CO2 in an amount equivalent to 3.2 mgCO2/g sample weight, thus 35 times less. The research of CO2 adsorption on polymer-modified mesoporous materials from fly ashes carried out within this work has shown that these materials are characterized by high CO2 adsorption capacity under conditions typical of coal combustionboiler flue gas and have the chance of becoming an efficient adsorbent for application to post-combustion CO2 separation. For PEI impregnated samples, a different behaviour of adsorption/desorption profiles has also been observed (both sorption and desorptionprogressesvery rapidly).

Development of an advanced Two-Micron triple-pulse IPDA lidar for carbon dioxide and water vapor measurements

NASA Astrophysics Data System (ADS)

Petros, Mulugeta; Refaat, Tamer F.; Singh, Upendra N.; Yu, Jirong; Antill, Charles; Remus, Ruben; Taylor, Bryant D.; Wong, Teh-Hwa; Reithmaier, Karl; Lee, Jane; Ismail, Syed; Davis, Kenneth J.

2018-04-01

An advanced airborne triple-pulse 2-μm integrated path differential absorption (IPDA) lidar is under development at NASA Langley Research Center that targets both carbon dioxide (CO2) and water vapor (H2O) measurements simultaneously and independently. This lidar is an upgrade to the successfully demonstrated CO2 2-μm double-pulse IPDA. Upgrades include high-energy, highrepetition rate 2-μm triple-pulse laser transmitter, innovative wavelength control and advanced HgCdTe (MCT) electron-initiated avalanche photodiode detection system. Ground testing and airborne validation plans are presented.

Dependence of the radiative forcing of the climate system on fossil fuel type

NASA Astrophysics Data System (ADS)

Nunez, L. I.

2015-12-01

Climate change mitigation strategies are greatly directed towards the reduction of CO2 emissions and other greenhouse gases from fossil fuel combustion to limit warming to 2º C in this century. For example, the Clean Power Plan aims to reduce CO2 emissions from the power sector by 32% of 2005 levels by 2030 by increasing power plant efficiency but also by switching from coal-fired power plants to natural gas-fired power plants. It is important to understand the impact of such fuel switching on climate change. While all fossil fuels emit CO2, they also emit other pollutants with varying effects on climate, health and agriculture. First, The emission of CO2 per joule of energy produced varies significantly between coal, oil and natural gas. Second, the complexity that the co-emitted pollutants add to the perturbations in the climate system necessitates the detangling of radiative forcing for each type of fossil fuel. The historical (1850-2011) net radiative forcing of climate as a function of fuel type (coal, oil, natural gas and biofuel) is reconstructed. The results reveal the significant dependence of the CO2 and the non-CO2 forcing on fuel type. The CO2 forcing per joule of energy is largest for coal. Radiative forcing from the co-emitted pollutants (black carbon, methane, nitrogen oxides, organic carbon, sulfate aerosols) changes the global mean CO2 forcing attributed to coal and oil significantly. For natural gas, the CO2-only radiative forcing from gas is increased by about 60% when the co-emitted pollutants are included.

Early talk about the past revisited: affect in working-class and middle-class children's co-narrations.

PubMed

Burger, L K; Miller, P J

1999-02-01

This study contributes to our understanding of sociocultural variation in children's early storytelling by comparing co-narrations produced by children and their families from two European-American communities, one working-class and one middle-class. Six children from each community were observed in their homes at 2;6 and 3;0 years of age, yielding a corpus of nearly 400 naturally-occurring co-narrations of past experience. Analyses of generic properties, content, and emotion talk revealed a complex configuration of similarities and differences. Working-class and middle-class families produced co-narrations that were similar in referential/evaluative functions and temporal structure, with a preponderance of positive content. Working-class families produced twice as many co-narrations as their middle-class counterparts, produced more negative emotion talk, and used more dramatic language for conveying negative emotional experience. These findings suggest that (1) differentiation between working-class and middle-class communities in the content of early narratives may occur primarily with respect to negative experience and (2) researchers need to go beyond emotion state terms in order to accurately represent sociocultural variation in personal storytelling.

Leakage Risk Assessment for a Potential CO2 Storage Project in Saskatchewan, Canada

DOE Office of Scientific and Technical Information (OSTI.GOV)

Houseworth, J.E.; Oldenburg, C.M.; Mazzoldi, A.

2011-05-01

A CO{sub 2} sequestration project is being considered to (1) capture CO{sub 2} emissions from the Consumers Cooperative Refineries Limited at Regina, Saskatchewan and (2) geologically sequester the captured CO{sub 2} locally in a deep saline aquifer. This project is a collaboration of several industrial and governmental organizations, including the Petroleum Technology Research Centre (PTRC), Sustainable Development Technology Canada (SDTC), SaskEnvironment Go Green Fund, SaskPower, CCRL, Schlumberger Carbon Services, and Enbridge. The project objective is to sequester 600 tonnes CO{sub 2}/day. Injection is planned to start in 2012 or 2013 for a period of 25 years for a total storagemore » of approximately 5.5 million tonnes CO{sub 2}. This report presents an assessment of the leakage risk of the proposed project using a methodology known as the Certification Framework (CF). The CF is used for evaluating CO{sub 2} leakage risk associated with geologic carbon sequestration (GCS), as well as brine leakage risk owing to displacement and pressurization of brine by the injected CO{sub 2}. We follow the CF methodology by defining the entities (so-called Compartments) that could be impacted by CO{sub 2} leakage, the CO{sub 2} storage region, the potential for leakage along well and fault pathways, and the consequences of such leakage. An understanding of the likelihood and consequences of leakage forms the basis for understanding CO{sub 2} leakage risk, and forms the basis for recommendations of additional data collection and analysis to increase confidence in the risk assessment.« less

Earth Battery: An Approach for Reducing the Carbon and Water Intensity of Energy

NASA Astrophysics Data System (ADS)

Buscheck, T. A.; Bielicki, J. M.; Randolph, J.

2016-12-01

Mitigating climate change requires a range of measures, including increased use of renewable and low-carbon energy and reducing the CO2 intensity of fossil energy use. Our approach, called the Earth Battery, uses the storage of supercritical CO2, N2, or pressurized air to enable utility-scale energy storage needed for increased use of variable renewable energy and low-carbon baseload power. When deployed with CO2, the Earth Battery is designed to address the major deployment barriers to CO2 capture, utilization, and storage (CCUS) by managing overpressure and creating a business case for CO2 storage. We use the huge fluid and thermal storage capacity of the earth, together with overpressure driven by CO2, N2, or pressurized air storage, to harvest, store, and dispatch energy from subsurface (geothermal) and surface (solar, fossil) thermal resources, as well as excess energy from electric grids. The storage of CO2, N2, or air enables the earth to function as a low-carbon energy-system hub. Stored CO2, N2, or air plays three key roles: (1) as a supplemental fluid that creates pressure to efficiently recirculate working fluids that store and recover energy, (2) as a working fluid for efficient, low-water-intensity electricity conversion, and (3) as a shock absorber to allow diurnal and seasonal recharge/discharge cycles with minimal pressure oscillations, providing large pressure-storage capacity, with reduced risk of induced seismicity or leakage of stored CO2. To keep reservoir pressures in a safe range, a portion of the produced brine is diverted to generate water. Concentric rings of injection and production wells create a hydraulic divide to store pressure, CO2, N2/air, and thermal energy. Such storage can take excess power from the grid and excess thermal energy, and dispatch that energy when it is demanded. The system is pressurized and heated when power supply exceeds demand and depressurized when demand exceeds supply. The Earth Battery is designed for locations where a permeable geologic formation is overlain by an impermeable formation that constrains migration of buoyant CO2, N2/air, and heated brine. Such geologic conditions exist over half of the contiguous United States. This work was performed under the auspices of the USDOE by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

Equilibrium model analysis of waste plastics gasification using CO2 and steam.

PubMed

Kannan, P; Lakshmanan, G; Al Shoaibi, A; Srinivasakannan, C

2017-12-01

Utilization of carbon dioxide (CO 2 ) in thermochemical treatment of waste plastics may significantly help to improve CO 2 recycling, thus simultaneously curtailing dioxins/furans and CO 2 emissions. Although CO 2 is not such an effective gasifying agent as steam, a few investigations have explored the utilization of CO 2 in conjunction with steam to achieve somewhat higher carbon conversion. This work presents a comparative evaluation study of CO 2 and steam gasification of a typical post-consumer waste plastics mixture using an Aspen Plus equilibrium model. The effect of flow rate of gasifying medium (CO 2 and/or steam) and gasification temperature on product gas composition, carbon conversion, and cold gas efficiency has been analyzed. Simulation results demonstrate that CO 2 can serve as a potential gasifying agent for waste plastics gasification. The resulting product gas was rich in CO whereas CO 2 -steam blends yield a wider H 2 /CO ratio, thus extending the applications of the product gas.

Weekend effect of O3, NO, NO2, CO and PM10 concentrations in the south of Spain during 2003-2008

NASA Astrophysics Data System (ADS)

Adame Carnero, Jose Antonio; Lozano, Antonio; Sorribas, Mar; Contreras, Juan; Ángel Hernández-Ceballos, Miguel; Godoy, Francisca; Fernández-León, Mercedes; Bolívar, Juan Pedro; de La Morena, Benito A.

2010-05-01

The weekly evolutions and the difference between labour and non-labour days for O3, NO, NO2, CO and PM10 concentrations have been analysed in the south of Spain (Andalusia). The hourly data have been collected in 70 stations (urban, suburban and rural) belong to the Air Quality Network of Andalusia. The data period used was 2003-2008. The study has been focused in order to identify the weekend effect for those pollutants. The weekly patterns has been evaluated using daily mean of O3 and CO and 90th percentile daily values of NO, NO2 and PM10. The mean daily ozone concentrations show similar values during the week days with a maximum increase of the concentrations during weekend days of 5 ?g m-3 in urban stations. The NO and NO2 levels present in general a decrease of 90th percentile daily values during weekend days. The maximum decrease observed was of 50 and 25 ?g m-3 for NO and NO2 respectively. The most of stations show similar concentrations for the mean daily CO levels during the week. In the event of PM10 while some stations present an increase of the concentrations during the weekdays others have similar values during all days with 90th percentile of 45 ?g m-3. The daily pollutants variation between week and weekend days has been evaluated from the hourly differences between weekend and week concentrations. The ozone daily evolution show negative differences from 00:00 to 5:00 local time (LT) while during the rest of the day the differences are positives. The maximum differences were registered early in the morning ranging between 4 ?g m-3 for rural stations to 14 ?g m-3 for urban stations. The NO and NO2 show positive differences between 00:00 to 7:00 (LT) with negative values within the next hours. The higher differences could reach 80 ?g m-3 for NO and 25 ?g m-3 for NO2, both in urban stations, with values lower than 10 ?g m-3and 5 ?g m-3 in suburban and rural stations respectively. The CO daily evolution show similar values in week and weekend days. The behaviour of the PM10 daily differences is similar to the observed for NO and NO2, with higher differences between 10:00 to 14:00 and values between 5 to 20 ?g m-3. The results obtained in this work point out a weak or absence for weekend effect of O3 and CO concentrations over the study area. Nevertheless, for NO, NO2 and PM10 concentrations present a decrease during the weekend. This phenomenon has been observed with more intensity over the metropolitan areas, mainly in urban stations. The results obtained in this study are being used to define the air quality plans in the south of Spain. These plans will start to apply during 2010 with the purpose to reduce the levels of these air pollutants in Andalusia.

Predicting CO2 Solubility in Imidazole Ionic Liquids for Use in Absorption Refrigeration Systems by Using the Group Contribution Equation of State Method

NASA Astrophysics Data System (ADS)

Wu, Wei-Dong; Wu, Jun; Hou, Yong; Su, Lin; Zhang, Hua

2017-09-01

Traditional absorption refrigeration such as H2O-LiBr- and NH3-H2O-based refrigeration has limited applications because of several issues, including crystallization, corrosion, and large volume. CO2-ionic liquids (ILs) as new absorption working pairs were investigated in this study. The objective was to use the group contribution equation of state (GC-EOS) method to predict the solubilities of binary systems containing high-pressure CO2-imidazole bis(trifluoromethanesulfonimide) ILs and to investigate the applicability and accuracy of the GC-EOS model. The results showed that at pressures up to 11.0 MPa and temperatures of 273 K to 400 K, the CO2 solubility in the ILs increased with increasing system pressure but decreased with increasing temperature, and its variation rate was lower at higher pressures or temperatures. Also, CO2 solubility increased in the order of [emim][Tf2N] < [bmim][Tf2N] < [hmim][Tf2N] < [omim][Tf2N], indicating that longer alkyl chains of identical IL families resulted in higher CO_{2 } solubility. The model prediction of CO2 solubility in the four different ILs showed reasonable consistency with the corresponding experimental results from the literature; the largest deviation was 5.7 % for CO2-[emim][Tf2N]. Therefore, it can be concluded that the GC-EOS model is a promising theoretical solution that can be used to search for suitable CO2-IL working pairs for absorption refrigeration systems.

Observation of ferromagnetic ordering in a stable α -Co (OH) 2 phase grown on a Mo S2 surface

NASA Astrophysics Data System (ADS)

Debnath, Anup; Bhattacharya, Shatabda; Saha, Shyamal K.

2017-12-01

Because of the potential application of Co (OH) 2 in a magnetic cooling system as a result of its superior magnetocaloric effect many people have investigated magnetic properties of Co (OH) 2 . Unfortunately, most of the works have been carried out on the β -Co (OH) 2 phase due to the fact that the α -Co (OH) 2 phase is very unstable and continuously transformed into the stable β -Co (OH) 2 phase. However, in the present work, using a Mo S2 sheet as a two-dimensional template, we have been able to synthesize a stable α -Co (OH) 2 phase in addition to a β -Co (OH) 2 phase by varying the layer thickness. It is seen that for thinner samples the β phase, while for thicker samples α phase, is grown on the Mo S2 surface. Magnetic measurements are carried out for the samples over the temperature range from 2 to 300 K and it is seen that for the β phase, ferromagnetic ordering with fairly large coercivity (1271 Oe) at 2 K is obtained instead of the usual antiferromagnetism. The most interesting result is the observation of ferromagnetic ordering with a transition temperature (Curie temperature) more than 100 K in the α -Co (OH) 2 phase. Complete saturation in the hysteresis curve under application of very low field having coercivity of ˜162 Oe at 2 K and 60 Oe at 50 K is obtained. A thin stable α -Co (OH) 2 phase grown on Mo S2 surface with very soft ferromagnetic ordering will be very useful as the core material in electromagnets.

Site systems engineering fiscal year 1999 multi-year work plan (MYWP) update for WBS 1.8.2.2

DOE Office of Scientific and Technical Information (OSTI.GOV)

GRYGIEL, M.L.

1998-10-08

Manage the Site Systems Engineering process to provide a traceable integrated requirements-driven, and technically defensible baseline. Through the Site Integration Group(SIG), Systems Engineering ensures integration of technical activities across all site projects. Systems Engineering's primary interfaces are with the RL Project Managers, the Project Direction Office and with the Project Major Subcontractors, as well as with the Site Planning organization. Systems Implementation: (1) Develops, maintains, and controls the site integrated technical baseline, ensures the Systems Engineering interfaces between projects are documented, and maintain the Site Environmental Management Specification. (2) Develops and uses dynamic simulation models for verification of the baselinemore » and analysis of alternatives. (3) Performs and documents fictional and requirements analyses. (4) Works with projects, technology management, and the SIG to identify and resolve technical issues. (5) Supports technical baseline information for the planning and budgeting of the Accelerated Cleanup Plan, Multi-Year Work Plans, Project Baseline Summaries as well as performance measure reporting. (6) Works with projects to ensure the quality of data in the technical baseline. (7) Develops, maintains and implements the site configuration management system.« less

Isolation of anacardic acid from natural cashew nut shell liquid (CNSL) using supercritical carbon dioxide.

PubMed

Philip, Joseph Y N; Da Cruz Francisco, José; Dey, Estera S; Buchweishaija, Joseph; Mkayula, Lupituko L; Ye, Lei

2008-10-22

Solvent extracted cashew nut shell liquid (CNSL), conventionally known as natural CNSL, is a mixture of several alkenyl phenols. One of these alkenyl phenols is anacardic acid, which is present at the highest concentration. In view of anticipated industrial applications of anacardic acid, the objective of this work was to isolate anacardic acid from natural CNSL by supercritical carbon dioxide (scCO 2). In this study, the solubility data for natural CNSL in scCO 2 under a range of operating conditions of pressure (100, 200, and 300 bar), temperature (40 and 50 degrees C), and CO 2 flow rate (5, 10, and 15 g min (-1)) were established. The best scCO 2 working conditions were found to be 50 degrees C and 300 bar at a flow rate of 5 g min (-1) CO 2. Using 3 g of sample (CNSL/solid adsorbent = 1/2) under these scCO 2 conditions, it was possible to quantitatively isolate high purity anacardic acid from crude natural CNSL (82% of total anacardic acid) within 150 min. The anacardic acid isolated by scCO 2 was analyzed by different spectroscopic techniques (UV-vis, FT-IR, and (1)H NMR) and HPLC analysis, indicating that the anacardic acid isolated by scCO 2 has better quality than that obtained through a conventional method involving several chemical conversion steps.

An Analysis of Costs and Health Co-Benefits for a U.S. Power Plant Carbon Standard

PubMed Central

Buonocore, Jonathan J.; Lambert, Kathleen F.; Burtraw, Dallas; Sekar, Samantha; Driscoll, Charles T.

2016-01-01

Reducing carbon dioxide (CO2) emissions from power plants can have important “co-benefits” for public health by reducing emissions of air pollutants. Here, we examine the costs and health co-benefits, in monetary terms, for a policy that resembles the U.S. Environmental Protection Agency’s Clean Power Plan. We then examine the spatial distribution of the co-benefits and costs, and the implications of a range of cost assumptions in the implementation year of 2020. Nationwide, the total health co-benefits were $29 billion 2010 USD (95% CI: $2.3 to $68 billion), and net co-benefits under our central cost case were $12 billion (95% CI: -$15 billion to $51 billion). Net co-benefits for this case in the implementation year were positive in 10 of the 14 regions studied. The results for our central case suggest that all but one region should experience positive net benefits within 5 years after implementation. PMID:27270222

An Analysis of Costs and Health Co-Benefits for a U.S. Power Plant Carbon Standard.

PubMed

Buonocore, Jonathan J; Lambert, Kathleen F; Burtraw, Dallas; Sekar, Samantha; Driscoll, Charles T

2016-01-01

Reducing carbon dioxide (CO2) emissions from power plants can have important "co-benefits" for public health by reducing emissions of air pollutants. Here, we examine the costs and health co-benefits, in monetary terms, for a policy that resembles the U.S. Environmental Protection Agency's Clean Power Plan. We then examine the spatial distribution of the co-benefits and costs, and the implications of a range of cost assumptions in the implementation year of 2020. Nationwide, the total health co-benefits were $29 billion 2010 USD (95% CI: $2.3 to $68 billion), and net co-benefits under our central cost case were $12 billion (95% CI: -$15 billion to $51 billion). Net co-benefits for this case in the implementation year were positive in 10 of the 14 regions studied. The results for our central case suggest that all but one region should experience positive net benefits within 5 years after implementation.

Development of a CO2 releasing co-formulation 1 based on starch, Saccharomyces cerevisiae and Beauveria bassiana attractive towards western corn rootworm larvae

USDA-ARS?s Scientific Manuscript database

CO2 is known as an attractant for many soil-dwelling pests. To implement an attract-and-kill strategy for soil pest control, CO2 emitting formulations need to be developed. This work aimed at the development of a slow release bead system in order to bridge the gap between application and hatching of...

Knowledge Co-production at the Research-Practice Interface: Embedded Case Studies from Urban Forestry.

PubMed

Campbell, Lindsay K; Svendsen, Erika S; Roman, Lara A

2016-06-01

Cities are increasingly engaging in sustainability efforts and investment in green infrastructure, including large-scale urban tree planting campaigns. In this context, researchers and practitioners are working jointly to develop applicable knowledge for planning and managing the urban forest. This paper presents three case studies of knowledge co-production in the field of urban forestry in the United States. These cases were selected to span a range of geographic scales and topical scopes; all three are examples of urban researcher-practitioner networks in which the authors are situated to comment on reflexively. The three cases resemble institutional structures described in the knowledge co-production literature, including participatory research, a hybrid organization of scientists and managers, and a community of practice. We find that trust, embeddedness, new approaches by both practitioners and researchers, and blending of roles all serve to recognize multiple forms of capability, expertise, and ways of knowing. We discuss the impacts of knowledge co-production and the ways in which hybrid institutional forms can enable its occurrence.

Knowledge Co-production at the Research-Practice Interface: Embedded Case Studies from Urban Forestry

NASA Astrophysics Data System (ADS)

Campbell, Lindsay K.; Svendsen, Erika S.; Roman, Lara A.

2016-06-01

Cities are increasingly engaging in sustainability efforts and investment in green infrastructure, including large-scale urban tree planting campaigns. In this context, researchers and practitioners are working jointly to develop applicable knowledge for planning and managing the urban forest. This paper presents three case studies of knowledge co-production in the field of urban forestry in the United States. These cases were selected to span a range of geographic scales and topical scopes; all three are examples of urban researcher-practitioner networks in which the authors are situated to comment on reflexively. The three cases resemble institutional structures described in the knowledge co-production literature, including participatory research, a hybrid organization of scientists and managers, and a community of practice. We find that trust, embeddedness, new approaches by both practitioners and researchers, and blending of roles all serve to recognize multiple forms of capability, expertise, and ways of knowing. We discuss the impacts of knowledge co-production and the ways in which hybrid institutional forms can enable its occurrence.

Modeling CO 2 ice clouds with a Mars Global Climate Model

NASA Astrophysics Data System (ADS)

Audouard, Joachim; Määttänen, Anni; Listowski, Constantino; Millour, Ehouarn; Forget, Francois; Spiga, Aymeric

2016-10-01

Since the first claimed detection of CO2 ice clouds by the Mariner campaign (Herr and Pimentel, 1970), more recent observations and modelling works have put new constraints concerning their altitude, region, time and mechanisms of formation (Clancy and Sandor, 1998; Montmessin et al., 2007; Colaprete et al., 2008; Määttänen et al., 2010; Vincendon et al., 2011; Spiga et al. 2012; Listowski et al. 2014). CO2 clouds are observed at the poles at low altitudes (< 20 km) during the winter and at high altitudes (60-110 km) in the equatorial regions during the first half of the year. However, Martian CO2 clouds's variability and dynamics remain somehow elusive.Towards an understanding of Martian CO2 clouds and especially of their precise radiative impact on the climate throughout the history of the planet, including their formation and evolution in a Global Climate Model (GCM) is necessary.Adapting the CO2 clouds microphysics modeling work of Listowski et al. (2013; 2014), we aim at implementing a complete CO2 clouds scheme in the GCM of the Laboratoire de Météorologie Dynamique (LMD, Forget et al., 1999). It covers CO2 microphysics, growth, evolution and dynamics with a methodology inspired from the water ice clouds scheme recently included in the LMD GCM (Navarro et al., 2014).Two main factors control the formation and evolution of CO2 clouds in the Martian atmosphere: sufficient supersaturation of CO2 is needed and condensation nuclei must be available. Topography-induced gravity-waves (GW) are expected to propagate to the upper atmosphere where they produce cold pockets of supersaturated CO2 (Spiga et al., 2012), thus allowing the formation of clouds provided enough condensation nuclei are present. Such supersaturations have been observed by various instruments, in situ (Schofield et al., 1997) and from orbit (Montmessin et al., 2006, 2011; Forget et al., 2009).Using a GW-induced temperature profile and the 1-D version of the GCM, we simulate the formation of CO2 clouds in the mesosphere and investigate the sensitivity of our microphysics scheme. First results and steps towards the integration in the 3-D GCM will be presented and discussed at the conference.This work is funded by the Laboratory of Excellence ESEP.

Evaluation of a co-delivered training package for community mental health professionals on service user- and carer-involved care planning.

PubMed

Grundy, A C; Walker, L; Meade, O; Fraser, C; Cree, L; Bee, P; Lovell, K; Callaghan, P

2017-08-01

WHAT IS KNOWN ON THE SUBJECT?: There is consistent evidence that service users and carers feel marginalized in the process of mental health care planning. Mental health professionals have identified ongoing training needs in relation to involving service users and carers in care planning. There is limited research on the acceptability of training packages for mental health professionals which involve service users and carers as co-facilitators. WHAT DOES THIS PAPER ADD TO EXISTING KNOWLEDGE?: A co-produced and co-delivered training package on service user- and carer-involved care planning was acceptable to mental health professionals. Aspects of the training that were particularly valued were the co-production model, small group discussion and the opportunity for reflective practice. The organizational context of care planning may need more consideration in future training models. WHAT ARE THE IMPLICATIONS FOR PRACTICE?: Mental health nurses using co-production models of delivering training to other mental health professionals can be confident that such initiatives will be warmly welcomed, acceptable and engaging. On the basis of the results reported here, we encourage mental health nurses to use co-production approaches more often. Further research will show how clinically effective this training is in improving outcomes for service users and carers. Background There is limited evidence for the acceptability of training for mental health professionals on service user- and carer-involved care planning. Aim To investigate the acceptability of a co-delivered, two-day training intervention on service user- and carer-involved care planning. Methods Community mental health professionals were invited to complete the Training Acceptability Rating Scale post-training. Responses to the quantitative items were summarized using descriptive statistics (Miles, ), and qualitative responses were coded using content analysis (Weber, ). Results Of 350 trainees, 310 completed the questionnaire. The trainees rated the training favourably (median overall TARS scores = 56/63; median 'acceptability' score = 34/36; median 'perceived impact' score = 22/27). There were six qualitative themes: the value of the co-production model; time to reflect on practice; delivery preferences; comprehensiveness of content; need to consider organizational context; and emotional response. Discussion The training was found to be acceptable and comprehensive with participants valuing the co-production model. Individual differences were apparent in terms of delivery preferences and emotional reactions. There may be a need to further address the organizational context of care planning in future training. Implications for practice Mental health nurses should use co-production models of continuing professional development training that involve service users and carers as co-facilitators. © 2017 The Authors. Journal of Psychiatric and Mental Health Nursing Published by John Wiley & Sons Ltd.

Health working with industry to promote fruit and vegetables: a case study of the Western Australian Fruit and Vegetable Campaign with reflection on effectiveness of inter-sectoral action.

PubMed

Miller, Margaret; Pollard, Christina

2005-04-01

In 1990, the Department of Health in Western Australia (DOH) initiated a five-year campaign to increase awareness of the need to eat more fruit and vegetables and to encourage increased consumption. This paper describes aspects of the campaign and reviews the strengths and weaknesses of health and fruit and vegetable industry alliances to extend and sustain the campaign. The fruit and vegetable industry was engaged through information sharing, consultation, working groups and joint promotions. The partnership was examined in terms of six inter-sectoral action dimensions (necessity; opportunity and capacity to work together; established relationships for goal achievement; degree of planning; potential for evaluation; and sustainability of action). There were both need and opportunity for each sector to work together. Health had commitment, expertise and resources to plan, implement and evaluate the campaign. Industry had established channels of communication within the supply chain. Sustained health sector presence provided incentive, endorsement and policy direction. Resources and infrastructure limited partnership sustainability. Greatest potential for success occurred when participants' contributions were closely aligned to their core business and there was a body responsible for co-ordinating action.

CO2-Switchable Membranes Prepared by Immobilization of CO2-Breathing Microgels.

PubMed

Zhang, Qi; Wang, Zhenwu; Lei, Lei; Tang, Jun; Wang, Jianli; Zhu, Shiping

2017-12-20

Herein, we report the development of a novel CO 2 -responsive membrane system through immobilization of CO 2 -responsive microgels into commercially available microfiltration membranes using a method of dynamic adsorption. The microgels, prepared from soap-free emulsion polymerization of CO 2 -responsive monomer 2-(diethylamino)ethyl methacrylate (DEA), can be reversibly expanded and shrunken upon CO 2 /N 2 alternation. When incorporated into the membranes, this switching behavior was preserved and further led to transformation between microfiltration and ultrafiltration membranes, as indicated from the dramatic changes on water flux and BSA rejection results. This CO 2 -regulated performance switching of membranes was caused by the changes of water transportation channel, as revealed from the dynamic water contact angle tests and SEM observation. This work represents a simple yet versatile strategy for making CO 2 -responsive membranes.

Prescriptions and Insurance Plans

MedlinePlus

... drugs $ Level 2 Preferred $$ Level 3 Non-preferred brand-name drugs $$$ The more dollar signs in the ... co-pay amount. What’s the difference between a brand-name drug and a generic drug? When a ...

A treatment planning comparison between modulated tri-cobalt-60 teletherapy and linear accelerator-based stereotactic body radiotherapy for central early-stage non-small cell lung cancer.

PubMed

Merna, Catherine; Rwigema, Jean-Claude M; Cao, Minsong; Wang, Pin-Chieh; Kishan, Amar U; Michailian, Argin; Lamb, James; Sheng, Ke; Agazaryan, Nzhde; Low, Daniel A; Kupelian, Patrick; Steinberg, Michael L; Lee, Percy

2016-01-01

We evaluated the feasibility of planning stereotactic body radiotherapy (SBRT) for large central early-stage non-small cell lung cancer with a tri-cobalt-60 (tri-(60)Co) system equipped with real-time magnetic resonance imaging (MRI) guidance, as compared to linear accelerator (LINAC)-based SBRT. In all, 20 patients with large central early-stage non-small cell lung cancer who were treated between 2010 and 2015 with LINAC-based SBRT were replanned using a tri-(60)Co system for a prescription dose of 50Gy in 4 fractions. Doses to organs at risk were evaluated based on established MD Anderson constraints for central lung SBRT. R100 values were calculated as the total tissue volume receiving 100% of the dose (V100) divided by the planning target volume and compared to assess dose conformity. Dosimetric comparisons between LINAC-based and tri-(60)Co SBRT plans were performed using Student׳s t-test and Wilcoxon Ranks test. Blinded reviews by radiation oncologists were performed to assess the suitability of both plans for clinical delivery. The mean planning target volume was 48.3cc (range: 12.1 to 139.4cc). Of the tri-(60)Co SBRT plans, a mean 97.4% of dosimetric parameters per patient met MD Anderson dose constraints, whereas a mean 98.8% of dosimetric parameters per patient were met with LINAC-based SBRT planning (p = 0.056). R100 values were similar between both plans (1.20 vs 1.21, p = 0.79). Upon blinded review by 4 radiation oncologists, an average of 90% of the tri-(60)Co SBRT plans were considered acceptable for clinical delivery compared with 100% of the corresponding LINAC-based SBRT plans (p = 0.17). SBRT planning using the tri-(60)Co system with built-in MRI is feasible and achieves clinically acceptable plans for most central lung patients, with similar target dose conformity and organ at risk dosimetry. The added benefit of real-time MRI-guided therapy may further optimize tumor targeting while improving normal tissue sparing, which warrants further investigation in a prospective feasibility clinical trial. Copyright © 2016 American Association of Medical Dosimetrists. Published by Elsevier Inc. All rights reserved.

A treatment planning comparison between modulated tri-cobalt-60 teletherapy and linear accelerator–based stereotactic body radiotherapy for central early-stage non−small cell lung cancer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Merna, Catherine; Rwigema, Jean-Claude M.; Cao, Minsong

We evaluated the feasibility of planning stereotactic body radiotherapy (SBRT) for large central early-stage non−small cell lung cancer with a tri-cobalt-60 (tri-{sup 60}Co) system equipped with real-time magnetic resonance imaging (MRI) guidance, as compared to linear accelerator (LINAC)–based SBRT. In all, 20 patients with large central early-stage non−small cell lung cancer who were treated between 2010 and 2015 with LINAC-based SBRT were replanned using a tri-{sup 60}Co system for a prescription dose of 50 Gy in 4 fractions. Doses to organs at risk were evaluated based on established MD Anderson constraints for central lung SBRT. R{sub 100} values were calculatedmore » as the total tissue volume receiving 100% of the dose (V{sub 100}) divided by the planning target volume and compared to assess dose conformity. Dosimetric comparisons between LINAC-based and tri-{sup 60}Co SBRT plans were performed using Student's t-test and Wilcoxon Ranks test. Blinded reviews by radiation oncologists were performed to assess the suitability of both plans for clinical delivery. The mean planning target volume was 48.3 cc (range: 12.1 to 139.4 cc). Of the tri-{sup 60}Co SBRT plans, a mean 97.4% of dosimetric parameters per patient met MD Anderson dose constraints, whereas a mean 98.8% of dosimetric parameters per patient were met with LINAC-based SBRT planning (p = 0.056). R{sub 100} values were similar between both plans (1.20 vs 1.21, p = 0.79). Upon blinded review by 4 radiation oncologists, an average of 90% of the tri-{sup 60}Co SBRT plans were considered acceptable for clinical delivery compared with 100% of the corresponding LINAC-based SBRT plans (p = 0.17). SBRT planning using the tri-{sup 60}Co system with built-in MRI is feasible and achieves clinically acceptable plans for most central lung patients, with similar target dose conformity and organ at risk dosimetry. The added benefit of real-time MRI-guided therapy may further optimize tumor targeting while improving normal tissue sparing, which warrants further investigation in a prospective feasibility clinical trial.« less

Energy performance of stripper configurations for CO{sub 2} capture by aqueous amines

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oyenekan, B.A.; Rochelle, G.T.

2006-04-12

Aqueous absorption/stripping is the state-of-the-art technology for the capture of CO{sub 2} from coal-fired power plants. This technology is energy-intensive and has been applied to CO{sub 2} removal from natural gas, ammonia, and hydrogen gas streams. Energy requirements can be reduced by the use of a more-reactive solvent, operating the cross exchanger at a lower temperature, optimizing the stripper operation, and using innovative stripper configurations (vacuum and multipressure). This work calculates stripper performance with an algorithm in Aspen Custom Modeler (ACM) that incorporates thermodynamic studies, reaction rate measurements, physical properties, and contactor-specific information for three stripper configuration-a simple stripper operatingmore » at 160 kPa, a multipressure stripper operating at three pressures (330/230/160 kPa), and a vacuum stripper (30 kPa) for two solvents: 7m (30 wt %) monoethanolamine (MEA) and 5m K{sup +}/2.5m piperazine. The temperature approach is varied from 5 to 10{sup o}C. With some approximations, we predict the influence of using solvents with varying heats of desorption {Delta}H{sub des}) on the reboiler duty and the equivalent work for stripping (reboiler duty as equivalent Carnot work plus compression work). With a rich solution giving PCO{sub 2}{asterisk} = 2.5 kPa at 40{sup o}C, the vacuum stripper is favored for solvents with Delta H{sub des} {<=} 21 kcal/(gmol of CO{sub 2}) while the multipressure configuration is attractive for solvents with {Delta}(H{sub des} {>=} 21 kcal/(gmol of CO{sub 2}).« less

Enhancement of SOFC Cathode Electrochemical Performance Using Multi-Phase Interfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Morgan, Dane

2015-09-30

This work explored the use of oxide heterostructures for enhancing the catalytic and degradation properties of solid oxide fuel cell (SOFC) cathode electrodes. We focused on heterostructures of Ruddlesden-Popper and perovskite phases. Building on previous work showing enhancement of the Ruddlesden-Popper (La,Sr) 2CoO 4 / perovskite (La,Sr)CoO 3 heterostructure compared to pure (La,Sr)CoO 3 we explored the application of related heterostructures of Ruddlesden-Popper phases on perovskite (La,Sr)(Co,Fe)O 3. Our approaches included thin-film electrodes, physical and electrochemical characterization, elementary reaction kinetics modeling, and ab initio simulations. We demonstrated that Sr segregation to surfaces is likely playing a critical role in themore » performance of (La,Sr)CoO 3 and (La,Sr)(Co,Fe)O 3 and that modification of this Sr segregation may be the mechanism by which Ruddlesden-Popper coatings enhance performances. We determined that (La,Sr)(Co,Fe)O 3 could be enhanced in thin films by about 10× by forming a heterostructure simultaneously with (La,Sr) 2CoO 4 and (La,Sr)CoO 3. We hope that future work will develop this heterostructure for use as a bulk porous electrode.« less

Microbial potential for carbon and nutrient cycling in a geogenic supercritical carbon dioxide reservoir

PubMed Central

Freedman, Adam J.E.; Tan, BoonFei

2017-01-01

Summary Microorganisms catalyze carbon cycling and biogeochemical reactions in the deep subsurface and thus may be expected to influence the fate of injected supercritical (sc) CO2 following geological carbon sequestration (GCS). We hypothesized that natural subsurface scCO2 reservoirs, which serve as analogs for the long‐term fate of sequestered scCO2, harbor a ‘deep carbonated biosphere’ with carbon cycling potential. We sampled subsurface fluids from scCO2‐water separators at a natural scCO2 reservoir at McElmo Dome, Colorado for analysis of 16S rRNA gene diversity and metagenome content. Sequence annotations indicated dominance of Sulfurospirillum, Rhizobium, Desulfovibrio and four members of the Clostridiales family. Genomes extracted from metagenomes using homology and compositional approaches revealed diverse mechanisms for growth and nutrient cycling, including pathways for CO2 and N2 fixation, anaerobic respiration, sulfur oxidation, fermentation and potential for metabolic syntrophy. Differences in biogeochemical potential between two production well communities were consistent with differences in fluid chemical profiles, suggesting a potential link between microbial activity and geochemistry. The existence of a microbial ecosystem associated with the McElmo Dome scCO2 reservoir indicates that potential impacts of the deep biosphere on CO2 fate and transport should be taken into consideration as a component of GCS planning and modelling. PMID:28229521

Microbial potential for carbon and nutrient cycling in a geogenic supercritical carbon dioxide reservoir: Microbial life in the deep carbonated biosphere

DOE Office of Scientific and Technical Information (OSTI.GOV)

Freedman, Adam J. E.; Tan, BoonFei; Thompson, Janelle R.

Microorganisms catalyze carbon cycling and biogeochemical reactions in the deep subsurface and thus may be expected to influence the fate of injected super-critical (sc) CO 2 following geological carbon sequestration (GCS). We hypothesized that natural subsurface scCO 2 reservoirs, which serve as analogs for the long-term fate of sequestered scCO 2 harbor a ‘deep carbonated biosphere’ with carbon cycling potential. We sampled subsurface fluids from scCO 2- water separators at a natural scCO 2 reservoir at McElmo Dome, Colorado for analysis of 16S rRNA gene diversity and metagenome content. Sequence annotations indicated dominance of Sulfurospirillum, Rhizobium, Desulfovibrio and four membersmore » of the Clostridiales family. Genomes extracted from metagenomes using homology and compositional approaches revealed diverse mechanisms for growth and nutrient cycling, including pathways for CO 2 and N 2 fixation, anaerobic respiration, sulfur oxidation, fermentation and potential for metabolic syntrophy. Differences in biogeochemical potential between two production well communities were consistent with differences in fluid chemical profiles, suggesting a potential link between microbial activity and geochemistry. In conclusion, the existence of a microbial ecosystem associated with the McElmo Dome scCO 2 reservoir indicates that potential impacts of the deep biosphere on CO 2 fate and transport should be taken into consideration as a component of GCS planning and modelling.« less

Microbial potential for carbon and nutrient cycling in a geogenic supercritical carbon dioxide reservoir: Microbial life in the deep carbonated biosphere

DOE PAGES

Freedman, Adam J. E.; Tan, BoonFei; Thompson, Janelle R.

2017-05-02

Microorganisms catalyze carbon cycling and biogeochemical reactions in the deep subsurface and thus may be expected to influence the fate of injected super-critical (sc) CO 2 following geological carbon sequestration (GCS). We hypothesized that natural subsurface scCO 2 reservoirs, which serve as analogs for the long-term fate of sequestered scCO 2 harbor a ‘deep carbonated biosphere’ with carbon cycling potential. We sampled subsurface fluids from scCO 2- water separators at a natural scCO 2 reservoir at McElmo Dome, Colorado for analysis of 16S rRNA gene diversity and metagenome content. Sequence annotations indicated dominance of Sulfurospirillum, Rhizobium, Desulfovibrio and four membersmore » of the Clostridiales family. Genomes extracted from metagenomes using homology and compositional approaches revealed diverse mechanisms for growth and nutrient cycling, including pathways for CO 2 and N 2 fixation, anaerobic respiration, sulfur oxidation, fermentation and potential for metabolic syntrophy. Differences in biogeochemical potential between two production well communities were consistent with differences in fluid chemical profiles, suggesting a potential link between microbial activity and geochemistry. In conclusion, the existence of a microbial ecosystem associated with the McElmo Dome scCO 2 reservoir indicates that potential impacts of the deep biosphere on CO 2 fate and transport should be taken into consideration as a component of GCS planning and modelling.« less

Reducing the cost of Ca-based direct air capture of CO2.

PubMed

Zeman, Frank

2014-10-07

Direct air capture, the chemical removal of CO2 directly from the atmosphere, may play a role in mitigating future climate risk or form the basis of a sustainable transportation infrastructure. The current discussion is centered on the estimated cost of the technology and its link to "overshoot" trajectories, where atmospheric CO2 levels are actively reduced later in the century. The American Physical Society (APS) published a report, later updated, estimating the cost of a one million tonne CO2 per year air capture facility constructed today that highlights several fundamental concepts of chemical air capture. These fundamentals are viewed through the lens of a chemical process that cycles between removing CO2 from the air and releasing the absorbed CO2 in concentrated form. This work builds on the APS report to investigate the effect of modifications to the air capture system based on suggestions in the report and subsequent publications. The work shows that reduced carbon electricity and plastic packing materials (for the contactor) may have significant effects on the overall price, reducing the APS estimate from $610 to $309/tCO2 avoided. Such a reduction does not challenge postcombustion capture from point sources, estimated at $80/tCO2, but does make air capture a feasible alternative for the transportation sector and a potential negative emissions technology. Furthermore, air capture represents atmospheric reductions rather than simply avoided emissions.

Embedding covalency into metal catalysts for efficient electrochemical conversion of CO2.

PubMed

Lim, Hyung-Kyu; Shin, Hyeyoung; Goddard, William A; Hwang, Yun Jeong; Min, Byoung Koun; Kim, Hyungjun

2014-08-13

CO2 conversion is an essential technology to develop a sustainable carbon economy for the present and the future. Many studies have focused extensively on the electrochemical conversion of CO2 into various useful chemicals. However, there is not yet a solution of sufficiently high enough efficiency and stability to demonstrate practical applicability. In this work, we use first-principles-based high-throughput screening to propose silver-based catalysts for efficient electrochemical reduction of CO2 to CO while decreasing the overpotential by 0.4-0.5 V. We discovered the covalency-aided electrochemical reaction (CAER) mechanism in which p-block dopants have a major effect on the modulating reaction energetics by imposing partial covalency into the metal catalysts, thereby enhancing their catalytic activity well beyond modulations arising from d-block dopants. In particular, sulfur or arsenic doping can effectively minimize the overpotential with good structural and electrochemical stability. We expect this work to provide useful insights to guide the development of a feasible strategy to overcome the limitations of current technology for electrochemical CO2 conversion.

The Climate Impacts Research Consortium: Lessons Learned from the Evaluation of Co-production projects

NASA Astrophysics Data System (ADS)

Sokolovska, I.; Andrepont, J. A.; Lach, D.

2017-12-01

The Pacific Northwest Climate Impacts Research Consortium (CIRC) is a climate-science-to-climate-action team funded by the National Oceanic and Atmospheric Administration (NOAA), member of NOAA's Regional Integrated Sciences and Assessments (RISA) program. The internal evaluation of the last 6 years of CIRC's work focused on the co-production of knowledge process. The evaluation was based on CIRC's Reflection and Logic model and used a mixed methods design. During regular monthly meetings in 2014/15, all CIRC PIs reflected on the co-production process and presented their evaluation of the projects they worked on. Additionally, we conducted semi-structured interviews with CIRC participants, purposefully targeting key informants. The Climate Impacts Research Consortium teams also administered surveys to assess participants' experiences of the coproduction process as they were engaging in it. Identifying and cultivating an informant from the local stakeholder group with deep, accessible roots within the target community can lead to better coproduction results than having to build those relationships from naught. Across projects, most participants agreed that the project increased their understanding of their area's hazards and by the end of the project most participants were confident the project would produce useful results for themselves. Finally, most participants intended to share what they had learned from this experience with their colleagues and we found that co-production built capacities necessary for communities to incorporate climate change in discussions even after the end of CIRC's participation. During the projects, the involvement of non-traditional participants along with experts was critical to success and a lot of work and preparation needs to be put into the planning of any co-production meeting to overcome various barriers to communication and build trust.

Eddy Covariance measurements of stable CO2 and H2O isotopologues

NASA Astrophysics Data System (ADS)

Braden-Behrens, Jelka; Knohl, Alexander

2015-04-01

The analysis of the stable isotope composition of CO2 and H2O fluxes (such as 13C, 18O and 2H in H2O and CO2) has provided valuable insights into ecosystem gas exchange. The approach builds on differences in the isotope signature of different ecosystem components that are primarily caused by the preference for or the discrimination against respective isotope species by important processes within the ecosystem (e.g. photosynthesis or leaf water diffusion). With the ongoing development of laser spectrometric methods, fast and precise measurements of isotopologue mixing ratios became possible, hence also enabling Eddy Covariance (EC) based approaches to directly measure the isotopic composition of CO2 and H2Ov net fluxes on ecosystem scale. During an eight month long measurement campaign in 2015, we plan to simultaneously measure CO2 and H2Ov isotopologue fluxes using an EC approach in a managed beech forest in Thuringia, Germany. For this purpose, we will use two different laser spectrometers for high frequency measurements of isotopic compositions: For H2Ov measurements, we will use an off axis cavity output water vapour isotope analyser (WVIA, Los Gatos Research Inc.) with 5 Hz response; and for CO2 measurements, we will use a quantum cascade laser-based system (QCLAS, Aerodyne Research Inc.) with thermoelectrically cooled detectors and up to 10 Hz measurement capability. The resulting continuous isotopologue flux measurements will be accompanied by intensive sampling campaigns on the leaf scale: Water from leaf, twig, soil and precipitation samples will be analysed in the lab using isotope ratio mass spectrometry. During data analysis we will put a focus on (i) the influence of carbon and oxygen discrimination on the isotopic signature of respective net ecosystem exchange, (ii) on the relationship between evapotranspiration and leaf water enrichment, and (iii) on the 18O exchange between carbon dioxide and water. At present, we already carried out extensive instrument performance tests for both laser spectrometers that will be presented here. In addition, we will present the instrumentation, the measurement periphery as well as anticipated analysis approaches required for the planned measurement campaign.

What component of executive functions contributes to normal and impaired reading comprehension in young adults?

PubMed

Georgiou, George K; Das, J P

2016-01-01

The purpose of this study was two-fold: (a) to examine what component of executive functions (EF) - planning and working memory - predicts reading comprehension in young adults (Study 1), and (b) to examine if less skilled comprehenders experience deficits in the EF components (Study 2). In Study 1, we assessed 178 university students (120 females; mean age=21.82 years) on planning (Planned Connections, Planned Codes, and Planned Patterns), working memory (Listening Span, Digit Span Backward, and Digit Memory), and reading comprehension (Nelson-Denny Reading Test). The results of structural equation modeling indicated that only planning was a significant predictor of reading comprehension. In Study 2, we assessed 30 university students with a specific reading comprehension deficit (19 females; mean age=23.01 years) and 30 controls (18 females; mean age=22.77 years) on planning (Planned Connections and Crack the Code) and working memory (Listening Span and Digit Span Backward). The results showed that less skilled comprehenders performed significantly poorer than controls only in planning. Taken together, the findings of both studies suggest that planning is the preeminent component of EF that is driving its relationship with reading comprehension in young adults. Copyright © 2015 Elsevier Ltd. All rights reserved.

Structure sensitivity in the kinetics and the dynamics of CO oxidation over stepped Pd(335) studied by the molecular beam infrared chemiluminescence technique: Determination of working sites during the steady-state reaction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Uetsuka, H.; Watanabe, K.; Kimpara, H.

Kinetics and dynamics of CO oxidation have been studied on a stepped Pd(335) surface at a steady-state condition and compared with those on flat Pd(111). The infrared (IR) chemiluminescence technique was applied to determine where the active catalytic sites are on the Pd(335) surface. Since the vibrational energy state of the product CO{sub 2} is sensitive to the structures of the reaction sites on Pd surfaces, information about the working reaction sites during the steady-state CO oxidation can be obtained from the IR emission spectra of the product CO{sub 2}. The production rate of CO{sub 2} was higher on Pd(335)more » than on Pd(111), indicating that the steps on the surface enhance the catalytic activity for Co oxidation under the steady-state condition. However, the rate data do not necessarily show the real active sites for the CO + O recombination reaction. At a surface temperature of 850 K, the vibrational Boltzmann temperature (T{sub v}) of the product CO{sub 2} on Pd(335) was quite different from (much lower than) that on Pd(111), although the Pd(335) surface has four-atom wide (111) terraces. The lower T{sub v} value on Pd(335) was similar to that on Pd(110)(1 x 1), indicating that a relatively linear activated CO{sub 2} complex was formed. Therefore, during the steady-state CO oxidation on Pd(335), the reaction does not take place on the (111) terrace sites, but mostly on the step sites at 850 K. On the contrary, as the CO coverage increased at a lower surface temperature and at a high CO/O{sub 2} ratio, the T{sub v} values on Pd(335) tend to approach those on Pd(111), indicating that the contribution of the active sites on the steps is decreased and the working reaction sites shift to the (111) terrace sites.« less

Acute and Chronic Exposure to CO2 in Space Flight

NASA Technical Reports Server (NTRS)

Alexander, D.; Wu, J.; Barr, Y. R.; Watkins, S. D.

2010-01-01

Spacecraft and space stations, similar to other habitable confined spaces such as submarines, need to provide a breathable atmosphere for their inhabitants. The inevitable production of CO2 during respiration necessitates life support systems that "scrub" the atmosphere and lower CO2 levels. Due to operational limitations associated with space flight (limited mass, volume, power, and consumables) CO2 is not scrubbed down to its terrestrial equivalent of 0.03% CO2 (ppCO2 of 0.23 mmHg), but is kept below 0.7% (ppCO2 of 5.3 mmHg), a level established in NASA s 180-day mission Spacecraft Maximum Allowable Concentration (SMAC) to be safe and unlikely to cause symptoms. Reports of space flight crewmembers becoming symptomatic with headaches, fatigue, and malaise at levels below those known to cause such symptoms terrestrially has prompted studies measuring the levels of CO2 on both the space shuttle and the space station. Data from cabin atmosphere sampling were collected on space shuttle missions STS-113, STS-122, STS-123, and International Space Station Expeditions 12-15 and 17, and the measured CO2 levels were then correlated to symptoms reported by the crew. The results indicate that a correlation exists between CO2 levels and symptomatology, however causality cannot be established at this time. While the short-term effects of elevated CO2 exposure are well known terrestrially, less is known regarding potential long-term effects of prolonged exposure to a CO2-rich environment or how the physiological changes caused by microgravity may interact with such exposures. Other challenges include limitations in the CO2 monitors used, lack of convection in the microgravity environment, and formation of localized CO2 pockets. As it is unclear if the unique environment of space increases sensitivity to CO2 or if other confounding factors are present, further research is planned to elucidate these points. At the same time, efforts are underway to update the SMAC to a lower level

Analysis of CO2, CO and HC emission reduction in automobiles

NASA Astrophysics Data System (ADS)

Balan, K. N.; Valarmathi, T. N.; Reddy, Mannem Soma Harish; Aravinda Reddy, Gireddy; Sai Srinivas, Jammalamadaka K. M. K.; Vasan

2017-05-01

In the present scenario, the emission from automobiles is becoming a serious problem to the environment. Automobiles, thermal power stations and Industries majorly constitute to the emission of CO2, CO and HC. Though the CO2 available in the atmosphere will be captured by oceans, grasslands; they are not enough to control CO2 present in the atmosphere completely. Also advances in engine and vehicle technology continuously to reduce the emission from engine exhaust are not sufficient to reduce the HC and CO emission. This work concentrates on design, fabrication and analysis to reduce CO2, CO and HC emission from exhaust of automobiles by using molecular sieve 5A of 1.5mm. In this paper, the details of the fabrication, results and discussion about the process are discussed.

A Case Study of Coordination in Distributed Agile Software Development

NASA Astrophysics Data System (ADS)

Hole, Steinar; Moe, Nils Brede

Global Software Development (GSD) has gained significant popularity as an emerging paradigm. Companies also show interest in applying agile approaches in distributed development to combine the advantages of both approaches. However, in their most radical forms, agile and GSD can be placed in each end of a plan-based/agile spectrum because of how work is coordinated. We describe how three GSD projects applying agile methods coordinate their work. We found that trust is needed to reduce the need of standardization and direct supervision when coordinating work in a GSD project, and that electronic chatting supports mutual adjustment. Further, co-location and modularization mitigates communication problems, enables agility in at least part of a GSD project, and renders the implementation of Scrum of Scrums possible.

Delphi based consensus study into planning for chemical incidents.

PubMed

Crawford, I W F; Mackway-Jones, K; Russell, D R; Carley, S D

2004-01-01

To achieve consensus in all phases of chemical incident planning and response. A three round Delphi study was conducted using a panel of 39 experts from specialties involved in the management of chemical incidents. Areas that did not reach consensus in the Delphi study were presented as synopsis statements for discussion in four syndicate groups at a conference hosted by the Department of Health Emergency Planning Co-ordination Unit. A total of 183 of 322 statements had reached consensus upon completion of the Delphi study. This represented 56.8% of the total number of statements. Of these, 148 reached consensus at >94% and 35 reached consensus at >89%. The results of the process are presented as a series of synopsis consensus statements that cover all phases of chemical incident planning and response. The use of a Delphi study and subsequent syndicate group discussions achieved consensus in aspects of all phases of chemical incident planning and response that can be translated into practical guidance for use at regional prehospital and hospital level. Additionally, areas of non-consensus have been identified where further work is required.

Delphi based consensus study into planning for chemical incidents

PubMed Central

Crawford, I; Mackway-Jones, K; Russell, D; Carley, S

2004-01-01

Objective: To achieve consensus in all phases of chemical incident planning and response. Design: A three round Delphi study was conducted using a panel of 39 experts from specialties involved in the management of chemical incidents. Areas that did not reach consensus in the Delphi study were presented as synopsis statements for discussion in four syndicate groups at a conference hosted by the Department of Health Emergency Planning Co-ordination Unit. Results: A total of 183 of 322 statements had reached consensus upon completion of the Delphi study. This represented 56.8% of the total number of statements. Of these, 148 reached consensus at >94% and 35 reached consensus at >89%. The results of the process are presented as a series of synopsis consensus statements that cover all phases of chemical incident planning and response. Conclusions: The use of a Delphi study and subsequent syndicate group discussions achieved consensus in aspects of all phases of chemical incident planning and response that can be translated into practical guidance for use at regional prehospital and hospital level. Additionally, areas of non-consensus have been identified where further work is required. PMID:14734369

Evaluating metal-organic frameworks for post-combustion carbon dioxide capture via temperature swing adsorption

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mason, JA; Sumida, K; Herm, ZR

Two representative metal-organic frameworks, Zn4O(BTB)(2)(BTB3- = 1,3,5-benzenetribenzoate; MOF-177) and Mg-2(dobdc) (dobdc(4-) = 1,4-dioxido-2,5-benzenedicarboxylate; Mg-MOF-74, CPO-27-Mg), are evaluated in detail for their potential use in post-combustion CO2 capture via temperature swing adsorption (TSA). Low-pressure single-component CO2 and N-2 adsorption isotherms were measured every 10 degrees C from 20 to 200 degrees C, allowing the performance of each material to be analyzed precisely. In order to gain a more complete understanding of the separation phenomena and the thermodynamics of CO2 adsorption, the isotherms were analyzed using a variety of methods. With regard to the isosteric heat of CO2 adsorption, Mg-2(dobdc) exhibits anmore » abrupt drop at loadings approaching the saturation of the Mg2+ sites, which has significant implications for regeneration in different industrial applications. The CO2/N-2 selectivities were calculated using ideal adsorbed solution theory (IAST) for MOF-177, Mg-2(dobdc), and zeolite NaX, and working capacities were estimated using a simplified TSA model. Significantly, MOF-177 fails to exhibit a positive working capacity even at regeneration temperatures as high as 200 degrees C, while Mg-2(dobdc) reaches a working capacity of 17.6 wt% at this temperature. Breakthrough simulations were also performed for the three materials, demonstrating the superior performance of Mg-2(dobdc) over MOF-177 and zeolite NaX. These results show that the presence of strong CO2 adsorption sites is essential for a metal-organic framework to be of utility in post-combustion CO2 capture via a TSA process, and present a methodology for the evaluation of new metal-organic frameworks via analysis of single-component gas adsorption isotherms.« less

The Second "Ring of Towers": Over-sampling the Mid Continent Intensive region CO2 mixing ratio?

NASA Astrophysics Data System (ADS)

Richardson, S.; Miles, N.; Davis, K.; Crosson, E.; Denning, S.; Zupanksi, D.; Uliasz, M.

2007-12-01

A central barrier preventing the scientific community from understanding the carbon balance of the continent is methodological; it is technically difficult to bridge the gap in spatial scales that exists between the detailed understanding of ecological processes that can be gathered via intensive local field study, and the overarching but mechanistically poor understanding of the global carbon cycle that is gained by analyzing the atmospheric CO2 budget. The NACP's Midcontinental Intensive (MCI) study seeks to bridge this gap by conducting a rigorous methodological test of our ability to measure the terrestrial carbon balance of the upper Midwest. A critical need in bridging this gap is increased data density. A primary goal of the project is to increase the regional atmospheric CO2 data density so that 1) atmospheric inversions can derive well-constrained regional ecosystem carbon flux estimates and 2) the trade off between data density and accuracy of the flux estimates can be determined quantitatively using field observations, thus providing guidance to future observational network designs. Our work adds a regional network of five communications-tower based atmospheric CO2 observations to the planned long-term atmospheric CO2 observing network (tall towers, flux towers and aircraft profiles) in the midcontinent intensive region. Measurements began in April-June 2007, If the measurements are shown to be spatially dense enough to over sample the CO2 mixing ratio, the experiment will provide an upper bounds on the density of measurements required to produce the most accurate flux possible with current atmospheric inversions. The five sites for "Ring 2" and deployment dates are Centerville, IA (Apr 07), Round Lake, MN (May 07), Kewanee, IL (Apr 07), Mead, NE (Apr 07), Galesville, WI (June 07). Two heights are sampled at each tower (30 m AGL and between 110 and 140 m AGL). More details are available at www.ring2.psu.edu. In addition, two systems in PSU's network of well-calibrated CO2 mixing ratio measurements deployed at Ameriflux towers are within the midcontinental region: Ozark, MO (30 m AGL) and Mead, NE (3-6 m AGL) (www.amerifluxco2.psu.edu). The instruments chosen for the Ring 2 deployment are Picarro Inc., Cavity Ring-Down Spectroscopy (CRDS) instruments. One advantage of the CRDS instruments is the reduced need for calibration compared to the systems used in PSU's Ameriflux CO2 network which are calibrated every four hours using four calibration tanks. Although the long-term stability is not exactly known, tests have shown accuracy to within 0.2 ppm on a monthly time scale without additional calibration. Preliminary results show spatial differences in daytime CO2 across the ring that are as large as 40 ppm, and highly variable in time. We will present observations and preliminary interpretation of these data.

Formulation of consumables management models. Development approach for the mission planning processor working model

NASA Technical Reports Server (NTRS)

Connelly, L. C.

1977-01-01

The mission planning processor is a user oriented tool for consumables management and is part of the total consumables subsystem management concept. The approach to be used in developing a working model of the mission planning processor is documented. The approach includes top-down design, structured programming techniques, and application of NASA approved software development standards. This development approach: (1) promotes cost effective software development, (2) enhances the quality and reliability of the working model, (3) encourages the sharing of the working model through a standard approach, and (4) promotes portability of the working model to other computer systems.

Carbon Isotopic Compositions in Carbon Dioxide Measured By Micro-Laser Raman Spectroscopy

NASA Astrophysics Data System (ADS)

Li, J.-J.; Li, R.-X.; Dong, H.; Wang, Zh.-H.; Zhao, B.-S.; Wang, N.; Cheng, J.-H.

2017-05-01

We have prepared a series of 12CO2/13CO2 binary mixtures as standard samples at room temperature. Using microlaser Raman spectroscopy, it was found that the relationship between the 12CO2 mole fractions and the peak area ratios of 12CO2/13CO2 in the Raman spectra of CO2 binary mixtures showed a polynomial correlation. The establishment of the experimental working curve paves the way for estimating the mole fractions of each individual fluid inclusion and determining 13C/12C and δ13C u sing micro-Raman spectroscopy. The Raman spectra of 12CO2 and 13CO2 showed a characteristic peak at 1348 cm-1 with an argon laser at 785 nm, which is perhaps due to the formation of dimers.

Coupling molecular catalysts with nanostructured surfaces for efficient solar fuel production

NASA Astrophysics Data System (ADS)

Jin, Tong

Solar fuel generation via carbon dioxide (CO2) reduction is a promising approach to meet the increasing global demand for energy and to minimize the impact of energy consumption on climate change. However, CO2 is thermodynamically stable; its activation often requires the use of appropriate catalysts. In particular, molecular catalysts with well-defined structures and tunability have shown excellent activity in photochemical CO2 reduction. These homogenous catalysts, however, suffer from poor stability under photochemical conditions and difficulty in recycling from the reaction media. Heterogenized molecular catalysts, particularly those prepared by coupling molecular catalysts with solid-state surfaces, have attracted more attention in recent years as potential solutions to address the issues associated with molecular catalysts. In this work, solar CO2 reduction is investigated using systems coupling molecular catalysts with robust nanostructured surfaces. In Chapter 2, heterogenization of macrocyclic cobalt(III) and nickel (II) complexes on mesoporous silica surface was achieved by different methods. Direct ligand derivatization significantly lowered the catalytic activity of Co(III) complex, while grafting the Co(III) complex onto silica surface through Si-O-Co linkage resulted in hybrid catalysts with excellent activity in CO2 reduction in the presence of p-terphenyl as a molecular photosensitizer. An interesting loading effect was observed, in which the optimal activity was achieved at a medium Co(III) surface density. Heterogenization of the Ni(II) complex on silica surface has also been implemented, the poor photocatalytic activity of the hybrid catalyst can be attributed to the intrinsic nature of the homogeneous analogue. This study highlighted the importance of appropriate linking strategies in preparing functional heterogenized molecular catalysts. Coupling molecular complexes with light-harvesting surfaces could avoid the use of expensive molecular photosensitizers. In Chapter 3, effective coupling of the macrocyclic Co(III) complex with titanium dioxide (TiO¬2) nanoparticles was achieved by two deposition methods. The synthesized hybrid photocatalysts were thoroughly characterized with a variety of techniques. Upon UV light irradiation, photoexcited electrons in TiO2 nanoparticles were transferred to the surface Co(III) catalyst for CO2 reduction. Production of carbon monoxide (CO) from CO2 was confirmed by isotope labeling combined with infrared spectroscopy. Deposition of the Co(III) catalyst through Ti-O-Co linkages was essential for the photo-induced electron transfer and CO2-reduction activity using the hybrid photocatalysts. In Chapter 4, molecular Re(I) and Co(II) catalysts were coupled with silicon-based photoelectrodes, including a silicon nanowire (SiNW) photoelectrode, to achieve photoelectrochemical CO2 reduction. Photovoltages between 300-600 mV were obtained using the molecular catalysts on the silicon photoelectrodes. SiNWs exhibited enhanced properties, including significantly higher photovoltages than a planar silicon photoelectrode, the ability to protect one of the molecular catalysts from photo-induced decomposition, and excellent selectivity towards CO production in CO2 reduction. Recent theoretical and experimental work have demonstrated low-energy, binuclear pathways for CO2-to-CO conversion using several molecular catalysts. In such binuclear pathways, two metal centers work cooperatively to achieve two-electron CO2 reduction. Chapter 5 describes our effort to promote the binuclear pathway by grafting the molecular Co(III) catalyst onto silica surfaces. Different linking strategies were attempted to achieve this goal by planting the surface Co(III) sites in close proximity.

Flow Distribution Measurement Feasibility in Supercritical CO 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lance, Blake

2017-12-01

Supercritical CO 2 (sCO 2) is a fluid of interest for advanced power cycles that can reach thermal to electric energy conversion efficiencies of 50% or higher. Of particular interest for fossil-fired natural gas is the Allam cycle that captures nearly all CO 2 emissions and exports it as a fluid stream where it may be of value. The combustion process conditions are unlike any before realized with 90-95% CO 2 concentration, temperatures around 1000°C, and pressures near 300 bar. This work outlines the experimental feasibility of flow measurements to acquire the first known data in pure sCO 2 atmore » similar but reduced temperature and pressure conditions.« less

Carbon Monoxide Alarm and Smoke Alarm Use Among Parents Recruited From a Pediatric Emergency Department.

PubMed

Roberts, Kristin J; Fowler, Erica; Comstock, R Dawn; Fernandez, Soledad; Abdel-Rasoul, Mahmoud; Mihalov, Leslie; Casavant, Marcel J; McKenzie, Lara B

2018-02-01

Although the proper installation and maintenance of carbon monoxide (CO) and smoke alarms can protect individuals from residential CO-related and fire-related injuries, these devices are underutilized. We describe characteristics associated with self-reported CO and smoke alarm use of parents recruited from a pediatric emergency department to improve CO alarm use. Parents of children ≤ 18 years (N = 299) reported socio-demographic characteristics and CO and smoke alarm ownership and practices. We assigned participants to a behavioral profile and a Precaution Adoption Process Model stage based on their self-reported CO and smoke alarm use. Most participants (71%) did not have CO alarms in their homes, but reported owning at least one working smoke alarm (98%). Participants who reported "perfect" CO alarm behavior (defined as having a working CO alarm, one near a sleeping area, with batteries replaced every 6 months; 9%) were more likely to earn a higher income, own their home, and have lived at their current residence for at least 2 years. Participants who reported "perfect" smoke alarm behavior (defined as having a working smoke alarm on every level, with batteries replaced every 6 months; 49%) were more likely to rent their home, receive federal assistance, and have lived at their current residence for at least 2 years. Interventions to increase correct CO alarm use are necessary.

Final Work Plan: Targeted Investigation at York, Nebraska

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, Lorraine M.

The targeted investigation at York will be implemented in phases, so that data collected and interpretations developed at each stage of the program can be evaluated to guide subsequent phases most effectively. Section 2 of this Work Plan presents a brief overview of the York site, its geologic and hydrologic setting, and the previous CCC/USDA investigations. Section 3, outlines the proposed technical program for the targeted investigation, and Section 4 describes the investigative methods to be employed. A community relations plan is in Section 5, and Section 6 includes health and safety information. In addition to this site-specific Work Plan,more » the Master Work Plan (Argonne 2002) developed by Argonne for CCC/USDA investigations in Nebraska should be consulted for complete details of the methods and procedures to be used at York.« less

Carbon Capture and Storage (CCS): Risk assessment focused on marine bacteria.

PubMed

Borrero-Santiago, A R; DelValls, T A; Riba, I

2016-09-01

Carbon capture and storage (CCS) is one of the options to mitigate the negative effects of the climate change. However, this strategy may have associated some risks such as CO2 leakages due to an escape from the reservoir. In this context, marine bacteria have been underestimated. In order to figure out the gaps and the lack of knowledge, this work summarizes different studies related to the potential effects on the marine bacteria associated with an acidification caused by a CO2 leak from CSS. An improved integrated model for risk assessment is suggested as a tool based on the rapid responses of bacterial community. Moreover, this contribution proposes a strategy for laboratory protocols using Pseudomona stanieri (CECT7202) as a case of study and analyzes the response of the strain under different CO2 conditions. Results showed significant differences (p≤0.05) under six diluted enriched medium and differences about the days in the exponential growth phase. Dilution 1:10 (Marine Broth 2216 with seawater) was selected as an appropriate growth medium for CO2 toxicity test in batch cultures. This work provide an essential and a complete tool to understand and develop a management strategy to improve future works related to possible effects produced by potential CO2 leaks. Copyright © 2016 Elsevier Inc. All rights reserved.

Rubber muscle actuation with pressurized CO2 from enzyme-catalyzed urea hydrolysis

NASA Astrophysics Data System (ADS)

Sutter, Thomas M.; Dickerson, Matthew B.; Creasy, Terry S.; Justice, Ryan S.

2013-09-01

A biologically inspired pneumatic pressure source was designed and sized to supply high pressure CO2(g) to power a rubber muscle actuator. The enzyme urease served to catalyze the hydrolysis of urea, producing CO2(g) that flowed into the actuator. The actuator’s power envelope was quantified by testing actuator response on a custom-built linear-motion rig. Reaction kinetics and available work density were determined by replacing the actuator with a double-action piston and measuring volumetric gas generation against a fixed pressure on the opposing piston. Under the conditions investigated, urease catalyzed the generation of up to 0.81 MPa (117 psi) of CO2(g) in the reactor headspace within 18 min, and the evolved gas produced a maximum work density of 0.65 J ml-1.

The O2-assisted Al/CO2 electrochemical cell: A system for CO2 capture/conversion and electric power generation.

PubMed

Al Sadat, Wajdi I; Archer, Lynden A

2016-07-01

Economical and efficient carbon capture, utilization, and sequestration technologies are a requirement for successful implementation of global action plans to reduce carbon emissions and to mitigate climate change. These technologies are also essential for longer-term use of fossil fuels while reducing the associated carbon footprint. We demonstrate an O2-assisted Al/CO2 electrochemical cell as a new approach to sequester CO2 emissions and, at the same time, to generate substantial amounts of electrical energy. We report on the fundamental principles that guide operations of these cells using multiple intrusive electrochemical and physical analytical methods, including chronopotentiometry, cyclic voltammetry, direct analysis in real-time mass spectrometry, energy-dispersive x-ray spectroscopy, x-ray photoelectron spectroscopy, and coupled thermogravimetric analysis-Fourier transform infrared spectroscopy. On this basis, we demonstrate that an electrochemical cell that uses metallic aluminum as anode and a carbon dioxide/oxygen gas mixture as the active material in the cathode provides a path toward electrochemical generation of a valuable (C2) species and electrical energy. Specifically, we show that the cell first reduces O2 at the cathode to form superoxide intermediates. Chemical reaction of the superoxide with CO2 sequesters the CO2 in the form of aluminum oxalate, Al2(C2O4)3, as the dominant product. On the basis of an analysis of the overall CO2 footprint, which considers emissions associated with the production of the aluminum anode and the CO2 captured/abated by the Al/CO2-O2 electrochemical cell, we conclude that the proposed process offers an important strategy for net reduction of CO2 emissions.

The O2-assisted Al/CO2 electrochemical cell: A system for CO2 capture/conversion and electric power generation

PubMed Central

Al Sadat, Wajdi I.; Archer, Lynden A.

2016-01-01

Economical and efficient carbon capture, utilization, and sequestration technologies are a requirement for successful implementation of global action plans to reduce carbon emissions and to mitigate climate change. These technologies are also essential for longer-term use of fossil fuels while reducing the associated carbon footprint. We demonstrate an O2-assisted Al/CO2 electrochemical cell as a new approach to sequester CO2 emissions and, at the same time, to generate substantial amounts of electrical energy. We report on the fundamental principles that guide operations of these cells using multiple intrusive electrochemical and physical analytical methods, including chronopotentiometry, cyclic voltammetry, direct analysis in real-time mass spectrometry, energy-dispersive x-ray spectroscopy, x-ray photoelectron spectroscopy, and coupled thermogravimetric analysis–Fourier transform infrared spectroscopy. On this basis, we demonstrate that an electrochemical cell that uses metallic aluminum as anode and a carbon dioxide/oxygen gas mixture as the active material in the cathode provides a path toward electrochemical generation of a valuable (C2) species and electrical energy. Specifically, we show that the cell first reduces O2 at the cathode to form superoxide intermediates. Chemical reaction of the superoxide with CO2 sequesters the CO2 in the form of aluminum oxalate, Al2(C2O4)3, as the dominant product. On the basis of an analysis of the overall CO2 footprint, which considers emissions associated with the production of the aluminum anode and the CO2 captured/abated by the Al/CO2-O2 electrochemical cell, we conclude that the proposed process offers an important strategy for net reduction of CO2 emissions. PMID:27453949

eHealth and IMIA's Strategic Planning Process - IMIA conference introductory address.

PubMed

Murray, Peter; Haux, Reinhold; Lorenzi, Nancy

2008-01-01

The International Medical Informatics Association (IMIA) is the only organization in health and biomedical informatics which is fully international in scope, bridging the academic, health practice, education, and health industry worlds through conferences, working groups, special interest groups and publications. Authored by the IMIA Interim Vice President for Strategic Planning Implementation and co-authored by the current IMIA President and the IMIA Past-President, the intention of this paper is to introduce IMIA's current strategic planning process and to set this process in relation to 'eHealth: Combining Health Telematics, Telemedicine, Biomedical Engineering and Bioinformatics to the Edge', the theme of this conference. From the viewpoint of an international organization such as IMIA, an eHealth strategy needs to be considered in a comprehensive way, including broadly stimulating high-quality health and biomedical informatics research and education, as well as providing support to bridging outcomes towards a new practice of health care in a changing world.

In Situ Study of CO2 and H2O Partitioning Between Na-Montmorillonite and Variably Wet Supercritical Carbon Dioxide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Loring, John S.; Ilton, Eugene S.; Chen, Jeffrey

Shale formations play fundamental roles in large-scale geologic carbon sequestration (GCS) aimed primarily to mitigate climate change, and in smaller-scale GCS targeted mainly for CO2-enhanced gas recovery operations. In both technologies, CO2 is injected underground as a supercritical fluid (scCO2), where interactions with shale minerals could influence successful GCS implementation. Reactive components of shales include expandable clays, such as montmorillonites and mixed-layer illite/smectite clays. In this work, we used in situ X-ray diffraction (XRD) and in situ infrared (IR) spectroscopy to investigate the swelling/shrinkage and water/CO2 sorption of a pure montmorillonite, Na-SWy-2, when the clay is exposed to variably hydratedmore » scCO2 at 50 °C and 90 bar. Measured interlayer spacings and sorbed water concentrations at varying levels of scCO2 hydration are similar to previously reported values measured in air at ambient pressure over a range of relative humidities. IR spectra show evidence of both water and CO2 intercalation, and variations in peak shapes and positions suggest multiple sorbed types with distinct chemical environments. Based on the intensity of the asymmetric CO stretching band of the CO2 associated with the Na-SWy-2, we observed a significant increase in sorbed CO2 as the clay expands from a 0W to a 1W state, suggesting that water props open the interlayer so that CO2 can enter. However, as the clay transitions from a 1W to a 2W state, CO2 desorbs sharply. These observations were placed in the context of two conceptual models concerning hydration mechanisms for expandable clays and were also discussed in light of recent theoretical studies on CO2-H2O-clay interactions. The swelling/shrinkage of expandable clays could affect solid volume, porosity, and permeability of shales. Consequently, the results from this work could aid predictions of shale caprock integrity in large-scale GCS, as well as methane transmissivity in enhanced gas recovery operations.« less

Core Ion Structures and Solvation Effects in Gas Phase [Sn(CO_{2})_{n}]^{-} Clusters

NASA Astrophysics Data System (ADS)

Thompson, Michael C.; Weber, J. Mathias

2017-06-01

We report infrared photodissociation spectra of [Sn(CO_{2})_{n}] (n=2-6) clusters. We explore core ion geometries through quantum chemical calculations and assign our experimental spectra through comparison with calculated vibrational frequencies. We discuss our results in the context of heterogeneous catalytic reduction of CO_{2}, and compare our results with previous work on other post-transition metal species.

Early opportunities of CO2 geological storage deployment in coal chemical industry in China

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wei, Ning; Li, Xiaochun; Liu, Shengnan

2014-11-12

Abstract: Carbon dioxide capture and geological storage (CCS) is regarded as a promising option for climate change mitigation; however, the high capture cost is the major barrier to large-scale deployment of CCS technologies. High-purity CO2 emission sources can reduce or even avoid the capture requirements and costs. Among these high-purity CO2 sources, certain coal chemical industry processes are very important, especially in China. In this paper, the basic characteristics of coal chemical industries in China is investigated and analyzed. As of 2013 there were more than 100 coal chemical plants in operation or in late planning stages. These emission sourcesmore » together emit 430 million tons CO2 per year, of which about 30% are emit high-purity and pure CO2 (CO2 concentration >80% and >99% respectively).Four typical source-sink pairs are studied by a techno-economic evaluation, including site screening and selection, source-sink matching, concept design, and experienced economic evaluation. The technical-economic evaluation shows that the levelized cost of a CO2 capture and aquifer storage project in the coal chemistry industry ranges from 14 USD/t to 17 USD/t CO2. When a 15USD/t CO2 tax and 15USD/t for CO2 sold to EOR are considered, the levelized cost of CCS project are negative, which suggests a net economic benefit from some of these CCS projects. This might provide China early opportunities to deploy and scale-up CCS projects in the near future.« less

CO2 Capture by Absorption with Potassium Carbonate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gary T. Rochelle; Eric Chen; Babatunde Oyenekan

The objective of this work is to improve the process for CO{sub 2} capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous K{sub 2}CO{sub 3} promoted by piperazine. Ethylenediamine was detected in a degraded solution of MEA/PZ solution, suggesting that piperazine is subject to oxidation. Stripper modeling has demonstrated that vacuum strippers will be more energy efficient if constructed short and fat rather than tall and skinny. The matrix stripper has been identified as a configuration that will significantly reduce energy use. Extensive measurements of CO{sub 2} solubility in 7 m MEA at 40 and 60 C have confirmedmore » the work by Jou and Mather. Corrosion of carbon steel without inhibitors increases from 19 to 181 mpy in lean solutions of 6.2 m MEA/PZ as piperazine increases from 0 to 3.1 m.« less

Doping Li and K into Na2ZrO3 Sorbent to Improve Its CO2 Capture Capability

NASA Astrophysics Data System (ADS)

Duan, Yuhua

Carbon dioxide is one of the major combustion products which once released into the air can contribute to global climate change. Solid sorbents have been reported in several previous studies to be promising candidates for CO2 sorbent applications due to their high CO2 absorption capacities at moderate working temperatures. However, at a given CO2 pressure, the turnover temperature (Tt) of an individual solid capture CO2 reaction is fixed and may be outside the operating temperature range (ΔTo) for a particularly capture technology. In order to shift such Tt for a solid into the range of ΔTo, its corresponding thermodynamic property must be changed by changing its structure by reacting (mixing) with other materials or doping with other elements. As an example, by combining thermodynamic database searching with ab initio thermodynamics calculations, in this work, we explored the Li- and K-doping effects on the Tt shifts of Na2ZrO3 at different doping levels. The obtained results showed that compared to pure Na2ZrO3, the Li- and K-doped mixtures Na2-αMαZrO3 (M =Li, K) have lower Tt and higher CO2 capture capacities.

The Relationship between Working Memory Capacity and L2 Oral Performance under Task-Based Careful Online Planning Condition

ERIC Educational Resources Information Center

Ahmadian, Mohammad Javad

2012-01-01

The study reported in this article aimed to investigate the way working memory capacity (WMC) interacts with careful online planning--a task-based implementation variable--to affect second language (L2) speech production. This issue is important to teachers, because it delves into one of the possible task-based implementation variables and thus…

Phonological and Executive Working Memory in L2 Task-Based Speech Planning and Performance

ERIC Educational Resources Information Center

Wen, Zhisheng

2016-01-01

The present study sets out to explore the distinctive roles played by two working memory (WM) components in various aspects of L2 task-based speech planning and performance. A group of 40 post-intermediate proficiency level Chinese EFL learners took part in the empirical study. Following the tenets and basic principles of the…

An Interval Type-2 Fuzzy Multiple Echelon Supply Chain Model

NASA Astrophysics Data System (ADS)

Miller, Simon; John, Robert

Planning resources for a supply chain is a major factor determining its success or failure. In this paper we build on previous work introducing an Interval Type-2 Fuzzy Logic model of a multiple echelon supply chain. It is believed that the additional degree of uncertainty provided by Interval Type-2 Fuzzy Logic will allow for better representation of the uncertainty and vagueness present in resource planning models. First, the subject of Supply Chain Management is introduced, then some background is given on related work using Type-1 Fuzzy Logic. A description of the Interval Type-2 Fuzzy model is given, and a test scenario detailed. A Genetic Algorithm uses the model to search for a near-optimal plan for the scenario. A discussion of the results follows, along with conclusions and details of intended further work.

Building partnerships in community-based participatory research: budgetary and other cost considerations.

PubMed

Hoeft, Theresa J; Burke, Wylie; Hopkins, Scarlett E; Charles, Walkie; Trinidad, Susan B; James, Rosalina D; Boyer, Bert B

2014-03-01

Community-based participatory research (CBPR) is an important framework for partnering with communities to reduce health disparities. Working in partnership with community incurs additional costs, some that can be represented in a budget summary page and others that are tied to the competing demands placed on community and academic partners. These cost considerations can inform development of community-academic partnerships. We calculated costs from a case study based on an ongoing CBPR project involving a Community Planning Group (CPG) of community co-researchers in rural Alaska and a bicultural liaison group who help bridge communication between CPG and academic co-researchers. Budget considerations specific to CBPR include travel and other communication-related costs, compensation for community partners, and food served at meetings. We also identified sources of competing demands for community and academic partners. Our findings can inform budget discussions in community-academic partnerships. Discussions of competing demands on community partners' time can help plan timelines for CBPR projects. Our findings may also inform discussions about tenure and promotion policies that may represent barriers to participation in CBPR for academic researchers.

A dose homogeneity and conformity evaluation between ViewRay and pinnacle-based linear accelerator IMRT treatment plans

PubMed Central

Saenz, Daniel L.; Paliwal, Bhudatt R.; Bayouth, John E.

2014-01-01

ViewRay, a novel technology providing soft-tissue imaging during radiotherapy is investigated for treatment planning capabilities assessing treatment plan dose homogeneity and conformity compared with linear accelerator plans. ViewRay offers both adaptive radiotherapy and image guidance. The combination of cobalt-60 (Co-60) with 0.35 Tesla magnetic resonance imaging (MRI) allows for magnetic resonance (MR)-guided intensity-modulated radiation therapy (IMRT) delivery with multiple beams. This study investigated head and neck, lung, and prostate treatment plans to understand what is possible on ViewRay to narrow focus toward sites with optimal dosimetry. The goal is not to provide a rigorous assessment of planning capabilities, but rather a first order demonstration of ViewRay planning abilities. Images, structure sets, points, and dose from treatment plans created in Pinnacle for patients in our clinic were imported into ViewRay. The same objectives were used to assess plan quality and all critical structures were treated as similarly as possible. Homogeneity index (HI), conformity index (CI), and volume receiving <20% of prescription dose (DRx) were calculated to assess the plans. The 95% confidence intervals were recorded for all measurements and presented with the associated bars in graphs. The homogeneity index (D5/D95) had a 1-5% inhomogeneity increase for head and neck, 3-8% for lung, and 4-16% for prostate. CI revealed a modest conformity increase for lung. The volume receiving 20% of the prescription dose increased 2-8% for head and neck and up to 4% for lung and prostate. Overall, for head and neck Co-60 ViewRay treatments planned with its Monte Carlo treatment planning software were comparable with 6 MV plans computed with convolution superposition algorithm on Pinnacle treatment planning system. PMID:24872603

A dose homogeneity and conformity evaluation between ViewRay and pinnacle-based linear accelerator IMRT treatment plans.

PubMed

Saenz, Daniel L; Paliwal, Bhudatt R; Bayouth, John E

2014-04-01

ViewRay, a novel technology providing soft-tissue imaging during radiotherapy is investigated for treatment planning capabilities assessing treatment plan dose homogeneity and conformity compared with linear accelerator plans. ViewRay offers both adaptive radiotherapy and image guidance. The combination of cobalt-60 (Co-60) with 0.35 Tesla magnetic resonance imaging (MRI) allows for magnetic resonance (MR)-guided intensity-modulated radiation therapy (IMRT) delivery with multiple beams. This study investigated head and neck, lung, and prostate treatment plans to understand what is possible on ViewRay to narrow focus toward sites with optimal dosimetry. The goal is not to provide a rigorous assessment of planning capabilities, but rather a first order demonstration of ViewRay planning abilities. Images, structure sets, points, and dose from treatment plans created in Pinnacle for patients in our clinic were imported into ViewRay. The same objectives were used to assess plan quality and all critical structures were treated as similarly as possible. Homogeneity index (HI), conformity index (CI), and volume receiving <20% of prescription dose (DRx) were calculated to assess the plans. The 95% confidence intervals were recorded for all measurements and presented with the associated bars in graphs. The homogeneity index (D5/D95) had a 1-5% inhomogeneity increase for head and neck, 3-8% for lung, and 4-16% for prostate. CI revealed a modest conformity increase for lung. The volume receiving 20% of the prescription dose increased 2-8% for head and neck and up to 4% for lung and prostate. Overall, for head and neck Co-60 ViewRay treatments planned with its Monte Carlo treatment planning software were comparable with 6 MV plans computed with convolution superposition algorithm on Pinnacle treatment planning system.

A NOVEL CO{sub 2} SEPARATION SYSTEM

DOE Office of Scientific and Technical Information (OSTI.GOV)

Robert J. Copeland

2000-03-01

Because of concern over global climate change, new systems are needed that produce electricity from fossil fuels and emit less CO{sub 2}. The fundamental problem with current systems which recover and concentrate CO{sub 2} from flue gases is the need to separate dilute CO{sub 2} and pressurize it to roughly 35 atm for storage or sequestration. This is an energy intensive process that can reduce plant efficiency by 9-37% and double the cost of electricity. There are two fundamental reasons for the current high costs of power consumption, CO{sub 2} removal, and concentration systems: (1) most disposal, storage and sequesteringmore » systems require high pressure CO{sub 2} (at roughly 35 atm). Thus, assuming 90% removal of the CO{sub 2} from a typical atmospheric pressure flue gas that contains 10% CO{sub 2}, the CO{sub 2} is essentially being compressed from 0.01 atm to 35 atm (a pressure ratio of 3,500). This is a very energy intensive process. (2) The absorption-based (amine) separation processes that are used to remove the CO{sub 2} from the flue gas and compress it to 1 atm consume approximately 10 times as much energy as the theoretical work of compression because they are heat driven cycles working over a very low temperature difference. Thus, to avoid the problems of current systems, we need a power cycle in which the CO{sub 2} produced by the oxidation of the fuel is not diluted with a large excess of nitrogen, a power cycle which would allow us to eliminate the very inefficient thermally driven absorption/desorption step. In addition, we would want the CO{sub 2} to be naturally available at high pressure (approximately 3 to 6 atmospheres), which would allow us to greatly reduce the compression ratio between generation and storage (from roughly 3,500 to approximately 8).« less

A NOVEL CO{sub 2} SEPARATION SYSTEM

DOE Office of Scientific and Technical Information (OSTI.GOV)

Robert J. Copeland

2000-05-01

Because of concern over global climate change, new systems are needed that produce electricity from fossil fuels and emit less CO{sub 2}. The fundamental problem with current systems which recover and concentrate CO{sub 2} from flue gases is the need to separate dilute CO{sub 2} and pressurize it to roughly 35 atm for storage or sequestration. This is an energy intensive process that can reduce plant efficiency by 9-37% and double the cost of electricity. There are two fundamental reasons for the current high costs of power consumption, CO{sub 2} removal, and concentration systems: (1) most disposal, storage and sequesteringmore » systems require high pressure CO{sub 2} (at roughly 35 atm). Thus, assuming 90% removal of the CO{sub 2} from a typical atmospheric pressure flue gas that contains 10% CO{sub 2}, the CO{sub 2} is essentially being compressed from 0.01 atm to 35 atm (a pressure ratio of 3,500). This is a very energy intensive process. (2) The absorption-based (amine) separation processes that are used to remove the CO{sub 2} from the flue gas and compress it to 1 atm consume approximately 10 times as much energy as the theoretical work of compression because they are heat driven cycles working over a very low temperature difference. Thus, to avoid the problems of current systems, we need a power cycle in which the CO{sub 2} produced by the oxidation of the fuel is not diluted with a large excess of nitrogen, a power cycle which would allow us to eliminate the very inefficient thermally driven absorption/desorption step. In addition, we would want the CO{sub 2} to be naturally available at high pressure (approximately 3 to 6 atmospheres), which would allow us to greatly reduce the compression ratio between generation and storage (from roughly 3,500 to approximately 8).« less

A NOVEL CO{sub 2} SEPARATION SYSTEM

DOE Office of Scientific and Technical Information (OSTI.GOV)

Robert J. Copeland

2000-08-01

Because of concern over global climate change, new systems are needed that produce electricity from fossil fuels and emit less CO{sub 2}. The fundamental problem with current systems which recover and concentrate CO{sub 2} from flue gases is the need to separate dilute CO{sub 2} and pressurize it to roughly 35 atm for storage or sequestration. This is an energy intensive process that can reduce plant efficiency by 9-37% and double the cost of electricity. There are two fundamental reasons for the current high costs of power consumption, CO{sub 2} removal, and concentration systems: (1) most disposal, storage and sequesteringmore » systems require high pressure CO{sub 2} (at roughly 35 atm). Thus, assuming 90% removal of the CO{sub 2} from a typical atmospheric pressure flue gas that contains 10% CO{sub 2}, the CO{sub 2} is essentially being compressed from 0.01 atm to 35 atm (a pressure ratio of 3,500). This is a very energy intensive process. (2) The absorption-based (amine) separation processes that are used to remove the CO{sub 2} from the flue gas and compress it to 1 atm consume approximately 10 times as much energy as the theoretical work of compression because they are heat driven cycles working over a very low temperature difference. Thus, to avoid the problems of current systems, we need a power cycle in which the CO{sub 2} produced by the oxidation of the fuel is not diluted with a large excess of nitrogen, a power cycle which would allow us to eliminate the very inefficient thermally driven absorption/desorption step. In addition, we would want the CO{sub 2} to be naturally available at high pressure (approximately 3 to 6 atmospheres), which would allow us to greatly reduce the compression ratio between generation and storage (from roughly 3,500 to approximately 8).« less

Carbon dioxide as working gas for laboratory plasmas

NASA Technical Reports Server (NTRS)

Kist, R.

1976-01-01

Measurements with a RF probe, retarding potential analyzer and mass spectrometer in a laboratory plasma tank were performed using the gases CO2, N2, A and He in order to compare their properties as working gases for laboratory plasma production. The overall result of that CO2 leads to higher plasma densities at lower neutral-gas pressures as well as to a larger Maxwellian component of the electron population, while the electron temperature is lower than that when N2, A and He are used.

Taking it one day at a time: African American women aging with HIV and co-morbidities.

PubMed

Warren-Jeanpiere, Lari; Dillaway, Heather; Hamilton, Pilar; Young, Mary; Goparaju, Lakshmi

2014-07-01

Self-managing HIV/AIDS presents challenges for anyone infected. These challenges may be further complicated for older HIV-infected African American women who acquired the disease at younger ages and now have co-morbidities. Little is known regarding how women's age identity, social responsibilities, co-morbidities, and romantic relationship status influence their HIV self-management. Five focus groups were conducted in Washington DC, with HIV-positive African American women aged 52-65. Topics included HIV and co-morbidity self-management, social support needs, medication adherence, and future plans for old age. A constant comparison approach was applied during data analysis. Co-morbidities, including diabetes and hypertension, were perceived to be more difficult to self-manage than HIV. This difficulty was not attributed to aging but to daily struggles such as lack of income and/or health insurance, an inflexible work schedule, and loneliness. Social responsibilities, including caring for family, positively impacted participants' ability to self-manage HIV by serving as motivation to stay healthy in order to continue to help family members. In contrast, inflexible work schedules negatively impacted women's ability to sustain medication adherence. Overall, this study demonstrates that HIV and co-morbidity self-management are inextricably linked. We can no longer afford to view engagement in HIV care as a single-disease issue and hope to attain optimal health and well-being in our HIV-affected populations. Optimal HIV self-management must be framed within a larger context that simultaneously addresses HIV and co-morbidities, while considering how social and cultural factors uniquely intersect to influence older African American women's self-management strategies.

Occupational Training Plans for Disadvantaged and Handicapped Students in Vocational Education. A Manual for Use in Cooperative Work Experience Programs.

ERIC Educational Resources Information Center

Eley, Robert K., Ed.

This manual, developed to provide vocational instructors or coordinators with model training plans to be used to conduct concurrent work and education programs for disadvantaged and handicapped students, has the purposes of: (1) serving as a description of the kinds of content that should be included in a training plan, (2) serving as an example…

78 FR 46861 - Approval and Promulgation of Air Quality Implementation Plans; State of Colorado; Second Ten-Year...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-02

...) section 175A(b) second 10-year maintenance plan for the Greeley area for the carbon monoxide (CO) National Ambient Air Quality Standard (NAAQS). This limited maintenance plan (LMP) addresses maintenance of the CO..., Mailcode 8P-AR, 1595 Wynkoop Street, Denver, Colorado 80202-1129. Hand Delivery: Carl Daly, Director, Air...

Search For Effects of an Electrostatic Potential on Clocks in the Frame of Reference of a Charged Particle

NASA Technical Reports Server (NTRS)

Ringermacher, Harry I.; Conradi, Mark S.; Cassenti, Brice N.; Millis, Marc G. (Technical Monitor)

2001-01-01

The Program Planning meeting was held on Jan 27-28 at the Washington University, Dept. of Physics. Experiment strategies and details were discussed and milestones mapped. Dr. Ringermacher, the program technical leader and Co-Principal Investigator, presented a Physics Department seminar on the theory and experiment in progress. Following the meeting Professor Conradi (CO-PI) and his students designed the NMR probe and electronics required for the experiment and submitted the drawings to the shop for fabrication. Dr. Cassenti, at UTRC, initiated analytic and computer analysis of the experimental conditions in order to anticipate possible classical effects. Dr. Ringermacher, at KRONOTRAN, re-evaluated the experiment interpretation from the theory and continued working to secure its underpinnings.